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Sample records for al modelado 3d

  1. An approach to 3D modeling of marine platforms in operation; Un enfoque al modelado 3D de plataformas marinas en operacion

    Energy Technology Data Exchange (ETDEWEB)

    Gomez Camargo, Octavio [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2007-07-01

    marinas se estan disenando con herramientas CAD, por lo que antes de su instalacion cuentan con un modelo 3D, el cual se va actualizando conforme avanza el diseno, hasta llegar a la version aprobada para construccion. Posteriormente, el modelo digital de la plataforma marina sirve para guiar en la construccion y dar seguimiento al avance de la misma. De igual forma, el modelo 3D se debe de actualizar respecto a los cambios surgidos durante la construccion e instalacion, hasta la puesta en servicio de la plataforma, sin embargo, muchas de estas fueron construidas cuando aun no se disponia de estas herramientas, por lo que se torna necesario construir el modelo digital de acuerdo al estado actual que presenten. Para desarrollar el modelo digital de las plataformas marinas en operacion, las actividades se agrupan en tres grandes etapas: especificacion de alcance, recuperacion de informacion y modelado.

  2. Aproximación al modelado del componente conceptual básico del Dispositivo Hipermedial Dinámico

    Directory of Open Access Journals (Sweden)

    Rodríguez, Guillermo L.

    2011-01-01

    Full Text Available El presente trabajo interdisciplinario, propone una primera aproximación conceptual y de uso al modelado descriptivo y de simulación para el análisis del Dispositivo Hipermedial Dinámico con la finalidad de avanzar hacia la generación de configuraciones más efectivas que posibiliten desarrollos e implementaciones tanto de tecnologías sociales como digitales para la construcción de variadas alternativas de integración responsable de las TIC. Se plantea la utilización del formalismo DEVS (Discrete EVents dynamic Systems que propone una teoría de modelado de sistemas a tiempo continuo usando modelado de eventos discretos. En ese sentido, se presenta el modelado y simulación del denominado "Paquete Hipermedial", como componente conceptual básico del DHD. Lo expuesto aporta un posible camino hacia el análisis evaluativo sobre cómo se desarrollan o se podrían implementar procesos de participación responsable a través de redes sociotécnicas que tengan por objeto investigar, educar y producir en actual contexto físico-virtual.

  3. Modelado e impresión en 3D en la enseñanza de las matemáticas: un estudio exploratorio

    Directory of Open Access Journals (Sweden)

    Beltrán Pellicer, Pablo

    2017-01-01

    Full Text Available Las impresoras en 3D constituyen un recurso que poco a poco está encontrando su hueco en los centros educativos, de la mano de docentes innovadores y creativos. Normalmente, son profesores de Tecnología o Informática en educación secundaria, o los de ciertas especialidades de ciclos formativos, los que buscan utilizar el diseño de piezas y su posterior impresión como medio para alcanzar sus objetivos de aprendizaje. Nos planteamos aquí como objetivo el justificar la utilización de este recurso para la enseñanza de las matemáticas. Método: Se adopta una metodología de carácter descriptivo y exploratorio. Se realiza, en primer lugar, un breve análisis de la tecnología de impresión y de modelado de objetos en 3D. Posteriormente, a partir de una serie de experiencias de aula, analizamos algunas tareas que se pueden plantear para comprobar que se ponen en juego conocimientos matemáticos, aplicando la noción de configuración de objetos y significados matemáticos. Resultados: Las configuraciones de objetos matemáticos para cada una de las situaciones revelan contenidos propios del nivel educativo del alumnado al que se dirigen. Conclusiones: Es pertinente, desde el punto de vista epistémico, considerar propuestas de enseñanza-aprendizaje que hagan uso del modelado y la impresión en 3D. Abstract: 3D printers are finding their place in educational institutions, as innovative and creative teachers use them to propose activities in their lessons. Usually, they are teachers of technology and computer science in secondary education, or of certain specialties in professional training. In these cases, the tasks involve designing and printing solid pieces as a means of achieving the learning objectives. The purpose of this paper is to justify using this resource in the teaching of mathematics at different educational levels. Method: We adopt a descriptive and exploratory qualitative methodology, first depicting 3D printing technology and

  4. Modelado de Secaderos Rotatorios en Isocorriente

    Directory of Open Access Journals (Sweden)

    F. Castaño

    2009-10-01

    Full Text Available Resumen: Este trabajo presenta una metodología para el modelado de secaderos rotatorios de s ólidos en isocorriente. El planteamiento del modelo está basado tanto en ecuaciones diferenciales paramétricas como en el uso de algunas correlaciones que permiten simplificar su tratamiento. En el trabajo se muestran aspectos de modelado que son comunes a la mayoría de instalaciones de secado y se detallan algunos puntos que pueden ser particulares o específicos de cada planta en función de su configuración o del material de secado. Se muestran también los ensayos a los que hay que someter al material para la determinación de algunas expresiones analíticas imprescindibles en el modelo. Asimismo, se presenta la aplicación del modelado a una planta experimental de secado de arena. Palabras clave: Secadero rotatorio, modelado, ecuaciones diferenciales, parámetros distribuidos, coeficientes de correlación

  5. Modelado de un amortiguador magneto-reológico mediante EcosimPro

    OpenAIRE

    Rodríguez Cadenas, Rubén

    2012-01-01

    El objetivo de este proyecto es la creación de una librería en la herramienta de modelado y simulación EcosimPro enfocada a amortiguadores magneto‐reológicos. El modelado y simulación mediante cualquier herramienta informática permite la obtención de datos y el desarrollo de componentes con un coste inferior al que habría que invertir mediante una experimentación real. Además, permite llevar el componente hasta el límite sin el riesgo de romperlo o dejarlo inutilizable. Por tanto, se puede de...

  6. The crystal structure of γ-AlD3

    International Nuclear Information System (INIS)

    Brinks, H.W.; Brown, C.; Jensen, C.M.; Graetz, J.; Reilly, J.J.; Hauback, B.C.

    2007-01-01

    γ-AlD 3 was synthesized from LiAlD 4 and AlCl 3 via thermal decomposition of aluminum hydride etherate in presence of excess LiAlD 4 . γ-AlD 3 was determined by powder neutron diffraction and synchrotron X-ray diffraction to crystallize in the space group Pnnm. The orthorhombic structure has unit-cell dimensions a = 7.3360(3) A, b = 5.3672(2) A and c = 5.7562(1) A, and it consists of both corner- and edge-sharing AlD 6 octahedra where each hydrogen is shared between two octahedra. The average Al-D distances in octahedra with edge-sharing is 1.706 A and in the octahedra with only corner-sharing 1.719 A

  7. HERRAMIENTAS EN 3D PARA EL MODELADO DE ESCENARIOS VIRTUALES BASADOS EN LOGO. ESTADO DEL ARTE

    Directory of Open Access Journals (Sweden)

    Luz Santamaría Granados

    2009-01-01

    Full Text Available Este artículo revisa la comprobada fundamentación pedagógica de LOGO (Papert, 2003 que a su vez ofrece interesantes estrategias de motivación para los niños, en aspectos tales como el desarrollo de habilidades espaciales a través de su propia exploración de mundos virtuales. La metodología original fue propuesta por Seymour Papert para escenarios en dos dimensiones (2D. Por lo tanto, se analiza la posibilidad de integrar las ventajas pedagógicas de LOGO con una interfaz gráfica en tres dimensiones (3D, al aprovechar la tecnología contemplada en los estándares del consorcio Web3D. Además menciona los componentes X3D que permiten el uso de avatares (humanoides para facilitar la interacción de los usuarios en mundos virtuales dinámicos, al disponer de personajes adicionales al de la tortuga de LOGO.

  8. Competencia Digital: Uso y manejo de modelos 3D tridimensionales digitales e impresos en 3D

    OpenAIRE

    Jose Luis Saorín; Cecile Meier; Jorge de la Torre-Cantero; Carlos Carbonell-Carrera; Dámari Melián-Díaz; Alejandro Bonnet de León

    2017-01-01

    El uso y manejo de modelos tridimensionales digitales no está concebido dentro de la competencia digital de los currículos de secundaria y Bachillerato. Sin embargo muchos autores relacionan la competencia digital con el manejo de modelos 3D, el modelado 3D y entornos virtuales tridimensionales (Realidad aumentada, virtual,…). En este artículo se presenta un recurso educativo para facilitar el acceso a contenidos didácticos de carácter tridimensional digital y tangible. Determinadas materias ...

  9. Modelado sólido y análisis por elementos finitos de un cilindro de motor endotérmico de 2 tiempos de altas prestaciones

    OpenAIRE

    Pérez Ferreirós, Oscar

    2005-01-01

    El proyecto pretende explicar el proceso de evolución de un cilindro monobloque de motor endotérmico, 2 tiempos de altas prestaciones. El proceso real de evolución del motor consta de los siguientes pasos: - Modelado en 3D del cilindro, de una forma sencilla para que sea fácilmente modificable (modelado con Pro-Engineer WildFire). - Hipótesis de cálculo para realizar un cálculo de esfuerzos sobre los pernos que fijan el culatín y la culata del cilindro (Se proponen 2 estudio...

  10. Incorporación de TICs de modelado molecular en la enseñanza universitaria de la Química

    Directory of Open Access Journals (Sweden)

    Marzocchi, Victorio A.

    2012-12-01

    Full Text Available Se informan logros alcanzados en la incorporación de TICs de visualización y modelado molecular en el inicio de carreras de grado de la Facultad de Ingeniería Química, UNL. A partir de 2008 desarrollamos una serie de actividades: promovimos la instalación de doble booteo en los gabinetes informáticos, seleccionamos e instalamos software libre de visualización y modelado molecular, dictamos un ciclo de charlas y realizamos talleres para estudiantes y docentes. Estas actividades iniciales lograron despertar un imprescindible interés y generar el involucramiento y compromiso de docentes que permitieron proponer y respaldar actualizaciones curriculares que incluyen estas TICs tanto en asignaturas optativas como del tercio inicial. La modificación curricular más importante es la realizada en la asignatura Informática que se dicta para los ingresantes de todas las carreras de la FIQ. En el primer cuatrimestre de 2011 se incluyó el Gabedit, interfaz gráfica con un avanzado constructor de moléculas, y en el primer cuatrimestre de 2012 se amplió al Jmol que permite animación con visión estereoscópica usando lentes 3D anaglifo. Estos logros configuran un hecho de alto impacto en todas las actividades de docencia, que potenciará diversas iniciativas de actualización, perfeccionamiento, aplicación y desarrollo con estas herramientas.

  11. Método y sistema de modelado de memoria cache

    OpenAIRE

    Posadas Cobo, Héctor; Villar Bonet, Eugenio; Díaz Suárez, Luis

    2010-01-01

    Un método de modelado de una memoria cache de datos de un procesador destino, para simular el comportamiento de dicha memoria cache de datos en la ejecución de un código software en una plataforma que comprenda dicho procesador destino, donde dicha simulación se realiza en una plataforma nativa que tiene un procesador diferente del procesador destino que comprende dicha memoria cache de datos que se va a modelar, donde dicho modelado se realiza mediante la ejecución en dicha plataforma nativa...

  12. Stress Wave attenuation in SiC3D/Al Composite

    International Nuclear Information System (INIS)

    Yuan Chunyuan; Wang Yangwei; Li Guoju; Zhang Xu; Gao Jubin

    2013-01-01

    SiC 3D /Al composite is a kind of special composite with interpenetrating network microstructure. The attenuation properties of stress wave propagation along the SiC 3D /Al composite are studied by a Split Hopkinson Pressure Bar system and FEM simulations, and the attenuation mechanism is discussed in this paper. Results show that the attenuation rate of the stress wave in the composite is up to 1.73MPa·mm −1 . The reduction of the amplitude of waves is caused by that plenty of interfaces between SiC and Al within the composite acting with stress waves. When the incident plane wave reaches the SiC 3D /Al interface, reflection wave and transmission wave propagates in different directions along the irregular interface between SiC phase and aluminium phase due to the impedance mismatch of them, which leads to the divergence of stress wave. At the same time, some stress micro-focuses occurs in the aluminium phase for the complex wave superimposition, and some plastic deformation may take place within such micro-regions, which results in the consumption of stress wave energy. In conclusion, the stress wave attenuation is derived from divergence and consumption of stress wave.

  13. Modelado y uso de escenarios de aprendizaje en entornos b-learning desde la práctica educativa

    NARCIS (Netherlands)

    Burgos, Daniel; Corbalan, Gemma

    2006-01-01

    Please, cite this publication as: Burgos, D. & Corbalan, G. (2006). Modelado y uso de escenarios de aprendizaje en entornos b-learning desde la práctica educativa. III Jornadas Campus Virtual. September, Madrid (Spain): University Complutense of Madrid. Retrieved June 30th, 2006, from

  14. Metodología de modelado de aplicaciones web móviles basada en componentes

    OpenAIRE

    Vera, Pablo Martín; Pons, Claudia; González González, Carina Soledad; Giulianelli, Daniel Alberto; Rodríguez, Rocío Andrea

    2013-01-01

    Esta línea de investigación busca crear una metodología de modelado utilizando una extensión conservativa de UML (Lenguaje Unificado de Modelado) que permita diseñar aplicaciones web móviles centrándose en el modelado de la interfaz de usuario mediante la utilización de componente configurables. El objetivo final es la generación automática del código fuente completo de la aplicación. Para lograr tal fin se extienden los diagramas de clases y componentes de UML. El diagrama de clases es exten...

  15. Nanometre-scale 3D defects in Cr2AlC thin films.

    Science.gov (United States)

    Chen, Y T; Music, D; Shang, L; Mayer, J; Schneider, J M

    2017-04-20

    MAX-phase Cr 2 AlC containing thin films were synthesized by magnetron sputtering in an industrial system. Nanometre-scale 3D defects are observed near the boundary between regions of Cr 2 AlC and of the disordered solid solution (CrAl) x C y . Shrinkage of the Cr-Cr interplanar distance and elongation of the Cr-Al distance in the vicinity of the defects are detected using transmission electron microscopy. The here observed deformation surrounding the defects was described using density functional theory by comparing the DOS of bulk Cr 2 AlC with the DOS of a strained and unstrained Cr 2 AlC(0001) surface. From the partial density of states analysis, it can be learned that Cr-C bonds are stronger than Cr-Al bonds in bulk Cr 2 AlC. Upon Cr 2 AlC(0001) surface formation, both bonds are weakened. While the Cr-C bonds recover their bulk strength as Cr 2 AlC(0001) is strained, the Cr-Al bonds experience only a partial recovery, still being weaker than their bulk counterparts. Hence, the strain induced bond strengthening in Cr 2 AlC(0001) is larger for Cr d - C p bonds than for Cr d - Al p bonds. The here observed changes in bonding due to the formation of a strained surface are consistent with the experimentally observed elongation of the Cr-Al distance in the vicinity of nm-scale 3D defects in Cr 2 AlC thin films.

  16. Role of Delamination in Zeolite-Catalyzed Aromatic Alkylation: UCB-3 versus 3-D Al-SSZ-70

    Energy Technology Data Exchange (ETDEWEB)

    Runnebaum, Ron C.; Ouyang, Xiaoying; Edsinga, Jeffrey A.; Rea, Thomas; Arslan, Ilke; Hwang, Son-Jong; Zones, Stacey I.; Katz, Alexander

    2014-07-03

    Delaminated zeolite UCB-3 exhibits 2.4-fold greater catalytic activity relative to its three-dimensional (3D) zeolite counterpart, Al-SSZ-70, and 2.0-fold greater activity (per catalyst mass) when compared with industrial catalyst MCM-22, for the alkylation of toluene with propylene at 523 K. The former increase is nearly equal to the observed relative increase in external surface area and acid sites upon delamination. However, at 423 K for the same reaction, UCB-3 exhibits a 3.5-fold greater catalytic activity relative to 3D Al-SSZ-70. The higher relative rate enhancement for the delaminated material at lower temperature can be elucidated on the basis of increased contributions from internal acid sites. Evidence of possible contributions from such acid sites is obtained by performing catalysis after silanation treatment, which demonstrates that although virtually all catalysis in MCM-22 occurs on the external surface, catalysis also occurs on internal sites for 3D Al-SSZ-70. The additional observed enhancement at low temperatures can therefore be rationalized by greater access to internal active sites as a result of sheet breakage during delamination. Such breakage leads to shorter characteristic internal diffusion paths and was visualized using TEM comparisons of UCB-3 and 3D Al-SSZ-70.

  17. Competencia Digital: Uso y manejo de modelos 3D tridimensionales digitales e impresos en 3D

    Directory of Open Access Journals (Sweden)

    Jose Luis Saorín

    2017-07-01

    Full Text Available El uso y manejo de modelos tridimensionales digitales no está concebido dentro de la competencia digital de los currículos de secundaria y Bachillerato. Sin embargo muchos autores relacionan la competencia digital con el manejo de modelos 3D, el modelado 3D y entornos virtuales tridimensionales (Realidad aumentada, virtual,…. En este artículo se presenta un recurso educativo para facilitar el acceso a contenidos didácticos de carácter tridimensional digital y tangible. Determinadas materias precisan de la comprensión e interpretación de conceptos volumétricos: los recursos didácticos innovadores para la edición, visualización e impresión 3D ofrecen una alternativa a las representaciones 2D en los procesos de enseñanza y aprendizaje. En este artículo se describe la creación de un catálogo escultórico que contempla versiones digitales y tangibles de modelos tridimensionales de las esculturas a través de tecnologías innovadoras de bajo coste como la visualización e impresión 3D. La prueba piloto desarrollada con 15 alumnos de bachillerato recoge una alta valoración de los participantes sobre las tecnologías empleadas.

  18. Crystal structure and stability of LiAlD4 with TiF3 additive

    International Nuclear Information System (INIS)

    Brinks, H.W.; Fossdal, A.; Fonnelop, J.E.; Hauback, B.C.

    2005-01-01

    LiAlD 4 samples with TiF 3 additives have been investigated by synchrotron X-ray diffraction, neutron diffraction and a Sieverts-type apparatus. Directly after ball milling there are no signs of any Ti-containing phases, and the unit-cell of LiAlD 4 and Al give no indication of any solid solutions. Hence it is concluded that the Ti is in an amorphous state directly after ball milling. Furthermore, no LiF was observed in the samples. Based on Sieverts-type measurements the plateau pressure at 80 deg C has been proved to be higher than 85 bar. Samples stored in a glove box are slowly desorbed, and after 6 months for a LiAlD 4 + TiF 3 sample, the reaction to LiD + Al is nearly finished

  19. Una extensión de UML para el modelado de servicios Web

    Directory of Open Access Journals (Sweden)

    Esperanza Marcos M.

    2004-01-01

    Full Text Available Los servicios Web han surgido para proveer un marco basado en estándares, que permite la interacción de aplicaciones a través de la Web. A pesar de que existen varias tecnologías que facilitan el desarrollo de servicios Web y aplicaciones orientadas a servicios, la carencia de una base metodológica sólida para el desarrollo de tales aplicaciones, plantea la necesidad de nuevos métodos o técnicas de modelado que puedan garantizar la calidad en el desarrollo de este tipo de aplicaciones. MIDAS es un marco metodológico orientado a modelos para el desarrollo de SIWs, que está basado en UML, XML y tecnología objetorelacional y que propone el modelado del comportamiento del sistema basado en servicios Web. En este artículo se presenta una extensión de UML para el modelado de servicios Web, basada en el estándar Web Service Description Language (WSDL propuesto por el W3C para la descripción de servicios Web. La extensión propuesta aporta una notación en UML que, por un lado, permite obtener una representación gráfica de un servicio Web y por otro, facilitará la generación automática de código WSDL a partir de un diagrama UML.

  20. Validación de un cuestionario para investigar concepciones de profesores sobre ciencia y modelado científico en el contexto de la física

    Directory of Open Access Journals (Sweden)

    Fernando Lang da Silveira

    2011-07-01

    Full Text Available Aunque los términos ‘naturaleza de la ciencia’ y ‘modelo científico’ sean polisémicos en la Enseñanza de Ciencias, hay una especie de consenso en el área en cuanto a la importancia de la epistemología y del modelado científico en la formación de estudiantes y profesores. Por eso, diversos investigadores han dedicado esfuerzos a la enseñanza y a la investigación de esos temas. Parte de esos investigadores, así como nosotros, creen que la estrategia del modelado científico aplicada a la Enseñanza de Ciencias, además de ser una herramienta útil para la resolución de problemas, puede favorecer la construcción de una visión de ciencia adecuada a la práctica científica contemporánea. Pero una de las preguntas de investigación que sigue pendiente se refiere a los instrumentos de evaluación de las concepciones de estudiantes y profesores sobre esos temas. Dentro de ese contexto, este estudio tuvo el objetivo de validar un cuestionario para investigar en qué medida las concepciones de profesores sobre ciencia se correlacionan con las de modelado científico en el contexto de la Física. Compuesto inicialmente por 48 afirmaciones, el cuestionario fue aplicado a 218 personas. El análisis de las respuestas llevó a: a la identificación de cuatro factores subyacentes al contenido de las afirmaciones; b una fuerte correlación entre las concepciones sobre ciencia en general y modelado científico en Física; y c la construcción de dos formas alternativas y equivalentes del cuestionario, cada una con 23 afirmaciones, que pueden ser útiles cuando se pretende reducir posibles efectos de test en delineamientos experimentales. Enfatizamos que un instrumento de ese tipo puede ser útil como herramienta auxiliar para la evaluación de estrategias didácticas fundamentadas en elementos teórico - metodológicos pertinentes al proceso de modelado científico que pretendan integrar contenidos de naturaleza epistemológica en la

  1. Modelado y generación del Prototipo Virtual de una máquina calibradora para la inspección de fruta en postcosecha. Simulación de funcionamiento de sus partes móviles

    OpenAIRE

    TORMO SOLER, EDUARDO

    2015-01-01

    [ES] Las tareas a realizar serían, usando la aplicación de modelado Inventor/Solidworks: ¿Elaboración de los modelos 3D de todas las partes básicas de la máquina de inspección. ¿Generación del prototipo virtual de la máquina. ¿Generación de los planos. ¿Simulación de las partes móviles. Tormo Soler, E. (2015). Modelado y generación del Prototipo Virtual de una máquina calibradora para la inspección de fruta en postcosecha. Simulación de funcionamiento de sus partes móviles....

  2. Método para el Modelado y Prueba de Diagramas de Actividades Mediante Redes de Petri

    Directory of Open Access Journals (Sweden)

    Lionel Baquero Hernández

    2015-11-01

    Full Text Available Las redes de Petri son ideales para describir y estudiar sistemas que procesan información y con características concurrentes, asíncronas, distribuidas, paralelas, no determinísticas y/o estocásticas. . Sin embargo, la teoría clásica de estas redes se enfrenta al desafío de adecuarse a las nuevas necesidades de los sistemas informáticos que los ingenieros diseñan en la actualidad. Un diagrama de actividades representa una secuencia de actividades. Podría aplicarse a cualquier propósito, pero se considera especialmente útil para visualizar los flujos de trabajo y los procesos del negocio, o casos de uso. El presente trabajo se ha desarrollado con el objetivo de diseñar un método para el modelado y prueba de diagramas de actividades mediante redes de Petri. El método propuesto brinda una serie de pasos necesarios para modelar un diagrama de actividades con redes de Petri y a partir de dicha red obtener una representación matemática de la misma. Esta representación matemática se utiliza para con ella realizar una serie de operaciones basadas en el marcaje de la red que permiten realizar pruebas al diagrama. Este método es capaz de identificar errores comunes que se cometen en el modelado de los diagramas de actividades, lo cual se demostró a través del método de experimentación.

  3. Molecular dynamics simulations of radiation damage in D019 Ti3Al intermetallic compound

    International Nuclear Information System (INIS)

    Voskoboinikov, Roman E.

    2013-01-01

    Molecular dynamics (MD) has been applied to simulate the radiation damage created in displacement cascades in D0 19 Ti 3 Al structural intermetallics. Collision cascades formed by the recoil of either Al or Ti primary knock-on atoms (PKA) with energy E PKA = 5, 10, 15 or 20 keV were considered in Ti 3 Al single crystals at T = 100, 300, 600 and 900 K. At least 24 different cascades for each (E PKA , T, PKA type) set were simulated. A comprehensive treatment of the modelling results has been carried out. We have evaluated the number of Frenkel pairs, fraction of Al and Ti vacancies, self-interstitial atoms and anti-sites as a function of (E PKA ,T, PKA type). Preferred formation of both Al vacancies and self-interstitial atoms in D0 19 Ti 3 Al exposed to irradiation has been detected

  4. Análisis comparativo de descriptores de forma 3D para detección de características faciales / Comparative analysis of 3D shape descriptors for facial feature detection

    OpenAIRE

    Cerón Correa, Alexander

    2011-01-01

    El rostro humano presenta una gran cantidad de características que actualmente pueden ser modeladas mediante un simple patrón 2D, un conjunto complejo de vértices 3D que forman una malla poligonal o un conjunto de par�ametros para cada grado de libertad o variación. La caracterización del rostro tiene gran cantidad de aplicaciones dentro de las cuales se tienen: identificación de rostros, modelado de la cara, síntesis de voz, identificación de expresiones y cirugía facial. Los modelos t...

  5. Crystal structure and stability of LiAlD{sub 4} with TiF{sub 3} additive

    Energy Technology Data Exchange (ETDEWEB)

    Brinks, H.W. [Department of Physics, Institute for Energy Technology, P.O. Box 40, Kjeller NO-2027 (Norway)]. E-mail: hwbrinks@ife.no; Fossdal, A. [Department of Physics, Institute for Energy Technology, P.O. Box 40, Kjeller NO-2027 (Norway); Fonnelop, J.E. [Department of Physics, Institute for Energy Technology, P.O. Box 40, Kjeller NO-2027 (Norway); Hauback, B.C. [Department of Physics, Institute for Energy Technology, P.O. Box 40, Kjeller NO-2027 (Norway)

    2005-07-19

    LiAlD{sub 4} samples with TiF{sub 3} additives have been investigated by synchrotron X-ray diffraction, neutron diffraction and a Sieverts-type apparatus. Directly after ball milling there are no signs of any Ti-containing phases, and the unit-cell of LiAlD{sub 4} and Al give no indication of any solid solutions. Hence it is concluded that the Ti is in an amorphous state directly after ball milling. Furthermore, no LiF was observed in the samples. Based on Sieverts-type measurements the plateau pressure at 80 deg C has been proved to be higher than 85 bar. Samples stored in a glove box are slowly desorbed, and after 6 months for a LiAlD{sub 4} + TiF{sub 3} sample, the reaction to LiD + Al is nearly finished.

  6. ESTUDIO Y MODELADO DE UN BRAZO ROBÓTICO LEGO DE TRES GRADOS DE LIBERTAD

    Directory of Open Access Journals (Sweden)

    JAIME ALBERTO GUZMÁN

    2011-12-01

    Full Text Available En este artículo se presenta el estudio y modelado de un brazo robótico lego de tres grados de libertad en asocio con sus respectivos modelos de su cinemática directa e inversa junto con una aproximación al análisis dinámico para la generación de trayectorias de este robot. Las ecuaciones que rigen el movimiento son deducidas de los modelos matemáticos propios a las cadenas cinemáticas y son implementadas en el lenguaje de programación Java y ejecutadas por el robot a través de la extensión Java -LeJOS.

  7. MODELADO CONCEPTUAL DE LA SUPERVISIÓN DE UN SISTEMA HOLÓNICO DE PRODUCCIÓN CONTINUA

    Directory of Open Access Journals (Sweden)

    CARLOS PARRA ORTEGA

    2012-06-01

    Full Text Available La arquitectura de automatización PROSA es una descripción orientada hacia objetos que implementan sistemas de producción. Un enfoque basadoen sistemas para eventos discretos, detección de eventos y la teoría de control supervisorio, representa el comportamiento de una unidad de producción controlada. Para obtener la descripción orientada a objetosde esta unidad, se aplicó modelado conceptual y se utilizó el Lenguaje unificado de modelado.

  8. Hibridación de técnicas de ingeniería inversa para el modelado preciso de estructuras, edificios y ciudades

    OpenAIRE

    Cosido Cobos, Óscar Jesús

    2017-01-01

    Uno de los temas más candentes de investigación en gráficos por computador de los últimos años es el uso de técnicas de realidad virtual y aumentada para el archivado, preservación y divulgación del patrimonio histórico y cultural. En este contexto, se plantea esta tesis relacionada con Sistemas de Gestión de la Información, GIS y Modelado 3D, Sistemas Estructurales y Patrimonio Industrial. Para poder simular y virtualizar la evolución histórica de una ciudad es necesario representar en prime...

  9. 2D and 3D milled surface roughness of high volume fraction SiCp/Al composites

    Directory of Open Access Journals (Sweden)

    Tao Wang

    2015-06-01

    Full Text Available This paper presents a study on surface roughness generated by high speed milling of high volume fraction (65% silicon carbide particle-reinforced aluminum matrix (SiCp/Al composites. Typical 2D (Ra and Rz and 3D (Sa and Sq surface roughness parameters were selected to evaluate the influence of the milling parameters on the surface quality in comparison with aluminum alloy. The 3D topography of the milled surface was studied as well. The results indicate that 3D parameters (Sa and Sq are more capable to describe the influence of the milling parameters on the surface quality, and among them Sq is preferable due to its good sensitivity. Sq decreases with milling speed and increases with feed rate. The influence of axial depth of cut (ADOC is negligible.

  10. Ácido mandélico: Modelado de su estructura y espectro de rotación

    OpenAIRE

    Lirio Martínez, Ángel

    2016-01-01

    En este trabajo, se ha realizado el modelado teórico del panorama conformacional de la molécula del ácido mandélico, mediante el uso de diversos tipos de métodos computacionales. Una vez obtenidos los confórmeros más estables, todos con energías menores a 1000 cm-1, se llevado a cabo un análisis de las interacciones intramoleculares que se dan. A partir de los datos obtenidos se ha realizado el modelado del espectro de rotación de cada confórmero, en el rango del espectro de 1...

  11. Modelado y Simulación del Proceso de Producción del Azúcar

    Directory of Open Access Journals (Sweden)

    A. Merino

    2009-07-01

    Full Text Available Resumen: En este artículo se muestra una metodología para el desarrollo de librerías de modelos matemáticos dinámicos para la industria azucarera. Las especificaciones y requisitos de esta librería hacen necesaria la utilización del paradigma de modelado Modelado Orientado a Objetos Basado en Ecuaciones. Utilizando una herramienta que utiliza este paradigma se han desarrollado una serie de librerías de modelos, que contienen los elementos necesarios para la construcción del modelo conjunto de una fábrica azucarera completa. En este artículo se muestran los detalles constructivos más interesantes de algunas de éstas librerías, así como algunos de los problemas que se han abordado durante su desarrollo. Mediante la aplicación de los mecanismos de agregación que posee la herramienta de modelado utilizada, es posible la construcción del modelo de fábricas azucareras completas en base a la conexión de las distintas unidades de proceso que la componen. Las principales aportaciones de la librería desarrollada, respecto a otras herramientas y librerías existentes en la actualidad en el mercado, son el hecho de utilizar modelos dinámicos detallados de proceso y el que estos modelos incluyan anomalías y malfunciones. Esto ofrece una gran versatilidad en la utilización de la librería en aplicaciones como el diseño de controladores, los simuladores de entrenamiento o la utilización de los modelos como fuente de datos en herramientas de optimización en línea de procesos. Palabras clave: Modelado de Procesos Continuos, Simulación de procesos, Industria Azucarera

  12. Evaluación de alternativas de modelado y visualización para la construcción

    OpenAIRE

    Isaza Pulido, Jorge Alonso

    2015-01-01

    Durante décadas las prácticas de CAD [computer-aided design: diseño asistido por compu-tador] han estado presentes en los proyectos de AEC/FM [architecture, engineering, construction and facilities management: arquitectura, ingeniería, construcción y administración de inmuebles]; sin embargo, los últimos años las prácticas de BIM [building information modeling: modelado de información en construcción] están seduciendo a los profesionales en Colombia y en el mundo, por sus grandes ventajas, co...

  13. Field ion microscopy and 3-D atom probe analysis of Al3Zr particles in 7050 Al alloy

    International Nuclear Information System (INIS)

    Sha, G.; Cerezo, A.

    2004-01-01

    Full text: For high strength 7xxx series Al alloys, Zr is an important trace alloy element which is often added to optimise properties, having effects such as refining grain size, inhibiting recrystallization, and improving stress corrosion cracking resistance and quench sensitivity. In addition, it has been reported recently that Zr addition also has a significant influence on early stage ageing behaviour of a 7xxx series Al alloy. Zr equilibrium solubility in solid Al is extremely low. After solution or ageing treatment, most Zr is present as small spherical Ai 3 Zr dispersoids approximately 20 nm in diameter, distributed at grain boundaries as well as within the Al matrix. The crystallographic nature of intermetallic phase Al 3 Zr has been well studied in the literatures. So far, no direct measurement of the chemistry of the Al 3 Zr particles in 7xxx series Al alloys has been published. It is unclear if there is significant Zn, Mg or Cu included in the particles. In this research, 3DAP has been employed for the first time to investigate ionisation behaviour of Al 3 Zr particles and determine the chemistry of the particles in 7050 Al alloy. Using field ion microscopy, the local evaporation radius of the Al 3 Zr particle has been measured to be equivalent to 36 nm for a 10 kV tip, less than the equivalent tip radius for the Al matrix of ∼68 nm. Using the matrix Al evaporation field (19 V/nm) as a reference, this allows the evaporation field of Al 3 Zr to be calculated as 35 V/nm, the same as the field calculated for evaporation of Al as Al 2+ (35 V/nm), and that of Zr as Zr 3+ (35 V/nm). This result is consistent with Al 2+ and Zr 3+ being the main species observed in the mass spectrum during analysis of Al 3 Zr particles. Using 3DAP, the chemical compositions of Al 3 Zr particles are determined to be 64.8∼67.7 at% Al, 23.6∼24.8 at% Zr, 6.9∼9.1 at% Zn, 0.4∼0.7 at% Cu, 0.5∼1.2 at% Mg, with a (Al+Zn)/Zr ratio close to 3. Choice of specimen temperature of

  14. Coherent 3D nanostructure of γ-Al{sub 2}O{sub 3}: Simulation of whole X-ray powder diffraction pattern

    Energy Technology Data Exchange (ETDEWEB)

    Pakharukova, V.P., E-mail: verapakh@catalysis.ru [Boreskov Institute of Catalysis SB RAS, Pr. Lavrentieva 5, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogova Street 2, 630090 Novosibirsk (Russian Federation); Research and Educational Center for Energy Efficient Catalysis, Novosibirsk State University, Novosibirsk 630090 (Russian Federation); Yatsenko, D.A. [Boreskov Institute of Catalysis SB RAS, Pr. Lavrentieva 5, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogova Street 2, 630090 Novosibirsk (Russian Federation); Gerasimov, E. Yu.; Shalygin, A.S.; Martyanov, O.N.; Tsybulya, S.V. [Boreskov Institute of Catalysis SB RAS, Pr. Lavrentieva 5, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogova Street 2, 630090 Novosibirsk (Russian Federation); Research and Educational Center for Energy Efficient Catalysis, Novosibirsk State University, Novosibirsk 630090 (Russian Federation)

    2017-02-15

    The structure and nanostructure features of nanocrystalline γ-Al{sub 2}O{sub 3} obtained by dehydration of boehmite with anisotropic platelet-shaped particles were investigated. The original models of 3D coherent nanostructure of γ-Al{sub 2}O{sub 3} were constructed. The models of nanostructured γ-Al{sub 2}O{sub 3} particles were first confirmed by a direct simulation of powder X–Ray diffraction (XRD) patterns using the Debye Scattering Equation (DSE) with assistance of high-resolution transmission electron microscopy (HRTEM) study. The average crystal structure of γ-Al{sub 2}O{sub 3} was shown to be tetragonally distorted. The experimental results revealed that thin γ-Al{sub 2}O{sub 3} platelets were heterogeneous on a nanometer scale and nanometer-sized building blocks were separated by partially coherent interfaces. The XRD simulation results showed that a specific packing of the primary crystalline blocks in the nanostructured γ-Al{sub 2}O{sub 3} particles with formation of planar defects on (001), (100), and (101) planes nicely accounted for pronounced diffuse scattering, anisotropic peak broadening and peak shifts in the experimental XRD pattern. The identified planar defects in cation sublattice seem to be described as filling cation non-spinel sites in existing crystallographic models of γ-Al{sub 2}O{sub 3} structure. The overall findings provided an insight into the complex nanostructure, which is intrinsic to the metastable γ-Al{sub 2}O{sub 3} oxide. - Highlights: • Thin plate-like crystallites of γ-Al{sub 2}O{sub 3} were obtained. • Models of 3D coherent nanostructure of γ-Al{sub 2}O{sub 3} were constructed. • Models were verified by simulating XRD patterns using the Debye Scattering Equation. • Specific broadening of XRD peaks was explained in terms of planar defects. • Primary crystalline blocks in γ-Al{sub 2}O{sub 3} are separated by partially coherent interfaces.

  15. MODELADO CON REDES DE PETRI E IMPLEMENTACIÓN CON GRAFCET DE UN SISTEMA DE MANUFACTURA FLEXIBLE CON PROCESOS CONCURRENTES Y RECURSOS COMPARTIDOS

    Directory of Open Access Journals (Sweden)

    Johanna Stella Castellanos Arias

    2010-01-01

    Full Text Available En este trabajo, se presenta el modelado de un Sistema de Manufactura Flexible (SMF, con procesos concurrentes y recursos compartidos mediante Sistemas a Eventos Discretos (SED, específicamente Redes de Petri (RdP, y GRAFCET. El SMF se plantea como un modelo hipotético que se modela con una RdP con el objeto de identificar su dinámica y hallar la secuencia óptima de funcionamiento del sistema. Se desarrolló un modelo matemático que permite estimar el vector de tiempo acumulado de un proceso modelado mediante una RdP, el cual constituye la base para hallar la mejor secuencia posible del sistema modelado. Por último, se realizó una implementación en el Laboratorio de Automatización de la Universidad Militar Nueva Granada, que simula el funcionamiento del SMF modelado por un montaje electrohidroneumático controlado con GRAFCET mediante PLC.

  16. A novel method to fabricate TiAl intermetallic alloy 3D parts using additive manufacturing

    Directory of Open Access Journals (Sweden)

    J.J.S. Dilip

    2017-04-01

    Full Text Available The present work explores the feasibility of fabricating porous 3D parts in TiAl intermetallic alloy directly from Ti–6Al–4V and Al powders. This approach uses a binder jetting additive manufacturing process followed by reactive sintering. The results demonstrate that the present approach is successful for realizing parts in TiAl intermetallic alloy.

  17. Role of manganese on the grain refining efficiency of AZ91D magnesium alloy refined by Al4C3

    International Nuclear Information System (INIS)

    Liu Shengfa; Zhang Yuan; Han Hui

    2010-01-01

    A novel Mg-50% Al 4 C 3 (hereafter in wt.%) master alloy has been developed by powder in situ synthesis process, the role of manganese on the grain refining efficiency of AZ91D magnesium alloy refined by this master alloy has been investigated. X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDS) results show the existence of Al 4 C 3 particles in this master alloy. After addition of 0.6% Al 4 C 3 or combined addition of 0.6% Al 4 C 3 and 0.27% Mn, the average grain size of AZ91D decreased dramatically from 360 μm to 210 μm, and from 360 μm to130 μm, respectively. However, no further refinement of grain size was achieved with additional amount of Mn exceeding 0.27% for AZ91D alloy refined by 0.6% Al 4 C 3 in the present investigation. Al-C-O-Mn-Fe-rich intermetallic particles with an Al-C-O-rich coating film, often observed in the central region of magnesium grains of the AZ91D alloy treated by the combination of Al 4 C 3 and Mn, are proposed to be the potent nucleating substrates for primary α-Mg.

  18. Electronic structure of Ni/sub 3/Al and Ni/sub 3/Ga alloys

    CERN Document Server

    Pong, W F; Chang, Y K; Tsai, M H; Hsieh, H H; Pieh, J Y; Tseng, P K; Lee, J F; Hsu, L S

    1999-01-01

    This work investigates the charge transfer and Al(Ga) p-Ni d hybridization effects in the intermetallic Ni/sub 3/Al(Ni/sub 3/Ga) alloy using the NiL/sub 3.2/- and K-edge and Al(Ga)K X-ray absorption near edge structure (XANES) measurements. We find that the intensity of white-line features at the NiL/sub 3.2/-edge in the Ni/sub 3/Al(Ni /sub 3/Ga) alloy decreased in comparison with that of pure Ni, which can be attributed to the enhancement of Ni3d states filling and the depletion of the density of Ni 3d unoccupied states in the Ni/sub 3 /Al(Ni/sub 3/Ga) alloy. Two clear features are also observed in the Ni/sub 3/Al(Ni/sub 3/Ga) XANES spectrum at the Al(Ga) K-edge, which can be assigned to the Al(Ga) unoccupied 3p (4p) states and their hybridized states with the Ni 3d/4sp states above the Fermi level in Ni/sub 3/Al(Ni/sub 3/Ga). The threshold at Al K-edge XANES for Ni/sub 3/Al clearly shifts towards higher photon energies relative to that of pure Al, indicating that Al loses charges upon forming Ni/sub 3 /Al. ...

  19. Luminescence of Eu:Y3Al5O12, Eu:Lu3Al5O12, and Eu:GdAlO3 Nanocrystals Synthesized by Solution Combustion

    Science.gov (United States)

    Vilejshikova, E. V.; Khort, A. A.; Podbolotov, K. B.; Loiko, P. A.; Shimanski, V. I.; Shashkov, S. N.; Yumashev, K. V.

    2017-11-01

    Nanocrystals of rare-earth garnets Y3Al5O12 and Lu3Al5O12 and perovskite GdAlO3 highly doped (10-20 at%) with Eu3+ are synthesized by the solution combustion technique and subsequent annealing in air at 800 and 1300oC. Their structure, morphology, and phase composition are studied. These materials exhibit intense red luminescence under UV excitation. Eu:GdAlO3 luminescence has CIE 1931 color coordinates (0.632, 0.368); dominant wavelength, 599.6 nm; and color purity, >99%. Judd-Ofelt parameters, luminescence branching ratios, and lifetimes of the Eu3+ 5D0 state are determined. The luminescence quantum yield for Eu:GdAlO3 (10 at%) reaches 74% with a lifetime of 1.4 ms for the 5D0 state. The synthesized materials are promising for red ceramic phosphors.

  20. Modelado y análisis de sistemas fotovoltaicos

    OpenAIRE

    Guasch Murillo, Daniel

    2003-01-01

    Bajo la etiqueta de "Modelado y análisis de sistemas fotovoltaicos" se presentan los trabajos realizados a lo largo del doctorado. Estos estudios centran su aplicación en el área de los sistemas fotovoltaicos. Tienen por objetivo conseguir un entorno de trabajo que permita analizar la problemática asociada a instalaciones fotovoltaicas desde su diseño hasta su puesta en marcha y posterior explotación. Se ha escogido Matlab/Simulink como núcleo del entorno de trabajo debido a la gran potencia ...

  1. Modelado, Simulación y Control de Satélites en los Puntos de Lagrange del Sistema Tierra - Luna

    Directory of Open Access Journals (Sweden)

    F. Alonso Zotes

    2011-07-01

    Full Text Available Resumen: El objetivo de este artículo es modelar, analizar y controlar una constelación de cinco satélites, situados en los puntos de Lagrange del sistema Tierra – Luna. El modelo se ha desarrollado incluyendo efectos complejos no considerados habitualmente, como el viento solar, la no esfericidad de los planetas y la deriva de la órbita lunar, para hacerlo más realista. Sobre los satélites se ejerce una propulsión continua, calculada por medio de controladores tipo PD, tanto convencionales como borrosos, y cuya finalidad es situar y mantener a cada satélite en su punto de Lagrange frente a las inestabilidades y derivas inherentes al sistema. El sistema completo se ha implementado en el lenguaje de modelado Modelica, para el que se han creado una serie de elementos aeroespaciales, y las simulaciones se han desarrollado con el software Dymola. Tanto con los controladores clásicos como con los borrosos se han obtenido muy buenos resultados. Palabras clave: modelado, simulación, control borroso, satélites, puntos de Lagrange, sistema Tierra-Luna

  2. 29Si(d,3He)28Al reaction at 29 MeV

    International Nuclear Information System (INIS)

    Vernotte, J.; Berrier-Ronsin, G.; Fortier, S.; Hourani, E.; Kalifa, J.; Khendriche, A.; Maison, J.M.; Rosier, L.H.; Rotbard, G.

    1994-01-01

    The 29 Si(d, 3 He) 28 Al reaction has been investigated at 29 MeV incident energy. Observations using a split-pole magnetic spectrograph have been made of 55 levels of 28 Al in the range of excitation energy between 0 and 6.7 MeV. Most of them have been identified with 28 Al levels which have been previously observed by other techniques. The spectroscopic factors have been obtained for 23 of these levels through distorted-wave Born approximation analyses of measured angular distributions. The levels at E x =3.105 and 3.762 MeV have been definitely assigned J π =1 + and 0 + , respectively. Four levels which are populated through the pickup of a l p =1 proton have been observed at E x =4.998, 5.406, 6.021, and 6.652 MeV. The excitation energies and spectroscopic factors for positive-parity states were compared with the results of a recent, complete sd-shell space, shell-model calculation. This comparison led to the identification of 21 shell-model levels with experimental levels. This comparison seems accurate enough to make very likely the J π =3 + assignment for the levels at E x =2.988 and 4.597 MeV which were previously assigned J π =(1,3) +

  3. Metodologías ágiles enfocadas al modelado de requerimientos

    Directory of Open Access Journals (Sweden)

    Silvia Gabriela Rivadeneira Molina

    2014-06-01

    Full Text Available El dinamismo y la variabilidad de la industria del software hace necesario replantear las bases y prácticas que sustentan el desarrollo de software convencional. Un reciente estudio realizado por (Boehm, 2006, sobre tendencias en ingeniería del software, muestra que el mercado actual está caracterizado por el desarrollo rápido de aplicaciones y la reducción de la vida de los productos. En este contexto variable e inestable se requiere como ventaja competitiva aumentar la productividad y satisfacer las necesidades cambiantes de los clientes en el menor tiempo posible para proporcionar un mayor valor al negocio. Ante este panorama, cabe reflexionar sobre el grado de adaptación de las metodologías convencionales a estas circunstancias. La mayoría de los estudios coinciden en que el carácter normativo y la fuerte dependencia de planificaciones previas al desarrollo que definen a las metodologías convencionales, implican que resulten excesivamente pesadas para cubrir las necesidades de un amplio porcentaje del mercado software actual. Las metodologías ágiles surgidas a fines de los ’90, no han sidomuy tenidas en cuenta por el mundo académico, quizás recién a mediados de la década anterior se comienzan a encontrar trabajos de investigación al respecto. En este trabajo se analizan las metodologías ágiles más utilizadas enfocándose en las primeras etapas del ciclo de vida del software ydeteniéndose en las prácticas, técnicas y productos que se utilizan en las mencionadas etapas. Para ello se indagó en la literatura existente para conocer cada una de las metodologías involucradas, logrando una primera selección y comparación de las mismas, y exponiendo los resultados y sus conclusiones en este informe.

  4. Core electron binding energy shifts of AlBr3 and Al2Br6 vapor

    International Nuclear Information System (INIS)

    Mueller, Astrid M.; Plenge, Juergen; Leone, Stephen R.; Canton, Sophie E.; Rude, Bruce S.; Bozek, John D.

    2006-01-01

    The Al 2p and Br 3d inner-shell photoelectron spectra of aluminum tribromide monomer and dimer vapor were measured at 90 and 95 eV photon energy, respectively, to determine the core electron binding energies of the atoms in the two molecular species. While AlBr 3 has three identical Br atoms, Al 2 Br 6 exhibits four terminal and two bridging Br atoms. The species are identified by their distinct valence photoelectron spectra. Comparison of the observed Al 2p 1/2 and Al 2p 3/2 electron binding energies of AlBr 3 with those of Al 2 Br 6 shows that there is a chemical shift of (0.15 ± 0.03) eV to lower energy in the dimer. In Al 2 Br 6 , an assignment is proposed in which the Br 3d 3/2 and Br 3d 5/2 binding energies of terminal Br atoms are (1.18 ± 0.03) eV lower than those of bridging Br atoms. This assignment assumes that both types of Br atoms have similar cross-sections for ionization. With this result, the Br 3d 3/2 and Br 3d 5/2 binding energies of Br atoms in AlBr 3 are (0.81 ± 0.03) eV lower than those of bridging Br atoms of the dimer but (0.37 ± 0.03) eV higher than those of terminal Br atoms of the dimer. The obtained chemical shifts are considered in terms of the binding relations and electron density distributions in both molecules. Chemical shifts that are larger than a few hundred millielectron volts, as observed in the Al 2 Br 6 /AlBr 3 system, offer potential to study the dissociation dynamics of the dimer in a femtosecond visible or ultraviolet-pump/XUV-probe experiment

  5. Una formalización del modelado multi-nivel

    OpenAIRE

    Álvarez Picallo, Mario

    2014-01-01

    Los sistemas formales de modelado, como el Unified Modeling Language (UML), son bien cono-cidos por todos los ingenieros de software. Los mismos permiten razonar sobre la estructura a gran escala de los sistemas de la información, facilitando el análisis, diseño e implementación de los mismos, así como su mantenimiento posterior, y simplificando tareas como la refactorización automática o la generación de códi-go. Por otro lado, a pesar del éxito que han tenido estas herramientas, no están...

  6. RECONSTRUCTION OF 3D VECTOR MODELS OF BUILDINGS BY COMBINATION OF ALS, TLS AND VLS DATA

    Directory of Open Access Journals (Sweden)

    H. Boulaassal

    2012-09-01

    Full Text Available Airborne Laser Scanning (ALS, Terrestrial Laser Scanning (TLS and Vehicle based Laser Scanning (VLS are widely used as data acquisition methods for 3D building modelling. ALS data is often used to generate, among others, roof models. TLS data has proven its effectiveness in the geometric reconstruction of building façades. Although the operating algorithms used in the processing chain of these two kinds of data are quite similar, their combination should be more investigated. This study explores the possibility of combining ALS and TLS data for simultaneously producing 3D building models from bird point of view and pedestrian point of view. The geometric accuracy of roofs and façades models is different due to the acquisition techniques. In order to take these differences into account, the surfaces composing roofs and façades are extracted with the same algorithm of segmentation. Nevertheless the segmentation algorithm must be adapted to the properties of the different point clouds. It is based on the RANSAC algorithm, but has been applied in a sequential way in order to extract all potential planar clusters from airborne and terrestrial datasets. Surfaces are fitted to planar clusters, allowing edge detection and reconstruction of vector polygons. Models resulting from TLS data are obviously more accurate than those generated from ALS data. Therefore, the geometry of the roofs is corrected and adapted according to the geometry of the corresponding façades. Finally, the effects of the differences between raw ALS and TLS data on the results of the modeling process are analyzed. It is shown that such combination could be used to produce reliable 3D building models.

  7. The Effects of Al and Ti Additions on the Structural Stability, Mechanical and Electronic Properties of D8m-Structured Ta5Si3

    Directory of Open Access Journals (Sweden)

    Linlin Liu

    2016-05-01

    Full Text Available In the present study, the influence of substitutional elements (Ti and Al on the structural stability, mechanical properties, electronic properties and Debye temperature of Ta5Si3 with a D8m structure were investigated by first principle calculations. The Ta5Si3 alloyed with Ti and Al shows negative values of formation enthalpies, indicating that these compounds are energetically stable. Based on the values of formation enthalpies, Ti exhibits a preferential occupying the Ta4b site and Al has a strong site preference for the Si8h site. From the values of the bulk modulus (B, shear modulus (G and Young’s modulus (E, we determined that both Ti and Al additions decrease both the shear deformation resistance and the elastic stiffness of D8m structured Ta5Si3. Using the shear modulus/bulk modulus ratio (G/B, Poisson’s ratio (υ and Cauchy’s pressure, the effect of Ti and Al additions on the ductility of D8m-structured Ta5Si3 are explored. The results show that Ti and Al additions reduce the hardness, resulting in solid solution softening, but improve the ductility of D8m-structured Ta5Si3. The electronic calculations reveal that Ti and Al additions change hybridization between Ta-Si and Si-Si atoms for the binary D8m-structured Ta5Si3. The new Ta-Al bond is weaker than the Ta-Si covalent bonds, reducing the covalent property of bonding in D8m-structured Ta5Si3, while the new strong Ti4b-Ti4b anti-bonding enhances the metallic behavior of the binary D8m-structured Ta5Si3. The change in the nature of bonding can well explain the improved ductility of D8m-structured Ta5Si3 doped by Ti and Al. Moreover, the Debye temperatures, ΘD, of D8m-structured Ta5Si3 alloying with Ti and Al are decreased as compared to the binary Ta5Si3.

  8. Implementación de un mantenimiento basado en la condición usando modelado y simulación: caso de estudio de un motor sin-crónico de imanes permanentes

    Directory of Open Access Journals (Sweden)

    Jabid Quiroga Méndez

    2011-05-01

    Full Text Available Este artículo introduce la arquitectura de un CBM (mantenimiento basado en la condición en una aplicación eléctrica. La detección de fallas de manera oportuna y eficiente constituye uno de los retos más importantes asociados al CBM y el enfoque basado en modelos en el medio para conseguirlo. Un caso de estudio en un motor sincrónico de imanes permanentes (PMSM es ejecutado para ilustrar cómo el modelado es utilizado en la implementación de un CBM. El monitoreo fue implementado en tiempo real usando Matlab® y dSpace®. Se emplea como indicadora de falla la diferencia entre los valores de la componente secuencial negativa para las corrientes predichas usando una red neuronal multicapa y la corriente obtenida del motor. Resultados experimentales demostraron la efectividad del modelo propuesto en la detección de la falla de cortocircuito en el estator en distintos niveles de severidad y carga, obteniendo una confiabilidad en la detección mayor al 95%.

  9. A computational study of magnetic exchange interactions of 3d and 4f electrons in Ti-Ce co-doped AlN

    Energy Technology Data Exchange (ETDEWEB)

    Majid, Abdul, E-mail: abdulmajid40@yahoo.com [Department of Physics, University of Gujrat, Gujrat (Pakistan); Department of Adaptive Machine Systems, Osaka University, Osaka (Japan); Azmat, Mian [Department of Physics, University of Gujrat, Gujrat (Pakistan); Rana, Usman Ali; Khan, Salah Ud-Din [Sustainable Energy Technologies Center, College of Engineering, King Saud University, PO-Box 800, Riyadh 11421 (Saudi Arabia); Alzahrani, Eman [Department of Chemistry, Faculty of Science, Taif University, 888 Taif (Saudi Arabia)

    2016-08-15

    To investigate the nature of 3d-4f exchange interactions in III-Nitride semiconductors, Ti-Ce co-doped AlN were studied using first principles calculations. The calculations were performed using supercell approach with varying dopant concentration and different inter-dopant separation. The configuration with dopant located as nearest neighbor distance and diluted concentration of 3.125% was found most stable. The results exhibited prominent evidence of 3d-4f-5d strong hybridization suggesting 3d-4f direct exchange interactions which may play valuable role to exploit the system as high Curie temperature ferromagnetic semiconductors for use in spintronics. Moreover, metal to metal charge transfer was also observed in the materials which may be exploited for their use in electrochemical applications. The 4f-5d and 3d-5d hybridizations were observed that predicts excellent luminescence phenomena in the materials. The presence of impurity related deep intermediate bands suggest applications of the materials in opto-electronic and spintronics devices. - Highlights: • Double exchange interaction in Ti:AlN. • Impurity induced narrowing of band gap. • Superexchange interaction in Ce:AlN. • 3d-4f exchange interaction between Ti-3d and Ce-4f states. • High Curie temperature n-type ferromagnetic semiconductors.

  10. A computational study of magnetic exchange interactions of 3d and 4f electrons in Ti-Ce co-doped AlN

    International Nuclear Information System (INIS)

    Majid, Abdul; Azmat, Mian; Rana, Usman Ali; Khan, Salah Ud-Din; Alzahrani, Eman

    2016-01-01

    To investigate the nature of 3d-4f exchange interactions in III-Nitride semiconductors, Ti-Ce co-doped AlN were studied using first principles calculations. The calculations were performed using supercell approach with varying dopant concentration and different inter-dopant separation. The configuration with dopant located as nearest neighbor distance and diluted concentration of 3.125% was found most stable. The results exhibited prominent evidence of 3d-4f-5d strong hybridization suggesting 3d-4f direct exchange interactions which may play valuable role to exploit the system as high Curie temperature ferromagnetic semiconductors for use in spintronics. Moreover, metal to metal charge transfer was also observed in the materials which may be exploited for their use in electrochemical applications. The 4f-5d and 3d-5d hybridizations were observed that predicts excellent luminescence phenomena in the materials. The presence of impurity related deep intermediate bands suggest applications of the materials in opto-electronic and spintronics devices. - Highlights: • Double exchange interaction in Ti:AlN. • Impurity induced narrowing of band gap. • Superexchange interaction in Ce:AlN. • 3d-4f exchange interaction between Ti-3d and Ce-4f states. • High Curie temperature n-type ferromagnetic semiconductors.

  11. Modelado específico de procedimientos en el dominio de la Administración Electrónica

    Directory of Open Access Journals (Sweden)

    Aquilino Adolfo Juan Fuente

    2012-06-01

    Full Text Available Debido a la complejidad que reviste el dominio de la Administración Electrónica (AE, las desarrolladas deberán ser capaces de integrarse con la multitud de plataformas y sistemas que componen dicho dominio. El impacto de esta integración además mejorar la tramitación de procedimientos. En el presente trabajo se propone un lenguaje de modelado gráfico (DSL para la tramitación de procedimientos en el dominio específico de la AE. Este lenguaje parte de la definición de un metamodelo de AE que identifica sus principales entidades y define sus relaciones. Además se construyó una herramienta gráfica de modelado la cual fue probada con dos casos de estudio reales.

  12. Modelado y simulación de la cadena de suministro con AnyLogic®

    Directory of Open Access Journals (Sweden)

    Beatriz Andres

    2016-01-01

    Full Text Available En este artículo se presenta una herramienta de software AnyLogic, para el modelado y simulación de la Cadena de Suministro (CS proporcionando ayuda a la toma de decisiones a través de la simulación de escenarios de un mismo modelo de CS. AnyLogic da soporte a las metodologías de simulación más conocidas: sistemas de eventos discretos, dinámica de sistemas y modelado de agentes. Este artículo se centra en el contexto de dinámica de sistemas permitiendo la simulación de dos tipos de CS: colaborativa y no-colaborativa. Finalmente, se presenta un ejemplo ilustrativo en AnyLogic que permite comparar los dos modelos de CS (i no-colaborativa  vs. (ii colaborativa, caracterizada por un modelo de Inventario Administrado por el Proveedor (en inglés Supplier Managed Inventory, SMI, en la que existe colaboración entre el proveedor y el fabricante de la CS.

  13. Proton pickup from /sup 27/Al via the (n,d) reaction at 56. 3 MeV

    Energy Technology Data Exchange (ETDEWEB)

    Brady, F P; Shepard, J R; King, N S.P.; McNaughton, M W; Wang, J C [California Univ., Davis (USA)

    1977-09-26

    Energy spectra of deuterons from the /sup 27/Al(n,d)/sup 26/Mg reaction due to 56.3 MeV neutrons incident have been measured for 10/sup 0/ <= thetasub(c.m.) <= 55 /sup 0/. The angular distributions for the excitations observed at 0.0, 1.81, and 4.33 MeV are quite well described by DWBA calculations and yield spectroscopic factors in agreement with shell model calculations; but with calculations based on the rotational model, the agreement is less satisfactory particularly for the 4.33 MeV level. For the states at 7.86 and 9.16 MeV the fits, assuming p-shell pick-up, are only fair. Comparison with /sup 27/Al(d,/sup 3/He)/sup 26/Mg measurements shows that the deduced spectroscopic factors for the two reactions agree quite well.

  14. High-κ Al{sub 2}O{sub 3} material in low temperature wafer-level bonding for 3D integration application

    Energy Technology Data Exchange (ETDEWEB)

    Fan, J., E-mail: fanji@hust.edu.cn; Tu, L. C. [MOE Key Laboratory of Fundamental Physical Quantities Measurement, School of Physics, Huazhong University of Science and Technology, Wuhan 430074 (China); Tan, C. S. [School of Electrical and Electronics Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)

    2014-03-15

    This work systematically investigated a high-κ Al{sub 2}O{sub 3} material for low temperature wafer-level bonding for potential applications in 3D microsystems. A clean Si wafer with an Al{sub 2}O{sub 3} layer thickness of 50 nm was applied as our experimental approach. Bonding was initiated in a clean room ambient after surface activation, followed by annealing under inert ambient conditions at 300 °C for 3 h. The investigation consisted of three parts: a mechanical support study using the four-point bending method, hermeticity measurements using the helium bomb test, and thermal conductivity analysis for potential heterogeneous bonding. Compared with samples bonded using a conventional oxide bonding material (SiO{sub 2}), a higher interfacial adhesion energy (∼11.93 J/m{sup 2}) and a lower helium leak rate (∼6.84 × 10{sup −10} atm.cm{sup 3}/sec) were detected for samples bonded using Al{sub 2}O{sub 3}. More importantly, due to the excellent thermal conductivity performance of Al{sub 2}O{sub 3}, this technology can be used in heterogeneous direct bonding, which has potential applications for enhancing the performance of Si photonic integrated devices.

  15. Ingeniería guiada por Modelado y Simulación de Eventos Discretos:

    CERN Document Server

    Bonaventura, Matias Alejandro; The ATLAS collaboration

    2015-01-01

    En este trabajo presentamos una metodología iterativa e incre-mental para desarrollo de proyectos de ingeniería guiados por modelado y simu-lación (M&S) formal. Basándonos en el marco formal DEVS (Discrete Event Systems Specification), y sumando prácticas estándar en proyectos de software, se obtienen modelos que dan respuesta a preguntas de diseño y optimización de redes de datos. Presentamos una aplicación práctica de la metodología a un caso de estudio de ingeniería de redes, en el contexto de un experimento científico a gran escala: el experimento ATLAS (Máquina de Dios) en el cual científicos de todo el mundo intentan responder preguntas sobre el origen del universo. Estas redes absorben en tiempo real datos de experimentos físicos, y por su criticidad se someten a diseños exhaustivos y mejoras continuas. Sin embargo, por la es-cala del proyecto, estas redes están disponibles para ensayos solo esporádica-mente. Mostramos como asistimos su diseño mediante técnicas de modelado y si...

  16. Modelado de Amortiguadores guiado por sus Diagramas Característicos

    Directory of Open Access Journals (Sweden)

    Jorge de-J. Lozoya-Santos

    2015-07-01

    Full Text Available Resumen: Una metodología para modelar amortiguadores guiada por sus diagramas característicos es presentada y validada. Los diagramas característicos del amortiguador son construidos a partir de datos experimentales generados por pruebas estándar: fuerza versus desplazamiento y velocidad versus aceleración. Estos son explorados en las frecuencias de interés. Los diagramas son clasificados en siete patrones, los cuales sirven de guía para construir el modelo matemático el cual puede identificarse con algoritmos convencionales. La metodología es validada con cuatro amortiguadores comerciales de diferentes tecnologías, obteniendo resultados con errores de estimación menores al 5%. Abstract: A methodology for modeling guided by its characteristic damping diagrams is proposed. From experimental data generated by standard tests the damper characteristic diagrams are constructed, which considers the force versus displacement, velocity and acceleration for the frequencies of interest. These characteristic diagrams can be classified into seven patterns, which serve as a guide to build the same mathematical model that can be identified with algorithms conventional. The methodology was validated with four different technologies of commercial dampers. The precision of the results presented errors less than 5%. Keywords: semi-active damper passive damper modeling methodology simulation, Palabras clave: amortiguador semi-activo, amortiguador pasivo, modelado, metodología, simulación

  17. Real-Space Bonding Indicator Analysis of the Donor-Acceptor Complexes X3BNY3, X3AlNY3, X3BPY3, and X3AlPY3 (X, Y = H, Me, Cl).

    Science.gov (United States)

    Mebs, Stefan; Beckmann, Jens

    2017-10-12

    Calculations of real-space bonding indicators (RSBI) derived from Atoms-In-Molecules (AIM), Electron Localizability Indicator (ELI-D), Non-Covalent Interactions index (NCI), and Density Overlap Regions Indicator (DORI) toolkits for a set of 36 donor-acceptor complexes X 3 BNY 3 (1, 1a-1h), X 3 AlNY 3 (2, 2a-2h), X 3 BPY 3 (3, 3a-3h), and X 3 AlPY 3 (4, 4a-4h) reveal that the donor-acceptor bonds comprise covalent and ionic interactions in varying extents (X = Y = H for 1-4; X = H, Y = Me for 1a-4a; X = H, Y = Cl for 1b-4b; X = Me, Y = H for 1c-4c; X, Y = Me for 1d-4d; X = Me, Y = Cl for 1e-4e; X = Cl, Y = H for 1f-4f; X = Cl, Y = Me for 1g-4g; X, Y = Cl for 1h-4h). The phosphinoboranes X 3 BPY 3 (3, 3a-3h) in general and Cl 3 BPMe 3 (3f) in particular show the largest covalent contributions and the least ionic contributions. The aminoalanes X 3 AlNY 3 (2, 2a-2h) in general and Me 3 AlNCl 3 (2e) in particular show the least covalent contributions and the largest ionic contributions. The aminoboranes X 3 BNY 3 (1, 1a-1h) and the phosphinoalanes X 3 AlPY 3 (4, 4a-4h) are midway between phosphinoboranes and aminoalanes. The degree of covalency and ionicity correlates with the electronegativity difference BP (ΔEN = 0.15) < AlP (ΔEN = 0.58) < BN (ΔEN = 1.00) < AlN (ΔEN = 1.43) and a previously published energy decomposition analysis (EDA). To illustrate the importance of both contributions in Lewis formula representations, two resonance formulas should be given for all compounds, namely, the canonical form with formal charges denoting covalency and the arrow notation pointing from the donor to the acceptor atom to emphasis ionicity. If the Lewis formula mainly serves to show the atomic connectivity, the most significant should be shown. Thus, it is legitimate to present aminoalanes using arrows; however, for phosphinoboranes the canonical form with formal charges is more appropriate.

  18. c-axis compression twinning in an off-stoichiometric compound Ti3Al with the D019 structure

    International Nuclear Information System (INIS)

    Kishida, K.; Takahama, Y.; Inui, H.

    2005-01-01

    The characteristics of the c-axis compression twin in single crystals of a D0 19 compound Ti 3 Al with off-stoichiometric composition (Ti-36.5at.%Al) have been studied by trace analysis and transmission electron microscopy. Deformation twinning is operative only at high temperatures above 1000deg. C. All observed deformation twins are assigned to be of the type II and the twinning elements are determined as: K 1 :'{2-bar 121-bar 0-bar 3}', K 2 :{202-bar 1-bar }, η 1 : , η 2 :' ', s=0.346

  19. ZnO Nanorods on a LaAlO 3 -SrTiO 3 Interface: Hybrid 1D-2D Diodes with Engineered Electronic Properties

    KAUST Repository

    Bera, Ashok

    2015-12-28

    Integrating nanomaterials with different dimensionalities and properties is a versatile approach toward realizing new functionalities in advanced devices. Here, a novel diode-type heterostructure is reported consisting of 1D semiconducting ZnO nanorods and 2D metallic LaAlO3-SrTiO3 interface. Tunable insulator-to-metal transitions, absent in the individual components, are observed as a result of the competing temperature-dependent conduction mechanisms. Detailed transport analysis reveals direct tunneling at low bias, Fowler-Nordheim tunneling at high forward bias, and Zener breakdown at high reverse bias. Our results highlight the rich electronic properties of such artificial diodes with hybrid dimensionalities, and the design principle may be generalized to other nanomaterials. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. ZnO Nanorods on a LaAlO 3 -SrTiO 3 Interface: Hybrid 1D-2D Diodes with Engineered Electronic Properties

    KAUST Repository

    Bera, Ashok; Lin, Weinan; Yao, Yingbang; Ding, Junfeng; Lourembam, James; Wu, Tao

    2015-01-01

    Integrating nanomaterials with different dimensionalities and properties is a versatile approach toward realizing new functionalities in advanced devices. Here, a novel diode-type heterostructure is reported consisting of 1D semiconducting ZnO nanorods and 2D metallic LaAlO3-SrTiO3 interface. Tunable insulator-to-metal transitions, absent in the individual components, are observed as a result of the competing temperature-dependent conduction mechanisms. Detailed transport analysis reveals direct tunneling at low bias, Fowler-Nordheim tunneling at high forward bias, and Zener breakdown at high reverse bias. Our results highlight the rich electronic properties of such artificial diodes with hybrid dimensionalities, and the design principle may be generalized to other nanomaterials. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Uso de Plataformas para el Desarrollo de Aplicaciones Virtuales en el Modelado de Robot Manipuladores

    Directory of Open Access Journals (Sweden)

    Róger E. Sánchez-Alonso

    2017-07-01

    Full Text Available Resumen: En este trabajo se propone el uso de plataformas para el desarrollo de aplicaciones virtuales como herramientas para el modelado de robots manipuladores. La propuesta se basa en aprovechar el gran potencial que actualmente tienen estas plataformas para solucionar la dinámica de cuerpos rígidos, lo que permite modelar de forma sencilla los aspectos mecánicos del manipulador. Por otro lado, la posibilidad ofrecida por estas plataformas de incorporar código de programación en lenguajes convencionales, permite modelar el comportamiento dinámico de sistemas físicos reales, tales como sensores y actuadores, lo que hace posible la implementación de una etapa virtual de instrumentación y control tal y como se realiza en un robot real. El uso de estas plataformas permite modelar desde cero cualquier robot manipulador. El modelado de un robot paralelo reconfigurable es presentado como caso de estudio. Abstract: This paper describes the use of platforms for the development of virtual applications as tools for modeling of robot manipulators. The proposal is based on take advantage of the potential that these platforms currently have for solving the rigid body dynamics, which easily allows modeling the mechanical aspects of the manipulator. On the other hand, the possibility offered by these platforms of incorporate programming code in conventional languages allows to modeling the dynamic behavior of real physical systems, such as sensors and actuators, which allows implementing the development of the instrumentation and control stage of an industrial robot in the same way as a real one. Using these platforms allows the modeling from the bases of any manipulator robot. The modeling of a reconfigurable parallel robot is presented as a case study. Palabras clave: Modelado, Robots manipuladores, Realidad virtual, Sistemas dinámicos, Keywords: Modeling, Manipulator Robots, Virtual reality, Dynamic systems

  2. Metallurgy, fabrication, and superconducting properties of multifilamentary Nb3Al composites

    International Nuclear Information System (INIS)

    Hafstrom, J.W.

