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Sample records for alkaline pluton kola

  1. Loparite-(Ce) from the Khibiny Alkaline Pluton, Kola Peninsula, Russia

    Science.gov (United States)

    Konopleva, N. G.; Ivanyuk, G. Yu.; Pakhomovsky, Ya. A.; Yakovenchuk, V. N.; Mikhailova, Yu. A.

    2017-12-01

    Data on the occurrence, morphology, anatomy, composition, and formation conditions of loparite-(Ce) in the Khibiny alkaline pluton are given. Loparite-(Ce), (Na,Ce,Sr)(Ce,Th)(Ti,Nb)2O6, resulted from metasomatic alteration and assimilation of metamorphic host rocks at the contact with foyaite as well as foyaite on the contact with foidolite. This alteration was the highest in pegmatite, and albitite developed there. A decrease in temperature resulted in enrichment of the perovskite and tausonite endmembers in loparite-(Ce) owing to a decrease in the loparite and lueshite endmembers. La and Ce sharply predominate among rare earth elements in the composition of loparite-(Ce).

  2. Fluorcanasite, K3Na3Ca5Si12O30(F,OH)4 · H2O, a new mineral species from the Khibiny alkaline pluton, Kola Peninsula, Russia, and new data on canasite

    Science.gov (United States)

    Khomyakov, A. P.; Nechelyustov, G. N.; Krivokoneva, G. K.; Rastsvetaeva, R. K.; Rozenberg, K. A.; Rozhdestvenskaya, I. V.

    2009-12-01

    Fluorcanasite is described, a new mineral species found in dumps of the Kirovsk apatite mine, Mt. Kukisvumchorr, Khibiny alkaline pluton, Kola Peninsula, Russia. The new mineral is associated with microcline, nepheline, aegirine, scherbakovite, lamprophyllite, pectolite, mosandrite, villiaumite, rasvumite, and molybdenite. It occurs as prismatic crystals up to 0.2-0.3 × 1-2 mm in size extending along [010]. Fluorcanasite is purple, transparent, with white streak and vitreous luster. The fracture is hackly along the extension and stepped in other directions. The mineral is brittle. The cleavage is eminent parallel to {100} and {201} and perfect parallel to {001}. D(meas) = 2.68(2) g/cm3 (volumetric method); D(calc) = 2.69 g/cm3. Fluorcanasite is biaxial, negative, n α = 1.538(1), n β = 1.546(1), n γ = 1.549(1), 2 V(meas) = 60(2)°, 2 V(calc) = 63°. Dispersion r > v. The new mineral is pleochroic according to the scheme N β > N γ > N α; N β is purple, N γ is lilac, and N α is amber-yellow. Orientation is as follows: b = N β, a∧ N γ = 3°, c∧ N α = 19°. Fluorcanasite is not luminescent in UV light and slowly decomposes in acid. The new mineral is monoclinic, space group Cm, a = 18.846(4), b = 7.242(1), c = 12.650(2) Å, β = 111.84(2)°, V = 1602.6(4) Å3, Z = 2. The strongest reflections [ d, Å( I)] in the X-ray powder pattern of a grainoriented sample are 2.915(100), 4.204(40), 5.872(36), 4.712(36), 2.358(32), 3.012(24), 2.310(24), 3.082(24) and the same reflections in a randomly oriented sample are 3.082(100), 2.915(85), 4.712(46), 4.204(41), 3.340(35), 5.872(33), 2.658(30). The chemical composition, determined with an electron microprobe, is as follows, wt %: 7.19 Na2O, 10.91 K2O, 19.55 CaO, 0.27 FeO, 2.08 MnO, 55.84 SiO2, 4.10 F, 2.22 H2O (determined on the basis of structural data), 1.73-O = F2; the total is 100.43. The empirical formula, calculated on the basis of Si = 12, is K2.99Na3.00(Ca4.50Mn0.38·Fe{0.05/2+})Σ4.93Si12O29.93(F2.79OH1

  3. Crystal Chemistry of Pyroaurite from the Kovdor Pluton, Kola Peninsula, Russia, and the Långban Fe-Mn deposit, Värmland, Sweden

    Science.gov (United States)

    Zhitova, E. S.; Ivanyuk, G. Yu.; Krivovichev, S. V.; Yakovenchuk, V. N.; Pakhomovsky, Ya. A.; Mikhailova, Yu. A.

    2017-12-01

    Pyroaurite [Mg6Fe2 3+ (OH)16][(CO3)(H2O)] from the Kovdor Pluton on the Kola Peninsula, Russia, and the Långban deposit in Filipstad, Värmland, Sweden were studied with single crystal and powder X-ray diffraction, an electron microprobe, and Raman spectroscopy. Both samples are rhombohedral, space group R3̅ m, a = 3.126(3), c = 23.52(2) Å (Kovdor), and a = 3.1007(9), c = 23.34(1) (Långban). The powder XRD revealed only the 3 R polytype. The ratio of di- and trivalent cations M 2+: M 3+ was determined as 3.1-3.2 (Kovdor) and 3.0 (Långban). The Raman spectroscopy of the Kovdor sample verified hydroxyl groups and/or water molecules in the mineral (absorption bands in the region of 3600-3500 cm-1) and carbonate groups (absorption bands in the region of 1346-1058 cm-1). Based on the data obtained, the studied samples should be identified as pyroaurite-3 R (hydrotalcite group).

  4. A review of the compositional variation of amphiboles in alkaline plutonic complexes

    Science.gov (United States)

    Mitchell, Roger H.

    1990-12-01

    Compositional data for amphiboles occurring in alkaline plutonic complexes are reviewed and a standard procedure for plotting these data in an isometric prism is proposed. The main compositional trend found in both oversaturated and undersaturated complexes of either miascitic or peralkaline affinity is referred to as the primary magmatic trend. Amphiboles range in composition from magnesian hastingsitic hornblende and ferro-edenitic hornblende through katophorite to ferro-richterite and arfvedsonite. Individual complexes differ with respect to the amphibole {Mg}/{Fe} and {Si}/{Al} ratio and the extent of Na-enrichment. Extensive or limited ranges in the composition of amphiboles may occur in a given complex. A subtrend found only in oversaturated complexes is from ferro-edenitic hornblende to ferro-actinolite. This trend termed the ferro-actinolitic subtrend is found only in low temperature non-peralkaline residua. Some aluminous nepheline syenites and associated alkali gabbros contain amphiboles which range in composition from kaersutite through ferroan pargasitic hornblende to hastingsite. This trend termed the primary miascitic magmatic trend is is one of decreasing {Mg}/{Fe}, at essentially constant {Si}/{Al} and Ca content. Na-enrichment does not occur. Amphiboles formed by reactions of preexisting phases with hydrothermal or deuteric fluids are termed the late stage reaction assemblage. Amphibole compositional trends from calcic through sodic-calcic to sodic amphiboles reflect decreasing temperature and oxygen fugacity at or below the QFM oxygen buffer. The compositional trends are of use in determining petrogenetic relationships between apparently consanguineous syenites.

  5. Graphite as an indicator of contact influence of Western Keivy alkaline granite intrusion, the Kola Peninsula

    Directory of Open Access Journals (Sweden)

    Fomina E. N.

    2017-03-01

    Full Text Available The results of complex petro-mineragraphic, Raman and isotope- geochemical study of three types of graphite- bearing rocks circulated at different distances from the alkaline granites: (1 kyanite schists of Bolshiye Keivy, sampled at a considerable distance from a contact with alkaline gran ites; (2 sillimanite schists, sampled close to the contact, and (3 silexites, located in the inner part of th e alkaline granite massif Western Keivy have been presented. Five morphogenetic types of graphite have been revealed in the rocks under consideration: fine- grained Gr-1, intergranular Gr-2, nest-shaped Gr-3, vein Gr- 4 and spherulitic Gr-5. Current study demonstrates that these five types of graphite distinctly vary not only i n morphology, but also in temperature of crystallization, as determined by RSCM-Raman geothermometer, and in carbon isotop e composition. The most likely source for the anomalous "light" graphite Gr-1 and Gr-2 [δ 13 C(PDB = −43...−45 ‰] from kyanite schists is a water- methane fluid originating from sedimentary rocks with org anic compounds. The carbon of graphite Gr-5 of the silexites selected at the inner part of alkaline granite massif West ern Keivy, on the contrary, proved to be most "heavy" [δ 13 C(PDB = −8 ‰], which indicates its origin from the lower crustal or mantle carbon dioxide fluid. Thus, carbon extracted into the rocks of Keivy structure from at least two contrasting isotope sources. Graphite Gr-3, that makes up the bulk of graphite of exocontact sil limanite schists, is also isotopically light, but not anomalously [δ 13 C(PDB = −17...−28 ‰]. The crystallization temperature of the gi ven graphite (435−520 ºC, and its structural relationships with other minerals of th e rock evidence of its synmetamorphic origin. The presence of veinlets of isotopically heavy [δ 13 C(PDB = −10 ‰...−11 ‰] high-temperature (570−670 ºC graphite intersecting minerals of the metamorphic paragenesis (i

  6. The Fontaine Pluton : an early Ross Orogeny calc-alkaline gabbro from southern Victoria Land, Antarctica

    International Nuclear Information System (INIS)

    Cottle, J.M.; Cooper, A.F.

    2006-01-01

    The Fontaine Pluton is a previously undescribed mafic intrusion outcropping at Fontaine Bluff on the south side of the Carlyon Glacier in southern Victoria Land, Antarctica. It is the southern-most member of a laterally extensive mafic suite emplaced at mid-crustal depths during the initial stages of the Ross Orogeny. The pluton comprises recrystallised hornblende-biotite gabbro, which in places shows well-defined centimetre to metre scale primary igneous layering. Recrystallised ultramafic enclaves composed of amphibole-chlorite-talc are inferred to be remnants of a chemically and mineralogically distinct cumulate fraction. The intrusion has a 87 Sr/ 86 Sr (i) ratio of 0.70679 and a 143 Nd/ 144 Nd (i) ratio of 0.51187 (εNd (i) = -1.2). This, coupled with other geochemical data, implies that the Fontaine Pluton was formed by c. 15% partial melting of a depleted mantle source that was subsequently contaminated by continental crust. Preliminary U-Pb geochronology on zircon suggests an emplacement age for the pluton of 546 ± 10 Ma. These new data indicate that Ross Orogeny magmatism in this area of southern Victoria Land was initiated in the late Neoproterozoic along a subducting plate margin. (author). 55 refs., 10 figs., 3 tabs

  7. Marketing and distribution of Garcinia kola ( Bitter kola ) in southwest ...

    African Journals Online (AJOL)

    Marketing and distribution of Garcinia kola ( Bitter kola ) in southwest Nigeria: opportunity ... The study evaluates the different marketing of Bitter kola (Garcinia kola) starting from the point of ... EMAIL FREE FULL TEXT EMAIL FREE FULL TEXT

  8. Origin and mobility of hydrocarbon gases in alkaline plutons : the example of the Khibina complex, NW Russia

    Energy Technology Data Exchange (ETDEWEB)

    Treloar, P.J.; Beeskow, B.; Rankin, A.H. [Kingston Univ., Kingston upon Thames (United Kingdom). School of Earth Sciences; Potter, J. [Western Ontario Univ., London, ON (Canada). Dept. of Earth Science; Nivin, V. [Geological Inst., Apatity (Russian Federation). Kola Science Centre

    2006-07-01

    The origin and distribution of abiogenic hydrocarbon gases (HCGs) was discussed with particular reference to HCGs in the Khibina pluton which are dominated by methane (CH{sub 4}) with minor amounts of higher hydrocarbons and hydrogen (H{sub 2}). Although isotopic data and hydrocarbon species ratios point to an abiogenic source, they do not distinguish between primary magmatic hydrocarbons and those generated by late magmatic re-speciation or post-magmatic Fischer-Tropsch (FT) synthesis. Some rock textures suggest limited CH{sub 4} production by FT synthesis, but the presence of primary, syn-magmatic CH{sub 4}-rich fluid inclusions, and the absence of primary and secondary carbon dioxide (CO{sub 2}) rich inclusions, suggest a dominantly early magmatic origin for the HCGs. The permeability and porosity in the Khibina pluton can be constrained by the distribution and geometry of fluid inclusion planes (FIPs) and open cracks (OCs), as well as by the magnitude and pathways of fluid flow. Orientation data for FIPs and OCs, obtained from oriented thin sections, revealed a range of orientations in sub-parallel arrays, suggesting continual re-activation of old fracture systems. The extensive occurrence of OCs and sealed FIPs points to long lived porosities and permeabilities with large fluid fluxes integrated over time. FIP and OC density values were found to be consistent with gas release patterns characterized by spontaneous release during mining of large volumes of HCG stored in a network of interconnected, sealed microfractures and fluid inclusion planes that unzip during stress. It was determined that the HCGs have a primary magmatic origin although there is local evidence for limited post-magmatic FT synthesis. Long term continuous gas migration has occurred within the complex through an interconnected set of fractures. FIPs represent aliquots of gas sealed during open system migration. It was concluded that the complex contains a potentially economically viable

  9. Geochemistry of the Serifos calc-alkaline granodiorite pluton, Greece: constraining the crust and mantle contributions to I-type granitoids

    Science.gov (United States)

    Stouraiti, C.; Baziotis, I.; Asimow, P. D.; Downes, H.

    2017-11-01

    The Late Miocene (11.6-9.5 Ma) granitoid intrusion on the island of Serifos (Western Cyclades, Aegean Sea) is composed of syn- to post-tectonic granodiorite with quartz monzodiorite enclaves, cut by dacitic and aplitic dikes. The granitoid, a typical I-type metaluminous calcic amphibole-bearing calc-alkaline pluton, intruded the Cycladic Blueschists during thinning of the Aegean plate. Combining field, textural, geochemical and new Sr-Nd-O isotope data presented in this paper, we postulate that the Serifos intrusion is a single-zoned pluton. The central facies has initial 87Sr/86Sr = 0.70906 to 0.7106, ɛNd(t) = - 5.9 to - 7.5 and δ18Οqtz = + 10 to + 10.6‰, whereas the marginal zone (or border facies) has higher initial 87Sr/86Sr = 0.711 to 0.7112, lower ɛ Nd(t) = - 7.3 to - 8.3, and higher δ18Οqtz = + 10.6 to + 11.9‰. The small range in initial Sr and Nd isotopic values throughout the pluton is paired with a remarkable uniformity in trace element patterns, despite a large range in silica contents (58.8 to 72 wt% SiO2). Assimilation of a crustally derived partial melt into the mafic parental magma would progressively add incompatible trace elements and SiO2 to the evolving mafic starting liquid, but the opposite trend, of trace element depletion during magma evolution, is observed in the Serifos granodiorites. Thermodynamic modeling of whole-rock compositions during simple fractional crystallization (FC) or assimilation-fractional crystallization (AFC) processes of major rock-forming minerals—at a variety of pressure, oxidation state, and water activity conditions—fails to reproduce simultaneously the major element and trace element variations among the Serifos granitoids, implying a critical role for minor phases in controlling trace element fractionation. Both saturation of accessory phases such as allanite and titanite (at SiO2 ≥ 71 wt%)(to satisfy trace element constraints) and assimilation of partial melts from a metasedimentary component (to

  10. Mesozoic alkaline plutonism: Evidence for extensional phase in Alpine-Himalayan orogenic belt in Central Alborz, north Iran

    Directory of Open Access Journals (Sweden)

    Roghieh Doroozi

    2017-12-01

    Full Text Available The Kamarbon Jurassic alkaline basic intrusion crops out in Central Alborz, north Iran, along the northern margin of the Alpine-Himalayan belt. The intrusion includes foid gabbros at the margins and foid monzodiorites towards the center. The foid monzodiorites are considered as the evolved melts after the fractional crystallization mostly of olivine and clinopyroxene from a foid gabbro parental magma. Based on mass balance calculation the evolution of the Kamarbon alkaline gabbro could be explained by 19.2% fractionation of clinopyroxene, 13.8% of olivine, 3% of plagioclase and 1.0% Ti-Magnetite, with 63% of residual liquid. REE inversion modeling indicates that the Kamarbon intrusion magma was generated by low degrees (<3% of partial melting from a garnet-bearing mantle source. In primitive mantle-normalized incompatible element diagrams, the Kamarbon rocks show enrichment in LILE elements (Ba, Rb, Sr and Th, HFSE elements (Nb, Ta, Ti, Zr and Hf and P and depletion in K, Y and HREE (Yb, Lu which are similar to patterns of HIMU-OIBs or intraplate alkaline magmas. According to the existence of extensional phases and occurrence of different rifting during late Triassic to middle Jurassic in Central Alborz, the formation of Kamarbon intrusion could be related to an intracontinental rifting.

  11. PREPUBLICATION: From structure topology to chemical composition. XXIII. Revision of the crystal structure and chemical formula of zvyaginite, a seidozerite-supergroup mineral from the Lovozero alkaline massif, Kola peninsula, Russia

    KAUST Repository

    Sokolova, E.

    2017-04-02

    The crystal structure and chemical formula of zvyaginite, ideally Na2ZnTiNb2(Si2O7)2O2(OH)2 (H2O)4, a lamprophyllite-group mineral of the seidozerite supergroup from the type locality, Mt. Malyi Punkaruaiv, Lovozero alkaline massif, Kola Peninsula, Russia have been revised. The crystal structure was refined with a new origin in space group C⎯1, a = 10.769(2), b = 14.276(3), c = 12.101(2) Å, α = 105.45(3), β = 95.17(3), γ = 90.04(3)°, V = 1785.3(3.2) Å3, R1 = 9.23%. The electron-microprobe analysis gave the following empirical formula [calculated on 22 (O + F)]:(Na0.75Ca0.09K0.04��1.12)Σ2 (Na1.12Zn0.88Mn0.17Fe2+0.04��0.79)Σ3(Nb1.68Ti1.25Al0.07)Σ3 (Si4.03O14)O2 [(OH)1.11F0.89]Σ2(H2O)4, Z = 4. Electron-diffraction patterns have prominent streaking along c* and HRTEM images show an intergrowth of crystalline zvyaginite with two distinct phases, both of which are partially amorphous. The crystal structure of zvyaginite is an array of TS (Titanium Silicate) blocks connected via hydrogen bonds between H2O groups. The TS block consists of HOH sheets (H = heteropolyhedral, O = octahedral) parallel to (001). In the O sheet, the [6]MO(1,4,5) sites are occupied mainly by Ti, Zn and Na and the [6]MO(2,3) sites are occupied by Na at less than 50%. In the H sheet, the [6]MH(1,2) sites are occupied mainly by Nb and the [8]AP(1) and [8]AP(2) sites are occupied mainly by Na and ��. The MH and AP polyhedra and Si2O7 groups constitute the H sheet. The ideal structural formula is Na��Nb2NaZn��Ti(Si2O7)2O2(OH)2(H2O)4. Zvyaginite is a Zn-bearing and Na-poor analogue of epistolite, ideally (Na��)Nb2Na3Ti(Si2O7)2O2(OH)2(H2O)4. Epistolite and zvyaginite are related by the following substitution in the O sheet of the TS-block: (Na+2)epi ↔ Zn2+ zvy + ��zvy. The doubling of the t1 and t2 translations of zvyaginite relative to those of epistolite is due to the order of Zn and Na along a (t1) and b (t2) in the O sheet of zvyaginite.

  12. Relative contributions of crust and mantle to generation of Campanian high-K calc-alkaline I-type granitoids in a subduction setting, with special reference to the Harsit Pluton, Eastern Turkey

    NARCIS (Netherlands)

    Karsli, O.; Dokuz, A.; Uysal, I.; Aydin, F.; Chen, B.; Kandemir, R.; Wijbrans, J.R.

    2010-01-01

    We present elemental and Sr-Nd-Pb isotopic data for the magmatic suite (~79 Ma) of the Harşit pluton, from the Eastern Pontides (NE Turkey), with the aim of determining its magma source and geodynamic evolution. The pluton comprises granite, granodiorite, tonalite and minor diorite (SiO

  13. Geology and U-Pb geochronology of the Kipawa Syenite Complex - a thrust related alkaline pluton - and adjacent rocks in the Grenville Province of western Quebec

    Energy Technology Data Exchange (ETDEWEB)

    Van Breemen, O.; Currie, K.L. [Geological Survey of Canada, Ottawa, Ontario (Canada)]. E-mail: ovanbree@nrcan.gc.ca

    2004-07-01

    The Kipawa Syenite Complex, a thin, folded sheet of amphibole syenite, quartz syenite and minor nepheline syenite, lies along a west-vergent thrust separating a lower slice comprising the Kikwissi granodiorite and biotite tonalite dated at 2717 {sub -11}{sup +15} Ma, and unconformably overlying metasedimentary rocks from an overlying slice containing the Red Pine Chute orthogneiss, an alkali granite gneiss, and the Mattawa Quartzite. The syenite complex, dated at 1033 {+-} 3 Ma, lies within the lower slice but has metasomatically altered the overlying slice. Texturally guided U-Pb spot analyses on partially metasomatised zircons from the alkali granite gneiss yield a cluster of {sup 207}G'Pb/{sup 206}Pb ages at 1389 {+-} 8 Ma, interpreted as the time of igneous crystallization and four ages overlapping the time of syenite emplacement, interpreted as in situ, metasomatic growth. The highest structural slice comprises garnet amphibolite separated from lower slices by the Allochthon Boundary Thrust. Metamorphic grade increases upward from greenschist grade in the biotite tonalite to amphibolite grade (690 {sup o}C, 9 kbar (1 kbar = 100 MPa)) at the lower boundary of the alkali granite. Emplacement of the Kipawa Syenite Complex took place after assembly of the thrust stack had begun and after emplacement of the allochthon or hot slab responsible for the inverted metamorphic gradient. Origin of the syenite is tentatively ascribed to anatexis of material metasomatized by flow of alkaline solutions along a major shear surface. Crystallization of new zircon in the margins of the syenite shows that metasomatism continued from ca. 1035 to 990 Ma, redistributing alkalies, fluorine, rare-earth elements and zirconium. (author)

  14. Garcinia kola (Bitter Kola) as an Antimicrobial Agent: Effects on the ...

    African Journals Online (AJOL)

    Abstract: This work investigated the effects of Garcinia kola (bitter kola) on the normal flora of the mouth. Two methods were adopted in this work. In the first method, the bacterial load of saliva samples collected after chewing Garcinia kola for days 1-5 decreased drastically when compared to bacterial load from saliva ...

  15. Panorama Pluton : a composite gabbro-monzodiorite early Ross Orogeny intrusion in southern Victoria Land, Antarctica

    International Nuclear Information System (INIS)

    Mellish, S.D.; Cooper, A.F.; Walker, N.W.

    2002-01-01

    The Koettlitz Glacier Alkaline Province of the Walcott Glacier to Radian Glacier area of the Transantarctic Mountains contains a diverse suite of intrusions ranging from gabbro and diorite to granite, nepheline syenite, and carbonatite. Most of the plutons are alkaline (A-type), although the Panorama Pluton is mafic, comprising both hypersthene normative gabbroic and quartz normative monzodioritic lithologies. The pluton has a composite nature, determined by whole-rock geochemical trends and Nd-Sr isotope data that reflect distinctive source regions for the different components. U-Pb geochronology of zircon and titanite indicates the Panorama Pluton was intruded during the early stages of the Neoproterozoic-early Paleozoic Ross Orogeny at 535 ± 9 Ma, and that it is coeval with the geochemically similar Dromedary Mafic Complex which crops out 10 km to the southeast. The Panorama Pluton is a volumetrically minor mafic component of the Koettlitz Glacier Alkaline Province, which predates, by at least 15 m.y., the dominant calc-alkaline suites that occur along-strike in the Dry Valleys area to the north, and the central Transantarctic Mountains to the south. The Panorama Pluton magmas, and other Koettlitz Glacier Alkaline Province lithologies, are interpreted to have formed in an extensional or transtensional jog that predates the onset of widespread Ross Orogeny subduction. (author). 48 refs., 7 figs., 3 tabs

  16. Use of local materials in the preservation of Garcinia kola (bitter kola ...

    African Journals Online (AJOL)

    Storage of Bitter kola (Garcinia kola) was carried out using different local materials to evaluate the most appropriate storage material relative to the extension of its shelf life. The materials were kept moist by wetting them throughout the period of study (8 weeks). The local materials used were sandy soil, jute bag, clay pot and ...

  17. Garcinia Kola (Bitter Kola): Is it truly the Wonder Seed? | Labo ...

    African Journals Online (AJOL)

    African Journal of Sustainable Development ... Garcinia kola seed is eaten raw with the belief that it promotes longevity. ... This review summarises the diverse biological activities of Garcinia kola and possible role as an emerging ... Browse By Country · List All Titles · Free To Read Titles This Journal is Open Access.

  18. Isotopic character of Cambro-Ordovician plutonism, southern Victoria Land

    International Nuclear Information System (INIS)

    Cox, S.C.; Parkinson, D.L.; Allibone, A.H.; Cooper, A.F.

    2000-01-01

    Previous mapping of granitoid rocks in the Dry Valleys area of southern Victoria Land, Antarctica, identified the calc-alkaline (DV1a), adakitic (DV1b), and monzonitic (DV2) suites. A fourth older suite comprising alkaline gabbro, syenite, and A-type granite occurs in the Mt Dromedary area c. 80 km to the south. U-Pb zircon dating of Bonney Pluton, the largest calc-alkaline DV1a intrusion, indicates emplacement of this regional-scale body at 505 +/- 2 Ma. Pb-loss and inherited zircon were common to Bonney Pluton analyses of this study. U-Pb dating of monazite from Valhalla Pluton, a principal DV1b suite adakitic intrusion, indicates emplacement at 488 +/- 2 Ma. The Bonney Pluton age constrains the peak of calc-alkaline plutonism at 505 Ma and the Valhalla Pluton age records the major pulse of adakitic plutonism that is inferred to mark the final stages of subduction c. 490 Ma along this section of the East Antarctic margin. Nd and Sr isotope data for the calc-alkaline DV1a suite and adakitic DV1b suite define distinct ranges for each suite, supporting their subdivision on the basis of field relationships, petrography, and whole-rock geochemistry. Calc-alkaline DV1a suite granite magmas have eNd(T) = -4.2 to -6.1 and Sri = 0.7071-0.7079, whereas the adakitic DV1b suite rocks have a wider range of eNd(T) = -1.9 to -7.2 and Sri = 0.7065-0.7097. The isotopic data suggest a significant mantle component and subordinate crustal component in the source region of both suites. Time-dependent variations in the isotopic ratios of DV1a and DV1b suites imply a progressive increase in the proportion of more radiogenic material in the source region of the granitoid rocks, either mantle- or crust-derived material. Larger adakitic DV1b plutons are more 'evolved' than equivalent, smaller plutons of the same DV1b suite. Vanda Dikes and monzonitic DV2 suite intrusions are characterised by particularly low Sri = 0.7044-0.7067 and near-constant eNd(T) = -4.8 to -5.3, which indicate a

  19. Garcinia kola extract reduced lipopolysaccharide activation of ...

    African Journals Online (AJOL)

    The effect of Garcinia kola heckel seed extract on the promonocytic cell line U937 activated by lipopolysaccharide (LPS) was investigated. 200 l of U937 cells maintained in culture at 5 x 105 cells per ml was delivered into wells of a culture plate according to groups. Cells were pre-treated with 20 l of 100 ng/ml phorbol ...

  20. Siudaite, Na8(Mn2+ 2Na)Ca6Fe3+ 3Zr3NbSi25O74(OH)2Cl·5H2O: a new eudialyte-group mineral from the Khibiny alkaline massif, Kola Peninsula

    Science.gov (United States)

    Chukanov, Nikita V.; Rastsvetaeva, Ramiza K.; Kruszewski, Łukasz; Aksenov, Sergey M.; Rusakov, Vyacheslav S.; Britvin, Sergey N.; Vozchikova, Svetlana A.

    2018-03-01

    The new eudialyte-group mineral siudaite, ideally Na8(Mn2+ 2Na)Ca6Fe3+ 3Zr3NbSi25O74(OH)2Cl·5H2O, was discovered in a peralkaline pegmatite situated at the Eveslogchorr Mt., Khibiny alkaline massif, Kola Peninsula, Russia. The associated minerals are aegirine, albite, microcline, nepheline, astrophyllite, and loparite-(Ce). Siudaite forms yellow to brownish-yellow equant anhedral grains up to 1.5 cm across. Its lustre is vitreous, and the streak is white. Cleavage is none observed. The Mohs' hardness is 4½. Density measured by hydrostatic weighing is 2.96(1) g/cm3. Density calculated using the empirical formula is equal to 2.973 g/cm3. Siudaite is nonpleochroic, optically uniaxial, negative, with ω = 1.635(1) and ɛ = 1.626(1) (λ = 589 nm). The IR spectrum is given. The chemical composition of siudaite is (wt%; electron microprobe, H2O determined by HCN analysis): Na2O 8.40, K2O 0.62, CaO 9.81, La2O3 1.03, Ce2O3 1.62, Pr2O3 0.21, Nd2O3 0.29, MnO 6.45, Fe2O3 4.51. TiO2 0.54, ZrO2 11.67, HfO2 0.29, Nb2O5 2.76, SiO2 47.20, Cl 0.54, H2O 3.5, -O = Cl - 0.12, total 99.32. According to Mössbauer spectroscopy data, all iron is trivalent. The empirical formula (based on 24.5 Si atoms pfu, in accordance with structural data) is [Na7.57(H2O)1.43]Σ9(Mn1.11Na0.88Ce0.31La0.20Nd0.05Pr0.04K0.41)Σ3(H2O)1.8(Ca5.46Mn0.54)Σ6(Fe3+ 1.76Mn2+ 1.19)Σ2.95Nb0.65(Ti0.20Si0.50)Σ0.71(Zr2.95Hf0.04Ti0.01)Σ3Si24.00Cl0.47O70(OH)2Cl0.47·1.82H2O. The crystal structure was determined using single-crystal X-ray diffraction data. The new mineral is trigonal, space group R3m, with a = 14.1885(26) Å, c = 29.831(7) Å, V = 5200.8(23) Å3 and Z = 3. Siudaite is chemically related to georgbarsanovite and is its analogue with Fe3+-dominant M2 site. The strongest lines of the powder X-ray diffraction pattern [d, Å (I, %) (hkl)] are: 6.38 (60) (-114), 4.29 (55) (-225), 3.389 (47) (131), 3.191 (63) (-228). 2.963 (100) (4-15), 2.843 (99) (-444), 2.577 (49) (3-39). Siudaite is named after the Polish

  1. In vitro study of interaction between quinine and Garcinia kola ...

    African Journals Online (AJOL)

    Purpose: To investigate the interaction between quinine and Garcinia kola using an in vitro adsorption study. Methods: In vitro interaction between quinine and G. kola was conducted at 37 ± 0.1 °C. Adsorption of quinine (2.5 - 40 μg/ml) to 2.5 % w/v G. kola suspension was studied. Thereafter, quinine desorption process ...

  2. The Solarya Volcano-Plutonic Complex (NW Turkey): Petrography, Petrogenesis and Tectonic Implications

    Science.gov (United States)

    Ünal, Alp; Kamacı, Ömer; Altunkaynak, Şafak

    2014-05-01

    The post collisional magmatic activity produced several volcano-plutonic complexes in NW Anatolia (Turkey) during the late Oligocene- Middle Miocene. One of the major volcano-plutonic complexes, the Solarya volcano-plutonic complex is remarkable for its coeval and cogenetic plutonic (Solarya pluton), hypabysal and volcanic rocks of Early Miocene (24-21 Ma) age. Solarya pluton is an epizonal pluton which discordantly intruded into metamorphic and nonmetamorphic basement rocks of Triassic age. It is a N-S trending magmatic body covering an area of 220 km2,approximatelly 20 km in length and 10 km in width. Based on the field and petrographic studies, three main rock groups distinguished in Solarya pluton; K-feldspar megacrystalline granodiorite, microgranite-granodiorite and haplogranite. Porphyritic and graphic-granophyric textures are common in these three rock groups. Pluton contains magmatic enclaves and syn-plutonic dykes of dioritic composition. Hypabyssal rocks are represented by porphyritic microdiorite and porphyritic quartz-diorite. They form porphyry plugs, sheet inrusions and dykes around the pluton. Porphyrites have microcrystalline-cryptocrystalline groundmass displaying micrographic and granophyric textures. Petrographically similar to the hypabyssal rocks, volcanic rocks are formed from andesitic and dasitic lavas and pyroclastic rocks. Plutonic, hypabyssal and volcanic rocks of Solarya volcano-plutonic complex show similar major-trace element and Sr-Nd-Pb isotopic compositions, indicating common magmatic evolution and multicomponent melt sources including mantle and crustal components. They are mainly metaluminous, medium to high-K calc alkaline rocks and display enrichment in LILE and depletion in Nb, Ta, P and Ti. They have initial 87Sr/86Sr values of 0.70701- 0.70818 and 143Nd/144Nd values of 0.51241-0.51250. These geochemical characteristics and isotopic signatures are considered to reflect the composition of the magmas derived from a

  3. Kola reindeer herder measured by Finns

    International Nuclear Information System (INIS)

    Illukka, E.; Rahola, T.

    1995-01-01

    Experts from the Finnish Centre for Radiation and Nuclear Safety and from the Department of Radiochemistry of the University of Helsinki travelled in August 1994 to Lovozero in the Kola peninsula, Russia, to study the local radioactivity contents. The purpose of the study, which formed a part of the science and technology cooperation programme between Finland and Russia, was to compare activity levels in Kola and in Finnish Lapland, in the food chain between lichen, reindeer and people. By means of samples taken from nature, the study group also determined the composition of fallout from nuclear weapons tests and from the Chernobyl accident. Using a whole-body counting system, the experts measured 33 people from Lovozero. Samples were collected, for instance, of reindeer meat, lichen and the bottom sediment of Lovozero lake. On the basis of preliminary findings, it seems that the levels of radiocesium do ALARA 1/1995. (orig.)

  4. Discussion on the petrochemistry characteristics and uranium deposit of Xiazhuang pluton in northern Guangdong province

    International Nuclear Information System (INIS)

    Wu Jiguang

    2011-01-01

    The element characteristic of Indo-Chinese epoch Xiazhuang granite is rich in silicon (SiO 2 =69.13%∼73.39%), alkalis (K 2 O+Na 2 O=7.49%∼8.69%), the ASI=1.01∼1.21 and ratio of w (K 2 O)/w (Na 2 O)>1, Xiazhuang pluton is belong to high potassium calcium-alkaline and aluminous series rocks. It shows that the pluton is typical S-type granite, little part is A-type granite character. Under the extension tectonic setting of lithosphere, the Xiazhuang pluton is partial melting product that making up metamorphic mud and sandstone together. By analysing the tectonic setting,the pluton is belong to post-collision granite that original rock provide abundant of uranium content for granite and the tectonic setting of forming provide the moving channels and occurrence space for uranium deposit. (authors)

  5. In vitro study of interaction between quinine and Garcinia kola

    African Journals Online (AJOL)

    Methods: In vitro interaction between quinine and G. kola was conducted at 37 ± 0.1 °C. Adsorption of ... The amount of quinine adsorbed and desorbed was quantified using HPLC. A ..... first place, G. kola is known to contain flavonoids.

  6. Preliminary studies on ethanol production from Garcinia kola (bitter ...

    African Journals Online (AJOL)

    Dr. J. T. Ekanem

    A study on yeast fermentation of bitter kola pod( agricultural waste) was ... optimization of the ethanol production were investigated. ... components of biomass to produce a liquid .... Mani, S., Tabil, L. G. and Opoku, A. (2002). Ethanol from Agricultural crop residues-An. Overview. ... Effect of acid hydrolysis of Garcinia kola.

  7. Geochemistry and U/Pb geochronology of the Neuvy-Bouin pluton (Vendean Haut-Bocage): an example of a multistage granite pluton

    International Nuclear Information System (INIS)

    Cuney, M.; Brouand, M.; Dautel, D.; Michard, A.; Stussi, J.M.; Poncet, D.; Bouton, P.; Colchen, M.; Vervialle, J.P.

    1993-01-01

    New geological, structural and geochemical data show the presence of at least four magmatic units in the Neuvy-Bouin massif. U/Pb zircon age (340±4 Ma) obtained on the Largeasse granites indicates that in the Neuvy-Bouin pluton the magmatic activity began during Visean times. The emplacement of the Largeasse granites is followed by the aluminopotassic two-mica granites of Pougne-Herisson and by two mica leucogranites. The small high-K calc-alkaline granite body discovered in the Neuvy-Bouin pluton represents the first occurrence of this type of magmatism in the area

  8. Effects of gamma radiation on the kola nut weevil, Balanogastris kolae (Desbr. ) (Coleopera: Curculionidae)

    Energy Technology Data Exchange (ETDEWEB)

    Ivbijaro, M F [Ibadan Univ. (Nigeria)

    1977-09-01

    Studies on the kola nut weevil, Balanogastris kolae (Desbr.) with gamma radiation showed that 20 krad effectively caused high larval mortality and prevented pupation. Dead larvae became soft and bluishblack and, occasionally, dry and brown. Percentage adult emergence from irradiated pupae, longevity and fecundity of emerging adults provided the basis for evaluating the effectiveness of the ionizing radiation. Mean survival and adult emergence from young pupae irradiated with 20 krad was 6 and 2 percent, respectively, in contrast to 86 and 8 percent, respectively, in old pupae given the same dosage. Old pupae (3-5 days old) showed some tolerance to gamma radiation and over 20 krad was required to prevent adult emergence. Gamma radiation seriously reduced longevity to an average of 6 and 15 days, respectively, in pre- and post-emergence irradiated adults in contrast to 44 days in the control. Distortion of the membranous hind wings were some of the adverse effects observed in adults that emerged from irradiated pupae. Reproduction and oviposition was seriously impaired by irradiation before or immediately after emergence. The opinion of a panel of experienced kola nut testers was that gamma irradiation did not alter the taste or flavour of the kola nuts and no change was observed in the colour or texture of the irradiated nuts.

  9. The bioactive and phytochemical properties of Garcinia kola (Heckel ...

    African Journals Online (AJOL)

    STORAGESEVER

    2008-11-05

    Nov 5, 2008 ... cardiac glycoside, saponins, steroids and reducing sugars. Key words: ..... to be a novel cancer therapeutic agent (Robert et al.,. 2008). Cardiac ... their relationship with such compounds as sex hormone. (Okwu, 2001).G. kola ...

  10. in-vitro antifungal effect of garcinia kola and garlic

    African Journals Online (AJOL)

    boaz

    Alliums sativum and Garcinia kola seeds were tested for their ... resistance and this has led to development of more potent synthetic ... outer coat were removed, the cloves were air dried at .... regulated genes to Candida albicans virulence.

  11. Efficiency of bitter kola marketing in Abia State, Nigeria | Iheke ...

    African Journals Online (AJOL)

    Efficiency of bitter kola marketing in Abia State, Nigeria. ... The goal of marketing of agricultural products is to ensure that consumers get satisfaction from the entire process of production, as well as ... EMAIL FULL TEXT EMAIL FULL TEXT

  12. Economic Value Of Garcinia kola Marketing In Enugu State, Nigeria ...

    African Journals Online (AJOL)

    Economic Value Of Garcinia kola Marketing In Enugu State, Nigeria. ... returns and identifying and determining the Socio-economic variables that affect the marketers net returns. Three markets, one ... EMAIL FULL TEXT EMAIL FULL TEXT

  13. Gastroprotective potentials of the methanolic extract of Garcinia kola ...

    African Journals Online (AJOL)

    McRoy

    Induced Oxidative. Gastric Mucosa Damage in Rats by Kolaviron, A Natural. Biflavonoid of Garcinia kola Seed. Phytother Res. 2006;20:14-20. 8. Ibironke GF, Olaleye SB, Balogun O and Aremu. DA. Antiulcerogenic effect of diet containing seeds of.

  14. Fuel consumption organization at the Kola NPP

    International Nuclear Information System (INIS)

    Matveev, A.A.; Ignatenko, E.I.; Volkov, A.P.; Trofimov, B.A.

    1981-01-01

    Problems of using NPPs in the power systems including hydroelectric power plants and NPPs are considered on the example of the Kola power system. The methods of the WWER-440 reactor fuel loading formation, reactor power forcing, optimization of volumes and time of the NPP main equipment planned maintenance are discussed. It is concluded that the optimal methods for the WWER-440 reactor fuel loading formation are the following: reactor make-up with the lesser number of fuel assemblies with maximum designed enrichment; for the case of decreased loading energy capacity displacement of make-up fuel with 2.4% enrichment by the fuel with 3.6% enrichment when preserving the designed number of make-up fuel assemblies [ru

  15. Compositional Evolution of Pyrochlore-Group Minerals in Carbonatites of the Belaya Zima Pluton, Eastern Sayan

    Science.gov (United States)

    Khromova, E. A.; Doroshkevich, A. G.; Sharygin, V. V.; Izbrodin, L. A.

    2017-12-01

    Pyrochlore-group minerals are the main concentrators of niobium in carbonatites of the Belaya Zima alkaline pluton. Fluorcalciopyrochlore, kenopyrochlore and hydropyrochlore were identified in chemical composition. Their main characteristics are given: compositional variation, morphology, and zoning. During evolution from early calcite to late ankerite carbonatites, the UO2, TiO2, REE, and Y contents gradually increased. All carbonatite types are suggested to contain initial fluorcalciopyrochlore. However, in calcite-dolomite and ankerite carbonatites, it is partially or completely hydrated due to hydrothermal processes at the late stage of the pluton. This hydration resulted in the appearance of kenopyrochlore and hydropyrochlore due to removal of Ca, Na and F, and input of Ba, H2O, K, Si, Fe, and probably U and REE. At the last stage of the pluton, this hydrated pyrochlore was replaced by Fe-bearing columbite.

  16. Correct nomenclature for the Angadimogar pluton, Kerala ...

    Indian Academy of Sciences (India)

    The proper usage of modal composition and geochemical classification of granitoids is discussed for assigning a proper nomenclature for the Angadimogar pluton, Kerala, southwestern India. This discussion is mainly aimed at addressing questions concerning the nomenclature of Angadimogar pluton (syenite vs. granite).

  17. The Study of enclaves and relative age of plutonic bodies in the Alvand Plutonic complex

    International Nuclear Information System (INIS)

    Sepahi Gerow, A. A.; Moien-Vaziri, H.

    2000-01-01

    The study of enclaves and field observations indicate that: The Alvand plutonic complex comprise several plutonic phases with sharp contact and different ages. The older plutonic rocks are composed of gabbro, diorite and tonalites. The porphyroid granites were formed at least in two phases and they are younger than gabbros, diorites and tonalites. The hololeucocratic granitoids were also formed in two phases and they are the youngest plutonic phase in the Alvand plutonic complex. The granitic rocks are magmatic and they are not metasomatic in origin. The porphyroid granites (monzogranites and granodiorites) are S-type (Anatexites). According to radiometric ages and relative ages we believe that mafic plutonism have occurred during pre-middle Cretaceous to Paleocene ages and felsic plutonism have occurred during middle Cretaceouc to Paleocene ages

  18. Effect of Combined Intake of Garcinia Kola and Ascorbic Acid on ...

    African Journals Online (AJOL)

    Proximate and nutritional composition of kola nut, garcinia kola and alligator pepper. African Journal ... primarily carried bound to albumin in the blood and only a minor amount is ... increased oxida ve stress. With regular intake, the ascorbic ...

  19. Evaluation of the anti-fertility effect of Garcinia Kola Seeds on male ...

    African Journals Online (AJOL)

    In Nigeria, West Africa, Garcinia Kola seed is widely use for social, therapeutic and nutritional purposes. In recent times, there have been reports about its negative effects on male fertility. In view of this, a study was carried out to evaluate the effect of Garcinia Kola seed on male fertility indices. 2Kg of the Garcinia Kola seed ...

  20. Genesis of zoned granite plutons in the Iapetus Suture Zone: new constraints from high-precision micro-analysis of accessory minerals

    OpenAIRE

    Miles, Andrew James

    2013-01-01

    The Trans-Suture Suite (TSS) of granitic plutons located in Northern Britain span the Iapetus Suture and represent a particularly enigmatic stage of post-Caledonian Devonian magmatism. Despite calc-alkaline affinities, proximity to the Iapetus Suture precludes a direct relationship to active subduction. Furthermore, the absence of inherited zircons distinguishes the TSS from plutons of a similar age throughout the Scottish Highlands, and is not easily reconciled with the abunda...

  1. Possibilities for wind energy on the Kola peninsula

    Energy Technology Data Exchange (ETDEWEB)

    Wolff, J; Rathmann, O; Lundsager, P [and others

    1999-03-01

    This paper presents an extensive feasibility study regarding the introduction of wind energy in the energy supply of the Kola peninsula in north-western Russia that was carried out during 1996-97. The study covers as well grid connected wind turbines as autonomous systems and a wind atlas was prepared. Special emphasis is put on non-technical activities and objectives like financing models, international funding and a sound politic support. The wind resources on the Kola peninsula are excellent and there are still no reasons to why wind energy installations couldn`t be carried out successfully. Recommendations for starting this development are presented. (au)

  2. Unusual Rb-Sr data on the age of two typical peralkaline granitoid plutons in West Transbeikalia

    International Nuclear Information System (INIS)

    Litvinovskij, B.A.; Posokhov, V.F.; Zanvilevich, A.N.

    1995-01-01

    Rb-Sr isotope study of two typical plutons in West Transbaikalia (Bryansk and Kharitonov) has been carried out. For alkaline and peralkaline suits of the Bryansk pluton the obtained data are 287 ± m.y., I Sx =0.7054 ± 3 and 285 ± 1 m.y., I Sr =0.7037 ± 3 respectively. Rb-Sr age of peralkaline syenites and granites from the Kharitonov pluton are in more or less consistency with those on the Malokunal pluton (233 ± 5 m.y.) and much less than the age of the Khorinsk pluton (253 ± 3 m.y.). Taking into account the K-Ar data on amphibole from the peralkaline granitoids it is concluded that probable age of these rocks span the interval 250-220 m.y. However results obtained from the Bryansk pluton suggest that within the Mongolia-Transbaikalia belt one more stage of peralkaline granitoid generation i.e. the Early Permian stage could be manifested as well. 20 refs.; 5 figs.; 3 tabs

  3. Petrography and geochemistry of five granitic plutons from south central Uruguay: contribution to the knowledge of the Piedra Alta terrane

    International Nuclear Information System (INIS)

    Preciozzi, F.

    2005-01-01

    Granitoid rocks in south-central Uruguay are largely concentrated in three east-west trending metamorphic belts, known as (from south to north) the Montevideo Belt, the San José Belt and the Arroyo Grande Belt. These belts are separated from one another by intervening bands of gneisses of granitic composition. The whole assemblage, the gneisses as well as the metamorphic belts and their associated granites, collectively constitute the Piedra Alta Terrane. Five of these granite plutons, two from the San José Belt and three from the Arroyo Grande Belt, have been studied in some detail and the chemical composition of 86 samples (major elements as well as a selected suite of trace elements) have been determined. These data, as well as Rb-Sr isotopic data, show that these plutons are typically composite in nature, and that the various units range in age from 1900 Ma to 2500 Ma. The older ages were obtained from the main units of the plutons themselves whereas the younger ages are from late dykes which were emplaced into the plutons and which are clearly not related to them. The plutons are predominantly, but not exclusively, of calc-alkaline affinity and are typically synorogenic whereas the dykes are post-orogenic and are either calc-alkaline or alkaline in composition. These data have been incorporated into a tectonic model for the Piedra Alta Terrane which is considerably different from that heretofore proposed. The essential features of the geological history of the area are: 1) development of an older ''basement'' of granitic gneisses 2) deposition, upon or adjacent to this gneisses basement, of a typical Archean greenstone belt assemblage (no komatiites so far reported) 3) Paleo-proterozoic metamorphism, followed by syn-tectonic to post-tectonic intrusion of the plutonic rocks 4) major tectonic dislocation(s) associated with the Transamazonian orogeny 5) dyke emplacement (post-orogenic to anorogenic) following the Transamazonian orogeny

  4. Distinctly different parental magmas for plutons and lavas in the central Aleutian arc

    Science.gov (United States)

    Cai, Y.; Rioux, M. E.; Kelemen, P. B.; Goldstein, S. L.; Bolge, L.; Kylander-Clark, A. R.

    2014-12-01

    While it is generally agreed that continental crust is generated by arc magmatism, average arc lavas are basaltic while the bulk continental crust is andesitic, and this has led to many models for secondary reprocessing of the arc crust in order to form continental crust. We report new data on calc-alkaline plutons in the central Aleutians showing that they have distinctly different sources compared to Holocene tholeiitic lavas. Therefore the lavas are not representative of the net magmatic transfer from the mantle into the arc crust. Eocene to Miocene (9-39 Ma) intermediate to felsic plutonic rocks from the central Aleutian arc show higher SiO2 at a given Mg#, higher ɛNd- and ɛHf-values, and lower Pb isotope ratios than Holocene volcanic rocks from the same region. Instead, the plutonic rocks resemble volcanics from the western Aleutians isotopically, and have chemical compositions similar to bulk continental crust. These data could reflect temporal variation of Aleutian magma source compositions, from Eocene-Miocene "isotopically depleted" and predominantly calc-alkaline to Holocene "isotopically enriched" and predominantly tholeiitic. Alternatively, they may reflect different transport and emplacement processes for the magmas that form plutons and lavas: calc-alkaline magmas with higher Si content and high viscosity may preferentially form plutons, perhaps after extensive mid-crustal degassing of initially high water contents. The latter case implies that the upper and middle arc crust is more like the calc-alkaline bulk composition of the continental crust than the lavas alone. Crustal reprocessing mechanisms that preserve upper and middle arc crust, while removing lower arc crust, can account for the genesis and evolution of continental crust. Since gabbroic lower arc crust extends from ca 20-40 km depth, and is density stable over most of this depth range, "delamination" of dense lithologies [1] may not be sufficient to accomplish this. Alternatively

  5. Antibacterial Interaction of Crude Methanol Extract of Garcinia kola ...

    African Journals Online (AJOL)

    Purpose: Concurrent use of orthodox and herbal medicines is likely to precipitate an overall effect which may or may not be beneficial to the patient. The objective of this study was to evaluate the antimicrobial interaction between the methanol extract of Garcinia kola seed (GKS) which is chewed habitually as a masticatory ...

  6. The bioactive and phytochemical properties of Garcinia kola (Heckel ...

    African Journals Online (AJOL)

    STORAGESEVER

    2008-11-05

    Nov 5, 2008 ... About 0.5 g of the extract was dissolved in 2 ml of glacial acetic acid containing .... this observation, G. kola extract compared favourably with the .... lactone and other volatile constituents of the oleoresin from seeds of. Garcinia ...

  7. Kolaviron, a biflavonoid complex from Garcinia kola seeds ...

    African Journals Online (AJOL)

    In previous studies, we established that kolaviron (KV) (a biflavonoid from Garcinia kola seeds) elicited anti-oxidative and hepatoprotective effects in Wistar rats chronically treated with ethanol. The present study investigates the possible ameliorative effect of KV against ethanol-induced reproductive toxicity in male Wistar ...

  8. Antibacterial activity of methanolic extract of Garcinia kola (Heckel ...

    African Journals Online (AJOL)

    This has lent credence to the ethnopharmaceutical claims of the curative affect of raw-chewed Garcinia kola seeds on throat infections as well as highlighting the bacterial resistance to standard antibiotics, particularly, the β-lactams. African Journal of Clinical and Experimental Microbiology Vol. 8 (1) 2007: pp. 68-76 ...

  9. Plutonic rocks in the Mineoka-Setogawa ophiolitic mélange, central Japan: Fragments of middle to lower crust of the Izu-Bonin-Mariana Arc?

    Science.gov (United States)

    Ichiyama, Yuji; Ito, Hisatoshi; Hokanishi, Natsumi; Tamura, Akihiro; Arai, Shoji

    2017-06-01

    A Paleogene accretionary complex, the Mineoka-Setogawa Belt, is distributed around the Izu Collision Zone, central Japan. Plutonic rocks of gabbro, diorite and tonalite compositions are included as fragments and dykes in an ophiolitic mélange in this belt. Zircon U-Pb dating of the plutonic rocks indicates that they were formed at ca. 35 Ma simultaneously. These ages are consistent with Eocene-Oligocene tholeiite and calc-alkaline arc magmatism in the Izu-Bonin-Mariana (IBM) Arc and exclude several previous models for the origin of the Mineoka-Setogawa ophiolitic rocks. The geochemical characteristics of these plutonic rocks are similar to those of the Eocene-Oligocene IBM tholeiite and calc-alkaline volcanic rocks as well as to the accreted middle crust of the IBM Arc, the Tanzawa Plutonic Complex. Moreover, their lithology is consistent with those of the middle and lower crust of the IBM Arc estimated from the seismic velocity structure. These lines of evidence strongly indicate that the plutonic rocks in the Mineoka-Setogawa ophiolitic mélange are fragments of the middle to lower crust of the IBM Arc. Additionally, the presence of the Mineoka-Setogawa intermediate to felsic plutonic rocks supports the hypothesis that intermediate magma can form continental crust in intra-oceanic arcs.

  10. Petrology and radiogeology of the Stripa pluton

    Energy Technology Data Exchange (ETDEWEB)

    Wollenberg, H.; Flexser, S.; Andersson, L.

    1980-12-01

    Both the quartz monzonite and the metavolcanic leptite which it intruded are strongly fractured. Two stages of fracture filling are evident; an earlier stage encompassing quartz, sericite, feldspar, epidote, and chlorite, and a later stage dominated by carbonate minerals. The Stripa quartz monozite is chemically and mineralogically distinct from other plutons in the region. Muscovite is the predominant mica in the quartz monzonite; biotite has been altered to chlorite, hornblende is absent, and accessory minerals are scarce. In contrast, in other plutons in the Stripa region, biotite and hornblende are prominent mafic minerals and accessory minerals are abundant. The Stripa quartz monzonite is also considerably more radioactive than the the leptite and other plutons in the region. Uranium and thorium abundances are both approx. 30 ppM, considerably higher than in normal granitic rocks where the thorium-to-uranium ratio generally exceeds 2. Potassium-argon dating of muscovite from the Stripa quartz monzonite indicates that this rock may be older, at 1691 million years than granitic rock of the neighboring Gusselby and Kloten massifs, whose ages, based on K-Ar dating of biotite, are respectively 1604 and 1640 m.y. Heat flow and heat productivity considerations show that although Stripa quartz monzonite contains high abundances of radioelements, the pluton has little efect on the regional heat flow. If it occurs in a layered plutonic setting, it is not more than 1.5 km thick; otherwise it may comprise a stock, dike, or border phase that is relatively small compared with the large granitic plutons exposed in the region.

  11. Bullialdus - Strengthening the case for lunar plutons

    Science.gov (United States)

    Pieters, Carle M.

    1991-01-01

    Although many craters expose materials of a composition different from that of the local surroundings, Bullialdus has excavated material representing three distinct stratigraphic zones that occur in the upper 6 km of crust, the top two of which are gabbroic and the deepest of which is noritic. This three-component stratigraphy at Bullialdus provides strong evidence that the lunar crust includes pockets of compositionally layered material reminiscent of mafic layered plutons. When combined with previous information on the compositional diversity at other large craters, these remote analyses obtained in a geologic context substantially strengthen the hypothesis suggested from lunar samples that plutons play an integral role in lunar crustal evolution.

  12. K, Rb and Sr abundances and Sr isotopic composition of the Tanzawa granitic and associated gabbroic rocks, Japan: low-potash island arc plutonic complex

    International Nuclear Information System (INIS)

    Ishizaka, K.; Yanagi, T.

    1977-01-01

    The granitic and associated gabbroic rocks of the Tanzawa plutonic complex of Miocene age occurring in the northern part of the Izu-Bonin arc are characterized by low abundances of K (229-6790 ppm) and Rb (0.414-12.1 ppm), low K 2 O/Na 2 O ratios (0.037-0.21), moderately high K/Rb ratios (541-630), low Rb/Sr ratios (0.00137-0.0579) and low initial 87 Sr/ 86 Sr ratios (0.70332-0.70372). This indicates that acid to intermediate plutonic rocks with these geochemical characteristics also occur in island arc environments besides mid-oceanic ridge environments. They represent, together with associated gabbroic rocks, a low-potash island arc plutonic complex and are expected to occur beneath young island arcs, although now unexposed. The Tanzawa plutonic complex may have been formed by differentiation of low-K calc-alkaline magma. (Auth.)

  13. Mineralization related to Alvand pluton in the Hamadan, western Iran

    Science.gov (United States)

    Salehi, M. H.; Doosti, E. A.; Ahadnejad, V.

    2009-04-01

    The Alvand (Hamadan) plutonic batholith is one of the largest plutonic bodies in the Sanandaj-Sirjan metamorphic belt. This complex is consist of mafic part (gabbro-diorite-tonalite), intermediate (granite-granodiorite porphyroids), and hololeucocratic granitoids. Previous studies have shown that S-type granite-granodiorites are mostly peraluminous and calc-alkaline; the gabbro-diorite-tonalite suite is mostly metaluminous and tholeiitic to calc-alkaline (Sepahi, 2008). High initial 87Sr-86Sr ratios (0.7081 to 0.7115), low epsilon Nd values (-1.0 to -3.3), and peraluminous character reflects a different origin for the granites, possibly crustal sources (Ghalamghash et al, 2007). Aplite-pegmatite dikes are intruded in granitoide rocks, metamorphic rocks and the contact of Alvand granite with metamorphic rocks. The contact of Alvand granite with metamorphic rocks is sharp. By using heavy mineral studies on the alluvium of Alvand complex, it is recognized 28 minerals amongst Scheelite, Cassiterite, Ilmenite, Zircon and Garnet. Different geostatistical studies such as variant, bivariant and multivariant studies have been done on rough data of heavy minerals. They showed normal concentration of gold in studied rocks and low enrichment of tin and tungsten. The index of the ore elements average, frequeney distribution criteria of elements, the ratio of elements index and multielements show that Alvand granite is barren. Mineralography studies did not recognized any tin and tungsten minerals. The grains of gold was recognized in some of the microscopic thin sections. Calcopyrotite is the most important ore mineral that is accompanied with oxides and iron carbonates. The contacts of aplite-pegmatite dikes with granitoide rocks mostly are not prolific. For recognizing Scheelite, some samples of rocks studied by ultraviolet and few Scheelite is recognized in the samples. Some alteration zone observed in this area but they are not accompany with main mineralization. Although

  14. Petrology and radiogeology of the Stripa pluton

    International Nuclear Information System (INIS)

    Wollenberg, Harold; Flexser, Steve; Andersson, Lennart

    1980-01-01

    To better define the character of the rock encompassing the thermomechanical and hydrological experiments at the Stripa mine in central Sweden, and to help determine the size of the Stripa pluton, detailed studies were conducted of the petrology and radiogeology of the quartz monzonite and adjacent rocks. Petrologic studies emphasized optical petrography, with supplementary X-ray diffraction, X-ray fluorescence and microprobe analyses. Radiogeologic investigations were based primarily on surface and underground gamma-ray spectrometric measurements of uranium, thorium and potassium, supplemented by laboratory gamma spectrometric analyses and fission-track radiographic determinations of the locations and abundance of uranium in the rock matrix. Both the quartz monzonite and the metavolcanic leptite which it intruded are strongly fractured. Two stages of fracture filling are evident; an earlier stage encompassing quartz, sericite, feldspar, epidote, and chlorite, and a later stage dominated by carbonate minerals. The Stripa quartz monzonite is chemically and mineralogically distinct from other plutons in the region. Muscovite is the predominant mica in the quartz monzonite; biotite has been altered to chlorite, hornblende is absent, and accessory minerals are scarce. In contrast, in other plutons in the Stripa region biotite and hornblende are prominent mafic minerals and accessory minerals are abundant. The Stripa quartz monzonite is also considerably more radioactive than the leptite and other plutons in the region. Uranium and thorium abundances are both- 30 ppm, considerably higher than in 'normal' granitic rocks where the thorium-to-uranium ratio generally exceeds 2. Potassium-argon dating of muscovite from the Stripa quartz monzonite indicates that this rock may be older, at 1691 million years than granitic rock of the neighboring Gusselby and Kloten massifs, whose ages, based on K-Ar dating of biotite, are respectively 1604 and 1640 m.y. Heat flow and heat

  15. Petrology and radiogeology of the Stripa pluton

    Energy Technology Data Exchange (ETDEWEB)

    Wollenberg, Harold; Flexser, Steve; Andersson, Lennart

    1980-12-01

    To better define the character of the rock encompassing the thermomechanical and hydrological experiments at the Stripa mine in central Sweden, and to help determine the size of the Stripa pluton, detailed studies were conducted of the petrology and radiogeology of the quartz monzonite and adjacent rocks. Petrologic studies emphasized optical petrography, with supplementary X-ray diffraction, X-ray fluorescence and microprobe analyses. Radiogeologic investigations were based primarily on surface and underground gamma-ray spectrometric measurements of uranium, thorium and potassium, supplemented by laboratory gamma spectrometric analyses and fission-track radiographic determinations of the locations and abundance of uranium in the rock matrix. Both the quartz monzonite and the metavolcanic leptite which it intruded are strongly fractured. Two stages of fracture filling are evident; an earlier stage encompassing quartz, sericite, feldspar, epidote, and chlorite, and a later stage dominated by carbonate minerals. The Stripa quartz monzonite is chemically and mineralogically distinct from other plutons in the region. Muscovite is the predominant mica in the quartz monzonite; biotite has been altered to chlorite, hornblende is absent, and accessory minerals are scarce. In contrast, in other plutons in the Stripa region biotite and hornblende are prominent mafic minerals and accessory minerals are abundant. The Stripa quartz monzonite is also considerably more radioactive than the leptite and other plutons in the region. Uranium and thorium abundances are both- 30 ppm, considerably higher than in "normal" granitic rocks where the thorium-to-uranium ratio generally exceeds 2. Potassium-argon dating of muscovite from the Stripa quartz monzonite indicates that this rock may be older, at 1691 million years than granitic rock of the neighboring Gusselby and Kloten massifs, whose ages, based on K-Ar dating of biotite, are respectively 1604 and 1640 m.y. Heat flow and heat

  16. Helminths of brown bears (Ursus arctos) in the Kola Peninsula.

    Science.gov (United States)

    Bugmyrin, S V; Tirronen, K F; Panchenko, D V; Kopatz, A; Hagen, S B; Eiken, H G; Kuznetsova, A S

    2017-06-01

    We present data on the species composition of helminths in brown bears (Ursus arctos) from the Murmansk Region, Russia. The absence of any information about helminths of brown bear in the region necessitated the conduct of these studies. Samples were collected in 2014 and 2015 in the southern part of the Kola Peninsula from the White Sea coastal habitats. Annually, in the study area, 1-3 bears are legally hunted and biological samples for examination are very difficult to obtain. Therefore, we used fecal samples. We studied 93 feces and identified parasite eggs identified in 43 of them by morphometric criteria. The surveys revealed eggs of the following helminths: Dicrocoelium sp., Diphyllobothrium sp., Anoplocephalidae, Capillariidae, Baylisascaris sp., Strongylida 1, and Strongylida 2. These results represent the first reconnaissance stage, which allowed characterizing the taxonomic diversity and prevalence of parasites of brown bears of the Kola Peninsula.

  17. Technology for NPP decantate treatment realized at Kola NPP

    International Nuclear Information System (INIS)

    Stakhiv, Michael; Avezniyazov, Slava; Savkin, Alexander; Fedorov, Denis; Dmitriev, Sergei; Kornev, Vladimir

    2007-01-01

    At Moscow SIA 'Radon' jointly with JSC 'Alliance Gamma', the technology for NPP Decantate Treatment was developed, tested and realized at Kola NPP. This technology consists of dissolving the salt residue and subsequent treatment by ozonization, separation of the deposits formed from ozonization and selective cleaning by ferro-cyanide sorbents. The nonactive salt solution goes to an industrial waste disposal site or a repository specially developed at NPP sites for 'exempt waste' products by IAEA classification. This technology was realized at Kola NPP in December 2006 year. At this time more than 1000 m 3 of decantates log time stored are treated. It allows solving very old problem to empty decantates' tanks at NPPs in environmentally safe manner and with high volume reduction factor. (authors)

  18. Marketingový mix firmy ALU KOLA CB

    OpenAIRE

    URBAN, Karel

    2011-01-01

    This bachelor thesis is focused on a marketing mix practical application in my own company ALU KOLA CB. My company sells alloy wheels and tyres for personal cars. In a literary review are introduced and explained terms marketing, marketing mix and its parts - product, price, place and promotion. In a practical part of this thesis are these terms applied on my company. The end of this part contains results and improvement suggestions.

  19. The status of nuclear cooperation with Kola and Leningrad nuclear power plant; Status for atomsikkerhetssamarbeidet med Kola og Leningrad kjernekraftverk

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-11-01

    Norway has since 1993 participated in joint projects with Russia to improve nuclear safety at the Kola and Leningrad nuclear power plant. The project have been funded under the Government's nuclear action under the leadership of the Ministry of Foreign Affairs. Institute for Energy Technology (IFE) has completed most of the projects. NRPA is the authority responsible for assessing the implementation of the projects. (eb)

  20. Evaluation of Kola-Pod Husk Meal in Broiler Finisher Diets ...

    African Journals Online (AJOL)

    Nigeria is the world's largest producer of kola nut. The pod husk, which constitutes over 50% of the kola fruit, has been a farm waste to date. Its crude protein content which is similar to that of maize suggests that it is possible to partially replace maize with pod husk meal (KPHM) in broiler finisher diets. In this study, KPHM ...

  1. Effect of hormone on the seed germination of Garcinia kola Heckel ...

    African Journals Online (AJOL)

    Effect of hormone on the seed germination of Garcinia kola Heckel. FB Yakubu, JO Ogunade, OT Bolanle-Ojo, DK Yahaya. Abstract. Garcinia kola plays an important socioeconomic role in the Africa culture. Inspite of this, the plant only exists in the wild or as part of left over in the Agroforestry farms. Therefore, this research ...

  2. Fennoscandia in the Phanerozoic: Paleogeodynamic Reconstructions Based on the New Paleomagnetic and Geochronological Data from the Kola Magmatic Province (kola Peninsula, Russia)

    Science.gov (United States)

    Veselovskiy, R. V.; Arzamastsev, A. A.

    2013-12-01

    During last four years we studied more than 100 dolerite and alkaline dykes, which are widely spread on the Kola Peninsula and belong to the Devonian magmatic province. Within the scope of our researches some of these dykes have been dated and their precise isotopic ages (Ar/Ar, Sm-Nd, Rb-Sr) lie in the range of 390-360 Ma (Veselovskiy et al., 2013). The age of other sampled dykes can be considered as Devonian due to similarity of their paleomagnetic, geochemical and petrological characteristics to the dated ones. Paleomagnetic directions have been obtained from more than 80 dykes. Almost all dykes yielded (a) a low-temperature component that is aligned along the present-day field and is likely of viscous origin; (b) a well defined dual-polarity intermediate-temperature component with steep eastward directions that accounts for a main part of the NRM and often decays to the origin on orthogonal plots; and (c) a dual-polarity high-temperature component with shallow inclinations and ENE declinations of presumed primary origin. The presence of the primary high-temperature component makes us possible to calculate preliminary Baltica's paleomagnetic pole for the Middle-Late Devonian. In view of the obtained microprobe data we believe that intermediate component is a result of unknown hydrothermal process, which age can be estimated from the comparison of corresponding paleomagnetic pole with the Baltica's APWP as Jurassic. We believe that both mentioned episodes of endogenous activity within the large stable craton were connected with plume-lithospheric interaction in the Devonian and Jurassic. In this presentation we use the obtained paleomagnetic, petrological and geochronological data to determine the paleogeography of Baltica in the Devonian and Jurassic times and to find its position within the global paleotectonic and geodynamic reconstructions. This study was funded by grants RFBR # 12-05-00216, 13-05-12021, 13-05-12030 and grant MK-3383.2012.5.

  3. Geology of the plutonic basement rocks of Stewart Island, New Zealand

    International Nuclear Information System (INIS)

    Allibone, A.H.; Tulloch, A.J.

    2004-01-01

    Exposures of basement rocks on Stewart Island provide a c. 70 km long by 50 km wide map of part of the Median Batholith that spans the margin of the Western Province. Because of their distance from the present plate boundary, these rocks are relatively unaffected by Cenozoic tectonism, allowing examination of unmodified Carboniferous-Cretaceous relationships within the Median Batholith. Thirty individual plutons (>c.20 km 2 ) have been mapped along with numerous relatively small intrusions ( 2 ). The large plutons form 85-90% of the Median Batholith on Stewart Island while the many smaller intrusions comprise 10-15%, mostly in the north. Lithologies include: biotite ± minor hornblende granodiorite, granite and leucogranite with accessory titanite - magmatic epidote and allanite (c. 50%); biotite ± muscovite ± garnet granite with S-type affinities (c. 10%); alkaline quartz monzonite, granite, and alkali feldspar granite with rare aegirine and blue-green amphibole (c. 3%); quartz monzodiorite and diorite with hornblende > biotite (c. 23%); gabbro and anorthosite (c. 12%) and ultramafic rocks (c. 2%). U-Pb zircon and monazite dating indicates that c. 12% of these plutonic rocks were emplaced during the Carboniferous between 345 and 290 Ma, c. 20% in the Early-Middle Jurassic at c. 170-165 Ma, c. 30% in the latest Jurassic to earliest Cretaceous between 152 and 128 Ma, and c. 38% in the Early Cretaceous between 128 and 100 Ma. The distribution of Pegasus Group schists and peraluminous granitoid rocks indicates that the northern limit of extensive early Paleozoic Western Province basement is located either within the Gutter Shear Zone or at the Escarpment Fault, 10-15 km south of the Freshwater Fault System previously thought to mark this boundary. Carboniferous and Middle Jurassic magmatism extended plutonic basement northwards as far as the Freshwater Fault System, while further magmatism during the latest Jurassic and earliest Cretaceous produced the basement

  4. Genesis of felsic plutonic magmas and their igneous enclaves

    DEFF Research Database (Denmark)

    Clemens, John D.; Maas, Roland; Waight, Tod Earle

    2016-01-01

    -type Pyalong pluton was emplaced, apparently along an east-west-orientated fracture zone. Around 367 Ma, the main I-type Baynton pluton intruded as numerous shallow-dipping sheets. The last plutonic event was the intrusion of the broad, thin, flat-lying, and crosscutting sheet of the I-type Beauvallet pluton...... the relatively high abundance of igneous-textured microgranular enclaves (MEs). The MEs show neither chemical nor isotope mixing trends with each other or with the host magmas. Variations in the Baynton magmas were derived from the heterogeneity of the source terrane, with individual magma batches formed from...

  5. U-Pb ages and Hf isotope compositions of zircons in plutonic rocks from the central Famatinian arc, Argentina

    Science.gov (United States)

    Otamendi, Juan E.; Ducea, Mihai N.; Cristofolini, Eber A.; Tibaldi, Alina M.; Camilletti, Giuliano C.; Bergantz, George W.

    2017-07-01

    The Famatinian arc formed around the South Iapetus rim during the Ordovician, when oceanic lithosphere subducted beneath the West Gondwana margin. We present combined in situ U-Th-Pb and Lu-Hf isotope analyses for zircon to gain insights into the origin and evolution of Famatinian magmatism. Zircon crystals sampled from four intermediate and silicic plutonic rocks confirm previous observations showing that voluminous magmatism took place during a relatively short pulse between the Early and Middle Ordovician (472-465 Ma). The entire zircon population for the four plutonic rocks yields coherent εHf negative values and spreads over several ranges of initial εHf(t) units (-0.3 to -8.0). The range of εHf units in detrital zircons of Famatinian metasedimentary rocks reflects a prolonged history of the cratonic sources during the Proterozoic to the earliest Phanerozoic. Typical tonalites and granodiorites that contain zircons with evolved Hf isotopic compositions formed upon incorporating (meta)sedimentary materials into calc-alkaline metaluminous magmas. The evolved Hf isotope ratios of zircons in the subduction related plutonic rocks strongly reflect the Hf isotopic character of the metasedimentary contaminant, even though the linked differentiation and growth of the Famatinian arc crust was driven by ascending and evolving mantle magmas. Geochronology and Hf isotope systematics in plutonic zircons allow us understanding the petrogenesis of igneous series and the provenance of magma sources. However, these data could be inadequate for computing model ages and supporting models of crustal evolution.

  6. The Precambrian/Lower Cambrian pluton from Vila Nova (Central Portugal)

    Energy Technology Data Exchange (ETDEWEB)

    Reis, A. I. M.; Silva, M. M. V. G.; Antunes, I. M. H. R.

    2010-07-01

    The Vila Nova pluton is a small, Pre-Variscan granitic body that intruded rocks of the Central Iberian Zone near the contact with the Ossa Morena Zone and is affected by several shear zones and faults. Its contact metamorphic aureole is constituted by micaschist with porphyroblasts in the outer zone and hornfels in the inner zone. Small mainstreamed xenoliths are dispersed all over the body. The pluton has a great mineralogical heterogeneity with pronounced variations in muscovite/biotite and plagioclase/ microcline contents and is classified as granite, granodiorite or tonalite. It is a leuco granite, highly peraluminous (A/CN K = 1.31 - 1.64), magnesian and calc-alkaline to alkaline-calcic. The variation diagrams show curvilinear trends with silica. Eu/Eu* = 0.47 - 0.77 and there is a slight enrichment in LREE relative to HREE. The normalized diagrams indicated dominantly crustal granite, related to subduction. U-Pb isotopic data of zircon and monazite gives 540-542 Ma age. (Author) 19 refs.

  7. Petrological studies of plutonic rocks of Ecuador

    International Nuclear Information System (INIS)

    Aly, S.

    1980-01-01

    The feldspars of many tonalitic plutonic rocks in the coastal regions and West Andean regions are zoned. This leads to the conclusion that they are relatively flat intrusions and to some extent transition rocks in the subvulcanite direction. This is in accordance with the genetic and chronological relationship between plutonites and the surrounding vulcanites of the Basic Igreous Complex (BIC). The composition of representative minerals, e.g. alkali feldspar, plagioclase feldspar, biotite, chlorite, and amphibole has been determined as well as the age of plutonite samples by the K/Ar dating method. (DG) [de

  8. Discussion on geochemical characteristics and tectonic setting of Maofeng pluton

    International Nuclear Information System (INIS)

    Wu Yi; Ruan Kun; Cai Jiajia; Liu Jing; Li Haidong; Zhang Lu; Wang Xiaona

    2014-01-01

    Xiazhuang granite type uranium deposit is the most important one in South China. The closest relation with Xiazhuang uranium mineralization is Maofeng granite pluton. To expound the relationship of granite and uranium mineralization, the paper studied Maofeng granite pluton which is the host granite of the deposit in petrogeochemistry, its structure and geodynamic setting. (authors)

  9. Effects of Aqueous Extract of Kola Nut (Cola Nitida Rubra) on ...

    African Journals Online (AJOL)

    Chigo Okwuosa

    This study evaluates the effects of kola nut extract on plasma level of ... combination with other drugs (Rall, 1980). Caffeine and some of its ... combination of coffee drinking with smoking ... effects on reproductive functions using male rats.

  10. MEASUREMENTS OF THE CONFINEMENT LEAKTIGHTNESS AT THE KOLA NUCLEAR POWER STATION (UNIT 2) IN RUSSIA

    International Nuclear Information System (INIS)

    GREENE, G.A.; GUPPY, J.G.

    1998-01-01

    This is the final report on the INSP project entitled, ''Kola Confinement Leaktightness'' conducted by BNL under the authorization of Project Work Plan WBS 1.2.2.1. This project was initiated in February 1993 to assist the Russians to reduce risks associated with the continued operation of older Soviet-designed nuclear power plants, specifically the Kola VVER-440/230 Units 1 and 2, through upgrades in the confinement performance to reduce the uncontrolled leakage rate. The major technical objective of this-project was to improve the leaktightness of the Kola NPP VVER confinement boundaries, through the application of a variety of sealants to penetrations, doors and hatches, seams and surfaces, to the extent that current technology permitted. A related objective was the transfer, through training of Russian staff, of the materials application procedures to the staff of the Kola NPP. This project was part of an overall approach to minimizing uncontrolled releases from the Kola NPP VVER440/230s in the event of a serious accident, and to thereby significantly mitigate the consequences of such an accident. The US provided materials, application technology, and applications equipment for application of sealant materials, surface coatings, potting materials and gaskets, to improve the confinement leaktightness of the Kola VVER-440/23Os. The US provided for training of Russian personnel in the applications technology

  11. Prevalence and associated risk factors of Kola nut chewing among secondary school students in Osogbo, Nigeria.

    Science.gov (United States)

    Erinfolami, Adebayo; Eegunranti, Adekunle; Ogunsemi, Olawale; Oguntuase, Akin; Akinbode, Abiola; Erinfolami, Gloria

    2011-02-22

    The objectives of this study were to determine the prevalence and pattern of Kola nut use among secondary school students in Osogbo, Osun State, Nigeria. The study also aimed to determine the association of socio-demographic variables (of the students and their parents) with kola nut chewing. A questionnaire consisting of socio-demographic variables, the stimulant use section of the WHO Students Drug Use Questionnaire was administered on three hundred and eighty-five (385) randomly selected students of the two Local Government Areas of Osogbo. The prevalence rate of kola nut use was calculated and some socio demographic variables were determined. The 30-day prevalence rate of kola nut use was 11.2%. The one-year prevalence of kola nut use was 29.1 percent and the lifetime rate was 74.8 percent. Majority of users started at age 14 years or below. Kola nut use was associated with lower age group, poor school attendance, polygamous background, low education of mother, high education of father and the description of mother as being too permissive. The findings suggest the need to increase the awareness of the dangers of kolanut use among adolescents. Control program are urgently needed to prevent student wastage.

  12. Prevalence and associated risk factors of Kola nut chewing among secondary school students in Osogbo, Nigeria

    Directory of Open Access Journals (Sweden)

    Gloria Erinfolami

    2011-02-01

    Full Text Available The objectives of this study were to determine the prevalence and pattern of Kola nut use among secondary school students in Osogbo, Osun State, Nigeria. The study also aimed to determine the association of sociodemographic variables (of the students and their parents with kola nut chewing. A questionnaire consisting of socio-demographic variables, the stimulant use section of the WHO Students Drug Use Questionnaire was administered on three hundred and eighty-five (385 randomly selected students of the two Local Government Areas of Osogbo. The prevalence rate of kola nut use was calculated and some socio demographic variables were determined. The 30-day prevalence rate of kola nut use was 11.2%. The one-year prevalence of kola nut use was 29.1 percent and the lifetime rate was 74.8 percent. Majority of users started at age 14 years or below. Kola nut use was associated with lower age group, poor school attendance, polygamous background, low education of mother, high education of father and the description of mother as being too permissive. The findings suggest the need to increase the awareness of the dangers of kolanut use among adolescents. Control program are urgently needed to prevent student wastage.

  13. MEASUREMENTS OF THE CONFINEMENT LEAKTIGHTNESS AT THE KOLA NUCLEAR POWER STATION (UNIT 2) IN RUSSIA

    Energy Technology Data Exchange (ETDEWEB)

    GREENE,G.A.; GUPPY,J.G.

    1998-08-01

    This is the final report on the INSP project entitled, ``Kola Confinement Leaktightness'' conducted by BNL under the authorization of Project Work Plan WBS 1.2.2.1. This project was initiated in February 1993 to assist the Russians to reduce risks associated with the continued operation of older Soviet-designed nuclear power plants, specifically the Kola VVER-440/230 Units 1 and 2, through upgrades in the confinement performance to reduce the uncontrolled leakage rate. The major technical objective of this-project was to improve the leaktightness of the Kola NPP VVER confinement boundaries, through the application of a variety of sealants to penetrations, doors and hatches, seams and surfaces, to the extent that current technology permitted. A related objective was the transfer, through training of Russian staff, of the materials application procedures to the staff of the Kola NPP. This project was part of an overall approach to minimizing uncontrolled releases from the Kola NPP VVER440/230s in the event of a serious accident, and to thereby significantly mitigate the consequences of such an accident. The US provided materials, application technology, and applications equipment for application of sealant materials, surface coatings, potting materials and gaskets, to improve the confinement leaktightness of the Kola VVER-440/23Os. The US provided for training of Russian personnel in the applications technology.

