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Sample records for aldol condensation estrutura

  1. Functioned Calix[4]arenes as Artificial Enzymes Catalyze Aldol Condensation

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Aldolase models derived from calix[4]arene were designed and synthesized. The aldol condensation of p-nitrobenzaldehyde with acetone was catalyzed by the synthetic enzymes proceeded under mild conditions to offer chiefly aldol-type product in good yield.

  2. Activated hydrotalcites as solid base catalysts in aldol condensations

    NARCIS (Netherlands)

    Roelofs, J.C.A.A.

    2002-01-01

    The development of new catalytic materials and routes to replace environmentally unacceptable processes in the fine chemical industry is emerging due to stringent legislation. Replacement of currently applied alkali bases in liquid-phase aldol condensations can result in diminishing of waste water s

  3. Aldol Condensation of Citral with Acetone on Basic Solid Catalysts

    Directory of Open Access Journals (Sweden)

    NODA C.

    1998-01-01

    Full Text Available The catalytic performance of solids with basic properties, such as CaO, MgO and hydrotalcites, was evaluated in the aldol condensation of citral and acetone, the first step in the synthesis of ionones from citral. The best results were obtained with CaO and hydrotalcite with high conversions (98% and selectivities (close to 70% for the main product observed for both of the catalyst. Such pseudoionone yields were greater than those reported in the literature for the homogeneous reaction.

  4. Mineral catalysis of a potentially prebiotic aldol condensation

    Science.gov (United States)

    De Graaf, R. M.; Visscher, J.; Xu, Y.; Arrhenius, G.; Schwartz, A. W.

    1998-01-01

    Minerals may have played a significant role in chemical evolution. In the course of investigating the chemistry of phosphonoacetaldehyde (PAL), an analogue of glycolaldehyde phosphate, we have observed a striking case of catalysis by the layered hydroxide mineral hydrotalcite ([Mg2Al(OH)6][Cl.nH2O]). In neutral or moderately basic aqueous solutions, PAL is unreactive even at a concentration of 0.1 M. In the presence of a large excess of NaOH (2 M), the compound undergoes aldol condensation to produce a dimer containing a C3-C4 double-bond. In dilute neutral solutions and in the presence of the mineral, however, condensation takes place rapidly, to produce a dimer which is almost exclusively the C2-C3 unsaturated product.

  5. Five-membered ring annelation in [2.2]paracyclophanes by aldol condensation

    Directory of Open Access Journals (Sweden)

    Henning Hopf

    2014-08-01

    Full Text Available Under basic conditions 4,5,12,13-tetraacetyl[2.2]paracyclophane (9 cyclizes by a double aldol condensation to provide the two aldols 12 and 15 in a 3:7 ratio. The structures of these compounds were obtained from X-ray structural analysis, spectroscopic data, and mechanistic considerations. On acid treatment 12 is dehydrated to a mixture of the condensed five-membered [2.2]paracyclophane derivatives 18–20, whereas 15 yields a mixture of the isomeric cyclopentadienones 21–23. The structures of these elimination products are also deduced from X-ray and spectroscopic data. The sequence presented here constitutes the simplest route so far to cyclophanes carrying an annelated five-membered ring.

  6. Modified calcium oxide as stable solid base catalyst for Aldol condensation reaction

    Indian Academy of Sciences (India)

    Ying Tang; Jingfang Xu; Xuefan Gu

    2013-03-01

    A highly efficient and stable solid-base catalyst for Aldol condensation was prepared by modifying commercial CaO with benzyl bromide in a simple way. It was found that modified CaO can effectively catalyse the Aldol condensation of cyclohexanone and benzaldehyde, as well as various benzaldehydes, to produce 2-benzylidenecyclohexanone with a good selectivity and high yield. Higher yield of 95.8% was obtained over modified CaO after 3 h, which is short compared with the yield of 92.1% after 12 h over commercial CaO. The influence of several reaction parameters, such as temperature, catalyst loading, was investigated. The humidity test over modified CaO reveals that the basic centres of modified CaO are stable for CO2 and moisture. From the results of Fourier transform-infrared (FT-IR) and Thermogravity analysis (TG) characterization, the modifier was bonded on surface of CaO chemically and almost no Ca(OH)2 formed during the modification process. The type of aldehyde has great influence on the yield of aldol condensation.

  7. A green, inexpensive and efficient organocatalyzed procedure for aqueous aldol condensations

    Energy Technology Data Exchange (ETDEWEB)

    Abaee, M. Saeed; Mojtahedi, Mohammad M.; Forghani, Soudabeh; Sharifi, Roholah [Chemistry and Chemical Engineering Research Center of Iran, Tehran (Iran, Islamic Republic of). Faculty of Organic Chemistry and Natural Products; Ghandchi, Nafiseh M. [Islamic Azad University, Tehran (Iran, Islamic Republic of). Dept. of Chemistry; Forouzani, Mehdi; Chaharnazm, Behnam [Payam Noor University, Sari (Iran, Islamic Republic of)

    2009-07-01

    A facile and general procedure is presented for diethylamine-catalyzed double crossed aldol condensation of cyclic ketones with various aromatic aldehydes under aqueous conditions. Excellent yields of 3,5-bisarylmethylidenes of homocyclic and heterocyclic ketones are achieved in a one-pot procedure. Furthermore, the methodology is efficiently applied to the synthesis of chalcones from their corresponding methyl ketones. In the majority of the cases studied, products precipitate from the reaction mixtures and the medium is recycled in subsequent several reactions without significant loss of activity. (author)

  8. An overview of dehydration, aldol-condensation and hydrogenation processes for production of liquid alkanes from biomass-derived carbohydrates

    Energy Technology Data Exchange (ETDEWEB)

    Chheda, Juben N.; Dumesic, James A. [University of Wisconsin-Madison, Department of Chemical and Biological Engineering, Madison, WI 53706 (United States)

    2007-05-30

    We present results for the conversion of carbohydrate feedstocks to liquid alkanes by the combination of dehydration, aldol-condensation/hydrogenation, and dehydration/hydrogenation processing. With respect to the first dehydration step, we demonstrate that HMF can be produced in good selectivity from abundantly available polysaccharides (such as inulin, sucrose) containing fructose monomer units using a biphasic batch reactor system. The reaction system can be optimized to achieve good yields to 5-hydroxymethylfurfural (HMF) from fructose by varying the contents of aqueous-phase modifiers such as dimethylsulfoxide (DMSO) and 1-methyl-2-pyrrolidinone (NMP). Regarding the aldol-condensation/hydrogenation step, we present the development of stable, solid base catalysts in aqueous environments. We address the effects of various reaction parameters such as the molar ratio of reactants and temperature on overall product yield for sequential aldol-condensation and hydrogenation steps. Overall, our results show that it is technically possible to convert carbohydrate feedstocks to produce liquid alkanes by the combination of dehydration, aldol-condensation/hydrogenation, and dehydration/hydrogenation processing; however, further optimization of these processes is required to decrease the overall number of separate steps (and reactors) required in this conversion. (author)

  9. InCl3.4H2O Catalyzed Aldol Condensation of Cycloalkanones with Aromatic Aldehydes

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    InCl3·4H2O catalyzes the cross-aldol condensation of cycloalkanones with aromatic aldehydes in sealed tube under solvent free condition to afford an efficient method for the synthesis of α, α-bis(substituted)benzylidenecycloalkanones.

  10. Substrate inhibition in the heterogeneous catalyzed aldol condensation: A mechanistic study of supported organocatalysts

    Energy Technology Data Exchange (ETDEWEB)

    Kandel, Kapil; Althaus, Stacey M.; Peeraphatdit, Chorthip; Kobayashi, Takeshi; Trewyn, Brian G.; Pruski, Marek; Slowing, Igor I.

    2012-05-23

    In this study, we demonstrate how materials science can be combined with the established methods of organic chemistry to find mechanistic bottlenecks and redesign heterogeneous catalysts for improved performance. By using solid-state NMR, infrared spectroscopy, surface and kinetic analysis, we prove the existence of a substrate inhibition in the aldol condensation catalyzed by heterogeneous amines. We show that modifying the structure of the supported amines according to the proposed mechanism dramatically enhances the activity of the heterogeneous catalyst. We also provide evidence that the reaction benefits significantly from the surface chemistry of the silica support, which plays the role of a co-catalyst, giving activities up to two orders of magnitude larger than those of homogeneous amines. This study confirms that the optimization of a heterogeneous catalyst depends as much on obtaining organic mechanistic information as it does on controlling the structure of the support.

  11. Cu/MgAl(2)O(4) as bifunctional catalyst for aldol condensation of 5-hydroxymethylfurfural and selective transfer hydrogenation.

    Science.gov (United States)

    Pupovac, Kristina; Palkovits, Regina

    2013-11-01

    Copper supported on mesoporous magnesium aluminate has been prepared as noble-metal-free solid catalyst for aldol condensation of 5-hydroxymethylfurfural with acetone, followed by hydrogenation of the aldol condensation products. The investigated mesoporous spinels possess high activity as solid-base catalysts. Magnesium aluminate exhibits superior activity compared to zinc and cobalt-based aluminates, reaching full conversion and up to 81 % yield of the 1:1 aldol product. The high activity can be correlated to a higher concentration of basic surface sites on magnesium aluminate. Applying continuous regeneration, the catalysts can be recycled without loss of activity. Focusing on the subsequent hydrogenation of aldol condensation products, Cu/MgAl2 O4 allows a selective hydrogenation and CO bond cleavage, delivering 3-hydroxybutyl-5-methylfuran as the main product with up to 84 % selectivity avoiding ring saturation. Analysis of the hydrogenation activity reveals that the reaction proceeds in the following order: CC>CO>CO cleavage>ring hydrogenation. Comparable activity and selectivity can be also achieved utilizing 2-propanol as solvent in the transfer hydrogenation, providing the possibility for partial recycling of acetone and optimization of the hydrogen management.

  12. Sulfamic acid: An efficient, cost-effective and green catalyst for crossed-aldol condensation of ketones with aromatic aldehydes under solvent-free

    Institute of Scientific and Technical Information of China (English)

    Amin Rostami; Firoz Ahmad-Jangi

    2011-01-01

    Aromatic aldehydes undergo crossed-aldol condensation with ketones in the presence of catalytic amount of sulfamic acid (SA) to afford the corresponding α,β-unsaturated aldol products under solvent-free conditions in good to high yields at 45-80 ℃.

  13. Amorphous metal-aluminophosphate catalysts for aldol condensation of n-heptanal and benzaldehyde to jasminaldehyde

    Institute of Scientific and Technical Information of China (English)

    A. Hamza; N. Nagaraju

    2015-01-01

    Amorphous aluminophosphate (AlP) and metal‐aluminophosphates (MAlPs, where M=2.5 mol%Cu, Zn, Cr, Fe, Ce, or Zr) were prepared by coprecipitation method. Their surface properties and catalytic activity for the synthesis of jasminaldehyde through the aldol condensation of n‐heptanal and benzaldehyde were investigated. The nitrogen adsorption‐desorption isotherms showed that the microporosity exhibited by the aluminophosphate was changed to a mesoporous and macroporous structure which depended on the metal incorporated, with a concomitant change in the surface area. Temperature‐programmed desorption of NH3 and CO2 revealed that the materials possessed both acidic and basic sites. The acidic strength of the material was either increased or decreased depending on the nature of the metal. The basicity was increased compared to AlP. All the materials were X‐ray amorphous and powder X‐ray diffraction studies indicated the absence of metal oxide phases. The Fourier transform infrared analysis confirmed the presence of phosphate groups and also the absence of any M‐O moieties in the materials. The selected organic reaction occurred only in the presence of the AlP and MAlPs. The selectivity for the jasminaldehyde product was up to 75%with a yield of 65%. The best conversion of n‐heptanal with a high selectivity to jasminaldehyde was obtained with FeAlP as the catalyst, and this material was characterized to have less weak acid sites and more basic sites.

  14. Convergent fabrication of a nanoporous two-dimensional carbon network from an aldol condensation on metal surfaces

    Science.gov (United States)

    Landers, John; Chérioux, Frédéric; De Santis, Maurizio; Bendiab, Nedjma; Lamare, Simon; Magaud, Laurence; Coraux, Johann

    2014-12-01

    We report a convergent surface polymerization reaction scheme on Au(111), based on a triple aldol condensation, yielding a carbon-rich, covalent nanoporous two-dimensional network. The reaction is not self-poisoning and proceeds up to a full surface coverage. The deposited precursor molecules 1, 3, 5-tri(4’-acetylphenyl) first form supramolecular assemblies that are converted to the porous covalent network upon heating. The formation and structure of the network and of the intermediate steps are studied with scanning tunneling microscopy, Raman spectroscopy and density functional theory.

  15. Gallium(III)- and calcium(II)-catalyzed Meyer-Schuster rearrangements followed by intramolecular aldol condensation or endo-Michael addition.

    Science.gov (United States)

    Presset, M; Michelet, B; Guillot, R; Bour, C; Bezzenine-Lafollée, S; Gandon, V

    2015-03-28

    The first gallium- and calcium-catalyzed Meyer-Schuster rearrangements are described. Under substrate control, the incipient conjugated ketones can be trapped intramolecularly by β-keto esters or amides to yield cyclic products after aldol condensation or endo-Michael addition. An interesting additive effect that promotes the latter tandem process with calcium has been found.

  16. Study on Aldol Condensation of HCHO and CH3CHO over MgO Catalysts Modified by Lanthanum and Cerium

    Institute of Scientific and Technical Information of China (English)

    王幸宜; 李春香; 杨菊群

    2004-01-01

    Aldol condensation of HCHO and CH3CHO over MgO, modified MgO and Al2O3 with rare earth oxides, was studied. The measurement of adsorption of pyrrole on catalysts by in-situ FT-IR and NH3 TPD indicated that the addition of elements La or Ce into MgO increased the acidity of the solid. In-situ FT-IR showed that the activation of-C=O in HCHO adsorbed on CeO-MgO and La2O3-MgO occurred. The measurement of catalytic activity implied that the modified catalysts can promote the formation of pentaerythritol, dipentaerthritol and tripentaerythritol.

  17. Hydroxyapatite catalyzed aldol condensation: Synthesis, spectral linearity, antimicrobial and insect antifeedant activities of some 2,5-dimethyl-3-furyl chalcones

    Science.gov (United States)

    Subramanian, M.; Vanangamudi, G.; Thirunarayanan, G.

    2013-06-01

    A series of 2,5-dimethyl-3-furyl chalcones [2E-1-(2,5-dimethyl-3-furyl)-3-(substituted phenyl)-2-propen-1-ones] have been synthesized by Hydrotalcite catalyzed aldol condensation between 3-acetyl-2,5-dimethylfuron and substituted benzaldehydes. Yields of chalcones are more than 80%. These chalcones were characterized by their physical constants and spectral data. The group frequencies of infrared ν(cm-1) of CO s-cis and s-trans, CH in-plane and out of plane, CHdbnd CH out of plane, lbond2 Cdbnd Crbond2 out of plane modes, NMR chemical shifts δ(ppm) of Hα, Hβ, CO, Cα and Cβ of these chalcones were correlated with Hammett substituent constants, F and R parameters using single and multi-regression analyses. From the results of statistical analyses, the effects of substituents on the group frequencies are explained. Antibacterial, antifungal and insect antifeedant activities of these chalcones have been studied.

  18. Hydroxyapatite catalyzed aldol condensation: synthesis, spectral linearity, antimicrobial and insect antifeedant activities of some 2,5-dimethyl-3-furyl chalcones.

    Science.gov (United States)

    Subramanian, M; Vanangamudi, G; Thirunarayanan, G

    2013-06-01

    A series of 2,5-dimethyl-3-furyl chalcones [2E-1-(2,5-dimethyl-3-furyl)-3-(substituted phenyl)-2-propen-1-ones] have been synthesized by Hydrotalcite catalyzed aldol condensation between 3-acetyl-2,5-dimethylfuron and substituted benzaldehydes. Yields of chalcones are more than 80%. These chalcones were characterized by their physical constants and spectral data. The group frequencies of infrared ν(cm(-1)) of CO s-cis and s-trans, CH in-plane and out of plane, CH=CH out of plane, C=C out of plane modes, NMR chemical shifts δ(ppm) of Hα, Hβ, CO, Cα and Cβ of these chalcones were correlated with Hammett substituent constants, F and R parameters using single and multi-regression analyses. From the results of statistical analyses, the effects of substituents on the group frequencies are explained. Antibacterial, antifungal and insect antifeedant activities of these chalcones have been studied.

  19. Aldol condensations of a variety of different aldehydes and ketones under ultrasonic irradiation using poly(N-vinylimidazole) as a new heterogeneous base catalyst under solvent-free conditions in a liquid-solid system

    Institute of Scientific and Technical Information of China (English)

    Nader Ghaffari Khaligh; Taraneh Mihankhah

    2013-01-01

    An ultrasound-assisted aldol condensation reaction has been developed for a range of ketones with a variety of aromatic aldehydes using poly(N-vinylimidazole) as a solid base catalyst in a liquid-solid system. The catalyst can be recovered by simple filtration and reused at least 10 times without any significant reduction in its activity. The reaction is also amenable to the large scale, making the pro-cedure potentially useful for industrial applications.

  20. Improvement on the catalytic performance of Mg-Zr mixed oxides for furfural-acetone aldol condensation by supporting on mesoporous carbons.

    Science.gov (United States)

    Faba, Laura; Díaz, Eva; Ordóñez, Salvador

    2013-03-01

    A new procedure for improving the performance of the most common catalysts used in aqueous-phase aldol condensation (Mg-Zr mixed oxides) reactions is presented. This reaction is of interest for upgrading carbohydrate feedstocks. The procedure involves supporting Mg-Zr oxides on non-microporous carbonaceous materials, such as carbon nanofibers (CNFs) or high-surface-area graphites (HSAGs), using either incipient wetness or coprecipitation procedures. The use of HSAGs together with the coprecipitation method provides the best performance. Results obtained for the cross-condensation of acetone and furfural at 323 K reveal that the catalyst performance is greatly improved compared to the bulk oxides (96.5 % conversion vs. 81.4 % with the bulk oxide; 87.8 % selectivity for C13 and C8 adducts vs. 76.2 % with the bulk oxide). This difference is even more prominent in terms of rates per catalytically active basic site (four and seven times greater for C8 and C13 adducts, respectively). The improved performance is explained in terms of a more appropriate basic site distribution and by greater interaction of the reactants with the carbon surface. In addition, deactivation behavior of the catalyst is improved by tuning the morphology of the carbonaceous support. An important enhancement of the catalytic stability can be obtained selecting a HSAG with an appropriate pore diameter. With HSAG100 the activity decreased by less than 20 % between successive reaction cycles and the selectivity for the condensation products remained almost unaltered. The decrease is greater than 80 % for the bulk oxides tested at these conditions, with important increases in the selectivity for by-product formation.

  1. Hydrolysis/dehydration/aldol-condensation/hydrogenation of lignocellulosic biomass and biomass-derived carbohydrates in the presence of Pd/WO3-ZrO2 in a single reactor.

    Science.gov (United States)

    Dedsuksophon, W; Faungnawakij, K; Champreda, V; Laosiripojana, N

    2011-01-01

    Hydrolysis/dehydration/aldol-condensation/hydrogenation of lignocellulosic-biomass (corncobs) and biomass-derived carbohydrates (tapioca flour) to produce water-soluble C5-C15 compounds was developed in a single reactor system. WO3-ZrO2 efficiently catalyzed the hydrolysis/dehydration of these feedstocks to 5-hydroxymethylfurfural and furfural, while the impregnation of WO3-ZrO2 with Pd allowed sequential aldolcondensation/hydrogenation of these furans to C5-C15 compounds. The highest C5-C15 yields of 14.8-20.3% were observed at a hydrolysis/dehydration temperature of 573 K for 5 min, an aldol-condensation temperature of 353 K for 30 h, and a hydrogenation temperature of 393 K for 6 h. The C5-C15 yield from tapioca flour was higher than that from corncobs (20.3% compared to 14.8%). Tapioca flour produced more C6/C9/C15, whereas corncobs generated more C5/C8/C13 compounds due to the presence of hemicellulose in the corncobs. These water-soluble organic compounds can be further converted to liquid alkanes with high cetane numbers for replacing diesel fuel in transportation applications.

  2. Cross-aldol Condensation of Cycloalkanones and Aromatic Aldehydes in the Presence of Nanoporous Silica-based Sulfonic Acid (SiO2-Pr-SO3H) under Solvent Free Conditions

    Institute of Scientific and Technical Information of China (English)

    MOHAMMADI ZIARANI Ghodsi; BADIEI Alireza; ABBASI Alireza; FARAHANI Zahra

    2009-01-01

    The aromatic aldehydes underwent cross aldol condensation with cycloalkanones in the presence of a catalytic amount of nanoporous silica-based sulfonic acid (SiO2-Pr-SO3H) under solvent-free conditions to afford the corresponding a,a'-bis(substituted benzylidene)cycloalkanones in excellent yields with short reaction time without any side reactions.This method is very general,simple and environmentally friendly in contrast with other existing methods.SiO2-Pr-SO3H was proved to be an efficient heterogeneous solid acid catalyst,which could be easily handled and removed from the reaction mixture by simple filtration,and also recovered and reused without loss of reactivity.

  3. Direct Asymmetric Aldol Type Reaction with Ethyl Diazoacetate: Stereoselective Synthesis of α, β-Dihydroxy Esters

    Institute of Scientific and Technical Information of China (English)

    LIAO Ming-Yi; YAO Wen-Gang; FENG Hai-Tao; WANG Jian-Bo

    2003-01-01

    @@ Enantioselective aldol condensation under catalytic condition remains a challenging task in modern organic synthesis, and numerous efforts have been directed to this area. In particular, the direct catalytic asymmetric aldol reaction is very attractive considering the requirement of atom efficiency. This has been studied only recently, and several very practical processes have been developed. We have recently initiated a study on the direct asymmetric aldol type reaction with ethyl diazoacetate as nucleophile. Moderate enantioselectivities (65% ~91% ee ) were achieved in the condensation of aldehydes with ethyl diazoacetate catalyzed by the chiral complex of BINOL derivatives-Zr (OBu- t )4. [1

  4. Thermodynamics of Aldol Condensation of Acetaldehyde%乙醛缩合反应体系热力学计算和分析

    Institute of Scientific and Technical Information of China (English)

    伍艳辉; 梁泽磊; 刘剑; 刘仲能

    2011-01-01

    The standard enthalpies of formation, the standard Gibbs free energy of formation and the heat capacity of each compound in acetaldehyde condensation reaction system were calculated with the application of Yoneda group contribution method. Comparison of the calculated results with some literature values show that the calculation results are reliable.Then the reaction enthalpies, reaction Gibbs free energy changes and equilibrium constants of relevant reactions in this system from 278 K to 368 K in liquid phase and 600 K in vapor phase were calculated and analyzed. The results show that the temperature has important influence on the main reaction.Conducting the reactions in liquid phase at low temperature benefited the main reaction, while high temperature led to low conversion and selectivity. 2,4-hexadienoic aldehyde was the main by-product. The thermodynamic analysis agreed well with experimental results. Acetaldehyde condensation is not recommended to proceed at high temperature. To improve the conversion and selectivity of practical reaction, the temperature is proposed be controlled reasonably or the main product needs to be separated from the reactant in time.%采用Yoneda基团贡献法估算了乙醛羟醛缩合反应体系中各物质的标准生成焓、标准熵和等压热容,与部分文献值的比较表明估算较为准确.在此基础上计算了278-368 K液相反应和600 K气相反应时主、副反应的反应焓变、反应吉布斯自由能变和反应平衡常数.结果表明温度对主反应影响较大,低温液相反应对主反应有利,高温气相反应选择性低,主要副产物为2,4-己二烯醛.热力学分析与实验结果一致,乙醛缩合反应不宜采用高温气固相反应.因此实际生产中需对反应温度进行合理控制或对反应产物和原料及时分离,以提高反应转化率和选择性.

  5. Metal-catalyzed asymmetric aldol reactions

    Energy Technology Data Exchange (ETDEWEB)

    Dias, Luiz C.; Lucca Junior, Emilio C. de; Ferreira, Marco A. B.; Polo, Ellen C., E-mail: ldias@iqm.unicamp.br [Universidade de Campinas (UNICAMP), SP (Brazil). Inst. de Quimica

    2012-12-15

    The aldol reaction is one of the most powerful and versatile methods for the construction of C-C bonds. Traditionally, this reaction was developed in a stoichiometric version; however, great efforts in the development of chiral catalysts for aldol reactions were performed in recent years. Thus, in this review article, the development of metal-mediated chiral catalysts in Mukaiyama-type aldol reaction, reductive aldol reaction and direct aldol reaction are discussed. Moreover, the application of these catalysts in the total synthesis of complex molecules is discussed. (author)

  6. Facile Aldol Reaction Between Unmodified Aldehydes and Ketones in Bronsted Acid Ionic Liquids

    Institute of Scientific and Technical Information of China (English)

    LIU Bao-you; ZHAO Di-shun; XU Dan-qian; XU Zhen-yuan

    2007-01-01

    A series of condensation reactions of unmodified ketones and aromatic aldehydes to prepare α ,β-unsaturated carbonyl compounds by means of Aldol reactions in Bronsted acid ionic liquids(BAILs) was explored. 1-Butyl-3-methylimidazolium hydrogen sulphate( BMImHSO4 ) acting as an effective media and catalyst in aldol reactions was compared with other BAILs, with the advantages of high conversion and selectivity. The product was easily isolated andthe left ionic liquid can be readily recovered and reused at least 3 times with almost the same efficiency. The scope and limitation of the present method were explored and the possible catalytic mechanism was speculated.

  7. Chiral Diamine-catalyzed Asymmetric Aldol Reaction

    Institute of Scientific and Technical Information of China (English)

    LI Hui; XU Da-zhen; WU Lu-lu; WANG Yong-mei

    2012-01-01

    A highly efficient catalytic system composed of a simple and commercially available chiral primary diamine (1R,2R)-cyclohexane-1,2-diamine(6) and trifluoroacetic acid(TFA) was employed for asymmetric Aldol reaction in i-PrOH at room temperature.A loading of 10%(molar fraction) catalyst 6 with TFA as a cocatalyst could catalyze the Aldol reactions of various ketones or aldehydes with a series of aromatic aldehydes,furnishing Aldol products in moderate to high yields(up to >99%) with enantioselectivities of up to >99% and diastereoselectivities of up to 99:1.

  8. An unprecedented, tandem Aldol-Grob reaction sequence

    Energy Technology Data Exchange (ETDEWEB)

    Kabalka, G.W.; Tejedor, D.; Li, N.S.; Malladi, R.R.; Trotman, S. [Univ. of Tennessee, Knoxville, TN (United States)

    1998-09-18

    The authors report an unprecedented, tandem Aldol-Grob sequence involving the reaction of ketones with aromatic aldehydes in nonnucleophilic solvents in the presence of boron trifluoride. Although a detailed study of the reaction mechanism has not yet been completed, the consistent formation of (E)-alkene products, as well as the fact that aromatic aldehydes appear to be required, would point toward the intermediacy of a carbocation derivative. A reasonable mechanism would involve the formation of the mixed aldol followed by the formation and subsequent nonsynchronous ring opening of a lactol. The proposed fragmentation is reminiscent of two-step Grob fragmentations that have been reported for N-halo-{alpha}-amino acids and cyclobutane hemiacetals as well as the acid-catalyzed fragmentation of {beta}-hydroxy acetals. The authors examined the effect of various acids on the reaction sequence in order to ascertain which would be most efficient. They conclude that boron trifluoride is the most effective of the acids studied in achieving the new tandem condensation-cleavage sequence.

  9. Acid-Base Pairs in Lewis Acidic Zeolites Promote Direct Aldol Reactions by Soft Enolization.

    Science.gov (United States)

    Lewis, Jennifer D; Van de Vyver, Stijn; Román-Leshkov, Yuriy

    2015-08-17

    Hf-, Sn-, and Zr-Beta zeolites catalyze the cross-aldol condensation of aromatic aldehydes with acetone under mild reaction conditions with near quantitative yields. NMR studies with isotopically labeled molecules confirm that acid-base pairs in the Si-O-M framework ensemble promote soft enolization through α-proton abstraction. The Lewis acidic zeolites maintain activity in the presence of water and, unlike traditional base catalysts, in acidic solutions.

  10. Small Organic Molecules for Direct Aldol Reaction

    Institute of Scientific and Technical Information of China (English)

    TANG Zhuo; GONG Liu-Zhu; MI Ai-Qiao; JIANG Yao-Zhong

    2004-01-01

    Since the pioneering finding by List and Barbas Ⅲ and their coworkers that L-proline could work as a catalyst in the intermolecular direct aldol reaction, the concept of small organic molecules as catalysts has received great attention. However, new organic molecule which have better catalysis ability are reported scarcely.Our groups1 found L-Prolinamides 1 to be active catalysts for the direct aldol reaction of 4-nitrobenaldehyde with neat acetone at room temperature. The enantioselectivity increases as the amide N-H becomes more acidic and thus a better hydrogen bond donor. Introducing another proton donor, hydroxyl, in the catalyst lead to a further improvement in the catalytic enantioselectivity.The calculations reveal that the amide N-H and the terminal hydroxyl groups form hydrogen bonds with the benzaldehyde substrate. These hydrogen bonds reduce the activation energy and cause high enantioselectivity.Catalyst 2, prepared from L-proline and (1S, 2S)-diphenyl-2-aminoethanol, exhibits high enantioselectivities of up to 93% ee for aromatic aldehydes and up to >99% ee for aliphatic aldehydes. It is noteworthy that our results refuted the conventional wisdom that the carboxylic acid group of proline is a reqirement for high enatioselectivity and provide a powerful strategy in the molecular design of new organic catalyst because plentiful chiral resource containing multi-hydrogen bonding donor, for example, peptides.Very recently, we found that L-proline-based peptides 3-7 can catalyze the aldol reactions of hydroxyacetone with aldehydes 8 in aqueous media, to give 1,4-diols 9, the disfavored products with either aldolase or L-proline. Both peptides 5 and 6 give good results.The abilities of peptides 5 and 6 to catalyze the direct aldol reactions of hydroxyacetone with avariety of aldehydes were examined under optimal conditions. The results are shown in table. Highyields and entioselectivities of up to 96% ee were observed for aromatic aldehydes

  11. Preparation and Characterization of Amine Grafted SBA-15 Catalysts and Their Application in Aldol Condensation Reaction%SBA-15接枝有机胺官能团催化剂的制备、表征及在醇醛缩合反应中的应用

    Institute of Scientific and Technical Information of China (English)

    任洪清; 谢建军; 刘华财; 阴秀丽; 吴创之

    2014-01-01

    采用后接枝法对介孔分子筛载体SBA-15接枝伯胺基(PA)、仲胺基(SA)、叔胺基(TA)和哌嗪基(PP)4种有机胺官能团制得4种催化剂,用XRD、BET、TG、SEM和元素分析仪对所制备的固体碱催化剂进行表征,以糠醛、丙酮为生物油模型化合物研究了4种催化剂的醇醛缩合反应性能,考察了接枝环境、接枝剂官能团、溶剂及温度对糠醛转化率及糠叉丙酮( FA)与二糠叉丙酮( F2 A)选择性的影响。结果表明,XRD及SEM图谱显示后接枝法胺基化改性SBA-15保留了载体高度有序的孔道结构,BET分析结果表明接枝后SBA-15比表面积从829 m2/g下降至292 m2/g(哌嗪基SBA-15),经TG与元素分析计算得到N的接枝量为0.6~1.0 mmol/g;采用N2保护条件进行接枝反应可提高催化剂的催化性能,使用质子型溶剂、升高反应温度均有利于提高糠醛转化率和目标产物选择性,4种碱性官能团中伯胺基具有最高的催化活性和产物选择性。 N2保护环境下以H2 O为溶剂,糠醛和丙酮在 PA/SBA-15催化下80℃经8 h反应后,糠醛转化率为82.6%,FA和F2 A选择性分别为41.4%、8.7%。%Solid basic catalysts were synthesized by post-grafting four different organic amines, i. e. primary amine ( PA ) , secondary amine(SA), tertiary amine(TA) and piperazidine(PP) to mesoporous SBA-15. The samples were characterized by X-ray diffraction, nitrogen adsorption, thermogravimetric analysis, scanning electron microscopy and elemental analysis. The activity of prepared catalysts was tested in aldol condensation reaction of bio-oil model compounds (furfural and acetone). The influence of graft reaction conditions, different functional groups of amine, solvents and temperature on conversion of furfural and selectivity of FA and F2 A were investigated. The results indicated that the prepared samples retain excellent ordered mesoporous structure with the amino loading at 0. 6 - 1. 0 mmol/g. The catalytic activity

  12. Asymmetric Aldol Reaction Catalyzed by Modularly Designed Organocatalysts

    Institute of Scientific and Technical Information of China (English)

    Sinha, Debarshi; Mandal, Tanmay; Gogoi, Sanjib; Goldman, Joshua J.; 赵从贵

    2012-01-01

    The self-assembly of the precatalyst modules, which are amino acids and cinchona alkaloid derivatives, leads to the direct formation of the desired organocatalysts without any synthesis. These modularly designed organocatalysts (MDOs) may be used for catalyzed asymmetric aldol reaction the corresponding aldol products may be obtained in mediocre diastereoselectivities (up to 79 : 21 dr). Depending on structure of the aldehyde substrates, to excellent ee values (up to 92% ee) with moderate

  13. Direct asymmetric aldol reactions catalyzed by lipase from porcine pancreas.

    Science.gov (United States)

    Zheng, Jing; Xie, Bang-Hua; Chen, Yan-Li; Cao, Jian-Fei; Yang, Yang; Guan, Zhi; He, Yan-Hong

    2014-01-01

    Porcine pancreas lipase type II (PPL II) exhibited unnatural catalytic activity in direct asymmetric aldol reactions between cyclic ketones and aromatic or heteroaromatic aldehydes in acetonitrile in the presence of phosphate buffer. A wide range of substrates was accepted by the enzyme to afford the corresponding aldol products in low to high yields (10-98%), with moderate to excellent enantioselectivities (53-94% ee, for anti-isomers) and low to moderate diastereoselectivities (48/52-87/13 dr, anti/syn). This methodology expands the application of PPL II, and it might be developed into a potentially valuable method for sustainable organic synthesis.

  14. Solvent- and Catalyst-Free Direct Aldol Reactions

    Institute of Scientific and Technical Information of China (English)

    王宗令; 张成潘; 张春桃; 肖吉昌

    2011-01-01

    Aldol reaction between simple benzaldehydes and ketones successfully happened in solvent- and catalyst-free condition. The desired products were obtained in moderate yield at suitable temperature. Heat was assumed as the driving force for the reaction. This approach has obvious advantages to fully meet the requirement of the principles of green chemistry.

  15. Synthesis of sulphonated mesoporous phenolic resins and their application in esterification and asymmetric aldol reactions

    Energy Technology Data Exchange (ETDEWEB)

    Muylaert, Ilke [Department of Inorganic and Physical Chemistry, Ghent University, Center for Ordered Materials, Organometallics and Catalysis (COMOC), Krijgslaan 281-S3, 9000 Ghent (Belgium); Verberckmoes, An, E-mail: an.verberckmoes@hogent.be [Department of Inorganic and Physical Chemistry, Ghent University, Center for Ordered Materials, Organometallics and Catalysis (COMOC), Krijgslaan 281-S3, 9000 Ghent (Belgium); Associated Faculty of Applied Engineering Sciences, University College Ghent, Valentin Vaerwyckweg 1, 9000 Ghent (Belgium); Spileers, Jeremy [Associated Faculty of Applied Engineering Sciences, University College Ghent, Valentin Vaerwyckweg 1, 9000 Ghent (Belgium); Demuynck, Anneleen; Peng, Li; De Clippel, Filip; Sels, Bert [Katholieke Universiteit Leuven, Centre for Surface Chemistry and Catalysis (COK), Kasteelpark Arenberg 23, 3001 Heverlee (Belgium); Van Der Voort, Pascal, E-mail: pascal.vandervoort@ugent.be [Department of Inorganic and Physical Chemistry, Ghent University, Center for Ordered Materials, Organometallics and Catalysis (COMOC), Krijgslaan 281-S3, 9000 Ghent (Belgium)

    2013-02-15

    Mesoporous phenolic resins were functionalized with sulphonic acid groups by four different types of sulphonation procedures: (i) direct sulphonation on the aromatic ring, (ii) alkyl sulphonation of the aromatic ring, and functionalizations of the phenolic hydroxyl surface by using an aryl silane, 2-(4-chlorosulphonylphenyl)ethyl trichlorosilane (iii) or a propyl silane, 3-mercaptopropyltrimethoxysilane (iv). The highest acidity loadings were obtained through direct sulphonation with fuming sulphuric acid (1.90 mmol H{sup +} g{sup −1}) or chlorosulphonic acid (1.31 mmol H{sup +} g{sup −1}) and these materials showed the highest conversion (97+ %) in Fischer esterification of acetic acid with propanol. However, the alkyl sulphonic groups, obtained through sulphonation procedure (ii) showed the highest stability in terms of maintenance of their acidity after use in consecutive catalytic runs or leaching treatments. This was demonstrated both through evaluation of the regenerated catalysts in a consecutive esterification run and during a leaching resistance test in aqueous medium. Moreover, the developed sulphonated mesoporous phenolic resins are presented as novel support for the non-covalent immobilization of an L-phenylalanine derived chiral diamine organocatalyst for asymmetric aldol reactions. The immobilization is established by an acid–base interaction between the sulphonic acid group and the amine function. The acidity and in particular the electronic withdrawing environment of the sulphonic acid groups influence enormously the catalytic performance of the non-covalent immobilized chiral diamine catalyst (aromatic > aliphatic). - Highlights: ► Different types of sulphonation procedures for mesoporous phenolic resins. ► Influence of acidity and electronic withdrawing environment. ► Novel support for non-covalent immobilization of chiral diamine catalyst. ► Catalytic performance in esterification and asymmetric aldol condensation. ► Demonstration

  16. Investigating Ionic Effects Applied to Water Based Organocatalysed Aldol Reactions

    Directory of Open Access Journals (Sweden)

    Joshua P. Delaney

    2011-12-01

    Full Text Available Saturated aqueous solutions of various common salts were examined for their effect on aqueous aldol reactions catalysted by a highly active C2-symmetric diprolinamide organocatalyst developed in our laboratory. With respect to the aldol reaction between cyclohexanone and 4-nitrobenzaldehyde, deionised water was always a superior medium to salt solutions though some correlation to increasing anion size and depression in enantiomeric excess could be observed. Additionally, the complete inhibition of catalyst activity observed when employing tap water could be alleviated by the inclusion of ethylenediaminetetraacetate (EDTA into the aqueous media prior to reaction initiation. Extension of these reaction conditions demonstrated that these ionic effects vary on a case-to-case basis depending on the ketone/aldehyde combination.

  17. Zinc-prolinamide complex catalyzed direct asymmetric aldol reactions in the presence of water

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    An efficient direct asymmetric aldol reaction with zinc triflate and prolinamides as combined catalysts is reported.A series of chiral prolinamides have been designed and used in the direct aldol reaction resulting in the desired products with excellent yields(up to 94% yield) and high enantioselectivities(up to 96% ee).Water was found to play a significant role in the formation of the aldol products,which suggests a new strategy in the design of new organic catalysts.

  18. One-step Synthesis of n-Butanol from Ethanol Condensation over Alumina-supported Metal Catalysts

    Institute of Scientific and Technical Information of China (English)

    Ke Wu YANG; Xuan Zhen JIANG; Wei Chao ZHANG

    2004-01-01

    One-step synthesis of n-butanol from bimolecular condensation of ethanol was firstly achieved over nickel supported gamma alumina catalyst. A mechanism of dehydration path for the growth of carbon chain by eliminating a hydroxy group from one ethanol molecule with a α-H of other ethanol molecule rather than aldol condensation was verified.

  19. Estrutura & História.

    Directory of Open Access Journals (Sweden)

    Alicia Ferreira Gonçalves

    2015-06-01

    Full Text Available O presente artigo discorre sobre as ligações entre estrutura e história a partir das perspectivas estruturalista francesa e culturalista norte-americana, focalizando as interlocuções teóricas entre Claude Lévi-Strauss e Marshall Sahlins entre o final dos anos 1940 e ao longo dos anos 1990 do século XX.

  20. Aldol reactions of the trans-o-hydroxybenzylidenepyruvate hydratase-aldolase (tHBP-HA) from Pseudomonas fluorescens N3.

    Science.gov (United States)

    Sello, Guido; Di Gennaro, Patrizia

    2013-08-01

    In this paper, a recombinant trans-o-hydroxybenzylidenepyruvate hydratase-aldolase (tHBP-HA) of Pseudomonas fluorescens N3 was used as a new catalyst for aldol condensation reactions. The reaction of some aldehydes with a different electronic activation catalyzed by tHBP-HA is presented and discussed together with some hints on the product structure. The enzyme is strictly pyruvate-dependent but uses different aldehydes as acceptors. The structure of the products is highly dependent on the electronic characteristics of the aldehyde. The results are interesting for both their synthetic importance and the mechanism of the formation of the products. Not only the products obtained and the recognition power are reported, but also some characteristics of its mechanism are analyzed. The results clearly show that the enzyme is efficiently prepared, purified, and stored, that it recognizes many different substrates, and that the products depend on the substrate electronic nature.

  1. Catalytic asymmetric 5-enolexo aldolizations. A computational study.

    Science.gov (United States)

    Georgieva, Miglena K; Duarte, Filipe J S; Queirós, Margarida V B; Santos, A Gil

    2012-07-06

    The diastereo- and enantioselectivity obtained experimentally by Enders et all. (Enders, D.; Niemeier, O.; Straver, S. Synlett 2006, 3399-3402) in the amine-catalyzed intramolecular 5-enolexo aldolization of 1,6-dicarbonyl compounds were fully rationalized using density functional theory methods. A polarizable continuum model was used to describe solvent effects. While 6-enolexo aldolizations are well described by Houk's model on the basis of steric and electrostatic contacts, the main factors conditioning the final selectivity in 5-enolexo processes are calculated to be quite different. Thus, the selectivity results from the summation of several small electrostatic contacts with an unexpected HOMO electronic overlapping plus the ring strain of the five-membered ring, whereas steric effects seem to be unimportant. Our results indicate, in contrast with 6-enolexo processes, that high selectivities are not expected in this type of reaction and that the experimental selectivity shall be very dependent on the reaction conditions, as known experimental results seem to suggest. 7-enolendo products are not expected, as they are predicted to be formed by higher energetic transition states. Variable reaction rates, experimentally observed with different catalysts, are suggested to be mainly a result of different catalyst solubilities.

  2. Domino Michael-Michael and Aldol-Aldol Reactions: Diastereoselective Synthesis of Functionalized Cyclohexanone Derivatives Containing Quaternary Carbon Center.

    Science.gov (United States)

    Ghorai, Manas K; Halder, Sandipan; Das, Subhomoy

    2015-10-02

    A simple strategy for the synthesis of highly functionalized cyclohexanone derivatives containing an all-carbon quaternary center from α-(aryl/alkyl)methylidene-β-keto esters or β-diketones via a K-enolate mediated domino Michael-Michael reaction sequence with moderate to good yield and excellent diastereoselectivity (de > 99%) is described. Interestingly, Li-base mediated reaction of α-arylmethylidene-β-diketones affords functionalized 3,5-dihydroxy cyclohexane derivatives as the kinetically controlled products via a domino aldol-aldol reaction sequence with excellent diastereoselectivity. Li-enolates of the β-keto esters or β-diketones undergo facile domino Michael-Michael reaction with nitro-olefins to afford the corresponding nitrocyclohexane derivatives in good yields and excellent diastereoselectivity (de > 99%). The formation of the products and the observed stereoselectivity were explained by plausible mechanisms and supported by extensive computational study. An asymmetric version of the protocol was explored with (L)-menthol derived nonracemic substrates, and the corresponding nonracemic cyclohexanone derivatives containing an all-carbon quaternary center were obtained with excellent stereoselectivity (de, ee > 99%).

  3. Direct asymmetric aldol reaction using MBHA resin-supported peptide containing L-proline unit

    Institute of Scientific and Technical Information of China (English)

    Liang Zhang; Wen Bo Ding; Yong Ping Yu; Hong Bin Zou

    2009-01-01

    MBHA resin-supported tripeptide catalyst system containing L-proline unit has been developed for use in the direct asymmetric aldol reaction of acetone and aldehydes,which afford the corresponding products with satisfactory isolated yields and enantiomeric excesses.

  4. Small Peptides Catalyzed Direct Aldol Reactions of Aldehydes with Hydroxyacetone with Regiocontrol in Aqueous Media

    Institute of Scientific and Technical Information of China (English)

    TANG,Zhuo; YANG,Zhi-Hua; CUN,Lin-Feng; GONG,Liu-Zhu; MI,Ai-Qiao; JIANG,Yao-Zhong

    2004-01-01

    @@ Very recently, we[1] found that L-proline amides and dipeptides acted as efficient catalysts for the asymmetric direct aldol reaction. We report here that L-proline-based peptides 1~5 can catalyze the aldol reactions of hydroxyacetone with aldehydes 6 in aqueous media, to give 1,4-diols (7), the disfavored products with either aldolase or L-proline. Both peptides 3 and 4 give good results.

  5. The pivotal role of chelation as a stereochemical control element in non-Evans anti aldol product formation.

    Science.gov (United States)

    Shinisha, C B; Sunoj, Raghavan B

    2010-06-18

    The origin of stereoselective formation of Evans syn and non-Evans anti aldol products in the reaction between titanium enolate derived from N-succinyloxazolidinone and benzaldehyde is established by using transition-state modeling. The chelated transition-state model is found to hold the key to otherwise less likely non-Evans anti aldol product, whereas the nonchelated model offers a convincing rationalization toward Evans syn aldol product. The computed results are in agreement with the reported experimental observations.

  6. The Aldol Addition and Condensation: The Effect of Conditions on Reaction Pathway

    Science.gov (United States)

    Crouch, R. David; Richardson, Amie; Howard, Jessica L.; Harker, Rebecca L.; Barker, Kathryn H.

    2007-01-01

    The reaction of a ketone and an aldehyde in aqueous Na[subscript 2]CO[subscript 2] is described. This experiment is performed in the absence of strong bases or organic solvents and offers the opportunity for students to observe the critical role that reaction temperature and base strength have in determining the product of the base-mediated…

  7. Three-Component Halo Aldol Condensation of Thioacrylates with Aldehydes Mediated by Titanium (IV Halide

    Directory of Open Access Journals (Sweden)

    Guigen Li

    2002-01-01

    Full Text Available a,b-Ethyl thioacrylate was difuctionalized by a tandem X-C/C=C bond formation reaction. The new system uses Ti (IV halide as both the Lewis acidic promoter and the halogen source for the Michael-type addition onto the thioacrylate. The titanium enolate species resulting from Michael-type addition react with aldehydes followed by dehydration to afford trisubstituted olefin products. Complete geometric selectivity (>95% and up to 72% yield have been obtained for 7 examples.

  8. Montmorillonite Clay-Promoted, Solvent-Free Cross-Aldol Condensations under Focused Microwave Irradiation

    Directory of Open Access Journals (Sweden)

    Damiano Rocchi

    2014-06-01

    Full Text Available An environmentally benign, clean and general protocol was developed for the synthesis of aryl and heteroaryl trans-chalcones. This method involved solvent-free reaction conditions under microwave irradiation in the presence of a clay-based catalyst, and afforded the target compounds in good yields and short reaction times. Furthermore, the same conditions allowed the synthesis of symmetrical, diarylmethylene-α,β-unsaturated ketones from aromatic aldehydes and ketones.

  9. As estruturas territoriais dos insetos

    Directory of Open Access Journals (Sweden)

    Witold Zmitrowicz

    2001-04-01

    Full Text Available AS SOCIEDADES de insetos utilizam muitos tipos de materiais e recursos biológicos para construir seus abrigos. As disposições espaciais e estruturas de apoio são criadas de forma engenhosa, oferecendo condições adequadas para a criação da prole, a produção ou o armazenamento de alimentos. A sua localização e as suas interconexões as inserem nas áreas circundantes, e elas podem aproveitar vantagens circunstanciais oferecidas pelo meio ambiente. As técnicas de construção e de manutenção fazem parte da cultura desses seres, e permitem uma visão interessante de soluções obtidas mediante a utilização eficiente de uma ampla gama de recursos disponíveis.INSECT SOCIETIES use many kinds of materials and biologic resources to build their shelters. Space arrangements and supporting structures are created in an ingenious way to provide adequate conditions for development of the young, for food production or storage. Their location and interconnections insert them into the surrounding areas, and they may take advantage of circumstantial benefits of their environment. Building and maintenance techniques belong to the culture of these beings, and they offer an interesting vision of solutions based on efficient use of a wide range of available resources.

  10. One-pot synthesis of cyclic aldol tetramer and,β-unsaturated aldol from linear aldehydes using quaternary ammonium combined with sodium hydroxide as catalysts

    Institute of Scientific and Technical Information of China (English)

    许海峰; 钟宏; 王帅; 李方旭

    2015-01-01

    One-pot synthesis of cyclic aldol tetramer anda,β-unsaturated aldol from C3−C8 linear aldehydes using phase-transfer catalyst (PTC), quaternary ammonium, combined with sodium hydroxide as catalysts was investigated. Butanal was subjected for detail investigations to study the effect of parameters. It was found that the selectivity of cyclic aldol tetramer depends greatly on the operating conditions of the reaction, especially the PTC/butanal molar ratio. The average selectivity of 2-hydroxy-6-propyl-l, 3, 5-triethyl-3-cyclohexene-1-carboxaldehyde (HPTECHCA) was 54.41% using tetrabutylammonium chloride combined with 14% (mass fraction) NaOH as catalysts at 60 °C for 2 h with a PTC-to-butanal molar ratio of 0.09:1. Pentanal was more likely to generate cyclic aldol tetramer compared with other aldehydes under the optimum experimental conditions. Recovery of the PTC through water washing followed by adding enough sodium hydroxide from the washings was also demonstrated.

  11. A self-assembled nanotube for the direct aldol reaction in water.

    Science.gov (United States)

    Lee, Kwang Soo; Parquette, Jon R

    2015-11-01

    Nanotubes formed by the aqueous assembly of a proline-lysine dipeptide (1) were used to create the hydrophobic microenvironments required to catalyze the aldol reaction in water. The self-assembly process occurred most efficiently in the presence of the substrates, producing an array of homogeneous nanotubes under the reaction conditions. The nanotubes formed by dipeptide 1 served as an efficient catalyst for the aldol reaction that functioned at low loading levels and provided good to excellent conversions. The catalytic activity of 1 was minimal under conditions that dissociated the nanotube into soluble monomers.

  12. Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity.

    Science.gov (United States)

    Osborne, James D; Willis, Michael C

    2008-10-28

    The pathway for the combination of enones and beta-S-substituted aldehydes using Rh-catalysis can be switched between a hydroacylation reaction or a reductive aldol reaction by simple choice of the phosphine ligand; this catalyst controlled switch allows access to new ketone hydroacylation products; useful 1,4-diketone intermediates for the synthesis of N-, S- and O-heterocycles.

  13. RUTHENIUM-CATALYZED TANDEM OLEFIN MIGRATION-ALDOL AND MANNICH-TYPE REACTIONS IN IONIC LIQUID.

    Science.gov (United States)

    In the presence of a catalytic amount of RuCl2(PPh3)3, a cross-coupling of 3-buten-2-ol with aldehydes and imines was developed via a tandem olefin migration--aldol--Mannich reaction in bmim[PF6]. With In(OAc)3 as a co-catalyst, a-vinylbenzyl alcohol and aldehydes underwent sim...

  14. Proline Catalyzed Asymmetric Aldol Reaction between Methyl Ketones and 1-Aryl-2,2,2-trifluoroethanones

    Institute of Scientific and Technical Information of China (English)

    QIU Li-Hua; SHEN Zong-Xuan; SHI Chang-Qing; LIU Yan-Hua; ZHANG Ya-Wen

    2005-01-01

    Direct asymmetric aldol addition of methyl ketones to 2,2,2-trifluoro-1-phenylethanone and its ring-substituted derivatives was achieved using L-proline as a chiral promoter. Various optically active β-trifluoromethyl-β-hydroxy ketones were obtained in almost quantitative yields with moderate enantioselectivities up to 64 % ee.

  15. Heterogeneously Catalysed Aldol Reactions in Supercritical Carbon Dioxide as Innovative and Non-Flammable Reaction Medium

    DEFF Research Database (Denmark)

    Musko, Nikolai; Grunwaldt, Jan-Dierk

    2011-01-01

    hydrogenation of 2-butenal and is therefore a potential catalyst for the “one-pot” synthesis of 2-ethyl-2-hexenal and 2-ethylhexanal via combined hydrogenation and aldol reaction from 2-butenal. A number of characterisation techniques, such as temperature-programmed desorption of ammonia (NH3-TPD), transmission...

  16. Total Synthesis of the Antimicrotubule Agent (+)-Discodermolide Using Boron-Mediated Aldol Reactions of Chiral Ketones.

    Science.gov (United States)

    Paterson; Florence; Gerlach; Scott

    2000-01-01

    With a similar mechanism of action to taxol, the title compound 1 is a particularly promising candidate for development in cancer chemotherapy. This efficient synthesis, based on stereocontrolled aldol reactions, should help to overcome the scarce natural supply of 1 from the rare sponge source.

  17. ALDOL- AND MANNICH-TYPE REACTIONS VIA IN SITU OLEFIN MIGRATION IN IONIC LIQUID

    Science.gov (United States)

    An aldol-type and a Mannich-type reaction via the cross-coupling of aldehydes and imines with allylic alcohols catalyzed by RuCl2(PPh3)3 was developed with ionic liquid as the solvent. The solvent/catalyst system could be reused for at least five times with no loss of reactiv...

  18. Chitosan aerogel: a recyclable, heterogeneous organocatalyst for the asymmetric direct aldol reaction in water.

    Science.gov (United States)

    Ricci, Alfredo; Bernardi, Luca; Gioia, Claudio; Vierucci, Simone; Robitzer, Mike; Quignard, Françoise

    2010-09-14

    Aerogel microspheres of chitosan, an abundant biopolymer obtained from marine crustaceans, have been successfully applied to catalyze the asymmetric aldol reaction in water, providing the products in high yields and with good stereoselectivity (up to 93% ee) and recyclability (up to 4 runs). Yields were favourably affected by additives such as DNP and stearic acid.

  19. Mukaiyama Aldol Reaction of 1, 2-Bis(trimethylsiloxy) Cyclobutene Catalyzed by Magnesium(II) Iodide

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Efficient Mukaiyama-type aldol reaction of 1, 2-bis(trimethylsiloxy)cyclobutene with aromatic aldehydes catalyzed by MgI2 is reported. The resulting succinoylation product of aldehyde was converted into the synthetic useful γ-lactone and butenolide derivatives.

  20. Water Condensation

    DEFF Research Database (Denmark)

    Jensen, Kasper Risgaard; Fojan, Peter; Jensen, Rasmus Lund

    2014-01-01

    The condensation of water is a phenomenon occurring in multiple situations in everyday life, e.g., when fog is formed or when dew forms on the grass or on windows. This means that this phenomenon plays an important role within the different fields of science including meteorology, building physics......, and chemistry. In this review we address condensation models and simulations with the main focus on heterogeneous condensation of water. The condensation process is, at first, described from a thermodynamic viewpoint where the nucleation step is described by the classical nucleation theory. Further, we address...

  1. Transition state models for probing stereoinduction in Evans chiral auxiliary-based asymmetric aldol reactions.

    Science.gov (United States)

    Shinisha, C B; Sunoj, Raghavan B

    2010-09-08

    The use of chiral auxiliaries is one of the most fundamental protocols employed in asymmetric synthesis. In the present study, stereoselectivity-determining factors in a chiral auxiliary-based asymmetric aldol reaction promoted by TiCl(4) are investigated by using density functional theory methods. The aldol reaction between chiral titanium enolate [derived from Evans propionyl oxazolidinone (1a) and its variants oxazolidinethione (1b) and thiazolidinethione (1c)] and benzaldehyde is examined by using transition-state modeling. Different stereochemical possibilities for the addition of titanium enolates to aldehyde are compared. On the basis of the coordination of the carbonyl/thiocarbonyl group of the chiral auxiliary with titanium, both pathways involving nonchelated and chelated transition states (TSs) are considered. The computed relative energies of the stereoselectivity-determining C-C bond formation TSs in the nonchelated pathway, for both 1a and 1c, indicate a preference toward Evans syn aldol product. The presence of a ring carbonyl or thiocarbonyl group in the chiral auxiliary renders the formation of neutral TiCl(3)-enolate, which otherwise is energetically less favored as compared to the anionic TiCl(4)-enolate. Hence, under suitable conditions, the reaction between titanium enolate and aldehyde is expected to be viable through chelated TSs leading to the selective formation of non-Evans syn aldol product. Experimentally known high stereoselectivity toward Evans syn aldol product is effectively rationalized by using the larger energy differences between the corresponding diastereomeric TSs. In both chelated and nonchelated pathways, the attack by the less hindered face of the enolate on aldehyde through a chair-like TS with an equatorial disposition of the aldehydic substituent is identified as the preferred mode. The steric hindrance offered by the isopropyl group and the possible chelation are identified as the key reasons behind the interesting

  2. Synthesis of the cores of hypocrellin and shiraiachrome: diastereoselective 1,8-diketone aldol cyclization.

    Science.gov (United States)

    O'Brien, Erin M; Li, Jingxian; Carroll, Patrick J; Kozlowski, Marisa C

    2010-01-01

    Intramolecular 1,8-diketone aldol reactions were studied as a tool for the construction of the seven-membered rings of hypocrellin and shiraiachrome. Conditions were identified to obtain the relative stereochemistries present in the two natural products with excellent diastereoselectivity. In addition, a nine-membered ring congener, which has yet to be observed in nature, formed with high selectivity when a hindered amine was used in conjunction with silazide bases.