    1976-01-01

    The control of metallurgical structure during fabrication that will improve the superconducting properties of multifilamentary, aluminium-stabilized, Nb 3 Al composites is described. Composites are fabricated by placing niobium rods in an aluminum matrix, and then drawing to wire. Nb 3 Al is formed at temperatures exceeding 1800 0 C for about 5 s and ordered at 750 0 C for 48 h. A critical current, J/sub c/(H), in excess of 10 5 A/cm 2 (F/sub p/ approximately equal to 7 x 10 8 dynes/cm 3 ) at 7 T and a T/sub c/ to 18.2 K are obtained. Attempts to improve J/sub c/(H) by controlling the grain size in the Nb 3 Al diffused layer are discussed. Precipitates, arising from the addition of carbon during Nb 3 Al layer growth, do not appear to be effective as grain-boundary or flux pinners. When 1 percent Zr is added to the Nb, the growth of the Nb 3 Al layer is accelerated, T/sub c/ is lowered and J/sub c/(H) is not significantly improved. J/sub c/(H) rapidly decreases with an increase in Nb 3 Al or (Nb-Zr) 3 Al layer thickness, d. J/sub c/(H) is independent of d in composites with d greater than or approximately equal to 1.5 μm. In general, the Nb 3 Al grain size appears comparable to d for d less than or equal to 1 μm. Significant improvement of J/sub c/(H) for Nb 3 Al superconducting composites reacted at temperatures above 1800 0 C (to achieve T/sub c/ greater than 17 K) is achieved only by maintaining the layer thickness well below d approximately equal to 1.0 μm

  3. Dalle applicazioni professionali al 3D per tutti

    Directory of Open Access Journals (Sweden)

    Domenico Santarsiero

    2008-03-01

    Full Text Available From professional applications to 3D for everyone The applications of 3D technology are constantly maturing and so are the solutions designed to satisfy the needs of various professionals. The development of extremely user oriented solutions, which encouraged the use of 3D technology by a wide range of users, have evolved alongside a market in which final user skills are fundamental. The origins of this trend are particularly evident in the massive diffusion of geospatial web applications.

  4. Investigation of orientation gradients around a hard Laves particle in a warm-rolled Fe3Al-based alloy using a 3D EBSD-FIB technique

    International Nuclear Information System (INIS)

    Konrad, J.; Zaefferer, S.; Raabe, D.

    2006-01-01

    We present a study of the microstructure around a hard Laves particle in a warm-rolled intermetallic Fe 3 Al-based alloy. The experiments are conducted using a system for three-dimensional orientation microscopy (3D electron backscattering diffraction, EBSD). The approach is realized by a combination of a focused ion beam (FIB) unit for serial sectioning with high-resolution field emission scanning electron microscopy with EBSD. We observe the formation of steep 3D orientation gradients in the Fe 3 Al matrix around the rigid precipitate which entail in part particle-stimulated nucleation events in the immediate vicinity of the particle. The orientation gradients assume a characteristic pattern around the particle in the transverse plane while revealing an elongated tubular morphology in the rolling direction. However, they do not reveal a characteristic common rotation axis. Recovered areas in the matrix appear both in the transverse and rolling directions around the particle. The work demonstrates that the new 3D EBSD-FIB technique provides a new level of microstructure information that cannot be achieved by conventional 2D-EBSD analysis

  5. Modelado e implementación de un sistema multiagente para el diagnóstico de enfermedades de transmisión sexual

    Directory of Open Access Journals (Sweden)

    Mauro Callejas Cuervo

    2012-01-01

    Full Text Available Esta investigación presenta el modelado e implementación de una aplicación informática basada en un sistema multiagente como herramienta de apoyo a programas de prevención de enfermedades de transmisión sexual (ETS. Para ello se abordó el proceso de investigación concerniente al área de los agentes de software y los sistemas multiagentes, así como también las características que identifican las enfermedades de transmisión sexual; finalmente se exponen las principales fases del desarrollo de una aplicación web basado en sistemas multiagentes para la prevención de estas enfermedades, siguiendo la metodología Ingenias y usando la plataforma Java Agent Development Framework.

  6. Al-Qurû’ fi Al-Qur’an ‘Inda Al-Anbary fi Al-Adhdâd

    Directory of Open Access Journals (Sweden)

    Raushani Azza

    2018-03-01

    Full Text Available This study examines about the term al-Qurû in the Qur’an. Al-Qurû is one of the most popular discussions among muslim scholars and mufasir, both in terms of language and fiqh. However, there is a bate among muslim scholar and mufasir about the meaning of al-Qurû. It’s because al-Qurû is one of the sentence of al-Adhdâd wich has two meaning, especially in the Qur’an, namely haid (menstruation and thahr. One of the most popular muslim scholar who concern in Qur’an and Arabic is al-Anbari with his book al-Adhdâd. Al-Anbari explains that Qurû has two meanings, First, al-Qurû in etymology is the form of Jama’ from aqra and qurû. Second, al-Qurû has a meaning of menstruation, thahr, or the period of iddah as a sign of being allowed to remarry after certain period of time.

  7. Contribución al modelado acústico de la línea de escape en motores de combustión. Aplicación a silenciadores y catalizadores

    OpenAIRE

    Antebas -, Antoine

    2011-01-01

    Esta Tesis se centra en el desarrollo e implementación de métodos eficaces para el diseño y modelado acústico de la línea de escape de motores de combustión, y en concreto, de dos de sus componentes más relevantes desde el punto de vista de control de emisiones sonoras, como son los silenciadores y los catalizadores. Por ello, se realiza una revisión bibliográfica de los modelos unidimensionales y la representación matricial asociada. También se lleva a cabo una revisión de la literatura ...

  8. Contribución al modelado acústico de la línea de escape en motores de combustión. Aplicación a silenciadores y catalizadores

    OpenAIRE

    Antebas -, Antoine

    2010-01-01

    Esta Tesis se centra en el desarrollo e implementación de métodos eficaces para el diseño y modelado acústico de la línea de escape de motores de combustión, y en concreto, de dos de sus componentes más relevantes desde el punto de vista de control de emisiones sonoras, como son los silenciadores y los catalizadores. Por ello, se realiza una revisión bibliográfica de los modelos unidimensionales y la representación matricial asociada. También se lleva a cabo una revisión de la literatura ...

  9. 3D microstructural characterization and mechanical properties of constituent particles in Al 7075 alloys using X-ray synchrotron tomography and nanoindentation

    International Nuclear Information System (INIS)

    Singh, Sudhanshu S.; Schwartzstein, Cary; Williams, Jason J.; Xiao, Xianghui; De Carlo, Francesco; Chawla, Nikhilesh

    2014-01-01

    Highlights: • Combined 3D microstructural characterization and mechanical properties of inclusions in Al 7075 alloys. • 3D microstructural characterization of inclusions was obtained by X-ray synchrotron tomography. • Mechanical properties of inclusions was obtained by CSM technique in nanoindentation. • Quantitative characterization of volume fraction, size, and morphology of inclusions and porosity. - Abstract: Inclusions (constituent particles) in Al 7075 alloys can be classified as Fe-bearing and Si-bearing inclusions. They play important roles in the deformation behavior, particular under fatigue loading. Thus, in order to understand the deformation behavior under fatigue loading of Al 7075 alloys, it is important to investigate the size and distribution of these inclusions and porosity in the material, along with their mechanical properties. X-ray synchrotron tomography was used to obtain the 3D microstructure of these microconstituents in Al 7075 alloy. Quantitative analysis in terms of volume, size, and morphology of inclusions and porosity was performed. The mechanical properties of these constituent particles along with the matrix were obtained using nanoindentation. Scanning electron microscopy (SEM) and EDS was used to analyze the indentations after testing. The Young’s modulus and hardness of all inclusions were higher than the matrix. The Young’s modulus values of Al 7 Cu 2 Fe, Al 23 Fe 4 Cu, and Mg 2 Si were measured to be 160.2 ± 10.9, 139.5 ± 3.7, and 94.8 ± 7.5 GPa respectively. Values of hardness of Al 7 Cu 2 Fe, Al 23 Fe 4 Cu, and Mg 2 Si were 8.8 ± 0.9, 7.5 ± 0.8, and 5.2 ± 0.5 GPa respectively. Comparison of these values with nanoindentation data in the literature was also conducted

  10. 3D microstructural characterization and mechanical properties of constituent particles in Al 7075 alloys using X-ray synchrotron tomography and nanoindentation

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Sudhanshu S.; Schwartzstein, Cary; Williams, Jason J. [Materials Science and Engineering, Arizona State University, Tempe, AZ 85287-6106 (United States); Xiao, Xianghui; De Carlo, Francesco [Advanced Photon Source, Argonne National Laboratory, Argonne, IL (United States); Chawla, Nikhilesh, E-mail: nchawla@asu.edu [Materials Science and Engineering, Arizona State University, Tempe, AZ 85287-6106 (United States)

    2014-07-25

    Highlights: • Combined 3D microstructural characterization and mechanical properties of inclusions in Al 7075 alloys. • 3D microstructural characterization of inclusions was obtained by X-ray synchrotron tomography. • Mechanical properties of inclusions was obtained by CSM technique in nanoindentation. • Quantitative characterization of volume fraction, size, and morphology of inclusions and porosity. - Abstract: Inclusions (constituent particles) in Al 7075 alloys can be classified as Fe-bearing and Si-bearing inclusions. They play important roles in the deformation behavior, particular under fatigue loading. Thus, in order to understand the deformation behavior under fatigue loading of Al 7075 alloys, it is important to investigate the size and distribution of these inclusions and porosity in the material, along with their mechanical properties. X-ray synchrotron tomography was used to obtain the 3D microstructure of these microconstituents in Al 7075 alloy. Quantitative analysis in terms of volume, size, and morphology of inclusions and porosity was performed. The mechanical properties of these constituent particles along with the matrix were obtained using nanoindentation. Scanning electron microscopy (SEM) and EDS was used to analyze the indentations after testing. The Young’s modulus and hardness of all inclusions were higher than the matrix. The Young’s modulus values of Al{sub 7}Cu{sub 2}Fe, Al{sub 23}Fe{sub 4}Cu, and Mg{sub 2}Si were measured to be 160.2 ± 10.9, 139.5 ± 3.7, and 94.8 ± 7.5 GPa respectively. Values of hardness of Al{sub 7}Cu{sub 2}Fe, Al{sub 23}Fe{sub 4}Cu, and Mg{sub 2}Si were 8.8 ± 0.9, 7.5 ± 0.8, and 5.2 ± 0.5 GPa respectively. Comparison of these values with nanoindentation data in the literature was also conducted.

  11. Thermodynamics of superconducting Nb3Al, Nb3Ge, Nb3Sn, and V3Ga

    Science.gov (United States)

    Mitrović, B.; Schachinger, E.; Carbotte, J. P.

    1984-06-01

    We have calculated the superconducting thermodynamic properties for several high-transition-temperature A15 compounds: Nb-Al, Nb-Ge, Nb-Sn, and V-Ga. In our calculations we have used the tunneling electron-phonon-coupling spectra α2F for all four systems considered, and in the case of Nb-Al and Nb-Ge we have also used α2F=CG, where G is the measured generalized phonon density of states and C is a constant. We find that all Nb-based A15 compounds display similar thermodynamic properties, which do not depend explicitly on the band density of states: 2Δ0κBTc≅4.6, ΔCγTc≅2.5-2.6,-Tc[dHc(T)dT]TcHc(0)≅2.1, γ[TcHc(0)]2≅0.134, and positive D(t)'s with the maximum value around 0.02. For Nb3Sn we find good agreement between the calculated properties and the old specific-heat experimental results (γ≅52 mJ/mol K2). The same applies to V3Ga, where the theoretical results have been compared with the experiments of Junod et al. However, we do not find good agreement between calculated ΔCγTc, - Tc[dHc(T)dT]TcHc(0), γ[TcHc(0)]2, and experimental values for Nb3Al and Nb3Ge, presumably due to broadened transitions. It is argued that the tunneling experiments underestimate the value of the gap which should be associated with the inverted α2F.

  12. Enhanced photocatalytic properties of the 3D flower-like Mg-Al layered double hydroxides decorated with Ag{sub 2}CO{sub 3} under visible light illumination

    Energy Technology Data Exchange (ETDEWEB)

    Ao, Yanhui, E-mail: andyao@hhu.edu.cn; Wang, Dandan; Wang, Peifang; Wang, Chao; Hou, Jun; Qian, Jin

    2016-08-15

    Highlights: • 3D flower-like Ag{sub 2}CO{sub 3}/Mg-Al layered double hydroxide composite was prepared. • The nanocomposites exhibited high photocatalytic activities on different organic pollutants. • The mechanism of the enhanced activity were investigated. - Abstract: A facile anion-exchange precipitation method was employed to synthesize 3D flower-like Ag{sub 2}CO{sub 3}/Mg-Al layered double hydroxide composite photocatalyst. Results showed that Ag{sub 2}CO{sub 3} nanoparticles dispersed uniformly on the petals of the flower-like Mg-Al LDH. The obtained nanocomposites exhibited high photocatalytic activities on different organic pollutants (cationic and anionic dyes, phenol) under visible light illumination. The high photocatalytic activity can be ascribed to the special structure which accomplishes the wide-distribution of Ag{sub 2}CO{sub 3} nanoparticles on the surfaces of the 3D flower-like nanocomposites. Therefore, it can provide much more active sites for the degradation of organic pollutant. Then the photocatalytic mechanism was also verified by reactive species trapping experiments in detail. The work would pave a facile way to prepare LDHs based hierarchical photocatalysts with high activity for the degradation of wide range organic pollutants under visible light irradiation.

  13. Modelado de sistemas bioquímicos: De la Ley de Acción de Masas a la Aproximación Lineal del Ruido

    Directory of Open Access Journals (Sweden)

    Jesús Picó

    2015-07-01

    Full Text Available Resumen: Durante la ultima década hemos vivido una creciente aplicación de técnicas propias de las ingenierías a la biología. Áreas como la Biología de Sistemas o, más recientemente, la Biología Sintética, reciben una atención cada vez mayor por parte de los ingenieros. En particular, el modelado en estos ámbitos permite la generación de nuevas hipótesis contrastables experimentalmente, y de nuevas formas de intervención biológica, así como explicaciones más o menos mecanicistas de los resultados experimentales. Una aproximación basada en modelo requiere considerar la dinámica de las reacciones bioquímicas y su regulación. En la primera parte de este tutorial se introducen el modelado determinista y reducción de modelos de la clase de reacciones bioquímicas propias de la biología molecular celular.El ruido juega un papel crucial en la dinámica de los circuitos biológicos. En el área de control automático hay una larga tradición de modelado mediante ecuaciones diferenciales estocásticas lineales, bajo la hipótesis simplificadora de asumir que el ruido tiene una magnitud independiente de la del estado. Esta hipótesis no es válida en los circuitos biológicos. En la segunda parte del tutorial se describen los métodos de modelado estocástico más usados en biología molecular, con especial atención a denominada aproximación lineal del ruido. Abstract: In the last decade we have witnessed a growing application of engineering techniques to biology. Areas such as Systems Biology or, more recently, Synthetic Biology, get more and more attention from the engineers. Specifically, modeling in these fields makes possible the generation of new experimentally verifiable hypothesis, and new ways of biological intervention, as well as more or less mechanistic explanations of experimental results. A model-based approximation requires the consideration of the biochemical reactions dynamics and their regulation. The first part

  14. Formation of epitaxial Al 2O 3/NiAl(1 1 0) films: aluminium deposition

    Science.gov (United States)

    Lykhach, Y.; Moroz, V.; Yoshitake, M.

    2005-02-01

    Structure of epitaxial Al 2O 3 layers formed on NiAl(1 1 0) substrates has been studied by means of reflection high-energy electron diffraction (RHEED). The elucidated structure was compared to the model suggested for 0.5 nm-thick Al 2O 3 layers [K. Müller, H. Lindner, D.M. Zehner, G. Ownby, Verh. Dtsch. Phys. Ges. 25 (1990) 1130; R.M. Jaeger, H. Kuhlenbeck, H.J. Freund, Surf. Sci. 259 (1991) 235]. The stepwise growth of Al 2O 3 film, involving deposition and subsequent oxidation of aluminium onto epitaxial 0.5 nm-thick Al 2O 3 layers, has been investigated. Aluminium was deposited at room temperature, whereas its oxidation took place during annealing at 1070 K. The Al 2O 3 thickness was monitored by means of Auger electron spectroscopy (AES). It was found that Al 2O 3 layer follows the structure of 0.5 nm thick Al 2O 3 film, although a tilting of Al 2O 3(1 1 1) surface plane with respect to NiAl(1 1 0) surface appeared after Al deposition.

  15. Abrupt symmetry decrease in the ThT2Al20 alloys (T = 3d transition metal)

    International Nuclear Information System (INIS)

    Uziel, A.; Bram, A.I.; Venkert, A.; Kiv, A.E.; Fuks, D.; Meshi, L.

    2015-01-01

    Th-T-Al system, where T-3d transition metals, was studied at ThT 2 Al 20 stoichiometry to establish the influence of T on the structural stability of ternary aluminide formed. Different alloys were prepared, varying T in the row from Ti to Fe. Using electron microscopy and X-ray diffraction methods it was found that ThT 2 Al 20 phase adopts CeCr 2 Al 20 structure type when T = Ti, V, and Cr. Starting from Mn, the symmetry of the stable Al-rich phase, which forms in the alloys with the same composition, decreases from cubic to orthorhombic. The results of Density Functional Theory (DFT) calculations coincide with experiments. Concepts of the Theory of Coordination Compounds and Jahn–Teller effect were used to explain the observed abrupt change of the symmetry. These considerations were supported by DFT calculations. - Highlights: • Type of transition metal influences symmetry change in the ThT 2 Al 20 alloys. • It was found that cubic ThT 2 Al 20 phase is stable for T = Ti, V and Cr. • When T = Mn, Fe–Al + orthorhombic ThT 2 Al 10 are formed, lowering the symmetry. • Experimental results and DFT calculations were in full agreement. • TCC and of Jahn–Teller effect were used for explanation of the results

  16. Desarrollo y validación experimental de un modelo computacional de pilas de combustible tipo PEM y su aplicación al análisis de monoceldas

    OpenAIRE

    Iranzo Paricio, Alfredo

    2010-01-01

    La presente tesis doctoral tiene como objetivo fundamental el desarrollo de un modelo computacional para pilas de combustible tipo PEM, que suponga un avance con respecto al estado actual del modelado de pilas de combustible. ... * Desarrollo de un model

  17. Hydrogenation/Deoxygenation (H/D Reaction of Furfural-Acetone Condensation Product using Ni/Al2O3-ZrO2 Catalyst

    Directory of Open Access Journals (Sweden)

    Adam Mahfud

    2016-08-01

    Full Text Available The catalytic hydrogenation/deoxygenation (H/D reaction was carried out using Ni/Al2O3-ZrO2 catalyst. The 10% (wt/wt of Ni were impregnated on Al2O3-ZrO2 (10NiAZ by wet impregnation method followed by calcination and reduction. X-Ray diffraction analysis showed that Nideposited on the surface, with specific surface areas (SBET was 48.616 m2/g. Catalyst performance were evaluated for H/D reaction over furfural-acetone condensation products, mixture of 2-(4-furyl-3-buten-2-on and 1,5-bis-(furan-2-yl-pentan-3-one. The reaction was carried out in a batch, performed at 150°C for 8 hours. The H/D reaction gave alkane derivatives C8 and C10 by hydrogenation process followed by ring opening of furan in 15.2% yield. While, oxygenated product C10-C13 were also detected in 17.2% yield. The increasing of pore volume of 10NiAZ might enhance catalyst activity over H/D reaction. The alkene C=C bond was easy to hydrogenated under this condition by the lower bond energy gap.

  18. Thermodynamics of superconducting Nb3Al, Nb3Ge, Nb3Sn, and V3Ga

    International Nuclear Information System (INIS)

    Mitrovic, B.; Schachinger, E.; Carbotte, J.P.

    1984-01-01

    We have calculated the superconducting thermodynamic properties for several high-transition-temperature A15 compounds: Nb-Al, Nb-Ge, Nb-Sn, and V-Ga. In our calculations we have used the tunneling electron-phonon--coupling spectra α 2 F for all four systems considered, and in the case of Nb-Al and Nb-Ge we have also used α 2 F = CG, where G is the measured generalized phonon density of states and C is a constant. We find that all Nb-based A15 compounds display similar thermodynamic properties, which do not depend explicitly on the band density of states: 2Δ 0 /k/sub B/T/sub c/approx. =4.6, ΔC/γT/sub c/approx. =2.5--2.6, -T/sub c/[dH/sub c/(T)/dT]c/ H/sub c/(0)approx. =2.1, γ[T/sub c//H/sub c/(0)] 2 approx. =0.134, and positive D(t)'s with the maximum value around 0.02. For Nb 3 Sn we find good agreement between the calculated properties and the old specific-heat experimental results (γapprox. =52 mJ/mol K 2 ). The same applies to V 3 Ga, where the theoretical results have been compared with the experiments of Junod et al. However, we do not find good agreement between calculated ΔC/γT/sub c/, -T/sub c/[dH/sub c/(T)/dT]c/H/sub c/(0), γ[T/sub c//H/sub c/(0)] 2 , and experimental values for Nb 3 Al and Nb 3 Ge, presumably due to broadened transitions. It is argued that the tunneling experiments underestimate the value of the gap which should be associated with the inverted α 2 F

  19. Stability and electronic structure studies of LaAlO3/SrTiO3 (110) heterostructures

    International Nuclear Information System (INIS)

    Du Yan-Ling; Wang Chun-Lei; Li Ji-Chao; Xu Pan-Pan; Zhang Xin-Hua; Liu Jian; Su Wen-Bin; Mei Liang-Mo

    2014-01-01

    The first-principles calculations are employed to investigate the stability, magnetic, and electrical properties of the oxide heterostructure of LaAlO 3 /SrTiO 3 (110). By comparing their interface energies, it is obtained that the buckled interface is more stable than the abrupt interface. This result is consistent with experimental observation. At the interface of LaAlO 3 /SrTiO 3 (110) heterostructure, the Ti—O octahedron distortions cause the Ti t 2g orbitals to split into the two-fold degenerate d xz /d yz and nondegenerate d xy orbitals. The former has higher energy than the latter. The partly filled two-fold degenerate t 2g orbitals are the origin of two-dimensional electron gas, which is confined at the interface. Lattice mismatch between LaAlO 3 and SrTiO 3 leads to ferroelectric-like lattice distortions at the interface, and this is the origin of spin-splitting of Ti 3d electrons. Hence the magnetism appears at the interface of LaAlO 3 /SrTiO 3 (110). (condensed matter: electronic structure, electrical, magnetic, and optical properties)

  20. MODELADO DE PROCESOS DE TRABAJO INTENSIVOS EN CONOCIMIENTO. UNA APLICACIÓN EN LA INDUSTRIA DEL SOFTWARE CUBANA

    Directory of Open Access Journals (Sweden)

    Carlos Rolando Macías Gelabert

    2009-09-01

    Full Text Available

    En este documento se propone un método general para el modelado de procesos de trabajo intensivos en conocimiento, donde se establece la necesidad de integrar los esfuerzos de mejoramiento de flujos de trabajo y del conocimiento. Se plantean criterios para la selección del proceso utilizando enfoques cualitativos, su análisis a través de la matriz de la estructura de diseño y el modelado genérico de actividades, que contribuyen a determinar la dependencia y estructuración del conocimiento en las actividades, respectivamente. Estas herramientas permiten identificar factores a considerar para la toma de decisiones de mejoramiento en dichos procesos de trabajo. El método fue aplicado en una organización cubana de la industria del software.

  1. Development of permanent magnet MnAlC/polymer composites and flexible filament for bonding and 3D-printing technologies

    Science.gov (United States)

    Rial, Javier; de Vicente, Javier; Skårman, Björn; Vidarsson, Hilmar; Larsson, Per-Olof

    2018-01-01

    Abstract Searching for high-performance permanent magnets components with no limitation in shape and dimensions is highly desired to overcome the present design and manufacturing restrictions, which affect the efficiency of the final devices in energy, automotive and aerospace sectors. Advanced 3D-printing of composite materials and related technologies is an incipient route to achieve functional structures avoiding the limitations of traditional manufacturing. Gas-atomized MnAlC particles combined with polymer have been used in this work for fabricating scalable rare earth-free permanent magnet composites and extruded flexible filaments with continuous length exceeding 10 m. Solution casting has been used to synthesize homogeneous composites with tuned particles content, made of a polyethylene (PE) matrix embedding quasi-spherical particles of the ferromagnetic τ-MnAlC phase. A maximum filling factor of 86.5 and 72.3% has been obtained for the composite and the filament after extrusion, respectively. The magnetic measurements reveal no deterioration of the properties of the MnAlC particles after the composite synthesis and filament extrusion. The produced MnAlC/PE materials will serve as precursors for an efficient and scalable design and fabrication of end-products by different processing techniques (polymerized cold-compacted magnets and 3D-printing, respectively) in view of technological applications (from micro electromechanical systems to energy and transport applications).

  2. LMPS como propuesta alterna a BPMN para el modelado de procesos de software

    Directory of Open Access Journals (Sweden)

    Sandro Javier Bolaños Castro

    2012-12-01

    Full Text Available This paper presents an overview of the recently-released LMPS (Lenguaje de Modelado de Procesos de Software language, intended for modeling software processes. LMPS is compared with the BPMN (Business Process Management Notation standard, establishing differences and similarities in their notation, perspective, tools and proposal. The idea is to highlight the advantages and disadvantages of using each of the notations and encourage the reader’s reflections about an alternative approach that allows modeling software processes in an easy and customized way.

  3. Influence of Al on the fatigue crack growth behavior of Fe–22Mn–(3Al)–0.6C TWIP steels

    International Nuclear Information System (INIS)

    Ma, Penghui; Qian, Lihe; Meng, Jiangying; Liu, Shuai; Zhang, Fucheng

    2015-01-01

    The influence of Al on fatigue crack growth (FCG) behavior of the high-Mn austenitic twinning-induced plasticity (TWIP) steel was investigated by conducting FCG tests on Fe–22Mn–0Al–0.6C and Fe–22Mn–3Al–0.6C TWIP steels (hereafter, referred to as 0Al and 3Al TWIP steel, respectively). The FCG tests were performed at stress ratio of 0.1 under the control of stress intensity factor range using three-point bending specimens. Excepting that the traditional two-dimensional (2D) observation methods (optical, scanning and transmission electron microscopes) were used to observe the crack paths, fracture surfaces and microstructure features, a high-resolution synchrotron X-ray computed tomography was also applied to observe the three-dimensional (3-D) crack morphology. The results indicate that the FCG resistance of the 0Al TWIP steel is superior to that of 3Al TWIP steel in the near threshold regime. Observed from the 2D crack paths and 3D crack morphologies, it can be found that the crack surface roughness and crack deflection of the 0Al steel are greater than those of 3Al steel. It is suggested that the degree of roughness-induced crack closure decreases with the addition of Al. And the 0Al steel shows much larger plastic zone sizes ahead of the crack tip than the 3Al steel, suggesting that plasticity-induced crack closure may also play an important role in decreasing the FCG rate in the 0Al steel. By excluding the crack closure effects, the 0Al steel still exhibits a higher effective crack growth threshold value than the 3Al steel; this is considered to be due to the higher planarity of slip in the 0Al steel than in the 3Al steel, and the mechanical twins generated in the 0Al steel reduce the stress concentration at crack tip

  4. Modelado de sistemas de visión en 2D y 3D: un enfoque hacia el control de robots manipuladores

    Directory of Open Access Journals (Sweden)

    Maximiliano Bueno López

    2013-09-01

    Full Text Available Visual servoing of robot manipulators has been an evolving issue in recent years, especially in applications where the environment is not structured or where access is difficult for operators. To design these controllers, previous simulations are important to adjust parameters or implement a behavioral approach. In this paper we present two different models of vision systems. The models focus on applications in the field of manipulator-robot control. The modeling of video cameras is obtained by using perspective projections. To validate the models, two servo visual controllers in 2D and 3D are simulated.

  5. The bonding character and magnetic properties of Fe3Al: Comparison between disordered and ordered alloy

    International Nuclear Information System (INIS)

    Fan Runhua; Qi Liang; Sun Kangning; Min Guanghui; Gong Hongyu

    2006-01-01

    Fe 3 Al with D0 3 -ordered structure is one of the few structural intermetallics that can be disordered using non-equilibrium processing techniques. The bonding and magnetic character of the stoichiometric Fe 3 Al, with D0 3 -ordered or disordered structure, have been studied using the empirical electron theory of solid and molecular (EET). It was found that the magnetic property is basically dictated by the chemical bonding. There is a change of the character of the interatomic bonds from 3d(Fe)-3p(Al) for the D0 3 -ordered Fe 3 Al to 4sp(Fe)-3p(Al) for the disordered Fe 3 Al. For the latter, while the Fe 3d electrons participating in bonding is reduced, the mean magnetic moment is increased

  6. Pressure effects on the 2D electron system in LaAlO{sub 3}/SrTiO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Borisov, Vladislav; Jeschke, Harald O.; Valenti, Roser [Institute of Theoretical Physics, Goethe University, D-60438 Frankfurt am Main (Germany); Zabaleta, Jone [Max Planck Institute for Solid State Research, D-70569 Stuttgart (Germany); Kopp, Thilo [Center for Electronic Correlations and Magnetism, Experimental Physics VI, Institute of Physics, University of Augsburg, D-86135 Augsburg (Germany)

    2016-07-01

    We present a theoretical study of pressure effects on the electronic properties of the LaAlO{sub 3}/SrTiO{sub 3} (001) interface. Lattice relaxation plays a crucial role for the formation of the 2D electron system (2DES), in agreement with previous reports. We observe that the carrier density of the 2DES at zero pressure is much lower than the ''polar catastrophe'' estimate of 0.5 e{sup -} per two-dimensional unit cell, which agrees with most experimental works. Under hydrostatic pressure, structural distortions in LaAlO{sub 3} (LAO) are largely suppressed, whereas they increase in SrTiO{sub 3} (STO), and the carrier density of the 2DES is enhanced by almost 45% using a moderate pressure of 4.1 GPa. The origin of this behavior as well as the explanation for the low carrier density at the interface at ambient pressure are discussed in terms of the lattice polarization and electronic Berry phase in the LAO oxide. Reduction of the calculated static dielectric constants of LAO and STO under pressure might account for the recent experimental findings regarding the carrier mobility.

  7. Control y Operación de Estaciones Depuradoras de Aguas Residuales: Modelado y Simulación

    Directory of Open Access Journals (Sweden)

    Ramon Vilanova

    2017-07-01

    Full Text Available Resumen: Este trabajo constituye la primera parte de una revisión de la problemática del control y operación de estaciones depuradoras de aguas residuales (EDAR para el tratamiento de agua residual urbana. En esta primera parte nos centramos en el modelado y simulación mientras que la segunda parte se dedica en exclusiva al control y operación. Esta depuración se realiza, mayoritariamente, mediante procesos biológicos, concretamente, mediante el denominado proceso de fangos activados. El hecho de tratar con un proceso biológico conlleva una elevada complejidad tanto desde el punto de vista de modelado como, por supuesto, de control y operación. Para poder ubicar convenientemente el problema, se presenta una caracterización de las aguas residuales urbanas y las necesidades de depuración asociadas. El control y operación descansan en gran medida en la disponibilidad de modelos apropiados y, ya hoy en día, de una elevada fiabilidad. Se presentan los modelos de la familia ASM; poniendo especial énfasis en el ASM1 que se describe en más detalle; así como las características de otras unidades de proceso como el decantador y su interconexión. En estos modelos destacan los entornos BSM de benchmarking, que han sido esenciales para todo el posterior desarrollo en la actividad de control y operación. Abstract: This tutorial is the first part of a review of the problems arising with the control and operation of wastewater treatment plants (WWTP for urban wastewater. This first part will concentrate in the modelling and simulation steps whereas the second part will cover the control and operation issues. This treatment is carried out, mainly, by biological processes. Specifically, by the so-called activated sludge process. Dealing with a biological process entails a high complexity both from the viewpoint of modelling and, of course, from what matters to control and operation. In order to properly locate the problem, a characterisation of

  8. Insight into the mechanism of methanol assistance with syngas conversion over partially hydroxylated γ-Al2O3(110D) surface in slurry bed.

    Science.gov (United States)

    Bai, Bing; Bai, Hui; Cao, Hao-Jie; Gao, Zhi-Hua; Zuo, Zhi-Jun; Huang, Wei

    2018-04-27

    Despite numerous studies devoted to the various properties of γ-Al2O3, the explorations of its catalytic activity remain scarce. In this study, density functional theory calculations are performed to study the elementary adsorption and reaction mechanisms for syngas conversion on partially hydroxylated γ-Al2O3(110D) surface in liquid paraffin. It is found that the partially hydroxylated γ-Al2O3(110D) surface with the hydroxyl coverage of 8.9 OH nm-2 is formed by two dissociative adsorptions of H2O on the dry γ-Al2O3(110D) surface. The hydroxyl coverage conditions play a key role in determining the dominant reaction mechanism on account of the existence of strong hydrogen bonds. The preferential pathway for syngas conversion with assistance of methanol over the partially hydroxylated γ-Al2O3(110D) surface in liquid paraffin has been proven to be CH3OH → CH3O + H → CH3 + OH, CH3 + CO → CH3CO. C2H5OH is then formed by successive hydrogenation via the pathway CH3CO + 3H → CH3CHO + 2H → CH3CH2O + H → C2H5OH. Here, CH3CHO formation by CH3CO hydrogenation is not inhibited. Actually, with the assistance of partially hydroxylated γ-Al2O3, CH3CHO has been synthesized with high selectivity in our previous experiment by the reaction of methanol and syngas, which provides favorable evidence for our results. The rate-limiting step is the formation of CH3O from CH3OH dehydrogenation with an activation barrier of 122.2 kJ mol-1. Moreover, the reaction barrier of CO insertion into the adsorbed CH3 group is at least 89.4 kJ mol-1, lower than those of CH4, C2H6, and CH3OCH3 formations. ADCH charge and ESP analyses indicate that the typical (Al, O) Lewis acid-base pair may have a significant effect upon the initial C-C chain formation. Thus, the present study provides a new approach for the rational tailoring and designing of new catalysts with superior reactivity involved in syngas conversion.

  9. The Study of Electrical Properties for Multilayer La2O3/Al2O3 Dielectric Stacks and LaAlO3 Dielectric Film Deposited by ALD.

    Science.gov (United States)

    Feng, Xing-Yao; Liu, Hong-Xia; Wang, Xing; Zhao, Lu; Fei, Chen-Xi; Liu, He-Lei

    2017-12-01

    The capacitance and leakage current properties of multilayer La 2 O 3 /Al 2 O 3 dielectric stacks and LaAlO 3 dielectric film are investigated in this paper. A clear promotion of capacitance properties is observed for multilayer La 2 O 3 /Al 2 O 3 stacks after post-deposition annealing (PDA) at 800 °C compared with PDA at 600 °C, which indicated the recombination of defects and dangling bonds performs better at the high-k/Si substrate interface for a higher annealing temperature. For LaAlO 3 dielectric film, compared with multilayer La 2 O 3 /Al 2 O 3 dielectric stacks, a clear promotion of trapped charges density (N ot ) and a degradation of interface trap density (D it ) can be obtained simultaneously. In addition, a significant improvement about leakage current property is observed for LaAlO 3 dielectric film compared with multilayer La 2 O 3 /Al 2 O 3 stacks at the same annealing condition. We also noticed that a better breakdown behavior for multilayer La 2 O 3 /Al 2 O 3 stack is achieved after annealing at a higher temperature for its less defects.

  10. UNA HERRAMIENTA MATRICIAL PARA EL MODELADO EN 2-D DE ALGUNOS PROBLEMAS DE CONTACTO ELÁSTICO

    Directory of Open Access Journals (Sweden)

    FABIO ALEXANDER SUÁREZ

    2008-01-01

    Full Text Available En los contactos localizados, la búsqueda de las relaciones entre la carga, la geometría de los cuerpos, sus propiedades elásticas y la geometría de la zona de contacto, constituye un campo del conocimiento de alto impacto tecnológico. El conocimiento de estas relaciones permite entender mejor el comportamiento de los sistemas tribológicos para mejorar su diseño y desempeño. Este artículo busca dar a conocer una herramienta matricial útil para el modelado de problemas bidimiensionales de contactos elásticos. Basada en una generalización del problema de Flamant, dicha matriz constituye un vínculo entre los desplazamientos perpendiculares a la superficie que experimentan los puntos de ésta y la forma como se distribuye la carga en la zona de contacto, permitiendo encontrar una de estas variables en función de la otra. Esta es una herramienta sencilla y de gran utilidad para la solución de problemas complejos de este tipo. Para mostrar su utilidad, esta matriz fue empleada para resolver el problema del contacto elástico entre dos cilindros largos, problema inicialmente planteado por Hertz; los resultados encontrados son iguales a los obtenidos por Hertz en su solución analítica.

  11. Synthesis of some (eta-arene)dihydridorhenium cations and their reactions with LiAlH4 and LiAlD4

    International Nuclear Information System (INIS)

    Baudrey, D.; Boydell, P.; Ephritikhine, M.

    1986-01-01

    A series of cations [Re(eta-arene)H 2 (PPh 3 ) 2 ] + (arene benzene, toluene, p-xylene, or mesitylene) was prepared from the corresponding neutral dihydridocyclohexadienyl complexes by treatment with CPh 3 BF 4 . These cations reacted with LiAlH 4 and LiAlD 4 to form dihydridocyclohexadienyl complexes. The unusual selectivity of the hydride attack is explained by steric interactions between the ring methyl groups and the bulky phosphine ligands. The initial product of the reaction of the eta-mesitylene cation with LiAlD 4 allows the isomerisation mechanism for the cyclohexadienyl complexes to be clarified. (author)

  12. Ibn Qutayba en al-Andalus. La préface à I 'Adab al-Kātib dans le commentaire d'Ibn al-Sīd al-Baṭalyawsī

    Directory of Open Access Journals (Sweden)

    Soravia, Bruna

    2004-12-01

    Full Text Available Ibn Qutayba's preface to his Adab al-kātib has been considered for centuries the most important section of this work and it has been the object of many commentaries, both in the Muslim East and West. This paper deals with Ibn al-Sīd al-Baṭalyawsī´s commentary al-Iqtiḍāb, trying to show the peculiar way in which Ibn al-Sīd develops his own critique of Ibn Qutayba's controversial thesis on the relation between orthodoxy, falsafa and kalām. At the same time, the Andalusi author works out his own conception of adab, deeply influenced by his biographical experience. Finally a full translation of Ibn Qutayba's preface is proposed, half a century after G. Lecomte's partial one.

    El prefacio de Ibn Qutayba a su Adab al-Kātib ha sido considerado durante siglos como el fragmento más importante de su obra, y ha sido objeto de muchos comentarios, tanto orientales como occidentales. Este artículo trata del comentario que Ibn al-Sīd al-Baṭalyawsī hizo de ese texto de Ibn Qutayba, e intenta mostrar la forma peculiar en que Ibn al-Sīd desarrolla su propia crítica a la polémica tesis de Ibn Qutayba sobre la relación entre ortodoxia, falsafa y kalām. Al mismo tiempo, el autor andalusí elabora su propia concepción del adab, profundamente influida por su experiencia biográfica. Para concluir, se presenta una traducción completa del prefacio de Ibn Qutayba, medio siglo después de la parcial realizada por G. Lecomte.

  13. Perfect absorption in 1D photonic crystal nanobeam embedded with graphene/Al2O3 multilayer stack

    Science.gov (United States)

    Liu, Hanqing; Zha, Song; Liu, Peiguo; Zhou, Xiaotian; Bian, Li-an

    2018-05-01

    We exploit the concept of critical coupling to graphene based chip-integrated applications and numerically demonstrate that a perfect absorption (PA) absorber in the near-infrared can be obtained by graphene/Al2O3 multilayer stack (GAMS) critical coupling with a resonant cavity in the 1D photonic crystal nanobeam (PCN). The key point is dynamically matching the coupling rate of incident light wave to the cavity with the absorbing rate of GAMS via electrically modulating the chemical potential of graphene. Simulation results show that the radius of GAMS as well as the thickness of Al2O3 layer are closely connected with the performance of perfect absorption. These results may provide potential applications in the high-density integrated optical devices, photolectric transducers, and laser pulse limiters.

  14. Spectral response of REE3+ doped LaAlO3

    International Nuclear Information System (INIS)

    Boronat, C.; Correcher, V.; Garcia G, J.; Morales, A.; Zarate, J.; Rivera, T.

    2016-10-01

    This paper reports on the preliminary results obtained from the cathodoluminescence (Cl) and thermoluminescence (Tl) properties of undoped LaAlO 3 (LAO) and LaAlO 3 : REE (REE=Dy 3+ , Pr 3+ and Eu 3+ ) to be potentially employed for dosimetric purposes. The samples were synthesized by a sol-gel process based on the Pechini 's method with a spray-drying technique and, subsequently, characterized by environmental scanning electron microscopy and energy dispersive X-ray analysis spectrometry. Cl spectra display sharp and narrow wavebands that could specifically be associated with structural (in the range of 300-450 nm) and point defects (from 450 to 800 nm). The observed wavebands could be assigned as follows: (i) 480 and 570 from the Dy-doped LAO should corresponding respectively to 4 F 9/2 → 6 H 15/2 and 4 F 9/2 → 6 H 13/2 transitions, (II) 490-638 from the Pr-doped LAO is linked to 3 P 0 → 3 H 4 , 1 D 2 → 3 H 4 transitions and (III) 590 and 620 where the dopant Eu 3+ gives rise to 5 D 0 → 7 F 1 and 5 D 0 → 7 F 2 transitions and (IV) a UV-blue broad band is associated with NBOHC in undoped LAO. Such emissions are due to the presence of the 4f electrons of rare earth ions that are shielded by the outer 5s and 5p electrons, the intra-4f emission spectra of REE. Furthermore, the study performed on the Tl emission of LaAlO 3 :Dy 3+ displays (i) two maxima centred at 150 and 240 degrees Celsius (ratio 1:2) similarly to the Pr 3+ doped sample but with 7:5 of ratio. And (II) the highest radiation sensitivity, allowing us to think on the potential use of this material for dosimetric purposes, however further works are necessary to confirm such assertion. (Author)

  15. The bonding character and magnetic properties of Fe{sub 3}Al: Comparison between disordered and ordered alloy

    Energy Technology Data Exchange (ETDEWEB)

    Fan Runhua [MOE Key Laboratory for Liquid Structure and Heredity of Materials, Shandong University, Jinan 250061 (China)]. E-mail: fan@sdu.edu.cn; Qi Liang [MOE Key Laboratory for Liquid Structure and Heredity of Materials, Shandong University, Jinan 250061 (China); Sun Kangning [MOE Key Laboratory for Liquid Structure and Heredity of Materials, Shandong University, Jinan 250061 (China); Min Guanghui [MOE Key Laboratory for Liquid Structure and Heredity of Materials, Shandong University, Jinan 250061 (China); Gong Hongyu [MOE Key Laboratory for Liquid Structure and Heredity of Materials, Shandong University, Jinan 250061 (China)

    2006-12-25

    Fe{sub 3}Al with D0{sub 3}-ordered structure is one of the few structural intermetallics that can be disordered using non-equilibrium processing techniques. The bonding and magnetic character of the stoichiometric Fe{sub 3}Al, with D0{sub 3}-ordered or disordered structure, have been studied using the empirical electron theory of solid and molecular (EET). It was found that the magnetic property is basically dictated by the chemical bonding. There is a change of the character of the interatomic bonds from 3d(Fe)-3p(Al) for the D0{sub 3}-ordered Fe{sub 3}Al to 4sp(Fe)-3p(Al) for the disordered Fe{sub 3}Al. For the latter, while the Fe 3d electrons participating in bonding is reduced, the mean magnetic moment is increased.

  16. Three-Dimensional FIB/EBSD Characterization of Irradiated HfAl3-Al Composite

    Energy Technology Data Exchange (ETDEWEB)

    Hua, Zilong; Guillen, Donna Post; Harris, William; Ban, Heng

    2016-09-01

    A thermal neutron absorbing material, comprised of 28.4 vol% HfAl3 in an Al matrix, was developed to serve as a conductively cooled thermal neutron filter to enable fast flux materials and fuels testing in a pressurized water reactor. In order to observe the microstructural change of the HfAl3-Al composite due to neutron irradiation, an EBSD-FIB characterization approach is developed and presented in this paper. Using the focused ion beam (FIB), the sample was fabricated to 25µm × 25µm × 20 µm and mounted on the grid. A series of operations were carried out repetitively on the sample top surface to prepare it for scanning electron microscopy (SEM). First, a ~100-nm layer was removed by high voltage FIB milling. Then, several cleaning passes were performed on the newly exposed surface using low voltage FIB milling to improve the SEM image quality. Last, the surface was scanned by Electron Backscattering Diffraction (EBSD) to obtain the two-dimensional image. After 50 to 100 two-dimensional images were collected, the images were stacked to reconstruct a three-dimensional model using DREAM.3D software. Two such reconstructed three-dimensional models were obtained from samples of the original and post-irradiation HfAl3-Al composite respectively, from which the most significant microstructural change caused by neutron irradiation apparently is the size reduction of both HfAl3 and Al grains. The possible reason is the thermal expansion and related thermal strain from the thermal neutron absorption. This technique can be applied to three-dimensional microstructure characterization of irradiated materials.

  17. Modelado tridimensional y análisis funcional de una cabria para la extracción del mineral

    Directory of Open Access Journals (Sweden)

    José Ignacio Rojas-Sola

    2013-01-01

    Full Text Available En el presente artículo se analiza en detalle un ejemplo del patrimonio industrial minero del antiguo distrito minero de Linares- La Carolina (Jaén, España, como es una cabria de mampostería con su castillete metálico, utilizada en la extracción del mineral de plomo, concretamente de galena o sulfuro de plomo. En particular, se ha realizado el modelado tridimensional con ayuda de software paramétrico gracias a técnicas empíricas de cada uno de los elementos que componen el conjunto. Asimismo, una vez obtenido el modelo 3D, se ha realizado un análisis funcional mediante técnicas de Ingeniería Asistida por Ordenador, basadas en el análisis tensional y el análisis de desplazamientos, comprobando que las mayores concentraciones de tensiones se producen en la parte media e inferior de los muros, que los mayores valores de tensión se producen en los alrededores de los huecos de los muros, y que la mayor concentración de desplazamientos de la cabria de mampostería se encuentran en los muros en la parte media y superior, y del castillete en las correas de la cubierta.

  18. Color-tunable and highly thermal stable Sr_2MgAl_2_2O_3_6:Tb"3"+ phosphors

    International Nuclear Information System (INIS)

    Zhang, Haiming; Zhang, Haoran; Liu, Yingliang; Lei, Bingfu; Deng, Jiankun; Liu, Wei-Ren; Zeng, Yuan; Zheng, Lingling; Zhao, Minyi

    2017-01-01

    Tb"3"+ activated Sr_2MgAl_2_2O_3_6 phosphor was prepared by a high-temperature solid-state reaction route. The X-ray diffraction, scanning electron microscopy, and photoluminescence spectroscopy were used to characterize the as-prepared samples. The Sr_2MgAl_2_2O_3_6:Tb"3"+ phosphors show intense green light emission under UV excitation. The phosphor exhibit two groups of emission lines from about 370 to 700 nm, which originating from the characteristic "5D_3-"7F_J and "5D_4-"7F_J transitions of the Tb"3"+ ion, respectively. The cross-relaxation mechanism between the "5D_3 and "5D_4 emission was investigated and discussed. The emission colors of these phosphors can be tuned from bluish-green to green by adjusting the Tb"3"+ doping concentration. Furthermore, the thermal quenching temperature (T_1_/_2) is higher than 500 K. The excellent thermal stability and color-tunable luminescent properties suggest that the developed material is a promising green-emitting phosphor candidate for optical devices. - Highlights: • A Color-tunable emitting phosphor Sr_2MgAl_2_2O_3_6:Tb"3"+ was prepared successfully via high-temperature solid-state reaction. • The photoluminescence of Sr_2MgAl_2_2O_3_6:Tb"3"+ shows highly thermal stable. • The cross-relaxation mechanism between the "5D_3 and "5D_4 emission was investigated and discussed.

  19. Measurement of the d({sup 26}Al{sup m},p){sup 27}Al reaction for nuclear astrophysics

    Energy Technology Data Exchange (ETDEWEB)

    Roeder, B.T.; Trache, L.; Iacob, V.E.; McCleskey, M.; Simmons, E.; Spiridon, A.; Tribble, R.E. [Texas A and M Univ., TX (United States); Davinson, T.; Lotay, G.; Woods, P.J. [University of Edinburgh (United Kingdom); La Cognata, M.; Pizzone, R.G.; Rapisarda, G.G.; Sparta, R.; Spitaleri, C. [Istituto Nazionale di Fisica Nucleare (LNS/INFN), Catania (Italy). Lab. Nazionali del Sud

    2012-07-01

    Full text: The detection of gamma rays from the decay of the {sup 26}Al ground state in the galaxy gives evidence that nucleosynthesis is occurring in present-day stars, but its origin is not yet clear. This implies that reactions involving {sup 26}Al are important for astrophysical processes. In a recent experiment at the Cyclotron Institute at Texas A and M University, reactions with the ground state and isomeric state of {sup 26}Al were investigated with the Texas A and M-Edinburgh-Catania Silicon detector Array (TECSA). TECSA is a collaborative effort to build a high-efficiency detector Si array useful for measuring reactions of interest for nuclear astrophysics and nuclear structure. The array consists of up to 16 Micron Semiconductor YY1 detectors that are each 300 μm thick. Each detector has 16 annular ring sectors to measure the energy and the scattering angle of the detected particles. Using TECSA, we measured d({sup 26}Al{sup g},p){sup 27}Al and d({sup 26}Al{sup m},p){sup 27}Al with a {sup 26}Al secondary beam prepared in-flight with the MARS spectrometer. First, the composition of the {sup 26}Al beam was determined by measuring the ratio of beta-decays to {sup 26}Al ions produced. It was found that at different spectrometer rigidities, beams of 2/3 isomer to ground state ratio or vice-versa could be obtained. Then, in the second part of the experiment, angular distributions were measured for both reactions at backward angles with TECSA. The protons were measured in TECSA in coincidence with timing signals from the beam detected by a scintillator and with the cyclotron radio-frequency. Details of the experiment and preliminary results from the analysis of the d({sup 26}Al{sup m},p){sup 27}Al and d({sup 26}Al{sup g},p){sup 27}Al data will be presented. They will give information about the proton capture reactions {sup 26}Al{sup m}(p,γ){sup 27}Si and {sup 26}Al{sup g}(p,γ){sup 27}Si taking place in stars. (author)

  20. The MRCI studies of low-lying electronic states of Al.sub.3./sub. and Al.sup.-./sup.3

    Czech Academy of Sciences Publication Activity Database

    Czernek, Jiří; Živný, Oldřich

    2011-01-01

    Roč. 512, 1-3 (2011), s. 40-43 ISSN 0009-2614 R&D Projects: GA ČR GAP205/11/2070 Institutional research plan: CEZ:AV0Z40500505; CEZ:AV0Z20430508 Keywords : Al3 * excitations * MRCI Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.337, year: 2011

  1. Separation of reaction mechanisms at low energy. Study of the reactions: {sup 27}Al(d,p) {sup 28}Al, {sup 24}Mg(d,p) {sup 25}Mg, and {sup 24}Mg(d, {alpha}) {sup 22}Na; Sur la separation des mecanismes de reaction a basse energie. Etude des reactions: {sup 27}Al(d,p) {sup 28}Al, {sup 24}Mg(d,p) {sup 25}Mg, et {sup 24}Mg(d, {alpha}) {sup 22}Na

    Energy Technology Data Exchange (ETDEWEB)

    Mermaz, M. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-06-01

    The two sets of angular distributions of (d,p) reactions on Al and Mg, measured between 2 and 6 MeV, have given the possibility to test, in analysing the statistical fluctuations of cross-section, the validity of the separation of their mean values in two parts, one 'direct', another given by the statistical mechanism. With the same method of analysis we have studied excitation functions for several alpha groups of the reaction {sup 24}Mg(d, {alpha}) {sup 22}Na and given an evidence for an intermediate structure for the alpha channel leading to the 3. excited state of {sup 22}Na. The angular distribution of the wide resonance at 15.9 MeV in {sup 26}Al has been obtained. (author) [French] Les deux ensembles de distributions angulaires des reactions (d,p) sur Al et Mg, mesures entre 2 et 6 MeV, nous ont permis, en analysant les fluctuations statistiques de sections efficaces, de verifier la possibilite de la separation de leurs valeurs moyennes en deux composantes: l'une 'directe', l'autre due au mecanisme statistique. Avec la meme methode d'analyse nous avons etudie les fonctions d'excitation des premiers groupes alpha de la reaction {sup 24}Mg(d,{alpha}) {sup 22}Na et mis en evidence une structure intermediaire pour la voie de reaction aboutissant au 3eme niveau de {sup 22}Na. Nous avons obtenu la distribution angulaire de la resonance large situee a une energie d'excitation de 15,9 MeV dans {sup 26}Al. (auteur)

  2. Separation of reaction mechanisms at low energy. Study of the reactions: {sup 27}Al(d,p) {sup 28}Al, {sup 24}Mg(d,p) {sup 25}Mg, and {sup 24}Mg(d, {alpha}) {sup 22}Na; Sur la separation des mecanismes de reaction a basse energie. Etude des reactions: {sup 27}Al(d,p) {sup 28}Al, {sup 24}Mg(d,p) {sup 25}Mg, et {sup 24}Mg(d, {alpha}) {sup 22}Na

    Energy Technology Data Exchange (ETDEWEB)

    Mermaz, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-06-01

    The two sets of angular distributions of (d,p) reactions on Al and Mg, measured between 2 and 6 MeV, have given the possibility to test, in analysing the statistical fluctuations of cross-section, the validity of the separation of their mean values in two parts, one 'direct', another given by the statistical mechanism. With the same method of analysis we have studied excitation functions for several alpha groups of the reaction {sup 24}Mg(d, {alpha}) {sup 22}Na and given an evidence for an intermediate structure for the alpha channel leading to the 3. excited state of {sup 22}Na. The angular distribution of the wide resonance at 15.9 MeV in {sup 26}Al has been obtained. (author) [French] Les deux ensembles de distributions angulaires des reactions (d,p) sur Al et Mg, mesures entre 2 et 6 MeV, nous ont permis, en analysant les fluctuations statistiques de sections efficaces, de verifier la possibilite de la separation de leurs valeurs moyennes en deux composantes: l'une 'directe', l'autre due au mecanisme statistique. Avec la meme methode d'analyse nous avons etudie les fonctions d'excitation des premiers groupes alpha de la reaction {sup 24}Mg(d,{alpha}) {sup 22}Na et mis en evidence une structure intermediaire pour la voie de reaction aboutissant au 3eme niveau de {sup 22}Na. Nous avons obtenu la distribution angulaire de la resonance large situee a une energie d'excitation de 15,9 MeV dans {sup 26}Al. (auteur)

  3. Structural stability and electronic properties of AlCu3, AlCu2Zr in AlZr3: Stabilnost strukture in elektronske lastnosti AlCu3, AlCu2Zr in AlZr3:

    OpenAIRE

    Cheng, Rong; Wu, Xiao-Yu

    2013-01-01

    First-principles calculations were performed to study the alloying stability and electronic structure of the Al-based intermetallic compounds AlCusub3, AlCusub{2}Zr and AlZrsub3. The results show that the lattice parameters obtained after the full relaxation of the crystalline cells are consistent with the experimental data, and these intermetallics have a strong alloying ability and structural stability due to their negative formation energies and their cohesive energies. A further analysis ...

  4. Lattice stabilities, mechanical and thermodynamic properties of Al3Tm and Al3Lu intermetallics under high pressure from first-principles calculations

    Science.gov (United States)

    Xu-Dong, Zhang; Wei, Jiang

    2016-02-01

    The effects of high pressure on lattice stability, mechanical and thermodynamic properties of L12 structure Al3Tm and Al3Lu are studied by first-principles calculations within the VASP code. The phonon dispersion curves and density of phonon states are calculated by using the PHONONPY code. Our results agree well with the available experimental and theoretical values. The vibrational properties indicate that Al3Tm and Al3Lu keep their dynamical stabilities in L12 structure up to 100 GPa. The elastic properties and Debye temperatures for Al3Tm and Al3Lu increase with the increase of pressure. The mechanical anisotropic properties are discussed by using anisotropic indices AG, AU, AZ, and the three-dimensional (3D) curved surface of Young’s modulus. The calculated results show that Al3Tm and Al3Lu are both isotropic at 0 GPa and anisotropic under high pressure. In the present work, the sound velocities in different directions for Al3Tm and Al3Lu are also predicted under high pressure. We also calculate the thermodynamic properties and provide the relationships between thermal parameters and temperature/pressure. These results can provide theoretical support for further experimental work and industrial applications. Project supported by the Scientific Technology Plan of the Educational Department of Liaoning Province and Liaoning Innovative Research Team in University, China (Grant No. LT2014004) and the Program for the Young Teacher Cultivation Fund of Shenyang University of Technology, China (Grant No. 005612).

  5. Direct detection of neutral metal atoms in electron-stimulated desorption: Al from CH3O/Al(111) - velocity distribution and absolute yield

    International Nuclear Information System (INIS)

    Whitten, J.E.; Young, C.E.; Pellin, M.J.; Gruen, D.M.; Jones, P.L.

    1994-01-01

    Electron-stimulated desorption of neutral aluminum from the system CH 3 O/Al(111) has been directly monitored via quasiresonant photoionization with 193 nm excimer laser light and confirmed by two-step resonant ionization, utilizing the Al 3d 2 D manifold. Velocity distribution measurements for the neutral Al peak at ∼ 800 m/s for 1 keV incident electron energy. An absolute yield of 3.2 x 10 -6 Al atoms/electron was determined by comparison with sputtering measurements in the same apparatus. This is the first observation of electron-stimulated metal desorption from adsorbate-covered metallic surfaces

  6. Quench tests of Nb3Al small racetrack magnets

    International Nuclear Information System (INIS)

    Yamada, R.; Kikuchi, A.; Tartaglia, Michael Albert; Ambrosio, G.; Andreev, N.; Barzi, E.; Carcagno, R.; Feher, S.; Kashikhin, V.V.; Kotelnikov, S.; Lamm, Michael J.; Fermilab; NIMC, Tsukuba; KEK, Tsukuba

    2007-01-01

    Two Cu stabilized Nb3Al strands, F1 (Nb matrixed) and F3 (Ta matrixed), have been made at NIMS and their Rutherford cables were made at Fermilab in collaboration with NIMS. A Small Race-track magnet using F1 Rutherford cable, the first Nb3Al dipole magnet in the world, was constructed and tested to full current at Fermilab. This magnet was tested extensively to full short sample data and its quench characteristics were studied and reported. The 3-D magnetic field calculation was done with ANSYS to find the peak field. The quench characteristics of the magnet are explained with the characteristics of the Nb3Al strand and Rutherford cable. The other Small Race-track magnet using Ta matrixed F3 strand was constructed and will be tested in the near future. The advantages and disadvantages of these Nb3Al cables are discussed

  7. Quench tests of Nb3Al small racetrack magnets

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, R.; Kikuchi, A.; Tartaglia, Michael Albert; Ambrosio, G.; Andreev, N.; Barzi, E.; Carcagno, R.; Feher, S.; Kashikhin, V.V.; Kotelnikov, S.; Lamm, Michael J.; /Fermilab /NIMC, Tsukuba /KEK, Tsukuba

    2007-08-01

    Two Cu stabilized Nb3Al strands, F1 (Nb matrixed) and F3 (Ta matrixed), have been made at NIMS and their Rutherford cables were made at Fermilab in collaboration with NIMS. A Small Race-track magnet using F1 Rutherford cable, the first Nb3Al dipole magnet in the world, was constructed and tested to full current at Fermilab. This magnet was tested extensively to full short sample data and its quench characteristics were studied and reported. The 3-D magnetic field calculation was done with ANSYS to find the peak field. The quench characteristics of the magnet are explained with the characteristics of the Nb3Al strand and Rutherford cable. The other Small Race-track magnet using Ta matrixed F3 strand was constructed and will be tested in the near future. The advantages and disadvantages of these Nb3Al cables are discussed.

  8. Heterogeneous nucleation of solid Al from the melt by Al 3 Ti : Molecular dynamics simulations

    KAUST Repository

    Wang, Junsheng; Horsfield, Andrew; Lee, Peter D.; Brommer, Peter

    2010-01-01

    It has been known experimentally for some time that Al3 Ti is a powerful nucleant for the solidification of aluminum from the melt; however, a full microscopic understanding is still lacking. To develop this understanding, we have performed molecular dynamics simulations of the nucleation and early stages of growth using published embedded atom method potentials for Al-Ti, but modified by us to stabilize the D 022 structure. We discover that Al3 Ti can indeed be very effective in promoting the growth of solid Al but the manner in which growth takes place depends sensitively on the surface on which the Al nucleates. In particular, complete growth of solid Al from the liquid on the (001) and (110) surfaces of Al3 Ti occurs at a lower temperature than on the (112) surface. This anisotropy agrees with observations in previous experiments. We explain this observation in terms of interfacial energies. On the preferential (111) surface of Al the solid-liquid interfacial energy is highest while the solid-vacuum energy is lowest. Our simulations also show that the extent of ordering taking place in liquid Al close to the Al 3 Ti substrate above the melting point correlates well with the effectiveness of the substrate as a nucleant below the melting temperature: this could provide a computationally efficient scheme to identify good nucleants. © 2010 The American Physical Society.

  9. Heterogeneous nucleation of solid Al from the melt by Al 3 Ti : Molecular dynamics simulations

    KAUST Repository

    Wang, Junsheng

    2010-10-27

    It has been known experimentally for some time that Al3 Ti is a powerful nucleant for the solidification of aluminum from the melt; however, a full microscopic understanding is still lacking. To develop this understanding, we have performed molecular dynamics simulations of the nucleation and early stages of growth using published embedded atom method potentials for Al-Ti, but modified by us to stabilize the D 022 structure. We discover that Al3 Ti can indeed be very effective in promoting the growth of solid Al but the manner in which growth takes place depends sensitively on the surface on which the Al nucleates. In particular, complete growth of solid Al from the liquid on the (001) and (110) surfaces of Al3 Ti occurs at a lower temperature than on the (112) surface. This anisotropy agrees with observations in previous experiments. We explain this observation in terms of interfacial energies. On the preferential (111) surface of Al the solid-liquid interfacial energy is highest while the solid-vacuum energy is lowest. Our simulations also show that the extent of ordering taking place in liquid Al close to the Al 3 Ti substrate above the melting point correlates well with the effectiveness of the substrate as a nucleant below the melting temperature: this could provide a computationally efficient scheme to identify good nucleants. © 2010 The American Physical Society.

  10. Hole centers in γ-irradiated, oxidized Al2O3

    International Nuclear Information System (INIS)

    Lee, K.H.; Holmberg, G.E.; Crawford, J.H. Jr.

    1976-01-01

    ESR observations of centers with S = 1/2, g approximately equal to 2, S = 1, g approximately equal to 2 have been made at 77 K on oxidized Al 2 O 3 after γ-irradiation at 30 0 C. From the radiation growth data, it is shown that the S = 1/2 centers are precursors of the S = 1 centers. In addition, when the S = 1 centers anneal out at about 110 0 C, the S = 1/2 centers reappear and eventually anneal out at about 260 0 C. Previously Gamble (Gamble, F.T.; Ph.D. Thesis, U. of Connecticut (1963)) and Cox (Cox, R.T.; Ph.D. Thesis, U. of Grenoble (1972) unpublished), respectively, observed S = 1/2 and S = 1 paramagnetic centers in electron-irradiated nominally pure Al 2 O 3 and γ-irradiated, oxidized, titanium-doped Al 2 O 3 . The models proposed for these centers were one hole and two holes trapped on oxygen ions adjacent to Al 3+ vacancies. Our results further substantiate these models. (author)

  11. Chemical failure modes of AlQ3-based OLEDs: AlQ3 hydrolysis.

    Science.gov (United States)

    Knox, John E; Halls, Mathew D; Hratchian, Hrant P; Schlegel, H Bernhard

    2006-03-28

    Tris(8-hydroxyquinoline)aluminum(III), AlQ3, is used in organic light-emitting diodes (OLEDs) as an electron-transport material and emitting layer. The reaction of AlQ3 with trace H2O has been implicated as a major failure pathway for AlQ3-based OLEDs. Hybrid density functional calculations have been carried out to characterize the hydrolysis of AlQ3. The thermochemical and atomistic details for this important reaction are reported for both the neutral and oxidized AlQ3/AlQ3+ systems. In support of experimental conclusions, the neutral hydrolysis reaction pathway is found to be a thermally activated process, having a classical barrier height of 24.2 kcal mol(-1). First-principles infrared and electronic absorption spectra are compared to further characterize AlQ3 and the hydrolysis pathway product, AlQ2OH. The activation energy for the cationic AlQ3 hydrolysis pathway is found to be 8.5 kcal mol(-1) lower than for the neutral reaction, which is significant since it suggests a role for charge imbalance in promoting chemical failure modes in OLED devices.

  12. Orientation and temperature dependence of yield stress and slip geometry of Ti3Al and Ti3Al-V single crystals

    International Nuclear Information System (INIS)

    Umakoshi, Y.; Nakano, T.; Takenaka, T.; Sumimoto, K.; Yamane, T.

    1993-01-01

    Single crystals of binary Ti 3 Al and ternary Ti 3 Al-V alloys with the D0 19 structure were deformed in compression at 20-900 C. Slip systems of the (10 bar 10) -type and the (11 bar 21) -type were observed in these alloys throughout the entire temperature range depending on orientation, but the (11 bar 21) -slip was limited to orientations near [0001]. The basal (0001) -slip was also activated in quenched Ti 3 Al. The CRSS for the (10 bar 10) -slip in the binary and ternary alloys decreases monotonically with increasing temperature. In the ternary alloy the CRSS for the (10 bar 10) -slip shows a violation of Schmid's law, while the binary alloy obeys the CRSS law. When Ti 3 Al is deformed by (11 bar 21) -slip the CRSS for the slip exhibits an anomalous peak in the temperature-CRSS curve but the addition of vanadium suppresses the extent of the anomalous strengthening

  13. SELECCIÓN DE PREDICTORES AMBIENTALES PARA EL MODELADO DE LA DISTRIBUCIÓN DE ESPECIES EN MAXENT

    Directory of Open Access Journals (Sweden)

    Gustavo Cruz-Cárdenas

    2014-01-01

    Full Text Available A ntes de realizar el modelado de la distribución potencial de una especie, se recomienda ha - cer una preselección de covariables pues la redundancia o variables irrelevantes pueden in - ducir sesgos en la mayoría de los modelos. En este estudio, se propuso un método automati - zado para la selección a priori de covariables utilizadas en el modelado. Se emplearon cinco especies típicas de la flora mexicana ( Catopheria chiapensis, Liquidambar styraciflua, Quercus martinezii, Telanthopora grandifolia y Viburnum acutifolium y 56 covariables ambientales. Se generaron matrices de presencia-ausencia para cada especie y se analizaron empleando regresión logística; el modelo resul - tante de cada especie se evaluó mediante un remuestreo bootstrap. La distribución de las cinco especies se modeló usando el algoritmo de máxima entropía y con el empleo de tres conjuntos de covariables ambientales. La precisión de los modelos generados se evaluó con intervalos de confianza de cada curva característica operativa del receptor (COR. Los intervalos de confianza de las curvas COR resultantes no mostraron diferencia significativa ( P < 0.05 entre los tres modelos predictivos generados; sin em - bargo, el modelo más parsimonioso se obtuvo con el método propuesto.

  14. Interfacial phenomena in the reactions of Al-B, Al-Ti-B, and Al-Zr-B alloys with KF-AlF3 and NaF-AlF3 melts

    International Nuclear Information System (INIS)

    Lee, M.S.; Terry, B.S.; Grieveson, P.

