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Sample records for alkali atom vapor

  1. Fabrication method for microscopic vapor cells for alkali atoms.

    Science.gov (United States)

    Baluktsian, T; Urban, C; Bublat, T; Giessen, H; Löw, R; Pfau, T

    2010-06-15

    A quantum network that consists of several components should ideally work on a single physical platform. Neutral alkali atoms have the potential to be very well suited for this purpose due to their electronic structure, which involves long-lived nuclear spins and very sensitive highly excited Rydberg states. In this Letter, we describe a fabrication method based on quartz glass to structure arbitrary shapes of microscopic vapor cells. We show that the usual spectroscopic properties known from macroscopic vapor cells are almost unaffected by the strong confinement.

  2. High quality anti-relaxation coating material for alkali atom vapor cells

    CERN Document Server

    Balabas, M V; Wasilewski, W; Krauter, H; Madsen, L S; Muller, J H; Fernholz, T; Polzik, E S

    2009-01-01

    We present an experimental investigation of alkali atom vapor cells coated with a high quality anti-relaxation coating material based on alkenes. The prepared cells with single compound alkene based coating showed the longest spin relaxation times which have been measured up to now with room temperature vapor cells. Suggestions are made that chemical binding of a cesium atom and an alkene molecule by attack to the C=C bond plays a crucial role in such improvement of anti-relaxation coating quality.

  3. (abstract) Fundamental Mechanisms of Electrode Kinetics and Alkali Metal Atom Transport at the Alkali Beta'-Alumina/Porous Electrode/Alkali Metal Vapor Three Phase Boundary

    Science.gov (United States)

    Williams, R. M.; Jeffries-Nakamura, B.; Ryan, M. A.; Underwood, M. L.; O'Connor, D.; Kisor, A.; Kikkert, S. K.

    1993-01-01

    The mechanisms of electrode kinetics and mass transport of alkali metal oxidation and alkali metal cation reduction at the solid electrolyte/porous electrode boundary as well as alkali metal transport through porous metal electrodes has important applications in optimizing device performance in alkali metal thermal to electric converter (AMTEC) cells which are high temperature, high current density electrochemical cells. Basic studies of these processes also affords the opportunity to investigate a very basic electrochemical reaction over a wide range of conditions; and a variety of mass transport modes at high temperatures via electrochemical techniques. The temperature range of these investigations covers 700K to 1240K; the alkali metal vapor pressures range from about 10(sup -2) to 10(sup 2) Pa; and electrodes studied have included Mo, W, Mo/Na(sub 2)MoO(sub 4), W/Na(sub 2)WO(sub 4), WPt(sub x), and WRh(sub x) (1.0 alkali metal vapor and alkali metal vapor/solid electrolyte/vapor cells have been used to characterize the reaction and transport processes. We have previously reported evidence of ionic, free molecular flow, and surface transport of sodium in several types of AMTEC electrodes.

  4. Positron-alkali atom scattering

    Science.gov (United States)

    Mceachran, R. P.; Horbatsch, M.; Stauffer, A. D.; Ward, S. J.

    1990-01-01

    Positron-alkali atom scattering was recently investigated both theoretically and experimentally in the energy range from a few eV up to 100 eV. On the theoretical side calculations of the integrated elastic and excitation cross sections as well as total cross sections for Li, Na and K were based upon either the close-coupling method or the modified Glauber approximation. These theoretical results are in good agreement with experimental measurements of the total cross section for both Na and K. Resonance structures were also found in the L = 0, 1 and 2 partial waves for positron scattering from the alkalis. The structure of these resonances appears to be quite complex and, as expected, they occur in conjunction with the atomic excitation thresholds. Currently both theoretical and experimental work is in progress on positron-Rb scattering in the same energy range.

  5. Light-induced changes in an alkali metal atomic vapor cell coating studied by X-ray photoelectron spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Hibberd, A. M.; Bernasek, S. L. [Department of Chemistry, Princeton University, Princeton, New Jersey 08544 (United States); Seltzer, S. J. [Department of Chemistry, University of California, Berkeley, California 94720 (United States); Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Balabas, M. V. [Department of Physics, Saint-Petersburg State University, St. Petersburg 198504 (Russian Federation); Morse, M. [Department of Materials Science Engineering, Boise State University, Boise, Idaho 83725 (United States); Budker, D. [Department of Physics, University of California, Berkeley, California 94720-7300 (United States); Nuclear Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

    2013-09-07

    The light-induced desorption of Rb atoms from a paraffin coating is studied with depth-profiling X-ray photoelectron spectroscopy (XPS) using tunable synchrotron radiation. Following Rb exposure, shifts of the C1s signal to higher binding energies, as well as the appearance of lower binding energy components in the O1s region, were observed. These effects were diminished after irradiation with desorbing light. Additionally, following desorbing-light irradiation, changes in the depth-dependent concentration of carbon were observed. These observations offer an insight into the microscopic changes that occur during light-induced atomic desorption and demonstrate the utility of XPS in understanding atom-coating interactions.

  6. High-Temperature Alkali Vapor Cells with Anti-Relaxation Surface Coatings

    CERN Document Server

    Seltzer, S J

    2009-01-01

    Anti-relaxation surface coatings allow long spin relaxation times in alkali-metal cells without buffer gas, enabling free motion of the alkali atoms and giving larger signals due to narrower optical linewidths. Effective coatings were previously unavailable for operation at temperatures above 80 C. We demonstrate that octadecyltrichlorosilane (OTS) can allow potassium or rubidium atoms to experience hundreds of collisions with the cell surface before depolarizing, and that an OTS coating remains effective up to about 170 C for both potassium and rubidium. We consider the experimental concerns of operating without buffer gas at high vapor density, studying the stricter need for effective quenching of excited atoms and deriving the optical rotation signal shape for atoms with resolved hyperfine structure in the spin-temperature regime. As an example of a high-temperature application of anti-relaxation coated alkali vapor cells, we operate a spin-exchange relaxation-free (SERF) atomic magnetometer with sensitivi...

  7. Atomic vapor spectroscopy in integrated photonic structures

    CERN Document Server

    Ritter, Ralf; Pernice, Wolfram; Kübler, Harald; Pfau, Tilman; Löw, Robert

    2015-01-01

    We investigate an integrated optical chip immersed in atomic vapor providing several waveguide geometries for spectroscopy applications. The narrow-band transmission through a silicon nitride waveguide and interferometer is altered when the guided light is coupled to a vapor of rubidium atoms via the evanescent tail of the waveguide mode. We use grating couplers to couple between the waveguide mode and the radiating wave, which allow for addressing arbitrary coupling positions on the chip surface. The evanescent atom-light interaction can be numerically simulated and shows excellent agreement with our experimental data. This work demonstrates a next step towards miniaturization and integration of alkali atom spectroscopy and provides a platform for further fundamental studies of complex waveguide structures.

  8. Coherent coupling of alkali atoms by random collisions.

    Science.gov (United States)

    Katz, Or; Peleg, Or; Firstenberg, Ofer

    2015-09-11

    Random spin-exchange collisions in warm alkali vapor cause rapid decoherence and act to equilibrate the spin state of the atoms in the vapor. In contrast, here we demonstrate experimentally and theoretically a coherent coupling of one alkali species to another species, mediated by these random collisions. We show that the minor species (potassium) inherits the magnetic properties of the dominant species (rubidium), including its lifetime (T_{1}), coherence time (T_{2}), gyromagnetic ratio, and spin-exchange relaxation-free magnetic-field threshold. We further show that this coupling can be completely controlled by varying the strength of the magnetic field. Finally, we explain these phenomena analytically by mode mixing of the two species via spin-exchange collisions.

  9. Measurement of background gas in paraffin-coated alkali vapor cells

    CERN Document Server

    Sekiguchi, Naota

    2015-01-01

    We measured the rate of velocity-changing collisions (VCCs) between alkali atoms and background gas in buffer-gas-free anti-spin-relaxation-coated cells. The average VCC rate in paraffin-coated rubidium vapor cells prepared in this work was $1 \\times 10^{6}$ s$^{-1}$, which corresponds to $\\sim$1 mm in the mean free path of rubidium atoms. This short mean free path indicates that alkali atoms do not travel freely between the cell walls. In addition, we found that a heating process known as "ripening" increases the VCC rate, and also confirmed that ripening improves the anti-relaxation performance of the coatings.

  10. Investigation of Anti-Relaxation Coatings for Alkali-Metal Vapor Cells Using Surface Science Techniques

    OpenAIRE

    Seltzer, S. J.; Michalak, D. J.; Donaldson, M. H.; Balabas, M. V.; Barber, S. K.; Bernasek, S. L.; Bouchiat, M. -A.; Hexemer, A.; Hibberd, A. M.; Kimball, D. F. Jackson; C. Jaye; Karaulanov, T.; Narducci, F. A.; Rangwala, S. A.; Robinson, H. G.

    2010-01-01

    Many technologies based on cells containing alkali-metal atomic vapor benefit from the use of anti-relaxation surface coatings in order to preserve atomic spin polarization. In particular, paraffin has been used for this purpose for several decades and has been demonstrated to allow an atom to experience up to 10,000 collisions with the walls of its container without depolarizing, but the details of its operation remain poorly understood. We apply modern surface and bulk techniques to the stu...

  11. Investigation of anti-Relaxation coatings for alkali-metal vapor cells using surface science techniques

    OpenAIRE

    Seltzer, S. J.

    2011-01-01

    Many technologies based on cells containing alkali-metal atomic vapor benefit from the use of antirelaxation surface coatings in order to preserve atomic spin polarization. In particular, paraffin has been used for this purpose for several decades and has been demonstrated to allow an atom to experience up to 10?000 collisions with the walls of its container without depolarizing, but the details of its operation remain poorly understood. We apply modern surface and bulk techniques to the stud...

  12. Positronium impact ionization of Alkali atoms

    CERN Document Server

    Ghosh, D

    2015-01-01

    Target ionization processes of alkali atoms by Positronium impact are investigated. Calculations are performed in the frame work of model potential formalism using the Coulomb distorted eikonal approximation. Interesting qualitative features are noted both in the scattered Ps and the ejected electron distributions in differential as well as double differential levels of the collision cross sections.

  13. Coherent coupling of alkali atoms by random collisions

    CERN Document Server

    Katz, Or; Firstenberg, Ofer

    2015-01-01

    Random spin-exchange collisions in warm alkali vapor cause rapid decoherence and act to equilibriate the spin state of the atoms. In contrast, here we demonstrate experimentally and theoretically a coherent coupling of one alkali specie to another specie, mediated by these random collisions. We show that, the minor specie (potassium) inherits the magnetic properties of the dominant specie (rubidium), including its lifetime (T1), coherence time (T2), gyromagnetic ratio, and SERF magnetic-field threshold. We further show that this coupling can be completely controlled by varying the strength of the magnetic field. Finally, we explain these phenomena analytically by modes-mixing of the two species via spin-exchange collisions.

  14. Microfabrication of MEMS alkali metal vapor cells for chip-scale atomic devices%芯片级原子器件MEMS碱金属蒸气腔室制作

    Institute of Scientific and Technical Information of China (English)

    尤政; 马波; 阮勇; 陈硕; 张高飞

    2013-01-01

    提出了基于两步低温阳极键合工艺的碱金属蒸气腔室制作方法,用于实现原子钟、原子磁力计及原子陀螺仪等器件的芯片级集成.由微机电系统(MEMS)体硅工艺制备了腔室结构.首先采用标准工艺将刻蚀有腔室的硅圆片与Pyrex玻璃阳极键合成预成型腔室,然后引入氮缓冲气体和由惰性石蜡包覆的微量碱金属铷或铯.通过两步阳极键合来密封腔室,键合温度低于石蜡燃点198℃.第一步键合预封装腔室,键合电压小于缓冲气体的击穿电压.第二步键合在大气氛围中进行,电压增至1 200 V来增强封装质量.通过高功率激光器局部加热释放碱金属,同时在腔壁上形成均匀的石蜡镀层以延长极化原子寿命.本文实现了160℃的低温阳极键合封装,键合率达到95%以上.封装的碱金属铷释放后仍具有金属光泽,实现的最小双腔室体积为6.5 mm×4.5 mm×2 mm.铷的吸收光谱表明铷有效地封装在腔室中,证明两步低温阳极键合工艺制作碱金属蒸气腔室是可行的.%This paper reported on the microfabrication of alkali metal vapor cells based on the two-step low temperature anodic bonding for the chip-scale integration of atomic clock,atomic magnetometer,atomic gyroscope and other atomic devices.Cell structures were fabricated by Micro-electromechanical System (MEMS) bulk silicon process,and the etched silicon with cells was firstly bonded to Pyrex glass to fabricate preformed chambers by the standard anodic bonding process.Then,nitrogen buffer gas and micro-scale alkali metal (rubidium or cesium) were introduced into the preformed cells.The two-step anodic bonding process was used to seal the cells at a temperature lower than the paraffin flash point (198 ℃).In the first step,bonding voltage was lower than the breakdown voltage of nitrogen buffer gas to pre-seal the cells.In the second step,the bonding was in air atmosphere,and the bonding voltage increased up to 1

  15. Investigation of Anti-Relaxation Coatings for Alkali-Metal Vapor Cells Using Surface Science Techniques

    CERN Document Server

    Seltzer, S J; Donaldson, M H; Balabas, M V; Barber, S K; Bernasek, S L; Bouchiat, M -A; Hexemer, A; Hibberd, A M; Kimball, D F Jackson; Jaye, C; Karaulanov, T; Narducci, F A; Rangwala, S A; Robinson, H G; Voronov, D L; Yashchuk, V V; Pines, A; Budker, D

    2010-01-01

    Many technologies based on cells containing alkali-metal atomic vapor benefit from the use of anti-relaxation surface coatings in order to preserve atomic spin polarization. In particular, paraffin has been used for this purpose for several decades and has been demonstrated to allow an atom to experience up to 10,000 collisions with the walls of its container without depolarizing, but the details of its operation remain poorly understood. We present a survey of modern surface science techniques applied to the study of paraffin coatings, in order to characterize the properties that enable the effective preservation of alkali spin polarization. These methods include Fourier transform infrared spectroscopy, differential scanning calorimetry, atomic force microscopy, near-edge X-ray absorption fine structure spectroscopy, and X-ray photoelectron spectroscopy. Experimental results include the determination that crystallinity of the coating material is unnecessary, and the detection of C=C double bonds present with...

  16. Ab Initio Molecular Dynamics of Dimerization and Clustering in Alkali Metal Vapors.

    Science.gov (United States)

    Chaban, Vitaly V; Prezhdo, Oleg V

    2016-06-30

    Alkali metals are known to form dimers, trimers, and tetramers in their vapors. The mechanism and regularities of this phenomenon characterize the chemical behavior of the first group elements. We report ab initio molecular dynamics (AIMD) simulations of the alkali metal vapors and characterize their structural properties, including radial distribution functions and atomic cluster size distributions. AIMD confirms formation of Men, where n ranges from 2 to 4. High pressure sharply favors larger structures, whereas high temperature decreases their fraction. Heavier alkali metals maintain somewhat larger fractions of Me2, Me3, and Me4, relative to isolated atoms. A single atom is the most frequently observed structure in vapors, irrespective of the element and temperature. Due to technical difficulties of working with high temperatures and pressures in experiments, AIMD is the most affordable method of research. It provides valuable understanding of the chemical behavior of Li, Na, K, Rb, and Cs, which can lead to development of new chemical reactions involving these metals.

  17. Molecular photons interfaced with alkali atoms.

    Science.gov (United States)

    Siyushev, Petr; Stein, Guilherme; Wrachtrup, Jörg; Gerhardt, Ilja

    2014-05-01

    Future quantum communication will rely on the integration of single-photon sources, quantum memories and systems with strong single-photon nonlinearities. Two key parameters are crucial for the single-photon source: a high photon flux with a very small bandwidth, and a spectral match to other components of the system. Atoms or ions may act as single-photon sources--owing to their narrowband emission and their intrinsic spectral match to other atomic systems--and can serve as quantum nonlinear elements. Unfortunately, their emission rates are still limited, even for highly efficient cavity designs. Single solid-state emitters such as single organic dye molecules are significantly brighter and allow for narrowband photons; they have shown potential in a variety of quantum optical experiments but have yet to be interfaced with other components such as stationary memory qubits. Here we describe the optical interaction between Fourier-limited photons from a single organic molecule and atomic alkali vapours, which can constitute an efficient quantum memory. Single-photon emission rates reach up to several hundred thousand counts per second and show a high spectral brightness of 30,000 detectable photons per second per megahertz of bandwidth. The molecular emission is robust and we demonstrate perfect tuning to the spectral transitions of the sodium D line and efficient filtering, even for emitters at ambient conditions. In addition, we achieve storage of molecular photons originating from a single dibenzanthanthrene molecule in atomic sodium vapour. Given the large set of molecular emission lines matching to atomic transitions, our results enable the combination of almost ideal single-photon sources with various atomic vapours, such that experiments with giant single-photon nonlinearities, mediated, for example, by Rydberg atoms, become feasible.

  18. Multi-photon processes in alkali metal vapors

    Science.gov (United States)

    Gai, Baodong; Hu, Shu; Li, Hui; Shi, Zhe; Cai, Xianglong; Guo, Jingwei; Tan, Yannan; Liu, Wanfa; Jin, Yuqi; Sang, Fengting

    2015-02-01

    Achieving population inversion through multi-photon cascade pumping is almost always difficult, and most laser medium work under 1-photon excitation mechanism. But for alkali atoms such as cesium, relatively large absorption cross sections of several low, cascading energy levels enable them properties such as up conversion. Here we carried out research on two-photon excitation alkali fluorescence. Two photons of near infrared region are used to excite alkali atoms to n 2 D5/2, n 2 D3/2 or higher energy levels, then the blue fluorescence of (n+1) 2 P3/2,(n+1) 2 P1/2-->n 2 S1/2 are observed. Different pumping paths are tried and by the recorded spectra, transition routes of cesium are deducted and concluded. Finally the possibility of two-photon style DPALs (diode pumped alkali laser) are discussed, such alkali lasers can give output wavelengths in the shorter end of visual spectroscopy (400-460 nm) and are expected to get application in underwater communication and material laser processing.

  19. Impurity detection in alkali-metal vapor cells via nuclear magnetic resonance

    Science.gov (United States)

    Patton, B.; Ishikawa, K.

    2016-11-01

    We use nuclear magnetic resonance spectroscopy of alkali metals sealed in glass vapor cells to perform in situ identification of chemical contaminants. The alkali Knight shift varies with the concentration of the impurity, which in turn varies with temperature as the alloy composition changes along the liquidus curve. Intentional addition of a known impurity validates this approach and reveals that sodium is often an intrinsic contaminant in cells filled with distilled, high-purity rubidium or cesium. Measurements of the Knight shift of the binary Rb-Na alloy confirm prior measurements of the shift's linear dependence on Na concentration, but similar measurements for the Cs-Na system demonstrate an unexpected nonlinear dependence of the Knight shift on the molar ratio. This non-destructive approach allows monitoring and quantification of ongoing chemical processes within the kind of vapor cells which form the basis for precise sensors and atomic frequency standards.

  20. Estimating the hydration enthalpies of neutral alkali metal atoms.

    Science.gov (United States)

    Stace, A J

    2006-10-26

    Using existing data on the ionization energies of alkali metal atoms in small clusters of water, a thermodynamic cycle is proposed from which the hydration enthalpies of the neutral metal atoms can be estimated. Where comparisons are possible, the results are in reasonable agreement with those obtained using both experimental and ab initio methods. Application of the thermodynamic cycle to neutral alkali metal atoms solvated in ammonia yields solvation enthalpies that are significantly lower than those obtained for water.

  1. Important role of alkali atoms in A4C60

    OpenAIRE

    Gunnarsson, O.; Erwin, S. C.; Koch, E.; Martin, R. M.

    1997-01-01

    We show that hopping via the alkali atoms plays an important role for the t1u band of A4C60 (A=K, Rb), in strong contrast to A3C60. Thus the t1u band is broadened by more than 40 % by the presence of the alkali atoms. The difference between A4C60 and A3C60 is in particular due to the less symmetric location of the alkali atoms in A4C60.

  2. High-Order Dispersion Coefficients for Alkali-metal Atoms

    Institute of Scientific and Technical Information of China (English)

    KANG Shuai; DING Chi-Kun; CHEN Chang-Yong; WU Xue-Qing

    2013-01-01

    High-order dispersion coefficients C9,C11,C12,and C13 for the ground-state alkali-metals were calculated by combining the l-dependent model potential of alkali-metal atoms and linear variation method based on B-spline basis functions.The results were compared.

  3. Hall Determination of Atomic Radii of Alkali Metals

    Science.gov (United States)

    Houari, Ahmed

    2008-01-01

    I will propose here an alternative method for determining atomic radii of alkali metals based on the Hall measurements of their free electron densities and the knowledge of their crystal structure. (Contains 2 figures.)

  4. Buffer gas-assisted four-wave mixing resonances in alkali vapor excited by a single cw laser

    Science.gov (United States)

    Shmavonyan, Svetlana; Khanbekyan, Aleksandr; Khanbekyan, Alen; Mariotti, Emilio; Papoyan, Aram V.

    2016-12-01

    We report the observation of a fluorescence peak appearing in dilute alkali (Rb, Cs) vapor in the presence of a buffer gas when the cw laser radiation frequency is tuned between the Doppler-broadened hyperfine transition groups of an atomic D2 line. Based on steep laser radiation intensity dependence above the threshold and spectral composition of the observed features corresponding to atomic resonance transitions, we have attributed these features to the buffer gas-assisted four-wave mixing process.

  5. Diffusion with chemical reaction: An attempt to explain number density anomalies in experiments involving alkali vapor

    Science.gov (United States)

    Snow, W. L.

    1974-01-01

    The mutual diffusion of two reacting gases is examined which takes place in a bath of inert gas atoms. Solutions are obtained between concentric spheres, each sphere acting as a source for one of the reactants. The calculational model is used to illustrate severe number density gradients observed in absorption experiments with alkali vapor. Severe gradients result when sq root k/D R is approximately 5 where k, D, and R are respectively the second order rate constant, the multicomponent diffusion constant, and the geometrical dimension of the experiment.

  6. Investigation of anti-Relaxation coatings for alkali-metal vapor cells using surface science techniques

    Energy Technology Data Exchange (ETDEWEB)

    Seltzer, S. J.; Michalak, D. J.; Donaldson, M. H.; Balabas, M. V.; Barber, S. K.; Bernasek, S. L.; Bouchiat, M.-A.; Hexemer, A.; Hibberd, A. M.; Jackson Kimball, D. F.; Jaye, C.; Karaulanov, T.; Narducci, F. A.; Rangwala, S. A.; Robinson, H. G.; Shmakov, A. K.; Voronov, D. L.; Yashchuk, V. V.; Pines, A.; Budker, D.

    2010-10-11

    Many technologies based on cells containing alkali-metal atomic vapor benefit from the use of antirelaxation surface coatings in order to preserve atomic spin polarization. In particular, paraffin has been used for this purpose for several decades and has been demonstrated to allow an atom to experience up to 10?000 collisions with the walls of its container without depolarizing, but the details of its operation remain poorly understood. We apply modern surface and bulk techniques to the study of paraffin coatings in order to characterize the properties that enable the effective preservation of alkali spin polarization. These methods include Fourier transform infrared spectroscopy, differential scanning calorimetry, atomic force microscopy, near-edge x-ray absorption fine structure spectroscopy, and x-ray photoelectron spectroscopy. We also compare the light-induced atomic desorption yields of several different paraffin materials. Experimental results include the determination that crystallinity of the coating material is unnecessary, and the detection of C=C double bonds present within a particular class of effective paraffin coatings. Further study should lead to the development of more robust paraffin antirelaxation coatings, as well as the design and synthesis of new classes of coating materials.

  7. Oscillation Frequencies for Simultaneous Trapping of Heteronuclear Alkali Atoms

    CERN Document Server

    Kaur, Kiranpreet; Arora, Bindiya

    2016-01-01

    We investigate oscillation frequencies for simultaneous trapping of more than one type of alkali atoms in a common optical lattice. For this purpose, we present numerical results for magic trapping conditions, where the oscillation frequencies for two different kind of alkali atoms using laser lights in the wavelength range 500-1200 nm are same. These wavelengths will be of immense interest for studying static and dynamic properties of boson-boson, boson-fermion, fermion-fermion, and boson-boson-boson mixtures involving different isotopes of Li, Na, K, Rb, Cs and Fr alkali atoms. In addition to this, we were also able to locate a magic wavelength around 808.1 nm where all the three Li, K, and Rb atoms are found to be suitable for oscillating at the same frequency in a common optical trap.

  8. The Structure and Thermodynamics of Alkali Halide Vapors.

    Science.gov (United States)

    Hartley, John George

    A comprehensive set of electron diffraction experiments were performed on 16 of the alkali halides in the vapor phase. A 40kev electron beam was scattered from the vapor effusing out of the nozzle of a temperature controlled gas cell. The resulting data were analyzed at the University of Edinburgh with the program ED80. This resulted in values for the bond lengths of monomers and the dimers, the bond angle of the dimers and the monomer-dimer ratios. In several cases, it was possible to further refine the data to obtain information on the mean amplitudes of vibration. As a check on the accuracy of the results, the monomer bond distances obtained by electron diffraction were compared to values obtained previously by microwave spectroscopy. The average monomer bond length r_{a} is corrected to obtain the equilibrium bond distance r_{e}. This value is then compared to the value of r_{e } obtained from microwave spectroscopy and found to be in excellent agreement. The bond lengths and angles of the dimers were compared against model calculations. While no one model was found to accurately predict the dimer structure parameters of all of the alkali halides, the Rittner model of Gowda et al was found to accurately predict the structure of six of the dimers. Thermodynamical calculations were performed on the model data which resulted in theoretical curves of the monomer-dimer ratios. Comparison of these curves with the experimental monomer-dimer ratio permits an evaluation of the model vibration frequencies. The enthalpy of formation of the dimer, Delta H_sp{2}{f}(298) is examined with regard to the size of the variation necessary to bring about agreement of the experimental and model monomer-dimer ratios.

  9. Pi resonance of chemisorbed alkali atoms on noble metals.

    Science.gov (United States)

    Borisov, A G; Sametoglu, V; Winkelmann, A; Kubo, A; Pontius, N; Zhao, J; Silkin, V M; Gauyacq, J P; Chulkov, E V; Echenique, P M; Petek, H

    2008-12-31

    We have performed a joint experimental and theoretical study of the unoccupied electronic structure of alkali adsorbates on the (111) surfaces of Cu and Ag. Combining angle- and time-resolved two-photon photoemission spectroscopy with wave packet propagation calculations we show that, along with the well known sigma resonance oriented along the surface normal, there exist long-lived alkali-localized resonances oriented parallel to the surface (pi symmetry). These new resonances are stabilized by the projected band gap of the substrate and emerge primarily from the mixing of the p and d Rydberg orbitals of the free alkali atom modified by the interaction with the surface.

  10. Diffusion of Rb atoms in paraffin - coated resonant vapor cells

    CERN Document Server

    Atutov, S N; Plekhanov, A I; Sorokin, V A; Yakovlev, A V

    2016-01-01

    We present the results of a study of the diffusion of Rb atoms in paraffin - coated resonant vapor cells. We have modeled the Rb diffusion both in the cell and in the coating, assuming that the main loss of Rb atoms is due to the physical absorption of the atoms by the glass substrate. It is demonstrated that the equilibrium atomic density in the cell is a monotonic function of the thickness of the paraffin coating: the density increases with an increase in the thickness of the coating. The diffusion coefficient for rubidium in paraffin thin films has been determined to be equal to 4,7*10^-7 cm^2/s. The results of the experiment might be useful for a better understanding of the details involved in the processes of the interaction of alkali atoms with a paraffin coating.

  11. Positronium-alkali atom scattering at medium energies

    Energy Technology Data Exchange (ETDEWEB)

    Chakraborty, Ajoy [Laban Hrad Vidyapith, AD-369, Salt Lake City, Kolkata 700 064 (India); Basu, Arindam [Department of Physics, Maheshtala College, Chandannagar, South 24 Parganas, Kolkata 700 140 (India); Sarkar, Nirmal K [Sodepur Chandrachur Vidyapith, 1, Desh Bandhu Nagar, Sodepur, 743 174 (India); Sinha, Prabal K [Department of Physics, Bangabasi College, 19, Raj Kumar Chakravorty Sarani, Kolkata 700 009 (India)

    2004-04-28

    We investigate the scattering of orthopositronium (o-Ps) atom off different atomic alkali targets (Na to Cs) at low and medium energies (up to 120 eV). Projectile-elastic and target-elastic close-coupling models have been employed to investigate the systems in addition to the static-exchange model. Elastic, excitation and total cross sections have been reported for all four systems. The magnitude of the alkali excitation cross section increases with increasing atomic number of the target atom while the position of the peak value shifts towards lower incident energies. The magnitudes of the Ps excitation and ionization cross sections increase steadily with atomic number with no change in the peak position. The reported results show regular behaviour with increasing atomic number of the target atom. Scattering parameters for the Ps-Rb and Ps-Cs systems are being reported for the first time.

  12. Near atomically smooth alkali antimonide photocathode thin films

    CERN Document Server

    Feng, Jun; Nasiatka, James; Schubert, Susanne; Smedley, John; Padmore, Howard

    2016-01-01

    Nano-roughness limits the emittance of electron beams that can be generated by high efficiency photocathodes, such as the thermally reacted alkali antimonide thin films. However there is an urgent need for photocathodes that can produce an order of magnitude or more lower emittance than present day systems in order to increase the transverse coherence width of the electron beam. In this paper we demonstrate a method for producing alkali antimonide cathodes with near atomic smoothness with high reproducibility.

  13. Wavelength diversity in optically pumped alkali vapor lasers

    Science.gov (United States)

    Perram, Glen P.

    2017-01-01

    Alternative wavelengths for optically pumped alkali vapor lasers have been developed using single photon excitation of higher lying P-states, stimulated Raman processes, two-photon excitation of S and D states, and electric quadruple excitation on S-D transitions. Two photon excitation of Cs 72D leads to competing and cascade lasing producing red and infrared lasers operating on the D-P transitions, followed by ultraviolet, blue, the standard near infrared DPAL transitions operating on P-S transitions. The S-D pump transitions are fully bleached at pump intensities exceeding 1 MW/cm2, allowing for lasing transitions that terminate on the ground state. The kinetics of these systems are complex due to competition for population inversion among the many optical transitions. An optically pumped mid-infrared rubidium pulsed, mirrorless laser has also been demonstrated in a heat pipe along both the 62P3/2 - 62S1/2 transition at 2.73 μm and the 62P1/2 - 62S1/2 transition at 2.79 μm with a maximum energy of 100 nJ. Performance improves dramatically as the rubidium vapor density is increased, in direct contradiction with the prior work. No scaling limitations associated with energy pooling or ionization kinetics have been observed. Practical application for infrared counter measures depends on the further development of blue diode pump sources. Finally, stimulated electronic Raman scattering and hyper-Raman processes in potassium vapor near the D1 and D2 lines have been observed using a stable resonator and pulsed laser excitation. First and second order Stokes and anti-Stokes lines were observed simultaneously and independently for a pump laser tuning range exceeding 70 cm-1. When the pump is tuned between the K D1 and D2 lines, an efficient hyper-Raman process dominates with a slope efficiency that exceeds 10%. Raman shifted laser may be useful as a target illuminator or atmospheric compensation beacon for a high power diode pumped alkali laser.

  14. Orbital Feshbach Resonance in Alkali-Earth Atoms.

    Science.gov (United States)

    Zhang, Ren; Cheng, Yanting; Zhai, Hui; Zhang, Peng

    2015-09-25

    For a mixture of alkali-earth atomic gas in the long-lived excited state ^{3}P_{0} and the ground state ^{1}S_{0}, in addition to nuclear spin, another "orbital" index is introduced to distinguish these two internal states. In this Letter we propose a mechanism to induce Feshbach resonance between two atoms with different orbital and nuclear spin quantum numbers. Two essential ingredients are the interorbital spin-exchange process and orbital dependence of the Landé g factors. Here the orbital degrees of freedom plays a similar role as the electron spin degree of freedom in magnetic Feshbach resonance in alkali-metal atoms. This resonance is particularly accessible for the ^{173}Yb system. The BCS-BEC crossover in this system requires two fermion pairing order parameters, and displays a significant difference compared to that in an alkali-metal system.

  15. Polarizabilities and hyperpolarizabilities of the alkali metal atoms

    Energy Technology Data Exchange (ETDEWEB)

    Fuentealba, P. (Chile Univ., Santiago (Chile). Departamento de Fisica and Centro de Mecanica Cuantica Aplicada (CMCA)); Reyes, O. (Chile Univ., Santiago (Chile). Dept. de Fisica)

    1993-08-14

    The electric static dipole polarizability [alpha], quadrupole polarizability C, dipole-quadrupole polarizability B, and the second dipole hyperpolarizability [gamma] have been calculated for the alkali metal atoms in the ground state. The results are based on a pseudopotential which is able to incorporate the very important core-valence correlation effect through a core polarization potential, and, in an empirical way, the main relativistic effects. The calculated properties compare very well with more elaborated calculations for the Li atom, excepting the second hyperpolarizability [gamma]. For the other atoms, there is neither theoretical nor experimental information about most of the higher polarizabilities. Hence, the results of this paper should be seen as a first attempt to give a complete account of the series expansion of the interaction energy of an alkali metal atom and a static electric field. (author).

  16. The Measuring Method of Atomic Polarization of Alkali Metal Vapor Based on Optical Rotation and the Analysis of the Influence Factors%基于光偏振旋转效应的碱金属气室原子极化率测量方法及影响因素分析

    Institute of Scientific and Technical Information of China (English)

    尚慧宁; 全伟; 陈瑶; 李洋; 李红

    2016-01-01

    利用原子自旋效应能够实现超高灵敏度的惯性和磁场测量.一类操控原子自旋处于无自旋交换弛豫态的器件可以进行物理参数测量.碱金属气室为该类器件的敏感表头.碱金属原子密度与原子极化率是碱金属气室的重要参数 ,对研究原子自旋处于无自旋交换弛豫态有着重要的作用.光的偏振效应在量子计算和原子物理研究中发挥了重要作用.利用光的偏振效应能够实现对碱金属原子密度与原子极化率的检测.提出一种基于光偏振旋转效应的碱金属原子极化率测量方法.首先对碱金属气室加恒定磁场 ,利用激光作为检测光 ,根据光偏振旋转原理 ,检测通过气室的偏振光的法拉第旋转角 ,得到碱金属气室原子密度.然后将碱金属原子抽运 ,利用激光作为检测光 ,检测通过气室的偏振光的偏转角 ,得到碱金属原子极化率.该方法在测量原子极化率的过程中也测量了碱金属原子密度 ,实现利用一套系统测量两个重要参数 ,具有快速测量和高灵敏度等特点 ,简化了实验设备及过程.对两种偏转角进行仿真分析 ,得到该方法实验时检测激光波长变化对偏转角的影响 ,根据仿真图得到检测激光波长的可取范围 ,验证了该方法的可行性.最后分析激光器波长波动与磁场波动对其测量精度的影响 ,提出实验对激光器与磁场的要求.%High sensitivity measurements of inertia and magnetic field could be achieved by utilizing a category of devices ,which manipulate the atomic spins in the spin-exchange-relaxation-free regime .The alkali cell which contains the alkali metal vapor is used to sense magnetic field and inertia .The atomic number density of alkali vapor and the polarization of alkali metal vapor are two of the most important parameters of the cell .They play an important role in the research on atomic spins in the spin-ex-change-relaxation-free regime .Besides

  17. Absence of neutral alkali atoms in rhodizite

    Science.gov (United States)

    Donnay, G.; Thorpe, A.N.; Senftle, F.E.; Sioda, R.

    1966-01-01

    The formula CsB12Be4Al4O28 has been proposed by others for the mineral rhodizite. Electron-spin-resonance and magnetic susceptibility measurements prove the absence of neutral cesium atoms. An ionic formula CsB11Be4Al4O 26(OH)2is proposed.

  18. Saturated vapor pressure above the amalgam of alkali metals in discharge lamps

    Science.gov (United States)

    Gavrish, S. V.

    2011-12-01

    A theoretical and numerical analysis of the evaporation process of two-component compounds in vapors of alkali metals in discharge lamps is presented. Based on the developed mathematical model of calculation of saturated vapor pressure of the metal above the amalgam, dependences of mass fractions of the components in the discharge volume on design parameters and thermophysical characteristics of the lamp are obtained.

  19. Scattering of positrons and electrons by alkali atoms

    Science.gov (United States)

    Stein, T. S.; Kauppila, W. E.; Kwan, C. K.; Lukaszew, R. A.; Parikh, S. P.; Wan, Y. J.; Zhou, S.; Dababneh, M. S.

    1990-01-01

    Absolute total scattering cross sections (Q sub T's) were measured for positrons and electrons colliding with sodium, potassium, and rubidium in the 1 to 102 eV range, using the same apparatus and experimental approach (a beam transmission technique) for both projectiles. The present results for positron-sodium and -rubidium collisions represent the first Q sub T measurements reported for these collision systems. Features which distinguish the present comparisons between positron- and electron-alkali atom Q sub T's from those for other atoms and molecules (room-temperature gases) which have been used as targets for positrons and electrons are the proximity of the corresponding positron- and electron-alkali atom Q sub T's over the entire energy range of overlap, with an indication of a merging or near-merging of the corresponding positron and electron Q sub T's near (and above) the relatively low energy of about 40 eV, and a general tendency for the positron-alkali atom Q sub T's to be higher than the corresponding electron values as the projectile energy is decreased below about 40 eV.

  20. Atom Interferometry in a Warm Vapor

    CERN Document Server

    Biedermann, G W; Rakholia, A V; Jau, Y -Y; Wheeler, D R; Sterk, J D; Burns, G R

    2016-01-01

    We demonstrate matterwave interference in a warm vapor of rubidium atoms. Established approaches to light pulse atom interferometry rely on laser cooling to concentrate a large ensemble of atoms into a velocity class resonant with the atom optical light pulse. In our experiment, we show that clear interference signals may be obtained without laser cooling. This effect relies on the Doppler selectivity of the atom interferometer resonance. This interferometer may be configured to measure accelerations, and we demonstrate that multiple interferometers may be operated simultaneously by addressing multiple velocity classes.

  1. Desorption of alkali atoms from 4He nanodroplets.

    Science.gov (United States)

    Hernando, Alberto; Barranco, Manuel; Pi, Martí; Loginov, Evgeniy; Langlet, Marina; Drabbels, Marcel

    2012-03-21

    The dynamics following the photoexcitation of Na and Li atoms located on the surface of helium nanodroplets has been investigated in a joint experimental and theoretical study. Photoelectron spectroscopy has revealed that excitation of the alkali atoms via the (n + 1)s ←ns transition leads to the desorption of these atoms. The mean kinetic energy of the desorbed atoms, as determined by ion imaging, shows a linear dependence on excitation frequency. These experimental findings are analyzed within a three-dimensional, time-dependent density functional approach for the helium droplet combined with a Bohmian dynamics description of the desorbing atom. This hybrid method reproduces well the key experimental observables. The dependence of the observables on the impurity mass is discussed by comparing the results obtained for the (6)Li and (7)Li isotopes. The calculations show that the desorption of the excited alkali atom is accompanied by the creation of highly non-linear density waves in the helium droplet that propagate at supersonic velocities.

  2. A heated vapor cell unit for dichroic atomic vapor laser lock in atomic rubidium.

    Science.gov (United States)

    McCarron, Daniel J; Hughes, Ifan G; Tierney, Patrick; Cornish, Simon L

    2007-09-01

    The design and performance of a compact heated vapor cell unit for realizing a dichroic atomic vapor laser lock (DAVLL) for the D(2) transitions in atomic rubidium is described. A 5 cm long vapor cell is placed in a double-solenoid arrangement to produce the required magnetic field; the heat from the solenoid is used to increase the vapor pressure and correspondingly the DAVLL signal. We have characterized experimentally the dependence of important features of the DAVLL signal on magnetic field and cell temperature. For the weaker transitions both the amplitude and gradient of the signal are increased by an order of magnitude.

  3. Faraday effect in alkali-metal vapors in a strong bichromatic field of laser light

    Science.gov (United States)

    Karagodova, T. Ya.; Kuptsova, A. V.

    2002-04-01

    Results of a numerical study of the Faraday effect arising upon propagation of the light beams with the frequencies ω L1 (resonant to the nS 1/2- nP 1/2, 3/2 transitions) and ω L2 (resonant to the nP 1/2, 3/2-( n+2) S 1/2 transitions) through alkali-metal vapors are presented. Characteristics of the magneto-optical rotation spectra at each of the frequencies are strongly affected by the second intense radiation field resonant to the adjacent transition. When the atoms interact with two strong light waves, resonant to adjacent transitions, and with a magnetic field, the shape of the Faraday rotation spectra depends on the energy shifts of the atomic states that arise due to the dynamic Stark effect and the Zeeman effect (the Paschen-Back or an intermediate-type effect), as well as due to the difference of populations of these states caused by the interaction of the atoms with the fields. The results obtained show that in the frequency selection method, based on the resonance Faraday effect, the frequency of the generated narrow-band beam can be tuned by the intensity of the strong wave, resonant to the transition between the excited states.

  4. PYRAMIDAL-HOLLOW-BEAM DIPOLE TRAP FOR ALKALI ATOMS

    Institute of Scientific and Technical Information of China (English)

    YIN JIAN-PING; GAO WEI-JIAN; WANG YU-ZHU; ZHU YI-FU; WANG YI-QIU

    2000-01-01

    We propose a dark gravito-optical dipole trap, for alkali atoms, consisting of a blue-detuned, pyramidal-hollow laser beam propagating upward and the gravity field. When cold atoms from a magneto-optical trap are loaded into the pyramidal-hollow beam and bounce inside the pyramidal-hollow beam, they experience efficient Sisyphus cooling and geometric cooling induced by the pyramidal-hollow beam and the weak repumping beam propagating downward. Our study shows that an ultracold and dense atomic sample with an equilibrium 3D momentum of ~ 3hk and an atomic density above the point of Bose-Einstein condensation may be obtained in this pure optical trap.

  5. Electron densities and alkali atoms in exoplanet atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Lavvas, P. [GSMA, Université de Reims Champagne Ardenne, CNRS UMR 7331, Reims, 51687 France (France); Koskinen, T.; Yelle, R. V., E-mail: panayotis.lavvas@univ-reims.fr [Lunar and Planetary Laboratory, University of Arizona, Tucson, AZ 85719 (United States)

    2014-11-20

    We describe a detailed study on the properties of alkali atoms in extrasolar giant planets, and specifically focus on their role in generating the atmospheric free electron densities, as well as their impact on the transit depth observations. We focus our study on the case of HD 209458b, and we show that photoionization produces a large electron density in the middle atmosphere that is about two orders of magnitude larger than the density anticipated from thermal ionization. Our purely photochemical calculations, though, result in a much larger transit depth for K than observed for this planet. This result does not change even if the roles of molecular chemistry and excited state chemistry are considered for the alkali atoms. In contrast, the model results for the case of exoplanet XO-2b are in good agreement with the available observations. Given these results we discuss other possible scenarios, such as changes in the elemental abundances, changes in the temperature profiles, and the possible presence of clouds, which could potentially explain the observed HD 209458b alkali properties. We find that most of these scenarios cannot explain the observations, with the exception of a heterogeneous source (i.e., clouds or aerosols) under specific conditions, but we also note the discrepancies among the available observations.

  6. Atomic lithium vapor laser isotope separation

    CERN Document Server

    Olivares, I E

    2002-01-01

    An atomic vapor laser isotope separation in lithium was performed using tunable diode lasers. The method permits also the separation of the isotopes between the sup 6 LiD sub 2 and the sup 7 LiD sub 1 lines using a self-made mass separator which includes a magnetic sector and an ion beam designed for lithium. (Author)

  7. Penetration of alkali atoms throughout a graphene membrane: theoretical modeling.

    Science.gov (United States)

    Boukhvalov, D W; Virojanadara, C

    2012-03-07

    Theoretical studies of penetration of various alkali atoms (Li, Na, Rb, Cs) throughout a graphene membrane grown on a silicon carbide substrate are reported and compared with recent experimental results. Results of first principles modeling demonstrate a rather low (about 0.8 eV) energy barrier for the formation of temporary defects in the carbon layer required for the penetration of Li at a high concentration of adatoms, a higher (about 2 eV) barrier for Na, and barriers above 4 eV for Rb and Cs. Experiments prove migration of lithium adatoms from the graphene surface to the buffer layer and SiC substrate at room temperature, sodium at 100 °C and impenetrability of the graphene membrane for Rb and Cs. Differences between epitaxial and free-standing graphene for the penetration of alkali ions are also discussed.

  8. Dispersion coefficients for the interaction of inert gas atoms with alkali and alkaline earth ions and alkali atoms with their singly ionized ions

    CERN Document Server

    Singh, Sukhjit; Sahoo, B K; Arora, Bindiya

    2016-01-01

    We report the dispersion coefficients for the interacting inert gas atoms with the alkali ions, alkaline earth ions and alkali atoms with their singly charged ions. We use our relativistic coupled-cluster method to determine dynamic dipole and quadrupole polarizabilities of the alkali atoms and singly ionized alkaline earth atoms, whereas a relativistic random phase approximation approach has been adopted to evaluate these quantities for the closed-shell configured inert gas atoms and the singly and doubly ionized alkali and alkaline earth atoms, respectively. Accuracies of these results are adjudged from the comparison of their static polarizability values with their respective experimental results. These polarizabilities are further compared with the other theoretical results. Reason for the improvement in the accuracies of our estimated dispersion coefficients than the data listed in [At. Data and Nucl. Data Tables 101, 58 (2015)] are discussed. Results for some of the atom-ion interacting systems were not...

  9. Atomic forces between noble gas atoms, alkali ions, and halogen ions for surface interactions

    Science.gov (United States)

    Wilson, J. W.; Outlaw, R. A.; Heinbockel, J. H.

    1988-01-01

    The components of the physical forces between noble gas atoms, alkali ions, and halogen ions are analyzed and a data base developed from analysis of the two-body potential data, the alkali-halide molecular data, and the noble gas crystal and salt crystal data. A satisfactory global fit to this molecular and crystal data is then reproduced by the model to within several percent. Surface potentials are evaluated for noble gas atoms on noble gas surfaces and salt crystal surfaces with surface tension neglected. Within this context, the noble gas surface potentials on noble gas and salt crystals are considered to be accurate to within several percent.

  10. Electric dipole polarizabilities of Rydberg states of alkali atoms

    CERN Document Server

    Yerokhin, V A; Fritzsche, S; Surzhykov, A

    2016-01-01

    Calculations of the static electric-dipole scalar and tensor polarizabilities are presented for two alkali atoms, Rb and Cs, for the $nS$, $nP_{1/2, 3/2}$, and $nD_{3/2, 5/2}$ states with large principal quantum numbers up to $n = 50$. The calculations are performed within an effective one-electron approximation, based on the Dirac-Fock Hamiltonian with a semi-empirical core-polarization potential. The obtained results are compared with those from a simpler semi-empirical approach and with available experimental data.

  11. Diffusion of Rb atoms in paraffin-coated resonant vapor cells

    Science.gov (United States)

    Atutov, Sergey N.; Benimetskiy, Fedor A.; Plekhanov, Alexander I.; Sorokin, Vladimir A.; Yakovlev, Alexander V.

    2017-01-01

    We present the results of a study of the diffusion of Rb atoms in paraffin-coated resonant vapor cells. We have modeled the Rb diffusion both in the cell and in the coating, assuming that the main loss of Rb atoms is due to the physical absorption of the atoms by the glass substrate. It is demonstrated that the equilibrium of atomic density in the cell is a monotonic function of the thickness of the paraffin coating: the density increases with an increase in the thickness of the coating. The diffusion coefficient for rubidium in paraffin thin films has been determined to be equal to 5 × 10-7 cm2/s. The results of the experiment might provide for a better understanding of the processes involved in the interaction of alkali atoms with a paraffin coating and atomic diffusion in resonant vapor cells.

  12. Interactions and low energy collisions between an alkali ion and an alkali atom of different nucleus

    CERN Document Server

    Rakshit, Arpita; Berriche, Hamid; Deb, Bimalendu

    2015-01-01

    We study theoretically interaction potentials and low energy collisions between different alkali atoms and alkali ions. Specifically, we consider systems like X + Y$^{+}$, where X(Y$^{+})$ is either Li(Cs$^+$) or Cs((Li$^+$), Na(Cs$^+$) or Cs(Na$^+$) and Li(Rb$^+$) or Rb(Li$^+$). We calculate the molecular potentials of the ground and first two excited states of these three systems using pseudopotential method and compare our results with those obtained by others. We calculate ground-state scattering wave functions and cross sections of these systems for a wide range of energies. We find that, in order to get convergent results for the total scattering cross sections for energies of the order $1$ K, one needs to take into account at least 60 partial waves. In the low energy limit ($< 1 \\mu$K), elastic scattering cross sections exhibit Wigner law threshold behavior while in the high energy limit the cross sections go as $E^{-1/3}$. We discuss qualitatively the possibilities of forming cold molecular ion by ...

  13. Atomic mercury vapor inside a hollow-core photonic crystal fiber

    CERN Document Server

    Vogl, Ulrich; Joly, Nicolas Y; Russell, Philip St J; Marquardt, Christoph; Leuchs, Gerd

    2014-01-01

    We demonstrate high atomic mercury vapor pressure in a kagom\\'e-style hollow-core photonic crystal fiber at room temperature. After a few days of exposure to mercury vapor the fiber is homogeneously filled and the optical depth achieved remains constant. With incoherent optical pumping from the ground state we achieve an optical depth of 114 at the $6^3P_2 - 6^3D_3$ transition, corresponding to an atomic mercury number density of $6 \\times 10^{10}$ cm$^{-3}$. The use of mercury vapor in quasi one-dimensional confinement may be advantageous compared to chemically more active alkali vapor, while offering strong optical nonlinearities in the ultraviolet region of the optical spectrum.

  14. Optical phase conjugation in atomic beams and vapors

    Science.gov (United States)

    Donoghue, John James

    1997-07-01

    Optical phase conjugation in atomic beams and vapors using alkali metal atoms as the nonlinear medium is examined. The significance of the sodium system is that the nonlinear gain is high due to the hyperfine system, which behaves as a Raman system. The gains observed were larger than 100 in cases involving two separate pump lasers. The gain is also seen to be more complicated than a Raman system. The frequency of the beams is examined for three separate configurations. We examine a self pumped configuration, an externally pumped configuration consisting of two pump lasers and a probe, and a ring configuration. The observed gain in a self pumped configuration is a result of a mixture of a three level Mollow type gain and a Raman gain. The initial cavity laser is a result of the Mollow gain, and the conjugate produced is seen to arise from the interaction of the cavity beams with the initial pump beam to produce the conjugate. In the externally pumped scheme, the gain is due to Coherent Population Trapping (CPT) in a double-Λ Raman system. There is an equilibrium that is obtained that is responsible for the high gains observed in this particular setup. The bandwidth of the ground state two photon induced coherence is less than the natural lifetime, indicating CPT as the gain mechanism. In the ring configuration, we observed two separate gains. There is a forward and a backward gain. These two oscillations occur together for a 430 MHZ bandwidth which coincides with the observed width of the phase conjugate oscillation. The design of our vapor cells is discussed in depth. The heat pipe configuration, necessary to successfully conduct these experiments is shown in detail. The design of our atomic beams is also discussed.

  15. Spectroscopic properties of alkali atoms embedded in Ar matrix.

    Science.gov (United States)

    Jacquet, E; Zanuttini, D; Douady, J; Giglio, E; Gervais, B

    2011-11-07

    We present a theoretical investigation of visible absorption and related luminescence of alkali atoms (Li, Na, and K) embedded in Ar matrix. We used a model based on core polarization pseudopotentials, which allows us to determine accurately the gas-to-matrix shifts of various trapping sites. The remarkable agreement between our calculated results and the experimental spectra recorded by several authors allows us to establish a clear assignment of the observed spectra, which are made of contributions from crystalline sites on the one hand, and of grain boundary sites on the other hand. Our study reveals remarkably large Stokes shifts, up to 9000 cm(-1), which could be observed experimentally to identify definitely the trapping sites.

  16. Study of Rb - vapor coated cell; atomic diffusion and cell curing process

    CERN Document Server

    Atutov, S N; Plekhanov, A I; Sorokin, V A

    2015-01-01

    We present the results of the study of an optical resonant cell filled by a vapor of the Rb atoms and coated with a non-stick polydimethylsiloxane (PDMS) polymer. We show that it is possible to define correctly the diffusion coefficient of the atoms in the coating, using geometric parameters of the cell and the vapor density in the cell volume only. The dependence of the diffusion coefficient on the cell curing time is presented. It is shown that the mysterious cell curing process can be explained in terms of the polymerization of the polymer coating by alkali atoms. Anomalous long dwell time of the Rb atoms on the PDMS coating is discussed as well.

  17. "Textbook" adsorption at "nontextbook" adsorption sites: Halogen atoms on alkali halide surfaces

    OpenAIRE

    Li, B.; Michaelides, A.; Scheffler, M.

    2006-01-01

    Density-functional theory (DFT) and second order Møller-Plesset perturbation theory calculations indicate that halogen atoms bond preferentially to halide substrate atoms on a series of alkali halide surfaces, rather than to the alkali atoms as might be anticipated. An analysis of the electronic structures in each system reveals that this novel adsorption mode is stabilized by the formation of textbook two-center three-electron covalent bonds. The implications of these findings to, for exampl...

  18. Spin Noise Exchange in Coupled Alkali-Metal Vapors

    CERN Document Server

    Dellis, A T; Kominis, I K

    2013-01-01

    The physics of spin exchange collisions has fueled a large number of discoveries in fundamental physics, chemistry and biology, and has led to several applications in medical imaging and nuclear magnetic resonance. We here report on the experimental observation and theoretical justification of a novel effect, the transfer of spin noise from one atomic species to another, through the mechanism of spin exchange. Essentially, we extend the foundational studies of spin exchange into the deeper layer of quantum fluctuations. The signature of spin noise exchange is an increase of the total spin noise power at low magnetic fields where the two-species spin noise resonances overlap.

  19. Experimental and Theoretical Studies of Pressure Broadened Alkali-Metal Atom Resonance Lines

    Science.gov (United States)

    Shindo, F.; Zhu, C.; Kirby, K.; Babb, J. F.

    2006-01-01

    We are carrying out a joint theoretical and experimental research program to study the broadening of alkali atom resonance lines due to collisions with helium and molecular hydrogen for applications to spectroscopic studies of brown dwarfs and extrasolar giant planets.

  20. Analysis of the physical atomic forces between noble gas atoms, alkali ions and halogen ions

    Science.gov (United States)

    Wilson, J. W.; Heinbockel, J. H.; Outlaw, R. A.

    1986-01-01

    The physical forces between atoms and molecules are important in a number of processes of practical importance, including line broadening in radiative processes, gas and crystal properties, adhesion, and thin films. The components of the physical forces between noble gas atoms, alkali ions, and halogen ions are analyzed and a data base for the dispersion forces is developed from the literature based on evaluations with the harmonic oscillator dispersion model for higher order coefficients. The Zener model of the repulsive core is used in the context of the recent asymptotic wave functions of Handler and Smith; and an effective ionization potential within the Handler and Smith wave functions is defined to analyze the two body potential data of Waldman and Gordon, the alkali-halide molecular data, and the noble gas crystal and salt crystal data. A satisfactory global fit to this molecular and crystal data is then reproduced by the model to within several percent. Surface potentials are evaluated for noble gas atoms on noble gas and salt crystal surfaces with surface tension neglected. Within this context, the noble gas surface potentials on noble gas and salt crystals are considered to be accurate to within several percent.

  1. Sub-Shot-Noise Magnetometry with a Correlated Spin-Relaxation Dominated Alkali-Metal Vapor

    OpenAIRE

    Kominis, I. K.

    2007-01-01

    Spin noise sets fundamental limits to the precision of measurements using spin-polarized atomic vapors, such as performed with sensitive atomic magnetometers. Spin squeezing offers the possibility to extend the measurement precision beyond the standard quantum limit of uncorrelated atoms. Contrary to the current understanding, we show that even in the presence of spin relaxation, spin squeezing can lead to a significant reduction of spin noise, and hence an increase in magnetometric sensitivi...

  2. Refined potentials for rare gas atom adsorption on rare gas and alkali-halide surfaces

    Science.gov (United States)

    Wilson, J. W.; Heinbockel, J. H.; Outlaw, R. A.

    1985-01-01

    The utilization of models of interatomic potential for physical interaction to estimate the long range attractive potential for rare gases and ions is discussed. The long range attractive force is calculated in terms of the atomic dispersion properties. A data base of atomic dispersion parameters for rare gas atoms, alkali ion, and halogen ions is applied to the study of the repulsive core; the procedure for evaluating the repulsive core of ion interactions is described. The interaction of rare gas atoms on ideal rare gas solid and alkali-halide surfaces is analyzed; zero coverage absorption potentials are derived.

  3. A heated vapor cell unit for DAVLL in atomic rubidium

    OpenAIRE

    McCarron, Daniel J.; Hughes, Ifan G.; Tierney, Patrick; Cornish, Simon L

    2007-01-01

    The design and performance of a compact heated vapor cell unit for realizing a dichroic atomic vapor laser lock (DAVLL) for the D2 transitions in atomic rubidium is described. A 5 cm-long vapor cell is placed in a double-solenoid arrangement to produce the required magnetic field; the heat from the solenoid is used to increase the vapor pressure and correspondingly the DAVLL signal. We have characterized experimentally the dependence of important features of the DAVLL signal on magnetic field...

  4. Alkali-vapor cell with metal coated windows for efficient application of an electric field

    Science.gov (United States)

    Sarkisyan, D.; Sarkisyan, A. S.; Guéna, J.; Lintz, M.; Bouchiat, M.-A.

    2005-05-01

    We describe the implementation of a cylindrical T-shaped alkali-vapor cell for laser spectroscopy in the presence of a longitudinal electric field. The two windows are used as two electrodes of the high-voltage assembly, which is made possible by a metallic coating which entirely covers the inner and outer sides of the windows except for a central area to let the laser beams in and out of the cell. This allows very efficient application of the electric field, up to 2kV/cm in a rather dense superheated vapor, even when significant photoemission takes place at the windows during pulsed laser irradiation. The body of the cell is made of sapphire or alumina ceramic to prevent large currents resulting from surface conduction observed in cesiated glass cells. The technique used to attach the monocrystalline sapphire windows to the cell body causes minimal stress birefringence in the windows. In addition, reflection losses at the windows can be made very small. The vapor cell operates with no buffer gas and has no magnetic part. The use of this kind of cell has resulted in an improvement of the signal-to-noise ratio in the measurement of parity violation in cesium vapor underway at ENS, Paris. The technique can be applied to other situations where a brazed assembly would give rise to unacceptably large birefringence in the windows.

  5. "Textbook" adsorption at "nontextbook" adsorption sites: halogen atoms on alkali halide surfaces.

    Science.gov (United States)

    Li, Bo; Michaelides, Angelos; Scheffler, Matthias

    2006-07-28

    Density-functional theory and second order Møller-Plesset perturbation theory calculations indicate that halogen atoms bond preferentially to halide substrate atoms on a series of alkali halide surfaces, rather than to the alkali atoms as might be anticipated. An analysis of the electronic structures in each system reveals that this novel adsorption mode is stabilized by the formation of textbook two-center three-electron covalent bonds. The implications of these findings to, for example, nanostructure crystal growth, are briefly discussed.

  6. Investigation of odd-order nonlinear susceptibilities in atomic vapors

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Yaqi [Key Laboratory for Physical Electronics and Devices of the Ministry of Education, Xi’an Jiaotong University, Xi’an 710049 (China); Shaanxi Key Laboratory of Information Photonic Technique, Xi’an Jiaotong University, Xi’an 710049 (China); Teaching and Research Section of Maths and Physics, Guangzhou Commanding Academy of Chinese People’s Armed Police Force, Guangzhou, 510440 (China); Wu, Zhenkun; Si, Jinhai; Yan, Lihe; Zhang, Yiqi; Yuan, Chenzhi; Sun, Jia [Key Laboratory for Physical Electronics and Devices of the Ministry of Education, Xi’an Jiaotong University, Xi’an 710049 (China); Shaanxi Key Laboratory of Information Photonic Technique, Xi’an Jiaotong University, Xi’an 710049 (China); Zhang, Yanpeng, E-mail: ypzhang@mail.xjtu.edu.cn [Key Laboratory for Physical Electronics and Devices of the Ministry of Education, Xi’an Jiaotong University, Xi’an 710049 (China); Shaanxi Key Laboratory of Information Photonic Technique, Xi’an Jiaotong University, Xi’an 710049 (China)

    2013-06-15

    We theoretically deduce the macroscopic symmetry constraints for arbitrary odd-order nonlinear susceptibilities in homogeneous media including atomic vapors for the first time. After theoretically calculating the expressions using a semiclassical method, we demonstrate that the expressions for third- and fifth-order nonlinear susceptibilities for undressed and dressed four- and six-wave mixing (FWM and SWM) in atomic vapors satisfy the macroscopic symmetry constraints. We experimentally demonstrate consistence between the macroscopic symmetry constraints and the semiclassical expressions for atomic vapors by observing polarization control of FWM and SWM processes. The experimental results are in reasonable agreement with our theoretical calculations. -- Highlights: •The macroscopic symmetry constraints are deduced for homogeneous media including atomic vapors. •We demonstrate that odd-order nonlinear susceptibilities satisfy the constraints. •We experimentally demonstrate the deduction in part.

  7. Cold three-body collisions in hydrogen-hydrogen-alkali atomic system

    CERN Document Server

    Wang, Yujun; Esry, B D

    2010-01-01

    We have studied hydrogen-hydrogen-alkali three-body systems in the adiabatic hyperspherical representation. For the spin-stretched case, there exists a single $X$H molecular state when $X$ is one of the bosonic alkali atoms: $^7$Li, $^{23}$Na, $^{39}$K, $^{87}$Rb and $^{133}$Cs. As a result, the {\\em only} recombination process is the one that leads to formation of $X$H molecules, H+H+$X

  8. Communication: angular momentum alignment and fluorescence polarization of alkali atoms photodetached from helium nanodroplets.

    Science.gov (United States)

    Hernando, Alberto; Beswick, J Alberto; Halberstadt, Nadine

    2013-12-14

    The theory of photofragments angular momentum polarization is applied to the photodetachment of an electronically excited alkali atom from a helium nanocluster (N = 200). The alignment of the electronic angular momentum of the bare excited alkali atoms produced is calculated quantum mechanically by solving the excited states coupled equations with potentials determined by density functional theory (DFT). Pronounced oscillations as a function of excitation energy are predicted for the case of Na@(He)200, in marked contrast with the absorption cross-section and angular distribution of the ejected atoms which are smooth functions of the energy. These oscillations are due to quantum interference between different coherently excited photodetachment pathways. Experimentally, these oscillations should be reflected in the fluorescence polarization and polarization-resolved photoelectron yield of the ejected atoms, which are proportional to the electronic angular momentum alignment. In addition, this result is much more general than the test case of NaHe200 studied here. It should be observable for larger droplets, for higher excited electronic states, and for other alkali as well as for alkali-earth atoms. Detection of these oscillations would show that the widely used pseudo-diatomic model can be valid beyond the prediction of absorption spectra and could help in interpreting parts of the dynamics, as already hinted by some experimental results on angular anisotropy of bare alkali fragments.

  9. Communication: Angular momentum alignment and fluorescence polarization of alkali atoms photodetached from helium nanodroplets

    Energy Technology Data Exchange (ETDEWEB)

    Hernando, Alberto; Beswick, J. Alberto; Halberstadt, Nadine [LCAR-IRSAMC, Université Toulouse 3 - Paul Sabatier and CNRS, 31062 Toulouse (France)

    2013-12-14

    The theory of photofragments angular momentum polarization is applied to the photodetachment of an electronically excited alkali atom from a helium nanocluster (N = 200). The alignment of the electronic angular momentum of the bare excited alkali atoms produced is calculated quantum mechanically by solving the excited states coupled equations with potentials determined by density functional theory (DFT). Pronounced oscillations as a function of excitation energy are predicted for the case of Na@(He){sub 200}, in marked contrast with the absorption cross-section and angular distribution of the ejected atoms which are smooth functions of the energy. These oscillations are due to quantum interference between different coherently excited photodetachment pathways. Experimentally, these oscillations should be reflected in the fluorescence polarization and polarization-resolved photoelectron yield of the ejected atoms, which are proportional to the electronic angular momentum alignment. In addition, this result is much more general than the test case of NaHe{sub 200} studied here. It should be observable for larger droplets, for higher excited electronic states, and for other alkali as well as for alkali-earth atoms. Detection of these oscillations would show that the widely used pseudo-diatomic model can be valid beyond the prediction of absorption spectra and could help in interpreting parts of the dynamics, as already hinted by some experimental results on angular anisotropy of bare alkali fragments.

  10. First-principles study of ternary graphite compounds cointercalated with alkali atoms (Li, Na, and K) and alkylamines towards alkali ion battery applications

    Science.gov (United States)

    Ri, Gum-Chol; Yu, Chol-Jun; Kim, Jin-Song; Hong, Song-Nam; Jong, Un-Gi; Ri, Mun-Hyok

    2016-08-01

    First-principles calculations were carried out to investigate the structural, energetic, and electronic properties of ternary graphite compounds cointercalated with alkali atoms (AM = Li, Na, and K) and normal alkylamine molecules (nCx; x = 1, 2, 3, 4), denoted as AM-nCx-GICs. From the optimization of the orthorhombic unit cells for the crystalline compounds, it was found that, with the increase in the atomic number of alkali atoms, the layer separations decrease in contrast to AM-GICs, while the bond lengths between alkali atoms and graphene layer, and nitrogen atom of alkylamine increase. The calculated formation energies and interlayer binding energies of AM-nC3-GICs indicate that the compounds is increasingly stabilized from Li to K, and the energy barriers for migration of alkali atoms suggest that alkali cation with larger ionic radius diffuses more smoothly in graphite, being similar to AM-GICs. Through the analysis of electronic properties, it was established that more extent of electronic charge is transferred from more electropositive alkali atom to the carbon ring of graphene layer, and the hybridization of valence electron orbitals between alkylamine molecules and graphene layer is occurred.

  11. Hyperfine-frequency shifts of alkali-metal atoms during long-range collisions

    CERN Document Server

    McGuyer, B H

    2013-01-01

    Collisions with chemically inert atoms or molecules change the hyperfine coupling of an alkali-metal atom through the hyperfine-shift interaction. This interaction is responsible for the pressure shifts of the microwave resonances of alkali-metal atoms in buffer gases, is an important spin interaction in alkali-metal--noble-gas van der Waals molecules, and is anticipated to enable the magnetoassociation of ultracold molecules such as RbSr. An improved estimate is presented for the long-range asymptote of this interaction for Na, K, Rb, and Cs. To test the results, the change in hyperfine coupling due to a static electric field is estimated and reasonable agreement is found.

  12. An Alkali-Vapor Cell with Metal Coated Windows for Efficient Application of an Electric Field

    CERN Document Server

    Sarkisyan, D; Guena, J; Lintz, M; Bouchiat, M A; Sarkisyan, David; Gu\\'{e}na, Jocelyne; Lintz, Michel; Bouchiat, Marie-Anne

    2005-01-01

    We describe the implementation of a cylindrical T-shaped alkali-vapor cell for laser spectroscopy in the presence of a longitudinal electric field. The two windows are used as two electrodes of the high-voltage assembly, which is made possible by a metallic coating which entirely covers the inner and outer sides of the windows except for a central area to let the laser beams in and out of the cell. This allows very efficient application of the electric field, up to 2 kV/cm in a rather dense superheated vapor, even when significant photoemission takes place at the windows during pulsed laser irradiation. The body of the cell is made of sapphire or alumina ceramic to prevent large currents resulting from surface conduction observed in cesiated glass cells. The technique used to attach the monocrystalline sapphire windows to the cell body causes minimal stress birefringence in the windows. In addition, reflection losses at the windows can be made very small. The vapor cell operates with no buffer gas and has no ...