  14. Cooling history of nested plutons from the Variscan Tichka plutonic complex (Morocco)

    Science.gov (United States)

    Lécuyer, Christophe; Gasquet, Dominique; Allemand, Pascal; Martineau, François; Martinez, Isabelle

    2017-03-01

    Four imbricated mafic to felsic plutons of Variscan age from Morocco have been investigated for their cooling history and geochemical interactions with surrounding continental rocks. Oxygen isotope compositions of whole rocks and minerals have been used to model the cooling rates of these kilometer-sized intrusions. By combining both the knowledge of oxygen-self diffusion data of rock-forming minerals and the determination by IR-spectroscopy of the water content of quartz, the cooling times are estimated ranging from 105 to 5 × 105 years in agreement with the shallow emplacement (4-6 km depth) of these intrusions into the continental crust. Such fast cooling rates could explain why after assimilation of the various country rocks, heterogeneities of both neodymium and strontium isotope ratios were still preserved. A progressive δ18O increase from the mafic to felsic terms of the plutonic suite, which does not excess 1 to 1.5‰, could be explained by the assimilation of metamorphosed pelitic and volcanic rocks that constitute the basement of the Tichka plutonic complex.

  15. Petrology of Terra Nova pluton, Brazil, and associated ultrapotassic dykes

    International Nuclear Information System (INIS)

    Silva Filho, A.F. da; Thompson, R.N.; Leat, P.T.

    1987-01-01

    The Upper Precambrian Terra Nova Pluton, situated 550 Km inland from Recife, Brazil, is 220 Km 2 in area and intrudes deformed metasedimentary rocks of the Pianco-Alto Brigida Mobile Belt. The Pluton shows complex petrological relationships. It consists of subalkaline quartz-monzonites and quartz-syenites, and the major minerals are K-feldspars, albite, hornblende, and quartz. The pluton is intermediate in composition (SiO 2 = 58.9-65.6 wt%, MgO=0.9-3.7 wt%) and is dominantly potassic (K 2 O=3.3-5.6 wt %; K 2 O/Na 2 O=0.9-1.8). Ba (up to 2.300 ppm) and Sr (up to 1,100 ppm) are abundant in the rocks, and LREE are enriched relative to HREE (La N /Lu N = 25.6-43.2). There is no significant Eu Anomaly. Rounded autoliths within the pluton are similar, but more mafic in composition (SiO 2 =54.6-57.5 wt %; MgO=4.9-6.4 wt %). A suite of dykes cut pluton and the surrounding country rocks. These dykes are varied in composition, encompassing most of the chemical range shown by the pluton and associated autoliths. The dykes are holocrystalline, peralkaline, and strongly enriched in both K 2 O(K 2 O=5.3-11.4 wt %) and Ba (Ba=2,400 ppm-10,500 ppm), which are considered to be magmatic abundances. The dykes have similar REE and other trace elements and ratios to the autoliths and plutonic rocks, and the dykes and the pluton are thought to be chemically related. The Terra Nova Pluton records the fractionation of mantle-derived ultrapotassic magma from mafic to intermediate compositions. (author) [pt

  16. From steep feeders to tabular plutons - Emplacement controls of syntectonic granitoid plutons in the Damara Belt, Namibia

    Science.gov (United States)

    Hall, Duncan; Kisters, Alexander

    2016-01-01

    Granitoid plutons in the deeply eroded south Central Zone of the Damara Belt in Namibia commonly show tabular geometries and pronounced stratigraphic controls on their emplacement. Subhorizontal, sheet-like pluton geometries record emplacement during regional subhorizontal shortening, but the intrusion of spatially and temporally closely-related granitoid plutons at different structural levels and in distinct structural settings suggests independent controls on their levels of emplacement. We describe and evaluate the controls on the loci of the dyke-to-sill transition that initiated the emplacement of three syntectonic (560-530 Ma) plutons in the basement-cover stratigraphy of the Erongo region. Intrusive relationships highlight the significance of (1) rigidity anisotropies associated with competent sedimentary packages or pre-existing subhorizontal granite sheets and (2) rheological anisotropies associated with the presence of thick ductile marble horizons. These mechanical anisotropies may lead to the initial deflection of steep feeder conduits as well as subsequent pluton assembly by the repeated underaccretion of later magma batches. The upward displacement of regional isotherms due to the heat advection associated with granite emplacement is likely to have a profound effect on the mechanical stratification of the upper crust and, consequently, on the level at which granitoid pluton emplacement is initiated. In this way, pluton emplacement at progressively shallower crustal depths may have resulted in the unusually high apparent geothermal gradients recorded in the upper crustal levels of the Damara Belt during its later evolution.

  17. The chemical and isotopic differentiation of an epizonal magma body: Organ Needle pluton, New Mexico

    Science.gov (United States)

    Verplanck, P.L.; Farmer, G.L.; McCurry, M.; Mertzman, S.A.

    1999-01-01

    Major and trace element, and Nd and Sr isotopic compositions of whole rocks and mineral separates from the Oligocene, alkaline Organ Needle pluton (ONP), southern New Mexico, constrain models for the differentiation of the magma body parental to this compositionally zoned and layered epizonal intrusive body. The data reveal that the pluton is rimmed by lower ??(Nd) (~-5) and higher 87Sr/86Sr (~0.7085) syenitic rocks than those in its interior (??(Nd) ~ 2, 87Sr/86Sr ~0.7060) and that the bulk compositions of the marginal rocks become more felsic with decreasing structural depth. At the deepest exposed levels of the pluton, the ??(Nd)~-5 lithology is a compositionally heterogeneous inequigranular syenite. Modal, compositional and isotopic data from separates of rare earth element (REE)-bearing major and accesory mineral phases (hornblende, titanite, apatite, zircon) demonstrate that this decoupling of trace and major elements in the inequigranular syenite results from accumulation of light REE (LREE)-bearing minerals that were evidently separated from silicic magmas as the latter rose along the sides of the magma chamber. Chemical and isotopic data for microgranular mafic enclaves, as well as for restite xenoliths of Precambrian granite wall rock, indicate that the isotopic distinction between the marginal and interior facies of the ONP probably reflects assimilation of the wall rock by ??(Nd) ~-2 mafic magmas near the base of the magma system. Fractional crystallization and crystal liquid separation of the crystally contaminated magma at the base and along the margins of the chamber generated the highly silicic magmas that ultimately pooled at the chamber top.

  18. Multiscale magmatic cyclicity, duration of pluton construction, and the paradoxical relationship between tectonism and plutonism in continental arcs

    Science.gov (United States)

    de Saint Blanquat, Michel; Horsman, Eric; Habert, Guillaume; Morgan, Sven; Vanderhaeghe, Olivier; Law, Richard; Tikoff, Basil

    2011-03-01

    The close relationship between crustal magmatism, an expression of heat dissipation, and tectonics, an expression of stress dissipation, leads to the question of their mutual relationships. Indeed, the low viscosity of magmas and the large viscosity contrast between magmas and surrounding rocks favor strain localization in magmas, and then possible "magmatic" initiation of structures at a wide range of scales. However, new data about 3-d pluton shape and duration of pluton construction perturb this simple geological image, and indicate some independence between magmatism and tectonics. In some cases we observe a direct genetic link and strong arguments for physical interactions between magmas and tectonics. In other cases, we observe an absence of these interactions and it is unclear how magma transfer and emplacement are related to lithospheric-plate dynamics. A simple explanation of this complexity follows directly from the pulsed, incremental assembly of plutons and its spatial and temporal characteristics. The size of each pluton is related to a magmatic pulsation at a particular time scale, and each of these coupled time/space scales is related to a specific process: in small plutons, we can observe the incremental process, the building block of plutons; in larger plutons, the incremental process is lost, and the pulsation, which consists of a cycle of injections at different timescales, must be related to the composition and thermal regime of the source region, itself driving magmatic processes (melting, segregation, and transfer) that interact with tectonic boundary conditions. The dynamics of pulsed magmatism observed in plutonic systems is then a proxy for deep lithospheric and magmatic processes. From our data and a review of published work, we find a positive corelation between volume and duration of pluton construction. The larger a pluton, the longer its construction time. Large/fast or small/slow plutons have not been identified to date. One

  19. Geochemistry and meaning of the geotectonic position of plutonic rocks from Chapada region, Goias, Brazil

    International Nuclear Information System (INIS)

    Kuyumjian, R.M.

    1989-01-01

    In common with other orogenic belts, in which the presence of both, granitic and small basic-ultrabasic intrusions are characteristics of medium-high pressure metamorphic terranes, the geological and geochemical evidences indicate a close relationship between the granitoid, gabbroic and pyroxenitic plutons and the orogenic metabasaltic rocks from the Chapada volcano-sedimentary sequence. The granitoids are tonalitic and, on discriminant diagrams, they plot in the volcanic arc and pre-collisional fields. They display geochemical characteristics similar to the Jamaican oceanic arc-related granities. They show low LIL and HSF element abundances, low (Ta, Nb)/(K, La, etc) ratios and very low concentrations of Th, Hf, K and Y, when compared to patterns of calkaline, alkali-calcic and alkaline-peralkaline granitoids of magmatic arcs. These chemical features are characteristic of immature island arcs mantle-derived intrusives. The Chapada olivine gabbro has a chondrite-normalized spidergram, closely resembling those of island-arc basaltic lavas, the compositions of its coexisting olivine and plagioclase been similar to those from arc-related cumulate gabbros, and therefore, it could be the plutonic equivalent of the arc volcanics in the Chapada region. It is suggested that the evolution of the granitoids and gabbro intrusives from Chapada are related to a process of subduction that occurred in central Brazil during the Brasiliano/Pan-African event. (author) [pt

  20. Isotopic-geochemical investigation of Vitosh pluton (Bulgaria)

    International Nuclear Information System (INIS)

    Amelin, Yu.V.; Drubetskoj, E.R.; Monchev, N.B.; Nejmark, L.A.; Ovchinnikova, G.V.; Levskij, L.K.

    1989-01-01

    A set of isotope-geochronological (Rb-Sr, K-Ar, uranium fission tracks) and isotope-geochemical (Sr, Pb, Nd, He) methods was used to establish genesis and age of multi-phase Vitosh pluton. The investigation results have shown that primary magma from which pluton rocks were formed is generated at the level of high mantle - low crust. Insignificant difference in time of implantation and crystallization between variuos pluton phases is established. In the interval 84-79 millions of years the velocity of rock cooling and the velocity of pluton lift to the surface were estimated. In the interval 79-0 millions of years these velocities decrease essentially. After formation the rocks were not subjected to additional heat affects

  1. Orogenic potassic mafic magmatism, a product of alkaline-peraluminous mixing ? Variscan 'calc-alkaline' rocks from the Central Iberian and Ossa Morena Zones, Central Spain.

    Science.gov (United States)

    Scarrow, Jane H.; Cambeses, Aitor; Bea, Fernando; Montero, Pilar; Molina, José F.; Moreno, Juan Antonio

    2013-04-01

    Orogenic magmatic rocks provide information about mantle and crust melt-generation and -interaction processes. In this context, minor potassic mafic stocks which are formed of enriched mantle and crustal components and are common as late-orogenic intrusions in granitic plutons give insight into the timing of new crust formation and crustal recycling. Potassic mafic stocks are prevalent, albeit low volume, constituents of granite batholiths all through the European Variscan (350-280 Ma). In the Central Iberia Zone, Spanish Central System, crustal-melt, S-type, granitoid plutons are intruded by minor concomitant ultramafic-intermediate appinitic-vaugneritic stocks. Notwithstanding their whole-rock calc-alkaline composition, the stocks apparently did not have a subduction-related origin. Recent studies have attributed their genesis to mixing of alkaline mantle and peraluminous crustal melts. Their primary alkaline character, as indicated by amphibole and biotite mineral chemistry data, points, rather, towards an extension-related genesis. In the Ossa Morena Zone, south of the Central Iberian Zone, the igneous rocks also have a whole-rock calc-alkaline composition which has been considered to be the result of northward subduction of the South Portuguese Zone. Nevertheless, identification of a 'sill' of significant volume of mafic magma in the middle crust, the ´IBERSEIS reflective body', in a seismic profile across the Ossa Morena and South Portuguese Zones has cast doubt upon the calc-alkaline magmatism-subduction model; leading, instead, to the magmatism being attributed to intra-orogenic extension related to a mantle plume active from 340 Ma to 330 Ma. The aim here, then, is to reinvestigate the petrogenesis and age of the calc-alkaline rocks of the Ossa Morena Zone to determine their tectonomagmatic context be it subduction-, plume- or extension-related, and establish what they may reveal about mantle-crust interactions. Focussing, initially, on the Valencia del

  2. K/Ar age dating of Oshnaviyeh plutonic complex

    International Nuclear Information System (INIS)

    Ghalamghash, J.; Vosoughi Abedini, M.; Bellon, H.; Emami, M.H.; Pourmafi, M.; Rashid, H.

    2003-01-01

    Oshnaviyeh plutonic complex, the western member of Urumiyeh-Golpayehgan intrusive plutons is located in northern part of Sanandaj-Sirjan zon. Oshnaviyeh plutonic complex, exposing in an area of about 700 km 2 , comprises 10 plutons that can be divided into three suites, i.e.,diorite,granite,and alkali syenite-alkali granite. Dioritic bodies are the oldest intrusive rocks of the region, which on the basis of the field study, their relative age of emplacement is estimated to be post-Jurassic and pre-miocene. However, with respect to the age of other similar intrusive bodies in Naghadeh area, they are most likely of post early cretaceous-pre miocene age. Hybrid intrusive rocks, occurring at the contact of dioritic and granitic rocks may suggest a simultaneous emplacement of both magmas. Syntetic pluton from alkali syenite-alkali granite has intruded dioritic and granitic rocks, in contrast, flourine bearing alkali granite pluton from this suite shows no contact with other igneous rocks in the area. K-Ar age determinations obtained on amphibole specimens from diorite suite are 91.9±2.3, 94.1±2.3 and 100±2.4 Ma, and on biotite specimens from granite suite are 100±1.5 to 98.9±1.5 Ma. Chronology study using same method on arfvedsonite specimens from syenite pluton shows 78.9±3.1, 79.6±1.9 and 81.7±2.0 Ma and on K-fled par samples of flourine bearing alkali granite pluton from the alkali syenite-alkali granite suite presents 76±3.4 and 77.1±1.8. Therefore, based on field evidence and K/Ar age dating, Oshnaviyeh plutonic complex presumably formed during two episodes: granite and diorite suites formed simultaneously at about 100 Ma, then plutons of alkali syenite-alkali granite suite emplaced at about 80 Ma

  3. Digital relief 3D model of the Khibiny massive (Kola peninsula)

    Science.gov (United States)

    Chesalova, Elena; Asavin, Alex

    2015-04-01

    On the basis of maps of 1: 50,000 and 1: 200,000 3D model Khibiny massif developed. We used software ARC / INFO v10.2 ESRI. This project will be organised to build background for gas pollution monitoring network. We planned to use the model to estimate local heterogeneities in the composition of the atmosphere at the emanation of greenhouse gases in the area, the construction of models of vertical distribution of the content of trace gases in the rock mass. In addition to the project GIS digital elevation model contains layers of geological and tectonic map that allows us to estimate the area of the output of certain petrographic rock groups characterized by different ratios of emitted hydrocarbons (CH4/ H2). The model allows to construct a classification of fault in the array. At first glance, there are two groups of faults - the ancient associated with the formation of the intrusive phases sequence, and the young - due to recent tectonic shifts. Ancient faults form a common semicircular structure of the pluton cause overall asymmetry Khibin heights with the transition to the border area between the Khibiny and Lovoozero. Modern tectonics mainly represented by radial and chord faults which are formed narrow mountain valleys and troughs. It remains an open question as to which system fault (old or young) is more productive to gas emanations? On the one hand the system characterized by a large old depth, on the other hand a young more active faults. Address these issues require further detailed observations. The essential question is to assess the possibility of maintaining a constant concentration gradient of these impurities in the atmosphere due to gas emanations of fracture zones and areas enriched occluded gases. In the simulation of these processes can be used initially set parameters: 1 the flow rate of the gas impurities 2 the value of wind flows in closed and open valley 3 Assessment of thermal diffusion coefficients determined by the temperature gradient

  4. Hydrothermal convection and uranium deposits in abnormally radioactive plutons

    International Nuclear Information System (INIS)

    1978-09-01

    Hydrothermal uranium deposits are often closely associated with granites of abnormally high uranium content. We have studied the question whether the heat generated within such granites can cause fluid convection of sufficient magnitude to develop hydrothermal uranium deposits. Numerical models of flow through porous media were used to calculate temperatures and fluid flow in and around plutons similar to the Conway Granite, New Hampshire, i.e. with a halfwidth of 17 km, a thickness of 6.25 km, and with a uniform internal heat generation rate of 20 x 10 -13 cal/cm 3 -sec. Fluid convection was computed for plutons with permeabilities between 0.01 and 5 millidarcies (1 x10 -13 cm 2 to 5 x 10 -11 cm 2 . Flow rates and the size and location of convection cells in and around radioactive plutons like the Conway Granite were found to depend critically on the permeability distribution within the pluton and in adjacent country rocks. The depth of burial, the distribution of heat sources within the pluton, and small rates of heat generation in the country rock are only of minor importance. Topographic relief is unlikely to effect flow rates significantly, but can have a major influence on the distribution of recharge and discharge areas. Within a few million years, the mass of water transported by steady state convection through such radioactive plutons can equal the mass of water which can convect through them during initial cooling from magmatic temperatures. If the permeability in a Conway-type pluton is on the order of 0.5 millidarcies, the rate of fluid convection is probably sufficient to develop a hydrothermal ore deposit containing 10,000 tons of uranium in a period of two million years. Such a uranium deposit is most likely to develop in an area of strong upwelling or strong downwelling flow

  5. Geochemistry and petrogenesis of the Dehe Bala calc-alkaline granodiorites, south west of Boein Zahra

    Directory of Open Access Journals (Sweden)

    Zeynab Gharamohammadi

    2016-09-01

    Full Text Available The Dehe Bala pluton is exposed approximately 45 km south-west of Boein Zahra town, Qazvin province. This Pluton which intruded the Eocene volcano-sedimentary rocks of the Urumieh-Dokhtar Magmatic assemblage (UDMA, is mainly composed of granodiorite and produced narrow thermal metamorphic contact aureoles surrounding the intrusion. The body is characterized by SiO2 content ranging from 64.2 to 66.9 wt%, high-k calc-alkaline nature and metaluminous character (A/CNK

  6. The reliability improvement plan of hot cell examination data by introducing of Kolas

    International Nuclear Information System (INIS)

    Hong, Kwon Pyo; Park, Dae Gyu; Ahn, Sang Bok; Choo, Yong Sun; Song, Wung Sup; Jung, Yang Hong; Yoo, Byung Ok; Baik, Seung Je; Lim, Nam Jin; Nam Ju Hee

    2000-01-01

    For enhancement of hot cell data reliability produced at Irradiated Material Examination Facility in KAERI,Korea a project to introduce Kolas of National Quality Assurance Institute. By Kolas introduction the examination data currently produced would be reinforced by additional function of uncertainty evaluation and would obtained more reliable data. The all of data collected would be quality controlled, so that it would be re-traceable. Presently at IMEF shock test, tension test, dimension measurement test, hardness test, density test, and composition analysis test will be subject to Kolas. It is also planned to expand the number of test items in near future. At the end of 2000 year IMEF aims to secure the certificate issued by the National Quality Assurance Institute. (Hong, J. S.)

  7. Is spent nuclear fuel at the Kola coast a real danger?

    International Nuclear Information System (INIS)

    Gussgard, K.

    1995-01-01

    Norwegian authorities regard with some disquiet the possibility of a criticality accident in a ship propulsion reactor core at the Kola coast. Along this coast, in land storages, floating storages and in submarines taken out of service, the total number of spent fuel reactor cores amount to two hundred. The total Cs-137 radioactivity in spent ship propulsion reactor fuel at the Kola peninsula can be assessed to 600,000 TBq. A worst case release may amount to more than 5,000 TBq Cs-137, a quantity which under unfavourable conditions might cause serious contamination locally and even across the border to Norway

  8. Feasibility study on introduction of KOLAS (Korea Laboratory Accreditation Scheme) in nuclear examination facility

    International Nuclear Information System (INIS)

    Park, Dae Gyu; Hong, K. P.; Song, W. S.; Min, D. K.

    1999-07-01

    To be an institute officially authorized by the KOLAS, the understanding and the analysis of following contents is required.: the understanding of concept required to get the accreditation of testing, the system specifying an internationally accredited testing and examination organization, international organization in the field of laboratory accreditation, domestic laboratory accreditation organization(KOLAS), the investigation of the regulations with laboratory accreditation in Korea, the investigation of the procedures accrediting a testing and examination organization, the investigation of general requirements(ISO 17025) for a testing and examination organization. (author)

  9. The Effects of Bitter Kola Supplemented Diet on Hepatotoxicity of ...

    African Journals Online (AJOL)

    MICHAEL

    supplemented rat chow and mercury contaminated water, group V animals were ... hepatotoxic effects of the heavy metal indirectly assessed by measurement of the serum levels of alkaline .... III vs V: Group IV vs V.P-values less than 0.05.

  10. Physico-Chemical conditions of four calc-alkaline granitoid plutons ...

    Indian Academy of Sciences (India)

    63

    Centre), Indian Institute of Technology, Roorkee. An accelerating .... microcline which pinch out into more mafic matrix several millimeters from both ends of ..... In low oxygen fugacity, on the contrary, the introduction of Fe2+ is favoured in.

  11. Analgesic and anti-inflammatory effects of kaviiron (a Garcinia kola ...

    African Journals Online (AJOL)

    Kolaviron is a defatted ethanol extract from the seeds of Garcinia Kola. In the present study, the analgesic and anti-inflammatory properties of Kolaviron is investigated using both thermal and chemical models of pain assessment in mice and rats. Varying doses of Kolaviron were given 30 minutes prior to the induction of ...

  12. Effect of Combined Intake of Garcinia Kola and Ascorbic Acid on ...

    African Journals Online (AJOL)

    This study was carried out to determine the effect of combined intake of Garcinia kola and Ascorbic acid on Intraocular pressure (IOP) of normotensive Nigerians. A total of one hundred and sixty (n= 160) parcipants, males, and females within the age range of 18-50 years (Mean age = 29.29± 8.74) were used for this study.

  13. Effects of Caffeine from Different Kola Nut Extracts on Kidney and ...

    African Journals Online (AJOL)

    The effect of caffeine from different kola nut extracts on kidney and liver functions of male wistar rats were investigated using standard methods. Twelve male wistar rats were used for the study. They were randomly divided into four groups A, B, C and D made up of 3 rats each. The control group (A) received water + food ad ...

  14. Geochemistry of the Serra das Melancias Pluton in the Serra da Aldeia Suite: a classic post-collisional high Ba-Sr granite in The Riacho do Pontal Fold Belt, NE Brazil

    Directory of Open Access Journals (Sweden)

    Marcela Paschoal Perpétuo

    Full Text Available ABSTRACT: The Serra da Aldeia Suite is composed by circular or oval-shaped plutons, intrusive in meta-sedimentary and meta-volcanosedimentary rocks in the Riacho do Pontal Fold Belt, NE Brazil. The Serra das Melancias Pluton, belonging to Serra da Aldeia Suite, is located southeastern of Piaui state, near Paulistana city. These plutons represent a major magmatic expression in this area and contain important information about the late magmatic/collisional geologic evolution of the Brasiliano Orogeny. Based on petrographic and geochemical data, three facies were defined in the Serra das Melancias Pluton: granites, syenites and quartz monzonites. The rocks display high-K and alkaline to shoshonitic affinities, are metaluminous and show ferrous character. They are enriched in Light Rare Earth Elements and Large Ion Lithophile Elements, with negative anomalies in Nb, Ta and Ti. Their high Ba, Sr, K/Rb, low Rb, relatively low U, Th, Nb to very low Heavy Rare Earth Elements and Y resemble those of typical high Ba-Sr granitoids. The geochemical data suggest the emplacement of Serra das Melancias Pluton in a transitional, late to post-orogenic setting in the Riacho do Pontal Fold Belt during the late Brasiliano-Pan African Orogeny.

  15. The Variscan calc-alkalic plutonism of western Corsica: mineralogy and major and trace element geochemistry

    Science.gov (United States)

    Cocherie, A.; Rossi, Ph.; Le Bel, L.

    1984-10-01

    Petrographic and structural observations on the calc-alkalic plutonism of western Corsica revealed the existence of several successively emplaced units associated with large basic bodies. The present mineralogical and geochemical study deals with the genesis, evolution and relationships of these different units. Basic plutonism is represented by three genetically linked types of rock: norites and troctolites with cumulate textures characterized by low REE contents and either no Eu anomaly or a positive Eu anomaly; gabbros with enriched LREE relatively to HREE patterns, probably close to an initial basaltic liquid; and diorites ranging up to charnockites which represent liquids evolved to varying degrees, mainly by fractional crystallization. Trace element data and studies on the evolution of pyroxene pairs demonstrate the consanguinity of these calc-alkaline basic rocks which are derived from a high alumina basaltic melt. The various granitoids (granodiorites, monzogranites and leucocratic monzogranites, i.e., adamellites) have distinct evolution trends as shown by the composition of their mafic minerals and by trace element distributions. They cannot be considered as being derivatives of the basic suite and they cannot be related by a common fractionation sequence. Rather, they represent distinctive batches of crustal anatexis. In addition, hybridization phenomena with the basic melt are noticed in granodiorites. The particular problem of the low La/Yb, Eu/Eu∗ and the high U, Th, Cs leucocratic monzogranites is discussed in detail. In addition to more conventional trace element diagrams, the simultaneous statistical treatment of all the geochemical data by correspondence factor analysis is shown to be a very use tool in distinguishing between the different units and to classify the elements according to their geochemical properties.

  16. Pilot scale trials of irradiation preservation of maize, kola nuts and dried fish, and preliminary market test

    International Nuclear Information System (INIS)

    Akingbohungbe, A.E.

    1994-01-01

    Various studies were conducted to determine the possibility of utilizing gamma irradiation to disinfect cowpea, maize, kola nuts and smoked fish in Nigeria. The studies included the determination of radiosensitivity of important storage insect pests such as the cowpea seed beetle, 'Callosobrucus maculatus', the cigarette beetle, 'Lasioderma serricorne', the kola weevils, 'Balanogastris kolae' and 'Sophrorhinus gbanjaensis'. They also included consumer acceptance and or sensory evaluation of irradiated cowpea, maize and smoked-dried fish. The results showed that irradiation could be integrated with the traditional peasant farmers' method of storing unshelled dry cowpea in granaries; and such an integration can completely eliminate seed beetle infestation. Irradiation at a dose of 0.2-1.0KGy was quite effective in preventing development of 'L. Serricorne'. All stages of development of 'B.kolae' and 'S. gbanjaensis' were very sensitive to irradiation; and a dose of 0.1KGy-0.2KGy was found to be adequate for disinfecting kola nut of the weevils. Irradiation up to 0.2KGy also did not cause any significant change in proximate composition of kola nuts. Consumer acceptance and sensory evaluation tests on cowpea, maize and smoke-dried fish showed that Nigerian consumers did not have any aversion to irradiated foods. A high percentage of respondents indicated their willingness to purchase samples

  17. Garcinia kola aqueous suspension prevents cerebellar neurodegeneration in long-term diabetic rat - a type 1 diabetes mellitus model.

    Science.gov (United States)

    Farahna, Mohammed; Seke Etet, Paul F; Osman, Sayed Y; Yurt, Kıymet K; Amir, Naheed; Vecchio, Lorella; Aydin, Isınsu; Aldebasi, Yousef H; Sheikh, Azimullah; Chijuka, John C; Kaplan, Süleyman; Adem, Abdu

    2017-01-04

    The development of compounds able to improve metabolic syndrome and mitigate complications caused by inappropriate glycemic control in type 1 diabetes mellitus is challenging. The medicinal plant with established hypoglycemic properties Garcinia kola Heckel might have the potential to mitigate diabetes mellitus metabolic syndrome and complications. We have investigated the neuroprotective properties of a suspension of G. kola seeds in long-term type 1 diabetes mellitus rat model. Wistar rats, made diabetic by single injection of streptozotocin were monitored for 8 months. Then, they were administered with distilled water or G. kola oral aqueous suspension daily for 30 days. Body weight and glycemia were determined before and after treatment. After sacrifice, cerebella were dissected out and processed for stereological quantification of Purkinje cells. Histopathological and immunohistochemical analyses of markers of neuroinflammation and neurodegeneration were performed. Purkinje cell counts were significantly increased, and histopathological signs of apoptosis and neuroinflammation decreased, in diabetic animals treated with G. kola compared to diabetic rats given distilled water. Glycemia was also markedly improved and body weight restored to non-diabetic control values, following G. kola treatment. These results suggest that G. kola treatment improved the general condition of long-term diabetic rats and protected Purkinje cells partly by improving the systemic glycemia and mitigating neuroinflammation. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

  18. Carboniferous continental arc in the Hegenshan accretionary belt: Constrains from plutonic complex in central Inner Mongolia

    Science.gov (United States)

    Wei, Ruihua; Gao, Yongfeng; Xu, Shengchuan; Santosh, M.; Xin, Houtian; Zhang, Zhenmin; Li, Weilong; Liu, Yafang

    2018-05-01

    The architecture and tectonic evolution of the Hegenshan accretionary belt in the Central Asian Orogenic Belt (CAOB) remains debated. Here we present an integrated study of zircon U-Pb isotopic ages, whole rock major-trace elements, and Sr-Nd-Pb isotopic data from the Hegenshan volcanic-plutonic belt in central Inner Mongolia. Field observations and zircon U-Pb ages allow us to divide the intrusive complex into an early phase at 329-306 Ma and a late phase at 304 to 299 Ma. The intrusive bodies belong to two magma series: calc-alkaline rocks with I-type affinity and A-type granites. The early intrusions are composed of granodiorite, monzogranite and porphyritic granite, and the late calc-alkaline intrusions include gabbro though diorite to granodiorite. The calc-alkaline intrusive rocks exhibit a well-defined compositional trend from gabbro to granite, reflecting continuous fractional crystallization. These rocks show obvious enrichment in LILEs and LREEs and relative depletion of HFSEs, typical of subduction-related magma. They also exhibit isotopic characteristics of mantle-derived magmas such as low initial 87Sr/86Sr (0.7029-0.7053), positive ɛNd(t) values (0.06-4.76) and low radiogenic Pb isotopic compositions ((206Pb/204Pb)I = 17.907-19.198, (207Pb/204Pb)I = 15.474-15.555, (208Pb/204Pb)I = 37.408-38.893). The marked consistency in geochemical and isotopic compositions between the intrusive rocks and the coeval Baoligaomiao volcanic rocks define a Carboniferous continental arc. Together with available regional data, we infer that this east-west trending continental arc was generated by northward subduction of the Hegenshan ocean during Carboniferous. The late alkali-feldspar granites and the high-Si rhyolites of the Baoligaomiao volcanic succession show similar geochemical compositions with high SiO2 and variable total alkali contents, and low TiO2, MgO and CaO. These rocks are characterized by unusually low Sr and Ba, and high abundances of Zr, Th, Nb, HREEs

  19. Infrasound research at Kola Regional Seismological Centre, Russia

    Science.gov (United States)

    Asming, Vladimir; Kremenetskaya, Elena

    2013-04-01

    A small-aperture infrasound array has been installed in Kola Peninsula, Russia 17 km far from the town of Apatity in the year 2000. It comprises 3 Chaparral V microbarographs placed closely to the APA seismic array sensors and equipped with pipe wind reducing filters. The data are digitized at the array site and transmitted in real time to a processing center in Apatity. To search for infrasound events (arrivals of coherent signals) a beamforming-style detector has been developed. Now it works in near real time. We analyzed the detecting statistics for different frequency bands. Most man-made events are detected in 1-5 Hz band, microbaromes are typically detected in 0.2-1 Hz band. In lower frequencies we record mostly a wind noise. A data base of samples of infrasound signals of different natures has been collected. It contains recordings of microbaromes, industrial and military explosions, airplane shock waves, infrasound of airplanes, thunders, rocket launches and reentries, bolides etc. The most distant signals we have detected are associated with Kursk Magnetic Anomaly explosions (1700 km far from Apatity). We implemented an algorithm for association of infrasound signals and preliminary location of infrasound events by several arrays. It was tested with Apatity data together with data of Sweden - Finnish infrasound network operated by the Institute of Space Physics in Umea (Sweden). By agreement with NORSAR we have a real-time access to the data of Norwegian experimental infrasound installation situated in Karasjok (North Norway). Currently our detection and location programs work both with Apatity and Norwegian data. The results are available in Internet. Finnish militaries routinely destroy out-of-date weapon in autumns at the same compact site in North Finland. This is a great source of repeating infrasound signals of the same magnitude and origin. We recorded several hundreds of such explosions. The signals have been used for testing our location routines

  20. Miscellaneous investigations series: Bedrock geologic map of the Lone Mountain pluton area, Esmeralda County, Nevada

    International Nuclear Information System (INIS)

    Maldonado, F.

    1984-01-01

    The joint attitudes were measured in the field and plotted on aerial photos at a scale of 1:24,000. The pluton is intensely jointed, primarily as a result of cooling and movement of the magma within a northwest-trending stress field. Foliation, in general, is poorly developed, and quality varies from area to area, but it is best developed close to the contacts with the metasedimentary rocks. A prominent northwest foliation direction was observed that parallels the northwest elongation of the exposed pluton. Faults in the pluton are difficult to identify because of the homogeneity of the rock. Several faults were mapped in the northern part of the area where they have a northeast trend and intersect the northwest-trending lamprophyre dikes with little apparent displacement. A major fault that bounds the northern part of the pluton is downthrown to the north and strikes northeast. This fault offsets the alluvium, the metasedimentary rocks, and the pluton and forms fault scraps as high as 10 m. Aeromagnetic data (US Geological Survey, 1979) suggest the following: (1) the local magnetic highs in the central part of the Lone Mountain pluton are probably related to topographic highs (peaks) where the flight lines are closer to the pluton; (2) a magnetic low in the northeastern part of Lone Mountain coincides with the pluton-country rock contact, which may be very steep; (3) the contours for the southwestern part of the mapped area indicate that the pluton-country rock contact is not as steep as that in the northeastern part and that the pluton probably coalesces at depth with the Weepah pluton, a pluton exposed south of the mapped area; and (4) the contours for the area of the Lone Mountain pluton express a northwest-trending gradient that parallels the northwest elongation of the Lone Mountain pluton and the northwest-trending stress field. 10 refs

  1. Zircon U-Pb age, Lu-Hf isotope, mineral chemistry and geochemistry of Sundamalai peralkaline pluton from the Salem Block, southern India: Implications for Cryogenian adakite-like magmatism in an aborted-rift

    Science.gov (United States)

    Renjith, M. L.; Santosh, M.; Li, Tang; Satyanarayanan, M.; Korakoppa, M. M.; Tsunogae, T.; Subba Rao, D. V.; Kesav Krishna, A.; Nirmal Charan, S.

    2016-01-01

    The Sundamalai peralkaline pluton is one among the Cryogenian alkaline plutons occurring in the Dharmapuri Rift Zone (DRZ) of the Salem Block in the Southern Granulite Terrane (SGT) of India. Here we present zircon U-Pb age and Lu-Hf isotopic composition, mineral chemistry and geochemistry of the pluton to explore the petrogenesis and geodynamic implications. Systematic modal variation of orthoclase, Na-plagioclase, Ca-amphibole (ferro-edenite and hastingsite) and quartz developed quartz-monzonite and granite litho units in the Sundamalai pluton. Thermometry based on amphibole-plagioclase pair suggests that the pluton was emplaced and solidified at around 4.6 kbar pressure with crystallization of the major phases between 748 and 661 °C. Estimated saturation temperature of zircon (712-698 °C) is also well within this range. However, apatite saturation occurred at higher temperatures between 835 and 870 °C, in contrast with monazite saturation (718-613 °C) that continued up to the late stage of crystallization. Estimated oxygen fugacity values (log fO2: -14 to -17) indicate high oxidation state for the magma that stabilized titanite and magnetite. The magmatic zircons from Sundamalai pluton yielded a weighted mean 206Pb/238U age of 832.6 ± 3.2 Ma. Geochemically, the Sundamalai rocks are high-K to shoshonitic, persodic (Na2O/K2O ratio > 1), silica-saturated (SiO2:65-72 wt.%), and peralkaline in composition (aluminum saturation index, ASI Sc(2-3 ppm), positive Sr anomaly and predominantly negative zircon εHf(t) values (-10.8 to -9.3 with an average of -10.2) and initial 176Hf/177Hf ratios (0.281947-0.282022) confirm a Paleoproterozoic crustal source. Based on the field and geochemical evidences, we propose that a previously metasomatized mafic lower-crustal source enriched in alkalis has undergone CO2-present partial melting as a result of asthenospheric upwelling beneath an aborted rifting along the DRZ generating the magma that crystallized the Sundamalai rocks

  2. The Precambrian/Lower Cambrian pluton from Vila Nova (Central Portugal

    Directory of Open Access Journals (Sweden)

    Reis, A. I.M.

    2010-06-01

    Full Text Available The Vila Nova pluton is a small, Pre-Variscan granitic body that intruded rocks of the Central Iberian Zone near the contact with the Ossa Morena Zone and is affected by several shear zones and faults. Its contact metamorphic aureole is constituted by micaschist with porphyroblasts in the outer zone and hornfels in the inner zone. Small metasedimentar xenoliths are dispersed all over the body. The pluton has a great mineralogical heterogeneity with pronounced variations in muscovite/biotite and plagioclase/microcline contents and is classified as granite, granodiorite or tonalite. It is a leucogranite, highly peraluminous (A/CNK = 1.31 – 1.64, magnesian and calc-alkaline to alkaline-calcic. The variation diagrams show curvilinear trends with silica. Eu/Eu* = 0.47 – 0.77 and there is a slight enrichment in LREE relative to HREE. The normalized diagrams indicated dominantly crustal granite, related to subduction. U-Pb isotopic data of zircon and monazite gives 540-542 Ma age.

    El plutón de Vila Nova es un pequeño cuerpo granítico pre-varisco, que intruyó en las rocas de la Zona Centro Ibérica, cerca del contacto con la Zona de Ossa Morena, siendo afectado por varias fallas y zonas de cizalla. Su aureola de metamorfismo de contacto consiste en esquistos con porfiroblastos y corneanas. Pequeños xenolitos metasedimentarios aparecen dispersos por todo el cuerpo granítico. Presenta una gran diversidad mineralógica, con amplias variaciones en las relaciones biotita/moscovita y microclina/plagioclasa, siendo clasificado como tonalita-granodiorita-granito. Se trata de un leucogranito fuertemente peralumínico (A/CNK = 1.31 – 1.64, magnesiano y calco-alcalino a alcalino-cálcico. Los diagramas muestran variaciones curvilíneas con la variación de sílice. Eu/Eu* = 0.47 – 0.77 y hay un ligero enriquecimiento de LREE en relación con HREE. Los diagramas indican que la norma es un granito dominante de la corteza, relacionados con la

  3. Norite and charnockites from the Venda Nova Pluton, SE Brazil: Intensive parameters and some petrogenetic constraints

    Directory of Open Access Journals (Sweden)

    Julio Cezar Mendes

    2012-11-01

    Full Text Available The Venda Nova Pluton (VNP is a zoned ring structure emplaced in the southern portion of the Neoproterozoic Araçuai Belt, in Espírito Santo, Brazil. It is a slightly westward tilted cylinder-like intrusion, with an almost circular horizontal section. In the center of this structure, an off-centered gabbro-noritic core, surrounded by syeno-monzonitic rocks, intrudes an outer ring of charnockites and norite. These envelop the syeno-monzonitic and gabbro-noritic center, as a narrow discontinuous belt. While, in the core intrusion, mingling and mixing processes are widespread and well documented in the literature, in the outer ring, the norite and charnockite layers show predominantly homogeneous and isotropic internal structures. Nevertheless, smaller interaction zones between charnockites and norite denote a comparatively more restricted mingling process. The norite is a fine-grained rock with hypidiomorphic granular to intergranular texture. The charnockites are medium-grained and made up of: (a orthopyroxene-tonalite, (b orthopyroxene-quartz-diorite, and (c orthopyroxene-granodiorite with hypidiomorphic granular to porphyritic textures. In all lithotypes both ortho- and clinopyroxene are replaced by hornblende and biotite. Two contrasting compositional sequences have been recognized, based on whole rock geochemistry: (1 a basic, with tholeiitic affinities (norite and, (2 an intermediate, medium-K calc-alkaline, comprising the charnockites. Estimated crystallization temperatures, which have been calculated from micro-probe analysis of pyroxenes, range from 915 ± 25 °C to 960 ± 50 °C. Re-equilibration temperature (ilmenite-magnetite calibration is around 600 ± 50 °C. This indicates oxygen fugacities four order of magnitude below the FMQ-buffer and a reduced environment. Coeval pressure conditions estimated from the Al-content in hornblende range from 5.5 ± 0.6 kbar. Data obtained for the norite point toward an evolution from

  4. Petrographical and geochemical characterization and deformation conditions of the San Cristobal pluton, Sierra de Velasco, La Rioja, Argentina; Caracterizacion petrografica y geoquimica y condiciones de deformacion del pluton San Cristobal, Sierra de Velasco, La Rioja, Argentina

    Energy Technology Data Exchange (ETDEWEB)

    Bellos, L.I.; Toselli, A.J.; Rossi, J.N.; Grosse, P.; Rosa, J.D. de la; Castro, A.

    2010-07-01

    The San Cristobal pluton is a 35 km2 granitic body that outcrops at the southestern tip of the Sierra de Velasco, located west of La Rioja city, Argentina. It is formed by monzogranites and syenogranites, together with scarce granodiorites, with medium to fine-grained, equigranular to slightly porphyritic textures. Their mineral assemblage consists of quartz + microcline + plagioclase + biotite {+-} muscovite + zircon + apatite + magnetite. The granite contains dioritic to tonalitic mafic enclaves. The central and eastern parts of the granite have been deformed by the NNW-SSE trending South Mylonitic shear zone formed by mylonitic rocks. The metamorphic host-rock is represented by scarce greenschist facies xenoliths and hornfels with the high T/P assemblage K-feldspar - cordierite - biotite {+-} sillimanite. The granites are calc-alkaline, weak- to moderately peraluminous, and formed as part of a continental magmatic arc developed along the active margin of western Gondwana during the Early Paleozoic. The depth of emplacement of the San Cristobal pluton is estimated at {approx}12 km. (Author).

  5. Magma flow recorded by magmatic and magnetic fabrics in a shallow granitic pluton: La Gloria Pluton, central Chile

    Science.gov (United States)

    Payacán, I. J.; Gutiérrez, F. J.; Gelman, S. E.; Bachmann, O.; Parada, M. A.

    2013-12-01

    To better understand the dynamics of a small, shallow, silicic magma reservoir, magmatic and magnetic (AMS) fabrics are compared in samples obtained from La Gloria Pluton (LGP), a 10 Ma granitic intrusion located in southern Andes. The magnetic fabric of LGP, mainly given by magnetite, is characterized by oblate shapes. Magnetic lineations have a NW trend with subhorizontal dip, following the main pluton elongation, while magnetic foliation planes have dips varying gradually from vertical at the walls to subhorizontal toward the center and the roof of the pluton. On the basis of numerical simulations, magnetic fabric was interpreted to represent the shear record induced by magmatic convection along solidification fronts as the reservoir reached its rheological locking point. Magmatic fabric (mineral orientation) was determined on 12 samples along the pluton. Three mutually orthogonal thin sections were produced for each sample, perpendicular to the AMS tensor axes. Size and orientation of individual crystals were obtained by image analysis. A 2-D tensor for two mineral groups (plagioclase and amphibole+biotitie) was defined in each mineral plane projecting the crystal lengths on the main crystal orientation (given by Bingham statistics). A 3-D magmatic fabric tensor was obtained. In order to compare the magmatic and magnetic fabrics, magmatic anisotropy parameters were defined similar to the AMS tensors. Magmatic fabric and anisotropy parameter values vary depending on the location inside the pluton: (1) Samples located at the borders exhibit vertical foliations and lineations with a NW trend, similar to the magnetic fabric tensors and higher anisotropy values for plagioclase than amphibole+biotite,; (2) samples located at the center of the LGP commonly present subvertical foliations/lineations, which differ from the magnetic fabric, and higher magmatic anisotropy degree values for amphibole+biotite than plagioclase. Based on numerical simulations of the fluid

  6. Neogene Uplift and Exhumation of Plutonic Bodies in the Beni Bou Ifrour Massif (Nador, northeastern Morocco)

    Science.gov (United States)

    Lebret, Noëmie; Jolivet, Laurent; Branquet, Yannick; Bourdier, Jean-Louis; Jolivet, Marc; Marcoux, Eric

    2013-04-01

    In Neogene times, the whole Mediterranean Sea was the center of an intense magmatic activity. This post-collisional magmatism produced a large amount of volcanic edifices through the Alpine belts, together with some intrusives. These plutonic bodies can be associated with skarn-type mineralization, well-known in Elba Island or Serifos Island (Cyclades), where they are generally exhumed by detachment faults. In Morocco, the plutons hosted by the Beni Bou Ifrour massif are connected to the biggest skarn-type iron concentrations of the country (production > 60 Mt, reserves ≈ 25 Mt). The purpose of this work is to explain the late uplift of this massif and subsequent exhumation of the intrusives. As a final product of the Africa-Eurasia plate convergence since ca. 70 Ma, the Rif Mountains constitute the westernmost segment of the Mediterranean Alpine belts. In the oriental part of this range, volcanic summits and Paleozoic to Mesozoic massifs outcrop in the surrounding Mio-Pliocene plains. The Beni Bou Ifrour massif, in the Nador province, consists in a dome-shaped folded Mesozoic series (Domerian to Barremian) affected by a slight epizonal regional metamorphism (ca. 14-12 Ma), dislocated by Neogene NE-SW faults and eventually sealed by upper Miocene transgressive sediments. The hosted intrusives (7.58 ± 0.03 Ma; Duggen et al., 2005) are the plutonic equivalents to the potassic calc-alkaline lavas (andesites mainly) from the surrounding "satellite" volcanic massifs. They turn out to stand in higher topographic position than the younger shoshonitic lavas of the neighboring Gourougou stratovolcano (6.12 ± 0.01 Ma; Duggen et al., 2005). Previous studies have attributed this uplift to the action of normal faults (pull-apart basins; Guillemin & Houzay, 1982), thrusting (Kerchaoui, 1985; 1995) or even of a caldeira resurgence (El Bakkali, 1995). To discriminate against those exhumation mechanisms, field work has been performed, coming along with new cross-sections to

  7. The status of nuclear cooperation with Kola and Leningrad nuclear power plant

    International Nuclear Information System (INIS)

    2012-01-01

    Norway has since 1993 participated in joint projects with Russia to improve nuclear safety at the Kola and Leningrad nuclear power plant. The project have been funded under the Government's nuclear action under the leadership of the Ministry of Foreign Affairs. Institute for Energy Technology (IFE) has completed most of the projects. NRPA is the authority responsible for assessing the implementation of the projects. (eb)

  8. Kola Fjord radioactive contamination in the vicinity of the nuclear icebreakers fleet base

    International Nuclear Information System (INIS)

    Namjatov, A.

    1995-01-01

    The civil nuclear icebreakers have been based at the enterprise ''Atomflot'' in the Kola Bay for more than 30 years. In this paper the effects of nuclear discards from these ships on the ecosystem in the region have been stipulated. It is concluded that the estimated individual dose to man in the area is 1.7 to 4.1 x 10 -4 μSv/year

  9. Trace elements in bottom sediments of the Barents Sea on the standard section "Kola Meridian"

    OpenAIRE

    Lapteva A. M.; Plotitsyna N. F.

    2017-01-01

    The levels of trace metals (Cu, Zn, Ni, Cr, Mn, Co, Pb, Cd, Hg) and arsenic (As) in samples of bottom sediments from the Barents Sea on eight stations of the standard section "Kola Meridian" have been investigated. Trace elements have been determined on atomic absorption spectrophotometer AA-6800 with mercury-hydride attachment HVG-1 of the company Shimadzu (Japan) by the methods of flaming (acetylene – air) and electrothermal atomization. Common and very toxic trace elements incl...

  10. Magmatic tempo of Earth's youngest exposed plutons as revealed by detrital zircon U-Pb geochronology.

    Science.gov (United States)

    Ito, Hisatoshi; Spencer, Christopher J; Danišík, Martin; Hoiland, Carl W

    2017-09-29

    Plutons are formed by protracted crystallization of magma bodies several kilometers deep within the crust. The temporal frequency (i.e. episodicity or 'tempo') of pluton formation is often poorly constrained as timescales of pluton formation are largely variable and may be difficult to resolve by traditional dating methods. The Hida Mountain Range of central Japan hosts the youngest exposed plutons on Earth and provides a unique opportunity to assess the temporal and spatial characteristics of pluton emplacement at high temporal resolution. Here we apply U-Pb geochronology to zircon from the Quaternary Kurobegawa Granite and Takidani Granodiorite in the Hida Mountain Range, and from modern river sediments whose fluvial catchments include these plutons in order to reconstruct their formation. The U-Pb data demonstrate that the Kurobegawa pluton experienced two magmatic pulses at ~2.3 Ma and ~0.9 Ma; whereas, to the south, the Takidani pluton experienced only one magmatic pulse at ~1.6 Ma. These data imply that each of these magmatic systems were both spatially and temporally distinct. The apparent ~0.7 Myr age gap between each of the three magmatic pulses potentially constrains the recharge duration of a single pluton within a larger arc plutonic complex.

  11. Granitoids of the Dry Valleys area, southern Victoria Land, Antarctica : plutons, field relationships, and isotopic dating

    International Nuclear Information System (INIS)

    Allibone, A.H.; Cox, S.C.; Johnstone, R.D.

    1993-01-01

    Detailed mapping throughout much of the Dry Valleys area indicates the region is underlain by 15 major granitoid plutons and numerous smaller plugs and dikes. Intrusive relationships of these plutons and dikes indicate repeated intrusion of superficially similar granitoids at different times. Sufficient internal lithologic variation occurs within individual plutons, to allow correlation with several of the previously defined granitoid units based on lithologic character. Consequently, previous subdivision schemes based on lithology are no longer tenable and are here replaced with a subdivision scheme based on the identification of individual plutons. The elongate, concordant Bonney, Denton, Cavendish, and Wheeler Plutons, which range in composition between monzodiorite and granodiorite, are the oldest relatively undeformed plutons in the Dry Valleys area. Each pluton is characterised by flow alignment of K-feldspar megacrysts, hornblende, biotite, and mafic enclaves. Field relationships and radiometric dating indicate these are deep-level plutons, emplaced synchronous with upper amphibolite facies metamorphism of the adjacent Koettlitz Group between 589 and 490 Ma ago. Elongate, discordant plutons of equigranular homogeneous biotite granodiorite and granite (Hedley, Valhalla, St Johns, Suess) were subsequently emplaced by stoping at a relatively high crustal level at 490 Ma. These eight plutons are cut by numerous swarms of Vanda mafic and felsic porphyry dikes. The ovoid, discordant, high level Pearse, Nibelungen, Orestes, Brownworth, Swinford, and Harker Plutons, emplaced between c. 486 and 477 Ma, display mutually crosscutting relationships with the youngest of the Vanda dikes. These younger plutons range in composition between monzonite and granite. Some are characterised by K-feldspar megacrystic textures superficially similar to some of the oldest concordant plutons. (author). 57 refs.; 2 tabs.; 4 figs

  12. New petrographic, geochemical and geochronological data for the Reguengos de Monsaraz pluton (Ossa Morena Zone, SW Iberian Massif, Portugal)

    Energy Technology Data Exchange (ETDEWEB)

    Antunes, A.; Santos, J. F.; Azevedo, M. R.; Mendez, M. H.; Ribeiro, S.

    2010-07-01

    The Reguengos de Monsaraz pluton is a late to post-tectonic Variscan intrusion occurring in the Ossa Morena Zone (Iberian Variscan Chain). The dominant lithological types are tonalites and granodiorites, but the internal area of the massif is composed of gabbro-dioritic rocks. Field evidence shows that the intrusion is heterogeneous at mesoscopic scale suggesting that the emplacement of mafic and felsic magmas was contemporaneous. Petrographic and geochemical studies reveal that the different lithologic types define a continuous sequence with compositions varying from metaluminous to slightly peraluminous and a typical calc-alkaline signature. In Harker variation diagrams, it is possible to observe systematic rectilinear correlations pointing to the involvement of magma mingling/mixing processes in the petrogenesis of this sequence. Rb-Sr isotopic data, using a mineral-mineral pair from a granodiorite sample, yielded an age of 298 Ma, interpreted as a cooling age after igneous crystallization. (Author) 13 refs.

  13. Site-sensitive hazards of potential airborne radioactive release from sources on the Kola peninsula

    International Nuclear Information System (INIS)

    Bergman, R.; Thaning, L.; Baklanov, A.

    1998-02-01

    In this work we focus on cases of airborne releases from some of the sources on the Kola Peninsula - primarily nuclear reactors on submarines and the Kola Nuclear Power Plant (KNPP). The purpose of our study is to illustrate, and discuss some features - dependent on site and release characteristics - of the deposition patterns resulting from assumed unit radioactive releases to the atmosphere from a location at a fjord and from the KNPP in Polyarnye Zori. Using meteorological data for one real weather situation, the analysis is based on simulating the transport in air of assumed radioactive releases and estimating the deposition pattern on local, meso- and regional scales. By allowing unit releases to occur simultaneously from the site at the fjord and from the power plant (and with the same release profile in time) comparisons are made of differences in deposition patterns in and outside the Kola region. In this case study a set of assumed release heights, durations of the release, and particle size distributions are applied to indicate the dependence for the resulting deposition pattern on these parameters

  14. Producers’ motivation for collective action for kola production and marketing in Cameroon

    Directory of Open Access Journals (Sweden)

    Steven Franzel

    2012-04-01

    Full Text Available Collective action has been used as a strategy to improve the benefits of smallholder producers of kola nuts in Cameroon. Despite demonstrated benefits, not all producers are involved in the collective action. The presented study used a modified Technology Acceptance Model (TAM namely the Collective Action Behaviour model (CAB model to analyse kola producers’ motivation for collective action activities. Five hypotheses are formulated and tested using data obtained from 185 farmers who are involved in kola production and marketing in theWestern highlands of Cameroon. Results which were generated using Partial Least Squares (PLS approach for Structural Equation Modelling (SEM showed that farmers’ intrinsic motivators and ease of use influenced their behavioural intent to join a group marketing activities. The perceived usefulness that was mainly related to the economic benefits of group activities did not influence farmers’ behavioural intent. It is therefore concluded that extension messages and promotional activities targeting collective action need to emphasise the perceived ease of use of involvement and social benefits associated with group activities in order to increase farmers’ participation.

  15. Evidence of recent plutonic magmatism beneath Northeast Peloponnesus (Greece) and its relationship to regional tectonics

    Science.gov (United States)

    Tzanis, A.; Efstathiou, A.; Chailas, S.; Stamatakis, M.

    2018-03-01

    This work reports evidence of recent tectonically controlled plutonic magmatism related to Neogene volcanism in a broad area of Northeast Peloponnesus (Greece) that is straddled by the Hellenic Volcanic Arc and comprises the Argolid, the Argolic and Saronic gulfs and eastern Corinthia including the province of Crommyonia at the western half of Megaris peninsula (western Attica). We assess the contemporary stress field based on formal inversion of well-constrained crustal earthquake focal mechanisms and determine that it is principally extensional and NE-SW oriented, with σ1 strike and plunge being N64° and 77°, respectively and σ3 strikes and plunge N210° and 10°. This generates WNW-ESE and NW-SE faults, the former being dominant in the Saronic Gulf and the latter in the Argolic. In addition, the analysis predicts E-W and N330° faults with non-trivial right- and left-lateral heave, respectively, which are consistent with the R and R΄ directions of Riedel shear theory and explain a number of observed earthquake focal mechanisms and earthquake epicentre alignments. We also present a semi-quantitative analysis of observed aeromagnetic anomalies by performing numerical modelling of the radially averaged power spectrum with an efficient anomaly separation scheme based on a new type of 2-D Fourier domain filter introduced herein, the Radial Extended Meyer Window. This analysis identifies an extensive complex of magnetized rock formations buried at depths greater than 3 km which, given the geology and geotectonic setting of the area, can hardly be explained with anything other than calc-alkaline intrusions (plutons). At northeastern Corinthia and Crommyonia, this type of intrusive activity is unexceptional, mainly concentrated in the Gulf of Megara-Sousaki areas and consistent with the low-intensity, small-scale Pliocene dacitic volcanism observed therein. Conversely, large-scale elongate anomalies of E-W and N330° orientation have been identified in the Argolid

  16. Reconnaissance study of the Taylor Mountains pluton, southwestern Alaska

    Science.gov (United States)

    Hudson, Travis L.; Miller, Marti L.; Klimasauskas, Edward P.; Layer, Paul W.

    2010-01-01

    The Taylor Mountains pluton is a Late Cretaceous to early Tertiary (median age 65 + or ? 2 Ma) epizonal, composite biotite granite stock located about 235 km (145 mi) northeast of Dillingham in southwestern Alaska. This 30 km2 (12 mi2) pluton has sharp and discordant contacts with hornfels that developed in Upper Cretaceous clastic sedimentary rocks of the Kuskokwim Group. The three intrusive phases in the Taylor Mountains pluton, in order of emplacement, are (1) porphyritic granite containing large K-feldspar phenocrysts in a coarse-grained groundmass, (2) porphyritic granite containing large K-feldspar and smaller, but still coarse, plagioclase, quartz, and biotite phenocrysts in a fine-grained groundmass, and (3) fine-grained, leucocratic, equigranular granite. The porphyritic granites have different emplacement histories, but similar compositions; averages are 69.43 percent SiO2, 1.62 percent CaO, 5.23 percent FeO+MgO, 3.11 percent Na2O, and 4.50 percent K2O. The fine-grained, equigranular granite is distinctly felsic compared to porphyritic granite; it averages 75.3 percent SiO2, 0.49 percent CaO, 1.52 percent FeO+MgO, 3.31 percent Na2O, and 4.87 percent K2O. Many trace elements including Ni, Cr, Sc, V, Ba, Sr, Zr, Y, Nb, La, Ce, Th, and Nd are strongly depleted in fine-grained equigranular granite. Trace elements are not highly enriched in any of the granites. Known hydrothermal alteration is limited to one tourmaline-quartz replacement zone in porphyritic granite. Mineral deposits in the Taylor Mountains area are primarily placer gold (plus wolframite, cassiterite, and cinnabar); sources for these likely include scattered veins in hornfels peripheral to the Taylor Mountain pluton. The granite magmas that formed the Taylor Mountains pluton are thought to represent melted continental crust that possibly formed in response to high heat flow in the waning stage of Late Cretaceous subduction beneath interior Alaska.

  17. Discharges of nuclear waste into the Kola Bay and its impact on human radiological doses

    International Nuclear Information System (INIS)

    Matishov, Genady G.; Matishov, Dimitry G.; Namjatov, Alexey A.; Carroll, JoLynn; Dahle, Salve

    2000-01-01

    The civilian nuclear icebreaker facility, RTP ''ATOMFLOT,'' is located in Kola Bay, Northwest Russia, as are several nuclear installations operated by the Russian Northern Fleet. A treatment plant at the Atomflot facility discharges purified nuclear waste into the bay at an annual rate of 500 m 3 . As a result of plant modifications this rate will soon increase to 5000 m 3 /yr. Evidence of minor leakages of 60 Co are reported by in the vicinity of Atomflot as well as near several military installations in Kola and the adjacent Motovsky Bays. 137 Cs levels reported in the present study for seawater and seaweed collected from locations within the bays are at expected levels except in the vicinity of Atomflot, where the 137 Cs level in a seaweed sample was 46±5 Bq/kg w.w. indicating significant uptake of radionuclides to biota. Uptake also may be occurring in higher trophic levels of the food web through environmental exchange and/or biotransformation. We consider the impact of the present and anticipated discharges from Atomflot through a radiological dose assessment for humans consuming fish from Kola Bay. Mixing and transport of nuclear waste is simulated using a simple box model. Maximum doses, assuming consumption of 100 kg/yr of fish, are below 10 -9 Sv/yr; the planned ten-fold increase in the discharge of treated waste will increase the doses to below 10 -8 Sv/yr. Using data on radionuclide levels in sediments and assuming equilibrium partitioning of radionuclides among sediment, seawater and fish, we estimate that the total doses to humans consuming fish from different areas of Kola and Motovsky Bays, including adjacent to military-controlled nuclear installations, are ∼10 -7 Sv/yr. Nuclear activities in Kola and Motovsky Bays thus far have had minimal impact on the environment. Discharges from the treatment plant currently account for less than 0.2% of the total dose predictions. The increase in discharges from the treatment plant is not expected to change

  18. Reconstruction of early Holocene paleoclimate and environment in the SW Kola region, Russian Arctic

    Science.gov (United States)

    Grekov, Ivan; Kolka, Vasiliy; Syrykh, Liudmila; Nazarova, Larisa

    2016-04-01

    In the current period of the global climate change it becomes necessary to have a clear understanding of not only the changes taking place in the components of the natural environment, but also to understand development of all interactions between those components. Quaternary terrigenic sediments and lakes of the Kola Peninsula store information about the development of the region in the Late Glacial and Holocene: movements of the glacier, neotectonic activity, post-glacial rebound, formation and development of natural environments after deglaciation. Multi-proxy study of landscapes evolution of the Kola Peninsula in the Late Quaternary will help to establish a detailed reconstruction of climatic and environmental changes of this poor studied sector of the Arctic. Quaternary history on the Kola Peninsula is represented mainly by Late Pleistocene and Holocene sediments covering the Baltic Shield (Lavrova, 1960; Evzerov, 2015). Several palaeolimnological investigations in the Baltic Shield area have been performed earlier (Donner et al., 1977; Anundsen, 1985; Berglund, 2004). Studies of the southern coast of the Kola Peninsula have shown that marine transgression took place in the Late Pleistocene that was then replaced by a regression with variable speed. The slowdown of the uplift of the area took place between 8800 - 6800 BP (cal. years) and corresponded to the time of the Tapes transgression of the Arctic Ocean (Evzerov et al. 2010; Kolka, et al., 2013). Palaeoclimatic studies based on micro-paleontological analyzes indicate uneven development of the Kola Peninsula landscapes in the Late Glacial and Early Holocene. The northern coast of the Peninsula became free of ice first. In this area tundra-steppe vegetation was established for a short time and was later replaced by tundra (Snyder et al, 2000). Southern part of the Kola Peninsula was dependent on the conditions of deglaciation of the White Sea basin and cleared of ice much later (Evzerov et al., 2010; Kolka

  19. Plume-related mantle source of super-large rare metal deposits from the Lovozero and Khibina massifs on the Kola Peninsula, Eastern part of Baltic Shield: Sr, Nd and Hf isotope systematics

    Science.gov (United States)

    Kogarko, L. N.; Lahaye, Y.; Brey, G. P.

    2010-03-01

    The two world’s largest complexes of highly alkaline nepheline syenites and related rare metal loparite and eudialyte deposits, the Khibina and Lovozero massifs, occur in the central part of the Kola Peninsula. We measured for the first time in situ the trace element concentrations and the Sr, Nd and Hf isotope ratios by LA-ICP-MS (laser ablation inductively coupled plasma mass spectrometer) in loparite, eudialyte an in some other pegmatitic minerals. The results are in aggreement with the whole rock Sr and Nd isotope which suggests the formation of these superlarge rare metal deposits in a magmatic closed system. The initial Hf, Sr, Nd isotope ratios are similar to the isotopic signatures of OIB indicating depleted mantle as a source. This leads to the suggestion that the origin of these gigantic alkaline intrusions is connected to a deep seated mantle source—possibly to a lower mantle plume. The required combination of a depleted mantle and high rare metal enrichment in the source can be explained by the input of incompatible elements by metasomatising melts/fluids into the zones of alkaline magma generation shortly before the partial melting event (to avoid ingrowth of radiogenic isotopes). The minerals belovite and pyrochlore from the pegmatites are abnormally high in 87Sr /86Sr ratios. This may be explained by closed system isotope evolution as a result of a significant increase in Rb/Sr during the evolution of the peralkaline magma.

  20. GEOCHEMICAL CHARACTERISTICS OF TIANMENSHAN COMPOSITE PLUTON, SOUTH CHINA

    Directory of Open Access Journals (Sweden)

    Yanjiao Chen

    2017-01-01

    Full Text Available The southern Jiangxi province is located at east Nanling range, which is an important W-Sn metallogenic province of China. The Early Yanshanian Tianmenshan is composed of the main-phase porphyritic biotite granite and the highly differentiated fine-gained biotite granite, intruding in the Lower Cambrian Niujiaohe Formation. The main-phase granite and the late-stage highly differentiated granite emplaced at 152–158 Ma and 152–151 Ma, respectively. The later was in the center of the pluton as a ovalize shape, with a transitional contact with the main-phase granite.

  1. Modeling of the regional and global transport of radionuclides from the Kola NPP

    Energy Technology Data Exchange (ETDEWEB)

    Marchuk, G.I.; Aloyan, A.E.; Arutyunyan, V.O.; Louzan, P.I. [Russian Academy of Sciences, Moscow (Russian Federation). Inst. for Numerical Mathematics; Bergman, R. [ed.] [Defence Research Establishment, Umeaa (Sweden). Div. of NBC Defence

    2000-05-01

    This Technical Report belongs to the INTAS project 96-1802: Assessment of potential risk of environmental radioactive contamination in northern Europe from terrestrial nuclear units in north-west Russia. The aim of this INTAS project is to assess the potential risk of environmental radioactive contamination from nuclear units in northwest Russia and resulting impacts on population and terrestrial ecosystems in the north. The work focuses mainly on airborne radioactive contamination, but some case studies also deal with accidental leakage from terrestrial nuclear sites to soil and coastal waters. The main aim in this technical report is to calculate and describe radioactive contamination levels in the Kola Peninsula resulting from a hypothetical accidental release from the Kola Nuclear Power Plant (KNPP). The method of assessment of radioactive contamination in the Kola Peninsula described here is based on the mathematical models developed at the Institute for Numerical Mathematics of the Russian Academy of Sciences (INM RAS). Model validation was performed several times on a wide variety of actual problems and case studies. The validation procedure indicated good capabilities in predicting the qualitative and quantitative contamination patterns resulting from the processes under consideration. Various scenarios reflecting typical meteorological conditions in a specific area are used in the numerical simulation. The conclusions resulting from analysis of such scenario calculations are of rather general character, and can be extrapolated in time provided that climate remains relatively stable. The employed 3D numerical model of radionuclide transport in the Northern hemisphere takes into account the interaction between boundary layers of the ocean and atmosphere, long term tracing of the radionuclides evolution in the atmosphere, their deposition on the earth surface, and migration in soil and sea water.

  2. Investigation and design concepts for a nuclear waste repository in the Kola Peninsula of Northwest Russia

    International Nuclear Information System (INIS)

    Melnikov, N.N.; Sharp, W.R.

    1994-01-01

    The Murmansk and Archangelsk regions located in northwestern Russia have accumulated large quantities of radioactive waste products from nuclear power plants, military ships (submarines, aircraft carriers and cruisers), ice breakers and light ships of the Murmansk Merchant Marines. This nuclear waste and associated byproducts are temporarily stored in surface facilities which lack long-term safety and containment assurances. Due to the lack of temporary storage facilities, the Russian Navy accumulates nuclear waste on floating ships and continues to dump liquid wastes into the Arctic Sea. The extent and nature of the problem is presently unknown. Waste producing organizations have neither facilities for the treatment and disposal, nor the capital necessary to construct such facilities. If urgent measures are not taken soon, the increasing quantity of waste will create an even more serious danger not only to the local population but also to the neighboring countries. The problem is one of global concern. This paper describes work being done at the Kola Mining Institute to mitigate problems of the past and to assure the continued safe production of energy from nuclear resources. The Kola Peninsula provides a natural location for the storage of nuclear materials and as a site for the production of abundant, inexpensive nuclear power. Recent studies support the theory that Kola is an ideal location for both the production of nuclear power and as a site to store and recycle radioactive materials. However, there exists today in Russia several potential long-term, world-threatening environmental problems if they are not addressed and resolved within the next few years. The problem is not due to the lack of technical solutions, but rather a lack of political and capital commitment

  3. Genesis of apocarbonatitic titanium metasomatites of the Petyayan-vara rare-earth occurrence (Vuoriyarvi, the Kola Region

    Directory of Open Access Journals (Sweden)

    Kozlov E. N.

    2018-03-01

    Full Text Available The objects of the study are apocarbonatitic titanium metasomatites ("titanium carbonatites" associated with the rare earth carbonatites of the Petyayan-Vara area of the Vuoriyarvi complex (the Kola region. In this paper, the following mechanism for the formation of these rocks has been substantiated based on the agreed results of mineralogical and geochemical studies. Prior to the onset of carbonatite genesis, a fluorine-enriched fluid phase originated in the lower horizons of the complex passed along the deep-permeating fracture system of several hundred meters length up to the level of the modern erosion surface. It transported Al, Fe2+, Mg, Ti, P into the pyroxenites and Si, Ca and Na out of them, as a result of which the pyroxenites were transformed into giant-grained phlogopite rocks – glimmerites. The most probable source of this fluid is alkaline aluminosilicate magma. Then carbonate melts intruded along the same fractures. In the course of carbonatite genesis, F-fluid caused a local migration of K, Al, Si, Fe, P, Ti, Nb, Ta, Zr, Hf and HREE out of glimmerites into igneous dolomite carbonatites, which led to the formation of apocarbonatitic titanium metasomatites. They represent several paragenetic associations superimposed on each other, the mineral composition and the formation sequence of which correspond to the metasomatic column zones directly observed within the contact "carbonatite – altered pyroxenite". The separation of HFSE and REE is controlled by the same metasomatic column: Ti, Nb and Ta were accumulated in titanium carbonatites, i. e. in associations of the frontal and intermediate zones, and Zr, Hf and HREE – in apatitized fields corresponding to the rear zone of the column. Accordingly, the fractionation of these elements occurred due to the "fluid – rock" interaction. Subsequently, the same long-lived fractures served as a channel for REE-Sr-Ba-S fluids, but the recrystallization caused by K

  4. Assessing the Effect of Salinity on an Irrigated Land at Kofai, Ardo-Kola Local Government Area, Taraba State - Nigeria

    Directory of Open Access Journals (Sweden)

    Buba Apagu ANKIDAWA

    2010-12-01

    Full Text Available A study of the effect of salinity on an irrigated land was carried out at Kofai, Ardo-Kola Local Government of Taraba State. The study area was divided into four (4 units designated as A, B, C and D, each unit was subdivided into five (5 parts, designated as A1, A2, A3, A4, A5, B1, B2, B3, B4, B5, C1, C2, C3, C4, C5, D1, D2, D3, D4, and D5, respectively, made up of twenty (20 soil samples that were collected within the irrigated land for the laboratory analysis of salinity. The parameters analyzed were pH, Electrical Conductivity (EC, Magnesium, Sodium, Potassium, Calcium, Hydrogen and Aluminum concentration. The results of the soil sample analysis shows that the mean value of pH is 5.99 which indicates that the soil is slightly acidic, the mean value of electrical conductivity (EC is 0.76 ds/m, Calcium, Magnesium, Aluminum and Hydrogen concentration were obtained to be 11.29, 7.89, 7.98 and 16.88 mg/l respectively, while Sodium and Potassium concentration were obtained to be 0.90 and 0.67 mg/l respectively with Sodium Absorption Ratio (SAR of 0.25 mEq/l. From the analysis it indicates that the soil is low in salinity. Similarly for water sample analysis the pH is 7.7 which indicate that the water is slightly alkaline, EC is 0.8 ds/m, calcium and magnesium concentration were 0.48 and 0.35 mg/l, while sodium and potassium were 0.57 and 0.71 mg/l respectively, with Sodium Absorption Ratio (SAR of 0.89 meq/l, which shows that the water sample were found within the safe limit for irrigation. It can be recommended that application of good quality water, choice of salt tolerant crops and gypsum be adopted in the study area.

  5. Field experience of new nuclear fuel types on the Kola NPP

    International Nuclear Information System (INIS)

    Adeev, V.; Burlov, S.; Panov, A.; Saprykin, V.

    2008-01-01

    Specificity of the Kola nuclear power plant geographical position, conditions of region economics determine fuel management strategy. Isolation of Kola power supply system and, as a consequence, generating capacities redundancy cause operation of the nuclear power plant on reduced power level. At the same time there is a need to operate the power unit on the maximum power level in the case of not planned conditions. The basis of in-core fuel management is an achievement of the maximal burnup under providing of high installed capacity. At present there are not abilities to improve the fuel cycle based on traditional implementation fuel assemblies. Burnup maximum in these fuel cycles is achieved. At the core periphery installed highest possible quantity of the burned-up assemblies in the view of safety operation margins satisfaction. Works on application of the second generation fuel have been carried out on the Kola NPP since 2002. Fuel assemblies of this type are profiled. Burnable absorber, changed lattice spacing in relation to standard fuel, changed height of a fuel column, thickness of fuel pin clad are applied. In CR fuel followers modernized docking unit (with hafnium plates are intended for energy-release splash suppression) is used. At present 2-nd generation fuel is in experimental operation on unit 3 (18-21 fuel cycles, 2002-2007 years) and unit 4 (18-19 fuel cycles, 2005-2007 years). Safety margins did not exceeded. Coolant activity did not exceed the limiting value. There were not damaged fuel assemblies of second generation. Originally in the project of applications of new fuel it was supposed to refuel annually 78 fresh assemblies. At the moment annual refueling consists of 66 assemblies with effective enrichment 3.82 %. Cycle duration does not exceed 250-260 effective days. The part of assemblies is left on 5-th cycle of operation. In a similar fuel cycle in 2007 on the unit 1 operation with profiled fuel (enrichment of 3.82 %) of shakeproof type

  6. Stavovi nastavnika osnovnih škola o inkluzivnom odgoju i obrazovanju u Republici Makedoniji

    OpenAIRE

    Dimitrova-Radojičić, Daniela; Čičevska-Jovanova, Nataša

    2013-01-01

    Cilj je ovog istraživanja utvrditi kakvi su stavovi nastavnika/ca razredne i predmetne nastave u 25 redovnih osnovnih škola prema uključivanju učenika s posebnim odgojno-obrazobnim potrebama (POOP) u njihove razrede. Korišten je upitnik koji je posebno napravljen za ovo istraživanje. Podatci su dobiveni od ukupno 879 nastavnika/ca. Ovim smo istraživanjem htjeli utvrditi broj učenika s POOP uključenih u redovnim školama, stavove nastavnika/ca o inkluzivnom obrazovanju kao i njihovo mišljenje o...

  7. Guidelines to classification and nomenclature of Arabian felsic plutonic rocks

    Science.gov (United States)

    Ramsay, C.R.; Stoeser, D.B.; Drysdall, A.R.

    1986-01-01

    Well-defined procedures for classifying the felsic plutonic rocks of the Arabian Shield on the basis of petrographic, chemical and lithostratigraphic criteria and mineral-resource potential have been adopted and developed in the Saudi Arabian Deputy Ministry for Mineral Resources over the past decade. A number of problems with conventional classification schemes have been identified and resolved; others, notably those arising from difficulties in identifying precise mineral compositions, continue to present difficulties. The petrographic nomenclature used is essentially that recommended by the International Union of Geological Sciences. Problems that have arisen include the definition of: (1) rocks with sodic, zoned or perthitic feldspar, (2) trondhjemites, and (3) alkali granites. Chemical classification has been largely based on relative molar amounts of alumina, lime and alkalis, and the use of conventional variation diagrams, but pilot studies utilizing univariate and multivariate statistical techniques have been made. The classification used in Saudi Arabia for stratigraphic purposes is a hierarchy of formation-rank units, suites and super-suites as defined in the Saudi Arabian stratigraphic code. For genetic and petrological studies, a grouping as 'associations' of similar and genetically related lithologies is commonly used. In order to indicate mineral-resource potential, the felsic plutons are classed as common, precursor, specialized or mineralized, in order of increasing exploration significance. ?? 1986.

  8. Plutons and accretionary episodes of the Klamath Mountains, California and Oregon

    Science.gov (United States)

    Irwin, William P.; Wooden, Joseph L.

    1999-01-01

    The Klamath Mountains consist of various accreted terranes and include many plutons that range in composition from gabbro to granodiorite. Some of the plutons (preaccretionary plutons) were parts of terranes before the terranes accreted; others (accretionary plutons) intruded during or after the accretion of their host terrane(s). This report attempts to (1) graphically illustrate how the Klamath Mountains grew by the accretion of allochthonous oceanic terranes during early Paleozoic to Cretaceous times, (2) identify the plutons as either preaccretionary or accretionary, and (3) genetically relate the plutonic intrusions to specific accretionary episodes. The eight accretionary episodes portrayed in this report are similar to those shown by Irwin and Mankinen (1998) who briefly described the basis for the timing of the episodes and who illustrated the ~110 degrees of clockwise rotation of the Klamath Mountains since Early Devonian time. Each episode is named for the accreting terrane. In all episodes (Figs. 1-8), the heavy black line represents a fault that separates the accreting oceanic rocks on the left from earlier accreted terranes on the right. The preaccretionary plutons are shown within the accreting oceanic crustal rocks to the left of the heavy black line, and the accretionary plutons in most instances are shown intruding previously accreted terranes to the right. Episodes earlier than the Central Metamorphic episode (Fig. 1), and that may have been important in the formation of the early Paleozoic nucleous of the province (the Eastern Klamath terrane), are not known. The 'Present Time' distribution of the accreted terranes and plutons is shown at a large scale in Figure 9. The schematic vertical section (Fig. 10) depicts the terranes as a stack of horizontal slabs that include or are intruded by vertical plutons. Note that at their base the ~170 Ma preaccretionary plutons of the Western Hayfork subterrane are truncated by the ~164 Ma Salt Creek

  9. A PCR detection method for rapid identification of Melissococcus pluton in honeybee larvae.

    Science.gov (United States)

    Govan, V A; Brözel, V; Allsopp, M H; Davison, S

    1998-05-01

    Melissococcus pluton is the causative agent of European foulbrood, a disease of honeybee larvae. This bacterium is particularly difficult to isolate because of its stringent growth requirements and competition from other bacteria. PCR was used selectively to amplify specific rRNA gene sequences of M. pluton from pure culture, from crude cell lysates, and directly from infected bee larvae. The PCR primers were designed from M. pluton 16S rRNA sequence data. The PCR products were visualized by agarose gel electrophoresis and confirmed as originating from M. pluton by sequencing in both directions. Detection was highly specific, and the probes did not hybridize with DNA from other bacterial species tested. This method enabled the rapid and specific detection and identification of M. pluton from pure cultures and infected bee larvae.

  10. The application of mathematical transformation in order to define edges of pluton Valja Strž

    Directory of Open Access Journals (Sweden)

    Ignjatović Snežana M.

    2014-01-01

    Full Text Available The Timok Magmatic Complex (TMC belongs to the East Serbian and is the largest volcanic area in our country. The largest pluton in this area is Valja Strž. This pluton is situated in the northwestern part of the complex. Applying different methods of mathematical transformation on aeromagnetic data facilitated outlining of pluton edges in subsurface of surrounding rocks. In this paper we used mathematical transformation on anomaly values of the magnetic field, obtained from processing of aeromagnetic data. In order to detect the edges of pluton Valja Strž we used following set of mathematical transformation: first vertical derivative, the total horizontal derivative, tilt derivative, upward continuation, and combination of upward continuation and tilt derivative. Results of application of mathematical transformation showed that outspread of the pluton Valja Strž in the subsurface is larger than its extend on the surface.

  11. Analysis on uranium metallogenetic conditions of granite pluton in Ulan Uzhur

    International Nuclear Information System (INIS)

    Lu Yaozu

    2014-01-01

    Qimantage area in Qinghai province is one of the important exploration areas in the present China, Ulan Uzhur complex pluton, located in the compound tectonic magmatic belt of Qimantage, is the main cluster area with uranium mineralization. This paper describes the petrochemical, geochemical, petrophysical and Heishan uranium deposit mineralization characteristics of rocks formed at the different tectonic-magmatic cycles in Ulan Uzhur complex pluton. Uranium metallogenic conditions in Ulan Uzhur complex pluton were analyzed from uranium source, magmatic activity and structure. The research shew that the Ulan Uzhur complex pluton has the petrochemical characteristics of uranium rock and Cisuralian monzonitic granite has the most significant relationship to uranium mineralization, it has the characteristics of high background radiation, many anomalies and pronounced ore-control structure, Heishan uranium deposit was controlled by factors such as pronounced northeast and the northwest structure and alteration. To conclude, Ulan Uzhur complex pluton possesses good uranium metallogenic prospect. (author)

  12. Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile

    Science.gov (United States)

    Michael, Peter J.