    1993-01-01

    The interfacial phenomena occurring during the contacting of liquid Al-B, Al-Ti-B, and Al-Zr-B melts with KF-AlF 3 liquid fluxes have been investigated by optical examination of quenched metal drops previously immersed in the liquid fluxes. Reactions in the Al-B/KF-AlF 3 system involve the formation of metastable AlB 12 at the metal/flux interface. At high KBF 4 levels in the flux, the AlB 12 is dispersed in the flux and also at low KBF 4 levels in the metal. Reactions in the Al-Ti-B/KF-AlF 3 system involve the formation of TiB 2 , which may be dispersed in either the metal or the flux depending upon the composition of the flux. The results obtained for the Al-Ti-B/NaF-AlF 3 and Al-Zr-B/KF-AlF 3 systems were similar to those observed for the Al-Ti-B/KF-AlF 3 system

  15. Photoluminescence properties of the Eu-doped alpha-Al2O3 microspheres

    International Nuclear Information System (INIS)

    Liu, Dianguang; Zhu, Zhenfeng

    2014-01-01

    Highlights: • Al 2 O 3 :Eu 3+ phosphors were prepared via a microwave solvothermal route. • The particles were hierarchically nanostructured microspheres packaged by nanosheets. • The powders presented excellent orange–red emission when excited at 393 nm. • Critical concentration and distance of Eu 3+ in Al 2 O 3 is 0.007, 18 Å, respectively. -- Abstract: Al 2 O 3 :Eu 3+ samples were synthesized via microwave solvothermal method and thermal decomposition of Eu 3+ doped precursors. The sample characterizations were carried out by means of X-ray diffraction (XRD), scanning electron microscope (SEM) and photoluminescence (PL) spectra. XRD results indicated that Eu 3+ doped samples were most of α-Al 2 O 3 phase after being calcined at 1473 K. SEM results showed that the obtained α-Al 2 O 3 based powders via microwave solvothermal method were microspheres with an average diameter about 1.6 μm. PL spectra showed that upon excitation at 393 nm, the orange–red emission bands at the wavelength longer than 560 nm were from 5 D 0 → 7 F J (J = 1, 2) transitions. The asymmetry ratio of ( 5 D 0 → 7 F 2 )/( 5 D 0 → 7 F 1 ) intensity is about 1 and this value suggests that Eu 3+ ions occupy the same ratio of symmetry and asymmetry sites. It is shown that the 0.7 mol% of doping concentration of Eu 3+ ions in α-Al 2 O 3 :Eu 3+ is optimum. According to Dexter’s theory, the critical distance between Eu 3+ ions for energy transfer was determined to be 18 Å

  16. Synthesis of some (eta-arene)dihydridorhenium cations and their reactions with LiAlH/sub 4/ and LiAlD/sub 4/

    Energy Technology Data Exchange (ETDEWEB)

    Baudrey, D.; Boydell, P.; Ephritikhine, M.

    1986-03-01

    A series of cations (Re(eta-arene)H/sub 2/(PPh/sub 3/)/sub 2/)/sup +/ (arene benzene, toluene, p-xylene, or mesitylene) was prepared from the corresponding neutral dihydridocyclohexadienyl complexes by treatment with CPh/sub 3/BF/sub 4/. These cations reacted with LiAlH/sub 4/ and LiAlD/sub 4/ to form dihydridocyclohexadienyl complexes. The unusual selectivity of the hydride attack is explained by steric interactions between the ring methyl groups and the bulky phosphine ligands. The initial product of the reaction of the eta-mesitylene cation with LiAlD/sub 4/ allows the isomerisation mechanism for the cyclohexadienyl complexes to be clarified.

  17. Dynamic grain growth in superplastic Y-TZP and Al2O3/YTZ

    International Nuclear Information System (INIS)

    Nieh, T.G.; Tomasello, C.M.; Wadsworth, J.

    1990-01-01

    This paper reports that both static and dynamic grain growth have been studied during superplastic deformation of fine-grained yttria-stabilized tetragonal zirconia (Y-TZP) and alumina reinforced yttria-stabilized tetragonal zirconia (Al 2 O 3 /YTZ). Grain growth was observed in both materials at temperatures above 1350 degrees C. In the case of Y-TZP, both static and dynamic grain growth were found to obey a similar equation of the form: D 3 -D 0 3 = kt where D is the instantaneous grain size, D 0 is the initial grain size, t is the time, and k is a kinetic constant which depends primarily on temperature and grain boundary energy. The activation energies for Y-TZP were approximately 580 and 520 kJ/mol, for static and dynamic grain growth, respectively. In the case of Al 2 O 3 /YTZ, it was found that the grain growth rate for the Al 2 O 3 phase was slower than that for the ZrO 2 phase. The growth rate of the ZrO 2 phase in Al 2 O 3 /YTZ is, however, similar to that in monolithic ZrO 2 i.e., Y-TZP

  18. Orientation of Al3Ti platelets in Al-Al3Ti functionally graded material manufactured by centrifugal method

    International Nuclear Information System (INIS)

    Watanabe, Y.; Fukui, Y.

    1997-01-01

    Al-Al 3 Ti functionally graded materials (FGMs) were manufactured by the centrifugal method with a commercial ingot of Al-5 mass% Ti master alloy. The alloy was melted at a liquid/solid coexisting temperature, at which Al 3 Ti remains as a solid, and then it was cast into a thick-walled ring. It was found that the Al-Al 3 Ti functionally graded material can be successfully fabricated by the centrifugal method. It was also found that the volume fraction of the Al 3 Ti can be increased by repetition of the centrifugal method. Since the shape of Al 3 Ti particles in a commercial alloy ingot is that of a platelet, the Al 3 Ti particles are arranged with their platelet planes nearly perpendicular to the radial direction. The orientation effects become stronger when the G number becomes larger. Although the final centrifugal casting was conducted under a very large centrifugal force for the specimen cast three times, the orientation effects were weaker than those in the specimen cast one time. From these observations, it is concluded that the origin of orientation of Al 3 Ti platelets can be attributed to the angular velocity gradient of the melt along the radial direction produced by the difference in the viscosity. (orig.)

  19. Atomic-scale microstructures of Zr2Al3C4 and Zr3Al3C5 ceramics

    International Nuclear Information System (INIS)

    Lin, Z.J.; Zhuo, M.J.; He, L.F.; Zhou, Y.C.; Li, M.S.; Wang, J.Y.

    2006-01-01

    The microstructures of bulk Zr 2 Al 3 C 4 and Zr 3 Al 3 C 5 ceramics have been investigated using transmission electron microscopy and scanning transmission electron microscopy. These two carbides were determined to have a point group 6/mmm and a space group P6 3 /mmc using selected-area electron diffraction and convergent beam electron diffraction. The atomic-scale microstructures of Zr 2 Al 3 C 4 and Zr 3 Al 3 C 5 were investigated through high-resolution imaging and Z-contrast imaging. Furthermore, intergrowth between Zr 2 Al 3 C 4 and Zr 3 Al 3 C 5 was identified. Stacking faults in Zr 3 Al 3 C 5 were found to result from the insertion of an additional Zr-C layer. Cubic ZrC was occasionally identified to be incorporated in elongated Zr 3 Al 3 C 5 grains. In addition, Al may induce a twinned ZrC structure and lead to the formation of ternary zirconium aluminum carbides

  20. Abrupt symmetry decrease in the ThT{sub 2}Al{sub 20} alloys (T = 3d transition metal)

    Energy Technology Data Exchange (ETDEWEB)

    Uziel, A.; Bram, A.I. [Department of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva, 8410501 (Israel); Ilse Katz Institute for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Beer-Sheva, 8410501 (Israel); Venkert, A. [Nuclear Research Center-Negev, POB 9001, Beer-Sheva (Israel); Kiv, A.E.; Fuks, D. [Department of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva, 8410501 (Israel); Meshi, L., E-mail: louisa@bgu.ac.il [Department of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva, 8410501 (Israel); Ilse Katz Institute for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Beer-Sheva, 8410501 (Israel)

    2015-11-05

    Th-T-Al system, where T-3d transition metals, was studied at ThT{sub 2}Al{sub 20} stoichiometry to establish the influence of T on the structural stability of ternary aluminide formed. Different alloys were prepared, varying T in the row from Ti to Fe. Using electron microscopy and X-ray diffraction methods it was found that ThT{sub 2}Al{sub 20} phase adopts CeCr{sub 2}Al{sub 20} structure type when T = Ti, V, and Cr. Starting from Mn, the symmetry of the stable Al-rich phase, which forms in the alloys with the same composition, decreases from cubic to orthorhombic. The results of Density Functional Theory (DFT) calculations coincide with experiments. Concepts of the Theory of Coordination Compounds and Jahn–Teller effect were used to explain the observed abrupt change of the symmetry. These considerations were supported by DFT calculations. - Highlights: • Type of transition metal influences symmetry change in the ThT{sub 2}Al{sub 20} alloys. • It was found that cubic ThT{sub 2}Al{sub 20} phase is stable for T = Ti, V and Cr. • When T = Mn, Fe–Al + orthorhombic ThT{sub 2}Al{sub 10} are formed, lowering the symmetry. • Experimental results and DFT calculations were in full agreement. • TCC and of Jahn–Teller effect were used for explanation of the results.

  1. Microstructure of Al2O3 scales formed on NiCrAl alloys. Ph.D. Thesis - Case Western Reserve Univ.

    Science.gov (United States)

    Smialek, J. L.

    1981-01-01

    The structure of transient scales formed on pure and Y or Zr-doped Ni-15Cr-13Al alloys oxidized for 0.1 hr at 1100 C was studied by the use of transmission electron microscopy. Crystallographically oriented scales were found on all three alloys, but especially for the Zr-doped NiCrAl. The oriented scales consisted of alpha-(Al,Cr)2O3, Ni(Al,Cr)2O4 and gamma-Al2O3. They were often found in intimate contact with each other such that the close-packed planes and directions of one oxide phase were aligned with those of another. The prominent structural features of the oriented scales were approximately equal to micrometer subgrains; voids, antiphase domain boundaries and aligned precipitates were also prevalent. Randomly oriented alpha-Al2O3 was also found and was the only oxide ever observed at the immediate oxide metal interface. These approximately 0.15 micrometer grains were populated by intragranular voids which decreased in size and number towards the oxide metal interface. A sequence of oxidation was proposed in which the composition of the growing scale changed from oriented oxides rich in Ni and Cr to oriented oxides rich in Al. At the same time the structure changed from cubic spinels to hexagonal corundums with apparent precipitates of one phase in the matrix of the other. Eventually randomly oriented pure alpha-Al2O3 formed as the stable oxide with an abrupt transition: there was no gradual loss of orientation, no gradual compositional change or no gradual decrease in precipitate density.

  2. Calculation of Al2O3 contents in Al2O3-PTFE composite thick films fabricated by using the aerosol deposition

    International Nuclear Information System (INIS)

    Kim, Hyung-Jun; Kim, Yoon-Hyun; Nam, Song-Min; Yoon, Young-Joon; Kim, Jong-Hee

    2010-01-01

    Low-temperature fabrication of Al 2 O 3 -PTFE (poly tetra fluoro ethylene) composite thick films for flexible integrated substrates was attempted by using the aerosol deposition method. For optimization of composite thick films, a novel calculation method for the ceramic contents in the composites was attempted. Generally, a thermogravimetry (TG) analysis is used to calculate the ceramic contents in the ceramic-polymer composites. However, the TG analysis requires a long measurement time in each analysis, so we studied a novel calculation method that used a simple dielectric measurement. We used Hashin-Shtrikman bounds to obtain numerical results for the relationship between the dielectric constant of the composites and the contents of Al 2 O 3 . A 3-D electrostatic simulation model similar to the deposited Al 2 O 3 -PTFE composite thick films was prepared, and the simulation result was around the lower bound of the Hashin-Shtrikman bounds. As a result, we could calculate the Al 2 O 3 contents in the composites with a low error of below 5 vol.% from convenient dielectric measurements, and the Al 2 O 3 contents ranged from 51 vol.% to 54 vol.%.

  3. Thermoluminescence studies of γ-irradiated Al{sub 2}O{sub 3}:Ce{sup 3+} phosphor

    Energy Technology Data Exchange (ETDEWEB)

    Reddy, S. Satyanarayana [Physics R & D Center, PES Institute of Technology, BSK 3rd Stage, Bangalore 560085 (India); Nagabhushana, K.R., E-mail: bhushankr@gmail.com [Physics R & D Center, PES Institute of Technology, BSK 3rd Stage, Bangalore 560085 (India); Department of Physics, PES University, BSK 3rd Stage, Bangalore 560085 (India); Singh, Fouran [Inter University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110 067 (India)

    2016-07-15

    Pure and Ce{sup 3+} doped Al{sub 2}O{sub 3} phosphors were synthesized by solution combustion method. The synthesized samples were characterized by X-ray diffraction (XRD) and its shows α-phase of Al{sub 2}O{sub 3}. Crystallite size was estimated by Williamson–Hall (W–H) method and found to be 49, 59 and 84 nm for pure, 0.1 mol% and 1 mol% Ce{sup 3+} doped Al{sub 2}O{sub 3} respectively. Trace elemental analysis of undoped Al{sub 2}O{sub 3} shows impurities viz. Fe, Cr, Mn, Mg, Ti, etc. Photoluminescence (PL) spectra of Al{sub 2}O{sub 3}:Ce{sup 3+} shows emission at 367 nm and excitation peak at 273 nm, which are corresponding to {sup 5}D → {sup 4}F and {sup 4}F → {sup 5}D transitions respectively. PL intensity decreases with concentration up to 0.4 mol%, beyond this mol% PL intensity increases with doping concentration up to 2 mol%. Thermoluminescence (TL) studies of γ-rayed pure and Ce{sup 3+} doped Al{sub 2}O{sub 3} have been studied. Two well resolved TL glow peaks at 457.5 K and 622 K were observed in pure Al{sub 2}O{sub 3}. Additional glow peak at 566 K was observed in Al{sub 2}O{sub 3}:Ce{sup 3+}. Maximum TL intensity was observed for Al{sub 2}O{sub 3}:Ce{sup 3+} (0.1 mol%) beyond this TL intensity decreases with increasing Ce{sup 3+} concentration. Computerized glow curve deconvolution (CGCD) method was used to resolve the multiple peaks and to calculate TL kinetic parameters. Thermoluminescence emission (TLE) spectra of pure Al{sub 2}O{sub 3} glow peaks (457.5 K and 622 K) shows sharp emission at 694 nm and two small humps at 672 nm and 709 nm. The sharp peak at 696 nm corresponds to Cr{sup 3+} impurity of {sup 2}E{sub g} → {sup 4}A{sub 2g} transition of R lines and 713 nm hump is undoubtedly belongs to Cr{sup 3+} emission of near neighbor pairs. The emission at 672 nm is characteristic of Mn{sup 4+} impurity ions of {sup 2}E → {sup 4}A{sub 2} transition. TLE of Al{sub 2}O{sub 3}:Ce{sup 3+} (0.1 mol%) shows additional broad emission at 412 nm

  4. Ideal tensile strength of Ni3Al and Fe3Al with D03 structure

    Czech Academy of Sciences Publication Activity Database

    Legut, Dominik; Šob, Mojmír

    2008-01-01

    Roč. 567-568, - (2008), s. 77-80 ISSN 0255-5476. [MSMF /5./. Brno, 27.06.2007-29.06.2007] R&D Projects: GA ČR GA106/07/1078; GA AV ČR IAA1041302 Institutional research plan: CEZ:AV0Z20410507 Keywords : ideal tensile strength * intermetallics * DO3 structure * magnetism Subject RIV: BM - Solid Matter Physics ; Magnetism

  5. Single step synthesis of GdAlO3 powder

    International Nuclear Information System (INIS)

    Sinha, Amit; Nair, S.R.; Sinha, P.K.

    2011-01-01

    Research highlights: → First report on direct formation of GdAlO 3 powder using a novel combustion process. → Study of combustion characteristics of Gd(NO 3 ) 3 and Al(NO 3 ) 3 towards three fuels. → Preparation of highly sinterable GdAlO 3 powders through fuel-mixture approach. → Significant reduction in energy consumption for production of GdAlO 3 sintered body. - Abstract: A novel method for preparation of nano-crystalline gadolinium aluminate (GdAlO 3 ) powder, based on combustion synthesis, is reported. It was observed that aluminium nitrate and gadolinium nitrate exhibit different combustion characteristics with respect to urea, glycine and β-alanine. While urea was proven to be a suitable fuel for direct formation of crystalline α-Al 2 O 3 from its nitrate, glycine and β-alanine are suitable fuels for gadolinium nitrate for preparation of its oxide after combustion reaction. Based on the observed chemical characteristics of gadolinium and aluminium nitrates with respect to above mentioned fuels for the combustion reaction, the fuel mixture composition could be predicted that could lead to phase pure perovskite GdAlO 3 directly after the combustion reaction without any subsequent calcination step. The use of single fuel, on the other hand, leads to formation of amorphous precursor powders that call for subsequent calcination for the formation of crystalline GdAlO 3 . The powders produced directly after combustion reactions using fuel mixtures were found to be highly sinterable. The sintering of the powders at 1550 o C for 4 h resulted in GdAlO 3 with sintered density of more than 95%. T.D.

  6. A comparison of porosity analysis using 2D stereology estimates and 3D serial sectioning for additively manufactured Ti 6Al 2Sn 4Zr 2Mo alloy; Vergleich der Porositaetsanalyse einer Ti 6Al 2Sn 4Zr 2Mo-Legierung aus additiver Fertigung mittels stereologischer Schaetzungen (2D) und mit Serienschnitten (3D)

    Energy Technology Data Exchange (ETDEWEB)

    Ganti, Satya R.; Velez, Michael A.; Geier, Brian A.; Hayes, Brian J.; Turner, Bryan J.; Jenkins, Elizabeth J. [UES Inc., Dayton, OH (United States)

    2017-02-15

    Porosity is a typical defect in additively manufactured (AM) parts. Such defects limit the properties and performance of AM parts, and therefore need to be characterized accurately. Current methods for characterization of defects and microstructure rely on classical stereological methods that extrapolate information from two dimensional images. The automation of serial sectioning provides an opportunity to precisely and accurately quantify porosity in three dimensions in materials. In this work, we analyzed the porosity of an additively manufactured Ti 6Al 2Sn 4Zr 2Mo sample using Robo-Met.3D {sup registered}, an automated serial sectioning system. Image processing for three dimensional reconstruction of the serial-sectioned two dimensional images was performed using open source image analysis software (Fiji/ImageJ, Dream.3D, Paraview). The results from this 3D serial sectioning analysis were then compared to classical 2D stereological methods (Saltykov stereological theory). We found that for this dataset, the classical 2D methods underestimated the porosity size and distributions of the larger pores; a critical attribute to fatigue behavior of the AM part. The results suggest that acquiring experimental data with equipment such as Robo-Met.3D {sup registered} to measure the number and size of particles such as pores in a volume irrespective of knowing their shape is a better choice.

  7. Hiperparatiroidismo secundario al déficit de vitamina D

    OpenAIRE

    López-Ramiro, E.; Rubert, M.; Mahillo, I.; de la Piedra, C.

    2016-01-01

    Introducción: Cada vez está más demostrado el papel de la vitamina D en múltiples patologías, una de ellas el desarrollo de un hiperparatiroidismo secundario al déficit de vitamina D. Los métodos de laboratorio de cuantificación de vitamina D en suero no estaban bien estandarizados hasta ahora, por lo que no podía establecerse con certeza a partir de qué niveles de vitamina D se producían determinadas anomalías como la elevación de la PTH. Nuestro estudio pretende determinar por debajo de qué...

  8. Separation of reaction mechanisms at low energy. Study of the reactions: 27Al(d,p) 28Al, 24Mg(d,p) 25Mg, and 24Mg(d, α) 22Na

    International Nuclear Information System (INIS)

    Mermaz, M.

    1966-06-01

    The two sets of angular distributions of (d,p) reactions on Al and Mg, measured between 2 and 6 MeV, have given the possibility to test, in analysing the statistical fluctuations of cross-section, the validity of the separation of their mean values in two parts, one 'direct', another given by the statistical mechanism. With the same method of analysis we have studied excitation functions for several alpha groups of the reaction 24 Mg(d, α) 22 Na and given an evidence for an intermediate structure for the alpha channel leading to the 3. excited state of 22 Na. The angular distribution of the wide resonance at 15.9 MeV in 26 Al has been obtained. (author) [fr

  9. First-principles study of new quaternary Heusler compounds without 3d transition metal elements: ZrRhHfZ (Z = Al, Ga, In)

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xiaotian [School of Material Sciences and Engineering, Hebei University of Technology, Tianjin 300130 (China); Institute for Superconducting & Electronic Materials (ISEM), University of Wollongong, Wollongong 2500 (Australia); Cheng, Zhenxiang, E-mail: cheng@uow.edu.au [Institute for Superconducting & Electronic Materials (ISEM), University of Wollongong, Wollongong 2500 (Australia); Guo, Ruikang [School of Material Sciences and Engineering, Hebei University of Technology, Tianjin 300130 (China); Wang, Jianli [Institute for Superconducting & Electronic Materials (ISEM), University of Wollongong, Wollongong 2500 (Australia); Rozale, Habib [Condensed Matter and Sustainable Development Laboratory, Physics Department, University of Sidi-Bel-Abbès, 22000 Sidi-Bel-Abbès (Algeria); Wang, Liying [Department of Physics, Tianjin University, Tianjin 300350 (China); Yu, Zheyin [Institute for Superconducting & Electronic Materials (ISEM), University of Wollongong, Wollongong 2500 (Australia); Liu, Guodong, E-mail: gdliu1978@126.com [School of Material Sciences and Engineering, Hebei University of Technology, Tianjin 300130 (China)

    2017-06-01

    Plane-wave pseudo-potential methods based on density functional theory are employed to investigate the electronic structures, and the magnetic and half-metallic properties of the newly designed quaternary Heusler compounds ZrRhHfZ (Z = Al, Ga, In) without 3d transition metal elements. The calculated results show that ZrRhHfZ (Z = Al, Ga, In) compounds are half-metallic, with 100% spin polarization around the Fermi level. The structural stability of these compounds has been tested from the aspects of their cohesion energy and formation. The spin-flip/half-metallic gaps of ZrRhHfZ (Z = Al, Ga, In) compounds are quite large, with values of 0.2548 eV, 0.3483 eV, and 0.2866 eV, respectively. These compounds show Slater-Pauling behavior, and the total spin magnetic moment per unit cell (M{sub t}) scales with the total number of valence electrons (Z{sub t}) following the rule: M{sub t} = Z{sub t} - 18. The magnetization of ZrRhHfZ (Z = Al, Ga, In) compounds mainly comes from the 4d electrons of the Zr atoms and the 5d electrons of the Hf atoms. Furthermore, the effects of uniform strain and tetragonal deformation on the half metallicity has been investigated in detail, which is important for practical application. Finally, we reveal that the half-metallicity can be maintained when the Coulomb interactions are considered. - Highlights: • New quaternary compounds without 3d transition metal elements have been designed. • The electronic structures and magnetism of the ZrRhHfZ compounds have been studied. • The effect of strain on the half-metallic behavior has been tested. • The effect of the Coulomb interactions on the half-metallicity has been investigated.

  10. PARÁMETROS INERCIALES PARA EL MODELADO BIOMECÁNICO DEL CUERPO HUMANO

    Directory of Open Access Journals (Sweden)

    M. Gutiérrez

    2010-09-01

    Full Text Available

    RESUMEN

    El presente trabajo expone una visión general de los parámetros inerciales necesarios para el modelado biomecánico del cuerpo humano desde una perspectiva biomecánica, realizando un análisis retrospectivo, situación actual así como tendencias futuras en este ámbito. El modelado del cuerpo humano implica la determinación de una serie de puntos anatómicos y segmentos interconectados, que deben ser complementados con información inercial como es la masa segmentaria, el vector posición del centro de gravedad, los ejes de un sistema de referencia local segmentario, así como los momentos de inercia. La obtención de estos parámetros inerciales se considera imprescindible para el análisis biomecánico ya que permiten obtener algunas variables consideradas como básicas en cualquier análisis cuantitativo del movimiento, como son el centro de gravedad (CG tanto segmentario como corporal, el momento de inercia (I y el momento angular (H segmentario y corporal.
    PALABRAS CLAVE: Biomecánica, parámetros inerciales. .

     

    ABSTRACT

    This work gives a general view of the inertial parameters needed for the biomechanical modelling of the human body from the biomechanical point of view, making an analysis of the past, present situations and future tendencies in this subject. Human body modelling needs to determine several anatomical points and interconnected segments, which should be complemented with inertial information such as the segmentary mass, centre of gravity position vector, axes of the local segmentary reference system, and also the moments of inertia. The process of obtaining this inertial parameters is essential for biomechanical analysis since it enables us to obtain several basic variables needed in any quantitative analysis of movement, for example

  11. Synthesis of Al(OH3 Nanostructures from Al(OH3 Microagglomerates via Dissolution-Precipitation Route

    Directory of Open Access Journals (Sweden)

    Bo Yu

    2013-01-01

    Full Text Available A facile method was developed to synthesize Al(OH3 nanostructures from Al(OH3 microagglomerates by dissolution in 9.0 mol·L−1 NaOH at 115°C followed by dilution and aging of the solution at room temperature. The influence of Al(OH3 nanoseed and surfactants as sodium dodecyl sulfate (SDS, polyethylene glycol 6000 (PEG6000, and cetyltrimethylammonium bromide (CTAB on the formation of the Al(OH3 nano-structures was investigated. The experimental results indicated that the Al(OH3 microspheres composed of nanoparticles were prepared in the blank experiment, while dispersive Al(OH3 nano-particles with a diameter of 80–100 nm were produced in the presence of Al(OH3 nano-seed and CTAB.

  12. Dehydration of D-xylose over SiO2-Al2O3 catalyst: Perspective on the pathways for condensed products

    International Nuclear Information System (INIS)

    You, Su Jin; Park, Eun Duck; Park, Myung-June

    2016-01-01

    This work addresses the kinetic mechanism for the dehydration of D-xylose over the SiO 2 -Al 2 O 3 solid catalyst, where the formation of condensed products is included in addition to the production of furfural and its decomposition. The kinetic modeling and parametric sensitivity show that the isomerization of D-xylose takes place in the early stages of the reaction, followed by the dehydration of isomers. Accordingly, the homogeneous polymerization of isomers is found to be dominant. The developed model is used to evaluate the effects of operating conditions on the catalytic performance; high temperature and D-xylose concentration guarantee high furfural yield.

  13. Texturierung und Visualisierung virtueller 3D-Stadtmodelle

    OpenAIRE

    Lorenz, Haik

    2011-01-01

    Im Mittelpunkt dieser Arbeit stehen virtuelle 3D-Stadtmodelle, die Objekte, Phänomene und Prozesse in urbanen Räumen in digitaler Form repräsentieren. Sie haben sich zu einem Kernthema von Geoinformationssystemen entwickelt und bilden einen zentralen Bestandteil geovirtueller 3D-Welten. Virtuelle 3D-Stadtmodelle finden nicht nur Verwendung als Mittel für Experten in Bereichen wie Stadtplanung, Funknetzplanung, oder Lärmanalyse, sondern auch für allgemeine Nutzer, die realitätsnah dargestellte...

  14. Modelado de Control de Nivel en Molde para Vaciado Continuo de Palanquillas de Acero

    Directory of Open Access Journals (Sweden)

    Guillermo González Yero

    2014-01-01

    Full Text Available Resumen: Este trabajo presenta un modelo del sistema de control de nivel en molde de una máquina de vaciado continuo de palanquillas de acero. El objetivo fue realizar el modelado de cada elemento del sistema incluyendo las perturbaciones y transformaciones de la planta que más afectan la calidad del control. Se obtuvo y validó un modelo aproximado, utilizando leyes físicas, la identificación experimental mediante señales especiales e identificación paramétrica fuera de línea. En el modelo se incluyen de forma explícita los fenómenos de obstrucción y erosión en la válvula, que tienen una incidencia significativa en el funcionamiento de la planta. Para el servosistema hidráulico de la instalación se logró un modelo de caja gris que contribuye a un mejor entendimiento del comportamiento del proceso y a evaluar la incidencia de una implementación multifrecuencia bajo esquema convencional. Con el modelo obtenido es posible estudiar la operación del sistema a escala de simulación y la efectividad de soluciones de control avanzadas. El trabajo desarrollado es parte de un proceso de I+D que en el transcurso de más de 10 años ha contribuido a que en la acería donde se realiza la investigación, exista un sistema de control de nivel en molde que tiene impacto positivo sobre la calidad del acero producido. Abstract: This paper presents a model of system for the mould level control in a continuous casting machine for steel billets. The objective was to carry out the modeling of each element of the system including disturbances and transformations of the plant that affect the quality of control in the installation study object. It was obtained and validated an approximate model of the control system using physical laws governing the same one, experimental identification by special signals and parametric identification off- line. The model explicitly includes the phenomena of obstruction and erosion of the valve which have a

  15. Simulator sickness analysis of 3D video viewing on passive 3D TV

    Science.gov (United States)

    Brunnström, K.; Wang, K.; Andrén, B.

    2013-03-01

    The MPEG 3DV project is working on the next generation video encoding standard and in this process a call for proposal of encoding algorithms was issued. To evaluate these algorithm a large scale subjective test was performed involving Laboratories all over the world. For the participating Labs it was optional to administer a slightly modified Simulator Sickness Questionnaire (SSQ) from Kennedy et al (1993) before and after the test. Here we report the results from one Lab (Acreo) located in Sweden. The videos were shown on a 46 inch film pattern retarder 3D TV, where the viewers were using polarized passive eye-glasses to view the stereoscopic 3D video content. There were 68 viewers participating in this investigation in ages ranges from 16 to 72, with one third females. The questionnaire was filled in before and after the test, with a viewing time ranging between 30 min to about one and half hour, which is comparable to a feature length movie. The SSQ consists of 16 different symptoms that have been identified as important for indicating simulator sickness. When analyzing the individual symptoms it was found that Fatigue, Eye-strain, Difficulty Focusing and Difficulty Concentrating were significantly worse after than before. SSQ was also analyzed according to the model suggested by Kennedy et al (1993). All in all this investigation shows a statistically significant increase in symptoms after viewing 3D video especially related to visual or Oculomotor system.

  16. Diseño y desarrollo de productos mediante impresión 3D para su integración en prendas textiles destinadas al deporte

    OpenAIRE

    MONASTERIO DIES, JAVIER

    2018-01-01

    [ES] En el presente proyecto se realizará el desarrollo de un portocolo de trabajo que permita intergar y adaptar la impresion 3D a determinados textiles deportivos. Ello implicará el desarrollo de algunos productos especializados en el campo de ropa deportiva y se analizará como se puede adaptar la impresion de 3D, al flujo de trabajo de diseño y desarrollo de un producto. Se trabajará en la seleccion de materiales compatibles con el 3D y se adaptará y optimizará el diseño utilizando estas n...

  17. Characterization of Al2O3 surface passivation of silicon solar cells

    International Nuclear Information System (INIS)

    Albadri, Abdulrahman M.

    2014-01-01

    A study of the passivation of silicon surface by aluminum oxide (Al 2 O 3 ) is reported. A correlation of fixed oxide charge density (Q f ) and interface trap density (D it ) on passivation efficiency is presented. Low surface recombination velocity (SRV) was obtained even by as-deposited Al 2 O 3 films and this was found to be associated to the passivation of interface states. Fourier transfer infrared spectroscopy spectra show the existence of an interfacial silicon oxide thin layer in both as-deposited and annealed Al 2 O 3 films. Q f is found positive in as-deposited films and changing to negative upon subsequent annealing, providing thus an enhancement of the passivation in p-type silicon wafers, associated to field effects. Secondary ion mass spectrometry analysis confirms the correlation between D it and hydrogen concentration at the Al 2 O 3 /Si interface. A lowest SRV of 15 cm/s was obtained after an anneal at 400 °C in nitrogen atmosphere. - Highlights: • Al 2 O 3 provides superior passivation for silicon surfaces. • Atomic layer deposition-Al 2 O 3 was deposited at a low temperature of 200 °C. • A lowest surface passivation velocity of 15 cm/s was obtained after an anneal at 400 °C in nitrogen. • As-deposited Al 2 O 3 films form very thin SiO 2 layer responsible of low interface trap densities. • High negative fixed charge density of (− 2 × 10 12 cm −2 ) was achieved upon annealing at 400 °C

  18. Superstructure formation in PrNi_2Al_3 and ErPd_2Al_3

    International Nuclear Information System (INIS)

    Eustermann, Fabian; Hoffmann, Rolf-Dieter; Janka, Oliver; Oldenburg Univ.

    2017-01-01

    The intermetallic phase ErPd_2Al_3 was obtained by arc-melting of the elements and subsequent annealing for crystal growth. The sample was studied by X-ray diffraction on powders and single crystals. The structure of ErPd_2Al_3 was refined from X-ray diffraction data and revealed a superstructure of PrNi_2Al_3 - a CaCu_5 derivative (P6/m, a=1414.3(1), c=418.87(3) pm wR=0.0820, 1060 F"2 values, 48 variables). The same superstructure was subsequently found for PrNi_2Al_3 (P6/m, a=1407.87(4), c=406.19(2) pm, wR=0.0499, 904 F"2 values, 47 variables). In the crystal structure, the aluminium and transition metal atoms form a polyanionic network according to [T_2Al_3]"δ"-, while rare earth atoms fill cavities within the networks. They are coordinated by six transition metal and twelve aluminum atoms. In contrast to the PrNi_2Al_3 type structure reported so far, two crystallographic independent rare-earth sites are found of which one (1b) is shifted by 1/2 z, causing a distortion in the structure along with a recoloring of the T and Al atoms in the network.

  19. Comparative study of phase structure and dielectric properties for K0.5Bi0.5TiO3-BiAlO3 and LaAlO3-BiAlO3

    International Nuclear Information System (INIS)

    Hou, Yudong; Zheng, Mupeng; Si, Meiju; Cui, Lei; Zhu, Mankang; Yan, Hui

    2013-01-01

    In this work, two perovskite-type compounds, K 0.5 Bi 0.5 TiO 3 and LaAlO 3 , have been selected as host material to incorporate with BiAlO 3 using a solid-state reaction route. The phase evolution and dielectric properties for both systems have been investigated in detail. For the K 0.5 Bi 0.5 TiO 3 -BiAlO 3 system, it is interesting to find that when using Bi 2 O 3 , Al 2 O 3 , K 2 CO 3 , and TiO 2 as starting materials, the formed compounds are K 0.5 Bi 0.5 TiO 3 -K 0.5 Bi 4.5 Ti 4 O 15 and Al 2 O 3 only plays a dopant role. There are two distinct dielectric peaks appearing in the patterns of temperature dependence of dielectric constant, corresponding to the phase-transition points of perovskite-type K 0.5 Bi 0.5 TiO 3 and Aurivillius-type K 0.5 Bi 4.5 Ti 4 O 15 , independently. In comparison, using Bi 2 O 3 , Al 2 O 3 , and La 2 O 3 as starting materials, the pure perovskite phase LaAlO 3 -BiAlO 3 can be obtained. Compared to the inherent paraelectric behavior in LaAlO 3 , the diffuse phase-transition phenomena can be observed in the LaAlO 3 -BiAlO 3 binary system, which corresponds well to the Vogel-Fulcher (VF) relationship. Moreover, compared to pure LaAlO 3 , the synthesized LaAlO 3 -BiAlO 3 compound shows enhanced dielectric properties, which are promising in application as gate dielectric materials. (copyright 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  20. Spectral response of REE{sup 3+} doped LaAlO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Boronat, C.; Correcher, V. [CIEMAT, Av. Complutense 40, 28040 Madrid (Spain); Garcia G, J. [Museo Nacional de Ciencias Naturales - Consejo Superior de Investigaciones Cientificas, 28006 Madrid (Spain); Morales, A.; Zarate, J. [Universidad Michoacana de San Nicolas de Hidaldo, Instituto de Investigacion en Metalurgia y Materiales, Ciudad Universitaria, Morelia, Michoacan (Mexico); Rivera, T., E-mail: Cecilia.Boronat@ciemat.es [IPN, Ciudad de Mexico (Mexico)

    2016-10-15

    This paper reports on the preliminary results obtained from the cathodoluminescence (Cl) and thermoluminescence (Tl) properties of undoped LaAlO{sub 3} (LAO) and LaAlO{sub 3}: REE (REE=Dy{sup 3+}, Pr{sup 3+} and Eu{sup 3+}) to be potentially employed for dosimetric purposes. The samples were synthesized by a sol-gel process based on the Pechini 's method with a spray-drying technique and, subsequently, characterized by environmental scanning electron microscopy and energy dispersive X-ray analysis spectrometry. Cl spectra display sharp and narrow wavebands that could specifically be associated with structural (in the range of 300-450 nm) and point defects (from 450 to 800 nm). The observed wavebands could be assigned as follows: (i) 480 and 570 from the Dy-doped LAO should corresponding respectively to {sup 4}F{sub 9/2}→{sup 6}H{sub 15/2} and {sup 4}F{sub 9/2}→{sup 6}H{sub 13/2} transitions, (II) 490-638 from the Pr-doped LAO is linked to {sup 3}P{sub 0}→{sup 3}H{sub 4}, {sup 1}D{sub 2}→{sup 3}H{sub 4} transitions and (III) 590 and 620 where the dopant Eu{sup 3+} gives rise to {sup 5}D{sub 0}→{sup 7}F{sub 1} and {sup 5}D{sub 0}→{sup 7}F{sub 2} transitions and (IV) a UV-blue broad band is associated with NBOHC in undoped LAO. Such emissions are due to the presence of the 4f electrons of rare earth ions that are shielded by the outer 5s and 5p electrons, the intra-4f emission spectra of REE. Furthermore, the study performed on the Tl emission of LaAlO{sub 3}:Dy{sup 3+} displays (i) two maxima centred at 150 and 240 degrees Celsius (ratio 1:2) similarly to the Pr{sup 3+} doped sample but with 7:5 of ratio. And (II) the highest radiation sensitivity, allowing us to think on the potential use of this material for dosimetric purposes, however further works are necessary to confirm such assertion. (Author)

  1. Resonant photoelectron spectroscopy of γ-Al{sub 2}O{sub 3}/SrTiO{sub 3} heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Schuetz, Philipp; Pfaff, Florian; Zapf, Michael; Gabel, Judith; Dudy, Lenart; Berner, Goetz; Sing, Michael; Claessen, Ralph [Wuerzburg Univ. (Germany). Physikalisches Inst. and Roentgen Center for Complex Material Systems (RCCM); Chen, Yunzhong; Pryds, Nini [Technical Univ. of Denmark, Risoe (Denmark). Dept. of Energy Conversion and Storage; Rogalev, Victor; Strocov, Vladimir [Paul Scherrer Institut, Villigen (Switzerland). Swiss Light Source; Schlueter, Christoph; Lee, Tien-Lin [Diamond Light Source Ltd., Didcot (United Kingdom)

    2015-07-01

    The spinel/perovskite heterointerface between the band insulators γ-Al{sub 2}O{sub 3} and SrTiO{sub 3} hosts a two-dimensional electron system (2DES) with exceptionally high electron mobility. Soft X-ray resonant photoelectron spectroscopy at the Ti L absorption edge is used to probe the Ti 3d derived interface states. Marked differences in the resonance behavior are found for the SrTiO{sub 3} valence band and the different interface states, which are observed in the band gap of SrTiO{sub 3}. A comparison to X-ray absorption spectra of Ti 3d{sup 0} and Ti 3d{sup 1} systems reveals the presence of different types of electronic states with Ti 3d character, i.e., oxygen vacancy induced, trapped in-gap states and itinerant states contributing to the 2DES. Furthermore, exposure to low doses of oxygen during irradiation allows for the controlled and reversible manipulation of the interfacial electronic structure, i.e., the in-gap state intensity and the valence band offset between SrTiO{sub 3} and γ-Al{sub 2}O{sub 3}.

  2. Thermal stability of multilayered Pt-Al2O3 nanocoatings for high temperature CSP systems

    CSIR Research Space (South Africa)

    Nuru, ZY

    2015-10-01

    Full Text Available B), 115-120 Thermal stability of multilayered Pt-Al2O3 nanocoatings for high temperature CSP systems Z.Y. Nuru a, b, *, L. Kotsedi a, b, C.J. Arendse c, D. Motaung d, B. Mwakikunga d, K. Roro d, e, M. Maaza a, b a UNESCO-UNISA Africa Chair... Pretoria, South Africa e R&D Core-Energy, Council for Scientific and Industrial Research, P O Box 395, 0001 Pretoria, South Africa Abstract This contribution reports on the effect of thermal annealing on sputtered Pt–Al(sub2)O(sub3) multilayered...

  3. La teoría de los conjuntos-T aplicada al desarrollo de la competencia de modelado matemático

    Directory of Open Access Journals (Sweden)

    RICARDO JOAQUÍN DE ARMAS COSTA

    2016-06-01

    Full Text Available En este artículo queremos dar a conocer apartes de la teoría de los conjuntos-T y cómo se aplica en la educación superior para desarrollar la competencia de modelado matemático de los sujetos. Esta teoría surge como respuesta a los problemas de enseñanza aprendizaje de las matemáticas que se originan en los programas curriculares diseñados para adquirir exclusivamente información y no para desarrollar las competencias matemáticas de los estudiantes. The theory of the Conjuntos-T applied to the development of the competition of mathematical modeling In this article we want to present parts of the theory of joint-T and how it is applied in higher education to develop the competence of mathematical modeling subjects. We explain how the theory can develop the skills of students. This theory is a response to the problems of learning of mathematics that originate in the curriculum designed to acquire information and not only to develop the math skills of students. A teoria de Conjuntos-T aplicada ao desenvolvimento da concorrência  modelagem matemática Neste artigo, nos queremos apresentar algumas noções da teoria dos conjuntos-T e como ela é aplicada na docência, de ensino superior, para desenvolver a competência da modelagem matemática. Nos vamos explicar como a teoria pode desenvolver as habilidades dos alunos. Esta teoria é uma resposta para os problemas de ensino e aprendizagem da matemática que se originam nos programas curriculares destinados a adquirir somente informação e não para desenvolver as habilidades matemáticas dos alunos.

  4. Different magnetic behaviour of the Kondo compounds Al3Ce and Al11Ce3

    International Nuclear Information System (INIS)

    Benoit, A.; Flouquet, J.; Palleau, J.; Buevoz, J.L.

    1979-08-01

    Neutron diffraction experiments on the Al 3 Ce and Al 11 Ce 3 compounds have been performed on the multidetector of the I.L.L. high flux reactor. No magnetic structure has been detected on the Al 3 Ce compound down to 20 mK. This confirms the non magnetic ground state of Al 3 Ce. For Al 11 Ce 3 , two magnetic structures have been observed: a ferromagnetic one at 4.2 K and an antiferromagnetic one at 2 K. The antiferromagnetic structure, which corresponds to a propagation vector (0,0,1/3), implies a strong reduction of the magnetic moment of determined sites; this reflects the Kondo character of the compounds

  5. Coronary arteries segmentation based on the 3D discrete wavelet transform and 3D neutrosophic transform.

    Science.gov (United States)

    Chen, Shuo-Tsung; Wang, Tzung-Dau; Lee, Wen-Jeng; Huang, Tsai-Wei; Hung, Pei-Kai; Wei, Cheng-Yu; Chen, Chung-Ming; Kung, Woon-Man

    2015-01-01

    Most applications in the field of medical image processing require precise estimation. To improve the accuracy of segmentation, this study aimed to propose a novel segmentation method for coronary arteries to allow for the automatic and accurate detection of coronary pathologies. The proposed segmentation method included 2 parts. First, 3D region growing was applied to give the initial segmentation of coronary arteries. Next, the location of vessel information, HHH subband coefficients of the 3D DWT, was detected by the proposed vessel-texture discrimination algorithm. Based on the initial segmentation, 3D DWT integrated with the 3D neutrosophic transformation could accurately detect the coronary arteries. Each subbranch of the segmented coronary arteries was segmented correctly by the proposed method. The obtained results are compared with those ground truth values obtained from the commercial software from GE Healthcare and the level-set method proposed by Yang et al., 2007. Results indicate that the proposed method is better in terms of efficiency analyzed. Based on the initial segmentation of coronary arteries obtained from 3D region growing, one-level 3D DWT and 3D neutrosophic transformation can be applied to detect coronary pathologies accurately.

  6. The effects of boron in TiAl/Ti3Al

    International Nuclear Information System (INIS)

    Feng, C.R.; Michel, D.J.; Crowe, C.R.

    1989-01-01

    The authors discuss the TiAl/Ti 3 Al interfacial misfit dislocations structures investigated by TEM in Ti-45Al alloy and Ti-45Al/TiB 2 composite. For TiAl with c/a = 1.02, only a single set of misfit dislocation arrays are crystallographically possible; these were observed in Ti-45Al alloy. However, the observation of three sets of misfit dislocation arrays in the Ti-45Al/TiB 2 composite suggests that the occupation of octahedral sites in the TiAl structure by excess boron was responsible for a decrease in the c/a ratio leading to an increased fcc character of the TiAl at the TiAl/Ti 3 Al interface

  7. Valence and conduction band offsets of β-Ga2O3/AlN heterojunction

    Science.gov (United States)

    Sun, Haiding; Torres Castanedo, C. G.; Liu, Kaikai; Li, Kuang-Hui; Guo, Wenzhe; Lin, Ronghui; Liu, Xinwei; Li, Jingtao; Li, Xiaohang

    2017-10-01

    Both β-Ga2O3 and wurtzite AlN have wide bandgaps of 4.5-4.9 and 6.1 eV, respectively. We calculated the in-plane lattice mismatch between the (-201) plane of β-Ga2O3 and the (0002) plane of AlN, which was found to be 2.4%. This is the smallest mismatch between β-Ga2O3 and binary III-nitrides which is beneficial for the formation of a high quality β-Ga2O3/AlN heterojunction. However, the valence and conduction band offsets (VBO and CBO) at the β-Ga2O3/AlN heterojunction have not yet been identified. In this study, a very thin (less than 2 nm) β-Ga2O3 layer was deposited on an AlN/sapphire template to form the heterojunction by pulsed laser deposition. High-resolution X-ray photoelectron spectroscopy revealed the core-level (CL) binding energies of Ga 3d and Al 2p with respect to the valence band maximum in individual β-Ga2O3 and AlN layers, respectively. The separation between Ga 3d and Al 2p CLs at the β-Ga2O3/AlN interface was also measured. Eventually, the VBO was found to be -0.55 ± 0.05 eV. Consequently, a staggered-gap (type II) heterojunction with a CBO of -1.75 ± 0.05 eV was determined. The identification of the band alignment of the β-Ga2O3/AlN heterojunction could facilitate the design of optical and electronic devices based on these and related alloys.

  8. Photoluminescence properties of the Eu-doped alpha-Al{sub 2}O{sub 3} microspheres

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Dianguang, E-mail: dianguang12@gmail.com [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, West Youyi Rd., No. 127, Xi’an, Shaanxi 710072 (China); Science and Technology on Thermostructure Composite Materials Laboratory, Northwestern Polytechnical University, West Youyi Rd., No. 127, Xi’an, Shaanxi 710072 (China); Zhu, Zhenfeng [School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi’an 710021 (China)

    2014-01-15

    Highlights: • Al{sub 2}O{sub 3}:Eu{sup 3+} phosphors were prepared via a microwave solvothermal route. • The particles were hierarchically nanostructured microspheres packaged by nanosheets. • The powders presented excellent orange–red emission when excited at 393 nm. • Critical concentration and distance of Eu{sup 3+} in Al{sub 2}O{sub 3} is 0.007, 18 Å, respectively. -- Abstract: Al{sub 2}O{sub 3}:Eu{sup 3+} samples were synthesized via microwave solvothermal method and thermal decomposition of Eu{sup 3+} doped precursors. The sample characterizations were carried out by means of X-ray diffraction (XRD), scanning electron microscope (SEM) and photoluminescence (PL) spectra. XRD results indicated that Eu{sup 3+} doped samples were most of α-Al{sub 2}O{sub 3} phase after being calcined at 1473 K. SEM results showed that the obtained α-Al{sub 2}O{sub 3} based powders via microwave solvothermal method were microspheres with an average diameter about 1.6 μm. PL spectra showed that upon excitation at 393 nm, the orange–red emission bands at the wavelength longer than 560 nm were from {sup 5}D{sub 0} → {sup 7}F{sub J} (J = 1, 2) transitions. The asymmetry ratio of ({sup 5}D{sub 0} → {sup 7}F{sub 2})/({sup 5}D{sub 0} → {sup 7}F{sub 1}) intensity is about 1 and this value suggests that Eu{sup 3+} ions occupy the same ratio of symmetry and asymmetry sites. It is shown that the 0.7 mol% of doping concentration of Eu{sup 3+} ions in α-Al{sub 2}O{sub 3}:Eu{sup 3+} is optimum. According to Dexter’s theory, the critical distance between Eu{sup 3+} ions for energy transfer was determined to be 18 Å.

  9. Magnetic field effects in UNi.sub.1/3./sub.Ru.sub.2/3./sub.Al

    Czech Academy of Sciences Publication Activity Database

    Alsmadi, A. M.; El-Khatib, S.; de Chatel, P.F.; Nakotte, H.; Lacerda, A. H.; Jung, M. H.; Andreev, Alexander V.; Honda, F.; Sechovský, V.

    2005-01-01

    Roč. 97, - (2005), 10A919/1-10A919/3 ISSN 0021-8979 R&D Projects: GA ČR(CZ) GA202/02/0739 Keywords : UNi 1/3 Ru 2/3 Al * magnetic field effects Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.498, year: 2005

  10. Metal oxide multilayer hard mask system for 3D nanofabrication

    Science.gov (United States)

    Han, Zhongmei; Salmi, Emma; Vehkamäki, Marko; Leskelä, Markku; Ritala, Mikko

    2018-02-01

    We demonstrate the preparation and exploitation of multilayer metal oxide hard masks for lithography and 3D nanofabrication. Atomic layer deposition (ALD) and focused ion beam (FIB) technologies are applied for mask deposition and mask patterning, respectively. A combination of ALD and FIB was used and a patterning procedure was developed to avoid the ion beam defects commonly met when using FIB alone for microfabrication. ALD grown Al2O3/Ta2O5/Al2O3 thin film stacks were FIB milled with 30 keV gallium ions and chemically etched in 5% tetramethylammonium hydroxide at 50 °C. With metal evaporation, multilayers consisting of amorphous oxides Al2O3 and Ta2O5 can be tailored for use in 2D lift-off processing, in preparation of embedded sub-100 nm metal lines and for multilevel electrical contacts. Good pattern transfer was achieved by lift-off process from the 2D hard mask for micro- and nano-scaled fabrication. As a demonstration of the applicability of this method to 3D structures, self-supporting 3D Ta2O5 masks were made from a film stack on gold particles. Finally, thin film resistors were fabricated by utilizing controlled stiction of suspended Ta2O5 structures.

  11. Comparative Review of Abu al-Tayyib al-Mutanabbi’s & Masu’d Sa’d Salman Odes

    Directory of Open Access Journals (Sweden)

    f Ishraqi

    2014-11-01

    This survey reviews similar contents of the two Divan using comparative aspect in Abu al-Tayyib and Masu’d Sa’d-i Salman’s poems. Several exemplifications show that Masu’d Sa’d-i Salman sometimes translated al-mutanbbi’s poets and used them artily. Sometimes however, we can find identical contents originating from connotation between the two poets, so they should not be considered as adoption or translation.

  12. Photo- and radio-excited luminescence properties of Eu-doped La2O3Al2O3 based eutectics

    International Nuclear Information System (INIS)

    Fujimoto, Yutaka; Kamada, Kei; Yanagida, Takayuki; Wakahara, Shingo; Suzuki, Shotaro; Kurosawa, Shunsuke; Yoshikawa, Akira

    2013-01-01

    Eutectic crystal of 0.5% Eu-doped 30LaAlO 3 –70Al 2 O 3 (vol %) was prepared by micro-pulling down (μ-PD) technique under nitrogen atmosphere. Being excited at a wavelength of 320 nm, the crystal exhibited intense emission band with a maximum at 450 nm which is corresponding to 4f 6 5d-4f 7 ( 8 S 7/2 ) transitions of Eu 2+ . The decay time and fluorescence quantum efficiency (QE) were determined to be about 475 ns and 60%, respectively. When alpha-ray excited the crystal, both Eu 2+ 4f 6 5d-4f 7 ( 8 S 7/2 ) and Eu 3+ 4f 6 -4f 6 ( 5 D 0 - 7 F 1,2 ) emission peaks were observed at 435 nm and 600 nm. By the pulse height spectra, the relative scintillation light yield of the crystal was about 4% compared with that of BGO commercial scintillator. -- Highlights: •0.5% Eu-doped 30LaAlO 3 –70Al 2 O 3 eutectic crystal was grown by μ-PD technique. •The crystal showed intense Eu 2+ 5d-4f emission at 450 nm under excited at 320 nm. •The fluorescence quantum efficiency was calculated to be about 60%. •The scintillation light yield was about 4% compared with that of BGO scintillator

  13. Electrodeposition of Al from a 1-butylpyrrolidine-AlCl3 ionic liquid

    Directory of Open Access Journals (Sweden)

    Giridhar Pulletikurthi

    2015-12-01

    Full Text Available The addition of 1-butylpyrrolidine to AlCl3 results in the formation of an electrolyte that is suited to Al deposition. The feasibility of electrodepositing Al from the synthesized electrolyte was investigated. Several compositions of AlCl3 and 1-butylpyrrolidine were prepared for this purpose. These mixtures show a different phase behavior at various compositions of AlCl3 and 1-butylpyrrolidine. IR, Raman and NMR spectroscopy were employed to characterize the synthesized liquids. Among the prepared compositions, 1:1.2 mol ratio of 1-butylpyrrolidine:AlCl3 and the upper phase of 1:1.3 mol ratio of 1-butylpyrrolidine:AlCl3 were found to be suitable for Al electrodeposition at room temperature (RT. Uniform and thick (~µm thick layers of Al were obtained on copper at RT. Al deposition occured from the cationic species of AlCl3−xLy+ (where x≤2, y=1–2, and L=1-butylpyrrolidine in this electrolyte. This behavior is contrary to the well investigated classic AlCl3 based ionic liquids, where the deposition of Al occurs mainly from anionic Al2Cl7− ions.

  14. Octahedral rotations in strained LaAlO3/SrTiO3 (001 heterostructures

    Directory of Open Access Journals (Sweden)

    T. T. Fister

    2014-02-01

    Full Text Available Many complex oxides display an array of structural instabilities often tied to altered electronic behavior. For oxide heterostructures, several different interfacial effects can dramatically change the nature of these instabilities. Here, we investigate LaAlO3/SrTiO3 (001 heterostructures using synchrotron x-ray scattering. We find that when cooling from high temperature, LaAlO3 transforms from the Pm3¯m to the Imma phase due to strain. Furthermore, the first 4 unit cells of the film adjacent to the substrate exhibit a gradient in rotation angle that can couple with polar displacements in films thinner than that necessary for 2D electron gas formation.

  15. Synthesizing (ZrAl3 + AlN)/Mg-Al composites by a 'matrix exchange' method

    Science.gov (United States)

    Gao, Tong; Li, Zengqiang; Hu, Kaiqi; Han, Mengxia; Liu, Xiangfa

    2018-06-01

    A method named 'matrix exchange' to synthesize ZrAl3 and AlN reinforced Mg-Al composite was developed in this paper. By inserting Al-10ZrN master alloy into Mg matrix and reheating the cooled ingot to 550 °C, Al and Mg atoms diffuse to the opposite side. As a result, liquid melt occurs once the interface areas reach to proper compositions. Then dissolved Al atoms react with ZrN, leading to the in-situ formation of ZrAl3 and AlN particles, while the Al matrix is finally replaced by Mg. This study provides a new insight for preparing Mg composites.

  16. Bulk-compositional changes of Ni2Al3 and NiAl3 during ion etching

    International Nuclear Information System (INIS)

    Chen Houwen; Wang Rong

    2008-01-01

    Bulk-compositional changes of Ni 2 Al 3 and NiAl 3 in a Ni-50 wt% Al alloy during ion etching have been investigated by transmission electron microscopy and energy dispersive X-ray spectroscopic analyses. After etching with 7, 5 and 3 keV Ar + ions for 15, 24 and 100 h nickel contents in both Ni 2 Al 3 and NiAl 3 exceeded greatly those in the initial compounds and increased with the decrement of the sputtering energy. After 100 h etching with 3 keV Ar + ions the compositions of these two compounds reached a similar value, about Ni 80-83 Al 12-15 Fe 3-4 Cr 1-2 (at%). A synergistic action of preferential sputtering, radiation-induced segregation and radiation-enhanced diffusion enables the altered-layers at the top and bottom of the film extend through the whole film. The bulk-compositional changes are proposed to occur in the unsteady-state sputtering regime of ion etching and caused by an insufficient supply of matter in a thin film

  17. Valence and conduction band offsets of β-Ga2O3/AlN heterojunction

    KAUST Repository

    Sun, Haiding

    2017-10-16

    Both β-Ga2O3 and wurtzite AlN have wide bandgaps of 4.5–4.9 and 6.1 eV, respectively. We calculated the in-plane lattice mismatch between the (−201) plane of β-Ga2O3 and the (0002) plane of AlN, which was found to be 2.4%. This is the smallest mismatch between β-Ga2O3 and binary III-nitrides which is beneficial for the formation of a high quality β-Ga2O3/AlN heterojunction. However, the valence and conduction band offsets (VBO and CBO) at the β-Ga2O3/AlN heterojunction have not yet been identified. In this study, a very thin (less than 2 nm) β-Ga2O3 layer was deposited on an AlN/sapphire template to form the heterojunction by pulsed laser deposition. High-resolution X-ray photoelectron spectroscopy revealed the core-level (CL) binding energies of Ga 3d and Al 2p with respect to the valence band maximum in individual β-Ga2O3 and AlN layers, respectively. The separation between Ga 3d and Al 2p CLs at the β-Ga2O3/AlN interface was also measured. Eventually, the VBO was found to be −0.55 ± 0.05 eV. Consequently, a staggered-gap (type II) heterojunction with a CBO of −1.75 ± 0.05 eV was determined. The identification of the band alignment of the β-Ga2O3/AlN heterojunction could facilitate the design of optical and electronic devices based on these and related alloys.

  18. Investigation on the neutron beam characteristics for boron neutron capture therapy with 3D and 2D transport calculations

    International Nuclear Information System (INIS)

    Kodeli, I.; Diop, C.M.; Nimal, J.C.

    1994-01-01

    In the framework of future Boron Neutron Capture Therapy (BNCT) experiments, where cells and animals irradiations are planned at the research reactor of Strasbourg University, the feasibility to obtain a suitable epithermal neutron beam is investigated. The neutron fluence and spectra calculations in the reactor are performed using the 3D Monte Carlo code TRIPOLI-3 and the 2D SN code TWODANT. The preliminary analysis of Al 2 O 3 and Al-Al 2 O 3 filters configurations are carried out in an attempt to optimize the flux characteristics in the beam tube facility. 7 figs., 7 refs

  19. Microstructure and Properties of Fe3Al-Fe3AlC x Composite Prepared by Reactive Liquid Processing

    Science.gov (United States)

    Verona, Maria Nalu; Setti, Dalmarino; Paredes, Ramón Sigifredo Cortés

    2018-04-01

    A Fe3Al-Fe3AlC x composite was prepared using reactive liquid processing (RLP) through controlled mixture of carbon steel and aluminum in the liquid state. The microstructure and phases of the composite were assessed using X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, optical microscopy, and differential scanning calorimetry. In addition, the density, hardness, microhardness, and elastic modulus were evaluated. The Fe3Al-Fe3AlC x composite consisted of 65 vol pct Fe3Al and 35 vol pct Fe3AlC x ( κ). The κ phase contained 10.62 at. pct C, resulting in the stoichiometry Fe3AlC0.475. The elastic modulus of the Fe3Al-Fe3AlC0.475 composite followed the rule of mixtures. The RLP technique was shown to be capable of producing Fe3Al-Fe3AlC0.475 with a microstructure and properties similar to those achieved using other processing techniques reported in the literature.

  20. Coronary Arteries Segmentation Based on the 3D Discrete Wavelet Transform and 3D Neutrosophic Transform

    Directory of Open Access Journals (Sweden)

    Shuo-Tsung Chen

    2015-01-01

    Full Text Available Purpose. Most applications in the field of medical image processing require precise estimation. To improve the accuracy of segmentation, this study aimed to propose a novel segmentation method for coronary arteries to allow for the automatic and accurate detection of coronary pathologies. Methods. The proposed segmentation method included 2 parts. First, 3D region growing was applied to give the initial segmentation of coronary arteries. Next, the location of vessel information, HHH subband coefficients of the 3D DWT, was detected by the proposed vessel-texture discrimination algorithm. Based on the initial segmentation, 3D DWT integrated with the 3D neutrosophic transformation could accurately detect the coronary arteries. Results. Each subbranch of the segmented coronary arteries was segmented correctly by the proposed method. The obtained results are compared with those ground truth values obtained from the commercial software from GE Healthcare and the level-set method proposed by Yang et al., 2007. Results indicate that the proposed method is better in terms of efficiency analyzed. Conclusion. Based on the initial segmentation of coronary arteries obtained from 3D region growing, one-level 3D DWT and 3D neutrosophic transformation can be applied to detect coronary pathologies accurately.

  1. Modelado numérico del comportamiento de los vertidos de hidrocarburos vertidos al mar

    OpenAIRE

    Siguero Güemes, Augusto

    2010-01-01

    En el informe de esta tesina se aborda la problemática de la contaminación marina de los hidrocarburos asociada al transporte marítimo. El gran impacto mediático que suscitaron los grandes accidentes sucedidos en pasado reciente como es el caso del Prestige o que lo están haciendo actualmente en el golfo de México debido al accidente de la plataforma petrolífera de la compañía British Petroleum (BP) generan controversia en la sociedad justificada por las consecuencias socio-económicas y medio...

  2. A comparison of porosity analysis using 2D stereology estimates and 3D serial sectioning for additively manufactured Ti 6Al 2Sn 4Zr 2Mo alloy

    International Nuclear Information System (INIS)

    Ganti, Satya R.; Velez, Michael A.; Geier, Brian A.; Hayes, Brian J.; Turner, Bryan J.; Jenkins, Elizabeth J.

    2017-01-01

    Porosity is a typical defect in additively manufactured (AM) parts. Such defects limit the properties and performance of AM parts, and therefore need to be characterized accurately. Current methods for characterization of defects and microstructure rely on classical stereological methods that extrapolate information from two dimensional images. The automation of serial sectioning provides an opportunity to precisely and accurately quantify porosity in three dimensions in materials. In this work, we analyzed the porosity of an additively manufactured Ti 6Al 2Sn 4Zr 2Mo sample using Robo-Met.3D "r"e"g"i"s"t"e"r"e"d, an automated serial sectioning system. Image processing for three dimensional reconstruction of the serial-sectioned two dimensional images was performed using open source image analysis software (Fiji/ImageJ, Dream.3D, Paraview). The results from this 3D serial sectioning analysis were then compared to classical 2D stereological methods (Saltykov stereological theory). We found that for this dataset, the classical 2D methods underestimated the porosity size and distributions of the larger pores; a critical attribute to fatigue behavior of the AM part. The results suggest that acquiring experimental data with equipment such as Robo-Met.3D "r"e"g"i"s"t"e"r"e"d to measure the number and size of particles such as pores in a volume irrespective of knowing their shape is a better choice.

  3. Modelado de vehículos eléctricos

    OpenAIRE

    Peña Mariano, Carlos Alejandro

    2011-01-01

    En aquest projecte s'estudiaran les diverses tipologies de vehicles elèctrics, els quals estan tenint cada vegada més una major importancia al mercat automobilístic. Es modelaran els components elèctrics i mecànics d'un vehicle elèctric utilitzant la representació energètica macroscòpica (REM) per observar el seu comportament a nivell energètic. Finalment aquest model s'implementarà al programa informàtic Matlab®, per obtenir els resultats i la seva posterior anàlisi.

  4. Implementation of a 3D printer into a small business

    OpenAIRE

    Kodejšová, Jana

    2017-01-01

    This thesis deals with the implementation of a 3D printer into a small business. The theoret-ical part deals with technology of 3D printing, types of 3D printers, as well as basic materi-als suitable for 3D printing. The practical part is devoted to the purchasing of a 3D printer for this company that deals with the service and the supply of bicycles and other cycling needs. There is chosen the most suitable 3D printer for this business, and there are also ex-amples of specific parts that thi...

  5. Fracture toughness of Ti-Al3Ti-Al-Al3Ti laminate composites under static and cyclic loading conditions

    Science.gov (United States)

    Patselov, A. M.; Gladkovskii, S. V.; Lavrikov, R. D.; Kamantsev, I. S.

    2015-10-01

    The static and cyclic fracture toughnesses of a Ti-Al3Ti-Al-Al3Ti laminate composite material containing at most 15 vol % intermetallic compound are studied. Composite specimens are prepared by terminating reaction sintering of titanium and aluminum foils under pressure. The fracture of the titanium layers is quasi-cleavage during cyclic crack growth and is ductile during subsequent static loading.

  6. Bulk Synthesis and Characterization of Ti3Al Nanoparticles by Flow-Levitation Method

    Directory of Open Access Journals (Sweden)

    Shanjun Chen

    2013-01-01

    Full Text Available A novel bulk synthesis method for preparing high pure Ti3Al nanoparticles was developed by flow-levitation method (FL. The Ti and Al vapours ascending from the high temperature levitated droplet were condensed by cryogenic Ar gas under atmospheric pressure. The morphology, crystalline structure, and chemical composition of Ti3Al nanoparticles were, respectively, investigated by transmission electron microscopy, X-ray diffraction, and inductively coupled plasma atomic emission spectrometry. The results indicated that the Ti3Al powders are nearly spherical-shaped, and the particle size ranges from several nanometers to 100 nm in diameter. Measurements of the d-spacing from X-ray (XRD and electron diffraction studies confirmed that the Ti3Al nanoparticles have a hexagonal structure. A thin oxidation coating of 2-3 nm in thickness was formed around the particles after exposure to air. Based on the XPS measurements, the surface coating of the Ti3Al nanoparticles is a mixture of Al2O3 and TiO2. The production rate of Ti3Al nanoparticles was estimated to be about 3 g/h. This method has a great potential in mass production of Ti3Al nanoparticles.

  7. Narrow in-gap states in doped Al2O3

    KAUST Repository

    Casas-Cabanas, Montse; Fré sard, Marion; Lü ders, Ulrike; Fré sard, Raymond; Schuster, Cosima B.; Schwingenschlö gl, Udo

    2011-01-01

    Based on XRD data testifying that the M ions occupy substitutional sites, transmittance measurement are discussed in comparison to electronic structure calculations for M-doped Al2O3 with M = V, Mn, and Cr. The M 3d states are found approximatively 2 eV above the top of the host valence band. The fundamental band gap of Al2O3 is further reduced in the V and Mn cases due to a splitting of the narrow band at the Fermi energy. Nevertheless the measured transmittance in the visible range remains high in all three cases. © 2011 Elsevier B.V. All rights reserved.

  8. Narrow in-gap states in doped Al2O3

    KAUST Repository

    Casas-Cabanas, Montse

    2011-10-01

    Based on XRD data testifying that the M ions occupy substitutional sites, transmittance measurement are discussed in comparison to electronic structure calculations for M-doped Al2O3 with M = V, Mn, and Cr. The M 3d states are found approximatively 2 eV above the top of the host valence band. The fundamental band gap of Al2O3 is further reduced in the V and Mn cases due to a splitting of the narrow band at the Fermi energy. Nevertheless the measured transmittance in the visible range remains high in all three cases. © 2011 Elsevier B.V. All rights reserved.

  9. Phase constituents and microstructure of laser cladding Al2O3/Ti3Al reinforced ceramic layer on titanium alloy

    International Nuclear Information System (INIS)

    Li Jianing; Chen Chuanzhong; Lin Zhaoqing; Squartini, Tiziano

    2011-01-01

    Research highlights: → In this study, Fe 3 Al has been chosen as cladding powder due to its excellent properties of wear resistance and high strength, etc. → Laser cladding of Fe 3 Al + TiB 2 /Al 2 O 3 pre-placed alloy powder on Ti-6Al-4V alloy substrate can form the Ti 3 Al/Fe 3 Al + TiB 2 /Al 2 O 3 ceramic layer, which can increase wear resistance of substrate. → In cladding process, Al 2 O 3 can react with TiB 2 leading to formation of Ti 3 Al and B. → This principle can be used to improve the Fe 3 Al + TiB 2 laser-cladded coating. - Abstract: Laser cladding of the Fe 3 Al + TiB 2 /Al 2 O 3 pre-placed alloy powder on Ti-6Al-4V alloy can form the Ti 3 Al/Fe 3 Al + TiB 2 /Al 2 O 3 ceramic layer, which can greatly increase wear resistance of titanium alloy. In this study, the Ti 3 Al/Fe 3 Al + TiB 2 /Al 2 O 3 ceramic layer has been researched by means of electron probe, X-ray diffraction, scanning electron microscope and micro-analyzer. In cladding process, Al 2 O 3 can react with TiB 2 leading to formation of amount of Ti 3 Al and B. This principle can be used to improve the Fe 3 Al + TiB 2 laser cladded coating, it was found that with addition of Al 2 O 3 , the microstructure performance and micro-hardness of the coating was obviously improved due to the action of the Al-Ti-B system and hard phases.

  10. 3D, chemical and electrochemical characterization of blasted TI6Al4V surfaces: Its influence on the corrosion behaviour

    International Nuclear Information System (INIS)

    Barranco, V.; Escudero, M.L.; Garcia-Alonso, M.C.

    2007-01-01

    The blasting process to increase the roughness of the surface of metallic biomaterials is widely used. As a consequence, one can produce a renewed surface with different topography and chemical composition compared to the original one, which can alter the general corrosion behaviour of the samples. With this idea, the aim of this work is not only the topographical and compositional characterization of blasted surfaces of Ti6Al4V alloy but mainly its influence on the corrosion behaviour of these modified surfaces. The surfaces of Ti6Al4V alloys were blasted with SiO 2 /ZrO 2 and Al 2 O 3 particles of different size in order to obtain different roughnesses. To carry out the microstructural and topographical characterization of the blasted surfaces, the scanning electron microscopy (SEM) coupled with an energy dispersive X-ray (EDX), the contact profilometry method and the 3D characterization by means of stereo-Fe-SEM have been used. By means of stereo-Fe-SEM, the roughness and the real surface area of the rough surfaces have been calculated. The microstructural, topographical and compositional results have been correlated with the corrosion behaviour of the samples immersed in Hank's solution and studied by means of electrochemical impedance spectroscopy (EIS). The blasting process alters topographical and chemically the surface of the samples. These modifications induce to an increase in the capacitance values of the roughened samples due to the prevalence of the effect of electrochemically active areas of Ti6Al4V surface over the effect of the presence of Al 2 O 3 and ZrO 2 particles on the blasted surfaces. However, the general corrosion behaviour of the samples is not drastically changed

  11. Microstructure of two phases alloy Al3Ti/Al3Ti0.75Fe0.25

    International Nuclear Information System (INIS)

    Angeles, C.; Rosas, G.; Perez, R.