  13. Emission Channeling Studies of the Lattice Site of Oversized Alkali Atoms Implanted in Metals

    CERN Multimedia

    2002-01-01

    % IS340 \\\\ \\\\ As alkali atoms have the largest atomic radius of all elements, the determination of their lattice configuration following implantation into metals forms a critical test for the various models predicting the lattice site of implanted impurity atoms. The site determination of these large atoms will especially be a crucial check for the most recent model that relates the substitutional fraction of oversized elements to their solution enthalpy. Recent exploratory $^{213}$Fr and $^{221}$Fr $\\alpha$-emission channeling experiments at ISOLDE-CERN and hyperfine interaction measurements on Fr implanted in Fe gave an indication for anomalously large substitutional fractions. To investigate further the behaviour of Fr and other alkali atoms like Cs and Rb thoroughly, more on-line emission channeling experiments are needed. We propose a number of shifts for each element, where the temperature of the implanted metals will be varied between 50$^\\circ$ and 700$^\\circ$~K. Temperature dependent measurements wi...

  14. Long-range interactions between excited helium and alkali-metal atoms

    KAUST Repository

    Zhang, J.-Y.

    2012-12-03

    The dispersion coefficients for the long-range interaction of the first four excited states of He, i.e., He(2 1,3S) and He(2 1,3P), with the low-lying states of the alkali-metal atoms Li, Na, K, and Rb are calculated by summing over the reduced matrix elements of the multipole transition operators. For the interaction between He and Li the uncertainty of the calculations is 0.1–0.5%. For interactions with other alkali-metal atoms the uncertainty is 1–3% in the coefficient C5, 1–5% in the coefficient C6, and 1–10% in the coefficients C8 and C10. The dispersion coefficients Cn for the interaction of He(2 1,3S) and He(2 1,3P) with the ground-state alkali-metal atoms and for the interaction of He(2 1,3S) with the alkali-metal atoms in their first 2P states are presented in this Brief Report. The coefficients for other pairs of atomic states are listed in the Supplemental Material.

  15. Hyperfine-induced quadrupole moments of alkali-metal atom ground states and their implications for atomic clocks

    CERN Document Server

    Derevianko, Andrei

    2016-01-01

    Spherically-symmetric ground states of alkali-metal atoms do not posses electric quadrupole moments. However, the hyperfine interaction between nuclear moments and atomic electrons distorts the spherical symmetry of electronic clouds and leads to non-vanishing atomic quadrupole moments. We evaluate these hyperfine-induced quadrupole moments using techniques of relativistic many-body theory and compile results for Li, Na, K, Rb, and Cs atoms. For heavy atoms we find that the hyperfine-induced quadrupole moments are strongly (two orders of magnitude) enhanced by correlation effects. We further apply the results of the calculation to microwave atomic clocks where the coupling of atomic quadrupole moments to gradients of electric fields leads to clock frequency uncertainties. We show that for $^{133}$Cs atomic clocks, the spatial gradients of electric fields must be smaller than $30 \\, \\mathrm{V}/\\mathrm{cm}^2$ to guarantee fractional inaccuracies below $10^{-16}$.

  16. Widefield Microwave Imaging in Alkali Vapor Cells with sub-100 um Resolution

    CERN Document Server

    Horsley, Andrew; Treutlein, Philipp

    2015-01-01

    We report on widefield microwave vector field imaging with sub um resolution using a microfabricated alkali vapor cell. The setup can additionally image dc magnetic fields, and can be configured to image microwave electric fields. Our camera-based widefield imaging system records 2D images with a 6x6 mm2 field of view at a rate of 10 Hz. It provides up to 50 um spatial resolution, and allows imaging of fields as close as 150 um above structures, through the use of thin external cell walls. This is crucial in allowing us to take practical advantage of the high spatial resolution, as feature sizes in near-fields are on the order of the distance from their source, and represents an order of magnitude improvement in surface-feature resolution compared to previous vapor cell experiments. We present microwave and dc magnetic field images above a selection of devices, demonstrating a microwave sensitivity of 1.4 uT/sqrt-Hz per 50x50x140 um3 voxel, at present limited by the speed of our camera system. Since we image ...

  17. Tensorial depolarization of alkali atoms by isotropic collisions with neutral hydrogen

    CERN Document Server

    Derouich, Moncef

    2012-01-01

    Results. We consider the problem of isotropic collisions between an alkali atom and neutral hydrogen. We calculate the collisional tensorial components of general p and s-states, characterized by their effective principal quantum number $n^{*}$. It is found that the behaviour of the tensorial components obey simple power laws allowing quick calculations of the depolarizing collisional rates. As application, our results should allow a rigorous treatment of the atomic polarization profiles of the D1 -D2 lines of alkali atoms. Conclusions. Close coupling treatments of atomic collisions are needed to decipher the information encoded in the polarized radiation from the Sun. Important problems remain unresolved like the role of collisions in the Paschen-Back conditions.

  18. "Doubly magic" conditions in magic-wavelength trapping of ultracold alkali-metal atoms.

    Science.gov (United States)

    Derevianko, Andrei

    2010-07-16

    In experiments with trapped atoms, atomic energy levels are shifted by the trapping optical and magnetic fields. Regardless of this strong perturbation, precision spectroscopy may be still carried out using specially crafted, "magic" trapping fields. Finding these conditions for particularly valuable microwave transitions in alkali-metal atoms has so far remained an open challenge. Here I demonstrate that the microwave transitions in alkali-metal atoms may be indeed made impervious to both trapping laser intensity and fluctuations of magnetic fields. I consider driving multiphoton transitions between the clock levels and show that these "doubly magic" conditions are realized at special values of trapping laser wavelengths and fixed values of relatively weak magnetic fields. This finding has implications for precision measurements and quantum information processing with qubits stored in hyperfine manifolds.

  19. Van der Waals Interactions among Alkali Rydberg Atoms with Excitonic States

    CERN Document Server

    Zoubi, Hashem

    2015-01-01

    We investigate the influence of the appearance of excitonic states on van der Waals interactions among two Rydberg atoms. The atoms are assumed to be in different Rydberg states, e.g., in the $|ns\\rangle$ and $|np\\rangle$ states. The resonant dipole-dipole interactions yield symmetric and antisymmetric excitons, with energy splitting that give rise to new resonances as the atoms approach each other. Only far from these resonances the van der Waals coefficients, $C_6^{sp}$, can be defined. We calculate the $C_6$ coefficients for alkali atoms and present the results for lithium by applying perturbation theory. At short interatomic distances of several $\\mu m$, we show that the widely used simple model of two-level systems for excitons in Rydberg atoms breaks down, and the correct representation implies multi-level atoms. Even though, at larger distances one can keep the two-level systems but in including van der Waals interactions among the atoms.

  20. Spectral line shifts of alkali atoms in liquid helium: a relativistic density functional approach

    Energy Technology Data Exchange (ETDEWEB)

    Anton, J [Universitaet Kassel, Institut fuer Physik, 34109 Kassel (Germany); Mukherjee, P K [Indian Association for the Cultivation of Science, Jadavpur, Kolkata-700 032 (India); Fricke, B [Universitaet Kassel, Institut fuer Physik, 34109 Kassel (Germany); Fritzsche, S [Universitaet Kassel, Institut fuer Physik, 34109 Kassel (Germany)

    2007-06-28

    Excitation line shifts of the principal resonance transitions in alkali atoms sodium and cesium embedded inside the liquid helium environment have been calculated using four-component relativistic density functional theory. The effect of the liquid helium environment is assumed to be represented by a cluster of 14 atoms surrounding the central alkali atom. The estimated blue shift of the principal resonance line {sup 2}S {yields}{sup 2}P is 22.8 nm for Na and 16.7 nm for Cs. The result for Cs is in good agreement with the experimental shift of 18.2 nm. In the absence of the experimental data for Na, our result is compared with those of other theoretical estimates.

  1. Indirect Relativistic Effect in Electron-Alkali-Atom Collision

    Institute of Scientific and Technical Information of China (English)

    LIU Yi-Bao; PANG Wen-Ning; DING Hai-Bing; SHANG Ren-Cheng

    2005-01-01

    @@ We present detailed studies on the differential cross section (DCS) and total cross section (TCS) in electronalkali-atom collision processes by using two types of distorted wave methods, the ordinary distorted wave method and the indirect-relativistic distorted wave method. We find that the indirect relativistic effect in the target atom can be neglected in the TCS calculation in the processes; however, with an increase of the atomic number, this effect becomes significant in the DCS calculation. Then, based on the density matrix theory, the orientation and alignment parameters of excited caesium P states scattered by electrons at low incident energy are calculated,and comparisons are made for the two series between the two methods. The results show that accordance is reached at scattering angles smaller than 45°, but considerable difference appears at angles larger than 45° due to the relativistic effect.

  2. Controlled Reactions between Ultracold Alkali and Metastable Helium Atoms

    CERN Document Server

    Flores, Adonis Silva; Knoop, Steven

    2016-01-01

    In an ultracold, optically trapped mixture of $^{87}$Rb and metastable triplet $^4$He atoms we have studied trap loss for different spin-state combinations, for which interspecies Penning ionization is the main two-body loss process. We observe long trapping lifetimes for the purely quartet spin-state combination, indicating strong suppression of Penning ionization loss by at least two orders of magnitude. For the other spin-mixtures we observe short lifetimes that depend linearly on the doublet character of the entrance channel. We compare the extracted loss rate coefficient with recent predictions of multichannel quantum-defect theory for reactive collisions involving a strong exothermic loss channel and find near-universal loss for doublet scattering. Our work demonstrates control of reactive collisions by internal atomic state preparation, which also implies magnetic field tunability.

  3. Reactions between cold methyl halide molecules and alkali-metal atoms.

    Science.gov (United States)

    Lutz, Jesse J; Hutson, Jeremy M

    2014-01-07

    We investigate the potential energy surfaces and activation energies for reactions between methyl halide molecules CH3X (X = F, Cl, Br, I) and alkali-metal atoms A (A = Li, Na, K, Rb) using high-level ab initio calculations. We examine the anisotropy of each intermolecular potential energy surface (PES) and the mechanism and energetics of the only available exothermic reaction pathway, CH3X + A → CH3 + AX. The region of the transition state is explored using two-dimensional PES cuts and estimates of the activation energies are inferred. Nearly all combinations of methyl halide and alkali-metal atom have positive barrier heights, indicating that reactions at low temperatures will be slow.

  4. Photoabsorption by ground-state alkali-metal atoms.

    Science.gov (United States)

    Weisheit, J. C.

    1972-01-01

    Principal-series oscillator strengths and ground-state photoionization cross sections are computed for sodium, potassium, rubidium, and cesium. The degree of polarization of the photoelectrons is also predicted for each atom. The core-polarization correction to the dipole transition moment is included in all of the calculations, and the spin-orbit perturbation of valence-p-electron orbitals is included in the calculations of the Rb and Cs oscillator strengths and of all the photoionization cross sections. The results are compared with recent measurements.

  5. Method And Apparatus For Atomizing And Vaporizing Liquid

    KAUST Repository

    Lal, Amit

    2014-09-18

    A method and apparatus for atomizing and vaporizing liquid is described. An apparatus having an ejector configured to eject one or more droplets of liquid may be inserted into a reservoir containing liquid. The ejector may have a vibrating device that vibrates the ejector and causes liquid to move from the reservoir up through the ejector and out through an orifice located on the top of the ejector. The one or more droplets of liquid ejected from the ejector may be heated and vaporized into the air.

  6. Tuning the work function of ultrathin oxide films on metals by adsorption of alkali atoms.

    Science.gov (United States)

    Martinez, Umberto; Giordano, Livia; Pacchioni, Gianfranco

    2008-04-28

    We report a theoretical investigation of the adsorption of alkali metal atoms deposited on ultrathin oxide films. The properties of Li, Na, and K atoms adsorbed on SiO(2)/Mo(112) and of K on MgO / Ag(100) and TiO(2)/Pt(111) have been analyzed with particular attention to the induced changes in the work function of the system, Phi. On the nonreducible SiO(2) and MgO oxide films there is a net transfer of the outer ns electron of the alkali atom to the metal substrate conduction band; the resulting surface dipole substantially lowers Phi. The change in Phi depends (a) on the adsorption site (above the oxide film or at the interface) and (b) on the alkali metal coverage. Deposition of K on reducible TiO(2) oxide films results in adsorbed K(+) ions and in the formation of Ti(3+) ions. No charge transfer to the metal substrate is observed but also in this case the surface dipole resulting from the K-TiO(2) charge transfer has the effect to considerably reduce the work function of the system.

  7. Unraveling the absorption spectra of alkali metal atoms attached to helium nanodroplets.

    Science.gov (United States)

    Bünermann, Oliver; Droppelmann, Georg; Hernando, Alberto; Mayol, Ricardo; Stienkemeier, Frank

    2007-12-13

    The absorption spectra of the first electronic exited state of alkali metal atoms on helium nanodroplets formed of both 4He and 3He isotopes were studied experimentally as well as theoretically. In the experimental part new data on the 2palkali metal atoms with helium nanodroplets, a model calculation was performed. New helium density profiles as well as a refined model allowed us to achieve good agreement with the experimental findings. For the first time the red-shifted intensities in the lithium and sodium spectra are explained in terms of enhanced binding configurations in the excited state displaced spatially from the ground state configurations.

  8. Antiproton and proton collisions with the alkali-metal atoms Li, Na, and K

    DEFF Research Database (Denmark)

    Lühr, Armin Christian; Saenz, Alejandro

    2008-01-01

    Single-electron ionization and excitation cross sections as well as cross sections for excitation into the first excited p state of the alkali-metal atoms Li(2s), Na(3s), and K(4s) colliding with antiprotons and protons were calculated using a time-dependent channel-coupling approach....... For antiprotons an impact-energy range from 0.25 to 1000 keV and for protons from 2 to 1000 keV was considered. The target atoms are treated as effective one-electron systems using a model potential. The results are compared with theoretical and experimental data from literature and calculated cross sections...

  9. Continuation of Atomic Spectroscopy on Alkali Isotopes at ISOLDE

    CERN Multimedia

    2002-01-01

    Laser optical measurements on Rb, Cs and Fr have already been performed at ISOLDE in 1978-79. The hyperfine structure and isotope shift of |7|6|-|9|8Rb, |1|1|8|-|1|4|5Cs, |2|0|8|-|2|1|3Fr and 14 of their isomers have been studied. Among the wealth of information which has been obtained, the most important are the first observation of an optical transition of the element Fr, the evidence of the onset of nuclear deformation at N~=~60 for Rb isotopes and the shape isomerism isotopes. \\\\ \\\\ From both the atomic and nuclear physics point of view, new studies seem very promising: \\item - the search for new optical transitions in Fr; the shell effect in the rms charge radius at N~=~126 for Fr isotopes \\item - the study of a possible onset of deformation for Cs isotopes beyond |1|4|5Cs \\item - the study of a region of static deformation in neutron-deficient Rb isotopes. \\\\ \\\\ \\end{enumerate} A new apparatus has been built. The principle remains the same as used in our earlier experiments. The improvements concern ess...

  10. Adsorption of alkali, alkaline-earth, and 3d transition metal atoms on silicene

    Science.gov (United States)

    Sahin, H.; Peeters, F. M.

    2013-02-01

    The adsorption characteristics of alkali, alkaline-earth, and transition metal adatoms on silicene, a graphene-like monolayer structure of silicon are analyzed by means of first-principles calculations. In contrast to graphene, interaction between the metal atoms and the silicene surface is quite strong due to its highly reactive buckled hexagonal structure. In addition to structural properties, we also calculate the electronic band dispersion, net magnetic moment, charge transfer, work function, and dipole moment of the metal adsorbed silicene sheets. Alkali metals, Li, Na, and K, adsorb to hollow sites without any lattice distortion. As a consequence of the significant charge transfer from alkalis to silicene, metalization of silicene takes place. Trends directly related to atomic size, adsorption height, work function, and dipole moment of the silicene/alkali adatom system are also revealed. We found that the adsorption of alkaline-earth metals on silicene is entirely different from their adsorption on graphene. The adsorption of Be, Mg, and Ca turns silicene into a narrow gap semiconductor. Adsorption characteristics of eight transition metals Ti, V, Cr, Mn, Fe, Co, Mo, and W are also investigated. As a result of their partially occupied d orbital, transition metals show diverse structural, electronic, and magnetic properties. Upon the adsorption of transition metals, depending on the adatom type and atomic radius, the system can exhibit metal, half-metal, and semiconducting behavior. For all metal adsorbates, the direction of the charge transfer is from adsorbate to silicene, because of its high surface reactivity. Our results indicate that the reactive crystal structure of silicene provides a rich playground for functionalization at nanoscale.

  11. Electron- and Photon-stimulated Desorption of Alkali Atoms from Lunar Sample and a Model Mineral Surface

    Science.gov (United States)

    Yakshinskiy, B. V.; Madey, T. E.

    2003-01-01

    We report recent results on an investigation of source mechanisms for the origin of alkali atoms in the tenuous planetary atmospheres, with focus on non-thermal processes (photon stimulated desorption (PSD), electron stimulated desorption (ESD), and ion sputtering). Whereas alkaline earth oxides (MgO, CaO) are far more abundant in lunar samples than alkali oxides (Na2O, K2O), the atmosphere of the Moon contains easily measurable concentrations of Na and K, while Ca and Mg are undetected there; traces of Ca have recently been seen in the Moon's atmosphere (10-3 of Na). The experiments have included ESD, PSD and ion sputtering of alkali atoms from model mineral surface (amorphous SiO2) and from a lunar basalt sample obtained from NASA. The comparison is made between ESD and PSD efficiency of monovalent alkalis (Na, K) and divalent alkaline earths (Ba, Ca).The ultrahigh vacuum measurement scheme for ESD and PSD of Na atoms includes a highly sensitive alkali metal detector based on surface ionization, and a time-of-flight technique. For PSD measurements, a mercury arc light source (filtered and chopped) is used. We find that bombardment of the alkali covered surfaces by ultraviolet photons or by low energy electrons (E>4 eV) causes desorption of hot alkali atoms. This results are consistent with the model developed to explain our previous measurements of sodium desorption from a silica surface and from water ice: electron- or photon-induced charge transfer from the substrate to the ionic adsorbate causes formation of a neutral alkali atom in a repulsive configuration, from which desorption occurs. The two-electron charge transfer to cause desorption of divalent alkaline eath ions is a less likely process.The data support the suggestion that PSD by UV solar photons is a dominant source process for alkalis in the tenuous lunar atmosphere.

  12. Carrier-wave Rabi-flopping signatures in high-order harmonic generation for alkali atoms.

    Science.gov (United States)

    Ciappina, M F; Pérez-Hernández, J A; Landsman, A S; Zimmermann, T; Lewenstein, M; Roso, L; Krausz, F

    2015-04-10

    We present a theoretical investigation of carrier-wave Rabi flopping in real atoms by employing numerical simulations of high-order harmonic generation (HHG) in alkali species. Given the short HHG cutoff, related to the low saturation intensity, we concentrate on the features of the third harmonic of sodium (Na) and potassium (K) atoms. For pulse areas of 2π and Na atoms, a characteristic unique peak appears, which, after analyzing the ground state population, we correlate with the conventional Rabi flopping. On the other hand, for larger pulse areas, carrier-wave Rabi flopping occurs, and is associated with a more complex structure in the third harmonic. These characteristics observed in K atoms indicate the breakdown of the area theorem, as was already demonstrated under similar circumstances in narrow band gap semiconductors.

  13. Carrier-wave Rabi flopping signatures in high-order harmonic generation for alkali atoms

    CERN Document Server

    Ciappina, M F; Landsman, A S; Zimmermann, T; Lewenstein, M; Roso, L; Krausz, F

    2015-01-01

    We present the first theoretical investigation of carrier-wave Rabi flopping in real atoms by employing numerical simulations of high-order harmonic generation (HHG) in alkali species. Given the short HHG cutoff, related to the low saturation intensity, we concentrate on the features of the third harmonic of sodium (Na) and potassium (K) atoms. For pulse areas of 2$\\pi$ and Na atoms, a characteristic unique peak appears, which, after analyzing the ground state population, we correlate with the conventional Rabi flopping. On the other hand, for larger pulse areas, carrier-wave Rabi flopping occurs, and is associated with a more complex structure in the third harmonic. These new characteristics observed in K atoms indicate the breakdown of the area theorem, as was already demonstrated under similar circumstances in narrow band gap semiconductors.

  14. Theory of metal atom-water interactions and alkali halide dimers

    Science.gov (United States)

    Jordan, K. D.; Kurtz, H. A.

    1982-01-01

    Theoretical studies of the interactions of metal atoms with water and some of its isoelectronic analogs, and of the properties of alkali halides and their aggregates are discussed. Results are presented of ab initio calculations of the heats of reaction of the metal-water adducts and hydroxyhydrides of Li, Be, B, Na, Mg, and Al, and of the bond lengths and angles an; the heats of reaction for the insertion of Al into HF, H2O, NH3, H2S and CH3OH, and Be and Mg into H2O. Calculations of the electron affinities and dipole moments and polarizabilities of selected gas phase alkali halide monomers and dimers are discussed, with particular attention given to results of calculations of the polarizability of LiF taking into account electron correlation effects, and the polarizability of the dimer (LiF)2.

  15. Split window resonances for the photoionization of spin-orbit coupled subshell states in alkali atoms

    Energy Technology Data Exchange (ETDEWEB)

    Koide, M. [Department of Science and Technology, Meisei University, Tokyo 191-8656 (Japan)]. E-mail: mkoide@galaxy.ocn.ne.jp; Koike, F. [School of Medicine, Kitasato University, Kanagawa 228-8555 (Japan); Azuma, Y. [PhotonFactory, IMSS, KEK, Ibaraki 305-0801 (Japan); Nagata, T. [Department of Science and Technology, Meisei University, Tokyo 191-8656 (Japan)

    2005-06-15

    We study the origin of dual window-type 3s->4p photoexcitation resonances of potassium atoms that have been observed previously [M. Koide et al., J. Phys. Soc. Jpn. 71 (2002) 1676] by means of photoion spectroscopy. We also consider the sub-valence shell photoexcitations of other alkali metal atoms. In potassium 3p photoionizations, the photoion energy levels may be labeled by their total angular momenta, and they are well separated due to the spin-orbit couplings in 3p subshells. The system of a photoion and a photoelectron is therefore a superposition of different total spin states if expressed in terms of the LS-coupling scheme. The ionization continuum may couple with several intermediate discrete states with different total spin quantum numbers, giving a possibility to observe split resonance structures in the spectra of 3s->np photoexcitations and in other alkali-atom photoexcitations. We discuss the dual window-type resonances in potassium, rubidium, and cesium atoms.

  16. Coupling a thermal atomic vapor to an integrated ring resonator

    CERN Document Server

    Ritter, Ralf; Pernice, Wolfram; Kübler, Harald; Pfau, Tilman; Löw, Robert

    2016-01-01

    Strongly interacting atom-cavity systems within a network with many nodes constitute a possible realization for a quantum internet which allows for quantum communication and computation on the same platform. To implement such large-scale quantum networks, nanophotonic resonators are promising candidates because they can be scalably fabricated and interconnected with waveguides and optical fibers. By integrating arrays of ring resonators into a vapor cell we show that thermal rubidium atoms above room temperature can be coupled to photonic cavities as building blocks for chip-scale hybrid circuits. Although strong coupling is not yet achieved in this first realization, our approach provides a key step towards miniaturization and scalability of atom-cavity systems.

  17. DPAL: a new class of CW near-infrared high-power diode-pumped alkali (vapor) lasers

    Science.gov (United States)

    Krupke, William F.; Beach, Raymond J.; Kanz, Vernon K.; Payne, Stephen A.

    2004-05-01

    DPAL, a new class of diode pumped alkali vapor lasers, offers the prospect for high efficiency cw laser radiation at near-infrared wavelengths: cesium 895 nm, rubidium 795 nm, and potassium 770 nm. The physics of DPAL lasers are outlined, and the results of laboratory demonstrations using a titanium sapphire surrogate pump are summarized, along with benchmarked device models. DPAL electrical efficiencies of 25-30% are projected and near-diffraction-limited DPAL device power scaling into the multi-kilowatt regime from a single aperture is also projected.

  18. Measurement method for the nuclear anapole moment of laser trapped alkali atoms

    CERN Document Server

    Gómez, E; Sprouse, G D; Orozco, L A; De Mille, D P

    2004-01-01

    Weak interactions within a nucleus generate a nuclear spin dependent parity violating electromagnetic moment; the anapole moment. In heavy nuclei, the anapole moment is the dominant contribution to spin-dependent atomic parity violation. We analyze a method to measure the nuclear anapole moment through the electric dipole transition it induces between hyperfine states of the ground level. The method requires tight confinement of the atoms to position them at the anti-node of a standing wave driving the anapole-induced E1 transiton. We explore the necessary limits in the number of atoms, excitation fields, trap type, interrogation method, and systematic tests necessary for such measurements in francium, the heaviest alkali.

  19. Photon Hall Scattering from Alkaline-earth-like atoms and Alkali-like ions

    CERN Document Server

    van Tiggelen, B A

    2016-01-01

    We investigate the possibility of observing a magneto-transverse scattering of photons from alkaline-earth-like atoms as well as alkali-like ions and provide orders of magnitude. The transverse magneto-scattering is physically induced by the interference between two possible quantum transitions of an outer electron in a S-state, one dispersive electric-dipole transition to a P-orbital state and a second resonant electric-quadrupole transition to a P-orbital state. In contrast with previous mechanisms proposed for such an atomic photonic Hall effect, no real photons are scattered by the electric-dipole allowed transition, which increases the ratio of Hall current to background photons significantly. The main experimental challenge is to overcome the small detection threshold, with only 10^{-5} photons scattered per atom per second.

  20. Momentum densities and Compton profiles of alkali-metal atoms

    Indian Academy of Sciences (India)

    Pranab Sarkar; Anupam Sarkar; S N Roy; B Talukdar

    2003-03-01

    It is assumed that the dynamics of valence electrons of alkali-metal atoms can be well accounted for by a quantum-defect theoretic model while the core electrons may be supposed to move in a self-consistent field. This model is used to study the momentum properties of atoms from 3Li to 37Rb. The numerical results obtained for the momentum density, moments of momentum density and Compton profile are found to be in good agreement with the results of more detailed configuration-interaction calculations for the atom 3Li. Similar results for 11Na, 19K and 37Rb are compared with the corresponding Hartree–Fock–Roothaan values only, for want of data from other realistic calculations.

  1. Electric dipole polarizabilities of Rydberg states of alkali-metal atoms

    Science.gov (United States)

    Yerokhin, V. A.; Buhmann, S. Y.; Fritzsche, S.; Surzhykov, A.

    2016-09-01

    Calculations of the static electric-dipole scalar and tensor polarizabilities are presented for two alkali-metal atoms, Rb and Cs, for the n S , n P½,3 /2 , and n D3 /2 ,5 /2 states with large principal quantum numbers up to n =50 . The calculations are performed within an effective one-electron approximation, based on the Dirac-Fock Hamiltonian with a semiempirical core-polarization potential. The obtained results are compared with those from a simpler semiempirical approach and with available experimental data.

  2. Bose–Einstein condensation in a vapor of sodium atoms in an electric field

    Energy Technology Data Exchange (ETDEWEB)

    You, Pei-Lin, E-mail: youpeli@163.com

    2016-06-15

    Bose–Einstein condensation (BEC) at normal temperature (T=343K) has been observed because an electric field was first applied. There are two ways to achieve phase transition: lower the temperature of Bose gas or increase its density. This article provides more appropriate method: increase the voltage. In theory, 3s and 3p states of sodium are not degenerate, but Na may be polar atom doesnot conflict with quantum mechanics because it is hydrogen-like atom. Our innovation lies in we applied an electric field used for the orientation polarization. Na vapor was filled in a cylindrical capacitor. In order to determine the polarity of sodium, we measured the capacitance at different temperatures. If Na is non-polar atom, its capacitance should be independent of temperature because the nucleus of atom is located at the center of the electron cloud. But our experiment shows that its capacitance is related to temperature, so Na is polar atom. In order to achieve Na vapor phase transition, we measured the capacitance at different voltages. From the entropy of Na vapor S=0, the critical voltage V{sub c}=68volts. When Vatoms are in random orientation S>0; when V>V{sub c}, the atoms become aligned with the field S<0, phase transition occurred. When V=390 volts »V{sub c}, the capacitance decreased from C=1.9C{sub 0} to C≈C{sub 0} (C{sub 0} is the vacuum capacitance), this result implies that almost all the Na atoms (more than 98%) are aligned with the field, Na vapor entered quasi-vacuum state. We create a BEC with 2.506×10{sup 17} atoms, condensate fraction reached 98.9%. This is BEC in momentum space. Our experiment shows that if a Bose gas enters quasi-vacuum state, this also means that it underwent phase transition and generates BEC. Therefore, quasi-vacuum state of alkali gas is essentially large-scale BEC. This is an unexpected discovery. BEC and vacuum theory are two unrelated research areas, but now they are closely linked together. The maximum

  3. Two-photon photoemission study of the coverage-dependent electronic structure of chemisorbed alkali atoms on a Ag(111) surface.

    Science.gov (United States)

    Wang, Lei-Ming; Sametoglu, Vahit; Winkelmann, Aimo; Zhao, Jin; Petek, Hrvoje

    2011-09-01

    We report a systematic investigation of the electronic structure of chemisorbed alkali atoms (Li-Cs) on a Ag(111) surface by two-photon photoemission spectroscopy. Angle-resolved two-photon photoemission spectra are obtained for 0-0.1 monolayer coverage of alkali atoms. The interfacial electronic structure as a function of periodic properties and the coverage of alkali atoms is observed and interpreted assuming ionic adsorbate/substrate interaction. The energy of the alkali atom σ-resonance at the limit of zero coverage is primarily determined by the image charge interaction, whereas at finite alkali atom coverages, it follows the formation of a dipolar surface field. The coverage- and angle-dependent two-photon photoemission spectra provide information on the photoinduced charge-transfer excitation of adsorbates on metal surfaces. This work complements the previous work on alkali/Cu(111) chemisorption [Phys. Rev. B 2008, 78, 085419].

  4. Single Molecule DNA Detection with an Atomic Vapor Notch Filter

    CERN Document Server

    Uhland, Denis; Widmann, Matthias; Lee, Sang-Yun; Wrachtrup, Jörg; Gerhardt, Ilja

    2015-01-01

    The detection of single molecules has facilitated many advances in life- and material-sciences. Commonly, it founds on the fluorescence detection of single molecules, which are for example attached to the structures under study. For fluorescence microscopy and sensing the crucial parameters are the collection and detection efficiency, such that photons can be discriminated with low background from a labeled sample. Here we show a scheme for filtering the excitation light in the optical detection of single stranded labeled DNA molecules. We use the narrow-band filtering properties of a hot atomic vapor to filter the excitation light from the emitted fluorescence of a single emitter. The choice of atomic sodium allows for the use of fluorescent dyes, which are common in life-science. This scheme enables efficient photon detection, and a statistical analysis proves an enhancement of the optical signal of more than 15% in a confocal and in a wide-field configuration.

  5. Nonlinear optical properties of atomic vapor and semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Doseok [Univ. of California, Berkeley, CA (United States). Dept. of Physics

    1997-05-01

    This thesis contains the study of highly forbidden resonant second harmonic generation (SHG) in atomic potassium vapor using tunable picosecond pulses. Various output characteristics of vapor SHG have been investigated including the input intensity dependence, potassium vapor density dependence, buffer gas pressure dependence, and spatial profile. Recently, the discovery of new nonlinear optical crystals such as barium borate (β-BaB2O4, BBO) and lithium borate (LiB3O5, LBO) has greatly improved the performance of a tunable coherent optical devices based on optical parametric generation and amplification. In the second part of this thesis, a homebuilt picosecond optical parametric generator/amplifier (OPG/OPA) system is described in detail, including its construction details and output characteristics. This laser device has found many useful applications in spectroscopic studies including surface nonlinear optical spectroscopy via sum-frequency generation (SFG). The last part of this thesis reports studies on multiphoton-excited photoluminescence from porous silicon and GaN. Multiphoton excitation and photoluminescence can give numerous complementary information about semiconductors not obtainable with one-photon, above-bandgap excitation.

  6. The higher order C_n dispersion coefficients for the alkali atoms

    CERN Document Server

    Mitroy, J

    2004-01-01

    The van der Waals coefficients, from C_11 through to C_16 resulting from 2nd, 3rd and 4th order perturbation theory are estimated for the alkali (Li, Na, K and Rb) atoms. The dispersion coefficients are also computed for all possible combinations of the alkali atoms and hydrogen. The parameters are determined from sum-rules after diagonalizing the fixed core Hamiltonian in a large basis. Comparisons of the radial dependence of the C_n/r^n potentials give guidance as to the radial regions in which the various higher-order terms can be neglected. It is seen that including terms up to C_10/r^10 results in a dispersion interaction that is accurate to better than 1 percent whenever the inter-nuclear spacing is larger than 20 a_0. This level of accuracy is mainly achieved due to the fortuitous cancellation between the repulsive (C_11, C_13, C_15) and attractive (C_12, C_14, C_16) dispersion forces.

  7. Internal Spin Control, Squeezing and Decoherence in Ensembles of Alkali Atomic Spins

    Science.gov (United States)

    Norris, Leigh Morgan

    Large atomic ensembles interacting with light are one of the most promising platforms for quantum information processing. In the past decade, novel applications for these systems have emerged in quantum communication, quantum computing, and metrology. Essential to all of these applications is the controllability of the atomic ensemble, which is facilitated by a strong coupling between the atoms and light. Non-classical spin squeezed states are a crucial step in attaining greater ensemble control. The degree of entanglement present in these states, furthermore, serves as a benchmark for the strength of the atom-light interaction. Outside the broader context of quantum information processing with atomic ensembles, spin squeezed states have applications in metrology, where their quantum correlations can be harnessed to improve the precision of magnetometers and atomic clocks. This dissertation focuses upon the production of spin squeezed states in large ensembles of cold trapped alkali atoms interacting with optical fields. While most treatments of spin squeezing consider only the case in which the ensemble is composed of two level systems or qubits, we utilize the entire ground manifold of an alkali atom with hyperfine spin f greater than or equal to 1/2, a qudit. Spin squeezing requires non-classical correlations between the constituent atomic spins, which are generated through the atoms' collective coupling to the light. Either through measurement or multiple interactions with the atoms, the light mediates an entangling interaction that produces quantum correlations. Because the spin squeezing treated in this dissertation ultimately originates from the coupling between the light and atoms, conventional approaches of improving this squeezing have focused on increasing the optical density of the ensemble. The greater number of internal degrees of freedom and the controllability of the spin-f ground hyperfine manifold enable novel methods of enhancing squeezing. In

  8. Theoretical and experimental study of the Stark effect in the ground state of alkali atoms in helium crystals

    OpenAIRE

    2007-01-01

    This thesis work describes a detailed study of the Stark interaction in the ground state of cesium atoms trapped in a solid helium matrix. The motivation for the investigation of electric field effects on alkali species implanted in solid helium is related to the original main goal of our experimental activities, i.e., the measurement of a permanent atomic electric dipole moment (EDM). The existence of an atomic EDM simultaneously violates the discrete symmetries of time reversal (T) and pari...

  9. Dispersion C3 coefficients for the alkali-metal atoms interacting with a graphene layer and with a carbon nanotube

    CERN Document Server

    Arora, Bindiya; Sahoo, B K

    2013-01-01

    We evaluate separation dependent van der Waal dispersion ($C_3$) coefficients for the interactions of the Li, Na, K and Rb alkali atoms with a graphene layer and with a single walled carbon nanotube (CNT) using the hydrodynamic and Dirac models. The results from both the models are evaluated using accurate values of the dynamic polarizabilities of the above atoms. Accountability of these accurate values of dynamical polarizabilities of the alkali atoms in determination of the above $C_3$ coefficients are accentuated by comparing them with the coefficients evaluated using the dynamic dipole polarizabilities estimated from the single oscillator approximation which are typically employed in the earlier calculations. For practical description of the atom-surface interaction potentials the radial dependent $C_3$ coefficients are given for a wide range of separation distances between the ground states of the considered atoms and the wall surfaces and also for different values of nanotube radii. The coefficients for...

  10. Interfacing transitions of different alkali atoms and telecom bands using one narrowband photon pair source

    CERN Document Server

    Schunk, Gerhard; Strekalov, Dmitry V; Förtsch, Michael; Sedlmeir, Florian; Schwefel, Harald G L; Göbelt, Manuela; Christiansen, Silke; Leuchs, Gerd; Marquardt, Christoph

    2015-01-01

    Photon-atom coupling, in particular for proposed quantum repeater schemes, requires pure and versatile sources of quantum light. Here we demonstrate coupling to alkali dipole transitions in the near-infrared with a tunable source of photon pairs generated via spontaneous parametric down-conversion in a whispering-gallery mode resonator (WGMR). We have developed novel wavelength tuning mechanisms, which allow for a coarse step-wise central wavelength tuning from 790 nm to 1630 nm as well as continuous tuning with MHz resolution. We demonstrate the compatibility of our source with atomic transitions, such as the D1 line of rubidium at 795 nm (idler at 1608 nm) and cesium at 895\\,nm (idler at 1312 nm). At the cesium D1 transition, we exemplarily show a continuous scanning of the signal wavelength over the Doppler-broadened absorption line, and finally a heralded single photon spectroscopy of the atomic decay. Providing this flexibility in connecting various atomic transitions with telecom wavelengths, we demonst...

  11. NMR and Nqr Study of Atomic Order in Alkali Borate Glasses.

    Science.gov (United States)

    Gravina, Samuel John

    A modified Robinson oscillator circuit was built for the detection of nuclear quadrupole resonance (NQR) in the 200 to 10,000 kHz region. The circuit demonstrates near ideal performance with the detected noise limited only by the sample temperature. The use of computer controlled data acquisition and a carefully designed sample probe allows for the use of an integrating time constant of up to 6 hours. This spectrometer has been used to detect ^{10}B and ^{11 }B NQR in lithium and sodium borate glasses and crystals. In pure boron oxide glass two distinct boron sites are found. By comparing this experiment with previous NMR and Raman spectroscopy studies, one of the sites, which comprises 85% of the total boron, can be attributed to boron atoms in boroxol rings. As sodium is added to the glass the abundance of boroxol rings decreases. At 20 mol% sodium oxide less than 2% of the boron atoms are found in boroxol rings. The dipole-dipole interaction between lithium cations and four-coordinated boron atoms (B_4 units) has been measured. It is found that every B_4 unit has one lithium cation next to it at an average distance of 2.82 A. A comparison with lithium borate crystals shows that diborate groups do not occur in significant quantities. Both high field and low field NMR studies of the boron quadrupole interaction in a B_4 unit also show that diborate groups are not found in the glass. A ^{23}Na and ^6Li NMR MASS study of lithium and sodium borate glasses shows that ^{23 }Na chemical shifts can distinguish sodium cations bound to non-bridging oxygens from sodium cations bound to bridging oxygens. The chemical shifts measured in lithium-sodium borate glasses are identical to those measured in lithium borate or sodium borate glasses, indicating similar alkali-oxygen coordination. A significant narrowing of the ^6Li NMR spectrum in a mixed alkali glass can be understood as a decrease in the entropy of the lithium cations. This result is consistent with the weak

  12. Single molecule DNA detection with an atomic vapor notch filter

    Energy Technology Data Exchange (ETDEWEB)

    Uhland, Denis; Rendler, Torsten; Widmann, Matthias; Lee, Sang-Yun [University of Stuttgart and Stuttgart Research Center of Photonic Engineering (SCoPE) and IQST, 3rd Physics Institute, Stuttgart (Germany); Wrachtrup, Joerg; Gerhardt, Ilja [University of Stuttgart and Stuttgart Research Center of Photonic Engineering (SCoPE) and IQST, 3rd Physics Institute, Stuttgart (Germany); Max Planck Institute for Solid State Research, Stuttgart (Germany)

    2015-12-01

    The detection of single molecules has facilitated many advances in life- and material-science. Commonly the fluorescence of dye molecules is detected, which are attached to a non-fluorescent structure under study. For fluorescence microscopy one desires to maximize the detection efficiency together with an efficient suppression of undesired laser leakage. Here we present the use of the narrow-band filtering properties of hot atomic sodium vapor to selectively filter the excitation light from the red-shifted fluorescence of dye labeled single-stranded DNA molecules. A statistical analysis proves an enhancement in detection efficiency of more than 15% in a confocal and in a wide-field configuration. (orig.)

  13. Quantum degenerate mixtures of alkali and alkaline-earth-like atoms.

    Science.gov (United States)

    Hara, Hideaki; Takasu, Yosuke; Yamaoka, Yoshifumi; Doyle, John M; Takahashi, Yoshiro

    2011-05-20

    We realize simultaneous quantum degeneracy in mixtures consisting of the alkali and alkaline-earth-like atoms Li and Yb. This is accomplished within an optical trap by sympathetic cooling of the fermionic isotope ⁶Li with evaporatively cooled bosonic ¹⁷⁴Yb and, separately, fermionic ¹⁷³Yb. Using cross-thermalization studies, we also measure the elastic s-wave scattering lengths of both Li-Yb combinations, |a(⁶Li-¹⁷⁴Yb)| = 1.0 ± 0.2 nm and |a(⁶Li-¹⁷³Yb)| = 0.9 ± 0.2 nm. The equality of these lengths is found to be consistent with mass-scaling analysis. The quantum degenerate mixtures of Li and Yb, as realized here, can be the basis for creation of ultracold molecules with electron spin degrees of freedom, studies of novel Efimov trimers, and impurity probes of superfluid systems.

  14. Model for fast, nonadiabatic collisions between alkali atoms and diatomic molecules

    Science.gov (United States)

    Hickman, A. P.

    1980-11-01

    Equations for collisions involving two potential surfaces are presented in the impact parameter approximation. In this approximation, a rectilinear classical trajectory is assumed for the translational motion, leading to a time-dependent Schroedinger's equation for the remaining degrees of freedom. Model potentials are considered for collisions of alkali atoms with diatomic molecules that lead to a particularly simple form of the final equations. Using the Magnus approximation, these equations are solved for parameters chosen to model the process Cs+O2→Cs++O2-, and total cross sections for ion-pair formation are obtained as a function of energy. The results exhibit oscillations that correspond qualitatively to those seen in recent measurements. In addition, the model predicts that the oscillations will become less pronounced as the initial vibrational level of O2 is increased.

  15. Atomic many-body effects and Lamb shifts in alkali metals

    CERN Document Server

    Ginges, J S M

    2016-01-01

    We present a detailed study of the Flambaum-Ginges radiative potential method which enables the accurate inclusion of quantum electrodynamics (QED) radiative corrections in a simple manner in atoms, ions, and molecules over the range 10<=Z<=120, where Z is the nuclear charge. Calculations are performed for binding energy shifts to the lowest valence s, p, and d waves over the series of alkali atoms Na to E119. The high accuracy of the radiative potential method is demonstrated by comparison with rigorous QED calculations in frozen atomic potentials, with deviations on the level of 1%. The many-body effects of core relaxation and second- and higher-order perturbation theory on the interaction of the valence electron with the core are calculated. The inclusion of many-body effects tends to increase the size of the shifts, with the enhancement particularly significant for d waves; for K to E119, the self-energy shifts for d waves are only an order of magnitude smaller than the s-wave shifts. It is shown th...

  16. Exchange-correlation interaction and AO-hybridization of alkali-metal atomic clusters.

    Science.gov (United States)

    Liu, Xuan; Ito, Haruhiko; Torikai, Eiko

    2013-09-19

    The structure of alkali-metal atomic clusters is optimized with B3P86 hybrid functional for the highest spin state as well as with B3LYP hybrid functional for the lowest spin state. A dramatic change from plane to solid occurs in the highest spin state when the number of constituent atoms is four. The binding, exchange, and correlation energies are evaluated for both the highest and lowest spin states. Next, we explore the dependence of the exchange and correlation energies on the binding energy. The exchange energy contributes to the formation of the highest spin clusters, whereas the correlation energy contributes to the formation of the lowest spin clusters. The highest spin clusters are most stable when the exchange energy is a minimum. Then, to see why the ferromagnetic bond among spin-aligned identical atoms arises against Pauli exclusion principle, we estimate the mixing ratio of p orbitals in molecular orbitals. The s-p hybridization increases the binding energy in absolute value due to the extensive overlap of molecular orbitals and leads to generation of the highest spin clusters.

  17. Atomic many-body effects and Lamb shifts in alkali metals

    Science.gov (United States)

    Ginges, J. S. M.; Berengut, J. C.

    2016-05-01

    We present a detailed study of the radiative potential method [V. V. Flambaum and J. S. M. Ginges, Phys. Rev. A 72, 052115 (2005), 10.1103/PhysRevA.72.052115], which enables the accurate inclusion of quantum electrodynamics (QED) radiative corrections in a simple manner in atoms and ions over the range 10 ≤Z ≤120 , where Z is the nuclear charge. Calculations are performed for binding energy shifts to the lowest valence s , p , and d waves over the series of alkali-metal atoms Na to E119. The high accuracy of the radiative potential method is demonstrated by comparison with rigorous QED calculations in frozen atomic potentials, with deviations on the level of 1%. The many-body effects of core relaxation and second- and higher-order perturbation theory on the interaction of the valence electron with the core are calculated. The inclusion of many-body effects tends to increase the size of the shifts, with the enhancement particularly significant for d waves; for K to E119, the self-energy shifts for d waves are only an order of magnitude smaller than the s -wave shifts. It is shown that taking into account many-body effects is essential for an accurate description of the Lamb shift.

  18. Research Investigation Directed Toward Extending the Useful Range of the Electromagnetic Spectrum. [atomic spectra and electronic structure of alkali metals

    Science.gov (United States)

    Hartmann, S. R.; Happer, W.

    1974-01-01

    The report discusses completed and proposed research in atomic and molecular physics conducted at the Columbia Radiation Laboratory from July 1972 to June 1973. Central topics described include the atomic spectra and electronic structure of alkali metals and helium, molecular microwave spectroscopy, the resonance physics of photon echoes in some solid state systems (including Raman echoes, superradiance, and two photon absorption), and liquid helium superfluidity.

  19. Shifts in the ESR spectra of alkali-metal atoms (Li, Na, K, Rb) on helium nanodroplets.

    Science.gov (United States)

    Hauser, Andreas W; Gruber, Thomas; Filatov, Michael; Ernst, Wolfgang E

    2013-03-18

    He-droplet-induced changes of the hyperfine structure constants of alkali-metal atoms are investigated by a combination of relativistically corrected ab initio methods with a simulation of the helium density distribution based on He density functional theory. Starting from an accurate description of the variation of the hyperfine structure constant in the M-He diatomic systems (M=Li, Na, K, Rb) as a function of the interatomic distance we simulate the shifts induced by droplets of up to 10,000 (4)He atoms. All theoretical predictions for the relative shifts in the isotropic hyperfine coupling constants of the alkali-metal atoms attached to helium droplets of different size are then tied to a single, experimentally derived parameter of Rb.

  20. Study on water-dispersible colloids in saline-alkali soils by atomic force microscopy and spectrometric methods.

    Science.gov (United States)

    Liu, Zhiguo; Xu, Fengjie; Zu, Yuangang; Meng, Ronghua; Wang, Wenjie

    2016-06-01

    Recent studies have revealed that water-dispersible colloids play an important role in the transport of nutrients and contaminants in soils. In this study, water-dispersible colloids extracted from saline-alkali soils have been characterized by atomic force microscopy (AFM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and UV absorption spectra. AFM observation indicated that the water-dispersible colloids contain some large plates and many small spherical particles. XRD, XPS, and UV absorption measurement revealed that the water-dispersible colloids are composed of kaolinite, illite, calcite, quartz and humic acid. In addition, UV absorption measurement demonstrated that the humic acids are associated with clay minerals. Water-dispersible colloids in the saline-alkali soils after hydrolyzed polymaleic anhydride treatment and an agricultural soil (nonsaline-alkali soil) were also investigated for comparison. The obtained results implied that the saline-alkali condition facilitates the formation of a large quantity of colloids. The use of AFM combined with spectrometric methods in the present study provides new knowledge on the colloid characteristics of saline-alkali soils. Microsc. Res. Tech. 79:525-531, 2016. © 2016 Wiley Periodicals, Inc.

  1. Properties of alkali metal atoms deposited on a MgO surface: a systematic experimental and theoretical study.

    Science.gov (United States)

    Finazzi, Emanuele; Di Valentin, Cristiana; Pacchioni, Gianfranco; Chiesa, Mario; Giamello, Elio; Gao, Hongjun; Lian, Jichun; Risse, Thomas; Freund, Hans-Joachim

    2008-01-01

    The adsorption of small amounts of alkali metal atoms (Li, Na, K, Rb, and Cs) on the surface of MgO powders and thin films has been studied by means of EPR spectroscopy and DFT calculations. From a comparison of the measured and computed g values and hyperfine coupling constants (hfccs), a tentative assignment of the preferred adsorption sites is proposed. All atoms bind preferentially to surface oxide anions, but the location of these anions differs as a function of the deposition temperature and alkali metal. Lithium forms relatively strong bonds with MgO and can be stabilized at low temperatures on terrace sites. Potassium interacts very weakly with MgO and is stabilized only at specific sites, such as at reverse corners where it can interact simultaneously with three surface oxygen atoms (rubidium and cesium presumably behave in the same way). Sodium forms bonds of intermediate strength and could, in principle, populate more than a single site when deposited at room temperature. In all cases, large deviations of the hfccs from the gas-phase values are observed. These reductions in the hfccs are due to polarization effects and are not connected to ionization of the alkali metal, which would lead to the formation of an adsorbed cation and a trapped electron. In this respect, hydrogen atoms behave completely differently. Under similar conditions, they form (H(+))(e(-)) pairs. The reasons for this different behavior are discussed.

  2. Effects of dipole-dipole interaction between cigar-shaped BECs of cold alkali atoms: towards inverse-squared interactions.

    Science.gov (United States)

    Yu, Yue; Luo, Zhuxi; Wang, Ziqiang

    2014-07-30

    We show that the dipole-dipole coupling between Wannier modes in cigar-shaped Bose-Einstein condensates (BECs) is significantly enhanced while the short-range coupling is strongly suppressed. As a result, the dipole-dipole interaction can become the dominant interaction between ultracold alkali Bose atoms. In the long length limit of a cigar-shaped BEC, the resulting effective one-dimensional models possess an effective inverse squared interacting potential, the Calogero-Sutherland potential, which plays a fundamental role in many fields of contemporary physics; but its direct experimental realization has been a challenge for a long time. We propose to realize the Calogero-Sutherland model in ultracold alkali Bose atoms and study the effects of the dipole-dipole interaction.

  3. Quantum control of the hyperfine-coupled electron and nuclear spins in alkali-metal atoms

    Science.gov (United States)

    Merkel, Seth T.; Jessen, Poul S.; Deutsch, Ivan H.

    2008-08-01

    We study quantum control of the full hyperfine manifold in the ground-electronic state of alkali-metal atoms based on applied radio frequency and microwave fields. Such interactions should allow essentially decoherence-free dynamics and the application of techniques for robust control developed for NMR spectroscopy. We establish the conditions under which the system is controllable in the sense that one can generate an arbitrary unitary map on the system. We apply this to the case of Cs133 with its d=16 dimensional Hilbert space of magnetic sublevels in the 6S1/2 state, and design control wave forms that generate an arbitrary target state from an initial fiducial state. We develop a generalized Wigner function representation for this space consisting of the direct sum of two irreducible representations of SU(2), allowing us to visualize these states. The performance of different control scenarios is evaluated based on the ability to generate a high-fidelity operation in an allotted time with the available resources. We find good operating points commensurate with modest laboratory requirements.

  4. Alkali metal and simple gas atom adsorption and coadsorption on transition metal surfaces

    CERN Document Server

    Norris, A G

    2000-01-01

    system is formed by adsorption of potassium or cesium on the Ni(100)c(2x2)-O overlayer. The difficulty of the structural fit is compounded' by the size of the unit cell. In this study, Anomalous Scattering was used to investigate whether there is a contribution from the nickel substrate to the reconstruction. Measurements of the fractional order rods at 10 eV and 200 eV below the nickel K edge (8333 eV) showed no discernible differences and involvement of the nickel substrate in the reconstruction can be eliminated. Alkali metal coadsorption systems represent a step along the pathway from simple model adsorbate overlayers to more technologically relevant real systems. Such is their complexity, however, that very few systems have been solved structurally. Presented here are SXRD and STM investigations of two such systems. The first study involves potassium adsorption on the Ni(100)(2x2)p4g-N surface, where a clock reconstruction is present with the nickel substrate atoms rotated in alternate clockwise and anti...

  5. Collisions of alkali-metal atoms Cs and Rb in the ground state. Spin exchange cross sections

    Science.gov (United States)

    Kartoshkin, V. A.

    2016-09-01

    Collisions of alkali-metal atoms 133Cs and 85Rb in the ground state are considered in the energy interval of 10-4-10-2 au. Complex cross sections of the spin exchange, which allow one to calculate the processes of polarization transfer and the relaxation times, as well as the magnetic resonance frequency shifts caused by spin exchange Cs-Rb collisions, are obtained.

  6. NONLINEAR OPTICS: Stimulated resonant hyper-Raman scattering of light by polaritons in alkali metal vapors

    Science.gov (United States)

    Galaĭchuk, Yu A.; Yashkir, Yu N.

    1989-12-01

    A theory is developed for the calculation of the gain g due to stimulated resonant hyper-Raman scattering of light by polaritons in gaseous media. It is shown that throughout the tuning range of the pump frequency (including one- and two-photon resonances) a maximum of g corresponds to a dispersion curve of polaritons plotted ignoring attenuation. Theoretical results are used to analyze characteristics of hyper-Raman scattering in sodium vapor. It is shown that under normal experimental conditions the splitting of polariton branches is considerable (amounting to tens of reciprocal centimeters on the frequency scale and several angular degrees). The value of g is estimated for two-photon resonances in the case when the pump frequency is tunable in a wide range. The optimal conditions for stimulated hyper-Raman scattering are identified.

  7. Photoionization in alkali lasers.

    Science.gov (United States)

    Knize, R J; Zhdanov, B V; Shaffer, M K

    2011-04-11

    We have calculated photoionization rates in alkali lasers. The photoionization of alkali atoms in the gain medium of alkali lasers can significantly degrade the laser performance by reducing the neutral alkali density and with it the gain. For a ten atmosphere Rb laser and a Cs exciplex laser, the photoionization induced alkali atom loss rates are greater than 10(5) sec(-1). These high loss rates will quickly deplete the neutral alkali density, reducing gain, and may require fast, possibly, supersonic flow rates to sufficiently replenish the neutral medium for CW operation.

  8. Two-photon photoemission investigation of electronic and dynamical properties of alkali atoms adsorbed on noble metal surfaces

    Science.gov (United States)

    Sametoglu, Vahit

    We present a systematic time-resolved two-photon photoemission study of the electronic and dynamical properties of Li through Cs adsorbed on Cu(111) and Ag(111) surfaces. A fundamental problem in surface science is how to describe the electronic structure of a chemisorption interface based on the intrinsic properties of the interacting materials. Because of their simple s-electron structure, elements of the alkali atom group comprise paradigmatic adsorbates in many theories of chemisorption, whereas the complementary experimental studies are sparse and incomplete. Through a combination of spectroscopic and femtosecond time-resolved surface measurements, we are able to probe systematically the binding energies, symmetries, and electron and nuclear relaxation dynamics of the initially unoccupied alkali atom resonances. As a prelude, we study the two-photon photoemission process occurring at the bare Ag(111) surface. We develop a quantitative model for two-photon photoemission process, where the nonresonant and k-dependent two-photon absorption between the lower and upper sp-bands is modeled by the optical Bloch equations, and the angle-dependent intensities are described by the Fresnel equations. Our two-photon photoemission spectra of Li through Cs chemisorbed Cu(111) and Ag(111) surfaces reveal two resonances with the m = 0 and m = +/-1 symmetry ('m' is the projection of the orbital angular momentum 'l' onto the surface plane). For the m = 0 resonance, which is derived from the hybridization of the ns and npz orbitals of alkali atoms, we find a binding energy of 1.84--1.99 eV below the vacuum level, which is independent of the alkali atom period, and tunes with coverage in a universal manner. At 0.3--0.7 eV higher energy, we discover and identify the m = +/-1 resonance by its characteristic angular intensity distribution, which derives from the antisymmetry of the npx and npy orbitals. We implement a quantitative model for the alkali atom chemisorption based on the

  9. Size-specific interaction of alkali metal ions in the solvation of M+-benzene clusters by Ar atoms.

    Science.gov (United States)

    Huarte-Larrañaga, F; Aguilar, A; Lucas, J M; Albertí, M

    2007-08-23

    The size-specific influence of the M+ alkali ion (M = Li, Na, K, Rb, and Cs) in the solvation process of the M+-benzene clusters by Ar atoms is investigated by means of molecular dynamic simulations. To fully understand the behavior observed in M+-bz-Ar(n) clusters, solvation is also studied in clusters containing either M+ or benzene only. The potential energy surfaces employed are based on a semiempirical bond-atom decomposition, which has been developed previously by some of the authors. The outcome of the dynamics is analyzed by employing radial distribution functions, studying the evolution of the distances between the Ar atoms and the alkali ion M+ or the benzene molecule for all M+-bz-Ar(n) clusters. For all members, in the M+-bz series, the benzene molecule (bz) is found to remain strongly bound to M+ even in the presence of solvent atoms. The radial distribution functions for the heavier clusters (K+-bz, Rb+-bz, and Cs+-bz), are found to be different than for the lighter (Na+-bz and Li+-bz) ones.

  10. One- and two-photon spectroscopy of highly excited states of alkali-metal atoms on helium nanodroplets.

    Science.gov (United States)

    Pifrader, Alexandra; Allard, Olivier; Auböck, Gerald; Callegari, Carlo; Ernst, Wolfgang E; Huber, Robert; Ancilotto, Francesco

    2010-10-28

    Alkali-metal atoms captured on the surface of superfluid helium droplets are excited to high energies (≈3 eV) by means of pulsed lasers, and their laser-induced-fluorescence spectra are recorded. We report on the one-photon excitation of the (n+1)p←ns transition of K, Rb, and Cs (n=4, 5, and 6, respectively) and on the two-photon one-color excitation of the 5d←5s transition of Rb. Gated-photon-counting measurements are consistent with the relaxation rates of the bare atoms, hence consistent with the reasonable expectation that atoms quickly desorb from the droplet and droplet-induced relaxation need not be invoked.

  11. Visualizing the Solute Vaporization Interference in Flame Atomic Absorption Spectroscopy

    Science.gov (United States)

    Dockery, Christopher R.; Blew, Michael J.; Goode, Scott R.

    2008-01-01

    Every day, tens of thousands of chemists use analytical atomic spectroscopy in their work, often without knowledge of possible interferences. We present a unique approach to study these interferences by using modern response surface methods to visualize an interference in which aluminum depresses the calcium atomic absorption signal. Calcium…

  12. Studies of Pressure-Broadening of Alkali Atom Resonance Lines for Modeling Atmospheres of Extrasolar Giant Planets and Brown Dwarfs

    Science.gov (United States)

    Kirby, Kate; Babb, J.; Yoshino, K.

    2004-01-01

    In L-dwarfs and T-dwarfs the resonance lines of sodium and potassium are so profoundly pressure-broadened that their wings extend several hundred nanometers from line center. With accurate knowledge of the line profiles as a function of temperature and pressure: such lines can prove to be valuable diagnostics of the atmospheres of such objects. We have initiated a joint program of theoretical and experimental research to study the line-broadening of alkali atom resonance lines due to collisions with species such as helium and molecular hydrogen. Although potassium and sodium are the alkali species of most interest in the atmospheres of cool brown dwarfs and extrasolar giant planets, some of our theoretical focus this year has involved the calculation of pressure-broadening of lithium resonance lines by He, as a test of a newly developed suite of computer codes. In addition, theoretical calculations have been carried out to determine the leading long range van der Waals coefficients for the interactions of ground and excited alkali metal atoms with helium atoms, to within a probable error of 2%. Such data is important in determining the behavior of the resonance line profiles in the far wings. Important progress has been made on the experimental aspects of the program since the arrival of a postdoctoral fellow in September. A new absorption cell has been designed, which incorporates a number of technical improvements over the previous cell, including a larger cell diameter to enhance the signal, and fittings which allow for easier cleaning, thereby significantly reducing the instrument down-time.

  13. Prospects for sympathetic cooling of polar molecules: NH with alkali-metal and alkaline-earth atoms--a new hope.

    Science.gov (United States)

    Soldán, Pavel; Zuchowski, Piotr S; Hutson, Jeremy M

    2009-01-01

    We explore the potential energy surfaces for NH molecules interacting with alkali-metal and alkaline-earth atoms using highly correlated ab initio electronic structure calculations. The surfaces for interaction with alkali-metal atoms have deep wells dominated by covalent forces. The resulting strong anisotropies will produce strongly inelastic collisions. The surfaces for interaction with alkaline-earth atoms have shallower wells that are dominated by induction and dispersion forces. For Be and Mg the anisotropy is small compared to the rotational constant of NH, so that collisions will be relatively weakly inelastic. Be and Mg are thus promising coolants for sympathetic cooling of NH to the ultracold regime.

  14. Sensitive determination of the spin polarization of optically pumped alkali-metal atoms using near-resonant light

    Science.gov (United States)

    Ding, Zhichao; Long, Xingwu; Yuan, Jie; Fan, Zhenfang; Luo, Hui

    2016-09-01

    A new method to measure the spin polarization of optically pumped alkali-metal atoms is demonstrated. Unlike the conventional method using far-detuned probe light, the near-resonant light with two specific frequencies was chosen. Because the Faraday rotation angle of this approach can be two orders of magnitude greater than that with the conventional method, this approach is more sensitive to the spin polarization. Based on the results of the experimental scheme, the spin polarization measurements are found to be in good agreement with the theoretical predictions, thereby demonstrating the feasibility of this approach.

  15. The optical pumping of alkali atoms using coherent radiation from semi-conductor injection lasers and incoherent radiation from resonance lamps

    Science.gov (United States)

    Singh, G.

    1973-01-01

    An experimental study for creating population differences in the ground states of alkali atoms (Cesium 133) is presented. Studies made on GaAs-junction lasers and the achievement of population inversions among the hyperfine levels in the ground state of Cs 133 by optically pumping it with radiation from a GaAs diode laser. Laser output was used to monitor the populations in the ground state hyperfine levels as well as to perform the hyperfine pumping. A GaAs laser operated at about 77 K was used to scan the 8521 A line of Cs 133. Experiments were performed both with neon-filled and with paraflint-coated cells containing the cesium vapor. Investigations were also made for the development of the triple resonance coherent pulse technique and for the detection of microwave induced hyperfine trasistions by destroying the phase relationships produced by a radio frequency pulse. A pulsed cesium resonance lamp developed, and the lamp showed clean and reproducible switching characteristics.

  16. High quality anti-relaxation coating material for alkali atom vapor cells

    DEFF Research Database (Denmark)

    Balabas, M.V.; Jensen, Kasper; Wasilewski, Wojciech

    2010-01-01

    Brain aging is associated with synaptic decline and synaptic function is highly dependent on mitochondria. Increased levels of oxidative DNA base damage and accumulation of mitochondrial DNA (mtDNA) mutations or deletions lead to mitochondrial dysfunction, playing an important role in the aging p...

  17. QED radiative corrections and many-body effects in atoms: the Uehling potential and shifts in alkali metals

    CERN Document Server

    Ginges, J S M

    2015-01-01

    We consider the largest (Uehling) contribution to the one-loop vacuum polarization correction to the binding energies in neutral alkali atoms, from Na through to the superheavy element E119. We use the relativistic Hartree-Fock method to demonstrate the importance of core relaxation effects. These effects are sizeable everywhere, though particularly important for orbitals with angular momentum quantum number l > 0. For d waves, the Uehling shift is enhanced by many orders of magnitude: for Cs the enhancement is more than four orders of magnitude and for the lighter alkali atoms it is even larger. We also study the effects of second- and higher-order many-body perturbation theory on the valence level shifts through inclusion of the correlation potential. The many-body enhancement mechanisms that operate in the case of the Uehling potential apply also to the case of the larger QED self-energy radiative corrections. The huge enhancement for d level shifts makes high-precision studies of transition frequencies in...

  18. Measuring the spin polarization of alkali-metal atoms using nuclear magnetic resonance frequency shifts of noble gases

    Directory of Open Access Journals (Sweden)

    X. H. Liu

    2015-10-01

    Full Text Available We report a novel method of measuring the spin polarization of alkali-metal atoms by detecting the NMR frequency shifts of noble gases. We calculated the profile of 87Rb D1 line absorption cross sections. We then measured the absorption profile of the sample cell, from which we calculated the 87Rb number densities at different temperatures. Then we measured the frequency shifts resulted from the spin polarization of the 87Rb atoms and calculated its polarization degrees at different temperatures. The behavior of frequency shifts versus temperature in experiment was consistent with theoretical calculation, which may be used as compensative signal for the NMRG closed-loop control system.

  19. Measuring the spin polarization of alkali-metal atoms using nuclear magnetic resonance frequency shifts of noble gases

    Energy Technology Data Exchange (ETDEWEB)

    Liu, X. H.; Luo, H.; Qu, T. L., E-mail: qutianliang@nudt.edu.cn; Yang, K. Y.; Ding, Z. C. [College of Optoelectronic Science and Engineering, National University of Defense Technology, Changsha 410073 (China)

    2015-10-15

    We report a novel method of measuring the spin polarization of alkali-metal atoms by detecting the NMR frequency shifts of noble gases. We calculated the profile of {sup 87}Rb D1 line absorption cross sections. We then measured the absorption profile of the sample cell, from which we calculated the {sup 87}Rb number densities at different temperatures. Then we measured the frequency shifts resulted from the spin polarization of the {sup 87}Rb atoms and calculated its polarization degrees at different temperatures. The behavior of frequency shifts versus temperature in experiment was consistent with theoretical calculation, which may be used as compensative signal for the NMRG closed-loop control system.

  20. Radio-frequency Electrometry Using Rydberg Atoms in Vapor Cells: Towards the Shot Noise Limit

    Science.gov (United States)

    Kumar, Santosh; Fan, Haoquan; Jahangiri, Akbar; Kuebler, Harald; Shaffer, James P.; 5. Physikalisches Institut, Universitat Stuttgart, Germany Collaboration

    2016-05-01

    Rydberg atoms are a promising candidate for radio frequency (RF) electric field sensing. Our method uses electromagnetically induced transparency with Rydberg atoms in vapor cells to read out the effect that the RF electric field has on the Rydberg atoms. The method has the potential for high sensitivity (pV cm-1 Hz- 1 / 2) and can be self-calibrated. Some of the main factors limiting the sensitivity of RF electric field sensing from reaching the shot noise limit are the residual Doppler effect and the sensitivity of the optical read-out using the probe laser. We present progress on overcoming the residual Doppler effect by using a new multi-photon scheme and reaching the shot noise detection limit using frequency modulated spectroscopy. Our experiments also show promise for studying quantum optical effects such as superradiance in vapor cells using Rydberg atoms. This work is supported by DARPA, ARO, and NRO.

  1. Quantum Zeno effect in atomic spin-exchange collisions

    OpenAIRE

    Kominis, I. K.

    2008-01-01

    The suppression of spin-exchange relaxation in dense alkali-metal vapors discovered in 1973 and governing modern atomic magnetometers is here reformulated in terms of quantum measurement theory and the quantum Zeno effect. This provides a new perspective of understanding decoherence in spin-polarized atomic vapors.

  2. Quantum Zeno effect in atomic spin-exchange collisions

    Energy Technology Data Exchange (ETDEWEB)

    Kominis, I.K. [Department of Physics, University of Crete, Heraklion 71103 (Greece); Institute of Electronic Structure and Laser, Foundation for Research and Technology, Heraklion 71110 (Greece)], E-mail: ikominis@iesl.forth.gr

    2008-07-07

    The suppression of spin-exchange relaxation in dense alkali-metal vapors discovered in 1973 and governing modern atomic magnetometers is here reformulated in terms of quantum measurement theory and the quantum Zeno effect. This provides a new perspective of understanding decoherence in spin-polarized atomic vapors.

