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Sample records for alkaline pluton kola

  1. Pyroxenes of the Khibiny alkaline pluton, Kola Peninsula

    Science.gov (United States)

    Yakovenchuk, V. N.; Ivanyuk, G. Yu.; Pakhomovsky, Ya. A.; Men'shikov, Yu. P.; Konopleva, N. G.; Korchak, Yu. A.

    2008-12-01

    Seven pyroxene varieties were identified in nepheline syenites and foidolites of the Khibiny pluton: enstatite, ferrosilite, diopside, hedenbergite, augite, aegirine-augite, and aegirine. Enstatite and augite are typical of alkaline and ultramafic rocks of dike series. Ferrosilite was found in country quartzitic hornfels. Diopside is a rock-forming mineral in alkaline and ultramafic rocks, alkali gabbroids, hornfels in xenoliths of volcanic and sedimentary rocks and foyaite, melteigite-urtite that assimilate them, and certain hydrothermal pegmatite veins. Hedenbergite was noted in hornfels from xenoliths of volcanic and sedimentary rocks and in a hydrothermal pegmatite vein at Mount Eveslogchorr. Aegirine-augite is the predominant pyroxene in all types of nepheline syenites, phonolites and tinguaites, foidolites, alkaline and ultramafic rocks of dike series, fenitized wall rocks surrounding the pluton, and xenoliths of Devonian volcanic and sedimentary rocks. Aegirine is an abundant primary or, more often, secondary mineral in nepheline syenites, foidolites, and hydrothermal pegmatite veins. It occurs as separate crystals, outer zones of diopside and aegirine-augite crystals, and homoaxial pseudomorphs after Na-Ca amphiboles. Microprobe analyses of 265 pyroxenes samples allowed us to distinguish ten principal trends of isomorphic replacement and corresponding typomorphic features of pyroxenes. Compositional variations in clinopyroxenes along the sampled 35-km profile from the margin of the Khibiny pluton to its center confirm the symmetric zoning of the foyaite pluton relative to semicircular faults of the Minor Arc and the Main (Central) Ring marked by Devonian volcanic and sedimentary rocks, foidolites, and related metasomatic rocks (rischorrite, albitite, and aegirinite). Changes in the composition of pyroxenes are explained mainly by the redistribution of elements between coexisting minerals of foyaites in the process of their intense differentiation under the

  2. Amphiboles of the Khibiny alkaline pluton, Kola Peninsula, Russia

    Science.gov (United States)

    Konopleva, N. G.; Ivanyuk, G. Yu.; Pakhomovsky, Ya. A.; Yakovenchuk, V. N.; Men'shikov, Yu. P.; Korchak, Yu. A.

    2008-12-01

    The rocks of the Khibiny pluton contain 25 amphibole varieties, including edenite, fluoredenite, kaersutite, pargasite, ferropargasite, hastingsite, magnesiohastingsite, katophorite, ferrikatophorite, magnesiokatophorite, magnesioferrikatophorite, magnesioferrifluorkatophorite, ferrimagnesiotaramite, ferrorichterite, potassium ferrorichterite, richterite, potassium richterite, potassium fluorrichterite, arfvedsonite, potassium arfvedsonite, magnesioarfvedsonite, magnesioriebeckite, ferriferronyboite, ferrinyboite, and ferroeckermannite. The composition of rock-forming amphiboles changes symmetrically relative to the Central Ring of the pluton; i.e., amphiboles enriched in K, Ca, Mg, and Si are typical of foyaite near and within the Central Ring. The Fe and Mn contents in amphiboles increase in the direction from marginal part of the pluton to its center. Foyaite of the marginal zone contains ferroeckermannite, richterite, arfvedsonite, and ferrorichterite; edenite is typical of foyaite and hornfels of the Minor Arc. Between the Minor Arc and the Central Ring, foyaite contains ferroeckermannite, arfvedsonite, and richterite; amphiboles in rischorrite, foidolite and hornfels of the Central Ring are (potassium) arfvedsonite, (potassium) richterite, magnesiokatophorite, magnesioarfvedsonite, ferroeckermannite, and ferriferronyboite; amphiboles in foyaite within the Central Ring, in the central part of the pluton, are arfvedsonite, magnesioarfvedsonite, ferriferronyboite, katophorite, and richterite. It is suggested that such zoning formed due to the alteration of foyaite by a foidolite melt intruded into the Main (Central) Ring Fault.

  3. Typomorphism of fluorapatite in the Khibiny alkaline pluton, Kola Peninsula

    Science.gov (United States)

    Konopleva, N. G.; Ivanyuk, G. Yu.; Pakhomovsky, Ya. A.; Yakovenchuk, V. N.; Mikhailova, Yu. A.

    2014-12-01

    The zoning of accessory and rock-forming fluorapatite in the Khibiny pluton is discussed in its content, morphology, and chemical composition. The concentrations of Na, REE, and Si impurities in fluorapatite decrease from the margin and center of the pluton to the Major Ring, composed of melteigiteurtite and rischorrite. Within this structure, the purest apatite is characteristic of the high-grade ore in large deposits, where it occurs free of Na, and REE, as well as Sr in place of Ca. The fractal dimension of fluorapatite aggregates in all textural types of apatite-nepheline rocks (ores) corresponds to the dimension of fractures. Along with mineralogy of apatite-nepheline rocks and zoning of host foidolite, this feature indicates the superimposed character of apatite mineralization.

  4. Corundum-group minerals in rocks of the Khibiny alkaline pluton, Kola Peninsula

    Science.gov (United States)

    Mikhailova, Yu. A.; Konopleva, N. G.; Yakovenchuk, V. N.; Ivanyuk, G. Yu.; Men'shikov, Yu. P.; Pakhomovsky, Ya. A.

    2007-12-01

    Five minerals of the corundum group have been identified in the Khibiny pluton with certainty. Corundum proper and karelianite occur only in hornfels after volcanic and sedimentary rocks. Xenoliths of hornfels mark the ring faults that bound foidalite within the field of foyaite. Hematite occurs in hydrothermally altered nepheline syenite and crosscutting hydrothermal veins related to the ring faults. Minerals of the ilmenite-pyrophanite series are present in all rocks of the pluton, including veins. Accessory ilmenite in foyaite varies from the manganese variety and pyrophanite in the inner and outer parts of the pluton to manganese-free ilmenite in zone of the Main Ring Fault. In xenoliths of volcanic rocks and alkaline ultramafic rocks, ilmenite is enriched in magnesium. The zoning in distribution of the above-mentioned minerals and the character of variation in their compositions from margins of the pluton to its center are consistent with the petrochemical zoning formed as a result of foyaite alteration of near ring faults.

  5. Spinel-group minerals in rocks of the Khibiny alkaline pluton, Kola Peninsula

    Science.gov (United States)

    Ivanyuk, G. Yu.; Pakhomovsky, Ya. A.; Konopleva, N. G.; Yakovenchuk, V. N.; Men'shikov, Yu. P.; Mikhailova, Yu. A.

    2007-12-01

    Seven spinel-group minerals in various geological settings have been revealed in the rocks of the Khibiny pluton. Hercynite, gahnite, and vuorelainenite occur only in xenoliths of hornfels after volcanic and sedimentary rocks, whereas spinel and magnesiochromite occur in alkaline ultramafic rocks of dike series. Franklinite has been discovered in a low-temperature hydrothermal vein. Ubiquitous magnetite is abundant in foyaite, foidolites, alkaline ultrabasic rocks, and pegmatite and hydrothermal veins and may even be the main mineral in some foidolite varieties. The spinel-group minerals are characterized by various chemical compositions due to the fractionation of nepheline syenites resulting in formation of the Main ring of foidolites and apatite-nepheline ore. Like most other minerals found throughout the pluton, magnetite is characterized by variation in the chemical composition along the radial line from the contact with country Proterozoic volcanic rocks to the geometric center of the pluton. Toward the center, the total Ti and Mn contents in magnetite increase from 5 15 up to 40 at %.

  6. Typochemistry of rinkite and products of its alteration in the Khibiny Alkaline pluton, Kola Peninsula

    Science.gov (United States)

    Konopleva, N. G.; Ivanyuk, G. Yu.; Pakhomovsky, Ya. A.; Yakovenchuk, V. N.; Mikhailova, Yu. A.; Selivanova, E. A.

    2015-12-01

    The occurrence, morphology, and composition of rinkite are considered against the background of zoning in the Khibiny pluton. Accessory rinkite is mostly characteristic of foyaite in the outer part of pluton, occurs somewhat less frequently in foyaite and rischorrite in the central part of pluton, even more sparsely in foidolites and apatite-nepheline rocks, and sporadically in fenitized xenoliths of the Lovozero Formation. The largest, up to economic, accumulations of rinkite are related to the pegmatite and hydrothermal veins, which occur in nepheline syenite on both sides of the Main foidolite ring. The composition of rinkite varies throughout the pluton. The Ca, Na, and F contents in accessory rinkite and amorphous products of its alteration progressively increase from foyaite and fenitized basalt of the Lovozero Formation to foidolite, rischorrite, apatite-nepheline rocks, and pegmatite-hydrothermal veins.

  7. Rock-Forming feldspars of the Khibiny alkaline pluton, Kola Peninsula, Russia

    Science.gov (United States)

    Ivanyuk, G. Yu.; Pakhomovsky, Ya. A.; Konopleva, N. G.; Kalashnikov, A. O.; Korchak, Yu. A.; Selivanova, E. A.; Yakovenchuk, V. N.

    2010-12-01

    This paper describes the structural-compositional zoning of the well-known Khibiny pluton in regard to rock-forming feldspars. The content of K-Na-feldspars increases inward and outward from the Main foidolite ring. The degree of coorientation of tabular K-Na-feldspar crystals sharply increases in the Main ring zone, and microcline-dominant foyaite turns into orthoclase-dominant foyaite. The composition of K-Na-feldspars in the center of the pluton and the Main ring zone is characterized by an enrichment in Al. This shift is compensated by a substitution of some K and Na with Ba (the Main ring zone) or by an addition of K and Na cations to the initially cation-deficient microcline (the central part of the pluton). Feldspars of volcanosedimentary rocks occurring as xenoliths in foyaite primarily corresponded to plagioclase An15-40, but high-temperature fenitization and formation of hornfels in the Main ring zone gave rise to the crystallization of anorthoclase subsequently transformed into orthoclase and albite due to cooling and further fenitization. Such a zoning is the result of filling the Main ring fault zone within the homogeneous foyaite pluton with a foidolite melt, which provided the heating and potassium metasomatism of foyaite and xenoliths of volcanosedimentary rocks therein. The process eventually led to the transformation of foyaite into rischorrite-lyavochorrite, while xenoliths were transformed into aluminum hornfels with anorthoclase, annite, andalusite, topaz, and sekaninaite.

  8. Relationship between oxosilicate niobium mineralization and organic matter in alkaline pegmatites of the Khibiny pluton, Kola Peninsula

    Science.gov (United States)

    Chukanov, N. V.; Pekov, I. V.; Perepelitsina, E. O.; Ermolaeva, V. N.; Vozchikova, S. A.

    2010-12-01

    In alkaline pegmatites of the Khibiny pluton niobium oxosilicates with (Nb + Ti)/Si ≥ 1 and Nb > Ti occur in intimate fine intergrowths with endogenic organic matter, which makes it possible to assume a genetic relationship between them. Such intergrowths from pegmatites of Mounts Kukisvumchorr and Koashva have been studied by electron microscopy, electron microprobe, IR spectroscopy, and exclusion chromatography. Unsaturated hydrocarbon groups, including aromatic ones, and carboxylate groups are prevalent in the organic matter intergrown with the niobium oxosilicates. The molecular weight distribution in the part of the bitumen soluble in tetrahydrofurane is polymodal, probably due to its formation as a result of parallel reactions on several catalytic centers of polymerization.

  9. Structural paragenesis as an indicator of the origin of alkaline rocks in the ijolite-urtite arc of the Khibiny pluton, Kola Peninsula

    Science.gov (United States)

    Kulakovsky, A. L.

    2015-03-01

    The results of structural analysis of the ore-bearing complex in the Khibiny pluton are presented. A multistage history of the formation of the ijolite-urtite arc structure has been established. The conic shear zone that determines the structural appearance of the ore-bearing complex is related to the early deformation stage. Only massive ijolite and melteigite are rocks of predeformation matrix. All other rock varieties and apatite ore are syndeformation (gneissic ijolite) or postdeformation (urtite, apatite ore) and thus are not magmatic in origin. The formation of the Paleozoic conic shear zone was most likely predetermined by a Precambrian central-type structure, more precisely, by a binucleus vortex structure related to shearing.

  10. Fluorcanasite, K3Na3Ca5Si12O30(F,OH)4 · H2O, a new mineral species from the Khibiny alkaline pluton, Kola Peninsula, Russia, and new data on canasite

    Science.gov (United States)

    Khomyakov, A. P.; Nechelyustov, G. N.; Krivokoneva, G. K.; Rastsvetaeva, R. K.; Rozenberg, K. A.; Rozhdestvenskaya, I. V.

    2009-12-01

    Fluorcanasite is described, a new mineral species found in dumps of the Kirovsk apatite mine, Mt. Kukisvumchorr, Khibiny alkaline pluton, Kola Peninsula, Russia. The new mineral is associated with microcline, nepheline, aegirine, scherbakovite, lamprophyllite, pectolite, mosandrite, villiaumite, rasvumite, and molybdenite. It occurs as prismatic crystals up to 0.2-0.3 × 1-2 mm in size extending along [010]. Fluorcanasite is purple, transparent, with white streak and vitreous luster. The fracture is hackly along the extension and stepped in other directions. The mineral is brittle. The cleavage is eminent parallel to {100} and {201} and perfect parallel to {001}. D(meas) = 2.68(2) g/cm3 (volumetric method); D(calc) = 2.69 g/cm3. Fluorcanasite is biaxial, negative, n α = 1.538(1), n β = 1.546(1), n γ = 1.549(1), 2 V(meas) = 60(2)°, 2 V(calc) = 63°. Dispersion r > v. The new mineral is pleochroic according to the scheme N β > N γ > N α; N β is purple, N γ is lilac, and N α is amber-yellow. Orientation is as follows: b = N β, a∧ N γ = 3°, c∧ N α = 19°. Fluorcanasite is not luminescent in UV light and slowly decomposes in acid. The new mineral is monoclinic, space group Cm, a = 18.846(4), b = 7.242(1), c = 12.650(2) Å, β = 111.84(2)°, V = 1602.6(4) Å3, Z = 2. The strongest reflections [ d, Å( I)] in the X-ray powder pattern of a grainoriented sample are 2.915(100), 4.204(40), 5.872(36), 4.712(36), 2.358(32), 3.012(24), 2.310(24), 3.082(24) and the same reflections in a randomly oriented sample are 3.082(100), 2.915(85), 4.712(46), 4.204(41), 3.340(35), 5.872(33), 2.658(30). The chemical composition, determined with an electron microprobe, is as follows, wt %: 7.19 Na2O, 10.91 K2O, 19.55 CaO, 0.27 FeO, 2.08 MnO, 55.84 SiO2, 4.10 F, 2.22 H2O (determined on the basis of structural data), 1.73-O = F2; the total is 100.43. The empirical formula, calculated on the basis of Si = 12, is K2.99Na3.00(Ca4.50Mn0.38·Fe{0.05/2+})Σ4.93Si12O29.93(F2.79OH1

  11. Shlykovite KCa[Si4O9(OH)] · 3H2O and cryptophyllite K2Ca[Si4O10] · 5H2O, new mineral species from the Khibiny alkaline pluton, Kola Peninsula, Russia

    Science.gov (United States)

    Pekov, I. V.; Zubkova, N. V.; Filinchuk, Ya. E.; Chukanov, N. V.; Zadov, A. E.; Pushcharovsky, D. Yu.; Gobechiya, E. R.

    2010-12-01

    New minerals, shlykovite and cryptophyllite, hydrous Ca and K phyllosilicates, have been identified in hyperalkaline pegmatite at Mount Rasvumchorr, Khibiny alkaline pluton, Kola Peninsula, Russia. They are the products of low-temperature hydrothermal activity and are associated with aegirine, potassium feldspar, nepheline, lamprophyllite, eudialyte, lomonosovite, lovozerite, tisinalite, shcherbakovite, shafranovskite, ershovite, and megacyclite. Shlykovite occurs as lamellae up to 0.02 × 0.02 × 0.5 mm in size or fibers up to 0.5 mm in length usually combined in aggregates up to 3 mm in size, crusts, and parallel-columnar veinlets. Cryptophyllite occurs as lamellae up to 0.02 × 0.1 × 0.2 mm in size intergrown with shlykovite being oriented parallel to {001} or chaotically arranged. Separate crystals of the new minerals are transparent and colorless; the aggregates are beige, brownish, light cream, and pale yellowish-grayish. The cleavage is parallel to (001) perfect. The Mohs hardness of shlykovite is 2.5-3. The calculated densities of shlykovite and cryptophyllite are 2.444 and 2.185 g/cm3, respectively. Both minerals are biaxial; shlykovite: 2 V meas = -60(20)°; cryptophyllite: 2 V meas > 70°. The refractive indices are: shlykovite: α = 1.500(3), β = 1.509(2), γ = 1.515(2); cryptophyllite: α = 1.520(2), β = 1.523(2), γ = 1.527(2). The chemical composition of shlykovite determined by an electron microprobe (H2O determined from total deficiency) is as follows, wt %: 0.68 Na2O, 11.03 K2O, 13.70 CaO, 59.86 SiO2, 14.73 H2O; the total is 100.00. The empirical formula calculated on the basis of 13 O atoms (OH/H2O calculated from the charge balance) is (K0.96Na0.09)Σ1.05Ca1.00Si4.07O9.32(OH)0.68 · 3H2O. The idealized formula is KCa[Si4O9(OH)] · 3H2O. The chemical composition of cryptophyllite determined by an electron microprobe (H2O determined from the total deficiency) is as follows, wt %: 1.12 Na2O, 17.73 K2O, 11.59 CaO, 0.08 Al2O3, 50.24 SiO2, 19.24 H2

  12. Elpasolite from hyperalkaline pegmatite of the Khibiny pluton, Kola Peninsula. Symmetry of elpasolite

    Science.gov (United States)

    Pekov, I. V.; Chukanov, N. V.; Kononkova, N. N.; Zubkova, N. V.; Rabadanov, M. Kh.; Pushcharovsky, D. Yu.

    2008-12-01

    Elpasolite, K2NaAlF6, has been found for the first time in a pegmatite related to peralkaline foid syenite at Mt. Koashva, Khibiny alkaline pluton, Kola Peninsula, Russia, as pale pink octahedral crystals up to 2 mm in size within cavities in the natrolite core of pegmatite in association with amicite, sodalite, aegirine, pectolite, catapleiite, sitinakite, lemmleinite-K, and vinogradovite. The chemical composition determined with an electron microprobe is as follows, wt %: 31.53 K; 9.22 Na; 11.20 Al; 47.21 F; total is 99.16. The empirical formula is K1.96Na0.98Al1.01F6.05. The infrared spectrum is given. The crystal structure has been refined to R = 0.030, space group Fm bar 3 m, a = 8.092 Å. The result of a special X-ray powder diffraction study confirmed the suggestion made by Morss (1974) that reflections violating space group Fm bar 3 m in some published X-ray powder patterns of natural elpasolite are Kβ-lines.

  13. Davinciite, Na12K3Ca6Fe{3/2+}Zr3(Si26O73OH)Cl2, a New K,Na-Ordered mineral of the eudialyte group from the Khibiny Alkaline Pluton, Kola Peninsula, Russia

    Science.gov (United States)

    Khomyakov, A. P.; Nechelyustov, G. N.; Rastsvetaeva, R. K.; Rozenberg, K. A.

    2013-12-01

    This paper presents a description of a new zirconosilicate of the eudialyte group, which was named davinciite in honor of Leonardo da Vinci (1452-1519), a famous Italian scientist, painter, sculptor and architect. The new mineral has been found in hyperagpaitic pegmatite at the Rasvumchorr Mountain, Khibiny Pluton, Kola Peninsula, as relict inclusions, up to 1-2 mm in size in a rastsvetaevite matrix. It is associated with nepheline, sodalite, potassium feldspar, delhayelite, aegirine, shcherbakovite, villiaumite, nitrite, nacaphite, rasvumite, and djerfisherite. Davinciite is dark lavender and transparent, with a vitreous luster and white streak. The new mineral is brittle, with conchoidal fracture; the Mohs' hardness is 5. No indications of cleavage or parting were observed. The measured density is 2.82(2) g/cm3 (volumetric method); the calculated density is 2.848 g/cm3. Davinciite is optically uniaxial, positive; ω = 1.603(2), ɛ = 1.605(2). It is nonpleochroic and nonfluorescent in UV light. The new mineral slowly breaks down and gelates in 50% HCl and HNO3. It is trigonal, space group R3m. The unit-cell dimensions are a = 14.2956(2), c = 30.0228(5) Å, V=5313.6(2) Å3. The strongest reflections in the X-ray powder diffraction pattern [ d, Å ( I, %) ( hkl)] are as follows: 2.981(100)(315), 2.860(96)(404), 4.309(66)(205), 3.207(63)(208), 6.415(54)(104), 3.162(43)(217). The chemical composition (electron microprobe, H2O calculated from X-ray diffraction data) is as follows, wt %: 12.69 Na2O, 3.53 K2O, 11.02 CaO, 0.98 SrO, 0.15 BaO, 5.33 FeO, 0.37 MnO, 0.07 Al2O3, 51.20 SiO2, 0.39 TiO2, 11.33 ZrO2, 0.21HfO2, 0.09 Nb2O5, 1.89 Cl, 0.93H2O, -O = Cl2 0.43; total is 99.75. The empirical formula calculated on the basis of Si + Al + Zr + Hf + Ti + Nb = 29 ( Z = 3) is (Na1l.75Sr0.29Ba0.03)Σ12.07(K2.28Na0.72)Σ3Ca5.99(Fe2.26Mn0.16)Σ2.42(Zr2.80Ti0.15Hf0.03Nb0.02) Σ3(Si1.96Al0.04)Σ2[Si3O9]2 [Si9O27]2[(OH)1.42O0.58]Σ2[Cl1.62(H2O)0.38]Σ2 · 0.48H2O. The simplified

  14. Kalsilite of the Khibiny and Lovozero alkaline plutons, Kola Peninsula

    Science.gov (United States)

    Pakhomovsky, Ya. A.; Yakovenchuk, V. N.; Ivanyuk, G. Yu.

    2009-12-01

    Kalsilite—a typical mineral of ore-bearing zones of the Khibiny and Lovozero plutons—was formed after low-Si and high-K nepheline in one of three ways: (1) by relatively high-temperature replacement of Na with K; (2) due to orthoclase-kalsilite poikiloblastesis in foidolites and overlapping foyaites; or (3) by replacement of nepheline with zeolite.

  15. Initial subalkaline magmatism of the neoarchean alkaline province of the Kola Peninsula

    International Nuclear Information System (INIS)

    U-Pb Dating of zircons from sub-alkaline rock of latite-monzonite association has been performed to study the specific features of sub-alkaline magmatism of the neoarchean alkaline province of the Kola Peninsula central area. It is found that prevalent portions of zircon grains subjected to isotope dating have concordant ages as follows (m.a.): 2671 ± 6 (quartz latite), 2667 ± 10 (quartz monzonite), 2677 ± 5 (quartz syenite). Taking into account the error of age determination, a 2670 - 2680 m.a. limit is set on the time of magmatic crystallization of latite-monzonite rocks

  16. Uranium-lead dating of perovskite from the Afrikanda plutonic complex (Kola Peninsula, Russia) using LA-ICP-MS.

    Science.gov (United States)

    Reguir, E.; Camacho, A.; Yang, P.; Chakhmouradian, A. R.; Halden, N. M.

    2009-04-01

    Perovskite (CaTiO3) is a common early crystallizing accessory phase in a variety of alkaline rocks, and has been shown to contain enough U and Th for U-Pb dating. U and Pb analysis of perovskite has been primarily carried out using the SHRIMP or ID-TIMS techniques, and the resulting U-Pb dates commonly yield the emplacement age of the host rock. To our knowledge, only one U-Pb study of perovskite has been done using the LA-ICP-MS (Cox and Wilton, 2006). Some of the advantages of this method over the SHRIMP and ID-TIMS techniques include greater speed and lower cost of analysis. In this work, the U-Pb ages of perovskite from the Afrikanda plutonic complex (Russia) were obtained in situ using the LA-ICP-MS. The measured 238U/206Pb and 207Pb/206Pb ratios were corrected for time-dependent mass-bias using the well-calibrated zircon standard GJ-1 (608.5 ± 0.4 Ma; Jackson et al., 2004). On a Tera-Wasserburg diagram (Tera and Wasserburg, 1972) the analyses of perovskite from two magmatic phases (clinopyroxenite and carbonatite) plot in separate clusters. Although the variations in the 238U/206Pb and 207Pb/206Pb ratios within each group are small, there is enough dispersion between the two clusters to obtain a reasonably precise age of 375 ± 13 Ma (2; MSWD = 0.23), which strongly suggests that the carbonatitic rocks are broadly coeval with the clinopyroxenite. The only other isotopic study on the Afrikanda Complex was done on a clinopyroxenite using the Rb-Sr method and yielded a whole rock-mineral (perovskite, biotite, augite and apatite) isochron age of 364.0 ± 3.1 Ma (2; MSWD = 0.72). This age is within error of our U-Pb date, which demonstrates that LA-ICP-MS-based U-Pb dating of perovskite can serve as a reliable geochronological tool. References Cox, R.A. and Wilton, D.H.C. (2006) U-Pb dating of perovskite by LA-ICP-MS: An example from the Oka carbonatite, Quebec, Canada. Chem. Geol., 235, 21-32. Jackson, S.E., Pearson, N.J., Griffin, W.L. and Belousova, E.A. (2004

  17. Andrianovite, Na12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O, H2O,OH)5, a new potassium-rich mineral species of the eudialyte group from the Khibiny alkaline Pluton, Kola Peninsula, Russia

    Science.gov (United States)

    Khomyakov, A. P.; Nechelyustov, G. N.; Rastsvetaeva, R. K.; Rozenberg, K. A.

    2008-12-01

    This paper presents the description of a new eudialyte-group mineral, which was named andrianovite in honor of Valerii Ivanovich Andrianov (1938-1991), a famous Russian mathematician and crystallographer, who developed the AREN software package for structural study of minerals with variable composition. The new mineral has been found in pegmatite from the Koashva open pit, Khibiny Pluton, Kola Peninsula, as rims 0.1-1.0 mm wide surrounding the crystals of typical eudialyte. Aegirine, sodalite, microcline, natrolite, lomonosovite, lamprophyllite, mosandrite, and villiaumite are associated minerals. Andrianovite is light yellow, with vitreous luster and stepped fracture. It is transparent or turbid, with a white streak. The new mineral is brittle; the Mohs hardness is 5. The cleavage is imperfect parallel to (001). The measured density is 2.93(2) g/cm3 (volumetric method); the calculated density is 3.02 g/cm3. Andrianovite is optically uniaxial, negative; ω = 1.622(2), ɛ= 1.617(2). It is nonfluorescent and nonpleochroic. The new mineral slowly breaks down and gelates in 50% HCl and HNO3 at room temperature. It is trigonal, space group R3 m. The unit cell dimensions are a = 14.281(4), c = 30.243(7) Å, V = 5342(4) Å3. The strongest reflections in the X-ray powder pattern [ d, Å ( I, %)( hkl)] are as follows: 2.982(100)(315), 2.860(94)(404), 4.322(71)(205), 3.222(70)(208), 6.447(60)(104), 3.170(50)(217), 5.719(40)(202), 3.540(38)(027). The chemical composition (electron microprobe, H2O and CO2 determined by chemical analysis) is as follows, wt %: 11.61 Na2O, 2.05 K2O, 10.26 CaO, 3.11 SrO, 0.19 BaO, 3.97 MnO, 2.43 FeO, 0.81 La2O3, 1.73 Ce2O3, 0.52 Nd2O3, 0.28 Y2O3, 0.02 Al2O3, 47.06 SiO2, 0.12 TiO2, 11.32 ZrO2, 0.26 HfO2, 2.84 Nb2O5, 0.31 Cl, 0.57 CO2, 0.87 H2O, -O = 0.07 Cl2; total is 100.26. The empirical formula atcat = 53 ( Z= 3) is Na12.09(K1.40Sr0.97REE0.60Ba0.04)Σ3.01(Ca5.90Y0.08).98(Mn1.81)Fe{1.19/2+} Σ2.90(Zr2.96Hf0.04)Σ3.0(Nb0.69Si0.27Ti0.05Al0.01)Σ1

  18. Middendorfite, K3Na2Mn5Si12(O,OH)36 · 2H2O, a new mineral species from the Khibiny pluton, Kola Peninsula

    Science.gov (United States)

    Pekov, I. V.; Chukanov, N. V.; Dubinchuk, V. T.; Zadov, A. E.

    2007-12-01

    Middendorfite, a new mineral species, has been found in a hydrothermal assemblage in Hilairite hyperperalkaline pegmatite at the Kirovsky Mine, Mount Kukisvumchorr apatite deposit, Khibiny alkaline pluton, Kola Peninsula, Russia. Microcline, sodalite, cancrisilite, aegirine, calcite, natrolite, fluorite, narsarsukite, labuntsovite-Mn, mangan-neptunite, and donnayite are associated minerals. Middendorfite occurs as rhombshaped lamellar and tabular crystals up to 0.1 × 0.2 × 0.4 mm in size, which are combined in worm-and fanlike segregations up to 1 mm in size. The color is dark to bright orange, with a yellowish streak and vitreous luster. The mineral is transparent. The cleavage (001) is perfect, micalike; the fracture is scaly; flakes are flexible but not elastic. The Mohs hardness is 3 to 3.5. Density is 2.60 g/cm3 (meas.) and 2.65 g/cm3 (calc.). Middendorfite is biaxial (-), α = 1.534, β = 1.562, and γ = 1.563; 2 V (meas.) = 10°. The mineral is pleochroic strongly from yellowish to colorless on X through brown on Y and to deep brown on Z. Optical orientation: X = c. The chemical composition (electron microprobe, H2O determined with Penfield method) is as follows (wt %): 4.55 Na2O, 10.16 K2O, 0.11 CaO, 0.18 MgO, 24.88 MnO, 0.68 FeO, 0.15 ZnO, 0.20 Al2O3, 50.87 SiO2, 0.17 TiO2, 0.23 F, 7.73 H2O; -O=F2-0.10, total is 99.81. The empirical formula calculated on the basis of (Si,Al)12(O,OH,F)36 is K3.04(Na2.07Ca0.03)Σ2.10(Mn4.95Fe0.13Mg0.06Ti0.03Zn0.03)Σ5.20(Si11.94Al0.06)Σ12O27.57(OH)8.26F0.17 · 1.92H2O. The simplified formula is K3Na2Mn5Si12(O,OH)36 · 2H2O. Middenforite is monoclinic, space group: P21/ m or P21. The unit cell dimensions are a = 12.55, b = 5.721, c = 26.86 Å; β = 114.04°, V = 1761 Å3, Z = 2. The strongest lines in the X-ray powder pattern [ d, Å, ( I)( hkl)] are: 12.28(100)(002), 4.31(81)(11overline 4 ), 3.555(62)(301, 212), 3.063(52)(008, 31overline 6 ), 2.840(90)(312, 021, 30overline 9 ), 2.634(88)(21overline 9 , 1.0.overline 1 0

  19. Duration of formation of magmatic system of polyphase paleozoic alkaline complexes of the Central Kola: U-Pb, Rb-Sr, Ar-Ar data

    International Nuclear Information System (INIS)

    Attempt was made for the determination of duration of all abyssal system formation in the central part of the Kola peninsula. System of isotope methods inclosing Rb-Sr-isochronic dating, 40Ar/39Ar-age analysis of rocks as well as U-Th-Pb-dating is applied. Formation of the Khibiny-Lovozero-Kurga volcano-plutonic system is proposed to have a multiphase character. Summary scheme of the order of events is performed

  20. Redox potential of the Khibiny magmatic system and genesis of abiogenic hydrocarbons in alkaline plutons

    Science.gov (United States)

    Ryabchikov, I. D.; Kogarko, L. N.

    2009-12-01

    The temperature and redox conditions of the crystallization of rocks from the Khibiny alkaline pluton have been estimated based on an analysis of coexisting magnetite, ilmenite, titanite, and pyroxene. Under redox conditions characteristic of the Khibiny Complex, CO2 is contained in fluid and carbonate anions are contained in melt at high temperature; then graphite is released and an appreciable amount of hydrocarbons appear at a lower temperature as products of reaction of graphite with fluid. Abiogenic hydrocarbons can arise in igneous complexes owing to a processes distinct from Fischer-Tropsch synthesis.

  1. Distinctly different parental magmas for calc-alkaline plutons and tholeiitic lavas in the central and eastern Aleutian arc

    Science.gov (United States)

    Cai, Yue; Rioux, Matthew; Kelemen, Peter B.; Goldstein, Steven L.; Bolge, Louise; Kylander-Clark, Andrew R. C.

    2015-12-01

    Cenozoic calc-alkaline plutons that comprise the middle crust of the central and eastern Aleutians have distinct isotopic and elemental compositions compared to Holocene tholeiitic lavas in the same region, including those from the same islands. Therefore the Holocene lavas are not representative of the net magmatic transfer from the mantle into the arc crust. Compared to the lavas, the Eocene to Miocene (9-39 Ma) intermediate to felsic plutonic rocks show higher SiO2 at a given Fe/Mg ratio, and have higher εNd-εHf values and lower Pb-Sr isotope ratios. However, the plutonic rocks strongly resemble calc-alkaline Holocene volcanics with more "depleted" isotope ratios in the western Aleutians, whose composition has been attributed to significant contributions from partial melting of subducted basaltic oceanic crust. These data could reflect a temporal variation of central and eastern Aleutian magma source compositions, from predominantly calc-alkaline compositions with more "depleted" isotope ratios in the Paleogene, to tholeiitic compositions with more "enriched" isotopes more recently. Alternatively, the differences between central Aleutian plutonic and volcanic rocks may reflect different transport and emplacement processes for the magmas that form plutons versus lavas. Calc-alkaline parental magmas, with higher SiO2 and high viscosity, are likely to form plutons after extensive mid-crustal degassing of initially high water contents. This conclusion has overarching importance because the plutonic rocks are chemically similar to bulk continental crust. Formation of similar plutonic rocks worldwide may play a key role in the genesis and evolution of continental crust.

  2. Minerals of zirconolite group from fenitized xenoliths in nepheline syenites of Khibiny and Lovozero plutons, Kola Peninsula

    Science.gov (United States)

    Menshikov, Yu. P.; Mikhailova, Yu. A.; Pakhomovsky, Ya. A.; Yakovenchuk, V. N.; Ivanyuk, G. Yu.

    2015-12-01

    Zirconolite, its Ce-, Nd-, and Y-analogs, and laachite, another member of the zirconolite group, are typomorphic minerals of the fenitized xenoliths in nepheline syenite and foidolite of the Khibiny-Lovozero Complex, Kola Peninsula, Russia. All these minerals are formed at the late stage of fenitization as products of ilmentie alteration under the effect of Zr-bearing fluids. The diversity of these minerals is caused by the chemical substitutions of Na and Ca for REE, Th, and U compensated by substitution of Ti and Zr for Nb, Fe and Ta, as well as by the redistribution of REE between varieties enriched in Ti (HREE) or Nb (LREE). The results obtained can be used in the synthesis of Synroc-type titanate ceramics assigned for the immobilization of actinides.

  3. The rare-metal ore potential of the Proterozoic alkaline ultramafic massifs from eastern part of the Baltic Shield in the Kola alkaline province.

    Science.gov (United States)

    Sorokhtina, Natalia; Kogarko, Lia

    2014-05-01

    The Kola Alkaline Province consists of intrusions of two main stages of the intraplate alkaline magmatism. The early stage of igneous activity occurred in Proterozoic 1.9 billion years ago, the next in Paleozoic at 380 million years. The Proterozoic alkaline magmatism produced Gremyakha-Vyrmes and Elet'ozero large alkaline-ultrabasic massifs, Tiksheozero carbonatite massif and numerous small syenite complexes. Paleozoic magmatism on Baltic Shield exhibited more widely, than Proterozoic. The world largest Khibiny and Lovozero alkaline intrusions, numerous alkaline-ultrabasic massifs with carbonanites, alkaline dike swarms and diatremes were formed. It is well known that carbonatites of Paleozoic alkaline-ultrabasic massifs contain large-scale deposits of rare-metal ores (Afanasiev et al., 1998). The metasomatic rocks on foidolites and carbonatites of Gremyakha-Vyrmes are final products of differentiation of Proterozoic alkaline-ultrabasic magma enriched in incompatible elements, including Nb and Zr similar to Paleozoic carbonatites. The massif Gremyakha-Vyrmes is one of the largest titanomagnetite-ilmenite deposits in Russia associated with ultrabasites. Our investigation showed that albite-microcline and aegirine-albite metasomatites formed rich rare-metal ores consisting of 3.2 wt. % Nb2O5 and 0.7 ZrO2. Zircon and pyrochlore-group minerals represent the main minerals of rare-metal ores. The following evolutionary sequences of pyrochlore group minerals has been observed: betafite or U pyrochlore - Na-Ca pyrochlore - Ba-Sr pyrochlore - "silicified" pyrochlore - Fe-Nb, Al-Nb silicates. Such evolution from primary Nb oxides to secondary silicates under low temperature hydrothermal conditions is similar to the evolution of rare metal phases in Paleozoic alkaline massifs analogous to Lovozero syenites and in carbonatites. The rare metal minerals of Gremyakha-Vyrmes crystallized in high alkaline hydrothermal environment at increased activity of Nb, Ta, Zr, U, Th and at

  4. The Fontaine Pluton : an early Ross Orogeny calc-alkaline gabbro from southern Victoria Land, Antarctica

    International Nuclear Information System (INIS)

    The Fontaine Pluton is a previously undescribed mafic intrusion outcropping at Fontaine Bluff on the south side of the Carlyon Glacier in southern Victoria Land, Antarctica. It is the southern-most member of a laterally extensive mafic suite emplaced at mid-crustal depths during the initial stages of the Ross Orogeny. The pluton comprises recrystallised hornblende-biotite gabbro, which in places shows well-defined centimetre to metre scale primary igneous layering. Recrystallised ultramafic enclaves composed of amphibole-chlorite-talc are inferred to be remnants of a chemically and mineralogically distinct cumulate fraction. The intrusion has a 87Sr/86Sr(i) ratio of 0.70679 and a 143Nd/144Nd(i) ratio of 0.51187 (εNd(i) = -1.2). This, coupled with other geochemical data, implies that the Fontaine Pluton was formed by c. 15% partial melting of a depleted mantle source that was subsequently contaminated by continental crust. Preliminary U-Pb geochronology on zircon suggests an emplacement age for the pluton of 546 ± 10 Ma. These new data indicate that Ross Orogeny magmatism in this area of southern Victoria Land was initiated in the late Neoproterozoic along a subducting plate margin. (author). 55 refs., 10 figs., 3 tabs

  5. Evolution and geochemistry of the Tertiary calc-alkaline plutons in the Adak Island region of the central Aleutian oceanic island arc

    Science.gov (United States)

    Kay, Suzanne; Citron, Gary P.; Kay, Robert W.; Jicha, Brian; Tibbetts, Ashley

    2014-05-01

    Calc-alkaline plutons are major crustal building blocks of continental margin mountain belts like the Mesozoic to Tertiary Andes and the Sierra Nevada, but are rare in oceanic island arcs. Some of the most calc-alkaline I-type island arc plutons are in the Central Aleutians with the most extreme signatures, as indicated by FeO/MgO ratios of mafic volcanic and sedimentary rocks and postdate the small ~38 Ma tholeiitic Finger Bay pluton. The chemistry of these older magmatic rocks is basically similar to that of young Central Aleutian magmatic rocks with boninites and arc tholeiitic magmas seemingly being absent. The formation of the calc-alkaline plutons seems to require a sufficient crustal thickness, fluid concentration and contractional stress such that magma chambers can stabilize significant amounts of pargasitic hornblende. Seismic receiver function analyses (Janiszewski et al., 2013) indicate the modern Adak crust is ~ 37 km thick. Existing and new hornblende, plagioclase and biotite Ar/Ar ages from 16 Hidden Bay pluton and Gannet Lake stock gabbro, porphyritic diorite, diorite, granodiorite, leucogranodiorite and aplite samples range from 34.6 to 30.9 Ma and indicate an ~ 4 Ma intrusion history. Biotite Ar/Ar ages for Kagalaska gabbro and granodiorite samples range from 14.7 to 13.9 Ma. The new ages are consistent with the plutons being related to several eruptive centers and forming during the waning stages of volcanism as the magmatic arc front was displaced to the north, possibly in response to accelerated periods of forearc subduction erosion. The gabbroic to leucogranodioritic units evolved in the lower to mid-crust with more silicic magmas rising buoyantly to higher levels where final crystallization and segregation of aplites occurred. Most gabbro and all mafic diorite units are largely crystal cumulates; one gabbro approaches the melt composition of a high Al basalt. The volumetrically dominant silicic diorites and granodiorites (58-63% SiO2) show

  6. Mid-Neoproterozoic ridge subduction and magmatic evolution in the northeastern margin of the Indochina block: Evidence from geochronology and geochemistry of calc-alkaline plutons

    Science.gov (United States)

    Qi, Xuexiang; Santosh, M.; Zhao, Yuhao; Hu, Zhaocuo; Zhang, Chao; Ji, Fengbao; Wei, Cheng

    2016-04-01

    The mid-Neoproterozoic medium- to high-K calc-alkaline magmatic rocks in the northeastern margin of the Indochina block, SW China, provide important insights into the relationship of the Indochina block with the Gondwana supercontinent. Here we report zircon LA-ICP-MS U-Pb data from the early and late stage plutons which yield weighted mean 206Pb/238U ages of 765 Ma and 732-739 Ma suggesting mid-Neoproterozoic emplacement. The zircon εHf(t) values show a range of - 3.2 to + 2.4 (average + 0.1 ± 0.9) with TDMC of 1510 to 1870 Ma for the early plutons, and - 5.4 to + 5.1 (average + 2.1 to - 3.9) with TDMC of 1366 to 1985 Ma for late plutons. Both groups show similar geochemical characteristics including high Mg#, enrichment of LILE and LREE, slight negative Eu anomalies, and strongly negative Nb, Ta and Ti anomalies, with all the samples falling within the continental/island arc field in tectonic discrimination diagrams. These features suggest that the early and late stage magmas were produced by the mixing of mantle-derived magma and crust-derived magma in different proportion within an active continental margin, in subduction-related continental-arc tectonic setting. The linear zoning and roughly parallel distribution of the two generations of intrusions with a hiatus of 20 Ma might suggest an episode of ridge subduction with asthenosphere upwelling through the slab window that generated the second phase of plutons.

  7. Burovaite-Ca, (Na,K)4Ca2(Ti,Nb)8[Si4O12]4(OH,O)8·12H2O, a new labuntsovite-group mineral species and its place in low-temperature mineral formation in pegmatites of the Khibiny pluton, Kola Peninsula, Russia

    Science.gov (United States)

    Azarova, Yu. V.; Shlyukova, Z. V.; Zolotarev, A. A.; Organova, N. I.

    2009-12-01

    This paper presents data on burovaite-Ca, the first Ti-dominant member of the labuntsovite group with a calcium D-octahedron. The idealized formula of burovaite-Ca is (K,Na)4Ca2(Ti,Nb)8[Si4O12]4(OH,O)8 · 12H2O. The mineral has been found in the hydrothermal zone of aegirine-microcline pegmatite located in khibinite at Mt. Khibinpakhkchorr, the Khibiny pluton, Kola Peninsula, Russia. Radiaxial intergrowths of burovaite-Ca and labuntsovite-Mn associated with lemmleynite-Ba, analcime, and apophyllite have been identified in caverns within microcline. The mean composition of the mineral is as follows, wt %: 3.72 Na2O, 2.76 K2O, 4.22 CaO, 0.47 SrO, 0.23 BaO, 0.01 MnO, 0.30 Fe2O3, 0.14 Al2O3, 42.02 SiO2, 17.30 TiO2, 15.21 Nb2O5, 12.60 H2O (measured); the total is 98.98. Its empirical formula has been calculated on the basis of [(Si,Al)16O48]: {(Na3.10K1.07Ca0.37Sr0.04Ba0.04)4.62}(Ca1.28Zn0.01)1.29(Ti4.97Nb2.56Fe0.08Ta0.02)7.63(Si15.93Al0.07)16O48(OH6.70O0.93)7.63 · 12H2O. The strongest lines in the X-ray powder diffraction pattern of burovaite-Ca ( I-d Å] are as follows: 70-7.08, 40-6.39, 40-4.97, 30-3.92, 40-3.57, 100-3.25, 70-3.11, 50-2.61, 70-2.49, 40-2.15, 50-2.05, 70-1.712, 70-1.577, and 70-1.444. The structure of burovaite-Ca was solved by A.A. Zolotarev, Jr. The mineral is monoclinic, space group C2/ m. The unit-cell dimensions are a = 14.529(3), b = 14.203(3), c = 7.899(1), β = 117.37(1)°, V = 1447.57 Å3. Burovaite-Ca is an isostructural Ti-dominant analogue of karupmøllerite-Ca and gjerdingenite-Ca. Two stages of mineral formation—pegmatite proper and hydrothermal—have been recognized in the host pegmatite. The hydrothermal stage included K-Ba-Na, Na-K-Ca, and Na-Sr substages. Burovaite-Ca is related to the intermediate Na-K-Ca substage. At the first substage, labuntsovite-Mn and lemmleynite-Ba were formed, and tsepinite-Na, paratsepinite-Nd, and tsepinite-Sr were formed at the final substage. Thus, the sequence of crystallization of labuntsovite

  8. Geochemical features and age of baddeleyite from carbonatites of the Proterozoic Tiksheozero alkaline-ultramafic pluton, North Karelia

    Science.gov (United States)

    Rodionov, N. V.; Belyatsky, B. V.; Antonov, A. V.; Simakin, S. G.; Sergeev, S. A.

    2015-10-01

    On the basis of the local composition, baddeleyite grains that were less altered due to interaction with an alkaline melt and corresponded to the primary stage of crystallization of the intrusion were selected from the carbonatite intrusion of the Proterozoic polyphase Tiksheozero alkaline-ultramafic complex. The single age of carbonatite crystallization characterized of the bulk volume of the intrusion was estimated for the first time on the basis of 40 local U-Th-Pb (SHRIMP II) analyses of these grains. The overall concordant age of baddeleyite is 1994.8 ± 9.4 Ma, and the lower age limit of the polyphase complex formation is less than 1998.4 ± 3.5 Ma.

  9. The miocene Ashizuri complex (SW Japan): source and magma differentiation of an alkaline plutonic assemblage in an island-arc environment

    International Nuclear Information System (INIS)

    The Ashizuri complex, mainly composed of gabbro, syenite and granite, belongs to the Shimanto Middle Miocene magmatic province and represents one of the rare examples of a within-plate-like alkaline complex in an island-arc setting. This complex is temporally and spatially associated with calc-alkaline volcano-plutonic bodies and, in a lesser amount, with T- to E-MORB and arc tholeites. The least evolved rocks of the Ashizuri complex are enriched in light rare earth elements ((La/Yb)n = 8-16) and other incompatible elements (e.g., Ba/La ≅ 11-13; Ba/Nb ≅ 9-11), features of intra-plate alkali basalts. These features are also characteristic of the more evolved rocks of acidic composition. Trace element petrogenetic modelling suggests that all the different components of the suite are co-magmatic and points out the major role of crystal fractionation process in its genesis. Sr and Nd isotopic data (εNdi = -0.59 to +2.56; εSri = -9.19 to + 2.90) suggest that assimilation as well as crystal fractionation occurred. Derivation through mixing of a MORB-like source and an old enriched component (e.g., sediment or old crust), or through partial melting of lower crust cannot explain both the elemental and isotopic signature of the Ashizuri suite. An OIB-type enriched mantle source is required. By comparison with volcanic rocks in southwest Japan and in the neighbouring Philippine Sea oceanic plate, this source is believed to lie not in the sub-Japan lithosphere but deeper in the asthenosphere prevalent under Japan and the Philippine Sea Plate. (authors). 83 refs., 8 figs., 7 tabs

  10. A review of the occurrence, form and origin of C-bearing species in the Khibiny Alkaline Igneous Complex, Kola Peninsula, NW Russia

    Science.gov (United States)

    Nivin, V. A.; Treloar, P. J.; Konopleva, N. G.; Ikorsky, S. V.

    2005-11-01

    The Khibiny Complex hosts a wide variety of carbon-bearing species that include both oxidized and reduced varieties. Oxidised varieties include carbonate minerals, especially in the carbonatite complex at the eastern end of the pluton, and Na-carbonate phases. Reduced varieties include abiogenic hydrocarbon gases, particularly methane and ethane, dispersed bitumens, solid organic substances and graphite. The majority of the carbon in the Khibiny Complex is hosted in either the carbonatite complex or within the so-called "Central Arch". The Central Arch is a ring-shaped structure which separates khibinites (coarse-grained eudialite-bearing nepheline-syenites) in the outer part of the complex from lyavochorrites (medium-grained nepheline-syenites) and foyaites in the inner part. The Central Arch is petrologically diverse and hosts the major REE-enriched apatite-nepheline deposits for which the complex is best known. It also hosts zones with elevated hydrocarbon (dominantly methane) gas content and zones of hydrothermally deposited Na-carbonate mineralisation. The hydrocarbon gases are most likely the product of a series of post-magmatic abiogenic reactions. It is likely that the concentration of apatite-nepheline deposits, hydrocarbon gases and Na-carbonate mineralisation, is a function of long lived fluid percolation through the Central Arch. Fluid migration was facilitated by stress release during cooling and uplift of the Khibiny Complex. As a result, carbon with a mantle signature was concentrated into a narrow ring-shaped zone.

  11. Mineralogy, geochemistry, and genesis of high-alumina fenites of the Mont Saint-Hilaire alkaline pluton, Québec, Canada

    Science.gov (United States)

    Yakovleva, O. S.; Pekov, I. V.; Horváth, L.; Bryzgalov, I. A.; Yapaskurt, V. O.; Guseva, E. V.

    2010-12-01

    High-alumina fenites in the Mont Saint-Hilaire alkaline complex, Québec, Canada, form bodies at the contact of peralkaline nepheline syenite. Fenites are subdivided into four types: corundum-spessartine-biotite-feldspar, muscovite-corundum-hercynite-biotite-feldspar, carbonated muscovite-biotite-hercynite-feldspar, and spessartine-hercynite-feldspar. Accessory minerals of the ilmenite-pyrophanite series, columbites, zircon, thorite, pyrrhotite, Fe, Mn, Mg, Ca, Ba, and REE carbonates, uedaite-(Ce), etc. are identified. Three stages are suggested in the formation of these rocks. In mineralogy and geochemistry, the Mont Saint-Hilaire high-alumina fenites are similar to Al-rich fenites replacing xenoliths in the Khibiny alkaline complex, Russia. In both cases, fenites are related to peralkaline rocks and replace high-alumina protoliths: granite at Mont Saint-Hilaire and metapelites in the Khibiny Mountains. These fenites are regarded as a specific type of fenites with rock-forming Mg-depleted hercynite.

  12. The mafic dikes from the Panticosa pluton (Pyrenean Axial Zone): petrology and mineral chemistry

    OpenAIRE

    Tierz, Pablo; Lago San José, Marceliano; Galé, Carlos; Arranz, Enrique; Ubide, Teresa; Larrea, Patricia; Sanz, Tomás

    2012-01-01

    The Panticosa pluton is one of multiple granitic plutons cropping out in the Pyrenean Axial Zone, which corresponds to the Palaeozoic core of the Pyrenees. Mafic dikes cut both the Panticosa pluton and its Devonian metasedimentary country rocks. According to their mineralogy and mineral composition, these dikes can be classified into two different groups, with little textural variations: a calc-alkaline group and an alkaline group. The calcalkaline rocks (spessartites and ca...

  13. Cymrite as an indicator of high barium activity in the formation of hydrothermal rocks related to carbonatites of the Kola Peninsula

    Science.gov (United States)

    Sorokhtina, N. V.; Chukanov, N. V.; Voloshin, A. V.; Pakhomovsky, Ya. A.; Bogdanova, A. N.; Moiseev, M. M.

    2008-12-01

    Cymrite, BaAl2Si2O8 · nH2O, is a rare mineral formed during low-grade dynamothermal metamorphism ( T = 250-300°C, P = 1-3 kbar). Cymrite has been described from many metasedimentary ores and hydrothermal rocks. In carbonatites, it has been found for the first time. Cymrite has been identified in the Kovdor and Seblyavr massifs, Kola Peninsula. In Kovdor, this mineral has been described from one of the hydrothermal veins cutting the pyroxenite-melilitite-ijolite complex at the Phlogopite deposit; cymrite is associated with thomsonite, calcite, and stivensite. In the Seblyavr pluton, cymrite occurs in thin veins of calcite carbonatite that cut pyroxenite contacting with ijolite. Cymrite from the Seblyavr pluton is associated with calcite, natrolite, pyrite, and chalcopyrite. The mineral is optically negative and uniaxial, with extinction parallel to elongation; ω ˜ 1.607(1). According to X-ray diffraction data, cymrite from Seblyavr is monoclinic, space group P1 m1; unit-cell dimensions are: a = 5.33, b = 36.96, c = 7.66 Å, β = 90°, V = 1510.55 Å3. According to the results of IR spectroscopy, in the series of samples from different massifs (in the running order Kovdor-Voishor-Seblyavr), the double-layer deformation is enhanced and accompanied by a decrease in the Si-O-Si angle and weakening of hydrogen bonds of interlayer water. The empirical formulas of cymrite calculated from electron microprobe analyses are Ba0.93-0.95Ca0.01-0.02K0.00-0.05Na0.02-0.04Al1.97-2.01Si1.99-2.03O8(H2O) and Ba1.00-1.02Ca0.00-0.01Sr0.00-0.01Fe0.00-0.01Al1.94-2.00Si1.98-2.03O8(H2O) at Seblyavr and Kovdor, respectively. Cymrite from the carbonatite massifs of the Kola Peninsula was formed under hydrothermal conditions at low temperature (200-300°C), high activity of Ba and Si, and high water pressure. At Kovdor, the mineral crystallized directly from the residual solution enriched in Ba. The sequence of mineral deposition is as follows: thomsonite-cymrite-calcite-stevensite. Cymrite

  14. Thermobarometry of mantle-derived garnets and pyroxenes of Kola region (NW Russia: lithosphere composition, thermal regime and diamond prospectivity

    Directory of Open Access Journals (Sweden)

    Dmitry R. Zozulya

    2009-12-01

    Full Text Available More than 700 pyrope, chrome diopside and chromite grains recovered from Quaternary sediments of the Kola craton, and from the Ermakovsky kimberlite in the Terskii Coast field were analyzed in order to determine their P-T parameters. Ni-thermometry on pyropes from SE Kola gives a range of temperatures between 650–1250 °C, corresponding to a sampling interval of c. 75–190 km. Pyrope compositions imply a stratified structure to the SE Kola lithospheric mantle, with G10-pyropes absent in the shallow mantle (75–110 km where the bulk of the G9-pyropes are sourced, while a deeper mantle horizon, between110 and 190 km, has contributed abundant G10-pyropes. Approximately 16 % of all these pyropes are derived from the diamond stability field. The Ni-temperatures of garnets from the Ermakovsky kimberlite reveal a relatively shallow sampling interval of the mantle (c.75–140 km, dominantly within the graphite-stability field. P-T values for peridotitic chrome diopsides imply that most grains from SE Kola were derived from the graphite stability field, apparently originating from non-diamondiferous alkaline-ultramafic dykes. Nevertheless, c. 15 % of SE Kola diopsides have been derived from the stability field of diamond. Diopsides from SW Kola mostly plot in the diamond stability field. 20 % of diopsides from central Kolaare derived from the diamond stability field, whereas diopsides from northern Kola region all fall within the stability field of graphite. The maximum depth of diopside xenocryst sampling varies from up to 200 km in SE and SW Kola, to 170 km in central Kola, and only to 140 km in the northern Kola region. The P-T values for chrome diopsides imply significant regional differences in heat flow: 38–44 mW/m^2 within the southern part of Kola adjacent to the Kandalaksha graben; 35–38 mW/m^2 towards the SE and SW away from the graben; 38–44 mW/m^2 in central Kola; and up to 50 mW/m^2 in northernmost Kola. These data indicate that

  15. Radioactivity Levels in Kola Bay

    International Nuclear Information System (INIS)

    Sediment samples were collected in May 1995 from 16 locations in Kola Bay, North-west Russia, during an expedition starting from Murmansk and ending at Kildin Island in the Barents Sea. The purpose was to study the contamination level in an area with several potential sources of civilian and military radioactive pollution. 137Cs concentrations in the sediments, algae and benthic samples were low, but small particles containing 137Cs were separated from the sediment samples. All the sediments between the nuclear icebreaker base Atomflot and the open Barents Sea contained 60Co. Traces of 125Sb, 134Cs, 95Zr, 154Eu and 152Eu were also detected in some of the samples. Plutonium levels were low, but the increased 238Pu/239,240Pu ratio at Atomflot indicated a fresh release from the facility or from the waste storage vessels, Lepse and Imandra, lying in front of it. An increased 238Pu/239,240Pu ratio was also found in sediment collected in the outlet of Kola Bay in the Barents Sea. (author)

  16. Petrology of the Plutonic Rocks of west-central Alaska

    Science.gov (United States)

    Miller, Thomas P.

    1970-01-01

    A series of plutons in west-central Alaska defines the Hogatza plutonic belt which extends for about 200 miles in an east-west direction from the northeastern Seward Peninsula to the Koyukuk River. The plutonic rocks have an aggregate area of about 1,200 square miles and their composition, distribution, and possible petrogenesis are discussed for the first time in this report. Field, petrographic and chemical data supported by K/Ar age dating indicate the plutonic rocks are divisible into two suites differing in age, location, and composition. The western plutons are mid-Cretaceous (~100 m.y.) in age and consist of a heterogeneous assemblage of monzonite, syenite, quartz monzonite. Associated with these granitic rocks is a group of alkaline sub-silicic rocks that forma belt of intrusive complexes extending for a distance of at least 180 miles from west-central Alaska to the Bering Sea. The complex at Granite Mountain shows a rare example of zoning from an alkaline rim to a quartz-bearing core. The occurrence of a similar complex at Cape Dezhnev on the easternmost tip of Siberia suggests the alkaline province may extend into Siberia. The easternmost plutons are Late Cretaceous (180 m.y.) in age and composed primarily of granodiorite and quartz monzonite similar to calc-alkaline plutons found throughout the North America Cordillera. The plutons are epizonal and intrude deformed but unmetamorphosed Lower Cretaceous andesitic volcanics and volcanic graywacke which constitute the highly mobile Yukon-Koyukuk volcanogenic province of west-central Alaska. No older rocks have been found within the confines of this vast tract; the occurrence of a bounding ophiolite sequence has lead to the suggestion that the province was formed by large-scale rifting and is underlain by oceanic crust. The possibility of no juvenile sialic crust over much of the area suggests that the potassium-rich magma now represented by the alkaline rocks originated in the mantle. The distribution of the

  17. K-Ar ages of plutonic rocks in the Lassiter Coast area, Antarctica

    Science.gov (United States)

    Mehnert, Harald H.; Rowley, Peter D.; Schmidt, Dwight L.

    1975-01-01

    Numerous middle Cretaceous stocks and small batholiths intruded Middle and Upper Jurassic sedimentary and volcanic rocks in the Lassiter Coast area of the southern Antarctic Peninsula. To establish the age of the quartz diorite and granodiorite plutonic events, five plutons were dated by the K-Ar method. The results indicate a timespan of about 20 m.y. for the emplacement of the plutons and a minimum age of 120 m.y. for the deformation of the sedimentary (Latady Formation) and volcanic rocks. Three of the more silicic plutons have concordant biotite and hornblende ages of 100 and 106 m.y.; two discordant ages of about 118 m.y. were obtained on the more mafic plutons. Petrographically, chemically, and geochronologically, the plutons of the southern to central Lassiter Coast are similar to the calc-alkaline suite of igneous rocks of the Andes of Patagonia, the Antarctic Peninsula, and eastern Ellsworth Land.

  18. Panorama Pluton : a composite gabbro-monzodiorite early Ross Orogeny intrusion in southern Victoria Land, Antarctica

    International Nuclear Information System (INIS)

    The Koettlitz Glacier Alkaline Province of the Walcott Glacier to Radian Glacier area of the Transantarctic Mountains contains a diverse suite of intrusions ranging from gabbro and diorite to granite, nepheline syenite, and carbonatite. Most of the plutons are alkaline (A-type), although the Panorama Pluton is mafic, comprising both hypersthene normative gabbroic and quartz normative monzodioritic lithologies. The pluton has a composite nature, determined by whole-rock geochemical trends and Nd-Sr isotope data that reflect distinctive source regions for the different components. U-Pb geochronology of zircon and titanite indicates the Panorama Pluton was intruded during the early stages of the Neoproterozoic-early Paleozoic Ross Orogeny at 535 ± 9 Ma, and that it is coeval with the geochemically similar Dromedary Mafic Complex which crops out 10 km to the southeast. The Panorama Pluton is a volumetrically minor mafic component of the Koettlitz Glacier Alkaline Province, which predates, by at least 15 m.y., the dominant calc-alkaline suites that occur along-strike in the Dry Valleys area to the north, and the central Transantarctic Mountains to the south. The Panorama Pluton magmas, and other Koettlitz Glacier Alkaline Province lithologies, are interpreted to have formed in an extensional or transtensional jog that predates the onset of widespread Ross Orogeny subduction. (author). 48 refs., 7 figs., 3 tabs

  19. Isotopic character of Cambro-Ordovician plutonism, southern Victoria Land

    International Nuclear Information System (INIS)

    Previous mapping of granitoid rocks in the Dry Valleys area of southern Victoria Land, Antarctica, identified the calc-alkaline (DV1a), adakitic (DV1b), and monzonitic (DV2) suites. A fourth older suite comprising alkaline gabbro, syenite, and A-type granite occurs in the Mt Dromedary area c. 80 km to the south. U-Pb zircon dating of Bonney Pluton, the largest calc-alkaline DV1a intrusion, indicates emplacement of this regional-scale body at 505 +/- 2 Ma. Pb-loss and inherited zircon were common to Bonney Pluton analyses of this study. U-Pb dating of monazite from Valhalla Pluton, a principal DV1b suite adakitic intrusion, indicates emplacement at 488 +/- 2 Ma. The Bonney Pluton age constrains the peak of calc-alkaline plutonism at 505 Ma and the Valhalla Pluton age records the major pulse of adakitic plutonism that is inferred to mark the final stages of subduction c. 490 Ma along this section of the East Antarctic margin. Nd and Sr isotope data for the calc-alkaline DV1a suite and adakitic DV1b suite define distinct ranges for each suite, supporting their subdivision on the basis of field relationships, petrography, and whole-rock geochemistry. Calc-alkaline DV1a suite granite magmas have eNd(T) = -4.2 to -6.1 and Sri = 0.7071-0.7079, whereas the adakitic DV1b suite rocks have a wider range of eNd(T) = -1.9 to -7.2 and Sri = 0.7065-0.7097. The isotopic data suggest a significant mantle component and subordinate crustal component in the source region of both suites. Time-dependent variations in the isotopic ratios of DV1a and DV1b suites imply a progressive increase in the proportion of more radiogenic material in the source region of the granitoid rocks, either mantle- or crust-derived material. Larger adakitic DV1b plutons are more 'evolved' than equivalent, smaller plutons of the same DV1b suite. Vanda Dikes and monzonitic DV2 suite intrusions are characterised by particularly low Sri = 0.7044-0.7067 and near-constant eNd(T) = -4.8 to -5.3, which indicate a

  20. Structural setting and geochemistry of Devonian dikes in the Kola Peninsula

    Science.gov (United States)

    Terekhov, E. N.; Baluev, A. S.; Przhiyalgovsky, E. S.

    2012-01-01

    The structural setting and geochemistry of the Devonian dikes in the Kola Peninsula are considered. The alkaline dikes are controlled by rift- and drift-related structural elements. The first type of structures is exemplified by the Khibiny-Kontozero Fault Zone, which is regarded as a propagation zone of the East Barents Rift. The second type comprises Early Precambrian structural elements reactivated during Devonian drift of the East European Plate. Alkaline dikes occur in the ring structures at the ends of rifts and in the accommodation zones where the polarity of the main fault plane changes. These are the sites of accumulation and abrupt relaxation of tectonic stresses. Despite the significant differences in the petrography and chemistry of alkaline dikes, all of them are enriched in REE, apparently due to the elevated concentrations of these elements in the fluids. The dolerite dikes at the Murmansk Coast are located in the outer zone of the vast, concentrically zoned plateau basalt province with the East Barents Trough as its center. According to geophysical data, basaltic flows are suggested within this trough. The dolerite dikes increase in number in the inland propagation zone of the East Barents Trough extending in the Baltic Shield. The alkaline igneous rocks of the Kola Peninsula were formed under local compression at the periphery of the plateau basalt province.

  1. Coeval Shoshonitic-ultrapotassic dyke emplacements within the Kestanbol Pluton, Ezine – Biga Peninsula (NW Anatolia)

    OpenAIRE

    Akal, Cüneyt

    2013-01-01

    The Biga Peninsula, in the north-western part of Western Anatolia, is part of the Sakarya Zone of the Western Pontides and the tectonically overlying Ezine group. The basement rocks are intruded by the early Miocene Kestanbol Pluton and early to middle Miocene calc-alkaline to shoshonitic-ultrapotassic volcanic successions related to postcollisional continental extension. The Kestanbol Pluton mainly comprises monzonite and granodiorite and is cut by shoshonitic-ultrapotassic tephriphonolite d...

  2. Kola Sami language revitalisation - opportunities and challenges.

    OpenAIRE

    Scheller, Elisabeth

    2013-01-01

    Today, all four Kola Sami languages are seriously endangered by a language shift from Sami to Russian. However, a language revitalisation process has started. Particularly the Kildin Sami language community in Lovozero seems to have the necessary political, financial and practical conditions for being able to carry out an effective language revitalisation, also in terms of a reintroduction of Kildin Sami as an everyday language of communication. But there are also challenges and barr...

  3. Paravinogradovite, (Na,□)2 [(Ti4+, Fe3+)4 {Si2 O6}2 {Si3 Al O10} (OH)4] H2O, a new mineral species for the Khibina alkaline massif, Kola Peninsula, Russia: description and crystal structure

    International Nuclear Information System (INIS)

    Paravinogradovite is a new mineral species from Mount Kukisvumchorr, Khibina alkaline massif, Kola Peninsula, Russia. Paravinogradovite forms prismatic crystals elongate along [100] and up to 0.5-1.0cm long; crystals in some cases occur in fan-shaped aggregates sporadically scattered throughout a matrix of feldspar, nepheline and natrolite in a strongly mineralized nepheline-feldspar pegmatite. Associated minerals are nepheline, K-feldspar, albite, analcime, natrolite, aegirine, biotite, chlorite, zircon, ilmenite, pyrochlore, ancylite-(Ce), nordstrandite, carbonate-fluorapatite, fluorite, galena and cerussite. Crystals of paravinogradovite are colorless to white, with a white streak and a luster that varies from vitreous to pearly. The mineral is translucent to transparent, and shows weak yellow-green fluorescence under 240-400 nm ultraviolet radiation. Paravinogradovite has a perfect cleavage on {001} and an indistinct cleavage on {010}. It is brittle, has a splintery fracture and a Mohs hardness of 5. Its observed and calculated densities are 2.77(2) and 2.76 g/cm3, respectively. It is biaxial negative with α 1.707(2), β 1.741(2), γ 1.755(2), 2V(obs.) = 64(1)o, 2V(calc.) = 64o, nonpleochroic with dispersion r> v, with Z ∼ b, X Λα 30o. Paravinogradovite is triclinic, space group P1, a 5.2533(1), b 8.7411(3), c 12.9480(5) Angstroem, α 70.466(1), β 78.472(1), γ 89.932(1)o, V547.65(5) )Angstroem, Z = 1. The strongest seven lines in the X-ray powder-diffraction pattern [d in Angstroem(I)((hkl)] are: 3.182(100)(0 13,014), 5.88(65)(011,012), 11.9(58)(001), 4.35 (38)(021,102), 5.98(35)(002), 3.085(29)(123) and 2.735(21)(122). Chemical analysis by electron microprobe gave SiO2 43.54, A12O3 6.12, Fe2O3 4.11, Nb2O5 0.50, TiO2 29.59, BeO 0.76, MgO 0.13, Na2O 7.77, K2O 0.87, H2O 6.23, sum 99.62 wt.%, where the amount of Be and the amount of H2O were determined by crystal-structure analysis, and the valence state of Fe was determined by Moessbauer spectroscopy. The

  4. Cell-zonal textures of tinguaites from the Kola Peninsula

    Science.gov (United States)

    Voitsekhovsky, Y. L.; Shpachenko, A. K.; Skiba, V. I.

    Textures of tinguaite dykes cutting the alkaline Khibiny massif in the Kola Peninsula, Russia, are described. They are characterized by a combination of a fractal microfracture network dividing rock into pencil-like cells and of a concentric rhythmical zonation in almost all of them. The latter is formed by interchange of volatile-enriched and volatile-depleted mineral zones. The location of the textures only where dykes contact host khibinites appears to point out the contraction nature of the microfracture network. The cooling time calculated agrees well with this hypothesis. The zonation appears to have arisen through autometamorphic processes with two main competing factors, namely (a) overall cooling of the system and (b) periodic depletion of it in some elements, mainly Na and K. Another mechanism which may be applied to explain the zonation is the known Marangoni Instability effect at the early stage of evolution of the volatile-saturated phonolite melt. Thus, tinguaite textures are caused by nonspecific influences external to the system and may be regarded as an example of self-organization in nature.

  5. Geochemistry and geochronology of the volcano-plutonic rocks associated with the Glojeh epithermal gold mineralization, NW Iran

    OpenAIRE

    Siani Majid Ghasemi; Mehrabi Behzad; Azizi Hossein; Wilkinson Camilla Maya; Ganerød Morgan

    2015-01-01

    Eocene to Oligocene volcano-plutonic rocks are widespread throughout NW Iran. The Tarom-Hashtjin metallogenic province is one of the most promising epithermal-porphyry ore mineralized districts in NW Iran. The Glojeh gold deposit, located in the center of this province, is a typical high to intermediate sulfidation epithermal system, spatially and temporally associated with a granite intrusion and associated high-K calc-alkaline to shoshonitic volcano-plutonic rocks. T...

  6. Definition of magmatic suites in ediacaran bodies of the NE Province Borborema (State of Rio Grande do Norte: Pitombeira, Taipu and Gameleira Plutons

    Directory of Open Access Journals (Sweden)

    Maria Tatiany Duarte de Oliveira

    2014-12-01

    Full Text Available The Pitombeira, Taipu and Gameleira plutons, located in the northeasternmost portion of the São José do Campestre Domain within the Borborema Province (NE, Brazil, are subjects of lithogeochemical studies in the present work. The Pitombeira Pluton comprises a monzo- to syenogranitic facies defined by K-feldspar phenocrysts, and a quartz-dioritic to tonalitic facies, mainly as enclaves, with laths of plagioclase showing compositional zoning and chilled rims. The Taipu Pluton is made of equigranular, locally porphyritic, monzo- to syenogranites, whereas the Gamaleira Pluton encompasses tonalitic and grano- dioritic rocks with porphyritic textures and compositionally zoned plagioclase crystals. Geochemical discriminant diagrams reveal that the rocks forming the Gameleira Pluton are metaluminous, with a calc-alkaline signature and magnesian character, contrasting with the subalkaline (high-K calc-alkaline signature and ferroan character of the Taipu and Pitombeira Plutons, where the former is highly peraluminous and the latter is metaluminous to slightly peraluminous. Rare Earth Elements patterns are similar to all plutons and register negative Eu anomalies and a relative enrichment of LREE over HREE, with LaN/YbN ratios between 9.38 to 16.20 (Gamaleira Pluton, 17.99 to 31.39 (granitic facies of the Pitombeira Pluton, 14.15 to 21.81 (dioritic facies of the Pitombeira Pluton and 15.17 to 175.41 (Taipu Pluton. Based on the combined investigation of structural, textural and geochemical data, a late- to post-collisional tectonic environment is suggested for the plutons here studied.

  7. The Study of enclaves and relative age of plutonic bodies in the Alvand Plutonic complex

    International Nuclear Information System (INIS)

    The study of enclaves and field observations indicate that: The Alvand plutonic complex comprise several plutonic phases with sharp contact and different ages. The older plutonic rocks are composed of gabbro, diorite and tonalites. The porphyroid granites were formed at least in two phases and they are younger than gabbros, diorites and tonalites. The hololeucocratic granitoids were also formed in two phases and they are the youngest plutonic phase in the Alvand plutonic complex. The granitic rocks are magmatic and they are not metasomatic in origin. The porphyroid granites (monzogranites and granodiorites) are S-type (Anatexites). According to radiometric ages and relative ages we believe that mafic plutonism have occurred during pre-middle Cretaceous to Paleocene ages and felsic plutonism have occurred during middle Cretaceouc to Paleocene ages

  8. Possibilities for wind energy on the Kola peninsula

    Energy Technology Data Exchange (ETDEWEB)

    Wolff, J.; Rathmann, O.; Lundsager, P. [and others

    1999-03-01

    This paper presents an extensive feasibility study regarding the introduction of wind energy in the energy supply of the Kola peninsula in north-western Russia that was carried out during 1996-97. The study covers as well grid connected wind turbines as autonomous systems and a wind atlas was prepared. Special emphasis is put on non-technical activities and objectives like financing models, international funding and a sound politic support. The wind resources on the Kola peninsula are excellent and there are still no reasons to why wind energy installations couldn`t be carried out successfully. Recommendations for starting this development are presented. (au)

  9. Genesis of Felsic Plutonic Magmas and Their Igneous Enclaves

    DEFF Research Database (Denmark)

    Clemens, John D.; Maas, Roland; Waight, Tod Earle;

    2016-01-01

    -type Pyalong pluton was emplaced, apparently along an east-west-orientated fracture zone. Around 367 Ma, the main I-type Baynton pluton intruded as numerous shallow-dipping sheets. The last plutonic event was the intrusion of the broad, thin, flat-lying, and crosscutting sheet of the I-type Beauvallet pluton...

  10. Zircon LA-ICPMS study and petrogenesis simulation of Dahuabei pluton in the Wulashan area,Inner Mongolia

    Institute of Scientific and Technical Information of China (English)

    Dapeng Li; Yuelong Chen; Liemeng Chen; Zhong Wang; Jinbao Liu

    2009-01-01

    Dahuabei pluton in the Wulashan area,Inner Mongolia,is an alkaline and peraluminous granitic pluton.LA-ICPMS U-Pb dating of zircons indicates that this pluton crystallized at 330±10 Myr.The pluton did not experience apparent zircon fractionation.The consistent temperatures between Zr saturation (765℃) and the average zircon-rutile Ti equilibrium (780℃),together with zircon ages and their CL images,indicated that there were no inherited zircons in this pluton.Through the simulation of the dry-system crystallization process of magma cooling at 200 MPa and 1100-709℃,the phase diagram and composition evolution tendency of different phases were obtained.The magma reached its liquidus at 1069℃.Sanidine was the first crystallized phase;at 709℃ the residual magma was less than 4%,and the range of 1069-719℃ should be the most suitable approach to the real condition.It is shown that at least some part of the pluton underwent such isobaric equilibrium crystallization processes during its crystallization.

  11. Clinical effects of Garcinia kola in knee osteoarthritis

    OpenAIRE

    Oyelami Oyesiku A; Okimi Oluwakemi C; Idowu Thomas O; Adesanya Saburi A; Adegbehingbe Olayinka O; Iwalewa Ezekiel O

    2008-01-01

    Abstract Objectives Over the past years, there has been a growing number of knee osteoarthritis (KOA) patients who are not willing to comply with long-term non-steroidal anti-inflammatory drugs (NSAID) treatment and wish to use herbal anti- rheumatic medicine. This study assessed the clinical effects of Garcinia kola (GK) in KOA patients. Patients and methods Prospective randomized, placebo controlled, double blind, clinical trial approved by the institutional medical ethics review board and ...

  12. Results of storm activity registration in the Kola Peninsula

    Directory of Open Access Journals (Sweden)

    Burtsev A. V.

    2015-12-01

    Full Text Available Results of storm activity registration processing in the Kola Peninsula during 2013-2014 have been given. Considerable fluctuations of storm activity and unevenness of lightning discharges distribution across the region territory have been noted. It has been proposed to use a cloud-to-ground discharge density indicator taking into account their distribution in the region at an assessment of lightning protection efficiency of power generation facilities in areas with low thunder-storms intensity

  13. Marketingový mix firmy ALU KOLA CB

    OpenAIRE

    Urban, Karel

    2011-01-01

    This bachelor thesis is focused on a marketing mix practical application in my own company ALU KOLA CB. My company sells alloy wheels and tyres for personal cars. In a literary review are introduced and explained terms marketing, marketing mix and its parts - product, price, place and promotion. In a practical part of this thesis are these terms applied on my company. The end of this part contains results and improvement suggestions.

  14. Petrology and radiogeology of the Stripa pluton

    International Nuclear Information System (INIS)

    Both the quartz monzonite and the metavolcanic leptite which it intruded are strongly fractured. Two stages of fracture filling are evident; an earlier stage encompassing quartz, sericite, feldspar, epidote, and chlorite, and a later stage dominated by carbonate minerals. The Stripa quartz monozite is chemically and mineralogically distinct from other plutons in the region. Muscovite is the predominant mica in the quartz monzonite; biotite has been altered to chlorite, hornblende is absent, and accessory minerals are scarce. In contrast, in other plutons in the Stripa region, biotite and hornblende are prominent mafic minerals and accessory minerals are abundant. The Stripa quartz monzonite is also considerably more radioactive than the the leptite and other plutons in the region. Uranium and thorium abundances are both approx. 30 ppM, considerably higher than in normal granitic rocks where the thorium-to-uranium ratio generally exceeds 2. Potassium-argon dating of muscovite from the Stripa quartz monzonite indicates that this rock may be older, at 1691 million years than granitic rock of the neighboring Gusselby and Kloten massifs, whose ages, based on K-Ar dating of biotite, are respectively 1604 and 1640 m.y. Heat flow and heat productivity considerations show that although Stripa quartz monzonite contains high abundances of radioelements, the pluton has little efect on the regional heat flow. If it occurs in a layered plutonic setting, it is not more than 1.5 km thick; otherwise it may comprise a stock, dike, or border phase that is relatively small compared with the large granitic plutons exposed in the region

  15. Petrology and radiogeology of the Stripa pluton

    Energy Technology Data Exchange (ETDEWEB)

    Wollenberg, H.; Flexser, S.; Andersson, L.

    1980-12-01

    Both the quartz monzonite and the metavolcanic leptite which it intruded are strongly fractured. Two stages of fracture filling are evident; an earlier stage encompassing quartz, sericite, feldspar, epidote, and chlorite, and a later stage dominated by carbonate minerals. The Stripa quartz monozite is chemically and mineralogically distinct from other plutons in the region. Muscovite is the predominant mica in the quartz monzonite; biotite has been altered to chlorite, hornblende is absent, and accessory minerals are scarce. In contrast, in other plutons in the Stripa region, biotite and hornblende are prominent mafic minerals and accessory minerals are abundant. The Stripa quartz monzonite is also considerably more radioactive than the the leptite and other plutons in the region. Uranium and thorium abundances are both approx. 30 ppM, considerably higher than in normal granitic rocks where the thorium-to-uranium ratio generally exceeds 2. Potassium-argon dating of muscovite from the Stripa quartz monzonite indicates that this rock may be older, at 1691 million years than granitic rock of the neighboring Gusselby and Kloten massifs, whose ages, based on K-Ar dating of biotite, are respectively 1604 and 1640 m.y. Heat flow and heat productivity considerations show that although Stripa quartz monzonite contains high abundances of radioelements, the pluton has little efect on the regional heat flow. If it occurs in a layered plutonic setting, it is not more than 1.5 km thick; otherwise it may comprise a stock, dike, or border phase that is relatively small compared with the large granitic plutons exposed in the region.