  3. Enantioselective aldol reaction between isatins and cyclohexanone catalyzed by amino acid sulphonamides.

    Science.gov (United States)

    Wang, Jun; Liu, Qi; Hao, Qing; Sun, Yanhua; Luo, Yiming; Yang, Hua

    2015-04-01

    Sulphonamides derived from primary α-amino acid were successfully applied to catalyze the aldol reaction between isatin and cyclohexanone under neat conditions. More interestingly, molecular sieves, as privileged additives, were found to play a vital role in achieving high enantioselectivity. Consequently, high yields (up to 99%) along with good enantioselectivities (up to 92% ee) and diastereoselectivities (up to 95:5 dr) were obtained. In addition, this reaction was also conveniently scaled up, demonstrating the applicability of this protocol.

  4. Novel chiral ionic liquid (CIL) assisted selectivity enhancement to (L)-proline catalyzed asymmetric aldol reactions

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Long; Zhang, Haibo; Luo, Huadong; Zhou, Xiaohai; Cheng, Gongzhen [College of Chemistry, Wuhan University (China)

    2011-09-15

    A significant improvement of the chemical yields (up to 88%), stereoselectivity (> 99:1) and enantiomeric excesses (up to 98%) of (L)-proline catalyzed direct asymmetric aldol reaction was found when proline based chiral ionic liquids (CILs) were added as additives. Different ratios of DMSO/H{sub 2}O as solvent and chiral ionic liquids (CILs) with chiral cations of different chain length were investigated. (author)

  5. Monofunctional primary amine: A new class of organocatalyst for asymmetric Aldol reaction

    Indian Academy of Sciences (India)

    KHIANGTE VANLALDINPUIA; PORAG BORA; GHANASHYAM BEZ

    2017-03-01

    A new class of organocatalysts involving a primary amine as the only functional group is developed for catalytic asymmetric aldol reaction of cyclohexanone/ cyclopentanone with various aryl aldehydes in thepresence of benzoic acid as an additive at −10◦C. In an unexpected observation, the primary amine catalyzed reactions gave excellent yield and good to excellent stereoselectivity, while secondary amines were found to have little or no reactivity under similar reaction conditions.

  6. Cooperative organocatalysis of Mukaiyama-type aldol reactions by thioureas and nitro compounds

    KAUST Repository

    Bukhriakov, Konstantin

    2016-05-16

    A unique organocatalytic system for Mukaiyama-type aldol reactions based on the cooperative action of nitro compounds and thioureas has been identified. This system is compatible with a wide range of substrates and does not require low temperatures, inert atmospheres, or an aqueous workup. A catalytic mechanism based on nitro group-mediated silyl cation transfer has been proposed. © The Royal Society of Chemistry 2016.

  7. A practical synthesis of (+)-discodermolide and analogues: fragment union by complex aldol reactions.

    Science.gov (United States)

    Paterson, I; Florence, G J; Gerlach, K; Scott, J P; Sereinig, N

    2001-10-01

    A practical stereocontrolled synthesis of (+)-discodermolide (1) has been completed in 10.3% overall yield (23 steps longest linear sequence). The absolute stereochemistry of the C(1)-C(6) (7), C(9)-C(16) (8), and C(17)-C(24) (9) subunits was established via substrate-controlled, boron-mediated, aldol reactions of the chiral ethyl ketones 10, 11, and 12. Key fragment coupling reactions were a lithium-mediated, anti-selective, aldol reaction of aryl ester 8 (under Felkin-Anh induction from the aldehyde component 9), followed by in situ reduction to produce the 1,3-diol 40, and a (+)-diisopinocampheylboron chloride-mediated aldol reaction of methyl ketone 7 (overturning the inherent substrate induction from the aldehyde component 52) to give the (7S)-adduct 58. The flexibility of our overall strategy is illustrated by the synthesis of a number of diastereomers and structural analogues of discodermolide, which should serve as valuable probes for structure-activity studies.

  8. Asymmetric Aldol Reaction Catalyzed by L-Proline and Achiral Thiourea Fluoroboric Acid Salt

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Eun; Lee, Haney; Kim, Taek Hyeon [Chonnam National University, Gwangju (Korea, Republic of)

    2015-01-15

    Considering its ready availability and low cost, L-proline would be the first choice catalyst for preparing aldol adducts with high diastereo- and enantioselectivity. However, proline presents some major drawbacks, including poor performance in direct aldol reactions with aromatic aldehydes, limited solubility, and reactivity in nonpolar organic solvents, and side reactions that make using high catalyst loadings necessary to reach satisfactory conversions. Therefore, numerous proline-modified organo catalysts such as prolinamides, proline thioamides, sulfonamides, chiral amines, and organic salts have been designed for direct aldol reactions. An alternative is to add a readily available additive to the reactions containing proline. This last approach is clearly advantageous in avoiding tedious chemical syntheses of organo catalysts and would ultimately allow the construction of libraries of catalyst protocols by simply changing the additive. Acid additives can influence the outcome of enamine mediated reactions; however, only a few screening studies of acid additions to thiourea organo catalysts are available in the literature. The reaction between cyclohexanone and 4-nitrobenzaldehyde was selected as a standard model reaction for screening of more effective acid additives to thiourea.

  9. As novas estruturas organizacionais das bolsas

    OpenAIRE

    Marcos Galileu Lorena Dutra

    2008-01-01

    O presente trabalho investiga as novas estruturas organizacionais das bolsas de valores e das bolsas de mercadorias e futuros, implementadas após os processos de desmutualização. É feita uma análise da importância das bolsas para o desenvolvimento econômico, bem como do seu papel de entidades auto-reguladoras. São ainda apresentados os principais fatores que motivaram a conversão das bolsas de associações mutualísticas para sociedades anônimas, bem como as conseqüências dessa alteração organi...

  10. Estrutura temporal dos tipos de xuro

    OpenAIRE

    Reboredo Nogueira, Juan Carlos

    2013-01-01

    Esta unidade didáctica forma parte do curso de Análise Económica dos Mercados Financeiros I que se imparte no primeiro cuadrimestre do Máster en Economía: Organización Industrial e Mercados Financeiros. Esta unidade ten como obxectivo analizar a estrutura temporal dos tipos de xuro, é dicir a relación existente entre os tipos de xuro a diferentes prazos. En particular, estudarase a curva cupón cero, a súa utilidade no proceso de valoración dos activos financeiros e os diferentes mé...

  11. Quests em World Of Warcraft como estrutura narrativa seriada

    Directory of Open Access Journals (Sweden)

    Jônatas Kerr de Oliveira

    2010-10-01

    Full Text Available Assumindo que as quests em World of Warcraft funcionam como uma estrutura narrativa dentro do jogo, busca-se verificar se esta estrutura apresenta características que possam caracterizá-la como uma narrativa seriada. Para tal, é feita uma análise das principais características da narrativa seriada televisiva, assim como da estrutura de quests, para verificar a viabilidade de tal aproximação. Sendo a estrutura narrativa de quests em MMORPGs uma estrutura narrativa seriada, abre-se um grande leque de possibilidades, tanto para as análises teóricas dos videogames, utilizando o ferramental adaptado, como para os game designers utilizarem este referencial para acrescer detalhes aos mundos ficcionais criados.

  12. L-Proline catalyzed aldol reactions between acetone and aldehydes in supercritical fluids:An environmentally friendly reaction procedure

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The direct asymmetric aldol reaction between various aldehydes and acetone catalyzed by L-proline catalyst was successfully carried out in supercritical CO2 (scCO2) and 1,1,1,2-tetrafluoroethane (R-134a) fluids.The enantioselectivity of 84% ee to the targeted product was achieved under 20 MPa,40 °C,and 15 mol% of the catalyst in supercritical CO2 (scCO2) fluid.The effects of reaction parameters,such as temperature,pressure,catalyst loading and different substituted aldehydes on both enantioselectivity and aldol yield were discussed.The titled reaction was also performed in 1,1,1,2-tetrafluoroethane,and the obtained results were compared with those in scCO2.This new reaction procedure provides an environmental asymmetric aldol reaction system as compared with that in organic solvents.

  13. Proline and benzylpenicillin derivatives grafted into mesoporous MCM-41: Novel organic-inorganic hybrid catalysts for direct aldol reaction

    Indian Academy of Sciences (India)

    Dwairath Dhar; Ian Beadham; Srinivasan Chandrasekaran

    2003-10-01

    New organic-inorganic hybrid catalysts were synthesized by covalent grafting of proline and benzylpenicillin derivatives into mesoporous MCM-41. These catalysts were extensively characterized using FT-IR, 13C CP MAS solid state NMR, XRD and TEM techniques. These were used as catalysts for direct, asymmetric aldol reaction between acetone and activated aromatic aldehydes. In the reaction of 4-nitro and 4-fluoro benzaldehyde, the aldol products were obtained in 36% and 59% ee respectively. The catalysts were reusable with neither significant drop in enantioselectivity nor loss of mesostructure. An attempt was made to substantiate the proposed `enamine’ mechanism for direct aldol reaction by trapping the intermediate between proline-MCM-41 and acetone.

  14. Bicyclic proline analogues as organocatalysts for stereoselective aldol reactions: an in silico DFT study.

    Science.gov (United States)

    Shinisha, C B; Sunoj, Raghavan B

    2007-04-21

    Density functional theory has been employed in investigating the efficiency of a series of bicyclic analogues of proline as stereoselective organocatalysts for the aldol reaction. Three classes of conformationally restricted proline analogues, as part of either a [2.2.1] or [2.1.1] bicyclic framework, have been studied. Transition states for the stereoselective C-C bond formation between enamines derived from [2.2.1] and [2.1.1] bicyclic amino acids and p-nitrobenzaldehyde, leading to enantiomeric products, have been identified. Analysis of the transition state geometries revealed that the structural rigidity of catalysts, improved transition state organization as well as other weak interactions influence the relative stabilities of diastereomeric transition states and help contribute to the overall stereoselectivity in the aldol reaction. These bicyclic catalysts are predicted to be substantially more effective in improving the enantiomeric excess than the widely used organocatalyst proline. Enantiomeric excesses in the range 82-95% are predicted for these bicyclic catalysts when a sterically unbiased substrate such as p-nitrobenzaldehyde is employed for the asymmetric aldol reaction. More interestingly, introduction of substituents, as simple as a methyl group, at the ortho position of the aryl aldehyde bring about an increase in the enantiomeric excess to values greater than 98%. The reasons behind the vital energy separation between diastereomeric transition states has been rationalized with the help of a number of weak interactions such as intramolecular hydrogen bonding and Coulombic interactions operating on the transition states. These predictions could have wider implications for the rational design of improved organocatalysts for stereoselective carbon-carbon bond-forming reactions.

  15. Solvent-Induced Reversal of Activities between Two Closely Related Heterogeneous Catalysts in the Aldol Reaction

    Energy Technology Data Exchange (ETDEWEB)

    Kandel, Kapil [Ames Laboratory; Althaus, Stacey M [Ames Laboratory; Peeraphatdit, Chorthip [Ames Laboratory; Kobayashi, Takeshi [Ames Laboratory; Trewyn, Brian G [Ames Laboratory; Pruski, Marek [Ames Laboratory; Slowing, Igor I [Ames Laboratory

    2013-01-11

    The relative rates of the aldol reaction catalyzed by supported primary and secondary amines can be inverted by 2 orders of magnitude, depending on the use of hexane or water as a solvent. Our analyses suggest that this dramatic shift in the catalytic behavior of the supported amines does not involve differences in reaction mechanism, but is caused by activation of imine to enamine equilibria and stabilization of iminium species. The effects of solvent polarity and acidity were found to be important to the performance of the catalytic reaction. This study highlights the critical role of solvent in multicomponent heterogeneous catalytic processes.

  16. DFT Study on the (S)-Proline-catalyzed Direct Aldol Reaction between Acetone and 4-Nitrobenzaldehyde

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    DFT/6-31G* calculations were applied to study the direct aldol reaction between acetone and 4-nitrobenzaldehyde catalyzed by (S)-proline. Four transition states associated with the stereo-controlling step, corresponding to syn and anti arrangements of methylene moiety related to the carboxylic acid group in enamine intermediate and re and si attacks to the aldehyde carbonyl carbon have been obtained. The solvent effect of DMSO was investigated with polarized continuum model. The computed energies of transition states reveal the stereo-selectivity of the reaction.

  17. Noninnocent role of N-methyl pyrrolidinone in thiazolidinethione-promoted asymmetric aldol reactions.

    Science.gov (United States)

    Sreenithya, A; Sunoj, Raghavan B

    2012-11-16

    The origin of stereoselectivity in the reaction between α-azido titanium enolate derived from chiral auxiliary N-acyl thiazolidinethione and benzaldehyde is established using the DFT(B3LYP) method. A nonchelated transition state with N-methyl-2-pyrrolidinone (NMP) bound to a TiCl(3) enolate is found to be energetically the most preferred model responsible for the formation of an Evans syn aldol product. The TS model devoid of NMP, although of higher energy, is found to be successful in predicting the right stereochemical outcome.

  18. Lewis base activation of Lewis acids: catalytic, enantioselective vinylogous aldol addition reactions.

    Science.gov (United States)

    Denmark, Scott E; Heemstra, John R

    2007-07-20

    The generality of Lewis base catalyzed, Lewis acid mediated, enantioselective vinylogous aldol addition reactions has been investigated. The combination of silicon tetrachloride and chiral phosphoramides is a competent catalyst for highly selective additions of a variety of alpha,beta-unsaturated ketone-, 1,3-diketone-, and alpha,beta-unsaturated amide-derived dienolates to aldehydes. These reactions provided high levels of gamma-site selectivity for a variety of substitution patterns on the dienyl unit. Both ketone- and morpholine amide-derived dienol ethers afforded high enantio- and diastereoselectivity in the addition to conjugated aldehydes. Although alpha,beta-unsaturated ketone-derived dienolate did not react with aliphatic aldehydes, alpha,beta-unsaturated amide-derived dienolates underwent addition at reasonable rates affording high yields of vinylogous aldol product. The enantioselectivities achieved with the morpholine derived-dienolate in the addition to aliphatic aldehydes was the highest afforded to date with the silicon tetrachloride-chiral phosphoramide system. Furthermore, the ability to cleanly convert the morpholine amide to a methyl ketone was demonstrated.

  19. Catalytic, Conjugate Reduction-Aldol Addition Reaction of β'Oxoal kyl α, β-Unsatu rated Carboxylates%Catalytic, Conjugate Reduction-Aldol Addition Reaction of β'Oxoal kyl α, β-Unsatu rated Carboxylates

    Institute of Scientific and Technical Information of China (English)

    郑爱军; 姜岚; 李争宁

    2012-01-01

    Intramolecular conjugate reduction-aldol addition reactions of β'-oxoalkyl a,fl-unsaturated carboxylates were performed in the presence of copper catalysts generated in situ from copper salts, phosphine ligands and silanes. Moderate to good yields and high diastereoselectivities were obtained in 15 min to 3 h using bis[(2-diphenyl- phosphino)phenyl] ether as the ligand.

  20. Lewis Acid-Promoted Mukaiyama Aldol-Prins (MAP) Cyclizations of Acetals, Ketals, α-Acetoxy Ethers, and Orthoformates.

    Science.gov (United States)

    Gesinski, Michael R; Van Orden, Lori J; Rychnovsky, Scott D

    2008-02-12

    The Mukaiyama aldol-Prins (MAP) cyclization of acetals stereoselectively provided substituted tetrahydropyrans. The scope of the reaction has been expanded to include other electrophiles, including ketals and α-acetoxy ethers. Finally, a double MAP cyclization with orthoformates is described.

  1. Teratoma do ovario com estruturas semelhando cristalino

    Directory of Open Access Journals (Sweden)

    C. Magarinos Torres

    1940-01-01

    Full Text Available Em uma mulher, brasileira, de côr parda, com 48 anos de idade, morta com tuberculose do peritoneo, tuberculose peribronquica do lóbo superior do pulmão esquerdo e tuberculose cronica fibrosa do apice de ambos os pulmões, a necropsía revelou a existencia de um teratoma no ovario esquerdo. O ovario, pouco aumentado de volume, é constituído por duas porções de tamanho sensivelmente egual, de consistencia firme, separadas, em sua superficie, por profundo sulco. Ao córte, tem a aparencia de tecido fibroso em cuja espessura existem numerosos pequenos cistos. Ao microscopio, os cistos são revestidos por epitelio descontinuo, despertando grande interesse o seu conteúdo. Este é formado por fibras e células com morfologia semelhante ás do cristalino. Sugerimos a possibilidade de que, no presente teratoma (Teratoma lentifer, de lens, lentis: cristalino, e ferre: produzir haja participado, de modo dominante, o ectodérme, e mesmo uma região circumscrita do ectodérme, a qual corresponderia aquela emque se desenvolve, habitualmente, a placa do cristalino (« Linsenplatte ». A multiplicidade e a presença exclusiva de estruturas figurando saculos cristalinicos (« Linsensäckchen » são argumentos a favor de uma origem de ponto restrito do ectodérme, destinado a desenvolvimento posterior especifico, qual o da formação do cristalino.

  2. A new fatty aldol ester from the aerial part of Mimosa invisa (Mimosaceae).

    Science.gov (United States)

    Nana, Frederic; Sandjo, Louis Pergaud; Keumedjio, Felix; Kuete, Victor; Ngadjui, Bonaventure Tchaleu

    2012-01-01

    A new aldol ester named 17-O-triacontanoylheptadecanal (1) was isolated from the aerial part of Mimosa invisa (Mimosaceae) together with eight known compounds identified as β-sitosterol (2), α-amyrine (3), lupeol (4), 4'-O-methylepinumisoflavone (5), alpinumisoflavone (6), betulinic acid (7), 3-O-β-D-glucopyranoside of sitosterol (8) and epirobinetinidol (9). The structures of compounds were determined on the basis of NMR and mass spectrometry data as well as by comparing the data reported in the literatures. The antimicrobial activities of the crude extract and compounds 1 and 9 were investigated against seven microbial species. The natural products showed moderate activities compared to that of the crude extract.

  3. Estrutura social e criação de empresas

    Directory of Open Access Journals (Sweden)

    Gláucia Maria Vasconcelos Vale

    2015-12-01

    Full Text Available RESUMO Para a Sociologia Econômica, as estruturas sociais, no formato de redes interpessoais, influenciam as iniciativas individuais e os resultados econômicos daí derivados. Segundo Granovetter, existem três tipos básicos de estruturas: fortemente acopladas; fortemente desacopladas; fracamente acopladas. Este trabalho situa-se no contexto dessas reflexões, e procura-se, por meio de uma pesquisa amostral realizada com 100 empreendedores, localizados no município de Belo Horizonte, Minas Gerais, Brasil: identificar as estruturas sociais de origem desses indivíduos, em consonância com a tipologia genérica de Granovetter; avaliar a presença de associações entre essas estruturas e a trajetória dos empreendimentos, em particular, a motivação para empreender e o acesso ao mercado. Termina-se por elaborar uma tipologia de estruturas/redes sociais específicas para a análise do empreendedor, composta por três categorias: familiar, profissional e difusa.

  4. Condensation heat transfer

    Science.gov (United States)

    Rose, J. W.

    The paper gives a brief description of some of the better understood aspects of condensation heat transfer and includes discussion of the liquid-vapour interface, natural and forced convection laminar film condensation and dropwise condensation.

  5. N-Heterocyclic Carbene-Catalyzed Vinylogous Mukaiyama Aldol Reaction of α-Keto Esters and α-Trifluoromethyl Ketones

    KAUST Repository

    Du, Guang-Fen

    2015-11-05

    © Georg Thieme Verlag Stuttgart · New York · Synthesis 2016. N-Heterocyclic carbene (NHC)-catalyzed vinylogous Mukaiyama aldol reaction of ketones was developed. Under the catalysis of 5 mol% NHC, α-keto esters and α-trifluoromethyl ketones reacted with 2-(trimethysilyloxy)furan efficiently to produce γ-substituted butenolides containing adjacent quaternary and tertiary carbon centers in high yields with good diastereoselectivities.

  6. L-Prolinamide Catalyzed Aqueous Direct Aldol Reaction: an Environment-friendly Method for the Synthesis of β-Hydroxylketones

    Institute of Scientific and Technical Information of China (English)

    PENG, Yi-Yuang; LIU, Han; CUI, Ming; CHENG, Jin-Pei

    2007-01-01

    An environment-friendly L-prolinamide catalyzed aldol reaction has been developed. The reaction exhibited broad substrate generality, and high yields with good diastereoselectivity were obtained for cyclic ketones. The simplicity of product isolation, usage of water as environmentally benign reaction medium, and the usage of cheap,readily available and recyclable catalyst make this process promising to be developed for large-scale preparation of β-hydroxyl ketones.

  7. Stereoselective synthesis of 1,3-anti diols by an Ipc-mediated domino aldol-coupling/reduction sequence.

    Science.gov (United States)

    Dieckmann, Michael; Menche, Dirk

    2013-01-04

    A novel domino process for 1,3-anti diol synthesis by the union of a methyl ketone with an aldehyde is described. The operationally simple procedure is based on an Ipc-boron-aldol coupling and subsequent Ipc-mediated reduction of the intermediate β-hydroxy-ketone. The sequence proceeds with excellent anti-selectivities and enables the rapid construction of complex polyketide fragments.

  8. 1,6-asymmetric induction in boron-mediated aldol reactions: application to a practical total synthesis of (+)-discodermolide.

    Science.gov (United States)

    Paterson, Ian; Delgado, Oscar; Florence, Gordon J; Lyothier, Isabelle; Scott, Jeremy P; Sereinig, Natascha

    2003-01-01

    By relying solely on substrate-based stereocontrol, a practical total synthesis of the microtubule-stabilizing anticancer agent (+)-discodermolide has been realized. This exploits a novel aldol bond construction with 1,6-stereoinduction from the boron enolate of (Z)-enone 3 in addition to aldehyde 2. The 1,3-diol 7 is employed as a common building block for the C(1)-C(5), C(9)-C(16), and C(17)-C(24) subunits. [reaction--see text

  9. Accurate Reaction Enthalpies and Sources of Error in DFT Thermochemistry for Aldol, Mannich, and α-Aminoxylation Reactions

    Science.gov (United States)

    Wheeler, Steven E.; Moran, Antonio; Pieniazek, Susan N.; Houk, K. N.

    2009-08-01

    Enthalpies for bond-forming reactions that are subject to organocatalysis have been predicted using the high-accuracy CBS-QB3 model chemistry and six DFT functionals. Reaction enthalpies were decomposed into contributions from changes in bonding and other intramolecular effects via the hierarchy of homodesmotic reactions. The order of the reaction exothermicities (aldol < Mannich ≈ α-aminoxylation) arises primarily from changes in formal bond types mediated by contributions from secondary intramolecular interactions. In each of these reaction types, methyl substitution at the β- and γ-positions stabilizes the products relative to the unsubstituted case. The performance of six DFT functionals (B3LYP, B3PW91, B1B95, MPW1PW91, PBE1PBE, and M06-2X), MP2, and SCS-MP2 has been assessed for the prediction of these reaction enthalpies. Even though the PBE1PBE and M06-2X functionals perform well for the aldol and Mannich reactions, errors roughly double when these functionals are applied to the α-aminoxylation reactions. B3PW91 and B1B95, which offer modest accuracy for the aldol and Mannich reactions, yield reliable predictions for the two α-aminoxylation reactions. The excellent performance of the M06-2X and PBE1PBE functionals for aldol and Mannich reactions stems from the cancellation of sizable errors arising from inadequate descriptions of the underlying bond transformations and intramolecular interactions. SCS-MP2/cc-pVTZ performs most consistently across these three classes of reactions, although the reaction exothermicities are systematically underestimated by 1-3 kcal mol-1. Conventional MP2, when paired with the cc-pVTZ basis set, performs somewhat better than SCS-MP2 for some of these reactions, particularly the α-aminoxylations. Finally, the merits of benchmarking DFT functionals for the set of simple chemically meaningful transformations underlying all bond-forming reactions are discussed.

  10. Aldol Reactions of Axially Chiral 5-Methyl-2-(o-arylimino-3-(o-aryl-thiazolidine-4-ones

    Directory of Open Access Journals (Sweden)

    Sule Erol Gunal

    2016-06-01

    Full Text Available Axially chiral 5-methyl-2-(o-arylimino-3-(o-aryl-thiazolidine-4-ones have been subjected to aldol reactions with benzaldehyde to produce secondary carbinols which have been found to be separable by HPLC on a chiral stationary phase. Based on the reaction done on a single enantiomer resolved via a chromatographic separation from a racemic mixture of 5-methyl-2-(α-naphthylimino-3-(α-naphthyl-thiazolidine-4-one by HPLC on a chiral stationary phase, the aldol reaction was shown to proceed via an enolate intermediate. The axially chiral enolate of the thiazolidine-4-one was found to shield one face of the heterocyclic ring rendering face selectivity with respect to the enolate. The selectivities observed at C-5 of the ring varied from none to 11.5:1 depending on the size of the ortho substituent. Although the aldol reaction proceeded with a lack of face selectivity with respect to benzaldehyde, recrystallization returned highly diastereomerically enriched products.

  11. Estratigrafia e estrutura do Cerro do Jarau: nova proposta

    Directory of Open Access Journals (Sweden)

    Joana Paula Sánchez

    Full Text Available A estrutura do Cerro do Jarau está localizada no Estado do Rio Grande do Sul, nas proximidades de Quarai, divisa com o Uruguai. É uma estrutura circular de aproximadamente 8 km de diâmetro, cujos dados geológicos apontam para uma origem por impacto meteorítico. Está situada na Bacia do Paraná e compreende uma área de afloramento de arenitos na porção central, circundada por basaltos da Formação Serra Geral. Nos trabalhos publicados, o arenito da porção central é interpretado como pertencente à Formação Botucatu, soerguido em meio aos basaltos da Formação Serra Geral, correspondendo, para muitos autores, a uma feição dômica. O objetivo do presente trabalho é apresentar novos dados sobre a estratigrafia e estrutura do Cerro do Jarau, que mostram que os arenitos estão estrutural e estratigraficamente sobrepostos aos basaltos e ambas unidades exibem mergulhos centrípetos. A estrutura do Cerro do Jarau é, portanto, uma bacia com a porção central rebaixada, e não um domo como antes admitido.

  12. Esparsidade, Estrutura, Escalamento e Estabilidade em Algebra Linear Computacional

    CERN Document Server

    Stern, Julio M

    2011-01-01

    Sparsity, Structure, Scaling and Stability in Computational Linear Algebra - Textbook from the IX School of Computer Science, held on July 24-31 of 1994 at Recife, Brazil. Esparsidade, Estrutura, Escalamento e Estabilidade em Algebra Linear Computacional - Livro texto da IX Escola de Computacao, realizada nos dias 24 a 31 de Julho de 1994 em Recife, Brasil. This textbook is written in Portuguese Language.

  13. Expedient synthesis of C-aryl carbohydrates by consecutive biocatalytic benzoin and aldol reactions.

    Science.gov (United States)

    Hernández, Karel; Parella, Teodor; Joglar, Jesús; Bujons, Jordi; Pohl, Martina; Clapés, Pere

    2015-02-16

    The introduction of aromatic residues connected by a C-C bond into the non-reducing end of carbohydrates is highly significant for the development of innovative structures with improved binding affinity and selectivity (e.g., C-aril-sLex). In this work, an expedient asymmetric "de novo" synthetic route to new aryl carbohydrate derivatives based on two sequential stereoselectively biocatalytic carboligation reactions is presented. First, the benzoin reaction of aromatic aldehydes to dimethoxyacetaldehyde is conducted, catalyzed by benzaldehyde lyase from Pseudomonas fluorescens biovar I. Then, the α-hydroxyketones formed are reduced by using NaBH4 yielding the anti diol. After acetal hydrolysis, the aldol addition of dihydroxyacetone, hydroxyacetone, or glycolaldehyde catalyzed by the stereocomplementary D-fructose-6-phosphate aldolase and L-rhamnulose-1-phosphate aldolase is performed. Both aldolases accept unphosphorylated donor substrates, avoiding the need of handling the phosphate group that the dihydroxyacetone phosphate-dependent aldolases require. In this way, 6-C-aryl-L-sorbose, 6-C-aryl-L-fructose, 6-C-aryl-L-tagatose, and 5-C-aryl-L-xylose derivatives are prepared by using this methodology.

  14. Sorption of tylosin A, D, and A-aldol and degradation of tylosin A in soils.

    Science.gov (United States)

    Sassman, Stephen A; Sarmah, Ajit K; Lee, Linda S

    2007-08-01

    Heightened concerns regarding the potential impact on soil and water quality of veterinary antibiotics warrant a better understanding of the environmental fate of antibiotics in soil. Sorption of the macrolides tylosin A (TA), tylosin D, and TA-aldol was measured in several soils and evaluated with respect to soil pH, organic matter content, percentage clay, and cation-exchange capacity (CEC). Tylosin and related compounds exhibit similar sorption characteristics and generally are strongly sorbed, with sorption being well and positively correlated to surface area, clay content, and CEC. Sorption coefficients normalized by CEC were within a narrow range (10(4.1+/-0.21 L/molc) for all but one soil; however, good extraction recoveries with only methanol for most soils suggested that hydrophobic processes also contribute to sorption. Aerobic degradation of TA over a three-month period in two freshly collected agricultural soils and 60Co-irradiated soils indicated that both abiotic and microbial processes contribute to TA transformation. The abiotic process was much slower and dominated in the first two weeks, followed by rapid microbial degradation within 3 d. Three primary degradation products were identified using liquid chromatography with full-scan mass spectrometry, with unconfirmed identifications of TA having the aldehyde group oxidized to an acid (m/z = 932) in both soils and tyslosin B (m/z = 772) as well as tylosin B having the aldehyde group oxidized to an acid (m/z = 788) in the sandy soil.

  15. A estrutura silábica em esperanto

    Directory of Open Access Journals (Sweden)

    Karina Gonçalves de Souza de Oliveira

    2016-06-01

    Full Text Available Este artigo tem como objetivo comentar a bibliografia disponível sobre a estrutura das sílabas em esperanto, baseada em conceitos da teoria fonológica sobre as possíveis estruturações silábicas existentes nas mais variadas línguas. Primeiramente veremos o que pode-se dizer sobre a sílaba, sua estruturação e seus constituintes, para após verificar o que já foi escrito em esperanto e sobre o esperanto em relação ao assunto. Por fim, formulamos regras estruturais de acordo com a discussão feita ao longo do trabalho. Há poucos estudos relacionados a essa temática sobre o esperanto. Nossas principais fontes são artigos de Oostendorp (1999 e Bavant (2006, que fez uma compilação de vários livros que citam a noção de "sílaba" e tentam defini-la, além de ter analisado, por meio de um programa computacional, todas as palavras (mais de 47 mil que compõem o PIV – Plena Ilustrita Vortaro (Dicionário Completo ilustrado, para achar os constituintes possíveis da sílaba e suas frequências na língua.

  16. Direct asymmetric vinylogous aldol reaction of allyl ketones with isatins: Divergent synthesis of 3-hydroxy-2-oxindole derivatives

    KAUST Repository

    Zhu, Bo

    2013-05-03

    6 in 1: The highly enantioselective title reaction is mediated by a bifunctional catalyst and leads to E-configured vinylogous aldol products (see scheme). These products are used as common intermediates in the synthesis of six biologically active 3-hydroxy-2-oxindole derivatives (e.g., CPC-1). Computational studies indicated that the observed stereoselectivity is a result of favorable secondary π-π* and H-bonding interactions in the transition state. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. An Environmentally Benign System for Synthesis of β-Hydroxylketones: L-Histidine Asymmetrically Catalyzed Direct Aldol Reactions in Aqueous Micelle and Water-like Media

    Institute of Scientific and Technical Information of China (English)

    PENG Yi-Yuan; PENG Shu-Jun; DING Qiu-Ping; WANG Qi; CHENG Jin-Pei

    2007-01-01

    The first histidine catalyzed direct aldol reactions of ketones with nitrobenzaldehydes in water and in poly(ethylene glycol) (PEG) were reported. It reveals that histidine is a good aldol catalyst for synthesis of β-hydroxylketones in water and in PEG, giving good to excellent yields of the respective products. Better enantioand regioselectivity were achieved using low molecular weight PEG as the media. The results show that histidine and PEG-200 or -300 may constitute a promising environmentally benign system for asymmetric synthesis of β-hydroxylketones.

  18. Condensation in insulated homes

    Energy Technology Data Exchange (ETDEWEB)

    Wiley, R A

    1978-05-28

    A research proposal on condensation in insulated homes is presented. Information is provided on: justification for condensation control; previous work and present outlook (good vapor barrier, condensation and retrofit insulation, vapor barrier decreases condensation, brick-veneer walls, condensation in stress-skin panels, air-conditioned buildings, retrofitting for conservation, study on mobile homes, high indoor relative humidity, report on various homes); and procedure (after funding has been secured). Measures are briefly described on opening walls, testing measures, and retrofitting procedures. An extensive bibliography and additional informative citations are included. (MCW)

  19. Synthesis of Dendrimer-supported Chiral Bis(oxazoline) Ligands and Their Applications in Aldol Reaction via Aqueous Media

    Institute of Scientific and Technical Information of China (English)

    CHEN Xiao-min; YANG Bai-yuan; ZHANG Yi-li; QU Xue; FAN Qing-hua

    2004-01-01

    Chiral bis(oxazoline) ligands have been applied in many enatioselective reactions.Recently, studies of the immobilization of bis(oxazoline) on both soluble and insoluble supports have been of great interest. Among the different methods to anchor the homogeneous catadysts, a soluble, polymer-supported catalyst usually achieves higher stereoselectivity and activity because the catalysis can be separated and recycled via simple methods such as solvent precipitation.Dendrimers are highly branched macromolecules having precisely defined molecular structures with nano-scale size. Compared with soluble polymer supports, the dendrimer architecture may offer better control of the deposition of the catalytic species in soluble polymer-based catalysts. Therefore,such catalysts may fill the gap between homogeneous and heterogeneous catalysis and combine the advantages of both.In this paper, we report the synthesis of bis(oxazoline)-centered dendrimers and their application in Mukaiyama aldol reaction in aqueous media. It was found that the dendritic chiral bis(oxazolines)showed the similar reactivities and enantioselectivities in the asymmetric copper-catalyzed aldol reaction in aqueous media in comparison to the corresponding small molecular ligands.

  20. Liquid-Phase Aldol Condesation of Acetaldehyde and Its Kinetics%乙醛液相羟醛缩合反应工艺和动力学

    Institute of Scientific and Technical Information of China (English)

    伍艳辉; 任伟丽; 梁泽磊; 刘仲能; 吴高胜

    2013-01-01

    考察了KOH,NaOH,Na2CO3,NaOH和Na2CO3混合碱,三乙胺及阴离子交换树脂在乙醛缩合反应过程中的催化性能,以及反应体系的pH值和温度对反应的影响.结果表明,以Na2CO3为催化剂有利于维持反应体系pH稳定,当反应体系pH值为11~12,反应温度35℃时,反应转化率和选择性较高.在不同温度和pH值时进行动力学研究,得到pH值分别为10.4,11.0和11.4的动力学方程和相应的参数,其中pH值为11.4时,反应活化能最小.%The catalytic performance of different catalysts, KOH, NaOH, Na2CO3, mixed alkalis of NaOH and Na2CO3, triethylamine, and anionic exchange resin, in aldol condensation of acetaldehyde, were examined. The effects of solution pH level and reaction temperature on the reaction extent were investigated. The results indicate that a relatively constant pH level could be maintained with Na2CO3 as the catalyst. The reaction has a high conversion and a high selectivity at the reaction temperature of 35 ℃ and the pH range of 11-12. Kinetic studies were then carried out with Na2CO3 as the catalyst at different reaction temperatures and pH levels. The kinetic equations and the corresponding parameters were finally obtained for pH level of 10.4, 11.0, and 11.4, respectively. The activation energy at pH value of 11.4 is the lowest.

  1. Estrutura e discursividade do texto poético

    OpenAIRE

    Francisco de Assis Moura Sobreira

    2007-01-01

    Esta dissertação constitui uma investigação da estrutura e da discursividade do texto poético em suas virtualidades e está dividida em duas partes, distintas, mas não estanques. Na primeira parte, estudamos o texto poético considerando seus aspectos estruturais; na segunda, tratamos dos fatores que envolvem seus aspectos discursivos. Em relação aos os aspectos estruturais, consideramos o que formalmente torna o texto um objeto de arte literária. Aqui, em primeira mão, atentamos para os estudo...

  2. A estrutura retórica do verbete Spinoza

    Directory of Open Access Journals (Sweden)

    Marilena Chaui

    2009-12-01

    Full Text Available Propomos uma análise do verbete "Spinoza" do Dictionnaire Historique et Critique salientando a estrutura retórica do texto, em cujo centro se encontra a nova figura do ateu, construída por Bayle, o ateu especulativo ou "o ateu de sistema".The paper presents a study of the rhetorical framework of the article "Spinoza" in Bayle's Dictionnaire Historique et Critique and the new image of the atheist as athée de système.

  3. Determinantes da estrutura de capital das empresas listadas na Bovespa

    OpenAIRE

    Eduardo Glasenapp Moraes

    2005-01-01

    Os determinantes da estrutura de capital das empresas geram pesquisas e discussões no mundo acadêmico e profissional. Algumas teorias que concorrem para dar explicações são a teoria de custos de agência, teoria do trade-off, teoria de assimetria informacional e a teoria de interação entre as empresas no mercado de competição de produtos e com fornecedores. No mercado brasileiro, alguns trabalhos analisaram variáveis explicativas dos modelos de custos de agência, trade-off e assimetria informa...

  4. Condensation Energy of a Spacetime Condensate

    CERN Document Server

    de Matos, Clovis Jacinto

    2010-01-01

    Starting from an analogy between the Planck-Einstein scale and the dual length scales in Ginzburg-Landau theory of superconductivity, and assuming that space-time is a condensate of neutral fermionic particles with Planck mass, we derive the baryonic mass of the universe. In that theoretical framework baryonic matter appears to be associated with the condensation energy gained by spacetime in the transition from its normal (symetric) to its (less symetric) superconducting-like phase. It is shown however that the critical transition temperature cannot be the Planck temperature. Thus leaving open the enigma of the microscopic description of spacetime at quantum level.

  5. Estruturas elásticas e fadiga muscular

    Directory of Open Access Journals (Sweden)

    Gláucia Andreza Kronbauer

    2013-06-01

    Full Text Available A fadiga muscular pode ser definida pela incapacidade de manter certa tarefa ao longo do tempo; os mecanismos neuromusculares e metabólicos envolvidos na contração muscular estão diretamente associados a esse fenômeno. Este estudo bibliográfico busca descrever as alterações nos elementos contráteis e elásticos envolvidos na contração muscular e sua relação com o desempenho na locomoção. As estruturas contráteis são aquelas que desenvolvem força ativa com gasto de energia metabólica - mecanismo de pontes cruzadas; as elásticas são aquelas que oferecem resistência mecânica ao alongamento sem custo energético - força passiva - e conservam energia elástica para uma nova contração. Após a análise de ambas, é possível afirmar que a fadiga muscular está associada à função das estruturas contráteis e elásticas.

  6. INTERNACIONALIZAÇÃO DE EMPRESAS DE INFRA-ESTRUTURA

    Directory of Open Access Journals (Sweden)

    Frederico Araujo Turolla

    2009-01-01

    Full Text Available A decisão de internacionalização das firmas de infra-estrutura não é trivial. Ao contrário damaioria dos setores, o investimento requer grades volumes de capital, há significativos custosde transação e também envolve questões conjunturais e institucionais, específicas a cada paísde destino. Não obstante os elevados riscos, vários grupos econômicos da área de infraestruturatêm buscado novos mercados para investimento e têm ampliado a parcela dasreceitas que são obtidas fora dos mercados de origem. O estudo proposto neste artigo constituirefinamento da teoria estabelecida de Negócios Internacionais, com auxílio da Teoria deOrganização Industrial sobre a Economia da Infra-Estrutura. A metodologia é teóricoempírica,pois parte de duas teorias estabelecidas. As hipóteses testadas relacionam o Grau deInternacionalização (GI a um conjunto de determinantes da internacionalização. Asconclusões apontam que, à exceção da economia de densidade e da economia de escala, asquais não se mostraram relevantes para explicar a internacionalização de empresas, todas asdemais variáveis apontaram para o resultado esperado.

  7. Measure Guideline: Evaporative Condensers

    Energy Technology Data Exchange (ETDEWEB)

    German, A [Alliance for Residential Building Innovation (ARBI), Davis, CA (United States); Dakin, B. [Alliance for Residential Building Innovation (ARBI), Davis, CA (United States); Hoeschele, M. [Alliance for Residential Building Innovation (ARBI), Davis, CA (United States)

    2012-03-01

    This measure guideline on evaporative condensers provides information on properly designing, installing, and maintaining evaporative condenser systems as well as understanding the benefits, costs, and tradeoffs. This is a prescriptive approach that outlines selection criteria, design and installation procedures, and operation and maintenance best practices.

  8. Systematic text condensation

    DEFF Research Database (Denmark)

    Malterud, Kirsti

    2012-01-01

    To present background, principles, and procedures for a strategy for qualitative analysis called systematic text condensation and discuss this approach compared with related strategies.......To present background, principles, and procedures for a strategy for qualitative analysis called systematic text condensation and discuss this approach compared with related strategies....

  9. An Environmentally-Friendly and Catalytic Procedure for Mukaiyama Aldol Reaction Using Organic Catalyst DBU under Solvent Free Conditions

    Institute of Scientific and Technical Information of China (English)

    SHEN,Zhi-Liang; JI,Shun-Jun; LOH,Teck Peng

    2004-01-01

    @@ Recently, methods based exclusively on organic catalysts have become of major significance in synthetic chemistry.Mukaiyama-aldol reaction, as one of the most important and frequently utilized methods for C-C bond formation, is well documented in literatures recently. A variety of reagents, particularly metal-containing Lewis acids or bases, are known to promote the nucleophilic process. However, many of the reported strategies might have the following limitations from environmental viewpoints: (1) the use of metal-containing catalyst. Some of the catalysts are air or moisture sensitive (such as lithium amide), and crucial reaction conditions are needed; Some of the catalysts derived from poisonous metal (for example: SnCl4, SmI2 etc.) may cause harmful influence on humane body and environment; (2) the use of organic solvent (such as DMF, CH2Cl2 etc.) may bring about environmental pollution and solvent waste.

  10. Busca de estruturas em grandes escalas em altos redshifts

    Science.gov (United States)

    Boris, N. V.; Sodrã©, L., Jr.; Cypriano, E.

    2003-08-01

    A busca por estruturas em grandes escalas (aglomerados de galáxias, por exemplo) é um ativo tópico de pesquisas hoje em dia, pois a detecção de um único aglomerado em altos redshifts pode por vínculos fortes sobre os modelos cosmológicos. Neste projeto estamos fazendo uma busca de estruturas distantes em campos contendo pares de quasares próximos entre si em z Â3 0.9. Os pares de quasares foram extraídos do catálogo de Véron-Cetty & Véron (2001) e estão sendo observados com os telescópios: 2,2m da University of Hawaii (UH), 2,5m do Observatório de Las Campanas e com o GEMINI. Apresentamos aqui a análise preliminar de um par de quasares observado nos filtros i'(7800 Å) e z'(9500 Å) com o GEMINI. A cor (i'-z') mostrou-se útil para detectar objetos "early-type" em redshifts menores que 1.1. No estudo do par 131046+0006/J131055+0008, com redshift ~ 0.9, o uso deste método possibilitou a detecção de sete objetos candidatos a galáxias "early-type". Num mapa da distribuição projetada dos objetos para 22 < i' < 25 observou-se que estas galáxias estão localizadas próximas a um dos quasares e há indícios de que estejam aglomeradas dentro de um área de ~ 6 arcmin2. Se esse for o caso, estes objetos seriam membros de uma estrutura em grande escala. Um outro argumento em favor dessa hipótese é que eles obedecem uma relação do tipo Kormendy (raio equivalente X brilho superficial dentro desse raio), como a apresentada pelas galáxias elípticas em z = 0.

  11. Sedimentary condensation and authigenesis

    Science.gov (United States)

    Föllmi, Karl

    2016-04-01

    Most marine authigenic minerals form in sediments, which are subjected to condensation. Condensation processes lead to the formation of well individualized, extremely thin ( 100ky), and which experienced authigenesis and the precipitation of glaucony, verdine, phosphate, iron and manganese oxyhydroxides, iron sulfide, carbonate and/or silica. They usually show complex internal stratigraphies, which result from an interplay of sediment accumulation, halts in sedimentation, sediment winnowing, erosion, reworking and bypass. They may include amalgamated faunas of different origin and age. Hardgrounds may be part of condensed beds and may embody strongly condensed beds by themselves. Sedimentary condensation is the result of a hydrodynamically active depositional regime, in which sediment accumulation, winnowing, erosion, reworking and bypass are processes, which alternate as a function of changes in the location and intensity of currents, and/or as the result of episodic high-energy events engendered by storms and gravity flow. Sedimentary condensation has been and still is a widespread phenomenon in past and present-day oceans. The present-day distribution of glaucony and verdine-rich sediments on shelves and upper slopes, phosphate-rich sediments and phosphorite on outer shelves and upper slopes, ferromanganese crusts on slopes, seamounts and submarine plateaus, and ferromanganese nodules on abyssal seafloors is a good indication of the importance of condensation processes today. In the past, we may add the occurrence of oolitic ironstone, carbonate hardgrounds, and eventually also silica layers in banded iron formations as indicators of the importance of condensation processes. Besides their economic value, condensed sediments are useful both as a carrier of geochemical proxies of paleoceanographic and paleoenvironmental change, as well as the product of episodes of paleoceanographic and paleoenvironmental change themselves.

  12. A estrutura do sentido: Goldstein e Merleau-Ponty

    Directory of Open Access Journals (Sweden)

    Claudinei Aparecido de Freitas da Silva

    2012-12-01

    Full Text Available Ao reatar o elo mais profundo entre a psicologia e a filosofia, Merleau-Ponty revisita a obra clínica de Kurt Goldstein (1878-1965, reavivando, em especial, seu contributo fenomenológico. As noções de "estrutura" (Gestalt e "sentido" são, aqui, agenciadas quanto a uma compreensão mais integral do comportamento, da vida e da linguagem; alcance que Goldstein obtém, ao estudar os diferentes distúrbios linguísticos, na contramão das teorias intelectualistas e empiristas, essencialmente causais. Ao retomar esse inventário crítico, Merleau-Ponty atenta para o caráter original, dinâmico e, sobretudo, ontológico dessa proposta.

  13. Estrutura de mercado e tendências da atividade comercial

    Directory of Open Access Journals (Sweden)

    Jefferson Mariano

    2007-11-01

    Full Text Available O presente artigo busca realizar uma caracterização do setor comercial, com ênfase na RMSP, destacando o processo de concentração, evidenciado principalmente no segmento de hiper e supermercados. Na primeira seção, busca-se ilustrar o processo de concentração em alguns segmentos do comércio varejista, à luz das teorias de estrutura de mercado. Na segunda, apresenta se um painel com o perfil dessa atividade econômica, com informações agregadas para Brasil, Estado de São Paulo e Região Metropolitana de São Paulo. Na terceira, são apontadas as tendências e perspectivas do setor.

  14. Physics of condensed matter

    CERN Document Server

    Misra, Prasanta K

    2012-01-01

    Physics of Condensed Matter is designed for a two-semester graduate course on condensed matter physics for students in physics and materials science. While the book offers fundamental ideas and topic areas of condensed matter physics, it also includes many recent topics of interest on which graduate students may choose to do further research. The text can also be used as a one-semester course for advanced undergraduate majors in physics, materials science, solid state chemistry, and electrical engineering, because it offers a breadth of topics applicable to these majors. The book be

  15. Estrutura populacional da raça Nelore Mocho

    Directory of Open Access Journals (Sweden)

    Faria F.J.C.

    2002-01-01

    Full Text Available Descreveu-se a estrutura populacional da raça Nelore Mocho utilizando dados do registro genealógico de animais nascidos entre 1969 e 1998. O banco de dados foi separado em quatro períodos de 1979-1983, 1984-1988, 1989-1993 e 1994-1998. Calcularam-se as estatísticas descritivas do número de criadores, de reprodutores e de reprodutrizes. A endogamia total aumentou de 0,55% para 0,98%, a esperada sob acasalamento ao acaso aumentou de 0,11% para 0,56% e a endogamia devido à subdivisão populacional permaneceu constante, ao redor de 0,45%, indicando que a subdivisão genética da raça Nelore Mocho é próxima a zero e praticamente inexistente. O tamanho efetivo populacional foi estimado pelo coeficiente total de endogamia e permaneceu ao redor de 120. A inclusão de animais no livro genealógico aumentou de 4.630 para 13.907, entretanto, esta ação não foi suficiente para incrementar o tamanho efetivo. Baseado na probabilidade de origem do gene foram calculados o número efetivo de fundadores, de ancestrais e de genomas remanescentes. Esses parâmetros decresceram ao longo do período, atingindo valores de 144, 98 e 64. Todas as estimativas foram análogas na descrição da estrutura genética populacional e devem ser consideradas no futuro para o desenvolvimento de programas de seleção.

  16. Measure Guideline: Evaporative Condensers

    Energy Technology Data Exchange (ETDEWEB)

    German, A.; Dakin, B.; Hoeschele, M.

    2012-03-01

    The purpose of this measure guideline on evaporative condensers is to provide information on a cost-effective solution for energy and demand savings in homes with cooling loads. This is a prescriptive approach that outlines selection criteria, design and installation procedures, and operation and maintenance best practices. This document has been prepared to provide a process for properly designing, installing, and maintaining evaporative condenser systems as well as understanding the benefits, costs, and tradeoffs.

  17. Discovery-Oriented Approach To Organic Synthesis: Tandem Aldol Condensation-Michael Addition Reactions. Identifying Diastereotopic Hydrogens in an Achiral Molecule by NMR Spectroscopy

    Science.gov (United States)

    Wachter-Jurcsak, Nanette; Reddin, Kendra

    2001-09-01

    We have found a beautiful example of anisochrony of diastereotopic acyclic methylene hydrogens in a symmetric diketone, synthesized by techniques traditionally performed in an introductory organic laboratory course. Synthesis of the diketone is high-yielding and easy to carry out, and the products can be directly isolated with a good degree of purity with no need of further manipulation. The reaction can be accomplished in a single laboratory session.

  18. Illustrating the Utility of X-Ray Crystallography for Structure Elucidation through a Tandem Aldol Condensation/Diels-Alder Reaction Sequence

    Science.gov (United States)

    Hoang, Giang T.; Kubo, Tomohiro; Young, Victor G., Jr.; Kautzky, Jacob A.; Wissinger, Jane E.

    2015-01-01

    Two introductory organic chemistry laboratory experiments are described based on the Diels-Alder reaction of 2,3,4,5-tetraphenylcyclopentadienone, which is synthesized prior to or in a one-pot reaction, with styrene. Students are presented with three possible products, the "endo" and "exo" diastereomers and the decarbonylated…

  19. 丙二酸发生羟醛缩合时的二次脱羧反应%The second decarboxylation of malonic acid in aldol condensation

    Institute of Scientific and Technical Information of China (English)

    彭啸; 吴松福; 毛宇; 戴晓畅

    2004-01-01

    丙二酸与对羟基苯甲醛及对羟基间甲氧基苯甲醛反应会发生第二步脱羧,生成对羟基苯乙烯及对羟基间甲氧基苯乙烯,是一种形成对羟基苯乙烯的新方法.而间羟基及其它烷氧基取代苯甲醛则不能发生此反应,讨论了对羟基苯甲醛与丙二酸发生脱羧反应的电子效应.

  20. Enantioselective organocatalyzed Oxa-Michael-Aldol cascade reactions: Construction of chiral 4H-chromenes with a trifluoromethylated tetrasubstituted carbon stereocenter

    KAUST Repository

    Zhang, Jing

    2015-03-13

    The first organocatalytic asymmetric synthesis of 4H-chromenes bearing a trifluoromethylated tetrasubstituted carbon center is presented. Chiral secondary amines promote the oxa-Michael-aldol cascade reaction between alkynals and 2-trifluoroacetylphenols via iminium-allenamine activation to produce pharmaceutically important heterocycles with excellent enantioselectivities. The proposed reaction can be scaled-up easily with maintenance of the excellent enantioselectivity. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Regulated-stereoselective construction of thirteen stereogenic centers necessary for the frame of (+)-discodermolide, based on iterative Lewis acid-promoted aldol reactions.

    Science.gov (United States)

    Kiyooka, Syun-ichi; Shahid, Kazi Abdus; Goto, Fumitaka; Okazaki, Momotoshi; Shuto, Yoshihiro

    2003-10-17

    The segments C(1)-C(13) and C(15)-C(21) containing the 13 stereogenic centers required for the frame of (+)-discodermolide were synthesized in good to excellent enantio- and diastereoselectivities from a common racemic aldehyde, derived from 2-methyl-1,3-propanediol. The enantioselective aldol reactions of the racemic aldehyde with a silylketene acetal, derived from ethyl 2-bromopropionate, in the presence of chiral oxazaborolidinones, prepared in situ with N-p-toluenesulfonyl-(R)- and -(S)-valine and BH(3).THF, proceeded under kinetic control to give the stereotriads with a high degree of enantioselectivity. Enantioselective (chiral borane) and diastereoselective (BF(3).OEt(2) and TiCl(4)) aldol reactions with the silylketene acetal, coupled with diastereoselective radical debrominations (Bu(3)SnH, Et(3)B, with or without MgBr(2)), were used iteratively. This aldol reaction strategy for the construction of the polypropionate frame dramatically shortened the steps needed for the construction of the final segments.

  2. Determinantes da folga organizacional em uma empresa com estrutura descentralizada.

    Directory of Open Access Journals (Sweden)

    Ilse Maria Beuren

    2015-08-01

    Full Text Available O objetivo do estudo é identificar os determinantes da folga organizacional em uma empresa com estrutura descentralizada, com ênfase no modo como os controllers das unidades de negócios afetam a folga. Foi realizada uma pesquisa descritiva com abordagem quantitativa, por meio de survey, utilizando o instrumento de pesquisa concebido por Indjejikian e Matëjka (2006, que se constitui de dois questionários, um para o gestor e outro para o controller de cada UN. A empresa objeto de estudo apresenta estrutura descentralizada com 45 UNs, das quais 32 responderam aos questionários. Os resultados da pesquisa indicam que as metas de desempenho, quando o crescimento das UNs é provocado pelo aumento das vendas e do market share, com sacrifício do retorno sobre o investimento no curto e médio prazos, são mais fáceis de alcançar e permitem maior folga organizacional do que em situações de UNs mais estáveis. Também indicam que a folga organizacional é maior em ambientes caracterizados por maior assimetria de informação entre a holding e os gestores das UNs, definidos pelo foco do controller da UN. Os resultados dos testes da relação entre as variáveis foco do controller da UN e folga organizacional evidenciam que os controllers das UNs priorizam o apoio à tomada de decisão na UN, em detrimento de suas responsabilidades com o sistema de controle gerencial corporativo. Quanto maior o tempo de atuação do controller na UN, maior é a sua dedicação às responsabilidades relacionadas à gestão da UN em detrimento do foco nas tarefas da holding. Conclui-se que a relação constatada nesta pesquisa entre o nível de folga organizacional e o foco dos controllers das UNs se coaduna com aquela enunciada no estudo de referência. De maneira geral, os resultados das análises estão alinhados com os da pesquisa de Indjejikian e Matëjka (2006, consideradas as limitações de comparabilidade em função das diferenças amostrais.

  3. Estrutura populacional do rebanho Tabapuã registrado no Brasil

    Directory of Open Access Journals (Sweden)

    Vercesi Filho A.E.

    2002-01-01

    Full Text Available Descreveu-se a estrutura da população do rebanho Tabapuã registrado no Brasil. Foram geradas estatísticas descritivas da distribuição do número de progênies e estimados o intervalo de gerações, estatísticas de F, número efetivo de fundadores, de ancestrais e de genomas remanescentes, além do tamanho efetivo da população, usando o registro genealógico de animais nascidos entre 1971-1998. Entre 1994 e 1998 foram registrados 37.778 animais, 18.736 machos e 19.042 fêmeas, pertencentes a 136 criadores. As médias dos intervalos de gerações estimadas para os períodos de 1979-1983, 1984-1988, 1989-1993 e 1994-1998 foram, respectivamente, 6,26; 7,18; 7,68 e 7,56 anos para pais-filhos e 6,18; 6,43; 6,99 e 7,27 para pais-pais. O tamanho efetivo da população e o número efetivo de fundadores, de ancestrais e de genomas remanescentes em cada um dos períodos foram, respectivamente, 378, 218, 213 e 181; 131, 254, 202 e 163; 73, 150, 119 e 94 e 55, 112, 78 e 61.