    1998-01-01

    The titanium-aluminium system presents three intermetallic compounds from those Al 3 Ti is what less attention has received. The objective of this work is to generate and characterize the microstructure of multiphase alloys nearby to Al 3 Ti compound through Fe addition as alloying. This is because it has been seen that little precipitates of Al 2 Ti phase over Al 3 Ti intermetallic compound increases its ductility. (Author)

  12. 3D-Master-Leitungssatz - Konzept zur Entwicklung von Leitungssätzen als 3D-Master in einem realistischen, vollständigen DMU-Modell

    OpenAIRE

    Neckenich, Jonas

    2017-01-01

    Die Fokussierung auf eine 3D-orientierte Produktentwicklung und einen durchgängigen 3D-Prozess wird in der heutigen Industrie immer wichtiger. Im Entwicklungsprozess des Kabelbaums trifft dabei die bauraumorientierte 3D-Entwicklung auf die produktorientierte 2D-Entwicklung. Die unsaubere Trennung zwischen bestehenden Definitionssystemen im heutigen Entwicklungsprozess führt dabei zu Datendiskrepanzen, Zeitverzug und Fehlern. Im Digital Mock-Up, welcher zur digitalen Absicherung des Fahrzeugs ...

  13. Barium aluminides BaxAl5(x=3,3.5,4)

    International Nuclear Information System (INIS)

    Jehle, Michael; Scherer, Harald; Wendorff, Marco; Roehr, Caroline

    2009-01-01

    Three aluminides of the series Ba x Al 5 (x=3,3.5,4) were synthesized from stoichiometric ratios of the elements in Ta crucibles. The crystal structure of the new compound Ba 7 Al 10 was determined using single crystal X-ray data (space group R3-barm, a=604.23(9), c=4879.0(12)pm, Z=3, R1=0.0325). The compound exhibits Al Kagome (3.6.3.6.) nets in which half of the triangles form the basis of trigonal bipyramids Al 5 . The apical Al are thus three-bonded assuming a charge of -2 ( 27 Al-NMR chemical shift δ=660pm), whereas the Al atoms of the basal triangle (i.e. of the Kagome net) are four-bonded and thus of formal charge -1(δ=490ppm). The total charge of the anion is thus exactly compensated by the Ba cations, i.e. the compound can be interpreted as an electron precise Zintl phase, exhibiting a distinct pseudo-band gap at the Fermi level of the calculated tDOS. According to the total formula, the structure displays a combination the stacking sequences of Ba 3 Al 5 and Ba 4 Al 5 , the structures of which have been redetermined with current methods (both hexagonal with space group P6 3 /mmc; Ba 3 Al 5 : a=606.55(7), c=1461.8(2)pm, Z=2, R1=0.0239; Ba 4 Al 5 : a=609.21(7), c=1775.8(3)pm, Z=2, R1=0.0300). These three compounds with slightly different electron counts but similar polyanions allow to compare the bond lengths, the electronic structures and the overall bonding situation in dependence of positive or negative deviation of the electron count in relation to the novel formally electron precise Zintl compound Ba 7 Al 10 . - Al 5 layers of Kagome nets in the new binary electron precise Zintl compound Ba 3.5 Al 5 , also found in Ba 3 Al 5 and Ba 4 Al 5 .

  14. Análisis y modelado del generador de inducción doblemente alimentado. Analysis and Modeling of Doubly Fed Induction Generators.

    Directory of Open Access Journals (Sweden)

    Lesyani T. León Viltre

    2015-04-01

    Full Text Available Uno de los generadores eólicos de velocidad variable más utilizados en la actualidad es el generador de inducción doblemente alimentado (DFIG. En el presente trabajo se presenta un esquema de control del DFIG. El convertidor de potencia del lado de la red es modelado y controlado usando el vector de tensión orientado a los ejes dq, lo que garantiza que con la componente del eje d de la corriente se pueda controlar la potencia activa y, por consiguiente, la tensión del bus DC. La componente del eje q es forzada a cero para mantener un factor de potencia unitario. En el convertidor del lado del rotor se utiliza un control orientado al flujo del estator. Para la sincronización con la red se utiliza un método novedoso basado en el método GDSC-PLL (Generalizad delayed signal cancellation. Además, se presenta un análisis del comportamiento del DFIG, ante huecos de tensión.  One of the variable speed wind turbines most commonly used today is the doubly feed induction generator(DFIG.A control scheme of DFIG is discussed in this paper. The power converter connected to the grid side (bus is modeled and controlled using voltage vectororiented dq reference frame, whichguarantees that the active power can be controlled by the daxiscurrent component and consequently the DC bus voltage. The qaxis component is forced to be zero in order to ensurethe unitary power factor. Astator flux oriented control in the rotor circuit converter is used.A novel GDSC-PLL method is used in order to achieve an efficient synchronization with the grid.Onthe order hand, this paper presents an analysis about the DFIG (Double Feed Induction Generator behavior during voltages sags.

  15. Análisis y modelado del generador de inducción doblemente alimentado; Analysis and Modeling of Doubly Fed Induction Generators

    Directory of Open Access Journals (Sweden)

    Lesyani T- León Viltre

    2014-06-01

    Full Text Available Uno de los generadores eólicos de velocidad variable más utilizados en la actualidad es el generador de inducción doblemente alimentado (DFIG. En el presente trabajo se presenta un esquema de control del DFIG. El convertidor de potencia del lado de la red es modelado y controlado usando el vector de tensión orientado a los ejes dq, lo que garantiza que con la componente del eje d de la corriente se pueda controlar la potencia activa y, por consiguiente, la tensión del bus DC. La componente del eje q es forzada a cero para mantener un factor de potencia unitario. En el convertidor del lado del rotor se utiliza un control orientado al flujo del estator. Para la sincronización con la red se utiliza un método novedoso basado en el método GDSC-PLL (Generalizad delayed signal cancellation. Además, se presenta un análisis del comportamiento del DFIG, ante huecos de tensión. One of the variable speed wind turbines most commonly used today is the doubly feed induction generator(DFIG.A control scheme of DFIG is discussed in this paper. The power converter connected to the grid side (bus is modeled and controlled using voltage vectororiented dq reference frame, whichguarantees that the active power can be controlled by the daxiscurrent component and consequently the DC bus voltage. The qaxis component is forced to be zero in order to ensurethe unitary power factor. Astator flux oriented control in the rotor circuit converter is used.A novel GDSC-PLL method is used in order to achieve an efficient synchronization with the grid.Onthe order hand, this paper presents an analysis about the DFIG (Double Feed Induction Generator behavior during voltages sags

  16. Processing and characterisation of novel metal-reinforced Al{sub 2}O{sub 3}-composites; Herstellung und Charakterisierung neuartiger metallverstaerkter Al{sub 2}O{sub 3}-Verbundwerkstoffe

    Energy Technology Data Exchange (ETDEWEB)

    Guenther, R. [GKSS-Forschungszentrum Geesthacht GmbH (Germany). Inst. fuer Werkstofforschung

    1999-07-01

    Using a new processing route, Al{sub 2}O{sub 3}-based ceramic composites have been prepared, that consist of 3-d networks of the ceramic and different metallic phases. The damage tolerance of these composites could be significantly improved over monolithic Al{sub 2}O{sub 3}: fracture strength and fracture toughness were increased by a factor of 4 up to 1393 MPa and 11.8 MPa {radical}(m), respectively. Similarly, resistance against abrasive wear was successfully improved by a factor of two over monolithic Al{sub 2}O{sub 3}. In combination with the good electrical and thermal conductivity, these superior mechanical properties are of great interest for automotive and biomedical industries. (orig.) [German] Mit einem neu entwickelten Verfahren werden keramische Al{sub 2}O{sub 3}-Verbundwerkstoffe hergestellt, die sich durch eine dreidimensionale Vernetzung der (inter)metallischen und der keramischen Phase auszeichnen. Die Schadenstoleranz derartiger Verbundwerkstoffe konnte im Vergleich zu monolithischer Al{sub 2}O{sub 3}-Keramik deutlich gesteigert werden: Die Bruchfestigkeit und die Bruchzaehigkeit wurden jeweils um einen Faktor 4 auf 1393 MPa bzw. 11,8 MPa {radical}(m) erhoeht, die Abriebfestigkeit um einen Faktor 2 verbessert. In Kombination mit der elektrischen und thermischen Leitfaehigkeit sind diese aussergewoehnlichen mechanischen Eigenschaften in Automobilbau und in der Medizintechnik von grossem Interesse. (orig.)

  17. Structure of 26Al studied by one - nucleon transfer reaction 27Al(d,t

    Directory of Open Access Journals (Sweden)

    Srivastava Vishal

    2015-01-01

    Full Text Available The excited states of 26Al have been produced and studied using 27Al(d,t reaction with 25 MeV deuteron as projectile. Optical model potential parameters were extracted from the measured elastic scattering angular distribution. Zero range distorted wave Born approximation analysis for the ground and 0.223 MeV states of 26Al have been done. The spectroscopic factors calculated for these states are found to be in good agreement with the previously reported values.

  18. Al2O3 adherence on CoCrAl alloys

    International Nuclear Information System (INIS)

    Kingsley, L.M.

    1980-04-01

    Adherence of protective oxides on NiCrAl and CoCrAl superalloys has been promoted by a dispersion of a highly oxygen reactive element or its oxide being produced within the protection system. Two aspects of this subject are investigated here: the use of Al 2 O 3 as both the dispersion and protective oxide; and the production of an HfO 2 dispersion while simultaneously aluminizing the alloy. It was found that an Al 2 O 3 dispersion will act to promote the adherence of an external scale of Al 2 O 3 to a degree comparable to previously tested dispersions and an HfO 2 dispersion comparable to that produced by a Rhines pack treatment is produced during aluminization

  19. Three dimensional (3D) microstructure-based finite element modeling of Al-SiC nanolaminates using focused ion beam (FIB) tomography

    Energy Technology Data Exchange (ETDEWEB)

    Mayer, Carl R. [Materials Science and Engineering, Arizona State University, Tempe, AZ 85287-6106 (United States); Molina-Aladareguia, Jon [IMDEA Materials Institute, c/Eric Kandel 2, Getafe, Madrid 28906 (Spain); Chawla, Nikhilesh, E-mail: nchawla@asu.edu [Materials Science and Engineering, Arizona State University, Tempe, AZ 85287-6106 (United States)

    2016-10-15

    Al-SiC nanolaminate composites show promise as high performance coating materials due to their combination of strength and toughness. Although a significant amount of modeling effort has been focused on materials with an idealized flat nanostructure, experimentally these materials exhibit complex undulating layer geometries. This work utilizes FIB tomography to characterize this nanostructure in 3D and finite element modeling to determine the effect that this complex structure has on the mechanical behavior of these materials. A sufficiently large volume was characterized such that a 1 × 2 μm micropillar could be generated from the dataset and compared directly to experimental results. The mechanical response from this nanostructure was then compared to pillar models using simplified structures with perfectly flat layers, layers with sinusoidal waviness, and layers with arc segment waviness. The arc segment based layer geometry showed the best agreement with the experimentally determined structure, indicating it would be the most appropriate geometry for future modeling efforts. - Highlights: •FIB tomography was used to determine the structure of an Al-SiC nanolaminate in 3D. •FEM was used to compare the deformation of the nanostructure to experimental results. •Idealized structures from literature were compared to the FIB determined structure. •Arc segment based structures approximated the FIB determined structure most closely.

  20. 3D primary grain shapes resulting from semi-solid metal processing

    CSIR Research Space (South Africa)

    Curle, Ulyate A

    2017-07-01

    Full Text Available ) size. Are these 2D globules also spherical in shape in 3D or are these 2D shapes remnants of the 3D shapes after sectioning along planes? An Al-Si-Mg alloy is semi-solid processed using a patented processing coil that induces contactless stirring while...

  1. Ordering and site occupancy of D03 ordered Fe3Al-5 at%Cr evaluated by means of atom probe tomography

    International Nuclear Information System (INIS)

    Rademacher, Thomas; Al-Kassab, Talaat; Deges, Johannes; Kirchheim, Reiner

    2011-01-01

    Addition of ternary elements to the D0 3 ordered Fe 3 Al intermetallic phase is a general approach to optimise its mechanical properties. To understand the physical influences of such additions the determination of the probability of site occupancies of these additions on the lattice site and ordering parameters is of high interest. Some common experimental techniques such as X-ray diffraction or Atom Location by Channelling Enhanced Microanalysis (ALCHEMI) are usually applied to explore this interplay. Unfortunately, certain published results are partly inconsistent, imprecise or even contradictory. In this study, these aspects are evaluated systematically by atom probe tomography (APT) and a special data analysis method. Additionally, to account for possible field evaporation effects that can falsify the estimation of site occupancy and induce misinterpretations, APT evaporation sequences were also simulated. As a result, chromium occupies most frequently the next nearest neighbour sites of Al atoms and local ordering parameters could be achieved. -- Research highlights: → APT measurements of Fe 3 Al-Cr are systematically analysed to study ordering. → APT measurements are simulated using EAM to calculate binding energies. → Cr occupies next nearest neighbour sites of aluminium with at least 83% ordering. → Aluminium ordering is at least 92%

  2. Luminescence thermometry with Eu{sup 3+} doped GdAlO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Lojpur, Vesna, E-mail: vesna.lojpur@yahoo.com; Ćulubrk, Sanja; Medić, Mina; Dramicanin, Miroslav

    2016-02-15

    Eu{sup 3+} doped GdAlO{sub 3} powder synthesized by solid state reaction was investigated for application in luminescence thermometry. Phase composition of material was confirmed by X-ray powder diffraction analysis. The photoluminescence emission spectra were collected under excitation of 399 nm, while elevating the temperature of the sample from the room temperature to 793 K. Emissions from {sup 5}D{sub 1}→{sup 7}F{sub 1} and {sup 5}D{sub 0}→{sup 7}F{sub 2} characteristic transitions of Eu{sup 3+} ions are selected for the temperature-dependence study using the fluorescence intensity ratio method. Emission decay curves measured at the strongest emission peak centered at 614 nm were recorded in a same temperature range. Data analysis showed that thermometry by fluorescence intensity ratio method can be used over the temperature region 293–793 K with the maximal relative sensitivity of 2.96% K{sup −1} (at 293 K). Temporal dependence of emission (lifetime) provides temperature sensing from 620 to 793 K with the maximal relative sensitivity of 2.28% K{sup −1}. - Highlights: • GdAlO{sub 3}: 4 at% of Eu{sup 3+} can be used for luminescence thermometry in the 293–793 K range. • Combined FIR and lifetime thermometry provide >0.5% K{sup −1} relative sensitivity. • Temperature dependence of lifetime is well described energy gap law model.

  3. Tunable emission in Ln3+ (Ce3+/Dy3+, Ce3+/Tb3+) doped KNa3Al4Si4O16 phosphor synthesized by combustion method

    Science.gov (United States)

    Kolte, M. M.; Pawade, V. B.; Bhattacharya, A. B.; Dhoble, S. J.

    2018-05-01

    Ln3+ (Ln = Ce3+/Dy3+, Ce3+/Tb3+) doped KNa3Al4Si4O16 phosphor has been synthesized by Combustion method (CS) at 550° C successfully. Ln3+ (Ln = Ce3+, Dy3+, Tb3+) ions when doped in KNa3Al4Si4O16 host lattice, it shows blue and green emission band under the near Ultraviolet (NUV) excitation wavelength. The Photoluminescence excitation (PLE) and emission spectra are observed due to f-f and d-f transition of rare earth ions. Also, an effective energy transfer (ET) study from Ce3+ → Dy3+ and Ce3+ → Tb3+ ions has been studied and confirmed on the basis of Dexter-Foster theory. Further synthesized phosphor is well characterized by XRD, SEM, TEM and decay time measurement. However, the analysis of crystallite size, lattice strain has been studied by using theoretical as well as experimental techniques. Hence, the observed tunable emission in Ln3+ doped KNa3Al4Si4O16 phosphor may be applicable for solid state lighting technology.

  4. Ab-initio studies of the electronic and optical properties of Al2O3:Ti3+ laser crystals

    Science.gov (United States)

    Brik, M. G.

    2018-03-01

    The structural and electronic properties of pure and Ti3+-doped α-Al2O3 were calculated in the present paper by using the first-principles methods. Special attention has been paid to the location of the Ti3+ states (3d1 electron configuration) in the band gap; the lowest 3d states are at about 4.78 eV above the top of the valence band. The crystal field strength 10Dq at the Ti3+ site was estimated from the density of states diagrams to be about 17,700 cm-1. The structural optimization of the unit cell was also performed at elevated hydrostatic pressure in the range from 0 to 25 GPa. By application of the Murnaghan equation to the obtained results, the bulk modulus of α-Al2O3 was estimated to be 225.69 GPa. In addition, from the analysis of the Ti3+3d density of states the distance dependence of the crystal field strength was found to be described by the following function: 10Dq=61.744/R4.671, where R is expressed in Å and 10Dq in eV.

  5. Optimising 3D printed concrete structures using topology optimisation

    NARCIS (Netherlands)

    Martens, P.; Mathot, M.; Bos, F.P.; Coenders, J.; Hordijk, D.A.; Luković, M.

    2017-01-01

    Additive manufacturing and 3D printing are rapidly developing digital fabrication techniques (Lu et al. 2015). After the first steps in small scale printing of metals (Frazier 2014) and plastics (Gibson et al. 2014) have been made, research from various groups around the world is now also focusing

  6. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al_3Ni_2@Al nanoparticles as a high microwave absorption material

    International Nuclear Information System (INIS)

    Pang, Yu; Xie, Xiubo; Li, Da; Chou, Wusheng; Liu, Tong

    2017-01-01

    The Al_3Ni_2@Al nanoparticles (NPs) were prepared from Ni_4_5Al_5_5 master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m"2/g and big pore volume of 0.507 cc/g. The saturation magnetization (M_S) and coercivity (H_C) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al_3Ni_2@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m"2/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  7. Simulating the 3-D Structure of Titan's Upper Atmosphere

    Science.gov (United States)

    Bell, J. M.; Waite, H.; Westlake, J.; Magee, B.

    2009-05-01

    We present results from the 3-D Titan Global Ionosphere-Thermosphere Model (Bell et al [2009], PSS, in review). We show comparisons between simulated N2, CH4, and H2 density fields and the in-situ data from the Cassini Ion Neutral Mass Spectrometer (INMS). We describe the temperature and wind fields consistent with these density calculations. Variations with local time, longitude, and latitude will be addressed. Potential plasma heating sources can be estimated using the 1-D model of De La Haye et al [2007, 2008] and the impacts on the thermosphere of Titan can be assessed in a global sense in Titan-GITM. Lastly, we will place these findings within the context of recent work in modeling the 2-D structure of Titan's upper atmosphere (Mueller-Wodarg et al [2008]).

  8. Improvement of High-Temperature Stability of Al2O3/Pt/ZnO/Al2O3 Film Electrode for SAW Devices by Using Al2O3 Barrier Layer

    Directory of Open Access Journals (Sweden)

    Xingpeng Liu

    2017-12-01

    Full Text Available In order to develop film electrodes for the surface acoustic wave (SAW devices operating in harsh high-temperature environments, novel Al2O3/Pt/ZnO/Al2O3 multilayered film electrodes were prepared by laser molecular beam epitaxy (LMBE at 150 °C. The first Al2O3 layer was used as a barrier layer to prevent the diffusion of Ga, La, and Si atoms from the La3Ga5SiO14 (LGS substrate to the film electrode and thus improved the crystalline quality of ZnO and Pt films. It was found that the resistance of the Al2O3/Pt/ZnO/Al2O3 electrode did not vary up to a temperature of 1150 °C, suggesting a high reliability of electrode under harsh high-temperature environments. The mechanism of the stable resistance of the Al2O3/Pt/ZnO/Al2O3 film electrodes at high temperature was investigated by analyzing its microstructure. The proposed Al2O3/Pt/ZnO/Al2O3 film electrode has great potential for application in high-temperature SAW devices.

  9. Microstructure and compression properties of 3D powder printed Ti-6Al-4V scaffolds with designed porosity: Experimental and computational analysis

    Energy Technology Data Exchange (ETDEWEB)

    Barui, Srimanta; Chatterjee, Subhomoy; Mandal, Sourav [Laboratory for Biomaterials, Materials Research Centre, Indian Institute of Science, Bangalore (India); Center of Excellence and Innovation in Biotechnology-' Translational Centre on Biomaterials for Orthopaedic and Dental Applications' , Materials Research Center, Indian Institute of Science, Bangalore (India); Kumar, Alok [Laboratory for Biomaterials, Materials Research Centre, Indian Institute of Science, Bangalore (India); Basu, Bikramjit, E-mail: bikram@mrc.iisc.ernet.in [Laboratory for Biomaterials, Materials Research Centre, Indian Institute of Science, Bangalore (India); Centre for Biosystems Science and Engineering, Indian Institute of Science, Bangalore (India); Center of Excellence and Innovation in Biotechnology-' Translational Centre on Biomaterials for Orthopaedic and Dental Applications' , Materials Research Center, Indian Institute of Science, Bangalore (India)

    2017-01-01

    The osseointegration of metallic implants depends on an effective balance among designed porosity to facilitate angiogenesis, tissue in-growth and bone-mimicking elastic modulus with good strength properties. While addressing such twin requirements, the present study demonstrates a low temperature additive manufacturing based processing strategy to fabricate Ti-6Al-4V scaffolds with designed porosity using inkjet-based 3D powder printing (3DPP). A novel starch-based aqueous binder was prepared and the physico-chemical parameters such as pH, viscosity, and surface tension were optimized for drop-on-demand (DOD) based thermal inkjet printing. Micro-computed tomography (micro-CT) of sintered scaffolds revealed a 57% total porosity in homogeneously porous scaffold and 45% in the gradient porous scaffold with 99% interconnectivity among the micropores. Under uniaxial compression testing, the strength of homogeneously porous and gradient porous scaffolds were ~ 47 MPa and ~ 90 MPa, respectively. The progressive failure in homogeneously porous scaffold was recorded. In parallel to experimental measurements, finite element (FE) analyses have been performed to study the stress distribution globally and also locally around the designed pores. Consistent with FE analyses, a higher elastic modulus was recorded with gradient porous scaffolds (~ 3 GPa) than the homogenously porous scaffolds (~ 2 GPa). While comparing with the existing literature reports, the present work, for the first time, establishes ‘direct powder printing methodology’ of Ti-6Al-4V porous scaffolds with biomedically relevant microstructural and mechanical properties. Also, a new FE analysis approach, based on the critical understanding of the porous architecture using micro-CT results, is presented to realistically predict the compression response of porous scaffolds. - Highlights: • Binder physics and process parameters in inkjet 3D printing of Ti-6Al-4V • Phase assembly and detailed microstructure

  10. Microstructure and compression properties of 3D powder printed Ti-6Al-4V scaffolds with designed porosity: Experimental and computational analysis

    International Nuclear Information System (INIS)

    Barui, Srimanta; Chatterjee, Subhomoy; Mandal, Sourav; Kumar, Alok; Basu, Bikramjit

    2017-01-01

    The osseointegration of metallic implants depends on an effective balance among designed porosity to facilitate angiogenesis, tissue in-growth and bone-mimicking elastic modulus with good strength properties. While addressing such twin requirements, the present study demonstrates a low temperature additive manufacturing based processing strategy to fabricate Ti-6Al-4V scaffolds with designed porosity using inkjet-based 3D powder printing (3DPP). A novel starch-based aqueous binder was prepared and the physico-chemical parameters such as pH, viscosity, and surface tension were optimized for drop-on-demand (DOD) based thermal inkjet printing. Micro-computed tomography (micro-CT) of sintered scaffolds revealed a 57% total porosity in homogeneously porous scaffold and 45% in the gradient porous scaffold with 99% interconnectivity among the micropores. Under uniaxial compression testing, the strength of homogeneously porous and gradient porous scaffolds were ~ 47 MPa and ~ 90 MPa, respectively. The progressive failure in homogeneously porous scaffold was recorded. In parallel to experimental measurements, finite element (FE) analyses have been performed to study the stress distribution globally and also locally around the designed pores. Consistent with FE analyses, a higher elastic modulus was recorded with gradient porous scaffolds (~ 3 GPa) than the homogenously porous scaffolds (~ 2 GPa). While comparing with the existing literature reports, the present work, for the first time, establishes ‘direct powder printing methodology’ of Ti-6Al-4V porous scaffolds with biomedically relevant microstructural and mechanical properties. Also, a new FE analysis approach, based on the critical understanding of the porous architecture using micro-CT results, is presented to realistically predict the compression response of porous scaffolds. - Highlights: • Binder physics and process parameters in inkjet 3D printing of Ti-6Al-4V • Phase assembly and detailed microstructure

  11. Proton spectra from 6.3 GeV/c deuteron break-up on H, D, C, Al and Bi nuclei

    International Nuclear Information System (INIS)

    Azhgirey, L.S.; Ignatenko, M.A.; Ivanov, V.V.; Kuznetsov, A.S.; Mescheryakov, M.G.; Razin, S.V.; Stoletov, G.D.; Vzorov, I.K.; Zhmyrov, V.N.

    1977-01-01

    The proton spectra from deuteron break-up on H, D, 12 C, 27 Al and 209 Bi nuclei were measured at an angle of 103 mrad (lab. system) in the momentum interval from 2.6 to 3.6 GeV/c. The measurements were made at the JINR synchrophasotron by one-arm magnetic spectrometer on-line with a computer. The extracted 6.3 GeV/c deuteron beam was incident on targets of CH 2 , CD 2 , C, Al and Bi at the thickness from 0.8 to 2 g/cm 2 . The flux of deuteron beam was equal to 5x10 8 -5x10 9 particles/pulse with a typical pulse length of 300 ms. The repetition rate was one pulse every 10 s. Proton peaks with the maximum at about 3.1 GeV/c and 280-300 MeV/c FWHM dominate in all the measured spectra. Experimental proton spectra are compared with calculations with the Reid, the Moravcsik Gartenhaus, the Hulten and the Gauss wave functions. The results, on the whole, are reasonably reproduced in the framework of the Glauber multiple scattering model taking into account the relativistic deformation of the deuteron wave function

  12. Averaged description of 3D MHD equilibrium

    International Nuclear Information System (INIS)

    Medvedev, S.Yu.; Drozdov, V.V.; Ivanov, A.A.; Martynov, A.A.; Pashekhonov, Yu.Yu.; Mikhailov, M.I.

    2001-01-01

    A general approach by S.A.Galkin et al. in 1991 to 2D description of MHD equilibrium and stability in 3D systems was proposed. The method requires a background 3D equilibrium with nested flux surfaces to generate the metric of a Riemannian space in which the background equilibrium is described by the 2D equation of Grad-Shafranov type. The equation can be solved then varying plasma profiles and shape to get approximate 3D equilibria. In the framework of the method both planar axis conventional stellarators and configurations with spatial magnetic axis can be studied. In the present report the formulation and numerical realization of the equilibrium problem for stellarators with planar axis is reviewed. The input background equilibria with nested flux surfaces are taken from vacuum magnetic field approximately described by analytic scalar potential

  13. Relaxation electron excitations in Al2O3, Y3Al5O12 and YAlO3

    International Nuclear Information System (INIS)

    Kuznetsov, A.I.; Namozov, B.R.; Myurk, V.V.

    1985-01-01

    Excitation spectra of short-wave Al 2 O 3 , YAlO 3 and Y 3 Al 5 O 12 crystal luminescence, cathodoluminescence (including time resolution) and lay-temperature thermoluminescence are investigated. Analysis of experimental data permits to distingnish among these objects pairs of bands of supposedly characteristic luminescences: 7.5 and 3.8 eV (Al 2 O 3 ), 5.9 and 4.2 eV (YAlO 3 ), and 4.9 and 4.2 eV (Y 3 Al 5 O 12 ), where recombination luminescence is characteristic for long-wave ones, at that time exciton-like luminescence - for short-wave ones. A hypothesis about strong difference between states of an autolocalized exciton and ''autolocalized hole + electron'' (responsible for short-wave and long-wave bands of characteristic luminescence) is expressed; the difference is based on their genetic origin from different regions of a valent zone (in particular, long-wave bands - from the subzone of heavy holes of a valent zone ceiling, originating from nonbinding 2p-orbitals of oxygen)

  14. Thickness and microstructure characterization of TGO in thermal barrier coatings by 3D reconstruction

    Energy Technology Data Exchange (ETDEWEB)

    Song, Xuemei; Meng, Fangli [The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, , Chinese Academy of Sciences, Shanghai 200050 (China); Kong, Mingguang [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Wang, Yongzhe [The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, , Chinese Academy of Sciences, Shanghai 200050 (China); Huang, Liping; Zheng, Xuebin [Key Laboratory of Inorganic Coating Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); Zeng, Yi, E-mail: zengyi@mail.sic.ac.cn [The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, , Chinese Academy of Sciences, Shanghai 200050 (China); CAS Center for Excellence in Superconducting Electronics (CENSE), Shanghai 200050 (China)

    2016-10-15

    Yttria-stabilized zirconia (YSZ) thermal barrier coatings (TBCs) are prepared by plasma spraying. Thermally grown oxide (TGO) would be formed between YSZ topcoat and bond coat after 50 h thermal service for YSZ TBCs. The electron back scattered diffraction (EBSD) results reveal that the TGO layer is composed of α-Al{sub 2}O{sub 3} and cubic Al{sub 2}NiO{sub 4} layers. Measured values of TGO thickness from the 2D-SEM image are greater than or equal to its real thickness due to the fact that the TGO layer is much rolling so that up and down surfaces of the TGO can't be completely perpendicular to the cross-section direction confirmed by 3D-SEM. Furthermore, 3D-SEM results reveal that the real thickness of TGO layer is 3.10 μm instead of 7.1 μm. In addition, 3D-EBSD confirmed that α-Al{sub 2}O{sub 3} layer in TGO is composed of single layer of grains and Al{sub 2}NiO{sub 4} layer consist of multilayer of grains while α-Al{sub 2}O{sub 3} layer is mixed with single layer and multilayer of α-Al{sub 2}O{sub 3} grains from observation of the 2D-EBSD image. It provides a new method to characterize real thickness and microstructure of TGO, which is also applied to other film materials. - Highlights: •This work provides a new method to measure the real thickness of TGO. •YSZ TBCs were prepared by plasma spraying. •TGO is formed in TBCs by simulating thermal service at 1100 °C for 50 h. •Real thickness and microstructure of TGO were investigated by 3D reconstruction.

  15. Blokify: Juego de modelado e impresión 3D en tableta digital para el aprendizaje de vistas normalizadas y perspectiva

    OpenAIRE

    Saorin, Jose; De la Torre Cantero, Jorge; Melian, Damari; Meier, Cecile; Rivero Trujillo, David

    2015-01-01

    En este artículo se analiza el uso del juego Blokify para introducir al alumnado en las competencias que relacionan las figuras tridimensionales con su representación bidimensional mediante las vistas normalizadas y la perspectiva. Estos contenidos se estudian en asignaturas de dibujo a partir de secundaria y Bachillerato.Blokify es un juego gratuito para tabletas digitales que permite modelar figuras tridimensionales de forma similar al popular video juego Minecraft: "bloque a bloque”....

  16. Dehydration of D-xylose over SiO{sub 2}-Al{sub 2}O{sub 3} catalyst: Perspective on the pathways for condensed products

    Energy Technology Data Exchange (ETDEWEB)

    You, Su Jin; Park, Eun Duck; Park, Myung-June [Ajou University, Suwon (Korea, Republic of)

    2016-03-15

    This work addresses the kinetic mechanism for the dehydration of D-xylose over the SiO{sub 2}-Al{sub 2}O{sub 3} solid catalyst, where the formation of condensed products is included in addition to the production of furfural and its decomposition. The kinetic modeling and parametric sensitivity show that the isomerization of D-xylose takes place in the early stages of the reaction, followed by the dehydration of isomers. Accordingly, the homogeneous polymerization of isomers is found to be dominant. The developed model is used to evaluate the effects of operating conditions on the catalytic performance; high temperature and D-xylose concentration guarantee high furfural yield.

  17. Temperature and concentration quenching of Tb3+ emissions in Y4Al2O9 crystals

    International Nuclear Information System (INIS)

    Boruc, Z.; Fetlinski, B.; Kaczkan, M.; Turczynski, S.; Pawlak, D.; Malinowski, M.

    2012-01-01

    Highlights: ► Spectroscopic properties of Tb 3+ :Y 4 Al 2 O 9 crystals are studied. ► Concentration and temperature dependencies of fluorescence are investigated. ► The cross-relaxation transfer rates are experimentally determined. ► Strong influence of cross relaxation process on 5 D 3 emission quenching is observed. ► Decays are modelled using Inokuti–Hirayama approach. - Abstract: Spectroscopic properties of trivalent terbium (Tb 3+ ) activated Y 4 Al 2 O 9 (abbreviated YAM) crystals were studied. Concentration and temperature dependent emission spectra and fluorescence dynamics profiles have been investigated in YAM:Tb 3+ in order to understand better processes responsible for quenching of the terbium 5 D 3 and 5 D 4 emissions. Decays were modelled using Inokuti–Hirayama approach to obtain information on the energy transfer mechanism. The cross-relaxation transfer rates were experimentally determined as a function of temperature and Tb 3+ concentration. The investigation revealed strong influence of cross-relaxation process on 5 D 3 emission quenching. The two different processes responsible for the increase of fluorescence quenching with growing temperature were observed, both related to thermal activation energy. For temperatures above 700 K, the temperature dependence of the emission intensity ratio ( 5 D 3 / 5 D 4 ) becomes linear and the decay times are rapidly decreasing monotonously with increasing temperature, what is confirming the potential of Y 4 Al 2 O 9 :Tb 3+ material in high temperature luminescence thermometry.

  18. Underpotential and overpotential deposition of Al onto Cu(111 from the AlCl3–EtMeImCl room temperature molten salt

    Directory of Open Access Journals (Sweden)

    V. D. JOVIC

    2006-04-01

    Full Text Available The processes of underpotential (UPD and overpotential (OPD deposition ofAl onto Cu(111, from the room temperature molten salt AlCl3–EtMeImCl of different compositions, has been investigated by the cyclic volatmmetry (CV and potentiostatic pulse techniques. It was shown that the CVs of the UPD are characterized by two sharp peaks, while the potentiostatic cathodic and anodic j–t-transients of this process are characterized by two waves, indicating that the UPD of Al results in the formation of two structures. The first, less dense one,most probably the (sqrt3 x sqrt3 R30 º ordered structure of Al, is formed at a more positive potential of about 200 mV vs. Al, while the second one, a complete momolayer of Al, is formed at about 20 mV vs. Al, just before the reversible potential of Al in these melts (–20mV vs. Al. The OPD of Al was detected at potentials more negative than –30 mV vs. Al, occurring through the progressive 3D nucleation and growth mechanism. Slow surface alloying of Al with Cu was found to occur at a potential close to the reversible potential of Al.

  19. Effect of Al/Ga substitution on the structural and luminescence properties of Y3(Al1-xGax)5O12: Ce3+ phosphors

    Science.gov (United States)

    Fu, Sheng; Tan, Jin; Bai, Xin; Yang, Shanjie; You, Lei; Du, Zhengkang

    2018-01-01

    As candidates for display and lighting materials, a series of gallium-substituted cerium-doped yttrium aluminum garnet (Y3(GaxAl1-x)5O12: Ce3+) phosphors were synthesized by high temperature solid-state reaction. The phases, morphology, luminescence spectra and thermal stability of the phosphors were investigated. The volatilization of Ga2O3 induces the constituents out of stoichiometric ratio and different impurities in the system. The excitation and emission spectra occur red shift (339 nm - 351 nm) and blue shift (465 nm - 437 nm), and blue shift (541 nm - 517 nm), respectively. The spectra have no further blue shift and the luminescence intensity decrease with x over 0.4. Combining crystal structure with PL spectrum, the distortion of dodecahedron and crystal field splitting of 5d level of Ce3+ are influenced by Ga3+ in octahedral coordination polyhedron rather than tetrahedron. The crystalline perfection and Ga3+ occupying the tetrahedron induce less garnet phase formation, more impurities and the 5d level located in the conductive bands, thus accounting for the x = 0.4 turning points of the PL and PLE intensity. Based on the thermal quenching and CIE, the Y3(GaxAl1-x)5O12: Ce3+0.06 phosphors have great potential for use on the w-LED.

  20. Diseño de carcasa para impresora 3D modelo Prusa i3

    OpenAIRE

    ESTEVE ROS, LUCAS

    2016-01-01

    [ES] Los objetivos de este trabajo son: - Diseñar una carcasa externa para una impresora 3D tipo Prusa i3. - Aportar cierta carga inventiva al producto. - Proyectar el concepto de DIY ”Do it yourself” al producto, con lo que el usuario podrá montarlo él mismo. - Plantear el producto para que sea fácil de fabricar y de bajo coste. - Resolver ciertos puntos de problemática que acarrea el uso de una impresora tipo Prusa i3. Esteve Ros, L. (2016). Diseño de carcasa para impre...

  1. Annealing Effects on Microstructure and Mechanical Properties of Ultrafine-Grained Al Composites Reinforced with Nano-Al2O3 by Rotary Swaging

    Science.gov (United States)

    Chen, Cunguang; Wang, Wenwen; Guo, Zhimeng; Sun, Chunbao; Volinsky, Alex A.; Paley, Vladislav

    2018-03-01

    Microstructure evolution and variations in mechanical properties of Al-Al2O3 nanocomposite produced by powder metallurgy were investigated and compared with commercially pure aluminum (Al-1050) after furnace annealing. Fine gas-atomized Al powder compacts were first sintered in flowing nitrogen, subsequently consolidated into wires by rotary swaging and eventually annealed at 300 and 500 °C for 24 h each. Scanning and transmission electron microscopy with energy-dispersive spectroscopy was utilized to document the microstructure evolution. Rotary swaging was proven to lead to a marked decrease in grain size. After heavy swaging to true deformation degree of φ = 6 and annealing at 500 °C, obvious recrystallization was observed at Al-1050's existing grain boundaries and the crystals began to grow perpendicular to the flow direction. In the Al-Al2O3 nanocomposite, fabricated from d 50 = 6 μm Al powder, recrystallization partially occurred, while grains were still extremely fine. Due to the dual role of fine-grained Al2O3 dispersion strengthening, the nanocomposite showed improved mechanical performance in terms of tensile strength, approximately twice higher than Al-1050 after annealing at 500 °C.

  2. Fabrication and luminescence properties of Al{sub 2}O{sub 3}:Tb{sup 3+} microspheres via a microwave solvothermal route

    Energy Technology Data Exchange (ETDEWEB)

    Zhu Zhenfeng, E-mail: zhuzf@sust.edu.cn [School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi' an 710021 (China); Liu Dianguang; Liu Hui; Li Guangjun; Du Juan; He Zuoli [School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi' an 710021 (China)

    2012-02-15

    Al{sub 2}O{sub 3}:Tb{sup 3+} green phosphors were synthesized via a microwave solvothermal and thermal decomposition route, and characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), photoluminescence (PL) spectra, and decay curves. XRD results indicate that Tb{sup 3+} doped samples are {gamma}-Al{sub 2}O{sub 3} after being calcined at 773 K. SEM results show that the particles of Al{sub 2}O{sub 3}:Tb{sup 3+} are hierarchically nanostructured microspheres assembled from nanosheets. The PL spectra indicate that the {sup 5}D{sub 4}{yields}{sup 7}F{sub 5} (545 nm) electric dipole transition is the most intensive when excited at 235 nm. It is shown that 0.7 mol% of doping concentration of Tb{sup 3+} ions in {gamma}-Al{sub 2}O{sub 3}:Tb{sup 3+} is optimum. According to Dexter's theory, the critical distance between Tb{sup 3+} ions for energy transfer was determined to be 18.4 A. It is found that the curve followed the single-exponential decay. The excellent chromaticity coordinates of Al{sub 2}O{sub 3}:Tb{sup 3+} phosphors, as defined by the International Commission on Illumination (CIE), indicate that it is a good candidate for use in light display systems and optoelectronic devices. - Highlights: Black-Right-Pointing-Pointer Al{sub 2}O{sub 3}:Tb{sup 3+} phosphors prepared via a microwave solvothermal route. Black-Right-Pointing-Pointer The particles were hierarchically nanostructured microspheres packaged by nanosheets. Black-Right-Pointing-Pointer {sup 5}D{sub 4}{yields}{sup 7}F{sub 5} electric dipole transition is the most intensive when excited at 235 nm. Black-Right-Pointing-Pointer 0.7 mol% of doping concentration of Tb{sup 3+} ions in {gamma}-Al{sub 2}O{sub 3}:Tb{sup 3+} is optimum. Black-Right-Pointing-Pointer Critical distance between Tb{sup 3+} ions for energy transfer is 18.4 A.

  3. Optical fabrication of lightweighted 3D printed mirrors

    Science.gov (United States)

    Herzog, Harrison; Segal, Jacob; Smith, Jeremy; Bates, Richard; Calis, Jacob; De La Torre, Alyssa; Kim, Dae Wook; Mici, Joni; Mireles, Jorge; Stubbs, David M.; Wicker, Ryan

    2015-09-01

    Direct Metal Laser Sintering (DMLS) and Electron Beam Melting (EBM) 3D printing technologies were utilized to create lightweight, optical grade mirrors out of AlSi10Mg aluminum and Ti6Al4V titanium alloys at the University of Arizona in Tucson. The mirror prototypes were polished to meet the λ/20 RMS and λ/4 P-V surface figure requirements. The intent of this project was to design topologically optimized mirrors that had a high specific stiffness and low surface displacement. Two models were designed using Altair Inspire software, and the mirrors had to endure the polishing process with the necessary stiffness to eliminate print-through. Mitigating porosity of the 3D printed mirror blanks was a challenge in the face of reconciling new printing technologies with traditional optical polishing methods. The prototypes underwent Hot Isostatic Press (HIP) and heat treatment to improve density, eliminate porosity, and relieve internal stresses. Metal 3D printing allows for nearly unlimited topological constraints on design and virtually eliminates the need for a machine shop when creating an optical quality mirror. This research can lead to an increase in mirror mounting support complexity in the manufacturing of lightweight mirrors and improve overall process efficiency. The project aspired to have many future applications of light weighted 3D printed mirrors, such as spaceflight. This paper covers the design/fab/polish/test of 3D printed mirrors, thermal/structural finite element analysis, and results.

  4. Phase Constituents and Microstructure of Ti3Al/Fe3Al + TiN/TiB2 Composite Coating on Titanium Alloy

    Science.gov (United States)

    Li, Jianing; Chen, Chuanzhong; Zhang, Cuifang

    Laser cladding of the Fe3Al + B4C/TiN + Al2O3 pre-placed powders on the Ti-6Al-4V alloy can form the Ti3Al/Fe3Al + TiN/TiB2 composite coating, which improved the wear resistance of the Ti-6Al-4V alloy surface. In this study, the Ti3Al/Fe3Al + TiN/TiB2 composite coating has been researched by means of X-ray diffraction and scanning electron microscope. It was found that during the laser cladding process, Al2O3 can react with TiB2, leading to the formations of Ti3Al and B. This principle can be used to improve the Fe3Al + B4C/TiN laser-cladded coating on the Ti-6Al-4V alloy. Furthermore, during the cladding process, C consumed the oxygen in Fe3Al + B4C /TiN + Al2O3 molten pool, which retarded the productions of the redundant metal oxides.

  5. 3D-ICONS Ireland – fulfilling the potential of a rich 3D resource

    Directory of Open Access Journals (Sweden)

    Anthony Corns

    2017-03-01

    Full Text Available As a partner in the EU co-funded 3D-ICONS project, the Discovery Programme undertook the 3D documentation of some of the most iconic cultural heritage sites in Ireland. This pan-European project aimed to establish a complete pipeline for the production of 3D replicas of archaeological monuments and historic buildings, and to publish the content to Europeana for public access. The list of Irish icons range from wider cultural landscapes to smaller ornately carved stones and includes a wide range of chronological periods: from Neolithic rock art from 2500 BC to Derry's 17th-century fortifications. The primary digitisation methods include airborne laser scanning (ALS, phase-based terrestrial laser scanning (Faro Focus 3D and close range structured light scanning (Artec EVA. These are now mainstream approaches for surveying historic landscapes, structures and objects, generating precise, high-resolution point cloud data, primarily for viewing and interaction in proprietary software applications. The challenge was to convert these complex high-volume datasets into textured 3D models, retaining the geometric integrity of the original data. The article highlights the development of a pipeline to produce a lightweight 3D model that enables the public to interact with a photorealistic model based upon accurate survey and texture data. 3D-ICONS ended in January 2015, but a new website 3dicons.ie was launched to offer continued access to the Irish 3D models and associated content and media generated during the project. The article will consider the impact of this online content, particularly how it has been used as a teaching aid in secondary schools and how this may be extended in the future. It will also demonstrate how content from the project has been remodelled to develop an interactive and immersive experience for the great mound at Knowth, a development in partnership with the operators of the Brú na Bóinne visitor centre.

  6. MODELADO, DISEÑO Y CONSTRUCCIÓN DE UN SISTEMA ACTIVO DE CONTROL DE ESTABILIDAD DE BAJO COSTO PARA COHETES EXPERIMENTALES TIPO AFICIONADO

    OpenAIRE

    Jorge Alexander Aponte Rodríguez; Darío Amaya Hurtado; Astrid Rubiano Fonseca; Vladimir Prada Jiménez

    2010-01-01

    Este artículo presenta el modelado, diseño y construcción de un cohete tipo aficionado de bajo costo, empleando un sistema de control activo por medio de una tobera móvil para lograr una mayor estabilidad. Se plantean los métodos y procedimientos utilizados en el experimento, desarrollando el análisis, simulación e implementación de un prototipo de control para lograr una trayectoria de vuelo.

  7. MODELADO, DISEÑO Y CONSTRUCCIÓN DE UN SISTEMA ACTIVO DE CONTROL DE ESTABILIDAD DE BAJO COSTO PARA COHETES EXPERIMENTALES TIPO AFICIONADO

    Directory of Open Access Journals (Sweden)

    Jorge Alexander Aponte Rodríguez

    2010-01-01

    Full Text Available Este artículo presenta el modelado, diseño y construcción de un cohete tipo aficionado de bajo costo, empleando un sistema de control activo por medio de una tobera móvil para lograr una mayor estabilidad. Se plantean los métodos y procedimientos utilizados en el experimento, desarrollando el análisis, simulación e implementación de un prototipo de control para lograr una trayectoria de vuelo.

  8. Análisis traceológico de la cerámica: modelado y espacio social durante el postalayótico (V-I A.C.) en la Península de Santa Ponça (Calvià, Mallorca)

    OpenAIRE

    Garcia Rosselló, Jaume

    2010-01-01

    La tesis doctoral que presentamos a continuación bajo el título: “Análisis traceológico de la cerámica: modelado y espacio social durante el postalayótico (V-I A.C.) en la Península de Santa Ponça (Calvià, Mallorca) tiene una doble orientación: Por una parte es una nueva propuesta metodológica fundamentada en la reconstrucción de los sistemas de modelado por medio de la traceología cerámica. Por otro, es una aplicación metodológica sobre un conjunto de cerámicas adscritas a la edad de hierro ...

  9. Herramientas colaborativas multiplataforma en la enseñanza de la ingeniería de software

    OpenAIRE

    Neil, Carlos; De Vincenzi, Marcelo; Battaglia, Nicolás; Martínez, Roxana

    2016-01-01

    En el uso de herramientas CASE (Computer Aided Software Engineering) como soporte de modelado para la enseñanza de la ingeniería de software, suelen utilizarse productos comerciales de uso profesional o herramientas de modelado de acceso libre no tan comunes en el mercado. Surge entonces la necesidad de contar con herramientas CASE que permitan asistir al alumno a adquirir y afianzar los contenidos académicos desarrollados dentro de un espacio que facilite tanto a sus pares como al docente co...

  10. UAICase: integración de un entorno académico con una herramienta CASE en una plataforma virtual colaborativa

    OpenAIRE

    Battaglia, Nicolás; Neil, Carlos; De Vincenzi, Marcelo; Martínez, Roxana

    2016-01-01

    En el uso de herramientas CASE como soporte de modelado para la enseñanza de la ingeniería de software, suelen utilizarse productos comerciales de uso profesional muy complejos o herramientas de modelado de acceso libre no tan comunes en el mercado. Surge entonces la necesidad de contar con herramientas CASE que permitan asistir al alumno a adquirir y afianzar los contenidos académicos desarrollados dentro de un espacio que facilite tanto a sus pares como al docente colaborar entre sí, sin...

  11. Grain refinement of AZ91D magnesium alloy by a new Mg–50%Al4C3 master alloy

    International Nuclear Information System (INIS)

    Liu, Shengfa; Chen, Yang; Han, Hui

    2015-01-01

    A novel and simple method for preparing Mg–50%Al 4 C 3 (hereafter in wt.%) master alloy has been developed by powder in-situ synthesis process under argon atmosphere. X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive X-ray spectroscopy (EDS) results show the existence of Al 4 C 3 particles in this master alloy. After adding 1.8% Mg–50%Al 4 C 3 master alloy, the average grain size of α-Mg decreased from 360 μm to 154 μm. Based on the DTA test results and calculation of the planar disregistry between Al 4 C 3 and α-Mg, Al 4 C 3 particles located in the central regions of magnesium grains can act as the heterogeneous nucleus of primary α-Mg phase

  12. Liquidus projection of the Nb-Cr-Al system near the Al3(Nb,Cr) + Cr(Al,Nb) eutectic region

    International Nuclear Information System (INIS)

    Souza, S.A.; Ferrandini, P.L.; Nunes, C.A.; Coelho, A.A.; Caram, R.

    2006-01-01

    The system Nb-Cr-Al was investigated in the region near the Al 3 (Nb,Cr) + Cr(Al,Nb) eutectic and the liquidus projection of that region was determined based on the microstructural characterization of arc melted alloys. The characterization utilized scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), differential thermal analysis (DTA) and X-ray diffraction (XRD). The results allowed one to determine three primary solidification liquidus surfaces ((Cr,Al) 2 Nb, Cr(Al,Nb) and Al 3 (Nb,Cr)), that are originated from the binary systems Cr-Nb, Cr-Al and Al-Nb. It is proposed the occurrence of the invariant reaction L + (Cr,Al) 2 Nb ↔ Al 3 (Nb,Cr) + Cr(Al,Nb) and of a point of minimum, which involves a three phase reaction, L ↔ Al 3 (Nb,Cr) + Cr(Al,Nb). All alloys studied showed formation of the Al 3 (Nb,Cr) + Cr(Al,Nb) eutectic as the last solidification step with Al(Nb)Cr 2 precipitating from Cr(Al,Nb)

  13. PHASE CONSTITUENTS AND MICROSTRUCTURE OF Ti3Al/Fe3Al + TiN/TiB2 COMPOSITE COATING ON TITANIUM ALLOY

    OpenAIRE

    JIANING LI; CHUANZHONG CHEN; CUIFANG ZHANG

    2011-01-01

    Laser cladding of the Fe3Al + B4C/TiN + Al2O3 pre-placed powders on the Ti-6Al-4V alloy can form the Ti3Al/Fe3Al + TiN/TiB2 composite coating, which improved the wear resistance of the Ti-6Al-4V alloy surface. In this study, the Ti3Al/Fe3Al + TiN/TiB2 composite coating has been researched by means of X-ray diffraction and scanning electron microscope. It was found that during the laser cladding process, Al2O3 can react with TiB2, leading to the formations of Ti3Al and B. This principle can be...

  14. Annexe 3. Constitution d'une exploitation à Homs

    OpenAIRE

    2015-01-01

    ‘Abd al-Laṭīf, né en 1925, est jardinier à Horns. Il exploite avec son fils aîné et l'aide de deux de ses petits-fils un jardin de quelques 35 dunum (3,5 hectares) situé dans le zūr al-Ǧdīdeh, secteur central de la zone agricole. Cette grande exploitation, constituée de plusieurs parcelles ayant différents statuts, est en partie le produit d'une histoire familiale dont je voudrais présenter ici brièvement les principaux aspects. Figure 50 – Alliances matrimoniales entre la lignée de ‘Abbās e...

  15. Site occupancy and magnetic study of Al3+ and Cr3+ co-substituted Y3Fe5O12

    International Nuclear Information System (INIS)

    Bouziane, K.; Yousif, A.; Widatallah, H.M.; Amighian, J.

    2008-01-01

    Single-phased polycrystalline Y 3 Fe 5-2x Al x Cr x O 12 garnet samples (x=0, 0.2, 0.4 and 0.6) have been prepared by the conventional ceramic technique. Rietveld refinement of X-ray diffraction patterns of the samples shows them to crystallize in the Ia3d space group and the corresponding lattice constant to decrease with increasing Al 3+ and Cr 3+ contents (x). Moessbauer results indicate that Cr 3+ substitutes for Fe 3+ at the octahedral sites whilst Al 3+ essentially replaces Fe 3+ at the tetrahedral sites. This result indicates that co-doping of Y 3 Fe 5 O 12 does not affect the preferential site occupancy for separate individual substitution of either Cr 3+ or Al 3+ . The magnetization measurements reveal that the Curie temperature (T c ) monotonically decreases with increasing x while the magnetic moment per unit formula decreases up to x=0.4 and then slightly increases for x=0.6. This reflects a progressive weakening of the ferrimagnetic exchange interaction between the Fe 3+ ions at octahedral and tetrahedral sites due to co-substitution. The magnetic moment was calculated using the cations distribution inferred from the Moessbauer data and the collinear ferrimagnetic model, and was found to agree reasonably with the experimentally measured value. The phenomenological amplitude crossover, characterized by the temperature T*, has also been observed in the doped YIG and briefly discussed

  16. Thermoluminescence of LaAlO{sub 3}; Termoluminescencia de LaAlO{sub 3}:Dy

    Energy Technology Data Exchange (ETDEWEB)

    Morales H, A.; Zarate M, J. [Universidad Michoacana de San Nicolas de Hidalgo, Instituto de Investigacion en Metalurgia y Materiales, Ciudad Universitaria, Edif. U, 58060 Morelia, Michoacan (Mexico); Rivera M, T. [IPN, Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada, Av. Legaria 694, 11500 Mexico D. F. (Mexico); Azorin N, J., E-mail: feyo_yo@hotmail.com [Universidad Autonoma Metropolitana, Unidad Iztapalapa, Av. San Rafael Atlixco 186, Col. Vicentina, 09340 Mexico D. F. (Mexico)

    2015-10-15

    In this paper the thermoluminescent properties of doped lanthanum aluminate (LaAlO{sub 3}) with dysprosium ion (Dy) were studied. The thermoluminescence characteristics in the samples were obtained using an ultraviolet radiation of 220 nm. The LaAlO{sub 3}:Dy samples were prepared by the modified Pechini method (Spray Dryer). The structural and morphological characterization was obtained by X-ray diffraction (XRD) and scanning electron microscopy (Sem) techniques respectively. The size particle composing the agglomerate was determined by Sem, agglomerated particles composed size of 2μm were observed. The thermoluminescence response of LaAlO{sub 3}:Dy was compared with that obtained with the undoped sample. Thermoluminescence brightness curves of LaAlO{sub 3}:Dy showed a peak centered at 185 grades C. Sensitivity of doped sample was greater, about 100 times compared with the undoped sample. Thermoluminescence response in function of the wavelength showed a maximum at 220 nm. Also the fading in thermoluminescence response was studied. (Author)

  17. Atomistic calculations of hydrogen interactions with Ni3Al grain boundaries and Ni/Ni3Al interfaces

    International Nuclear Information System (INIS)

    Baskes, M.I.; Angelo, J.E.; Moody, N.R.

    1995-01-01

    Embedded Atom Method (EAM) potentials have been developed for the Ni/Al/H system. The potentials have been fit to numerous properties of this system. For example, these potentials represent the structural and elastic properties of bulk Ni, Al, Ni 3 Al, and NiAl quite well. In addition the potentials describe the solution and migration behavior of hydrogen in both nickel and aluminum. A number of calculations using these potentials have been performed. It is found that hydrogen strongly prefers sites in Ni 3 Al that are surrounded by 6 Ni atoms. Calculations of the trapping of hydrogen to a number of grain boundaries in Ni 3 Al have been performed as a function of hydrogen chemical potential at room temperature. The failure of these bicrystals under tensile stress has been examined and will be compared to the failure of pure Ni 3 Al boundaries. Boundaries containing a preponderance of nickel are severely weakened by hydrogen. In order to investigate the potential embrittlement of γ/γ' alloys, trapping of hydrogen to a spherical Ni 3 Al precipate in nickel as a function of chemical potential at room temperature has been calculated. It appears that the boundary is not a strong trap for hydrogen, hence embrittlement in these alloys is not primarily due to interactions of hydrogen with the γ/γ interface

  18. Multichannel Luminescence Properties of Mixed-Valent Eu2+/Eu3+ Coactivated SrAl3BO7 Nanocrystalline Phosphors for Near-UV LEDs.

    Science.gov (United States)

    Liu, Xiaoming; Xie, Weijie; Lü, Ying; Feng, Jingchun; Tang, Xinghua; Lin, Jun; Dai, Yuhua; Xie, Yu; Yan, Liushui

    2017-11-20

    Up to now, orchestrating the coexistence of Eu 2+ and Eu 3+ activators in a single host lattice has been an extremely difficult task, especially for the appearance of the characteristic emission of Eu 2+ and Eu 3+ in order to generate white light. Nevertheless, here we demonstrate a new Eu 2+ /Eu 3+ coactivated SrAl 3 BO 7 nanocrystalline phosphor with abundant and excellent multichannel luminescence properties. A series of Eu 2+ /Eu 3+ coactivated SrAl 3 BO 7 nanocrystalline phosphors were prepared through a Pechini-type sol-gel method followed by a reduction process. With excitation of UV/NUV light, the prepared SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphors show not only the characteristic f-f transitions of Eu 3+ ion ( 5 D J → 7 F J,J' , J, J' = 0-3), but also the 5d → 4f transitions of Eu 2+ ion with comparable intensity from 400 to 700 nm in the whole visible spectral region. The luminescence color of the SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphor can be tuned from blue, blue-green, white, and orange to orange-red by changing the excitation wavelength, the overall doping concentration of europium ions (Eu 2+ , Eu 3+ ), and the relative ratio of Eu 2+ to Eu 3+ ions to some extent. A single-phase white-light emission has been realized in SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphor. The obtained SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphor has potential application in the area of NUV white-light-emitting diodes.

  19. Electronic transport in the heavy fermion superconductors UPd2Al3 and UNi2Al3. Thin film studies

    International Nuclear Information System (INIS)

    Foerster, Michael

    2008-01-01

    This work addresses the electronical properties of the superconductors UPd 2 Al 3 and UNi 2 Al 3 on the basis of thin film experiments. Epitaxial thin film samples of UPd 2 Al 3 and UNi 2 Al 3 were prepared using UHV Molecular Beam Epitaxy (MBE). For UPd 2 Al 3 , the change of the growth direction from the intrinsic (001) to epitaxial (100) was predicted and sucessfully demonstrated using LaAlO3 substrates cut in (110) direction. With optimized deposition process parameters for UPd 2 Al 3 (100) on LaAlO 3 (110) superconducting samples with critical temperatures up to T c =1.75 K were obtained. UPd 2 Al 3 -AlO x -Ag mesa junctions with superconducting base electrode were prepared and shown to be in the tunneling regime. However, no signatures of a superconducting density of states were observed in the tunneling spectra. The resistive superconducting transition was probed for a possible dependence on the current direction. In contrast to UNi 2 Al 3 , the existence of such feature was excluded in UPd 2 Al 3 (100) thin films. The second focus of this work is the dependence of the resistive transition in UNi 2 Al 3 (100) thin films on the current direction. The experimental fact that the resistive transition occurs at slightly higher temperatures for I parallel a than for I parallel c can be explained within a model of two weakly coupled superconducting bands. Evidence is presented for the key assumption of the two-band model, namely that transport in and out of the ab-plane is generated on different, weakly coupled parts of the Fermi surface. Main indications are the angle dependence of the superconducting transition and the dependence of the upper critical field B c 2 on current and field orientation. Additionally, several possible alternative explanations for the directional splitting of the transition are excluded in this work. An origin due to scattering on crystal defects or impurities is ruled out, likewise a relation to ohmic heating or vortex dynamics. The

  20. Effect of Al{sup 3+} ions on fluorescence properties of Eu{sup 3+} ions in YbO{sub 3} phosphors

    Energy Technology Data Exchange (ETDEWEB)

    Balakrishnaiah, R.; Kim, Dong Woo; Yi, Soung Soo [Silla Univ., Busan (Korea, Republic of); Balakrishnaiah, R.; Jang, Kiwan; Lee, Ho Sueb [Changwon National Univ., Changwon (Korea, Republic of); Jeong, Jung Hyun [Pukyong National Univ., Busan (Korea, Republic of)

    2008-11-15

    Over the past few years, much attention has been paid to the synthesis and development of luminescence properties, of various lanthanide (Ln)doped materials that are useful for plasma display panels (PDPs). In order to display full colors in PDPs, red, green and blue phosphors are required. The PDP phosphors emit visible light under VUV excitation. The VUV pump photon is absorbed by the host lattice and the absorbed energy is transferred to the activator. Since the red emission, which comes from the {sup 5D0→7F2t}ransition, is hypersensitive to the lattice symmetry of the host crystal and will be relatively strong if the symmetry of the crystal is low, it is possible to tune the intensity of red emission by modifying the neighboring network design around Eu{sup 3}+{sup i}ons on introducing other atoms such as Ca, Sr, Ba, Zn, Al, Li, Sc, Bi, La, Gd, etc., into the ortho borate host lattice. Incorporation of these metal atoms into the host lattice of YBO{sup 3d}istorts the lattice to modify the energy absorption and transfer behaviors, resulting in an increased emission intensity. In this work, we have prepared Y{sup (}0.95-X)Eu{sup 0}.05{sup B}O{sup 3:}Al{sup 3}+{sup (}X){sup (}x=0, 0.05, 0.10, 0.15 and 0.20)phosphors by solid state reaction method by using the high purity chemicals of Y{sup 2O3,} H{sup 3B}O{sup 3,} Eu{sup 2O3a}nd Al{sup 2O3t}o study the effect of concentration of Al{sup 3}+{sup i}ons on the luminescence properties of Eu{sup 3}+{sup i}ons in YBO{sup 3p}hosphor. The prepared samples are characterized by XRD, SEM, photoluminescence excitation, photoluminescence emission and lifetime measurements. The results are also compared with those of earlier reported works.

  1. Control monocular 3D dinámico basado en imagen

    Directory of Open Access Journals (Sweden)

    Luis Hernández Santana

    2011-09-01

    Full Text Available Normal 0 21 false false false MicrosoftInternetExplorer4 /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Tabla normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin:0cm; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:10.0pt; font-family:"Times New Roman"; mso-ansi-language:#0400; mso-fareast-language:#0400; mso-bidi-language:#0400;} En este trabajo se presenta un sistema de control servovisual para regulación de posición de un robot manipulador con cámara en mano que se mueve en el espacio cartesiano 3D. El objetivo es control el robot de tal forma que la imagen de una esfera en movimiento se mantenga en el centro del plano imagen con radio constante. Se propone una estrategia de control con dos lazos en cascada, el lazo interno resuelve el control articular y el lazo externo implementa el control con realimentación visual. El robot y el sistema de visión son modelados para pequeñas variaciones alrededor del punto de operación para control de posición. Para estas condiciones se muestran la estabilidad del sistema y la respuesta en estado estable para trayectorias del objeto. Para ilustrar las prestaciones del sistema, se presentan los resultados experimentales para un manipulador ASEAIRB6.

  2. A 3D printed superconducting aluminium microwave cavity

    Energy Technology Data Exchange (ETDEWEB)

    Creedon, Daniel L. [School of Physics, University of Melbourne, Parkville, Victoria 3010 (Australia); Goryachev, Maxim; Kostylev, Nikita; Tobar, Michael E., E-mail: michael.tobar@uwa.edu.au [ARC Centre of Excellence for Engineered Quantum Systems, University of Western Australia, 35 Stirling Highway, Crawley, WA 6009 (Australia); Sercombe, Timothy B. [School of Mechanical and Chemical Engineering, University of Western Australia, 35 Stirling Highway, Crawley 6009 (Australia)

    2016-07-18

    3D printing of plastics, ceramics, and metals has existed for several decades and has revolutionized many areas of manufacturing and science. Printing of metals, in particular, has found a number of applications in fields as diverse as customized medical implants, jet engine bearings, and rapid prototyping in the automotive industry. Although many techniques are used for 3D printing metals, they commonly rely on computer controlled melting or sintering of a metal alloy powder using a laser or electron beam. The mechanical properties of parts produced in such a way have been well studied, but little attention has been paid to their electrical properties. Here we show that a microwave cavity (resonant frequencies 9.9 and 11.2 GHz) 3D printed using an Al-12Si alloy exhibits superconductivity when cooled below the critical temperature of aluminium (1.2 K), with a performance comparable with the common 6061 alloy of aluminium. Superconducting cavities find application in numerous areas of physics, from particle accelerators to cavity quantum electrodynamics experiments. The result is achieved even with a very large concentration of non-superconducting silicon in the alloy of 12.18%, compared with Al-6061, which has between 0.4% and 0.8%. Our results may pave the way for the possibility of 3D printing superconducting cavity configurations that are otherwise impossible to machine.

  3. A 3D printed superconducting aluminium microwave cavity

    International Nuclear Information System (INIS)

    Creedon, Daniel L.; Goryachev, Maxim; Kostylev, Nikita; Tobar, Michael E.; Sercombe, Timothy B.

    2016-01-01

    3D printing of plastics, ceramics, and metals has existed for several decades and has revolutionized many areas of manufacturing and science. Printing of metals, in particular, has found a number of applications in fields as diverse as customized medical implants, jet engine bearings, and rapid prototyping in the automotive industry. Although many techniques are used for 3D printing metals, they commonly rely on computer controlled melting or sintering of a metal alloy powder using a laser or electron beam. The mechanical properties of parts produced in such a way have been well studied, but little attention has been paid to their electrical properties. Here we show that a microwave cavity (resonant frequencies 9.9 and 11.2 GHz) 3D printed using an Al-12Si alloy exhibits superconductivity when cooled below the critical temperature of aluminium (1.2 K), with a performance comparable with the common 6061 alloy of aluminium. Superconducting cavities find application in numerous areas of physics, from particle accelerators to cavity quantum electrodynamics experiments. The result is achieved even with a very large concentration of non-superconducting silicon in the alloy of 12.18%, compared with Al-6061, which has between 0.4% and 0.8%. Our results may pave the way for the possibility of 3D printing superconducting cavity configurations that are otherwise impossible to machine.

  4. A 3D printed superconducting aluminium microwave cavity

    Science.gov (United States)

    Creedon, Daniel L.; Goryachev, Maxim; Kostylev, Nikita; Sercombe, Timothy B.; Tobar, Michael E.

    2016-07-01

    3D printing of plastics, ceramics, and metals has existed for several decades and has revolutionized many areas of manufacturing and science. Printing of metals, in particular, has found a number of applications in fields as diverse as customized medical implants, jet engine bearings, and rapid prototyping in the automotive industry. Although many techniques are used for 3D printing metals, they commonly rely on computer controlled melting or sintering of a metal alloy powder using a laser or electron beam. The mechanical properties of parts produced in such a way have been well studied, but little attention has been paid to their electrical properties. Here we show that a microwave cavity (resonant frequencies 9.9 and 11.2 GHz) 3D printed using an Al-12Si alloy exhibits superconductivity when cooled below the critical temperature of aluminium (1.2 K), with a performance comparable with the common 6061 alloy of aluminium. Superconducting cavities find application in numerous areas of physics, from particle accelerators to cavity quantum electrodynamics experiments. The result is achieved even with a very large concentration of non-superconducting silicon in the alloy of 12.18%, compared with Al-6061, which has between 0.4% and 0.8%. Our results may pave the way for the possibility of 3D printing superconducting cavity configurations that are otherwise impossible to machine.

  5. Immersive 3D geovisualisation in higher education

    Science.gov (United States)

    Philips, Andrea; Walz, Ariane; Bergner, Andreas; Graeff, Thomas; Heistermann, Maik; Kienzler, Sarah; Korup, Oliver; Lipp, Torsten; Schwanghart, Wolfgang; Zeilinger, Gerold

    2014-05-01

    Through geovisualisation we explore spatial data, we analyse it towards a specific questions, we synthesise results, and we present and communicate them to a specific audience (MacEachren & Kraak 1997). After centuries of paper maps, the means to represent and visualise our physical environment and its abstract qualities have changed dramatically since the 1990s - and accordingly the methods how to use geovisualisation in teaching. Whereas some people might still consider the traditional classroom as ideal setting for teaching and learning geographic relationships and its mapping, we used a 3D CAVE (computer-animated virtual environment) as environment for a problem-oriented learning project called "GEOSimulator". Focussing on this project, we empirically investigated, if such a technological advance like the CAVE make 3D visualisation, including 3D geovisualisation, not only an important tool for businesses (Abulrub et al. 2012) and for the public (Wissen et al. 2008), but also for educational purposes, for which it had hardly been used yet. The 3D CAVE is a three-sided visualisation platform, that allows for immersive and stereoscopic visualisation of observed and simulated spatial data. We examined the benefits of immersive 3D visualisation for geographic research and education and synthesized three fundamental technology-based visual aspects: First, the conception and comprehension of space and location does not need to be generated, but is instantaneously and intuitively present through stereoscopy. Second, optical immersion into virtual reality strengthens this spatial perception which is in particular important for complex 3D geometries. And third, a significant benefit is interactivity, which is enhanced through immersion and allows for multi-discursive and dynamic data exploration and knowledge transfer. Based on our problem-oriented learning project, which concentrates on a case study on flood risk management at the Wilde Weisseritz in Germany, a river

  6. A hybrid method for the computation of quasi-3D seismograms.

    Science.gov (United States)

    Masson, Yder; Romanowicz, Barbara

    2013-04-01

    The development of powerful computer clusters and efficient numerical computation methods, such as the Spectral Element Method (SEM) made possible the computation of seismic wave propagation in a heterogeneous 3D earth. However, the cost of theses computations is still problematic for global scale tomography that requires hundreds of such simulations. Part of the ongoing research effort is dedicated to the development of faster modeling methods based on the spectral element method. Capdeville et al. (2002) proposed to couple SEM simulations with normal modes calculation (C-SEM). Nissen-Meyer et al. (2007) used 2D SEM simulations to compute 3D seismograms in a 1D earth model. Thanks to these developments, and for the first time, Lekic et al. (2011) developed a 3D global model of the upper mantle using SEM simulations. At the local and continental scale, adjoint tomography that is using a lot of SEM simulation can be implemented on current computers (Tape, Liu et al. 2009). Due to their smaller size, these models offer higher resolution. They provide us with images of the crust and the upper part of the mantle. In an attempt to teleport such local adjoint tomographic inversions into the deep earth, we are developing a hybrid method where SEM computation are limited to a region of interest within the earth. That region can have an arbitrary shape and size. Outside this region, the seismic wavefield is extrapolated to obtain synthetic data at the Earth's surface. A key feature of the method is the use of a time reversal mirror to inject the wavefield induced by distant seismic source into the region of interest (Robertsson and Chapman 2000). We compute synthetic seismograms as follow: Inside the region of interest, we are using regional spectral element software RegSEM to compute wave propagation in 3D. Outside this region, the wavefield is extrapolated to the surface by convolution with the Green's functions from the mirror to the seismic stations. For now, these

  7. 3D Structure of Tillage Soils

    Science.gov (United States)

    González-Torre, Iván; Losada, Juan Carlos; Falconer, Ruth; Hapca, Simona; Tarquis, Ana M.