    1991-10-01

    The Cordillera del Paine pluton in the southernmost Andes of Chile represents a deeply dissected magma chamber where mafic magma intruded into crystallizing granitic magma. Throughout much of the 10x15 km pluton, there is a sharp and continuous boundary at a remarkably constant elevation of 1,100 m that separates granitic rocks (Cordillera del Paine or CP granite: 69 77% SiO2) which make up the upper levels of the pluton from mafic and comingled rocks (Paine Mafic Complex or PMC: 45 60% SiO2) which dominate the lower exposures of the pluton. Chilled, crenulate, disrupted contacts of mafic rock against granite demonstrate that partly crystallized granite was intruded by mafic magma which solidified prior to complete crystallization of the granitic magma. The boundary at 1,100 m was a large and stable density contrast between the denser, hotter mafic magma and cooler granitic magma. The granitic magma was more solidified near the margins of the chamber when mafic intrusion occurred, and the PMC is less disrupted by granites there. Near the pluton margins, the PMC grades upward irregularly from cumulate gabbros to monzodiorites. Mafic magma differentiated largely by fractional crystallization as indicated by the presence of cumulate rocks and by the low levels of compatible elements in most PMC rocks. The compositional gap between the PMC and CP granite indicates that mixing (blending) of granitic magma into the mafic magma was less important, although it is apparent from mineral assemblages in mafic rocks. Granitic magma may have incorporated small amounts of mafic liquid that had evolved to >60% SiO2 by crystallization. Mixing was inhibited by the extent of crystallization of the granite, and by the thermal contrast and the stable density contrast between the magmas. PMC gabbros display disequilibrium mineral assemblages including early formed zoned olivine (with orthopyroxene coronas), clinopyroxene, calcic plagioclase and paragasite and later-formed amphibole

  13. Geochronology and geochemistry of the Borohoro pluton in the northern Yili Block, NW China: Implication for the tectonic evolution of the northern West Tianshan orogen

    Science.gov (United States)

    Wang, Meng; Zhang, Jinjiang; Zhang, Bo; Liu, Kai; Chen, Youxin; Zheng, Yanrong

    2018-03-01

    The closure of the North Tianshan Ocean between the Junggar Terrane and the Yili Block is a longtime debated issue in literature, because of the different understanding of the Carboniferous volcanic rocks in the northern margin of the Yili Block. This study presents new geochronological and whole-rock geochemical data for the granitic rocks from the Borohoro pluton to provide constraints on the tectonic regime for the northern West Tianshan during the Carboniferous. LA-ICP-MS U-Pb dating results reveal two magmatic phases for the Borohoro pluton. The former magmatic activity in the Early Carboniferous formed the fine-grained granodiorite (332 Ma). The later magmatic activity occurred during the Late Carboniferous (305-300 Ma), forming a diversity of granitic rocks, involving quartz diorite, granodiorite and granite. Geochemical and mineralogical studies reveal that the studied granitic rocks from the Borohoro pluton all belong to metaluminous to weakly peraluminous, calc-alkaline I-type granites. They are characterized by enrichment in LILEs relative to HFSEs, and depletion of Nb, Ti and P, typical of continental arc-type granites. The intermediate SiO2, high Al2O3, and relatively low Fe2O3T, MgO and TiO2 contents reflect that these granitic rocks are mainly crust-derived. But the high Mg# values for most samples and the occurrence of microgranular mafic enclaves indicate that their magma sources were mixed by mantle-derived components. Especially, the Late Carboniferous rocks define an elegant mixing trend in both the Rb-Rb/V and the 1/V-Rb/V diagrams, consistent with mixing between magmas from subcontinental lithospheric mantle and mafic lower crust. Taking into consideration of the facts that all the Devonian to Carboniferous granitoids belong to calc-alkaline I-type granites, and granitoids of A-type didn't appear until the Early Permian, we suggest that the subduction of the North Tianshan Ocean continued to the Late Carboniferous, generating the granitic

  14. In Vitro Antilisterial Properties of Crude Methanol Extracts of Garcinia kola (Heckel Seeds

    Directory of Open Access Journals (Sweden)

    Dambudzo Penduka

    2012-01-01

    Full Text Available Crude methanol extracts of Garcinia kola (Heckel seeds were screened for their antilisterial activities against 42 Listeria bacteria isolated from wastewater effluents. The extract had activity against 45% of the test bacteria and achieved minimum inhibitory concentrations (MICs ranging between 0.157 and 0.625 mg/mL. The rate of kill of the extract was determined against four representative Listeria species in the study, and the results showed that the highest percentage of bacteria cells were killed after the maximum exposure time of 2 h at the highest concentration of 4×MIC value, with the maximum number of bacteria cells killed being for L. ivanovii (LEL 30 100%, L. monocytogenes (LAL 8 94.686%, L. ivanovii (LEL 18 60.330%, and L. grayi (LAL 15 56.071% We therefore conclude that the nature of inhibition of the crude methanol extracts of Garcinia kola seeds can be either bactericidal or bacteriostatic depending on the target Listeria species and can also differ among same species as evidenced by L. ivanovii strains LEL 30 and LEL 18.

  15. Development of the safety analysis system - SAIS - application to the Kola nuclear power plant

    International Nuclear Information System (INIS)

    Balfanz, H.P.; Fuhrmann, C.; Neumann, L.; Rumpf, J.; Kubintsev, B.; Marakulin, I.; Shevelev, V.; Terekhov, I.

    1995-01-01

    The project was started in July 1991 and finished by the end of 1993. It was aimed at adapting SAIS to WWER-440/W213 plant design and operational procedures, demonstrating the possibilities of SAIS for safety evaluation and examining the system by plant personnel and a PSA team. The project covered -the use of data form as well as fault and event tree methods of SAIS, - a probabilistic assessment of the high pressure injection system in case of a small break loss-of-coolant accident, - a quantification of human error probabilities for operator actions to cool down the primary circuit in case of a small break loss-of-coolant accident when the high pressure injection system has failed and - a comparison of Russian and German operational procedures and safety documents used in the probabilistic analyses of the SAIS-Kola project. As a main result SAIS was found to be an appropriate tool to give assistance to the plant personnel on safety evaluation of the plant within the frame of reconstruction measures and on the establishment of a qualified reliability data collection system at Kola NPP. (orig./HP) [de

  16. Current and perspective on the radioactive waste management at territory of the Kola Peninsula

    International Nuclear Information System (INIS)

    Amazova, Ludmila

    1999-01-01

    According to this presentation, 25 thousand cubic metres of solid radioactive waste of one million Ci activity has accumulated in the Murmansk Region because of previous civilian and military activities and more will come as a result of the coming decommissioning of nuclear submarines and nuclear power plants. Only a part of the solid radioactive waste is reprocessed at the Kola nuclear power plant and at the repairing and technological enterprise Atomflot. Compaction and incineration are used to decrease the volume of waste. An incineration facility at Atomflot fails to satisfy new requirements and even releases more radioactivity to the atmosphere than what used to come from the Kola nuclear power plant operation. Solid radioactive waste is stored non-reprocessed Spetscombinat special plant Radon. This plant collects and stores radioactive waste produced by the civil industry and at the bases of the Northern Fleet. It is emphasised, however, that during the observation period there were no cases of dangerous increase in radioactivity in the atmosphere. Soil and vegetation contamination by long-lived radionuclides was at the background level. The establishment of a common reprocessing and regional storage facility for long-term storage has been proposed by the Ministry for Atomic Energy

  17. Characterization of crystalline rocks in deep boreholes. The Kola, Krivoy Rog and Tyrnauz boreholes

    International Nuclear Information System (INIS)

    1992-12-01

    SKB studies, as one alternative, the feasibility of disposing of spent nuclear fuel in very deep boreholes. As a part of this work NEDRA has compiled geoscientific data from three superdeep boreholes within the former Soviet Union. The holes considered were: the Kola borehole, 12261 m deep and located on the Kola Peninsula, the Krivoy Rog borehole, 5000 m deep and located in Ukraine, and the Tyrnauz borehole, 4001 m deep and located between the Black Sea and the Caspian Sea. These boreholes all penetrate crystalline formations, but major differences are found when their tectonic environments are compared. Excluding the uppermost horizon affected by surface phenomena, data do not indicate any general correlation between depth and the state of rock fracturing, which is instead governed by site specific, lithological and tectonical factors. This applies also to fracture zones, which are found at similar frequencies at all depths. As opposed to the structural data, the hydrogeological and hydrochemical information reveals a vertical zonation, with clear similarities between the three boreholes. An upper zone with active circulation and fresh or slightly mineralized groundwaters reaches down 1000-2000 m. The interval from 1000-2000 m down to 4000-5000 m can be characterized as a transition zone with lower circulation rates and gradually increasing mineralisation. Below 4000-5000 m, strongly mineralized, stagnant, juvenile or metamorphogenic waters are found. Geothermal data verify the existence of this zonation. 28 figs, 30 tabs

  18. Uranium in alkaline rocks

    International Nuclear Information System (INIS)

    Murphy, M.; Wollenberg, H.; Strisower, B.; Bowman, H.; Flexser, S.; Carmichael, I.

    1978-04-01

    Geologic and geochemical criteria were developed for the occurrence of economic uranium deposits in alkaline igneous rocks. A literature search, a limited chemical analytical program, and visits to three prominent alkaline-rock localities (Ilimaussaq, Greenland; Pocos de Caldas, Brazil; and Powderhorn, Colorado) were made to establish criteria to determine if a site had some uranium resource potential. From the literature, four alkaline-intrusive occurrences of differing character were identified as type-localities for uranium mineralization, and the important aspects of these localities were described. These characteristics were used to categorize and evaluate U.S. occurrences. The literature search disclosed 69 U.S. sites, encompassing nepheline syenite, alkaline granite, and carbonatite. It was possible to compare two-thirds of these sites to the type localities. A ranking system identified ten of the sites as most likely to have uranium resource potential

  19. Uranium in alkaline rocks

    Energy Technology Data Exchange (ETDEWEB)

    Murphy, M.; Wollenberg, H.; Strisower, B.; Bowman, H.; Flexser, S.; Carmichael, I.

    1978-04-01

    Geologic and geochemical criteria were developed for the occurrence of economic uranium deposits in alkaline igneous rocks. A literature search, a limited chemical analytical program, and visits to three prominent alkaline-rock localities (Ilimaussaq, Greenland; Pocos de Caldas, Brazil; and Powderhorn, Colorado) were made to establish criteria to determine if a site had some uranium resource potential. From the literature, four alkaline-intrusive occurrences of differing character were identified as type-localities for uranium mineralization, and the important aspects of these localities were described. These characteristics were used to categorize and evaluate U.S. occurrences. The literature search disclosed 69 U.S. sites, encompassing nepheline syenite, alkaline granite, and carbonatite. It was possible to compare two-thirds of these sites to the type localities. A ranking system identified ten of the sites as most likely to have uranium resource potential.

  20. Juvenile helium in ancient rocks: II. U-He,K-Ar, Sm-Nd, and Rb-Sr systematics in the Monche Pluton. 3He/4He ratios frozen in uranium-free ultramafic rocks

    International Nuclear Information System (INIS)

    Tolstikhin, I.N.; Dokuchaeva, V.S.; Kamensky, I.L.; Amelin, Yu.V.

    1992-01-01

    The important geodynamic parameter, the 3 He/ 4 He ratio in rocks and fluids of the continental crust, is generally decreasing from the mantle values (≅ 10 -5 ) to the radiogenic ratio (≅ 10 -8 ) on the time scale of about 1 Ga or less. However, the ratios, observed in some ancient rocks and minerals, are much higher than the radiogenic value due to a preferential retention of trapped He, when compared with radiogenic helium and/or a low U/ 3 He ratio in a sample. The distribution of He, Ar, Nd, and Sr isotopes, K, Rb, Sm, and U in ultrabasic rocks, in rock-forming minerals, in ores from the 2.49 Ga Monche Pluton, and in basic rocks of the Main Range (the Kola Peninsula) enables one to distinguish sources of the rocks and trapped fluids and outline some peculiarities of petrogenetic and fluid processes. The initial values of var-epsilon Nd (T) = -0.9 ± 0.5 , 87 Sr/ 86 Sr(T) = 0.7021 ± 0.0002, for the 2.49 Ga Monche Pluton are rather similar to these for other layered intrusions of the Baltic Shield. They differ considerably from the model values for the depleted 2.5 Ga old mantle. The observed and rather different sources of 3 He and 4 He as well as the considerable constancy of their ratio in different minerals, separated from both the ultramafic rocks and gabbros, implies: (1) an intensive process of mixing between mantle and crustal components: a melt convection in the chamber may have occurred; (2) the two types of rocks could originate by crystallization differentiation of one and the same melt. Practically all 3 He and 4 He are concentrated in secondary amphiboles; hence the fluid which stimulated the metamorphic process was probably released from the ultramafite-bearing melt

  1. Radioactive sources of main radiological concern in the Kola-Barents region

    International Nuclear Information System (INIS)

    Bergman, R.; Baklanov, A.

    1998-07-01

    This overview focuses on some major issues for risk analysis appearing in our recent study surveying radioactive sources on the Kola Peninsula, along with adjacent parts of the Arctic seas. The main issues of the parts are as follows: An introduction to the presence of radioactive sources and environmental contamination in the Barents Euro-Arctic Region and the current status as regards various significant studies. Radioactive contamination in man and the environment on the Kola Peninsula, as well as radioactive transfer during the last three decades from external sources to the Kola-Barents region. The main conclusion from the findings is that the contamination is generally relatively low and that neither the activity levels in samples of soil, vegetation, and the important food-chains, nor the content in man indicate any changes since 1986 that could not be explained by the combined effect of the cumulative deposition from the nuclear weapons testing and the accident in Chernobyl. The radioactive sources of main concern in the region belong to the following categories: nuclear power submarine and cruiser naval bases; civil nuclear power ice-breaker fleet; building and repairing shipyards; nuclear power plants; radioactive waste and spent nuclear fuel storage facilities; sunken reactors/ships; liquid radioactive waste dumping; solid radioactive waste dumping; nuclear weapon bases; nuclear weapon tests; civil nuclear explosions; nuclear accidents; mining radioactive ore deposits and plants; new projects and others. Several case studies concerning releases in the Kola-Barents region are reviewed, and followed by consequence analyses for the categories of primary interest covering: a) airborne releases from the Kola NPP, and from submarines or spent nuclear fuel; b) releases from objects in the marine environment including submarines, dumped reactors, and various other radioactive objects and waste; c) releases from liquid and solid wastes stored on land or during

  2. Radioactive sources of main radiological concern in the Kola-Barents region

    Energy Technology Data Exchange (ETDEWEB)

    Bergman, R.; Baklanov, A

    1998-07-01

    This overview focuses on some major issues for risk analysis appearing in our recent study surveying radioactive sources on the Kola Peninsula, along with adjacent parts of the Arctic seas. The main issues of the parts are as follows: An introduction to the presence of radioactive sources and environmental contamination in the Barents Euro-Arctic Region and the current status as regards various significant studies. Radioactive contamination in man and the environment on the Kola Peninsula, as well as radioactive transfer during the last three decades from external sources to the Kola-Barents region. The main conclusion from the findings is that the contamination is generally relatively low and that neither the activity levels in samples of soil, vegetation, and the important food-chains, nor the content in man indicate any changes since 1986 that could not be explained by the combined effect of the cumulative deposition from the nuclear weapons testing and the accident in Chernobyl. The radioactive sources of main concern in the region belong to the following categories: nuclear power submarine and cruiser naval bases; civil nuclear power ice-breaker fleet; building and repairing shipyards; nuclear power plants; radioactive waste and spent nuclear fuel storage facilities; sunken reactors/ships; liquid radioactive waste dumping; solid radioactive waste dumping; nuclear weapon bases; nuclear weapon tests; civil nuclear explosions; nuclear accidents; mining radioactive ore deposits and plants; new projects and others. Several case studies concerning releases in the Kola-Barents region are reviewed, and followed by consequence analyses for the categories of primary interest covering: a) airborne releases from the Kola NPP, and from submarines or spent nuclear fuel; b) releases from objects in the marine environment including submarines, dumped reactors, and various other radioactive objects and waste; c) releases from liquid and solid wastes stored on land or during

  3. Assessment of the uncertainty and the proficiency test for accrediting KOLAS of ISO 17025 for a neutron radiography facility

    International Nuclear Information System (INIS)

    Oh, H.; Sim, C.M.; Lim, I.C.; Hong, K.P.; Choi, B.H.

    2004-01-01

    KOLAS(Korea of Lab Accreditation Scheme) is the charter member of ILAS (International Lab Accreditation Scheme) and APLAS (Asia Pacific Lab Accreditation Scheme), which originates from ISO 17025. KATS (Korea Agent of Technology Standard) governs the KOLAS. The KOLAS describes the basis of satisfying those issues related to a quality assurance and management system. The requirements specify an organization, the accommodation and environmental conditions, an uncertainty in the measurement and an inter-laboratory comparison or proficiency test program. The evaluation process of the requirements of certifying KOLAS for HANARO NRF has been proceeded by a neutron radiography laboratory, NRT level II course of SNT-TC-1A II is opened, with 20 persons attending for certification. An inter-laboratory comparison or proficiency test program is conducted through with Kyoto University in accordance with ASTM method for determining the imaging quality in direct thermal neutron radiographic testing (E545-91). In order to determine the uncertainty, dimensional measurements for the calibration fuel pin of the RISO using a profile project is performed with the ASTM practice for thermal neutron radiography of materials (E748-95) (orig.)

  4. Les granitoïdes néoprotérozoïques de Khzama, Anti-Atlas central, Maroc: marqueurs de l'évolution d'un magmatisme d'arc à un magmatisme alcalineNeoproterozoic granitoids from Khzama, central Anti-Atlas, Morocco: evolution markers from arc magmatism to alkaline magmatism

    Science.gov (United States)

    El-Khanchaoui, T.; Lahmam, M.; El-Boukhari, A.; El-Beraaouz, H.

    2001-05-01

    Petrological study and zircon typology provide important information that is related to the classification and genesis of Neoproterozoic granitoids in the Khzama area (northeast Siroua). The Pan-African granitoids show a transition from island-arc magmatism to alkaline magmatism. A space and time zonation of magmatism from the north to the south is evident. Early Pan-African granitoids were generated from various magma sources through different petrogenetic mechanisms. The first association corresponds to the low-K calc-alkaline plutons of Ait Nebdas, the second one correponds to high-K calc-alkaline post-collisional granites (Tamassirte-Tiferatine and Ifouachguel). Finally, shoshonitic magmatism (Irhiri) ends the magmatic evolution of the region. Thus, the late Pan-African granitic plutonism began with calc-alkaline associations and ended with K-alkaline magmatism in a transtensional setting, heralding the onset of the Moroccan Palæozoic cycle.

  5. Rb-Sr isochronous age of Vepor pluton granitoids

    International Nuclear Information System (INIS)

    Bagdasaryan, G.P.; Gykasyan, R.Kh.; Cambel, B.

    1986-01-01

    The result are presented of geochronological investigations of the Vepor pluton granitoids by the Rb-Sr isochronous method. The results prove the Variscan age of granodiorite magmatism of the Sihla type (387±27 m.y.) and the Early Variscan age of leucocratic granitoids of the Vepor and the Ipel types (284±22 m.y.). Since the initial ratio of 87 Sr/ 86 Sr in granitoids of the Sihla type is 0.7054 and of the Vepor type 0.7060, it can be assumed that during the formation of the granitoids of veporides there was an increased supply of matter from the main source affecting genesis of granitoids. The results prove a polyphase character of the Variscan granitoids of Veporicum. (author)

  6. Plutonic rocks of the Median Batholith in southwest Fiordland, New Zealand : field relations, geochemistry, and correlation

    International Nuclear Information System (INIS)

    Allibone, A.H.; Turnbull, I.M.; Tulloch, A.J.; Cooper, A.F.

    2007-01-01

    This paper provides a first description of all major plutonic rock units between Resolution Island and Lake Poteriteri in southwest Fiordland. Plutonic rocks, of which c. 95% are granitoids, comprise c. 60% of the basement in southwest Fiordland. Approximately 50% of the plutonic rocks were emplaced between c. 355 and 348 Ma, 5% at c. 164 Ma, 25% between c. 140 and 125 Ma, and 20% between c. 125 and 110 Ma. These episodes of plutonism occurred in response to terrane amalgamation, continental thickening, and subduction along the convergent margin of Gondwana. Correlatives of Devonian plutonic rocks which occur in Nelson are absent from the area described here. A wide variety of plutonic rocks were emplaced at c. 355-348 Ma. These include relatively small plutons of K- and Rb-rich gabbro-diorite and members of at least three distinct suites of granitoids. Plutons of two-mica ± garnet granodiorite, granite, and minor tonalite share affinities with the S-type Ridge Suite and are the most widespread c. 355-348 Ma old granitoids in southern Fiordland. Plutons rich in Ca, Fe and Zr, depleted in K and Na, and containing quartz diorite, tonalite, and minor granodiorite with the unusual assemblage red-brown biotite, garnet ± hornblende ± clinopyroxene also occur widely in southern Fiordland. These plutons are similar to peraluminous A-type granitoids, indicating A as well as I and S-type plutonism occurred in the Western Province at this time. The Newton River and Mt Evans Plutons have no correlatives amongst c. 355-348 Ma granitoids in southern Fiordland, but their chemistry is similar to that of the older Karamea Suite. Three regional-scale metasedimentary units - locally fossiliferous Fanny Bay Group Buller Terrane rocks in southern Fiordland, Edgecumbe and Cameron Group Takaka Terrane rocks in south-central Fiordland, and undifferentiated Deep Cove Gneiss high-grade metasedimentary rocks of western Fiordland - are all stitched by c. 355-348 Ma old plutons, indicating

  7. High-18O granitic plutons from the Frontenac Axis, Grenville Province of Ontario, Canada

    International Nuclear Information System (INIS)

    Shieh, Y.-N.

    1985-01-01

    18 O/ 16 O ratios have been determined for whole rock as well as coexisting minerals from nine syn- to post-tectonic monzonite and quartz monzonite plutons in the Westport-Gananoque area covering approximately 2500 km 2 . The plutons fall into two distinct isotopic groups: (I) Low- 18 O group: Rideau Lake, Westport, and Wolfe Lake plutons and (II) High- 18 O group: Lyndhurst, Perth Road, Battersea, Gananoque, South Lake and Crow Lake plutons. The 18 O/ 16 O ratios of granitic rocks from the latter group are among the highest ever reported in the literature. The isotopic compositions of samples within each pluton bear no relationship to the sample distance from the intrusive contacts nor are they affected by the types of country rocks into which they are emplaced. Oxygen isotope fractionations among coexisting quartz, feldspar, biotite and magnetite all show normal plutonic values. Thus, all lines of evidence suggest that the monzonite and quartz monzonite plutons did not acquire their characteristic 18 O/ 16 O ratios at the present level of exposure, either by isotopic exchange with the surrounding metasedimentary country rocks or by any post-crystallization low-temperature alteration processes. The results are discussed. (author)

  8. Cretaceous plutonic rocks in the Donner Lake-Cisco Grove area, northern Sierra Nevada, California

    Science.gov (United States)

    Kulow, Matthew J.; Hanson, Richard E.; Girty, Gary H.; Girty, Melissa S.; Harwood, David S.

    1998-01-01

    The northernmost occurrences of extensive, glaciated exposures of the Sierra Nevada batholith occur in the Donner Lake-Cisco Grove area of the northern Sierra Nevada. The plutonic rocks in this area, which are termed here the Castle Valley plutonic assemblage, crop out over an area of 225 km2 and for the most part are shown as a single undifferentiated mass on previously published geological maps. In the present work, the plutonic assemblage is divided into eight separate intrusive units or lithodemes, two of which each consist of two separate plutons. Compositions are dominantly granodiorite and tonalite, but diorite and granite form small plutons in places. Spectacular examples of comb layering and orbicular texture occur in the diorites. U-Pb zircon ages have been obtained for all but one of the main units and range from ~120 to 114 Ma, indicating that the entire assemblage was emplaced in a narrow time frame in the Early Cretaceous. This is consistent with abundant field evidence that many of the individual phases were intruded penecontemporaneously. The timing of emplacement correlates with onset of major Cretaceous plutonism in the main part of the Sierra Nevada batholith farther south. The emplacement ages also are similar to isotopic ages for gold-quartz mineralization in the Sierran foothills west of the study area, suggesting a direct genetic relationship between the voluminous Early Cretaceous plutonism and hydrothermal gold mineralization.

  9. An Archean Geomagnetic Reversal in the Kaap Valley Pluton, South Africa

    Science.gov (United States)

    Layer; Kroner; McWilliams

    1996-08-16

    The Kaap Valley pluton in South Africa is a tonalite intrusion associated with the Archean Barberton Greenstone Belt. Antipodal paleomagnetic directions determined from the central and marginal parts of the pluton record a geomagnetic reversal that occurred as the pluton cooled. The age of the reversal is constrained by an 40Ar/39Ar plateau age from hornblende at 3214 +/- 4 million years, making it the oldest known reversal. The data presented here suggest that Earth has had a reversing, perhaps dipolar, magnetic field since at least 3.2 billion years ago.

  10. Oster pluton (Central Karelia) - the ancient massif of two-feldspar granites of Baltic Shield

    International Nuclear Information System (INIS)

    Kovalenko, A.V.; Rizvanova, N.G.

    2000-01-01

    Geochronological study of two-feldspar granites forming the Oster pluton in the Central Karelia was performed using the methods of U-Pb- and Sm-Nd-dating. U-Pb isotope data for zircons from granite of the Oster pluton correspond to the age of 2876±21 mln. years, whereas Sm-Nd isotope data obtained for three samples of the garnet correspond to the age varying from 3.0 to 3.5 bln. years. The ancient age of granites of the Oster pluton is explained by the presence of a sufficiently powerful crust in the region by that moment [ru

  11. Reconnaissance geochemical exploration of plutons of syenite and shonkinite, southern Asir, Kingdom of Saudi Arabia

    Science.gov (United States)

    Overstreet, W.C.; Assegaff, A.B.; Hussain, M.A.; Naqvi, M.I.; Selner, G.I.; Matzko, J.J.

    1985-01-01

    Reconnaissance geochemical exploration for rare metals in plutons of syenite and shonkinite disclosed generally less than 20 ppm Nb in rocks, wadi sediments, and concentrates. The sparsity of Nb is accompanied by low values for La, Sn, W, Y, and Zr and relatively high but insignificant values for Be and Mo. Base and precious metals are either below their respective limits of determination in the various sample media or are present at background levels commensurate with average crustal abundances in felsic rocks. Pegmatite dikes associated with the syenite plutons are rare and lack vermiculite. The present investigation disclosed no possible ore deposits in the plutons covered by the field work.

  12. ABCGheritage project - promoting geotourism in northern Finland, northern Norway and the Kola Peninsula

    Science.gov (United States)

    Pihlaja, Jouni; Johansson, Peter; Lauri, Laura S.

    2014-05-01

    Nature tourism has been a growing business sector in the Barents area during the recent decades. With the purpose to develop nature tourism in a sustainable way, a cooperation project ABCGheritage - Arctic Biological, Cultural and Geological Heritage has been carried out. Project has received partial funding from the EU Kolarctic ENPI program. In the geoheritage part of the project the main activities were aimed to develop pro-environmental ways of geotourism in the area. The three main participants in the geoheritage part of the project are the Geological Survey of Finland, Northern Finland Office, the Geological Institute of the Kola Science Centre of the Russian Academy of Sciences and Bioforsk Soil and Environment from northeastern Norway. The duration of the project is 2012-2014 and most of the work has already been completed even if most of the results are not published yet. Totally ten different tasks have been implemented in the geological part of the project. The largest task has been the preparation of a geological outdoor map and guide book of the Khibiny Tundra locating in the central part of the Kola Peninsula. In Finland already 11 such maps have been published, and the experiences gained during their production have been used in this project, too. Geological heritage trails to the Khibiny Tundra have also been created and they will be drawn on the map. The second concrete result is the Barents Tour for Geotourist -guide, which will be published as a guide book, web pages and an exhibition. The route comprises ca 35 best geological demonstration sites along the circle route from northern Finland to northeastern Norway, from there to Kola Peninsula and then back to Finland. Information of the route will be available for all interested travelers. In addition to the geological outdoor map of the Khibiny Tundra and "Barents Tour for Geotourists"-guide, the primary outputs of the project are the geological nature trails on the field, geological

  13. Alkaline earth metals

    International Nuclear Information System (INIS)

    Brown, Paul L.; Ekberg, Christian

    2016-01-01

    The beryllium ion has a relatively small ionic radius. As a consequence of this small size, its hydrolysis reactions begin to occur at a relatively low pH. To determine the stability and solubility constants, however, the Gibbs energy of the beryllium ion is required. In aqueous solution calcium, like the other alkaline earth metals, only exists as a divalent cation. The size of the alkaline earth cations increases with increasing atomic number, and the calcium ion is bigger than the magnesium ion. The hydrolysis of barium(II) is weaker than that of strontium(II) and also occurs in quite alkaline pH solutions, and similarly, only the species barium hydroxide has been detected. There is only a single experimental study on the hydrolysis of radium. As with the stability constant trend, it would be expected that the enthalpy of radium would be lower than that of barium due to the larger ionic radius.

  14. Advanced alkaline water electrolysis

    International Nuclear Information System (INIS)

    Marini, Stefania; Salvi, Paolo; Nelli, Paolo; Pesenti, Rachele; Villa, Marco; Berrettoni, Mario; Zangari, Giovanni; Kiros, Yohannes

    2012-01-01

    A short review on the fundamental and technological issues relevant to water electrolysis in alkaline and proton exchange membrane (PEM) devices is given. Due to price and limited availability of the platinum group metal (PGM) catalysts they currently employ, PEM electrolyzers have scant possibilities of being employed in large-scale hydrogen production. The importance and recent advancements in the development of catalysts without PGMs are poised to benefit more the field of alkaline electrolysis rather than that of PEM devices. This paper presents our original data which demonstrate that an advanced alkaline electrolyzer with performances rivaling those of PEM electrolyzers can be made without PGM and with catalysts of high stability and durability. Studies on the advantages/limitations of electrolyzers with different architectures do show how a judicious application of pressure differentials in a recirculating electrolyte scheme helps reduce mass transport limitations, increasing efficiency and power density.

  15. The primary circuit materials properties results analysis performed on archive material used in NPP V-1 and Kola NPP Units 1 and 2

    Energy Technology Data Exchange (ETDEWEB)

    Kupca, L.; Beno, P. [Nuclear Power Plants Research Institute Inc., Trnava (Slovakia)

    1997-04-01

    A very brief summary is provided of a primary circuit piping material properties analysis. The analysis was performed for the Bohunice V-1 reactor and the Kola-1 and -2 reactors. Assessment was performed on Bohunice V-1 archive materials and primary piping material cut from the Kola units after 100,000 hours of operation. Main research program tasks included analysis of mechanical properties, corrosion stability, and microstructural properties. Analysis results are not provided.

  16. Fractures and fracture infillings of the Eye-Dashwa Lakes pluton, Atikokan, Ontario

    International Nuclear Information System (INIS)

    Stone, Denver; Kamineni, D.C.

    1982-01-01

    Fractures in the Eye-Dashwa pluton near Atikokan, Ontario can be subdivided on the basis of their filling materials. These materials include aplite, epidote, chlorite, and gypsum-carbonate-clay, listed in order of decreasing age established from crosscutting relations. Textues indicate that infilling occurred during fracture growth. Continuous cooling of the pluton during fracturing is inferred from the expected crystallization temperatures of fillings. Fracturing began before the pluton was completely solidified (650-600 0 C) and continued to temperatures below 100 0 C. Many fractures appear to have been sealed by the filling materials after initiation but were subsequently sheared and filled by lower temperatue materials. Apparently the majority of fractures formed during or immediately after pluton solidification and new fractures became smaller and more restricted in location as cooling progressed. Fractures and filling materials are seen as important features in assessing the possibility of movement of radionuclides in aqueous solutions away from a nuclear fuel waste repository

  17. Geochemical and chronological characteristics of Xiangcaoping granite pluton in Miaoershan area

    International Nuclear Information System (INIS)

    Li Wuwei; Wang Gan; Chen Weifeng; Zhao Kuidong

    2010-01-01

    Xiangcaoping granite pluton is mainly composed of medium-macro grain porphyritic biotite. The age of signle zircon dated by SHRIMP U-Pb is 211 ± 2 Ma, which suggest s that this pluton was formed during Indosinan. The geochemical characteristics is A > CNK, trace elements spider chart is slightly oblique to the right, enriched in LREE and bears obvious negative Eu anomaly which is similar to that of the S-type granite in South China. High ("8"7Sr/"8"6Sr)_i and low ε_N_d (t) suggest that this pluton was derived from partial melting of middle maturity Precambrian basement rock, which was rich in uranium and had supplied enough U element to the formation of Xiangcaoping granite pluton. (authors)

  18. Iron variation within a granitic pluton as determined by near-infrared reflectance

    Science.gov (United States)

    Baird, A. K.

    1984-01-01

    One-hundred fifty-one previously chemically analyzed samples of tonalite from the Lakeview Mountains pluton, southern California batholith, were analyzed for their iron content using near-infrared spectrophotometry. Compared to the earlier analyses of the same sample set by X-ray fluorescence spectrography, the infrared data have higher analytical variance but clearly define patterns of compositional zonation in the pluton which are closely similar to those patterns obtained from X-ray data; petrogenetic interpretations for the pluton would be the same from either data set. Infrared spectral data can be obtained directly in the field with relatively simple instruments and field measurements can be made to average local heterogeneities that often mask significant plutonic variations.

  19. Bedrock geologic map of the Knox Mountain pluton area, Marshfield and Peacham, Vermont

    Data.gov (United States)

    Vermont Center for Geographic Information — Digital Data from VG08-3 Kim, J., Charnock, R., Chow, D. and Springston, G., 2008, Bedrock geologic map of the Knox Mountain pluton area, Marshfield and Peacham,...

  20. A review on the nomenclature of Angadimogar and Kumbdaje plutons, Kasaragod district, Kerala

    Digital Repository Service at National Institute of Oceanography (India)

    AnilKumar, A.; Gopinathan, V.; Gopinath, K.S.; Rao, V.P.

    These granites are coarse grained and traversed by anastomising patches of aplite They are in sharp contact with the country rock The Angadimogar pluton was earlier considered a syenitic body Normative mineralogy and petrography of the Angadimogar and Kumbdaje...

  1. Paleomagnetism of Devonian dykes in the northern Kola Peninsula and its bearing on the apparent polar wander path of Baltica in the Precambrian

    Science.gov (United States)

    Veselovskiy, Roman V.; Bazhenov, Mikhail L.; Arzamastsev, Andrey A.

    2016-04-01

    Mafic dykes and large alkaline and carbonatite intrusions of Middle-Late Devonian age are widespread on the Kola Peninsula in NE Fennoscandia. These magmatic rocks are well characterized with petrographic, geochemical and geochronological data but no paleomagnetic results have been reported yet. We studied dolerite dykes from the northern part of the Peninsula and isolated three paleomagnetic components in these rocks. A low-temperature component is aligned along the present-day field, while a major constituent of natural remanent magnetization is an intermediate-temperature component (Decl. = 79.6°, Inc. = 78.5°, α95 = 5,9°, N = 17 sites) that is present in most Devonian dykes but is found in some baked metamorphic rocks and Proterozoic dykes too. Finally, a primary Devonian component could be reliably isolated from two dykes only. Rock-magnetic studies point to presumably primary low-Ti titanomagnetite and/or pure magnetite as the main remanence carriers but also reveal alteration of the primary minerals and the formation of new magnetic phases. The directions of a major component differ from the Middle Paleozoic reference data for Baltica but closely match those for the 190 ± 10 Ma interval recalculated from the apparent polar wander path of the craton. We assume that this Early Jurassic component is a low-temperature overprint of chemical origin. The main impact of the new results is not to mid-Paleozoic or Early Mesozoic times but to much older epochs. Analysis of paleomagnetic data shows that the directionally similar remanences are present in objects with the ages ranging from 500 Ma to 2 Ga over entire Fennoscandia. Hence we argue that an Early Jurassic remagnetization is of regional extent but cannot link it to a certain process and a certain tectonic event. If true, this hypothesis necessitates a major revision of the APWP for Baltica over a wide time interval.

  2. Alternative technologies for remediation of technogenic barrens in the Kola Subarctic

    Science.gov (United States)

    Koptsik, G. N.; Koptsik, S. V.; Smirnova, I. E.

    2016-11-01

    The efficiency of remediation of technogenic barrens under the reduction of air pollutant emissions from the Severonikel smelter in the Kola Subarctic is determined largely by the soil state and the technology applied. The covering of the contaminated soils with artificially made material based on organomineral substrates and the following liming and fertilization promoted a sharp and long-term reduction of acidity, decrease in the biological availability of heavy metals, increase in the supply with nutrients, and improvement of the life state of willow and birch plantations. The effect of economically more profitable chemo-phytostabilization is short-term; it requires constant maintenance. Under the current production and a high level of soil contamination, repeated measures are required to optimize the soil reaction, supply with nutrients, and to correct the availability of heavy metals in the soils based on the results of continuous monitoring

  3. Efficiency of remediation of technogenic barrens around the Pechenganikel works in the Kola Subarctic

    Science.gov (United States)

    Koptsik, G. N.; Koptsik, S. V.; Smirnova, I. E.

    2014-05-01

    Remediation of the technogenic barrens around the Pechenganikel works on the Kola Peninsula resulted in the improvement of the soil properties, namely, in a decrease in acidity and enrichment with nutrients, which continued for several years. However, the reaction of most of the treated soils remained strongly acid, and the concentrations of available calcium, magnesium, potassium, and phosphorus were much lower than their background levels and the demands of the plants for nutrients (especially, for magnesium and potassium). The soils were depleted in available manganese and zinc. Most of the treated soils contained the same (or higher) amounts of available nickel and copper compounds in comparison with their untreated analogues. The willow plantations on the remediated plots were in a satisfactory state, but they experienced a deficit of magnesium, manganese, and zinc; they consumed elevated amounts of nickel and copper. Recommendations on the nutrient regime of the soils aimed at decreasing the mobility and biological availability of heavy metals were made.

  4. Results of complex annual parasitological monitoring in the coastal area of Kola Bay

    Science.gov (United States)

    Kuklin, V. V.; Kuklina, M. M.; Kisova, N. E.; Maslich, M. A.

    2009-12-01

    The results of annual parasitological monitoring in the coastal area near the Abram-mys (Kola Bay, Barents Sea) are presented. The studies were performed in 2006-2007 and included complex examination of the intermediate hosts (mollusks and crustaceans) and definitive hosts (marine fish and birds) of the helminths. The biodiversity of the parasite fauna, seasonal dynamics, and functioning patterns of the parasite systems were investigated. The basic regularities in parasite circulation were assessed in relation to their life cycle strategies and the ecological features of the intermediate and definitive hosts. The factors affecting the success of parasite circulation in the coastal ecosystems were revealed through analysis of parasite biodiversity and abundance dynamics.

  5. Intermediate storage of radioactive waste and spent nuclear fuel at the Kola Peninsula

    International Nuclear Information System (INIS)

    Bohmer, N.

    1999-01-01

    The problem of nuclear waste and disused nuclear submarines are a product of the arms race and the Cold War. Russia still continues to build new nuclear submarines, but there are very few provisions being made to properly store old nuclear submarines, and develop sufficient storage facilities for spent nuclear fuel and other radioactive waste. A solution to this problem is proposed: to construct a new regional interim storage facilities at Kola for the spent nuclear fuel instead of transporting it to Mayak, the existing reprocessing plant. This storage should have the capacity to handle the fuel in the existing storage and the fuel still on board of retired nuclear submarines. Its lifetime should be 50 years. later it would be possible to make a decision on the future of this fuel

  6. Trace elements in bottom sediments of the Barents Sea on the standard section "Kola Meridian"

    Directory of Open Access Journals (Sweden)

    Lapteva A. M.

    2017-03-01

    Full Text Available The levels of trace metals (Cu, Zn, Ni, Cr, Mn, Co, Pb, Cd, Hg and arsenic (As in samples of bottom sediments from the Barents Sea on eight stations of the standard section "Kola Meridian" have been investigated. Trace elements have been determined on atomic absorption spectrophotometer AA-6800 with mercury-hydride attachment HVG-1 of the company Shimadzu (Japan by the methods of flaming (acetylene – air and electrothermal atomization. Common and very toxic trace elements include Pb, Cd, As, and Hg. It is believed that 90 % of lead, 70–80 % of cadmium, and arsenic, over 30 % of mercury in the atmosphere are of anthropogenic origin, and emissions of these elements in the atmosphere are almost completely manufactured in the Northern Hemisphere. The main sources of income in the Barents Sea are waters of the North Atlantic current and the large-scale atmospheric transport from industrialized Central Europe. As a rule the spatial distribution of trace elements is in good agreement with the granulometric composition of bottom sediments and the content of organic carbon. The contents of most of the listed trace elements in samples of bottom sediments on the standard section "Kola Meridian" in the Norwegian classification are consistent with background levels with the exception of Ni, Cr, and As. Their content in bottom sediments at some stations has met the criteria for "slight" and "moderate" pollution. The obtained results confirm the insignificant levels of contamination of bottom sediments of some trace elements. On the status of stocks of commercial species of aquatic biological resources, the observed levels of contamination of bottom sediments in the investigated areas of the Barents Sea will have no significant effect

  7. Anthropogenic radionuclides in Kola and Motovsky Bays of the Barents Sea, Russia

    International Nuclear Information System (INIS)

    Matishov, G.G.; Matishov, D.G.; Namjatov, A.A.; Carroll, J.; Dahle, S.

    1999-01-01

    Russia's military and civilian nuclear powered maritime fleets operate in the Kola and Motovsky Bays on the northwest Arctic coast of Russia. Levels of anthropogenic radionuclides were measured in sediment grab samples collected from approximately 100 stations in areas near military and civilian nuclear installations and in the open waters of the two bays. In most areas, radionuclide levels are similar to those reported for other Arctic seas: 137 Cs=1-24 Bq kg -1 d.w., 60 Co= -1 d.w. and 239,240 Pu=0.8-1.6 Bq kg -1 d.w. However, the presence of 60 Co (up to 27 Bq kg -1 d.w.) indicates that minor leakage of radioactive waste has occurred near several military installations. Sites where leakage is detected include Pala, Sayda, Olenya and Ekaterininskaya Bays in the Kola Bay and Zapadnaya Litsa in Motovsky Bay. 137 Cs levels of 40-50 Bq kg -1 d.w. and 239,240 Pu levels of up to 2.2 Bq kg -1 d.w. were measured near several military installations but these levels do not indicate leakage as the source.Some of the highest 60 Co activities were detected in sediments collected near the civilian nuclear installation, Atomflot. The sediments also contained higher 137 Cs activities compared to samples from other regions of the study area with similar particle size distributions. Routine discharges of purified radioactive waste from the Atomflot facility are the likely source of 60 Co and enhanced 137 Cs levels. With this investigation, we have detected evidence of radioactive waste leakage in the marine environment, but the environmental impact on the bays has been minimal. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

  8. Searching pristine source of two gabbric plutons outcroping in Central Sierras Pampeanas Range, Argentina

    International Nuclear Information System (INIS)

    Daziano, C.; Ayala, R.

    2010-01-01

    This work is about the study of two gabbric plutons outcrop ing throughout Central Sierras Pampeanas range (Cordoba province, Argentina). San Lorenzo hill gabbric plutons is in the Upper proterozoic age whereas Cañada del Puerto belongs to the Early proterozoic.They are stock-type igneous bodies and they are intrusive s in an Upper Precambrian crystalline basement; it is mainly composed by gneisses, migmatites, schistes, marbles, amphibolite s, tact's, serpentinites and related rocks

  9. Petrology and Geochemistry of Neoproterozoic Arc Plutons Beneath the Atlantic Coastal Plain, SRS, SC

    Energy Technology Data Exchange (ETDEWEB)

    Maryak, M.

    1998-10-21

    In this report is presented first a brief review of the regional geologic setting of the Savannah River Site, descriptions of the plutonic rock units sampled here, whole rock geochemical data on the plutonic igneous rocks, and finally, a discussion of how the crystalline basement rocks of the Savannah River Site formed and how they may correlate with other terranes exposed in the Piedmont of the Carolinas, Georgia, and Virginia.

  10. Research on the age and origin of Hongshan pluton in north Guangdong

    International Nuclear Information System (INIS)

    Zhu Ba; Deng Peng; Ling Hongfei; Shen Weizhou; Tan Zhengzhong

    2009-01-01

    Located in the midwest of south Zhuguangshan composite pluton, Hongshan pluton is constituted by biotite granite and two-micro granite. The SHRIMP U-Pb age of zircons from the pluton is 155±2 Ma, which belongs to Yanshanian. Hongshan pluton is rich in silicon (SiO 2 =76.08%∼77.25%) and alkali(K 2 O+Na 2 O=8.78%∼9.43%), low in ACNK value (0.94∼1.07) and CaO/Na 2 O value (0.10∼0.19). In trace elements, the pluton is rich in Rb, Th, U, depleted in Ba, Sr, P, Ti and has high Rb/Sr (30.02∼930.9), Rb/Ba (18.91∼231.8), has low LREE/HREE value (1.99∼2.40) and remarkable Eu depletion (δEu=0.01∼0.07), has low Σ Nd (t) value (-10.2∼-12.0) and old Nd model age(1777∼1923 Ma). All the evidence indicate that it have the characteristic of S type granite. Hongshan pluton is believed to be formed by partial melting of protozoic rocks, which related to the reactivation of Qitianling-Zhuguangshan (east-west) fracture zones resulted from the subduction of Pacific plate. (authors)

  11. Geological, geochemical and isotopic characteristics of the Archaean Kaap Valley pluton, Barberton mountain land, South Africa

    International Nuclear Information System (INIS)

    Robb, L.J.; Barton, J.M. Jr.; Kable, E.J.D.; Wallace, R.C.

    1984-01-01

    The Kaap Valley pluton consists predominantly of a homogeneous weakly foliated, hornblende-bearing tonalite. It is among the oldest granitoid bodies yet recognized in the environs of the Barberton greenstone belt, yielding 207 Pb/ 206 Pb mineral ages of about 3300 Ma and a Rb-Sr whole rock isochron age of about 3500 Ma. The Kaap Valley pluton is distinctive in many respects. Whereas all other gneiss plutons in the area are characterized by a trondhjemitic bulk composition with mafic mineralogies dominated by biotite, the Kaap Valley pluton is tonalitic in bulk composition with hornblende (plus minus minor biotite) as its major mafic phase. In this paper, the results of a detailed geological, geochemical and Pb-isotopic study of the Kaap Valley pluton are presented. Questions relating to the origin of the body are considered, with an emphasis on the formation of a tonalitic magma which is more mafic than those typically encountered in the region. Although exposure does not permit a detailed structural study of the gneiss pluton consideration is given to its mode of emplacement

  12. Some geomorphological features of the Orhaneli Pluton: Implications for denudation history

    Directory of Open Access Journals (Sweden)

    Ahmet Evren ERGİNAL

    2008-12-01

    Full Text Available The granitic intrusions of the variable age of cooling, size and mineral composition are widely exposed in the northwest Anatolia, Turkey. The nearly circular Orhaneli Pluton emplaced during the Early Eocene with some 15 km in diameter, is one of such plutonic bodies. Geomorphological features of the pluton are discussed here with special emphasis given on the denudation history. To this end, evidence from two isolated Inselberglike hills as remnants of roof rocks in the centre of the pluton and episodically emergence of granite landforms of etch origin after unroofing process were investigated. Field data reveal the absence of granodiorite clasts within Early to Middle Miocene lacustrine deposits in the north of the pluton, implying that the pluton might not have been exposure prior to Upper Miocene as a whole. After the first exposure, the granite landforms, such as boulders, corestones and tors constituting sound evidence of an etch origin, became exposure by continual removing of regolith cover by surficial runoff. These forms of various scale were formed at first by subsurface weathering and shaped by surficial weathering processes after any stages of removal of the regolith cover. Drainage segments accounted for removal of regolith is mostly structurally controlled defined by NW-SE, NE-SW and N-S-aligned fracture systems.

  13. Thermal modeling of pluton emplacement and associated contact metamorphism:Parashi stock emplacement in the Serranía de Jarara (Alta Guajira, Colombia

    Directory of Open Access Journals (Sweden)

    Zuluaga C. Carlos A.

    2010-12-01

    Full Text Available

    In the northernmost portion of the Serrania de Jarara (Alta Guajira, Colombia, low - medium grade metamorphic rocks from the Etpana Metamorphic Suite were thermally affected by emplacement of a small calc-alkaline intrusion (Parashi Stock. Detailed petrographic analysis in collected rock samples across the NE and NW plutonic contacts show occurrences of textural and mineralogical changes in the country rock fabric that evidence contact metamorphism overprinting regional metamorphism of the Etpana Suite. These changes include growth of andalusite (chiastolite, calcic clinopyroxeneand amphibole porphyroblast crosscutting Sn+1 metamorphicfoliation. Hornblende-plagioclase barometry (ca. 3.1 kbar and cooling models for the stock show maximum time temperature evolution in the country rock at the interpreted depth of intrusion (ca. 11 km and help to evaluate the behavior of the country rock with the changing local geotherm.

  14. Zircon U–Pb–Hf isotopic and geochemical characteristics of the Xierzi biotite monzogranite pluton, Linxi, Inner Mongolia and its tectonic implications

    Directory of Open Access Journals (Sweden)

    Qing-Bin Guan

    2018-03-01

    Full Text Available The opening, subduction and final closure of the Paleo-Asian Ocean led to the formation of the Central Asian Orogenic Belt. Controversy has long surrounded the timing of final closure of the Paleo-Asian Ocean. Here we present zircon U–Pb ages and petrological, geochemical and in situ Hf isotope data for the Xierzi biotite monzogranite pluton, Linxi, SE Inner Mongolia. U–Pb dating of zircon by LA-ICP-MS yields a middle Permian emplacement age (268.7 ± 2.3 Ma for the Xierzi pluton that is dominated by biotite monzogranites with high SiO2 (71.2–72.8 wt.%, alkali (Na2O + K2O = 8.05–8.44 wt.%, Al2O3 (14.4–15.2 wt.% and Fe2O3T relative to low MgO contents, yielding Fe2O3T/MgO ratios of 2.87–3.44, and plotting within the high-K calc-alkaline field on a SiO2 vs. K2O diagram. The aluminum saturation indexes (A/CNK of the biotite monzogranites range from 1.06 to 1.19, corresponding to weakly to strongly peraluminous. They are enriched in rare earth elements (REE, high field strength elements (HFSEs; Zr, Hf, and large ion lithophile elements (LILEs; Rb, U, Th. The LREEs are enriched relative to the HREEs, with a distinct negative Eu anomaly in a chondrite–normalized REE diagram. Geochemically, the Xierzi biotite monzogranite is classified as an aluminous A-type granite, with all samples plotting within the A2-type granite field on a Y/Nb vs. Rb/Nb diagram. Zircon εHf(t values and two-stage modal ages of the zircons within the pluton range from +4.80 to +13.65 and from 983 to 418 Ma, respectively, indicating that the primary magma was generated through partial melting of felsic rocks from juvenile crust. Consequently, these results demonstrate that the Xierzi pluton formed under the post-orogenic extensional setting after arc–continent collision in the middle Permian.

  15. Petrotectonic characteristics, geochemistry, and U-Pb geochronology of Jurassic plutons in the Upper Magdalena Valley-Colombia: Implications on the evolution of magmatic arcs in the NW Andes

    Science.gov (United States)

    Rodríguez, G.; Arango, M. I.; Zapata, G.; Bermúdez, J. G.

    2018-01-01

    Field, petrographic, and geochemical characterization along with U-Pb zircon geochronology of the Jurassic plutons exposed in the Upper Magdalena Valley (Colombia) allowed recognizing distinct western and eastern suites formed in at least three magmatic pulses. The western plutons crop out between the eastern flank of the Central Cordillera and the Las Minas range, being limited by the Avirama and the Betania-El Agrado faults. The western suite comprises a quartz monzonite - quartz monzodiorite - quartz diorite series and subordinate monzogranites. Chemically, the rocks are high-K calc-alkaline I-type granitoids (some reaching the shoshonitic series) with metaluminous of magnesium affinity. Trace-element tectonic discrimination is consistent with magmatism in a continental arc environment. Most rocks of this suite crystallized between 195 and 186 Ma (Early Jurassic, Pliensbachian), but locally some plutons yielded younger ages between 182 and 179 Ma (Early Jurassic, Toarcian). The eastern suite crops out in the eastern margin of the Upper Magdalena Valley, east of the Betania - El Agrado fault. Plutons of this unit belong to the monzogranite series with rock types ranging between syenogranites and granodiorites. They are high-K calc-alkaline continental granitoids, some metaluminous and some peraluminous, related to I-type granites generated in a volcanic arc. Crystallization of the suite was between 173 and 169 Ma (Middle Jurassic, Aalenian-Bajocian), but locally these rocks contain zircon with earlier inherited ages related to the magmatic pulse of the western suite between 182 and 179 Ma (Early Jurassic, Toarcian). The evolution of the Jurassic plutons in the Upper Magdalena Valley is best explained by onset or increase in subduction erosion of the accretionary prism. This explains the eastward migration of the arc away from the trench. Subduction of prism sediments increased the water flux from the subducting slab, decreasing solidus temperatures, therefore

  16. Early Paleozoic dioritic and granitic plutons in the Eastern Tianshan Orogenic Belt, NW China: Constraints on the initiation of a magmatic arc in the southern Central Asian Orogenic Belt

    Science.gov (United States)

    Du, Long; Long, Xiaoping; Yuan, Chao; Zhang, Yunying; Huang, Zongying; Sun, Min; Zhao, Guochun; Xiao, Wenjiao

    2018-03-01

    Early Paleozoic dioritic and granitic plutons in the Eastern Tianshan Orogenic Belt (ETOB) have been studied in order to constraint the initiation of a magmatic arc formed in this region. Zircon U-Pb dating indicates that two dioritic plutons in the northern ETOB were generated in the Late Ordovician (452 ± 4 Ma) and the Early Silurian (442 ± 3 Ma), respectively. Diorites from the two plutons are characterized by enrichments in large ion lithophile elements (LILE) and highly incompatible elements, with depletions in high field strength elements (HSFE) displaying typical geochemical features of a subduction-related origin. They have positive εNd(t) values (+5.08-+6.58), relatively young Nd model ages (TDM = 0.71-1.08 Ga), with Ta/Yb (0.05-0.09) and Nb/Ta ratios (12.06-15.19) similar to those of depleted mantle, suggesting a juvenile mantle origin. Their high Ba/La (13.3-35.9), low Th/Yb (0.72-2.02), and relatively low Ce/Th (4.57-14.7) and Ba/Th (47.8-235) ratios indicate that these diorites were probably produced by partial melting of a depleted mantle wedge metasomatized by both subducted sediment-derived melts and slab-derived aqueous fluids. Zircon U-Pb dating of a granitic pluton in the northern ETOB yielded a Late Ordovician intrusion age of 447 ± 5 Ma. Granites from this pluton show calc-alkaline compositions with geochemical characteristics of I-type granites. They also show positive εNd(t) values (+6.49-+6.95) and young Nd model ages (TDM = 0.69-0.87 Ga), indicating that the granites were most likely derived from juvenile lower crust. Our new dating results on the dioritic and granitic plutons suggest that arc-type magmatism in the northern ETOB began prior to or at the Late Ordovician (452-442 Ma). In addition, north-dipping subduction of the Kangguertage oceanic lithosphere may account for the arc-type magmatism and the geodynamic process of the ETOB in the Early Paleozoic.

  17. Magnetic properties of ilmenite-hematite single crystals from the Ecstall pluton near Prince Rupert, British Columbia

    DEFF Research Database (Denmark)

    Brownlee, Sarah J.; Feinberg, Joshua M.; Kasama, Takeshi

    2011-01-01

    Paleomagnetic studies of the 91 Ma Ecstall pluton and other Cretaceous plutons of British Columbia imply large northward tectonic movements (>2000 km) may have occurred during the tectonic evolution of western North America. However, more recent studies have shown that the eastern edge...... of the Ecstall pluton experienced considerable mineralogical changes as younger Eocene plutons, such as the ∼58 Ma Quottoon Pluton, were emplaced along its margins. We investigated changes in the rock magnetic properties associated with this reheating event by examining isolated grains of intergrown ilmenite...... and hematite, the primary paleomagnetic recorder in the Ecstall pluton. Measurements of hysteresis properties, low-temperature remanence, and room temperature isothermal remanent magnetization acquisition and observations from magnetic force microscopy and off-axis electron holography indicate that samples...

  18. The U-Pb System in Schorlomite from Calcite-Amphobole-Pyroxene Pegmatite of the Afrikanda Complex (Kola Peninsula)

    Science.gov (United States)

    Salnikova, E. B.; Stifeeva, M. V.; Chakhmouradian, A. R.; Glebovitsky, V. A.; Reguir, E. P.

    2018-02-01

    The geochronological U-Pb study of shorlomite from igneous rocks of the alkali-ultramafic Afrikanda massif (Kola Peninsula) was performed. The results demonstrate the reliability of calcium garnet as a mineral for the U-Pb geochronology of a wide range of igneous rocks, i.e., carbonatite, syenite, foidolite, foidite, melilitolite, melilitite, lamprophyres, micaceous kimberlites, etc., and associated rare earth and trace elements (REE, Nb, Zr) mineralization.

  19. Constraints on the depth of generation and emplacement of a magmatic epidote-bearing quartz diorite pluton in the Coast Plutonic Complex, British Columbia

    Science.gov (United States)

    Chang, J.M.; Andronicos, C.L.

    2009-01-01

    Petrology and P-T estimates indicate that a magmatic epidote-bearing quartz diorite pluton from Mt. Gamsby, Coast Plutonic Complex, British Columbia, was sourced at pressures below ???1.4 GPa and cooled nearly isobarically at ???0.9 GPa. The P-T path indicates that the magma was within the stability field of magmatic epidote early and remained there upon final crystallization. The pluton formed and crystallized at depths greater than ???30 km. REE data indicate that garnet was absent in the melting region and did not fractionate during crystallization. This suggests that the crust was less than or equal to ???55 km thick at 188 Ma during the early phases of magmatism in the Coast Plutonic Complex. Late Cretaceous contractional deformation and early Tertiary extension exhumed the rocks to upper crustal levels. Textures of magmatic epidote and other magmatic phases, combined with REE data, can be important for constraining the P-T path followed by magmas. ?? 2009 Blackwell Publishing Ltd.

  20. Is there a geochemical link between volcanic and plutonic rocks in the Organ Mountains caldera?

    Science.gov (United States)

    Memeti, V.; Davidson, J.

    2013-12-01

    Results from separate volcanic and plutonic studies have led to inconsistent conclusions regarding the origins and thus links between volcanic and plutonic systems in continental arcs and the magmatic processes and time scales responsible for their compositional variations. Some have suggested that there is a geochemical and geochronological disconnect between volcanic and plutonic rocks and hence have questioned the existence of magma mush columns beneath active volcanoes. Investigating contemporary volcanic and plutonic rocks that are spatially connected is thus critical in exploring these issues. The ca. 36 Ma Organ Mountains caldera in New Mexico, USA, represents such a system exposing contemporaneous volcanic and plutonic rocks juxtaposed at the surface due to tilting during extensional tectonics along the Rio Grande Rift. Detailed geologic and structural mapping [1] and 40Ar/39Ar ages of both volcanics and plutons [2] demonstrate the spatial and temporal connection of both rock types with active magmatism over >2.5 myr. Three caldera-forming ignimbrites erupted within 600 kyr [2] from this system with a total erupted volume of 500-1,000 km3 as well as less voluminous pre- and post-caldera trachyte and andesite lavas. The ignimbrite sequence ranges from a crystal-poor, high-SiO2 rhyolite at the base to a more crystal-rich, low-SiO2 rhyolite at the top. Compositional zoning with quartz-monzonite at the base grading to syenite and alaskite at the top is also found in the Organ Needle pluton, the main intrusion, which is interpreted to be the source for the ignimbrites [1]. Other contemporaneous and slightly younger plutons have dioritic to leucogranitic compositions. We examined both volcanic and plutonic rocks with petrography and their textural variations with color cathodoluminescence, and used whole rock element and Sr, Nd and Pb isotope geochemistry to constrain magma compositions and origins. Electron microprobe analyses on feldspars have been completed to

  1. Geochemical characteristics and genesis of Baiyun pluton in southern Zhuguangshan mountain

    International Nuclear Information System (INIS)

    Zhang Shanguo; Huang Guolong; Fu Shuncheng; Wang Xiaodong; Xu Lili; Shen Weizhou

    2011-01-01

    Located in the east-central of the southern Zhuguangshan complex pluton, Baiyun pluton is an important uranium producing pluton. In lithology, it is coarse grain black mica granite. In major elements, the pluton is with rich silicon (SiO 2 average for 73.47%), rich aluminum (A/CNK value average 1.09) and high ratio of K 2 O/Na 2 O (average for 1.99). It is rich in large-ion trace elements Rb, Th, but poor in Ba, Sr, Ti, Nb, Ta, P. Rock samples have high Rb/Sr (average for 6.22) and Rb/ Nb ratio (average for 1.447), and rich uranium (average for 9.04 x 10 -6 ) which can act as the source for the formation of uranium deposit. In REE chemistry, the pluton is rich in LREE and relatively high fractionation between LREE and HREE, and bear the right-wing-type distribution pattern with obviously Eu depletion. In Isotopic chemistry,the pluton has low ε Nd (t) value(average for -10.6), high ( 87 Sr/ 86 Sr) i value (average for 0.71688), and old Nd mode age (1865∼1874 Ma). These characteristics consistently show that Baiyun pluton belongs to typical crustal source granite type and formed in an extensional tectonic environment shortly after the collision between South China and Indo-China plate from partial melting of argillaceous rocks in the middle-lower crust due to the comprehensive action of the decompression, water-prodution and mantle upwelling induced by crust stretching and thinning. (authors)

  2. Natural radioactivity levels in granitic plutons and groundwaters in Southeast part of Eskisehir, Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Oerguen, Y. [Faculty of Mines, Istanbul Technical University (ITU), Ayazaga Kampusu, 34469 Istanbul (Turkey)]. E-mail: orgun@itu.edu.tr; Altinsoy, N. [Institute of Energy, Istanbul Technical University (ITU), Ayazaga Kampusu, 34469 Istanbul (Turkey); Gueltekin, A.H. [Faculty of Mines, Istanbul Technical University (ITU), Ayazaga Kampusu, 34469 Istanbul (Turkey); Karahan, G. [Cekmece Nuclear Research and Training Center, P.O. Box 1, Atatuerk Airport, 34149 Istanbul (Turkey); Celebi, N. [Cekmece Nuclear Research and Training Center, P.O. Box 1, Atatuerk Airport, 34149 Istanbul (Turkey)

    2005-08-01

    The present work investigated the radioactivity level of the granitoid plutons and its effect on the groundwaters in the southeast part of Eskisehir. Fourteen granitic samples from the Kaymaz and Sivrihisar plutons and 11 groundwater samples from the near vicinity of the pluton were analyzed. The activity concentrations measured for {sup 238}U and {sup 232}Th ranged from 43.59{+-}2 to 651.80{+-}24 Bq/kg, and 51.16{+-}3 to 351.94{+-}13 Bq/kg, respectively. The activity concentrations obtained for {sup 40}K varied from 418.50{+-}17 to 1618.03{+-}66 Bq/kg. The absorbed dose rates in air outdoors ranged from 87.14 to 531.81 nGy/h. All the results obtained from the Kaymaz pluton are higher than those from the Sivrihisar. The U (ave. 16.6 ppm) and Th (ave. 49.9 ppm) values of the Kaymaz pluton are higher than the average concentrations of the magmatic rocks of granitic composition. These results are consistent with high dose rates of the pluton. The gross-{alpha} activities in the groundwater samples ranged from 0.009 to 1.64 Bq/l and the gross-{beta} activities from 0.006 to 0.89 Bq/l. The highest gross-{alpha} value was found in the sample taken from near the Kaymaz pluton. The concentrations of {sup 222}Rn varied from 0.060 to 0.557 Bq/l.

  3. LA-ICPMS zircon U-Pb age of Maofeng pluton of uranium deposit No.337 and its significance

    International Nuclear Information System (INIS)

    Zhang Zhanshi; Hua Renmin; Yao Junmin; Gu Shengyan; Deng Ping; Wu Lieqin

    2007-01-01

    Maofeng pluton is the most important uranium-host granite in Xiazhuang uranium orefield. The accurate granite formation age and its evolution history is crucial for understanding the mineralization in this district. LA-ICPMS zircon dating was applied in this paper and found the formation age of Maofeng pluton is 238.2 ± 2.3 Ma which suggests that Maofeng pluton was produced in the Indosinian magmatic event. Uranium mineralization age of No.337 deposit is commonly recognized to be 138 Ma. Therefore No.337 uranium deposit was not the typical magma hydrothermal deposit due to the long time gap between the pluton formation and the uranium mineralization. (authors)

  4. Evidence in Variscan Corsica of a brief and voluminous Late Carboniferous to Early Permian volcanic-plutonic event contemporaneous with a high-temperature/low-pressure metamorphic peak in the lower crust

    International Nuclear Information System (INIS)

    Rossi, Philippe; Cocherie, Alain; Fanning, C. Mark

    2015-01-01

    The U2 group of plutonic rocks constituting the main exposed part of the Corsica-Sardinia batholith (CSB) was emplaced from 308 to 275 Ma (the early Visean U1 group of Mg-K intrusions is not considered here). Field evidence earlier established volcanic-plutonic relationships in the U2 group of calc-alkaline intrusions of the CSB, though detailed chronological data were still lacking. Large outcrops of U2 volcanic formations are restricted to the less eroded zone north-west of the Porto-Ponte Leccia line in Corsica, but volcanic and volcano-sedimentary formations were widely eroded elsewhere since Permian times. They probably covered most of the batholith before the Miocene, as testified by the volcanic nature of the pebbles that form much of the Early Miocene conglomerates of eastern Corsica. U-Pb zircon dating (SHRIMP) was used for deciphering the chronology and duration of different volcanic pulses and for better estimating the time overlap between plutonic and volcanic rock emplacement in the CSB. The obtained ages fit well with field data, showing that most of the U2 and U3 volcanic formations were emplaced within a brief time span of roughly 15 m.y., from 293 to 278 Ma, coeval with most U2 monzo-granodiorites and leuco-monzo-granites (295-280 Ma), alkaline U3 complexes (about 288 Ma), and mafic-ultramafic tholeiitic complexes (295-275 Ma). The same chronological link between deep-seated magma chambers and eruptions was identified in the Pyrenees. These results correlate with U-Pb zircon dating of HT-LP granulites from the Variscan deep crust exhumed along the 'European' margin of the thinned Tethys margin in Corsica and Calabria. Here, the peak of the low-pressure/high-temperature metamorphism was dated at about 285-280 Ma. Our results throw light on the condition of magma production during the orogenic collapse in the southern Variscan realm. While juvenile tholeiitic basaltic magma was produced by the melting of spinel mantle lithosphere, all

  5. Oxygen and hydrogen isotope studies of plutonic granitic rocks

    International Nuclear Information System (INIS)

    Taylor, H.P. Jr.

    1978-01-01

    The primary deltaD values of the biotites and hornblendes in granitic batholiths are remarkably constant at about -50 to -85, identical to the values in regional metamorphic rocks, marine sediments and greenstones, and most weathering products in temperate climates. Therefore the primary water in these igneous rocks is probably not 'juvenile', but is ultimately derived by dehydration and/or partial melting of the lower crust or subducted lithosphere. Most granitic rocks have delta 18 O = +7.0 to +10.0, probably indicating significant involvment of high- 18 O metasedimentary or altered volcanic rocks in the melting process; such an origin is demanded for many other granodiorites and tonalites that have delta 18 O = +10 to +13. Gigantic meteoric-hydrothermal convective circulation systems were established in the epizonal portions of all batholiths, locally producing very low delta 18 O values (particularly in feldspars) during subsolidus exchange. Some granitic plutons in such environments also were emplaced as low- 18 O magmas probably formed by melting or assimilation of hydrothermally altered roof rocks. However, the water/rock ratios were typically low enough that over wide areas the only evidence for meteoric water exchange in the batholiths is given by low D/H ratios (deltaK as low as -180); for example, because of latitudinal isotopic variations in meteoric waters, as one moves north through the Cordilleran batholiths of western North America an increasingly higher proportion of the granitic rocks have deltaD values lower than -120. The lowering of deltaD values commonly corelates with re-setting of K-Ar ages. (Auth.)

  6. Magmatic apatite - a window into melt evolution of the Dalgety pluton.

    Science.gov (United States)

    Pope, M. D.; Tailby, N.; Webster, J. D.

    2017-12-01

    The Dalgety Pluton is located in the Lachlan Fold Belt in southeastern Australia, and is a coarse grained, peraluminous, S-type, biotite granodiorite. Historically, pluton emplacement has been thought of as cooling from a single, large body of magma over a geologically quick period. Current studies suggest issues with this model and propose a slower, incremental model of emplacement in some settings (Glazner et al., 2004). This work proposes that the emplacement of the Dalgety Pluton occurred in incremental phases demonstrated through halogen, minor, and trace element concentrations in apatites. Apatites from 13 samples collected along a north-south transect of the pluton were analyzed using a 5-spectrometer Cameca SX-100 calibrated for seventeen elements (F, Na, Cl, P, Mg, Al, Si, Ca, S, K, Ti, Mn, Fe, Sr, Ba, La, and Ce) at the American Museum of Natural History. The majority of apatites are fluorapatites, having >50 % F, <15 % Cl, and <25 % OH (calculated from Ketchum et al., 2015). However, the concentrations of the halogens vary throughout the pluton with the highest Cl concentrations near the southern edge. Two of the minor elements, Mn and Fe, also show distinct variation with the lowest concentrations being 0.35 wt% in Mn and 0.25 wt% in Fe and the highest being 1.10 wt% and 0.95 wt%, respectively. Trace elements Ce and La vary as well with their highest concentrations being 0.29 wt% and 0.11 wt% and their lowest for both being below the detection limit of the electron probe. Elemental variation across the pluton is seen in the concentration of minor elements and halogens with a sharp increases at 10,000 meters and again at 21,000 meters from the southern rim of the pluton. Similar shifts in concentration are also seen in the trace elements, however the concentrations decrease at these distances. These wholesale elemental fluctuations in composition are indicative of a dramatic shift in melt composition supporting the hypothesis of multiple melt injection

  7. Strontium and oxygen isotopic variations in mesozoic and tertiary plutons of central Idaho

    International Nuclear Information System (INIS)

    Fleck, R.J.; Criss, R.E.

    1985-01-01

    Regional variations in initial 87 Sr/ 86 Sr ratios (rsub(i)) of Mesozoic plutons in central Idaho locate the edge of Precambrian continental crust at the boundary between the late Paleozoic-Mesozoic accreted terranes and Precambrian sialic crust in western Idaho. The rsub(i) values increase abruptly but continuously from less than 0.704 in the accreted terranes to greater than 0.708 across a narrow, 5 to 15 km zone, characterized by elongate, lens-shaped, highly deformed plutons and schistose metasedimentary and metavolcanic units. The chemical and petrologic character of the plutons changes concomitantly from ocean-arc-type units to a weakly peraluminous, calcit to calcalkalic suite. Plutons in both suites yield Late Cretaceous ages, but Permian through Early Cretaceous bodies are confined to the accreted terranes and early Tertiary intrusions are restricted to areas underlain by Precambrian crust. The two major terranes were juxtaposed between 75 and 130 m.y. ago, probably between 80 and 95 m.y. Oxygen and strontium isotopic ratios and Rb and Sr concentrations of the plutonic rocks document a significant upper-crustal contribution to the magmas that intrude Precambrian crust. Magmas intruding the arc terranes were derived from the upper mantle/subducted oceanic lithosphere and may have been modified by anatexis of earlier island-arc volcanic and sedimentary units. (orig./PW)

  8. The research on the geochemical characteristics of Longyuanba composite pluton in Nanling region

    International Nuclear Information System (INIS)

    Zhang Min; Chen Peirong; Ling Hongfei

    2006-01-01

    The Longyuanba composite pluton, located in the eastern part of the Nanling Range, is an important part of the Nanling granites belt, which was regarded as a portion of Yanshanian epoch Pitou pluton to the east of it, and was lowly studied. The newest research shows that, the main body of Longyuanba pluton formed in Indosinian, different from Pitou pluton, which is Yanshanian. From main elements geochemical characteristics, there is obvious gap between Indosinian granites, Yanshanian granites and Yanshanian syenites in major oxides composition, which implies that there is possibly no fractional crystallization relationship between them. Form trace element geochemical characteristics, Indosinian Σ granites are enriched in LREE and high in REE. Yanshanian granites are depleted in MREE and low in Σ REE and ratios of Th/U, Nb/Ta, Zr/Hf, and obvious in fraction. The above characteristics show that, liquid action was rather strong in Yanshanian magmatism. Yanshanian syenites are enriched in high field elements and REE, are similar with A-type granite. Sr, Nd isotopic geochemical characteristics show that, Longyuanba composite pluton belongs to crust-original S-type granite and its original resource is early-Proterozoic crust from crust-mantle fraction. (authors)

  9. Lateral extrusion of a thermally weakened pluton overburden (Campiglia Marittima, Tuscany)

    Science.gov (United States)

    Vezzoni, Simone; Rocchi, Sergio; Dini, Andrea

    2017-10-01

    The ascent and emplacement of magmas in the upper crust modify the local pre-existing thermal and rheological settings. Such changes have important effects in producing anomalous structures, mass extrusion, rock fracturing, and in some conditions, hydrothermal mineralizations. In the Campiglia Marittima area, detailed field mapping led to the reconstruction of a local deformation history that overlaps, chronologically and spatially, with regional extension. This local deformation was triggered at the Miocene-Pliocene boundary by the intrusion of a monzogranitic pluton beneath a carbonate sedimentary sequence. The emplacement of the pluton produced a perturbation in the rheological behaviour of the carbonate host rocks, producing transient ductile conditions in the very shallow crust. The carbonate rocks were thermally weakened and flowed laterally, accumulating downslope of the pluton roof, mainly toward the east. As the thermal anomaly was decaying, the brittle-ductile boundary moved progressively back towards the pluton, and large tension gash-shaped volumes of fractured marble were generated. These fractured volumes were exploited by rising hydrothermal fluids generating sigmoidal skarn bodies and ore shoots. This work presents the Campiglia Marittima case study as a prime example of structural interference between regional extensional structures and local, lateral mass extrusion in a transient ductile rheological regime triggered by pluton emplacement.

  10. Geochemistry of biotite granites from the Lamas de Olo Pluton, northern Portugal

    Science.gov (United States)

    Fernandes, Susana; Gomes, Maria; Teixeira, Rui; Corfu, Fernando

    2013-04-01

    In the Central Iberian Zone (CIZ) extensive crustal recycling occurred during the post-thickening extension stage of the Variscan orogeny (~330-290 Ma). After the ductile deformation phase D3 (~320-300 Ma), characterized by the intrusion of large volumes of highly peraluminous granitic magmas, rapid and drastic tectonic changes at about 300 Ma gave rise to the brittle phase of deformation D4 that controlled the emplacement of Fe-K subalkaline granites (296-290 Ma; Dias et al. 1998). The Lamas de Olo Pluton (LOP) is controlled by NE-SW and NW-SE fracture systems, probably related to the Régua-Verin fault zone (Pereira, 1989). The LOP is a medium to coarse-grained, porphyritic biotite granite, accompanied by medium- to fine grained, porphyritic biotite granite (Alto dos Cabeços- AC) and a more leucocratic, fine-grained, slightly porphyritic biotite-muscovite granite (Barragens- BA). The contacts between LO and AC are generally diffuse, whereas those to BA are sharp. In fact, the BA granite can occur in dykes and sills cutting LO and AC. Microgranular enclaves and xenoliths are very rare. The LOP intrudes the Douro Group, presumably of Precambrian to Cambrian age, and two-mica granites from the Vila Real composite massif. The LOP granites consist of quartz, microcline, plagioclase, biotite, zircon, titanite, tourmaline apatite, fluorite, ilmenite, magnetite, and rutile, with muscovite in BA granite and rare allanite in the LO and AC granites. The plagioclase composition is of oligoclase (An12) - andesine (An35) for LO granite, albite (An9) - andesine (An30) for CA granite and albite (An5) - oligoclase (An20) for BA granite. There are decreases in: a) anorthite content from phenocryst to matrix plagioclase; b) Ba content from phenocryst to matrix microcline in all granites. The Fe2+ biotite has a composition similar to that of biotite from calc-alkaline to sub-alkaline rock series. The LO and AC granites are meta- to peraluminous with ASI variable between 1.05 and 1

  11. Evaluating the controls on Tourmaline Crystallization in the mylonitic granite-gneiss pluton in the Northeastern of Jan mine (Lorestan province

    Directory of Open Access Journals (Sweden)

    Arezoo Moradi

    2017-02-01

    Full Text Available Introduction The study area is a part of the Sanandaj- Sirjan zone that is located in the NW of Azna city and NE of the dimension stone mine of Jan between 49° 11' 41"and 49° 16' 07" E longitude and 33° 36'35" and 33° 38'12" N latitude., A pluton of mylonitic granite-gneiss is exposed in the area which contains abundant tourmalines as black and patchy or subgrain association. Geochemically, the studied granite-gneiss is A-type, peraluminous to slightly metaluminous and calc – alkaline to slightly alkaline (Moradi et al., 7. The electron microprobe analyses of the tourmalines display shorl-dravite in composition with more tendency to shorl (Moradi et al., 2015. In this paper we try to study the petrological sites of tourmaline formation with associated minerals, controller factors of crystallization using mineral chemistry of tourmaline, comprehensive behavior of trace elements in the tourmaline, synthetic phase diagrams and finally relationships between the associated minerals. Materials and methods The results of trace-element and major-element analyses were obtained from one polished thin section including 2 tourmaline grains. Major-element analyses of tourmaline were obtained at Oklahama City University of America using the JEOL 8200 electron microprobe with a spot size of 5 μm and trace-element analyses were performed on just a sample by Laser Ablation-Inductively Coupled Plasma-Mass Spectroscopy (LA-ICP-MS a 193nm ArF excimer laser ablation system (MicroLas GeoLas 200Q in combination with a quadrupole ICP-MS (Micromass Platform ICP at Utrecht University of Netherland. Representative EMP and LA-ICP-MS analyses of tourmaline samples are presented in Tables1 and 2. Results The results of LA-ICP-MS on tourmalines of Jan mine in the North east of mylonitic granite-gneiss body show that distribution and diffusion of trace elements during the growth of tourmaline trend is positive on the plots of binary Mn versus Fetot / (Fetot +Mg and it

  12. Use of olivine and plagioclase saturation surfaces for the petrogenetic modeling of recrystallized basic plutonic systems

    Science.gov (United States)

    Hanson, G. N.

    1983-01-01

    During petrogenetic studies of basic plutonic rocks, there are at least three major questions to be considered: (1) what were the relative proportions of cumulate crystals and intercumulus melt in a given sample? (2) what is the composition and variation in composition of the melts within the pluton? and (3) what is the original composition of the liquids, their source and evolution prior to the time of emplacement? Use of both saturation surfaces can place strong limits on the compositions of potential cumulate phases and intercumulus melts. Consideration of appropriate trace elements can indicate whether a sample is an orthocumulate, adcumulate or mesocumulate. Thus, when trace element and petrographic data are considered together with the saturation surfaces, it should be possible to begin to answer the three major questions given above, even for strongly recrystallized basic plutons.

  13. Main features of Kola, Leningrad and Ignalina NPPs for emergency preparedness purposes

    Energy Technology Data Exchange (ETDEWEB)

    Holmstroem, H. [VTT Energy (Finland)

    2001-12-01

    Of the nuclear power plants situated in the Nordic and their neighbouring countries, the Ignalina, Lenigrad and Kola plants are considered to pose the largest risks to the public. The purpose of this report is to provide basic relevant information about these three plants for use in a case of a major nuclear accident or incident in any of them. The report could be used e.g. by authorities dealing with the resulting emergency measures to provide the public and the media with relevant information about the plant in question. The report can also be used for quick general familiarization With the plants in question. The total activity inventories for all the plants are listed at the end of the report, in Chapter 4. The release of noble gases is close to 100 % in most severe accidents, but the releases of other elements depend strongly on the plant features and the nature of the accident. This report has been compiled from several sources. The main source has been an earlier NKS-report: 'Design and Safety Features of Nuclear Reactors Neighbouring the Nordic Countries', TemaNord 1994:595, 1994. Only limited editing has been done. Sources of the figures are presented in parenthesis after the figure titles. (au)

  14. International aid is needed in resolving the military nuclear waste problems in Kola peninsula

    International Nuclear Information System (INIS)

    Forss, S.