  3. Vapor generation – atomic spectrometric techniques. Expanding frontiers through specific-species preconcentration. A review

    Energy Technology Data Exchange (ETDEWEB)

    Gil, Raúl A.; Pacheco, Pablo H.; Cerutti, Soledad [Área de Química Analítica, Facultad de Química Bioquímica y Farmacia, Universidad Nacional de San Luis, Ciudad de San Luis 5700 (Argentina); Instituto de Química de San Luis, INQUISAL, Centro Científico-Tecnológico de San Luis (CCT-San Luis), Consejo Nacional de Investigaciones Científicas y Universidad Nacional de San Luis, Ciudad de San Luis 5700 (Argentina); Martinez, Luis D., E-mail: ldm@unsl.edu.ar [Área de Química Analítica, Facultad de Química Bioquímica y Farmacia, Universidad Nacional de San Luis, Ciudad de San Luis 5700 (Argentina); Instituto de Química de San Luis, INQUISAL, Centro Científico-Tecnológico de San Luis (CCT-San Luis), Consejo Nacional de Investigaciones Científicas y Universidad Nacional de San Luis, Ciudad de San Luis 5700 (Argentina)

    2015-05-22

    This article reviews 120 articles found in SCOPUS and specific Journal cites corresponding to the terms ‘preconcentration’; ‘speciation’; ‘vapor generation techniques’ and ‘atomic spectrometry techniques’ in the last 5 years. - Highlights: • Recent advances in vapor generation and atomic spectrometry were reviewed. • Species-specific preconcentration strategies after and before VG were discussed. • New preconcentration and speciation analysis were evaluated within this framework. - Abstract: We review recent progress in preconcentration strategies associated to vapor generation techniques coupled to atomic spectrometric (VGT-AS) for specific chemical species detection. This discussion focuses on the central role of different preconcentration approaches, both before and after VG process. The former was based on the classical solid phase and liquid–liquid extraction procedures which, aided by automation and miniaturization strategies, have strengthened the role of VGT-AS in several research fields including environmental, clinical, and others. We then examine some of the new vapor trapping strategies (atom-trapping, hydride trapping, cryotrapping) that entail improvements in selectivity through interference elimination, but also they allow reaching ultra-low detection limits for a large number of chemical species generated in conventional VG systems, including complete separation of several species of the same element. This review covers more than 100 bibliographic references from 2009 up to date, found in SCOPUS database and in individual searches in specific journals. We finally conclude by giving some outlook on future directions of this field.

  4. A geração química de vapor em espectrometria atômica Chemical vapor generation in atomic spectrometry

    Directory of Open Access Journals (Sweden)

    Iracema Takase

    2002-12-01

    Full Text Available The historical development of atomic spectrometry techniques based on chemical vapor generation by both batch and flow injection sampling formats is presented. Detection via atomic absorption spectrometry (AAS, microwave induced plasma optical emission spectrometry (MIP-OES, inductively coupled plasma optical emission spectrometry (ICP-OES , inductively coupled plasma mass spectrometry (ICP-MS and furnace atomic nonthermal excitation spectrometry (FANES are considered. Hydride generation is separately considered in contrast to other methods of generation of volatile derivatives. Hg ¾ CVAAS (cold vapor atomic absorption spectrometry is not considered here. The current state-of-the-art, including extension, advantages and limitations of this approach is discussed.

  5. Comparisons between adsorption and diffusion of alkali, alkaline earth metal atoms on silicene and those on silicane: Insight from first-principles calculations

    Science.gov (United States)

    Bo, Xu; Huan-Sheng, Lu; Bo, Liu; Gang, Liu; Mu-Sheng, Wu; Chuying, Ouyang

    2016-06-01

    The adsorption and diffusion behaviors of alkali and alkaline-earth metal atoms on silicane and silicene are both investigated by using a first-principles method within the frame of density functional theory. Silicane is staler against the metal adatoms than silicene. Hydrogenation makes the adsorption energies of various metal atoms considered in our calculations on silicane significantly lower than those on silicene. Similar diffusion energy barriers of alkali metal atoms on silicane and silicene could be observed. However, the diffusion energy barriers of alkali-earth metal atoms on silicane are essentially lower than those on silicene due to the small structural distortion and weak interaction between metal atoms and silicane substrate. Combining the adsorption energy with the diffusion energy barriers, it is found that the clustering would occur when depositing metal atoms on perfect hydrogenated silicene with relative high coverage. In order to avoid forming a metal cluster, we need to remove the hydrogen atoms from the silicane substrate to achieve the defective silicane. Our results are helpful for understanding the interaction between metal atoms and silicene-based two-dimensional materials. Project supported by the Natural Science Foundation of Jiangxi Province, China (Grant Nos. 20152ACB21014, 20151BAB202006, and 20142BAB212002) and the Fund from the Jiangxi Provincial Educational Committee, China (Grant No. GJJ14254). Bo Xu is also supported by the Oversea Returned Project from the Ministry of Education, China.

  6. Ultrathin atomic vapor film transmission spectroscopy: analysis of Dicke narrowing structure

    Institute of Scientific and Technical Information of China (English)

    Yuanyuan Li; Yanpeng Zhang; Chenli Gan

    2005-01-01

    Transmission sub-Doppler spectroscopy with confined atomic vapor film between two dielectric walls is theoretically studied. Because of atoms flying from wall to wall, where they get de-excited, the atomfield interaction time is anisotropic so that the contribution of slow atoms is enhanced, a sub-Doppler transmission spectroscopy (Dicke narrowing effect) can be obtained when the thickness of the film is much small or comparable with the wavelength even at small angle oblique incidence. It is feasible to get a sub-Doppler structure in a new region (L <λ/4) in experiments.

  7. The combination of atomic force microscopy and sugar analysis to evaluate alkali-soluble Canna edulis Ker pectin.

    Science.gov (United States)

    Zhang, Juan; Cui, Junhui; Xiao, Lin; Wang, Zhengwu

    2014-08-01

    Alkali-soluble pectin, which has been extracted from Canna edulis Ker, was characterized by single sugar determination and atomic force microscopy (AFM). The results indicated that the amounts of four predominant sugars including arabinose (Ara), glucose (Glc), galactose (Gal) and galacturonic acid (GalA) significantly decreased during the process of mild acid hydrolysis. The decreasing rates of these four sugars followed a sequential order of Ara>Gal>Glc>GalA. The homogalacturonan (HG) chain present in pectin, and the quantity of branched material is greater than the sample containing the main neutral sugars. The results indicated that the neutral sugar and HG side chains are attached to pectin as part of the rhamnogalacturonan I (RGI) complex. Moreover, hydrolysis leads to the reduction of mean lengths of backbone and branch, as well as the number/weight-average molecular weight. Meanwhile, the amount of short chain fractions increased during hydrolysis. Furthermore, the decrease of the polymerization degree of alkali-soluble C. edulis pectin as a function of the hydrolysis time could be described by a first-order exponential decay function.

  8. Cascade correlation-enhanced Raman scattering in atomic vapors

    Science.gov (United States)

    Ma, Hong-Mei; Chen, Li-Qing; Yuan, Chun-Hua

    2016-12-01

    A new Raman process can be used to realize efficient Raman frequency conversion by coherent feedback at low light intensity [Chen B, Zhang K, Bian C L, Qiu C, Yuan C H, Chen L Q, Ou Z Y, and Zhang W P 2013 Opt. Express 21, 10490]. We present a theoretical model to describe this enhanced Raman process, termed as cascade correlation-enhanced Raman scattering, which is a Raman process injected by a seeded light field. It is correlated with the initially prepared atomic spin excitation and driven by the quasi-standing-wave pump fields, and the processes are repeated until the Stokes intensities are saturated. Such an enhanced Raman scattering may find applications in quantum information, nonlinear optics, and optical metrology due to its simplicity. Project supported by the National Natural Science Foundation of China (Grant Nos. 11474095, 11274118, and 91536114).

  9. Redistribution of light frequency by multiple scattering in a resonant atomic vapor

    CERN Document Server

    Carvalho, J C de A; Oriá, M; Chevrollier, M; de Silans, T Passerat

    2015-01-01

    The propagation of light in a resonant atomic vapor can \\textit{a priori} be thought of as a multiple scattering process, in which each scattering event redistributes both the direction and the frequency of the photons. Particularly, the frequency redistribution may result in L\\'evy flights of photons, directly affecting the transport properties of light in a resonant atomic vapor and turning this propagation into a superdifusion process. Here, we report on a Monte-Carlo simulation developed to study the evolution of the spectrum of the light in a resonant thermal vapor. We observe the gradual change of the spectrum and its convergence towards a regime of Complete Frequency Redistribution as the number of scattering events increases. We also analyse the probability density function of the step length of photons between emissions and reabsorptions in the vapor, which governs the statistics of the light diffusion. We observe two different regime in the light transport: superdiffusive when the vapor is excited n...

  10. Light scattering studies of solids and atomic vapors

    Energy Technology Data Exchange (ETDEWEB)

    Chiang, T.C.

    1978-09-01

    The general technique of light scattering and luminescence was used to study the properties of a number of material systems. First, multi-phonon resonant Raman scattering up to four phonons in GaSe and one- and two-phonon resonant Raman scattering in the mixed GaS/sub x/Se/sub 1-x/ crystals with x < or = 0.23 were investigated. Second, the observation of one-phonon resonant Raman scattering in HfS/sub 2/ is reported. The result is used to determine the position of the direct gap of HfS/sub 2/. Third, the first observation of the ..pi..-polarized one-magnon luminescence sideband of the /sup 4/T/sub lg/ (/sup 4/G) ..-->.. /sup 6/A/sub lg/(/sup 6/S) excitonic transition in antiferromagnetic MnF/sub 2/ is presented. An effective temperature of the crystal is deduced from the simultaneously observed anti-Stokes sideband emission. Multi-magnon (< or = 7) excitonic luminescence sidebands were also observed in MnF/sub 2/, KMnF/sub 2/, and RbMnF/sub 3/ using pulsed excitation and detection. A simple model based on two-ion local exchange is proposed to explain the results qualitatively. Fourth, the first observation of two-magnon resonant Raman scattering in MnF/sub 2/ around the magnon sidebands is reported. A simple theoretical description explains the experimental observations. Fifth, a detailed theory of exciton-exciton interaction in MnF/sub 2/ is developed to explain and to predict the experimental results on two-exciton absorption, high level excitation, and exciton--exciton scattering. Sixth, Brillouin scattering was used to obtain the five independent elastic constants of the layered compound GaSe. The results show clear elastic anisotropy of the crystal. Resonant Brillouin scattering near the absorption edge was also studied, but no resonant enhancement was found. Seventh, two-photon parametric scattering in sodium vapor was studied. Phase matching angles and scattering cross sections are calculated for a given set of experimental conditions.

  11. The Trapping and Cooling of Alkalis Metal Atoms%碱金属原子的囚禁与冷却

    Institute of Scientific and Technical Information of China (English)

    邓海明; 李璋

    2012-01-01

      描述了如何利用激光以及磁场构建光学粘胶、激光阱、磁阱、磁光阱等实现对碱金属的囚禁与冷却,旨在明晰的呈现BEC实验实现的关键技术、物理原理以及各种装置的优缺点。%  This essay describes how to use laser and magnetic field to construct optical molasses ,laser trap ,mag-netic trap and magneto -optical trap to trap and cool alkali-metal atoms .It presents clearly the key experimental technologies of Bose-Einstein condensate ,the physical principle and the relative advantages and disadvantages of different equipments .

  12. Temporal intensity correlation of light scattered by a hot atomic vapor

    CERN Document Server

    Dussaux, A; Guerin, W; Alibart, O; Tanzilli, S; Vakili, F; Kaiser, R

    2016-01-01

    We present temporal intensity correlation measurements of light scattered by a hot atomic vapor. Clear evidence of photon bunching is shown at very short time-scales (ns) imposed by the Doppler broadening of the hot vapor. Moreover, we demonstrate that some relevant information about the scattering process, such as the ratio of single to multiple scattering, can be deduced from the measured intensity correlation function. These measurements confirm the interest of temporal intensity correlation measurements to access non-trivial spectral features, with potential applications in astrophysics.

  13. Temperature Sensitivity of an Atomic Vapor Cell-Based Dispersion-Enhanced Optical Cavity

    Science.gov (United States)

    Myneni, K.; Smith, D. D.; Chang, H.; Luckay, H. A.

    2015-01-01

    Enhancement of the response of an optical cavity to a change in optical path length, through the use of an intracavity fast-light medium, has previously been demonstrated experimentally and described theoretically for an atomic vapor cell as the intracavity resonant absorber. This phenomenon may be used to enhance both the scale factor and sensitivity of an optical cavity mode to the change in path length, e.g. in gyroscopic applications. We study the temperature sensitivity of the on-resonant scale factor enhancement, S(sub o), due to the thermal sensitivity of the lower-level atom density in an atomic vapor cell, specifically for the case of the Rb-87 D(sub 2) transition. A semi-empirical model of the temperature-dependence of the absorption profile, characterized by two parameters, a(sub o)(T) and gamma(sub a)(T) allows the temperature-dependence of the cavity response, S(sub o)(T) and dS(sub o)/dT to be predicted over a range of temperature. We compare the predictions to experiment. Our model will be useful in determining the useful range for S(sub o), given the practical constraints on temperature stability for an atomic vapor cell.

  14. Demonstration of a Dual Alkali Rb/Cs Atomic Fountain Clock

    CERN Document Server

    Guéna, J; Laurent, Ph; Abgrall, M; Rovera, D; Lours, M; Santarelli, G; Tobar, M E; Bize, S; Clairon, A; 10.1109/TUFFC.2010.1461

    2013-01-01

    We report the operation of a dual Rb/Cs atomic fountain clock. 133Cs and 87Rb atoms are cooled, launched, and detected simultaneously in LNE-SYRTE's FO2 double fountain. The dual clock operation occurs with no degradation of either the stability or the accuracy. We describe the key features for achieving such a simultaneous operation. We also report on the results of the first Rb/Cs frequency measurement campaign performed with FO2 in this dual atom clock configuration, including a new determination of the absolute 87Rb hyperfine frequency.

  15. Ladder-type electromagnetically induced transparency using nanofiber-guided light in a warm atomic vapor

    CERN Document Server

    Jones, D E; Pittman, T B

    2015-01-01

    We demonstrate ladder-type electromagnetically induced transparency (EIT) using an optical nanofiber suspended in a warm rubidium vapor. The signal and control fields are both guided along the nanofiber, which enables strong nonlinear interactions with the surrounding atoms at relatively low powers. Transit-time broadening is found to be a significant EIT decoherence mechanism in this tightly-confined waveguiding geometry. Nonetheless, we observe significant EIT and controlled polarization rotation using control-field powers of only a few microWatts in this relatively robust warm-atom nanofiber system.

  16. Relative-intensity squeezing at audio frequencies using four-wave mixing in an atomic vapor

    CERN Document Server

    McCormick, C F; Lett, P D; Marino, A M

    2007-01-01

    We demonstrate the use of four-wave mixing in hot atomic vapor to generate up to -7.1 dB of measured relative-intensity squeezing. Due to its intrinsic simplicity, our system is strongly decoupled from environmental noise, and we observe more than -4 dB of squeezing down to frequencies as low as 5 kHz. This robust source of narrowband squeezed light may be useful for a variety of applications, such as coupling to atomic ensembles and enhancing the sensitivity of photothermal spectroscopy.

  17. Eigenmode description of Raman scattering in atomic vapors in the presence of decoherence

    OpenAIRE

    Kolodynski, Jan; Chwedenczuk, Jan; Wasilewski, Wojciech

    2012-01-01

    A theoretical model describing the Raman scattering process in atomic vapors is constructed. The treatment investigates the low-excitation regime suitable for modern experimental applications. Despite the incorporated decoherence effects (possibly mode dependent) it allows for a direct separation of the time evolution from the spatial degrees of freedom. The impact of noise on the temporal properties of the process is examined. The model is applied in two experimentally relevant situations of...

  18. Accurate van der Waals coefficients between fullerenes and fullerene-alkali atoms and clusters: Modified single-frequency approximation

    Science.gov (United States)

    Tao, Jianmin; Mo, Yuxiang; Tian, Guocai; Ruzsinszky, Adrienn

    2016-08-01

    Long-range van der Waals (vdW) interaction is critically important for intermolecular interactions in molecular complexes and solids. However, accurate modeling of vdW coefficients presents a great challenge for nanostructures, in particular for fullerene clusters, which have huge vdW coefficients but also display very strong nonadditivity. In this work, we calculate the coefficients between fullerenes, fullerene and sodium clusters, and fullerene and alkali atoms with the hollow-sphere model within the modified single-frequency approximation (MSFA). In the MSFA, we assume that the electron density is uniform in a molecule and that only valence electrons in the outmost subshell of atoms contribute. The input to the model is the static multipole polarizability, which provides a sharp cutoff for the plasmon contribution outside the effective vdW radius. We find that the model can generate C6 in excellent agreement with expensive wave-function-based ab initio calculations, with a mean absolute relative error of only 3 % , without suffering size-dependent error. We show that the nonadditivities of the coefficients C6 between fullerenes and C60 and sodium clusters Nan revealed by the model agree remarkably well with those based on the accurate reference values. The great flexibility, simplicity, and high accuracy make the model particularly suitable for the study of the nonadditivity of vdW coefficients between nanostructures, advancing the development of better vdW corrections to conventional density functional theory.

  19. Universal ultracold collision rates for polar molecules of two alkali-metal atoms.

    Science.gov (United States)

    Julienne, Paul S; Hanna, Thomas M; Idziaszek, Zbigniew

    2011-11-14

    Universal collision rate constants are calculated for ultracold collisions of two like bosonic or fermionic heteronuclear alkali-metal dimers involving the species Li, Na, K, Rb, or Cs. Universal collisions are those for which the short range probability of a reactive or quenching collision is unity such that a collision removes a pair of molecules from the sample. In this case, the collision rates are determined by universal quantum dynamics at very long range compared to the chemical bond length. We calculate the universal rate constants for reaction of the reactive dimers in their ground vibrational state v = 0 and for vibrational quenching of non-reactive dimers with v ≥ 1. Using the known dipole moments and estimated van der Waals coefficients of each species, we calculate electric field dependent loss rate constants for collisions of molecules tightly confined to quasi-two-dimensional geometry by a one-dimensional optical lattice. A simple scaling relation of the quasi-two-dimensional loss rate constants with dipole strength, trap frequency and collision energy is given for like bosons or like fermions. It should be possible to stabilize ultracold dimers of any of these species against destructive collisions by confining them in a lattice and orienting them with an electric field of less than 20 kV cm(-1).

  20. Enhanced light-vapor interactions and all optical switching in a chip scale micro-ring resonator coupled with atomic vapor

    CERN Document Server

    Stern, Liron; Mazurski, Noa; Levy, Uriel

    2016-01-01

    The coupling of atomic and photonic resonances serves as an important tool for enhancing light-matter interactions and enables the observation of multitude of fascinating and fundamental phenomena. Here, by exploiting the platform of atomic-cladding wave guides, we experimentally demonstrate the resonant coupling of rubidium vapor and an atomic cladding micro ring resonator. Specifically, we observed cavity-atom coupling in the form of Fano resonances having a distinct dependency on the relative frequency detuning between the photonic and the atomic resonances. Moreover, we were able to significantly enhance the efficiency of all optical switching in the V-type pump-probe scheme. The coupled system of micro-ring resonator and atomic vapor is a promising building block for a variety of light vapor experiments, as it offers a very small footprint, high degree of integration and extremely strong confinement of light and vapor. As such it may be used for important applications, such as all optical switching, disp...

  1. Interfacing transitions of different alkali atoms and telecom bands using one narrowband photon pair source

    DEFF Research Database (Denmark)

    Schunk, Gerhard; Vogl, Ulrich; Strekalov, Dmitry V.;

    2015-01-01

    Quantum information technology strongly relies on the coupling of optical photons with narrowband quantum systems, such as quantum dots, color centers, and atomic systems. This coupling requires matching the optical wavelength and bandwidth to the desired system, which presents a considerable pro...

  2. Dynamics of Finite Energy Airy Beams Carrying Orbital Angular Momentum in Multilevel Atomic Vapors

    Science.gov (United States)

    Wu, Zhenkun; Wang, Shun; Hu, Weifei; Gu, Yuzong

    2016-10-01

    We numerically investigate the dynamics of inward circular finite-energy Airy beams carrying different orbital angular momentum (OAM) numbers in a close-Λ three-level atomic vapor with the electromagnetically induced transparency (EIT) window. We report that due to the EIT induced by the microwave field, the transverse intensity distribution properties of Airy beam can be feasibly manipulated and modulated through adjusting OAM numbers l and the frequency detuning, as well as the propagation distance, in the multi-level atomic systems. What's more, the rotation of the beam also can be observed with different positions in atomic ensembles. The investigation may provide a useful tool for studying particle manipulation, signal processing and propagation in graded-index (GRIN) fibers.

  3. Eigenmode description of Raman scattering in atomic vapors in the presence of decoherence

    CERN Document Server

    Chwedenczuk, Jan; Wasilewski, Wojciech

    2012-01-01

    A theoretical model describing the Raman scattering process in atomic vapors is constructed. Despite the incorporated decoherence effects, it allows for a direct separation of system's time evolution from its spatial degrees of freedom. The impact of noise on the temporal properties of the system is investigated. In particular, it is shown that even in the presence of decoherence, the estimation of the number of spin waves created in the process can reach sensitivity below the projection noise limit. The model is then applied in two experimentally relevant situations of ultra-cold and room-temperature atoms. In both cases, the spatial eigenmodes of the Stokes photon and atomic excitation fields and their coupling parameters are computed.

  4. Desorption Dynamics of Heavy Alkali Metal Atoms (Rb, Cs) off the Surface of Helium Nanodroplets

    CERN Document Server

    von Vangerow, J; Stienkemeier, F; Mudrich, M; Leal, A; Mateo, D; Hernando, A; Barranco, M; Pi, M

    2014-01-01

    We present a combined ion imaging and density functional theory study of the dynamics of the desorption process of rubidium and cesium atoms off the surface of helium nanodroplets upon excitation of the perturbed $6s$ and $7s$ states, respectively. Both experimental and theoretical results are well represented by the pseudodiatomic model for effective masses of the helium droplet in the desorption reaction of m_eff/m_He~10 (Rb) and 13 (Cs). Deviations from this model are found for Rb excited to the 6p state. Photoelectron spectra indicate that the dopant-droplet interaction induces relaxation into low-lying electronic states of the desorbed atoms in the course of the ejection process.

  5. Nonlinear pressure shifts of alkali-metal atoms in inert gases.

    Science.gov (United States)

    Gong, F; Jau, Y-Y; Happer, W

    2008-06-13

    Precise measurements show that the microwave resonance frequencies of ground-state Rb or Cs atoms have a nonlinear dependence on the pressure of the buffer gases Ar and Kr. No nonlinearities were observed in the gases He or N(2). These observations strongly suggest that the nonlinearities are due to the van der Waals molecules that form in Ar and Kr, but not in He or N(2). The nonlinear part of the shifts is largest in the pressure range of a few tens of torr, similar to the operating pressures of gas-cell atomic clocks. The observed shifts are very well described by a simple function, parametrized by the effective three-body formation rate of molecules and by the effective product of the collisionally limited lifetime times the shift of the hyperfine coupling coefficient in the molecule.

  6. Desorption dynamics of heavy alkali metal atoms (Rb, Cs) off the surface of helium nanodroplets.

    Science.gov (United States)

    von Vangerow, J; Sieg, A; Stienkemeier, F; Mudrich, M; Leal, A; Mateo, D; Hernando, A; Barranco, M; Pi, M

    2014-08-21

    We present a combined ion imaging and density functional theory study of the dynamics of the desorption process of rubidium and cesium atoms off the surface of helium nanodroplets upon excitation of the perturbed 6s and 7s states, respectively. Both experimental and theoretical results are well represented by the pseudodiatomic model for effective masses of the helium droplet in the desorption reaction of meff/mHe ≈ 10 (Rb) and 13 (Cs). Deviations from this model are found for Rb excited to the 6p state. Photoelectron spectra indicate that the dopant-droplet interaction induces relaxation into low-lying electronic states of the desorbed atoms in the course of the ejection process.

  7. Extrapolated intermediate Hamiltonian coupled-cluster approach: theory and pilot application to electron affinities of alkali atoms.

    Science.gov (United States)

    Eliav, Ephraim; Vilkas, Marius J; Ishikawa, Yasuyuki; Kaldor, Uzi

    2005-06-08

    The intermediate Hamiltonian (IH) coupled-cluster method makes possible the use of very large model spaces in coupled-cluster calculations without running into intruder states. This is achieved at the cost of approximating some of the IH matrix elements, which are not taken at their rigorous effective Hamiltonian (EH) value. The extrapolated intermediate Hamiltonian (XIH) approach proposed here uses a parametrized IH and extrapolates it to the full EH, with model spaces larger by several orders of magnitude than those possible in EH coupled-cluster methods. The flexibility and resistance to intruders of the IH approach are thus combined with the accuracy of full EH. Various extrapolation schemes are described. A pilot application to the electron affinities (EAs) of alkali atoms is presented, where converged EH results are obtained by XIH for model spaces of approximately 20,000 determinants; direct EH calculations converge only for a one-dimensional model space. Including quantum electrodynamic effects, the average XIH error for the EAs is 0.6 meV and the largest error is 1.6 meV. A new reference estimate for the EA of Fr is proposed at 486+/-2 meV.

  8. Sympathetic cooling in an optically trapped mixture of alkali and spin-singlet atoms.

    Science.gov (United States)

    Ivanov, Vladyslav V; Khramov, Alexander; Hansen, Anders H; Dowd, William H; Münchow, Frank; Jamison, Alan O; Gupta, Subhadeep

    2011-04-15

    We report on the realization of a stable mixture of ultracold lithium and ytterbium atoms confined in a far-off-resonance optical dipole trap. We observe sympathetic cooling of 6Li by 174Yb and extract the s-wave scattering length magnitude |a(6Li-174Yb)|=(13±3)a0 from the rate of interspecies thermalization. Using forced evaporative cooling of 174Yb, we achieve reduction of the 6Li temperature to below the Fermi temperature, purely through interspecies sympathetic cooling.

  9. Emission Channeling Studies on the Behaviour of Light Alkali Atoms in Wide-Band-Gap Semiconductors

    CERN Multimedia

    Recknagel, E; Quintel, H

    2002-01-01

    % IS342 \\\\ \\\\ A major problem in the development of electronic devices based on diamond and wide-band-gap II-VI compound semiconductors, like ZnSe, is the extreme difficulty of either n- or p-type doping. The only reports of successful n-type doping of diamond involves ion implanted Li, which was found to be an intersititial donor. Recent theoretical calculations suggest that Na, P and N dopant atoms are also good candidates for n-type doping of diamond. No experimental evidence has been obtained up to now, mainly because of the complex and partly unresolved defect situation created during ion implantation, which is necessary to incorporate potential donor atoms into diamond. \\\\ \\\\In the case of ZnSe, considerable effort has been invested in trying to fabricate pn-junctions in order to make efficient, blue-light emitting diodes. However, it has proved to be very difficult to obtain p-type ZnSe, mainly because of electrical compensation related to background donor impurities. Li and Na are believed to be ampho...

  10. 异核碱金属原子间的三体相互作用系数%Three-body dispersion coefficients for heteronuclear alkali-metal atoms

    Institute of Scientific and Technical Information of China (English)

    谢柏东; 黄时中

    2013-01-01

    By utilizing the model potential for alkali-metal atoms and the variationally stable method, the three-body dispersion coefficients for heteronuclear interactions of the alkali-metal atoms are calculated for the first time. In order to illustrate the reliability of the calculated results, the multipolar polarizabil-ities of the alkali-metal atoms are also calculated and compared with those of the previous calculations and experimental data. The results show that the present three-body dispersion coefficients are reliable.%利用碱金属原子的模型势和稳定变分法,首次计算了异核碱金属原子间的三体相互作用系数.为了说明计算结果的精度,同时计算了碱金属原子的电多级极化率.与其他作者的理论数据和有关实验数据的比较表明,本文所得到的异核碱金属原子间的三体相互作用系数是可靠的.

  11. Amplified light storage with high fidelity based on electromagnetically induced transparency in rubidium atomic vapor

    Science.gov (United States)

    Zhou, Wei; Wang, Gang; Tang, Guoyu; Xue, Yan

    2016-06-01

    By using slow and stored light based on electromagnetically induced transparency (EIT), we theoretically realize the storage of optical pulses with enhanced efficiency and high fidelity in ensembles of warm atoms in 85Rb vapor cells. The enhancement of storage efficiency is achieved by introducing a pump field beyond three-level configuration to form a N-type scheme, which simultaneously inhibits the undesirable four-wave mixing effect while preserves its fidelity. It is shown that the typical storage efficiency can be improved from 29% to 53% with the application of pump field. Furthermore, we demonstrate that this efficiency decreases with storage time and increases over unity with optical depth.

  12. Optical detection of potassium chloride vapor using collinear photofragmentation and atomic absorption spectroscopy.

    Science.gov (United States)

    Sorvajärvi, Tapio; Saarela, Jaakko; Toivonen, Juha

    2012-10-01

    A sensitive and selective optical technique to detect potassium chloride (KCl) vapor is introduced. The technique is based on the photofragmentation of KCl molecules, using a pulsed UV laser, and optical probing of the temporarily increased amount of potassium atoms with a near-infrared laser. The two laser beams are aligned to go through the sample volume along the same optical path. The performance of the technique is demonstrated by detecting KCl concentrations from 25 ppb to 30 ppm in a temperature-controlled cell.

  13. Synthesis of magnetic tunnel junctions with full in situ atomic layer and chemical vapor deposition processes

    Energy Technology Data Exchange (ETDEWEB)

    Mantovan, R., E-mail: roberto.mantovan@mdm.imm.cnr.it [Laboratorio MDM, IMM-CNR, Via C. Olivetti 2, 20864 Agrate Brianza (Italy); Vangelista, S.; Kutrzeba-Kotowska, B.; Cocco, S.; Lamperti, A.; Tallarida, G. [Laboratorio MDM, IMM-CNR, Via C. Olivetti 2, 20864 Agrate Brianza (MB) (Italy); Mameli, D. [Laboratorio MDM, IMM-CNR, Via C. Olivetti 2, 20864 Agrate Brianza (Italy); Dipartimento di Scienze Chimiche, Universita di Cagliari, Cittadella Universitaria, 09042 Monserrato, Cagliari (Italy); Fanciulli, M. [Laboratorio MDM, IMM-CNR, Via C. Olivetti 2, 20864 Agrate Brianza (Italy); Dipartimento di Scienza dei Materiali, Universita degli studi Milano-Bicocca, Via R Cozzi 53, 20125 Milano (Italy)

    2012-05-01

    Magnetic tunnel junctions, i.e. the combination of two ferromagnetic electrodes separated by an ultrathin tunnel oxide barrier, are core elements in a large variety of spin-based devices. We report on the use of combined chemical vapor and atomic layer deposition processes for the synthesis of magnetic tunnel junctions with no vacuum break. Structural, chemical and morphological characterizations of selected ferromagnetic and oxide layers are reported, together with the evidence of tunnel magnetoresistance effect in patterned Fe/MgO/Co junctions.

  14. Iodine Determination by Microwave Plasma Torch Atomic Emission Spectrometer Coupled with Online Preconcentration Vapor Generation Technique

    Institute of Scientific and Technical Information of China (English)

    FEI Yan-qun; LUO Gui-min; FENG Guo-dong; CHEN Huan-wen; FEI Qiang; HUAN Yan-fu; JIN Qin-han

    2008-01-01

    This article focuses on iodine determination by microwave plasma torch atomic emission spectrometry (MPT-AES) coupled with online preconcentration vapor generation method.A new desolvation device,multistrand Nation dryer,was used as the substitute for condenser desolvation system.Some experimental conditions,such as preconcentration time,acidity of sample solution,rinsing solution acidity and dynamic linear range were investigated and optimized.The new desolvation system eliminates the problem of decreasing emission intensity of I(I) 206.238 nm line with the increase of working time on a conventional condenser desolvation system,thus greatly improving the reproducibility.

  15. Modulation of the photonic band structure topology of a honeycomb lattice in an atomic vapor

    CERN Document Server

    Zhang, Yiqi; Belić, Milivoj R; Wu, Zhenkun; Zhang, Yanpeng

    2015-01-01

    In an atomic vapor, a honeycomb lattice can be constructed by utilizing the three-beam interference method. In the method, the interference of the three beams splits the dressed energy level periodically, forming a periodic refractive index modulation with the honeycomb profile. The energy band topology of the honeycomb lattice can be modulated by frequency detunings, thereby affecting the appearance (and disappearance) of Dirac points and cones in the momentum space. This effect can be usefully exploited for the generation and manipulation of topological insulators.

  16. Effect of atomic noise on optical squeezing via polarization self-rotation in a thermal vapor cell

    DEFF Research Database (Denmark)

    Hsu, M.T.L.; Hetet, G.; Peng, A.

    2006-01-01

    show results of the characterization of PSR in isotopically enhanced rubidium-87 cells, performed in two independent laboratories. We observed that, contrary to earlier work, the presence of atomic noise in the thermal vapor overwhelms the observation of squeezing. We present a theory that contains......The traversal of an elliptically polarized optical field through a thermal vapor cell can give rise to a rotation of its polarization axis. This process, known as polarization self-rotation (PSR), has been suggested as a mechanism for producing squeezed light at atomic transition wavelengths. We...... atomic noise terms and show that a null result in squeezing is consistent with this theory....

  17. Atom Resonance Lines for Modeling Atmosphere: Studies of Pressure-Broadening of Alkali Atom Resonance Lines for Modeling Atmospheres of Extrasolar Giant Planets and Brown Dwarfs

    Science.gov (United States)

    Hasan, Hashima (Technical Monitor); Kirby, K.; Babb, J.; Yoshino, K.

    2005-01-01

    We report on progress made in a joint program of theoretical and experimental research to study the line-broadening of alkali atom resonance lines due to collisions with species such as helium and molecular hydrogen. Accurate knowledge of the line profiles of Na and K as a function of temperature and pressure will allow such lines to serve as valuable diagnostics of the atmospheres of brown dwarfs and extra-solar giant planets. A new experimental apparatus has been designed, built and tested over the past year, and we are poised to begin collecting data on the first system of interest, the potassium resonance lines perturbed by collisions with helium. On the theoretical front, calculations of line-broadening due to sodium collisions with helium are nearly complete, using accurate molecular potential energy curves and transition moments just recently computed for this system. In addition we have completed calculations of the three relevant potential energy curves and associated transition moments for K - He, using the MOLPRO quantum chemistry codes. Currently, calculations of the potential surfaces describing K-H2 are in progress.

  18. Demonstration of a Tunable-Bandwidth White Light Interferometer using Anomalous Dispersion in Atomic Vapor

    CERN Document Server

    Pati, G S; Salit, M; Shahriar, M S

    2006-01-01

    The concept of the 'white-light cavity' has recently generated considerable research interest in the context of gravitational wave detection. Cavity designs are proposed using negative (or anomalous) dispersion in an intracavity medium to make the cavity resonate over a large range of frequencies and still maintain a high cavity build-up. This paper presents the first experimental attempt and demonstration of white-light effect in a meter long ring cavity using an intracavity atomic medium. The medium's negative dispersion is caused by bi-frequency Raman gain in an atomic vapor cell. Although the white light condition was not perfectly achieved and improvements in experimental control are still desirable, significantly broad cavity response over bandwidth greater than 20 MHz has been observed. These devices will have potential applications in new generation laser interferometer gravitational wave detectors.

  19. Frequency-Tunable Microwave Field Detection in an Atomic Vapor Cell

    CERN Document Server

    Horsley, Andrew

    2016-01-01

    We use an atomic vapor cell as a frequency tunable microwave field detector operating at frequencies from GHz to tens of GHz. We detect microwave magnetic fields from 2.3 GHz to 26.4 GHz, and measure the amplitude of the sigma+ component of an 18 GHz microwave field. Our proof-of-principle demonstration represents a four orders of magnitude extension of the frequency tunable range of atomic magnetometers from their previous dc to several MHz range. When integrated with a high resolution microwave imaging system, this will allow for the complete reconstruction of the vector components of a microwave magnetic field and the relative phase between them. Potential applications include near-field characterisation of microwave circuitry and devices, and medical microwave sensing and imaging.

  20. Controlled Synthesis of Atomically Layered Hexagonal Boron Nitride via Chemical Vapor Deposition

    Directory of Open Access Journals (Sweden)

    Juanjuan Liu

    2016-11-01

    Full Text Available Hexagonal boron nitrite (h-BN is an attractive material for many applications including electronics as a complement to graphene, anti-oxidation coatings, light emitters, etc. However, the synthesis of high-quality h-BN is still a great challenge. In this work, via controlled chemical vapor deposition, we demonstrate the synthesis of h-BN films with a controlled thickness down to atomic layers. The quality of as-grown h-BN is confirmed by complementary characterizations including high-resolution transition electron microscopy, atomic force microscopy, Raman spectroscopy and X-ray photo-electron spectroscopy. This work will pave the way for production of large-scale and high-quality h-BN and its applications as well.

  1. Double resonance fequency light shift compensation in optically oriented laser-pumped alkali atoms

    Energy Technology Data Exchange (ETDEWEB)

    Baranov, A. A., E-mail: lexusbar@gmail.com; Ermak, S. V.; Sagitov, E. A.; Smolin, R. V.; Semenov, V. V. [St. Petersburg Polytechnic University (Russian Federation)

    2015-09-15

    The contributions of the vector and scalar components to the magnetically dependent microwave transition frequency light shift are analyzed and the compensation of these components is experimentally demonstrated for the {sup 87}Rb atoms optically oriented by a laser tuned to the D{sub 2} line of the head doublet. The Allan variance is studied as a function of the averaging time for a tandem of optically pumped quantum magnetometers (OPQMs), one of which is based on a low-frequency spin oscillator while another is based on a quantum microwave discriminator with a resonance frequency that corresponds to magnetically dependent transitions between HFS sublevels with the extremal value of the magnetic quantum number. It is shown that the compensation of the scalar and vector components of the light shift in OPQMs reduces the Allan variance at averaging times that exceed hundreds of seconds compared to a quantum discriminator based on the magnetically independent 0–0 transition. In this case, the minimal Allan variance in OPQMs at the end resonance is achieved at considerably longer averaging times than in the case of the quantum discriminator that is tuned to the 0–0 transition frequency.

  2. Plasma formation in diode pumped alkali lasers sustained in Cs

    Science.gov (United States)

    Markosyan, Aram H.; Kushner, Mark J.

    2016-11-01

    In diode pumped alkali lasers (DPALs), lasing action occurs on the resonant lines of alkali atoms following pumping by broadband semiconductor lasers. The goal is to convert the efficient but usually poor optical quality of inexpensive diode lasers into the high optical quality of atomic vapor lasers. Resonant excitation of alkali vapor leads to plasma formation through the excitation transfer from the 2P states to upper lying states, which then are photoionized by the pump and intracavity radiation. A first principles global model was developed to investigate the operation of the He/Cs DPAL system and the consequences of plasma formation on the efficiency of the laser. Over a range of pump powers, cell temperatures, excitation frequency, and mole fraction of the collision mixing agent (N2 or C2H6), we found that sufficient plasma formation can occur that the Cs vapor is depleted. Although N2 is not a favored collisional mixing agent due to large rates of quenching of the 2P states, we found a range of pump parameters where laser oscillation may occur. The poor performance of N2 buffered systems may be explained in part by plasma formation. We found that during the operation of the DPAL system with N2 as the collisional mixing agent, plasma formation is in excess of 1014-1015 cm-3, which can degrade laser output intensity by both depletion of the neutral vapor and electron collisional mixing of the laser levels.

  3. Design and implementation of a novel portable atomic layer deposition/chemical vapor deposition hybrid reactor

    Science.gov (United States)

    Selvaraj, Sathees Kannan; Jursich, Gregory; Takoudis, Christos G.

    2013-09-01

    We report the development of a novel portable atomic layer deposition chemical vapor deposition (ALD/CVD) hybrid reactor setup. Unique feature of this reactor is the use of ALD/CVD mode in a single portable deposition system to fabricate multi-layer thin films over a broad range from "bulk-like" multi-micrometer to nanometer atomic dimensions. The precursor delivery system and control-architecture are designed so that continuous reactant flows for CVD and cyclic pulsating flows for ALD mode are facilitated. A custom-written LabVIEW program controls the valve sequencing to allow synthesis of different kinds of film structures under either ALD or CVD mode or both. The entire reactor setup weighs less than 40 lb and has a relatively small footprint of 8 × 9 in., making it compact and easy for transportation. The reactor is tested in the ALD mode with titanium oxide (TiO2) ALD using tetrakis(diethylamino)titanium and water vapor. The resulting growth rate of 0.04 nm/cycle and purity of the films are in good agreement with literature values. The ALD/CVD hybrid mode is demonstrated with ALD of TiO2 and CVD of tin oxide (SnOx). Transmission electron microscopy images of the resulting films confirm the formation of successive distinct TiO2-ALD and SnOx-CVD layers.

  4. Design and implementation of a novel portable atomic layer deposition/chemical vapor deposition hybrid reactor.

    Science.gov (United States)

    Selvaraj, Sathees Kannan; Jursich, Gregory; Takoudis, Christos G

    2013-09-01

    We report the development of a novel portable atomic layer deposition chemical vapor deposition (ALD/CVD) hybrid reactor setup. Unique feature of this reactor is the use of ALD/CVD mode in a single portable deposition system to fabricate multi-layer thin films over a broad range from "bulk-like" multi-micrometer to nanometer atomic dimensions. The precursor delivery system and control-architecture are designed so that continuous reactant flows for CVD and cyclic pulsating flows for ALD mode are facilitated. A custom-written LabVIEW program controls the valve sequencing to allow synthesis of different kinds of film structures under either ALD or CVD mode or both. The entire reactor setup weighs less than 40 lb and has a relatively small footprint of 8 × 9 in., making it compact and easy for transportation. The reactor is tested in the ALD mode with titanium oxide (TiO2) ALD using tetrakis(diethylamino)titanium and water vapor. The resulting growth rate of 0.04 nm/cycle and purity of the films are in good agreement with literature values. The ALD/CVD hybrid mode is demonstrated with ALD of TiO2 and CVD of tin oxide (SnOx). Transmission electron microscopy images of the resulting films confirm the formation of successive distinct TiO2-ALD and SnO(x)-CVD layers.

  5. Quantum correlations by four-wave-mixing in atomic vapor. Theory and Experiments

    CERN Document Server

    Glorieux, Quentin

    2011-01-01

    We study both theoretically and experimentally the generation of quantum correlations in the continuous variable regime by way of four-wave mixing in a hot atomic vapor. Two theoretical approaches have been developed. On one side, we study the four-wave mixing under the "classical" non-linear optics point of view. In such a way we obtain the evolution equation for an ideal linear amplifier in a {\\chi}^(3) medium. On the other side, we present a microscopic model with 4 levels in the double-{\\Lambda} configuration to calculate the {\\chi}^(3) coefficient in a atomic vapor dressed with a laser. This calculation allows us to derive the spectra of intensity noise for interesting parameters. The experimental part of this work describes the demonstration of this effect on the D1 line of rubidium 85. We present a measurement of relative intensity squeezing as high as -9.2dB below the standard quantum limit, and an original regime where quantum correlations have been measured without amplification.These results have b...

  6. Doping the alkali atom: an effective strategy to improve the electronic and nonlinear optical properties of the inorganic Al12N12 nanocage.

    Science.gov (United States)

    Niu, Min; Yu, Guangtao; Yang, Guanghui; Chen, Wei; Zhao, Xingang; Huang, Xuri

    2014-01-06

    Under ab initio computations, several new inorganic electride compounds with high stability, M@x-Al12N12 (M = Li, Na, and K; x = b66, b64, and r6), were achieved for the first time by doping the alkali metal atom M on the fullerene-like Al12N12 nanocage, where the alkali atom is located over the Al-N bond (b66/b64 site) or six-membered ring (r6 site). It is revealed that independent of the doping position and atomic number, doping the alkali atom can significantly narrow the wide gap between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) (EH-L = 6.12 eV) of the pure Al12N12 nanocage in the range of 0.49-0.71 eV, and these doped AlN nanocages can exhibit the intriguing n-type characteristic, where a high energy level containing the excess electron is introduced as the new HOMO orbital in the original gap of pure Al12N12. Further, the diffuse excess electron also brings these doped AlN nanostructures the considerable first hyperpolarizabilities (β0), which are 1.09 × 10(4) au for Li@b66-Al12N12, 1.10 × 10(4), 1.62 × 10(4), 7.58 × 10(4) au for M@b64-Al12N12 (M = Li, Na, and K), and 8.89 × 10(5), 1.36 × 10(5), 5.48 × 10(4) au for M@r6-Al12N12 (M = Li, Na, and K), respectively. Clearly, doping the heavier Na/K atom over the Al-N bond can get the larger β0 value, while the reverse trend can be observed for the series with the alkali atom over the six-membered ring, where doping the lighter Li atom can achieve the larger β0 value. These fascinating findings will be advantageous for promoting the potential applications of the inorganic AlN-based nanosystems in the new type of electronic nanodevices and high-performance nonlinear optical (NLO) materials.

  7. Formation and Transport of Atomic Hydrogen in Hot-Filament Chemical Vapor Deposition Reactors

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    In this paper we focus on diamond film hot-filament chemical vapor deposition reactors where the only reactant ishydrogen so as to study the formation and transport of hydrogen atoms. Analysis of dimensionless numbers forheat and mass transfer reveals that thermal conduction and diffusion are the dominant mechanisms for gas-phaseheat and mass transfer, respectively. A simplified model has been established to simulate gas-phase temperature andH concentration distributions between the filament and the substrate. Examination of the relative importance ofhomogeneous and heterogeneous production of H atoms indicates that filament-surface decomposition of molecularhydrogen is the dominant source of H and gas-phase reaction plays a negligible role. The filament-surface dissociationrates of H2 for various filament temperatures were calculated to match H-atom concentrations observed in the liter-ature or derived from power consumption by filaments. Arrhenius plots of the filament-surface hydrogen dissociationrates suggest that dissociation of H2 at refractory filament surface is a catalytic process, which has a rather lowereffective activation energy than homogeneous thermal dissociation. Atomic hydrogen, acting as an important heattransfer medium to heat the substrate, can freely diffuse from the filament to the substrate without recombination.

  8. Direct atomic absorption determination of cadmium and lead in strongly interfering matrices by double vaporization with a two-step electrothermal atomizer

    Science.gov (United States)

    Grinshtein, Ilia L.; Vilpan, Yuri A.; Saraev, Alexei V.; Vasilieva, Lubov A.

    2001-03-01

    Thermal pretreatment of a sample using double vaporization in a two-step atomizer with a purged vaporizer makes possible the direct analysis of samples with strongly interfering matrices including solids. A porous-graphite capsule or a filter inserted into the vaporizer is used for solid sample analysis. The technique was used for the direct determination of Cd and Pb in human urine, potatoes, wheat, bovine liver, milk powder, grass-cereal mixtures, caprolactam, bituminous-shale and polyvinyl chloride plastic without chemical modification or any other sample pretreatment.

  9. Evanescent light-matter Interactions in Atomic Cladding Wave Guides

    CERN Document Server

    Stern, Liron; Goykhman, Ilya; Levy, Uriel

    2012-01-01

    Alkali vapors, and in particular rubidium, are being used extensively in several important fields of research such as slow and stored light non-linear optics3 and quantum computation. Additionally, the technology of alkali vapors plays a major role in realizing myriad industrial applications including for example atomic clocks magentometers8 and optical frequency stabilization. Lately, there is a growing effort towards miniaturizing traditional centimeter-size alkali vapor cells. Owing to the significant reduction in device dimensions, light matter interactions are greatly enhanced, enabling new functionalities due to the low power threshold needed for non-linear interactions. Here, taking advantage of the mature Complimentary Metal-Oxide-Semiconductor (CMOS) compatible platform of silicon photonics, we construct an efficient and flexible platform for tailored light vapor interactions on a chip. Specifically, we demonstrate light matter interactions in an atomic cladding wave guide (ACWG), consisting of CMOS ...

  10. The long-range non-additive three-body dispersion interactions for the rare gases, alkali, and alkaline-earth atoms.

    Science.gov (United States)

    Tang, Li-Yan; Yan, Zong-Chao; Shi, Ting-Yun; Babb, James F; Mitroy, J

    2012-03-14

    The long-range non-additive three-body dispersion interaction coefficients Z(111), Z(112), Z(113), and Z(122) are computed for many atomic combinations using standard expressions. The atoms considered include hydrogen, the rare gases, the alkali atoms (up to Rb), and the alkaline-earth atoms (up to Sr). The term Z(111) arising from three mutual dipole interactions is known as the Axilrod-Teller-Muto coefficient or the DDD (dipole-dipole-dipole) coefficient. Similarly, the terms Z(112), Z(113), and Z(122) arise from the mutual combinations of dipole (1), quadrupole (2), and octupole (3) interactions between atoms and they are sometimes known, respectively, as dipole-dipole-quadrupole, dipole-dipole-octupole, and dipole-quadrupole-quadrupole coefficients. Results for the four Z coefficients are given for the homonuclear trimers, for the trimers involving two like-rare-gas atoms, and for the trimers with all combinations of the H, He, and Li atoms. An exhaustive compilation of all coefficients between all possible atomic combinations is presented as supplementary data.

  11. The long-range non-additive three-body dispersion interactions for the rare gases, alkali and alkaline-earth atoms

    CERN Document Server

    Tang, Li-Yan; Shi, Ting-Yun; Babb, James F; Mitroy, J

    2012-01-01

    The long-range non-additive three-body dispersion interaction coefficients $Z_{111}$, $Z_{112}$, $Z_{113}$, and $Z_{122}$ are computed for many atomic combinations using standard expressions. The atoms considered include hydrogen, the rare gases, the alkali atoms (up to Rb) and the alkaline-earth atoms (up to Sr). The term $Z_{111}$, arising from three mutual dipole interactions is known as the Axilrod-Teller-Muto coefficient or the DDD (dipole-dipole-dipole) coefficient. Similarly, the terms $Z_{112}$, $Z_{113}$, and $Z_{122}$ arise from the mutual combinations of dipole (1), quadrupole (2), and octupole (3) interactions between atoms and they are sometimes known, respectively, as DDQ, DDO, and DQQ coefficients. Results for the four $Z$ coefficients are given for the homonuclear trimers, for the trimers involving two like-rare-gas atoms, and for the trimers with all combinations of the H, He, Li atoms. An exhaustive compilation of all coefficients between all possible atomic combinations is presented as supp...

  12. Adsorption of alkali, alkaline-earth, simple and 3d transition metal, and nonmetal atoms on monolayer MoS2

    Directory of Open Access Journals (Sweden)

    X. D. Li

    2015-05-01

    Full Text Available Single adsorption of different atoms on pristine two-dimensional monolayer MoS2 have been systematically investigated by using density functional calculations with van der Waals correction. The adatoms cover alkali metals, alkaline earth metals, main group metal, 3d-transition metals, coinage metal and nonmetal atoms. Depending on the adatom type, metallic, semimetallic or semiconducting behavior can be found in direct bandgap monolayer MoS2. Additionally, local or long-range magnetic moments of two-dimensional MoS2 sheet can also attained through the adsorption. The detailed atomic-scale knowledge of single adsorption on MoS2 monolayer is important not only for the sake of a theoretical understanding, but also device level deposition technological application.

  13. Dispersion coefficients for the interactions of the alkali and alkaline-earth ions and inert gas atoms with a graphene layer

    CERN Document Server

    Kaur, Kiranpreet; Sahoo, B K

    2015-01-01

    Largely motivated by a number of applications, the van der Waals dispersion coefficients ($C_3$s) of the alkali ions (Li$^+$, Na$^+$, K$^+$ and Rb$^+$), the alkaline-earth ions (Ca$^+$, Sr$^+$, Ba$^+$ and Ra$^+$) and the inert gas atoms (He, Ne, Ar and Kr) with a graphene layer are determined precisely within the framework of Dirac model. For these calculations, we have evaluated the dynamic polarizabilities of the above atomic systems very accurately by evaluating the transition matrix elements employing relativistic many-body methods and using the experimental values of the excitation energies. The dispersion coefficients are, finally, given as functions of the separation distance of an atomic system from the graphene layer and the ambiance temperature during the interactions. For easy extraction of these coefficients, we give a logistic fit to the functional forms of the dispersion coefficients in terms of the separation distances at the room temperature.

  14. Determination of mercury in phosphate fertilizers by cold vapor atomic absorption spectrometry.

    Science.gov (United States)

    de Jesus, Robson M; Silva, Laiana O B; Castro, Jacira T; de Azevedo Neto, Andre D; de Jesus, Raildo M; Ferreira, Sergio L C

    2013-03-15

    In this paper, a method for the determination of mercury in phosphate fertilizers using slurry sampling and cold vapor atomic absorption spectrometry (CV QT AAS) is proposed. Because mercury (II) ions form strong complexes with phosphor compounds, the formation of metallic mercury vapor requires the presence of lanthanum chloride as a release agent. Thiourea increases the amount of mercury that is extracted from the solid sample to the liquid phase of the slurry. The method is established using two steps. First, the slurry is prepared using the sample, lanthanum chloride, hydrochloric acid solution and thiourea solution and is sonicated for 20 min. Afterward, mercury vapor is generated using an aliquot of the slurry in the presence of the hydrochloric acid solution and isoamylic alcohol with sodium tetrahydroborate solution as the reducing agent. The experimental conditions for slurry preparation were optimized using two-level full factorial design involving the factors: thiourea and lanthanum chloride concentrations and the duration of sonication. The method allows the determination of mercury by external calibration using aqueous standards with limits of detection and quantification of 2.4 and 8.2 μg kg(-1), respectively, and precision, expressed as relative standard deviation, of 6.36 and 5.81% for two phosphate fertilizer samples with mercury concentrations of 0.24 and 0.57 mg kg(-1), respectively. The accuracy was confirmed by the analysis of a certified reference material of phosphate fertilizer that was provided by the National Institute of Standards & Technology (NIST). The method was applied to determine mercury in six commercial samples of phosphate fertilizers. The mercury content varied from 33.97 to 209.28 μg kg(-1). These samples were also analyzed employing inductively coupled plasma mass spectrometry (ICP-MS). The ICP-MS results were consistent with the results from our proposed method.

  15. Magnetically tuned, robust and efficient filtering system for spatially multimode quantum memory in warm atomic vapors

    CERN Document Server

    Dąbrowski, Michał; Wasilewski, Wojciech

    2015-01-01

    Warm atomic vapor quantum memories are simple and robust, yet suffer from a number of parasitic processes which produce excess noise. For operating in a single-photon regime precise filtering of the output light is essential. Here we report a combination of magnetically tuned absorption and Faraday filters, both light-direction-insensitive, which stop the driving lasers and attenuate spurious fluorescence and four-wave mixing while transmitting narrowband Stokes and anti-Stokes photons generated in write-in and readout processes. We characterize both filters with respect to adjustable working parameters. We demonstrate a significant increase in the signal to noise ratio upon applying the filters seen qualitatively in measurements of correlation between the Raman-scattered photons.

  16. Magnetically tuned, robust and efficient filtering system for spatially multimode quantum memory in warm atomic vapors

    Science.gov (United States)

    Dąbrowski, M.; Chrapkiewicz, R.; Wasilewski, W.

    2016-11-01

    Warm atomic vapor quantum memories are simple and robust, yet suffer from a number of parasitic processes which produce excess noise. For operating in a single-photon regime precise filtering of the output light is essential. Here, we report a combination of magnetically tuned absorption and Faraday filters, both light-direction insensitive, which stop the driving lasers and attenuate spurious fluorescence and four-wave mixing while transmitting narrowband Stokes and anti-Stokes photons generated in write-in and readout processes. We characterize both filters with respect to adjustable working parameters. We demonstrate a significant increase in the signal-to-noise ratio upon applying the filters seen qualitatively in measurements of correlation between the Raman scattered photons.

  17. Wet Etching of Heat Treated Atomic Layer Chemical Vapor Deposited Zirconium Oxide in HF Based Solutions

    Science.gov (United States)

    Balasubramanian, Sriram; Raghavan, Srini

    2008-06-01

    Alternative materials are being considered to replace silicon dioxide as gate dielectric material. Of these, the oxides of hafnium and zirconium show the most promise. However, integrating these new high-k materials into the existing complementary metal-oxide-semiconductor (CMOS) process remains a challenge. One particular area of concern is the wet etching of heat treated high-k dielectrics. In this paper, work done on the wet etching of heat treated atomic layer chemical vapor deposited (ALCVD) zirconium oxide in HF based solutions is presented. It was found that heat treated material, while refractory to wet etching at room temperature, is more amenable to etching at higher temperatures when methane sulfonic acid is added to dilute HF solutions. Selectivity over SiO2 is still a concern.

  18. Magnetically tuned, robust and efficient filtering system for spatially multimode quantum memory in warm atomic vapors.

    Science.gov (United States)

    Dąbrowski, M; Chrapkiewicz, R; Wasilewski, W

    2016-11-12

    Warm atomic vapor quantum memories are simple and robust, yet suffer from a number of parasitic processes which produce excess noise. For operating in a single-photon regime precise filtering of the output light is essential. Here, we report a combination of magnetically tuned absorption and Faraday filters, both light-direction insensitive, which stop the driving lasers and attenuate spurious fluorescence and four-wave mixing while transmitting narrowband Stokes and anti-Stokes photons generated in write-in and readout processes. We characterize both filters with respect to adjustable working parameters. We demonstrate a significant increase in the signal-to-noise ratio upon applying the filters seen qualitatively in measurements of correlation between the Raman scattered photons.

  19. Determination of mercury in rice by cold vapor atomic fluorescence spectrometry after microwave-assisted digestion

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Maria Jose da [Department of Analytical Chemistry, Edificio de Investigacion, University of Valencia, 50 Dr. Moliner Street, E-46100 Burjassot, Valencia (Spain); Departamento de Quimica Fundamental, Universidade Federal de Pernambuco, Cidade Universitaria, 50740-550 Recife, PE (Brazil); Paim, Ana Paula S. [Departamento de Quimica Fundamental, Universidade Federal de Pernambuco, Cidade Universitaria, 50740-550 Recife, PE (Brazil); Pimentel, Maria Fernanda [Departamento de Engenharia Quimica, Universidade Federal de Pernambuco, Recife, PE (Brazil); Cervera, M. Luisa, E-mail: m.luisa.cervera@uv.es [Department of Analytical Chemistry, Edificio de Investigacion, University of Valencia, 50 Dr. Moliner Street, E-46100 Burjassot, Valencia (Spain); Guardia, Miguel de la [Department of Analytical Chemistry, Edificio de Investigacion, University of Valencia, 50 Dr. Moliner Street, E-46100 Burjassot, Valencia (Spain)

    2010-05-14

    A cold vapor atomic fluorescence spectrometry method (CV-AFS) has been developed for the determination of Hg in rice samples at a few ng g{sup -1} concentration level. The method is based on the previous digestion of samples in a microwave oven with HNO{sub 3} and H{sub 2}O{sub 2} followed by dilution with water containing KBr/KBrO{sub 3} and hydroxylamine and reduction with SnCl{sub 2} in HCl using external calibration. The matrix interferences and the effect of nitrogen oxide vapors have been evaluated and the method validated using a certified reference material. The limit of detection of the method was 0.9 ng g{sup -1} with a recovery percentage of 95 {+-} 4% at an added concentration of 5 ng g{sup -1}. The concentration level of Hg found in 24 natural rice samples from different origin ranged between 1.3 and 7.8 ng g{sup -1}.

  20. Spectrum, radial wave functions, and hyperfine splittings of the Rydberg states in heavy alkali-metal atoms

    Science.gov (United States)

    Sanayei, Ali; Schopohl, Nils

    2016-07-01

    We present numerically accurate calculations of the bound-state spectrum of the highly excited valence electron in the heavy alkali-metal atoms solving the radial Schrödinger eigenvalue problem with a modern spectral collocation method that applies also for a large principal quantum number n ≫1 . As an effective single-particle potential we favor the reputable potential of Marinescu et al. [Phys. Rev. A 49, 982 (1994)], 10.1103/PhysRevA.49.982. Recent quasiclassical calculations of the quantum defect of the valence electron agree for orbital angular momentum l =0 ,1 ,2 ,... overall remarkably well with the results of the numerical calculations, but for the Rydberg states of rubidium and also cesium with l =3 this agreement is less fair. The reason for this anomaly is that in rubidium and cesium the potential acquires for l =3 deep inside the ionic core a second classical region, thus invalidating a standard Wentzel-Kramers-Brillouin (WKB) calculation with two widely spaced turning points. Comparing then our numerical solutions of the radial Schrödinger eigenvalue problem with the uniform analytic WKB approximation of Langer constructed around the remote turning point rn,j ,l (" close=")n -δ0)">+ we observe everywhere a remarkable agreement, apart from a tiny region around the inner turning point rn,j ,l (-). For s states the centrifugal barrier is absent and no inner turning point exists: rn,j ,0 (-)=0 . With the help of an ansatz proposed by Fock we obtain for the s states a second uniform analytic approximation to the radial wave function complementary to the WKB approximation of Langer, which is exact for r →0+ . From the patching condition, that is, for l =0 the Langer and Fock solutions should agree in the intermediate region 0 application we consider recent spectroscopic data for the hyperfine splittings of the isotopes 85Rb and 87Rb and find a remarkable agreement with the predicted scaling relation An,j ,0 (HFS )=const .

  1. Ab initio interaction potentials and scattering lengths for ultracold mixtures of metastable helium and alkali-metal atoms

    Science.gov (United States)

    Kedziera, Dariusz; Mentel, Łukasz; Żuchowski, Piotr S.; Knoop, Steven

    2015-06-01

    We have obtained accurate ab initio +4Σ quartet potentials for the diatomic metastable triplet helium+alkali-metal (Li, Na, K, Rb) systems, using all-electron restricted open-shell coupled cluster singles and doubles with noniterative triples corrections CCSD(T) calculations and accurate calculations of the long-range C6 coefficients. These potentials provide accurate ab initio quartet scattering lengths, which for these many-electron systems is possible, because of the small reduced masses and shallow potentials that result in a small amount of bound states. Our results are relevant for ultracold metastable triplet helium+alkali-metal mixture experiments.

  2. A Simplified Digestion Protocol for the Analysis of Hg in Fish by Cold Vapor Atomic Absorption Spectroscopy

    Science.gov (United States)

    Kristian, Kathleen E.; Friedbauer, Scott; Kabashi, Donika; Ferencz, Kristen M.; Barajas, Jennifer C.; O'Brien, Kelly

    2015-01-01

    Analysis of mercury in fish is an interesting problem with the potential to motivate students in chemistry laboratory courses. The recommended method for mercury analysis in fish is cold vapor atomic absorption spectroscopy (CVAAS), which requires homogeneous analyte solutions, typically prepared by acid digestion. Previously published digestion…

  3. Synthesis of multiferroic Er-Fe-O thin films by atomic layer and chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Mantovan, R., E-mail: roberto.mantovan@mdm.imm.cnr.it; Vangelista, S.; Wiemer, C.; Lamperti, A.; Tallarida, G. [Laboratorio MDM IMM-CNR, I-20864 Agrate Brianza (MB) (Italy); Chikoidze, E.; Dumont, Y. [GEMaC, Université de Versailles St. Quentin en Yvelines-CNRS, Versailles (France); Fanciulli, M. [Laboratorio MDM IMM-CNR, I-20864 Agrate Brianza (MB) (Italy); Dipartimento di Scienza dei Materiali, Università di Milano Bicocca, Milano (Italy)

    2014-05-07

    R-Fe-O (R = rare earth) compounds have recently attracted high interest as potential new multiferroic materials. Here, we report a method based on the solid-state reaction between Er{sub 2}O{sub 3} and Fe layers, respectively grown by atomic layer deposition and chemical vapor deposition, to synthesize Er-Fe-O thin films. The reaction is induced by thermal annealing and evolution of the formed phases is followed by in situ grazing incidence X-ray diffraction. Dominant ErFeO{sub 3} and ErFe{sub 2}O{sub 4} phases develop following subsequent thermal annealing processes at 850 °C in air and N{sub 2}. Structural, chemical, and morphological characterization of the layers are conducted through X-ray diffraction and reflectivity, time-of-flight secondary ion-mass spectrometry, and atomic force microscopy. Magnetic properties are evaluated by magnetic force microscopy, conversion electron Mössbauer spectroscopy, and vibrating sample magnetometer, being consistent with the presence of the phases identified by X-ray diffraction. Our results constitute a first step toward the use of cost-effective chemical methods for the synthesis of this class of multiferroic thin films.

  4. Synthesis of multiferroic Er-Fe-O thin films by atomic layer and chemical vapor deposition

    Science.gov (United States)

    Mantovan, R.; Vangelista, S.; Wiemer, C.; Lamperti, A.; Tallarida, G.; Chikoidze, E.; Dumont, Y.; Fanciulli, M.

    2014-05-01

    R-Fe-O (R = rare earth) compounds have recently attracted high interest as potential new multiferroic materials. Here, we report a method based on the solid-state reaction between Er2O3 and Fe layers, respectively grown by atomic layer deposition and chemical vapor deposition, to synthesize Er-Fe-O thin films. The reaction is induced by thermal annealing and evolution of the formed phases is followed by in situ grazing incidence X-ray diffraction. Dominant ErFeO3 and ErFe2O4 phases develop following subsequent thermal annealing processes at 850 °C in air and N2. Structural, chemical, and morphological characterization of the layers are conducted through X-ray diffraction and reflectivity, time-of-flight secondary ion-mass spectrometry, and atomic force microscopy. Magnetic properties are evaluated by magnetic force microscopy, conversion electron Mössbauer spectroscopy, and vibrating sample magnetometer, being consistent with the presence of the phases identified by X-ray diffraction. Our results constitute a first step toward the use of cost-effective chemical methods for the synthesis of this class of multiferroic thin films.

  5. Photo excitation and photoionization of alkali atoms%碱金属原子的光激发与光电离∗

    Institute of Scientific and Technical Information of China (English)

    戚晓秋; 汪峰; 戴长建

    2015-01-01

    The dynamical process of photoexcitation and photoionization of alkali atoms is studied with three-step laser pulses, focusing on the similarities and differences between Li and Cs atoms on their properties by making a comparison of them. Based on several excitation schemes, the present work not only establishes the rate equations of atom population for all related transition states, but also obtains the analytical solutions of photoexcitation and photoionization process. The mathematical solutions are simplified significantly by restricting the most general case to the several special cases, either designed or selected carefully, in order to highlight the main factors and obtain the physical insight underlying the complicated mathematical expressions. With self-programming, the possible impact of time configuration of laser pulses on the three-step laser excitation process of the photoexcitation and photoionization is calculated and studied systematically. Variation of the ionization efficiency with the laser parameters is investigated and discussed. With the same time configuration of laser pulses, the dependences of atom population for all the related transition states on the two different excitation paths are compared and analyzed, reflecting the impact of changing the atomic parameters. Under the similar excitation conditions, the differences of ionization efficiency between Li and Cs atoms are explored. Finally, based on the present study, several means for optimizing ionization efficiency are proposed.

  6. (Super)alkali atoms interacting with the σ electron cloud: a novel interaction mode triggers large nonlinear optical response of M@P₄ and M@C₃H₆ (M=Li, Na, K and Li₃O).

    Science.gov (United States)

    Zhao, Xingang; Yu, Guangtao; Huang, Xuri; Chen, Wei; Niu, Min

    2013-12-01

    Under high-level ab initio calculations, the geometrical structures and nonlinear optical properties of M@P₄ (M=Li, Na, K and Li₃O) and M@C₃H₆ (M=Li and Li₃O) were investigated; all were found to exhibit considerable first hyperpolarizabilities (18110, 1440, 22490, 50487, 2757 and 31776 au, respectively). The computational results revealed that when doping the (super)alkali atom M into the tetrahedral P₄ molecule, the original dual spherical aromaticity of the P₄ moiety is broken and new σ electron cloud is formed on the face of P₄ part interacting with the M atom. It was found that interaction of the (super)alkali atom with the σ electron cloud is a novel mode to produce diffuse excess electrons effectively to achieve a considerable β₀ value. Further, beyond the alkali atom, employing the superalkali unit can be a more effective approach to significantly enhance the first hyperpolarizability of the systems, due to the much lower vertical ionization potential. These results were further supported by the case of the (super)alkali atom interacting with the cyclopropane C₃H₆ molecule with its typical σ aromatic electron cloud. Moreover, the β₀ values of the M@P₄ series are nonmonotonic dependent on alkali atomic number, namely, 1440 au (M = Na) alkali atom and the interacting surface with the σ electron cloud in P4 is a crucial geometrical factor in determining their first hyperpolarizabilities. These intriguing findings will be advantageous for promoting the design of novel high-performance nonlinear optical materials.