    2015-04-01

    Soil structure may be defined as the spatial arrangement of soil particles, aggregates and pores. The geometry of each one of these elements, as well as their spatial arrangement, has a great influence on the transport of fluids and solutes through the soil. Fractal/Multifractal methods have been increasingly applied to quantify soil structure thanks to the advances in computer technology (Tarquis et al., 2003). There is no doubt that computed tomography (CT) has provided an alternative for observing intact soil structure. These CT techniques reduce the physical impact to sampling, providing three-dimensional (3D) information and allowing rapid scanning to study sample dynamics in near real-time (Houston et al., 2013a). However, several authors have dedicated attention to the appropriate pore-solid CT threshold (Elliot and Heck, 2007; Houston et al., 2013b) and the better method to estimate the multifractal parameters (Grau et al., 2006; Tarquis et al., 2009). The aim of the present study is to evaluate the effect of the algorithm applied in the multifractal method (box counting and box gliding) and the cube size on the calculation of generalized fractal dimensions (Dq) in grey images without applying any threshold. To this end, soil samples were extracted from different areas plowed with three tools (moldboard, chissel and plow). Soil samples for each of the tillage treatment were packed into polypropylene cylinders of 8 cm diameter and 10 cm high. These were imaged using an mSIMCT at 155keV and 25 mA. An aluminium filter (0.25 mm) was applied to reduce beam hardening and later several corrections where applied during reconstruction. References Elliot, T.R. and Heck, R.J. 2007. A comparison of 2D and 3D thresholding of CT imagery. Can. J. Soil Sci., 87(4), 405-412. Grau, J, Médez, V.; Tarquis, A.M., Saa, A. and Díaz, M.C.. 2006. Comparison of gliding box and box-counting methods in soil image analysis. Geoderma, 134, 349-359. González-Torres, Iván. Theory and

  8. Effect of grain size on yield strength of Ni3Al and other alloys

    International Nuclear Information System (INIS)

    Takeyama, M.; Liu, C.T.

    1988-01-01

    This paper analyzes the effect of grain size on yield stress of ordered Ni 3 Al and Zr 3 Al, and mild steels that show Lueders band propagation after yielding, using the Hall--Petch relation, σ/sub y/ = σ 0 +k/sub y/ d -1 /sup // 2 , and the new relation proposed by Schulson et al., σ/sub y/ = σ 0 +kd/sup -(//sup p//sup +1)/2/ [Schulson et al., Acta Metall. 33, 1587 (1985)]. The major emphasis is placed on the analysis of Ni 3 Al data obtained from published and new results, with a careful consideration of the alloy stoichiometry effect. All data, except for binary stoichiometric Ni 3 Al prepared by powder extrusion, fit the Hall--Petch relation, whereas the data from boron-doped Ni 3 Al and mild steels do not follow the Schulson relation. However, no conclusion can be made simply from the curve fitting using either relation. The results are also discussed in terms of Lueders strain and alloy preparation methods. On the basis of the Hall--Petch analysis, the small slope k/sub y/ is obtained only for hypostoichiometric Ni 3 Al with boron, which would be related to a stronger segregation of boron in nickel-rich Ni 3 Al. In addition, the potency for the solid solution strengthening effect of boron is found to be much higher for stoichiometric Ni 3 Al than for hypostoichiometric alloys

  9. Lagrangian MHD in 2D and 3D

    International Nuclear Information System (INIS)

    Oliphant, T.A.; Morel, J.E.; Gula, W.P.; Pfeufer, G.W.

    1997-01-01

    The cell-centered diffusion differencing scheme presented by Morel et al. has been applied to magnetic diffusion associated with Lagrangian hydrodynamic codes. Thus, the method applies to non-orthogonal meshes. Although the present application involves structured meshes, the method applies equally well to unstructured meshes. Morel's example of application is to 2D diffusion using Ficke's law. Thus, a volume integral approach is applied to the divergence operator. In 2D magnetic diffusion symmetry allows the use of an area integral approach involving the field components normal to the area, e.g. A-theta and B-theta. Instead of a divergence of a term proportional to the field gradient a curl of a term proportional to the curl of the field is used. An essential fact that allows this procedure is that the solenoidal property of the magnetic field is automatic. In the case of 3D it is necessary to return to the volumetric integral approach and to use rectangular components of the vector potential. Successful benchmarks have been run in comparison with the 1D code RAVEN. A typical example is that of a metal cylinder being compressed by a magnetic field applied at the outer boundary. So far, the 3D diffusion model has been tested in the orthogonal case and found to preserve the linear, homogeneous solution. Results of these and further tests are presented

  10. Stereo 3D spatial phase diagrams

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Jinwu, E-mail: kangjw@tsinghua.edu.cn; Liu, Baicheng, E-mail: liubc@tsinghua.edu.cn

    2016-07-15

    Phase diagrams serve as the fundamental guidance in materials science and engineering. Binary P-T-X (pressure–temperature–composition) and multi-component phase diagrams are of complex spatial geometry, which brings difficulty for understanding. The authors constructed 3D stereo binary P-T-X, typical ternary and some quaternary phase diagrams. A phase diagram construction algorithm based on the calculated phase reaction data in PandaT was developed. And the 3D stereo phase diagram of Al-Cu-Mg ternary system is presented. These phase diagrams can be illustrated by wireframe, surface, solid or their mixture, isotherms and isopleths can be generated. All of these can be displayed by the three typical display ways: electronic shutter, polarization and anaglyph (for example red-cyan glasses). Especially, they can be printed out with 3D stereo effect on paper, and watched by the aid of anaglyph glasses, which makes 3D stereo book of phase diagrams come to reality. Compared with the traditional illustration way, the front of phase diagrams protrude from the screen and the back stretches far behind of the screen under 3D stereo display, the spatial structure can be clearly and immediately perceived. These 3D stereo phase diagrams are useful in teaching and research. - Highlights: • Stereo 3D phase diagram database was constructed, including binary P-T-X, ternary, some quaternary and real ternary systems. • The phase diagrams can be watched by active shutter or polarized or anaglyph glasses. • The print phase diagrams retains 3D stereo effect which can be achieved by the aid of anaglyph glasses.

  11. Electronic structures, elastic properties, and minimum thermal conductivities of cermet M{sub 3}AlN

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jin [Faculty of Materials and Energy, Southwest University, Chongqing 400715 (China); Key Laboratory of Liquid–Solid Structural Evolution and Processing of Materials, Ministry of Education, Shandong University, Jinan 250061 (China); Chen, ZhiQian, E-mail: chen_zq@swu.edu.cn [Faculty of Materials and Energy, Southwest University, Chongqing 400715 (China); Li, ChunMei; Li, Feng; Nie, ChaoYin [Faculty of Materials and Energy, Southwest University, Chongqing 400715 (China)

    2014-08-15

    The electronic structures and elastic anisotropies of cubic Ti{sub 3}AlN, Zr{sub 3}AlN, and Hf{sub 3}AlN are investigated by pseudopotential plane-wave method based on density functional theory. At the Fermi level, the electronic structures of these compounds are successive with no energy gap between conduct and valence bands, and exhibit metallicity in ground states. In valence band of each partial density of states, the different orbital electrons indicate interaction of corresponding atoms. In addition, the anisotropy of Hf{sub 3}AlN is found to be significantly different from that of Ti{sub 3}AlN and Zr{sub 3}AlN, which involve the differences in the bonding strength. It is notable that Hf{sub 3}AlN is a desired thermal barrier material with the lowest thermal conductivity at high temperature among the three compounds. - Graphical abstract: 1.Young's moduli of anti-perovskite Ti{sub 3}AlN, Zr{sub 3}AlN, and Hf{sub 3}AlN in full space. 2.Electron density differences on crystal planes (1 0 0), (2 0 0), and (1 1 0) of anti-perovskite Zr{sub 3}AlN. - Highlights: • We calculated three anti-perovskite cermets with first-principles theory. • We illustrated 3D Young modulus and found the anomalous anisotropy. • We explained the anomaly and calculated the minimum thermal conductivities.

  12. Growth of porous anodized alumina on the sputtered aluminum films with 2D-3D morphology for high specific surface area

    Science.gov (United States)

    Liao, M. W.; Chung, C. K.

    2014-08-01

    The porous anodic aluminum oxide (AAO) with high-aspect-ratio pore channels is widely used as a template for fabricating nanowires or other one-dimensional (1D) nanostructures. The high specific surface area of AAO can also be applied to the super capacitor and the supporting substrate for catalysis. The rough surface could be helpful to enhance specific surface area but it generally results in electrical field concentration even to ruin AAO. In this article, the aluminum (Al) films with the varied 2D-3D morphology on Si substrates were prepared using magnetron sputtering at a power of 50 W-185 W for 1 h at a working pressure of 2.5 × 10-1 Pa. Then, AAO was fabricated from the different Al films by means of one-step hybrid pulse anodizing (HPA) between the positive 40 V and the negative -2 V (1 s:1 s) for 3 min in 0.3 M oxalic acid at a room temperature. The microstructure and morphology of Al films were characterized by X-ray diffraction, scanning electron microscope and atomic force microscope, respectively. Some hillocks formed at the high target power could be attributed to the grain texture growth in the normal orientation of Al(1 1 1). The 3D porous AAO structure which is different from the conventional 2D planar one has been successfully demonstrated using HPA on the film with greatly rough hillock-surface formed at the highest power of 185 W. It offers a potential application of the new 3D AAO to high specific surface area devices.

  13. Data Assimilation of Lightning using 1D+3D/4D WRF Var Assimilation Schemes with Non-Linear Observation Operators

    Science.gov (United States)

    Navon, M. I.; Stefanescu, R.; Fuelberg, H. E.; Marchand, M.

    2012-12-01

    NASA's launch of the GOES-R Lightning Mapper (GLM) in 2015 will provide continuous, full disc, high resolution total lightning (IC + CG) data. The data will be available at a horizontal resolution of approximately 9 km. Compared to other types of data, the assimilation of lightning data into operational numerical models has received relatively little attention. Previous efforts of lightning assimilation mostly have employed nudging. This paper will describe the implementation of 1D+3D/4D Var assimilation schemes of existing ground-based WTLN (Worldwide Total Lightning Network) lightning observations using non-linear observation operators in the incremental WRFDA system. To mimic the expected output of GLM, the WTLN data were used to generate lightning super-observations characterized by flash rates/81 km2/20 min. A major difficulty associated with variational approaches is the complexity of the observation operator that defines the model equivalent of lightning. We use Convective Available Potential Energy (CAPE) as a proxy between lightning data and model variables. This operator is highly nonlinear. Marecal and Mahfouf (2003) have shown that nonlinearities can prevent direct assimilation of rainfall rates in the ECMWF 4D-VAR (using the incremental formulation proposed by Courtier et al. (1994)) from being successful. Using data from the 2011 Tuscaloosa, AL tornado outbreak, we have proved that the direct assimilation of lightning data into the WRF 3D/4D - Var systems is limited due to this incremental approach. Severe threshold limits must be imposed on the innovation vectors to obtain an improved analysis. We have implemented 1D+3D/4D Var schemes to assimilate lightning observations into the WRF model. Their use avoids innovation vector constrains from preventing the inclusion of a greater number of lightning observations Their use also minimizes the problem that nonlinearities in the moist convective scheme can introduce discontinuities in the cost function

  14. Diffusion-induced quadrupole relaxation of 27Al nuclei in dilute Al-Ti, Al-Cr, Al-Mn, and Al-Cu alloys at high temperatures

    International Nuclear Information System (INIS)

    Bottyan, L.; Beke, D.L.; Tompa, K.

    1983-01-01

    The temperature dependence of the laboratory frame spin-lattice relaxation time of 27 Al nuclei is measured in 5N Al and in dilute Al-Ti, Al-Cr, Al-Mn, and Al-Cu alloys at 5.7 and 9.7 MHz resonance frequencies. The relaxation in pure aluminium is found to be purely due to the conduction electrons. An excess T 1 -relaxation contribution is detected in all Al-3d alloys investigated above 670 K. The excess relaxation rate is proportional to the impurity content and the temperature dependence of the excess contribution is of Arrhenius-type with an activation energy of (1.3 +- 0.3) eV for all of the investigated alloys. The relaxation contribution is found to be quadrupolar in origin and is caused by the relative diffusional jumps of solute atoms and Al atoms relatively far from the impurity. (author)

  15. Superstructure formation in PrNi{sub 2}Al{sub 3} and ErPd{sub 2}Al{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Eustermann, Fabian; Hoffmann, Rolf-Dieter [Muenster Univ. (Germany). Inst. fuer Anorganische und Analytische Chemie; Janka, Oliver [Muenster Univ. (Germany). Inst. fuer Anorganische und Analytische Chemie; Oldenburg Univ. (Germany). Inst. fuer Chemie

    2017-09-01

    The intermetallic phase ErPd{sub 2}Al{sub 3} was obtained by arc-melting of the elements and subsequent annealing for crystal growth. The sample was studied by X-ray diffraction on powders and single crystals. The structure of ErPd{sub 2}Al{sub 3} was refined from X-ray diffraction data and revealed a superstructure of PrNi{sub 2}Al{sub 3} - a CaCu{sub 5} derivative (P6/m, a=1414.3(1), c=418.87(3) pm wR=0.0820, 1060 F{sup 2} values, 48 variables). The same superstructure was subsequently found for PrNi{sub 2}Al{sub 3} (P6/m, a=1407.87(4), c=406.19(2) pm, wR=0.0499, 904 F{sup 2} values, 47 variables). In the crystal structure, the aluminium and transition metal atoms form a polyanionic network according to [T{sub 2}Al{sub 3}]{sup δ-}, while rare earth atoms fill cavities within the networks. They are coordinated by six transition metal and twelve aluminum atoms. In contrast to the PrNi{sub 2}Al{sub 3} type structure reported so far, two crystallographic independent rare-earth sites are found of which one (1b) is shifted by 1/2 z, causing a distortion in the structure along with a recoloring of the T and Al atoms in the network.

  16. Magnetization anomaly of Nb3Al strands and instability of Nb3Al Rutherford cables

    International Nuclear Information System (INIS)

    Yamada, Ryuji; Kikuchi, Akihiro; Wake, Masayoshi

    2006-01-01

    Using a Cu stabilized Nb 3 Al strand with Nb matrix, a 30 meter long Nb 3 Al Rutherford cable was made by a collaboration of Fermilab and NIMS. Recently the strand and cable were tested. In both cases instability was observed at around 1.5 Tesla. The magnetization of this Nb 3 Al strand was measured first using a balanced coil magnetometer at 4.2 K. Strands showed an anomalously large magnetization behavior around at 1.6 T, which is much higher than the usual B c2 ∼ 0.5 Tesla (4.2 K) of Nb matrix. This result is compared with the magnetization data of short strand samples using a SQUID magnetometer, in which a flux-jump signal was observed at 0.5 Tesla, but not at higher field. As a possible explanation for this magnetization anomaly, the interfilament coupling through the thin Nb films in the strands is suggested. The instability problem observed in low field tests of the Nb 3 Al Rutherford cables is attributed to this effect

  17. Modelado Energético de Convertidores Primarios para el Aprovechamiento de las Energías Renovables Marinas

    Directory of Open Access Journals (Sweden)

    Amable López

    2014-04-01

    Full Text Available Resumen: El objetivo principal de este artículo es presentar los métodos más habituales de aprovechamiento de distintos tipos de energías renovables procedentes del mar y analizar los modelos energéticos de los dispositivos utilizados para su explotación. Estos modelos son necesarios para el diseño del dispositivo así como para el estudio de su comportamiento dinámico. Su conocimiento resulta imprescindible también para su simulación dinámica y para el diseño de los algoritmos de control necesarios para conseguir una optimización energética y económica. En este trabajo se presentan algunos de los diferentes tipos de energías del mar, y se j ustifica el interés en el desarrollo de dispositivos específicos para el aprovechamiento de las corrientes marinas y de las olas, junto con una pequeña clasificación en función de la profundidad del agua en la zona de instalación de estos dispositivos. Para los convertidores de energía de las olas, generalmente, de tipo resonante, se presenta una metodología de tipo general, analizando los distintos campos de fuerzas actuantes y los métodos de obtención de las respuestas temporal y frecuencial. Para los dispositivos de aprovechamiento de las corrientes, se propone una metodología simplificada de modelado dinámico que puede ser utilizada en análisis del dispositivo concreto. Para ello se tiene en cuenta los perfiles hidrodinámicos que utilizan estos dispositivos, los datos del perfil de la corriente con la profundidad y del modelo de oleaje, y la dinámica propia del conjunto multiplicadora y generador eléctrico. La metodología propuesta se aplica al estudio de un caso concreto, correspondiente a un rotor de eje horizontal de un convertidor de energía de las corrientes. Los resultados obtenidos permiten analizar los efectos del oleaje y de las condiciones de flujo de la corriente no uniforme sobre las magnitudes energéticas más importantes. Abstract: The main objective of

  18. COMPARISON OF 2D AND 3D VIDEO DISPLAYS FOR TEACHING VITREORETINAL SURGERY.

    Science.gov (United States)

    Chhaya, Nisarg; Helmy, Omar; Piri, Niloofar; Palacio, Agustina; Schaal, Shlomit

    2017-07-11

    To compare medical students' learning uptake and understanding of vitreoretinal surgeries by watching either 2D or 3D video recordings. Three vitreoretinal procedures (tractional retinal detachment, exposed scleral buckle removal, and four-point scleral fixation of an intraocular lens [TSS]) were recorded simultaneously with a conventional recorder for two-dimensional viewing and a VERION 3D HD system using Sony HVO-1000MD for three-dimensional viewing. Two videos of each surgery, one 2D and the other 3D, were edited to have the same content side by side. One hundred UMass medical students randomly assigned to a 2D group or 3D, then watched corresponding videos on a MacBook. All groups wore BiAL Red-blue 3D glasses and were appropriately randomized. Students filled out questionnaires about surgical steps or anatomical relationships of the pathologies or tissues, and their answers were compared. There was no significant difference in comprehension between the two groups for the extraocular scleral buckle procedure. However, for the intraocular TSS and tractional retinal detachment videos, the 3D group performed better than 2D (P < 0.05) on anatomy comprehension questions. Three-dimensional videos may have value in teaching intraocular ophthalmic surgeries. Surgical procedure steps and basic ocular anatomy may have to be reviewed to ensure maximal teaching efficacy.

  19. Phase constituents and microstructure of laser cladding Al{sub 2}O{sub 3}/Ti{sub 3}Al reinforced ceramic layer on titanium alloy

    Energy Technology Data Exchange (ETDEWEB)

    Li Jianing [Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Department of Materials Science, Shandong University, Jing Shi Road 17923, Jinan 250061, Shandong (China); Chen Chuanzhong, E-mail: czchen@sdu.edu.cn [Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Department of Materials Science, Shandong University, Jing Shi Road 17923, Jinan 250061, Shandong (China); Lin Zhaoqing [Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Department of Materials Science, Shandong University, Jing Shi Road 17923, Jinan 250061, Shandong (China); Squartini, Tiziano [INFM - Department of Physics, Siena University, Siena 53100 (Italy)

    2011-04-07

    Research highlights: > In this study, Fe{sub 3}Al has been chosen as cladding powder due to its excellent properties of wear resistance and high strength, etc. > Laser cladding of Fe{sub 3}Al + TiB{sub 2}/Al{sub 2}O{sub 3} pre-placed alloy powder on Ti-6Al-4V alloy substrate can form the Ti{sub 3}Al/Fe{sub 3}Al + TiB{sub 2}/Al{sub 2}O{sub 3} ceramic layer, which can increase wear resistance of substrate. > In cladding process, Al{sub 2}O{sub 3} can react with TiB{sub 2} leading to formation of Ti{sub 3}Al and B. > This principle can be used to improve the Fe{sub 3}Al + TiB{sub 2} laser-cladded coating. - Abstract: Laser cladding of the Fe{sub 3}Al + TiB{sub 2}/Al{sub 2}O{sub 3} pre-placed alloy powder on Ti-6Al-4V alloy can form the Ti{sub 3}Al/Fe{sub 3}Al + TiB{sub 2}/Al{sub 2}O{sub 3} ceramic layer, which can greatly increase wear resistance of titanium alloy. In this study, the Ti{sub 3}Al/Fe{sub 3}Al + TiB{sub 2}/Al{sub 2}O{sub 3} ceramic layer has been researched by means of electron probe, X-ray diffraction, scanning electron microscope and micro-analyzer. In cladding process, Al{sub 2}O{sub 3} can react with TiB{sub 2} leading to formation of amount of Ti{sub 3}Al and B. This principle can be used to improve the Fe{sub 3}Al + TiB{sub 2} laser cladded coating, it was found that with addition of Al{sub 2}O{sub 3}, the microstructure performance and micro-hardness of the coating was obviously improved due to the action of the Al-Ti-B system and hard phases.

  20. Gd3+-ESR and magnetic susceptibility of GdCu4Al8 and GdMn4Al8

    International Nuclear Information System (INIS)

    Coldea, R.; Coldea, M.; Pop, I.

    1994-01-01

    Gd ESR of GdCu 4 Al 8 and GdMn 4 Al 8 and magnetic susceptibility of GdCu 4 Al 8 , GdMn 4 Al 8 , and YMn 4 Al 8 were measured in the temperature range of 290K--460K and 90K--1050K, respectively. The occurrence of the Mn moment in YMn 4 Al 8 and GdMn 4 Al 8 is strongly correlated with the critical value of d∼2.6 angstrom of the Mn-Mn distance below which the Mn moment is not stable. The experimental data for GdMn 4 Al 8 , compared with the data for the isostructural compounds GdCu 4 Al 8 and YMn 4 Al 8 , show that near the critical value of d, the existence of Mn moment depends not only on the value of d, but also on the local magnetic surroundings. It has been revealed that the magnetic character of Mn moment in YMn 4 Al 8 and GdMn 4 Al 8 changes from an itinerant electron type to a local-moment type with increasing temperature

  1. A 3D-Printed Sensor for Monitoring Biosignals in Small Animals

    OpenAIRE

    Cho, Sung-Joon; Byun, Donghak; Nam, Tai-Seung; Choi, Seok-Yong; Lee, Byung-Geun; Kim, Myeong-Kyu; Kim, Sohee

    2017-01-01

    Although additive manufacturing technologies, also known as 3D printing, were first introduced in the 1980s, they have recently gained remarkable popularity owing to decreased costs. 3D printing has already emerged as a viable technology in many industries; in particular, it is a good replacement for microfabrication technology. Microfabrication technology usually requires expensive clean room equipment and skilled engineers; however, 3D printing can reduce both cost and time dramatically. Al...

  2. Formalizing Implementable Constraints in the INTERLIS Language for Modelling Legal 3D RRR Spaces and 3D Physical Objects

    NARCIS (Netherlands)

    Kalogianni, Eftychia; Dimopoulou, Efi; Quak, C.W.; van Oosterom, P.J.M.; van Oosterom, P.J.M.; Dimopoulou, Efi; Fendel, Elfriede M.

    2016-01-01

    Building Information Models (e.g. BIM, IFC) and virtual 3D city models (e.g. CityGML) are revolutionising the way we manage information about cities. The main focus of such models is on the physical and functional characteristics of urban structures (Aien et al, 2015). On the other hand cadastral

  3. Microstructure of two phases alloy Al{sub 3}Ti/Al{sub 3}Ti{sub 0.75}Fe{sub 0.25}; Microestructura de una aleacion de dos fases Al{sub 3}Ti/Al{sub 3}Ti{sub 0.75}Fe{sub 0.25}

    Energy Technology Data Exchange (ETDEWEB)

    Angeles, C; Rosas, G; Perez, R [Instituto Nacional de Investigaciones Nucleares, Departamento de Sintesis y Caracterizacion de Materiales, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    1998-07-01

    The titanium-aluminium system presents three intermetallic compounds from those Al{sub 3}Ti is what less attention has received. The objective of this work is to generate and characterize the microstructure of multiphase alloys nearby to Al{sub 3}Ti compound through Fe addition as alloying. This is because it has been seen that little precipitates of Al{sub 2}Ti phase over Al{sub 3}Ti intermetallic compound increases its ductility. (Author)

  4. Eff icient energy back transfer from Ce{sup 3+} 5d state to Pr{sup 3+} {sup 1}D{sub 2} level in Lu{sub 3}Al{sub 5}O{sub 12} upon Pr{sup 3+} 4f5d excitation

    Energy Technology Data Exchange (ETDEWEB)

    Dan Wu [State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, Jilin (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Hao, Zhendong; Zhang, Xia; Pan, Guo-Hui; Luo, Yongshi; Zhang, Ligong; Zhao, Haifeng [State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, Jilin (China); Zhang, Jiahua, E-mail: zhangjh@ciomp.ac.cn [State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, Jilin (China)

    2017-06-15

    The step energy transfers from Pr{sup 3+} 4f5d state to Ce{sup 3+} 5d state followed by energy back transfer from Ce{sup 3+} 5d state to Pr{sup 3+} {sup 1}D{sub 2} level are studied. The Ce{sup 3+}→Pr{sup 3+} energy back transfer upon Pr{sup 3+} 4f5d excitation is found to be more efficient than the normal Ce{sup 3+}→Pr{sup 3+} energy transfer upon Ce{sup 3+} 5d excitation. The efficient energy back transfer is attributed to preferential excitation of the Ce{sup 3+} ion with an adjacent Pr{sup 3+} surrounding in Pr{sup 3+}→Ce{sup 3+} energy transfer of the first step, whereas Ce{sup 3+} is excited randomly in the normal energy transfer. The efficiencies of Ce{sup 3+}→Pr{sup 3+} energy back transfer as a function of Ce{sup 3+} and Pr{sup 3+} concentration are evaluated, respectively.

  5. Studies on SiC(p) reinforced Al-Al sub 3 Ni eutectic matrix composites

    International Nuclear Information System (INIS)

    Masrom, A.K.; Foo, L.C.; Ismail, A.B.

    1996-01-01

    An investigation on processing of Al-5.69wt% Ni eutectic with SiC particulate composites is reported. The intermetallic composites are prepared by elemental powder metallurgy route and sintered at two different temperatures, i.e., 600 degree C and 620 degree C. Results show that the metal matrix was Al-Al sub 3 Ni eutectic. The phase analysis by XRD identified the presence of Al sub 3 Ni and Al as dominant phases together with silicon and Al sub 4 C sub 3 phase as minor phases. The Al sub 4 C sub 3 and Si phases are formed during sintering due to SiC-Al interface reaction. SEM micrographs also reveal the formation of microvoid surrounding the SiC particle

  6. [Al3+ Absorption and Assimilation by Four Ectomycorrhizal Fungi].

    Science.gov (United States)

    Wang, Ming-xia; Yuan, Ling; Huang, Jian-guo; Zhou, Zhi-feng

    2015-09-01

    The present experiment was carried out in order to know the resistance mechanism of the ectomycorrhizal (ECM) fungi under Al stress, to establish the theoretical foundation to alleviate the Al toxicity of trees, to guide the selection of Al-resisted ECM fungi and preserve forest health. The absorption and assimilation of Al3+ by four ECM fungi [Pisolithus tinctorius (Pt 715), Suillus luteus (Sl 08 and Sl 14), Gyroporus cyanescens (Gc 99)], which were isolated from different forest soils, were investigated in pure culture in liquid media. The growths of Pt 715 and Sl 08 were less affected by Al3+, but growths of S114 and Gc 99 were obviously inhibited by Al3+. With the increasing of Al3+ concentration in culture, the absorption and assimilation of Al3+ by four ECM fungi increased. It indicated that the concentration of Al3+ in environments might be the primary factor determining the Al3+ content in the cell of each tested fungi. Amounts of Al3+ absorbed (in total or calculated in unit hyphae) by the Al3+ tolerant strains (Pt 715 and Sl 08) were significantly lower than those by the Al3+ sensitive strains (S1 14 and Gc 99), which illustrated that reducing the absorption of Al3+ under Al3+ stress environment might be an effective approach to alleviate the Al3+ poison for these Al3+ tolerant strains. Furthermore, Al3+ stress could stimulate the ECM fungi to assimilate more N, P, and K, which might indicate that increasing requirement of the nutrients also could be helpful for ECM fungi to fight against the harmful effects caused by Al3+ stress.

  7. Herramientas de software con licencia pública general para el modelado por elementos finitos

    Directory of Open Access Journals (Sweden)

    CARLOS GALEANO

    2007-01-01

    Full Text Available En el presente artículo se presentan los resultados de una revisión realizada a varios programas con licencias GPL para el modelamiento de problemas con elementos finitos. Este estudio permitió realizar la caracterización de estos programas teniendo en cuenta criterios como el tipo de análisis permitido, la compatibilidad con programas CAD, el tipo de soporte ofrecido, la actualización de las versiones, el tipo de interfaz de usuario implementado y la curva de aprendizaje para nuevos usuarios, entre otros. Posteriormente se estudiaron tres casos diferentes, los cuales fueron modelados con elementos finitos empleando distintos programas GPL. En la parte final del documento se comparan los resultados obtenidos con software libre, los arrojados por un programa comercial (Ansys, y los modelos analíticos derivados de la solución de la ecuación diferencial que rige el fenómeno particular, obteniendo una convergencia aceptable entre todos los resultados

  8. Robótica Submarina: Conceptos, Elementos, Modelado y Control

    Directory of Open Access Journals (Sweden)

    Héctor A. Moreno

    2014-01-01

    Full Text Available Resumen: Los robots submarinos han revolucionado la exploración del fondo marino. Por otro lado, estos robots han permitido realizar operaciones en aguas profundas sin la necesidad de enviar un veh́ıculo tripulado por humanos. El futuro de esta tecnoloǵıa es prometedor. El propo’ito de este documento es servir de primer contacto con este tema y va dirigido a estudiantes de postgrado, ingenieros e investigadores con intere’ en la robótica submarina. Adema’, se reporta el estado actual de los diferentes aspectos que giran alrededor de esta área de la robótica. Abstract: Underwater robots have considerably changed the exploration of deep sea. Even more, these robots allow performing opera- tions in remote subsea installations. The future of this techno- logy is promising. The purpose of this work is to provide an insight into the subject to postgraduate students, engineers and researchers interested in underwater robotics. Additionally, this work presents a survey of the different subjects that this branch of robotics include. Palabras clave: Robots Submarinos, Introducción, Componentes, Modelado, Control, Estado del Arte, Keywords: Underwater Robotics, Introduction, Components, Modeling, Control, State of the Art.

  9. Surface morphology of Al0.3Ga0.7N/Al2O3-high electron mobility transistor structure.

    Science.gov (United States)

    Cörekçi, S; Usanmaz, D; Tekeli, Z; Cakmak, M; Ozçelik, S; Ozbay, E

    2008-02-01

    We present surface properties of buffer films (AIN and GaN) and Al0.3Gao.zN/Al2O3-High Electron Mobility Transistor (HEMT) structures with/without AIN interlayer grown on High Temperature (HT)-AIN buffer/Al2O3 substrate and Al2O3 substrate. We have found that the GaN surface morphology is step-flow in character and the density of dislocations was about 10(8)-10(9) cm(-2). The AFM measurements also exhibited that the presence of atomic steps with large lateral step dimension and the surface of samples was smooth. The lateral step sizes are in the range of 100-250 nm. The typical rms values of HEMT structures were found as 0.27, 0.30, and 0.70 nm. HT-AIN buffer layer can have a significant impact on the surface morphology of Al0.3Ga0.7N/Al2O3-HEMT structures.

  10. Spin-Orbit Interaction and Kondo Scattering at the PrAlO3/SrTiO3 Interface

    Science.gov (United States)

    Mozaffari, Shirin; Guchhait, Samaresh; Markert, John

    We have investigated the effect of oxygen content, in the PO2 range of 6 ×10-6 - 1 ×10-3 torr, on the spin-orbit (SO) interaction at PrAlO3/SrTiO3 interface. The most-conducting 2-D-like PrAlO3 interfaces were not as conducting as comparable LaAlO3 samples, indicating either a steric or mixed-valent effect. The least-conducting, most oxygenated PrAlO3 interface exhibits hole conductivity, a departure from the typical electron-doped behavior. For 10-5 and 10-4 torr samples, high-temperature metallic behavior is accompanied by an upturn in resistivity at low temperatures, consistent with Kondo scattering theory; analysis gives a Kondo temperature 17 K. The magnetoresistance (MR) for the low PO2-grown samples was modeled with a positive part due to weak anti-localization (WAL) from a strong SO interaction, and a negative part due to the Kondo effect. The variation of MR suggests a strong SO interaction for the 10-5 torr sample with HSO = 1.25 T in both field orientations. The WAL effect is smaller for higher PO2-grown samples, where the high-field MR is dominated by the Kondo effect.

  11. Combustion synthesis of AlB2-Al2O3 composite powders with AlB2 nanowire structures

    Science.gov (United States)

    Yang, Pan; Xiao, Guoqing; Ding, Donghai; Ren, Yun; Yang, Shoulei; Lv, Lihua; Hou, Xing

    2018-05-01

    Using of Al and B2O3 powders as starting materials, and Mg-Al alloy as additives, AlB2-Al2O3 composite powders with AlB2 nanowire structures were successfully fabricated via combustion synthesis method in Ar atmosphere at a pressure of 1.5 MPa. The effect of different amount of Mg-Al alloy on the phase compositions and morphology of the combustion products was investigated. The results revealed that AlB2 and Al2O3 increased, whereas Al decreased with the content of Mg-Al alloy increasing. The impurities MgAl2O4 and AlB12 would exist in the sample with adding of 18 wt% Mg-Al alloy. Interestingly, FESEM/TEM/EDS results showed that AlB2 nanowires were observed in the products when the content of Mg-Al alloy is 6 wt% and 12 wt%. The more AlB2 nanowires can be found as the content of Mg-Al alloy increased. And the yield of AlB2 nanowires with the diameter of about 200 nanometers (nm) and the length up to several tens of micrometers (μm) in the combustion product is highest when the content of Mg-Al alloy is 12 wt%. The vapor, such as Mg-Al (g), B2O2 (g), AlO (g) and Al2O (g), produced during the process of combustion synthesis, reacted with each other to yield AlB2 nanowires by vapor-solid (VS) mechanism and the corresponding model was also proposed.

  12. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al nanoparticles as a high microwave absorption material

    Energy Technology Data Exchange (ETDEWEB)

    Pang, Yu; Xie, Xiubo; Li, Da [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China); Chou, Wusheng [School of Mechanical Engineering and Automation, Beihang University, Beijing 100191 (China); Liu, Tong, E-mail: tongliu@buaa.edu.cn [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China)

    2017-03-15

    The Al{sub 3}Ni{sub 2}@Al nanoparticles (NPs) were prepared from Ni{sub 45}Al{sub 55} master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m{sup 2}/g and big pore volume of 0.507 cc/g. The saturation magnetization (M{sub S}) and coercivity (H{sub C}) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m{sup 2}/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  13. Raman and fluorescence contributions to the resonant inelastic soft x-ray scattering on LaAlO3/SrTiO3 heterostructures

    Science.gov (United States)

    Pfaff, F.; Fujiwara, H.; Berner, G.; Yamasaki, A.; Niwa, H.; Kiuchi, H.; Gloskovskii, A.; Drube, W.; Gabel, J.; Kirilmaz, O.; Sekiyama, A.; Miyawaki, J.; Harada, Y.; Suga, S.; Sing, M.; Claessen, R.

    2018-01-01

    We present a detailed study of the Ti 3 d carriers at the interface of LaAlO3/SrTiO3 heterostructures by high-resolution resonant inelastic soft x-ray scattering (RIXS), with special focus on the roles of overlayer thickness and oxygen vacancies. Our measurements show the existence of interfacial Ti 3 d electrons already below the critical thickness for conductivity. The (total) interface charge carrier density increases up to a LaAlO3 overlayer thickness of 6 unit cells before it levels out. Furthermore, we observe strong Ti 3 d charge carrier doping by oxygen vacancies. The RIXS data combined with photoelectron spectroscopy and transport measurements indicate the simultaneous presence of localized and itinerant charge carriers. At variance with previous interpretations, we show that in our excitation energy dependent RIXS measurements the amounts of localized and itinerant Ti 3 d electrons in the ground state do not scale with the intensities of the Raman and fluorescence peaks, respectively. Rather, we attribute the observation of either Raman components or fluorescence signal to the specific nature of the intermediate state reached in the RIXS excitation process.

  14. Pile oscillator measurements of thermal absorption cross sections of Al, Mg, Fe and Cu; Mesure des sections efficaces thermiques d'absorption de l'Al, du Mg, du Fe et du Cu par la methode d'oscillation

    Energy Technology Data Exchange (ETDEWEB)

    Carre, J C; Vidal, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    The phase oscillation technique used at ZOE has the property of reducing of a marked factor the effect of neutron scattering by the sample. The absorption cross sections of poorly absorbing and highly scattering materials have been measured; for neutrons of 2,200 m/s, the following values are obtained: 229 {+-} 3 mb for Al; 64.2 {+-} 1.5 mb for Mg, 2.53 {+-} 0.03 b for Fe and 3.74 {+-} 0.04 b for Cu. (authors) [French] La methode d'oscillation de phase utilisee a ZOE possede la propriete de diminuer d'un facteur important l'influence de la diffusion. Les sections efficaces de capture de materiaux peu capturants et tres diffusants, ont ete mesurees; pour des neutrons de 2200 m/s, on obtient pour l'Al: 229 {+-} 3mb, pour le Mg: 64,2 {+-} 1,5 mb, pour le Fe: 2,53 {+-} 0,03 b et pour le Cu: 3,74 {+-} 0,04 b. (auteurs)

  15. Design and syntheses of hybrid metal-organic materials based on K3[M(C2O4)33H2O [M(III)=Fe, Al, Cr] metallotectons

    Science.gov (United States)

    Sun, Yayong; Zong, Yingxia; Ma, Haoran; Zhang, Ao; Liu, Kang; Wang, Debao; Wang, Wenqiang; Wang, Lei

    2016-05-01

    By using K3[M(C2O4)33H2O [M(III)=Fe, Al, Cr] (C2O42-=oxalate) metallotectons as the starting material, we have synthesized eight novel complexes with formulas [{Fe(C2O4)2(H2O)2}2]·(H-L1)2·H2O 1, [Fe(C2O4)Cl2]·(H2-L2)0.5·(L2)0.5·H2O 2, [{Fe(C2O4)1.5Cl2}2]·(H-L3)43, [Fe2(C2O4)Cl8]·(H2-L4)2·2H2O 4, K[Al(C2O4)3]·(H2-L5)·2H2O 5, K[Al(C2O4)3]·(H-L6)2·2H2O 6, K[Cr(C2O4)3]·2H2O 7, Na[Fe(C2O4)3]·(H-L6)2·2H2O 8 (with L1=4-dimethylaminopyridine, L2=2,3,5,6-tetramethylpyrazine, L3=2-aminobenzimidazole, L4=1,4-bis-(1H-imidazol-1-yl)benzene, L5=1,4-bis((2-methylimidazol-1-yl)methyl)benzene, L6=2-methylbenzimidazole). Their structures have been determined by single-crystal X-ray diffraction analyses, elemental analyses, IR spectra and thermogravimetric analyses. Compound 3 is a 2D H-bonded supramolecular architecture. Others are 3D supramolecular structures. Compound 1 shows a [Fe(C2O4)2(H2O)2]- unit and 3D antionic H-bonded framework. Compound 2 features a [Fe(C2O4)Cl2]- anion and 1D iron-oxalate-iron chain. Compound 3 features a [Fe2(C2O4)3Cl4]4- unit. Compound 4 features distinct [Fe2(C2O4)Cl8]4- units, which are mutual linked by water molecules to generated a 2D H-bonded network. Compound 5 features infinite ladder-like chains constructed by [Al(C2O4)3]3- units and K+ cations. The 1D chains are further extended into 3D antionic H-bonded framework through O-H···O H-bonds. Compounds 6-8 show 2D [KAl(C2O4)3]2- layer, [KCr(C2O4)3]2- layer and [NaFe(C2O4)3]2- layer, respectively.

  16. Universality of electron mobility in LaAlO3/SrTiO3 and bulk SrTiO3

    Science.gov (United States)

    Trier, Felix; Reich, K. V.; Christensen, Dennis Valbjørn; Zhang, Yu; Tuller, Harry L.; Chen, Yunzhong; Shklovskii, B. I.; Pryds, Nini

    2017-08-01

    Metallic LaAlO3/SrTiO3 (LAO/STO) interfaces attract enormous attention, but the relationship between the electron mobility and the sheet electron density, ns, is poorly understood. Here, we derive a simple expression for the three-dimensional electron density near the interface, n3 D , as a function of ns and find that the mobility for LAO/STO-based interfaces depends on n3 D in the same way as it does for bulk doped STO. It is known that undoped bulk STO is strongly compensated with N ≃5 ×1018 cm-3 background donors and acceptors. In intentionally doped bulk STO with a concentration of electrons n3 DN , the mobility collapses because scattering happens on n3 D intentionally introduced donors. For LAO/STO, the polar catastrophe which provides electrons is not supposed to provide an equal number of random donors and thus the mobility should be larger. The fact that the mobility is still the same implies that for the LAO/STO, the polar catastrophe model should be revisited.

  17. In-process 3D geometry reconstruction of objects produced by direct light projection

    DEFF Research Database (Denmark)

    Andersen, Ulrik Vølcker; Pedersen, David Bue; Hansen, Hans Nørgaard

    2013-01-01

    al. 2011), this method has shown its potential with 3D printing (3DP) and selective laser sintering additive manufacturing processes, where it is possible to directly capture the geometrical features of each individual layer during a build job using a digital camera. When considering the process...... equipment such as coordinate measuring machines cannot be verified easily. This problem is addressed by developing an in-line reverse engineering and 3D reconstruction method that allows a true-to-scale reconstruction of a part being additively manufactured. In earlier works (Pedersen et al. 2010; Hansen et...

  18. Modelado e impresión en 3D en la enseñanza de las matemáticas: un estudio exploratorio

    OpenAIRE

    Beltrán Pellicer, Pablo; Rodríguez Jaso, Carlos

    2017-01-01

    Las impresoras en 3D constituyen un recurso que poco a poco está encontrando su hueco en los centros educativos, de la mano de docentes innovadores y creativos. Normalmente, son profesores de Tecnología o Informática en educación secundaria, o los de ciertas especialidades de ciclos formativos, los que buscan utilizar el diseño de piezas y su posterior impresión como medio para alcanzar sus objetivos de aprendizaje. Nos planteamos aquí como objetivo el justificar la utilización de este recurs...

  19. MODELADO CON REDES DE PETRI E IMPLEMENTACIÓN CON GRAFCET DE UN SISTEMA DE MANUFACTURA FLEXIBLE CON PROCESOS CONCURRENTES Y RECURSOS COMPARTIDOS

    OpenAIRE

    Johanna Stella Castellanos Arias; Leonardo Enrique Solaque Guzmán

    2010-01-01

    En este trabajo, se presenta el modelado de un Sistema de Manufactura Flexible (SMF), con procesos concurrentes y recursos compartidos mediante Sistemas a Eventos Discretos (SED), específicamente Redes de Petri (RdP), y GRAFCET. El SMF se plantea como un modelo hipotético que se modela con una RdP con el objeto de identificar su dinámica y hallar la secuencia óptima de funcionamiento del sistema. Se desarrolló un modelo matemático que permite estimar el vector de tiempo acumulado de un proces...

  20. MODELADO, DISEÑO Y CONSTRUCCIÓN DE UN SISTEMA ACTIVO DE CONTROL DE ESTABILIDAD DE BAJO COSTO PARA COHETES EXPERIMENTALES TIPO AFICIONADO

    OpenAIRE

    Aponte Rodríguez, Jorge Alexander; Amaya Hurtado, Darío; Rubiano Fonseca, Astrid; Prada Jiménez, Vladimir

    2010-01-01

    Este artículo presenta el modelado, diseño y construcción de un cohete tipo aficionado de bajo costo, empleando un sistema de control activo por medio de una tobera móvil para lograr una mayor estabilidad. Se plantean los métodos y procedimientos utilizados en el experimento, desarrollando el análisis, simulación e implementación de un prototipo de control para lograr una trayectoria de vuelo. This paper presents the modeling, design and construction of a Rocket amateur of low cost, using ...

  1. Research Update: Conductivity and beyond at the LaAlO3/SrTiO3 interface

    Directory of Open Access Journals (Sweden)

    S. Gariglio

    2016-06-01

    Full Text Available In this review, we focus on the celebrated interface between two band insulators, LaAlO3 and SrTiO3, that was found to be conducting, superconducting, and to display a strong spin-orbit coupling. We discuss the formation of the 2-dimensional electron liquid at this interface, the particular electronic structure linked to the carrier confinement, the transport properties, and the signatures of magnetism. We then highlight distinctive characteristics of the superconducting regime, such as the electric field effect control of the carrier density, the unique tunability observed in this system, and the role of the electronic subband structure. Finally we compare the behavior of Tc versus 2D doping with the dome-like behavior of the 3D bulk superconductivity observed in doped SrTiO3. This comparison reveals surprising differences when the Tc behavior is analyzed in terms of the 3D carrier density for the interface and the bulk.

  2. Acoustic investigations on PbO–Al2O3–B2O3 glasses doped with ...

    Indian Academy of Sciences (India)

    Unknown

    meters such as Debye temperature (θD), diffusion constant (Di), latent heat of melting (∆Hm) etc of PbO–Al2O3– ... From these results (together with IR spectra of these glasses), an ... range below 200°C, which is far below when compared.

  3. Piezo-tunnel effect in Al/Al2O3/Al junctions elaborated by atomic layer deposition

    Science.gov (United States)

    Rafael, R.; Puyoo, E.; Malhaire, C.

    2017-11-01

    In this work, the electrical transport in Al/Al2O3/Al junctions under mechanical stress is investigated in the perspective to use them as strain sensors. The metal/insulator/metal junctions are elaborated with a low temperature process (≤200 °C) fully compatible with CMOS back-end-of-line. The conduction mechanism in the structure is found to be Fowler-Nordheim tunneling, and efforts are made to extract the relevant physical parameters. Gauge factors up to -32.5 were found in the fabricated devices under tensile stress. Finally, theoretical mechanical considerations give strong evidence that strain sensitivity in Al/Al2O3/Al structures originates not only from geometrical deformations but also from the variation of interface barrier height and/or effective electronic mass in the tunneling oxide layer.

  4. Redes de Petri: Modelado e implementación de algoritmos para autómatas programables

    Directory of Open Access Journals (Sweden)

    Luis Diego Murillo

    2008-04-01

    Full Text Available El presente trabajo es una monografía orientada hacia la utilización del formalismo de las Redes de Petri, propuesto por Carl Petri en la descripción de Sistemas Dinámicos de Eventos Discretos (DEDS. Las Redes de Petri, cuyo acrónimo en inglés es PN, fueron utilizadas inicialmente para el análisis de algoritmos en la computación paralela o concurrente, pero dada la complejidad de los procesos productivos actuales, las PN son un método alternativo de diseño tanto para el procesoindustrial como para el controlador. En este sentido, este estudio hace una revisión de las referencias bibliográficas donde se indica cómo realizar el modelado y la implementación de algoritmos de control en Controladores Lógicos Programables (PLCs por sus siglas en inglés.

  5. Obras musicales colombianas publicadas por Mundo al día

    Directory of Open Access Journals (Sweden)

    Ellie Anne Duque

    1996-05-01

    Full Text Available Entre 1924 y 1938 se publicó en Bogotá el diario gráfico vespertino Mundo al día, propiedad de Arturo Manrique (Tío Kiosko y dirigido por su dueño junto con Luis Carlos Páez. Circulaba todos los días de la semana a excepción de los domingos y ofrecía una edición especial los sábados, a manera de magacín, con las secciones usuales y además portada en colores, la popular tira cómica "Mojicón", una sección infantil, breves escritos de carácter literario y durante algunos años, una partitura musical al reverso de la portada. Las acuarelas, dibujos y caricaturas de Gómez Leal, Adolfo Samper y R. Scandroglio complementaron la rica imagen gráfica que tuvo la publicación al tiempo que la dotaron de interés artístico. El espíritu del periódico era liberal y los hechos en tomo a la candidatura, elección y gestión de Enrique Olaya Herrera como presidente de Colombia, como también su muerte en 1937, se cubrieron prolíficamente. El Mundo al día ofreció a sus lectores un periodismo moderno, ágil y variado.

  6. Nintendo Papercraft. Del 3D en pantalla al 3D en cartolina

    OpenAIRE

    Iborra i Mondéjar, Vicent Juli

    2013-01-01

    XVIII Jornades de Foment de la Investigació de la Facultat de Ciències Humanes i Socials (Any 2013) El marc d'aquest article se centra en els personatges de les consoles Nintendo passats a cartolina. L’anomenat papercraft és una construcció de figures tridimensionals de paper o cartolina, similar a l'origami. No obstant això, difereix de l'origami perquè els seus patrons poden consistir en moltes peces de paper tallades amb tisores o cúter i unides amb cola, cosa que no pot succeir a...

  7. A safety assessment approach using coupled NEAR3D and CHAN3D - Forsmark

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Longcheng; Moreno, Luis; Neretnieks, Ivars (Dept. of Chemical Engineering and Technology, Royal Inst. of Technology, Stockholm (Sweden)); Gylling, Bjoern (Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden))

    2010-12-15

    Safety assessment calculations for the Forsmark site were performed using a new code, which couples the far-field code CHAN3D and the near-field code NEAR3D. In addition, the package has a Graphical User Interface (GUI) and a code that governs the simulations (Coupling). The simulations were performed for 90 different canister locations, which were randomly chosen. Deterministic data were used for tunnels, deposition holes, and shafts. The background fractures were stochastically generated in two HRD realizations. The F-ratio and the water travel time distributions were used to study the performance of the simulations. Near-field calculations were not performed for the Forsmark site using the new coded presented in the prevailing report. However, the obtained results in this study are compared with the results from the Task 2 model of the ConnectFlow report /Joyce et al. 2010/. Although the results cannot be compared directly, a reasonably good agreement is obtained for the F-ratio

  8. Electric conductivity of low-temperature molten electrolyte KF-AlF3 with additions of LiF and Al2O3

    International Nuclear Information System (INIS)

    Apisarov, A.P.; Kryukovskij, V.A.; Zajkov, Yu.P.; Red'kin, A.A.; Tkacheva, O.Yu.; Khokhlov, V.A.

    2007-01-01

    Electric conductivity of LiF, Al 2 O 3 doped KF-AlF 3 (Cryolite Ratio CR=1.3) molten electrolytes was estimated on the basis of empiric equations. Specific electric conductivity of KF-AlF 3 , KF-AIF 3 -AI 2 O 3 , KF-AlF 3 -LiF, KF-AlF 3 -LiF-Al 2 0 3 molten mixtures was measured in the range 687-797 Deg C. Cells with the pyrolytic boron nitride capillary and parallel molybdena electrodes were applied for the determination of electric conductivity. Comparison of calculated and experimental data of the specific electric conductivity of cryolite-alumina melts confirms that the offered model of the calculation adequate represents temperature and concentration dependencies, and it permits forecasting its change under the introduction of different additives in electrolyte [ru

  9. Oxidation Kinetics of Cast TiAl3

    Science.gov (United States)

    Smialek, J. L.; Humphrey, D. L.

    1992-01-01

    The isothermal oxidation kinetics of the TiAl3 compound over a wide temperature range is documented, and these rates are related to exclusive alpha-Al2O3 scale growth. The specific weight change vs time curves are shown. Two abnormalities are immediately apparent. One is that a rapid initial uptake of oxygen occurs at times less than 5 h, followed by a lower oxidation rate at longer times, for tests at 900 C and below. The other is that the final weight changes for the 700, 800, and 900 C tests are not in the sequence expected with respect to temperature. Isothermal oxidation of drop cast TiAl above 1000 C was found to exhibit parabolic oxidation controlled by protective alpha-Al2O3 scale formation. TiAl is the only phase in the binary Ti-Al system that forms exclusive scales of alpha-Al2O3 in isothermal oxidation. High anomalous rates at short times and at temperatures below 1000 C resulted from the internal oxidation of a second phase of aluminum.

  10. Temperature-programmed reaction of CO2 reduction in the presence of hydrogen over Fe/Al2O3, Re/Al2O3 and Cr-Mn-O/Al2O3 catalysts

    International Nuclear Information System (INIS)

    Mirzabekova, S.R.; Mamedov, A.B.; Krylov, O.V.

    1996-01-01

    Regularities in CO 2 reduction have been studied using the systems Fe/Al 2 O 3 , Re/Al 2 O 3 and Cr-Mn-O/Al 2 O 3 under conditions of thermally programmed reaction by way of example. A sharp increase in the reduction rate in the course of CO 2 interaction with reduced Fe/Al 2 O 3 and Re/Al 2 O 3 , as well as with carbon fragments with addition in CO 2 flow of 1-2%H 2 , has been revealed. The assumption is made on intermediate formation of a formate in the process and on initiating effect of hydrogen on CO 2 reduction by the catalyst. Refs. 26, figs. 10

  11. Tunable magnetism in the LaAlO3/SrTiO3 heterostructure: Insights from first-principles calculations

    Science.gov (United States)

    Xue, Yuanbin; Zhao, Jinzhu; Shan, Yueyue; Xu, Hu

    2018-04-01

    By performing first-principles calculations, we explored the origin and controlling methods of magnetism in ideal and oxygen deficient (001) LaAlO3/SrTiO3 (LAO/STO) heterostructures. It was found that the ferromagnetic ordering is the ground state and that the interfacial Ti 3d electrons introduced by the LaO-termination, polar catastrophe and oxygen vacancies can all contribute to the magnetism. With respect to the ways of tuning the magnetic properties, our results show that LaO-terminated films generally carry much stronger magnetic moments than their AlO2-terminated counterparts and that the magnitude of magnetic moments can also be effectively controlled by the LAO film thickness. In addition, oxygen vacancy leads to substantial electronic reconstruction of the interfacial Ti 3d orbitals, which enhances the magnetization and makes the magnetism emerge in thinner polar LAO films. This work offers useful information to facilitate one's understanding of the magnetism and to provide clues to engineer the magnetic behaviors in related oxide heterostructures.

  12. Electronic Structures and Bonding Properties of Ti2AlC and Ti3AlC2

    Institute of Scientific and Technical Information of China (English)

    MIN Xinmin; REN Yi

    2007-01-01

    The relation among electronic structure, chemical bond and property of Ti2AlC, Ti3AlC2 and doping Si into Ti2AlC was studied by density function and the discrete variation (DFT-DVM) method. After adding Si into Ti2AlC, the interaction between Si and Ti is weaker than that between Al and Ti, and the strengths of ionic and covalent bonds decrease both. The ionic and covalent bonds in Ti3AlC2, especially in Ti-Al, are stronger than those in Ti2AlC. Therefore, in synthesis of Ti2AlC, the addition of Si enhances the Ti3AlC2 content instead of Ti2AlC. The density of state (DOS) shows that there is mixed conductor characteristic in Ti2AlC and Ti3AlC2. The DOS of Ti3AlC2 is much like that of Ti2AlC. Ti2SixAl1-x C has more obvious tendency to form a semiconductor than Ti2AlC, which is seen from the obvious difference of partial DOS between Si and Al3p.

  13. Instability of TiC and TiAl3 compounds in Al-10Mg and Al-5Cu alloys by addition of Al-Ti-C master alloy

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The performance of Al-Ti-C master alloy in refining Al-10Mg and A1-5Cu alloys was studied by using electron probe micro-analyzer (EPMA) and X-ray diffractometer (XRD) analysis.The results indicate that there are obvious fading phenomena in both Al-10Mg and Al-5Cu alloys with the addition of Al-5Ti-0.4C refiner which contains TiC and TiAl3 compounds.Mg element has no influence on the stability of TiC and TiAl3, while TiC particles in Al-10Mg alloy react with Al to form Al4C3 particles, resulting in the refinement fading.However, TiC particles are relatively stable in Al-5Cu alloy, while TiAl3 phase reacts with Al2Cu to produce a new phase Ti(Al, Cu)2, which is responsible for the refinement fading in Al-5Cu alloy.These indicate that the refinement fading will not occur only when both the TiC particles and TiAl3 compound of Al-Ti-C refiner are stable in Al alloys.

  14. Ordering and site occupancy of D03 ordered Fe3Al-5 at%Cr evaluated by means of atom probe tomography

    KAUST Repository

    Rademacher, Thomas W.

    2011-05-01

    Addition of ternary elements to the D03 ordered Fe3Al intermetallic phase is a general approach to optimise its mechanical properties. To understand the physical influences of such additions the determination of the probability of site occupancies of these additions on the lattice site and ordering parameters is of high interest. Some common experimental techniques such as X-ray diffraction or Atom Location by Channelling Enhanced Microanalysis (ALCHEMI) are usually applied to explore this interplay. Unfortunately, certain published results are partly inconsistent, imprecise or even contradictory. In this study, these aspects are evaluated systematically by atom probe tomography (APT) and a special data analysis method. Additionally, to account for possible field evaporation effects that can falsify the estimation of site occupancy and induce misinterpretations, APT evaporation sequences were also simulated. As a result, chromium occupies most frequently the next nearest neighbour sites of Al atoms and local ordering parameters could be achieved. © 2010 Elsevier B.V.

  15. Ordering and site occupancy of D03 ordered Fe3Al-5 at%Cr evaluated by means of atom probe tomography

    KAUST Repository

    Rademacher, Thomas W.; Al-Kassab, Talaat; Deges, Johannes; Kirchheim, Reiner

    2011-01-01

    Addition of ternary elements to the D03 ordered Fe3Al intermetallic phase is a general approach to optimise its mechanical properties. To understand the physical influences of such additions the determination of the probability of site occupancies of these additions on the lattice site and ordering parameters is of high interest. Some common experimental techniques such as X-ray diffraction or Atom Location by Channelling Enhanced Microanalysis (ALCHEMI) are usually applied to explore this interplay. Unfortunately, certain published results are partly inconsistent, imprecise or even contradictory. In this study, these aspects are evaluated systematically by atom probe tomography (APT) and a special data analysis method. Additionally, to account for possible field evaporation effects that can falsify the estimation of site occupancy and induce misinterpretations, APT evaporation sequences were also simulated. As a result, chromium occupies most frequently the next nearest neighbour sites of Al atoms and local ordering parameters could be achieved. © 2010 Elsevier B.V.

  16. Thermoluminescence of LaAlO3

    International Nuclear Information System (INIS)

    Morales H, A.; Zarate M, J.; Rivera M, T.; Azorin N, J.

    2015-10-01

    In this paper the thermoluminescent properties of doped lanthanum aluminate (LaAlO 3 ) with dysprosium ion (Dy) were studied. The thermoluminescence characteristics in the samples were obtained using an ultraviolet radiation of 220 nm. The LaAlO 3 :Dy samples were prepared by the modified Pechini method (Spray Dryer). The structural and morphological characterization was obtained by X-ray diffraction (XRD) and scanning electron microscopy (Sem) techniques respectively. The size particle composing the agglomerate was determined by Sem, agglomerated particles composed size of 2μm were observed. The thermoluminescence response of LaAlO 3 :Dy was compared with that obtained with the undoped sample. Thermoluminescence brightness curves of LaAlO 3 :Dy showed a peak centered at 185 grades C. Sensitivity of doped sample was greater, about 100 times compared with the undoped sample. Thermoluminescence response in function of the wavelength showed a maximum at 220 nm. Also the fading in thermoluminescence response was studied. (Author)

  17. Study On Nanohardness Of Phases Occurring In ZnAl22Cu3 And ZnAl40Cu3 Alloys

    Directory of Open Access Journals (Sweden)

    Michalik R.

    2015-06-01

    Full Text Available Zn-Al alloys are mainly used due to their high tribological and damping properties. A very important issue is determination of the hardness of the phases present in the Zn-Al-Cu alloys. Unfortunately, in literature there is lack of studies on the hardness of the phases present in the alloys Zn-Al-Cu. The aim of this research was to determine the hardness of the phases present in the ZnAl22Cu3Si and ZnAl40Cu3Si alloys. The scope of the research included examination of the structure, chemical composition of selected micro-regions and hardness of phases present in the examined alloys. The research carried out has shown, that CuZn4 phase is characterized by a similar hardness as the hardness of the interdendritic areas. The phases present in the structure of ZnAl40Cu3 and ZnAl22Cu3 alloys after soaking at the temperature of 185 °C are characterized by lower hardness than the phase present in the structure of the as-cast alloys.

  18. Current linearity and operation stability in Al2O3-gate AlGaN/GaN MOS high electron mobility transistors

    Science.gov (United States)

    Nishiguchi, Kenya; Kaneki, Syota; Ozaki, Shiro; Hashizume, Tamotsu

    2017-10-01

    To investigate current linearity and operation stability of metal-oxide-semiconductor (MOS) AlGaN/GaN high electron mobility transistors (HEMTs), we have fabricated and characterized the Al2O3-gate MOS-HEMTs without and with a bias annealing in air at 300 °C. Compared with the as-fabricated (unannealed) MOS HEMTs, the bias-annealed devices showed improved linearity of I D-V G curves even in the forward bias regime, resulting in increased maximum drain current. Lower subthreshold slope was also observed after bias annealing. From the precise capacitance-voltage analysis on a MOS diode fabricated on the AlGaN/GaN heterostructure, it was found that the bias annealing effectively reduced the state density at the Al2O3/AlGaN interface. This led to efficient modulation of the AlGaN surface potential close to the conduction band edge, resulting in good gate control of two-dimensional electron gas density even at forward bias. In addition, the bias-annealed MOS HEMT showed small threshold voltage shift after applying forward bias stress and stable operation even at high temperatures.

  19. Ingeniería guiada por Modelado y Simulación de Eventos Discretos: Metodología y Caso de Estudio en la Red de Datos del Experimento ATLAS

    CERN Document Server

    Bonaventura, Matias Alejandro; The ATLAS collaboration

    2015-01-01

    En este trabajo presentamos una metodología iterativa e incremental para desarrollo de proyectos de ingeniería guiados por modelado y simulación (M&S) for-mal. Basándonos en el marco formal DEVS (Discrete Event Systems Specification), y sumando prácticas estándar en proyectos de software, se obtienen modelos que dan respuesta a preguntas de diseño y optimización de redes de datos. Presentamos una aplicación práctica de la metodología a un caso de estudio de ingeniería de redes, en el contexto de un experimento científico a gran escala: el experimento ATLAS (Máquina de Dios) en el cual científicos de todo el mundo intentan responder preguntas acerca del origen del universo. Estas redes absorben en tiempo real datos de experimentos físicos, y por su criticidad se someten a diseños exhaustivos y mejoras continuas. Sin embargo, por la escala del problema, estas redes están disponibles para ensayos solo esporádicamente. Mostraremos como asistimos su diseño mediante técnicas de modelado y s...

  20. 3D city models as a basis for heat demand simulations; 3D-Stadtmodelle als Grundlage fuer Waermebedarfssimulationen

    Energy Technology Data Exchange (ETDEWEB)

    Schulte, Claudia; Coors, Volker; Eicker, Ursula [Hochschule fuer Technik (HFT), Stuttgart (Germany)

    2012-07-01

    The biggest potential for heat consumption reduction and CO2 emission reduction in Germany is in older buildings. By applying innovative modernization concepts, primary energy consumption could be reduced by 80 percent. Planning of modernisation and energy concepts requires data on the current status. HFT Stuttgart developed a promising method for assessing heat consumption according to DIN 18599 of urban districts on the basis of 3D models of buildings (CityGML). The method is presented and explained here.

  1. Growth and scintillation properties of Ce{sup 3+}-doped (Y{sub 1-x}Gd{sub x})AlO{sub 3} crystals

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, Yutaka; Wakahara, Shingo; Suzuki, Shotaro; Kurosawa, Shunsuke [Institute of Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577 (Japan); Yanagida, Takayuki [New Industry Creation Hatchery Center, Tohoku University, 6-6-10 Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Yoshikawa, Akira [Institute of Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577 (Japan); New Industry Creation Hatchery Center, Tohoku University, 6-6-10 Aramaki, Aoba-ku, Sendai 980-8579 (Japan)

    2012-12-15

    The optical and scintillation properties of 0.5% fixed Ce-doped (Y{sub 1-x}Gd{sub x})AlO{sub 3} single crystals have been investigated at three different levels of Gd doping: x = 0.2, 0.4 and 0.6. Single crystal of the Ce{sup 3+}-doped (Y{sub 0.8}Gd{sub 0.2})AlO{sub 3}, (Y{sub 0.6}Gd{sub 0.4})AlO{sub 3} and (Y{sub 0.4}Gd{sub 0.6})AlO{sub 3} were successfully grown by {mu}-PD technique in nitrogen atmosphere. From X-ray diffraction analysis, no impurity phase was detected for the grown Ce-doped crystals. Ce-doped (Y{sub 0.6}Gd{sub 0.4})AlO{sub 3} crystal demonstrated highest fluorescence quantum efficiency ({proportional_to} 25%) with improvement of excitation efficiency due to the Gd-doping. When irradiated by the alpha-rays from a {sup 241}Am source, all the Ce-doped crystals showed luminescence band that corresponding to 5d (t{sub 2g})-4f transition of Ce{sup 3+}. The scintillation decay time was characterized by two components; the fast component (5-15 ns) is ascribed to 5d-4f transition of Ce{sup 3+}, while the slow one (100-200 ns) may be related to energy transfer between Ce{sup 3+} and Gd{sup 3+} ion. According to the result of {sup 137}Cs gamma-ray irradiated pulse height spectra compared with BGO scintillator, the relative scintillation light output was found to be about 12200 {+-} 1220 (Gd 20%) and 16000 {+-} 1600 (Gd 40%) ph/MeV. (copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  2. 3D freeform printing of silk fibroin.

    Science.gov (United States)

    Rodriguez, Maria J; Dixon, Thomas A; Cohen, Eliad; Huang, Wenwen; Omenetto, Fiorenzo G; Kaplan, David L

    2018-04-15

    Freeform fabrication has emerged as a key direction in printing biologically-relevant materials and structures. With this emerging technology, complex structures with microscale resolution can be created in arbitrary geometries and without the limitations found in traditional bottom-up or top-down additive manufacturing methods. Recent advances in freeform printing have used the physical properties of microparticle-based granular gels as a medium for the submerged extrusion of bioinks. However, most of these techniques require post-processing or crosslinking for the removal of the printed structures (Miller et al., 2015; Jin et al., 2016) [1,2]. In this communication, we introduce a novel method for the one-step gelation of silk fibroin within a suspension of synthetic nanoclay (Laponite) and polyethylene glycol (PEG). Silk fibroin has been used as a biopolymer for bioprinting in several contexts, but chemical or enzymatic additives or bulking agents are needed to stabilize 3D structures. Our method requires no post-processing of printed structures and allows for in situ physical crosslinking of pure aqueous silk fibroin into arbitrary geometries produced through freeform 3D printing. 3D bioprinting has emerged as a technology that can produce biologically relevant structures in defined geometries with microscale resolution. Techniques for fabrication of free-standing structures by printing into granular gel media has been demonstrated previously, however, these methods require crosslinking agents and post-processing steps on printed structures. Our method utilizes one-step gelation of silk fibroin within a suspension of synthetic nanoclay (Laponite), with no need for additional crosslinking compounds or post processing of the material. This new method allows for in situ physical crosslinking of pure aqueous silk fibroin into defined geometries produced through freeform 3D printing. Copyright © 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights

  3. Synthesis and Evaluation of A High Precision 3D-Printed Ti6Al4V Compliant Parallel Manipulator

    Science.gov (United States)

    Pham, Minh Tuan; Teo, Tat Joo; Huat Yeo, Song; Wang, Pan; Nai, Mui Ling Sharon

    2017-12-01

    A novel 3D printed compliant parallel manipulator (CPM) with θX - θX - Z motions is presented in this paper. This CPM is synthesized using the beam-based method, a new structural optimization approach, to achieve optimized stiffness properties with targeted dynamic behavior. The CPM performs high non-actuating stiffness based on the predicted stiffness ratios of about 3600 for translations and 570 for rotations, while the dynamic response is fast with the targeted first resonant mode of 100Hz. A prototype of the synthesized CPM is fabricated using the electron beam melting (EBM) technology with Ti6Al4V material. Driven by three voice-coil (VC) motors, the CPM demonstrated a positioning resolution of 50nm along the Z axis and an angular resolution of ~0.3 “about the X and Y axes, the positioning accuracy is also good with the measured values of ±25.2nm and ±0.17” for the translation and rotations respectively. Experimental investigation also shows that this large workspace CPM has a first resonant mode of 98Hz and the stiffness behavior matches the prediction with the highest deviation of 11.2%. Most importantly, the full workspace of 10° × 10° × 7mm of the proposed CPM can be achieved, that demonstrates 3D printed compliant mechanisms can perform large elastic deformation. The obtained results show that CPMs printed by EBM technology have predictable mechanical characteristics and are applicable in precise positioning systems.