  16. Geochemistry of Mesozoic plutons, southern Death Valley region, California: Insights into the origin of Cordilleran interior magmatism

    Science.gov (United States)

    Ramo, O.T.; Calzia, J.P.; Kosunen, P.J.

    2002-01-01

    Mesozoic granitoid plutons in the southern Death Valley region of southeastern California reveal substantial compositional and isotopic diversity for Mesozoic magmatism in the southwestern US Cordillera. Jurassic plutons of the region are mainly calc-alkaline mafic granodiorites with ??Ndi of -5 to -16, 87Sr/86Sri of 0.707-0.726, and 206Pb/204Pbi of 17.5-20.0. Cretaceous granitoids of the region are mainly monzogranites with ??Ndi of -6 to -19, 87Sr/86Sri of 0.707-0.723, and 206Pb/204Pbi of 17.4-18.6. The granitoids were generated by mixing of mantle-derived mafic melts and pre-existing crust - some of the Cretaceous plutons represent melting of Paleoproterozoic crust that, in the southern Death Valley region, is exceptionally heterogeneous. A Cretaceous gabbro on the southern flank of the region has an unuasually juvenile composition (??Ndi -3.2, 87Sr/86Sri 0.7060). Geographic position of the Mesozoic plutons and comparison with Cordillera plutonism in the Mojave Desert show that the Precambrian lithosphere (craton margin) in the eastern Mojave Desert region may consists of two crustal blocks separated by a more juvenile terrane.

  17. The status of nuclear cooperation with Kola and Leningrad nuclear power plant; Status for atomsikkerhetssamarbeidet med Kola og Leningrad kjernekraftverk

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-11-01

    Norway has since 1993 participated in joint projects with Russia to improve nuclear safety at the Kola and Leningrad nuclear power plant. The project have been funded under the Government's nuclear action under the leadership of the Ministry of Foreign Affairs. Institute for Energy Technology (IFE) has completed most of the projects. NRPA is the authority responsible for assessing the implementation of the projects. (eb)

  18. Multiphase groundwater flow near cooling plutons

    Science.gov (United States)

    Hayba, D.O.; Ingebritsen, S.E.

    1997-01-01

    We investigate groundwater flow near cooling plutons with a computer program that can model multiphase flow, temperatures up to 1200??C, thermal pressurization, and temperature-dependent rock properties. A series of experiments examines the effects of host-rock permeability, size and depth of pluton emplacement, single versus multiple intrusions, the influence of a caprock, and the impact of topographically driven groundwater flow. We also reproduce and evaluate some of the pioneering numerical experiments on flow around plutons. Host-rock permeability is the principal factor influencing fluid circulation and heat transfer in hydrothermal systems. The hottest and most steam-rich systems develop where permeability is of the order of 10-15 m2. Temperatures and life spans of systems decrease with increasing permeability. Conduction-dominated systems, in which permeabilities are ???10-16m2, persist longer but exhibit relatively modest increases in near-surface temperatures relative to ambient conditions. Pluton size, emplacement depth, and initial thermal conditions have less influence on hydrothermal circulation patterns but affect the extent of boiling and duration of hydrothermal systems. Topographically driven groundwater flow can significantly alter hydrothermal circulation; however, a low-permeability caprock effectively decouples the topographically and density-driven systems and stabilizes the mixing interface between them thereby defining a likely ore-forming environment.

  19. Petrology and radiogeology of the Stripa pluton

    Energy Technology Data Exchange (ETDEWEB)

    Wollenberg, Harold; Flexser, Steve; Andersson, Lennart

    1980-12-01

    To better define the character of the rock encompassing the thermomechanical and hydrological experiments at the Stripa mine in central Sweden, and to help determine the size of the Stripa pluton, detailed studies were conducted of the petrology and radiogeology of the quartz monzonite and adjacent rocks. Petrologic studies emphasized optical petrography, with supplementary X-ray diffraction, X-ray fluorescence and microprobe analyses. Radiogeologic investigations were based primarily on surface and underground gamma-ray spectrometric measurements of uranium, thorium and potassium, supplemented by laboratory gamma spectrometric analyses and fission-track radiographic determinations of the locations and abundance of uranium in the rock matrix. Both the quartz monzonite and the metavolcanic leptite which it intruded are strongly fractured. Two stages of fracture filling are evident; an earlier stage encompassing quartz, sericite, feldspar, epidote, and chlorite, and a later stage dominated by carbonate minerals. The Stripa quartz monzonite is chemically and mineralogically distinct from other plutons in the region. Muscovite is the predominant mica in the quartz monzonite; biotite has been altered to chlorite, hornblende is absent, and accessory minerals are scarce. In contrast, in other plutons in the Stripa region biotite and hornblende are prominent mafic minerals and accessory minerals are abundant. The Stripa quartz monzonite is also considerably more radioactive than the leptite and other plutons in the region. Uranium and thorium abundances are both- 30 ppm, considerably higher than in "normal" granitic rocks where the thorium-to-uranium ratio generally exceeds 2. Potassium-argon dating of muscovite from the Stripa quartz monzonite indicates that this rock may be older, at 1691 million years than granitic rock of the neighboring Gusselby and Kloten massifs, whose ages, based on K-Ar dating of biotite, are respectively 1604 and 1640 m.y. Heat flow and heat

  20. Evaluation of Hypoglycemic and Antioxidative Properties of Aqueous Extract of Garcinia kola Seeds in Wistar Rats

    OpenAIRE

    Omage Kingsley; Erifeta O. Georgina; Uhunmwangho S. Esosa; Josiah J. Sunday; Ajeigbe O. Kazeem

    2011-01-01

    The effects of aqueous extract of Garcinia kola seed on glucose, superoxide dismutase catalase and malondialdehyde of normal rats were investigated. Oral administration of aqueous seed extract of Garcinia kola at a concentration of 200 mg/kg body weight, over a period of 21 days, significantly (p

  1. A refinement of the emission data for Kola Peninsula based on inverse dispersion modelling

    NARCIS (Netherlands)

    Prank, M.; Sofiev, M.; Denier Van Der Gon, H.A.C.; Kaasik, M.; Ruuskanen, T.M.; Kukkonen, J.

    2010-01-01

    The study reviews the emission estimates of sulphur oxides (SOx) and primary particulate matter (PM) from the major industrial sources of Kola Peninsula. Analysis of the disagreements between the existing emission inventories for the Kola region combined with forward and inverse ensemble dispersion

  2. Model of formation of the Khibiny-Lovozero ore-bearing volcanic-plutonic complex

    Science.gov (United States)

    Arzamastsev, A. A.; Arzamastseva, L. V.; Zhirova, A. M.; Glaznev, V. N.

    2013-09-01

    The paper presents the results of a study of the large Paleozoic ore-magmatic system in the northeastern Fennoscandian Shield comprising the Khibiny and Lovozero plutons, the Kurga intrusion, volcanic rocks, and numerous alkaline dike swarms. As follows from the results of deep drilling and 3D geophysical simulation, large bodies of rocks pertaining to the ultramafic alkaline complex occur at the lower level of the ore-magmatic system. Peridotite, pyroxenite, melilitolite, melteigite, and ijolite occupy more than 50 vol % of the volcanic-plutonic complex within the upper 15 km accessible to gravity exploration. The proposed model represents the ore-magmatic system as a conjugate network of mantle magmatic sources localized at different depth levels and periodically supplying the melts belonging to the two autonomous groups: (1) ultramafic alkaline rocks with carbonatites and (2) alkali syenites-peralkaline syenites, which were formed synchronously having a common system of outlet conduits. With allowance for the available isotopic datings and new geochronological evidence, the duration of complex formation beginning from supply of the first batches of melt into calderas and up to postmagmatic events, expressed in formation of late pegmatoids, was no less than 25 Ma.

  3. ALKALINE VOLCANISM IN THE KOLA PENINSULA, RUSSIA: PALEOZOIC KHIBINY, LOVOZERO AND KONTOZERO CALDERAS

    OpenAIRE

    Арзамасцев, Андрей; Петровский, Михаил

    2012-01-01

    Представлены результаты изучения палеозойских вулканических серий Кольской провинции, распространенных в районах Ловозера, Хибин, Контозера и Ивановского вулкано-плутонического комплекса. Особенностью вулканитов является присутствие умеренно щелочных базанитов наряду с недонасыщенными кремнеземом щелочными ассоциациями. Все породы значительно обогащены некогерентными элементами: содержания Rb, Ba, Sr, Zr, Nb, Y в вулканитах ловозерской и контозерской свит значительно превышают таковые в щелоч...

  4. Magma Interaction Processes Inferred from Fe-Ti Oxide Compositions in the Dölek and Sarıçiçek Plutons, Eastern Turkey

    OpenAIRE

    KARSLI, ORHAN; Aydin, Faruk; SADIKLAR, İBRAHİM UYSAL & M. BURHAN

    2008-01-01

    Magnetite-ulvöspinel and ilmenite-hematite solid solution intergrowths from the high-K calc-alkaline Dölek and Sarıçiçek plutons, Eastern Turkey, were investigated using microprobe analyses. Compositions of twenty-eight samples from the host rocks and their enclaves in the plutons were used to estimate the oxygen fugacity and temperature. The ilmenite and ulvöspinel component exsolves out along certain preferred crystallographic planes in the titanomagnetite of the host rocks, while they are ...

  5. User experiences using the operator support systems SCORPIO and SPDS at Kola NPP

    International Nuclear Information System (INIS)

    Full text: During the years from 2000 to 2004 a Safety Parameter Display System (SPDS) and a SCORPIO-VVER system have been installed and put into operation at Kola NPP in northern Russia. The projects have been carried out in co-operation with Finnish and Russian subcontractors with IFE, Halden, as the main contractor and the project manager. Both projects have been defined within the Norwegian Assistance Programme to Nuclear Installations at the Kola Peninsula and financed by the Norwegian government. The SPDS project has also been partly financed by the Finnish government. The Kola SPDS, which is based on a system originally developed for the Loviisa Nuclear Power Plant in Finland, was installed and put into operation on Kola NPP units 1 and 2 in April 2000 and on Kola NPP units 3 and 4 in March 2004. The system has been licensed and approved by Russian authority (GAN) for use in the control room environment. The SCORPIO-VVER system is based on the SCORPIO-VVER framework developed for Dukovany NPP, Czech Republic and Bohunice NPP, Slovak Republic. Further, the experience gained with the SCORPIO framework developed for Western PWRs have been utilised. The SCORPIO-VVER system was installed and put into operation at Kola NPP Nuclear Safety Centre in December 2003 for core monitoring on units 3 and 4. The user experiences by introducing the SPDS and the SCORPIO-VVER system at Kola NPP are so far very positive. By introducing an SPDS at Kola NPP, the process safety status (single or combinations of signals) is presented for the operator in a centralized location (on one screen) in the control room and in a form that makes it easier to obtain a quick assessment of the process safety status. According to feedback from control room personnel the SPDS has enhanced the monitoring of the safety status of the plant. The reactor core is the most central component of a nuclear power plant and a comprehensive core monitoring system is very important for maintaining reactor

  6. Correct nomenclature for the Angadimogar pluton, Kerala, southwestern India

    Indian Academy of Sciences (India)

    H M Rajesh

    2006-04-01

    The proper usage of modal composition and geochemical classification of granitoids is discussed for assigning a proper nomenclature for the Angadimogar pluton,Kerala,southwestern India.This discussion is mainly aimed at addressing questions concerning the nomenclature of Angadimogar pluton (syenite vs. granite).Modal composition and whole-rock XRD data clearly show that the pluton exposed near Angadimogar is a quartz-syenite and its geochemistry is typical of a ferroan, metaluminous,alkali (A-type)granitoid.

  7. The Precambrian/Lower Cambrian pluton from Vila Nova (Central Portugal)

    Energy Technology Data Exchange (ETDEWEB)

    Reis, A. I. M.; Silva, M. M. V. G.; Antunes, I. M. H. R.

    2010-07-01

    The Vila Nova pluton is a small, Pre-Variscan granitic body that intruded rocks of the Central Iberian Zone near the contact with the Ossa Morena Zone and is affected by several shear zones and faults. Its contact metamorphic aureole is constituted by micaschist with porphyroblasts in the outer zone and hornfels in the inner zone. Small mainstreamed xenoliths are dispersed all over the body. The pluton has a great mineralogical heterogeneity with pronounced variations in muscovite/biotite and plagioclase/ microcline contents and is classified as granite, granodiorite or tonalite. It is a leuco granite, highly peraluminous (A/CN K = 1.31 - 1.64), magnesian and calc-alkaline to alkaline-calcic. The variation diagrams show curvilinear trends with silica. Eu/Eu* = 0.47 - 0.77 and there is a slight enrichment in LREE relative to HREE. The normalized diagrams indicated dominantly crustal granite, related to subduction. U-Pb isotopic data of zircon and monazite gives 540-542 Ma age. (Author) 19 refs.

  8. Petrological studies of plutonic rocks of Ecuador

    International Nuclear Information System (INIS)

    The feldspars of many tonalitic plutonic rocks in the coastal regions and West Andean regions are zoned. This leads to the conclusion that they are relatively flat intrusions and to some extent transition rocks in the subvulcanite direction. This is in accordance with the genetic and chronological relationship between plutonites and the surrounding vulcanites of the Basic Igreous Complex (BIC). The composition of representative minerals, e.g. alkali feldspar, plagioclase feldspar, biotite, chlorite, and amphibole has been determined as well as the age of plutonite samples by the K/Ar dating method. (DG)

  9. MEASUREMENTS OF THE CONFINEMENT LEAKTIGHTNESS AT THE KOLA NUCLEAR POWER STATION (UNIT 2) IN RUSSIA

    Energy Technology Data Exchange (ETDEWEB)

    GREENE,G.A.; GUPPY,J.G.

    1998-08-01

    This is the final report on the INSP project entitled, ``Kola Confinement Leaktightness'' conducted by BNL under the authorization of Project Work Plan WBS 1.2.2.1. This project was initiated in February 1993 to assist the Russians to reduce risks associated with the continued operation of older Soviet-designed nuclear power plants, specifically the Kola VVER-440/230 Units 1 and 2, through upgrades in the confinement performance to reduce the uncontrolled leakage rate. The major technical objective of this-project was to improve the leaktightness of the Kola NPP VVER confinement boundaries, through the application of a variety of sealants to penetrations, doors and hatches, seams and surfaces, to the extent that current technology permitted. A related objective was the transfer, through training of Russian staff, of the materials application procedures to the staff of the Kola NPP. This project was part of an overall approach to minimizing uncontrolled releases from the Kola NPP VVER440/230s in the event of a serious accident, and to thereby significantly mitigate the consequences of such an accident. The US provided materials, application technology, and applications equipment for application of sealant materials, surface coatings, potting materials and gaskets, to improve the confinement leaktightness of the Kola VVER-440/23Os. The US provided for training of Russian personnel in the applications technology.

  10. MEASUREMENTS OF THE CONFINEMENT LEAKTIGHTNESS AT THE KOLA NUCLEAR POWER STATION (UNIT 2) IN RUSSIA

    International Nuclear Information System (INIS)

    This is the final report on the INSP project entitled, ''Kola Confinement Leaktightness'' conducted by BNL under the authorization of Project Work Plan WBS 1.2.2.1. This project was initiated in February 1993 to assist the Russians to reduce risks associated with the continued operation of older Soviet-designed nuclear power plants, specifically the Kola VVER-440/230 Units 1 and 2, through upgrades in the confinement performance to reduce the uncontrolled leakage rate. The major technical objective of this-project was to improve the leaktightness of the Kola NPP VVER confinement boundaries, through the application of a variety of sealants to penetrations, doors and hatches, seams and surfaces, to the extent that current technology permitted. A related objective was the transfer, through training of Russian staff, of the materials application procedures to the staff of the Kola NPP. This project was part of an overall approach to minimizing uncontrolled releases from the Kola NPP VVER440/230s in the event of a serious accident, and to thereby significantly mitigate the consequences of such an accident. The US provided materials, application technology, and applications equipment for application of sealant materials, surface coatings, potting materials and gaskets, to improve the confinement leaktightness of the Kola VVER-440/23Os. The US provided for training of Russian personnel in the applications technology

  11. Zircon U-Pb age, Lu-Hf isotope, mineral chemistry and geochemistry of Sundamalai peralkaline pluton from the Salem Block, southern India: Implications for Cryogenian adakite-like magmatism in an aborted-rift

    Science.gov (United States)

    Renjith, M. L.; Santosh, M.; Li, Tang; Satyanarayanan, M.; Korakoppa, M. M.; Tsunogae, T.; Subba Rao, D. V.; Kesav Krishna, A.; Nirmal Charan, S.

    2016-01-01

    The Sundamalai peralkaline pluton is one among the Cryogenian alkaline plutons occurring in the Dharmapuri Rift Zone (DRZ) of the Salem Block in the Southern Granulite Terrane (SGT) of India. Here we present zircon U-Pb age and Lu-Hf isotopic composition, mineral chemistry and geochemistry of the pluton to explore the petrogenesis and geodynamic implications. Systematic modal variation of orthoclase, Na-plagioclase, Ca-amphibole (ferro-edenite and hastingsite) and quartz developed quartz-monzonite and granite litho units in the Sundamalai pluton. Thermometry based on amphibole-plagioclase pair suggests that the pluton was emplaced and solidified at around 4.6 kbar pressure with crystallization of the major phases between 748 and 661 °C. Estimated saturation temperature of zircon (712-698 °C) is also well within this range. However, apatite saturation occurred at higher temperatures between 835 and 870 °C, in contrast with monazite saturation (718-613 °C) that continued up to the late stage of crystallization. Estimated oxygen fugacity values (log fO2: -14 to -17) indicate high oxidation state for the magma that stabilized titanite and magnetite. The magmatic zircons from Sundamalai pluton yielded a weighted mean 206Pb/238U age of 832.6 ± 3.2 Ma. Geochemically, the Sundamalai rocks are high-K to shoshonitic, persodic (Na2O/K2O ratio > 1), silica-saturated (SiO2:65-72 wt.%), and peralkaline in composition (aluminum saturation index, ASI aborted rifting along the DRZ generating the magma that crystallized the Sundamalai rocks. Age of this pluton is comparable with that of the other Cryogenian felsic alkaline plutons from Salem Block suggesting extensive rift-related magmatism at this time in the SGT.

  12. Discrimination of alkalinity in granitoid Rocks: A potential TIMS application

    Science.gov (United States)

    Ruff, Steven W.

    1995-01-01

    In mineral exploration, the ability to distinguish and map petrochemical variations of magmatic rocks can be a useful reconnaissance tool. Alkalinity is one such petrochemical parameter and is used in the characterization of granitoid rocks. In quartz normative plutonic rocks, alkalinity is related to the composition and abundance of feldspars. Together with quartz abundance, knowledge of feldspar modes allows the classification of these igneous rocks according to the Streckeisen diagram. Alternative classification schemes rely on whole rock geochemistry instead of mineral identifications. The relative ease of obtaining whole rock analyses means that geochemical classifications tend to be favored in exploration geology. But the technique of thermal infrared spectroscopy of rocks yields information on mineralogy and is one that can be applied remotely. The goal of the current work then is to establish whether data from TIMS can be used to distinguish the mineralogical variations that relate to alkalinity. An ideal opportunity to test this thesis arises from the work presented in a paper by Dewitt (1989). This paper contains the results of mapping and analysis of Proterozoic plutonic rocks in north-central Arizona. The map resulting from this work delineates plutons according to alkalinity in an effort to establish a trend or polarity in the regional magmatism. Also contained within this paper are brief descriptions of the mineralogy of half of the region's plutons. This combination of mineralogical and geochemical information was the rationale behind choosing this area as a site for TIMS over flights. A portion of the region centered on the northern Bradshaw Mountains was selected because it contains plutons of all three alkalinity classifications (alkali-calcic, calc-alkalic, and calic) present on DeWitt's map within a relatively small area. The site was flown in August of 1994 and the data received a few days before the writing of this manuscript. Most of this

  13. Kola Nut and Conflict Resolution Among the Igala People of Kogi State, Nigeria

    Directory of Open Access Journals (Sweden)

    Joel Abah

    2016-04-01

    Full Text Available This paper examined Kola nut and Conflict Resolution among the Igala people of Kogi State, Nigeria. In a world ravaged by conflicts, certain Africans have kept the fire of brotherhood, through the breaking and eating of Kola nut. Literatures exist on Conflict Resolution, but no empirical study on the topic in question. The aims are to examine (a the types of Kola nut cotyledons and its relevance in conflict resolution (b the myths about Kola nut that enhances conflict resolution, and (c its role in conflict resolution. The qualitative approach was adopted. The sources of data were primary and secondary. The Primary Sources included 20 oral interviews. Purposive sampling was adopted. Content analysis was used to analyse. The secondary sources included books and an unpublished work. The findings reveal (a two types of Kola nut, (cola acuminata 0-7 cotyledons and cola nitida 2 cotyledons, (b As regards the myth, it is used to invite and welcome the ancestors during conflict resolution, whosoever harbours grudges against a neighbour after the kola had been eaten will come under the wrath of the ancestors, and (c It is the harbinger of peace. In conclusion, peace can only be guaranteed when there is security and justice, which could be embedded in a unifying factor(s, like the kola nut. Any community that finds this generally acceptable factor will experience a considerable level of peace, especially when acculturated into every aspect of the modern conflict resolution mechanisms, putting into consideration the indigenous socio-religious conflict resolution strategies.

  14. Petrophysical and geochemical characterization of the late-variscan Santa Eulália Plutonic Complex (Ossa-Morena Zone, Portugal)

    OpenAIRE

    Sant'Ovaia, Helena; Lopes, José Carrilho; Nogueira, Pedro; Gomes, Celeste; Cruz, Cláudia; Machado, Joana

    2012-01-01

    The Santa Eulália Plutonic Complex (SEPC) is a calc-alkaline granitic body located in the northern part of the Ossa Morena Zone, composed by a medium- to coarse-grained pink granite (G0 group) involving large elongated masses of mafic (gabbroic) to intermediate (granodioritic) rocks, M group, and a central gray monzonitic granite (G1 group) which present dominant medium granular facies. A multidisciplinary study, including petrophysical, AMS and IRM measurements, and geochemical d...

  15. Intrusive rocks and plutonic belts of southeastern Alaska, U.S.A.

    Science.gov (United States)

    Brew, David A.; Morrell, Robert P.

    1983-01-01

    About 30 percent of the 175,000-km2 area of southeastern Alaska is underlain by intrusive igneous rocks. Compilation of available information on the distribution, composition, and ages of these rocks indicates the presence of six major and six minor plutonic belts. From west to east, the major belts are: the Fairweather-Baranof belt of early to mid-Tertiary granodiorite; the Muir-Chichagof belt of mid-Cretaceous tonalite and granodiorite; the Admiralty-Revillagigedo belt of porphyritic granodiorite, quartz diorite, and diorite of probable Cretaceous age; the Klukwan-Duke belt of concentrically zoned or Alaskan-type ultramafic-mafic plutons of mid-Cretaceous age within the Admiralty-Revillagigedo belt; the Coast Plutonic Complex sill belt of tonalite of unknown, but perhaps mid-Cretaceous, age; and the Coast Plutonic Complex belt I of early to mid-Tertiary granodiorite and quartz monzonite. The minor belts are distributed as follows: the Glacier Bay belt of Cretaceous and(or) Tertiary granodiorite, tonalite, and quartz diorite lies within the Fair-weather-Baranof belt; layered gabbro complexes of inferred mid-Tertiary age lie within and are probably related to the Fairweather-Baranof belt; the Chilkat-Chichagof belt of Jurassic granodiorite and tonalite lies within the Muir-Chichagof belt; the Sitkoh Bay alkaline, the Kendrick Bay pyroxenite to quartz monzonite, and the Annette and Cape Fox trondhjemite plutons, all interpreted to be of Ordovician(?) age, together form the crude southern southeastern Alaska belt within the Muir-Chichagof belt; the Kuiu-Etolin mid-Tertiary belt of volcanic and plutonic rocks extends from the Muir-Chichagof belt eastward into the Admiralty-Revillagigedo belt; and the Behm Canal belt of mid- to late Tertiary granite lies within and next to Coast Plutonic Complex belt II. In addition, scattered mafic-ultramafic bodies occur within the Fairweather-Baranof, Muir-Chichagof, and Coast Plutonic Complex belts I and II. Palinspastic

  16. A statistical approach to the volcanic-plutonic connection

    Science.gov (United States)

    Schoene, B.; Keller, C.; Samperton, K. M.; Barboni, M.; Husson, J. M.

    2013-12-01

    The geochemical relationship between volcanic and plutonic rocks - whether the two are geochemically identical, or if the choice between eruption or intrusion is correlated with magma chemistry - represents a major unanswered question in igneous petrology. In one endmember scenario, felsic to intermediate plutons represent the unerupted residue from which crystal-poor eruptible melts are extracted. At the other end of the spectrum, it is argued that a nearly the entire volume of magma is evacuated during eruption, and that the probability of eruption versus intrusion is instead largely a function of magma flux. In the first scenario, parental magmas originating at depth experience substantial fractionation during volcanic melt extraction, leading to complementary volcanic and plutonic reservoirs. In the second endmember scenario, volcanic/plutonic fractionation in the middle to upper crust is negligible, predicting no geochemical difference between volcanic and plutonic rocks. A third endmember scenario that is not exclusive from the other two predicts differences between volcanic and plutonic rocks if geochemical characteristics are correlated with the eventual eruptibility of magma. Deciphering the relative importance of each of these models is important for understanding both the long-term geochemical balance of the crust and mantle due to increased erosion and recycling of volcanic rocks and also for understanding magma transport dynamics. We have compared the geochemistry of ~500,000 volcanic and plutonic rocks from a range of tectonic settings by Monte Carlo bootstrap analysis in order to produce maximally representative average compositions. The results indicate that while volcanic and plutonic rocks in general show remarkably similar major element trends, intermediate to felsic plutonic rocks, for a given silica content, display clear enrichments in Sr and Ba and depletions in Zr, Hf, and HREEs relative to their volcanic equivalents. More subtly

  17. Oxygen isotope geochemistry of a potassic porphyritic calc-alkalic composite pluton: the Itaporanga batholith, state of Paraiba, Northeastern Brazil

    International Nuclear Information System (INIS)

    The composite porphyritic, potassic calc-alkaline Itaporanga batholith was intruded between the metasediments of the Cachoeirinha-Salgueiro groups and the gneisses of the basement, in the western portion of the State of Paraiba, Northeastern Brazil. The close interaction of mafic (potassium diorite) with felsic porphyritic rocks (quartz monzonite to granite) forming hybrid ones (monzonite to granodiorite) developed migmatite-like structures (stromatic and, less often, agmatic) suggesting coexistence and mixing of magmas as a major process during the evolution of this pluton. Quartz, known for its resistence to weathering and subsequent oxygen isotope exchange, was used to compare the δ18O values among these rocks. (author)

  18. Plutonic rocks of Jurassic age in the Alaska-Aleutian Range batholith: chemical variation and polarity.

    Science.gov (United States)

    Reed, B.I.; Miesch, A.T.; Lanphere, M.A.

    1983-01-01

    Plutonic rocks of Jurassic age exposed on the Pacific side of this batholith form a compositionally continuous calc-alkaline suite that ranges from hornblende gabbro to quartz monzonite. Tonalite and quartz diorite are the dominant rock types. Trend-surface analysis of 102 samples indicates that the direction of slope of the trend is approximately normal to the Jurassic magmatic arc. K2O and SiO2 increase towards the E-SE and the other oxides towards the W-NW. If the chemical trends reflect the approximate geometry of a palaeo-subduction zone, the polarity of the Jurassic magmatic arc is to the NW, i.e. subduction was directed towards the SE. Thus the palaeo-subduction zone is on the opposite side of the arc from the position that has generally been assumed, indicating that the Jurassic plutonic rocks were not generated in response to classical Andean-type convergent plate margins. The magmatic arc may have been formed in an intra-ocean environment and subsequently has been rafted northwards and accreted to this part of the N Pacific rim during the late Mesozoic. Middle and Upper Jurassic clastics underlying Cook Inlet to the SE and derived from the magmatic arc are classified as back-arc deposits, rather than as an arc-trench gap sequence.-L.C.H.

  19. Digital relief 3D model of the Khibiny massive (Kola peninsula)

    Science.gov (United States)

    Chesalova, Elena; Asavin, Alex

    2015-04-01

    On the basis of maps of 1: 50,000 and 1: 200,000 3D model Khibiny massif developed. We used software ARC / INFO v10.2 ESRI. This project will be organised to build background for gas pollution monitoring network. We planned to use the model to estimate local heterogeneities in the composition of the atmosphere at the emanation of greenhouse gases in the area, the construction of models of vertical distribution of the content of trace gases in the rock mass. In addition to the project GIS digital elevation model contains layers of geological and tectonic map that allows us to estimate the area of the output of certain petrographic rock groups characterized by different ratios of emitted hydrocarbons (CH4/ H2). The model allows to construct a classification of fault in the array. At first glance, there are two groups of faults - the ancient associated with the formation of the intrusive phases sequence, and the young - due to recent tectonic shifts. Ancient faults form a common semicircular structure of the pluton cause overall asymmetry Khibin heights with the transition to the border area between the Khibiny and Lovoozero. Modern tectonics mainly represented by radial and chord faults which are formed narrow mountain valleys and troughs. It remains an open question as to which system fault (old or young) is more productive to gas emanations? On the one hand the system characterized by a large old depth, on the other hand a young more active faults. Address these issues require further detailed observations. The essential question is to assess the possibility of maintaining a constant concentration gradient of these impurities in the atmosphere due to gas emanations of fracture zones and areas enriched occluded gases. In the simulation of these processes can be used initially set parameters: 1 the flow rate of the gas impurities 2 the value of wind flows in closed and open valley 3 Assessment of thermal diffusion coefficients determined by the temperature gradient

  20. The reliability improvement plan of hot cell examination data by introducing of Kolas

    International Nuclear Information System (INIS)

    For enhancement of hot cell data reliability produced at Irradiated Material Examination Facility in KAERI,Korea a project to introduce Kolas of National Quality Assurance Institute. By Kolas introduction the examination data currently produced would be reinforced by additional function of uncertainty evaluation and would obtained more reliable data. The all of data collected would be quality controlled, so that it would be re-traceable. Presently at IMEF shock test, tension test, dimension measurement test, hardness test, density test, and composition analysis test will be subject to Kolas. It is also planned to expand the number of test items in near future. At the end of 2000 year IMEF aims to secure the certificate issued by the National Quality Assurance Institute. (Hong, J. S.)

  1. Geophysical modeling and structure of Ushuaia Pluton, Fuegian Andes, Argentina

    Science.gov (United States)

    Peroni, Javier Ignacio; Tassone, Alejandro Alberto; Menichetti, Marco; Cerredo, María Elena

    2009-10-01

    Within the area of Ushuaia Bay (Tierra del Fuego, southernmost South America) the deformed Lower Cretaceous sedimentary rocks of Yahgán Formation host the Ushuaia Pluton. The intrusive body is oval in map view; it is compositionally varied with rocks ranging from the ultrabasic to the mesosiliceous realm. The emplacement time is constrained within the Albian-Cenomanian span by new amphibole K/Ar data. Meso- and microstructures of Ushuaia Pluton and its host indicate a synkinematic emplacement with a dominant extensional component. A set of transcurrent and normal faults related to the sinistral strike-slip Beagle Channel Fault System affects the pluton and its host. On the basis of aeromagnetic data combined with field information, a new model is presented for the Ushuaia Pluton. Modeling results fit well with a laccolithic body with an estimated volume of around 111 km 3. The model pluton cross-section displays a central zone with an average thickness of 2000 m which progressively thins toward the margins (˜ 500 m) and a southern root which reaches 5000 m deep. The combined structural and geophysical model supports a transtensive scenario for the Ushuaia Pluton emplacement at Early-Late Cretaceous boundary.

  2. Od zrna i klipa do kruha i kolača u Podravini do 1945. godine

    OpenAIRE

    Kolar Dimitrijević, Mira

    2009-01-01

    Osnovna privredna grana Podravine je poljoprivreda, a u njoj su žitarstvo, kukuruzarstvo, mlinovi i pekare stupnjevi na putu od zrna i klipa do kruha i kolača. Mlinarstvo je bilo jedan od najzastupljenijih, najvidljivijih i najprisutnijih proizvodnih pogona. Za razliku od pilana, mlinovi su bili najviše zgrade u mnogim mjestima, a dimnjaci mlinova bili su označavajući faktor kao i crkveni tornjevi. Brundanje i tiho zujanje mlinskih kola uz klopotanje klipa parne mašine označavalo je da je mli...

  3. Feasibility study on introduction of KOLAS (Korea Laboratory Accreditation Scheme) in nuclear examination facility

    International Nuclear Information System (INIS)

    To be an institute officially authorized by the KOLAS, the understanding and the analysis of following contents is required.: the understanding of concept required to get the accreditation of testing, the system specifying an internationally accredited testing and examination organization, international organization in the field of laboratory accreditation, domestic laboratory accreditation organization(KOLAS), the investigation of the regulations with laboratory accreditation in Korea, the investigation of the procedures accrediting a testing and examination organization, the investigation of general requirements(ISO 17025) for a testing and examination organization. (author)

  4. Mateřská škola v Sedlejově

    OpenAIRE

    Pavlů, Iveta

    2013-01-01

    Diplomová práce s názvem Mateřská škola v Sedlejově řeší projektovou dokumentaci ve stupni pro provedení stavby. Mateřská škola má dvě nadzemní podlaží. Objekt je nepodsklepený. Zastřešení je provedeno plochou střechou. Zdící systém POROTHERM s kontaktním zateplením minerální vatou.

  5. Geochemistry and tectonic implications of the trans-Himalayan Lohit plutonic complex, eastern Arunachal Pradesh

    International Nuclear Information System (INIS)

    The Trans-Himalayan Lohit Plutonic Complex occurs to the east of the Eastern Syntaxis in eastern Arunachal Pradesh and the investigations were carried out mainly along the Lohit River section. The plutonic complex intrudes the metavolcanics of probable arc affinity in the west and high-grade metamorphic rocks of the Asian continental margin in the east. It can be sub divided into western and eastern belts, separated by Walong Thrust. The complex consists of multiple intrusions and they are: (I) an early phase of metaluminous, tholeitic to calc- alkaline gabbro and quartz diorites with minor diorites and hybrid rocks; (2) an intermediate phase of calc-alkaline, metaluminous, leucotonalite of high Al-trondhjemitic or adakitic composition; (3) a last phase of peraluminous leucogranite and associated veins of pegmatite and aplite. The enrichment of large-ion-lithophile elements (LILE) relative to high field strength elements (HFSE) of these rock types suggest that they were emplaced in a subduction related environment and derived from different source materials. The major and trace element variations in the early gabbro-quartz diorite, along with the low initial 87Sr/86Sr ratio (0.703-0.704) suggest that they were derived from a parental tholeitic magma, from which the intrusives have been differentiated under increasing water pressure conditions. The geochemical characteristics of the trondhjemites, such as the high Na2O, Al2O3, Sr, Sr/Y ratios and low K2O, Y and depletion of heavy rare earth elements (HREE) are similar to those of adakite and Archaean high Al- trondhjemite. They might have been derived either by melting of the subducted oceanic crust or by partial melting of newly under- plated basaltic crust beneath the thickened continental arc leaving residual garnet and amphibole. The leucogranites with high K2O, Rb, K2O/Na2O, K/Rb, Rb/Sr ratios, and high initial 87Sr/86Sr ratio (0.713), along with depletion in HREE and absence of negative Eu anomaly, suggest

  6. Petrogenesis of the Dengzhazi A-type pluton from the Taihang-Yanshan Mesozoic orogenic belts, North China Craton

    Science.gov (United States)

    Xiaolu, Niu; Bin, Chen; Xu, Ma

    2011-05-01

    The voluminous Mesozoic monzonitic to monzogranitic rocks in the north China craton (NCC) mostly show high-K calc-alkaline and I-type granitoids features. The Dengzhazi granitic pluton, however, shows features typical of A-type granites. The A-type pluton was emplaced in the Taihang-Yanshan orogenic belts of the northern margin of the NCC, with zircon U-Pb ages of around 140 Ma. The Dengzhazi A-type granites are characterized by high SiO 2 (70.2-77.7 wt.%), K 2O + Na 2O, Zr, Nb, Ga, Zn, and Y contents as well as high Ga/Al ratios, and extremely low CaO, Ba, Sr. In addition, they show high zircon saturation temperatures (870-950 °C), low water and low oxygen fugacity. All these features are consistent with the A-type affinity of the pluton. In situ Hf isotopic analyses for the dated zircons show relatively small range of ɛHf( t) (-13 to -17). They also have homogeneous initial Nd isotopic compositions with ɛNd( t) ranging from -15.1 to -16.3. The Hf and Nd isotopic data suggest that the Dengzhazi A-type granites originated from a homogeneous crustal source, probably the Archean mafic-intermediate granulites. Taking into account the high temperatures, the low H 2O and fO 2 of the magma system, we believe that partial melting of the granulites should have been triggered by underplating of mantle-derived magmas at the base of the mafic lower crust in an extensional regime. The Dengzhazi A-type granite is the oldest pluton of the Taihang-Yanshan Mesozoic magma belts, signifying the commencement of extensive underplating of mafic magmas, and thus of lithospheric thinning in the northern NCC.

  7. Crystal structure of hydrogen-bearing vuonnemite from the Lovozero alkaline massif

    International Nuclear Information System (INIS)

    Hydrogen-bearing vuonnemite from the Shkatulka hyperagpaitic pegmatite (the Lovozero alkaline massif, Kola Peninsula) was studied by single-crystal X-ray diffraction. The triclinic unit-cell parameters are as follows: a = 5.4712(1) Å, b = 7.1626(1) Å, c = 14.3702(3) Å, α = 92.623(2)°, β = 95.135(1)°, γ = 90.440(1)°, sp. gr. P1, R = 3.4%. The Na+ cations and H2O molecules are ordered in sites between the packets. The water molecules are hydrogen bonded to the PO4 tetrahedra.

  8. Phenological development of introduced species Picea A. Dietr. on the Kola Peninsula

    Directory of Open Access Journals (Sweden)

    Goncharova Oxana Alexandrovna

    2015-12-01

    Full Text Available In the article results of long-term phenologucal observations of introduced species of Picea A. Dietr. on the Kola Peninsula. The cycle of vegetative development of types of Picea corresponds to the vegetative period of a place of an introduction.

  9. Evaluation of machine-building enterprises of the Kola Peninsula for developing of the Arctic communications

    Directory of Open Access Journals (Sweden)

    Turchaninova T. V.

    2015-09-01

    Full Text Available The research of engineering enterprises with a single and small-batch manufacturing of the Kola Peninsula has been carried out. The possibilities of satisfying demands for their products and services in the regional market have been determined, that is very important for understanding the prospects for the development and exploitation of the Arctic communications

  10. ALP (Alkaline Phosphatase) Test

    Science.gov (United States)

    ... Also known as: ALK PHOS; Alkp Formal name: Alkaline Phosphatase Related tests: AST ; ALT ; GGT ; Bilirubin ; Liver Panel ; Bone Markers ; Alkaline Phosphatase Isoenzymes; Bone Specific ALP All content on ...

  11. An extrusive-plutonic event at Hardy Point and its vicinity - Greenwich Island - Antarctic

    International Nuclear Information System (INIS)

    The volcanic and intrusive rocks at Hardy point and its vicinity were formed mainly during a Mesozoic magmatism. Andesitic-basalt flows and and andesites constitute the volcanic rocks. The intrusive ones were expressed as an epizonal body, with dioritic to granitic composition, and are cogenetic to the volcanic ones. The geochemical patterns indicate that volcanism preceded plutonism. In rare earth elements diagram the intrusive rocks present a further developed pattern, in which all rocks show calc-alkaline affinity, an enrichment in light rare earth diagram the intrusive rocks present a further, in which all rocks show calc-alkaline affinity, an enrichment in light rare earth elements relative to the heavy ones, probably due to partial melting of the mantle. In the spidergram (LILE, HFSE) the same pattern is observed for all rock groups, with strong negative anomalies of ti, p Nb, typical of island arcs, besides a positive anomaly of Ce, which could be related to the assimilation of Ce-enriched marine sediments. (author)

  12. Survey of lunar plutonic and granulitic lithic fragments

    Science.gov (United States)

    Bickel, C. E.; Warner, J. L.

    1978-01-01

    A catalog of lunar plutonic rocks and granulitic impactites belonging to the ANT suite has been compiled. The coarser-grained, plutonic rocks in the compilation are probably pristine; they belong to two groups, Mg-rich plutonic rocks and anorthosites, with a preponderance of the latter type. The granulitic impactites, however, have bulk and mineral compositions that fall between the two groups defined by the pristine nonmare samples of Warren and Wasson (1977). Thus the granulitic impactites may have originated by metamorphism of mixed impactites in early breccia sheets. The catalog, representative of the lunar crust before the end of heavy bombardment, suggests a crust with over 78 vol. % plagioclase and about equal proportions of material with noritic and troctolitic affinity.

  13. The Plutón Diorítico Moat: Mildly alkaline monzonitic magmatism in the Fuegian Andes of Argentina

    Science.gov (United States)

    González Guillot, M.; Escayola, M.; Acevedo, R.; Pimentel, M.; Seraphim, G.; Proenza, J.; Schalamuk, I.

    2009-12-01

    The Plutón Diorítico Moat (Moat Dioritic Pluton, PDM) is the largest of several isolated Cretaceous plutons exposed in the Fuegian Andes of Argentina. It is made of a large variety of rock types ranging from ultramafic bodies (pyroxenites and hornblendites) to syenites. The petrological diversity is thought to have been originated by fractional crystallization of a mantle-derived magma combined with minor assimilation of continental crust (AFC). Its geochemical characteristics indicate a mildly-alkaline monzonitic affinity, contrasting with the typical calc-alkaline plutons of the Southern Patagonian Batholith (PB) to the south, in the Chilean archipelago. The PDM original magma is arc-related and its crystallization, as indicated by the Rb-Sr mineral isochron age of 115 ± 3 Ma, is coeval with some plutons of the PB. Therefore a similar tectonic regime is assumed for the emplacement of these plutonic bodies, both south and north of the Beagle channel. Differences in magma sources and degree of partial melting are inferred to account for the contrasting lithological and geochemical characteristics of the PB and PDM. The data suggest that the original magmas of the PDM were generated at greater depths in the mantle, by a smaller degree of partial melting, compared with the PB. The Barros Arana basalts, exposed to the north in Chile, forming a back-arc volcanic complex, display the same mildly-alkaline shoshonitic affinity, and are considered in this study as the volcanic equivalents of the PDM. All the plutons in the Argentinean Fuegian Andes display similar lithological and geochemical characteristics and are, therefore, grouped in this work under the name of Magmatismo Potásico Fueguino ( Fuegian Potassic Magmatism).

  14. Amino acid composition of two masticatory nuts (Cola acuminata and Garcinia kola) and a snack nut (Anacardium occidentale).

    Science.gov (United States)

    Adeyeye, E I; Asaolu, S S; Aluko, A O

    2007-06-01

    The amino acid compositions of Cola acuminata, Garcinia kola and Anacardium occidentale were evaluated by ion-exchange chromatography. Glutamic acid was the most concentrated acid in the samples. In all the amino acids determined, A. occidentale had the most concentrated acid on a pairwise basis. The total amino acids were 356.24 mg/g protein, 112.90 mg/g protein and 659.17 mg/g protein for C. acuminata, G. kola and A. occidentale, respectively. The percentage total essential amino acids were 38.39% (C. acuminata), 47.05% (G. kola) and 51.04% (A. occidentale). Also the percentage total acidic amino acids were 38.16% (C. acuminata), 30.61% (G. kola) and 30.35% (A. occidentale). The calculated isoelectric points were 2.0 (C. acuminata), 0.7 (G. kola) and 3.9 (A. occidentale), showing they can all be precipitated at acidic pH. While threonine was the limiting amino acid in A. occidentale, it was valine in both C. acuminata and G. kola. The percentage cystine (Cys) levels in the total sulphur amino acid were 44.27% (C. acuminata), 37.75% (G. kola) and 50.51% (A. occidentale). The aim of this work was to compare the amino acid profile of the samples. It is recommended that C. acuminata and G. kola consumption be avoided by ulcer patients because of their high levels of acidic amino acids. A. occidentale amino acid scores ranged from 42% to 127%, suggesting that it could be used to enhance the protein quality of cereals through food complementation. PMID:17566886

  15. Pilot scale trials of irradiation preservation of maize, kola nuts and dried fish, and preliminary market test

    International Nuclear Information System (INIS)

    Various studies were conducted to determine the possibility of utilizing gamma irradiation to disinfect cowpea, maize, kola nuts and smoked fish in Nigeria. The studies included the determination of radiosensitivity of important storage insect pests such as the cowpea seed beetle, 'Callosobrucus maculatus', the cigarette beetle, 'Lasioderma serricorne', the kola weevils, 'Balanogastris kolae' and 'Sophrorhinus gbanjaensis'. They also included consumer acceptance and or sensory evaluation of irradiated cowpea, maize and smoked-dried fish. The results showed that irradiation could be integrated with the traditional peasant farmers' method of storing unshelled dry cowpea in granaries; and such an integration can completely eliminate seed beetle infestation. Irradiation at a dose of 0.2-1.0KGy was quite effective in preventing development of 'L. Serricorne'. All stages of development of 'B.kolae' and 'S. gbanjaensis' were very sensitive to irradiation; and a dose of 0.1KGy-0.2KGy was found to be adequate for disinfecting kola nut of the weevils. Irradiation up to 0.2KGy also did not cause any significant change in proximate composition of kola nuts. Consumer acceptance and sensory evaluation tests on cowpea, maize and smoke-dried fish showed that Nigerian consumers did not have any aversion to irradiated foods. A high percentage of respondents indicated their willingness to purchase samples

  16. Infrasound research at Kola Regional Seismological Centre, Russia

    Science.gov (United States)

    Asming, Vladimir; Kremenetskaya, Elena

    2013-04-01

    A small-aperture infrasound array has been installed in Kola Peninsula, Russia 17 km far from the town of Apatity in the year 2000. It comprises 3 Chaparral V microbarographs placed closely to the APA seismic array sensors and equipped with pipe wind reducing filters. The data are digitized at the array site and transmitted in real time to a processing center in Apatity. To search for infrasound events (arrivals of coherent signals) a beamforming-style detector has been developed. Now it works in near real time. We analyzed the detecting statistics for different frequency bands. Most man-made events are detected in 1-5 Hz band, microbaromes are typically detected in 0.2-1 Hz band. In lower frequencies we record mostly a wind noise. A data base of samples of infrasound signals of different natures has been collected. It contains recordings of microbaromes, industrial and military explosions, airplane shock waves, infrasound of airplanes, thunders, rocket launches and reentries, bolides etc. The most distant signals we have detected are associated with Kursk Magnetic Anomaly explosions (1700 km far from Apatity). We implemented an algorithm for association of infrasound signals and preliminary location of infrasound events by several arrays. It was tested with Apatity data together with data of Sweden - Finnish infrasound network operated by the Institute of Space Physics in Umea (Sweden). By agreement with NORSAR we have a real-time access to the data of Norwegian experimental infrasound installation situated in Karasjok (North Norway). Currently our detection and location programs work both with Apatity and Norwegian data. The results are available in Internet. Finnish militaries routinely destroy out-of-date weapon in autumns at the same compact site in North Finland. This is a great source of repeating infrasound signals of the same magnitude and origin. We recorded several hundreds of such explosions. The signals have been used for testing our location routines

  17. Poverty Alleviation through Optimizing the Marketing of Garcinia kola and Irvingia gabonensis in Ondo State, Nigeria

    OpenAIRE

    Agbelade, A. D.; Onyekwelu, J. C.

    2013-01-01

    The paper examines poverty alleviation through optimizing the marketing of Garcinia kola and Irvingia gabonensis in Ondo State, Nigeria. Data for this study were collected using structured questionnaire. Two categories of pretested structured questionnaires were used to obtain information from the respondents (farmers and the marketers of the species). Data analysis was done using descriptive analysis, and Student t-test was used to compare the income generated by the producers and the market...

  18. In Vitro Antilisterial Properties of Crude Methanol Extracts of Garcinia kola (Heckel) Seeds

    OpenAIRE

    Dambudzo Penduka; Okoh, Anthony I.

    2012-01-01

    Crude methanol extracts of Garcinia kola (Heckel) seeds were screened for their antilisterial activities against 42 Listeria bacteria isolated from wastewater effluents. The extract had activity against 45% of the test bacteria and achieved minimum inhibitory concentrations (MICs) ranging between 0.157 and 0.625 mg/mL. The rate of kill of the extract was determined against four representative Listeria species in the study, and the results showed that the highest percentage of bacteria cells w...

  19. Kolaviron, isolated from Garcinia kola, inhibits acetylcholinesterase activities in the hippocampus and striatum of wistar rats

    OpenAIRE

    Ijomone, Omamuyovwi M.; Obi, Augustine U.

    2013-01-01

    Background Kolaviron, isolated from seeds of Garcinia kola, have been shown to possess wide pharmacological properties. Purpose The present study examined the effect of kolaviron on acetylcholinesterase activities in the hippocampus and striatum of adult Wistar rats. Methods In this study, histological and histochemical methods were used to investigate the effects of kolaviron on the histology of the hippocampus and striatum and on acetylcholinesterase activities in these brain regions. Resul...

  20. Science, sulphur and sustainability : environmental strategies of mining in the Russian Kola Peninsula

    OpenAIRE

    Salmi, Olli H

    2008-01-01

    This dissertation analyses the problem of co-aligning corporate strategy and public policy for effective environmental governance. A case study of the mining industry in the Russian Kola Peninsula shows how institutional arrangements (including public policies) affect the environmental performance of industrial organizations. The analysis emphasizes the motivations that drive people's decisions and how they are affected by culture and formal institutions both inside and outside the domain of ...

  1. Producers’ motivation for collective action for kola production and marketing in Cameroon

    Directory of Open Access Journals (Sweden)

    Steven Franzel

    2012-04-01

    Full Text Available Collective action has been used as a strategy to improve the benefits of smallholder producers of kola nuts in Cameroon. Despite demonstrated benefits, not all producers are involved in the collective action. The presented study used a modified Technology Acceptance Model (TAM namely the Collective Action Behaviour model (CAB model to analyse kola producers’ motivation for collective action activities. Five hypotheses are formulated and tested using data obtained from 185 farmers who are involved in kola production and marketing in theWestern highlands of Cameroon. Results which were generated using Partial Least Squares (PLS approach for Structural Equation Modelling (SEM showed that farmers’ intrinsic motivators and ease of use influenced their behavioural intent to join a group marketing activities. The perceived usefulness that was mainly related to the economic benefits of group activities did not influence farmers’ behavioural intent. It is therefore concluded that extension messages and promotional activities targeting collective action need to emphasise the perceived ease of use of involvement and social benefits associated with group activities in order to increase farmers’ participation.

  2. LED osvětlení jízdního kola

    OpenAIRE

    Čmelík, Matouš

    2014-01-01

    V semestrální práci navrhuji osvětlení jízdního kola pomocí LED diod, které jsou napájené z alternátoru. Navrhuji osvětlení s akumulátorem, který se při jízdě dobíjí a při zastavení umožňuje nepřerušené osvětlení kola. Celý koncept je navržen, tak aby výsledná cena byla co nejnižší. Celé zapojení navrhuji, aby šlo vložit do stávajícího osvětlení kola Eska či Favorit a nevzbuzovalo pozornost. Použití měničů zaručuje vysokou efektivitu celého konceptu. Použití LED diod zaručuje vysokou svítivos...

  3. Petrographical and geochemical characterization and deformation conditions of the San Cristobal pluton, Sierra de Velasco, La Rioja, Argentina; Caracterizacion petrografica y geoquimica y condiciones de deformacion del pluton San Cristobal, Sierra de Velasco, La Rioja, Argentina

    Energy Technology Data Exchange (ETDEWEB)

    Bellos, L.I.; Toselli, A.J.; Rossi, J.N.; Grosse, P.; Rosa, J.D. de la; Castro, A.

    2010-07-01

    The San Cristobal pluton is a 35 km2 granitic body that outcrops at the southestern tip of the Sierra de Velasco, located west of La Rioja city, Argentina. It is formed by monzogranites and syenogranites, together with scarce granodiorites, with medium to fine-grained, equigranular to slightly porphyritic textures. Their mineral assemblage consists of quartz + microcline + plagioclase + biotite {+-} muscovite + zircon + apatite + magnetite. The granite contains dioritic to tonalitic mafic enclaves. The central and eastern parts of the granite have been deformed by the NNW-SSE trending South Mylonitic shear zone formed by mylonitic rocks. The metamorphic host-rock is represented by scarce greenschist facies xenoliths and hornfels with the high T/P assemblage K-feldspar - cordierite - biotite {+-} sillimanite. The granites are calc-alkaline, weak- to moderately peraluminous, and formed as part of a continental magmatic arc developed along the active margin of western Gondwana during the Early Paleozoic. The depth of emplacement of the San Cristobal pluton is estimated at {approx}12 km. (Author).

  4. Miscellaneous investigations series: Bedrock geologic map of the Lone Mountain pluton area, Esmeralda County, Nevada

    International Nuclear Information System (INIS)

    The joint attitudes were measured in the field and plotted on aerial photos at a scale of 1:24,000. The pluton is intensely jointed, primarily as a result of cooling and movement of the magma within a northwest-trending stress field. Foliation, in general, is poorly developed, and quality varies from area to area, but it is best developed close to the contacts with the metasedimentary rocks. A prominent northwest foliation direction was observed that parallels the northwest elongation of the exposed pluton. Faults in the pluton are difficult to identify because of the homogeneity of the rock. Several faults were mapped in the northern part of the area where they have a northeast trend and intersect the northwest-trending lamprophyre dikes with little apparent displacement. A major fault that bounds the northern part of the pluton is downthrown to the north and strikes northeast. This fault offsets the alluvium, the metasedimentary rocks, and the pluton and forms fault scraps as high as 10 m. Aeromagnetic data (US Geological Survey, 1979) suggest the following: (1) the local magnetic highs in the central part of the Lone Mountain pluton are probably related to topographic highs (peaks) where the flight lines are closer to the pluton; (2) a magnetic low in the northeastern part of Lone Mountain coincides with the pluton-country rock contact, which may be very steep; (3) the contours for the southwestern part of the mapped area indicate that the pluton-country rock contact is not as steep as that in the northeastern part and that the pluton probably coalesces at depth with the Weepah pluton, a pluton exposed south of the mapped area; and (4) the contours for the area of the Lone Mountain pluton express a northwest-trending gradient that parallels the northwest elongation of the Lone Mountain pluton and the northwest-trending stress field. 10 refs

  5. Reconstruction of early Holocene paleoclimate and environment in the SW Kola region, Russian Arctic

    Science.gov (United States)

    Grekov, Ivan; Kolka, Vasiliy; Syrykh, Liudmila; Nazarova, Larisa

    2016-04-01

    In the current period of the global climate change it becomes necessary to have a clear understanding of not only the changes taking place in the components of the natural environment, but also to understand development of all interactions between those components. Quaternary terrigenic sediments and lakes of the Kola Peninsula store information about the development of the region in the Late Glacial and Holocene: movements of the glacier, neotectonic activity, post-glacial rebound, formation and development of natural environments after deglaciation. Multi-proxy study of landscapes evolution of the Kola Peninsula in the Late Quaternary will help to establish a detailed reconstruction of climatic and environmental changes of this poor studied sector of the Arctic. Quaternary history on the Kola Peninsula is represented mainly by Late Pleistocene and Holocene sediments covering the Baltic Shield (Lavrova, 1960; Evzerov, 2015). Several palaeolimnological investigations in the Baltic Shield area have been performed earlier (Donner et al., 1977; Anundsen, 1985; Berglund, 2004). Studies of the southern coast of the Kola Peninsula have shown that marine transgression took place in the Late Pleistocene that was then replaced by a regression with variable speed. The slowdown of the uplift of the area took place between 8800 - 6800 BP (cal. years) and corresponded to the time of the Tapes transgression of the Arctic Ocean (Evzerov et al. 2010; Kolka, et al., 2013). Palaeoclimatic studies based on micro-paleontological analyzes indicate uneven development of the Kola Peninsula landscapes in the Late Glacial and Early Holocene. The northern coast of the Peninsula became free of ice first. In this area tundra-steppe vegetation was established for a short time and was later replaced by tundra (Snyder et al, 2000). Southern part of the Kola Peninsula was dependent on the conditions of deglaciation of the White Sea basin and cleared of ice much later (Evzerov et al., 2010; Kolka

  6. Anodes for alkaline electrolysis

    Science.gov (United States)

    Soloveichik, Grigorii Lev

    2011-02-01

    A method of making an anode for alkaline electrolysis cells includes adsorption of precursor material on a carbonaceous material, conversion of the precursor material to hydroxide form and conversion of precursor material from hydroxide form to oxy-hydroxide form within the alkaline electrolysis cell.

  7. Alkaline "Permanent" Paper.

    Science.gov (United States)

    Pacey, Antony

    1991-01-01

    Discussion of paper manufacturing processes and their effects on library materials focuses on the promotion of alkaline "permanent" paper, with less acid, by Canadian library preservation specialists. Standards for paper acidity are explained; advantages of alkaline paper are described, including decreased manufacturing costs; and recyclability is…

  8. Thermophysical properties of americium-containing barium plutonate

    International Nuclear Information System (INIS)

    Polycrystalline specimens of americium-containing barium plutonate have been prepared by mixing the appropriate amounts of (Pu0.91Am0.09)O2 and BaCO3 powders followed by reacting and sintering at 1600 K under the flowing gas atmosphere of dry-air. The sintered specimens had a single phase of orthorhombic perovskite structure and were crack-free. Elastic moduli were determined from longitudinal and shear sound velocities. Debye temperature was also determined from sound velocities and lattice parameter measurements. Thermal conductivity was calculated from measured density at room temperature, literature values of heat capacity and thermal diffusivity measured by laser flash method in vacuum. Thermal conductivity of americium-containing barium plutonate was roughly independent of temperature and registered almost the same magnitude as that of BaPuO3 and BaUO3. (author)

  9. Granitoids of the Dry Valleys area, southern Victoria Land, Antarctica : plutons, field relationships, and isotopic dating

    International Nuclear Information System (INIS)

    Detailed mapping throughout much of the Dry Valleys area indicates the region is underlain by 15 major granitoid plutons and numerous smaller plugs and dikes. Intrusive relationships of these plutons and dikes indicate repeated intrusion of superficially similar granitoids at different times. Sufficient internal lithologic variation occurs within individual plutons, to allow correlation with several of the previously defined granitoid units based on lithologic character. Consequently, previous subdivision schemes based on lithology are no longer tenable and are here replaced with a subdivision scheme based on the identification of individual plutons. The elongate, concordant Bonney, Denton, Cavendish, and Wheeler Plutons, which range in composition between monzodiorite and granodiorite, are the oldest relatively undeformed plutons in the Dry Valleys area. Each pluton is characterised by flow alignment of K-feldspar megacrysts, hornblende, biotite, and mafic enclaves. Field relationships and radiometric dating indicate these are deep-level plutons, emplaced synchronous with upper amphibolite facies metamorphism of the adjacent Koettlitz Group between 589 and 490 Ma ago. Elongate, discordant plutons of equigranular homogeneous biotite granodiorite and granite (Hedley, Valhalla, St Johns, Suess) were subsequently emplaced by stoping at a relatively high crustal level at 490 Ma. These eight plutons are cut by numerous swarms of Vanda mafic and felsic porphyry dikes. The ovoid, discordant, high level Pearse, Nibelungen, Orestes, Brownworth, Swinford, and Harker Plutons, emplaced between c. 486 and 477 Ma, display mutually crosscutting relationships with the youngest of the Vanda dikes. These younger plutons range in composition between monzonite and granite. Some are characterised by K-feldspar megacrystic textures superficially similar to some of the oldest concordant plutons. (author). 57 refs.; 2 tabs.; 4 figs

  10. Apollo 14 inverted pigeonites - Possible samples of lunar plutonic rocks.

    Science.gov (United States)

    Papike, J. J.; Bence, A. E.

    1972-01-01

    Analysis of 'inverted pigeonites' found in Apollo 14 samples 14082 and 14083 (a polymict breccia, the 'white rock') by a combination of optical, electron probe, and single-crystal X-ray diffraction techniques. These 'inverted pigeonites' are regarded as samples of plutonic rocks that have been blasted out of the Imbrium Basin. It is also concluded that lunar pigeonites will invert to orthopyroxenes, given sufficiently slow cooling histories even in very anhydrous environments.

  11. Indoor - soil gas radon relationshipin the Central Bohemian Plutonic Complex

    OpenAIRE

    I. Fojtíková; J. Miksová; I. Barnet

    2005-01-01

    The relationship of indoor radon measurements and radon in bedrock was studied in the granitoid Central Bohemian Plutonic Complex (CBPC). The indoor data were linked to vectorised geological and radon risk maps using the coordinates of particular dwellings. For each geological unit and rock type it was possible to calculate the statistical characteristics of indoor radon measurements. A clear relationship between indoor radon values and radon in bedrock was confirmed in al...

  12. Isolation and Characterization of Flavanone Glycoside 4I,5, 7-Trihydroxy Flavanone Rhamnoglucose from Garcinia kola Seed

    Science.gov (United States)

    Okwu, D. E.; Morah, F. N. I.

    The ethanolic extract of Garcinia kola, Heckel (Guttiferae), which had previously been shown to have biological activity were studied. Preliminary phytochemical screening of the plants showed the presence of flavonoids, phenolic compounds, tannins and saponins. The ethanolic extract of Garcinia kola seeds resulted in the isolation and characterization of flavanone glycoside 4I, 5, 7-trihydroxyflavonone rhamnoglucose (that is naringin-7-rharmnoglucoseside) from its spectral data. IHNMR spin system analysis and acid hydrolysis were performed to characterize the higher order rhamnoglucosyl moiety comprising glucose and rhamnose linked to carbon 7 of the flavanone ring system of the isolate. It is concluded that 4I, 5, 7-trihydroxyflavanone rhamnoglucose may be a contributor to the antioxidants, anti-inflammatory, anti-microbial, anti-tumor and anti-hepatotoxic properties exhibited by Garcinia kola seed.

  13. Experience of the chronological correlation of the Holocene sea coastal landforms in the Tuloma River valley and the Kola Bay

    Directory of Open Access Journals (Sweden)

    Tolstobrov D. S.

    2016-03-01

    Full Text Available The paper is a continuation of studies of the Earth's crust neotectonic movements within the north-western part of the Kola region. New radiocarbon data of the lake bottom sediments in the Tuloma River valley allowed to modify diagram of the relative uplift lines of the Earth surface in the north-western part of the Kola region and to compare them with previously constructed epeirogenic spectra of coastal landforms for the study area. The dynamics and nature of the area uplift have been established and the dating of the ancient shorelines within the Tuloma River valley and the Kola Bay of the Barents Sea during the Holocene has been carried out

  14. Concentrations of 90Sr and 137Cs in region of discharge of warm water from the Kola Atomic Power Station

    International Nuclear Information System (INIS)

    The90Sr and 137Cs concentrations in trout cultivated in warm water from the Kola Atomic Power Station (APS) in the period 1974-1979 were 30-70 pCi/kg. This is one-quarter to one-third of the radionuclide concentrations in wild fish living in this region and one-tenth of that in commerical fishes from other waters on the Kola Peninsula. The low radionuclide concentrations can be attributed to the absence of pollution in the coolant reservoir of the Kola APS during this period of operation, and also to the fact that the main mode of entry of radionuclides into the fish's body is through food. The investigations lead to the very important conclusion that fish-farming based on the warm effluents of atomic power stations is a feasible proposition

  15. Artificial radionuclides in the ecosystems of the gulfs in the Kola peninsula and in the areas of radioactive wastes keeping

    International Nuclear Information System (INIS)

    The results of radioactive contamination investigations carried out in the Kola Peninsula gulf's ecosystems in the vicinity of the places of radioactive wastes keeping are presented. These investigations were conducted during 1994-2004 by specialists of the Murmansk Marine Biological Institute KSC RAS. The data on the artificial radionuclides contents in bottom sediments, water and hydrobiontes of the Kola, the Motovsky Bays and gulfs of the Barents Sea are presented. Coefficients values of caesium radionuclides distribution between water and bottom sediments of the Kola Bay obtained experimentally and developed on the basis of the data on the composition and amount of artificial radionuclides in bottom sediments classification of bays and gulfs are also given. (author)

  16. Nutrient and phytochemical composition of two varieties of Monkey kola (Cola parchycarpa and Cola lepidota): An underutilised fruit.

    Science.gov (United States)

    Ene-Obong, Henrietta N; Okudu, Helen O; Asumugha, Ukamaka V

    2016-02-15

    The nutrient and phytochemical composition of two varieties of Monkey kola: Cola parchycarpa and Cola lepidota were determined. The pulps were extracted, grated and dried using solar dryer. Dried pulps were milled into flour with attrition milling machine (0.5mm sieve size). The nutrient compositions were determined using standard AOAC methods. Gravimetric and spectrophotometric methods were used for phytochemical determinations. There were significant (p1.0 and ⩽0.06, respectively). Monkey kola had substantial amounts of iron, zinc, and copper; the B-vitamins and vitamin C. The phytochemical contents were quiet high, the most abundant being flavonoids (415-494mg/100g). Monkey kola is a fruit that should be fully exploited for its potential health benefits. PMID:26433302

  17. Alkaline battery operational methodology

    Energy Technology Data Exchange (ETDEWEB)

    Sholklapper, Tal; Gallaway, Joshua; Steingart, Daniel; Ingale, Nilesh; Nyce, Michael

    2016-08-16

    Methods of using specific operational charge and discharge parameters to extend the life of alkaline batteries are disclosed. The methods can be used with any commercial primary or secondary alkaline battery, as well as with newer alkaline battery designs, including batteries with flowing electrolyte. The methods include cycling batteries within a narrow operating voltage window, with minimum and maximum cut-off voltages that are set based on battery characteristics and environmental conditions. The narrow voltage window decreases available capacity but allows the batteries to be cycled for hundreds or thousands of times.

  18. Uranium in alkaline rocks

    Energy Technology Data Exchange (ETDEWEB)

    Murphy, M.; Wollenberg, H.; Strisower, B.; Bowman, H.; Flexser, S.; Carmichael, I.

    1978-04-01

    Geologic and geochemical criteria were developed for the occurrence of economic uranium deposits in alkaline igneous rocks. A literature search, a limited chemical analytical program, and visits to three prominent alkaline-rock localities (Ilimaussaq, Greenland; Pocos de Caldas, Brazil; and Powderhorn, Colorado) were made to establish criteria to determine if a site had some uranium resource potential. From the literature, four alkaline-intrusive occurrences of differing character were identified as type-localities for uranium mineralization, and the important aspects of these localities were described. These characteristics were used to categorize and evaluate U.S. occurrences. The literature search disclosed 69 U.S. sites, encompassing nepheline syenite, alkaline granite, and carbonatite. It was possible to compare two-thirds of these sites to the type localities. A ranking system identified ten of the sites as most likely to have uranium resource potential.

  19. Uranium in alkaline rocks

    International Nuclear Information System (INIS)

    Geologic and geochemical criteria were developed for the occurrence of economic uranium deposits in alkaline igneous rocks. A literature search, a limited chemical analytical program, and visits to three prominent alkaline-rock localities (Ilimaussaq, Greenland; Pocos de Caldas, Brazil; and Powderhorn, Colorado) were made to establish criteria to determine if a site had some uranium resource potential. From the literature, four alkaline-intrusive occurrences of differing character were identified as type-localities for uranium mineralization, and the important aspects of these localities were described. These characteristics were used to categorize and evaluate U.S. occurrences. The literature search disclosed 69 U.S. sites, encompassing nepheline syenite, alkaline granite, and carbonatite. It was possible to compare two-thirds of these sites to the type localities. A ranking system identified ten of the sites as most likely to have uranium resource potential

  20. Investigation and design concepts for a nuclear waste repository in the Kola Peninsula of Northwest Russia

    International Nuclear Information System (INIS)

    The Murmansk and Archangelsk regions located in northwestern Russia have accumulated large quantities of radioactive waste products from nuclear power plants, military ships (submarines, aircraft carriers and cruisers), ice breakers and light ships of the Murmansk Merchant Marines. This nuclear waste and associated byproducts are temporarily stored in surface facilities which lack long-term safety and containment assurances. Due to the lack of temporary storage facilities, the Russian Navy accumulates nuclear waste on floating ships and continues to dump liquid wastes into the Arctic Sea. The extent and nature of the problem is presently unknown. Waste producing organizations have neither facilities for the treatment and disposal, nor the capital necessary to construct such facilities. If urgent measures are not taken soon, the increasing quantity of waste will create an even more serious danger not only to the local population but also to the neighboring countries. The problem is one of global concern. This paper describes work being done at the Kola Mining Institute to mitigate problems of the past and to assure the continued safe production of energy from nuclear resources. The Kola Peninsula provides a natural location for the storage of nuclear materials and as a site for the production of abundant, inexpensive nuclear power. Recent studies support the theory that Kola is an ideal location for both the production of nuclear power and as a site to store and recycle radioactive materials. However, there exists today in Russia several potential long-term, world-threatening environmental problems if they are not addressed and resolved within the next few years. The problem is not due to the lack of technical solutions, but rather a lack of political and capital commitment

  1. Assessing the Effect of Salinity on an Irrigated Land at Kofai, Ardo-Kola Local Government Area, Taraba State - Nigeria

    Directory of Open Access Journals (Sweden)

    Buba Apagu ANKIDAWA

    2010-12-01

    Full Text Available A study of the effect of salinity on an irrigated land was carried out at Kofai, Ardo-Kola Local Government of Taraba State. The study area was divided into four (4 units designated as A, B, C and D, each unit was subdivided into five (5 parts, designated as A1, A2, A3, A4, A5, B1, B2, B3, B4, B5, C1, C2, C3, C4, C5, D1, D2, D3, D4, and D5, respectively, made up of twenty (20 soil samples that were collected within the irrigated land for the laboratory analysis of salinity. The parameters analyzed were pH, Electrical Conductivity (EC, Magnesium, Sodium, Potassium, Calcium, Hydrogen and Aluminum concentration. The results of the soil sample analysis shows that the mean value of pH is 5.99 which indicates that the soil is slightly acidic, the mean value of electrical conductivity (EC is 0.76 ds/m, Calcium, Magnesium, Aluminum and Hydrogen concentration were obtained to be 11.29, 7.89, 7.98 and 16.88 mg/l respectively, while Sodium and Potassium concentration were obtained to be 0.90 and 0.67 mg/l respectively with Sodium Absorption Ratio (SAR of 0.25 mEq/l. From the analysis it indicates that the soil is low in salinity. Similarly for water sample analysis the pH is 7.7 which indicate that the water is slightly alkaline, EC is 0.8 ds/m, calcium and magnesium concentration were 0.48 and 0.35 mg/l, while sodium and potassium were 0.57 and 0.71 mg/l respectively, with Sodium Absorption Ratio (SAR of 0.89 meq/l, which shows that the water sample were found within the safe limit for irrigation. It can be recommended that application of good quality water, choice of salt tolerant crops and gypsum be adopted in the study area.

  2. Effects of Garcinia kola on the Lipid Profile of Alloxan-Induced Diabetic Wistar Rats

    OpenAIRE

    Nwangwa, E. K.

    2012-01-01

    In this study, the effects of Garcinia kola on the lipid profile of alloxan-induced diabetic Wistar rats were studied. A total of twenty four (24) albino rats of wistar strain weighing between 100-150 g were made diabetic by single freshly prepared intraperitoneal injection of 150 mg/dL of alloxan monohydrate. Eight (8) weeks after confirmation of diabetes, the rats were randomly divided into four (4) experimental groups (n = 6). Group I (Control) rats were treated with 1ml of 5% ethanol, Gro...

  3. Profesionalna zrelost učenika viših razreda osnovnih škola

    OpenAIRE

    BABAROVIĆ, Toni; Šverko, Iva

    2011-01-01

    Profesionalna zrelost je spremnost pojedinca da na temelju detaljnog istraživanja svojih osobina i prikupljanja informacija o svijetu rada isplanira svoj profesionalni put i donese realnu odluku o svojoj karijeri. Cilj ovog rada bio je utvrditi razinu profesionalne zrelosti učenika viših razreda osnovne škola te ustanoviti u kojoj je mjeri profesionalna zrelost povezana s nekim obilježjima učenika. Na reprezentativnim uzorcima učenika petih, šestih, sedmih i osmih razreda oba spola (ukupni N ...

  4. Field experience of new nuclear fuel types on the Kola NPP

    International Nuclear Information System (INIS)

    Specificity of the Kola nuclear power plant geographical position, conditions of region economics determine fuel management strategy. Isolation of Kola power supply system and, as a consequence, generating capacities redundancy cause operation of the nuclear power plant on reduced power level. At the same time there is a need to operate the power unit on the maximum power level in the case of not planned conditions. The basis of in-core fuel management is an achievement of the maximal burnup under providing of high installed capacity. At present there are not abilities to improve the fuel cycle based on traditional implementation fuel assemblies. Burnup maximum in these fuel cycles is achieved. At the core periphery installed highest possible quantity of the burned-up assemblies in the view of safety operation margins satisfaction. Works on application of the second generation fuel have been carried out on the Kola NPP since 2002. Fuel assemblies of this type are profiled. Burnable absorber, changed lattice spacing in relation to standard fuel, changed height of a fuel column, thickness of fuel pin clad are applied. In CR fuel followers modernized docking unit (with hafnium plates are intended for energy-release splash suppression) is used. At present 2-nd generation fuel is in experimental operation on unit 3 (18-21 fuel cycles, 2002-2007 years) and unit 4 (18-19 fuel cycles, 2005-2007 years). Safety margins did not exceeded. Coolant activity did not exceed the limiting value. There were not damaged fuel assemblies of second generation. Originally in the project of applications of new fuel it was supposed to refuel annually 78 fresh assemblies. At the moment annual refueling consists of 66 assemblies with effective enrichment 3.82 %. Cycle duration does not exceed 250-260 effective days. The part of assemblies is left on 5-th cycle of operation. In a similar fuel cycle in 2007 on the unit 1 operation with profiled fuel (enrichment of 3.82 %) of shakeproof type

  5. In Vitro Antilisterial Properties of Crude Methanol Extracts of Garcinia kola (Heckel Seeds

    Directory of Open Access Journals (Sweden)

    Dambudzo Penduka

    2012-01-01

    Full Text Available Crude methanol extracts of Garcinia kola (Heckel seeds were screened for their antilisterial activities against 42 Listeria bacteria isolated from wastewater effluents. The extract had activity against 45% of the test bacteria and achieved minimum inhibitory concentrations (MICs ranging between 0.157 and 0.625 mg/mL. The rate of kill of the extract was determined against four representative Listeria species in the study, and the results showed that the highest percentage of bacteria cells were killed after the maximum exposure time of 2 h at the highest concentration of 4×MIC value, with the maximum number of bacteria cells killed being for L. ivanovii (LEL 30 100%, L. monocytogenes (LAL 8 94.686%, L. ivanovii (LEL 18 60.330%, and L. grayi (LAL 15 56.071% We therefore conclude that the nature of inhibition of the crude methanol extracts of Garcinia kola seeds can be either bactericidal or bacteriostatic depending on the target Listeria species and can also differ among same species as evidenced by L. ivanovii strains LEL 30 and LEL 18.

  6. Widespread tannin intake via stimulants and masticatories, especially guarana, kola nut, betel vine, and accessories.

    Science.gov (United States)

    Morton, J F

    1992-01-01

    Tannins are increasingly recognized as dietary carcinogens and as antinutrients interfering with the system's full use of protein. Nevertheless, certain tannin-rich beverages, masticatories, and folk remedies, long utilized in African, Asiatic, Pacific, and Latin American countries, are now appearing in North American sundry shops and grocery stores. These include guarana (Paullinia cupana HBK.) from Brazil, kola nut (Cola nitida Schott & Endl. and C. acuminata Schott & Endl.) from West Africa, and betel nut (Areca catechu L.) from Malaya. The betel nut, or arecanut, has long been associated with oral and esophageal cancer because of its tannin content and the tannin contributed by the highly astringent cutch from Acacia catechu L. and Uncaria gambir Roxb. and the aromatic, astringent 'pan' (leaves of Piper betel L.) chewed with it. In addition to the constant recreational/social ingestion of these plant materials, they are much consumed as aphrodisiacs and medications. Guarana and kola nut enjoy great popularity in their native lands because they are also rich in caffeine, which serves as a stimulant. Research and popular education on the deleterious effects of excessive tannin intake could do much to reduce the heavy burden of early mortality and health care, especially in developing countries. PMID:1417698

  7. Characterization of crystalline rocks in deep boreholes. The Kola, Krivoy Rog and Tyrnauz boreholes

    International Nuclear Information System (INIS)

    SKB studies, as one alternative, the feasibility of disposing of spent nuclear fuel in very deep boreholes. As a part of this work NEDRA has compiled geoscientific data from three superdeep boreholes within the former Soviet Union. The holes considered were: the Kola borehole, 12261 m deep and located on the Kola Peninsula, the Krivoy Rog borehole, 5000 m deep and located in Ukraine, and the Tyrnauz borehole, 4001 m deep and located between the Black Sea and the Caspian Sea. These boreholes all penetrate crystalline formations, but major differences are found when their tectonic environments are compared. Excluding the uppermost horizon affected by surface phenomena, data do not indicate any general correlation between depth and the state of rock fracturing, which is instead governed by site specific, lithological and tectonical factors. This applies also to fracture zones, which are found at similar frequencies at all depths. As opposed to the structural data, the hydrogeological and hydrochemical information reveals a vertical zonation, with clear similarities between the three boreholes. An upper zone with active circulation and fresh or slightly mineralized groundwaters reaches down 1000-2000 m. The interval from 1000-2000 m down to 4000-5000 m can be characterized as a transition zone with lower circulation rates and gradually increasing mineralisation. Below 4000-5000 m, strongly mineralized, stagnant, juvenile or metamorphogenic waters are found. Geothermal data verify the existence of this zonation. 28 figs, 30 tabs

  8. A refinement of the emission data for Kola Peninsula based on inverse dispersion modelling

    Directory of Open Access Journals (Sweden)

    M. Prank

    2010-11-01

    Full Text Available The study reviews the emission estimates of sulphur oxides (SOx and primary particulate matter (PM from the major industrial sources of Kola Peninsula. Analysis of the disagreements between the existing emission inventories for the Kola region combined with forward and inverse ensemble dispersion modelling, analysis of observation time-series and model-measurement comparison showed that the emission of the Nikel metallurgy plant was missing or strongly under-estimated in the major European emission inventories, such as EMEP, EDGAR, TNO-GEMS, and PAREST-MEGAPOLI. In some cases it was misplaced or mis-attributed to other sources of the region. A more consistent inventory of the anthropogenic emissions of SOx and PM has been compiled for the Peninsula, compared with the existing estimates and verified by means of dispersion modelling. In particular, the SILAM model simulations for 2003 and 2006 with the revised emission data showed much smaller under-estimation of SO2 concentrations at 8 Finnish and Norwegian observational stations. For the nearest site to the plant the 10-fold underestimation turned to a 1.5-fold over-prediction. Temporal correlation improved more moderately (up to 45% for concentrations, up to 3 times for deposition. The study demonstrates the value of a combined usage of forward and inverse ensemble modelling for source apportionment in case of limited observational data.