  7. Rydberg Matter clusters of alkali metal atoms: the link between meteoritic matter, polar mesosphere summer echoes (PMSE), sporadic sodium layers, polar mesospheric clouds (PMCs, NLCs), and ion chemistry

    CERN Document Server

    Olofson, Frans; Holmlid, Leif

    2010-01-01

    A material exists which links together the influx of meteoritic matter from interplanetary space, the polar mesosphere summer echoes (PMSE), the sporadic sodium layers, the polar mesospheric clouds (PMCs, NLCs), and the observed ion chemistry in the mesosphere. The evidence in these research fields is here analyzed and found to agree well with the properties of Rydberg Matter (RM). This material has been studied with numerous methods in the laboratory. Alkali atoms, mainly Na, reach the mesosphere in the form of interplanetary (meteoritic, cometary) dust. The planar RM clusters NaN usually contain N = 19, 37 or 61 atoms, and have the density of air at 90 km altitude where they float. The diameters of the clusters are 10-100 nm from laboratory high precision radio frequency spectroscopic studies. Such experiments show that RM clusters interact strongly with radar frequencies: this explains the radio frequency heating and reflection studies of PMSE layers. The clusters give the low temperature in the mesosphere...

  8. Collisional Broadening and Shift of D1 and D2 Spectral Lines in Atomic Alkali Vapor - Noble Gas Systems

    Science.gov (United States)

    2013-03-01

    broadening using a WKB approximation in a semiclassical approach (Weisskopf, 1932a, 1932b), and Jabloński, who also used a WKB approximation but treated...appropriate, compiled and executed on AFIT’s Linux Cluster and on supercomputers run by the DoD High Performance Computing Modernization Program...The result is a cross section that decays with increasing temperature; we expect that a greater kinetic energy results in a lesser fractional change

  9. Improved preparation of small biological samples for mercury analysis using cold vapor atomic absorption spectroscopy.

    Science.gov (United States)

    Adair, B M; Cobb, G P

    1999-05-01

    Concentrations of mercury in biological samples collected for environmental studies are often less than 0.1 microgram/g. Low mercury concentrations and small organ sizes in many wildlife species (approximately 0.1 g) increase the difficulty of mercury determination at environmentally relevant concentrations. We have developed a digestion technique to extract mercury from small (0.1 g), biological samples at these relevant concentrations. Mean recoveries (+/- standard error) from validation trials of mercury fortified tissue samples using cold vapor atomic absorption spectroscopy for analysis ranged from 102 +/- 4.3% (2.5 micrograms/L, n = 15) to 108 +/- 1.4% (25 micrograms/L, n = 15). Recoveries of inorganic mercury were 99 +/- 5 (n = 19) for quality assurance samples analyzed during environmental evaluations conducted during a 24 month period. This technique can be used to determine total mercury concentrations of 60 ng Hg/g sample. Samples can be analyzed in standard laboratories in a short time, at minimal cost. The technique is versatile and can be used to determine mercury concentrations in several different matrices, limiting the time and expense of method development and validation.

  10. 氢原子能级与碱金属原子能级的比较研究%Comparative Studying of Hydrogen Atomic Energy Level and Alkali Metal Atomic Energy Level

    Institute of Scientific and Technical Information of China (English)

    王建伟; 蒲小芹

    2014-01-01

    The article by Bohr theory and The analysis of forces method, considered the interaction of different sit-uation, hydrogen atoms with alkali metal atomic energy level structure have been analyzed, and the numerical cal-culation, energy level diagram have been drawn out., Hydrogen energy and alkali metal atomic energy level were compared, by using the method of comparative study on the similarities and differences are found out.%运用玻尔理论及受力分析的方法,考虑相互作用的不同情况,分析了氢原子与碱金属原子能级结构,并进行了数值计算,画出了能级结构图。再运用比较研究的方法对氢原子能级与碱金属原子能级进行比较,找出其相同点及不同点。

  11. Detection of slow atoms confined in a Cesium vapor cell by spatially separated pump and probe laser beams

    CERN Document Server

    Todorov, Petko; Maurin, Isabelle; Saltiel, Solomon; Bloch, Daniel

    2013-01-01

    The velocity distribution of atoms in a thermal gas is usually described through a Maxwell-Boltzman distribution of energy, and assumes isotropy. As a consequence, the probability for an atom to leave the surface under an azimuth angle {\\theta} should evolve as cos {\\theta}, in spite of the fact that there is no microscopic basis to justify such a law. The contribution of atoms moving at a grazing incidence towards or from the surface, i.e. atoms with a small normal velocity, here called "slow" atoms, reveals essential in the development of spectroscopic methods probing a dilute atomic vapor in the vicinity of a surface, enabling a sub-Doppler resolution under a normal incidence irradiation. The probability for such "slow" atoms may be reduced by surface roughness and atom-surface interaction. Here, we describe a method to observe and to count these slow atoms relying on a mechanical discrimination, through spatially separated pump and probe beams. We also report on our experimental progresses toward such a g...

  12. Atomic magnetometer

    Science.gov (United States)

    Schwindt, Peter [Albuquerque, NM; Johnson, Cort N [Albuquerque, NM

    2012-07-03

    An atomic magnetometer is disclosed which uses a pump light beam at a D1 or D2 transition of an alkali metal vapor to magnetically polarize the vapor in a heated cell, and a probe light beam at a different D2 or D1 transition to sense the magnetic field via a polarization rotation of the probe light beam. The pump and probe light beams are both directed along substantially the same optical path through an optical waveplate and through the heated cell to an optical filter which blocks the pump light beam while transmitting the probe light beam to one or more photodetectors which generate electrical signals to sense the magnetic field. The optical waveplate functions as a quarter waveplate to circularly polarize the pump light beam, and as a half waveplate to maintain the probe light beam linearly polarized.

  13. Adsorption kinetics of surfactants at liquid-solid and liquid-vapor interfaces from atomic-scale simulations

    Science.gov (United States)

    Iskrenova, Eugeniya K.; Patnaik, Soumya S.

    2012-02-01

    Nucleate pool boiling of pure liquid is a complex process involving different size- and time-scale phenomena. The appearance of the first nanobubble in the liquid at the bottom of a hot pan, the detachment of the bubble from the solid surface, its subsequent coalescence with other bubbles, all represent complex multiscale phenomena. Surfactants added to water increase the complexity of the process by contributing to the dynamic surface tension at the liquid-vapor and liquid-solid interfaces and thus affecting the heat and mass transfer at those interfaces. We apply molecular dynamics simulations to study the adsorption kinetics of anionic, cationic, and non-ionic surfactants at liquid/solid and liquid/vapor interfaces. The all-atom vs. united-atom approaches for the solid and surfactants are surveyed in view of their applicability at near boiling temperatures and a range of model water potentials is assessed for reproducing the thermal properties of water at boiling conditions.

  14. Critical points of metal vapors

    Energy Technology Data Exchange (ETDEWEB)

    Khomkin, A. L., E-mail: alhomkin@mail.ru; Shumikhin, A. S. [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation)

    2015-09-15

    A new method is proposed for calculating the parameters of critical points and binodals for the vapor–liquid (insulator–metal) phase transition in vapors of metals with multielectron valence shells. The method is based on a model developed earlier for the vapors of alkali metals, atomic hydrogen, and exciton gas, proceeding from the assumption that the cohesion determining the basic characteristics of metals under normal conditions is also responsible for their properties in the vicinity of the critical point. It is proposed to calculate the cohesion of multielectron atoms using well-known scaling relations for the binding energy, which are constructed for most metals in the periodic table by processing the results of many numerical calculations. The adopted model allows the parameters of critical points and binodals for the vapor–liquid phase transition in metal vapors to be calculated using published data on the properties of metals under normal conditions. The parameters of critical points have been calculated for a large number of metals and show satisfactory agreement with experimental data for alkali metals and with available estimates for all other metals. Binodals of metals have been calculated for the first time.

  15. Simple analysis of total mercury and methylmercury in seafood using heating vaporization atomic absorption spectrometry.

    Science.gov (United States)

    Yoshimoto, Keisuke; Anh, Hoang Thi Van; Yamamoto, Atsushi; Koriyama, Chihaya; Ishibashi, Yasuhiro; Tabata, Masaaki; Nakano, Atsuhiro; Yamamoto, Megumi

    2016-01-01

    This study aimed to develop a simpler method for determining total mercury (T-Hg) and methylmercury (MeHg) in biological samples by using methyl isobutyl ketone (MIBK) in the degreasing step. The fat in the samples was extracted by MIBK to the upper phase. T-Hg transferred into the water phase. This was followed by the extraction of MeHg from the water phase using HBr, CuCl2 and toluene. The MeHg fraction was reverse-extracted into L-cysteine-sodium acetate solution from toluene. The concentrations of T-Hg and MeHg were determined by heating vaporization atomic absorption spectrometry. Certified reference materials for T-Hg and MeHg in hair and fish were accurately measured using this method. This method was then applied to determine T-Hg and MeHg concentrations in the muscle, liver and gonads of seafood for the risk assessment of MeHg exposure. The mean T-Hg and MeHg concentrations in squid eggs were 0.023 and 0.022 µg/g, and in squid nidamental glands 0.052 and 0.049 µg/g, respectively. The MeHg/T-Hg ratios in the eggs and nidamental glands of squid were 94.4% and 96.5%, respectively. The mean T-Hg and MeHg concentrations in the gonads of sea urchins were 0.043 and 0.001 µg/g, respectively, with a MeHg/T-Hg ratio of 3.5%. We developed an efficient analytical method for T-Hg and MeHg using MIBK in the degreasing step. The new information on MeHg concentration and MeHg/T-Hg ratios in the egg or nidamental glands of squid and gonads of sea urchin will also be useful for risk assessment of mercury in seafood.

  16. Atomic arrangement and electron band structure of Si(1 1 1)-ß-√3 x √3-Bi reconstruction modified by alkali-metal adsorption: ab initio study.

    Science.gov (United States)

    Eremeev, S V; Chukurov, E N; Gruznev, D V; Zotov, A V; Saranin, A A

    2015-08-05

    Using ab initio calculations, atomic structure and electronic properties of Si(1 1 1)[Formula: see text]-Bi surface modified by adsorption of 1/3 monolayer of alkali metals, Li, Na, K, Rb and Cs, have been explored. Upon adsorption of all metals, a similar atomic structure develops at the surface where twisted chained Bi trimers are arranged into a honeycomb network and alkali metal atoms occupy the [Formula: see text] sites in the center of each honeycomb unit. Among other structural characteristics, the greatest variation concerns the relative heights at which alkali metals reside with respect to Bi-trimer layer. Except for Li, the other metals reside higher than Bi layer and their heights increase with atomic number. All adsorbed surface structures display similar electron band structures of which the most essential feature is metallic surface-state band with a giant spin splitting. This electronic property allows one to consider the Si(1 1 1)[Formula: see text]-Bi surfaces modified by alkali metal adsorption as a set of material systems showing promise for spintronic applications.

  17. Atomic arrangement and electron band structure of Si(1 1 1)-ß-\\sqrt{3}\\times \\sqrt{3} -Bi reconstruction modified by alkali-metal adsorption: ab initio study

    Science.gov (United States)

    Eremeev, S. V.; Chukurov, E. N.; Gruznev, D. V.; Zotov, A. V.; Saranin, A. A.

    2015-08-01

    Using ab initio calculations, atomic structure and electronic properties of Si(1 1 1)\\sqrt{3}× \\sqrt{3} -Bi surface modified by adsorption of 1/3 monolayer of alkali metals, Li, Na, K, Rb and Cs, have been explored. Upon adsorption of all metals, a similar atomic structure develops at the surface where twisted chained Bi trimers are arranged into a honeycomb network and alkali metal atoms occupy the {{T}4} sites in the center of each honeycomb unit. Among other structural characteristics, the greatest variation concerns the relative heights at which alkali metals reside with respect to Bi-trimer layer. Except for Li, the other metals reside higher than Bi layer and their heights increase with atomic number. All adsorbed surface structures display similar electron band structures of which the most essential feature is metallic surface-state band with a giant spin splitting. This electronic property allows one to consider the Si(1 1 1)\\sqrt{3}× \\sqrt{3} -Bi surfaces modified by alkali metal adsorption as a set of material systems showing promise for spintronic applications.

  18. Single-resonance optical pumping spectroscopy and application in dressed-state measurement with atomic vapor cell at room temperature.

    Science.gov (United States)

    Liang, Qiangbing; Yang, Baodong; Zhang, Tiancai; Wang, Junmin

    2010-06-21

    By monitoring the transmission of probe laser beam (also served as coupling laser beam) which is locked to a cycling hyperfine transition of cesium D(2) line, while pumping laser is scanned across cesium D(1) or D(2) lines, the single-resonance optical pumping (SROP) spectra are obtained with atomic vapor cell. The SROP spectra indicate the variation of the zero-velocity atoms population of one hyperfine fold of ground state, which is optically pumped into another hyperfine fold of ground state by pumping laser. With the virtue of Doppler-free linewidth, high signal-to-noise ratio (SNR), flat background and elimination of crossover resonance lines (CRLs), the SROP spectra with atomic vapor cell around room temperature can be employed to measure dressed-state splitting of ground state, which is normally detected with laser-cooled atomic sample only, even if the dressed-state splitting is much smaller than the Doppler-broaden linewidth at room temperature.

  19. Atomic layer chemical vapor deposition of ZrO2-based dielectric films: Nanostructure and nanochemistry

    Science.gov (United States)

    Dey, S. K.; Wang, C.-G.; Tang, D.; Kim, M. J.; Carpenter, R. W.; Werkhoven, C.; Shero, E.

    2003-04-01

    A 4 nm layer of ZrOx (targeted x˜2) was deposited on an interfacial layer (IL) of native oxide (SiO, t˜1.2 nm) surface on 200 mm Si wafers by a manufacturable atomic layer chemical vapor deposition technique at 300 °C. Some as-deposited layers were subjected to a postdeposition, rapid thermal annealing at 700 °C for 5 min in flowing oxygen at atmospheric pressure. The experimental x-ray diffraction, x-ray photoelectron spectroscopy, high-resolution transmission electron microscopy, and high-resolution parallel electron energy loss spectroscopy results showed that a multiphase and heterogeneous structure evolved, which we call the Zr-O/IL/Si stack. The as-deposited Zr-O layer was amorphous ZrO2-rich Zr silicate containing about 15% by volume of embedded ZrO2 nanocrystals, which transformed to a glass nanoceramic (with over 90% by volume of predominantly tetragonal-ZrO2 (t-ZrO2) and monoclinic-ZrO2 (m-ZrO2) nanocrystals) upon annealing. The formation of disordered amorphous regions within some of the nanocrystals, as well as crystalline regions with defects, probably gave rise to lattice strains and deformations. The interfacial layer (IL) was partitioned into an upper SiO2-rich Zr silicate and the lower SiOx. The latter was substoichiometric and the average oxidation state increased from Si0.86+ in SiO0.43 (as-deposited) to Si1.32+ in SiO0.66 (annealed). This high oxygen deficiency in SiOx was indicative of the low mobility of oxidizing specie in the Zr-O layer. The stacks were characterized for their dielectric properties in the Pt/{Zr-O/IL}/Si metal oxide-semiconductor capacitor (MOSCAP) configuration. The measured equivalent oxide thickness (EOT) was not consistent with the calculated EOT using a bilayer model of ZrO2 and SiO2, and the capacitance in accumulation (and therefore, EOT and kZr-O) was frequency dispersive, trends well documented in literature. This behavior is qualitatively explained in terms of the multilayer nanostructure and nanochemistry that

  20. Flow injection-chemical vapor generation atomic fluorescence spectrometry hyphenated system for organic mercury determination: A step forward

    Energy Technology Data Exchange (ETDEWEB)

    Angeli, Valeria [National Research Council of Italy, C.N.R., Istituto di Chimica dei Composti Organo Metallici - ICCOM-UOS Pisa, Area di Ricerca, Via G. Moruzzi 1, 56124 Pisa (Italy); Biagi, Simona [National Research Council of Italy, C.N.R., Istituto per i Processi Chimico-Fisici - IPCF-UOS Pisa, Area di Ricerca, Via G. Moruzzi 1, 56124 Pisa (Italy); Ghimenti, Silvia [University of Pisa, Department of Chemistry and Industrial Chemistry, Via Risorgimento 35, 56126 Pisa (Italy); Onor, Massimo; D' Ulivo, Alessandro [National Research Council of Italy, C.N.R., Istituto di Chimica dei Composti Organo Metallici - ICCOM-UOS Pisa, Area di Ricerca, Via G. Moruzzi 1, 56124 Pisa (Italy); Bramanti, Emilia, E-mail: bramanti@pi.iccom.cnr.it [National Research Council of Italy, C.N.R., Istituto di Chimica dei Composti Organo Metallici - ICCOM-UOS Pisa, Area di Ricerca, Via G. Moruzzi 1, 56124 Pisa (Italy)

    2011-11-15

    Monomethylmercury and ethylmercury were determined on line using flow injection-chemical vapor generation atomic fluorescence spectrometry without neither requiring a pre-treatment with chemical oxidants, nor UV/MW additional post column interface, nor organic solvents, nor complexing agents, such as cysteine. Inorganic mercury, monomethylmercury and ethylmercury were detected by atomic fluorescence spectrometry in an Ar/H{sub 2} miniaturized flame after sodium borohydride reduction to Hg{sup 0}, monomethylmercury hydride and ethylmercury hydride, respectively. The effect of mercury complexing agent such as cysteine, ethylendiaminotetracetic acid and HCl with respect to water and Ar/H{sub 2} microflame was investigated. The behavior of inorganic mercury, monomethylmercury and ethylmercury and their cysteine-complexes was also studied by continuous flow-chemical vapor generation atomic fluorescence spectrometry in order to characterize the reduction reaction with tetrahydroborate. When complexed with cysteine, inorganic mercury, monomethylmercury and ethylmercury cannot be separately quantified varying tetrahydroborate concentration due to a lack of selectivity, and their speciation requires a pre-separation stage (e.g. a chromatographic separation). If not complexed with cysteine, monomethylmercury and ethylmercury cannot be separated, as well, but their sum can be quantified separately with respect to inorganic mercury choosing a suitable concentration of tetrahydroborate (e.g. 10{sup -5} mol L{sup -1}), thus allowing the organic/inorganic mercury speciation. The detection limits of the flow injection-chemical vapor generation atomic fluorescence spectrometry method were about 45 nmol L{sup -1} (as mercury) for all the species considered, a relative standard deviation ranging between 1.8 and 2.9% and a linear dynamic range between 0.1 and 5 {mu}mol L{sup -1} were obtained. Recoveries of monomethylmercury and ethylmercury with respect to inorganic mercury were

  1. Flow injection-chemical vapor generation atomic fluorescence spectrometry hyphenated system for organic mercury determination: A step forward

    Science.gov (United States)

    Angeli, Valeria; Biagi, Simona; Ghimenti, Silvia; Onor, Massimo; D'Ulivo, Alessandro; Bramanti, Emilia

    2011-11-01

    Monomethylmercury and ethylmercury were determined on line using flow injection-chemical vapor generation atomic fluorescence spectrometry without neither requiring a pre-treatment with chemical oxidants, nor UV/MW additional post column interface, nor organic solvents, nor complexing agents, such as cysteine. Inorganic mercury, monomethylmercury and ethylmercury were detected by atomic fluorescence spectrometry in an Ar/H 2 miniaturized flame after sodium borohydride reduction to Hg 0, monomethylmercury hydride and ethylmercury hydride, respectively. The effect of mercury complexing agent such as cysteine, ethylendiaminotetracetic acid and HCl with respect to water and Ar/H 2 microflame was investigated. The behavior of inorganic mercury, monomethylmercury and ethylmercury and their cysteine-complexes was also studied by continuous flow-chemical vapor generation atomic fluorescence spectrometry in order to characterize the reduction reaction with tetrahydroborate. When complexed with cysteine, inorganic mercury, monomethylmercury and ethylmercury cannot be separately quantified varying tetrahydroborate concentration due to a lack of selectivity, and their speciation requires a pre-separation stage (e.g. a chromatographic separation). If not complexed with cysteine, monomethylmercury and ethylmercury cannot be separated, as well, but their sum can be quantified separately with respect to inorganic mercury choosing a suitable concentration of tetrahydroborate (e.g. 10 - 5 mol L - 1 ), thus allowing the organic/inorganic mercury speciation. The detection limits of the flow injection-chemical vapor generation atomic fluorescence spectrometry method were about 45 nmol L - 1 (as mercury) for all the species considered, a relative standard deviation ranging between 1.8 and 2.9% and a linear dynamic range between 0.1 and 5 μmol L - 1 were obtained. Recoveries of monomethylmercury and ethylmercury with respect to inorganic mercury were never less than 91%. Flow injection

  2. Spin-orbit coupling in the dissociative excitation of alkali atoms at the surface of rare gas clusters: A theoretical study.

    Science.gov (United States)

    Gervais, B; Zanuttini, D; Douady, J

    2016-05-21

    We analyze the role of the spin-orbit (SO) coupling in the dissociative dynamics of excited alkali atoms at the surface of small rare gas clusters. The electronic structure of the whole system is deduced from a one-electron model based on core polarization pseudo-potentials. It allows us to obtain in the same footing the energy, forces, and non-adiabatic couplings used to simulate the dynamics by means of a surface hopping method. The fine structure state population is analyzed by considering the relative magnitude of the SO coupling ξ, with respect to the spin-free potential energy. We identify three regimes of ξ-values leading to different evolution of adiabatic state population after excitation of the system in the uppermost state of the lowest np (2)P shell. For sufficiently small ξ, the final population of the J=12 atomic states, P12, grows up linearly from P12=13 at ξ = 0 after a diabatic dynamics. For large values of ξ, we observe a rather adiabatic dynamics with P12 decreasing as ξ increases. For intermediate values of ξ, the coupling is extremely efficient and a complete transfer of population is observed for the set of parameters associated to NaAr3 and NaAr4 clusters.

  3. Comparison of Adsorbed Mercury Screening Method With Cold-Vapor Atomic Absorption Spectrophotometry for Determination of Mercury in Soil

    Science.gov (United States)

    Easterling, Donald F.; Hovanitz, Edward S.; Street, Kenneth W.

    2000-01-01

    A field screening method for the determination of elemental mercury in environmental soil samples involves the thermal desorption of the mercury from the sample onto gold and then the thermal desorption from the gold to a gold-film mercury vapor analyzer. This field screening method contains a large number of conditions that could be optimized for the various types of soils encountered. In this study, the conditions were optimized for the determination of mercury in silty clay materials, and the results were comparable to the cold-vapor atomic absorption spectrophotometric method of determination. This paper discusses the benefits and disadvantages of employing the field screening method and provides the sequence of conditions that must be optimized to employ this method of determination on other soil types.

  4. Prospects for diode-pumped alkali-atom-based hollow-core photonic-crystal fiber lasers.

    Science.gov (United States)

    Sintov, Yoav; Malka, Dror; Zalevsky, Zeev

    2014-08-15

    By employing large hollow-core Kagome fiber in a double-clad configuration, the performance of a potentially rubidium vapor-based fiber laser is explored. The absorbed power and laser efficiency versus pump power are calculated utilizing a simple laser model. Our results show that a Kagome-based high-power fiber laser is feasible provided that the value of the collisional fine-structure mixing rate will be elevated by increasing the ambient temperature or by increasing the helium pressure.

  5. Alkali Aggregate Reaction in Alkali Slag Cement Mortars

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    By means of "Mortar Bar Method",the ratio of cement to aggregate was kept as a constant 1∶2.25,the water-cement ratio of the mixture was 0.40,and six prism specimens were prepared for each batch of mixing proportions with dimensions of 10×10×60mm3 at 38±2℃ and RH≥95%, the influences of content and particle size of active aggregate, sort and content of alkali component and type of slag on the expansion ratios of alkali-activated slag cement(ASC) mortars due to alkali aggregate reaction(AAR) were studied. According to atomic absorption spectrometry,the amount of free alkali was measured in ASC mortars at 90d.The results show above factors affect AAR remarkably,but no dangerous AAR will occur in ASC system when the amount of active aggregate is below 15% and the mass fraction of alkali is not more than 5% (Na2O).Alkali participated in reaction as an independent component, and some hydrates containing alkali cations were produced, free alkalis in ASC system can be reduced enormously.Moreover,slag is an effective inhibitor, the possibility of generating dangerous AAR in ASC system is much lower at same conditions than that in ordinary Portland cement system.

  6. Atomic parity violation in heavy alkalis: detection by stimulated emission for cesium and traps for cold francium

    Energy Technology Data Exchange (ETDEWEB)

    Sanguinetti, St

    2004-07-01

    The present work deals with the recent advances of atomic spectroscopy experiments on cesium and francium, which aim at precise parity violation (PV) measurements in these atoms. Within the framework of a 'double-badged thesis', the candidate devoted himself on the one hand to the preliminary PV measurement (8% accuracy) of the present Cs experiment at the Kastler-Brossel laboratory in Paris and on the other hand to the preparation of a Fr radioactive atomic sample (production and trapping) at the LNL (INFN) in Italy. The two experiments are at very different stages. The measurements reported for cesium were actually made possible thanks to the work initiated in 1991, for the PV detection by stimulated emission. The Italian experiment is instead in a beginning stage: in order to probe the properties of francium, which is unstable, a number of atoms large enough has to be first produced and collected. The PV schemes which proved to be well suited for cesium are a solid starting point for the case of francium. (author)

  7. Quantum-state-controlled Penning-ionization reactions between ultracold alkali-metal and metastable helium atoms

    Science.gov (United States)

    Flores, A. S.; Vassen, W.; Knoop, S.

    2016-11-01

    In an ultracold, optically trapped mixture of 87Rb and metastable triplet 4He atoms we have studied trap loss for different spin-state combinations, for which interspecies Penning ionization is the main two-body loss process. We observe long trapping lifetimes for the purely quartet spin-state combination, indicating strong suppression of Penning-ionization loss by at least two orders of magnitude. For the other spin mixtures we observe short lifetimes that depend linearly on the doublet character of the entrance channel. We compare the extracted loss rate coefficient with recent predictions of multichannel quantum-defect theory for reactive collisions involving a strong exothermic loss channel and find near-universal loss for doublet scattering. Our work demonstrates control of Penning-ionization reactive collisions by internal atomic state preparation.

  8. Optimal densities of alkali metal atoms in an optically pumped K-Rb hybrid atomic magnetometer considering the spatial distribution of spin polarization.

    Science.gov (United States)

    Ito, Yosuke; Sato, Daichi; Kamada, Keigo; Kobayashi, Tetsuo

    2016-07-11

    An optically pumped K-Rb hybrid atomic magnetometer can be a useful tool for biomagnetic measurements due to the high spatial homogeneity of its sensor property inside a cell. However, because the property varies depending on the densities of potassium and rubidium atoms, optimization of the densities is essential. In this study, by using the Bloch equations of K and Rb and considering the spatial distribution of the spin polarization, we confirmed that the calculation results of spin polarization behavior are in good agreement with the experimental data. Using our model, we calculated the spatial distribution of the spin polarization and found that the optimal density of K atoms is 3 × 1019 m-3 and the optimal density ratio is nK/nRb ~ 400 to maximize the output signal and enhance spatial homogeneity of the sensor property.

  9. Chemical Vapor Deposition of Atomically-Thin Molybdenum Disulfide (MoS2)

    Science.gov (United States)

    2015-03-01

    photoluminescence. 15. SUBJECT TERMS Chemical vapor deposition (CVD) Nanotechnology Molybdenum disulfide (MoS2) Raman spectroscopy 16...by ANSI Std. Z39.18 UNCLASSIFIED Approved for public release; distribution is unlimited. i CONTENTS Page Introduction 1...UNCLASSIFIED Approved for public release; distribution is unlimited. 1 INTRODUCTION Recently, an explosion of interest in low-dimensional

  10. Precision measurements of cross sections of inelastic processes realized in collisions of alkali metal ions with atoms of rare gases

    CERN Document Server

    Lomsadze, R A; Mosulishvili, N O; Kezerashvili, R Ya

    2015-01-01

    This work presents a multifaceted experimental study of collisions of Na$^{+}$ and K$^{+}$ ions in the energy range 0.5 -- 10 keV with He and Ar atoms. Absolute cross sections for charge-exchange, ionization, stripping and excitation were measured using a refined version of the transfer electric field method, angle- and energy-dependent collection of product ions, energy loss, and optical spectroscopy. The experimental data and the schematic correlation diagrams have been employed to analyze and determine the mechanisms for these processes.

  11. Precision measurements of cross-sections for inelastic processes in collisions of alkali metal ions with atoms of rare gases

    Science.gov (United States)

    Lomsadze, R. A.; Gochitashvili, M. R.; Kezerashvili, R. Ya.

    2017-01-01

    A multifaceted experimental study of collisions of Na+ and K+ ions in the energy range of 0.5-10 keV with He and Ar atoms is presented. Absolute cross-sections for charge-exchange, ionization, stripping and excitation processes were measured using a refined version of the transfer electric field method, angle- and energy-dependent collection of product ions, energy loss and optical spectroscopy methods. The experimental data and the schematic correlation diagrams are employed to analyze and determine the mechanisms for these processes.

  12. Plasma Formation During Operation of a Diode Pumped Alkali Laser (DPAL) in Cs

    Science.gov (United States)

    Babaeva, Natalia Yu.; Zatsarinny, Oleg; Bartschat, Klaus; Kushner, Mark J.

    2014-10-01

    Diode pumped Alkali Lasers (DPALs) produce laser action on the resonant lines of alkali atoms. Diode lasers resonantly pump the 2P3/2 state of the alkali atom which is collisionally relaxed to the 2P3/2 state which then lases to the ground state 2S1/2. The low optical quality of high power semiconductor diode lasers is converted into high optical quality laser radiation from the alkali vapor. The Cs DPAL system using Ar/Cs/C2H6 mixtures has shown promising results. (C2H6 is the collisional relaxant.) In other studies, resonant excitation of alkali vapor by low power lasers has been used to produce highly ionized channels, initiated through associative ionization and superelastic electron heating. The issue then arises if plasma formation occurs during DPAL by similar mechanisms which would be detrimental to laser performance. In this paper, we report on results from a computational study of a DPAL using Cs vapor. The global model addresses quasi-cw pumping of the Cs(2P3/2) state by laser diodes, and includes a full accounting of the resulting electron kinetics. To enable this study, the B-spline R-matrix (BSR) with pseudostates method was employed to calculate electron impact cross sections for Cs. We found that for pump rates of many to 10 kW/cm2, plasma densities approaching 1013 cm-3 occur during laser oscillation with higher values in the absence of laser oscillation. Supported by DoD High Energy Laser Mult. Res. Initiative and NSF.

  13. Polarization squeezing of light by single passage through an atomic vapor

    Energy Technology Data Exchange (ETDEWEB)

    Barreiro, S.; Valente, P.; Failache, H.; Lezama, A. [Instituto de Fisica, Facultad de Ingenieria, Universidad de la Republica, J. Herrera y Reissig 565, 11300 Montevideo (Uruguay)

    2011-09-15

    We have studied relative-intensity fluctuations for a variable set of orthogonal elliptic polarization components of a linearly polarized laser beam traversing a resonant {sup 87}Rb vapor cell. Significant polarization squeezing at the threshold level (-3dB) required for the implementation of several continuous-variable quantum protocols was observed. The extreme simplicity of the setup, which is based on standard polarization components, makes it particularly convenient for quantum information applications.

  14. Chemistry of recoil atoms of bromine-82 in neutron-irradiated crystalline perbromates of the alkali metals and ammonium

    Energy Technology Data Exchange (ETDEWEB)

    Gavrilov, V.V.; Isupov, V.K.; Kirin, I.S.

    1975-01-01

    It was established by ion exchange chromatography that the recoil atoms of bromine-82 in perbromates with thermal neutrons are stabilized in the form of five valence forms: BrO/sub 4//sup -/, BrO/sub 3//sup -/, BrO/sub 2//sup -/, BrO/sup -/, Br/sup -/. The retention of bromine-82 of BrO/sub 4//sup -/ is 2.1 +- 0.4 percent for LiBrO/sub 4/, 2.1 +- 0.4 percent for NaBrO/sub 4/, 2.3 +- 0.4 percent for KBrO/sub 4/, 2.6 +- 0.4 percent for RbBrO/sub 4/, 2.2 +- 0.4 percent for CsBrO/sub 4/, and 1.6 +- 0.4 percent for NH/sub 4/BrO/sub 4/.

  15. Multiwavelength Strontium Vapor Lasers

    Science.gov (United States)

    Soldatov, A. N.; Yudin, N. A.

    2016-08-01

    Based on an analysis of experimental and theoretical works, modern notion on conditions of forming of population density inversion on self-terminating IR transitions of alkali-earth metals is given. It is demonstrated that there is a significant difference in the inversion formation in lasers on self-terminating transitions in the visible and near-IR ranges and lasers on self-terminating transitions of alkali-earth metals lasing IR lines in the mid-IR range. It is shown that in the discharge circuit of lasers on self-terminating metal atom transitions (LSMT) there are processes strengthening the influence of the known mechanism limiting the frequency and energy characteristics (FEC) of radiation caused by the presence of prepulse electron concentration. The mechanism of influence of these processes on FEC of the LSMT and technical methods of their neutralization are considered. The possibility of obtaining average lasing power of ~200 W from one liter volume of the active medium of the strontium vapor laser is demonstrated under conditions of neutralization of these processes.

  16. Nanosized alkali-metal-doped ethoxotitanate clusters.

    Science.gov (United States)

    Chen, Yang; Trzop, Elzbieta; Makal, Anna; Sokolow, Jesse D; Coppens, Philip

    2013-05-06

    The synthesis and crystallographic characterization of alkali-metal-doped ethoxotitanate clusters with 28 and 29 Ti atoms as well as a new dopant-free Ti28 cluster are presented. The light-metal-doped polyoxotitanate clusters in which the alkali-metal atom is the critical structure-determining component are the largest synthesized so far. Calculations show that doping with light alkali atoms narrows the band gap compared with the nondoped crystals but does not introduce additional energy levels within the band gap.

  17. Direct determination of mercury in white vinegar by matrix assisted photochemical vapor generation atomic fluorescence spectrometry detection

    Energy Technology Data Exchange (ETDEWEB)

    Liu Qingyang, E-mail: liuqingyang0807@yahoo.com.c [Beijing Center for Physical and Chemical Analysis, Beijing 100089 (China)

    2010-07-15

    This paper proposes the use of photochemical vapor generation with acetic acid as sample introduction for the direct determination of ultra-trace mercury in white vinegars by atomic fluorescence spectrometry. Under ultraviolet irradiation, the sample matrix (acetic acid) can reduce mercury ion to atomic mercury Hg{sup 0}, which is swept by argon gas into an atomic fluorescence spectrometer for subsequent analytical measurements. The effects of several factors such as the concentration of acetic acid, irradiation time, the flow rate of the carrier gas and matrix effects were discussed and optimized to give detection limits of 0.08 ng mL{sup -1} for mercury. Using the experimental conditions established during the optimization (3% v/v acetic acid, 30 s irradiation time and 20 W mercury lamp), the precision levels, expressed as relative standard deviation, were 4.6% (one day) and 7.8% (inter-day) for mercury (n = 9). Addition/recovery tests for evaluation of the accuracy were in the range of 92-98% for mercury. The method was also validated by analysis of vinegar samples without detectable amount of Hg spiked with aqueous standard reference materials (GBW(E) 080392 and GBW(E) 080393). The results were also compared with those obtained by acid digestion procedure and determination of mercury by ICP-MS. There was no significant difference between the results obtained by the two methods based on a t-test (at 95% confidence level).

  18. Direct determination of mercury in white vinegar by matrix assisted photochemical vapor generation atomic fluorescence spectrometry detection

    Science.gov (United States)

    Liu, Qingyang

    2010-07-01

    This paper proposes the use of photochemical vapor generation with acetic acid as sample introduction for the direct determination of ultra-trace mercury in white vinegars by atomic fluorescence spectrometry. Under ultraviolet irradiation, the sample matrix (acetic acid) can reduce mercury ion to atomic mercury Hg 0, which is swept by argon gas into an atomic fluorescence spectrometer for subsequent analytical measurements. The effects of several factors such as the concentration of acetic acid, irradiation time, the flow rate of the carrier gas and matrix effects were discussed and optimized to give detection limits of 0.08 ng mL -1 for mercury. Using the experimental conditions established during the optimization (3% v/v acetic acid, 30 s irradiation time and 20 W mercury lamp), the precision levels, expressed as relative standard deviation, were 4.6% (one day) and 7.8% (inter-day) for mercury ( n = 9). Addition/recovery tests for evaluation of the accuracy were in the range of 92-98% for mercury. The method was also validated by analysis of vinegar samples without detectable amount of Hg spiked with aqueous standard reference materials (GBW(E) 080392 and GBW(E) 080393). The results were also compared with those obtained by acid digestion procedure and determination of mercury by ICP-MS. There was no significant difference between the results obtained by the two methods based on a t-test (at 95% confidence level).

  19. A low phase noise microwave frequency synthesis for a high-performance cesium vapor cell atomic clock.

    Science.gov (United States)

    François, B; Calosso, C E; Danet, J M; Boudot, R

    2014-09-01

    We report the development, absolute phase noise, and residual phase noise characterization of a 9.192 GHz microwave frequency synthesis chain devoted to be used as a local oscillator in a high-performance cesium vapor cell atomic clock based on coherent population trapping (CPT). It is based on frequency multiplication of an ultra-low phase noise 100 MHz oven-controlled quartz crystal oscillator using a nonlinear transmission line-based chain. Absolute phase noise performances of the 9.192 GHz output signal are measured to be -42, -100, -117 dB rad(2)/Hz and -129 dB rad(2)/Hz at 1 Hz, 100 Hz, 1 kHz, and 10 kHz offset frequencies, respectively. Compared to current results obtained in a state-of-the-art CPT-based frequency standard developed at LNE-SYRTE, this represents an improvement of 8 dB and 10 dB at f = 166 Hz and f = 10 kHz, respectively. With such performances, the expected Dick effect contribution to the atomic clock short term frequency stability is reported at a level of 6.2 × 10(-14) at 1 s integration time, that is a factor 3 higher than the atomic clock shot noise limit. Main limitations are pointed out.

  20. Site Preference in Multimetallic Nanoclusters: Incorporation of Alkali Metal Ions or Copper Atoms into the Alkynyl-Protected Body-Centered Cubic Cluster [Au7 Ag8 (C≡C(t) Bu)12 ]().

    Science.gov (United States)

    Wang, Yu; Su, Haifeng; Ren, Liting; Malola, Sami; Lin, Shuichao; Teo, Boon K; Häkkinen, Hannu; Zheng, Nanfeng

    2016-11-21

    The synthesis, structure, substitution chemistry, and optical properties of the gold-centered cubic monocationic cluster [Au@Ag8 @Au6 (C≡C(t) Bu)12 ](+) are reported. The metal framework of this cluster can be described as a fragment of a body-centered cubic (bcc) lattice with the silver and gold atoms occupying the vertices and the body center of the cube, respectively. The incorporation of alkali metal atoms gave rise to [Mn Ag8-n Au7 (C≡C(t) Bu)12 ](+) clusters (n=1 for M=Na, K, Rb, Cs and n=2 for M=K, Rb), with the alkali metal ion(s) presumably occupying the vertex site(s), whereas the incorporation of copper atoms produced [Cun Ag8 Au7-n (C≡C(t) Bu)12 ](+) clusters (n=1-6), with the Cu atom(s) presumably occupying the capping site(s). The parent cluster exhibited strong emission in the near-IR region (λmax =818 nm) with a quantum yield of 2 % upon excitation at λ=482 nm. Its photoluminescence was quenched upon substitution with a Na(+) ion. DFT calculations confirmed the superatom characteristics of the title compound and the sodium-substituted derivatives.

  1. Organic, inorganic and total mercury determination in fish by chemical vapor generation with collection on a gold gauze and electrothermal atomic absorption spectrometry

    Science.gov (United States)

    Duarte, Fábio Andrei; Bizzi, Cezar Augusto; Antes, Fabiane Goldschmidt; Dressler, Valderi Luiz; Flores, Érico Marlon de Moraes

    2009-06-01

    A method for organic, inorganic and total mercury determination in fish tissue has been developed using chemical vapor generation and collection of mercury vapor on a gold gauze inside a graphite tube and further atomization by electrothermal atomic absorption spectrometry. After drying and cryogenic grinding, potassium bromide and hydrochloric acid solution (1 mol L - 1 KBr in 6 mol L - 1 HCl) was added to the samples. After centrifugation, total mercury was determined in the supernatant. Organomercury compounds were selectively extracted from KBr solution using chloroform and the resultant solution was back extracted with 1% m/v L-cysteine. This solution was used for organic Hg determination. Inorganic Hg remaining in KBr solution was directly determined by chemical vapor generation electrothermal atomic absorption spectrometry. Mercury vapor generation from extracts was performed using 1 mol L - 1 HCl and 2.5% m/v NaBH 4 solutions and a batch chemical vapor generation system. Mercury vapor was collected on the gold gauze heated resistively at 80 °C and the atomization temperature was set at 650 °C. The selectivity of extraction was evaluated using liquid chromatography coupled to chemical vapor generation and determination by inductively coupled plasma mass spectrometry. The proposed method was applied for mercury analysis in shark, croaker and tuna fish tissues. Certified reference materials were used to check accuracy and the agreement was better than 95%. The characteristic mass was 60 pg and method limits of detection were 5, 1 and 1 ng g - 1 for organic, inorganic and total mercury, respectively. With the proposed method it was possible to analyze up to 2, 2 and 6 samples per hour for organic, inorganic and total Hg determination, respectively.

  2. Organic, inorganic and total mercury determination in fish by chemical vapor generation with collection on a gold gauze and electrothermal atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Duarte, Fabio Andrei; Bizzi, Cezar Augusto; Goldschmidt Antes, Fabiane; Dressler, Valderi Luiz [Departamento de Quimica, Universidade Federal de Santa Maria, 97105-900 Santa Maria, RS (Brazil); Flores, Erico Marlon de Moraes [Departamento de Quimica, Universidade Federal de Santa Maria, 97105-900 Santa Maria, RS (Brazil)], E-mail: flores@quimica.ufsm.br

    2009-06-15

    A method for organic, inorganic and total mercury determination in fish tissue has been developed using chemical vapor generation and collection of mercury vapor on a gold gauze inside a graphite tube and further atomization by electrothermal atomic absorption spectrometry. After drying and cryogenic grinding, potassium bromide and hydrochloric acid solution (1 mol L{sup - 1} KBr in 6 mol L{sup - 1} HCl) was added to the samples. After centrifugation, total mercury was determined in the supernatant. Organomercury compounds were selectively extracted from KBr solution using chloroform and the resultant solution was back extracted with 1% m/v L-cysteine. This solution was used for organic Hg determination. Inorganic Hg remaining in KBr solution was directly determined by chemical vapor generation electrothermal atomic absorption spectrometry. Mercury vapor generation from extracts was performed using 1 mol L{sup - 1} HCl and 2.5% m/v NaBH{sub 4} solutions and a batch chemical vapor generation system. Mercury vapor was collected on the gold gauze heated resistively at 80 deg. C and the atomization temperature was set at 650 deg. C. The selectivity of extraction was evaluated using liquid chromatography coupled to chemical vapor generation and determination by inductively coupled plasma mass spectrometry. The proposed method was applied for mercury analysis in shark, croaker and tuna fish tissues. Certified reference materials were used to check accuracy and the agreement was better than 95%. The characteristic mass was 60 pg and method limits of detection were 5, 1 and 1 ng g{sup - 1} for organic, inorganic and total mercury, respectively. With the proposed method it was possible to analyze up to 2, 2 and 6 samples per hour for organic, inorganic and total Hg determination, respectively.

  3. Bias-assisted atomic force microscope nanolithography on NbS2 thin films grown by chemical vapor deposition

    Science.gov (United States)

    Bark, Hunyoung; Kwon, Sanghyuk; Lee, Changgu

    2016-12-01

    Niobium disulfide, one of the metallic transition metal dichalcogenides, has a high potential as an electrode material for electronic devices made of 2D materials. Here, we investigated the bias-assisted atomic force microscope nanolithography of NbS2 thin films synthesized by chemical vapor deposition. We analyzed the lithographed pattern using Raman spectroscopy, transmission electron microscopy and friction force microscopy. These analyses showed that lines having various widths and thicknesses could be generated using the lithography technique by simply varying the scan speed and applied voltage. These analyses also revealed that the NbS2 film transformed from a layered crystalline structure into an amorphous structure upon being lithographed. By generating four line segments forming a square and measuring I/V curves inside and outside of the square, the electrical properties of the lithographed material were characterized. These analyses indicate that NbS2 became hydrogenated and an insulator upon being lithographed.

  4. Progress towards atomic vapor photonic microcells: Coherence and polarization relaxation measurements in coated and uncoated HC-PCF

    Science.gov (United States)

    Bradley, T. D.; McFerran, J. J.; Jouin, J.; Ilinova, E.; Thomas, P.; Benabid, F.

    2013-03-01

    We report a comparative study on dephasing mechanisms between inner core coated and uncoated sections of the same Kagome hypocycloid-shaped core hollow core photonic crystal fibers (HC-PCF) filled with rubidium vapor. The comparison is performed by measuring the atomic polarization relaxation and electromagnetically induced transparency (EIT) linewidth in Rb loaded polydimethylsiloxane (PDMS) inner wall coated and bare silica core Kagome HC-PCF. The measurements show a polarization relaxation time of 32μs in a PDMS coated Kagome HC-PCF and 24μs in uncoated Kagome HC-PCF. A minimum EIT linewidth of 6.2±0.8MHz is achieved in PDMS coated Kagome HC-PCF, and 8.3±0.9 MHz for the uncoated Kagome HC-PCF.

  5. Mercury determination in non- and biodegradable materials by cold vapor capacitively coupled plasma microtorch atomic emission spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Frentiu, Tiberiu, E-mail: ftibi@chem.ubbcluj.ro [Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University, Arany Janos 11, 400028 Cluj-Napoca (Romania); Mihaltan, Alin I., E-mail: alinblaj2005@yahoo.com [National Institute for Research and Development of Optoelectronics Bucharest - Research Institute for Analytical Instrumentation, Donath 67, 400293 Cluj-Napoca (Romania); Ponta, Michaela, E-mail: mponta@chem.ubbcluj.ro [Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University, Arany Janos 11, 400028 Cluj-Napoca (Romania); Darvasi, Eugen, E-mail: edarvasi@chem.ubbcluj.ro [Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University, Arany Janos 11, 400028 Cluj-Napoca (Romania); Frentiu, Maria, E-mail: frentiu.maria@yahoo.com [National Institute for Research and Development of Optoelectronics Bucharest - Research Institute for Analytical Instrumentation, Donath 67, 400293 Cluj-Napoca (Romania); Cordos, Emil, E-mail: emilcordos@gmail.com [National Institute for Research and Development of Optoelectronics Bucharest - Research Institute for Analytical Instrumentation, Donath 67, 400293 Cluj-Napoca (Romania)

    2011-10-15

    Highlights: {yields} Use of a miniaturized analytical system with microtorch plasma for Hg determination. {yields} Determination of Hg in non- and biodegradable materials using cold vapor generation. {yields} Figures of merit and advantages of the miniaturized system for Hg determination. - Abstract: A new analytical system consisting of a low power capacitively coupled plasma microtorch (20 W, 13.56 MHz, 150 ml min{sup -1} Ar) and a microspectrometer was investigated for the Hg determination in non- and biodegradable materials by cold-vapor generation, using SnCl{sub 2} reductant, and atomic emission spectrometry. The investigated miniaturized system was used for Hg determination in recyclable plastics from electronic equipments and biodegradable materials (shopping bags of 98% biodegradable polyethylene and corn starch) with the advantages of easy operation and low analysis costs. Samples were mineralized in HNO{sub 3}-H{sub 2}SO{sub 4} mixture in a high-pressure microwave system. The detection limits of 0.05 ng ml{sup -1} or 0.08 {mu}g g{sup -1} in solid sample were compared with those reported for other analytical systems. The method precision was 1.5-9.4% for Hg levels of 1.37-13.9 mg kg{sup -1}, while recovery in two polyethylene certified reference materials in the range 98.7 {+-} 4.5% (95% confidence level).

  6. Evaluation of vapor generation for the determination of nickel by inductively coupled plasma-atomic emission spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Marrero, Julieta [Comision Nacional de Energia Atomica, Unidad de Actividad Quimica, Centro Atomico Constituyentes, Av. Gral. Paz 1499, 1650-San Martin, Pcia. de Buenos Aires (Argentina); Smichowski, Patricia [Comision Nacional de Energia Atomica, Unidad Proyectos Especiales de Suministros Nucleares, Av. Libertador 8250, 1429-Buenos Aires (Argentina)

    2002-09-01

    Volatile species of Ni were generated by merging acidified aqueous samples and sodium tetrahydroborate(III) in a continuous flow system. The gaseous analyte was subsequently introduced via a stream of Ar carrier into the inlet tube of the plasma torch. Inductively coupled plasma atomic emission spectrometry (ICP-AES) was used for detection. The operating conditions (chemical and physical parameters) and the concentrations of different acids were evaluated for the efficient generation of Ni vapor. The detection limit (3 {sigma}{sub blank}) was 1.8 ng mL{sup -1}. The precision (RSD) of the determination was 4.2% at a level of 500 ng mL{sup -1} and 7.3% for 20 ng mL{sup -1} (n=10). The efficiency of the generation process was estimated to be 51%. The possible interfering effect of transition metals (Cd, Co, Cu, Cr, Fe, Mn, Zn), hydride forming elements (As, Ge, Pb, Sb, Se, Sn, Te), and Hg on Ni signal was examined. This study has demonstrated that Ni vapor generation is markedly free of interferences. (orig.)

  7. Model calculation of the characteristic mass for convective and diffusive vapor transport in graphite furnace atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Bencs, László, E-mail: bencs.laszlo@wigner.mta.hu [Institute for Solid State Physics and Optics, Wigner Research Centre for Physics, Hungarian Academy of Sciences, P.O. Box 49, H-1525 Budapest (Hungary); Laczai, Nikoletta [Institute for Solid State Physics and Optics, Wigner Research Centre for Physics, Hungarian Academy of Sciences, P.O. Box 49, H-1525 Budapest (Hungary); Ajtony, Zsolt [Institute of Food Science, University of West Hungary, H-9200 Mosonmagyaróvár, Lucsony utca 15–17 (Hungary)

    2015-07-01

    A combination of former convective–diffusive vapor-transport models is described to extend the calculation scheme for sensitivity (characteristic mass — m{sub 0}) in graphite furnace atomic absorption spectrometry (GFAAS). This approach encompasses the influence of forced convection of the internal furnace gas (mini-flow) combined with concentration diffusion of the analyte atoms on the residence time in a spatially isothermal furnace, i.e., the standard design of the transversely heated graphite atomizer (THGA). A couple of relationships for the diffusional and convectional residence times were studied and compared, including in factors accounting for the effects of the sample/platform dimension and the dosing hole. These model approaches were subsequently applied for the particular cases of Ag, As, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Mo, Ni, Pb, Sb, Se, Sn, V and Zn analytes. For the verification of the accuracy of the calculations, the experimental m{sub 0} values were determined with the application of a standard THGA furnace, operating either under stopped, or mini-flow (50 cm{sup 3} min{sup −1}) of the internal sheath gas during atomization. The theoretical and experimental ratios of m{sub 0}(mini-flow)-to-m{sub 0}(stop-flow) were closely similar for each study analyte. Likewise, the calculated m{sub 0} data gave a fairly good agreement with the corresponding experimental m{sub 0} values for stopped and mini-flow conditions, i.e., it ranged between 0.62 and 1.8 with an average of 1.05 ± 0.27. This indicates the usability of the current model calculations for checking the operation of a given GFAAS instrument and the applied methodology. - Highlights: • A calculation scheme for convective–diffusive vapor loss in GFAAS is described. • Residence time (τ) formulas were compared for sensitivity (m{sub 0}) in a THGA furnace. • Effects of the sample/platform dimension and dosing hole on τ were assessed. • Theoretical m{sub 0} of 18 analytes were

  8. Determination of cadmium in rice and water by tungsten coil electrothermal vaporization-atomic fluorescence spectrometry and tungsten coil electrothermal atomic absorption spectrometry after cloud point extraction

    Energy Technology Data Exchange (ETDEWEB)

    Wen Xiaodong [College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu, Sichuan 610064 (China); Wu Peng [Analytical and Testing Center, Sichuan University, 29 Wangjiang Road, Chengdu, Sichuan 610064 (China); Chen Li [College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu, Sichuan 610064 (China); Hou Xiandeng, E-mail: houxd@scu.edu.cn [College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu, Sichuan 610064 (China); Analytical and Testing Center, Sichuan University, 29 Wangjiang Road, Chengdu, Sichuan 610064 (China)

    2009-09-14

    In this work, the microsampling nature of tungsten coil electrothermal vaporization Ar/H{sub 2} flame atomic fluorescence spectrometry (W-coil ETV-AFS) as well as tungsten coil electrothermal atomic absorption spectrometry (W-coil ET-AAS) was used with cloud point extraction (CPE) for the ultrasensitive determination of cadmium in rice and water samples. When the temperature of the extraction system is higher than the cloud point temperature of the selected surfactant Triton X-114, the complex of cadmium with dithizone can be quantitatively extracted into the surfactant-rich phase and subsequently separated from the bulk aqueous phase by centrifugation. The main factors affecting the CPE, such as concentration of Triton X-114 and dithizone, pH, equilibration temperature and incubation time, were optimized for the best extract efficiency. Under the optimal conditions, the limits of detection for cadmium by W-coil ETV-AFS and W-coil ET-AAS were 0.01 and 0.03 {mu}g L{sup -1}, with sensitivity enhancement factors of 152 and 93, respectively. The proposed methods were applied to the determination of cadmium in certified reference rice and water samples with analytical results in good agreement with certified values.

  9. Testing the distance-dependence of the van der Waals interaction between an atom and a surface through spectroscopy in a vapor nanocell

    CERN Document Server

    Laliotis, A; Todorov, P; Hamdi, I; Dutier, G; Yarovitski, A; Saltiel, S; Gorza, M P; Fichet, M; Ducloy, M; Bloch, D; Laliotis, Athanasdios; Maurin, Isabelle; Todorov, Petko; Hamdi, Ismah\\`{e}ne; Dutier, Gabriel; Yarovitski, Alexander; Saltiel, Solomon; Gorza, Marie-Pascale; Fichet, Mich\\`{e}le; Ducloy, Martial; Bloch, Daniel

    2007-01-01

    This paper presents our current measurements in a vapor nanocell aiming at a test of the distance-dependence of the atom-surface interaction, when simple asymptotic descriptions may turn to be not valid. A state-of-the-art of atom-surface interaction measurements is provided as an introduction, along with the comparison with the theory of the van der Waals (or Casimir-Polder) interaction; it is followed by a presentation of the most salient features of nanocell spectroscopy

  10. Sub-natural $N$-type Resonance in Cesium Atomic Vapor: splitting in magnetic fields

    CERN Document Server

    Slavov, D; Sarkisyan, D; Mirzoyan, R; Krasteva, A; Wilson-Gordon, A D; Cartaleva, S

    2013-01-01

    The sub-natural-width $N$-type resonance in {\\Lambda}-system, on the $D_2$ line of Cs atoms is studied for the first time in the presence of a buffer gas (neon) and the radiations of two continuous narrow band diode lasers. $L$ = 1 cm long cell is used to investigate $N$-type process. The $N$-type resonance in a magnetic field for $^{133}$Cs atoms is shown to split into seven or eight components, depending on the magnetic field and laser radiation directions. The results obtained indicate that levels $F_g$ = 3, 4 are initial and final in the N resonance formation. The experimental results with magnetic field agree well with the theoretical curves.

  11. Photonic properties of one-dimensionally-ordered cold atomic vapors under conditions of electromagnetically induced transparency

    CERN Document Server

    Schilke, Alexander; Guerin, William

    2012-01-01

    We experimentally study the photonic properties of a cold-atom sample trapped in a one-dimensional optical lattice under the conditions of electromagnetically induced transparency. We show that such a medium has two photonic band gaps. One of them is in the transparency window and gives rise to a Bragg mirror, which is spectrally very narrow and dynamically tunable. We discuss the advantages and the limitations of this system. As an illustration of a possible application we demonstrate a two-port all-optical switch.

  12. Methylmercury determination using a hyphenated high performance liquid chromatography ultraviolet cold vapor multipath atomic absorption spectrometry system

    Science.gov (United States)

    Campos, Reinaldo C.; Gonçalves, Rodrigo A.; Brandão, Geisamanda P.; Azevedo, Marlo S.; Oliveira, Fabiana; Wasserman, Julio

    2009-06-01

    The present work investigates the use of a multipath cell atomic absorption mercury detector for mercury speciation analysis in a hyphenated high performance liquid chromatography assembly. The multipath absorption cell multiplies the optical path while energy losses are compensated by a very intense primary source. Zeeman-effect background correction compensates for non-specific absorption. For the separation step, the mobile phase consisted in a 0.010% m/v mercaptoethanol solution in 5% methanol (pH = 5), a C 18 column was used as stationary phase, and post column treatment was performed by UV irradiation (60 °C, 13 W). The eluate was then merged with 3 mol L - 1 HCl, reduction was performed by a NaBH 4 solution, and the Hg vapor formed was separated at the gas-liquid separator and carried through a desiccant membrane to the detector. The detector was easily attached to the system, since an external gas flow to the gas-liquid separator was provided. A multivariate approach was used to optimize the procedure and peak area was used for measurement. Instrumental limits of detection of 0.05 µg L - 1 were obtained for ionic (Hg 2+) and HgCH 3+, for an injection volume of 200 µL. The multipath atomic absorption spectrometer proved to be a competitive mercury detector in hyphenated systems in relation to the most commonly used atomic fluorescence and inductively coupled plasma mass spectrometric detectors. Preliminary application studies were performed for the determination of methyl mercury in sediments.

  13. Methylmercury determination using a hyphenated high performance liquid chromatography ultraviolet cold vapor multipath atomic absorption spectrometry system

    Energy Technology Data Exchange (ETDEWEB)

    Campos, Reinaldo C. [Department of Chemistry, Pontifical Catholic University of Rio de Janeiro, Rua Marques de S Vicente 225, 22453-900 Rio de Janeiro (Brazil)], E-mail: rccampos@puc-rio.br; Goncalves, Rodrigo A.; Brandao, Geisamanda P.; Azevedo, Marlo S. [Department of Chemistry, Pontifical Catholic University of Rio de Janeiro, Rua Marques de S Vicente 225, 22453-900 Rio de Janeiro (Brazil); Oliveira, Fabiana; Wasserman, Julio [Institut of Geosciences, Fluminense Federal University, Av. Gal. Milton Tavares de Souza, s/n, 24.210-340, Niteroi, Rio de Janeiro (Brazil)

    2009-06-15

    The present work investigates the use of a multipath cell atomic absorption mercury detector for mercury speciation analysis in a hyphenated high performance liquid chromatography assembly. The multipath absorption cell multiplies the optical path while energy losses are compensated by a very intense primary source. Zeeman-effect background correction compensates for non-specific absorption. For the separation step, the mobile phase consisted in a 0.010% m/v mercaptoethanol solution in 5% methanol (pH = 5), a C{sub 18} column was used as stationary phase, and post column treatment was performed by UV irradiation (60 deg. C, 13 W). The eluate was then merged with 3 mol L{sup -1} HCl, reduction was performed by a NaBH{sub 4} solution, and the Hg vapor formed was separated at the gas-liquid separator and carried through a desiccant membrane to the detector. The detector was easily attached to the system, since an external gas flow to the gas-liquid separator was provided. A multivariate approach was used to optimize the procedure and peak area was used for measurement. Instrumental limits of detection of 0.05 {mu}g L{sup -1} were obtained for ionic (Hg{sup 2+}) and HgCH{sub 3}{sup +}, for an injection volume of 200 {mu}L. The multipath atomic absorption spectrometer proved to be a competitive mercury detector in hyphenated systems in relation to the most commonly used atomic fluorescence and inductively coupled plasma mass spectrometric detectors. Preliminary application studies were performed for the determination of methyl mercury in sedi0011men.

  14. First-principles study on saturated adsorption of alkali metal atoms on silicene%硅烯饱和吸附碱金属原子的第一性原理研究∗

    Institute of Scientific and Technical Information of China (English)

    黄艳平; 袁健美; 郭刚; 毛宇亮

    2015-01-01

    基于密度泛函理论的第一性原理计算,研究了硅烯饱和吸附碱金属元素原子的稳定性、微观几何结构和电子性质,并与纯硅烯及其饱和氢化结构进行了对比分析.研究发现复合物SiX (X =Li, Na, K, Rb)的形成能都是负的,相对于纯硅烯来说可以稳定存在. Bader电荷分析表明,电荷从碱金属原子转移至硅原子.从成键方式来看,硅烯与氢原子形成共价键,而与碱金属原子之间形成的键主要是离子性成键,但还存在部分共价关联成分.能带计算表明,锂原子饱和吸附在硅烯形成的复合物SiLi是直接带隙的半导体,带隙大小为0.34 eV.其他碱金属饱和吸附在硅烯上形成的复合物都表现为金属性.%Based on density functional first-principles calculations, we study the stability, micro-geometry, and electronic properties of alkali metal atoms adsorbed on silicene, and perform the comparison between pure and hydrogen-saturated silicenes. We found that all the formation energies of SiX (X = Li, Na, K and Rb) are negative, indicating that the relative structural stability of these new compounds is higher than silicene. Bader charge analysis shows that electric charge is transferred from Si atoms to H atoms in SiH compound, but in SiX the direction of charge transfer is opposite, i.e., the charge is transferred from alkali metal atoms to Si atoms. From the viewpoint of chemical bonding, it can be regarded that valence bond is formed between Si atoms and H atoms, and the bonds between Si and alkali metal atoms are mainly ionic, but there exists covalent contribution. From the band structure calculations, it is also found that the new type compound SiLi is a semiconductor with a direct band gap of 0.34 eV; however, all the other compounds of SiX(X =Na, K and Rb) exhibit metallic property.

  15. Famed Bulgarian physicists. I. St. Petroff's Goettingen research of the photostimulated interconversions of color centers in alkali halides: the discovery of the photostimulated aggregation

    CERN Document Server

    Georgiev, Mladen

    2008-01-01

    This essay tells briefly of the life and work of one of the most successful scientists originating from a Balkan settlement whose name and popularity have greatly exceeded its realm. The word is of a discovery during WWII of the photostimulated aggregation of the F centers (else alkali atoms) dissolved from the vapor into an alkali halide crystal. Using optical absorption techniques while a grantee of Humboldt's Foundation in Goettingen, Germany between 1943-1944, he found new absorption bands pertaining to small-size F center aggregates and followed their interconversions. A primary photochemical solid state reaction was evidenced for the first time leading to nanoscale products.

  16. Vapor-Phase Atomic Layer Deposition of Co9S8 and Its Application for Supercapacitors.

    Science.gov (United States)

    Li, Hao; Gao, Yuanhong; Shao, Youdong; Su, Yantao; Wang, Xinwei

    2015-10-14

    Atomic layer deposition (ALD) of cobalt sulfide (Co9S8) is reported. The deposition process uses bis(N,N'-diisopropylacetamidinato)cobalt(II) and H2S as the reactants and is able to produce high-quality Co9S8 films with an ideal layer-by-layer ALD growth behavior. The Co9S8 films can also be conformally deposited into deep narrow trenches with aspect ratio of 10:1, which demonstrates the high promise of this ALD process for conformally coating Co9S8 on high-aspect-ratio 3D nanostructures. As Co9S8 is a highly promising electrochemical active material for energy devices, we further explore its electrochemical performance by depositing Co9S8 on porous nickel foams for supercapacitor electrodes. Benefited from the merits of ALD for making high-quality uniform thin films, the ALD-prepared electrodes exhibit remarkable electrochemical performance, with high specific capacitance, great rate performance, and long-term cyclibility, which highlights the broad and promising applications of this ALD process for energy-related electrochemical devices, as well as for fabricating complex 3D nanodevices in general.

  17. UV-photochemical vapor generation of selenium for atomic absorption spectrometry: Optimization and 75Se radiotracer efficiency study

    Science.gov (United States)

    Rybínová, Marcela; Musil, Stanislav; Červený, Václav; Vobecký, Miloslav; Rychlovský, Petr

    2016-09-01

    Volatile selenium compounds were generated UV-photochemically in the continuous flow mode using four UV-photoreactors differing in the material of the reaction coil; Teflon tubing and quartz tubes with various inner diameters and wall thicknesses were tested. Atomic absorption spectrometry with an externally heated quartz furnace atomizer was employed as the detector. The relevant experimental generation parameters were optimized and the basic analytical characteristics were determined. Using formic acid as the photochemical agent, limits of detection achieved for selenium were in the range 46-102 ng L- 1 in dependence on the type of UV-photoreactor employed. When nitric acid was also added to the photochemical agent, the limits of detection were reduced to 27-44 ng L- 1. The repeatability did not exceed 2.4% (5 μg L- 1 Se(IV), n = 10). Experiments with 75Se radiotracer have been performed for the first time to quantify the efficiency of UV-photochemical vapor generation (UV-PVG) of selenium. The highest efficiency of 67 ± 1% was obtained for a UV-photoreactor containing a quartz reaction coil (2.0 mm i.d., 4.0 mm o.d.). The generation efficiency of 61 ± 1% was obtained for a Teflon reaction coil (1.0 mm i.d., 1.4 mm o.d.). Mapping of the radiotracer distribution in the individual parts of the apparatus did not reveal substantial transport losses of the analyte in the UV-PVG system.

  18. Selection of non-adsorbing alkali components

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S.H.D.; Natesan, K.; Swift, W.M.

    1992-11-01

    This project consists of three phases of laboratory experimental study. In phase I (screening), eight candidate materials, 304SS (serves as a base material for comparison), Hastelloy C-276, Hastelloy X, Haynes No. 188, Allonized 304SS, Pt-coated 304SS, and ceramic-coated 304SS, will be subjected to atmospheric TGA study under the simulated PFBC (oxidizing) environment with and without alkali vapor doping. Each candidate material will be evaluated for its resistance toward alkali-vapor capture. In addition, a post-test metallographic characterization of the sample will be performed to obtain a better understanding of the alkali capture mechanism and material behavior. The material(s) with little or no alkali-vapor adsorption will be selected as the promising material(s) for the Phase II study. In Phase II, the promising material(s) will be further tested in the TGA under elevated pressure to simulate the PFBC environment (in terms of temperature, pressure, and gas composition). The effect of pressure on the extent of alkali-vapor adsorption will be evaluated, and the test samples will be metallographically characterized. The most promising candidate material(s) will be identified and recommended for further tesfing in the actual PFBC environment. In Phase III, four materials will be selected from the eight candidate materials screened in the PFBC environment and will be evaluated for their alkali-vapor capture by atmospheric TGA under the coal gasification fuel gas (reducing) environment. The tested samples will also be metallographically characterized. The most promising material(s) will be identified and recommended for further testing in the actual coal gasification environment.

  19. Selection of non-adsorbing alkali components

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S.H.D.; Natesan, K.; Swift, W.M.