  4. Al-TiC in situ composite coating fabricated by low power pulsed laser cladding on AZ91D magnesium alloy

    Science.gov (United States)

    Yang, Liuqing; Li, Zhiyong; Zhang, Yingqiao; Wei, Shouzheng; Liu, Fuqiang

    2018-03-01

    Al + (Ti + B4C) composite coating was cladded on AZ91D magnesium alloy by a low power pulsed Nd-YAG laser. The Ti+B4C mixed powder is with the ratio of Ti: B4C = 5:1, which was then mixed with Al powder by weight fraction of 10%, 15% and 20%, respectively. Scanning electron microscopy, energy dispersive spectrometer and X-ray diffraction were used to study the microstructure, chemical composition and phase composition of the coating. Results showed that the coating had satisfied metallurgical bonding with the magnesium substrate. Al3Mg2, Al12Mg17, Al3Ti and TiC were formed by in-situ reaction. The coatings have micro-hardness of 348HV, which is about 5-6 times higher than that of AZ91D. The wear resistance and corrosion resistance of the coatings are enhanced with the addition of the mixed powder.

  5. Karakterisasi Paduan AlMgSi Untuk Kelongsong Bahan Bakar U3Si2/Al Dengan Densitas Uranium 5,2 gU/cm3

    Directory of Open Access Journals (Sweden)

    Aslina Br. Ginting

    2018-03-01

    Full Text Available Meningkatnya densitas uranium dari 2,96 gU/cm3 menjadi 5,2 gU/cm3 bahan bakar U3Si2/Al harus diikuti dengan penggunaan kelongsong yang kompatibel. Bahan bakar berdensitas tinggi mempunyai kekerasan yang tinggi, sehingga bila menggunakan paduan AlMg2 sebagai kelongsong dapat menyebabkan terjadi dogbone pada saat perolan. Selain fenomena dogbone, pada saat bahan bakar tersebut digunakan di reaktor dapat terjadi swelling karena meningkatnya hasil fisi maupun burn up. Oleh karena itu, perlu dicari pengganti bahan kelongsong untuk bahan bakar U3Si2/Al densitas tinggi. Pada penelitian ini telah dilakukan karakterisasi paduan AlMgSi sebagai kandidat pengganti kelongsong AlMg2. Karakterisasi yang dilakukan meliputi analisis termal, kekerasan, mikrostruktur dan laju korosi. Analisis termal dilakukan menggunakan DTA (Differential Thermal Analysis dan DSC (Differential Scanning Calorimetry. Analisis kekerasan menggunakan alat uji kekerasan mikro, mikrostruktur menggunakan SEM (Scanning Electron Microscope dan analisis laju korosi dilakukan dengan pemanasan pada temperatur 150 oC selama 77 jam di dalam autoclave. Hasil analisis menunjukkan bahwa kelongsong AlMgSi maupun AlMg2 mempunyai kompatibilitas panas dengan bahan bakar U3Si2/Al cukup stabil hingga temperatur 650 oC. Kelongsong AlMgSi mempunyai kekerasan sebesar 115 HVN dan kelongsong AlMg2 sebesar 70,1 HVN. Sementara itu, analisis mikrostruktur menunjukkan bahwa morfologi ikatan antarmuka (interface bonding kelongsong AlMgSi lebih baik dari kelongsong AlMg2, demikian halnya dengan laju korosi bahwa kelongsong AlMgSi mempunyai laju korosi lebih kecil dibanding kelongsong AlMg2. Hasil karakterisasi termal, kekerasan, mikrostruktur dan laju korosi menunjukkan bahwa PEB U3Si2/Al densitas 5,2 gU/cm3 menggunakan kelongsong AlMgSi lebih baik dibanding PEB U3Si2/Al  densitas 5,2 gU/cm3  menggunakan kelongsong AlMg2. Kata kunci: U3Si2/Al, densitas 5,2 gU/cm3, kelongsong AlMgSi dan AlMg2.

  6. TEM characterization of Al-C-Cu-Al2O3 composites produced by mechanical milling

    International Nuclear Information System (INIS)

    Santos-Beltran, A.; Gallegos-Orozco, V.; Estrada-Guel, I.; Bejar-Gomez, L.; Espinosa-Magana, F.; Miki-Yoshida, M.; Martinez-Sanchez, R.

    2007-01-01

    Novel Al-based composites (Al-C-Cu-Al 2 O 3 ) obtained by mechanical milling (MM), were characterized by transmission electron microscopy (TEM) and electron energy loss spectroscopy (EELS). Analyses of composites were carried out in both, the as-milled and the as-sintered conditions. C nanoparticles were found in the as-milled condition and Al 2 O 3 nanofibers were found in as-sintered products, as determined by EELS. C and Cu react with Al to crystallize in Al 3 C 4 and Al 2 Cu structures, respectively

  7. Synthesis of Ti3AlC2 by spark plasma sintering of mechanically milled 3Ti/xAl/2C powder mixtures

    International Nuclear Information System (INIS)

    Yang Chen; Jin Songzhe; Liang Baoyan; Liu Guojun; Duan Lianfeng; Jia Shusheng

    2009-01-01

    Elemental powders of Ti, Al and C were mechanically milled as starting materials for the fabrication of ternary carbide Ti 3 AlC 2 by spark plasma sintering (SPS) technique. The effect of Al content in the starting materials on the Ti 3 AlC 2 synthesis was investigated. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were employed to determine the phase identification and observe the microstructure of the synthesized samples. With increasing proper Al content, it was found that the purity of Ti 3 AlC 2 increased and the sintering temperature reduced. The dense and high-purity Ti 3 AlC 2 could be successfully fabricated from 3Ti/1.2Al/2C powders at a lower sintering temperature of 1050 deg. C, holding for 10 min. In addition, the reaction path for the formation of Ti 3 AlC 2 in the present study was proposed

  8. Ductility of Ni3Al doped with substitutional elements

    International Nuclear Information System (INIS)

    Hanada, S.; Chiba, A.; Guo, H.Z.; Watanabe, S.

    1993-01-01

    This paper reports on ductility of B-free Ni 3 Al alloys. Recrystallized Ni 3 Al binary alloys with Ni-rich compositions show appreciable ductility when an environmental effect is eliminated, while the alloys with stoichiometric and Al-rich compositions remain brittle. The ductility in the Ni-rich Ni 3 Al alloys is associated with low ordering energy. The additions of ternary elements, which are classified as γ formers, ductilize ternary Ni 3 Al alloys(Ni-23 at% Al-2 at% X, X = Pd, Pt, Cu and Co), whereas the additions of γ' formers embrittle ternary Ni 3 Al alloys(Ni-23 at% Al-2 at% X, X = Ta, Mo, Nb, Zr, Hf, V, Ti and Si). The additions of small amounts (less than 1 at%) of γ' formers such as Zr and Hf also ductilize as-cast ternary Ni 3 Al alloys. Ductility of Ni 3 Al alloys doped with substitutional elements is discussed in terms of ordering energy and microstructure

  9. Quasirecognition by prime graph of finite simple groups ${}^2D_n(3$

    Directory of Open Access Journals (Sweden)

    Behrooz Khosravi

    2014-12-01

    Full Text Available Let $G$ be a finite group. In [Ghasemabadi et al., characterizations of the simple group ${}^2D_n(3$ by prime graph and spectrum, Monatsh Math., 2011] it is proved that if $n$ is odd, then ${}^2D _n(3$ is recognizable by prime graph and also by element orders. In this paper we prove that if $n$ is even, then $D={}^2D_{n}(3$ is quasirecognizable by prime graph, i.e. every finite group $G$ with $Gamma(G=Gamma(D$ has a unique nonabelian composition factor and this factor is isomorphic to $D$.

  10. Precision casting of Ti-15V-3Cr-3Al-3Sn alloy setting

    OpenAIRE

    Nan Hai; Liu Changkui; Huang Dong

    2008-01-01

    In this research, Ti-15V-3Cr-3Al-3Sn alloy ingots were prepared using ceramic mold and centrifugal casting. The Ti-15V-3Cr-3Al-3Sn setting casting, for aeronautic engine, with 1.5 mm in thickness was manufactured. The alloy melting process, precision casting process, and problems in casting application were discussed. Effects of Hot Isostatic Pressing and heat treatment on the mechanical properties and microstructure of the Ti-15V-3Cr-3Al-3Sn alloy were studied.

  11. Role of 3d-ions for radiation defect production in MgO and MgAl2O4

    International Nuclear Information System (INIS)

    Mironova, N.A.; Grinvald, G.A.; Skvortsova, V.N.

    1985-01-01

    Optical properties of MgO and MgAl 2 O 4 crystals containing chromium and manganese impurity ions were studied by exposure to but all types of radiation. Complicated defects of the ''impurity-intrinsic matrix defect'' type were preferably considered. It has been shown that different symmetry center forming chromium ions in MgO:Crsup(3+) change their valency with various efficiency being exposed to external action. Besides, the compensating vacancy does not participate in the hole center formation. For MgOxAl 2 O 3 single crystals the presence of octahedrally coordinated manganese ions suppresses the hole center creation by gamma-irradiation. Studying luminescence spectra of Crsup(3+) ions in MgAl 2 O 4 it has been states that neutron irradiation increases the degree of inversion for the magnesium-aluminium spinel

  12. Color-tunable and highly thermal stable Sr{sub 2}MgAl{sub 22}O{sub 36}:Tb{sup 3+} phosphors

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Haiming; Zhang, Haoran; Liu, Yingliang [Guangdong Provincial Engineering Technology Research Center for Optical Agricultural, College of Materials and Energy, South China Agricultural University, Guangzhou 510642 (China); Lei, Bingfu, E-mail: tleibf@scau.edu.cn [Guangdong Provincial Engineering Technology Research Center for Optical Agricultural, College of Materials and Energy, South China Agricultural University, Guangzhou 510642 (China); Deng, Jiankun [Guangdong Provincial Engineering Technology Research Center for Optical Agricultural, College of Materials and Energy, South China Agricultural University, Guangzhou 510642 (China); Liu, Wei-Ren [Department of Chemical Engineering, Chung Yuan Christian University, Taoyuan City, Taiwan (China); Zeng, Yuan; Zheng, Lingling; Zhao, Minyi [Guangdong Provincial Engineering Technology Research Center for Optical Agricultural, College of Materials and Energy, South China Agricultural University, Guangzhou 510642 (China)

    2017-06-01

    Tb{sup 3+} activated Sr{sub 2}MgAl{sub 22}O{sub 36} phosphor was prepared by a high-temperature solid-state reaction route. The X-ray diffraction, scanning electron microscopy, and photoluminescence spectroscopy were used to characterize the as-prepared samples. The Sr{sub 2}MgAl{sub 22}O{sub 36}:Tb{sup 3+} phosphors show intense green light emission under UV excitation. The phosphor exhibit two groups of emission lines from about 370 to 700 nm, which originating from the characteristic {sup 5}D{sub 3}-{sup 7}F{sub J} and {sup 5}D{sub 4}-{sup 7}F{sub J} transitions of the Tb{sup 3+} ion, respectively. The cross-relaxation mechanism between the {sup 5}D{sub 3} and {sup 5}D{sub 4} emission was investigated and discussed. The emission colors of these phosphors can be tuned from bluish-green to green by adjusting the Tb{sup 3+} doping concentration. Furthermore, the thermal quenching temperature (T{sub 1/2}) is higher than 500 K. The excellent thermal stability and color-tunable luminescent properties suggest that the developed material is a promising green-emitting phosphor candidate for optical devices. - Highlights: • A Color-tunable emitting phosphor Sr{sub 2}MgAl{sub 22}O{sub 36}:Tb{sup 3+} was prepared successfully via high-temperature solid-state reaction. • The photoluminescence of Sr{sub 2}MgAl{sub 22}O{sub 36}:Tb{sup 3+} shows highly thermal stable. • The cross-relaxation mechanism between the {sup 5}D{sub 3} and {sup 5}D{sub 4} emission was investigated and discussed.

  13. Metodologi Hukum Islam ‘Abd al-Halîm Mahmûd

    Directory of Open Access Journals (Sweden)

    M. Lathoif Ghozali

    2015-09-01

    Full Text Available This article discusses the concept of ijtihâd (legal reasoning and the typology of legal thought of ‘Abd al-Halîm Mahmûd. According to Mahmûd, ijtihad is devoting all abilities of a mujtahid to arrive at the essence and substance of a problem intended by the Prophet Muhammad. This definition is supported by the division of ijtihâd into two: ijtihâd istinbâtî, the object of which is the texts of the Qur’ân or the Sunnah, and ijtihâd tatbîqî, the object of which is legal problems of the time. Mahmud maintains that a mujtahid should meet certain qualifications such as the abilities of understanding Arabic language, memorizing the Qur’ân, understanding asbâb al-nuzûl (causes of revelation, memorizing the Traditions of the Prophet related to legal matters, and the brilliance in making legal reasoning and conclusions. Mahmûd belongs to moderate group that agrees with the formalization of private laws, while public laws in his view serve only as materials for national laws. Mahmûd also gives an emphasis on the integration between nass (text and maqâsid al-sharî‘ah (the objectives of law.

  14. Elucidating the 3D structures of Al(iii)-Aβ complexes: a template free strategy based on the pre-organization hypothesis.

    Science.gov (United States)

    Mujika, Jon I; Rodríguez-Guerra Pedregal, Jaime; Lopez, Xabier; Ugalde, Jesus M; Rodríguez-Santiago, Luis; Sodupe, Mariona; Maréchal, Jean-Didier

    2017-07-01

    Senile plaques are extracellular deposits found in patients with Alzheimer's Disease (AD) and are mainly formed by insoluble fibrils of β-amyloid (Aβ) peptides. The mechanistic details about how AD develops are not fully understood yet, but metals such as Cu, Zn, or Fe are proposed to have a non-innocent role. Many studies have also linked the non biological metal aluminum with AD, a species whose concentration in the environment and food has been constantly increasing since the industrial revolution. Gaining a molecular picture of how Al(iii) interacts with an Aβ peptide is of fundamental interest to improve understanding of the many variables in the evolution of AD. So far, no consensus has been reached on how this metal interacts with Aβ, partially due to the experimental complexity of detecting and quantifying the resulting Al(iii)-Aβ complexes. Computational chemistry arises as a powerful alternative to investigate how Al(iii) can interact with Aβ peptides, as suitable strategies could shed light on the metal-peptide description at the molecular level. However, the absence of any reliable template that could be used for the modeling of the metallopeptide structure makes computational insight extremely difficult. Here, we present a novel strategy to generate accurate 3D models of the Al(iii)-Aβ complexes, which still circumvents first principles simulations of metal binding to peptides of Aβ. The key to this approach lies in the identification of experimental structures of the isolated peptide that are favourably pre-organized for the binding of a given metal in configurations of the first coordination sphere that were previously identified as the most stable with amino acid models. This approach solves the problem of the absence of clear structural templates for novel metallopeptide constructs. The posterior refinement of the structures via QM/MM and MD calculations allows us to provide, for the first time, physically sound models for Al

  15. Al-Si/Al2O3 in situ composite prepared by displacement reaction of CuO/Al system

    Directory of Open Access Journals (Sweden)

    Zhang Jing

    2010-02-01

    Full Text Available Al2O3 particle-reinforced ZL109 composite was prepared by in situ reaction between CuO and Al. The microstructure was observed by means of OM, SEM and TEM. The Al2O3 particles in sub-micron sizes distribute uniformly in the matrix, and the Cu displaced from the in situ reaction forms net-like alloy phases with other alloy elements. The hardness and the tensile strength of the composites at room temperature have a slight increase as compared to that of the matrix. However, the tensile strength at 350 ℃ has reached 90.23 MPa, or 16.92 MPa higher than that of the matrix. The mechanism of the reaction in the CuO/Al system was studied by using of differential scanning calorimetry(DSC and thermodynamic calculation. The reaction between CuO and Al involves two steps. First, CuO reacts with Al to form Cu2O and Al2O3 at the melting temperature of the matrix alloy, and second, Cu2O reacts with Al to form Cu and Al2O3 at a higher temperature. At ZL109 casting temperature of 750–780 ℃, the second step can also take place because of the effect of exothermic reaction of the first step.

  16. 3D Finite Element Modelling of Drilling Process of Al2024-T3 Alloy with solid tooling and Experimental Validation

    DEFF Research Database (Denmark)

    Davoudinejad, Ali; Tosello, Guido

    2017-01-01

    Drilling is an indispensable process for many manufacturing industries due to the importance of the process for assembling components. This study presents a 3D finite element modeling (3D FEM) approach for drilling process of aluminum 2024-T3. The 3D model of tool for two facet HSSCo and four facet...... area were determined numerically. The results confirm the ability and advantage of 3D FE model of the drilling process....... HSS were generated base on the details geometry. The simulations were carried out for both drills in different cutting conditions. The numerically obtained thrust forces were compared against experimental results. The tool stress distribution, chip formation and temperature distribution in the chip...

  17. Modelado de Caden as Cinemáticas mediante Matrices de Desplazamiento. Una alternativa al método de Denavit-Hartenberg

    Directory of Open Access Journals (Sweden)

    A. Barrientos

    2012-10-01

    Full Text Available Resumen: En este trabajo se presenta un método para el modelado de cadenas cinemáticas de robots que salva las dificultades asociadas a la elección de los sistemas de coordenadas y obtención de los parámetros de Denavit-Hartenberg. El método propuesto parte del conocimiento de la posición y orientación del extremo del robot en su configuración de reposo, para ir obteniendo en qué se transforman éstas tras los sucesivos movimientos de sus grados de libertad en secuencia descendente, desde el más alejado al más cercano a su base. Los movimientos son calculados en base a las Matrices de Desplazamiento, que permiten conocer en que se transforma un punto cuando éste es desplazado (trasladado o rotado con respecto a un eje que no pasa por el origen. A diferencia del método de Denavit-Hartenberg, que precisa ubicar para cada eslabón el origen y las direcciones de los vectores directores de los sistemas de referencia asociados, el método basado en las Matrices de Desplazamiento precisa solo identificar el eje de cada articulación, lo que le hace más simple e intuitivo que aquel. La obtención de las Matrices de Desplazamiento y con ellas del Modelo Cinemático Directo a partir de los ejes de la articulación, puede hacerse mediante algunas simples operaciones, fácilmente programables. Abstract: In this paper, a new method for modelling kinematic chains in Robotics is presented. This method eludes the difficulties de- rived from selecting the coordinate frames required to obtain Denavit-Hartenberg parameters. The proposed method arises from knowing the position and orientation of the end-effector of the robot in its home position. This algorithm allows obtaining their transformations according to the successive variations of its degrees of freedom in descending order from the remotest to the closest to the base.The movements are calculated based on the Displacement Matrixes by determining

  18. Al2O3 Passivation Effect in HfO2·Al2O3 Laminate Structures Grown on InP Substrates.

    Science.gov (United States)

    Kang, Hang-Kyu; Kang, Yu-Seon; Kim, Dae-Kyoung; Baik, Min; Song, Jin-Dong; An, Youngseo; Kim, Hyoungsub; Cho, Mann-Ho

    2017-05-24

    The passivation effect of an Al 2 O 3 layer on the electrical properties was investigated in HfO 2 -Al 2 O 3 laminate structures grown on indium phosphide (InP) substrate by atomic-layer deposition. The chemical state obtained using high-resolution X-ray photoelectron spectroscopy showed that interfacial reactions were dependent on the presence of the Al 2 O 3 passivation layer and its sequence in the HfO 2 -Al 2 O 3 laminate structures. Because of the interfacial reaction, the Al 2 O 3 /HfO 2 /Al 2 O 3 structure showed the best electrical characteristics. The top Al 2 O 3 layer suppressed the interdiffusion of oxidizing species into the HfO 2 films, whereas the bottom Al 2 O 3 layer blocked the outdiffusion of In and P atoms. As a result, the formation of In-O bonds was more effectively suppressed in the Al 2 O 3 /HfO 2 /Al 2 O 3 /InP structure than that in the HfO 2 -on-InP system. Moreover, conductance data revealed that the Al 2 O 3 layer on InP reduces the midgap traps to 2.6 × 10 12 eV -1 cm -2 (compared to that of HfO 2 /InP, that is, 5.4 × 10 12 eV -1 cm -2 ). The suppression of gap states caused by the outdiffusion of In atoms significantly controls the degradation of capacitors caused by leakage current through the stacked oxide layers.

  19. Preparation and microwave-infrared absorption of reduced graphene oxide/Cu-Ni ferrite/Al2O3 composites

    Science.gov (United States)

    De-yue, Ma; Xiao-xia, Li; Yu-xiang, Guo; Yu-run, Zeng

    2018-01-01

    Reduced graphene oxide (RGO)/Cu-Ni ferrite/Al2O3 composite was prepared by solvothermal method, and its properties were characterized by SEM, x-ray diffraction, energy-dispersive x-ray spectroscopy and FTIR. The electromagnetic parameters in 2-18 GHz and mid-infrared (IR) spectral transmittance of the composite were measured, respectively. The results show that Cu0.7Ni0.3Fe2O4 nanoparticles with an average size of tens nanometers adsorb on surface of RGO, and meanwhile, Al2O3 nanoparticles adhere to the surface of Cu0.7Ni0.3Fe2O4 nanoparticles and RGO. The composite has both dielectric and magnetic loss mechanism. Its reflection loss is lower than -19 dB in 2-18 GHz, and the maximum of -23.2 dB occurs at 15.6 GHz. With the increasing of Al2O3 amount, its reflection loss becomes lower and the maximum moves towards low frequency slightly. Compared with RGO/Cu-Ni ferrite composites, its magnetic loss and reflection loss slightly reduce with the increasing of Al2O3 amount, and the maximum of reflection loss shifts from a low frequency to a high one. However, its broadband IR absorption is significantly enhanced owing to nano-Al2O3. Therefore, RGO/Cu-Ni ferrite/Al2O3 composites can be used as excellent broadband microwave and IR absorbing materials, and maybe have broad application prospect in electromagnetic shielding, IR absorbing and coating materials.

  20. Reconstructing 3D profiles of flux distribution in array of unshunted Josephson junctions from 2D scanning SQUID microscope images

    International Nuclear Information System (INIS)

    Nascimento, F.M.; Sergeenkov, S.; Araujo-Moreira, F.M.

    2012-01-01

    By using a specially designed algorithm (based on utilizing the so-called Hierarchical Data Format), we report on successful reconstruction of 3D profiles of local flux distribution within artificially prepared arrays of unshunted Nb-AlO x -Nb Josephson junctions from 2D surface images obtained via the scanning SQUID microscope. The analysis of the obtained results suggest that for large sweep areas, the local flux distribution significantly deviates from the conventional picture and exhibits a more complicated avalanche-type behavior with a prominent dendritic structure. -- Highlights: ► The penetration of external magnetic field into an array of Nb-AlO x -Nb Josephson junctions is studied. ► Using Scanning SQUID Microscope, 2D images of local flux distribution within array are obtained. ► Using specially designed pattern recognition algorithm, 3D flux profiles are reconstructed from 2D images.

  1. Interface reactions in the Al-Si-SiC and Mg-Al-Al{sub 2}O{sub 3} composite systems

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, P.K. [Commission of the European Communities, Petten (Netherlands). Inst. for Advanced Materials; Fazal-Ur-Rehman [Imperial Coll. of Science, Technology and Medicine, London (United Kingdom). Dept. of Materials; Fox, S. [Imperial Coll. of Science, Technology and Medicine, London (United Kingdom). Dept. of Materials; Flower, H.M. [Imperial Coll. of Science, Technology and Medicine, London (United Kingdom). Dept. of Materials; West, D.R.F.

    1995-12-31

    Structural and compositional observations are reported on the influence of the interfaces on the mechanisms and kinetics of liquid metal-ceramic reactions in Al-SiC, Al-Si-SiC, Mg-Al{sub 2}O{sub 3} and Mg-Al-Al{sub 2}O{sub 3} composites. The aluminium based materials contained up to 20 vol% SiC in particulate form, and were produced by a spray casting process; subsequently the interface reactions were studied in samples heated to temperatures up to 1100 C. The reaction product was Al{sub 4}C{sub 3} in both Al-SiC and Al-Si-SiC composites. The influence of the crystallography and topology of the SiC particle surfaces on the nucleation of the Al{sub 4}C{sub 3} has been demonstrated; surface asperities play an important role. Growth of nuclei proceeds to form continuous reaction product layers which control the subsequent kinetics. The magnesium based composites contained 5 vol% Al{sub 2}O{sub 3} fibres (3 {mu}m in diameter), and were produced by a liquid infiltration process. SD Safimax fibres with relatively low and high porosity, and also RF Saffil fibres, with a silica binder, were investigated. Fibre porosity plays a major role in accelerating the penetration of Mg into the fibres with reaction to form MgO. Silica binder on the fibre surface transforms to MgO. The reaction rate was reduced by the presence of aluminium in the matrix. The factors controlling the reactions in the aluminium and magnesium based composites are compared. (orig.)

  2. Universality of electron mobility in LaAlO3/SrTiO3 and bulk SrTiO3

    DEFF Research Database (Denmark)

    Trier, Felix; Reich, K. V.; Christensen, Dennis Valbjørn

    2017-01-01

    Metallic LaAlO3/SrTiO3 (LAO/STO) interfaces attract enormous attention, but the relationship between the electron mobility and the sheet electron density, ns, is poorly understood. Here, we derive a simple expression for the three-dimensional electron density near the interface, n3D, as a function...

  3. Er3+-Al2O3 nanoparticles doping of borosilicate glass

    International Nuclear Information System (INIS)

    Massera, Jonathan; Petit, Laeticia; Hupa, Leena; Hupa, Mikko; Koponen, Joona; Glorieux, Benoit

    2015-01-01

    Novel borosilicate glasses were developed by adding in the glass batch Er 3+ -Al 2 O 3 nanoparticles synthetized by using a soft chemical method. A similar nanoparticle doping with modified chemical vapour deposition (MCVD) process was developed to increase the efficiency of the amplifying silica fibre in comparison to using MCVD and solution doping. It was shown that with the melt quench technique, a Er 3+ -Al 2 O 3 nanoparticle doping neither leads to an increase in the Er 3+ luminescence properties nor allows one to control the rare-earth chemical environment in a borosilicate glass. The site of Er 3+ in the Er 3+ -Al 2 O 3 nanoparticle containing glass seems to be similar as in glasses with the same composition prepared using standard raw materials. We suspect the Er 3+ ions to diffuse from the nanoparticles into the glass matrix. There was no clear evidence of the presence of Al 2 O 3 nanoparticles in the glasses after melting. (author)

  4. Museologia e tecnologia 3D - Applicazioni sui reperti del Museo Archeologico di Aidone in mostra al The J. Paul Getty Museum ( Malibu, aprile 2012-gennaio 2013

    Directory of Open Access Journals (Sweden)

    Erika Piccillo

    2014-06-01

    Full Text Available Il progetto rigurda la scansione e la riproduzione, mediante tecnologia laser scanner 3D, di 19 reperti archeologici (datati dal IV al III secolo a.C. che, dal Museo Archeologico Regionale di Aidone (Sicilia, Italia sono stati dati in prestito, dopo il rientro della “Dea di Morgantina”, al The J.Paul Getty Museum di Malibu (California, USA, dove da aprile 2012 a gennaio 2013 si è tenuta la mostra temporanea “The Sanctuaries of Demeter andPersephoneat Morgantina”.Il caso studiato e documentato riguarda le scansioni, mediante prototipo David Lasercanner®dei suddetti reperti. Il lavoro è stato svolto al fine di documentare con la massima precisione e riprodurre  la copia virtuale fedele dei reperti dati in prestito al The J.Paul Getty Museum di Malibu, per poter verificare, al rientro degli stessi,il loro  stato dopo gli interventi di restauro eseguiti negli Stati Uniti oeventuali danneggiamenti dovuti al loro trasporto. Tali scansioni potrebbero in seguito anche essere utilizzate per aspetti volti alla promozione, alla fruizione (mostra virtualein situ o itinerante e la valorizzazione dei reperti presi in esame.  

  5. Comparison on the interaction of Al3+/nano-Al13 with calf thymus DNA /salmon sperm DNA

    Science.gov (United States)

    Ma, Fei; Ma, Yue; Du, Changwen; Yang, Xiaodi; Shen, Renfang

    2015-11-01

    The conformation change, binding mode and binding site between Al3+/nano-Al13 and calf thymus DNA/salmon sperm DNA were investigated by UV-vis absorption, FTIR spectra, Raman spectroscopy and CD spectra, as well as melting curves measurement. The UV-vis spectra and circular dichroism spectra results suggested that the phosphate group structure was changed when Al3+ interacted with DNA, while the double-helix was distorted when nano-Al13 interacted with DNA. The FTIR and Raman spectroscopy revealed that the binding sites were Al3+ … PO2, Al3+ … N7/guanine PO2 … Al13 … N7-C8/guanine with calf thymus DNA, and Al3+ … N3-O2/cytosine, Al3+ … N7-C8/guanine, PO2 … Al13 … N7-C8/guanine, PO2 … Al13 … N1/adenine with salmon sperm DNA, respectively. The electrostatic binding was existed between Al3+ and DNA, and the electrostatic binding and complexing were found between nano-Al13 and DNA.

  6. Case study: Beauty and the Beast 3D: benefits of 3D viewing for 2D to 3D conversion

    Science.gov (United States)

    Handy Turner, Tara

    2010-02-01

    From the earliest stages of the Beauty and the Beast 3D conversion project, the advantages of accurate desk-side 3D viewing was evident. While designing and testing the 2D to 3D conversion process, the engineering team at Walt Disney Animation Studios proposed a 3D viewing configuration that not only allowed artists to "compose" stereoscopic 3D but also improved efficiency by allowing artists to instantly detect which image features were essential to the stereoscopic appeal of a shot and which features had minimal or even negative impact. At a time when few commercial 3D monitors were available and few software packages provided 3D desk-side output, the team designed their own prototype devices and collaborated with vendors to create a "3D composing" workstation. This paper outlines the display technologies explored, final choices made for Beauty and the Beast 3D, wish-lists for future development and a few rules of thumb for composing compelling 2D to 3D conversions.

  7. Prinsip dan Ajaran Tasawuf ‘Abd Allâh al-Haddâd

    Directory of Open Access Journals (Sweden)

    Fikri Mahzumi

    2015-09-01

    Full Text Available ‘Abd Allâh al-Haddâd is a prominent figure who has great influence in many parts of the world, including Indonesia. His mystical teachings (tasawwuf, which are sunni, akhlâqî and ‘amalî, are oriented to guide morality of the society and, therefore, are more acceptable. A variety of his work, both in the form of books, wird, kasidah, and his Râtib are widely spread and practiced by many people, especially his followers. Al-Haddâd’s mystical orientation also puts emphasis on socio-moral movement. Among his mystical teachings are science, charity, khawf, wara‘, and sincerity which are based on al-Qur’ân, the Sunnah of the Prophet, and the example of the pious Salaf. Here, al-Haddâd was able to make renewal in the field of Sufism by reforming the segment and the orientation of the tarekat. If in the past tarekat was only familiar to elites, it then has been converged by al-Haddâd into two different segments, i.e. the tarekat of elite and and the tarekat of public, with the same orientation that is approaching to God. Through this reorientation, al-Haddâd had attempted to present Sufism as a social movement that raise morale both individuals and social groups. Keywords: Râtib, tasawwuf, the tarekat of elite, the tarekat of public.

  8. Synthesis and thermoluminescence of LaAlO3:Pr3+ to UVC radiation dosimetry

    International Nuclear Information System (INIS)

    Morales-Hernández, A.; Zarate-Medina, J.; Contreras-García, M.E.; Azorín-Nieto, J.; Rivera-Montalvo, T.

    2016-01-01

    Thermoluminescent (TL) response of trivalent praseodymium ion doped lanthanum aluminate (LaAlO 3 :Pr 3+ ) obtained by Pechini method and Spray Dryer was studied. TL response of LaAlO 3 :Pr 3+ powders submitted at 1600 °C exhibited one peak centered at 157 °C. Sensitivity of LaAlO 3 :Pr 3+ was improved in around 90 times compared with undoped LaAlO 3 . TL response as a function of wavelength showed a maximum in 230 nm. Dosimetric characteristics of LaAlO 3 :Pr 3+ under UVR radiation effects were analyzed. Evaluation of activation energy was obtained by Glow Fit v.1.3 software. Experimental results about thermoluminescent characteristics of LaAlO 3 :Pr 3+ suggest as good candidate to be employed as a complementary thermoluminescent device with other TL phosphors as aluminum oxide - Highlights: • High sensitivity of new phosphor to UVC dosimetry was is studied. • Thermoluminescence response of LaAlO 3 :Pr 3+ is presented. • LaAlO 3 :Pr 3+ is suggested as UVCR dosimeter. • TL response of LaAlO 3 :Pr 3+ has dependence on sintering temperature.

  9. Formation of Nb3Al in powder processed Nb-Al superconductors

    International Nuclear Information System (INIS)

    Johnson, P.E.

    1987-05-01

    In high magnetic fields, the critical current density is strongly dependent on the upper critical field, which is determined primarily by the stoichiometry of the Nb 3 Al. The critical temperature (T/sub c/), like the upper critical field, is considered to be a measure of the ''intrinsic'' quality of the superconductor, indicating the stoichiometry, order, and strain. If the A15 phase is stoichiometric and well ordered, a high T/sub c/ (and high H/sub C 2 /) is expected, regardless of the volume fraction of superconductor. On the other hand, if sigma phase is present with the A15, the resultant composition gradient across the sigma-A15 interface(s) requires that some of the A15 be off-stoichiometric, and therefore that the T/sub c/ (and H/sub C 2 /) be low. Thus the extent of the A15 (Nb 3 Al) reaction and the quality of the A15 formed are interdependent. This work focuses on the factors that control the extent of Nb 3 Al formation in Nb/Al powder wires. The morphology and content of the reacted and unreacted wires are studied in optical, SEM, and TEM micrographs. Critical current density data and its dependence on processing are explained in terms of the unreacted microstructure and its effect on the extent of Nb 3 Al formation. As a method of improving the critical current density, a new variation of the conventional powder process for wire manufacturing is developed and tested

  10. Wear protection in cutting tool applications by PACVD (Ti,Al)N and Al2O3 coatings

    International Nuclear Information System (INIS)

    Kathrein, M.; Heiss, M.; Rofner, R.; Schleinkofer, U.; Schintlmeister, W.; Schatte, J.; Mitterer, C.

    2001-01-01

    Various (Ti,Al)N-, Al 2 O 3 -, and (Ti,Al)N/Al 2 O 3 multilayer coatings were deposited onto cemented carbide cutting tool inserts by a plasma assisted chemical vapor deposition (PACVD) technique. Al 2 O 3 coatings were deposited using the gaseous mixture AlCl 3 , Ar, H 2 , and O 2 . (Ti,Al)N intermediate layers were deposited in the same device using the process mentioned and the gases AICl 3 , Ar, H 2 , TiCl 4 and N 2 . The unique properties of (Ti,Al)N/Al 2 O 3 multilayer coatings result in superior wear protection for cutting inserts applied in severe multifunction cutting processes. The influence of different deposition temperatures an structure and properties of the coatings like crystallographic phases, chemical composition, mechanical and technological properties is shown. PACVD (Ti,Al)N/Al 2 O 3 coated cutting inserts with fine grained crystalline α/κ-Al 2 O 3 offer performance advantages which are superior with respect to coatings deposited by chemical vapor deposition (CVD) due to the low deposition temperature applied. (author)

  11. Nanoscale spatial non-homogeneity of 3D in {delta}{sub {pi}} Mg{sub 0.9}Al{sub 0.1}B{sub 2} single crystals

    Energy Technology Data Exchange (ETDEWEB)

    Giubileo, F. [CNR-INFM Laboratorio Regionale SUPERMAT e Dipartimento di Fisica ' E.R. Caianiello' , Universita degli Studi di Salerno, via Salvador Allende, 84081 Baronissi (Italy)], E-mail: giubileo@sa.infn.it; Bobba, F.; Scarfato, A. [CNR-INFM Laboratorio Regionale SUPERMAT e Dipartimento di Fisica ' E.R. Caianiello' , Universita degli Studi di Salerno, via Salvador Allende, 84081 Baronissi (Italy); Roditchev, D. [Institut des Nanosciences de Paris, INSP, Universite P. et M.Curie Paris 6, CNRS, UMR 75-88, Paris (France); Zhigadlo, N.; Karpinski, J. [Solid State Physics Laboratory, ETH Zurich, CH-8093 Zurich (Switzerland); Cucolo, A.M. [CNR-INFM Laboratorio Regionale SUPERMAT e Dipartimento di Fisica ' E.R. Caianiello' , Universita degli Studi di Salerno, via Salvador Allende, 84081 Baronissi (Italy)

    2007-09-01

    We have performed I(V) and dI/dV(V) measurements on high quality Mg{sub 0.9}Al{sub 0.1}B{sub 2} single crystals by means of a variable temperature scanning tunneling spectroscopy (STS) working in magnetic field up to 7 T. c-axis tunneling showed a single gap, probing the three-dimensional Dp that appeared highly non-homogeneous in its spatial distribution on nanometer scale, with an amplitude between 1.5 meV and 2.3 meV. Temperature and magnetic field dependence of the conductance spectra were studied in S-I-N configuration as well as in S-I-S configuration, after pushing the Pt/Ir tip in the sample to capture a superconducting grain at the very apex of the tip. For the largest energy gap (2.3 meV), we found H{sub c2} {approx} 3 T, i.e., a 25% raising with respect to what observed in the pure crystal.

  12. Luminescence of Cr{sup 3+} ions in ZnAl{sub 2}O{sub 4} and MgAl{sub 2}O{sub 4} spinels: correlation between experimental spectroscopic studies and crystal field calculations

    Energy Technology Data Exchange (ETDEWEB)

    Brik, M.G., E-mail: mikhail.brik@ut.ee [College of Sciences, Chongqing University of Posts and Telecommunications, Chongqing 400065 (China); Institute of Physics, University of Tartu, W. Ostwald Str. 1, Tartu 50411 (Estonia); Institute of Physics, Jan Dlugosz University, Al. Armii Krajowej 13/15, Czestochowa PL-42200 (Poland); Papan, J.; Jovanović, D.J. [University of Belgrade, Vinča Institute of Nuclear Sciences, P.O. Box 522, Belgrade 11001 (Serbia); Dramićanin, M.D., E-mail: dramican@vinca.rs [University of Belgrade, Vinča Institute of Nuclear Sciences, P.O. Box 522, Belgrade 11001 (Serbia)

    2016-09-15

    Details of preparation, spectroscopic and structural studies along with crystal field calculations for two Cr{sup 3+} doped spinels MgAl{sub 2}O{sub 4} and ZnAl{sub 2}O{sub 4} are given in the present paper. Both compounds show efficient red emission at about 685 nm, which is due to the {sup 2}E{sub g} → {sup 4}A{sub 2g} spin-forbidden transition of Cr{sup 3+} ions located at the sites with D{sub 3d} local symmetry. Analysis of structure of the CrO{sub 6} clusters was performed; comparison of the crystal field effects in both compounds revealed that the low-symmetry splitting of the orbital triplet states is more pronounced in ZnAl{sub 2}O{sub 4}. Both compounds show potential for applications as red-emitting phosphors. - Highlights: • Cr{sup 3+}-doped MgAl{sub 2}O{sub 4} and ZnAl{sub 2}O{sub 4} spinels were synthesized. • Excitation/emission spectra were recorded and analyzed. • Symmetry properties of the Cr-sites were analyzed. • Cr{sup 3+} energy levels in trigonal crystal field were calculated. • Cr{sup 3+}-doped MgAl{sub 2}O{sub 4} and ZnAl{sub 2}O{sub 4} spinels can be used as red phosphors.

  13. Densification and mechanical properties of sintered Al{sub 2}O{sub 3}-Y{sub 3}Al{sub 5}O{sub 12} ceramic composite

    Energy Technology Data Exchange (ETDEWEB)

    Paneto, Flavio Jose; Pereira, Joaquim Lopes; Oliveira, Jean de Lima; Jesus Filho, Edson de; Silva, Leandro Anselmo da; Cabral, Ricardo de Freitas; Santos, Claudinei dos [Centro Universitario de Volta Redonda (UNIFOA), Volta Redonda, RJ (Brazil); Lima, Eduardo de Sousa [Institutlo Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil)

    2014-06-15

    In this work, Al{sub 2}O{sub 3}-Y{sub 3}Al{sub 5}O{sub 12} ceramic composites were developed with different proportions of Al{sub 2}O{sub 3}-Y{sub 3}Al{sub 5}O{sub 12}, which were mixed and compacted at different pressures of 40MPa to 100MPa, being consequently sintered at 1600 deg C-2h. The sintered samples were characterized by X-ray diffraction presenting α-Al{sub 2}O{sub 3} and Y{sub 3}Al{sub 5}O{sub 12} as crystalline phases. Samples with relative densities ranging from 78 to 80% and 87 to 91% were obtained depending on the composition and the compaction pressure used. The hardness values obtained were of 1010 to 1080HV and 370- 470HV, for mixes Al{sub 2}O{sub 3}-Y{sub 3}Al{sub 5}O{sub 12} having the composition with levels of 20 and 36.5wt.%, respectively. (author)

  14. Disordered crystal structure of 20H-AlON, Al10O3N8

    International Nuclear Information System (INIS)

    Banno, Hiroki; Funahashi, Shiro; Asaka, Toru; Hirosaki, Naoto; Fukuda, Koichiro

    2015-01-01

    The disordered crystal structure of 20H-AlON (Al 10 O 3 N 8 ) was determined by combined use of X-ray powder diffraction and transmission electron microscopy. The title compound is hexagonal with space group P6 3 /mmc (Z=2) and the unit-cell dimensions are a=0.307082(5) nm, c=5.29447(8) nm and V=0.432376(12) nm 3 . The structural model showed the positional disordering of three of the six Al sites in the unit cell. The reliability indices calculated from the Rietveld method were R wp =6.97%, S (=R wp /R e )=1.68, R p =5.45%, R B =5.13% and R F =4.56%. We interpreted the disordered structure of 20H-AlON as a statistical average of six different types of ordered structural configurations, which are composed of an octahedral [Al(O, N) 6 ] layer and tetrahedral [Al(O, N) 4 ] layers. We demonstrated the high correlations between the hexagonal unit-cell dimensions and the octahedral layer concentrations for AlON and SiAlON polytypoids. - Graphical abstract: Variations of a and c/(n O +n T ) with n O /(n O +n T ). The a and c are the hexagonal unit-cell dimensions of AlON, SiAlON and AlN. The n O and n T are, respectively, the numbers of octahedral and tetrahedral layers in the unit cells. The unit-cell dimensions in literature are plotted in black plus for AlON and black cross for SiAlON. The unit-cell dimensions of AlN are a=0.3110 nm and c=0.4980 nm. - Highlights: • Crystal structure of Al10O3N8 is determined by laboratory X-ray powder diffraction. • The atom arrangements are represented by the split-atom model. • Six types of ordered atom arrangements are derived from the disordered structure. • Hexagonal unit-cell dimensions changed systematically for AlON and SiAlON compounds

  15. Ho3+-doped AlF3-TeO2-based glass fibers for 2.1 µm laser applications

    Science.gov (United States)

    Wang, S. B.; Jia, Z. X.; Yao, C. F.; Ohishi, Y.; Qin, G. S.; Qin, W. P.

    2017-05-01

    Ho3+-doped AlF3-TeO2-based glass fibers based on AlF3-BaF2-CaF2-YF3-SrF2-MgF2-TeO2 glasses are fabricated by using a rod-in-tube method. The glass rod including a core and a thick cladding layer is prepared by using a suction method, where the thick cladding layer is used to protect the core from the effect of surface crystallization during the fiber drawing. By inserting the glass rod into a glass tube, the glass fibers with relatively low loss (~2.3 dB m-1 @ 1560 nm) are prepared. By using a 38 cm long Ho3+-doped AlF3-TeO2-based glass fiber as the gain medium and a 1965 nm fiber laser as the pump source, 2065 nm lasing is obtained for a threshold pump power of ~220 mW. With further increasing the pump power to ~325 mW, the unsaturated output power of the 2065 nm laser is about 82 mW and the corresponding slope efficiency is up to 68.8%. The effects of the gain fiber length on the lasing threshold, the slope efficiency, and the operating wavelength are also investigated. Our experimental results show that Ho3+-doped AlF3-TeO2-based glass fibers are promising gain media for 2.1 µm laser applications.

  16. Tribological Behavior of Plasma-Sprayed Al2O3-20 wt.%TiO2 Coating

    Science.gov (United States)

    Cui, Shiyu; Miao, Qiang; Liang, Wenping; Zhang, Zhigang; Xu, Yi; Ren, Beilei

    2017-05-01

    Al2O3-20 wt.% TiO2 ceramic coatings were deposited on the surface of Grade D steel by plasma spraying of commercially available powders. The phases and the microstructures of the coatings were investigated by x-ray diffraction and scanning electron microscopy, respectively. The Al2O3-20 wt.% TiO2 composite coating exhibited a typical inter-lamellar structure consisting of the γ-Al2O3 and the Al2TiO5 phases. The dry sliding wear behavior of the coating was examined at 20 °C using a ball-on-disk wear tester. The plasma-sprayed coating showed a low wear rate ( 4.5 × 10-6 mm3 N-1 m-1), which was matrix ( 283.3 × 10-6 mm3 N-1 m-1), under a load of 15 N. In addition, the tribological behavior of the plasma-sprayed coating was analyzed by examining the microstructure after the wear tests. It was found that delamination of the Al2TiO5 phase was the main cause of the wear during the sliding wear tests. A suitable model was used to simulate the wear mechanism of the coating.

  17. Cast Aluminum Alloys for High Temperature Applications Using Nanoparticles Al2O3 and Al3-X Compounds (X = Ti, V, Zr)

    Science.gov (United States)

    Lee, Jonathan A.

    2009-01-01

    In this paper, the effect of nanoparticles Al2O3 and Al3-X compounds (X = Ti, V, Zr) on the improvement of mechanical properties of aluminum alloys for elevated temperature applications is presented. These nanoparticles were selected based on their low cost, chemical stability and low diffusions rates in aluminum at high temperatures. The strengthening mechanism at high temperature for aluminum alloy is based on the mechanical blocking of dislocation movements by these nanoparticles. For Al2O3 nanoparticles, the test samples were prepared from special Al2O3 preforms, which were produced using ceramic injection molding process and then pressure infiltrated by molten aluminum. In another method, Al2O3 nanoparticles can also be homogeneously mixed with fine aluminum powder and consolidated into test samples through hot pressing and sintering. With the Al3-X nanoparticles, the test samples are produced as precipitates from in-situ reactions with molten aluminum using conventional permanent mold or die casting techniques. It is found that cast aluminum alloy using nanoparticles Al3-X is the most cost effective method to produce high strength aluminum alloys for high temperature applications in comparison to nanoparticles Al2O3. Furthermore, significant mechanical properties retention in high temperature environment could be achieved with Al3-X nanoparticles, resulting in tensile strength of nearly 3 times higher than most 300- series conventional cast aluminum alloys tested at 600 F.

  18. Una propuesta para incorporar más semántica de los modelos al código generado

    OpenAIRE

    Pérez Lovelle, Sonia; Cue Galindo, Julio C.; Hernández Perenzuela, Alexei; Arredondo López, Andry; Recio Nápoles, Luis R.; Carnero González, Frances

    2014-01-01

    Actualmente hay un amplio uso del paradigma Model Driven Architecture (MDA) para la generación de código a partir de modelos, pues esto garantiza menores tiempos de desarrollo y de puesta a punto. Los modelos creados a partir de los diagramas del Lenguaje Unificado de Modelado (UML) son de amplia utilización teniendo en cuenta que se trata de un estándar y además, la gran cantidad de herramientas de modelado que existen para ello. Cada diagrama de UML es un punto de vista diferente del sistem...

  19. Forged HITEMAL: Al-based MMCs strengthened with nanometric thick Al{sub 2}O{sub 3} skeleton

    Energy Technology Data Exchange (ETDEWEB)

    Balog, Martin, E-mail: ummsbama@savba.sk [Institute of Materials and Machine Mechanics, Slovak Academy of Sciences, Racianska 75, 83102 Bratislava (Slovakia); Krizik, Peter; Nosko, Martin; Hajovska, Zuzana [Institute of Materials and Machine Mechanics, Slovak Academy of Sciences, Racianska 75, 83102 Bratislava (Slovakia); Victoria Castro Riglos, Maria [Centro Atómico Bariloche, Av. Bustillo 9.500, 8400 Bariloche, Río Negro (Argentina); Rajner, Walter [New Materials Development GmbH, Römerstrasse 28, 83410 Laufen, Leobendorf (Germany); Liu, De-Shin [National Chung Cheng University, 168 University Rd., Min-Hsiung, 62102 Chia-Yi, Taiwan (China); Simancik, Frantisek [Institute of Materials and Machine Mechanics, Slovak Academy of Sciences, Racianska 75, 83102 Bratislava (Slovakia)

    2014-09-08

    Bulk Al–Al{sub 2}O{sub 3} metal matrix composites (MMCs) named HITEMAL (high temperature aluminum) were fabricated in situ by forging compaction of five different types of gas-atomized commercial purity Al powders with a mean particle size in the range of 1–9 µm. As-forged HITEMAL consisted of (sub)micrometric Al grains (matrix) decorated with nanometric thick amorphous Al{sub 2}O{sub 3} (a-Al{sub 2}O{sub 3}) skeleton. Low-angle grain boundaries (LAGBs) free of Al{sub 2}O{sub 3} were located in the Al grain interior. The Al grain size and the portion of LAGBs increased with the increase in the relative powder surface area. As-forged HITEMAL shows excellent thermal stability up to 400 °C for 24 h. Annealing at temperatures ≥450 °C led to crystallization and morphological transformation from a-Al{sub 2}O{sub 3} skeleton to nanometric γ-Al{sub 2}O{sub 3} particles. Owing to the pinning effect of Al{sub 2}O{sub 3} phase, no Al grain growth took place during annealing up to 500 °C. HITEMAL showed attractive mechanical properties especially when tested at 300 °C (yield strength up to 220 MPa, Young's modulus up to 58 GPa). Despite the presence of a nearly continuous a-Al{sub 2}O{sub 3} skeleton along adjacent Al grains, forged HITEMAL materials had reasonable room temperature elongation of 7–26%. HITEMAL's elongation decreased as the Al grain size decreased and with increased testing temperature. The loss in elongation (uniform and total) was attributed to the inhomogeneous flow, which occurred due to high densities of high angle grain boundaries (dislocation sinks) and small content of LAGBs. The strength of HITEMAL stemmed from grain boundary mediated strengthening mechanisms. The results showed a positive deviation from the Hall–Petch plot, which is typical behavior of ultrafine-grained metals. Transformation of a-Al{sub 2}O{sub 3} skeleton to γ-Al{sub 2}O{sub 3} particles led to deterioration of the HITEMAL strength and Young's modulus.

  20. Crystal structure of (Al,V)4(P4O12)3, archetype of double cubic ring tetraphosphate

    International Nuclear Information System (INIS)

    Yakubovich, O. V.; Biralo, G. V.; Dimitrova, O. V.

    2012-01-01

    The crystal structure of the (Al,V) 4 (P 4 O 12 ) 3 solid solution, obtained in the single-crystal form by hydrothermal synthesis in the Al(OH) 3 -VO 2 -NaCl-H 3 PO 4 -H 2 O system, has been solved by X-ray diffraction analysis (Xcalibur-S-CCD diffractometer, R = 0.0257): a = 13.7477(2) Å, sp. gr. I 4 bar 3d, Z = 4, and ρ calcd = 2.736 g/cm 3 . It is shown that the crystal structure of the parent cubic Al 4 (P 4 O 12 ) 3 modification can formally be considered an archetype for the formation of double isosymmetric tetraphosphates on its basis.

  1. Preparation of Mo/Al2O3 Sulfide Catalysts Modified by Ir Nanoparticles

    Czech Academy of Sciences Publication Activity Database

    Cinibulk, Josef; Vít, Zdeněk

    2002-01-01

    Roč. 143, - (2002), s. 443-451 ISSN 0167-2991. [International Symposium Scientific Bases for the Preparation of Heterogeneous Catalysts /8./. Louvain-la-Neuve, 09.09.2002-12.09.2002] R&D Projects: GA AV ČR IAA4072103 Keywords : catalysts modified * sulfide catalysts * Mo/Al2O3 Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.468, year: 2002

  2. Hot corrosion of the ceramic composite coating Ni{sub 3}Al-Al{sub 2}O{sub 3}-Al{sub 2}O{sub 3}/MgO plasma sprayed on 316L stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Shirazi, Amir Khodaparast; Kiahosseini, Seyed Rahim [Islamic Azad Univ., Damghan (Iran, Islamic Republic of). Dept. of Engineering

    2017-08-15

    Ni{sub 3}Al-Al{sub 2}O{sub 3}-Al{sub 2}O{sub 3}/MgO three-layered coatings with thicknesses of 50, 100, and 150 μm for Al{sub 2}O{sub 3}/MgO and 100 μm for the other layers were deposited on 316L stainless steel using plasma spraying. X-ray diffraction, atomic force microscopy, furnace hot corrosion testing in the presence of a mixture of Na{sub 2}SO{sub 4} and V{sub 2}O{sub 5} corrosive salts and scanning electron microscopy were used to determine the structural, morphological and hot corrosion resistance of samples. Results revealed that the crystalline grains of MgO and Al{sub 2}O{sub 3} coating were very small. Weight loss due to hot corrosion decreased from approximately 4.267 g for 316L stainless steel without coating to 2.058 g. The samples with 150 μm outer coating showed improved resistance with the increase in outer layer thickness. Scanning electron microscopy of the coated surface revealed that the coating's resistance to hot corrosion is related to the thickness and the grain size of Al{sub 2}O{sub 3}/MgO coatings.

  3. Temperature dependence of microstructure and strain evolution in strained ZnO films on Al2O3(0001)

    International Nuclear Information System (INIS)

    Kim, In-Woo; Lee, Kyu-Mann

    2008-01-01

    We have studied the temperature dependence of the growth mode and microstructure evolution in highly mismatched sputter-grown ZnO/Al 2 O 3 (0001) heteroepitaxial films. The growth mode was studied by real-time synchrotron x-ray scattering. We find that the growth mode changes from a two-dimensional (2D) layer to a 3D island in the early growth stage with temperature (300-600 deg. C), in sharp contrast to the reported transition from three dimensions to two dimensions in metal-organic vapor phase epitaxy. At around 400 deg. C intermediate 2D platelets nucleate in the early stage, which act as nucleation cores of 3D islands and transform to a misaligned state during further growth. Meanwhile, at high temperature (above 500 deg. C), the spinel structure of ZnAl 2 O 4 grows in the early stage, and it undergoes a transition to wurtzite-ZnO (w-ZnO) with thickness. The spinel formation is presumably driven by high temperature and large incident energy of impacting atoms during sputtering. The results of the strain evolution as functions of temperature and thickness during growth suggest that the surface diffusion is a major factor determining the microstructural properties in the strained ZnO/Al 2 O 3 (0001) heteroepitaxy

  4. Refined 3d-3d correspondence

    Energy Technology Data Exchange (ETDEWEB)

    Alday, Luis F.; Genolini, Pietro Benetti; Bullimore, Mathew; Loon, Mark van [Mathematical Institute, University of Oxford, Andrew Wiles Building,Radcliffe Observatory Quarter, Woodstock Road, Oxford, OX2 6GG (United Kingdom)

    2017-04-28

    We explore aspects of the correspondence between Seifert 3-manifolds and 3d N=2 supersymmetric theories with a distinguished abelian flavour symmetry. We give a prescription for computing the squashed three-sphere partition functions of such 3d N=2 theories constructed from boundary conditions and interfaces in a 4d N=2{sup ∗} theory, mirroring the construction of Seifert manifold invariants via Dehn surgery. This is extended to include links in the Seifert manifold by the insertion of supersymmetric Wilson-’t Hooft loops in the 4d N=2{sup ∗} theory. In the presence of a mass parameter for the distinguished flavour symmetry, we recover aspects of refined Chern-Simons theory with complex gauge group, and in particular construct an analytic continuation of the S-matrix of refined Chern-Simons theory.

  5. Antimicrobial effect of Al2O3, Ag and Al2O3/Ag thin films on Escherichia coli and Pseudomonas putida

    International Nuclear Information System (INIS)

    Angelov, O; Stoyanova, D; Ivanova, I; Todorova, S

    2016-01-01

    The influence of Al 2 O 3 , Ag and Al 2 O 3 /Ag thin films on bacterial growth of Gramnegative bacteria Pseudomonas putida and Escherichia coli is studied. The nanostructured thin films are deposited on glass substrates without intentional heating through r.f. magnetron sputtering in Ar atmosphere of Al 2 O 3 and Ag targets or through sequential sputtering of Al 2 O 3 and Ag targets, respectively. The individual Ag thin films (thickness 8 nm) have a weak bacteriostatic effect on Escherichia coli expressed as an extended adaptive phase of the bacteria up to 5 hours from the beginning of the experiment, but the final effect is only 10 times lower bacterial density than in the control. The individual Al 2 O 3 film (20 nm) has no antibacterial effect against two strains E. coli - industrial and pathogenic. The Al 2 O 3 /Ag bilayer films (Al 2 O 3 20 nm/Ag 8 nm) have strong bactericidal effect on Pseudomonas putida and demonstrate an effective time of disinfection for 2 hours. The individual films Al2O3 and Ag have not pronounced antibacterial effect on Pseudomonas putida . A synergistic effect of Al2O3/Ag bilayer films in formation of oxidative species on the surface in contact with the bacterial suspension could be a reason for their antimicrobial effect on E. coli and P. putida . (paper)

  6. Modelado urbano a microescala: contribución al confort urbano de ecosistemas áridos

    OpenAIRE

    Roca, G.; Puliafito, S.; Allende, D.; Ruggieri, F.; Pascual Flores, R.

    2016-01-01

    Este trabajo es la continuación de estudios anteriores, mejorando los criterios de selección, evaluación y clasificación. Describe la formulación y evaluación de un Modelo de Confort Urbano a Microescala, que permite describir y estimar el impacto de la antropización a nivel local, con el propósito de ayudar en la toma de decisiones relacionadas al confort urbano. La conformación de hábitats urbanos de escala media en zonas áridas, requiere estudios puntuales que hasta el momento no se han re...

  7. Thermal conductivity and viscosity of Al2O3 nanofluid based on car engine coolant

    International Nuclear Information System (INIS)

    Kole, Madhusree; Dey, T K

    2010-01-01

    Various suspensions containing Al 2 O 3 nanoparticles ( 2 O 3 nanoparticles as well as temperature between 10 and 80 0 C. The prepared nanofluid, containing only 0.035 volume fraction of Al 2 O 3 nanoparticles, displays a fairly higher thermal conductivity than the base fluid and a maximum enhancement (k nf /k bf ) of ∼10.41% is observed at room temperature. The thermal conductivity enhancement of the Al 2 O 3 nanofluid based on engine coolant is proportional to the volume fraction of Al 2 O 3 . The volume fraction and temperature dependence of the thermal conductivity of the studied nanofluids present excellent correspondence with the model proposed by Prasher et al (2005 Phys. Rev. Lett. 94 025901), which takes into account the role of translational Brownian motion, interparticle potential and convection in fluid arising from Brownian movement of nanoparticles for thermal energy transfer in nanofluids. Viscosity data demonstrate transition from Newtonian characteristics for the base fluid to non-Newtonian behaviour with increasing content of Al 2 O 3 in the base fluid (coolant). The data also show that the viscosity increases with an increase in concentration and decreases with an increase in temperature. An empirical correlation of the type log(μ nf ) = A exp(-BT) explains the observed temperature dependence of the measured viscosity of Al 2 O 3 nanofluid based on car engine coolant. We further confirm that Al 2 O 3 nanoparticle concentration dependence of the viscosity of nanofluids is very well predicted on the basis of a recently reported theoretical model (Masoumi et al 2009 J. Phys. D: Appl. Phys. 42 055501), which considers Brownian motion of nanoparticles in the nanofluid.

  8. YouDash3D: exploring stereoscopic 3D gaming for 3D movie theaters

    Science.gov (United States)

    Schild, Jonas; Seele, Sven; Masuch, Maic

    2012-03-01

    Along with the success of the digitally revived stereoscopic cinema, events beyond 3D movies become attractive for movie theater operators, i.e. interactive 3D games. In this paper, we present a case that explores possible challenges and solutions for interactive 3D games to be played by a movie theater audience. We analyze the setting and showcase current issues related to lighting and interaction. Our second focus is to provide gameplay mechanics that make special use of stereoscopy, especially depth-based game design. Based on these results, we present YouDash3D, a game prototype that explores public stereoscopic gameplay in a reduced kiosk setup. It features live 3D HD video stream of a professional stereo camera rig rendered in a real-time game scene. We use the effect to place the stereoscopic effigies of players into the digital game. The game showcases how stereoscopic vision can provide for a novel depth-based game mechanic. Projected trigger zones and distributed clusters of the audience video allow for easy adaptation to larger audiences and 3D movie theater gaming.

  9. Optical microcavities and enhanced electroluminescence from electroformed Al-Al{sub 2}O{sub 3}-Ag diodes

    Energy Technology Data Exchange (ETDEWEB)

    Hickmott, T. W. [Department of Physics, State University of New York at Albany, Albany, New York 12222 (United States)

    2013-12-21

    Electroluminescence (EL) and electron emission into vacuum (EM) occur when a non-destructive dielectric breakdown of Al-Al{sub 2}O{sub 3}-Ag diodes, electroforming, results in the development of a filamentary region in which current-voltage (I-V) characteristics exhibit voltage-controlled negative resistance. The temperature dependence of I-V curves, EM, and, particularly, EL of Al-Al{sub 2}O{sub 3}-Ag diodes with anodic Al{sub 2}O{sub 3} thicknesses between 12 nm and 30 nm, has been studied. Two filters, a long-pass (LP) filter with transmission of photons with energies less than 3.0 eV and a short-pass (SP) filter with photon transmission between 3.0 and 4.0 eV, have been used to characterize EL. The voltage threshold for EL with the LP filter, V{sub LP}, is ∼1.5 V. V{sub LP} is nearly independent of Al{sub 2}O{sub 3} thickness and of temperature and is 0.3–0.6 V less than the threshold voltage for EL for the SP filter, V{sub SP}. EL intensity is primarily between 1.8 and 3.0 eV when the bias voltage, V{sub S} ≲ 7 V. EL in the thinnest diodes is enhanced compared to EL in thicker diodes. For increasing V{sub S}, for diodes with the smallest Al{sub 2}O{sub 3} thicknesses, there is a maximum EL intensity, L{sub MX}, at a voltage, V{sub LMX}, followed by a decrease to a plateau. L{sub MX} and EL intensity at 4.0 V in the plateau region depend exponentially on Al{sub 2}O{sub 3} thickness. The ratio of L{sub MX} at 295 K for a diode with 12 nm of Al{sub 2}O{sub 3} to L{sub MX} for a diode with 25 nm of Al{sub 2}O{sub 3} is ∼140. The ratio of EL intensity with the LP filter to EL intensity with the SP filter, LP/SP, varies between ∼3 and ∼35; it depends on Al{sub 2}O{sub 3} thickness and V{sub S}. Enhanced EL is attributed to the increase of the spontaneous emission rate of a dipole in a non-resonant optical microcavity. EL photons interact with the Ag and Al films to create surface plasmon polaritons (SPPs) at the metal-Al{sub 2}O

  10. Influence of Al{sub 2}O{sub 3} addition on microstructure and mechanical properties of 3YSZ-Al{sub 2}O{sub 3} composites

    Energy Technology Data Exchange (ETDEWEB)

    Abden, Md. Jaynul [International Islamic Univ., Chittagong (Bangladesh). Dept. of Electrical and Electronic Engineering; Afroze, Jannatul Dil [Noakhali Science and Technology Univ. (Bangladesh). Faculty of Science and Engineering; Gafur, Md. Abdul [Bangladesh Council of Scientific and Industrial Research, Dhaka (Bangladesh). Pilot Plant and Process Development Centre; Chowdhury, Faruque-Uz-Zaman [Chittagong University of Engineering and Technology (Bangladesh). Dept. of Physics

    2015-07-01

    The effect of the amount of Al{sub 2}O{sub 3} content on microstructure, tetragonal phase stability and mechanical properties of 3YSZ-Al{sub 2}O{sub 3} composites are investigated in this study. The ceramic composites are obtained by means of uniaxial compacting at 210 MPa and green compacts are sintered at 1550 C for 3 h in air. The monoclinic zirconia (m-ZrO{sub 2}) phase has completely been transformed into tetragonal zirconia (t-ZrO{sub 2}) phase with corresponding higher Al{sub 2}O{sub 3} content. The t-ZrO{sub 2} grains induce transgranular fracture mode that has contribution in improvement of fracture toughness. The maximum flexural strength of 340 MPa, Vickers hardness value of 14.31 GPa and fracture toughness of 5.1 MPa x m{sup 1/2} in the composition containing 40 wt.-% Al{sub 2}O{sub 3} is attributed to the microstructure with t-ZrO{sub 2} grains as inter- and intragranular particles in the Al{sub 2}O{sub 3} grains, which makes it suitable for dental applications.

  11. Tunable Electron-Electron Interactions in LaAlO_{3}/SrTiO_{3} Nanostructures

    Directory of Open Access Journals (Sweden)

    Guanglei Cheng

    2016-12-01

    Full Text Available The interface between the two complex oxides LaAlO_{3} and SrTiO_{3} has remarkable properties that can be locally reconfigured between conducting and insulating states using a conductive atomic force microscope. Prior investigations of “sketched” quantum dot devices revealed a phase in which electrons form pairs, implying a strongly attractive electron-electron interaction. Here, we show that these devices with strong electron-electron interactions can exhibit a gate-tunable transition from a pair-tunneling regime to a single-electron (Andreev bound state tunneling regime where the interactions become repulsive. The electron-electron interaction sign change is associated with a Lifshitz transition where the d_{xz} and d_{yz} bands start to become occupied. This electronically tunable electron-electron interaction, combined with the nanoscale reconfigurability of this system, provides an interesting starting point towards solid-state quantum simulation.

  12. Ab initio study on the thermal properties of the fcc Al3Mg and Al3Sc alloys

    International Nuclear Information System (INIS)

    Li Donglin; Chen Ping; Yi Jianxiong; Tang Biyu; Peng Liming; Ding Wenjiang

    2009-01-01

    Ab initio density functional theory (DFT) and density function perturbation theory (DFPT) have been used to investigate the thermal properties of the fcc Al 3 Mg and Al 3 Sc alloys over a wide range of pressure and temperature, in comparison with fcc Al. Phonon dispersions were obtained at equilibrium and strained configurations by density functional perturbation theory. Using the quasiharmonic approximation for the free energy, several thermal quantities of interest, such as the thermal Grueneisen parameter, heat capacity, thermal expansion coefficient and entropy, were calculated as a function of temperature and pressure, and the variation features of these quantities were discussed in detail. This investigation provides useful information for design and applications of technologically relevant Al-based alloys.

  13. Landslide/reservoir interaction: 3D numerical modelling of the Vajont rockslide and generated water wave

    Science.gov (United States)

    Crosta, G.; Imposimato, S.; Roddeman, D.; Frattini, P.

    2012-04-01

    Fast moving landslides can be originated along slopes in mountainous terrains with natural and artificial lakes, or fjords at the slope foot. This landslides can reach extremely high speed and the impact with the immobile reservoir water can be influenced by the local topography and the landslide mass profile. The impact can generate large impulse waves and landslide tsunami. Initiation, propagation and runup are the three phases that need to be considered. The landslide evolution and the consequent wave can be controlled by the initial mass position (subaerial, partially or completely submerged), the landslide speed, the type of material, the subaerial and subaqueous slope geometry, the landslide depth and length at the impact, and the water depth. Extreme events have been caused by subaerial landslides: the 1963 Vajont rockslide (Italy), the 1958 Lituya Bay event (Alaska), the Tafjord and the Loen multiple events event (Norway), also from volcanic collapses (Hawaii and Canary islands). Various researchers completed a systematic experimental work on 2D and 3D wave generation and propagation (Kamphuis and Bowering, 1970; Huber, 1980; Müller, 1995; Huber and Hager, 1997; Fritz, 2002; Zweifel, 2004; Panizzo et al., 2005; Heller, 2007; Heller and Kinnear, 2010; Sælevik et al., 2009), using both rigid blocks and deformable granular" masses. Model data and results have been used to calibrate and validate numerical modelling tools (Harbitz, 1992; Jiang and LeBlond, 1993; Grilli et al., 2002; Grilli and Watts, 2005; Lynett and Liu, 2005; Tinti et al., 2006; Abadie et al., 2010) generally considering simplified rheologies (e.g. viscous rheologies) for subaerial subaqueous spreading. We use a FEM code (Roddeman, 2011; Crosta et al., 2006, 2009, 2010, 2011) adopting an Eulerian-Lagrangian approach to give accurate results for large deformations. We model both 2D and fully 3D events considering different settings. The material is considered as a fully deformable elasto

  14. Spectrum designation and effect of Al substitution on the luminescence of Cr3+ doped ZnGa2O4 nano-sized phosphors

    International Nuclear Information System (INIS)

    Zhang Weiwei; Zhang Junying; Chen Ziyu; Wang Tianmin; Zheng Shukai

    2010-01-01

    Low-temperature photoluminescent spectra of ZnGa 2 O 4 :Cr 3+ nano-sized phosphors calcined at different temperatures were reported. The fine structure of the emission spectra has been designated to Cr 3+ ions in different sites including ideal octahedral, Zn-interstitial, Ga ZN 4 -Zn Ga 6 sites and Ga 2 O 3 impurity. The vibronic sidebands for both Stokes' and anti-Stokes' sides are related to the host lattice vibrations, which were confirmed by IR and Raman spectra. Al 3+ is substituted in Ga 3+ sites to form Zn(Ga 1-y Al y ) 2 O 4 :Cr 0.01 3+ (0≤y≤0.5). The blue shift and luminescent intensity variations of the charge transfer band and 3d-3d transitions in the spectra caused by Al substitution were related to larger band gap and stronger crystal field, respectively. The calculated crystal-field parameters indicated that Al incorporation enhanced the crystal field strength and induced more trigonal distortion due to different radii of Al 3+ and Ga 3+ .