  9. Petrochemistry and petrology of I-type granitoids in an arc setting: the composite Torul pluton, Eastern Pontides, NE Turkey

    Science.gov (United States)

    Kaygusuz, Abdullah; Siebel, Wolfgang; Şen, Cüneyt; Satir, Muharrem

    2008-07-01

    The Upper Cretaceous Torul pluton, located in the Eastern Pontides, is of sub-alkaline affinity and displays features typical of volcanic arc granitoids. It is a composite pluton consisting of granodiorite, biotite hornblende monzogranite, quartz monzodiorite, quartz monzonite and hornblende biotite monzogranite. The oldest syenogranite (77.9 ± 0.3 Ma) and the youngest quartz diorite form small stocks within the pluton. Samples from the granodiorites, biotite hornblende monzogranites, quartz monzodiorites, quartz monzonites and hornblende biotite monzogranites have SiO2 between 57 and 68 wt% and display high-K calc-alkaline, metaluminous to peraluminous characteristics. Chondrite-normalized REE patterns are fractionated (Lacn/Lucn = 6.0-14.2) with pronounced negative Eu anomalies (Eu/Eu* = 0.59-0.84). Initial ɛNd(i) values vary between -3.1 and -4.1, initial 87Sr/86Sr values between 0.7058 and 0.7072, and δ18O values between +4.4 and +7.3‰. The quartz diorites are characterized by relatively high Mg-number of 36-38, low contents of Na2O (2.3-2.5 wt%) and SiO2 (52-55 wt%) and medium-K calc-alkaline, metaluminous composition. Chondrite-normalized REE patterns are relatively flat [(La/Yb)cn = 2.8-3.3; (Tb/Yb)cn = 1.2] and show small negative Eu anomalies (Eu/Eu* = 0.74-0.76). Compared to the other rock types, radiogenic isotope signatures of the quartz diorites show higher 87Sr/86Sr (0.7075-0.7079) and lower ɛNd(i) (-4.5 to -5.3). The syenogranites have high SiO2 (70-74 wt%) and display high-K calc-alkaline, peraluminous characteristics. Their REE patterns are characterized by higher Lacn/Lucn (12.9) and Eu/Eu* (0.76-0.77) values compared to the quartz diorites. Isotopic signatures of these rocks [ɛNd(i) = -4.0 to -3.3; 87Sr/86Sr(i) = 0.7034-0.7060; δ18 O = + 4.9 to + 8.2] are largely similar to the other rock types but differ from that of the quartz diorites. Fractionation of plagioclase, hornblende, pyroxene and Fe-Ti oxides played an important role in the

  10. Les granitoïdes néoprotérozoïques de Khzama, Anti-Atlas central, Maroc: marqueurs de l'évolution d'un magmatisme d'arc à un magmatisme alcalineNeoproterozoic granitoids from Khzama, central Anti-Atlas, Morocco: evolution markers from arc magmatism to alkaline magmatism

    Science.gov (United States)

    El-Khanchaoui, T.; Lahmam, M.; El-Boukhari, A.; El-Beraaouz, H.

    2001-05-01

    Petrological study and zircon typology provide important information that is related to the classification and genesis of Neoproterozoic granitoids in the Khzama area (northeast Siroua). The Pan-African granitoids show a transition from island-arc magmatism to alkaline magmatism. A space and time zonation of magmatism from the north to the south is evident. Early Pan-African granitoids were generated from various magma sources through different petrogenetic mechanisms. The first association corresponds to the low-K calc-alkaline plutons of Ait Nebdas, the second one correponds to high-K calc-alkaline post-collisional granites (Tamassirte-Tiferatine and Ifouachguel). Finally, shoshonitic magmatism (Irhiri) ends the magmatic evolution of the region. Thus, the late Pan-African granitic plutonism began with calc-alkaline associations and ended with K-alkaline magmatism in a transtensional setting, heralding the onset of the Moroccan Palæozoic cycle.

  11. Radioactive sources of main radiological concern in the Kola-Barents region

    International Nuclear Information System (INIS)

    This overview focuses on some major issues for risk analysis appearing in our recent study surveying radioactive sources on the Kola Peninsula, along with adjacent parts of the Arctic seas. The main issues of the parts are as follows: An introduction to the presence of radioactive sources and environmental contamination in the Barents Euro-Arctic Region and the current status as regards various significant studies. Radioactive contamination in man and the environment on the Kola Peninsula, as well as radioactive transfer during the last three decades from external sources to the Kola-Barents region. The main conclusion from the findings is that the contamination is generally relatively low and that neither the activity levels in samples of soil, vegetation, and the important food-chains, nor the content in man indicate any changes since 1986 that could not be explained by the combined effect of the cumulative deposition from the nuclear weapons testing and the accident in Chernobyl. The radioactive sources of main concern in the region belong to the following categories: nuclear power submarine and cruiser naval bases; civil nuclear power ice-breaker fleet; building and repairing shipyards; nuclear power plants; radioactive waste and spent nuclear fuel storage facilities; sunken reactors/ships; liquid radioactive waste dumping; solid radioactive waste dumping; nuclear weapon bases; nuclear weapon tests; civil nuclear explosions; nuclear accidents; mining radioactive ore deposits and plants; new projects and others. Several case studies concerning releases in the Kola-Barents region are reviewed, and followed by consequence analyses for the categories of primary interest covering: a) airborne releases from the Kola NPP, and from submarines or spent nuclear fuel; b) releases from objects in the marine environment including submarines, dumped reactors, and various other radioactive objects and waste; c) releases from liquid and solid wastes stored on land or during

  12. Radioactive sources of main radiological concern in the Kola-Barents region

    Energy Technology Data Exchange (ETDEWEB)

    Bergman, R.; Baklanov, A

    1998-07-01

    This overview focuses on some major issues for risk analysis appearing in our recent study surveying radioactive sources on the Kola Peninsula, along with adjacent parts of the Arctic seas. The main issues of the parts are as follows: An introduction to the presence of radioactive sources and environmental contamination in the Barents Euro-Arctic Region and the current status as regards various significant studies. Radioactive contamination in man and the environment on the Kola Peninsula, as well as radioactive transfer during the last three decades from external sources to the Kola-Barents region. The main conclusion from the findings is that the contamination is generally relatively low and that neither the activity levels in samples of soil, vegetation, and the important food-chains, nor the content in man indicate any changes since 1986 that could not be explained by the combined effect of the cumulative deposition from the nuclear weapons testing and the accident in Chernobyl. The radioactive sources of main concern in the region belong to the following categories: nuclear power submarine and cruiser naval bases; civil nuclear power ice-breaker fleet; building and repairing shipyards; nuclear power plants; radioactive waste and spent nuclear fuel storage facilities; sunken reactors/ships; liquid radioactive waste dumping; solid radioactive waste dumping; nuclear weapon bases; nuclear weapon tests; civil nuclear explosions; nuclear accidents; mining radioactive ore deposits and plants; new projects and others. Several case studies concerning releases in the Kola-Barents region are reviewed, and followed by consequence analyses for the categories of primary interest covering: a) airborne releases from the Kola NPP, and from submarines or spent nuclear fuel; b) releases from objects in the marine environment including submarines, dumped reactors, and various other radioactive objects and waste; c) releases from liquid and solid wastes stored on land or during

  13. A ground-validated NDVI dataset for monitoring vegetation dynamics and mapping phenology in Fennoscandia and the Kola peninsula

    NARCIS (Netherlands)

    Beck, P.S.A.; Jonsson, P.; Hogda, K.A.; Karlsen, S.R.; Skidmore, A.K.; Eklundh, L.

    2007-01-01

    An NDVI dataset covering Fennoscandia and the Kola peninsula was created for vegetation and climate studies, using Moderate Resolution Imaging Spectroradiometer 16-day maximum value composite data from 2000 to 2005. To create the dataset, (1) the influence of the polar night and snow on the NDVI val

  14. Sheeted and bulbous pluton intrusion mechanisms of a small granitoid from southeastern Australia: implications for dyke-to-pluton transformation during emplacement

    Science.gov (United States)

    Fowler, T. J.

    1994-06-01

    The small late syn-tectonic Carboniferous Davys Creek Granite (DCG) of southeastern Australia consists of microgranitic intrusive bodies of diverse geometry and structure. These bodies include: (1) subvertical concordant sheets; (2) bulbous peneconcordant plutons with apophyses and discordant lobes; and (3) subvertical dykes and stocks. The sequence of changing intrusive style is broadly 1-2-3. Transition from 1 to 2 was probably a response to rising magma pressures or declining tectonic stresses. The λ parameter of Emerman and Marrett (1990), which discriminates between stable sheet-like and potential stock/pluton/batholith emplacement modes, adequately predicts the transitions between sheet and pluton emplacements for the DCG. Ductile dyking along actively forming foliations appears to have been an important early intrusive mechanism. A transition from sheet to bulbous pluton intrusion style is suggested to have been in response to magma pressure increases.

  15. ISTRAŽIVANJE PRIPREMLJENOSTI UČENIKA SREDNJIH TRGOVAČKIH, EKONOMSKIH I UPRAVNIH ŠKOLA ZA NASTAVAK OBRAZOVANJA NA SRODNIM FAKULTETIMA

    OpenAIRE

    Miletić, Josip

    2015-01-01

    Cilj je rada ustvrditi jesu li polaznici četverogodišnjih strukovnih škola koji se obrazuju po programima za područje ekonomije, trgovine i poslovne administracije bolje pripremljeni za upis srodnih fakulteta, koji znače nastavak njihove obrazovne vertikale, od učenika ostalih strukovnih škola, pa i gimnazijalaca, koji se obrazuju po drugačijim programima hrvatskoga jezika. Autor je među učenicima četvrtih razreda ekonomskih i upravnih škola proveo istraživanje u obliku testa koji uključuje g...

  16. Albitization and the gold-bearing Roodepoort pluton, Pietersburg granite-greenstone terrane, South Africa

    International Nuclear Information System (INIS)

    The gold bearing Roodepoort pluton in the Pietersburg granite-greenstone terrane of South Africa consists primarily of undeformed albite with lesser amounts of quartz, ankerite, magnesite, and pyrite. The pluton intruded a major N-70 degrees trending shear zone, the Knight's Pietersburg line. The present mineralogy of the pluton and its gold content are essentially secondary, formed by open system hydrothermal alteration. However, relic minerals indicate that the pluton originally had a granodioritic composition. This composition, as well as its initial 87Sr/86Sr ratio, are similar to those of the 2 660 Ma Turfloop batholith and are consistent with the possibility that the Roodepoort pluton is an altered phase of the batholith. Sr isotopic data also suggest that hydrothermal alteration occured shortly after the magmatic crystallization of the pluton. Some alteration along the Knight's Pietersburg line occured about 2 680 Ma ago. It is proposed that the emplacement of the Roodepoort pluton, the hydrothermal alteration and the gold mineralization are related to the Limpopo Orogeny. A second phase of open system hydrothermal alteration occured in shear zones along the margins of and within the Roodepoort pluton, apparently about 2 320 Ma ago. 5 figs., 5 tabs., 27 refs

  17. Guidelines to classification and nomenclature of Arabian felsic plutonic rocks

    Science.gov (United States)

    Ramsay, C.R.; Stoeser, D.B.; Drysdall, A.R.

    1986-01-01

    Well-defined procedures for classifying the felsic plutonic rocks of the Arabian Shield on the basis of petrographic, chemical and lithostratigraphic criteria and mineral-resource potential have been adopted and developed in the Saudi Arabian Deputy Ministry for Mineral Resources over the past decade. A number of problems with conventional classification schemes have been identified and resolved; others, notably those arising from difficulties in identifying precise mineral compositions, continue to present difficulties. The petrographic nomenclature used is essentially that recommended by the International Union of Geological Sciences. Problems that have arisen include the definition of: (1) rocks with sodic, zoned or perthitic feldspar, (2) trondhjemites, and (3) alkali granites. Chemical classification has been largely based on relative molar amounts of alumina, lime and alkalis, and the use of conventional variation diagrams, but pilot studies utilizing univariate and multivariate statistical techniques have been made. The classification used in Saudi Arabia for stratigraphic purposes is a hierarchy of formation-rank units, suites and super-suites as defined in the Saudi Arabian stratigraphic code. For genetic and petrological studies, a grouping as 'associations' of similar and genetically related lithologies is commonly used. In order to indicate mineral-resource potential, the felsic plutons are classed as common, precursor, specialized or mineralized, in order of increasing exploration significance. ?? 1986.

  18. U/Pb Zircon Ages of Plutons from the Central Appalachians and GIS-Based Assessment of Plutons with Comments on Their Regional Tectonic Significance

    OpenAIRE

    Wilson, John Robert

    2001-01-01

    The rocks of the Appalachian orogen are world-class examples of collisional and extensional tectonics, where multiple episodes of mountain building and rifting from the pre-Cambrian to the present are preserved in the geologic record. These orogenic events produced plutonic rocks, which can be used as probes of the thermal state of the source region. SIMS (secondary ion mass spectrometry) U/Pb ages of zircons were obtained for ten plutons (Leatherwood, Rich Acres, Melrose, Buckingham, Diana ...

  19. Crystal structure of hydrogen-bearing vuonnemite from the Lovozero alkaline massif

    Energy Technology Data Exchange (ETDEWEB)

    Rastsvetaeva, R. K., E-mail: rast@ns.crys.ras.ru; Aksenov, S. M.; Verin, I. A. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Lykova, I. S. [Moscow State University (Russian Federation)

    2011-05-15

    Hydrogen-bearing vuonnemite from the Shkatulka hyperagpaitic pegmatite (the Lovozero alkaline massif, Kola Peninsula) was studied by single-crystal X-ray diffraction. The triclinic unit-cell parameters are as follows: a = 5.4712(1) Angstrom-Sign , b = 7.1626(1) Angstrom-Sign , c = 14.3702(3) Angstrom-Sign , {alpha} = 92.623(2) Degree-Sign , {beta} = 95.135(1) Degree-Sign , {gamma} = 90.440(1) Degree-Sign , sp. gr. P1, R = 3.4%. The Na{sup +} cations and H{sub 2}O molecules are ordered in sites between the packets. The water molecules are hydrogen bonded to the PO{sub 4} tetrahedra.

  20. Age and intrusive relations of the Lamarck granodiorite and associated mafic plutons, Sierra Nevada, California

    Energy Technology Data Exchange (ETDEWEB)

    Joye, J.L.; Bachl, C.A.; Miller, J.S.; Glazner, A.F. (Univ. of North Carolina, Chapel Hill, NC (United States). Dept. of Geology); Frost, T.P. (Geological Survey, Spokane, WA (United States)); Coleman, D.S. (Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Earth, Atmospheric and Planetary Sciences)

    1993-04-01

    The compositionally zoned Late Cretaceous Lamarck granodiorite, west of Bishop, hosts numerous mafic intrusions ranging from hornblende gabbro to mafic granodiorite. Frost and Mahood (1987) suggested from field relations that the Lamarck and the associated mafic plutons were co-intrusive. Contact relations between the Lamarck host and the mafic intrusions are variable (sharp to diffuse) and in places suggest commingling. In order to constrain the intrusive relationships between the Lamarck and its associated mafic plutons, the authors have analyzed feldspars from the Mt. Gilbert pluton and the Lamarck granodiorite to see if feldspar compositions in the Mt. Gilbert overlap those in the Lamarck host and determined U-Pb zircon ages for the Mt. Gilbert and Lake Sabrina plutons to see if they have the same age as the Lamarck granodiorite. Feldspars from the Lamarck granodiorite are normally zoned and range compositionally from An[sub 38--32]; those in the Mt. Gilbert diorite are also normally zoned but range compositionally from An[sub 49--41] and do not overlap the Lamarck host. Four to five zircon fractions from each pluton were handpicked and dated using U-Pb methods. The Mt. Gilbert mafic diorite has a concordant age of 92.5 Ma and the Lake Sabrina diorite has a concordant age of 91.5 Ma. Ages for the two plutons overlap within error, but multiple fractions from each suggest that the Lake Sabrina pluton is slightly younger than the Mt. Gilbert pluton. These data and field relationships indicate: (1) plagioclase phenocrysts in the Mt. Gilbert pluton were not derived from the Lamarck granodiorite despite their textural similarity; but (2) the Lamarck granodiorite and its associated mafic plutons are co-intrusive as supported by the close agreement of the ages with the crystallization age obtained by Stern and others for the Lamarck granodiorite.

  1. ABCGheritage project - promoting geotourism in northern Finland, northern Norway and the Kola Peninsula

    Science.gov (United States)

    Pihlaja, Jouni; Johansson, Peter; Lauri, Laura S.

    2014-05-01

    Nature tourism has been a growing business sector in the Barents area during the recent decades. With the purpose to develop nature tourism in a sustainable way, a cooperation project ABCGheritage - Arctic Biological, Cultural and Geological Heritage has been carried out. Project has received partial funding from the EU Kolarctic ENPI program. In the geoheritage part of the project the main activities were aimed to develop pro-environmental ways of geotourism in the area. The three main participants in the geoheritage part of the project are the Geological Survey of Finland, Northern Finland Office, the Geological Institute of the Kola Science Centre of the Russian Academy of Sciences and Bioforsk Soil and Environment from northeastern Norway. The duration of the project is 2012-2014 and most of the work has already been completed even if most of the results are not published yet. Totally ten different tasks have been implemented in the geological part of the project. The largest task has been the preparation of a geological outdoor map and guide book of the Khibiny Tundra locating in the central part of the Kola Peninsula. In Finland already 11 such maps have been published, and the experiences gained during their production have been used in this project, too. Geological heritage trails to the Khibiny Tundra have also been created and they will be drawn on the map. The second concrete result is the Barents Tour for Geotourist -guide, which will be published as a guide book, web pages and an exhibition. The route comprises ca 35 best geological demonstration sites along the circle route from northern Finland to northeastern Norway, from there to Kola Peninsula and then back to Finland. Information of the route will be available for all interested travelers. In addition to the geological outdoor map of the Khibiny Tundra and "Barents Tour for Geotourists"-guide, the primary outputs of the project are the geological nature trails on the field, geological

  2. Melt segregation evidence from a young pluton, Takidani Granodiorite (Japan)

    Science.gov (United States)

    Hartung, Eva; Caricchi, Luca; Floess, David; Wallis, Simon; Harayama, Satoru; Chiaradia, Massimo; Kouzmanov, Kalin

    2016-04-01

    We are presenting new petrological data from one of the youngest exposed plutons in the world, the Takidani Granodiorite (Japan), which has been suggested as a source for large volume ignimbrites (> 300km3). Takidani Granodiorite (1.54 Ma ± 0.23 Ma) is located within the active Norikura Volcanic Chain in the Northen Japan Alps and has been previously linked to large andesitic (1.76 Ma ± 0.17 Ma) and rhyolitic eruptions (1.75 Ma ± 0.17 Ma). The pluton is vertically zoned and consists of granites (67 to 68 wt.% SiO2) in the lower section, granodiorites (65 to 66 wt.% SiO2) in the middle section, a chemically more evolved fine-grained porphyritic unit (67 to 71 wt.% SiO2) near the roof and a marginal granodiorite at the roof (67 to 68 wt.% SiO2). The porphyritic texture of the more evolved unit near the roof indicates rapid crystallisation, which could be the result of the late intrusion of this unit at the roof of the magmatic system. However, no sharp contact is found between the underlying granodiorite and the porphyritic unit. Instead, a gradual change in rock fabric, whole-rock chemistry and mineralogy is observed suggesting that melt was extracted from the granodiorite. Electron microprobe analyses of plagioclases show three main crystal populations (Type I, II and III) with distinct anorthite and Fe contents. Type I plagioclase (An30‑40) occurs dominantly within the marginal granodiorite at the roof. Type II plagioclase (An40‑45) are common in the granodiorite and porphyritic unit. Type III plagioclase (An45‑50) is predominantly present in the granite. All plagioclase populations share a common sodic rim (An22) across the different units. Takidani Granodiorite rocks are compared to crystallisation experiments from similar magmatic suites. Emplacement conditions of the Takidani Granodiorite are obtained from the latter as well as barometry, thermometry and hygrometry indicating that magmas were ultimately emplaced at around 200 MPa, 850° C to 875° C

  3. The primary circuit materials properties results analysis performed on archive material used in NPP V-1 and Kola NPP Units 1 and 2

    Energy Technology Data Exchange (ETDEWEB)

    Kupca, L.; Beno, P. [Nuclear Power Plants Research Institute Inc., Trnava (Slovakia)

    1997-04-01

    A very brief summary is provided of a primary circuit piping material properties analysis. The analysis was performed for the Bohunice V-1 reactor and the Kola-1 and -2 reactors. Assessment was performed on Bohunice V-1 archive materials and primary piping material cut from the Kola units after 100,000 hours of operation. Main research program tasks included analysis of mechanical properties, corrosion stability, and microstructural properties. Analysis results are not provided.

  4. Paleomagnetism of Devonian dykes in the northern Kola Peninsula and its bearing on the apparent polar wander path of Baltica in the Precambrian

    Science.gov (United States)

    Veselovskiy, Roman V.; Bazhenov, Mikhail L.; Arzamastsev, Andrey A.

    2016-04-01

    Mafic dykes and large alkaline and carbonatite intrusions of Middle-Late Devonian age are widespread on the Kola Peninsula in NE Fennoscandia. These magmatic rocks are well characterized with petrographic, geochemical and geochronological data but no paleomagnetic results have been reported yet. We studied dolerite dykes from the northern part of the Peninsula and isolated three paleomagnetic components in these rocks. A low-temperature component is aligned along the present-day field, while a major constituent of natural remanent magnetization is an intermediate-temperature component (Decl. = 79.6°, Inc. = 78.5°, α95 = 5,9°, N = 17 sites) that is present in most Devonian dykes but is found in some baked metamorphic rocks and Proterozoic dykes too. Finally, a primary Devonian component could be reliably isolated from two dykes only. Rock-magnetic studies point to presumably primary low-Ti titanomagnetite and/or pure magnetite as the main remanence carriers but also reveal alteration of the primary minerals and the formation of new magnetic phases. The directions of a major component differ from the Middle Paleozoic reference data for Baltica but closely match those for the 190 ± 10 Ma interval recalculated from the apparent polar wander path of the craton. We assume that this Early Jurassic component is a low-temperature overprint of chemical origin. The main impact of the new results is not to mid-Paleozoic or Early Mesozoic times but to much older epochs. Analysis of paleomagnetic data shows that the directionally similar remanences are present in objects with the ages ranging from 500 Ma to ~ 2 Ga over entire Fennoscandia. Hence we argue that an Early Jurassic remagnetization is of regional extent but cannot link it to a certain process and a certain tectonic event. If true, this hypothesis necessitates a major revision of the APWP for Baltica over a wide time interval.

  5. Rb-Sr isochronous age of Vepor pluton granitoids

    International Nuclear Information System (INIS)

    The result are presented of geochronological investigations of the Vepor pluton granitoids by the Rb-Sr isochronous method. The results prove the Variscan age of granodiorite magmatism of the Sihla type (387±27 m.y.) and the Early Variscan age of leucocratic granitoids of the Vepor and the Ipel types (284±22 m.y.). Since the initial ratio of 87Sr/86Sr in granitoids of the Sihla type is 0.7054 and of the Vepor type 0.7060, it can be assumed that during the formation of the granitoids of veporides there was an increased supply of matter from the main source affecting genesis of granitoids. The results prove a polyphase character of the Variscan granitoids of Veporicum. (author)

  6. Cretaceous plutonic rocks in the Donner Lake-Cisco Grove area, northern Sierra Nevada, California

    Science.gov (United States)

    Kulow, Matthew J.; Hanson, Richard E.; Girty, Gary H.; Girty, Melissa S.; Harwood, David S.

    1998-01-01

    The northernmost occurrences of extensive, glaciated exposures of the Sierra Nevada batholith occur in the Donner Lake-Cisco Grove area of the northern Sierra Nevada. The plutonic rocks in this area, which are termed here the Castle Valley plutonic assemblage, crop out over an area of 225 km2 and for the most part are shown as a single undifferentiated mass on previously published geological maps. In the present work, the plutonic assemblage is divided into eight separate intrusive units or lithodemes, two of which each consist of two separate plutons. Compositions are dominantly granodiorite and tonalite, but diorite and granite form small plutons in places. Spectacular examples of comb layering and orbicular texture occur in the diorites. U-Pb zircon ages have been obtained for all but one of the main units and range from ~120 to 114 Ma, indicating that the entire assemblage was emplaced in a narrow time frame in the Early Cretaceous. This is consistent with abundant field evidence that many of the individual phases were intruded penecontemporaneously. The timing of emplacement correlates with onset of major Cretaceous plutonism in the main part of the Sierra Nevada batholith farther south. The emplacement ages also are similar to isotopic ages for gold-quartz mineralization in the Sierran foothills west of the study area, suggesting a direct genetic relationship between the voluminous Early Cretaceous plutonism and hydrothermal gold mineralization.

  7. Technology of production of high-level concentrate of rare earths from Kola apatite

    International Nuclear Information System (INIS)

    The procedure is described of separating rare earth elements from the Kola apatite which contains 0.7 to 1.0% oxides of rare earths. The separation takes place during the manufacture of combined fertilizer NPK-1. During the manufacture of the fertilizer the solution is neutralized with the precipitation of phosphates of rare earths. Increasing pH is accompanied by increased yield of the sum of rare earths. The yield is higher for lighter lanthanoids than for heavier lanthanoids. The phosphate concentrate is decomposed by nitric acid and rare earth elements are precipitated by oxalic acid. Following the annealing of the oxalate concentrate the obtained oxide concentrate will contain 92 to 95% oxides of rare earths. (E.S.)

  8. Why are plutons dry? Outgassing mechanisms of crustal magmatic bodies

    Science.gov (United States)

    parmigiani, andrea; Huber, Christian; Bachmann, Olivier; Leclaire, Sébastien

    2016-04-01

    Magma bodies crystallizing to completion within the crust (i.e., forming plutons) typically undergo significant amounts of second boiling (i.e. cooling and crystallization of dominantly anhydrous minerals lead to volatile saturation and bubble nucleation/growth). The low water content ( 6 wt % H2O for evolved compositions in subduction zones), testify that outgassing from crystalline mushy reservoirs must be an efficient and widespread process. Understanding this outgassing mechanism is key to understand how volatiles are transferred from mantle depths to the surface. From the hydrodynamics point of view, the mass balance of exsolved volatiles in these plutonic bodies is controlled by the difference between the rate of degassing (formation of bubbles by 2nd boiling) and outgassing (transport of gas out of the magma body). In this study, we use pore-scale multiphase modeling to constrain these rates as function of the crystal and volatile contents in the magma. Because second boiling is a slow process, one can consider equilibrium degassing as a valid assumption. Outgassing, on the other end, is controlled by the competition between buoyancy, capillary and viscous forces. Our numerical simulations are used to determine the most efficient setting for gas to escape its magmatic trap. The high viscosity of interstitial melts and capillary forces (due to the non-wetting nature of the gas phase with most of the mineral phases in magmatic systems) strongly limits gas transport until vertically extensive gas channels are generated. We show that channels can readily form in volatile-rich coarse-grained mush zones in the upper crust, and allow efficient outgassing at crystallinities around 50-75 vol%, when millimetric bubbles can still win capillary resistive forces.

  9. Ten year trend analysis of malaria prevalence in Kola Diba, North Gondar, Northwest Ethiopia

    Directory of Open Access Journals (Sweden)

    Alemu Abebe

    2012-08-01

    Full Text Available Abstract Background Malaria is caused by protozoan parasites of the genus Plasmodium. It is one of the leading causes of illness and death in the world. It is a major public health problem in Ethiopia. Over the past years, the disease has been consistently reported as the first leading cause of outpatient visits, hospitalization and death in health facilities across the country. Methods A retrospective study was conducted to determine the prevalence of malaria from peripheral blood smear examinations from the Kola Diba Health Center of Ethiopia. The case notes of all malaria cases reported between 2002–2011 were carefully reviewed and analyzed. Additionally, any malaria intervention activities that had been taken to control malaria were collected using a well-prepared checklist from the study area. Results Within the last decade (2002–2011 a total of 59, 208 blood films were requested for malaria diagnosis in Kola Diba health center and 23,473 (39.6% microscopically confirmed malaria cases were reported in the town with a fluctuating trend. Regarding the identified plasmodium species, Plasmodium falciparum and Plasmodium vivax accounted for 75% and 25% of malaria morbidity, respectively. Malaria was reported in all age groups and both sexes, but the 15–44 year age group and males were more affected. Despite the apparent fluctuation of malaria trends in the area, the highest peak of malaria cases was reported during spring seasons. Conclusion Comparatively, after the introduction of the current malaria control strategies, the morbidity and mortality by malaria is decreasing but malaria is still a major health problem and the deadly species P. falciparium is predominant. Therefore, control activities should be continued in a strengthened manner in the study area considering both P. falciparium and P. vivax.

  10. An Archean Geomagnetic Reversal in the Kaap Valley Pluton, South Africa

    Science.gov (United States)

    Layer; Kroner; McWilliams

    1996-08-16

    The Kaap Valley pluton in South Africa is a tonalite intrusion associated with the Archean Barberton Greenstone Belt. Antipodal paleomagnetic directions determined from the central and marginal parts of the pluton record a geomagnetic reversal that occurred as the pluton cooled. The age of the reversal is constrained by an 40Ar/39Ar plateau age from hornblende at 3214 +/- 4 million years, making it the oldest known reversal. The data presented here suggest that Earth has had a reversing, perhaps dipolar, magnetic field since at least 3.2 billion years ago. PMID:8688075

  11. Oster pluton (Central Karelia) - the ancient massif of two-feldspar granites of Baltic Shield

    International Nuclear Information System (INIS)

    Geochronological study of two-feldspar granites forming the Oster pluton in the Central Karelia was performed using the methods of U-Pb- and Sm-Nd-dating. U-Pb isotope data for zircons from granite of the Oster pluton correspond to the age of 2876±21 mln. years, whereas Sm-Nd isotope data obtained for three samples of the garnet correspond to the age varying from 3.0 to 3.5 bln. years. The ancient age of granites of the Oster pluton is explained by the presence of a sufficiently powerful crust in the region by that moment

  12. Alkaline quinone flow battery.

    Science.gov (United States)

    Lin, Kaixiang; Chen, Qing; Gerhardt, Michael R; Tong, Liuchuan; Kim, Sang Bok; Eisenach, Louise; Valle, Alvaro W; Hardee, David; Gordon, Roy G; Aziz, Michael J; Marshak, Michael P

    2015-09-25

    Storage of photovoltaic and wind electricity in batteries could solve the mismatch problem between the intermittent supply of these renewable resources and variable demand. Flow batteries permit more economical long-duration discharge than solid-electrode batteries by using liquid electrolytes stored outside of the battery. We report an alkaline flow battery based on redox-active organic molecules that are composed entirely of Earth-abundant elements and are nontoxic, nonflammable, and safe for use in residential and commercial environments. The battery operates efficiently with high power density near room temperature. These results demonstrate the stability and performance of redox-active organic molecules in alkaline flow batteries, potentially enabling cost-effective stationary storage of renewable energy. PMID:26404834

  13. Alkaline broadening in Stars

    CERN Document Server

    De Kertanguy, A

    2015-01-01

    Giving new insight for line broadening theory for atoms with more structure than hydrogen in most stars. Using symbolic software to build precise wave functions corrected for ds;dp quantum defects. The profiles obtained with that approach, have peculiar trends, narrower than hydrogen, all quantum defects used are taken from atomic database topbase. Illustration of stronger effects of ions and electrons on the alkaline profiles, than neutral-neutral collision mechanism. Keywords : Stars: fundamental parameters - Atomic processes - Line: profiles.

  14. Alkaline quinone flow battery

    OpenAIRE

    Lin, Kaixiang; Chen, Qing; Gerhardt, Michael; Tong, Liuchuan; Kim, Sang Bok; Eisenach, Louise Ann; Valle, Alvaro West; Hardee, D.; Gordon, Roy Gerald; Aziz, Michael J.; Marshak, M

    2015-01-01

    Storage of photovoltaic and wind electricity in batteries could solve the mismatch problem between the intermittent supply of these renewable resources and variable demand. Flow batteries permit more economical long-duration discharge than solid-electrode batteries by using liquid electrolytes stored outside of the battery. We report an alkaline flow battery based on redox-active organic molecules that are composed entirely of Earth-abundant elements and are nontoxic, nonflammable, and safe f...

  15. In Vitro Anti-Listerial Activities of Crude n-Hexane and Aqueous Extracts of Garcinia kola (heckel) Seeds

    OpenAIRE

    Okoh, Anthony I.; Dambudzo Penduka

    2011-01-01

    We assessed the anti-Listerial activities of crude n-hexane and aqueous extracts of Garcinia kola seeds against a panel of 42 Listeria isolates previously isolated from wastewater effluents in the Eastern Cape Province of South Africa and belonging to Listeria monocytogenes, Listeria grayi and Listeria ivanovii species. The n-hexane fraction was active against 45% of the test bacteria with zones of inhibition ranging between 8–17 mm, while the aqueous fraction was active against 29% with zone...

  16. In-Vitro Antagonistic Characteristics of Crude Aqueous and Methanolic Extracts of Garcinia kola (Heckel) Seeds against Some Vibrio Bacteria

    OpenAIRE

    Okoh, Anthony I.; Dambudzo Penduka; Omobola O. Okoh

    2011-01-01

    The methanolic and aqueous extracts of Garcinia kola seeds were screened for their anti-Vibrio activities against 50 Vibrio isolates obtained from wastewater final effluents in the Eastern Cape Province, South Africa. The crude extracts at 10 mg/mL exhibited appreciable inhibitory activities against most of the test Vibrio isolates, with zones of inhibition ranging from 10–19 mm for methanol extract and 8–15 mm for the aqueous extracts. The minimum inhibitory concentrations (MIC) of the metha...

  17. The microstructural effects of aqueous extract of Garcinia kola (Linn) on the hippocampus and cerebellum of malnourished mice

    Institute of Scientific and Technical Information of China (English)

    Sunday A Ajayi; David A Ofusori; Gideon B Ojo; Oladele A Ayoka; Taiwo A Abayomi; Adekilekun A Tijani

    2011-01-01

    Objective: To assess the neuroprotective effects of aqueous extract of Garcinia kola on neurotoxin administered malnourished mice adopting histological procedure. Methods: The study was carried out using thirty-two adult malnourished mice which were randomly assigned into four groups (n=8): A, B, C and D. Group A served as control, while the other groups served as the experimental groups. Animals in group A were fed malnourished diet ad libitum and given water liberally. Animals in group B were administered with 3-Nitropropionic acid (3-NP) (neurotoxin) only at 20 mg/kg body weight, group C were given only Garcinia kola extracts, and group D were pre-treated with Garcinia kola extracts at 200 mg/kg for seven days prior to administration of neurotoxin at 20 mg/kg body weight. After three days of neurotoxins administration in the relevant groups, the brains were excised and fixed in formal calcium for histological processing. Results:The study showed that hippocampal and cerebellar neurons of animals in group B exhibited some cellular degeneration and blood vessel blockage, which were not seen in groups A, C and D. Cresyl violet staining was least intense in group B than in groups A, C and D. Despite the fact that animals in group D has equal administration of 3-Nitropropionic acid concentration, there were no traces of neural degeneration as it was evidenced in group B. Conclusions: It is concluded that Garcinia kola has protective effects on the neurons of the hippocampus and cerebellum of malnourished mice.

  18. Chronology and cooling history of the Tianmenshan pluton in South Jiangxi Province and their geological significance

    Institute of Scientific and Technical Information of China (English)

    ZENG Qingtao; MAO Jianren; HU Qing; ZHAO Xilin; YE Haimin

    2008-01-01

    Geochronological studies on the crust-derived Tianmenshan pluton were undertaken by SHRIMP zircon U-Pb dating and Ar-Ar dating of biotite, muscovite and K-feldspar, giving a petrogenetic age of 167 Ma. Owing to the closure systems in different minerals, the cooling history of the pluton can be determined with an age-temperature diagram. The late hydrothermal event has been recognized, which is related probably with mineralization. In terms of the comparative geochronological and petrologic records, it is concluded that there are some constrains on tectonic evolution and that the formation of the Tianmenshan pluton proceeded in a transition period from lndosinian post-orogeny extension to strong compressive tectonics. And the timing of the hydrothermal event matches the compressive climax of the Yanshanian orogeny. The temporal gap between granite emplacement and wolframite mineralization could last 10-20 Ma owing to the low cooling rate of the pluton.

  19. Iron variation within a granitic pluton as determined by near-infrared reflectance

    Science.gov (United States)

    Baird, A. K.

    1984-01-01

    One-hundred fifty-one previously chemically analyzed samples of tonalite from the Lakeview Mountains pluton, southern California batholith, were analyzed for their iron content using near-infrared spectrophotometry. Compared to the earlier analyses of the same sample set by X-ray fluorescence spectrography, the infrared data have higher analytical variance but clearly define patterns of compositional zonation in the pluton which are closely similar to those patterns obtained from X-ray data; petrogenetic interpretations for the pluton would be the same from either data set. Infrared spectral data can be obtained directly in the field with relatively simple instruments and field measurements can be made to average local heterogeneities that often mask significant plutonic variations.

  20. Tertiary plutonic rocks of southern Serbia Vardar Zone as dimension stone

    Directory of Open Access Journals (Sweden)

    Kurešević Lidja

    2014-01-01

    Full Text Available Three granitoid plutons of south-Serbian part of the Vardar Zone, of Tertiary age were studied in order to establish their potential for utilization as dimension stone. These rocks vary in composition from quartzmonconite to quartzdiorite. Field study aimed at establishing the geological factors - presence of fractures, harmful minerals, alterations, jointing type and fabric homogeneity in order to determine the possibility of obtaining large size blocks of stone from the plutons. Laboratory examinations comprised petrological analyses and testing of technical properties. Stone from these plutons has shown favourable results in both field and laboratory examinations. Evaluation of the rock based on obtained laboratory testing results is performed according to technical requirements of the Serbian standard B.B3.200. It has shown that rocks from these plutons can be used as dimension stone for the production of slabs for the exterior and interior paving and cladding. [Projekat Ministarstva nauke Republike Srbije, br. OI176016

  1. Volcanic-plutonic parity and the differentiation of the continental crust.

    Science.gov (United States)

    Keller, C Brenhin; Schoene, Blair; Barboni, Melanie; Samperton, Kyle M; Husson, Jon M

    2015-07-16

    The continental crust is central to the biological and geological history of Earth. However, crustal heterogeneity has prevented a thorough geochemical comparison of its primary igneous building blocks-volcanic and plutonic rocks-and the processes by which they differentiate to felsic compositions. Our analysis of a comprehensive global data set of volcanic and plutonic whole-rock geochemistry shows that differentiation trends from primitive basaltic to felsic compositions for volcanic versus plutonic samples are generally indistinguishable in subduction-zone settings, but are divergent in continental rifts. Offsets in major- and trace-element differentiation patterns in rift settings suggest higher water content in plutonic magmas and reduced eruptibility of hydrous silicate magmas relative to dry rift volcanics. In both tectonic settings, our results indicate that fractional crystallization, rather than crustal melting, is predominantly responsible for the production of intermediate and felsic magmas, emphasizing the role of mafic cumulates as a residue of crustal differentiation. PMID:26178961

  2. Ulvöspinel from xenoliths of contact-altered volcanic and volcanosedimentary rocks in nepheline syenites of the Khibiny and Lovozero plutons

    Science.gov (United States)

    Ivanyuk, G. Yu.; Korchak, Yu. A.; Pakhomovsky, Ya. A.; Men'shikov, Yu. P.; Yakovenchuk, V. N.

    2012-12-01

    Ulvöspinel is a typical accessory mineral of xenoliths of volcanic and volcanosedimentary rocks in alkaline syenites of the Khibiny and Lovozero plutons. Ulvöspinel forms homogeneous Cr- and V-rich grains in slightly altered olivine basalts, basaltic tuffs, and tuffites and is enriched in Mn and Si in the course of contact-metasomatic alteration of these rocks. The strongly reduced conditions of contact metamorphism controlled by ascending flows of hydrocarbon gases and hydrogen sulfide gave rise to the subsolidus decomposition of primary ulvöspinel and Ti-high magnetite with the formation of ilmenite lamellae and then, with decreasing redox potential, of the second-generation latticed ulvöspinel lamellae.

  3. Thermal modeling of pluton emplacement and associated contact metamorphism:Parashi stock emplacement in the Serranía de Jarara (Alta Guajira, Colombia

    Directory of Open Access Journals (Sweden)

    Zuluaga C. Carlos A.

    2010-12-01

    Full Text Available

    In the northernmost portion of the Serrania de Jarara (Alta Guajira, Colombia, low - medium grade metamorphic rocks from the Etpana Metamorphic Suite were thermally affected by emplacement of a small calc-alkaline intrusion (Parashi Stock. Detailed petrographic analysis in collected rock samples across the NE and NW plutonic contacts show occurrences of textural and mineralogical changes in the country rock fabric that evidence contact metamorphism overprinting regional metamorphism of the Etpana Suite. These changes include growth of andalusite (chiastolite, calcic clinopyroxeneand amphibole porphyroblast crosscutting Sn+1 metamorphicfoliation. Hornblende-plagioclase barometry (ca. 3.1 kbar and cooling models for the stock show maximum time temperature evolution in the country rock at the interpreted depth of intrusion (ca. 11 km and help to evaluate the behavior of the country rock with the changing local geotherm.

  4. Vliv stočení oběžného kola na charakteristiku čerpadla

    OpenAIRE

    Jelen, Richard

    2014-01-01

    Diplomová práce se zabývá změnou geometrie výstupní části oběžného kola u radiálních odstředivých čerpadel a jejímu vlivu na charakteristiku čerpadla. Při použití těchto radiálních odstředivých čerpadel v praxi je možno měnit jejich parametry na základě požadavků. Toto přizpůsobení parametrů se nazývá stočení oběžného kola. Jedná se o zmenšení průměru oběžného kola, čímž dochází ke snížení průtoku, dopravní výšky a účinnosti. Existující vztahy pro výpočet změny charakteristiky po stočení oběž...

  5. Petrology and Geochemistry of Neoproterozoic Arc Plutons Beneath the Atlantic Coastal Plain, SRS, SC

    Energy Technology Data Exchange (ETDEWEB)

    Maryak, M.

    1998-10-21

    In this report is presented first a brief review of the regional geologic setting of the Savannah River Site, descriptions of the plutonic rock units sampled here, whole rock geochemical data on the plutonic igneous rocks, and finally, a discussion of how the crystalline basement rocks of the Savannah River Site formed and how they may correlate with other terranes exposed in the Piedmont of the Carolinas, Georgia, and Virginia.

  6. Colour masks in digital image analysis: a technique for modal analyses of quartz saturated plutonic rocks

    OpenAIRE

    Elliott, B.A.

    1999-01-01

    Mineral modes can be calculated quickly and accurately by using colour masks in scanned digital images of stained, quartz saturated plutonic rocks. The image analysis method for determining modal compositions is as accurate as manual point counting, and remarkably faster. A comparison of the manual point counting and pixel resolution methods, and a step by step procedure for calculating mineral modes in quartz saturated plutonic rocks are provided to make modal composition calculations fast, ...

  7. Multidisciplinary study of Santa Eulália Plutonic Complex (Central Portugal): Preliminary insight.

    OpenAIRE

    Sant’Ovaia, Helena; Lopes, José Carrilho; Nogueira, Pedro

    2011-01-01

    Multidisciplinary study of Santa Eulalia Plutonic Complex (Central Portugal): Preliminary insight H. SANT’OVAIA1*, J. CARRILHO LOPES2 AND P. NOGUEIRA2 1DGAOT, Centro de Geologia, FCUP, Portugal (*correspondence: ) 2Dep. Geo., Univ. Évora, Centro de Geologia UL, Portugal The Santa Eulália Plutonic Complex (SEPC) is a late- Variscan calcalkaline granitic body that occupies an area of 400 km2 and is located in the Variscan Iberian sector. The host ...

  8. Colour masks in digital image analysis: a technique for modal analyses of quartz saturated plutonic rocks

    Directory of Open Access Journals (Sweden)

    Elliott, B.A.

    1999-12-01

    Full Text Available Mineral modes can be calculated quickly and accurately by using colour masks in scanned digital images of stained, quartz saturated plutonic rocks. The image analysis method for determining modal compositions is as accurate as manual point counting, and remarkably faster. A comparison of the manual point counting and pixel resolution methods, and a step by step procedure for calculating mineral modes in quartz saturated plutonic rocks are provided to make modal composition calculations fast, accurate, and efficient.

  9. Using micro-scale evidence to understand regional-scale hydrothermal alteration of plutonic rocks

    OpenAIRE

    Plümper, O.; King, H. E.; Putnis, A.

    2009-01-01

    Subsolidus re-equilibration of plutonic feldspars induced by hydrothermal fluids provides a valuable record of fluid-rock interactions that affect large volumes of the Earth's continental crust (Taylor, 1977). The effect of hydrothermal fluids has important implications for the interpretation of the present plutonic mineralogy and geochemistry. However, crustal hydrothermal activity is usually not accounted for unless stages of replacement can be identified or new minerals that are characteri...

  10. Different meanings for cummingtonite-hornblende association in plutonic rocks (Iberian Massif, Portugal)

    OpenAIRE

    Solá, A. R.; Moita, P.; Santos, J. F.; Neiva, A.M.R.; Ribeiro, M. L.

    2010-01-01

    Cummingtonite-grunerite series is frequently related with metamorphism or volcanic environments but rarely described as belonging to a plutonic assemblage [1]. Recently, in Iberian Massif (Portugal), there have been several references [2,3,4,5] of this Fe-Mg amphibole intimately associated with Ca amphiboles (mainly hornblende) on plutonic rocks. Different textural relations between two amphibole types have been argued to for a primary (igneous) or subsolidus metamorphic origin for Fe-Mg amph...

  11. Uranium-Lead Zircon Ages and Sr, Nd, and Pb Isotope Geochemistry of Selected Plutonic Rocks from Western Idaho

    Science.gov (United States)

    Unruh, Daniel M.; Lund, Karen; Kuntz, Mel A.; Snee, Lawrence W.

    2008-01-01

    Across the Salmon River suture in western Idaho, where allochthonous Permian to Cretaceous oceanic rocks are juxtaposed against Proterozoic North American rocks, a wide variety of plutonic rocks are exposed. Available data indicate much variation in composition, source, and structural state of these plutons. The plutonic rocks were long described as the western border zone of the Cretaceous Idaho batholith but limited pre-existing age data indicate more complicated origins. Because the affinity and age of the plutonic rocks cannot be reliably determined from field relations, TIMS U-Pb dating in conjunction with Sr, Nd, and Pb isotopic studies of selected plutons across the suture in western Idaho were undertaken. The data indicate three general groups of plutons including (1) those that intruded the island arc terranes during the Triassic and Jurassic, those that intruded near the western edge of oceanic rocks along the suture in the Early Cretaceous, and the plutons of the Idaho batholith that intruded Proterozoic North American rocks in the Late Cretaceous. Plutons that intruded Proterozoic North American rocks commonly include xenocrystic zircons and in several cases, ages could not be determined. The least radiogenic Sr and most radiogenic Nd are found among the Blue Mountains superterrane island arc samples. Suture-zone plutons have isotopic characteristics that span the range between Idaho batholith and island arc samples but mostly follow island arc signatures. Plutons of the Idaho batholith have the most radiogenic initial Pb and Sr ratios and the least radiogenic Nd of the samples analyzed.

  12. The Cryogenian arc formation and successive high-K calc-alkaline plutons of Socotra Island (Yemen)

    OpenAIRE

    Denele, Y.; Leroy, S.; Pelleter, Ewan; Pik, R; Talbot, J-y.; Khanbari, K.

    2012-01-01

    The Socotra Island belongs to the southern rifted margin of the Gulf of Aden and occupied in Neoproterozoic times a key position to constrain the age and the nature of the largely hidden Neoproterozoic rocks of the Arabian plate. Our integrated field, petrographic, geochemical and geochronological study in the Neoproterozoic rocks recognises three main successive events: (a) high-temperature ductile deformation and metamorphism forming probably in a compressive or transpressive regime; (b) ma...

  13. Geological, geochemical and isotopic characteristics of the Archaean Kaap Valley pluton, Barberton mountain land, South Africa

    International Nuclear Information System (INIS)

    The Kaap Valley pluton consists predominantly of a homogeneous weakly foliated, hornblende-bearing tonalite. It is among the oldest granitoid bodies yet recognized in the environs of the Barberton greenstone belt, yielding 207Pb/206Pb mineral ages of about 3300 Ma and a Rb-Sr whole rock isochron age of about 3500 Ma. The Kaap Valley pluton is distinctive in many respects. Whereas all other gneiss plutons in the area are characterized by a trondhjemitic bulk composition with mafic mineralogies dominated by biotite, the Kaap Valley pluton is tonalitic in bulk composition with hornblende (plus minus minor biotite) as its major mafic phase. In this paper, the results of a detailed geological, geochemical and Pb-isotopic study of the Kaap Valley pluton are presented. Questions relating to the origin of the body are considered, with an emphasis on the formation of a tonalitic magma which is more mafic than those typically encountered in the region. Although exposure does not permit a detailed structural study of the gneiss pluton consideration is given to its mode of emplacement

  14. Petrogenetic evolution of the Early Miocene Alaçamdağ volcano-plutonic complex, northwestern Turkey: implications for the geodynamic framework of the Aegean region

    Science.gov (United States)

    Erkül, Sibel Tatar

    2012-01-01

    Extensional-tectonic processes have generated extensive magmatic activity that produced volcanic/plutonic rocks along an E-W-trending belt across north-western Turkey; this belt includes granites and coeval volcanic rocks of the Alaçamdağ volcano-plutonic complex. The petrogenesis of the Early Miocene Alaçamdağ granitic and volcanic rocks are here investigated by means of whole-rock Sr-Nd isotopic data along with field, petrographic and whole-rock geochemical studies. Geological and geochemical data indicate two distinct granite facies having similar mineral assemblages, their major distinguishing characteristic being the presence or absence of porphyritic texture as defined by K-feldspar megacrysts. I-type Alaçamdağ granitic stocks have monzogranitic-granodioritic compositions and contain a number of mafic microgranular enclaves of monzonitic, monzodioritic/monzogabbroic composition. Volcanic rocks occur as intrusions, domes, lava flows, dykes and volcanogenic sedimentary rocks having (first episode) andesitic and dacitic-trachyandesitic, and (second episode) dacitic, rhyolitic and trachytic-trachydacitic compositions. These granitic and volcanic rocks are metaluminous, high-K, and calc-alkaline in character. Chondrite-normalised rare earth element patterns vary only slightly such that all of the igneous rocks of the Alaçamdağ have similar REE patterns. Primitive-mantle-normalised multi-element diagrams show that these granitic and volcanic rocks are strongly enriched in LILE and LREE pattern, high (87Sr/86Sr)i and low ɛ Nd( t) ratios suggesting Alaçamdağ volcano-plutonic rocks to have been derived from hybrid magma that originated mixing of co-eval lower crustal-derived more felsic magma and enriched subcontinental lithospheric mantle-derived more mafic magmas during extensional processes, and the crustal material was more dominant than the mantle contribution. The Alaçamdağ volcano-plutonic complex rocks may form by retreat of the Hellenic

  15. Zircon U-Pb age, Lu-Hf isotope, mineral chemistry and geochemistry of Sundamalai peralkaline pluton from the Salem Block, southern India: Implications for Cryogenian adakite-like magmatism in an aborted-rift

    Science.gov (United States)

    Renjith, M. L.; Santosh, M.; Li, Tang; Satyanarayanan, M.; Korakoppa, M. M.; Tsunogae, T.; Subba Rao, D. V.; Kesav Krishna, A.; Nirmal Charan, S.

    2016-01-01

    The Sundamalai peralkaline pluton is one among the Cryogenian alkaline plutons occurring in the Dharmapuri Rift Zone (DRZ) of the Salem Block in the Southern Granulite Terrane (SGT) of India. Here we present zircon U-Pb age and Lu-Hf isotopic composition, mineral chemistry and geochemistry of the pluton to explore the petrogenesis and geodynamic implications. Systematic modal variation of orthoclase, Na-plagioclase, Ca-amphibole (ferro-edenite and hastingsite) and quartz developed quartz-monzonite and granite litho units in the Sundamalai pluton. Thermometry based on amphibole-plagioclase pair suggests that the pluton was emplaced and solidified at around 4.6 kbar pressure with crystallization of the major phases between 748 and 661 °C. Estimated saturation temperature of zircon (712-698 °C) is also well within this range. However, apatite saturation occurred at higher temperatures between 835 and 870 °C, in contrast with monazite saturation (718-613 °C) that continued up to the late stage of crystallization. Estimated oxygen fugacity values (log fO2: -14 to -17) indicate high oxidation state for the magma that stabilized titanite and magnetite. The magmatic zircons from Sundamalai pluton yielded a weighted mean 206Pb/238U age of 832.6 ± 3.2 Ma. Geochemically, the Sundamalai rocks are high-K to shoshonitic, persodic (Na2O/K2O ratio > 1), silica-saturated (SiO2:65-72 wt.%), and peralkaline in composition (aluminum saturation index, ASI AI < 0). The initial magma was mildly metaluminous which evolved to strongly peralkaline as result of fractional crystallization (plagioclase effect) controlled differentiation between quartz-monzonite and granite. Both rock types have high content of Na2O (5.1-6.3 wt.%), Ba (350-2589 ppm) and Sr (264-1036 ppm); low content of Y (8.7-17 ppm) and Yb (0.96-1.69 ppm); elevated ratios of La/Yb (11-46) and Sr/Y (46-69) and are depleted in Ti, with a positive Sr anomaly suggesting an adakite-like composition and garnet controlled

  16. Alkaline Phosphatase in Stem Cells

    Directory of Open Access Journals (Sweden)

    Kateřina Štefková

    2015-01-01

    Full Text Available Alkaline phosphatase is an enzyme commonly expressed in almost all living organisms. In humans and other mammals, determinations of the expression and activity of alkaline phosphatase have frequently been used for cell determination in developmental studies and/or within clinical trials. Alkaline phosphatase also seems to be one of the key markers in the identification of pluripotent embryonic stem as well as related cells. However, alkaline phosphatases exist in some isoenzymes and isoforms, which have tissue specific expressions and functions. Here, the role of alkaline phosphatase as a stem cell marker is discussed in detail. First, we briefly summarize contemporary knowledge of mammalian alkaline phosphatases in general. Second, we focus on the known facts of its role in and potential significance for the identification of stem cells.

  17. Archean to Paleoproterozoic polymetamorphic history of the Salma eclogite in Kola Peninsula, Russia

    Science.gov (United States)

    Imayama, Takeshi; Oh, Chang-Whan; Park, Chan-Soo; Yi, Keewook; Jung, Haemyeong

    2015-04-01

    One of the most important questions in the Earth Science is when and how plate tectonics operate in the Precambrian time. The tectonic and thermal evolution of the Precambrian eclogite is significant key for understanding the Precambrian geodynamic mechanisms. Eclogites in Kola Peninsula, Russia are some of the oldest eclogites of the world, but there has been much debate about the timing of eclogite-facies metamorphism: Archean (e.g. Volodichev et al. 2004; Mints et al., 2010) or Paleoproterozoic (e.g. Skublob et al., 2011, 2012). The controversy is mainly because of the lack of zircon dating coupled with the formation of garnet and omphacite. In this study, we present geochronological, petrographic, and geochemical data from the Salma eclogites in the Kola Peninsula, Russia to characterize subduction and collision processes in the Precambrian. Microstructural observations, P-T analyses, zircon inclusion analyses, and U-Pb zircon dating revealed multiple metamorphic stages that the Salma eclogite underwent. The amphibolite facies metamorphic event firstly occurred at 2.73-2.72 Ga during Archean. In the Paleoproterozoic period, the Salma eclogites underwent prograde stage of epidote-amphibolite facies metamorphism. The eclogite facies metamorphic event took place under the P-T condition of 16-18 kbar and 740-770 °C at 1.89-1.88 Ga, with a subsequent granulite facies metamorphism during decompression stage from 18 kbar to 9-12 kbar. Finally, later amphibolite facies metamorphism occurred at 8-10 kbar and 590-610 °C on cooling. The Archean metamorphic zircons that contain inclusions of Grt + Am + Bt + Pl + Qtz + Rt are unzoned grains with dark CL, and they are relatively enriched in HREE. In contrast, the 1.89-1.88 Ga sector or concentric zoned zircons with pale-grey CL include inclusions of Grt + Omp + Ca-Cpx + Am + Bt + Qtz + Rt, and they have the flat pattern of HREE due to the amounts of abundant garnet during the eclogite-facies metamorphism. Whole rock

  18. Alkaline fuel cells applications

    Science.gov (United States)

    Kordesch, Karl; Hacker, Viktor; Gsellmann, Josef; Cifrain, Martin; Faleschini, Gottfried; Enzinger, Peter; Fankhauser, Robert; Ortner, Markus; Muhr, Michael; Aronson, Robert R.

    On the world-wide automobile market technical developments are increasingly determined by the dramatic restriction on emissions as well as the regimentation of fuel consumption by legislation. Therefore there is an increasing chance of a completely new technology breakthrough if it offers new opportunities, meeting the requirements of resource preservation and emission restrictions. Fuel cell technology offers the possibility to excel in today's motive power techniques in terms of environmental compatibility, consumer's profit, costs of maintenance and efficiency. The key question is economy. This will be decided by the costs of fuel cell systems if they are to be used as power generators for future electric vehicles. The alkaline hydrogen-air fuel cell system with circulating KOH electrolyte and low-cost catalysed carbon electrodes could be a promising alternative. Based on the experiences of Kordesch [K. Kordesch, Brennstoffbatterien, Springer, Wien, 1984, ISBN 3-387-81819-7; K. Kordesch, City car with H 2-air fuel cell and lead-battery, SAE Paper No. 719015, 6th IECEC, 1971], who operated a city car hybrid vehicle on public roads for 3 years in the early 1970s, improved air electrodes plus new variations of the bipolar stack assembly developed in Graz are investigated. Primary fuel choice will be a major issue until such time as cost-effective, on-board hydrogen storage is developed. Ammonia is an interesting option. The whole system, ammonia dissociator plus alkaline fuel cell (AFC), is characterised by a simple design and high efficiency.

  19. Geochemistry, geochronology and zircon Hf isotopic study of peralkaline-alkaline intrusions along the northern margin of the North China Craton and its tectonic implication for the southeastern Central Asian Orogenic Belt

    Science.gov (United States)

    Zhao, Pan; Jahn, Bor-ming; Xu, Bei; Liao, Wen; Wang, Yanyang

    2016-09-01

    A giant Permian alkaline magmatic belt has recently been identified in southern Inner Mongolia, along the northern margin of the North China Craton (NCC). This belt is mainly composed of syenite, quartz syenite, alkaline granite and mafic microgranular enclaves (MME)-bearing granodiorite. In order to study the petrogenesis and tectonic implications of these rocks, we undertook zircon U-Pb dating and geochemical analysis of two Permian alkaline plutons. The first Guangxingyuan Pluton occurs in the Hexigten area and is composed of MME-bearing tonalite, K-feldspar granite and syenite. The second Durenwuliji Pluton, located in the Xianghuangqi area, comprises syenite, quartz syenite and K-feldspar granite. Zircon U-Pb dating on tonalite, K-feldspar granite, syenite and quartz syenite from the two plutons yielded a tight range of ages from 259 to 267 Ma. The peralkaline-alkaline rocks show high abundance of total alkalis (K2O + Na2O = 7.9-12.9%) and K2O contents (3.9-8.0%), enrichment in large ion lithophile elements (LILE) and light rare earth element (LREE), and depletion of high field strength elements (HFSE). The associated tonalite and MMEs display I-type granitic geochemical affinity, with less total abundance of trace elements than the peralkaline-alkaline rocks. Zircon Hf isotopic analysis of the Guangxingyuan pluton yielded a large range of εHf(t) values from - 15.5 to + 6.7 and model ages (TDMC) from 781 to 2012 Ma. By contrast, the Hf isotopic data of the Durenwuliji pluton shows a small range of εHf(t) from + 6.2 to + 8.9 and TDMC from 667 to 816 Ma. The geochemical and Hf isotopic characteristics indicate that the parental magma was derived from a mixing of metasomatic mantle-derived mafic magma with different amount of crust-derived felsic magma, and followed by fractional crystallization. Considering previous tectonic studies in Inner Mongolia, a Permian post-orogenic extension was proposed to account for these peralkaline-alkaline intrusions following

  20. Mineral potential of felsic plutonic rocks in the north-central Arabian Shield, Kingdom of Saudi Arabia

    Science.gov (United States)

    Moore, W.J.

    1985-01-01

    Fourteen plutons of Late Proterozoie age potentially favorable for rare-element mineralization have been identified in a geochemical and petrographic assessment of felsic plutonic rocks in the north-central Arabian Shield (lat 23°00'-25°00' N., long 40°00'-45°00' E.). The plutons are highly fractionated, leucocratic granitoids assigned to a major magmatic pulse that spanned the later stages of the Hijaz orogeny (about 610 Ma to about 550 Ma). Most of the targeted plutons are small or not deeply eroded. Two rock types are dominant: subsolvus, muscovite-bearing monzogranite or syenogranite; and hypersolvus, mieroeline perthite granite commonly containing sodic pyriboles. Enrichment in varied suites of the granitophile elements (Sn-W-NbTa-Zr-Y-Th-U) is characteristic. The plutons occupy the central part of a broad arcuate belt of geochemically specialized plutons that conforms generally to the eastern limit of exposed Proterozoic basement.

  1. Magnetic properties of ilmenite-hematite single crystals from the Ecstall pluton near Prince Rupert, British Columbia

    DEFF Research Database (Denmark)

    Brownlee, Sarah J.; Feinberg, Joshua M.; Kasama, Takeshi;

    2011-01-01

    Ecstall pluton experienced considerable mineralogical changes as younger Eocene plutons, such as the ∼58 Ma Quottoon Pluton, were emplaced along its margins. We investigated changes in the rock magnetic properties associated with this reheating event by examining isolated grains of intergrown ilmenite and......Paleomagnetic studies of the 91 Ma Ecstall pluton and other Cretaceous plutons of British Columbia imply large northward tectonic movements (>2000 km) may have occurred during the tectonic evolution of western North America. However, more recent studies have shown that the eastern edge of the...... hematite, the primary paleomagnetic recorder in the Ecstall pluton. Measurements of hysteresis properties, low-temperature remanence, and room temperature isothermal remanent magnetization acquisition and observations from magnetic force microscopy and off-axis electron holography indicate that samples...

  2. Evidence in Variscan Corsica of a brief and voluminous Late Carboniferous to Early Permian volcanic-plutonic event contemporaneous with a high-temperature/low-pressure metamorphic peak in the lower crust

    International Nuclear Information System (INIS)

    The U2 group of plutonic rocks constituting the main exposed part of the Corsica-Sardinia batholith (CSB) was emplaced from 308 to 275 Ma (the early Visean U1 group of Mg-K intrusions is not considered here). Field evidence earlier established volcanic-plutonic relationships in the U2 group of calc-alkaline intrusions of the CSB, though detailed chronological data were still lacking. Large outcrops of U2 volcanic formations are restricted to the less eroded zone north-west of the Porto-Ponte Leccia line in Corsica, but volcanic and volcano-sedimentary formations were widely eroded elsewhere since Permian times. They probably covered most of the batholith before the Miocene, as testified by the volcanic nature of the pebbles that form much of the Early Miocene conglomerates of eastern Corsica. U-Pb zircon dating (SHRIMP) was used for deciphering the chronology and duration of different volcanic pulses and for better estimating the time overlap between plutonic and volcanic rock emplacement in the CSB. The obtained ages fit well with field data, showing that most of the U2 and U3 volcanic formations were emplaced within a brief time span of roughly 15 m.y., from 293 to 278 Ma, coeval with most U2 monzo-granodiorites and leuco-monzo-granites (295-280 Ma), alkaline U3 complexes (about 288 Ma), and mafic-ultramafic tholeiitic complexes (295-275 Ma). The same chronological link between deep-seated magma chambers and eruptions was identified in the Pyrenees. These results correlate with U-Pb zircon dating of HT-LP granulites from the Variscan deep crust exhumed along the 'European' margin of the thinned Tethys margin in Corsica and Calabria. Here, the peak of the low-pressure/high-temperature metamorphism was dated at about 285-280 Ma. Our results throw light on the condition of magma production during the orogenic collapse in the southern Variscan realm. While juvenile tholeiitic basaltic magma was produced by the melting of spinel mantle lithosphere, all

  3. Dose- and time-dependent effects of Garcinia kola seed extract on sexual behaviour and reproductive parameters in male Wistar rats.

    Science.gov (United States)

    Sewani-Rusike, C R; Ralebona, N; Nkeh-Chungag, B N

    2016-04-01

    The aim of the present study was to investigate the effects of a crude extract of Garcinia kola on male sexual function after subchronic and chronic treatment periods at different sublethal doses. Adult male Wistar rats were treated orally with 100, 200 and 400 mg kg(-1) of a 70% ethanolic extract of G. kola daily for 56 days. Sexual behaviour studies were performed on days 28 and 50. At termination on day 56, organ weights, sperm count, reproductive hormone levels and testicular histology were assessed. Subchronic and chronic treatment of normal male rats with G. kola extract resulted in overall increase in components of libido, erection and ejaculation in treated rats - with lower doses being more efficient than the higher dose. There was a slight reduction in some components of sexual behaviour with prolonged time of treatment. G. kola treatment at all doses resulted in increased testicular weights, increased sperm count with no change in motility and increased serum testosterone levels with no change in gonadotropin levels. Gross testicular histology was not affected by treatment. We conclude that G. kola seed extract possesses potent aphrodisiac activity in male albino rats with resultant increase in sperm count and testosterone levels. PMID:26123866

  4. Is there a geochemical link between volcanic and plutonic rocks in the Organ Mountains caldera?

    Science.gov (United States)

    Memeti, V.; Davidson, J.

    2013-12-01

    Results from separate volcanic and plutonic studies have led to inconsistent conclusions regarding the origins and thus links between volcanic and plutonic systems in continental arcs and the magmatic processes and time scales responsible for their compositional variations. Some have suggested that there is a geochemical and geochronological disconnect between volcanic and plutonic rocks and hence have questioned the existence of magma mush columns beneath active volcanoes. Investigating contemporary volcanic and plutonic rocks that are spatially connected is thus critical in exploring these issues. The ca. 36 Ma Organ Mountains caldera in New Mexico, USA, represents such a system exposing contemporaneous volcanic and plutonic rocks juxtaposed at the surface due to tilting during extensional tectonics along the Rio Grande Rift. Detailed geologic and structural mapping [1] and 40Ar/39Ar ages of both volcanics and plutons [2] demonstrate the spatial and temporal connection of both rock types with active magmatism over >2.5 myr. Three caldera-forming ignimbrites erupted within 600 kyr [2] from this system with a total erupted volume of 500-1,000 km3 as well as less voluminous pre- and post-caldera trachyte and andesite lavas. The ignimbrite sequence ranges from a crystal-poor, high-SiO2 rhyolite at the base to a more crystal-rich, low-SiO2 rhyolite at the top. Compositional zoning with quartz-monzonite at the base grading to syenite and alaskite at the top is also found in the Organ Needle pluton, the main intrusion, which is interpreted to be the source for the ignimbrites [1]. Other contemporaneous and slightly younger plutons have dioritic to leucogranitic compositions. We examined both volcanic and plutonic rocks with petrography and their textural variations with color cathodoluminescence, and used whole rock element and Sr, Nd and Pb isotope geochemistry to constrain magma compositions and origins. Electron microprobe analyses on feldspars have been completed to

  5. Subduction polarity of the prototethys: insights from the Yirba pluton of the western Kunlun range, NW China

    OpenAIRE

    C. Yuan; M. Sun; Xiao, WJ; Zhou, H.; Hou, QL; Li, JL

    2003-01-01

    The Yirba (128 km) pluton is an early Paleozoic dioritic intrusion of western Kunlun orogenic belt, northwest China as an important element when reconstructing the evolution history of this belt. Due to the scarcity of field data and methodological difference in studying this pluton, however, no consensus for its age, source and tectonic setting has been adopted. In this paper, we present new geochronological and geochemical data for the Yirba pluton, aiming to better understand its age, sour...

  6. Calc-alkaline rear-arc magmatism in the Fuegian Andes: Implications for the mid-cretaceous tectonomagmatic evolution of southernmost South America

    Science.gov (United States)

    Guillot, Mauricio González; Escayola, Mónica; Acevedo, Rogelio

    2011-02-01

    The magmatic arc of the Fuegian Andes is composed mostly of Upper Mesozoic to Cenozoic calc-alkaline plutons and subordinated lavas. To the rear arc, however, isolated mid-Cretaceous monzonitic plutons and small calc-alkaline dykes and sills crop out. This calc-alkaline unit (the Ushuaia Peninsula Andesites, UPA) includes hornblende-rich, porphyritic quartz meladiorites, granodiorites, andesites, dacites and lamprophyres. Radiometric dating and cross-cutting relationships indicate that UPA is younger than the monzonitic suite. The geochemistry of UPA is medium to high K, with high LILE (Ba 500-2000 ppm, Sr 800-1400 ppm), HFSE (Th 7-23 ppm, Nb 7-13 ppm, Ta 0.5-1.1 ppm) and LREE (La 16-51 ppm) contents, along with relatively low HREE (Yb 1.7-1.3 ppm) and Y (9-19 ppm). The similar mineralogy and geochemistry of all UPA rocks suggest they evolved from a common parental magma, by low pressure crystal fractionation, without significant crustal assimilation. A pure Rayleigh fractionation model indicates that 60-65% of crystal fractionation of 60% hornblende + 34% plagioclase + 4% clinopyroxene + 1% Fe-Ti oxide, apatite and sphene (a paragenesis similar of UPA mafic rocks) can explain evolution from lamprophyres to dacites. The UPA has higher LILE, HFSE and LREE, and lower HREE and Y than the calc-alkaline plutons and lavas of the volcanic front. The HREE and Y are lower than in the potassic plutons as well. High concentrations of Th, Nb, Ta, Zr, Hf, LREE and Ce/Pb, and low U/Th, Ba/Th ratios in UPA, even in the least differentiated samples, suggest contributions from subducted sediments to the mantle source. On the other hand, relatively low HREE and Y, high LREE/HREE (La/Yb 11-38) ratios and Nb-Ta contents can be interpreted as mantle metasomatism by partial melts of either subducted garnetiferous oceanic sediment or basalt as well. Additionally, high LILE content in UPA, similar to the potassic plutons, suggests also a mantle wedge previously metasomatized by potassic

  7. Bifunctional alkaline oxygen electrodes

    Science.gov (United States)

    Swette, L.; Kackley, N.; Mccatty, S. A.

    1991-01-01

    The authors describe the identification and testing of electrocatalysts and supports for the positive electrode of moderate-temperature, single-unit, rechargeable alkaline fuel cells. Recent work on Na(x)Pt3O4, a potential bifunctional catalyst, is described, as well as the application of novel approaches to the development of more efficient bifunctional electrode structures. The three dual-character electrodes considered here showed similar superior performance; the Pt/RhO2 and Rh/RhO2 electrodes showed slightly better performance than the Pt/IrO2 electrode. It is concluded that Na(x)Pt3O4 continues to be a promising bifunctional oxygen electrode catalyst but requires further investigation and development.

  8. Silica in alkaline brines

    Science.gov (United States)

    Jones, B.F.; Rettig, S.L.; Eugster, H.P.

    1967-01-01

    Analysis of sodium carbonate-bicarbonate brines from closed basins in volcanic terranes of Oregon and Kenya reveals silica contents of up to 2700 parts per million at pH's higher than 10. These high concentrations of SiO 2 can be attributed to reaction of waters with silicates, and subsequent evaporative concentration accompanied by a rise in pH. Supersaturation with respect to amorphous silica may occur and persist for brines that are out of contact with silicate muds and undersaturated with respect to trona; correlation of SiO2 with concentration of Na and total CO2 support this interpretation. Addition of moredilute waters to alkaline brines may lower the pH and cause inorganic precipitation of substantial amounts of silica.

  9. Accounting for local meteorological effects in the ozone time-series of Lovozero (Kola Peninsula

    Directory of Open Access Journals (Sweden)

    O. A. Tarasova

    2003-01-01

    Full Text Available The relationship between local meteorological conditions and the surface ozone variability was studied by means of statistical modeling, using ozone and meteorological parameters measured at Lovozero (250 m a.s.l., 68.5°N, 35.0°E, Kola Peninsula for the period of 1999-2000. The regression model of daily mean ozone concentrations on such meteorological parameters as temperature, relative humidity and wind speed explains up to 70% of day-to-day ozone variability in terms of meteorological condition changes, if the seasonal cycle is also considered. A regression model was created for separated time scales of the variables. Short-term, synoptical and seasonal components are separated by means of Kolmogorov-Zurbenko filtering. The synoptical scale variations were chosen as the most informative from the point of their mutual relation with meteorological parameters. Almost 40% of surface ozone variations in time periods of 11-60 days can be explained by the regression model on separated scales that is 30% more efficient than ozone residuals usage. Quantitative and qualitative estimations of the relations between surface ozone and meteorological predictors let us preliminarily conclude that at the Lovozero site surface ozone variability is governed mainly by dynamical processes of various time scale rather than photochemistry, especially during the cold season.

  10. Main features of Kola, Leningrad and Ignalina NPPs for emergency preparedness purposes

    International Nuclear Information System (INIS)

    Of the nuclear power plants situated in the Nordic and their neighbouring countries, the Ignalina, Lenigrad and Kola plants are considered to pose the largest risks to the public. The purpose of this report is to provide basic relevant information about these three plants for use in a case of a major nuclear accident or incident in any of them. The report could be used e.g. by authorities dealing with the resulting emergency measures to provide the public and the media with relevant information about the plant in question. The report can also be used for quick general familiarization With the plants in question. The total activity inventories for all the plants are listed at the end of the report, in Chapter 4. The release of noble gases is close to 100 % in most severe accidents, but the releases of other elements depend strongly on the plant features and the nature of the accident. This report has been compiled from several sources. The main source has been an earlier NKS-report: 'Design and Safety Features of Nuclear Reactors Neighbouring the Nordic Countries', TemaNord 1994:595, 1994. Only limited editing has been done. Sources of the figures are presented in parenthesis after the figure titles. (au)

  11. Cardioprotective effect of Kolaviron (Garcinia kola seed extract in cholesterol-fed rats.

    Directory of Open Access Journals (Sweden)

    NWANERI-CHIDOZIE V. O.

    2014-03-01

    Full Text Available Flavonoids – a group of polyphenolic substances are naturally present in vegetables, fruits, seeds and beverages such as tea and wine. Studies have shown that flavonoid intake is inversely correlated with mortality from coronary heart diseases and myocardial infarction. The effect of kolaviron (a flavonoid complex extracted from Garcinia kola seeds on the organ weights (lungs, kidneys, heart, spleen and liver of rats administered with cholesterol, five times a week, for eight consecutive weeks was investigated. The results revealed that cholesterol administration at a dose of 30mg/day for eight consecutive weeks caused a significant increase (p<0.001 in relative heart weights of the cholesterol-fed rats when compared with the control. However, co-treatment with kolaviron at doses 100 and 200mg/kg significantly (p<0.001 reduced the cholesterol induced enlargement of the heart. This is a pointer to the cardioprotective potential of kolaviron; and thus suggests a possible use as a dietary supplement for the prevention and management of coronary heart diseases.

  12. Community assessment for identification and prioritization health problems in Navai Kola village, Babol, Iran

    Directory of Open Access Journals (Sweden)

    Abbas Abbasi-Ghahramanloo

    2016-02-01

    Full Text Available Introduction: Attracting community participation is the most important developmental solution in various sectors of the society. In this regard, the community evaluation is the process during which researchers and community members get the right understanding of health, living concerns, and community health care system by collecting and analyzing data and determining the strengths, resources, and the needs of society. Navai Kola is a village in the Babol, Iran, in which this research has been done to identify and prioritize problems. Methods: This research is based on the model of the Northern Carolina. In this model, the process of community assessment is done in an eight-stage process that the first seven stages include: identification and classification of problems and the eighth involves drawing up operational plans for solving high priority problems. Results: In this study, a total of 40 different problems were identified in order, and the main were lack of sports facilities and entertainment, waste disposal, dangerous U-turn point in the entrance of the village, worn out power and water utilities, and youth unemployment. Conclusion: Most of the problems identified were issues not directly related to health, but had effects that differently appeared in community health.

  13. Granite intrusion by externally induced growth and deformation of the magma reservoir, the example of the Plasenzuela pluton, Spain

    Science.gov (United States)

    Castro, Antonio; Fernández, Carlos

    1998-09-01

    The Plasenzuela pluton in the Central Extremadura batholith in the southern Iberian Massif, is an example of permissive emplacement in relation to the tectonic development of extensional fractures in the upper continental crust. Paradoxically, this pluton has a concordant structural pattern which is classically attributed to diapirism or ballooning. This pattern consists of the following elements: (a) nearly elliptical shape in the horizontal section; (b) conformity of the pre-existing aureole structures to the shape of the pluton contacts; and (c) development of a crenulation cleavage, parallel to the contacts, in the vicinity of the pluton walls. All these features have been interpreted in many plutons as resulting from the pushing-aside of the country rock structures due to the expansion of the pluton. However, the detailed structural relationships in the aureole do not favour a forceful emplacement mechanism. By contrast, these relationships constitute prime evidence of permissive intrusion in extensional fractures. According to this interpretation, the concordant shape of the pluton was acquired by syn-plutonic opening of a mixed tensional-shear fracture, parallel to the main foliation in the host rocks, and by folding of the fracture walls together with the previous anisotropy of the country rocks. This is a growth-deformation process that can operate at local conditions in the upper continental crust giving rise to concordant syn-tectonic plutons.

  14. Use of Digital Elevation Models to understand map landforms and history of the magmatism Khibiny Massif (Kola Peninsula, Russia)

    Science.gov (United States)

    Chesalova, Elena; Asavin, Alex

    2016-04-01

    most intense free gas emission. The technical possibilities that are offered by Remote Sensing (RS) and Geographical Information Systems (GIS) facilitate the geomorphological investigation of inhospitable and inaccessible mountain areas Digital Elevation Models (DEMs) are valuable tools for approximation of the real world's continuous surface. They allow a visual analysis of the earth's surface morphology, quanti?cation of sediment volumes and the calculation of topographic derivatives such as the slope gradient, slope aspect and pro?le curvature that consume ?eld investigations and optimize time The project has been sponsored by programmm Presidium of RAS P44. Reference Ivanyuk G, Kalashnikov A, Mikhailova J, Konoplyova N, Goryainov P, Yakovenchuk V, Pakhomovsky Y. Self-Organization of the Khibiny Alkaline Massif (Kola Peninsula, Russia). In Earth Sciences, Dr. Imran Ahmad Dar(Ed.), ISBN: 978-953-307-861-8, InTech, Available from: http://www.intechopen.com/books/earth-sciences/self-organization-of-the-khibiny-alkaline -massif -kolapeninsula-russia INTECH Open Access Publisher; 2012, Head7, P.131-156.

  15. Radioactivity and Geochemistry of Jasperoid Veins in Gabal Al-AGLAB Granitic Pluton, North Eastern Desert, Egypt

    International Nuclear Information System (INIS)

    Al-Aglab granitic pluton hosts jasperoid as vein type mineralization. This mineralization are structurally controlled by faults and their feather joints, which are associated with NE-SW to ENE- WSW joints and micro-fractures,widespread silicification, and to a lesser extent kaolinitization and sericitization as well as other alterations accompanying the uranium mineralization. Petrologically, the studied younger granites are classified as syenogranites and texturally asperthitic leucogranites. They are originated from per aluminous, calc-alkaline, highly fractionated magma. The studied granites showed higher U and Th contents and lower Th/U ratios than those of the normal granites. They are considered as uraniferous granites originated from highly fractionated U rich magma with trapping high concentrations of uranium in the higher quotient of the radioactive accessory minerals (e.g. zircon, apatite and sphene). Uranium is concentrated at the central parts of the jasperoid veins, following the NE trend and dipping SE direction, due to their intersection with the WNW sinistral fault. Some of the anomalies are associated with visible secondary uranium minerals mainly uranophane and beta-uranophane. The high levels of radioactivity are mainly due to the high U and Th contents in jasperoid veins and the uranium content reached to 843 ppm and thorium 206 ppm. Gabal Al-Aglab uranium occurrence is considered as an example for a simple uranium vein type mineralization. It is closely associated with and restricted to the younger granite itself that affected by hydrothermal alteration. The uranium bearing late magmatic fluids could be derived from the same magma that originates the granitic pluton itself at the late stage of the magmatic activity. Geochemically, XRF and ESEM (environmental scanning electron microscope) analyses showed that Gabal Al-Aglab jasperoid veins were enriched in Th, U, Zr, W and LREE (Ce and La). The separated heavy fractions of jasperoid veins showed

  16. Characterization of HANARO neutron radiography facility in accordance with ASTM standard E545-91/E803-91 for KOLAS/ISO17025.