    1992-01-01

    This project consists of three phases of laboratory experimental study. In phase I (screening), eight candidate materials, 304SS (serves as a base material for comparison), Hastelloy C-276, Hastelloy X, Haynes No. 188, Allonized 304SS, Pt-coated 304SS, and ceramic-coated 304SS, will be subjected to atmospheric TGA study under the simulated PFBC (oxidizing) environment with and without alkali vapor doping. Each candidate material will be evaluated for its resistance toward alkali-vapor capture. In addition, a post-test metallographic characterization of the sample will be performed to obtain a better understanding of the alkali capture mechanism and material behavior. The material(s) with little or no alkali-vapor adsorption will be selected as the promising material(s) for the Phase II study. In Phase II, the promising material(s) will be further tested in the TGA under elevated pressure to simulate the PFBC environment (in terms of temperature, pressure, and gas composition). The effect of pressure on the extent of alkali-vapor adsorption will be evaluated, and the test samples will be metallographically characterized. The most promising candidate material(s) will be identified and recommended for further tesfing in the actual PFBC environment. In Phase III, four materials will be selected from the eight candidate materials screened in the PFBC environment and will be evaluated for their alkali-vapor capture by atmospheric TGA under the coal gasification fuel gas (reducing) environment. The tested samples will also be metallographically characterized. The most promising material(s) will be identified and recommended for further testing in the actual coal gasification environment.

  20. Immersed single-drop microextraction-electrothermal vaporization atomic absorption spectroscopy for the trace determination of mercury in water samples.

    Science.gov (United States)

    Bagheri, Habib; Naderi, Mehrnoush

    2009-06-15

    A new method based on single-drop microextraction (SDME) combined with electrothermal vaporization atomic absorption spectroscopy (ETV-AAS) was developed for the trace determination of mercury in water samples. A microdrop of m-xylene was applied as the extraction solvent. After extraction, the microdrop was introduced, directly, into a graphite furnace of AAS. Some important extraction parameters such as type of solvent, volume of solvent, sample stirring, ionic strength, sample pH, chelating agent concentration, sample temperature, and extraction time were investigated and optimized. The highest possible microdrop volume of 10 microL, a sampling temperature of 27 degrees C, and use of m-xylene containing dithizone, as complexing agent, are major parameters led to achieve a high enrichment factor of 970. Under the optimized conditions, the detection limit of the method was 0.01 microg L(-1) and the relative standard deviation was 6.1% (n=7). The proposed method has been successfully applied to the determination of Hg in two river water samples. The effects of interfering species such as Pt, Pd, Cu, Au, and Bi, having the tendency to form complexes with dithizone, at two concentration levels of 100 and 1000 microg L(-1) were also studied.

  1. Mercury determination in non- and biodegradable materials by cold vapor capacitively coupled plasma microtorch atomic emission spectrometry.

    Science.gov (United States)

    Frentiu, Tiberiu; Mihaltan, Alin I; Ponta, Michaela; Darvasi, Eugen; Frentiu, Maria; Cordos, Emil

    2011-10-15

    A new analytical system consisting of a low power capacitively coupled plasma microtorch (20 W, 13.56 MHz, 150 ml min(-1) Ar) and a microspectrometer was investigated for the Hg determination in non- and biodegradable materials by cold-vapor generation, using SnCl(2) reductant, and atomic emission spectrometry. The investigated miniaturized system was used for Hg determination in recyclable plastics from electronic equipments and biodegradable materials (shopping bags of 98% biodegradable polyethylene and corn starch) with the advantages of easy operation and low analysis costs. Samples were mineralized in HNO(3)-H(2)SO(4) mixture in a high-pressure microwave system. The detection limits of 0.05 ng ml(-1) or 0.08 μg g(-1) in solid sample were compared with those reported for other analytical systems. The method precision was 1.5-9.4% for Hg levels of 1.37-13.9 mg kg(-1), while recovery in two polyethylene certified reference materials in the range 98.7 ± 4.5% (95% confidence level).

  2. Atomic-layer chemical-vapor-deposition of TiN thin films on Si(100) and Si(111)

    CERN Document Server

    Kim, Y S; Kim, Y D; Kim, W M

    2000-01-01

    An atomic-layer chemical vapor deposition (AL-CVD) system was used to deposit TiN thin films on Si(100) and Si(111) substrates by cyclic exposures of TiCl sub 4 and NH sub 3. The growth rate was measured by using the number of deposition cycles, and the physical properties were compared with those of TiN films grown by using conventional deposition methods. To investigate the growth mechanism, we suggest a growth model for TiN n order to calculate the growth rate per cycle with a Cerius program. The results of the calculation with the model were compared with the experimental values for the TiN film deposited using the AL-CVD method. The stoichiometry of the TiN film was examined by using Auger electron spectroscopy, and the chlorine and the oxygen impurities were examined. The x-ray diffraction and the transmission electron microscopy results for the TiN film exhibited a strong (200) peak and a randomly oriented columnar microstructure. The electrical resistivity was found to decrease with increasing deposit...

  3. Structure and electronic properties of alkali-C60 nanoclusters.

    Science.gov (United States)

    Rabilloud, Franck

    2010-07-08

    I investigated the structural and electronic properties of both Na(n)C(60) and Li(n)C(60) (n alkali atoms over the C(60) surface is analyzed. The hypotheses for either an homogeneous coating of the C(60) surface by the alkali atoms or the growth of an alkali droplet not wetting the fullerene surface are discussed. Lithium atoms are found to coat homogeneously the fullerene on the C(60) surface via pentagonal sites, contrary to sodium atoms, which prefer to form 4-atom islands on the surface. The charge transfer, the energetics, and the dipole moments are discussed in relation with available results. The adsorption of alkali atoms on the C(60) surface considerably enhances the capacity of C(60) to accept electrons. The arrangement of lithium atoms seems more favorable for the hydrogen storage than that of sodium atoms.

  4. Improving Sensitivity and Bandwidth of an Atomic Magnetometer using Quantum Non-Demolition Measurement

    Science.gov (United States)

    Shah, Vishal; Vasilakis, Georgios; Romalis, Michael

    2009-05-01

    The fundamental sensitivity of an atomic magnetometer is limited by spin projection noise. In the case of uniform spin relaxation, it is well understood that it is not possible to improve the sensitivity using spin squeezing induced by quantum non-demolition (QND) measurement for measurement time scales longer than spin relaxation time [1, 2]. It is however possible to increase the bandwidth of the magnetometer using QND measurement. Here we experimentally demonstrate, in excellent agreement with the theory, an improvement in the bandwidth of our scalar alkali vapor atomic magnetometer using continuous QND measurement. We also investigate the possibility of improving sensitivity of our magnetometer in the special case in which the spin relaxation is time dependent. The case of time dependent spin relaxation naturally arises in high polarization regime in an alkali-alkali spin-exchange relaxation dominated atomic sample. [1] S. F. Huelga, Phys. Rev. Lett. 79, 3865 -- 3868, 1997. [2] M. Auzinsh, Phys. Rev. Lett. 93, 173002, 2004.

  5. Trace mercury determination in drinking and natural water after preconcentration and separation by DLLME-SFO method coupled with cold vapor atomic absorption spectrometry

    OpenAIRE

    Abdollahi Atousa; Amirkavehei Mooud; Gheisari Mohammad Mehdi; Tadayon Fariba

    2014-01-01

    A novel dispersive liquid–liquid microextraction based on solidification of floating organic drop (DLLME-SFO) for simultaneous separation/preconcentration of ultra trace amounts of mercury was used. A method based on amalgamation was used for collection of gaseous mercury on gold coated sand (Gold trap). The concentration of mercury was determined by cold vapor atomic absorption spectrometry (CV-AAS). The DLLME-SFO behavior of mercury by using dithizone as complexing agent was systematically ...

  6. Environmental site description for a Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) production plant at the Paducah Gaseous Diffusion Plant site

    Energy Technology Data Exchange (ETDEWEB)

    Marmer, G.J.; Dunn, C.P.; Moeller, K.L.; Pfingston, J.M.; Policastro, A.J.; Yuen, C.R.; Cleland, J.H. (ed.)

    1991-09-01

    Uranium enrichment in the United States has utilized a diffusion process to preferentially enrich the U-235 isotope in the uranium product. The U-AVLIS process is based on electrostatic extraction of photoionized U-235 atoms from an atomic vapor stream created by electron-beam vaporization of uranium metal alloy. The U-235 atoms are ionized when precisely tuned laser light -- of appropriate power, spectral, and temporal characteristics -- illuminates the uranium vapor and selectively photoionizes the U-235 isotope. A programmatic document for use in screening DOE site to locate a U-AVLIS production plant was developed and implemented in two parts. The first part consisted of a series of screening analyses, based on exclusionary and other criteria, that identified a reasonable number of candidate sites. These sites were subjected to a more rigorous and detailed comparative analysis for the purpose of developing a short list of reasonable alternative sites for later environmental examination. This environmental site description (ESD) provides a detailed description of the PGDP site and vicinity suitable for use in an environmental impact statement (EIS). The report is based on existing literature, data collected at the site, and information collected by Argonne National Laboratory (ANL) staff during a site visit. 65 refs., 15 tabs.

  7. Study of bisphosphonates by matrix-assisted laser desorption/ionization mass spectrometry--influence of alkali atoms on fragmentation patterns.

    Science.gov (United States)

    Guénin, Erwann; Lecouvey, Marc; Hardouin, Julie

    2009-05-01

    1-hydroxymethylene-1,1-bisphosphonic acids (or bisphosphonates) are compounds that have interesting pharmacological applications. However, few mass spectrometric investigations have been carried out to determine their fragmentation patterns. Herein, we evaluated different matrices for the study by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOFMS) of the formation and fragmentation of the protonated, the cationized (MNa+ and MK+) and the deprotonated bisphosphonates. Some in-source fragmentations were observed both in positive and in negative ion modes. The fragmentation patterns obtained in post-source decay mode are also discussed. In contrast to previous electrospray ionization/multi-stage mass spectrometry (ESI-MSn) studies, some new fragmentation pathways were deduced and the effects of alkali ions on the fragmentation patterns were shown. The results summarized here completed the data previously recorded by ESI-MSn and could be used for the characterization of bisphosphonates as alkali complexes in biological mixtures.

  8. In-situ measurements of low-level mercury vapor exposure from dental amalgam with zeeman atomic absorption spectroscopy.

    Science.gov (United States)

    Halbach, Stefan; Welzl, Gerhard

    2004-01-01

    Alongside food, emissions from amalgam fillings are an essential contribution to man's mercury burden. Previous methods for the determination of intraoral mercury vapor (Hg degrees ) release used principally some form of preconcentration of Hg on gold (film or wool), allowing relatively few measurements with unknown precision and sensitivity at selected times. Recently available computer-controlled Hg detectors operating on Zeeman atomic absorption spectroscopy (ZAAS) facilitate the direct real-time measurement of Hg degrees concentrations. It was the aim to adapt this method for a comparative investigation of emission processes from fillings in situ and from amalgam specimens in vitro. In addition to the ZAAS instrument, the apparatus consisted of a pump, magnetic valves, an electronic flow controller and a handle with a disposable mouth piece for aspiration of oral air. A programmable timer integrated the computer-controlled instrument operation and the data collection into a standard sampling protocol. A fast exponential decay of the emission was found after stimulation of amalgam specimens and of fillings in situ (halftimes 8.6 and 10.7 min). Precision was evaluated by a series of measurements on a single patient which indicated a consistently low coefficient of variation between 18% and 25%. After insertion of a few new fillings, sensitivity was high enough to detect a significant increase in emission against the background emission from the majority of old fillings. Zeeman-AAS in connection with a semi-automated sampling protocol and data storage provides precise in-situ measurements of Hg degrees emission from dental amalgam with real-time resolution. This facilitates the detailed exploration of the Hg degrees release kinetics and the applicability to large-scale studies.

  9. Nature of the Charge Localized Between Alkali Adatoms and Metal Substrates

    OpenAIRE

    Wertheim, G. K.; Riffe, D. Mark; Citrin, P. H.

    1994-01-01

    Two previously unappreciated features in photoemission spectra from alkali atoms adsorbed on W(110), namely, the sign of the alkali-induced surface-atom core-level shift of the substrate at low coverage and the very large alkali shallow core-hole lifetime width at all coverages, show that the alkali-substrate interaction is not well described by a transfer of alkali charge. Instead, both features point to the formation of a charge cloud between the alkali adatom and substrate that is d...

  10. AMTEC vapor-vapor series connected cells

    Science.gov (United States)

    Underwood, Mark L.; Williams, Roger M.; Ryan, Margaret A.; Nakamura, Barbara J.; Oconnor, Dennis E.

    1995-08-01

    An alkali metal thermoelectric converter (AMTEC) having a plurality of cells structurally connected in series to form a septum dividing a plenum into two chambers, and electrically connected in series, is provided with porous metal anodes and porous metal cathodes in the cells. The cells may be planar or annular, and in either case a metal alkali vapor at a high temperature is provided to the plenum through one chamber on one side of the wall and returned to a vapor boiler after condensation at a chamber on the other side of the wall in the plenum. If the cells are annular, a heating core may be placed along the axis of the stacked cells. This arrangement of series-connected cells allows efficient generation of power at high voltage and low current.

  11. Atoms

    Institute of Scientific and Technical Information of China (English)

    刘洪毓

    2007-01-01

    Atoms(原子)are all around us.They are something like the bricks (砖块)of which everything is made. The size of an atom is very,very small.In just one grain of salt are held millions of atoms. Atoms are very important.The way one object acts depends on what

  12. Slurry sampling fluorination assisted electrothermal vaporization-inductively coupled plasma-atomic emission spectrometry for the direct determination of metal impurities in aluminium oxide ceramic powders.

    Science.gov (United States)

    Peng, T; Chang, G; Wang, L; Jiang, Z; Hu, B

    2001-03-01

    A new analytical procedure for the direct determination of metal impurities (Cr, Cu, Fe and V) in aluminium oxide ceramic powders by slurry sampling fluorination assisted electrothermal vaporization-inductively coupled plasma-atomic emission spectrometry (ETV-ICP-AES) is reported. A polytetrafluoroethylene (PTFE) emulsion was used as a fluorinating reagent to promote the vaporization of impurity elements in aluminium oxide ceramic powders from the graphite tube. A vaporization stage with a long ramp time and a short hold time provided the possibility of temporal analyte-matrix separation. The experimental results indicated that a 10 microL 1% m/v slurry of aluminium oxide could be destroyed and vaporized completely with 600 micrograms PTFE under the selected conditions. Two aluminium oxide ceramic powder samples were used without any additional pretreatment. Analytical results obtained by using standard addition method with aqueous standard solution were checked by comparison of the results with pneumatic nebulization (PN)-ICP-AES based on the wet-chemical decomposition and analyte-matrix separation. The limits of detection (LODs) between 0.30 microgram g-1 (Fe) and 0.08 microgram g-1 (Cu) were achieved, and, the repeatability of measurements was mainly better than 10%.

  13. Low-Temperature Process for Atomic Layer Chemical Vapor Deposition of an Al2O3 Passivation Layer for Organic Photovoltaic Cells.

    Science.gov (United States)

    Kim, Hoonbae; Lee, Jihye; Sohn, Sunyoung; Jung, Donggeun

    2016-05-01

    Flexible organic photovoltaic (OPV) cells have drawn extensive attention due to their light weight, cost efficiency, portability, and so on. However, OPV cells degrade quickly due to organic damage by water vapor or oxygen penetration when the devices are driven in the atmosphere without a passivation layer. In order to prevent damage due to water vapor or oxygen permeation into the devices, passivation layers have been introduced through methods such as sputtering, plasma enhanced chemical vapor deposition, and atomic layer chemical vapor deposition (ALCVD). In this work, the structural and chemical properties of Al2O3 films, deposited via ALCVD at relatively low temperatures of 109 degrees C, 200 degrees C, and 300 degrees C, are analyzed. In our experiment, trimethylaluminum (TMA) and H2O were used as precursors for Al2O3 film deposition via ALCVD. All of the Al2O3 films showed very smooth, featureless surfaces without notable defects. However, we found that the plastic flexible substrate of an OPV device passivated with 300 degrees C deposition temperature was partially bended and melted, indicating that passivation layers for OPV cells on plastic flexible substrates need to be formed at temperatures lower than 300 degrees C. The OPV cells on plastic flexible substrates were passivated by the Al2O3 film deposited at the temperature of 109 degrees C. Thereafter, the photovoltaic properties of passivated OPV cells were investigated as a function of exposure time under the atmosphere.

  14. Milk-alkali syndrome

    Science.gov (United States)

    ... this page: //medlineplus.gov/ency/article/000332.htm Milk-alkali syndrome To use the sharing features on this page, please enable JavaScript. Milk-alkali syndrome is a condition in which there ...

  15. The role of the alkali and chalcogen atoms on the stability of the layered chalcogenide \\mathbf{{{A}_{2}}{{M}^{II}}M_{3}^{\\,IV}{{Q}_{8}}} (A  =  alkali-metal M  =  metal-cations Q  =  chalcogen) compounds: a density functional theory investigation within van der Waals corrections

    Science.gov (United States)

    Besse, Rafael; Da Silva, Juarez L. F.

    2017-01-01

    There is a great interest to design two-dimensional (2D) chalcogenide materials, however, our atomistic understanding of the major physical parameters that drive the formation of 2D or three-dimensional (3D) chalcogenides is far from satisfactory, in particular, for complex quaternary systems. To address this problem, we selected a set of quaternary 2D and 3D chalcogenide compounds, namely, {{\\text{A}}2}\\text{ZnS}{{\\text{n}}3}{{\\text{Q}}8} (A  =  Li, K, Cs; Q  =  S, Se, Te), which were investigated by density functional theory calculations within van der Waals (vdW) corrections. Employing experimental crystal structures and well designed crystal modifications, we found that the average atomic radius of the alkali-metal, A, and chalcogen, Q, species play a crucial role in the stability of the 2D structures. For example, the 2D structures are energetically favored for smaller (R1.8~{\\mathring{\\text{A}}}) average atomic radius, while 3D structures are favored at intermediate average atomic radius. Those results are explained in terms of strain minimization and Coulomb repulsion of the anionic species in the structure framework. Furthermore, the equilibrium lattice parameters are in excellent agreement with experimental results. Thus, the present insights can help in the design of stable quartenary 2D chalcogenide compounds.

  16. Atomic Beam Merging and Suppression of Alkali Contaminants in Multi Body High Power Targets: Design and Test of Target and Ion Source Prototypes at ISOLDE

    CERN Document Server

    Bouquerel, Elian J A; Lettry, J; Stora, T

    2009-01-01

    The next generation of high power ISOL-facilities will deliver intense and pure radioactive ion beams. Two key issues of developments mandatory for the forthcoming generation of ISOL target-ion source units are assessed and demonstrated in this thesis. The design and production of target and ion-source prototypes is described and dedicated measurements at ISOLDE-CERN of their radioisotope yields are analyzed. The purity of short lived or rare radioisotopes suffer from isobaric contaminants, notably alkalis which are highly volatile and easily ionized elements. Therefore, relying on their chemical nature, temperature controlled transfer lines were equipped with a tube of quartz that aimed at trapping these unwanted elements before they reached the ion source. The successful application yields high alkali-suppression factors for several elements (ie: 80, 82mRb, 126, 142Cs, 8Li, 46K, 25Na, 114In, 77Ga, 95, 96Sr) for quartz temperatures between 300ºC and 1100ºC. The enthalpies of adsorption on quartz were measu...

  17. Ab initio study of the adsorption, diffusion, and intercalation of alkali metal atoms on the (0001) surface of the topological insulator Bi{sub 2}Se{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Ryabishchenkova, A. G., E-mail: ryaange@gmail.com; Otrokov, M. M.; Kuznetsov, V. M.; Chulkov, E. V. [Tomsk State University (Russian Federation)

    2015-09-15

    Ab initio study of the adsorption, diffusion, and intercalation of alkali metal adatoms on the (0001) step surface of the topological insulator Bi{sub 2}Se{sub 3} has been performed for the case of low coverage. The calculations of the activation energies of diffusion of adatoms on the surface and in van der Waals gaps near steps, as well as the estimate of diffusion lengths, have shown that efficient intercalation through steps is possible only for Li and Na. Data obtained for K, Rb, and Cs atoms indicate that their thermal desorption at high temperatures can occur before intercalation. The results have been discussed in the context of existing experimental data.

  18. Enhanced water vapor barrier properties for biopolymer films by polyelectrolyte multilayer and atomic layer deposited Al{sub 2}O{sub 3} double-coating

    Energy Technology Data Exchange (ETDEWEB)

    Hirvikorpi, Terhi [VTT Technical Research Centre of Finland, Biologinkuja 7, Espoo, P.O. Box 1000, FI-02044 VTT (Finland); Vaehae-Nissi, Mika, E-mail: mika.vaha-nissi@vtt.fi [VTT Technical Research Centre of Finland, Biologinkuja 7, Espoo, P.O. Box 1000, FI-02044 VTT (Finland); Harlin, Ali [VTT Technical Research Centre of Finland, Biologinkuja 7, Espoo, P.O. Box 1000, FI-02044 VTT (Finland); Salomaeki, Mikko [University of Turku, Department of Chemistry, Laboratory of Materials Chemistry and Chemical Analysis, Vatselankatu 2, FI-20014 (Finland); Areva, Sami [Tampere University of Technology, Department of Biomedical Engineering, Biokatu 6, P.O. Box 692, FI-33101 Tampere (Finland); Korhonen, Juuso T. [Aalto University School of Science, Department of Applied Physics, P.O. Box 15100 FI-00076 AALTO, Espoo (Finland); Karppinen, Maarit [Aalto University School of Chemical Technology, Laboratory of Inorganic Chemistry, P.O. Box 16100, FI-00076 AALTO, Espoo (Finland)

    2011-09-01

    Commercial polylactide (PLA) films are coated with a thin (20 nm) non-toxic polyelectrolyte multilayer (PEM) film made from sodium alginate and chitosan and additionally with a 25-nm thick atomic layer deposited (ALD) Al{sub 2}O{sub 3} layer. The double-coating of PEM + Al{sub 2}O{sub 3} is found to significantly enhance the water vapor barrier properties of the PLA film. The improvement is essentially larger compared with the case the PLA film being just coated with an ALD-grown Al{sub 2}O{sub 3} layer. The enhanced water vapor barrier characteristics of the PEM + Al{sub 2}O{sub 3} double-coated PLA films are attributed to the increased hydrophobicity of the surface of these films.

  19. Methods of Soft Tissue Emulsification Using a Mechanism of Ultrasonic Atomization Inside Gas or Vapor Cavities and Associated Systems and Devices

    Science.gov (United States)

    Sapozhnikov, Oleg A. (Inventor); Bailey, Michael R. (Inventor); Crum, Lawrence A. (Inventor); Khokhlova, Tatiana D. (Inventor); Khokhlova, Vera A. (Inventor); Simon, Julianna C. (Inventor); Wang, Yak-Nam (Inventor)

    2016-01-01

    The present technology is directed to methods of soft tissue emulsification using a mechanism of ultrasonic atomization inside gas or vapor cavities, and associated systems and devices. In several embodiments, for example, a method of non-invasively treating tissue includes pulsing ultrasound energy from the ultrasound source toward the target site in tissue. The ultrasound source is configured to emit high intensity focused ultrasound (HIFU) waves. The target site comprises a pressure-release interface of a gas or vapor cavity located within the tissue. The method continues by generating shock waves in the tissue to induce a lesion in the tissue at the target site. The method additionally includes characterizing the lesion based on a degree of at least one of a mechanical or thermal ablation of the tissue.

  20. Environmental site description for a Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) production plant at the Oak Ridge Gaseous Diffusion Plant Site

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-01

    In January 1990, the Secretary of Energy approved a plan for the demonstration and deployment of the Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) technology, with the near-term goal to provide the necessary information to make a deployment decision by November 1992. The U-AVLIS process is based on electrostatic extraction of photoionized U-235 atoms from an atomic vapor stream created by electron-beam vaporization of uranium metal alloy. A programmatic document for use in screening DOE sites to locate the U-AVLIS production plant was developed and implemented in two parts (Wolsko et al. 1991). The first part consisted of a series of screening analyses, based on exclusionary and other criteria, that identified a reasonable number of candidate sites. These sites were then subjected to a more rigorous and detailed comparative analysis for the purpose of developing a short list of reasonable alternative sites for later environmental examination. This environmental site description (ESD) provides a detailed description of the ORGDP site and vicinity suitable for use in an environmental impact statement (EIS). The report is based on existing literature, data collected at the site, and information collected by Argonne National Laboratory (ANL) staff during a site visit. The organization of the ESD is as follows. Topics addressed in Sec. 2 include a general site description and the disciplines of geology, water resources, biotic resources, air resources, noise, cultural resources, land use, socioeconomics, and waste management. Identification of any additional data that would be required for an EIS is presented in Sec. 3. Following the site description and additional data requirements, Sec. 4 provides a short, qualitative assessment of potential environmental issues. 37 refs., 20 figs., 18 tabs.

  1. Development of an optically pumped atomic magnetometer using a K-Rb hybrid cell and its application to magnetocardiography

    Directory of Open Access Journals (Sweden)

    Yosuke Ito

    2012-09-01

    Full Text Available We have developed an optically pumped atomic magnetometer using a hybrid cell of K and Rb. The hybrid optical pumping technique can apply dense alkali-metal vapor to the sensor head and leads to high signal intensity. We use dense Rb vapor as probed atoms, and achieve a sensitivity of approximately 100 fTrms/Hz1/2 around 10 Hz. In this case, the sensitivity is limited by the system noise, and the magnetic linewidth is narrower than that for direct Rb optical pumping. We demonstrated magnetocardiography using the magnetometer and obtained clear human magnetocardiograms.

  2. Binding to Redox-Inactive Alkali and Alkaline Earth Metal Ions Strongly Deactivates the C-H Bonds of Tertiary Amides toward Hydrogen Atom Transfer to Reactive Oxygen Centered Radicals.

    Science.gov (United States)

    Salamone, Michela; Carboni, Giulia; Mangiacapra, Livia; Bietti, Massimo

    2015-09-18

    The effect of alkali and alkaline earth metal ions on the reactions of the cumyloxyl radical (CumO(•)) with N,N-dimethylformamide (DMF) and N,N-dimethylacetamide (DMA) was studied by laser flash photolysis. In acetonitrile, a >2 order of magnitude decrease in the rate constant for hydrogen atom transfer (HAT) from the C-H bonds of these substrates (kH) was measured after addition of Li(+). This behavior was explained in terms of a strong interaction between Li(+) and the oxygen atom of both DMF and DMA that increases the extent of positive charge on the amide, leading to C-H bond deactivation toward HAT to the electrophilic radical CumO(•). Similar effects were observed after addition of Ca(2+), which was shown to strongly bind up to four equivalents of the amide substrates. With Mg(2+), weak C-H deactivation was observed for the first two substrate equivalents followed by stronger deactivation for two additional equivalents. No C-H deactivation was observed in DMSO after addition of Li(+) and Mg(2+). These results point toward the important role played by metal ion Lewis acidity and solvent Lewis basicity, indicating that C-H deactivation can be modulated by varying the nature of the metal cation and solvent and allowing for careful control over the HAT reactivity of amide substrates.

  3. Generation and characterization of alkali metal clusters in Y-FAU zeolites. An ESR and MAS NMR spectroscopic study

    Science.gov (United States)

    Hannus, István; Béres, Attila; Nagy, János B.; Halász, János; Kiricsi, Imre

    1997-06-01

    Charged and neutral metal clusters of various compositions and sizes can be prepared by controlling the alkali metal content by the decomposition of alkali azides and the composition of the host zeolite by ion-exchange. ESR signals show that electron transfer from alkali metal atoms to alkali metal cations does occur, but in a direction opposite to that predicted by the gas-phase thermochemistry. Alkali metal clusters proved to be very active basic catalytic centers.

  4. Simple-design ultra-low phase noise microwave frequency synthesizers for high-performing Cs and Rb vapor-cell atomic clocks

    Energy Technology Data Exchange (ETDEWEB)

    François, B. [FEMTO-ST, CNRS, Université de Franche-Comté, 26 chemin de l’Epitaphe, 25030 Besançon (France); INRIM, Strada delle Cacce 91, 10135 Torino (Italy); Calosso, C. E.; Micalizio, S. [INRIM, Strada delle Cacce 91, 10135 Torino (Italy); Abdel Hafiz, M.; Boudot, R. [FEMTO-ST, CNRS, Université de Franche-Comté, 26 chemin de l’Epitaphe, 25030 Besançon (France)

    2015-09-15

    We report on the development and characterization of novel 4.596 GHz and 6.834 GHz microwave frequency synthesizers devoted to be used as local oscillators in high-performance Cs and Rb vapor-cell atomic clocks. The key element of the synthesizers is a custom module that integrates a high spectral purity 100 MHz oven controlled quartz crystal oscillator frequency-multiplied to 1.6 GHz with minor excess noise. Frequency multiplication, division, and mixing stages are then implemented to generate the exact output atomic resonance frequencies. Absolute phase noise performances of the output 4.596 GHz signal are measured to be −109 and −141 dB rad{sup 2}/Hz at 100 Hz and 10 kHz Fourier frequencies, respectively. The phase noise of the 6.834 GHz signal is −105 and −138 dB rad{sup 2}/Hz at 100 Hz and 10 kHz offset frequencies, respectively. The performances of the synthesis chains contribute to the atomic clock short term fractional frequency stability at a level of 3.1 × 10{sup −14} for the Cs cell clock and 2 × 10{sup −14} for the Rb clock at 1 s averaging time. This value is comparable with the clock shot noise limit. We describe the residual phase noise measurements of key components and stages to identify the main limitations of the synthesis chains. The residual frequency stability of synthesis chains is measured to be at the 10{sup −15} level for 1 s integration time. Relevant advantages of the synthesis design, using only commercially available components, are to combine excellent phase noise performances, simple-architecture, low-cost, and to be easily customized for signal output generation at 4.596 GHz or 6.834 GHz for applications to Cs or Rb vapor-cell frequency standards.

  5. Simple-design ultra-low phase noise microwave frequency synthesizers for high-performing Cs and Rb vapor-cell atomic clocks.

    Science.gov (United States)

    François, B; Calosso, C E; Abdel Hafiz, M; Micalizio, S; Boudot, R

    2015-09-01

    We report on the development and characterization of novel 4.596 GHz and 6.834 GHz microwave frequency synthesizers devoted to be used as local oscillators in high-performance Cs and Rb vapor-cell atomic clocks. The key element of the synthesizers is a custom module that integrates a high spectral purity 100 MHz oven controlled quartz crystal oscillator frequency-multiplied to 1.6 GHz with minor excess noise. Frequency multiplication, division, and mixing stages are then implemented to generate the exact output atomic resonance frequencies. Absolute phase noise performances of the output 4.596 GHz signal are measured to be -109 and -141 dB rad(2)/Hz at 100 Hz and 10 kHz Fourier frequencies, respectively. The phase noise of the 6.834 GHz signal is -105 and -138 dB rad(2)/Hz at 100 Hz and 10 kHz offset frequencies, respectively. The performances of the synthesis chains contribute to the atomic clock short term fractional frequency stability at a level of 3.1 × 10(-14) for the Cs cell clock and 2 × 10(-14) for the Rb clock at 1 s averaging time. This value is comparable with the clock shot noise limit. We describe the residual phase noise measurements of key components and stages to identify the main limitations of the synthesis chains. The residual frequency stability of synthesis chains is measured to be at the 10(-15) level for 1 s integration time. Relevant advantages of the synthesis design, using only commercially available components, are to combine excellent phase noise performances, simple-architecture, low-cost, and to be easily customized for signal output generation at 4.596 GHz or 6.834 GHz for applications to Cs or Rb vapor-cell frequency standards.

  6. Relativistic many-body calculations of energy levels, hyperfine constants, electric-dipole matrix elements and static polarizabilities for alkali-metal atoms

    CERN Document Server

    Safronova, M S; Derevianko, S A

    1999-01-01

    Removal energies and hyperfine constants of the lowest four $ns, np_{1/2}$ and $np_{3/2}$ states in Na, K, Rb and Cs are calculated; removal energies of the n=7--10 states and hyperfine constants of the n=7 and 8 states in Fr are also calculated. The calculations are based on the relativistic single-double (SD) approximation in which single and double excitations of Dirac-Hartree-Fock (DHF) wave functions are included to all-orders in perturbation theory. Using SD wave functions, accurate values of removal energies, electric-dipole matrix elements and static polarizabilities are obtained, however, SD wave functions give poor values of magnetic-dipole hyperfine constants for heavy atoms. To obtain accurate values of hyperfine constants for heavy atoms, we include triple excitations partially in the wave functions. The present calculations provide the basis for reevaluating PNC amplitudes in Cs and Fr.

  7. Direct determination of arsenic in soil samples by fast pyrolysis–chemical vapor generation using sodium formate as a reductant followed by nondispersive atomic fluorescence spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Duan, Xuchuan; Zhang, Jingya; Bu, Fanlong

    2015-09-01

    This new study shows for the first time that sodium formate can react with trace arsenic to form volatile species via fast pyrolysis – chemical vapor generation. We found that the presence of thiourea greatly enhanced the generation efficiency and eliminated the interference of copper. We studied the reaction temperature, the volume of sodium formate, the reaction acidity, and the carried argon rate using nondispersive atomic fluorescence spectrometry. Under optimal conditions of T = 500 °C, the volumes of 30% sodium formate and 10% thiourea were 0.2 ml and 0.05 ml, respectively. The carrier argon rate was 300 ml min{sup −1} and the detection limit and precision of arsenic were 0.39 ng and 3.25%, respectively. The amount of arsenic in soil can be directly determined by adding trace amount of hydrochloric acid as a decomposition reagent without any sample pretreatment. The method was successfully applied to determine trace amount of arsenic in two soil-certified reference materials (GBW07453 and GBW07450), and the results were found to be in agreement with certified reference values. - Highlights: • Sodium formate can react with trace arsenic to form volatile species via pyrolysis–chemical vapor generation. • Thiourea can enhance the generation efficiency and eliminate the interference of copper. • Arsenic in soil Sample can be directly determined without sample pretreatment.

  8. Determination of Hg(II) in waters by on-line preconcentration using Cyanex 923 as a sorbent — Cold vapor atomic absorption spectrometry

    Science.gov (United States)

    Duan, Taicheng; Song, Xuejie; Xu, Jingwei; Guo, Pengran; Chen, Hangting; Li, Hongfei

    2006-09-01

    Using a solid phase extraction mini-column home-made from a neutral extractant Cyanex 923, inorganic Hg could be on-line preconcentrated and simultaneously separated from methyl mercury. The preconcentrated Hg (II) was then eluted with 10% HNO 3 and subsequently reduced by NaBH 4 to form Hg vapor before determination by cold vapor atomic absorption spectrometry (CVAAS). Optimal conditions for and interferences on the Hg preconcentration and measurement were at 1% HCl, for a 25 mL sample uptake volume and a 10 mL min - 1 sample loading rate. The detection limit was 0.2 ng L - 1 and much lower than that of conventional method (around 15.8 ng L - 1 ). The relative standard deviation (RSD) is 1.8% for measurements of 40 ng L - 1 of Hg and the linear working curve is from 20 to 2000 ng L - 1 (with a correlation coefficient of 0.9996). The method was applied in determination of inorganic Hg in city lake and deep well water (from Changchun, Jilin, China), and recovery test results for both samples were satisfactory.

  9. Determination of Hg(II) in waters by on-line preconcentration using Cyanex 923 as a sorbent - Cold vapor atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Duan Taicheng [State Key Laboratory of Electroanalytical Chemistry, National Research Center of Electroanalytical and Spectroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Song Xuejie [State Key Laboratory of Electroanalytical Chemistry, National Research Center of Electroanalytical and Spectroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Xu Jingwei [State Key Laboratory of Electroanalytical Chemistry, National Research Center of Electroanalytical and Spectroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Guo Pengran [State Key Laboratory of Electroanalytical Chemistry, National Research Center of Electroanalytical and Spectroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Chen Hangting [State Key Laboratory of Electroanalytical Chemistry, National Research Center of Electroanalytical and Spectroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China)]. E-mail: htchen@ciac.jl.cn; Li Hongfei [Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China)

    2006-09-15

    Using a solid phase extraction mini-column home-made from a neutral extractant Cyanex 923, inorganic Hg could be on-line preconcentrated and simultaneously separated from methyl mercury. The preconcentrated Hg (II) was then eluted with 10% HNO{sub 3} and subsequently reduced by NaBH{sub 4} to form Hg vapor before determination by cold vapor atomic absorption spectrometry (CVAAS). Optimal conditions for and interferences on the Hg preconcentration and measurement were at 1% HCl, for a 25 mL sample uptake volume and a 10 mL min{sup -1} sample loading rate. The detection limit was 0.2 ng L{sup -1} and much lower than that of conventional method (around 15.8 ng L{sup -1}). The relative standard deviation (RSD) is 1.8% for measurements of 40 ng L{sup -1} of Hg and the linear working curve is from 20 to 2000 ng L{sup -1} (with a correlation coefficient of 0.9996). The method was applied in determination of inorganic Hg in city lake and deep well water (from Changchun, Jilin, China), and recovery test results for both samples were satisfactory.

  10. On-line continuous generation of zinc chelates in the vapor phase by reaction with sodium dithiocarbamates and determination by atomic fluorescence spectrometry

    Science.gov (United States)

    Duan, Xuchuan; Sun, Rui; Fang, Jinliang

    2017-02-01

    The present study shows for the first time that a volatile zinc chelate species can be generated by the on-line continuous merging of an acidified sample solution with an aqueous sodium diethyldithiocarbamate solution followed by rapid separation using a frit-based bubble gas-liquid separator at room temperature. The operating conditions for the generation of the vaporous zinc chelate were preliminarily investigated by non-dispersive atomic fluorescence spectrometry. The possible mechanism of zinc vapor generation is discussed. The study shows that the volatile species is an intermediate species with very similar properties to diethyldithiocarbamic acid and a very short half-life in the acidic solution. Moreover, this species can only be generated by on-line mixing and rapid separation. The efficiency of generation was 33-85% depending on acidity. Under optimal conditions, the flow rates of the sample and Na-DDTC solution were 1.3 ml min- 1, the carrier argon flow rate was 225 ml min- 1, the acid concentration of the sample solution and the concentration of Na-DDTC were 0.05 M and 0.4% (m/v), respectively, the detection limit of zinc was 0.33 (3σ) ng ml- 1, and the relative standard deviation (RSD) was 1.3%. The accuracy of the method was verified by the determination of zinc in the plant reference materials GBW10015 (spinach) and GBW10045 (rice). The results were in good agreement with the certified reference values.

  11. Model polymer etching and surface modification by a time modulated RF plasma jet: role of atomic oxygen and water vapor

    Science.gov (United States)

    Luan, P.; Knoll, A. J.; Wang, H.; Kondeti, V. S. S. K.; Bruggeman, P. J.; Oehrlein, G. S.

    2017-01-01

    The surface interaction of a well-characterized time modulated radio frequency (RF) plasma jet with polystyrene, poly(methyl methacrylate) and poly(vinyl alcohol) as model polymers is investigated. The RF plasma jet shows fast polymer etching but mild chemical modification with a characteristic carbonate ester and NO formation on the etched surface. By varying the plasma treatment conditions including feed gas composition, environment gaseous composition, and treatment distance, we find that short lived species, especially atomic O for Ar/1% O2 and 1% air plasma and OH for Ar/1% H2O plasma, play an essential role for polymer etching. For O2 containing plasma, we find that atomic O initiates polymer etching and the etching depth mirrors the measured decay of O atoms in the gas phase as the nozzle-surface distance increases. The etching reaction probability of an O atom ranging from 10-4 to 10-3 is consistent with low pressure plasma research. We also find that adding O2 and H2O simultaneously into Ar feed gas quenches polymer etching compared to adding them separately which suggests the reduction of O and OH density in Ar/O2/H2O plasma.

  12. Ionic Vapor Composition in Critical and Supercritical States of Strongly Interacting Ionic Compounds.

    Science.gov (United States)

    Chaban, Vitaly V; Prezhdo, Oleg V

    2016-05-12

    The critical point, CP (T, P), of the phase diagram quantifies the minimum amount of kinetic energy needed to prevent a substance from existing in a condensed phase. Therefore, the CP is closely related to the properties of the fluid far below the critical temperature. Approaches designed to predict thermophysical properties of a system necessarily aim to provide reliable estimates of the CP. Vice versa, CP estimation is impossible without knowledge of the vapor phase behavior. We report ab initio Born-Oppenheimer molecular dynamics (BOMD) simulations of sodium and potassium chlorides, NaCl and KCl, at and above their expected CPs. We advance the present knowledge regarding the existence of ionic species in the vapor phase by establishing significant percentages of atomic clusters: 29-30% in NaCl and 34-38% in KCl. A neutral pair of counterions is the most abundant cluster in the ionic vapors (ca. 35% of all vaporized ions exist in this form). Unexpectedly, an appreciable fraction of clusters is charged. The ionic vapor composition is determined by the vapor density, rather than the nature of the alkali ion. The previously suggested CPs of NaCl and KCl appear overestimated, based on the present simulations. The reported results offer essential insights into the ionic fluid properties and assist in development of thermodynamic theories. The ab initio BOMD method has been applied to investigate the vapor phase composition of an ionic fluid for the first time.

  13. Slow and stored light under conditions of electromagnetically induced transparency and four wave mixing in an atomic vapor

    Science.gov (United States)

    Phillips, Nathaniel Blair

    The recent prospect of efficient, reliable, and secure quantum communication relies on the ability to coherently and reversibly map nonclassical states of light onto long-lived atomic states. A promising technique that accomplishes this employs Electromagnetically Induced Transparency (EIT), in which a strong classical control field modifies the optical properties of a weak signal field in such a way that a previously opaque medium becomes transparent to the signal field. The accompanying steep dispersion in the index of refraction allows for pulses of light to be decelerated, then stored as an atomic excitation, and later retrieved as a photonic mode. This dissertation presents the results of investigations into methods for optimizing the memory efficiency of this process in an ensemble of hot Rb atoms. We have experimentally demonstrated the effectiveness of two protocols for yielding the best memory efficiency possible at a given atomic density. Improving memory efficiency requires operation at higher optical depths, where undesired effects such as four-wave mixing (FWM) become enhanced and can spontaneously produce a new optical mode (Stokes field). We present the results of experimental and theoretical investigations of the FWM-EIT interaction under continuous-wave (cw), slow light, and stored light conditions. In particular, we provide evidence that indicates that while a Stokes field is generated upon retrieval of the signal field, any information originally encoded in a seeded Stokes field is not independently preserved during the storage process. We present a simple model that describes the propagation dynamics and provides an intuitive description of the EIT-FWM process.

  14. Study of porogen removal by atomic hydrogen generated by hot wire chemical vapor deposition for the fabrication of advanced low-k thin films

    Energy Technology Data Exchange (ETDEWEB)

    Godavarthi, S., E-mail: srinivas@cinvestav.mx [Program of Nanoscience and Nanotechnology, Cinvestav-IPN (Mexico); Universidad Nacional Autonoma de Mexico, Instituto de Ciencias Fisicas, Av. Universidad, Cuernavaca, Morelos (Mexico); Wang, C.; Verdonck, P. [imec, Kapeldreef 75, 3001 Leuven (Belgium); Matsumoto, Y.; Koudriavtsev, I. [Program of Nanoscience and Nanotechnology, Cinvestav-IPN (Mexico); SEES, Electrical Engineering Department, Cinvestav-IPN (Mexico); Dutt, A. [SEES, Electrical Engineering Department, Cinvestav-IPN (Mexico); Tielens, H.; Baklanov, M.R. [imec, Kapeldreef 75, 3001 Leuven (Belgium)

    2015-01-30

    In order to obtain low-k dielectric films, a subtractive technique, which removes sacrificial porogens from a hydrogenated silicon oxycarbide (SiOC:H) film, has been used successfully by different groups in the past. In this paper, we report on the porogen removal from porogenated SiOC:H films, using a hot wire chemical vapor deposition (HWCVD) equipment. Molecular hydrogen is dissociated into atomic hydrogen by the hot wires and these atoms may successfully remove the hydrocarbon groups from the porogenated SiOC:H films. The temperature of the HWCVD filaments proved to be a determining factor. By Fourier transform infrared spectroscopy, X-ray reflectivity (XRR), secondary ion mass spectrometry (SIMS), ellipsometric porosimetry and capacitance-voltage analyses, it was possible to determine that for temperatures higher than 1700 °C, efficient porogen removal occurred. For temperatures higher than 1800 °C, the presence of OH groups was detected. The dielectric constant was the lowest, 2.28, for the samples processed at a filament temperature of 1800 °C, although porosity measurements showed higher porosity for the films deposited at the higher temperatures. XRR and SIMS analyses indicated densification and Tungsten (W) incorporation at the top few nanometers of the films.

  15. Evaluation of the memory effect on gold-coated silica adsorption tubes used for the analysis of gaseous mercury by cold vapor atomic absorption spectrometry.

    Science.gov (United States)

    Rahman, Mohammad Mahmudur; Brown, Richard J C; Kim, Ki-Hyun; Yoon, Hye-On; Phan, Nhu-Thuc

    2013-01-01

    In an effort to reduce the experimental bias involved in the analysis of gaseous elemental mercury (Hg(o)), the blank response from gold-coated adsorption tubes has been investigated using cold vapor atomic absorption spectrometry (CVAAS). Our study has been compared with our recent investigation on memory effect in a cold vapour atomic fluorescence spectrometry (CVAFS). The pattern of blank responses was quantified after loading different amounts of mercury and after different time intervals of 1, 14, and 45 days. In case of the one day interval, the result of five to six instant blank heating cycles confirmed successful liberation of mercury following the second and third blank heating cycles. The results of 14 or 45 days generally suggest that liberation of excess mercury is affected by both the initial loading amount and the length of storage time prior to analysis. We have demonstrated a possibly effective way to reduce memory effects. Some similarities of these results with those from CVAFS experiment suggests that the blank response is caused by a combination of mercury absorbed within the bulk gold and micro- and nanoparticles liberated during heating and not from coabsorbing interfering gaseous species.

  16. Evaluation of the Memory Effect on Gold-Coated Silica Adsorption Tubes Used for the Analysis of Gaseous Mercury by Cold Vapor Atomic Absorption Spectrometry

    Directory of Open Access Journals (Sweden)

    Mohammad Mahmudur Rahman

    2013-01-01

    Full Text Available In an effort to reduce the experimental bias involved in the analysis of gaseous elemental mercury (Hgo, the blank response from gold-coated adsorption tubes has been investigated using cold vapor atomic absorption spectrometry (CVAAS. Our study has been compared with our recent investigation on memory effect in a cold vapour atomic fluorescence spectrometry (CVAFS. The pattern of blank responses was quantified after loading different amounts of mercury and after different time intervals of 1, 14, and 45 days. In case of the one day interval, the result of five to six instant blank heating cycles confirmed successful liberation of mercury following the second and third blank heating cycles. The results of 14 or 45 days generally suggest that liberation of excess mercury is affected by both the initial loading amount and the length of storage time prior to analysis. We have demonstrated a possibly effective way to reduce memory effects. Some similarities of these results with those from CVAFS experiment suggests that the blank response is caused by a combination of mercury absorbed within the bulk gold and micro- and nanoparticles liberated during heating and not from coabsorbing interfering gaseous species.

  17. Recyclable decoration of amine-functionalized magnetic nanoparticles with Ni(2+) for determination of histidine by photochemical vapor generation atomic spectrometry.

    Science.gov (United States)

    Hu, Yuan; Wang, Qi; Zheng, Chengbin; Wu, Li; Hou, Xiandeng; Lv, Yi

    2014-01-07

    It is critically important to accurately determine histidine since it is an indicator for many diseases when at an abnormal level. Here, an inexpensive and simple method using an amine-functionalized magnetic nanoparticle-based Ni(2+)-histidine affinity pair system was developed for highly sensitive and selective detection of histidine in human urine by photochemical vapor generation atomic spectrometry. Ni(2+) was first bound to the amine groups of the amine-functionalized magnetic nanoparticles and then liberated to solution via the highly specific interaction between the histidine and Ni(2+) in the presence of histidine. The liberated histidine-Ni(2+) complex was exposed to UV irradiation in the presence of formic acid to form gaseous nickel tetracarbonyl, which was separated from the sample matrix and determined by atomic absorption/fluorescence spectrometry. Compared to other methods, this approach promises high sensitivity, simplicity in design, and convenient operation. The need for organic solvents, enzymatic reactions, separation processes, chemical modification, expensive instrumentations, and sophisticated and complicated pretreatment is minimized with this strategy. A limit of detection of 1 nM was obtained and provided tens-to-hundreds of fold improvements over that achieved with conventional methods. The protocol was evaluated by analysis of several urine samples with good recoveries and showed great potential for practical application.

  18. Optical pumping in a microfabricated Rb vapor cell using a microfabricated Rb discharge light source

    Energy Technology Data Exchange (ETDEWEB)

    Venkatraman, V.; Kang, S.; Affolderbach, C.; Mileti, G., E-mail: gaetano.mileti@unine.ch [Laboratoire Temps-Fréquence, University of Neuchâtel, Neuchâtel 2000 (Switzerland); Shea, H. [Microsystems for Space Technologies Laboratory, Ecole Polytechnique Fédérale de Lausanne (EPFL), Neuchâtel 2002 (Switzerland)

    2014-02-03

    Miniature (vapor-cell based devices using optical pumping of alkali atoms, such as atomic clocks and magnetometers, today mostly employ vertical-cavity surface-emitting lasers as pump light sources. Here, we report on the demonstration of optical pumping in a microfabricated alkali vapor resonance cell using (1) a microfabricated Rb discharge lamp light source, as well as (2) a conventional glass-blown Rb discharge lamp. The microfabricated Rb lamp cell is a dielectric barrier discharge (DBD) light source, having the same inner cell volume of around 40 mm{sup 3} as that of the resonance cell, both filled with suitable buffer gases. A miniature (∼2 cm{sup 3} volume) test setup based on the M{sub z} magnetometer interrogation technique was used for observation of optical-radiofrequency double-resonance signals, proving the suitability of the microfabricated discharge lamp to introduce efficient optical pumping. The pumping ability of this light source was found to be comparable to or even better than that of a conventional glass-blown lamp. The reported results indicate that the micro-fabricated DBD discharge lamp has a high potential for the development of a new class of miniature atomic clocks, magnetometers, and quantum sensors.

  19. Magic frequencies in atom-light interaction for precision probing of the density matrix

    CERN Document Server

    Givon, Menachem; Waxman, Amir; David, Tal; Groswasser, David; Japha, Yonathan; Folman, Ron

    2013-01-01

    We analyze theoretically and experimentally the existence of a {\\it magic frequency} for which the absorption of a linearly polarized light beam by vapor alkali atoms is independent of the population distribution among the Zeeman sub-levels and the angle between the beam and a magnetic field. The phenomenon originates from a peculiar cancelation of the contributions of higher moments of the atomic density matrix, and is described using the Wigner-Eckart theorem and inherent properties of Clebsch-Gordan coefficients. One important application is the robust measurement of the hyperfine population.

  20. Metallorganic chemical vapor deposition and atomic layer deposition approaches for the growth of hafnium-based thin films from dialkylamide precursors for advanced CMOS gate stack applications

    Science.gov (United States)

    Consiglio, Steven P.

    To continue the rapid progress of the semiconductor industry as described by Moore's Law, the feasibility of new material systems for front end of the line (FEOL) process technologies needs to be investigated, since the currently employed polysilicon/SiO2-based transistor system is reaching its fundamental scaling limits. Revolutionary breakthroughs in complementary-metal-oxide-semiconductor (CMOS) technology were recently announced by Intel Corporation and International Business Machines Corporation (IBM), with both organizations revealing significant progress in the implementation of hafnium-based high-k dielectrics along with metal gates. This announcement was heralded by Gordon Moore as "...the biggest change in transistor technology since the introduction of polysilicon gate MOS transistors in the late 1960s." Accordingly, the study described herein focuses on the growth of Hf-based dielectrics and Hf-based metal gates using chemical vapor-based deposition methods, specifically metallorganic chemical vapor deposition (MOCVD) and atomic layer deposition (ALD). A family of Hf source complexes that has received much attention recently due to their desirable properties for implementation in wafer scale manufacturing is the Hf dialkylamide precursors. These precursors are room temperature liquids and possess sufficient volatility and desirable decomposition characteristics for both MOCVD and ALD processing. Another benefit of using these sources is the existence of chemically compatible Si dialkylamide sources as co-precursors for use in Hf silicate growth. The first part of this study investigates properties of MOCVD-deposited HfO2 and HfSixOy using dimethylamido Hf and Si precursor sources using a customized MOCVD reactor. The second part of this study involves a study of wet and dry surface pre-treatments for ALD growth of HfO2 using tetrakis(ethylmethylamido)hafnium in a wafer scale manufacturing environment. The third part of this study is an investigation of

  1. Alkali promotion of N-2 dissociation over Ru(0001)

    DEFF Research Database (Denmark)

    Mortensen, Jens Jørgen; Hammer, Bjørk; Nørskov, Jens Kehlet

    1998-01-01

    Using self-consistent density functional calculations, we show that adsorbed Na and Cs lower the barrier for dissociation of N2 on Ru(0001). Since N2 dissociation is a crucial step in the ammonia synthesis reaction, we explain in this way the experimental observation that alkali metals promote...... the ammonia synthesis reaction over Ru catalysts. We also show that the origin of this effect is predominantly a direct electrostatic attraction between the adsorbed alkali atoms and the dissociating molecule....

  2. Photoemission spectroscopy study of a multi-alkali photocathode

    CERN Document Server

    Ettema, A R H

    2000-01-01

    In this paper a photoemission study of the highest core levels of the elements and the electron escape barrier (work function) in a multi-alkali photocathode are presented. The core levels indicate that the alkali atoms are in an oxidized state and therefore the compound Na sub 2 KSb can be regarded as an ionic semiconductor. The measured escape barrier of the Cs sub 2 O surface layer is determined as 2.3 eV.

  3. Porphyrins as Templates for Site-Selective Atomic Layer Deposition: Vapor Metalation and in Situ Monitoring of Island Growth.

    Science.gov (United States)

    Avila, Jason R; Emery, Jonathan D; Pellin, Michael J; Martinson, Alex B F; Farha, Omar K; Hupp, Joseph T

    2016-08-10

    Examinations of enzymatic catalysts suggest one key to efficient catalytic activity is discrete size metallo clusters. Mimicking enzymatic cluster systems is synthetically challenging because conventional solution methods are prone to aggregation or require capping of the cluster, thereby limiting its catalytic activity. We introduce site-selective atomic layer deposition (ALD) on porphyrins as an alternative approach to grow isolated metal oxide islands that are spatially separated. Surface-bound tetra-acid free base porphyrins (H2TCPP) may be metalated with Mn using conventional ALD precursor exposure to induce homogeneous hydroxide synthetic handles which acts as a nucleation point for subsequent ALD MnO island growth. Analytical fitting of in situ QCM mass uptake reveals island growth to be hemispherical with a convergence radius of 1.74 nm. This growth mode is confirmed with synchrotron grazing-incidence small-angle X-ray scattering (GISAXS) measurements. Finally, we extend this approach to other ALD chemistries to demonstrate the generality of this route to discrete metallo island materials.

  4. Alkali-metal azides interacting with metal-organic frameworks.

    Science.gov (United States)

    Armata, Nerina; Cortese, Remedios; Duca, Dario; Triolo, Roberto

    2013-01-14

    Interactions between alkali-metal azides and metal-organic framework (MOF) derivatives, namely, the first and third members of the isoreticular MOF (IRMOF) family, IRMOF-1 and IRMOF-3, are studied within the density functional theory (DFT) paradigm. The investigations take into account different models of the selected IRMOFs. The mutual influence between the alkali-metal azides and the π rings or Zn centers of the involved MOF derivatives are studied by considering the interactions both of the alkali-metal cations with model aromatic centers and of the alkali-metal azides with distinct sites of differently sized models of IRMOF-1 and IRMOF-3. Several exchange and correlation functionals are employed to calculate the corresponding interaction energies. Remarkably, it is found that, with increasing alkali-metal atom size, the latter decrease for cations interacting with the π-ring systems and increase for the azides interacting with the MOF fragments. The opposite behavior is explained by stabilization effects on the azide moieties and determined by the Zn atoms, which constitute the inorganic vertices of the IRMOF species. Larger cations can, in fact, coordinate more efficiently to both the aromatic center and the azide anion, and thus stabilizing bridging arrangements of the azide between one alkali-metal and two Zn atoms in an η(2) coordination mode are more favored.

  5. Vibrations of alkali metal overlayers on metal surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Rusina, G G; Eremeev, S V; Borisova, S D [Institute of Strength Physics and Materials Science SB RAS, 634021, Tomsk (Russian Federation); Echenique, P M; Chulkov, E V [Donostia International Physics Center (DIPC), 20018 San Sebastian/Donostia, Basque Country (Spain); Benedek, G [Dipartimento di Scienza dei Materiali, Universita di Milano-Bicocca, Via Cozzi 53, 20125 Milano (Italy)], E-mail: rusina@ispms.tsc.ru

    2008-06-04

    We review the current progress in the understanding of vibrations of alkalis adsorbed on metal surfaces. The analysis of alkali vibrations was made on the basis of available theoretical and experimental results. We also include in this discussion our recent calculations of vibrations in K/Pt(111) and Li(Na)/Cu(001) systems. The dependence of alkali adlayer localized modes on atomic mass, adsorption position and coverage as well as the dependence of vertical vibration frequency on the substrate orientation is discussed. The square root of atomic mass dependence of the vertical vibration energy has been confirmed by using computational data for alkalis on the Al(111) and Cu(001) substrates. We have confirmed that in a wide range of submonolayer coverages the stretch mode energy remains nearly constant while the energy of in-plane polarized modes increases with the increase of alkali coverage. It was shown that the spectrum of both stretch and in-plane vibrations can be very sensitive to the adsorption position of alkali atoms and substrate orientation.

  6. Vibrations of alkali metal overlayers on metal surfaces

    Science.gov (United States)

    Rusina, G. G.; Eremeev, S. V.; Echenique, P. M.; Benedek, G.; Borisova, S. D.; Chulkov, E. V.

    2008-06-01

    We review the current progress in the understanding of vibrations of alkalis adsorbed on metal surfaces. The analysis of alkali vibrations was made on the basis of available theoretical and experimental results. We also include in this discussion our recent calculations of vibrations in K/Pt(111) and Li(Na)/Cu(001) systems. The dependence of alkali adlayer localized modes on atomic mass, adsorption position and coverage as well as the dependence of vertical vibration frequency on the substrate orientation is discussed. The square root of atomic mass dependence of the vertical vibration energy has been confirmed by using computational data for alkalis on the Al(111) and Cu(001) substrates. We have confirmed that in a wide range of submonolayer coverages the stretch mode energy remains nearly constant while the energy of in-plane polarized modes increases with the increase of alkali coverage. It was shown that the spectrum of both stretch and in-plane vibrations can be very sensitive to the adsorption position of alkali atoms and substrate orientation.

  7. Methylmercury in water samples at the pg/L level by online preconcentration liquid chromatography cold vapor-atomic fluorescence spectrometry

    Science.gov (United States)

    Brombach, Christoph-Cornelius; Chen, Bin; Corns, Warren T.; Feldmann, Jörg; Krupp, Eva M.

    2015-03-01

    Ultra-traces of methylmercury at the sub-ppt level can be magnified in the foodweb and is of concern. In environmental monitoring a routine robust analytical method is needed to determine methylmercury in water. The development of an analytical method for ultra-trace speciation analysis of methylmercury (MeHg) in water samples is described. The approach is based on HPLC-CV-AFS with on-line preconcentration of water samples up to 200 mL, resulting in a detection limit of 40 pg/L (ppq) for MeHg, expressed as Hg. The unit consists of an optimized preconcentration column filled with a sulfur-based sorption material, on which mercury species are preconcentrated and subsequently eluted, separated and detected via HPLC-CV-AFS (high performance liquid chromatography-cold vapor atomic fluorescence spectrometry). During the method development a type of adsorbate material, the pH dependence, the sample load rate and the carry-over were investigated using breakthrough experiments. The method shows broad pH stability in the range of pH 0 to 7, without the need for buffer addition and shows limited matrix effects so that MeHg is quantitatively recovered from sewage, river and seawater directly in the acidified samples without sample preparation.

  8. Automatic flow-batch system for cold vapor atomic absorption spectroscopy determination of mercury in honey from Argentina using online sample treatment.

    Science.gov (United States)

    Domínguez, Marina A; Grünhut, Marcos; Pistonesi, Marcelo F; Di Nezio, María S; Centurión, María E

    2012-05-16

    An automatic flow-batch system that includes two borosilicate glass chambers to perform sample digestion and cold vapor atomic absorption spectroscopy determination of mercury in honey samples was designed. The sample digestion was performed by using a low-cost halogen lamp to obtain the optimum temperature. Optimization of the digestion procedure was done using a Box-Behnken experimental design. A linear response was observed from 2.30 to 11.20 μg Hg L(-1). The relative standard deviation was 3.20% (n = 11, 6.81 μg Hg L(-1)), the sample throughput was 4 sample h(-1), and the detection limit was 0.68 μg Hg L(-1). The obtained results with the flow-batch method are in good agreement with those obtained with the reference method. The flow-batch system is simple, allows the use of both chambers simultaneously, is seen as a promising methodology for achieving green chemistry goals, and is a good proposal to improving the quality control of honey.

  9. Solid Phase Extraction of Inorganic Mercury Using 5-Phenylazo-8-hydroxyquinoline and Determination by Cold Vapor Atomic Fluorescence Spectroscopy in Natural Water Samples

    Science.gov (United States)

    Daye, Mirna; Halwani, Jalal; Hamzeh, Mariam

    2013-01-01

    8-Hydroxyquinoline (8-HQ) was chosen as a powerful ligand for Hg solid phase extraction. Among several chelating resins based on 8-HQ, 5-phenylazo-8-hydroxyquinoline (5Ph8HQ) is used for mercury extraction in which the adsorption dynamics were fully studied. It has been shown that Hg(II) is totally absorbed by 5Ph8HQ within the first 30 minutes of contact time with t1/2 5 minutes, following Langmuir adsorption model. At pH 4, the affinity of mercury is unchallenged by other metals except, for Cu(II), which have shown higher Kd value. With these latter characteristics, 5Ph8HQ was examined for the preconcentration of trace levels of Hg(II). The developed method showed quantitative recoveries of Hg(II) with LOD = 0.21 pg mL−1 and RSD = 3–6% using cold vapor atomic fluorescence spectroscopy (CV-AFS) with a preconcentration factor greater than 250. PMID:24459417

  10. Trace mercury determination in drinking and natural water samples by room temperature ionic liquid based-preconcentration and flow injection-cold vapor atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Martinis, Estefania M.; Berton, Paula [Laboratory of Environmental Research and Services of Mendoza (LISAMEN), (CCT - CONICET - Mendoza), Av. Ruiz Leal S/N Parque General San Martin, CC. 131, M 5502 IRA Mendoza (Argentina); Olsina, Roberto A. [INQUISAL-CONICET, Departamento de Quimica Analitica, Facultad de Quimica, Bioquimica y Farmacia, Universidad Nacional de San Luis, San Luis (Argentina); Altamirano, Jorgelina C. [Laboratory of Environmental Research and Services of Mendoza (LISAMEN), (CCT - CONICET - Mendoza), Av. Ruiz Leal S/N Parque General San Martin, CC. 131, M 5502 IRA Mendoza (Argentina); Instituto de Ciencias Basicas, Universidad Nacional de Cuyo, Mendoza (Argentina); Wuilloud, Rodolfo G., E-mail: rwuilloud@lab.cricyt.edu.ar [Laboratory of Environmental Research and Services of Mendoza (LISAMEN), (CCT - CONICET - Mendoza), Av. Ruiz Leal S/N Parque General San Martin, CC. 131, M 5502 IRA Mendoza (Argentina); Instituto de Ciencias Basicas, Universidad Nacional de Cuyo, Mendoza (Argentina)

    2009-08-15

    A liquid-liquid extraction procedure (L-L) based on room temperature ionic liquid (RTIL) was developed for the preconcentration and determination of mercury in different water samples. The analyte was quantitatively extracted with 1-butyl-3-methylimidazolium hexafluorophosphate ([C{sub 4}mim][PF{sub 6}]) under the form of Hg-2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (Hg-5-Br-PADAP) complex. A volume of 500 {mu}l of 9.0 mol L{sup -1} hydrochloric acid was used to back-extract the analyte from the RTIL phase into an aqueous media prior to its analysis by flow injection-cold vapor atomic absorption spectrometry (FI-CV-AAS). A preconcentration factor of 36 was achieved upon preconcentration of 20 mL of sample. The limit of detection (LOD) obtained under the optimal conditions was 2.3 ng L{sup -1} and the relative standard deviation (RSD) for 10 replicates at 1 {mu}g L{sup -1} Hg{sup 2+} was 2.8%, calculated with peaks height. The method was successfully applied to the determination of mercury in river, sea, mineral and tap water samples and a certified reference material (CRM).

  11. Trace mercury determination in drinking and natural water after preconcentration and separation by DLLME-SFO method coupled with cold vapor atomic absorption spectrometry

    Directory of Open Access Journals (Sweden)

    Abdollahi Atousa

    2014-07-01

    Full Text Available A novel dispersive liquid–liquid microextraction based on solidification of floating organic drop (DLLME-SFO for simultaneous separation/preconcentration of ultra trace amounts of mercury was used. A method based on amalgamation was used for collection of gaseous mercury on gold coated sand (Gold trap. The concentration of mercury was determined by cold vapor atomic absorption spectrometry (CV-AAS. The DLLME-SFO behavior of mercury by using dithizone as complexing agent was systematically investigated. The factors influencing, the complex formation and extraction of DLLME-SFO method such as type and volume of extraction and disperser solvents, pH, concentration of salt, centrifuging time and concentration of the chelating agent were optimized. The method was successfully applied to the determination of mercury in drinking and natural water and satisfactory relative recoveries (95–105% were achieved. The proposed procedure was based on very low consumption of organic solvents. The other benefits of the system were sensitive, simple, friendly to the environment, rejection of matrix constituent, low cost, the time consuming and high enrichment factor.

  12. Solid Phase Extraction of Inorganic Mercury Using 5-Phenylazo-8-hydroxyquinoline and Determination by Cold Vapor Atomic Fluorescence Spectroscopy in Natural Water Samples

    Directory of Open Access Journals (Sweden)

    Mirna Daye

    2013-01-01

    Full Text Available 8-Hydroxyquinoline (8-HQ was chosen as a powerful ligand for Hg solid phase extraction. Among several chelating resins based on 8-HQ, 5-phenylazo-8-hydroxyquinoline (5Ph8HQ is used for mercury extraction in which the adsorption dynamics were fully studied. It has been shown that Hg(II is totally absorbed by 5Ph8HQ within the first 30 minutes of contact time with t1/2 5 minutes, following Langmuir adsorption model. At pH 4, the affinity of mercury is unchallenged by other metals except, for Cu(II, which have shown higher Kd value. With these latter characteristics, 5Ph8HQ was examined for the preconcentration of trace levels of Hg(II. The developed method showed quantitative recoveries of Hg(II with LOD = 0.21 pg mL−1 and RSD = 3–6% using cold vapor atomic fluorescence spectroscopy (CV-AFS with a preconcentration factor greater than 250.

  13. Analysis of trace mercury in water by solid phase extraction using dithizone modified nanometer titanium dioxide and cold vapor atomic absorption spectrometry

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    A new method for analysis of trace mercury in water samples was developed, based on the combination of preconcentration/separation using dithizone-modified nanometer titanium dioxide (TiO2) as a solid phase extractant and determination by cold vapor atomic adsorption spectrometry (CVAAS). Dithizone was dissolved with alcohol and loaded on the surface of nano-sized TiO2 powders by stirring. The static adsorption behavior of Hg2+ on the dithizone-modified nanoparticles was investigated in detail. It was found that excellent adsorption ratio for Hg2+ could be obtained in the pH range of 7-8 with an oscillation time of 15 min, and a 5 mL of 3.5 mol·L-1 HCl solution could quantitatively elute Hg2+ from nanometer TiO2 powder. Common coexisting ions caused no obvious influence on the determination of mercury. The mechanisms for the adsorption and desorption were discussed. The detection limit (3σ) for Hg2+ was calculated to be 5 ng·L-1. The proposed method was applied to the determination of Hg2+ in a mineral water sample and a Zhujiang River water sample. By the standard addition method, the average recoveries were found to be 94.4%-108.3% with RSD (n = 5) of 2.9%-3.5%.