  4. Atitude do Consumidor: Estrutura dos Modelos Teóricos

    Directory of Open Access Journals (Sweden)

    Rafael Barreiros Porto

    2010-10-01

    Full Text Available Este trabalho visa oferecer uma organização de teorias de atitude originada por meio de levantamento bibliográfico da literatura de psicologia do consumidor. O pesquisador de marketing poderá ver algumas limitações e utilidades da medição do constructo - atitude - muitas vezes concebido através de pesquisas acadêmicas com o fim de compreender o processo de compra ou escolha. Pretendeu-se prover explicações sobre as estruturas formadoras de atitudes em modelos teóricos, ofertando uma classificação de ênfase de investigação empírica dos componentes da atitude. Este ensaio propõe uma agenda de pesquisa na área para que novas estratégias de investigação possam ser elaboradas em marketing.DOI: 10.5585/remark.v9i2.2145

  5. Raízes e estruturas da sociedade brasileira

    Directory of Open Access Journals (Sweden)

    Leonor Natividade de Campos Medeiros

    2014-05-01

    Full Text Available Este estudo teve como objetivo conhecer e refletir as raízes e estruturas da sociedade brasileira, na visão de dois grandes pensadores: Sérgio Buarque de Holanda com Raízes do Brasil e Gilberto Freyre com Casa-Grande & Senzala. Holanda dividiu o Brasil em duas fases a primeira da colonização portuguesa e a segunda uma critica ao Estado Novo. Freyre mostra a organização social, política e econômica da época da colonização e desenvolve seus estudos ao final da década de 1920, época em que o ambiente intelectual brasileiro está sob a força do modernismo. Conclui-se que o pensamento de Holanda e Freyre se assemelha em alguns aspectos e diverge em outros.   Sociologia de Freyre; Sociologia de Holanda; Raízes da sociedade brasileira

  6. CONDENSATION OF WATER VAPOR IN A VERTICAL TUBE CONDENSER

    Directory of Open Access Journals (Sweden)

    Jan Havlík

    2015-10-01

    Full Text Available This paper presents an analysis of heat transfer in the process of condensation of water vapor in a vertical shell-and-tube condenser. We analyze the use of the Nusselt model for calculating the condensation heat transfer coefficient (HTC inside a vertical tube and the Kern, Bell-Delaware and Stream-flow analysis methods for calculating the shell-side HTC from tubes to cooling water. These methods are experimentally verified for a specific condenser of waste process vapor containing air. The operating conditions of the condenser may be different from the assumptions adopted in the basic Nusselt theory. Modifications to the Nusselt condensation model are theoretically analyzed.

  7. Condensed matter physics

    CERN Document Server

    Isihara, A

    2007-01-01

    More than a graduate text and advanced research guide on condensed matter physics, this volume is useful to plasma physicists and polymer chemists, and their students. It emphasizes applications of statistical mechanics to a variety of systems in condensed matter physics rather than theoretical derivations of the principles of statistical mechanics and techniques. Isihara addresses a dozen different subjects in separate chapters, each designed to be directly accessible and used independently of previous chapters. Topics include simple liquids, electron systems and correlations, two-dimensional

  8. Preventing freezing of condensate inside tubes of air cooled condenser

    Energy Technology Data Exchange (ETDEWEB)

    Joo, Jeong A; Hwang, In Hwan; Lee, Dong Hwan [Chonbuk Nat' l Univ., Jeonju (Korea, Republic of); Cho, Young Il [Drexel Univ., Philadelphia (United States)

    2012-08-15

    An air cooled condenser is a device that is used for converting steam into condensate by using ambient air. The air cooled condenser is prone to suffer from a serious explosion when the condensate inside the tubes of a heat exchanger is frozen; in particular, tubes can break during winter. This is primarily due to the structural problem of the tube outlet of an existing conventional air cooled condenser system, which causes the backflow of residual steam and noncondensable gases. To solve the backflow problem in such condensers, such a system was simulated and a new system was designed and evaluated in this study. The experimental results using the simulated condenser showed the occurrence of freezing because of the backflow inside the tube. On the other hand, no backflow and freezing occurred in the advanced new condenser, and efficient heat exchange occurred.

  9. Soft condensed matter

    NARCIS (Netherlands)

    Frenkel, D.

    2002-01-01

    These lectures illustrate some of the concepts of soft-condensed matter physics, taking examples from colloid physics. Many of the theoretical concepts will be illustrated with the results of computer simulations. After a brief introduction describing interactions between colloids, the paper focuses

  10. Condensed Matter Physics

    Science.gov (United States)

    Marder, Michael P.

    2000-01-01

    A modern, unified treatment of condensed matter physics This new work presents for the first time in decades a sweeping review of the whole field of condensed matter physics. It consolidates new and classic topics from disparate sources, teaching "not only about the effective masses of electrons in semiconductor crystals and band theory, but also about quasicrystals, dynamics of phase separation, why rubber is more floppy than steel, electron interference in nanometer-sized channels, and the quantum Hall effect." Six major areas are covered---atomic structure, electronic structure, mechanical properties, electron transport, optical properties, and magnetism. But rather than defining the field in terms of particular materials, the author focuses on the way condensed matter physicists approach physical problems, combining phenomenology and microscopic arguments with information from experiments. For graduate students and professionals, researchers and engineers, applied mathematicians and materials scientists, Condensed Matter Physics provides: * An exciting collection of new topics from the past two decades. * A thorough treatment of classic topics, including band theory, transport theory, and semiconductor physics. * Over 300 figures, incorporating many images from experiments. * Frequent comparison of theory and experiment, both when they agree and when problems are still unsolved. * More than 50 tables of data and a detailed index. * Ample end-of-chapter problems, including computational exercises. * Over 1000 references, both recent and historically significant.

  11. Rins de Baleia Minke (Baleanoptera acutorostrata: arquitetura e estrutura

    Directory of Open Access Journals (Sweden)

    Carlos A.P. Sarmento

    2012-08-01

    Full Text Available Entre os mamíferos marinhos, a baleia é um dos animais que mais desperta atenção, especialmente no atinente ao seu sistema urinário. Este sistema segue o padrão entre os mamíferos quanto a sua constituição, entretanto, difere na morfologia renal, em número de lobos, que por sua vez, forma renículos completos, aglutinados às centenas. Esta estrutura é sustentada por tecido conjuntivo fibroso, mas altamente capaz de manter o equilíbrio hidroeletrolítico. Foram dissecados 6 pares de rins de baleia Minke (Balaenoptera acutorostrata, colhidos em 1982, Cabedelo, Estado da Paraíba, Brasil, na última pesca autorizada. Estes rins estavam conservados em formol 10% e apresentaram uma camada histológica de colágeno muito grande circundando a parede medular. O duto coletor urinário forma cálices papilares, desembocando num único centro coletor que desemboca no ureter. Verificou-se que o rim da baleia Minke apresenta característica lobulada possuindo em média 700 renículos, cada renículo possui características anatômicas e funcionais de um rim unipiramidal, com uma camada interna (medula, e uma camada externa (córtex, e irrigação independente, com formação das artérias arqueadas individualmente, como observadas em mamíferos terrestres unipiramidais. Entretanto, o conjunto destes renículos constitui ao final um rim multilobular e polipiramidal, contrariando a morfologia da maioria dos mamíferos terrestres. Não foi possível distinguir ao nível de microscopia de luz as estruturas do córtex renicular da baleia Minke. Na microscopia eletrônica de varredura foi possível visualizar uma camada cortical que fica localizada entre duas cápsulas fibrosas. Esta junção por sua vez é feita por tecido conjuntivo o qual juntamente com uma camada de colágeno e fibras elásticas, separa o córtex da medula , foram visualizados os glomérulos renais, completamente tomados pelos vasos glomerulares e dispostos em várias camadas

  12. Domains of Disoriented Chiral Condensate

    CERN Document Server

    Amado, R D; Lu, Yang

    1996-01-01

    The probability distribution of neutral pion fraction from independent domains of disoriented chiral condensate is characterized. The signal for the condensate is clear for a small number of domains but is greatly reduced for more than three.

  13. Highly selective condensation of biomass-derived methyl ketones as a source of aviation fuel.

    Science.gov (United States)

    Sacia, Eric R; Balakrishnan, Madhesan; Deaner, Matthew H; Goulas, Konstantinos A; Toste, F Dean; Bell, Alexis T

    2015-05-22

    Aviation fuel (i.e., jet fuel) requires a mixture of C9 -C16 hydrocarbons having both a high energy density and a low freezing point. While jet fuel is currently produced from petroleum, increasing concern with the release of CO2 into the atmosphere from the combustion of petroleum-based fuels has led to policy changes mandating the inclusion of biomass-based fuels into the fuel pool. Here we report a novel way to produce a mixture of branched cyclohexane derivatives in very high yield (>94 %) that match or exceed many required properties of jet fuel. As starting materials, we use a mixture of n-alkyl methyl ketones and their derivatives obtained from biomass. These synthons are condensed into trimers via base-catalyzed aldol condensation and Michael addition. Hydrodeoxygenation of these products yields mixtures of C12 -C21 branched, cyclic alkanes. Using models for predicting the carbon number distribution obtained from a mixture of n-alkyl methyl ketones and for predicting the boiling point distribution of the final mixture of cyclic alkanes, we show that it is possible to define the mixture of synthons that will closely reproduce the distillation curve of traditional jet fuel.

  14. Photon condensation: A new paradigm for Bose-Einstein condensation

    Science.gov (United States)

    Rajan, Renju; Ramesh Babu, P.; Senthilnathan, K.

    2016-10-01

    Bose-Einstein condensation is a state of matter known to be responsible for peculiar properties exhibited by superfluid Helium-4 and superconductors. Bose-Einstein condensate (BEC) in its pure form is realizable with alkali atoms under ultra-cold temperatures. In this paper, we review the experimental scheme that demonstrates the atomic Bose-Einstein condensate. We also elaborate on the theoretical framework for atomic Bose-Einstein condensation, which includes statistical mechanics and the Gross-Pitaevskii equation. As an extension, we discuss Bose-Einstein condensation of photons realized in a fluorescent dye filled optical microcavity. We analyze this phenomenon based on the generalized Planck's law in statistical mechanics. Further, a comparison is made between photon condensate and laser. We describe how photon condensate may be a possible alternative for lasers since it does not require an energy consuming population inversion process.

  15. Condensed matter physics

    CERN Document Server

    Marder, Michael P

    2010-01-01

    This Second Edition presents an updated review of the whole field of condensed matter physics. It consolidates new and classic topics from disparate sources, teaching not only about the effective masses of electrons in semiconductor crystals and band theory, but also about quasicrystals, dynamics of phase separation, why rubber is more floppy than steel, granular materials, quantum dots, Berry phases, the quantum Hall effect, and Luttinger liquids.

  16. Asymmetric condensed dark matter

    CERN Document Server

    Aguirre, Anthony

    2015-01-01

    We explore the viability of a boson dark matter candidate with an asymmetry between the number densities of particles and antiparticles. A simple thermal field theory analysis confirms that, under certain general conditions, this component would develop a Bose-Einstein condensate in the early universe that, for appropriate model parameters, could survive the ensuing cosmological evolution until now. The condensation of a dark matter component in equilibrium with the thermal plasma is a relativistic process, hence the amount of matter dictated by the charge asymmetry is complemented by a hot relic density frozen out at the time of decoupling. Contrary to the case of ordinary WIMPs, dark matter particles in a condensate can be very light, $10^{-22}\\,{\\rm eV} \\lesssim m \\lesssim 10^2\\,{\\rm eV}$; the lower limit arises from constraints on small-scale structure formation, while the upper bound ensures that the density from thermal relics is not too large. Big-Bang nucleosynthesis constrains the temperature of deco...

  17. Asymmetric condensed dark matter

    Science.gov (United States)

    Aguirre, Anthony; Diez-Tejedor, Alberto

    2016-04-01

    We explore the viability of a boson dark matter candidate with an asymmetry between the number densities of particles and antiparticles. A simple thermal field theory analysis confirms that, under certain general conditions, this component would develop a Bose-Einstein condensate in the early universe that, for appropriate model parameters, could survive the ensuing cosmological evolution until now. The condensation of a dark matter component in equilibrium with the thermal plasma is a relativistic process, hence the amount of matter dictated by the charge asymmetry is complemented by a hot relic density frozen out at the time of decoupling. Contrary to the case of ordinary WIMPs, dark matter particles in a condensate must be lighter than a few tens of eV so that the density from thermal relics is not too large. Big-Bang nucleosynthesis constrains the temperature of decoupling to the scale of the QCD phase transition or above. This requires large dark matter-to-photon ratios and very weak interactions with standard model particles.

  18. Chaos of chiral condensate

    CERN Document Server

    Hashimoto, Koji; Yoshida, Kentaroh

    2016-01-01

    Assigning a chaos index for vacua of generic quantum field theories is a challenging problem. We find chaotic behavior of chiral condensates of a quantum gauge theory at strong coupling limit, by using the AdS/CFT correspondence. We evaluate the time evolution of homogeneous quark condensates and in an N=2 supersymmetric QCD with the SU(N_c) gauge group at large N_c and at large 't Hooft coupling lambda. At an equivalent classical gravity picture, a Lyapunov exponent is readily defined. We show that the condensates exhibit chaotic behavior for energy density E > (6x10^2) (N_c/lambda^2) (m_q)^4 where m_q is the quark mass. The energy region of the chaotic vacua of the N=2 supersymmetric QCD increases for smaller N_c or larger lambda. The Lyapunov exponent is calculated as a function of the theory (N_c,lambda,E), showing that the N=2 supersymmetric QCD is more chaotic for smaller N_c.

  19. Highly efficient aldol additions of DHA and DHAP to N-Cbz-amino aldehydes catalyzed by L-rhamnulose-1-phosphate and L-fuculose-1-phosphate aldolases in aqueous borate buffer.

    Science.gov (United States)

    Garrabou, Xavier; Calveras, Jordi; Joglar, Jesús; Parella, Teodor; Bujons, Jordi; Clapés, Pere

    2011-12-21

    Aldol addition reactions of dihydroxyacetone (DHA) to N-Cbz-amino aldehydes catalyzed by L-rhamnulose-1-phosphate aldolase (RhuA) in the presence of borate buffer are reported. High yields of aldol adduct (e.g. 70-90%) were achieved with excellent (>98 : 2 syn/anti) stereoselectivity for most S or R configured acceptors, which compares favorably to the reactions performed with DHAP. The stereochemical outcome was different and depended on the N-Cbz-amino aldehyde enantiomer: the S acceptors gave the syn (3R,4S) aldol adduct whereas the R ones gave the anti (3R,4R) diastereomer. Moreover, the tactical use of Cbz protecting group allows simple and efficient elimination of borate and excess of DHA by reverse phase column chromatography or even by simple extraction. This, in addition to the use of unphosphorylated donor nucleophile, makes a useful and expedient methodology for the synthesis of structurally diverse iminocyclitols. The performance of aldol additions of dihydroxyacetone phosphate (DHAP) to N-Cbz-amino aldehydes using RhuA and L-fuculose-1-phosphate aldolase (FucA) catalyst in borate buffer was also evaluated. For FucA catalysts, including FucA F131A, the initial velocity of the aldol addition reactions using DHAP were between 2 and 10 times faster and the yields between 1.5 and 4 times higher than those in triethanolamine buffer. In this case, the retroaldol velocities measured for some aldol adducts were lower than those without borate buffer indicating some trapping effect that could explain the improvement of yields.

  20. Variáveis urbanas na estruturação de assembleia de aves

    OpenAIRE

    Anne Gomes Sacco

    2012-01-01

    A organização espacial de uma cidade e a maneira como a infra-estrutura para atender as necessidades da população humana está disposta, impõe diferentes efeitos na estruturação de assembleias. Este estudo avaliou como as características de um ambiente urbano e as diferentes intensidades de urbanização atuam na estruturação da avifauna. Verificando as respostas relacionadas às métricas tradicionais como riqueza, abundância e composição taxonômica; além dos os efeitos da urbanização sobre a div...

  1. A estrutura temática em A HORA DA ESTRELA

    Directory of Open Access Journals (Sweden)

    Roberta Rego Rodrigues

    2012-06-01

    Full Text Available Este artigo apresenta um estudo da estrutura temática em A hora da estrela de Clarice Lispector. A estrutura temática é abordada aqui enquanto recurso coesivo estrutural (HALLIDAY, 1994. Quanto à metodologia, o corpus foi digitalizado e revisado. Após esta etapa, houve a anotação manual do mesmo e posterior extração de dados no WordSmith Tools. Resultados apontam  um alto índice de Temas ideacionais elípticos, o que possivelmente pode ser correlacionado com o estilo clariceano de escrita. Pode-se concluir que a escritora, no que tange à estrutura temática de sua textualização, faz escolhas que dão indícios de como seu estilo de escrita é construído.

  2. Condensed Matter Nuclear Science

    Science.gov (United States)

    Biberian, Jean-Paul

    2006-02-01

    1. General. A tribute to gene Mallove - the "Genie" reactor / K. Wallace and R. Stringham. An update of LENR for ICCF-11 (short course, 10/31/04) / E. Storms. New physical effects in metal deuterides / P. L. Hagelstein ... [et al.]. Reproducibility, controllability, and optimization of LENR experiments / D. J. Nagel -- 2. Experiments. Electrochemistry. Evidence of electromagnetic radiation from Ni-H systems / S. Focardi ... [et al.]. Superwave reality / I. Dardik. Excess heat in electrolysis experiments at energetics technologies / I. Dardik ... [et al.]. "Excess heat" during electrolysis in platinum/K[symbol]CO[symbol]/nickel light water system / J. Tian ... [et al.]. Innovative procedure for the, in situ, measurement of the resistive thermal coefficient of H(D)/Pd during electrolysis; cross-comparison of new elements detected in the Th-Hg-Pd-D(H) electrolytic cells / F. Celani ... [et al.]. Emergence of a high-temperature superconductivity in hydrogen cycled Pd compounds as an evidence for superstoihiometric H/D sites / A. Lipson ... [et al.]. Plasma electrolysis. Calorimetry of energy-efficient glow discharge - apparatus design and calibration / T. B. Benson and T. O. Passell. Generation of heat and products during plasma electrolysis / T. Mizuno ... [et al.]. Glow discharge. Excess heat production in Pd/D during periodic pulse discharge current in various conditions / A. B. Karabut. Beam experiments. Accelerator experiments and theoretical models for the electron screening effect in metallic environments / A. Huke, K. Czerski, and P. Heide. Evidence for a target-material dependence of the neutron-proton branching ratio in d+d reactions for deuteron energies below 20keV / A. Huke ... [et al.]. Experiments on condensed matter nuclear events in Kobe University / T. Minari ... [et al.]. Electron screening constraints for the cold fusion / K. Czerski, P. Heide, and A. Huke. Cavitation. Low mass 1.6 MHz sonofusion reactor / R. Stringham. Particle detection. Research

  3. Convective condensation heat transfer in a horizontal condenser tube

    Energy Technology Data Exchange (ETDEWEB)

    Sarma, P.K. [College of Engineering, GITAM, Visakhapatnam (India); Sastry, C.V.N.; Rao, V.D. [Andhra Univ., College of Engineering, Visakhapatnam (India); Kakac, S.; Liu, H. [Miami Univ., College of Engineering, FL (United States)

    2002-03-01

    The purpose of this article is to solve analytically the problem of convective condensation of vapors inside a horizontal condenser tube. Homogeneous model approach is employed in the estimation of shear velocity, which is subsequently, made use of in predicting local convective condensation heat transfer coefficients. The resulting analysis of the present study is compared with some of the available equations in the literature. It is observed that the agreement is reasonably satisfactory validating the assumptions and the theory presented. (authors)

  4. Superfluidity in polariton condensates

    Energy Technology Data Exchange (ETDEWEB)

    Amo, A; Lefrere, J; Adrados, C; Giacobino, E; Bramati, A [Laboratoire Kastler Brossel, UPMC, ENS and CNRS, 75005 Paris (France); Sanvitto, D; Laussy, F P; Ballarini, D; Valle, E del; MartIn, M D; Tejedor, C; Vina, L [SEMICUAM, Universidad Autonoma de Madrid, 28049 Madrid (Spain); Pigeon, S; Ciuti, C [Laboratoire Materiaux et Phenomenes Quantiques, UMR 7162, Universite Paris Diderot-Paris 7 and CNRS, 75013 Paris (France); Carusotto, I [BEC-CNR-INFM and Dip. di Fisica, Universita di Trento, I-38050 Povo (Italy); Houdre, R [Institut de Photonique et d' Electronique Quantique, Ecole Polytechnique Federale de Lausanne, Station 3, CH-1015 Lausanne (Switzerland); LemaItre, A; Bloch, J [Laboratoire de Photonique et de Nanostructures, CNRS, Route de Nozay, 91460 Marcoussis (France); Krizhanovskii, D N; Skolnick, M S, E-mail: alberto.amo@spectro.jussieu.f [Department of Physics and Astronomy, University of Sheffield, S3 7RH, Sheffield (United Kingdom)

    2010-02-01

    Exciton-polaritons, two-dimensional composite bosons arising from the quantum mixture of excitons and photons, can manifest many-body quantum effects at liquid He temperatures (4 K). Interestingly, polaritons are predicted to behave as particular quantum fluids due to their out of equilibrium character, arising from their reduced lifetime (shorter than their thermalization time). Here we report the observation of superfluid motion of polaritons in semiconductor microcavities both under cw and pulsed excitation. Among other signatures, superfluidity is manifested via the absence of scattering of the polariton condensates when encountering a localized defect in their flow path.

  5. Condensed landscape experience

    DEFF Research Database (Denmark)

    Earon, Ofri

    2011-01-01

    demands, quality of space, mixture of functions, urban complexity, public life and cultural heritage. In order to launch such an approach, an understanding of the spatial, social and environmental significance of a radical re-thinking of relationships between architecture and landscape is necessary....... This paper addresses the question of whether the sensation of landscape can be condensed in function or to the size of an urban building. It also discusses the benefits and potentials of the amalgamate, by underlining the unique qualities of such a hybrid. In an attempt to define the experience of landscape...

  6. Galaxies as condensates

    CERN Document Server

    Bugg, D V

    2012-01-01

    A novel interpretation of MOND is presented. For galactic data, in addition to Newtonian acceleration, there is an attractive acceleration peaking at Milgrom's parameter a_0. The peak lies within experimental error where a_0 = cH_0/2\\pi and H_0 is the present-time value of the Hubble constant. This peaking may be understood in terms of quantum mechanical mixing between Newtonian gravitation and the Hubble mechanism. There are five pointers towards galaxies being Fermi-Dirac condensates.

  7. Polariton condensates put in motion

    Energy Technology Data Exchange (ETDEWEB)

    Sanvitto, D; Amo, A; Vina, L [Departamento de Fisica de Materiales, Universidad Autonoma de Madrid, E-28049, Madrid (Spain); Laussy, F P; Tejedor, C [Departamento de Fisica Teorica de la Materia Condensada, Universidad Autonoma de Madrid, E-28049, Madrid (Spain); LemaItre, A; Bloch, J, E-mail: daniele.sanvitto@uam.es [LPN/CNRS, Route de Nozay, F-91460, Marcoussis (France)

    2010-04-02

    We present several examples of the interesting phenomenology shown by a moving polariton condensate in semiconductor microcavities. The superfluid behavior is probed by colliding the polariton condensate against physical obstacles in the form of natural defects of the sample, demonstrating a clear suppression of scattering when the speed of the flow lies below the critical velocity. At higher velocities Cerenkov-like shock waves around the defect and disruption of the condensate are also observed.

  8. Quantitative assessment of DNA condensation.

    Science.gov (United States)

    Trubetskoy, V S; Slattum, P M; Hagstrom, J E; Wolff, J A; Budker, V G

    1999-02-15

    A fluorescent method is proposed for assessing DNA condensation in aqueous solutions with variety of condensing agents. The technique is based on the effect of concentration-dependent self-quenching of covalently bound fluorophores upon DNA collapse. The method allows a more precise determination of charge equivalency in titration experiments with various polycations. The technique's ability to determine the number of DNA molecules that are condensed together in close proximity is under further investigation.

  9. A new synthesis of enantiomerically pure syn-(S)-β-hydroxy-α-amino acids via asymmetric aldol reactions of aldehydes with a homochiral Ni(II)-glycine/(S)-BPB Schiff base complex

    NARCIS (Netherlands)

    Belokon, Yuri N.; Kochetkov, Konstantin A.; Ikonnikov, Nikolai S.; Strelkova, Tatiana V.; Harutyunyan, Syuzanna R.; Saghiyan, Ashot S.

    2001-01-01

    syn-(S)-β-Hydroxy-α-amino acids were synthesised stereoselectively via elaboration of the asymmetric aldol reactions of aldehydes with a chiral Ni(II)-(S)-BPB/glycine Schiff base complex in the presence of equimolar NaH in THF. The stereoselectivity of the reaction was studied as a function of time,

  10. Nonequilibrium Weak Processes in Kaon Condensation; 2, Kinetics of condensation

    CERN Document Server

    Muto, T; Iwamoto, N; Muto, Takumi; Tatsumi, Toshitaka; Iwamoto, Naoki

    2000-01-01

    The kinetics of negatively charged kaon condensation in the early stages of a newly born neutron star is considered. The thermal kaon process, in which kaons are thermally produced by nucleon-nucleon collisions, is found to be dominant throughout the equilibration process. Temporal changes of the order parameter of the condensate and the number densities of the chemical species are obtained from the rate equations, which include the thermal kaon reactions as well as the kaon-induced Urca and the modified Urca reactions. It is shown that the dynamical evolution of the condensate is characterized by three stages: the first, prior to establishment of a condensate, the second, during the growth and subsequent saturation of the condensate, and the third, near chemical equilibrium. The connection between the existence of a soft kaon mode and the instability of the noncondensed state is discussed. Implications of the nonequilibrium process on the possible delayed collapse of a protoneutron star are also mentioned.

  11. Condensation Processes in Geothermal Systems

    Science.gov (United States)

    Norman, D. I.; Moore, J. N.

    2005-12-01

    We model condensation processes in geothermal systems to understand how this process changes fluid chemistry. We assume two processes operate in geothermal systems: 1) condensation of a vapor phase derived by boiling an aqueous geothermal fluid into a cool near surface water and 2) condensation of a magmatic vapor by a deep circulating meteoric thermal fluid. It is assumed that the condensation process has two stages. Initially the condensing fluid is under saturated in gaseous species. Condensation of the vapor phase continues until the pressure on the fluid equals the sum of the partial pressures of water and the dissolved gaseous species. At that time bubbles flux through the condensing fluid. In time the fluid and fluxing gas phase come to equilibrium. Calculation shows that during the second stage of the condensation process the liquid phase becomes enriched in more soluble gaseous species like CO2 and H2S, and depleted in less soluble species like CH4 and N2. Stage 2 condensation processes can therefore be monitored by ratios of more and less condensable species like CO2/N2. Condensation of vapor released by boiling geothermal fluids results in liquids with high concentrations of H2S and CO2 like is seen in geothermal system steam-heated waters. Condensation of a magmatic vapor into circulating meteoric water has been proposed, but not well demonstrated. We compare to our models the Cerro Prieto, Mexico gas analysis data set collected over twelve years time by USGS personnel. It was assumed for modeling that the Cerro Prieto geothermal fluids are circulating meteoritic fluids with N2/Ar ratios about 40 to which is added a magmatic vapor with N2/Ar ratio = 400. The Cerro Prieto analyses show a strong correlation between N2/Ar and CO2/N2 as predicted by calculation. Two dimensional image plots of well N2/Ar + CO2/N2 show a bull's-eye pattern on the geothermal field. Image plots of analyses collected over a year or less time show N2/Ar and CO2/N2 hot spots

  12. Estrutura fatorial da escala de atitudes frente a relacionamentos afetivos estáveis

    Directory of Open Access Journals (Sweden)

    Taciano Lemos Milfont

    Full Text Available O presente estudo visa contribuir para a comprovação da estrutura fatorial da Escala de Atitudes Frente a Relacionamentos Afetivos Estáveis (RAE; Reis, 1995. Participaram da pesquisa 658 estudantes universitários com idade média 19,9 anos (DP=2,5. Análises fatoriais exploratórias e confirmatórias indicaram a existência de uma estrutura multidimensional. Os cinco fatores encontrados (Comprometimento, Edificação, Mutualidade, Envolvimento e Indulgência apresentaram índices de consistência interna satisfatórios (0,68<α<0,83, itens com saturações altas (0,46<λy<0,75 e significativas (p<0,05. Esta estrutura multidimensional apresentou melhores índices de bondade de ajuste (χ2/gl=3,07; GFI=0,91; CFI=0,97; RMSEA=0,056 e foi estatisticamente superior [Δχ2(111=676,69, p<0,001] à estrutura unidimensional. Resultados de correlações com as auto-imagens independente e interdependente (Singelis, 1994, com os valores humanos básicos (Gouveia, 2003, além de diferenças quanto ao sexo, confirmam a validade dos cinco novos fatores.

  13. Microgravity condensing heat exchanger

    Science.gov (United States)

    Thomas, Christopher M. (Inventor); Ma, Yonghui (Inventor); North, Andrew (Inventor); Weislogel, Mark M. (Inventor)

    2011-01-01

    A heat exchanger having a plurality of heat exchanging aluminum fins with hydrophilic condensing surfaces which are stacked and clamped between two cold plates. The cold plates are aligned radially along a plane extending through the axis of a cylindrical duct and hold the stacked and clamped portions of the heat exchanging fins along the axis of the cylindrical duct. The fins extend outwardly from the clamped portions along approximately radial planes. The spacing between fins is symmetric about the cold plates, and are somewhat more closely spaced as the angle they make with the cold plates approaches 90.degree.. Passageways extend through the fins between vertex spaces which provide capillary storage and communicate with passageways formed in the stacked and clamped portions of the fins, which communicate with water drains connected to a pump externally to the duct. Water with no entrained air is drawn from the capillary spaces.

  14. PPOOLEX experiments on wall condensation

    Energy Technology Data Exchange (ETDEWEB)

    Laine, J.; Puustinen, M. (Lappeenranta Univ. of Technology, Nuclear Safety Research Unit (Finland))

    2009-08-15

    This report summarizes the results of the wall condensation experiments carried out in December 2008 and January 2009 with the scaled down PPOOLEX test facility designed and constructed at Lappeenranta University of Technology. Steam was blown into the dry well compartment and from there through a DN200 blowdown pipe to the condensation pool. Altogether five experiments, each consisting of several blows, were carried out. The main purpose of the experiment series was to study wall condensation phenomenon inside the dry well compartment while steam is discharged through it into the condensation pool and to produce comparison data for CFD calculations at VTT. The PPOOLEX test facility is a closed stainless steel vessel divided into two compartments, dry well and wet well. For the wall condensation experiments the test facility was equipped with a system for collecting and measuring the amount of condensate from four different wall segments of the dry well compartment. A thermo graphic camera was used in a couple of experiments for filming the outside surface of the dry well wall. The effect of the initial temperature level of the dry well structures and of the steam flow rate for the accumulation of condensate was studied. The initial temperature level of the dry well structures varied from 23 to 99 deg. C. The steam flow rate varied from 90 to 690 g/s and the temperature of incoming steam from 115 to 160 deg. C. During the initial phase of steam discharge the accumulation of condensate was strongly controlled by the temperature level of the dry well structures; the lower the initial temperature level was the more condensate was accumulated. As the dry well structural temperatures increased the condensation process slowed down. Most of the condensate usually accumulated during the first 200 seconds of the discharge. However, the condensation process never completely stopped because a small temperature difference remained between the dry well atmosphere and inner wall

  15. APPARATUS FOR CONDENSATION AND SUBLIMATION

    Science.gov (United States)

    Schmidt, R.J.; Fuis, F. Jr.

    1958-10-01

    An apparatus is presented for the sublimation and condensation of uranium compounds in order to obtain an improved crystalline structure of this material. The apparatus comprises a vaporizing chamber and condensing structure connected thereto. There condenser is fitted with a removable liner having a demountable baffle attached to the liner by means of brackets and a removable pin. The baffle is of spiral cross-section and is provided with cooling coils disposed between the surfaces of the baffle for circulation of a temperature controlling liquid within the baffle. The cooling coll provides for controlllng the temperature of the baffle to insure formatlon of a satisfactory condensate, and the removable liner facilitates the removal of condensate formed during tbe sublimation process.

  16. Antikaon condensation in neutron stars

    CERN Document Server

    Pal, S; Greiner, W

    2000-01-01

    We investigate the condensation of charged K sup - meson and neutral anti-K sup 0 meson in dense neutron star matter. Calculations are performed in relativistic mean field models in which both the baryon-baryon and (anti)kaon-baryon interactions are mediated by meson exchange. It is found that anti-K sup 0 condensation is quite sensitive to the antikaon optical potential and depends more strongly on the nucleonic equation of state. For moderate values of antikaon potential and a rather stiff equation of state, a significant region of maximum mass star will contain anti-K sup 0 meson. The critical density of anti-K sup 0 condensation is always higher than that of K sup - condensation. With the appearance of K sup - and anti-K sup 0 condensates, pairs of p-K sup - and n-Kbar sup 0 are produced with equal proportion leading to a perfectly symmetric matter of nucleons and antikaons in neutron stars. Along with K sup - condensate, anti-K sup 0 condensate makes the equation of state much softer resulting in smaller...

  17. DFT Study on the Origin of the Enantioselectivity of (S)-4-HydroxyIproline-Catalyzed Direct Aldol Reaction between Acetone and 4-Nitrobenzaldehyde

    Institute of Scientific and Technical Information of China (English)

    FAN,Jian-Fen; WU,Li-Fen; SUN,Yun-Peng

    2007-01-01

    DFT-B3LYP calculations were carried out to study the enantioselectivity of the(S)-4-hydroxylproline-catalyzed direct aldol reaction between acetone and 4-nitrobenzaldehyde.Four transition structures associated with the stereo-controlling step of the reaction have been determined.They are corresponding to the anti and syn arrangements of the methylene moiety related to the carboxylic acid group in enamine intermediate and the si and re attacks to the aldehyde carbonyl carbon.The effect of DMSO solvent on the stereo-controlling step was investigated with polarized continuum model(PCM).The computed energies of the transition states reveal the moderate enantioselectivity of the reaction.

  18. Synthesis, double-helix formation, and higher-assembly formation of chiral polycyclic aromatic compounds: conceptual development of polyketide aldol synthesis.

    Science.gov (United States)

    Yamaguchi, Masahiko; Shigeno, Masanori; Saito, Nozomi; Yamamoto, Koji

    2014-02-01

    Polycyclic aromatic compounds are an important group of substances in chemistry, and the study of their properties is a subject of interest in the development of drugs and materials. We have been conducting studies to develop chiral polycyclic aromatic compounds, i.e., helicenes and equatorenes. These helical molecules showed notable aggregate-forming properties and the capability for chiral recognition exerted by noncovalent bond interactions, which were not observed in compounds with central chirality. Homo- and hetero-double-helix-forming helicene oligomers were developed, and the latter self-assembled to form gels and vesicles. In this article, we describe such hierarchical studies of polycyclic aromatic compounds, which were started from polyketide aldol synthesis.

  19. Efficient, Long-Life Biocidal Condenser Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Environmental control systems for manned lunar and planetary bases will require condensing heat exchangers to control humidity in manned modules. Condensing surfaces...

  20. Efficient, Long-Life Biocidal Condenser Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Environmental control systems for manned lunar and planetary bases will require condensing heat exchangers to control humidity. Condensing surfaces must be...

  1. Bose condensation in (random traps

    Directory of Open Access Journals (Sweden)

    V.A. Zagrebnov

    2009-01-01

    Full Text Available We study a non-interacting (perfect Bose-gas in random external potentials (traps. It is shown that a generalized Bose-Einstein condensation in the random eigenstates manifests if and only if the same occurs in the one-particle kinetic-energy eigenstates, which corresponds to the generalized condensation of the free Bose-gas. Moreover, we prove that the amounts of both condensate densities are equal. This statement is relevant for justification of the Bogoliubov approximation} in the theory of disordered boson systems.

  2. ESTRUTURA ORGANIZACIONAL E GESTÃO DO CONHECIMENTO

    Directory of Open Access Journals (Sweden)

    Edoardo Perrotti

    2005-11-01

    -style-type:export-only; mso-default-props:yes; font-size:10.0pt; mso-ansi-font-size:10.0pt; mso-bidi-font-size:10.0pt;} @page Section1 {size:612.0pt 792.0pt; margin:70.85pt 3.0cm 70.85pt 3.0cm; mso-header-margin:36.0pt; mso-footer-margin:36.0pt; mso-paper-source:0;} div.Section1 {page:Section1;} -->

    Resumo

    Determinar quais os efeitos dos critérios de departamentalização em estruturas organizacionais na geração e disseminação do conhecimento é o objetivo principal proposto nesta pesquisa. Para isto há necessidade de entender como o conhecimento e as informações circulam dentro das organizações, quais tipos de conhecimento são estes, quais processos são utilizados para disseminação dos novos conhecimentos adquiridos, como são gerados os conhecimentos nas organizações, como a empresa está estruturada, dentre outros temas relevantes para o estudo. Com os dados gerais obtidos através da aplicação das entrevistas, foi elaborada uma análise qualitativa para detecção de correlação efetiva entre questões e variáveis. O presente estudo permitiu concluir que a Estrutura Organizacional pode ter efeito substancialmente positivo sobre a Gestão do

  3. Nuclear fusion inside condense matters

    Institute of Scientific and Technical Information of China (English)

    HE Jing-tang

    2007-01-01

    This article describes in detail the nuclear fusion inside condense matters--the Fleischmann-Pons effect, the reproducibility of cold fusions, self-consistentcy of cold fusions and the possible applications.

  4. Nonequilibrium Thermodynamics of Wealth Condensation

    CERN Document Server

    Braun, D

    2006-01-01

    We analyze wealth condensation for a wide class of stochastic economy models on the basis of the economic analog of thermodynamic potentials, termed transfer potentials. The economy model is based on three common transfers modes of wealth: random transfer, profit proportional to wealth and motivation of poor agents to work harder. The economies never reach steady state. Wealth condensation is the result of stochastic tunneling through a metastable transfer potential. In accordance with reality, both wealth and income distribution transiently show Pareto tails for high income subjects. For metastable transfer potentials, exponential wealth condensation is a robust feature. For example with 10 % annual profit 1% of the population owns 50 % of the wealth after 50 years. The time to reach such a strong wealth condensation is a hyperbolic function of the annual profit rate.

  5. Solar engineering - a condensed course

    Energy Technology Data Exchange (ETDEWEB)

    Broman, Lars

    2011-11-15

    The document represents the material covered in a condensed two-week course focusing on the most important thermal and PV solar energy engineering topics, while also providing some theoretical background.

  6. Modelagem de estruturas fotonicas por elementos finitos 2D no dominio do tempo

    OpenAIRE

    Vitaly Felix Rodriguez Esquerre

    2003-01-01

    Resumo: Esta tese apresenta uma metodologia numérica eficiente e robusta para a análise de estruturas fotônicas tanto em coordenadas cartesianas como cilíndricas, e pressupõe estruturas com índices de refração arbitrários. Os algoritmos, baseados no método dos elementos finitos, foram desenvolvidos no domínio do tempo e da freqüência. A primeira abordagem é baseada no método de propagação de ondas (WPM: Wave Propagation Method), levando-se em conta três esquemas: banda estreita (desprezando a...

  7. Mudança de estrutura moraica do latim ao português

    Directory of Open Access Journals (Sweden)

    Evellyne Patrícia Figueiredo de Sousa Costa

    2011-12-01

    Full Text Available Este estudo tem como objetivo investigar a evolução da estrutura moraica do latim ao português. A língua latina apresenta distinção quantitativa vocálica e consonantal: (i sílabas leves, portadoras de uma mora (e.le.men.tum; (ii sílabas pesadas, portadoras de duas moras (bul.ga; (iii sílabas superpesadas, portadoras de três moras segundo a nossa proposta (paul.lum. Diacronicamente, há a perda da distintividade quantitativa dentre as vogais e, na passagem às línguas neorromânicas, a estrutura moraica tem seus efeitos. Diante desse cenário e a partir dos pressupostos da Teoria Moraica de Hayes (1989, investigamos os efeitos dessa mudança através de processos fonológicos envolvidos, tais como ditongação e monotongação. A Teoria Moraica busca caracterizar de que modo as línguas atribuem estrutura moraica e que princípios atuam nessas línguas. Hayes (1989 define mora como uma unidade de peso do tier prosódico que caracteriza o contraste entre sílabas longas e breves, além de contar como uma posição fonológica (segmento longo é representado como duplamente ligado. Propomos que as escolhas feitas pela língua portuguesa, tais como ditongação e monotongação, para lidar com a estrutura moraica latina já estão disponíveis em latim vulgar e que princípios como Stray Erasure e Parasitic Delinking, relacionados com Licenciamento Prosódico atuam na referida mudança.

  8. Estrutura de capital: uma exploração preliminar da abordagem pecking order no Brasil

    OpenAIRE

    Pereira, António Augusto Negreiros Vaz Simões

    1995-01-01

    Este trabalho tem por objetivo, essencialmente, estudar um dos modelos que procuram explicar as políticas de concepção de estrutura de capital. Embora já usado em 1961 por Donaldson, o termo pecking order rotula um modelo criado em 1984 por stwart Myers e Nicholas Majluf, segundo o qual as empresas, procuram financiar seus novos investimentos dando prioridade aos recursos internamente gerados e, uma vez esgotados estes, aderem ao uso de instrumentos de financiamento ex...

  9. A abordagem do conceito como uma estrutura semiótica

    Directory of Open Access Journals (Sweden)

    Carlos Xavier de Azevedo Netto

    Full Text Available O presente trabalho parte da consideração de que qualquer prática informacional possui uma estruturação que viabiliza a transferência da informação e a sua efetivação enquanto conhecimento. E essa efetivação realiza-se a partir da estruturação e uso de conceitos. Considerando-se que essa estruturação se dá no nível discursivo de cada comunidade informacional, utiliza-se a noção de discurso fundada em Foucault (1996. Para discutir a troca de informação, utilizou-se dos aportes teóricos de Dalhberg (1978a,1978b; para a teoria do conceito, de Cassirer (1977; Foucault (1992 e Gardin (1992, na discussão da representação. Assim, a conceituação e compartilhamento das representações sociais fazem com que seja necessário o entendimento do papel dos conceitos dentro da formação simbólica e discursiva, em um processo de transferência da informação em uma determinada comunidade. Para tanto, discute-se a formação e prática do discurso, sob o ponto de vista da teoria semiótica de Peirce (1977 e se propõe a análise da entidade conceito como estrutura semiótica.

  10. Narrativa visual: o interplay entre modo e estruturas genéricas

    OpenAIRE

    Silvestre, Carminda; Gonçalves, Madalena

    2010-01-01

    O presente artigo pretende explorar a narrativa visual a partir da variante de registo – o modo – para mostrar que as estruturas genéricas do género são determinadas pelo uso dos recursos semióticos que o produtor de texto escolhe para a concretização da função do texto.

  11. Condenser Optimization in Steam Power Plant

    Institute of Scientific and Technical Information of China (English)

    Sukru Bekdemir; Recep Ozturk; Zehra Yumurtac

    2003-01-01

    In this paper the effects of the condenser design parameters (such as turbine inlet condition, turbine power and condenser pressure) on heat transfer area, cooling water flow-rate, condenser cost and specific energy generation cost are studied for surface type condenser.The results are given in the text and also shown as diagrams.

  12. Rapid Drop Dynamics During Superhydrophobic Condensation

    Science.gov (United States)

    Zhang, Xiaodong; Boreyko, Jonathan; Chen, Chuan-Hua

    2008-11-01

    Rapid drop motion is observed on superhydrophobic surfaces during condensation; condensate drops with diameter of order 10 μm can move at above 100G and 0.1 m/s. When water vapor condenses on a horizontal superhydrophobic surface, condensate drops move in a seemingly random direction. The observed motion is attributed to the energy released through coalescence of neighboring condensate drops. A scaling analysis captured the initial acceleration and terminal velocity. Our work is a step forward in understanding the dynamics of superhydrophobic condensation occurring in both natural water-repellant plants and engineered dropwise condensers.

  13. Asymmetric synthesis of α-amino acids via homologation of Ni(II) complexes of glycine Schiff bases. Part 2: aldol, Mannich addition reactions, deracemization and (S) to (R) interconversion of α-amino acids.

    Science.gov (United States)

    Sorochinsky, Alexander E; Aceña, José Luis; Moriwaki, Hiroki; Sato, Tatsunori; Soloshonok, Vadim

    2013-11-01

    This review provides a comprehensive treatment of literature data dealing with asymmetric synthesis of α-amino-β-hydroxy and α,β-diamino acids via homologation of chiral Ni(II) complexes of glycine Schiff bases using aldol and Mannich-type reactions. These reactions proceed with synthetically useful chemical yields and thermodynamically controlled stereoselectivity and allow direct introduction of two stereogenic centers in a single operation with predictable stereochemical outcome. Furthermore, new application of Ni(II) complexes of α-amino acids Schiff bases for deracemization of racemic α-amino acids and (S) to (R) interconversion providing additional synthetic opportunities for preparation of enantiomerically pure α-amino acids, is also reviewed. Origin of observed diastereo-/enantioselectivity in the aldol, Mannich-type and deracemization reactions, generality and limitations of these methodologies are critically discussed.

  14. Scrutinizing the pion condensed phase

    CERN Document Server

    Carignano, Stefano; Mammarella, Andrea; Mannarelli, Massimo; Pagliaroli, Giulia

    2016-01-01

    When the isospin chemical potential exceeds the pion mass, charged pions condense in the zero-momentum state forming a superfluid. Chiral perturbation theory provides a very powerful tool for studying this phase. However, the formalism that is usually employed in this context does not clarify various aspects of the condensation mechanism and makes the identification of the soft modes problematic. We re-examine the pion condensed phase using different approaches within the chiral perturbation theory framework. As a first step, we perform a low-density expansion of the chiral Lagrangian valid in the normal phase and close to the onset of the Bose-Einstein condensation. We obtain an effective theory that can be mapped to a Gross-Pitaevskii Lagrangian in which, remarkably, all the coefficients depend on the isospin chemical potential. The low-density expansion becomes unreliable deep in the pion condensed phase. For this reason, we develop an alternative field expansion deriving a low-energy Lagrangian analog to ...

  15. Polariton condensates at room temperature

    Science.gov (United States)

    Guillet, Thierry; Brimont, Christelle

    2016-10-01

    We review the recent developments of the polariton physics in microcavities featuring the exciton-photon strong coupling at room temperature, and leading to the achievement of room-temperature polariton condensates. Such cavities embed active layers with robust excitons that present a large binding energy and a large oscillator strength, i.e. wide bandgap inorganic or organic semiconductors, or organic molecules. These various systems are compared, in terms of figures of merit and of common features related to their strong oscillator strength. The various demonstrations of polariton laser are compared, as well as their condensation phase diagrams. The room-temperature operation indeed allows a detailed investigation of the thermodynamic and out-of-equilibrium regimes of the condensation process. The crucial role of the spatial dynamics of the condensate formation is discussed, as well as the debated issue of the mechanism of stimulated relaxation from the reservoir to the condensate under non-resonant excitation. Finally the prospects of polariton devices are presented.

  16. On the onset of surface condensation: formation and transition mechanisms of condensation mode

    Science.gov (United States)

    Sheng, Qiang; Sun, Jie; Wang, Qian; Wang, Wen; Wang, Hua Sheng

    2016-08-01

    Molecular dynamics simulations have been carried out to investigate the onset of surface condensation. On surfaces with different wettability, we snapshot different condensation modes (no-condensation, dropwise condensation and filmwise condensation) and quantitatively analyze their characteristics by temporal profiles of surface clusters. Two different types of formation of nanoscale droplets are identified, i.e. the formations with and without film-like condensate. We exhibit the effect of surface tensions on the formations of nanoscale droplets and film. We reveal the formation mechanisms of different condensation modes at nanoscale based on our simulation results and classical nucleation theory, which supplements the ‘classical hypotheses’ of the onset of dropwise condensation. We also reveal the transition mechanism between different condensation modes based on the competition between surface tensions and reveal that dropwise condensation represents the transition states from no-condensation to filmwise condensation.

  17. Condensed Matter Physics - Biology Resonance

    Science.gov (United States)

    Baskaran, G.

    The field of condensed matter physics had its genesis this century and it has had a remarkable evolution. A closer look at its growth reveals a hidden aim in the collective consciousness of the field - a part of the development this century is a kind of warm up exercise to understand the nature of living condensed matter, namely the field of biology, by a growing new breed of scientists in the coming century. Through some examples the vitality of this interaction will be pointed out.

  18. Turbulent mixing condensation nucleus counter

    Science.gov (United States)

    Mavliev, Rashid

    The construction and operating principles of the Turbulent Mixing Condensation Nucleus Counter (TM CNC) are described. Estimations based on the semiempirical theory of turbulent jets and the classical theory of nucleation and growth show the possibility of detecting particles as small as 2.5 nm without the interference of homogeneous nucleation. This conclusion was confirmed experimentally during the International Workshop on Intercomparison of Condensation Nuclei and Aerosol Particle Counters (Vienna, Austria). Number concentration, measured by the Turbulent Mixing CNC and other participating instruments, is found to be essentially equal.

  19. Evaporative Condensers in Comfortable Air Conditioning System

    Institute of Scientific and Technical Information of China (English)

    YIN Ying-de; ZHU Dong-sheng; DU Gui-mei; LI Yuan-xi; SUN He-jing; LIU Qing-ming

    2009-01-01

    The operating theory of an evaporative condenser was expatiated.The difference between an e-vaporative condensing refrigeration system and a general refrigeration system was analyzed.Compared with the air-cooled and the water-cooled,the virtues of energy-conservation and water-conservation of evaporative con-densers were analyzed.Some questions existing in the application of evaporative condensers were pointed out,the corresponding solving methods were analyzed accordingly,and the development trend of evaporative con-densing technique in mechanical refrigeration system field and the applied foreground of evaporative condensers in comfortable air conditioning were prospected.

  20. Modelagem da formação de estruturas tridimensionais em crescimento epitaxial

    OpenAIRE

    Leal, Fábio Fagundes

    2011-01-01

    Nesta tese estudamos o surgimento de estruturas tridimensionais auto-arranjadas em superfícies crescidas por epitaxia por feixe molecular (MBE). Foram utilizadas simulações de Monte Carlo cinético para a descrição de dois casos específicos dessas morfologias: formação de morros e de nucleação de ilhas 3d de escalas nanométricas conhecidas como pontos quânticos (QDs). Os modelos propostos nessa tese possuem como principal processo a difusão super cial termicamente ativada. O principal ingredie...

  1. Teoria da firma: comportamento dos administradores, custos de agência e estrutura de propriedade

    OpenAIRE

    Jensen, Michael C.; Meckling,William H.

    2008-01-01

    Este artigo integra elementos da teoria da agência, da teoria dos direitos de propriedade e da teoria das finanças para desenvolver uma teoria da estrutura de propriedade da firma. Definimos o conceito de custos de agência, demonstramos a sua relação com a questão da "separação e controle", investigamos a natureza dos custos de agência resultantes da presença de capital de terceiros e capital próprio externo, demonstramos quem arca com esses custos e por quê, e investigamos o ótimo de Pareto ...

  2. Estruturas flexíveis multicamada para gestão de humidade

    OpenAIRE

    Madeira, Manuela José Cubelo Torres da Fonseca e

    2009-01-01

    O conforto é uma necessidade para a maioria das pessoas. A busca de vestuário que se adapte às condições ambientais tornou-se essencial. Queremos materiais que nos mantenham quentes ou frescos, em condições de frio ou calor, e sejam capazes de nos manter secos se chover, ou se transpirarmos, devido a actividade intensa, ou simplesmente porque está quente. O objectivo principal deste trabalho era desenvolver uma estrutura multicamada respirável, para posterior aplicação num sapato perfurado...

  3. Sensores ópticos para monitorização dinâmica de estruturas

    OpenAIRE

    Antunes, Paulo Fernando da Costa

    2011-01-01

    O presente trabalho centra-se no desenvolvimento e aplicação de sensores de aceleração ópticos, baseados em redes de Bragg gravadas em fibras ópticas, para monitorização da integridade estrutural de estruturas de engenharia civil. Foram implementados dois acelerómetros uniaxiais e um acelerómetro biaxial. Recorreu-se a uma ferramenta de simulação baseada no método dos elementos finitos que permitiu optimizar, sem custos de produção, as características dos sensores, nomeadamente a sua frequ...

  4. Inovação empresarial : investimento e estrutura de financiamento

    OpenAIRE

    Silva, Marlos Henrique da

    2008-01-01

    O presente trabalho propõe-se a analisar a teoria financeira tradicional para a qual as empresas procurarão sempre uma estrutura de capital “óptima”, que minimize ao mesmo tempo os seus custos e riscos. Quanto maiores as vantagens de custo associadas ao nível corrente das taxas de juros e dos impostos, maior a tendência ao uso de endividamento, ocorrendo o inverso quanto maior for o risco de falência, buscando uma relação entre o endividamento e a emissão óptima para a empre...

  5. Análise da estrutura genética da raça caracu

    OpenAIRE

    Dias, Amábily Cardoso

    2012-01-01

    O objetivo do trabalho foi determinar a estrutura genética dos bovinos da raça Caracu. Foi utilizado um arquivo de pedigree de 130.165 animais que foi obtido da Associação Brasileira de Criadores de Caracu. O banco de dados foi dividido em seis períodos: 1979-1983, 1984-1988, 1989-1993, 1994-1998, 1999-2003 e 2004-2008. Foram estimados o coeficiente de endogamia, o tamanho efetivo populacional e o número efetivo de fundadores e ancestrais. O coeficiente médio de endogamia entre os animais c...

  6. Mudanças ambientais e estrutura de relacionamento do corredor de transporte centroleste

    OpenAIRE

    2013-01-01

    Resumo: O objetivo central desta pesquisa foi identificar a influência de mudanças ambientais no padrão de relacionamento de uma rede de organizações. Na busca desse alvo, foi analisado o impacto da mudança cambial brasileira de janeiro de 1999, na rede formada pelos participantes do Corredor de Transporte Centro leste. Além desse objetivo, esta pesquisa identificou a estrutura de relações da rede com base na existência ou não do relacionamento, sua periodicidade, razão e base predominantes, ...

  7. A estrutura científica da inteligência competitiva

    Directory of Open Access Journals (Sweden)

    Elaine Coutinho MARCIAL

    Full Text Available Resumo A estrutura científica de uma área é a base para o seu reconhecimento como disciplina científica. Sendo a Inteligência Competitiva uma área recente do conhecimento, objetiva-se com esta pesquisa a proposição de sua estrutura científica e sistema de investigação nos níveis epistemológico, científico e aplicado. Busca-se também identificar o paradigma da Inteligência Competitiva, enumerar as teorias e modelos que a fundamentam e listar as soluções de problemas da vida real propostos por essa área. Trata-se de pesquisa descritiva cujo método utilizado foi o levantamento e análise estatística do comportamento de variáveis de um modelo sistêmico de definição de objeto científico em uma amostra formada por artigos científicos publicados em língua inglesa e portuguesa. Os resultados mostram a existência de estudo nos três níveis da estrutura científica. Há três paradigmas que regem a pesquisa nessa área. Apresenta corpo teórico que apoia estudos desse campo e que é utilizado para auxiliar na solução de problemas de ordem prática. Há pesquisas em nível aplicado, destacando-se as relacionadas à melhoria do processo de Inteligência Competitiva e à contribuição desta área a outros processos organizacionais. Conclui-se que a proposta explicitada de estrutura científica e de sistema de investigação, nos níveis epistemológico, científico e aplicado, para a Inteligência Competitiva é adequada à compreensão desta disciplina.

  8. Crescimento e estrutura de monocamadas de Co sobre Cu90Au10(100)

    OpenAIRE

    Alysson Martins Almeida Silva

    2008-01-01

    O estudo das correlações entre as propriedades estruturais e magnéticas de filmes finos e ultrafinos é hoje assunto de grande interesse tanto científico como tecnológico, sendo que, dada a disponibilidade de materiais e a importância das aplicações atuais e potenciais, filmes magnéticos compostos por metais e ligas de metais de transição 3d estão entre os materiais mais investigados. O Co é um metal de transição 3d, ferromagnético, e que, em volume, apresenta estrutura hexagonal compacta (...

  9. Decisões da estrutura de capital: empresas portuguesas em Angola

    OpenAIRE

    Sousa, Ana Rita de Castro

    2011-01-01

    Objectivo: o presente estudo consiste na observação dos factores determinantes da estrutura de capital das empresas que detêm investimento directo em Angola. Metodologia: dados em painel, pois a amostra é bastante reduzida e os dados são não equilibrados. Resultados: Crescimento das Vendas provoca um crescimento de 2.89 valores monetários do Debt to Equity Ratio; a Liquidez fomenta um aumento de 2.76 unidades monetários no Debt to Equity Ratio; a Rentabilidade das Vendas ...