    Science.gov (United States)

    Cheul-Muu, Sim; Ki-Yong, Nam; In-Cheol, Lim; Chang-Hee, Lee; Ha-Lim, Choi

    2004-10-01

    As neutron radiography is even more in demand for industrial applications of aircraft, turbine blade, automobile, explosive igniters, etc, it is necessary to review the standards which are the most appropriate for preparing the procedures for setting up the QA system. Recently, Korea Of Lab Accreditation Scheme (KOLAS) was originated from ISO 17025. It is widely recognized by research peer groups for conducting valid tests. The neutron radiography facility (NRF) of High Flux Advanced Neutron Application Reactor (HANARO), which started ion 1996, is the preliminary stages of KOLAS. The HANARO NRF is not only characterized using ASTM standards E545-91/E803-91 to satisfy the requirements of KOLAS, but in the design phase of the tomography system. PMID:15246410

  17. Návrh oběžného kola odstředivého čerpadla pro dané parametry

    OpenAIRE

    Moravec, Prokop

    2014-01-01

    Tato diplomová práce se zabývá návrhem oběžného kola odstředivého čerpadla pro dané parametry. Tento návrh se skládá z výpočtu základních rozměrů meridiálního řezu kola, návrhu tvaru tohoto řezu a z návrhu tvaru lopatky. Kompletní návrh kola je následně simulován v CFD programu. This thesis deals with centrifugal pump impeller design for given parameters. This pump impeller design consists of the calculation of basic dimensions, the meridional flow channel design and blade design. Complete...

  18. Modulators of intestinal alkaline phosphatase.

    Science.gov (United States)

    Bobkova, Ekaterina V; Kiffer-Moreira, Tina; Sergienko, Eduard A

    2013-01-01

    Small molecule modulators of phosphatases can lead to clinically useful drugs and serve as invaluable tools to study functional roles of various phosphatases in vivo. Here, we describe lead discovery strategies for identification of inhibitors and activators of intestinal alkaline phosphatases. To identify isozyme-selective inhibitors and activators of the human and mouse intestinal alkaline phosphatases, ultrahigh throughput chemiluminescent assays, utilizing CDP-Star as a substrate, were developed for murine intestinal alkaline phosphatase (mIAP), human intestinal alkaline phosphatase (hIAP), human placental alkaline phosphatase (PLAP), and human tissue-nonspecific alkaline phosphatase (TNAP) isozymes. Using these 1,536-well assays, concurrent HTS screens of the MLSMR library of 323,000 compounds were conducted for human and mouse IAP isozymes monitoring both inhibition and activation. This parallel screening approach led to identification of a novel inhibitory scaffold selective for murine intestinal alkaline phosphatase. SAR efforts based on parallel testing of analogs against different AP isozymes generated a potent inhibitor of the murine IAP with IC50 of 540 nM, at least 65-fold selectivity against human TNAP, and >185 selectivity against human PLAP. PMID:23860652

  19. Alkaline battery, separator therefore

    Science.gov (United States)

    Schmidt, George F. (Inventor)

    1980-01-01

    An improved battery separator for alkaline battery cells has low resistance to electrolyte ion transfer and high resistance to electrode ion transfer. The separator is formed by applying an improved coating to an electrolyte absorber. The absorber, preferably, is a flexible, fibrous, and porous substrate that is resistant to strong alkali and oxidation. The coating composition includes an admixture of a polymeric binder, a hydrolyzable polymeric ester and inert fillers. The coating composition is substantially free of reactive fillers and plasticizers commonly employed as porosity promoting agents in separator coatings. When the separator is immersed in electrolyte, the polymeric ester of the film coating reacts with the electrolyte forming a salt and an alcohol. The alcohol goes into solution with the electrolyte while the salt imbibes electrolyte into the coating composition. When the salt is formed, it expands the polymeric chains of the binder to provide a film coating substantially permeable to electrolyte ion transfer but relatively impermeable to electrode ion transfer during use.

  20. Physical Properties and Distribution of Intrusive Rocks (Plutons) in the Great Basin

    Science.gov (United States)

    Ponce, D. A.; Watt, J. T.; Glen, J. M.

    2010-12-01

    The distribution of intrusive rocks throughout the Great Basin is important because many plutons are associated with base and precious metal mineral deposits, and may provide insights on regional magmatism and tectonism. Combined information on their physical properties and geophysical signatures will allow improvements on their inferred horizontal extent and facilitate modeling their subsurface structure. Physical property measurements of over 1700 plutonic rock samples in the Great Basin, excluding those in the Sierra Nevada, show an average grain density of about 2670 and a range of about 2260 to 3200 kg/m3; show an average saturated bulk density of about 2630 and a range of about 2290 to 3050 kg/m3; an average magnetic susceptibility of about 0.007 and range from essentially non-magnetic to 0.126 SI-units (equivalent to just over 3 per cent magnetite). As a comparison, over 6,000 granitic samples in the Sierra Nevada (Sikora et al., 1991) have an average grain density of about 2690 and a range of about 2420 to 2780 kg/m3; an average magnetic susceptibility of about 0.006 and range from essentially non-magnetic to 0.016 SI-units (equivalent to about 0.4 per cent magnetite). Remanent magnetizations were measured for selected plutons, for example the remanent magnetization of the Ibapah pluton in the Deep Creek Range, Utah is relatively low and has a Koenigsberger ratio (the ratio between remanent and induced magnetization) of about 0.1. In Nevada, previous pluton extents (Grauch et al., 1988; Grauch , 1996) have been only slightly modified. For example, the Cretaceous to Jurassic stock at Blue Mountain, north-central Nevada (Wilden, 1964) is now mapped as a diorite dike swarm (Wyld, 2002) and thought to be mid-Miocene and related to the inception of the Yellowstone Hotspot (Ponce et al, 2010). Magnetic and gravity data indicate that a possible pluton (or other magnetic basement rock), the top of which could be at moderate crustal depths, is skewed from the

  1. Analysis of ISO/IEC 17025 for establishment of KOLAS (Korea Laboratory Accreditation Scheme) quality assurance system

    International Nuclear Information System (INIS)

    Besides one existent accredited lab, radioactive material chemical analysis lab, five test laboratories and two calibration labs are under plan to acquire the accreditation from KOLAS. But the current Quality Manual was developed according to ISO Guide 25 that was superceded by ISO/IEC 17025. Since it is tailored to the radioactive material chemical analysis lab, a number of requirements of the Manual are not applicable to the labs other than radioactive material chemical analysis lab. Through the analysis of ISO/IEC 17025, a model of quality system was established which is not only consistent with ISO/IEC 17025 but reflective of the KAERI's situation

  2. Geochemistry and U-Pb geochronology of the Neoproterozoic-Cambrian Koettlitz Glacier Alkaline Province, Royal Society Range, Transantarctic Mountains, Antarctica

    International Nuclear Information System (INIS)

    In the southeastern foothills of the Royal Society Range, southern Victoria Land, a diverse array of gabbroic to granitic rocks intrude marbles and schists of the late Proterozoic Skelton Group. A-type characteristics include abundant fluorite, high SiO2, Na2O, K2O, Ga/Al, Y and Nb with low Sr and CaO. A monzogabbro and a monzonite have identical 539 ± 4 Ma ages and a quartz-monzonite is 534 ± 3 Ma. Nearby is a 517 ± 4 Ma A-type granite pluton with more extreme A-type geochemical characteristics. This is the first report of A-type granites from anywhere in the Transantarctic Mountains. The presence of these A-type granitoids in close proximity to contemporaneous nepheline syenites and carbonatites suggests strongly that this area was undergoing extension during pluton emplacement. The occurrence of A-type granitoids at least as far south as the Skelton Glacier suggests that the atypical, extensional province, herein referred to as the Koettlitz Glacier Alkaline Province, extends for at least 60 km parallel to the Transantarctic Mountains. Alkaline magmatism in the Koettlitz Glacier Alkaline Province initiated before the generation of voluminous subduction-related calc-alkaline magmas related to the Ross Orogeny. (author). 38 refs., 7 figs., 2 tabs

  3. THE PALEOPROTEROZOIC IMANDRA-VARZUGA RIFTING STRUCTURE (KOLA PENINSULA: INTRUSIVE MAGMATISM AND MINERAGENY

    Directory of Open Access Journals (Sweden)

    V. V. Chashchin

    2015-09-01

    Full Text Available The article provides data on the structure of the Paleoproterozoic intercontinental Imandra-Varzuga rifting structure (IVS and compositions of intrusive formations typical of the early stage of the IVS development and associated mineral resources. IVS is located in the central part of the Kola region. Its length is about 350 km, and its width varies from 10 km at the flanks to 50 km in the central part. IVS contains an association of the sedimentary-volcanic, intrusive and dyke complexes. It is a part of a large igneous Paleoproterozoic province of the Fennoscandian Shield spreading for a huge area (about 1 million km2, which probably reflects the settings of the head part of the mantle plume. Two age groups of layered intrusions were associated with the initial stage of the IVS development. The layered intrusions of the Fedorovo-Pansky and Monchegorsk complexes (about 2.50 Ga are confined to the northern flank and the western closure of IVS, while intrusions of the Imandra complex (about 2.45 Ga are located at the southern flank of IVS. Intrusions of older complexes are composed of rock series from dunite to gabbro and anorthosites (Monchegorsk complex and from orthopyroxenite to gabbro and anorthosites (Fedorovo-Pansky complex. Some intrusions of this complexes reveal features of multiphase ones. The younger Imandra complex intrusions (about 2.45 Ga are stratified from orthopyroxenite to ferrogabbro. Their important feature is comagmatical connection with volcanites. All the intrusive complexes have the boninite-like mantle origin enriched by lithophyle components. Rocks of these two complexеs with different age have specific geochemical characteristics. In the rocks of the Monchegorsk and Fedorovo-Pansky complexes, the accumulation of REE clearly depends on the basicity of the rocks, the spectrum of REE is non-fractionated and ‘flat’, and the Eu positive anomaly is slightly manifested. In the rocks of the Imandra complex, the level of

  4. Perspectives of humic substances application in remediation of highly heavy metals contaminated soils in Kola Subarctic

    Science.gov (United States)

    Tregubova, Polina; Turbaevskaya, Valeria; Zakharenko, Andrey; Kadulin, Maksim; Smirnova, Irina; Stepanov, Andrey; Koptsik, Galina

    2016-04-01

    Northwestern part of Russia, the Kola Peninsula, is one of the most heavy metals (HM) contaminated areas in the northern hemisphere. The main polluters, mining-and-metallurgical integrated works "Pechenganikel" and "Severonikel", are surrounded by heavily damaged barren lands that require remediation. The main contaminating metals are Ni and Cu. Using of exogenous humic substances could be possible effective and cost-efficient solution of HM contamination problem. Rational application of humates (Na-K salts of humic acids) can result in improvement of soil properties, localization of contamination and decreasing bioavailability through binding HM in relatively immobile organic complexes. Our research aim was to evaluate the influence of increasing doses of different origin humates on i) basic properties of contaminated soils; ii) mobility and bioavailability of HMs; iii) vegetation state and chemistry. In summer 2013 a model field experiment was provided in natural conditions of the Kola Peninsula. We investigated the Al-Fe-humus abrazem, soil type that dominates in technogenic barren lands around the "Severonikel" work. These soils are strongly acid: pHH2O was 3.7-4.1; pHKCl was 3.4-4.0. The exchangeable acidity is low (0.8-1.6 cmol(+)/kg) due to the depletion of fine particles and organic matter, being the carriers of exchange positions. The abrazems of barrens had lost organic horizon. 12 sites were created in 1 km from the work. In those sites, except 2 controls, various amendments were added: i) two different by it's origin types of humates: peat-humates and coal-humates, the last were in concentrations 0.5% and 1%; ii) lime; iii) NPK-fertilizer; iv) biomates (organic degradable cover for saving warm and erosion protection). As a test-culture a grass mixture with predominance of Festuca rubra and Festuca ovina was sowed. As a result we concluded that humates of different origin have unequal influence on soil properties and cause decreasing as well as

  5. Petrology, geochemistry and thermobarometry of the northern area of the Flamenco pluton, Coastal Range batholith, northern Chile. A thermal approach to the emplacement processes in the Jurassic andean batholiths

    Science.gov (United States)

    Rodríguez, Natalia; Díaz-Alvarado, Juan; Rodríguez, Carmen; Riveros, Karl; Fuentes, Paulina

    2016-04-01

    The Flamenco pluton is part of a N-S alignment of Late Triassic to Early Jurassic intrusive belt comprising the westernmost part of the Coastal Range batholith in northern Chile. The Jurassic-Cretaceous voluminous magmatism related to subduction in the western active continental margin of Gondwana is emplaced in the predominantly metasedimentary Paleozoic host-rocks of the Las Tórtolas formation, which in the northern area of the Flamenco pluton present an intense deformation, including the Chañaral mélange. Geochemically, the Flamenco pluton shows a wide compositional variability (SiO2 between 48wt % and 67wt %). Gabbros, Qtz-diorites and tonalites, mesocratic and leucocratic granodiorites are classified as calc-alkaline, calcic, magnesian and metaluminous magmatism. Flamenco granitoids define cotectic linear evolution trends, typical of magmatic fractionation processes. Geochemical trends are consistent with magmas evolved from undersaturated and low-pressure melts, even though the absence of transitional contacts between intrusive units precludes in-situ fractionation. Although some granodioritic samples show crossed geochemical trends that point to the compositional field of metasediments, and large euhedral prismatic pinnite-biotite crystals, typical Crd pseudomorph, are observed in contact magmatic facies, geochemical assimilation processes are short range, and the occurrence of host-rocks xenoliths is limited to a few meters from the pluton contact. A thermal approach to the emplacement process has been constrained through the thermobarometric results and a 2D thermo-numerical model of the contact aureole. Some Qtz-diorites and granodiorites located in the north area of the pluton exhibit granulitic textures as Hbl-Pl-Qtz triple junctions, poikiloblastic Kfs and Qtz recrystallization. The Hbl-Pl pairs have been used for the thermobarometric study of this metamorphic process, resulting granoblastic equilibrium temperatures between 770 and 790 °C, whereas

  6. Three hydroxylated lupeol-based triterpenoid esters isolated from the Eastern Nigeria mistletoe parasitic on Kola acuminata.

    Science.gov (United States)

    Omeje, Edwin Ogechukwu; Osadebe, Patience Ogoamaka; Esimone, Charles Okechukwu; Nworu, Chukwuemeka Sylvester; Kawamura, Akira; Proksch, Peter

    2012-01-01

    Column fractionation and purification of an n-hexane fraction led to the isolation of three lupeol-based triterpenoid esters from the leaves of the Eastern Nigeria mistletoe, Loranthus micranthus Linn parasitic on a local kola nut tree, Kola acuminata. These three compounds were adequately characterised using a combination of UV/visible, IR, NMR (¹³C-NMR and ¹H-NMR), DEPT, MS and two-dimensional correlation (H-H COSY, Hetero-nuclear Single Quantum Correlation (HSQC), HMBC, NOE and NOESY) studies as 7β,15α-dihydroxyl-lup-20(29)-ene-3β-esters of palmitic (I), stearic (II) and eicosanoic acids (III). The characterisation of other isolated compounds is ongoing. Remarkably, this is the first report of the existence of fatty acid esters of an unusual 7β,15α-dihydroxylated lupeol in the Eastern Nigeria mistletoe. These isolated compounds might contribute in part to the numerous established bio-activities of the Eastern Nigeria mistletoes. PMID:22007932

  7. The alkaline and alkaline-carbonatite magmatism from Southern Brazil

    Science.gov (United States)

    Ruberti, E.; Gomes, C. D. B.; Comin-Chiaramonti, P.

    2015-12-01

    Early to Late Cretaceous lasting to Paleocene alkaline magmatism from southern Brazil is found associated with major extensional structural features in and around the Paraná Basin and grouped into various provinces on the basis of several data. Magmatism is variable in size, mode of occurrence and composition. The alkaline rocks are dominantly potassic, a few occurrences showing sodic affinity. The more abundant silicate rocks are evolved undersaturated to saturated in silica syenites, displaying large variation in igneous forms. Less evolved types are restricted to subvolcanic environments and outcrops of effusive suites occur rarely. Cumulatic mafic and ultramafic rock types are very common, particularly in the alkali-carbonatitic complexes. Carbonatite bodies are represented by Ca-carbonatites and Mg-carbonatites and more scarcely by Fe-carbonatites. Available radiometric ages for the alkaline rocks fit on three main chronological groups: around 130 Ma, subcoveal with the Early Cretaceous flood tholeiites of the Paraná Basin, 100-110 Ma and 80-90 Ma (Late Cretaceous). The alkaline magmatism also extends into Paleocene times, as indicated by ages from some volcanic lavas. Geochemically, alkaline potassic and sodic rock types are distinguished by their negative and positive Nb-Ta anomalies, respectively. Negative spikes in Nb-Ta are also a feature common to the associated tholeiitic rocks. Sr-Nd-Pb systematics confirm the contribution of both HIMU and EMI mantle components in the formation of the alkaline rocks. Notably, Early and Late Cretaceous carbonatites have the same isotopic Sr-Nd initial ratios of the associated alkaline rocks. C-O isotopic Sr-Nd isotopic ratios indicate typical mantle signature for some carbonatites and the influence of post-magmatic processes in others. Immiscibility of liquids of phonolitic composition, derived from mafic alkaline parental magmas, has been responsible for the origin of the carbonatites. Close association of alkaline

  8. Detection of pollution-induced forest decline in the Kola Peninsula using remote sensing and mathematical modelling

    Energy Technology Data Exchange (ETDEWEB)

    Rigina, Olga

    1998-07-01

    Forests on the Kola Peninsula in Northern Russia grow close to the northern tree line. They are subjected to both natural and anthropogenic stress factors. The Cu-Ni smelter 'Severonikel' (Lat. 67 deg 55'N; Long. 32 deg 57'E) near Monchegorsk is one of the two major sources of sulphur dioxide and heavy metals emissions on the Kola Peninsula. These emissions have caused significant deterioration of the surrounding vegetation. The thesis demonstrates how methods of Remote sensing, ground survey and mathematical modelling can be integrated for monitoring of the smelter's environmental impact on the surrounding vegetation: ground truth data are used for calibration of remote-sensed data, which further serve to verify mathematical models. The study aims were: * to estimate the scale of airborne sulphur pollution from the smelting industry on the Kola Peninsula and its effect on vegetation; * to assess spatial extent of the forest decline in the 'Severonikel' smelter impact zone; * to display dynamics of the forest damage area in spatial and temporal perspective; * to validate the Gaussian plume sector model and the IIASA forest impact model as components of the analysis of forest damage. The Regional Acidification Information and Simulation model (RAINS) was applied to calculate sulphur deposition and loads in Fennoscandia in order to assess the contribution of the Kola sources to the deposition pattern in the region. The percentage of the ecosystems where the critical load had been exceeded was calculated. For more detailed assessments, calculations based on local and meso-scale models were made. Landsat-MSS summer images from 1978, 1986 and 1992 and a Landsat -TM image from 1996 were used for change-detection analyses. The methods applied were bandwise histogram matching and subsequent differencing. An unsupervised classification of land-cover was made using the 1996 Landsat-TM image. In situ observations of vegetation type and

  9. Detection of pollution-induced forest decline in the Kola Peninsula using remote sensing and mathematical modelling

    International Nuclear Information System (INIS)

    Forests on the Kola Peninsula in Northern Russia grow close to the northern tree line. They are subjected to both natural and anthropogenic stress factors. The Cu-Ni smelter 'Severonikel' (Lat. 67 deg 55'N; Long. 32 deg 57'E) near Monchegorsk is one of the two major sources of sulphur dioxide and heavy metals emissions on the Kola Peninsula. These emissions have caused significant deterioration of the surrounding vegetation. The thesis demonstrates how methods of Remote sensing, ground survey and mathematical modelling can be integrated for monitoring of the smelter's environmental impact on the surrounding vegetation: ground truth data are used for calibration of remote-sensed data, which further serve to verify mathematical models. The study aims were: * to estimate the scale of airborne sulphur pollution from the smelting industry on the Kola Peninsula and its effect on vegetation; * to assess spatial extent of the forest decline in the 'Severonikel' smelter impact zone; * to display dynamics of the forest damage area in spatial and temporal perspective; * to validate the Gaussian plume sector model and the IIASA forest impact model as components of the analysis of forest damage. The Regional Acidification Information and Simulation model (RAINS) was applied to calculate sulphur deposition and loads in Fennoscandia in order to assess the contribution of the Kola sources to the deposition pattern in the region. The percentage of the ecosystems where the critical load had been exceeded was calculated. For more detailed assessments, calculations based on local and meso-scale models were made. Landsat-MSS summer images from 1978, 1986 and 1992 and a Landsat -TM image from 1996 were used for change-detection analyses. The methods applied were bandwise histogram matching and subsequent differencing. An unsupervised classification of land-cover was made using the 1996 Landsat-TM image. In situ observations of vegetation type and degradation levels on permanent field

  10. Reconstruction of mid-crustal pluton assembly and evolution using trace elements in augite: Sausfjellet pluton, Bindal batholith, north-central Norway.

    Science.gov (United States)

    Coint, Nolwenn; Barnes, Calvin; Yoshinobu, Aaron; Prestvik, Tore; Barnes, Melanie

    2013-04-01

    The Sausfjellet pluton is a 445 Ma gabbroic to monzonitic body of 7 Km in diameter emplaced in two stages at ~700 MPa pressure. Stage 1 is a coarse pyroxene hornblende gabbro. Stage 2 intrudes a steep contact between marbles on the east and pelitic migmatites on the west. Stage 2 displays a gradational transition from hornblende biotite two-pyroxene diorite to hornblende biotite three-pyroxene quartz monzonite. This transition is accompanied by a decrease in the An content of normally-zoned plagioclase from An61 to An27. Much of the pluton consists of cumulate rocks, as illustrated by the presence of anorthosite and pyroxene-rich layers. In the western part of the intrusion, hosted by metapelitic rocks, incompatible element concentrations and bulk-rock ^18O increase to levels that cannot be explained by fractional crystallization. These increases were originally explained by AFC processes, but because of the cumulative nature of the rocks, it is difficult to assess magmatic processes using bulk rock compositions. Therefore, we analyzed trace element contents and core-to-rim zoning in augite as a proxy to track changes in melt composition. Augite is normally zoned, with lower incompatible element abundances in the cores than in the rims, consistent with evolution of the melt by fractional crystallization. However, instead of plotting along a single differentiation trend, augite compositions define two trends, which is inconsistent with a closed system. The most mafic rocks define a trend with lower REE contents and smaller (negative) Eu anomalies compared to those from the more evolved part of the pluton, although the two trends overlap in Zr content. The two trends correspond to the central, more mafic zone that intrudes marble and the western, more evolved zone that intrudes metapelites. The trend associated with the western zone consists of the same samples that show bulk-rock ^18O enrichment, and is best explained as resulting from assimilation of the host

  11. ‘Diffuse faulting’ in the Machu Picchu granitoid pluton, Eastern Cordillera, Peru

    Science.gov (United States)

    Mazzoli, Stefano; Vitale, Stefano; Delmonaco, Giuseppe; Guerriero, Vincenzo; Margottini, Claudio; Spizzichino, Daniele

    2009-11-01

    A series of batholiths, forming part of the 'roots' of a Permo-Liassic rift system, are exposed in the high Eastern Cordillera of central Peru as a result of tectonic inversion. Shortening of the Machu Picchu granitoid pluton was accommodated by widespread shear reactivation of primary joints, by a process termed here 'diffuse faulting'. Fault-like reactivation of precursor joint surfaces, marked by chlorite, epidote and quartz shear fibres, is locally evidenced by few centimetres offsets within apparently undeformed granite. Analysis of fault slip data indicates that shear reactivation of different joint sets was kinematically consistent with ENE oriented shortening. Less frequent mylonitic shear zones appear to have evolved from the common brittle precursors. Apart from rare phyllonitic shear zones, fluid-rock interaction along the brittle precursors was generally limited, and pluton deformation appears to be mainly controlled by the geometry and distribution of primary joints. Three main sets of reactivated joints can be recognized, characterized by oblique-slip kinematics with variable reverse and strike-slip components of motion. Theoretical modelling based on quantitative fracture analysis (scan-line data) and different displacement-length relationships applied to the main reactivated joint sets yield first-order estimates of pluton finite strain. The results suggest that bulk finite strain is oblate and essentially coaxial, and is characterized by horizontal shortening not exceeding 10%. Relatively small finite strains, integrated over the size of the pluton, still result in a few kilometres of crustal shortening.

  12. Geochronology and geochemistry of granite plutons from east Khasi hills, Meghalaya

    International Nuclear Information System (INIS)

    Discordant granite plutons at Kyrdem, Nongpoh and South Khasi intrude the basement gneisses and the overlying Shillong Group of metasediments in the Meghalaya Plateau. Porphyritic granitoids ranging in composition from quartz monazonite to granite represent the dominant component in all the three plutons. Common characteristics of these granitoids are spatial association with homblende dioritic rocks, dominantly potassic and metaluminous nature. A positive correlation of SiO2, Na2O+K2O, Rb, Rb/Sr and negative correlation of CaO, MgO, FeO(T), Sr, TiO2 with Differentiation Index in the Kyrdem pluton point to fractional crystallisation processes. Rb-Sr whole rock isochron data of the plutons yield ages in the range 480-690 Ma with initial 87Sr/86Sr ratios ranging from 0.70948-0.71482. Absence of post emplacement tectonothermal event is suggested by near concordant K-Ar biotite ages. A protracted thermal event during late proterozoic-early paleozoic (500-700 Ma), possibly related to mantle upwelling, possibly triggered the generation of these granitoids. (author). 14 refs., 9 figs. , 6 tabs

  13. The geochemistry, age, and origin of groundwater in a mafic pluton, East Bull Lake, Ontario, Canada

    International Nuclear Information System (INIS)

    Atomic Energy of Canada Ltd. (AECL) is conducting geoscience investigations of several plutons in Canada's Precambrian Shield as part of the Canadian Nuclear Fuel Waste Management Program, to determine whether such rock masses are suitable for the safe disposal of nuclear fuel waste. The East Bull Lake (EBL) gabbro-anorthosite layered complex is unique in this program as it is the only mafic pluton in which hydrogeological and hydrogeochemical studies have been conducted. These results can be compared with those of similar studies of granitic rocks which have been investigated more extensively. During the period, 1983-85, hydrogeological testing and hydrochemical sampling were conducted by the National Hydrology Research Institute of Environment Canada and AECL in boreholes drilled to depths of up to 850 m into the EBL pluton (Raven et al., 1987). This paper discusses the hydrogeochemistry of the pluton and identifies the major rock-water interactions controlling the chemistry. The spatial variability in chemistry will be shown to be related to the nature of the groundwater flow systems present at this site. The ages and origins of the groundwaters and their solutes are inferred from isotopic analyses

  14. Field Guide to Plutonic and Metamorphic Rocks. Earth Science Curriculum Project Pamphlet Series PS-5.

    Science.gov (United States)

    Romey, William D.

    Suggested are methods for the collection of field evidence about processes that form plutonic and metamorphic rock. Description and discussion of these types of rocks are provided. The planning and execution of a successful field trip is discussed. Advanced field projects are also discussed. Included are five appendices, references, and a…

  15. Using micro-scale evidence to understand regional-scale hydrothermal alteration of plutonic rocks

    NARCIS (Netherlands)

    Plümper, O.; King, H. E.; Putnis, A.

    2009-01-01

    Subsolidus re-equilibration of plutonic feldspars induced by hydrothermal fluids provides a valuable record of fluid-rock interactions that affect large volumes of the Earth's continental crust (Taylor, 1977). The effect of hydrothermal fluids has important implications for the interpretation of the

  16. Evaluation of phase chemistry and petrochemical aspects of Samchampi–Samteran differentiated alkaline complex of Mikir Hills, northeastern India

    Indian Academy of Sciences (India)

    Abhishek Saha; Sohini Ganguly; Jyotisankar Ray; Nilanjan Chaterjee

    2010-10-01

    The Samchampi –Samteran alkaline complex occurs as a plug-like pluton within the Precambrian granite gneisses of Mikir Hills,Assam,northeastern India and it is genetically related to Sylhet Traps.The intrusive complex is marked by dominant development of syenite within which ijolite – melteigite suite of rocks is emplaced with an arcuate outcrop pattern.Inliers of alkali pyroxenite and alkali gabbro occur within this ijolite –melteigite suite of rocks.The pluton is also traversed by younger intrusives of nepheline syenite and carbonatite.Development of sporadic,lumpy magnetite ore bodies is also recorded within the pluton.Petrographic details of the constituent lithomembers of the pluton have been presented following standard nomenclatorial rules.Overall pyroxene compositions range from diopside to aegirine augite while alkali feldspars are typically orthoclase and plagioclase in syenite corresponds to oligoclase species.Phase chemistry of nepheline is suggestive of Na-rich alkaline character of the complex.Biotite compositions are typically restricted to a uniform compositional range and they belong to ‘biotite ’field in the relevant classification scheme.Garnets (developed in syenite and melteigite)typically tend to be Ti-rich andradite,which on a closer scan can be further designated as melanites.Opaque minerals mostly correspond to magnetite.Use of Lindsley ’s pyroxene thermometric method suggests an equilibration temperature from ∼450°–600°C for melteigite/alkali gabbro and ∼400° C for syenite.Critical assessment of other thermometric methods reveals a temperature of equilibration of ∼700°–1350°C for ijolite –melteigite suite of rocks in contrast to a relatively lower equilibration temperature of ∼600° C for syenite. Geobarometric data based on pyroxene chemistry yield an equilibration pressure of 5.32 –7.72 kb for ijolite,melteigite,alkali pyroxenite,alkali gabbro and nepheline syenite.The dominant syenite member of the

  17. Insights Into the Formation of Rhyolite From the Searchlight Pluton: Evidence from Oriented Quartz Clusters

    Science.gov (United States)

    Froemming, N.; Deering, C. D.; Beane, R. J.; Bachmann, O.

    2012-12-01

    The Miocene Searchlight pluton (SLP) in the Colorado River extensional corridor of southern Nevada, is well-exposed and tilted near-vertical for exceptional cross-sectional study of magma reservoir dynamics and crystal fractionation of a mid- to upper-crustal pluton (3 to 13 km depth). The upper quartz monzonite section is dominated by minerals in apparent random orientation with a medium- to fine-grained texture due to direct contact with the cold host rock. The middle granitic section is dominated by coarse-grained quartz and feldspar, and interpreted to be a zone of extracted liquid from an intermediate magma. The lower monzonite section is composed of coarse-grained plagioclase and potassium feldspar. We used the crystallographic orientations of quartz clusters, as determined by Electron Backscatter Diffraction (EBSD), to test for crystal accumulation in the SLP. Clusters of quartz crystals with matched dipyramidal faces (parallel or Esterel twin orientation) may indicate a period of crystal accumulation. By analyzing representative samples from each section of the pluton, we found that the lower section (intermediate cumulate) and upper section (crystallization front) do not have quartz clusters with matched dipyramidal faces. Although plagioclase grains are aligned in the lower section, the late crystallization of quartz appears to have prevented aligned or preferred growth orientations. In contrast, the middle section has a high percentage of quartz clusters with matched dipyramidal faces - similar to that found in granite porphyry of the Vinalhaven pluton, Maine. The aligned grains may have formed by fractional crystallization, compaction and synneusis of the early forming quartz in this granitic section. We interpret the middle section of the Searchlight pluton as being similar to shallow, upper crustal plutons (3-8 km depth) such as Vinalhaven pluton. The deep vertical exposure of the SLP, shows that the middle section was formed from periodic episodes of

  18. Magnetic fabrics and their relationship with the emplacement of the Piracaia pluton, SE Brazil

    Science.gov (United States)

    Raposo, M. Irene B.; Pressi, Leonardo Frederico; de Assis Janasi, Valdecir

    2012-04-01

    Magnetic fabric and rock-magnetism studies were performed on the four units of the 578 ± 3-Ma-old Piracaia pluton (NW of São Paulo State, southern Brazil). This intrusion is roughly elliptical (~32 km2), composed of (i) coarse-grained monzodiorite (MZD-c), (ii) fine-grained monzodiorite (MZD-f), which is predominant in the pluton, (iii) monzonite heterogeneous (MZN-het), and (iv) quartz syenite (Qz-Sy). Magnetic fabrics were determined by applying both anisotropy of low-field magnetic susceptibility (AMS) and anisotropy of anhysteretic remanent magnetization (AARM). The two fabrics are coaxial. The parallelism between AMS and AARM tensors excludes the presence of a single domain (SD) effect on the AMS fabric of the units. Several rock-magnetism experiments performed in one specimen from each sampled units show that for all of them, the magnetic susceptibility and magnetic fabrics are carried by magnetite grains, which was also observed in the thin sections. Foliations and lineations in the units were successfully determined by applying magnetic methods. Most of the magnetic foliations are steeply dipping or vertical in all units and are roughly parallel to the foliation measured in the field and in the country rocks. In contrast, the magnetic lineations present mostly low plunges for the whole pluton. However, for eight sites, they are steep up to vertical. Thin-section analyses show that rocks from the Piracaia pluton were affected by the regional strain during and after emplacement since magmatic foliation evolves to solid-state fabric in the north of the pluton, indicating that magnetic fabrics in this area of the pluton are related to this strain. Otherwise, the lack of solid-state deformation at outcrop scale and in thin sections precludes deformation in the SW of the pluton. This evidence allows us to interpret the observed magnetic fabrics as primary in origin (magmatic) acquired when the rocks were solidified as a result of magma flow, in which steeply

  19. Apatite trace element and halogen compositions as petrogenetic-metallogenic indicators: Examples from four granite plutons in the Sanjiang region, SW China

    Science.gov (United States)

    Pan, Li-Chuan; Hu, Rui-Zhong; Wang, Xin-Song; Bi, Xian-Wu; Zhu, Jing-Jing; Li, Chusi

    2016-06-01

    The abundances of trace elements including Sr, Ga and rare earth elements (REE) and halogens in apatite crystals from four intermediate-felsic plutons in the Zhongdian terrane in the Sanjiang region have been determined using electron microprobe and laser ablation inductively coupled plasma mass spectrometry to evaluate the potential of apatite as a petrogenic-metallogenic indicator. The selected plutons include one that is not mineralized (the Triassic Xiuwacu pluton, or the TXWC pluton), one that hosts a porphyry-type Cu deposit (the Pulang pluton, or the PL pluton), one that hosts a porphyry-type Mo deposit (the Tongchanggou pluton, or the TCG pluton), and one that hosts a vein-type Mo deposit (the Cretaceous Xiuwacu pluton, or the CXWC pluton). Except for the CXWC pluton, the other three plutons have adakite-like trace element signatures in whole rocks. The results from this study show that REE, Sr and halogens in apatite can be used to track magma compositions, oxidation states and crystallization history. Apatite crystals from the adakite-like plutons are characterized by much higher Sr/Y and δEu than the non-adakite-type pluton. This means that apatite, which is not susceptible to alteration, is a useful tool for identifying the adakite-like plutons that no longer preserve the initial Sr/Y ratios in whole rocks due to weathering and hydrothermal alteration. Based on apatite Ga contents and δEu values, it is inferred that the parental magmas for the two adakite-like plutons containing porphyry-type Cu and Mo mineralization are more oxidized than that for the non-adakite-type pluton containing vein-type Mo mineralization. Apatite crystals from the vein-type Mo deposit have much lower Cl/F ratios than those from the porphyry-type Cu and Mo deposits. Apatite crystals from the adakite-like pluton without Cu or Mo mineralization is characterized by much lower Cl/F ratios than those from the adakite-like plutons that host the porphyry-type Cu and Mo deposits. The

  20. The rapakivi granite plutons of Bodom and Obbnäs, southern Finland: petrography and geochemistry

    Directory of Open Access Journals (Sweden)

    Kosunen, P.

    1999-12-01

    Full Text Available The Obbnäs and Bodom granite plutons of southernmost Finland show the typical petrographic and geochemical features of the Proterozoic rapakivi granites in Finland and elsewhere: they cut sharply across the 1900 Ma Svecofennian metamorphic bedrock and have the geochemical characteristics of subalkaline A-type granites. The Bodom pluton is composed of porphyritic granites (hornblende-, hornblende-biotite-, and biotite-bearing varieties and an even-grained granite that probably represent two separate intrusive phases. This lithologic variation does not occur in the Obbnäs pluton, which is almost entirely composed of porphyritic hornblende-biotite granite that gradually becomes more mafic to the southwest. Three types of hybrid granitoids resulting from magma mingling and mixing occur on the southwestern tip of the Obbnäs peninsula. The Bodom granites are syenogranites, whereas the composition of the Obbnäs granite varies from syeno- to monzogranite. The main silicates of both the Bodom and Obbnäs granites are quartz, microcline, plagioclase (An1541, biotite (siderophyllite, and generally also amphibole (ferropargasite or hastingsite. Plagioclase-mantled alkali feldspar megacrysts are absent or rare. The accessory minerals are fluorite, allanite, zircon, apatite, and iron-titanium oxides; the Obbnäs granite also contains titanite. The Bodom and Obbnäs granites are metaluminous to weakly peraluminous, with average A/CNK of 1.00 and 1.05, respectively, have high Fe/Mg (average FeOtot/[FeOtot+MgO] is 0.94 for the Bodom and 0.87 for the Obbnäs granites, and high Ga/Al (3.78 to 5.22 in Bodom and 2.46 to 4.18 in Obbnäs. The REE contents are high with LREE-enriched chondrite-normalized patterns and moderate (Obbnäs to relatively strong (Bodom negative Eu-anomalies. The Obbnäs granite is enriched in CaO, TiO2, MgO, and FeO, and depleted in SiO2 and K2O compared to the Bodom granites. Also, there are differences in the Ba, Rb, and Sr contents of

  1. 2nd Generation Alkaline Electrolysis

    DEFF Research Database (Denmark)

    Yde, Lars; Kjartansdóttir, Cecilia Kristin; Allebrod, Frank; Mogensen, Mogens Bjerg; Møller, Per; Hilbert, Lisbeth R.; Nielsen, Peter Tommy; Mathiesen, Troels; Jensen, Jørgen; Andersen, Lars; Dierking, Alexander

    This report provides the results of the 2nd Generation Alkaline Electrolysis project which was initiated in 2008. The project has been conducted from 2009-2012 by a consortium comprising Århus University Business and Social Science – Centre for Energy Technologies (CET (former HIRC)), Technical...

  2. Varaždinski kolegij i gimnazija u mreži isusovačkih europskih škola

    OpenAIRE

    MATIĆ, IVAN

    2007-01-01

    Prosvjetni rad je od početaka Družbe Isusove bio jedna od najvažnijih njezinih djelatnosti. Trebalo je proći 50 godina do nastanka konačne verzije „ratio studiorum“, najuspješnijeg plana studija u povijesti školstva. Isusovačke škole u Hrvatskoj bile su dio europske mreže škola. Varaždinski kolegij otvoren svečano je otvoren 18. prosinca 1678. godine, gimnazija čak 40 godina ranije. Velikim brojem učenika (uvijek oko 300) ubraja se među najznačajnije kolegije na ovom području. Nastava i cjelo...

  3. In Vitro Anti-Listerial Activities of Crude n-Hexane and Aqueous Extracts of Garcinia kola (heckel Seeds

    Directory of Open Access Journals (Sweden)

    Anthony I. Okoh

    2011-10-01

    Full Text Available We assessed the anti-Listerial activities of crude n-hexane and aqueous extracts of Garcinia kola seeds against a panel of 42 Listeria isolates previously isolated from wastewater effluents in the Eastern Cape Province of South Africa and belonging to Listeria monocytogenes, Listeria grayi and Listeria ivanovii species. The n-hexane fraction was active against 45% of the test bacteria with zones of inhibition ranging between 8–17 mm, while the aqueous fraction was active against 29% with zones of inhibition ranging between 8–11 mm. The minimum inhibitory concentrations (MIC were within the ranges of 0.079–0.625 mg/mL for the n-hexane extract and 10 to >10 mg/mL for the aqueous extract. The rate of kill experiment carried out for the n-hexane extract only, revealed complete elimination of the initial bacterial population for L. grayi (LAL 15 at 3× and 4× MIC after 90 and 60 min; L. monocytogenes (LAL 8 at 3× and 4× MIC after 60 and 15 min; L. ivanovii (LEL 18 at 3× and 4× MIC after 120 and 15 min; L. ivanovii (LEL 30 at 2, 3 and 4× MIC values after 105, 90 and 15 min exposure time respectively. The rate of kill activities were time- and concentration-dependant and the extract proved to be bactericidal as it achieved a more than 3log10 decrease in viable cell counts after 2 h exposure time for all of the four test organisms at 3× and 4× MIC values. The results therefore show the potential presence of anti-Listerial compounds in Garcinia kola seeds that can be exploited in effective anti-Listerial chemotherapy.

  4. Central planning, market and subsistence from a tundra perspective: Field experience with reindeer herders in the Kola Peninsula

    Directory of Open Access Journals (Sweden)

    Dessislav Sabev

    2002-04-01

    Full Text Available This paper is based on field experience in the tundra camp of a reindeer-herding brigade with mixed ethnic background (Komi, Sami, Nenets, Russians belonging to the ex-Sovkhoz of Krasnoschelie. Its purpose is to situate the new critical issues facing the reindeer-herding collectives after the economic collapse in Russia in 1998. My main argument is that the increasing economic isolation of the tundra periphery forces the herders to redefine their relationship with both the centre(s and the other tundra actors. Reindeer herding on the Kola Peninsula is analysed in relation to its heterogeneous economic system defined by the old Sovkhoz-like management and the new Western buyer of reindeer meat. Furthermore, the social environment in the herding territories has changed since the deterioration of the central planning economy, implying new renewable resources' users. After massive loss of jobs, militaries, miners and geologists came into the tundra for substantial hunting and fishing and so became actors in the local informal economy. Finally, tundra-located herders and hunters seem to be somewhere unified by a discourse against the town-based administrative power and economic actors such as mining industry. Therefore herders have to deal with both an old administrative system in the agrocentre and new realities in the tundra. Based on a case study of herding/hunting activities in a tundra camp, the paper analyses the social relationships between the different actors in the post-Soviet Kola tundra and express their quest for solutions.

  5. Electromagnetic studies on the Kola peninsula and in Northern Finland by means of a powerful controlled source

    Science.gov (United States)

    Velikhov, Ye. P.; Zhamaletdinov, A. A.; Belkov, I. V.; Gorbunov, G. I.; Hjelt, S. E.; Lisin, A. S.; Vanyan, L. L.; Zhdanov, M. S.; Demidova, T. A.; Korja, T.; Kirillov, S. K.; Kuksa, Yu. I.; Poltanov, A. Ye.; Tokarev, A. D.; Yevstigneyev, V. V.

    1986-07-01

    Station "Khibiny", equipped with a powerful magnetohydrodynamic (MHD) generator and/or diesel generator, has been successfully used since 1976 to study the electrical conductivity of the Earth's crust in the northern part of the Baltic Shield. The present paper describes the techniques of measurement, data processing and interpretation of the five-component electromagnetic fields created by this source. A longitudinal conductance map for the upper 10 km of the Earth's crust has been constructed. Several blocks, with conductances varying from 0.1 to some thousands of Siemens, have been revealed on the Kola Peninsula, in northern Karelia and in northern Finland. The blocks of high conductance are connected with relatively young complexes of Early Proterozoic and Late Archean ages. In some places, they create thick and extensive conductive belts such as the Imandra-Varzuga and the Pechenga zones. More often, they appear in the shape of vast regions with enhanced conductivity (e.g., the granulite belts and the Allarechen region). The geoelectric cross-section of the Imandra-Varzuga ore-critical structure has been studied in detail, using the method of electromagnetic field migration. Its depth extent is approximately 10 km. Highly resistant blocks are associated with the most ancient geological units, of early Archean age. Resistant regions have been found in the Murmansk and Central Kola regions, as well as in the Kovdor massif and in the Central Finland granite area. These regions are the most promising ones for deep electromagnetic sounding of the lower crust and the upper mantle of the Earth.

  6. Induced seismicity in large-scale mining in the kola peninsula and monitoring to reveal informative precursors

    Science.gov (United States)

    Melnikov, N. N.; Kozyrev, A. A.; Panin, V. I.

    1996-07-01

    Large volumes of rock mass, mined-out and moved within these deposits, resulted in irreversible changes in the geodynamic regime in the upper earth's crust of the adjacent territory. These changes manifest themselves in a more frequent occurrence of such intensive dynamic phenomena as tectonic rock bursts due to fault movement adjacent to the area which is mined-out and man-made earthquakes which sharply decrease mining safety and result in great material losses. To develop the prediction techniques of such phenomena, a monitoring system is created, based on the program of the Kola Complex of geodynamic measuring stations. Most of this system is realized in the region of the Khibiny apatite mines. The system provides regional seismological monitoring, local prediction of seismicity in separate areas of a rock mass and, determination of stress and strain in rock masses, local geophysical monitoring over the state of rocks in a rock mass as well as physical and mathematical modelling of geodynamic processes in the upper earth's crust. The investigations have resulted in the distinguishing of some regularities in manifestations of induced seismicity and tectonic rock bursts and in the determination of strain precursors of intensive seismic events in the Khibiny mines. The mechanism is provided by the induced seismicity which resulted from the anthropogenic impact on the geological medium. A geodynamic monitoring complex is described, which is used to reveal the precursors of powerful seismic events in situ, and monitoring results are shown, obtained in the Kola Complex of geodynamic stations. Methods of preventing tectonic rock bursts and induced earthquakes are presented.

  7. Petrology and U-Pb geochronology of buried Avalonian plutonic rocks on southeastern Cape Cod

    Science.gov (United States)

    Leo, G.W.; Mortensen, J.K.; Barreiro, B.; Phillips, J.D.

    1993-01-01

    Plutonic rocks have been intersected by two separate drill holes on souteastern Cape Cod. Hole CC2 is located about 7 km south of the Nauset anomaly, an east-northeast-trending magnetic lineament that was considered to separate the distinct plutonic zones of Avalon terrane. This drill hole intersected weakly foliated, fairly homogeneous biotite granite. Zircons from this granite give a U-Pb age of 584+9/-8 Ma. Hole CC1 is located about 12 km north of the Nauset anomaly. The drill core intersected foliated, sheared, biotite granodiorite and biotite-hornblende-clinopyroxene-quartz gabbro, metamorphosed to greenschist facies. The deformed and altered state of these rocks, as well as their geochemistry, suggest that their origin and possibly their ages are distinct from the granite in hole CC2. No datable zircons were obtained from rocks in CC1. -from Authors

  8. Isotopic studies of the late Archean plutonic rocks of the Wind River Range, Wyoming.

    Science.gov (United States)

    Stuckless, J.S.; Hedge, C.E.; Worl, R.G.; Simmons, K.R.; Nkomo, I.T.; Wenner, D.B.

    1985-01-01

    Two late Archaean intrusive events were documented in the Wind River Range by isotopic studies of the Rb-Sr and U-Th-Pb systems in whole-rock samples and the U-Pb systematics for zircon. An age of approx 2630(20) m.y. for the Louis Lake batholith and apparent ages of 2504(40) to 2575(50) m.y. for the Bear Ears pluton were obtained. Post-magmatic hydrothermal events approximately Tertiary in age, lowered delta 18O values and disturbed parent-daughter relationships in most of the isotopic systems investigated. The two intrusive units apparently were derived from different protoliths. Initial isotopic ratios and petrochemistry for the Louis Lake batholith are consistent with an early Archaean trondhjemitic to tonalitic source. The protolith for the Bear Ears pluton must have been subjected to high-grade metamorphism that caused loss of Rb and U prior to magma generation. -L.C.H.

  9. Contributions to pegmatite exploration within granitic plutons in Central and Northern Portugal

    OpenAIRE

    Pereira, B; Azevedo, J.; de Oliveira, J.; Dias, P. A.; Gomes, C. Leal; Carvalho, José

    2013-01-01

    Exploration programs for granitic pegmatites face the lack of detectable contrasts, either geophysical or geochemical, between pegmatites and their granitic host-rocks. The known productive sectors bearing pegmatites located inside granitic plutons, with economic interest for quartz and feldspar provide adequate field testing for alternative research, dealing with the peculiarities of lithological diversity and the arrangement of structural elements, around pegmatite swarms at suitable granit...

  10. Potassium-argon and lead-alpha ages of plutonic rocks, Bokan Mountain area, Alaska

    Science.gov (United States)

    Lanphere, M.A.; MacKevett, E.M., Jr.; Stern, T.W.

    1964-01-01

    Most of the granitic rocks in the Bokan Mountain area, southeastern Alaska, are early Paleozoic (probably Ordovician) judged by potassium-argon and lead-alpha age measurements. The Bokan Mountain Granite, the youngest intrusive unit in the area, belongs to a Mesozoic plutonic episode. These age measurements are the first direct evidence for the emplacement of early Paleozoic granitic intrusive rocks close to the Pacific margin of North America.

  11. Potassium-Argon and Lead-Alpha Ages of Plutonic Rocks, Bokan Mountain Area, Alaska.

    Science.gov (United States)

    Lanphere, M A; Mackevett, E M; Stern, T W

    1964-08-14

    Most of the granitic rocks in the Bokan Mountain area, southeastern Alaska, are early Paleozoic (probably Ordovician) judged by potassium-argon and lead-alpha age measurements. The Bokan Mountain Granite, the youngest intrusive unit in the area, belongs to a Mesozoic plutonic episode. These age measurements are the first direct evidence for the emplacement of early Paleozoic granitic intrusive rocks close to the Pacific margin of North America. PMID:17754670

  12. Tertiary plutonic rocks of southern Serbia Vardar Zone as dimension stone

    OpenAIRE

    Kurešević Lidja; Simić Vladimir

    2014-01-01

    Three granitoid plutons of south-Serbian part of the Vardar Zone, of Tertiary age were studied in order to establish their potential for utilization as dimension stone. These rocks vary in composition from quartzmonconite to quartzdiorite. Field study aimed at establishing the geological factors - presence of fractures, harmful minerals, alterations, jointing type and fabric homogeneity in order to determine the possibility of obtaining large size blocks of...

  13. Volcanic-plutonic connections in a tilted nested caldera complex in Hong Kong

    OpenAIRE

    Sewell, Roderick J.; Tang, Denise L.K.; Campbell, S. Diarmad G.

    2012-01-01

    Exceptional exposures of four, precisely-dated, Middle Jurassic to Early Cretaceous,silicic volcanic centers and their plutonic equivalents in Hong Kong have provided an excellent opportunity to examine close connections in time and space between magma chambers and their overlying calderas. Here, we describe a ~14 km crustal section through a collapsed caldera in southeastern Hong Kong where the intracaldera fill suggests that the magmatic discharge was of supereruption scale. The main subvol...

  14. Geochemical evaluation of felsic plutonic rocks in the eastern and southeastern Arabian Shield, Kingdom of Saudi Arabia

    Science.gov (United States)

    Du Bray, E.A.; Elliott, James E.; Stoeser, D.B.

    1983-01-01

    In a geochemical evaluation of the eastern and southeastern Arabian Shield, which included collection of 696 rock samples and 694 pan concentrate samples, a province of tin-anomalous granitoid plutons was defined. Pan concentrates collected in and around these plutons were enriched in tin and tungsten relative to the concentrate population. Rock samples of these leucocratic, muscovite-bearing, peraluminous granites contained anomalously high concentrations of lithium, fluorine, beryllium, lead, rubidium, niobium, yttrium, tin, bismuth, silver, and tungsten. Ten tin-anomalous plutons were located in the study area. The plutons are typically small, less than 10 km2 in areal extent, and circular to elliptical in plan view. The resource potential of these latest Proterozoic plutons has not been established; economically exploitable concentrations of tin, tungsten, molybdenum, or zinc may be present, and followup studies are warranted. Further, two of the plutons are characterized by higher than normal total-count radioactivity and have potential for uranium, thorium, or rare-earth element deposits.

  15. Two stages of isotopic exchanges experienced by the Ertaibei granite pluton, northern Xinjiang, China

    Institute of Scientific and Technical Information of China (English)

    刘伟

    2000-01-01

    18O/16O and D/H of coexisting feldspar, quartz, and biotite separates of twenty samples collected from the Ertaibei granite pluton, northern Xinjiang, China are determined. It is shown that the Ertaibei pluton experienced two stages of isotopic exchanges. The second stage of 18O/16O and D/H exchanges with meteoric water brought about a marked decrease in the δ18O values of feldspar and biotite from the second group of samples. The D/H of biotite exhibits a higher sensitivity to the meteoric water alteration than its 18O/16O. However, the first stage of 18O/16O exchange with the 18O-rich aqueous fluid derived from the dehydration within the deep crust caused the Δ18OQuariz-Feidspar reversal. It is inferred that the dehydration-melting may have been an important mechanism for anatexis. It is shown that the deep fluid encircled the Ertaibei pluton like an envelope which serves as an effective screen to the surface waters.

  16. Two stages of isotopic exchanges experienced by the Ertaibei granite pluton, northern Xinjiang, China

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    18O/16O and D/H of coexisting feldspar, quartz, and biotite separates of twenty samples collected from the Ertaibei granite pluton, northern Xinjiang, China are determined. It is shown that the Ertaibei pluton experienced two stages of isotopic exchanges. The second stage of 18O/16O and D/H exchanges with meteoric water brought about a marked decrease in the δ18O values of feldspar and biotite from the second group of samples. The D/H of biotite exhibits a higher sensitivity to the meteoric water alteration than its 18O/16O. However, the first stage of 18O/16O exchange with the 18O-rich aqueous fluid derived from the dehydration within the deep crust caused the δ18OQuartz-Feldspar reversal. It is inferred that the dehydration-melting may have been an important mechanism for anatexis. It is shown that the deep fluid encircled the Ertaibei pluton like an envelope which serves as an effective screen to the surface waters.

  17. Age paradoxes of Devonian magmatism of the northeastern part of the Kola Peninsula

    Science.gov (United States)

    Terekhov, E. N.; Baluev, A. S.; Shcherbakova, T. F.; Ipat'eva, I. S.

    2012-02-01

    A structural-geochemical study has been conducted on the dikes of presumably Devonian mafic rocks confined to a small graben filled in with Riphean sedimentary rocks hosted by Early Precambrian granite-gneiss of the Murmansk block. It has been demonstrated that the dolerite dikes of this region can be considered as manifestations of trap magmatism whose products fill in the foundation of the East Barents riftogenic downfold. In turn, manifestations of alkaline and kimberlite rocks of the White Sea region are confined to the peripheral portion of the trap magnetism area. Zircons from dolerite transecting Late Riphean sediments examined in two laboratories have a concordant age of 2.74-2.72 Ba, while zircons from a similar dike located in granite-gneiss of the basement are characterized by an age range of 2700-155 Ma, and the concordant age based on 4 points is 790 Ma. All these factors indicate that the age determinations of the mafic rocks are ambiguous, particularly in the zone of transition from the center of the trap province to its periphery, where alkaline magmatism is observed.

  18. Development of alkaline fuel cells.

    Energy Technology Data Exchange (ETDEWEB)

    Hibbs, Michael R.; Jenkins, Janelle E.; Alam, Todd Michael; Janarthanan, Rajeswari [Colorado School of Mines, Golden, CO; Horan, James L. [Colorado School of Mines, Golden, CO; Caire, Benjamin R. [Colorado School of Mines, Golden, CO; Ziegler, Zachary C. [Colorado School of Mines, Golden, CO; Herring, Andrew M. [Colorado School of Mines, Golden, CO; Yang, Yuan [Colorado School of Mines, Golden, CO; Zuo, Xiaobing [Argonne National Laboratory, Argonne, IL; Robson, Michael H. [University of New Mexico, Albuquerque, NM; Artyushkova, Kateryna [University of New Mexico, Albuquerque, NM; Patterson, Wendy [University of New Mexico, Albuquerque, NM; Atanassov, Plamen Borissov [University of New Mexico, Albuquerque, NM

    2013-09-01

    This project focuses on the development and demonstration of anion exchange membrane (AEM) fuel cells for portable power applications. Novel polymeric anion exchange membranes and ionomers with high chemical stabilities were prepared characterized by researchers at Sandia National Laboratories. Durable, non-precious metal catalysts were prepared by Dr. Plamen Atanassov's research group at the University of New Mexico by utilizing an aerosol-based process to prepare templated nano-structures. Dr. Andy Herring's group at the Colorado School of Mines combined all of these materials to fabricate and test membrane electrode assemblies for single cell testing in a methanol-fueled alkaline system. The highest power density achieved in this study was 54 mW/cm2 which was 90% of the project target and the highest reported power density for a direct methanol alkaline fuel cell.

  19. An unusually rich scuttle fly fauna (Diptera, Phoridae from north of the Arctic Circle in the Kola Peninsula, N. W. Russia

    Directory of Open Access Journals (Sweden)

    R. Henry Disney

    2013-10-01

    Full Text Available 64 species of Phoridae, in 6 genera, are reported from the Kola Peninsula, north of the Arctic Circle. The new species Megaselia elenae and M. kozlovi are described. 33 species of Megaselia, only known from females, are given code numbers. Keys to the species of all the females of Megaselia and Phora are provided; and also a key to the males European Megaselia species with a notopleural cleft.

  20. Evaluation of the dust and methanol extracts of Garcinia kolae for the control of Callosobruchus maculatus (F.) and Sitophilus zeamais (Mots)

    OpenAIRE

    Ogunleye, R.F.; Adefemi, S.O.

    2007-01-01

    Insecticidal effects of different doses of the dust and methanol extracts of Garcinia kolae on Callosobruchus maculatus and Sitophilus zeamais were tested. The dust had no significant effect on the two insects; none of them died even at 3 d after treatment. The methanol extracts, however, had rapid lethal effects on both C. maculatus and S. zeamais. The mortality of C. maculatus by the lowest concentration of methanol extracts ranged from 95%~100% whereas in S. zeamais, the mortality ranged f...

  1. A pilot study on the distribution of 137Cs between vegetation and soil in an industrial pollution gradient at the Kola peninsula

    International Nuclear Information System (INIS)

    The activity concentration of radiocesium in dwarf shrubs, mosses, organic and inorganic soil was studied in an industrial pollution gradient from the Monchegorsk smelter at the Kola peninsula. As expected the highest values for vegetation was found in mosses/lichens followed by dwarf shrubs. The transfer factor between organic and vascular vegetation was ten times higher in the control area (100 km from the smelter) than in the affected areas (7 to 31 km from the smelter). 3 refs

  2. Natural radioactivity and radiation index of the major plutonic bodies in Greece

    International Nuclear Information System (INIS)

    The natural radioactivity of the major plutonic bodies in Greece, as well as the assessment of any potential health hazard due to their usage as decorative building materials is studied. One hundred and twenty one samples from every major plutonic body in Greece, including various rock-types from gabbro to granite, have been measured for their natural radioactivity using γ-spectrometry methodology. According to the experimental results, the natural radioactivity levels were ranged up to 315 Bq kg−1 for 226Ra, up to 376 Bq kg−1 for 232Th and up to 1632 Bq kg−1 for 40K, with arithmetic mean values and standard deviations of 74 (±51), 85 (±54) and 881 (±331) Bq kg−1 respectively, which are below the international representative mean values for granite stones. The excess on the effective dose received annually indoors due to granite tiles usage is estimated considering a standard room model where granite tiles with 1.5 cm in thickness cover only the floor of the room. The increment on the external γ-radiation effective dose rate shows a Gaussian distribution well dispersed below 0.3 mSv y−1, presenting a mean value of 0.14 (±0.06) mSv y−1. In case of the internal α-radiation a log-normal distribution is appeared scattering below 0.5 mSv y−1 with a mean value 0.19 (±0.13) mSv y−1, for a well-ventilated living environment. In case of a poor-ventilated room the increment on internal effective dose rate is estimated with a mean value 0.27 (±0.19) mSv y−1 scattering below 0.8 mSv y−1. The majority of the samples increase the external as well as the internal dose less than 30% of the maximum permitted limit of the effective dose rate. Therefore, at least from radiological point of view, the plutonic rocks of Greece could be safely used as decorative building materials. -- Highlights: • Data upon natural radioactivity of all the major plutons of Greece are presented. • The samples from Pelagonian zone present the lower excess of the total

  3. From Migmatites to Plutons: Power Law Relationships in the Evolution of Magmatic Bodies

    Science.gov (United States)

    Soesoo, Alvar; Bons, Paul D.

    2015-07-01

    Magma is generated by partial melting from micrometre-scale droplets at the source and may accumulate to form >100 km-scale plutons. Magma accumulation thus spans well over ten orders of magnitude in scale. Here we provide measurements of migmatitic leucosomes and granitic veins in drill cores from the Estonian Proterozoic basement and outcrops at Masku in SW Finland and Montemor-o-Novo, central Portugal. Despite the differences in size and number of measured leucosomes and magmatic veins, differences in host rock types and metamorphic grades, the cumulative width distribution of the studied magmatic leucosomes/veins follows a power law with exponents usually between 0.7 and 1.8. Published maps of the SE Australian Lachlan Fold Belt were used to investigate the distribution of granitoid pluton sizes. The granites occupy ca. 22 % of the 2.6 × 105 km2 area. The cumulative pluton area distributions show good power law distributions with exponents between 0.6 and 0.8 depending on pluton area group. Using the self-affine nature of pluton shapes, it is possible to estimate the total volume of magma that was expelled from the source in the 2.6 × 105 km2 map area, giving an estimated 0.8 km3 of magma per km2. It has been suggested in the literature that magma batches in the source merge to form ever-bigger batches in a self-organized way. This leads to a power law for the cumulative distribution of magma volumes, with an exponent m V between 1 for inefficient melt extraction, and 2/3 for maximum accumulation efficiency as most of the volume resides in the largest batches that can escape from the source. If m V ≥ 1, the mass of the magma is dominated by small batches; in case m = 2/3, about 50 % of all magma in the system is placed in a single largest batch. Our observations support the model that the crust develops a self-organized critical state during magma generation. In this state, magma batches accumulate in a non-continuous, step-wise manner to form ever

  4. Geology, petrology and U-Pb geochronology of Serra da Rajada Granitic Pluton: implications about ediacaran magmatic evolution in NE portion of the Rio Piranhas-Serido Domain (NE of Borborema Province); Geologia, petrologia e geocronologia U-Pb do Pluton Granitico Serra da Rajada: implicacoes sobre a evolucao magmatica ediacarana na porcao do Dominio Rio Piranhas-Serido (NE da Provincia Borborema)

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Alan Pereira da; Dantas, Alexandre Ranier, E-mail: alan.costa@cprm.gov.br, E-mail: alexandre.dantas@cprm.gov.br [Servico Geologico do Brasil (CPRM), Natal, RN (Brazil). Nucleo de Apoio de Natal/Superintendencia Regional de Recife; Nascimento, Marcos Antonio Leite do; Galindo, Antonio Carlos, E-mail: marcos@geologia.ufrn.br, E-mail: galindo@geologia.ufrn.br [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Departamento de Geologia

    2015-12-15

    The Ediacaran plutonic activity, related to the Brazilian/Pan-African orogeny, is one of the most important geological features in the Borborema Province, formed by batholiths, stocks and dikes. The Serra da Rajada Granitic Pluton (SRGP), located in the central portion of the Rio Piranhas-Serido Domain, is an example of these bodies. This site is the target of cartographic, petrographic, lithochemical and geochronological studies. Its rocks are described as monzogranites consisting of K-feldspar, plagioclase (oligoclase-An{sub 23-24%}), quartz and biotite (main mafic), having as accessory minerals opaque, titanite, allanite, apatite and zircon. Chlorite, white mica and carbonate are alteration minerals. Lithochemical data from 15 samples show quite evolved rocks (SiO{sub 2} , 69% to 75%), rich in alkalis (Na{sub 2}O + K{sub 2}O ≥ 8.0%), depleted in MgO (≤ 0.45%), CaO (≤ 1.42%) and TiO{sub 2} (≤ 0.36%), and displaying moderate levels of Fe{sub 2}O{sub 3} t (2.16 to 3.53%). These rocks present a transitional nature between metaluminous and peraluminous (predominance of the latter) and have subalkaline/monzonitic affinity (high-K Calc-alkaline). Harker diagrams represent negative correlations in Fe{sub 2}O{sub 3}t, MgO and CaO, indicating fractionation of mafic and plagioclase. The REE spectrum show enrichment of light in relation to heavy REE (LaN/YbN = 23.70 to 10.13), with negative anomaly in Eu (Eu/ Eu* = 0.70 to 10.13) suggesting fractionation or accumulation in the feldspars source (plagioclase). Data integration allows correlating the SRGP rocks with those described as Equigranular high-K Calc-alkaline Suite. The U-Pb geochronology and Sm-Nd isotope dating indicate that the biotite monzogranite have a crystallization age of 557 ± 13 Ma and TDM model age of 2.36 Ga, respectively, and ε{sub Nd} value of - 20.10 for the crystallization age, allowing to infer a crustal source for the magma generated in the Paleoproterozoic age. (author)

  5. Fingerprinting and validation of a LC-DAD method for the analysis of biflavanones in Garcinia kola-based antimalarial improved traditional medicines.

    Science.gov (United States)

    Tshibangu, P Tshisekedi; Kapepula, P Mutwale; Kapinga, M J Kabongo; Lupona, H Kabika; Ngombe, N Kabamba; Kalenda, Dibungi T; Jansen, O; Wauters, J N; Tits, M; Angenot, L; Rozet, E; Hubert, Ph; Marini, R D; Frédérich, M

    2016-09-01

    African populations use traditional medicines in their initial attempt to treat a range of diseases. Nevertheless, accurate knowledge of the composition of these drugs remains a challenge in terms of ensuring the health of population and in order to advance towards improved traditional medicines (ITMs). In this paper chromatographic methods were developed for qualitative and quantitative analyses of a per os antimalarial ITM containing Garcinia kola. The identified analytical markers were used to establish TLC and HPLC fingerprints. G. kola seeds were analysed by HPLC to confirm the identity of the extract used by the Congolese manufacturer in the ITM. The main compounds (GB1, GB2, GB-1a and Kolaflavanone) were isolated by preparative TLC and identified by UPLC-MS and NMR. For the quantification of the major compound GB1, a simple and rapid experimental design was applied to develop an LC method, and then its validation was demonstrated using the total error strategy with the accuracy profile as a decision tool. The accurate results were observed within 0.14-0.45mg/mL range of GB1 expressed as naringenin. The extracts used in several batches of the analysed oral solutions contained GB1 (expressed as naringenin) within 2.04-2.43%. Both the fingerprints and the validated LC-DAD were found suitable for the quality control of G. kola-based raw material and finished products, respectively. PMID:27343901

  6. INSTALLATION OF A POST-ACCIDENT CONFINEMENT HIGH-LEVEL RADIATION MONITORING SYSTEM IN THE KOLA NUCLEAR POWER STATION (UNIT 2) IN RUSSIA

    International Nuclear Information System (INIS)

    This is the final report on the INSP project entitled, ''Post-Accident Confinement High-Level Radiation Monitoring System'' conducted by BNL under the authorization of Project Work Plan WBS 1.2.2.6 (Attachment 1). This project was initiated in February 1993 to assist the Russians in reducing risks associated with the continued operation of older Soviet-designed nuclear power plants, specifically the Kola VVER-440/230 Unit 2, through improved accident detection capability, specifically by the installation of a dual train high-level radiation detection system in the confinement of Unit 2 of the Kola NPP. The major technical objective of this project was to provide, install and make operational the necessary hardware inside the confinement of the Kola NPP Unit 2 to provide early and reliable warning of the release of radionuclides from the reactor into the confinement air space as an indication of the occurrence of a severe accident at the plant. In addition, it was intended to provide hands-on experience and training to the Russian plant workers in the installation, operation, calibration and maintenance of the equipment in order that they may use the equipment without continued US assistance as an effective measure to improve reactor safety at the plant

  7. Some bioactive potentials of two biflavanols isolated from Garcinia kola on cadmium-induced alterations of raw U937 cells and U937-derived macrophages

    Institute of Scientific and Technical Information of China (English)

    Tebekeme Okoko; Diepreye Ere

    2013-01-01

    Objective: To investigate the abilities of two flavonoids - Garcinia biflavanol-1 (GB-1) and Garcinia biflavanol-2 (GB-2) from Garcinia kola (G. kola) in reducing cadmium-induced effects on raw U937 cells and U937-derived macrophages. Methods: Macrophage U937 cells were incubated with cadmium followed by treatment with the flavonoids and cell viability assessed via trypan blue staining. In the other experiment, the U937 cells were transformed to the macrophage form and treated with cadmium in order to activate them. The cells were later incubated with the flavonoids and finally the supernatant of each cell culture was analysed for the secretion of nitric oxide, catalyse activity, and the release of tumour necrosis factor-alpha, interleukin-1 and interleukin-2 as indices of macrophage activation. Quercetin (a flavonol) was used as the reference flavonoid in all experiments. Results: It revealed that the flavonoids significantly increased the viability of the cells and also reduced the cadmium-induced activation of the macrophage cells in a concentration-dependent manner. The flavanols GB-1 and GB-2 possessed higher activities than quercetin in all cases (P<0.05). Garcinia biflavanol-2 possessed a higher bioactivity than GB-1 significantly (P<0.05). Conclusions: In addition to corroborating the several reported importance of G. kola as a potential neutraceutical and pharmacological condiment, the study also clearly indicates the role hydroxylation especially at the 3´- position of polyphenols could play in enhancing bioactivities of flavonoids.

  8. INSTALLATION OF A POST-ACCIDENT CONFINEMENT HIGH-LEVEL RADIATION MONITORING SYSTEM IN THE KOLA NUCLEAR POWER STATION (UNIT 2) IN RUSSIA

    Energy Technology Data Exchange (ETDEWEB)

    GREENE,G.A.; GUPPY,J.G.

    1998-09-01

    This is the final report on the INSP project entitled, ``Post-Accident Confinement High-Level Radiation Monitoring System'' conducted by BNL under the authorization of Project Work Plan WBS 1.2.2.6 (Attachment 1). This project was initiated in February 1993 to assist the Russians in reducing risks associated with the continued operation of older Soviet-designed nuclear power plants, specifically the Kola VVER-440/230 Unit 2, through improved accident detection capability, specifically by the installation of a dual train high-level radiation detection system in the confinement of Unit 2 of the Kola NPP. The major technical objective of this project was to provide, install and make operational the necessary hardware inside the confinement of the Kola NPP Unit 2 to provide early and reliable warning of the release of radionuclides from the reactor into the confinement air space as an indication of the occurrence of a severe accident at the plant. In addition, it was intended to provide hands-on experience and training to the Russian plant workers in the installation, operation, calibration and maintenance of the equipment in order that they may use the equipment without continued US assistance as an effective measure to improve reactor safety at the plant.

  9. The Holocene vegetation history of the Khibiny Mountains: implications for the post-glacial expansion of spruce and alder on the Kola Peninsula, northwestern Russia

    Science.gov (United States)

    Kremenetski, Constantin; Vaschalova, Tatiana; Sulerzhitsky, Leopold

    1999-02-01

    Pollen and peat botanical investigations of the Lutnermayok peat bog, Kola Peninsula, northwestern Russia, were carried out, and 21 surface pollen samples were studied. Combined with previous studies our data form the basis for the vegetation history over the last 7000 yr of the Khibiny Mountains. Pinus sylvestris was the dominant species between 7000 and 5000 yr BP and Picea obovata penetrated to the Khibiny Mountains ca. 5500/5300 yr BP. Since 4500 yr BP, Picea replaced Pinus in major parts of the area and dominated the forest cover. Picea immigrated to the Kola Peninsula after 7000 yr BP. There were two paths of spruce migration: from the southeast and the southwest. Grey alder, Alnusincana, immigrated to the Kola Peninsula from the southwest and northwest about ca. 8000 yr BP. Grey alder has been restricted to its modern range since 4000 yr BP. The range of vertical movement of the treeline in Khibiny Mountains during the last 700 yr was 240-260 m, which corresponds to an amplitude of summer temperature change of 2°C.

  10. Development of modal layering in granites: a case study from the Carna Pluton, Connemara, Ireland

    Science.gov (United States)

    McKenzie, Kirsty; McCarthy, William; Hunt, Emma

    2016-04-01

    Modal layering in igneous rocks uniquely record dynamic processes operating in magma chambers and also host a large proportion of Earth's strategic mineral deposits. This research investigates the origin of biotite modal layering and primary pseudo-sedimentary structures in felsic magmas, by using a combination of Crystal Size Distribution (CSD) analysis and Electron Probe Microanalysis (EPMA) to determine the mechanisms responsible for the development of these structures in the Carna Pluton, Connemara, Ireland. The Carna Pluton is a composite granodiorite intrusion and is one of five plutons comprising the Galway Granite Complex (425 - 380 Ma). Prominent 30 cm thick modal layers are defined by sharp basal contacts to a biotite-rich (20%) granite, which grades upward over 10 cm into biotite-poor, alkali-feldspar megacrystic granite. The layering strikes parallel to, and dips 30-60° N toward the external pluton contact. Pseudo-sedimentary structures (cross-bedding, flame structures, slumping and crystal graded bedding) are observed within these layers. Petrographic observations indicate the layers contain euhedral biotite and fresh undeformed quartz and feldspar. Throughout the pluton, alkali-feldspar phenocrysts define a foliation that is sub-parallel to the strike of biotite modal layers. Together these observations indicate that the intrusion's concentric foliation, biotite layers and associated structures formed in the magmatic state and due to a complex interaction between magma flow and crystallisation processes. Biotite CSDs (>250 crystals per sample) were determined for nine samples across three biotite-rich layers in a single unit. Preliminary CSD results suggest biotite within basal contacts accumulated via fractional crystallisation within an upward-growing crystal pile, likely reflecting the yield strength of the magma as a limiting factor to gravitational settling of biotite. This is supported by the abrupt decrease in mean biotite crystal size across

  11. Reconstructing the Late Paleozoic : Early Mesozoic plutonic and sedimentary record of south-east Peru : Orphaned back-arcs along the western margin of Gondwana

    OpenAIRE

    Reitsma, Martje Jel

    2012-01-01

    This thesis investigates the sedimentary, plutonic and tectonic evolution of the Eastern Cordillera region of south-east Peru during assembly of the Pangea supercontinent and subsequent early pulses of break-up. We present a chronostratigraphic framework for the Carboniferous to Triassic sedimentary and plutonic record using geochronological, geochemical and isotopic methods, integrated with field observations. The first chapter investigates the plutonic record and its relation to growth of t...

  12. Multi-stage emplacement of the Götemar Pluton, SE Sweden: new evidence inferred from field observations and microfabric analysis, including cathodoluminescence microscopy

    OpenAIRE

    Friese, Nadine; Vollbrecht, Axel; Tanner, David; Fahlbusch, Wiebke; Weidemann, Miriam

    2011-01-01

    The emplacement of the Mesoproterozoic Götemar Pluton into Paleoproterozoic granitoid host rocks of the Transscandinavian Igneous Belt is re-examined by microfabric analysis, including cathodoluminescence microscopy. Field data on the pluton-host rock system are used to strengthen the model. The Götemar Pluton, situated on the Baltic Shield of SE Sweden, is a horizontally zoned tabular structure that was constructed by the intrusion of successive pulses of magma with different crystal/melt ra...

  13. Consistent magmatic and magnetic anisotropy data in La Gloria Pluton, central Chile: Implications for the magma flow record in a shallow pluton

    Science.gov (United States)

    Payacan, I.; Gutierrez, F. J.; Bachmann, O.; Parada, M.

    2012-12-01

    The magmatic origin of the anisotropy of magnetic susceptibility (AMS) is examined in comparison with magmatic anisotropy data in a small, shallow, silicic magma reservoir in the upper crust. La Gloria Pluton (LGP) is a 10 Ma granodiorite/quartz monzonite of about 250 km3 located in the southern Andes, central Chile. LGP represents a particularly simple case of a silicic intrusion which was assembled in a few pulses and cooled over a short time interval. Hornblende, biotite and minor magnetite are ubiquitous mafic phases. The AMS tensor indicates that magnetic fabric has an oblate shape (i.e. magnetic foliation is higher than magnetic lineation). Lineations are weak (values up to 1.05), have a N-NW trend with a nearly horizontal dip and represent axisymmetric convection parallel to the main pluton elongation. Foliations are more pronounced (values up to 1.14), having NW trends and dips that vary gradually from vertical at the walls, to horizontal at the center and near the roof of the chamber. We interpret this to represent shear localization near the magma locking point along solidification fronts. Magmatic anisotropy data were obtained by measuring mineral length, width and orientation in the three main planes of the AMS tensor. We define the planes Pmax, Pint, and Pmin as orthogonal to the maximum, intermediate, and minimum axes of the AMS tensor, respectively. Mineral data were collected for plagioclase and amphibole + bitotite independently. For each site, the Bingham distribution with 95% of confidence is used to determine the mean mineral orientation and their angle difference with the AMS axes. Preliminary results indicate that mean crystal orientations are well defined for Pmax and Pint for all analyzed minerals, but Pmin is only well constrained for amphibole + bitotite and poorly constrained for plagioclase. Angle differences generally decrease with magnetic anisotropy but are independent of the size and aspect ratio of the crystals. Mean values of

  14. Fabric and microstructural analysis of the Loch Borralan pluton, Northwest Highlands, Scotland

    Science.gov (United States)

    Calhoun, Justin

    The Loch Borralan pluton was emplaced within the Assynt Region of the Moine Thrust zone during the Scandian event (ca. 435-425 Ma) of the Caledonian Orogeny (478-425 Ma). It consists of two major magma suites, the syenitic early suite (431.1 +/- 1.2 Ma), and the quartz syenitic later suite (429.2 +/- 0.5 Ma). The region is characterized by a series of in-sequence thrust faults that strike NE-SW and dip approximately 20° to the SE, including (from lower to upper): the Sole Thrust, the Borralan Thrust (hypothesized, but not exposed), the Ben More Thrust, and the Moine Thrust. A series of imbricate thrusts between the Sole and Borralan Thrusts juxtapose repeated Cambrian and Ordovician strata. The Loch Borralan pluton intruded between the Sole and Ben More thrust faults, and may be bounded below by a hypothesized Borralan Thrust fault. Based on the overlap in pluton crystallization age and orogenic activity, the combination of macroscopic field lineation and foliation measurements, anisotropy of magnetic susceptibility (AMS) lineation and foliations measurements, mineral shape preferred orientation (SPO) analysis, and petrographic deformation microstructure analysis will be used to determine if the pluton expresses deformation features and fabrics corresponding to thrust fault tectonics. The dominant magnetic mineralogy as determined by thermomagnetic data and hysteresis plots was determined to be magnetite and titanomagnetite. Some paramagnetic components were seen in the early suite, and can be attributed to biotite. Both minerals contributed to the AMS signal that was used to interpret pluton fabrics. The pluton contains S>L (foliation stronger than lineation) fabrics throughout, defined by alignment of alkali feldspar grains. The foliation strike of both the early and late suites are subparallel to the thrust faults, providing evidence that the fabrics are related to deformation. The early suite is only well exposed in the southeast at the top of the Borralan

  15. Review of the Norwegian-Russian Cooperation on Safety Projects at Kola and Leningrad Nuclear Power Plants 2005 - 2009

    Energy Technology Data Exchange (ETDEWEB)

    Mattsson, H.; Tishakov, P.