  14. Direct determination of arsenic in soil samples by fast pyrolysis-chemical vapor generation using sodium formate as a reductant followed by nondispersive atomic fluorescence spectrometry

    Science.gov (United States)

    Duan, Xuchuan; Zhang, Jingya; Bu, Fanlong

    2015-09-01

    This new study shows for the first time that sodium formate can react with trace arsenic to form volatile species via fast pyrolysis - chemical vapor generation. We found that the presence of thiourea greatly enhanced the generation efficiency and eliminated the interference of copper. We studied the reaction temperature, the volume of sodium formate, the reaction acidity, and the carried argon rate using nondispersive atomic fluorescence spectrometry. Under optimal conditions of T = 500 °C, the volumes of 30% sodium formate and 10% thiourea were 0.2 ml and 0.05 ml, respectively. The carrier argon rate was 300 ml min- 1 and the detection limit and precision of arsenic were 0.39 ng and 3.25%, respectively. The amount of arsenic in soil can be directly determined by adding trace amount of hydrochloric acid as a decomposition reagent without any sample pretreatment. The method was successfully applied to determine trace amount of arsenic in two soil-certified reference materials (GBW07453 and GBW07450), and the results were found to be in agreement with certified reference values.

  15. Ultraviolet vapor generation atomic fluorescence spectrometric determination of mercury in natural water with enrichment by on-line solid phase extraction

    Science.gov (United States)

    Qin, Deyuan; Gao, Feng; Zhang, Zhaohui; Zhao, Liqian; Liu, Jixin; Ye, Jianping; Li, Junwei; Zheng, Fengxi

    2013-10-01

    A novel method, which coupled an on-line solid phase extraction (SPE) enrichment with ultraviolet vapor generation (UVG) atomic fluorescence spectrometry (AFS), was developed to improve the sensitivity of mercury determination and to remove the interference of some anion and organics to UVG of mercury. A high mercury retention efficiency and maximum exclusion of inorganic and organic matrix in water samples were achieved by using C18 SPE mini cartridge modified with sodium diethyldithiocarbamate (DDTC). Fast and efficient elution from the cartridge was found by using L-cysteine mixing solution. Furthermore, through the investigation of different UV reactor designs, the most important factor was the structure of the reactor (which corresponded roughly to the photon flux) wherein the tubing was sintered into the UV lamp to give the highest UV generation efficiency. The second factor was the materials of the tubing (which roughly corresponded to the working wavelength). Synthetic quartz, characterized by the highest transparency at 185 nm, attained the highest UVG efficiency, suggesting that the most favorable wavelength for UVG was 185 nm. Under optimum conditions, the achievable detection limit (3σ) with sample loadings of 10.0 mL was 0.03 ng L- 1 and 0.08 ng L- 1 with different manifolds, respectively. The method was successfully applied to the determination of Hg in tap water, river water and lake water samples.

  16. An analytical method for determination of mercury by cold vapor atomic absorption spectroscopy; Determinazione di mercurio. Metodo per spettrometria di assorbimento atomico a vapori freddi (CV-AAS)

    Energy Technology Data Exchange (ETDEWEB)

    Campanella, L. [Rome Univ. La Sapienza, Rome (Italy); Mastroianni, D.; Capri, S.; Pettine, M. [CNR, Rome (Italy). Ist. di Ricerca sulle Acque; Spezia, S.; Bettinelli, M. [ENEL, Unified Modelling Language, Piacenza (Italy)

    1999-09-01

    An analytical procedure for the determination of total mercury in wastewaters and natural waters is described. Aqueous samples are fast digested with nitric acid by using the microwave-oven technique; the analysis of mercury is then performed by cold vapor atomic absorption spectrometry (CV-AAS) using two possible instrumental apparatus (batch system or flow injection). Sodium borohydride is used as the reducing agent for mercury in solution (Method A). The use of amalgamation traps on gold for the preconcentration of mercury lowers the detection limit of the analyte (Method B). [Italian] Viene descritta una procedura analitica per la determinazione del mercurio totale in acque di scarico e naturali. Il campione acquoso viene sottoposto a mineralizzazione con acido nitrico in forno a microonde e analizzato mediante spettroscopia di assorbimento atomico a vapori freddi (CV-AAS) in due possibili configurazioni strumentali (sistema batch oppure flow injection), utilizzando sodio boro idruro come agente riducente del mercurio (metodo A). L'impiego della trappola di oro per la preconcentrazione del mercurio mediante amalgama consente di determinare l'analita a livelli di pochi ng/L (metodo B).

  17. ALKALI RESISTANT CATALYST

    DEFF Research Database (Denmark)

    2008-01-01

    The present invention concerns the selective removal of nitrogen oxides (NOx) from gasses. In particular, the invention concerns a process, a catalyst and the use of a catalyst for the selective removal of nitrogen oxides in the presence of ammonia from gases containing a significant amount...... of alkali metal and/or alkali-earth compounds which process comprises using a catalyst combined of (i) a formed porous superacidic support, said superacidic support having an Hammett acidity stronger than Ho=-12, and (ii) a metal oxide catalytic component deposited on said superacidic support selected from...

  18. Formation and Stability of High-Spin Alkali Clusters

    Science.gov (United States)

    Schulz, C. P.; Claas, P.; Schumacher, D.; Stienkemeier, F.

    2004-01-01

    Helium nanodroplet isolation has been applied to agglomerate alkali clusters at temperatures of 380mK. The very weak binding to the surface of the droplets allows a selection of only weakly bound, high-spin states. Here we show that larger clusters of alkali atoms in high-spin states can be formed. The lack of strong bonds from pairing electrons makes these systems nonmetallic, vanderWaals like complexes of metal atoms. We find that sodium and potassium readily form such clusters containing up to 25atoms. In contrast, this process is suppressed for rubidium and cesium. Apparently, for these heavy alkalis, larger high-spin aggregates are not stable and depolarize spontaneously upon cluster formation.

  19. Positron collisions with alkali-metal atoms

    Science.gov (United States)

    Gien, T. T.

    1990-01-01

    The total cross sections for positron and electron collisions with potassium, sodium, lithium and rubidium are calculated, employing the modified Glauber approximation. The Modified Glauber cross sections for positron collision with potassium and sodium at low intermediate energies are found to agree reasonably well with existing experimental data.

  20. The Inhomogeneous Light Shift in Alkali Atoms.

    Science.gov (United States)

    1985-06-24

    could be easily confused with this effect. It is our contention that this was exactly the case with the asymmetries observed by Arditi and Picque for the...Goodwin, ed., Advances in Quantum Electronics, (Academic Press, New York, 1975). 21. M. Arditi and J. L. Picqug, J. Phys. B. 8 (14), L331 (1975). 38 0

  1. On-line cloud point extraction combined with electrothermal vaporization inductively coupled plasma atomic emission spectrometry for the speciation of inorganic antimony in environmental and biological samples

    Energy Technology Data Exchange (ETDEWEB)

    Li Yingjie [Department of Chemistry, Wuhan University, Wuhan 430072 (China); Hu Bin [Department of Chemistry, Wuhan University, Wuhan 430072 (China)]. E-mail: binhu@whu.edu.cn; Jiang Zucheng [Department of Chemistry, Wuhan University, Wuhan 430072 (China)

    2006-08-25

    A new method for the determination of inorganic Sb species by on-line cloud point extraction combined with electrothermal vaporization inductively coupled plasma atomic emission spectrometry (ETV-ICP-AES) is presented and evaluated. The method is based on the complexation of Sb(III) with pyrrolidine dithiocarbamate (PDC) which form an hydrophobic complex at pH 5.5 and subsequently enter surfactant-rich phase at pH 5.5, whereas Sb(V) remained in aqueous solutions. The preconcentration step is mediated by micelles of the non-ionic surfactant Triton X-114 with ammonium pyrrolidine dithiocarbamate (APDC). The micellar system containing the complex was loaded into the FIA manifold at a flow rate of 2.5 mL min{sup -1}, and the surfactant-rich phase was retained in a microcolumn packed with absorbent cotton, at pH 5.5. After the surfactant-rich phase was eluted with 100 {mu}L acetonitrile, it was determined by ETV-ICP-AES. Sb(V) is reduced to Sb(III) by L-cysteine prior to determined total Sb, and its assay is based on subtracting Sb(III) from total antimony. The main factors affecting separation/preconcentration and the vaporization behavior of analyte in graphite tube were investigated in detail. Under the optimized conditions, the precision relative standard deviation (R.S.D.) for eight replicate measurements of 0.2 {mu}g mL{sup -1} Sb(III) was 4.3%. The apparent concentration factor, which is defined as the concentration ratio of the analyte in the final diluted surfactant-rich extract ready for ETV-ICP-AES detection and in the initial solution, was 872 for Sb(III). The limit of detection (LOD) for Sb(III) was 0.09 {mu}g L{sup -1}. The proposed method was successfully applied for the speciation of inorganic antimony in different water samples and urine sample with satisfactory results.

  2. Ionic liquid-based zinc oxide nanofluid for vortex assisted liquid liquid microextraction of inorganic mercury in environmental waters prior to cold vapor atomic fluorescence spectroscopic detection.

    Science.gov (United States)

    Amde, Meseret; Liu, Jing-Fu; Tan, Zhi-Qiang; Bekana, Deribachew

    2016-01-01

    Zinc oxide nanofluid (ZnO-NF) based vortex assisted liquid liquid microextraction (ZnO-NF VA-LLME) was developed and employed in extraction of inorganic mercury (Hg(2+)) in environmental water samples, followed by cold vapor atomic fluorescence spectrometry (CV-AFS). Unlike other dispersive liquid liquid microextraction techniques, ZnO-NF VA-LLME is free of volatile organic solvents and dispersive solvent consumption. Analytical signals were obtained without back-extraction from the ZnO-NF phase prior to CV-AFS determination. Some essential parameters of the ZnO-NF VA-LLME and cold vapor generation such as composition and volume of the nanofluid, vortexing time, pH of the sample solution, amount of the chelating agent, ionic strength and matrix interferences have been studied. Under optimal conditions, efficient extraction of 1ng/mL of Hg(2+) in 10mL of sample solution was achieved using 50μL of ZnO-NF. The enrichment factor before dilution, detection limits and limits of quantification of the method were about 190, 0.019 and 0.064ng/mL, respectively. The intra and inter days relative standard deviations (n=8) were found to be 4.6% and 7.8%, respectively, at 1ng/mL spiking level. The accuracy of the current method was also evaluated by the analysis of certified reference materials, and the measured Hg(2+) concentration of GBW08603 (9.6ng/mL) and GBW(E)080392 (8.9ng/mL) agreed well with their certified value (10ng/mL). The method was applied to the analysis of Hg(2+) in effluent, influent, lake and river water samples, with recoveries in the range of 79.8-92.8% and 83.6-106.1% at 1ng/mL and 5ng/mL spiking levels, respectively. Overall, ZnO-NF VA-LLME is fast, simple, cost-effective and environmentally friendly and it can be employed for efficient enrichment of the analyte from various water samples.

  3. Theoretical investigation of lead vapor adsorption on kaolinite surfaces with DFT calculations

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xinye [Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 210096 (China); Huang, Yaji, E-mail: heyyj@seu.edu.cn [Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 210096 (China); Pan, Zhigang [College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009 (China); Wang, Yongxing; Liu, Changqi [Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 210096 (China)

    2015-09-15

    Highlights: • Al surface after dehydroxylation is active while Si surface is inert. • The active sites are the unsaturated Al atoms and O atoms losing H atom. • PbO is the most suitable species for adsorption. • Increasing the activities of Al atoms can enhance the performance of kaolinite. • Produce of amorphous silica is a potential path to enhance the performance of kaolinite. - Abstract: Kaolinite can be used as the in-furnace sorbent/additive to adsorb lead (Pb) vapor at high temperature. In this paper, the adsorptions of Pb atom, PbO molecule and PbCl{sub 2} molecule on kaolinie surfaces were investigated by density functional theory (DFT) calculation. Si surface is inert to Pb vapor adsorption while Al surfaces with dehydroxylation are active for the unsaturated Al atoms and the O atoms losing H atoms. The adsorption energy of PbO is much higher than that of Pb atom and PbCl{sub 2}. Considering the energy barriers, it is easy for PbO and PbCl{sub 2} to adsorb on Al surfaces but difficult to escape. The high energy barriers of de–HCl process cause the difficulties of PbCl{sub 2} to form PbO·Al{sub 2}O{sub 3}·2SiO{sub 2} with kaolinite. Considering the inertia of Si atoms and the activity of Al atoms after dehydroxylation, calcination, acid/alkali treatment and some other treatment aiming at amorphous silica producing and Al activity enhancement can be used as the modification measures to improve the performance of kaolinite as the in-furnace metal capture sorbent.

  4. Calculation of Radiative Corrections to E1 matrix elements in the Neutral Alkalis

    Energy Technology Data Exchange (ETDEWEB)

    Sapirstein, J; Cheng, K T

    2004-09-28

    Radiative corrections to E1 matrix elements for ns-np transitions in the alkali metal atoms lithium through francium are evaluated. They are found to be small for the lighter alkalis but significantly larger for the heavier alkalis, and in the case of cesium much larger than the experimental accuracy. The relation of the matrix element calculation to a recent decay rate calculation for hydrogenic ions is discussed, and application of the method to parity nonconservation in cesium is described.

  5. Absorption spectra of alkali-C₆₀ nanoclusters.

    Science.gov (United States)

    Rabilloud, Franck

    2014-10-28

    We investigate the absorption spectra of alkali-doped C60 nanoclusters, namely C60Nan, C60Kn, and C60Lin, with n = 1, 2, 6, 12, in the framework of the time-dependent density-functional theory (TDDFT). We study the dependence of the absorption spectra on the nature of the alkali. We show that in few cases the absorption spectra depend on the arrangement of the alkali atoms over the fullerene, though sometimes the absorption spectra do not allow us to distinguish between different configurations. When only one or two alkali atoms are adsorbed on the fullerene, the optical response of alkali-doped C60 is similar to that of the anion C60(-) with a strong response in the UV domain. In contrast, for higher concentration of alkali, a strong optical response is predicted in the visible range, particularly when metal-metal bonds are formed. The weak optical response of the I(h)-symmetry C60Li12 is proposed to be used as a signature of its structure.

  6. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    Energy Technology Data Exchange (ETDEWEB)

    Gordon, John Howard

    2014-09-09

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  7. Determination of thiomersal by flow injection coupled with microwave-assisted photochemical online oxidative decomposition of organic mercury and cold vapor atomic fluorescence spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Campanella, Beatrice; Onor, Massimo; Mascherpa, Marco Carlo; D’Ulivo, Alessandro [National Research Council of Italy, C.N.R., Istituto di Chimica dei Composti Organo Metallici-ICCOM-UOS Pisa, Area di Ricerca, Via G. Moruzzi 1, 56124 Pisa (Italy); Ferrari, Carlo [National Research Council of Italy, C.N.R., Istituto Nazionale di Ottica, INO–UOS Pisa, Area di Ricerca, Via G. Moruzzi 1, 56124 Pisa (Italy); Bramanti, Emilia, E-mail: bramanti@pi.iccom.cnr.it [National Research Council of Italy, C.N.R., Istituto di Chimica dei Composti Organo Metallici-ICCOM-UOS Pisa, Area di Ricerca, Via G. Moruzzi 1, 56124 Pisa (Italy)

    2013-12-04

    Graphical abstract: -- Highlights: •Thiomersal was determined on line using FI-MW/UV-CVGAFS. •MW/UV allows a “green” on line oxidation of organic mercury to Hg{sup II}. •Each measure requires less than 5 min with a LOD of 3 ng mL{sup −1} (as mercury). •Hg concentration in commercial ophthalmic solutions ranges between 7.5 and 59.0 μg mL{sup −1}. -- Abstract: We developed a flow injection (FI) method for the determination of thiomersal (sodium ethylmercurithiosalicylate, C{sub 9}H{sub 9}HgNaO{sub 2}S) based on the UV/microwave (MW) photochemical, online oxidation of organic mercury, followed by cold vapor generation atomic fluorescence spectrometry (CVG-AFS) detection. Thiomersal was quantitatively converted in the MW/UV process to Hg(II), with a yield of 97 ± 3%. This reaction was followed by the reduction of Hg(II) to Hg(0) performed in a knotted reaction coil with NaBH{sub 4} solution, and AFS detection in an Ar/H{sub 2} miniaturized flame. The method was linear in the 0.01–2 μg mL{sup −1} range, with a LOD of 0.003 μg mL{sup −1}. This method has been applied to the determination of thiomersal in ophthalmic solutions, with recoveries ranging between 97% and 101%. We found a mercury concentration in commercial ophthalmic solutions ranging between 7.5 and 59.0 μg mL{sup −1}.

  8. Development of a method for total Hg determination in oil samples by cold vapor atomic absorption spectrometry after its extraction induced by emulsion breaking.

    Science.gov (United States)

    Vicentino, Priscila de O; Brum, Daniel M; Cassella, Ricardo J

    2015-01-01

    This work reports the development of a novel extraction method for total Hg determination in oil samples. After extracting Hg from samples it was quantified in the extracts by cold vapor atomic absorption spectrometry (CV-AAS), employing a laboratory-made gas-liquid separator (GLS) and NaBH4 as reducing agent. The extraction of Hg from samples was carried out by extraction induced by emulsion breaking (EIEB), which is based on the formation and breaking of water-in-oil emulsion between the oil samples and an extractant solution containing an emulsifying agent (surfactant) and nitric acid. Operational parameters of the GLS were evaluated in order to set the best performance of the measurement system. In these studies it was proven that the volume of sample and the concentration of HCl added to the sample extracts had significant influence on Hg response. The best conditions were achieved by adding 0.5 mL of a 0.3 mol L(-1) HCl solution on 1 mL of sample extract. The extraction conditions were also optimized. The highest efficiency was observed when 4 mL of a solution containing 2.5% triton X-100 and 15% v/v HNO3 were employed for the extraction of Hg contained in 20 mL of sample. Emulsion breaking was performed by heating at 80 °C and took approximately 20 min. The limit of quantification of the method was 1.9 µg L(-1) and recovery percentages between 80% and 103% were observed when spiked samples (2 and 10 µg L(-1)) of diesel oil, biodiesel and mineral oil were analyzed.

  9. Methylmercury in water samples at the pg/L level by online preconcentration liquid chromatography cold vapor-atomic fluorescence spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Brombach, Christoph-Cornelius [Trace Element Speciation Laboratory, Department of Chemistry, Meston Walk, University of Aberdeen, Aberdeen AB24 3UE (United Kingdom); Chen, Bin; Corns, Warren T. [PS Analytical, Arthur House, Crayfields Industrial Estate, Main Road, Orpington, Kent BR5 3HP (United Kingdom); Feldmann, Jörg [Trace Element Speciation Laboratory, Department of Chemistry, Meston Walk, University of Aberdeen, Aberdeen AB24 3UE (United Kingdom); Krupp, Eva M., E-mail: e.krupp@abdn.ac.uk [Trace Element Speciation Laboratory, Department of Chemistry, Meston Walk, University of Aberdeen, Aberdeen AB24 3UE (United Kingdom)

    2015-03-01

    Ultra-traces of methylmercury at the sub-ppt level can be magnified in the foodweb and is of concern. In environmental monitoring a routine robust analytical method is needed to determine methylmercury in water. The development of an analytical method for ultra-trace speciation analysis of methylmercury (MeHg) in water samples is described. The approach is based on HPLC-CV-AFS with on-line preconcentration of water samples up to 200 mL, resulting in a detection limit of 40 pg/L (ppq) for MeHg, expressed as Hg. The unit consists of an optimized preconcentration column filled with a sulfur-based sorption material, on which mercury species are preconcentrated and subsequently eluted, separated and detected via HPLC-CV-AFS (high performance liquid chromatography–cold vapor atomic fluorescence spectrometry). During the method development a type of adsorbate material, the pH dependence, the sample load rate and the carry-over were investigated using breakthrough experiments. The method shows broad pH stability in the range of pH 0 to 7, without the need for buffer addition and shows limited matrix effects so that MeHg is quantitatively recovered from sewage, river and seawater directly in the acidified samples without sample preparation. - Highlights: • We demonstrate that a novel mixture of thiourea-thiolsilica shows an excellent trapping of MeHg between a broad pH range 1–6. • We develop the method so that it can potentially be automated for inorganic and methyl-mercury. • The method is matrix independent with highly accurate results for MeHg in hair CRM extracts and spiked water samples • The limit of detection is around 40 pg/L when just 200 mL sample is used, without any intensive preparation.

  10. Environmental site description for a Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) production plant at the Portsmouth Gaseous Diffusion Plant site

    Energy Technology Data Exchange (ETDEWEB)

    Marmer, G.J.; Dunn, C.P.; Filley, T.H.; Moeller, K.L.; Pfingston, J.M.; Policastro, A.J.; Cleland, J.H.

    1991-09-01

    Uranium enrichment in the United States has utilized a diffusion process to preferentially enrich the U-235 isotope in the uranium product. In the 1970s, the US Department of Energy (DOE) began investigating more efficient and cost-effective enrichment technologies. In January 1990, the Secretary of Energy approved a plan for the demonstration and deployment of the Uranium Atomic Vapor Laser isotope Separation (U-AVLIS) technology with the near-term goal to provide the necessary information to make a deployment decision by November 1992. Initial facility operation is anticipated for 1999. A programmatic document for use in screening DOE sites to locate a U-AVLIS production plant was developed and implemented in two parts. The first part consisted of a series of screening analyses, based on exclusionary and other criteria, that identified a reasonable number of candidate sites. The final evaluation, which included sensitivity studies, identified the Oak Ridge Gaseous Diffusion Plant (ORGDP) site, the Paducah Gaseous Diffusion Plant (PGDP) site, and the Portsmouth Gaseous Diffusion Plant (PORTS) site as having significant advantages over the other sites considered. This environmental site description (ESD) provides a detailed description of the PORTS site and vicinity suitable for use in an environmental impact statement (EIS). This report is based on existing literature, data collected at the site, and information collected by Argonne National Laboratory (ANL) staff during site visits. The organization of the ESD is as follows. Topics addressed in Sec. 2 include a general site description and the disciplines of geology, water resources, biotic resources, air resources, noise, cultural resources, land use. Socioeconomics, and waste management. Identification of any additional data that would be required for an EIS is presented in Sec. 3.

  11. Communication: Dopant-induced solvation of alkalis in liquid helium nanodroplets

    Science.gov (United States)

    Renzler, Michael; Daxner, Matthias; Kranabetter, Lorenz; Kaiser, Alexander; Hauser, Andreas W.; Ernst, Wolfgang E.; Lindinger, Albrecht; Zillich, Robert; Scheier, Paul; Ellis, Andrew M.

    2016-11-01

    Alkali metal atoms and small alkali clusters are classic heliophobes and when in contact with liquid helium they reside in a dimple on the surface. Here we show that alkalis can be induced to submerge into liquid helium when a highly polarizable co-solute, C60, is added to a helium nanodroplet. Evidence is presented that shows that all sodium clusters, and probably single Na atoms, enter the helium droplet in the presence of C60. Even clusters of cesium, an extreme heliophobe, dissolve in liquid helium when C60 is added. The sole exception is atomic Cs, which remains at the surface.

  12. Relationships among equivalent oxide thickness, nanochemistry, and nanostructure in atomic layer chemical-vapor-deposited Hf-O films on Si

    Science.gov (United States)

    Dey, S. K.; Das, A.; Tsai, M.; Gu, D.; Floyd, M.; Carpenter, R. W.; De Waard, H.; Werkhoven, C.; Marcus, S.

    2004-05-01

    The relationships among the equivalent oxide thickness (EOT), nanochemistry, and nanostructure of atomic layer chemical-vapor-deposited (ALCVD) Hf-O-based films, with oxide and nitrided oxide interlayers on Si substrates, were studied using x-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (HRTEM), scanning transmission electron microscopy (STEM) in annular dark-field imaging (ADF), and parallel electron energy-loss spectroscopy (PEELS), capacitance-voltage, and leakage-current-voltage measurements. The XPS (Hf 4f binding energy shift) studies indicated the formation of Hf-O-Si bonds in as-deposited amorphous films, the amount of which was influenced by the interlayer composition and annealing conditions. After post-deposition annealing in N2 and O2, the Hf-O layers were nanocrystalline. Although HRTEM images showed a structurally sharp interface between the Hf-O layer and the interlayer, angle-resolved XPS, ADF imaging, and PEELS in the STEM revealed a chemically diffused HfSiOx region in between. This interdiffusion was observed by the detection of Si (using Si L edge) and Hf (using Hf O2,3 edge) in the Hf-O layer and the interlayer. For an annealed Hf-O/interlayer stack, with an ALCVD target thickness of 4.0 nm for the Hf-O layer on 1.2 nm of nitrided chemical oxide, the experimentally measured EOT and leakage current (at -1 V) were 1.52 nm and ˜10-8 A/cm2. A three-layer (1.2 nm interlayer of nitrided chemical oxide/compositionally graded, 2 nm region of HfSiOx/2 nm HfO2 layer) capacitor model was used to determine the respective contributions to the measured EOT, and the dielectric permittivity of the interlayer was found to be 6.06. These studies clearly indicate that a total EOT of 1 nm and below is attainable in the Hf-N-O-Si/Si-N-O system.

  13. Evaluation of the effect of 16% carbamide peroxide gel (Nite White on mercury release from Iranian and foreign spherical and admixed amalgams by cold vapor atomic absorption method

    Directory of Open Access Journals (Sweden)

    Kasraie Sh.

    2008-04-01

    Full Text Available Background and Aim: Nowadays, esthetic dentistry has become an important part of modern dentistry. Bleaching is considered as a conservative, safe and effective way for treatment of discolored teeth. Although bleaching is commonly used on anterior teeth, the bleaching gel may come into contact with patient's former amalgam restorations and result in corrosive effects, dissolution of amalgam phases and increasing release of mercury. Mercury released from dental amalgam during mouthguard bleaching can be absorbed and increase the total mercury body burden. The aim of this study was to determine the amount of mercury released from Iranian and foreign brands of amalgams with spherical and admixed particles, polished and unpolished, after 16%carbamide peroxide gel application.Materials and Methods: This experimental in vitro study was performed on 256 Iranian and foreign amalgam samples with spherical and admixed particles. The provided samples were put in distilled water and classified according to the type of amalgam, shape of particles and quality of surface polishing. The test samples were placed in Nite White 16% carbamid peroxide gel and control samples were put in phosphate buffer (Ph=6.5 for 14 and 28 hours. The amount of released mercury was calculated using AVA-440 Mercury Analysis System (Thermo Jarrell Ash model SH/229 with cold-vapor atomic absorption. Data were analyzed using t-test, four way and three way ANOVA tests with P<0.05 as the level of significance.Results: 16% Nite White carbamide peroxide gel caused a significant increase in amount of mercury released from amalgams in all groups (P<0.05. Mercury release from Iranian amalgam was higher than that from the foreign brands (P<0.05. There was no significant difference in mercury released from spherical and admixed amalgams (P>0.05. The amount of mercury released from Iranian and foreign amalgams was time dependent (P<0.05. Furthermore, the amount of mercury released from

  14. Improvement of a polarized alkali ion source by means of optical pumping

    Energy Technology Data Exchange (ETDEWEB)

    Dreves, W.; Koch, E.; Jaensch, H.; Kamke, W.; Broermann, W.; Fick, D.

    1982-01-01

    A source for polarized alkali ions can be improved considerably by optical pumping of the atom beam in combination with a modified weak field transition. M-level populations were investigated using laser induced fluorescence in a magnetic field.

  15. The calcium-alkali syndrome

    OpenAIRE

    Arroyo, Mariangeli; Fenves, Andrew Z.; Emmett, Michael

    2013-01-01

    The milk-alkali syndrome was a common cause of hypercalcemia, metabolic alkalosis, and renal failure in the early 20th century. It was caused by the ingestion of large quantities of milk and absorbable alkali to treat peptic ulcer disease. The syndrome virtually vanished after introduction of histamine-2 blockers and proton pump inhibitors. More recently, a similar condition called the calcium-alkali syndrome has emerged as a common cause of hypercalcemia and alkalosis. It is usually caused b...

  16. Use of precalciners to remove alkali from raw materials in the cement industry. Final report, July 1978-July 1980

    Energy Technology Data Exchange (ETDEWEB)

    Gartner, E.M.

    1980-07-01

    The objective of this work was to develop an efficient means of removing alkali metal compounds (alkalies) from high-alkali aluminosilicate raw materials of the type commonly used as part of cement raw mixes in order to increase the energy efficiency of cement manufacture. The intention of this project was to determine whether the high-alkali raw materials could be pyroprocessed separately to remove the alkalies before they entered the rotary kiln, where they would be mixed with the other raw feed components. If this could be achieved, considerable savings could be made in the energy required to remove alkalies, compared to conventional methods in which the cement raw mix must be treated as a whole. Two different methods of alkali removal were examined, namely, vaporization of alkalies at relatively low temperatures; and alkali-rich melt separation at relativey high temperatures. The results showed that the removal of alkalies by pyroprocessing of high-alkali raw feed components separate from the other cement raw mix components is not likely to be a practical alternative to the best available conventional precalciner technology. (LCL)

  17. Adding nickel formate in alkali lignin to increase contents of alkylphenols and aromatics during fast pyrolysis.

    Science.gov (United States)

    Geng, Jing; Wang, Wen-Liang; Yu, Yu-Xiang; Chang, Jian-Min; Cai, Li-Ping; Shi, Sheldon Q

    2017-03-01

    The composition of pyrolysis vapors obtained from alkali lignin pyrolysis with the additive of nickel formate was examined using the pyrolysis gas chromatography-mass spectrometry (Py-GC/MS). Characterization of bio-chars was performed using X-ray diffraction (XRD). Results showed that the nickel formate significantly increased liquid yield, simplified the types of alkali lignin pyrolysis products and increased individual component contents. The additive of nickel formate increased contents of alkylphenols and aromatics from alkali lignin pyrolysis. With an increase in temperature, a greater amount of the relative contents can be achieved. The nickel formate was thermally decomposed to form hydrogen, resulting in hydrodeoxygenation of alkali lignin during pyrolysis. It was also found that Ni is in favor of producing alkylphenols. The analysis based on the experimental result provided evidences used to propose reaction mechanism for pyrolysis of nickel formate-assisted alkali lignin.

  18. Efficient potassium diode pumped alkali laser operating in pulsed mode.

    Science.gov (United States)

    Zhdanov, Boris V; Rotondaro, Matthew D; Shaffer, Michael K; Knize, Randall J

    2014-07-14

    This paper presents the results of our experiments on the development of an efficient hydrocarbon free diode pumped alkali laser based on potassium vapor buffered by He gas at 600 Torr. A slope efficiency of more than 50% was demonstrated with a total optical conversion efficiency of 30%. This result was achieved by using a narrowband diode laser stack as the pump source. The stack was operated in pulsed mode to avoid limiting thermal effects and ionization.

  19. Natural Alkali Shifts to the Methanol Business

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    @@ Inner Mongolia Yuanxing Natural Alkali Co., Ltd. (Natural Alkali SZ: 000683) established in 1997 is a large chemical enterprise with new energy as its leading business and natural gas chemicals and natural alkali chemicals as the supplement business.

  20. Field emission properties of capped carbon nanotubes doped by alkali metals:a theoretical investigation

    Institute of Scientific and Technical Information of China (English)

    Jin Lei; Fu Hong-Gang; Xie Ying; Yu Hai-Tao

    2012-01-01

    The electronic structures and field emission properties of capped CNT55 systems with or without alkali metal atom adsorption were systematically investigated by density functional theory calculation.The results indicate that the adsorption of alkali metal on the center site of a CNT tip is energetically favorable.In addition,the adsorption energies increase with the introduction of the electric field.The excessive negative charges on CNT tips make electron emittance much easier and result in a decrease in work function.Furthermore,the inducing effect by positively charged alkali metal atoms can be reasonably considered as the dominant reason for the improvement in field emission properties.

  1. Valence photoelectron spectra of alkali bromides calculated within the propagator theory

    DEFF Research Database (Denmark)

    Karpenko, Alexander; Iablonskyi, Denys; Aksela, Helena

    2013-01-01

    The valence ionization spectra covering the binding energy range 0-45 eV of alkali bromide XBr (X = Li, Na, K, Rb) vapors are studied within the framework of the propagator theory. Relativistic Algebraic Diagrammatic Construction calculations have been carried out in order to investigate photoion......The valence ionization spectra covering the binding energy range 0-45 eV of alkali bromide XBr (X = Li, Na, K, Rb) vapors are studied within the framework of the propagator theory. Relativistic Algebraic Diagrammatic Construction calculations have been carried out in order to investigate...

  2. THE STRUCTURES AND HYDROGEN STORAGE PROPERTIES OF ALKALI METAL LITHIUM DECORATED ON THE END OF THE SILICON ATOMIC CHAIN CLUSTERS%碱金属锂原子修饰硅原子链团簇的结构和储氢性能

    Institute of Scientific and Technical Information of China (English)

    吴永恒; 蔡余峰; 曾华东; 阮文

    2015-01-01

    采用密度泛函理论(DFT)方法研究Li2Sim(m=2,4,6)链状团簇结构及其储氢性能。研究结果表明,氢分子在碱金属Li原子修饰的三种硅链结构中均发生吸附,并且每个Li原子都可以吸附多个氢分子,其中两个Li原子修饰Si2链的结构能够吸附氢分子的储氢质量分数达18.6 wt %,氢分子的平均吸附能为1.850 kcal/moL。结果表明,碱金属Li原子修饰的硅链在室温条件下可作为氢气的存储媒介。%The structures and the hydrogen storage properties of the alkali metallithium decorated the linear silicon atomic chainsclusters are investigated by using the density functional theory. The results show that the lithium atoms can decorate on the end of thesilicon atomic chain clusters but not suffer from clustering. Every Li atom can absorb up to several intact hydrogen molecules in the Li-decoratedsilicon atomic chainsLi2Sim (m=2, 4, 6) clusters. The calculated gravimetric density of hydrogen for Li-decorated the Si2chain cluster is up to 18.6 wt%, and the hydrogen average adsorption energy is 1.850 kcal.mol-1, which shows that the Li-decoratedsilicon atomic chainscan be used as hydrogen storage materials under the room temperature condition.

  3. Alkali metal and alkali earth metal gadolinium halide scintillators

    Energy Technology Data Exchange (ETDEWEB)

    Bourret-Courchesne, Edith; Derenzo, Stephen E.; Parms, Shameka; Porter-Chapman, Yetta D.; Wiggins, Latoria K.

    2016-08-02

    The present invention provides for a composition comprising an inorganic scintillator comprising a gadolinium halide, optionally cerium-doped, having the formula A.sub.nGdX.sub.m:Ce; wherein A is nothing, an alkali metal, such as Li or Na, or an alkali earth metal, such as Ba; X is F, Br, Cl, or I; n is an integer from 1 to 2; m is an integer from 4 to 7; and the molar percent of cerium is 0% to 100%. The gadolinium halides or alkali earth metal gadolinium halides are scintillators and produce a bright luminescence upon irradiation by a suitable radiation.

  4. Alkali-helium snowball complexes formed on helium nanodroplets.

    Science.gov (United States)

    Müller, S; Mudrich, M; Stienkemeier, F

    2009-07-28

    We systematically investigate the formation and stability of snowballs formed by femtosecond photoionization of small alkali clusters bound to helium nanodroplets. For all studied alkali species Ak = (Na,K,Rb,Cs) we observe the formation of snowballs Ak(+)He(N) when multiply doping the droplets. Fragmentation of clusters Ak(N) upon ionization appears to enhance snowball formation. In the case of Na and Cs we also detect snowballs Ak(2) (+)He(N) formed around Ak dimer ions. While the snowball progression for Na and K is limited to less than 11 helium atoms, the heavier atoms Rb and Cs feature wide distributions at least up to Ak(+)He(41). Characteristic steps in the mass spectra of Cs-doped helium droplets are found at positions consistent with predictions on the closure of the first shell of helium atoms around the Ak(+) ion based on variational Monte Carlo simulations.

  5. Real-Time Monitoring of Atom Vapor Concentration With Laser Absorption Spectroscopy%激光吸收光谱法实时监测原子蒸气密度

    Institute of Scientific and Technical Information of China (English)

    范凤英; 高鹏; 江涛

    2012-01-01

    采用固体激光器泵浦环形染料激光器作为光源,通过激光吸收光谱法对钆原子蒸气密度进行实时监测.应用光纤远距离传输提高光路稳定性,采用多步吸收光程技术,并引入参考光消除激光功率不稳定因素影响.实验结果表明:采用该方法建立的原子蒸气密度实时监测系统标准误差约为4%,可为激光同位素分离过程提供可靠数据,从而提高分离效率.%The technology of laser absorption spectroscopy was used for real-time monitoring of gadolinium atom vapor concentration measurement and the solid state laser pumped ring dye laser was used as optical source. The optical fiber was taken to improve the stability of laser transmission. The multi-pass absorption technology combined with reference optical signal avoided the influence of laser power fluctuation. The experiment result shows that the system based on this detection method has a standard error of 4%. It is proved that the monitoring system provides reliable data for atom vapor laser isotope separation process and the separation efficiency can be improved.

  6. Low-frequency Raman scattering in alkali tellurite glasses

    Indian Academy of Sciences (India)

    Angelos G Kalampounias

    2008-10-01

    Raman scattering has been employed to study the alkali-cation size dependence and the polarization characteristics of the low-frequency modes for the glass-forming tellurite mixtures, 0.1M2O–0.9TeO2 (M = Na, K, Rb and Cs). The analysis has shown that the Raman coupling coefficient alters by varying the type of the alkali cation. The addition of alkali modifier in the tellurite network leads to the conversion of the TeO4 units to TeO3 units with a varying number of non-bridging oxygen atoms. Emphasis has also been given to the lowfrequency modes and particular points related to the low-frequency Raman phenomenology are discussed in view of the experimental findings.

  7. Path integral Monte Carlo study of 4He clusters doped with alkali and alkali-earth ions.

    Science.gov (United States)

    Galli, D E; Ceperley, D M; Reatto, L

    2011-06-30

    Path integral Monte Carlo calculations of (4)He nanodroplets doped with alkali (Na(+), K(+) and Cs(+)) and alkali-earth (Be(+) and Mg(+)) ions are presented. We study the system at T = 1 K and between 14 and 128 (4)He atoms. For all studied systems, we find that the ion is well localized at the center of the droplet with the formation of a "snowball" of well-defined shells of localized (4)He atoms forming solid-like order in at least the first surrounding shell. The number of surrounding helium shells (two or three) and the number of atoms per shell and the degree of localization of the helium atoms are sensitive to the type of ion. The number of (4)He atoms in the first shell varies from 12 for Na(+) to 18 for Mg(+) and depends weakly on the size of the droplet. The study of the density profile and of the angular correlations shows that the local solid-like order is more pronounced for the alkali ions with Na(+) giving a very stable icosahedral order extending up to three shells.

  8. Density functional theory based screening of ternary alkali-transition metal borohydrides: A computational material design project

    DEFF Research Database (Denmark)

    Hummelshøj, Jens Strabo; Landis, David; Voss, Johannes

    2009-01-01

    We present a computational screening study of ternary metal borohydrides for reversible hydrogen storage based on density functional theory. We investigate the stability and decomposition of alloys containing 1 alkali metal atom, Li, Na, or K (M1); and 1 alkali, alkaline earth or 3d/4d transition...

  9. Upgrading platform using alkali metals

    Energy Technology Data Exchange (ETDEWEB)

    Gordon, John Howard

    2017-01-17

    A method for removing sulfur, nitrogen or metals from an oil feedstock. The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

  10. Upgrading platform using alkali metals

    Energy Technology Data Exchange (ETDEWEB)

    Gordon, John Howard

    2014-09-09

    A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

  11. Light shift averaging in paraffin-coated alkali vapor cells

    CERN Document Server

    Zhivun, Elena; Sudyka, Julia; Pustelny, Szymon; Patton, Brian; Budker, Dmitry

    2015-01-01

    Light shifts are an important source of noise and systematics in optically pumped magnetometers. We demonstrate that the long spin coherence time in paraffin-coated cells leads to spatial averaging of the light shifts over the entire cell volume. This renders the averaged light shift independent, under certain approximations, of the light-intensity distribution within the sensor cell. These results and the underlying mechanism can be extended to other spatially varying phenomena in anti-relaxation-coated cells with long coherence times.

  12. Propagation of Gaussian Schell-model beam in electromagnetically induced transparency atomic vapor%高斯谢尔模型光束在EIT原子气体中的传输特性研究

    Institute of Scientific and Technical Information of China (English)

    许森东; 徐弼军; 陆璇辉

    2013-01-01

    为了研究高斯-谢尔模型(GSM)光束在电磁感应透明(EIT)材料中的传输特性,利用矩阵光学理论、衍射积分理论、相干偏振统一理论推导了GSM光束通过EIT材料的传输交叉谱密度方程的解析表达式。该表达式可以用于计算和研究GSM光束通过EIT原子气体的谱密度和相干度的变化。分析显示GSM光束的谱密度和相干度都可以通过控制光的拉比频率调控。此研究结果提供了一种新的调控光传输的方法和技术,同时该发现也为控制部分相干光的谱密度和相干度提供了一种新方法。%In order to study the propagation characteristics of Gaussian Schell-model (GSM) beams in electromagnetically induced transparency atomic vapor, the analytical expression was obtained for the cross-spectral density function of a Gaussian Schell-model beam passing through the electromagnetically induced transparency atomic vapor based on the matrix optics theory, diffraction integral theory and unified theory of coherence and polarization. The formula can be used in the study of the changes in the spectral density and spectral degree of coherence of the beam through the EIT atomic vapor. Numerical examples show that both the spectral density and the spectral degree of coherence of the GSM beam can be modulated by the Rabi frequency of the control light. The results have been provided a new method and technique for modulation the beam propagation. The findings indicate a new technique for controlling the spectral density and the spectral degree of coherence of the partially coherent light beam.

  13. Vapor Bubbles

    Science.gov (United States)

    Prosperetti, Andrea

    2017-01-01

    This article reviews the fundamental physics of vapor bubbles in liquids. Work on bubble growth and condensation for stationary and translating bubbles is summarized and the differences with bubbles containing a permanent gas stressed. In particular, it is shown that the natural frequency of a vapor bubble is proportional not to the inverse radius, as for a gas bubble, but to the inverse radius raised to the power 2/3. Permanent gas dissolved in the liquid diffuses into the bubble with strong effects on its dynamics. The effects of the diffusion of heat and mass on the propagation of pressure waves in a vaporous bubbly liquid are discussed. Other topics briefly touched on include thermocapillary flow, plasmonic nanobubbles, and vapor bubbles in an immiscible liquid.

  14. Is electronegativity a useful descriptor for the pseudo-alkali metal NH4?

    Science.gov (United States)

    Whiteside, Alexander; Xantheas, Sotiris S; Gutowski, Maciej

    2011-11-18

    Molecular ions in the form of "pseudo-atoms" are common structural motifs in chemistry, with properties that are transferrable between different compounds. We have determined one such property--the electronegativity--for the "pseudo-alkali metal" ammonium (NH(4)), and evaluated its reliability as a descriptor versus the electronegativities of the alkali metals. The computed properties of ammonium's binary complexes with astatine and of selected borohydrides confirm the similarity of NH(4) to the alkali metal atoms, although the electronegativity of NH(4) is relatively large in comparison to its cationic radius. We have paid particular attention to the molecular properties of ammonium (angular anisotropy, geometric relaxation and reactivity), which can cause deviations from the behaviour expected of a conceptual "true alkali metal" with this electronegativity. These deviations allow for the discrimination of effects associated with the molecular nature of NH(4).

  15. Alkali-metal-supported bismuth polyhedra-principles and theoretical studies.

    Science.gov (United States)

    Monakhov, Kirill Yu; Linti, Gerald; Wolters, Lando P; Bickelhaupt, F Matthias

    2011-06-20

    We have quantum chemically investigated the structure, stability, and bonding mechanism in highly aggregated alkali-metal salts of bismuthanediide anions [RBi](2-) using relativistic density functional theory (DFT, at ZORA-BP86/TZ2P) in combination with a quantitative energy decomposition analysis (EDA). Our model systems are alkali-metal-supported bismuth polyhedra [(RBi)(n)M(2n-4)](4-) with unique interpenetrating shells of a bismuth polyhedron and an alkali-metal superpolyhedron. Furthermore, we have analyzed the trianionic inclusion complexes [M'@{(RBi)(n)M(2n-4)}](3-) involving an additional endohedral alkali-metal ion M'. The main objective is to assist the further development of synthetic approaches toward this class of compounds. Our analyses led to electron-counting rules relating, for example, the number of bonding orbitals (N(bond)) of the cage molecules [(RBi)(n)M(2n+Q)](Q) to the number of bismuth atoms (n(Bi)), alkali-metal atoms (n(M)), and net charge Q as N(bond) = n(Bi) + n(M) - Q (R = one-electron donor ligand; M = alkali metal; n = 4-12; Q = -4, -6, -8). Finally, on the basis of our findings, we predict the next members in the 5-fold symmetrical row of alkali-metallobismaspheres with a macroicosahedral arrangement.

  16. Calculated Pressure Induced BCC-FCC Phase Transitions in Alkali Metals

    OpenAIRE

    DAĞISTANLI, Hamdi; MUTLU, R. Haluk

    2008-01-01

    The partial occupation numbers and density of states (DOS), and the total DOS at the Fermi level are calculated as a function of reduced atomic volume for bcc and fcc alkali metals employing the linear-muffin-tin-orbital (LMTO) method. By means of the abrupt changes obtained in the partial and total DOS values at the Fermi level, good agreement with regard to experiment were found in predicting the bcc-fcc transition volumes of the alkali metals.

  17. Alkali and heavy metal emissions of the PCFB-process; Alkali- ja raskasmetallipaeaestoet PCFB-prosessista

    Energy Technology Data Exchange (ETDEWEB)

    Kuivalainen, R.; Eriksson, T.; Lehtonen, P. [Foster Wheeler Energia Oy, Karhula (Finland)

    1997-10-01

    Pressurized Circulating Fluidized Bed (PCFB) combustion technology has been developed in Karhula R and D Center since 1986. As part of the development, 10 MW PCFB test facility was built in 1989. The test facility has been used for performance testing with different coal types through the years 1990-1995 in order to gain data for design and commercialization of the high-efficiency low-emission PCFB combustion technology. The main object of the project was to measure vapor phase Na and K concentrations in the PCFB flue gas after hot gas filter and investigate the effects of process conditions and sorbents on alkali release. The measurements were performed using plasma assisted method of TUT Laboratory of Plasma Technology and wet absorption method of VTT Energy. The measurements were carried out during three test campaigns at PCFB Test Facility in Karhula. In autumn 1995 both VTT and TUT methods were used. The measurements of the following test period in spring 1996 were performed by VTT, and during the last test segment in autumn 1996 TUT method was in use. During the last test period, the TUT instrument was used as semi-continuous (3 values/minute) alkali analyzer for part of the time. The measured Na concentrations were below 30 ppb(w) in all measured data points. The results of K were below 10 ppb(w). The accuracies of the both methods are about +50 % at this concentration range. The scatter of the data covers the effects of different process variables on the alkali emission. The measured emissions are at the same order of magnitude as the guideline emission limits estimated by gas turbine manufacturers

  18. Optical atomic magnetometer

    Science.gov (United States)

    Budker, Dmitry; Higbie, James; Corsini, Eric P

    2013-11-19

    An optical atomic magnetometers is provided operating on the principles of nonlinear magneto-optical rotation. An atomic vapor is optically pumped using linearly polarized modulated light. The vapor is then probed using a non-modulated linearly polarized light beam. The resulting modulation in polarization angle of the probe light is detected and used in a feedback loop to induce self-oscillation at the resonant frequency.

  19. PMMA-Etching-Free Transfer of Wafer-scale Chemical Vapor Deposition Two-dimensional Atomic Crystal by a Water Soluble Polyvinyl Alcohol Polymer Method

    Science.gov (United States)

    van Ngoc, Huynh; Qian, Yongteng; Han, Suk Kil; Kang, Dae Joon

    2016-09-01

    We have explored a facile technique to transfer large area 2-Dimensional (2D) materials grown by chemical vapor deposition method onto various substrates by adding a water-soluble Polyvinyl Alcohol (PVA) layer between the polymethyl-methacrylate (PMMA) and the 2D material film. This technique not only allows the effective transfer to an arbitrary target substrate with a high degree of freedom, but also avoids PMMA etching thereby maintaining the high quality of the transferred 2D materials with minimum contamination. We applied this method to transfer various 2D materials grown on different rigid substrates of general interest, such as graphene on copper foil, h-BN on platinum and MoS2 on SiO2/Si. This facile transfer technique has great potential for future research towards the application of 2D materials in high performance optical, mechanical and electronic devices.

  20. IRMPD action spectroscopy of alkali metal cation-cytosine complexes: effects of alkali metal cation size on gas phase conformation.

    Science.gov (United States)

    Yang, Bo; Wu, R R; Polfer, N C; Berden, G; Oomens, J; Rodgers, M T

    2013-10-01

    The gas-phase structures of alkali metal cation-cytosine complexes generated by electrospray ionization are probed via infrared multiple photon dissociation (IRMPD) action spectroscopy and theoretical calculations. IRMPD action spectra of five alkali metal cation-cytosine complexes exhibit both similar and distinctive spectral features over the range of ~1000-1900 cm(-1). The IRMPD spectra of the Li(+)(cytosine), Na(+)(cytosine), and K(+)(cytosine) complexes are relatively simple but exhibit changes in the shape and shifts in the positions of several bands that correlate with the size of the alkali metal cation. The IRMPD spectra of the Rb(+)(cytosine) and Cs(+)(cytosine) complexes are much richer as distinctive new IR bands are observed, and the positions of several bands continue to shift in relation to the size of the metal cation. The measured IRMPD spectra are compared to linear IR spectra of stable low-energy tautomeric conformations calculated at the B3LYP/def2-TZVPPD level of theory to identify the conformations accessed in the experiments. These comparisons suggest that the evolution in the features in the IRMPD action spectra with the size of the metal cation, and the appearance of new bands for the larger metal cations, are the result of the variations in the intensities at which these complexes can be generated and the strength of the alkali metal cation-cytosine binding interaction, not the presence of multiple tautomeric conformations. Only a single tautomeric conformation is accessed for all five alkali metal cation-cytosine complexes, where the alkali metal cation binds to the O2 and N3 atoms of the canonical amino-oxo tautomer of cytosine, M(+)(C1).

  1. Two-dimensional recrystallisation processes of nanometric vanadium oxide thin films grown by atomic layer chemical vapor deposition (ALCVD) evidenced by AFM

    Energy Technology Data Exchange (ETDEWEB)

    Groult, H. [Laboratoire Liquides Ioniques et Interfaces Chargees (CNRS-UMR 7612), Universite P and M Curie, 4 Place Jussieu, 75252 Paris Cedex 05 (France)]. E-mail: groult@ccr.jussieu.fr; Balnois, E. [Laboratoire Liquides Ioniques et Interfaces Chargees (CNRS-UMR 7612), Universite P and M Curie, 4 Place Jussieu, 75252 Paris Cedex 05 (France); Laboratoire Polymeres, Proprietes aux Interfaces et Composites, Universite de Bretagne Sud, rue de St. Maude, BP92116, 56321 Lorient Cedex (France); Mantoux, A. [Laboratoire Liquides Ioniques et Interfaces Chargees (CNRS-UMR 7612), Universite P and M Curie, 4 Place Jussieu, 75252 Paris Cedex 05 (France); Le Van, K. [Laboratoire Liquides Ioniques et Interfaces Chargees (CNRS-UMR 7612), Universite P and M Curie, 4 Place Jussieu, 75252 Paris Cedex 05 (France); Lincot, D. [Laboratoire d' Electrochimie et de Chimie Analytique (UMR CNRS 7575), ENSCP, 11 rue P and M Curie, 75231 Paris Cedex 05 (France)

    2006-06-15

    The influence of thermal annealing on the morphology and structure of nanometer range thickness vanadium oxide films deposited by ALCVD on silicon substrate was investigated by AFM. The appearance of crystalline centres with typical rectangular V{sub 2}O{sub 5} plates was clearly observed from 400 deg. C. Furthermore, spectacular 2D-reorganisation phenomenon with increasing temperature was pointed out since, initial circular particles change to elongated ones with a rectangular shape with increasing temperature. This reorganisation process results from an increase in the high surface atomic mobilities with increasing temperature. The growth of V{sub 2}O{sub 5} particles in the ab-plane occurs preferentially along the b-direction for which the atoms density is higher, in good agreement with results previously deduced from XRD analyses. The latter show limitation of the coherence domains values along the a-axis for temperatures higher than 450 deg. C.

  2. Bose-Einstein condensation of atomic hydrogen

    NARCIS (Netherlands)

    Willmann, L

    1999-01-01

    The recent creation of a Bose-Einstein condensate of atomic hydrogen has added a new system to this exciting field, The differences between hydrogen and the alkali metal atoms require other techniques for the initial trapping and cooling of the atoms and the subsequent detection of the condensate. T

  3. A HBAR-oscillator-based 4.596~GHz frequency source: Application to a coherent population trapping Cs vapor cell atomic clock

    CERN Document Server

    Daugey, Thomas; Martin, Gilles; Boudot, Rodolphe

    2015-01-01

    This article reports on the design and characterization of a high-overtone bulk acoustic wave resonator (HBAR)-oscillator-based 4.596~GHz frequency source. A 2.298~GHz signal, generated by an oscillator constructed around a thermally-controlled two-port AlN-sapphire HBAR resonator with a Q-factor of 24000 at 68$^{\\circ}$C, is frequency multiplied by 2 to 4.596~GHz, half of the Cs atom clock frequency. The temperature coefficient of frequency (TCF) of the HBAR is measured to be $-23$~ppm/$^{\\circ}$C at 2.298~GHz. The measured phase noise of the 4.596~GHz source is $-105$~dBrad$^2$/Hz at 1~kHz offset and $-150$~dBrad$^2$/Hz at 100~kHz offset. The 4.596~GHz output signal is used as a local oscillator (LO) in a laboratory-prototype Cs microcell-based coherent population trapping (CPT) atomic clock. The signal is stabilized onto the atomic transition frequency by tuning finely a voltage-controlled phase shifter (VCPS) implemented in the 2.298~GHz HBAR-oscillator loop, preventing the need for a high-power-consuming...

  4. 基于光谱吸收法的碱金属原子配比检测方法研究%Measurement of Mole Ratio for Alkali Metal Mixture by Using Spectral Absorption Method

    Institute of Scientific and Technical Information of China (English)

    邹升; 张红; 陈瑶; 陈熙源

    2015-01-01

    The ratio of alkali metal mixture is one of the most important parameters in gauge head belonging to the ultra‐sensitiv‐ity inertial measurement equipment ,which is required to detect precisely .According to the feature that ratio of alkali metal is re‐lated to alkali metal vapor density ,the theory of optical depth is used to detect the ratio of alkali metal in the present article .The result shows that the data got by the theory of optical depth compared with empirical formula differs at three orders of magni‐tude ,which can’t ensure the accuracy .By changing the data processing method ,model between spectral absorption rate and temperature in cell is established .The temperature in alkali metal cell is calibrated by spectral absorption rate .The ratio of alkali metal atoms in the cell is analyzed by calculating the alkali density with empirical formula .The computational error is less than 10% .%碱金属混合物原子配比是超高灵敏惯性测量装置表头的重要参数,需精确测量。针对碱金属配比与碱金属蒸汽密度相关的特点,提出运用光深理论检测碱金属配比。结果表明:受多种因素影响,光深理论得到的碱金属蒸汽密度与饱和蒸汽压经验公式计算的结果相差3个数量级,无法保证碱金属配比的测量精度;改变数据处理方法,建立光谱吸收率与气室内部温度的映射模型,运用光谱吸收率标定碱金属气室内部温度,通过碱金属饱和蒸汽压经验公式计算气室内部碱金属原子的配比,多组数据分析表明:检测误差在10%以内。

  5. Alloy formation and chemisorption at Zn/Pt(111) bimetallic surfaces using alkali ISS, XPD, and TPD.

    Science.gov (United States)

    Ho, Chih-Sung; Martono, Eddie; Banerjee, Santanu; Roszell, John; Vohs, John; Koel, Bruce E

    2013-11-21

    Alloy formation and chemisorption at bimetallic surfaces formed by vapor-depositing Zn on a Pt(111) single crystal were investigated primarily by using X-ray photoelectron diffraction (XPD), X-ray photoelectron spectroscopy (XPS), low-energy alkali ion scattering spectroscopy (ALISS), low electron energy diffraction (LEED), and temperature programmed desorption (TPD). A wide range of conditions were investigated to explore whether deposition and annealing of Zn films could produce well-defined, ordered alloy surfaces, similar to those encountered for Sn/Pt(111) surface alloys. These attempts were unsuccessful, although weak, diffuse (2 × 2) spots were observed under special conditions. The particular PtZn bimetallic alloy created by annealing one monolayer of Zn on Pt(111) at 600 K, which has a Zn composition in the surface layer of about 5 at. %, was investigated in detail by using XPD and ALISS. Only a diffuse (1 × 1) pattern was observed from this surface by LEED, suggesting that no long-range, ordered alloy structure was formed. Zn atoms were substitutionally incorporated into the Pt(111) crystal to form a near-surface alloy in which Zn atoms were found to reside primarily in the topmost and second layers. The alloyed Zn atoms in the topmost layer are coplanar with the Pt atoms in the surface layer, without any "buckling" of Zn, that is, displacement in the vertical direction. This result is expected because of the similar size of Pt and Zn, based on previous studies of bimetallic Pt alloys. Zn atoms desorb upon heating rather than diffusing deep into the bulk of the Pt crystal. Temperature programmed desorption (TPD) measurements show that both CO and NO have lower desorption energies on the PtZn alloy surface compared to that on the clean Pt(111) surface.

  6. Surface phonons on Al(111) surface covered by alkali metals

    Science.gov (United States)

    Rusina, G. G.; Eremeev, S. V.; Borisova, S. D.; Sklyadneva, I. Yu.; Chulkov, E. V.

    2005-06-01

    We investigated the vibrational and structural properties of the Al(111)-(3×3)R30°-AM (AM=Na,K,Li) adsorbed systems using interaction potentials from the embedded-atom method. The surface relaxation, surface phonon dispersion, and polarization of vibrational modes for the alkali adatoms and the substrate atoms as well as the local density of states are discussed. Our calculated structural parameters are in close agreement with experimental and ab initio results. The obtained vibrational frequencies compare fairly well with the available experimental data.

  7. A Lithium Vapor Box similarity experiment employing water vapor

    Science.gov (United States)

    Schwartz, Ja; Jagoe, C.; Goldston, Rj; Jaworski, Ma

    2016-10-01

    Handling high power loads and heat flux in the divertor is a major challenge for fusion power plants. A detached plasma will likely be required. However, hydrogenic and impurity puffing experiments show that detached operation leads easily to X-point MARFEs, impure plasmas, degradation in confinement, and lower helium pressure at the exhaust. The concept of the Lithium Vapor Box Divertor is to use local evaporation and strong differential pumping through condensation to localize the gas-phase material that absorbs the plasma heat flux, and so avoid those difficulties. In order to design such a box first the vapor without plasma must be simulated. The density of vapor required can be estimated using the SOL power, major radius, poloidal box length, and cooling energy per lithium atom. For an NSTX-U-sized machine, the Knudsen number Kn spans 0.01 to 1, the transitional flow regime. This regime cannot handled by fluid codes or collisionless Monte Carlo codes, but can be handled by Direct Simulation Monte Carlo (DSMC) codes. To validate a DSMC model, we plan to build a vapor box test stand employing more-convenient water vapor instead of lithium vapor as the working fluid. Transport of vapor between the chambers at -50C will be measured and compared to the model. This work supported by DOE Contract No. DE-AC02-09CH11466.

  8. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides

    Energy Technology Data Exchange (ETDEWEB)

    Gordon, John Howard; Alvare, Javier

    2016-10-25

    Alkali metals and sulfur may be recovered from alkali monosulfide and polysulfides in an electrolytic process that utilizes an electrolytic cell having an alkali ion conductive membrane. An anolyte solution includes an alkali monosulfide, an alkali polysulfide, or a mixture thereof and a solvent that dissolves elemental sulfur. A catholyte includes molten alkali metal. Applying an electric current oxidizes sulfide and polysulfide in the anolyte compartment, causes alkali metal ions to pass through the alkali ion conductive membrane to the catholyte compartment, and reduces the alkali metal ions in the catholyte compartment. Liquid sulfur separates from the anolyte solution and may be recovered. The electrolytic cell is operated at a temperature where the formed alkali metal and sulfur are molten.

  9. A negative ion source for alkali ions

    NARCIS (Netherlands)

    Vermeer, A.; Zwol, N.A. van

    1980-01-01

    An ion source is described which delivers negative alkali ions. With this source, which consists of a duoplasmatron and a charge exchange canal with alkali vapour, negative Li, Na and K ions are produced. The oven in which alkali metals are evaporated can reach temperatures up to 575°C.

  10. Alkali binding in hydrated Portland cement paste

    NARCIS (Netherlands)

    Chen, W.; Brouwers, H.J.H.

    2010-01-01

    The alkali-binding capacity of C–S–H in hydrated Portland cement pastes is addressed in this study. The amount of bound alkalis in C–S–H is computed based on the alkali partition theories firstly proposed by Taylor (1987) and later further developed by Brouwers and Van Eijk (2003). Experimental data

  11. Microfabricated cells for chip-scale atomic clock based on coherent population trapping: Fabrication and investigation

    Directory of Open Access Journals (Sweden)

    S.V. Ermak

    2015-03-01

    Full Text Available A universal method for fabrication of miniature cells for frequency standards and quantum magnetometers containing 87Rb atoms in the atmosphere of inert gas neon based on integrated technologies is considered. The results of experimental studies of coherent population trapping signals observed for a series of cells which provided recovery of vapors of an alkali metal from the rubidium dichromate salt with the help of laser radiation are presented. The coherent population trapping signals with a typical linewidth of 2–3 kHz and a signal-to-noise ratio of 1500 in the 1-Hz bandwidth were observed, which allows one to provide a relative frequency stability of atomic clock of 10−11 at 100 s.

  12. A high-overtone bulk acoustic wave resonator-oscillator-based 4.596 GHz frequency source: Application to a coherent population trapping Cs vapor cell atomic clock

    Energy Technology Data Exchange (ETDEWEB)

    Daugey, Thomas; Friedt, Jean-Michel; Martin, Gilles; Boudot, Rodolphe [FEMTO-ST, CNRS, UFC, 26 chemin de l’Epitaphe 25030 Besançon Cedex (France)

    2015-11-15

    This article reports on the design and characterization of a high-overtone bulk acoustic wave resonator (HBAR)-oscillator-based 4.596 GHz frequency source. A 2.298 GHz signal, generated by an oscillator constructed around a thermally controlled two-port aluminum nitride-sapphire HBAR resonator with a Q-factor of 24 000 at 68 °C, is frequency multiplied by 2–4.596 GHz, half of the Cs atom clock frequency. The temperature coefficient of frequency of the HBAR is measured to be −23 ppm/ °C at 2.298 GHz. The measured phase noise of the 4.596 GHz source is −105 dB rad{sup 2}/Hz at 1 kHz offset and −150 dB rad{sup 2}/Hz at 100 kHz offset. The 4.596 GHz output signal is used as a local oscillator in a laboratory-prototype Cs microcell-based coherent population trapping atomic clock. The signal is stabilized onto the atomic transition frequency by tuning finely a voltage-controlled phase shifter implemented in the 2.298 GHz HBAR-oscillator loop, preventing the need for a high-power-consuming direct digital synthesis. The short-term fractional frequency stability of the free-running oscillator is 1.8 × 10{sup −9} at one second integration time. In locked regime, the latter is improved in a preliminary proof-of-concept experiment at the level of 6.6 × 10{sup −11} τ{sup −1/2} up to a few seconds and found to be limited by the signal-to-noise ratio of the detected CPT resonance.

  13. Light-induced atom desorption from glass surfaces characterized by X-ray photoelectron spectroscopy

    Science.gov (United States)

    Kumagai, Ryo; Hatakeyama, Atsushi

    2016-07-01

    We analyzed the surfaces of vitreous silica (quartz) and borosilicate glass (Pyrex) substrates exposed to rubidium (Rb) vapor by X-ray photoelectron spectroscopy (XPS) to understand the surface conditions of alkali metal vapor cells. XPS spectra indicated that Rb atoms adopted different bonding states in quartz and Pyrex. Furthermore, Rb atoms in quartz remained in the near-surface region, while they diffused into the bulk in Pyrex. For these characterized surfaces, we measured light-induced atom desorption (LIAD) of Rb atoms. Clear differences in time evolution, photon energy dependence, and substrate temperature dependence were found; the decay of LIAD by continuous ultraviolet irradiation for quartz was faster than that for Pyrex, a monotonic increase in LIAD with increasing photon energy from 1.8 to 4.3 eV was more prominent for quartz, and LIAD from quartz was more efficient at higher temperatures in the range from 300 to 580 K, while that from Pyrex was almost independent of temperature.

  14. Hydrogen storage over alkali metal hydride and alkali metal hydroxide composites

    Institute of Scientific and Technical Information of China (English)

    Pei Yu; Yong Shen Chua; Hujun Cao; Zhitao Xiong; Guotao Wu; Ping Chen

    2014-01-01

    Alkali metal hydroxide and hydride composite systems contain both protic (H bonded with O) and hydridic hydrogen. The interaction of these two types of hydrides produces hydrogen. The enthalpy of dehydrogenation increased with the increase of atomic number of alkali metals, i.e.,-23 kJ/molH2 for LiOH-LiH, 55.34 kJ/molH2 for NaOH-NaH and 222 kJ/molH2 for KOH-KH. These thermodynamic calculation results were consistent with our experimental results. H2 was released from LiOH-LiH system during ball milling. The dehydrogenation temperature of NaOH-NaH system was about 150◦C; whereas KOH and KH did not interact with each other during the heating process. Instead, KH decomposed by itself. In these three systems, NaOH-NaH was the only reversible hydrogen storage system, the enthalpy of dehydrogenation was about 55.65 kJ/molH2 , and the corresponding entropy was ca. 101.23 J/(molH2 ·K), so the temperature for releasing 1.0 bar H2 was as high as 518◦C, showing unfavorable thermodynamic properties. The activation energy for hydrogen desorption of NaOH-NaH was found to be 57.87 kJ/mol, showing good kinetic properties.

  15. 硼氢化钾还原冷原子荧光测定大米中的汞%Determination of mercury in rice by potassium borohydride reduction cold vapor atomic fluorescence

    Institute of Scientific and Technical Information of China (English)

    毛荐; 刘忠胜

    2011-01-01

    本方法采用硝酸-过氧化氢微波消解,硼氢化钾还原冷原子荧光测定大米中的汞,消解液无需赶酸,直接测汞,方法简便快捷,实验检出限浓度为0.024μg/L,线性范围0~40 ng/ml,经国家一级标准物质验证,方法准确可靠。%This method uses nitric acid-hydrogen peroxide microwave digestion,potassium borohydride reduction of rice in cold vapor atomic fluorescence of mercury,acid digestion solution without the need to catch,direct measurement of mercury,the method is quick and easy experimental detection limit concentration of 0.024 μg / L,the linear range of 0 ~ 40 ng / ml,The method is accurate and reliable verified by the national standard.

  16. Alkali metal cation-hexacyclen complexes: effects of alkali metal cation size on the structure and binding energy.

    Science.gov (United States)

    Austin, C A; Rodgers, M T

    2014-07-24

    Threshold collision-induced dissociation (CID) of alkali metal cation-hexacyclen (ha18C6) complexes, M(+)(ha18C6), with xenon is studied using guided ion beam tandem mass spectrometry techniques. The alkali metal cations examined here include: Na(+), K(+), Rb(+), and Cs(+). In all cases, M(+) is the only product observed, corresponding to endothermic loss of the intact ha18C6 ligand. The cross-section thresholds are analyzed to extract zero and 298 K M(+)-ha18C6 bond dissociation energies (BDEs) after properly accounting for the effects of multiple M(+)(ha18C6)-Xe collisions, the kinetic and internal energy distributions of the M(+)(ha18C6) and Xe reactants, and the lifetimes for dissociation of the activated M(+)(ha18C6) complexes. Ab initio and density functional theory calculations are used to determine the structures of ha18C6 and the M(+)(ha18C6) complexes, provide molecular constants necessary for the thermodynamic analysis of the energy-resolved CID data, and theoretical estimates for the M(+)-ha18C6 BDEs. Calculations using a polarizable continuum model are also performed to examine solvent effects on the binding. In the absence of solvent, the M(+)-ha18C6 BDEs decrease as the size of the alkali metal cation increases, consistent with the noncovalent nature of the binding in these complexes. However, in the presence of solvent, the ha18C6 ligand exhibits selectivity for K(+) over the other alkali metal cations. The M(+)(ha18C6) structures and BDEs are compared to those previously reported for the analogous M(+)(18-crown-6) and M(+)(cyclen) complexes to examine the effects of the nature of the donor atom (N versus O) and the number donor atoms (six vs four) on the nature and strength of binding.