    1995-01-01

    Information about military nuclear waste problems in the counties of Murmansk and Arkhangelsk has become public on an unprecedented scale since the end of the cold war and the collapse of the Soviet Union. Relevant technical details about the nuclear waste problem are still unclassified. The amount of knowledge is, however, steadily increasing despite military secrecy. It is now possible to perform a fairly reliable evaluation of the scope and magnitude of the nuclear waste problem that stems from more than three decades of operation of nuclear submarines and ships of the former Soviet Northern Fleet. The former Soviet Navy built some 240 nuclear submarines, most of them with twin reactors. About 180 nuclear submarines will have to be disposed of in the coming years. Since the late eighties the Soviet/Russian Navy has retired about twenty nuclear submarines a year. Approximately one hundred nuclear submarines now lie in Russian harbours in the North and in the Far East, awaiting disposal. More than seventy are in the Kola and Arkhangelsk areas. Most of the retired submarines still carry nuclear fuel in their reactor. (orig.)

  15. Frequency electromagnetic sounding with industrial power lines on Karelia-Kola geotraverse

    Directory of Open Access Journals (Sweden)

    А. Н. Шевцов

    2017-04-01

    Full Text Available The paper describes theory, method and first experimental results of research on the interaction between electromagnetic waves of extremely low and ultra low frequency (0.1-200 Hz, the Earth crust and ionosphere in the field of two mutually orthogonal industrial power lines, 109 and 120 km long, in the course of FENICS experiment (Fennoscandian Electrical conductivity from Natural and Induction Control Source soundings. The main focus was on the observation results along the line of Karelia-Kola geotraverse over a distance of 700 km from the source. High horizontal homogeneity of geoelectrical lithosphere section has been detected in the eastern part of the Baltic shield at depth range from 10-15 to 50-70 km. Parameters of «regular» lithosphere section have been specified to the depth of 60-70 km. As a result of inverse problem solution for the western part of Karelia and Central Finland, a zone of decreased transverse resistivity has been detected at the depth of 50-60 km, corresponding to the area, detected by seismic methods, where Moho boundary reaches the same depth.

  16. U-Pb and Rb-Sr geochronology of the Wedgeport granitoid pluton, southwestern Nova Scotia

    International Nuclear Information System (INIS)

    Cormier, R.F.; Keppie, J.D.; Odom, A.L.

    1988-01-01

    Zircons from biotite monzogranite of the Wedgeport Pluton, intrusive into deformed metasediments of the Cambrian(?) Goldenville formation in the southwestern Meguma Terrane of Nova Scotia, yield concordant U-Pb ages of 316 ± 5 Ma. This is interpreted as the time of intrusion and crystallization. Within the error limits, the 323 ± 0.0056 Rb-Sr analyses of mineral separates of biotite, potassium feldspar, and quartz-plagioclase from several samples yield subparallel, internal isochrons with an average age of 257 ± 8 Ma. Initial ratios of the internal isochrons range from 0.716 to 0.759. A slow-cooling model for the latter data is discarded because the mineral data fall on straight lines. Instead, a reheating event related to plutonism ca 257 Ma ago, which was sufficient to cause local grain-to-grain migration and reequilibration of strontium and rubidium but not large-scale redistribution, is invoked. This reheating is also inferred to be responsible for the hydrothermal alteration and Sn-U mineralization concentrated along the northwestern margin of the pluton. A dextral northeast-southeast shear zone cutting the pluton is also inferred to be ca. 257 Ma old. It may be related to the last stages of westward abduction of the Meguma Terrane. These results provide a clear example of Permo-Carboniferous plutonism in the southwestern Meguma Terrane and suggest a similar interpretation may apply to other anomalously young ages recorded in this area. In light of these results, the Permo-Carboniferous age of the large East Kemptville tin deposit and its location in a dextral shear zone suggest that the association of younger plutonism and shear zones may be a significant factor for economic mineralization. (22 refs., 4 tabs., 3 figs.)

  17. Alkalinity of the Mediterranean Sea

    OpenAIRE

    Schneider, Anke; Wallace, Douglas W.R.; Körtzinger, Arne

    2007-01-01

    Total alkalinity (AT) was measured during the Meteor 51/2 cruise, crossing the Mediterranean Sea from west to east. AT concentrations were high (∼2600 μmol kg−1) and alkalinity-salinity-correlations had negative intercepts. These results are explained by evaporation coupled with high freshwater AT inputs into coastal areas. Salinity adjustment of AT revealed excess alkalinity throughout the water column compared to mid-basin surface waters. Since Mediterranean waters are supersaturated with r...

  18. Alkaline fuel cells applications

    Science.gov (United States)

    Kordesch, Karl; Hacker, Viktor; Gsellmann, Josef; Cifrain, Martin; Faleschini, Gottfried; Enzinger, Peter; Fankhauser, Robert; Ortner, Markus; Muhr, Michael; Aronson, Robert R.

    On the world-wide automobile market technical developments are increasingly determined by the dramatic restriction on emissions as well as the regimentation of fuel consumption by legislation. Therefore there is an increasing chance of a completely new technology breakthrough if it offers new opportunities, meeting the requirements of resource preservation and emission restrictions. Fuel cell technology offers the possibility to excel in today's motive power techniques in terms of environmental compatibility, consumer's profit, costs of maintenance and efficiency. The key question is economy. This will be decided by the costs of fuel cell systems if they are to be used as power generators for future electric vehicles. The alkaline hydrogen-air fuel cell system with circulating KOH electrolyte and low-cost catalysed carbon electrodes could be a promising alternative. Based on the experiences of Kordesch [K. Kordesch, Brennstoffbatterien, Springer, Wien, 1984, ISBN 3-387-81819-7; K. Kordesch, City car with H 2-air fuel cell and lead-battery, SAE Paper No. 719015, 6th IECEC, 1971], who operated a city car hybrid vehicle on public roads for 3 years in the early 1970s, improved air electrodes plus new variations of the bipolar stack assembly developed in Graz are investigated. Primary fuel choice will be a major issue until such time as cost-effective, on-board hydrogen storage is developed. Ammonia is an interesting option. The whole system, ammonia dissociator plus alkaline fuel cell (AFC), is characterised by a simple design and high efficiency.

  19. Reconnaissance study of the uranium and thorium contents of plutonic rocks of the southwestern Seward Peninsula, Alaska

    International Nuclear Information System (INIS)

    Miller, T.P.; Bunker, C.M.

    1976-01-01

    Large granitic Cretaceous plutons are exposed along and adjacent to an arcuate belt of igneous and high-grade metamorphic rocks in the southeastern Seward Peninsula of Alaska. Reconnaissance studies of these plutons have shown that the Darby pluton has well above average amounts of uranium and thorium (11.2 ppm and 58.7 ppm, respectively), the Kachauik pluton contains average to above average uranium and thorium (5.7 ppm and 22.5 ppm, respectively), and the Bendeleben pluton contains average amounts of uranium and thorium (3.4 ppm and 16.7 ppm, respectively). The three plutons show compositional and textural differences indicative of different source materials that may have controlled the distribution of uranium and thorium. The high uranium and thorium contents of the Darby pluton, similar to those of the Conway Granite of New Hampshire which has been mentioned as a possible low-grade thorium resource, suggest that this pluton may be a favorable area for economic concentrations of uranium and thorium

  20. Evidence for a close phylogenetic relationship between Melissococcus pluton, the causative agent of European foulbrood disease, and the genus Enterococcus.

    Science.gov (United States)

    Cai, J; Collins, M D

    1994-04-01

    The 16S rRNA gene sequence of Melissococcus pluton, the causative agent of European foulbrood disease, was determined in order to investigate the phylogenetic relationships between this organism and other low-G + C-content gram-positive bacteria. A comparative sequence analysis revealed that M. pluton is a close phylogenetic relative of the genus Enterococcus.

  1. Granitoid emplacement during syn-convergent transtension: An example from the Huamenlou pluton in North Qinling, central China

    Directory of Open Access Journals (Sweden)

    Yang Li

    2018-01-01

    Full Text Available The Huamenlou pluton, is an elongated granite intrusion with high aspect ratio, emplaced within the southern margin of the North Qinling (central China. Here we investigate this pluton through multiple techniques including the fabric study, microstructural observation and zircon geochronology. Our zircon U–Pb data confirm that the granite crystallized at ca. 462 Ma which is consistent with the ages of other linear plutons in North Qinling. Microstructural observations of the Huamenlou granites illustrate that the pluton has undergone superimposed deformation during its emplacement, from magmatic to high-temperature solid state conditions. The internal fabric obtained by anisotropy of magnetic susceptibility (AMS and shape preferred orientation (SPO show similar results. The fabrics are relatively concordant and generally vary from NE–SW to NEE–SWW which are roughly oblique to the trend of the pluton elongation and the regional structures. Meanwhile, scalar parameters reflect two completely different strain regimes for the pluton and its host rocks, i.e., the fabrics within host rocks are mainly oblate while the central part of the intrusion displays mainly prolate fabrics. It is inferred that the structural pattern recorded in this pluton was caused by local dextral transtension in consequence of oblique convergence between the South and North China Blocks. We propose that the local transtension in convergence setting probably evolved from vertical extrusion tectonics that provided room for the magma emplacement and imparted prolate fabrics in the Huamenlou pluton.

  2. Syn-collisional I-type Esenköy Pluton (Eastern Anatolia-Turkey): An indication for collision between Arabian and Eurasian plates

    Science.gov (United States)

    Açlan, Mustafa; Altun, Yusuf

    2018-06-01

    The Esenköy pluton which is situated in the East Anatolian Accretionary Complex (EACC) is represented by I-type, metalumino, calc-alkaline, VAG + syn-COLG, gabbro, diorite, quartz diorite, tonalite and granodiorite type rocks. This paper presents the characteristics of the above granitoids on their major, trace, rare earth elements (REE) and their zircon U-Pb dating. Zircon U-Pb crystallisation ages for gabbro, tonalite and granodiorite are 22.3 ± 0.2 Ma, 21.7 ± 0.2 Ma and 21.8 ± 0.2 Ma respectively. Esenköy granitoids show medium and high-K calc-alkaline character, with six exceptional K-poor sample plot in tholeiitic series field. The Rb/Y-Nb/Y diagram for Esenköy granitoids display subduction zone enrichment trend. The data which obtained from major, trace and REE geochemical characteristics and 206Pb/238U ages indicate that the collision which is take place between Arabian and Eurasian plates along the Bitlis-Zagros suture zone has begun in the Early Miocene (Aquitanian) or before from Early Miocene.

  3. Use of Digital Elevation Models to understand map landforms and history of the magmatism Khibiny Massif (Kola Peninsula, Russia)

    Science.gov (United States)

    Chesalova, Elena; Asavin, Alex

    2016-04-01

    most intense free gas emission. The technical possibilities that are offered by Remote Sensing (RS) and Geographical Information Systems (GIS) facilitate the geomorphological investigation of inhospitable and inaccessible mountain areas Digital Elevation Models (DEMs) are valuable tools for approximation of the real world's continuous surface. They allow a visual analysis of the earth's surface morphology, quanti?cation of sediment volumes and the calculation of topographic derivatives such as the slope gradient, slope aspect and pro?le curvature that consume ?eld investigations and optimize time The project has been sponsored by programmm Presidium of RAS P44. Reference Ivanyuk G, Kalashnikov A, Mikhailova J, Konoplyova N, Goryainov P, Yakovenchuk V, Pakhomovsky Y. Self-Organization of the Khibiny Alkaline Massif (Kola Peninsula, Russia). In Earth Sciences, Dr. Imran Ahmad Dar(Ed.), ISBN: 978-953-307-861-8, InTech, Available from: http://www.intechopen.com/books/earth-sciences/self-organization-of-the-khibiny-alkaline -massif -kolapeninsula-russia INTECH Open Access Publisher; 2012, Head7, P.131-156.

  4. The history of decisions on creation of nuclear and metallurgical complex on the basis of the Kola nuclear power plant

    Directory of Open Access Journals (Sweden)

    Kudrin B. I.

    2017-02-01

    Full Text Available Some reasons for the choice of directions for using electric and thermal energy of the Kola nuclear power plant located beyond the Arctic Circle have been presented. The regions of the country and their large-scale industrial productions based on metallurgical enterprises have been indicated; the electrical supply of these enterprises is implemented from the Kola NPP. The results of research of energy inputs for the production of a ton of steel and cast iron have been presented. It has been determined that the main direction of technological modernization in the steel industry is avoiding the use of organic fuels (particularly in coke-blast furnace production as the most energy-intensive and its replacement with the technology of direct reduction of iron with hydrogen. As an alternative energy source for organic fuels the creation of a fuel-free nuclear-metallurgical electrified complex has been proposed. The principal scheme of the fuel-free nuclear-metallurgical electrified complex has been described, here the main novelty has a reducing gases preparation block giving the potential ability for creating waste-free process. It has been noted that this technology requires using high temperatures and solving technical problems related to heat resistance of constructions. Some examples of world research on the implementation of similar projects have been presented. It has been determined that the use of new technology will cause the need for optimization of power consumption structure due to the redistribution of capacity and electrical consumption between productions. The introduction of new technologies requires solving a number of problems on electric power supply and electrical equipment designing. It has been observed that on the Kola NPP large-scale reconstruction was carried out during the working period, it helped to increase its project capacity and extend the operation life. Nowadays the region has excess installed capacity that can be

  5. Tinnunculite, C5H4N4O3 · 2H2O: Occurrences on the Kola Peninsula and Redefinition and Validation as a Mineral Species

    Science.gov (United States)

    Pekov, I. V.; Chukanov, N. V.; Yapaskurt, V. O.; Belakovskiy, D. I.; Lykova, I. S.; Zubkova, N. V.; Shcherbakova, E. P.; Britvin, S. N.; Chervonnyi, A. D.

    2017-12-01

    Based on a study of samples found in the Khibiny (Mt. Rasvumchorr: the holotype) and Lovozero (Mts Alluaiv and Vavnbed) alkaline complexes on the Kola Peninsula, Russia, tinnunculite was approved by the IMA Commission on New Minerals, Nomenclature, and Classification as a valid mineral species (IMA no. 2015-02la) and, taking into account a revisory examination of the original material from burnt dumps of coal mines in the southern Urals, it was redefined as crystalline uric acid dihydrate (UAD), C5H4N4O3 · 2H2O. Tinnunculite is poultry manure mineralized in biogeochemical systems, which could be defined as "guano microdeposits." The mineral occurs as prismatic or tabular crystals up to 0.01 × 0.1 × 0.2 mm in size and clusters of them, as well as crystalline or microglobular crusts. Tinnunculite is transparent or translucent, colorless, white, yellowish, reddish or pale lilac. Crystals show vitreous luster. The mineral is soft and brittle, with a distinct (010) cleavage. D calc = 1.68 g/cm3 (holotype). Tinnunculite is optically biaxial (-), α = 1.503(3), β = 1.712(3), γ = 1.74(1), 2 V obs = 40(10)°. The IR spectrum is given. The chemical composition of the holotype sample (electron microprobe data, content of H is calculated by UAD stoichiometry) is as follows, wt %: 37.5 O, 28.4 C, 27.0 N, 3.8 Hcalc, total 96.7. The empirical formula calculated on the basis of (C + N+ O) = 14 apfu is: C4.99H8N4.07O4.94. Tinnunculite is monoclinic, space group (by analogy with synthetic UAD) P21/ c. The unit cell parameters of the holotype sample (single crystal XRD data) are a = 7.37(4), b = 6.326(16), c = 17.59(4) Å, β = 90(1)°, V = 820(5) Å3, Z = 4. The strongest reflections in the XRD pattern ( d, Å- I[ hkl]) are 8.82-84[002], 5.97-15[011], 5.63-24[102̅, 102], 4.22-22[112], 3.24-27[114̅,114], 3.18-100[210], 3.12-44[211̅, 211], 2.576-14[024].

  6. Analysis of ISO/IEC 17025 for establishment of KOLAS (Korea Laboratory Accreditation Scheme) quality assurance system

    International Nuclear Information System (INIS)

    Nam, Ji Hee

    2000-12-01

    Besides one existent accredited lab, radioactive material chemical analysis lab, five test laboratories and two calibration labs are under plan to acquire the accreditation from KOLAS. But the current Quality Manual was developed according to ISO Guide 25 that was superceded by ISO/IEC 17025. Since it is tailored to the radioactive material chemical analysis lab, a number of requirements of the Manual are not applicable to the labs other than radioactive material chemical analysis lab. Through the analysis of ISO/IEC 17025, a model of quality system was established which is not only consistent with ISO/IEC 17025 but reflective of the KAERI's situation

  7. Dynamics of metamorphism processes by the fractal textures analysis of garnets, amphiboles and pyroxenes of Lapland Granulite Belt, Kola Peninsula

    Directory of Open Access Journals (Sweden)

    Miłosz A. Huber

    2012-01-01

    Full Text Available About thousand analyzes of garnet, amphibole and pyroxene crystals from selected samples of amphibolite and granulite rocks from Lapland Granulite Belt in Kandalaksha region (Kola Peninsula has been made. Indicated fractal-box dimension of studied minerals has a good correlation with tectonic zones, lead to a new insight in the dynamics of processes, which has modified the examined region. Fractal-box dimension makes the textural analysis more precise, because it consents for the mathematic and repeated review of crystals topology depending directly on processes which had created them.

  8. Method of cleaning alkaline metal

    International Nuclear Information System (INIS)

    Kawakami, Yukio; Naito, Kesahiro; Iizawa, Katsuyuki; Nakasuji, Takashi

    1981-01-01

    Purpose: To prevent scattering of used sodium and aqueous alkaline solution when cleaning used sodium and metallic sodium adhering to equipment with an aqueous alkaline solution. Method: A sodium treating container is filled with an aqueous alkaline solution, and stainless steel gauze is sunk in the container. Equipment to be cleaned such as equipment with sodium adhering to it are retained under the gauze and are thus cleaned. On the other hand, the surface of the aqueous alkaline solution is covered with a fluid paraffin liquid covering material. Thus, the hydrogen produced by the reaction of the sodium and the aqueous alkaline solution will float up, pass through the liquid covering material and be discharged. The sodium will pass through the gauze and float upwardly while reacting with the aqueous alkaline solution in a partic ulate state to the boundary between the aqueous alkaline solution and up to the covering material, and thus the theratment reaction will continue. Thus, the cover material prevents the sodium and the aqueous alkaline solution from scattering. (Kamimura, M.)

  9. Isotopic disequilibrium among commingled hybrid magmas: Evidence for a two-stage magma mixing-commingling process in the Mt. Perkins Pluton, Arizona

    International Nuclear Information System (INIS)

    Metcalf, R.V.; Smith, E.I.; Reed, R.C.

    1995-01-01

    The syn-extensional Miocene Mt. Perkins pluton, northwestern Arizona, cooled rapidly due to its small size (6 km 2 ) and shallow emplacement (7.5 km) and allows examination of commingled rocks that experienced little isotopic exchange. Within the pluton, quartz dioritic to granodioritic host rocks (58-68 wt% SiO 2 ) enclose dioritic enclaves (50-55 wt% SiO 2 ) and a portion contains enclave-free granodiorite (70-74 wt% SiO 2 ). Fine-grained, crenulate enclave margins and a lack of advanced mixing structures (e.g., schlieren, flow fabrics, etc.) indicate an incipient stage of commingling. Isotopic variation between enclaves and enclosing host rocks is large (6.8 to 10.6 ε Nd units; 0.0036 to 0.0046 87 Sr/ 86 Sr units), suggesting isotopic disequilibrium. Comparison of an enclave core and rim suggests that isotopic exchange with the host magma was limited to the enclave rim. Enclaves and hosts collectively form a calc-alkaline suite exhibiting a large range of ε Nd (+1.2 to -12.5) and initial 87 Sr/ 86 Sr (0.705 to 0.71267) with a correlation among ε Nd , initial 87 Sr/ 86 Sr, and major and trace element compositions. Modeling suggests that the suite formed by magma hybridization involving magma mixing accompanied by fractional crystallization. The magma mixing must have predated commingling at the present exposure level and indicates a larger mixing chamber at depth. Isotopic and trace element data suggests mixing end-members were asthenospheric mantle-derived mafic and crustal-derived felsic magmas. Fractional crystallization facilitated mixing by reducing the rheological contrasts between the mafic and felsic mixing end-members. 58 refs., 11 figs., 3 tabs

  10. Perspectives of humic substances application in remediation of highly heavy metals contaminated soils in Kola Subarctic

    Science.gov (United States)

    Tregubova, Polina; Turbaevskaya, Valeria; Zakharenko, Andrey; Kadulin, Maksim; Smirnova, Irina; Stepanov, Andrey; Koptsik, Galina

    2016-04-01

    Northwestern part of Russia, the Kola Peninsula, is one of the most heavy metals (HM) contaminated areas in the northern hemisphere. The main polluters, mining-and-metallurgical integrated works "Pechenganikel" and "Severonikel", are surrounded by heavily damaged barren lands that require remediation. The main contaminating metals are Ni and Cu. Using of exogenous humic substances could be possible effective and cost-efficient solution of HM contamination problem. Rational application of humates (Na-K salts of humic acids) can result in improvement of soil properties, localization of contamination and decreasing bioavailability through binding HM in relatively immobile organic complexes. Our research aim was to evaluate the influence of increasing doses of different origin humates on i) basic properties of contaminated soils; ii) mobility and bioavailability of HMs; iii) vegetation state and chemistry. In summer 2013 a model field experiment was provided in natural conditions of the Kola Peninsula. We investigated the Al-Fe-humus abrazem, soil type that dominates in technogenic barren lands around the "Severonikel" work. These soils are strongly acid: pHH2O was 3.7-4.1; pHKCl was 3.4-4.0. The exchangeable acidity is low (0.8-1.6 cmol(+)/kg) due to the depletion of fine particles and organic matter, being the carriers of exchange positions. The abrazems of barrens had lost organic horizon. 12 sites were created in 1 km from the work. In those sites, except 2 controls, various amendments were added: i) two different by it's origin types of humates: peat-humates and coal-humates, the last were in concentrations 0.5% and 1%; ii) lime; iii) NPK-fertilizer; iv) biomates (organic degradable cover for saving warm and erosion protection). As a test-culture a grass mixture with predominance of Festuca rubra and Festuca ovina was sowed. As a result we concluded that humates of different origin have unequal influence on soil properties and cause decreasing as well as

  11. THE PALEOPROTEROZOIC IMANDRA-VARZUGA RIFTING STRUCTURE (KOLA PENINSULA: INTRUSIVE MAGMATISM AND MINERAGENY

    Directory of Open Access Journals (Sweden)

    V. V. Chashchin

    2014-01-01

    Full Text Available The article provides data on the structure of the Paleoproterozoic intercontinental Imandra-Varzuga rifting structure (IVS and compositions of intrusive formations typical of the early stage of the IVS development and associated mineral resources. IVS is located in the central part of the Kola region. Its length is about 350 km, and its width varies from 10 km at the flanks to 50 km in the central part. IVS contains an association of the sedimentary-volcanic, intrusive and dyke complexes. It is a part of a large igneous Paleoproterozoic province of the Fennoscandian Shield spreading for a huge area (about 1 million km2, which probably reflects the settings of the head part of the mantle plume. Two age groups of layered intrusions were associated with the initial stage of the IVS development. The layered intrusions of the Fedorovo-Pansky and Monchegorsk complexes (about 2.50 Ga are confined to the northern flank and the western closure of IVS, while intrusions of the Imandra complex (about 2.45 Ga are located at the southern flank of IVS. Intrusions of older complexes are composed of rock series from dunite to gabbro and anorthosites (Monchegorsk complex and from orthopyroxenite to gabbro and anorthosites (Fedorovo-Pansky complex. Some intrusions of this complexes reveal features of multiphase ones. The younger Imandra complex intrusions (about 2.45 Ga are stratified from orthopyroxenite to ferrogabbro. Their important feature is comagmatical connection with volcanites. All the intrusive complexes have the boninite-like mantle origin enriched by lithophyle components. Rocks of these two complexеs with different age have specific geochemical characteristics. In the rocks of the Monchegorsk and Fedorovo-Pansky complexes, the accumulation of REE clearly depends on the basicity of the rocks, the spectrum of REE is non-fractionated and ‘flat’, and the Eu positive anomaly is slightly manifested. In the rocks of the Imandra complex, the level of

  12. Thermal modification of hematite-ilmenite intergrowths in the Ecstall pluton, British Columbia, Canada

    DEFF Research Database (Denmark)

    Brownlee, S.J.; Feinberg, J.M.; Harrison, R.J.

    2010-01-01

    In this study, we examine the effects of reheating on finely exsolved hematite-ilmenite intergrowths from the similar to 91 Ma Ecstall pluton using reflected light microscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). As a result of the emplacement of the you......In this study, we examine the effects of reheating on finely exsolved hematite-ilmenite intergrowths from the similar to 91 Ma Ecstall pluton using reflected light microscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). As a result of the emplacement...... of the younger adjacent similar to 52 Ma Quottoon pluton, samples closer to a thermal boundary have experienced greater degrees of thermal alteration. Five main microstructural features characterize hematite-ilmenite intergrowths from the Ecstall: (I) exsolution lamellae of hematite and ilmenite; (II) oxidation....... Higher temperatures also enhanced oxidation in ilmenite. The formation of magnetite altered the bulk magnetic properties of these samples, increasing NRM intensity. This study underscores the need to consider a pluton's post-emplacement thermal history before making tectonic interpretations based...

  13. Contribution to the radioactivity of Um Ara granitic pluton, south-eastern desert, Egypt

    International Nuclear Information System (INIS)

    El Reedy, M.W.; Kamel, A.F.; Mansour, S.E.I.

    1988-01-01

    Um Ara area lies in the southern part of the eastern desert between latitudes 22 0 30' and 22 0 41'N and longitudes 33 0 46' and 33 0 54'E. Several types of granitic varieties ranging from high silica granite (SiO 2 >75%) to low silica granite (SiO 2 68-70%) occur in Um Ara granitic pluton. Surface samples were collected from the high anomalous locations in the pluton together with trenches samples (about 50cm in depth). The U content in the surface samples ranges from 69 to 7 ppm while in trenches samples, it ranges from 38 to 759 ppm. The thorium content on the other hand ranges from 34 to 402 ppm in surface samples and from 158 to 316 ppm in trenches samples. Some samples show no Th contents. The Th/U ratios ranges from 0.065 to 3.137 in surface samples and from 0.386 to 2.590 in trenches samples. An enrichment of U content is the main feature characterising this granitic pluton, it is mainly connected with the fractured zones. Uranium is mostly present as secondary U mineralization accompanied by Fe, Mn and to some extent by carbonate materials. A hydrothermal origin could be considered for this U mineralization in the pluton. Primary U mineralization (pitchblende) together with secondary mineralization was observed in some locations in the area disseminated in the granite, this reflects the syngenetic origin of this granitic type

  14. Magmatic evolution and controls on rare metal-enrichment of the Strange Lake A-type peralkaline granitic pluton, Québec-Labrador

    Science.gov (United States)

    Siegel, Karin; Vasyukova, Olga V.; Williams-Jones, Anthony E.

    2018-05-01

    Although it is well known that A-type granites are enriched in the rare earth elements (REE) and other high field strength elements (HFSE), the magmatic processes that concentrate these elements are still poorly understood. The 1.24 Ga Strange Lake pluton in northern Québec-Labrador provides an extraordinary example of hyper-enrichment in the REE, Zr, and Nb in a peralkaline A-type granite. The pluton consists of two hypersolvus granite units (southern and northern) and a transsolvus granite, all of which contain perthitic alkali feldspar as the earliest major mineral; the transsolvus granite also contains separate albite and microcline crystals. Arfvedsonite, a sodic amphibole, occurs exclusively as phenocrysts in the transsolvus granite, whereas in the hypersolvus granite it is present as a late, interstitial phase. The primary HFSE minerals are zircon, monazite-(Ce), gagarinite-(Ce) and the pyrochlore group minerals. Magma evolution was monitored by the alumina content in the bulk rock, which decreases from the southern to the northern hypersolvus granite and is lowest in the transsolvus granite. Alkalinity indices and bulk Si, Fe, Rb, REE, Zr, Nb concentrations show the opposite trend. Alkali feldspar compositions mirror the trend shown by the bulk rock, i.e., decreasing Al contents are accompanied by increasing Si, Fe3+, REE, Zr and Nb contents. The major driving forces for the evolution of the hypersolvus magma prior to emplacement were the early separation of a fluoride melt from the silicate melt and the crystallization of alkali feldspar and HFSE-rich phases (zircon, monazite-(Ce), pyrochlore group). An alkali feldspar-rich crystal-mush containing LREE-fluoride melt droplets was emplaced as the least evolved southern hypersolvus granite. Massive fractionation of alkali feldspar led to a sharp increase in ƒH2O and F- activity in the magma chamber that triggered the crystallization of arfvedsonite and was followed by emplacement of the northern hypersolvus

  15. Assessment of current exposure levels in different population groups of the Kola Peninsula

    International Nuclear Information System (INIS)

    Travnikova, I.G.; Shutov, V.N.; Ya Bruk, G.; Balonov, M.I.; Skuterud, L.; Strand, P.; Pogorely, Ju.A.; Burkova, T.F.

    2002-01-01

    Activity concentrations of 137 Cs and 90 Sr in samples of vegetation and natural food products collected in the Kola Peninsula in 1998 and 1999 indicate a very slow decrease in contamination levels during the last decade, mainly due to the physical decay of the radionuclides. The activity concentrations of 137 Cs in reindeer meat decreased with a half-life of about 9 years. 137 Cs in lichen, moss and fungi is significantly higher than in natural vegetation (grasses) and agricultural plants (potatoes). The activity concentrations of 137 Cs in reindeer meat were two orders of magnitude higher than those in locally produced beef and pork. Consumption of reindeer meat, fish, mushrooms and berries constituted the main contribution to the internal dose from 137 Cs and 90 Sr for reindeer-breeders in the Lovozero area. The estimated committed doses due to 137 Cs intake in this group were about 10 μSv per month in summer 1998 and 15 μSv per month in winter, 1999. There was good agreement between internal dose estimates based on intake assessment and whole body measurements. The population of Umba settlement, which is not involved in reindeer breeding, received individual committed doses due to 137 Cs intake of about 0.5 μSv per month, about a factor of 20 less than the reindeer-breeders in Lovozero. In this case, the main contribution to the internal dose of the general population came from consumption the of 137 Cs in mushrooms and forest berries. The contribution of 90 Sr to the internal dose varied from 1% to 5% in the different population groups studied

  16. Geochemical constraints on the link between volcanism and plutonism at the Yunshan caldera complex, SE China

    Science.gov (United States)

    Yan, Lili; He, Zhenyu; Beier, Christoph; Klemd, Reiner

    2018-01-01

    The Yunshan caldera complex is part of a larger scale, ca. 2000-km-long volcanic-plutonic complex belt in the coastal region of SE China. The volcanic rocks in the caldera complex are characterized by high-silica peraluminous and peralkaline rhyolites associated with an intracaldera porphyritic quartz monzonite pluton. In this study, we present zircon U-Pb, Hf and stable O isotopes along with geochemical data of both volcanic and plutonic rocks to evaluate the potential petrogenetic link between volcanism and plutonism in the Yunshan caldera complex. SHRIMP zircon U-Pb geochronology of both volcanic and plutonic rocks yields almost identical ages ranging from 95.6 to 93.1 Ma. The peraluminous and peralkaline rhyolites show negative anomalies of Sr, P, Ti and Ba and to a lesser extent negative Nb and Ta anomalies, along with positive Rb anomalies and `seagull-like' rare earth element (REE) patterns with negative Eu anomalies and low (La/Yb)N ratios. The intracaldera porphyritic quartz monzonite displays minor negative Rb, Nb, Ta, Sr, P and Ti anomalies and a positive Ba anomaly with REE patterns characterized by relatively high (La/Yb)N ratios and lack significant Eu anomalies. The peraluminous and peralkaline rhyolites and the porphyritic quartz monzonite exhibit consistent ɛ Nd( t) of - 3.7 to - 2.2 and display zircon ɛ Hf( t) values of - 2.1 to 3.7. They further have similar, mantle-like, zircon oxygen isotopic compositions (δ18OVSMOW mainly = 4.63 to 5.76‰). We interpret these observations to be in agreement with a crystal mush model in which the parental magma of the volcanic and plutonic rocks of the Yunshan caldera complex was likely produced by interaction of asthenosphere melts with subduction-influenced enriched mantle wedge. The peralkaline rhyolites are interpreted to represent the most differentiated magma that has subsequently experienced significant fluid-melt interactions, whereas the porphyritic quartz monzonite may be representative of the

  17. Quantifying the Plutonic to Volcanic Relationship Along the Puna Plateau: Implications for Cordilleran Plateau Evolution

    Science.gov (United States)

    Ward, K. M.; Delph, J. R.; Zandt, G.; Beck, S. L.; Ducea, M. N.

    2016-12-01

    Quantifying well constrained plutonic to volcanic (P:V) ratios is inherently difficult because the tectonic processes that exhume intrusive bodies rarely preserve their extrusive equivalents. Conversely, active magmatic systems that have well-preserved volcanic deposits require sophisticated geophysical or geochemical approaches to estimate their plutonic roots and even when these sophisticated approaches are available, it is not always clear what constitutes a plutonic volume. Further complicating the enigmatic plutonic to volcanic relationship is the highly episodic nature of pluton emplacement where magmatic flare-ups produce several orders of magnitude more magmatism when compared against magmatic lulls. Despite this inherent difficulty, a growing body of independently measured P:V ratios (e.g. seismic tomography, geomorphic modeling, geological mapping/dating, and Zircon age spectra modeling) suggests the contribution of magmatic addition as an uplift mechanism in Cordilleran systems is much larger than is currently accepted. However, it remains unclear if these studies can be generalized to represent type behavior in Cordilleran systems or result from the non-uniform sampling imposed by the ability to measure large P:V ratios in only a few select and potentially anomalous regions of the American Cordillera. To better examine the role of magmatic processes in building Cordilleran high plateaus, we image the crustal seismic shear-wave velocity for an 800 km section (20.5°-28°S) of the active South American Cordillera (Puna Plateau). When placed in the context of existing geological and geophysical datasets, our seismic model reveals numerous mid-crustal low-velocity zones that we unambiguously interpret as the plutonic underpinnings associated with the voluminous silicic volcanics of the Puna Plateau. These larger P:V ratios are consistent with recent thermomechanical modeling of granitic magma intrusions that support the existence of long-lived, partially

  18. Modelling and Evaluation of Environmental Impact due to Continuous Emissions of the Severonickel Plant (Kola Peninsula)

    Science.gov (United States)

    Mahura, A.; Gonzalez-Aparicio, I.; Nuterman, R.; Baklanov, A.

    2012-04-01

    In this study, evaluation of potential impact - through concentration, deposition and loadings patterns - on population and environment due to continuous anthropogenic emissions (on example of sulfates) of the Cu-Ni smelters of the Russian North is given. To estimate impact, the Danish Emergency Response Model for Atmosphere (DERMA) was employed to perform long-term simulations of air concentration, time integrated air concentration (TIAC), dry (DD) and wet (WD) deposition patterns resulting from continuous emissions of the Severonickel smelters located on the Kola Peninsula (Murmansk region, Russia). To perform such simulations the 3D meteorological fields (from the European Center for Medium-Range Weather Forecasts, ECMWF) for the year 2000 were used as input. For simplicity, it has been assumed that normalized releases of sulfates from smelters location occurred at a constant rate every day. For each daily release the atmospheric transport, dispersion, dry and wet deposition due to removal processes were estimated during 10 day interval. Output from these long-term simulations is an essential input for evaluation of impact, doses, risks, and short- and long-term consequences, etc. Detailed analyses of simulated concentration and deposition fields allowed evaluating the spatial and temporal variability of resulted patterns on different scales. Temporal variability of both wet and dry deposition as well as their contribution into total deposition have been estimated. On an annual scale, the concentration and deposition patterns were estimated for the most populated cities of the North-West Russia. The modeled annual fields were also integrated into GIS environment as well as layers with population density (from the Center for International Earth Science Information Network, CIESIN) and standard administrative division of the North-West Russia and bordering countries. Furthermore, the estimation of deposited amounts (loadings) of sulfates for selected regions of

  19. Geographically diverse Australian isolates of Melissococcus pluton exhibit minimal genotypic diversity by restriction endonuclease analysis.

    Science.gov (United States)

    Djordjevic, S P; Smith, L A; Forbes, W A; Hornitzky, M A

    1999-04-15

    Melissococcus pluton, the causative agent of European foulbrood is an economically significant disease of honey bees (Apis mellifera) across most regions of the world and is prevalent throughout most states of Australia. 49 Isolates of M. pluton recovered from diseased colonies or honey samples in New South Wales, Queensland, South Australia, Tasmania and Victoria were compared using SDS-PAGE, Western immunoblotting and restriction endonuclease analyses. DNA profiles of all 49 geographically diverse isolates showed remarkably similar AluI profiles although four isolates (one each from Queensland, South Australia, New South Wales and Victoria) displayed minor profile variations compared to AluI patterns of all other isolates. DNA from a subset of the 49 Australian and three isolates from the United Kingdom were digested separately with the restriction endonucleases CfoI, RsaI and DraI. Restriction endonuclease fragment patterns generated using these enzymes were also similar although minor variations were noted. SDS-PAGE of whole cell proteins from 13 of the 49 isolates from different states of Australia, including the four isolates which displayed minor profile variations (AluI) produced indistinguishable patterns. Major immunoreactive proteins of approximate molecular masses of 21, 24, 28, 30, 36, 40, 44, 56, 60, 71, 79 and 95 kDa were observed in immunoblots of whole cell lysates of 22 of the 49 isolates and reacted with rabbit hyperimmune antibodies raised against M. pluton whole cells. Neither SDS-PAGE or immunoblotting was capable of distinguishing differences between geographically diverse isolates of M. pluton. Collectively these data confirm that Australian isolates of M. pluton are genetically homogeneous and that this species may be clonal. Plasmid DNA was not detected in whole cell DNA profiles of any isolate resolved using agarose gel electrophoresis.

  20. Potassium, rubidium, strontium, thorium and uranium of the cretaceous plutons in the Kitakami Mountains

    International Nuclear Information System (INIS)

    Katada, Masato; Kanaya, Hiroshi.

    1980-01-01

    The Cretaceous plutonic rocks in the Kitakami Mountains, 110 to 125 Ma in K-Ar ages on biotite, etc., can be petrographically and petrochemically classified into seven groups; Zones I, II, III, IV, V, VIa and VIb. Some of them are arranged in the east to west direction. The plutons of Zones II and V are mainly felsic. They are of comparatively big dimension reaching 600 square kilometers. The plutons of other zones are composed of felsic and mafic rocks. They occur on a small scale. The plutonic rocks have been chemically analysed for CaO, K 2 O, Rb, Sr, Th, and U. In the mafic rocks of CaO > 8.2 percent, the contents of CaO and Na 2 O are nearly equal in each zone throughout the Kitakami Mountains. K 2 O, Rb, Th, and U contents, however, generally increase westward. Sr also does. In the westernmost zone, Zone IV, the mafic rocks resemble shoshonite concerning their major elements. Some of the plutons, especially in Zones II and V, are zonally divided into marginal and central facies. The two facies are different in their K 2 O, Rb, etc. contents, and K/Rb and other ratios. In the marginal facies K 2 O and Rb are richer and K/Rb is smaller than those in the central facies. This fact suggests the different processes of magmatic differentiation in the two facies. Intrusion of the marginal facies have successively followed by that of the central facies. (author)

  1. Subsurface profiling of granite pluton using microtremor method: southern Aravalli, Gujarat, India

    Science.gov (United States)

    Joshi, Aditya U.; Sant, Dhananjay A.; Parvez, Imtiyaz A.; Rangarajan, Govindan; Limaye, Manoj A.; Mukherjee, Soumyajit; Charola, Mitesh J.; Bhatt, Meghnath N.; Mistry, Sagar P.

    2018-01-01

    We report, using the microtremor method, a subsurface granitic pluton underneath the Narukot Dome and in its western extension along a WNW profile, in proximity of eastern fringe of Cambay Rift, India. The dome and its extension is a part of the Champaner Group of rocks belonging to the Mesoproterozoic Aravalli Supergroup. The present finding elucidates development of an asymmetric double plunge along Narukot Dome. Microtremor measurements at 32 sites were carried out along the axial trace (N95°) of the dome. Fourier amplitude spectral studies were applied to obtain the ratio between the horizontal and vertical components of persisting Rayleigh waves as local ambient noise. Fundamental resonant frequencies with amplitude ≥1-sigma for each site are considered to distinguish rheological boundary. Two distinct rheological boundaries are identified based on frequency ranges determined in the terrain: (1) 0.2219-10.364 Hz recorded at 31 stations identified as the Champaner metasediment and granite boundary, and (2) 10.902-27.1119 Hz recorded at 22 stations identified as the phyllite and quartzite boundary. The proposed equation describing frequency-depth relationship between granite and overlaying regolith matches with those already published in the literature. The morphology of granite pluton highlights the rootless character of Champaner Group showing sharp discordance with granitic pluton. The findings of manifestation of pluton at a shallower depth imply a steep easterly plunge within the Champaner metasediments, whereas signature of pluton at a deeper level implies a gentle westerly plunge. The present method enables to assess how granite emplacement influences the surface structure.

  2. Results of national lake surveys 1995 in Finland, Norway, Sweden, Denmark, Russian Kola, Russian Karelia, Scotland and Wales

    Energy Technology Data Exchange (ETDEWEB)

    Henriksen, Arne; Skjelkvaale, Brit Lisa [Norsk Inst. for Vannforskning, Oslo (Norway); Mannio, Jaakko [FEI, (Finland)] [and others

    1997-12-31

    Beginning in 1995, national lake surveys were conducted in the above North European countries. This report provides the first united evaluation of lake water chemistry in Northern Europe. It was found that, except for Denmark, the water was characterized by low ionic strength and had low content of nitrogen and phosphorus. In Finland, Norway, Sweden, Russian Kola and Karelia more than 50% of the lakes had low critical load (CL) values for sulphur acidity (S), while Scotland, Wales and Denmark had very few lakes with low CL for S. The highest percentage (27%) of lakes with exceedence of CL for S was found in Norway, while the values for Russian Kola, Sweden and Finland were 17%, 9% and 9%, respectively. In Scotland and Wales, critical loads for sulphur acidity were exceeded in 1% of the total lake population. For Denmark and Russian Karelia, too few lakes were sampled to give reliable estimates. This adds up to approximately 22000 lakes in Northern Europe where CL for S was exceeded. However, this number of lakes is a minimum as exceedence of CL for N was not included in the calculation due to lack of catchment data. 26 refs., 21 figs., 13 tabs.

  3. Possible mechanism of horizontal overpressure generation of the Khibiny, Lovozero, and Kovdor ore clusters on the Kola Peninsula

    Science.gov (United States)

    Rebetsky, Yu. L.; Sim, L. A.; Kozyrev, A. A.

    2017-07-01

    The paper discusses questions related to the generation of increasing crustal horizontal compressive stresses compared to the idea of the standard gravitational state at the elastic stage or even from the prevalence of horizontal compression over vertical stress equal to the lithostatic pressure. We consider a variant of superfluous horizontal compression related to internal lithospheric processes occurrin in the crust of orogens, shields, and plates. The vertical ascending movements caused by these motions at the sole of the crust or the lithosphere pertain to these and the concomitant exogenic processes giving rise to denudation and, in particular, to erosion of the surfaces of forming rises. The residual stresses of the gravitational stressed state at the upper crust of the Kola Peninsula have been estimated for the first time. These calculations are based on the volume of sediments that have been deposited in Arctic seas beginning from the Mesozoic. The data speak to the possible level of residual horizontal compressive stresses up to 90 MPa in near-surface crustal units. This estimate is consistent with the results of in situ measurements that have been carried out at the Mining Institute of the Kola Science Center, Russian Academy of Sciences (RAS), for over 40 years. It is possible to forecast the horizontal stress gradient based on depth using our concept on the genesis of horizontal overpressure, and this forecasting is important for studying the formation of endogenic deposits.

  4. U-Pb zircon dating of the Bassies granite (Pyrenees): a syn-tectonic pluton of Westphalian age

    International Nuclear Information System (INIS)

    Paquette, J.L.

    1997-01-01

    A new U-Pb zircon age of 312 ± 2 Ma for the Bassies pluton (Pyrenees) contradicts the previous whole-rock Rb-Sr dating at 276 ± 16 Ma, which was considered as the age of emplacement, therefore regarded as post-tectonic. The new date is in agreement with recent structural studies which suggest a Hercynian syn-tectonic emplacement for the Bassies pluton. These results strengthen the few U-Pb ages already published for the Pyrenean granites and indicate that the Hercynian plutonism of the Pyrenees is essentially Carboniferous in age and syn-tectonic. (authors)

  5. Detection of pollution-induced forest decline in the Kola Peninsula using remote sensing and mathematical modelling

    International Nuclear Information System (INIS)

    Rigina, Olga

    1998-01-01

    Forests on the Kola Peninsula in Northern Russia grow close to the northern tree line. They are subjected to both natural and anthropogenic stress factors. The Cu-Ni smelter 'Severonikel' (Lat. 67 deg 55'N; Long. 32 deg 57'E) near Monchegorsk is one of the two major sources of sulphur dioxide and heavy metals emissions on the Kola Peninsula. These emissions have caused significant deterioration of the surrounding vegetation. The thesis demonstrates how methods of Remote sensing, ground survey and mathematical modelling can be integrated for monitoring of the smelter's environmental impact on the surrounding vegetation: ground truth data are used for calibration of remote-sensed data, which further serve to verify mathematical models. The study aims were: * to estimate the scale of airborne sulphur pollution from the smelting industry on the Kola Peninsula and its effect on vegetation; * to assess spatial extent of the forest decline in the 'Severonikel' smelter impact zone; * to display dynamics of the forest damage area in spatial and temporal perspective; * to validate the Gaussian plume sector model and the IIASA forest impact model as components of the analysis of forest damage. The Regional Acidification Information and Simulation model (RAINS) was applied to calculate sulphur deposition and loads in Fennoscandia in order to assess the contribution of the Kola sources to the deposition pattern in the region. The percentage of the ecosystems where the critical load had been exceeded was calculated. For more detailed assessments, calculations based on local and meso-scale models were made. Landsat-MSS summer images from 1978, 1986 and 1992 and a Landsat -TM image from 1996 were used for change-detection analyses. The methods applied were bandwise histogram matching and subsequent differencing. An unsupervised classification of land-cover was made using the 1996 Landsat-TM image. In situ observations of vegetation type and degradation levels on permanent field

  6. Detection of pollution-induced forest decline in the Kola Peninsula using remote sensing and mathematical modelling

    Energy Technology Data Exchange (ETDEWEB)

    Rigina, Olga

    1998-07-01

    Forests on the Kola Peninsula in Northern Russia grow close to the northern tree line. They are subjected to both natural and anthropogenic stress factors. The Cu-Ni smelter 'Severonikel' (Lat. 67 deg 55'N; Long. 32 deg 57'E) near Monchegorsk is one of the two major sources of sulphur dioxide and heavy metals emissions on the Kola Peninsula. These emissions have caused significant deterioration of the surrounding vegetation. The thesis demonstrates how methods of Remote sensing, ground survey and mathematical modelling can be integrated for monitoring of the smelter's environmental impact on the surrounding vegetation: ground truth data are used for calibration of remote-sensed data, which further serve to verify mathematical models. The study aims were: * to estimate the scale of airborne sulphur pollution from the smelting industry on the Kola Peninsula and its effect on vegetation; * to assess spatial extent of the forest decline in the 'Severonikel' smelter impact zone; * to display dynamics of the forest damage area in spatial and temporal perspective; * to validate the Gaussian plume sector model and the IIASA forest impact model as components of the analysis of forest damage. The Regional Acidification Information and Simulation model (RAINS) was applied to calculate sulphur deposition and loads in Fennoscandia in order to assess the contribution of the Kola sources to the deposition pattern in the region. The percentage of the ecosystems where the critical load had been exceeded was calculated. For more detailed assessments, calculations based on local and meso-scale models were made. Landsat-MSS summer images from 1978, 1986 and 1992 and a Landsat -TM image from 1996 were used for change-detection analyses. The methods applied were bandwise histogram matching and subsequent differencing. An unsupervised classification of land-cover was made using the 1996 Landsat-TM image. In situ observations of vegetation type and

  7. Amphibole Thermometry and a Comparison of Results from Plutonic and Volcanic Systems

    Science.gov (United States)

    Sherman, T. M.; Putirka, K. D.; De Los Reyes, A. M. A.; Ratschbacher, B. C.

    2015-12-01

    Recent work (Ridolfi and Renzulli 2014) shows that amphiboles can be used to infer magmatic temperatures, even without knowledge of co-existing liquids. Here, we apply this approach, using new calibrations, to investigate felsic-mafic magma interactions, in a volcanic (Lassen Volcanic Center, a Cascade volcano) and plutonic (the Jurassic Guadalupe Igneous Complex) system. Preliminary data suggest that volcanic processes, as might be expected, preserve higher temperatures than plutonic materials (on average, volcanic amphiboles recorded 907±57.3°C while plutonic amphiboles recorded 764±59.7°C). We also find that the average T of a given mineral grain decreases with increased mineral size such that those crystallized below 800°C sometimes reach sizes beyond ~1mm, while those near 900°C appear truncated to ~0.3mm. It is not clear if T is the only control on amphibole crystal growth; however, our results would imply that larger grains not only require more time to grow but require continued undercooling. Significant cooling or heating is also recorded in many volcanically- and plutonically-grown grains, which may reflect transitioning between magmas of different T and composition. Core-to-rim cooling trends (with a common T of drop of 80oC) likely represent mafic-to-felsic magma transitions, whereas core-to-rim heating of similar magnitudes indicate a felsic-mafic transition. Some grains, though, exhibit a constant T (in the range 700-900°C) from core to rim, which perhaps indicates some shielding from magma mixing processes. Amphiboles might thus provide a reliable record of the intensity of magma mingling and mixing experienced by any particular enclave. Interestingly, volcanically-derived amphiboles appear to mostly record cooling towards the rims, while their plutonic counterparts tend to experience heating. It would thus appear that at Lassen, amphiboles are unaffected by later mafic magma recharge, but at the GIC, the plutonic amphiboles are more likely to

  8. The rapakivi granite plutons of Bodom and Obbnäs, southern Finland: petrography and geochemistry

    Directory of Open Access Journals (Sweden)

    Kosunen, P.

    1999-12-01

    Full Text Available The Obbnäs and Bodom granite plutons of southernmost Finland show the typical petrographic and geochemical features of the Proterozoic rapakivi granites in Finland and elsewhere: they cut sharply across the 1900 Ma Svecofennian metamorphic bedrock and have the geochemical characteristics of subalkaline A-type granites. The Bodom pluton is composed of porphyritic granites (hornblende-, hornblende-biotite-, and biotite-bearing varieties and an even-grained granite that probably represent two separate intrusive phases. This lithologic variation does not occur in the Obbnäs pluton, which is almost entirely composed of porphyritic hornblende-biotite granite that gradually becomes more mafic to the southwest. Three types of hybrid granitoids resulting from magma mingling and mixing occur on the southwestern tip of the Obbnäs peninsula. The Bodom granites are syenogranites, whereas the composition of the Obbnäs granite varies from syeno- to monzogranite. The main silicates of both the Bodom and Obbnäs granites are quartz, microcline, plagioclase (An1541, biotite (siderophyllite, and generally also amphibole (ferropargasite or hastingsite. Plagioclase-mantled alkali feldspar megacrysts are absent or rare. The accessory minerals are fluorite, allanite, zircon, apatite, and iron-titanium oxides; the Obbnäs granite also contains titanite. The Bodom and Obbnäs granites are metaluminous to weakly peraluminous, with average A/CNK of 1.00 and 1.05, respectively, have high Fe/Mg (average FeOtot/[FeOtot+MgO] is 0.94 for the Bodom and 0.87 for the Obbnäs granites, and high Ga/Al (3.78 to 5.22 in Bodom and 2.46 to 4.18 in Obbnäs. The REE contents are high with LREE-enriched chondrite-normalized patterns and moderate (Obbnäs to relatively strong (Bodom negative Eu-anomalies. The Obbnäs granite is enriched in CaO, TiO2, MgO, and FeO, and depleted in SiO2 and K2O compared to the Bodom granites. Also, there are differences in the Ba, Rb, and Sr contents of

  9. [Impact of industrial pollution on emission of carbon dioxide by soils in the Kola Subarctic Region].

    Science.gov (United States)

    Koptsik, G N; Kadulin, M S; Zakharova, A I

    2015-01-01

    Soil emission of carbon dioxide, the key component of carbon cycle and the characteristic of soil biological activity, has been studied in background and polluted ecosystems in the Kola subarctic, the large industrial region of Russia. Long-term air pollution by emissions of "Pechenganikel" smelter, the largest source of sulphur dioxide and heavy metals in Northern Europe, has caused the technogenic digression of forest ecosystems. As a result of the digression, the tree layer was destructed, the number of plant species was diminished, the activity of soil biota was weakened, the soils were polluted and exhausted, biogeochemical cycles of elements were disturbed and productivity of ecosystems shrunk. Field investigations revealed the decrease of the in.situ soil respiration in average from 190-230 mg C-CO2/m2 x per h in background pine forests to 130-160, 100, and 20 mg C-CO2/m2.per h at the stages of pine defoliation, sparse pine forest and technogenic barrens of the technogenic succession, respectively. The soil respira- tion in birch forests was more intense than in pine forests and tended to decrease from about 290 mg C-CO2/m2 x per h in background forests to 210-220 and 170-190 mg C-CO2/m2 x per h in defoliating forests and technogenic sparse forests, respectively. Due to high spatial variability of soil respiration in both pine and birch forests significant differences from the background level were found only in technogenic sparse forests and barrens. Soil respiration represents total production of carbon dioxide by plant roots and soil microorganisms. The decrease in share of root respiration in the total soil respiration with the rise of pollution from 38-57% in background forests up to zero in technogenic barrens has been revealed for the first time for this region. This indicates that plants seem to be more sensitive to pollution as compared to relatively resistant microorganisms. Soil respiration and the contribution of roots to the total respiration

  10. Science, sulphur and sustainability. Environmental strategies of mining in the russian Kola peninsula

    Energy Technology Data Exchange (ETDEWEB)

    Salmi, O.H.

    2008-07-01

    This dissertation analyses the problem of co-aligning corporate strategy and public policy for effective environmental governance. A case study of the mining industry in the Russian Kola Peninsula shows how institutional arrangements (including public policies) affect the environmental performance of industrial organizations. The analysis emphasizes the motivations that drive people's decisions and how they are affected by culture and formal institutions both inside and outside the domain of public policy. It bridges management and governance studies with an added focus on engineering approaches to sustainability. In substantial terms, the dissertation has a strong focus on 'complex utilization', which has been a common environmental and natural resource strategy in Russia since the 1930s. In an important respect, complex utilization both antedates and closely resembles industrial ecology that has been developed in the West. This suggests that a lack of technical knowledge was not the principal cause of the well-known environmental problems that existed in the Soviet Union. On the contrary, the potential benefits of complex utilization were not realized because Soviet political and economic institutions provided weak incentives for pollution control and efficient resource use. The central theoretical effort of this dissertation is to show how effective environmental governance is contingent upon emergent strategy and policy processes. Both corporate environmental strategy and public environmental policy depend on power relations and network building among a variety of actors in the society. The case study yields three different emergent processes: political embedding of scientific concepts, cultural contextualization of indicators, and legitimacy in stakeholder salience. The dissertation also delivers policy recommendations pertaining to the future development of the Barents Euro-Arctic region. This future depends both on the level of political

  11. Garcinia kola seeds may prevent cognitive and motor dysfunctions in a type 1 diabetes mellitus rat model partly by mitigating neuroinflammation.

    Science.gov (United States)

    Seke Etet, Paul F; Farahna, Mohammed; Satti, Gwiria M H; Bushara, Yahia M; El-Tahir, Ahmed; Hamza, Muaawia A; Osman, Sayed Y; Dibia, Ambrose C; Vecchio, Lorella

    2017-04-15

    Background We reported recently that extracts of seeds of Garcinia kola, a plant with established hypoglycemic properties, prevented the loss of inflammation-sensible neuronal populations like Purkinje cells in a rat model of type 1 diabetes mellitus (T1DM). Here, we assessed G. kola extract ability to prevent the early cognitive and motor dysfunctions observed in this model. Methods Rats made diabetic by single injection of streptozotocin were treated daily with either vehicle solution (diabetic control group), insulin, or G. kola extract from the first to the 6th week post-injection. Then, cognitive and motor functions were assessed using holeboard and vertical pole behavioral tests, and animals were sacrificed. Brains were dissected out, cut, and processed for Nissl staining and immunohistochemistry. Results Hyperglycemia (209.26 %), body weight loss (-12.37 %), and T1DM-like cognitive and motor dysfunctions revealed behavioral tests in diabetic control animals were not observed in insulin and extract-treated animals. Similar, expressions of inflammation markers tumor necrosis factor (TNF), iba1 (CD68), and Glial fibrillary acidic protein (GFAP), as well as decreases of neuronal density in regions involved in cognitive and motor functions (-49.56 % motor cortex, -33.24 % medial septal nucleus, -41.8 % /-37.34 % cerebellar Purkinje /granular cell layers) were observed in diabetic controls but not in animals treated with insulin or G. kola. Conclusions Our results indicate that T1DM-like functional alterations are mediated, at least partly, by neuroinflammation and neuronal loss in this model. The prevention of the development of such alterations by early treatment with G. kola confirms the neuroprotective properties of the plant and warrant further mechanistic studies, considering the potential for human disease.

  12. Map showing the distribution and characteristics of plutonic rocks in the Tonopah 1 degree by 2 degrees Quadrangle, central Nevada

    Science.gov (United States)

    John, D.A.

    1987-01-01

    Plutonic rocks, mostly granite and granodiorite, are widely distributed in the west two-thirds of the Tonopah 1 degree by 2 degree quadrangle, Nevada. These rocks were systematically studied as part of the Tonopah CUSMAP project. Studies included field mapping, petrographic and modal analyses, geochemical studies of both fresh and altered plutonic rocks and altered wallrocks, and K-Ar and Rb-Sr radiometric dating. Data collected during this study were combined with previously published data to produce a 1:250,000-scale map of the Tonopah quadrangle showing the distribution of individual plutons and an accompanying table summarizing composition, texture, age, and any noted hydrothermal alteration and mineralization effects for each pluton.

  13. River Valley pluton, Ontario - A late-Archean/early-Proterozoic anorthositic intrusion in the Grenville Province

    Science.gov (United States)

    Ashwal, Lewis D.; Wooden, Joseph L.

    1989-01-01

    This paper presents Nd, Sr, and Pb isotopic data indicating a late-Archean/early-Proterozoic age for the River Valley anorthositic pluton of the southwestern Grenville Province of Sudbury, Ontario. Pb-Pb isotopic data on 10 whole-rock samples ranging in composition from anorthosite to gabbro yield an age of 2560 + or - 155 Ma. The River Valley pluton is thus the oldest anorthositic intrusive yet recognized within the Grenville Province. The Sm-Nd isotopic system records an age of 2377 + or - 68 Ma. High Pb-208/Pb-204 of deformed samples relative to igneous-textured rocks implies Th introduction and/or U loss during metamorphism in the River Valley area. Rb-Sr data from igneous-textured and deformed samples and from mineral separates give an age of 2185 + or - 105 Ma, indicating substantial disturbance of the Rb-Sr isotopic system.

  14. Geology, geochemistry, age and tectonic setting of the Gore-Gambella plutonic rocks, western Ethiopia

    Energy Technology Data Exchange (ETDEWEB)

    Alemayehu, T.A.

    1989-01-01

    In transect across the Birbir and Baro domains of western Ethiopia, distinct granitoid suites are recognized on the basis of their field relations, petrology, chemical features and age. The Baro Domain consists of migmatitic, upper amphibolite facies gneisses and metaleucogranites. The Birbir Domain consists of lower amphibolite facies rocks with abundant intrusive and meta-intrusive rocks of mafic and intermediate composition. A ductile, transcurrent fault system, the Birbir Shear Zone, traverses the Birbir Domain. Kinematic indicators such as disrupted dykes and sills within the shear zone suggest major dextral movement which was succeeded by sinistral movement during its final stage. The pre- to syn-kinematic intrusives within the Birbir Domain are metamorphosed and mylonitized to variable degrees. Geochemical and isotopic data from early plutonic units in the Birbir Domain reflect arc-type igneous activity; late- to post-kinematic plutons are more alkalic and of intraplate character. U-Pb zircon and Rb-Sr whole-rock isochron dates show plutonic activity between 830 and 540 Ma. A whole-rock Rb-Sr date of 760 Ma from a pre- to syn-kinematic pluton coincides with the age of low-grade metamorphism of arc-related rocks of the Red Sea Hills of NE Africa and the Jeddah terrane of Arabia. The Birbir Domain is a southward extension of the Pan-African crust of NE Africa and Arabia. The Birbir shear zone indicates a tectonically active continental margin along which magmatic arc rocks were accreted. The Baro Domain is interpreted as a reactivated pre-Pan-African continental margin linked to the Mozambique Belt of east Africa. A subduction model, involving closure of an ocean basin, is proposed for the evolution of rocks of the Birbir Domain.

  15. The role of pegmatites and acid fluids for REE/HFSE mobilization in the Strange Lake peralkaline granitic pluton, Canada

    Science.gov (United States)

    Gysi, A. P.; Williams-Jones, A.

    2012-12-01

    The Strange Lake pluton in Canada is a mid-Proterozoic peralkaline granitic intrusion that is host to a world-class rare earth element (REE), yttrium (Y) and high-field strength element (HFSE) deposit containing more than 50 Mt ore at >1.5 wt.% REE and >3 wt.% Zr. The highest REE/HFSE concentrations are found in pegmatite-rich zones characterized by intense alteration. Previous studies of Strange Lake and other peralkaline and alkaline intrusions, such as Khan Bogd (Mongolia) and Tamazeght (Morocco) plutons have shown that hydrothermal alteration may play an important role in the mobility of the REE/HFSE. However, the fluid chemistry and conditions of alteration (i.e., P, T, pH, fO2, ligand activity) in these systems still need to be constrained to evaluate the importance and scale of such hydrothermal mobilization. We present new data from the B-zone, a pegmatite-rich zone located in NW Strange Lake. The pegmatites are generally zoned and form two main types. The border-type pegmatites consist of quartz, K-feldspar and hematized aegirine, whereas volatile-rich pegmatites consist of hydrothermal quartz and fluorite. Transitions between both types were also observed, with the K-feldspar being partly altered and replaced by Al-Si-rich phyllosilicates. The heavy (H)REE and Zr were primarily concentrated in zirconosilicates such as elpidite, now pseudomorphed by zircon or gittinsite, whereas light (L)REE and Y were concentrated in REE-F-(CO2)-minerals such as fluocerite and bastnäsite. Textural and mineralogical observations indicate that these minerals are primary and were partly to completely leached upon fluid-rock interaction in the pegmatites. Secondary phases include Ca-F-Y-rich minerals, mainly hydrothermal fluorite, that fill vugs and replaced primary REEHFSE minerals. The presence of hydrothermal fluorite veins, micro-veins, vugs and micro-breccia in the most altered parts of the B-zone are interpreted to reflect interaction of the rocks with a F-rich fluid

  16. Radiogeologic assessment for nuclear waste isolation: studies of the Stripa pluton

    International Nuclear Information System (INIS)

    Wollenberg, H.; Flexser, S.; Andersson, L.

    1982-01-01

    To properly characterize candidate sites for radioactive waste isolation, it will be necessary to obtain a good understanding of their radiogeologic settings. The distribution and abundance of the naturally occurring radioelements - 238 U, 232 Th, their daughters, and 40 K, both in the rock mass encompassing the repository and in the neighboring rocks - constitute the baseline upon which the effects of the radioactive waste are superimposed. The distribution of these radioelements is also a good indicator of the geochemical homogeneity of the rock mass. At the Stripa experimental facility in an inactive iron mine in central Sweden, radiogeologic studies included gamma-spectrometric surveys, on the surface and underground, of the U, Th, and K contents of the quartz monzonite pluton encompassing the experiments, the high-grade metamorphic rocks surrounding the pluton, and the neighboring larger granitic plutons. The gamma-spectral surveys were calibrated by laboratory analyses of hand specimens and drill cores, permitting calculation of radioelement concentrations from field counting rates

  17. Erupted frothy xenoliths may explain lack of country-rock fragments in plutons

    Science.gov (United States)

    Burchardt, Steffi; Troll, Valentin R.; Schmeling, Harro; Koyi, Hemin; Blythe, Lara

    2016-01-01

    Magmatic stoping is discussed to be a main mechanism of magma emplacement. As a consequence of stoping, abundant country-rock fragments should occur within, and at the bottom of, magma reservoirs as “xenolith graveyards”, or become assimilated. However, the common absence of sufficient amounts of both xenoliths and crustal contamination have led to intense controversy about the efficiency of stoping. Here, we present new evidence that may explain the absence of abundant country-rock fragments in plutons. We report on vesiculated crustal xenoliths in volcanic rocks that experienced devolatilisation during heating and partial melting when entrained in magma. We hypothesise that the consequential inflation and density decrease of the xenoliths allowed them to rise and become erupted instead of being preserved in the plutonic record. Our thermomechanical simulations of this process demonstrate that early-stage xenolith sinking can be followed by the rise of a heated, partially-molten xenolith towards the top of the reservoir. There, remnants may disintegrate and mix with resident magma or erupt. Shallow-crustal plutons emplaced into hydrous country rocks may therefore not necessarily contain evidence of the true amount of magmatic stoping during their emplacement. Further studies are needed to quantify the importance of frothy xenolith in removing stoped material. PMID:27804996

  18. Seychelles alkaline suite records the culmination of Deccan Traps continental flood volcanism

    Science.gov (United States)

    Owen-Smith, T. M.; Ashwal, L. D.; Torsvik, T. H.; Ganerød, M.; Nebel, O.; Webb, S. J.; Werner, S. C.

    2013-12-01

    Silhouette and North Islands in the Seychelles represent an alkaline plutonic-volcanic complex, dated at 63 to 63.5 Ma by U-Pb zircon and 40Ar/39Ar methods. This magmatism coincides with the final stages of the cataclysmic Deccan Traps continental flood volcanism in India (67 to 63 Ma), and thus a causal link has been suggested. Recent reconstructions have placed the Seychelles islands adjacent to the Laxmi Ridge and at the western margin of the Réunion mantle plume at the time of formation of the complex. Here we present geochemical evidence in support of the notion that the Seychelles alkaline magmatism was initiated by the peripheral activity of the Réunion mantle plume and is thus part of the Deccan magmatic event. Positive εNd (0.59 to 3.76) and εHf (0.82 to 6.79) and initial Sr of 0.703507 to 0.705643 at 65 Ma indicate derivation of the Seychelles alkaline magmas from a Réunion-like mantle source with an additional minor enriched component, suggesting entrainment of sub-continental lithospheric mantle. The similarity in trace element composition between the Seychelles suite and Deccan alkaline felsic and mafic rocks provides additional evidence for a common mantle source for the Seychelles and Deccan magmatism. Furthermore, we demonstrate the role of fractional crystallisation in the evolution of the alkaline suite. Modelling using major elements suggests that fractional crystallisation and varying degrees of accumulation of olivine, plagioclase, ilmenite, clinopyroxene, alkali feldspar and apatite can describe the spectrum of rock types, from gabbro, through syenite, to granite.

  19. Cryogenian alkaline magmatism in the Southern Granulite Terrane, India: Petrology, geochemistry, zircon U-Pb ages and Lu-Hf isotopes

    Science.gov (United States)

    Santosh, M.; Yang, Qiong-Yan; Ram Mohan, M.; Tsunogae, T.; Shaji, E.; Satyanarayanan, M.

    2014-11-01

    The Southern Granulite Terrane (SGT) in India preserves the records of the formation and recycling of continental crust from Mesoarchean through Paleoproterozoic to Neoproterozoic and Cambrian, involving multiple subduction-accretion-collision associated with major orogenic cycles. A chain of unmetamorphosed and undeformed alkaline magmatic intrusions occurs along the northern margin of the SGT aligned along paleo-suture zones. Here we investigate two representative plutons from this suite, the Angadimogar syenite (AM) and the Peralimala alkali granite (PM) through field, petrological, geochemical, zircon U-Pb and Lu-Hf studies. Magma mixing and mingling textures and mineral assemblages typical of alkaline rocks are displayed by these plutons. The whole-rock major and trace element data characterize their alkaline nature. In trace element discrimination diagrams, the AM rocks straddle between the VAG (volcanic-arc granites) and WPG (within plate granites) fields with most of the samples confined to the VAG field, whereas the PM rocks are essentially confined to the WPG field. The diversity in some of the geochemical features between the two plutons is interpreted to be the reflection of source heterogeneities. Most zircon grains from the AM and PM plutons display oscillatory zoning typical of magmatic crystallization although some grains, particularly those from the PM pluton, show core-rim structures with dark patchy zoned cores surrounded by irregular thin rims resulting from fluid alteration. The weighted mean 206Pb/238U ages of the magmatic zircons from three samples of the AM syenite are in the range of 781.8 ± 3.8 Ma to 798 ± 3.6 Ma and those from two samples of the PM alkali granite yield ages of 797.5 ± 3.7 Ma and 799 ± 6.2 Ma. A mafic magmatic enclave from the AM pluton shows weighted mean 206Pb/238U age of 795 ± 3.3 Ma. The AM and PM plutons also carry rare xeneocrystic zircons which define upper intercept concordia ages of 3293 ± 13 Ma and 2530

  20. Characteristics and mode of emplacement of gneiss domes and plutonic domes in central-eastern Pyrenees

    Science.gov (United States)

    Soula, Jean-Claude

    Gneiss domes and plutonic granitoid domes make up almost 50% of the pre-Hercynian terrains in the Central and Eastern Pyrenees. From a structural study of the shape and internal structure of the domes and of their relationships with the enclosing rocks, it can be shown that both types of domes were emplaced diapirically during the major regional deformation phase and the peak of regional metamorphism. The study also shows that the internal structure, the overall shape and general behaviour relative to the host rocks are similar for plutonic domes and for gneiss domes. This appears to be in good agreement with H. Ramberg's (1967, Gravity Deformation and the Earth's Crust. Academic Press, London; 1970, Model studies in relation to intrusion of plutonic bodies. In: Mechanisms of Igneous Intrusion (edited by Newall, G. & Rast, N.) Geol. J. Spec. Issue2, 261-286.) model studies showing that dome or mushroom-like structures, similar to those observed, develop when there is a small viscosity ratio between the rising body and its enclosing medium. This implies a high crystal content for the granitoid magma. This crystal content has been estimated by (i) calculating the viscosity and density in natural conditions from petrological data for the magma considered as a suspension, using the model and program of J. P. Carron et al. (1978 Bull Soc. géol. Fr.20, 739-744.); (ii) using the recent results of experimental deformation of partially melted granites of I. van der Molen & M. S. Paterson (1979, Contr. Miner. Petrol.70, 299-318.) and (ii) comparing the preceding results with the data obtained by deformation experiments on rocks similar to those enclosing the domes. The minimum crystal content for the development of a dome-like structure has been, thus, estimated to about 70%, i.e. a value very close to that estimated by van der Molen & Paterson (1979) to be the critical value separating the granular framework flow from suspension-like behaviour. The effect of small

  1. Exterior indicators and physiological signs' indices of juveniles Salmo salar L. in the rivers of the Kola Peninsula

    Directory of Open Access Journals (Sweden)

    Anokhina V. S.

    2017-06-01

    Full Text Available The range of background values of main parameters of the exterior and indices of morphophysiological features of autumn juvenile salmon Salmon salar L. in four rivers of the Kola Peninsula not affected by hatchery production have been investigated. The importance of such studies is associated with intensification of artificial reproduction of salmon and occurrence of hatchery fish with characters different from wild individuals in the rivers. Currently hatchery reproduction of Atlantic salmon is not carried out in the European North of Russia, however, the need to choose a local salmon population for further hatchery reproduction is obvious. Accumulation of biological data on salmon in the rivers of the Kola Peninsula is important for population monitoring of wild stocks. Samples of juveniles widely varying in size have been collected by electrofishing in the Rivers Pechenga, Zapadnaya Litsa and Titovka of the Barents Sea basin, as well as in the tributaries of the River Varzuga inflowing the White Sea. For each sample individual and group indices of elongation, girth and massiveness have been calculated. The physiological state of the fish has been assessed with allowance for the fatness factor (according to Clark and indices of internal organs. It has been found that in the autumn season (September the average statistical values of the morphological indices characterizing the appearance of the fry from four rivers differ with a high degree of reliability. Individual fluctuations in morphological parameters are in the range of values: elongation – from 311 to 725 %; girth – from 41 to 85 %; massiveness – from 150 to 530 %. The mean values of morphophysiological indices for each of the four river populations have been presented. The obtained values of the studied parameters of juveniles of Atlantic salmon can be used for subsequent monitoring of populations.

  2. Sample preparation in alkaline media

    International Nuclear Information System (INIS)

    Nobrega, Joaquim A.; Santos, Mirian C.; Sousa, Rafael A. de; Cadore, Solange; Barnes, Ramon M.; Tatro, Mark

    2006-01-01

    The use of tetramethylammonium hydroxide, tertiary amines and strongly alkaline reagents for sample treatment involving extraction and digestion procedures is discussed in this review. The preparation of slurries is also discussed. Based on literature data, alkaline media offer a good alternative for sample preparation involving an appreciable group of analytes in different types of samples. These reagents are also successfully employed in tailored speciation procedures wherein there is a critical dependence on maintenance of chemical forms. The effects of these reagents on measurements performed using spectroanalytical techniques are discussed. Several undesirable effects on transport and atomization processes necessitate use of the method of standard additions to obtain accurate results. It is also evident that alkaline media can improve the performance of techniques such as inductively coupled plasma mass spectrometry and accessories, such as autosamplers coupled to graphite furnace atomic absorption spectrometers

  3. Geology, petrology and U-Pb geochronology of Serra da Rajada Granitic Pluton: implications about ediacaran magmatic evolution in NE portion of the Rio Piranhas-Serido Domain (NE of Borborema Province); Geologia, petrologia e geocronologia U-Pb do Pluton Granitico Serra da Rajada: implicacoes sobre a evolucao magmatica ediacarana na porcao do Dominio Rio Piranhas-Serido (NE da Provincia Borborema)

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Alan Pereira da; Dantas, Alexandre Ranier, E-mail: alan.costa@cprm.gov.br, E-mail: alexandre.dantas@cprm.gov.br [Servico Geologico do Brasil (CPRM), Natal, RN (Brazil). Nucleo de Apoio de Natal/Superintendencia Regional de Recife; Nascimento, Marcos Antonio Leite do; Galindo, Antonio Carlos, E-mail: marcos@geologia.ufrn.br, E-mail: galindo@geologia.ufrn.br [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Departamento de Geologia

    2015-12-15

    The Ediacaran plutonic activity, related to the Brazilian/Pan-African orogeny, is one of the most important geological features in the Borborema Province, formed by batholiths, stocks and dikes. The Serra da Rajada Granitic Pluton (SRGP), located in the central portion of the Rio Piranhas-Serido Domain, is an example of these bodies. This site is the target of cartographic, petrographic, lithochemical and geochronological studies. Its rocks are described as monzogranites consisting of K-feldspar, plagioclase (oligoclase-An{sub 23-24%}), quartz and biotite (main mafic), having as accessory minerals opaque, titanite, allanite, apatite and zircon. Chlorite, white mica and carbonate are alteration minerals. Lithochemical data from 15 samples show quite evolved rocks (SiO{sub 2} , 69% to 75%), rich in alkalis (Na{sub 2}O + K{sub 2}O ≥ 8.0%), depleted in MgO (≤ 0.45%), CaO (≤ 1.42%) and TiO{sub 2} (≤ 0.36%), and displaying moderate levels of Fe{sub 2}O{sub 3} t (2.16 to 3.53%). These rocks present a transitional nature between metaluminous and peraluminous (predominance of the latter) and have subalkaline/monzonitic affinity (high-K Calc-alkaline). Harker diagrams represent negative correlations in Fe{sub 2}O{sub 3}t, MgO and CaO, indicating fractionation of mafic and plagioclase. The REE spectrum show enrichment of light in relation to heavy REE (LaN/YbN = 23.70 to 10.13), with negative anomaly in Eu (Eu/ Eu* = 0.70 to 10.13) suggesting fractionation or accumulation in the feldspars source (plagioclase). Data integration allows correlating the SRGP rocks with those described as Equigranular high-K Calc-alkaline Suite. The U-Pb geochronology and Sm-Nd isotope dating indicate that the biotite monzogranite have a crystallization age of 557 ± 13 Ma and TDM model age of 2.36 Ga, respectively, and ε{sub Nd} value of - 20.10 for the crystallization age, allowing to infer a crustal source for the magma generated in the Paleoproterozoic age. (author)

  4. Crystal structure of modular sodium-rich and low-iron eudialyte from Lovozero alkaline massif

    Energy Technology Data Exchange (ETDEWEB)

    Rozenberg, K. A.; Rastsvetaeva, R. K., E-mail: rast@ns.crys.ras.ru; Aksenov, S. M. [Federal Scientific Research Center “Crystallography and Photonics”, Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)

    2016-09-15

    The structure of the sodium-rich representative of the eudialyte group found by A.P. Khomyakov at the Lovozero massif (Kola Peninsula) is studied by X-ray diffraction. The trigonal cell parameters are: a = 14.2032(1) and c = 60.612(1) Å, V = 10589.13 Å3, space group R3m. The structure is refined to the final R = 5.0% in the anisotropic approximation of atomic displacement parameters using 3742|F| > 3σ(F). The idealized formula (Z = 3) is Na{sub 37}Ca{sub 10}Mn{sub 2}FeZr{sub 6}Si{sub 50}(Ti, Nb){sub 2}O{sub 144}(OH){sub 5}Cl{sub 3} · H{sub 2}O. Like other 24-layer minerals of the eudialyte group, this mineral has a modular structure. Its structure contains two modules, namely, “alluaivite” (with an admixture of “eudialyte”) and “kentbrooksite,” called according to the main structural fragments of alluaivite, eudialyte, and kentbrooksite. The mineral found at the Lovozero alkaline massif shows some chemical and symmetry-structural distinctions from the close-in-composition labyrinthite modular mineral from the Khibiny massif. The difference between the minerals stems from different geochemical conditions of mineral formation in the two regions.

  5. Depositional features and stratigraphic sections in granitic plutons: implications for the emplacement and crystallization of granitic magma

    Science.gov (United States)

    Wiebe, R. A.; Collins, W. J.

    1998-09-01

    Many granitic plutons contain sheet-like masses of dioritic to gabbroic rocks or swarms of mafic to intermediate enclaves which represent the input of higher temperature, more mafic magma during crystallization of the granitic plutons. Small-scale structures associated with these bodies (e.g. load-cast and compaction features, silicic pipes extending from granitic layers into adjacent gabbroic sheets) indicate that the sheets and enclave swarms were deposited on a floor of the magma chamber (on granitic crystal mush and beneath crystal-poor magma) while the mafic magma was incompletely crystallized. These structures indicate 'way up', typically toward the interior of the intrusions, and appear to indicate that packages of mafic sheets and enclave concentrations in these plutons are a record of sequential deposition. Hence, these plutons preserve a stratigraphic history of events involved in the construction (filling, replenishment) and crystallization of the magma chamber. The distinctive features of these depositional portions of plutons allow them to be distinguished from sheeted intrusions, which usually preserve mutual intrusive contacts and 'dike-sill' relations of different magma types. The considerable thickness of material that can be interpreted as depositional, and the evidence for replenishment, suggest that magma chamber volumes at any one time were probably much less than the final size of the pluton. Thus, magma chambers may be constructed much more slowly than presently envisaged. The present steep attitudes of these structures in many plutons may have developed gradually as the floor of the chamber (along with the underlying solidified granite and country rock) sank during continuing episodes of magma chamber replenishment. These internal magmatic structures support recent suggestions that the room problem for granites could be largely accommodated by downward movement of country rock beneath the magma chamber.

  6. New petrographic, geochemical and geochronological data for the Reguengos de Monsaraz pluton (Ossa Morena Zone, SW Iberian Massif, Portugal

    Directory of Open Access Journals (Sweden)

    Antunes, A.