    2010-11-15

    In this report, Norwegian Radiation Protection Authority (NRPA) has reviewed the Norwegian funded projects on nuclear safety performed in the period 2005-2009 under the Norwegian Action Plan. NRPA has evaluated the progress of eight projects implemented by the Institute for Energy Technology (IFE) at Kola Nuclear Power Plant (KNPP) and Leningrad Nuclear Power Plant (LNPP). NRPA has visited the plants, inspected delivered equipment and discussed the projects implementation with relevant personnel at the plants. One of NRPA findings is that the equipment has been delivered to KNPP and LNPP, it is in regular use by competent personnel, and the equipment contributes to safety of both plants. Furthermore, the cooperation between three main project partners - IFE, LNPP and KNPP, seems to be very productive. NRPA's main conclusion is therefore that the projects have been implemented as described in IFE's project reports and that the goals are met. Furthermore, this report reviews safety levels at the KNPP and LNPP. Safety parameters at the plants indicate that the safety level has been significantly improved since early 1990s when the cooperation between Norway and Russia was initiated. Probabilistic safety assessment (PSA) values and number of INES (International Nuclear Event Scale) events, two internationally acknowledged safety parameters, indicate that the safety level has been much improved since the early 1990s when the cooperation between Norway and Russia started. Although it is clear that the Norwegian-funded projects have contributed positively to this development it is difficult to quantify the contribution. Moreover, the report also reviews the planned life-time of and the decommissioning plans for the reactors at KNPP and LNPP. Construction of new LNPP reactors has started and it is estimated that they will be operational in 2013- 2015. The license of the oldest reactor at LNPP expires in 2018 and if the new reactors are in operation by that time

  16. Long-term aerosol and trace gas measurements in Eastern Lapland, Finland: the impact of Kola air pollution to new particle formation and potential CCN

    Science.gov (United States)

    Kyrö, Ella-Maria; Väänänen, Riikka; Kerminen, Veli-Matti; Virkkula, Aki; Asmi, Ari; Nieminen, Tuomo; Dal Maso, Miikka; Petäjä, Tuukka; Keronen, Petri; Aalto, Pasi; Riipinen, Ilona; Lehtipalo, Katrianne; Hari, Pertti; Kulmala, Markku

    2014-05-01

    Sulphur and primary emissions have been decreasing largely all over Europe, resulting in improved air quality and decreased direct radiation forcing by aerosols. The smelter industry in Kola Peninsula is one of largest sources of anthropogenic SO2 within the Arctic domain and since late 1990s the sulphur emissions have been decreasing rapidly (Paatero et al., 2008; Prank et al., 2010). New particle formation (NPF) is tightly linked with the oxidizing product of SO2, namely sulphuric acid (H2SO4), since it is known to be the key component in atmospheric nucleation (Sipilä et al., 2010). Thus, decreasing sulphur pollution may lead to less NPF. However, low values of condensation sink (CS), which is determined by the amount of pre-existing particles, favours NPF. We used 14 years (1998-2011) of aerosol number size distribution and trace gas data from SMEAR I station in Eastern Lapland, Finland, to investigate these relationships between SO2, NPF and CS. The station is a clean background station with occasional sulphur pollution episodes when the air masses arrive over Kola Peninsula. We found that while SO2 decreased by 11.3 % / year, the number of clear NPF event days was also decreasing by 9.9 % / year. At the same time, CS was decreasing also (-8.0 % / year) leading to formation of more particles per single NPF event (J3 increased by 29.7 % / year in 2006-2011) but the low vapour concentrations of H2SO4 (proxy decreased by 6.2 % / year) did not allow them to grow into climatically relevant sizes. Over the time, concentrations of potential CCN (cloud condensing nuclei) were also decreasing with more moderate pace, -4.0 % / year. The events started on average earlier after sunrise when the SO2 concentration during the start of the event was higher and NPF occurred more frequently in air masses which were travelling over Kola. Despite the total decrease in sulphur pollution originating from Kola there is currently no evidence of cleaning of the emissions, rather the

  17. Alkaline fuel cell performance investigation

    Science.gov (United States)

    Martin, R. E.; Manzo, M. A.

    1988-01-01

    An exploratory experimental fuel cell test program was conducted to investigate the performance characteristics of alkaline laboratory research electrodes. The objective of this work was to establish the effect of temperature, pressure, and concentration upon performance and evaluate candidate cathode configurations having the potential for improved performance. The performance characterization tests provided data to empirically establish the effect of temperature, pressure, and concentration upon performance for cell temperatures up to 300 F and reactant pressures up to 200 psia. Evaluation of five gold alloy cathode catalysts revealed that three doped gold alloys had more that two times the surface areas of reference cathodes and therefore offered the best potential for improved performance.

  18. Petrogenesis and tectonic implications of the high-K Alamas calc-alkaline granitoids at the northwestern margin of the Tibetan Plateau: Geochemical and Sr-Nd-Hf-O isotope constraints

    Science.gov (United States)

    Zhang, Qichao; Liu, Yan; Huang, He; Wu, Zhenhan; Zhou, Qing

    2016-09-01

    The Alamas granitoid pluton in the eastern part of the Western Kunlun Orogen, the northwestern margin of the Tibetan Plateau, is composed of quartz diorite. Zircon separates from the pluton has SIMS U-Pb age of ∼446 Ma. Rocks from the pluton have a narrow range of SiO2 (56.84-62.57 wt%), MgO (1.76-2.94 wt%), and total alkalis (Na2O + K2O = 5.14-9.59 wt%), and are metaluminous and high-K calc-alkaline to shoshonitic in composition. They are enriched in light rare earth elements (LREEs), with (La/Yb)N = 14-25, and show weakly negative Eu anomalies. These rocks are relatively enriched in Sr (472-676 ppm) and Ba (435-2388 ppm), and depleted in Nb, Ta, Th, and Ti. Their εNd(t) values range from -6.4 to -8.4, and (87Sr/86Sr)i = 0.7184-0.7200. Zircons from the pluton show εHf(t) values of -1.4 to -8.8, and δ18O = 6.4-9.0‰. Geochemical data indicate that the granitoids were likely derived from the reworking of an ancient, deep crustal source, influenced by a minor mantle-derived component. Magmatic differentiation was dominated by the fractional crystallization of hornblende, biotite, and accessory minerals such as apatite, allanite, and Fe-Ti oxides. In summary, the Late Ordovician Alamas pluton is an I-type granitoid that was emplaced in a post-collisional environment, suggesting that this tectonic stage had already initiated prior to ∼445 Ma.

  19. An integrated geological, geochemical, and geophysical investigation of uranium metallogenesis in selected granitic plutons of the Miramichi Anticlinorium, New Brunswick

    International Nuclear Information System (INIS)

    Integrated geological, geochemical, and geophysical data for the post-tectonic granitic rocks of the North Pole, Burnthill, Dungarvon, Trout Brook, and Rocky Brook plutons and surrounding areas were examined to assess their potential for uranium mineralization. Geological, geochemical, and geophysical criteria that are thought to be useful guides for uranium exploration were also established for the host granites. The granitic plutons were emplaced discordantly, late in the tectonomagmatic sequence and at shallow depths within the metasedimentary rocks of the Miramichi Anticlinorium. Geochemically, the host granites are highly evolved (Si02 > 75 wt. %), peraluminous and have strong similarities with ilmenite-series 'S-type' and 'A-type' granitoids. Uranium occurrences are spatially and perhaps temporally associated with late-phase differentiates of the plutons where elevated levels of other lithophile elements such as Sn, W, Mo, and F were also detected. Geophysically, the granitic plutons are associated with distinctively high aeroradiometric eU, eTh, and K anomalies that coincide with strong negative Bouguer anomalies and low magnetic values. Conceptual models involving magmatic and hydrothermal processes have been adopted to explain the concentration of uranium and associated metals in the granitic plutons

  20. Asymmetric textural and structural patterns of a granitic body emplaced at shallow levels: The La Chinchilla pluton, northwestern Argentina

    Science.gov (United States)

    Macchioli Grande, M.; Alasino, P. H.; Rocher, S.; Larrovere, M. A.; Dahlquist, J. A.

    2015-12-01

    New mapping and a detailed structural study of the La Chinchilla stock, Sierra de Velasco, NW Argentina, suggest an asymmetrical shape of the pluton and provide strong evidence for its shallow emplacement depth. The pluton is a Lower Carboniferous monzogranite composed of K-feldspar, quartz, plagioclase and biotite. It exhibits an internal asymmetric textural zoning, defined by porphyritic granite in the southeastern region to equigranular granite in the northwestern region. The presence of subhorizontal dikes in the northwestern area, where the contacts dip shallowly, and subvertical dikes intruding the host rock nearby steep-dipping intrusive contacts in the southeastern region are compatible with an overall asymmetrical shape and internal structure of this pluton. Considering published crystallization ages, a dominant strain field occurring at around 12 Ma is inferred based on magmatic fabrics in the pluton and its host rock (the Huaco pluton), with a principal shortening direction oriented SW-NE, consistent with the general NW-SE strike of the body. Field evidence supports brittle fracturing and block displacement as the dominant emplacement mechanism, suggesting that magmatic stoping dominated during the late stage of the evolution of the magma chamber.

  1. Mineralogy, geochemistry, and evolution of the Mivehrood skarn and the associated pluton, northwest Iran

    Science.gov (United States)

    Alirezaei, Saeed; Einali, Morteza; Jones, Peter; Hassanpour, Shohreh; Arjmandzadeh, Reza

    2016-04-01

    An Upper Miocene (9.12 ± 0.19 Ma; biotite 40Ar/39Ar) shallow pluton and numerous dykes and sills of felsic-intermediate compositions intruded the Upper Cretaceous, flysch-type sediments in the Mivehrood area, northwest Iran. The intrusions caused extensive thermal metamorphism and metasomatism, leading to the formation of hornfels and skarn. A massive skarn, 1-10 m thick, immediate to the intrusive contact, is bordered by a banded skarn, 100-400 m thick, that grades outward into hornfels and original sediments. The Mivehrood pluton is characterized by steep REE pattern, high Al2O3 (14.64-16.4 wt%) and Sr (380-786 ppm), and low MgO (1.3-3.4 wt%), Y (4.8-10.7 ppm), and Yb (0.35-0.95 ppm), characteristics typical of high-silica adakites. Skarn formation started with thermal metamorphism, followed by anhydrous prograde and hydrous retrograde stages. Prograde and retrograde mineral assemblages are developed in both skarns, represented by garnet-clinopyroxene-wollastonite and epidote-actinolite-scapolite-chlorite, respectively. Granditic F-bearing garnet dominates clinopyroxene in both skarns. The banded skarn contains minor scapolite of marialite composition. The calc-silicate mineral assemblages and the mineral chemistry allow the Mivehrood skarn to be classified as a calcic, oxidized skarn. Mass balance assessments suggest that Fe, Si, and S were significantly enriched, and Na, LILEs, and LREEs were strongly depleted, in the massive skarn. In the banded skarn, Na, K, Si, and S were enriched. Significant dehydration and carbon degassing occurred in both skarns. Stockworks, veins, and replacement bodies of pyrite ± chalcopyrite locally occur in the pluton and the dykes and in the skarns. The δ34SCDT values for the sulfides fall in a narrow range around 0.0 ‰, suggesting a magmatic source for sulfur and possibly the hydrothermal water and solutes involved in the skarn formation.

  2. Ductile strain rate recorded in the Symvolon syn-extensional plutonic body (Rhodope core complex, Greece)

    Science.gov (United States)

    Cirrincione, Rosolino; Fazio, Eugenio; Ortolano, Gaetano; Fiannacca, Patrizia; Kern, Hartmut; Mengel, Kurt; Pezzino, Antonino; Punturo, Rosalda

    2016-04-01

    The present contribution deals with quantitative microstructural analysis, which was performed on granodiorites of the syn-tectonic Symvolon pluton (Punturo et al., 2014) at the south-western boundary of the Rhodope Core Complex (Greece). Our purpose is the quantification of ductile strain rate achieved across the pluton, by considering its cooling gradient from the centre to the periphery, using the combination of a paleopiezometer (Shimizu, 2008) and a quartz flow law (Hirth et al., 2001). Obtained results, associated with a detailed cooling history (Dinter et al., 1995), allowed us to reconstruct the joined cooling and strain gradient evolution of the pluton from its emplacement during early Miocene (ca. 700°C at 22 Ma) to its following cooling stage (ca. 500-300°C at 15 Ma). Shearing temperature values were constrained by means of a thermodynamic approach based on the recognition of syn-shear assemblages at incremental strain; to this aim, statistical handling of mineral chemistry X-Ray maps was carried out on microdomains detected at the tails of porphyroclasts. Results indicate that the strain/cooling gradients evolve "arm in arm" across the pluton, as also testified by the progressive development of mylonitic fabric over the magmatic microstructures approaching the host rock. References • Dinter, D. A., Macfarlane, A., Hames, W., Isachsen, C., Bowring, S., and Royden, L. (1995). U-Pb and 40Ar/39Ar geochronology of the Symvolon granodiorite: Implications for the thermal and structural evolution of the Rhodope metamorphic core complex, northeastern Greece. Tectonics, 14 (4), 886-908. • Shimizu, I. (2008). Theories and applicability of grain size piezometers: The role of dynamic recrystallization mechanisms. Journal of Structural Geology, 30 (7), 899-917. • Hirth, G., Teyssier, C., and Dunlap, J. W. (2001). An evaluation of quartzite flow laws based on comparisons between experimentally and naturally deformed rocks. International Journal of Earth

  3. Occurrence of parsonite, a secondary uranium mineral, in alaskite of the Wheeler Creek pluton, Alaska

    International Nuclear Information System (INIS)

    Reconnaissance investigations in the Purcell Mountains of westcentral Alaska in 1977 revealed the presence of parsonite, a hydrous phosphate of lead and uranium with the formula Pb2UO2(PO4)22H2O. This is the first reported occurrence of parsonite in Alaska. The parsonite occurs as a soft, yellow to chocolate brown coating closely associated with green muscovite on fracture surfaces in a shear zone in alaskite of the Wheeler Creek pluton. Thin magnetite veinlets are also present. The identification of parsonite was confirmed by x-ray diffraction. Delayed neutron analysis were run on samples of the Alaskite

  4. Sm-Nd whole-rock isotope system of the Eye-Dashwa Lakes pluton

    International Nuclear Information System (INIS)

    An unaltered drill-core sample of the Eye-Dashwa Lakes pluton (sample ATK-1 (990.97-996.78)) is light rare earth enriched, with a 147Sm/144Nd ratio of 0.08699 and a 143Nd/144Nd ratio of 0.510815. The depleted mantle model age of 2.68 Ga agrees with emplacement ages, indicating that parental magma or its protolith was derived directly from a depleted mantle and that the crustal residence time was short

  5. Grace DAKASEP alkaline battery separator

    Science.gov (United States)

    Giovannoni, R. T.; Lundquist, J. T.; Choi, W. M.

    1987-01-01

    The Grace DAKASEP separator was originally developed as a wicking layer for nickel-zinc alkaline batteries. The DAKASEP is a filled non-woven separator which is flexible and heat sealable. Through modification of formulation and processing variables, products with a variety of properties can be produced. Variations of DAKASEP were tested in Ni-H2, Ni-Zn, Ni-Cd, and primary alkaline batteries with good results. The properties of DAKASEP which are optimized for Hg-Zn primary batteries are shown in tabular form. This separator has high tensile strength, 12 micron average pore size, relatively low porosity at 46-48 percent, and consequently moderately high resistivity. Versions were produced with greater than 70 percent porosity and resistivities in 33 wt percent KOH as low as 3 ohm cm. Performance data for Hg-Zn E-1 size cells containing DAKASEP with the properties shown in tabular form, are more reproducible than data obtained with a competitive polypropylene non-woven separator. In addition, utilization of active material is in general considerably improved.

  6. Swedish-Russian cooperation to prevent and detect trafficking on the Kola Peninsula: A work in progress

    International Nuclear Information System (INIS)

    Since 1996, Sweden has been working on the improvement of nuclear security in the Russian Federation. The first areas of interest for the Swedish Nuclear Power Inspectorate (SKI) were physical protection works. Thus, SKI had established a number of contacts and partnerships in Murmansk and in the Murmansk Region (which in geographical terms is roughly the same as the Kola Peninsula) when, in September 2004, a request came for Swedish cooperation assistance. Russian authorities realized that there were problems involving illicit trafficking of nuclear and radioactive materials. Lengthy negotiations between SKI and Rosatom ensued, involving agreed contracts and status reports which identified several concerns (such as legal inadequacies, and coordination and access difficulties). SKI wishes to remain an active cooperation partner for the Russian Federation in this field. The intention is to find an area where cooperation is the next practical step - possibilities for which include the development of legislation, or structures for cooperation between authorities, or the provision of detection equipment and communication systems. (author)

  7. Mateřská škola v Českých Budějovicích

    OpenAIRE

    Šturma, Pavel

    2015-01-01

    Diplomová práce je zpracována ve formě projektové dokumentace k provedení novostavby mateřské školy v Českých Budějovicích. Projektová dokumentace je navržena dle platných norem. Objekt je navržen v katastrálním území České Budějovice. Mateřská škola má dvě nadzemní podlaží. Budova je navržena ze systému Porotherm s kontaktním zateplovacím systémem, zastřešena jednoplášťovou vegetační plochou střechou a založena na základových pasech z prostého betonu. Stropní konstrukce je tvořena z předem p...

  8. Holocene climate variability on the Kola Peninsula, Russian Subarctic, based on aquatic invertebrate records from lake sediments

    Science.gov (United States)

    Ilyashuk, Elena A.; Ilyashuk, Boris P.; Kolka, Vasily V.; Hammarlund, Dan

    2013-05-01

    Sedimentary records of invertebrate assemblages were obtained from a small lake in the Khibiny Mountains, Kola Peninsula. Together with a quantitative chironomid-based reconstruction of mean July air temperature, these data provide evidence of Holocene climate variability in the western sector of the Russian Subarctic. The results suggest that the amplitude of climate change was more pronounced in the interior mountain area than near the White Sea coast. A chironomid-based temperature reconstruction reflects a warming trend in the early Holocene, interrupted by a transient cooling at ca. 8500-8000 cal yr BP with a maximum drop in temperature (ca. 1°C) around 8200 cal yr BP. The regional Holocene Thermal Maximum, characterized by maximum warmth and dryness occurred at ca. 7900-5400 cal yr BP. During this period, July temperatures were at least 1°C higher than at present. The relatively warm and dry climate persisted until ca. 4000 cal yr BP, when a pronounced neoglacial cooling was initiated. Minimum temperatures, ca. 1-2°C lower than at present, were inferred at ca. 3200-3000 cal yr BP. Faunal shifts in the stratigraphic profile imply also that the late-Holocene cooling was followed by a general increase in effective moisture.

  9. Emissions from the copper-nickel industry on the Kola Peninsula and at Noril'sk, Russia

    Science.gov (United States)

    Boyd, Ron; Barnes, S.-J.; De Caritat, P.; Chekushin, V.A.; Melezhik, V.A.; Reimann, C.; Zientek, M.L.

    2009-01-01

    Published estimates for base metal emissions from the copper-nickel industry on the Kola Peninsula are re-examined in the light of (a) chemical data on the composition of the ores; (b) official emission figures for 1994; and (c) modelled emissions based on dry and wet deposition estimates derived from data for snow and rain samples collected in 1994. The modelled emissions, official emission figures and chemical data are mutually compatible for Ni, Cu and Co and show that previously published figures underestimated the emissions of the major elements, Ni and Cu (though within the same order of magnitude) and overestimated the emissions of As, Pb, Sb and Zn by up to several orders of magnitude, in some cases exceeding the calculated total input to the plants. Published estimates have neglected information on the nature and chemistry of the ores processed in metallurgical industries in the Noril'sk area of Siberia and the Urals. Revised emission estimates for 1994, using knowledge of the chemistry of the ores, are proposed: taken with published information on total emissions up to 2000 these data give an indication of emission levels in more recent years. ?? 2008 Elsevier Ltd. All rights reserved.

  10. Autumn migration and wintering areas of Peregrine Falcons Falco peregrinus nesting on the Kola Peninsula, northern Russia

    Science.gov (United States)

    Ganusevich, S.A.; Maechtle, T.L.; Seegar, W.S.; Yates, M.A.; McGrady, M.J.; Fuller, M.; Schueck, L.; Dayton, J.; Henny, C.J.

    2004-01-01

    Four female Peregrine Falcons Falco peregrinus breeding on the Kola Peninsula, Russia, were fitted with satellite-received transmitters in 1994. Their breeding home ranges averaged 1175 (sd = ??714) km2, and overlapped considerably. All left their breeding grounds in September and migrated generally south-west along the Baltic Sea. The mean travel rate for three falcons was 190 km/day. Two Falcons wintered on the coasts of France and in southern Spain, which were, respectively, 2909 and 4262 km from their breeding sites. Data on migration routes suggested that Falcons took a near-direct route to the wintering areas. No prolonged stopovers were apparent. The 90% minimum convex polygon winter range of a bird that migrated to Spain encompassed 213 km2 (n = 54). The area of the 50% minimum convex polygon was 21.5 km2 (n = 29). Data from this study agree with others from North America that show that Falcons breeding in a single area do not necessarily follow the same migratory path southward and do not necessarily use the same wintering grounds.

  11. Alkaline and alkaline earth metal phosphate halides and phosphors

    Science.gov (United States)

    Lyons, Robert Joseph; Setlur, Anant Achyut; Cleaver, Robert John

    2012-11-13

    Compounds, phosphor materials and apparatus related to nacaphite family of materials are presented. Potassium and rubidium based nacaphite family compounds and phosphors designed by doping divalent rare earth elements in the sites of alkaline earth metals in the nacaphite material families are descried. An apparatus comprising the phosphors based on the nacaphite family materials are presented herein. The compounds presented is of formula A.sub.2B.sub.1-yR.sub.yPO.sub.4X where the elements A, B, R, X and suffix y are defined such that A is potassium, rubidium, or a combination of potassium and rubidium and B is calcium, strontium, barium, or a combination of any of calcium, strontium and barium. X is fluorine, chlorine, or a combination of fluorine and chlorine, R is europium, samarium, ytterbium, or a combination of any of europium, samarium, and ytterbium, and y ranges from 0 to about 0.1.

  12. Progress of research on the influence of alkaline cation and alkaline solution on bentonite properties

    International Nuclear Information System (INIS)

    Based on the previous laboratory studies and numerical simulation on bentonite in alkaline environments, the effects of alkaline cation and alkaline solution on mineral composition, microstructure, swelling capacity and hydraulic properties of bentonite are emphasized in this paper, temperature, pH values and concentration are discussed as main affecting factors. When bentonite is exposed to alkaline cation or alkaline solution, microstructure of bentonite will be changed due to the dissolution of montmorillonite and the formation of secondary minerals, which results in the decrease of swelling pressure. The amount of the reduction of swelling pressure depends on the concentration of alkaline solution. Temperature, polyvalent cation, salinity and concentration are the main factors affecting hydraulic properties of bentonite under alkaline conditions. Therefore, future research should focus on the mechanism of coupling effects of weak alkaline solutions on the mineral composition, microstructure, swelling capacity and hydraulic properties of bentonite under different temperatures and different pH values. (authors)

  13. Pluton accommodation at high strain rates in the upper continental crust. The example of the Central Extremadura batholith, Spain

    Science.gov (United States)

    Fernández, Carlos; Castro, Antonio

    1999-08-01

    Emplacement in the tensional bridge of a stepped dextral shear zone system is proposed for the Central Extremadura batholith (Spain). The country rocks show a pervasive anisotropy that conditioned the style of the structures developed as a consequence of the transference of displacement from the stepped shear zones to the releasing area. The kinematic evolution of the resulting megakink fold provided the volume increase necessary for the granite emplacement. Thermal and kinematic models suggest that the growth of individual plutons took place in periods of no more than several hundred to a few thousand years. Fast strain rates (10 -10-10 -11 s -1) must concentrate in local structures (e.g. initiation of kink folds) even in zones deforming as a whole under typical strain rates (10 -14±1 s -1). Granite plutons might be used as strain-rate gauges for syn-plutonic structures.

  14. Investigation of the mineral potential of the Clipper Gap, Lone Mountain-Weepah, and Pipe Spring plutons, Nevada

    International Nuclear Information System (INIS)

    The Clipper Gap pluton, composed mostly of quartz monzonite with minor granite, granodiorite, and crosscutting alaskite dikes, intrudes Paleozoic western facies strata. A narrow zone of contact metamorphism is present at the intrusive-sediment contact. No mineral production has been recorded from Clipper Gap, but quartz veins containing gold-silver-copper mineral occurrences have been prospected there from the late 1800's to the present. Areas of the Lone Mountain-Weepah plutons that were studied are located in Esmeralda County about 14 km west of Tonopah, Nevada. At Lone Mountain, a Cretaceous intrusive cuts folded Precambrian and Cambrian sediments. Lead-zinc ores have been mined from small replacement ore bodies in the Alpine district, west of Lone Mountain. Copper and molybdenum occurrences have been found along the east flank of Lone Mountain, and altered areas were noted in intrusive outcrops around the south end of Lone Mountain. Mineral occurrences are widespread and varied with mining activity dating back to the 1860's. The Pipe Spring pluton study area is flanked by two important mining districts, Manhattan to the north and Belmont to the northeast. Mining activity at Belmont dates from 1865. Activity at Manhattan was mainly between 1907 and 1947, but the district is active at the present time (1979). Four smaller mining areas, Monarch, Spanish Springs, Baxter Spring, and Willow Springs, are within the general boundary of the area. The Pipe Spring pluton study area contains numerous prospects along the northern contact zone of the pluton. Tungsten-bearing veins occur within the pluton near Spanish Springs, with potential for gold-tungsten placer in the Ralston Valley. Nickel and associated metals occur at Willow Spring and Monarch Ranch, where prospects may be associated with the margin of the Big Ten Peak Caldera

  15. Open-System Alkaline Magmatism in the Caledonides of North-Central Norway

    Science.gov (United States)

    Barnes, C. G.; Prestvik, T.; Barnes, M. A.

    2002-12-01

    The Caledonian-age Hortavaer intrusion is exposed on small islands and skerries off the coast of north-central Norway. It was emplaced into a range of host rocks that includes calcitic and dolomitic marble to migmatitic gneiss to quartz-rich meta-arenite. The intrusion is unusual relative to Caledonian plutons on the mainland because of its alkaline nature and its possible circa 460-470 Ma age (based on imprecise Sr and Nd isochrones). The intrusion is broadly zoned, with central diorite and outer syenite. Dike-like bodies of monzonite and syenite are also present and are elongate in a NNE-SSW direction. Each lithologic unit is characterized by evidence for magma mingling, particularly by synplutonic dikes and enclaves. In the syenitic zone, mingled magmas ranged from monzonitic (syenitic) to dioritic. In the diorite zone, mingling was dominated by diorite-in-diorite, but composite diorite-syenite dikes are present. The contact between the syenite and diorite units is marked by an approximately 500-m-wide zone of sheeted diorite/syenite dikes that are mutually intrusive. In addition to magma mingling, the complex shows a variety of types of interaction with screens of its host rocks, which are typically subparallel to foliation in the pluton. Some screens were apparently unreactive with the surrounding magma, whereas others resulted in intense reaction and formation of garnet melasyenite, pyroxene-rich monzodiorite, and rare nepheline-bearing rocks. A trend toward Fe enrichment among the dioritic rocks, the low Mg/(Mg+Fe) and Sr contents of the evolved syenites, and curvilinear composition trends for many elements in the suite suggest fractional crystallization was a major control on magma evolution. However, low epsilon Nd (465 Ma) (-3 to -10), moderate initial 87Sr/86Sr (0.705 to 0.710), and high delta18O (+8.3 to +14.0 %) suggest either a crustal source or intense contamination. The presence of primary calcite with delta13C typical of host carbonate rocks

  16. A reassessment of models for hydrocarbon generation in the Khibiny nepheline syenite complex, Kola Peninsula, Russia

    Science.gov (United States)

    Beeskow, B.; Treloar, P. J.; Rankin, A. H.; Vennemann, T. W.; Spangenberg, J.

    2006-10-01

    Although hydrocarbon-bearing fluids have been known from the alkaline igneous rocks of the Khibiny intrusion for many years, their origin remains enigmatic. A recently proposed model of post-magmatic hydrocarbon (HC) generation through Fischer-Tropsch (FT) type reactions suggests the hydration of Fe-bearing phases and release of H 2 which reacts with magmatically derived CO 2 to form CH 4 and higher HCs. However, new petrographic, microthermometric, laser Raman, bulk gas and isotope data are presented and discussed in the context of previously published work in order to reassess models of HC generation. The gas phase is dominated by CH 4 with only minor proportions of higher hydrocarbons. No remnants of the proposed primary CO 2-rich fluid are found in the complex. The majority of the fluid inclusions are of secondary nature and trapped in healed microfractures. This indicates a high fluid flux after magma crystallisation. Entrapment conditions for fluid inclusions are 450-550 °C at 2.8-4.5 kbar. These temperatures are too high for hydrocarbon gas generation through the FT reaction. Chemical analyses of rims of Fe-rich phases suggest that they are not the result of alteration but instead represent changes in magma composition during crystallisation. Furthermore, there is no clear relationship between the presence of Fe-rich minerals and the abundance of fluid inclusion planes (FIPs) as reported elsewhere. δ 13C values for methane range from - 22.4‰ to - 5.4‰, confirming a largely abiogenic origin for the gas. The presence of primary CH 4-dominated fluid inclusions and melt inclusions, which contain a methane-rich gas phase, indicates a magmatic origin of the HCs. An increase in methane content, together with a decrease in δ 13C isotope values towards the intrusion margin suggests that magmatically derived abiogenic hydrocarbons may have mixed with biogenic hydrocarbons derived from the surrounding country rocks.

  17. Regional geochemical study of the felsic plutonic rocks in the Nuqrah Quadrangle, sheet 25E, Kingdom of Saudi Arabia

    Science.gov (United States)

    Hall, W.E.; Dellinger, David; Selner, G.I.

    1985-01-01

    A regional geochemical investigation of the felsic plutonic rocks of the Nuqrah quadrangle, sheet 25 E, Kingdom of Saudi Arabia, in which pan concentrates of 384 wadi samples, and 145 rock samples, were collected, defined two separate and distinct anomalous areas. One area contains Jabal Tuwalah and Jabal Awja, and the other is at the north end of Jabal Safad. Both pan concentrates and the rock samples in the Jabal Tuwalah and Jabal Awja areas contain high concentrations of Be, F, La, Mo, Nb, Pb, Th, U, Sn, Y, and Zr, and the plutons underlying those areas are characterized by high total-count radioactivity.

  18. Santa Eulália Plutonic Complex (Southern Portugal): petrology, geochemistry and structural control of a late variscan structure

    OpenAIRE

    Lopes, Luis; Lopes, José Carrilho; Sant'Ovaia, Helena; Nogueira, Pedro; Ribeiro, Maria dos Anjos

    2013-01-01

    The Santa Eulália Plutonic Complex (SEPC) is a 400 km2 late variscan granitic pluton in the SW sector of the Iberian Variscides which cross-cuts the regional NW-SE Upper Proterozoic to Lower Palaeozoic lithological units. From the rim to the core, SEPC shows a medium- to coarse-grained pink granite (G0 group) involving large elongated masses of mafic to intermediate rocks (M group) and a central grey monzonitic granite (G1 group) mainly represented by medium-grained textures. Elemental geo...

  19. The gabbro (shoshonitic)-monzonite-granodiorite association of Khankandi pluton, Alborz Mountains, NW Iran

    Science.gov (United States)

    Aghazadeh, Mehraj; Castro, Antonio; Omran, Nematallah Rashidnejad; Emami, Mohamad Hashem; Moinvaziri, Hossien; Badrzadeh, Zahra

    2010-05-01

    The Khankandi pluton forms part of a group of gabbro-granodiorite intrusions in the Alborz Mountains of NW Iran. A petrographical and geochemical study of this plutonic association reveals the existence of several magmatic cycles with different origins and slight differences in age. The oldest cycle (C1) is represented by granodiorites. A second cycle (C2) is formed by a gabbro-monzonite association, with a clear shoshonitic affinity, that dominates most of the intrusive volume. Gabbros and monzonites form a co-magmatic association. Zircons from the monzonites were analyzed by LA-ICP-MS for U-Pb dating. An average age of 28.9 Ma, ranging from 23.7 to 33.6 Ma was obtained. Gabbros, monzonites and granodiorites share a nearly common isotopic ratio for Sr and Nd. Both initial Sr and Nd ratios are clustered within a narrow range from 0.7045 to 0.7047 for the 87Sr/ 86Sr ratio and ɛNd from 1.46 to 1.89. Comparison with experimental studies, together with mantle-like isotopic ratios and comparisons of REE patterns, points to an origin by variable melting rates from a common metasomatised mantle source for gabbros and monzonites. Melting of a subducted mélange is suggested for the granodiorite magmas predating the gabbro-monzonite intrusion. The two sources, a metasomatised mantle and ascending silicic plumes, are direct consequence of subduction.

  20. Reworked old crust-derived shoshonitic magma: The Guarany pluton, Northeastern Brazil

    Science.gov (United States)

    Ferreira, Valderez P.; Sial, Alcides N.; Pimentel, Marcio M.; Armstrong, Richard; Guimarães, Ignez P.; da Silva Filho, Adejardo F.; de Lima, Mariucha Maria C.; da Silva, Thyego R.

    2015-09-01

    The 572 Ma Guarany stock consists of magmatic epidote-bearing hornblende monzodiorite to biotite granite that intruded Paleoproterozoic orthogneisses about 10 km inland from the coast in northeastern Brazil. Co-magmatic diorite enclaves and dikes are abundant throughout the pluton. The monzodiorite-granite pluton and diorite enclaves are shoshonitic and display continuous trends in variation diagrams. They display chemical and isotopic characteristics of crustal melts, such as enrichment in incompatible elements, high back-calculated initial 87Sr/86Sr ratios (avg. 0.71253), negative εNd (0.57Ga) values (avg. - 14.58), as well as high and variable (+ 9.1 to + 11.1‰VSMOW) δ18O (zircon) values. Correlations between O-isotope and whole-rock silica contents, as well as initial 87Sr/86Sr ratios with 1/Sr concentrations, suggest hybridization of a lower continental crustal melt with more felsic crustal rocks, concomitant with fractional crystallization. Amphibole chemistry and whole rock Zr, TiO2 and P2O5 contents suggest magma solidification at a pressure ~ 7 kbar and near liquidus temperature ~ 900 °C. The parental magma was likely formed by partial melting of old (tDM = 2.0 Ga) amphibolitic lower continental crustal rocks, in a post-collisional setting, probably triggered by underplating of mantle-derived mafic magma during the period of relaxation after collision.

  1. Alkaline azide mutagenicity in cowpea

    International Nuclear Information System (INIS)

    Sodium azide is known as a potent mutagen in cereals and legumes. It is very effective in acidic medium in barley. Here an attempt is made to measure the effectiveness of sodium azide in alkaline medium (pH 7.4) on cowpea (Vigna unguiculata (L.) Walp., variety FS-68). Seeds pre-soaked in distilled water for 5 hours were treated with different concentrations (10-6, 10-5, 10-4 and 10-3M) of sodium azide (NaN3) for 4 hours at 28± 2 deg. C. Bottles were intermittently shaken, then the seeds were thoroughly washed in running tap water and subsequently planted in pots. The treatment caused significant biological damage such as reduction in seed germination, length of root and shoot, number of nodules and pods per plant and morphological leaf variations. Morphological, as well as chlorophyll mutants, were detected in M2

  2. Tracking the growth of plutons: the contribution of high-precision U-Pb zircon dating

    International Nuclear Information System (INIS)

    Full text: A growing body of high-precision U-Pb data from magmatic zircon indicates that plutons grow over timescales of 105-106 years. A complex interplay of processes - including accumulation of melt batches from lower and middle crustal levels, crystallization, remelting of solidified crystal mushes, mixing and mingling, transfer of pheno- and xenocrysts between melt portions, and many more - results in equally complicated pluton structures and rock textures. The use of (202Pb-) 205Pb-233U-235U tracer solutions in U-Pb dating of magmatic zircon can lead to a precision of 0.1 % in the 206Pb/238U age of an individual zircon analysis, and to as low as 0.02 % for a weighted mean of 6-10 coeval analyses. Such uncertainty is well within the time interval of zircon crystallization and residence in intermediate and acid magmatic liquids and allows resolution of incremental accumulation of melt batches in plutons. We demonstrate that we can achieve sub-permil precisions with MSWD values of around 1 on weighted mean dates by analyzing simultaneously precipitated zircon from H2O-enriched residual liquids within zircon-undersaturated basalt. Any age variation in granitoid rocks beyond this analytical spread is therefore considered real age dispersion, leading to an array of non-equivalent, analytically concordant points (within decay constant uncertainty). The reasons for such age dispersion may be the following: incorporation of antecrystic zircon from earlier magma batches of the same magmatic system, which have crystallized 104 to 105 years earlier; protracted zircon crystallization within a single batch of magma during its ascent and emplacement; presence of smallest xenocrystic cores in the analyzed zircons which contain a small proportion of older lead; minor degrees of unresolved lead loss that lead to slightly young ages. Though Pb-loss can largely be avoided by applying chemical abrasion prior to analysis, its effects are difficult to rule out completely

  3. Contrasting petrogenesis of Mg-K and Fe-K granitoids and implications for post-collisional magmatism: case study from the late-Archaean Matok pluton (South Africa)

    Science.gov (United States)

    Laurent, Oscar; Rapopo, Mafusi; Stevens, Gary; Moyen, Jean-François; Martin, Hervé; Zeh, Armin; Doucelance, Régis

    2014-05-01

    Post-collisional, metaluminous high-K calc-alkaline granitoids emplaced throughout the last 3.0 Ga are compositionally diverse, ranging from Mg-rich (e.g. sanukitoids) to Fe-rich compositions, both being intimately associated locally. While the origin of Mg-K suites is fairly well understood, that of Fe-K magmas is much less constrained. In addition, no model accounts for the post-collisional nature of both granitoid types, in one hand, and their geochemical differences, on the other hand. This work addresses these issues investigating the petrography and geochemistry (major-, trace elements and Sm-Nd isotope data on whole rocks, trace element and in situ Sr-Hf-Nd isotopes on accessory phases) of the 2.69 Ga-old Matok pluton, emplaced in the northern Kaapvaal Craton (South Africa). It consists of diorites, granodiorites and monzogranites, which show clear petrographic and compositional affinities with other post-collisional Fe-K suites. In spite of unradionegic Hf-Nd isotope compositions (ɛNd(WR) = -2.7 to -4.6; ɛHf(Zrn) = -3.2 to -3.6) and radiogneic Sr ones (Sr(i) > 0.702), most of the Matok pluton derives from neither reworking of local continental crust, nor crustal contamination of basaltic melt. Whole-rock as well as accessory mineral geochemistry indicate that the whole suite fractionated from a common mafic parent, either by partial melting or crystallization. Geochemical modelling shows that this parent magma or source rock derives itself from the involvement of two distinct mantle sources: (1) enriched, subcontinental lithospheric mantle, which was metasomatized by sedimentary (or sediment-derived) material derived from local crust of the Pietersburg block; and (2) asthenospheric mantle. Mantle enrichment took place less than 0.3 Ga prior to the pluton emplacement, and explains the 'crustal' isotope signature of the Matok pluton. Involvement of both sources is the only relevant way to explain the differences between Fe-K suites, such as the Matok pluton

  4. Magma flow paths and strain patterns in magma chambers growing by floor subsidence: a model based on magnetic fabric study of shallow-level plutons in the Stiavnica volcano-plutonic complex, Western Carpathians

    Czech Academy of Sciences Publication Activity Database

    Tomek, Filip; Žák, J.; Chadima, Martin

    2014-01-01

    Roč. 76, č. 11 (2014), Article 873. ISSN 0258-8900 Institutional support: RVO:67985831 Keywords : anisotropy of magnetic susceptibility (AMS) * caldera * intrusive strain * magma emplacement * pluton floor subsidence * stratovolcano Subject RIV: DB - Geology ; Mineralogy Impact factor: 2.519, year: 2014

  5. Identification of the AntiListerial Constituents in Partially Purified Column Chromatography Fractions of Garcinia kola Seeds and Their Interactions with Standard Antibiotics

    OpenAIRE

    Penduka, D.; Buwa, L.; Mayekiso, B.; Basson, A. K.; Okoh, A. I.

    2014-01-01

    Partially purified fractions of the n-hexane extract of Garcinia kola seeds were obtained through column chromatography and their constituents were identified through the use of gas chromatography coupled to mass spectrometry (GC-MS). Three fractions were obtained by elution with benzene as the mobile phase and silica gel 60 as the stationery phase and these were named Benz1, Benz2, and Benz3 in the order of their elution. The antiListerial activities of these fractions were assessed through ...

  6. Alteration of podzolized tills by acid load near Ni-Cu smelters at Monchegorsk, Kola Peninsula, Russia

    Directory of Open Access Journals (Sweden)

    Räisänen, M.L.

    1994-06-01

    Full Text Available Mineralogy and geochemistry of podzolized tills was studied in the area of dieback forest near the Ni-Cu smelters at Monchegorsk, and less extensively forest damage near by Apatity and Kirovsk in the Russian Kola Peninsula. The abundances of main elements (Si, Al, Fe, Mg, Ca, K, Na in the <64 μm fraction were determined by the hot aqua regia digestion method and inductively coupled plasma spectrometry. The clay mineralogy of the silt plus clay fraction was examined by X-ray diffraction after selective extraction and heating treatments. At all study sites, trioctahedral mica and chlorite were totally weathered from the silt and clay fraction (<64 μm of the eluvial layer, leaving behind interstratified mica-vermiculite-smectite clays. In general, the mixed-layer clay of the eluvial layer had low levels of hydroxy interlayering. Illuviated layers were characterized by hydroxy interlayered vermiculite-chlorite. The abundance of chlorite and mica was greater, and the degree of interlayering lower, in parent tills than in the overlying illuviated layers. Regardless of differences in bedrock and till geochemistry, the weathering sequence throughout the podzolized till profile was coherent at most of the sampling sites. Exceptionally, in a few profiles sampled at the totally destroyed forest site, the swelling mixed-layer clay of the eluvial layer displayed a neochloritized structure. On the basis of XRD patterns and geochemistry of the samples, it was inferred that a short-term decomposition of plagioclase had promoted, via inputs of Al-hydroxides, the transformation of mica-vermiculite-smectite to a poorly crystalline interstratification of chlorite-aluminous montmorillonite. The accelerated weathering occurring occasionally in exposed places was probably activated by the strongly acidic load in the vicinity of the smelters and the city of Monchegorsk.

  7. Long-term consequences for Northern Norway of a hypothetical release from the Kola nuclear power plant

    International Nuclear Information System (INIS)

    The spatial and temporal variation in radiocaesium and 90Sr doses to two population groups of the two Northernmost counties of Norway, Troms and Finnmark, following a hypothetical accident at the Kola nuclear power plant (KNPP) have been estimated using a model implemented within a geographical information system. The hypothetical accident assumes a severe loss of coolant accident at the KNPP coincident with meteorological conditions causing significant radionuclide deposition in the two counties. External doses are estimated from ground deposition and the behaviour of the different population groups, and internal doses from predicted food product activity concentrations and dietary consumption data. Doses are predicted for reindeer keepers and other Norwegian inhabitants, taking account of existing 137Cs and 90Sr deposition but not including the remedial effect of any countermeasures that might be used. The predicted doses, arising mainly from radiocaesium, confirm the Arctic Monitoring and Assessment Programme assessment that residents of the Arctic are particularly vulnerable to radiocaesium contamination, which could persist for many years. External doses are predicted to be negligible compared to ingestion doses. Ingestion doses for reindeer keepers are predicted to exceed 1 mSv y-1 for several decades primarily due to their high consumption of reindeer meat. Other Norwegians would also be potentially exposed to doses exceeding 1 mSv y-1 for several years, especially if they consume many local products. Whilst reindeer production is the most important exposure pathway, freshwater fish, lamb meat, dairy products, mushrooms and berries are also significant contributors to predicted ingestion doses. Radionuclide fluxes, defined as the total output of radioactivity in food from an area for a unit time, are dominated by reindeer meat. The results show the need for an effective emergency response, with appropriate countermeasures, should an accident of the scale

  8. Structural characterization and composition of Y-rich hainite from Sakharjok nepheline syenite pegmatite (Kola Peninsula, Russia)

    Science.gov (United States)

    Lyalina, L.; Zolotarev, A.; Selivanova, E.; Savchenko, Ye.; Zozulya, D.; Krivovichev, S.; Mikhailova, Yu.

    2015-08-01

    Y-rich hainite occurs in nepheline syenite pegmatite of the Sakharjok massif (Kola Peninsula, Russia). It forms euhedral prismatic crystals up to 2 mm in length as well as rims around an unidentified mineral phase (silicate of Ca, Y, Zr and Ti). The mineral is triclinic, space group P-1, a 9.6054(10), b 5.6928(6), c 7.3344(7) Å, α 89.903(2), β 101.082(2), γ 100.830(2)°, V 386.32(7) Å3, Z = 1. The calculated density is 3.39 g/cm3. Chemical composition of Sakharjok hainite is different from the previously published data by much higher Y and Nb contents up to 0.72 and 0.20 atoms per formula unit, respectively, by the two- to five-fold depletion in the LREEs and by the strong enrichment of the HREEs. From the single-crystal X-ray diffraction data, there is a significant amount of Y in the M1 site associated with the absence of Zr in it. Nb and Zr are concentrated in the M5 site substituting Ti. Combination of single-crystal X-ray diffraction data and electron microprobe data give the empirical formula (Ca1.04Y0.63REE0.24Mn0.02)∑1.93(Na0.92Ca0.77)∑1.69Ca2.00(Na0.65Ca0.10)∑0.75(Ti0.60Zr0.21Nb0.15Fe0.03)∑0.99((Si4.00Al0.02)∑4.02O14) (F2.61O1.39)∑4.00.

  9. Organochlorine pesticides, chlorinated dioxins and furans, and PCBs in peregrine falcon Falco peregrinus eggs from the Kola peninsula, Russia

    Science.gov (United States)

    Henny, C.J.; Ganusevich, S.A.; Ward, F.P.; Schwartz, T.R.

    1994-01-01

    Nesting of a bog-associated population of mlgfatory Peregrine Falcons, Falco peregrinus, along the Ponoy River depression, Kola Peninsula, Russia, has been studied since 1977. In 1987 91 production rates averaged 1.94 young per active nest and the number of breeding pairs increased from 4 to 10. In 1991, most eyrie sites were visited during the egg stage and a 'sample' egg was collected for contaminant analysis. Eight Peregrine Falcon eggs contained relatively low concentrations of p,p' -DOE (DOE) (geometric mean 3.5 g/g) and of other organochlorine pesticides. These DOE concentrations are similar to those reported in Peregrine Falcon eggs from an Alaskan population that had also showed a recent population increase. Eggshell thinning (11.4%) was similar to that found in Alaska. Concentrations of polychlorinated biphenyls (PCBs) were higher than DOE concentrations, comparable to the contamination profile shown by Peregrine Falcon populations in Fennoscandia, and were higher than those found in Alaskan birds. Before this study, no Peregrine Falcon eggs from Russia had 'been analyzed for PCB congeners, polychlorinated dibenzo- p-dioxins (PCDDs), or pol ychlorinated dibenzofurans (PCD Fs). Conversions of analytical concentrations of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD), other PCDDs, PCDFs and PCB congeners based on relative aryl hydrocarbon hydroxylase induction potencies allowed the estimation of total 2,3,7,8- TCDD equivalents (TEQs). The TEQs are in the range that is associated with embryonic mortality in other species. Even though the Peregrine Falcon population now seems to be released from decades of a DOT problem, exposure to other contaminant continues. There is an obvious need to assess further the sources and longer-term trends of the PCBs. We also report residue concentrations from one White-tailed Eagle, Haliaeetus albicilla, egg.

  10. Large capacity cnergy from Geo- Plutonic formation for power plants with zero CO2 emissions

    Directory of Open Access Journals (Sweden)

    R.H. Kozłowski

    2010-12-01

    Full Text Available Purpose: The publication presented is a realistic, one of the practicable idea for a substitute to system power plants, consisting in the construction of combined heat and power plants using renewable resources of geo-plutonic energy.Design/methodology/approach: There are various methods of obtaining geothermal energy and various uses for it. The proposed GEO-PLUTONIC ENERGY represents an endless, renewable source of energy coming from nuclear reaction in the Earth’s nucleus, where the temperature reaches 6,000 Centigrade. Mass production of electricity from the Earth’s heat, possible in Iceland due to the volcanic nature of these resources and the shallow depth at which they occur, was difficult in other countries due to the high cost of drilling to greater depths. This barrier has been overcome by us through using a special horizontal drilling technique.Findings: In order to extract and collect the accumulated energy from the area of a large thermal field, a modified shaft/drilling system (called a Super Daisy System equipped with a 3D grate of directional bore-holes called Jet-Stingers fitted with multi-functional heat exchangers is used. The emission-free concept of Geo-Plutonic Energy with the temperature of only over 250ºC, from which we can obtain about 30 MPa of pressure on the turbine. With increased the depth the temperature and heat transmissibility will be raised significantly, which can resulted the yield even to 7-10 MWe (of electricity from one deep heat exchanger.Research limitations/implications: From the rock mass we can collect renewable resources of ,,dry” ascending energy from the paleo heat flow coming from the great atomic furnace – the magma.Originality/value: We are experienced in using the appropriate hydro-thermodynamic theory and its applications which allows us to almost precisely forecast and control the quantity of heat not exceeding 20% of the 100% regeneration capability in the same time range.

  11. Natural radioactivity and radiation index of the major plutonic bodies in Greece.

    Science.gov (United States)

    Papadopoulos, A; Christofides, G; Koroneos, A; Papadopoulou, L; Papastefanou, C; Stoulos, S

    2013-10-01

    The natural radioactivity of the major plutonic bodies in Greece, as well as the assessment of any potential health hazard due to their usage as decorative building materials is studied. One hundred and twenty one samples from every major plutonic body in Greece, including various rock-types from gabbro to granite, have been measured for their natural radioactivity using γ-spectrometry methodology. According to the experimental results, the natural radioactivity levels were ranged up to 315 Bq kg(-1) for (226)Ra, up to 376 Bq kg(-1) for (232)Th and up to 1632 Bq kg(-1) for (40)K, with arithmetic mean values and standard deviations of 74 (±51), 85 (±54) and 881 (±331) Bq kg(-1) respectively, which are below the international representative mean values for granite stones. The excess on the effective dose received annually indoors due to granite tiles usage is estimated considering a standard room model where granite tiles with 1.5 cm in thickness cover only the floor of the room. The increment on the external γ-radiation effective dose rate shows a Gaussian distribution well dispersed below 0.3 mSv y(-1), presenting a mean value of 0.14 (±0.06) mSv y(-1). In case of the internal α-radiation a log-normal distribution is appeared scattering below 0.5 mSv y(-1) with a mean value 0.19 (±0.13) mSv y(-1), for a well-ventilated living environment. In case of a poor-ventilated room the increment on internal effective dose rate is estimated with a mean value 0.27 (±0.19) mSv y(-1) scattering below 0.8 mSv y(-1). The majority of the samples increase the external as well as the internal dose less than 30% of the maximum permitted limit of the effective dose rate. Therefore, at least from radiological point of view, the plutonic rocks of Greece could be safely used as decorative building materials. PMID:23827232

  12. Magmatic epidote, hornblende barometric estimates, and emplacement of the Conceicao das Creoulas pluton, Alto Pajeu Terrane, NE Brazil

    International Nuclear Information System (INIS)

    The Brasiliano-age magmatic epidote-bearing Conceicao das Creoulas batholith, in the Transversal Zone superterrane in northeastern Brazil, intruded migmatites and metagranitoids of the Riacho do Forno/Recanto Formations. This pluton is composed of porphyritic granodiorite and porphyritic monzogranite. Hornblendes in this pluton solidified between 6-7 Kbar in mafic enclaves and around 8 Kbar for porphyritic granodiorite as estimated by its Al contents. Temperatures for zircon saturation are in the 790-830 deg C range for the mafic enclaves and 800-850 deg C for the porphyritic granodiorite, whereas hornblende-plagioclase pairs yielded temperatures in the 670-690 de C range. In this pluton, epidote, undoubtedly of magmatic origin, with or without allanite cores, included in plagioclase, is rimmed by biotite or is partially resorpted by the magma. Sometimes, patches of hornblende and biotite are present inside epidote. Magmatic epidote compositions vary in the interval 20-25% mole of pistacite, and always exhibit Ti O2 < 0.20% by weight. This compositional range suggested crystallization along the NNO buffer. High initial ratio suggest a significant crustal component in the magma genesis. The magma probably was transported upward by diking and inflated outwards near or at its final site of emplacement, giving to the pluton a diapiric appearance. (author)

  13. Transpressional granite-emplacement model: Structural and magnetic study of the Pan-African Bandja granitic pluton (West Cameroon)

    Science.gov (United States)

    Sandjo, A. F. Yakeu; Njanko, T.; Njonfang, E.; Errami, E.; Rochette, P.; Fozing, E.

    2016-02-01

    The Pan-African NE-SW elongated Bandja granitic pluton, located at the western part of the Pan-African belt in Cameroon, is a K-feldspar megacryst granite. It is emplaced in banded gneiss and its NW border underwent mylonitization. The magmatic foliation shows NE-SW and NNE-SSW strike directions with moderate to strong dip respectively in its northern and central parts. This mostly, ferromagnetic granite displays magnetic fabrics carried by magnetite and characterized by (i) magnetic foliation with best poles at 295/34, 283/33 and 35/59 respectively in its northern, central and southern parts and (ii) a subhorizontal magnetic lineation with best line at 37/8, 191/9 and 267/22 respectively in the northern, central and southern parts. Magnetic lineation shows an `S' shape trend that allows to (1) consider the complete emplacement and deformation of the pluton during the Pan-African D 2 and D 3 events which occurred in the Pan-African belt in Cameroon and (2) reorganize Pan-African ages from Nguiessi Tchakam et al. (1997) compared with those of the other granitic plutons in the belt as: 686 ±17 Ma (Rb/Sr) for D 1 age of metamorphism recorded in gneiss; and the period between 604-557 Ma for D 2-D 3 emplacement and deformation age of the granitic pluton in a dextral ENE-WSW shear movement.

  14. U-Pb geochronology and geochemistry of Zahedan and Shah kuh plutons, eastern Iran: Implication for the late stage of the tectonic evolution of the South Sistan Zone

    Science.gov (United States)

    Mohammadi, Ali; Burg, Jean-Pierre; Ruh, Jonas; Von Quadt, Albrecht; Peytcheva, Irena

    2015-04-01

    The N-S trending Sistan Suture Zone (SSZ) in eastern Iran is attributed to eastward subduction beneath the Afghan continental block of an inlet of the Mesozoic Tethys Ocean. We present U-Pb zircon crystallization ages combined with petrography, major and trace element analyses, Hf isotopes, Rb-Sr and Sm-Nd isotopes of intermediate to granitic intrusions stretched along the southern segment of the SSZ. We obtained two clearly separated clusters of concordant ages, which are taken as the crystallization age of the host plutonic rocks. The first cluster, between ca 42.5 and ca 44.5 Ma from euhedral zircons of the main granodiorite to diorite and related dykes. The second age cluster span from ca 28.3 to ca 31 Ma. These ages were obtained for granites and dykes, the latter being consistently slightly younger than the country rock. The high SiO2 content (62-75 wt %) of Eocene magmatic rocks points to melts with a high crustal contribution in consistency with their relatively high-K (3-4.4 wt %) calc-alkaline nature. The high SiO2 and K contents in the Oligocene calk-alkaline rocks series shows adakite-like fractionation. Oligocene adakite-like rocks have relatively low to medium 87Sr/86Sr and 143Nd/144Nd ratios, which are similar to typical lower thick crust-derived adakites. The mix positive and negative ɛHf(T) values of all zircons from the 42.5-44.5 Ma shows mix nature of magma (the contamination of subduction related magma with partial melting of crust). The positive ɛHf(T) values of all zircons from the 28-31 Ma adakite-like rocks indicate that the magma was not produced from pure depleted mantle. Instead, they are consistent with a host magma source within a largely juvenile and subduction-related mafic lower crust. Eocene granitoids represent anatectic melts emplaced at higher crustal levels; in addition slab melts modified the mantle wedge and subsequent, contaminated mantle magmas fed intrusions such as the Zahedan diorite.

  15. Alkaline sorbent injection for mercury control

    Science.gov (United States)

    Madden, Deborah A.; Holmes, Michael J.

    2003-01-01

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  16. Alkaline rocks and the occurrence of uranium

    International Nuclear Information System (INIS)

    Many alkaline complexes contain uranium and other minerals in low concentrations and are regarded as constituting valuable potential reserves. Certain complex metallurgical problems, however, remain to be solved. Alkaline rocks occur in a number of forms and environments and it is noted that they are generated during periods of geological quiescence emplaced mainly in stable aseismic areas. Many occur along the extensions of oceanic transform faults beneath the continental crust and the application of this concept to areas not currently known to host alkaline complexes may prove useful in identifying potential target areas for prospecting operations

  17. Exploring the plutonic crust at a fast-spreading ridge:new drilling at Hess Deep

    Energy Technology Data Exchange (ETDEWEB)

    Gillis, Kathryn M. [Univ. of Victoria, BC (Canada). School of Earth and Ocean Sciences; Snow, Jonathan E. [Univ. of Houston, Houston, TX (United States). Earth & Atmospheric Sciences; Klaus, Adam [Texas A & M Univ., College Station, TX (United States). Integrated Ocean Drilling Program (IODP). United States Implementing Organization.; Guerin, Gilles [Lamont-Doherty Earth Observatory of Columbia Univ., Palisades, NY (United States). Borehole Research Group; Abe, Natsue [Japan Agency for Marine-Earth Science and Technology (JAMSTEC), Yokosuka (Japan). Inst. for Research on Earth Evolution (IFREE); Akizawa, Norikatsu [Kanazawa Univ. (Japan). Dept. of Earth Sciences; Ceuleneer, Georges [Univ. Paul Sabatier, Toulouse (France). Observatoire Midi-Pyrenees (UMS 831), CNRS; Cheadle, Michael J. [Univ. of Wyoming, Laramie, WY (United States). Dept. of Geology and Geophysics; Adriao, Alden de Brito [Federal Univ. of Rio Grande do Sul, Porto Alegre (Brazil). Geology Inst. (IGEO); Faak, Kathrin [Ruhr Univ., Bochum (Germany). Geological Inst.; Falloon, Trevor J. [Univ. of Tasmania, Hobart, TAS (Australia). Inst. for Marine and Antarctic Studies; Friedman, Sarah A. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology; Godard, Marguerite M. [Univ. Montpellier II (France). Geosciences Montpellier-UMR 5243; Harigane, Yumiko [National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Marine Geology Dept.; Horst, Andrew J. [Syracuse Univ., NY (United States). Dept. of Earth Science; Hoshide, Takashi [Tohoku Univ., Sendai (Japan). Graduate School of Science; Ildefonse, Benoit [Univ. Montpellier II (France). Lab. de Tectonophysique; Jean, Marlon M. [Northern Illinois Univ., DeKalb, IL (United States). Dept. of Geology and Environmental Geosciences; John, Barbara E. [Univ. of Wyoming, Laramie, WY (United States). Dept. of Geology and Geophysics; Koepke, Juergen H. [Univ. of Hannover (Germany). Inst. of Mineralogy; Machi, Sumiaki [Kanazawa Univ. (Japan). Dept. of Earth Sciences; Maeda, Jinichiro [Hokkaido Univ., Sapporo (Japan). Dept. of Natural History Sciences; Marks, Naomi E. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Chemistry and Material Sciences Dept.; McCaig, Andrew M. [Univ. of Leeds (United Kingdom). School of Earth and Environment; Meyer, Romain [Univ. of Bergen (Norway). Dept. of Earth Science and Centre for Geobiology; Morris, Antony [Univ. of Plymouth (United Kingdom). School of Earth, Ocean & Environmental Sciences; Nozaka, Toshio [Okayama Univ. (Japan). Dept. of Earth Sciences; Python, Marie [Hokkaido Univ., Sapporo (Japan). Dept. of Earth and Planetary Sciences; Saha, Abhishek [Indian Inst. of Science (IISC), Bangalore (India). Centre for Earth Sciences; Wintsch, Robert P. [Indiana Univ., Bloomington, IN (United States). Dept. of Geological Sciences

    2013-02-28

    Integrated Ocean Drilling Program (IODP) Hess Deep Expedition 345 was designed to sample lower crustal primitive gabbroic rocks that formed at the fast-spreading East Pacific Rise (EPR) in order to test models of magmatic accretion and the intensity of hydrothermal cooling at depth. The Hess Deep Rift was selected to exploit tectonic exposures of young EPR plutonic crust, building upon results from ODP Leg 147 as well as more recent submersible, remotely operated vehicle, and near-bottom surveys. The primary goal was to acquire the observations required to test end-member crustal accretion models that were in large part based on relationships from ophiolites, in combination with mid-ocean ridge geophysical studies. This goal was achieved with the recovery of primitive layered olivine gabbros and troctolites with many unexpected mineralogical and textural relationships, such as the abundance of orthopyroxene and the preservation of delicate skeletal olivine textures.

  18. MCROC - a model to estimate time-dependent microcracking in plutonic rock due to heat

    International Nuclear Information System (INIS)

    Atomic Energy of Canada Limited is studying the disposal of nuclear-fuel waste in a vault in plutonic rock. An important part of this study is to develop models to assess the rate of escape of waste components to the biosphere. Time-dependent changes in the system are important. One such change is the increase in temperature of the rock mass surrounding the vault. Differential thermal expansion between rock constituents (crystals) and the expansion of trapped water will produce microcracking and, hence, possibly changes in intact-rock elastic modulus and permeability. This report describes a model (MCROC) devised to estimate the extent of microcracking and consequent changes in rock elastic modulus and permeability. The model is discussed in detail and is illustrated by various calculations pertinent to a vault designed to accept Canadian nuclear fuel waste. 18 refs

  19. U-Pb geochronology of Gangdese (Transhimalaya) plutonism in the Lhasa-Xigaze region, Tibet

    International Nuclear Information System (INIS)

    A series of different plutons from the Lhasa-Xigaze segment of the Gangdese (Transhimalaya) belt has been studied by high-resolution U-Pb analyses of zircon (using zircon fractions of 5-100 grains each, selected upon specific grain characteristics). For two diorites, located east of Xigaze (Dazhuka), the zircons yield concordant ages of 93.4 +- 1.0 and 94.2 +- 1.0 m.y., respectively. Also concordant ages of 41.1 +- 0.4 and 41.7 +- 0.4 m.y. have been obtained for two granodiorites, collected southwest of Lhasa (Qushui). The precision on the ages of two granites from the Xigaze and Lhasa area, is limited by two factors: the presence of inherited radiogenic lead and the occurrence of subsequent lead loss. However, some concordant zircons, detected in both granites, define approximate ages of about 67 and 53 m.y., respectively. The inherited lead components show the melting of Precambrian material was involved in magma genesis. The U-Pb ages substantiate a magmatic activity lasting from mid-Cretaceous (Cenomanian) to Eocene (Lutetian) time. Such a period of plutonism at the southern margin of Eurasia, as well as the occurrence of magma generation from continental crust, suggest that the Gangdese range results from the subduction of Tethys oceanic lithosphere (Indian plate) underneath Eurasia (Eurasian plate). If this model is true, the collision of India with Eurasia (Along the Lhasa-Xigaze sector) postdates the emplacement of the 41 m.y. old Gangdese granodiorites, i.e. the collision occurred after Lutetian time. (orig.)

  20. The geology and geochronology of the Belmont pluton and microgranite dykes from the Margate area

    International Nuclear Information System (INIS)

    Field, petrographic, geochemical and Rb-Sr isotope data are presented for two granitic units which are considered to represent amongst the youngest intrusive rocks in the Natal Metamorphic Province. These are the Belmont granite pluton and a suite of unfoliated biotite microgranite dykes from the Margate area. The data suggest that these rocks do not form part of a consanguineous suite as previously envisaged. It is concluded that the Belmont pluton (1055 ± 60Ma) should be assigned to the garnet leucogranite phase of the syntectonic Margate Suite, and that the dykes (∼965 Ma) represent the products of a discrete, late-stage magmatic event which took place towards the end of the Natal orogenesis. Furthermore, the high initial Sr isotopic ratio (∼0,715) of the dykes suggests that they were derived from the melting of pre-existing radiogenic crust. The termination of major tectono-magmatic events in the Late Proterozoic Namaqua-Natal Belt apparently youngs from west to east across South Africa. Reconstructions of Gondwanaland place the Falkland Plateau and the Maudheim Province of Antarctica off the southeast of Africa. Dates obtained from this region range from ∼1000Ma to ∼500Ma, suggesting a continued decrease in age of tectono-magmatic activity eastwards. The microgranite dykes described here are unequivocally amongst the youngest post-tectono-metamorphic intrusions of southern Natal, yet they do not preserve any whole-rock indication of Pan-African isotopic disturbances. Sparse Rb-Sr mineral isotopic data support this indication that there was no significant Pan-African activity in the Natal Metamorphic Province. 8 figs., 7 tabs., 38 refs

  1. Obrobení náboje kola formulového vozu na CNC obráběcím centru

    OpenAIRE

    Jelínek, Petr

    2011-01-01

    Diplomová práce se zabývá návrhem a výrobou pravého zadního náboje kola formulového vozu na CNC obráběcím centru s využitím moderních technologií CAD/CAM. V teoretické části je uveden popis a charakteristika technologie frézování společně s obrobitelností hliníkových slitin. Praktická část se zabývá konstrukcí náboje kola v CAD programu Pro/Engineer, návrhem obráběcích strategií za pomoci CAM programu PowerMILL a samotnou realizací výroby na CNC obráběcím stroji. Práce je ukončena technicko-e...

  2. Climatic response of stable isotope variations in wood cellulose of pine (Pinus sylvestris l.) and their tree-ring width on the Kola Peninsula, north-western Russia

    International Nuclear Information System (INIS)

    The Kola Peninsula region of northwestern Russia, adjacent to relatively well studied Scandinavian areas, is climatically affected by not only the Gulf Stream and the North Atlantic but also the Eurasian continent. Living and subfossil pine trees from the Khibiny mountains on the Kola Peninsula were analysed for carbon, oxygen and hydrogen isotope composition and for tree-ring width. Comparisons of local meteorological and tree-ring data revealed significant correlations. δ13C and δ18O values are particularly sensitive to changes in the temperature in July and August and to precipitation in the winter months of the previous year, respectively. On average, 13C in the cellulose of pine trees between c. 1000 and 1300 AD is enriched by δ values of around 1 per mille compared to the modern trees from this region. This indicates a distinctly warmer summer climate at that time (the Medieval Warm epoch in Europe) than recently observed. The δ18O values of wood cellulose and the δ2H values of non-exchangeable hydrogen of tree cellulose from both fossil and modern samples cover a wide range between around 22 and 29 per mille and between about -80 and -120 per mille vs. SMOW, respectively. This suggests variations in the seasonal distribution of precipitation at that time, assuming its source has remained the same as in the past. (author)

  3. Komplexní strukturální analýza kompresorového kola s využitím MKP

    OpenAIRE

    Chromek, Lukáš

    2012-01-01

    Tato diplomová práce se zabývá využitím MKP softwaru ANSYS při analýze skutečného lopatkového kola radiálního kompresoru, používaného v malých leteckých turbínových motorech. Kompresorové kolo bylo navrženo a vyrobeno v První brněnské strojírně Velká Bíteš, konkrétně na Divizi letecké techniky. Cílem diplomové práce je komplexní analýza kompresorového kola, která se skládá z několika dílčích částí. První část je věnována strukturální statické a elasticko-plastické pevnostní analýze, za účelem...

  4. Výroba modelu jízdního kola s využitím aditivní metody Fused Deposition Modeling

    OpenAIRE

    Krobot, Daniel

    2012-01-01

    Bakalářská práce je zaměřena na popis současného stavu problematiky navrhování výrobků, především dostupným technologiím Rapid Prototyping. Práce se zaměřuje na výrobu 3D modelu jízdního kola s využitím grafického programu Autodesk Inventor. Výroba modelu jízdního kola byla realizována na 3D tiskárně uPrint s využitím metody Fused Deposition Modeling. Součástí práce je také technicko-ekonomické zhodnocení. The thesis is focused on describing the current state of product design issues, in p...

  5. Verification of the TRANSURANUS-WWER code version V1M2J00 by SOFIT and KOLA-3 data bases

    International Nuclear Information System (INIS)

    The paper presents verification results of the TRANSURANUS computer code for fuel behavior modeling. The verification has been done by the SOFIT and Kola-3 database set upon additional information from the year 2000. A brief description of SOFIT database as a part of IFPE-OECD/IAEA-NEA database is shown including remarks concerning some errors in the database, obtained by the authors. Verification of the TRANSURANUS code by SOFIT-1.1 experimental data includes justifying of the models and performing of calculations for: burnup, fuel central temperature, fission gas release, changes in the fuel rod diameter. Verification by the SOFIT-1.3 experimental data shows results from calculations of: fuel central temperature, axial cladding elongation and axial fuel expansion. Verification by Kola-3 database also includes justifying of the models and performing of the calculations for: burnup, temperature, fission gas release, size changes (fuel elongation, diameter and gap size), internal fuel rod gas pressure. The updated results reflect more adequately the real fuel behavior, observed in the experiment. The latest TRANSURANUS-WWER version V1M2J00 reproduces very well the existing experimental data for all variables with so chosen set of models and options. Some exceptions could be seen, most of which are due to the imperfections of the experimental data

  6. Alkalinity in oil field waters - what alkalinity is and how it is measured

    International Nuclear Information System (INIS)

    The alkalinity is an important parameter in the description of pH-behaviour, buffer capacity and scaling potentials in oil field waters. Although the alkalinity is widely used, it seems to be considerable confusion in connection with the concept. It is often used incorrectly and different authors define the concept in different ways. Several different methods for the determination of alkalinity can be found in the literature. This paper discusses the definition of alkalinity and how to use alkalinity in oil field waters to obtain data of importance for scale and pH predictions. There is also shown how a simple titration of oil field waters can give both the alkalinity and the content of organic acids in these waters. It is obvious from these findings that most of the methods used to day may give considerable errors when applied to oil field waters with high contents of organic acids. 8 refs., 8 figs., 5 tabs

  7. Geology, petrology and U-Pb geochronology of Serra da Rajada Granitic Pluton: implications about ediacaran magmatic evolution in NE portion of the Rio Piranhas-Serido Domain (NE of Borborema Province)

    International Nuclear Information System (INIS)

    The Ediacaran plutonic activity, related to the Brazilian/Pan-African orogeny, is one of the most important geological features in the Borborema Province, formed by batholiths, stocks and dikes. The Serra da Rajada Granitic Pluton (SRGP), located in the central portion of the Rio Piranhas-Serido Domain, is an example of these bodies. This site is the target of cartographic, petrographic, lithochemical and geochronological studies. Its rocks are described as monzogranites consisting of K-feldspar, plagioclase (oligoclase-An23-24%), quartz and biotite (main mafic), having as accessory minerals opaque, titanite, allanite, apatite and zircon. Chlorite, white mica and carbonate are alteration minerals. Lithochemical data from 15 samples show quite evolved rocks (SiO2 , 69% to 75%), rich in alkalis (Na2O + K2O ≥ 8.0%), depleted in MgO (≤ 0.45%), CaO (≤ 1.42%) and TiO2 (≤ 0.36%), and displaying moderate levels of Fe2O3 t (2.16 to 3.53%). These rocks present a transitional nature between metaluminous and peraluminous (predominance of the latter) and have subalkaline/monzonitic affinity (high-K Calc-alkaline). Harker diagrams represent negative correlations in Fe2O3t, MgO and CaO, indicating fractionation of mafic and plagioclase. The REE spectrum show enrichment of light in relation to heavy REE (LaN/YbN = 23.70 to 10.13), with negative anomaly in Eu (Eu/ Eu* = 0.70 to 10.13) suggesting fractionation or accumulation in the feldspars source (plagioclase). Data integration allows correlating the SRGP rocks with those described as Equigranular high-K Calc-alkaline Suite. The U-Pb geochronology and Sm-Nd isotope dating indicate that the biotite monzogranite have a crystallization age of 557 ± 13 Ma and TDM model age of 2.36 Ga, respectively, and εNd value of - 20.10 for the crystallization age, allowing to infer a crustal source for the magma generated in the Paleoproterozoic age. (author)

  8. Batievaite-(Y), Y2Ca2Ti[Si2O7]2(OH)2(H2O)4, a new mineral from nepheline syenite pegmatite in the Sakharjok massif, Kola Peninsula, Russia

    Science.gov (United States)

    Lyalina, L. M.; Zolotarev, A. A.; Selivanova, E. A.; Savchenko, Ye. E.; Krivovichev, S. V.; Mikhailova, Yu. A.; Kadyrova, G. I.; Zozulya, D. R.

    2016-05-01

    Batievaite-(Y), Y2Ca2Ti[Si2O7]2(OH)2(H2O)4, is a new mineral found in nepheline syenite pegmatite in the Sakharjok alkaline massif, Western Keivy, Kola Peninsula, Russia. The pegmatite mainly consists of nepheline, albite, alkali pyroxenes, amphiboles, biotite and zeolites. Batievaite-(Y) is a late-pegmatitic or hydrothermal mineral associated with meliphanite, fluorite, calcite, zircon, britholite-group minerals, leucophanite, gadolinite-subgroup minerals, titanite, smectites, pyrochlore-group minerals, zirkelite, cerianite-(Ce), rutile, behoite, ilmenite, apatite-group minerals, mimetite, molybdenite, and nickeline. Batievaite-(Y) is pale-cream coloured with white streak and dull, greasy or pearly luster. Its Mohs hardness is 5-5.5. No cleavage or parting was observed. The measured density is 3.45(5) g/cm3. Batievaite-(Y) is optically biaxial positive, α 1.745(5), β 1.747(5), γ 1.752(5) (λ 589 nm), 2V meas. = 60(5)°, 2V calc. = 65°. Batievaite-(Y) is triclinic, space group P-1, a 9.4024(8), b 5.5623(5), c 7.3784(6) Å, α 89.919(2), β 101.408(2), γ 96.621(2)°, V 375.65(6) Å3 and Z = 1. The eight strongest lines of the X-ray powder diffraction pattern [d(Å)(I)(hkl)] are: 2.991(100)(11-2), 7.238(36)(00-1), 3.061(30)(300), 4.350(23)(0-1-1), 9.145(17)(100), 4.042(16)(11-1), 2.819(16)(3-10), 3.745(13)(2-10). The chemical composition determined by electron probe microanalysis (EPMA) is (wt.%): Nb2O5 2.25, TiO2 8.01, ZrO2 2.72, SiO2 29.96, Al2O3 0.56, Fe2O3 0.43, Y2O3 11.45, La2O3 0.22, Ce2O3 0.33, Nd2O3 0.02, Gd2O3 0.07, Dy2O3 0.47, Er2O3 1.07, Tm2O3 0.25, Yb2O3 2.81, Lu2O3 0.45, CaO 24.98, MnO 1.31, MgO 0.01, Na2O 1.13, K2O 0.02, F 2.88, Cl 0.19, H2O 6.75 (determined on the basis of crystal structure data), O = (F,Cl) -1.25, total 97.09 wt.%. The empirical formula based on the EPMA and single-crystal structure analyses is (Y0.81Ca0.65Mn0.15Zr0.12Yb0.11Er0.04Fe3+ 0.04Ce0.02Dy0.02Lu0.02La0.01Tm0.01)Σ2.00((H2O)0.75Ca0.70□0.55)Σ2.00Ca2.00(□0.61Na0.25( H2O

  9. Technetium recovery from high alkaline solution

    Science.gov (United States)

    Nash, Charles A.

    2016-07-12

    Disclosed are methods for recovering technetium from a highly alkaline solution. The highly alkaline solution can be a liquid waste solution from a nuclear waste processing system. Methods can include combining the solution with a reductant capable of reducing technetium at the high pH of the solution and adding to or forming in the solution an adsorbent capable of adsorbing the precipitated technetium at the high pH of the solution.

  10. Alkaline tolerant dextranase from streptomyces anulatus

    Science.gov (United States)

    Decker, Stephen R.; Adney, William S.; Vinzant, Todd B.; Himmel, Michael E.

    2003-01-01

    A process for production of an alkaline tolerant dextranase enzyme comprises culturing a dextran-producing microorganism Streptomyces anulatus having accession no. ATCC PTA-3866 to produce an alkaline tolerant dextranase, Dex 1 wherein the protein in said enzyme is characterized by a MW of 63.3 kDa and Dex 2 wherein its protein is characterized by a MW of 81.8 kDa.

  11. Alkaline Water and Longevity: A Murine Study

    Science.gov (United States)

    Magro, Massimiliano; Corain, Livio; Ferro, Silvia; Baratella, Davide; Bonaiuto, Emanuela; Terzo, Milo; Corraducci, Vittorino; Salmaso, Luigi; Vianello, Fabio

    2016-01-01

    The biological effect of alkaline water consumption is object of controversy. The present paper presents a 3-year survival study on a population of 150 mice, and the data were analyzed with accelerated failure time (AFT) model. Starting from the second year of life, nonparametric survival plots suggest that mice watered with alkaline water showed a better survival than control mice. Interestingly, statistical analysis revealed that alkaline water provides higher longevity in terms of “deceleration aging factor” as it increases the survival functions when compared with control group; namely, animals belonging to the population treated with alkaline water resulted in a longer lifespan. Histological examination of mice kidneys, intestine, heart, liver, and brain revealed that no significant differences emerged among the three groups indicating that no specific pathology resulted correlated with the consumption of alkaline water. These results provide an informative and quantitative summary of survival data as a function of watering with alkaline water of long-lived mouse models. PMID:27340414

  12. Carboniferous magmatism in the Evora Massif (southwest Portugal, Ossa-Morena Zone): from typical arc calc-alkaline to adakitic-like magmatism

    Science.gov (United States)

    Lima, Selma M.; Neiva, Ana M. R.; Ramos, Joao M. F.

    2014-05-01

    The Evora Massif is one of the subdivisions of western Ossa-Morena Zone. It is a dome-like structure mainly composed of Ediacaran, Cambrian and Ordovician country rocks, affected by medium- and high-grade metamorphism coeval with the emplacement of several mafic to felsic intrusive bodies. The last magmatic event recorded in this area (Carboniferous) consists of calc-alkaline volcanism and voluminous plutonism (mainly composed by tonalites, gabbros, diorites and late-orogenic granodiorites and granites) [1]. Detailed chemical and isotopic studies from Evora Massif plutons were performed in the last few years. Whole-rock chemical and isotopic data suggest that the Hospitais tonalite (HT), Alto de Sao Bento area (ASB) and Reguengos de Monsaraz pluton (RM) resulted from fractional crystallization of mantle-derived magmas followed by mixing with variable proportions of crustal melts [2-4]. U-Pb ID-TIMS data indicate an age of 337-335 for the RM [4]. The Pavia pluton is a multiphase granitic body constructed incrementally by the episodic emplacement of several batches of magma (at 328 Ma, ca. 324 Ma and 319-317 Ma) [5]. The main granitic phases range from tonalite to two-mica granite that contain rare surmicaceous and fine-grained enclaves, and granitic and amphibolitic xenoliths. On the other hand, they are cut by abundant rhyodacite porphyries, microgranites (s.l.) and pegmatite dikes, predominantly oriented NE-SW and NW-SE. Although each phase seems to represent a distinct batch of magma, whole-rock Sr-Nd isotopic data suggest a similar and fairly homogenous source for all the constituent phases. Initial 87Sr/86Sr varies between 0.70428 and 0.7058 and ɛ Ndt ranges from -3.4 to +0.4, pointing towards a mantle or juvenile crust origin. A higher variation is observed in whole-rock δ18O (5.6-9.6 o), consistent with assimilation of crust. The PP was interpreted as the result of assimilation-fractional crystallization of a basaltic magma. Substantial differences between

  13. Soil organic carbon sequestration as affected by afforestation: the Darab Kola forest (north of Iran) case study.

    Science.gov (United States)

    Kooch, Yahya; Hosseini, Seyed Mohsen; Zaccone, Claudio; Jalilvand, Hamid; Hojjati, Seyed Mohammad

    2012-09-01

    Following the ratification of the Kyoto Protocol, afforestation of formerly arable lands and/or degraded areas has been acknowledged as a land-use change contributing to the mitigation of increasing atmospheric CO(2) concentration in the atmosphere. In the present work, we study the soil organic carbon sequestration (SOCS) in 21 year old stands of maple (Acer velutinum Bioss.), oak (Quercus castaneifolia C.A. Mey.), and red pine (Pinus brutia Ten.) in the Darab Kola region, north of Iran. Soil samples were collected at four different depths (0-10, 10-20, 20-30, and 30-40 cm), and characterized with respect to bulk density, water content, electrical conductivity, pH, texture, lime content, total organic C, total N, and earthworm density and biomass. Data showed that afforested stands significantly affected soil characteristics, also raising SOCS phenomena, with values of 163.3, 120.6, and 102.1 Mg C ha(-1) for red pine, oak and maple stands, respectively, vs. 83.0 Mg C ha(-1) for the control region. Even if the dynamics of organic matter (OM) in soil is very complex and affected by several pedo-climatic factors, a stepwise regression method indicates that SOCS values in the studied area could be predicted using the following parameters, i.e., sand, clay, lime, and total N contents, and C/N ratio. In particular, although the chemical and physical stabilization capacity of organic C by soil is believed to be mainly governed by clay content, regression analysis showed a positive correlation between SOCS and sand (R = 0.86(**)), whereas a negative correlation with clay (R = -0.77(**)) was observed, thus suggesting that most of this organic C occurs as particulate OM instead of mineral-associated OM. Although the proposed models do not take into account possible changes due to natural and anthropogenic processes, they represent a simple way that could be used to evaluate and/or monitor the potential of each forest plantation in immobilizing organic C in soil (thus

  14. 21 CFR 864.7660 - Leukocyte alkaline phosphatase test.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Leukocyte alkaline phosphatase test. 864.7660... Leukocyte alkaline phosphatase test. (a) Identification. A leukocyte alkaline phosphatase test is a device used to identify the enzyme leukocyte alkaline phosphatase in neutrophilic granulocytes...