  17. Performance characterization of rigid polyurethane foam with refined alkali lignin and modified alkali lignin

    Institute of Scientific and Technical Information of China (English)

    LIU Zhi-ming; YU Fei; FANG Gui-zhen; YANG Hui-jun

    2009-01-01

    The two kinds of rigid polyurethane (PU) foams were prepared with respectively adding the refined alkali lignin and alkali lignin modified by 3-chloro-1,2-epoxypropane to be instead of 15% of the polyether glycol in weight. The indexes of mechanical performance, apparent density, thermal stability and aging resistance were separately tested for the prepared PU foams. The results show that the mechanical property, thermal insulation and thermal stability for PU foam with modified alkali lignin are excellent among two kinds of PU foams and control samples. The additions of the refined alkali lignin and modified alkali lignin to PU foam have little effect on the natural aging or heat aging resistance except for decreasing hot alkali resistance apparently. Additionally, the thermal conductivity of modified alkali lignin PU foam is lowest among two kinds of PU foams and control samples. The alkali lignin PU foam modified by 3-chloro-1,2-epoxypropane could be applied in the heat preservation field.

  18. Epitaxial Growth of a Methoxy-Functionalized Quaterphenylene on Alkali Halide Surfaces

    DEFF Research Database (Denmark)

    Balzer, Frank; Sun, Rong; Parisi, Jürgen

    2015-01-01

    The epitaxial growth of the methoxy functionalized para-quaterphenylene (MOP4) on the (001) faces of the alkali halides NaCl and KCl and on glass is investigated by a combination of lowenergy electron diffraction (LEED), polarized light microscopy (PLM), atomic force microscopy (AFM), and X...

  19. Design strategies for development of SCR catalyst: improvement of alkali poisoning resistance and novel regeneration method.

    Science.gov (United States)

    Peng, Yue; Li, Junhua; Shi, Wenbo; Xu, Jiayu; Hao, Jiming

    2012-11-20

    Based on the ideas of the additives modification and regeneration method update, two different strategies were designed to deal with the traditional SCR catalyst poisoned by alkali metals. First, ceria doping on the V(2)O(5)-WO(3)/TiO(2) catalyst could promote the SCR performance even reducing the V loading, which resulted in the enhancement of the catalyst's alkali poisoning resistance. Then, a novel method, electrophoresis treatment, was employed to regenerate the alkali poisoned V(2)O(5)-WO(3)/TiO(2) catalyst. This novel technique could dramatically enhance the SCR activities of the alkali poisoned catalysts by removing approximately 95% K or Na ions from the catalyst and showed less hazardous to the environment. Finally, the deactivation mechanisms by the alkali metals were extensively studied by employing both the experimental and DFT theoretical approaches. Alkali atom mainly influences the active site V species rather than W oxides. The decrease of catalyst surface acidity might directly reduce the catalytic activity, while the reducibility of catalysts could be another important factor.

  20. Heterometallic aluminates: alkali metals trapped by an aluminium aryloxide claw.

    Science.gov (United States)

    Muñoz, M Teresa; Cuenca, Tomás; Mosquera, Marta E G

    2014-10-14

    A series of heterometallic aluminium-alkali metal species [AlMMe2{2,6-(MeO)2C6H3O}2]n have been isolated for lithium, sodium and potassium. These compounds can be generated by the reaction of [AlMe2{2,6-(MeO)2C6H3O}]2 with the metallated phenol [M{2,6-(MeO)2C6H3O}]n or through the reaction of the mixture of AlMe3 and the appropriate alkali metal alkyl base with two equivalents of 2,6-dimethoxyphenol. In the heterometallic species obtained, the {AlMe2{2,6-(MeO)2C6H3O}2}(-) moiety is observed and could be described as a claw which fixes the alkali ion by the phenoxide oxygen atoms while the methoxy groups help to stabilize their coordination sphere. All compounds have been characterized by NMR spectroscopy and X-ray diffraction methods. Catalytic studies reveal that these compounds are active in ring-opening polymerization of L-lactide.

  1. Superconductivity in alkali-doped C{sub 60}

    Energy Technology Data Exchange (ETDEWEB)

    Ramirez, Arthur P., E-mail: apr@ucsc.edu

    2015-07-15

    Highlight: • Superconductivity in alkali-doped C{sub 60} (A{sub 3}C{sub 60}) is well described by an s-wave state produced by phonon mediated pairing. • Moderate coupling of electrons to high-frequency shape-changing intra-molecular vibrational modes produces transition temperatures up to 33 K in single-phase material. • The good understanding of pairing in A{sub 3}C{sub 60} offers a paradigm for the development of new superconducting materials. - Abstract: Superconductivity in alkali-doped C{sub 60} (A{sub 3}C{sub 60}, A = an alkali atom) is well described by an s-wave state produced by phonon mediated pairing. Moderate coupling of electrons to high-frequency shape-changing intra-molecular vibrational modes produces transition temperatures (T{sub c}) up to 33 K in single-phase material. The good understanding of pairing in A{sub 3}C{sub 60} offers a paradigm for the development of new superconducting materials.

  2. Precision two-photon spectroscopy of alkali elements

    Indian Academy of Sciences (India)

    P V Kiran Kumar; M V Suryanarayana

    2014-08-01

    In this paper, we have briefly reviewed the work on two-photon spectroscopy of alkali elements and its applications. The technique of Doppler-free two-photon spectroscopy is briefly summarized. A review of various techniques adopted for measuring absolute frequencies of the atomic transitions and precision measurements of isotope shifts and hyperfine structures (HFS) is presented. Some of the recent works on precision measurements of HFS constants of 6 ${}^2S_{1/2}$ level of ${}^{39}$K and ${}^{41}$K, 9 ${}^2S_{1/2}$ level and 7 ${}^2D_{3/2}$ level of 133Cs are also discussed.

  3. Bioinorganic Chemistry of the Alkali Metal Ions.

    Science.gov (United States)

    Kim, Youngsam; Nguyen, Thuy-Tien T; Churchill, David G

    2016-01-01

    The common Group 1 alkali metals are indeed ubiquitous on earth, in the oceans and in biological systems. In this introductory chapter, concepts involving aqueous chemistry and aspects of general coordination chemistry and oxygen atom donor chemistry are introduced. Also, there are nuclear isotopes of importance. A general discussion of Group 1 begins from the prevalence of the ions, and from a comparison of their ionic radii and ionization energies. While oxygen and water molecule binding have the most relevance to biology and in forming a detailed understanding between the elements, there is a wide range of basic chemistry that is potentially important, especially with respect to biological chelation and synthetic multi-dentate ligand design. The elements are widely distributed in life forms, in the terrestrial environment and in the oceans. The details about the workings in animal, as well as plant life are presented in this volume. Important biometallic aspects of human health and medicine are introduced as well. Seeing as the elements are widely present in biology, various particular endogenous molecules and enzymatic systems can be studied. Sodium and potassium are by far the most important and central elements for consideration. Aspects of lithium, rubidium, cesium and francium chemistry are also included; they help in making important comparisons related to the coordination chemistry of Na(+) and K(+). Physical methods are also introduced.

  4. Electrical properties of GaAs metal–oxide–semiconductor structure comprising Al2O3 gate oxide and AlN passivation layer fabricated in situ using a metal–organic vapor deposition/atomic layer deposition hybrid system

    Directory of Open Access Journals (Sweden)

    Takeshi Aoki

    2015-08-01

    Full Text Available This paper presents a compressive study on the fabrication and optimization of GaAs metal–oxide–semiconductor (MOS structures comprising a Al2O3 gate oxide, deposited via atomic layer deposition (ALD, with an AlN interfacial passivation layer prepared in situ via metal–organic chemical vapor deposition (MOCVD. The established protocol afforded self-limiting growth of Al2O3 in the atmospheric MOCVD reactor. Consequently, this enabled successive growth of MOCVD-formed AlN and ALD-formed Al2O3 layers on the GaAs substrate. The effects of AlN thickness, post-deposition anneal (PDA conditions, and crystal orientation of the GaAs substrate on the electrical properties of the resulting MOS capacitors were investigated. Thin AlN passivation layers afforded incorporation of optimum amounts of nitrogen, leading to good capacitance–voltage (C–V characteristics with reduced frequency dispersion. In contrast, excessively thick AlN passivation layers degraded the interface, thereby increasing the interfacial density of states (Dit near the midgap and reducing the conduction band offset. To further improve the interface with the thin AlN passivation layers, the PDA conditions were optimized. Using wet nitrogen at 600 °C was effective to reduce Dit to below 2 × 1012 cm−2 eV−1. Using a (111A substrate was also effective in reducing the frequency dispersion of accumulation capacitance, thus suggesting the suppression of traps in GaAs located near the dielectric/GaAs interface. The current findings suggest that using an atmosphere ALD process with in situ AlN passivation using the current MOCVD system could be an efficient solution to improving GaAs MOS interfaces.

  5. Electrical properties of GaAs metal-oxide-semiconductor structure comprising Al2O3 gate oxide and AlN passivation layer fabricated in situ using a metal-organic vapor deposition/atomic layer deposition hybrid system

    Science.gov (United States)

    Aoki, Takeshi; Fukuhara, Noboru; Osada, Takenori; Sazawa, Hiroyuki; Hata, Masahiko; Inoue, Takayuki

    2015-08-01

    This paper presents a compressive study on the fabrication and optimization of GaAs metal-oxide-semiconductor (MOS) structures comprising a Al2O3 gate oxide, deposited via atomic layer deposition (ALD), with an AlN interfacial passivation layer prepared in situ via metal-organic chemical vapor deposition (MOCVD). The established protocol afforded self-limiting growth of Al2O3 in the atmospheric MOCVD reactor. Consequently, this enabled successive growth of MOCVD-formed AlN and ALD-formed Al2O3 layers on the GaAs substrate. The effects of AlN thickness, post-deposition anneal (PDA) conditions, and crystal orientation of the GaAs substrate on the electrical properties of the resulting MOS capacitors were investigated. Thin AlN passivation layers afforded incorporation of optimum amounts of nitrogen, leading to good capacitance-voltage (C-V) characteristics with reduced frequency dispersion. In contrast, excessively thick AlN passivation layers degraded the interface, thereby increasing the interfacial density of states (Dit) near the midgap and reducing the conduction band offset. To further improve the interface with the thin AlN passivation layers, the PDA conditions were optimized. Using wet nitrogen at 600 °C was effective to reduce Dit to below 2 × 1012 cm-2 eV-1. Using a (111)A substrate was also effective in reducing the frequency dispersion of accumulation capacitance, thus suggesting the suppression of traps in GaAs located near the dielectric/GaAs interface. The current findings suggest that using an atmosphere ALD process with in situ AlN passivation using the current MOCVD system could be an efficient solution to improving GaAs MOS interfaces.

  6. Strong Turbulence in Alkali Halide Negative Ion Plasmas

    Science.gov (United States)

    Sheehan, Daniel

    1999-11-01

    Negative ion plasmas (NIPs) are charge-neutral plasmas in which the negative charge is dominated by negative ions rather than electrons. They are found in laser discharges, combustion products, semiconductor manufacturing processes, stellar atmospheres, pulsar magnetospheres, and the Earth's ionosphere, both naturally and man-made. They often display signatures of strong turbulence^1. Development of a novel, compact, unmagnetized alkali halide (MX) NIP source will be discussed, it incorporating a ohmically-heated incandescent (2500K) tantulum solenoid (3cm dia, 15 cm long) with heat shields. The solenoid ionizes the MX vapor and confines contaminant electrons, allowing a very dry (electron-free) source. Plasma densities of 10^10 cm-3 and positive to negative ion mass ratios of 1 Fusion 4, 91 (1978).

  7. Atomic Faraday filter with equivalent noise bandwidth less than 1 GHz

    CERN Document Server

    Zentile, Mark A; Keaveney, James; Adams, Charles S; Hughes, Ifan G

    2015-01-01

    We demonstrate an atomic bandpass optical filter with an equivalent noise bandwidth less than 1 GHz using the D$_1$ line in a cesium vapor. We use the ElecSus computer program to find optimal experimental parameters, and find that for important quantities the cesium D$_1$ line clearly outperforms other alkali metals on either D-lines. The filter simultaneously achieves a peak transmission of 77%, a passband of 310 MHz and an equivalent noise bandwidth of 0.96 GHz, for a magnetic field of 45.3 gauss and a temperature of 68.0$\\,^\\circ$C. Experimentally, the prediction from the model is verified. The experiment and theoretical predictions show excellent agreement.

  8. Structure and photoabsorption properties of cationic alkali dimers solvated in neon clusters.

    Science.gov (United States)

    Zanuttini, D; Douady, J; Jacquet, E; Giglio, E; Gervais, B

    2010-11-07

    We present a theoretical investigation of the structure and optical absorption of M(2)(+) alkali dimers (M=Li,Na,K) solvated in Ne(n) clusters for n=1 to a few tens Ne atoms. For all these alkali, the lowest-energy isomers are obtained by aggregation of the first Ne atoms at the extremity of the alkali molecule. This particular geometry, common to other M(2)(+)-rare gas clusters, is intimately related to the shape of the electronic density of the X  (2)Σ(g)(+) ground state of the bare M(2)(+) molecules. The structure of the first solvation shell presents equilateral Ne(3) and capped pentagonal Ne(6) motifs, which are characteristic of pure rare gas clusters. The size and geometry of the complete solvation shell depend on the alkali and were obtained at n=22 with a D(4h) symmetry for Li and at n=27 with a D(5h) symmetry for Na. For K, our study suggests that the closure of the first solvation shell occurs well beyond n=36. We show that the atomic arrangement of these clusters has a profound influence on their optical absorption spectrum. In particular, the XΣ transition from the X  (2)Σ(g)(+) ground state to the first excited (2)Σ(u)(+) state is strongly blueshifted in the Frank-Condon area.

  9. Determination of Surface Exciton Energies by Velocity Resolved Atomic Desorption

    Energy Technology Data Exchange (ETDEWEB)

    Hess, Wayne P.; Joly, Alan G.; Beck, Kenneth M.; Sushko, Petr V.; Shluger, Alexander L.

    2004-08-20

    We have developed a new method for determining surface exciton band energies in alkali halides based on velocity-resolved atomic desorption (VRAD). Using this new method, we predict the surface exciton energies for K1, KBr, KC1, and NaC1 within +0.15 eV. Our data, combined with the available EELS data for alkali fluorides, demonstrate a universal linear correlation with the inverse inter-atomic distance in these materials. The results suggest that surface excitons exist in all alkali halides and their excitation energies can be predicted from the known bulk exciton energies and the obtained correlation plot.

  10. Finite Size Effects in Adsorption of Helium Mixtures by Alkali Substrates

    Science.gov (United States)

    Barranco, M.; Guilleumas, M.; Hernández, E. S.; Mayol, R.; Pi, M.; Szybisz, L.

    2004-08-01

    We investigate the behavior of mixed 3He-4He droplets on alkali surfaces at zero temperature, within the frame of Finite Range Density Functional theory. The properties of one single 3He atom on 4He_N4 droplets on different alkali surfaces are addressed, and the energetics and structure of 4He_N4+3He_N3 systems on Cs surfaces, for nanoscopic 4He drops, are analyzed through the solutions of the mean field equations for varying number N3 of 3He atoms. We discuss the size effects on the single particle spectrum of 3He atoms and on the shapes of both helium distributions.

  11. Structure and properties of alizarin complex formed with alkali metal hydroxides in methanol solution.

    Science.gov (United States)

    Jeliński, Tomasz; Cysewski, Piotr

    2016-06-01

    Quantum chemical computations were used for prediction of the structure and color of alizarin complex with alkali metal hydroxides in methanolic solutions. The color prediction relying on the single Gaussian-like band once again proved the usefulness of the PBE0 density functional due to the observed smallest color difference between computed and experimentally derived values. It was found that the alkali metal hydroxide molecules can bind to the two oxygen atoms of both hydroxyl groups of alizarin or to one of these atoms and the oxygen atom from the keto group in a complex with three methanol molecules. This means that two electronic transitions need to be taken into account when considering the spectra of the studied complexes. The resulting bond lengths and angles are correlated with the properties of the alkali metal atoms. The molar mass, the atomic radius, and the Pauling electronegativity of studied metals are quite accurate predictors of the geometric properties of hydroxide complexes with alizarin in methanol solution. Graphical abstract The spectra of the neutral and monoanionic form of alizarin together with color changes resulting from addition of different metal hydroxides and represented in CIE color space.

  12. A hetero-alkali-metal version of the utility amide LDA: lithium-potassium diisopropylamide.

    Science.gov (United States)

    Armstrong, David R; Kennedy, Alan R; Mulvey, Robert E; Robertson, Stuart D

    2013-03-14

    Designed to extend the synthetically important alkali-metal diisopropylamide [N(i)Pr(2); DA] class of compounds, the first example of a hetero-alkali-metallic complex of DA has been prepared as a partial TMEDA solvate. Revealed by an X-ray crystallographic study, its structure exists as a discrete lithium-rich trinuclear Li(2)KN(3) heterocycle, with TMEDA only solvating the largest of the alkali-metals, with the two-coordinate lithium atoms being close to linearity [161.9(2)°]. A variety of NMR spectroscopic studies, including variable temperature and DOSY NMR experiments, suggests that this new form of LDA maintains its integrity in non-polar hydrocarbon solution. This complex thus represents a rare example of a KDA molecule which is soluble in non-polar medium without the need for excessive amounts of solubilizing Lewis donor being added.

  13. Strong coupling and high contrast all optical modulation in atomic cladding waveguides

    CERN Document Server

    Stern, Liron; Mazurski, Noa; Levy, Uriel

    2016-01-01

    In recent years we are witnessing a flourish in research aimed to facilitate alkali vapors in guided wave configurations. Owing to the significant reduction in device dimensions, the increase in density of states, the interaction with surfaces and primarily the high intensities carried along the structure, a rich world of light vapor interactions can be studied, and new functionalities, e.g. low power nonlinear light-matter interactions can be achieved. One immense remaining challenge is to study the effects of quantum coherence and shifts in such nano-scale waveguides, characterized by ultra-small mode areas and fast dynamics. Here, we construct a serpentine silicon-nitride wave guide, having atomic vapor as its cladding. The unprecedented mode volume of 5e-13 m^3 supported over a length of 17 mm is used to demonstrate efficient linear and non-linear spectroscopy. Fascinating and important phenomena such as van der Waals shifts, dynamical stark shifts, and coherent effects such as strong coupling (in the for...

  14. Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane

    Energy Technology Data Exchange (ETDEWEB)

    Gordon, John Howard; Alvare, Javier

    2016-09-13

    A reactor has two chambers, namely an oil feedstock chamber and a source chamber. An ion separator separates the oil feedstock chamber from the source chamber, wherein the ion separator allows alkali metal ions to pass from the source chamber, through the ion separator, and into the oil feedstock chamber. A cathode is at least partially housed within the oil feedstock chamber and an anode is at least partially housed within the source chamber. A quantity of an oil feedstock is within the oil feedstock chamber, the oil feedstock comprising at least one carbon atom and a heteroatom and/or one or more heavy metals, the oil feedstock further comprising naphthenic acid. When the alkali metal ion enters the oil feedstock chamber, the alkali metal reacts with the heteroatom, the heavy metals and/or the naphthenic acid, wherein the reaction with the alkali metal forms inorganic products.

  15. High effective silica fume alkali activator

    Indian Academy of Sciences (India)

    Vladimír Živica

    2004-04-01

    Growing demands on the engineering properties of cement based materials and the urgency to decrease unsuitable ecologic impact of Portland cement manufacturing represent significant motivation for the development of new cement corresponding to these aspects. One category represents prospective alkali activated cements. A significant factor influencing their properties is alkali activator used. In this paper we present a new high effective alkali activator prepared from silica fume and its effectiveness. According to the results obtained this activator seems to be more effective than currently used activators like natrium hydroxide, natrium carbonate, and water glass.

  16. Electron transport through monovalent atomic wires

    DEFF Research Database (Denmark)

    Lee, Y. J.; Brandbyge, Mads; Puska, M. J.

    2004-01-01

    Using a first-principles density-functional method we model electron transport through linear chains of monovalent atoms between two bulk electrodes. For noble-metal chains the transport resembles that for free electrons over a potential barrier whereas for alkali-metal chains resonance states...... at the chain determine the conductance. As a result, the conductance for noble-metal chains is close to one quantum of conductance, and it oscillates moderately so that an even number of chain atoms yields a higher value than an odd number. The conductance oscillations are large for alkali-metal chains...

  17. Relaxation of quadrupole orientation in an optically pumped alkali vapour

    Energy Technology Data Exchange (ETDEWEB)

    Bernabeu, E.; Tornos, J.

    1985-04-01

    The relaxation of quadrupole orientation (alignment) in an optically pumped alkali vapour is theoretically studied by taking into account the relaxation processes by alkali-buffer gas, alkali-alkali with spin exchange and alkali-cell wall (diffusion process) collisions. The relaxation transients of the quadrupole orientation are obtained by introducing a first-order weak-pumping approximation (intermediate pumping) less restrictive than the usually considered (zeroth order) one.

  18. Milk Alkali and Hydrochlorothiazide: A Case Report

    Directory of Open Access Journals (Sweden)

    Babar Parvez

    2011-01-01

    Full Text Available Hypercalcemia is a relatively common clinical problem in both outpatient and inpatient settings. Primary pathophysiology is the entry of calcium that exceeds its excretion into urine or deposition in bone into circulation. Among a wide array of causes of hypercalcemia, hyperparathyroidism and malignancy are the most common, accounting for greater than 90 percent of cases. Concordantly, there has been a resurgence of milk-alkali syndrome associated with the ingestion of large amounts of calcium and absorbable alkali, making it the third leading cause of hypercalcemia (Beall and Scofield, 1995 and Picolos et al., 2005. This paper centers on a case of over-the-counter calcium and alkali ingestion for acid reflux leading to milk alkali with concordant use of thiazide diuretic for hypertension.

  19. Validation of an analytical method for the determination of total mercury in urine samples using cold vapor atomic absorption spectrometry (CV-AAS); Validacao de metodologia analitica para determinacao de mercurio total em amostras de urina para espectrometria de absorcao atomica com geracao de vapor frio (CV-AAS)

    Energy Technology Data Exchange (ETDEWEB)

    Guilhen, Sabine Neusatz

    2009-07-01

    Mercury (Hg) is a toxic metal applied to a variety of products and processes, representing a risk to the health of occupationally or accidentally exposed subjects. Dental amalgam is a restorative material composed of metallic mercury, which use has been widely debated in the last decades. Due to the dubiety of the studies concerning dental amalgam, many efforts concerning this issue have been conducted. The Tropical Medicine Foundation (Tocantins, Brazil) has recently initiated a study to evaluate the environmental and occupational levels of exposure to mercury in dentistry attendants at public consulting rooms in the city of Araguaina (TO). In collaboration with this study, the laboratory of analysis at IPEN's Chemistry and Environment Center is undertaking the analysis of mercury levels in exposed subjects' urine samples using cold vapor atomic absorption spectrometry. This analysis requires the definition of a methodology capable of generating reliable results. Such methodology can only be implemented after a rigorous validation procedure. As part of this work, a series of tests were conducted in order to confirm the suitability of the selected methodology and to assert that the laboratory addresses all requirements needed for a successful implementation of the methodology. The following parameters were considered in order to test the method's performance: detection and quantitation limits, selectivity, sensitivity, linearity, accuracy and precision. The assays were carried out with certified reference material, which assures the traceability of the results. Taking into account the estimated parameters, the method can be considered suitable for the afore mentioned purpose. The mercury concentration found for the reference material was of (95,12 +- 11,70)mug.L{sup -1} with a recovery rate of 97%. The method was also applied to 39 urine samples, six of which (15%) showing urinary mercury levels above the normal limit of 10{mu}g.L{sup -1}. The

  20. Validation of an analytical method for the determination of total mercury in urine samples using cold vapor atomic absorption spectrometry (CV-AAS); Validacao de metodologia analitica para determinacao de mercurio total em amostras de urina por espectrometria de absorcao atomica com geracao de vapor frio (CV-AAS)

    Energy Technology Data Exchange (ETDEWEB)

    Guilhen, Sabine Neusatz

    2009-07-01

    Mercury (Hg) is a toxic metal applied to a variety of products and processes, representing a risk to the health of occupationally or accidentally exposed subjects. Dental amalgam is a restorative material composed of metallic mercury, which use has been widely debated in the last decades. Due to the dubiety of the studies concerning dental amalgam, many efforts concerning this issue have been conducted. The Tropical Medicine Foundation (Tocantins, Brazil) has recently initiated a study to evaluate the environmental and occupational levels of exposure to mercury in dentistry attendants at public consulting rooms in the city of Araguaina (TO). In collaboration with this study, the laboratory of analysis at IPEN's Chemistry and Environment Center is undertaking the analysis of mercury levels in exposed subjects' urine samples using cold vapor atomic absorption spectrometry. This analysis requires the definition of a methodology capable of generating reliable results. Such methodology can only be implemented after a rigorous validation procedure. As part of this work, a series of tests were conducted in order to confirm the suitability of the selected methodology and to assert that the laboratory addresses all requirements needed for a successful implementation of the methodology. The following parameters were considered in order to test the method’s performance: detection and quantitation limits, selectivity, sensitivity, linearity, accuracy and precision. The assays were carried out with certified reference material, which assures the traceability of the results. Taking into account the estimated parameters, the method can be considered suitable for the afore mentioned purpose. The mercury concentration found for the reference material was of (95,12 ± 11,70)μg.L{sup -1} with a recovery rate of 97%. The method was also applied to 39 urine samples, six of which (15%) showing urinary mercury levels above the normal limit of 10μg.L{sup −1}. The obtained

  1. Extreme early solar system chemical fractionation recorded by alkali-rich clasts contained in ordinary chondrite breccias

    Science.gov (United States)

    Yokoyama, Tatsunori; Misawa, Keiji; Okano, Osamu; Shih, Chi-Yu; Nyquist, Laurence E.; Simon, Justin I.; Tappa, Michael J.; Yoneda, Shigekazu

    2017-01-01

    New K-Ca and Rb-Sr isotopic analyses have been performed on alkali-rich igneous rock fragments in the Yamato (Y)-74442 and Bhola LL-chondritic breccias to better understand the extent and timing of alkali enrichments in the early solar system. The Y-74442 fragments yield a K-Ca age of 4.41 ± 0.28 Ga for λ(40K) = 0.5543 Ga-1 with an initial 40Ca/44Ca ratio of 47.1618 ± 0.0032. Studying the same fragments with the Rb-Sr isotope system yields an age of 4.420 ± 0.031 Ga for λ(87Rb) = 0.01402 Ga-1 with an initial ratio of 87Sr/86Sr = 0.7203 ± 0.0044. An igneous rock fragment contained in Bhola shows a similar alkali fractionation pattern to those of Y-74442 fragments but does not plot on the K-Ca or Rb-Sr isochron of the Y-74442 fragments. Calcium isotopic compositions of whole-rock samples of angrite and chondrites are primordial, indistinguishable from mantle-derived terrestrial rocks, and here considered to represent the initial composition of bulk silicate Earth. The initial ε40Ca value determined for the source of the alkali clasts in Y-74442 that is ∼0.5 ε-units higher than the solar system value implies an early alkali enrichment. Multi-isotopic studies on these alkali-rich fragments reveal that the source material of Y-74442 fragments had elemental ratios of K/Ca = 0.43 ± 0.18, Rb/Sr = 3.45 ± 0.66 and K/Rb ∼ 170, that may have formed from mixtures of an alkali-rich component (possibly an alkali-enriched gaseous reservoir produced by fractionation of early nebular condensates) and chondritic components that were flash-heated during an impact event on the LL-chondrite parent body ∼4.42 Ga ago. Further enrichments of potassium and rubidium relative to calcium and strontium as well as a mutual alkali-fractionation (K/Rb ∼ 50 and heavier alkali-enrichment) would have likely occurred during subsequent cooling and differentiation of this melt. Alkali fragments in Bhola might have undergone similar solid-vapor fractionation processes to those of Y

  2. Validação de metodologia analítica para determinação de mercúrio total em amostras de urina por espectrometria de absorção atômica com geração de vapor frio (CV-AAS: estudo de caso Validation of an analytical method for the determination of total mercury in urine samples using cold vapor atomic absorption spectrometry (CV-AAS: case study

    Directory of Open Access Journals (Sweden)

    Sabine Neusatz Guilhen

    2010-01-01

    Full Text Available Mercury is a toxic metal used in a variety of substances over the course history. One of its more dubious uses is in dental amalgam restorations. It is possible to measure very small concentrations of this metal in the urine of exposed subjects by the cold vapor atomic absorption technique. The present work features the validation as an essential tool to confirm the suitability of the analytical method chosen to accomplish such determination. An initial analysis will be carried out in order to evaluate the environmental and occupational levels of exposure to mercury in 39 members of the auxiliary dental staff at public consulting rooms in the city of Araguaína (TO.

  3. Difference of coordination between alkali- and alkaline-earth-metal ions to a symmetrical α,α',δ,δ'-tetramethylcucurbit[6]uril.

    Science.gov (United States)

    Chen, Wen-Jian; Yu, Da-Hai; Xiao, Xin; Zhang, Yun-Qian; Zhu, Qian-Jiang; Xue, Sai-Feng; Tao, Zhu; Wei, Gang

    2011-08-01

    To explore differences in coordination between alkali- and alkaline-earth-metal ions and cucurbit[n]urils, a water-soluble α,α',δ,δ'-tetramethylcucurbit[6]uril (TMeQ[6]) was used to synthesize a series of complexes and their supramolecular assemblies, based on the coordination of TMeQ[6] with alkali- and alkaline-earth-metal ions. The complexes and corresponding supramolecular assemblies were structurally characterized by single-crystal X-ray diffraction. Unlike cucurbituril (Q[6]), which formed the metal-Q[6] polymers based on the direct coordination of carbonyl oxygen atoms to the alkali-metal ions, TMeQ[6] formed metal-TMeQ[6] polymers based on the direct coordination of carbonyl oxygen atoms with the alkaline-earth-metal ions rather than the alkali-metal ions.

  4. Periodic DFT approaches to crystalline alkali metal azides

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The energy bands, electronic structures andrelationship between structures and properties of the crys-talline alkali metal azides, LiN3, α-NaN3 and KN3, are investigated at the DFT-B3LYP level. The crystalline bulks arepredicted to be insulator, speculated from their band gaps ofca. 0.23-0.25 a.u. and from their level frontier bands. Theatomic overlaps and electron densities show that the metalsand the azides are combined by ionic bonds. The crystal lat-tice energies, being corrected for the basis set superpositionerrors, are -852.30, -771.45 and - 614.78 kJ @ mol-1 for LiN3,α-NaN3 and KN3 respectively. These values are similar tothose by Gray's approximate method. The frontier crystalorbital mainly consists of the atomic orbital of the terminalnitrogen of azides. The contribution of the metallic orbital tothe LUMO is very small. The electron transition from theHOMO to the LUMO is difficult to occur. Hence all the al-kali metal azides are expected to be insensitive explosives,according to the "principle of easiest electron transition".

  5. Photoelectron spectroscopy of phthalocyanine vapors

    Energy Technology Data Exchange (ETDEWEB)

    Berkowitz, J.

    1979-01-01

    The He(I) photoelectron spectra of several metal phthalocyanines and metal-free phthalocyanine vapor shows that: a sharp peak at 4.99 eV is an artifact due to ionization of atomic He by He(II) radiation; the first phthalocyanine peak (metal-containing or metal-free) occurs at 6.4 eV; and the metal-like d orbitals lie at least 1 to 2 eV deeper, except in the case of Fe. (DLC)

  6. Alkali metal salts of formazanate ligands : diverse coordination modes as a result of the nitrogen-rich [NNCNN] ligand backbone

    NARCIS (Netherlands)

    Travieso-Puente, Raquel; Chang, Mu-Chieh; Otten, Edwin

    2014-01-01

    Alkali metal salts of redox-active formazanate ligands were prepared, and their structures in the solid-state and in solution are determined. The nitrogen-rich [NNCNN] backbone of formazanates results in a varied coordination chemistry, with both the internal and terminal nitrogen atoms available fo

  7. Surface Morphology and Structure of Double-Phase Magnetic Alkali Borosilicate Glasses

    Science.gov (United States)

    Andreeva, N. V.; Naberezhnov, A. A.; Tomkovich, M. V.; Nacke, B.; Kichigin, V.; Rudskoy, A. I.; Filimonov, A. V.

    2016-11-01

    The surface morphology of double-phase magnetic alkali borosilicate glasses of four types obtained by induction melting is studied by the methods of atomic-force and scanning electron microscopy. The distribution of elements over the surface and the elemental composition of the glasses are determined. It is shown that a dendritic system of interrelated channels required for formation of porous matrixes with controlled mean pore diameter may be obtained in these objects depending on the heat treatment mode.

  8. 碱熔-电感耦合等离子体发射光谱法测定大气颗粒物样品中无机元素%Quantification of Inorganic Elements in Aerosol Samples by Inductively Coupled Plasma-Atomic Emission Spectrometry with Alkali Melting

    Institute of Scientific and Technical Information of China (English)

    付爱瑞; 陈庆芝; 罗治定; 姜云军; 金倩; 王芸

    2011-01-01

    大气颗粒物(TSP和PM10)中Si、Al、Ca、Mg、K、Fe、Na等元素含量较高,是颗粒物源分析的指示性元素.目前分析大气颗粒物样品中无机元素的方法有中子活化分析法、X射线荧光光谱法、微波消解(或高压釜消解)电感耦合等离子体发射光谱法和电感耦合等离子体质谱法.本文建立了碱熔-电感耦合等离子体发射光谱法测定大气颗粒物样品中Si、Al、Ca、Mg、Fe、Ti、Ba、Sr、Zr等无机元素的分析方法,样品于镍坩埚中530~550℃灰化60 min后用NaOH融熔,水提取,再用2 mL 50%的HCl酸化,钠基体匹配消除干扰,解决了大气颗粒物滤膜样品中Si易产生的溶解不完全等问题,提高了Ti、Ba、Sr、Zr等主、次量元素测定的精密度和准确度.讨论了坩埚和熔剂的选择、灰化温度、灰化时间、酸度、干扰等影响因素.在选定条件下,测定结果相对误差(RE)﹤4%,相对标准偏差(RSD,n=12)﹤5%,检出限为0.0047~1.2 ng/g.方法所需设备简单,分析成本低,快速简便,精密度好,准确度高,适宜批量样品的测定.%In atmospheric particles ( TSP and PM10 ), the high contents of some inorganic elements including Si, Al, Ca, Mg, K, Fe and Na are the proxy elements for the particles source analysis. At present, there are several methods to analyze inorganic elements for atmospheric particles such as neutron activation analysis, X-ray Fluorescence Spectrometry ( XRF ), Inductively Coupled Plasma-Atomic Emission Spectrometry ( ICP-AES ) and Inductively Coupled Plasma-Mass Spectrometry ( ICP-MS ) after dissolving by microwave ( or high-pressured cauldron ). The established method for determining Si, Al, Ca, Mg, Fe, Ti, Sr, Ba and Zr in aerosols by ICP-AES with alkali melting solved the problems of incomplete dissolving for Si caught in an atmospheric particles filter diaphragm, and improved the precision and accuracy of the determinations of major and trace elements such as Ti, Ba, Sr, Zr. In

  9. Structure and energetics of helium films on alkali substrates

    Science.gov (United States)

    Boninsegni, Massimo; Szybisz, Leszek

    2004-07-01

    Low-temperature adsorption of He4 films on Alkali metal substrates is investigated theoretically by means of ground-state quantum Monte Carlo simulations. The most accurate potentials currently available are utilized to model the interaction of He4 atoms with the substrate. Continuous growth of film thickness as a function of chemical potential is observed on Li, Na, and K substrates. A superfluid monolayer forms on a Li substrate; on Na and K, thermodynamically stable films are a few layers thick. The uncertainties of the calculation and in the potentials, preclude a definitive conclusion on the existence of a stable He4 film on Rb. A comparison of the results of this calculation with those obtained using the Orsay-Trento density functional shows broad quantitative agreement.

  10. Phonon dispersion in alkali metals and their equiatomic sodium-based binary alloys

    Institute of Scientific and Technical Information of China (English)

    Aditya M. VORA

    2008-01-01

    In the present article, the theoretical calcula-tions of the phonon dispersion curves (PDCs) of five alkali metals viz. Li, Na, K, Rb, Cs and their four equia-tomic sodium-based binary alloys viz. Na0.5Li0.5,Na0.5K0.5, Na0.5Rb0.5 and Na0.5Cs0.5 to second order in a local model potential is discussed in terms of the real-space sum of the Born yon Karman central force con-stants. Instead of the concentration average of the force constants of pure alkali metals, the pseudo-alloy-atom (PAA) is adopted to directly compute the force constants of the four equiatomic sodium based binary alloys and was successfully applied. The exchange and correlation functions due to the Hartree (H) and Ichimaru-Utsumi (IU) are used to investigate the influence of the screening effects. The phonon frequencies of alkali metals and their four equiatomic sodium-based binary alloys in the longit-udinal branch are more sensitive to the exchange and cor-relation effects in comparison with the transverse branches. The PDCs of pure alkali metals are found in qualitative agreement with the available experimental data. The frequencies in the longitudinal branch are sup-pressed rather due to IU-screening function than those due to static H-screening function.

  11. Mechanical and microstructural properties of alkali-activated fly ash geopolymers.

    Science.gov (United States)

    Komljenović, M; Bascarević, Z; Bradić, V

    2010-09-15

    This paper investigates the properties of geopolymer obtained by alkali-activation of fly ash (FA), i.e. the influence of characteristics of the representative group of FA (class F) from Serbia, as well as that of the nature and concentration of various activators on mechanical and microstructural properties of geopolymers. Aqueous solutions of Ca(OH)(2), NaOH, NaOH+Na(2)CO(3), KOH and sodium silicate (water glass) of various concentrations were used as alkali activators. It was established that the nature and concentration of the activator was the most dominant parameter in the alkali-activation process. In respect of physical characteristics of FA, the key parameter was fineness. The geopolymer based on FA with the highest content of fine particles (<43 microm), showed the highest compressive strength in all cases. Regardless of FA characteristics, nature and concentration of the activator, the alkali-activation products were mainly amorphous. The formation of crystalline phases (zeolites) occurred in some cases, depending on the reaction conditions. The highest compressive strength was obtained using sodium silicate. Together with the increase of sodium silicate SiO(2)/Na(2)O mass ratio, the atomic Si/Al ratio in the reaction products was also increased. Under the experimental conditions of this investigation, high strength was directly related to the high Si/Al ratio.

  12. Superconductivity and electrical resistivity in alkali metal doped fullerides: Phonon mechanism

    Indian Academy of Sciences (India)

    Dinesh Varshney; A Dube; K K Choudhary; R K Singh

    2005-04-01

    We consider a two-peak model for the phonon density of states to investigate the nature of electron pairing mechanism for superconducting state in fullerides. We first study the intercage interactions between the adjacent C60 cages and expansion of lattice due to the intercalation of alkali atoms based on the spring model to estimate phonon frequencies from the dynamical matrix for the intermolecular alkali-C60 phonons. Electronic parameter as repulsive parameter and the attractive coupling strength are obtained within the random phase approximation. Transition temperature, c, is obtained in a situation when the free electrons in lowest molecular orbital are coupled with alkali-C60 phonons as 5 K, which is much lower as compared to reported c (≈ 20 K). The superconducting pairing is mainly driven by the high frequency intramolecular phonons and their effects enhance it to 22 K. To illustrate the usefulness of the above approach, the carbon isotope exponent and the pressure effect are also estimated. Temperature dependence of electrical resistivity is then analysed within the same model phonon spectrum. It is inferred from the two-peak model for phonon density of states that high frequency intramolecular phonon modes play a major role in pairing mechanism with possibly some contribution from alkali-C60 phonon to describe most of the superconducting and normal state properties of doped fullerides.

  13. Zintl cluster chemistry in the alkali-metal-gallium systems

    Energy Technology Data Exchange (ETDEWEB)

    Henning, Robert [Iowa State Univ., Ames, IA (United States)

    1998-03-27

    Previous research into the alkali-metal-gallium systems has revealed a large variety of networked gallium deltahedra. The clusters are analogues to borane clusters and follow the same electronic requirements of 2n+2 skeletal electrons for closo-deltahedra. This work has focused on compounds that do not follow the typical electron counting rules. The first isolated gallium cluster was found in Cs8Ga11. The geometry of the Ga117- unit is not deltahedral but can be described as a penta-capped trigonal prism. The reduction of the charge from a closo-Ga1113- to Ga117- is believed to be the driving force of the distortion. The compound is paramagnetic because of an extra electron but incorporation of a halide atom into the structure captures the unpaired electron and forms a diamagnetic compound. A second isolated cluster has been found in Na10Ga10Ni where the tetra-capped trigonal prismatic gallium is centered by nickel. Stabilization of the cluster occurs through Ni-Ga bonding. A simple two-dimensional network occurs in the binary K2Ga3 Octahedra are connected through four waist atoms to form a layered structure with the potassium atoms sitting between the layers. Na30.5Ga60-xAgx is nonstoichiometric and needs only a small amount of silver to form (x ~ 2-6). The structure is composed of three different clusters which are interconnected to form a three-dimensional structure. The RbGa3-xAux system is also nonstoichiometric with a three-dimensional structure composed of Ga8 dodecahedra and four-bonded gallium atoms. Unlike Na30.5Ga60-xAgx, the RbGa3 binary is also stable. The binary is formally a Zintl phase but the ternary is not. Some chemistry in the alkali-metal-indium system also has been explored. A new potassium-indium binary

  14. Ion spatial distributions at the liquid-vapor interface of aqueous potassium fluoride solutions.

    Science.gov (United States)

    Brown, Matthew A; D'Auria, Raffaella; Kuo, I-F William; Krisch, Maria J; Starr, David E; Bluhm, Hendrik; Tobias, Douglas J; Hemminger, John C

    2008-08-28

    X-Ray photoemission spectroscopy operating under ambient pressure conditions is used to probe ion distributions throughout the interfacial region of a free-flowing aqueous liquid micro-jet of 6 M potassium fluoride. Varying the energy of the ejected photoelectrons by carrying out experiments as a function of X-ray wavelength measures the composition of the aqueous-vapor interfacial region at various depths. The F(-) to K(+) atomic ratio is equal to unity throughout the interfacial region to a depth of 2 nm. The experimental ion profiles are compared with the results of a classical molecular dynamics simulation of a 6 M aqueous KF solution employing polarizable potentials. The experimental results are in qualitative agreement with the simulations when integrated over an exponentially decaying probe depth characteristic of an APPES experiment. First principles molecular dynamics simulations have been used to calculate the potential of mean force for moving a fluoride anion across the air-water interface. The results show that the fluoride anion is repelled from the interface, consistent with the depletion of F(-) at the interface revealed by the APPES experiment and polarizable force field-based molecular dynamics simulation. Together, the APPES and MD simulation data provide a detailed description of the aqueous-vapor interface of alkali fluoride systems. This work offers the first direct observation of the ion distribution at an aqueous potassium fluoride solution interface. The current experimental results are compared to those previously obtained for saturated solutions of KBr and KI to underscore the strong difference in surface propensity between soft/large and hard/small halide ions in aqueous solution.

  15. An 80-W Laser Diode Array with 0.1 nm Linewidth for Rubidium Vapor Laser Pumping

    Institute of Scientific and Technical Information of China (English)

    YANG Zi-Ning; WANG Hong-Yan; LU Qi-Sheng; HUA Wei-Hong; XU Xiao-Jun

    2011-01-01

    The spectral linewidth of a 64-emitter laser-diode array is effectively suppressed by using a volume Bragg grating (VBG) based external cavity.At a maximal driven current of 90 A,the device produces a cw output of 80 W with 1.2 W/A slope efficiency and 0.1 nm spectral linewidth (FWHM) centered at 780 nm.The power extraction efficiency reaches 90% as compared with the free running case.The central wavelength of the narrowed spectrum is tuned over a 0.3nm range by adjusting the VBG's temperature.The absorption of 45% laser radiation by a 5-mm-long rubidium vapor cell with 150Torr ethane and 450 Torr helium at 383K is demonstrated.Diode pumped alkali vapor lasers (DPALs) have attracted much attention and have developed quickly in recent years due to their great potential in the high power laser field.[1-4] The efficient operation of DPALs requires pump sources with a linewidth that matches the pressure-broadened absorption band of alkali atoms.In moderate (~5 atm buffer gas) and low (~1 atm buffer gas) pressure operating regimes,the required pump linewidths should be 0.4 nm and less than 0.1 nm,respectively,[5] while the typical linewidth of commercial laser diode arrays (LDAs) is 2-4 nm.%The spectral linewidth of a 64-emitter laser-diode array is effectively suppressed by using a volume Bragg grating (VBG) based external cavity. At a maximal driven current of 90 A, the device produces a cw output of80W with 1.2 W/A slope efficiency and 0.1 nm spectral linewidth (FWHM) centered at 780 nm. The power extraction efficiency reaches 90% as compared with the free running case. The central wavelength of the narrowed spectrum is tuned over a 0.3nm range by adjusting the VBG's temperature. The absorption of 45% laser radiation by a 5-mm-long rubidium vapor cell with 150 Torr ethane and 450 Torr helium at 383 K is demonstrated.

  16. Recognizing nitrogen dopant atoms in graphene using atomic force microscopy

    DEFF Research Database (Denmark)

    van der Heijden, Nadine J.; Smith, Daniel; Calogero, Gaetano

    2016-01-01

    Doping graphene by heteroatoms such as nitrogen presents an attractive route to control the position of the Fermi level in the material. We prepared N-doped graphene on Cu(111) and Ir(111) surfaces via chemical vapor deposition of two different molecules. Using scanning tunneling microscopy images...... as a benchmark, we show that the position of the dopant atoms can be determined using atomic force microscopy. Specifically, the frequency shift-distance curves Delta f(z) acquired above a N atom are significantly different from the curves measured over a C atom. Similar behavior was found for N-doped graphene...

  17. Alkali and heavy metal emissions of the PCFB-process; Alkalipaeaestoet PCFB-prosessissa

    Energy Technology Data Exchange (ETDEWEB)

    Kuivalainen, R.; Eriksson, T.; Lehtonen, P. [Foster Wheeler Energia Oy, Karhula (Finland)

    1996-12-01

    Pressurized Circulating Fluidized Bed (PCFB) combustion technology has been developed in Karhula R and D Center since 1986. As a part of the development, 10 MW PCFB Test Facility was built in 1989. The Test Facility has been used for performance testing with different coal types through the years 1990-1995 in order to gain data for design and commercialization of the high-efficiency low-emission PCFB combustion technology. The project Y44 `Alkali and heavy metal emissions of the PCFB-process` was part of national LIEKKI 2 research program. The main object of the project was to measure vapor phase Na and K concentrations in the PCFB flue gas after hot gas filter and investigate the effects of process conditions and sorbents on alkali release. The measurements were performed using plasma assisted method by TUT Laboratory of Plasma Technology and wet absorption method of VTT Energy. The measured Na concentrations were below 30 ppb(w) in all measured data points. The results of K were below 10 ppb(w). The accuracies of the both methods are about + 50 % at this concentration range. The scatter of the data covers the effects of different process variables on the alkali emission. The measured emissions are at the same order of magnitude as the guideline emission limits estimated by gas turbine manufacturers. The measurements and development of the analyses methods are planned to be continued during PCFB test runs in spring 1996 for example within Joule II research program. (author)

  18. Alkali metal salts of formazanate ligands: diverse coordination modes as a result of the nitrogen-rich [NNCNN] ligand backbone.

    Science.gov (United States)

    Travieso-Puente, Raquel; Chang, Mu-Chieh; Otten, Edwin

    2014-12-28

    Alkali metal salts of redox-active formazanate ligands were prepared, and their structures in the solid-state and in solution are determined. The nitrogen-rich [NNCNN] backbone of formazanates results in a varied coordination chemistry, with both the internal and terminal nitrogen atoms available for bonding with the alkali metal. The potassium salt K[PhNNC(p-tol)NNPh]·2THF (1-K) is dimeric in the solid state and even in THF solution, as a result of the K atom bridging via interaction with a terminal N atom and the aromatic ring of a second unit. Conversely, for the compounds Na[MesNNC(CN)NNMes]·2THF (2-Na) and Na[PhNNC((t)Bu)NNPh] (3-Na) polymeric and hexameric structures are found in the solid state respectively. The preference for binding the alkali metal through internal N atoms (1-K and 2-Na) to give a 4-membered chelate, or via internal/external N atoms (5-membered chelate in 3-Na), contrasts with the 6-membered chelate mode observed in our recently reported formazanate zinc complexes.

  19. New bonding configuration on Si(111) and Ge(111) surfaces induced by the adsorption of alkali metals

    DEFF Research Database (Denmark)

    Lottermoser, L.; Landemark, E.; Smilgies, D.M.;

    1998-01-01

    The structure of the (3×1) reconstructions of the Si(111) and Ge(111) surfaces induced by adsorption of alkali metals has been determined on the basis of surface x-ray diffraction and low-energy electron diffraction measurements and density functional theory. The (3×1) surface results primarily f...... from the substrate reconstruction and shows a new bonding configuration consisting of consecutive fivefold and sixfold Si (Ge) rings in 〈11̅ 0〉 projection separated by channels containing the alkali metal atoms. © 1998 The American Physical Society......The structure of the (3×1) reconstructions of the Si(111) and Ge(111) surfaces induced by adsorption of alkali metals has been determined on the basis of surface x-ray diffraction and low-energy electron diffraction measurements and density functional theory. The (3×1) surface results primarily...

  20. Catalytically active Au-O(OH)x-species stabilized by alkali ions on zeolites and mesoporous oxides.

    Science.gov (United States)

    Yang, Ming; Li, Sha; Wang, Yuan; Herron, Jeffrey A; Xu, Ye; Allard, Lawrence F; Lee, Sungsik; Huang, Jun; Mavrikakis, Manos; Flytzani-Stephanopoulos, Maria

    2014-12-19

    We report that the addition of alkali ions (sodium or potassium) to gold on KLTL-zeolite and mesoporous MCM-41 silica stabilizes mononuclear gold in Au-O(OH)x-(Na or K) ensembles. This single-site gold species is active for the low-temperature (alkali ions and establishing an active site on various supports. The intrinsic activity of the single-site gold species is the same on irreducible supports as on reducible ceria, iron oxide, and titania supports, apparently all sharing a common, similarly structured gold active site. This finding paves the way for using earth-abundant supports to disperse and stabilize precious metal atoms with alkali additives for the WGS and potentially other fuel-processing reactions.

  1. Corollary from the Exact Expression for Enthalpy of Vaporization

    Directory of Open Access Journals (Sweden)

    A. A. Sobko

    2011-01-01

    Full Text Available A problem on determining effective volumes for atoms and molecules becomes actual due to rapidly developing nanotechnologies. In the present study an exact expression for enthalpy of vaporization is obtained, from which an exact expression is derived for effective volumes of atoms and molecules, and under certain assumptions on the form of an atom (molecule it is possible to find their linear dimensions. The accuracy is only determined by the accuracy of measurements of thermodynamic parameters at the critical point.

  2. Analysis of polarizability measurements made with atom interferometry

    CERN Document Server

    Gregoire, Maxwell D; Trubko, Raisa; Cronin, Alexander D

    2016-01-01

    We present revised measurements of the static electric dipole polarizabilities of K, Rb, and Cs based on atom interferometer experiments presented in [Phys. Rev. A 2015, 92, 052513] but now re-analyzed with new calibrations for the magnitude and geometry of the applied electric field gradient. The resulting polarizability values did not change, but the uncertainties were significantly reduced. Then we interpret several measurements of alkali metal atomic polarizabilities in terms of atomic oscillator strengths $f_{ik}$, Einstein coefficients $A_{ik}$, state lifetimes $\\tau_{k}$, transition dipole matrix elements $D_{ik}$, line strengths $S_{ik}$, and van der Waals $C_6$ coefficients. Finally, we combine atom interferometer measurements of polarizabilities with independent measurements of lifetimes and $C_6$ values in order to quantify the residual contribution to polarizability due to all atomic transitions other than the principal $ns$-$np_J$ transitions for alkali metal atoms.

  3. Analysis of Polarizability Measurements Made with Atom Interferometry

    Directory of Open Access Journals (Sweden)

    Maxwell D. Gregoire

    2016-07-01

    Full Text Available We present revised measurements of the static electric dipole polarizabilities of K, Rb, and Cs based on atom interferometer experiments presented in [Phys. Rev. A 2015, 92, 052513] but now re-analyzed with new calibrations for the magnitude and geometry of the applied electric field gradient. The resulting polarizability values did not change, but the uncertainties were significantly reduced. Then, we interpret several measurements of alkali metal atomic polarizabilities in terms of atomic oscillator strengths fik, Einstein coefficients Aik, state lifetimes τk, transition dipole matrix elements Dik, line strengths Sik, and van der Waals C6 coefficients. Finally, we combine atom interferometer measurements of polarizabilities with independent measurements of lifetimes and C6 values in order to quantify the residual contribution to polarizability due to all atomic transitions other than the principal ns-npJ transitions for alkali metal atoms.

  4. 40 CFR Table 6 to Subpart IIIii of... - Examples of Techniques for Equipment Problem Identification, Leak Detection and Mercury Vapor

    Science.gov (United States)

    2010-07-01

    ...; cracks or spalling in cell room floors, pillars, or beams; caustic leaks; liquid mercury accumulations or... Problem Identification, Leak Detection and Mercury Vapor 6 Table 6 to Subpart IIIII of Part 63 Protection... Hazardous Air Pollutants: Mercury Emissions From Mercury Cell Chlor-Alkali Plants Pt. 63, Subpt....

  5. Electrospray droplet exposure to organic vapors: metal ion removal from proteins and protein complexes.

    Science.gov (United States)

    DeMuth, J Corinne; McLuckey, Scott A

    2015-01-20

    The exposure of aqueous nanoelectrospray droplets to various organic vapors can dramatically reduce sodium adduction on protein ions in positive ion mass spectra. Volatile alcohols, such as methanol, ethanol, and isopropanol lead to a significant reduction in sodium ion adduction but are not as effective as acetonitrile, acetone, and ethyl acetate. Organic vapor exposure in the negative ion mode, on the other hand, has essentially no effect on alkali ion adduction. Evidence is presented to suggest that the mechanism by which organic vapor exposure reduces alkali ion adduction in the positive mode involves the depletion of alkali metal ions via ion evaporation of metal ions solvated with organic molecules. The early generation of metal/organic cluster ions during the droplet desolvation process results in fewer metal ions available to condense on the protein ions formed via the charged residue mechanism. These effects are demonstrated with holomyoglobin ions to illustrate that the metal ion reduction takes place without detectable protein denaturation, which might be revealed by heme loss or an increase in charge state distribution. No evidence is observed for denaturation with exposure to any of the organic vapors evaluated in this work.

  6. A Thermo-Chemical Reactor for analytical atomic spectrometry

    Science.gov (United States)

    Gilmutdinov, A. Kh.; Nagulin, K. Yu.

    2009-01-01

    A novel atomization/vaporization system for analytical atomic spectrometry is developed. It consists of two electrically and thermally separated parts that can be heated separately. Unlike conventional electrothermal atomizers in which atomization occurs immediately above the vaporization site and at the same instant of time, the proposed system allows analyte atomization via an intermediate stage of fractional condensation as a two stage process: Vaporization → Condensation → Atomization. The condensation step is selective since vaporized matrix constituents are mainly non-condensable gases and leave the system by diffusion while analyte species are trapped on the cold surface of a condenser. This kind of sample distillation keeps all the advantages of traditional electrothermal atomization and allows significant reduction of matrix interferences. Integration into one design a vaporizer, condenser and atomizer gives much more flexibility for in situ sample treatment and thus the system is called a Thermo-Chemical Reactor (TCR). Details of the design, temperature measurements, vaporization-condensation-atomization mechanisms of various elements in variety of matrices are investigated in the TCR with spectral, temporal and spatial resolution. The ability of the TCR to significantly reduce interferences and to conduct sample pyrolysis at much higher temperatures as compared to conventional electrothermal atomizers is demonstrated. The analytical potential of the system is shown when atomic absorption determination of Cd and Pb in citrus leaves and milk powder without the use of any chemical modification.

  7. Modulation of the work function of fullerenes C{sub 60} and C{sub 70} by alkali-metal adsorption: A theoretical study

    Energy Technology Data Exchange (ETDEWEB)

    Liang, Hong [Institute of Architecture and Engineering, Weifang University of Science and Technology, Weifang 262700 (China); Xu, Shunfu, E-mail: xushunfu2009@gmail.com [Institute of Architecture and Engineering, Weifang University of Science and Technology, Weifang 262700 (China); Department of Physics, Institute of Information Science and Engineering, Ocean University of China, Qingdao 266100 (China); Liu, Weihui [Department of Physics, Institute of Information Science and Engineering, Ocean University of China, Qingdao 266100 (China); Sun, Yueqiang; Liu, Xiangfa; Zheng, Xinqing; Li, Sen; Zhang, Qiang; Zhu, Ziliang; Zhang, Xiaochun; Dong, Chengguo [Institute of Architecture and Engineering, Weifang University of Science and Technology, Weifang 262700 (China); Li, Chun [Department of Physics, Institute of Information Science and Engineering, Ocean University of China, Qingdao 266100 (China); Yuan, Guang, E-mail: yuanguang@ouc.edu.cn [Department of Physics, Institute of Information Science and Engineering, Ocean University of China, Qingdao 266100 (China); Research Institute of Electronics, University of Shizuoka, Hamamasu 432-8011 (Japan); Mimura, Hitenori [Department of Physics, Institute of Information Science and Engineering, Ocean University of China, Qingdao 266100 (China)

    2013-11-15

    The impact of alkali-metal (Li/Na/Cs) adsorption on work function of fullerenes C{sub 60} and C{sub 70} was investigated by first-principles calculations. After adsorption, the work functions of fullerenes C{sub 60} and C{sub 70} decrease distinctly and vary linearly with the electronegativity of the alkali metal elements, and the positions where the alkali atoms are adsorbed considerably influence the work functions. On the contrary, a vacancy defect elevates the work functions of the fullerenes C{sub 60} and C{sub 70}. The variation in the work functions rests with variation in Fermi level (which are attributed to charge transfer) and variation in vacuum levels (which are attributed to the induced dipole moments). Moreover, alkali-metal adsorption can also improve the electric conductivity of a fullerene mixture of C{sub 60} and C{sub 70}.

  8. Optically pumped alkali laser and amplifier using helium-3 buffer gas

    Science.gov (United States)

    Beach, Raymond J.; Page, Ralph; Soules, Thomas; Stappaerts, Eddy; Wu, Sheldon Shao Quan

    2010-09-28

    In one embodiment, a laser oscillator is provided comprising an optical cavity, the optical cavity including a gain medium including an alkali vapor and a buffer gas, the buffer gas including .sup.3He gas, wherein if .sup.4He gas is also present in the buffer gas, the ratio of the concentration of the .sup.3He gas to the .sup.4He gas is greater than 1.37.times.10.sup.-6. Additionally, an optical excitation source is provided. Furthermore, the laser oscillator is capable of outputting radiation at a first frequency. In another embodiment, an apparatus is provided comprising a gain medium including an alkali vapor and a buffer gas including .sup.3He gas, wherein if .sup.4He gas is also present in the buffer gas, the ratio of the concentration of the .sup.3He gas to the .sup.4He gas is greater than 1.37.times.10.sup.-6. Other embodiments are also disclosed.

  9. Synthetic, structural, and theoretical investigations of alkali metal germanium hydrides--contact molecules and separated ions.

    Science.gov (United States)

    Teng, Weijie; Allis, Damian G; Ruhlandt-Senge, Karin

    2007-01-01

    The preparation of a series of crown ether ligated alkali metal (M=K, Rb, Cs) germyl derivatives M(crown ether)nGeH3 through the hydrolysis of the respective tris(trimethylsilyl)germanides is reported. Depending on the alkali metal and the crown ether diameter, the hydrides display either contact molecules or separated ions in the solid state, providing a unique structural insight into the geometry of the obscure GeH3- ion. Germyl derivatives displaying M--Ge bonds in the solid state are of the general formula [M([18]crown-6)(thf)GeH3] with M=K (1) and M=Rb (4). The compounds display an unexpected geometry with two of the GeH3 hydrogen atoms closely approaching the metal center, resulting in a partially inverted structure. Interestingly, the lone pair at germanium is not pointed towards the alkali metal, rather two of the three hydrides are approaching the alkali metal center to display M--H interactions. Separated ions display alkali metal cations bound to two crown ethers in a sandwich-type arrangement and non-coordinated GeH3- ions to afford complexes of the type [M(crown ether)2][GeH3] with M=K, crown ether=[15]crown-5 (2); M=K, crown ether=[12]crown-4 (3); and M=Cs, crown ether=[18]crown-6 (5). The highly reactive germyl derivatives were characterized by using X-ray crystallography, 1H and 13C NMR, and IR spectroscopy. Density functional theory (DFT) and second-order Møller-Plesset perturbation theory (MP2) calculations were performed to analyze the geometry of the GeH3- ion in the contact molecules 1 and 4.

  10. Orbital disproportionation of electronic density is a universal feature of alkali-doped fullerides

    Science.gov (United States)

    Iwahara, Naoya; Chibotaru, Liviu F.

    2016-10-01

    Alkali-doped fullerides show a wide range of electronic phases in function of alkali atoms and the degree of doping. Although the presence of strong electron correlations is well established, recent investigations also give evidence for dynamical Jahn-Teller instability in the insulating and the metallic trivalent fullerides. In this work, to reveal the interplay of these interactions in fullerides with even electrons, we address the electronic phase of tetravalent fulleride with accurate many-body calculations within a realistic electronic model including all basic interactions extracted from first principles. We find that the Jahn-Teller instability is always realized in these materials too. In sharp contrast to the correlated metals, tetravalent system displays uncorrelated band-insulating state despite similar interactions present in both fullerides. Our results show that the Jahn-Teller instability and the accompanying orbital disproportionation of electronic density in the degenerate lowest unoccupied molecular orbital band is a universal feature of fullerides.

  11. An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry.

    Science.gov (United States)

    Mulvey, Robert E

    2013-05-21

    This perspective article takes an alternative look at alkali-metal-mediated chemistry (exchange of a relatively inert C-H bond for a more reactive C-metal bond by a multicomponent reagent usually containing an alkali metal and a less electropositive metal such as magnesium or zinc). It pictures that the cleavage of selected C-H bonds can be accompanied by the capturing of the generated anion by the multi (Lewis acid)-(Lewis base) character of the residue of the bimetallic base. In this way small atoms or molecules (hydrides, oxygen-based anions) as well as sensitive organic anions (of substituted aromatic compounds, ethers or alkenes) can be captured. Cleave and capture reactions which occur in special positions on the organic substrate are also included.

  12. Rapid yet accurate first principle based predictions of alkali halide crystal phases using alchemical perturbation

    CERN Document Server

    Solovyeva, Alisa

    2016-01-01

    We assess the predictive power of alchemical perturbations for estimating fundamental properties in ionic crystals. Using density functional theory we have calculated formation energies, lattice constants, and bulk moduli for all sixteen iso-valence-electronic combinations of pure pristine alkali halides involving elements $A \\in \\{$Na, K, Rb, Cs$\\}$ and $X \\in \\{$F, Cl, Br, I$\\}$. For rock salt, zincblende and cesium chloride symmetry, alchemical Hellmann-Feynman derivatives, evaluated along lattice scans of sixteen reference crystals, have been obtained for all respective 16$\\times$15 combinations of reference and predicted target crystals. Mean absolute errors (MAE) are on par with density functional theory level of accuracy for energies and bulk modulus. Predicted lattice constants are less accurate. NaCl is the best reference salt for alchemical estimates of relative energies (MAE $<$ 40 meV/atom) while alkali fluorides are the worst. By contrast, lattice constants are predicted best using NaF as a re...

  13. Investigation on orientation, epitaxial growth and microstructure of a-axis-, c-axis-, (103)/(110)- and (113)-oriented YBa2Cu3O7-δ films prepared on (001), (110) and (111) SrTiO3 single crystal substrates by spray atomizing and coprecipitating laser chemical vapor deposition

    Science.gov (United States)

    Zhao, Pei; Wang, Ying; Huang, Zhi liang; Mao, Yangwu; Xu, Yuan Lai

    2015-04-01

    a-axis-, c-axis-, (103)/(110)- and (113)-oriented YBa2Cu3O7-δ (YBCO) films were pareared by spray atomizing and coprecipitating laser chemical vapor deposition. The surface of the a-axis-oriented YBCO film consisted of rectangular needle-like grains whose in-plane epitaxial growth relationship was YBCO [100] // STO [001] (YBCO [001] // STO [100]), and that of the c-axis-oriented YBCO film consisted of dense flat surface with epitaxial growth relationship of YBCO [001] // STO [001] (YBCO [100] //STO [100]). For the (103)/(110)-oriented and (113)-oriented YBCO film, they showed wedge-shaped and triangle-shaped grains, with corresponding in-plane epitaxial growth relationship of YBCO [110] // STO [110] (YBCO [010] // STO [010]) and YBCO [100] // STO [100] (YBCO [113] // STO [111], respectively.

  14. Molecular dynamics evidence for alkali-metal rattling in the β-pyrochlores, AOs2O6 (A = K, Rb, Cs).

    Science.gov (United States)

    Shoko, E; Peterson, V K; Kearley, G J

    2013-11-27

    We have used ab initio molecular dynamics simulations validated against inelastic neutron scattering data to study alkali-metal dynamics in the β-pyrochlore osmates AOs2O6 (A=K, Rb, Cs) at 300 K to gain insight into the microscopic nature of rattling dynamics in these materials. Our results provide new evidence at the microscopic level for rattling dynamics: (1) the elemental magnitude spectra calculated from the MD show a striking dominance by the alkali metals at low energies indicating weak coupling to the cage, (2) the atomic root-mean-square displacements for the alkali metals are significantly larger than for the other atoms, e.g., 25% and 150% larger than O and Os, respectively, in KOs2O6, and (3) motions of the alkali metals are weakly correlated to the dynamics in their immediate environment, e.g. K in KOs2O6 is 6 times less sensitive to its local environment than Os, indicating weak bonding of the K. There is broadening of the elemental spectra of the alkali metals from Cs to K corresponding to a similar broadening of the local potential around these atoms as determined from potential of mean-force calculations. This feature of the spectra is partly explained by the well-known increase in the relative cage volume with decreasing atomic size of the alkali metal. We find that for the smallest rattler in this series (K) the larger relative cage volume allows this atom freedom to explore a large space inside the cage leading to vibration at a broader range of frequencies, hence a broader spectrum. Thus, since K is considered the best rattler in this series, these findings suggest that a significant feature of a good rattler is the ability to vibrate at several different but closely spaced frequencies.

  15. On the applicability of jellium model to the description of alkali clusters

    DEFF Research Database (Denmark)

    Matveentsev, Anton; Lyalin, Andrey G.; Solov'yov, Ilia;

    2003-01-01

    This work is devoted to the elucidation of the applicability of the jellium model to the description of alkali cluster properties. We compare the jellium model results with those derived within ab initio theoretical approaches and with experiments. On the basis of Hartree–Fock and local-density a......This work is devoted to the elucidation of the applicability of the jellium model to the description of alkali cluster properties. We compare the jellium model results with those derived within ab initio theoretical approaches and with experiments. On the basis of Hartree–Fock and local......-density approximations we have calculated the binding energies per atom, ionization potentials, deformation parameters and optimized values of the Wigner–Seitz radii for neutral and singly charged sodium clusters with the number of atoms N... role of the cluster shape deformations in the formation cluster properties and quite reasonable level of applicability of the deformed jellium model. This elucidates the similarities of atomic cluster physics with the physics of atomic nuclei....