  10. Impacto de baixa velocidade em estruturas sandwich à base de cortiça

    OpenAIRE

    Nunes, Cláudia Patrícia Zeferino

    2009-01-01

    Os componentes tipo sandwich têm alcançado uma vasta aceitação em aplicações estruturais, devido às suas vantagens relativamente a outros materiais em termos de melhoria de estabilidade, elevada rigidez e resistência específicas. Os compósitos à base de aglomerados de cortiça apresentam-se como uma das alternativas mais promissoras aos materiais sintéticos para a construção de estruturas sandwich. Além das suas características estruturais únicas que permitem, entre outros aspectos, uma melhor...

  11. Magnetofermionic condensate in two dimensions

    Science.gov (United States)

    Kulik, L. V.; Zhuravlev, A. S.; Dickmann, S.; Gorbunov, A. V.; Timofeev, V. B.; Kukushkin, I. V.; Schmult, S.

    2016-11-01

    Coherent condensate states of particles obeying either Bose or Fermi statistics are in the focus of interest in modern physics. Here we report on condensation of collective excitations with Bose statistics, cyclotron magnetoexcitons, in a high-mobility two-dimensional electron system in a magnetic field. At low temperatures, the dense non-equilibrium ensemble of long-lived triplet magnetoexcitons exhibits both a drastic reduction in the viscosity and a steep enhancement in the response to the external electromagnetic field. The observed effects are related to formation of a super-absorbing state interacting coherently with the electromagnetic field. Simultaneously, the electrons below the Fermi level form a super-emitting state. The effects are explicable from the viewpoint of a coherent condensate phase in a non-equilibrium system of two-dimensional fermions with a fully quantized energy spectrum. The condensation occurs in the space of vectors of magnetic translations, a property providing a completely new landscape for future physical investigations.

  12. Approaching Bose-Einstein Condensation

    Science.gov (United States)

    Ferrari, Loris

    2011-01-01

    Bose-Einstein condensation (BEC) is discussed at the level of an advanced course of statistical thermodynamics, clarifying some formal and physical aspects that are usually not covered by the standard pedagogical literature. The non-conventional approach adopted starts by showing that the continuum limit, in certain cases, cancels out the crucial…

  13. Condensational theory of stationary tornadoes

    CERN Document Server

    Makarieva, Anastassia M; Nefiodov, Andrei V; 10.1016/j.physleta.2011.04.023

    2012-01-01

    Using the Bernoulli integral for air streamline with condensing water vapor a stationary axisymmetric tornado circulation is described. The obtained profiles of vertical, radial and tangential velocities are in agreement with observations for the Mulhall tornado, world's largest on record and longest-lived among the three tornadoes for which 3D velocity data are available. Maximum possible vortex velocities are estimated.

  14. Estrutura e temporalidade na psicologia e na psicanálise Structure and temporality in psychology and psychoanalysis

    Directory of Open Access Journals (Sweden)

    Isabel Fortes

    2006-12-01

    Full Text Available Pretende-se fazer uma diferenciação entre a forma como a estrutura é vista pela psicologia e a maneira como é concebida pela psicanálise, com o intuito de analisar a especificidade da noção de estrutura na teoria psicanalítica e a sua importância no que diz respeito à questão da temporalidade. Para isso, a estrutura psicológica é vista, primeiramente, a partir do gestaltismo psicológico, um estruturalismo sem gênese, e, depois, na teoria piagetiana, que introduz a gênese na estrutura. Na estrutura psicanalítica, a temporalidade é da ordem da atualização, como se pode atestar no conceito de a posteriori (o Nachträglichkeit.The article intends to distinguish the way structure is regarded by psychology from the way it is conceived in psychoanalysis, with the aim of analyzing the specificity of the idea of structure in psychoanalytical theory and its importance in relation to temporality. To this effect, psychological structure is seen firstly from the point of view of psychological Gestaltism, a structuralism without genesis, and secondly, in Piagetian theory, which introduces genesis into structure. In psychoanalytical structure temporality is of the order of actualization, as it can be seen in the concept of a posteriori (Nachträglichkeit.

  15. Structure and tanning properties of melamine-aldol resin%密胺-醇胺树脂的结构及其鞣革功能研究

    Institute of Scientific and Technical Information of China (English)

    王玉增; 李建波; 单志华

    2016-01-01

    研究了制备密胺-醇胺树脂MAR(melamine-aldol resin)的方法,分析了MAR的基本结构和性能,并探究了其做鞣剂的效果以及其他鞣剂复鞣MAR鞣革的效果.经试验发现:MAR溶液的耐温稳定性及耐盐稳定性较好,在低pH下对醛鞣剂也较为稳定.MAR具良好的鞣革性能,6% MAR鞣革的Ts达78.2℃.MAR鞣革的复鞣试验发现用荆树皮栲胶复鞣时,复鞣革Ts高达97.5℃;用戊二醛作复鞣剂时,复鞣革Ts达92.7℃,说明MAR是一种很好的鞣革材料,尤其是MAR鞣革经加脂后Ts降低极少.

  16. Estrutura e Dinâmica do Sistema Afectivo das Dimensões de Avaliação às Estruturas de Acção - Emoções

    OpenAIRE

    Cardoso, Francisco Manuel dos Santos

    2008-01-01

    Tese de Doutoramento em Psicologia Tivemos como principal propósito a apresentação de uma hermenêutica para o sistema afectivo que se oferecesse também como tela para o desenvolvimento da presente dissertação. Nessa sequência, ao longo da primeira parte desenvolvemos uma reflexão que procurou realçar uma estrutura de representação para o sistema afectivo que confluiu para uma estrutura bipolar arquitectada por um sistema hedónico definido pela dimensão bivalente prazer versus desprazer e p...

  17. Molecular Effects on Evaporation and Condensation

    OpenAIRE

    Meland, Roar

    2002-01-01

    In this thesis the evaporation from and condensation on a plane liquid surface have been studied by analysis and molecular dynamics simulations. The effect of the condensation coefficient on the inverted temperature gradient for a two-surface evaporation-condensation geometry is investigated by the moment method. The influence of the molecular exchange phenomenon on the gas-kinetic treatment of evaporation and condensation is shown to be neglible under certain assumptions. Methods to simulate...

  18. O toxicômano: dados psico-sociais e estrutura psico-dinâmica

    Directory of Open Access Journals (Sweden)

    Richard Bucher

    Full Text Available Toxicómanos foram examinados mediante um questionário e o teste projetivo de Szondi. A divisão em três grupos (dois masculinos e um feminino permitiu efetuar comparações estatísticas e interpretar as estruturas pulsionais bem como suas características diferenciais. Os resultados do teste de Szondi revelam um desequilíbrio profundo da personalidade e de suas possibilidades de relacionar-se com outros, sendo que estas dificuldades afetam os dois sexos de maneira diferente. Ambos os grupos em cura de desintoxicação apresentam numerosos sintomas psicopatológicos, consequências prováveis tanto do consumo de tóxicos como de desestruturações anteriores. O terceiro grupo (toxicômanos encarcerados apresenta conflitos que parecem ser mais diretamente sociais do que familiares ou psicológicos. Nos outros grupos, as dificuldades de estruturação psíquica e de integração psicossocial parecem ser devidas à problemática familiar.

  19. Biologia de ninfas e adultos do percevejo-verde em estruturas reprodutivas de algodoeiro

    Directory of Open Access Journals (Sweden)

    Rosalia Azambuja

    2014-06-01

    Full Text Available O objetivo deste trabalho foi determinar a biologia de ninfas e adultos do percevejo-verde em estruturas reprodutivas do algodoeiro. Os alimentos testados foram: dieta padrão, contendo vagem de feijão, amendoim cru e frutos de ligustro; vagem verde de soja; semente de soja; botão floral de algodoeiro; e maçãs e sementes de algodoeiro. Foram avaliados os parâmetros biológicos: período de desenvolvimento e sobrevivência ninfal; longevidade de fêmeas e machos; percentagem de fêmeas em oviposição; períodos de pré-oviposição e oviposição; número total de ovos por fêmea; e viabilidade dos ovos. Ninfas alimentadas com estruturas reprodutivas do algodoeiro morreram no segundo ou no terceiro ínstar. Adultos alimentados com botão floral e semente de algodoeiro não se reproduzem; porém, há reprodução quando adultos os de percevejo-verde são alimentados com maçã de algodoeiro, o que indica a capacidade de adaptação da espécie na fase reprodutiva do algodoeiro.

  20. A estrutura em psicanálise: uma enunciação desde Freud

    Directory of Open Access Journals (Sweden)

    Glória Sadala

    2011-12-01

    Full Text Available Pretende-se abordar a importância da noção de estrutura no campo psicanalítico, considerando sua pertinência nas formulações freudianas e seus destinos no percurso teórico de Lacan. O termo estrutura encontra-se implícito na obra de Freud no que tange à importância do diagnóstico diferencial. Lacan se propôs a reler Freud a partir do estruturalismo a fim de reconduzir a experiência psicanalítica à fala e à linguagem. Ressaltaremos duas divergências que marcam o afastamento incondicional de Lacan do movimento estruturalista: a concepção do sujeito e o registro do real.The structure in psychoanalysis: an enunciation since Freud. This article intends to approach the importance of the notion of structure in the psychoanalytic field, considering its relevance in Freudian formulations and its destinations in the theoretical trajectory of Lacan. The term structure is implicit in the work of Freud in terms of the importance of differential diagnosis. Lacan's proposal was to re-read Freud from structuralism to reconduct the psychoanalytic experience to speech and language. We emphasize two disagreements that mark the unconditional withdrawal of Lacan's structuralist movement: the conception of the subject and the register of the real.

  1. Estrutura e organização espacial de duas comunidades de anuros do bioma Pampa

    Directory of Open Access Journals (Sweden)

    Victor M. Lipinski

    2014-12-01

    Full Text Available O Pampa é o menor bioma brasileiro e está entre os mais ameaçados devido ao rápido avanço das culturas agropastoris e da silvicultura; é um dos biomas com menor representação no sistema de unidades de conservação. Neste estudo são apresentadas informações sobre a estrutura e a organização espacial das comunidades de anuros de duas das quatro regiões fisiográficas em que o bioma é dividido. Foram amostrados dez corpos d’água em cada região entre os meses de setembro de 2011 e agosto de 2012. Foram registradas 24 espécies caracterizadas como generalistas, de ampla distribuição e típicas de ambientes abertos. A curva de acumulação de espécies apresentou a formação de uma assíntota após o 12° mês de amostragem. A análise de similaridade mostrou uma segregação na estrutura das duas comunidades, que foram influenciadas pelos descritores ambientais e da paisagem.

  2. Polymer induced condensation of dna supercoils

    NARCIS (Netherlands)

    Bessa Ramos Jr., J.E.; Ruggiero Neto, J.; Vries, de R.J.

    2008-01-01

    Macromolecular crowding is thought to be a significant factor driving DNA condensation in prokaryotic cells. Whereas DNA in prokaryotes is supercoiled, studies on crowding-induced DNA condensation have so far focused on linear DNA. Here we compare DNA condensation by poly(ethylene oxide) for superco

  3. Condensed matter analogues of cosmology

    Science.gov (United States)

    Kibble, Tom; Srivastava, Ajit

    2013-10-01

    It is always exciting when developments in one branch of physics turn out to have relevance in a quite different branch. It would be hard to find two branches farther apart in terms of energy scales than early-universe cosmology and low-temperature condensed matter physics. Nevertheless ideas about the formation of topological defects during rapid phase transitions that originated in the context of the very early universe have proved remarkably fruitful when applied to a variety of condensed matter systems. The mathematical frameworks for describing these systems can be very similar. This interconnection has led to a deeper understanding of the phenomena in condensed matter systems utilizing ideas from cosmology. At the same time, one can view these condensed matter analogues as providing, at least in a limited sense, experimental access to the phenomena of the early universe for which no direct probe is possible. As this special issue well illustrates, this remains a dynamic and exciting field. The basic idea is that when a system goes through a rapid symmetry-breaking phase transition from a symmetric phase into one with spontaneously broken symmetry, the order parameter may make different choices in different regions, creating domains that when they meet can trap defects. The scale of those domains, and hence the density of defects, is constrained by the rate at which the system goes through the transition and the speed with which order parameter information propagates. This is what has come to be known as the Kibble-Zurek mechanism. The resultant scaling laws have now been tested in a considerable variety of different systems. The earliest experiments illustrating the analogy between cosmology and condensed matter were in liquid crystals, in particular on the isotropic-to-nematic transition, primarily because it is very easy to induce the phase transition (typically at room temperature) and to image precisely what is going on. This field remains one of the

  4. Estrutura espacial urbana e mobilidade: o caso da Região Metropolitana de São Paulo

    OpenAIRE

    Sabrina Harris Agostini

    2015-01-01

    A metrópole de São Paulo é a maior e mais importante aglomeração urbana do Brasil e está entre as dez maiores áreas urbanas do mundo. No entanto, a forma como acessibilidade espacial ocorre gera um fardo para a população e para a atividade econômica. Este trabalho pretende contribuir para a discussão de como melhorar a acessibilidade na Região Metropolitana de São Paulo estudando as características e impactos de estruturas espaciais urbana, analisando criticamente a estrutura espacial da metr...

  5. Estrutura de capital : teoria da agência, teoria da sinalização e teoria do controle

    OpenAIRE

    Carnaúba, Wilson Matias

    2010-01-01

    Trata da discussão teórica sobre estrutura de capital das empresas tratando das teorias tradicionais que concentraram o debate, bem como da teoria da agência, sinalização e controle cujo desenvolvimento é mais recente. O tema é abordado mostrando a evolução da empresa, evidenciando onde se enquadra a questão da estrutura de capital. Também mostra os testes emp1ricos utilizados na sustentação das teorias

  6. O diagnóstico em psicanálise: do fenômeno à estrutura

    OpenAIRE

    2000-01-01

    Este artigo desenvolve a questão do diagnóstico em psicanálise a partir de estudos feitos na pesquisa sobre o tema. Inicialmente, aborda-se a própria concepção de pesquisa em psicanálise e, a seguir, situa-se o conceito de estrutura, tal como formulado por Lacan, no cerne da discussão. Finalmente, apresenta-se a construção de um caso clínico para melhor localizar a relação entre fenômeno e estrutura.

  7. O gênero textual na EJA : configuração contextual e estrutura potencial de gênero

    OpenAIRE

    Rocha, Sônia Margarida Ribeiro Guedes da

    2011-01-01

    Esta dissertação é o resultado de uma pesquisa realizada com as quatro turmas do 2º segmento da Educação de Jovens e Adultos (EJA) com o objetivo de (i) mapear os gêneros textuais estudados em aulas de Língua Portuguesa, (ii) definir as Configurações Contextuais (CC) e as Estruturas Potenciais de Gênero (EPG), (iii) estabelecer as estruturas esquemáticas das EPGs de cada texto trabalhado nesse segmento da educação, durante três meses de aula e (iv) discutir, a partir da abordagem de gênero te...

  8. ESTRUTURA POPULACIONAL, BIOLOGIA REPRODUTIVA E ECOLOGIA ALIMENTAR DE Loricariichthys melanocheilus REIS & PEREIRA, 2000 (SILURIFORMES, LORICARIIDAE) NO RIO IBICUÍ, RS, BRASIL.

    OpenAIRE

    Éverton Luís Zardo

    2014-01-01

    O objetivo do presente trabalho foi avaliar aspectos da estrutura populacional, biologia reprodutiva e ecologia alimentar de Loricariichthys melanocheilus no rio Ibicuí. Os peixes foram coletados bimestralmente em ambientes lênticos e lóticos no rio Ibicuí, entre os municípios de São Vicente do Sul e Itaqui, utilizando redes de espera e feiticeiras, com revisão a cada seis horas no período de 24 horas. A estrutura populacional foi avaliada através da distribuição sazonal e espacial, das varia...

  9. Polymer Bose–Einstein condensates

    Energy Technology Data Exchange (ETDEWEB)

    Castellanos, E., E-mail: ecastellanos@fis.cinvestav.mx [Departamento de Física, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional, A.P. 14-740, México D.F. 07000 (Mexico); Chacón-Acosta, G., E-mail: gchacon@correo.cua.uam.mx [Departamento de Matemáticas Aplicadas y Sistemas, Universidad Autónoma Metropolitana-Cuajimalpa, Artificios 40, México D.F. 01120 (Mexico)

    2013-05-13

    In this work we analyze a non-interacting one-dimensional polymer Bose–Einstein condensate in a harmonic trap within the semiclassical approximation. We use an effective Hamiltonian coming from the polymer quantization that arises in loop quantum gravity. We calculate the number of particles in order to obtain the critical temperature. The Bose–Einstein functions are replaced by series, whose high order terms are related to powers of the polymer length. It is shown that the condensation temperature presents a shift respect to the standard case, for small values of the polymer scale. In typical experimental conditions, it is possible to establish a bound for λ{sup 2} up to ≲10{sup −16} m{sup 2}. To improve this bound we should decrease the frequency of the trap and also decrease the number of particles.

  10. Fundamentals of condensed matter physics

    CERN Document Server

    Cohen, Marvin L

    2016-01-01

    Based on an established course and covering the fundamentals, central areas, and contemporary topics of this diverse field, Fundamentals of Condensed Matter Physics is a much-needed textbook for graduate students. The book begins with an introduction to the modern conceptual models of a solid from the points of view of interacting atoms and elementary excitations. It then provides students with a thorough grounding in electronic structure as a starting point to understand many properties of condensed matter systems - electronic, structural, vibrational, thermal, optical, transport, magnetic and superconductivity - and methods to calculate them. Taking readers through the concepts and techniques, the text gives both theoretically and experimentally inclined students the knowledge needed for research and teaching careers in this field. It features 200 illustrations, 40 worked examples and 150 homework problems for students to test their understanding. Solutions to the problems for instructors are available at w...

  11. Advances in condensed matter optics

    CERN Document Server

    Chen, Liangyao; Jiang, Xunya; Jin, Kuijuan; Liu, Hui; Zhao, Haibin

    2015-01-01

    This book describes some of the more recent progresses and developmentsin the study of condensed matter optics in both theoretic and experimental fields.It will help readers, especially graduate students and scientists who are studying and working in the nano-photonic field, to understand more deeply the characteristics of light waves propagated in nano-structure-based materials with potential applications in the future.

  12. Atomistic modeling of dropwise condensation

    Science.gov (United States)

    Sikarwar, B. S.; Singh, P. L.; Muralidhar, K.; Khandekar, S.

    2016-05-01

    The basic aim of the atomistic modeling of condensation of water is to determine the size of the stable cluster and connect phenomena occurring at atomic scale to the macroscale. In this paper, a population balance model is described in terms of the rate equations to obtain the number density distribution of the resulting clusters. The residence time is taken to be large enough so that sufficient time is available for all the adatoms existing in vapor-phase to loose their latent heat and get condensed. The simulation assumes clusters of a given size to be formed from clusters of smaller sizes, but not by the disintegration of the larger clusters. The largest stable cluster size in the number density distribution is taken to be representative of the minimum drop radius formed in a dropwise condensation process. A numerical confirmation of this result against predictions based on a thermodynamic model has been obtained. Results show that the number density distribution is sensitive to the surface diffusion coefficient and the rate of vapor flux impinging on the substrate. The minimum drop radius increases with the diffusion coefficient and the impinging vapor flux; however, the dependence is weak. The minimum drop radius predicted from thermodynamic considerations matches the prediction of the cluster model, though the former does not take into account the effect of the surface properties on the nucleation phenomena. For a chemically passive surface, the diffusion coefficient and the residence time are dependent on the surface texture via the coefficient of friction. Thus, physical texturing provides a means of changing, within limits, the minimum drop radius. The study reveals that surface texturing at the scale of the minimum drop radius does not provide controllability of the macro-scale dropwise condensation at large timescales when a dynamic steady-state is reached.

  13. Radiative corrections to Bose condensation

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, A. (Academia de Ciencias de Cuba, La Habana. Inst. de Matematica, Cibernetica y Computacion)

    1985-04-01

    The Bose condensation of the scalar field in a theory behaving in the Coleman-Weinberg mode is considered. The effective potential of the model is computed within the semiclassical approximation in a dimensional regularization scheme. Radiative corrections are shown to introduce certain ..mu..-dependent ultraviolet divergences in the effective potential coming from the Many-Particle theory. The weight of radiative corrections in the dynamics of the system is strongly modified by the charge density.

  14. Theory of laminar film condensation

    CERN Document Server

    Fujii, Tetsu

    1991-01-01

    Since the petroleum crisis in the 1970s, a lot of effort to save energy was made in industry, and remarkable achievements have been made. In the research and development concerning thermal energy, however, it was clar­ ified that one of the most important problems was manufacturing con­ densing systems with smaller size and higher performance. To solve this problem we need a method which synthesizes selections_ of the type of con­ denser, cooling tube and its arrangement, assessment of fouling on the cooling surfaces, consideration of transient characteristics of a condenser, etc. The majority of effort, however, has been to devise a surface element which enhances the heat transfer coefficient in condensation of a single or multicomponent vapor. Condensation phenomena are complexly affected by a lot of physical property values, and accordingly the results of theo­ retical research are expressed with several dimensionless parameters. On the other hand, the experimental research is limited to those with som...

  15. Condensation on Slippery Asymmetric Bumps

    Science.gov (United States)

    Park, Kyoo-Chul; Kim, Philseok; Aizenberg, Joanna

    2016-11-01

    Controlling dropwise condensation by designing surfaces that enable droplets to grow rapidly and be shed as quickly as possible is fundamental to water harvesting systems, thermal power generation, distillation towers, etc. However, cutting-edge approaches based on micro/nanoscale textures suffer from intrinsic trade-offs that make it difficult to optimize both growth and transport at once. Here we present a conceptually different design approach based on principles derived from Namib desert beetles, cacti, and pitcher plants that synergistically couples both aspects of condensation and outperforms other synthetic surfaces. Inspired by an unconventional interpretation of the role of the beetle's bump geometry in promoting condensation, we show how to maximize vapor diffusion flux at the apex of convex millimetric bumps by optimizing curvature and shape. Integrating this apex geometry with a widening slope analogous to cactus spines couples rapid drop growth with fast directional transport, by creating a free energy profile that drives the drop down the slope. This coupling is further enhanced by a slippery, pitcher plant-inspired coating that facilitates feedback between coalescence-driven growth and capillary-driven motion. We further observe an unprecedented six-fold higher exponent in growth rate and much faster shedding time compared to other surfaces. We envision that our fundamental understanding and rational design strategy can be applied to a wide range of phase change applications.

  16. Quality factors to consider in condensate selection

    Energy Technology Data Exchange (ETDEWEB)

    Lywood, B. [Crude Quality Inc., Edmonton, AB (Canada)

    2009-07-01

    Many factors must be considered when assessing the feasibility of using condensates as a diluent for bitumen or heavy crude production blending. In addition to commercial issues, the effect of condensate quality is a key consideration. In general, condensate quality refers to density and viscosity. However, valuation decisions could be enhanced through the expansion of quality definitions and understanding. This presentation focused on the parameters that are important in choosing a diluent grade product. It also reviewed pipeline and industry specifications and provided additional information regarding general properties for bitumen and condensate compatibility; sampling and quality testing needs; and existing sources of information regarding condensate quality. tabs., figs.

  17. Condensate from a two-stage gasifier

    DEFF Research Database (Denmark)

    Bentzen, Jens Dall; Henriksen, Ulrik Birk; Hindsgaul, Claus

    2000-01-01

    that the organic compounds and the inhibition effect are very low even before treatment with activated carbon. The moderate inhibition effect relates to a high content of ammonia in the condensate. The nitrifiers become tolerant to the condensate after a few weeks of exposure. The level of organic compounds......Condensate, produced when gas from downdraft biomass gasifier is cooled, contains organic compounds that inhibit nitrifiers. Treatment with activated carbon removes most of the organics and makes the condensate far less inhibitory. The condensate from an optimised two-stage gasifier is so clean...

  18. Estrutura nuclear e competição entre modos de decaimento de ressonancia gigantes

    OpenAIRE

    Carlos Augusto P. Ceneviva

    1997-01-01

    Resumo: A estrutura dos níveis de mais baixa energia para isótopos ímpares de Pb (193A205) é investigada no contexto da aproximação de BCS projetada (PBCS) com uma- e três- quase-partículas. Uma interação do tipo delta de superficie (SDI) foi utilizada como interação residual. Energias de excitação, fatores espectroscópicos e momentos de dipolo magnético e quadrupolo elétrico foram calculados e comparados com valores experimentais. Para isótopos ímpares de Te (115A131), os cálculos das energi...

  19. Algoritmos evolutivos para predição de estruturas de proteínas

    OpenAIRE

    Telma Woerle de Lima

    2006-01-01

    A Determinação da Estrutura tridimensional de Proteínas (DEP) a partir da sua seqüência de aminoácidos é importante para a engenharia de proteínas e o desenvolvimento de novos fármacos. Uma alternativa para este problema tem sido a aplicação de técnicas de computação evolutiva. As abordagens utilizando Algoritmos Evolutivos (AEs) tem obtido resultados relevantes, porém estão restritas a pequenas proteínas, com dezenas de aminoácidos e a algumas classes de proteínas. Este trabalho propõe a inv...

  20. Estudo analítico da estrutura organizacional do Senado Federal no ano 2001

    OpenAIRE

    2001-01-01

    o presente trabalho pretende responder à questão da adequação ou não da atual estrutura organizacional do Senado Federal frente às novas exigências decorrentes da promulgação da Constituição de 1988 e da mudança de parâmetros e valores trazida pelo paradigma emergente na Administração Pública a partir de 1990. O estudo se propõe a correlacionar de modo analítico quais são as funções de uma Casa legislativa com o órgão técnico responsável por sua realização, priorizando valores ...

  1. Distribuição exata para estrutura de simetria composta do tipo II

    OpenAIRE

    1984-01-01

    Resumo: Neste trabalho, utilizando as transformadas direta e inversa de Mellin e com a aplicação do teorema dos resíduos, determinamos a distribuição exata do critério de Wilks para o teste de hipótese de estrutura de siimetria composta do tipo II para a matriz de covariâncias de uma população normal multivariada de t covariáveis (t = nh, onde h é o número de características medidas na população de interesse e n>2 é o número de vezes em que estas características são medidas ao longo do tempo)...

  2. Controle adaptativo por modelo de referencia e estrutura variável discreto no tempo

    OpenAIRE

    Jacome, Isael Calistrato

    2013-01-01

    Com o avanco da tecnologia, sistemas embarcados utilizando técnicas adaptativas estão sendo utilizados com mais frequencia. Uma dessas técnicas é o Controlador adaptativo por Modelo de Referencia e Estrutura Variavel (VS-MRAC). A implementação dessa técnica em sistemas embarcados, requer a consideração de um período de amostragem que se não for levado em consideração, pode afetar de maneira negativa a performance do sistema e até mesmo levá-lo a instabilizacao. Este trabalho propõe uma anális...

  3. Modelagem de sensores e atuadores piezeletricos com aplicações em controle ativo de estruturas

    OpenAIRE

    1999-01-01

    Resumo: Apresenta-se uma metodologia para a modelagem analítica e numérica de estruturas, com elementos piezelétricos incorporados. Obtêm-se modelos analíticos de placa de Kirchhoff e Mindlin-Reissner e de viga de Euler-Bemoulli e Timoshenko, a partir das equações de movimento de casca, com a aplicação dos Postulados de Love e da escolha apropriada dos raios de curvaturas e dos Parâmetros de Lamé. Em seguida, são consideradas, nos modelos, as influências do elemento piezelétrico. O princípio ...

  4. O campo dos economistas franceses no fim dos anos 90: lutas de fronteira, autonomia e estrutura

    Directory of Open Access Journals (Sweden)

    Frédéric Lebaron

    2001-04-01

    Full Text Available A noção de economista, longe de simples e evidente, é objeto de numerosas lutas de definição. O exemplo do campo dos economistas franceses, analisado a partir de um conjunto de entrevistas, observações de dados prosopográficos, revela certas características dessas lutas. Estas opõem detendores de formas diferenciadas de capital, que estão elas mesmas em correspondência com posições distintas no campo do poder. Nessas lutas, estão em questão ao mesmo tempo a autonomia e a estrutura desse campo científico. A fraca autonomia relativa do campo da ciência econômica se faz acompanhar de uma forte homologia entre a estrutura desse campo e aquela do campo do poder francês em seu conjunto.The concept of the economist, rather than being a simple and evident one, is the object of numerous conflicting definitions. The example of the field of French economists, as analysed in a set of interviews and the observation of prospographical data, reveal certain characteristics of these conflicts. These struggles oppose those who detain differentiated forms of capital, which are themselves in correspondence with distinct positions in the field of power. These conflicts put into question both the autonomy and the structure of this scientific field. The relatively weak autonomy of the field of economical sciences is followed by a strong homology between the structure of this field and that of the field of French power in its entirety.

  5. Estrutura organizacional da atencao pos-parto na estrategia saude da familia

    Directory of Open Access Journals (Sweden)

    Daniela do Carmo Oliveira

    2013-09-01

    Full Text Available Objetivou-se descrever atributos da estrutura organizacional da atenção pós-parto na Estratégia Saúde da Família, a partir de quesitos presentes na política de saúde nacional, relativos à infraestrutura, pessoal e a ações assistenciais e de gestão. Estudo quantitativo, descritivo e transversal, realizado em 55 unidades da Estratégia Saúde da Família de Cuiabá, Mato Grosso, mediante entrevista e análise estatística descritiva. A maioria das unidades contempla quesitos de infraestrutura física e de oferta de ações no pós-parto. Há limitações na oferta de consultas de enfermagem, de educação grupal e de anticoncepcional oral de uso no pós-parto. Nem sempre há disponibilidade de material para o preventivo de câncer de colo uterino e de médicos nas unidades. O agendamento da consulta pós-parto não é rotineiro, e dados do sistema de informação não são habitualmente usados no planejamento dessa atenção. É necessário investir na melhoria da estrutura organizacional para que a atenção pós-parto ganhe qualidade.

  6. Estrutura e personalidade na neurose: da metapsicologia do sintoma à narrativa do sofrimento

    Directory of Open Access Journals (Sweden)

    Christian Ingo Lenz Dunker

    2014-04-01

    Full Text Available Neste artigo, originalmente uma aula para concurso de professor titular junto ao Instituto de Psicologia da USP, são examinadas as noções de personalidade e de estrutura em sua aplicação ao diagnóstico de neurose, em psicopatologia de extração psicanalítica. Examina-se a consistência das relações de ordem, classe e gênero, que, por hipótese, ao lado da concepção de causalidade, subsidiam a força e pertinência de uma categoria diagnóstica. Discute-se o valor da exceção e a potência normativa de conformação da experiência clínica à racionalidade diagnóstica. Os resultados deste exame epistemológico preliminar nos levam a propor a tese crítica de que há menos homogeneidade no emprego da noção freudiana de neurose do que a recepção corrente vem admitindo. Argumenta-se que cada modelo metapsicológico, no qual emergem redefinições de neurose, corresponde a uma valência narrativa e uma forma de sofrimento distinto, sendo a exclusão da narrativa de sofrimento uma dimensão relevante para reconsiderar a noção de personalidade e de estrutura na diagnóstica psicanalítica.

  7. Condensation on slippery asymmetric bumps

    Science.gov (United States)

    Park, Kyoo-Chul; Kim, Philseok; Grinthal, Alison; He, Neil; Fox, David; Weaver, James C.; Aizenberg, Joanna

    2016-03-01

    Controlling dropwise condensation is fundamental to water-harvesting systems, desalination, thermal power generation, air conditioning, distillation towers, and numerous other applications. For any of these, it is essential to design surfaces that enable droplets to grow rapidly and to be shed as quickly as possible. However, approaches based on microscale, nanoscale or molecular-scale textures suffer from intrinsic trade-offs that make it difficult to optimize both growth and transport at once. Here we present a conceptually different design approach—based on principles derived from Namib desert beetles, cacti, and pitcher plants—that synergistically combines these aspects of condensation and substantially outperforms other synthetic surfaces. Inspired by an unconventional interpretation of the role of the beetle’s bumpy surface geometry in promoting condensation, and using theoretical modelling, we show how to maximize vapour diffusion fluxat the apex of convex millimetric bumps by optimizing the radius of curvature and cross-sectional shape. Integrating this apex geometry with a widening slope, analogous to cactus spines, directly couples facilitated droplet growth with fast directional transport, by creating a free-energy profile that drives the droplet down the slope before its growth rate can decrease. This coupling is further enhanced by a slippery, pitcher-plant-inspired nanocoating that facilitates feedback between coalescence-driven growth and capillary-driven motion on the way down. Bumps that are rationally designed to integrate these mechanisms are able to grow and transport large droplets even against gravity and overcome the effect of an unfavourable temperature gradient. We further observe an unprecedented sixfold-higher exponent of growth rate, faster onset, higher steady-state turnover rate, and a greater volume of water collected compared to other surfaces. We envision that this fundamental understanding and rational design strategy can be

  8. Quantum tunnelling in condensed media

    CERN Document Server

    Kagan, Yu

    1992-01-01

    The essays in this book deal with of the problem of quantum tunnelling and related behavior of a microscopic or macroscopic system, which interacts strongly with an ""environment"" - this being some form of condensed matter. The ""system"" in question need not be physically distinct from its environment, but could, for example, be one particular degree of freedom on which attention is focussed, as in the case of the Josephson junction studied in several of the papers. This general problem has been studied in many hundreds, if not thousands, of articles in the literature, in contexts as diverse

  9. Velocity condensation for magnetotactic bacteria

    CERN Document Server

    Rupprecht, Jean-Francois; Bocquet, Lydéric

    2015-01-01

    Magnetotactic swimmers tend to align along magnetic field lines against stochastic reorientations. We show that the swimming strategy, e.g. active Brownian motion versus run-and-tumble dynamics, strongly affects the orientation statistics. The latter can exhibit a velocity condensation whereby the alignment probability density diverges. As a consequence, we find that the swimming strategy affects the nature of the phase transition to collective motion, indicating that L\\'evy run-and-tumble walks can outperform active Brownian processes as strategies to trigger collective behavior.

  10. Dropwise Condensation on Hydrophobic Cylinders

    CERN Document Server

    Park, Kyoo-Chul; Hoang, Michelle; McManus, Brendan; Aizenberg, Joanna

    2016-01-01

    In this work, we studied the effect of the diameter of horizontal hydrophobic cylinders on droplet growth. We postulate that the concentration gradient created by natural convection around a horizontal circular cylinder is related to the droplet growth on the cylinder by condensation. We derive a simple scaling law of droplet growth and compare it with experimental results. The predicted negative exponent of drop diameter (d) as a function of cylinder diameter (D) at different time points is similar to the general trend of experimental data. Further, this effect of cylinder diameter on droplet growth is observed to be stronger than the supersaturation conditions created by different surface temperatures.

  11. Avaliação visual da qualidade da estrutura do solo em sistemas de uso das terras

    Directory of Open Access Journals (Sweden)

    Joelcio Eurich

    2014-12-01

    Full Text Available Sistemas sustentáveis de produção agropecuária demandam solos com boa estrutura, por isso, são necessários métodos eficientes para avaliação dessa estrutura. Objetivou-se, com este estudo, aplicar a metodologia de avaliação visual da estrutura do solo, em áreas previamente cobertas por Floresta com Araucária, em longo período de uso após o desmatamento. Selecionaram-se áreas sob três tipos de usos: floresta nativa, pastagem e cultivo agrícola, considerados como tratamento, sendo realizadas dez amostragens por tipo de uso. Nas amostras coletadas, procedeu-se à avaliação da qualidade da estrutura do solo, seguida da análise estatística dos dados, por meio da análise de variância e do teste de separação de médias. Observaram-se diferenças significativas nos valores médios de escore entre as áreas avaliadas. Os solos da área com floresta apresentaram Qe (Qualidade visual médio = 1.68, estatisticamente semelhante ao dos solos sob pastagem (Qe médio = 2.25 e inferior ao dos solos cultivados, Qe médio = 2.40. Os valores de Qe obtidos por avaliação visual da qualidade da estrutura do solo mostraram-se eficientes para identificar diferenças entre os sistemas de uso do solo.

  12. The physics of exciton-polariton condensates

    CERN Document Server

    Lagoudakis, Konstantinos

    2013-01-01

    In 2006 researchers created the first polariton Bose-Einstein condensate at 19K in the solid state. Being inherently open quantum systems, polariton condensates open a window into the unpredictable world of physics beyond the “fifth state of matter”: the limited lifetime of polaritons renders polariton condensates out-of-equilibrium and provides a fertile test-bed for non-equilibrium physics. This book presents an experimental investigation into exciting features arising from this non-equilibrium behavior. Through careful experimentation, the author demonstrates the ability of polaritons to synchronize and create a single energy delocalized condensate. Under certain disorder and excitation conditions the complete opposite case of coexisting spatially overlapping condensates may be observed. The author provides the first demonstration of quantized vortices in polariton condensates and the first observation of fractional vortices with full phase and amplitude characterization. Finally, this book investigate...

  13. Bio-oil fractionation and condensation

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Robert C.; Jones, Samuel T.; Pollard, Anthony

    2017-04-04

    The present invention relates to a method of fractionating bio-oil vapors which involves providing bio-oil vapors comprising bio-oil constituents. The bio-oil vapors are cooled in a first stage which comprises a condenser having passages for the bio-oil separated by a heat conducting wall from passages for a coolant. The coolant in the condenser of the first stage is maintained at a substantially constant temperature, set at a temperature in the range of 75 to 100.degree. C., to condense a first liquid fraction of liquefied bio-oil constituents in the condenser of the first stage. The first liquid fraction of liquified bio-oil constituents from the condenser in the first stage is collected. Also disclosed are steps for subsequently recovering further liquid fractions of liquefied bio-oil constituents. Particular compositions of bio-oil condensation products are also described.

  14. Bio-oil fractionation and condensation

    Science.gov (United States)

    Brown, Robert C; Jones, Samuel T; Pollard, Anthony

    2013-07-02

    A method of fractionating bio-oil vapors which involves providing bio-oil vapors comprising bio-oil constituents is described. The bio-oil vapors are cooled in a first stage which comprises a condenser having passages for the bio-oil separated by a heat conducting wall from passages for a coolant. The coolant in the condenser of the first stage is maintained at a substantially constant temperature, set at a temperature in the range of 75 to 100.degree. C., to condense a first liquid fraction of liquefied bio-oil constituents in the condenser of the first stage. The first liquid fraction of liquified bio-oil constituents from the condenser in the first stage is collected. Also described are steps for subsequently recovering further liquid fractions of liquefied bio-oil constituents. Particular compositions of bio-oil condensation products are also described.

  15. Muonic Chemistry in Condensed Matter

    CERN Multimedia

    2002-01-01

    When polarized muons (@m|+) stop in condensed matter, muonic atoms are formed in the final part of their range, and direct measurements of the @m|+-spin polarization are possible via the asymmetric decay into positrons. The hyperfine interaction determines the characteristic precession frequencies of the @m|+ spin in muonium, @w(Mu). Such frequencies can be altered by the interactions of the muonium's electron spin with the surrounding medium. The measurement of @w(Mu) in a condensed system is known often to provide unique information regarding the system. \\\\ \\\\ In particular, the use of muonium atoms as a light isotope of the simple reactive radical H|0 allows the investigation of fast reactions of radicals over a typical time scale 10|-|9~@$<$~t~@$<$~10|-|5~sec, which is determined by the instrumental resolution at one end and by the @m|+ lifetime at the other. \\\\ \\\\ In biological macromolecules transient radicals, such as the constituents of DNA itself, exist on a time scale of sub-microseconds, acco...

  16. Condensation induced water hammer safety

    Energy Technology Data Exchange (ETDEWEB)

    Gintner, M.A.

    1997-03-10

    Condensation induced water hammer events in piping systems can cause catastrophic steam system failures which can result in equipment damage, personal injury, and even death. As an industry, we have learned to become accustomed to the ''banging'' that we often hear in our steam piping systems, and complacent in our actions to prevent it. It is unfortunate that lives are lost needlessly, as this type of water hammer event is preventable if one only applies some basic principles when operating and maintaining their steam systems. At the U. S. Department of Energy's Hanford Site where I work, there was one such accident that occurred in 1993 which took the life of a former co-worker and friend of mine. Hanford was established as part of the Manhattan Project during World War II. it is a 560 square mile complex located along the banks of the Columbia River in Southeastern Washington State. For almost 45 years, hanford's mission was to produce weapons grade plutonium for our nations defense programs. Today, Hanford no longer produces plutonium, but is focused on site clean-up and economic diversification. Hanford still uses steam for heating and processing activities, utilizing over 20 miles of piping distribution systems similar to those found in industry. Although these aging systems are still sound, they cannot stand up to the extreme pressure pulses developed by a condensation induced water hammer.

  17. DNA condensation in one dimension

    Science.gov (United States)

    Pardatscher, Günther; Bracha, Dan; Daube, Shirley S.; Vonshak, Ohad; Simmel, Friedrich C.; Bar-Ziv, Roy H.

    2016-12-01

    DNA can be programmed to assemble into a variety of shapes and patterns on the nanoscale and can act as a template for hybrid nanostructures such as conducting wires, protein arrays and field-effect transistors. Current DNA nanostructures are typically in the sub-micrometre range, limited by the sequence space and length of the assembled strands. Here we show that on a patterned biochip, DNA chains collapse into one-dimensional (1D) fibres that are 20 nm wide and around 70 µm long, each comprising approximately 35 co-aligned chains at its cross-section. Electron beam writing on a photocleavable monolayer was used to immobilize and pattern the DNA molecules, which condense into 1D bundles in the presence of spermidine. DNA condensation can propagate and split at junctions, cross gaps and create domain walls between counterpropagating fronts. This system is inherently adept at solving probabilistic problems and was used to find the possible paths through a maze and to evaluate stochastic switching circuits. This technique could be used to propagate biological or ionic signals in combination with sequence-specific DNA nanotechnology or for gene expression in cell-free DNA compartments.

  18. Lorentz violation and Condensed Matter Physics

    CERN Document Server

    Ajaib, Muhammad Adeel

    2014-01-01

    We present heuristic arguments that hint to a possible connection of Lorentz violation with observed phenomenon in condensed matter physics. Various references from condensed matter literature are cited where operators in the Standard Model Extension (SME) appear to be enhanced. Based on this we propose that, in the non-relativistic limit, Lorentz violation in the context of the SME exhibits itself in various condensed matter systems.

  19. Van der Waals Interactions and Exciton Condensation

    Science.gov (United States)

    Handel, P. H.; Kittel, C.

    1971-01-01

    It is shown that the van der Waals interaction can lead at low temperatures to a condensed state of excitons with properties in qualitative agreement with the observations of exciton droplets. Our calculation gives a binding energy of the correct sign and magnitude for the exciton condensate. In a diclectric medium, the strong enhancement of the exciton polarizability leads to a giant van der Waals interaction, and this interaction appears to make possible a condensed exciton phase. PMID:16591958

  20. Ultra-low threshold polariton condensation

    CERN Document Server

    Steger, Mark; Alberi, Kirstin; Mascarenhas, Angelo; Snoke, David W; Pfeiffer, Loren N; West, Ken

    2016-01-01

    We demonstrate condensation of microcavity polaritons with a very sharp threshold occuring at two orders of magnitude lower pump intensity than previous demonstrations of condensation. The long cavity-lifetime and trapping and pumping geometries are crucial to the realization of this low threshold. Polariton condensation, or "polariton lasing" has long been proposed as a promising source of coherent light at lower threshold than traditional lasing, and these results suggest methods to bring this threshold even lower.

  1. Structure of Nonlocal Vacuum Condensate of Quarks

    Institute of Scientific and Technical Information of China (English)

    周丽娟; 马维兴

    2003-01-01

    The Dyson-Schwinger formalism is used to derive a fully dressed quark propagator. By use of the derived form of the quark propagator, the structure of non-local quark vacuum condensate is studied, and the values of local quark vacuum condensate as well as quark gluon mixed condensate are calculated. The theoretical predictions are in good agreement with the empirical one used commonly in the literature.

  2. Enhanced condensation heat transfer with wettability patterning

    Science.gov (United States)

    Sinha Mahapatra, Pallab; Ghosh, Aritra; Ganguly, Ranjan; Megaridis, Constantine

    2015-11-01

    Condensation of water vapor on metal surfaces is useful for many engineering applications. A facile and scalable method is proposed for removing condensate from a vertical plate during dropwise condensation (DWC) in the presence of non-condensable gases (NCG). We use wettability-patterned superhydrophilic tracks (filmwise condensing domains) on a mirror-finish (hydrophilic) aluminum surface that promotes DWC. Tapered, horizontal ``collection'' tracks are laid to create a Laplace pressure driven flow, which collects condensate from the mirror-finish domains and sends it to vertical ``drainage tracks'' for gravity-induced shedding. An optimal design is achieved by changing the fractional area of superhydrophilic tracks with respect to the overall plate surface, and augmenting capillary-driven condensate-drainage by adjusting the track spatial layout. The design facilitates pump-less condensate drainage and enhances DWC heat transfer on the mirror-finish regions. The study highlights the relative influences of the promoting and retarding effects of dropwise and filmwise condensation zones on the overall heat transfer improvement on the substrate. The study demonstrated ~ 34% heat transfer improvement on Aluminum surface for the optimized design.

  3. Advances in modelling of condensation phenomena

    Energy Technology Data Exchange (ETDEWEB)

    Liu, W.S.; Zaltsgendler, E. [Ontario Hydro Nuclear, Toronto (Canada); Hanna, B. [Atomic Energy of Canada Limited, Pinawa, Manitoba (Canada)

    1997-07-01

    The physical parameters in the modelling of condensation phenomena in the CANDU reactor system codes are discussed. The experimental programs used for thermal-hydraulic code validation in the Canadian nuclear industry are briefly described. The modelling of vapour generation and in particular condensation plays a key role in modelling of postulated reactor transients. The condensation models adopted in the current state-of-the-art two-fluid CANDU reactor thermal-hydraulic system codes (CATHENA and TUF) are described. As examples of the modelling challenges faced, the simulation of a cold water injection experiment by CATHENA and the simulation of a condensation induced water hammer experiment by TUF are described.

  4. Effects of Composition and Structure of Mg/Al Oxides on Their Activity and Selectivity for the Condensation of Methyl Ketones

    KAUST Repository

    Shylesh, Sankaranarayanapillai

    2016-09-22

    The effects of chemical composition and pretreatment on Mg–Al hydrotalcites and alumina-supported MgO were evaluated for the gas-phase, self-condensation reaction of C3–C5 biomass-derived methyl ketones. We show that the selectivity toward the acyclic dimer enone and the cyclic enone trimer can be tuned by controlling the temperature of hydrotalcite calcination. Methyl ketone cyclization is promoted by Lewis acidic sites present on the hydrotalcite catalysts. XRD and thermal decomposition analysis reveal that the formation of periclase MgO starts above 623 K accompanied by complete disappearance of the hydrotalcite structure and is accompanied by an increase in hydroxyl condensation as the formation of well-crystallized periclase. 27Al MQMAS and 25Mg MAS NMR show that at progressively higher temperatures, Al3+ cations diffuses out of the octahedral brucite layers and incorporate into the tetrahedral and octahedral sites of the MgO matrix thereby creating defects to compensate the excess positive charge generated. The oxygen anions adjacent to the Mg2+/Al3+ defects become coordinatively unsaturated, leading to the formation of new basic sites. A kinetic isotope effect, kH/kD = 0.96, is observed at 473 K for the reaction of (CH3)2CO versus (CD3)2CO, which suggests that carbon–carbon bond formation leading to the dimer aldol product is the rate-determining step in the condensation reaction of methyl ketones. We also show that acid–base catalysts having similar reactivity and higher hydrothermal stability to that of calcined hydrotalcites can be achieved by creating defects in MgO crystallites supported alumina as a consequence of the diffusion of Al3+ cations into MgO. The physical properties of these materials are shown to be very similar to those of hydrotalcite calcined at 823 K.

  5. Efeitos da estrutura da floresta de Terra-Firme no uso de habitat em corujas (Aves, Strigiformes) na Amazônia Central

    OpenAIRE

    Esclarski, Priscilla

    2014-01-01

    As corujas, apesar atuarem na regulação de presas e controle biológico, representam um grupo ainda pouco estudado quanto à distribuição e abundância, principalmente as espécies neotropicais. Os componentes da estrutura da floresta têm sido usados para explicar padrões de uso de habitat e a estrutura de comunidades, porém, os estudos relacionando tais componentes às corujas concentram-se em espécies do hemisfério norte. O presente estudo analisou se os componentes de estrutura da floresta infl...

  6. The mean condensate heat resistance of dropwise condensation with flowing inert gases

    NARCIS (Netherlands)

    Geld, van der C.W.M.; Brouwers, H.J.H.

    1995-01-01

    The quantification of the condensate heat resistance is studied for dropwise condensation from flowing air-steam mixtures. Flows are essentially laminar and stable with gas Reynolds numbers around 900 and 2000. The condensate shaping up as hemispheres on a plastic plane wall and the presence of iner

  7. Sistemas de estacionamento vertical modulado em estrutura metálica

    Directory of Open Access Journals (Sweden)

    Ezequiel Mendonça Rezende

    2006-09-01

    Full Text Available Um dos maiores problemas das grandes cidades está relacionado ao envelhecimento dos centros urbanos associado à falência de toda a estrutura viária para receber um sistema de trânsito cada vez mais conturbado. Em função de toda essa situação, vêm sendo implementadas políticas públicas no sentido de revitalizar os centros urbanos. Concomitantemente, vem ocorrendo uma procura de melhoria nos transportes coletivos. Assim, espera-se resolver parte desse quadro de problemas, o qual vem sendo intensificado com a questão da falta de vagas para o estacionamente de veículos nos referidos centros urbanos. Surge, dessa forma, um novo enfoque para a questão dos estacionamentos, sendo, então, criadas novas propostas para a solução de tal problema. Para a criação de novos espaços de estacionamento nessas regiões centrais, é necessário buscar soluções criativas que adotem um aumento da densidade de armazenamento de veículos em determinados locais. Uma das possibilidades é a implantação de edifícios modulados em estrutura metálica, totalmente automatizados, que consistem, praticamente, em simples estruturas, sem a necessidade do uso de lajes para pisos, ou mesmo, de elementos de fechamentos. Como exemplo desses edifícios modulados, podemos citar os galpões de armazenamento de grandes atacadistas existentes no Brasil. Esses edifícios, por suas próprias características, não permitem o acesso do usuário ao seu interior, já que os veículos são conduzidos por equipamentos totalmente robotizados.One of the greatest problems of a big city is associated with the aging of urban downtown centers and the failure of the traffic structure to support a traffic system that becomes more and more chaotic every day. While a growth of public policies which encourage downtown revitalization and the improvement of mass transportation should help revert part of this scenario, ironically it aggravates the already complex parking problem in

  8. Condensation on Slippery Asymmetric Bumps

    CERN Document Server

    Park, Kyoo-Chul; He, Neil; Aizenberg, Joanna

    2015-01-01

    Bumps are omnipresent from human skin to the geological structures on planets, which offer distinct advantages in numerous phenomena including structural color, drag reduction, and extreme wettability. Although the topographical parameters of bumps such as radius of curvature of convex regions significantly influence various phenomena including anti-reflective structures and contact time of impacting droplets, the effect of the detailed bump topography on growth and transport of condensates have not been clearly understood. Inspired by the millimetric bumps of the Namib Desert beetle, here we report the identified role of radius of curvature and width of bumps with homogeneous surface wettability in growth rate, coalescence and transport of water droplets. Further rational design of asymmetric convex topography and synergetic combination with slippery coating simultaneously enable self-transport, leading to unseen five-fold higher growth rate and an order of magnitude faster shedding time of droplets compared...

  9. Statistical physics and condensed matter

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    This document is divided into 4 sections: 1) General aspects of statistical physics. The themes include: possible geometrical structures of thermodynamics, the thermodynamical foundation of quantum measurement, transport phenomena (kinetic theory, hydrodynamics and turbulence) and out of equilibrium systems (stochastic dynamics and turbulence). The techniques involved here are typical of applied analysis: stability criteria, mode decomposition, shocks and stochastic equations. 2) Disordered, glassy and granular systems: statics and dynamics. The complexity of the systems can be studied through the structure of their phase space. The geometry of this phase space is studied in several works: the overlap distribution can now be computed with a very high precision; the boundary energy between low lying states does not behave like in ordinary systems; and the Edward's hypothesis of equi-probability of low lying metastable states is invalidated. The phenomenon of aging, characteristic of glassy dynamics, is studied in several models. Dynamics of biological systems or of fracture is shown to bear some resemblance with that of disordered systems. 3) Quantum systems. The themes include: mesoscopic superconductors, supersymmetric approach to strongly correlated electrons, quantum criticality and heavy fermion compounds, optical sum rule violation in the cuprates, heat capacity of lattice spin models from high-temperature series expansion, Lieb-Schultz-Mattis theorem in dimension larger than one, quantum Hall effect, Bose-Einstein condensation and multiple-spin exchange model on the triangular lattice. 4) Soft condensed matter and biological systems. Path integral representations are invaluable to describe polymers, proteins and self-avoiding membranes. Using these methods, problems as diverse as the titration of a weak poly-acid by a strong base, the denaturation transition of DNA or bridge-hopping in conducting polymers have been addressed. The problems of RNA folding

  10. Condensed Matter Theories - Volume 22

    Science.gov (United States)

    Reinholz, Heidi; Röpke, Gerd; de Llano, Manuel

    2007-09-01

    pt. A. Fermi liquids. Pressure comparison between the spherical cellular model and the Thomas-Fermi model / G.A. Baker, Jr. Pair excitations and vertex corrections in Fermi fluids and the dynamic structure function of two-dimension 3He / H.M. Böhm, H. Godfrin, E. Krotscheck, H.J. Lauter, M. Meschke and M. Panholzer. Condensation of helium in wedges / E.S. Hernádez ... [et al.]. Non-Fermi liquid behavior from the Fermi-liquid approach / V.A. Khodel ... [et al.]. Theory of third sound and stability of thin 3He-4He superfluid films / E. Krotscheck and M.D. Miller. Pairing in asymmetrical Fermi systems / K.F. Quader and R. Liao. Ground-state properties of small 3He drops from quantum Monte Carlo simulations / E. Sola, J. Casulleras and J. Boronat. Ground-state energy and compressibility of a disordered two-dimensional electron gas / Tanatar ... [et al.]. Quasiexcitons in photoluminescence of incompressible quantum liquids / A. Wójs, A.G ladysiewicz and J.J. Quinn -- pt. B. Bose liquids. Quantum Boltzmann liquids / K.A. Gernoth, M L. Ristig and T. Lindenau. Condensate fraction in the dynamic structure function of Bose fluids / M. Saarela, F. Mazzanti and V. Apaja -- pt. C. Strongly-correlated electronic systems. Electron gas in high-field nanoscopic transport: metallic carbon nanotubes / F. Green and D. Neilson. Evolution and destruction of the Kondo effect in a capacitively coupled double dot system / D.E. Logan and M.R. Galpin. The method of increments-a wavefunction-based Ab-Initio correlation method for solids / B. Paulus. Fractionally charged excitations on frustrated lattices / E. Runge, F. Pollmann and P. Fulde. 5f Electrons in actinides: dual nature and photoemission spectra / G. Zwicknagl -- pt. D. Magnetism. Magnetism in disordered two-dimensional Kondo-Necklace / W. Brenig. On the de Haas-can Alphen oscillation in 2D / S. Fujita and D.L. Morabito. Dynamics in one-dimensional spin systems-density matrix reformalization group study / S. Nishimoto and M

  11. Assessment of the controllability of condensible emissions. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Shareef, G.S.; Waddell, J.T.

    1990-10-01

    The report gives results of a study to gain insights into the condensible emissions area from an air toxics perspective, with emphasis on controllability and chemical composition of these emissions. The study: compiled existing data on condensible emissions; determined the chemical composition of condensible emissions, where possible; identified source categories that are major emitters of condensibles; evaluated the effectiveness of various control devices in reducing condensible emissions; and evaluated how the performance of currently available control technologies can be improved to better control condensible emissions. Two data bases were developed: the Condensibles Data Base contains 43 emission source categories; the Specialized Condensibles Data Base focuses on the chemical composition of condensible emissions.

  12. ESTRUTURA DE MADEIRA PARA COBERTURA DE AVIÁRIOS NO ESTADO DA PARAÍBA

    Directory of Open Access Journals (Sweden)

    Marluce Araújo de Azevedo

    1999-12-01

    Full Text Available RESUMO Este trabalho apresenta o cálculo estrutural de cobertura com treliça do tipo "Howe", utilizando-se as madeiras roxinho ( Peltogyne sp., Leguminosae e maçaranduba ( Manilkara sp., Sapotaceae disponíveis no mercado de Campina Grande, Paraíba, e visa a execução de projeto de estrutura para aviário, considerando-se as recomendações da norma técnica brasileira NBR 7190/1997 e duas situações de galpão: aviário com oitões em alvenaria e ventilação artificial e aviário com oitões abertos e túnel de vento no sentido longitudinal, ambas com 12 m de vão e 125 m de comprimento. Devido à globalização da economia, a escolha do projeto arquitetônico se deu em função do tipo de exploração, dos parâmetros de conforto térmico, manejo, custo e uso racional da madeira. Os resultados obtidos indicam que a estrutura formada por treliça composta de banzos com seções transversais simples de 7,5 x 12,5 cm, diagonais com seções transversais simples de 7,5 x 10,0 cm e montantes com seções transversais duplas de 3,5 x 12,5 cm, terças com seções transversais de 7,5 x 15 cm, contraventamento tendo seção transversal de 7,5 x 12,5 cm e espaçamento entre treliças de 2,72 m, apresenta o menor consumo de madeira por metro quadrado de área coberta e, conseqüentemente, o menor custo.