  15. 40Ar/39Ar dating of alkaline and tholeiitic magmatism of Saudi Arabia related to the early Red Sea Rifting

    International Nuclear Information System (INIS)

    40Ar/39Ar plateau-ages at 27-28 Ma obtained on feeder dykes and one lava flow of the alkaline massif of Harrat Hadan are in agreement with the assumed age partly deduced from the conventional K/Ar data of the early activity of other alkaline volcanic massifs from Saudi Arabia. This magmatic activity is spatially distributed over a large area, along the western edge of the Arabian plate, and their N-S to NW-SE volcano-tectonic directions are similar to those of the future Red Sea Rift. Preliminary results obtained on tholeiitic lava flows, dykes and plutons gave 17 plateau-ages which, combined with 6 ages deduced from more disturbed age-spectra, display a main histogram peak from 24 to 21 Ma, much narrower than that obtained with conventional K/Ar ages on the same formations. Therefore, a strong tholeiitic activity affected a narrow linear area following the actual eastern Red Sea coast, over nearly 1700 km, during a brief period of time, and without showing any apparent migration. The main volcano-tectonic features of the future Red Sea are strongly outlined during this event. Such brief magmatic episodes related to continental rifts have also been documented by precise 40Ar/39Ar analyses on the British Tertiary Igneous Province, the Deccan traps and the eastern Central Atlantic. (orig.)

  16. Composition of coarse-grained magnetite from pegmatite dikes related to plutons of quartz monzonite in the Jabal Lababa area, Kingdom of Saudi Arabia

    Science.gov (United States)

    Overstreet, William C.; Mousa, Hassan; Matzko, John J.

    1985-01-01

    Crystals of magnetite as large as 30 mm long and 7 mm thick are locally present in quartz-rich zones of interior and exterior pegmatite dikes related to plutons of quartz monzonite in the Jabal Lababa area. Niobium, tin, and yttrium are strongly enriched in six specimens of magnetite from interior pegmatite dikes in a small pluton where these elements form geochemical anomalies in nonmagnetic heavy-mineral concentrates from wadi sediment. Less abundant anomalous elements in the magnetite are molybdenum, lead, and zirconium, which also tend to be present in anomalous amounts in the nonmagnetic concentrates from the niobium-bearing pluton. The most anomalous trace element in the magnetite is zinc, which is at least 10 times as abundant as it is in the quartz monzonite plutons or in the nonmagnetic concentrates. The capacity of magnetite to scavenge molybdenum, zinc, niobium, lead, tin, yttrium, and zirconium suggests the possible utility of magnetite as a geochemical sample medium.

  17. Prophylactic treatment with alkaline phosphatase in cardiac surgery induces endogenous alkaline phosphatase release

    NARCIS (Netherlands)

    Kats, Suzanne; Brands, Ruud; Hamad, Mohamed A. Soliman; Seinen, Willem; Schamhorst, Volkher; Wulkan, Raymond W.; Schoenberger, Jacques P.; van Oeveren, Wim

    2012-01-01

    Introduction: Laboratory and clinical data have implicated endotoxin as an important factor in the inflammatory response to cardiopulmonary bypass. We assessed the effects of the administration of bovine intestinal alkaline phosphatase (bIAP), an endotoxin detoxifier, on alkaline phosphatase levels

  18. A paleomagnetic and stable isotope study of the pluton at Rio Hondo near Questa, New Mexico: Implications for CRM related to hydrothermal alteration

    International Nuclear Information System (INIS)

    Paleomagnetic and rock magnetic data combined with stable isotope data from the middle Tertiary pluton along the Rio Hondo in northern New Mexico suggest that its magnetic remanence has both thermal (TRM) and high-temperature chemical (CRM) components. Oxygen isotope temperatures indicate that magnetite associated with the more rapidly cooled higher levels of the pluton, and with mafic inclusions and cogenetic rhyolitic dikes sampled at lower levels of exposure, ceased subsolidus recrystallization and isotopic exchange above its Curie temperature (5800C) in the presence of a magmatic fluid. Continued cooling imparted a TRM to these portions of the pluton. The more slowly cooled granodiorite at lower levels has quartz-magnetite isotopic temperatures that are below the Curie temperature of magnetite implying that its magnetization is high-temperature CRM. Sub-Curie isotopic temperatures for other granitic plutons in the western U.S.A. suggest that CRM may be commonly derived from subsolidus interactions between magnetite and magmatic fluids in plutonic rocks. A meteoric-hydrothermal system generated by the cooling Rio Hondo pluton, and not by younger adjacent intrusions, resulted in limited alteration along zones of high permeability near the southern margin of the Rio Hondo pluton, and in more prevasive alteration of the pluton to the north. The meteoric-hydrothermal alteration occurred at relatively high temperatures (>3500C) and, with the exception of local chloritization, caused little visible alteration of the rocks. The isotopic ratios indicate that little of the magnetite could have grown from or exchanged with a meteoric-hydrothermal fluid. (orig.)

  19. A paleomagnetic and stable isotope study of the pluton at Rio Hondo near Questa, New Mexico: implications for CRM related to hydrothermal alteration

    Science.gov (United States)

    Hagstrum, J.T.; Johnson, C.M.

    1986-01-01

    Paleomagnetic and rock magnetic data combined with stable isotope data from the middle Tertiary pluton along the Rio Hondo in northern New Mexico suggest that its magnetic remanence has both thermal (TRM) and high-temperature chemical (CRM) components. Oxygen isotope temperatures indicate that magnetite associated with the more rapidly cooled higher levels of the pluton, and with mafic inclusions and cogenetic rhyolitic dikes sampled at lower levels of exposure, ceased subsolidus recrystallization and isotopic exchange above its Curie temperature (580??C) in the presence of a magmatic fluid. Continued cooling imparted a TRM to these portions of the pluton. The more slowly cooled granodiorite at lower levels has quartz-magnetite isotopic temperatures that are below the Curie temperature of magnetite implying that its magnetization is high-temperature CRM. Sub-Curie isotopic temperatures for other granitic plutons in the western U.S.A. suggest that CRM may be commonly derived from subsolidus interactions between magnetite and magmatic fluids in plutonic rocks. A meteoric-hydrothermal system generated by the cooling Rio Hondo pluton, and not by younger adjacent intrusions, resulted in limited alteration along zones of high permeability near the southern margin of the Rio Hondo pluton, and in more prevasive alteration of the pluton to the north. The meteoric-hydrothermal alteration occurred at relatively high temperatures (> 350??C) and, with the exception of local chloritization, caused little visible alteration of the rocks. The isotopic ratios indicate that little of the magnetite could have grown from or exchanged with a meteoric-hydrothermal fluid. ?? 1986.

  20. Mineralogical, chemical and isotopic diversity in plutonic rock suites from the Coastal Maine Magmatic Province:the role of source region heterogeneity, tectonic setting and magmatic processes

    OpenAIRE

    Hogan, John Patrick

    1990-01-01

    This dissertation represents an investigation of the mid-Paleozoic tectono-thermal and kinematic evolution of the crust in eastern coastal Maine as recorded by the plutonic rocks of this region. The first chapter describes the plutonic rocks of the Coastal Maine Magmatic Province. A tectonic model is developed in which late Ordovician-Silurian bimodal magmatism is interpreted to reflect crustal melting as a result of intraplating of mantle melts at high crustal levels during...

  1. Petro-structural study of volcano-plutonic rocks of Yaoure Mountains: Contribution to understanding the metallotectic gold mineralization (Central Côte d'Ivoire)

    OpenAIRE

    Barthelemy Gnammytchet KOFFI; Gbele Ouattara; Alain Nicaise KOUAMELAN; Jean Paul DEROIN

    2013-01-01

    The petrographic study of rocks and some few outcrops revealed the great diversity of volcano-plutonic formations. Indeed, magmatism of the Yaouré Mountains is quite differentiated, ranging from basic terms (basalts) to acidic terms (rhyolites), passing to neutral terms (rhyodacites, andesites and dacites). The study also identifies several varieties of plutonic igneous rocks, including diorites, granodiorites, gabbros and sub-volcanic (microgranites). Diorites and granodiorites are dykes or ...

  2. Intervention effects of Gotu Kola P. E on hyperlipemia mice%积雪草总苷对高脂血症小鼠的干预作用

    Institute of Scientific and Technical Information of China (English)

    陆海鹏; 李彬; 马维

    2011-01-01

    Objective To observe the intervention effects of Gotu Kola P. E. on hyperlipemia and fatty liver mice which were caused by high-fat diet. Methods The hyperlipemia and fatty liver mice were molded by continuously feeding high-fat diet, comparison with DBGT. TC, TG, HDL-C, ALT, AST and liver organization pathology were examined. Results Gotu Kola P. E. could obviously reduce TC, TG levels in liver, as well as LDL-C level in serum and ALT, AST activities in serum. Conclusion Gotu Kola P. E. could obviously improve the hyperlipemia and alleviate the fatty denaturation of mice. It is worthy of further research.%目的 观察积雪草总苷对高脂乳剂诱导的高脂血症小鼠的血脂及肝脏调节作用.方法 以高脂肪乳剂连续灌胃制作小鼠高脂血症模型,给予不同剂量的积雪草总苷予以干预,以复方蛋氨酸胆碱为阳性对照组,1周后检测小鼠血清以及肝组织匀浆TC、TG、HDL-C、ALT、AST含量以及小鼠肝脏组织病理变化,以评价积雪草总苷干预效果.结果 积雪草总苷能降低高脂血症小鼠血清以及肝脏组织匀浆中TC、TG含量(P<0.05),同时降低血清LDL-C、ALT、AST含量(P<0.05).结论 积雪草总苷能够起到调节脂质代谢、保护肝脏的作用,值得深入研究以及开发利用.

  3. Chemistry and petrology of the Apennine Front, Apollo 15. I - KREEP basalts and plutonic rocks. II - Impact melt rocks

    Science.gov (United States)

    Simon, S. B.; Papike, J. J.; Laul, J. C.

    1988-01-01

    The mineralogy, petrology, and chemistry of rock fragments for the Apennine Front coarse fines (10-4 and 4-2 mm) have been determined. The data are consistent with a single eruptive event that produced several flows. It is found that most of the plutonic rocks are ferroan in nature, with a few belonging to the Mg-suite. The mineral and bulk chemistry of KREEP basalts and the composition of ferroan anorthosites are discussed. Petrographic studies of 21 impact melts are also presented, showing a variety of textures. It is found that the Apollo 15 impact melts are mixtures of low-K Fra Mauro, KREEP, and plutonic components. The Ni/Ir ratios of the melt rocks are shown to be greater than chondritic values, indicating ancient and/or iron meteorite components.

  4. Mineralogy and geochemistry of the Late Neoproterozoic rare metal granitoids of Gabal El-Ineigi pluton, Northern Arabian-Nubian Shield, Egypt

    Science.gov (United States)

    Sami, Mabrouk; Ntaflos, Theodoros; Mohamed, Haroun A.; Farahat, Esam S.; Ahmed, Awaad F.

    2016-04-01

    Gabal El-Ineigi granitoid pluton is situated in the Central Eastern Desert of Egypt and is considered as one of the good examples of the fluorite bearing rare metal granites in the Arabian Nubian Shield (ANS). It constitutes a multiphase pluton consists of porphyritic syenogranites (SG) and coarse to medium grained highly evolved alkali-feldspar granites (AFG) intruded into the older granodiorites and metagabbro-diorite rocks. Petrographic features indicate that quartz, K-feldspar (perthite, Or97‑99), plagioclase (albite, An0‑6) and biotite are the major mineral phases of both granitic types with subordinate muscovite that is observed only in the AFG. Columbite, rutile, fluorite, zircon and thorite are the significant accessory minerals in the AFG while, allanite is exclusively encountered in the SG. Mineral chemistry study reveals that Nb-Ta-Ti-bearing oxides [columbite-group minerals (CGM)] and Nb-bearing oxides (ilmenorutile) represent the most common Nb-Ta host in the AFG. The CGM are represented mostly by complex zoned columbite-(Fe) and rarely by yttrocolumbite-(Y), with Mn/(Mn+Fe) ratios ranging from 0.17 to 0.31. Xenomorphic fluorite (F=46-51 wt%) is commonly filling the spaces between the major mineral phases and sometimes host rare metal minerals, e.g. columbite and thorite. Euhedral zoned allanite (Ce-Nd) is the common REE bearing mineral encountered in the SG. Geochemically, Gabal El-Ineigi granitoids are metaluminous (A/CNK= 0.95-0.99) related to post-collosional A2-type granites. The late phase AFG have distinctive geochemical features typical of rare-metal granites. They are highly fractionated calc-alkaline granitoids characterized by high Rb, Nb, Y, U and many HFSE contents, and extremely low Sr and Ba contents (4-35 and 13-18 ppm, respectively). Moreover, their REE patterns show pronounced negative Eu anomalies (Eu/Eu*=0.03 - 0.05) and tetrad effect (TE1,3=1.16 and 1.42), implying extensive fractionation via fluid-rock interaction that

  5. Characterizing fractured plutonic rocks of the Canadian shield for deep geological disposal of Canada's radioactive wastes

    International Nuclear Information System (INIS)

    Since 1978 AECL has been investigating plutonic rocks of the Canadian Shield as a potential medium for the disposal of Canada's nuclear fuel waste. During the last two years this study has been continued as part of Ontario Hydro's used fuel disposal program. Methods have been developed for characterizing the geotechnical conditions at the regional scale of the Canadian Shield as well as for characterizing conditions at the site scale and the very near-field scale needed for locating and designing disposal vault rooms and waste emplacement areas. The Whiteshell Research Area (WRA) and the Underground Research Laboratory (URL) in southeastern Manitoba have been extensively used to develop and demonstrate the different scales of characterization methods. At the regional scale, airborne magnetic and electromagnetic surveys combined with LANDSAT 5 and surface gravity survey data have been helpful in identifying boundaries of the plutonic rocks , overburden thicknesses, major lineaments that might be geological structures, lithological contacts and depths of the batholiths. Surface geological mapping of exposed rock outcrops, combined with surface VLF/EM, radar and seismic reflection surveys were useful in identifying the orientation and depth continuity of low-dipping fracture zones beneath rock outcrops to a depth of 500 to 1000 m. The surface time-domain EM method has provided encouraging results for identifying the depth of highly saline pore waters. The regional site scale investigations at the WRA included the drilling of twenty deep boreholes (> 500 m) at seven separate study areas. Geological core logging combined with borehole geophysical logging, TV/ATV logging, flowmeter logging and full waveform sonic logging in these boreholes helped to confirm the location of hydro geologically important fractures, orient cores and infer the relative permeability of some fracture zones. Single-hole radar and crosshole seismic tomography surveys were useful to establish the

  6. The Ajo Mining District, Pima County, Arizona--Evidence for Middle Cenozoic Detachment Faulting, Plutonism, Volcanism, and Hydrothermal Alteration

    Science.gov (United States)

    Cox, Dennis P.; Force, Eric R.; Wilkinson, William H.; More, Syver W.; Rivera, John S.; Wooden, Joseph L.

    2006-01-01

    Introduction: The Ajo porphyry copper deposit and surrounding Upper Cretaceous rocks have been separated from their plutonic source and rotated by detachment faulting. Overlying middle Cenozoic sedimentary and volcanic rocks have been tilted and show evidence for two periods of rotation. Following these rotations, a granitic stock (23.7?0.2 Ma) intruded basement rocks west of the Ajo deposit. This stock was uplifted 2.5 km to expose deep-seated Na-Ca alteration.

  7. Map showing distribution and classification of felsic plutonic rocks in the eastern Arabian Shield, Kingdom of Saudi Arabia

    Science.gov (United States)

    Du Bray, E.A.

    1983-01-01

    This 1:500,000-scale compilation shows the distribution of felsic plutonic rocks, lithologic types, and associated mineralization in an area between lat 21° and 24°30’ N., long 43°30’ and 46° E. It is part of a shieldwide compilation being done within the framework of Saudi Arabian Deputy Ministry for Mineral Resources projects 2.04 and 3.12.

  8. Mineral-scale Sr isotope variation in plutonic rocks – a tool for unraveling the evolution of magma systems.

    OpenAIRE

    Davidson, J. P.; Font, L.; Charlier, B.L.A.; Tepley, F.J. III

    2006-01-01

    Isotope ratios of elements such as Sr, Nd, Pb and Hf can be used as tracers of magmatic sources and processes. Analytical capabilities have evolved so that isotope ratios can now be analysed in situ, and isotopic tracers can therefore be used within single minerals to track the changing magmatic environment in which a given mineral grew. This contribution shows that Sr isotope ratios in feldspars that make up plutonic rocks will typically preserve initial isotopic variations, provided precise...

  9. Paleoproterozoic structural frame of the Yetti domain (Eglab shield, Algeria): Emplacement conditions of the Tinguicht late pluton from magnetic fabric study

    Science.gov (United States)

    Merabet, Nacer-eddine; Mahdjoub, Yamina; Henry, Bernard; Abtout, Abdeslam; Maouche, Said; Kahoui, Mohamed; Lamali, Atmane; Ayache, Mohamed

    2016-02-01

    The Tinguicht pluton is part of the ˜2.07 Ga post-collisional magmatic suites that intruded the Yetti Paleoproterozoic volcano-sedimentary series of the western part of the Eglab Shield (West African Craton). It represents one of the most recent units of these suites. This pluton, with a NW-SE elliptic shape, is unfoliated, and its deformational structures are practically restricted to fracturing and faulting. New structural, microstructural and aeromagnetic data are presented in order to analyze in particular the relationship between the Tinguicht pluton emplacement and the related NNW-SSE major mega-shear zone, separating the Yetti and Eglab domains. To constrain the context of the regional post-collisional evolution of the Eglab shield, a structural analysis was performed by mapping the magnetic structures (foliation and lineation) using AMS. The combination of the results of all the used approaches leads to a new and enriched image of this granitic pluton and of its tectonic emplacement context. The elliptic shape of the granitic body and the AMS strain pattern are consistent with the presence of a NNW-SSE major structure. NNW-SSE is also one of the major directions highlighted by the aeromagnetic data. This study thus evidences the role of the pre-existing major shear zones in controlling emplacement of post-collisional Paleoproterozoic plutons like Tinguicht, as shown for Drissa pluton in the Eglab domain earlier.

  10. The evolution of Neoproterozoic magmatism in Southernmost Brazil: shoshonitic, high-K tholeiitic and silica-saturated, sodic alkaline volcanism in post-collisional basins

    Directory of Open Access Journals (Sweden)

    Sommer Carlos A.

    2006-01-01

    Full Text Available The Neoproterozoic shoshonitic and mildly alkaline bimodal volcanism of Southernmost Brazil is represented by rock assemblages associated to sedimentary successions, deposited in strike-slip basins formed at the post-collisional stages of the Brasilian/Pan-African orogenic cycle. The best-preserved volcano sedimentary associations occur in the Camaquã and Campo Alegre Basins, respectively in the Sul-riograndense and Catarinense Shields and are outside the main shear belts or overlying the unaffected basement areas. These basins are characterized by alternation of volcanic cycles and siliciclastic sedimentation developed dominantly on a continental setting under subaerial conditions. This volcanism and the coeval plutonism evolved from high-K tholeiitic and calc-alkaline to shoshonitic and ended with a silica-saturated sodic alkaline magmatism, and its evolution were developed during at least 60 Ma. The compositional variation and evolution of post-collisional magmatism in southern Brazil are interpreted as the result mainly of melting of a heterogeneous mantle source, which includes garnet-phlogopite-bearing peridotites, veined-peridotites with abundant hydrated phases, such as amphibole, apatite and phlogopite, and eventually with the addition of an asthenospheric component. The subduction-related metasomatic character of post-collisional magmatism mantle sources in southern Brazil is put in evidence by Nb-negative anomalies and isotope features typical of EM1 sources.

  11. The evolution of Neoproterozoic magmatism in Southernmost Brazil: shoshonitic, high-K tholeiitic and silica-saturated, sodic alkaline volcanism in post-collisional basins.

    Science.gov (United States)

    Sommer, Carlos A; Lima, Evandro F; Nardi, Lauro V S; Liz, Joaquim D; Waichel, Breno L

    2006-09-01

    The Neoproterozoic shoshonitic and mildly alkaline bimodal volcanism of Southernmost Brazil is represented by rock assemblages associated to sedimentary successions, deposited in strike-slip basins formed at the post-collisional stages of the Brasilian/Pan-African orogenic cycle. The best-preserved volcano sedimentary associations occur in the Camaquã and Campo Alegre Basins, respectively in the Sul-riograndense and Catarinense Shields and are outside the main shear belts or overlying the unaffected basement areas. These basins are characterized by alternation of volcanic cycles and siliciclastic sedimentation developed dominantly on a continental setting under subaerial conditions. This volcanism and the coeval plutonism evolved from high-K tholeiitic and calc-alkaline to shoshonitic and ended with a silica-saturated sodic alkaline magmatism, and its evolution were developed during at least 60 Ma. The compositional variation and evolution of post-collisional magmatism in southern Brazil are interpreted as the result mainly of melting of a heterogeneous mantle source, which includes garnet-phlogopite-bearing peridotites, veined-peridotites with abundant hydrated phases, such as amphibole, apatite and phlogopite, and eventually with the addition of an asthenospheric component. The subduction-related metasomatic character of post-collisional magmatism mantle sources in southern Brazil is put in evidence by Nb-negative anomalies and isotope features typical of EM1 sources. PMID:16936944

  12. Evaluation of the dust and methanol extracts of Garcinia kolae for the control of Callosobruchus maculatus (F.) and Sitophilus zeamais (Mots)

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Insecticidal effects of different doses of the dust and methanol extracts ofGarcinia kolae on Callosobruchus maculatus and Sitophilus zeamais were tested. The dust had no significant effect on the two insects; none of them died even at 3 d after treatment. The methanol extracts, however, had rapid lethal effects on both C. maculatus and S. zeamais. The mortality of C.maculatus by the lowest concentration of methanol extracts ranged from 95%~100% whereas in S. zeamais, the mortality ranged from 87.5%~100% and 70% ~100% in concentrations of 1 g extract+3 ml methanol and 1 g extract+5 ml methanol, respectively,from 24 to 48 h. The least concentration of 1 g extract+15 ml methanol had no significant lethal effect on Sitophilus zeamais.

  13. Verification of the transuranus-WWER code version V1M2J00 by SOFIT and Kola-3 data bases: Part 1

    International Nuclear Information System (INIS)

    The object of this study is standard WWER-440 fuel as described in the IFPE-OECD/IAEA-NEA database. The SOFIT and Kola-3 data base have been used the purpose, each one described in a separate paper, referred to as Part I and Part II. It has been shown that the latest modifications of the programme lead to considerable improvements of the predictions on the fuel behaviour. The calculations, made by the latest TRANSURANUS-WWER version V1M2J00, lead to the following conclusions: the fuel central temperature is reproduced very well by the code, especially in the beginning of life; the experimental value for fission gas releases in rod 12 of SOFIT-1.1 is reproduced fairly well by the standard WWER correlations; the fuel and cladding extension is reproduced excellently by the code for rod 1 and rod 3

  14. Formation of lower continental crust by relamination of buoyant arc lavas and plutons

    Science.gov (United States)

    Kelemen, Peter B.; Behn, Mark D.

    2016-03-01

    The formation of the Earth's continents is enigmatic. Volcanic arc magmas generated above subduction zones have geochemical compositions that are similar to continental crust, implying that arc magmatic processes played a central role in generating continental crust. Yet the deep crust within volcanic arcs has a very different composition from crust at similar depths beneath the continents. It is therefore unclear how arc crust is transformed into continental crust. The densest parts of arc lower crust may delaminate and become recycled into the underlying mantle. Here we show, however, that even after delamination, arc lower crust still has significantly different trace element contents from continental lower crust. We suggest that it is not delamination that determines the composition of continental crust, but relamination. In our conceptual model, buoyant magmatic rocks generated at arcs are subducted. Then, upon heating at depth, they ascend and are relaminated at the base of the overlying crust. A review of the average compositions of buoyant magmatic rocks -- lavas and plutons -- sampled from the Aleutians, Izu-Bonin-Marianas, Kohistan and Talkeetna arcs reveals that they fall within the range of estimated major and trace elements in lower continental crust. Relamination may thus provide an efficient process for generating lower continental crust.

  15. Metamorphism and plutonism in the Quetico Belt, Superior Province, N.W. Ontario

    Science.gov (United States)

    Percival, J. A.

    1986-01-01

    The Quetico Belt lies between the metavolcanic Wawa-Shebandowan and Wabigoon Belts. It consists of marginal metasedimentary rocks and central pelitic, gneissic and plutonic rocks. Metamorphism is Barrovian, at depths less than 10 km, and grade increases from margins to core of the belt: the outermost pelites are at chlorite-muscovite grade; inward a garnet-andalusite zone formed throughout the inner margin; and the central zone ranges form garnet-andalusite in the west and garnet-sillimanite-muscovite to garnet-sillimanite-cordierite and rare kyanite 6 to 150 km to the east. This increase is correlated with granitic intrusives. Migmatites in the core have intrusive leucosomes in the west and locally derived ones in the east. Isograd surfaces are steep where the belt is narrow and dip gently where it is wide. The Quetico Park intrusive complex of the central region of the Quetico Belt shows a zonation across it 20 to 50 km width from older, medium grained biotite composition to younger, coarse to pegmatitic granitic composition. Sediment of the Quetico basin had its source in the bordering metavolcanic belts and was deposited ca. 2.75 to 2.70 Ga ago. Boundaries of the belt dip inward, so it essentially is a graben of inter-arc or back-arc type.

  16. Fission Track Geochronology of Xiaonanchuan Pluton and the Morphotectonic Evolution of Eastern Kunlun since Late Miocene

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Apatite fission track (AFT) thermochronology of seven samples from the Xiaonanchuan(小南川) pluton in the Kunlun (昆仑) pass area was carried out, for the purpose of determining the timing of cooling and the relation between the exhumation and the morphotectonic processes. The AFT ages yield low denudation rates of 0.020-0.035 mm/ a during the late Miocene, which correspond to a stable geomorphic and weak tectonic uplifting environment. The low denudation rates can be considered as the approximate tectonic uplifting rates. The AFT geochronology shows paroxysmally rapid cooling since the Pliocene and an apparent material unroofing of more than 3 km in the Xiaonanchuan area. This was not the result of simple denudation. The rapid cooling was coupled with the intensive orogeny since the Pliocene, which was driven by tectonic uplifting. The accelerated relief building was accompanied by a series of faulting, which caused the basin and the valley formation and sinking. The space pattern of the AFT ages also shows differential uplifting, which decreases northwardly. This trend is supported by the regional AFT data, which indicate that the exhumation decreases northwardly in eastern Kunlun. This trend also exists in east-west orientation from the western Kunlun range to the eastern. The uplifting trend is also supported by geomorphic characteristics including the elevation and the relief differences as well as the distribution of the Late Cenozoic volcanism.

  17. Distribution of manganese between coexisting biotite and hornblende in plutonic rocks

    Science.gov (United States)

    Greenland, L.P.; Gottfried, D.; Tilling, R.I.

    1968-01-01

    The distribution of manganese between coexisting biotite and hornblende for 80 mineral pairs from igneous rocks of diverse provenance (including Southern California, Sierra Nevada, Boulder, and Boulder Creek batholiths and the Jemez Mountains volcanics) has been determined by neutron activation analysis. Data on the distribution ratio (Kd = Mnhornblende Mnbiotite) indicate that an equilibrium distribution of Mn is closely approached, though not completely attained, in most samples from plutonic environments. Comparison of Kd values of mineral pairs with bulk chemical composition of host rocks reveals no correlation. Because initial crystallization temperatures vary with rock composition, the lack of correlation of composition with Kd suggests that the equilibrium distribution of Mn between biotite and hornblende reflects exchange at subsolidus temperatures rather than initial crystallization temperatures. The highest Kd values are for volcanic rocks, in which rapid quenching prevents subsolidus redistribution of Mn. For sample pairs from the Southern California and Sierra Nevada batholiths there is a positive correlation of Kd with TiO2 content of biotite. Though the evidence is not compelling, Kd may also correlate with the rate of cooling and/or the presence or absence of sphene in the rock. ?? 1968.

  18. Natural radionuclides in the rocks of the Valle del Cervo Pluton in Piedmont

    International Nuclear Information System (INIS)

    Monitoring of the gamma radiation in Valle del Cervo Pluton was performed by determining U and Th contents in the main rock types cropping out over the entire area and pertaining to the granitic complex, syenitic complex and monzonitic complex. In particular, syenitic rocks were largely used as building and ornamental materials (e.g. Sienite della Balma). All the samples are fresh and do not present joints or fractures filled with U minerals. In the crushed samples the activity of uranium varies from 346 to 764 Bq/kg. Concentration of thorium varies from 202 to 478 Bq/kg. For all the analysed rocks uranium activity is higher than thorium one. The lowest value of radioactive concentration is referred to rocks of the granitic complex. The most active rocks are syenites. The data confirm the high activities of Valle del Cervo rock types, strongly connected with high K content of the source magma (geochemical signature); on the contrary, the activity seems to be not related to the location of the samples. (authors)

  19. The intrusive complexof the Island of Giglio: geomagnetic characteristics of plutonic facies with low susceptibility contrast

    Directory of Open Access Journals (Sweden)

    R. Cavallini

    1998-06-01

    Full Text Available Two main plutonic facies characterize the intrusive complex of the Island of Giglio, and the trend of their contact at depth has been modelled using a 2D½ analysis based on a detailed geomagnetic survey in order to verify the geological hypothesis of the subsurface geometry of this contact. The magnetic anomaly connected with the discontinuity is quite low, due to the small difference between the magnetic susceptibilities of the two granitic facies. Development of this model of inversion of the magnetic field, which is in good agreement with the geological interpretation, was made possible by: 1 accurate control of the geomagnetic time variations and consequent temporal reduction, 2 a very low level of the artificial magnetic noise, 3 high density of the magnetic survey, 4 detailed knowledge of the mapped geologic contact between facies and of their petrologic characteristics, and 5 direct local measurements of the magnetic susceptibilities of the key lithologies. The model shows the trends of the geological contact, as projected in three E-W sections, that dips eastward in the range between 210 and 540, supporting the geologic hypothesis that the Pietrabona facies represents an external shell of the shallowly emplaced Giglio monzogranite intrusion.

  20. Specific Examples of Hybrid Alkaline Cement

    OpenAIRE

    Fernández-Jiménez Ana; García-Lodeiro Inés; Donatello Shane; Maltseva Olga; Palomo Ángel

    2014-01-01

    Hybrid alkaline cements are obtained by alkali-activating cementitious blends in the Na2O-CaO-SiO2-Al2O3-H2O system. The present paper discusses the results of activating different cementitious blends containing a low OPC clinker content ( 15MPa a 2 days) different alkaline activators were used (liquid and solid). The reaction products obtained were also characterised by XRD, SEM/EDX and 27Al and 29Si NMRMAS. The results showed that the main reaction product was a mix of cementitious gels C-A...

  1. Alkaline earth filled nickel skutterudite antimonide thermoelectrics

    Science.gov (United States)

    Singh, David Joseph

    2013-07-16

    A thermoelectric material including a body centered cubic filled skutterudite having the formula A.sub.xFe.sub.yNi.sub.zSb.sub.12, where A is an alkaline earth element, x is no more than approximately 1.0, and the sum of y and z is approximately equal to 4.0. The alkaline earth element includes guest atoms selected from the group consisting of Be, Mb, Ca, Sr, Ba, Ra and combinations thereof. The filled skutterudite is shown to have properties suitable for a wide variety of thermoelectric applications.

  2. Alkaline Capacitors Based on Nitride Nanoparticles

    Science.gov (United States)

    Aldissi, Matt

    2003-01-01

    High-energy-density alkaline electrochemical capacitors based on electrodes made of transition-metal nitride nanoparticles are undergoing development. Transition- metal nitrides (in particular, Fe3N and TiN) offer a desirable combination of high electrical conductivity and electrochemical stability in aqueous alkaline electrolytes like KOH. The high energy densities of these capacitors are attributable mainly to their high capacitance densities, which, in turn, are attributable mainly to the large specific surface areas of the electrode nanoparticles. Capacitors of this type could be useful as energy-storage components in such diverse equipment as digital communication systems, implanted medical devices, computers, portable consumer electronic devices, and electric vehicles.

  3. Electrochemical behaviour of alkaline copper complexes

    Indian Academy of Sciences (India)

    C L Aravinda; S M Mayanna; V R Muralidharan

    2000-10-01

    A search for non-cyanide plating baths for copper resulted in the development of alkaline copper complex baths containing trisodium citrate [TSC] and triethanolamine [TEA]. Voltammetric studies were carried out on platinum to understand the electrochemical behaviour of these complexes. In TSC solutions, the deposition of copper involves the slow formation of a monovalent species. Adsorption of this species obeys Langmuir isotherm. In TEA solutions the deposition involves the formation of monovalent ions obeying the non-activated Temkin isotherm. Conversion of divalent to monovalent copper is also slow. In TEA and TSC alkaline copper solutions, the predominant species that undergo stepwise reduction contain only TEA ligands

  4. The Alkaline Diet: Is There Evidence That an Alkaline pH Diet Benefits Health?

    Directory of Open Access Journals (Sweden)

    Gerry K. Schwalfenberg

    2012-01-01

    Full Text Available This review looks at the role of an alkaline diet in health. Pubmed was searched looking for articles on pH, potential renal acid loads, bone health, muscle, growth hormone, back pain, vitamin D and chemotherapy. Many books written in the lay literature on the alkaline diet were also reviewed and evaluated in light of the published medical literature. There may be some value in considering an alkaline diet in reducing morbidity and mortality from chronic diseases and further studies are warranted in this area of medicine.

  5. The Alkaline Diet: Is There Evidence That an Alkaline ph Diet Benefits Health?

    International Nuclear Information System (INIS)

    This review looks at the role of an alkaline diet in health. Pub med was searched looking for articles on ph, potential renal acid loads, bone health, muscle, growth hormone, back pain, vitamin D and chemotherapy. Many books written in the lay literature on the alkaline diet were also reviewed and evaluated in light of the published medical literature. There may be some value in considering an alkaline diet in reducing morbidity and mortality from chronic diseases and further studies are warranted in this area of medicine

  6. Potentiometric assay for acid and alkaline phosphatase

    International Nuclear Information System (INIS)

    Simple potentiometric kinetic assay for evaluation of acid and alkaline phosphatase activity has been developed. Enzymatically catalyzed hydrolysis of monofluorophosphate, the simplest inorganic compound containing P-F bond, has been investigated as the basis of the assays. Fluoride ions formed in the course of the hydrolysis of this specific substrate have been detected using conventional fluoride ion-selective electrode based on membrane made of lanthanum fluoride. The key analytical parameters necessary for sensitive and selective detection of both enzymes have been assessed. Maximal sensitivity of the assays was observed at monofluorophosphate concentration near 10-3 M. Maximal sensitivity of acid phosphatase assay was found at pH 6.0, but pH of 4.8 is recommended to eliminate effects from alkaline phosphatase. Optimal pH for alkaline phosphatase assay is 9.0. The utility of the developed substrate-sensor system for determination of acid and alkaline phosphatase activity in human serum has been demonstrated

  7. Persistently increased intestinal fraction of alkaline phosphatase

    DEFF Research Database (Denmark)

    Nathan, E; Baatrup, G; Berg, H;

    1984-01-01

    Persistent elevation of the intestinal fraction of the alkaline phosphatase (API) as an isolated finding has to our knowledge not been reported previously. It was found in a boy followed during a period of 5.5 years. The only symptom was transient periodic fatigue observed at home, but not apparent...

  8. Growth of a Large Composite Magma System: the EJB Pluton, Eastern California.

    Science.gov (United States)

    Matty, D. J.; Vervoort, J.; Dufrane, A.; Hart, G.; Student, J.; Morgan, S.

    2008-12-01

    The composite EJB pluton crops out in the White-Inyo Mountains of eastern California, and comprises the Eureka Valley monzonite (EVM), the Joshua Flat quartz monzonite (JFQM), the Beer Creek granite (BCG), and an unnamed diorite. While sometimes equivocal, field relationships suggest that the EVM was emplaced first, followed by the JFQM, and finally the BCG; the diorite predates the BCG. Sylvester and others (GSAB, 1978) reported zircon U-Pb ages of 179±2 Ma for the EVM and 174±5 Ma for the JFQM. Coleman and others (GSAB, 2003) determined a U-Pb age of 179±3 Ma (via Pb-loss trajectory) for the BCG. Because of the uncertainty in the ages and ambiguous field relations, the sequence and duration of EJB magmatism remain unclear. To understand more fully the timing of EJB magmatism, we separated zircons from 12 samples collected from each of the main EJB units. These samples were characterized using light microscopy, SEM and CL techniques. U-Pb ages were determined from individual zircons by LA-ICP-MS following the method of Chang and others (G3, 2006). For the ages reported below, the reported uncertainties are based on factors within the analysis, but do not include external factors such as sample/standard bias or other matrix effects. Overall uncertainty in LA-ICPMS U-Pb geochronology is hard to assess, but we estimate that all ages reported below are subject to a minimum 2% uncertainty. We determined a concordant U-Pb age of 180±2 Ma for the EVM, which agrees with the results of Sylvester and others (1978). The unnamed diorite produced a concordant U-Pb age of 177±3 Ma. Concordant U-Pb ages of 172±2, 172±3, 173±2, 174±2, and 175±2 Ma were determined for individual samples of the JFQM and agree with the age reported by Sylvester and others (1978) of 174±5 Ma. Concordant U-Pb ages of 168±4, 168±3, 169±1, 172±2, and 172±2 Ma were determined for individual BCG samples. Within the reported error, there is no difference in age between individual samples of

  9. Death Valley turtlebacks: Mesozoic contractional structures overprinted by Cenozoic extension and metamorphism beneath syn-extensional plutons

    International Nuclear Information System (INIS)

    The term turtleback was first coined to describe the curvilinear fault surfaces that produced a distinctive geomorphic form in the Black Mountains east of Death Valley, and although it was decades before their full significance was appreciated, they remain one of the most distinctive features of the extensional structure of the Death Valley region. Historically the interpretation of the features has varied markedly, and misconceptions about their character continue to abound, including descriptions in popular field guides for the area. It the 1990's, however, the full history of the systems began to be apparent from several key data: 1) the dating of the plutonic assemblage associated with the turtlebacks demonstrated that late Miocene, syn-extensional plutonism was fundamental to their formation; 2) the plutonic assemblage forms an intrusive sheet structurally above the turtlebacks, indicating a tie between much of the high grade metamorphism and Cenozoic plutonism; 3) a modern analog for the syn-extensional plutonism in the Black Mountains was recognized beneath Death Valley with the imaging of a mid-crustal magma body; 4) the Neogene structural history was worked out in the turtlebacks showing that folding of early-formed shear zones formed the turtleback anticlinoria but overprinting by brittle faults produced the final form as they cut obliquely across the older structure; and 5) the pre-extensional structural history was clarified, demonstrating that Mesozoic basement-involved thrust systems are present within the turtlebacks, but have been overprinted by the extensional system. An unresolved issue is the significance of Eocene U-Pb dates for pegmatites within the region, but presumably these relate somehow to the pre-extensional history. Miller and Pavlis (2005; E. Sci. Rev.) reviewed many features of the turtlebacks, and our working model for the region is that the turtlebacks originated as mid-crustal ductile-thrust systems within the Cordilleran fold

  10. Improved electrodes and gas impurity investigations on alkaline electrolysers

    DEFF Research Database (Denmark)

    Reissner, R.; Schiller, G.; Knoeri, T.;

    Alkaline water electrolysis for hydrogenproduction is a well-established techniquebut some technological issues regarding thecoupling of alkaline water electrolysis andRenewable Energy Sources (RES) remain tobe improved....

  11. Alkaline magmatism in the eastern of Paraguay.Generals characteristics

    International Nuclear Information System (INIS)

    This paper deals with the distribution of alkaline occurrences in Paraguayan territory and their assemblage into different provinces. Also draws the attention to the petrographic and geochemical characteristics showed by the alkaline rock-types. (author)

  12. Indoor radon related to uranium in granitoids of the Central Bohemian plutonic complex

    International Nuclear Information System (INIS)

    The study is based on the indoor radon data (one year measurements, Kodak LR 115 track etch detectors), vectorized geological maps 1:50000, vectorized coordinates of dwellings and uranium data for granitoid types of the Central Bohemian Plutonic Complex (CBPC). Using ArcGis 8.2 programme, the position of 16145 dwellings was linked to a geological database covering the CBPC (approx. 3200 km2), and the type of underlying rock type was specified for each house. The resulting databases enabled us to calculate the mean EEC indoor Rn data for particular granitoid types and to study the relationship between the indoor Rn and the U concentrations. The petrogenetically variable CBPC was emplaced during Variscan orogenesis (330-350 Ma) and is among the most radioactive rock types within the Bohemian Massif. A long-term process of CBPC genesis resulted in more than 20 granitoid types, differing by their petrogenetic characteristics as well as mineralogical and chemical composition, including uranium concentration. The relation between the mean indoor radon values and uranium concentrations in particular rock types was examined. A positive regression between indoor Rn and uranium as the source of Rn soil gas clearly demonstrates how regional geology influences the indoor radon activity concentration in dwellings. The highest indoor Rn concentrations were observed in the Sedlcany granodiorite and Certovo bremeno syenite, where also the highest gamma dose rates (150-210 nGy.h-1) within all granitoid types in the Czech Republic were observed. The two rock types differ from other granitoids by a relatively high zircon concentration, which is the main source of U and subsequently of soil gas Rn being released from the bedrock. The lower indoor Rn values of Certovo bremeno syenite which do not correspond with the high U concentrations can be explained by a relatively low permeability of its clayey weathering crust. This feature was also observed for soil gas radon concentration

  13. Geologic and hydrologic controls on the economic potential of hydrothermal systems associated with upper crustal plutons

    Science.gov (United States)

    Weis, Philipp; Driesner, Thomas; Scott, Samuel; Lecumberri-Sanchez, Pilar

    2016-04-01

    Heat and mass transport in hydrothermal systems associated with upper crustal magmatic intrusions can result in resources with large economic potential (Kesler, 1994). Active hydrothermal systems can form high-enthalpy geothermal reservoirs with the possibility for renewable energy production. Fossil continental or submarine hydrothermal systems may have formed ore deposits at variable crustal depths, which can be mined near today's surface with an economic profit. In both cases, only the right combination of first-order geologic and hydrologic controls may lead to the formation of a significant resource. To foster exploration for these hydrothermal georesources, we need to improve our understanding of subsurface fluxes of mass and energy by combining numerical process modelling, observations at both active and fossil systems, as well as knowledge of fluid and rock properties and their interactions in natural systems. The presentation will highlight the role of non-linear fluid properties, phase separation, salt precipitation, fluid mixing, permeability structure, hydraulic fracturing and the transition from brittle to ductile rock behavior as major geologic and hydrologic controls on the formation of high-enthalpy and supercritical geothermal resources (Scott et al., 2015), and magmatic-hydrothermal mineral resources, such as porphyry copper, massive sulfide and epithermal gold deposits (Lecumberri-Sanchez et al., 2015; Weis, 2015). References: Kesler, S. E., 1994: Mineral Resources, economics and the environment, New York, McMillan, 391. Lecumberri-Sanchez, P., Steele-MacInnis, M., Weis, P., Driesner, T., Bodnar, R.J. (2015): Salt precipitation in magmatic-hydrothermal systems associated with upper crustal plutons. Geology, v. 43, p. 1063-1066, doi:10.1130/G37163.1 Scott, S., Driesner, T., Weis, P. (2015): Geologic controls on supercritical geothermal resources above magmatic intrusions. Nature Communications, 6:7837 doi: 10.1038/ncomms8837 Weis, P. (2015): The

  14. Chemically treated kola nut pod as low-cost natural adsorbent for the removal of 2,4-dinitrophenol from synthetic wastewater: batch equilibrium, kinetic, and thermodynamic modelling studies

    OpenAIRE

    AGARRY, Samuel; OGUNLEYE, Oladipupo

    2014-01-01

    The feasibility of using chemically treated kola nut pod to remove 2,4-dinitrophenol from its aqueous solutions under batch mode was investigated. The results showed that biosorption of 2,4-dinitrophenol was dependent on initial concentration, contact time, pH, biosorbent particle size, biosorbent dosage, and temperature. The batch equilibrium biosorption data were analyzed by 2 two-parameter (Langmuir and Freundlich) and 2 three-parameter (Redlich--Peterson and Sips) adsorption isother...

  15. Pojetí počátečního čtení a psaní v učebnicích nakladatelství Nová škola, Didaktis a Fraus

    OpenAIRE

    HOFFMANNOVÁ, Lenka

    2010-01-01

    This diploma thesis deals with the comparison of conception of very beginning reading and writing in the textbooks of three chosen publishers (Nová škola, Didaktis, Fraus). It is divided into theoretical and comparative part. In the theoretical part the authoress closely analyses the present condition and the development of elementary reading and writing in before syllabary period, syllabary period and after syllabary period. The comparative part is concentrated on the comparison of methodica...

  16. Geochemistry, zircon U-Pb ages and Sr-Nd-Hf isotopes of an Ordovician appinitic pluton in the East Kunlun orogen: New evidence for Proto-Tethyan subduction

    Science.gov (United States)

    Xiong, Fuhao; Ma, Changqian; Wu, Liang; Jiang, Hong'an; Liu, Bin

    2015-11-01

    Appinite is commonly derived from a mantle source in subduction zones and thus holds a key to constrain the tectonic evolution of ancient orogens. This study presents chronological, mineralogical and geochemical data for one appinitic pluton from the south Tethyan suture zone in the East Kunlun orogen, Northern Tibetan Plateau. The pluton is predominantly composed of hornblende-rich mafic appinites, with minor amounts of granodiorite. Zircon U-Pb age of the granodiorite (466 Ma) is identical to the mafic appinites (447-450 Ma). The mafic appinites are commonly hornblende diorites, which comprise large amounts of magnesio-hornblende [Mg/(Fe + Mg) = 0.61-0.68] and andesine (An43-54). The hornblende diorites have low contents of SiO2 (48.62-54.95 wt.%), high contents of total FeO (7.90-12.84 wt.%) and MgO (4.32-11.89 wt.%) and moderate values of Mg# [Mg# = molar 100 ∗ Mg/(Mg + Fe); 49-69]. Their geochemistry displays: slight enrichment of light rare earth elements ((La/Yb)N = 1.89-6.84) and flat heavy rare earth elements ((Ga/Yb)N = 1.49-2.22); enrichment in large ion lithophile elements and depletion in high field strength elements; less-enriched isotopic compositions with initial 87Sr/86Sr ratios of 0.70536-0.70617, εNd(t) of 0.79-3.02 and zircon εHf(t) of 8.73-12.82. The associated granodiorites comprise plagioclase (45-50 vol.%, An = 26-39), quartz (15-20 vol.%), K-feldspar (5-10 vol.%), ferrohornblende [2-5 vol.%, (Mg/(Fe + Mg) = 0.45-0.49] and epidote (1-5 vol.%). The epidotes have pistacite components ranging from 23 to 28. The granodiorites exhibit calc-alkaline character, and have rare earth and trace element patterns similar to the hornblende diorites. The geochemical compositions and simulations suggest that the parental magma of the mafic appinites was generated by partial melting of one depleted mantle source which was metasomatised by subducted sediment-derived felsic melts (ca. 20-25%). Fractional crystallization of clinopyroxene, hornblende

  17. Structural characterization of the Misajé granitic pluton (NW Cameroon): constraints from magnetic and field observations

    Science.gov (United States)

    Fozing, Eric Martial; Njanko, Théophile; Naba, Séta; Kwékam, Maurice; Njonfang, Emmanuel; Rochette, Pierre

    2015-12-01

    The Misajé granitic pluton, emplaced between 569 and 560 Ma in an amphibolitic and gneissic host rock, comprises four petrographic units namely biotite-hornblende granite (BHG), granodiorite (Gd), biotite granite (BG), and leucocratic granite (LG). Four major tectonic events have been described in the studied area: a D1-early tectonic event, responsible of the E-W flat foliation which has been progressively transposed by a D2 tectonic event. A D2 event has developed heterogeneous simple shear in a dextral transpressive context with moderate to strong dipping NE-SW striking foliation; a D3 tectonic event has lead to a sinistral N-S ductile shear characterized by N- to ENE-striking foliation and E-W strike-slip shear corridors and a D4 tectonic event that developed N-S dextral ductile strike-slip deformation. The magnetic study of the pluton, based on the AMS parameters, reveals the coexistence of both paramagnetic (dominated by iron-bearing silicates; 54 % of sites) and ferromagnetic (due to the occurrence of PSD and MD grains of magnetite or other ferromagnetic minerals; 46 % of sites) behaviors. Magnetic foliation shows best poles at 55/82 for the whole pluton, 95/32 in BHG, and 273/83 in BG, and the magnetic lineation trends are mostly NNE-SSW with best lines at 210/8, 198/19, and 36/3, respectively. The trend of the magnetic lineation in BG indicates an S-shape trajectory, suggesting a sinistral sense of shear motion along discrete E-W corridors situated at the northern and southern ends. Kinematic indicators in BG point to a sinistral sense of shear, suggesting its emplacement during the D3 event. The close relationship between K 1 and K 3 points to a syn-kinematic emplacement and crystallization of the Misajé granitic pluton during the Pan-African event, and the tectonic evolution of the study area is considered to be coeval with the tectonic evolution of the trans-Saharan Pan-African belt of eastern Nigeria.

  18. The use of borehole geophysical logs and hydrologic tests to characterize plutonic rock for nuclear fuel waste disposal

    International Nuclear Information System (INIS)

    The selection of an igneous rock body for the disposal of nuclear fuel waste will likely require the drilling and testing of a number of deep investigative boreholes in the rock body. Although coring of at least one hole at each Research Area will be essential, methods for making in situ geophysical and hydrological measurements can substitute for widespread coring and result in significant savings in time and money. A number of borehole methods have been applied to the investigation of plutonic rocks at Whiteshell Nuclear Research Establishment and Chalk River Nuclear Laboratories in Canada

  19. Petrogenesis of the Kösedağ Pluton, Suşehri-NE Sivas, East-Central Pontides, Turkey

    OpenAIRE

    BOZTUĞ, DURMUŞ

    2008-01-01

    The Kösedağ syenite crops out as a shallow-seated pluton within the Eocene volcano-sedimentary rocks and is unconformably overlain by Lower Miocene limestones in the Suşehri-NE Sivas region, east-central Pontides. It consists of syenites and quartz syenites with a phaneritic, porphyritic texture characterized by K-feldspar megacrysts set in a coarse- to medium-grained groundmass comprising K-feldspar, plagioclase, clinopyroxene, amphibole, biotite and quartz. Major element geochemistry data r...

  20. Specific Examples of Hybrid Alkaline Cement

    Directory of Open Access Journals (Sweden)

    Fernández-Jiménez Ana

    2014-04-01

    Full Text Available Hybrid alkaline cements are obtained by alkali-activating cementitious blends in the Na2O-CaO-SiO2-Al2O3-H2O system. The present paper discusses the results of activating different cementitious blends containing a low OPC clinker content ( 15MPa a 2 days different alkaline activators were used (liquid and solid. The reaction products obtained were also characterised by XRD, SEM/EDX and 27Al and 29Si NMRMAS. The results showed that the main reaction product was a mix of cementitious gels C-A-S-H and (N,C-A-S-H, and that their relative proportions were strongly influenced by the calcium content in the initial binder

  1. Study of niobium corrosion in alkaline medium

    International Nuclear Information System (INIS)

    A comparative study of niobium electrochemical behaviour in NaOH and KOH solution, with concentrations between 0,5 and 6,1M is presented. The studies were done through electrochemicals assays, consisting in the corrosion potential and anodic and cathodic polarization curves, complemented by loss of mass experiments. The niobium anodic behaviour in alkaline medium is characterized by passivation occurrence, with a stable film formation. The Na oH solution in alkaline medium are more corrosible to niobium than the KOH solution. The loss of mass assays showed that the corrosion velocit is more dependente of hydroxide concentration in KOH medium than the NaOH medium. (C.G.C.)

  2. High temperature and pressure alkaline electrolysis

    DEFF Research Database (Denmark)

    Allebrod, Frank; Chatzichristodoulou, Christodoulos; Mogensen, Mogens Bjerg

    2013-01-01

    Alkaline electrolyzers have proven to operate reliable for decades on a large scale, but in order to become commercially attractive and compete against conventional technologies for hydrogen production, the production and investment costs have to be reduced. This may occur by increasing the...... operational temperature and pressure to produce pressurized hydrogen at high rate (m3 H2·h-1·m-2 cell area) and high electrical efficiency. This work describes an exploratory technical study of the possibility to produce hydrogen and oxygen with a new type of alkaline electrolysis cell at high temperatures...... SrTiO3 was used for immobilization of aqueous KOH solutions. Electrolysis cells with this electrolyte and metal foam based gas diffusion electrodes were successfully demonstrated at temperatures up to 250 °C at 40 bar. Different electro-catalysts were tested in order to reduce the oxygen and hydrogen...

  3. High Temperature and Pressure Alkaline Electrolysis

    DEFF Research Database (Denmark)

    Allebrod, Frank

    radiation raises the necessity to store the produced energy. Hydrogen production by water electrolysis is one of the most promising ways to do so. Alkaline electrolyzers have proven to operate reliable for decades on a large scale (up to 160 MW), but in order to become commercially attractive and compete...... and oxygen with a new type of alkaline electrolysis cell at high temperatures and pressures. To perform measurements under high pressure and at elevated temperatures it was necessary to build a measurement system around an autoclave which could stand high temperatures up to 250 °C and pressures up to...... 200 bar as well as extremely caustic environments. Based on a literature study to identify resistant materials for these conditions, Inconel 600 was selected among the metals which are available for autoclave construction. An initial single atmosphere high temperature and pressure measurement setup...

  4. CARINA alkalinity data in the Atlantic Ocean

    Directory of Open Access Journals (Sweden)

    A. Velo

    2009-08-01

    Full Text Available Data on carbon and carbon-relevant hydrographic and hydrochemical parameters from previously non-publicly available cruise data sets in the Arctic, Atlantic and Southern Ocean have been retrieved and merged to a new database: CARINA (CARbon IN the Atlantic.

    These data have gone through rigorous quality control (QC procedures to assure the highest possible quality and consistency. The data for most of the measured parameters in the CARINA data base were objectively examined in order to quantify systematic differences in the reported values, i.e. secondary quality control. Systematic biases found in the data have been corrected in the data products, i.e. three merged data files with measured, calculated and interpolated data for each of the three CARINA regions; Arctic, Atlantic and Southern Ocean. Out of a total of 188 cruise entries in the CARINA database, 98 were conducted in the Atlantic Ocean and of these, 75 cruises report alkalinity values.

    Here we present details of the secondary QC on alkalinity for the Atlantic Ocean part of CARINA. Procedures of quality control, including crossover analysis between cruises and inversion analysis of all crossover data are briefly described. Adjustments were applied to the alkalinity values for 16 of the cruises in the Atlantic Ocean region. With these adjustments the CARINA database is consistent both internally as well as with GLODAP data, an oceanographic data set based on the World Hydrographic Program in the 1990s. Based on our analysis we estimate the internal accuracy of the CARINA-ATL alkalinity data to be 3.3 μmol kg−1. The CARINA data are now suitable for accurate assessments of, for example, oceanic carbon inventories and uptake rates and for model validation.

  5. Alkaline leaching of iron and steelmaking dust

    OpenAIRE

    Stafanova, Anna; Aromaa, Jari

    2012-01-01

    Steel production generates significant quantities of dust and sludge in blast furnaces (BF),basic oxygen furnaces (BOF), and electric arc furnaces (EAF). These dusts contain toxicelements, such as heavy metals, and are thus classified as harmful waste making the disposalof them expensive. In addition, direct recycling of dust back to steel production is hindered dueto the presence of zinc. In this literature survey the alkaline leaching of zinc from iron and steelmaking dusts isreviewed. T...

  6. Alkaline earth cation extraction from acid solution

    Science.gov (United States)

    Dietz, Mark; Horwitz, E. Philip

    2003-01-01

    An extractant medium for extracting alkaline earth cations from an aqueous acidic sample solution is described as are a method and apparatus for using the same. The separation medium is free of diluent, free-flowing and particulate, and comprises a Crown ether that is a 4,4'(5')[C.sub.4 -C.sub.8 -alkylcyclohexano]18-Crown-6 dispersed on an inert substrate material.

  7. Bifunctional Catalysts for Alkaline Fuel Cells

    Czech Academy of Sciences Publication Activity Database

    Klápště, Břetislav; Vondrák, Jiří; Velická, Jana

    Vol. 1. Brno : Akademické nakladatelství CERM, 2000 - (Vondrák, J.; Sedlaříková, M.), s. 24.1-24.4 ISBN 80-214-1614-9. [Advanced Batteries and Accumulators /1./. Brno (CZ), 28.08.2000-01.09.2000] R&D Projects: GA MŠk ME 216 Institutional research plan: CEZ:AV0Z4032918; CEZ:MSM 262200010 Keywords : alkaline * catalysts * electrochemistry Subject RIV: CG - Electrochemistry

  8. Heavy water production by alkaline water electrolysis

    International Nuclear Information System (INIS)

    Several heavy water isotope production processes are reported in literature. Water electrolysis in combination with catalytic exchange CECE process is considered as a futuristic process to increase the throughput and reduce the cryogenic distillation load but the application is limited due to the high cost of electricity. Any improvement in the efficiency of electrolyzers would make this process more attractive. The efficiency of alkaline water electrolysis is governed by various phenomena such as activation polarization, ohmic polarization and concentration polarization in the cell. A systematic study on the effect of these factors can lead to methods for improving the efficiency of the electrolyzer. A bipolar and compact type arrangement of the alkaline water electrolyzer leads to increased efficiency and reduced inventory in comparison to uni-polar tank type electrolyzers. The bipolar type arrangement is formed when a number of single cells are stacked together. Although a few experimental studies have been reported in the open literature, CFD simulation of a bipolar compact alkaline water electrolyzer with porous electrodes is not readily available.The principal aim of this study is to simulate the characteristics of a single cell compact electrolyzer unit. The simulation can be used to predict the Voltage-Current Density (V-I) characteristics, which is a measure of the efficiency of the process.The model equations were solved using COMSOL multi-physics software. The simulated V-I characteristic is compared with the experimental data

  9. Three-dimensional cooling pattern of a granitic pluton I. The study of exsolution sub-solidus reactions in the Toki granite, Central Japan

    International Nuclear Information System (INIS)

    This paper presents the results of petrographical studies carried out to examine the development and variation of sub-solidus reactions occurring in the Toki granite, Central Japan. The results reveal the three-dimensional cooling pattern of this zoned pluton. Samples collected from 19 boreholes in the Toki granite indicate a spatial variation in the extent of sub-solidus reactions. Exsolution coarsening produced microperthite textures with albite-rich lamellae in this pluton, whereas deuteric coarsening resulted in patchperthite with albite-rich patches. The width and spacing of the albite-rich lamella in microperthite increase systematically and prominently with elevation in the pluton. This indicates that the Toki granite effectively cooled from the roof during the exsolution coarsening stage. Measurements obtained using the hornblende-plagioclase and ternary feldspar thermometers indicate that volume diffusion took place in the temperature range 780-690°C; this diffusion was associated with exsolution coarsening. (author)

  10. Origin of mafic microgranular enclaves (MMEs) and their host quartz monzonites from the Muchen pluton in Zhejiang Province, Southeast China: Implications for magma mixing and crust-mantle interaction

    Science.gov (United States)

    Liu, Liang; Qiu, Jian-Sheng; Li, Zhen

    2013-02-01

    The origin of mafic enclaves in granitoid plutons has long been a matter of debate. In this paper, we present detailed petrographic, mineralogical, geochemical, and Srsbnd Ndsbnd Hf isotopic data, Usbnd Pb zircon dates, and field and petrological observations, for mafic microgranular enclaves (MMEs) and their host quartz monzonites from the Muchen pluton in Southeast China to evaluate their origins. LA-ICP-MS Usbnd Pb dating of zircon yields crystallisation ages of 112.4 ± 1.2 Ma and 112.1 ± 1.0 Ma for the MMEs and host quartz monzonites, respectively, indicating their coeval formation during the late Early Cretaceous. Field and petrological observations, such as spheroidal shapes, back-veining, double enclaves, xenocrysts, acicular apatites, and oscillatory zoning with repeated resorption surfaces in plagioclases, suggest that the MMEs are globules of a more mafic magma that was injected into and mingled with the host felsic magma. Geochemically, the host monzonites are intermediate-acidic, metaluminous, alkaline, and K-rich. In contrast, the MMEs are relatively poor in Si and K. The host monzonites are enriched in Rb, Th and U, and depleted in Sr, P, Nb, Ta and Ti, and show moderate to strong europium depletions (δEu = 0.12-0.60). These mineralogical and geochemical features classify the quartz monzonites as belonging to the I-type granitoids. The MMEs have broadly similar trace element signatures to those of the host monzonite, but are distinct in having relatively enriched Sr and P, more depleted Zr and Hf, and weak to moderate Eu depletions (δEu = 0.43-0.93). Major and trace element data plotted versus isotopic data for the MMEs and the host quartz monzonites yield covariant arrays that result from magma mixing during their petrogenesis. The MMEs and the host quartz monzonites have similar initial 87Sr/86Sr ratios (ISr) of 0.7058-0.7070 and 0.7062-0.7065, respectively, and both have high ɛNd(t) values (- 2.6 to + 0.6 for MMEs; - 3.2 to - 2.4 for quartz

  11. The fate of added alkalinity in model scenarios of ocean alkalinization

    Science.gov (United States)

    Ferrer González, Miriam; Ilyina, Tatiana

    2014-05-01

    The deliberate large-scale manipulation of the Earth's climate (geo-engineering) has been proposed to mitigate climate change and ocean acidification. Whilst the mitigation potential of these technologies could sound promising, they may also pose many environmental risks. Our research aims at exploring the ocean-based carbon dioxide removal method of alkalinity enhancement. Its mitigation potential to reduce atmospheric CO2 and counteract the consequences of ocean acidification, risks and unintended consequences are studied. In order to tackle these questions, different scenarios are implemented in the state-of-the-art Earth system model of the Max Planck Institute for Meteorology. The model configuration is based on the 5th phase of the coupled model intercomparison project following a high CO2 future climate change scenario RCP8.5 (in which radiative forcing rises to 8.5 W/m² in 2100). Two different scenarios are performed where the alkalinity is artificially added globally uniformly in the upper ocean. In the first scenario, alkalinity is increased as a pulse by doubling natural values of the first 12 meters. In the second scenario we add alkalinity into the same ocean layer such that the atmospheric CO2 concentration is reduced from RCP8.5 to RCP4.5 levels (with the radiative forcing of 4.5 W/m² in 2100). We investigate the fate of the added alkalinity in these two scenarios and compare the differences in alkalinity budgets. In order to increase oceanic CO2 uptake from the atmosphere, enhanced alkalinity has to stay in the upper ocean. Once the alkalinity is added, it will become part of the biogeochemical cycles and it will be distributed with the ocean currents. Therefore, we are particularly interested in the residence time of the added alkalinity at the surface. Variations in CO2 partial pressure, seawater pH and saturation state of carbonate minerals produced in the implemented scenarios will be presented. Collateral changes in ocean biogeochemistry and

  12. Chronological and geochemical studies of granite and enclave in Baimashan pluton, Hunan, South China

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Zircon LA-ICP-MS U-Pb dating reveals that the Baimashan Pluton is composed mainly of late Indosinian (204.5±2.8 Ma-209.2±3.8 Ma) biotite granodiorites/monzonitic granites (LIGs) and early Yanshanian (176.7±1.7 Ma) two-micas monzonitic granites (EYGs),and the coeval (203.2±4.5 Ma-205.1±3.9 Ma) mafic microgranular enclaves (MMEs) are generally found in the former.In addition,the ages of cores within zircons from LIGs and MMEs ranging from 221.4±4.0 Ma to 226.5±4.1Ma provide evidence of multistage magma intrusion during Indosinian in the study area.Measured 3010±20.6 Ma of inherited zircon age suggests that there may be recycling Archaean curstal material in existence in this area.LIGs and EYGs share some similar geochemical features: subalkaline and peraluminous granites,enrichment of Th,U,K,Ta,Zr,Hf and LREE but depletion of Ba,Nb,P,Ti and Eu,low εNd(t) values but high (87Sr/86Sr)i ratios,and old T2DM (ca.1.9-2.0 Ga).The behaviors of incompatible elements and REE are mainly dominated by fractional crystallization of plagioclase,K-feldspar,ilmenite and apatite,but that of Sr isotope mainly controlled by EC-AFC.They are crust-sourced and derived from partial melting of paleo-Proterozoic metagreywackes and related to biotite dehydration melting.LIGs are formed in post-collisional tectonic setting as crustal local extension and thinning during late Indosinian.But EYGs may be evolved products of congeneric granitic magma with LIGs formed in late Indoinian,which were emplaced again when crust underwent extensive thinning and extension in post-orogenic tectonic setting during Yanshanian in SC after undergoing EC-AFC.MMEs should be cognate enclaves and derived from liquid immiscibility of host magma.

  13. 40Ar/39Ar and U-Pb Ages and Isotopic Data for Oligocene Ignimbrites, Calderas, and Granitic Plutons, Southern Stillwater Range and Clan Alpine Mountains: Insights into the Volcanic-Plutonic Connection and Crustal Evolution in Western Nevada

    Science.gov (United States)

    John, D. A.; Watts, K. E.; Henry, C.; Colgan, J. P.; Cousens, B.

    2014-12-01

    Calderas in the southern Stillwater Range (SSR) and Clan Alpine Mountains (CAM) were formed during the mid-Tertiary ignimbrite flareup and subsequently tilted (40->90°) by large-magnitude extension. New geologic mapping, geochemistry, and 40Ar/39Ar and SHRIMP U-Pb zircon dating document 2 periods of magmatism resulting in 4 nested calderas and related granitoid plutons in sections up to 10 km thick. The first period included pre-caldera rhyolite lava domes (30(?) Ma), ~5 km of pre- and post-collapse intermediate lavas and rhyolite tuff that filled the Job Canyon caldera (~29.4 to 28.8 Ma), and the >4-5 km thick, geochemically similar IXL pluton (28.9±0.4 Ma) that intruded the Job Canyon caldera. The second period included pre-caldera rhyolite lava domes and dikes (~25.5 Ma) and 3 ignimbrite units in 3 calderas: tuff of the Louderback Mountains (low-silica rhyolite; ≥600 m thick; ~25.2 Ma); tuff of Poco Canyon (high-silica rhyolite; up to 4.3 km thick; 25.27±0.05 Ma); and ≥2000 km3 tuff of Elevenmile Canyon (trachydacite to rhyolite; up to 4.5 km thick; 25.12±0.01 Ma). The composite Freeman Creek pluton (granite, 24.8±0.4 Ma; granodiorite, 25.0±0.2 Ma) and Chalk Mountain rhyolite porphyry (25.2±0.2 Ma) and granite (24.8±0.3 Ma) plutons intruded the Poco Canyon and Elevenmile Canyon calderas. Early (30 Ma) rhyolites have the least radiogenic compositions (Sri~0.7040), whereas other units are relatively homogeneous (Sri~0.7050, ENd~0.0). Oxygen isotope compositions for SSR and CAM calderas are highly variable (d18Oquartz=5.6-8.2‰, d18Osanidine=5.5-7.0‰, d18Ozircon= 4.1-6.3‰), corresponding to a magmatic range of 5.7-7.9‰. U-Pb dating of zircons indicates homogeneous age populations and few/no xenocrysts and antecrysts. These data show that (1) thick plutons (>2-5 km) underlie compositionally and temporally related caldera-filling ignimbrites, (2) caldera-forming cycles are isotopically variable, requiring divergent magmatic sources in relatively

  14. PLUTON: A Three-Group Model for the Radial Distribution of Plutonium, Burnup, and Power Profiles in Highly Irradiated LWR Fuel Rods

    International Nuclear Information System (INIS)

    A three-group model (PLUTON) is described, which predicts the power density distribution, plutonium buildup, and burnup profiles across the fuel pellet radius as a function of in-pile time and parameters characterizing the type of reactor system with respect to fuel temperature and changes of density during the irradiation period. The PLUTON model is a part of two fuel performance codes (ASFAD and FEMAXI-V), which provide all necessary input for this model, mainly local temperatures and fuel matrix density across the radius. Comparisons between measurements and predictions of the PLUTON model are made on fuels with enrichments in the range 2.9 to 8.25% and with burnup between 21 000 and 64 000 MWd/t. It is shown that the PLUTON predictions are in good agreement with measurements as well as with predictions of the well-known TUBRNP model. The proposed model is flexibly applicable for all types of light water reactor (LWR) fuels, including mixed oxide, and for fuel tested in the Organization for Economic Corporation and Development's Halden heavy water reactor. The PLUTON three-group model is based on analytical (theoretical) consideration of neutron absorption in a resonant region of the fuel in its apparent form. It makes the model more flexible in comparison with the semi-empirical TUBRNP one-group model and allows the physically based model analysis of commercial LWR-type fuels at high burnup as well as analysis of experimental fuel rods tested in the Halden heavy water reactor, which is one of the main test reactors in the world. The differences in fuel behavior in the Halden reactor in terms of burnup distribution and plutonium buildup can be more clearly understood with the PLUTON model

  15. Isotopic characteristics (Nd and Sr) of the intrusive plutonism at the northwestern Amazonian Craton, Venezuela, and implications for the Paleoproterozoic evolution

    International Nuclear Information System (INIS)

    Nd and Sr analyses were performed on selected granitoid plutons that intrude Archean and Paleoproterozoic domains of the Guyana shield (Venezuela). The isotopic signatures of these plutons together with the geochronologic background of the country rocks are used to constrain their magma genesis and tectonic setting within the Paleoproterozoic evolutions of mobile belts (Maroni-Itacaiunas and Ventuari-Tapajos provinces) of the Amazonian Craton. The Encrucijada Suite (2187 +- 94 Ma), which intrudes Archean rocks of the Imataca Complex, originated predominantly from partial melt of this crust, as supported by negative epsilonNd(2.1Ga) values (-2.2 to - 4.9) and TDM ages between 2.82 and 2.49 Ga. Conversely, the plutons from the Supamo Complex (2230 - 2050 Ma) and Cuchivero Group (1980 - 1830 Ma), occurring within the adjoining Paleoproterozoic provinces, are juvenile in nature (derived from roughly contemporary protoliths). These bodies display TDM ages between 2.13 and 2.22 Ga, as well as positive epsilonNd(2.1Ga) values (+0.74 to + 3.05). Isotopic correlation diagrams 143 Nd/144 Nd vs. 147 Sm/144 Nd and 143 Nd/144 Nd vs. time) plotted together with the plutonic rocks and Imataca Complex rocks were evaluated taking into account the geologic background of the NW part of the Amazonian Craton. Interpretation of these isotopic data supports the idea of tectonic juxtaposition between the Imataca Complex and the Maroni-Itacaiunas province during the Transamazonian orogeny (2.25 - 2.05 Ga). On the other hand, the Cuchivero Group plutons have a contrasting isotopic signature compared to the other Paleoproterozoic plutonic rocks. This is consistent with the existence of a tectonic boundary between the Maroni-Itacaiunas and the Ventuari-Tapajos province in the late Paleoproterozoic. (author)

  16. The link between volcanism and plutonism in epizonal magma systems; high-precision U-Pb zircon geochronology from the Organ Mountains caldera and batholith, New Mexico

    Science.gov (United States)

    Rioux, Matthew; Farmer, G. Lang; Bowring, Samuel A.; Wooton, Kathleen M.; Amato, Jeffrey M.; Coleman, Drew S.; Verplanck, Philip L.

    2016-02-01

    The Organ Mountains caldera and batholith expose the volcanic and epizonal plutonic record of an Eocene caldera complex. The caldera and batholith are well exposed, and extensive previous mapping and geochemical analyses have suggested a clear link between the volcanic and plutonic sections, making this an ideal location to study magmatic processes associated with caldera volcanism. Here we present high-precision thermal ionization mass spectrometry U-Pb zircon dates from throughout the caldera and batholith, and use these dates to test and improve existing petrogenetic models. The new dates indicate that Eocene volcanic and plutonic rocks in the Organ Mountains formed from ~44 to 34 Ma. The three largest caldera-related tuff units yielded weighted mean 206Pb/238U dates of 36.441 ± 0.020 Ma (Cueva Tuff), 36.259 ± 0.016 Ma (Achenback Park tuff), and 36.215 ± 0.016 Ma (Squaw Mountain tuff). An alkali feldspar granite, which is chemically similar to the erupted tuffs, yielded a synchronous weighted mean 206Pb/238U date of 36.259 ± 0.021 Ma. Weighted mean 206Pb/238U dates from the larger volume syenitic phase of the underlying Organ Needle pluton range from 36.130 ± 0.031 to 36.071 ± 0.012 Ma, and the youngest sample is 144 ± 20 to 188 ± 20 ka younger than the Squaw Mountain and Achenback Park tuffs, respectively. Younger plutonism in the batholith continued through at least 34.051 ± 0.029 Ma. We propose that the Achenback Park tuff, Squaw Mountain tuff, alkali feldspar granite and Organ Needle pluton formed from a single, long-lived magma chamber/mush zone. Early silicic magmas generated by partial melting of the lower crust rose to form an epizonal magma chamber. Underplating of the resulting mush zone led to partial melting and generation of a high-silica alkali feldspar granite cap, which erupted to form the tuffs. The deeper parts of the chamber underwent continued recharge and crystallization for 144 ± 20 ka after the final eruption. Calculated magmatic

  17. Isotopic studies of the Eye-Dashwa Lakes pluton and the long-term integrity of whole-rock and mineral systems

    International Nuclear Information System (INIS)

    This report presents results of isotopic studies of the Eye-Dashwa Lakes pluton, located near Atikokan, Ontario. Suites of pristine unaltered and highly altered core samples from deep boreholes were used to study Rb-Sr, U-Th-Pb and Sr-Nd systematics, whole-rock Pb isotopes and fission track dating of apatite. The results have been used to investigate natural analogues for radionuclide migration in the geosphere, the tectonic stability of the pluton and the extent of water-rock interaction in fracture zones

  18. The Val Gabbro Plutonic Suite: a sub-volcanic intrusion emplaced at the end of flood basalt volcanism on the Kerguelen Archipelago

    OpenAIRE

    Scoates, J.S.; Weis, D; Franssens, M.; N. Mattielli; Annell, H.; Frey, F. A.; Nicolaysen, K.; Giret, A.

    2008-01-01

    The age, petrology, major and trace element geochemistry, and Sr–Nd–Hf–Pb isotopic geochemistry of basic and felsic rocks from the Val gabbro plutonic suite on the Kerguelen Archipelago, Southern Indian Ocean, are used to constrain the temporal and compositional relationships between sub-volcanic intrusions and flood basalt volcanism during the formation of a major oceanic island. The 4 km2 Val gabbro plutonic suite was emplaced at 24•25 ± 0•15 Ma (U–Pb zircon) into 25 Ma volcanic rocks of th...

  19. Modeling of the Climax Stock and Related Plutons Based on the Inversion of Magnetic Data, Southwest Nevada

    Science.gov (United States)

    Phelps, Geoffrey A.; Jachens, Robert C.; Moring, Barry C.; Roberts, Carter W.

    2004-01-01

    Two models of the Climax and Gold Meadows stocks were generated using a new method of magnetic inversion modeling based on the pseudogravity anomaly. The first model examined the shape of the two stocks and their connection at depth, concluding that the stocks are connected -4000 m below the ground surface. The second model re-examined the shape and depth of the Climax stock using a two-layer model and new magnetic data collected from drill hole ER-8-1. Existing and new magnetic data support a model of a zoned pluton with increasing magnetization with depth. A model of a zoned pluton was generated and adjusted to fit the magnetic anomaly measured over the stock. The model has an upper layer that extends to a depth of 1,700 m and is magnetized at 0.06 A/m, and a lower layer that extends to a maximum depth of 7,600 m and is magnetized at 0.17 A/m. The model matches the outcrop data, but was unable to match the intercept of the Climax stock from drill hole ER-8-1.

  20. Geochemistry and petrogenesis of anorogenic basic volcanic-plutonic rocks of the Kundal area, Malani Igneous Suite, western Rajasthan, India

    Indian Academy of Sciences (India)

    A Krishnakanta Singh; G Vallinayagam

    2004-12-01

    The Kundal area of Malani Igneous Suite consists of volcano-plutonic rocks. Basalt flows and gabbro intrusives are associated with rhyolite. Both the basic rocks consist of similar mineralogy of plagioclase, clinopyroxene as essential and Fe-Ti oxides as accessories. Basalt displays sub-ophitic and glomeroporphyritic textures whereas gabbro exhibits sub-ophitic, porphyritic and intergrannu- lar textures. They show comparable chemistry and are enriched in Fe, Ti and incompatible ele- ments as compared to MORB/CFB. Samples are enriched in LREE and slightly depleted HREE patterns with least significant positive Eu anomalies. Petrographical study and petrogenetic mod- eling of [Mg]-[Fe], trace and REE suggest cogenetic origin of these basic rocks and they probably derived from Fe-enriched source with higher Fe/Mg ratio than primitive mantle source. Thus, it is concluded that the basic volcano-plutonic rocks of Kundal area are the result of a low to moderate degree (> 30%) partial melting of source similar to picrite/komatiitic composition. Within plate, anorogenic setting for the basic rocks of Kundal area is suggested, which is in conformity with the similar setting for Malani Igneous Suite.

  1. Metamorphic evolution of the contact aureole of the Jhirgadandi pluton, Sonbhadra district,Mahakoshal mobile belt, central India

    Indian Academy of Sciences (India)

    S P Singh; Anand K Srivastava; Gopendra Kumar; S B Dwivedi

    2013-06-01

    The metamorphic evolution of the contact aureole around the Late Paleoproterozoic Jhirgadandi pluton in the eastern part of Parsoi Formation of Mahakoshal terrain, central India represents three distinct metamorphic zones, characterized by definite mineral assemblages. The contact-metamorphic event produced the peak-metamorphic mineral assemblages Bt + Qtz + Alb + Sil ± Cd ± Grt ± Mus ± Kfs in the metapelites of inner aureole, Bt + Qtz + And + Mus + Kfs + Plag ± Cd ± Chl in middle aureole and Chl + Mus + Bt ± And + Alb + Qtz ± Ep + Mt ± tourmaline in the outer aureole. The estimated P–T conditions based on detailed geothermobarometric calculations in the thermal metamorphosed rocks are 690°C/3.4 kbar, 580 ± 15°C and 487 ± 30°C in inner aureole, middle aureole and outer aureole, respectively. The variation in metamorphic condition suggests that the shallow crustal level emplacement of Jhirgadandi pluton is responsible for the overprinting of contact metamorphic assemblages (M2) in the low grade metapelites (regional metamorphism M1) of Mahakoshal Group.

  2. Near conductive cooling rates in the upper-plutonic section of crust formed at the East Pacific Rise

    Science.gov (United States)

    Faak, Kathrin; Coogan, Laurence A.; Chakraborty, Sumit

    2015-08-01

    A new geospeedometer, based on diffusion modeling of Mg in plagioclase, is used to determine cooling rates of the upper section of the lower oceanic crust formed at fast-spreading mid-ocean ridges. The investigated natural sample suites include gabbroic rocks formed at three different locations along the fast-spreading East Pacific Rise. These samples cover a depth interval of 0-840 m below the sheeted dike/gabbro boundary and therefore allow the variation of cooling rate as a function of depth within the upper plutonic sequence to be determined. We demonstrate that the cooling rates we obtained are robust (reproducible and consistent across different vertical sections at fast spreading ridges) and decrease significantly with increasing sample depth (covering almost 4 orders of magnitude, ranging from ∼1 °C y-1 for the shallowest samples to 0.0003 °C y-1 for the deepest samples). Both the absolute cooling rates, and the rate of decrease of cooling rate with depth, are consistent with conductive thermal models. In contrast, the absolute cooling rates determined from the deeper samples (>300 m below DGB), and the large decrease in cooling rate with depth are inconsistent with thermal models that include substantial cooling by off-axis hydrothermal circulation within the upper plutonic section of the crust.