  16. Local structure of alkalis in mixed-alkali borate glass to elucidate the origin of mixed-alkali effect

    Directory of Open Access Journals (Sweden)

    Yomei Tokuda

    2015-12-01

    Full Text Available We report the structural analysis of Na+ and Cs+ in sodium cesium borate crystals and glasses using 23Na and 133Cs magic-angle spinning nuclear magnetic resonance (MAS NMR spectroscopy. The composition dependence of NMR spectra of the borate was similar to that of the silicate: (1 the peak position of cesium borate crystals shifted to upfield for structures with larger Cs+ coordination numbers, (2 the MAS NMR spectra of xNa2O-yCs2O-3B2O3 (x = 0, 0.25, 0.5, 0.75, 1.0, x + y = 1 glass showed that the average coordination number (CN of both the alkali cations decreases with increasing Cs+/(Na+ + Cs+ ratio. However, the degree of decrement in borates is much smaller than that in silicates. We have considered that the small difference in CN is due to 4-coordinated B, because it is electrically compensated by the alkali metal ions resulting in the restriction of having various coordinations of O to alkali metal.

  17. Optically Pumped Atomic Rubidium Lasers: Two-Photon and Exciplex Excitation Mechanisms

    Science.gov (United States)

    Gallagher, Jeffrey E.

    The Doppler-broadened two-photon absorption (TPA) cross-section for the 52S1/2 → 52 D5/2 transition in Rb is measured using direct absorption methods. The selection rule |DeltaF| ≤ 2 applied to both isotopes yields 17 transitions in 3 Doppler limited lines. A detailed model of the intensity profile was also developed to account for a focused Gaussian beam (with an M2 value of 1.09) propagating through a two-photon absorption medium. A peak absorbance of 24% was observed for an intensity of 6.28 kWcm2 at the focus, a Rb density of 4.6x1015 cm-3 , and a path length of 15 cm. Alkali concentrations from 1.61 - 8.52x1015 cm -3 were monitored in the far wing of the D 2 line. Extracting the hyperfine-broadened TPA cross-section from 87 test configurations, while varying the pump power, alkali concentration and focal length, yielded an error-weighted average of 6.75x10^-21 cm4W with a standard deviation of 3.61x10-21 cm4W. This cross-section is sufficient for a pulsed dye laser to bleach the pump transition in the Two-Photon Pumped Alkali Laser (TPAL) that lases at 420 nm and 5.2 microm. Optically pumped atomic rubidium lasers pumped in the blue satellite of the D2 line from the ground Rb-Ar or Rb-Kr collision pair to the dissociative B2S+1/2 state produce laser emission at 780.2 nm. Lasing is achieved for pump wavelengths of 752.3 to greater than 760 nm for the Rb-Ar system and 757.1 -- 760.4 nm for the Rb-Kr system. Slope efficiencies increase with both Rb and Ar concentrations and exceed 0.25% using a heat pipe configuration. The gain is very high with photon build-up times of 1--3.7 ns. Laser induced heating and subsequent condensation of alkali vapor in the heat pipe configuration currently limits operation to less than 2500 Torr.

  18. Removal of Retired Alkali Metal Test Systems

    Energy Technology Data Exchange (ETDEWEB)

    Brehm, W. F.; Church, W. R.; Biglin, J. W.

    2003-02-26

    This paper describes the successful effort to remove alkali metals, alkali metal residues, and piping and structures from retired non-radioactive test systems on the Hanford Site. These test systems were used between 1965 and 1982 to support the Fast Flux Test Facility and the Liquid Metal Fast Breeder Reactor Program. A considerable volume of sodium and sodium-potassium alloy (NaK) was successfully recycled to the commercial sector; structural material and electrical material such as wiring was also recycled. Innovative techniques were used to safely remove NaK and its residues from a test system that could not be gravity-drained. The work was done safely, with no environmental issues or significant schedule delays.

  19. Infrared spectra of FHF - in alkali halides

    Science.gov (United States)

    Chunnilall, C. J.; Sherman, W. F.

    1982-03-01

    The bifluoride ion, FHF -, has been substitutionally isolated within single crystal samples of several different alkali halides. Infrared spectra of these crystals have been studied for sample temperatures down to 8K when half-bandwidths of less than 1 cm -1 have been observed. (Note that at room temperature ν 3 is observed to have a half-bandwidth of about 40 cm -1). The frequency shifts and half-bandwidth changes caused by cooling are considered together with the frequency shifts caused by pressures up to 10 k bar. The low temperature spectra clearly indicate that FHF - is a linear symmetrical ion when substitutionally isolated within alkali halides of either the NaCl or CsCl structure.

  20. Pyrolysis characteristic of kenaf studied with separated tissues, alkali pulp, and alkali li

    Directory of Open Access Journals (Sweden)

    Yasuo Kojima

    2015-12-01

    Full Text Available To estimate the potential of kenaf as a new biomass source, analytical pyrolysis was performed using various kenaf tissues, i.e., alkali lignin and alkali pulp. The distribution of the pyrolysis products from the whole kenaf was similar to that obtained from hardwood, with syringol, 4-vinylsyringol, guaiacol, and 4-vinylguaiacol as the major products. The phenols content in the pyrolysate from the kenaf core was higher than that from the kenaf cuticle, reflecting the higher lignin content of the kenaf core. The ratios of the syringyl and guaiacyl compounds in the pyrolysates from the core and cuticle samples were 2.79 and 6.83, respectively. Levoglucosan was the major pyrolysis product obtained from the kenaf alkali pulp, although glycol aldehyde and acetol were also produced in high yields, as previously observed for other cellulosic materials. Moreover, the pathways for the formation of the major pyrolysis products from alkali lignin and alkali pulp were also described, and new pyrolysis pathways for carbohydrates have been proposed herein. The end groups of carbohydrates bearing hemiacetal groups were subjected to ring opening and then they underwent further reactions, including further thermal degradation or ring reclosing. Variation of the ring-closing position resulted in the production of different compounds, such as furans, furanones, and cyclopentenones.

  1. Sulfate Resistance of Alkali Activated Pozzolans

    OpenAIRE

    Bondar, Dali

    2015-01-01

    The consequence of sulfate attack on geopolymer concrete, made from an alkali activated natural pozzolan (AANP) has been studied in this paper. Changes in the compressive strength, expansion and capillary water absorption of specimens have been investigated combined with phases determination by means of X-ray diffraction. At the end of present investigation which was to evaluate the performance of natural alumina silica based geopolymer concrete in sodium and magnesium sulfate solution, the l...

  2. Effect of Mineral Admixtures on Alkali-Silica Reaction

    Institute of Scientific and Technical Information of China (English)

    ZHANG Chengzhi; WANG Aiqin

    2008-01-01

    The influence of silica fume,slag and fly ash on alkali-silica reaction under the condition of 70℃ is studied.The results show that silica,slag and fly ash may inhibit alkali-silica reaction only under suitable content.When the content is less than 10%,silica fume does not markedly influence the expansion of alkali-silica reaction.When the content is 15%-20%,silica fume only may delay the expansion of alkali-silica reaction.When the content is 30%-70%,slag may only delay the expansion of alkali-silica reaction,but cannot inhibit the expansion of alkali-silica reaction.When the content is 10%,fly ash does not markedly influence the expansion of alkali-silica reaction.When the content is 20%-30%,fly ash may only delay the expansion of alkali-silica reaction,but cannot inhibit the expansion of alkali-silica reaction.When the content is over 50%,it is possible that fly ash can inhibit effectively alkali-silica reaction.

  3. Clusters of atoms and molecules theory, experiment, and clusters of atoms

    CERN Document Server

    1994-01-01

    Clusters of Atoms and Molecules is devoted to theoretical concepts and experimental techniques important in the rapidly expanding field of cluster science. Cluster properties are dicussed for clusteres composed of alkali metals, semiconductors, transition metals, carbon, oxides and halides of alkali metals, rare gases, and neutral molecules. The book is composed of several well-integrated treatments all prepared by experts. Each contribution starts out as simple as possible and ends with the latest results so that the book can serve as a text for a course, an introduction into the field, or as a reference book for the expert.

  4. Measurement of the Kerr nonlinear refractive index of Cs vapor

    CERN Document Server

    Araújo, Michelle O; Oriá, Marcos; Chevrollier, Martine; de Silans, Thierry Passerat; Castro, Romeu; Moretti, Danieverton

    2014-01-01

    Atomic vapors are systems well suited for nonlinear optics studies but very few direct measurements of their nonlinear refractive index have been reported. Here we use the z-scan technique to measure the Kerr coefficient, $n_2$, for a Cs vapor. Our results are analyzed through a four-level model, and we show that coherence between excited levels as well as cross-population effects contribute to the Kerr-nonlinearity.

  5. Ion Pairing in Alkali Nitrate Electrolyte Solutions.

    Science.gov (United States)

    Xie, Wen Jun; Zhang, Zhen; Gao, Yi Qin

    2016-03-10

    In this study, we investigate the thermodynamics of alkali nitrate salt solutions, especially the formation of contact ion pairs between alkali cation and nitrate anion. The ion-pairing propensity shows an order of LiNO3 activity coefficients and suggest that the empirical "law of matching water affinity" is followed by these alkali nitrate salt solutions. The spatial patterns of contact ion pairs are different in the three salt solutions studied here: Li(+) forms the contact ion pair with only one oxygen of the nitrate while Na(+) and K(+) can also be shared by two oxygens of the nitrate. In reproducing the salt activity coefficient using Kirkwood-Buff theory, we find that it is essential to include electronic polarization for Li(+) which has a high charge density. The electronic continuum correction for nonpolarizable force field significantly improves the agreement between the calculated activity coefficients and their experimental values. This approach also improves the performance of the force field on salt solubility. From these two aspects, this study suggests that electronic continuum correction can be a promising approach to force-field development for ions with high charge densities.

  6. On the origin of alkali metals in Europa exosphere

    Science.gov (United States)

    Ozgurel, Ozge; Pauzat, Françoise; Ellinger, Yves; Markovits, Alexis; Mousis, Olivier; LCT, LAM

    2016-10-01

    At a time when Europa is considered as a plausible habitat for the development of an early form of life, of particular concern is the origin of neutral sodium and potassium atoms already detected in its exosphere (together with magnesium though in smaller abundance), since these atoms are known to be crucial for building the necessary bricks of prebiotic species. However their origin and history are still poorly understood. The most likely sources could be exogenous and result from the contamination produced by Io's intense volcanism and/or by meteoritic bombardment. These sources could also be endogenous if these volatile elements originate directly from Europa's icy mantle. Here we explore the possibility that neutral sodium and potassium atoms were delivered to the satellite's surface via the upwelling of ices formed in contact with the hidden ocean. These metallic elements would have been transferred as ions to the ocean at early epochs after Europa's formation, by direct contact of water with the rocky core. During Europa's subsequent cooling, the icy layers formed at the top of the ocean would have kept trapped the sodium and potassium, allowing their future progression to the surface and final identification in the exosphere of the satellite. To support this scenario, we have used chemistry numerical models based on first principle periodic density functional theory (DFT). These models are shown to be well adapted to the description of compact ice and are capable to describe the trapping and neutralization of the initial ions in the ice matrix. The process is found relevant for all the elements considered, alkali metals like Na and K, as well as for Mg and probably for Ca, their respective abundances depending essentially of their solubility and chemical capabilities to blend with water ices.

  7. Pretreated Butterfly Wings for Tuning the Selective Vapor Sensing

    Science.gov (United States)

    Piszter, Gábor; Kertész, Krisztián; Bálint, Zsolt; Biró, László Péter

    2016-01-01

    Photonic nanoarchitectures occurring in the scales of Blue butterflies are responsible for their vivid blue wing coloration. These nanoarchitectures are quasi-ordered nanocomposites which are constituted from a chitin matrix with embedded air holes. Therefore, they can act as chemically selective sensors due to their color changes when mixing volatile vapors in the surrounding atmosphere which condensate into the nanoarchitecture through capillary condensation. Using a home-built vapor-mixing setup, the spectral changes caused by the different air + vapor mixtures were efficiently characterized. It was found that the spectral shift is vapor-specific and proportional with the vapor concentration. We showed that the conformal modification of the scale surface by atomic layer deposition and by ethanol pretreatment can significantly alter the optical response and chemical selectivity, which points the way to the efficient production of sensor arrays based on the knowledge obtained through the investigation of modified butterfly wings. PMID:27618045

  8. Pretreated Butterfly Wings for Tuning the Selective Vapor Sensing

    Directory of Open Access Journals (Sweden)

    Gábor Piszter

    2016-09-01

    Full Text Available Photonic nanoarchitectures occurring in the scales of Blue butterflies are responsible for their vivid blue wing coloration. These nanoarchitectures are quasi-ordered nanocomposites which are constituted from a chitin matrix with embedded air holes. Therefore, they can act as chemically selective sensors due to their color changes when mixing volatile vapors in the surrounding atmosphere which condensate into the nanoarchitecture through capillary condensation. Using a home-built vapor-mixing setup, the spectral changes caused by the different air + vapor mixtures were efficiently characterized. It was found that the spectral shift is vapor-specific and proportional with the vapor concentration. We showed that the conformal modification of the scale surface by atomic layer deposition and by ethanol pretreatment can significantly alter the optical response and chemical selectivity, which points the way to the efficient production of sensor arrays based on the knowledge obtained through the investigation of modified butterfly wings.

  9. Alkali metal adsorption on Ge(0 0 1)-c(2 × 4) surface: 0.25 monolayer of Na, K, Rb and Cs

    Energy Technology Data Exchange (ETDEWEB)

    Stankiewicz, B., E-mail: bst@ifd.uni.wroc.pl [Institute of Experimental Physics, University of Wrocław, Pl. Maxa Borna 9, 50-204 Wrocław (Poland); Mikołajczyk, P. [Nokia Solutions and Networks, Gen. J. Bema Str. 2, 50-265 Wrocław (Poland)

    2014-05-01

    Highlights: • We examine alkali metals adsorption on the Ge(0 0 1)-c(2 × 4) surface. • We calculated atomic and electronic structures using local-orbital and plane-waves methods. • We simulated expected scanning tunneling microscopy images. - Abstract: Alkali metals on Ge(0 0 1) surface reveal different adsorption energy depending on the initial substrate reconstruction and the adsorption site. The theoretical analysis of adsorption of 0.25 monolayer of alkali metals (Na, K, Rb and Cs) on Ge(0 0 1)-c(2 × 4) surface is presented. Stable adsorption sites are found and adsorption energy, atomic and electronic structures are given. The simulated STM images are also presented for the discussed adsorbed surface structures.

  10. Vapor Control Layer Recommendations

    Energy Technology Data Exchange (ETDEWEB)

    None

    2009-09-08

    This information sheet describes the level of vapor control required on the interior side of framed walls with typical fibrous cavity insulation (fibreglass, rockwool, or cellulose, based on DOE climate zone of construction.

  11. Gasoline Vapor Recovery

    Science.gov (United States)

    1979-01-01

    Gasoline is volatile and some of it evaporates during storage, giving off hydrocarbon vapor. Formerly, the vapor was vented into the atmosphere but anti-pollution regulations have precluded that practice in many localities, so oil companies and storage terminals are installing systems to recover hydrocarbon vapor. Recovery provides an energy conservation bonus in that most of the vapor can be reconverted to gasoline. Two such recovery systems are shown in the accompanying photographs (mid-photo at right and in the foreground below). They are actually two models of the same system, although.configured differently because they are customized to users' needs. They were developed and are being manufactured by Edwards Engineering Corporation, Pompton Plains, New Jersey. NASA technological information proved useful in development of the equipment.

  12. Alkali-metal electron spin density shift induced by a helium nanodroplet

    Science.gov (United States)

    Koch, Markus; Callegari, Carlo; Ernst, Wolfgang E.

    2010-04-01

    Helium (He) nanodroplets provide a cold and virtually unperturbing environment for the study of weakly bound molecules and van der Waals aggregates. High resolution microwave spectroscopy and the detection of electron spin transitions in doped He droplets have recently become possible. Measurements of hyperfine-resolved electron spin resonance in potassium (39K) and rubidium (85Rb) atoms on the surface of He droplets show small line shifts relative to the bare atoms. These shifts were recorded for all 2I + 1 components (I is the nuclear spin) of a transition at high accuracy for He droplets ranging in size from 1000 to 15,000 He atoms. Evaluation of the spectra yields the influence of the He environment on the electron spin density at the alkali-metal nucleus. A semi-empirical model is presented that shows good qualitative agreement with the measured droplet size dependent increase of Fermi contact interaction at the nuclei of dopant K and Rb.

  13. Laser spectroscopy of atoms in superfluid helium for the measurement of nuclear spins and electromagnetic moments of radioactive atoms

    Energy Technology Data Exchange (ETDEWEB)

    Fujita, T., E-mail: tomomi.fujita@riken.jp [Osaka University, Department of Physics (Japan); Furukawa, T. [Tokyo Metropolitan University, Department of Physics (Japan); Imamura, K.; Yang, X. F. [RIKEN Nishina Center (Japan); Hatakeyama, A. [Tokyo University of Agriculture and Technology, Department of Applied Physics (Japan); Kobayashi, T. [RIKEN Center for Advanced Photonics (Japan); Ueno, H. [RIKEN Nishina Center (Japan); Asahi, K. [Tokyo Institute of Technology, Department of Physics (Japan); Shimoda, T. [Osaka University, Department of Physics (Japan); Matsuo, Y. [Hosei University, Department of Advanced Sciences (Japan); Collaboration: OROCHI Collaboration

    2015-11-15

    A new laser spectroscopic method named “OROCHI (Optical RI-atom Observation in Condensed Helium as Ion catcher)” has been developed for deriving the nuclear spins and electromagnetic moments of low-yield exotic nuclei. In this method, we observe atomic Zeeman and hyperfine structures using laser-radio-frequency/microwave double-resonance spectroscopy. In our previous works, double-resonance spectroscopy was performed successfully with laser-sputtered stable atoms including non-alkali Au atoms as well as alkali Rb and Cs atoms. Following these works, measurements with {sup 84−87}Rb energetic ion beams were carried out in the RIKEN projectile fragment separator (RIPS). In this paper, we report the present status of OROCHI and discuss its feasibility, especially for low-yield nuclei such as unstable Au isotopes.

  14. Two-Pulse Atomic Coherent Control (2PACC) Spectroscopy of Eley-Rideal Reactions. An Application of an Atom Laser

    CERN Document Server

    Jorgensen, S F; Jorgensen, Solvejg; Kosloff, Ronnie

    2003-01-01

    A spectroscopic application of the atom laser is suggested. The spectroscopy termed 2PACC employs the coherent properties of matter-waves from a two pulse atom laser. These waves are employed to control a gas-surface chemical recombination reaction. The method is demonstrated for an Eley-Rideal reaction of a hydrogen or alkali atom-laser pulse where the surface target is an adsorbed hydrogen atom. The reaction yields either a hydrogen or alkali hydride molecule. The desorbed gas phase molecular yield and its internal state is shown to be controlled by the time and phase delay between two atom-laser pulses. The calculation is based on solving the time-dependent Schrodinger equation in a diabatic framework. The probability of desorption which is the predicted 2PACC signal has been calculated as a function of the pulse parameters.

  15. Thermalization of different alkali and alkali-earth elements at the TRI{mu}P facility

    Energy Technology Data Exchange (ETDEWEB)

    Shidling, P.D., E-mail: P.Shidling@rug.n [Kernfysisch Versneller Instituut, University of Groningen, Zernikelaan 25, 9747 AA Groningen (Netherlands); Giri, G.S.; Hoek, D.J. van der; Jungmann, K.; Kruithof, W.L.; Onderwater, C.J.G.; Santra, B.; Sohani, M.; Versolato, O.O.; Willmann, L.; Wilschut, H.W. [Kernfysisch Versneller Instituut, University of Groningen, Zernikelaan 25, 9747 AA Groningen (Netherlands)

    2010-10-01

    Radioactive isotopes produced by the in-flight method are converted into low-energy ions with a thermal ionizer (TI) ion catcher, the operation of which is based on a hot cavity ion source. The extraction efficiency of the TI for different alkali and alkali-earth elements has been studied and compared to a model based on diffusion only. The model describes the stationary limit, i.e. the extraction efficiency, as well as the dynamic response of the TI output when the primary beam is switched on and off.

  16. Direct synthesis of large area graphene on insulating substrate by gallium vapor-assisted chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Murakami, Katsuhisa, E-mail: k.murakami@bk.tsukuba.ac.jp; Hiyama, Takaki; Kuwajima, Tomoya; Fujita, Jun-ichi [Institute of Applied Physics, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8573 (Japan); Tsukuba Research Center for Interdisciplinary Materials Science, University of Tsukuba, Tsukuba 305-8573 (Japan); Tanaka, Shunsuke; Hirukawa, Ayaka [Institute of Applied Physics, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8573 (Japan); Kano, Emi [Institute of Applied Physics, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8573 (Japan); National Institute for Materials Science, Tsukuba 305-0047 (Japan); Takeguchi, Masaki [National Institute for Materials Science, Tsukuba 305-0047 (Japan)

    2015-03-02

    A single layer of graphene with dimensions of 20 mm × 20 mm was grown directly on an insulating substrate by chemical vapor deposition using Ga vapor catalysts. The graphene layer showed highly homogeneous crystal quality over a large area on the insulating substrate. The crystal quality of the graphene was measured by Raman spectroscopy and was found to improve with increasing Ga vapor density on the reaction area. High-resolution transmission electron microscopy observations showed that the synthesized graphene had a perfect atomic-scale crystal structure within its grains, which ranged in size from 50 nm to 200 nm.

  17. The spectroscopy in the atomic vapour

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jai Hyung; Chang, Joon Sung; Jhe, Won Ho [Seoul National University, Seoul (Korea)

    1998-04-01

    As spectroscopies in the atomic vapor, we perform experiments on fluorescence in dense atomic vapor, single color two-photon resonant three photon ionization, production of high temperature oven and its spectroscopic application, atomic trap and cold atomic beam. We observe lengthening of lifetime as atomic density increase and compare this result with Holstein equation. Dependence on pressure an d polarization reveals the result is due to collisions between Yb atom and Ar buffer gas. At high atomic density, self-focusing and conical emission are observed. In two-photon resonant three photon ionization scheme, ionization rate is dependent on polarization. From selection rule, we determined the energy level. At higher energy, asymmetry and broadening of ionization linewidth due to AC Stark effect are observed. As the result of numerical simulation of time evolution in the two-photon transition, distortion of time evolution of density is obtained. For spectroscopy of high-melting-point elements, we design and produce high temperature oven. We observe absorption spectra of high-melting-point elements, Er and Sm. As high temperature nonlinear spectroscopies, we perform conical emission and self-diffraction in Sm vapor. We produce magneto-optical trap system and measure fluorescence from trapped atoms and temperature. By trapping Rb isotopes simultaneously, we perform collision experiment at low temperature. Using hollow mirror system, we trap atoms and produce cold atomic beam. (author). 160 refs., 66 figs., 5 tabs.

  18. Effective oscillator strength distributions of spherically symmetric atoms for calculating polarizabilities and long-range atom–atom interactions

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, Jun, E-mail: phyjiang@yeah.net [Key Laboratory of Atomic and Molecular Physics and Functional Materials of Gansu Province, College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou 730070 (China); School of Engineering, Charles Darwin University, Darwin, Northern Territory, 0909 (Australia); Mitroy, J. [School of Engineering, Charles Darwin University, Darwin, Northern Territory, 0909 (Australia); Cheng, Yongjun, E-mail: cyj83mail@gmail.com [School of Engineering, Charles Darwin University, Darwin, Northern Territory, 0909 (Australia); Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Harbin 150080 (China); Bromley, M.W.J., E-mail: brom@physics.uq.edu.au [School of Mathematics and Physics, The University of Queensland, Brisbane, Queensland 4075 (Australia)

    2015-01-15

    Effective oscillator strength distributions are systematically generated and tabulated for the alkali atoms, the alkaline-earth atoms, the alkaline-earth ions, the rare gases and some miscellaneous atoms. These effective distributions are used to compute the dipole, quadrupole and octupole static polarizabilities, and are then applied to the calculation of the dynamic polarizabilities at imaginary frequencies. These polarizabilities can be used to determine the long-range C{sub 6}, C{sub 8} and C{sub 10} atom–atom interactions for the dimers formed from any of these atoms and ions, and we present tables covering all of these combinations.

  19. Characterization of high-temperature performance of cesium vapor cells with anti-relaxation coating

    CERN Document Server

    Li, Wenhao; Peng, Xiang; Pustelny, Szymon; Wickenbrock, Arne; Guo, Hong; Budker, Dmitry

    2016-01-01

    Vapor cells with antirelaxation coating are widely used in modern atomic physics experiments due to the coating's ability to maintain the atoms' spin polarization during wall collisions. We characterize the performance of vapor cells with different coating materials by measuring longitudinal spin relaxation and vapor density at temperatures up to 95{\\deg}C. We found that the spin-projection-noise-limited sensitivity for atomic magnetometers with such cells improves with temperature, which demonstrates the potential of antirelaxation coated cells in applications of future high-sensitivity magnetometers.

  20. Characterization of high-temperature performance of cesium vapor cells with anti-relaxation coating

    Science.gov (United States)

    Li, Wenhao; Balabas, Mikhail; Peng, Xiang; Pustelny, Szymon; Wickenbrock, Arne; Guo, Hong; Budker, Dmitry

    2017-02-01

    Vapor cells with antirelaxation coating are widely used in modern atomic physics experiments due to the coating's ability to maintain the atoms' spin polarization during wall collisions. We characterize the performance of vapor cells with different coating materials by measuring longitudinal spin relaxation and vapor density at temperatures up to 95 °C. We infer that the spin-projection-noise-limited sensitivity for atomic magnetometers with such cells improves with temperature, which demonstrates the potential of antirelaxation coated cells in applications of future high-sensitivity magnetometers.

  1. Alkali cation specific adsorption onto fcc(111) transition metal electrodes.

    Science.gov (United States)

    Mills, J N; McCrum, I T; Janik, M J

    2014-07-21

    The presence of alkali cations in electrolyte solutions is known to impact the rate of electrocatalytic reactions, though the mechanism of such impact is not conclusively determined. We use density functional theory (DFT) to examine the specific adsorption of alkali cations to fcc(111) electrode surfaces, as specific adsorption may block catalyst sites or otherwise impact surface catalytic chemistry. Solvation of the cation-metal surface structure was investigated using explicit water models. Computed equilibrium potentials for alkali cation adsorption suggest that alkali and alkaline earth cations will specifically adsorb onto Pt(111) and Pd(111) surfaces in the potential range of hydrogen oxidation and hydrogen evolution catalysis in alkaline solutions.

  2. Alkali metal control over N-N cleavage in iron complexes.

    Science.gov (United States)

    Grubel, Katarzyna; Brennessel, William W; Mercado, Brandon Q; Holland, Patrick L

    2014-12-03

    Though N2 cleavage on K-promoted Fe surfaces is important in the large-scale Haber-Bosch process, there is still ambiguity about the number of Fe atoms involved during the N-N cleaving step and the interactions responsible for the promoting ability of K. This work explores a molecular Fe system for N2 reduction, particularly focusing on the differences in the results obtained using different alkali metals as reductants (Na, K, Rb, Cs). The products of these reactions feature new types of Fe-N2 and Fe-nitride cores. Surprisingly, adding more equivalents of reductant to the system gives a product in which the N-N bond is not cleaved, indicating that the reducing power is not the most important factor that determines the extent of N2 activation. On the other hand, the results suggest that the size of the alkali metal cation can control the number of Fe atoms that can approach N2, which in turn controls the ability to achieve N2 cleavage. The accumulated results indicate that cleaving the triple N-N bond to nitrides is facilitated by simultaneous approach of least three low-valent Fe atoms to a single molecule of N2.

  3. Enthalpic Interaction for α-Amino Acid with Alkali Metal Halides in Water

    Institute of Scientific and Technical Information of China (English)

    LU,Yan(卢雁)

    2004-01-01

    The studies of the enthalpic interaction parameters, hxy, hxyy and hxxv, of alkali metal halides with glycine,α-alanine and α-aminobutyric acid were published. Synthetic considering of the results of the studies, some interesting behaviors of the interaction between alkali metal halides and the α-amino acids have been found. The values of hxy will increase with the increase of the number of carbon atoms in alkyl side chain of amino acid molecules and decrease with the increase of the radius of the ions. The increasing of the salt's effect on the hydrophobic hydration structure as the radii of anion is more obvious than as that of cation. The value of hxxy will regularly decrease with the increase of the number of carbon atoms in the alkyl chain of amino acids and linear increase with the increase of the radius. But the relation of hxxy with the radius of cations is not evident. The value of hxyy will increase with the increase of the radii of the ions. As the increase of the number of carbon atoms of amino acids, hxyy is decreas for the ions which have lager size and there is a maximum value at α-alanine for the ions which have small size. The behaviors of the interaction mentioned above were further discussed in view of electrostatic and structural interactions.

  4. Low Energy Atomic Photodesorption from Organic Coatings

    Directory of Open Access Journals (Sweden)

    Alessandro Lucchesini

    2016-10-01

    Full Text Available Organic coatings have been widely used in atomic physics during the last 50 years because of their mechanical properties, allowing preservation of atomic spins after collisions. Nevertheless, this did not produce detailed insight into the characteristics of the coatings and their dynamical interaction with atomic vapors. This has changed since the 1990s, when their adsorption and desorption properties triggered a renewed interest in organic coatings. In particular, a novel class of phenomena produced by non-destructive light-induced desorption of atoms embedded in the coating surface was observed and later applied in different fields. Nowadays, low energy non-resonant atomic photodesorption from organic coatings can be considered an almost standard technique whenever large densities of atomic vapors or fast modulation of their concentration are required. In this paper, we review the steps that led to this widespread diffusion, from the preliminary observations to some of the most recent applications in fundamental and applied physics.

  5. The Physics of Miniature Atomic Clocks: 0-0 Versus "End" Transitions

    Science.gov (United States)

    Post, Amber; Jau, Yuan-Yu; Kuzma, Nicholas; Happer, William

    2003-05-01

    The majority of traditional atomic-clock designs are based on the 0-0 hyperfine transition of a Cs 133 atom. We are currently investigating the advantages of operating a miniature optical atomic clock using the "end" transitions, e.g. connecting states |f=1, mf =+/-1> and |f=2, mf=+/-2> in 87Rb. In our paper we present extensive new measurements of relevant relaxation rates, such as those due to spin-exchange collisions, buffer-gas pressure shifts, Carver Rates and others, which ultimately determine the choices of an operating regime for the miniature optical atomic clock. The relationship between these rates is non-trivial: for example, using higher laser power will increase polarization and reduce the spin-exchange rate [1], but it can simultaneously increase the linewidth due to the optical pumping rate. The dependence of these and other relaxation rates on the cell size, temperature, pressure, a choice of buffer gas, and other parameters will be reported. Based on these measured rates, our modeling can be used to predict the transition linewidths, signal-to-noise ratios and thus the stability of the clock in different operating regimes. The trade-off between the stability of the clock and the desired small cell size and low power consumption needs to be carefully considered in order to optimize our design. In our experiments we used optical, microwave, and radio-frequency excitation to study hyperfine and Zeeman resonance lines in heated glass cells containing pure-isotope alkali-metal vapor and buffer gasses (N2, Ar, He, etc.) at low (0 - 10 G) magnetic fields. Simultaneous use of light, microwave and radio-frequency fields allowed us to calibrate surrounding magnetic fields by observing the corresponding shifts of the resonance, thus leading us to a quantitative understanding of our system. [1] S. Appelt, A. B. Baranga, A. R. Young, W. Happer, Phys. Rev. A 59, 2078 (1999).

  6. A contribution to the surface characterization of alkali metal sulfates

    Energy Technology Data Exchange (ETDEWEB)

    Fantauzzi, Marzia; Rigoldi, Americo; Elsener, Bernhard; Atzei, Davide; Rossi, Antonella, E-mail: rossi@unica.it

    2014-03-01

    s peaks. In the chemical state plot the alkali sulfates fall on a line with an Auger parameter of ca. 2275 eV whereas elemental sulfur is found at 2277 eV. A shift of 0.6 eV in the calculated Auger parameter α′ is observed from 2274.7 ± 0.1 eV for Li to 2275.3 ± 0.2 eV for Cs sulfate. These results are discussed with respect to the influence of the cation using fundamental data and concepts such as ion radius, oxidation state and ionization energy, and separating intra-atomic and inter-atomic effects. All the information show a relatively small interaction between the sulfate anion and the cations as a consequence of the strong group localization of the valence states over the sulfate tetrahedron. The sulfur SKLL spectrum of sulfates and elemental sulfur consisting of an intense {sup 1}D and a low intensity {sup 1}S contribution with constant energy difference of 8 eV can be considered a first step toward curve fitting of multicomponent sulfur SKLL spectra and the interpretation of complex mechanisms of oxidation and dissolution that involve sulfur.

  7. The Mixed-Alkali Effect on The Resistance of Glass to Water

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Based on the composition of float glass, the resistance of glass to water, in which a small amount of K2O (0—1.0 wt%) was substituted for equivalent amount of Na2O, was investigated by means of glass grains testing. The components extracted from the glass and total alkalinities in extraction solution were determined by atomic absorption spectroscopy and neutralizing method, respectively. The composition of the glass was 14.4 K2O+Na2O, 4.0MgO, 8.2CaO, 1.4Al2O3, 72.0 SiO2, and the minimum extraction ratio of oxides (maximum durability) occurred at a K2O/Na2O ratio of 0.051(by weight) due to the presence of the mixed-alkali effect. The relative extraction ratio of alkali oxides (R2O) was greater than that of alkaline earth oxides (RO). By means of mixed-alkali effect and lowing relative contents of R2O in the glass, the resistance of float glass to water was improved and its mildew-proof ability was therefore increased.

  8. Shortcuts for understanding rovibronic spectroscopy of ultracold alkali metal diatomic molecules

    Science.gov (United States)

    Stwalley, William C.; Bellos, Michael; Carollo, Ryan; Banerjee, Jayita; Bermudez, Matthew

    2012-08-01

    The high-resolution rovibronic spectroscopies of cold and ultracold molecules (e.g. supersonic molecular beam excitation spectra (MB), photoassociation spectra of ultracold atoms (PA), resonance-enhanced multiphoton ionization spectra (REMPI), stimulated Raman transfer (SRT) spectra) are of major current interest. This manuscript summarizes the significant level of understanding of these various spectroscopies, enabled by using simple graphical and semiclassical ideas and shortcuts. Physical realizations of these spectroscopies will be illustrated using the alkali metal diatomic molecules, both homonuclear (e.g. Rb2) and heteronuclear (e.g. KRb).

  9. The effect of atoms excited by electron beam on metal evaporation

    CERN Document Server

    Xie Guo Feng; Ying Chun Tong

    2002-01-01

    In atomic vapor laser isotope separation (AVLIS), the metal is heated to melt by electron beams. The vapor atoms may be excited by electrons when flying through the electron beam. The excited atoms may be deexcited by inelastic collision during expansion. The electronic energy transfers translational energy. In order to analyse the effect of reaction between atoms and electron beams on vapor physical parameters, such as density, velocity and temperature, direct-simulation Monte Carlo method (DSMC) is used to simulate the 2-D gadolinium evaporation from long and narrow crucible. The simulation results show that the velocity and temperature of vapor increase, and the density decreases

  10. Collisional broadening of alkali doublets by helium perturbers

    CERN Document Server

    Mullamphy, D F T; Peach, G; Venturi, V; Whittingham, I B

    2006-01-01

    We report results for the Lorentzian profiles of the Li I, Na I and K I doublets and the Na I subordinate doublet broadened by helium perturbers for temperatures up to 3000 K They have been obtained from a fully quantum-mechanical close-coupling description of the colliding atoms, the Baranger theory of line shapes and new ab initio potentials for the alkali-helium interaction. For all lines except the 769.9 nm K I line, the temperature dependence of the widths over the range 70 < T < 3000 K is accurately represented by the power law form w=aT^b with 0.37 < b < 0.43. The 769.9 K I line has this form for 500 < T < 3000 K with b = 0.49. Although the shifts have a more complex temperature dependence, they all have the general feature of increasing with temperature above T=500 K apart from the 769.9 K I line whose shift decreases with temperature.

  11. Structural properties of low-density liquid alkali metals

    Indian Academy of Sciences (India)

    A Akande; G A Adebayo; O Akinlade

    2005-12-01

    The static structure factors of liquid alkali metals have been modelled at temperatures close to their melting points and a few higher temperatures using the reverse Monte Carlo (RMC) method. The positions of 5000 atoms in a box, with full periodicity, were altered until the experimental diffraction data of the structure factor agrees with the associated model structure factor within the errors. The model generated is then analysed. The position of the first peak of the pair distribution function () does not show any significant temperature dependence and the mean bond lengths can be approximated within an interval of 3.6–5.3 Å, 4.5–6.6 Å, 4.8–6.7 Å and 5.1–7.3 Å for Na, K, Rb and Cs respectively. The cosine bond distributions show similar trend with the flattening up of the first peak with increase in temperature. In addition, the coordination numbers of these liquid metals are high due to the presence of non-covalent bonding between them. On the average, we surmise that the coordination number decreases with increase in temperature.

  12. Alkali-crown ether complexes at metal surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Thontasen, Nicha; Deng, Zhitao; Rauschenbach, Stephan [Max Planck Institute for Solid State Research, Stuttgart (Germany); Levita, Giacomo [University of Trieste, Trieste (Italy); Malinowski, Nikola [Max Planck Institute for Solid State Research, Stuttgart (Germany); Bulgarian Academy of Sciences, Sofia (Bulgaria); Kern, Klaus [Max Planck Institute for Solid State Research, Stuttgart (Germany); EPFL, Lausanne (Switzerland)

    2010-07-01

    Crown ethers are polycyclic ethers which, in solution, selectively bind cations depending on the size of the ring cavity. The study of a single host-guest complex is highly desirable in order to reveal the characteristics of these specific interactions at the atomic scale. Such detailed investigation is possible at the surface where high resolution imaging tools like scanning tunneling microscopy (STM) can be applied. Here, electrospray ion beam deposition (ES-IBD) is employed for the deposition of Dibenzo-24-crown-8 (DB24C8)-H{sup +}, -Na{sup +} and -Cs{sup +} complexes on a solid surface in ultrahigh vacuum (UHV). Where other deposition techniques have not been successful, this deposition technique combines the advantages of solution based preparation of the complex ions with a highly clean and controlled deposition in UHV. Single molecular structures and the cation-binding of DB24C8 at the surface are studied in situ by STM and MALDI-MS (matrix assisted laser desorption ionization mass spectrometry). The internal structure of the complex, i.e. ring and cavity, is observable only when alkali cations are incorporated. The BD24C8-H{sup +} complex in contrast appears as a compact feature. This result is in good agreement with theoretical models based on density functional theory calculations.

  13. Vapor pressures and enthalpies of vaporization of azides

    Energy Technology Data Exchange (ETDEWEB)

    Verevkin, Sergey P., E-mail: sergey.verevkin@uni-rostock.de [Department of Physical Chemistry, University of Rostock, Dr-Lorenz-Weg 1, D-18059 Rostock (Germany); Emel' yanenko, Vladimir N. [Department of Physical Chemistry, University of Rostock, Dr-Lorenz-Weg 1, D-18059 Rostock (Germany); Algarra, Manuel [Centro de Geologia do Porto, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre 687, 4169-007 Porto (Portugal); Manuel Lopez-Romero, J. [Department of Organic Chemistry, University of Malaga. Campus de Teatinos s/n, 29071 Malaga (Spain); Aguiar, Fabio; Enrique Rodriguez-Borges, J.; Esteves da Silva, Joaquim C.G. [Centro de Investigacao em Quimica (CIQ-UP), Faculdade de Ciencias da Universidade do Porto, Rua do Campo Alegre 687, 4169-007 Porto (Portugal)

    2011-11-15

    Highlights: > We prepared and measured vapor pressures and vaporization enthalpies of 7 azides. > We examined consistency of new and available in the literature data. > Data for geminal azides and azido-alkanes selected for thermochemical calculations. - Abstract: Vapor pressures of some azides have been determined by the transpiration method. The molar enthalpies of vaporization {Delta}{sub l}{sup g}H{sub m} of these compounds were derived from the temperature dependencies of vapor pressures. The measured data sets were successfully checked for internal consistency by comparison with vaporization enthalpies of similarly structured compounds.

  14. Observation of light dragging in rubidium vapor cell

    CERN Document Server

    Strekalov, D V; Yu, N; Maleki, L; Strekalov, Dmitry; Matsko, Andrey B.; Yu, Nan; Maleki, Lute

    2003-01-01

    We report on the experimental demonstration of light dragging effect due to atomic motion in a rubidium vapor cell. We found that the minimum group velocity is achieved for light red-shifted from the center of the atomic resonance, and that the value of this shift increases with decreasing group velocity, in agreement with the theoretical predictions by Kocharovskaya, Rostovtsev, and Scully [Phys. Rev. Lett. {\\bf 86}, 628 (2001)].

  15. Control of inhomogeneous atomic ensembles of hyperfine qudits

    DEFF Research Database (Denmark)

    Mischuck, Brian Edward; Merkel, Seth T.; Deutsch, Ivan H.

    2012-01-01

    We study the ability to control d-dimensional quantum systems (qudits) encoded in the hyperfine spin of alkali-metal atoms through the application of radio- and microwave-frequency magnetic fields in the presence of inhomogeneities in amplitude and detuning. Such a capability is essential...

  16. Durability of Alkali Activated Blast Furnace Slag

    Science.gov (United States)

    Ellis, K.; Alharbi, N.; Matheu, P. S.; Varela, B.; Hailstone, R.

    2015-11-01

    The alkali activation of blast furnace slag has the potential to reduce the environmental impact of cementitious materials and to be applied in geographic zones where weather is a factor that negatively affects performance of materials based on Ordinary Portland Cement. The scientific literature provides many examples of alkali activated slag with high compressive strengths; however research into the durability and resistance to aggressive environments is still necessary for applications in harsh weather conditions. In this study two design mixes of blast furnace slag with mine tailings were activated with a potassium based solution. The design mixes were characterized by scanning electron microscopy, BET analysis and compressive strength testing. Freeze-thaw testing up to 100 freeze-thaw cycles was performed in 10% road salt solution. Our findings included compressive strength of up to 100 MPa after 28 days of curing and 120 MPa after freeze-thaw testing. The relationship between pore size, compressive strength, and compressive strength after freeze-thaw was explored.

  17. Laser Spectroscopy of bi-alkali molecules

    Science.gov (United States)

    Dutta, Sourav; Altaf, A.; Lorenz, J.; Elliott, D.; Chen, Yong

    2010-03-01

    We report a study of laser spectroscopy of bi-alkali molecules, such as Li2, Rb2 and LiRb (work is in progress). We have constructed a dual-species (Li/Rb) heat pipe oven with a side viewport. The molecular fluorescence is excited by a dye laser with Rh6G dye (operating between 564 nm and 610 nm) and various home-made diode lasers (operating near 635 nm and 665 nm). The fluorescence is recorded using a .5ex1 -.1em/ -.15em.25ex4 m monochromator with a 0.1 nm (˜ 3 cm-1) spectral resolution. Transitions to the X^1σg^+ in Li2 and Rb2 have been measured and studies on LiRb are in progress. Molecular parameters, such as force constant, may be obtained from the analysis of the data (which agree with previously known values to within ˜ 3%). Using the known values of dissociation energy De and harmonic frequency φe for the alkali dimers, we also demonstrate that simple calculations with Morse potential approximation can be used to estimate the molecular transition wavelengths to within a few (1-3) nanometers from the experimentally measured values. Such information will aid in creating cold molecules via photoassociation in a dual species magneto-optical trap (LiRb in our case).

  18. Pathways of birnessite formation in alkali medium

    Institute of Scientific and Technical Information of China (English)

    FENG Xionghan; TAN Wenfeng; LIU Fan; HUANG Qiaoyun; LIU Xiangwen

    2005-01-01

    Birnessite is a common weathering and oxidation product of manganese-bearing rocks. An O2 oxidation procedure of Mn(OH)2 in the alkali medium has been used to synthesize birnessite. Fast and powder X-ray diffraction (XRD), transmission electron microscopy (TEM), electron diffraction (ED), energy dispersed X-ray analysis (EDAX), infrared spectroscopy (IR) techniques and chemical composition analysis, Eh-pH equilibrium diagram approaches were employed to investigate the reaction process and pathways of birnessite formation. Results showed that the process of the birnessite formation could be divided into four stages: (1) formation stage for hausmannite and feitknechtite, (2) stage of transformation of hausmannite and feitknechtite to buserite, (3) buserite crystal growing stage, and (4) stage of conversion of buserite into birnessite. Mn(OH)2 was mainly present as amorphous state only for a short initial time of oxidation reaction. In the oxidation process, buserite formed following two pathways by recrystallization after dissolution of the intermediates, and the transformations of the minerals depended on the Eh determined by the dissolved O2 concentration on their surfaces. The results are fundamental in further exploration on the mechanism of birnessite formation in the alkali medium. A great practical significance would also be expected with respect to the areas of material sciences.

  19. Power scaling of a wavelength-narrowed diode laser system for pumping alkali vapors

    Science.gov (United States)

    Hersman, F. W.; Distelbrink, J. H.; Ketel, J.; Wilson, J.; Watt, D. W.

    2016-03-01

    We report a method for locking the output wavelength and reducing the spectral linewidth of diode lasers by feeding back light to the emitters from a wavelength selective external optical cavity. Ten years ago our team developed a stepped-mirror that allowed a single external cavity to lock the wavelength of a stack of diode array bars by equalizing path lengths between each emitter and the grating. Here we report combining one such step-mirror external cavity with an array of power dividers, each sending a portion of this feedback power to a separate diode array bar stack.

  20. Investigation of Anti-Relaxation Coatings for Alkali-Metal Vapor Cells using Surface Science Techniques

    Science.gov (United States)

    2011-02-01

    www.escholarship.org/uc/item/0ch5f6qq Local Identifier: LBNL Paper LBNL-4152E Preferred Citation: Journal of Chemical Physics, 133, 144703, 10/14...NOTES SJS, DJM, MHD , AP, and DB, the Advanced 11 Light Source, and the DSC, FTIR, and AFM studies were supported by the Director, O ce of Science, Of...low-doped (phosphorus, 74-86 Ω·cm resis- tivity) silicon wafers (Silicon Quest International ) were instead used as substrates for paraffin coating

  1. New diagnostic technique for Zeeman-compensated atomic beam slowing: technique and results

    NARCIS (Netherlands)

    Molenaar, P.A.; Straten, P. van der; Heideman, H.G.M.; Metcalf, H.

    2001-01-01

    We have developed a new diagnostic tool for the study of Zeeman-compensated slowing of an alkali atomic beam. Our time-of-flight technique measures the longitudinal veloc- ity distribution of the slowed atoms with a resolution below the Doppler limit of 30 cm/s. Furthermore, it can map the position

  2. A Study on HA Titanium Surface with Atomic Force Microscope (AFM)

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    Three kinds of titanium surface especially the HA surface are analyzed. Titanium was treated by 3 kinds of methods that were acid & alkali, calcic solution and apatite solution. Samples were observed by optic microscope and atomic force microscope ( AFM). The typical surface morphology of the acid and alkali group is little holes, and on the two HA surface the tiny protuberances is typical. The surface treated by apatite solution was smoother than the two formers. The rough surface treated with acid and alkali was propitious to Ca + , Pand proteins' adhesion, and the relatively smooth HA surface was of benefit to the cell adhesion.

  3. IRMPD Action Spectroscopy of Alkali Metal Cation-Cytosine Complexes: Effects of Alkali Metal Cation Size on Gas Phase Conformation

    NARCIS (Netherlands)

    Yang, B.; Wu, R.R.; Polfer, N.C.; Berden, G.; Oomens, J.; Rodgers, M.T.

    2013-01-01

    The gas-phase structures of alkali metal cation-cytosine complexes generated by electrospray ionization are probed via infrared multiple photon dissociation (IRMPD) action spectroscopy and theoretical calculations. IRMPD action spectra of five alkali metal cation-cytosine complexes exhibit both simi

  4. Strong relative intensity squeezing by 4-wave mixing in Rb vapor

    CERN Document Server

    McCormick, C F; Boyer, V; Lett, P D

    2006-01-01

    We have measured -3.5 dB (-8.1 dB corrected for losses) relative intensity squeezing between the probe and conjugate beams generated by stimulated, nondegenerate four-wave mixing in hot rubidium vapor. Unlike early observations of squeezing in atomic vapors based on saturation of a two-level system, our scheme uses a resonant nonlinearity based on ground-state coherences in a three-level system. Since this scheme produces narrowband, squeezed light near an atomic resonance it is of interest for experiments involving cold atoms or atomic ensembles.

  5. Determinação de mercúrio total em amostras de água, sedimento e sólidos em suspensão de corpos aquáticos por espectrofotometria de absorção atômica com gerador de vapor a frio Determination of total mercury in water, sediments and solids in suspension in aquatic systems by cold vapor atomic absorption spectrometry

    Directory of Open Access Journals (Sweden)

    José L. F. Vieira

    1996-06-01

    Full Text Available O emprego de mercúrio metálico nos processos de extração do ouro libera toneladas de mercúrio ao meio ambiente, provocando um aumento considerável nas concentrações presentes. Com a finalidade de prevenir a exposição humana a concentrações excessivas, o que poderá resultar em graves episódios de intoxicação mercurial, bem como avaliar a possibilidade de sedimentos tornarem-se fontes potenciais de contaminação para os seres vivos, é de fundamental importância a monitorização do mercúrio em diversos compartimentos ambientais. Efetuou-se a padronização de uma metodologia analítica para determinação de mercúrio total em amostras de água, sólidos em suspensão e sedimentos de corpos aquáticos para monitorização ambiental do xenobiótico. Posteriormente, foram analisadas amostras oriundas de regiões garimpeiras, com vistas a avaliar o desempenho do método em amostras reais e efetuar levantamento preliminar sobre a contaminação mercurial na área de estudo.The use of metallic mercury in the extraction and concentration of gold causes the discarding of tons of this metal in the environment, leading to a considerable increase in the natural levels of the same and the contamination of the surrounding areas. Thus it is extremely important to monitor the presence of this metal in various sectors of the environment with a view aiming to previnting human exposure to excessive concentrations which can result in serious episodes of mercury poisoning. It is also important to estimate the possibility of river sediments becoming potential sources of contamination of human beings. The determination of total mercury was undertaken by using cold vapor atomic absorption spectrometry. River waters, as well as sediments and suspended solids were used as samples for the standardization of the analytical procedure. Later on, this method was tested on samples originating in gold mining areas for the purpose of assessing its validity.

  6. Effects of Plasma Formation on the Cesium Diode (DPAL) and Excimer (XPAL) Pumped Alkali Laser

    Science.gov (United States)

    Markosyan, Aram H.; Kushner, Mark J.

    2015-09-01

    Diode pumped alkali lasers (DPALs) and excimer pumped alkali lasers (XPALs) are being investigated as a means to convert optical pumps having poor optical quality to laser radiation having high optical quality. DPALs sustained in Cs vapor are pumped on the D2(852.35 nm), Cs(62S1/2) --> Cs(62P3/2) , transition and lase on the D1(894.59 nm) transition, Cs(62P1/2) --> Cs(62S1/2) . Collisional mixing (spin orbit relaxation) of the Cs(62P3/2) and Cs(62P1/2) levels is a key part of this three-level (in fact, a quasi-two-level) laser scheme. In the five-level XPAL pumping scheme, the CsAr(B2Σ1/ 2 +) state is optically pumped by 836.7 nm pulses, which later dissociates and produces Cs(62P3/2) . As in DPAL, a collisional relaxant transfers the population of Cs(62P3/2) to Cs(62P1/2) , which enables lasing on D1 transition. A first principals global computer model has been developed for both systems to investigate the effects of plasma formation on the laser performance. Argon is used as a buffer gas and nitrogen or ethane are used as a collisional relaxant at total pressure of 600 Torr at temperatures of 350-450 K, which produces vapor pressures of Cs of systems, a plasma formation in excess of 1014 - 1016cm-3 occurs, which potentially reduces laser output power by electron collisional mixing of upper and lower laser levels. Work supported by DoD High Energy Laser Multidisc, Res. Initiative.

  7. Cation-π interaction of alkali metal ions with C24 fullerene: a DFT study.

    Science.gov (United States)

    Moradi, Morteza; Peyghan, Ali Ahmadi; Bagheri, Zargham; Kamfiroozi, Mohammad

    2012-08-01

    Using first principle calculations, we investigated cation-π interactions between alkali cations (Li(+), Na(+), and K(+)) and pristine C(24) or doped fullerenes of BC(23), and NC(23). The most suitable adsorption site is found to be atop the center of a six-membered ring of the exterior surface of C(24) molecule. Interaction energies of these cations decreased in the order: Li(+) > Na(+) > K(+), with values of -31.82, -22.36, and -15.68 kcal mol(-1), respectively. It was shown that the interaction energies are increased and decreased by impurity doping of B and N atoms in adjacent wall of adsorption site, depending on electron donating or receptivity of the doping atoms.

  8. Atom chips

    CERN Document Server

    Reichel, Jakob

    2010-01-01

    This book provides a stimulating and multifaceted picture of a rapidly developing field. The first part reviews fundamentals of atom chip research in tutorial style, while subsequent parts focus on the topics of atom-surface interaction, coherence on atom chips, and possible future directions of atom chip research. The articles are written by leading researchers in the field in their characteristic and individual styles.

  9. Atomic energy

    CERN Multimedia

    1996-01-01

    Interviews following the 1991 co-operation Agreement between the Department of Atomic Energy (DAE) of the Government of India and the European Organization for Nuclear Research (CERN) concerning the participation in the Large Hadron Collider Project (LHC) . With Chidambaram, R, Chairman, Atomic Energy Commission and Secretary, Department of Atomic Energy, Department of Atomic Energy (DAE) of the Government of India and Professor Llewellyn-Smith, Christopher H, Director-General, CERN.

  10. Thermoluminescence of alkali halides and its implications

    Energy Technology Data Exchange (ETDEWEB)

    Gartia, R.K., E-mail: rkgartia02@yahoo.in [Physics Department, Manipur University, Imphal 795003 (India); Rey, L. [Aerial-CRT-parc d' Innovation, B.P. 40443, F-67412 Illkirch Cedex (France); Tejkumar Singh, Th. [Physics Department, Manipur University, Imphal 795003 (India); Basanta Singh, Th. [Luminescence Dating Laboratory, Manipur University, Imphal 795003 (India)

    2012-03-01

    Trapping levels present in some alkali halides namely NaCl, KCl, KBr, and KI are determined by deconvolution of the thermoluminescence (TL) curves. Unlike most of the studies undertaken over the last few decades, we have presented a comprehensive picture of the phenomenon of TL as an analytical technique capable of revealing the position of the trapping levels present in the materials. We show that for all practical purposes, TL can be described involving only the three key trapping parameters, namely, the activation energy (E), the frequency factor (s), and the order of kinetics (b) even for complex glow curves having a number of TL peaks. Finally, based on these, we logically infer the importance of TL in development and characterization of materials used in dosimetry, dating and scintillation.

  11. Spectroscopic detection of atom-surface interactions in an atomic vapour layer with nanoscale thickness

    CERN Document Server

    Whittaker, K A; Hughes, I G; Sargsyan, A; Sarkisyan, D; Adams, C S

    2015-01-01

    We measure the resonance line shape of atomic vapor layers with nanoscale thickness confined between two sapphire windows. The measurement is performed by scanning a probe laser through resonance and collecting the scattered light. The line shape is dominated by the effects of Dicke narrowing, self-broadening, and atom-surface interactions. By fitting the measured line shape to a simple model we discuss the possibility to extract information about the atom-surface interaction.

  12. Alkali-activated cementitious materials: Mechanisms, microstructure and properties

    Science.gov (United States)

    Jiang, Weimin

    The goal of this study was to examine the activation reaction, microstructure, properties, identify the mechanisms of activation, and achieve an enhanced understanding of activation processes occurring during the synthesis of alkali activated cementitious materials (AAC). The discussions classify the following categories. (1) alkali activated slag cement; (2) alkali activated portland-slag cement; (3) alkali activated fly ash-slag cement; (4) alkali activated pozzolana-lime cement; (5) alkali activated pozzolana cement. The activators involved are NaOH, KOH; Nasb2SOsb4;\\ Nasb2COsb3;\\ CaSOsb4, and soluble silicate of sodium and potassium. The effect of alkali activation on the microstructure of these materials were analyzed at the micro-nanometer scale by SEM, EDS, ESEM, and TEM. Also sp{29}Si and sp{27}Al MAS-NMR, IR, Raman, TGA, and DTA were performed to characterize the phase in these systems. Slag, fly ash, silica fume, as well as blended cements containing mixtures of these and other components were characterized. A set of ordinary portland cement paste samples served as a control. This study confirmed that AAC materials have great potential because they could generate very early high strength, greater durability and high performance. Among the benefits to be derived from this research is a better understanding of the factors that control concrete properties when using AAC materials, and by controlling the chemistry and processing to produce desired microstructures and properties, as well as their durability.

  13. Controlled in-situ dissolution of an alkali metal

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Jeffrey Donald; Dooley, Kirk John; Tolman, David Donald

    2012-09-11

    A method for the controllable dissolution of one or more alkali metals from a vessel containing a one or more alkali metals and/or one or more partially passivated alkali metals. The vessel preferably comprising a sodium, NaK or other alkali metal-cooled nuclear reactor that has been used. The alkali metal, preferably sodium, potassium or a combination thereof, in the vessel is exposed to a treatment liquid, preferably an acidic liquid, more preferably citric acid. Preferably, the treatment liquid is maintained in continuous motion relative to any surface of unreacted alkali metal with which the treatment liquid is in contact. The treatment liquid is preferably pumped into the vessel containing the one or more alkali metals and the resulting fluid is extracted and optionally further processed. Preferably, the resulting off-gases are processed by an off-gas treatment system and the resulting liquids are processed by a liquid disposal system. In one preferred embodiment, an inert gas is pumped into the vessel along with the treatment liquid.

  14. Enhanced Spin Depolarization and Storage Time in a Rb Vapor

    Institute of Scientific and Technical Information of China (English)

    QI Yue-Rong; GAO Hong; ZHANG Shou-Gang

    2009-01-01

    The experiment of measuring the spin depolarized time and light storage time in a Rb vapor under different conditions is performed. Typically, these measurements are accomplished in three different containers: atoms in a bare glass ceil, atoms in a buffer gas cell, and atoms in a tetracontane (C40H82) coating cell. The increasing depolarization and storage times are observed in both the buffer gas ceil and the tetracontane coating cell. In the latter case, a storage time greater than 400 μs is obtained.

  15. Atomic polarizabilities

    Energy Technology Data Exchange (ETDEWEB)

    Safronova, M. S. [Department of Physics and Astronomy, University of Delaware, Newark, DE 19716 (United States); Mitroy, J. [School of Engineering, Charles Darwin University, Darwin NT 0909 (Australia); Clark, Charles W. [Joint Quantum Institute, National Institute of Standards and Technology and the University of Maryland, Gaithersburg, Maryland 20899-8410 (United States); Kozlov, M. G. [Petersburg Nuclear Physics Institute, Gatchina 188300 (Russian Federation)

    2015-01-22

    The atomic dipole polarizability governs the first-order response of an atom to an applied electric field. Atomic polarization phenomena impinge upon a number of areas and processes in physics and have been the subject of considerable interest and heightened importance in recent years. In this paper, we will summarize some of the recent applications of atomic polarizability studies. A summary of results for polarizabilities of noble gases, monovalent, and divalent atoms is given. The development of the CI+all-order method that combines configuration interaction and linearized coupled-cluster approaches is discussed.

  16. Hg soil pollution around the Flix chlor-alkali plant

    Science.gov (United States)

    Esbrí, José Maria; López-Berdoces, Miguel Angel; Martínez-Coronado, Alba; Fernández-Calderon, Sergio; Díez, Sergi; León Higueras, Pablo

    2014-05-01

    Main mercury consumer in industrialized countries is the chlor-alkali industry. In Spain, this industry declares 2.54 tons of mercury emissions to the atmosphere per year, but the losses of mercury in this industrial process seem to be higher than this. In the next 15 years, these industries are going to make a technology change to a free mercury based technology. This study has been applied to the Flix (Tarragona, NE Spain) plant, located very near the Ebro River. Local industrial activity started in the late 18th Century, being the first Spanish industrial precinct in activity. Technology used in this plant is obsolete, and produces important emissions to the atmosphere. Besides, it has also produced an important pollution problem in the Ebro River. The aim of this work is the characterization of mercury soil pollution around the oldest chlor-alkali plant (CAP), actually in process of decommissioning. For this porpoises, we provided data of mercury in soils and in olive oil leaves, in order to assess the extent of this pollution, and the consequences in terms of transferring to local agricultural biota. We present data from two soils geochemistry surveys, one centered in the general area, and a second one centered in an anomalous area identified by the first survey, at the Ebro margins downstream the town area. A total of 126 surface soil samples were taken and analyzed for total mercury by means of a Lumex RA-915+ device with RP- 91C pyrolysis attachment. Soil-plant transfer was studied based on mercury contents in olive leaves, the most ubiquitous plant species in the area; these biological samples were thoroughly clean and freeze-dried before its total mercury analysis in a Lumex RA-915+ device with its RP-91c pyrolysis attachment. Mercury contents in soils reach maximum levels in the vicinity of CAP (495 mg kg-1), much higher than baseline levels found in the area (0.18 mg kg-1, in average). These polluted soils are located near CAP and the riverbanks of Ebro

  17. Influence of alkalis from different sources than cement in the evolution of alkali-silica reaction

    Directory of Open Access Journals (Sweden)

    Olague, C.

    2003-12-01

    Full Text Available A bibliographical revision of the existent literature allows showing symptoms of alkali-silica reaction (ASR in highways, and the practical and economic method uranyl acetate to confirm the presence of ASR. The existence of reaction in concrete pavements of Chihuahua City was verified by a visual observation of patterns cracks, examination of gel deposits and the presence of reactive materials. Considering that the cement used to construct this pavements with problems of ASR, was low alkalis cement, the research was devoted to study the influence of alkalis coming from different sources than cement in the evolution of reaction such as: a aggregates: gravel and sand, b mix water, c additives and d minerals additions The initial classification of cements like high and low alkalis concerned to ASR must be revised for accept the fact that there is not a unique maximum limit alkalis of cement under which the expansible reactivity cannot occur.

    Una revisión bibliográfica de la literatura existente permite mostrar las manifestaciones de reacción álcali-sílice (RAS en estructuras de carreteras y el método práctico y económico de acetato de uranilo para confirmar la presencia de RAS. La existencia de la reacción en pavimentos de hormigón de la ciudad de Chihuahua se pudo confirmar tras la observación visual de modelos de grietas, estudios de depósitos de gel y existencia de fuentes de materiales reactivos. Considerando que el cemento utilizado para construir los tramos de pavimento con problemas de RAS, era un cemento bajo en álcalis, se enfocó la investigación al estudio de la influencia de los álcalis provenientes de fuentes distintas al cemento en la evolución de la reacción tales como: a áridos gruesos y finos, b agua de mezclado, c aditivos y d adiciones minerales El concepto inicial de clasificación de cementos altos y bajos en álcalis con respecto a la RAS debe ser revisado para aceptar el hecho de que no hay un solo

  18. Light-pulse atom interferometric device

    Science.gov (United States)

    Biedermann, Grant; McGuinness, Hayden James Evans; Rakholia, Akash; Jau, Yuan-Yu; Schwindt, Peter; Wheeler, David R.

    2016-03-22

    An atomic interferometric device useful, e.g., for measuring acceleration or rotation is provided. The device comprises at least one vapor cell containing a Raman-active chemical species, an optical system, and at least one detector. The optical system is conformed to implement a Raman pulse interferometer in which Raman transitions are stimulated in a warm vapor of the Raman-active chemical species. The detector is conformed to detect changes in the populations of different internal states of atoms that have been irradiated by the optical system.

  19. Cation and anion dependence of stable geometries and stabilization energies of alkali metal cation complexes with FSA(-), FTA(-), and TFSA(-) anions: relationship with physicochemical properties of molten salts.

    Science.gov (United States)

    Tsuzuki, Seiji; Kubota, Keigo; Matsumoto, Hajime

    2013-12-19

    Stable geometries and stabilization energies (Eform) of the alkali metal complexes with bis(fluorosulfonyl)amide, (fluorosulfonyl)(trifluoromethylslufonyl)amide and bis(trifluoromethylsulfonyl)amide (FSA(-), FTA(-) and TFSA(-)) were studied by ab initio molecular orbital calculations. The FSA(-) complexes prefer the bidentate structures in which two oxygen atoms of two SO2 groups have contact with the metal cation. The FTA(-) and TFSA(-) complexes with Li(+) and Na(+) prefer the bidentate structures, while the FTA(-) and TFSA(-) complexes with Cs(+) prefer tridentate structures in which the metal cation has contact with two oxygen atoms of an SO2 group and one oxygen atom of another SO2 group. The two structures are nearly isoenergetic in the FTA(-) and TFSA(-) complexes with K(+) and Rb(+). The magnitude of Eform depends on the alkali metal cation significantly. The Eform calculated for the most stable TFSA(-) complexes with Li(+), Na(+), K(+), Rb(+) and Cs(+) cations at the MP2/6-311G** level are -137.2, -110.5, -101.1, -89.6, and -84.1 kcal/mol, respectively. The viscosity and ionic conductivity of the alkali TFSA molten salts have strong correlation with the magnitude of the attraction. The viscosity increases and the ionic conductivity decreases with the increase of the attraction. The melting points of the alkali TFSA and alkali BETA molten salts also have correlation with the magnitude of the Eform, which strongly suggests that the magnitude of the attraction play important roles in determining the melting points of these molten salts. The anion dependence of the Eform calculated for the complexes is small (less than 2.9 kcal/mol). This shows that the magnitude of the attraction is not the cause of the low melting points of alkali FTA molten salts compared with those of corresponding alkali TFSA molten salts. The electrostatic interactions are the major source of the attraction in the complexes. The electrostatic energies for the most stable TFSA

  20. 多碱阴极XPS分析研究%XPS analysis on multi alkali photocathode

    Institute of Scientific and Technical Information of China (English)

    李晓峰; 冯刘; 石峰; 张云昆

    2014-01-01

    介绍了多碱阴极的特点及其在超二代像增强器中的应用。叙述了多碱阴极进行制作和封接,之后在XPS 分析仪器的预真空室中进行解封并送入仪器分析室进行分析的过程。对多碱阴极不同膜层厚度处各元素原子的百分比进行了XPS分析。首先对多碱阴极的表面进行宽谱扫描,发现元素之后再针对各个元素进行窄谱扫描,之后进行氩离子刻蚀。刻蚀一定时间后再对多碱阴极表面进行宽谱或窄谱扫描,氩离子刻蚀一直进行到阴极玻璃窗的表面。通过氩离子刻蚀并结合XPS能谱分析,得出了多碱阴极膜层内部不同厚度处Na元素、K元素和Sb元素的原子百分比。结果表明:多碱阴极的结构是一种两层结构,即以Na2KSb为基础层,表面再吸附Cs原子层。两层膜层中,Na2KSb基础层较厚,而Cs原子层较薄,厚度仅为整个阴极膜层厚度的2.7%。另外,实测多碱阴极膜层中Na原子、K原子和Sb原子数量的百分比并不完全遵循2:1:1的化学计量比,并且在整个阴极膜层厚度范围内,三种元素的原子百分比并不保持恒定,未出现在某一位置处三种元素原子百分比达到2:1:1的理想状态。原因是目前多碱阴极制作工艺对蒸发元素蒸发量的控制精度较低。理论和实践证明,只有获得具有严格化学计量比的Na2KSb膜层才可能获得高的灵敏度,因此,如果采用分子束外延技术来制作多碱阴极,那么成分控制的精度将大大改善,2:1:1的化学计量比才可能获得,阴极灵敏度才会得到进一步的提高。%The characteristics of multi-alkali cathode, making process as well as the application in the second generational image intensifier was introduced, the sealing process between cathodes and envelops was explained, and cathode was fed to pre chamber of XPS analysis instrument. The percentage of atoms of each element in the