  13. Estrutura urbana e atividade tecnológica em Minas Gerais

    Directory of Open Access Journals (Sweden)

    Eduardo Gonçalves

    2006-12-01

    Full Text Available Este trabalho utiliza uma base de dados de patentes do Instituto Nacional de Propriedade Industrial (INPI, com o objetivo de preencher algumas lacunas na literatura sobre o tema que relaciona inovação e desenvolvimento regional em Minas Gerais. Estes objetivos são os seguintes: 1 identificar os principais fatores determinantes da inovação nos municípios mineiros a partir dos fatores considerados relevantes pela literatura internacional; 2 determinar a relação que existe entre a estrutura urbana do Estado e a inovação; 3 revelar padrões de associação espaciais e identificar agrupamentos espaciais significativos de produção tecnológica; 4 verificar se ocorrem transbordamentos tecnológicos intermunicipais. O trabalho constatou que a atividade tecnológica é concentrada espacialmente, e tende a ocorrer principalmente ao redor da área metropolitana de Belo Horizonte. A estrutura urbana do Estado é, em parte, causadora desta distribuição espacial da atividade tecnológica, porque a maior parte das cidades não possui escala urbana e requisitos exigidos pela inovação.This paper uses a database of patent applications from the Brazilian Patent Office (INPI to throw some light on the relationship between innovation and regional development in the state of Minas Gerais. The objectives are described as follows: 1 to identify the main determinants of innovation in the municipalities of Minas Gerais considering the variables emphasized by the international literature; 2 to determine the relation existing between the urban structure of the state of Minas Gerais and its innovative performance; 3 to reveal the patterns of spatial associations and to identify significant spatial clustering of technological activity; 4 to verify the occurrence of interregional knowledge spillovers. The results showed that the innovative activity is spatially concentrated and presents a major tendency to take place around the metropolitan area of Belo

  14. Bose-Einstein condensation of atomic hydrogen

    NARCIS (Netherlands)

    Willmann, L

    1999-01-01

    The recent creation of a Bose-Einstein condensate of atomic hydrogen has added a new system to this exciting field, The differences between hydrogen and the alkali metal atoms require other techniques for the initial trapping and cooling of the atoms and the subsequent detection of the condensate. T

  15. Phase contrast imaging of Bose condensed clouds

    NARCIS (Netherlands)

    Meppelink, R; Rozendaal, R.A.; Koller, S.B.; Vogels, J.M.; van der Straten, P.

    2010-01-01

    Phase contrast imaging is used to observe Bose-Einstein condensates (BECs) at finite temperature in situ. The imaging technique is used to accurately derive the absolute phase shift of a probe laser beam due to both the condensate and the thermal cloud. The accuracy of the method is enhanced by usin

  16. ASSESSMENT OF THE CONTROLLABILITY OF CONDENSIBLE EMISSIONS

    Science.gov (United States)

    The report gives results of a study to gain insights into the condensible emissions area from an air toxics perspective, with emphasis on controllability and chemical composition of these emissions. he study compiled existing data on condensible emissions; determined the chemical...

  17. Soliton resonance in bose-einstein condensate

    Science.gov (United States)

    Zak, Michail; Kulikov, I.

    2002-01-01

    A new phenomenon in nonlinear dispersive systems, including a Bose-Einstein Condensate (BEC), has been described. It is based upon a resonance between an externally induced soliton and 'eigen-solitons' of the homogeneous cubic Schrodinger equation. There have been shown that a moving source of positive /negative potential induces bright /dark solitons in an attractive / repulsive Bose condensate.

  18. Hydrophilic structures for condensation management in appliances

    Science.gov (United States)

    Kuehl, Steven John; Vonderhaar, John J.; Wu, Guolian; Wu, Mianxue

    2016-02-02

    An appliance that includes a cabinet having an exterior surface; a refrigeration compartment located within the cabinet; and a hydrophilic structure disposed on the exterior surface. The hydrophilic structure is configured to spread condensation. The appliance further includes a wicking structure located in proximity to the hydrophilic structure, and the wicking structure is configured to receive the condensation.

  19. When does lasing become a condensation phenomenon?

    CERN Document Server

    Fischer, Baruch

    2012-01-01

    We present a generic classical light condensation (LC) phenomenon in linear photonic mode systems, such as cw laser cavities, in a noisy environment (spontaneous emission, etc.), based on weighting the modes in a loss-gain scale rather than in photon energy. It is characterized by a sharp transition from multi- to single-mode oscillation. The study uses a linear multivariate Langevin formulation which gives a mode occupation hierarchy that functions like Bose-Einstein statistics. We find that condensation occurs when the spectral filtering has near the lowest loss mode a power law dependence with exponent smaller than 1. We then discuss how and when condensation occurs in photon systems, how it relates to lasing, and the difficulties to observe regular photon Bose-Einstein condensation (BEC) in laser cavities. We raise the possibility that recent experiments on photon condensation in optical cavities fall in a classical LC or lasing category rather than being a thermal-quantum BEC phenomenon.

  20. Gravitino condensation, supersymmetry breaking and inflation

    CERN Document Server

    Houston, N

    2015-01-01

    Motivated by dualistic considerations of the reality of quark condensation in quantum chromodynamics, and the connections of supergravity to the exotic physics of string and M-theory, in this thesis we investigate the dynamical breaking of local supersymmetry via gravitino condensation. We firstly demonstrate non-perturbative gravitino mass generation via this mechanism in flat spacetime, and from this derive the condensate mode wavefunction renormalisation. By then calculating the full canonically normalised one-loop effective potential for the condensate mode about a de Sitter background, we demonstrate that, contrary to claims in the literature, this process may both occur and function in a phenomenologically viable manner. In particular, we find that outside of certain unfortunate gauge choices, the stability of the condensate is intimately tied via gravitational degrees of freedom to the sign of the tree-level cosmological constant. Furthermore, we find that the energy density liberated may provide the n...

  1. Tecnologia de estruturas EBG - electromagnetic band-gap - aplicada a antenas para comunicações moveis

    OpenAIRE

    Alexandre Manoel Pereira Alves da Silva

    2004-01-01

    Resumo: Este trabalho descreve a aplicação da tecnologia de estruturas EBG, Electromagnetic BandGap, em antenas para sistemas de comunicações móveis. Essa tecnologia pode ser adotada nos diversos sistemas de comunicações móveis de 3G e 4G; em ERBs (Estações Rádio-Base), picoERBs e terminais móveis; em padrões como WLAN, Wi-Fi, Bluetooth, WiMAX (IEEE802.16), entre outros. São projetadas, simuladas e analisadas, estruturas EBG com configurações de célu Ias quadradas e hexagonais, com um e dois ...

  2. Análise da estrutura temática em artigos audiovisuais de pesquisa de biologia

    Directory of Open Access Journals (Sweden)

    Victor Gomes Milani

    2016-12-01

    Full Text Available O presente estudo busca descrever a estrutura temática de Artigos Audiovisuais de Pesquisa (APP da área de biologia publicados no Journal of Visualized Experiments (JoVE partindo da metafunção Textual (HALLIDAY & MATTHIESSEN, 2014. Os exemplares selecionados foram transcritos, a fim de se identificar a estrutura Tema e Rema. Após a identificação, os padrões temáticos foram contabilizados e interpretados com base em Halliday e Metthiessen (2014 e Thompson (2004. Verificou-se que a metafunção Textual contribui para natureza instrucional dos AAP ao posicionar Processos e Circunstâncias como as escolhas temáticas mais recorrentes, corroborando com estudos prévios (SOUZA, 2015; SILVA, 2015a; 2015b; MILANI, 2014.

  3. Estrutura e processo assistencial de enfermagem ao paciente com câncer

    Directory of Open Access Journals (Sweden)

    Nilce Piva Adami

    1997-12-01

    Full Text Available Esta pesquisa objetivou avaliar a estrutura para o atendimento ao paciente com câncer e o processo asssistencial em quimioterapia antineoplásica. Foi realizada em seis unidades de internação e uma ambulatorial de um hospital universitário, utilizando-se a observação sistematizada e entrevista semi-estruturada, no período de janeiro a junho de 1996. Constatou-se que existem deficiências na área física e instalações das unidades estudadas. O pessoal de enfermagem, de modo geral, não possui preparo formal em Oncologia, com exceção do Setor de Quimioterapia. Verificou-se falta de sistematização da assistência de enfermagem e diferenças entre as unidades estudadas no que tange aos aspectos técnico-organizacionais da administração de antineoplásicos, bem como na interação entre profissionais e pacientes atendidos. As inadequações observadas poderiam ser minimizadas com uma política que contemple o aumento do financiamento do setor público da saúde, a implantação da sistematização da assistência e a inclusão da Oncologia na educação permanente do pessoal de enfermagem.

  4. Estrutura fatorial do inventário multifatorial de Coping para adolescentes (IMCA-43

    Directory of Open Access Journals (Sweden)

    Balbinotti, Marcos Alencar Abaide

    2006-01-01

    Full Text Available O inventário multifatorial de Coping para Adolescentes (IMCA-43 foi originalmente elaborado por Antoniazzi (2000 e as suas qualidades psicométricas avaliadas para uma população de 15 a 30 anos. Este trabalho replica este estudo e utiliza uma amostra de 285 adolescentes (132 masculinos e 153 femininos com idades variando de 13 a 18 anos. A análise dos dados foi feita por meio da análise fatorial exploratória e da consistência interna de dados. A solução final apresentou três fatores (Ações Diretas, Apoio Social e Negação dos quatro que compõe o IMCA. O quarto fator (autocontrole foi reduzido a outro, denominado Ações Agressivas. Todos os fatores apresentaram índices de consistência interna satisfatórios. Os resultados demonstraram que a replicação do IMCA-43, apresentou uma estrutura fatorial relativamente estável. Entretanto, novos estudos são necessários para refinamento do instrumento

  5. As instituições entre as estruturas e as ações

    Directory of Open Access Journals (Sweden)

    Théret Bruno

    2003-01-01

    Full Text Available Considerando-se as instituições como mediações entre estruturas e comportamentos individuais, sustenta-se que é possível encontrar, tanto em Ciência Política como em Economia e Sociologia, um mesmo desenvolvimento básico do institucionalismo, dividido em três grandes correntes, cada uma com sua própria genealogia. Na teoria econômica francesa essas três correntes correspondem à teoria da regulação, à nova economia institucional e à economia das convenções. Basicamente os novos institucionalismos se diferenciam a partir de duas grandes oposições: 1 o peso que atribuem na gênese das instituições aos conflitos de interesse e de poder ou à coordenação entre indivíduos; 2 o papel que atribuem à racionalidade estritamente instrumental, ou então às representações e à cultura.

  6. Estrutura eletrônica de isolantes topológicos em duas e três dimensões

    OpenAIRE

    Leandro Seixas Rocha

    2014-01-01

    Nessa tese de doutorado apresentamos um estudo da estrutura eletronica de materiais isolantes topologicos. A teoria fundamental dos isolantes topologicos foi abordada atraves de invariantes topologicos Z2, assim como os seus metodos para o calculo desses invariantes topologicos e as consequencias da topologia de bandas nao-trivial. Assim como as propriedades atomisticas e energeticas, as propriedades eletronicas de alguns isolantes topologicos foram calculadas atraves de metodos de primeiros ...

  7. A INFLUÃNCIA DA ESTRUTURA ORGANIZACIONAL NA EXECUÃÃO DOS PROCESSOS DE MANUTENÃÃO

    Directory of Open Access Journals (Sweden)

    Gustavo A. C. Guzman

    2003-12-01

    Full Text Available No contexto atual de competitividade, uma eficiência maior dos processos executados pelo departamento de manutenção é um dos fatores que contribui paRI o aumento de produtividade das empresas. Diferentes autores têm reconhecido a importância da estrutura organizacional do departamento de manutençào no seu desempenho. Entretanto, esses autores não detalham a influência da estrutura organizacional para a adequada execução dos processos de manutenção. Este artigo descreve um trabalho cujo objetivo foi procurar entender como a estrutura organizacional influência os processos do departamento de manutenção de urna empresa. Para isso foram realizados uma vasta pesquisa bibliográfica relativa ao gerenciamento de manutenção e à teoria sobre análise organizacional, além de um estudo de caso numa empresa de grande porte. O trabalho apresentado neste artigo serve como piloto e base para estudos futuros. As conclusões, se confirmadas em pesquisas posteriores, poderão subsidiar acomplementação da teoria existente.

  8. Governança em estruturas proprietárias concentradas: novas evidências para o Brasil

    Directory of Open Access Journals (Sweden)

    Igor Bernardi Sonza

    2014-06-01

    Full Text Available Neste artigo, o objetivo é analisar a influência da estrutura de propriedade na eficiência das empresas de capital aberto brasileiras, em que é identificada maior concentração de ações nas mãos de um grupo restrito de pessoas. No estudo, unem-se técnicas de otimização estática por meio de análise envoltória de dados, para identificar a eficiência das empresas de capital aberto, com dados em painel, para identificar a influência da estrutura de propriedade na eficiência das empresas, buscando agregar governança corporativa à literatura de eficiência produtiva no contexto de diferenças institucionais no ambiente brasileiro, a fim de complementar os estudos prévios que consideram somente os outputs como medidas de eficiência. Nos resultados obtidos, mostra-se que a estrutura de propriedade influencia negativamente a eficiência, contrariando grande parte dos estudos baseados no modelo norte-americano e evidenciando que as peculiaridades dos países devem ser levadas em consideração, principalmente com relação à sua origem legal.

  9. Mineralogia da fração argila e estrutura de latossolos da região sudeste do Brasil

    Directory of Open Access Journals (Sweden)

    M. M. Ferreira

    1999-09-01

    Full Text Available Este trabalho objetivou estudar a relação entre os constituintes mineralógicos da fração argila e o desenvolvimento da micro e macroestrutura de Latossolos do sudeste brasileiro. Para tanto, foram obtidas amostras do horizonte B de sete Latossolos, representativos deste grupamento, ocorrentes nos estados de Minas Gerais e Espírito Santo. As diferentes amostras foram submetidas à caracterização morfológica, química, física, mineralógica e micromorfológica. A partir dos diferentes resultados, foi possível concluir que caulinita e gibbsita são os principais constituintes mineralógicos responsáveis pelo desenvolvimento da estrutura dos Latossolos estudados. Latossolos cauliníticos apresentam estrutura em blocos, reflexo do ajuste face a face das placas de caulinita, enquanto os gibbsíticos apresentam estrutura granular, reflexo da ausência daquele ajuste.

  10. Enhancing dropwise condensation through bioinspired wettability patterning.

    Science.gov (United States)

    Ghosh, Aritra; Beaini, Sara; Zhang, Bong June; Ganguly, Ranjan; Megaridis, Constantine M

    2014-11-01

    Dropwise condensation (DWC) heat transfer depends strongly on the maximum diameter (Dmax) of condensate droplets departing from the condenser surface. This study presents a facile technique implemented to gain control of Dmax in DWC within vapor/air atmospheres. We demonstrate how this approach can enhance the corresponding heat transfer rate by harnessing the capillary forces in the removal of the condensate from the surface. We examine various hydrophilic-superhydrophilic patterns, which, respectively, sustain and combine DWC and filmwise condensation on the substrate. The material system uses laser-patterned masking and chemical etching to achieve the desired wettability contrast and does not employ any hydrophobizing agent. By applying alternating straight parallel strips of hydrophilic (contact angle ∼78°) mirror-finish aluminum and superhydrophilic regions (etched aluminum) on the condensing surface, we show that the average maximum droplet size on the less-wettable domains is nearly 42% of the width of the corresponding strips. An overall improvement in the condensate collection rate, up to 19% (as compared to the control case of DWC on mirror-finish aluminum) was achieved by using an interdigitated superhydrophilic track pattern (on the mirror-finish hydrophilic surface) inspired by the vein network of plant leaves. The bioinspired interdigitated pattern is found to outperform the straight hydrophilic-superhydrophilic pattern design, particularly under higher humidity conditions in the presence of noncondensable gases (NCG), a condition that is more challenging for maintaining sustained DWC.

  11. Dynamics of condensation on lubricant impregnated surfaces

    Science.gov (United States)

    Anand, Sushant; Paxson, Adam; Rykaczewski, Konrad; Beysens, Daniel; Varanasi, Kripa

    2013-03-01

    Replacing the filmwise condensation mode with dropwise condensation promises large improvements in heat transfer that will lead to large cost savings in material, water consumption and decreased size of the systems. In this regards, use of superhydrophobic surfaces fabricated by texturing surfaces with nano/microstructures has been shown to lead decrease in contact line pinning of millimetric drops resulting in fast shedding. However, these useful properties are lost during condensation where droplets that nucleate within texture grow by virtue of condensation to large sized droplets while still adhering to the surface. Recently we have shown that liquid impregnated surfaces can overcome many limitations of conventional superhydrophobic surfaces during condensation. Here we discuss aspects related to condensation on lubricant surfaces, such as behavior of growing droplets. We compare the characteristics of droplets condensing on these surfaces with their behavior on conventional un-impregnated superhydrophobic surfaces and show how use of lubricant impregnated surfaces may lead to large enhancement in heat transfer and energy efficiencies.

  12. Dispensing fuel with aspiration of condensed vapors

    Energy Technology Data Exchange (ETDEWEB)

    Butkovich, M.S.; Strock, D.J.

    1993-08-10

    A vapor recovery process is described, comprising the steps of: fueling a motor vehicle with gasoline by discharging gasoline into a fill opening or filler pipe of a tank of said vehicle through a fuel outlet conduit of a nozzle; emitting gasoline vapors from said tank during said fueling; substantially collecting said vapors during said fueling with a vapor return conduit of said nozzle and passing said vapors through said vapor return conduit in counter current flow relationship to said discharging gasoline in said fuel conduit; conveying said vapors from said vapor return conduit to a vapor return hose; at least some of said vapors condensing to form condensate in said vapor return hose; substantially removing said condensate from said vapor return hose during said fueling with a condensate pickup tube from said nozzle by passing said condensate through said condensate pickup tube in counter current flow relationship to said conveying vapors in said vapor return hose; sensing the presence of gasoline with a liquid sensing tube in said vapor return conduit of said nozzle between inner and outer spouts of said nozzle to detect when said tank of said vehicle is filled with said fuel conduit being within the inner spout of said nozzle; and automatically shutting off said fueling and condensate removing when said liquid sensing tube detects when said tank of said vehicle is filled and fuel enters said vapor return conduit.

  13. Direct contact condensation in packed beds

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yi; Klausner, James F.; Mei, Renwei; Knight, Jessica [Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, FL 32611 (United States)

    2006-12-15

    A diffusion driven desalination process was recently described where a very effective direct contact condenser with a packed bed is used to condense water vapor out of an air/vapor mixture. A laboratory scale direct contact condenser has been fabricated as a twin tower structure with two stages, co-current and countercurrent. Experiments have been operated in each stage with respective saturated air inlet temperatures of 36, 40 and 43{sup o}C. The temperature and humidity data have been collected at the inlet and exit of the packed bed for different water to air mass flow ratios that vary between 0 and 2.5. A one-dimensional model based on conservation principles has been developed, which predicts the variation of temperature, humidity, and condensation rate through the condenser stages. Agreement between the model and experiments is very good. It is observed that the countercurrent flow stage condensation effectiveness is significantly higher than that for the co-current stage. The condensation heat and mass transfer rates were found to decrease when water blockages occur within the packed bed. Using high-speed digital cinematography, it was observed that this problem can occur at any operating condition, and is dependent on the packing surface wetting characteristics. This observation is used to explain the requirement for two different empirical constants, depending on packing diameter, suggested by Onda for the air side mass transfer coefficient correlation. (author)

  14. Silicate condensation in Mira variables

    CERN Document Server

    Gail, Hans-Peter; Pucci, Annemarie

    2016-01-01

    We study whether the condensation of silicate dust in Mira envelopes could be caused by cluster formation by the abundant SiO molecules. For a simplified model of the pulsational motions of matter in the the outer layers of a Mira variable which is guided by a numerical model for Mira pulsations, the equations of dust nucleation and growth are solved in the co-moving frame of a fixed mass element. It is assumed that seed particles form by clustering of SiO molecules. The calculation of the nucleation rate is based on the experimental data of Nuth and Donn (1982). The quantity of dust formed is calculated by a moment method and the calculation of radiation pressure on the dusty gas is based on a dirty silicate model. Dust nucleation occurs in the model at the upper culmination of the trajectory of a gas parcel where it stays for a considerable time at low temperatures while subsequent dust growth occurs during the descending part of the motion and continues after the next shock reversed motion. It is found tha...

  15. Stellar matter with pseudoscalar condensates

    Energy Technology Data Exchange (ETDEWEB)

    Andrianov, A.A. [Saint-Petersburg State University, St. Petersburg (Russian Federation); Universitat de Barcelona, Departament d' Estructura i Constituents de la Materia and Institut de Ciencies del Cosmos (ICCUB), Barcelona, Catalonia (Spain); Andrianov, V.A.; Kolevatov, S.S. [Saint-Petersburg State University, St. Petersburg (Russian Federation); Espriu, D. [Universitat de Barcelona, Departament d' Estructura i Constituents de la Materia and Institut de Ciencies del Cosmos (ICCUB), Barcelona, Catalonia (Spain)

    2016-03-15

    In this work we consider how the appearance of gradients of pseudoscalar condensates in dense systems may possibly influence the transport properties of photons in such a medium as well as other thermodynamic characteristics. We adopt the hypothesis that in regions where the pseudoscalar density gradient is large the properties of photons and fermions are governed by the usual lagrangian extended with a Chern-Simons interaction for photons and a constant axial field for fermions. We find that these new pieces in the lagrangian produce non-trivial reflection coefficients both for photons and fermions when entering or leaving a region where the pseudoscalar has a non-zero gradient. A varying pseudoscalar density may also lead to instability of some fermion and boson modes and modify some properties of the Fermi sea. We speculate that some of these modifications could influence the cooling rate of stellar matter (for instance in compact stars) and have other observable consequences. While quantitative results may depend on the precise astrophysical details most of the consequences are quite universal and consideration should be given to this possibility. (orig.)

  16. Estrutura e estratégia: evolução de paradigmas Structure and strategy: evolution of paradigms

    Directory of Open Access Journals (Sweden)

    Fernando Carvalho de Almeida

    2006-06-01

    Full Text Available O presente trabalho analisa as relações de interdependência existentes entre a estrutura da empresa e as estratégias a serem implementadas. É feita uma breve revisão da literatura sobre estratégia, administração estratégica e as diversas formas de conduzir a implementação das que se apresentam como as mais adequadas à consecução dos objetivos organizacionais. Foram analisados os modelos tradicionais de estrutura organizacional, bem como as vantagens e desvantagens estratégicas que cada um apresenta. Por fim, foram estudadas as abordagens de diferentes autores sobre as relações de interdependência entre a estrutura da empresa e as suas estratégias. Em conclusão, verifica-se que, embora as estratégias da empresa possam ser fixadas a partir da análise da sua estrutura organizacional, dos seus pontos fortes e fracos, esta atitude nem sempre é viável. Numa época em que as tecnologias evoluem de forma extremamente rápida e a competitividade se acelera em nível global, tornam-se necessárias estruturas organizacionais flexíveis, que possam modificar-se rapidamente, para atender às estratégias capazes de permitir a adequada inserção da empresa em um ambiente externo extremamente volátil.The interdependent relations that exist between the structure of an organization and the organizational strategies to be implemented were analyzed. A review was made of literature on strategy, strategic management and methods of implementing strategies appropriate for organization objectives. Traditional models of organization structures were then analyzed as well as the inherent strategic advantages and disadvantages. Then the approach of various authors to these interdependent relations was studied. It was concluded that although organizational strategy can be established by analyzing organization structure as well as the strong and weak aspects involved, this is not always feasible. With fast paced technologies and sharpening global

  17. Microscopic theory of equilibrium polariton condensates

    Science.gov (United States)

    Xue, Fei; Wu, Fengcheng; Xie, Ming; Su, Jung-Jung; MacDonald, A. H.

    2016-12-01

    We present a microscopic theory of the equilibrium polariton condensate state of a semiconductor quantum well in a planar optical cavity. The theory accounts for the adjustment of matter excitations to the presence of a coherent photon field, predicts effective polariton-polariton interaction strengths that are weaker and condensate exciton fractions that are smaller than in the commonly employed exciton-photon model, and yields effective Rabi coupling strengths that depend on the detuning of the cavity-photon energy relative to the bare exciton energy. The dressed quasiparticle bands that appear naturally in the theory provide a mechanism for electrical manipulation of polariton condensates.

  18. Dropwise condensation dynamics in humid air

    Science.gov (United States)

    Castillo Chacon, Julian Eduardo

    Dropwise condensation of atmospheric water vapor is important in multiple practical engineering applications. The roles of environmental factors and surface morphology/chemistry on the condensation dynamics need to be better understood to enable efficient water-harvesting, dehumidication, and other psychrometric processes. Systems and surfaces that promote faster condensation rates and self-shedding of condensate droplets could lead to improved mass transfer rates and higher water yields in harvesting applications. The thesis presents the design and construction of an experimental facility that allows visualization of the condensation process as a function of relative humidity. Dropwise condensation experiments are performed on a vertically oriented, hydrophobic surface at a controlled relative humidity and surface subcooling temperature. The distribution and growth of water droplets are monitored across the surface at different relative humidities (45%, 50%, 55%, and 70%) at a constant surface subcooling temperature of 15 °C below the ambient temperature. The droplet growth dynamics exhibits a strong dependency on relative humidity in the early stages during which there is a large population of small droplets on the surface and single droplet growth dominates over coalescence effects. At later stages, the dynamics of droplet growth is insensitive to relative humidity due to the dominance of coalescence effects. The overall volumetric rate of condensation on the surface is also assessed as a function of time and ambient relative humidity. Low relative humidity conditions not only slow the absolute rate of condensation, but also prolong an initial transient regime over which the condensation rate remains significantly below the steady-state value. The current state-of-the-art in dropwise condensation research indicates the need for systematic experimental investigations as a function of relative humidity. The improved understanding of the relative humidity

  19. The Dynamics of Aerosols in Condensational Scrubbers

    DEFF Research Database (Denmark)

    Johannessen, Jens Tue; Christensen, Jan A.; Simonsen, Ole;

    1997-01-01

    A mathematical model for the simulation of the dynamics of aerosol change in condensational scrubbers and scrubbing condensers is proposed. The model is applicable for packed column gas/liquid contact when plug flow can be assumed. The model is compared with experimental data for particle removal...... in a pilot plant condensational scrubber. The model can satisfactorily predict particle growth and particle deposition by diffusional, convective and inertial mechanisms for a wide range of conditions. The parameters of principal importance for the model precision are identified and a procedure...

  20. Quark Virtuality and QCD Vacuum Condensates

    Institute of Scientific and Technical Information of China (English)

    ZHOU Li-Juan; MA Wei-Xing

    2004-01-01

    @@ Based on the Dyson-Schwinger equations (DSEs) in the ‘rainbow' approximation, we investigate the quark virtuality in the vacuum state and quantum-chromodynamics (QCD) vacuum condensates. In particular, we calculate the local quark vacuum condensate and quark-gluon mixed condensates, and then the virtuality of quark. The calculated quark virtualities are λ2u,d = 0.7 GeV2 for u, d quarks, and 2s 1.6 GeV2 for s quark.Our theoretical predictions are consistent with empirical values used in QCD sum rules, and also fit to lattice QCD predictions.

  1. Holographic Duality in Condensed Matter Physics

    Science.gov (United States)

    Zaanen, Jan; Liu, Yan; Sun, Ya-Wen; Schalm, Koenraad

    2015-11-01

    Preface; 1. Introduction; 2. Condensed matter: the charted territory; 3. Condensed matter: the challenges; 4. Large N field theories for holography and condensed matter; 5. The AdS/CFT correspondence as computational device: the dictionary; 6. Finite temperature magic: black holes and holographic thermodynamics; 7. Holographic hydrodynamics; 8. Finite density: the Reissner-Nordström black hole and strange metals; 9. Holographic photoemission and the RN metal: the fermions as probes; 10. Holographic superconductivity; 11. Holographic Fermi liquids; 12. Breaking translational invariance; 13. AdS/CMT from the top down; 14. Outlook: holography and quantum matter; References; Index.

  2. Pool boiling and condensation analysis for a vertical tube bundle condenser

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, W.; Wolf, B., E-mail: zhouw@purdue.edu [Purdue Univ., West Lafayette, Indiana (United States); Revankar, S.T., E-mail: shripad@ecn.purdue.edu [Purdue Univ., West Lafayette, Indiana (United States); POSTECH, Pohang (Korea, Republic of)

    2011-07-01

    An experimental and theoretical study is performed for the steam condensation in a vertical tube bundle passive condenser simulating PCCS condenser in the ESBWR. Four condenser tubes are submerged in a water pool where the heat from the condenser tube is removed through boiling heat transfer. Condenser tubes with a full length/diameter scale are used to obtain the condensation data with various process parameters. The comparison of tube bundle experimental data with the single tube data by both the experiments and models shows that the single tube secondary heat transfer coefficient (HTC) is between 25% - 35% less than what was recorded for the tube bundle, and the tube bundle condensation rates are slightly higher than the data from the single tube test sections due to turbulent mixing effect which increases the condensation heat removal. The turbulent mixing on the secondary side decreases the DT between pool water and condenser tube outer wall, causing an increase in secondary HTC. This increase in secondary HTC thus results in higher condensate mass flow rates. Tube bundle boundary layer model and heat and mass analogy model were then developed for the prediction of the filmwise steam condensation with noncondensable (NC) gas in a vertical tube bundle. The predictions from the models are compared with the experimental data for various complete condensation and through flow conditions and the agreement is satisfactory. The local parameters predicted by the boundary layer model and heat and mass analogy model with tube bundle pool boiling can also be predicted with the axial distance from entrance for different NC gas fractions and system pressures. (author)

  3. A estrutura de capital da micro e pequena empresa de Blumenau

    Directory of Open Access Journals (Sweden)

    Iara Regina dos Santos Parisotto

    2005-03-01

    Full Text Available O crescimento das micro e pequenas empresas na economia brasileira é indiscutível; um fator que preocupa, no entanto, é o alto nível de mortalidade dessas empresas. No ano de 2004, o SEBRAE apontou em pesquisa realizada, que 42% dos empresários responderam, como causas das dificuldades e razões para o fechamento das empresas, a falta de capital de giro. Tal fato motivou a realização dessa pesquisa, cujo objetivo foi de verificar como é formada a estrutura de capital da micro e pequena empresa blumenauense. Para atingir-se o objetivo proposto, foi realizada uma pesquisa descritiva, e os procedimentos foram: levantamento de dados, por meio de pesquisa de campo, bem como documental e bibliográfica. A amostra selecionada foi de 68 de um total de 76.258 micros e pequenas empresas blumenauenses (fonte: JUCESC, Florianópolis - SC, usando-se fórmula estatística de população finita, com 90% de confiança e 70% de desvio padrão. Os questionários foram aplicados pessoalmente. As conclusões foram que, na maioria das empresas pesquisadas, não está presente a visão de estrutura de capital. Os empresários atuam de acordo com as possibilidades, no momento dos acontecimentos dos fatos, utilizando os recursos que têm com maior disponibilidade e facilidade de captação, o que nem sempre se mostra a melhor opção. As empresas pesquisadas mostram que os recursos de capital de giro são provenientes, em 46,7% dos casos, de capital de terceiros a uma taxa média de 3,4%, quando poderiam pagar para captar recursos para investimentos uma taxa média de 1,9%.The growth of micro and small businesses in the Brazilian economy is unquestionable.However, worrying factor is the high leveI of mortality rate of these businesses. lnthe year of 2004, SEBRAE (Brazilian Support Service to Micro and Small Businessespresented the resu/t of survey in which 42% of the entrepreneurs pointed the lack ofworking capital as the cause of difficu/ties and c/osing down

  4. Estrutura e significado em "Uma rosa para Emily", de William Faulkner

    Directory of Open Access Journals (Sweden)

    Carlos Daghlian

    2004-01-01

    Full Text Available Trata-se de uma análise do consagrado conto "Uma Rosa para Emily", de William Faulkner, voltada para alguns dos principais aspectos de sua estrutura. Após considerarmos o enredo, discutimos a construção das personagens, com destaque para a protagonista, fazendo um levantamento e comentários sobre possíveis fontes de inspiração, destacando, entre outras, aspectos da biografia da poeta Emily Dickinson, a ficção e a poesia de E. A. Poe, romances de Charles Dickens e Henry James, o conto de Sherwood Anderson e a poesia de William Blake, Emily Dickinson, Robert Browning e John Crowe Ransom, acrescentando paralelos com o conto "Bartleby, o escrivão", de Herman Melville. Analisamos, então, o foco narrativo, os símbolos e o significado, ressaltando aqui o desenvolvimento temático da narrativa.This is an analysis of the well-known short story "A Rose for Emily," by William Faulkner, concentrating on some of the main aspects of its structure. A consideration of the plot is followed by a discussion of characterization, with emphasis on the protagonist, by means of a survey and comments on possible sources of inspiration including, among others, aspects of Emily Dickinson's biography, E. A. Poe's fiction and poetry, novels by Charles Dickens and Henry James, Sherwood Anderson's short stories, and the poetry of William Blake, Emily Dickinson, Robert Browning, and John Crowe Ransom, in addition to Herman Melville's short story "Bartleby, the Scrivener." The narrative focus, symbolism and meaning, stressing the thematic development of the narrative, are then analyzed.

  5. Fatores determinantes da estrutura de capital das empresas de materiais básicos do Brasil

    Directory of Open Access Journals (Sweden)

    David Ferreira Lopes Santos

    2014-09-01

    Full Text Available Este artigo examina a estrutura de capital de oito empresas representativas do Índice de Materiais Básicos da BM&FBOVESPA no período de 1994 a 2011. A controvérsia existente nas bases teóricas desenvolvidas neste tema permite que novas abordagens sejam levantadas com o objetivo de aumentar a compreensão dos fatores que determinam os níveis de endividamento das firmas. Neste estudo optou-se pelo uso de indicadores financeiros que representassem três eixos de interesse (rentabilidade, capacidade de pagamento e geração de caixa na explicação do endividamento de curto e longo prazo. A abordagem metodológica foi quantitativa, por meio da análise de regressão com dados em painel. A expectativa inicial é que os resultados encontrassem aderência nas premissas da Pecking Order Theory. Em que pese às restrições metodológicas, observou-se que as variáveis de liquidez corrente, ROA e ROE determinam o endividamento de longo e curto prazo, sendo este último, também influenciado pelas variáveis de ciclo financeiro e giro do ativo. Todavia, o grau de influência da rentabilidade é distinto para as variáveis dependentes, o que denota a existência de conflitos de agência entre credores e acionistas e a preferência pelo uso de fontes internas no financiamento dos ativos.

  6. Comportamento espectral de materiais de solos e de estruturas biogênicas associadas

    Directory of Open Access Journals (Sweden)

    J. A. M. Demattê

    1998-12-01

    Full Text Available No presente estudo, verificou-se a interferência da macrofauna edáfica sobre os atributos físicos e químicos e sua relação com a reflectância espectral de um Latossolo Vermelho-Amarelo (LV, Terra Roxa Estruturada latossólica (TR e Vertissolo (V. Esses solos localizam-se em três pontos ao longo de uma toposseqüência da região de Piracicaba (SP. As amostras foram direcionadas para os agregados formados pelas formigas cortadeiras (Atta sp., cupins (Cornitermes cumulans e minhocas (Pontoscolex corethrurus, os quais foram comparados com o solo-controle sem atividade visível e recente dos animais (testemunha. Foram avaliadas a granulometria e a composição química das amostras de solo. O comportamento espectral do solo foi obtido em laboratório, utilizando espectroradiômetro entre 400 e 2.500 nm. Os coprólitos de minhoca apresentaram 2 a 3 vezes mais fósforo e um incremento de 30 a 50% na matéria orgânica em relação ao horizonte superficial do solo. Os agregados de cupins e formigas apresentaram composição química semelhante à dos horizontes subsuperficiais dos solos. O comportamento espectral dos agregados biológicos variou conforme sua composição química e profundidade de ação dos animais. No caso da minhoca, as curvas de reflectância foram semelhantes às do horizonte superficial para os três solos. Para as estruturas de cupim e formiga, tanto a composição química como o comportamento espectral corresponderam ao horizonte subsuperficial no LV e TR.

  7. As atitudes políticas na Espanha, segundo uma estrutura dimensional indutiva

    Directory of Open Access Journals (Sweden)

    Araceli Mateos Díaz

    2004-05-01

    Full Text Available O artigo analisa as atitudes e percepções políticas dos espanhóis como constitutivas de sua cultura política, apontando o papel das atitudes políticas como um elemento necessário ao estabelecimento e consolidação da democracia no país. Apesar de concordar com a definição de Almond e Verba (1965 de que as atitudes políticas são englobadas pela cultura política, a autora apresenta uma crítica à sua classificação que divide as orientações em cognitivas, afetivas e avaliadoras e propõe que a distribuição das orientações não pode ser predeterminada, mas provém justamente da inter-relação entre elas. Em seguida, a autora propõe a construção de um modelo que distribua e agrupe os indicadores atitudinais diferentes dimensões. Embora as dimensões encontradas aproximem-se da classificação apresentada por Almond e Verba para a explicação do comportamento político, elas resultam de uma estrutura dimensional indutiva.The article considers attitudes and perceptions in Spain as aspects of the political culture, affirming the control role of the democratic political attitudes in the process of democratic consolidation. Although the author agrees to Almond and Verba (1965 definition that political culture includes political attitudes, the discusses their classification, which separates political orientations and political attitudes. She argues that distribution of orientations cannot be predetermined, and that results of their interrelations. The author presents a model of distribution and grouping the attitudinal indicators in different dimensions. The model resulted in a inductive dimensional schema.

  8. Estrutura, ultraestrutura e morfometria da veia cava de paca (Cuniculus paca Linnaeus, 1766 criada em cativeiro

    Directory of Open Access Journals (Sweden)

    Sérgio Pinter Garcia Filho

    2013-05-01

    Full Text Available A paca (Cuniculus paca é o segundo maior roedor da fauna brasileira. Apresenta carne de excelente qualidade, o que incentiva a criação comercial. Além disso, este animal pode tornar-se uma opção válida em experimentação embora poucas sejam as informações detalhadas sobre sua morfologia. Assim, objetivou-se descrever a morfologia, morfometria e ultraestrutura de segmentos das porções cranial e caudal da veia cava de quatro pacas (Cuniculus paca adultas excedentes do plantel do Setor de Animais Silvestres do Departamento de Zootecnia da FCAV-Unesp. Os segmentos venosos foram analisados à microscopia de luz e à microscopia eletrônica de varredura. Foram mensuradas as espessuras do complexo formado pelas túnicas íntima e média, além da túnica adventícia e analisou-se os resultados pela estatística descritiva, teste "T" pareado (p<0,05. Em relação à espessura das túnicas estudadas, comprovou-se que os valores da espessura das túnicas íntima, média e adventícia, para todos os animais, foram significativamente maiores no segmento cranial. As camadas das paredes dos vasos apresentaram variações entre si quanto à estrutura e espessura, supostamente devido a uma adaptação à exigência funcional.

  9. Dual condensates at finite isospin chemical potential

    CERN Document Server

    Zhang, Zhao

    2015-01-01

    The dual observables as order parameters for center symmetry are tested at finite isospin chemical potential $\\mu_I$ in a Polyakov-loop enhanced chiral model of QCD with physical quark masses. As a counterpart of the dressed Polyakov-loop, the first Fourier moment of pion condensate is introduced for $\\mu_I>{m_\\pi}/{2}$ under the temporal twisted boundary conditions for quarks. We demonstrate that this dual condensate exhibits the similar temperature dependence as the conventional Polyakov-loop. We confirm that its rapid increase with $T$ is driven by the evaporating of pion condensation. On the other hand, the dressed Polyakov-loop shows abnormal thermal behavior, which even decreases with $T$ at low temperatures due to the influence of pion condensate. We thus argue that in QCD the critical temperature extracting from a dual observable may have nothing to do with the quark confinement-deconfinement transition if the quark mass is very small.

  10. Convection in Condensible-rich Atmospheres

    CERN Document Server

    Ding, Feng

    2016-01-01

    Condensible substances are nearly ubiquitous in planetary atmospheres. For the most familiar case-water vapor in Earth's present climate-the condensible gas is dilute, in the sense that its concentration is everywhere small relative to the noncondensible background gases. A wide variety of important planetary climate problems involve nondilute condensible substances. These include planets near or undergoing a water vapor runaway and planets near the outer edge of the conventional habitable zone, for which CO2 is the condensible. Standard representations of convection in climate models rely on several approximations appropriate only to the dilute limit, while nondilute convection differs in fundamental ways from dilute convection. In this paper, a simple parameterization of convection valid in the nondilute as well as dilute limits is derived and used to discuss the basic character of nondilute convection. The energy conservation properties of the scheme are discussed in detail and are verified in radiative-co...

  11. Cold condensation of dust in the ISM

    CERN Document Server

    Rouillé, Gaël; Krasnokutski, Serge A; Krebsz, Melinda; Henning, Thomas

    2015-01-01

    The condensation of complex silicates with pyroxene and olivine composition at conditions prevailing in molecular clouds has been experimentally studied. For this purpose, molecular species comprising refractory elements were forced to accrete on cold substrates representing the cold surfaces of surviving dust grains in the interstellar medium. The efficient formation of amorphous and homogeneous magnesium iron silicates at temperatures of about 12 K has been monitored by IR spectroscopy. The gaseous precursors of such condensation processes in the interstellar medium are formed by erosion of dust grains in supernova shock waves. In the laboratory, we have evaporated glassy silicate dust analogs and embedded the released species in neon ice matrices that have been studied spectroscopically to identify the molecular precursors of the condensing solid silicates. A sound coincidence between the 10 micron band of the interstellar silicates and the 10 micron band of the low-temperature siliceous condensates can be...

  12. Condensate of excitations in moving superfluids

    CERN Document Server

    Kolomeitsev, E E

    2016-01-01

    A possibility of the condensation of excitations with a non-zero momentum in rectilinearly moving and rotating superfluid bosonic and fermionic (with Cooper pairing) media is considered in terms of a phenomenological order-parameter functional at zero and non-zero temperature. The results might be applicable to the description of bosonic systems like superfluid $^4$He, ultracold atomic Bose gases, charged pion and kaon condensates in rotating neutron stars, and various superconducting fermionic systems with pairing, like proton and color-superconducting components in compact stars, metallic superconductors, and neutral fermionic systems with pairing, like the neutron component in compact stars and ultracold atomic Fermi gases. Order parameters of the "mother" condensate in the superfluid and the new condensate of excitations, corresponding energy gains, critical temperatures and critical velocities are found.

  13. Vacuum condensates and `ether-drift' experiments

    OpenAIRE

    Consoli, M.; Pagano, A.; Pappalardo, L.

    2003-01-01

    The idea of a `condensed' vacuum state is generally accepted in modern elementary particle physics. We argue that this should motivate a new generation of precise `ether-drift' experiments with present-day technology.

  14. Recent developments in Bose-Einstein condensation

    Energy Technology Data Exchange (ETDEWEB)

    Kalman, G.

    1997-09-22

    This paper contains viewgraphs on developments on Bose-Einstein condensation. Some topics covered are: strongly coupled coulomb systems; standard response functions of the first and second kind; dynamical mean field theory; quasi localized charge approximation; and the main equations.

  15. Essay: fifty years of condensed matter physics.

    Science.gov (United States)

    Cohen, Marvin L

    2008-12-19

    Since the birth of Physical Review Letters fifty years ago, condensed matter physics has seen considerable growth, and both the journal and the field have flourished during this period. In this essay, I begin with some general comments about condensed matter physics and then give some personal views on the conceptual development of the field and list some highlights. The focus is mostly on theoretical developments.

  16. Experimental simulation of the condensation and metamorphism of seasonal CO2 condensates under martian conditions.

    Science.gov (United States)

    Grisolle, F.; Schmitt, B.; Beck, P.; Philippe, S.; Brissaud, O.

    2014-04-01

    An experimental set-up, CARBON-IR, has been developed in order to perform the condensation and metamorphism of CO2 condensates in various controlled martian conditions at, or out of, equilibrium. The sample texture is monitored and near-infrared reflectance spectra are recorded. We present a first set of experiments aimed to simulate the formation of compact translucent slabs by condensation of CO2 gas, the metamorphism of CO2 snow, as well as their sublimation.

  17. Wettability Patterning for Enhanced Dropwise Condensation

    Science.gov (United States)

    Ghosh, Aritra; Ganguly, Ranjan; Megaridis, Constantine

    2014-11-01

    Dropwise condensation (DwC), in order to be sustainable, requires removal of the condensate droplets. This removal is frequently facilitated by gravity. The rate of DwC heat transfer depends strongly on the maximum departing droplet diameter. Based on wettability patterning, we present a facile technique designed to control the maximum droplet size in DwC within vapor/air atmospheres, and demonstrate how this approach can be used to enhance the corresponding heat transfer rate. We examine various hydrophilic-superhydrophilic patterns, which, respectively sustain DwC and filmwise (FwC) condensation on the substrate. The fabrication method does notemploy any hydrophobizing agent. By juxtaposing parallel lines of hydrophilic (CA ~ 78°) and superhydrophilic (CA ~ 0°) regions on the condensing surface, we create alternating domains of DwC and FwC. The average droplet size on the DwC domain is reduced by ~ 60% compared to the theoretical maximum, which corresponds to the line width. We compare heat transfer rate between unpatternend DwC surfaces and patterned DwC surfaces. Even after sacrificing 40% of condensing area, we achieve up to 20% improvement in condensate collection rate using an interdigitated superhydrophilic pattern, inspired by the vein network of plant leaves. The bioinspired interdigitated pattern is found to outperform the straight hydrophilic-superhydrophilic pattern, particularly under higher vapor loadings in an air/vapor ambient atmosphere. NSF STTR Grant 1331817 via NBD Nano.

  18. Numerical simulation of condensation on structured surfaces.

    Science.gov (United States)

    Fu, Xiaowu; Yao, Zhaohui; Hao, Pengfei

    2014-11-25

    Condensation of liquid droplets on solid surfaces happens widely in nature and industrial processes. This phase-change phenomenon has great effect on the performance of some microfluidic devices. On the basis of micro- and nanotechnology, superhydrophobic structured surfaces can be well-fabricated. In this work, the nucleating and growth of droplets on different structured surfaces are investigated numerically. The dynamic behavior of droplets during the condensation is simulated by the multiphase lattice Boltzmann method (LBM), which has the ability to incorporate the microscopic interactions, including fluid-fluid interaction and fluid-surface interaction. The results by the LBM show that, besides the chemical properties of surfaces, the topography of structures on solid surfaces influences the condensation process. For superhydrophobic surfaces, the spacing and height of microridges have significant influence on the nucleation sites. This mechanism provides an effective way for prevention of wetting on surfaces in engineering applications. Moreover, it suggests a way to prevent ice formation on surfaces caused by the condensation of subcooled water. For hydrophilic surfaces, however, microstructures may be submerged by the liquid films adhering to the surfaces. In this case, microstructures will fail to control the condensation process. Our research provides an optimized way for designing surfaces for condensation in engineering systems.

  19. Condensation of the air-steam mixture in a vertical tube condenser

    Directory of Open Access Journals (Sweden)

    Havlík Jan

    2016-01-01

    Full Text Available This paper deals with the condensation of water vapour in the presence of non-condensable air. Experimental and theoretical solutions of this problem are presented here. A heat exchanger for the condensation of industrial waste steam containing infiltrated air was designed. The condenser consists of a bundle of vertical tubes in which the steam condenses as it flows downwards with cooling water flowing outside the tubes in the opposite direction. Experiments with pure steam and with mixtures of steam with added air were carried out to find the dependence of the condensation heat transfer coefficient (HTC on the air concentration in the steam mixture. The experimental results were compared with the theoretical formulas describing the cases. The theoretical determination of the HTC is based on the Nusselt model of steam condensation on a vertical wall, where the analogy of heat and mass transfer is used to take into account the behaviour of air in a steam mixture during the condensation process. The resulting dependencies obtained from the experiments and obtained from the theoretical model have similar results. The significant decrease in the condensation HTC, which begins at very low air concentrations in a steam mixture, was confirmed.

  20. Condensation of the air-steam mixture in a vertical tube condenser

    Science.gov (United States)

    Havlík, Jan; Dlouhý, Tomáš

    2016-03-01

    This paper deals with the condensation of water vapour in the presence of non-condensable air. Experimental and theoretical solutions of this problem are presented here. A heat exchanger for the condensation of industrial waste steam containing infiltrated air was designed. The condenser consists of a bundle of vertical tubes in which the steam condenses as it flows downwards with cooling water flowing outside the tubes in the opposite direction. Experiments with pure steam and with mixtures of steam with added air were carried out to find the dependence of the condensation heat transfer coefficient (HTC) on the air concentration in the steam mixture. The experimental results were compared with the theoretical formulas describing the cases. The theoretical determination of the HTC is based on the Nusselt model of steam condensation on a vertical wall, where the analogy of heat and mass transfer is used to take into account the behaviour of air in a steam mixture during the condensation process. The resulting dependencies obtained from the experiments and obtained from the theoretical model have similar results. The significant decrease in the condensation HTC, which begins at very low air concentrations in a steam mixture, was confirmed.

  1. Primes, Geometry and Condensed Matter

    Directory of Open Access Journals (Sweden)

    Al Rabeh R. H.

    2009-07-01

    Full Text Available Fascination with primes dates back to the Greeks and before. Primes are named by some "the elementary particles of arithmetic" as every nonprime integer is made of a unique set of primes. In this article we point to new connections between primes, geometry and physics which show that primes could be called "the elementary particles of physics" too. This study considers the problem of closely packing similar circles/spheres in 2D/3D space. This is in effect a discretization process of space and the allowable number in a pack is found to lead to some unexpected cases of prime configurations which is independent of the size of the constituents. We next suggest that a non-prime can be considered geometrically as a symmetric collection that is separable (factorable into similar parts- six is two threes or three twos for example. A collection that has no such symmetry is a prime. As a result, a physical prime aggregate is more difficult to split symmetrically resulting in an inherent stability. This "number/physical" stability idea applies to bigger collections made from smaller (prime units leading to larger stable prime structures in a limitless scaling up process. The distribution of primes among numbers can be understood better using the packing ideas described here and we further suggest that differing numbers (and values of distinct prime factors making a nonprime collection is an important factor in determining the probability and method of possible and subsequent disintegration. Disintegration is bound by energy conservation and is closely related to symmetry by Noether theorems. Thinking of condensed matter as the packing of identical elements, we examine plots of the masses of chemical elements of the periodic table, and also those of the elementary particles of physics, and show that prime packing rules seem to play a role in the make up of matter. The plots show convincingly that the growth of prime numbers and that of the masses of

  2. Mitotic chromosome condensation in vertebrates

    Energy Technology Data Exchange (ETDEWEB)

    Vagnarelli, Paola, E-mail: P.Vagnarelli@ed.ac.uk

    2012-07-15

    Work from several laboratories over the past 10-15 years has revealed that, within the interphase nucleus, chromosomes are organized into spatially distinct territories [T. Cremer, C. Cremer, Chromosome territories, nuclear architecture and gene regulation in mammalian cells, Nat. Rev. Genet. 2 (2001) 292-301 and T. Cremer, M. Cremer, S. Dietzel, S. Muller, I. Solovei, S. Fakan, Chromosome territories-a functional nuclear landscape, Curr. Opin. Cell Biol. 18 (2006) 307-316]. The overall compaction level and intranuclear location varies as a function of gene density for both entire chromosomes [J.A. Croft, J.M. Bridger, S. Boyle, P. Perry, P. Teague,W.A. Bickmore, Differences in the localization and morphology of chromosomes in the human nucleus, J. Cell Biol. 145 (1999) 1119-1131] and specific chromosomal regions [N.L. Mahy, P.E. Perry, S. Gilchrist, R.A. Baldock, W.A. Bickmore, Spatial organization of active and inactive genes and noncoding DNA within chromosome territories, J. Cell Biol. 157 (2002) 579-589] (Fig. 1A, A'). In prophase, when cyclin B activity reaches a high threshold, chromosome condensation occurs followed by Nuclear Envelope Breakdown (NEB) [1]. At this point vertebrate chromosomes appear as compact structures harboring an attachment point for the spindle microtubules physically recognizable as a primary constriction where the two sister chromatids are held together. The transition from an unshaped interphase chromosome to the highly structured mitotic chromosome (compare Figs. 1A and B) has fascinated researchers for several decades now; however a definite picture of how this process is achieved and regulated is not yet in our hands and it will require more investigation to comprehend the complete process. From a biochemical point of view a vertebrate mitotic chromosomes is composed of DNA, histone proteins (60%) and non-histone proteins (40%) [6]. I will discuss below what is known to date on the contribution of these two different classes

  3. Primes, Geometry and Condensed Matter

    Directory of Open Access Journals (Sweden)

    Al Rabeh R. H.

    2009-07-01

    Full Text Available Fascination with primes dates back to the Greeks and before. Primes are named by some “the elementary particles of arithmetic” as every nonprime integer is made of a unique set of primes. In this article we point to new connections between primes, geometry and physics which show that primes could be called “the elementary particles of physics” too. This study considers the problem of closely packing similar circles / spheres in 2D / 3D space. This is in effect a discretization process of space and the allowable num- ber in a pack is found to lead to some unexpected cases of prime configurations which is independent of the size of the constituents. We next suggest that a non-prime can be considered geometrically as a symmetric collection that is separable (factorable into similar parts- six is two threes or three twos for example. A collection that has no such symmetry is a prime. As a result, a physical prime aggregate is more difficult to split symmetrically resulting in an inherent stability. This “number / physical” stability idea applies to bigger collections made from smaller (prime units leading to larger sta- ble prime structures in a limitless scaling up process. The distribution of primes among numbers can be understood better using the packing ideas described here and we further suggest that differing numbers (and values of distinct prime factors making a nonprime collection is an important factor in determining the probability and method of possible and subsequent disintegration. Disintegration is bound by energy conservation and is closely related to symmetry by Noether theorems. Thinking of condensed matter as the packing of identical elements, we examine plots of the masses of chemical elements of the periodic table, and also those of the elementary particles of physics, and show that prime packing rules seem to play a role in the make up of matter. The plots show con- vincingly that the growth of prime numbers and that

  4. Enhanced tubes for steam condensers. Volume 1, Summary of condensation and fouling; Volume 2, Detailed study of steam condensation

    Energy Technology Data Exchange (ETDEWEB)

    Webb, R.L.; Chamra, L.; Jaber, H.

    1992-02-01

    Electric utility steam condensers typically use plain tubes made of titanium, stainless steel, or copper alloys. Approximately two-thirds of the total thermal resistance is on the water side of the plain tube. This program seeks to conceive and develop a tube geometry that has special enhancement geometries on the tube (water) side and the steam (shell) side. This ``enhanced`` tube geometry, will provide increased heat transfer coefficients. The enhanced tubes will allow the steam to condense at a lower temperature. The reduced condensing temperature will reduce the turbine heat rate, and increase the plant peak load capability. Water side fouling and fouling control is a very important consideration affecting the choice of the tube side enhancement. Hence, we have consciously considered fouling potential in our selection of the tube side surface geometry. Using appropriate correlations and theoretical models, we have designed condensation and water side surface geometries that will provide high performance and be cleanable using sponge ball cleaning. Commercial tube manufacturers have made the required tube geometries for test purposes. The heat transfer test program includes measurement of the condensation and water side heat transfer coefficients. Fouling tests are being run to measure the waterside fouling resistance, and to the test the ability of the sponge ball cleaning system to clean the tubes.

  5. Dropwise condensation on superhydrophobic surfaces with two-tier roughness

    Science.gov (United States)

    Chen, Chuan-Hua; Cai, Qingjun; Tsai, Chialun; Chen, Chung-Lung; Xiong, Guangyong; Yu, Ying; Ren, Zhifeng

    2007-04-01

    Dropwise condensation can enhance heat transfer by an order of magnitude compared to film condensation. Superhydrophobicity appears ideal to promote continued dropwise condensation which requires rapid removal of condensate drops; however, such promotion has not been reported on engineered surfaces. This letter reports continuous dropwise condensation on a superhydrophobic surface with short carbon nanotubes deposited on micromachined posts, a two-tier texture mimicking lotus leaves. On such micro-/nanostructured surfaces, the condensate drops prefer the Cassie state which is thermodynamically more stable than the Wenzel state. With a hexadecanethiol coating, superhydrophobicity is retained during and after condensation and rapid drop removal is enabled.