  3. Hf-Nd isotopic and trace element constraints on the genesis of alkaline and calc-alkaline lamprophyres

    International Nuclear Information System (INIS)

    Major and trace element, Nd and for the first time Hf isotopic compositions of Central European Hercynian and Alpine alkaline (nephelinites) and calc-alkaline (minettes) lamprophyres are reported. The alkaline dikes have significantly higher initial εNd values (+3.9 to +5.2) than the calc-alkaline dikes (-1 to -7). Their initial εHf values range between +1.9 and +6.0. Both groups show the typical high level of incompatible-element enrichment. In addition the calc-alkaline lamprophyres are characterized by an overabundance of Cs relative to Rb, high Ba/La and Ba/Sr ratios as well as depletion in Nb, Ti and Ta. Covariations between initial εHf-εNd and trace elements suggest that crust-mantle mixing processes were involved in the formation of the calc-alkaline mafic magmas. These data give way to a general, refined model of lamprophyre genesis and provide information about enrichment processes in the subcontinental lithospheric mantle. It is suggested that alkaline and calc-alkaline lamprophyres originate from similar mantle segments. Alkaline lamprophyres can be generated by 10% partial melting of a metasomatically enriched garnet peridotite. Calc-alkaline lamprophyres, however, can be generated in subduction related environments by mixing of 5-15% sedimentary melts, strongly enriched in K, Rb, Zr, Hf, Y and REE, produced by partial melting of subducted oceanic sediments, with a metasomatically enriched mantle source similar to that suggested for the ultramafic alkaline dikes. (orig.)

  4. Antioxidant activity and protective effects of cocoa and kola nut mistletoe (Globimetula cupulata against ischemia/reperfusion injury in Langendorff-perfused rat hearts

    Directory of Open Access Journals (Sweden)

    Afolabi Clement Akinmoladun

    2016-04-01

    Full Text Available Protection against cardiomyocyte damage following ischemia/reperfusion (I/R injury is highly desirable in patients with ischemic heart disease. Hydromethanol extracts of Globimetula cupulata (mistletoe growing on cocoa (CGCE and kola nut (KGCE trees were assessed for antioxidant content and cardioprotective potential against I/R. Graded concentrations (1–50 μg/mL of CGCE or KGCE were tested on Langendorff-perfused rat hearts to evaluate the effects on the flow rate, heart rate, and force of cardiac contraction, while another set of hearts were subjected to biochemical analyses. Both extracts showed good antioxidant content and activity, but KGCE (EC50: 24.8±1.8 μg/mL showed higher hydroxyl radical scavenging activity than CGCE (70.2±4.5 μg/mL. Both extracts at 3 μg/mL reversed (p < 0.001 membrane peroxidation and the significant decrease in nitrite level, coronary flow rate, and superoxide dismutase and catalase activity caused by the I/R cycle. It is concluded that G. cupulata protects against ischemia–reperfusion injury in rat hearts via augmenting endogenous antioxidants and significant restoration of altered hemodynamic parameters.

  5. Konstrukce a výroba nástavce nášlapného pedálu jízdního kola

    OpenAIRE

    Jurka, Adam

    2016-01-01

    Bakalářská práce je zaměřena na konstrukci a výrobu nástavce nášlapného pedálu jízdního kola, který bude sloužit při jízdě bez cyklistických treter. Součást bude zkonstruovaná ve 3D parametrickém softwaru Autodesk Inventor. Model součásti bude vyroben pomocí metody Fused Deposition Modeling s využitím 3D tiskárny uPrint. Součástí práce je výroba silikonové formy, která bude sloužit pro odlití plastového modelu nástavce nášlapného pedálu. Práce je ukončena technicko-ekonomickým zhodnocením. ...

  6. RES Hydrogen: efficient pressurised alkaline electrolysers

    DEFF Research Database (Denmark)

    Bowen, Jacob R.; Bentzen, Janet Jonna; Jørgensen, Peter Stanley;

    The RESelyser project addresses issues associated with coupling alkaline electrolysis to renewable energy sources such as electrode stability and gas purity by implementing improved electrodes and a new separator membrane concept. The project aims to improve performance, operation pressure and...... reduce system cost. The project supports DTU Energy's activities on electrodes within the larger FCH-JU project. The overall project demonstrated: improved electrode efficiency also during cyclic operation, safe gas purity at a system pressure of 30 bar, 10 kW stack operation and estimated system costs...

  7. Alkaline carbonates in blast furnace process

    Directory of Open Access Journals (Sweden)

    P. Besta

    2014-10-01

    Full Text Available The production of iron in blast furnaces is a complex of physical, chemical and mechanical processes. The input raw materials contain not only metallic components, but also a number of negative elements. The most important negative elements include alkaline carbonates. They can significantly affect the course of the blast furnace process and thus the overall performance of the furnace. As a result of that, it is essential to accurately monitor the alkali content in the blast furnace raw materials. The article analyzes the alkali content in input and output raw materials and their impact on the blast furnace process.

  8. A Fresh Plutonic Igneous Angrite Containing Grain Boundary Glass From Tamassint, Northwest Africa

    Science.gov (United States)

    Irving, A. J.; Kuehner, S. M.; Rumble, D.

    2006-12-01

    Tamassint Angrite: A small fragmented stone found in June 2006 south of Tamassint oasis in the Morocco-Algeria border region represents a new type of angrite lithology, unlike the coarse grained metamorphic or fine grained "basaltic" to quench-textured examples known previously. This extremely fresh, fusion-crusted specimen has a coarse grained (0.6-12 mm) plutonic igneous cumulate texture, and is composed of Al-Ti-rich clinopyroxene (33.4%), pure anorthite (28.6%), Ca-rich olivine (18.7%) with prominent exsolution lamellae (10-50 μm wide) of kirschsteinite, ulvöspinel (18.5%), and accessory glass, troilite and metal. Subhedral anorthite grains are partially enclosed within larger ulvöspinel grains. Mineral compositions are as follows: clinopyroxene (Fs20.8-33.3Wo53-54.9, Al2O3 = 5.7 to 9.4 wt.%, TiO2 = 0.9 to 2.9 wt.%, FeO/MnO = 85-278), olivine (Fa72.6-74.7Ln3.5-3.6, CaO = 2.1 wt.%, FeO/MnO = 70-87), kirschsteinite (Fa44.7-45.4Ln46-47.2, FeO/MnO = 73-82), ulvöspinel (TiO2 = 27.6 wt.%, Al2O3 = 5.5 wt.%). Reintegration of the kirschsteinite lamellae gives a pre-exsolution olivine composition of Fa68.1Ln12.2 with 7.3 wt.% CaO. Present along grain boundaries (notably between anorthite and ulvöspinel) are narrow (5-20 μm) curvilinear zones of glass associated with secondary kirschteinite, clinopyroxene and olivine (which show similar curvilinear morphology and truncate kirschsteinite lamellae). Glass compositions plot close to a mixing line between anorthite and ulvöspinel. Replicate oxygen isotopic analyses of acid-washed minerals by laser fluorination gave δ18O = 3.881, 3.845, δ17O = 1.967, 1.927, Δ17O = -0.0745, -0.0956 per mil (for TFL slope = 0.526). Comparison With NWA 2999: We previously showed [1] that angrite Northwest Africa 2999 is a metamorphically annealed breccia with distinctive symplectites and coronas representing forward and reverse versions of the same solid state reaction. We suggested that these disequilibrium textures required burial

  9. Alkaline chemistry of transuranium elements and technetium and the treatment of alkaline radioactive wastes

    International Nuclear Information System (INIS)

    Goal of this survey is to generalize the known data on fundamental physical-chemical properties of TRUs and Tc, methods for their isolation, and to provide recommendations that will be useful for partitioning them from alkaline high-level wastes

  10. Alkaline chemistry of transuranium elements and technetium and the treatment of alkaline radioactive wastes

    Energy Technology Data Exchange (ETDEWEB)

    Delegard, C.H. [Westinghouse Hanford Co., Richland, WA (United States); Peretrukhin, V.F.; Shilov, V.P.; Pikaev, A.K. [Russian Academy of Sciences (Russian Federation). Inst. of Physical Chemistry

    1995-05-01

    Goal of this survey is to generalize the known data on fundamental physical-chemical properties of TRUs and Tc, methods for their isolation, and to provide recommendations that will be useful for partitioning them from alkaline high-level wastes.

  11. Constraining the magma flow record based on magmatic and magnetic data in La Gloria Pluton, central Chile

    Science.gov (United States)

    Gutierrez, F. J.; Payacán, I.; Gelman, S. E.; Bachmann, O.; Creative Physical Petrology Team

    2013-05-01

    The magmatic origin of the anisotropy of magnetic susceptibility (AMS) is examined in comparison with magmatic anisotropy data in a small, shallow, silicic magma reservoir in the upper crust. La Gloria Pluton (LGP) is a 10 Ma granodiorite/quartz monzonite of about 250 km3 located in the southern Andes, central Chile. LGP represents a particularly simple case of a silicic intrusion that was assembled in only a few pulses and cooled over a short time interval. Hornblende, biotite and minor magnetite are ubiquitous mafic phases. The AMS tensor indicates that magnetic fabric has an oblate shape (i.e. magnetic foliation is higher than magnetic lineation). Lineations are weak (values up to 1.05), have a N-NW trend with a nearly horizontal dip and are interpreted to represent axisymmetric convection parallel to the main pluton elongation. Foliations are more pronounced (values up to 1.14), having NW trends and dips that vary gradually from vertical at the walls, to horizontal at the center and near the roof of the chamber. We selected 12 samples from AMS sites to obtain petrographic data (well-distributed throughout the pluton, containing samples from the walls, the center and the roof of LGP), and then, determine the magmatic fabric (anisotropy, lineation, foliation). We made 3 oriented thin sections per sample oriented with the AMS. Magmatic anisotropy data were obtained by measuring mineral length, width and orientation in photomicrographs of the three main planes of the AMS tensor, producing 3-D mineral data which were collected for plagioclase and amphibole + bitotite independently. For each site, a Bingham distribution with 95% of confidence is used to determine the mean mineral orientations and their angle difference with the AMS axes. Magmatic anisotropy tensor and rotations with respect to the AMS tensor are determined using both eigenvalues and minimization algorithms. Preliminary results indicate that crystals are coherently oriented in both mineral groups, and

  12. Recognition of favorable zones for uranium and thorium accumulation, at Um Ara-Um Shilman granitic pluton, south eastern desert, Egypt, using airborne spectrometric and magnetic data

    International Nuclear Information System (INIS)

    The objective is aimed at identifying significant U and Th anomalies, the amount of re-mobilization of U and Th, the structural framework of the granite pluton and the distribution of spectrometric anomalies. The study revealed that the granite pluton could be represented as a single radio-lithologic unit excluding abnormal measurements exceeding Xban + 2S. It also revealed the existence of eight strong spectrometric anomalies. Observed values of eU correlate well with eTh, r=0.72 while the correlation between eU/eTh and eU is lacking, r=0.190. Meanwhile, there is a negative correlation between eU/eTh and eTh,r= -0.335. This deficiency in correlation suggests a limited or zero remobilization of uranium, which was partly governed by magmatic processes. Most of the radioactive anomalies were found within or near the major contact faults which may act as channels for mineralized fluids from the subsurface. These fluids possess increased concentrations of U and/or Th which could exist in appropriate chemical and/or structural traps. The U and Th anomalies were found to be associated with the northern and southern parts of the granite pluton respectively. The difference between the northern and southern parts of the granite pluton may be attributed to differences in radioelement content, the effect of partial and/or complete digestion of older rocks, or to different levels of erosion. (author)

  13. Time-scales of assembly and thermal history of a composite felsic pluton: constraints from the Emerald Lake area, northern Canadian Cordillera, Yukon

    Science.gov (United States)

    Coulson, Ian M.; Villeneuve, Mike E.; Dipple, Gregory M.; Duncan, Robert A.; Russell, James K.; Mortensen, James K.

    2002-05-01

    Knowledge of the time-scales of emplacement and thermal history during assembly of composite felsic plutons in the shallow crust are critical to deciphering the processes of crustal growth and magma chamber development. Detailed petrological and chemical study of the mid-Cretaceous, composite Emerald Lake pluton, from the northern Canadian Cordillera, Yukon Territory, coupled with U-Pb and 40Ar/ 39Ar geochronology, indicates that this pluton was intruded as a series of magmatic pulses. Intrusion of these pulses produced a strong petrological zonation from augite syenite, hornblende quartz syenite and monzonite, to biotite granite. Our data further indicate that multiple phases were emplaced and cooled to below the mineral closure temperatures over a time-scale on the order of the resolution of the 40Ar/ 39Ar technique (˜1 Myr), and that emplacement occurred at 94.3 Ma. Simple thermal modelling and heat conduction calculations were used to further constrain the temporal relationships within the intrusion. These calculations are consistent with the geochronology and show that emplacement and cooling were complete in less than 100 kyr and probably 70±5 kyr. These results demonstrate that production, transport and emplacement of the different phases of the Emerald Lake pluton occurred essentially simultaneously, and that these processes must also have been closely related in time and space. By analogy, these results provide insights into the assembly and petrogenesis of other complex intrusions and ultimately lead to an understanding of the processes involved in crustal development.

  14. Three-dimensional cooling pattern of a granitic pluton 2. The study of deuteric sub-solidus reactions in the Toki granite, Central Japan

    International Nuclear Information System (INIS)

    Petrographical studies examining the development and variations of sub-solidus reactions recorded in the Toki granite represent the three-dimensional cooling pattern of this zoned pluton in Central Japan. Samples collected from 19 boreholes in the Toki granite show characteristics indicative of spatial variations in the extent of the sub-solidus reactions. Exsolution coarsening has produced microperthite, including albite-rich lamellae, in this pluton, while deuteric coarsening has resulted in the formation of patchperthite, myrmekite, and the reaction rim. The extent of the deuteric coarsening reactions can be evaluated from the width and spacing of the albite-rich patch in patchperthite and from the thickness of myrmekite and the reaction rim. The width, spacing, and thickness of these textural features increase systematically with elevation; they also increase gradually in the horizontal inward direction in the western part of the pluton but not in the eastern part of the pluton. The systematic variations in textural development indicate that the Toki granite cooled effectively from the roof and from the western margin during the deuteric coarsening stage. The deuteric coarsening may have occurred at temperatures below 500°C, as indicated by ternary feldspar thermometry. (author)

  15. U-Pb zircon ages and structural development of metagranitoids of the Teplá crystalline complex: evidence for pervasive Cambrian plutonism within the Bohemian massif (Czech Republic)

    Czech Academy of Sciences Publication Activity Database

    Dörr, W.; Fiala, Jiří; Vejnar, Zdeněk; Zulauf, G.

    1998-01-01

    Roč. 87, č. 1 (1998), s. 135-149. ISSN 0016-7835 R&D Projects: GA AV ČR KSK1012601 Grant ostatní: DFG(DE) Zu73/1-3 Keywords : Cambrian plutonism * U-Pb analyses * Bohemian massif Subject RIV: DB - Geology ; Mineralogy Impact factor: 0.841, year: 1998

  16. DNA DAMAGE QUANTITATION BY ALKALINE GEL ELECTROPHORESIS.

    Energy Technology Data Exchange (ETDEWEB)

    SUTHERLAND,B.M.; BENNETT,P.V.; SUTHERLAND, J.C.

    2004-03-24

    Physical and chemical agents in the environment, those used in clinical applications, or encountered during recreational exposures to sunlight, induce damages in DNA. Understanding the biological impact of these agents requires quantitation of the levels of such damages in laboratory test systems as well as in field or clinical samples. Alkaline gel electrophoresis provides a sensitive (down to {approx} a few lesions/5Mb), rapid method of direct quantitation of a wide variety of DNA damages in nanogram quantities of non-radioactive DNAs from laboratory, field, or clinical specimens, including higher plants and animals. This method stems from velocity sedimentation studies of DNA populations, and from the simple methods of agarose gel electrophoresis. Our laboratories have developed quantitative agarose gel methods, analytical descriptions of DNA migration during electrophoresis on agarose gels (1-6), and electronic imaging for accurate determinations of DNA mass (7-9). Although all these components improve sensitivity and throughput of large numbers of samples (7,8,10), a simple version using only standard molecular biology equipment allows routine analysis of DNA damages at moderate frequencies. We present here a description of the methods, as well as a brief description of the underlying principles, required for a simplified approach to quantitation of DNA damages by alkaline gel electrophoresis.

  17. Dissolution kinetics of smectite under alkaline conditions

    International Nuclear Information System (INIS)

    Extensive use of cement for encapsulation, backfilling, and grouting purposes is envisaged in radioactive waste disposal. Degradation of cement materials through contact with groundwater can produce a high pH pore fluid initially ranging from pH 13.0 to 13.5. The pore fluid pH eventually decreases to moderately alkaline ranges due to formation and evolution of subsequent materials. The high pH pore fluids can migrate outwards where it will chemically react with the host rock, and the bentonite utilized to enhance the repository's integrity. These chemical reactions degrade the host rocks' and bentonite ability to absorb radionuclides. Smectites comprising the bulk of bentonite can lose some of their desirable properties during the early stages of bentonite-cement-pore fluid interaction. This has been a key research issue in the performance assessment of radioactive waste disposal system. Elucidating the effects of high pH pore fluid on the physical and chemical properties of smectites (i.e. especially dissolution behavior and rates) is of utmost importance. Stirred-flow-through dissolution experiments were utilized to derive reliable dissolution rates for smectites under neutral to highly alkaline conditions. The effects of pH and temperature on smectite dissolution rates were also investigated. (author)

  18. Biological alkalinity generation in acid mine drainage

    International Nuclear Information System (INIS)

    Ecological Engineering and Biological Polishing technologies are a decommissioning approach to inactive coal, uranium and base metal mining operations. To improve acid mine drainage water, some fundamental aspects of wetland ecology and sediment microbiology are combined. The combination provides conditions which allow biomineralization of the contaminants. The authors report here the first records of microbial alkalinity generation in acid mine drainage, through the utilization of the ARUM (Acid Reduction Using Microbiology) process. Increases in pH are brought about by alkalinity-generating microbes such as sulfate reducers, iron reducers, methanogens, or denitrifiers. The ARUM process has been successful in increasing pH from 2.5 to 7.0 in laboratory-scale flow-through reactors operated continuously for more than 120 days. Ni was also reduced from 13 mg/l to < 0.01 mg/l. Batch ARUMators in the field have also performed well. Design parameters are being developed for low flow rates of 5 l/min in a pilot-scale system receiving seepage from mine tailings

  19. Alkaline flocculation of Phaeodactylum tricornutum induced by brucite and calcite

    OpenAIRE

    Vandamme, Dries; Pohl, Philip I.; Beuckels, Annelies; Foubert, Imogen; Brady, Patrick V.; Hewson, John C.; Muylaert, Koenraad

    2015-01-01

    Alkaline flocculation holds great potential as a low-cost harvesting method for marine microalgae biomass production. Alkaline flocculation is induced by an increase in pH and is related to precipitation of calcium and magnesium salts. In this study, we used the diatom Phaeodactylum tricornutum as model organism to study alkaline flocculation of marine microalgae cultured in seawater medium. Flocculation started when pH was increased to 10 and flocculation efficiency reached 90% when pH was 1...

  20. The effect of alkaline agents on retention of EOR chemicals

    Energy Technology Data Exchange (ETDEWEB)

    Lorenz, P.B.

    1991-07-01

    This report summarizes a literature survey on how alkaline agents reduce losses of surfactants and polymers in oil recovery by chemical injection. Data are reviewed for crude sulfonates, clean anionic surfactants, nonionic surfactants, and anionic and nonionic polymers. The role of mineral chemistry is briefly described. Specific effects of various alkaline anions are discussed. Investigations needed to improve the design of alkaline-surfactant-polymer floods are suggested. 62 refs., 28 figs., 6 tabs.

  1. Zircon U-Pb ages, geochemical and Sr-Nd-Pb-Hf isotopic constraints on petrogenesis of the Tarom-Olya pluton, Alborz magmatic belt, NW Iran

    Science.gov (United States)

    Nabatian, Ghasem; Jiang, Shao-Yong; Honarmand, Maryam; Neubauer, Franz

    2016-02-01

    A petrological, geochemical and Sr-Nd-Pb isotopic study was carried out on the Tarom-Olya pluton, Iran, in the central part of the Alpine-Himalayan orogenic belt. The pluton is composed of diorite, monzonite, quartz-monzonite and monzogranite, which form part of the Western Alborz magmatic belt. LA-ICP-MS analyses of zircons yield ages from 35.7 ± 0.8 Ma to 37.7 ± 0.5 Ma, interpreted as the ages of crystallization of magmas. Rocks from the pluton have SiO2 contents ranging from 57.0 to 69.9 wt.%, high K2O + Na2O (5.5 to 10.3 wt.%) and K2O/Na2O ratio of 0.9 to 2.0. Geochemical discrimination criteria show I-type and shoshonitic features for the studied rocks. All investigated rocks are enriched in light rare earth elements (LREEs), large ion lithophile elements (LILEs), depleted in high-field strength elements (HFSEs), and show weak or insignificant Eu anomalies (Eu/Eu* = 0.57-1.02) in chondrite-normalized trace element patterns. The Tarom-Olya pluton samples also show depletions in Nb, Ta and Ti typical of subduction-related arc magmatic signatures. The samples have relatively low ISr (0.7047-0.7051) and positive εNd(36 Ma) (+ 0.39 to + 2.10) values. The Pb isotopic ratios show a (206Pb/204Pb)i ratio of 18.49-18.67, (207Pb/204Pb)i ratio of 15.58-15.61 and (208Pb/204Pb)i ratio of 38.33-38.77. The εHf(t) values of the Tarom-Olya pluton zircons vary from - 5.9 to + 8.4, with a peak at + 2 to + 4. The depleted mantle Hf model ages for the Tarom-Olya samples are close to 600 Ma. These isotope evidences indicate contribution of juvenile sources in petrogenesis of the Tarom-Olya pluton. Geochemical and isotopic data suggest that the parental magma of the Tarom-Olya pluton was mainly derived from a sub-continental lithospheric mantle source, which was metasomatized by fluids and melts from the subducted Neotethyan slab with a minor crustal contribution. Subsequent hot asthenospheric upwelling and lithospheric extension caused decompression melting in the final stage of

  2. Extraction of uranium from alkaline medium by certain amines

    International Nuclear Information System (INIS)

    A possible route for treatment of irradiated uranium from alkaline solution was recently addressed. This may have some advantages related to the isolation of many troublesome fission products upon alkaline dissolution of uranium oxides. In this work, the solubility of uranium oxides in alkaline medium of sodium carbonate and sodium hydroxide mixture was investigated. The different factors affecting the solubility were studied. From alkaline solutions, the extraction of uranium by different amines was carried out. The equilibrium encountered in this extraction systems was elaborated. Possible use of these systems for treatment of irradiated uranium was discussed

  3. Paleomagnetism and magnetic fabric of Miocene plutons of the Tonalá shearz zone, Chiapas, Mexico: evidence of rotation of the remanence vector

    Science.gov (United States)

    Molina-Garza, Roberto S.; Geissman, John W.

    2016-04-01

    The Late Miocene plutons of coastal Chiapas are elongated parallel to the Tonalá mylonite belt, and some plutons show asymmetric outcrop patterns with sheared tails that trail behind the intrusions. Plutons were emplaced within a transpressional sinistral shear zone. Magnetic fabrics in the plutons are well-developed, and are subparallel to the structural trend of the Tonalá mylonitic belt, but locally magmatic fabrics are preserved. Magnetic fabrics in undeformed granites with igneous textures are also subparallel to the shear zone axis. Strongly deformed plutons have Ṕvalues as high as 1.7. Fabric ellipsoids are predominantly oblate, but they are triaxial in sites with igneous textures. Characteristic magnetizations reside in a cubic phase, such as low-Ti magnetite, but abundant particles in the MD range prevent isolating a stable magnetization in many of the sites. Site means are NW to NE directed, and of moderate positive inclination (or its antipodal), but locally they are very discordant in declination. The overall mean, discarding highly discordant sites is of D= 359.5 and I=41.9 (k=14.2, alpha95=8.1), which is nearly concordant with the NA reference direction indicating gentle northward tilt of less than about 10°. We explain the highly discordant directions as caused by continuing, progressive, deformation in the transpressive shear zone of a thermochemical remanence acquired during deformation. Deformation resulted in rotations, both in a clockwise and an anticlockwise sense. These results are interpreted as paleomagnetic vectors affected by distortional strain, which based on AMS exceed 40% shortening and accommodate shape and volume change in the rock.

  4. Magmatic and solid state structures of the Abu Ziran pluton: Deciphering transition from thrusting to extension in the Eastern Desert of Egypt

    Science.gov (United States)

    Fritz, Harald; Loizenbauer, Jürgen; Wallbrecher, Eckart

    2014-11-01

    The 606 Ma old Abu Ziran granite of the Eastern Desert of Egypt intruded the southern margin of the Meatiq dome in a sinistral shear extensional setting. Its emplacement was enabled by a system of NW-trending sinistral shears, related Riedel shears and N-S extensional shear zones and faults. Magmatic flow was east-directed and controlled by Riedel shears that progressively rotated to an orientation favourable for extension. Strain markers that document magmatic flow show eastward decreasing strain together with strain increase from pluton centre to margins. This is explained by Newtonian flow between non-parallel plates and differences in flow velocities across the pluton. Solid state fabrics including shear fabrics, orientation of late magmatic dykes and quartz tension gashes, together with quartz C-axes distributions, document southward extensional shear within the solidified pluton and adjacent host rocks. Extensional shear is correlated with exhumation of the Meatiq dome coeval and soon after pluton solidification (585 Ma). Pressure temperature evolutionary paths, derived from fluid inclusions, show a clockwise path with exhumation by isothermal decompression in the Meatiq dome. By contrast, the overlying volcanosedimentary nappes experienced an anti-clockwise path released by temperature rise due to pluton emplacement followed by isobaric cooling. Quartz fabrics indicate high-temperature coaxial N-S flow in the northern Meatiq dome and lower-temperature, non-coaxial southward flow within the overlaying superficial nappe. This is explained by the exhumation process itself that progressively localised into simple shear domains when rocks approached higher crustal levels. Late extension at ca. 580 Ma was pure shear dominated and resulted in reversal of shear, now dextral, in the western Meatiq shear zone.

  5. Growing season changes in Fennoscandia and Kola peninsula during the period 1982 to 1999 - Implications for reindeer husbandry (In Norwegian with Summary in English

    Directory of Open Access Journals (Sweden)

    Hans Tømmervik

    2005-04-01

    Full Text Available Climate change and particularly variations in air temperature have significant impacts on the growth rhythm of plants where these occur at the limits of their natural distribution range, especially at northern latitudes. Our study area, Fennoscandia and Kola Peninsula, is characterized by large regional climatic differences from south to north, from west to east, and from lowland to mountains. Accordingly, the region is well suited for looking for evidence of climatic change and studying regional differences in the response of such change. The International Panel on Climate Change (IPCC reports that the projected warming in northern Europe is greater than for many other regions of the world. Therefore major physical and ecological changes are expected. On land, there will be a tendency for shifts in major biomes such as tundra and boreal forest. Permafrost will decline, trees and shrubs will encroach northern tundra, and broad-leaved trees may encroach coniferous forests. Net primary productivity in ecosystems is likely to increase. The temperature level at the end of the 20th century is ca. 0.5 oC higher than in the 1930 for the Northern hemisphere (IPCC and World Meteorological Organization. Other studies show that in the period 1890-1999, the increase in temperature over Fennoscandia varies between 0.02 (Karasjok and 0.1 oC decade-1 (Helsinki, and they also showed that at several stations within the area the spring temperatures have increased steadily throughout the 20th century. Most stations experienced low spring temperatures in the beginning of the century, and rather high temperatures around 1950. At present, the winter temperature levels are considerably higher than in the rest of the period. However, at northern stations the winter temperatures were higher in the 1930s than at present. Phenological registrations have been used word-wide to look for possible effects of climate change, but within Fennoscandia the problem is that

  6. Statistical analysis of the geological-hydrological conditions within part of the Eye-Dashwa pluton, Atikokan, northwestern Ontario

    International Nuclear Information System (INIS)

    The occurrence and distribution of fracture-filling material within the Eye-Dashwa granite indicate that the dominant fracture system formed shortly after emplacement and cooling of the pluton at 2678 ± 67 Ma. Subsequent reactivation of these ancient fractures was accompanied by sequentially younger and lower temperature filling materials. These reopened ancient fractures are best developed in the upper 300-400 m of the rock mass and are commonly conduits for present-day groundwater flow. Multiple linear regression analysis performed on the geological variables identified a highly significant correlation between a number of these variable and hydraulic conductivity values measured in 25 m test sections of the boreholes. The predictive capability of the regression design was tested with seven new test data and found to be a valid estimator of the hydrogeological conditions

  7. A 17 Ma onset for the post-collisional K-rich calc-alkaline magmatism in the Maghrebides: Evidence from Bougaroun (northeastern Algeria) and geodynamic implications

    Science.gov (United States)

    Abbassene, Fatiha; Chazot, Gilles; Bellon, Hervé; Bruguier, Olivier; Ouabadi, Aziouz; Maury, René C.; Déverchére, Jacques; Bosch, Delphine; Monié, Patrick

    2016-04-01

    Bougaroun is the largest pluton (~ 200 km2) in the 1200 km-long Neogene magmatic belt located along the Mediterranean coast of Maghreb. New U-Pb dating on zircons and K-Ar ages on whole rocks and separated minerals document its emplacement at 17 Ma within the Lesser Kabylian basement, a continental block that collided with the African margin during the Neogene. This Upper Burdigalian intrusion is therefore the oldest presently identified K-rich calc-alkaline massif in the whole Maghrebides magmatic lineament and marks the onset of its activity. The Bougaroun peraluminous felsic rocks display a very strong crustal imprint. Associated mafic rocks (LREE-enriched gabbros) have preserved the "orogenic" (subduction-related) geochemical signature of their mantle source. Older depleted gabbros cropping out at Cap Bougaroun are devoid of clear subduction-related imprint and yielded Ar-Ar hornblende ages of 27.0 ± 3.0 Ma and 23.3 ± 3.2 Ma. We suggest that they are related to the Upper Oligocene back-arc rifted margin and Early Miocene oceanic crust formation of the nearby Jijel basin, an extension of the Algerian basin developed during the African (Tethyan) slab rollback. The fact that the Bougaroun pluton intrudes exhumed Kabylian lower crustal units, mantle slices and flysch nappes indicates that the Kabylian margin was already stretched and in a post-collisional setting at 17 Ma. We propose a tectono-magmatic model involving an Early Miocene Tethyan slab breakoff combined with delamination of the edges of the African and Kabylian continental lithospheres. At 17 Ma, the asthenospheric thermal flux upwelling through the slab tear induced the thermal erosion of the Kabylian lithospheric mantle metasomatized during the previous subduction event and triggered its partial melting. We attribute the strong trace element and isotopic crustal signature of Bougaroun felsic rocks to extensive interactions between ascending mafic melts and the African crust underthrust beneath the

  8. Sr and Pb isotopic geochemistry of feldspars and implications for the growth of megacrysts in plutonic settings.

    Science.gov (United States)

    Munnikhuis, J.; Glazner, A. F.; Coleman, D. S.; Mills, R. D.

    2015-12-01

    Why megacrystic textures develop in silicic igneous rocks is still unknown. One hypothesis is that these crystals nucleate early in a magma chamber with a high liquid content. A supportive observation of this hypothesis is areas in plutons with high concentrations of megacrysts suggesting flow sorting. Another group of hypotheses suggest megacrystic textures form during protracted late-stage coarsening in a low-melt, interlocked matrix due to either thermal oscillations from incremental pluton emplacement, or Ostwald ripening. Isotopic analyses of large, euhedral K-feldspar megacrysts from the Cretaceous intrusive suites of the Sierra Nevada batholith (SNB) provide new insight into their origin. Megacrysts from the SNB reach the decimeter scale, are Or rich (85-90%), are perthitic, and host mineral inclusions of nearly all phases in the host rock. In-situ micro-drilling of transects, from core to rim, of the alkali feldspars provides material for Sr and Pb isotopic analyses by thermal ionization mass spectrometry (TIMS). Preliminary 87Sr/86Sr(i) isotopic data from samples from the Cathedral Peak Granodiorite, of the Tuolumne Intrusive Suite range from 0.706337 to 0.706452 (~1.6ɛSr) near the cores, whereas a sawtooth pattern with larger variability, 0.706179 to 0.706533 (~5ɛSr), occurs nears the rims. We interpret these preliminary data to indicate that the late portion of growth (i.e. crystal rim) was dominated by either cannibalism of small K-feldspar crystals with isotopic variability, or by addition of isotopically diverse late components to the magma. By comparing the Sr and Pb isotopic stratigraphy of megacrysts from a variety of rock matrices and different granitoids in the SNB isotopic trends can be evaluated to determine if crystals sizes are dependent on disequilibrium processes or grow at a steady state.

  9. PLUTON: Three-group neutronic code for burnup analysis of isotope generation and depletion in highly irradiated LWR fuel rods

    International Nuclear Information System (INIS)

    PLUTON is a three-group neutronic code analyzing, as functions of time and burnup, the change of radial profiles, together with average values, of power density, burnup, concentration of trans-uranium elements, plutonium buildup, depletion of fissile elements, and fission product generation in water reactor fuel rod with standard UO2, UO2-Gd2O3, inhomogeneous MOX, and UO2-ThO2. The PLUTON code, which has been designed to be run on Windows PC, has adopted a theoretical shape function of neutron attenuation in pellet, which enables users to perform a very fast and accurate calculation easily. The present code includes the irradiation conditions of the Halden Reactor which gives verification data for the code. The total list of trans-uranium elements included in the calculations consists of 92U233-239, 93Np237-239, 94Pu238-243, 95Am241-244 (including isomers), and 96Cm242-245. Poisoning fission products are represented by 54Xe131,133,135, 48Cd113, 62Sm149,151,152, 64Gd154-160, 63Eu153,155, 36Kr83,85, 42Mo95, 43Tc99, 45Rh103, 47Ag109, 53I127,129,131, 55Cs133, 57La139, 59Pr141, 60Nd143-150, 61Pm147. Fission gases and volatiles included in the code are 36Kr83-86, 54Xe129-136, 52Te125-130, 53I127-131, 55Cs133-137, and 56Ba135-140. Verification has been performed up to 83 GWd/tU, and a satisfactory agreement has been obtained. (author)

  10. Updated paleomagnetic pole from Cretaceous plutonic rocks of the Sierra Nevada, California: Tectonic displacement of the Sierra Nevada block

    Science.gov (United States)

    Hillhouse, J.W.; Gromme, S.

    2011-01-01

    We report remanent magnetization measurements from 13 sites in Cretaceous plutonic rocks in the northern Sierra Nevada (38??N-39.5??N). By increasing the number of available paleomagnetic sites, the new data tighten constraints on the displacement history of the Sierra Nevada block and its pre-extensional position relative to interior North America. We collected samples in freshly exposed outcrops along four highway transects. The rocks include diorite, granodiorite, and tonalite with potassium-argon ages (hornblende) ranging from 100 Ma to 83 Ma. By combining our results with previous paleomagnetic determinations from the central and southern Sierra Nevada (excluding sites from the rotated southern tip east of the White Wolf-Kern Canyon fault system), we find a mean paleomagnetic pole of 70.5??N, 188.2??E, A95 = 2.6?? (N = 26, Fisher concentration parameter, K = 118). Thermal demagnetization indicates that the characteristic remanence is generally unblocked in a narrow range within 35 ??C of the Curie temperature of pure magnetite. Small apparent polar wander during the Cretaceous normal-polarity superchron, plus prolonged acquisition of remanence at the site level, may account for the low dispersion of virtual geomagnetic poles and relatively large K value. Tilt estimates based on overlapping sediments, stream gradients, and thermochronology of the Sierra Nevada plutons vary from 0?? to 3?? down to the southwest. Without tilt correction, the mean paleomagnetic pole for the Sierra Nevada is essentially coincident with the North American reference pole during the Cretaceous stillstand (125 Ma to 80 Ma). At 95% confidence, the apparent latitude shift is 1.1?? ?? 3.0?? (positive northward), and the apparent rotation is negligible, 0.0?? ?? 4.7??. Correcting for each degree of tilt, which is limited to 3?? on geologic evidence, increases the rotation anomaly 2.2?? counterclockwise, while the apparent latitude shift remains unchanged. ?? 2011 Geological Society of

  11. Dolomite Dissolution in Alkaline Cementious Media

    Science.gov (United States)

    Mittermayr, Florian; Klammer, Dietmar; Köhler, Stephan; Dietzel, Martin

    2010-05-01

    Chemical alteration of concrete has gained much attention over the past years as many cases of deterioration due to sulphate attack, thaumasite formation (TSA) or alkali silica reactions (ASR) have been reported in various constructions (Schmidt et al, 2009). Much less is known about the so called alkali carbonate reaction (ACR). It is believed that dolomite aggregates can react with the alkalis from the cement, dissolve and form calcite and brucite (Katayama, 2004). Due to very low solubility of dolomite in alkaline solutions this reaction seems doubtful. In this study we are trying to gain new insides about the conditions that can lead to the dissolution of dolomite in concrete. Therefore we investigated concrete samples from Austrian tunnels that show partially dissolved dolomite aggregates. Petrological analysis such as microprobe, SEM and Raman spectroscopy as well as a hydrochemical analysis of interstitial solutions and ground water and modelling with PhreeqC (Parkhurst and Appelo, 1999) are carried out. In addition a series of batch experiments is set up. Modelling approaches by PhreeqC show a thermodynamically possibility in the alkaline range when additional Ca2+ in solution causes dolomite to become more and more undersaturated as calcite gets supersaturated. Interacting ground water is enriched in Ca2+and saturated with respect to gypsum as marine evaporites are found in situ rocks. Furthermore it is more likely that Portlandite (Ca(OH)2) plays a more important role than Na and K in the cement. Portlandite acts as an additional Ca2+ source and is much more abundant than the alkalies. Some interstitial solutions are dominated mainly by Na+ and SO42- and reach concentrations up to 30 g/l TDS. It is believed that solutions can even reach thenardite saturation as efflorescences are found on the tunnel walls. In consequence dolomite solubility increases with increasing ionic strength. pH > 11 further accelerate the process of dedolomitization by the removal

  12. Alkaline pulping of some eucalypts from Sudan.

    Science.gov (United States)

    Khristova, P; Kordsachia, O; Patt, R; Dafaalla, S

    2006-03-01

    Four eucalypts (Eucalyptus camaldulensis, Eucalyptus microtheca, Eucalyptus tereticornis and Eucalyptus citriodora) grown in Sudan were examined for their suitability for pulping and papermaking with different alkaline methods. Their physical, morphological and chemical characteristics are reported. The pulping trials with E. citriodora and E. tereticornis were carried out using the kraft-AQ, soda-AQ, modified AS/AQ (ASA), ASAM and kraft methods. For the other two species, only the ASAM and the kraft process were applied. ASAM pulping gave the best results in terms of yield, degree of delignification, mechanical and optical pulp properties. The best pulps, obtained in kraft and ASAM cooking of E. citriodora, were bleached to 88% ISO brightness in a totally chlorine free bleaching sequence (OQ1O/PQ2P). The bleached pulps, especially the ASAM pulp, showed good papermaking properties and would be suitable for manufacture of writing and printing grades of paper. PMID:15935655

  13. Corrosion of copper in alkaline chloride environments

    International Nuclear Information System (INIS)

    The available literature information on the corrosion and electrochemical behaviour of copper in alkaline environments has been reviewed. The purpose of the review was to assess the impact of an alkaline plume from cementitious material on the corrosion behaviour of a copper canister in an SKB-3 type repository. The effect of the evolution of the environmental conditions within the repository have been considered, including the effects of temperature, redox conditions, pore-water salinity and pH. If the pore-water pH increases prior to the establishment of anoxic conditions, the canister surface will passivate as the pore-water pH exceeds a value of ∼ pH 9. Passivation will result from the formation of a duplex Cu2O/Cu(OH)2 film. The corrosion potential will be determined by the equilibrium potential for the Cu2O/Cu(OH)2 couple under oxic conditions, or by the Cu/Cu2O redox couple under anoxic conditions (in the absence of sulphide). Pitting corrosion is only likely to occur early in the evolution of the repository environment, whilst the canister is still relatively cool (2 available to support localised corrosion, and prior to the increase in pore-water pH and salinity. The subsequent increase in canister surface temperature, pore-water pH and salinity, and decrease in O2 will make pit initiation less likely, although the canister will remain passive provided the pore-water pH is maintained above pH 9. The higher the pore-water pH, the more strongly the canister is passivated and the less likely the surface is to undergo localised attack. If the pore-water salinity increases prior to the increase in pH, there could be a period of active canister corrosion before passivation occurs.Under these circumstances, the corrosion potential will be a true mixed potential, determine by the relative kinetics of Cu dissolution as CuCl2 - and of the reduction of O2. The development of anoxic conditions and an increase in pore-water sulphide concentration will result in

  14. Hydrogen in aluminum during alkaline corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Adhikari, Saikat; Ai, Jiahe [Department of Chemical and Biological Engineering, Iowa State University, Ames, IA 50011 (United States); Hebert, Kurt R., E-mail: krhebert@iastate.ed [Department of Chemical and Biological Engineering, Iowa State University, Ames, IA 50011 (United States); Ho, K.M.; Wang, C.Z. [US DOE, Ames Laboratory, Ames, IA 50011 (United States)] [Department of Physics and Astronomy, Iowa State University, Ames, IA 50011 (United States)

    2010-07-30

    The thermodynamic state of hydrogen in aluminum during alkaline corrosion was investigated, using a two-compartment hydrogen permeation cell with an Al/Pd bilayer membrane. The open-circuit potential of the Pd layer in a pH 7.0 buffer solution was monitored to sense the hydrogen chemical potential, {mu}{sub H}. At pH 12.5-13.5, the measurements established a minimum {mu}{sub H} of 0.55 eV relative to the ideal gas reference, equivalent to a H{sub 2} gas pressure of 5.7 GPa. Statistical mechanics calculations show that vacancy-hydrogen defects are stable in Al at this condition. A dissolution mechanism was proposed in which H at very high {mu}{sub H} is produced by oxidation of interfacial aluminum hydride. The mechanism explains the observed rapid accumulation of H in the metal by extensive formation of vacancy-hydrogen defects.

  15. Alkaline lixiviation of uranium in granitic pegmatite

    International Nuclear Information System (INIS)

    The work described herein concerns the determination of the experimental optimum conditions for the alkaline lixiviation of uranium based on the following parameters: time, pH, temperature, density and grane size. The samples were obtained from the Supamo complex, near the Currupia river in the Piar District of the Bolivar State in Venezuela. They have a granitic composition and graphitic texture. The uranium was found in them as a secondary oxidized mineral of green-yellow colour localized in fractures fissures, intergranular spaces and also in the mica as. Secondary uranitite. The lixiviation process was carried out using Na2CO3/NaHCO3 buffer solution and for 100 gr. samples the best values for an efficient process were found by using 170 mesh grane size and 500 ml of pH buffer at 700C for a 24 hour time period. (author)

  16. Polyvinyl alcohol membranes as alkaline battery separators

    Science.gov (United States)

    Sheibley, D. W.; Gonzalez-Sanabria, O.; Manzo, M. A.

    1982-01-01

    Polyvinly alcohol (PVA) cross-linked with aldehyde reagents yields membranes that demonstrate properties that make them suitable for use as alkaline battery separators. Film properties can be controlled by the choice of cross-linker, cross-link density and the method of cross-linking. Three methods of cross-linking and their effects on film properties are discussed. Film properties can also be modified by using a copolymer of vinyl alcohol and acrylic acid as the base for the separator and cross-linking it similarly to the PVA. Fillers can be incorporated into the films to further modify film properties. Results of separator screening tests and cell tests for several variations of PBA films are discussed.

  17. Retention of alkaline earth elements in man

    International Nuclear Information System (INIS)

    The data on human metabolism and long-term retention of alkaline earth elements (133Ba injected into six healthy male volunteers at age 25-81 y and 45Ca and 85Sr received by one healthy male volunteer) are presented. Excreta were collected for 2-3 weeks after injection of the tracer into an antecubital vein. Activity in urine, ashed faeces and early samples of blood plasma was determined by gamma-ray scintillation spectrometry. Whole body retention has been assessed through serial measurements of body radioactivity. The injected 133Ba apparently became mainly skeletal within several days, much earlier than predicted by the ICRP model. The whole-body retention at 32 d ranged from 5 to 14%, the rate of loss correlating with the excretory plasma clearance rate. No age-related trends were identified in the metabolism of Ca and Sr. 2 refs, 2 figs

  18. Enzymatic Hydrolysis of Alkaline Pretreated Coconut Coir

    Directory of Open Access Journals (Sweden)

    Akbarningrum Fatmawati

    2013-06-01

    Full Text Available The purpose of this research is to study the effect of concentration and temperature on the cellulose and lignin content, and the reducing sugars produced in the enzymatic hydrolysis of coconut coir. In this research, the coconut coir is pretreated using 3%, 7%, and 11% NaOH solution at 60oC, 80oC, and 100oC. The pretreated coir were assayed by measuring the amount of cellulose and lignin and then hydrolysed using Celluclast and Novozyme 188 under various temperature (30oC, 40oC, 50oC and pH (3, 4, 5. The hydrolysis results were assayed for the reducing sugar content. The results showed that the alkaline delignification was effective to reduce lignin and to increase the cellulose content of the coir. The best delignification condition was observed at 11% NaOH solution and 100oC which removed 14,53% of lignin and increased the cellulose content up to 50,23%. The best condition of the enzymatic hydrolysis was obtained at 50oC and pH 4 which produced 7,57 gr/L reducing sugar. © 2013 BCREC UNDIP. All rights reservedReceived: 2nd October 2012; Revised: 31st January 2013; Accepted: 6th February 2013[How to Cite: Fatmawati, A., Agustriyanto, R., Liasari, Y. (2013. Enzymatic Hydrolysis of Alkaline Pre-treated Coconut Coir. Bulletin of Chemical Reaction Engineering & Catalysis, 8 (1: 34-39 (doi:10.9767/bcrec.8.1.4048.34-39[Permalink/DOI: http://dx.doi.org/10.9767/bcrec.8.1.4048.34-39] | View in  |

  19. Protective effect of kolaviron, a biflavonoid from Garcinia kola seeds, in brain of Wistar albino rats exposed to gamma-radiation

    International Nuclear Information System (INIS)

    This study was designed to evaluate the protective effect of kolaviron (KV), a biflavonoid from Garcinia kola seeds, against γ-radiation (5 Gy)-induced oxidative stress in brain of Wistar rats. Vitamin C (VC) served as standard antioxidant. Forty-four rats were divided into 4 groups of 11 animals each. One group was un-irradiated (normal), two groups were treated with KV and VC (250 mg/kg) for 6 weeks prior to and 8 weeks after irradiation, and fourth group was only irradiated. Rats were sacrificed 1 and 8 weeks after irradiation. Cellular alterations were monitored using changes in the levels of malondialdehyde (MDA)-an index of lipid peroxidation, superoxide dismutase (SOD), glutathione-S-transferase (GST), reduced glutathione (GSH), catalase (CAT), alanine and aspartate aminotransferases (ALT and AST), urea and creatinine. MDA levels increased significantly (p<0.05) by 90% and 151% after 1 and 8 weeks of irradiation. Furthermore, levels of GSH and antioxidant enzymes were significantly (p<0.05) decreased in γ-irradiated animals. GSH and GST decreased by 61% and 43% after 1 week, and by 75% and 74%, after 8 weeks of exposure, respectively. γ-Irradiation decreased SOD and CAT levels by 53% and 68%, respectively, and caused significant (p<0.05) increases in serum ALT, AST and urea after 8 weeks of exposure. Treatment with KV and VC significantly decreased the levels of MDA, ALT, AST and urea. The antioxidant indices were significantly ameliorated in KV-treated animals. These data suggest that kolaviron may protect against γ-radiation-induced oxidative stress in brain of exposed rats. (author)

  20. Application of IBA to determine the effects of Kolaviron (Garcinia kola) on the elemental metabolism in the rat liver and kidney

    International Nuclear Information System (INIS)

    Full text: Poor or no antioxidant activity has been implicated in the aetiology of various pathologies. Since antioxidants are mostly derived from natural resources, the search for medicinal plants, that can either cure or alleviate ailments, has been phenomenal over the past decades. One plant, Garcinia kola, the oil of which is termed kolaviron, has been identified to have possible antioxidant activity [1]. Trace elements such as Fe, Mn, Cu, Zn and Se, form an integral part in antioxidant activity, especially in organ metabolism. In this study organ (Iiver and kidney) metabolism of major such as C, O, N, S, and trace elements is investigated. The kolaviron was dissolved in corn oil. Two groups (control and experimental) of Wistar rats were selected. The animals were housed in accordance with the WHO animal regulations. Both groups had ad libitum access to standard rat chow and potable tap water. The control group was fed, by gavage, with 200 microlitre of the solution of kolaviron in com oil once per day for a period of 4 weeks. After this period the animals were sacrificed by intraperitoneal injection of pentobarbitone. The organs were excised and homogenised into smaller parts which were freeze-dried - 80 deg C. The freeze-dried organ was then pulverized and press into a palette. Concentrations of trace elements were determined with proton induced X-ray emission (PIXE). PIXE was selected since with this technique concentrations down to minimum detection limits (MDLs) of parts per million (ppm) can be determined. A beam of 3 MeV protons was used for bombardment and a Be filter of 125 micrometer thickness for absorption. Backscattering spectrometry (BS) was used to determine the matrix composition. PIXE and BS measurements were determined simultaneously. Scanning electron microscopy was used both as complementary and supplementary to PIXE and BS. Statistical tests of p < 0.5 were considered significant. 1] Ogada and Braide (2009) Nig. J. Physio. Sci., vol. 24

  1. Application of IBA to determine the effects of Kolaviron (Garcinia kola) on the elemental metabolism in the rat liver and kidney

    Energy Technology Data Exchange (ETDEWEB)

    Mars, J.A.; Kunsevi-Kilola, C.; Gihwala, D. [Department of Biomedical Sciences, Cape Peninsula University of Technology, PO Box 1906, Bellville, 7535 (South Africa)

    2013-07-01

    Full text: Poor or no antioxidant activity has been implicated in the aetiology of various pathologies. Since antioxidants are mostly derived from natural resources, the search for medicinal plants, that can either cure or alleviate ailments, has been phenomenal over the past decades. One plant, Garcinia kola, the oil of which is termed kolaviron, has been identified to have possible antioxidant activity [1]. Trace elements such as Fe, Mn, Cu, Zn and Se, form an integral part in antioxidant activity, especially in organ metabolism. In this study organ (Iiver and kidney) metabolism of major such as C, O, N, S, and trace elements is investigated. The kolaviron was dissolved in corn oil. Two groups (control and experimental) of Wistar rats were selected. The animals were housed in accordance with the WHO animal regulations. Both groups had ad libitum access to standard rat chow and potable tap water. The control group was fed, by gavage, with 200 microlitre of the solution of kolaviron in com oil once per day for a period of 4 weeks. After this period the animals were sacrificed by intraperitoneal injection of pentobarbitone. The organs were excised and homogenised into smaller parts which were freeze-dried - 80 deg C. The freeze-dried organ was then pulverized and press into a palette. Concentrations of trace elements were determined with proton induced X-ray emission (PIXE). PIXE was selected since with this technique concentrations down to minimum detection limits (MDLs) of parts per million (ppm) can be determined. A beam of 3 MeV protons was used for bombardment and a Be filter of 125 micrometer thickness for absorption. Backscattering spectrometry (BS) was used to determine the matrix composition. PIXE and BS measurements were determined simultaneously. Scanning electron microscopy was used both as complementary and supplementary to PIXE and BS. Statistical tests of p < 0.5 were considered significant. 1] Ogada and Braide (2009) Nig. J. Physio. Sci., vol. 24

  2. Facilitated transport of alkaline and alkaline earth metals through liquid membranes with acidic extractants

    International Nuclear Information System (INIS)

    The removal of radioactive Cs and Sr from the liquid waste of nuclear plants is an important problem for both the defense arid the energy industries. Experiments with bulk liquid membranes and liquid membranes, immobilized on porous support, demonstrated the applicability of these systems for active transport of alkaline cations and Sr from alkaline to acidic solution against the concentration gradient of the metal. The mechanism of transport facilitated by fatty acids for alkali metals, or by di-2-ethylhexyl phosphoric acid for Sr in the presence of Ca and EDTA, corresponds to the open-quotes big carrouselclose quotes model, according to which the carrier is distributed between the membrane and aqueous solutions, where metal/H+- ion exchange takes place. The rate limiting step is the reextraction of Sr from the membrane into the acceptor (acidic) solution and is determined by the diffusion of the protonated carrier from the stripping acidic solution through the corresponding unstirred layer

  3. Nucleotide and amino acid sequences of human intestinal alkaline phosphatase: close homology to placental alkaline phosphatase

    International Nuclear Information System (INIS)

    A cDNA clone for human adult intestinal alkaline phosphatase (ALP) [orthophosphoric-monoester phosphohydrolase (alkaline optimum); EC 3.1.3.1] was isolated from a λgt11 expression library. The cDNA insert of this clone is 2513 base pairs in length and contains an open reading frame that encodes a 528-amino acid polypeptide. This deduced polypeptide contains the first 40 amino acids of human intestinal ALP, as determined by direct protein sequencing. Intestinal ALP shows 86.5% amino acid identity to placental (type 1) ALP and 56.6% amino acid identity to liver/bone/kidney ALP. In the 3'-untranslated regions, intestinal and placental ALP cDNAs are 73.5% identical (excluding gaps). The evolution of this multigene enzyme family is discussed

  4. Human placental alkaline phosphatase in liver and intestine

    International Nuclear Information System (INIS)

    Three distinct forms of human alkaline phosphatase, presumably isozymes, are known, each apparently associated with a specific tissue. These are placental, intestinal, and liver (kidney and bone). The authors have used a specific immunoassay and HPLC to show that placental alkaline phosphatase is also present in extracts of liver and intestine in appreciable amounts

  5. Space-time variability of alkalinity in the Mediterranean Sea

    Directory of Open Access Journals (Sweden)

    G. Cossarini

    2014-09-01

    Full Text Available The paper provides a basin assessment of the spatial distribution of ocean alkalinity in the Mediterranean Sea. The assessment is made using a 3-D transport-biogeochemical-carbonate model to integrate the available experimental findings, which also constrains model output. The results indicate that the Mediterranean Sea shows alkalinity values that are much higher than those observed in the Atlantic Ocean on a basin-wide scale. A marked west-to-east surface gradient of alkalinity is reproduced as a response to the terrestrial discharges, the mixing effect with the Atlantic water entering from the Gibraltar Strait and the Black Sea water from Dardanelles, and the surface flux of evaporation minus precipitation. Dense water production in marginal seas (Adriatic and Aegean Seas, where alkaline inputs are relevant, and the Mediterranean thermohaline circulation sustains the west-to-east gradient along the entire water column. In the surface layers, alkalinity has a relevant seasonal cycle (up to 40 μmol kg−1 that is driven both by physical and biological processes. A comparison of alkalinity vs. salinity indicates that different regions present different relationships. In regions of freshwater influence, the two measures are negatively correlated due to riverine alkalinity input, whereas they are positively correlated in open seas. Alkalinity always is much higher than in the Atlantic waters, which might indicate a higher than usual buffering capacity towards ocean acidification, even at high concentrations of dissolved inorganic carbon.

  6. Comparative Detection of Alkaline Protease Production in Exiguobacterium acetylicum

    International Nuclear Information System (INIS)

    Alkaline protease is one of the most important enzymes in industry, medicine, and research. In the present work, a comparative detection for alkaline protease activity was established for instant detection of enzyme activity. Eight different alkalophilic bacterial isolates were compared based on the clear zone they produced on skim milk agar. One strain gave an absolute clear zone in 16 hours and was used for alkaline protease detection. The result of Phenotypic identification using Biology Microlog 3 identified the isolate as Exiguobacterium acetylicum. The isolate under study showed slightly different characteristics from a known Exiguobacterium acetylicum strain. The isolate tolerated alkaline conditions up to ph 11, while good growth was evident at ph 7, the maximum alkaline protease activity was observed at ph 9 which reached up to 109.01 U/ml. The alkaline activity assay using alkaline protease enzyme assay were coordinating with those obtained by conductivity; there was a relevant decrease in conductivity at the maximum increase in enzyme activity, which proved the cell membrane conductivity has a close relation to alkaline protease production. This isolate has tolerated gamma radiation, the increase in dose (up to 4 Gy) gave wider clear zones in terms of diameter and this was relevant to the conductivity measurements

  7. Synergistic degradation of konjac glucomannan by alkaline and thermal method.

    Science.gov (United States)

    Jin, Weiping; Mei, Ting; Wang, Yuntao; Xu, Wei; Li, Jing; Zhou, Bin; Li, Bin

    2014-01-01

    The application of konjac glucomannan (KGM) in the food industry is always limited by its high viscosity. Hereby, low-viscosity KGM was prepared by alkaline-thermal degradation method. This process was demonstrated by the changes of average molecular weight and a kinetic model was developed. The results revealed that high alkalinity and high temperature had a synergetic effect on degradation. The structure of hydrolysates was evaluated by periodate oxidation and their fluidly properties were researched by rheology measurements. The degradation was divided into two regimes. The rate of the first regime (within 1h) is higher than that of the second one (last 1h). It is found that alkaline hydrolysis and deacetylation have a synergistic effect on the degradation under high alkalinity (pH 9.2) and low temperature condition (25 °C). Finally, rheology parameters showed alkaline-thermal degradation is a promising way that can be applied in practice to degrade KGM. PMID:24274506

  8. Phosphatidylinositol anchor of HeLa cell alkaline phosphatase

    International Nuclear Information System (INIS)

    Alkaline phosphatase from cancer cells, HeLa TCRC-1, was biosynthetically labeled with either 3H-fatty acids or [3H]ethanolamine as analyzed by sodium dodecyl sulfate-polyacrylamide gel electrophoresis and fluorography of immunoprecipitated material. Phosphatidylinositol-specific phospholipase C (PI-PLC) released a substantial proportion of the 3H-fatty acid label from immunoaffinity-purified alkaline phosphatase but had no effect on the radioactivity of [3H]ethanolamine-labeled material. PI-PLC also liberated catalytically active alkaline phosphatase from viable cells, and this could be selectively blocked by monoclonal antibodies to alkaline phosphatase. However, the alkaline phosphatase released from 3H-fatty acid labeled cells by PI-PLC was not radioactive. By contrast, treatment with bromelain removed both the 3H-fatty acid and the [3H]ethanolamine label from purified alkaline phosphatase. Subtilisin was also able to remove the [3H]ethanolamine label from the purified alkaline phosphatase. The 3H radioactivity in alkaline phosphatase purified from [3H]ethanolamine-labeled cells comigrated with authentic [3H]ethanolamine by anion-exchange chromatography after acid hydrolysis. The data suggest that the 3H-fatty acid and [3H]ethanolamine are covalently attached to the carboxyl-terminal segment since bromelain and subtilisin both release alkaline phosphatase from the membrane by cleavage at that end of the polypeptide chain. The data are consistent with findings for other proteins recently shown to be anchored in the membrane through a glycosylphosphatidylinositol structure and indicate that a similar structure contributes to the membrane anchoring of alkaline phosphatase

  9. Phosphatidylinositol anchor of HeLa cell alkaline phosphatase

    Energy Technology Data Exchange (ETDEWEB)

    Jemmerson, R.; Low, M.G.

    1987-09-08

    Alkaline phosphatase from cancer cells, HeLa TCRC-1, was biosynthetically labeled with either /sup 3/H-fatty acids or (/sup 3/H)ethanolamine as analyzed by sodium dodecyl sulfate-polyacrylamide gel electrophoresis and fluorography of immunoprecipitated material. Phosphatidylinositol-specific phospholipase C (PI-PLC) released a substantial proportion of the /sup 3/H-fatty acid label from immunoaffinity-purified alkaline phosphatase but had no effect on the radioactivity of (/sup 3/H)ethanolamine-labeled material. PI-PLC also liberated catalytically active alkaline phosphatase from viable cells, and this could be selectively blocked by monoclonal antibodies to alkaline phosphatase. However, the alkaline phosphatase released from /sup 3/H-fatty acid labeled cells by PI-PLC was not radioactive. By contrast, treatment with bromelain removed both the /sup 3/H-fatty acid and the (/sup 3/H)ethanolamine label from purified alkaline phosphatase. Subtilisin was also able to remove the (/sup 3/H)ethanolamine label from the purified alkaline phosphatase. The /sup 3/H radioactivity in alkaline phosphatase purified from (/sup 3/H)ethanolamine-labeled cells comigrated with authentic (/sup 3/H)ethanolamine by anion-exchange chromatography after acid hydrolysis. The data suggest that the /sup 3/H-fatty acid and (/sup 3/H)ethanolamine are covalently attached to the carboxyl-terminal segment since bromelain and subtilisin both release alkaline phosphatase from the membrane by cleavage at that end of the polypeptide chain. The data are consistent with findings for other proteins recently shown to be anchored in the membrane through a glycosylphosphatidylinositol structure and indicate that a similar structure contributes to the membrane anchoring of alkaline phosphatase.

  10. Magnetic anisotropy of the Redenção granite, eastern Amazonian craton (Brazil): Implications for the emplacement of A-type plutons

    Science.gov (United States)

    de Oliveira, Davis Carvalho; Neves, Sérgio Pacheco; Trindade, Ricardo I. F.; Dall'Agnol, Roberto; Mariano, Gorki; Correia, Paulo Barros

    2010-10-01

    A magnetic fabric study was performed on the Redenção pluton in an attempt to understand its emplacement history. The Redenção pluton is part of the 1.88 Ga, anorogenic, A-type Jamon suite that intruded 2.97-2.86 Ga-old Archean granitoids of the Rio Maria Granite-Greenstone Terrane in the eastern Amazonian craton (northern Brazil). Previous gravity survey indicates that the pluton is a 6 km-thick, tabular intrusion. It is characterized by a concentric distribution of facies, with rings of seriated and porphyritic granite that cut across the main facies of even-grained monzogranites. The whole set is intruded by leucogranites that occupy the center of the pluton. Petrographic examination, magnetic susceptibilities, coercivity-spectra and thermomagnetic curves indicate that the magnetic fabric is primarily carried by coarse-grained multidomain magnetite. This is reinforced by the coincidence of magnetic susceptibility and remanence anisotropy principal axes. The absence of solid-state deformation features and the low anisotropy degrees indicate that the magnetic fabric is magmatic in origin. The magnetic fabric displays a systematic pattern, with all facies, including the rings of porphyritic granite, being characterized by concentric, gently dipping foliations associated with gently plunging lineations. Only the central leucogranitic facies shows a slightly discordant pattern with steeply dipping fabrics at its northeastern sector. An emplacement model by vertical stacking of successive magma batches is proposed for the construction of the Redenção pluton, which reconciles the tabular shape of the intrusion, the petrographic and geochemical zoning, and the magnetic fabric pattern. Initially, two magma batches were emplaced as sills. First the even-grained monzogranite, then the seriated and porphyritic granites, which formed by mingling of a leucogranitic melt with the host biotite-monzogranitic magma as attested by geochemical data and field evidence. The

  11. Geochemistry of intrusive rocks associated with the Latir volcanic field, New Mexico, and contrasts between evolution of plutonic and volcanic rocks

    Science.gov (United States)

    Johnson, C.M.; Czamanske, G.K.; Lipman, P.W.

    1989-01-01

    Plutonic rocks associated with the Latir volcanic field comprise three groups: 1) ???25 Ma high-level resurgent plutons composed of monzogranite and silicic metaluminous and peralkaline granite, 2) 23-25 Ma syenogranite, and alkali-feldspar granite intrusions emplaced along the southern caldera margin, and 3) 19-23 Ma granodiorite and granite plutons emplaced south of the caldera. Major-element compositions of both extrusive and intrusive suites in the Latir field are broadly similar; both suites include high-SiO2 rocks with low Ba and Sr, and high Rb, Nb, Th, and U contents. Moreover, both intermediateto siliciccomposition volcanic and plutonic rocks contain abundant accessory sphene and apatite, rich in rare-earth elements (REE), as well as phases in which REE's are essential components. Strong depletion in Y and REE contents, with increasing SiO2 content, in the plutonic rocks indicate a major role for accessory mineral fractionation that is not observed in volcanic rocks of equivalent composition. Considerations of the rheology of granitic magma suggest that accessory-mineral fractionation may occur primarily by filter-pressing evolved magmas from crystal-rich melts. More limited accessory-mineral crystallization and fractionation during evolution of the volcanic magmas may have resulted from markedly lower diffusivities of essential trace elements than major elements. Accessory-mineral fractionation probably becomes most significant at high crystallinities. The contrast in crystallization environments postulated for the extrusive and intrusive rocks may be common to other magmatic systems; the effects are particularly pronounced in highly evolved rocks of the Latir field. High-SiO2 peralkaline porphyry emplaced during resurgence of the Questa caldera represents non-erupted portions of the magma that produced the Amalia Tuff during caldera-forming eruption. The peralkaline porphyry continues compositional and mineralogical trends found in the tuff. Amphibole

  12. Protracted late magmatic stage of the Caleu pluton (central Chile) as a consequence of heat redistribution by diking: Insights from zircon data and thermal modeling

    Science.gov (United States)

    Molina, Pablo G.; Parada, Miguel A.; Gutiérrez, Francisco J.; Ma, Changqian; Li, Jianwei; Yuanyuan, Liu; Reich, Martin; Aravena, Álvaro

    2015-06-01

    Zircon U-Pb geochronology and geochemistry are combined with whole-rock composition and thermal modeling to decipher the late magmatic stage of the composite Cretaceous Caleu pluton, which consists of four lithological zones: Gabbro-Diorite Zone (GDZ), Quartz Monzodiorite Zone (QMDZ), Granodiorite Zone (GZ) and Monzogranite Zone (MGZ). The four lithological zones include felsic dikes and veins of variable thickness and distribution. Zircons of four representative samples, each from the mentioned zones, were dated and chemically analyzed. The U-Pb ages exhibit sample-scale scatter derived from protracted zircon crystallization. At pluton scale the ages are substantially overlapped with a subtle decrease of ages from mafic to felsic sample; the latter has a normal age span distribution with a mean age of 94.68 ± 0.71 (2σ confidence) and a MSWD of 0.95. Zircon grains from the uppermost zone of the pluton, where the QMDZ is emplaced, have the highest REE and HFSE contents. Zircon crystallization temperatures oscillate between 680 and 850 °C, regardless of the zircon age and sample composition. Differences in temperature and age of zircon crystallization of up to 185 °C and 2.6 Myr were identified at sample scale, respectively. Numerical modeling indicates that the melts from which zircon crystallized are highly crystalline (mostly higher than 60% crystal) and resemble MGZ in compositions. Time-dependent thermal models were performed to account for preservation of the system above solidus temperature for long time intervals consistent with those of zircon crystallization. Two non-exclusive scenarios for the late-stage development of Caleu pluton were considered: (i) pluton construction by magma pulses assembled incrementally and (ii) upward transport of residual melts by diking through a mush system to yield heat redistribution to the levels where the samples collected. The first scenario does not preserve residual melts for intervals as long as 2.6 Myr unless an

  13. Source of magma for Elet-Ozero pluton (NE Baltic Shield) - subduction or plume-related material?

    Science.gov (United States)

    Ryabchikov, Igor; Kogarko, Liya

    2016-04-01

    Eletozero pluton is located in the northeastern part of the Karelian Craton, it covers an area of about 100 km2 and cuts through Archaean granite-gneisses. The complex has a concentric zoned structure, the peripheral part being composed of a layered gabbro series; the central area is occupied by nepheline syenites. Mafic and ultramafic rocks in this intrusion often contain potassium feldspar (olivine monzonites and monzonites). Gabbroids are characterized by rhythmic layering expressed in the alternation of leucocratic layers predominantly composed of plagioclase and melanocratic layers with pyroxenes, olivine, titanomagnetite and ilmenite. The rocks of the pluton are enriched in highly incompatible elements by comparison with moderately incompatible elements: average primitive mantle normalized La/Lu ratio is 18.3. At the same time, all the rocks from Elet-Ozero massif including the most primitive ones (high Mg-numbers and high Ni contents) exhibit distinct positive Ba anomaly: mean chondrite normalized Ba/Th ratio is 15.3 (both elements have similar incompatibility-[1]). Enrichment of parent magma in Ba is also confirmed by the presence of high-Ba feldspars and micas in some samples of gabbroids. The most Ba-rich feldspar contains 75% of celsian component: K0.09Na0.04Ca0.008Sr0.04Ba0.75Al1.73Fe0.14Si2.20O8. Ba is a fluid mobile incompatible lithophile element that is probably the most sensitive indicator of subduction fluid addition to the mantle wedge. Thus, positive Ba anomaly suggests input of subduction related component into the source of Elet-Ozero magma. The presence of subduction related material in the lithosphere of Karelian craton has been proposed on the basis of Os isotope studies of mantle xenoliths from Finnish kimberlites [2]. The age of this subduction event is similar to the age of Elet-Ozero pluton. On the other hand, there are certain arguments in favor of connection of Elet-Ozero intrusive complex with mantle plume activity. In particular it

  14. Titratable Acidity and Alkalinity of Red Soil Surfaces

    Institute of Scientific and Technical Information of China (English)

    SHAOZONG-CHEN; HEQUN; 等

    1993-01-01

    The surfaces of red soils have an apparent amphoteric character,carrying titratable acidity and titratable alkalinity simultaneously.The titratable acidity arises from deprotonation of hydroxyl groups of hydrous oxide-type surfaces and dissociation of weak-acid functional groups of soil organic matter,while the titratable alkalinity is derived from release of hydroxyl groups of hydrous oxide-type surfaces.The titratable acidity and titratable alkalinity mainly depended on the composition and content of iron and aluminum oxides in the soils.The results showed that the titratable acidity and titratable alkalinity were in significantly positive correlation not only with the content of amorphous aluminum oxide(Alo) and iron oxide(Feo) extracted with acid ammonium oxalate solution,free iron oxide(Fed) extracted with sodium dithionite-citrate-bicarbonate(DCB) and clays,but also with the zero point of charge (ZPC) of the samples.Organic matter made an important contribution to the titratable acidity.the titratable alkalinity was closely correlated with the amount of fluoride ions adsorbed.The titratable acidity and titratable alkalinity of red soils were influenced by parent materials,being in the order of red soil derived from basalt> that from tuff> that from granite.The titratable acidity and titratable alkalinity ware closely related with origination of the variable charges of red soils,and to a certain extent were responsible for variable negative and positive charges of the soils.

  15. The River Mountains Volcanic Section - Wilson Ridge Pluton, a Long Lived Multiphase Mid- Tertiary Igneous System in Southern Nevada and Northwestern Arizona, USA

    Science.gov (United States)

    Honn, D. K.; Simon, A. C.; Smith, E. I.; Spell, T. L.

    2007-12-01

    206Pb/238U zircon dates (LA-ICPMS) from 106-40 μm spots on 49 zircons suggest the Wilson Ridge Pluton in northwestern Arizona and its corresponding volcanic cover in the River Mountains of southern Nevada represent a complex multiphase igneous system active for 4.2 million years (based on a zircon core-rim pair) to a maximum of 7.2 million years (from two zircon rim dates 18.9 ± 0.8 to 13.1 ± 0.6 Ma). This period of activity is significantly longer than the 500 thousand year interval (12.99 ± 0.02 to 13.45 ± 0.02) determined by 40Ar/39Ar sanidine, biotite, hornblende, and whole rock dates. The 40Ar/39Ar dates only reflect the time when the igneous system cooled to mineral closure temperatures during emplacement in the upper crust. Zircon xenocrysts identified in cathodoluminescence images range in age from 1517.5 ± 11.2 Ma to 21.3 ± 0.8 Ma. Inherited zircon cores are as much as 8.9 million years older than their rims. Zircon dates correspond to pluton stratigraphy with late stage dikes at 15.3 Ma (mean age based on 9 dates), quartz monzonite intermediate in composition and age (mean age 15.5 Ma based on 20 dates), and the oldest unit, the Horsethief Canyon diorite (mean age 17.5 Ma based on 6 dates). Although the mean ages correspond to stratigraphy, the spread of ages for each unit overlaps, therefore these correlations are preliminary. The River Mountains volcanic section lies 20 km to the west of the pluton and may have been separated from it by west directed motion along the Saddle Island detachment fault. The River Mountains volcanic section and the Wilson Ridge Pluton are considered a single igneous system as demonstrated by major and trace element geochemistry, whole rock isotopic analyses (Sr and Nd), previous 40Ar/39Ar and K-Ar dates, mafic enclave chemistry, extensive magnesio-riebeckite alteration unique to both the River Mountains volcanic and Wilson Ridge Plutonic sections, and the location of the Saddle Island fault. Preliminary zircon dates

  16. Lead isotope compositions of Late Cretaceous and early Tertiary igneous rocks and sulfide minerals in Arizona: Implications for the sources of plutons and metals in porphyry copper deposits

    Science.gov (United States)

    Bouse, R.M.; Ruiz, J.; Titley, S.R.; Tosdal, R.M.; Wooden, J.L.

    1999-01-01

    Porphyry copper deposits in Arizona are genetically associated with Late Cretaceous and early Tertiary igneous complexes that consist of older intermediate volcanic rocks and younger intermediate to felsic intrusions. The igneous complexes and their associated porphyry copper deposits were emplaced into an Early Proterozoic basement characterized by different rocks, geologic histories, and isotopic compositions. Lead isotope compositions of the Proterozoic basement rocks define, from northwest to southeast, the Mojave, central Arizona, and southeastern Arizona provinces. Porphyry copper deposits are present in each Pb isotope province. Lead isotope compositions of Late Cretaceous and early Tertiary plutons, together with those of sulfide minerals in porphyry copper deposits and of Proterozoic country rocks, place important constraints on genesis of the magmatic suites and the porphyry copper deposits themselves. The range of age-corrected Pb isotope compositions of plutons in 12 Late Cretaceous and early Tertiary igneous complexes is 206Pb/204Pb = 17.34 to 22.66, 207Pb/204Pb = 15.43 to 15.96, and 208Pb/204Pb = 37.19 to 40.33. These Pb isotope compositions and calculated model Th/U are similar to those of the Proterozoic rocks in which the plutons were emplaced, thereby indicating that Pb in the younger rocks and ore deposits was inherited from the basement rocks and their sources. No Pb isotope differences distinguish Late Cretaceous and early Tertiary igneous complexes that contain large economic porphyry copper deposits from less rich or smaller deposits that have not been considered economic for mining. Lead isotope compositions of Late Cretaceous and early Tertiary plutons and sulfide minerals from 30 metallic mineral districts, furthermore, require that the southeastern Arizona Pb province be divided into two subprovinces. The northern subprovince has generally lower 206Pb/204Pb and higher model Th/U, and the southern subprovince has higher 206Pb/204Pb and

  17. Geochronology and geochemistry of the c. 80 Ma Rutog granitic pluton, northwestern Tibet: Implications for the tectonic evolution of the Lhasa Terrane

    OpenAIRE

    Zhao, TP; Zhou, MF; Zhao, JH; Zhang, KJ; Chen, W.

    2008-01-01

    The Rutog granitic pluton lies in the Gangdese magmatic arc in the westernmost part of the Lhasa Terrane, NW Tibet, and has SHRIMP zircon U-Pb ages of c. 80 Ma. The pluton consists of granodiorite and monzogranite with SiO2 ranging from 62 to 72 wt% and Al2 O3 from 15 to 17 wt%. The rocks contain 2.33-4.93 wt% K2O and 3.42-5.52 wt% Na2O and have Na2O/K2O ratios of 0.74-2.00. Their chondrite-normalized rare earth element (REE) patterns are enriched in LREE ((La/Yb)n = 15 to 26) and do not show...

  18. 2nd Generation alkaline electrolysis. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Yde, L. [Aarhus Univ. Business and Social Science - Centre for Energy Technologies (CET), Aarhus (Denmark); Kjartansdottir, C.K. [Technical Univ. of Denmark. DTU Mechanical Engineering, Kgs. Lyngby (Denmark); Allebrod, F. [Technical Univ. of Denmark. DTU Energy Conversion, DTU Risoe Campus, Roskilde (Denmark)] [and others

    2013-03-15

    The overall purpose of this project has been to contribute to this load management by developing a 2{sup nd} generation of alkaline electrolysis system characterized by being compact, reliable, inexpensive and energy efficient. The specific targets for the project have been to: 1) Increase cell efficiency to more than 88% (according to the higher heating value (HHV)) at a current density of 200 mA /cm{sup 2}; 2) Increase operation temperature to more than 100 degree Celsius to make the cooling energy more valuable; 3) Obtain an operation pressure more than 30 bar hereby minimizing the need for further compression of hydrogen for storage; 4) Improve stack architecture decreasing the price of the stack with at least 50%; 5) Develop a modular design making it easy to customize plants in the size from 20 to 200 kW; 6) Demonstrating a 20 kW 2{sup nd} generation stack in H2College at the campus of Arhus University in Herning. The project has included research and development on three different technology tracks of electrodes; an electrochemical plating, an atmospheric plasma spray (APS) and finally a high temperature and pressure (HTP) track with operating temperature around 250 deg. C and pressure around 40 bar. The results show that all three electrode tracks have reached high energy efficiencies. In the electrochemical plating track a stack efficiency of 86.5% at a current density of 177mA/cm{sup 2} and a temperature of 74.4 deg. C has been shown. The APS track showed cell efficiencies of 97%, however, coatings for the anode side still need to be developed. The HTP cell has reached 100 % electric efficiency operating at 1.5 V (the thermoneutral voltage) with a current density of 1. 1 A/cm{sup 2}. This track only tested small cells in an externally heated laboratory set-up, and thus the thermal loss to surroundings cannot be given. The goal set for the 2{sup nd} generation electrolyser system, has been to generate 30 bar pressure in the cell stack. An obstacle to be

  19. Anodic stripping voltammetry of technetium alkaline media

    International Nuclear Information System (INIS)

    A method of direct determination of technetium in 0.1 M NaOH by anodic stripping voltametry at glassy carbon electrode has been elaborated. The peak height of anodic TcO2(OH)2 dissolution was found to be linearly dependent on preconcentration time, and the concentration of technetium in the range 5.0 * 10-8 -6 M. The detection limit for the Tc determination by ASV technique under study was found to be 5.0 * 10-8 M with standard deviation 5-7% (p2(OH)2 anodic dissolution peak current. Addition of 1.0* 10-6 M U(UI) to the sample solution was found to shift the peak of the TcO2(OH)2 100 mV towards negative direction and disturb the linearity of the calibration curve. Therefore; for a successful application of the developed ASV technique for Tc determination in the alkaline media, uranium should be removed from the analyte before determination

  20. Response of Desulfovibrio vulgaris to Alkaline Stress

    Energy Technology Data Exchange (ETDEWEB)

    Stolyar, S.; He, Q.; He, Z.; Yang, Z.; Borglin, S.E.; Joyner, D.; Huang, K.; Alm, E.; Hazen, T.C.; Zhou, J.; Wall, J.D.; Arkin, A.P.; Stahl, D.A.

    2007-11-30

    The response of exponentially growing Desulfovibrio vulgarisHildenborough to pH 10 stress was studied using oligonucleotidemicroarrays and a study set of mutants with genes suggested by microarraydata to be involved in the alkaline stress response deleted. The datashowed that the response of D. vulgaris to increased pH is generallysimilar to that of Escherichia coli but is apparently controlled byunique regulatory circuits since the alternative sigma factors (sigma Sand sigma E) contributing to this stress response in E. coli appear to beabsent in D. vulgaris. Genes previously reported to be up-regulated in E.coli were up-regulated in D. vulgaris; these genes included three ATPasegenes and a tryptophan synthase gene. Transcription of chaperone andprotease genes (encoding ATP-dependent Clp and La proteases and DnaK) wasalso elevated in D. vulgaris. As in E. coli, genes involved in flagellumsynthesis were down-regulated. The transcriptional data also identifiedregulators, distinct from sigma S and sigma E, that are likely part of aD. vulgaris Hildenborough-specific stress response system.Characterization of a study set of mutants with genes implicated inalkaline stress response deleted confirmed that there was protectiveinvolvement of the sodium/proton antiporter NhaC-2, tryptophanase A, andtwo putative regulators/histidine kinases (DVU0331 andDVU2580).