    2010-06-01

    Full Text Available The Reguengos de Monsaraz pluton is a late to post-tectonic Variscan intrusion occurring in the Ossa Morena Zone (Iberian Variscan Chain. The dominant lithological types are tonalites and granodiorites, but the internal area of the massif is composed of gabbro-dioritic rocks. Field evidence shows that the intrusion is heterogeneous at mesoscopic scale suggesting that the emplacement of mafic and felsic magmas was contemporaneous. Petrographic and geochemical studies reveal that the different lithologic types define a continuous sequence with compositions varying from metaluminous to slightly peraluminous and a typical calc-alkaline signature. In Harker variation diagrams, it is possible to observe systematic rectilinear correlations pointing to the involvement of magma mingling/mixing processes in the petrogenesis of this sequence. Rb-Sr isotopic data, using a mineral-mineral pair from a granodiorite sample, yielded an age of 298 Ma, interpreted as a cooling age after igneous crystallization.

    El plutón de Reguengos de Monsaraz es una intrusión varisca tardi- a post- tectónica localizada en la Zona de Ossa Morena (Cadena Varisca Ibérica. Los tipos litológicos dominantes son las tonalitas y las granodioritas aunque la zona mas interna del macizo está formada por rocas gabro-dioríticas. Las evidencias de campo muestran que todos los tipos litológicos son heterogéneos a escala mesoscópica y sugieren que el emplazamiento de los magmas máficos y félsicos fue contemporáneo. Los estudios petrográficos y geoquímicos muestran que los diferentes litotipos definen una secuencia continua con una afinidad calcoalcalina típica y composiciones variando desde metaluminosas a peraluminosas. En los diagramas de Harker se observan correlaciones rectilíneas sistemáticas, lo que sugiere que la mezcla de magmas tuvo un papel decisivo en su petrogénesis. Los datos isotópicos de Rb-Sr, usando un par mineral-mineral de una granodiorita

  7. PURIFICATION AND CHARACTERISATION OF ALKALINE ...

    African Journals Online (AJOL)

    Prof. Adipala Ekwamu

    There was no clear decrease in the yield seen in the bands and the loss of enzyme was not observed with the gel analysis. It may ... The native gel results show clear distinct bands for the 3 alkaline phosphotase isoenzymes ..... British Medical.

  8. Source and fractionation controls on subduction-related plutons and dike swarms in southern Patagonia (Torres del Paine area) and the low Nb/Ta of upper crustal igneous rocks

    Science.gov (United States)

    Müntener, Othmar; Ewing, Tanya; Baumgartner, Lukas P.; Manzini, Mélina; Roux, Thibaud; Pellaud, Pierre; Allemann, Luc

    2018-05-01

    The subduction system in southern Patagonia provides direct evidence for the variability of the position of an active continental arc with respect to the subducting plate through time, but the consequences on the arc magmatic record are less well studied. Here we present a geochemical and geochronological study on small plutons and dykes from the upper crust of the southern Patagonian Andes at 51°S, which formed as a result of the subduction of the Nazca and Antarctic plates beneath the South American continent. In situ U-Pb geochronology on zircons and bulk rock geochemical data of plutonic and dyke rocks are used to constrain the magmatic evolution of the retro-arc over the last 30 Ma. We demonstrate that these combined U-Pb and geochemical data for magmatic rocks track the temporal and spatial migration of the active arc, and associated retro-arc magmatism. Our dataset indicates that the rear-arc area is characterized by small volumes of alkaline basaltic magmas at 29-30 Ma that are characterized by low La/Nb and Th/Nb ratios with negligible arc signatures. Subsequent progressive eastward migration of the active arc culminated with the emplacement of calc-alkaline plutons and dikes 17-16 Ma with elevated La/Nb and Th/Nb ratios and typical subduction signatures constraining the easternmost position of the southern Patagonian batholith at that time. Geochemical data on the post-16 Ma igneous rocks including the Torres del Paine laccolith indicate an evolution to transitional K-rich calc-alkaline magmatism at 12.5 ± 0.2 Ma. We show that trace element ratios such as Nb/Ta and Dy/Yb systematically decrease with increasing SiO2, for both the 17-16 Ma calc-alkaline and the 12-13 Ma K-rich transitional magmatism. In contrast, Th/Nb and La/Nb monitor the changes in the source composition of these magmas. We suggest that the transition from the common calc-alkaline to K-rich transitional magmatism involves a change in the source component, while the trace element ratios

  9. Alkaline resistant ceramics; Alkalimotstaandskraftiga keramer

    Energy Technology Data Exchange (ETDEWEB)

    Westberg, Stig-Bjoern [Vattenfall Utveckling AB, Aelvkarleby (Sweden)

    2001-02-01

    Despite durability in several environments, ceramics and refractories can not endure alkaline environments at high temperature. An example of such an environment is when burning biofuel in modern heat and power plants in which the demand for increasing efficiency results in higher combustion temperatures and content of alkaline substances in the flue gas. Some experiences of these environments has been gained from such vastly different equipment as regenerator chambers in the glass industry and MHD-generators. The grains of a ceramic material are usually bonded together by a glassy phase which despite it frequently being a minor constituent render the materials properties and limits its use at elevated temperature. The damage is usually caused by alkaline containing low-melting phases and the decrease of the viscosity of the bonding glass phase which is caused by the alkaline. The surfaces which are exposed to the flue gas in a modern power plant are not only exposed to the high temperature but also a corroding and eroding, particle containing, gas flow of high velocity. The use of conventional refractory products is limited to 1300-1350 deg C. Higher strength and fracture toughness as well as durability against gases, slag and melts at temperatures exceeding 1700 deg C are expected of the materials of the future. Continuous transport of corrosive compounds to the surface and corrosion products from the surface as well as a suitable environment for the corrosion to occur in are prerequisites for extensive corrosion to come about. The highest corrosion rate is therefore found in a temperature interval between the dew point and the melting point of the alkaline-constituent containing compound. It is therefore important that the corrosion resistance is sufficient in the environment in which alkaline containing melts or slag may appear. In environments such as these, even under normal circumstances durable ceramics, such as alumina and silicon carbide, are attacked

  10. The evaluation of physico-chemical parameters of the Nasrand Plutonic complex by using mineral composition

    Directory of Open Access Journals (Sweden)

    Fatemeh Sarjoughian

    2017-02-01

    Full Text Available Introduction Mineral composition is sensitive to variations in the composition of the magma and can be used to characterize the physical conditions of crystallization such as temperature, pressure, oxygen fugacity and water content. The studies have demonstrated that geobarometery by amphibole provides a tool for determining the depth of crystallization and knowledge of the depth of crystallization of hornblende through to solidification of calc-alkaline plutons (Anderson and Smith, 1995. The composition of pyroxene can be used as crystallization pressure and temperature indicators of pyroxene too. Anlytical methods The mineral compositions of the Nasrand intrusion were determined by electron microprobe, with special emphasis on the amphibole, feldspar, and pyroxene at the Naruto University, Japan, the EPMA (Jeol- JXA-8800R was used at operating conditions of 15 kV, 20 nA acceleration voltage and 20s counting time. Results The Nasrand intrusion (33°13'–33°15' N, 52°33'–52°34'E with an outcrop area of about 40 km2 is situated in the Urumieh–Dokhtar magmatic belt, SE of Ardestan. It is composed of granite and granodiorite and various dikes of diorite and gabbro which are intruded in it. It is intruded into Eocene volcanic rocks, including andesite, rhyolite, and dacite. The petrographical studies indicate that the granitic and granodioritic rocks contain major minerals such as quartz, K-feldspar, plagioclase, and amphibole, which are in an approximate equilibrium state. The gabbroic-dioritic dikes usually show microgranular porphyric texture. They mainly consist of plagioclase, amphibole, and pyroxene. The plagioclase shows variable composition from albite to oligoclase in the granitoid rocks and from oligoclase to bytownite in dioritic and gabbroic dikes (Deer et al., 1991. The amphiboles are calcic and their composition varies from hornblende to actinolite, whereas the composition of the basic dikes is inclined to hastingsite (Leake et

  11. A pilot study on the distribution of 137Cs between vegetation and soil in an industrial pollution gradient at the Kola peninsula

    International Nuclear Information System (INIS)

    Nylen, T.; Bergman, I.; Bergman, R.; Nikonov, V.

    1997-01-01

    The activity concentration of radiocesium in dwarf shrubs, mosses, organic and inorganic soil was studied in an industrial pollution gradient from the Monchegorsk smelter at the Kola peninsula. As expected the highest values for vegetation was found in mosses/lichens followed by dwarf shrubs. The transfer factor between organic and vascular vegetation was ten times higher in the control area (100 km from the smelter) than in the affected areas (7 to 31 km from the smelter). 3 refs

  12. The methanol seed extract of Garcinia kola attenuated angiotensin II- and lipopolyssacharide-inducedvascular smooth muscle cell proliferation and nitric oxide production

    Directory of Open Access Journals (Sweden)

    Adeolu A. Adedapo

    2016-10-01

    Full Text Available All over the world, cardiovascular diseases are a risk factor for poor health and early death with predisposing factors to include age, gender, tobacco use, physical inactivity, excessive alcohol consumption, unhealthy diet, obesity, family history of cardiovascular disease, hypertension, diabetes mellitus, hyperlipidemia, psychosocial factors, poverty and low educational status, and air pollution. It is envisaged that herbal products that can stem this trend would be of great benefit. Garcinia kola (GK, also known as bitter kola is one of such plants. Generally used as a social snack and offered to guests in some cultural settings, bitter kola has been indicated in the treatment of laryngitis, general inflammation, bronchitis, viral infections and diabetes. In this study, the effects of methanol seed extract of Garcinia kola on the proliferation of Vascular Smooth Muscle Cells (VSMCs in cell culture by Angiotensin II (Ang II and LPS-induced NO production were carried out. Confluent VSMCs were exposed to GK (25, 50 and 100 μg/ml before or after treatment with lipopolyssacharide (100μg/ml, and Angiotensin II (10-8-10-6M. Cellular proliferation was determined by MTT assay and NO production by Griess assay. Treatment with Angiotensin II (10-8, 10-6 or LPS significantly enhanced proliferation of VSM cells while LPS significantly increased nitric oxide (NO production. Treatment with GK (25, 50 & 100 μg/ml attenuated VSM cell proliferation. The results indicate that GK has potential to inhibit mitogen activated vascular cell growth and possibly inhibit inflammatory responses to LPS. Thus GK may be useful in condition that is characterized by cellular proliferation and inflammatory responses.

  13. An unusually rich scuttle fly fauna (Diptera, Phoridae) from north of the Arctic Circle in the Kola Peninsula, N. W. Russia.

    Science.gov (United States)

    Disney, R H L

    2013-01-01

    64 species of Phoridae, in 6 genera, are reported from the Kola Peninsula, north of the Arctic Circle. The new species Megaselia elenae and Megaselia kozlovi are described. 33 species of Megaselia, only known from females, are given code numbers. Keys to the species of all the females of Megaselia and Phora are provided; and also a key to the males European Megaselia species with a notopleural cleft.

  14. Determination of emplacement mechanism of Zafarghand granitoid Pluton (Southeast of Ardestan by using anisotropy of magnetic susceptibility method (AMS

    Directory of Open Access Journals (Sweden)

    Mahmoud Sadeghian

    2017-03-01

    Full Text Available Zafarghand granitoid pluton with compositional range from gabbro to granite and early to middle Miocene age cropped out about 35 km of SE Ardestan. This pluton intrudedthe Eocene volcanic and volcanosedimentary rocks of the Urumieh - Dokhtar structuralzone. In this research, for the first time, the emplacement mechanism of Zafarghandgranitoidic pluton method has been investigated using of anisotropy of magneticsusceptibility (AMS. Based on field observations, as well as petrography andinterpretations of magnetic parameters, Zafarghand pluton divided into 5 domains (1A,1B, 2, 3, 4 and 5. Domain 1, in turn, is divided into 1A and 1B. Domains 2 and 4 arelithologically, gabbro to quartzdiorite and have been emplaced first. They have playedas feeder zones. Domains 1A, 1B, 3, and 5 are dominantly granodioritic to graniticcomposition and have been emplaced as a big and low dip magmatic flow (or possibly as a sill. The occurrence of gabbro to quartzdiorite as well as grandiorite, granite andtonalite in the margin borders of the body, are all indication of magma mixing. It isshould be noted that during emplacement of the pluton studied, fractionalcrystallization, magma mixing and crustal contamination contributed to its generationand the evolution as well.

  15. An integrated geological, geochemical, and geophysical investigation of uranium metallogenesis in selected granitic plutons of the Miramichi Anticlinorium, New Brunswick

    International Nuclear Information System (INIS)

    Hassan, H.H.; McAllister, A.L.

    1992-01-01

    Integrated geological, geochemical, and geophysical data for the post-tectonic granitic rocks of the North Pole, Burnthill, Dungarvon, Trout Brook, and Rocky Brook plutons and surrounding areas were examined to assess their potential for uranium mineralization. Geological, geochemical, and geophysical criteria that are thought to be useful guides for uranium exploration were also established for the host granites. The granitic plutons were emplaced discordantly, late in the tectonomagmatic sequence and at shallow depths within the metasedimentary rocks of the Miramichi Anticlinorium. Geochemically, the host granites are highly evolved (Si0 2 > 75 wt. %), peraluminous and have strong similarities with ilmenite-series 'S-type' and 'A-type' granitoids. Uranium occurrences are spatially and perhaps temporally associated with late-phase differentiates of the plutons where elevated levels of other lithophile elements such as Sn, W, Mo, and F were also detected. Geophysically, the granitic plutons are associated with distinctively high aeroradiometric eU, eTh, and K anomalies that coincide with strong negative Bouguer anomalies and low magnetic values. Conceptual models involving magmatic and hydrothermal processes have been adopted to explain the concentration of uranium and associated metals in the granitic plutons

  16. Optical properties of alkaline earth borate glasses

    African Journals Online (AJOL)

    user

    ... devices; radiation shields, surgical lasers and their glass ceramic counter ... Alkaline earth oxides improve glass forming capability while heavy metal ... reports on optical properties of MO-B2O3 glasses containing alkaline earth oxides.

  17. Qualitative Carbohydrate Analysis using Alkaline Potassium ...

    Indian Academy of Sciences (India)

    IAS Admin

    CLASSROOM. 285. RESONANCE | March 2016. Qualitative Carbohydrate Analysis using Alkaline. Potassium Ferricyanide. Keywords. Alkaline potassium ferricyanide, qualitative ... Carbohydrates form a distinct class of organic compounds often .... Laboratory Techniques: A contemporary Approach, W B Saunders Com-.

  18. Verification of the transuranus-WWER code version V1M2J00 by SOFIT and Kola-3 data bases: Part 2

    International Nuclear Information System (INIS)

    Elenkov, D.; Boneva, S.; Djourelov, N.

    2002-01-01

    The object of this study is standard WWER-440 fuel as described in the IFPE-OECD/IAEA-NEA database. The SOFIT and Kola-3 data base have been used the purpose, each one described in a separate paper, referred to as Part I (concerning SOFIT) and Part II (concerning Kola-3). It has been shown that the latest modifications of the programme lead to considerable improvements of the predictions on the fuel behaviour. Concerning the TRANSURANUS-WWER code calculations of different fuel behaviour characteristics of Kola-3 standard fuel rods, the following conclusions can be made: the burnup calculations are in excellent agreement with the measured values; the fission gas release calculations accounting for the high burnup structure influence are in very good agreement with the experiment for the two assemblies in the burnup region up to 40 MWd/kgU; the size changes for the cladding are reproduced in fairly good way; the gas pressure is reproduced by some 10 -15 % underestimation. From the obtained results including the discussed deviations, the present version of TRANSURANUS-WWER can be considered as applicable for the modelling fuel performance in Bulgarian nuclear power plants operating WWER reactors

  19. Experimental Studies for the VVER-440/213 Bubble Condenser System for Kola NPP at the Integral Test Facility BC V-213

    International Nuclear Information System (INIS)

    Blinkov, V.N.; Melikhov, O.I.; Melikhov, V.I.; Davydov, M.V.; Wolff, H.; Arndt, S.

    2012-01-01

    In the frame of Tacis Project R2.01/99, which was running from 2003 to 2005, the bubble condenser system of Kola NPP (unit 3) was qualified at the integral test facility BC V-213. Three LB LOCA tests, two MSLB tests, and one SB LOCA test were performed. The appropriate test scenarios for BC V-213 test facility, modeling accidents in the Kola NPP unit 3, were determined with pretest calculations. Analysis of test results has shown that calculated initial conditions and test scenarios were properly reproduced in the tests. The detailed posttest analysis of the tests performed at BC V-213 test facility was aimed to validate the COCOSYS code for the calculation of thermohydraulic processes in the hermetic compartments and bubble condenser. After that the validated COCOSYS code was applied to NPP calculations for Kola NPP (unit 3). Results of Tacis R2.01/99 Project confirmed the bubble condenser functionality during large and small break LOCAs and MSLB accidents. Maximum loads were reached in the LB LOCA case. No condensation oscillations were observed.

  20. The results of marine electromagnetic sounding with a high-power remote source in the Kola Bay in the Barents Sea

    Science.gov (United States)

    Grigoriev, V. F.; Korotaev, S. M.; Kruglyakov, M. S.; Orekhova, D. A.; Popova, I. V.; Tereshchenko, E. D.; Tereshchenko, P. E.; Schors, Yu. G.

    2013-05-01

    The first Russian six-component seafloor electromagnetic (EM) receivers were tested in an experiment carried out in Kola Bay in the Barents Sea. The signals transmitted by a remote high-power ELF source at several frequencies in the decahertz range were recorded by six receivers deployed on the seafloor along the profile crossing the Kola Bay. Although not all the stations successfully recorded all the six components due to technical failures, the quality of the data overall is quite suitable for interpretation. The interpretation was carried out by the three-dimensional (3D) modeling of an electromagnetic field with neural network inversion. The a priori geoelectrical model of Kola Bay, which was reconstructed by generalizing the previous geological and geophysical data, including the data of the ground magnetotelluric sounding and magnetovariational profiling, provided the EM fields that are far from those measured in the experiment. However, by a step-by-step modification of the initial model, we achieved quite a satisfactory fit. The resulting model provides the basis for introducing the corrections into the previous notions concerning the regional geological and geophysical structure of the region and particularly the features associated with fault tectonics.

  1. INSTALLATION OF A POST-ACCIDENT CONFINEMENT HIGH-LEVEL RADIATION MONITORING SYSTEM IN THE KOLA NUCLEAR POWER STATION (UNIT 2) IN RUSSIA

    Energy Technology Data Exchange (ETDEWEB)

    GREENE,G.A.; GUPPY,J.G.

    1998-09-01

    This is the final report on the INSP project entitled, ``Post-Accident Confinement High-Level Radiation Monitoring System'' conducted by BNL under the authorization of Project Work Plan WBS 1.2.2.6 (Attachment 1). This project was initiated in February 1993 to assist the Russians in reducing risks associated with the continued operation of older Soviet-designed nuclear power plants, specifically the Kola VVER-440/230 Unit 2, through improved accident detection capability, specifically by the installation of a dual train high-level radiation detection system in the confinement of Unit 2 of the Kola NPP. The major technical objective of this project was to provide, install and make operational the necessary hardware inside the confinement of the Kola NPP Unit 2 to provide early and reliable warning of the release of radionuclides from the reactor into the confinement air space as an indication of the occurrence of a severe accident at the plant. In addition, it was intended to provide hands-on experience and training to the Russian plant workers in the installation, operation, calibration and maintenance of the equipment in order that they may use the equipment without continued US assistance as an effective measure to improve reactor safety at the plant.

  2. Fingerprinting and validation of a LC-DAD method for the analysis of biflavanones in Garcinia kola-based antimalarial improved traditional medicines.

    Science.gov (United States)

    Tshibangu, P Tshisekedi; Kapepula, P Mutwale; Kapinga, M J Kabongo; Lupona, H Kabika; Ngombe, N Kabamba; Kalenda, Dibungi T; Jansen, O; Wauters, J N; Tits, M; Angenot, L; Rozet, E; Hubert, Ph; Marini, R D; Frédérich, M

    2016-09-05

    African populations use traditional medicines in their initial attempt to treat a range of diseases. Nevertheless, accurate knowledge of the composition of these drugs remains a challenge in terms of ensuring the health of population and in order to advance towards improved traditional medicines (ITMs). In this paper chromatographic methods were developed for qualitative and quantitative analyses of a per os antimalarial ITM containing Garcinia kola. The identified analytical markers were used to establish TLC and HPLC fingerprints. G. kola seeds were analysed by HPLC to confirm the identity of the extract used by the Congolese manufacturer in the ITM. The main compounds (GB1, GB2, GB-1a and Kolaflavanone) were isolated by preparative TLC and identified by UPLC-MS and NMR. For the quantification of the major compound GB1, a simple and rapid experimental design was applied to develop an LC method, and then its validation was demonstrated using the total error strategy with the accuracy profile as a decision tool. The accurate results were observed within 0.14-0.45mg/mL range of GB1 expressed as naringenin. The extracts used in several batches of the analysed oral solutions contained GB1 (expressed as naringenin) within 2.04-2.43%. Both the fingerprints and the validated LC-DAD were found suitable for the quality control of G. kola-based raw material and finished products, respectively. Copyright © 2016 Elsevier B.V. All rights reserved.

  3. INSTALLATION OF A POST-ACCIDENT CONFINEMENT HIGH-LEVEL RADIATION MONITORING SYSTEM IN THE KOLA NUCLEAR POWER STATION (UNIT 2) IN RUSSIA

    International Nuclear Information System (INIS)

    GREENE, G.A.; GUPPY, J.G.

    1998-01-01

    This is the final report on the INSP project entitled, ''Post-Accident Confinement High-Level Radiation Monitoring System'' conducted by BNL under the authorization of Project Work Plan WBS 1.2.2.6 (Attachment 1). This project was initiated in February 1993 to assist the Russians in reducing risks associated with the continued operation of older Soviet-designed nuclear power plants, specifically the Kola VVER-440/230 Unit 2, through improved accident detection capability, specifically by the installation of a dual train high-level radiation detection system in the confinement of Unit 2 of the Kola NPP. The major technical objective of this project was to provide, install and make operational the necessary hardware inside the confinement of the Kola NPP Unit 2 to provide early and reliable warning of the release of radionuclides from the reactor into the confinement air space as an indication of the occurrence of a severe accident at the plant. In addition, it was intended to provide hands-on experience and training to the Russian plant workers in the installation, operation, calibration and maintenance of the equipment in order that they may use the equipment without continued US assistance as an effective measure to improve reactor safety at the plant

  4. PLUTON, Isotope Generation and Depletion in Highly Irradiated LWR Fuel Rods

    International Nuclear Information System (INIS)

    Lemehov, Sergei; Motoe, Suzuki

    2003-01-01

    1 - Description of program or function: The PLUTON-PC is a three-group neutronic code analyzing, as functions of time and burnup, the change of radial profiles, together with average values, of power density, burnup, concentration of trans-uranium elements, plutonium buildup, depletion of fissile elements, and fission product generation in water reactor fuel rod with standard UO 2 , UO 2 -Gd 2 O 3 , inhomogeneous MOX, and UO 2 -ThO 2 . The PLUTON-PC code, which has been designed to be run on Windows PC, has adopted a theoretical shape function of neutron attenuation in pellet, which enables users to perform a very fast and accurate calculation easily. The code includes the irradiation conditions of the Halden Reactor which gives verification data for the code. Verification has been performed up to 83 GWd/tU, and a satisfactory agreement has been obtained. 2 - Methods: Based upon cumulative yields, the PLUTON-PC code calculates as a function of radial position and local burnup concentrations of fission products, macroscopic scattering cross-sections and self-shielding effect which is important for standard fuel (for Pu-242 mainly) and more importantly for homogeneous and inhomogeneous MOX fuel because of higher concentrations of fissile and fertile isotopes of plutonium. The code results in burnup dependent fission rate density profiles throughout the in-reactor irradiation of LWR fuel rods. The isotopes included in calculations have been extended to cover all trans-uranium groups (plutonium plus higher actinides) of fissile and fertile isotopes. Self-shielding problem and scattering effects have been revised and solved for all isotopes in the calculations for adequacy at high burnup, different irradiation conditions and cladding materials

  5. Sm-Nd whole-rock isotope system of the Eye-Dashwa Lakes pluton

    International Nuclear Information System (INIS)

    Futa, K.

    1990-01-01

    An unaltered drill-core sample of the Eye-Dashwa Lakes pluton (sample ATK-1 (990.97-996.78)) is light rare earth enriched, with a 147 Sm/ 144 Nd ratio of 0.08699 and a 143 Nd/ 144 Nd ratio of 0.510815. The depleted mantle model age of 2.68 Ga agrees with emplacement ages, indicating that parental magma or its protolith was derived directly from a depleted mantle and that the crustal residence time was short

  6. Occurrence of parsonite, a secondary uranium mineral, in alaskite of the Wheeler Creek pluton, Alaska

    International Nuclear Information System (INIS)

    Miller, T.P.; Johnson, B.

    1978-01-01

    Reconnaissance investigations in the Purcell Mountains of westcentral Alaska in 1977 revealed the presence of parsonite, a hydrous phosphate of lead and uranium with the formula Pb 2 UO 2 (PO 4 ) 2 2H 2 O. This is the first reported occurrence of parsonite in Alaska. The parsonite occurs as a soft, yellow to chocolate brown coating closely associated with green muscovite on fracture surfaces in a shear zone in alaskite of the Wheeler Creek pluton. Thin magnetite veinlets are also present. The identification of parsonite was confirmed by x-ray diffraction. Delayed neutron analysis were run on samples of the Alaskite

  7. Porfiroblastic hornblendites: lithological, guide of arch root plutonism in Piedra Alta Terrane. (Paleoproterozoic, Uruguay)

    International Nuclear Information System (INIS)

    Bossi, J.; Pineyro, D.

    2004-01-01

    Petrographic and geochemical features of porphyroblastic hornblendites in Piedra Alta Terrene of Uruguay are described. Their spatial and genetic relationships whith hornblendic gabbros and other basic plutonic rocks is also stablished. Their association with low grade metamorphic supracrustals inmagmatic mingling structures and late development, suggests an origin related to high vapour pressure that take off stability to gabbro paragenesis and favours Deer's reaction:pyroxene+ plagioclase +water= hornblende + SIO2. The silica produced is expressed as quartz dikes frequently mineralized with gold and platinum group elements. San Carlos gabbro is an uruguayan exemple of such proposed model.

  8. Platinum, palladium, and rhodium in volcanic and plutonic rocks from the Gravina-Nutzotin belt, Alaska

    Science.gov (United States)

    Page, Norman J; Berg, Henry C.; Haffty, Joseph

    1977-01-01

    The Gravina-Nutzotin belt of Middle (?) Jurassic to middle Cretaceous sedimentary and volcanic rocks in south and southeastern Alaska includes concentrically zoned ultramafic complexes known to contain platinum-group metals. Previous isotopic, petrologic, and geologic studies suggested a close relation in time and space between the volcanic rocks and the ultramafic complexes. Interpretation of 40 analyses for platinum, palladium, and rhodium in volcanic and plutonic rocks of the belt indicates a strong geochemical correlation between the two groups of rocks and is in support of their being cogenetic either from directly connected magma chambers and flows or indirectly by selective concentration processes from similar mantle material.

  9. The geological processes time scale of the Ingozersky block TTG complex (Kola Peninsula)

    Science.gov (United States)

    Nitkina, Elena

    2013-04-01

    Ingozersky block located in the Tersky Terrane of the Kola Peninsula is composed of Archean gneisses and granitoids [1; 5; 8]. The Archaean basement complexes on the regional geological maps have called tonalite-trondemit-gneisses (TTG) complexes [6]. In the previous studies [1; 3; 4; 5; 7] within Ingozersky block the following types of rocks were established: biotite, biotite-amphibole, amphibole-biotite gneisses, granites, granodiorites and pegmatites [2]. In the rocks of the complex following corresponding sequence of endogenous processes observed (based on [5]): stage 1 - the biotitic gneisses formation; 2 - the introduction of dikes of basic rocks; 3 phase - deformation and foliation; 4 stage - implementation bodies of granite and migmatization; 5 stage - implementation of large pegmatite bodies; stage 6 - the formation of differently pegmatite and granite veins of low power, with and without garnet; stage 7 - quartz veins. Previous U-Pb isotopic dating of the samples was done for biotite gneisses, amphibole-biotite gneisses and biotite-amphibole gneisses. Thus, some Sm-Nd TDM ages are 3613 Ma - biotite gnesses, 2596 Ma - amphibole-biotite gnesses and 3493 Ma biotite-amphibole gneisses.. U-Pb ages of the metamorphism processes in the TTG complex are obtained: 2697±9 Ma - for the biotite gneiss, 2725±2 and 2667±7 Ma - for the amphibole-biotite gneisses, and 2727±5 Ma for the biotite-amphibole gneisses. The age defined for the biotite gneisses by using single zircon dating to be about 3149±46 Ma corresponds to the time of the gneisses protolith formation. The purpose of these studies is the age establishing of granite and pegmatite bodies emplacement and finding a geological processes time scale of the Ingozerskom block. Preliminary U-Pb isotopic dating of zircon and other accessory minerals were held for granites - 2615±8 Ma, migmatites - 2549±30 Ma and veined granites - 1644±7 Ma. As a result of the isotope U-Pb dating of the different Ingozerskogo TTG

  10. Site investigation methods used in Canada's nuclear fuel waste management program to determine the hydrogeological conditions of plutonic rock

    International Nuclear Information System (INIS)

    Davison, C.C.

    1985-01-01

    Atomic Energy of Canada Limited (AECL) is investigating the concept of disposing of Canada's nuclear fuel wastes in a mined vault at a depth of 500 m to 1000 m within a plutonic rock body. Much effort has been directed at developing site investigation methods that can be used to determine the hydrogeological conditions of plutonic rock bodies. The primary objective of this research is to define the physical and chemical characteristics of groundwater flow systems at the various scales that are relevant to the prediction of potential radionuclide migration from a disposal vault. Groundwater movement through plutonic rock is largely controlled by fractures within the rock, and the hydrogeological parameters of fractured geological media are extremely scale dependent

  11. Development of alkaline fuel cells.

    Energy Technology Data Exchange (ETDEWEB)

    Hibbs, Michael R.; Jenkins, Janelle E.; Alam, Todd Michael; Janarthanan, Rajeswari; Horan, James L.; Caire, Benjamin R.; Ziegler, Zachary C.; Herring, Andrew M.; Yang, Yuan; Zuo, Xiaobing; Robson, Michael H.; Artyushkova, Kateryna; Patterson, Wendy; Atanassov, Plamen Borissov

    2013-09-01

    This project focuses on the development and demonstration of anion exchange membrane (AEM) fuel cells for portable power applications. Novel polymeric anion exchange membranes and ionomers with high chemical stabilities were prepared characterized by researchers at Sandia National Laboratories. Durable, non-precious metal catalysts were prepared by Dr. Plamen Atanassovs research group at the University of New Mexico by utilizing an aerosol-based process to prepare templated nano-structures. Dr. Andy Herrings group at the Colorado School of Mines combined all of these materials to fabricate and test membrane electrode assemblies for single cell testing in a methanol-fueled alkaline system. The highest power density achieved in this study was 54 mW/cm2 which was 90% of the project target and the highest reported power density for a direct methanol alkaline fuel cell.

  12. Investigation of the mineral potential of the Clipper Gap, Lone Mountain-Weepah, and Pipe Spring plutons, Nevada

    International Nuclear Information System (INIS)

    Tingley, J.V.; Maldonado, F.

    1983-01-01

    The Clipper Gap pluton, composed mostly of quartz monzonite with minor granite, granodiorite, and crosscutting alaskite dikes, intrudes Paleozoic western facies strata. A narrow zone of contact metamorphism is present at the intrusive-sediment contact. No mineral production has been recorded from Clipper Gap, but quartz veins containing gold-silver-copper mineral occurrences have been prospected there from the late 1800's to the present. Areas of the Lone Mountain-Weepah plutons that were studied are located in Esmeralda County about 14 km west of Tonopah, Nevada. At Lone Mountain, a Cretaceous intrusive cuts folded Precambrian and Cambrian sediments. Lead-zinc ores have been mined from small replacement ore bodies in the Alpine district, west of Lone Mountain. Copper and molybdenum occurrences have been found along the east flank of Lone Mountain, and altered areas were noted in intrusive outcrops around the south end of Lone Mountain. Mineral occurrences are widespread and varied with mining activity dating back to the 1860's. The Pipe Spring pluton study area is flanked by two important mining districts, Manhattan to the north and Belmont to the northeast. Mining activity at Belmont dates from 1865. Activity at Manhattan was mainly between 1907 and 1947, but the district is active at the present time (1979). Four smaller mining areas, Monarch, Spanish Springs, Baxter Spring, and Willow Springs, are within the general boundary of the area. The Pipe Spring pluton study area contains numerous prospects along the northern contact zone of the pluton. Tungsten-bearing veins occur within the pluton near Spanish Springs, with potential for gold-tungsten placer in the Ralston Valley. Nickel and associated metals occur at Willow Spring and Monarch Ranch, where prospects may be associated with the margin of the Big Ten Peak Caldera

  13. Review of the Norwegian-Russian Cooperation on Safety Projects at Kola and Leningrad Nuclear Power Plants 2005 - 2009

    International Nuclear Information System (INIS)

    Mattsson, H.; Tishakov, P.

    2010-11-01

    In this report, Norwegian Radiation Protection Authority (NRPA) has reviewed the Norwegian funded projects on nuclear safety performed in the period 2005-2009 under the Norwegian Action Plan. NRPA has evaluated the progress of eight projects implemented by the Institute for Energy Technology (IFE) at Kola Nuclear Power Plant (KNPP) and Leningrad Nuclear Power Plant (LNPP). NRPA has visited the plants, inspected delivered equipment and discussed the projects implementation with relevant personnel at the plants. One of NRPA findings is that the equipment has been delivered to KNPP and LNPP, it is in regular use by competent personnel, and the equipment contributes to safety of both plants. Furthermore, the cooperation between three main project partners - IFE, LNPP and KNPP, seems to be very productive. NRPA's main conclusion is therefore that the projects have been implemented as described in IFE's project reports and that the goals are met. Furthermore, this report reviews safety levels at the KNPP and LNPP. Safety parameters at the plants indicate that the safety level has been significantly improved since early 1990s when the cooperation between Norway and Russia was initiated. Probabilistic safety assessment (PSA) values and number of INES (International Nuclear Event Scale) events, two internationally acknowledged safety parameters, indicate that the safety level has been much improved since the early 1990s when the cooperation between Norway and Russia started. Although it is clear that the Norwegian-funded projects have contributed positively to this development it is difficult to quantify the contribution. Moreover, the report also reviews the planned life-time of and the decommissioning plans for the reactors at KNPP and LNPP. Construction of new LNPP reactors has started and it is estimated that they will be operational in 2013- 2015. The license of the oldest reactor at LNPP expires in 2018 and if the new reactors are in operation by that time, it is

  14. Long-term fluctuations in population of Semibalanus balanoides (L. (Crustacea in the estuarine zone of the Kola Bay

    Directory of Open Access Journals (Sweden)

    Svitina V. S.

    2017-06-01

    Full Text Available The intertidal population of the barnacles Semibalanus balanoides has been explored in the estuarine zone of the Tuloma River at the end of the Kola Bay for the first time. Barnacles S. balanoides are typical species for the littoral zone of the northern seas, they populate both the high and low salinity areas along the coast of the Barents Sea. The ecology and distribution of barnacle population in estuarine intertidal zones of the Barents Sea are not studied previously, and under the critical salinity conditions of any estuary, in particular. The investigation have been carried out on the littoral of the western (left shore of the southern tribe of the Kola Bay – the estuary section from the Tuloma bridge to the Cape Elovy. The studied site is a sandy-boulder beach with stony bars, its length is about 1 150 m, the area is about 126 500 m2. Counting the number of S. balanoides in clusters has been performed on site (without removal of the copepods from the population by the standard method for intertidal sampling. Simultaneously with the defining the number of barnacles for the period 2003–2014, the measurements of salinity and temperature of water and air have been made. The peculiarity of the estuarine barnacle population is their complete absence in the upper horizon of the littoral, and in the middle and the lower horizons they are found only within the channels of the littoral streams (3–20 specimens in the sample. For the first time the abundance and biomass of barnacles S. balanoides in this estuarine population has been determined, and the causes of their narrow-local distribution on the estuary littoral of the Tuloma River have been revealed. The main ecological factors determining the abundance and specific distribution of barnacles under the conditions of estuarine littoral have been established. The regular increase in the density of adult S. balanoides settlements along the gradient of water salinity from the Tuloma River to

  15. Syn-extensional plutonism and peak metamorphism in the albion-raft river-grouse creek metamorphic core complex

    Science.gov (United States)

    Strickland, A.; Miller, E.L.; Wooden, J.L.; Kozdon, R.; Valley, J.W.

    2011-01-01

    The Cassia plutonic complex (CPC) is a group of variably deformed, Oligocene granitic plutons exposed in the lower plate of the Albion-Raft River- Grouse Creek (ARG) metamorphic core complex of Idaho and Utah. The plutons range from granodiorite to garnet-bearing, leucogranite, and during intrusion, sillimanite- grade peak metamorphism and ductile attenuation occurred in the country rocks and normal-sense, amphibolite-grade deformation took place along the Middle Mountain shear zone. U-Pb zircon geochronology from three variably deformed plutons exposed in the lower plate of the ARG metamorphic core complex revealed that each zircon is comprised of inherited cores (dominantly late Archean) and Oligocene igneous overgrowths. Within each pluton, a spread of concordant ages from the Oligocene zircon overgrowths is interpreted as zircon recycling within a long-lived magmatic system. The plutons of the CPC have very low negative whole rock ??Nd values of -26 to -35, and initial Sr values of 0.714 to 0.718, consistent with an ancient, crustal source. Oxygen isotope ratios of the Oligocene zircon overgrowths from the CPC have an average ??18O value of 5.40 ?? 0.63 permil (2SD, n = 65) with a slight trend towards higher ??18O values through time. The ??18O values of the inherited cores of the zircons are more variable at 5.93 ?? 1.51 permil (2SD, n = 29). Therefore, we interpret the plutons of the CPC as derived, at least in part, from melting Archean crust based on the isotope geochemistry. In situ partial melting of the exposed Archean basement that was intruded by the Oligocene plutons of the CPC is excluded as the source for the CPC based on field relationships, age and geochemistry. Correlations between Ti and Hf concentrations in zircons from the CPC suggest that the magmatic system may have become hotter (higher Ti concentration in zircon) and less evolved (lower Hf in zircon concentration) through time. Therefore, the CPC represents prolonged or episodic magmatism

  16. The Merensky Reef in the Chineisky Pluton (Siberia)? A myth or a reality?

    Science.gov (United States)

    Zhitova, L.; Sharapov, V.; Zhukova, I.

    2006-12-01

    It is a dream of each geologist to find a `Merensky Reef' in each layered basic intrusion. Scientists have been trying many various techniques to come this dream to reality. The most perspective way to do so is probably a combination of physicochemical and computer modeling of layered basic intrusion crystallization together with fluid and melt inclusions studies in situ. This combination allows us to do the following: 1. To study boundary conditions for separation of low density gas phase and salt melt from the crystallizing primary basic melt in large magma chamber. 2. To determine correct quantitative parameters for formation of residual fluid-bearing brines extracting high metal concentrations. 3. To compute critical levels for substance differentiation at phase, geochemical and other `barriers' in those basic mantle-crust ore magmatic systems. 4. To model metal extraction, transportation and deposition at these `barriers' for systems of various `silicate melt - residual salt brines' ratios under the conditions of continental lithosphere. Comparison of real and modeled data allows us to conclude if a formation of a narrow zone of high metal concentration is possible at those critical levels (phase and geochemical `barriers'). The above-mentioned algorithm has been used for the Chineisky Pluton (the Transbaikal region, Siberia). Fortunately we have found our own `Merensky Reef', which happened to be a PGE enrichment marginal zone of the Chineisky Pluton due to specific fluid regime of crystallization! This work was supported by the Ministry for Russian Science and Education, Grant #DSP.2.1.1.702.

  17. Oxygen isotope exchange kinetics between coexistent minerals and water in the Ertaibei granite pluton, northern Xinjiang

    Institute of Scientific and Technical Information of China (English)

    刘伟; 李志安; 赵志忠

    1996-01-01

    Coexistent minerals quartz, feldspar and biotite vary widely in δ18O value and display remarkable 18O/16O disequilibrium relations in the Ertaibei granite pluton, northern Xinjiang. The 18O/16O exchange reaction definitely occurred between granite and water. Initial δ18O values of the granite and exotic water are evaluated by the mass balance consideration. The results show that the 18O/16O exchange reaction is not necessarily accompanied by what geologists describe as petrological and mineralogiesl alteration effects, indicating that the exchange reaction occurs at a comparatively high temperature during subsolidus cooling of magmas. Exchange mechanism is mainly controlled by diffusion. It is demonstrated through quantitative modelling that the hydrothermal system associated with the Ertaibei pluton lived for 0.8-3 Ma, with a fluid flow rate of 3 × 10-14 mol · s-1 and water/rock (W/R) ratio of 0.79 - 3.08. Flow path and initial heterogeneity of the exotic metamorphic fluid are modelled with the δ1

  18. Emplacement and geochemical evolution of eocene plutonic rocks in the Colville batholith

    International Nuclear Information System (INIS)

    Holder, R.W.

    1986-01-01

    Eocene plutonic rocks in the Colville batholith are divided on the basis of field evidence and chemical composition into, in order of decreasing age, (1) several calc-alkalic biotite-hornblende monzodiorite to granodiorite intrusions referred to as the Devils Elbow suite, and (2) compositionally variable calc-alkalic to alkali-calcic intrusions referred to as the Herron Creek suite. These Eocene suites are distinct from older, more voluminous, leucocratic granite and granodiorite intrusions, designated the Keller Butte suite, which are calcic and characteristically lack hornblende. Results of qualitative and computer modeling of major element variation and quantitative models of trace element variation in the chemically coherent Bridge Creek intrusions, a member of the Herron Creek suite, are compatible with fractionation of plagioclase feldspar + hornblende + biotite + magnetite + apatite from a parent magma of andesitic composition to account for the observed variation. Strongly curved variation trends preclude mixing as the primary mechanism for the observed variation. It is suggested that parallel variation trends in the other Eocene intrusions are also the result of crystal fractionation. Lateral chemical variations including a decrease in silica saturation suggest the chemical characteristics of these rocks reflect those of parental magmas derived from the mantle, with an unknown amount of crustal contribution. Rotated and angular xenoliths, discordant contacts, and temporal and spatial proximity to graben structures indicate that the Eocene plutons were passively implaced into the upper crust along graben-bounding faults during graben formation, the earlier stages of which appear to have been contemporaneous with regional mylonitic deformation

  19. Tectonic significance of dykes in the Sarnu-Dandali alkaline complex, Rajasthan, northwestern Deccan Traps

    Directory of Open Access Journals (Sweden)

    Anjali Vijayan

    2016-09-01

    Full Text Available Whether swarms of preferentially oriented dykes are controlled by regional stress fields, or passively exploit basement structural fabric, is a much debated question, with support for either scenario in individual case studies. The Sarnu-Dandali alkaline complex, near the northwestern limit of the Deccan Traps continental flood basalt province, contains mafic to felsic alkaline volcano-plutonic rocks and carbonatites. The complex is situated near the northern end of the 600 km long, NNW–SSE-trending Barmer-Cambay rift. Mafic enclave swarms in the syenites suggest synplutonic mafic dykes injected into a largely liquid felsic magma chamber. Later coherent dykes in the complex, of all compositions and sizes, dominantly strike NNW–SSE, parallel to the Barmer-Cambay rift. The rift formed during two distinct episodes of extension, NW–SE in the early Cretaceous and NE–SW in the late Cretaceous. Control of the southern Indian Dharwar structural fabric on the rift trend, as speculated previously, is untenable, whereas the regional Precambrian basement trends (Aravalli and Malani run NE–SW and NNE–SSW. We therefore suggest that the small-scale Sarnu-Dandali dykes and the much larger-scale Barmer-Cambay rift were not controlled by basement structure, but related to contemporaneous, late Cretaceous regional ENE–WSW extension, for which there is varied independent evidence.

  20. Death Valley turtlebacks: Mesozoic contractional structures overprinted by Cenozoic extension and metamorphism beneath syn-extensional plutons

    Science.gov (United States)

    Pavlis, T. L.; Miller, M.; Serpa, L.

    2008-07-01

    The term turtleback was first coined to describe the curvilinear fault surfaces that produced a distinctive geomorphic form in the Black Mountains east of Death Valley, and although it was decades before their full significance was appreciated, they remain one of the most distinctive features of the extensional structure of the Death Valley region. Historically the interpretation of the features has varied markedly, and misconceptions about their character continue to abound, including descriptions in popular field guides for the area. It the 1990's, however, the full history of the systems began to be apparent from several key data: 1) the dating of the plutonic assemblage associated with the turtlebacks demonstrated that late Miocene, syn-extensional plutonism was fundamental to their formation; 2) the plutonic assemblage forms an intrusive sheet structurally above the turtlebacks, indicating a tie between much of the high grade metamorphism and Cenozoic plutonism; 3) a modern analog for the syn-extensional plutonism in the Black Mountains was recognized beneath Death Valley with the imaging of a mid-crustal magma body; 4) the Neogene structural history was worked out in the turtlebacks showing that folding of early-formed shear zones formed the turtleback anticlinoria but overprinting by brittle faults produced the final form as they cut obliquely across the older structure; and 5) the pre-extensional structural history was clarified, demonstrating that Mesozoic basement-involved thrust systems are present within the turtlebacks, but have been overprinted by the extensional system. An unresolved issue is the significance of Eocene U-Pb dates for pegmatites within the region, but presumably these relate somehow to the pre-extensional history. Miller and Pavlis (2005; E. Sci. Rev.) reviewed many features of the turtlebacks, and our working model for the region is that the turtlebacks originated as mid-crustal ductile-thrust systems within the Cordilleran fold

  1. Modern pollen and stomate deposition in lake surface sediments from across the treeline on the Kola Peninsula, Russia.

    Science.gov (United States)

    Gervais, B R.; MacDonald, G M.

    2001-04-01

    We sampled and analyzed surface sediments from 31 lakes along a latitudinal transect crossing the coniferous treeline on the Kola Peninsula, Russia. The major vegetation zones along the transect were tundra, birch-forest tundra, pine-forest tundra, and forest. The results indicate that the major vegetation types in our study area have distinct pollen spectra. Sum-of-squares cluster analysis and principal components analysis (PCA) groupings of pollen sites correspond to the major vegetation zones. PCA ordination of taxa indicates that the first axis separates taxa typical of the forest zone (Pinus, Picea) from taxa typical of tundra and forest-tundra zones (Polypodiaceae, Ericaceae, and Betula). The current position of the coniferous treeline, defined in our region by Pinus sylvestris, occurs roughly where Pinus pollen values reach 35% or greater. Arboreal pollen (AP)/non-arboreal pollen (NAP) ratios were calculated for each site and plotted against geographic distance along the transect. AP/NAP ratios of 7 or greater are found within pine-forest tundra and forest vegetation zones. Pinus stomates (dispersed stomatal guard cells) are absent from sites north of the coniferous treeline and all but two samples from the forested sites contain stomates. Stomate concentrations among the samples are highly variable and range from 10 to 458 per ml and positively correlate with the changing Pinus pollen values.

  2. The response of tundra springtails (Collembola, Hexapoda) to human activity on the Murman coast of the Kola Penisula, Russia

    Science.gov (United States)

    Olejniczak, Izabella; Boniecki, Paweł; Kaliszewicz, Anita; Panteleeva, Ninel

    2018-03-01

    This study was carried out in the Dalne Zelentsy settlement (69°07‧N, 36°03‧E) on the Barents Sea of the Kola Penisula in Russia. Three transects were established: the 'new garden transect'; the 'old garden transect'; and the 'settlement transect'. Overall, the number of springtails increased with distance from the 'settlement' and decreased from the 'old garden' towards the tundra. However, in the case of the 'new garden transect' there were no clear trends in springtail abundance. Eleven species of springtail were found, with Parisotoma notabilis being found at each of the studied areas along the transects. Trends in the species diversity of the springtail communities were not clear, and the values of H‧ ranged from 1.36 to 2.08. The springtail communities located 10 m from the 'new garden' and the 'old garden' were characterized by low species diversity compared with the other sites along the transects (H‧ values of 1.36 and 1.67, respectively). There were no differences in species diversity among the springtail communities along the 'settlement transect'.

  3. Magma flow paths and strain patterns in magma chambers growing by floor subsidence: a model based on magnetic fabric study of shallow-level plutons in the Stiavnica volcano-plutonic complex, Western Carpathians

    Czech Academy of Sciences Publication Activity Database

    Tomek, Filip; Žák, J.; Chadima, Martin

    2014-01-01

    Roč. 76, č. 11 (2014), Article 873 ISSN 0258-8900 Institutional support: RVO:67985831 Keywords : anisotropy of magnetic susceptibility (AMS) * caldera * intrusive strain * magma emplacement * pluton floor subsidence * stratovolcano Subject RIV: DB - Geology ; Mineralogy Impact factor: 2.519, year: 2014

  4. Devonian alkaline magmatism in the northern North China Craton: Geochemistry, SHRIMP zircon U-Pb geochronology and Sr-Nd-Hf isotopes

    Directory of Open Access Journals (Sweden)

    Dingling Huang

    2017-01-01

    Full Text Available The Wulanhada pluton is among the rare suite of Devonian alkaline plutons occurring along the northern margin of the North China Craton (NCC. The intrusion is mainly composed of quartz-monzonite. Here we report zircon SHRIMP U-Pb data from this intrusion which shows emplacement age of ca. 381.5 Ma. The rock is metaluminous with high (Na2O + K2O values ranging from 8.46 to 9.66 wt.%. The REE patterns of the rocks do not show any Eu anomaly whereas the primitive-mantle-normalized spider diagram shows strong positive Sr and Ba anomalies. The Wulanhada rocks exhibit high initial values of (87Sr/86Srt = 0.70762–0.70809, low ɛNd(t = −12.76 to −12.15 values and negative values of ɛHf(t = −23.49 to −17.02 with small variations in (176Hf/177Hft (0.281873–0.282049. These geochemical features and quantitative isotopic modeling results suggest that the rocks might have been formed through the partial melting of Neoarchean basic rocks in the lower crust of the NCC. The Wulanhada rocks, together with the Devonian alkaline rocks and mafic-ultramafic complex from neighboring regions, constitute a post-collisional magmatic belt along the northern NCC.

  5. Characterizing and modelling the radionuclide transport properties of fracture zones in plutonic rocks of the Canadian Shield

    International Nuclear Information System (INIS)

    Davison, C.C.; Kozak, E.T.; Frost, L.H.; Everitt, R.A.; Brown, A.; Gascoyne, M.; Scheier, N.W.

    1999-01-01

    Plutonic rocks of the Canadian Shield were investigated as a potential host medium for nuclear fuel waste disposal of used CANDU nuclear fuel. Field investigations at several geologic research areas on the Shield have shown that major fracture zones are the dominant pathways for the large scale movement of groundwater and solutes through plutonic rock bodies. Because of this, a significant amount of the geoscience work has focused on methods to identify, characterize and model the radionuclide transport properties of major fracture zones in the fractured plutonic rocks of the Shield. In order to quantify the transport properties of such fracture zones a series of, groundwater tracer tests were performed over a period of several years in several major, low dipping fracture zones. Sixteen tracer tests were performed using dipole recirculation methods to evaluate transport over distance scales ranging from 17 m to 700 m. It was concluded that only tracer tests can provide useful estimates of the effective porosity and dispersivity characteristics of these large fracture zones in plutonic rocks of the Canadian Shield. (author)

  6. Transpressional granite-emplacement model: Structural and magnetic study of the Pan-African Bandja granitic pluton (West Cameroon)

    Science.gov (United States)

    Sandjo, A. F. Yakeu; Njanko, T.; Njonfang, E.; Errami, E.; Rochette, P.; Fozing, E.

    2016-02-01

    The Pan-African NE-SW elongated Bandja granitic pluton, located at the western part of the Pan-African belt in Cameroon, is a K-feldspar megacryst granite. It is emplaced in banded gneiss and its NW border underwent mylonitization. The magmatic foliation shows NE-SW and NNE-SSW strike directions with moderate to strong dip respectively in its northern and central parts. This mostly, ferromagnetic granite displays magnetic fabrics carried by magnetite and characterized by (i) magnetic foliation with best poles at 295/34, 283/33 and 35/59 respectively in its northern, central and southern parts and (ii) a subhorizontal magnetic lineation with best line at 37/8, 191/9 and 267/22 respectively in the northern, central and southern parts. Magnetic lineation shows an `S' shape trend that allows to (1) consider the complete emplacement and deformation of the pluton during the Pan-African D 2 and D 3 events which occurred in the Pan-African belt in Cameroon and (2) reorganize Pan-African ages from Nguiessi Tchakam et al. (1997) compared with those of the other granitic plutons in the belt as: 686 ±17 Ma (Rb/Sr) for D 1 age of metamorphism recorded in gneiss; and the period between 604-557 Ma for D 2-D 3 emplacement and deformation age of the granitic pluton in a dextral ENE-WSW shear movement.

  7. Transformation of juvenile Izu-Bonin-Mariana oceanic arc into mature continental crust: An example from the Neogene Izu collision zone granitoid plutons, Central Japan

    Science.gov (United States)

    Saito, Satoshi; Tani, Kenichiro

    2017-04-01

    Granitic rocks (sensulato) are major constituents of upper continental crust. Recent reviews reveal that the average composition of Phanerozoic upper continental crust is granodioritic. Although oceanic arcs are regarded as a site producing continental crust material in an oceanic setting, intermediate to felsic igneous rocks occurring in modern oceanic arcs are dominantly tonalitic to trondhjemitic in composition and have lower incompatible element contents than the average upper continental crust. Therefore, juvenile oceanic arcs require additional processes in order to get transformed into mature continental crust enriched in incompatible elements. Neogene granitoid plutons are widely exposed in the Izu Collision Zone in central Japan, where the northern end of the Izu-Bonin-Mariana (IBM) arc (juvenile oceanic arc) has been colliding with the Honshu arc (mature island arc) since Middle Miocene. The plutons in this area are composed of various types of granitoids ranging from tonalite to trondhjemite, granodiorite, monzogranite and granite. Three main granitoid plutons are distributed in this area: Tanzawa plutonic complex, Kofu granitic complex, and Kaikomagatake granitoid pluton. Tanzawa plutonic complex is dominantly composed of tonalite and trondhjemite and characterized by low concentration of incompatible elements and shows geochemical similarity with modern juvenile oceanic arcs. In contrast, Kofu granitic complex and Kaikomagatake granitoid pluton consists mainly of granodiorite, monzogranite and granite and their incompatible element abundances are comparable to the average upper continental crust. Previous petrogenetic studies on these plutons suggested that (1) the Tanzawa plutonic complex formed by lower crustal anatexis of juvenile basaltic rocks occurring in the IBM arc, (2) the Kofu granitic complex formed by anatexis of 'hybrid lower crust' comprising of both basaltic rocks of the IBM arc and metasedimentary rocks of the Honshu arc, and (3) the

  8. Exploring the plutonic crust at a fast-spreading ridge:new drilling at Hess Deep

    Energy Technology Data Exchange (ETDEWEB)

    Gillis, Kathryn M. [Univ. of Victoria, BC (Canada). School of Earth and Ocean Sciences; Snow, Jonathan E. [Univ. of Houston, Houston, TX (United States). Earth & Atmospheric Sciences; Klaus, Adam [Texas A & M Univ., College Station, TX (United States). Integrated Ocean Drilling Program (IODP). United States Implementing Organization.; Guerin, Gilles [Lamont-Doherty Earth Observatory of Columbia Univ., Palisades, NY (United States). Borehole Research Group; Abe, Natsue [Japan Agency for Marine-Earth Science and Technology (JAMSTEC), Yokosuka (Japan). Inst. for Research on Earth Evolution (IFREE); Akizawa, Norikatsu [Kanazawa Univ. (Japan). Dept. of Earth Sciences; Ceuleneer, Georges [Univ. Paul Sabatier, Toulouse (France). Observatoire Midi-Pyrenees (UMS 831), CNRS; Cheadle, Michael J. [Univ. of Wyoming, Laramie, WY (United States). Dept. of Geology and Geophysics; Adriao, Alden de Brito [Federal Univ. of Rio Grande do Sul, Porto Alegre (Brazil). Geology Inst. (IGEO); Faak, Kathrin [Ruhr Univ., Bochum (Germany). Geological Inst.; Falloon, Trevor J. [Univ. of Tasmania, Hobart, TAS (Australia). Inst. for Marine and Antarctic Studies; Friedman, Sarah A. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology; Godard, Marguerite M. [Univ. Montpellier II (France). Geosciences Montpellier-UMR 5243; Harigane, Yumiko [National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Marine Geology Dept.; Horst, Andrew J. [Syracuse Univ., NY (United States). Dept. of Earth Science; Hoshide, Takashi [Tohoku Univ., Sendai (Japan). Graduate School of Science; Ildefonse, Benoit [Univ. Montpellier II (France). Lab. de Tectonophysique; Jean, Marlon M. [Northern Illinois Univ., DeKalb, IL (United States). Dept. of Geology and Environmental Geosciences; John, Barbara E. [Univ. of Wyoming, Laramie, WY (United States). Dept. of Geology and Geophysics; Koepke, Juergen H. [Univ. of Hannover (Germany). Inst. of Mineralogy; Machi, Sumiaki [Kanazawa Univ. (Japan). Dept. of Earth Sciences; Maeda, Jinichiro [Hokkaido Univ., Sapporo (Japan). Dept. of Natural History Sciences; Marks, Naomi E. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Chemistry and Material Sciences Dept.; McCaig, Andrew M. [Univ. of Leeds (United Kingdom). School of Earth and Environment; Meyer, Romain [Univ. of Bergen (Norway). Dept. of Earth Science and Centre for Geobiology; Morris, Antony [Univ. of Plymouth (United Kingdom). School of Earth, Ocean & Environmental Sciences; Nozaka, Toshio [Okayama Univ. (Japan). Dept. of Earth Sciences; Python, Marie [Hokkaido Univ., Sapporo (Japan). Dept. of Earth and Planetary Sciences; Saha, Abhishek [Indian Inst. of Science (IISC), Bangalore (India). Centre for Earth Sciences; Wintsch, Robert P. [Indiana Univ., Bloomington, IN (United States). Dept. of Geological Sciences

    2013-02-28

    Integrated Ocean Drilling Program (IODP) Hess Deep Expedition 345 was designed to sample lower crustal primitive gabbroic rocks that formed at the fast-spreading East Pacific Rise (EPR) in order to test models of magmatic accretion and the intensity of hydrothermal cooling at depth. The Hess Deep Rift was selected to exploit tectonic exposures of young EPR plutonic crust, building upon results from ODP Leg 147 as well as more recent submersible, remotely operated vehicle, and near-bottom surveys. The primary goal was to acquire the observations required to test end-member crustal accretion models that were in large part based on relationships from ophiolites, in combination with mid-ocean ridge geophysical studies. This goal was achieved with the recovery of primitive layered olivine gabbros and troctolites with many unexpected mineralogical and textural relationships, such as the abundance of orthopyroxene and the preservation of delicate skeletal olivine textures.

  9. Pluton emplacement and magmatic arc construction: A model from the Patagonian batholith

    Science.gov (United States)

    Bruce, Robert; Nelson, Eric; Weaver, Stephen

    1988-01-01

    A model of batholithic construction in Andean arcs and its applicability to possibly similar environments in the past is described. Age and compositional data from the Patagonian batholith of southern Chile show a long history of magmatism in any given area (total age range is 15 to 157 Ma), but different regions appear to have different magmatic starting ages. Furthermore, mafic rocks seem to be the oldest components of any given region. An assembly line model involving semicontinuous magmatism and uplift was outlined, which has implications for other terranes: uplift rates will be proportional to observed ranges in age, and total uplift will be proportional to the age of the oldest pluton in any given area. It is suggested that misleading results would be obtained if only small areas of similar terranes in the Archean were available for study.

  10. Magmatic Flow Record From AMS Data La Gloria Pluton, Central Chile

    Science.gov (United States)

    Gutierrez, F.; Payacan, I. J.; Calderon, S.

    2011-12-01

    La Gloria Pluton (LGP) is a 10 Ma epizonal intrusion in the Southern Andes, located 40 km east of Santiago, in central Chile. 20 km long and 5 km wide LPG has a thickness of 2.5 km, in the form of a NW elongating inverted canoe. LGP intrudes Miocene volcanics as NS extending cluster of Miocene granitoids. LGP was emplaced at the west of an inverse fault system without exhibiting significant post-intrusion deformation. The fault system includes the Laguna Negra Fault and the El Coironal Fault, at its southern and northern ends respectively. LGP has been interpreted to have had a short cooling time, where subsolidus reequilibration was not pervasive, allowing identification of early and late magmatic conditions and suggesting it to be a single closed chamber. LGP is zoned vertically from granodiorite/quartz monzodiorite to quartz monzonite towards the roof, where hornblende and biotite and minor magnetite-ilmenite are omnipresent. AMS samples were collected at 39 sites to determine of the magnetic anisotropy susceptibility tensor. Magnetic fabric is generally oblate and anisotropy values range from 1.3 to 13.9%, consistent with the prescience magnetite and ilmenite. Magnetic lineation (ML) has a NNW trend, a subhorizontal dip and values between 0.4 and 5.3%. Magnetic foliation (MF) has a NW trend and dip varying from vertical at the walls of the intrusive to subhorizontal inside and under the roof. MF values ranges between 0.8 and 13.3%. Since linear trend of MF is restricted to the LGP interior only and can not be caused by a simple inverse fault system, we interpret the AMS results as a consequence of magmatic flow. ML represents the main flow direction, where several shallow plutons intrude at 10Ma in NW direction. MF is consequence of convection, related to cooling and differentiation, and is comparable to numerical simulations of magma fluid-dynamics during differentiation (R4). Two profiles (EW and NS) indicate that MF linear trend is from 29°/km to 50

  11. The geology and geochronology of the Belmont pluton and microgranite dykes from the Margate area

    International Nuclear Information System (INIS)

    Thomas, R.J.; Eglington, B.M.; Kerr, A.

    1990-01-01

    Field, petrographic, geochemical and Rb-Sr isotope data are presented for two granitic units which are considered to represent amongst the youngest intrusive rocks in the Natal Metamorphic Province. These are the Belmont granite pluton and a suite of unfoliated biotite microgranite dykes from the Margate area. The data suggest that these rocks do not form part of a consanguineous suite as previously envisaged. It is concluded that the Belmont pluton (1055 ± 60Ma) should be assigned to the garnet leucogranite phase of the syntectonic Margate Suite, and that the dykes (∼965 Ma) represent the products of a discrete, late-stage magmatic event which took place towards the end of the Natal orogenesis. Furthermore, the high initial Sr isotopic ratio (∼0,715) of the dykes suggests that they were derived from the melting of pre-existing radiogenic crust. The termination of major tectono-magmatic events in the Late Proterozoic Namaqua-Natal Belt apparently youngs from west to east across South Africa. Reconstructions of Gondwanaland place the Falkland Plateau and the Maudheim Province of Antarctica off the southeast of Africa. Dates obtained from this region range from ∼1000Ma to ∼500Ma, suggesting a continued decrease in age of tectono-magmatic activity eastwards. The microgranite dykes described here are unequivocally amongst the youngest post-tectono-metamorphic intrusions of southern Natal, yet they do not preserve any whole-rock indication of Pan-African isotopic disturbances. Sparse Rb-Sr mineral isotopic data support this indication that there was no significant Pan-African activity in the Natal Metamorphic Province. 8 figs., 7 tabs., 38 refs

  12. U-Pb geochronology of Gangdese (Transhimalaya) plutonism in the Lhasa-Xigaze region, Tibet

    International Nuclear Information System (INIS)

    Schaerer, U.; Allegre, C.J.; Paris-6 Univ., 75; Paris-7 Univ., 75; Xu, R.H.

    1984-01-01

    A series of different plutons from the Lhasa-Xigaze segment of the Gangdese (Transhimalaya) belt has been studied by high-resolution U-Pb analyses of zircon (using zircon fractions of 5-100 grains each, selected upon specific grain characteristics). For two diorites, located east of Xigaze (Dazhuka), the zircons yield concordant ages of 93.4 +- 1.0 and 94.2 +- 1.0 m.y., respectively. Also concordant ages of 41.1 +- 0.4 and 41.7 +- 0.4 m.y. have been obtained for two granodiorites, collected southwest of Lhasa (Qushui). The precision on the ages of two granites from the Xigaze and Lhasa area, is limited by two factors: the presence of inherited radiogenic lead and the occurrence of subsequent lead loss. However, some concordant zircons, detected in both granites, define approximate ages of about 67 and 53 m.y., respectively. The inherited lead components show the melting of Precambrian material was involved in magma genesis. The U-Pb ages substantiate a magmatic activity lasting from mid-Cretaceous (Cenomanian) to Eocene (Lutetian) time. Such a period of plutonism at the southern margin of Eurasia, as well as the occurrence of magma generation from continental crust, suggest that the Gangdese range results from the subduction of Tethys oceanic lithosphere (Indian plate) underneath Eurasia (Eurasian plate). If this model is true, the collision of India with Eurasia (Along the Lhasa-Xigaze sector) postdates the emplacement of the 41 m.y. old Gangdese granodiorites, i.e. the collision occurred after Lutetian time. (orig.)

  13. Metamorphism and plutonism around the middle and south forks of the Feather River, California

    Science.gov (United States)

    Hietanen, Anna Martta

    1976-01-01

    The area around the Middle and South Forks of the Feather River provides information on metamorphic and igneous processes that bear on the origin of andesitic and granitic magmas in general and on the variation of their potassium content in particular. In the north, the area joins the Pulga and Bucks Lake quadrangles studied previously. Tectonically, this area is situated in the southern part of an arcuate segment of the Nevadan orogenic belt in the northwestern Sierra Nevada. The oldest rocks are metamorphosed calcalkaline island-arc-type andesite, dacite, and sodarhyolite with interbedded tuff layers (the Franklin Canyon Formation), all probably correlative with Devonian rocks in the Klamath Mountains. Younger rocks form a sequence of volcanic, volcaniclastic, and sedimentary rocks including some limestone (The Horseshoe Bend Formation), probably Permian in age. All the volcanic and sedimentary rocks were folded and recrystallized to the greenschist facies during the Nevadan (Jurassic) orogeny and were invaded by monzotonalitic magmas shortly thereafter. A second lineation and metamorphism to the epidote-amphibolite facies developed in a narrow zone around the plutons. In light of the concept of plate tectonics, it is suggested that the early (Devonian?) island-arc-type andesite, dacite, and sodarhyolite (the Franklin Canyon Formation) were derived from the mantle above a Benioff zone by partial melting of peridotite in hydrous conditions. The water was probably derived from an oceanic plate descending to the mantle. Later (Permian?) magmas were mainly basaltic; some discontinuous layers of potassium-rich rhyolite indicate a change into anhydrous conditions and a deeper level of magma generation. The plutonic magmas that invaded the metamorphic rocks at the end of the Jurassic may contain material from the mantle, the subducted oceanic lithosphere, and the downfolded metamorphic rocks. The ratio of partial melts from these three sources may have changed with time

  14. Geochemistry of mylonitic tourmaline-bearing granite- gneiss pluton in the northeast of June mine

    Directory of Open Access Journals (Sweden)

    Arezoo Moradi

    2017-07-01

    Full Text Available Introduction Studied mylonitic granite-gneiss body is located in the Northwest of the Azna region in the Lorestan province close to the June dimension stone mine. It is a part of the metamorphic- magmatic complex including granite-gneiss, amphibolite, marble and schist. The crystalline basement is attributed to late-Neoproterozoic and it indicates a Panafrican basement, which yields a laser-ablation ICP–MS U–Pb zircon ages of 608 ± 18 Ma and 588 ± 41 Ma (Shakerardakani et al., 2015. There are two granite-gneiss plutons in the complex that are Galeh– Dezh (Shabanian et al., 2009, and June plutons. The Galeh-Doz pluton are previously proposed as syn-deformation pluton with a major S-shaped bend which has been imparted during dextral shearing with a Late Cretaceous (Mohajjel and Fergusson, 2000. However, new age dating on the pluton using U–Pb in the magmatic zircon produced the late-Neoproterozoic dates (Nutman et al., 2014; Shakerardakani et al., 2015. The granite-gneiss plutons show mylonitic fabrics and microstructures (Shabanian et al., 2010. The geochemical characteristics of mylonitic granite-gneiss body near June mine in NW Azna, is in the focus of our research. Materials and methods Petrographic investigations of 30 thin sections were made. Then eight samples were selected and analyzed for whole rock major, trace and REE compositions by ICP-emission spectrometry and ICP-mass spectrometry using natural rock standards as reference samples for calibration at the ACME Analytical Laboratories in Vancouver, British Columbia, Canada. Results The studied gneiss- granitic body has lepido-granoblastic texture as its major texture. It variably shows evidence of dynamic deformation from ultramylonite to protomylonite. The gneiss- granite consists of quartz, alkali feldspar (mostly as perthite, plagioclase, biotite, white mica (muscovite and phengitic muscovite. Accessory phases in the granitoid include, tourmaline, zircon, magmatic epidote

  15. Progress of research on the influence of alkaline cation and alkaline solution on bentonite properties

    International Nuclear Information System (INIS)

    Ye Weimin; Zheng Zhenji; Chen Bao; Chen Yonggui

    2011-01-01

    Based on the previous laboratory studies and numerical simulation on bentonite in alkaline environments, the effects of alkaline cation and alkaline solution on mineral composition, microstructure, swelling capacity and hydraulic properties of bentonite are emphasized in this paper, temperature, pH values and concentration are discussed as main affecting factors. When bentonite is exposed to alkaline cation or alkaline solution, microstructure of bentonite will be changed due to the dissolution of montmorillonite and the formation of secondary minerals, which results in the decrease of swelling pressure. The amount of the reduction of swelling pressure depends on the concentration of alkaline solution. Temperature, polyvalent cation, salinity and concentration are the main factors affecting hydraulic properties of bentonite under alkaline conditions. Therefore, future research should focus on the mechanism of coupling effects of weak alkaline solutions on the mineral composition, microstructure, swelling capacity and hydraulic properties of bentonite under different temperatures and different pH values. (authors)

  16. Petrology of the Porriño late-Variscan pluton from NW Iberia. A model for post-tectonic plutons in collisional settings

    Energy Technology Data Exchange (ETDEWEB)

    González Menéndez, L.; Gallastegui, G.; Cuesta, A.; Montero, P.; Rubio-Ordoñez, A.; Molina, J.F.; Bea, F.

    2017-07-01

    The Variscan orogen of NW Iberia contains abundant syn- and post-tectonic granitoids. The post-tectonic granitoids are metaluminous to slightly peraluminous, I-type granites, monzogranites ± granodiorites ± tonalites. The Porriño pluton studied here is a representative example. It consists of two units: i) a pink-red, peraluminous, biotite granite and ii) a gray, metaluminous to peraluminous, biotite (± amphibole ± titanite) monzogranite, including maficintermediate enclaves. SHRIMP U-Pb dating yielded 290-295Ma ages for all the units. The mineralogy and geochemistry show that the pink-red granite has features of I- and A-type granites, whereas the gray monzogranite and enclaves are I-types. Sr isotopes show scattered values for the pink-red granite (87Sr/86Sr295Ma ≈ 0.702-0.710) and uniform values for the gray monzogranite and enclaves (87Sr/86Sr295Ma≈ 0.705-0.706). Geochemical results indicate a peritectic entrainment of clinopyroxene + orthopyroxene ± Ca-plagioclase ± ilmenite ± garnet, and minor accessory phases (± zircon ± titanite ± apatite) into a melt similar to the leucocratic gray monzogranite. A mafic-intermediate source is proposed for the gray monzogranite and its enclaves. Restitic protoliths generated granitic melts with A-type features such as the pink-red granite. The I-type nature of many post-tectonic granitoids could be explained by the previous extraction of S-type syn-tectonic granites that left restites and less fertile rocks. Late orogenic new melting affected the previously unmelted and more mafic lithologies of the lower-middle crust, and gave rise to I-type granitoids. Repeated melting events affecting such lithologies and previous restites could have generated granitic melts with A-type features.

  17. Monitoring of Soil Contamination by Heavy Metals in the Impact Zone of Copper-Nickel Smelter on the Kola Peninsula

    Science.gov (United States)

    Kashulina, G. M.

    2018-04-01

    The results of landscape monitoring of the concentrations of acid-extractable Ni, Cu, Co, Mn, and Zn in soils of the local impact zone of the Severonikel industrial complex on the Kola Peninsula are discussed. The aim of monitoring studies was to reveal the spatial and temporal regularities of variation in the degree of soil contamination by heavy metals. In 2001-2011, the concentrations of acid-extractable compounds of the elements in the upper part of organic soil horizons around this plant exceeded their background concentrations by two orders of magnitude for Cu and Co and by three orders of magnitude for Ni. The degree of topsoil contamination with Ni, Cu, and Co generally corresponded to the distance of the plots from the contamination source and to the modern technogenic load. However, because of the long period of the emissions, their extreme amounts, and complex composition, indirect factors—the degree of technogenic soil degradation, the loss of soil organic matter, saturation of the surface soil layers by the contaminating metals, and competitive relationships between the elements—also affect soil contamination level. The concentrations of all the studied metals in the topsoil are characterized by considerable (1.5 to 7 times) variability in their long-term dynamics. The most important factors of this variability for Ni, Cu, and Co are the organic matter content of the samples and the amount of atmospheric precipitation in the year preceding the sampling. An inverse relationship between element concentrations in the soils and the amount of atmospheric precipitation attests to the dynamic nature and reversible character of the accumulation of heavy metals in the soils.

  18. Long-term consequences for Northern Norway of a hypothetical release from the Kola nuclear power plant

    International Nuclear Information System (INIS)

    Howard, B.J.; Wright, S.M.; Salbu, B.; Skuterud, K.L.; Hove, K.; Loe, R.

    2004-01-01

    The spatial and temporal variation in radiocaesium and 90 Sr doses to two population groups of the two Northernmost counties of Norway, Troms and Finnmark, following a hypothetical accident at the Kola nuclear power plant (KNPP) have been estimated using a model implemented within a geographical information system. The hypothetical accident assumes a severe loss of coolant accident at the KNPP coincident with meteorological conditions causing significant radionuclide deposition in the two counties. External doses are estimated from ground deposition and the behaviour of the different population groups, and internal doses from predicted food product activity concentrations and dietary consumption data. Doses are predicted for reindeer keepers and other Norwegian inhabitants, taking account of existing 137 Cs and 90 Sr deposition but not including the remedial effect of any countermeasures that might be used. The predicted doses, arising mainly from radiocaesium, confirm the Arctic Monitoring and Assessment Programme assessment that residents of the Arctic are particularly vulnerable to radiocaesium contamination, which could persist for many years. External doses are predicted to be negligible compared to ingestion doses. Ingestion doses for reindeer keepers are predicted to exceed 1 mSv y -1 for several decades primarily due to their high consumption of reindeer meat. Other Norwegians would also be potentially exposed to doses exceeding 1 mSv y -1 for several years, especially if they consume many local products. Whilst reindeer production is the most important exposure pathway, freshwater fish, lamb meat, dairy products, mushrooms and berries are also significant contributors to predicted ingestion doses. Radionuclide fluxes, defined as the total output of radioactivity in food from an area for a unit time, are dominated by reindeer meat. The results show the need for an effective emergency response, with appropriate countermeasures, should an accident of the

  19. Alteration of podzolized tills by acid load near Ni-Cu smelters at Monchegorsk, Kola Peninsula, Russia

    Directory of Open Access Journals (Sweden)

    Räisänen, M.L.

    1994-06-01

    Full Text Available Mineralogy and geochemistry of podzolized tills was studied in the area of dieback forest near the Ni-Cu smelters at Monchegorsk, and less extensively forest damage near by Apatity and Kirovsk in the Russian Kola Peninsula. The abundances of main elements (Si, Al, Fe, Mg, Ca, K, Na in the <64 μm fraction were determined by the hot aqua regia digestion method and inductively coupled plasma spectrometry. The clay mineralogy of the silt plus clay fraction was examined by X-ray diffraction after selective extraction and heating treatments. At all study sites, trioctahedral mica and chlorite were totally weathered from the silt and clay fraction (<64 μm of the eluvial layer, leaving behind interstratified mica-vermiculite-smectite clays. In general, the mixed-layer clay of the eluvial layer had low levels of hydroxy interlayering. Illuviated layers were characterized by hydroxy interlayered vermiculite-chlorite. The abundance of chlorite and mica was greater, and the degree of interlayering lower, in parent tills than in the overlying illuviated layers. Regardless of differences in bedrock and till geochemistry, the weathering sequence throughout the podzolized till profile was coherent at most of the sampling sites. Exceptionally, in a few profiles sampled at the totally destroyed forest site, the swelling mixed-layer clay of the eluvial layer displayed a neochloritized structure. On the basis of XRD patterns and geochemistry of the samples, it was inferred that a short-term decomposition of plagioclase had promoted, via inputs of Al-hydroxides, the transformation of mica-vermiculite-smectite to a poorly crystalline interstratification of chlorite-aluminous montmorillonite. The accelerated weathering occurring occasionally in exposed places was probably activated by the strongly acidic load in the vicinity of the smelters and the city of Monchegorsk.

  20. Urinary Schistosomiasis among Children in Murbai and Surbai Communities of Ardo-Kola Local Government Area, Taraba State, Nigeria

    Science.gov (United States)

    Agere, H.; Wama, B. E.; Bingbeng, J. B.; Amuta, E. U.

    2016-01-01

    Background. This cross-sectional study was conducted to determine the prevalence, intensity of infection, and risk factors associated with urinary schistosomiasis among children in Murbai and Surbai communities of Ardo-Kola Local Government Area (LGA), Taraba State, Nigeria. Methods. Urine samples were analysed by the standard filtration technique using 10 ml syringe, Swinnex polypropylene filter holder (13 mm diameter), and polycarbonate membrane filters (12 μm porosity). Sociodemographic data and water contact activities were collated from children using structured questionnaires. Results. A point prevalence of 58.54% was reported out of the urine samples examined. Males were significantly more infected than their female counterparts (71.15% versus 43.66%, χ 2 = 89.12, p = 0.000). The age-related prevalence showed 6–10 and 11–15 years significantly infected with 78.70% and 73.02%, respectively (χ 2 = 89.12, p = 0.000). Light intensity of infection, 62.51%, was significantly higher than heavy intensity, 37.48%, among the infected children (χ 2 = 365.8, p = 0.000). Water contact activities such as fishing (OR = 4.01, CI = 3.04–5.61, p = 0.000), rice farming (OR = 4.01, CI = 2.96–5.36, p = 0.000), and dry season farming (OR = 4.78, CI = 3.68–6.22, p = 0.000) were the risk factors exposing children to infection in the area. Conclusion. There is an urgent need to undertake a large scale deworming control programme using praziquantel in the area. PMID:28096819

  1. Urinary Schistosomiasis among Children in Murbai and Surbai Communities of Ardo-Kola Local Government Area, Taraba State, Nigeria

    Directory of Open Access Journals (Sweden)

    R. S. Houmsou

    2016-01-01

    Full Text Available Background. This cross-sectional study was conducted to determine the prevalence, intensity of infection, and risk factors associated with urinary schistosomiasis among children in Murbai and Surbai communities of Ardo-Kola Local Government Area (LGA, Taraba State, Nigeria. Methods. Urine samples were analysed by the standard filtration technique using 10 ml syringe, Swinnex polypropylene filter holder (13 mm diameter, and polycarbonate membrane filters (12 μm porosity. Sociodemographic data and water contact activities were collated from children using structured questionnaires. Results. A point prevalence of 58.54% was reported out of the urine samples examined. Males were significantly more infected than their female counterparts (71.15% versus 43.66%, χ2 = 89.12, p=0.000. The age-related prevalence showed 6–10 and 11–15 years significantly infected with 78.70% and 73.02%, respectively (χ2 = 89.12, p=0.000. Light intensity of infection, 62.51%, was significantly higher than heavy intensity, 37.48%, among the infected children (χ2 = 365.8, p=0.000. Water contact activities such as fishing (OR = 4.01, CI = 3.04–5.61, p=0.000, rice farming (OR = 4.01, CI = 2.96–5.36, p=0.000, and dry season farming (OR = 4.78, CI = 3.68–6.22, p=0.000 were the risk factors exposing children to infection in the area. Conclusion. There is an urgent need to undertake a large scale deworming control programme using praziquantel in the area.