  15. Recent advances in alloy design of Ni{sub 3}Al alloys for structural use

    Energy Technology Data Exchange (ETDEWEB)

    Liu, C.T.; George, E.P.

    1996-12-31

    This is a comprehensive review of recent advances in R&D of Ni{sub 3}Al-based alloys for structural use at elevated temperatures in hostile environments. Recent studies indicate that polycrystalline Ni{sub 3}Al is intrinsically quite ductile at ambient temperatures, and its poor tensile ductility and brittle grain-boundary fracture are caused mainly by moisture-induced hydrogen embrittlement when the aluminide is tested in moisture- or hydrogen-containing environments. Tensile ductility is improved by alloying with substitutional and interstitial elements. Among these additives, B is most effective in suppressing environmental embrittlement and enhancing grain-boundary cohesion, resulting in a dramatic increase of tensile ductility at room temperature. Both B-doped and B-free Ni{sub 3}Al alloys exhibit brittle intergranular fracture and low ductility at intermediate temperatures (300-850 C) because of oxygen-induced embrittlement in oxidizing environments. Cr is found to be most effective in alleviating elevated-temperature embrittlement. Parallel efforts on alloy development using physical metallurgy principles have led to development of several Ni{sub 3}Al alloys for industrial use. The unique properties of these alloys are briefly discussed. 56 refs, 15 figs, 3 tabs.

  16. Crystal structures of hydrates of simple inorganic salts. III. Water-rich aluminium halide hydrates: AlCl3 · 15H2O, AlBr3 · 15H2O, AlI3 · 15H2O, AlI3 · 17H2O and AlBr3 · 9H2O.

    Science.gov (United States)

    Schmidt, Horst; Hennings, Erik; Voigt, Wolfgang

    2014-09-01

    Water-rich aluminium halide hydrate structures are not known in the literature. The highest known water content per Al atom is nine for the perchlorate and fluoride. The nonahydrate of aluminium bromide, stable pentadecahydrates of aluminium chloride, bromide and iodide, and a metastable heptadecahydrate of the iodide have now been crystallized from low-temperature solutions. The structures of these hydrates were determined and are discussed in terms of the development of cation hydration spheres. The pentadecahydrate of the chloride and bromide are isostructural. In AlI(3) · 15H2O, half of the Al(3+) cations are surrounded by two complete hydration spheres, with six H2O in the primary and 12 in the secondary. For the heptadecahydrate of aluminium iodide, this hydration was found for every Al(3+).

  17. Tailored white light emission in Eu3+/Dy3+ doped tellurite glass phosphors containing Al3+ ions

    Science.gov (United States)

    Walas, Michalina; Piotrowski, Patryk; Lewandowski, Tomasz; Synak, Anna; Łapiński, Marcin; Sadowski, Wojciech; Kościelska, Barbara

    2018-05-01

    Tellurite glass systems modified by addition of aluminum fluoride AlF3 have been successfully synthesized as host matrices for optically active rare earth ions RE3+ (RE3+ = Eu3+, Dy3+). Samples with different Eu3+ to Dy3+ molar ratio have been studied in order to determine possibility of white light emission via UV excitation. Structural investigations confirmed amorphous character of materials whereas spectroscopic studies brought more insight into glass network's nature. FTIR results shown presence of two features related to tellurite glass matrix (in 490-935 cm-1 spectral region) and another one (940-1250 cm-1) due to aluminum addition. Especially, Al-O and Te-O-Al bonds of AlO4 tetrahedrons have been found. AlO4 units are considered as glass formers that improve network's strength and thermal resistivity against devitrification. Based on XPS studies of Al3+ photoelectron band the existence of Al-O and also Al-F bonds have been examined. Moreover, signals originating from Eu3+ and Dy3+ have been found confirming their valence state. Luminescence results revealed possibility of simultaneous UV excitation of Eu3+ and Dy3+ ions. Excitation with λexc = 390 and 393 nm resulted in white light generation starting from warm white to neutral and cool white depending on Eu3+ concentration and used excitation wavelength. Additionally, increase of decay lifetime of Eu3+ induced by Al3+ presence have been revealed based on luminescence decay analysis. Thus, tellurite glass systems modified by AlF3 and doped with Eu3+/Dy3+ may be considered as promising candidates for white light emitting sources.

  18. Synthesis behavior of nanocrystalline Al-Al2O3 composite during low time mechanical milling process

    International Nuclear Information System (INIS)

    Alizadeh, Mostafa; Aliabadi, Morteza Mirzaei

    2011-01-01

    Research highlights: → In the low time milling the effect of Al 2 O 3 amount is investigated → Al 2 O 3 particles are distributed uniformly in the Al matrix → In the low time milling it is possible to produce nanostructured composite powder → Median size and bulk density measurements demonstrate reaching the steady state. - Abstract: In this work, four different volume fractions of Al 2 O 3 (10, 20, 30 and 40 vol.%) were mixed with the fine Al powder and the powder blends were milled for 5 h. Scanning electron microscopy analysis, particle size analysis and bulk density measurements were used to investigate the morphological changes and achieving the steady state conditions. The results showed that increasing the Al 2 O 3 content can provide the steady state particle size in 5 h milling process. It was found that increasing the volume fraction of Al 2 O 3 leads to increasing the uniformity of Al 2 O 3 . Standard deviations of microhardness measurements confirmed this result. The XRD pattern and XRF investigations depicted that increasing the Al 2 O 3 content causes an increase in the crystal defects, micro-strain and Fe contamination during 5 h milling process of nanocrystalline composite powders while the grain size is decreased. To investigate the effect of milling time, Al-30 vol.% Al 2 O 3 (which achieved steady state during 5 h milling process) was milled for 1-4 h. The results depicted that the milling time lower than 5 h, do not achieve to steady state conditions.

  19. Virtualización de Villava mediante Google Earth y realidad aumentada: modelado 3D, geolocalización y códigos QR

    OpenAIRE

    Olleta Aquerreta, Miguel; Alonso González, Raúl

    2013-01-01

    El objetivo principal de este proyecto es crear una virtualización de Villava para dar a conocer la localidad de una forma nueva, cómoda, sencilla y visual tanto a gente de Villava como a gente que venga a visitarla, de tal forma que puedan moverse por el pueblo de manera segura y teniendo nociones de la localización de los puntos de interés o de los lugares a los que quieran acudir. Aparte también deseamos lograr la aparición del modelo en 3D de algunos edificios importantes de Villava e...

  20. 3D structure determination from electron-microscope images: Electron crystallography of staurolite. [HFe[sub 2]Al[sub 9]Si[sub 4]O[sub 24

    Energy Technology Data Exchange (ETDEWEB)

    Wenk, H.R.; Hu Meisheng (California Univ., Berkeley, CA (United States). Dept. of Geology and Geophysics); Downing, K.H. (Lawrence Berkeley Lab., CA (United States). Donner Lab.); O' Keefe, M.A. (Lawrence Berkeley Lab., CA (United States). National Center for Electron Microscopy)

    1992-09-01

    Resolution of better than 2 A has been obtained in many crystals by high-resolution electron microscopy. Although this resolution is sufficient to resolve interatomic spacings, structures are traditionally interpreted by comparing experimental images with contrast calculations. A drawback of this method is that images are 2D projections in which information is invariably obscured by overlap of atoms. 3D electron crystallography, developed by biophysicists to study proteins, has been used to investigate the crystal structure of staurolite. Amplitudes and phases of structure factors are obtained experimentally from high-resolution images (JEOL ARM 1000 at the National Center for Electron Microscopy at LBL), taken in different directions from thin regions where dynamic scattering is minimal. From images in five orientations (containing 59 independent reflections to a resolution of 1.38 A), a 3D electron potential map is constructed which resolves clearly all cations (Al, Si, Fe, including those with partial occupancy) and all O atoms. This method has great potential in crystal structure determinations of small domains in heterogeneous crystals which are inaccessible to X-ray analysis. It is estimated that 3D structure determinations should be possible on regions only about ten unit cells wide and should resolve not only atom positions but also site occupancies. The method is also applicable to space-group determination. (orig.).

  1. 3D-mallien muokkaus 3D-tulostamista varten CAD-ohjelmilla

    OpenAIRE

    Lehtimäki, Jarmo

    2013-01-01

    Insinöörityössäni käsitellään 3D-mallien tulostamista ja erityisesti 3D-mallien mallintamista niin, että kappaleiden valmistaminen 3D-tulostimella onnistuisi mahdollisimman hyvin. Työ tehtiin Prohoc Oy:lle, joka sijaitsee Vaasassa. 3D-tulostuspalveluun tuli jatkuvasti 3D-malleja, joiden tulostuksessa oli ongelmia. Työssäni tutkin näiden ongelmien syntyä ja tein ohjeita eri 3D-mallinnusohjelmille, joiden tarkoituksena on auttaa tekemään helpommin tulostettavia 3D-malleja. Työhön kuului myös et...

  2. Compréhension de la stabilité thermique des alliages d'aluminium Al-Cu-Mg Understanding of the thermal stability of Al-Cu-Mg aluminum alloys

    Directory of Open Access Journals (Sweden)

    Pouget Gaëlle

    2013-11-01

    Full Text Available Les alliages d'aluminium 2xxx (Al-Cu-Mg sont connus pour être performants à chaud et sont par exemple utilisés pour certaines pièces de structure des avions. L'effet de la composition en Cu et Mg sur leur stabilité thermique, ainsi que celui de la précipitation durcissante associée ont été étudiés. Des comportements différents sont observés et trois zones de composition (en poids % identifiées: 3,1–3,7Cu et 1,6–2,0Mg : durcissement par la phase S' (Al2CuMg, limite d'élasticité ∼ 465 MPa à l'état T8 et bonne stabilité thermique jusqu'à 200 ∘C. 4,8–5,4Cu et 0–0,4Mg : durcissement par la phase θ' (Al2Cu, limite d'élasticité ∼ 380 MPa à l'état T8 et bonne stabilité thermique jusqu'à 300 ∘C. 3,7–4,3Cu et 0,9–1,3Mg : durcissement par S'+ θ', limite d'élasticité ∼ 470 MPa à l'état T8 mais stabilité thermique insuffisante à 150 ∘C et au delà; ce vieillissement important est associé à une concentration en Cu en solution solide élevée, ce qui accélère la cinétique de coalescence des précipités. La première zone de composition est donc recommandée pour des applications à température intermédiaire, typiquement 150 ∘C, et la seconde pour des applications à plus haute température, entre 250 et 300 ∘C. La troisième zone est à éviter pour des applications à 150 ∘C et au-delà. 2xxx aluminum alloys (Al-Cu-Mg have a good behaviour at elevated temperature and are used for some aircraft's structural parts. In this study, the effect of Cu and Mg content on the thermal stability and strengthening precipitation has been investigated. Three different behaviours are observed depending on the alloy composition: 3.1–3.7Cu, 1.6–2.0Mg: strengthening by S' (Al2CuMg, yield strength ∼ 465 MPa in T8 temper and good thermal stability up to 200 ∘C. 4.8–5.4Cu, 0–0.4Mg: strengthening by θ' (Al2Cu, yield strength ∼ 380 MPa in T8 and good thermal stability up to

  3. 3D imaging, 3D printing and 3D virtual planning in endodontics.

    Science.gov (United States)

    Shah, Pratik; Chong, B S

    2018-03-01

    The adoption and adaptation of recent advances in digital technology, such as three-dimensional (3D) printed objects and haptic simulators, in dentistry have influenced teaching and/or management of cases involving implant, craniofacial, maxillofacial, orthognathic and periodontal treatments. 3D printed models and guides may help operators plan and tackle complicated non-surgical and surgical endodontic treatment and may aid skill acquisition. Haptic simulators may assist in the development of competency in endodontic procedures through the acquisition of psycho-motor skills. This review explores and discusses the potential applications of 3D printed models and guides, and haptic simulators in the teaching and management of endodontic procedures. An understanding of the pertinent technology related to the production of 3D printed objects and the operation of haptic simulators are also presented.

  4. Potential of HfN, ZrN, and TiH as hot carrier absorber and Al2O3/Ge quantum well/Al2O3 and Al2O3/PbS quantum dots/Al2O3 as energy selective contacts

    Science.gov (United States)

    Shrestha, Santosh; Chung, Simon; Liao, Yuanxun; Wang, Pei; Cao, Wenkai; Wen, Xiaoming; Gupta, Neeti; Conibeer, Gavin

    2017-08-01

    The hot carrier (HC) solar cell is one of the most promising advanced photovoltaic concepts. It aims to minimise two major losses in single junction solar cells due to sub-band gap loss and thermalisation of above band gap photons by using a small bandgap absorber, and, importantly, collecting the photo-generated carriers before they thermalise. In this paper we will present recent development of the two critical components of the HC solar cell, i.e., the absorber and energy selective contacts (ESCs). For absorber, fabrication and carrier cooling rates in potential bulk materials — hafnium nitride, zirconium nitride, and titanium hydride are presented. Results of ESCs employing double barrier resonant tunneling structures Al2O3/Ge quantum well (QW)/Al2O3 and Al2O3/PbS quantum dots (QDs)/Al2O3 are also presented. These results are expected to guide further development of practical HC solar cell devices.

  5. Phase relations in the SiC-Al2O3-Pr2O3 system

    International Nuclear Information System (INIS)

    Pan, W.; Wu, L.; Jiang, Y.; Huang, Z.

    2016-01-01

    Phase relations in the Si-Al-Pr-O-C system, including the SiC-Al 2 O 3 -Pr 2 O 3 , the Al 2 O 3 -Pr 2 O 3 -SiO 2 and the SiC-Al 2 O 3 -Pr 2 O 3 -SiO 2 subsystems, were determined by means of XRD phase analysis of solid-state-reacted samples fabricated by using SiC, Al 2 O 3 , Pr 2 O 3 and SiO 2 powders as the starting materials. Subsolidus phase diagrams of the systems were presented. Two Pr-aluminates, namely PrAlO 3 (PrAP) and PrAl 11 O 18 (β(Pr) β-Al 2 O 3 type) were formed in the SiC-Al 2 O 3 -Pr 2 O 3 system. SiC was compatible with both of them. Pr-silicates of Pr 2 SiO 5 , Pr 2 Si 2 O 7 and Pr 9.33 Si 6 O 26 (H(Pr) apatite type) were formed owing to presence of SiO 2 impurity in the SiC powder. The presence of the SiO 2 extended the ternary system of SiC-Al 2 O 3 -Pr 2 O 3 into a quaternary system of SiC-Al 2 O 3 -SiO 2 -Pr 2 O 3 (Si-Al-Pr-O-C). SiC was compatible with Al 2 O 3 , Pr 2 O 3 and the Pr-silicates. The effect of SiO 2 on the phase relations and liquid phase sintering of SiC ceramics was discussed.

  6. 3D Cloud Radiative Effects on Polarized Reflectances

    Science.gov (United States)

    Cornet, C.; Matar, C.; C-Labonnote, L.; Szczap, F.; Waquet, F.; Parol, F.; Riedi, J.

    2017-12-01

    As recognized in the last IPCC report, clouds have a major importance in the climate budget and need to be better characterized. Remote sensing observations are a way to obtain either global observations of cloud from satellites or a very fine description of clouds from airborne measurements. An increasing numbers of radiometers plan to measure polarized reflectances in addition to total reflectances, since this information is very helpful to obtain aerosol or cloud properties. In a near future, for example, the Multi-viewing, Multi-channel, Multi-polarization Imager (3MI) will be part the EPS-SG Eumetsat-ESA mission. It will achieve multi-angular polarimetric measurements from visible to shortwave infrared wavelengths. An airborne prototype, OSIRIS (Observing System Including Polarization in the Solar Infrared Spectrum), is also presently developed at the Laboratoire d'Optique Atmospherique and had already participated to several measurements campaigns. In order to analyze suitably the measured signal, it it necessary to have realistic and accurate models able to simulate polarized reflectances. The 3DCLOUD model (Szczap et al., 2014) was used to generate three-dimensional synthetic cloud and the 3D radiative transfer model, 3DMCPOL (Cornet et al., 2010) to compute realistic polarized reflectances. From these simulations, we investigate the effects of 3D cloud structures and heterogeneity on the polarized angular signature often used to retrieve cloud or aerosol properties. We show that 3D effects are weak for flat clouds but become quite significant for fractional clouds above ocean. The 3D effects are quite different according to the observation scale. For the airborne scale (few tens of meter), solar illumination effects can lead to polarized cloud reflectance values higher than the saturation limit predicted by the homogeneous cloud assumption. In the cloud gaps, corresponding to shadowed areas of the total reflectances, polarized signal can also be enhanced

  7. Assay of 25-OH vitamin D3

    International Nuclear Information System (INIS)

    Nayer, P. de; Thalasso, M.; Beckers, C.

    1977-01-01

    A simplified version of the competitive protein binding assay for 25-OH vit D3 derived from the method of Belsey et al. is presented. The procedure does not include a chromatography step, and is performed on an alcoolic extract of 0.1 ml plasma or serum. Normal rat serum (1:20,000) was used as binding protein. No β-lipoproteins were added to the assay buffer. A 10% displacement of the tracer was observed at 0.04 ng/tube, and 50% at 0.15 ng/tube, allowing for the measurement of 25-OH vit D3 concentrations between 2 ng/ml and 200 ng/ml. Mean values in a normal group was 23.1 +- 6.5 ng/ml (range 16-37 ng/ml, n = 11). (orig.) [de

  8. A 3d-3d appetizer

    Energy Technology Data Exchange (ETDEWEB)

    Pei, Du; Ye, Ke [Walter Burke Institute for Theoretical Physics, California Institute of Technology, Pasadena, CA, 91125 (United States)

    2016-11-02

    We test the 3d-3d correspondence for theories that are labeled by Lens spaces. We find a full agreement between the index of the 3d N=2 “Lens space theory” T[L(p,1)] and the partition function of complex Chern-Simons theory on L(p,1). In particular, for p=1, we show how the familiar S{sup 3} partition function of Chern-Simons theory arises from the index of a free theory. For large p, we find that the index of T[L(p,1)] becomes a constant independent of p. In addition, we study T[L(p,1)] on the squashed three-sphere S{sub b}{sup 3}. This enables us to see clearly, at the level of partition function, to what extent G{sub ℂ} complex Chern-Simons theory can be thought of as two copies of Chern-Simons theory with compact gauge group G.

  9. Detection of Single Tree Stems in Forested Areas from High Density ALS Point Clouds Using 3d Shape Descriptors

    Science.gov (United States)

    Amiri, N.; Polewski, P.; Yao, W.; Krzystek, P.; Skidmore, A. K.

    2017-09-01

    Airborne Laser Scanning (ALS) is a widespread method for forest mapping and management purposes. While common ALS techniques provide valuable information about the forest canopy and intermediate layers, the point density near the ground may be poor due to dense overstory conditions. The current study highlights a new method for detecting stems of single trees in 3D point clouds obtained from high density ALS with a density of 300 points/m2. Compared to standard ALS data, due to lower flight height (150-200 m) this elevated point density leads to more laser reflections from tree stems. In this work, we propose a three-tiered method which works on the point, segment and object levels. First, for each point we calculate the likelihood that it belongs to a tree stem, derived from the radiometric and geometric features of its neighboring points. In the next step, we construct short stem segments based on high-probability stem points, and classify the segments by considering the distribution of points around them as well as their spatial orientation, which encodes the prior knowledge that trees are mainly vertically aligned due to gravity. Finally, we apply hierarchical clustering on the positively classified segments to obtain point sets corresponding to single stems, and perform ℓ1-based orthogonal distance regression to robustly fit lines through each stem point set. The ℓ1-based method is less sensitive to outliers compared to the least square approaches. From the fitted lines, the planimetric tree positions can then be derived. Experiments were performed on two plots from the Hochficht forest in Oberösterreich region located in Austria.We marked a total of 196 reference stems in the point clouds of both plots by visual interpretation. The evaluation of the automatically detected stems showed a classification precision of 0.86 and 0.85, respectively for Plot 1 and 2, with recall values of 0.7 and 0.67.

  10. Grain boundaries in Ni3Al. 2

    International Nuclear Information System (INIS)

    Kung, H.; Sass, S.L.

    1992-01-01

    This paper discusses the dislocation structure of small angle tilt and twist boundaries in ordered Ni 3 Al, with and without boron, investigated using transmission electron microscopy. Dislocation with Burgers vectors that correspond to anti-phase boundary (APB)-coupled superpartials were found in small angle twist boundaries in both boron-free and boron-doped Ni 3 Al, and a small angle tilt boundary in boron-doped Ni 3 Al. The boundary structures are in agreement with theoretical models proposed by Marcinkowski and co-workers. The APB energy determined from the dissociation of the grain boundary dislocations was lower than values reported for isolated APBs in Ni 3 Al. For small angle twist boundaries the presence of boron reduced the APB energy at the interface until it approached zero. This is consistent with the structure of these boundaries containing small regions of increased compositional disorder in the first atomic plane next to the interface

  11. Comparison the Antibacterial Activity of Vitamin D2 and D3

    Directory of Open Access Journals (Sweden)

    Intesar N. Khelkal

    2017-03-01

    Full Text Available An attempt has been made to determine the antimicrobial activity of vitamin D; D3 & D2 against clinical bacterial isolates as well as perform a comparative analytical study between the effects of both forms of vitamin. The ability of vitamin D (both D2 ergocalciferol& D3 cholecalciferol  to  inhibit bacterial growth of some clinical isolates have been tested . Forty - three pathogenic bacterial isolates (Gr+ ,Gr- have been identified  from fifty - five specimen  was collected from  different sources ; 24 urine, 17 sputum , 9 blood , 5 skin at Al-Kindey hospital for a period of two months . Antibiotic sensitivity was carried out towards 12 different antibiotic discs. The most resistant isolates have been chosen to be tested in the study. Two bacterial suspensions of the selected isolates have been prepared; the first was adjusted to McFarland standard No. 0.5 (1 ×10 8 CFU /mL; the second = 1×1010 CFU /mL. Three concentrations of both vitamins have been prepared; 50,000, 70,000 and 90,000 IU/mL as well as the control ( solvent only . Antibacterial activity has been examined by using agar diffusion (pore plating method to determine the most effective concentration among the three concentrations of the two forms of vitamin D. Results were suggesting the important role of vitamin D specially D3 as antibacterial agent .The third concentration (90,000 IU/mL was causing the largest inhibition zone with all tested isolates even with the high turbidity culture (1010CFU/mL ,followed by the second one (70,000 IU/mL, the lower inhibitor concentration was (50,000 IU/mL. Significant differences have been appeared among the measurements of the diameters of inhibition zones towards three vitamin concentrations when compared one to another and to control.

  12. The accuracy of a 2D and 3D dendritic tip scaling parameter in predicting the columnar to equiaxed transition (CET)

    Science.gov (United States)

    Seredyński, M.; Rebow, M.; Banaszek, J.

    2016-09-01

    The dendrite tip kinetics model accuracy relies on the reliability of the stability constant used, which is usually experimentally determined for 3D situations and applied to 2D models. The paper reports authors' attempts to cure the situation by deriving 2D dendritic tip scaling parameter for aluminium-based alloy: Al-4wt%Cu. The obtained parameter is then incorporated into the KGT dendritic growth model in order to compare it with the original 3D KGT counterpart and to derive two-dimensional and three-dimensional versions of the modified Hunt's analytical model for the columnar-to-equiaxed transition (CET). The conclusions drawn from the above analysis are further confirmed through numerical calculations of the two cases of Al-4wt%Cu metallic alloy solidification using the front tracking technique. Results, including the porous zone-under-cooled liquid front position, the calculated solutal under-cooling and a new predictor of the relative tendency to form an equiaxed zone, are shown, compared and discussed two numerical cases. The necessity to calculate sufficiently precise values of the tip scaling parameter in 2D and 3D is stressed.

  13. A study on preparation and hydriding of β-Mg2Al3 and γ-Mg17Al12

    International Nuclear Information System (INIS)

    Hadi Suwarno

    2009-01-01

    The mechanism of the synthetic formation of β-Mg 2 Al 3 and γ-Mg 17 Al 12 has been studied. Mechanical alloying of Mg and Al powders with the atomic ratio of Mg:Al = 2:3 in toluene solution yields β-Mg 2 Al 3 compound after milling for 30 h. The γ-Mg 17 Al 12 can be formed by heating the β-Mg 2 Al 3 at 430°C under high vacuum. The measured hydrogen capacities of β-Mg 2 Al 3 and γ-Mg 17 Al 12 as hydride at 300°C are 3.2 and 4.9 wt%, respectively. Microstructure of the Mg-Al specimen shows that on hydriding at 300°C the polygonal shape of the γ-Mg 17 Al 12 changes into irregular shapes which are composed of γ-MgH 2 and Al. (author)

  14. 3D Printing Meets Astrophysics: A New Way to Visualize and Communicate Science

    Science.gov (United States)

    Madura, Thomas Ignatius; Steffen, Wolfgang; Clementel, Nicola; Gull, Theodore R.

    2015-08-01

    3D printing has the potential to improve the astronomy community’s ability to visualize, understand, interpret, and communicate important scientific results. I summarize recent efforts to use 3D printing to understand in detail the 3D structure of a complex astrophysical system, the supermassive binary star Eta Carinae and its surrounding bipolar ‘Homunculus’ nebula. Using mapping observations of molecular hydrogen line emission obtained with the ESO Very Large Telescope, we obtained a full 3D model of the Homunculus, allowing us to 3D print, for the first time, a detailed replica of a nebula (Steffen et al. 2014, MNRAS, 442, 3316). I also present 3D prints of output from supercomputer simulations of the colliding stellar winds in the highly eccentric binary located near the center of the Homunculus (Madura et al. 2015, arXiv:1503.00716). These 3D prints, the first of their kind, reveal previously unknown ‘finger-like’ structures at orbital phases shortly after periastron (when the two stars are closest to each other) that protrude outward from the spiral wind-wind collision region. The results of both efforts have received significant media attention in recent months, including two NASA press releases (http://www.nasa.gov/content/goddard/astronomers-bring-the-third-dimension-to-a-doomed-stars-outburst/ and http://www.nasa.gov/content/goddard/nasa-observatories-take-an-unprecedented-look-into-superstar-eta-carinae/), demonstrating the potential of using 3D printing for astronomy outreach and education. Perhaps more importantly, 3D printing makes it possible to bring the wonders of astronomy to new, often neglected, audiences, i.e. the blind and visually impaired.

  15. IMRT vs. 2D-radiotherapy or 3D-conformal radiotherapy of nasopharyngeal carcinoma. Survival outcome in a Korean multi-institutional retrospective study (KROG 11-06)

    Energy Technology Data Exchange (ETDEWEB)

    Moon, Sung Ho; Cho, Kwan Ho [Proton Therapy Center, Research Institute and Hospital, National Cancer Center, Ilsandong-gu, Goyang-si Gyeonggi-do (Korea, Republic of); Lee, Chang-Geol; Keum, Ki Chang [Yonsei University College of Medicine, Department of Radiation Oncology, Seodaemun-gu, Seoul (Korea, Republic of); Kim, Yeon-Sil [Seoul St. Mary' s Hospital, College of Medicine, the Catholic University of Korea, Department of Radiation Oncology, Seocho-gu, Seoul (Korea, Republic of); Wu, Hong-Gyun; Kim, Jin Ho [Seoul National University College of Medicine, Department of Radiation Oncology, Jongno-gu, Seoul (Korea, Republic of); Ahn, Yong Chan; Oh, Dongryul [Samsung Medical Center, Sungkyunkwan University School of Medicine, Department of Radiation Oncology, Gangnam-gu, Seoul (Korea, Republic of); Lee, Jong Hoon [The Catholic University of Korea, College of Medicine, Department of Radiation Oncology, Paldal-gu, Suwon, Gyeonggi-do (Korea, Republic of)

    2016-06-15

    We compared treatment outcomes of two-dimensional radiotherapy (2D-RT), three-dimensional conformal radiotherapy (3D-CRT), and intensity-modulated radiotherapy (IMRT) in patients with nasopharyngeal carcinoma (NPC). In total, 1237 patients with cT1-4N0-3M0 NPC were retrospectively analyzed. Of these, 350, 390, and 497 were treated with 2D-RT, 3D-CRT, and IMRT, respectively. 3D-CRT and IMRT showed better 5-year overall survival (OS) rates (73.6 and 76.7 %, respectively) than did 2D-RT (5-year OS of 59.7 %, all p < 0.001). In T3-4 subgroup, IMRT was associated with a significantly better 5-year OS than was 2D-RT (70.7 vs. 50.4 %, respectively; p ≤ 0.001) and 3D-CRT (70.7 vs. 57.8 %, respectively; p = 0.011); however, the difference between the 2D-RT and 3D-CRT groups did not reach statistical significance (p = 0.063). In multivariate analyses of all patients, IMRT was a predictive factor for OS when compared with 2D-RT or 3D-CRT, as was 3D-CRT when compared with 2D-RT. Our study showed that 3D-CRT and IMRT were associated with a better local progression-free survival and OS than was 2D-RT in NPC. IMRT was significantly superior in terms of OS for advanced primary tumors (T3-4). (orig.) [German] Wir verglichen die Behandlungsergebnisse von zweidimensionaler Strahlentherapie (2D-RT), dreidimensionaler konformer Strahlentherapie (3D-CRT) und intensitaetsmodulierter Strahlentherapie (IMRT) bei Patienten mit Nasopharynxkarzinom (NPC). Insgesamt 1237 Patienten mit NPC im Stadium cT1-4/N0-3/M0 wurden rueckwirkend analysiert. Von diesen wurden jeweils 350, 390 und 497 mit 2D-RT, 3D-CRT und IMRT behandelt. 3D-CRT und IMRT zeigten eine bessere 5-Jahres-Gesamtueberlebensrate (5y-OS; jeweils 73,6 und 76,7%) als 2D-RT (59,7%; alle p < 0,001). In der Untergruppe T3-4 war die IMRT mit einer erheblich besseren 5y-OS verbunden als 2D-RT (jeweils 70,7 vs. 50,4%; p ≤ 0,001) und 3D-CRT (jeweils 70,7 vs. 57,8%; p = 0,011); jedoch gab es keinen Unterschied zwischen den Gruppen 2D

  16. Quasi 3D dosimetry (EPID, conventional 2D/3D detector matrices)

    International Nuclear Information System (INIS)

    Bäck, A

    2015-01-01

    Patient specific pretreatment measurement for IMRT and VMAT QA should preferably give information with a high resolution in 3D. The ability to distinguish complex treatment plans, i.e. treatment plans with a difference between measured and calculated dose distributions that exceeds a specified tolerance, puts high demands on the dosimetry system used for the pretreatment measurements and the results of the measurement evaluation needs a clinical interpretation. There are a number of commercial dosimetry systems designed for pretreatment IMRT QA measurements. 2D arrays such as MapCHECK ® (Sun Nuclear), MatriXX Evolution (IBA Dosimetry) and OCTAVIOUS ® 1500 (PTW), 3D phantoms such as OCTAVIUS ® 4D (PTW), ArcCHECK ® (Sun Nuclear) and Delta 4 (ScandiDos) and software for EPID dosimetry and 3D reconstruction of the dose in the patient geometry such as EPIDose TM (Sun Nuclear) and Dosimetry Check TM (Math Resolutions) are available. None of those dosimetry systems can measure the 3D dose distribution with a high resolution (full 3D dose distribution). Those systems can be called quasi 3D dosimetry systems. To be able to estimate the delivered dose in full 3D the user is dependent on a calculation algorithm in the software of the dosimetry system. All the vendors of the dosimetry systems mentioned above provide calculation algorithms to reconstruct a full 3D dose in the patient geometry. This enables analyzes of the difference between measured and calculated dose distributions in DVHs of the structures of clinical interest which facilitates the clinical interpretation and is a promising tool to be used for pretreatment IMRT QA measurements. However, independent validation studies on the accuracy of those algorithms are scarce. Pretreatment IMRT QA using the quasi 3D dosimetry systems mentioned above rely on both measurement uncertainty and accuracy of calculation algorithms. In this article, these quasi 3D dosimetry systems and their use in patient specific

  17. Electronic transport in the heavy fermion superconductors UPd{sub 2}Al{sub 3} and UNi{sub 2}Al{sub 3}. Thin film studies

    Energy Technology Data Exchange (ETDEWEB)

    Foerster, Michael

    2008-07-01

    This work addresses the electronical properties of the superconductors UPd{sub 2}Al{sub 3} and UNi{sub 2}Al{sub 3} on the basis of thin film experiments. Epitaxial thin film samples of UPd{sub 2}Al{sub 3} and UNi{sub 2}Al{sub 3} were prepared using UHV Molecular Beam Epitaxy (MBE). For UPd{sub 2}Al{sub 3}, the change of the growth direction from the intrinsic (001) to epitaxial (100) was predicted and sucessfully demonstrated using LaAlO3 substrates cut in (110) direction. With optimized deposition process parameters for UPd{sub 2}Al{sub 3} (100) on LaAlO{sub 3}(110) superconducting samples with critical temperatures up to T{sub c}=1.75 K were obtained. UPd{sub 2}Al{sub 3}-AlO{sub x}-Ag mesa junctions with superconducting base electrode were prepared and shown to be in the tunneling regime. However, no signatures of a superconducting density of states were observed in the tunneling spectra. The resistive superconducting transition was probed for a possible dependence on the current direction. In contrast to UNi{sub 2}Al{sub 3}, the existence of such feature was excluded in UPd{sub 2}Al{sub 3}(100) thin films. The second focus of this work is the dependence of the resistive transition in UNi{sub 2}Al{sub 3}(100) thin films on the current direction. The experimental fact that the resistive transition occurs at slightly higher temperatures for I parallel a than for I parallel c can be explained within a model of two weakly coupled superconducting bands. Evidence is presented for the key assumption of the two-band model, namely that transport in and out of the ab-plane is generated on different, weakly coupled parts of the Fermi surface. Main indications are the angle dependence of the superconducting transition and the dependence of the upper critical field B{sub c{sub 2}} on current and field orientation. Additionally, several possible alternative explanations for the directional splitting of the transition are excluded in this work. An origin due to scattering on

  18. Energies of Electronic States of Ni (II) Ion in NiO-Al2O3 Catalyst Prepared by Impregnation

    International Nuclear Information System (INIS)

    Obadovic, D. Z.; Kiurski, J.; Marinkovic-Neducin, R. P.

    2007-01-01

    The behavior of NiO-Al2O3 catalysts is strongly dependent on the preparation method, as well as on pretreatment conditions. In the present work we investigated the influences of Ni(II) ion on NiO-Al2O3 catalysts properties due to the preparation by impregnation method. Based on experimental diffuse reflectance spectroscopy (DRS) data of electronic d-d transitions of Ni (II) promoter ion the energies of electronic states in spinel-like structure were calculated, and the most probable scheme of molecular orbital have been proposed

  19. Micromechanisms of fracture and fatigue in Ti3Al based and TiAl based intermetallics

    International Nuclear Information System (INIS)

    James, A.W.; Chave, R.A.; Hippsley, C.A.; Bowen, P.

    1993-01-01

    Micromechanisms of fracture and fatigue crack growth resistance in specific Ti 3 Al based and TiAl based intermetallics are reviewed. Effects of test temperature, environment and microstructure on crack growth resistance are considered in detail for several Ti 3 Al and Ti'Al based intermetallic systems under development. The implications of these studies for the structural reliability of these materials is also addressed briefly. (orig.)

  20. Preparation and Properties of 3D Printed Alginate–Chitosan Polyion Complex Hydrogels for Tissue Engineering

    Directory of Open Access Journals (Sweden)

    Qiongqiong Liu

    2018-06-01

    Full Text Available Three-dimensional (3D printing holds great potential for preparing sophisticated scaffolds for tissue engineering. As a result of the shear thinning properties of an alginate solution, it is often used as 3D printing ink. However, it is difficult to prepare scaffolds with complexity structure and high fidelity, because the alginate solution has a low viscosity and alginate hydrogels prepared with Ca2+ crosslinking are mechanically weak. In this work, chitosan powders were dispersed and swelled in an alginate solution, which could effectively improve the viscosity of an alginate solution by 1.5–4 times. With the increase of chitosan content, the shape fidelity of the 3D printed alginate–chitosan polyion complex (AlCh PIC hydrogels were improved. Scanning electron microscope (SEM photographs showed that the lateral pore structure of 3D printed hydrogels was becoming more obvious. As a result of the increased reaction ion pairs in comparison to the alginate hydrogels that were prepared with Ca2+ crosslinking, AlCh PIC hydrogels were mechanically strong, and the compression stress of hydrogels at a 90% strain could achieve 1.4 MPa without breaking. In addition, human adipose derived stem cells (hASCs adhered to the 3D printed AlCh PIC hydrogels and proliferated with time, which indicated that the obtained hydrogels were biocompatible and could potentially be used as scaffolds for tissue engineering.

  1. Effective bending strain estimated from I c test results of a D-shaped Nb3Al CICC coil fabricated with a react-and-wind process for the National Centralized Tokamak

    International Nuclear Information System (INIS)

    Ando, T.; Kizu, K.; Miura, Y.M.; Tsuchiya, K.; Matsukawa, M.; Tamai, H.; Ishida, S.; Koizumi, N.; Okuno, K.

    2005-01-01

    Japan National Centralized Tokamak (NCT) is a superconducting tokamak proposed as a modification to JT-60U. As part of the R and D for the National Centralized Tokamak, a two-turn, approximately 2 m tall, D-shaped Nb 3 Al coil was wound and tested using a full-size cable-in-conduit conductor (CICC). The Nb 3 Al cable-in-conductor was bent following the heat treatment reaction with a maximum bending strain of 0.4% to simulate the react-and-wind fabrication. The comparison of the coil performance to the measured strand data shows that the effective axial strain of the conductor strands is essentially zero despite the 0.4% bending strain of the conductor. This suggests that the strands in the cable slipped relatively to each other during bending of the conduit, thus reducing the effective strain transmitted to the strands. This result is very encouraging for the low-cost fabrication of high-current-density fusion coils using the react-and-wind method

  2. Wear Behavior of Cold Pressed and Sintered Al2O3/TiC/CaF2Al2O3/TiC Laminated Ceramic Composite

    Institute of Scientific and Technical Information of China (English)

    Xuefeng YANG; Jian CHENG; Peilong SONG; Shouren WANG; Liying YANG; Yanjun WANG; Ken MAO

    2013-01-01

    A novel laminated Al2O3/TiC/CaF2-Al2O3/TiC sandwich ceramic composite was fabricated through cold pressing and sintering to achieve better anti-wear performance,such as low friction coefficient and low wear rate.Al2O3/TiC/CaF2 and Al2O3/TiC composites were alternatively built layer-by-layer to obtain a sandwich structure.Solid lubricant CaF2 was added evenly into the Al2O3/TiC/CaF2 layer to reduce the friction and wear.Al2O3/TiC ceramic was also cold pressed and sintered for comparison.Friction analysis of the two ceramics was then conducted via a wear-and-tear machine.Worn surface and surface compositions were examined by scanning electron microscopy and energy dispersion spectrum,respectively.Results showed that the laminated Al2O3/TiC/CaF2-Al2O3/TiC sandwich ceramic composite has lower friction coefficient and lower wear rate than those of Al2O3/TiC ceramic alone because of the addition of CaF2 into the laminated Al2O3/TiC/CaF2-Al2O3/TiC sandwich ceramic composite.Under the friction load,the tiny CaF2 particles were scraped from the Al2O3/TiC/CaF2 layer and spread on friction pairs before falling off into micropits.This process formed a smooth,self-lubricating film,which led to better anti-wear properties.Adhesive wear is the main wear mechanism of Al2O3/TiC/CaF2 layer and abrasive wear is the main wear mechanism of Al2O3/TiC layer.

  3. Atomistic simulations of diffusion mechanisms in off-stoichiometric Al-rich Ni3Al

    International Nuclear Information System (INIS)

    Duan, Jinsong

    2007-01-01

    This paper presents dynamics simulation results of diffusion in off-stoichiometric Al-rich Ni 3 Al (Ni 73 Al 27 ) at temperature ranging from 1300 to 1550 K. The interatomic forces are described by the Finnis-Sinclair type N-body potentials. Particular attention is devoted to the effect of the extra 2% of Al atoms sitting on the Ni sublattice as antisite point defects (Al Ni ) on diffusion. Simulation results show that Ni atoms mainly diffuse through the Ni sublattice at the temperatures investigated. Al atoms diffuse via both the intrasublattice and antistructure bridge (ASB) mechanisms. The contribution to Al diffusion from the ASB mechanism decreases at the lower temperature (T Ni ) enhances both Al and Ni diffusion in Ni 73 Al 27 . The Ni-Al coupled diffusion effect is observed and understood at the atomic level for the first time

  4. Anion exchange removal of Al3+ from Li+-Al3+ aqueous solution (originating from lithium recovery from brine

    Directory of Open Access Journals (Sweden)

    Anissa Somrani

    2014-06-01

    Full Text Available The purpose of this study is to separate aluminum(III ion from an aqueous solution containing Li+ at 25°C. Al3+ was transferred into [Al(C2O43]3- by means of complexation and removed by an anion exchange resin. This resin was anionic type Amberlite IRA 402 regenerated by sodium chloride. Hence, a theoretical study based on speciation diagrams was carried out to determine the best pH domain for separation. The complexation of aluminum ions by ammonium oxalate was studied. The motar ratio of Ox/Al and pH was investigated. Optimum values of these factors were found to be 3 and 4 respectively. In this case, the remaining lithium is 98.5%.

  5. 3D MR cisternography to identify distal dural rings. Comparison of 3D-CISS and 3D-SPACE sequences

    International Nuclear Information System (INIS)

    Watanabe, Yoshiyuki; Makidono, Akari; Nakamura, Miho; Saida, Yukihisa

    2011-01-01

    The distal dural ring (DDR) is an anatomical landmark used to distinguish intra- and extradural aneurysms. We investigated identification of the DDR using 2 three-dimensional (3D) magnetic resonance (MR) cisternography sequences-3D constructive interference in steady state (CISS) and 3D sampling perfection with application optimized contrasts using different flip angle evolutions (SPACE)-at 3.0 tesla. Ten healthy adult volunteers underwent imaging with 3D-CISS, 3D-SPACE, and time-of-flight (TOF) MR angiography (TOF-MRA) sequences at 3.0T. We analyzed DDR identification and internal carotid artery (ICA) signal intensity and classified the shape of the carotid cave. We identified the DDR using both 3D-SPACE and 3D-CISS, with no significant difference between the sequences. Visualization of the outline of the ICA in the cavernous sinus (CS) was significantly clearer with 3D-SPACE than 3D-CISS. In the CS and petrous portions, signal intensity was lower with 3D-SPACE, and the flow void was poor with 3D-CISS in some subjects. We identified the DDR with both 3D-SPACE and 3D-CISS, but the superior contrast of the ICA in the CS using 3D-SPACE suggests the superiority of this sequence for evaluating the DDR. (author)

  6. Interaction between Al3+ and acrylic acid and polyacrylic acid in acidic aqueous solution: a model experiment for the behavior of Al3+ in acidified soil solution.

    Science.gov (United States)

    Etou, Mayumi; Masaki, Yuka; Tsuji, Yutaka; Saito, Tomoyuki; Bai, Shuqin; Nishida, Ikuko; Okaue, Yoshihiro; Yokoyama, Takushi

    2011-01-01

    From the viewpoint of the phytotoxicity and mobility of Al(3+) released from soil minerals due to soil acidification, the interaction between Al(3+) and acrylic acid (AA) and polyacrylic acid (PAA) as a model compound of fulvic acid was investigated. The interaction was examined at pH 3 so as to avoid the hydrolysis of Al(3+). The interaction between Al(3+) and AA was weak. However, the interaction between Al(3+) and PAA was strong and depended on the initial (COOH in PAA)/Al molar ratio (R(P)) of the solution. For the range of 1/R(P), the interaction between Al(3+) and PAA can be divided into three categories: (1) 1:1 Al-PAA-complex (an Al(3+) combines to a carboxyl group), (2) intermolecular Al-PAA-complex (an Al(3+) combines to more than 2 carboxyl groups of other Al-PAA-complexes) in addition to the 1:1 Al-PAA-complex and (3) precipitation of intermolecular complexes. In conclusion, R(P) is an important factor affecting the behavior of Al(3+) in acidic soil solution.

  7. 3D video

    CERN Document Server

    Lucas, Laurent; Loscos, Céline

    2013-01-01

    While 3D vision has existed for many years, the use of 3D cameras and video-based modeling by the film industry has induced an explosion of interest for 3D acquisition technology, 3D content and 3D displays. As such, 3D video has become one of the new technology trends of this century.The chapters in this book cover a large spectrum of areas connected to 3D video, which are presented both theoretically and technologically, while taking into account both physiological and perceptual aspects. Stepping away from traditional 3D vision, the authors, all currently involved in these areas, provide th

  8. 2.5D real waveform and real noise simulation of receiver functions in 3D models

    DEFF Research Database (Denmark)

    Schiffer, Christian; Jacobsen, B. H.; Balling, N.

    to the Central Fjord area in East Greenland (Schiffer et al., 2013), where a 3D velocity model of crust and uppermost mantle was adjusted to receiver functions from 2 years of seismometer recordings and wide angle crustal profiles (Schlindwein and Jokat, 1999; Voss and Jokat, 2007). Computationally...

  9. In situ synthesis of Ti{sub 2}AlC–Al{sub 2}O{sub 3}/TiAl composite by vacuum sintering mechanically alloyed TiAl powder coated with CNTs

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jian [Department of Materials Science and Engineering of Tianjin University, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin 300072 (China); Zhao, Naiqin, E-mail: nqzhao@tju.edu.cn [State Key Laboratory of Hydraulic Engineering Simulation and Safety, Tianjin (China); Department of Materials Science and Engineering of Tianjin University, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin 300072 (China); Nash, Philip [Thermal Processing Technology Center, Illinois Institute of Technology, IL (United States); Liu, Enzuo; He, Chunnian; Shi, Chunsheng; Li, Jiajun [Department of Materials Science and Engineering of Tianjin University, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin 300072 (China)

    2013-11-25

    Highlights: •Using zwitterionic surfactant to enhance the dispersion of the CNTs on the powder surface. •CNTs as carbon source decreased the formation temperature of Ti{sub 2}AlC. •Al{sub 2}O{sub 3} was generated in situ from the oxygen atoms introduced in the drying procedure. •Nanosized Ti{sub 3}Al was precipitated at 1250 °C and distribute in the TiAl matrix homogeneously. •Ti{sub 2}AlC–Al{sub 2}O{sub 3}/TiAl composite was synthesized in situ by sintering pre-alloy Ti–Al coated with CNTs. -- Abstract: Bulk Ti{sub 2}AlC–Al{sub 2}O{sub 3}/TiAl composites were in situ synthesized by vacuum sintering mechanically alloyed Ti–50 at.% Al powders coated with carbon nanotubes (CNTs). The pre-alloyed Ti–50 at.% Al powder was obtained by ball milling Ti and Al powders. The multi-walled carbon nanotubes as the carbon resource were covered on the surface of the pre-alloyed powders by immersing them into a water solution containing the CNTs. A zwitterionic surfactant was used to enhance the dispersion of the CNTs on the powder surface. The samples were cold pressed and sintered in vacuum at temperatures from 950 to 1250 °C, respectively. The results show that the reaction of forming Ti{sub 2}AlC can be achieved below 950 °C, which is 150 °C lower than in the Ti–Al–TiC system and 250 °C lower than for the Ti–Al–C system due to the addition of CNTs. Additionally, the reinforcement of Al{sub 2}O{sub 3} particles was introduced in situ in Ti{sub 2}AlC/TiAl by the drying process and subsequent sintering of the composite powders. Dense Ti{sub 2}AlC–Al{sub 2}O{sub 3}/TiAl composites were obtained by sintering at 1250 °C and exhibited a homogeneous distribution of Ti{sub 2}AlC, Al{sub 2}O{sub 3} and precipitated Ti{sub 3}Al particles and a resulting high hardness.

  10. Nb and Ta layer doping effects on the interfacial energetics and electronic properties of LaAlO3/SrTiO3 heterostructure: first-principles analysis.

    Science.gov (United States)

    Nazir, Safdar; Behtash, Maziar; Cheng, Jianli; Luo, Jian; Yang, Kesong

    2016-01-28

    The two-dimensional electron gas (2DEG) formed at the n-type (LaO)(+1)/(TiO2)(0) interface in the polar/nonpolar LaAlO3/SrTiO3 (LAO/STO) heterostructure (HS) has emerged as a prominent research area because of its great potential for nanoelectronic applications. Due to its practical implementation in devices, desired physical properties such as high charge carrier density and mobility are vital. In this respect, 4d and 5d transition metal doping near the interfacial region is expected to tailor electronic properties of the LAO/STO HS system effectively. Herein, we studied Nb and Ta-doping effects on the energetics, electronic structure, interfacial charge carrier density, magnetic moment, and the charge confinements of the 2DEG at the n-type (LaO)(+1)/(TiO2)(0) interface of LAO/STO HS using first-principles density functional theory calculations. We found that the substitutional doping of Nb(Ta) at Ti [Nb(Ta)@Ti] and Al [Nb(Ta)@Al] sites is energetically more favorable than that at La [Nb(Ta)@La] and Sr [Nb(Ta)@Sr] sites, and under appropriate thermodynamic conditions, the changes in the interfacial energy of HS systems upon Nb(Ta)@Ti and Nb(Ta)@Al doping are negative, implying that the formation of these structures is energetically favored. Our calculations also showed that Nb(Ta)@Ti and Nb(Ta)@Al doping significantly improve the interfacial charge carrier density with respect to that of the undoped system, which is because the Nb(Ta) dopant introduces excess free electrons into the system, and these free electrons reside mainly on the Nb(Ta) ions and interfacial Ti ions. Hence, along with the Ti 3d orbitals, the Nb 4d and Ta 5d orbitals also contribute to the interfacial metallic states; accordingly, the magnetic moments on the interfacial Ti ions increase significantly. As expected, the Nb@Al and Ta@Al doped LAO/STO HS systems show higher interfacial charge carrier density than the undoped and other doped systems. In contrast, Nb@Ti and Ta@Ti doped systems may

  11. 3D composite image, 3D MRI, 3D SPECT, hydrocephalus

    International Nuclear Information System (INIS)

    Mito, T.; Shibata, I.; Sugo, N.; Takano, M.; Takahashi, H.

    2002-01-01

    The three-dimensional (3D)SPECT imaging technique we have studied and published for the past several years is an analytical tool that permits visual expression of the cerebral circulation profile in various cerebral diseases. The greatest drawback of SPECT is that the limitation on precision of spacial resolution makes intracranial localization impossible. In 3D SPECT imaging, intracranial volume and morphology may vary with the threshold established. To solve this problem, we have produced complimentarily combined SPECT and helical-CT 3D images by means of general-purpose visualization software for intracranial localization. In hydrocephalus, however, the key subject to be studied is the profile of cerebral circulation around the ventricles of the brain. This suggests that, for displaying the cerebral ventricles in three dimensions, CT is a difficult technique whereas MRI is more useful. For this reason, we attempted to establish the profile of cerebral circulation around the cerebral ventricles by the production of combined 3D images of SPECT and MRI. In patients who had shunt surgery for hydrocephalus, a difference between pre- and postoperative cerebral circulation profiles was assessed by a voxel distribution curve, 3D SPECT images, and combined 3D SPECT and MRI images. As the shunt system in this study, an Orbis-Sigma valve of the automatic cerebrospinal fluid volume adjustment type was used in place of the variable pressure type Medos valve currently in use, because this device requires frequent changes in pressure and a change in pressure may be detected after MRI procedure. The SPECT apparatus used was PRISM3000 of the three-detector type, and 123I-IMP was used as the radionuclide in a dose of 222 MBq. MRI data were collected with an MAGNEXa+2 with a magnetic flux density of 0.5 tesla under the following conditions: field echo; TR 50 msec; TE, 10 msec; flip, 30ueK; 1 NEX; FOV, 23 cm; 1-mm slices; and gapless. 3D images are produced on the workstation TITAN

  12. Emisión Acústica y Redes Neuronales para Modelado y Caracterización del Proceso de Soldadura por Fricción Agitación

    Directory of Open Access Journals (Sweden)

    Emilio Jiménez Macías

    2013-10-01

    Full Text Available Resumen: En esta investigación se realiza un análisis para el modelado y la caracterización de los parámetros del proceso de soldadura por fricción agitación (FSW a partir de las señales vibro-acústicas generadas por el proceso. El modelo se basa en una red neuronal empleada para predecir los parámetros del proceso de soldadura a partir de la medición on-line de las señales generadas durante su ejecución. En los ensayos se han soldado chapas de aluminio AA1050 H24 con 3 mm de espesor, y las señales del proceso de soldadura han sido adquiridas empleando un sistema de adquisición NI USB-9234. Como entradas para el modelo basado en la Red Neuronal Artificial (RNA se han empleado parámetros de caracterización de las señales a partir de la señal temporal y su descomposición a partir de la aplicación de Transformada Wavelet. Como salidas del modelo se han escogido los parámetros del proceso: velocidad de rotación, avance y diseño de la herramienta. Se ha empleado una red multicapas feed-forward, estudiándose diferentes topologías y algoritmos de entrenamiento. Los resultados obtenidos a partir de la comparación de los datos experimentales y los estimados por la RNA, demuestran la validez del modelo obtenido a partir de las investigaciones, el cual abre la puerta a avances en el control automático de los parámetros del proceso a partir de las señales vibro-acústicas, como línea natural de continuidad para futuras investigaciones. Abstract: This paper presents an analysis of the correlation between acoustic emission (AE signals and the main parameters of friction stir welding (FSW process, based on artificial neural networks (ANN. The AE signals have been acquired by the data acquisition instrument NI USB-9234, applied during the welding process carried out on plates of 3 mm thick of aluminium AA1050 alloy. Statistical and temporal parameters of discomposed EA signals using Wavelet Transform (WT have been used as input

  13. Design of high-temperature high-strength Al-Ti-V-Zr alloys

    International Nuclear Information System (INIS)

    Lee, H.M.

    1990-01-01

    This paper reports that it seems plausible to develop high-strength Al-base alloys useful up to 698K in view of the behavior of nickel base superalloys which resist degradation of mechanical properties to 75 pct of their absolute melting temperature. For high temperature Al alloys, the dispersed hardening phase must not undergo phase transformation to an undesirable phase during long time exposure at the temperature of interest. An additional factor to be considered is the stability of the hardening phase with respect to Ostwald ripening. This coarsening resistance is necessary so that the required strength level can be maintained after the long-time service at high temperatures. The equilibrium crystal structures of Al 3 Ti, Al 3 V and Al 3 Zr are tetragonal D0 22 , D0 22 and D0 23 , respectively. At the temperatures of interest, around 698K, vanadium and titanium are mutually substitutable in the form of Al 3 (Ti, V). Much of titanium and vanadium can be substituted for zirconium in the D0 23 - type Al 3 Zr compound, creating Al 3 (Ti, Zr) and Al 3 (V, Zr), respectively. In particular, it has been reported that fcc L1 2 -structured Al 3 M dispersoids form in the rapidly solidified Al-V-Zr and Al-Ti-Zr systems and both L1 2 and D0 23 -structured Al 3 M phases showed slow coarsening kinetics

  14. First-principles molecular dynamics study of Al/Alq3 interfaces

    Directory of Open Access Journals (Sweden)

    Kousuke Takeuchi et al

    2007-01-01

    Full Text Available We have carried out first-principles molecular dynamics simulations of Al deposition on tris (8-hydroxyquinoline aluminum (Alq3 layers to investigate atomic geometries and electronic properties of Al/Alq3 interfaces. Al atoms were ejected to Alq3 one by one with the kinetic energy of 37.4 kJ/mol, which approximately corresponds to the average kinetic energy of Al at the boiling temperature of metal Al. The first Al atom interacts with two of the three O atoms of meridional Alq3. Following Al atoms interact with Alq3 rather weakly and they tend to aggregate each other to form Al clusters. During the deposition process, Alq3 was not broken and its molecular structure remained essentially intact. At the interface, weak bonds between deposited Al atoms and N and C atoms were formed. The projected density of states (PDOS onto the Alq3 molecular orbitals shows gap states in between the highest occupied molecular orbitals (HOMOs and the lowest unoccupied molecular orbitals (LUMOs, which were experimentally observed by ultraviolet photoelectron spectroscopy (UPS and metastable atom electron spectroscopy (MAES. Our results show that even though the Alq3 molecular structure is retained, weak N–Al and C–Al bonds induce gap states.

  15. 3D Printing and 3D Bioprinting in Pediatrics.

    Science.gov (United States)

    Vijayavenkataraman, Sanjairaj; Fuh, Jerry Y H; Lu, Wen Feng

    2017-07-13

    Additive manufacturing, commonly referred to as 3D printing, is a technology that builds three-dimensional structures and components layer by layer. Bioprinting is the use of 3D printing technology to fabricate tissue constructs for regenerative medicine from cell-laden bio-inks. 3D printing and bioprinting have huge potential in revolutionizing the field of tissue engineering and regenerative medicine. This paper reviews the application of 3D printing and bioprinting in the field of pediatrics.

  16. 3D Printing and 3D Bioprinting in Pediatrics

    OpenAIRE

    Vijayavenkataraman, Sanjairaj; Fuh, Jerry Y H; Lu, Wen Feng

    2017-01-01

    Additive manufacturing, commonly referred to as 3D printing, is a technology that builds three-dimensional structures and components layer by layer. Bioprinting is the use of 3D printing technology to fabricate tissue constructs for regenerative medicine from cell-laden bio-inks. 3D printing and bioprinting have huge potential in revolutionizing the field of tissue engineering and regenerative medicine. This paper reviews the application of 3D printing and bioprinting in the field of pediatrics.

  17. A microfluidic device for 2D to 3D and 3D to 3D cell navigation

    International Nuclear Information System (INIS)

    Shamloo, Amir; Amirifar, Leyla

    2016-01-01

    Microfluidic devices have received wide attention and shown great potential in the field of tissue engineering and regenerative medicine. Investigating cell response to various stimulations is much more accurate and comprehensive with the aid of microfluidic devices. In this study, we introduced a microfluidic device by which the matrix density as a mechanical property and the concentration profile of a biochemical factor as a chemical property could be altered. Our microfluidic device has a cell tank and a cell culture chamber to mimic both 2D to 3D and 3D to 3D migration of three types of cells. Fluid shear stress is negligible on the cells and a stable concentration gradient can be obtained by diffusion. The device was designed by a numerical simulation so that the uniformity of the concentration gradients throughout the cell culture chamber was obtained. Adult neural cells were cultured within this device and they showed different branching and axonal navigation phenotypes within varying nerve growth factor (NGF) concentration profiles. Neural stem cells were also cultured within varying collagen matrix densities while exposed to NGF concentrations and they experienced 3D to 3D collective migration. By generating vascular endothelial growth factor concentration gradients, adult human dermal microvascular endothelial cells also migrated in a 2D to 3D manner and formed a stable lumen within a specific collagen matrix density. It was observed that a minimum absolute concentration and concentration gradient were required to stimulate migration of all types of the cells. This device has the advantage of changing multiple parameters simultaneously and is expected to have wide applicability in cell studies. (paper)

  18. Construct 3D porous hollow Co3O4 micro-sphere: A potential oxidizer of nano-energetic materials with superior reactivity

    Science.gov (United States)

    Wang, Jun; Zheng, Bo; Qiao, Zhiqiang; Chen, Jin; Zhang, Liyuan; Zhang, Long; Li, Zhaoqian; Zhang, Xingquan; Yang, Guangcheng

    2018-06-01

    High energy density and rapid reactivity are the future trend for nano-energetic materials. Energetic performance of nano-energetic materials depends on the interfacial diffusion and mass transfer during the reacted process. However, the development of desired structure to significantly enhance reactivity still remains challenging. Here we focused on the design and preparation of 3D porous hollow Co3O4 micro-spheres, in which gas-blowing agents (air) and maximize interfacial interactions were introduced to enhance mass transport and reduce the diffusion distance between the oxidizer and fuel (Aluminum). The 3D hierarchical Co3O4/Al based nano-energetic materials show a low-onset decomposition temperature (423 °C), and high heat output (3118 J g-1) resulting from porous and hollow nano-structure of Co3O4 micro-spheres. Furthermore, 3D hierarchical Co3O4/Al arrays were directly fabricated on the silicon substrate, which was fully compatible with silicon-based microelectromechanical systems to achieve functional nanoenergetics-on-a-chip. This approach provides a simple and efficient way to fabricate 3D ordered nano-energetic arrays with superior reactivity and the potential on the application in micro-energetic devices.

  19. Study on Microstructure and Mechanical Properties of Hypereutectic Al-18Si Alloy Modified with Al-3B.

    Science.gov (United States)

    Gong, Chunjie; Tu, Hao; Wu, Changjun; Wang, Jianhua; Su, Xuping

    2018-03-20

    An hypereutectic Al-18Si alloy was modified via an Al-3B master alloy. The effect of the added Al-3B and the modification temperature on the microstructure, tensile fracture morphologies, and mechanical properties of the alloy were investigated using an optical microscope, Image-Pro Plus 6.0, a scanning electron microscope, and a universal testing machine. The results show that the size of the primary Si and its fraction decreased at first, and then increased as an additional amount of Al-3B was added. When the added Al-3B reached 0.2 wt %, the fraction of the primary Si in the Al-18Si alloy decreased with an increase in temperature. Compared with the unmodified Al-18Si alloy, the tensile strength and elongation of the alloy modified at 850 °C with 0.2 wt % Al-3B increased by 25% and 81%, respectively. The tensile fracture of the modified Al-18Si alloy exhibited partial ductile fracture characteristics, but there were more areas with ductile characteristics compared with that of the unmodified Al-18Si alloy.

  20. Effects of Nb and Si on densities of valence electrons in bulk and defects of Fe3Al alloys

    Institute of Scientific and Technical Information of China (English)

    邓文; 钟夏平; 黄宇阳; 熊良钺; 王淑荷; 郭建亭; 龙期威

    1999-01-01

    Positron lifetime measurements have been performed in binary Fe3Al and Fe3Al doping with Nb or Si alloys. The densities of valence electrons of the bulk and microdefects in all tested samples have been calculated by using the positron lifetime parameters. Density of valence electron is low in the bulk of Fe3Al alloy. It indicates that, the 3d electrons in a Fe atom have strong-localized properties and tend to form covalent bonds with Al atoms, and the bonding nature in Fe3Al is a mixture of metallic and covalent bonds. The density of valence electron is very low in the defects of Fe3Al grain boundary, which makes the bonding cohesion in grain boundary quite weak. The addition of Si to Fe3Al gives rise to the decrease of the densities of valence electrons in the bulk and the grain boundary thus the metallic bonding cohesion. This makes the alloy more brittle. The addition of Nb to Fe3Al results in the decrease of the ordering energy of the alloy and increases the density of valence electron and th

  1. Nonequilibrium synthesis of NbAl3 and Nb-Al-V alloys by laser cladding. II - Oxidation behavior

    Science.gov (United States)

    Haasch, R. T.; Tewari, S. K.; Sircar, S.; Loxton, C. M.; Mazumder, J.

    1992-01-01

    Isothermal oxidation behaviors of NbAl3 alloy synthesized by laser cladding were investigated at temperatures between 800 and 1400 C, and the effect of vanadium microalloying on the oxidation of the laser-clad alloy was examined. The oxidation kinetics of the two alloys were monitored using thermal gravimetric weight gain data, and the bulk and surface chemistries were analyzed using XRD and XPS, respectively. It was found that NbAl3 did not form an exclusive layer of protective Al2O3. The oxidation products at 800 C were found to be a mixture of Nb2O5 and Al2O3. At 1200 C, a mixture of NbAlO4, Nb2O5, and Al2O3 formed; and at 1400 C, a mixture of NbAlO4, Al2O3, NbO2, NbO(2.432), and Nb2O5 formed. The addition of V led to a dramatic increase of the oxidation rate, which may be related to the formation of (Nb, V)2O5 and VO2, which grows in preference to protective Al2O3.

  2. Sintering of (Ni,Mg)(Al,Fe)2O4 Materials and their Corrosion Process in Na3AlF6-AlF3-K3AlF6 Electrolyte

    Science.gov (United States)

    Xu, Yibiao; Li, Yawei; Yang, Jianhong; Sang, Shaobai; Wang, Qinghu

    2017-06-01

    The application of ledge-free sidewalls in the Hall-Héroult cells can potentially reduce the energy requirement of aluminum production by about 30 pct (Nightingale et al. in J Eur Ceram, 33:2761-2765, 2013). However, this approach poses great material challenges since such sidewalls are in direct contact with corrosive electrolyte. In the present paper, (Ni,Mg)(Al,Fe)2O4 materials were prepared using fused magnesia, reactive alumina, nickel oxide, and iron oxide powders as the starting materials. The sintering behaviors of specimens as well as their corrosion resistance to molten electrolyte have been investigated by means of X-ray diffraction and scanning electron microscope. The results show that after firing at temperature ranging from 1673 K (1400 °C) up to 1873 K (1600 °C), all the specimens prepared are composed of single-phase (Ni,Mg)(Al,Fe)2O4 composite spinel, the lattice parameter of which increases with increasing Fe3+ ion concentration. Increasing the iron oxide content enhances densification of the specimens, which is accompanied by the formation of homogeneously distributed smaller pores in the matrix. The corrosion tests show that corrosion layers consist of fluoride and Ni(Al,Fe)2O4 composite spinel grains are produced in specimens with Fe/Al mole ratio no more than 1, whereas dense Ni(Al,Fe)2O4 composite spinel layers are formed on the surface of the specimens with Fe/Al mole ratio more than 1. The dense Ni(Al,Fe)2O4 composite spinel layers formed improve the corrosion resistance of the specimens by inhibiting the infiltration of electrolyte and hindering the chemical reaction between the specimen and electrolyte.

  3. Analysis conditions of an industrial Al-Mg-Si alloy by conventional and 3D atom probes.

    Science.gov (United States)

    Danoix, F; Miller, M K; Bigot, A

    2001-10-01

    Industrial 6016 Al-Mg-Si(Cu) alloys are presently regarded as attractive candidates for heat treatable sheet materials. Their mechanical properties can be adjusted for a given application by age hardening of the alloys. The resulting microstructural evolution takes place at the nanometer scale, making the atom probe a well suited instrument to study it. Accuracy of atom probe analysis of these aluminium alloys is a key point for the understanding of the fine scale microstructural evolution. It is known to be strongly dependent on the analysis conditions (such as specimen temperature and pulse fraction) which have been widely studied for ID atom probes. The development of the 3D instruments, as well as the increase of the evaporation pulse repetition rate have led to different analysis conditions, in particular evaporation and detection rates. The influence of various experimental parameters on the accuracy of atom probe data, in particular with regard to hydride formation sensitivity, has been reinvestigated. It is shown that hydrogen contamination is strongly dependent on the electric field at the specimen surface, and that high evaporation rates are beneficial. Conversely, detection rate must be limited to smaller than 0.02 atoms/pulse in order to prevent drastic pile-up effect.

  4. Does the index-to-ring finger length ratio (2D:4D) differ in amyotrophic lateral sclerosis (ALS)? Results from an international online case-control study.

    Science.gov (United States)

    Parkin Kullmann, Jane Alana; Pamphlett, Roger

    2017-08-07

    The ratio of the length of the index finger (2D) to the ring finger (4D) (2D:4D) has been reported to be lower (ie, 2Dcontrols. This has led to suggestions that exposure to increased prenatal testosterone, which also lowers this ratio, could be a risk factor for ALS. In an attempt to test this hypothesis, we examined 2D:4Ds from large numbers of patients with ALS and controls. An online multilingual questionnaire enabling respondents to measure their own index and ring finger lengths. Of the initial 949 respondents, 572 remained for analysis after elimination for inability to straighten fingers, not answering the question, statistical outliers and aged controls (112 males, 258 females). Unpaired t-tests with 95% CIs were used to assess differences in mean 2D:4Ds. Males had significantly lower mean 2D:4Ds than females, in both ALS and control groups, for both left and right hands. No significant differences were found in 2D:4Ds between ALS and control groups, in either males or females, for either left or right hands. Receiver operating characteristic curves showed no power for 2D:4Ds to predict ALS status in either males or females. 2D:4Ds did not differ between patients with ALS and controls in this study. This was despite the dataset being large enough to confirm the established finding of lower 2D:4Ds in males compared with females. These findings do not support the hypothesis that exposure to increased prenatal testosterone is a risk factor for ALS. A putative lower 2D:4D has been proposed to explain the link between ALS and exercise, but our results indicate that other exercise-related factors are more likely to explain this association. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2017. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

  5. Formation of Al3Ti/Mg composite by powder metallurgy of Mg-Al-Ti system.

    Science.gov (United States)

    Yang, Zi R; Qi Wang, Shu; Cui, Xiang H; Zhao, Yu T; Gao, Ming J; Wei, Min X

    2008-07-01

    An in situ titanium trialuminide (Al 3 Ti)-particle-reinforced magnesium matrix composite has been successfully fabricated by the powder metallurgy of a Mg-Al-Ti system. The reaction processes and formation mechanism for synthesizing the composite were studied by differential scanning calorimetry (DSC), x-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy-dispersive x-ray spectroscopy (EDS). Al 3 Ti particles are found to be synthesized in situ in the Mg alloy matrix. During the reaction sintering of the Mg-Al-Ti system, Al 3 Ti particles are formed through the reaction of liquid Al with as-dissolved Ti around the Ti particles. The formed intermetallic particles accumulate at the original sites of the Ti particles. As sintering time increases, the accumulated intermetallic particles disperse and reach a relatively homogeneous distribution in the matrix. It is found that the reaction process of the Mg-Al-Ti system is almost the same as that of the Al-Ti system. Mg also acts as a catalytic agent and a diluent in the reactions and shifts the reactions of Al and Ti to lower temperatures. An additional amount of Al is required for eliminating residual Ti and solid-solution strengthening of the Mg matrix.