  1. Magic wavelengths in the alkaline earth ions

    CERN Document Server

    Kaur, Jasmeet; Arora, Bindiya; Sahoo, B K

    2015-01-01

    We present magic wavelengths for the $nS$ - $nP_{1/2,3/2}$ and $nS$ - $mD_{3/2,5/2}$ transitions, with the respective ground and first excited $D$ states principal quantum numbers $n$ and $m$, in the Mg$^+$, Ca$^+$, Sr$^+$ and Ba$^+$ alkaline earth ions for linearly polarized lights by plotting dynamic polarizatbilities of the $nS$, $nP_{1/2,3/2}$ and $mD_{3/2,5/2}$ states of the ions. These dynamic polarizabilities are evaluated by employing a relativistic all-order perturbative method and their accuracies are ratified by comparing their static values with the available high precision experimental or other theoretical results. Moreover, some of the magic wavelengths identified by us in Ca$^+$ concurs with the recent measurements reported in [{\\bf Phys. Rev. Lett. 114, 223001 (2015)}]. Knowledge of these magic wavelengths are propitious to carry out many proposed high precision measurements trapping the above ions in the electric fields with the corresponding frequencies.

  2. Solubility of pllutonium in alkaline salt solutions

    International Nuclear Information System (INIS)

    Plutonium solubility data from several studies have been evaluated. For each data set, a predictive model has been developed where appropriate. In addition, a statistical model and corresponding prediction intervals for plutonium solubility as a quadratic function of the hydroxide concentration have been developed. Because of the wide range of solution compositions, the solubility of plutonium can vary by as much as three orders of magnitude for any given hydroxide concentration and still remain within the prediction interval. Any nuclear safety assessments that depend on the maximum amount of plutonium dissolved in alkaline salt solutions should use concentrations at least as great as the upper prediction limits developed in this study. To increase the confidence in the prediction model, it is recommended that additional solubility tests be conducted at low hydroxide concentrations and with all of the other solution components involved. To validate the model for application to actual waste solutions, it is recommended that the plutonium solubilities in actual waste solutions be determined and compared to the values predicted by the quadratic model

  3. Radioimmunoassay of human intestinal alkaline phosphatase

    International Nuclear Information System (INIS)

    A new method of radioimmunoassay using the double antibody method for human intestinal alkaline phosphatase (ALP) was first elaborated. The following results were obtained: 1) In this system, the optimal antibody concentration is 10,000 times the dilution of the original anti-serum, and the optimal assay range is 0.5 to 25 ng. Enzymatic activity of 1 ng intestinal ALP is 4.1 King-Armstrong units. 2) In this system, the sera including intestinal ALP are divided to two groups. One group shows a dose response curve similar to that of purified intestinal ALP, and the other shows a lesser one. This reason is not clear. Hepatic ALP, osseous ALP and placental ALP in the sera show no response in this system. 3) In this system, the B/T value of 50 μg of purified human placental ALP is almost equal to 1 ng of purified human intestinal ALP. Similarly, the B/T value of 50 μg of purified human intestinal ALP is equal to almost 5 ng of purified human placental ALP. This shows that cross-reaction exists between intestinal and placental ALPs at high concentrations. (J.P.N.)

  4. Revisiting zinc passivation in alkaline solutions

    International Nuclear Information System (INIS)

    Highlights: • Zinc passive films were characterised by electrochemical tests coupled with cross sectional FIB-SEM. • Passive layers at pH > 12 comprised of an outer precipitated layer and inner compact oxide. • The electrolyte pH influences the nature/stability of the outer precipitated layer and this impacts the passive state on zinc. • The precipitated layers on zinc at pH 12 support cathode reactions and catalyse oxide growth. -- Abstract: Passive films nominally consist of an inner compact oxide and the outer precipitated layer. In the case of zinc (Zn), the outer layer is mainly precipitated ZnO/Zn(OH)2. Electrolyte pH controls the stability of the outer precipitated layer. In a pH 13 solution, formation of soluble Zn(OH)3− and Zn(OH)42− phases render the precipitated layer unstable increasing zinc corrosion, whereas at pH 12, the precipitated layer (ZnO/Zn(OH)2) is more stable making it an effective anodic barrier upon zinc. These precipitated oxides formed at pH 12 support cathodic reactions on their surface which in turn catalyse further oxide growth by a cathodically driven process. Focused ion beam-scanning electron microscopy (FIB-SEM) was used to support some of the electrochemical assertions, revealing the form and morphology of the passive layers that grow upon zinc exposed to alkaline solutions

  5. Alkaline lipase of glyoxysomes is a glycoprotein

    International Nuclear Information System (INIS)

    In castor bean endosperm, the glyoxysomal alkaline lipase is an intrinsic membrane protein. At four days post-germination, the enzyme is also present in the endoplasmic reticulum where it accounts for approximately 15% of total activity. The active enzyme was purified by Maeshima and Beevers from isolated glyoxysomes. Specific antibodies to the 62 kD subunit were raised in rabbits. The anti-lipase has been used in preliminary experiments to determine the relationship between the lipase of the glyoxysomal membrane and the ER. Results indicate the presence of 3 cross-reacting antigens in carbonate-washed ER and glyoxysomal membranes. The 62 kD subunit, found predominantly in glyoxysomes, was eluted form Con-A Sepharose by 0.5 M α-methylglucoside. An 86kD form present in 2-d ER (but not in 4-d ER) and glyoxysomes did not bind Con-A Sepharose. This form appears to be an unglycosylated precursor or the 62 kD subunit. A 67 kD form was the only species seen in 4-d ER. In a time course experiment, the 67 kD form appeared on the glyoxysomal membrane

  6. PLUTON: Three-group neutronic code for burnup analysis of isotope generation and depletion in highly irradiated LWR fuel rods

    Energy Technology Data Exchange (ETDEWEB)

    Lemehov, Sergei E; Suzuki, Motoe [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2001-08-01

    PLUTON is a three-group neutronic code analyzing, as functions of time and burnup, the change of radial profiles, together with average values, of power density, burnup, concentration of trans-uranium elements, plutonium buildup, depletion of fissile elements, and fission product generation in water reactor fuel rod with standard UO{sub 2}, UO{sub 2}-Gd{sub 2}O{sub 3}, inhomogeneous MOX, and UO{sub 2}-ThO{sub 2}. The PLUTON code, which has been designed to be run on Windows PC, has adopted a theoretical shape function of neutron attenuation in pellet, which enables users to perform a very fast and accurate calculation easily. The present code includes the irradiation conditions of the Halden Reactor which gives verification data for the code. The total list of trans-uranium elements included in the calculations consists of {sub 92}U{sup 233-239}, {sub 93}Np{sup 237-239}, {sub 94}Pu{sup 238-243}, {sub 95}Am{sup 241-244} (including isomers), and {sub 96}Cm{sup 242-245}. Poisoning fission products are represented by {sub 54}Xe{sup 131,133,135}, {sub 48}Cd{sup 113}, {sub 62}Sm{sup 149,151,152}, {sub 64}Gd{sup 154-160}, {sub 63}Eu{sup 153,155}, {sub 36}Kr{sup 83,85}, {sub 42}Mo{sup 95}, {sub 43}Tc{sup 99}, {sub 45}Rh{sup 103}, {sub 47}Ag{sup 109}, {sub 53}I{sup 127,129,131}, {sub 55}Cs{sup 133}, {sub 57}La{sup 139}, {sub 59}Pr{sup 141}, {sub 60}Nd{sup 143-150}, {sub 61}Pm{sup 147}. Fission gases and volatiles included in the code are {sub 36}Kr{sup 83-86}, {sub 54}Xe{sup 129-136}, {sub 52}Te{sup 125-130}, {sub 53}I{sup 127-131}, {sub 55}Cs{sup 133-137}, and {sub 56}Ba{sup 135-140}. Verification has been performed up to 83 GWd/tU, and a satisfactory agreement has been obtained. (author)

  7. Mid-Miocene Rhyolite Sequence, Highland Range, NV: Record of Magma Evolution and Eruption From the Searchlight Pluton Magma Chamber

    Science.gov (United States)

    Colombini, L. L.; Gualda, G. A.; Miller, C. F.; Faulds, J.; Miller, J.; Wooden, J.; Mazdab, F.

    2008-12-01

    The Highland Range in southern Nevada contains a ~3 km-thick sequence of pre- to synextensional volcanic rock that records both large-magnitude Miocene extension and the evolution of large magma system. The volcanic sequence and probable source pluton are both well-exposed in a steeply W-tilted fault block (Faulds et al. 2002). A km-thick sequence of rhyolite in the southeast part of the range was emplaced above a thick section of trachyandesite and trachydacite at 16.2-16.0 Ma (SHRIMP zircon U-Pb, biotite Ar/Ar; Faulds et al 2002, J Miller et al 2007, new data). The lower half of the sequence comprises low-SiO2 rhyolite lavas (plag + biotite + cpx phenocrysts), which abruptly give way to tuffs and inter-fingered lavas (qtz + san + plag + bio + cpx + sphene) that mark a transition to a more explosive period of eruption of more evolved rhyolite plus active mafic input. Throughout the rhyolite sequence, mafic enclaves are abundant, changing from brittle fragments (lithics) in the lower lavas to quenched, crenulate-bordered magmatic enclaves in upper lavas and tuffs. Xenocrysts of reacted olivine, pyroxene, and plagioclase are evident in some rhyolites. The uppermost unit of the sequence is a quartz + sanidine-bearing lava that is heavily contaminated on all scales by mafic enclaves, lithics, and xenocrysts. Basaltic trachyandesite overlies this upper rhyolite. SHRIMP analysis of Ti and other trace elements in zircon from two samples near the top of the sequence documents strongly fluctuating T (720-920 C) and evolution of melt compositions; for the most part, rims grew at lower T from more evolved melt. Zr-in-sphene thermometry indicates that these phenocrysts grew at the lower temperatures recorded by the zircon rims. The rhyolite sequence appears to have erupted from the middle granite zone of the nearby Searchlight pluton, which is the same age and similarly evolved toward highly silicic compositions, records co-injection of mafic magma, and overlies slightly

  8. Characterizing fractured plutonic rocks of the Canadian shield for deep geological disposal of Canada`s radioactive wastes

    Energy Technology Data Exchange (ETDEWEB)

    Lodha, G.S.; Davison, C.C.; Gascoyne, M. [Atomic Energy of Canada Ltd. , Pinawa, MB (Canada). Whiteshell Labs.

    1998-09-01

    Since 1978 AECL has been investigating plutonic rocks of the Canadian Shield as a potential medium for the disposal of Canada`s nuclear fuel waste. During the last two years this study has been continued as part of Ontario Hydro`s used fuel disposal program. Methods have been developed for characterizing the geotechnical conditions at the regional scale of the Canadian Shield as well as for characterizing conditions at the site scale and the very near-field scale needed for locating and designing disposal vault rooms and waste emplacement areas. The Whiteshell Research Area (WRA) and the Underground Research Laboratory (URL) in southeastern Manitoba have been extensively used to develop and demonstrate the different scales of characterization methods. At the regional scale, airborne magnetic and electromagnetic surveys combined with LANDSAT 5 and surface gravity survey data have been helpful in identifying boundaries of the plutonic rocks , overburden thicknesses, major lineaments that might be geological structures, lithological contacts and depths of the batholiths. Surface geological mapping of exposed rock outcrops, combined with surface VLF/EM, radar and seismic reflection surveys were useful in identifying the orientation and depth continuity of low-dipping fracture zones beneath rock outcrops to a depth of 500 to 1000 m. The surface time-domain EM method has provided encouraging results for identifying the depth of highly saline pore waters. The regional site scale investigations at the WRA included the drilling of twenty deep boreholes (> 500 m) at seven separate study areas. Geological core logging combined with borehole geophysical logging, TV/ATV logging, flowmeter logging and full waveform sonic logging in these boreholes helped to confirm the location of hydro geologically important fractures, orient cores and infer the relative permeability of some fracture zones. Single-hole radar and crosshole seismic tomography surveys were useful to establish the

  9. Geochemical and geochronologic analysis of the plutonic basement of the Tacaná Volcano Complex, Chiapas México.

    Science.gov (United States)

    Paul William, L.

    2006-12-01

    The Tacana Volcano Complex (TVC) is located on the border between the State of Chiapas, southern Mexico, and Guatemala. This volcanic complex has been described as the last volcano in the northwest part of the Central American Volcanic Arc (CAVA). The region where the TVC was emplaced is influenced by the transpressional boundary formed by the shear movement between the North American and Caribbean Plates and the compressive stress by the subduction of the Cocos Plate under the North American Plate. The most recently study about TVC was by García-Palomo et al. (2004), who summarized the chronology of the TVC from basement formation to its recent activity and report that the active TVC lies on igneous basement rocks that were formed by two magmatic processes during the Mesozoic and Cenozoic. In this work, we present the results of detailed petrographic, geochemical and geochronologic analyses obtained from plutonic rocks in the basement of the TVC zone. The results show that t this basement (granites: SiO2 of 64.64 to 65.29 wt%, granodiorites: SiO2 of 60.18 wt%, and gabbros: SiO2 of 51.67 wt%) belongs to the suite of plutonic rocks of an orogenic environment. The granites are classified as both S-type peraluminosus granites derived form partial melting of continental crust, characterized by minerals such as quartz, k-feldspar, biotite, hornblende and some Fe-Ti oxides and I-type metaluminous granites derived from subduction processes with the main mineral phases being quartz, k-feldspar, hornblende, biotite and Fe-Ti oxides. The ages thus far obtained (K- Ma to 12.65 +/- 0.08 Ma) suggest that there were at least nine periods of magmatic activity that produced granitic and mafic magmas. Reference: Garcia-Palomo, A., Macias, J.L., Arce, J.L., Mora, J.C., Hughes, S., Saucedo, R., Espindola, J.M., Escobar, R., and Layer, P., (2004). GSA Special Paper 412, p 39-57.

  10. Contrasting response of accessory ilmenite and magnetite to magma mixing and postmagmatic alteration in Petrohan pluton, Western Balkan, Bulgaria

    International Nuclear Information System (INIS)

    Series of representative samples of granodiorite, diorite, hybrid diorite, hybrid gabbro and mafic magmatic enclaves (MME) from Petrohan pluton, Western Balkan, Bulgaria, were chosen to clarify the effects of magma mingling and mixing and postmagmatic alteration onto the chemical composition, microstructure and stability of accessory magnetite and ilmenite. Although the two oxide phases were found to crystallize simultaneously – after and, probably, during the mixing of magmas as late magmatic minerals, they demonstrated much contrasted behaviour during magmatic and postmagmatic processes. In all the studied rocks, magnetite occurs in the form of well-preserved homogeneous crystals with sporadic, very fine exsolutions of ulvöspinel and coarser oxy-exsolutions of ilmenite. The microstructure of accessory ilmenite in the rocks is more complicated, being a result of several post-magma-mixing processes: (i) prevailing part of the ilmenite grains has relic outlook due to intensive replacement by late-magmatic and postmagmatic titanite; (ii) each ilmenite grain contains numerous micro- and nanoscale hematite exsolutions distributed parallel to (0001) crystallographic plane of ilmenite; (iii) significant part of the ilmenite grains is locally decomposed into hematite and rutile as a result of postmagmatic oxidation alteration. Magnetite from different rocks does not show any essential differences in its chemical composition: the most important minor elements in the mineral as Al, Ti and V vary in similar ranges (Al2O3 -0.3–0.9 wt.%, TiO2 – 0.5–1.4 wt. %, V2O3 – 0.1–0.45 wt. %). The composition of ilmenite grains (point analyses of ilmenite and area analyses of ilmenite with hematite exsolutions) is more variable and reflects effects of magma mixing – similar range of Fe3+ content (5–18 mol.% of Fe2O3) and anomalously high content of Mn (∼40 mol.% of MnTiO3) in part of ilmenite grains of hybrid diorite as well as the specific influence of the chemical

  11. The aluminum chemistry and corrosion in alkaline solutions

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Jinsuo [International Nuclear System Engineering, MS-K 575, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)], E-mail: jszhang@lanl.gov; Klasky, Marc; Letellier, Bruce C. [International Nuclear System Engineering, MS-K 575, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2009-02-15

    Aluminum-alkaline solution systems are very common in engineering applications including nuclear engineering. Consequently, a thorough knowledge of the chemistry of aluminum and susceptibility to corrosion in alkaline solutions is reviewed. The aluminum corrosion mechanism and corrosion rate are examined based on current experimental data. A review of the phase transitions with aging time and change of environment is also performed. Particular attention is given to effect of organic and inorganic ions. As an example, the effect of boron is examined in detail because of the application in nuclear reactor power systems. Methods on how to reduce the corrosion rate of aluminum in alkaline solutions are also highlighted.

  12. The Early Andean Magmatic Province (EAMP): 40Ar/ 39Ar dating on Mesozoic volcanic and plutonic rocks from the Coastal Cordillera, northern Chile

    Science.gov (United States)

    Oliveros, Verónica; Féraud, Gilbert; Aguirre, Luis; Fornari, Michel; Morata, Diego

    2006-10-01

    The Early Andean Magmatic Province (EAMP), consists of about 150 000 km 3 of volcanic and plutonic units in the Coastal Cordillera of northern Chile and southern Peru and represents a major magmatic Mesozoic event in the world, for which the precise age of the thick volcanic series was unknown. Thirty 40Ar/ 39Ar analyses were carried out on primary mineral phases of volcanic and plutonic rocks from northern Chile (18°30'-24°S). Reliable plateau and "mini plateau" ages were obtained on plagioclase, amphibole and biotite from volcanic and plutonic rocks, despite widespread strong alteration degree. In the Arica, Tocopilla and Antofagasta (700 km apart) regions, the ages obtained on lava flows constrain the volcanic activity between 164 and 150 Ma and no N-S migration of volcanism is observed. The uppermost lava flows of the volcanic sequence at the type locality of the La Negra Formation extruded at ca. 153-150 Ma, suggesting the end of the volcanic activity of the arc at that time. The oldest volcanic activity occurred probably at ca. 175-170 Ma in the Iquique area, although no plateau age could be obtained. The plutonic bodies of the same regions were dated between ca. 160 and 142 Ma, indicating that they were partly contemporaneous with the volcanic activity. At least one volcanic pulse around 160 Ma is evidenced over the entire investigated reach of the EAMP, according to the ages found in Arica, Tocopilla, Michilla and Mantos Blancos regions. The episodic emplacement of huge amounts of subduction related volcanism is observed throughout the whole Andean history and particularly during the Jurassic (southern Peru, northern Chile and southern Argentina). These events probably correspond to periodic extensional geodynamic episodes, as a consequence of particular subduction conditions, such as change of obliquity of the convergence, change in the subduction angle, slab roll back effect or lower convergence rate, that remain to be precisely defined.

  13. Age and isotopic fingerprints of some plutonic rocks in the Wiborg rapakivi granite batholith with special reference to the dark wiborgite of the Ristisaari Island

    OpenAIRE

    Rämö, O.T.; Turkki, V.; Mänttäri, I.; Heinonen, A; Larjamo, K.; Lahaye, J.

    2014-01-01

    The mid-Proterozoic, locus classicus Wiborg rapakivi granite batholith of southeastern Finland and adjacent Russia comprises a varying, bimodal (silicic-basic) sequence of plutonic, subvolcanic, and volcanic rocks. At the current level of erosion silicic rocks are dominant, the most prominent of which are wiborgites and dark wiborgites (that have been considered to mark the main build-up stage of the batholith) and pyterlites. New observations and optical microscopy data from the dark wiborgi...

  14. Country rock contamination of marginal mafic granulites bordering the Nain Plutonic Suite : implications for mobilization of Sr during high-grade contact metamorphism

    OpenAIRE

    Royse, Katherine; Noble, Stephen; Tarney, John; Cadman, Andy

    1999-01-01

    The marginal mafic granulites that locally border the Nain Plutonic Suite (NPS) have a range of initial Nd-isotope ratios that overlap with that of the NPS anorthosites and associated Nain dykes. The similarity in Nd-isotope data suggests that gneissic Archaean country rocks have contaminated all the anorthosites, marginal mafic granulites, and dykes. Sr-isotope data for the mafic granulites and dykes support a country rock contamination scenario but preclude wholesale assimilation of rocks s...

  15. Petrology of the Post-Collisional, Within-Plate Yıldızdağ Gabbroic Pluton, Yıldızeli-Sivas Region, Central Anatolia, Turkey

    OpenAIRE

    BOZTUĞ, DURMUŞ; YAĞMUR, Mustafa; OTLU, Nazmi; YEŞİLTAŞ, Sibel TATAR and Akif

    1998-01-01

    The Yildizdag gabbroic pluton intrudes the Paleocene-Eocene Yakupoğlan formation which is imbricated with the ophiolitic melange of the northern branch of the Neo-Tethyan ocean, and the crustal metasediments of Kırsehir block or Central Anatolian Crystalline Complex. It is subdivided into some mapable subunits such as gabbroic main body, dioritic marginal facies and microdioritic dykes. Mineralogical-geochemical (major, some trace and REE) data reveal that the magnetite + olivine + augite ...

  16. Geophysical exploration of disseminated and stockwork deposits associated with plutonic intrusive rock: a case study on the eastern flank of colombia’s western cordillera

    OpenAIRE

    Hernández Pardo Orlando; Gretta C; Alexander E; Iraida M; Pintor B

    2012-01-01

    Disseminated deposits are low-grade, large tonnage deposits which are mainly mined for gold, copper, molybdenum and tin. These deposits are normally associated with intermediate to acid plutonic intrusive rocks and all are characterized by intense, extensive hydrothermal alteration of host rocks. Disseminated deposit exploration in the tropics suffers from difficult geological mapping due to dense vegetation, lack of rock outcrops and extensive but variable saprolytic weathering. Geo...

  17. Geochemistry and U-Pb zircon ages of plutonic rocks from the Algodões granite-greenstone terrane, Troia Massif, northern Borborema Province, Brazil: Implications for Paleoproterozoic subduction-accretion processes

    Science.gov (United States)

    Costa, Felipe Grandjean da; Palheta, Edney Smith de Moraes; Rodrigues, Joseneusa Brilhante; Gomes, Iaponira Paiva; Vasconcelos, Antonio Maurilio

    2015-04-01

    The Algodões metavolcano-sedimentary sequence is located at the northern margin of the Archean/Paleoproterozoic Troia Massif, northern Borborema Province (NE Brazil). It represents a well-preserved Paleoproterozoic greenstone-like sequence affected by two major plutonic events. The early plutonism, represented by the Cipó orthogneisses, mainly comprises biotite-bearing metatonalites, which share similar geochemical signatures with Archean tonalite-trondjhemite-granodiorite (TTG). For these rocks, we report U-Pb (LA-ICPMS) zircon ages of 2189 ± 14 Ma and 2180 ± 15 Ma. A subsequent plutonic magmatism occurred at ˜2150-2130 Ma and is mainly represented by hornblende-bearing dioritic to tonalitic orthogneisses of the Madalena Suite and São José da Macaoca Complex. Geochemical data indicate that these dioritic/tonalitic orthogneisses have adakitic characteristics and strongly suggest mantle-related magmas. A (sensu stricto) granite plutonism (Serra da Palha orthogneisses) also intruded the Algodões sequence and yielded U-Pb (LA-ICPMS) zircon age of 2150 ± 16 Ma. These granitic orthogneisses show high-K content, A-type characteristics and probably derived from partial melting of a crustal (tonalitic) source. We suggest that the early ˜2190-2160 Ma TTG plutons probably developed in intra-oceanic arc setting, whereas the following ˜2150-2130 Ma adakitic plutons and A-type granitic magmatism developed in response to arc-continent collision.

  18. Aeolus or Pluton?; Eole ou pluton?

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    2003-07-01

    In the next years the french government will have to take great decisions in matter of energy and specifically electric power. This report aims to give an estimation of wind power channel in France supposing financial possibilities equivalent to those implemented for the EPR (European Pressurized Reactor) channel. After a presentation of the electric power industry in France, the two channels are compared. (A.L.B.)

  19. Petrogenesis of the Mesozoic Zijinguan mafic pluton from the Taihang Mountains, North China Craton: Petrological and Os-Nd-Sr isotopic constraints

    Science.gov (United States)

    Liu, An-Kun; Chen, Bin; Suzuki, Katsuhiko; Liu, Ling

    2010-09-01

    Mantle peridotites show low Re/Os ratios and sub-chondritic 187Os/ 188Os ratios (hornblende pyroxenites, hornblende gabbros and gabbrodiorites. These rocks are enriched in LILE (e.g., Ba and Sr) and LREE, depleted in HFSE (e.g., Nb, Zr). They possess radiogenic Os isotopic compositions with 187Os/ 188Os = 0.187-0.603, and EM1-like Sr-Nd isotopic compositions (I Sr = 0.7058-0.7066, ɛNd( t) = -13.8 to -18.2). Petrography and elemental data suggest a significant fractionation and accumulation of olivine + pyroxene + hornblende in forming the mafic pluton. Clinopyroxene and plagioclase from the gabbrodiorites show complicated compositional zoning, suggesting a process of magma recharge in the late-stage of magma evolution. This is supported by their higher ɛNd( t) values (-14) than the other two rock types (-15 to -18). The parental magmas to the mafic pluton should be hydrous, which originated from an old, enriched lithospheric mantle, and were significantly contaminated by Precambrian mafic lower crust and TTG gneisses during magma evolution, as is suggested by the highly radiogenic Os- and unradiogenic Nd isotopic compositions of the mafic pluton.

  20. Whole-rock geochemistry of some tonalite and high Mg/Fe gabbro, diorite, and granodiorite plutons (sanukitoid suites in the Kuhmo district, eastern Finland

    Directory of Open Access Journals (Sweden)

    Asko Käpyaho

    2006-01-01

    Full Text Available New whole-rock geochemical analyses (major and trace elements of three tonalite plutons and high Mg/Fe granodiorites and diorites, termed sanukitoid suites, are presented from Neoarchaean Kuhmo district, eastern Finland. The 2.83 Ga and 2.78 Ga tonalites displayonly moderate fractionation of LREE/HREE thus demanding only minor or no residual garnet in their respective source regions. However, the more prominent HREE depletion in the 2.75 Ga tonalites requires more significant garnet residue. The relatively wide compositional variation in the tonalites implies that Archaean TTG (tonalite-trondhjemite-granodiorite magmatism was derived in general from sources that exhibited considerable mineralogical heterogeneity. The ~2.70 – 2.74 Ga high-Mg/Fe granodiorites and diorites are characterised by strong fractionation of LREE/HREE, relatively high Ba and Sr, and elevated abundances of Cr and Ni as well systematic depletions in P and Ti, which are all typical features of Archaean sanukitoid suites. Some of the granodiorite plutons contain compositionally intermediate high-K enclaves, which share these geochemical characteristics, implying a contribution of mafic-intermediate LILE- and LREE-enriched source for the magma. The geochemical characteristics of the studied plutonic rocks demonstrate the role of contrasting sources for the tonalites and sanukitoid suites in the Kuhmo district.

  1. Petro-structural study of volcano-plutonic rocks of Yaoure Mountains: Contribution to understanding the metallotectic gold mineralization (Central Côte d'Ivoire

    Directory of Open Access Journals (Sweden)

    Barthelemy Gnammytchet KOFFI

    2013-04-01

    Full Text Available The petrographic study of rocks and some few outcrops revealed the great diversity of volcano-plutonic formations. Indeed, magmatism of the Yaouré Mountains is quite differentiated, ranging from basic terms (basalts to acidic terms (rhyolites, passing to neutral terms (rhyodacites, andesites and dacites. The study also identifies several varieties of plutonic igneous rocks, including diorites, granodiorites, gabbros and sub-volcanic (microgranites. Diorites and granodiorites are dykes or sills in the N150° and N60° directions.The structural study made in the trenches and the pits, and on the few outcrops has highlighted several directions of fractures. The most common are: N-S to N20°, subvertical N60°, N90°-65°N, N150°-35°SW and N120°-25° NE. Genetic analysis made between the gold mineralization, the geological facies and the deformations shows that the mineralization is post-implementation of volcanic rocks (rhyodacites, dacites, andesites and basalts and subvolcanic rocks (microgranites with sulfides, and anterior to undeformed plutonic gabbroic rocks. The mineralization is hydrothermal and structural type, synchronous to conjugated fractures with dextral N150° and sinistral N060° directions. The host rocks of the gold mineralization are volcanic and sub-volcanic rocks. This mineralization occurs as stockworks and quartz veins.

  2. Neutron activation and other analytical data for plutonic rocks from North America and Africa. National Uranium Resource Evaluation

    International Nuclear Information System (INIS)

    The objective of this report is to retrieve the elements of an analytical study of granites and associated other plutonic rocks which was begun as a part of the U.S. Department of Energy's National Uranium Resource Evaluation (NURE) program. A discussion of the Savannah River Laboratory (SRL) neutron activation analysis system is given so that a user will understand the linmitations of the data. Enough information is given so that an experienced geochemist can clean up the data set to the extent required by any project. The data are generally good as they are presented. It is intended that the data be read from a magnetic tape written to accompany this report. Microfiche tables of the data follow the text. These tables were prepared from data on the tape, and programs which will read the tape are presented in the section THE DATA TAPE. It is our intent to write a later paper which will include a thoroughly scrubbed data set and a technical discussion of results of the study. 1 figure

  3. Interaction between two contrasting magmas in the Albtal pluton (Schwarzwald, SW Germany): textural and mineral-chemical evidence

    Science.gov (United States)

    Michel, Lorenz; Wenzel, Thomas; Markl, Gregor

    2016-07-01

    The magmatic evolution of the Variscan Albtal pluton, Schwarzwald, SW Germany, is explored using detailed textural observations and the chemical composition of plagioclase and biotite in both granite and its mafic magmatic enclaves (MMEs). MMEs probably formed in a two-step process. First, mafic magma intruded a granitic magma chamber and created a boundary layer, which received thermal and compositional input from the mafic magma. This is indicated by corroded "granitic" quartz crystals and by large "granitic" plagioclase xenocrysts, which contain zones of higher anorthite and partly crystallized from a melt of higher Sr content. Texturally, different plagioclase types (e.g. zoned and inclusion-rich types) correspond to different degrees of overprint most likely caused by a thermal and compositional gradient in the boundary layer. The intrusion of a second mafic magma batch into the boundary layer is recorded by a thin An50 zone along plagioclase rims that crystallized from a melt enriched in Sr. Most probably, the second mafic intrusion caused disruption of the boundary layer, dispersal of the hybrid magma in the granite magma and formation of the enclaves. Rapid thermal quenching of the MMEs in the granite magma is manifested by An30 overgrowths on large plagioclase grains that contain needle apatites. Our results demonstrate the importance of microtextural investigations for the reconstruction of possible mixing end members in the formation of granites.

  4. Rock deformation in hydrothermal systems: the nature of fractures in plutons and their host rocks. Technical progress report

    International Nuclear Information System (INIS)

    The purpose of this program is to accumulate the types of field data which are important for the analysis of magma-hydrothermal systems. The structural effects of thermal processes were identified in order to distinguish the thermally induced deformations from the deformations that occurred subsequent to complete cooling of the system. Mapping techniques were developed to record the structural data on the ground from local domains characteristic of larger areas in the magma chamber, and in the air from low-angle oblique aerial photography of the entire region. The ground system is complete and preliminary testing is currently being carried out to verify the method. The results indicate that granitic crystalline rocks have no structural resistance to thermal perturbations. If nuclear wastes are to be stored in granite, precautionary buffers would have to be incorporated into the system. A total of 30 fossil magma chambers have been studied over the past 2 years. An extensive set of fracture imagery has been collected, together with information related to the geological history of the plutons. Fossil magma chambers in Arizona, Utah, California, Washington, Montana, and British Columbia have been studied

  5. Spectral reflectance and discrimination of plutonic rocks in the 0.45- to 2.45-micron region

    Science.gov (United States)

    Blom, R. G.; Abrams, M. J.; Adams, H. G.

    1980-01-01

    Visible and near-infrared field spectral reflectance measurements of plutonic rocks were acquired in the 0.45- to 2.45-micron region with a portable field reflectance spectrometer. These spectra were used to determine spectral signatures for the various rock types and to evaluate the separability of these rocks based on their spectral characteristics. A total of 135 samples were divided into 11 groups based on their mineralogy. These 11 groups approximately correspond to traditional rock classifications and include five granitic groups, three gabbroic groups, and three ultramafic groups. The positions, intensity, and presence of iron, CO3(-2), and Al-OH and Mg-OH absorption bands varied among the 11 groups. Each rock group also had a range of albedos characteristic of the group. Stepwise linear discriminant analysis was performed on the spectral data to determine the separability of the 11 groups. Classification accuracy for 30 equally spaced wavelength bands between 0.45 and 2.45 microns was 78% with 10% serious misclassifications. The same analysis was repeated, limiting the spectral data to the wavelength regions corresponding to the proposed Landsat D thematic mapper scanner.

  6. Vein deposits hosted by plutonic rocks in the Croesus Stock and Hailey gold belt mineralized areas, Blaine County, Idaho

    Science.gov (United States)

    Worl, Ronald G.; Lewis, Reed S.

    2001-01-01

    Mineral deposits in the Croesus and Hailey gold belt mineralized areas in Blaine County, south-central Idaho, are preciousand base-metal quartz veins that are part of a family of vein deposits spatially and temporally associated with the Idaho batholith. Historic production from these veins has been mainly gold and silver. Host rocks are older border phase plutons of the Idaho batholith that are characterized by more potassium and less sodium as compared to rocks from the main body of the batholith to the west. Host structures are reverse faults that have moderate to shallow dips to the northeast and high-angle normal faults that also strike northwest. The veins are characterized by several generations of quartz and generally sparse sulfide minerals; gold is associated with late-stage comb quartz. The precious-metal ore bodies are in a series of shoots, each of which is as much as 8 ft in width, 400 ft in breadth, and 1,000 ft in pitch length.

  7. Concentration of 238U and 232Th among constituent minerals of two igneous plutonic rocks exhibiting elevated natural radioactivity levels

    International Nuclear Information System (INIS)

    The concentrations of 238U and 232Th of the constituent minerals in two plutonic rock samples, from N. Greece, exhibiting elevated levels of bulk rock natural radioactivity were determined by using LA-ICP-MS. The available data of whole rock 238U and 232Th concentrations were also used. The minerals were separated using a combination of heavy liquids of various densities, shaking table and magnetic separation techniques. The great variation in the concentrations of 238U and 232Th is probably indicative of the different distribution of U and Th within the same rock, as well as to secondary post-magmatic processes that were responsible for the redistribution of U and Th. An estimation of the contribution of each mineral constituent to the natural radioactivity levels of the bulk rock is attempted. Thorite and zircon contribute the most to the whole rock 238U and 232Th content, while the contribution of apatite is moderate. The contribution of the rest of the minerals examined (fluorite, quartz, plagioclase, K-feldspar, amphibole, pyroxene, magnetite and biotite) is not important. (author)

  8. The impact of geology on the migration of fluorides in mineral waters of the Bukulja and Brajkovac pluton area, Serbia

    Directory of Open Access Journals (Sweden)

    Papić Petar

    2012-01-01

    Full Text Available One of the hydrogeochemical parameters that classify groundwater as mineral water is the content of fluoride ions. Their concentration is both important and limited for bottled mineral waters. Hydrochemical research of mineral waters in the surrounding area of Bukulja and Brajkovac pluton, in central Serbia, was conducted in order to define the chemical composition and genesis of these waters. They are carbonated waters, with content of fluoride ranging from 0.2 up to 6.6 mg/L. Since hydrochemical analyses showed variations in the major water chemistry, it was obvious that, apart from hydrochemical research, some explorations of the structure of the regional terrain would be inevitable. For these purposes, some additional geological research was performed, creating an adequate basis for the interpretation of the genesis of these carbonated mineral waters. The results confirmed the significance of the application of hydrochemical methods in the research of mineral waters. The work tended to emphasize that “technological treatment” for decreasing the concentration of fluoride in mineral waters occurs in nature, indicating the existence of natural defluoridization. [Projekat Ministarstva nauke Republike Srbije, br. 43004

  9. Nordic Seas total alkalinity data in CARINA

    Directory of Open Access Journals (Sweden)

    A. Olsen

    2009-08-01

    Full Text Available Water column data of carbon and carbon relevant hydrographic and hydrochemical parameters from 188 previously non-publicly available cruises in the Arctic, Atlantic, and Southern Ocean have been retrieved and merged into a new database: CARINA (CARbon IN the Atlantic. The data have been subject to rigorous quality control (QC in order to ensure highest possible quality and consistency. The data for most of the parameters included were examined in order to quantify systematic biases in the reported values, i.e. secondary quality control. Significant biases have been corrected for in the data products, i.e. the three merged files with measured, calculated and interpolated values for each of the three CARINA regions; the Arctic Mediterranean Seas (AMS, the Atlantic (ATL and the Southern Ocean (SO. With the adjustments the CARINA database is consistent both internally as well as with GLODAP (Key et al., 2004 and is suitable for accurate assessments of, for example, oceanic carbon inventories and uptake rates and for model validation. The Arctic Mediterranean Seas includes the Arctic Ocean and the Nordic Seas, and the quality control was carried out separately in these two areas. This contribution presents an account of the quality control of the total alkalinity (ALK data from the Nordic Seas in CARINA. Out of the 35 cruises from the Nordic Seas included in CARINA, 21 had ALK data. The data from 6 of these were found to be of low quality and should not be used. Of the others, 3 were found to be biased low and were subject to adjustment. Thus the final CARINA data product contains ALK data from 15 cruises from the Nordic Seas, and these data appear consistent to ±3 μmol kg−1.

  10. Chlorine solubility in evolved alkaline magmas

    Directory of Open Access Journals (Sweden)

    M. R. Carroll

    2005-06-01

    Full Text Available Experimental studies of Cl solubility in trachytic to phonolitic melts provide insights into the capacity of alkaline magmas to transport Cl from depth to the earth?s surface and atmosphere, and information on Cl solubility variations with pressure, temperature and melt or fluid composition is crucial for understanding the reasons for variations in Cl emissions at active volcanoes. This paper provides a brief review of Cl solubility experiments conducted on a range of trachytic to phonolitic melt compositions. Depending on the experimental conditions the melts studied were in equilibrium with either a Cl-bearing aqueous fluid or a subcritical assemblage of low- Cl aqueous fluid + Cl-rich brine. The nature of the fluid phase(s was identified by examination of fluid inclusions present in run product glasses and the fluid bulk composition was calculated by mass balance. Chlorine concentrations in the glass increase with increasing Cl molality in the fluid phase until a plateau in Cl concentration is reached when melt coexists with aqueous fluid + brine. With fluids of similar Cl molality, higher Cl concentrations are observed in peralkaline phonolitic melts compared with peraluminous phonolitic melts; overall the Cl concentrations observed in phonolitic and trachytic melts are approximately twice those found in calcalkaline rhyolitic melts under similar conditions. The observed negative pressure dependence of Cl solubility implies that Cl contents of melts may actually increase during magma decompression if the magma coexists with aqueous fluid and Cl-rich brine (assuming melt-vapor equilibrium is maintained. The high Cl contents (approaching 1 wt% Cl observed in some melts/glasses from the Vesuvius and Campi Flegrei areas suggest saturation with a Cl-rich brine prior to eruption.

  11. The Martian ocean: First acid, then alkaline

    Science.gov (United States)

    Schaefer, M. W.

    1992-01-01

    In Mars' distant past, carbon dioxide and water may have been plentiful. Values of total outgassed CO2 from several to about 10 bar are consistent with present knowledge, and this amount of CO2 implies an amount of water outgassed equal to an equivalent depth of 500 to 1000 m. It is quite reasonable, therefore, to envision an early Mars in which there was a body or bodies of liquid water, perhaps in the northern plains, and a dense carbon dioxide atmosphere. Under such conditions, the pH of the water will be low, due to the dissolution of carbon dioxide in the water to form carbonic acid. This acidic water is capable of weathering the available rock quite intensely, particularly because this rock is likely to be heavily fractured (from meteorite bombardment) or even consist of fine particles (such as pyroclastic deposits). As time goes on, however, the carbon dioxide atmosphere will rapidly pass through the ocean to form carbonate deposits. As the density of the atmosphere decreases, so will the flux of carbonic acid into the ocean. Without this input of carbonic acid, the effect of the dissolved weathering products will be to increase the pH of the water. The ocean will then become alkaline. To study this process, I have developed a geochemical cycle model for the atmosphere-hydrosphere-regolith system of Mars. The treatment of geochemical cycles as complex kinetic chemical reactions has been undertaken for terrestrial systems in recent years with much success. This method is capable of elegantly handling the interactions between the simultaneous chemical reactions needed to understand such a system.

  12. Sulfate—Exchange Alkalinity of Ferralsol Colloid

    Institute of Scientific and Technical Information of China (English)

    ZHANGGANGYA; ZHANGXIAONIAN

    1999-01-01

    The amount of OH- replaced by sulfate,i.e.,sulfate-exchange alkalinity,from the electric double layer of ferralsol colloid was measured quantitatively in different conditions with an automatic titration equipment.The amount of OH- release increased with the amount of Na2SO4 added and decreased with raising pH in the suspension of ferralsol colloid.The exchange acidity was displayed as pH was higher than 5.6,If the negative effect of sodium ions was offset,the amount of OH- replaced by sulfate was larger than the original amount of OH- released in the pH range of lower than 5.8.The amount of OH- released decreased rapidly as pH was higher than 6.0 and dropped to zero when pH reached 6.5.In the solution of 2.0molL-1 NaClO4,the amount of OH- repleaced by sulfate from the surface of ferralsol colloid could be considered as the amount of OH- adsorbed by ligand exchange reaction.The amount of OH- released in the solution of NaClO4 concentration below 2.0mol L-1 from which the amount of OH- adsorbed by ligand exchange reaction was subtracted could be conidered as the OH- adsorbed by electrostatic force,The OH- adsorbed by electrostatic force decreased with increases in the concentration of NaClO4 and pH and increased almost linearly with the increasing amount of Na2SON4 added.The percentages of OH- adsorbed by electrostatic force in water and in the electrolyte solutions of 0.05 and 0.5mol L-1 NaClO4 in the total OH- released were calculated,respectively.

  13. Concentration and separation of vanadium from alkaline media by strong alkaline anion-exchange resin 717

    Institute of Scientific and Technical Information of China (English)

    HUANG Jinwen; SU Peng; WU Wenwei; LIAO Sen; QIN Huiquan; WU Xuehang; HE Xiaohu; TAO Liujia; FAN Yanjin

    2010-01-01

    With strong alkaline anion-exchange resin 717 as the sorbent and NaOH solution as the eluent, a study on the sorption from alkaline solution and elution of vanadium(Ⅴ), silicon(Ⅳ), and aluminium(Ⅲ) was carried out. Different parameters affecting the sorption and elution process,including temperature, pH values as well as the ratio of resin to solution, were investigated. The results show that sorption degree of vanadium(Ⅴ) increases with a decrease of pH values, and V(Ⅴ) ions are easier sorbed than Si(Ⅳ) and Al(Ⅲ) ions under the same conditions. The sorption degree of V(Ⅴ), Si(Ⅳ), and Al(Ⅲ) at pH 9.14 for 15 min are 90.6%, 33.5%, and 21.6%, respectively. Si(Ⅳ), Al(Ⅲ), and V(Ⅴ) ions sorbed on 717 resin were eluted by use of 2 mol.L-1 NaOH solution; the desorption degree of V(Ⅴ), Si(Ⅳ), and Al(Ⅲ) for 5 min are 81.7 %,99.1%, and 99.3%, respectively.

  14. Enhanced Thermostability of a Fungal Alkaline Protease by Different Additives

    OpenAIRE

    Nilesh P. Nirmal; R. Seeta Laxman

    2014-01-01

    A fungal strain (Conidiobolus brefeldianus MTCC 5184) isolated from plant detritus secreted a high activity alkaline protease. Thermostability studies of the fungal alkaline protease (FAP) revealed that the protease is stable up to 50°C with 40% residual activity after one hour. Effect of various additives such as sugars, sugar alcohols, polyols, and salts, on the thermostability of FAP was evaluated. Among the additives tested, glycerol, mannitol, xylitol, sorbitol, and trehalose were found ...

  15. A study of extracting uranium by intensified alkaline heap leaching

    International Nuclear Information System (INIS)

    A new technique of extracting uranium by intensified alkaline heap leaching was presented to treat a uranium ore of high carbonate content. A lixiviant, high concentration of alkaline solution, reacts with the ore prior to heap making for some time at a certain temperature,reducing the leaching time remarkably. With this technique, the leaching rate of uranium increased from 50% to 90% or above and the leaching time decreased from 64 days to 12 days. (authors)

  16. Overexpression of Human Bone Alkaline Phosphatase in Pichia Pastoris

    Science.gov (United States)

    Karr, Laurel; Malone, Christine, C.; Rose, M. Franklin (Technical Monitor)

    2000-01-01

    The Pichiapastoris expression system was utilized to produce functionally active human bone alkaline phosphatase in gram quantities. Bone alkaline phosphatase is a key enzyme in bone formation and biomineralization, yet important questions about its structural chemistry and interactions with other cellular enzymes in mineralizing tissues remain unanswered. A soluble form of human bone alkaline phosphatase was constructed by deletion of the 25 amino acid hydrophobic C-terminal region of the encoding cDNA and inserted into the X-33 Pichiapastoris strain. An overexpression system was developed in shake flasks and converted to large-scale fermentation. Alkaline phosphatase was secreted into the medium to a level of 32mgAL when cultured in shake flasks. Enzyme activity was 12U/mg measured by a spectrophotometric assay. Fermentation yielded 880mgAL with enzymatic activity of 968U/mg. Gel electrophoresis analysis indicates that greater than 50% of the total protein in the fermentation is alkaline phosphatase. A purification scheme has been developed using ammonium sulfate precipitation followed by hydrophobic interaction chromatography. We are currently screening crystallization conditions of the purified recombinant protein for subsequent X-ray diffraction analyses. Structural data should provide additional information on the role of alkaline phosphatase in normal bone mineralization and in certain bone mineralization anomalies.

  17. A fungal pathogen secretes plant alkalinizing peptides to increase infection.

    Science.gov (United States)

    Masachis, Sara; Segorbe, David; Turrà, David; Leon-Ruiz, Mercedes; Fürst, Ursula; El Ghalid, Mennat; Leonard, Guy; López-Berges, Manuel S; Richards, Thomas A; Felix, Georg; Di Pietro, Antonio

    2016-01-01

    Plant infections caused by fungi are often associated with an increase in the pH of the surrounding host tissue(1). Extracellular alkalinization is thought to contribute to fungal pathogenesis, but the underlying mechanisms are poorly understood. Here, we show that the root-infecting fungus Fusarium oxysporum uses a functional homologue of the plant regulatory peptide RALF (rapid alkalinization factor)(2,3) to induce alkalinization and cause disease in plants. An upshift in extracellular pH promotes infectious growth of Fusarium by stimulating phosphorylation of a conserved mitogen-activated protein kinase essential for pathogenicity(4,5). Fungal mutants lacking a functional Fusarium (F)-RALF peptide failed to induce host alkalinization and showed markedly reduced virulence in tomato plants, while eliciting a strong host immune response. Arabidopsis plants lacking the receptor-like kinase FERONIA, which mediates the RALF-triggered alkalinization response(6), displayed enhanced resistance against Fusarium. RALF homologues are found across a number of phylogenetically distant groups of fungi, many of which infect plants. We propose that fungal pathogens use functional homologues of alkalinizing peptides found in their host plants to increase their infectious potential and suppress host immunity. PMID:27572834

  18. Gravimetric, radiometric, and magnetic susceptibility study of the Paleoproterozoic Redenção and Bannach plutons, eastern Amazonian Craton, Brazil: Implications for architecture and zoning of A-type granites

    Science.gov (United States)

    de Oliveira, Davis Carvalho; Dall'Agnol, Roberto; Corrêa da Silva, João Batista; Costa de Almeida, José Arimatéia

    2008-02-01

    The 1.88 Ga, anorogenic, A-type Redenção and Bannach granites, representative of the Jamon suite and associated dikes, are intrusive in Archean granitoids of the Rio Maria Granite-Greenstone Terrane in the eastern Amazonian Craton in northern Brazil. Petrographic and geochemical aspects associated with magnetic susceptibility and gamma-ray spectrometry data show that the Redenção and the northern part of Bannach plutons are normally zoned. They were formed by two magmatic pulses: (1) a first magma pulse was fractionated in situ after emplacement at shallow crustal level, generating a series of coarse, even-grained monzogranites with variable modal proportions of biotite and hornblende; and (2) a second, slightly younger magma pulse, located to the center of the plutons, was composed of a more evolved liquid from which even-grained leucogranites derived. Gravity modeling indicates that the Redenção and Bannach plutons are sheeted-like composite intrusions, approximately 6 and 2 km thick, respectively. These plutons follow the general power law for laccolith dimension and are similar in this respect to classical rapakivi granite plutons. Gravity data suggest that the growth of the northern part of the Bannach pluton resulted from the amalgamation of smaller sheeted-like plutons that intruded in sequence from northwest to southeast. The Jamon suite plutons were emplaced in an extensional tectonic setting, and the stress was oriented approximately NNE-SSW to ENE-WSW, as indicated by the occurrence of diabase and granite porphyry dyke swarms, orientated WNW-ESE to NNW-SSE and coeval with the Jamon suite. The 1.88 Ga A-type granite plutons and stocks of Carajás are disposed along a belt that follows the general trend defined by the dikes. The inferred tabular geometry of the studied plutons and the high contrast of viscosity between the granites and their Archean country rocks can be explained by magma transport via dikes.

  19. The role of magma mixing in the evolution of high-K calc-alkaline granitoid suites: in situ trace element and Sr-Nd-Hf isotope constraints

    Science.gov (United States)

    Laurent, Oscar; Zeh, Armin; Gerdes, Axel; Slaby, Ewa; Villaros, Arnaud

    2015-04-01

    The so-called "I-type", high-K calc-alkaline granitoids are often considered as "hybrid" in origin, i.e. involving both mantle and crustal components in their petrogenesis. The interactions between both components either take place (1) at mantle levels (i.e. enriched mantle source); (2) at emplacement levels (i.e. crustal contamination and/or magma mixing with crustal melts) or (3) both. Magma mixing is, in particular, frequently invoked to explain the compositional range of high-K calc-alkaline granitoid suites, especially phases of intermediate composition (SiO2 = 60-65 wt.%) such as quartz-diorites or granodiorites. We investigated the role of magma mixing in the origin of such rocks using elemental and isotope (Sr-Nd-Hf) chemistry of magmatic minerals (plagioclase, zircon, apatite, titanite, epidote), measured in situ by LA-(MC-)ICPMS, allowing a much greater spatial resolution than classical whole-rock geochemistry. We focused on a suite of late-Archaean (2.69 Ga-old) high-K, calc-alkaline granitoids from the Pietersburg block, northern Kaapvaal Craton (South Africa): the Mashashane, Matlala, Matok and Moletsi plutons. Those plutons range from diorites to monzogranites, emplaced at different crustal levels but all within a relatively short time span and showing evidence for interactions (mingling), both at the outcrop and mineral scale. Hf isotope data on zircon confirm that all rocks are cogenetic (identical ɛHf(t)), but trace element and Sr isotopes in plagioclase point to the involvement of several components in their petrogenesis, at different stages of the magma evolution. The most mafic rocks (diorites) derive from the interaction, at mantle levels, between depleted peridotite and a sedimentary component of quartzofeldspathic nature. The mineral chemistry of more felsic rocks can be explained by (1) differentiation from the diorite magmas through Amp + Plag fractionation; (2) interactions with magmas derived from melting of local crust (tonalites

  20. Growth of plutons by incremental emplacement of sheets in crystal-rich host: Evidence from Miocene intrusions of the Colorado River region, Nevada, USA

    Science.gov (United States)

    Miller, C.F.; Furbish, D.J.; Walker, B.A.; Claiborne, L.L.; Koteas, G.C.; Bleick, H.A.; Miller, J.S.

    2011-01-01

    Growing evidence supports the notion that plutons are constructed incrementally, commonly over long periods of time, yet field evidence for the multiple injections that seem to be required is commonly sparse or absent. Timescales of up to several million years, among other arguments, indicate that the dominant volume does not remain largely molten, yet if growing plutons are constructed from rapidly solidifying increments it is unlikely that intrusive contacts would escape notice. A model wherein magma increments are emplaced into melt-bearing but crystal-rich host, rather than either solid or crystal-poor material, provides a plausible explanation for this apparent conundrum. A partially solidified intrusion undoubtedly comprises zones with contrasting melt fraction and therefore strength. Depending on whether these zones behave elastically or ductilely in response to dike emplacement, intruding magma may spread to form sheets by either of two mechanisms. If the melt-bearing host is elastic on the relevant timescale, magma spreads rather than continuing to propagate upward, where it encounters a zone of higher rigidity (higher crystal fraction). Similarly, if the dike at first ascends through rigid, melt-poor material and then encounters a zone that is weak enough (poor enough in crystals) to respond ductilely, the ascending material will also spread because the dike tip ceases to propagate as in rigid material. We propose that ascending magma is thus in essence trapped, by either mechanism, within relatively crystal-poor zones. Contacts will commonly be obscure from the start because the contrast between intruding material (crystal-poorer magma) and host (crystal-richer material) is subtle, and they may be obscured even further by subsequent destabilization of the crystal-melt framework. Field evidence and zircon zoning stratigraphy in plutons of the Colorado River region of southern Nevada support the hypothesis that emplacement of magma replenishments into a

  1. A Constructed Alkaline Consortium and Its Dynamics in Treating Alkaline Black Liquor with Very High Pollution Load

    OpenAIRE

    Yang, Chunyu; Cao, Guangchun; Li, Yang; Zhang, Xiaojun; Ren, Hongyan; Wang, Xia; Feng, Jinhui; Zhao, Liping; Xu, Ping

    2008-01-01

    Background Paper pulp wastewater resulting from alkaline extraction of wheat straw, known as black liquor, is very difficult to be treated and causes serious environmental problems due to its high pH value and chemical oxygen demand (COD) pollution load. Lignin, semicellulose and cellulose are the main contributors to the high COD values in black liquor. Very few microorganisms can survive in such harsh environments of the alkaline wheat straw black liquor. A naturally developed microbial com...

  2. 21 CFR 862.1050 - Alkaline phosphatase or isoenzymes test system.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Alkaline phosphatase or isoenzymes test system... Test Systems § 862.1050 Alkaline phosphatase or isoenzymes test system. (a) Identification. An alkaline phosphatase or isoenzymes test system is a device intended to measure alkaline phosphatase or its...

  3. 40 CFR 420.110 - Applicability; description of the alkaline cleaning subcategory.

    Science.gov (United States)

    2010-07-01

    ... alkaline cleaning subcategory. 420.110 Section 420.110 Protection of Environment ENVIRONMENTAL PROTECTION... Alkaline Cleaning Subcategory § 420.110 Applicability; description of the alkaline cleaning subcategory... alkaline cleaning baths to remove mineral and animal fats or oils from the steel, and those...

  4. Evaluation of some bean lines tolerance to alkaline soil

    Directory of Open Access Journals (Sweden)

    Abeer A. Radi

    2012-01-01

    Full Text Available Introduction: In less arid climates, salts are less concentrated and sodium dominates in carbonate and bicarbonate forms, which enhance the formation of alkaline soils. The development and identification of salt-tolerant crop cultivars or lines would complement salt management programs to improve the productivity and yields of salt stressed plants.Materials and methods: This work was to study the evaluation of alkalinity tolerance of some bean lines grown under different levels of sodium carbonate (Na2CO3 to select the most alkalinity tolerant lines versus the most-sensitive ones out of 6 lines of the test plants.Results: The symptoms induced by alkalinity included reduction in root, shoot growth, and leaf area which were more severe in some bean lines. Potassium leakage was severely affected by alkalinity in some lines at all tested levels, while in some others a moderate damage was manifested only at the higher levels. The increase in Na2CO3 level was associated with a gradual fall in chlorophyll a and b biosynthesis of all the test bean lines. However, alkalinity at low and moderate levels had a favorable effect on the biosynthesis of carotenoids in all the test bean lines. The increase in Na2CO3 supply had a considerable stimulatory effect on sodium accumulation, while potassium accumulation fluctuated in organs of bean lines.Conclusion: Assiut 1104 out of all the different lines investigated was found to display the lowest sensitivity to alkalinity stress, while Assiut 12/104 was the most sensitive one.

  5. Serum alkaline phosphatase screening for vitamin D deficiency states

    International Nuclear Information System (INIS)

    Objective: To determine whether serum vitamin D levels are correlated with serum levels of alkaline phosphatase or not. Study Design: Cross-sectional, observational study. Place and Duration of Study: Multi-centre study, conducted at Liaquat National Hospital and Medical College, National Medical Centre and Medicare Hospital, Karachi, from January to October 2009. Methodology: Patients attending the Orthopaedic OPDs with complaints of pain in different body regions and serum vitamin D/sub 3/ levels of greater or equal to 30 ng/ml were included in the study. Patients with vitamin D deficiency were further categorized into mild deficiency or insufficiency (vit. D/sub 3/ = 20-29 ng/ml), moderate deficiency (vit. D/sub 3/ = 5 - 19 ng/ml) and severe deficiency forms (vit. D/sub 3/ < 5 ng/ml). Pearson correlation was applied to test the correlation of serum alkaline phosphatase levels with serum vitamin D/sub 3/ levels. P-value < 0.05 was considered to be significant. Results: Out of 110 samples, 26 had mild (23%), 61 had moderate (55%) and 21 had severe (19.1%) vitamin D deficiencies. All of the patients in the three groups had alkaline phosphatase with in normal limits and the total mean value of the enzyme was 135.97 +- 68.14I U/L. The inter group comparison showed highest values of alkaline phosphatase in the moderate vitamin D deficiency group. The correlation coefficient of alkaline phosphatase and serum vitamin D/sub 3/ levels was r =0.05 (p =0.593). Conclusion: Serum vitamin D/sub 3/ levels may not be correlated with increased serum alkaline phosphatase levels. Therefore, alkaline phosphatase may not be used as a screening test to rule out vitamin D deficiency. (author)

  6. CHARACTERIZATION OF BULK SOIL HUMIN AND ITS ALKALINE-SOLUBLE AND ALKALINE-INSOLUBLE FRACTIONS

    Directory of Open Access Journals (Sweden)

    Cuilan Li

    2015-02-01

    Full Text Available Humic substances are the major components of soil organic matter. Among the three humic substance components (humic acid, fulvic acid, and humin, humin is the most insoluble in aqueous solution at any pH value and, in turn, the least understood. Humin has poor solubility mainly because it is tightly bonded to inorganic soil colloids. By breaking the linkage between humin and inorganic soil colloids using inorganic or organic solvents, bulk humin can be partially soluble in alkali, enabling a better understanding of the structure and properties of humin. However, the structural relationship between bulk humin and its alkaline-soluble (AS and alkaline-insoluble (AIS fractions is still unknown. In this study, we isolated bulk humin from two soils of Northeast China by exhaustive extraction (25 to 28 times with 0.1 mol L-1 NaOH + 0.1 mol L-1 Na4P2O7, followed by the traditional treatment with 10 % HF-HCl. The isolated bulk humin was then fractionated into AS-humin and AIS-humin by exhaustive extraction (12 to 15 times with 0.1 mol L-1 NaOH. Elemental analysis and solid-state 13C cross-polarization magic angle spinning nuclear magnetic resonance (13C CPMAS NMR spectroscopy were used to characterize and compare the chemical structures of bulk humin and its corresponding fractions. The results showed that, regardless of soil types, bulk humin was the most aliphatic and most hydrophobic, AS-humin was the least aliphatic, and AIS-humin was the least alkylated among the three humic components. The results showed that bulk humin and its corresponding AS-humin and AIS-humin fractions are structurally differed from one another, implying that the functions of these humic components in the soil environment differed.

  7. Petrology, Magnetic susceptibility, Tectonic setting and mineralization associated with Plutonic and Volcanic Rocks, Eastern Bajestan and Taherabad, Iran

    Directory of Open Access Journals (Sweden)

    Malihe Ghoorchi

    2009-09-01

    Full Text Available Study area is located in district of Bajestan and Ferdows cities, NE of Iran. Structurally, this area is part of Lut block. The oldest exposed rocks, to the north of intrusive rocks and in Eastern Bajestan, are meta-chert, slate, quartzite, thin-bedded crystalline limestone and meta-argillite. The sedimentary units are: Sardar Formation (Carboniferous, Jamal Formation (Permian, Sorkh Shale and Shotori Formations (Triassic, carbonateous rocks (Cretaceous and lithostratigraphically equivalent to Kerman conglomerate (Cretaceous-Paleocene are exposed in this area. Based on relative age, magmatism in eastern Bajestan and Taherabad started after Late Cretaceous and it has been active and repeated during Tertiary time. At least, three episodes of volcanic activities are recognized in this area. The first stage was mainly volcanic flow with mafic composition and minor intermediate. The second episode was mainly intermediate in composition. The third stage was changed to acid-intermediate in composition. Since the plutonic rocks intruded the volcanic rocks, therefore they may be Oligo-Miocene age. Bajestan intrusive rocks are granite-granodiorite-quartz monzonite. Taherabad intrusive rocks are diorite-quartz diorite- monzonite-latite. Bajestan intrusive rocks are reduced type (ilmenite series and Taherabad intrusive rocks are oxidized type (magnetite series.Based on geochemical analysis including trace elements, REE and isotopic data, Bajestan intrusive rocks formed in continental collision zone and the magma has crustal origin. Taherabad intrusive rocks were formed in subduction zone and magma originated from oceanic crust. Taherabad intrusive rock has exploration potential for Cu-Au and pb.

  8. Archaean tonalitic-trondhjemitic and granitic plutonism in the Gaviao block, Sao Francisco craton, Bahia, Brazil: geochemical and geochronological characteristics

    International Nuclear Information System (INIS)

    The granitic-gneissic terranes of the Gaviao Block in the central-southern Sao Francisco Craton are a Key area to the understanding of the evolution of the South American Platform. The Archaean granitic-gneissic rocks are intimately associated with the Umburanas and Contendas Mirante greenstone belts. The metamorphic grades vary from greenschist to amphibolite facies. These rocks were intensely deformed and intruded by Paleoproterozoic granites. The main evolution of the Gaviao Block is market by the formation of granitoid nuclei during various episodes of TTG plutonism between 3.2 and 3.4 Ga. The TDM Sm-Nd model ages for these granitoids range from 3.2 and 3.6 Ga, indicating involvement of sialic crust in their genesis, in agreement with the εNd(t) values between -4.0 and -1.3. Between 3.1 and 2.5 Ga, the Gaviao Block was affected by volcanic and sedimentary activity associated with the formation of the Umburanas and Contendas Mirante greenstone belts, intruded by granites about 2.75 and 2.5 Ga ago. During the paleoproterozoic, the Gaviao Block was regionally deformed and metamorphosed, and intruded by granites between 2.1 and 1.9 Ga. During the mesoproterozoic, tectonic and metamorphic activity occurred between 1.2 and 1.0 Ga as suggested by resetting of Rb-Sr and K-Ar systematics. Finally, regional tectono-thermal overprints in the areas occurred during the Neoproterozoic. These episodes are accompanied by the intrusion of mafic dikes at about 0.9 Ga K-Ar ages given by biotites fall within the range 0.5-0.7 Ga and mark the end of the cratonization stage. (author)

  9. Assessment of gamma radiation exposure and distribution of natural radioactivity in beach sands associated with plutonic rocks of Greece

    Science.gov (United States)

    Papadopoulos, Argyrios; Koroneos, Antonios; Christofides, Georgios; Stoulos, Stylianos

    2016-04-01

    This study aims to evaluate the activity concentrations of 238U, 226Ra, 232Th, 228Th and 40K along beaches of Greece associated with plutonic rocks. They range from 6-940, 1-2292, 5-10143, 5-9953 and 27-1319 Bq/kg respectively, with some of them representing the highest values of natural radioactivity measured in sediments in Greece. The investigated beaches include Sithonia peninsula (Chalkidiki, N. Greece), some islands of the Aegean Sea (Mykonos, Paros, Naxos, Serifos, Ikaria), the area of Kavala (N. Greece), Samothraki island, NE Chalkidiki and Maronia (NE Greece). Several of these places are associated with high touristic activity such as Mykonos, Naxos, Paros, Serifos, Ikaria, Sithonia and Kavala. The (% wt.) heavy magnetic fraction (HM) (allanite, amphibole, mica, clinopyroxene, magnetite and hematite), the heavy non-magnetic fraction (HNM) (monazite, zircon, titanite and apatite) and the total heavy fraction (TH), were correlated with the concentrations of the measured radionuclides in the bulk samples. The heavy fractions seem to control the activity concentrations of 238U and 232Th of all the samples, showing some local differences in the main 238U and 232Th mineral carrier. The measured radionuclides in the beach sands were normalized to the respective values measured in the granitic rocks, which are their most probable parental rocks, so as to provide data upon their enrichment or depletion. The highest values of the equivalent dose have been reported in Mykonos, Naxos, Kavala and Sithonia. The annual equivalent dose which should be limited to at least 1 mSv y-1, varies between 0.003 and 0.759 mSv y-1 for tourists and from 0.012 to 3.164 mSv y-1 for local people working on the beach.

  10. Studies on Fast Remediation of Soda Meadow Alkaline Soil

    Institute of Scientific and Technical Information of China (English)

    ZHOU Lianren; SUN Yankun; LI Dawei

    2010-01-01

    Researches on models of remediation quickly in soda meadow alkaline soil, and dynamic variation of water-salt in saline soil of Zhaozhou County were studied systematically from 2001 to 2006. Realize the vegetation cover of those years through the artificial planting, mixed seeding lymc grass (Elymus dahuricus Turcz) and melilot in the mode of rotary tillage and deep loosening in lower and medium saline soils. The results showed that there was remarkable relationship between net evaporation (difference of precipitation and evaporation) and total salt content in the soil. The net evaporation could be used as a new method to forecast the dynamics variation of salt to ensure the pasture optimum sowing time. Realize the autumnal vegetation cover of those years through direct planting on the bourgeon layer of soda meadow alkaline soil, on the other hand, the covered pasture made the function of restraining salt and alkaline content to realize the biology reverse succession quickly. Forage seeds were seeded directly on the seeding bed of soda alkaline meadow at the end of July. In fall of the same year, a certain amount of biomass was obtained. The model, which has remarkable economical efficiency and use widely, represented the innovative model for the fast vegetation restoration on the soda alkaline meadow soil.

  11. Characterization of Human Bone Alkaline Phosphatase in Pichia Pastoris

    Science.gov (United States)

    Malone, Christine C.; Ciszak, Eva; Karr, Laurel J.

    1999-01-01

    A soluble form of human bone alkaline phosphatase has been expressed in a recombinant strain of the methylotrophic yeast Pichia pastoris. We constructed a plasmid containing cDNA encoding for human bone alkaline phosphatase, with the hydrophobic carboxyl terminal portion deleted. Alkaline phosphatase was secreted into the medium to a level of 32mg/L when cultured in shake flasks, and enzyme activity was 12U/mg, as measured by a spectrophotometric assay. By conversion to a fermentation system, a yield of 880mg/L has been achieved with an enzyme activity of 968U/mg. By gel electrophoresis analysis, it appears that greater than 50% of the total protein in the fermentation media is alkaline phosphatase. Although purification procedures are not yet completely optimized, they are expected to include filtration, ion exchange and affinity chromatography. Our presentation will focus on the purification and crystallization results up to the time of the conference. Structural data should provide additional information on the role of alkaline phosphatase in normal bone mineralization and in certain bone mineralization anomalies.

  12. Magmatic-hydrothermal fluids and volatile metals in the Spirit Lake pluton and Margaret Cu-Mo porphyry system, SW Washington, USA

    Science.gov (United States)

    Iveson, Alexander A.; Webster, James D.; Rowe, Michael C.; Neill, Owen K.

    2016-03-01

    The halogen-bearing minerals tourmaline, amphibole, and biotite formed during magmatic-hydrothermal processes associated with the late-stage cooling of the Spirit Lake granitoid pluton (Mt. St. Helens, WA) and with the younger sulphide-mineralised rocks of the Margaret Cu-Mo porphyry deposit located entirely within the pluton. Major- and trace-element discrimination suggests that one tourmaline population crystallised from fractionated late-stage melt pockets in granodiorite-monzogranitic dykes of the pluton. These coarse, euhedral, oscillatory, and complexly sector-zoned uvite tourmalines span a limited range in Mg/(Mg + Fe) [Mg#] space (0.4-0.7 apfu) and show the highest Ti, Ca, F, Nb, and Ta contents, and low X-site vacancies (0.6 apfu), lower Ca and F contents, and the highest Li, As, and HREE contents (>80 ppm Li, >1200 ppm As). This population appears to record direct, rapid crystallisation from magmatic ± meteoric fluid(s) bearing the signature of the breakdown of primary feldspars and pyroxenes, with fluid exsolution from fractionated melt patches likely triggered by the formation of the previous generation of tourmaline. Mineralised porphyry deposit tourmaline compositions from the stockwork span a much larger range in Mg# space (0.05-0.9 apfu) and are almost entirely Ca-free. X-sites of these schorl tourmalines are dominated by Na or vacancies, and the Y-sites are strongly Fe enriched. The highest Mn and Zn concentrations (>4000 and >1000 ppm, respectively) potentially reflect the composition of mineralising fluids during ore deposition. A number of boron isotopic analyses yield predominantly heavy boron, but δ11B values range from -5.2 to 6.2 ‰ and average 1.4 ‰. Whilst most plutonic tourmalines conform to reported a- and c-sector element partitioning models, those from the mineralised porphyry show large and variable sector fractionation differences, suggesting that external controls may also be important. Wider evidence for late-stage pervasive

  13. U-Pb geochronology and geochemistry of Bibi-Maryam pluton, eastern Iran: Implication for the late stage of the tectonic evolution of the Sistan Ocean

    Science.gov (United States)

    Delavari, Morteza; Amini, Sadraddin; Schmitt, Axel K.; McKeegan, Kevin D.; Mark Harrison, T.

    2014-07-01

    The Bibi-Maryam pluton crops out in the Sistan suture zone, eastern Iran. This pluton is a 1.5 × 2 km stock composed of leucocratic tonalite, granodiorite and granite. U-Pb zircon geochronology of a leucogranite indicates an emplacement age of 58.6 ± 2.1 Ma (95% confidence). The Bibi-Maryam rock suite is sodic with elevated Na2O/K2O (2.9 to 5.5), Sr/Y (15.6-62.2), La/Yb (13.3-22.2), and low MgO (0.86-1.81) abundances. It lacks significant Eu anomalies. Because of these geochemical characteristics, Bibi-Maryam rocks are similar to high-SiO2 adakites. Trace element modeling indicates that the Bibi-Maryam adakitic rocks could be produced by 5-8% non-modal batch partial melting from a source with composition of 95% N-MORB + 5% sediment in the presence of 35-40% amphibole + 5-10% garnet + 55-60% clinopyroxene + 1% apatite + 1% rutile. This source mineralogy is similar to hornblende eclogite or garnet amphibolites. Collectively, these data provide new constraints for the evolution of the Sistan suture zone and suggest that the Bibi-Maryam pluton formed via slab melting in an oceanic arc and pre-plate collision tectonic setting. This implies that the closure of the Sistan Ocean and Lut-Afghan continental blocks collision happened after the Bibi-Maryam emplacement at 58.6 ± 2.1 Ma.

  14. Mesozoic thermal history and timing of structural events for the Yukon-Tanana Upland, east-central Alaska: 40Ar/39Ar data from metamorphic and plutonic rocks

    Science.gov (United States)

    Dusel-Bacon, C.; Lanphere, M.A.; Sharp, W.D.; Layer, P.W.; Hansen, V.L.

    2002-01-01

    We present new 40Ar/39Ar ages for hornblende, muscovite, and biotite from metamorphic and plutonic rocks from the Yukon-Tanana Upland, Alaska. Integration of our data with published 40Ar/39Ar, kinematic, and metamorphic pressure (P) and temperature (T) data confirms and refines the complex interaction of metamorphism and tectonism proposed for the region. The oldest metamorphic episode(s) postdates Middle Permian magmatism and predates the intrusion of Late Triassic (215-212 Ma) granitoids into the Fortymile River assemblage (Taylor Mountain assemblage of previous papers). In the eastern Eagle quadrangle, rapid and widespread Early Jurassic cooling is indicated by ???188-186 Ma 40Ar/39Ar plateau ages for hornblende from plutons that intrude the Fortymile River assemblage, and for metamorphic minerals from the Fortymile River assemblage and the structurally underlying Nasina assemblage. We interpret these Early Jurassic ages to represent cooling resulting from northwest-directed contraction that emplaced the Fortymile River assemblage onto the Nasina assemblage to the north as well as the Lake George assemblage to the south. This cooling was the final stage of a continuum of subduction-related contraction that produced crustal thickening, intermediate- to high-P metamorphism within both the Fortymile River assemblage and the structurally underlying Lake George assemblage, and Late Triassic and Early Jurassic plutonism in the Fortymile River and Nasina assemblages. Although a few metamorphic samples from the Lake George assemblage yield Jurassic 40Ar/39Ar cooling ages, most yield Early Cretaceous 40Ar/39Ar ages: hornblende ???135-115 Ma, and muscovite and biotite ???110-108 Ma. We interpret the Early Cretaceous metamorphic cooling, in most areas, to have resulted from regional extension and exhumation of the lower plate, previously tectonically thickened during Early Jurassic and older convergence.

  15. U-Pb zircon geochronology and Sm-Nd-Pb isotopic constraint for precambrian plutonic rocks in the northeastern part of Ryeongnam massif, Korea

    International Nuclear Information System (INIS)

    The Ryeongnam massif is composed of Precambrian gneisses, Paleozoic and Mesozoic sedimentary rocks and extensive Triassic-Jurassic plutonic rocks of felsic to mafic composition. In the northeast Ryeongnam massif, the oldest rocks belong to the Sobaegsan gneiss complex, which is composed of orthogneisses, paragneisses and mafic plutonic rocks. U-Pb zircon ages for the felsic and mafic intrusive bodies within the Sobaegsan gneiss complex are: the Icheon granite gneiss, 2357±43 and 2342±47 Ma; the Buncheon granite gneiss, 1963±5 Ma; the Pyeonghae granite gneiss, 1936±21 Ma; the Ogbang amphibolite, 1918±10 Ma; the Imwon leucogranite gneiss, 1826±20 Ma. The Hyeondong biotite schist, which is intruded by the Buncheon granite gneiss and the Ogbang amphibolite, yielded an age of 2271±44 Ma. The Nd-Sm-Pb isotopic data indicate that the felsic plutonic rocks are derived from an older Archean crust. The Nd TDM ages are Archean, and the εNd values are negative for the felsic rocks and positive for the amphibolite. Common Pb isotope compositions also indicate a crustal source for the felsic intrusives. The U-Pb ages of Precambrian rocks of the Ryeongnam massifs are similar to those in the Gyeonggi massif, and may have a similar crustal evolutionary history. The Precambrian rocks of South Korea could be related either to the North China block or to the South China block, as the isotope ages and patterns are not unique to either block. Similarly, a geologic correlation with Japan, although possible, is tenuous at present. (author)

  16. Age and isotopic fingerprints of some plutonic rocks in the Wiborg rapakivi granite batholith with special reference to the dark wiborgite of the Ristisaari Island

    Directory of Open Access Journals (Sweden)

    Rämö, O.T.

    2014-12-01

    Full Text Available The mid-Proterozoic, locus classicus Wiborg rapakivi granite batholith of southeastern Finland and adjacent Russia comprises a varying, bimodal (silicic-basic sequence of plutonic, subvolcanic, and volcanic rocks. At the current level of erosion silicic rocks are dominant, the most prominent of which are wiborgites and dark wiborgites (that have been considered to mark the main build-up stage of the batholith and pyterlites. New observations and optical microscopy data from the dark wiborgite-dominated Ristisaari Island in the southern, off-shore part of the Wiborg batholith show that dark plagioclase megacrysts in dark wiborgite are calcic xenocrysts. They were probably incorporated into wiborgite magma from consanguineous massiftype anorthosite magmas in the course of the evolution of the bimodal magmatic system. Our new ID-TIMS U-Pb zircon age of the Ristisaari Island dark wiborgite, 1627±3 Ma, is the youngest isotopic age so far determined for the plutonic rocks of the Wiborg batholith. This, combined with preexisting U-Pb zircon data, implies a minimum duration of 12 m.y. (1642–1630 Ma for the emplacement of the plutonic rocks of the batholith. Combined with data on highlevel dike rocks, a window of at least 20 m.y. (1642–1622 Ma is implied. Furthermore, as the batholith grew, the overall locus of magmatism may have shifted southwards. New whole-rock Nd isotope data on the dark wiborgite of the Ristisaari Island and three further granites of the batholith, as well as Nd (whole-rock and Sr (whole-rock, plagioclase isotope data on a spectrolite massif-type anorthosite from the east-central part of the batholith, are also presented. These data suggest that the lithosphere across the Wiborg batholith area in the southeastern part of the Svecofennian orogen may vary slightly in overall mantle separation age.

  17. ADVANCES IN THE MODEL OF CYLINDRICAL ALKALINE CELLS

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The advancement of a systematic investigation on the modeling of cylindrical alkaline cells is presented.Initial analysis utilizes thermodynamic and kinetic information to predict alkaline cell performance under low discharge rates.Subsequent modling has taken into consideration detailed information on the chemistry of electrode reactions,mass tranport of dissolved species,physical and chemical properties of the electrolyte and solid phases,and internal geonetry of cell systems.The model is capable of predicting alkaline cell performance under a variety of dicharge conditions.The model also provides information regarding internal cell changes during discharge.The model is the basis of a rational approach for the optimal design of cells.

  18. POLYETHER POLYURETHANE FROM MODIFIED WHEAT STRAW OXYGEN-ALKALINE LIGNIN

    Institute of Scientific and Technical Information of China (English)

    Quanxiao Liu; Huaiyu Zhan; Beihai He; Shuhui Yang; Jianhua Liu; Jianlu Liu; Zhenxing Pang

    2004-01-01

    Polyether polyurethane was synthesized from modified wheat straw oxygen-alkaline lignin,polyethylene glycol and two different diisocyanates (diphenylemethane-4, 4′-diisocyanate, tolulene diisocyanate) by solution casting method, its properties were investigated. The results show that modified wheat straw oxygen-alkaline lignin can substitute part of polyethylene glycol to react with diisocyanate to synthesize polyurethane. The molar ratio of NCO to OH and modified wheat straw oxygen-alkaline lignin content affect the properties of lignin-based polyether polyurethane respectively. The addition of plasticizer in the polyurethane synthesis process improves the properties of synthesized polyurethane, especially the elasticity of polyurethane. The synthesized polyurethane from modified wheat straw oxygen-alkali lignin can be used as both engineering plastic and hard foam plastic in future.

  19. POLYETHER POLYURETHANE FROM MODIFIED WHEAT STRAW OXYGEN-ALKALINE LIGNIN

    Institute of Scientific and Technical Information of China (English)

    QuanxiaoLiu; HuaiyuZhan; BeihaiHe; ShuhuiYang; JianhuaLiu; JianluLiu(1); ZhenxingPang

    2004-01-01

    Polyether polyurethane was synthesized from modified wheat straw oxygen-alkaline lignin, polyethylene glycol and two different diisocyanates (diphenylemethane-4, 4'-diisocyanate, tolulene diisocyanate) by solution casting method, its properties were investigated. The results show that modified wheat straw oxygen-alkaline lignin can substitute part of polyethylene glycol to react with diisocyanate to synthesize polyurethane. The molar ratio of NCO to OH and modified wheat straw oxygen-alkaline lignin content affect the properties of lignin-based polyether polyurethane respectively. The addition of plasticizer in the polyurethane synthesis process improves the properties of synthesized polyurethane, especially the elasticity of polyurethane. The synthesized polyurethane from modified wheat straw oxygen-alkali lignin can be used as both engineering plastic and hard foam plastic in future.

  20. Transient species produced in irradiated alkaline aqueous solutions containing oxygen

    International Nuclear Information System (INIS)

    The spectra and decay kinetics of the optical absorption in the UV region and at 430nm (maximum of the ozonide ion absorption), were investigated in oxygenated neutral, slightly and strongly alkaline aqueous solutions. It is assumed that the initial absorption after the pulse in oxygenated alkaline solutions is due to the ozonide ion O3-, superoxide radical ion O2- and ozone O3. The long-living absorption in these solutions cannot be excluded as to be probably caused by the ozone O3 or some product formed from O2- or an alkaline stabilized form of this radical-ion. The advantage of applying additional non-optical measurements of the system is shown on the example of H2O2 role played in the mechanism. (author)