  2. Alkaline azide mutagenicity in cowpea

    Energy Technology Data Exchange (ETDEWEB)

    Mahna, S K; Bhargava, Anubha; Mohan, Lalit [Cytogenetics and Mycology Laboratory, Department of Botany, Government College, Ajmer (India)

    1990-07-01

    Sodium azide is known as a potent mutagen in cereals and legumes. It is very effective in acidic medium in barley. Here an attempt is made to measure the effectiveness of sodium azide in alkaline medium (pH 7.4) on cowpea (Vigna unguiculata (L.) Walp., variety FS-68). Seeds pre-soaked in distilled water for 5 hours were treated with different concentrations (10{sup -6}, 10{sup -5}, 10{sup -4} and 10{sup -3}M) of sodium azide (NaN{sub 3}) for 4 hours at 28{+-} 2 deg. C. Bottles were intermittently shaken, then the seeds were thoroughly washed in running tap water and subsequently planted in pots. The treatment caused significant biological damage such as reduction in seed germination, length of root and shoot, number of nodules and pods per plant and morphological leaf variations. Morphological, as well as chlorophyll mutants, were detected in M{sub 2}.

  3. Alkaline azide mutagenicity in cowpea

    International Nuclear Information System (INIS)

    Mahna, S.K.; Bhargava, Anubha; Mohan, Lalit

    1990-01-01

    Sodium azide is known as a potent mutagen in cereals and legumes. It is very effective in acidic medium in barley. Here an attempt is made to measure the effectiveness of sodium azide in alkaline medium (pH 7.4) on cowpea (Vigna unguiculata (L.) Walp., variety FS-68). Seeds pre-soaked in distilled water for 5 hours were treated with different concentrations (10 -6 , 10 -5 , 10 -4 and 10 -3 M) of sodium azide (NaN 3 ) for 4 hours at 28± 2 deg. C. Bottles were intermittently shaken, then the seeds were thoroughly washed in running tap water and subsequently planted in pots. The treatment caused significant biological damage such as reduction in seed germination, length of root and shoot, number of nodules and pods per plant and morphological leaf variations. Morphological, as well as chlorophyll mutants, were detected in M 2

  4. catalysed oxidation of atenolol by alkaline permanganate

    Indian Academy of Sciences (India)

    Unknown

    Abstract. Kinetics of ruthenium (III) catalyzed oxidation of atenolol by permanganate in alkaline medium at constant ionic strength of 0⋅30 mol dm3 has been studied spectrophotometrically using a rapid kinetic accessory. Reaction between permanganate and atenolol in alkaline medium exhibits 1 : 8 stoichiometry.

  5. Increased liver alkaline phosphatase and aminotransferase ...

    African Journals Online (AJOL)

    The effect of daily, oral administration of ethanolic extract of Khaya senegalensis stem bark (2mg/kg body weight) for 18days on the alkaline phosphatase, aspartate and alanine aminotransferase activities of rat liver and serum were investigated. Compared with the control, the activities of liver alkaline phosphatase (ALP), ...

  6. Alkaline pH sensor molecules.

    Science.gov (United States)

    Murayama, Takashi; Maruyama, Ichiro N

    2015-11-01

    Animals can survive only within a narrow pH range. This requires continual monitoring of environmental and body-fluid pH. Although a variety of acidic pH sensor molecules have been reported, alkaline pH sensor function is not well understood. This Review describes neuronal alkaline pH sensors, grouped according to whether they monitor extracellular or intracellular alkaline pH. Extracellular sensors include the receptor-type guanylyl cyclase, the insulin receptor-related receptor, ligand-gated Cl- channels, connexin hemichannels, two-pore-domain K+ channels, and transient receptor potential (TRP) channels. Intracellular sensors include TRP channels and gap junction channels. Identification of molecular mechanisms underlying alkaline pH sensing is crucial for understanding how animals respond to environmental alkaline pH and how body-fluid pH is maintained within a narrow range. © 2015 Wiley Periodicals, Inc.

  7. Climatic response of stable isotope variations in wood cellulose of pine (Pinus sylvestris l.) and their tree-ring width on the Kola Peninsula, north-western Russia

    International Nuclear Information System (INIS)

    Boettger, T.; Hiller, A.; Gehre, M.; Friedrich, M.; Kremenetski, C.

    2002-01-01

    The Kola Peninsula region of northwestern Russia, adjacent to relatively well studied Scandinavian areas, is climatically affected by not only the Gulf Stream and the North Atlantic but also the Eurasian continent. Living and subfossil pine trees from the Khibiny mountains on the Kola Peninsula were analysed for carbon, oxygen and hydrogen isotope composition and for tree-ring width. Comparisons of local meteorological and tree-ring data revealed significant correlations. δ 13 C and δ 18 O values are particularly sensitive to changes in the temperature in July and August and to precipitation in the winter months of the previous year, respectively. On average, 13 C in the cellulose of pine trees between c. 1000 and 1300 AD is enriched by δ values of around 1 per mille compared to the modern trees from this region. This indicates a distinctly warmer summer climate at that time (the Medieval Warm epoch in Europe) than recently observed. The δ 18 O values of wood cellulose and the δ 2 H values of non-exchangeable hydrogen of tree cellulose from both fossil and modern samples cover a wide range between around 22 and 29 per mille and between about -80 and -120 per mille vs. SMOW, respectively. This suggests variations in the seasonal distribution of precipitation at that time, assuming its source has remained the same as in the past. (author)

  8. Composition of coarse-grained magnetite from pegmatite dikes related to plutons of quartz monzonite in the Jabal Lababa area, Kingdom of Saudi Arabia

    Science.gov (United States)

    Overstreet, William C.; Mousa, Hassan; Matzko, John J.

    1985-01-01

    Crystals of magnetite as large as 30 mm long and 7 mm thick are locally present in quartz-rich zones of interior and exterior pegmatite dikes related to plutons of quartz monzonite in the Jabal Lababa area. Niobium, tin, and yttrium are strongly enriched in six specimens of magnetite from interior pegmatite dikes in a small pluton where these elements form geochemical anomalies in nonmagnetic heavy-mineral concentrates from wadi sediment. Less abundant anomalous elements in the magnetite are molybdenum, lead, and zirconium, which also tend to be present in anomalous amounts in the nonmagnetic concentrates from the niobium-bearing pluton. The most anomalous trace element in the magnetite is zinc, which is at least 10 times as abundant as it is in the quartz monzonite plutons or in the nonmagnetic concentrates. The capacity of magnetite to scavenge molybdenum, zinc, niobium, lead, tin, yttrium, and zirconium suggests the possible utility of magnetite as a geochemical sample medium.

  9. An evolving tectonic environment of Late Carboniferous to Early Permian granitic plutons in the Chinese Altai and Eastern Junggar terranes, Central Asian Orogenic Belt, NW China

    Science.gov (United States)

    Zhang, Chen; Liu, Dongdong; Luo, Qun; Liu, Luofu; Zhang, Yunzhao; Zhu, Deyu; Wang, Pengfei; Dai, Quanqi

    2018-06-01

    The Central Asian Orogenic Belt (CAOB) represents one of the most important sites of juvenile crustal growth during the Phanerozoic. Located in the central part of the CAOB, the Chinese Altai and Eastern Junggar terranes record the collisional processes between the peri-Siberian and Kazakhstan orogenic systems. However, the precise timing of collision between the two terranes remains controversial. The Wukuli and Kadelat plutons in the Chinese Altai belt are dated at ∼305 and ∼280 Ma respectively, whereas the Aketas pluton in the Eastern Junggar terrane is dated at ∼308 Ma. Granites from the Wukuli and Kadelat plutons are strongly peraluminous (A/CNK > 1.1), and are characterized by low Al2O3, Na2O, MnO, MgO, CaO and heavy rare earth element (HREE) contents, but with high SiO2, K2O and Rb contents as well as high Rb/Sr ratios. Granites from the Wukuli pluton have low εNd(t) and εHf(t) values of -3.7 to -3.4 and -9.7 to +4.9, whereas those from the Kadelat pluton have values of -3.6 to -3.4 and -8.0 to +2.6. These features suggest S-type affinity for the Wukuli and Kadelat plutons with magma derivation through partial melting of Mesoproterozoic metasediments. The Aketas pluton is composed of weakly peraluminous quartz monzonites that have A/CNK values ranging from 0.92 to 1.08, with high Na2O, Sr, and Sr/Y, and low Y, Yb, Nb, and Ta. These rocks display positive εNd(t) (+4.8 to +6.4) and εHf(t) (+9.7 to +14.6) values, and low initial 87Sr/86Sr ratios (0.703357-0.703868), similar to modern adakites, suggesting that the quartz monzonites were derived from the partial melting of lower crustal material. The geochemical characteristics suggest that the Aketas pluton was formed in a subduction-related setting, the Wukuli pluton in a syn-collisional setting, and the Kadelat pluton in the subsequent post-orogenic strike-slip-related setting. In combination with data from other granitoids in these two terranes, the Aketas pluton represents the youngest record of

  10. The Jeffers Brook diorite-granodiorite pluton: style of emplacement and role of volatiles at various crustal levels in Avalonian appinites, Canadian Appalachians

    Science.gov (United States)

    Pe-Piper, Georgia; Piper, David J. W.

    2018-04-01

    Small appinite plutons ca. 610 Ma outcrop in the peri-Gondwanan Avalon terrane of northern Nova Scotia, with different structural levels exposed. Field mapping shows that the Jeffers Brook pluton is a laccolith emplaced along an upper crustal thrust zone, likely in a dilational jog in a regional dextral strike-slip system. The oldest rocks are probably mafic sills, which heated the area facilitating emplacement of intermediate magmas. Cross-cutting relationships show that both mafic and intermediate magmas were supplied throughout the history of pluton emplacement. The modal composition, mineral chemistry, and bulk chemistry of gabbro, diorite, tonalite, granodiorite, and granite have been studied in the main plutonic phases, dykes, and sills, and mafic microgranular enclaves. As with the type appinites in the Scottish Caledonides, the pluton shows evidence of high water content: the dominance of hornblende, locally within pegmatitic texture; vesicles and irregular felsic patches in enclaves; and late aplite dykes. Analyzed mafic microgranular enclaves are geochemically similar to larger diorite bodies in the pluton. Tonalite-granodiorite is distinct from the diorite in trace-element geochemistry and radiogenic isotopes. Elsewhere to the east, similar rocks of the same age form vertically sheeted complexes in major shear zones; hornblende chemistry shows that they were emplaced at a deeper upper crustal level. This implies that little of the observed geochemical variability in the Jeffers Brook pluton was developed within the pluton. The general requirements to form appinites are proposed to be small magma volumes of subduction-related magmas that reach the upper crust because of continual heating by mafic magmas moving through strike-slip fault pathways and trapping of aqueous fluids rather than venting through volcanic activity.

  11. The distribution, geochronology and geochemistry of early Paleozoic granitoid plutons in the North Altun orogenic belt, NW China: Implications for the petrogenesis and tectonic evolution

    Science.gov (United States)

    Meng, Ling-Tong; Chen, Bai-Lin; Zhao, Ni-Na; Wu, Yu; Zhang, Wen-Gao; He, Jiang-Tao; Wang, Bin; Han, Mei-Mei

    2017-01-01

    Abundant early Paleozoic granitoid plutons are widely distributed in the North Altun orogenic belt. These rocks provide clues to the tectonic evolution of the North Altun orogenic belt and adjacent areas. In this paper, we report an integrated study of petrological features, U-Pb zircon dating, in situ zircon Hf isotope and whole-rock geochemical compositions for the Abei, 4337 Highland and Kaladawan Plutons from north to south in the North Altun orogenic belt. The dating yielded magma crystallization ages of 514 Ma for the Abei Pluton, 494 Ma for the 4337 Highland Pluton and 480-460 Ma for the Kaladawan Pluton, suggesting that they are all products of oceanic slab subduction because of the age constraint. The Abei monzogranites derived from the recycle of Paleoproterozoic continental crust under low-pressure and high-temperature conditions are products of subduction initiation. The 4337 Highland granodiorites have some adakitic geochemical signatures and are sourced from partial melting of thickened mafic lower continental crust. The Kaladawan quartz diorites are produced by partial melting of mantle wedge according to the positive εHf(t) values, and the Kaladawan monzogranite-syenogranite are derived from partial melting of Neoproterozoic continental crust mixing the juvenile underplated mafic material from the depleted mantle. These results, together with existing data, provide significant information about the evolution history of oceanic crust subduction during the 520-460 Ma. The initiation of subduction occurred during 520-500 Ma with formation of Abei Pluton; subsequent transition from steep-angle to flat-slab subduction at ca.500 Ma due to the arrival of buoyant oceanic plateaus, which induces the formation of 4337 Highland Pluton. With ongoing subduction, the steep-angle subduction system is reestablished to cause the formation of 480-460 Ma Kaladawan Pluton. Meanwhile, it is this model that account for the temporal-spatial distribution of these early

  12. A paleomagnetic and stable isotope study of the pluton at Rio Hondo near Questa, New Mexico: Implications for CRM related to hydrothermal alteration

    International Nuclear Information System (INIS)

    Hagstrum, J.T.; Johnson, C.M.

    1986-01-01

    Paleomagnetic and rock magnetic data combined with stable isotope data from the middle Tertiary pluton along the Rio Hondo in northern New Mexico suggest that its magnetic remanence has both thermal (TRM) and high-temperature chemical (CRM) components. Oxygen isotope temperatures indicate that magnetite associated with the more rapidly cooled higher levels of the pluton, and with mafic inclusions and cogenetic rhyolitic dikes sampled at lower levels of exposure, ceased subsolidus recrystallization and isotopic exchange above its Curie temperature (580 0 C) in the presence of a magmatic fluid. Continued cooling imparted a TRM to these portions of the pluton. The more slowly cooled granodiorite at lower levels has quartz-magnetite isotopic temperatures that are below the Curie temperature of magnetite implying that its magnetization is high-temperature CRM. Sub-Curie isotopic temperatures for other granitic plutons in the western U.S.A. suggest that CRM may be commonly derived from subsolidus interactions between magnetite and magmatic fluids in plutonic rocks. A meteoric-hydrothermal system generated by the cooling Rio Hondo pluton, and not by younger adjacent intrusions, resulted in limited alteration along zones of high permeability near the southern margin of the Rio Hondo pluton, and in more prevasive alteration of the pluton to the north. The meteoric-hydrothermal alteration occurred at relatively high temperatures (>350 0 C) and, with the exception of local chloritization, caused little visible alteration of the rocks. The isotopic ratios indicate that little of the magnetite could have grown from or exchanged with a meteoric-hydrothermal fluid. (orig.)

  13. Paleomagnetic and stable isotope study of the pluton at Rio Hondo near Questa, New Mexico: Implications for CRM related to hydrothermal alteration

    Energy Technology Data Exchange (ETDEWEB)

    Hagstrum, J T; Johnson, C M

    1986-06-01

    Paleomagnetic and rock magnetic data combined with stable isotope data from the middle Tertiary pluton along the Rio Hondo in northern New Mexico suggest that its magnetic remanence has both thermal (TRM) and high-temperature chemical (CRM) components. Oxygen isotope temperatures indicate that magnetite associated with the more rapidly cooled higher levels of the pluton, and with mafic inclusions and cogenetic rhyolitic dikes sampled at lower levels of exposure, ceased subsolidus recrystallization and isotopic exchange above its Curie temperature (580/sup 0/C) in the presence of a magmatic fluid. Continued cooling imparted a TRM to these portions of the pluton. The more slowly cooled granodiorite at lower levels has quartz-magnetite isotopic temperatures that are below the Curie temperature of magnetite implying that its magnetization is high-temperature CRM. Sub-Curie isotopic temperatures for other granitic plutons in the western U.S.A. suggest that CRM may be commonly derived from subsolidus interactions between magnetite and magmatic fluids in plutonic rocks. A meteoric-hydrothermal system generated by the cooling Rio Hondo pluton, and not by younger adjacent intrusions, resulted in limited alteration along zones of high permeability near the southern margin of the Rio Hondo pluton, and in more prevasive alteration of the pluton to the north. The meteoric-hydrothermal alteration occurred at relatively high temperatures (>350/sup 0/C) and, with the exception of local chloritization, caused little visible alteration of the rocks. The isotopic ratios indicate that little of the magnetite could have grown from or exchanged with a meteoric-hydrothermal fluid.

  14. The Shahewan rapakivi-textured granite – quartz monzonite pluton, Qinling orogen, central China: mineral composition and petrogenetic significance

    Directory of Open Access Journals (Sweden)

    Xiaoxia Wang

    2002-01-01

    Full Text Available The Mesozoic Shahewan pluton consists of four texturally different types of biotite-hornblende quartz monzonite. In the porphyritic types alkali feldspar occurs as euhedral or ovoidal megacrysts that are often mantled by one or more plagioclase shells, and as smaller grains in the groundmass. Quartz, plagioclase (An20–28, biotite, and hornblende occur as inclusions in the alkali feldspar megacrystsand, more abundantly, in the groundmass. Euhedral quartz crystals in the groundmass are not as common and well developed as in typical rapakivi granite. Compared to typical rapakivi granites, the mafic minerals (biotite and hornblende are rich in Mg and poor in Fe, and the whole rock is low in Si, K, F, Ga, Zr, LREE, Fe/Mg, and K/Na. The rocks of the Shahewan pluton are thus regarded as rapakivi-textured quartz monzonites and granites but not true rapakivi granites.

  15. Poly-phase Deformation Recorded in the Core of the Coast Plutonic Complex, Western British Columbia

    Science.gov (United States)

    Hamblock, J. M.; Andronicos, C. L.; Hurtado, J. M.

    2006-05-01

    The Coast Plutonic Complex of western British Columbia constitutes the largest batholith within the North American Cordillera. The field area for this study is Mt. Gamsby, an unexplored region above the Kitlope River, east of the Coast Shear Zone and at the southern end of the Central Gneiss Complex. The dominant lithologies on Mt. Gamsby include amphibolite and metasedimentary gneiss, gabbro-diorite, and orthogneiss. The amphibolite gneiss contains alternating amphibolite and felsic layers, with chlorite and epidote pervasive in some regions and garnet rare. This unit is commonly migmatized and contains various folds, boudins, and shear zones. The metasedimentary gneiss contains quartz, k-spar, graphite, chlorite, and perhaps cordierite, but appears to lack muscovite and aluminosilicates. The gabbro-diorite is salt and pepper in color and contains ca. 50% pyroxene and plagioclase. The orthogneiss is light in color and plagioclase-rich, with a texture varying from coarse-grained and undeformed to mylonitic. In some regions, this unit contains abundant mafic enclaves. At least four deformational events (D1-4) are observed. The second generation of folding, F2, is dominant in the area and resulted in the production of a large synform during sinistral shearing. The S1 foliation is observed only in the amphibolite gneiss and is orthogonal to S2, creating mushroom- type fold interference patterns. S2 foliations strike NW-SE and dip steeply to the SW, suggesting SW-NE directed shortening. L2 lineations developed on S2 plunge shallowly to the NW and SE, implying strike-slip motion. Although both dextral and sinistral motions are indicated by shear band data, sinistral motion is dominant. The average right and left lateral shear band orientation is nearly identical to S2, suggesting that right and left lateral shearing were synchronous. Foliations within the orthogneiss are parallel to the axes of S2 folds and boudins in the amphibolite gneiss, suggesting that emplacement

  16. Characterizing fractured plutonic rocks of the Canadian shield for deep geological disposal of Canada's radioactive wastes

    International Nuclear Information System (INIS)

    Lodha, G.S.; Davison, C.C.; Gascoyne, M.

    1998-01-01

    Since 1978 AECL has been investigating plutonic rocks of the Canadian Shield as a potential medium for the disposal of Canada's nuclear fuel waste. During the last two years this study has been continued as part of Ontario Hydro's used fuel disposal program. Methods have been developed for characterizing the geotechnical conditions at the regional scale of the Canadian Shield as well as for characterizing conditions at the site scale and the very near-field scale needed for locating and designing disposal vault rooms and waste emplacement areas. The Whiteshell Research Area (WRA) and the Underground Research Laboratory (URL) in southeastern Manitoba have been extensively used to develop and demonstrate the different scales of characterization methods. At the regional scale, airborne magnetic and electromagnetic surveys combined with LANDSAT 5 and surface gravity survey data have been helpful in identifying boundaries of the plutonic rocks , overburden thicknesses, major lineaments that might be geological structures, lithological contacts and depths of the batholiths. Surface geological mapping of exposed rock outcrops, combined with surface VLF/EM, radar and seismic reflection surveys were useful in identifying the orientation and depth continuity of low-dipping fracture zones beneath rock outcrops to a depth of 500 to 1000 m. The surface time-domain EM method has provided encouraging results for identifying the depth of highly saline pore waters. The regional site scale investigations at the WRA included the drilling of twenty deep boreholes (> 500 m) at seven separate study areas. Geological core logging combined with borehole geophysical logging, TV/ATV logging, flowmeter logging and full waveform sonic logging in these boreholes helped to confirm the location of hydro geologically important fractures, orient cores and infer the relative permeability of some fracture zones. Single-hole radar and crosshole seismic tomography surveys were useful to establish the

  17. Understanding the evolution of S- and I-type granitic plutons through analysis of apatite.

    Science.gov (United States)

    Hess, B. L.; Fiege, A.; Tailby, N.

    2017-12-01

    The major and trace element composition of apatites from the Lachlan fold belt (LFB) S- and I-type granitoids (Australia) and the Central French Massif (CFM) S-type leucogranites (France) were analyzed to investigate their compositional and redox variation. Apatite is a common accessory mineral in magmatic systems that can incorporate a variety of trace elements, including the polyvalent elements sulfur (S), iron (Fe), and manganese (Mn). It was recently discovered that apatite can incorporate three oxidation states of S (S6+, S4+, S2-) into its structure as a function of oxygen fugacity [1]. However, the oxidation states of Mn and Fe in apatite are essentially unknown (2+ and/or 3+). In this study, we collected many electron probe line transects across apatites in several different host phases from a variety of S- and I-type plutons. The F-H-Cl contents of the S- and I-type LFB samples were similar ( 2.9 wt% F, 0.4 wt% Cl, 0.5 wt% OH). The CFM S-types contained virtually no Cl and ranged from near-endmember OH-apatite to near-endmember F-apatite. The apatites of all studied the S- and I-type plutons are characterized by similar ranges of Fe content (X-ray absorption near-edge structure (XANES) spectroscopy. The spectra show variability in S oxidation states ranging from mostly sulfate down to nearly equal S6+/S2- ratios, indicating redox variations during apatite formation. The S-type Mn + Fe content plots in a 1:1 ratio against calcium (Ca) in atoms per formula unit, while the I-type apatites have too low Mn and Fe to show a clear trend. Thus, divalent Mn and Fe probably replace Ca2+ in the S-types' apatite structure, while the incorporation of trivalent Mn or Fe in apatite is rather unlikely. We suggest that Mn and Fe contents in apatite may become a useful tracer of melt evolution once the distributions coefficients are experimentally calibrated. [1] Konecke et al. (2017), Am Mineral

  18. Temporal Evolution of Volcanic and Plutonic Magmas Related to Porphyry Copper Ores Based on Zircon Geochemistry

    Science.gov (United States)

    Dilles, J. H.; Lee, R. G.; Wooden, J. L.; Koleszar, A. M.

    2015-12-01

    Porphyry Cu (Mo-Au) and epithermal Au-Ag ores are globally associated with shallow hydrous, strongly oxidized, and sulfur-rich arc intrusions. In many localities, long-lived magmatism includes evolution from early andesitic volcanic (v) and plutonic (p) rocks to later dacitic or rhyolitic compositions dominated by plutons. We compare zircon compositions from three igneous suites with different time spans: Yerington, USA (1 m.y., p>v), El Salvador, Chile (4 m.y., p>v), and Yanacocha, Peru (6 m.y., v>p). At Yerington granite dikes and ores formed in one event, at ES in 2 to 3 events spanning 3 m.y., and at Yanacocha in 6 events spanning 5 m.y. At both ES and Yanacocha, high-Al amphiboles likely crystallized at high temperature in the mid-crust and attest to deep magmas that periodically recharged the shallow chambers. At Yanacocha, these amphiboles contain anhydrite inclusions that require magmas were sulfur-rich and strongly oxidized (~NNO+2). The Ti-in-zircon geothermometer provides estimates of 920º to 620º C for zircon crystallization, and records both core to rim cooling and locally high temperature rim overgrowths. Ore-related silicic porphyries yield near-solidus crystallization temperatures of 750-650°C consistent with low zircon saturation temperatures. The latter zircons have large positive Ce/Ce* and small negative Eu/Eu*≥0.4 anomalies attesting to strongly oxidized conditions (Ballard et al., 2001), which we propose result from crystallization and SO2 loss to the magmatic-hydrothermal ore fluid (Dilles et al., 2015). The Hf, REE, Y, U, and Th contents of zircons are diverse in the magma suites, and Th/U vs Yb/Gd plots suggest a dominant role of crystal fractionation with lesser roles for both crustal contamination and mixing with high temperature deep-sourced mafic magma. Ce/Sm vs Yb/Gd plots suggest that magma REE contents at contamination are most evident in pre-ore magmas, whereas ore-forming intrusions at low temperatures are dominated by crystal

  19. Formation of Intermediate Plutonic Rocks by Magma Mixing: the Shoshonite Suite of Timna, Southern Israel.

    Science.gov (United States)

    Fox, S.; Katzir, Y.

    2017-12-01

    In magmatic series considered to form by crystal fractionation intermediate rocks are usually much less abundant than expected. Yet, intermediate plutonic rocks, predominantly monzodiorites, are very abundant in the Neoproterozoic Timna igneous complex, S. Israel. A previously unnoticed plutonic shoshonitic suite was recently defined and mapped in Timna (Litvinovsky et al., 2015). It mostly comprises intermediate rocks in a seemingly 'continuous' trend from monzodiorite through monzonite to quartz syenite. Macroscale textures including gradational boundaries of mafic and felsic rocks and MME suggest that magma mixing is central in forming intermediate rocks in Timna. Our petrographic, microtextural and mineral chemistry study delineates the mode of incipient mixing, ultimate mingling and crystal equilibration in hybrid melts. An EMP study of plagioclase from rocks across the suite provides a quantitative evaluation of textures indicative of magma mixing/mingling, including recurrent/patchy zoning, Ca spike, boxy/sponge cellular texture and anti-Rapakivi texture. Each texture has an affinity to a particular mixing region. A modal count of these textures leads to a kinetic mixing model involving multi temporal and spatial scales necessary to form the hybrid intermediate rocks. A `shell'-like model for varying degrees of mixing is developed with the more intensive mixing at the core and more abundant felsic and mafic end-members towards the outer layer. REE patterns in zircon shows that it originated from both mafic and felsic parent melts. Whole rock Fe vs Sr plot suggests a two-stage mixing between the monzogabbro and quartz-syenite producing first mesocratic syenite, and subsequent mixing with a fractionating monzogabbro resulting in monzonitic compositions. A fractionating monzogabbro intruded into a syenitic melt sequentially. While slowly cooling, the monzogabbro heated the immediate syenitic melt, lowering the viscosity and rheological obstruction to overturn

  20. Ion-adsorption REEs in regolith of the Liberty Hill pluton, South Carolina, USA: An effect of hydrothermal alteration

    Science.gov (United States)

    Bern, Carleton R.; Yesavage, Tiffany; Foley, Nora K.

    2017-01-01

    Ion-adsorbed rare earth element (REE) deposits supply the majority of world heavy REE production and substantial light REE production, but relatively little is known of their occurrence outside Southeast Asia. We examined the distribution and forms of REEs on a North American pluton located in the highly weathered and slowly eroding South Carolina Piedmont. The Hercynian Liberty Hill pluton experiences a modern climate that includes ~ 1500 mm annual rainfall and a mean annual temperature of 17 °C. The pluton is medium- to coarse-grained biotite-amphibole granite with minor biotite granite facies. REE-bearing phases are diverse and include monazite, zircon, titanite, allanite, apatite and bastnäsite. Weathered profiles were sampled up to 7 m-deep across the ~ 400 km2 pluton. In one profile, ion-adsorbed REEs plus yttrium (REE + Y) ranged up to 581 mg/kg and accounted for up to 77% of total REE + Y in saprolite. In other profiles, ion-adsorbed REE + Y ranged 12–194 mg/kg and only accounted for 3–37% of totals. The profile most enriched in ion-adsorbed REEs was located along the mapped boundary of two granite facies and contained trioctahedral smectite in the saprolite, evidence suggestive of hydrothermal alteration of biotite at that location. Post-emplacement deuteric alteration can generate easily weathered REE phases, particularly fluorocarbonates. In the case of Liberty Hill, hydrothermal alteration may have converted less soluble to more soluble REE minerals. Additionally, regolith P content was inversely correlated with the fraction ion-adsorbed REEs, and weathering related secondary REE-phosphates were found in some regolith profiles. Both patterns illustrate how low P content aids in the accumulation of ion-adsorbed REEs. The localized occurrence at Liberty Hill sheds light on conditions and processes that generate ion-adsorbed REEs.

  1. Structure, emplacement, and tectonic setting of Late Devonian granitoid plutons in the Teplá–Barrandian unit, Bohemian Massif

    Czech Academy of Sciences Publication Activity Database

    Žák, J.; Kratinová, Zuzana; Trubač, J.; Janoušek, V.; Sláma, Jiří; Mrlina, Jan

    2011-01-01

    Roč. 100, č. 7 (2011), s. 1477-1495 ISSN 1437-3254 R&D Projects: GA AV ČR KJB300120702 Institutional research plan: CEZ:AV0Z30120515; CEZ:AV0Z30130516 Keywords : Bohemian Massif * Teplá-Barrandian unit * Variscan orogeny * granite * pluton * subduction Subject RIV: DB - Geology ; Mineralogy Impact factor: 2.342, year: 2011

  2. Alkaline pretreatment of Mexican pine residues for bioethanol ...

    African Journals Online (AJOL)

    Alkaline pretreatment of Mexican pine residues for bioethanol production. ... Keywords: Lignocellulosic biomass, alkaline pretreatment, enzymatic hydrolysis, fermentable sugars, fermentation. African Journal of Biotechnology Vol. 12(31), pp.

  3. The ultimate fate of a synmagmatic shear zone. Interplay between rupturing and ductile flow in a cooling granite pluton

    Science.gov (United States)

    Zibra, I.; White, J. C.; Menegon, L.; Dering, G.; Gessner, K.

    2018-05-01

    The Neoarchean Cundimurra Pluton (Yilgarn Craton, Western Australia) was emplaced incrementally along the transpressional Cundimurra Shear Zone. During syndeformational cooling, discrete networks of cataclasites and ultramylonites developed in the narrowest segment of the shear zone, showing the same kinematics as the earlier synmagmatic structures. Lithological boundaries between aplite/pegmatite veins and host granitic gneiss show more intense pre-cataclasite fabrics than homogeneous material, and these boundaries later became the preferred sites of shear rupture and cataclasite nucleation. Transient ductile instabilities established along lithological boundaries culminated in shear rupture at relatively high temperature (∼500-600 °C). Here, tensile fractures at high angles from the fault plane formed asymmetrically on one side of the fault, indicating development during seismic rupture, establishing the oldest documented earthquake on Earth. Tourmaline veins were emplaced during brittle shearing, but fluid pressure probably played a minor role in brittle failure, as cataclasites are in places tourmaline-free. Subsequent ductile deformation localized in the rheologically weak tourmaline-rich aggregates, forming ultramylonites that deformed by grain-size sensitive creep. The shape and width of the pluton/shear zone and the regime of strain partitioning, induced by melt-present deformation and established during pluton emplacement, played a key role in controlling the local distribution of brittle and then ductile subsolidus structures.

  4. [Discussion on diagenesis of Xilingang pluton-constrained by X-ray Fluorescence spectroscopy, plasma mass spectrometry and Raman spectroscopy].

    Science.gov (United States)

    Tang, Yu-Kun; Chen, Guo-Neng; Zhang, Ke; Huang, Hai-Hua

    2013-05-01

    The results on Xilingang pluton, mainly consisting of red beds, granites containing numerous debris of red beds and granites, obtained by X-ray fluorescence spectroscopy, plasma mass spectrometry and Raman spectroscopy show: (1) Xilingang pluton from red beds, granites containing numerous debris of red beds to granites has obvious characteristics of decreasing silicon and alkali content, and rising ignition loss, dark mineral content and oxidation index; (2) Chondrite-normalized REE distribution curves and primitive mantle-normalized spider diagram for trace elements of redbed, granites containing numerous debris of red beds and granites have a good consistency, the distribution characteristics of elements are similar to Nanling transformation-type granite; (3) The value of Raman spectrogram characteristic peak of quartz crystal in Xilingang granite decreased from the center of quartz crystal, and FWHM is steady. According to the above, the authors believe that Xilingang granite formed was related to in-situ melting of red beds and underlying strata and magma consolidation. Volatile components were discharged continuously, and oxidation index decreased gradually in the melting process. In the process of diagenesis, the top of pluton tend to be an ongoing silicon and alkali increase, while TFeO and MgO continue to migrate to bottom, and crystallization environment is a relatively closed and steady system.

  5. A tale of 10 plutons - Revisited: Age of granitic rocks in the White Mountains, California and Nevada

    Science.gov (United States)

    McKee, E.H.; Conrad, J.E.

    1996-01-01

    40Ar/39Ar incremental heating analysis and conventional K-Ar age determinations on plutonic rocks of the White Mountains define two stages of magmatic emplacement: Late Cretaceous, between ca. 90 Ma and 75 Ma, and Middle-Late Jurassic, between ca. 180 and 140 Ma. The Jurassic stage can be divided into two substages, 180-165 Ma and 150-140 Ma. Thermal effects of the younger plutons on the older granitoids partially to completely reset ages, making it difficult to determine the age of emplacement and cooling of several of the plutons even by 40Ar/39Ar incremental heating analyses. New data together with published ages and regional geochronological synthesis of the Sierra Nevada batholith indicate that regions within the batholith have coherent periods or episodes of magmatic activity. In the White Mountains and Sierra Nevada directly to the west there was little or no activity in Early Jurassic and Early Cretaceous time; magmatism took place during relatively short intervals of 15 m.y. or less in the Middle and Late Jurassic and Late Cretaceous periods. The new K-Ar and 40Ar/39Ar analyses of granitoids from the White Mountains help, but do not completely clarify the complex history of emplacement, cooling, and reheating of the batholith.

  6. The Transhimalaya (Gangdese) plutonism in the Ladakh region: A U-Pb and Rb-Sr study

    International Nuclear Information System (INIS)

    Schaerer, U.; Hamet, J.; Allegre, C.J.

    1984-01-01

    The age and origin of the Transhimalaya (Gangdese) plutonic belt in the Ladakh area has been studied by high-resolution U-Pb analyses of accessory minerals (zircon and monazite/allanite) and Rb-Sr measurements on whole rock samples. The ages determined of 101+-2 m.y. for a granodiorite and of 60.7+-0.4 m.y. for a granite substantiate that the Transhimalaya plutonism was active at least in mid-Cretaceous (Albian) and earliest Tertiary (Palaeocene) times. A Rb-Sr isochron of 73.4+-2.4 m.y. might be fortuitous because the Rb-Sr systematics shows important heterogeneities on the whole rock scale. The inherited radiogenic lead in zircon demonstrates that anatexis of continental crust was involved in magma genesis. The thus recycled continental material was heterogeneous with respect to its primary ages and/or metamorphic history; the approximate minimum ages of the continental sources range from 350 to 590 m.y. The 101+-2 m.y. old Transhimalaya granodiorite, which intrudes a series of mainly basaltic island arc rocks (Dras Series) shows that this island arc was attached to the continental margin at that times. This is consistent with the hypothesis that the ''Ladakh Tethys'' closed through two subduction regimes: (1) an early Cretaceous subduction, which formed the Dras island arc, and (2) a late Cretaceous to Palaeocene subduction at the continental margin, which caused the emplacement of the Transhimalaya plutonic belt. (orig.)

  7. Contrasting magmatic structures between small plutons and batholiths emplaced at shallow crustal level (Sierras de Córdoba, Argentina)

    Science.gov (United States)

    Pinotti, Lucio P.; D'Eramo, Fernando J.; Weinberg, Roberto F.; Demartis, Manuel; Tubía, José María; Coniglio, Jorge E.; Radice, Stefania; Maffini, M. Natalia; Aragón, Eugenio

    2016-11-01

    Processes like injection, magma flow and differentiation and influence of the regional strain field are here described and contrasted to shed light on their role in the formation of small plutons and large batholiths their magmatic structures. The final geometric and compositional arrangement of magma bodies are a complex record of their construction and internal flow history. Magma injection, flow and differentiation, as well as regional stresses, all control the internal nature of magma bodies. Large magma bodies emplaced at shallow crustal levels result from the intrusion of multiple magma batches that interact in a variety of ways, depending on internal and external dynamics, and where the early magmatic, growth-related structures are commonly overprinted by subsequent history. In contrast, small plutons emplaced in the brittle-ductile transition more likely preserve growth-related structures, having a relatively simple cooling history and limited internal magma flow. Outcrop-scale magmatic structures in both cases record a rich set of complementary information that can help elucidate their evolution. Large and small granitic bodies of the Sierra Pampeanas preserve excellent exposures of magmatic structures that formed as magmas stepped through different rheological states during pluton growth and solidification. These structures reveal not only the flow pattern inside magma chambers, but also the rheological evolution of magmas in response to temperature evolution.

  8. Relationship of Technological Properties with Dynamic Recrystallization of Quartz on the Example of Objects of the Karelian-Kola Region

    Science.gov (United States)

    Skamnitskaya, Lubov; Rakov, Leonid; Bubnova, Tatyana; Shchiptsov, Vladimir

    2017-12-01

    account the staged dynamic dynamical recrystallization of quartz in natural conditions. This factor can play both a positive and a negative role at various stages of mineral formation. Its influence is reflected in the state of the crystal structure of quartz, which should be taken into account when developing effective technologies for its enrichment. The intermediate stage of dynamic recrystallization corresponding to the end of the second stage-the beginning of the third stage of quartz recrystallization-is optimal for the formation of high-purity quartz. When choosing a site for the first-stage quartz mining at large deposits in the Karelian-Kola region, one should be guided by the stage of dynamic recrystallization.

  9. Soil organic carbon sequestration as affected by afforestation: the Darab Kola forest (north of Iran) case study.

    Science.gov (United States)

    Kooch, Yahya; Hosseini, Seyed Mohsen; Zaccone, Claudio; Jalilvand, Hamid; Hojjati, Seyed Mohammad

    2012-09-01

    Following the ratification of the Kyoto Protocol, afforestation of formerly arable lands and/or degraded areas has been acknowledged as a land-use change contributing to the mitigation of increasing atmospheric CO(2) concentration in the atmosphere. In the present work, we study the soil organic carbon sequestration (SOCS) in 21 year old stands of maple (Acer velutinum Bioss.), oak (Quercus castaneifolia C.A. Mey.), and red pine (Pinus brutia Ten.) in the Darab Kola region, north of Iran. Soil samples were collected at four different depths (0-10, 10-20, 20-30, and 30-40 cm), and characterized with respect to bulk density, water content, electrical conductivity, pH, texture, lime content, total organic C, total N, and earthworm density and biomass. Data showed that afforested stands significantly affected soil characteristics, also raising SOCS phenomena, with values of 163.3, 120.6, and 102.1 Mg C ha(-1) for red pine, oak and maple stands, respectively, vs. 83.0 Mg C ha(-1) for the control region. Even if the dynamics of organic matter (OM) in soil is very complex and affected by several pedo-climatic factors, a stepwise regression method indicates that SOCS values in the studied area could be predicted using the following parameters, i.e., sand, clay, lime, and total N contents, and C/N ratio. In particular, although the chemical and physical stabilization capacity of organic C by soil is believed to be mainly governed by clay content, regression analysis showed a positive correlation between SOCS and sand (R = 0.86(**)), whereas a negative correlation with clay (R = -0.77(**)) was observed, thus suggesting that most of this organic C occurs as particulate OM instead of mineral-associated OM. Although the proposed models do not take into account possible changes due to natural and anthropogenic processes, they represent a simple way that could be used to evaluate and/or monitor the potential of each forest plantation in immobilizing organic C in soil (thus

  10. Alkaline sorbent injection for mercury control

    Science.gov (United States)

    Madden, Deborah A.; Holmes, Michael J.

    2002-01-01

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  11. Alkaline rocks and the occurrence of uranium

    International Nuclear Information System (INIS)

    Hambleton-Jones, B.B.; Toens, P.D.

    1980-10-01

    Many alkaline complexes contain uranium and other minerals in low concentrations and are regarded as constituting valuable potential reserves. Certain complex metallurgical problems, however, remain to be solved. Alkaline rocks occur in a number of forms and environments and it is noted that they are generated during periods of geological quiescence emplaced mainly in stable aseismic areas. Many occur along the extensions of oceanic transform faults beneath the continental crust and the application of this concept to areas not currently known to host alkaline complexes may prove useful in identifying potential target areas for prospecting operations [af

  12. A transformation for predicting mechanical changes resulting from time-dependent microcracking in plutonic rock

    International Nuclear Information System (INIS)

    Heinrich, W.F.

    1987-01-01

    A transformation for a simple phenomenological model of microcracking is proposed. It relates the evolution of microcrack size in an elastic solid (plutonic rock) under different temporal macro- and microstresses. In this model, for a rock property that changes as a result of microcracking, both the calculated and the experimentally determined evolution of that property for a given stress history can be used to determine the evolution of that property (for the same range) for any other stress history. For example, the transformation can be used to extrapolate the short-term extent of microcracking due to thermally induced stresses to time scales too long for experimental determination. This is of interest in assessing the long-term behaviour of rock surrounding a high level nuclear waste vault, where thermally induced microcracking may take tens of thousands of years to develop. Experimental strategies are suggested for validation of the phenomenological model. Where results are obtained from the corresponding mathematical models, the transformation facilitates the efficient calculation of functions that depend only on the state of microcrack size once the functions have been calculated for any convenient stress history

  13. Spinel and orthopyroxene exsolved from clinopyroxene in the Haladala pluton in the middle Tianshan (Xinjiang, China)

    Science.gov (United States)

    Zhu, Yongfeng; Chen, Jing; Xue, Yunxin; Feng, Wanyi; Jiang, Jiuyang

    2017-12-01

    The Haladala pluton, consisting of troctolite, olivine gabbro and gabbro with zircon SHRIMP U-Pb age of 309 ± 2 Ma (MSWD = 0.72), intruded the Devonian-Carboniferous arc segments in the middle Tianshan. Amphibole, coexisting with magnetite, amphibole, and phlogopite, crystallized in a magma chamber at depth of 20 km (6.9-7.4 kbar, 934-943 °C) based on various thermobaramoters. Two kinds of exsolution textures (spinel rods in clinopyroxene, orthopyroxene lamellae in clinopyroxene) occur in troctolite and olivine gabbro. We describe oriented spinel rods and orthopyroxene lamellae exsolved from the host clinopyroxene based on optical and high-resolution transmission electron microscope (HRTEM) observations. The spinel rods (100) are parallel to their host clinopyroxene (010). Orthopyroxene lamellae (010) are coherent and strictly parallel to their host clinopyroxene (010). Exsolution of spinel rods from the host clinopyroxene is controlled by the reaction of (Ca0.5M2+ 0.5)Fe3+[AlSiO6]in clinopyroxene → (Ca0.86-0.17M2+ 0.14-0.17)(M2 + 1.00-0.96Al0-0.04)[Al0.17-0.10Si1.83-1.90O6] + Fe3O4 + O2.

  14. Natural radionuclides in the rocks of the Valle del Cervo Pluton in Piedmont.

    Science.gov (United States)

    Sesana, Lucia; Fumagalli, Marco; Carnevale, Mauro; Polla, Giancarla; Facchini, Ugo; Colombo, Annita; Tunesi, Annalisa; De Capitani, Luisa; Rusconi, Rosella

    2006-01-01

    Monitoring of the gamma radiation in Valle del Cervo Pluton was performed by determining U and Th contents in the main rock types cropping out over the entire area and pertaining to the granitic complex, syenitic complex and monzonitic complex. In particular, syenitic rocks were largely used as building and ornamental materials (e.g. Sienite della Balma). All the samples are fresh and do not present joints or fractures filled with U minerals. In the crushed samples the activity of uranium varies from 346 to 764 Bq/kg. Concentration of thorium varies from 202 to 478 Bq/kg. For all the analysed rocks uranium activity is higher than thorium one. The lowest value of radioactive concentration is referred to rocks of the granitic complex. The most active rocks are syenites. The data confirm the high activities of Valle del Cervo rock types, strongly connected with high K content of the source magma (geochemical signature); on the contrary, the activity seems to be not related to the location of the samples.

  15. U-Pb geochronology on zircon from the Aouli pluton, Haute Moulouya area, Morocco

    International Nuclear Information System (INIS)

    Oukemeni, D.; Krogh, T.E.

    1995-01-01

    The Aouli Pluton consists of four units: (1) granodiorite; (2) grey granite; (3) pink granite - these three units constituting a spatially continuous massif, and (4) muscovite granite, which is exposed in two small stocks somewhat removed from the other units. U-Pb ages obtained on zircon and titanite are 333 ± 2 Ma and 319 ± 1.5 Ma for the granodiorite and grey granite respectively. The 14 ma age difference between the granodiorite and the grey granite supports the multiple injection hypothesis which was the outcome of geochemical studies (Oukemeni and Bourne, 1993). These two rocks also contain an inherited component which has been dated at 1520 Ma in the granudiorite and at 1245 ma and 1804 Ma in the grey granite. The inherited components suggest the possible presence of Precambian crust below the Haute Moulouya. Since the intrusion is late-to post-tectonic (Oukemeni and Bourne, 1993), the age of the granodiorite (333 ± 2 Ma) indicates that the Hercynian deformation is pre-Visean in the Haute Moulouya area, and, by extension, throughout the eastern meseta region. (authors). 14 refs. 4 figs. 3 tabs

  16. Anomally '60': a uraniferous granitic pluton on Melville Peninsula, N.W.T

    International Nuclear Information System (INIS)

    Delpierre, M.E.

    1982-01-01

    The Proterozoic (Aphebian) Penrhyn Group in the Foxe Fold Belt in south-central Melville Peninsula, N.W.T. hosts numerous coarse-grained to pegmatitic granitic plutons, some of which show a definite enrichment in uranium with a few being significantly anomalous. Anomaly '60' is caused by a strongly radioactive pegmatitic granite intrusion that occurs at the base of the Penrhyn metasediments which rest unconformably on Archean gneisses. The granite is both discordant and concordant with the Proterozoic country rocks (marbles and paragneisses) and exhibits ghost layering at numerous localities. Uranium mineralization as uranophane and other secondary minerals sometimes forming pseudomorphs after uraninite appears to show a strong association with biotite accumulations. Thorium is variably present and may exceed the uranium content. Results from rock geochemistry, ground radiometry, detailed prospecting and a diamond drill program of six short holes conducted in 1979, indicate that although some ore grade mineralization occurs over short sections, the low grade and tonnage potential coupled with logistical difficulties, makes this 'porphyry uranium' occurrence uneconomic at present

  17. The intrusive complexof the Island of Giglio: geomagnetic characteristics of plutonic facies with low susceptibility contrast

    Directory of Open Access Journals (Sweden)

    R. Cavallini

    1998-06-01

    Full Text Available Two main plutonic facies characterize the intrusive complex of the Island of Giglio, and the trend of their contact at depth has been modelled using a 2D½ analysis based on a detailed geomagnetic survey in order to verify the geological hypothesis of the subsurface geometry of this contact. The magnetic anomaly connected with the discontinuity is quite low, due to the small difference between the magnetic susceptibilities of the two granitic facies. Development of this model of inversion of the magnetic field, which is in good agreement with the geological interpretation, was made possible by: 1 accurate control of the geomagnetic time variations and consequent temporal reduction, 2 a very low level of the artificial magnetic noise, 3 high density of the magnetic survey, 4 detailed knowledge of the mapped geologic contact between facies and of their petrologic characteristics, and 5 direct local measurements of the magnetic susceptibilities of the key lithologies. The model shows the trends of the geological contact, as projected in three E-W sections, that dips eastward in the range between 210 and 540, supporting the geologic hypothesis that the Pietrabona facies represents an external shell of the shallowly emplaced Giglio monzogranite intrusion.

  18. Alkalinity in oil field waters - what alkalinity is and how it is measured

    International Nuclear Information System (INIS)

    Kaasa, B.; Oestvold, T.

    1996-01-01

    The alkalinity is an important parameter in the description of pH-behaviour, buffer capacity and scaling potentials in oil field waters. Although the alkalinity is widely used, it seems to be considerable confusion in connection with the concept. It is often used incorrectly and different authors define the concept in different ways. Several different methods for the determination of alkalinity can be found in the literature. This paper discusses the definition of alkalinity and how to use alkalinity in oil field waters to obtain data of importance for scale and pH predictions. There is also shown how a simple titration of oil field waters can give both the alkalinity and the content of organic acids in these waters. It is obvious from these findings that most of the methods used to day may give considerable errors when applied to oil field waters with high contents of organic acids. 8 refs., 8 figs., 5 tabs

  19. Optical properties of alkaline earth borate glasses

    African Journals Online (AJOL)

    user

    The alkaline earth borate glasses containing heavy metal oxides show good solubility of rare-earth ions. Glasses containing PbO exhibit low glass transition temperature (Tg) and high ..... These oxygen ions carry a partial negative charge and.

  20. Technetium recovery from high alkaline solution

    Energy Technology Data Exchange (ETDEWEB)

    Nash, Charles A.

    2016-07-12

    Disclosed are methods for recovering technetium from a highly alkaline solution. The highly alkaline solution can be a liquid waste solution from a nuclear waste processing system. Methods can include combining the solution with a reductant capable of reducing technetium at the high pH of the solution and adding to or forming in the solution an adsorbent capable of adsorbing the precipitated technetium at the high pH of the solution.

  1. Zircon Lu-Hf isotope systematics and U-Pb geochronology, whole-rock Sr-Nd isotopes and geochemistry of the early Jurassic Gokcedere pluton, Sakarya Zone-NE Turkey: a magmatic response to roll-back of the Paleo-Tethyan oceanic lithosphere

    Science.gov (United States)

    Karsli, Orhan; Dokuz, Abdurrahman; Kandemir, Raif

    2017-05-01

    The early Mesozoic was a critical era for the geodynamic evolution of the Sakarya Zone as transition from accretion to collision events in the region. However, its complex evolutionary history is still debated. To address this issue, we present new in situ zircon U-Pb ages and Lu-Hf isotope data, whole-rock Sr-Nd isotopes, and mineral chemistry and geochemistry data of plutonic rocks to better understand the magmatic processes. The Gokcedere pluton is mainly composed of gabbro and gabbroic diorite. LA-ICP-MS zircon U-Pb dating reveals that the pluton was emplaced in the early Jurassic (177 Ma). These gabbros and gabbroic diorites are characterized by relatively low SiO2 content of 47.09 to 57.15 wt% and high Mg# values varying from 46 to 75. The samples belong to the calc-alkaline series and exhibit a metaluminous I-type character. Moreover, they are slightly enriched in large ion lithophile elements (Rb, Ba, Th and K) and light rare earth elements and depleted in high field strength elements (Nb and Ti). Gabbroic rocks of the pluton have a depleted Sr-Nd isotopic composition, including low initial 87Sr/86Sr ranging from 0.705124 to 0.705599, relatively high ɛ Nd ( t) values varying from 0.1 to 3.5 and single-stage Nd model ages ( T DM1 = 0.65-0.95 Ga). In situ zircon analyses show that the rocks have variable and positive ɛ Hf ( t) values (4.6 to 13.5) and single-stage Hf model ages ( T DM1 = 0.30 to 0.65 Ga). Both the geochemical signature and Sr-Nd-Hf isotopic composition of the gabbroic rocks reveal that the magma of the studied rocks was formed by the partial melting of a depleted mantle wedge metasomatized by slab-derived fluids. The influence of slab fluids is mirrored by their trace-element characteristics. Trace-element modeling suggests that the primary magma was generated by a low and variable degree of partial melting ( 5-15%) of a depleted and young lithospheric mantle wedge consisting of phlogopite- and spinel-bearing lherzolite. Heat to melt the

  2. Petrology, geochemistry and LA-ICP-MS U-Pb geochronology of Paleoproterozoic basement rocks in Bangladesh: An evaluation of calc-alkaline magmatism and implication for Columbia supercontinent amalgamation

    Science.gov (United States)

    Hossain, Ismail; Tsunogae, Toshiaki; Tsutsumi, Yukiyasu; Takahashi, Kazuki

    2018-05-01

    The Paleoproterozoic (1.7 Ga) basement rocks from Maddhapara, Bangladesh show a large range of chemical variations (e.g. SiO2 = 50.7-74.7%) and include diorite, quartz diorite, monzodiorite, quartz monzonite and granite. The pluton overall displays metaluminous, calc-alkaline orogenic suite; mostly I-type suites formed within subduction-related magmatism. The observed major elements show general trends for fractional crystallization. Trace element contents also indicate the possibility of a fractionation or assimilation; explain the entire variation from diorite to monzonite, even granite. The pluton may have evolved the unique chemical features by a process that included partial melting of calc-alkaline lithologies and mixing of mantle-derived magmas, followed by fractional crystallization, and by assimilation of country rocks. The pluton shows evidence of crystal fractionation involving largely plagioclase, amphibole and possibly biotite. Some of the fractionated magmas may have mixed with more potassic melts from distinct parts of the continental lithosphere to produce granites and/or pegmatites. New geochronological results of granitic pegmatite (1722 ± 10 Ma) are indisputably consistent with diorite and tonalite and those data showing credible geochronological sequence (i.e., diorite - tonalite - granitic pegmatite). Identical Paleoproterozoic age (1.7 Ga) with distinctive magmatism of the Maddhapara basement rocks have agreeable relationship with the CITZ, India. The consistent magmatism is also common in the Transamazonian of South America, Trans-Hudson orogeny in North America, Bohemian Massif and the Svecofennian, Poland, have identified the sequential growth of the continent through the amalgamation of juvenile terrains, succeeded by a major collisional orogeny. Such Paleoproterozoic subduction-related orogens in Australia have similar counterparts in Antarctica and other part of the world. These types of Paleoproterozoic magmatism dominantly contributed

  3. Improved electrodes and gas impurity investigations on alkaline electrolysers

    DEFF Research Database (Denmark)

    Reissner, R.; Schiller, G.; Knoeri, T.

    Alkaline water electrolysis for hydrogenproduction is a well-established techniquebut some technological issues regarding thecoupling of alkaline water electrolysis andRenewable Energy Sources (RES) remain tobe improved.......Alkaline water electrolysis for hydrogenproduction is a well-established techniquebut some technological issues regarding thecoupling of alkaline water electrolysis andRenewable Energy Sources (RES) remain tobe improved....

  4. Growth of a Large Composite Magma System: the EJB Pluton, Eastern California.

    Science.gov (United States)

    Matty, D. J.; Vervoort, J.; Dufrane, A.; Hart, G.; Student, J.; Morgan, S.

    2008-12-01

    The composite EJB pluton crops out in the White-Inyo Mountains of eastern California, and comprises the Eureka Valley monzonite (EVM), the Joshua Flat quartz monzonite (JFQM), the Beer Creek granite (BCG), and an unnamed diorite. While sometimes equivocal, field relationships suggest that the EVM was emplaced first, followed by the JFQM, and finally the BCG; the diorite predates the BCG. Sylvester and others (GSAB, 1978) reported zircon U-Pb ages of 179±2 Ma for the EVM and 174±5 Ma for the JFQM. Coleman and others (GSAB, 2003) determined a U-Pb age of 179±3 Ma (via Pb-loss trajectory) for the BCG. Because of the uncertainty in the ages and ambiguous field relations, the sequence and duration of EJB magmatism remain unclear. To understand more fully the timing of EJB magmatism, we separated zircons from 12 samples collected from each of the main EJB units. These samples were characterized using light microscopy, SEM and CL techniques. U-Pb ages were determined from individual zircons by LA-ICP-MS following the method of Chang and others (G3, 2006). For the ages reported below, the reported uncertainties are based on factors within the analysis, but do not include external factors such as sample/standard bias or other matrix effects. Overall uncertainty in LA-ICPMS U-Pb geochronology is hard to assess, but we estimate that all ages reported below are subject to a minimum 2% uncertainty. We determined a concordant U-Pb age of 180±2 Ma for the EVM, which agrees with the results of Sylvester and others (1978). The unnamed diorite produced a concordant U-Pb age of 177±3 Ma. Concordant U-Pb ages of 172±2, 172±3, 173±2, 174±2, and 175±2 Ma were determined for individual samples of the JFQM and agree with the age reported by Sylvester and others (1978) of 174±5 Ma. Concordant U-Pb ages of 168±4, 168±3, 169±1, 172±2, and 172±2 Ma were determined for individual BCG samples. Within the reported error, there is no difference in age between individual samples of

  5. Late magmatic stage of the zoned Caleu pluton (Central Chile): insights from zircon crystallization conditions

    Science.gov (United States)

    Molina, P. G.; Parada, M.; Gutierrez, F. J.; Chang-Qiang, M.; Jianwei, L.; Yuanyuan, L.

    2012-12-01

    The Caleu pluton consists of three N-S elongated lithological zones: Gabbro-Diorite Zone (GDZ), Tonalite Zone (TZ) and Granodiorite Zone (GZ); western, middle and eastern portions of the pluton, respectively. The zones are thought to be previously differentiated in a common, isotopically depleted (Sr-Nd), subjacent magma reservoir at a 4 kbar equivalent depth. The emplacement should have occurred at the climax of the Cretaceous rifting. We present preliminary results of U238/Pb206 zircon geochronology; zircon saturation, Tsat(Zrn), and crystallization temperatures (Ti-in-Zrn); as well as relative oxidation states at time of crystallization, based on: (i) the sluggish REE and HFSE subsolidus diffusivities in zircon; (ii) the behavior of Ti4+↔Si4+ and Ce4+↔Zr4+ isovalent replacement, in addition to a constrained TiO2 activity in almost all typical crustal rocks; and (iii) relative oxidation states at time of crystallization, respectively. The latter are obtained by interpolation of the partition coefficients of trivalent (REE) and tetravalent (HFSE) curves in Onuma diagrams for each zircon, and then estimating relative Ce(IV)/Ce(III) ratios. Results obtained from 4 samples (a total of 77 zircon grains) collected from the three mentioned lithological zones indicate U/Pb ages of approximately 99.5 ±1.5 Ma, 96.8 ±0.6 Ma, and 94.4 +2.2 -0.8 Ma; and Ti-in Zrn ranges of ca. 720-870°C, ca. 680-820°C and ca. 750-840°C, for the GDZ, TZ and GZ samples, respectively. On the other hand Tsat(Zrn) of ca. 750-780°C in the TZ, and ca. 830-890°C in the GZ, were obtained. As expected saturation temperatures are similar or higher than Ti-in-Zrn obtained in zircon grains of TZ and GZ, respectively. Cathodoluminiscence images in zircon suggest a magmatic origin, due to absence of complex zoning patterns and fairly well conserved morphologies. Exceptionally the GDZ sample zircons show evidence of inheritance, indicating a xenocrystic and/or antecrystic origin. A relative Ce

  6. Main results on pilot operation during 5 years of the 3rd generation fuel in VVER-440 reactors of Kola NPP

    International Nuclear Information System (INIS)

    Saprykin, V.; Sumarokov, M.; Gagarinskiy, A.; Sumarokova, A.; Adeev, V.

    2015-01-01

    In the report the results of comparison of main neutron-physical data of exploitation of nuclear fuel are presented for the average enrichment (on U - 235) of 4.87 for the 2nd and 3rd (12 piece) generations with the results of calculations by the complex of the programs KASKAD for 5 fuel loadings of Kola NPP Unit 4 with the reactor VVER- 440. The basic feature of fuel of the 3rd generation as compared with the 2nd is a presence of ribs of inflexibility at corners instead of cover of the fuel assembly and also the increased amount of uranium. The arrangement of fuel rods with different enrichment in fuel assemblies of the 2nd and 3rd generations is chosen identical for the convenient comparison of neutronic and thermohydraulic characteristics of the fuel of different generations. The fuel of 3rd generation was situated in the core symmetrically to the fuel of 2nd one

  7. Indoor radon related to uranium in granitoids of the Central Bohemian plutonic complex

    International Nuclear Information System (INIS)

    Barnet, I.; Fojtikova, I.

    2004-01-01

    The study is based on the indoor radon data (one year measurements, Kodak LR 115 track etch detectors), vectorized geological maps 1:50000, vectorized coordinates of dwellings and uranium data for granitoid types of the Central Bohemian Plutonic Complex (CBPC). Using ArcGis 8.2 programme, the position of 16145 dwellings was linked to a geological database covering the CBPC (approx. 3200 km 2 ), and the type of underlying rock type was specified for each house. The resulting databases enabled us to calculate the mean EEC indoor Rn data for particular granitoid types and to study the relationship between the indoor Rn and the U concentrations. The petrogenetically variable CBPC was emplaced during Variscan orogenesis (330-350 Ma) and is among the most radioactive rock types within the Bohemian Massif. A long-term process of CBPC genesis resulted in more than 20 granitoid types, differing by their petrogenetic characteristics as well as mineralogical and chemical composition, including uranium concentration. The relation between the mean indoor radon values and uranium concentrations in particular rock types was examined. A positive regression between indoor Rn and uranium as the source of Rn soil gas clearly demonstrates how regional geology influences the indoor radon activity concentration in dwellings. The highest indoor Rn concentrations were observed in the Sedlcany granodiorite and Certovo bremeno syenite, where also the highest gamma dose rates (150-210 nGy.h -1 ) within all granitoid types in the Czech Republic were observed. The two rock types differ from other granitoids by a relatively high zircon concentration, which is the main source of U and subsequently of soil gas Rn being released from the bedrock. The lower indoor Rn values of Certovo bremeno syenite which do not correspond with the high U concentrations can be explained by a relatively low permeability of its clayey weathering crust. This feature was also observed for soil gas radon concentration

  8. Death Valley turtlebacks: Mesozoic contractional structures overprinted by Cenozoic extension and metamorphism beneath syn-extensional plutons

    Energy Technology Data Exchange (ETDEWEB)

    Pavlis, T L; Serpa, L [Department of Geological Sciences, University of Texas at El Paso, El Paso, TX 7996 (United States); Miller, M [Department of Geological Sciences, University of Oregon, Eugene, OR 97403 (United States)], E-mail: tlpavlis@utep.edu

    2008-07-01

    The term turtleback was first coined to describe the curvilinear fault surfaces that produced a distinctive geomorphic form in the Black Mountains east of Death Valley, and although it was decades before their full significance was appreciated, they remain one of the most distinctive features of the extensional structure of the Death Valley region. Historically the interpretation of the features has varied markedly, and misconceptions about their character continue to abound, including descriptions in popular field guides for the area. It the 1990's, however, the full history of the systems began to be apparent from several key data: 1) the dating of the plutonic assemblage associated with the turtlebacks demonstrated that late Miocene, syn-extensional plutonism was fundamental to their formation; 2) the plutonic assemblage forms an intrusive sheet structurally above the turtlebacks, indicating a tie between much of the high grade metamorphism and Cenozoic plutonism; 3) a modern analog for the syn-extensional plutonism in the Black Mountains was recognized beneath Death Valley with the imaging of a mid-crustal magma body; 4) the Neogene structural history was worked out in the turtlebacks showing that folding of early-formed shear zones formed the turtleback anticlinoria but overprinting by brittle faults produced the final form as they cut obliquely across the older structure; and 5) the pre-extensional structural history was clarified, demonstrating that Mesozoic basement-involved thrust systems are present within the turtlebacks, but have been overprinted by the extensional system. An unresolved issue is the significance of Eocene U-Pb dates for pegmatites within the region, but presumably these relate somehow to the pre-extensional history. Miller and Pavlis (2005; E. Sci. Rev.) reviewed many features of the turtlebacks, and our working model for the region is that the turtlebacks originated as mid-crustal ductile-thrust systems within the Cordilleran fold

  9. Death Valley turtlebacks: Mesozoic contractional structures overprinted by Cenozoic extension and metamorphism beneath syn-extensional plutons

    International Nuclear Information System (INIS)

    Pavlis, T L; Serpa, L; Miller, M

    2008-01-01

    The term turtleback was first coined to describe the curvilinear fault surfaces that produced a distinctive geomorphic form in the Black Mountains east of Death Valley, and although it was decades before their full significance was appreciated, they remain one of the most distinctive features of the extensional structure of the Death Valley region. Historically the interpretation of the features has varied markedly, and misconceptions about their character continue to abound, including descriptions in popular field guides for the area. It the 1990's, however, the full history of the systems began to be apparent from several key data: 1) the dating of the plutonic assemblage associated with the turtlebacks demonstrated that late Miocene, syn-extensional plutonism was fundamental to their formation; 2) the plutonic assemblage forms an intrusive sheet structurally above the turtlebacks, indicating a tie between much of the high grade metamorphism and Cenozoic plutonism; 3) a modern analog for the syn-extensional plutonism in the Black Mountains was recognized beneath Death Valley with the imaging of a mid-crustal magma body; 4) the Neogene structural history was worked out in the turtlebacks showing that folding of early-formed shear zones formed the turtleback anticlinoria but overprinting by brittle faults produced the final form as they cut obliquely across the older structure; and 5) the pre-extensional structural history was clarified, demonstrating that Mesozoic basement-involved thrust systems are present within the turtlebacks, but have been overprinted by the extensional system. An unresolved issue is the significance of Eocene U-Pb dates for pegmatites within the region, but presumably these relate somehow to the pre-extensional history. Miller and Pavlis (2005; E. Sci. Rev.) reviewed many features of the turtlebacks, and our working model for the region is that the turtlebacks originated as mid-crustal ductile-thrust systems within the Cordilleran fold

  10. The evolution of Neoproterozoic magmatism in Southernmost Brazil: shoshonitic, high-K tholeiitic and silica-saturated, sodic alkaline volcanism in post-collisional basins

    Directory of Open Access Journals (Sweden)

    Sommer Carlos A.

    2006-01-01

    Full Text Available The Neoproterozoic shoshonitic and mildly alkaline bimodal volcanism of Southernmost Brazil is represented by rock assemblages associated to sedimentary successions, deposited in strike-slip basins formed at the post-collisional stages of the Brasilian/Pan-African orogenic cycle. The best-preserved volcano sedimentary associations occur in the Camaquã and Campo Alegre Basins, respectively in the Sul-riograndense and Catarinense Shields and are outside the main shear belts or overlying the unaffected basement areas. These basins are characterized by alternation of volcanic cycles and siliciclastic sedimentation developed dominantly on a continental setting under subaerial conditions. This volcanism and the coeval plutonism evolved from high-K tholeiitic and calc-alkaline to shoshonitic and ended with a silica-saturated sodic alkaline magmatism, and its evolution were developed during at least 60 Ma. The compositional variation and evolution of post-collisional magmatism in southern Brazil are interpreted as the result mainly of melting of a heterogeneous mantle source, which includes garnet-phlogopite-bearing peridotites, veined-peridotites with abundant hydrated phases, such as amphibole, apatite and phlogopite, and eventually with the addition of an asthenospheric component. The subduction-related metasomatic character of post-collisional magmatism mantle sources in southern Brazil is put in evidence by Nb-negative anomalies and isotope features typical of EM1 sources.

  11. The features of element concentration in natural waters of the Kola North in conditions of environmental contamination

    Science.gov (United States)

    Bazova, Mariya; Moiseenko, Tatyana

    2016-04-01

    The intensive use of fossil fuels and industrial development in last century led to the formation of acid rain and water acidification. The problem of water acidification greatly was denoted in the middle of last century in North America and in Europe as a result of air emissions of acid gases, primarily sulfur dioxide. The process of water acidification due to the interaction of two factors: 1) the high deposition of acidifying substances, taking into account the duration of exposure; 2) the sensitivity of the natural catchment area of geological, landscape, geographic and climatic characteristics (Moiseenko, 2005). The effects of acid rains on metal migration and cycling were discussed in a number of previous studies (Jeffries, 1997; Moiseenko, 1999; Manio, 2001; Moiseenko, Gashkina, 2007). The distribution of elements in water lakes has been mixed and due to the change of geochemical cycles of elements occurring in the catchment area and in water. On the Kola Peninsula as a result of long-term operation of the copper-nickel smelter was the anthropogenic acidification and water pollution metals. Increased contents of elements due to the combined effect of three factors: 1) landscape-geochemical characteristics of watersheds; 2) dispersion with flue emissions; 3) leaching elements and bonding of metals with organic matter, especially in forested watersheds and wetlands. This region is subject to long-term effects of mining and smelting industries, and therefore difficult to find of water bodies, which can serve as a background lakes. It is proved that manmade acid rain lead to leach into the water of a large group of elements entering the water as a result of man-made streams, as well as the elements that consist of the rocks forming the watersheds. In order to identify the relationships between the components of the elemental composition of the water in the lake was made a factor analysis using a computer program «STATISTICA 10". Factor analysis revealed the

  12. Interaction of the lithospheric mantle and crustal melts for the generation of the Horoz pluton (Niğde, Turkey: whole-rock geochemical and Sr–Nd–Pb isotopic evidence

    Directory of Open Access Journals (Sweden)

    Kerim Kocak

    2016-08-01

    Full Text Available The Horoz pluton includes granitic and granodioritic rocks, with widespread mafic microgranular enclaves (MMEs. Petrochemically, the rocks of the pluton show calc-alkaline to shoshonitic and metaluminous to slightly peraluminous composition. The rocks also exhibit an enrichment in large ion lithophile elements, e.g. Rb, K, and depletions of high field strength elements such as Y, Lu, and Mg#, Ni, with a slightly concave-upward rare earth element pattern. Both granitic and granodioritic rocks exhibit geochemical characteristics of tonalite, trondhjemite and granodiorite assemblages, possibly developed by the partial melting of a thickened lower crust. The granitoids have high concentrations of Na2O (2.6–4.5 wt%, Sr (347–599 ppm, intermediate-high (La/YbN (8.2–18.1, mostly >11 , Al2O3 (13.2–16.9 wt%, average 15.3 wt%, low MgO (0.2–1.4 wt%, average 0.84 wt% and Co (0.7–10.3 ppm. The MMEs include higher Na2O (4.5–5.5 wt%, Sr (389–1149 ppm, Al2O3 (16.9–19.2 wt%, average 17.8 wt%, MgO (1.4–4.4 wt%, average 2.75 wt% and Co (6.2–18.7 ppm contents in comparison with that of their hosts. There is a lack of negative Eu anomalies, except a few samples. Both host rocks and MMEs have a low initial 87Sr/86Sr ratio (respectively 0.7046–0.7051 and 0.7047–0.7058, low eNd value (–1.8 to –0.2 and –0.6 to 0.7 at 50 Ma and highly radiogenic 208Pb/204Pb ratios (39.43–39.47 and 39.39–39.54. Whole-rock chemistry and isotopic data suggest that parent magmas of both MMEs and their hosts have derived from melts of the mixing between the lithospheric mantle and crustal end members, than fractional crystallization processes in crustal levels.

  13. Indoor radon risk associated to post-tectonic biotite granites from Vila Pouca de Aguiar pluton, northern Portugal.

    Science.gov (United States)

    Martins, L M O; Gomes, M E P; Teixeira, R J S; Pereira, A J S C; Neves, L J P F

    2016-11-01

    At Vila Pouca de Aguiar area, northern Portugal, crops out a post-tectonic Variscan granite pluton, related with the Régua-Vila Real-Verín fault zone, comprising three types of biotite granites. Among these granites, PSG granite yield the highest average contents of U, probably due to its enrichment in accessory U-bearing minerals such as zircon. In the proximity of faults and joints, these granites are often affected by different degrees of hydrothermal alteration, forming reddish altered rocks, commonly known as "episyenites". These altered rocks are probably associated to the occurrence of hydrothermal processes, which led to uranium enrichment in the most advanced stages of episyenitization. In these granites, both average gamma absorbed dose rates in outdoor and indoor air are higher than those of the world average. Furthermore, even in the worst usage scenario, all these granites can be used as a building material, since their annual effective doses are similar to the limit defined by the European Commission. The geometric mean of radon activity of 91 dwellings located at the Vila Pouca de Aguiar pluton is 568Bqm(-3), exceeding that of other northern Portuguese granites. Measurements carried out during a winter season, indicate that 62.6% of the analysed dwellings yield higher indoor radon average values than the Portuguese legislation limit (400Bqm(-3)), and annual effective doses due higher than the world's average value (1.2mSvy(-1)). The interaction of geogenic, architectural and anthropogenic features is crucial to explain the variance in the geometric mean of radon activity of dwellings from Vila Pouca de Aguiar pluton, but the role of geologic faults is probably the most important decisive factor to increase the indoor radon concentration in dwellings. Hence, the development of awareness campaigns in order to inform population about the incurred radiological risks to radon exposure are highly recommended for this specific area. Copyright © 2016

  14. Petrography and geochemistry of granitoids from the Samphire Pluton, South Australia: Implications for uranium mineralisation in overlying sediments

    Science.gov (United States)

    Domnick, Urs; Cook, Nigel J.; Bluck, Russel; Brown, Callan; Ciobanu, Cristiana L.

    2018-02-01

    The Blackbush uranium deposit (JORC Inferred Resource: 12,580 tonnes U), located on the north-eastern Eyre Peninsula, is currently the only sediment-hosted U deposit investigated in detail in the Gawler Craton. Uranium is hosted within Eocene sandstone of the Kanaka Beds, overlying Mesoproterozoic granites of the Samphire pluton, affiliated with the Hiltaba Intrusive Suite ( 1.6 Ga). These are considered the most probable source rocks for uranium mineralisation. By constraining the petrography and mineralogy of the granites, insights into the post-emplacement evolution can be gained, which may provide an exploration indicator for other sediment-hosted uranium systems. Three geochemically distinct granite types were identified in the Samphire Pluton and correspond to domains interpreted from geophysical data. All granites show complex alteration overprints and textures with increasing intensity closer to the deposit, as well as crosscutting veining. Alkali feldspar has been replaced by porous K-feldspar and albite, and plagioclase is overprinted by an assemblage of porous albite + sericite ± calc-silicates (prehnite, pumpellyite and epidote). This style of feldspar alteration is regionally widespread and known from Hiltaba-aged granites associated with iron-oxide copper-gold mineralisation at Olympic Dam and in the Moonta-Wallaroo region. In two granite types biotite is replaced by calcic garnet. Calc-silicates are indicative of Ca-metasomatism, sourced from the anorthite component of altered plagioclase. Minor clay alteration of feldspars is present in all samples. Mineral assemblages in veins include quartz + hematite, hematite + coffinite, fluorite + quartz, and clay minerals. Minor chlorite and sericite are found in all vein types. All granite types are anomalously rich in U (concentrations between 10 and 81 ppm). Highly variable Th/U ratios, as well as hydrothermal U minerals (mostly coffinite) in granites and veins, are clear evidence for U mobility. Uranium

  15. The use of borehole geophysical logs and hydrologic tests to characterize plutonic rock for nuclear fuel waste disposal

    International Nuclear Information System (INIS)

    Davison, C.C.

    1984-05-01

    The selection of an igneous rock body for the disposal of nuclear fuel waste will likely require the drilling and testing of a number of deep investigative boreholes in the rock body. Although coring of at least one hole at each Research Area will be essential, methods for making in situ geophysical and hydrological measurements can substitute for widespread coring and result in significant savings in time and money. A number of borehole methods have been applied to the investigation of plutonic rocks at Whiteshell Nuclear Research Establishment and Chalk River Nuclear Laboratories in Canada

  16. Assessing ocean alkalinity for carbon sequestration

    Science.gov (United States)

    Renforth, Phil; Henderson, Gideon

    2017-09-01

    Over the coming century humanity may need to find reservoirs to store several trillions of tons of carbon dioxide (CO2) emitted from fossil fuel combustion, which would otherwise cause dangerous climate change if it were left in the atmosphere. Carbon storage in the ocean as bicarbonate ions (by increasing ocean alkalinity) has received very little attention. Yet recent work suggests sufficient capacity to sequester copious quantities of CO2. It may be possible to sequester hundreds of billions to trillions of tons of C without surpassing postindustrial average carbonate saturation states in the surface ocean. When globally distributed, the impact of elevated alkalinity is potentially small and may help ameliorate the effects of ocean acidification. However, the local impact around addition sites may be more acute but is specific to the mineral and technology. The alkalinity of the ocean increases naturally because of rock weathering in which >1.5 mol of carbon are removed from the atmosphere for every mole of magnesium or calcium dissolved from silicate minerals (e.g., wollastonite, olivine, and anorthite) and 0.5 mol for carbonate minerals (e.g., calcite and dolomite). These processes are responsible for naturally sequestering 0.5 billion tons of CO2 per year. Alkalinity is reduced in the ocean through carbonate mineral precipitation, which is almost exclusively formed from biological activity. Most of the previous work on the biological response to changes in carbonate chemistry have focused on acidifying conditions. More research is required to understand carbonate precipitation at elevated alkalinity to constrain the longevity of carbon storage. A range of technologies have been proposed to increase ocean alkalinity (accelerated weathering of limestone, enhanced weathering, electrochemical promoted weathering, and ocean liming), the cost of which may be comparable to alternative carbon sequestration proposals (e.g., $20-100 tCO2-1). There are still many

  17. Posttranslational heterogeneity of bone alkaline phosphatase in metabolic bone disease.

    Science.gov (United States)

    Langlois, M R; Delanghe, J R; Kaufman, J M; De Buyzere, M L; Van Hoecke, M J; Leroux-Roels, G G

    1994-09-01

    Bone alkaline phosphatase is a marker of osteoblast activity. In order to study the posttranscriptional modification (glycosylation) of bone alkaline phosphatase in bone disease, we investigated the relationship between mass and catalytic activity of bone alkaline phosphatase in patients with osteoporosis and hyperthyroidism. Serum bone alkaline phosphatase activity was measured after lectin precipitation using the Iso-ALP test kit. Mass concentration of bone alkaline phosphatase was determined with an immunoradiometric assay (Tandem-R Ostase). In general, serum bone alkaline phosphatase mass and activity concentration correlated well. The activity : mass ratio of bone alkaline phosphatase was low in hyperthyroidism. Activation energy of the reaction catalysed by bone alkaline phosphatase was high in osteoporosis and in hyperthyroidism. Experiments with neuraminidase digestion further demonstrated that the thermodynamic heterogeneity of bone alkaline phosphatase can be explained by a different glycosylation of the enzyme.

  18. High temperature and pressure alkaline electrolysis

    DEFF Research Database (Denmark)

    Allebrod, Frank; Chatzichristodoulou, Christodoulos; Mogensen, Mogens Bjerg

    2013-01-01

    Alkaline electrolyzers have proven to operate reliable for decades on a large scale, but in order to become commercially attractive and compete against conventional technologies for hydrogen production, the production and investment costs have to be reduced. This may occur by increasing the opera......Alkaline electrolyzers have proven to operate reliable for decades on a large scale, but in order to become commercially attractive and compete against conventional technologies for hydrogen production, the production and investment costs have to be reduced. This may occur by increasing...

  19. Catalytic oxidation of soot over alkaline niobates

    International Nuclear Information System (INIS)

    Pecchi, G.; Cabrera, B.; Buljan, A.; Delgado, E.J.; Gordon, A.L.; Jimenez, R.

    2013-01-01

    Highlights: ► No previous reported studies about alkaline niobates as catalysts for soot oxidation. ► NaNbO 3 and KNbO 3 perovskite-type oxides show lower activation energy than other lanthanoid perovskite-type oxides. ► The alkaline niobate does not show deactivation by metal loss. - Abstract: The lack of studies in the current literature about the assessment of alkaline niobates as catalysts for soot oxidation has motivated this research. In this study, the synthesis, characterization and assessment of alkaline metal niobates as catalysts for soot combustion are reported. The solids MNbO 3 (M = Li, Na, K, Rb) are synthesized by a citrate method, calcined at 450 °C, 550 °C, 650 °C, 750 °C, and characterized by AAS, N 2 adsorption, XRD, O 2 -TPD, FTIR and SEM. All the alkaline niobates show catalytic activity for soot combustion, and the activity depends basically on the nature of the alkaline metal and the calcination temperature. The highest catalytic activity, expressed as the temperature at which combustion of carbon black occurs at the maximum rate, is shown by KNbO 3 calcined at 650 °C. At this calcination temperature, the catalytic activity follows an order dependent on the atomic number, namely: KNbO 3 > NaNbO 3 > LiNbO 3 . The RbNbO 3 solid do not follow this trend presumably due to the perovskite structure was not reached. The highest catalytic activity shown by of KNbO 3 , despite the lower apparent activation energy of NaNbO 3 , stress the importance of the metal nature and suggests the hypothesis that K + ions are the active sites for soot combustion. It must be pointed out that alkaline niobate subjected to consecutive soot combustion cycles does not show deactivation by metal loss, due to the stabilization of the alkaline metal inside the perovskite structure.