  6. Atenção primária em diabetes no Sul do Brasil: estrutura, processo e resultado

    Directory of Open Access Journals (Sweden)

    Maria Cecília F Assunção

    2001-02-01

    Full Text Available OBJETIVO: Descrever e avaliar a estrutura, o processo e o resultado do cuidado do paciente diabético atendido em nível primário de atenção à saúde em Pelotas, RS. MÉTODOS: O delineamento foi transversal. Foram estudados todos os 32 postos de saúde e 61 médicos que atendem pacientes diabéticos nesses locais. Foi identificada uma amostra de 378 pacientes que tiveram consulta médica nos postos. Os pacientes foram entrevistados em casa, e sua glicemia capilar, pressão arterial e índice de massa corporal foram avaliados e comparados a padrões. Componentes da estrutura e do processo de atendimento foram comparados a padrões recomendados ao manejo de pacientes diabéticos. RESULTADOS: A maioria dos serviços carece de aproximadamente todos os requerimentos mínimos. A aferição da pressão arterial foi o item do exame físico mais relatado na visita inicial. Como plano de tratamento na consulta inicial, cerca de 85% dos médicos relataram prescrever dieta, e 72% exercício físico. Todos os médicos relataram solicitar glicemia de jejum, e 60% hemoglobina glicosilada na monitorização laboratorial dos pacientes. O controle da doença variou de 6% a 11%, conforme os diferentes parâmetros utilizados. CONCLUSÕES: A rede pública de saúde está deficiente, mas existe potencial de melhoria dos três aspectos (estrutura, processo e resultado através de treinamento em serviço e seguimento de normas-padrão.

  7. Atenção primária em diabetes no Sul do Brasil: estrutura, processo e resultado

    Directory of Open Access Journals (Sweden)

    Assunção Maria Cecília F

    2001-01-01

    Full Text Available OBJETIVO: Descrever e avaliar a estrutura, o processo e o resultado do cuidado do paciente diabético atendido em nível primário de atenção à saúde em Pelotas, RS. MÉTODOS: O delineamento foi transversal. Foram estudados todos os 32 postos de saúde e 61 médicos que atendem pacientes diabéticos nesses locais. Foi identificada uma amostra de 378 pacientes que tiveram consulta médica nos postos. Os pacientes foram entrevistados em casa, e sua glicemia capilar, pressão arterial e índice de massa corporal foram avaliados e comparados a padrões. Componentes da estrutura e do processo de atendimento foram comparados a padrões recomendados ao manejo de pacientes diabéticos. RESULTADOS: A maioria dos serviços carece de aproximadamente todos os requerimentos mínimos. A aferição da pressão arterial foi o item do exame físico mais relatado na visita inicial. Como plano de tratamento na consulta inicial, cerca de 85% dos médicos relataram prescrever dieta, e 72% exercício físico. Todos os médicos relataram solicitar glicemia de jejum, e 60% hemoglobina glicosilada na monitorização laboratorial dos pacientes. O controle da doença variou de 6% a 11%, conforme os diferentes parâmetros utilizados. CONCLUSÕES: A rede pública de saúde está deficiente, mas existe potencial de melhoria dos três aspectos (estrutura, processo e resultado através de treinamento em serviço e seguimento de normas-padrão.

  8. Estruturação de redes sociais virtuais em organizações: um estudo de caso

    Directory of Open Access Journals (Sweden)

    Debora Bobsin

    2014-06-01

    Full Text Available O uso das redes sociais virtuais resulta em mudanças nas interações e na comunicação entre pessoas e grupos. Como as pesquisas têm enfatizado menos a adoção e o uso dessas redes nas organizações, o objetivo neste estudo é compreender o processo de estruturação das redes sociais virtuais em organizações, usando a teoria da estruturação como base. Analisou-se esse processo em uma organização universitária em consolidação, adotando o estudo de caso como metodologia e a observação participante como principal técnica de coleta de dados. Identificou-se que as redes representaram um importante vetor de formação de identidade e de construção de significados para os participantes e para a própria organização. Com base nos objetivos e propósitos dos participantes das redes, em suas interações criaram-se e recriaram-se estruturas e alteraram-se papéis, regras e o uso de recursos (tecnológicos e outros. Como conclusão, destacam-se os principais elementos de uma rede social virtual e seus usos por organizações, e são oferecidos direcionamentos para pesquisas futuras.

  9. Modelos de verificação à flexão de estruturas protendidas

    Directory of Open Access Journals (Sweden)

    M. B. Cavalcanti

    Full Text Available No cálculo da capacidade portante de estruturas protendidas a protensão pode ser considerada tanto como resistência quanto como carga. Tem-se, portanto, o "Modelo 1" que considera os cabos como parte integrante da seção, onde a operação de protensão induz deformação imposta correspondente ao pré-alongamento das armaduras ativas. Alternativamente, tem-se o "Modelo 2" que considera a protensão como caso de carregamento externo, composto por sistema auto-equilibrante de forças nas ancoragens e transversais no concreto. Após ativação da aderência os cabos de protensão são considerados no cálculo como armadura convencional, apenas deslocando o eixo das deformações para levar em conta o pré-alongamento. Apesar do "Modelo 1" ser mais utilizado no dimensionamento de vigas contínuas e estar consagrado na NBR-6118, ele possui o inconveniente do surgimento de esforços adicionais denominados efeitos hiperestáticos de protensão, que precisam ser considerados na verificação a ruptura. O cálculo dos efeitos hiperestáticos de protensão é relativamente simples no caso de vigas contínuas, porém torna-se complexo no caso de pórticos e grelhas e inviável no caso de lajes e cascas. Já no "Modelo 2" não há necessidade do cálculo dos efeitos hiperestáticos, porém as seções forçosamente terão que ser verificadas à flexão composta. Para comparar os resultados dos modelos são apresentados dois exemplos: um pórtico e uma de laje de tabuleiro de viaduto analisado utilizando-se analogia de grelha.

  10. Comunidade ética e religião: A estruturação da fé kantiana.

    Directory of Open Access Journals (Sweden)

    Carlos Magno Teixeira

    2013-09-01

    Full Text Available TEIXEIRA, C. M. Comunidade ética e religião: A estruturação da fé kantiana. Dissertação (Mestrado. 2013. 113f - Pontifícia Universidade Católica de Minas Gerais, Programa de Pós-graduação em Ciências da Religião, Belo Horizonte Palavras-chave Liberdade. Comunidade ética. Igreja. Religião moral. Fé racional. 

  11. Estruturas de barreira dupla de PbTe/PbEuTe crescidas por epitaxia de feixe molecular

    OpenAIRE

    Alexandre Miranda Pires dos Anjos

    2006-01-01

    Este trabalho apresenta o crescimento por epitaxia de feixe molecular de estruturas de barreira dupla (BD) de PbTe/Pb$_{1-x}$Eu$_{x}$Te e o processamento do dispositivo, visando à medida de tunelamento ressonante. As amostras foram crescidas sobre substratos de BaF$_{2}$ (111) à temperatura de 300$°$C. Medidas de resistividade e efeito Hall foram realizadas em filmes de referência para determinação das propriedades elétricas adequadas para cada camada da BD. As camadas de PbTe com ...

  12. Composição e estrutura da comunidade de aves na paisagem fragmentada do Pontal do Paranapanema

    OpenAIRE

    2007-01-01

    Este estudo mostrou os efeitos da fragmentação sobre a avifauna considerando diferentes aspectos, levando em conta escalas espaciais e temporais distintas e os diferentes elementos que compõem uma paisagem fragmentada. Verificamos a influência das características intrínsecas dos fragmentos, da configuração das paisagens e da variação geográfica sobre as respostas das espécies à fragmentação. Igualmente importante está a variação temporal; modificações da estrutura da paisagem passada têm refl...

  13. ANÁLISE SOCIOMÉTRICA DA ESTRUTURA DA REDE DE PROPRIEDADE INTELECTUAL DE UMA UNIVERSIDADE PÚBLICA

    OpenAIRE

    Nivaldo Calixto Ribeiro; Luiz Marcelo Antonialli; André Luiz Zambalde

    2015-01-01

    Este trabalho teve como objetivo investigar a estrutura da rede de colaboração dos pesquisadores da Universidade Federal de Lavras que registraram inventos no Instituto Nacional de Propriedade Intelectual (INPI), no período de 1995 a 2013. Os temas que correspondem aos pressupostos teóricos usados para embasar este estudo são a força dos laços de Granovetter (1973) e a teoria dos buracos estruturais de Burt (1992) e sua importância para as relações interorganizacionais, no contexto das univer...

  14. Resposta de estruturas lineares sujeitas a carregamento dinâmico Response of linear structures subjected to dynamic loading

    Directory of Open Access Journals (Sweden)

    Vítor Faustino Pereira

    1982-11-01

    Full Text Available Demonstração do emprego da Transformada de Fourier no cálculo da resposta de estruturas de comportamento linear sujeitas a carregamento dinâmico. O emprego desta técnica é vantajoso quando a resposta é obtida numericamente graças ao algoritmo de Transformada Rápida de Fourier. The objective of this work is to show the use of Fourier Transform in the evaluation of the response of linear structures subjected to dynamic loading. The use of this technique is advantageous when the response is obtained numerically due to the Fast Fourier Transform algorithm.

  15. COOPERATIVAS AGROPECUÁRIAS DE SANTA CATARINA: GESTÃO E ESTRUTURA DE CAPITAL PRÓPRIO

    OpenAIRE

    Proner, Ademir; Amaral da Costa, Magnus

    2007-01-01

    O artigo objetiva verificar a estrutura do capital próprio das cooperativas agropecuárias de Santa Catarina no período de 1994 a 2003, bem como identificar a existência de empreendimento capitalizado pelo sócio, proporcionalmente à produção a ser entregue. A metodologia utilizada foi a pesquisa de campo e documental. Os resultados mostram que as reservas tendem a ter destaque, pois, pelo fato das cooperativas não terem um limite máximo das reservas sobre o patrimônio líquido, os dirigentes as...

  16. Estrutura, dinâmica e transições de fase do arseniato de betaína

    OpenAIRE

    2000-01-01

    Dissertação de Doutoramento em Física apresentada à Faculdade de Ciências da Universidade do Porto Neste trabalho apresentamos um estudo experimental relativo à sequência de transições de fase no arseniato de betaína (BA) e nos compostos parcial e fortemente deuterados (BA1-xDBAx), focando principalmente a estrutura das fases e a dinâmica dos processos envolvidos. Neste estudo foram utilizadas técnicas de difracção de raios X, de espectroscopia vibracional e técnicas macroscópicas de carac...

  17. A estrutura da oração em línguas indígenas brasileiras

    Directory of Open Access Journals (Sweden)

    MAIA Marcus

    1999-01-01

    Full Text Available Compara-se neste artigo um conjunto de fatos relacionados a interface sintaxe/morfologia em quatro línguas indígenas brasileiras, a saber, Kuikuro, Guarani, Karaja e Tikuna. Investiga-se o papel das categorias funcionais na derivação da estrutura básica da oração nessas línguas. Discutem-se os problemas que se colocam para a linearização da ordem SOV, propondo-se análises alternativas.

  18. Conceção e Execução de Estruturas Metálicas

    OpenAIRE

    Moreira, Tiago Manuel Rodrigues

    2014-01-01

    O presente relatório diz respeito ao trabalho desenvolvido ao longo de seis meses em ambiente de estágio curricular na empresa O FELIZ – Metalomecânica, S.A.. O objetivo principal deste trabalho foi o conhecimento resultante de uma experiência num ambiente industrial no sector das construções metálicas. Pela especificidade do setor, foi desenvolvido um estudo no âmbito da conceção e execução (na componente de fabrico) de estruturas. O relatório que resulta deste trabalho de estágio tem ...

  19. MODELAGEM DE OCORRÊNCIA DE COORTES NA ESTRUTURA DIAMÉTRICA DA Araucaria angustifolia (Bertol.) Kuntze

    OpenAIRE

    Ebling,Ângelo Augusto; Netto, Sylvio Péllico

    2015-01-01

    Estudos referentes à estrutura diamétrica das florestas nativas são essenciais para o entendimento do desenvolvimento, fornecer parâmetros do crescimento e produção suficientes para gerar estimativas que subsidiem o manejo sustentado. No entanto, a modelagem matemática de funções probabilísticas, como as de densidade, tornam-se de difícil aplicação em distribuições multimodais. A espécie Araucaria angustifolia (Bertol.) Kuntze, de importância social, ambiental e econômica, apresenta padrão de...

  20. Effect of Non-Condensable Gas Mass Fraction on Condensation Heat Transfer for Water-Ethanol Vapor Mixture

    Science.gov (United States)

    Wang, Shixue; Utaka, Yoshio

    The condensation heat transfer characteristic curves for a ternary vapor mixture of water, ethanol and air (or nitrogen) under several ethanol concentrations and relatively low concentrations of air (or nitrogen) were measured. The effect of non-condensable gas on several different domains in the condensation curves was discussed. The effect of non-condensable gas in the domains controlled by the diffusion resistance and the filmwise condensation was not notable; whereas that in the domain dominated by the condensate resistance of dropwise mode was remarkable. Moreover, variations due to changes in non-condensable gas concentration of several characteristic points representing the curves were discussed.

  1. Simulation Prediction of Transient Dropwise Condensation

    Science.gov (United States)

    Macner, Ashley; Daniel, Susan; Steen, Paul

    2014-11-01

    In order to design effective surfaces for large-scale dropwise condensation, an understanding of how surface functionalization affects drop growth and coalescence is needed. The long term technological goal is a set of design conditions to help NASA achieve maximum heat transfer rates of waste heat generated from electronics and habitable environments under microgravity conditions. Prediction of condenser surface heat transfer performance requires accurate simulation and modeling of the evolution of populations of drops in time. At shorter times, drops are primarily isolated and grow mainly by condensation onto the liquid-gas interface. At longer times, drops grow mainly by coalescence with neighbors. Simulation of dropwise condensation on a neutrally wetting surface and comparison with our previous experimental results is reported. A steady-state single drop conduction model is empirically fitted to determine a temperature profile that captures the drop size evolution. The simulation accurately predicts the continuous time evolution of number-density of drops, drop-size distributions, total condensate volume, fractional coverage, and median drop-size for both transient and steady states, all with no free parameters. This work was supported by a NASA Office of the Chief Technologist's Space Technology Research Fellowship.

  2. The NSF Condensed Matter Physics Program

    Science.gov (United States)

    Sokol, Paul

    The Condensed Matter Physics (CMP) program in the NSF Division of Materials Research (DMR) supports experimental, as well as combined experiment and theory projects investigating the fundamental physics behind phenomena exhibited by condensed matter systems. CMP is the largest Individual Investigator Award program in DMR and supports a broad portfolio of research spanning both hard and soft condensed matter. Representative research areas include: 1) phenomena at the nano- to macro-scale including: transport, magnetic, and optical phenomena; classical and quantum phase transitions; localization; electronic, magnetic, and lattice structure or excitations; superconductivity; topological insulators; and nonlinear dynamics. 2) low-temperature physics: quantum fluids and solids; 1D & 2D electron systems. 3) soft condensed matter: partially ordered fluids, granular and colloid physics, liquid crystals, and 4) understanding the fundamental physics of new states of matter as well as the physical behavior of condensed matter under extreme conditions e.g., low temperatures, high pressures, and high magnetic fields. In this talk I will review the current CMP portfolio and discuss future funding trends for the program. I will also describe recent activities in the program aimed at addressing the challenges facing current and future principal investigators.

  3. Condensation of refrigerants on vertical fluted tubes

    Energy Technology Data Exchange (ETDEWEB)

    Combs, S.K.; Mailen, G.S.; Murphy, R.W.

    1978-08-01

    Experiments were run to determine heat transfer performance of single vertical fluted tubes with selected fluids condensing on the outside. Working fluids included six fluorocarbons (Refrigerants 11, 21, 22, 113, 114, and 115) and a hydrocarbon (Refrigerant 600a or isobutane). The nine test tubes were of 2.54-cm (1-in.) nominal outside diameter and 1.2 m (4 ft) in length with from 0 (smooth) to 60 axial flutes. Condensing heat transfer coefficients ranged from 620 to 7900 W/m/sup 2/ . K (110 to 1400 Btu/hr . ft/sup 2/ . /sup 0/F) over the heat flux range of 2000 to 43,000 W/m/sup 2/ (920 to 13,600 Btu/hr . ft/sup 2/). All parameters are based on total condensing surface area. The data show that, for a given heat flux, a fluted tube can increase condensing coefficients up to 6.0 times smooth tube values. Further heat transfer enhancement was achieved by the use of drainage skirts on fluted tubes; these skirts effectively divided the 1.2-m (4-ft) tubes into two, four, and eight equal condensing lengths.

  4. CFD modelling and validation of wall condensation in the presence of non-condensable gases

    Energy Technology Data Exchange (ETDEWEB)

    Zschaeck, G., E-mail: guillermo.zschaeck@ansys.com [ANSYS Germany GmbH, Staudenfeldweg 12, Otterfing 83624 (Germany); Frank, T. [ANSYS Germany GmbH, Staudenfeldweg 12, Otterfing 83624 (Germany); Burns, A.D. [ANSYS UK Ltd, 97 Milton Park, Abingdon, Oxfordshire OX14 4RY (United Kingdom)

    2014-11-15

    Highlights: • A wall condensation model was implemented and validated in ANSYS CFX. • Condensation rate is assumed to be controlled by the concentration boundary layer. • Validation was done using two laboratory scale experiments. • CFD calculations show good agreement with experimental data. - Abstract: The aim of this paper is to present and validate a mathematical model implemented in ANSYS CFD for the simulation of wall condensation in the presence of non-condensable substances. The model employs a mass sink at isothermal walls or conjugate heat transfer (CHT) domain interfaces where condensation takes place. The model was validated using the data reported by Ambrosini et al. (2008) and Kuhn et al. (1997)

  5. Measurement of liquid-liquid equilibria for condensate + glycol and condensate + glycol + water systems

    DEFF Research Database (Denmark)

    Riaz, Muhammad; Kontogeorgis, Georgios; Stenby, Erling Halfdan

    2011-01-01

    Today's oil and gas production requires the application of various chemicals in large amounts. To evaluate the effects of those chemicals on the environment, it is of crucial importance to know how much of the chemicals are discharged via produced water and how much is dissolved in the crude oil....... The ultimate objective of this work is to develop a predictive thermodynamic model for the mutual solubility of oil, water, and polar chemicals. But for the development and validation of the model, experimental data are required. This work presents new experimental liquid-liquid equilibrium (LLE) data for 1......,2-ethanediol (MEG) + condensate and MEG + water + condensate systems at temperatures from (275 to 323) K at atmospheric pressure. The condensate used in this work is a stabilized natural gas condensate from an offshore field in the North Sea. Compositional analysis of the natural gas condensate was carried out...

  6. Preoperational test report, recirculation condenser cooling systems

    Energy Technology Data Exchange (ETDEWEB)

    Clifton, F.T.

    1997-11-04

    This represents a preoperational test report for Recirculation Condenser Systems, Project W-030. Project W-030 provides a ventilation upgrade for the four Aging Waste Facility tanks. The four system provide condenser cooling water for vapor space cooling of tanks AY1O1, AY102, AZ1O1, AZ102. Each system consists of a valved piping loop, a pair of redundant recirculation pumps, a closed-loop evaporative cooling tower, and supporting instrumentation; equipment is located outside the farm on concrete slabs. Piping is routed to the each ventilation condenser inside the farm via below-grade concrete trenches. The tests verify correct system operation and correct indications displayed by the central Monitor and Control System.

  7. Field theories of condensed matter physics

    CERN Document Server

    Fradkin, Eduardo

    2013-01-01

    Presenting the physics of the most challenging problems in condensed matter using the conceptual framework of quantum field theory, this book is of great interest to physicists in condensed matter and high energy and string theorists, as well as mathematicians. Revised and updated, this second edition features new chapters on the renormalization group, the Luttinger liquid, gauge theory, topological fluids, topological insulators and quantum entanglement. The book begins with the basic concepts and tools, developing them gradually to bring readers to the issues currently faced at the frontiers of research, such as topological phases of matter, quantum and classical critical phenomena, quantum Hall effects and superconductors. Other topics covered include one-dimensional strongly correlated systems, quantum ordered and disordered phases, topological structures in condensed matter and in field theory and fractional statistics.

  8. Dropwise condensation on inclined textured surfaces

    CERN Document Server

    Khandekar, Sameer

    2014-01-01

    Dropwise Condensation on Textured Surfaces presents a holistic framework for understanding dropwise condensation through mathematical modeling and meaningful experiments. The book presents a review of the subject required to build up models as well as to design experiments. Emphasis is placed on the effect of physical and chemical texturing and their effect on the bulk transport phenomena. Application of the model to metal vapor condensation is of special interest. The unique behavior of liquid metals, with their low Prandtl number and high surface tension, is also discussed. The model predicts instantaneous drop size distribution for a given level of substrate subcooling and derives local as well as spatio-temporally averaged heat transfer rates and wall shear stress.

  9. DROPWISE CONDENSATION ON MICRO- AND NANOSTRUCTURED SURFACES

    Energy Technology Data Exchange (ETDEWEB)

    Enright, R; Miljkovic, N; Alvarado, JL; Kim, K; Rose, JW

    2014-07-23

    In this review we cover recent developments in the area of surface-enhanced dropwise condensation against the background of earlier work. The development of fabrication techniques to create surface structures at the micro-and nanoscale using both bottom-up and top-down approaches has led to increased study of complex interfacial phenomena. In the heat transfer community, researchers have been extensively exploring the use of advanced surface structuring techniques to enhance phase-change heat transfer processes. In particular, the field of vapor-to-liquid condensation and especially that of water condensation has experienced a renaissance due to the promise of further optimizing this process at the micro-and nanoscale by exploiting advances in surface engineering developed over the last several decades.

  10. Condensation heat transfer coefficient versus wettability

    Science.gov (United States)

    Roudgar, M.; De Coninck, J.

    2015-05-01

    In this paper we show how condensation on substrates can induce wetting behavior that is quite different from that of deposited or impinging drops. We describe surfaces with the same wettability in ambient conditions presenting different wetting behavior and growth of droplets in condensation. The experimental results show a rapid spread of droplets and formation of the film on the copper surface, while droplets on SU-8 surface remains on the regular shape while they grow within the time, without coalescence, as observed for Cu. Although the heat conductivity of SU-8 is much lower, due to a difference in wetting behavior, the heat transfer coefficient (h) is higher for dropwise condensation on Cu with a thin layer of SU-8 than filmwise on the bare copper.

  11. Nonlocal Condensate Model for QCD Sum Rules

    CERN Document Server

    Hsieh, Ron-Chou

    2009-01-01

    We include effects of nonlocal quark condensates into QCD sum rules (QSR) via the K$\\ddot{\\mathrm{a}}$ll$\\acute{\\mathrm{e}}$n-Lehmann representation for a dressed fermion propagator, in which a negative spectral density function manifests their nonperturbative nature. Applying our formalism to the pion form factor as an example, QSR results are in good agreement with data for momentum transfer squared up to $Q^2 \\approx 10 $ GeV$^2$. It is observed that the nonlocal quark-condensate contribution descends like $1/Q^4$, different from the exponential decrease in $Q^2$ obtained in the literature, and contrary to the linear rise in the local-condensate approximation.

  12. Efficient cell migration requires global chromatin condensation.

    Science.gov (United States)

    Gerlitz, Gabi; Bustin, Michael

    2010-07-01

    Cell migration is a fundamental process that is necessary for the development and survival of multicellular organisms. Here, we show that cell migration is contingent on global condensation of the chromatin fiber. Induction of directed cell migration by the scratch-wound assay leads to decreased DNaseI sensitivity, alterations in the chromatin binding of architectural proteins and elevated levels of H4K20me1, H3K27me3 and methylated DNA. All these global changes are indicative of increased chromatin condensation in response to induction of directed cell migration. Conversely, chromatin decondensation inhibited the rate of cell migration, in a transcription-independent manner. We suggest that global chromatin condensation facilitates nuclear movement and reshaping, which are important for cell migration. Our results support a role for the chromatin fiber that is distinct from its known functions in genetic processes.

  13. The condensation of water on adsorbed viruses.

    Science.gov (United States)

    Alonso, José María; Tatti, Francesco; Chuvilin, Andrey; Mam, Keriya; Ondarçuhu, Thierry; Bittner, Alexander M

    2013-11-26

    The wetting and dewetting behavior of biological nanostructures and to a greater degree single molecules is not well-known even though their contact with water is the basis for all biology. Here, we show that environmental electron microscopy (EM) can be applied as a means of imaging the condensation of water onto viruses. We captured the formation of submicrometer water droplets and filaments on single viral particles by environmental EM and by environmental transmission EM. The condensate structures are compatible with capillary condensation between adsorbed virus particles and with known droplet shapes on patterned surfaces. Our results confirm that such droplets exist down to evaporation cycle as expected from their stability in air and water. Moreover we developed procedures that overcome problems of beam damage and of resolving structures with a low atomic number.

  14. Vector meson condensation in a pion superfluid

    CERN Document Server

    Brauner, Tomas

    2016-01-01

    We revisit the suggestion that charged rho-mesons undergo Bose-Einstein condensation in isospin-rich nuclear matter. Using a simple version of the Nambu-Jona-Lasinio (NJL) model, we conclude that rho-meson condensation is either avoided or postponed to isospin chemical potentials much higher than the rho-meson mass as a consequence of the repulsive interaction with the preformed pion condensate. In order to support our numerical results, we work out a linear sigma model for pions and rho-mesons, showing that the two models lead to similar patterns of medium dependence of meson masses. As a byproduct, we analyze in detail the mapping between the NJL model and the linear sigma model, focusing on conditions that must be satisfied for a quantitative agreement between the models.

  15. Vector meson condensation in a pion superfluid

    Science.gov (United States)

    Brauner, Tomáš; Huang, Xu-Guang

    2016-11-01

    We revisit the suggestion that charged ρ -mesons undergo Bose-Einstein condensation in isospin-rich nuclear matter. Using a simple version of the Nambu-Jona-Lasinio (NJL) model, we conclude that ρ -meson condensation is either avoided or postponed to isospin chemical potentials much higher than the ρ -meson mass as a consequence of the repulsive interaction with the preformed pion condensate. In order to support our numerical results, we work out a linear sigma model for pions and ρ -mesons, showing that the two models lead to similar patterns of medium dependence of meson masses. As a byproduct, we analyze in detail the mapping between the NJL model and the linear sigma model, focusing on conditions that must be satisfied for a quantitative agreement between the models.

  16. Why double-stranded RNA resists condensation

    Energy Technology Data Exchange (ETDEWEB)

    Tolokh, Igor S.; Pabit, Suzette; Katz, Andrea M.; Chen, Yujie; Drozdetski, Aleksander; Baker, Nathan A.; Pollack, Lois; Onufriev, Alexey

    2014-09-15

    The addition of small amounts of multivalent cations to solutions containing double-stranded DNA leads to attraction between the negatively charged helices and eventually to condensation. Surprisingly, this effect is suppressed in double-stranded RNA, which carries the same charge as the DNA, but assumes a different double helical form. However, additional characterization of short (25 base-pairs) nucleic acid (NA) duplex structures by circular dichroism shows that measured differences in condensation are not solely determined by duplex helical geometry. Here we combine experiment, theory, and atomistic simulations to propose a mechanism that connects the observed variations in condensation of short NA duplexes with the spatial variation of cobalt hexammine (CoHex) binding at the NA duplex surface. The atomistic picture that emerged showed that CoHex distributions around the NA reveals two major NA-CoHex binding modes -- internal and external -- distinguished by the proximity of bound CoHex to the helical axis. Decreasing trends in experimentally observed condensation propensity of the four studied NA duplexes (from B-like form of homopolymeric DNA, to mixed sequence DNA, to DNA:RNA hybrid, to A-like RNA) are explained by the progressive decrease of a single quantity: the fraction of CoHex ions in the external binding mode. Thus, while NA condensation depends on a complex interplay between various structural and sequence features, our coupled experimental and theoretical results suggest a new model in which a single parameter connects the NA condensation propensity with geometry and sequence dependence of CoHex binding.

  17. Temporal dynamics of Bose-condensed gases

    Energy Technology Data Exchange (ETDEWEB)

    Trujillo Martinez, Mauricio

    2014-03-19

    We perform a detailed quantum dynamical study of non-equilibrium trapped, interacting Bose-condensed gases. We investigate Josephson oscillations between interacting Bose-Einstein condensates confined in a finite size double-well trap and the non-trivial time evolution of a coherent state placed at the center of a two dimensional optical lattice. For the Josephson oscillations three time scales appear. We find that Josephson junction can sustain multiple undamped oscillations up to a characteristic time scale τ{sub c} without exciting atoms out of the condensates. Beyond the characteristic time scale τ{sub c} the dynamics of the junction are governed by fast, non-condensed particles assisted Josephson tunnelling as well as the collisions between non-condensed particles. In the non-condensed particles dominated regime we observe strong damping of the oscillations due to inelastic collisions, equilibrating the system leading to an effective loss of details of the initial conditions. In addition, we predict that an initially self-trapped BEC state will be destroyed by these fast dynamics. The time evolution of a coherent state released at the center of a two dimensional optical lattice shows a ballistic expansion with a decreasing expansion velocity for increasing two-body interactions strength and particle number. Additionally, we predict that if the two-body interactions strength exceeds a certain value, a forerunner splits up from the expanding coherent state. We also observe that this system, which is prepared far from equilibrium, can evolve to a quasistationary non-equilibrium state.

  18. Geometric approach to condensates in holographic QCD

    CERN Document Server

    Hirn, J; Sanz, V; Hirn, Johannes; Rius, Nuria; Sanz, Veronica

    2006-01-01

    An SU(Nf)xSU(Nf) Yang-Mills theory on an extra-dimensional interval is considered, with appropriate symmetry-breaking boundary conditions on the IR brane. UV-brane to UV-brane correlators at high energies are compared with the OPE of two-point functions of QCD quark currents. Condensates correspond to departure from AdS of the (different) metrics felt by vector and axial combinations, away from the UV brane. Their effect on hadronic observables is studied: the extracted condensates agree with the signs and orders of magnitude expected from QCD.

  19. Colored condensates deep inside neutron stars

    CERN Document Server

    Blaschke, David

    2014-01-01

    It is demonstrated how in the absence of solutions for QCD under conditions deep inside compact stars an equation of state can be obtained within a model that is built on the basic symmetries of the QCD Lagrangian, in particular chiral symmetry and color symmetry. While in the vacuum the chiral symmetry is spontaneously broken, it gets restored at high densities. Color symmetry, however, gets broken simultaneously by the formation of colorful diquark condensates. It is shown that a strong diquark condensate in cold dense quark matter is essential for supporting the possibility that such states could exist in the recently observed pulsars with masses of 2 $M_\\odot$.

  20. Effects of oxaliplatin on DNA condensation

    Institute of Scientific and Technical Information of China (English)

    JU HaiPeng; ZHANG HongYan; LI Wei; WANG PengYe

    2014-01-01

    In this paper the interactions between DNA and anti-cancer drug oxaliplatin were investigated by using magnetic tweezers.The dynamics of DNA condensation due to oxaliplatin was traced under various forces.It is found that torsion constraint in DNA enhances the ability of oxaliplatin for shortening DNA.The transplatin helps oxaliplatin combine to DNA and increase the rate of DNA condensation.All these results are consistent to the previously proposed model and are helpful for further investigation of interaction between DNA and oxaliplatin.

  1. Bose-Einstein Condensation of Atomic Hydrogen

    CERN Document Server

    Kleppner, D; Killian, T C; Fried, D G; Willmann, L; Landhuis, D; Moss, S C; Kleppner, Daniel; Greytak, Thomas J.; Killian, Thomas C.; Fried, Dale G.; Willmann, Lorenz; Landhuis, David; Moss, Stephen C.

    1998-01-01

    We have observed Bose-Einstein condensation (BEC) of trapped atomic hydrogen, and studied it by two-photon spectroscopy of the 1S-2S transition. In these lecture notes we briefly review the history of spin-polarized atomic hydrogen and describe the final steps to BEC. Laser spectroscopy, which probes the difference in mean field energy of the 1S and 2S states, is used to study the condensate, which has a peak density of 4.8e15 cm^-3 and population of 10^9.

  2. Turbulent meson condensation in quark deconfinement

    Directory of Open Access Journals (Sweden)

    Koji Hashimoto

    2015-06-01

    Full Text Available In a QCD-like strongly coupled gauge theory at large Nc, using the AdS/CFT correspondence, we find that heavy quark deconfinement is accompanied by a coherent condensation of higher meson resonances. This is revealed in non-equilibrium deconfinement transitions triggered by static, as well as quenched electric fields even below the Schwinger limit. There, we observe a “turbulent” energy flow to higher meson modes, which finally results in the quark deconfinement. Our observation is consistent with seeing deconfinement as a condensation of long QCD strings.

  3. Composition of gases vented from a condenser

    Energy Technology Data Exchange (ETDEWEB)

    Lyon, R.N.

    1980-08-01

    Designers of systems that involve condensers often need to predict the amount of process vapor that accompanies the noncondensable gases that are vented from the condensers. An approximation is given that appears to provide, in many cases, reasonably accurate values for the mole ratio of process vapor to noncondensable gases in the vented mixture. The approximation is particularly applicable to flash and direct-contact power systems for geothermal brines and ocean thermal energy conversion (OTEC). More regorous relationships are available for exceptional cases.

  4. Renormalisation Group Flow and Kaon Condensation

    CERN Document Server

    Krippa, Boris

    2016-01-01

    Functional renormalisation group approach is applied to a system of kaons with finite chemical potential. A set of approximate flow equations for the effective couplings is derived and solved. At high scale the system is found to be at the normal phase whereas at some critical value of the running scale it undergoes the phase transition (PT) to the phase with a spontaneously broken symmetry with the kaon condensate as an order parameter. The value of the condensate turns out to be quite sensitive to the kaon-kaon scattering length.

  5. Influence of condensation temperature on selected exhaled breath parameters

    Directory of Open Access Journals (Sweden)

    Manini Paola

    2005-09-01

    Full Text Available Abstract Background The effects of changes in cooling temperature on biomarker levels in exhaled breath condensate have been little investigated. The aim of the study was to test the effect of condensation temperature on the parameters of exhaled breath condensate and the levels of selected biomarkers. Methods Exhaled breath condensate was collected from 24 healthy subjects at temperatures of -10, -5, 0 and +5 C degrees. Selected parameters (condensed volume and conductivity and biomarkers (hydrogen peroxide, malondialdehyde were measured. Results There was a progressive increase in hydrogen peroxide and malondialdehyde concentrations, and condensate conductivity as the cooling temperature increased; total condensate volume increased as the cooling temperature decreased. Conclusion The cooling temperature of exhaled breath condensate collection influenced selected biomarkers and potential normalizing factors (particularly conductivity in different ways ex vivo. The temperature of exhaled breath condensate collection should be controlled and reported.

  6. Correlações entre as estruturas dos membros inferiores Correlations between lower limb structures

    Directory of Open Access Journals (Sweden)

    Francis Trombini-Souza

    2009-09-01

    Full Text Available A literatura sugere que mudanças no ângulo Q podem alterar o arco plantar longitudinal e que um mau alinhamento do retropé poderia também modificar a postura do antepé. Contudo, não foram encontrados estudos que correlacionem quantitativamente, na postura ortostática bipodal, todos esses segmentos. Assim, o propósito deste estudo foi avaliar quantitativamente e verificar eventuais correlações entre o ângulo Q, arco plantar longitudinal, alinhamento frontal do tendão do calcâneo e antepé, na postura ortostática bipodal, por meio de fotogrametria. Foram avaliados 30 indivíduos jovens (60 membros inferiores de ambos os sexos, com idade entre 18 e 24 anos. Foi feita captura fotográfica digital no plano frontal anterior de joelho e antepé; no plano frontal posterior, do tendão do calcâneo; e da impressão plantar exposta no podoscópio. Os dados foram analisados estatisticamente e o nível de signficância fixado em 5%. Foram obtidas as seguintes correlações entre: ângulo Q X arco plantar, r=0,29 (p=0,021; ângulo Q X antepé, r=0,23 (p=0,092; ângulo Q X tendão do calcâneo, r=0,06 (p=0,627; arco plantar X antepé, r=0,09 (p=0,464; arco plantar X tendão do calcâneo, r=-0,05 (p=0,680; e antepé X tendão do calcâneo, r=-0,02 (p=0,857. A única correlação significativa encontrada, embora fraca, foi entre o ângulo Q e o arco plantar longitudinal medial, o que sugere cautela ao se inferirem correlações entre estruturas dos membros inferiores.Literature often reports that changes in the Q angle may alter the longitudinal plantar arch and that a misalignment of the rearfoot might also modify forefoot position. However, no studies could be found that quantitatively establish correlations between those lower limb segments in orthostatic bipedal posture. The goal of this study was to quantitatively assess possible correlations between the Q angle, longitudinal plantar arch, frontal forefoot and rearfoot alignment in bipedal

  7. Desenvolvimento de marcadores microssatélites e estrutura genética espacial da Copernicia prunifera (Miller) H. E. Moore (Arecaceae)

    OpenAIRE

    Pinheiro, Luciana Gomes

    2015-01-01

    O estudo visou (1) desenvolver marcadores microssatélites (SSR) para Copernicia prunifera, e (2) caracterizar o padrão demográfico e a estrutura genética espacial (EGE) entre estágios de vida por meio de iniciadores ISSR. Foram desenvolvidos 17 pares de iniciadores SSR. A estrutura demográfica e EGE foram avaliadas em uma parcela com área de 0,55 ha em área natural, onde todos os indivíduos foram georreferenciados (n = 161). As análises moleculares dos SSR indicaram que todos os pares de inic...

  8. ANÁLISE DE TENSÕES EM ESTRUTURAS AXISSIMÉTRICAS EMPREGANDO A FORMULAÇÃO EM COORDENADAS POLARES DA TEORIA DE VOLUMES FINITOS

    OpenAIRE

    dos Santos, Arlan Ricardo C; Cavalcante, Márcio André A.

    2017-01-01

    Resumo. Este trabalho apresenta uma formulação para análise de tensões em estruturas axissimétricas, tais como tubos circulares, cilindros e anéis, elaborada com base em uma versão em coordenadas polares da Teoria de Volumes Finitos. Esta formulação é bastante apropriada para análise de tensões em estruturas com contornos curvos, apresentando geometria e campos mecânicos expressos em termo de coordenadas polares, visando melhorar o desempenho do método em tais situações. Diferentemente de ver...

  9. Enhancing Condensers for Geothermal Systems: the Effect of High Contact Angles on Dropwise Condensation Heat Transfer

    Energy Technology Data Exchange (ETDEWEB)

    Kennedy, John M.; Kim, Sunwoo; Kim, Kwang J.

    2009-10-06

    Phase change heat transfer is notorious for increasing the irreversibility of, and therefore decreasing the efficiency of, geothermal power plants. Its significant contribution to the overall irreversibility of the plant makes it the most important source of inefficiency in the process. Recent studies here have shown the promotion of drop wise condensation in the lab by means of increasing the surface energy density of a tube with nanotechnology. The use of nanotechnology has allowed the creation of surface treatments which discourage water from wetting a tube surface during a static test. These surface treatments are unique in that they create high- contact angles on the condensing tube surfaces to promote drop wise condensation.

  10. Condensation heat transfer on two-tier superhydrophobic surfaces

    Science.gov (United States)

    Cheng, Jiangtao; Vandadi, Aref; Chen, Chung-Lung

    2012-09-01

    We investigated water vapor condensation on a two-tier superhydrophobic surface in an environmental scanning electron microscope (ESEM) and in a customer-designed vapor chamber. We have observed continuous dropwise condensation (DWC) on the textured surface in ESEM. However, a film layer of condensate was formed on the multiscale texture in the vapor chamber. Due to the filmwise condensation, the condensation heat transfer coefficient of the superhydrophobic surface is lower than that of a flat hydrophobic surface especially under high heat flux situations. Our studies indicate that adaptive and prompt condensate droplet purging is the dominant factor for sustaining long-term DWC.

  11. On condensation of topological defects and confinement

    CERN Document Server

    Gaete, P; Gaete, Patricio; Wotzasek, Clovis

    2004-01-01

    We study the static quantum potential for a theory of anti-symmetric tensor fields that results from the condensation of topological defects, within the framework of the gauge-invariant but path-dependent variables formalism. Our calculations show that the interaction energy is the sum of a Yukawa and a linear potentials, leading to the confinement of static probe charges.

  12. PECVD silicon nitride diaphragms for condenser microphones

    NARCIS (Netherlands)

    Scheeper, P.R.; Voorthuyzen, J.A.; Bergveld, P.

    1991-01-01

    The application of plasma-enhanced chemical vapour deposited (PECVD) silicon nitride as a diaphragm material for condenser microphones has been investigated. By means of adjusting the SiH4/NH3 gas-flow composition, silicon-rich silicon nitride films have been obtained with a relatively low tensile s

  13. Spermine Condenses DNA, but Not RNA Duplexes

    Energy Technology Data Exchange (ETDEWEB)

    Katz, Andrea M.; Tolokh, Igor S.; Pabit, Suzette A.; Baker, Nathan; Onufriev, Alexey V.; Pollack, Lois

    2017-01-01

    Interactions between the polyamine spermine and nucleic acids drive important cellular processes. Spermine condenses DNA, and some RNAs such as poly(rA):poly(rU). A large fraction of the spermine present in cells is bound to RNA, but apparently does not condense it. Here, we study the effect of spermine binding to short duplex RNA and DNA and compare our findings with predictions of molecular dynamics simulations. When small numbers of spermine are introduced, RNA with a designed sequence, containing a mixture of 14 GC pairs and 11 AU pairs, resists condensation relative to DNA of an equivalent sequence or to 25 base pair poly(rA):poly(rU) RNA. Comparison of wide-angle x-ray scattering profiles with simulation suggests that spermine is sequestered deep within the major groove of mixed sequence RNA, preventing condensation by limiting opportunities to bridge to other molecules as well as stabilizing the RNA by locking it into a particular conformation. In contrast, for DNA, simulations suggest that spermine binds external to the duplex, offering opportunities for intermolecular interaction. The goal of this study is to explain how RNA can remain soluble, and available for interaction with other molecules in the cell, despite the presence of spermine at concentrations high enough to precipitate DNA.

  14. Polariton condensation in a disordered potential

    DEFF Research Database (Denmark)

    Antón, C.; Tosi, G.; Lingg, C. A.;

    2011-01-01

    We study polariton condensation under OPO (Optical Parametric Oscillator) out-of-equilibrium conditions [1] in the presence of linear and point defects. Because of the simultaneous presence of pump, signal and idler emitting at different wave vectors, as well as of photonic disorder, the system i...

  15. Fundamentals of neutron scattering by condensed matter

    Energy Technology Data Exchange (ETDEWEB)

    Scherm, R. [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1996-12-31

    The purpose of this introductory lecture is to give the basic facts about the scattering of neutrons by condensed matter. This lecture is restricted to nuclear scattering, whereas magnetic scattering will be dealt with in an other course. Most of the formalism, however, can also be easily extended to magnetic scattering. (author) 17 figs., 3 tabs., 10 refs.

  16. Dropwise condensation on a cold gradient substrate

    Science.gov (United States)

    Macner, Ashley; Daniel, Susan; Steen, Paul

    2012-11-01

    Distributions of drops that arise from dropwise condensation evolve by nucleation, growth, and coalescence of drops. An understanding of how surface-energy gradients applied to the substrate affect drop growth and coalescence is needed for design of effective surfaces for large-scale dropwise condensation. Transient dropwise condensation from a vapor phase onto a cold and chemically treated surface is reported. The surfaces were treated to deliver either a uniform contact-angle or a gradient of contact-angles by silanization. The time evolution of drop-size and number-density distributions is reported. For a typical condensation experiment, the drop distributions advance through two stages: an increase in drop density as a result of nucleation and a decrease in drop density as a result of larger scale coalescence events. Because the experiment is transient in nature, the shape of the distribution can be used to predict the number of drop generations and their stage of development. Preliminary results for gradient surfaces will be discussed and compared against observations of behavior on uniformly coated surfaces. NASA Space Technology Research Fellowship (NSTRF).

  17. Tachyon condensation and black hole entropy.

    Science.gov (United States)

    Dabholkar, Atish

    2002-03-04

    String propagation on a cone with deficit angle 2pi(1-1 / N) is considered for the purpose of computing the entropy of a large mass black hole. The entropy computed using the recent results on condensation of twisted-sector tachyons in this theory is found to be in precise agreement with the Bekenstein-Hawking entropy.

  18. Free convective condensation in a vertical enclosure

    Energy Technology Data Exchange (ETDEWEB)

    Fox, R.J.; Peterson, P.F. [Univ. of California, Berkeley, CA (United States); Corradini, M.L.; Pernsteiner, A.P. [Univ. of Wisconsin, Madison, WI (United States)

    1995-09-01

    Free convective condensation in a vertical enclosure was studied numerically and the results were compared with experiments. In both the numerical and experimental investigations, mist formation was observed to occur near the cooling wall, with significant droplet concentrations in the bulk. Large recirculation cells near the end of the condensing section were generated as the heavy noncondensing gas collecting near the cooling wall was accelerated downward. Near the top of the enclosure the recirculation cells became weaker and smaller than those below, ultimately disappearing near the top of the condenser. In the experiment the mist density was seen to be highest near the wall and at the bottom of the condensing section, whereas the numerical model predicted a much more uniform distribution. The model used to describe the formation of mist was based on a Modified Critical Saturation Model (MCSM), which allows mist to be generated once the vapor pressure exceeds a critical value. Equilibrium, nonequilibrium, and MCSM calculations were preformed, showing the experimental results to lie somewhere in between the equilibrium and nonequilibrium predictions of the numerical model. A single adjustable constant (indicating the degree to which equilibrium is achieved) is used in the model in order to match the experimental results.

  19. Condensing Organic Aerosols in a Microphysical Model

    Science.gov (United States)

    Gao, Y.; Tsigaridis, K.; Bauer, S.

    2015-12-01

    The condensation of organic aerosols is represented in a newly developed box-model scheme, where its effect on the growth and composition of particles are examined. We implemented the volatility-basis set (VBS) framework into the aerosol mixing state resolving microphysical scheme Multiconfiguration Aerosol TRacker of mIXing state (MATRIX). This new scheme is unique and advances the representation of organic aerosols in models in that, contrary to the traditional treatment of organic aerosols as non-volatile in most climate models and in the original version of MATRIX, this new scheme treats them as semi-volatile. Such treatment is important because low-volatility organics contribute significantly to the growth of particles. The new scheme includes several classes of semi-volatile organic compounds from the VBS framework that can partition among aerosol populations in MATRIX, thus representing the growth of particles via condensation of low volatility organic vapors. Results from test cases representing Mexico City and a Finish forrest condistions show good representation of the time evolutions of concentration for VBS species in the gas phase and in the condensed particulate phase. Emitted semi-volatile primary organic aerosols evaporate almost completely in the high volatile range, and they condense more efficiently in the low volatility range.

  20. Bose-Einstein condensation in quantum glasses

    OpenAIRE

    2009-01-01

    The role of geometrical frustration in strongly interacting bosonic systems is studied with a combined numerical and analytical approach. We demonstrate the existence of a novel quantum phase featuring both Bose-Einstein condensation and spin-glass behaviour. The differences between such a phase and the otherwise insulating "Bose glasses" are elucidated.

  1. Condensate formation in a Bose gas

    NARCIS (Netherlands)

    Stoof, H.T.C.

    1995-01-01

    Using magnetically trapped atomic hydrogen as an example, we investigate the prospects of achieving Bose-Einstein condensation in a dilute Bose gas. We show that, if gas is quenched sufficiently far into the critical region of the phase transition, the typical time scale for the nucleation of the co

  2. Capillary condensation as a morphological transition.

    Science.gov (United States)

    Kornev, Konstantin G; Shingareva, Inna K; Neimark, Alexander V

    2002-02-25

    The process of capillary condensation/evaporation in cylindrical pores is considered within the idea of symmetry breaking. Capillary condensation/evaporation is treated as a morphological transition between the wetting film configurations of different symmetry. We considered two models: (i) the classical Laplace theory of capillarity and (ii) the Derjaguin model which takes into account the surface forces expressed in terms of the disjoining pressure. Following the idea of Everett and Haynes, the problem of condensation/evaporation is considered as a transition from bumps/undulations to lenses. Using the method of phase portraits, we discuss the mathematical mechanisms of this transition hidden in the Laplace and Derjaguin equations. Analyzing the energetic barriers of the bump and lens formation, it is shown that the bump formation is a prerogative of capillary condensation: for the vapor-liquid transition in a pore, the bump plays the same role as the spherical nucleus in a bulk fluid. We show also that the Derjaguin model admits a variety of interfacial configurations responsible for film patterning at specific conditions.

  3. Neutrino emissivity under neutral kaon condensation

    OpenAIRE

    Kubis, Sebastian

    2005-01-01

    Neutrino emissivity from neutron star matter with neutral kaon condensate is considered. It is shown that a new cooling channel is opened, and what is more, all previously known channels acquire the greater emissivity reaching the level of the direct URCA cycle in normal matter.

  4. Bose-Einstein condensation of plexcitons

    CERN Document Server

    Rodriguez, S R K; Rivas, J Gomez

    2013-01-01

    Bosons (particles with integer spin) above a critical density to temperature ratio may macroscopically populate the ground state of a system, in an effect known as Bose-Einstein Condensation (BEC). The observation of BEC in dilute atomic gases was a great triumph of modern physics, a task requiring nK cooling of atoms. Following these demonstrations, a quest for lighter bosons enabling BEC at higher temperatures came to light. Photons in a microcavity were destined to fulfil this quest. Their coupling to semiconductor excitons allowed the condensation of exciton-polaritons at a few K in solid-state, and the condensation of photons was later observed in a liquid-state dye at room-temperature. Distinctly, one of the most actively studied excitations in condensed matter, surface plasmon polaritons - collective oscillations of conduction electrons in metals -, has never been shown or predicted to exhibit BEC. The strong radiative and Ohmic losses in metals, together with the lack of a suitable (e.g. harmonic) pot...

  5. Convection in Condensible-rich Atmospheres

    Science.gov (United States)

    Ding, F.; Pierrehumbert, R. T.

    2016-05-01

    Condensible substances are nearly ubiquitous in planetary atmospheres. For the most familiar case—water vapor in Earth’s present climate—the condensible gas is dilute, in the sense that its concentration is everywhere small relative to the noncondensible background gases. A wide variety of important planetary climate problems involve nondilute condensible substances. These include planets near or undergoing a water vapor runaway and planets near the outer edge of the conventional habitable zone, for which CO2 is the condensible. Standard representations of convection in climate models rely on several approximations appropriate only to the dilute limit, while nondilute convection differs in fundamental ways from dilute convection. In this paper, a simple parameterization of convection valid in the nondilute as well as dilute limits is derived and used to discuss the basic character of nondilute convection. The energy conservation properties of the scheme are discussed in detail and are verified in radiative-convective simulations. As a further illustration of the behavior of the scheme, results for a runaway greenhouse atmosphere for both steady instellation and seasonally varying instellation corresponding to a highly eccentric orbit are presented. The latter case illustrates that the high thermal inertia associated with latent heat in nondilute atmospheres can damp out the effects of even extreme seasonal forcing.

  6. Condensation enhancement by means of electrohydrodynamic techniques

    Directory of Open Access Journals (Sweden)

    Butrymowicz Dariusz

    2014-12-01

    Full Text Available Short state-of-the-art on the enhancement of condensation heat transfer techniques by means of condensate drainage is presented in this paper. The electrohydrodynamic (EHD technique is suitable for dielectric media used in refrigeration, organic Rankine cycles and heat pump devices. The electric field is commonly generated in the case of horizontal tubes by means of a rod-type electrode or mesh electrodes. Authors proposed two geometries in the presented own experimental investigations. The first one was an electrode placed just beneath the tube bottom and the second one consisted of a horizontal finned tube with a double electrode placed beneath the tube. The experimental investigations of these two configurations for condensation of refrigerant R-123 have been accomplished. The obtained results confirmed that the application of the EHD technique for the investigated tube and electrode arrangement caused significant increase in heat transfer coefficient. The condensation enhancement depends both on the geometry of the electrode system and on the applied voltage.

  7. Orientifold Planar Equivalence: The Chiral Condensate

    DEFF Research Database (Denmark)

    Armoni, Adi; Lucini, Biagio; Patella, Agostino

    2008-01-01

    The recently introduced orientifold planar equivalence is a promising tool for solving non-perturbative problems in QCD. One of the predictions of orientifold planar equivalence is that the chiral condensates of a theory with $N_f$ flavours of Dirac fermions in the symmetric (or antisymmetric...

  8. Tachyon Condensation in Rotated Brane Configurations

    CERN Document Server

    de Alwis, S P

    1999-01-01

    The decay of rotated brane configurations and the corresponding condensation of tachyons is discussed. In a certain IIB orbifold case a heuristic argument about the mass of the state living on the fixed plane is made. When the rotation angle is $\\pi$ this mass agrees with that obtained by Sen.

  9. Capillary condensation between disks in two dimensions

    DEFF Research Database (Denmark)

    Gil, Tamir; Ipsen, John Hjorth

    1997-01-01

    Capillary condensation between two two-dimensional wetted circular substrates (disks) is studied by an effective free energy description of the wetting interface. The interfacial free-energy potential is developed on the basis of the theory for the wetting of a single disk, where interfacial capi....... The theory can be applied to the description of flocculations in two-dimensional systems of colloids....

  10. Ultrafine Condensation Particle Counter Instrument Handbook

    Energy Technology Data Exchange (ETDEWEB)

    Kuang, C. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2016-02-01

    The Model 3776 Ultrafine Condensation Particle Counter (UCPC; pictured in Appendix A) is designed for researchers interested in airborne particles smaller than 20 nm. With sensitivity to particles down to 2.5 nm in diameter, this UCPC is ideally suited for atmospheric and climate research, particle formation and growth studies, combustion and engine exhaust research, and nanotechnology research.

  11. Activity, purification, and analysis of condensed tannins

    Science.gov (United States)

    As a class of plant polyphenolic compounds contained in some forages (i.e., sanfoin, big trefoil, birdfoot trefoil), condensed tannins (CTs), also referred to as proanthocyanidins (PAs), exhibit a variety of biological effects on ruminants and on the dairy farm nitrogen cycle. Interest in CTs stems ...

  12. ISOSPIN BREAKING AND THE CHIRAL CONDENSATE.

    Energy Technology Data Exchange (ETDEWEB)

    CREUTZ, M.

    2005-07-25

    With two degenerate quarks, the chiral condensate exhibits a jump as the quark masses pass through zero. I discuss how this single transition splits into two Ising like transitions when the quarks are made non-degenerate. The order parameter is the expectation of the neutral pion field. The transitions represent long distance coherent phenomena occurring without the Dirac operator having vanishingly small eigenvalues.

  13. Chaos in a Bose-Einstein condensate

    Institute of Scientific and Technical Information of China (English)

    Wang Zhi-Xia; Ni Zheng-Guo; Cong Fu-Zhong; Liu Xue-Shen; Chen Lei

    2010-01-01

    It is demonstrated that Smale-horseshoe chaos exists in the time evolution of the one-dimensional Bose-Einstein condensate driven by time-periodic harmonic or inverted-harmonic potential.A formally exact solution of the timedependent Gross-Pitaevskii equation is constructed,which describes the matter shock waves with chaotic or periodic amplitudes and phases.

  14. Initial stages of Bose-Einstein condensation

    NARCIS (Netherlands)

    Stoof, H.T.C.

    1997-01-01

    We present the quantum theory for the nucleation of Bose-Einstein condensation in a dilute atomic Bose gas. This quantum theory has the important advantage that both the kinetic and coherent stages of the nucleation process can be described in a unified way by a single Fokker-Planck equation.

  15. Initial stages of Bose-Einstein condensation

    NARCIS (Netherlands)

    Stoof, H.T.C.

    2001-01-01

    We present the quantum theory for the nucleation of Bose-Einstein condensation in a dilute atomic Bose gas. This quantum theory confirms the results of the semiclassical treatment, but has the important advantage that both the kinetic and coherent stages of the nucleation process can now be describe

  16. Neutrino emissivity under neutral kaon condensation

    CERN Document Server

    Kubis, S

    2006-01-01

    Neutrino emissivity from neutron star matter with neutral kaon condensate is considered. It is shown that a new cooling channel is opened, and what is more, all previously known channels acquire the greater emissivity reaching the level of the direct URCA cycle in normal matter.

  17. Interaction between ionic lattices and superconducting condensates

    OpenAIRE

    2007-01-01

    The interaction of the ionic lattice with the superconducting condensate is treated in terms of the electrostatic force in superconductors. It is shown that this force is similar but not identical to the force suggested by the volume difference of the normal and superconducting states. The BCS theory shows larger deviations than the two-fluid model.

  18. Condensation in Saturn's Stratospheric Haze Layers

    Science.gov (United States)

    Barth, Erika L.; Moses, Julianne I.

    2016-10-01

    Haze particles in Saturn's stratosphere can be seen in the visible limb images of Cassini's Imaging Science Subsystem (ISS). These hazes are likely a mix of particles, including solid organics formed as a result of methane photolysis and electron deposition, as well as the condensation of water and hydrocarbon ices. We have examined data from both Cassini and Voyager to study the detailed vertical structure of absorbing/scattering particulates in Saturn's stratosphere and developed a Saturn version of the Community Aerosol and Radiation Model for Atmospheres (CARMA), adding a large database of hydrocarbons that are observed or expected to be present in Saturn's atmosphere.Our modeling indicates that water ice condenses independently of the hydrocarbons to form a thin layer above the 0.1 mbar pressure level. Between about 5 and 50 mbar, the hydrocarbons reach their condensation levels (in order of increasing pressure level): C6H6, C5H12, C4H2, C4H10, and C2H2. Because of the proximity of their condensation levels and due to the gravitational settling of the particles, the hydrocarbons are likely condensing on one another and forming a thicker layer of mixed composition. Interestingly, butane (C4H10) has a triple point around 135 K which is much lower than most of the other condensing species we've explored. Given an approximate condensation level of 10 mbar and the observed temperature changes at this pressure level following the December 2010 northern-hemisphere storm (stratospheric temperatures were elevated by as much as 50-70 K in a region near 40° N latitude.), melting and further nucleation of droplets could be occurring.A number of factors including temperature profile, vapor pressure equation, volatile abundance, nucleation critical saturation, and coagulation efficiency will affect the altitudes of the individual ice layers. We will present a summary of results following the nucleation and growth of compounds in order to quantify the likely size and

  19. The effect of condensate inundation on steam condensation heat transfer to wire-wrapped tubing

    Science.gov (United States)

    Kanakis, G. D.

    1983-06-01

    Steam condensation heat transfer measurements were made in a 5-tube test condenser having an additional perforated tube to simulate up to 30 active tubes. Results were obtained for smooth tubes and roped tubes wrapped with wire. A Sieder-Tate equation was used to correlate the inside heat-transfer coefficient. For smooth tubes, a leading coefficient of 0.029 was found, while it was 0.061 for the roped tubes. The average condensing coefficient measured for 30 smooth tubes was 0.59 times the Nusselt coefficient calculated for the first tube. When the smooth tubes were wrapped with wire, this ratio increased up to 0.86. Further, roped tubes without wire experienced a ratio of 0.63, while roped tubes wrapped with wire resulted in a ratio of 0.86. These preliminary data show that wire-wrapped tubes may lead to a significant reduction in condenser surface area.

  20. Critical temperature and condensed fraction of Bose-Einstein condensation in optical lattices

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Critical temperature and condensate fraction of Bose-Einstein condensation in the optical lattice are studied. The results show that the critical temperature in optical lattices can be characterized with an equivalent critical temperature in a single lattice, which provide a fast evaluation of critical temperature and condensate fraction of Bose-Einstein condensation confined with pure optical trap. Critical temperature can be estimated with an equivalent critical temperature. It is predicted that critical temperature is proportional to q in q number lattices for superfluid state and should be equal to that in a single lattic for Mott insulate state. Required potential depth or Rabi frequency and maximum atom number in the lattices both for superfluid state and Mott state are presented based on views of thermal mechanical statistics.

  1. Refrigeration. Heat Transfer. Part I: Evaporators and Condensers

    DEFF Research Database (Denmark)

    Knudsen, Hans-Jørgen Høgaard

    2002-01-01

    The note gives an introduction to heat transfer with phase shift. Pool Boiling, Flow Boiling, Condensation.......The note gives an introduction to heat transfer with phase shift. Pool Boiling, Flow Boiling, Condensation....

  2. Effect of CEFR Condenser Pressure on Thermal Efficiency

    Institute of Scientific and Technical Information of China (English)

    DING; Tong-wei; ZHANG; Huan-qi

    2012-01-01

    <正>China Experimental Fast Reactor (CEFR) use two horizontal dual-flow condensers, circulating watersystem and vacuum system using fixed-speed pumps, therefore, thermal efficiency depends largely on thelevel of condenser pressure.

  3. Condensation: Passenger Not Driver in Atmospheric Thermodynamics

    Directory of Open Access Journals (Sweden)

    Jack Denur

    2016-11-01

    Full Text Available The second law of thermodynamics states that processes yielding work or at least capable of yielding work are thermodynamically spontaneous, and that those costing work are thermodynamically nonspontaneous. Whether a process yields or costs heat is irrelevant. Condensation of water vapor yields work and hence is thermodynamically spontaneous only in a supersaturated atmosphere; in an unsaturated atmosphere it costs work and hence is thermodynamically nonspontaneous. Far more of Earth’s atmosphere is unsaturated than supersaturated; based on this alone evaporation is far more often work-yielding and hence thermodynamically spontaneous than condensation in Earth’s atmosphere—despite condensation always yielding heat and evaporation always costing heat. Furthermore, establishment of the unstable or at best metastable condition of supersaturation, and its maintenance in the face of condensation that would wipe it out, is always work-costing and hence thermodynamically nonspontaneous in Earth’s atmosphere or anywhere else. The work required to enable supersaturation is most usually provided at the expense of temperature differences that enable cooling to below the dew point. In the case of most interest to us, convective weather systems and storms, it is provided at the expense of vertical temperature gradients exceeding the moist adiabatic. Thus, ultimately, condensation is a work-costing and hence thermodynamically nonspontaneous process even in supersaturated regions of Earth’s or any other atmosphere. While heat engines in general can in principle extract all of the work represented by any temperature difference until it is totally neutralized to isothermality, convective weather systems and storms in particular cannot. They can extract only the work represented by partial neutralization of super-moist-adiabatic lapse rates to moist-adiabaticity. Super-moist-adiabatic lapse rates are required to enable convection of saturated air

  4. Mechanocaloric and Thermomechanical Effects in Bose-Einstein Condensed Systems

    OpenAIRE

    Marques, G. C.; Bagnato, V. S.; Muniz, S. R.; Spehler, D.

    2005-01-01

    In this paper we extend previous hydrodynamic equations, governing the motion of Bose-Einstein-condensed fluids, to include temperature effects. This allows us to analyze some differences between a normal fluid and a Bose-Einstein-condensed one. We show that, in close analogy with superfluid He-4, a Bose-Einstein-condensed fluid exhibits the mechanocaloric and thermomechanical effects. In our approach we can explain both effects without using the hypothesis that the Bose-Einstein-condensed fl...

  5. Transient behavior of a radiative distiller/condenser system

    Energy Technology Data Exchange (ETDEWEB)

    Haddad, O.M.; Al-Nimr, M.A. [Jordan Univ. of Science and Technology, Dept. of Mechanical Engineering, Irbid (Jordan)

    2002-04-01

    In this work, a mathematical model is proposed to describe the thermal performance of a radiative distiller under transient conditions. The parameters which cause the dynamic variation in the condenser performance are the finite thermal capacity of the radiative condenser panel, effective sky-temperature, ambient temperature, humidity ratio and the condensers overall heat transfer coefficient. The presented model is solved numerically and the effects of the design and operating conditions on the condensers performance are investigated. (Author)

  6. Inhomogeneous Polyakov loop induced by inhomogeneous chiral condensates

    Directory of Open Access Journals (Sweden)

    Tomoya Hayata

    2015-05-01

    Full Text Available We study the spatial inhomogeneity of the Polyakov loop induced by inhomogeneous chiral condensates. We formulate an effective model of gluons on the background fields of chiral condensates, and perform its lattice simulation. On the background of inhomogeneous chiral condensates, the Polyakov loop exhibits an in-phase spatial oscillation with the chiral condensates. We also analyze the heavy quark potential and show that the inhomogeneous Polyakov loop indicates the inhomogeneous confinement of heavy quarks.

  7. Inhomogeneous Polyakov loop induced by inhomogeneous chiral condensates

    Energy Technology Data Exchange (ETDEWEB)

    Hayata, Tomoya, E-mail: hayata@riken.jp [Department of Physics, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Theoretical Research Division, Nishina Center, RIKEN, Wako, Saitama 351-0198 (Japan); Yamamoto, Arata [Department of Physics, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Theoretical Research Division, Nishina Center, RIKEN, Wako, Saitama 351-0198 (Japan)

    2015-05-11

    We study the spatial inhomogeneity of the Polyakov loop induced by inhomogeneous chiral condensates. We formulate an effective model of gluons on the background fields of chiral condensates, and perform its lattice simulation. On the background of inhomogeneous chiral condensates, the Polyakov loop exhibits an in-phase spatial oscillation with the chiral condensates. We also analyze the heavy quark potential and show that the inhomogeneous Polyakov loop indicates the inhomogeneous confinement of heavy quarks.

  8. Estudo teórico da estrutura molecular, da espectroscopia vibracional e da reatividade de hidrazinas e aminas.

    OpenAIRE

    Marina Pelegrini

    2007-01-01

    O desenvolvimento desta tese se baseou em dois enfoques de estudo. Um dos enfoques é a caracterização energética de reações elementares que podem estar envolvidas na decomposição da molécula hidrazina, a qual desperta especial interesse por se tratar de uma molécula cuja decomposição é exotérmica e utilizada como combustível em foguetes e lançadores de satélites, além de outras muitas aplicações. Neste estudo teórico, as estruturas conformacionais, a espectroscopia vibracional e a energética ...

  9. Estrutura oracional e posição do verbo no português clássico

    Directory of Open Access Journals (Sweden)

    André Luis ANTONELLI

    2013-10-01

    Full Text Available À luz de pressupostos da Teoria de Princípios e Parâmetros em sua versão minimalista (CHOMSKY, 1995, e trabalhos subsequentes, o objetivo central do presente artigo é determinar a posição ocupada pelo verbo finito na estrutura oracional de sentenças declarativas da gramática do Português Clássico. Para isso, investigaremos a Grammatica da Lingoagem Portuguesa, obra de Fernão de Oliveira publicada em 1536, tomando-a como um texto representativo da gramática do período clássico do Português Europeu. Aqui, defenderemos que a posição final do verbo seja no núcleo da categoria funcional FP (no sentido de URIAGEREKA, 1995, localizada entre CP e TP.

  10. Estrutura oracional e posição do verbo no português clássico

    Directory of Open Access Journals (Sweden)

    André Luis ANTONELLI

    2008-12-01

    Full Text Available À luz de pressupostos da Teoria de Princípios e Parâmetros em sua versão minimalista (CHOMSKY, 1995, e trabalhos subsequentes, o objetivo central do presente artigo é determinar a posição ocupada pelo verbo finito na estrutura oracional de sentenças declarativas da gramática do Português Clássico. Para isso, investigaremos a Grammatica da Lingoagem Portuguesa, obra de Fernão de Oliveira publicada em 1536, tomando-a como um texto representativo da gramática do período clássico do Português Europeu. Aqui, defenderemos que a posição final do verbo seja no núcleo da categoria funcional FP (no sentido de URIAGEREKA, 1995, localizada entre CP e TP.

  11. Abordagem construtivista do erro na resolução de problemas de aritmética de estrutura aditiva

    OpenAIRE

    2006-01-01

    O Objectivo deste estudo é analisar o tipo de erro, estrutural ou funcional, observado em crianças dos 5 aos 8 anos, durante a resolução de três tipos de problemas aritméticos de estrutura aditiva . combinação, separação e comparação . em situações diferenciadas (manipulativa, figurativa, numérica). A amostra do estudo é constituída por 45 crianças (15 do último ano do pré-escolar, 15 do 1º ano de escolaridade e 15 do 2º ano) de uma escola pública de Lisboa, de meio sócio-económico médio. ...

  12. Entre a epistemologia e a ontologia: a teoria da estruturação de Anthony Giddens

    Directory of Open Access Journals (Sweden)

    Fábio Rodrigues Ribeiro da Silva

    2014-12-01

    Full Text Available O artigo ilustra algumas peculiaridades metodológicas do projeto teórico de Anthony Giddens, a teoria da estruturação. O diagnóstico é que ela tem menos influência na teoria social atual do que poderia ter. A causa desse problema é identificada na transição ontológica que Giddens realiza no fim dos anos de 1970, que, de modo não intencional, acaba enfraquecendo o arcabouço teórico-metodológico de seu projeto. A fim de ajudar a sanar o problema, sugere-se uma reconstrução metodológica com base no modelo de filosofia da ciência de Mary Hesse.

  13. Thomas Kuhn. O caminho desde a Estrutura: ensaios filosóficos 1970-1993, com uma entrevista autobiográfica

    Directory of Open Access Journals (Sweden)

    Tamires Dal Magro

    2012-08-01

    Full Text Available Resenha de KUHN, Thomas S. O caminho desde a Estrutura: ensaios filosóficos 1970-1993, com uma entrevista autobiográfica. (Ed. por James Conant e John Haugeland. Trad. Cezar Mortari. São Paulo: Editora UNESP, 2006.

  14. ESTRUTURA FUNDIÁRIA E DESENVOLVIMENTO HUMANO: UMA ANÁLISE PARA AS MICRORREGIÕES DO RIO GRANDE DO SUL

    Directory of Open Access Journals (Sweden)

    Adilson Giovanini

    2011-12-01

    Full Text Available A partir da perspectiva do desenvolvimento como expansão das capacitações de Amartya Sen, o artigo testa a hipótese de que a concentração fundiária pode ser um fator prejudicial ao desenvolvimento humano nas microrregiões do Rio Grande do Sul. A pesquisa se caracteriza como histórico-empírica na medida em que busca na história a contextualização da atual estrutura fundiária e estatística e econométrica uma vez que estima a relação entre indicadores de desenvolvimento humano e de estrutura fundiária. Para tanto, calcula-se a correlação e ajustam-se regressões múltiplas entre indicadores de estrutura fundiária e de desenvolvimento humano. Um dos resultados encontrados é o de que as microrregiões com uma estrutura fundiária mais desigual possuem piores indicadores de expectativa de vida ao nascer.

  15. Estrutura de um cerrado strico sensu na Gleba Cerrado Pé-de-Gigante, Santa Rita do Passa Quatro, SP

    Directory of Open Access Journals (Sweden)

    Fidelis Alessandra Tomaselli

    2003-01-01

    Full Text Available O Cerrado ocupa aproximadamente 23% do território brasileiro e 70% do bioma correspondem a cerrado stricto sensu (s.s., sendo relevantes os estudos que buscam o entendimento da estrutura da vegetação nessas áreas. Com esse objetivo, foram estudadas cinco parcelas (10×25m em um hectare de cerrado s.s., amostrando-se todos os indivíduos com perímetro no nível do solo igual ou acima de 3cm (exceto lianas e indivíduos mortos. Alguns parâmetros fitossociológicos foram analisados, assim como a distribuição de classes de diâmetro dos indivíduos amostrados e a estrutura vertical. Foram amostradas 1.747 indivíduos, distribuídos em 75 espécies, pertencentes a 31 famílias. A densidade total absoluta encontrada foi de 13.976 ind.ha-1 e a área basal total, de 4,902m². Leguminosae foi a família com o maior número de espécies (16. As espécies que apresentaram os maiores valores de Índice do Valor de Importância (IVI foram Anadenanthera falcata (Benth. Altschul, Myrcia guianensis (Aubl. DC., Xylopia aromatica (Lm. Mart., Ouratea spectabilis (Mart. Engl. e Pouteria ramiflora (Mart. Radlk. O Índice de Shannon encontrado foi de 3,623. A distribuição de classes de diâmetro apresentou curva na forma de "J" invertido, estando a maioria dos indivíduos na primeira classe. A área estudada não apresentou estratos bem definidos, estando a maioria dos indivíduos entre 1 e 3m de altura.

  16. Estrutura e dinâmica dos contratos na suinocultura de Santa Catarina: um estudo de casos múltiplos

    Directory of Open Access Journals (Sweden)

    Marcelo Miele

    2007-12-01

    Full Text Available O desempenho econômico recente da suinocultura brasileira deve-se aos avanços tecnológicos e organizacionais incorporados ao longo das duas últimas décadas, com destaque para a crescente participação dos contratos como forma de coordenação da cadeia produtiva. O objetivo deste trabalho é caracterizar a transação entre os suinocultores e as empresas e cooperativas agroindustriais que abatem e processam suínos em Santa Catarina, bem como a estrutura de incentivos e controles dos contratos que dão suporte a essa transação. Para tanto, utilizou-se uma metodologia de estudo de casos múltiplos, com 19 suinocultores entrevistados e a análise de 12 contratos. Os resultados apontam para a diversidade organizacional e sua dinâmica. A estrutura de incentivos e controles nos contratos aponta para a busca de objetivos econômicos e de eficiência técnica.The economic performance of the Brazilian swine and swine meat production was based on technological and organizational innovations, in which the contracts play an important role in the supply chain coordination. The goal of this research is to characterize the transaction among swine producers and slaughters and meat processors in Santa Catarina, Brazil, and the contract structure of incentives and controls which supports this transaction. The research technique employed is a multiple case study, with 19 interviews with swine producers and the analysis of 12 contracts. The results show an organizational diversity and its dynamics. The contract incentives and controls are structured to reach economic and efficiency goals.

  17. ESTRUTURA DE PROPRIEDADE E CONTROLE E ASSIMETRIA DE INFORMAÇÃO NO MERCADO ACIONÁRIO BRASILEIRO

    Directory of Open Access Journals (Sweden)

    Thamirys de Sousa Correia

    2015-12-01

    Full Text Available Esta pesquisa teve o objetivo de investigar a relação existente entre a estrutura de propriedade e controle das empresas e a assimetria da informação existente nas negociações de suas ações. Para isso, apoiou-se em um referencial acerca da Teoria da Agência, reportando as principais evidências da literatura de estrutura de propriedade e assimetria de informação. Foram analisados os dados das empresas listadas na BM&FBOVESPA entre 2008 a 2013, por meio de modelos de regressão Tobit, sendo possível observar evidências distintas para empresas que possuíam American Depository Receipt (ADR ou estavam no segmento Novo Mercado de governança corporativa e para as demais empresas. Para o primeiro grupo, verificou-se que a concentração de propriedade e controle apresentou relação positiva com a assimetria, considerando as proxies retorno anormal, volatilidade e beta. Essas evidências são ainda mais fortes com relação à concentração de controle, indicando que a assimetria poderia ser reduzida por meio da pulverização de ações. Por outro lado, entre as empresas sem ADR ou fora desse segmento, a concentração de propriedade e controle tendeu a reduzir a assimetria. Assim, como principal contribuição se destaca tal evidência, pois revela que a concentração de ações tem efeito diferente sobre a assimetria, conforme características da empresa.

  18. Estrutura fundiária brasileira: o trabalho de campo como alternativa pedagógica do ensino

    Directory of Open Access Journals (Sweden)

    Neli Angélica Frozza Ariotti

    2010-07-01

    Full Text Available No presente artigo procura-se compreender a organização da estrutura fundiária brasileira e verificar como esta tem sido abordada no ensino de Geografia. Para essa compreensão, realizou-se com os alunos da 2ª série do ensino médio, do Colégio Lassale, visitas in loco em pequenas e médias propriedades, onde foram verificadas as realidades vividas pelas pessoas que habitam esses locais, bem como a realização de entrevistas para maior conhecimento do trabalho e da utilização da terra por essas pessoas. De volta à sala de aula, os alunos puderam ler e analisar as respostas obtidas das entrevistas e confrontá-las com textos de três livros didáticos selecionados, que são cotidianamente utilizados pelos professores na disciplina de Geografia, abordando conteúdos sobre a estrutura fundiária brasileira. Os alunos perceberam que os textos trazidos pelos livros não retratam claramente a realidade encontrada, principalmente, sobre a pequena propriedade. Os textos enfatizam a importância dos latifúndios, sua produção e destino dos produtos colhidos, mencionando, superficialmente, a existência das pequenas propriedades, do trabalho desenvolvido pela família e sua importância na produção de alimentos interna ao país e para a condição social desses grupos.

  19. O PAPEL DE ESTRUTURAS PROSÓDICAS E MORFOSSINTÁTICAS EM HIPOSSEGMENTAÇÕES DO ENSINO FUNDAMENTAL II

    Directory of Open Access Journals (Sweden)

    Luciani Ester Tenani

    2016-12-01

    Full Text Available Neste artigo, investigamos possíveis motivações linguísticas para ocorrer hipossegmentações (como “concerteza”, “jogalo” em textos escritos por alunos ao longo dos quatro últimos anos do Ensino Fundamental. Assumimos a premissa de que as hipossegmentações são resultados de relações entre fala e escrita nas quais os alunos se baseiam ao produzirem seus textos. Essas relações mobilizam, principalmente, estruturas prosódicas e morfossintáticas, além de informações letradas sobre fronteiras gráficas de palavra escrita. No que diz respeito à abordagem da prosódia, adotamos a perspectiva que a concebe como constitutiva da língua, seja falada ou escrita. Os resultados mostram que: (i a principal regularidade prosódica é a junção de clítico mais palavra prosódica que o segue, evidenciando que a prosodização de clíticos à direita guia os registros escritos observados; (ii a regularidade morfossintática predominante é a hipossegmentação de preposições, além de artigos, conjunções, pronomes átonos, evidenciando dificuldades na delimitação de palavras gramaticais como palavras ortográficas independentes. Quanto à distribuição de dados ao longo dos anos letivos, houve aumento de hipossegmentações que envolvem sequência de clíticos monossilábicos no nono ano, resultado que evidencia que estrutura linguística ainda não é dominada pelos estudantes ao final do Ensino Fundamental.

  20. A definição de activos nas estruturas conceptuais da informação financeira

    Directory of Open Access Journals (Sweden)

    Manuel Castelo Branco

    2005-12-01

    Full Text Available As estruturas conceptuais da informação financeira têm procurado definir, nomeadamente, os objectivos subjacentes à preparação e apresentação da informação financeira, as características qualitativas dessa informação, os elementos das demonstrações financeiras e os critérios para o seu reconhecimento e mensuração. Neste trabalho, procura-se mostrar quais são as questões mais importantes a serem resolvidas na definição dos elementos das demonstrações financeiras e a forma como as principais estruturas conceptuais lidaram com elas, designadamente no que diz respeito à definição de activos. Identifica-se uma evolução na definição de activos, argumentando-se que a definição apresentada pelo Accounting Standards Board do Reino Unido é a mais adequada das apresentadas até ao momento.Conceptual framework documents deal with the objectives of financial reporting, the qualitative characteristics of financial information, the definitions of the elements of financial statements and the criteria for their recognition and measurement. This paper addresses the most important issues to be dealt with when defining the elements of financial statements and the way in which the main conceptual frameworks resolves such issues, namely in terms of the definition of assets. An evolution in the definition of assets is identified, and the definition presented by the UK Accounting Standards Board is considered to be the most appropriate among those presented thus far.

  1. Observation of water condensate on hydrophobic micro textured surfaces

    Science.gov (United States)

    Kim, Ki Wook; Do, Sang Cheol; Ko, Jong Soo; Jeong, Ji Hwan

    2013-07-01

    We visually observed that a dropwise condensation occurred initially and later changed into a filmwise condensation on hydrophobic textured surface at atmosphere pressure condition. It was observed that the condensate nucleated on the pillar side walls of the micro structure and the bottom wall adhered to the walls and would not be lifted to form a spherical water droplet using environmental scanning electron microscope.

  2. Phase diffusion in a Bose-Einstein condensate of light

    NARCIS (Netherlands)

    De Leeuw, A. W.; Van Der Wurff, E. C I; Duine, R. A.; Stoof, H. T C

    2014-01-01

    We study phase diffusion in a Bose-Einstein condensate of light in a dye-filled optical microcavity, i.e., the spreading of the probability distribution for the condensate phase. To observe this phenomenon, we propose an interference experiment between the condensed photons and an external laser. We

  3. 21 CFR 131.120 - Sweetened condensed milk.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 2 2010-04-01 2010-04-01 false Sweetened condensed milk. 131.120 Section 131.120... FOR HUMAN CONSUMPTION MILK AND CREAM Requirements for Specific Standardized Milk and Cream § 131.120 Sweetened condensed milk. (a) Description. Sweetened condensed milk is the food obtained by partial...

  4. Electric field enhanced dropwise condensation on hydrophobic surfaces

    Science.gov (United States)

    Baratian, Davood; Hoek, Harmen; van den Ende, Dirk; Mugele, Frieder; Physics of Complex Fluids Team

    2016-11-01

    Dropwise condensation occurs when vapor condenses on a low surface energy surface, and the substrate is just partially wetted by the condensate. Dropwise condensation has attracted significant attention due to its reported superior heat transfer performance compared to filmwise condensation. Extensive research efforts are focused on how to promote, and enhance dropwise condensation by considering both physical and chemical factors. We have studied electrowetting-actuated condensation on hydrophobic surfaces, aiming for enhancement of heat transfer in dropwise condensation. The idea is to use suitably structured patterns of micro-electrodes that generate a heterogeneous electric field at the interface and thereby promote both the condensation itself and the shedding of condensed drops. Comforting the shedding of droplets on electrowetting-functionalized surfaces allows more condensing surface area for re-nucleation of small droplets, leading to higher condensation rates. Possible applications of this innovative concept include heat pipes for (micro) coolers in electronics as well as in more efficient heat exchangers. We acknowledge financial support by the Dutch Technology Foundation STW, which is part of the Netherlands Organization for Scientific Research (NWO), within the VICI program.

  5. 40 CFR 721.5713 - Phenol - biphenyl polymer condensate (generic).

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Phenol - biphenyl polymer condensate... Specific Chemical Substances § 721.5713 Phenol - biphenyl polymer condensate (generic). (a) Chemical... as a phenol - biphenyl polymer condensate (PMN P-00-1220) is subject to reporting under this...

  6. Collapsing dynamics of attractive Bose-Einstein condensates

    DEFF Research Database (Denmark)

    Bergé, L.; Juul Rasmussen, J.

    2002-01-01

    The self-similar collapse of 3D and quasi-2D atom condensates with negative scattering length is examined. 3D condensates are shown to blow up following the scenario of weak collapse, for which 3-body recombination weakly dissipates the atoms. In contrast, 2D condensates undergo a strong collapse...

  7. Análise de Estruturas Morfológicas da Cauda de Plasma do Cometa P/Halley

    Science.gov (United States)

    Voelzke, M. R.; Matsuura, O. T.

    1997-08-01

    531 imagens contidas no The International Halley Watch Atlas of Large-Scale Phenomena (Brandt et al., 1992) cobrindo o período de setembro de 1985 a julho de 1986 foram analisadas visando identificar, caracterizar as propriedades e correlacionar estruturas morfológicas da cauda de plasma do cometa P/Halley. A análise revelou 151 estruturas ondulatórias, 146 ondas solitárias (sólitons), 12 caudas do tipo Swan (Hyder et al., 1974; Niedner & Brandt, 1980; Jockers, 1985), 47 eventos de desconexão (D.E.'s) (Niedner & Brandt, 1979; Jockers, 1985; Celnik et al., 1988; Delva et al., 1991) e 23 regiões de adensamento ("knots") (Matsuura & Voelzke, 1990; Voelzke, 1996). - feita uma análise comparativa com outros trabalhos similares objetivando disciplinar a nomenclatura das estruturas morfológicas e a sua classificação. As estruturas ondulatórias correspondem a ondulaçóes ou trens de onda, enquanto que os sólitons referem-se a estruturas morfológicas usualmente denominadas "kinks" (Tomita et al., 1987). O valor médio do comprimento de onda, corrigido dos efeitos de projeção, Lc medido em 16 estruturas ondulatórias distintas corresponde a (2,2 +- 0,2) x 10^6 km. O valor médio da velocidade de fase cometocêntrica, corrigida dos efeitos de projeção, Vfc é igual a (114 +- 31) km/s e a amplitude média A da onda corresponde a (2,8 +- 0,5) x 10^5 km. Lc e A tendem a aumentar com o incremento da distància cometocêntrica. As ondas são claramente não-lineares e é discutido o local de sua excitação. A distribuição dos D.E.'s na distància heliocêntrica apresenta um caráter bimodal possivelmente associado com a distribuição espacial das fronteiras de setor magnético do meio interplanetário. Em geral, pode-se associar a ocorrência de um "knot" e/ou de uma cauda do tipo Swan com a ocorrência de um D.E., mas este último pode ocorrer independentemente. Os 47 D.E.'s em diferentes fases de evolução foram fotografados em 47 imagens distintas que

  8. INDICADORES ECONÔMICO-FINANCEIROS E OS DETERMINANTES DA ESTRUTURA DE CAPITAL DAS EMPRESAS DO SETOR DE SERVIÇOS: UMA ANÁLISE DE DADOS EM PAINEL

    Directory of Open Access Journals (Sweden)

    Marcelo Afonso Vieira Brunozi

    2016-12-01

    Full Text Available Pesquisas sobre a estrutura de capital das empresas possuem participação significativa e relevante na área de Finanças. Diversas abordagens empíricas e teóricas buscam explicar os determinantes e as escolhas das estruturas de capital nas firmas. Nesse sentido, o presente estudo analisou os fatores determinantes da estrutura de capital nas empresas do setor de serviços brasileiras com a argumentação teórica da Pecking Order (POT. Discutiu-se a hierarquia das fontes de financiamentos nas empresas. Metodologicamente, a pesquisa considerou empresas de capital aberto do setor de serviços no período de 2007 a 2013. Com a aplicação de Dados em Painel consideraram-se para a composição do modelo as variáveis de endividamento (dependente, tamanho, tangibilidade, market to book, lucratividade, liquidez (folga financeira, ciclo operacional e giro do ativo (independentes. Os resultados mostraram a aceitação parcial das hipóteses. Observou-se que, somente tangibilidade não se apresentou como métrica explicativa para a estrutura de capital. As variáveis folga financeira e lucratividade foram significativas e corroboraram com as pressuposições da POT. Em contrapartida, apesar de apresentarem significâncias com a estrutura de capital, as variáveis, market to book, indicando preferências para a emissão de ações e, tamanho, ciclo operacional e giro do ativo, com direcionamentos às dívidas, contradisseram a POT.

  9. Tunneling of trapped-atom Bose condensates

    Indian Academy of Sciences (India)

    Subodh R Shenoy

    2002-02-01

    We obtain the dynamics in number and phase difference, for Bose condensates that tunnel between two wells of a double-well atomic trap, using the (nonlinear) Gross–Pitaevskii equation. The dynamical equations are of the canonical form for the two conjugate variables, and the Hamiltonian corresponds to that of a momentum-shortened pendulum, supporting a richer set of tunneling oscillation modes than for a superconductor Josephson junction, that has a fixed-length pendulum as a mechanical model. Novel modes include ‘inverted pendulum’ oscillations with an average angle of ; and oscillations about a self-maintained population imbalance that we term ‘macroscopic quantum self-trapping’. Other systems with this phase-number nonlinear dynamics include two-component (interconverting) condensates in a single harmonic trap, and He3B superfluids in two containers connected by micropores.

  10. Confinement versus Bose-Einstein condensation

    CERN Document Server

    Langfeld, K

    2004-01-01

    The deconfinement phase transition at high baryon densities and low temperatures evades a direct investigation by means of lattice gauge calculations. In order to make this regime of QCD accessible by computer simulations, two proposal are made: (i) A Lattice Effective Theory (LET) is designed which incorporates gluon and diquark fields. The deconfinement transition takes place when the diquark fields undergo Bose-Einstein condensation. (ii) Rather than using eigenstates of the particle number operator, I propose to perform simulations for a fixed expectation value of the baryonic Noether current. This approach changes the view onto the finite density regime, but evades the sign and overlap problems. The latter proposal is exemplified for the LET: Although the transition from the confinement to the condensate phase is first order in the coupling constant space at zero baryon densities, the transition at finite densities appears to be a crossover.

  11. Hydrogen behavior in ice condenser containments

    Energy Technology Data Exchange (ETDEWEB)

    Lundstroem, P.; Hongisto, O. [Power Plant Lab., Helsinki (Finland); Theofanous, T.G. [Univ. of California, Santa Barbara, CA (United States)] [and others

    1995-09-01

    A new hydrogen management strategy is being developed for the Loviisa ice condenser containment. The strategy relies on containment-wide natural circulations that develop, once the ice condenser doors are forced open, to effectively produce a well-mixed behavior, and a correspondingly slow rise in hydrogen concentration. Levels can then be kept low by a distributed catalytic recombiner system, and (perhaps) an igniter system as a backup, while the associated energy releases can be effectively dissipated in the ice bed. Verification and fine-tuning of the approach is carried out experimentally in the VICTORIA facility and by associated scaling/modelling studies. VICTORIA represents an 1/15th scale model of the Loviisa containment, hydrogen is simulated by helium, and local concentration measurements are obtained by a newly developed instrument specifically for this purpose, called SPARTA. This paper is focused on experimental results from several key experiments that provide a first delineation of key behaviors.

  12. Astrophysical Bose-Einstein Condensates and Superradiance

    CERN Document Server

    Kuhnel, Florian

    2014-01-01

    We investigate gravitational analogue models to describe slowly rotating objects (e.g., dark-matter halos, or boson stars) in terms of Bose-Einstein condensates, trapped in their own gravitational potentials. We begin with a modified Gross-Pitaevskii equation, and show that the resulting background equations of motion are stable, as long as the rotational component is treated as a small perturbation. The dynamics of the fluctuations of the velocity potential are effectively governed by the Klein-Gordon equation of a "Eulerian metric", where we derive the latter by the use of a relativistic Lagrangian extrapolation. Superradiant scattering on such objects is studied. We derive conditions for its occurence and estimate its strength. Our investigations might give an observational handle to phenomenologically constrain Bose-Einstein condensates.

  13. Astrophysical Bose-Einstein condensates and superradiance

    Science.gov (United States)

    Kühnel, Florian; Rampf, Cornelius

    2014-11-01

    We investigate gravitational analogue models to describe slowly rotating objects (e.g., dark-matter halos, or boson stars) in terms of Bose-Einstein condensates, trapped in their own gravitational potentials. We begin with a modified Gross-Pitaevskii equation, and show that the resulting background equations of motion are stable, as long as the rotational component is treated as a small perturbation. The dynamics of the fluctuations of the velocity potential are effectively governed by the Klein-Gordon equation of an "Eulerian metric," where we derive the latter by the use of a relativistic Lagrangian extrapolation. Superradiant scattering on such objects is studied. We derive conditions for its occurrence and estimate its strength. Our investigations might give an observational handle to phenomenologically constrain Bose-Einstein condensates.

  14. Condensing Heat Exchanger with Hydrophilic Antimicrobial Coating

    Science.gov (United States)

    Thomas, Christopher M. (Inventor); Ma, Yonghui (Inventor)

    2014-01-01

    A multi-layer antimicrobial hydrophilic coating is applied to a substrate of anodized aluminum, although other materials may form the substrate. A silver layer is sputtered onto a thoroughly clean anodized surface of the aluminum to about 400 nm thickness. A layer of crosslinked, silicon-based macromolecular structure about 10 nm thickness overlies the silver layer, and the outermost surface of the layer of crosslinked, silicon-based macromolecular structure is hydroxide terminated to produce a hydrophilic surface with a water drop contact angle of less than 10.degree.. The coated substrate may be one of multiple fins in a condensing heat exchanger for use in the microgravity of space, which has narrow channels defined between angled fins such that the surface tension of condensed water moves water by capillary flow to a central location where it is pumped to storage. The antimicrobial coating prevents obstruction of the capillary passages.

  15. Quantum Effects of Bose-Einstein Condensates

    Institute of Scientific and Technical Information of China (English)

    YU Zhao-Xian; JIAO Zhi-Yong; SUN Jin-Zuo

    2004-01-01

    In this paper,we study quadrature squeezings of two Bose-Einstein condensates with collision and nonclassical properties of pair entanglement in four wave mixing in Bose-Einstein condensates.With the aid of a numerical method,we find that the two modes(pair entanglement modes)a1 and a2 may exhibit quadrature squeezing,in which they are affected by the initial phase.It is shown that the two pump modes exhibit the same super-Poissonian distribution.The analysis for the mode-mode correlation shows that there always exists a violation of the Cauchy-Schwartz inequality,which means that correlation between the two pump modes is nonclassical.

  16. Solitonic vortices in Bose-Einstein condensates

    Science.gov (United States)

    Tylutki, M.; Donadello, S.; Serafini, S.; Pitaevskii, L. P.; Dalfovo, F.; Lamporesi, G.; Ferrari, G.

    2015-04-01

    We analyse, theoretically and experimentally, the nature of solitonic vortices (SV) in an elongated Bose-Einstein condensate. In the experiment, such defects are created via the Kibble-Zurek mechanism, when the temperature of a gas of sodium atoms is quenched across the BEC transition, and are imaged after a free expansion of the condensate. By using the Gross-Pitaevskii equation, we calculate the in-trap density and phase distributions characterizing a SV in the crossover from an elongated quasi-1D to a bulk 3D regime. The simulations show that the free expansion strongly amplifies the key features of a SV and produces a remarkable twist of the solitonic plane due to the quantized vorticity associated with the defect. Good agreement is found between simulations and experiments.

  17. Statistical steady state in turbulent droplet condensation

    CERN Document Server

    Siewert, Christoph; Krstulovic, Giorgio

    2016-01-01

    Motivated by the early stages of clouds and other systems in which droplets grow and shrink in a turbulence-driven supersaturation field, we investigate the problem of turbulent condensation using direct numerical simulations. The turbulent fluctuations of the supersaturation field offer different conditions for the growth of droplets which evolve in time due to turbulent transport and mixing. Based on that, we propose a Lagrangian stochastic model for condensation and evaporation of small droplets in turbulent flows. It consists of a set of stochastic integro-differential equations for the joint evolution of the squared radius and the supersaturation along the droplet trajectories. The model has two parameters fixed by the total amount of water and the thermodynamic properties, as well as the Lagrangian integral timescale of the turbulent supersaturation. The model reproduces very well the droplet size distributions obtained from direct numerical simulations and their time evolution. A noticeable result is t...

  18. Electrostrong Nuclear Disintegration in Condensed Matter

    CERN Document Server

    Swain, J; Widom, A

    2013-01-01

    Photo- and electro-disintegration techniques have been traditionally used for studying giant dipole resonances and through them nuclear structure. Over a long period, detailed theoretical models for the giant dipole resonances were proposed and low energy electron accelerators were constructed to perform experiments to test their veracity. More recently, through laser and "smart" material devices, electrons have been accelerated in condensed matter systems up to several tens of MeV. We discuss here the possibility of inducing electro-disintegration of nuclei through such devices. It involves a synthesis of electromagnetic and strong forces in condensed matter via giant dipole resonances to give an effective "electro-strong interaction" - a large coupling of electromagnetic and strong interactions in the tens of MeV range.

  19. Essence of the Vacuum Quark Condensate

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, Stanley J.; /SLAC /Southern Denmark U., CP3-Origins; Roberts, Craig D.; /Argonne, PHY /Peking U.; Shrock, Robert; /YITP, Stony Brook; Tandy, Peter C.; /Kent State U.

    2010-08-25

    We show that the chiral-limit vacuum quark condensate is qualitatively equivalent to the pseudoscalar meson leptonic decay constant in the sense that they are both obtained as the chiral-limit value of well-defined gauge-invariant hadron-to-vacuum transition amplitudes that possess a spectral representation in terms of the current-quark mass. Thus, whereas it might sometimes be convenient to imagine otherwise, neither is essentially a constant mass-scale that fills all spacetime. This means, in particular, that the quark condensate can be understood as a property of hadrons themselves, which is expressed, for example, in their Bethe-Salpeter or light-front wavefunctions.

  20. TAPS condensers - 12 years of operating experience

    Energy Technology Data Exchange (ETDEWEB)

    Srinivasan, V.S. (Tarapur Atomic Power Station (India))

    This paper describes briefly the 12 years of operating experience of TAPS condensers, which have aluminium brass tubes and use sea water from Arabian sea for cooling. The abnormal tube failure rates led to a thorough investigation of the causes. The remedial measures adopted to arrest and bring down the failure rate are elaborated. In addition to improved preventive maintenance practices, additional measures like ferrous ion addition, partial zonal retubing are also brought out.

  1. Water condensation for submicronic particles abatement

    OpenAIRE

    Cozzolino, Gennaro

    2013-01-01

    Control of particulate matter (PM) emissions from industrial processes is important for protection of human health and the environment. A promising technique for submicron PM abatement is by condensing water vapor onto the particles, which enhances particle growth and improves the performance of traditional particle collection devices. This thesis analyzes the flue gases cleaning process by means of activation heterogeneous water nucleation mechanism on particles surface as a function of work...

  2. Modeling and Optimization of Superhydrophobic Condensation

    OpenAIRE

    Miljkovic, Nenad; Enright, Ryan; Wang, Evelyn N.

    2012-01-01

    Superhydrophobic micro/nanostructured surfaces for dropwise condensation have recently received significant attention due to their potential to enhance heat transfer performance by shedding water droplets via coalescence-induced droplet jumping at length scales below the capillary length. However, achieving optimal surface designs for such behavior requires capturing the details of transport processes that is currently lacking. While comprehensive models have been developed for flat hydrophob...

  3. Dilepton production from the Color Glass Condensate

    CERN Document Server

    Gelis, François; Jalilian-Marian, Jamal

    2002-01-01

    We consider dilepton production in high energy proton-nucleus (and very forward nucleus-nucleus) collisions. Treating the target nucleus as a Color Glass Condensate and describing the projectile proton (nucleus) as a collection of quarks and gluons as in the parton model, we calculate the differential cross section for dilepton production in quark-nucleus scattering and show that it is very sensitive to the saturation scale characterizing the target nucleus.

  4. Capillary condensation for fluids in spherical cavities

    OpenAIRE

    Urrutia, Ignacio; Szybisz, Leszek

    2005-01-01

    The capillary condensation for fluids into spherical nano-cavities is analyzed within the frame of two theoretical approaches. One description is based on a widely used simplified version of the droplet model formulated for studying atomic nuclei. The other, is a more elaborated calculation performed by applying a density functional theory. The agreement between both models is examined and it is shown that a small correction to the simple fluid model improves the predictions. A connection to ...

  5. Spin selective filtering of polariton condensate flow

    Energy Technology Data Exchange (ETDEWEB)

    Gao, T. [FORTH-IESL, P.O. Box 1385, 71110 Heraklion, Crete (Greece); Department of Materials Science and Technology, University of Crete, 71003 Heraklion, Crete (Greece); Antón, C.; Martín, M. D. [Departamento de Física de Materiales, Universidad Autónoma de Madrid, Madrid 28049 (Spain); Instituto de Ciencia de Materiales “Nicolás Cabrera,” Universidad Autónoma de Madrid, Madrid 28049 (Spain); Liew, T. C. H. [School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371 (Singapore); Hatzopoulos, Z. [FORTH-IESL, P.O. Box 1385, 71110 Heraklion, Crete (Greece); Department of Physics, University of Crete, 71003 Heraklion, Crete (Greece); Viña, L. [Departamento de Física de Materiales, Universidad Autónoma de Madrid, Madrid 28049 (Spain); Instituto de Ciencia de Materiales “Nicolás Cabrera,” Universidad Autónoma de Madrid, Madrid 28049 (Spain); Instituto de Física de la Materia Condensada, Universidad Autónoma de Madrid, Madrid 28049 (Spain); Eldridge, P. S., E-mail: eldridge@udel.edu [FORTH-IESL, P.O. Box 1385, 71110 Heraklion, Crete (Greece); Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716 (United States); Savvidis, P. G., E-mail: psav@materials.uoc.gr [FORTH-IESL, P.O. Box 1385, 71110 Heraklion, Crete (Greece); Department of Materials Science and Technology, University of Crete, 71003 Heraklion, Crete (Greece); Cavendish Laboratory, University of Cambridge, Cambridge CB3 0HE (United Kingdom)

    2015-07-06

    Spin-selective spatial filtering of propagating polariton condensates, using a controllable spin-dependent gating barrier, in a one-dimensional semiconductor microcavity ridge waveguide is reported. A nonresonant laser beam provides the source of propagating polaritons, while a second circularly polarized weak beam imprints a spin dependent potential barrier, which gates the polariton flow and generates polariton spin currents. A complete spin-based control over the blocked and transmitted polaritons is obtained by varying the gate polarization.

  6. A superheated Bose-condensed gas

    OpenAIRE

    Gaunt, Alexander L.; Fletcher, Richard J.; Robert P. Smith; Hadzibabic, Zoran

    2012-01-01

    Our understanding of various states of matter usually relies on the assumption of thermodynamic equilibrium. However, the transitions between different phases of matter can be strongly affected by non-equilibrium phenomena. Here we demonstrate and explain an example of non-equilibrium stalling of a continuous, second-order phase transition. We create a superheated atomic Bose gas, in which a Bose-Einstein condensate (BEC) persists above the equilibrium critical temperature, $T_c$, if its coup...

  7. THE COLOUR GLASS CONDENSATE: AN INTRODUCTION

    Energy Technology Data Exchange (ETDEWEB)

    IANCU,E.; LEONIDOV,A.; MCLERRAN,L.

    2001-08-06

    In these lectures, the authors develop the theory of the Colour Glass Condensate. This is the matter made of gluons in the high density environment characteristic of deep inelastic scattering or hadron-hadron collisions at very high energy. The lectures are self contained and comprehensive. They start with a phenomenological introduction, develop the theory of classical gluon fields appropriate for the Colour Glass, and end with a derivation and discussion of the renormalization group equations which determine this effective theory.

  8. Condensed Extended Hyper-Wiener Index

    Institute of Scientific and Technical Information of China (English)

    LI Xin-Hua; Abraham F. Jalbout; JI Zhi

    2008-01-01

    According to the definitions of molecular connectivity and hyper-Wiener index, a novel set of hyper-Wiener indexes (Dn, mDn) were defined and named as condensed extended hyper-Wiener index, the potential usefulness of which in QSAR/QSPR is evaluated by its correlation with a number of C3-C8 alkanes as well as by a favorable comparison with models based on molecular connectivity index and overall Wiener index.

  9. Thermal condensation mode in a dusty plasma

    Indian Academy of Sciences (India)

    B P Pandey; J Vranješ; S Parhi

    2003-03-01

    In the present work, the radiative condensation instability is investigated in the presence of dust charge fluctuations. We find that the charge variability of the grain reduces the growth rate of radiative mode only for fluctuation wavelength smaller or of the order of the Debye length and this reduction is not very large. Far from the Debye sphere, radiative mode can damp due to thermal conduction of electrons and ions.

  10. Experimental and theoretical study of reflux condensation

    Energy Technology Data Exchange (ETDEWEB)

    Bakke, Knut

    1997-12-31

    This thesis studies the separation of gas mixtures in a reflux condenser. also called a dephlegmator. Reflux condensation is separation of a gas mixture, in reflux flow with condensing liquid, under continuous heat removal. A numerical model of a dephlegmator for binary mixtures was developed. The model may readily be extended to multi-component mixtures, as the solution method is based on a matrix solver. Separation of a binary mixture in a reflux condenser test rig is demonstrated. The test facility contains a single-tube test section that was designed and built as part of the project. Test mixtures of propane and n-butane were used, and a total of 15 experiments are reported. Limited degree of separation was achieved due to limited heat transfer area and narrow boiling point range of the test mixture. The numerical model reproduces the experimental data within reasonable accuracy. Deviation between calculated and measured properties is less than 6% of the measured temperature and less than 5% of the measured flow rate. The model is based on mechanistic models of physical processes and is not calibrated or tuned to fit the experimental data. The numerical model is applied to a number of separation processes. These case studies show that the required heat transfer area increases rapidly with increments in top product composition (light component). Flooding limits the amount of reflux liquid. The dephlegmator is suitable for separation of feed mixtures that are rich in light components. The gliding temperature in the dephlegmation process enables utilization of top product as refrigerant, with subsequent energy saving as a result. 61 refs., 50 figs., 34 tabs.

  11. Bouncing cosmologies from quantum gravity condensates

    CERN Document Server

    Oriti, Daniele; Wilson-Ewing, Edward

    2016-01-01

    We show how the large-scale cosmological dynamics can be obtained from the hydrodynamics of isotropic group field theory condensate states in the Gross-Pitaevskii approximation. The correct Friedmann equations are recovered in the semi-classical limit for some choices of the parameters in the action for the group field theory, and quantum gravity corrections arise in the high-curvature regime causing a bounce which generically resolves the big-bang and big-crunch singularities.

  12. Boson Condensation in an Einstein Universe

    OpenAIRE

    Altaie, M. B.; Malkawi, Ehab

    2000-01-01

    In this paper we investigate the Bose-Einstein condensation of massive spin-1 particles in an Einstein universe. The system is considered under relativistic conditions taking into consideration the possibility of particle-antiparticle pair production. An exact expression for the charge density is obtained, then certain approximations are employed in order to obtain the solutions in closed form. A discussion of the approximations employed in this and other work is given. The effects of finite-...

  13. A Simple Analytic Solution for Tachyon Condensation

    CERN Document Server

    Erler, Theodore

    2009-01-01

    In this paper we present a new and simple analytic solution for tachyon condensation in open bosonic string field theory. Unlike the B_0 gauge solution, which requires a carefully regulated discrete sum of wedge states subtracted against a mysterious "phantom" counter term, this new solution involves a continuous integral of wedge states, and no regularization or phantom term is necessary. Moreover, we can evaluate the action and prove Sen's conjecture in a mere few lines of calculation.

  14. Bouncing cosmologies from quantum gravity condensates

    Science.gov (United States)

    Oriti, Daniele; Sindoni, Lorenzo; Wilson-Ewing, Edward

    2017-02-01

    We show how the large-scale cosmological dynamics can be obtained from the hydrodynamics of isotropic group field theory condensate states in the Gross–Pitaevskii approximation. The correct Friedmann equations are recovered in the classical limit for some choices of the parameters in the action for the group field theory, and quantum gravity corrections arise in the high-curvature regime causing a bounce which generically resolves the big-bang and big-crunch singularities.

  15. On the early and developed stages of surface condensation: competition mechanism between interfacial and condensate bulk thermal resistances

    Science.gov (United States)

    Sun, Jie; Wang, Hua Sheng

    2016-10-01

    We use molecular dynamics simulation to investigate the early and developed stages of surface condensation. We find that the liquid-vapor and solid-liquid interfacial thermal resistances depend on the properties of solid and fluid, which are time-independent, while the condensate bulk thermal resistance depends on the condensate thickness, which is time-dependent. There exists intrinsic competition between the interfacial and condensate bulk thermal resistances in timeline and the resultant total thermal resistance determines the condensation intensity for a given vapor-solid temperature difference. We reveal the competition mechanism that the interfacial thermal resistance dominates at the onset of condensation and holds afterwards while the condensate bulk thermal resistance gradually takes over with condensate thickness growing. The weaker the solid-liquid bonding, the later the takeover occurs. This competition mechanism suggests that only when the condensate bulk thermal resistance is reduced after it takes over the domination can the condensation be effectively intensified. We propose a unified theoretical model for the thermal resistance analysis by making dropwise condensation equivalent to filmwise condensation. We further find that near a critical point (contact angle being ca. 153°) the bulk thermal resistance has the least opportunity to take over the domination while away from it the probability increases.

  16. Majorana fermions in condensed-matter physics

    Science.gov (United States)

    Leggett, A. J.

    2016-06-01

    It is an honor and a pleasure to have been invited to give a talk in this conference celebrating the memory of the late Professor Abdus Salam. To my regret, I did not know Professor Salam personally, but I am very aware of his work and of his impact on my area of specialization, condensed matter physics, both intellectually through his ideas on spontaneously broken symmetry and more practically through his foundation of the ICTP. Since I assume that most of this audience are not specialized in condensed-matter physics, I thought I would talk about one topic which to some extent bridges this field and the particle-physics interests of Salam, namely Majorana fermions (M.F.s). However, as we shall see, the parallels which are often drawn in the current literature may be a bit too simplistic. I will devote most of this talk to a stripped-down exposition of the current orthodoxy concerning M.F.s. in condensed-matter physics and their possible applications to topological quantum computing (TQC), and then at the end briefly indicate why I believe this orthodoxy may be seriously misleading.

  17. Ice condensation as a planet formation mechanism

    CERN Document Server

    Ros, Katrin

    2013-01-01

    We show that condensation is an efficient particle growth mechanism, leading to growth beyond decimeter-sized pebbles close to an ice line in protoplanetary discs. As coagulation of dust particles is frustrated by bouncing and fragmentation, condensation could be a complementary, or even dominant, growth mode in the early stages of planet formation. Ice particles diffuse across the ice line and sublimate, and vapour diffusing back across the ice line recondenses onto already existing particles, causing them to grow. We develop a numerical model of the dynamical behaviour of ice particles close to the water ice line, approximately 3 AU from the host star. Particles move with the turbulent gas, modelled as a random walk. They also sediment towards the midplane and drift radially towards the central star. Condensation and sublimation are calculated using a Monte Carlo approach. Our results indicate that, with a turbulent alpha-value of 0.01, growth from millimeter to at least decimeter-sized pebbles is possible ...

  18. Capillary condensation of short-chain molecules.

    Science.gov (United States)

    Bryk, Paweł; Pizio, Orest; Sokolowski, Stefan

    2005-05-15

    A density-functional study of capillary condensation of fluids of short-chain molecules confined to slitlike pores is presented. The molecules are modeled as freely jointed tangent spherical segments with a hard core and with short-range attractive interaction between all the segments. We investigate how the critical parameters of capillary condensation of the fluid change when the pore width decreases and eventually becomes smaller than the nominal linear dimension of the single-chain molecule. We find that the dependence of critical parameters for a fluid of dimers and of tetramers on pore width is similar to that of the monomer fluid. On the other hand, for a fluid of chains consisting of a larger number of segments we observe an inversion effect. Namely, the critical temperature of capillary condensation decreases with increasing pore width for a certain interval of values of the pore width. This anomalous behavior is also influenced by the interaction between molecules and pore walls. We attribute this behavior to the effect of conformational changes of molecules upon confinement.

  19. Geysers advanced direct contact condenser research

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, J.; Bahning, T.; Bharathan, D.

    1997-12-31

    The first geothermal application of the Advanced Direct Contact Condenser (ADCC) technology developed by the National Renewable Energy Laboratory (NREL) is now operational and is being tested at The Geysers Power Plant Unit 11. This major research effort is being supported through the combined efforts of NREL, The Department of Energy (DOE), and Pacific Gas and Electric (PG&E). NREL and PG&E have entered into a Cooperative Research And Development Agreement (CRADA) for a project to improve the direct-contact condenser performance at The Geysers Power Plant. This project is the first geothermal adaptation of an advanced condenser design developed for the Ocean Thermal Energy Conversion (OTEC) systems. PG&E expects this technology to improve power plant performance and to help extend the life of the steam field by using steam more efficiently. In accordance with the CRADA, no money is transferred between the contracting parties. In this case the Department of Energy is funding NREL for their efforts in this project and PG&E is contributing funds in kind. Successful application of this technology at The Geysers will provide a basis for NREL to continue to develop this technology for other geothermal and fossil power plant systems.

  20. Orientifold Planar Equivalence: The Chiral Condensate

    CERN Document Server

    Armoni, A; Patella, A; Pica, C

    2008-01-01

    The recently introduced orientifold planar equivalence is a promising tool for solving non-perturbative problems in QCD. One of the predictions of orientifold planar equivalence is that the chiral condensates of a theory with $N_f$ flavours of Dirac fermions in the symmetric (or antisymmetric) representation and $N_f$ flavours of Majorana fermions in the adjoint representation have the same large $N$ value for any value of the mass of the (degenerate) fermions. Assuming the invariance of the theory under charge conjugation, we prove this statement on the lattice for staggered quenched condensates in SU($N$) Yang-Mills in the large $N$ limit. Then, we compute numerically those quenched condensates for $N$ up to 8. After separating the even from the odd corrections in $1/N$, we are able to show that our data support the equivalence; however, unlike other quenched observables, subleading terms in $1/N$ are needed for describing the data for the symmetric and antisymmetric representation at $N$=3. Possible lesson...

  1. Revisiting RG Flow for Kaon Condensation

    CERN Document Server

    Paeng, Won-Gi

    2014-01-01

    Kaon condensation in compact-star matter can be considered as a quantum critical phenomenon with the kaon mass tuned to zero by the baryon density plus the electron chemical potential that increases at the increase of the density. We approach this problem with a renormalization group flow at one loop of the system of anti-kaons considered as pseudo-Goldstone bosons coupled to nucleonic matter described as a Fermi liquid near its fixed point. While the Weinberg-Tomozawa term in chiral Lagrangians is of leading order in describing kaon-nucleon interactions in chiral perturbation theory, hence widely employed in the literature, it is irrelevant in the RG sense, therefore plays, if any, a less important role in the condensation process. The consequence is that the $\\Lambda (1405)$ resonance which is driven by the Weinberg-Tomozawa term is irrelevant for triggering kaon condensation. On the contrary, the $KN$ sigma term $\\Sigma_{KN}$, subleading in chiral counting, can play a more crucial role in renormalization g...

  2. Promotion of dropwise condensation of ethyl alcohol, methyl alcohol, and acetone by polytetrafluoroethylene

    Science.gov (United States)

    Kirby, C. E.

    1972-01-01

    Coating condensing surfaces with thin layer of nonpolar Teflon results in dropwise condensation of polar organic vapor. Greater heat transfer coefficients are produced increasing effectiveness of condensing system. Investigation shows that vapors with strong dipole moment tend to condense dropwise.

  3. 40 CFR 405.110 - Applicability; description of the condensed whey subcategory.