  20. Alkaline earth filled nickel skutterudite antimonide thermoelectrics

    Science.gov (United States)

    Singh, David Joseph

    2013-07-16

    A thermoelectric material including a body centered cubic filled skutterudite having the formula A.sub.xFe.sub.yNi.sub.zSb.sub.12, where A is an alkaline earth element, x is no more than approximately 1.0, and the sum of y and z is approximately equal to 4.0. The alkaline earth element includes guest atoms selected from the group consisting of Be, Mb, Ca, Sr, Ba, Ra and combinations thereof. The filled skutterudite is shown to have properties suitable for a wide variety of thermoelectric applications.

  1. Characteristics of Young Rhyolites at Taupo, New Zealand: Implications for the Sub-Surface Plutonic System

    Science.gov (United States)

    Wilson, C. J.; Charlier, B. L.

    2007-12-01

    The young history of Taupo volcano captures the growth and destruction in the 26.5 ka ca. 530 km3 Oruanui eruption of a large rhyolitic magma body, together with the subsequent rejuvenation of magma sources below the volcano. Integration of field information with petrological and isotopic studies at the whole-pumice and single- crystal scales provide a picture of this history. Several important contrasts are inferred to exist between Taupo and comparably-sized, long-lived silicic foci such at Long Valley and in the Bishop Tuff. At Taupo the following are demonstrable. 1. Even in crystal-poor rhyolites like the Oruanui, many grains are inherited antecrysts or xenocrysts. The Oruanui crystal-poor rhyolite body was an open system, with influxes of crystals (plus melt) from remobilised older crystal mush, melted metasedimentary country rocks and plutonics, and crystal-poor basaltic to andesitic magmas. 2. All the Taupo rhyolites were well mixed prior to eruption, and there are no gradients in the eruption products to suggest that the holding chamber(s) were stratified to any extent. 3. Mafic magmas rose into, interacted with, and ponded on the floors of crystal-poor rhyolite in the Oruanui and Waimihia (3.5 ka) examples, again implying that the chamber floor was sharply defined, not a gradual progression down into a more crystal- rich root zone. 4. Pre-Oruanui activity involved contrasting magma types being generated simultaneously, but erupting from geographically separated vents. Post-Oruanui activity has seen (subtly) contrasting magma groups being erupted from vents in the same geographic area, but separated in time. The Oruanui and post-Oruanui magmas are different and do not appear to be related by consanguinity or by mixing - the Oruanui eruption effectively destroyed its magma body. These features are consistent with rhyolite magma generation at Taupo that is exceptionally fast, driven by high fluxes of mafic magmas into a highly heterogeneous crustal melange

  2. The late-Variscan peraluminous Valdepeñas pluton (southern Central Iberian Zone)

    Energy Technology Data Exchange (ETDEWEB)

    Errandonea-Martín, J.; Carracedo-sánchez, M.; Sarrionandia, F.; Santos Zalduegui, J.F.; García de Madinabeitia, S.; Gil-Ibarguchi, J.I.

    2017-07-01

    The Valdepeñas pluton is the easternmost outcrop of the Cáceres-Valdepeñas magmatic alignment (southern Central Iberian Zone). This massif is constituted by a cordierite-bearing porphyritic monzogranite and may be grouped within the so-called “Serie Mixta” granitoids. The Valdepeñas monzogranite is of magnesian [FeOt/(FeOt+MgO)~0.76], alkali-calcic [(Na2O+K2O)–CaO=7.8–8.5] and peraluminous (A/CNK=1.14–1.20). Multielemental- and REE-normalized patterns are comparable to those of similar rocks in the Nisa- Alburquerque-Los Pedroches magmatic alignment, and slightly differ from those of the Montes de Toledo batholith, both in the southern Central Iberian Zone. The U-Pb zircon age of 303±3Ma is consistent with the late-orogenic character of the intrusion and is in accordance with most of the granitic peraluminous intrusions in the southern Central Iberian Zone. 86Sr/87Sr300Ma ratios (0.707424–0.711253), εNd300Mavalues (-5.53 to -6.68) and whole-rock major and trace element compositions of the studied rocks, suggest that the parental magma of the Valdepeñas monzogranite could derive from a crustal metaigneous source. The U-Pb ages (552–650Ma) of inherited zircon cores found in Valdepeñas monzogranite samples match those often found in Lower Paleozoic metavolcanics and granitic orthogneisses of Central Iberia and, furthermore, point to Upper Neoproterozoic metaigneous basement rocks as possible protoliths at the magma source. Based on the solubility of monazite in peraluminous melts, the estimated emplacement temperature of the studied monzogranite is 742–762ºC. The results obtained in this work would contribute to a better understanding of the origin of the “Serie Mixta” granitoids.

  3. Mineralogical, petrological and geochemical aspects of alkaline and alkaline-carbonatite associations from Brazil

    Science.gov (United States)

    Morbidelli, L.; Gomes, C. B.; Beccaluva, L.; Brotzu, P.; Conte, A. M.; Ruberti, E.; Traversa, G.

    1995-12-01

    A general description of Mesozoic and Tertiary (Fortaleza) Brazilian alkaline and alkaline-carbonatite districts is presented with reference to mineralogy, petrology, geochemistry and geochronology. It mainly refers to scientific results obtained during the last decade by an Italo-Brazilian research team. Alkaline occurrences are distributed across Brazilian territory from the southern (Piratini, Rio Grande do Sul State) to the northeastern (Fortaleza, Ceará State) regions and are mainly concentrated along the borders of the Paraná Basin generally coinciding with important tectonic lineaments. The most noteworthy characteristics of these alkaline and alkaline-carbonatite suites are: (i) prevalence of intrusive forms; (ii) abundance of cumulate assemblages (minor dunites, frequent clinopyroxenites and members of the ijolite series) and (iii) abundance of evolved rock-types. Many data demonstrate that crystal fractionation was the main process responsible for magma evolution of all Brazilian alkaline rocks. A hypothesis is proposed for the genesis of carbonatite liquids by immiscibility processes. The incidence of REE and trace elements for different major groups of lithotypes, belonging both to carbonatite-bearing and carbonatite-free districts, are documented. Sr and preliminary Nd isotopic data are indicative of a mantle origin for the least evolved magmas of all the studied occurrences. Mantle source material and melting models for the generation of the Brazilian alkaline magma types are also discussed.

  4. PLUTON: A Three-Group Model for the Radial Distribution of Plutonium, Burnup, and Power Profiles in Highly Irradiated LWR Fuel Rods

    International Nuclear Information System (INIS)

    Lemehov, Sergei; Nakamura, Jinichi; Suzuki, Motoe

    2001-01-01

    A three-group model (PLUTON) is described, which predicts the power density distribution, plutonium buildup, and burnup profiles across the fuel pellet radius as a function of in-pile time and parameters characterizing the type of reactor system with respect to fuel temperature and changes of density during the irradiation period. The PLUTON model is a part of two fuel performance codes (ASFAD and FEMAXI-V), which provide all necessary input for this model, mainly local temperatures and fuel matrix density across the radius. Comparisons between measurements and predictions of the PLUTON model are made on fuels with enrichments in the range 2.9 to 8.25% and with burnup between 21 000 and 64 000 MWd/t. It is shown that the PLUTON predictions are in good agreement with measurements as well as with predictions of the well-known TUBRNP model. The proposed model is flexibly applicable for all types of light water reactor (LWR) fuels, including mixed oxide, and for fuel tested in the Organization for Economic Corporation and Development's Halden heavy water reactor. The PLUTON three-group model is based on analytical (theoretical) consideration of neutron absorption in a resonant region of the fuel in its apparent form. It makes the model more flexible in comparison with the semi-empirical TUBRNP one-group model and allows the physically based model analysis of commercial LWR-type fuels at high burnup as well as analysis of experimental fuel rods tested in the Halden heavy water reactor, which is one of the main test reactors in the world. The differences in fuel behavior in the Halden reactor in terms of burnup distribution and plutonium buildup can be more clearly understood with the PLUTON model

  5. Isotopic characteristics (Nd and Sr) of the intrusive plutonism at the northwestern Amazonian Craton, Venezuela, and implications for the Paleoproterozoic evolution

    International Nuclear Information System (INIS)

    Teixeira, Wilson; Tassinari, Colombro Celso G.; Mondin, M.

    2002-01-01

    Nd and Sr analyses were performed on selected granitoid plutons that intrude Archean and Paleoproterozoic domains of the Guyana shield (Venezuela). The isotopic signatures of these plutons together with the geochronologic background of the country rocks are used to constrain their magma genesis and tectonic setting within the Paleoproterozoic evolutions of mobile belts (Maroni-Itacaiunas and Ventuari-Tapajos provinces) of the Amazonian Craton. The Encrucijada Suite (2187 +- 94 Ma), which intrudes Archean rocks of the Imataca Complex, originated predominantly from partial melt of this crust, as supported by negative epsilon Nd(2.1Ga ) values (-2.2 to - 4.9) and T DM ages between 2.82 and 2.49 Ga. Conversely, the plutons from the Supamo Complex (2230 - 2050 Ma) and Cuchivero Group (1980 - 1830 Ma), occurring within the adjoining Paleoproterozoic provinces, are juvenile in nature (derived from roughly contemporary protoliths). These bodies display T DM ages between 2.13 and 2.22 Ga, as well as positive epsilon Nd(2.1Ga ) values (+0.74 to + 3.05). Isotopic correlation diagrams 143 Nd/144 Nd vs. 147 Sm/144 Nd and 143 Nd/144 Nd vs. time) plotted together with the plutonic rocks and Imataca Complex rocks were evaluated taking into account the geologic background of the NW part of the Amazonian Craton. Interpretation of these isotopic data supports the idea of tectonic juxtaposition between the Imataca Complex and the Maroni-Itacaiunas province during the Transamazonian orogeny (2.25 - 2.05 Ga). On the other hand, the Cuchivero Group plutons have a contrasting isotopic signature compared to the other Paleoproterozoic plutonic rocks. This is consistent with the existence of a tectonic boundary between the Maroni-Itacaiunas and the Ventuari-Tapajos province in the late Paleoproterozoic. (author)

  6. Determination of Acidity and Alkalinity of Food Materials

    OpenAIRE

    三浦,芳助; 福永,祐子; 瀧川,裕里子; 津田,真美; 渡辺,陽子; 瀨山,一正

    2006-01-01

    The acidity and alkalinity of food materials in various menus was determined to clarify the influence of food on physiological functions. Menus mainly containing alkaline food materials (alkaline menu) and acid ones (acid menu) were compared. Determination of acidity and alkalinity was performed for each food material in the alkaline menu and acid menu, and acidity and alkalinity of one meal and a day's one were estimated. 1. Most of food materials in acid menu were assessed to be...

  7. The Alkaline Diet: Is There Evidence That an Alkaline pH Diet Benefits Health?

    Directory of Open Access Journals (Sweden)

    Gerry K. Schwalfenberg

    2012-01-01

    Full Text Available This review looks at the role of an alkaline diet in health. Pubmed was searched looking for articles on pH, potential renal acid loads, bone health, muscle, growth hormone, back pain, vitamin D and chemotherapy. Many books written in the lay literature on the alkaline diet were also reviewed and evaluated in light of the published medical literature. There may be some value in considering an alkaline diet in reducing morbidity and mortality from chronic diseases and further studies are warranted in this area of medicine.

  8. The Alkaline Diet: Is There Evidence That an Alkaline ph Diet Benefits Health?

    International Nuclear Information System (INIS)

    Schwalfenberg, G.K.

    2012-01-01

    This review looks at the role of an alkaline diet in health. Pub med was searched looking for articles on ph, potential renal acid loads, bone health, muscle, growth hormone, back pain, vitamin D and chemotherapy. Many books written in the lay literature on the alkaline diet were also reviewed and evaluated in light of the published medical literature. There may be some value in considering an alkaline diet in reducing morbidity and mortality from chronic diseases and further studies are warranted in this area of medicine

  9. Discordant K-Ar ages between hornblende and biotite from the Tanzawa tonalitic pluton in the southern Fossa Magna, central Japan

    International Nuclear Information System (INIS)

    Sato, Kohei; Shibata, Ken; Uchiumi, Shigeru

    1986-01-01

    K-Ar ages were determined for hornblende and biotite in three tonalites from the Tanzawa pluton in the southern Fossa Magna, central Japan. The two minerals show discordant ages of 10.1 and 10.7 Ma for hornblende and 4.6 - 5.1 Ma for biotite. The age data and field evidence indicate that the pluton was emplaced in the Tanzawa Group in Middle Miocene time and its slow cooling (ca. 50 deg C/Ma in average) resulted in younger ages of boitites than hornblendes due to lower closure temperature for biotite. (author)

  10. Volcanic-plutonic connections and metal fertility of highly evolved magma systems: A case study from the Herberton Sn-W-Mo Mineral Field, Queensland, Australia

    Science.gov (United States)

    Cheng, Yanbo; Spandler, Carl; Chang, Zhaoshan; Clarke, Gavin

    2018-03-01

    Understanding the connection between the highly evolved intrusive and extrusive systems is essential to explore the evolution of high silicic magma systems, which plays an important role in discussions of planetary differentiation, the growth of continents, crustal evolution, and the formation of highly evolved magma associated Sn-W-Mo mineral systems. To discern differences between "fertile" and "non-fertile" igneous rocks associated with Sn-W-Mo mineralization and reveal the genetic links between coeval intrusive and extrusive rocks, we integrate whole rock geochemistry, geochronology and Hf isotope signatures of igneous zircons from contemporaneous plutonic and volcanic rocks from the world-class Herberton Mineral Field of Queensland, Australia. The 310-300 Ma intrusive rocks and associated intra-plutonic W-Mo mineralization formed from relatively oxidized magmas after moderate degrees of crystal fractionation. The geochemical and isotopic features of the coeval volcanic succession are best reconciled utilizing the widely-accepted volcanic-plutonic connection model, whereby the volcanic rocks represent fractionated derivatives of the intrusive rocks. Older intrusions emplaced at 335-315 Ma formed from relatively low fO2 magmas that fractionated extensively to produce highly evolved granites that host Sn mineralization. Coeval volcanic rocks of this suite are compositionally less evolved than the intrusive rocks, thereby requiring a different model to link these plutonic-volcanic sequences. In this case, we propose that the most fractionated magmas were not lost to volcanism, but instead were effectively retained at the plutonic level, which allowed further localized build-up of volatiles and lithophile metals in the plutonic environment. This disconnection to the volcanism and degassing may be a crucial step for forming granite-hosted Sn mineralization. The transition between these two igneous regimes in Herberton region over a ∼30 m.y. period is attributed to

  11. Isotopic studies of the Eye-Dashwa Lakes pluton and the long-term integrity of whole-rock and mineral systems

    International Nuclear Information System (INIS)

    Peterman, Z.E.; Kamineni, D.C.

    1990-05-01

    This report presents results of isotopic studies of the Eye-Dashwa Lakes pluton, located near Atikokan, Ontario. Suites of pristine unaltered and highly altered core samples from deep boreholes were used to study Rb-Sr, U-Th-Pb and Sr-Nd systematics, whole-rock Pb isotopes and fission track dating of apatite. The results have been used to investigate natural analogues for radionuclide migration in the geosphere, the tectonic stability of the pluton and the extent of water-rock interaction in fracture zones

  12. Microstructures and magnetic fabrics of the Ngaoundéré granite pluton (Cameroon): Implications to the late-Pan-African evolution of Central Cameroon Shear Zone

    Science.gov (United States)

    Dawaï, Daouda; Tchameni, Rigobert; Bascou, Jérome; Awe Wangmene, Salomon; Fosso Tchunte, Périclex Martial; Bouchez, Jean-Luc

    2017-05-01

    The Ngaoundéré granite pluton, in Central-North Cameroon, located near the Central Cameroon Shear zone (CCSZ), and previously studied for its petrography and geochemistry, is characterized by the absence of macroscopic markers of deformation. In this study, we report microstructures and magnetic fabrics (AMS) of this pluton and discuss the relationship with the Pan-African evolution of the CCSZ. The pluton consists of a porphyritic Hbl-Bt-monzogranite at its rim and a porphyritic biotite-granite at its core, a petrographic distribution denoting a normal zoning pattern, i.e. more silicic toward the centre. As expected, magnetic susceptibilities values also exhibit a zoning pattern in agreement with petrographic zonation. Thermomagnetic data indicate that this pluton is dominantly ferromagnetic in behaviour. As indicated by its microstructures, the pluton has suffered a continuum of deformation from the magmatic state to the high temperature solid-state during magma crystallization and solidification. The magnetic foliations dominantly strike NE-SW and dip moderately to steeply and the lineations mostly plunge shallowly to the NE or SW, roughly parallel to NE-to ENE-trending Central Cameroun Shear Zone (CCSZ). The foliation poles define a girdle pattern with a zone axis (52°/11°) rather close to the best line of the lineations (44°/21°). These fabrics correlate with the structures of the country rocks ascribed by several workers to a regional transpression. Toward the margins of the pluton, particularly the northern one, the lineations tend to rotate from NE to N in azimuth. This change is interpreted as due to strain partitioning, simple shearing with NE-SW extension being relayed by compression toward the northern pluton border. This new magnetic fabric study suggests that the Ngaoundéré pluton (poorly dated at c. 575 Ma) was emplaced during the late stages of the CCSZ dextral transpressive movement. It also provides some more constraints on the correlation

  13. Rare earths, thorium, and other minor elements in sphene from some plutonic rocks in West-Central Alaska

    International Nuclear Information System (INIS)

    Staatz, M.H.; Conklin, N.M.; Brownfield, I.K.

    1977-01-01

    Sphene is an abundant accessory mineral in some abnormally radioactive plutonic rocks in west-central Alaska. Seven samples of sphene from four different areas in west-central Alaska contained from 20,350 to 39,180 parts per million total rare earths and 390 to 2000 ppM thorium. The lanthanide content in six of the seven sphenes is chiefly the light rare earths and is similar to that of crystal abundance; a seventh sphene from the Darby Mountains, however, contains above average amounts of the heavy rare earths. A comparison of the lanthanide distribution in sphene from several areas indicates that the structure of sphene will accommodate whatever lanthanides are available when the mineral crystallizes. The amount of thorium and rare earths in sphene is also affected by the presence of other accessory minerals. Sphene in rocks containing either allanite or zircon has a lower thorium content than in rocks that do not contain allanite or zircon. Sphene, because of its abundance, may contain the greater part of the rare earths and thorium in some of the plutonic rocks of west-central Alaska

  14. Paleozoic subduction complex and Paleozoic-Mesozoic island-arc volcano-plutonic assemblages in the northern Sierra terrane

    Science.gov (United States)

    Hanson, Richard E.; Girty, Gary H.; Harwood, David S.; Schweickert, Richard A.

    2000-01-01

    This field trip provides an overview of the stratigraphic and structural evolution of the northern Sierra terrane, which forms a significant part of the wall rocks on the western side of the later Mesozoic Sierra Nevada batholith in California. The terrane consists of a pre-Late Devonian subduction complex (Shoo Fly Complex) overlain by submarine arc-related deposits that record the evolution of three separate island-arc systems in the Late Sevonian-Early Mississippian, Permian, and Late Triassic-Jurassic. The two Paleozoic are packages and the underlying Shoo Fly Complex have an important bearing on plate-tectonic processes affecting the convergent margin outboard of the Paleozoic Cordilleran miogeocline, although their original paleogeographic relations to North America are controversial. The third arc package represents an overlap assemblage that ties the terrane to North America by the Late Triassic and helps constrain the nature and timing of Mesozoic orogenesis. Several of the field-trip stops examine the record of pre-Late Devonian subduction contained in the Shoo Fly Complex, as well as the paleovolcanology of the overlying Devonian to Jurassic arc rocks. Excellent glaciated exposures provide the opportunity to study a cross section through a tilted Devonian volcano-plutonic association. Additional stops focus on plutonic rocks emplaced during the Middle Jurassic arc magmatism in the terrane, and during the main pulse of Cretaceous magmatism in the Sierra Nevada batholith to the east.

  15. Alkaline Activator Impact on the Geopolymer Binders

    Science.gov (United States)

    Błaszczyński, Tomasz Z.; Król, Maciej R.

    2017-10-01

    Concrete structures are constantly moving in the direction of improving the durability. Durability depends on many factors, which are the composition of concrete mix, the usage of additives and admixtures and the place, where material will work and carry the load. The introduction of new geopolymer binders for geopolymer structures adds a new aspect that is type of used activator. This substance with strongly alkaline reaction is divided because of the physical state, the alkaline degree and above all the chemical composition. Taking into account, that at present the geopolymer binders are made essentially from waste materials or by-products from the combustion of coal or iron ore smelting, unambiguous determination of the effect of the activator on the properties of the geopolymer material requires a number of trials, researches and observation. This paper shows the influence of the most alkaline activators on the basic parameters of the durability of geopolymer binders. In this study there were used highly alkaline hydroxides, water glasses and granules, which are waste materials in a variety of processes taking place in chemical plants. As the substrate of geopolymer binders there were used fly ash which came from coal and high calcareous ash from the burning of lignite.

  16. ENHANCED OIL RECOVERY USING LOCAL ALKALINE

    African Journals Online (AJOL)

    user

    the discovery of new oil producing fields and the ever increasing ... followed by water flooding is between 35 to 50% of the ... involved and lack of scale up and is considered among ... carbonate alkaline chemical reacts with certain types of ... reservoirs because of the profusion of calcium and the ... damage the formation.

  17. Electrochemical behaviour of alkaline copper complexes

    Indian Academy of Sciences (India)

    Abstract. A search for non-cyanide plating baths for copper resulted in the development of alkaline copper complex baths containing trisodium citrate [TSC] and triethanolamine [TEA]. Voltammetric studies were carried out on platinum to understand the electrochemical behaviour of these complexes. In TSC solutions, the.

  18. Alkaline fuel cell technology in the lead

    International Nuclear Information System (INIS)

    Nor, J.K.

    2004-01-01

    The Alkaline Fuel Cell (AFC) was the first fuel cell successfully put into practice, a century after William Grove patented his 'hydrogen battery' in 1839. The space program provided the necessary momentum, and alkaline fuel cells became the power source for both the U.S. and Russian manned space flight. Astris Energi's mission has been to bring this technology down to earth as inexpensive, rugged fuel cells for everyday applications. The early cells, LABCELL 50 and LABCELL 200 were aimed at deployment in research labs, colleges and universities. They served well in technology demonstration projects such as the 1998 Mini Jeep, 2001 Golf Car and a series of portable and stationary fuel cell generators. The present third generation POWERSTACK MC250 poised for commercialization is being offered to AFC system integrators as a building block of fuel cell systems in numerous portable, stationary and transportation applications. It is also used in Astris' own E7 and E8 alkaline fuel cell generators. Astris alkaline technology leads the way toward economical, plentiful fuel cells. The paper highlights the progress achieved at Astris, improvements of performance, durability and simplicity of use, as well as the current and future thrust in technology development and commercialization. (author)

  19. Biomass production on saline-alkaline soils

    Energy Technology Data Exchange (ETDEWEB)

    Chaturvedi, A.N.

    1985-01-01

    In a trial of twelve tree species (both nitrogen fixing and non-fixing) for fuel plantations on saline-alkaline soil derived from Gangetic alluvium silty clay, Leucaena leucocephala failed completely after showing rapid growth for six months. Results for other species at age two showed that Prosopis juliflora had the best productivity.

  20. Production of alkaline proteases by alkalophilic Bacillus subtilis ...

    African Journals Online (AJOL)

    Tuoyo Aghomotsegin

    2016-11-23

    Nov 23, 2016 ... Key words: Production, alkaline protease, Bacillus subtilis, animal wastes, enzyme activity. ... Generally, alkaline proteases are produced using submerged fermentation .... biopolymer concentrations were reported to have an influence ... adding nitrogenous compounds stimulate microorganism growth and ...

  1. Osteocalcin and bone-specific alkaline phosphatase in Sickle cell ...

    African Journals Online (AJOL)

    specific alkaline phosphatase (b-AP) total protein levels were evaluated as indicators of bone turnover in twenty patients with sickle cell haemoglobinopathies and in twenty normal healthy individuals. The serum bonespecific alkaline phosphatase ...

  2. Composite Sunrise Butte pluton: Insights into Jurassic–Cretaceous collisional tectonics and magmatism in the Blue Mountains Province, northeastern Oregon

    Science.gov (United States)

    Johnson, Kenneth H.; Schwartz, J.J.; Žák, Jiří; Verner, Krystof; Barnes, Calvin G.; Walton, Clay; Wooden, Joseph L.; Wright, James E.; Kistler, Ronald W.

    2015-01-01

    The composite Sunrise Butte pluton, in the central part of the Blue Mountains Province, northeastern Oregon, preserves a record of subduction-related magmatism, arc-arc collision, crustal thickening, and deep-crustal anatexis. The earliest phase of the pluton (Desolation Creek unit) was generated in a subduction zone environment, as the oceanic lithosphere between the Wallowa and Olds Ferry island arcs was consumed. Zircons from this unit yielded a 206Pb/238U age of 160.2 ± 2.1 Ma. A magmatic lull ensued during arc-arc collision, after which partial melting at the base of the thickened Wallowa arc crust produced siliceous magma that was emplaced into metasedimentary rocks and serpentinite of the overthrust forearc complex. This magma crystallized to form the bulk of the Sunrise Butte composite pluton (the Sunrise Butte unit; 145.8 ± 2.2 Ma). The heat necessary for crustal anatexis was supplied by coeval mantle-derived magma (the Onion Gulch unit; 147.9 ± 1.8 Ma).The lull in magmatic activity between 160 and 148 Ma encompasses the timing of arc-arc collision (159–154 Ma), and it is similar to those lulls observed in adjacent areas of the Blue Mountains Province related to the same shortening event. Previous researchers have proposed a tectonic link between the Blue Mountains Province and the Klamath Mountains and northern Sierra Nevada Provinces farther to the south; however, timing of Late Jurassic deformation in the Blue Mountains Province predates the timing of the so-called Nevadan orogeny in the Klamath Mountains. In both the Blue Mountains Province and Klamath Mountains, the onset of deep-crustal partial melting initiated at ca. 148 Ma, suggesting a possible geodynamic link. One possibility is that the Late Jurassic shortening event recorded in the Blue Mountains Province may be a northerly extension of the Nevadan orogeny. Differences in the timing of these events in the Blue Mountains Province and the Klamath–Sierra Nevada Provinces suggest that

  3. Recognition of favorable zones for uranium and thorium accumulation, at Um Ara-Um Shilman granitic pluton, south eastern desert, Egypt, using airborne spectrometric and magnetic data

    International Nuclear Information System (INIS)

    Elkattan, E.M.

    1995-01-01

    The objective is aimed at identifying significant U and Th anomalies, the amount of re-mobilization of U and Th, the structural framework of the granite pluton and the distribution of spectrometric anomalies. The study revealed that the granite pluton could be represented as a single radio-lithologic unit excluding abnormal measurements exceeding Xban + 2S. It also revealed the existence of eight strong spectrometric anomalies. Observed values of eU correlate well with eTh, r=0.72 while the correlation between eU/eTh and eU is lacking, r=0.190. Meanwhile, there is a negative correlation between eU/eTh and eTh,r= -0.335. This deficiency in correlation suggests a limited or zero remobilization of uranium, which was partly governed by magmatic processes. Most of the radioactive anomalies were found within or near the major contact faults which may act as channels for mineralized fluids from the subsurface. These fluids possess increased concentrations of U and/or Th which could exist in appropriate chemical and/or structural traps. The U and Th anomalies were found to be associated with the northern and southern parts of the granite pluton respectively. The difference between the northern and southern parts of the granite pluton may be attributed to differences in radioelement content, the effect of partial and/or complete digestion of older rocks, or to different levels of erosion. (author)

  4. AN EARLY PERMIAN GARNET-BEATING PERALUMINOUS GRANITIC PLUTON IN THE SOUTH TIANSHAN OROGENIC BELT, NW CHINA: PETROLOGICAL, MINERALOGICAL AND GEOCHEMICAL CONSTRAINTS

    Directory of Open Access Journals (Sweden)

    Qie Qin

    2017-01-01

    Full Text Available The Ku’erchu granitic pluton (283±4 Ma was exposed in the eastern part of the South Tianshan Orogenic Belt. The granites from the intrusion are mainly composed of orthoclase (~45 vol. %, plagioclase (~15 vol. %, quartz (~20 vol. %, muscovite (~10 vol. % and biotite (~5 vol. %, with accessory minerals including garnet, zircon and Fe-Ti oxide.

  5. Three-dimensional cooling pattern of a granitic pluton 2. The study of deuteric sub-solidus reactions in the Toki granite, Central Japan

    International Nuclear Information System (INIS)

    Yuguchi, Takashi; Tsuruta, Tadahiko; Nishiyama, Tadao

    2011-01-01

    Petrographical studies examining the development and variations of sub-solidus reactions recorded in the Toki granite represent the three-dimensional cooling pattern of this zoned pluton in Central Japan. Samples collected from 19 boreholes in the Toki granite show characteristics indicative of spatial variations in the extent of the sub-solidus reactions. Exsolution coarsening has produced microperthite, including albite-rich lamellae, in this pluton, while deuteric coarsening has resulted in the formation of patchperthite, myrmekite, and the reaction rim. The extent of the deuteric coarsening reactions can be evaluated from the width and spacing of the albite-rich patch in patchperthite and from the thickness of myrmekite and the reaction rim. The width, spacing, and thickness of these textural features increase systematically with elevation; they also increase gradually in the horizontal inward direction in the western part of the pluton but not in the eastern part of the pluton. The systematic variations in textural development indicate that the Toki granite cooled effectively from the roof and from the western margin during the deuteric coarsening stage. The deuteric coarsening may have occurred at temperatures below 500°C, as indicated by ternary feldspar thermometry. (author)

  6. Time-scales of assembly and thermal history of a composite felsic pluton: constraints from the Emerald Lake area, northern Canadian Cordillera, Yukon

    Science.gov (United States)

    Coulson, Ian M.; Villeneuve, Mike E.; Dipple, Gregory M.; Duncan, Robert A.; Russell, James K.; Mortensen, James K.

    2002-05-01

    Knowledge of the time-scales of emplacement and thermal history during assembly of composite felsic plutons in the shallow crust are critical to deciphering the processes of crustal growth and magma chamber development. Detailed petrological and chemical study of the mid-Cretaceous, composite Emerald Lake pluton, from the northern Canadian Cordillera, Yukon Territory, coupled with U-Pb and 40Ar/ 39Ar geochronology, indicates that this pluton was intruded as a series of magmatic pulses. Intrusion of these pulses produced a strong petrological zonation from augite syenite, hornblende quartz syenite and monzonite, to biotite granite. Our data further indicate that multiple phases were emplaced and cooled to below the mineral closure temperatures over a time-scale on the order of the resolution of the 40Ar/ 39Ar technique (˜1 Myr), and that emplacement occurred at 94.3 Ma. Simple thermal modelling and heat conduction calculations were used to further constrain the temporal relationships within the intrusion. These calculations are consistent with the geochronology and show that emplacement and cooling were complete in less than 100 kyr and probably 70±5 kyr. These results demonstrate that production, transport and emplacement of the different phases of the Emerald Lake pluton occurred essentially simultaneously, and that these processes must also have been closely related in time and space. By analogy, these results provide insights into the assembly and petrogenesis of other complex intrusions and ultimately lead to an understanding of the processes involved in crustal development.

  7. PREPUBLICATION: From structure topology to chemical composition. XXIII. Revision of the crystal structure and chemical formula of zvyaginite, a seidozerite-supergroup mineral from the Lovozero alkaline massif, Kola peninsula, Russia

    KAUST Repository

    Sokolova, E.; Genovese, Alessandro; Falqui, Andrea; Hawthorne, F. C.; Cá mara, F.

    2017-01-01

    gave the following empirical formula [calculated on 22 (O + F)]:(Na0.75Ca0.09K0.04��1.12)Σ2 (Na1.12Zn0.88Mn0.17Fe2+0.04��0.79)Σ3(Nb1.68Ti1.25Al0.07)Σ3 (Si4.03O14)O2 [(OH)1.11F0.89]Σ2(H2O)4, Z = 4. Electron-diffraction patterns have prominent streaking

  8. La Escalerilla pluton, San Luis Argentina: The orogenic and post-orogenic magmatic evolution of the famatinian cycle at Sierras de San Luis

    Science.gov (United States)

    Morosini, Augusto Francisco; Ortiz Suárez, Ariel Emilio; Otamendi, Juan Enrique; Pagano, Diego Sebastián; Ramos, Gabriel Alejandro

    2017-01-01

    Field relationships, geochemical analysis and two new absolute ages (LA-MC-ICP-MS U/Pb-zircon) allow the division of the La Escalerilla pluton (previously considered to be a single granitic body) into two different plutons: a new La Escalerilla pluton (s.s.), dated at 476.7 ± 9.6 Ma, that represents the northern portion, and the El Volcán pluton, dated at 404.5 ± 8.5 Ma, located in the southern sector. The La Escalerilla pluton is composed of three facies: (1) biotite-bearing granodiorite, (2) porphyritic biotite-bearing granite, and (3) porphyritic two micas-bearing leucogranite, being the presence of late-magmatic dykes in these facies common. The El Volcán pluton is composed of two main facies: 1) porphyritic biotite-bearing granite, and 2) two micas-bearing leucogranite, but amphibole-bearing monzodioritic and tonalititic mega-enclaves are also common, as well as some dykes of amphibole and clinopyroxene-bearing syenites. A peculiarity between the two plutons is that their most representative facies (porphyritic biotite-bearing granites) have, apart from different absolute ages, distinctive geochemical characteristics in their concentrations of trace elements; the La Escalerilla granite is comparatively poorer in Ba, Sr, Nb, La, Ce, P, and richer in Rb, Tb, Y, Tm and Yb. The El Volcán granite is notably enriched in Sr and depleted in Y, resulting in high Sr/Y ratios (12.67-39.08) compared to the La Escalerilla granite (1.11-2.41). These contrasts indicate that the separation from their sources occurred at different depths: below 25 km for the La Escalerilla, and above 30 km for the El Volcán. Moreover, the contrasts allow us to interpret a thin crust linked to an environment of pre-collisional subduction for the first case, and a thickened crust of post-collisional environment for the second, respectively.

  9. Geochronological, geochemical, and Sr-Nd-Hf isotopic characteristics of Cretaceous monzonitic plutons in western Zhejiang Province, Southeast China: New insights into the petrogenesis of intermediate rocks

    Science.gov (United States)

    Liu, Liang; Qiu, Jian-Sheng; Zhao, Jiao-Long; Yang, Ze-Li

    2014-05-01

    We present comprehensive petrological, geochemical, and Sr-Nd-Hf isotopic data for the Matou and Dalai plutons in western Zhejiang Province, Southeast China, with the aim of constraining the petrogenesis of monzonites and to offer new insights into the deep processes of interaction between crustal- and mantle-derived magmas beneath SE China. The Matou pluton comprises quartz monzonite, whereas the Dalai pluton consists of quartz monzodiorite. Zircon U-Pb ages obtained by laser ablation-inductively coupled plasma-mass spectrometry show that both plutons were emplaced at 99-101 Ma. Rocks of both plutons are intermediate to silicic, metaluminous to weakly peraluminous, subalkaline, and K-rich in composition. Samples of the plutons are enriched in large ion lithophile (e.g., Rb, K, and Pb) and light rare earth elements, depleted in high-field strength elements (e.g., Nb, Ta, and Ti), and have small negative or no Eu anomalies. In addition, the rocks have high Mg# values (up to 53.9), high zircon ɛHf(t) values (up to - 1.4), and low Nb/U and Ta/U ratios. Geochemical evidence suggests that both depleted asthenospheric and metasomatically enriched mantle components were involved in the formation of these monzonitic rocks. The presence of inherited zircons with Palaeoproterozoic ages and zircons with unusually low ɛHf(t) values (- 12.9) in the Matou quartz monzonites indicates that ancient crustal materials were also involved in their petrogenesis. In combination with the presence of abundant mafic microgranular enclaves (MMEs) with spheroidal to ellipsoidal-ovoidal shapes and xenocrysts within the more diffused enclaves, and the results of trace element modelling, we suggest that the Matou quartz monzonites were generated by mixing between mantle-derived mafic magmas and crustally derived silicic magmas. The Dalai pluton is relatively homogeneous and contains fewer MMEs than the Matou pluton. Zircons from the Dalai pluton show no inherited components, indicating that

  10. Study of niobium corrosion in alkaline medium

    International Nuclear Information System (INIS)

    Almeida, S.H. de.

    1987-01-01

    A comparative study of niobium electrochemical behaviour in NaOH and KOH solution, with concentrations between 0,5 and 6,1M is presented. The studies were done through electrochemicals assays, consisting in the corrosion potential and anodic and cathodic polarization curves, complemented by loss of mass experiments. The niobium anodic behaviour in alkaline medium is characterized by passivation occurrence, with a stable film formation. The Na oH solution in alkaline medium are more corrosible to niobium than the KOH solution. The loss of mass assays showed that the corrosion velocit is more dependente of hydroxide concentration in KOH medium than the NaOH medium. (C.G.C.) [pt

  11. Hydrolysis of alkaline pretreated banana peel

    Science.gov (United States)

    Fatmawati, A.; Gunawan, K. Y.; Hadiwijaya, F. A.

    2017-11-01

    Banana peel is one of food wastes that are rich in carbohydrate. This shows its potential as fermentation substrate including bio-ethanol. This paper presented banana peel alkaline pretreatment and enzymatic hydrolysis. The pretreatment was intended to prepare banana peel in order to increase hydrolysis performance. The alkaline pretreatment used 10, 20, and 30% w/v NaOH solution and was done at 60, 70 and 80°C for 1 hour. The hydrolysis reaction was conducted using two commercial cellulose enzymes. The reaction time was varied for 3, 5, and 7 days. The best condition for pretreatment process was one conducted using 30% NaOH solution and at 80°C. This condition resulted in cellulose content of 90.27% and acid insoluble lignin content of 2.88%. Seven-day hydrolysis time had exhibited the highest reducing sugar concentration, which was7.2869 g/L.

  12. Oxidation catalysts on alkaline earth supports

    Science.gov (United States)

    Mohajeri, Nahid

    2017-03-21

    An oxidation catalyst includes a support including particles of an alkaline earth salt, and first particles including a palladium compound on the support. The oxidation catalyst can also include precious metal group (PMG) metal particles in addition to the first particles intermixed together on the support. A gas permeable polymer that provides a continuous phase can completely encapsulate the particles and the support. The oxidation catalyst may be used as a gas sensor, where the first particles are chemochromic particles.

  13. Statistical analysis of the geological-hydrological conditions within part of the Eye-Dashwa pluton, Atikokan, northwestern Ontario

    International Nuclear Information System (INIS)

    Brown, P.A.; Rey, N.A.C.

    1989-01-01

    The occurrence and distribution of fracture-filling material within the Eye-Dashwa granite indicate that the dominant fracture system formed shortly after emplacement and cooling of the pluton at 2678 ± 67 Ma. Subsequent reactivation of these ancient fractures was accompanied by sequentially younger and lower temperature filling materials. These reopened ancient fractures are best developed in the upper 300-400 m of the rock mass and are commonly conduits for present-day groundwater flow. Multiple linear regression analysis performed on the geological variables identified a highly significant correlation between a number of these variable and hydraulic conductivity values measured in 25 m test sections of the boreholes. The predictive capability of the regression design was tested with seven new test data and found to be a valid estimator of the hydrogeological conditions

  14. Multistage magma emplacement and progressive strain accumulation in the shallow-level Krkonoše-Jizera plutonic complex, Bohemian Massif

    Science.gov (United States)

    Žák, Jiří; Verner, Kryštof; Sláma, Jiří; Kachlík, Václav; Chlupáčová, Marta

    2013-09-01

    relationships combined with new U-Pb zircon geochronology suggest that the shallow-level Krkonoše-Jizera plutonic complex, northern Bohemian Massif, was assembled successively from bottom to top, starting with emplacement of the separately evolved S-type Tanvald granite (317.3 ± 2.1 Ma), followed by at least two voluminous batches of the I-type porphyritic Liberec (319.5 ± 2.3 Ma) and Jizera (320.1 ± 3.0 Ma and 319.3 ± 3.7 Ma) granites. The intrusive sequence was completed by uppermost, minor intrusions of the equigranular Harrachov (315.0 ± 2.7 Ma) and Krkonoše granites. The I-type granites exhibit an unusually complex pattern of superposed feldspar phenocryst and magnetic fabrics as revealed from the anisotropy of magnetic susceptibility (AMS). The outer Liberec granite preserves margin-parallel foliations and lineations, interpreted to record emplacement-related strain captured by cooling from the pluton floor and walls. In contrast, the inner Jizera, Harrachov, and Krkonoše granites were overprinted by synmagmatic strain resulting from dextral movements along regional strike-slip faults cutting the opposite ends of the plutonic complex. Late-stage felsic dikes in the Liberec and Jizera granites reorient from horizontal to vertical (lineation-perpendicular) attitude in response to changing the least principal stress direction, whereas mafic schlieren do not do so, representing only randomly oriented small-scale thermal-mechanical instabilities in the phenocryst framework. In general, this case example challenges the common approach of inferring pluton-wide magma flow from interpolated foliation, lineation, and schlieren patterns. More likely, magmatic fabrics in large plutons record complex temporal succession of superposed strains resulting from diverse processes at multiple scales.

  15. Heavy water production by alkaline water electrolysis

    International Nuclear Information System (INIS)

    Kamath, Sachin; Sandeep, K.C.; Bhanja, Kalyan; Mohan, Sadhana; Sugilal, G.

    2014-01-01

    Several heavy water isotope production processes are reported in literature. Water electrolysis in combination with catalytic exchange CECE process is considered as a futuristic process to increase the throughput and reduce the cryogenic distillation load but the application is limited due to the high cost of electricity. Any improvement in the efficiency of electrolyzers would make this process more attractive. The efficiency of alkaline water electrolysis is governed by various phenomena such as activation polarization, ohmic polarization and concentration polarization in the cell. A systematic study on the effect of these factors can lead to methods for improving the efficiency of the electrolyzer. A bipolar and compact type arrangement of the alkaline water electrolyzer leads to increased efficiency and reduced inventory in comparison to uni-polar tank type electrolyzers. The bipolar type arrangement is formed when a number of single cells are stacked together. Although a few experimental studies have been reported in the open literature, CFD simulation of a bipolar compact alkaline water electrolyzer with porous electrodes is not readily available.The principal aim of this study is to simulate the characteristics of a single cell compact electrolyzer unit. The simulation can be used to predict the Voltage-Current Density (V-I) characteristics, which is a measure of the efficiency of the process.The model equations were solved using COMSOL multi-physics software. The simulated V-I characteristic is compared with the experimental data

  16. Morphological and ecological variation of Gremmeniella abietina var. abietina in Pinus sylvestris, Pinus contorta and Picea abies sapling stands in northern Finland and the Kola Peninsula

    Energy Technology Data Exchange (ETDEWEB)

    Kaitera, Juha; Seitamaeki, Leena; Jalkanen, Risto [Finnish Forest Research Inst., Rovaniemi (Finland). Rovaniemi Research Station

    2000-07-01

    The morphological and ecological variation of two types of Gremmeniella abietina var. abietina causing scleroderris canker on conifers was investigated in Pinus spp. and Picea sp. sapling stands in northern Finland and the Kola Peninsula. Small-tree type (STT or B type) of G. abietina was detected alone in 13 Scots pine, three lodgepole pine and two Norway spruce sapling stands out of 26 stands investigated, both STT and large-tree type (LTT or A type) were observed in six Scots pine stands, and LTT was detected alone in two Scots pine stands. For the first time, G. abietina was found to injure Norway spruce saplings in a respective plantation in northern Fennoscandia. STT isolates produced statistically significantly more conidia in vitro than LTT isolates. Morphological variation in conidia septation revealed that STT produced conidia with more than five septa more frequently than did LTT. There was a greater range in variation in septation in STT than in LTT, with overlapping between the types. Isolates of both types were equally associated with cankers, coloured wood, pycnidia or apothecia in the infected saplings.

  17. Generation of post-collisional normal calc-alkaline and adakitic granites in the Tongbai orogen, central China

    Science.gov (United States)

    Zhang, Wen-Xiang; Zhu, Liu-Qin; Wang, Hao; Wu, Yuan-Bao

    2018-01-01

    Post-collisional granites are generally generated by partial melting of continental crust during orogenic extension. The occurrence of normal calc-alkaline granites following adakitic granites in a collisional orogen is frequently supposed as a sign of tectonic regime transition from compression to extension, which has been debated yet. In this paper, we present a comprehensive study of zircon U-Pb ages, Hf-O isotopes, as well as whole-rock major and trace elements and Sr-Nd isotopes, for Tongbai and Jigongshan post-collisional granitic plutons in the Tongbai orogen. Zircon U-Pb dating yields intrusion ages of ca. 140 and 135 Ma for the Tongbai and Jigongshan plutons, respectively, suggesting they are post-collisional granites. These granites are high-K calc-alkaline series, metaluminous to weakly peraluminous with A/CNK ratios of 0.85-1.08. The Tongbai gneissic granites are normal calc-alkaline granite, having variable SiO2 (61.93-76.74 wt%) and Sr/Y (2.9-38.9) and (La/Yb)N (1.7-30.1) ratios with variably negative Eu anomalies (0.41-0.92). They have relatively high initial Sr isotope ratios of 0.707571 to 0.710317, and low εNd(t) (- 15.74 to - 11.09) and εHf(t) (- 17.6 to - 16.9) values. Their Nd and Hf model ages range from 2.2 to 1.8 Ga and 2.3 to 2.2 Ga. On the contrary, the Jigongshan granites show higher SiO2 (66.56-72.11 wt%) and Sr/Y (30.1-182.0) and (La/Yb)N (27.4-91.4) ratios with insignificant Eu anomalies (0.73-1.00), belonging to adakitic granite. They have Isr = 0.707843-0.708366, εNd(t) = - 19.83 to - 17.59, and εHf(t) = - 26.0 to - 23.5. Their Nd and Hf model ages vary from ca. 2.5 to 2.4 Ga and ca. 2.8 to 2.6 Ga. The Tongbai and Jigongshan granites are characterized by mantle-like zircon δ18O values (5.17-5.46‰). These geochemical features suggest that the Tongbai and Jigongshan granites were derived from partial melting of Paleoproterozoic and Archean continental crust, respectively. Fractional crystallization affected the geochemical

  18. Tyramine functions as a toxin in honey bee larvae during Varroa-transmitted infection by Melissococcus pluton.

    Science.gov (United States)

    Kanbar, G; Engels, W; Nicholson, G J; Hertle, R; Winkelmann, G

    2004-05-01

    From wounds of honey bee pupae, caused by the mite Varroa destructor, coccoid bacteria were isolated and identified as Melissococcus pluton. The bacterial isolate was grown anaerobically in sorbitol medium to produce a toxic compound that was purified on XAD columns, gelfiltration and preparative HPLC. The toxic agent was identified by GC-MS and FTICR-MS as tyramine. The toxicity of the isolated tyramine was tested by a novel mobility test using the protozoon Stylonychia lemnae. A concentration of 0.2 mg/ml led to immediate inhibition of mobility. In addition the toxicity was studied on honey bee larvae by feeding tyramine/water mixtures added to the larval jelly. The lethal dosis of tyramine on 4-5 days old bee larvae was determined as 0.3 mg/larvae when added as a volume of 20 microl to the larval food in brood cells. Several other biogenic amines, such as phenylethylamine, histamine, spermine, cadaverine, putrescine and trimethylamine, were tested as their hydrochloric salts for comparison and were found to be inhibitory in the Stylonychia mobility test at similar concentrations. A quantitative hemolysis test with human red blood cells revealed that tyramine and histamine showed the highest membranolytic activity, followed by the phenylethylamine, trimethylamine and spermine, while the linear diamines, cadaverine and putrescine, showed a significantly lower hemolysis when calculated on a molar amine basis. The results indicate that tyramine which is a characteristic amine produced by M. pluton in culture, is the causative agent of the observed toxic symptoms in bee larvae. Thus this disease, known as European foulbrood, is possibly an infection transmitted by the Varroa destructor mite.

  19. Incremental growth of an upper crustal, A-type pluton, Argentina: Evidence of a re-used magma pathway

    Science.gov (United States)

    Alasino, Pablo H.; Larrovere, Mariano A.; Rocher, Sebastián; Dahlquist, Juan A.; Basei, Miguel A. S.; Memeti, Valbone; Paterson, Scott; Galindo, Carmen; Macchioli Grande, Marcos; da Costa Campos Neto, Mario

    2017-07-01

    Carboniferous igneous activity in the Sierra de Velasco (NW Argentina) led to the emplacement of several magmas bodies at shallow levels (relationships) intrusive units are: (1) the Asha unit (340 ± 7 Ma): a tabular to funnel-shaped intrusion emplaced during a regional strain field dominated by WSW-ENE shortening with contacts discordant to regional host-rock structures; (2) the San Blas unit (344 ± 2 Ma): an approximate cylindrical-shaped intrusion formed by multiple batches of magmas, with a roughly concentric fabric pattern and displacement of the host rock by ductile flow of about 35% of shortening; and (3) the Hualco unit (346 ± 6 Ma): a small body with a possible mushroom geometry and contacts concordant to regional host-rock structures. The magma pulses making up these units define two groups of A-type granitoids. The first group includes the peraluminous granitic rocks of the Asha unit generated mostly by crustal sources (εNdt = - 5.8 and εHft in zircon = - 2.9 to - 4.5). The second group comprises the metaluminous to peraluminous granitic rocks of the youngest units (San Blas and Hualco), which were formed by a heterogeneous mixture between mantle and crustal sources (εNdt = + 0.6 to - 4.8 and εHft in zircon = + 3 to - 6). Our results provide a comprehensive view of the evolution of an intrusive complex formed from multiple non-consanguineous magma intrusions that utilized the same magmatic plumbing system during downward transfer of host materials. As the plutonic system matures, the ascent of magmas is governed by the visco-elastic flow of host rock that for younger batches include older hot magma mush. The latter results in ductile downward flow of older, during rise of younger magma. Such complexes may reflect the plutonic portion of volcanic centers where chemically distinct magmas are erupted.

  20. Processing Methods of Alkaline Hydrolysate from Rice Husk

    Directory of Open Access Journals (Sweden)

    Olga D. Arefieva

    2017-07-01

    Full Text Available This paper devoted to finding processing methods of alkaline hydrolysate produced from rice husk pre-extraction, and discusses alkaline hydrolysate processing schemed and disengagement of some products: amorphous silica of various quality, alkaline lignin, and water and alkaline extraction polysaccharides. Silica samples were characterized: crude (air-dried, burnt (no preliminary water treatment, washed in distilled water, and washed in distilled water and burnt. Waste water parameters upon the extraction of solids from alkaline hydrolysate dropped a few dozens or thousand times depending on the applied processing method. Color decreased a few thousand times, turbidity was virtually eliminated, chemical oxygen demanded about 20–136 times; polyphenols content might decrease 50% or be virtually eliminated. The most prospective scheme obtained the two following solid products from rice husk alkaline hydrolysate: amorphous silica and alkaline extraction polysaccharide. Chemical oxygen demand of the remaining waste water decreased about 140 times compared to the silica-free solution.

  1. Alkaline solution/binder ratio as a determining factor in the alkaline activation of aluminosilicates

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz-Santaquiteria, C., E-mail: ruiz.cs@ietcc.csic.es [Eduardo Torroja Institute (CSIC), c/Serrano Galvache, n Degree-Sign 4, 28033 Madrid (Spain); Skibsted, J. [Instrument Centre for Solid-State NMR Spectroscopy, Interdisciplinary Nanoscience Center (iNANO), Department of Chemistry, Aarhus University, DK-8000 Aarhus C (Denmark); Fernandez-Jimenez, A.; Palomo, A. [Eduardo Torroja Institute (CSIC), c/Serrano Galvache, n Degree-Sign 4, 28033 Madrid (Spain)

    2012-09-15

    This study investigates the effect of the alkaline solution/binder (S/B) ratio on the composition and nanostructure of the reaction products generated in the alkaline activation of aluminosilicates. The experiments used two mixtures of fly ash and dehydroxylated white clay and for each of these, varying proportions of the solution components. The alkali activator was an 8 M NaOH solution (with and without sodium silicate) used at three S/B ratios: 0.50, 0.75 and 1.25. The {sup 29}Si, {sup 27}Al MAS NMR and XRD characterisation of the reaction products reveal that for ratios nearest the value delivering suitable paste workability, the reaction-product composition and structure depend primarily on the nature and composition of the starting materials and the alkaline activator used. However, when an excess alkaline activator is present in the system, the reaction products tend to exhibit SiO{sub 2}/Al{sub 2}O{sub 3} ratios of approximately 1, irrespective of the composition of the starting binder or the alkaline activator.

  2. Temperature Dependence of Mineral Solubility in Water. Part 2. Alkaline and Alkaline Earth Bromides

    Science.gov (United States)

    Krumgalz, B. S.

    2018-03-01

    Databases of alkaline and alkaline earth bromide solubilities in water at various temperatures were created using experimental data from publications over about the last two centuries. Statistical critical evaluation of the created databases was produced since there were enough independent data sources to justify such evaluation. The reliable experimental data were adequately described by polynomial expressions over various temperature ranges. Using the Pitzer approach for ionic activity and osmotic coefficients, the thermodynamic solubility products for the discussed bromide minerals have been calculated at various temperature intervals and also represented by polynomial expressions.

  3. Net alkalinity and net acidity 2: Practical considerations

    Science.gov (United States)

    Kirby, C.S.; Cravotta, C.A.

    2005-01-01

    The pH, alkalinity, and acidity of mine drainage and associated waters can be misinterpreted because of the chemical instability of samples and possible misunderstandings of standard analytical method results. Synthetic and field samples of mine drainage having various initial pH values and concentrations of dissolved metals and alkalinity were titrated by several methods, and the results were compared to alkalinity and acidity calculated based on dissolved solutes. The pH, alkalinity, and acidity were compared between fresh, unoxidized and aged, oxidized samples. Data for Pennsylvania coal mine drainage indicates that the pH of fresh samples was predominantly acidic (pH 2.5-4) or near neutral (pH 6-7); ??? 25% of the samples had pH values between 5 and 6. Following oxidation, no samples had pH values between 5 and 6. The Standard Method Alkalinity titration is constrained to yield values >0. Most calculated and measured alkalinities for samples with positive alkalinities were in close agreement. However, for low-pH samples, the calculated alkalinity can be negative due to negative contributions by dissolved metals that may oxidize and hydrolyze. The Standard Method hot peroxide treatment titration for acidity determination (Hot Acidity) accurately indicates the potential for pH to decrease to acidic values after complete degassing of CO2 and oxidation of Fe and Mn, and it indicates either the excess alkalinity or that required for neutralization of the sample. The Hot Acidity directly measures net acidity (= -net alkalinity). Samples that had near-neutral pH after oxidation had negative Hot Acidity; samples that had pH mine drainage treatment can lead to systems with insufficient Alkalinity to neutralize metal and H+ acidity and is not recommended. The use of net alkalinity = -Hot Acidity titration is recommended for the planning of mine drainage treatment. The use of net alkalinity = (Alkalinitymeasured - Aciditycalculated) is recommended with some cautions

  4. Magmatic evolution of the Jbel Boho alkaline complex in the Bou Azzer inlier (Anti-Atlas/Morocco) and its relation to REE mineralization

    Science.gov (United States)

    Benaouda, Rachid; Holzheid, Astrid; Schenk, Volker; Badra, Lakhlifi; Ennaciri, Aomar

    2017-05-01

    The Jbel Boho complex (Anti-Atlas/Morocco) is an alkaline magmatic complex that was formed during the Precambrian-Cambrian transition, contemporaneous with the lower early Cambrian dolomite sequence. The complex consists of a volcanic sequence comprising basanites, trachyandesites, trachytes and rhyolites that is intruded by a syenitic pluton. Both the volcanic suite and the pluton are cut by later microsyenitic and rhyolitic dykes. Although all Jbel Boho magmas were probably ultimately derived from the same, intraplate or plume-like source, new geochemical evidence supports the concept of a minimum three principal magma generations having formed the complex. Whereas all volcanic rocks (first generation) are LREE enriched and appear to be formed by fractional crystallization of a mantle-derived magma, resulting in strong negative Eu anomalies in the more evolved rocks associated with low Zr/Hf and Nb/Ta values, the younger syenitic pluton displays almost no negative Eu anomaly and very high Zr/Hf and Nb/Ta. The syenite is considered to be formed by a second generation of melt and likely formed through partial melting of underplated mafic rocks. The syenitic pluton consists of two types of syenitic rocks; olivine syenite and quartz syenite. The presence of quartz and a strong positive Pb anomaly in the quartz syenite contrasts strongly with the negative Pb anomaly in the olivine syenite and suggests the latter results from crustal contamination of the former. The late dyke swarm (third generation of melt) comprises microsyenitic and subalkaline rhyolitic compositions. The strong decrease of the alkali elements, Zr/Hf and Nb/Ta and the high SiO2 contents in the rhyolitic dykes might be the result of mineral fractionation and addition of mineralizing fluids, allowing inter-element fractionation of even highly incompatible HFSE due to the presence of fluorine. The occurrence of fluorite in some volcanic rocks and the Ca-REE-F carbonate mineral synchysite in the dykes

  5. Growing season changes in Fennoscandia and Kola peninsula during the period 1982 to 1999 - Implications for reindeer husbandry (In Norwegian with Summary in English

    Directory of Open Access Journals (Sweden)

    Hans Tømmervik

    2005-04-01

    Full Text Available Climate change and particularly variations in air temperature have significant impacts on the growth rhythm of plants where these occur at the limits of their natural distribution range, especially at northern latitudes. Our study area, Fennoscandia and Kola Peninsula, is characterized by large regional climatic differences from south to north, from west to east, and from lowland to mountains. Accordingly, the region is well suited for looking for evidence of climatic change and studying regional differences in the response of such change. The International Panel on Climate Change (IPCC reports that the projected warming in northern Europe is greater than for many other regions of the world. Therefore major physical and ecological changes are expected. On land, there will be a tendency for shifts in major biomes such as tundra and boreal forest. Permafrost will decline, trees and shrubs will encroach northern tundra, and broad-leaved trees may encroach coniferous forests. Net primary productivity in ecosystems is likely to increase. The temperature level at the end of the 20th century is ca. 0.5 oC higher than in the 1930 for the Northern hemisphere (IPCC and World Meteorological Organization. Other studies show that in the period 1890-1999, the increase in temperature over Fennoscandia varies between 0.02 (Karasjok and 0.1 oC decade-1 (Helsinki, and they also showed that at several stations within the area the spring temperatures have increased steadily throughout the 20th century. Most stations experienced low spring temperatures in the beginning of the century, and rather high temperatures around 1950. At present, the winter temperature levels are considerably higher than in the rest of the period. However, at northern stations the winter temperatures were higher in the 1930s than at present. Phenological registrations have been used word-wide to look for possible effects of climate change, but within Fennoscandia the problem is that

  6. RES Hydrogen: efficient pressurised alkaline electrolysers

    DEFF Research Database (Denmark)

    Bowen, Jacob R.; Bentzen, Janet Jonna; Jørgensen, Peter Stanley

    The RESelyser project addresses issues associated with coupling alkaline electrolysis to renewable energy sources such as electrode stability and gas purity by implementing improved electrodes and a new separator membrane concept. The project aims to improve performance, operation pressure...... and reduce system cost. The project supports DTU Energy's activities on electrodes within the larger FCH-JU project. The overall project demonstrated: improved electrode efficiency also during cyclic operation, safe gas purity at a system pressure of 30 bar, 10 kW stack operation and estimated system costs...

  7. Alkaline carbonates in blast furnace process

    Directory of Open Access Journals (Sweden)

    P. Besta

    2014-10-01

    Full Text Available The production of iron in blast furnaces is a complex of physical, chemical and mechanical processes. The input raw materials contain not only metallic components, but also a number of negative elements. The most important negative elements include alkaline carbonates. They can significantly affect the course of the blast furnace process and thus the overall performance of the furnace. As a result of that, it is essential to accurately monitor the alkali content in the blast furnace raw materials. The article analyzes the alkali content in input and output raw materials and their impact on the blast furnace process.

  8. Persistently increased intestinal fraction of alkaline phosphatase

    DEFF Research Database (Denmark)

    Nathan, E; Baatrup, G; Berg, H

    1984-01-01

    Persistent elevation of the intestinal fraction of the alkaline phosphatase (API) as an isolated finding has to our knowledge not been reported previously. It was found in a boy followed during a period of 5.5 years. The only symptom was transient periodic fatigue observed at home, but not apparent...... during hospitalization. His blood type was O, RH+, Le (a-, b+) and he was a secretor of H-substance, which may be associated with rising API activity after fat-loading. In this case API was unchanged after fat-loading. Neither intestinal nor liver diseases were found, and no other cause for the elevated...

  9. Alkaline erosion of CR 39 polymer surfaces

    International Nuclear Information System (INIS)

    Faiman, Laurence

    2009-01-01

    We have investigated the mechanism of erosion of CR 39 polymer in alkaline environments. We observed the kinetics of absorption of water and methanol into both unirradiated and γ-irradiated samples. We use a capillary model to interpret our results. We etched our samples in both KOH solutions, and KOH solutions doped with methanol. Etch rate was desensitizing to γ-irradiation when KOH concentration approached saturation, but KOH solutions doped with methanol were not desensitizing, unlike with nuclear tracks. We account for this difference

  10. Electrochemistry of Some New Alkaline Battery Electrodes

    Science.gov (United States)

    1976-02-01

    1NýT;7 ~~ AFAPI 4TR- 75)aI Electrochemistry of Somwý New Alkaline V CI RG, 0OTNME Dr/ David F., ’Pickett, IM Wayue ’,Hisb’q Mr. R ic ha rd A I Mid...adding ZnO to the electi-olyte (saturated) and usi .j the interc:ell conrec;tor d isr:ussed earlier ,itLh el4cc.roploated zinc ag inst. the silver fo

  11. Alkaline chemistry of transuranium elements and technetium and the treatment of alkaline radioactive wastes

    International Nuclear Information System (INIS)

    Delegard, C.H.; Peretrukhin, V.F.; Shilov, V.P.; Pikaev, A.K.

    1995-05-01

    Goal of this survey is to generalize the known data on fundamental physical-chemical properties of TRUs and Tc, methods for their isolation, and to provide recommendations that will be useful for partitioning them from alkaline high-level wastes

  12. Alkaline chemistry of transuranium elements and technetium and the treatment of alkaline radioactive wastes

    Energy Technology Data Exchange (ETDEWEB)

    Delegard, C.H. [Westinghouse Hanford Co., Richland, WA (United States); Peretrukhin, V.F.; Shilov, V.P.; Pikaev, A.K. [Russian Academy of Sciences (Russian Federation). Inst. of Physical Chemistry

    1995-05-01

    Goal of this survey is to generalize the known data on fundamental physical-chemical properties of TRUs and Tc, methods for their isolation, and to provide recommendations that will be useful for partitioning them from alkaline high-level wastes.

  13. Comparative Analysis of the Number and Structure of the Complexes of Microscopic Fungi in Tundra and Taiga Soils in the North of the Kola Peninsula

    Science.gov (United States)

    Korneikova, M. V.

    2018-01-01

    The number, biomass, length of fungal mycelium, and species diversity of microscopic fungi have been studied in soils of the tundra and taiga zones in the northern part of the Kola Peninsula: Al-Fe-humus podzols (Albic Podzols), podburs (Entic Podzols), dry peaty soils (Folic Histosols), low-moor peat soils (Sapric Histosols), and soils of frost bare spots (Cryosols). The number of cultivated microscopic fungi in tundra soils varied from 8 to 328 thousand CFU/g, their biomass averaged 1.81 ± 0.19 mg/g, and the length of fungal mycelium averaged 245 ± 25 m/g. The number of micromycetes in taiga soils varied from 80 to 350 thousand CFU/g, the number of fungal propagules in some years reached 600 thousand CFU/g; the fungal biomass varied from 0.23 to 6.2 mg/g, and the length of fungal mycelium varied from 32 to 3900 m/g. Overall, 36 species of fungi belonging to 16 genera, 13 families, and 8 orders were isolated from tundra soils. The species diversity of microscopic fungi in taiga soils was significantly higher: 87 species belonging to 31 genera, 21 families, and 11 orders. Fungi from the Penicillium genus predominated in both natural zones and constituted 38-50% of the total number of isolated species. The soils of tundra and taiga zones were characterized by their own complexes of micromycetes; the similarity of their species composition was about 40%. In soils of the tundra zone, Mortierella longicollis, Penicillium melinii, P. raistrickii, and P. simplicissimum predominated; dominant fungal species in soils of the taiga zone were represented by M. longicollis, P. decumbens, P. implicatum, and Umbelopsis isabellina.

  14. Application of IBA to determine the effects of Kolaviron (Garcinia kola) on the elemental metabolism in the rat liver and kidney

    Energy Technology Data Exchange (ETDEWEB)

    Mars, J.A.; Kunsevi-Kilola, C.; Gihwala, D. [Department of Biomedical Sciences, Cape Peninsula University of Technology, PO Box 1906, Bellville, 7535 (South Africa)

    2013-07-01

    Full text: Poor or no antioxidant activity has been implicated in the aetiology of various pathologies. Since antioxidants are mostly derived from natural resources, the search for medicinal plants, that can either cure or alleviate ailments, has been phenomenal over the past decades. One plant, Garcinia kola, the oil of which is termed kolaviron, has been identified to have possible antioxidant activity [1]. Trace elements such as Fe, Mn, Cu, Zn and Se, form an integral part in antioxidant activity, especially in organ metabolism. In this study organ (Iiver and kidney) metabolism of major such as C, O, N, S, and trace elements is investigated. The kolaviron was dissolved in corn oil. Two groups (control and experimental) of Wistar rats were selected. The animals were housed in accordance with the WHO animal regulations. Both groups had ad libitum access to standard rat chow and potable tap water. The control group was fed, by gavage, with 200 microlitre of the solution of kolaviron in com oil once per day for a period of 4 weeks. After this period the animals were sacrificed by intraperitoneal injection of pentobarbitone. The organs were excised and homogenised into smaller parts which were freeze-dried - 80 deg C. The freeze-dried organ was then pulverized and press into a palette. Concentrations of trace elements were determined with proton induced X-ray emission (PIXE). PIXE was selected since with this technique concentrations down to minimum detection limits (MDLs) of parts per million (ppm) can be determined. A beam of 3 MeV protons was used for bombardment and a Be filter of 125 micrometer thickness for absorption. Backscattering spectrometry (BS) was used to determine the matrix composition. PIXE and BS measurements were determined simultaneously. Scanning electron microscopy was used both as complementary and supplementary to PIXE and BS. Statistical tests of p < 0.5 were considered significant. 1] Ogada and Braide (2009) Nig. J. Physio. Sci., vol. 24

  15. The impact of industrial emissions of copper-nickel smelter complex on the status of populations and communities of small mammals in the Kola Peninsula

    Directory of Open Access Journals (Sweden)

    Gennadiy D. Kataev

    2017-08-01

    Full Text Available The population status of the small mammals, Micromammalia, was studied in the central mountain and taiga part of the Kola Peninsula in the Lapland Biosphere Reserve and its buffer zone. For this purpose, control groups of animals were selected at a different distance from the Severonikel' industrial complex which is considered as the largest metallurgical company in Europe. It produces nickel, copper and other non-ferrous metals. The study sites were located at 4–30 km from the local source of industrial pollution. The analysis of population dynamics, faunistic structure and biological parameters of mass species of Soricidae, Myomorpha has revealed the differences in habitats depending on the distance to the industrial complex. The results of the chemical analysis of organs and tissue samples of small rodents, their morpho-physiological and genetic characteristics within emission plume were analysed. The abundance of the studied Mammalia species was the lowest at 5 km north and 7 km south of the metallurgical industrial complex. According to our results, animals in a zone of increased industrial emission (sulfur dioxide, compounds of heavy metals concentrations had more deviations from the biological norms in comparison with the same species from less polluted areas. Long-term (1936–2014 abundance dynamics of Clethrionomys glareolus was presented due to the new ecological situation in the region and reduction of the volume of sulfur dioxide emission by the Severonikel' industrial complex. This biotesting method using mammals as study objects may be applied for the definition of ecologically safe level criteria of heavy metal production and it may be used in studies of similar ecological situations.

  16. Protective effect of kolaviron, a biflavonoid from Garcinia kola seeds, in brain of Wistar albino rats exposed to gamma-radiation

    International Nuclear Information System (INIS)

    Adaramoye, O.A.

    2010-01-01

    This study was designed to evaluate the protective effect of kolaviron (KV), a biflavonoid from Garcinia kola seeds, against γ-radiation (5 Gy)-induced oxidative stress in brain of Wistar rats. Vitamin C (VC) served as standard antioxidant. Forty-four rats were divided into 4 groups of 11 animals each. One group was un-irradiated (normal), two groups were treated with KV and VC (250 mg/kg) for 6 weeks prior to and 8 weeks after irradiation, and fourth group was only irradiated. Rats were sacrificed 1 and 8 weeks after irradiation. Cellular alterations were monitored using changes in the levels of malondialdehyde (MDA)-an index of lipid peroxidation, superoxide dismutase (SOD), glutathione-S-transferase (GST), reduced glutathione (GSH), catalase (CAT), alanine and aspartate aminotransferases (ALT and AST), urea and creatinine. MDA levels increased significantly (p<0.05) by 90% and 151% after 1 and 8 weeks of irradiation. Furthermore, levels of GSH and antioxidant enzymes were significantly (p<0.05) decreased in γ-irradiated animals. GSH and GST decreased by 61% and 43% after 1 week, and by 75% and 74%, after 8 weeks of exposure, respectively. γ-Irradiation decreased SOD and CAT levels by 53% and 68%, respectively, and caused significant (p<0.05) increases in serum ALT, AST and urea after 8 weeks of exposure. Treatment with KV and VC significantly decreased the levels of MDA, ALT, AST and urea. The antioxidant indices were significantly ameliorated in KV-treated animals. These data suggest that kolaviron may protect against γ-radiation-induced oxidative stress in brain of exposed rats. (author)

  17. Isotherms of ion exchange on titanates of alkaline metals

    International Nuclear Information System (INIS)

    Fillina, L.P.; Belinskaya, F.A.

    1986-01-01

    Present article is devoted to isotherms of ion exchange on titanates of alkaline metals. Therefore, finely dispersed hydrated titanates of alkaline metals (lithium, sodium, potassium) with ion exchange properties are obtained by means of alkaline hydrolysis of titanium chloride at high ph rates. Sorption of cations from salts solution of Li 2 SO 4 , NaNO 3 , Ca(NO 3 ) 2 , AgNO 3 by titanates is studied.

  18. Acid transformation of bauxite residue: Conversion of its alkaline characteristics

    OpenAIRE

    Kong, X.; Li, M.; Xue, S.; Hartley, W.; Chen, C.; Wu, C.; Li, X.; Li, Y.

    2016-01-01

    Bauxite residue (BR) is a highly alkaline solid hazardous waste produced from bauxite processing for alumina production. Alkaline transformation appears to reduce the environmental risk of bauxite residue disposal areas (BRDAs) whilst potentially providing opportunities for the sustainable reuse and on-going management of BR. Mineral acids, a novel citric acid and a hybrid combination of acid-gypsum treatments were investigated for their potential to reduce residue pH and total alkalinity and...

  19. Spectroscopic characterization of alkaline earth uranyl carbonates

    International Nuclear Information System (INIS)

    Amayri, Samer; Reich, Tobias; Arnold, Thuro; Geipel, Gerhard; Bernhard, Gert

    2005-01-01

    A series of alkaline uranyl carbonates, M[UO 2 (CO 3 ) 3 ].nH 2 O (M=Mg 2 , Ca 2 , Sr 2 , Ba 2 , Na 2 Ca, and CaMg) was synthesized and characterized by inductively coupled plasma mass spectrometry (ICP-MS) and atomic absorption spectrometry (AAS) after nitric acid digestion, X-ray powder diffraction (XRD), and thermal analysis (TGA/DTA). The molecular structure of these compounds was characterized by extended X-ray absorption fine-structure (EXAFS) spectroscopy and X-ray photoelectron spectroscopy (XPS). Crystalline Ba 2 [UO 2 (CO 3 ) 3 ].6H 2 O was obtained for the first time. The EXAFS analysis showed that this compound consists of (UO 2 )(CO 3 ) 3 clusters similar to the other alkaline earth uranyl carbonates. The average U-Ba distance is 3.90+/-0.02A.Fluorescence wavelengths and life times were measured using time-resolved laser-induced fluorescence spectroscopy (TRLFS). The U-O bond distances determined by EXAFS, TRLFS, XPS, and Raman spectroscopy agree within the experimental uncertainties. The spectroscopic signatures observed could be useful for identifying uranyl carbonate species adsorbed on mineral surfaces

  20. Activation of Alkaline Irrigation Fluids in Endodontics

    Directory of Open Access Journals (Sweden)

    Laurence J. Walsh

    2017-10-01

    Full Text Available In conventional endodontic treatment, alkaline solutions of sodium hypochlorite (NaOCl and ethylenediaminetetraacetic acid (EDTA are used in combination to disinfect the root canal system and to eliminate debris and smear layers. An important concept that has emerged over recent years is the use of active physical methods for agitating these fluids to improve their penetration within areas that are not reached by endodontic instruments and to accelerate the chemical actions of these alkaline fluids against planktonic microorganisms, biofilms, soft tissue remnants and smear layers. Ultrasonic agitation and more recently pulsed lasers have emerged as two promising methods for activating endodontic irrigation fluids. Ultrasonic agitation with piezoelectric devices employs a moving tip, while laser agitation uses a stationary tip. Both methods cause cavitation, followed by implosions and shear forces which assist with debridement. Fluid streaming further enhances the activity of the fluids. While agitation enhances performance of irrigants, extrusion of fluids from the root canal during activation is a hazard that must be controlled.

  1. DNA DAMAGE QUANTITATION BY ALKALINE GEL ELECTROPHORESIS.

    Energy Technology Data Exchange (ETDEWEB)

    SUTHERLAND,B.M.; BENNETT,P.V.; SUTHERLAND, J.C.

    2004-03-24

    Physical and chemical agents in the environment, those used in clinical applications, or encountered during recreational exposures to sunlight, induce damages in DNA. Understanding the biological impact of these agents requires quantitation of the levels of such damages in laboratory test systems as well as in field or clinical samples. Alkaline gel electrophoresis provides a sensitive (down to {approx} a few lesions/5Mb), rapid method of direct quantitation of a wide variety of DNA damages in nanogram quantities of non-radioactive DNAs from laboratory, field, or clinical specimens, including higher plants and animals. This method stems from velocity sedimentation studies of DNA populations, and from the simple methods of agarose gel electrophoresis. Our laboratories have developed quantitative agarose gel methods, analytical descriptions of DNA migration during electrophoresis on agarose gels (1-6), and electronic imaging for accurate determinations of DNA mass (7-9). Although all these components improve sensitivity and throughput of large numbers of samples (7,8,10), a simple version using only standard molecular biology equipment allows routine analysis of DNA damages at moderate frequencies. We present here a description of the methods, as well as a brief description of the underlying principles, required for a simplified approach to quantitation of DNA damages by alkaline gel electrophoresis.

  2. Geochemical Relationships between Volcanic and Plutonic Upper to Mid Crustal Exposures of the Rosario Segment, Alisitos Arc (Baja California, Mexico): An Outstanding Field Analog to the Izu-Bonin-Mariana Arc

    Science.gov (United States)

    Morris, R.; DeBari, S. M.; Busby, C. J.; Medynski, S.

    2015-12-01

    Exposed paleo-arcs, such as the Rosario segment of the Cretaceous Alisitos Arc in Baja California, Mexico, provide an opportunity to explore the evolution of arc crust through time. Remarkable 3-D exposures of the Rosario segment record crustal generation processes in the volcanic rocks and underlying plutonic rocks. In this study, we explore the physical and geochemical connection between the plutonic and volcanic sections of the extensional Alisitos Arc, and elucidate differentiation processes responsible for generating them. These results provide an outstanding analog for extensional active arc systems, such as the Izu-Bonin-Mariana (IBM) Arc. Upper crustal volcanic rocks have a coherent stratigraphy that is 3-5 km thick and ranges in composition from basalt to dacite. The most felsic compositions (70.9% SiO2) are from a welded ignimbrite unit. The most mafic compositions (51.5% SiO2, 3.2% MgO) are found in basaltic sill-like units. Phenocrysts in the volcanic units include plagioclase +/- amphibole and clinopyroxene. The transition to deeper plutonic rocks is clearly an intrusive boundary, where plutonic units intrude the volcanic units. Plutonic rocks are dominantly a quartz diorite main phase with a more mafic, gabbroic margin. A transitional zone is observed along the contact between the plutonic and volcanic rocks, where volcanics have coarsely recrystallized textures. Mineral assemblages in the plutonic units include plagioclase +/- quartz, biotite, amphibole, clinopyroxene and orthopyroxene. Most, but not all, samples are low K. REE patterns are relatively flat with limited enrichment. Normalization diagrams show LILE enrichment and HFSE depletion, where trends are similar to average IBM values. We interpret plutonic and volcanic units to have similar geochemical relationships, where liquid lines of descent show the evolution of least to most evolved magma types. We provide a model for the formation and magmatic evolution of the Alisitos Arc.

  3. The link between volcanism and plutonism in epizonal magma systems; high-precision U–Pb zircon geochronology from the Organ Mountains caldera and batholith, New Mexico

    Science.gov (United States)

    Rioux, Matthew; Farmer, Lang; Bowring, Samuel; Wooton, Kathleen M.; Amato, Jeffrey M.; Coleman, Drew S.; Verplanck, Philip L.

    2016-01-01

    The Organ Mountains caldera and batholith expose the volcanic and epizonal plutonic record of an Eocene caldera complex. The caldera and batholith are well exposed, and extensive previous mapping and geochemical analyses have suggested a clear link between the volcanic and plutonic sections, making this an ideal location to study magmatic processes associated with caldera volcanism. Here we present high-precision thermal ionization mass spectrometry U–Pb zircon dates from throughout the caldera and batholith, and use these dates to test and improve existing petrogenetic models. The new dates indicate that Eocene volcanic and plutonic rocks in the Organ Mountains formed from ~44 to 34 Ma. The three largest caldera-related tuff units yielded weighted mean 206Pb/238U dates of 36.441 ± 0.020 Ma (Cueva Tuff), 36.259 ± 0.016 Ma (Achenback Park tuff), and 36.215 ± 0.016 Ma (Squaw Mountain tuff). An alkali feldspar granite, which is chemically similar to the erupted tuffs, yielded a synchronous weighted mean 206Pb/238U date of 36.259 ± 0.021 Ma. Weighted mean 206Pb/238U dates from the larger volume syenitic phase of the underlying Organ Needle pluton range from 36.130 ± 0.031 to 36.071 ± 0.012 Ma, and the youngest sample is 144 ± 20 to 188 ± 20 ka younger than the Squaw Mountain and Achenback Park tuffs, respectively. Younger plutonism in the batholith continued through at least 34.051 ± 0.029 Ma. We propose that the Achenback Park tuff, Squaw Mountain tuff, alkali feldspar granite and Organ Needle pluton formed from a single, long-lived magma chamber/mush zone. Early silicic magmas generated by partial melting of the lower crust rose to form an epizonal magma chamber. Underplating of the resulting mush zone led to partial melting and generation of a high-silica alkali feldspar granite cap, which erupted to form the tuffs. The deeper parts of the chamber underwent continued recharge and crystallization for 144 ± 20 ka after the

  4. PLUTON: Three-group neutronic code for burnup analysis of isotope generation and depletion in highly irradiated LWR fuel rods

    Energy Technology Data Exchange (ETDEWEB)

    Lemehov, Sergei E; Suzuki, Motoe [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2001-08-01

    PLUTON is a three-group neutronic code analyzing, as functions of time and burnup, the change of radial profiles, together with average values, of power density, burnup, concentration of trans-uranium elements, plutonium buildup, depletion of fissile elements, and fission product generation in water reactor fuel rod with standard UO{sub 2}, UO{sub 2}-Gd{sub 2}O{sub 3}, inhomogeneous MOX, and UO{sub 2}-ThO{sub 2}. The PLUTON code, which has been designed to be run on Windows PC, has adopted a theoretical shape function of neutron attenuation in pellet, which enables users to perform a very fast and accurate calculation easily. The present code includes the irradiation conditions of the Halden Reactor which gives verification data for the code. The total list of trans-uranium elements included in the calculations consists of {sub 92}U{sup 233-239}, {sub 93}Np{sup 237-239}, {sub 94}Pu{sup 238-243}, {sub 95}Am{sup 241-244} (including isomers), and {sub 96}Cm{sup 242-245}. Poisoning fission products are represented by {sub 54}Xe{sup 131,133,135}, {sub 48}Cd{sup 113}, {sub 62}Sm{sup 149,151,152}, {sub 64}Gd{sup 154-160}, {sub 63}Eu{sup 153,155}, {sub 36}Kr{sup 83,85}, {sub 42}Mo{sup 95}, {sub 43}Tc{sup 99}, {sub 45}Rh{sup 103}, {sub 47}Ag{sup 109}, {sub 53}I{sup 127,129,131}, {sub 55}Cs{sup 133}, {sub 57}La{sup 139}, {sub 59}Pr{sup 141}, {sub 60}Nd{sup 143-150}, {sub 61}Pm{sup 147}. Fission gases and volatiles included in the code are {sub 36}Kr{sup 83-86}, {sub 54}Xe{sup 129-136}, {sub 52}Te{sup 125-130}, {sub 53}I{sup 127-131}, {sub 55}Cs{sup 133-137}, and {sub 56}Ba{sup 135-140}. Verification has been performed up to 83 GWd/tU, and a satisfactory agreement has been obtained. (author)

  5. Aeolus or Pluton?; Eole ou pluton?

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    2003-07-01

    In the next years the french government will have to take great decisions in matter of energy and specifically electric power. This report aims to give an estimation of wind power channel in France supposing financial possibilities equivalent to those implemented for the EPR (European Pressurized Reactor) channel. After a presentation of the electric power industry in France, the two channels are compared. (A.L.B.)