    Science.gov (United States)

    2010-07-01

    ... condensed whey subcategory. 405.110 Section 405.110 Protection of Environment ENVIRONMENTAL PROTECTION... Condensed Whey Subcategory § 405.110 Applicability; description of the condensed whey subcategory. The... whey and condensed acid whey....

  4. Competition between Bose-Einstein Condensation and Spin Dynamics.

    Science.gov (United States)

    Naylor, B; Brewczyk, M; Gajda, M; Gorceix, O; Maréchal, E; Vernac, L; Laburthe-Tolra, B

    2016-10-28

    We study the impact of spin-exchange collisions on the dynamics of Bose-Einstein condensation by rapidly cooling a chromium multicomponent Bose gas. Despite relatively strong spin-dependent interactions, the critical temperature for Bose-Einstein condensation is reached before the spin degrees of freedom fully thermalize. The increase in density due to Bose-Einstein condensation then triggers spin dynamics, hampering the formation of condensates in spin-excited states. Small metastable spinor condensates are, nevertheless, produced, and they manifest in strong spin fluctuations.

  5. Heat Transfer in Flue Gas with Vapor Condensation

    Institute of Scientific and Technical Information of China (English)

    贾力; 彭晓峰

    2002-01-01

    This paper combines the film model with Nusselt's condensation theory to analyze the effects of water vapor condensation on the heat transfer performance of flue gas flowing through a vertical tube. The analysis compares the condensation and convective heat transfer rates. For the concentration range investigated, the water vapor condensation transfers more energy than the flue gas convection, but the convective heat transfer can not be neglected. The heat transfer intensification due to the condensation increased as the water vapor fraction increased. The theoretical results compared well with experimental data.

  6. Droplet condensation on chemically homogeneous and heterogeneous surfaces

    Science.gov (United States)

    Ashrafi, Amir; Moosavi, Ali

    2016-09-01

    Nucleation and growth of condensing droplets on horizontal surfaces are investigated via a 2-D double distribution function thermal lattice Boltzmann method. First, condensation on completely uniform surface is investigated and different mechanisms which cause dropwise and filmwise condensation are studied. The results reveal the presence of cooled vapor layer instability in the condensation on completely smooth surfaces. In the second step, condensation on chemically heterogeneous surfaces is investigated. Moreover, the effect of non-uniformity in the surface temperature is also studied. The results indicate that the vapor layer instability and the nucleation start from the heterogeneities. The effects of different numbers of heterogeneities, their distance, and hydrophobicity on the condensation are also inspected. It is shown that by increasing the hydrophobicity of the heterogeneities and considering an optimum space between the heterogeneities, maximum condensation performance can be achieved. Finally, condensation on wettability gradient surfaces is studied and the effects of the gradient form and contact angle of the core region on the condensation are studied. It is shown that hydrophobicity of the core region plays a key role in increasing the condensation performance. A heat transfer analysis and flow dynamics of dropwise condensation as a function of time is also presented and it is shown that the results are in good agreements with the previous theoretical and experimental results.

  7. A Local Condensation Analysis Representing Two-phase Annular Flow in Condenser/radiator Capillary Tubes

    Science.gov (United States)

    Karimi, Amir

    1991-01-01

    NASA's effort for the thermal environmental control of the Space Station Freedom is directed towards the design, analysis, and development of an Active Thermal Control System (ATCS). A two phase, flow through condenser/radiator concept was baselined, as a part of the ATCS, for the radiation of space station thermal load into space. The proposed condenser rejects heat through direct condensation of ATCS working fluid (ammonia) in the small diameter radiator tubes. Analysis of the condensation process and design of condenser tubes are based on the available two phase flow models for the prediction of flow regimes, heat transfer, and pressure drops. The prediction formulas use the existing empirical relationships of friction factor at gas-liquid interface. An attempt is made to study the stability of interfacial waves in two phase annular flow. The formulation is presented of a stability problem in cylindrical coordinates. The contribution of fluid viscosity, surface tension, and transverse radius of curvature to the interfacial surface is included. A solution is obtained for Kelvin-Helmholtz instability problem which can be used to determine the critical and most dangerous wavelengths for interfacial waves.

  8. Assessment of TRACE Condensation Model Against Reflux Condensation Tests with Noncondensable Gases

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Kyung Won; Cheong, Ae Ju; Shin, Andong; Suh, Nam Duk [Korea Institute of Nuclear Safety, Daejeon (Korea, Republic of)

    2015-05-15

    The TRACE is the latest in a series of advanced, best-estimated reactor systems code developed by U.S. Nuclear Regulatory Commission for analyzing transient and steady-state neutronic-thermal-hydraulic behavior in light water reactors. This special model is expected to replace the default model in a future code release after sufficient testing has been completed. This study assesses the special condensation model of TRACE 5.0-patch4 against the counter-current flow configuration. For this purpose, the predicted results of special model are compared to the experimental and to those of default model. The KAST reflux condensation test with NC gases are used in this assessment. We assessed the special model for film condensation of TRACE 5.0-patch4 against the data of the reflux condensation test in the presence of NC gases. The special condensation model of TRACE provides a reasonable estimate of HTC with good agreement at the low inlet steam flow rate.

  9. Scalable graphene coatings for enhanced condensation heat transfer.

    Science.gov (United States)

    Preston, Daniel J; Mafra, Daniela L; Miljkovic, Nenad; Kong, Jing; Wang, Evelyn N

    2015-05-13

    Water vapor condensation is commonly observed in nature and routinely used as an effective means of transferring heat with dropwise condensation on nonwetting surfaces exhibiting heat transfer improvement compared to filmwise condensation on wetting surfaces. However, state-of-the-art techniques to promote dropwise condensation rely on functional hydrophobic coatings that either have challenges with chemical stability or are so thick that any potential heat transfer improvement is negated due to the added thermal resistance of the coating. In this work, we show the effectiveness of ultrathin scalable chemical vapor deposited (CVD) graphene coatings to promote dropwise condensation while offering robust chemical stability and maintaining low thermal resistance. Heat transfer enhancements of 4× were demonstrated compared to filmwise condensation, and the robustness of these CVD coatings was superior to typical hydrophobic monolayer coatings. Our results indicate that graphene is a promising surface coating to promote dropwise condensation of water in industrial conditions with the potential for scalable application via CVD.

  10. Quantification of chromatin condensation level by image processing.

    Science.gov (United States)

    Irianto, Jerome; Lee, David A; Knight, Martin M

    2014-03-01

    The level of chromatin condensation is related to the silencing/activation of chromosomal territories and therefore impacts on gene expression. Chromatin condensation changes during cell cycle, progression and differentiation, and is influenced by various physicochemical and epigenetic factors. This study describes a validated experimental technique to quantify chromatin condensation. A novel image processing procedure is developed using Sobel edge detection to quantify the level of chromatin condensation from nuclei images taken by confocal microscopy. The algorithm was developed in MATLAB and used to quantify different levels of chromatin condensation in chondrocyte nuclei achieved through alteration in osmotic pressure. The resulting chromatin condensation parameter (CCP) is in good agreement with independent multi-observer qualitative visual assessment. This image processing technique thereby provides a validated unbiased parameter for rapid and highly reproducible quantification of the level of chromatin condensation.

  11. Comparison of Heat Transfer Coefficients of Silver Coated and Chromium Coated Copper Tubes of Condenser in Dropwise Condensation

    Directory of Open Access Journals (Sweden)

    Er. Shivesh Kumar

    2016-09-01

    Full Text Available Since centuries steam is being used in power generating system. The steam leaving the power unit is reconverted into water in a condenser designed to transfer heat from the steam to the cooling water as rapidly and as efficiently as possible. The efficiency of condenser depends on rate of condensation and mode of condensation of steam in the condenser. The increase in efficiency of the condenser enhances the heat transfer co-efficient which in turn results in economic design of condenser and reduced pumping power for a desired output. Higher heat transfer coefficient in condensers is beneficial in the industrial applications e.g., Sugar industry, ships propulsion, nuclear power reactor, power generating system, production of Liquefied petroleum gases, liquid nitrogen and liquid oxygen. In the present experimental study, comparison of heat transfer coefficients of silver coated and chromium coated copper tubes of condenser have been performed. it has been observed that inside heat transfer coefficient (hᵢ, outside heat transfer coefficient (h₀ and overall heat transfer coefficient (U associated with silver coated condenser made of copper is more than that of chromium coated condenser made of copper. It is also observed that all the three types of heat transfer coefficient increases with increase of steam pressure [1].

  12. Uma aplicação dos métodos dos elementos finitos e diferenças finitas à interação fluido-estrutura

    OpenAIRE

    2006-01-01

    Em muitos casos práticos de Engenharia, uma estrutura pode ter seu comportamento dinâmico alterado em função da presença de um fluido denso, e nesses casos, deve-se investir em uma abordagem Fluido-Estrutura. Quando houver um regime de pequenos deslocamentos, tanto para a estrutura como para o fluido, este se torna um problema Acústico-Mecânico. Este trabalho apresenta alguns resultados numéricos baseados na formulação em Elementos Finitos (EF) “U-p” (deslocamento-pressão) (Zienkiewicz e Newt...

  13. Gerenciamento de riscos de incêndio: avaliação do impacto em estruturas de concreto armado através de uma análise experimental de vigas isostáticas

    OpenAIRE

    Ancelmo de Carvalho Pires de Oliveira, Tiago

    2006-01-01

    Incêndios em estruturas de concreto armado podem causar perdas significativas quando a estrutura perde sua capacidade resistente. A inexistência de dados estatísticos sobre estes incêndios impede uma estimativa do valor dos prejuízos com recuperação estrutural e colapso parcial ou total das estruturas. No entanto, acidentes deste tipo não são tão raros, cita-se, por exemplo, o recente incêndio no prédio do INSS em Brasília (2005). Para um dimensionamento adequado é necessário o...

  14. Tachyon condensation due to domain-wall annihilation in Bose-Einstein condensates.

    Science.gov (United States)

    Takeuchi, Hiromitsu; Kasamatsu, Kenichi; Tsubota, Makoto; Nitta, Muneto

    2012-12-14

    We show theoretically that a domain-wall annihilation in two-component Bose-Einstein condensates causes tachyon condensation accompanied by spontaneous symmetry breaking in a two-dimensional subspace. Three-dimensional vortex formation from domain-wall annihilations is considered a kink formation in subspace. Numerical experiments reveal that the subspatial dynamics obey the dynamic scaling law of phase-ordering kinetics. This model is experimentally feasible and provides insights into how the extra dimensions influence subspatial phase transition in higher-dimensional space.

  15. A tale of two condensates: the odd "Bose - Einstein" condensation of atomic Hydrogen

    OpenAIRE

    1998-01-01

    The recent report of the observation of Bose-Einstein condensation in atomic Hydrogen, characterized by an "anomalous" density spectrum, is shown to be in agreement with the prediction of the existence of two condensates for temperatures lower than a well defined temperature (which for Hydrogen is $ 105~ \\mu K $), based on the QED coherent interaction in a gas of ultracold atoms at a density $n > n_0 (n_0=(1/\\lambda)^3, \\lambda$ being the wave-length of the e.m. modes resonantly coupled to th...

  16. The effect of condensate inundation on steam condensation heat transfer in a tube bundle

    OpenAIRE

    Brower, Steven K.

    1985-01-01

    Approved for public release; distribution is unlimited Steam-condensation heat-transfer measurements were made using a 5-tube in-line test condenser with an additional perforated tube to simulate up to 30 active tubes. Results were obtained for smooth tubes, wire-wrapped tubes and dropwise-coated tubes. The average outside heat-transfer coefficient for 30 smooth tubes was 0.64 times the Nusselt coefficient for the first tube. A total of eight wirediameter and wire-pitc...

  17. O DEBATE CHOMSKY-PIAGET REVISITADO: UM ESTUDO A FAVOR DA ESTRUTURA RELATIVA COMO UMA ESTRATÉGIA COGNITIVA NA SLA

    Directory of Open Access Journals (Sweden)

    Gislaine Machado Jerônimo

    2011-01-01

    Full Text Available Resumo: O presente trabalho lida com o conceito de relativização, o qual trata da aquisição de estruturas complexas - orações relativas restritivas por aprendizes brasileiros de Inglês como língua estrangeira (LE. A estrutura relativa foi escolhida porque é considerada uma das estruturas mais importantes usada nas línguas de todo mundo por ter o recurso de encaixamento, podendo variar consideravelmente em termos de sua distribuição e forma sintática. O principal objetivo é diagnosticar estratégias, empregadas pelos aprendizes já mencionados, para a resolução de determinadas tarefas, aqui chamadas de desafios. Tais desafios convidam ao uso de estruturas que alternam em sujeito-sujeito (SS, sujeito-objeto (SO, objeto-sujeito (OS e objeto-objeto (OO. Estas estruturas são caracterizadas por uma diversidade sintática que ocorre de acordo com a posição dos personagens dos desafios (come- come. Como alternativa para relativização, os sujeitos das atividades (aprendizes de Inglês utilizaram estratégias como apassivação de uma das orações, uso de orações adverbiais, emprego de orações coordenadas aditivas e de duas orações independentes. Anterior a coleta de dados foi aplicado um pré-teste com professores graduados de Língua Inglesa e com alunos do nível pós-avançado de um curso de Inglês, para validar o instrumento. Os sujeitos da pesquisa foram alunos de 3°ano do Ensino Médio entre 15 e 17 anos de idade. Aspectos como idade e experiência no exterior foram levados em consideração. Dentre as estratégias, a estrutura aditiva foi a mais utilizada, seguida da relativização. Os resultados mostraram que estes aprendizes fizeram uso do seu conhecimento cognitivo para desenvolver formas alternativas no que tange à resolução de cada desafio. O referencial teórico foi baseado, principalmente, em AXT (1994.

  18. Tunneling Dynamics Between Atomic and Molecular Bose-Einstein Condensates

    Institute of Scientific and Technical Information of China (English)

    CHEN Chang-Yong

    2004-01-01

    Tunneling dynamics of multi-atomic molecules between atomic and multi-atomic molecular Bose-Einstein condensates with Feshbach resonance is investigated.It is indicated that the tunneling in the two Bose-Einstein condensates depends on not only the inter-atomic-molecular nonlinear interactions and the initial number of atoms in these condensates,but also the tunneling coupling between the atomic condensate and the multi-atomic molecular condensate.It is discovered that besides oscillating tunneling current between the atomic condensate and the multi-atomic molecular condensate,the nonlinear multi-atomic molecular tunneling dynamics sustains a self-locked population imbalance:a macroscopic quantum self-trapping effect.The influence of de-coherence caused by non-condensate atoms on the tunneling dynamics is studied.It is shown that de-coherence suppresses the multi-atomic molecular tunneling.Moreover,the conception of the molecular Bose-Einstein condensate,which is different from the conventional single-atomic Bose-Einstein condensate,is specially emphasized in this paper.

  19. Propriedades de estruturas temporais rápidas submilimétricas durante uma grande explosão solar

    Science.gov (United States)

    Raulin, J.-P.; Kaufmann, P.; Gimenez de Castro, C. G.; Pacini, A. A.; Makhmutov, V.; Levato, H.; Rovira, M.

    2003-08-01

    Apresentamos novas propriedades de variações rápidas da emissão submilimétrica durante uma das maiores explosões solares do ciclo solar 23. Os dados analisados neste estudo foram obtidos com o Telescópio Solar Submilimétrico (SST), que observa o Sol em 212 GHz e 405 GHz, e comparados com emissões em Raios-X duros e Raios-gama (fótons de energia > 10 MeV), que foram obtidas pelo experimento GRS do Yohkoh. Aplicamos diferentes metodologias para detectar e caracterizar, ao longo do evento, os pulsos submilimétricos (duração de 50-300 ms) detectados acima de uma componente mais lenta (alguns minutos). Os resultados mostram que durante a fase impulsiva, num instante próximo ao tempo do máximo do evento, houve um aumento da ocorrência de maiores e de mais rápidas estruturas temporais. Também identificamos uma boa correlação com as emissões em raios-X e raios-gama (até a faixa de energia 10-100 MeV), indicando que os pulsos rápidos submilimétricos refletiram injeções primárias de energia durante o evento.O espectro do fluxo desses pulsos é crescente com a freqüência entre 212 and 405 GHz, na maioria dos casos, ao contrário do observado para a componente gradual. As posições calculadas para as estruturas rápidas são discretas, compactas e localizadas em toda a área da região ativa, o que é previsto nos modelos de explosões solares decorrentes de instabilidades múltiplas em diferentes pequenas regiões. Por outro lado, a posição calculada para a componente lenta é estável durante a fase impulsiva. Assim, a comparação entre as características do espectro de fluxo e da localização da emissão, para os pulsos rápidos e para a componente gradual, sugere que as respectivas emissões são de natureza diferente.

  20. Estudos citológicos e citoquímicos em Stenophoridae Crawley, 1903 (Eugregarinidae, Protozoa II - ultra-estrutura

    Directory of Open Access Journals (Sweden)

    Sylvio Celso Goncalves da Costa

    1967-01-01

    Full Text Available 1 - Indivíduos de Stenophora juli (Frantzius, 1848 Labbé, 1899, parasitos de um Diplopoda, Rhinochricus padbergi Schubart. 1930 foram examinados em microscópia óptica e eletrônica. 2 - Os resultados do estudo citoquímico confirmam os dados obtidos por outros autores em outras espécies de gregarinas. 3 - Quanto à estrutura fina da morfologia celular foi examinada detalhadamente a película a qual apresenta cristas longitudinais de forma e estrutura complexas. 4 - No sulcos da película, entre as cristas, foram encontrados poros na membrana, por onde é realizada a secreção de muco. 5 - Aderente à película, pròpriamente dita foi encontrada, no deutomerito, uma camada homogênea de natureza desconhecida, abaixo da qual encontra-se o mionema. 6 - O septo que separa o proto do deutomerito é constituído por espêssa camada de mionemas incluindo numerosas mitocôndrias. 7 - O endoplasma é extremamente rico em granulações de paraglicogênio, aparecendo em menor quantidade os lipídeos. Observamos também mitocôndrias, retículo endoplasmático e o complexo de Golgi.Stenophora juli (Frantzius, 1848 Labbé, 1899, Sporozoa parasite of the Diplopoda Rhinocrius padbergi Schubart, 1930, were examined by light and electron microscopy. As a result of a cytochemical investigation, similar content to those obtained by other authors has been shown. Ultrastructure of membrane shows complex microscopic longitudinal folds and among this folds there are pores for mucous secretion. An unknown layer was found under the membrane and upon the mioneme. The sept which divide this protozoa in protomerite and deutomerite is formed by a large mionem, in which a great number of mitochondria has been shown. Paraglicogene granules appear present in large quantity in the endoplasm, and lipid inclusion appear in smaller quantity. Mitocondria, endoplasmic reticulum and Golgi complex are also observed in the endoplasm. The nuclear envelope shows a double

  1. Envelhecimento populacional e mudanças no padrão de consumo e na estrutura produtiva brasileira

    Directory of Open Access Journals (Sweden)

    Rodrigo Rafael Zanon

    2013-01-01

    Full Text Available Este trabalho objetiva analisar como o envelhecimento populacional pode afetar a estrutura produtiva brasileira, dadas as mudanças previstas no padrão de consumo da população no período 2005-2050. Para tanto, utilizou-se a análise insumo-produto em conjunto com informações da Pesquisa de Orçamentos Familiares (POF de 2008-2009, da Pesquisa Nacional por Amostra de Domicílios (PNAD de 2005 e da projeção da população do Brasil, por sexo e idade, para 1980-2050. Entre os principais resultados, observou-se que os produtos com maior consumo em favor das famílias idosas foram intermediação financeira e seguros, saúde mercantil, serviços domésticos e produtos farmacêuticos, enquanto para as famílias não idosas os destaques foram educação mercantil, vestuário, calçados e produtos do couro, transporte de passageiros e serviços de alojamento e alimentação. Quando comparada a produção necessária para satisfazer o consumo das famílias nos anos analisados, verificou-se que os setores com maior crescimento devem ser aqueles responsáveis pelos produtos com maior consumo pelas famílias idosas, com destaque para os setores produtos farmacêuticos, saúde mercantil, intermediação financeira e seguros, outros serviços, aparelho/instrumento médico-hospitalar, medida e óptico e serviços imobiliários e aluguel, ao passo que os setores com menor crescimento de sua produção devem ser educação mercantil, vestuário, calçados e produtos do couro, serviços de alojamento e alimentação, produtos do fumo, veículos automotores, peças e equipamentos. Por fim, apesar dessas diferenças observadas no crescimento dos setores, a estrutura produtiva brasileira pouco deve se alterar dadas as mudanças no consumo causadas pelo envelhecimento populacional.

  2. Estrutura da cadeia reversa: "caminhos" e "descaminhos" da embalagem PET Structure of the reverse chain: "ways" of PET packing

    Directory of Open Access Journals (Sweden)

    Sylmara Lopes Francelino Gonçalves-Dias

    2006-12-01

    Full Text Available O trabalho propõe-se a discutir as possibilidades, limites e desafios da reciclagem de PET - Politereftalato de Etileno. Como fundamentação teórico-conceitual, recorre à discussão sobre a natureza e o alcance da logística reversa, analisando as estratégias para estruturação da cadeia de reciclagem. A pesquisa é de caráter exploratório, com adoção de diferentes estratégias para a coleta de dados, envolvendo fontes secundárias produzidas por órgãos públicos, instituições especializadas e mídia, e ainda entrevistas semi-estruturadas com especialistas na área. Os resultados apontam que múltiplos atores estão envolvidos na estrutura da cadeia reversa do PET e que, apesar do avanço no volume de reciclagem, nenhum dos setores, seja público ou privado, consegue individualmente organizar-se para o alcance da efetividade operacional e ambiental desejável no cenário brasileiro. O alcance de bons resultados depende, sobretudo, do investimento nos dois extremos da cadeia reversa: na coleta seletiva e no mercado para o produto reciclado.The work discuss the possibilities, limits and challenges of the recycling of PET packing in the Brazilian case. The authors analyze the nature and the function of the reverse logistics and its strategies for articulation of the recycling chain. The research is based in the exploratory methodological approach, with adoption of different strategies for the collection of data, involving secondary sources produced by public institutions, specialized organizations and media, and still, interviews semi-structured with specialists in the area. The results point that the Brazilian public and private sectors doesn’t get to organize this activity in the desirable environmental scale. Good performances in the PET packing reverse chain depends on investing in the selective collection and in the market for the recycled products.

  3. Estrutura e relações ambientais de grupos florísticos em fragmento de floresta estacional subtropical

    Directory of Open Access Journals (Sweden)

    Suzane Bevilacqua Marcuzzo

    2013-04-01

    Full Text Available Este estudo teve por objetivos analisar a estrutura de grupos florísticos na vegetação arbórea-arbustiva de um trecho de encosta de Floresta Estacional Subtropical, no Parque Estadual Quarta Colônia, RS, e determinar fatores ambientais importantes na ocorrência das espécies, a fim de subsidiar programas de restauração de áreas degradadas como ecossistema de referência. Para isso, foi realizado estudo fitossociológico em 12 parcelas de 200 m² (10 x 20 m, distantes 20 m entre si, distribuídas sistematicamente em quatro faixas de 100 m entre si, seguindo gradiente de topografia. Em cada parcela foram realizadas a identificação e a medição da circunferência à altura do peito (CAP e da altura total dos indivíduos arbóreos e arbustivos, ou seja, com CAP > 15 cm, denominado componente arbóreo. Os dados do sub-bosque foram obtidos em parcelas circulares com raio de 1,78 m, instaladas no centro das parcelas de 10 x 20 m, medindo-se indivíduos com altura > 30 cm e CAP <15 cm. As variáveis ambientais foram compostas pela declividade, pela intensidade luminosa, pelas características químicas e textura do solo. Os dados foram analisados segundo a estrutura e diversidade da vegetação por meio da análise de agrupamento pelo método TWINSPAN (Two-way Indicator Species Analysis e da ordenação pelo método CCA (Análise de Correspondência Canônica. Foi identificada a formação de dois grupos florísticos. A composição de espécies de cada grupo pertence a diferentes estágios de sucessão natural, conforme histórico de uso agrícola, e, segundo suas características funcionais, podem ser indicadas para programas de restauração florestal.

  4. Análise setorial e topografia da estrutura produtiva: as cooperativas agropecuárias no Paraná

    Directory of Open Access Journals (Sweden)

    Rossana Lott Rodrigues

    2007-09-01

    Full Text Available O objetivo deste artigo é analisar a estrutura produtiva da economia paranaense enfatizando o papel das cooperativas agropecuárias no desenvolvimento do Estado nos anos de 1980, 1985, 1990 e 1995. A partir de tabelas de insumo-produto estimadas para o Paraná foi possível constatar que: i nos anos de 1980 e 1985 o setor Cooperativa foi chave na economia estadual; ii as cooperativas agropecuárias apresentaram, para todos os anos estudados, coeficientes técnicos de produção bastante similares aos das empresas não-cooperativas, mostrando que aquelas estão incorporando em seus processos produtivos o progresso tecnológico consolidado pelas não-cooperativas; iii alguns setores da indústria de transformação, tais como Máquinas e Equipamentos, Material de Transporte e, em menor grau, Metalurgia e Material Elétrico/Eletrônico parecem emergir na economia paranaense; iv a economia paranaense revelou maior diversificação da estrutura produtiva, crescimento das relações externas e, conseqüentemente, incremento da complexidade econômica.The goal of this paper is to analyze the productive structure of the Parana economy emphasizing the role of the agricultural cooperatives in the state development for the years 1980, 1985, 1990 and 1995. Using input-output tables estimated for those years it was possible to detect that: i for the years 1980 and 1985 the Cooperative sector was a key sector for the Parana economy; ii in all years analyzed, the agricultural cooperatives presented technical coefficients of production very similar to those of the non-cooperative sector, showing that the cooperatives are incorporating in their productive process the technological progress that have been consolidated by the non-cooperative sector; iii some sectors of the transformation industry, like Machinery and Equipment, Transport Equipment and, in a lesser scale, Metal Products and Electrical/Electronic Equipment seem to be increasing their participation

  5. Construction of the blowdown and condensation loop

    Energy Technology Data Exchange (ETDEWEB)

    Park, Choon Kyung; Song, Chul Kyung; Cho, Seok; Chun, S. Y.; Chung, Moon Ki

    1997-12-01

    The blowdown and condensation loop (B and C loop) has been constructed to get experimental data for designing the safety depressurization system (SDS) and steam sparger which are considered to implement in the Korea Next Generation Reactor (KNGR). In this report, system description on the B and C loop is given in detail, which includes the drawings and technical specification of each component, instrumentation and control system, and the operational procedures and the results of the performance testing. (author). 7 refs., 11 tabs., 48 figs.

  6. Condensate Accretion in Shock Tube's Expansion Fan

    Science.gov (United States)

    Mezonlin, Ephrem-Denis; DeSilva, Upul P.; Hunte, F.; Johnson, Joseph A., III

    1997-01-01

    It has been shown that turbulence and temperature influence the droplet sizes in expansion fan induced condensation by studying the Rayleigh scattering from one port in our shock tube's test section. We have modified our set-up so as to allow, using two ports, the real time measurement of the influence of turbulence and temperature on the rate at which these droplets grow. To do this, we looked at the Rayleigh scattering from two different ports for ten Reynolds numbers at five different temperatures. We modeled the time of flight of droplets, using the equations of one-dimensional gas dynamics and the measured shock wave speed in shock tube's driven section.

  7. Dissipative phenomena in condensed matter some applications

    CERN Document Server

    Dattagupta, Sushanta

    2004-01-01

    From the field of nonequilibrium statistical physics, this graduate- and research-level volume treats the modeling and characterization of dissipative phenomena. A variety of examples from diverse disciplines like condensed matter physics, materials science, metallurgy, chemical physics etc. are discussed. Dattagupta employs the broad framework of stochastic processes and master equation techniques to obtain models for a wide range of experimentally relevant phenomena such as classical and quantum Brownian motion, spin dynamics, kinetics of phase ordering, relaxation in glasses, dissipative tunneling. It provides a pedagogical exposition of current research material and will be useful to experimentalists, computational physicists and theorists.

  8. Diffusion in condensed matter methods, materials, models

    CERN Document Server

    Kärger, Jörg

    2005-01-01

    Diffusion as the process of particle transport due to stochastic movement is a phenomenon of crucial relevance for a large variety of processes and materials. This comprehensive, handbook- style survey of diffusion in condensed matter gives detailed insight into diffusion as the process of particle transport due to stochastic movement. Leading experts in the field describe in 23 chapters the different aspects of diffusion, covering microscopic and macroscopic experimental techniques and exemplary results for various classes of solids, liquids and interfaces as well as several theoretical concepts and models. Students and scientists in physics, chemistry, materials science, and biology will benefit from this detailed compilation.

  9. Exhaled breath condensate pH assays.

    Science.gov (United States)

    Davis, Michael D; Hunt, John

    2012-08-01

    Airway pH is central to the physiologic function and cellular biology of the airway. The causes of airway acidification include (1) hypopharyngeal gastric acid reflux with or without aspiration through the vocal cords, (2) inhalation of acid fog or gas (such as chlorine), and (3) intrinsic airway acidification caused by altered airway pH homeostasis in infectious and inflammatory disease processes. The recognition that relevant airway pH deviations occur in lung diseases is opening doors to new simple and inexpensive therapies. This recognition has resulted partly from the ability to use exhaled breath condensate as a window on airway acid-base balance.

  10. Exhaled Breath Condensate for Proteomic Biomarker Discovery

    Directory of Open Access Journals (Sweden)

    Sean W. Harshman

    2014-07-01

    Full Text Available Exhaled breath condensate (EBC has been established as a potential source of respiratory biomarkers. Compared to the numerous small molecules identified, the protein content of EBC has remained relatively unstudied due to the methodological and technical difficulties surrounding EBC analysis. In this review, we discuss the proteins identified in EBC, by mass spectrometry, focusing on the significance of those proteins identified. We will also review the limitations surrounding mass spectral EBC protein analysis emphasizing recommendations to enhance EBC protein identifications by mass spectrometry. Finally, we will provide insight into the future directions of the EBC proteomics field.

  11. HADRONIC SCATTERING IN THE COLOR GLASS CONDENSATE.

    Energy Technology Data Exchange (ETDEWEB)

    VENUGOPALAN, R.

    2005-05-15

    Multi-particle production in QCD is dominated by higher twist contributions. The operator product expansion is not very effective here because the number of relevant operators grow rapidly with increasing twist. The Color Glass Condensate (CGC) provides a framework in QCD to systematically discuss ''classical'' (multiple scattering) and ''quantum'' evolution (shadowing) effects in multi-particle production. The apparently insuperable problem of nucleus-nucleus scattering in QCD simplifies greatly in the CGC. A few examples are discussed with emphasis on open problems.

  12. System Study: Isolation Condenser 1998-2014

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, John Alton [Idaho National Lab. (INL), Idaho Falls, ID (United States). Risk Assessment and Management Services Dept.

    2015-12-01

    This report presents an unreliability evaluation of the isolation condenser (ISO) system at four U.S. boiling water reactors. Demand, run hours, and failure data from fiscal year 1998 through 2014 for selected components were obtained from the Institute of Nuclear Power Operations (INPO) Consolidated Events Database (ICES). The unreliability results are trended for the most recent 10 year period, while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing trends were identified. A statistically significant decreasing trend was identified for ISO unreliability. The magnitude of the trend indicated a 1.5 percent decrease in system unreliability over the last 10 years.

  13. System Study: Isolation Condenser 1998–2013

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, John Alton [Idaho National Lab. (INL), Idaho Falls, ID (United States). Risk Assessment and Management Services Dept.

    2015-01-31

    This report presents an unreliability evaluation of the isolation condenser (ISO) system at four U.S. boiling water reactors. Demand, run hours, and failure data from fiscal year 1998 through 2013 for selected components were obtained from the Institute of Nuclear Power Operations (INPO) Consolidated Events Database (ICES). The unreliability results are trended for the most recent 10-year period, while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the ISO results.

  14. The dielectric function of condensed systems

    CERN Document Server

    Keldysh, LV; Kirzhnitz, DA

    1989-01-01

    Much progress has been made in the understanding of the general properties of the dielectric function and in the calculation of this quantity for many classes of media. This volume gathers together the considerable information available and presents a detailed overview of the present status of the theory of electromagnetic response functions, whilst simultaneously covering a wide range of problems in its application to condensed matter physics.The following subjects are covered:- the dielectric function of the homogeneous electron gas, of crystalline systems, and of inh

  15. Boson Condensation in an Einstein Universe

    CERN Document Server

    Altaie, M B; Malkawi, Ehab

    2000-01-01

    In this paper we investigate the Bose-Einstein condensation of massive spin-1 particles in an Einstein universe. The system is considered under relativistic conditions taking into consideration the possibility of particle-antiparticle pair production. An exact expression for the charge density is obtained, then certain approximations are employed in order to obtain the solutions in closed form. A discussion of the approximations employed in this and other work is given. The effects of finite-size and spin-curvature coupling are emphasized.

  16. Polaron in Bose-Einstein-Condensation System

    Institute of Scientific and Technical Information of China (English)

    HUANG Bei-Bing; WAN Shao-Long

    2009-01-01

    We consider the motion of an impurity in a Bose-Einstein condensate system at T=0 K with the contact interactions for boson-boson and boson-impurity.Under the forward-scattering approximation,we obtain a Fr(o)hlich-like Hamiltonian for this system,which means that a polaron can be formed.The effective mass,the phonon number and the energy to form a polaron are obtained.We also discuss the validity of the forwardscattering approximation for this system.

  17. Thermophysics of condensed media. Teplofizika kondensirovannykh sred

    Energy Technology Data Exchange (ETDEWEB)

    Novikov, I.I.

    1985-01-01

    The papers presented in this volume deal with the properties of the condensed state of crystalline and amorphous solids and liquids. Topics discussed include a thermodynamic analysis of dissipative inhomogeneities in a continuum; the effect of plastic deformation of the electrical resistance of niobium; a study of the fine crystal structure, spinodal decomposition mechanism, and phase transformations in alloys based on Fe-Cr and Mu-Cu; and the optimal temperature of superplasticity. Papers are also included on the electron-photon interaction in Ti-V-Mo alloys, elastic properties and the nonlinear parameter of porous media, and hydrogen kinetics in a nickel-base amorphous alloy.

  18. Computational Theory of Warm Condensed Matter

    Energy Technology Data Exchange (ETDEWEB)

    Barbee, T W; Surh, M P; Benedict, L X

    2001-02-25

    We have developed an improved computational theory of condensed matter in the regime where T {le} T{sub Fermi}. Previous methods of calculating the equation of state (EOS) relied on interpolation between low-temperature (solid) and high-temperature (plasma) limits, or employed severe approximations. Recent theoretical and experimental developments have highlighted the need for accurate EOS and opacity data in the intermediate temperature range and offer the opportunity to test theoretical models. We describe our results for EOS and optical properties for temperatures up to 10{sup 6} K, and describe directions for future work.

  19. Kaon condensation and multi-strange matter

    Science.gov (United States)

    Gazda, D.; Friedman, E.; Gal, A.; Mareš, J.

    2010-04-01

    We report on dynamical calculations of multi- K¯ hypernuclei, which were performed by adding K¯ mesons to particle-stable configurations of nucleons, Λ and Ξ hyperons. The K¯ separation energy as well as the baryonic densities saturate with the number of antikaons. We demonstrate that the saturation is a robust feature of multi- K¯ hypernuclei. Because the K¯ separation energy B does not exceed 200 MeV, we conclude that kaon condensation is unlikely to occur in finite strong-interaction self-bound {N,Λ,Ξ} strange hadronic systems.

  20. Vector condensate model of electroweak interactions

    CERN Document Server

    Cynolter, G

    1996-01-01

    Motivated by the fact that the Higgs is not seen we proposed a version of the standard model where the scalar doublet is replaced by a doublet of vector fields. The neutral member of the doublet forms a nonvanishing condensate generating masses for the weak gauge bosons. The phenomenology of the model is studied in high energy e+e- colliders and in the formalism of the parameters S,T,U. The experiments recquire heavy new particles at least 200 GeV which can be produced at the next generation of colliders.

  1. Do termo à estruturação semântica: representação ontológica do domínio da Nanociência e Nanotecnologia utilizando a Estrutura Quali

    Directory of Open Access Journals (Sweden)

    Deni Yuzo Kasama

    2011-01-01

    Full Text Available O presente artigo apresenta as etapas de elaboração de uma ontologia do domínio da Nanociência e Nanotecnologia com vistas à sistematização do léxico dessa área de especialidade, por meio de formalismos descritos na Teoria do Léxico Gerativo, com ênfase na Estrutura Qualia e seus quatro papéis semânticos, a saber: Formal, Constitutivo, Agentivo e Télico. A partir de um córpus da área, e valendo-nos de métodos semiautomáticos para a extração de candidatos a termos e identificação de relações semânticas, delineamos um mapeamento semântico partindo de relações de herança conceitual, cuja representação foi feita em linguagem OWL, com o auxílio da ferramenta Protégé. 

  2. Do termo à estruturação semântica: representação ontológica do domínio da Nanociência e Nanotecnologia utilizando a Estrutura Quali

    Directory of Open Access Journals (Sweden)

    Deni Yuzo Kasama

    2011-01-01

    Full Text Available O presente artigo apresenta as etapas de elaboração de uma ontologia do domínio da Nanociência e Nanotecnologia com vistas à sistematização do léxico dessa área de especialidade, por meio de formalismos descritos na Teoria do Léxico Gerativo, com ênfase na Estrutura Qualia e seus quatro papéis semânticos, a saber: Formal, Constitutivo, Agentivo e Télico. A partir de um córpus da área, e valendo-nos de métodos semiautomáticos para a extração de candidatos a termos e identificação de relações semânticas, delineamos um mapeamento semântico partindo de relações de herança conceitual, cuja representação foi feita em linguagem OWL, com o auxílio da ferramenta Protégé. 

  3. Condition assessment and trending of condenser tube degradation for condenser life extension

    Science.gov (United States)

    Friant, C. Lee; Schlegel, Jennifer L.

    1995-05-01

    Eddy current testing (ET) is routinely used to assess tubing condition in heat exchangers at power plants. Generally, ET results provided by typical final report formats are not well- suited for facilitating condition assessments, especially when the component has a significant number of tubes. The main condenser at Calvert Cliffs Nuclear Power Plant (CCNPP) Unit #1 contains nearly 50,000 tubes. An accurate condition assessment based on 2,500 pages of final reports generated from a 100% condenser inspection in 1992 proved difficult, if not impossible, without some type of automated data management system. With the aid of a data management system, engineering recommendations, founded on database queries and graphics, can be made quickly and reliably. These displays effectively communicate information about overall condition, are helpful in making operating decisions, and aid in predicting future performance. Standard procedures for critical heat exchanger inspections require trending of indication growth over time to determine a rate of tube degradation. Specifically, for the 1994 ET inspection of CCNPP Unit #1 condenser, the size of indications were compared against their 1992 value to determine a mean growth rate. The results of these efforts are presented along with a discussion of how Baltimore Gas and Electric has used eddy current data to prolong the operating life of this condenser while ensuring leak tightness.

  4. Passividade da estrutura metálica para próteses fixas implanto-suportadas = Passivity of metallic framework for implant-supported fixed prosthesis

    Directory of Open Access Journals (Sweden)

    Stüker, Rafael Augusto

    2005-01-01

    Full Text Available Em virtude da freqüência cada vez maior de reabilitações implanto-suportadas, e de que esta modalidade de tratamento vem se mostrando extremamente eficaz na resolução de várias situações clínicas, foi realizada esta revisão literária com o objetivo de ressaltar questões relacionadas à passividade da estrutura metálica em próteses fixas sobre implantes. São descritos aspectos e alternativas relacionadas a alterações ósseas, assim como procedimentos clínicos e laboratoriais que podem influenciar na passividade de estruturas metálicas, esta que talvez seja o fator mais importante na determinação da longevidade tanto da restauração protética quanto dos implantes

  5. Deleuze e A lógica do sentido: o problema da estrutura Deleuze and The logic of sense: structure as a problem

    Directory of Open Access Journals (Sweden)

    Alessandro Carvalho Sales

    2006-01-01

    Full Text Available Este texto pretende acompanhar os principais movimentos apresentados pelo filósofo Gilles Deleuze para propor uma estrutura do sentido, de acordo com a Lógica do sentido (1969. Para tanto, tentando nos alçar ao estruturalismo muito particular de Deleuze, seguiremos especialmente alguns argumentos estabelecidos entre a quarta (Das dualidades e a oitava (Da estrutura séries desse livro, bem como pontos do artigo Em que se pode reconhecer o estruturalismo? (1972.This article intends to follow the main movements presented by the philosopher Gilles Deleuze (1925-1995. to propose a strucuture of the sense according to The logic of sense (1969. In order to do this, trying to achieve the very particular Deleuzian structuralism, we will follow especially some arguments established between the fourth (Of dualities. and the eighth (Of structure. series of this book, as well as points of the text How do we recognize structuralism? (1974.

  6. Aquisição das estruturas silábicas "VC e V": mais uma abordagem através da teoria da otimidade?

    Directory of Open Access Journals (Sweden)

    Bonilha, Giovana Ferreira Gonçalves

    2003-01-01

    Full Text Available O presente trabalho faz um estudo da aquisição das estruturas silábicas CV e V no português brasileiro, buscando trazer contribuições para as pesquisas em aquisição da fonologia, bem como tecer considerações sobre o modelo proposto pela teoria da otimidade. A pesquisa demonstra que, considerando as propostas já apresentadas para a aquisição das estruturas silábicas CV e V - Costa e Freitas (1998 e Matzenauer (1999 -,apenas Matzenauer é capaz de dar conta dos dados do português sem comprometer os princípios básicos da teoria. O trabalho também focaliza as estratégias de reparo aplicadas, vinculando-as a questões segmentais e métricas

  7. Modeling the Phase Composition of Gas Condensate in Pipelines

    Science.gov (United States)

    Dudin, S. M.; Zemenkov, Yu D.; Shabarov, A. B.

    2016-10-01

    Gas condensate fields demonstrate a number of thermodynamic characteristics to be considered when they are developed, as well as when gas condensate is transported and processed. A complicated phase behavior of the gas condensate system, as well as the dependence of the extracted raw materials on the phase state of the deposit other conditions being equal, is a key aspect. Therefore, when designing gas condensate lines the crucial task is to select the most appropriate methods of calculating thermophysical properties and phase equilibrium of the transported gas condensate. The paper describes a physical-mathematical model of a gas-liquid flow in the gas condensate line. It was developed based on balance equations of conservation of mass, impulse and energy of the transported medium within the framework of a quasi-1D approach. Constitutive relationships are given separately, and practical recommendations on how to apply the research results are provided as well.

  8. CFD modelling of condensers for freeze-drying processes

    Indian Academy of Sciences (India)

    Miriam Petitti; Antonello A Barresi; Daniele L Marchisio

    2013-12-01

    The aim of the present research is the development of a computational tool for investigating condensation processes and equipment with particular attention to freeze-dryers. These condensers in fact are usually operated at very low pressures, making it difficult to experimentally acquire quantitative knowledge of all the variables involved. Mathematical modelling and CFD (Computational Fluid Dynamics) simulations are used here to achieve a better comprehension of the flow dynamics and of the process of ice condensation and deposition in the condenser, in order to evaluate condenser efficiency and gain deeper insights of the process to be used for the improvement of its design. Both a complete laboratory-scale freeze-drying apparatus and an industrial-scale condenser have been investigated in this work, modelling the process of water vapour deposition. Different operating conditions have been considered and the influence exerted by the inert gas as well as other parameters has been investigated.

  9. Condensates in Quantum Chromodynamics and the Cosmological Constant

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, Stanley J.; Shrock, Robert

    2009-05-08

    Casher and Susskind have noted that in the light-front description, spontaneous chiral symmetry breaking in quantum chromodynamics (QCD) is a property of hadronic wavefunctions and not of the vacuum. Here we show from several physical perspectives that, because of color confinement, quark and gluon QCD condensates are associated with the internal dynamics of hadrons. We discuss condensates using condensed matter analogues, the AdS/CFT correspondence, and the Bethe-Salpeter/Dyson-Schwinger approach for bound states. Our analysis is in agreement with the Casher and Susskind model and the explicit demonstration of 'in-hadron' condensates by Roberts et al., using the Bethe-Salpeter/Dyson-Schwinger formalism for QCD bound states. These results imply that QCD condensates give zero contribution to the cosmological constant, since all of the gravitational effects of the in-hadron condensates are already included in the normal contribution from hadron masses.

  10. Nonresonant optical control of a spinor polariton condensate

    Science.gov (United States)

    Askitopoulos, A.; Kalinin, K.; Liew, T. C. H.; Cilibrizzi, P.; Hatzopoulos, Z.; Savvidis, P. G.; Berloff, N. G.; Lagoudakis, P. G.

    2016-05-01

    We investigate the spin dynamics of polariton condensates spatially separated from and effectively confined by the pumping exciton reservoir. We obtain a strong correlation between the ellipticity of the nonresonant optical pump and the degree of circular polarization (DCP) of the condensate at the onset of condensation. With increasing excitation density we observe a reversal of the DCP. The spin dynamics of the trapped condensate are described within the framework of the spinor complex Ginzburg-Landau equations in the Josephson regime, where the dynamics of the system are reduced to a current-driven Josephson junction. We show that the observed spin reversal is due to the interplay between an internal Josephson coupling effect and the detuning of the two projections of the spinor condensate via transition from a synchronized to a desynchronized regime. These results suggest that spinor polariton condensates can be controlled by tuning the nonresonant excitation density offering applications in electrically pumped polariton spin switches.

  11. Targeted Functionalization of Nanoparticle Thin Films via Capillary Condensation

    KAUST Repository

    Gemici, Zekeriyya

    2009-03-11

    Capillary condensation, an often undesired natural phenomenon in nanoporous materials, was used advantageously as a universal functionalization strategy in nanoparticle thin films assembled layer-by-layer. Judicious choice of nanoparticle (and therefore pore) size allowed targeted capillary condensation of chemical vapors of both hydrophilic and hydrophobic molecules across film thickness. Heterostructured thin films with modulated refractive index profiles produced in this manner exhibited broadband antireflection properties with an average reflectance over the visible region of the spectrum of only 0.4%. Capillary condensation was also used to modify surface chemistry and surface energy. Photosensitive capillary-condensates were UV-cross-linked in situ. Undesired adventitious condensation of humidity could be avoided by condensation of hydrophobic materials such as poly(dimethyl siloxane). © 2009 American Chemical Society.

  12. Entropy generation in a condenser and related correlations

    Directory of Open Access Journals (Sweden)

    Askowski Rafał

    2015-06-01

    Full Text Available The paper presents an analysis of relations describing entropy generation in a condenser of a steam unit. Connections between entropy generation, condenser ratio, and heat exchanger effectiveness, as well as relations implied by them are shown. Theoretical considerations allowed to determine limits of individual parameters which describe the condenser operation. Various relations for average temperature of the cold fluid were compared. All the proposed relations were verified against data obtained using a simulator and actual measurement data from a 200 MW unit condenser. Based on data from a simulator it was examined how the sum of entropy rates, steam condenser effectiveness, terminal temperature difference and condenser ratio vary with the change in the inlet cooling water temperature, mass flow rate of steam and the cooling water mass flow rate.

  13. Dropwise Condensation on a Radial Gradient Surface

    Science.gov (United States)

    Macner, Ashley; Daniel, Susan; Steen, Paul

    2013-11-01

    In transient dropwise condensation from steam onto a cool surface, distributions of drops evolve by nucleation, growth, and coalescence. This study examines how surface functionalization affects drop growth and coalescence. Surfaces are treated by silanization to deliver either a spatially uniform contact-angle (hydrophilic, neutral, and hydrophobic) or a radial gradient of contact-angles. The time evolution of number-density and associated drop-size distributions are reported. For a typical condensation experiment on a uniform angle surface, the number-density curves show two regimes: an initial increase in number-density as a result of nucleation and a subsequent decrease in number-density as a result of larger scale coalescence events. Without a removal mechanism, the fractional coverage, regardless of treatment, approaches unity. For the same angle-surface, the associated drop-size distributions progress through four different shapes along the growth curve. In contrast, for a radial gradient surface where removal by sweeping occurs, the number-density increases and then levels off to a value close to the maximum number-density that is well below unity coverage and only two shapes of distributions are observed. Implications for heat transfer will be discussed. This work was supported by a NASA Office of the Chief Technologist's Space Technology Research Fellowship.

  14. Gravity, holography and applications to condensed matter

    CERN Document Server

    Baggioli, Matteo

    2016-01-01

    Momentum relaxation is an ever-present and unavoidable ingredient of any realistic condensed matter system. In real-world materials the presence of a lattice, impurities or disorder forces momentum to dissipate and leads to relevant physical effects such as the finiteness of the DC transport properties, i.e. conductivities. The main purpose of this thesis is the introduction of momentum dissipation and its consequent effects into the framework of AdS/CMT, namely the applications of the gauge-gravity duality to condensed matter. A convenient and effective way of breaking the translational symmetry associated to such a conservation law is provided by massive gravity (MG) bulk theories. We consider generic massive gravity models embedded into asymptotically Anti de Sitter spacetime and we analyze them using holographic techniques. We study in detail their consistency and stability. We then focus our attention on the transport properties of the CFT duals. A big part of our work is devoted to the analysis of the e...

  15. Exhaled Breath Condensate: Technical and Diagnostic Aspects

    Directory of Open Access Journals (Sweden)

    Efstathia M. Konstantinidi

    2015-01-01

    Full Text Available Purpose. The aim of this study was to evaluate the 30-year progress of research on exhaled breath condensate in a disease-based approach. Methods. We searched PubMed/Medline, ScienceDirect, and Google Scholar using the following keywords: exhaled breath condensate (EBC, biomarkers, pH, asthma, gastroesophageal reflux (GERD, smoking, COPD, lung cancer, NSCLC, mechanical ventilation, cystic fibrosis, pulmonary arterial hypertension (PAH, idiopathic pulmonary fibrosis, interstitial lung diseases, obstructive sleep apnea (OSA, and drugs. Results. We found 12600 related articles in total in Google Scholar, 1807 in ScienceDirect, and 1081 in PubMed/Medline, published from 1980 to October 2014. 228 original investigation and review articles were eligible. Conclusions. There is rapidly increasing number of innovative articles, covering all the areas of modern respiratory medicine and expanding EBC potential clinical applications to other fields of internal medicine. However, the majority of published papers represent the results of small-scale studies and thus current knowledge must be further evaluated in large cohorts. In regard to the potential clinical use of EBC-analysis, several limitations must be pointed out, including poor reproducibility of biomarkers and absence of large surveys towards determination of reference-normal values. In conclusion, contemporary EBC-analysis is an intriguing achievement, but still in early stage when it comes to its application in clinical practice.

  16. The Solar Photosphere: Evidence for Condensed Matter

    Directory of Open Access Journals (Sweden)

    Robitaille P. M.

    2006-04-01

    Full Text Available The stellar equations of state treat the Sun much like an ideal gas, wherein the photosphere is viewed as a sparse gaseous plasma. The temperatures inferred in the solar interior give some credence to these models, especially since it is counterintuitive that an object with internal temperatures in excess of 1 MK could be existing in the liquid state. Nonetheless, extreme temperatures, by themselves, are insufficient evidence for the states of matter. The presence of magnetic fields and gravity also impact the expected phase. In the end, it is the physical expression of a state that is required in establishing the proper phase of an object. The photosphere does not lend itself easily to treatment as a gaseous plasma. The physical evidence can be more simply reconciled with a solar body and a photosphere in the condensed state. A discussion of each physical feature follows: (1 the thermal spectrum, (2 limb darkening, (3 solar collapse, (4 the solar density, (5 seismic activity, (6 mass displacement, (7 the chromosphere and critical opalescence, (8 shape, (9 surface activity, (10 photospheric/coronal flows, (11 photospheric imaging, (12 the solar dynamo, and (13 the presence of Sun spots. The explanation of these findings by the gaseous models often requires an improbable combination of events, such as found in the stellar opacity problem. In sharp contrast, each can be explained with simplicity by the condensed state. This work is an invitation to reconsider the phase of the Sun.

  17. Condensation energy of the superconducting bilayer cuprates

    Indian Academy of Sciences (India)

    Govind; Ajay; S K Joshi

    2002-05-01

    In the present work, we report the interplay of single particle and Cooper pair tunnelings on the superconducting state of layered high-c cuprate superconductors. For this we have considered a model Hamiltonian incorporating the intra-planar interactions and the contributions arising due to the coupling between the planes. The interplanar interactions include the single particle tunneling as well as the Josephson tunneling of Cooper pairs between the two layers. The expression of the out-of-plane correlation parameter which describes the hopping of a particle from one layer to another layer in the superconducting state is obtained within a Bardeen–Cooper–Schriefer (BCS) formalism using the Green’s function technique. This correlation is found to be sensitive to the various parameter of the model Hamiltonian. We have calculated the out-of-plane contribution to the superconducting condensation energy. The calculated values of condensation energy are in agreement with those obtained from the specific heat and the -axis penetration depth measurements on bilayer cuprates.

  18. Chiral magnetic effect in condensed matter systems

    Science.gov (United States)

    Li, Qiang; Kharzeev, Dmitri E.

    2016-12-01

    The chiral magnetic effect (CME) is the generation of electrical current induced by chirality imbalance in the presence of magnetic field. It is a macroscopic manifestation of the quantum chiral anomaly [S. L. Adler. Axial-vector vertex in spinor electrodynamics. Physical Review, 177, 2426 (1969), J. S. Bell and R. Jackiw. A PCAC puzzle: π 0 γγin the σ-model. Il Nuovo Cimento A, 60, 47-61 (1969)] in systems possessing charged chiral fermions. In quark-gluon plasma containing nearly massless quarks, the chirality imbalance is sourced by the topological transitions. In condensed matter systems, the chiral quasiparticles emerge in gapless semiconductors with two energy bands having pointlike degeneracies opening the path to the study of chiral anomaly [H. B. Nielsen and M. Ninomiya. The Adler-Bell-Jackiw anomaly and Weyl fermions in a crystal. Physics Letters B, 130, 389-396 (1983)]. Recently, these novel materials - so-called Dirac and Weyl semimetals have been discovered experimentally, are suitable for the investigation of the CME in condensed matter experiments. Here we report on the first experimental observation of the CME in a 3D Dirac semimetal ZrTe5 [Q. Li, D. E. Kharzeev, C. Zhang, Y. Huang, I. Pletikosić, A. V. Fedorov, R. D. Zhong, J. A. Schneeloch, G. D. Gu, and T. Valla. Chiral magnetic effect in ZrTe5. Nature Physics (2016) doi:10.1038/nphys3648].

  19. The Planck Scale from Top Condensation

    CERN Document Server

    Bai, Yang; Ponton, Eduardo

    2008-01-01

    We propose a scenario in which the Planck scale is dynamically linked to the electroweak scale induced by top condensation. The standard model field content, without the Higgs, is promoted to a 5D warped background. The only additional ingredient is a 5D fermion with the quantum numbers of the right-handed top. Localization of the zero-modes leads, at low energies, to a Nambu-Jona-Lasinio model that also stabilizes the radion field dynamically thus explaining the hierarchy between the Planck scale and v_EW = 174 GeV. The top mass arises dynamically from the electroweak breaking condensate. The other standard model fermion masses arise naturally from higher-dimension operators, and the fermion mass hierarchies and flavor structure can be explained from the localization of the zero-modes in the extra dimension. The model is easily consistent with the electroweak precision data, since the Kaluza-Klein scale is predicted to be about two orders of magnitude above the electroweak scale. This little hierarchy is a d...

  20. Nonlinear phenomena in Bose-Einstein condensates

    Science.gov (United States)

    Carr, Lincoln D.

    2008-05-01

    We present a medley of results from the last three years on nonlinear phenomena in BECs [1]. These include exact dynamics of multi-component condensates in optical lattices [2], vortices and ring solitons [3], macroscopic quantum tunneling [4], nonlinear band theory [5], and a pulsed atomic soliton laser [6]. 1. Emergent Nonlinear Phenomena in Bose-Einstein Condensates: Theory and Experiment, ed. P. G. Kevrekidis, D. J. Frantzeskakis, and R. Carretero-Gonzalez (Springer-Verlag, 2008). 2. R. Mark Bradley, James E. Bernard, and L. D. Carr, e-print arXiv:0711.1896 (2007). 3. G. Herring, L. D. Carr, R. Carretero-Gonzalez, P. G. Kevrekidis, D. J. Frantzeskakis, Phys. Rev. A in press, e-print arXiv:0709.2193 (2007); L. D. Carr and C. W. Clark, Phys. Rev. A v. 74, p.043613 (2006); L. D. Carr and C. W. Clark, Phys. Rev. Lett. v. 97, p.010403 (2006). 4. L. D. Carr, M. J. Holland, and B. A. Malomed, J. Phys. B: At. Mol. Opt. Phys., v.38, p.3217 (2005) 5. B. T. Seaman, L. D. Carr, and M. J. Holland, Phys. Rev. A, v. 71, p.033622 (2005). 6. L. D. Carr and J. Brand, Phys. Rev. A, v.70, p.033607 (2004); L. D. Carr and J. Brand, Phys. Rev. Lett., v.92, p.040401 (2004).