  6. Multiple magmatic pulses of the Eastern Volcano-Plutonic Complex, Krušné hory/ Erzgebirge batholith, and their phosphorus contents

    Czech Academy of Sciences Publication Activity Database

    Štemprok, M.; Holub, F. V.; Novák, Jiří Karel

    2003-01-01

    Roč. 78, č. 3 (2003), s. 277-296 ISSN 1214-1119 R&D Projects: GA ČR GA205/95/0149 Grant - others:GA UK(CZ) 165/1998 Institutional research plan: CEZ:AV0Z3013912 Keywords : volcano-plutonic complex * phosphorus * Krušné hory Mts. batholith Subject RIV: DB - Geology ; Mineralogy http://www.geology.cz/bulletin/contents/2003/vol78no3/bulgeosci200303277.pdf

  7. Sm-Nd, Rb-Sr and K-Ar age constraints of the El Molle and Barroso plutons, western Sierra de San Luis, Argentina

    International Nuclear Information System (INIS)

    Sato, A.M.; Gonzalez, P.D; Petronilho, L.A; Llambias, E.J.; Varela, R; Basei, M.A.S

    2001-01-01

    Within the Early Paleozoic Famatinian orogeny of Southern Sierras Pampeanas (Sierra de San Luis and Sierra de Cordoba), the post-orogenic granitoids are characterized by circular intrusions. The published Rb-Sr and K-Ar ages from plutons in the Sierra de San Luis range between 408 and 320 Ma (see synthesis in Llambias et al., 1998). The El Molle and Barroso plutons (Sims et al., 1997; Gonzalez and Sato, 2000) are the two main exposures of a post-orogenic intrusive complex located in the western area of the Sierra de San Luis basement. They also exhibit an overall circular map view of almost 8 km in diameter, and are emplaced in a metamorphic complex developed through pre-Famatinian (Proterozoic? to Early Paleozoic) to Famatinian (Early Paleozoic) orogenies (Gonzalez and Llambias, 1998; von Gosen and Prozzi, 1998). We are carrying out isotopic datings of the El Molle and Barroso plutons in order to contribute to the understanding of the magmatic and metamorphic evolution of the final stages of the Famatinian orogenic cycle in the Sierra de San Luis. The first results of the Sm-Nd, Rb-Sr and K-Ar dates are here presented (au)

  8. Neutron activation and other analytical data for plutonic rocks from North America and Africa. National Uranium Resource Evaluation

    International Nuclear Information System (INIS)

    Price, V.; Fay, W.M.; Cook, J.R.

    1982-09-01

    The objective of this report is to retrieve the elements of an analytical study of granites and associated other plutonic rocks which was begun as a part of the U.S. Department of Energy's National Uranium Resource Evaluation (NURE) program. A discussion of the Savannah River Laboratory (SRL) neutron activation analysis system is given so that a user will understand the linmitations of the data. Enough information is given so that an experienced geochemist can clean up the data set to the extent required by any project. The data are generally good as they are presented. It is intended that the data be read from a magnetic tape written to accompany this report. Microfiche tables of the data follow the text. These tables were prepared from data on the tape, and programs which will read the tape are presented in the section THE DATA TAPE. It is our intent to write a later paper which will include a thoroughly scrubbed data set and a technical discussion of results of the study. 1 figure

  9. Late Variscan, Permo-Carboniferous, Al-K plutonism in the South Portuguese Zone: El Crispinejo cordierite-bearing granite

    Energy Technology Data Exchange (ETDEWEB)

    Díez Montes, A.; Valverde-Vaquero, P.; Rey-Moral, C.; Sánchez García, L.

    2017-07-01

    The El Crispinejo granite forms part of a small, but distinctive late intrusive suite of cordierite-bearing peraluminous granites in the South Portuguese Zone (SPZ). This granite has the best outcrop relationships of the suite. It cross-cuts different members of the Sierra Norte Batholith of the SPZ and the Carboniferous Volcano-Sedimentary Complex of the Iberian Pyrite Belt, producing contact metamorphism. This late pluton has a high K content which results in a contrasting geophysical response (K-Th-U) with respect to the surrounding trondhjemitic granitoids of the TTG suite of the Sierra Norte Batholith. A concordant monazite-zircon U-Pb ID-TIMS age of 300.5 +0.5/-1.5Ma demonstrates Permo-Carboniferous age for this late Variscan magmatic event. The granite is associated with a series of ore showings (F-Pb-Zn and Sn-W) which are completely different from the nearby, massive sulphide and manganese ore deposits of the Iberian Pyrite Belt, indicating the unique character of this intrusion.

  10. The impact of geology on the migration of fluorides in mineral waters of the Bukulja and Brajkovac pluton area, Serbia

    Directory of Open Access Journals (Sweden)

    Papić Petar

    2012-01-01

    Full Text Available One of the hydrogeochemical parameters that classify groundwater as mineral water is the content of fluoride ions. Their concentration is both important and limited for bottled mineral waters. Hydrochemical research of mineral waters in the surrounding area of Bukulja and Brajkovac pluton, in central Serbia, was conducted in order to define the chemical composition and genesis of these waters. They are carbonated waters, with content of fluoride ranging from 0.2 up to 6.6 mg/L. Since hydrochemical analyses showed variations in the major water chemistry, it was obvious that, apart from hydrochemical research, some explorations of the structure of the regional terrain would be inevitable. For these purposes, some additional geological research was performed, creating an adequate basis for the interpretation of the genesis of these carbonated mineral waters. The results confirmed the significance of the application of hydrochemical methods in the research of mineral waters. The work tended to emphasize that “technological treatment” for decreasing the concentration of fluoride in mineral waters occurs in nature, indicating the existence of natural defluoridization. [Projekat Ministarstva nauke Republike Srbije, br. 43004

  11. Rock deformation in hydrothermal systems: the nature of fractures in plutons and their host rocks. Technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    Norton, D.

    1981-11-01

    The purpose of this program is to accumulate the types of field data which are important for the analysis of magma-hydrothermal systems. The structural effects of thermal processes were identified in order to distinguish the thermally induced deformations from the deformations that occurred subsequent to complete cooling of the system. Mapping techniques were developed to record the structural data on the ground from local domains characteristic of larger areas in the magma chamber, and in the air from low-angle oblique aerial photography of the entire region. The ground system is complete and preliminary testing is currently being carried out to verify the method. The results indicate that granitic crystalline rocks have no structural resistance to thermal perturbations. If nuclear wastes are to be stored in granite, precautionary buffers would have to be incorporated into the system. A total of 30 fossil magma chambers have been studied over the past 2 years. An extensive set of fracture imagery has been collected, together with information related to the geological history of the plutons. Fossil magma chambers in Arizona, Utah, California, Washington, Montana, and British Columbia have been studied.

  12. Hydrogen production by alkaline water electrolysis

    Directory of Open Access Journals (Sweden)

    Diogo M. F. Santos

    2013-01-01

    Full Text Available Water electrolysis is one of the simplest methods used for hydrogen production. It has the advantage of being able to produce hydrogen using only renewable energy. To expand the use of water electrolysis, it is mandatory to reduce energy consumption, cost, and maintenance of current electrolyzers, and, on the other hand, to increase their efficiency, durability, and safety. In this study, modern technologies for hydrogen production by water electrolysis have been investigated. In this article, the electrochemical fundamentals of alkaline water electrolysis are explained and the main process constraints (e.g., electrical, reaction, and transport are analyzed. The historical background of water electrolysis is described, different technologies are compared, and main research needs for the development of water electrolysis technologies are discussed.

  13. Alkaline lixiviation of uranium in granitic pegmatite

    International Nuclear Information System (INIS)

    Jambor, S.

    1980-06-01

    The work described herein concerns the determination of the experimental optimum conditions for the alkaline lixiviation of uranium based on the following parameters: time, pH, temperature, density and grane size. The samples were obtained from the Supamo complex, near the Currupia river in the Piar District of the Bolivar State in Venezuela. They have a granitic composition and graphitic texture. The uranium was found in them as a secondary oxidized mineral of green-yellow colour localized in fractures fissures, intergranular spaces and also in the mica as. Secondary uranitite. The lixiviation process was carried out using Na 2 CO 3 /NaHCO 3 buffer solution and for 100 gr. samples the best values for an efficient process were found by using 170 mesh grane size and 500 ml of pH buffer at 70 0 C for a 24 hour time period. (author)

  14. Ethylenediaminetetraacetates of neodymium and alkaline earth metals

    International Nuclear Information System (INIS)

    Barinov, A.V.; Pechurova, L.I.; Martynenko, K.I.; Popov, K.I.; Spitsyn, V.I.

    1977-01-01

    The possibilities have been studied of the formation of polynuclear complexonates of alkaline-earth metals (Ca, Sr, and Ba) based on neodymium derivatives EDTA of the composition NdA - . By pH-metry, electron spectroscopy, and derivatography it has been shown that the structure of complexes M 2 (NdA) 2 (where M- Ca, Sr, or Ba; A- EDTA) in the solution is not polynuclear. Hydroxopolynuclear complexes do not form under conditions studied. The data obtained agree with an assumption about polynuclear structure of the solid complex Ca(NdA) 2 x17 H 2 O and gradual weakening of the polynuclear nature upon substitution of Ca 2+ with Sr 2+ and Ba 2+

  15. Corrosion of copper in alkaline chloride environments

    International Nuclear Information System (INIS)

    King, F.

    2002-08-01

    The available literature information on the corrosion and electrochemical behaviour of copper in alkaline environments has been reviewed. The purpose of the review was to assess the impact of an alkaline plume from cementitious material on the corrosion behaviour of a copper canister in an SKB-3 type repository. The effect of the evolution of the environmental conditions within the repository have been considered, including the effects of temperature, redox conditions, pore-water salinity and pH. If the pore-water pH increases prior to the establishment of anoxic conditions, the canister surface will passivate as the pore-water pH exceeds a value of ∼ pH 9. Passivation will result from the formation of a duplex Cu 2 O/Cu(OH) 2 film. The corrosion potential will be determined by the equilibrium potential for the Cu 2 O/Cu(OH) 2 couple under oxic conditions, or by the Cu/Cu 2 O redox couple under anoxic conditions (in the absence of sulphide). Pitting corrosion is only likely to occur early in the evolution of the repository environment, whilst the canister is still relatively cool ( 2 available to support localised corrosion, and prior to the increase in pore-water pH and salinity. The subsequent increase in canister surface temperature, pore-water pH and salinity, and decrease in O 2 will make pit initiation less likely, although the canister will remain passive provided the pore-water pH is maintained above pH 9. The higher the pore-water pH, the more strongly the canister is passivated and the less likely the surface is to undergo localised attack. If the pore-water salinity increases prior to the increase in pH, there could be a period of active canister corrosion before passivation occurs.Under these circumstances, the corrosion potential will be a true mixed potential, determine by the relative kinetics of Cu dissolution as CuCl 2 - and of the reduction of O 2 . The development of anoxic conditions and an increase in pore-water sulphide concentration will

  16. Retention of alkaline earth elements in man

    International Nuclear Information System (INIS)

    Newton, D.

    1990-06-01

    The data on human metabolism and long-term retention of alkaline earth elements ( 133 Ba injected into six healthy male volunteers at age 25-81 y and 45 Ca and 85 Sr received by one healthy male volunteer) are presented. Excreta were collected for 2-3 weeks after injection of the tracer into an antecubital vein. Activity in urine, ashed faeces and early samples of blood plasma was determined by gamma-ray scintillation spectrometry. Whole body retention has been assessed through serial measurements of body radioactivity. The injected 133 Ba apparently became mainly skeletal within several days, much earlier than predicted by the ICRP model. The whole-body retention at 32 d ranged from 5 to 14%, the rate of loss correlating with the excretory plasma clearance rate. No age-related trends were identified in the metabolism of Ca and Sr. 2 refs, 2 figs

  17. Properties of cathode materials in alkaline cells

    International Nuclear Information System (INIS)

    Salkind, A.J.; McBreen, J.; Freeman, R.; Parkhurst, W.A.

    1985-01-01

    Conventional and new cathode materials in primary and secondary alkaline cells were investigated for stability, structure, electrochemical reversibility and efficiency. Included were various forms of AgO for reserve-type silver-zinc batteries, a new material - AgNiO/sub 2/ - and several nickel electrodes for nickel-cadmium and nickel-hydrogen cells for aerospace applications. A comparative study was made of the stability of electroformed and chemically prepared AgO. Stability was correlated with impurities detected by XPS and SAM. After the first discharge AgNiO/sub 2/ can be recharged to the monovalent level. The discharge product is predominantly silver. Plastic-bonded nickel electrodes display a second plateau on discharge. Additions of Co(OH)/sub 2/ largely eliminate this

  18. Alkaline pulping of some eucalypts from Sudan.

    Science.gov (United States)

    Khristova, P; Kordsachia, O; Patt, R; Dafaalla, S

    2006-03-01

    Four eucalypts (Eucalyptus camaldulensis, Eucalyptus microtheca, Eucalyptus tereticornis and Eucalyptus citriodora) grown in Sudan were examined for their suitability for pulping and papermaking with different alkaline methods. Their physical, morphological and chemical characteristics are reported. The pulping trials with E. citriodora and E. tereticornis were carried out using the kraft-AQ, soda-AQ, modified AS/AQ (ASA), ASAM and kraft methods. For the other two species, only the ASAM and the kraft process were applied. ASAM pulping gave the best results in terms of yield, degree of delignification, mechanical and optical pulp properties. The best pulps, obtained in kraft and ASAM cooking of E. citriodora, were bleached to 88% ISO brightness in a totally chlorine free bleaching sequence (OQ1O/PQ2P). The bleached pulps, especially the ASAM pulp, showed good papermaking properties and would be suitable for manufacture of writing and printing grades of paper.

  19. Corrosion of copper in alkaline chloride environments

    Energy Technology Data Exchange (ETDEWEB)

    King, F. [Integrity Corrosion Consulting Ltd., Calgary (Canada)

    2002-08-01

    The available literature information on the corrosion and electrochemical behaviour of copper in alkaline environments has been reviewed. The purpose of the review was to assess the impact of an alkaline plume from cementitious material on the corrosion behaviour of a copper canister in an SKB-3 type repository. The effect of the evolution of the environmental conditions within the repository have been considered, including the effects of temperature, redox conditions, pore-water salinity and pH. If the pore-water pH increases prior to the establishment of anoxic conditions, the canister surface will passivate as the pore-water pH exceeds a value of {approx} pH 9. Passivation will result from the formation of a duplex Cu{sub 2}O/Cu(OH){sub 2} film. The corrosion potential will be determined by the equilibrium potential for the Cu{sub 2}O/Cu(OH){sub 2} couple under oxic conditions, or by the Cu/Cu{sub 2}O redox couple under anoxic conditions (in the absence of sulphide). Pitting corrosion is only likely to occur early in the evolution of the repository environment, whilst the canister is still relatively cool (<40 deg C), whilst there is still O{sub 2} available to support localised corrosion, and prior to the increase in pore-water pH and salinity. The subsequent increase in canister surface temperature, pore-water pH and salinity, and decrease in O{sub 2} will make pit initiation less likely, although the canister will remain passive provided the pore-water pH is maintained above pH 9. The higher the pore-water pH, the more strongly the canister is passivated and the less likely the surface is to undergo localised attack. If the pore-water salinity increases prior to the increase in pH, there could be a period of active canister corrosion before passivation occurs.Under these circumstances, the corrosion potential will be a true mixed potential, determine by the relative kinetics of Cu dissolution as CuCl{sub 2} - and of the reduction of O{sub 2}. The development

  20. Alkaline batteries for hybrid and electric vehicles

    Science.gov (United States)

    Haschka, F.; Warthmann, W.; Benczúr-Ürmössy, G.

    Forced by the USABC PNGV Program and the EZEV regulation in California, the development of hybrid vehicles become more strong. Hybrids offer flexible and unrestricted mobility, as well as pollution-free driving mode in the city. To achieve these requirements, high-power storage systems are demanded fulfilled by alkaline batteries (e.g., nickel/cadmium, nickel/metal hydride). DAUG has developed nickel/cadmium- and nickel/metal hydride cells in Fibre Technology of different performance types (up to 700 W/kg peak power) and proved in electric vehicles of different projects. A special bipolar cell design will meet even extreme high power requirements with more than 1000 W/kg peak power. The cells make use of the Recom design ensuring high power charge ability at low internal gas pressure. The paper presents laboratory test results of cells and batteries.

  1. Alkaline batteries for hybrid and electric vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Haschka, F.; Warthmann, W.; Benczur-Uermoessy, G. [DAUG Deutsche Automobilgesellschaft, Esslingen (Germany)

    1998-03-30

    Forced by the USABC PNGV Program and the EZEV regulation in California, the development of hybrid vehicles become more strong. Hybrids offer flexible and unrestricted mobility, as well as pollution-free driving mode in the city. To achieve these requirements, high-power storage systems are demanded fulfilled by alkaline batteries (e.g. nickel/cadmium, nickel/metal hydride). DAUG has developed nickel/cadmium- and nickel/metal hydride cells in Fibre Technology of different performance types (up to 700 W/kg peak power) and proved in electric vehicles of different projects. A special bipolar cell design will meet even extreme high power requirements with more than 1000 W/kg peak power. The cells make use of the Recom design ensuring high power charge ability at low internal gas pressure. The paper presents laboratory test results of cells and batteries. (orig.)

  2. Enzymatic Hydrolysis of Alkaline Pretreated Coconut Coir

    Directory of Open Access Journals (Sweden)

    Akbarningrum Fatmawati

    2013-06-01

    Full Text Available The purpose of this research is to study the effect of concentration and temperature on the cellulose and lignin content, and the reducing sugars produced in the enzymatic hydrolysis of coconut coir. In this research, the coconut coir is pretreated using 3%, 7%, and 11% NaOH solution at 60oC, 80oC, and 100oC. The pretreated coir were assayed by measuring the amount of cellulose and lignin and then hydrolysed using Celluclast and Novozyme 188 under various temperature (30oC, 40oC, 50oC and pH (3, 4, 5. The hydrolysis results were assayed for the reducing sugar content. The results showed that the alkaline delignification was effective to reduce lignin and to increase the cellulose content of the coir. The best delignification condition was observed at 11% NaOH solution and 100oC which removed 14,53% of lignin and increased the cellulose content up to 50,23%. The best condition of the enzymatic hydrolysis was obtained at 50oC and pH 4 which produced 7,57 gr/L reducing sugar. © 2013 BCREC UNDIP. All rights reservedReceived: 2nd October 2012; Revised: 31st January 2013; Accepted: 6th February 2013[How to Cite: Fatmawati, A., Agustriyanto, R., Liasari, Y. (2013. Enzymatic Hydrolysis of Alkaline Pre-treated Coconut Coir. Bulletin of Chemical Reaction Engineering & Catalysis, 8 (1: 34-39 (doi:10.9767/bcrec.8.1.4048.34-39[Permalink/DOI: http://dx.doi.org/10.9767/bcrec.8.1.4048.34-39] | View in  |

  3. Application of alkaline waterflooding to a high acidity crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Sayyouh, M.H. (King Sand Univ., Riyadh (SA). Petroleum Engineering Dept.); Abdel-Waly, A.; Osman, A. (Cairo Univ. (EG). Petroleum Engineering Dept.); Awara, A.Z. (Geisum Oil Company, Cairo (EG))

    The enhanced recovery of a high acidity crude oil (South Geisum crude) by alkaline solutions is studied. Acidity, interfacial tension, and contact angle, were investigated. Displacement tests were carried out to study the effect of alkaline slug concentration, slug size, oil alkali type, temperature and viscosity on recovery. The interfacial tension between crude oil and formation water decreases with increasing alkaline concentration until a minimum, after which it increases again. Contact angle measurements indicated oil-wetting conditions that increase by the addition of alkaline solutions. At the early stages of displacement, oil recovery increases with increasing alkaline concentration until a maximum at 4% by weight NaOH concentration. Also, at such early stages, an excessive increase in alkaline concentration results in lower oil recovery. On the other hand, after the injection of many pore volumes of water, oil recovery is almost the same regardless of the alkaline concentration. Oil recovery increases with increasing alkaline slug size until a maximum at 15% PV. Sodium hydroxide slugs produce more oil recovery than sodium carbonate slugs. Oil recovery increases with increasing temperature (from 25 to 55{sup 0}C) and decreasing oil viscosity.

  4. Alkaline protease production on date waste by an alkalophilic ...

    African Journals Online (AJOL)

    STORAGESEVER

    2008-05-16

    May 16, 2008 ... After 72 h incubation in a shaker incubator ... different incubation times (0 to 72 h) were investigated. Alkaline .... of alkaline protease (75%) and 24% of total protein is precipitated. ... starches and wheat flour as carbon source on protease production .... JP 395, method of making and detergent composition.

  5. A generally applicable sequential alkaline phosphatase immunohistochemical double staining

    NARCIS (Netherlands)

    van der Loos, Chris M.; Teeling, Peter

    2008-01-01

    A universal type of sequential double alkaline phosphatase immunohistochemical staining is described that can be used for formalin-fixed, paraffin-embedded and cryostat tissue sections from human and mouse origin. It consists of two alkaline phosphatase detection systems including enzymatic

  6. Increased river alkalinization in the Eastern U.S.

    Science.gov (United States)

    Kaushal, Sujay S; Likens, Gene E; Utz, Ryan M; Pace, Michael L; Grese, Melissa; Yepsen, Metthea

    2013-09-17

    The interaction between human activities and watershed geology is accelerating long-term changes in the carbon cycle of rivers. We evaluated changes in bicarbonate alkalinity, a product of chemical weathering, and tested for long-term trends at 97 sites in the eastern United States draining over 260,000 km(2). We observed statistically significant increasing trends in alkalinity at 62 of the 97 sites, while remaining sites exhibited no significant decreasing trends. Over 50% of study sites also had statistically significant increasing trends in concentrations of calcium (another product of chemical weathering) where data were available. River alkalinization rates were significantly related to watershed carbonate lithology, acid deposition, and topography. These three variables explained ~40% of variation in river alkalinization rates. The strongest predictor of river alkalinization rates was carbonate lithology. The most rapid rates of river alkalinization occurred at sites with highest inputs of acid deposition and highest elevation. The rise of alkalinity in many rivers throughout the Eastern U.S. suggests human-accelerated chemical weathering, in addition to previously documented impacts of mining and land use. Increased river alkalinization has major environmental implications including impacts on water hardness and salinization of drinking water, alterations of air-water exchange of CO2, coastal ocean acidification, and the influence of bicarbonate availability on primary production.

  7. Increasing the alkaline protease activity of Bacillus cereus and ...

    African Journals Online (AJOL)

    User

    2011-05-09

    May 9, 2011 ... cereus and Bacillus polymyxa simultaneously with the start of sporulation phase as a ... microbial forms to inactivation by chemical or physical agents. .... alkaline pH, 9, 10 and 11 and the pH of the culture media was optimized with .... incubation temperature for alkaline protease production by Bacillus ...

  8. Production of alkaline protease by Teredinobacter turnirae cells ...

    African Journals Online (AJOL)

    The conditions for immobilizing the new alkaline protease-producing bacteria strain Teredinobacter turnirae by entrapment in calcium alginate gel were investigated. The influence of alginate concentration (20, 25 and 30 g/l) and initial cell loading (ICL) on enzyme production were studied. The production of alkaline ...

  9. Production of alkaline proteases by alkalophilic Bacillus subtilis ...

    African Journals Online (AJOL)

    Tuoyo Aghomotsegin

    2016-11-23

    Nov 23, 2016 ... A new strain of Bacillus sp. was isolated from alkaline soil, which was able to produce extracellular alkaline ... rice and dates (Khosravi-Darani et al., 2008), protein by- products from lather ..... Pigeon pea waste as a novel ...

  10. Comparative Detection of Alkaline Protease Production in Exiguobacterium acetylicum

    International Nuclear Information System (INIS)

    Gomaa, O.M.; EI Shafey, H.M.

    2009-01-01

    Alkaline protease is one of the most important enzymes in industry, medicine, and research. In the present work, a comparative detection for alkaline protease activity was established for instant detection of enzyme activity. Eight different alkalophilic bacterial isolates were compared based on the clear zone they produced on skim milk agar. One strain gave an absolute clear zone in 16 hours and was used for alkaline protease detection. The result of Phenotypic identification using Biology Microlog 3 identified the isolate as Exiguobacterium acetylicum. The isolate under study showed slightly different characteristics from a known Exiguobacterium acetylicum strain. The isolate tolerated alkaline conditions up to ph 11, while good growth was evident at ph 7, the maximum alkaline protease activity was observed at ph 9 which reached up to 109.01 U/ml. The alkaline activity assay using alkaline protease enzyme assay were coordinating with those obtained by conductivity; there was a relevant decrease in conductivity at the maximum increase in enzyme activity, which proved the cell membrane conductivity has a close relation to alkaline protease production. This isolate has tolerated gamma radiation, the increase in dose (up to 4 Gy) gave wider clear zones in terms of diameter and this was relevant to the conductivity measurements

  11. Partial purification and characterization of alkaline proteases from ...

    African Journals Online (AJOL)

    Alkaline proteases from the digestive tract of anchovy were partially purified by ammonium sulfate fractionation, dialysis and Sephadex G-75 gel filtration. The purification fold and yield were 6.23 and 4.49%, respectively. The optimum activities of partially purified alkaline proteases were observed at 60°C and at pH 11.0.

  12. Ethanol production from bamboo using mild alkaline pre-extraction followed by alkaline hydrogen peroxide pretreatment.

    Science.gov (United States)

    Yuan, Zhaoyang; Wen, Yangbing; Kapu, Nuwan Sella

    2018-01-01

    A sequential two-stage pretreatment process comprising alkaline pre-extraction and alkaline hydrogen peroxide pretreatment (AHP) was investigated to convert bamboo carbohydrates into bioethanol. The results showed that mild alkaline pre-extraction using 8% (w/w) sodium hydroxide (NaOH) at 100°C for 180min followed by AHP pretreatment with 4% (w/w) hydrogen peroxide (H 2 O 2 ) was sufficient to generate a substrate that could be efficiently digested with low enzyme loadings. Moreover, alkali pre-extraction enabled the use of lower H 2 O 2 charges in AHP treatment. Two-stage pretreatment followed by enzymatic hydrolysis with only 9FPU/g cellulose led to the recovery of 87% of the original sugars in the raw feedstock. The use of the pentose-hexose fermenting Saccharomyces cerevisiae SR8u strain enabled the utilization of 95.7% sugars in the hydrolysate to reach 4.6%w/v ethanol titer. The overall process also enabled the recovery of 62.9% lignin and 93.8% silica at high levels of purity. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Growth of plutons by incremental emplacement of sheets in crystal-rich host: Evidence from Miocene intrusions of the Colorado River region, Nevada, USA

    Science.gov (United States)

    Miller, C.F.; Furbish, D.J.; Walker, B.A.; Claiborne, L.L.; Koteas, G.C.; Bleick, H.A.; Miller, J.S.

    2011-01-01

    Growing evidence supports the notion that plutons are constructed incrementally, commonly over long periods of time, yet field evidence for the multiple injections that seem to be required is commonly sparse or absent. Timescales of up to several million years, among other arguments, indicate that the dominant volume does not remain largely molten, yet if growing plutons are constructed from rapidly solidifying increments it is unlikely that intrusive contacts would escape notice. A model wherein magma increments are emplaced into melt-bearing but crystal-rich host, rather than either solid or crystal-poor material, provides a plausible explanation for this apparent conundrum. A partially solidified intrusion undoubtedly comprises zones with contrasting melt fraction and therefore strength. Depending on whether these zones behave elastically or ductilely in response to dike emplacement, intruding magma may spread to form sheets by either of two mechanisms. If the melt-bearing host is elastic on the relevant timescale, magma spreads rather than continuing to propagate upward, where it encounters a zone of higher rigidity (higher crystal fraction). Similarly, if the dike at first ascends through rigid, melt-poor material and then encounters a zone that is weak enough (poor enough in crystals) to respond ductilely, the ascending material will also spread because the dike tip ceases to propagate as in rigid material. We propose that ascending magma is thus in essence trapped, by either mechanism, within relatively crystal-poor zones. Contacts will commonly be obscure from the start because the contrast between intruding material (crystal-poorer magma) and host (crystal-richer material) is subtle, and they may be obscured even further by subsequent destabilization of the crystal-melt framework. Field evidence and zircon zoning stratigraphy in plutons of the Colorado River region of southern Nevada support the hypothesis that emplacement of magma replenishments into a

  14. The effect of irrigated rice cropping on the alkalinity of two alkaline rice soils in the Sahel

    NARCIS (Netherlands)

    Asten, van P.J.A.; Zelfde, van 't J.A.; Zee, van der S.E.A.T.M.; Hammecker, C.

    2004-01-01

    Irrigated rice cropping is practiced to reclaim alkaline-sodic soils in many parts of the world. This practice is in apparent contrast with earlier studies in the Sahel, which suggests that irrigated rice cropping may lead to the formation of alkaline-sodic soils. Soil column experiments were done

  15. Insights into the emplacement of upper-crustal plutons and their relationship to large silicic calderas, from field relationships, geochronology, and zircon trace element geochemistry in the Stillwater - Clan Alpine caldera complex, western Nevada, USA

    Science.gov (United States)

    Colgan, Joseph P.; John, David A.; Henry, Christopher D.; Watts, Kathryn E.

    2018-01-01

    Geologic mapping, new U-Pb zircon ages, and new and published 40Ar/39Ar sanidine ages document the timing and extent of Oligocene magmatism in the southern Stillwater Range and Clan Alpine Mountains of western Nevada, where Miocene extension has exposed at least six nested silicic calderas and underlying granitic plutons to crustal depths locally ≥ 9 km. Both caldera-forming rhyolitic tuffs and underlying plutons were emplaced in two episodes, one from about 30.4-28.2 Ma that included the Deep Canyon, Job Canyon, and Campbell Creek calderas and underlying plutons, and one from about 25.3-24.8 Ma that included the Louderback Mountains, Poco Canyon, and Elevenmile Canyon calderas and underlying plutons. In these two 1-2 m.y. periods, almost the entire Mesozoic upper crust was replaced by Oligocene intrusive and extrusive rocks to depths ≥ 9 km over an estimated total area of 1500 km2 (pre-extension). Zircon trace element geochemistry indicates that some plutonic rock can be solidified residual magma from the tuff eruptions. Most plutons are not solidified residual magma, although they directly underlie calderas and were emplaced along the same structures shortly after to as much as one million years after caldera formation. Magma chambers and plutons grew by floor subsidence accommodated by downward transfer of country rocks. If other Great Basin calderas are similar, the dense concentration of shallowly exposed calderas in central Nevada is underlain by a complexly zoned mid-Cenozoic batholith assembled in discrete pulses that coincided with formation of large silicic calderas up to 2500-5000 km3.

  16. Insights into the emplacement of upper-crustal plutons and their relationship to large silicic calderas, from field relationships, geochronology, and zircon trace element geochemistry in the Stillwater – Clan Alpine caldera complex, western Nevada, USA

    Science.gov (United States)

    Colgan, Joseph P.; John, David A.; Henry, Christopher D.; Watts, Kathryn E.

    2018-01-01

    Geologic mapping, new U-Pb zircon ages, and new and published 40Ar/39Ar sanidine ages document the timing and extent of Oligocene magmatism in the southern Stillwater Range and Clan Alpine Mountains of western Nevada, where Miocene extension has exposed at least six nested silicic calderas and underlying granitic plutons to crustal depths locally ≥ 9 km. Both caldera-forming rhyolitic tuffs and underlying plutons were emplaced in two episodes, one from about 30.4–28.2 Ma that included the Deep Canyon, Job Canyon, and Campbell Creek calderas and underlying plutons, and one from about 25.3–24.8 Ma that included the Louderback Mountains, Poco Canyon, and Elevenmile Canyon calderas and underlying plutons. In these two 1–2 m.y. periods, almost the entire Mesozoic upper crust was replaced by Oligocene intrusive and extrusive rocks to depths ≥ 9 km over an estimated total area of ~ 1500 km2 (pre-extension). Zircon trace element geochemistry indicates that some plutonic rock can be solidified residual magma from the tuff eruptions. Most plutons are not solidified residual magma, although they directly underlie calderas and were emplaced along the same structures shortly after to as much as one million years after caldera formation. Magma chambers and plutons grew by floor subsidence accommodated by downward transfer of country rocks. If other Great Basin calderas are similar, the dense concentration of shallowly exposed calderas in central Nevada is underlain by a complexly zoned mid-Cenozoic batholith assembled in discrete pulses that coincided with formation of large silicic calderas up to 2500–5000 km3.

  17. Petrology, Magnetic susceptibility, Tectonic setting and mineralization associated with Plutonic and Volcanic Rocks, Eastern Bajestan and Taherabad, Iran

    Directory of Open Access Journals (Sweden)

    Malihe Ghoorchi

    2009-09-01

    Full Text Available Study area is located in district of Bajestan and Ferdows cities, NE of Iran. Structurally, this area is part of Lut block. The oldest exposed rocks, to the north of intrusive rocks and in Eastern Bajestan, are meta-chert, slate, quartzite, thin-bedded crystalline limestone and meta-argillite. The sedimentary units are: Sardar Formation (Carboniferous, Jamal Formation (Permian, Sorkh Shale and Shotori Formations (Triassic, carbonateous rocks (Cretaceous and lithostratigraphically equivalent to Kerman conglomerate (Cretaceous-Paleocene are exposed in this area. Based on relative age, magmatism in eastern Bajestan and Taherabad started after Late Cretaceous and it has been active and repeated during Tertiary time. At least, three episodes of volcanic activities are recognized in this area. The first stage was mainly volcanic flow with mafic composition and minor intermediate. The second episode was mainly intermediate in composition. The third stage was changed to acid-intermediate in composition. Since the plutonic rocks intruded the volcanic rocks, therefore they may be Oligo-Miocene age. Bajestan intrusive rocks are granite-granodiorite-quartz monzonite. Taherabad intrusive rocks are diorite-quartz diorite- monzonite-latite. Bajestan intrusive rocks are reduced type (ilmenite series and Taherabad intrusive rocks are oxidized type (magnetite series.Based on geochemical analysis including trace elements, REE and isotopic data, Bajestan intrusive rocks formed in continental collision zone and the magma has crustal origin. Taherabad intrusive rocks were formed in subduction zone and magma originated from oceanic crust. Taherabad intrusive rock has exploration potential for Cu-Au and pb.

  18. 2nd Generation alkaline electrolysis. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Yde, L. [Aarhus Univ. Business and Social Science - Centre for Energy Technologies (CET), Aarhus (Denmark); Kjartansdottir, C.K. [Technical Univ. of Denmark. DTU Mechanical Engineering, Kgs. Lyngby (Denmark); Allebrod, F. [Technical Univ. of Denmark. DTU Energy Conversion, DTU Risoe Campus, Roskilde (Denmark)] [and others

    2013-03-15

    The overall purpose of this project has been to contribute to this load management by developing a 2{sup nd} generation of alkaline electrolysis system characterized by being compact, reliable, inexpensive and energy efficient. The specific targets for the project have been to: 1) Increase cell efficiency to more than 88% (according to the higher heating value (HHV)) at a current density of 200 mA /cm{sup 2}; 2) Increase operation temperature to more than 100 degree Celsius to make the cooling energy more valuable; 3) Obtain an operation pressure more than 30 bar hereby minimizing the need for further compression of hydrogen for storage; 4) Improve stack architecture decreasing the price of the stack with at least 50%; 5) Develop a modular design making it easy to customize plants in the size from 20 to 200 kW; 6) Demonstrating a 20 kW 2{sup nd} generation stack in H2College at the campus of Arhus University in Herning. The project has included research and development on three different technology tracks of electrodes; an electrochemical plating, an atmospheric plasma spray (APS) and finally a high temperature and pressure (HTP) track with operating temperature around 250 deg. C and pressure around 40 bar. The results show that all three electrode tracks have reached high energy efficiencies. In the electrochemical plating track a stack efficiency of 86.5% at a current density of 177mA/cm{sup 2} and a temperature of 74.4 deg. C has been shown. The APS track showed cell efficiencies of 97%, however, coatings for the anode side still need to be developed. The HTP cell has reached 100 % electric efficiency operating at 1.5 V (the thermoneutral voltage) with a current density of 1. 1 A/cm{sup 2}. This track only tested small cells in an externally heated laboratory set-up, and thus the thermal loss to surroundings cannot be given. The goal set for the 2{sup nd} generation electrolyser system, has been to generate 30 bar pressure in the cell stack. An obstacle to be

  19. Alkaline fuel cell with nitride membrane

    Science.gov (United States)

    Sun, Shen-Huei; Pilaski, Moritz; Wartmann, Jens; Letzkus, Florian; Funke, Benedikt; Dura, Georg; Heinzel, Angelika

    2017-06-01

    The aim of this work is to fabricate patterned nitride membranes with Si-MEMS-technology as a platform to build up new membrane-electrode-assemblies (MEA) for alkaline fuel cell applications. Two 6-inch wafer processes based on chemical vapor deposition (CVD) were developed for the fabrication of separated nitride membranes with a nitride thickness up to 1 μm. The mechanical stability of the perforated nitride membrane has been adjusted in both processes either by embedding of subsequent ion implantation step or by optimizing the deposition process parameters. A nearly 100% yield of separated membranes of each deposition process was achieved with layer thickness from 150 nm to 1 μm and micro-channel pattern width of 1μm at a pitch of 3 μm. The process for membrane coating with electrolyte materials could be verified to build up MEA. Uniform membrane coating with channel filling was achieved after the optimization of speed controlled dip-coating method and the selection of dimethylsulfoxide (DMSO) as electrolyte solvent. Finally, silver as conductive material was defined for printing a conductive layer onto the MEA by Ink-Technology. With the established IR-thermography setup, characterizations of MEAs in terms of catalytic conversion were performed successfully. The results of this work show promise for build up a platform on wafer-level for high throughput experiments.

  20. Reduction of proteinuria through podocyte alkalinization.

    Science.gov (United States)

    Altintas, Mehmet M; Moriwaki, Kumiko; Wei, Changli; Möller, Clemens C; Flesche, Jan; Li, Jing; Yaddanapudi, Suma; Faridi, Mohd Hafeez; Gödel, Markus; Huber, Tobias B; Preston, Richard A; Jiang, Jean X; Kerjaschki, Dontscho; Sever, Sanja; Reiser, Jochen

    2014-06-20

    Podocytes are highly differentiated cells and critical elements for the filtration barrier of the kidney. Loss of their foot process (FP) architecture (FP effacement) results in urinary protein loss. Here we show a novel role for the neutral amino acid glutamine in structural and functional regulation of the kidney filtration barrier. Metabolic flux analysis of cultured podocytes using genetic, toxic, and immunologic injury models identified increased glutamine utilization pathways. We show that glutamine uptake is increased in diseased podocytes to couple nutrient support to increased demand during the disease state of FP effacement. This feature can be utilized to transport increased amounts of glutamine into damaged podocytes. The availability of glutamine determines the regulation of podocyte intracellular pH (pHi). Podocyte alkalinization reduces cytosolic cathepsin L protease activity and protects the podocyte cytoskeleton. Podocyte glutamine supplementation reduces proteinuria in LPS-treated mice, whereas acidification increases glomerular injury. In summary, our data provide a metabolic opportunity to combat urinary protein loss through modulation of podocyte amino acid utilization and pHi. © 2014 by The American Society for Biochemistry and Molecular Biology, Inc.

  1. Alkaline phosphatase activity of rumen bacteria.

    Science.gov (United States)

    Cheng, K J; Costerton, J W

    1977-11-01

    Of the 54 strains of rumen bacteria examined for alkaline phosphatase (APase) production, 9 of 33 gram-negative strains and none of 21 gram-positive strains produced the enzyme. The APase of the cells of the three strains of Bacteroides ruminicola that produced significant amounts of the enzyme was located in the periplasmic area of the cell envelope, whereas the enzyme was located in the strains of Selenomonas ruminantium and Succinivibrio dextrinosolvens was associated with the outer membrane. The localization of APase production in the cells of natural populations of rumen bacteria from hay-fed sheep was accomplished by reaction product deposition, and both the proportion of APase-producing bacteria and the location of the enzyme in the cell envelope of the producing cells could be determined. We suggest that this procedure is useful in detecting shifts in the bacterial population and the release of cell-bound APase that accompany feedlot bloat and other sequelae of dietary manipulation in ruminants.

  2. Identification of human pulmonary alkaline phosphatase isoenzymes.

    Science.gov (United States)

    Capelli, A; Cerutti, C G; Lusuardi, M; Donner, C F

    1997-04-01

    An increase of alkaline phosphatase (ALP) activity has been observed in the bronchoalveolar lavage fluid (BALF) of patients affected by pulmonary fibrosis in chronic interstitial lung disorders. To characterize the ALP isoenzymes in such cases, we used gel filtration, agarose gel electrophoresis, heat and amino acid inhibition assays, wheat-germ agglutinin (WGA) precipitation, and an immunoassay specific for the bone-isoform of ALP. Only one anodic band representing a high-molecular-weight isoform of ALP (Mr approximately 2,000 kDa) was observed on electrophoresis of BALF. The inhibition assay results were consistent for a tissue-nonspecific isoenzyme sensitive to a temperature of 56 degrees C (71.9 +/- 2.5% inhibition) and to homoarginine (65.7 +/- 1.9%), and resistant to L-phenylalanine and L-leucine. Less than 13% of ALP activity was heat-stable. After incubation of BALF specimens with glycosyl-phosphatidylinositol-phospholipase D plus Nonidet P-40, or with phosphatidylinositol-phospholipase C alone, an electrophoretic cathodic band (Mr approximately 220 kDa) appeared near the bone band of a standard serum. With the WGA assay, 84.4 +/- 3.3% of ALP precipitated and the band disappeared. After immunoassay for the bone isoform, a mean of less than 5% enzyme activity was measured. We conclude that the ALP found in BALF is a pulmonary isoform of a tissue nonspecific isoenzyme.

  3. Response of Desulfovibrio vulgaris to Alkaline Stress

    Energy Technology Data Exchange (ETDEWEB)

    Stolyar, S.; He, Q.; He, Z.; Yang, Z.; Borglin, S.E.; Joyner, D.; Huang, K.; Alm, E.; Hazen, T.C.; Zhou, J.; Wall, J.D.; Arkin, A.P.; Stahl, D.A.

    2007-11-30

    The response of exponentially growing Desulfovibrio vulgarisHildenborough to pH 10 stress was studied using oligonucleotidemicroarrays and a study set of mutants with genes suggested by microarraydata to be involved in the alkaline stress response deleted. The datashowed that the response of D. vulgaris to increased pH is generallysimilar to that of Escherichia coli but is apparently controlled byunique regulatory circuits since the alternative sigma factors (sigma Sand sigma E) contributing to this stress response in E. coli appear to beabsent in D. vulgaris. Genes previously reported to be up-regulated in E.coli were up-regulated in D. vulgaris; these genes included three ATPasegenes and a tryptophan synthase gene. Transcription of chaperone andprotease genes (encoding ATP-dependent Clp and La proteases and DnaK) wasalso elevated in D. vulgaris. As in E. coli, genes involved in flagellumsynthesis were down-regulated. The transcriptional data also identifiedregulators, distinct from sigma S and sigma E, that are likely part of aD. vulgaris Hildenborough-specific stress response system.Characterization of a study set of mutants with genes implicated inalkaline stress response deleted confirmed that there was protectiveinvolvement of the sodium/proton antiporter NhaC-2, tryptophanase A, andtwo putative regulators/histidine kinases (DVU0331 andDVU2580).

  4. Solubility of pllutonium in alkaline salt solutions

    International Nuclear Information System (INIS)

    Hobbs, D.T.; Edwards, T.B.

    1993-01-01

    Plutonium solubility data from several studies have been evaluated. For each data set, a predictive model has been developed where appropriate. In addition, a statistical model and corresponding prediction intervals for plutonium solubility as a quadratic function of the hydroxide concentration have been developed. Because of the wide range of solution compositions, the solubility of plutonium can vary by as much as three orders of magnitude for any given hydroxide concentration and still remain within the prediction interval. Any nuclear safety assessments that depend on the maximum amount of plutonium dissolved in alkaline salt solutions should use concentrations at least as great as the upper prediction limits developed in this study. To increase the confidence in the prediction model, it is recommended that additional solubility tests be conducted at low hydroxide concentrations and with all of the other solution components involved. To validate the model for application to actual waste solutions, it is recommended that the plutonium solubilities in actual waste solutions be determined and compared to the values predicted by the quadratic model

  5. Alkaline Materials and Regenerative Endodontics: A Review

    Directory of Open Access Journals (Sweden)

    Bill Kahler

    2017-12-01

    Full Text Available Periapical health is the primary goal of endodontic treatment in mature and immature teeth. In addition, the goals of treatment of immature teeth with arrested root development include root growth to length and maturation of the apex, as well as thickening of the canal wall. These goals are valid for immature teeth that have been subjected to trauma and dental caries or that are the result of developmental anomalies that expose the tooth to the risk of pulp necrosis and consequently result in the cessation of root maturation. Regenerative endodontic procedures (REPs have been described as a “paradigm shift” in the treatment of immature teeth with pulp necrosis and underdeveloped roots, as there is the potential for further root maturation and return of vitality. Treatment with REPs is advocated as the treatment of choice for immature teeth with pulp necrosis. REP protocols involve the use of alkaline biomaterials, primarily sodium hypochlorite, calcium hydroxide, mineral trioxide aggregates and Biodentine, and are the essential components of a successful treatment regimen.

  6. Alkaline Phosphatase, an Unconventional Immune Protein

    Directory of Open Access Journals (Sweden)

    Bethany A. Rader

    2017-08-01

    Full Text Available Recent years have seen an increase in the number of studies focusing on alkaline phosphatases (APs, revealing an expanding complexity of function of these enzymes. Of the four human AP (hAP proteins, most is known about tissue non-specific AP (TNAP and intestinal AP (IAP. This review highlights current understanding of TNAP and IAP in relation to human health and disease. TNAP plays a role in multiple processes, including bone mineralization, vitamin B6 metabolism, and neurogenesis, is the genetic cause of hypophosphatasia, influences inflammation through regulation of purinergic signaling, and has been implicated in Alzheimer’s disease. IAP regulates fatty acid absorption and has been implicated in the regulation of diet-induced obesity and metabolic syndrome. IAP and TNAP can dephosphorylate bacterial-derived lipopolysaccharide, and IAP has been identified as a potential regulator of the composition of the intestinal microbiome, an evolutionarily conserved function. Endogenous and recombinant bovine APs and recombinant hAPs are currently being explored for their potential as pharmacological agents to treat AP-associated diseases and mitigate multiple sources of inflammation. Continued research on these versatile proteins will undoubtedly provide insight into human pathophysiology, biochemistry, and the human holobiont.

  7. The aluminum chemistry and corrosion in alkaline solutions

    International Nuclear Information System (INIS)

    Zhang Jinsuo; Klasky, Marc; Letellier, Bruce C.

    2009-01-01

    Aluminum-alkaline solution systems are very common in engineering applications including nuclear engineering. Consequently, a thorough knowledge of the chemistry of aluminum and susceptibility to corrosion in alkaline solutions is reviewed. The aluminum corrosion mechanism and corrosion rate are examined based on current experimental data. A review of the phase transitions with aging time and change of environment is also performed. Particular attention is given to effect of organic and inorganic ions. As an example, the effect of boron is examined in detail because of the application in nuclear reactor power systems. Methods on how to reduce the corrosion rate of aluminum in alkaline solutions are also highlighted

  8. Magmatic-hydrothermal fluids and volatile metals in the Spirit Lake pluton and Margaret Cu-Mo porphyry system, SW Washington, USA

    Science.gov (United States)

    Iveson, Alexander A.; Webster, James D.; Rowe, Michael C.; Neill, Owen K.

    2016-03-01

    The halogen-bearing minerals tourmaline, amphibole, and biotite formed during magmatic-hydrothermal processes associated with the late-stage cooling of the Spirit Lake granitoid pluton (Mt. St. Helens, WA) and with the younger sulphide-mineralised rocks of the Margaret Cu-Mo porphyry deposit located entirely within the pluton. Major- and trace-element discrimination suggests that one tourmaline population crystallised from fractionated late-stage melt pockets in granodiorite-monzogranitic dykes of the pluton. These coarse, euhedral, oscillatory, and complexly sector-zoned uvite tourmalines span a limited range in Mg/(Mg + Fe) [Mg#] space (0.4-0.7 apfu) and show the highest Ti, Ca, F, Nb, and Ta contents, and low X-site vacancies (X-site vacancies (>0.6 apfu), lower Ca and F contents, and the highest Li, As, and HREE contents (>80 ppm Li, >1200 ppm As). This population appears to record direct, rapid crystallisation from magmatic ± meteoric fluid(s) bearing the signature of the breakdown of primary feldspars and pyroxenes, with fluid exsolution from fractionated melt patches likely triggered by the formation of the previous generation of tourmaline. Mineralised porphyry deposit tourmaline compositions from the stockwork span a much larger range in Mg# space (0.05-0.9 apfu) and are almost entirely Ca-free. X-sites of these schorl tourmalines are dominated by Na or vacancies, and the Y-sites are strongly Fe enriched. The highest Mn and Zn concentrations (>4000 and >1000 ppm, respectively) potentially reflect the composition of mineralising fluids during ore deposition. A number of boron isotopic analyses yield predominantly heavy boron, but δ11B values range from -5.2 to 6.2 ‰ and average 1.4 ‰. Whilst most plutonic tourmalines conform to reported a- and c-sector element partitioning models, those from the mineralised porphyry show large and variable sector fractionation differences, suggesting that external controls may also be important. Wider evidence for

  9. Zircon U-Pb Ages Chronicle 3 Myr of Episodic Crystallization in the Composite Miocene Tatoosh Pluton, Mount Rainier National Park, Washington Cascades

    Science.gov (United States)

    Bacon, C. R.; Du Bray, E. A.; Wooden, J. L.; Mazdab, F. K.

    2007-12-01

    Zircon geochronology of upper crustal plutons can constrain longevities of intermediate to silicic magmatic systems. As part of a larger study of the geochemistry and metallogeny of Tertiary Cascades magmatic arc rocks, we used the USGS-Stanford SHRIMP RG to determine 20 to 28 238U-206Pb ages for zircons from each of 6 quartz monzodiorite (qmd), quartz monzonite (qm), or granodiorite (grd) samples representative of the Tatoosh pluton, and one grd from the nearby Carbon River stock. The 7x12 km composite Tatoosh pluton, discontinuously exposed on the south flank of Mount Rainier, consists of at least 4 petrographic/compositional phases, here termed Pyramid Peak, Nisqually, Reflection Lake, and Tatoosh. These collectively intrude gently folded and weakly metamorphosed basaltic andesite flows and volcaniclastic rocks of the Eocene Ohanapecosh Formation, silicic ignimbrites and sedimentary rocks of the Oligocene Stevens Ridge Formation, and basaltic to intermediate volcanic rocks of the Miocene Fifes Peak Formation. Histograms and relative probability plots of U- Pb ages indicate 2 to 4 age populations within each sample. The weighted mean age of each of the youngest populations (all ±2σ) is interpreted as the time of final solidification: Pyramid Peak qmd (58.5% SiO2) 17.4±0.2 Ma, Nisqually grd (in Paradise Valley; 65.4% SiO2) 16.7±0.2 Ma, Nisqually grd (at Christine Falls; 66.4% SiO2) 17.3±0.2 Ma, Reflection Lake qm (along Pinnacle Peak trail; 66.6% SiO2) 17.1±0.2 Ma, Tatoosh grd (in Stevens Canyon; 67.8% SiO2) 18.2±0.2 Ma, Tatoosh grd (south of Louise Lake; 69.3% SiO2) 19.3±0.1 Ma, and Carbon River grd (68.0% SiO2) 17.4±0.3 Ma. The older Nisqually grd age is indistinguishable from a TIMS zircon age of 17.5±0.1 Ma reported by Mattinson (GSA Bulletin 88:1509-1514, 1977) for grd from a nearby locality. None of the 164 SHRIMP-RG U-Pb ages, including cores, is older than 21 Ma. The relatively small, high-level pluton likely was emplaced and solidified in pulses

  10. Age and isotopic fingerprints of some plutonic rocks in the Wiborg rapakivi granite batholith with special reference to the dark wiborgite of the Ristisaari Island

    Directory of Open Access Journals (Sweden)

    Rämö, O.T.

    2014-12-01

    Full Text Available The mid-Proterozoic, locus classicus Wiborg rapakivi granite batholith of southeastern Finland and adjacent Russia comprises a varying, bimodal (silicic-basic sequence of plutonic, subvolcanic, and volcanic rocks. At the current level of erosion silicic rocks are dominant, the most prominent of which are wiborgites and dark wiborgites (that have been considered to mark the main build-up stage of the batholith and pyterlites. New observations and optical microscopy data from the dark wiborgite-dominated Ristisaari Island in the southern, off-shore part of the Wiborg batholith show that dark plagioclase megacrysts in dark wiborgite are calcic xenocrysts. They were probably incorporated into wiborgite magma from consanguineous massiftype anorthosite magmas in the course of the evolution of the bimodal magmatic system. Our new ID-TIMS U-Pb zircon age of the Ristisaari Island dark wiborgite, 1627±3 Ma, is the youngest isotopic age so far determined for the plutonic rocks of the Wiborg batholith. This, combined with preexisting U-Pb zircon data, implies a minimum duration of 12 m.y. (1642–1630 Ma for the emplacement of the plutonic rocks of the batholith. Combined with data on highlevel dike rocks, a window of at least 20 m.y. (1642–1622 Ma is implied. Furthermore, as the batholith grew, the overall locus of magmatism may have shifted southwards. New whole-rock Nd isotope data on the dark wiborgite of the Ristisaari Island and three further granites of the batholith, as well as Nd (whole-rock and Sr (whole-rock, plagioclase isotope data on a spectrolite massif-type anorthosite from the east-central part of the batholith, are also presented. These data suggest that the lithosphere across the Wiborg batholith area in the southeastern part of the Svecofennian orogen may vary slightly in overall mantle separation age.

  11. U-Pb zircon geochronology and Sm-Nd-Pb isotopic constraint for precambrian plutonic rocks in the northeastern part of Ryeongnam massif, Korea

    International Nuclear Information System (INIS)

    Chang, Ho-Wan

    2003-01-01

    The Ryeongnam massif is composed of Precambrian gneisses, Paleozoic and Mesozoic sedimentary rocks and extensive Triassic-Jurassic plutonic rocks of felsic to mafic composition. In the northeast Ryeongnam massif, the oldest rocks belong to the Sobaegsan gneiss complex, which is composed of orthogneisses, paragneisses and mafic plutonic rocks. U-Pb zircon ages for the felsic and mafic intrusive bodies within the Sobaegsan gneiss complex are: the Icheon granite gneiss, 2357±43 and 2342±47 Ma; the Buncheon granite gneiss, 1963±5 Ma; the Pyeonghae granite gneiss, 1936±21 Ma; the Ogbang amphibolite, 1918±10 Ma; the Imwon leucogranite gneiss, 1826±20 Ma. The Hyeondong biotite schist, which is intruded by the Buncheon granite gneiss and the Ogbang amphibolite, yielded an age of 2271±44 Ma. The Nd-Sm-Pb isotopic data indicate that the felsic plutonic rocks are derived from an older Archean crust. The Nd T DM ages are Archean, and the εNd values are negative for the felsic rocks and positive for the amphibolite. Common Pb isotope compositions also indicate a crustal source for the felsic intrusives. The U-Pb ages of Precambrian rocks of the Ryeongnam massifs are similar to those in the Gyeonggi massif, and may have a similar crustal evolutionary history. The Precambrian rocks of South Korea could be related either to the North China block or to the South China block, as the isotope ages and patterns are not unique to either block. Similarly, a geologic correlation with Japan, although possible, is tenuous at present. (author)

  12. Reconnaissance geochemical exploration of the plutons of quartz monzonite and granite in the Jabal Lababa and Ar Rayth areas, southern Asir, Kingdom of Saudi Arabia

    Science.gov (United States)

    Overstreet, W.C.; Assegaff, A.B.; Jambi, Mohammed; Hussain, M.A.; Selner, G.I.; Matzko, J.J.

    1985-01-01

    Geochemical reconnaissance for rare metals in plutons of albite-muscovite granite and quartz monzonite in the vicinity of Jabal Lababa disclosed positive geochemical anomalies for beryllium, tantalum, thorium, lanthanum, niobium, tin, yttrium, and zirconium. The low anomalous values for the rare metals in rocks and the short mechanical dispersion trains, seldom exceeding 4 km in length, of rare-metal-bearing heavy minerals, are interpreted to indicate that primary deposits of these metals are lacking, and any placers would be small and low in tenor.

  13. Microbial alkaline proteases: Optimization of production parameters and their properties

    Directory of Open Access Journals (Sweden)

    Kanupriya Miglani Sharma

    2017-06-01

    Full Text Available Proteases are hydrolytic enzymes capable of degrading proteins into small peptides and amino acids. They account for nearly 60% of the total industrial enzyme market. Proteases are extensively exploited commercially, in food, pharmaceutical, leather and detergent industry. Given their potential use, there has been renewed interest in the discovery of proteases with novel properties and a constant thrust to optimize the enzyme production. This review summarizes a fraction of the enormous reports available on various aspects of alkaline proteases. Diverse sources for isolation of alkaline protease producing microorganisms are reported. The various nutritional and environmental parameters affecting the production of alkaline proteases in submerged and solid state fermentation are described. The enzymatic and physicochemical properties of alkaline proteases from several microorganisms are discussed which can help to identify enzymes with high activity and stability over extreme pH and temperature, so that they can be developed for industrial applications.

  14. Spectroscopic characterization of manganese-doped alkaline earth ...

    Indian Academy of Sciences (India)

    The shapes of spectra are also changed with varying alkaline earth ions content. ... of manganese ion and electrical properties of glass contain- ing mobile ions like .... octahedral crystal field are located above the ground 6S state. Figure 2.

  15. Optimization of alkaline protease production and its fibrinolytic ...

    African Journals Online (AJOL)

    Optimization of alkaline protease production and its fibrinolytic activity from the ... nitrogen sources and sodium chloride concentration for protease production by the ... exploited to assist in protein degradation in various industrial processes.

  16. Guest–host interactions in the alkaline bleaching of ...

    Indian Academy of Sciences (India)

    Administrator

    cyclodextrin on the bleaching rates of triphenylmethane dyes crystal violet (CV), malachite green (MG) and rosaniline. (RA) have been investigated in alkaline medium with a view to understand the guest–host interaction in these system. 2.

  17. The Estimation Formation Alkaline In The Proses Desalination MSF

    International Nuclear Information System (INIS)

    Latiffah, Siti Nurul

    2000-01-01

    Already to go on estimation phenomena formation alkaline scale of a seawater. In desalination system seawater on MSF to go on scale by a thermal decomposition HCO sub.3- ion and hydrolysis carbonate ion with water on the temperature operation. The varieties alkaline scale in attached on tube surface, while reduced efficiency heat transfer and to raise corrosion attack to structure material is caused all this high cost. Estimation to take please which a sum step by step decomposition ion bicarbonate from then information scale which carbonate and hydroxyl ion. The various scale maximal is alkaline form is a calcium carbonate = 116,5 gram per meter cubic the various sedimentation is alkaline and magnesium hydroxide = 67,57 gram per meter cubic

  18. Economic Analysis of Improved Alkaline Water Electrolysis

    International Nuclear Information System (INIS)

    Kuckshinrichs, Wilhelm; Ketelaer, Thomas; Koj, Jan Christian

    2017-01-01

    Alkaline water electrolysis (AWE) is a mature hydrogen production technology and there exists a range of economic assessments for available technologies. For advanced AWEs, which may be based on novel polymer-based membrane concepts, it is of prime importance that development comes along with new configurations and technical and economic key process parameters for AWE that might be of interest for further economic assessments. This paper presents an advanced AWE technology referring to three different sites in Europe (Germany, Austria, and Spain). The focus is on financial metrics, the projection of key performance parameters of advanced AWEs, and further financial and tax parameters. For financial analysis from an investor’s (business) perspective, a comprehensive assessment of a technology not only comprises cost analysis but also further financial analysis quantifying attractiveness and supply/market flexibility. Therefore, based on cash flow (CF) analysis, a comprehensible set of metrics may comprise levelised cost of energy or, respectively, levelized cost of hydrogen (LCH) for cost assessment, net present value (NPV) for attractiveness analysis, and variable cost (VC) for analysis of market flexibility. The German AWE site turns out to perform best in all three financial metrics (LCH, NPV, and VC). Though there are slight differences in investment cost and operation and maintenance cost projections for the three sites, the major cost impact is due to the electricity cost. Although investment cost is slightly lower and labor cost is significantly lower in Spain, the difference can not outweigh the higher electricity cost compared to Germany. Given the assumption that the electrolysis operators are customers directly and actively participating in power markets, and based on the regulatory framework in the three countries, in this special case electricity cost in Germany is lowest. However, as electricity cost is profoundly influenced by political decisions as

  19. Basic study of alkaline water electrolysis

    International Nuclear Information System (INIS)

    Manabe, A.; Kashiwase, M.; Hashimoto, T.; Hayashida, T.; Kato, A.; Hirao, K.; Shimomura, I.; Nagashima, I.

    2013-01-01

    In order to realize future hydrogen society, hydrogen production systems must meet the large demand of hydrogen usage. Alkaline water electrolysis (AWE) would be one of the candidate technologies to produce hydrogen on a large scale from renewable energy. We have conducted basic research into AWE, trying to reveal technical issues under zero gap system in new cell technology. The zero gap system contributes lower cell voltage without causing any major operating problems compared with conventional finite gap cell. However, it was observed that Ni base electrodes showed corrosion phenomena in a number of test trials including steady operating conditions and several shut-downs. Activated Raney Ni alloy coating for anode material had an advantage for oxygen overvoltage. It showed a saving of around 100 mV at 40 A/dm 2 (0.4 A/cm 2 ) against Ni bare anodes. In the Chlor–Alkali (C/A) industry, thermal decomposition coating of mixed noble metal on Ni substrate is commonly used for advanced activated cathodes. It showed very low hydrogen over-potential of around 100 mV in AWE. To achieve better cell performance, separator selection is very important. We evaluated several separators including ion exchange membrane (IEM) to understand the basic function in AWE. IEM for C/A electrolysis showed high cell voltage (over 2.2 V) but low O 2 impurity in H 2 gas. Hydrogen purity was over 99.95%. Porous separators made of polypropylene showed 1.76 V at 40 A/dm 2 (0.4 A/cm 2 ), 80 °C. But there was a weakness on the durability for continuous operation. Proper selection of separator is important in an actual plant for effective and safe cell operation. The concept of safety operation is referred to by diffusion coefficient of hydrogen

  20. Photovoltaic hydrogen production with commercial alkaline electrolysers

    Energy Technology Data Exchange (ETDEWEB)

    Ursua, A.; Lopez, J.; Gubia, E.; Marroyo, L.; Sanchis, P. [Public Univ. of Navarra, Pamplona (Spain). Dept. of Electric and Electronic Engineering

    2010-07-01

    Renewable energy sources and Electrolysis generate the so-called green Hydrogen, a zero-emission and potentially fossil fuel independent energy source. However, the inherent variability of the renewable energy sources implies a mode of operation for which most current electrolysers have not been designed. This paper analyses the operation of a water electrolyser fed with photovoltaic (PV) generator electric profile. The system, Integrated by a 1 Nm{sup 3}/h Hydrogenics alkaline electrolyser and a 5100 W PV generator with 60 BP585 modules, is installed at the Public University of Navarra (Spain). The PV generator profile fed to the electrolyser is emulated by a custom-made apparatus designed and built by the authors of this paper. The profile is designed according to real irradiance data measured by a calibration cell. The irradiance data are converted to the electric power profile that the PV generator would have delivered in case of having been connected to the electrolyser by means of a DC/DC converter with maximum power point tracking (MPPT). Finally, from previously measured power-current electrolyser characteristic curves, the current profile to be delivered to the electrolyser is obtained and programmed to the electronic device. The electrolyser was tested for two types of days. During the first day, the irradiance was very stable, whereas during the second day, the irradiance was very variable. The experimental results show an average power consumption rate and an efficiency of 4908 Wh/Nm{sup 3} and 72.1%, on the first day, and 4842 Wh/Nm{sup 3} and 73.3% on the second day. The electrolyser performance was particularly good in spite of the high variability of the electric supply of the second day. (orig.)

  1. Alkaline Peroxide Delignification of Corn Stover

    Energy Technology Data Exchange (ETDEWEB)

    Mittal, Ashutosh [Biosciences; Katahira, Rui [National; Donohoe, Bryon S. [Biosciences; Black, Brenna A. [National; Pattathil, Sivakumar [Complex; Stringer, Jack M. [National; Beckham, Gregg T. [National

    2017-05-30

    Selective biomass fractionation into carbohydrates and lignin is a key challenge in the conversion of lignocellulosic biomass to fuels and chemicals. In the present study, alkaline hydrogen peroxide (AHP) pretreatment was investigated to fractionate lignin from polysaccharides in corn stover (CS), with a particular emphasis on the fate of the lignin for subsequent valorization. The influence of peroxide loading on delignification during AHP pretreatment was examined over the range of 30-500 mg H2O2/g dry CS at 50 degrees C for 3 h. Mass balances were conducted on the solid and liquid fractions generated after pretreatment for each of the three primary components, lignin, hemicellulose, and cellulose. AHP pretreatment at 250 mg H2O2/g dry CS resulted in the pretreated solids with more than 80% delignification consequently enriching the carbohydrate fraction to >90%. Two-dimensional nuclear magnetic resonance (2D-NMR) spectroscopy of the AHP pretreated residue shows that, under high peroxide loadings (>250 mg H2O2/g dry CS), most of the side chain structures were oxidized and the aryl-ether bonds in lignin were partially cleaved, resulting in significant delignification of the pretreated residues. Gel permeation chromatography (GPC) analysis shows that AHP pretreatment effectively depolymerizes CS lignin into low molecular weight (LMW) lignin fragments in the aqueous fraction. Imaging of AHP pretreated residues shows a more granular texture and a clear lamellar pattern in secondary walls, indicative of layers of varying lignin removal or relocalization. Enzymatic hydrolysis of this pretreated residue at 20 mg/g of glucan resulted in 90% and 80% yields of glucose and xylose, respectively, after 120 h. Overall, AHP pretreatment is able to selectively remove more than 80% of the lignin from biomass in a form that has potential for downstream valorization processes and enriches the solid pulp into a highly digestible material.

  2. Economic Analysis of Improved Alkaline Water Electrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Kuckshinrichs, Wilhelm, E-mail: w.kuckshinrichs@fz-juelich.de; Ketelaer, Thomas; Koj, Jan Christian [Forschungszentrum Juelich, Institute for Energy and Climate Research – Systems Analysis and Technology Evaluation (IEK-STE), Juelich (Germany)

    2017-02-20

    Alkaline water electrolysis (AWE) is a mature hydrogen production technology and there exists a range of economic assessments for available technologies. For advanced AWEs, which may be based on novel polymer-based membrane concepts, it is of prime importance that development comes along with new configurations and technical and economic key process parameters for AWE that might be of interest for further economic assessments. This paper presents an advanced AWE technology referring to three different sites in Europe (Germany, Austria, and Spain). The focus is on financial metrics, the projection of key performance parameters of advanced AWEs, and further financial and tax parameters. For financial analysis from an investor’s (business) perspective, a comprehensive assessment of a technology not only comprises cost analysis but also further financial analysis quantifying attractiveness and supply/market flexibility. Therefore, based on cash flow (CF) analysis, a comprehensible set of metrics may comprise levelised cost of energy or, respectively, levelized cost of hydrogen (LCH) for cost assessment, net present value (NPV) for attractiveness analysis, and variable cost (VC) for analysis of market flexibility. The German AWE site turns out to perform best in all three financial metrics (LCH, NPV, and VC). Though there are slight differences in investment cost and operation and maintenance cost projections for the three sites, the major cost impact is due to the electricity cost. Although investment cost is slightly lower and labor cost is significantly lower in Spain, the difference can not outweigh the higher electricity cost compared to Germany. Given the assumption that the electrolysis operators are customers directly and actively participating in power markets, and based on the regulatory framework in the three countries, in this special case electricity cost in Germany is lowest. However, as electricity cost is profoundly influenced by political decisions as

  3. Net alkalinity and net acidity 1: Theoretical considerations

    International Nuclear Information System (INIS)

    Kirby, Carl S.; Cravotta, Charles A.

    2005-01-01

    Net acidity and net alkalinity are widely used, poorly defined, and commonly misunderstood parameters for the characterization of mine drainage. The authors explain theoretical expressions of 3 types of alkalinity (caustic, phenolphthalein, and total) and acidity (mineral, CO 2 , and total). Except for rarely-invoked negative alkalinity, theoretically defined total alkalinity is closely analogous to measured alkalinity and presents few practical interpretation problems. Theoretically defined 'CO 2 -acidity' is closely related to most standard titration methods with an endpoint pH of 8.3 used for determining acidity in mine drainage, but it is unfortunately named because CO 2 is intentionally driven off during titration of mine-drainage samples. Using the proton condition/mass-action approach and employing graphs to illustrate speciation with changes in pH, the authors explore the concept of principal components and how to assign acidity contributions to aqueous species commonly present in mine drainage. Acidity is defined in mine drainage based on aqueous speciation at the sample pH and on the capacity of these species to undergo hydrolysis to pH 8.3. Application of this definition shows that the computed acidity in mgL -1 as CaCO 3 (based on pH and analytical concentrations of dissolved Fe II , Fe III , Mn, and Al in mgL -1 ):acidity calculated =50{1000(10 -pH )+[2(Fe II )+3(Fe III )]/56+2(Mn) /55+3(Al)/27}underestimates contributions from HSO 4 - and H + , but overestimates the acidity due to Fe 3+ and Al 3+ . However, these errors tend to approximately cancel each other. It is demonstrated that 'net alkalinity' is a valid mathematical construction based on theoretical definitions of alkalinity and acidity. Further, it is shown that, for most mine-drainage solutions, a useful net alkalinity value can be derived from: (1) alkalinity and acidity values based on aqueous speciation (2) measured alkalinity minus calculated acidity, or (3) taking the negative of the

  4. Net alkalinity and net acidity 1: Theoretical considerations

    Science.gov (United States)

    Kirby, C.S.; Cravotta, C.A.

    2005-01-01

    Net acidity and net alkalinity are widely used, poorly defined, and commonly misunderstood parameters for the characterization of mine drainage. The authors explain theoretical expressions of 3 types of alkalinity (caustic, phenolphthalein, and total) and acidity (mineral, CO2, and total). Except for rarely-invoked negative alkalinity, theoretically defined total alkalinity is closely analogous to measured alkalinity and presents few practical interpretation problems. Theoretically defined "CO 2-acidity" is closely related to most standard titration methods with an endpoint pH of 8.3 used for determining acidity in mine drainage, but it is unfortunately named because CO2 is intentionally driven off during titration of mine-drainage samples. Using the proton condition/mass- action approach and employing graphs to illustrate speciation with changes in pH, the authors explore the concept of principal components and how to assign acidity contributions to aqueous species commonly present in mine drainage. Acidity is defined in mine drainage based on aqueous speciation at the sample pH and on the capacity of these species to undergo hydrolysis to pH 8.3. Application of this definition shows that the computed acidity in mg L -1 as CaCO3 (based on pH and analytical concentrations of dissolved FeII, FeIII, Mn, and Al in mg L -1):aciditycalculated=50{1000(10-pH)+[2(FeII)+3(FeIII)]/56+2(Mn)/ 55+3(Al)/27}underestimates contributions from HSO4- and H+, but overestimates the acidity due to Fe3+ and Al3+. However, these errors tend to approximately cancel each other. It is demonstrated that "net alkalinity" is a valid mathematical construction based on theoretical definitions of alkalinity and acidity. Further, it is shown that, for most mine-drainage solutions, a useful net alkalinity value can be derived from: (1) alkalinity and acidity values based on aqueous speciation, (2) measured alkalinity minus calculated acidity, or (3) taking the negative of the value obtained in a

  5. Processes determining the marine alkalinity and carbonate saturation distributions

    OpenAIRE

    B. R. Carter; J. R. Toggweiler; R. M. Key; J. L. Sarmiento

    2014-01-01

    We introduce a composite tracer, Alk*, that has a global distribution primarily determined by CaCO3 precipitation and dissolution. Alk* also highlights riverine alkalinity plumes that are due to dissolved calcium carbonate from land. We estimate the Arctic receives approximately twice the riverine alkalinity per unit area as the Atlantic, and 8 times that of the other oceans. Riverine inputs broadly elevate Alk* in the Arctic surface and particularly near ri...

  6. Block Copolymers for Alkaline Fuel Cell Membrane Materials

    Science.gov (United States)

    2014-07-30

    temperature fuel cells including proton exchange membrane fuel cell ( PEMFC ) and alkaline fuel cell (AFC) with operation temperature usually lower than 120...advantages over proton exchange membrane fuel cells ( PEMFCs ) resulting in the popularity of AFCs in the US space program.[8-11] The primary benefit AFC...offered over PEMFC is better electrochemical kinetics on the anode and cathode under the alkaline environment, which results in the ability to use

  7. Overexpression of Human Bone Alkaline Phosphatase in Pichia Pastoris

    Science.gov (United States)

    Karr, Laurel; Malone, Christine, C.; Rose, M. Franklin (Technical Monitor)

    2000-01-01

    The Pichiapastoris expression system was utilized to produce functionally active human bone alkaline phosphatase in gram quantities. Bone alkaline phosphatase is a key enzyme in bone formation and biomineralization, yet important questions about its structural chemistry and interactions with other cellular enzymes in mineralizing tissues remain unanswered. A soluble form of human bone alkaline phosphatase was constructed by deletion of the 25 amino acid hydrophobic C-terminal region of the encoding cDNA and inserted into the X-33 Pichiapastoris strain. An overexpression system was developed in shake flasks and converted to large-scale fermentation. Alkaline phosphatase was secreted into the medium to a level of 32mgAL when cultured in shake flasks. Enzyme activity was 12U/mg measured by a spectrophotometric assay. Fermentation yielded 880mgAL with enzymatic activity of 968U/mg. Gel electrophoresis analysis indicates that greater than 50% of the total protein in the fermentation is alkaline phosphatase. A purification scheme has been developed using ammonium sulfate precipitation followed by hydrophobic interaction chromatography. We are currently screening crystallization conditions of the purified recombinant protein for subsequent X-ray diffraction analyses. Structural data should provide additional information on the role of alkaline phosphatase in normal bone mineralization and in certain bone mineralization anomalies.

  8. Acid transformation of bauxite residue: Conversion of its alkaline characteristics.

    Science.gov (United States)

    Kong, Xiangfeng; Li, Meng; Xue, Shengguo; Hartley, William; Chen, Chengrong; Wu, Chuan; Li, Xiaofei; Li, Yiwei

    2017-02-15

    Bauxite residue (BR) is a highly alkaline solid hazardous waste produced from bauxite processing for alumina production. Alkaline transformation appears to reduce the environmental risk of bauxite residue disposal areas (BRDAs) whilst potentially providing opportunities for the sustainable reuse and on-going management of BR. Mineral acids, a novel citric acid and a hybrid combination of acid-gypsum treatments were investigated for their potential to reduce residue pH and total alkalinity and transform the alkaline mineral phase. XRD results revealed that with the exception of andradite, the primary alkaline solid phases of cancrinite, grossular and calcite were transformed into discriminative products based on the transformation used. Supernatants separated from BR and transformed bauxite residue (TBR) displayed distinct changes in soluble Na, Ca and Al, and a reduction in pH and total alkalinity. SEM images suggest that mineral acid transformations promote macro-aggregate formation, and the positive promotion of citric acid, confirming the removal or reduction in soluble and exchangeable Na. NEXAFS analysis of Na K-edge revealed that the chemical speciation of Na in TBRs was consistent with BR. Three acid treatments and gypsum combination had no effect on Na speciation, which affects the distribution of Na revealed by sodium STXM imaging. Copyright © 2016 Elsevier B.V. All rights reserved.

  9. Cation exchange properties of zeolites in hyper alkaline aqueous media.

    Science.gov (United States)

    Van Tendeloo, Leen; de Blochouse, Benny; Dom, Dirk; Vancluysen, Jacqueline; Snellings, Ruben; Martens, Johan A; Kirschhock, Christine E A; Maes, André; Breynaert, Eric

    2015-02-03

    Construction of multibarrier concrete based waste disposal sites and management of alkaline mine drainage water requires cation exchangers combining excellent sorption properties with a high stability and predictable performance in hyper alkaline media. Though highly selective organic cation exchange resins have been developed for most pollutants, they can serve as a growth medium for bacterial proliferation, impairing their long-term stability and introducing unpredictable parameters into the evolution of the system. Zeolites represent a family of inorganic cation exchangers, which naturally occur in hyper alkaline conditions and cannot serve as an electron donor or carbon source for microbial proliferation. Despite their successful application as industrial cation exchangers under near neutral conditions, their performance in hyper alkaline, saline water remains highly undocumented. Using Cs(+) as a benchmark element, this study aims to assess the long-term cation exchange performance of zeolites in concrete derived aqueous solutions. Comparison of their exchange properties in alkaline media with data obtained in near neutral solutions demonstrated that the cation exchange selectivity remains unaffected by the increased hydroxyl concentration; the cation exchange capacity did however show an unexpected increase in hyper alkaline media.

  10. Acidity and alkalinity in mine drainage: Theoretical considerations

    Science.gov (United States)

    Kirby, Carl S.; Cravotta,, Charles A.

    2004-01-01

    Acidity, net acidity, and net alkalinity are widely used parameters for the characterization of mine drainage, but these terms are not well defined and are often misunderstood. Incorrect interpretation of acidity, alkalinity, and derivative terms can lead to inadequate treatment design or poor regulatory decisions. We briefly explain derivations of theoretical expressions of three types of alkalinities (caustic, phenolphthalein, and total) and acidities (mineral, CO2, and total). Theoretically defined total alkalinity is closely analogous to measured alkalinity and presents few practical interpretation problems. Theoretically defined “CO2- acidity” is closely related to most standard titration methods used for mine drainage with an endpoint pH of 8.3, but it presents numerous interpretation problems, and it is unfortunately named because CO2 is intentionally driven off during titration of mine-drainage samples. Using the proton condition/massaction approach and employing graphs for visualization, we explore the concept of principal components and how to assign acidity contributions to solution species, including aqueous complexes, commonly found in mine drainage. We define a comprehensive theoretical definition of acidity in mine drainage on the basis of aqueous speciation at the sample pH and the capacity of these species to undergo hydrolysis to pH 8.3. This definition indicates the computed acidity in milligrams per liter (mg L-1 ) as CaCO3 (based on pH and analytical concentrations of dissolved FeIII , FeII , Mn, and Al in mg L-1 ): Aciditycomputed = 50. (10(3-pH) + 3.CFeIII/55.8 + 2.CFeII/55.8 + 2.CMn/54.9 + 3.CAl/27.0) underestimates contributions from HSO4 - and H+ , but overestimates the acidity due to Fe3+. These errors tend to approximately cancel each other. We demonstrate that “net alkalinity” is a valid mathematical construction based on theoretical definitions of alkalinity and acidity. We demonstrate that, for most mine-drainage solutions, a

  11. Antimicrobial Activity of Garcinia kola

    African Journals