  6. Temperature and concentration quenching of Tb{sup 3+} emissions in Y{sub 4}Al{sub 2}O{sub 9} crystals

    Energy Technology Data Exchange (ETDEWEB)

    Boruc, Z., E-mail: z.boruc@stud.elka.pw.edu.pl [Institute of Microelectronics and Optoelectronics, Warsaw University of Technology, ul. Koszykowa 75, 00-662 Warsaw (Poland); Fetlinski, B.; Kaczkan, M. [Institute of Microelectronics and Optoelectronics, Warsaw University of Technology, ul. Koszykowa 75, 00-662 Warsaw (Poland); Turczynski, S.; Pawlak, D. [Institute of Electronic Materials Technology, ul. Wolczynska 133, 01-919 Warsaw (Poland); Malinowski, M. [Institute of Microelectronics and Optoelectronics, Warsaw University of Technology, ul. Koszykowa 75, 00-662 Warsaw (Poland)

    2012-08-15

    Highlights: Black-Right-Pointing-Pointer Spectroscopic properties of Tb{sup 3+}:Y{sub 4}Al{sub 2}O{sub 9} crystals are studied. Black-Right-Pointing-Pointer Concentration and temperature dependencies of fluorescence are investigated. Black-Right-Pointing-Pointer The cross-relaxation transfer rates are experimentally determined. Black-Right-Pointing-Pointer Strong influence of cross relaxation process on {sup 5}D{sub 3} emission quenching is observed. Black-Right-Pointing-Pointer Decays are modelled using Inokuti-Hirayama approach. - Abstract: Spectroscopic properties of trivalent terbium (Tb{sup 3+}) activated Y{sub 4}Al{sub 2}O{sub 9} (abbreviated YAM) crystals were studied. Concentration and temperature dependent emission spectra and fluorescence dynamics profiles have been investigated in YAM:Tb{sup 3+} in order to understand better processes responsible for quenching of the terbium {sup 5}D{sub 3} and {sup 5}D{sub 4} emissions. Decays were modelled using Inokuti-Hirayama approach to obtain information on the energy transfer mechanism. The cross-relaxation transfer rates were experimentally determined as a function of temperature and Tb{sup 3+} concentration. The investigation revealed strong influence of cross-relaxation process on {sup 5}D{sub 3} emission quenching. The two different processes responsible for the increase of fluorescence quenching with growing temperature were observed, both related to thermal activation energy. For temperatures above 700 K, the temperature dependence of the emission intensity ratio ({sup 5}D{sub 3}/{sup 5}D{sub 4}) becomes linear and the decay times are rapidly decreasing monotonously with increasing temperature, what is confirming the potential of Y{sub 4}Al{sub 2}O{sub 9}:Tb{sup 3+} material in high temperature luminescence thermometry.

  7. Rediseño y fabricación de una impresora 3D RepRap.

    OpenAIRE

    Huertas González, Joan

    2014-01-01

    El objetivo principal de este proyecto es conseguir las habilidades necesarias para fabricar una impresora 3D del tipo Rep Rap, una tipología de impresoras Open source. Una vez conseguido este objetivo se rediseñan piezas de la propia impresora con el objetivo de mejorar el diseño actual. Se plantea el proyecto como iniciación al mundo de la impresión 3D y de los materiales plásticos con los que se puede trabajar, PLA, HDPE, ABS o NYLON. Se instruye al lector para que tambié...

  8. 3D game environments create professional 3D game worlds

    CERN Document Server

    Ahearn, Luke

    2008-01-01

    The ultimate resource to help you create triple-A quality art for a variety of game worlds; 3D Game Environments offers detailed tutorials on creating 3D models, applying 2D art to 3D models, and clear concise advice on issues of efficiency and optimization for a 3D game engine. Using Photoshop and 3ds Max as his primary tools, Luke Ahearn explains how to create realistic textures from photo source and uses a variety of techniques to portray dynamic and believable game worlds.From a modern city to a steamy jungle, learn about the planning and technological considerations for 3D modelin

  9. Plasma and milk concentrations of vitamin D3 and 25-hydroxy vitamin D3 following intravenous injection of vitamin D3 or 25-hydroxy vitamin D3.

    OpenAIRE

    Hidiroglou, M; Knipfel, J E

    1984-01-01

    Plasma levels of vitamin D3 or 25-hydroxyvitamin D3 in ewes after administration of a single massive intravenous dose of vitamin D3 (2 X 10(6) IU) or 25-hydroxy vitamin D3 (5 mg) were determined at zero, one, two, three, five, ten and 20 days postinjection. In six ewes injected with vitamin D3 conversion of vitamin D3 to 25-hydroxy vitamin D3 resulted in a six-fold increase in the plasma 25-hydroxy vitamin D3 level within one day. Elevated levels were maintained until day 10 but by day 20 a s...

  10. Synthetic of Zr2Al3C5 material

    International Nuclear Information System (INIS)

    Leela-Adisorn, U.; Yamaguchi, A.

    2005-01-01

    Synthesis method of Zr 2 Al 3 C 5 via solid state reaction between Al, ZrC and carbon powder was studied. Al-ZrC-C compact with equivalent mol ratio of Zr 2 Al 3 C 5 was heated up to 1600 C in Ar atmosphere for 1 h and 4 h but ZrC phase still existed as major phase with very small amount of Zr 2 Al 3 C 5 . Because ZrC started to oxidize at low temperature under very low oxygen partial pressure, the same mol ratio of Al-ZrC-C compact was heated at 1600 C in vacuum for 1 h as parallel test. After firing in vacuum, some carbon still exist with small amount of AlZrC 2 occurred with Zr 2 Al 3 C 5 as a main phase, but no ZrC was found. Different result from firing in Ar atmosphere and in vacuum had been discussed here. It was believed that very small amount of impurities in Ar had some effect on the formation of Al-Zr-C compound. The effect of very small amount of impurities in Ar was studied by thermal analysis (DTA/TG) and XRD. It was found that very small amount of impurities in Ar has effect on the reaction between Al, ZrC and carbon by diffusion through the surface and form Zr-C-O-N solid solution. This solid solution cannot differentiate from ZrC by XRD. With help of thermal analysis method (DTA/TG), Zr-C-O-N solid solution can be differentiated from ZrC. Therefore, synthesis of Al-Zr-C compound should be done in vacuum. Zr 2 Al 3 C 5 can be prepared from mixture of Al-ZrC-C with excess amount of Al at 1600 C for 1 h. (orig.)

  11. [Structure and luminescence properties of Ga2O3 : Cr3+ by Al doping].

    Science.gov (United States)

    Wang, Xian-Sheng; Wan, Min-Hua; Wang, Yin-Hai; Zhao, Hui; Hu, Zheng-Fa; Li, Hai-Ling

    2013-11-01

    The Al doping gallate phosphor (Ga(1-x)Al(x))2O3 : Cr3+ (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5) was synthesized by a high temperature solid-state reaction method. The X-ray diffractions show that the phase of the phosphors remains to be Ga2 O3 structure with increase in the contents of Al3+ ion. Beside, the fact that the X-ray diffraction peak shifts towards big angles with increasing Al3+ ions content shows that Al3+ ions entered the Ga2 O3 lattice. The peaks of the excitation spectra located at 258, 300, 410 and 550 nm are attributed to the band to band transition of the matrix, charge transfer band transition, and 4A2 --> 4T1 and 4A2 --> 4T2 transition of Cr3+ ions, respectively. Those excitation spectrum peak positions show different degrees of blue shift with the increase in the Al3+ ions content. The blue shift of the first two peaks are due to the band gap energy of substrate and the electronegativity between Cr3+ ions and ligands increasing, respectively. The blue shift of the energy level transition of Cr3+ ion is attributed to crystal field strength increasing. The Cr3+ ion luminescence changes from a broadband emission to a narrow-band emission with Al3+ doping, because the emission of Cr3+ ion changed from 4 T2 --> 4A2 to 2E --> 4A2 transition with the crystal field change after Al3+ ions doping. The Al3+ ions doping improved the long afterglow luminescence properties of samples, and the sample showed a longer visible near infrared when Al3+ ions content reaches 0.5. The thermoluminescence curve shows the sample with suitable trap energy level, and this is also the cause of the long afterglow luminescence materials.

  12. Irradiation effects of 6 MeV electron on electrical properties of Al/Al2O3/n-Si MOS capacitors

    International Nuclear Information System (INIS)

    Laha, P.; Banerjee, I.; Bajaj, A.; Chakraborty, P.; Barhai, P.K.; Dahiwale, S.S.; Das, A.K.; Bhoraskar, V.N.; Kim, D.; Mahapatra, S.K.

    2012-01-01

    The influence of 6 MeV electron irradiation on the electrical properties of Al/Al 2 O 3 /n-Si metal–oxide–semiconductor (MOS) capacitors has been investigated. Using rf magnetron sputtering deposition technique, Al/Al 2 O 3 /n-Si MOS capacitors were fabricated and such twelve capacitors were divided into four groups. The first group of MOS capacitors was not irradiated with 6 MeV electrons and treated as virgin. The second group, third group and fourth group of MOS capacitors were irradiated with 6 MeV electrons at 10 kGy, 20 kGy, and 30 kGy doses, respectively, keeping the dose rate ∼1 kGy/min. The variations in crystallinity of the virgin and irradiated MOS capacitors have been compared from GIXRD (Grazing Incidence X-ray Diffraction) spectra. Thickness and in-depth elemental distributions of individual layers were performed using Secondary Ion Mass Spectrometry (SIMS). The device parameters like flat band voltage (V FB ) and interface trap density (D it ) of virgin and irradiated MOS capacitors have been calculated from C vs V and G/ω vs V curve, respectively. The electrical properties of the capacitors were investigated from the tan δ vs V graph. The device parameters were estimated using C–V and G/ω–V measurements. Poole–Frenkel coefficient (β PF ) of the MOS capacitors was determined from leakage current (I)–voltage (V) measurement. The leakage current mechanism was proposed from the β PF value. - Highlights: ► The electron irradiation effects make variation in the device parameters. ► The device parameters changes due to percentage of defects and charge trapping. ► Leakage current of Al/Al 2 O 3 /n-Si changes due to interface dangling bonds. ► The leakage current mechanism of MOS structures is due to Poole-Frenkel effect.

  13. CHF Enhancement in Flow Boiling using Al2O3 Nano-Fluid and Al2O3 Nano-Particle Deposited Tube

    International Nuclear Information System (INIS)

    Kim, Tae Il; Chun, T. H.; Chang, S. H.

    2010-01-01

    Nano-fluids are considered to have strong ability to enhance CHF. Most CHF experiments using nano-fluids were conducted in pool boiling conditions. However there are very few CHF experiments with nano-fluids in flow boiling condition. In the present study, flow boiling CHF experiments using bare round tube with Al 2 O 3 nano-fluid and Al 2 O 3 nano-particle deposited tube with DI water were conducted under atmospheric pressure. CHFs were enhanced up to ∼ 80% with Al 2 O 3 nano-fluid and CHFs with Al 2 O 3 nano-particle deposited tube were also enhanced up to ∼ 80%. Inner surface of test section tube were observed by SEM and AFM after CHF experiments

  14. SAP-like ultrafine-grained Al composites dispersion strengthened with nanometric AlN

    International Nuclear Information System (INIS)

    Balog, M.; Krizik, P.; Yan, M.; Simancik, F.; Schaffer, G.B.; Qian, M.

    2013-01-01

    This paper reports the development of novel Sinter-Aluminum-Pulver (SAP)-like Al–AlN nanocomposites via replacing the native Al 2 O 3 thin films on fine Al powder with a large volume fraction of in situ formed nanometric AlN dispersoids. Fine gas-atomized Al powder (d 50 =1.3 µm) compacts were first partially nitrided at 590 °C in flowing nitrogen, controlled by a small addition of Sn (0.3–0.4 wt%), and subsequently consolidated by hot direct extrusion. The resulting Al–AlN composites consisted of submicrometric Al grains reinforced with nanometric AlN dispersoids together with some nanometric Al 2 O 3 dispersoids. An Al–13 vol% AlN nanocomposite fabricated this way achieved exceptional ultimate tensile strength of 227 MPa, yield strength of 195 MPa and Young's modulus of 66 GPa at 300 °C, superior to typical SAP materials and coarse grained Al–AlN composites. In addition, the Al–13 vol% AlN nanocomposite exhibited good thermal stability up to 500 °C. The strengthening mechanism is discussed

  15. Preparation, structure and analysis of the bonding in the molecular entity (OSO)2Li{[AlF(ORF)3]Li[Al(ORF)4]} (RF = C(CF3)3).

    Science.gov (United States)

    Cameron, T Stanley; Nikiforov, Grigory B; Passmore, Jack; Rautiainen, J Mikko

    2010-03-14

    The (SO(2))(2)Li[AlF(OR(F))(3)]Li[Al(OR(F))(4)] (1) (R(F) = C(CF(3))(3)) molecular entity was obtained by thermal decomposition of Li[Al(OR(F))(4)] followed by crystallization from liquid SO(2). 1, containing two SO(2) molecules eta(1)-O coordinated to Li(+), was structurally characterized by single crystal X-ray diffraction and NMR spectroscopy in SO(2)(l). Bonding analyses of 1 (bond valency units, AIM analysis, atomic charges, bond orders) show that 1 can be either considered as a Li(OSO)(2)(+) complex stabilized by the large WCA [AlF(OR(F))(3)](-)Li(+)[Al(OR(F))(4)](-) or as consisting of 2 SO(2), 2 Li(+), [AlF(OR(F))(3)](-), and [Al(OR(F))(4)](-) joined by electrostatic interactions into the discrete molecular entity 1. The bonding between Li(+) and SO(2) molecules is shown to be almost completely attributable to monopole-induced dipole electrostatic interactions. Theoretical gas phase lithium ion affinity of SO(2) is determined to be stronger than its silver(I) ion affinity owing largely to the shorter lithium SO(2) contacts in the calculated structures that increase the electrostatic interaction.

  16. Modification of Turen Bentonite with AlCl3 for Esterification of Palmitic Acid

    Directory of Open Access Journals (Sweden)

    Abdulloh Abdulloh

    2014-03-01

    Full Text Available Natural Turen bentonite has been modified and applied as catalyst for palmitic acid esterification. Modification of natural Turen bentonite was conducted by cation exchange method using AlCl3 solution. Catalyst characterization was performed on X-ray Fluoroscence, X-ray Diffraction, nitrogen adsorption-desorption and infrared spectroscopy techniques. The catalytic activity test in the esterification reaction of palmitic acid with methanol was conducted by bath at 65 °C with a variation of reaction time of 1, 2, 3, 4 and 5 h. Catalytic activity has been observed qualitatively using GC-MS and quantitatively by changes in acid number. The analysis showed the formation of Al3+-bentonite. Observation on the elements has shown that the presence of calcium decreased from 10.2% to 4.17%, with an increase of aluminium content from 9.9% to 13%. Diffraction line at 2θ 5.7379º became 5.6489º, along with changes in d-spacing of 15.3895 Å to 15.6319 Å. The surface area increased from 83.78 m2/g to 91.26 m2/g, while Brönsted acid sites increased from 10.2 µmol/g to 67.5 µmol/g and Lewis acid sites increased from 94.9 µmol/g to 132 µmol/g. Furthermore, Al3+-bentonite has showed as active catalyst in the esterification reaction of palmitic acid with palmitic acid with conversion of 78.78% for 5 h. © 2014 BCREC UNDIP. All rights reservedReceived: 24th September 2013; Revised: 31st December 2013; Accepted: 26th January 2014[How to Cite: Abdulloh, A., Maryam, S., Aminah, N.S., Triyono, T., Trisunaryanti, W., Mudasir, M., Prasetyoko, D. (2014. Modification of Turen’s Bentonite with AlCl3 for Esterification of Palmitic Acid. Bulletin of Chemical Reaction Engineering & Catalysis, 9 (1: 66-73. (doi:10.9767/bcrec.9.1.5513.66-73][Permalink/DOI: http://dx.doi.org/10.9767/bcrec.9.1.5513.66-73

  17. Surface study and thickness control of thin Al2O3 film on Cu-9%Al(111) single crystal

    International Nuclear Information System (INIS)

    Yamauchi, Yasuhiro; Yoshitake, Michiko; Song Weijie

    2004-01-01

    We were successful in growing a uniform flat Al 2 O 3 film on the Cu-9%Al(111) surface using the improved cleaning process, low ion energy and short time sputtering. The growth of ultra-thin film of Al 2 O 3 on Cu-9%Al was investigated using Auger electron spectroscopy (AES) and a scanning electron microscope (SEM). The Al 2 O 3 film whose maximum thickness was about 4.0 nm grew uniformly on the Cu-9%Al surface. The Al and O KLL Auger peaks of Al 2 O 3 film shifted toward low kinetic energy, and the shifts were related to Schottky barrier formation and band bending at the Al 2 O 3 /Cu-9%Al interface. The thickness of Al 2 O 3 film on the Cu-9%Al surface was controlled by the oxygen exposure

  18. 3-D Whole-Core Transport Calculation with 3D/2D Rotational Plane Slicing Method

    Energy Technology Data Exchange (ETDEWEB)

    Yoo, Han Jong; Cho, Nam Zin [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of)

    2014-10-15

    Use of the method of characteristics (MOC) is very popular due to its capability of heterogeneous geometry treatment and widely used for 2-D core calculation, but direct extension of MOC to 3-D core is not so attractive due to huge calculational cost. 2-D/1-D fusion method was very successful for 3-D calculation of current generation reactor types (highly heterogeneous in radial direction but piece-wise homogeneous in axial direction). In this paper, 2-D MOC concept is extended to 3-D core calculation with little modification of an existing 2-D MOC code. The key idea is to suppose 3-D geometry as a set of many 2-D planes like a phone-directory book. Dividing 3-D structure into a large number of 2-D planes and solving each plane with a simple 2-D SN transport method would give the solution of a 3-D structure. This method was developed independently at KAIST but it is found that this concept is similar with that of 'plane tracing' in the MCCG-3D code. The method developed was tested on the 3-D C5G7 OECD/NEA benchmark problem and compared with the 2-D/1-D fusion method. Results show that the proposed method is worth investigating further. A new approach to 3-D whole-core transport calculation is described and tested. By slicing 3-D structure along characteristic planes and solving each 2-D plane problem, we can get 3-D solution. The numerical test results indicate that the new method is comparable with the 2D/1D fusion method and outperforms other existing methods. But more fair comparison should be done in similar discretization level.

  19. Crystal-field excitations in PrAl sub 3 and NdAl sub 3 at ambient and elevated pressure

    CERN Document Server

    Straessle, T; Rusz, J; Janssen, S; Juranyi, F; Sadykov, R; Furrer, A

    2003-01-01

    The crystal fields (CFs) of the binary rare-earth compounds PrAl sub 3 and NdAl sub 3 have been examined at ambient pressure by means of inelastic neutron scattering. The CF of the latter compound has also been measured under hydrostatic pressure (p = 0.84 GPa). The observed substantial changes of the CF under pressure are discussed within the framework of first-principles density functional theory calculations.

  20. Constraints on Moho Depth and Crustal Thickness in the Liguro-Provençal Basin from a 3d Gravity Inversion : Geodynamic Implications Contraintes sur la profondeur du moho et l'épaisseur crustale dans le bassin liguro-provençal à partir de l'inversion 3D de données gravimétriques : implications géodynamiques

    Directory of Open Access Journals (Sweden)

    Gaulier J. M.

    2006-12-01

    Full Text Available 3D gravity modelling is combined with seismic refraction and reflection data to constrain a new Moho depth map in the Liguro-Provençal Basin (Western Mediterranean Sea. At seismically controlled points, the misfit between the gravimetric solution and the seismic data is about 2 km for a range of Moho depth between 12 km (deep basin and 30 km (mainlands. The oceanic crust thickness in the deep basin (5 km is smaller than the average oceanic crust thickness reported in open oceans (7 km, pointing to a potential mantle temperature 30°C to 50°C below normal and/or very slow oceanic spreading rate. Oceanic crust thickness is decreasing towards the Ligurian Sea and towards the continent-ocean boundary to values as small as 2 km. Poor magma supply is a result of low potential mantle temperature at depth, lateral thermal conduction towards unextended continental margin, and decrease of the oceanic spreading rate close to the pole of opening in the Ligurian Sea. Re-examination of magnetic data (paleomagnetic data and magnetic lineations indicates that opening of the Liguro-Provençal Basin may have ceased as late as Late Burdigalian (16. 5 Ma or even later. The absence of significant time gap between cessation of opening in the Liguro-Provençal Basin and rifting of the Tyrrhenian domain favours a continuous extension mechanism since Upper Oligocene driven by the African trench retreat. Ce rapport présente un travail commun avec le Laboratoire de géodynamique de l'École normale supérieure (ENS. Ce travail doit être resitué dans son contexte : l'étude régionale du golfe du Lion a été possible dans le cadre du projet européen Integrated Basin Studies. Le développement du code d'inversion 3D avait fait l'objet de conventions avec l'ENS pendant les années précédentes. La mise en Suvre d'une telle inversion est désormais possible à l'IFP. Il n'y a pas d'interface pour ce calculateur. L'aide des collègues de l'ENS est souhaitable pour la

  1. MODELACIÓN HIDROLÓGICA DEL HUMEDAL DE JABOQUE – BOGOTÁ, D.C. (COLOMBIA

    Directory of Open Access Journals (Sweden)

    Beltrán Julio

    2013-07-01

    Full Text Available Se propone un modelo de simulación dinámico para explicar los procesos hidrológicosdel humedal Jaboque – Bogotá D.C., Colombia, en tres secciones con característicasfísicas y químicas particulares. El modelo incluye los caudales de entrada y salidade agua para cada una de las secciones del humedal. La modelación dinámica sebasó en ecuaciones diferenciales. Se utilizó el método Euler de integración con elprograma computacional Stella 9.1®. El comportamiento hidrológico del humedaltiene una alta dependencia de los aportes de la cuenca aferente que a su vez obedecenfundamentalmente a las condiciones climáticas de la cuenca. En el año 1992 (añoNiño la precipitación fue 432.7 mm/año con una descarga de agua estimada de lacuenca aferente de 905 225 m3/año, siendo el valor más bajo en los últimos 39 años.En el 2010 (año Niña la precipitación anual fue de 1251.3. mm, con una descargade la cuenca aferente de 2 471 634 m3/año, que corresponde al dato más alto para elmismo periodo. La comparación entre los caudales de entrada y salida del humedalJaboque muestran una diferencia bruta de 82 165 m3/mes para un total anual de 985980 m3/año. El tiempo hidráulico de retención modelado (THR se estimó en quincepara la primera sección, 36 y 42 días para la segunda y tercera sección. El promedioen el humedal fue de 93 días/año. El análisis de sensibilidad mostró que entre loslimites de 800 mm/año y 900 mm/año, valores entre los cuales oscila el promediomultianual de la precipitación, el comportamiento del THR es de 13 a 15 días/año enla primera sección, en la segunda de 32 a 36 días/año y la tercera de 38 a 43 días. Secorrobora así la relación que existe entre la precipitación y los factores morfométricosdel humedal.

  2. Mechanochemically synthesized Al2O3-TiC nanocomposite

    International Nuclear Information System (INIS)

    Mohammad Sharifi, E.; Karimzadeh, F.; Enayati, M.H.

    2010-01-01

    Al 2 O 3 -TiC nanocomposite was synthesized by ball milling of aluminum, titanium oxide and graphite powder mixtures. Effect of the milling time and heat treatment temperatures were investigated. The structural evolution of powder particles after different milling times was studied by X-ray diffractometry and scanning electron microscopy. The results showed that after 40 h of ball milling the Al/TiO 2 /C reacted with a self-propagating combustion mode producing Al 2 O 3 -TiC nanocomposite. In final stage of milling, alumina and titanium carbide crystallite sizes were less than 10 nm. After annealing at 900 o C for 1 h, Al 2 O 3 and TiC crystallite sizes remained constant, however increasing annealing temperature to 1200 o C increased Al 2 O 3 and TiC crystallite size to 65 and 30 nm, respectively. No phase change was observed after annealing of the synthesized Al 2 O 3 -TiC powder.

  3. From 2D to 3D turbulence through 2D3C configurations

    Science.gov (United States)

    Buzzicotti, Michele; Biferale, Luca; Linkmann, Moritz

    2017-11-01

    We study analytically and numerically the geometry of the nonlinear interactions and the resulting energy transfer directions of 2D3C flows. Through a set of suitably designed Direct Numerical Simulations we also study the coupling between several 2D3C flows, where we explore the transition between 2D and fully 3D turbulence. In particular, we find that the coupling of three 2D3C flows on mutually orthogonal planes subject to small-scale forcing leads to a stationary 3D out-of-equilibrium dynamics at the energy containing scales where the inverse cascade is directly balanced by a forward cascade carried by a different subsets of interactions. ERC AdG Grant No 339032 NewTURB.

  4. Effects of O in a binary-phase TiAl-Ti3Al alloy: from site occupancy to interfacial energetics

    International Nuclear Information System (INIS)

    Wei Ye; Xu Huibin; Zhou Hongbo; Zhang Ying; Lu Guanghong

    2011-01-01

    We have investigated site occupancy and interfacial energetics of a TiAl-Ti 3 Al binary-phase system with O using a first-principles method. Oxygen is shown to energetically occupy the Ti-rich octahedral interstitial site, because O prefers to bond with Ti rather than Al. The occupancy tendency of O in TiAl alloy from high to low is α 2 -Ti 3 Al to the γ-α 2 interface and γ-TiAl. We demonstrate that O can largely affect the mechanical properties of the TiAl-Ti 3 Al system. Oxygen at the TiAl-Ti 3 Al interface reduces both the cleavage energy and the interface energy, and thus weakens the interface strength but strongly stabilizes the TiAl/Ti 3 Al interface with the O 2 molecule as a reference. Consequently, the mechanical property variation of TiAl alloy due to the presence of O not only depends on the number of TiAl/Ti 3 Al interfaces but also is related to the O concentration in the alloy.

  5. Site occupancy and magnetic study of Al{sup 3+} and Cr{sup 3+} co-substituted Y{sub 3}Fe{sub 5}O{sub 12}

    Energy Technology Data Exchange (ETDEWEB)

    Bouziane, K. [Department of Physics, College of Science, Sultan Qaboos University, P.O. Box 36, PC 123, Muscat, Sultanate of Oman (Oman)], E-mail: bouzi@squ.edu.om; Yousif, A.; Widatallah, H.M. [Department of Physics, College of Science, Sultan Qaboos University, P.O. Box 36, PC 123, Muscat, Sultanate of Oman (Oman); Amighian, J. [Department of Physics, University of Isfahan, Isfahan (Iran, Islamic Republic of)

    2008-10-15

    Single-phased polycrystalline Y{sub 3}Fe{sub 5-2x}Al{sub x}Cr{sub x}O{sub 12} garnet samples (x=0, 0.2, 0.4 and 0.6) have been prepared by the conventional ceramic technique. Rietveld refinement of X-ray diffraction patterns of the samples shows them to crystallize in the Ia3d space group and the corresponding lattice constant to decrease with increasing Al{sup 3+} and Cr{sup 3+} contents (x). Moessbauer results indicate that Cr{sup 3+} substitutes for Fe{sup 3+} at the octahedral sites whilst Al{sup 3+} essentially replaces Fe{sup 3+} at the tetrahedral sites. This result indicates that co-doping of Y{sub 3}Fe{sub 5}O{sub 12} does not affect the preferential site occupancy for separate individual substitution of either Cr{sup 3+} or Al{sup 3+}. The magnetization measurements reveal that the Curie temperature (T{sub c}) monotonically decreases with increasing x while the magnetic moment per unit formula decreases up to x=0.4 and then slightly increases for x=0.6. This reflects a progressive weakening of the ferrimagnetic exchange interaction between the Fe{sup 3+} ions at octahedral and tetrahedral sites due to co-substitution. The magnetic moment was calculated using the cations distribution inferred from the Moessbauer data and the collinear ferrimagnetic model, and was found to agree reasonably with the experimentally measured value. The phenomenological amplitude crossover, characterized by the temperature T*, has also been observed in the doped YIG and briefly discussed.

  6. 3D Space Shift from CityGML LoD3-Based Multiple Building Elements to a 3D Volumetric Object

    Directory of Open Access Journals (Sweden)

    Shen Ying

    2017-01-01

    Full Text Available In contrast with photorealistic visualizations, urban landscape applications, and building information system (BIM, 3D volumetric presentations highlight specific calculations and applications of 3D building elements for 3D city planning and 3D cadastres. Knowing the precise volumetric quantities and the 3D boundary locations of 3D building spaces is a vital index which must remain constant during data processing because the values are related to space occupation, tenure, taxes, and valuation. To meet these requirements, this paper presents a five-step algorithm for performing a 3D building space shift. This algorithm is used to convert multiple building elements into a single 3D volumetric building object while maintaining the precise volume of the 3D space and without changing the 3D locations or displacing the building boundaries. As examples, this study used input data and building elements based on City Geography Markup Language (CityGML LoD3 models. This paper presents a method for 3D urban space and 3D property management with the goal of constructing a 3D volumetric object for an integral building using CityGML objects, by fusing the geometries of various building elements. The resulting objects possess true 3D geometry that can be represented by solid geometry and saved to a CityGML file for effective use in 3D urban planning and 3D cadastres.

  7. Comparative first-principle analysis of un-doped and V{sup 3+}-doped {alpha}-ZnAl{sub 2}S{sub 4} spinel

    Energy Technology Data Exchange (ETDEWEB)

    Brik, M.G. [Institute of Physics, University of Tartu, Riia 142, Tartu 51014 (Estonia); Nazarov, M., E-mail: mvnazarov@mail.ru [School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); Institute of Applied Physics, Academiei Street 5, Chisinau MD-2028, Republic of Moldova (Moldova, Republic of); Ahmad-Fauzi, M.N. [School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); Kulyuk, L.; Anghel, S. [Institute of Applied Physics, Academiei Street 5, Chisinau MD-2028, Republic of Moldova (Moldova, Republic of); Sushkevich, K. [Moldova State University, Mateevici Street 60, Chisinau, MD-2009, Republic of Moldova (Moldova, Republic of); Boulon, G. [Physical Chemistry of Luminescent Materials, Claude Bernard Lyon 1 University, UMR 5620 CNRS, La Doua, 69622 Villeurbanne (France)

    2012-09-15

    The experimental and theoretical studies of the optical properties of pure {alpha}-ZnAl{sub 2}S{sub 4} and {alpha}-ZnAl{sub 2}S{sub 4}:V{sup 3+} crystals were carried out. The ab initio and crystal field calculations of the structural and optical properties of {alpha}-ZnAl{sub 2}S{sub 4}:V{sup 3+} were compared with the corresponding experimental data. It was shown that the lowest vanadium 3d states are located at about 1.36 eV above the valence band's top. The complete energy level scheme of the {alpha}-ZnAl{sub 2}S{sub 4}:V{sup 3+} system, which includes the host's electronic band structure and impurity ion's energy levels, was suggested on the basis of the performed calculations. - Highlights: Black-Right-Pointing-Pointer Experimental and theoretical studies of {alpha}-ZnAl{sub 2}S{sub 4} and {alpha}-ZnAl{sub 2}S{sub 4}:V{sup 3+} crystals were carried out. Black-Right-Pointing-Pointer Ab inito and crystal field calculations were used in structural and spectroscopic analyses. Black-Right-Pointing-Pointer The complete energy level scheme of the {alpha}-ZnAl{sub 2}S{sub 4}:V{sup 3+} system was suggested. Black-Right-Pointing-Pointer The lowest vanadium 3d states are located at about 1.36 eV above the valence band's top.

  8. Luminescence properties of Ce3+ and Tb3+ co-activated ZnAl2O4 phosphor

    International Nuclear Information System (INIS)

    Tshabalala, K.G.; Cho, S.-H.; Park, J.-K.; Pitale, Shreyas S.; Nagpure, I.M.; Kroon, R.E.; Swart, H.C.; Ntwaeaborwa, O.M.

    2012-01-01

    In this study, a solution combustion method was used to prepare green emitting Ce 3+ –Tb 3+ co-activated ZnAl 2 O 4 phosphor. The samples were annealed at 700 °C in air or hydrogen atmosphere to improve their crystallinity and optical properties. X-ray diffraction study confirmed that both as-prepared and post-preparation annealed samples crystallized in the well known cubic spinel structure of ZnAl 2 O 4 . An agglomeration of irregular platelet-like particles whose surfaces were encrusted with smaller spheroidal particles was confirmed by scanning electron microscopy (SEM). The fluorescence data collected from the annealed samples with different concentrations of Ce 3+ and Tb 3+ show the enhanced green emission at 543 nm associated with 5 D 4 → 7 F 5 transitions of Tb 3+ . The enhancement was attributed to energy transfer from Ce 3+ to Tb 3+ . Possible mechanism of energy transfer via a down conversion process is discussed. Furthermore, cathodoluminescence (CL) intensity degradation of this phosphor was also investigated and the degradation data suggest that the material was chemically stable and the CL intensity was also stable after 10 h of irradiation by a beam of high energy electrons.

  9. Annealing, temperature, and bias-induced threshold voltage instabilities in integrated E/D-mode InAlN/GaN MOS HEMTs

    Science.gov (United States)

    Blaho, M.; Gregušová, D.; Haščík, Š.; Ťapajna, M.; Fröhlich, K.; Šatka, A.; Kuzmík, J.

    2017-07-01

    Threshold voltage instabilities are examined in self-aligned E/D-mode n++ GaN/InAlN/GaN MOS HEMTs with a gate length of 2 μm and a source-drain spacing of 10 μm integrated in a logic invertor. The E-mode MOS HEMT technology is based on selective dry etching of the cap layer which is combined with Al2O3 grown by atomic-layer deposition at 380 K. In the D-mode MOS HEMT, the gate recessing is skipped. The nominal threshold voltage (VT) of E/D-mode MOS HEMTs was 0.6 and -3.4 V, respectively; the technology invariant maximal drain current was about 0.45 A/mm. Analysis after 580 K/15 min annealing step and at an elevated temperature up to 430 K reveals opposite device behavior depending on the HEMT operational mode. It was found that the annealing step decreases VT of the D-mode HEMT due to a reduced electron injection into the modified oxide. On the other hand, VT of the E-mode HEMT increases with reduced density of surface donors at the oxide/InAlN interface. Operation at the elevated temperature produces reversible changes: increase/decrease in the VT of the respective D-/E-mode HEMTs. Additional bias-induced experiments exhibit complex trapping phenomena in the devices: Coaction of shallow (˜0.1 eV below EC) traps in the GaN buffer and deep levels at the oxide/InAlN interface was identified for the E-mode device, while trapping in the D-mode HEMTs was found to be consistent with a thermo-ionic injection of electrons into bulk oxide traps (˜0.14 eV above EF) and trapping at the oxide/GaN cap interface states.

  10. Chemisorption of carbon dioxide and ethene on eta-Al2O3

    International Nuclear Information System (INIS)

    Schubart, W.; Knoezinger, H.

    1985-01-01

    The chemisorption of ethene on eta-Al 2 O 3 has been studied by thermal desorption spectroscopy (TDS) as a function of the degree of surface hydroxylation. The effect of CO 2 poisoning and the D 2 exchange with chemisorbed C 2 H 4 was investigated. While CO 2 shows a broad distribution of interaction energies, three (or four) distinct chemisorption states can be detected for C 2 H 4 . It is suggested that C 2 H 4 forms vinyl species via heterolytic cleavage of C-H bonds on acid-base pair sites. These presumably contain strong defects (ensembles of anion vacanies) and OH-groups coordinated to tetrahedral Al 3+ in immediate vicinity. Differences in coordination and local environment are assumed to be responsible for the formation of the three (or four) distinct chemisorption states. (orig.) [de

  11. Outlook for NanoInside Theme "3D nano-structuring and metrology"

    NARCIS (Netherlands)

    Kruit, P.; Kroon, M.G.M. de; Maas, D.J.; Baumer, S.M.B.; Spruit, W.E.T.

    2017-01-01

    Het vakgebied van 3D nano-structurering en metrologie ontwikkelt zich razendsnel, zowel in Nederland als in de rest van de wereld. Het niveau van de Nederlandse betrokken onderzoekers, kennisinstituten en bedrijven is van wereldklasse. Veel Nederlandse academische groepen, kennisinstituten en

  12. Effect of 24,25-dihydroxyvitamin D3 on 1,25-dihydroxyvitamin D3 [1,25-(OH)2D3] metabolism in vitamin D-deficient rats infused with 1,25-(OH)2D3

    International Nuclear Information System (INIS)

    Yamato, H.; Matsumoto, T.; Fukumoto, S.; Ikeda, K.; Ishizuka, S.; Ogata, E.

    1989-01-01

    Previous studies revealed that administration of 24,25-dihydroxyvitamin D3 [24,25-(OH)2D3] to calcium (Ca)-deficient rats causes a dose-dependent reduction in markedly elevated serum 1,25-(OH)2D3 level. Although the results suggested that the metabolism of 1,25-(OH)2D3 was accelerated by 24,25-(OH)2D3, those experiments could not define whether the enhanced metabolism of 1,25-(OH)2D3 played a role in the reduction in the serum 1,25-(OH)2D3 level. In the present study, in order to address this issue more specifically, serum 1,25-(OH)2D3 was maintained solely by exogenous administration through miniosmotic pumps of 1,25-(OH)2D3 into vitamin D-deficient rats. Thus, by measuring the serum 1,25-(OH)2D3 concentration, the effect of 24,25-(OH)2D3 on the MCR of 1,25-(OH)2D3 could be examined. Administration of 24,25-(OH)2D3 caused a dose-dependent enhancement in the MCR of 1,25-(OH)2D3, and 1 microgram/100 g rat.day 24,25-(OH)2D3, which elevated serum 24,25-(OH)2D3 to 8.6 +/- 1.3 ng/ml, significantly increased MCR and suppressed serum levels of 1,25-(OH)2D3. The effect of 24,25-(OH)2D3 on 1,25-(OH)2D3 metabolism developed with a rapid time course, and the recovery of iv injected [1 beta-3H]1,25-(OH)2D3 in blood was significantly reduced within 1 h. In addition, there was an increase in radioactivity in the water-soluble fraction of serum as well as in urine, suggesting that 1,25-(OH)2D3 is rapidly degraded to a water-soluble metabolite(s). Furthermore, the reduction in serum 1,25-(OH)2D3 was associated with a reduction in both serum and urinary Ca levels. Because the conversion of [3H]24,25-(OH)2D3 to [3H]1,24,25-(OH)2D3 or other metabolites was minimal in these rats, 24,25-(OH)2D3 appears to act without being converted into other metabolites. These results demonstrate that 24,25-(OH)2D3 rapidly stimulates the metabolism of 1,25-(OH)2D3 and reduces its serum level

  13. L'evoluzione della stampa 3D e le sue applicazioni in campo museale

    OpenAIRE

    Pignatelli, Francesco

    2014-01-01

    ItLa stampa 3D è passata dall'uso solo industriale al grande pubblico degli appassionati e dei maker. Questa evoluzione interessa anche i musei, che possono adottare le tecniche di stampa 3D per rendere più fruibili le loro collezioni, creare una maggiore interattività con il pubblico potenziale e generare nuovo business attraverso il merchandising. Più in futuro i musei andranno verso un modello in cui l'originale e la copia ad alta precisione ottenuta con la stampa 3D, e persino il suo mode...

  14. Effect of Al-doped YCrO3 on structural, electronic and magnetic properties

    Science.gov (United States)

    Durán, A.; Verdín, E.; Conde, A.; Escamilla, R.

    2018-05-01

    Structural, dielectric and magnetic properties were investigated in the YCr1-xAlxO3 with 0 cell volume of the orthorhombic structure without changes in the oxidation state of the Cr3+ ions. We discuss two mechanisms that could have a significant influence on the magnetic properties. The first is related to local deformation occurring for x structure. The local deformation is controlled by the inclination of the octahedrons and the octahedral distortion having a strong effect on the TN and the coercive field at low Al concentrations. On the other hand, the decreasing of the magnetization values (Mr and Hc) is ascribed to changes in the electronic structure, which is confirmed by a decreasing of the contribution of Cr 3d states at Fermi level due to increasing Al3+ content. Thus, we analyzed and discussed that both mechanisms influence the electronic properties of the YCr1-xAlxO3 solid solution.

  15. Synthesis and characterization of high volume fraction Al-Al2O3 nanocomposite powders by high-energy milling

    International Nuclear Information System (INIS)

    Prabhu, B.; Suryanarayana, C.; An, L.; Vaidyanathan, R.

    2006-01-01

    Al-Al 2 O 3 metal matrix composite (MMC) powders with volume fractions of 20, 30, and 50% Al 2 O 3 were synthesized by high-energy milling of the blended component powders. The particle sizes of Al 2 O 3 studied were 50 nm, 150 nm, and 5 μm. A uniform distribution of the Al 2 O 3 reinforcement in the Al matrix was successfully obtained after milling the powders for a period of 20 h at a ball-to-powder ratio of 10:1 in a SPEX mill. The uniform distribution of Al 2 O 3 in the Al matrix was confirmed by characterizing these nanocomposite powders by scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray mapping, and X-ray diffraction (XRD) techniques

  16. The microstructure and mechanical properties of Mg-3Al-3RE alloys

    International Nuclear Information System (INIS)

    Tian, X.; Wang, L.M.; Wang, J.L.; Liu, Y.B.; An, J.; Cao, Z.Y.

    2008-01-01

    The Mg-3Al-3RE alloys (RE, the cerium-rich or the yttrium-rich misch metal) were smelted in a resistance furnace under the protective flux from the Mg-RE master alloys and pure magnesium ingots. The microstructure and mechanical properties of samples prepared by steel mould casting method were investigated. Results show that the main phases of the alloys are α-Mg, Mg 17 Al 12 and Al-RE compounds, and the grain size reduced with the increasing content of the cerium-rich misch metal. Mg-3Al-2Ymm-1Cemm (Ymm, the yttrium-rich misch metal; Cemm, the Cerium-rich misch metal) exhibited the highest mechanical properties, that is UTS = 201 MPa and YS = 75 MPa, and ε = 8.2% at room temperature; UTS = 146 MPa, and YS = 70 MPa, ε = 18.2% at the temperature of 150 deg. C, respectively. Fracture surface analysis revealed that the Mg-3Al-2Ymm-1Cemm alloy has a mixed fracture feature at room temperature but ductile fracture at elevated temperature (150 deg. C)

  17. Intrinsic ductility and environmental embrittlement of binary Ni3Al

    International Nuclear Information System (INIS)

    George, E.P.; Liu, C.T.; Pope, D.P.

    1993-01-01

    Polycrystalline, B-free Ni 3 Al (23.4 at.% Al), produced by cold working and recrystallizing a single crystal, exhibits room temperature tensile ductilities of 3-5% in air and 13-16% in oxygen. These ductilities are considerably higher than anything previously reported, and demonstrate that the 'intrinsic' ductility of Ni 3 Al is much higher than previously thought. They also show that the moisture present in ordinary ambient air can severely embrittle Ni 3 Al (ductility decreasing from a high of 16% in oxygen to a low of 3% in air). Fracture is predominantly intergranular in both air and oxygen. This indicates that, while moisture can further embrittle the GBs in Ni 3 Al, they persist as weak links even in the absence of environmental embrittlement. However, they are not 'intrinsically brittle' as once thought, since they can withstand relatively large plastic deformations prior to fracture. Because B essentially eliminates environmental embrittlement in Ni 3 Al - and environmental embrittlement is a major cause of poor ductility in B-free Ni 3 Al - it is concluded that a significant portion of the so-called B effect must be related to suppression of moisture-induced environmental embrittlement. However, since B-doped Ni 3 Al fractures transgranularly, whereas B-free Ni 3 Al fractures predominantly intergranularly, B must have the added effect that it strengthens the GBs. A comparison with the earlier work on Zr-doped Ni 3 Al shows that Zr improves the ductility of Ni 3 Al, both in air and (and even more dramatically) in oxygen. While the exact mechanism of this ductility improvement is not clear at present, Zr appears to have more of an effect on (enhancing) GB strength than on (suppressing) environmental embrittlement

  18. Investigation of the phonon-spin interaction in systems: 3d1 ions in Al2O3

    International Nuclear Information System (INIS)

    Devismes, Nicole.

    1975-01-01

    The respective evolution of V 2+ , V 3+ and V 4+ ion concentrations in Al doped V monocrystals during a γ irradiation at 300K has been quantitatively studied from optical absorption, low temperature thermal conductivity, and ESR measurements. A wide range of the total concentration in V was investigated (from 60 to 1360ppm) and two domains can be distinguished ( approximately 250ppm) in which the evolutions of the ion concentrations are quite different. This indicates that several charge transfer mechanisms are involved. An estimate of the absolute concentrations of various ions before and after γ irradiation is given and some spin-phonon coupling constants derived [fr

  19. Characterization of nanosized Al2(WO4)3

    International Nuclear Information System (INIS)

    Nihtianova, D.; Velichkova, N.; Nikolova, R.; Koseva, I.; Yordanova, A.; Nikolov, V.

    2011-01-01

    Graphical abstract: TEM method allows to detect small quantities of impurities not detectable by other methods. In our case impurities of W 5 O 14 are detected in Al 2 (WO 4 ) 3 nanopowder. Highlights: → Nanosized Al 2 (WO 4 ) 3 by simple co-precipitation method. → Spherical particles with mean size of 22 nm distributed between 10 and 40 nm at 630 o C. → XRD, DTA and TEM confirm well defined products with perfect structure. → TEM locality allows detection of impurities not detectable by XRD and DTA. -- Abstract: Nanosized aluminum tungstate Al 2 (WO 4 ) 3 was prepared by co-precipitation reaction between Na 2 WO 4 and Al(NO 3 ) 3 aqueous solutions. The powder size and shape, as well as size distribution are estimated after different conditions of powder preparation. The purity of the final product was investigated by XRD and DTA analyses, using the single crystal powder as reference. Between the specimen and the reference no difference was detected. The crystal structure of Al 2 (WO 4 ) 3 nanosized powder was confirmed by TEM (SAED, HRTEM). In additional, TEM locality allows to detect some W 5 O 14 impurities, which are not visible by conventional X-ray powder diffraction and thermal analyses.

  20. Ta4AlC3: Phase determination, polymorphism and deformation

    International Nuclear Information System (INIS)

    Eklund, P.; Palmquist, J.-P.; Hoewing, J.; Trinh, D.H.; El-Raghy, T.; Hoegberg, H.; Hultman, L.

    2007-01-01

    Ta 4 AlC 3 , a new member of the M n+1 AX n -phase family, has been synthesized and characterized (n = 1-3; M = early transition metal; A A-group element; and X = C and/or N). Phase determination by Rietveld refinement of synchrotron X-ray diffraction data shows that Ta 4 AlC 3 belongs to the P6 3 /mmc space group with a and c lattice parameters of 3.10884 ± 0.00004 A and 24.0776 ± 0.0004 A, respectively. This is shown to be the α-polymorph of Ta 4 AlC 3 , with the same structure as Ti 4 AlN 3 . Lattice imaging by high-resolution transmission electron microscopy demonstrates the characteristic MAX-phase stacking of α-Ta 4 AlC 3 . Three modes of mechanical deformation of α-Ta 4 AlC 3 are observed: lattice bending, kinking and delamination

  1. RAG-3D: a search tool for RNA 3D substructures

    Science.gov (United States)

    Zahran, Mai; Sevim Bayrak, Cigdem; Elmetwaly, Shereef; Schlick, Tamar

    2015-01-01

    To address many challenges in RNA structure/function prediction, the characterization of RNA's modular architectural units is required. Using the RNA-As-Graphs (RAG) database, we have previously explored the existence of secondary structure (2D) submotifs within larger RNA structures. Here we present RAG-3D—a dataset of RNA tertiary (3D) structures and substructures plus a web-based search tool—designed to exploit graph representations of RNAs for the goal of searching for similar 3D structural fragments. The objects in RAG-3D consist of 3D structures translated into 3D graphs, cataloged based on the connectivity between their secondary structure elements. Each graph is additionally described in terms of its subgraph building blocks. The RAG-3D search tool then compares a query RNA 3D structure to those in the database to obtain structurally similar structures and substructures. This comparison reveals conserved 3D RNA features and thus may suggest functional connections. Though RNA search programs based on similarity in sequence, 2D, and/or 3D structural elements are available, our graph-based search tool may be advantageous for illuminating similarities that are not obvious; using motifs rather than sequence space also reduces search times considerably. Ultimately, such substructuring could be useful for RNA 3D structure prediction, structure/function inference and inverse folding. PMID:26304547

  2. Effect of 10Ce-TZP/Al2O3 nanocomposite particle amount and sintering temperature on the microstructure and mechanical properties of Al/(10Ce-TZP/Al2O3) nanocomposites

    International Nuclear Information System (INIS)

    Soltani, N.; Pech-Canul, M.I.; Bahrami, A.

    2013-01-01

    Highlights: • Increasing the 10Ce-TZP/Al 2 O 3 content up to 7 wt.%, enhanced composites’ hardness. • Significant enhancement in compressive strength is obtained with 7% 10Ce-TZP/Al 2 O 3 . • Sintering at 450 °C, hardness and compressive strength are higher than at 400 °C. - Abstract: A zirconia/alumina nanocomposite stabilized with cerium oxide (Ce-TZP/Al 2 O 3 nanocomposite) can be a good substitute as reinforcement in metal matrix composites. In the present study, the effect of the amount of 10Ce-TZP/Al 2 O 3 particles on the microstructure and properties of Al/(10Ce-TZP/Al 2 O 3 ) nanocomposites was investigated. For this purpose, aluminum powders with average size of 30 μm were ball-milled with 10Ce-TZP/Al 2 O 3 nanocomposite powders (synthesized by aqueous combustion) in varying amounts of 1, 3, 5, 7, and 10 wt.%. Cylindrical-shape samples were prepared by pressing the powders at 600 MPa for 60 min while heating at 400–450 °C. The specimens were then characterized by scanning and transmission electron microscopy (SEM and TEM) in addition to different physical and mechanical testing methods in order to establish the optimal processing conditions. The highest compression strength was obtained in the composite with 7 wt.% (10Ce-TZP/Al 2 O 3 ) sintered at 450 °C

  3. Determination of the 3d34d and 3d35s configurations of Fe V

    International Nuclear Information System (INIS)

    Azarov, V.I.

    2001-01-01

    The analysis of the spectrum of four times ionized iron, Fe V, has led to the determination of the 3d 3 4d and 3d 3 5s configurations. From 975 classified lines in the region 645-1190 A we have established 123 of 168 theoretically possible 3d 3 4d levels and 26 of 38 possible 3d 3 5s levels. The estimated accuracy of values of energy levels of these two configurations is about 0.7 cm -1 and 1.0 cm -1 , respectively. The level structure of the system of the 3d 4 , 3d 3 4s, 3d 3 4d and 3d 3 5s configurations has been theoretically interpreted and the energy parameters have been determined by a least squares fit to the observed levels. A comparison of parameters in Cr III and Fe V ions is given. (orig.)

  4. Raman and infrared spectroscopy of pure and doped GdAlO3 with rare earth ions

    International Nuclear Information System (INIS)

    Bagnato, V.S.

    1983-01-01

    IR and Raman measurements were carried out in pure and Eu +3 - doped GdAlO 3 with the purpose of understanding their K=O phonom modes and the Eu +3 electronic transitions. Starting from the GdAlO 3 symmetry, (D1 6 sub(2h)), the correlation method allows the classification of the number and symmetries of the modes, as well their assignement as either internal or external. Experimental and theoretical results are in good agreement and show three well defined absorption bands in GdAlO 3 . The internal modes are found to be located around 670 cm -1 (stretching) and 480 cm -1 (bending), while the external modes are around 200 cm -1 . The interaction of Eu +3 electronic states with the GdAlO 3 crystal field were studied by taking into account a small perturbative orthorrombic (C sub(s)) distortion on a crystal field with symmetry O sub(h). This small distortion lifts completely the degeneracy of the 7 F sub(J) (J=0,1,...,6) levels and allows the 7 J sub(o) → 7 F sub(J) transitions. (Author) [pt

  5. Reactive diffusion and superconductivity of Nb3Al multilayer films

    International Nuclear Information System (INIS)

    Vandenberg, J.M.; Hong, M.; Hamm, R.A.; Gurvitch, M.

    1985-01-01

    Thin films of A15 Nb 3 Al have been prepared by reactive diffusion of sputter-deposited Nb/Al multilayers. The diffusion reactions were studied by in situ annealing x-ray diffraction in the temperature range 50--950 0 C. Initially the Nb and Al sublayers react to form the phase NbAl 3 . This interface reaction prevents the formation of the sigma-phase Nb 2 Al, frequently found as a second phase in A15 Nb 3 Al materials; NbAl 3 reacts with the remaining Nb to form the A15 phase. The highest T/sub c/, 16.2 K measured resistively and 15.2 K inductively, was found in a Nb/Al multilayer with an A15 cell parameter a 0 = 5.195 A which corresponds to approx.20 at. % Al. From a comparison with previous investigations of the T/sub c/ dependence on Al concentration and A15 cell parameter, it is concluded that a small amount of the A15 phase has a higher composition of 22--23 at. % Al

  6. 2.5D real waveform and real noise simulation of receiver functions in 3D models

    Science.gov (United States)

    Schiffer, Christian; Jacobsen, Bo; Balling, Niels

    2014-05-01

    There are several reasons why a real-data receiver function differs from the theoretical receiver function in a 1D model representing the stratification under the seismometer. Main reasons are ambient noise, spectral deficiencies in the impinging P-waveform, and wavefield propagation in laterally varying velocity variations. We present a rapid "2.5D" modelling approach which takes these aspects into account, so that a given 3D velocity model of the crust and uppermost mantle can be tested more realistically against observed recordings from seismometer arrays. Each recorded event at each seismometer is simulated individually through the following steps: A 2D section is extracted from the 3D model along the direction towards the hypocentre. A properly slanted plane or curved impulsive wavefront is propagated through this 2D section, resulting in noise free and spectrally complete synthetic seismometer data. The real vertical component signal is taken as a proxy of the real impingent wavefield, so by convolution and subsequent addition of real ambient noise recorded just before the P-arrival we get synthetic vertical and horizontal component data which very closely match the spectral signal content and signal to noise ratio of this specific recording. When these realistic synthetic data undergo exactly the same receiver function estimation and subsequent graphical display we get a much more realistic image to compare to the real-data receiver functions. We applied this approach to the Central Fjord area in East Greenland (Schiffer et al., 2013), where a 3D velocity model of crust and uppermost mantle was adjusted to receiver functions from 2 years of seismometer recordings and wide angle crustal profiles (Schlindwein and Jokat, 1999; Voss and Jokat, 2007). Computationally this substitutes tens or hundreds of heavy 3D computations with hundreds or thousands of single-core 2D computations which parallelize very efficiently on common multicore systems. In perspective

  7. Direct production of D-arabinose from D-xylose by a coupling reaction using D-xylose isomerase, D-tagatose 3-epimerase and D-arabinose isomerase.

    Science.gov (United States)

    Sultana, Ishrat; Mizanur, Rahman Md; Takeshita, Kei; Takada, Goro; Izumori, Ken

    2003-01-01

    Klebsiella pneumoniae 40bXX, a mutant strain that constitutively produces D-arabinose isomerase (D-AI), was isolated through a series of repeated subcultures from the parent strain on a mineral salt medium supplemented with L-Xylose as the sole carbon source. D-AI could be efficiently immobilized on chitopearl beads. The optimum temperature for the activity of the immobilized enzyme was 40 degrees C and the enzyme was stable up to 50 degrees C. The D-Al was active at pH 10.0 and was stable in the range of pH 6.0-11.0. The enzyme required manganese ions for maximum activity. Three immobilized enzymes, D-xylose isomerase (D-XI), D-tagatose 3-epimerase (D-TE and D-AI were used for the preparation of D-arabinose from D-xylose in a coupling reaction. After completion of the reaction, degradation of D-xylulose was carried out by Saccharomyces cerevisiae. The reaction mixture containing D-Xylose, D-ribulose and the product was then separated by ion exchange column chromatography. After crystallization, the product was checked by HPLC, IR spectroscopy, NMR spectroscopy and optical rotation measurements. Finally, 2.0 g of D-arabinose could be obtained from 5 g of the substrate.

  8. Laser scanner 3D terrestri e mobile

    Directory of Open Access Journals (Sweden)

    Mario Ciamba

    2013-08-01

    Full Text Available Recentemente si è svolto a Roma un evento dimostrativo per informare, professionisti e ricercatori del settore inerente il rilievo strumentale, sulle recenti innovazioni che riguardano i laser scanner 3d. Il mercato della strumentazione dedicata al rilevamento architettonico e dell'ambiente, offre molte possibilità di scelta. Oggi i principali marchi producono strumenti sempre più efficienti ed ideati per ambiti di applicazione specifici, permettendo ai professionisti, la giusta scelta in termini di prestazioni ed economia. A demonstration event was recently held in Rome with the aim to inform professionals and researchers on recent innovations on instrumental survey related to the 3d laser scanner. The market of instrumentation for architectural survey offers many possibilitiesof choice. Today the major brands produce instruments that are more efficient and designed for specific areas of application, allowing the right choice in terms of performance and economy.

  9. Laser scanner 3D terrestri e mobile

    Directory of Open Access Journals (Sweden)

    Mario Ciamba

    2013-08-01

    Full Text Available Recentemente si è svolto a Roma un evento dimostrativo per informare, professionisti e ricercatori del settore inerente il rilievo strumentale, sulle recenti innovazioni che riguardano i laser scanner 3d. Il mercato della strumentazione dedicata al rilevamento architettonico e dell'ambiente, offre molte possibilità di scelta. Oggi i principali marchi producono strumenti sempre più efficienti ed ideati per ambiti di applicazione specifici, permettendo ai professionisti, la giusta scelta in termini di prestazioni ed economia.A demonstration event was recently held in Rome with the aim to inform professionals and researchers on recent innovations on instrumental survey related to the 3d laser scanner. The market of instrumentation for architectural survey offers many possibilitiesof choice. Today the major brands produce instruments that are more efficient and designed for specific areas of application, allowing the right choice in terms of performance and economy.

  10. Efficient dense blur map estimation for automatic 2D-to-3D conversion

    Science.gov (United States)

    Vosters, L. P. J.; de Haan, G.

    2012-03-01

    Focus is an important depth cue for 2D-to-3D conversion of low depth-of-field images and video. However, focus can be only reliably estimated on edges. Therefore, Bea et al. [1] first proposed an optimization based approach to propagate focus to non-edge image portions, for single image focus editing. While their approach produces accurate dense blur maps, the computational complexity and memory requirements for solving the resulting sparse linear system with standard multigrid or (multilevel) preconditioning techniques, are infeasible within the stringent requirements of the consumer electronics and broadcast industry. In this paper we propose fast, efficient, low latency, line scanning based focus propagation, which mitigates the need for complex multigrid or (multilevel) preconditioning techniques. In addition we propose facial blur compensation to compensate for false shading edges that cause incorrect blur estimates in people's faces. In general shading leads to incorrect focus estimates, which may lead to unnatural 3D and visual discomfort. Since visual attention mostly tends to faces, our solution solves the most distracting errors. A subjective assessment by paired comparison on a set of challenging low-depth-of-field images shows that the proposed approach achieves equal 3D image quality as optimization based approaches, and that facial blur compensation results in a significant improvement.

  11. Reactive synthesis of NbAl3 matrix composites

    International Nuclear Information System (INIS)

    Lu, L.; Kim, Y.S.; Gokhale, A.B.; Abbaschian, R.

    1990-01-01

    NbAl 3 matrix composites were synthesized in-situ via reactive hot compaction (RHC) of elemental powders. It was found that the simultaneous application of pressure during synthesis was effective in attaining a near-theoretical density matrix at relatively low temperatures and pressures. Using this technique, two types of composites were produced: matrices containing a uniform dispersion of second phase particles (either Nb 3 Al or Nb 2 Al with an Nb core or Nb 2 Al) and matrices reinforced with coated or uncoated ductile Nb filaments. It was found that a limited amount of toughening is obtained using the first approach, while composites containing coated Nb filaments exhibited a significant increase in the ambient temperature fracture toughness. In this paper, various aspects of RHC processing of NbAl 3 matrix composites, the effect of initial stoichiometry and powder size on the microstructure, as well as the mechanical behavior of the composites are discussed

  12. Monolithically integrated enhancement/depletion-mode AlGaN/GaN HEMT D flip-flop using fluorine plasma treatment

    International Nuclear Information System (INIS)

    Xie Yuanbin; Quan Si; Ma Xiaohua; Zhang Jincheng; Li Qingmin; Hao Yue

    2011-01-01

    Depletion-mode and enhancement-mode AlGaN/GaN HEMTs using fluorine plasma treatment were integrated on one wafer. Direct-coupled FET logic circuits, such as an E/D HEMT inverter, NAND gate and D flip-flop, were fabricated on an AlGaN/GaN heterostructure. The D flip-flop and NAND gate are demonstrated in a GaN system for the first time. The dual-gate AlGaN/GaN E-HEMT substitutes two single-gate E-HEMTs for simplifying the NAND gate and shrinking the area, integrating with a conventional AlGaN/GaN D-HEMT and demonstrating a NAND gate. E/D-mode D flip-flop was fabricated by integrating the inverters and the NAND gate on the AlGaN/GaN heterostructure. At a supply voltage of 2 V, the E/D inverter shows an output logic swing of 1.7 V, a logic-low noise margin of 0.49 V and a logic-high noise margin of 0.83 V. The NAND gate and D flip-flop showed correct logic function demonstrating promising potential for GaN-based digital ICs. (semiconductor integrated circuits)

  13. Crystalline gamma-Al2O3 physical vapour deposition-coating for steel thixoforging tools.

    Science.gov (United States)

    Bobzin, K; Hirt, G; Bagcivan, N; Khizhnyakova, L; Ewering, M

    2011-10-01

    The process of thixoforming, which has been part of many researches during the last decades, combines the advantages of forging and casting for the shaping of metallic components. But due to the high temperatures of semi-solid steel alloys high demands on the tools are requested. To resists the thermal and mechanical loads (wear, friction, thermal and thermomechanical fatigue) protecting thin films are necessary. In this regard crystalline gamma-Al2O3 deposited via Physical Vapour Deposition (PVD) is a promising candidate: It exhibits high thermal stability, high oxidation resistance and high hot hardness. In the present work the application of a (Ti, Al)N/gamma-Al2O3 coating deposited by means of Magnetron Sputter Ion Plating in an industrial coating unit is presented. The coating was analysed by means of Rockwell test, nanoindentation, and Scanning Electron Microscopy (SEM). The coated tool was tested in thixoforging experiments with steel grade X210CrW12 (AlSI D6). The surface of the coated dies was examined with Scanning Electron Microscope (SEM) after 22, 42, 90 and 170 forging cycles.

  14. Characterization of microstructure and mechanical properties of friction stir welded AlMg5- Al_2O_3 nanocomposites

    International Nuclear Information System (INIS)

    Babu, N. Kishore; Kallip, Kaspar; Leparoux, Marc; AlOgab, Khaled A.; Reddy, G.M.; Talari, M.K.

    2016-01-01

    In the present study, powder metallurgy processed unmilled AlMg5, milled AlMg5 and milled AlMg5-0.5 vol% Al_2O_3 nanocomposite have been successfully friction stir welded (FSW). The effect of friction stir welding on the evolution of weld microstructures; hardness and tensile properties were studied and discussed in detail. FSW of unmilled AlMg5 resulted in significant grain refinement and strain hardening in the nugget zone induced by the thermo-mechanical processing, thereby increasing the stir zone hardness and tensile strengths to 100 HV and 324 MPa when compared to 80 HV and 300 MPa of base metal, respectively. In contrast, the FSW of milled AlMg5 and milled AlMg5-0.5 vol% Al_2O_3 samples showed a reduction in UTS values to 375 MPa and 401 MPa in the stir zone compared to 401 MPa and 483 MPa of respective base metal values. Transmission electron microscopic (TEM) investigation of weld stir zones revealed the homogenous distribution of Al_4C_3 nanophases in milled AlMg5 and Al_2O_3 nanoparticles in milled AlMg5-0.5 vol% Al_2O_3 samples throughout the aluminium matrix. It was revealed that the pre-stored energy from the prior ball milling and hot pressing processes, higher deformation energy and grain boundary pinning effect due to the presence of reinforcement particles has resulted in a higher recrystallization tendency and retarded grain growth during FSW of milled samples. The welds prepared with milled AlMg5-0.5 vol% Al_2O_3 exhibited higher hardness and tensile strength in the stir zone when compared to all other conditions which was attributed to Hall Petch effect due to fine grain size and Orowan strengthening effect due to Al_2O_3 reinforcements.

  15. Axionic D3-D7 Inflation

    CERN Document Server

    Burgess, C P; Postma, M

    2009-01-01

    We study the motion of a D3 brane moving within a Type IIB string vacuum compactified to 4D on K3 x T_2/Z_2 in the presence of D7 and O7 planes. We work within the effective 4D supergravity describing how the mobile D3 interacts with the lightest bulk moduli of the compactification, including the effects of modulus-stabilizing fluxes. We seek inflationary solutions to the resulting equations, performing our search numerically in order to avoid resorting to approximate parameterizations of the low-energy potential. We consider uplifting from D-terms and from the supersymmetry-breaking effects of anti-D3 branes. We find examples of slow-roll inflation (with anti-brane uplifting) with the mobile D3 moving along the toroidal directions, falling towards a D7-O7 stack starting from the antipodal point. The inflaton turns out to be a linear combination of the brane position and the axionic partner of the K3 volume modulus, and the similarity of the potential along the inflaton direction with that of racetrack inflat...

  16. Fabrication and thermal characterization of amorphous and nanocrystalline Al{sub 9}FeNi/Al{sub 3}Ti compound

    Energy Technology Data Exchange (ETDEWEB)

    Tavoosi, Majid, E-mail: ma.tavoosi@gmail.com

    2017-01-15

    In this study, the fabrication and structural characterization of amorphous/nanocrystalline Al{sub 9}FeNi/Al{sub 3}Ti phase has been performed. In this regards, milling and annealing processes were applied on Al{sub 80}Fe{sub 10}Ti{sub 5}Ni{sub 5} (at. %) powder mixture for different periods of time. The prepared samples were characterized using X-ray diffraction (XRD), scanning and transmission electron microscopy (SEM and TEM) and differential scanning calorimetery (DSC). According to the results, supersaturated solid solution, nanocrystalline Al{sub 9}FeNi/Al{sub 3}Ti (with average crystallite size of about 7 nm) and amorphous phases indicated three different microstructures which can be formed in Al{sub 80}Fe{sub 10}Ti{sub 5}Ni{sub 5} system during milling process. The formed supersaturated solid solution and amorphous phases were unstable and transformed to Al{sub 9}FeNi/Al{sub 3}Ti intermetallic compound during annealing process. It is shown that, Al{sub 9}FeNi phase in Al{sub 9}FeNi/Al{sub 3}Ti intermetallic compound can decompose into Al{sub 3}Ni, Al{sub 13}Fe{sub 4} and liquid phases during a reversible peritectic reaction at 809 °C. - Highlights: • We study the effect of milling process on Al{sub 80}Fe{sub 10}Ti{sub 5}Ni{sub 5} alloy. • We study the effect of annealing on Al{sub 80}Fe{sub 10}Ti{sub 5}Ni{sub 5} supersaturated solid solution phase. • We study the effect of annealing on Al{sub 80}Fe{sub 10}Ti{sub 5}Ni{sub 5} amorphous phase. • We study the thermal behaviour of Al{sub 9}FeNi/Al{sub 3}Ti compound.

  17. A mechanical of spin-triplet superconductivity in Hubbard model on triangular lattice: application to UNi sub 2 Al sub 3

    CERN Document Server

    Nisikawa, Y

    2002-01-01

    We discuss the possibility of spin-triplet superconductivity in a two-dimensional Hubbard model on a triangular lattice within the third-order perturbation theory. When we vary the symmetry in the dispersion of the bare energy band from D sub 2 to D sub 6 , spin-singlet superconductivity in the D sub 2 -symmetric system is suppressed and we obtain spin-triplet superconductivity in near the D sub 6 -symmetric system. In this case, it is found that the vertex terms, which are not included in the interaction mediated by the spin fluctuation, are essential for realizing the spin-triplet pairing. We point out the possibility that obtained results correspond to the difference between the superconductivity of UNi sub 2 Al sub 3 and that of UPd sub 2 Al sub 3. (author)

  18. 3D Volume Rendering and 3D Printing (Additive Manufacturing).

    Science.gov (United States)

    Katkar, Rujuta A; Taft, Robert M; Grant, Gerald T

    2018-07-01

    Three-dimensional (3D) volume-rendered images allow 3D insight into the anatomy, facilitating surgical treatment planning and teaching. 3D printing, additive manufacturing, and rapid prototyping techniques are being used with satisfactory accuracy, mostly for diagnosis and surgical planning, followed by direct manufacture of implantable devices. The major limitation is the time and money spent generating 3D objects. Printer type, material, and build thickness are known to influence the accuracy of printed models. In implant dentistry, the use of 3D-printed surgical guides is strongly recommended to facilitate planning and reduce risk of operative complications. Copyright © 2018 Elsevier Inc. All rights reserved.

  19. 3D object-oriented image analysis in 3D geophysical modelling

    DEFF Research Database (Denmark)

    Fadel, I.; van der Meijde, M.; Kerle, N.

    2015-01-01

    Non-uniqueness of satellite gravity interpretation has traditionally been reduced by using a priori information from seismic tomography models. This reduction in the non-uniqueness has been based on velocity-density conversion formulas or user interpretation of the 3D subsurface structures (objects......) based on the seismic tomography models and then forward modelling these objects. However, this form of object-based approach has been done without a standardized methodology on how to extract the subsurface structures from the 3D models. In this research, a 3D object-oriented image analysis (3D OOA......) approach was implemented to extract the 3D subsurface structures from geophysical data. The approach was applied on a 3D shear wave seismic tomography model of the central part of the East African Rift System. Subsequently, the extracted 3D objects from the tomography model were reconstructed in the 3D...

  20. Laserscanning e 3D Modelling nell’archeologia urbana: lo scavo della chiesa di Sant’Agata al Carcere a Catania (Italia

    Directory of Open Access Journals (Sweden)

    L. Arcifa

    2010-05-01

    Full Text Available Urban archaeology undoubtedly represents the most problematic branch of archaeological research, due to the many problems of conservation and promotion of the evidence. A significant example is presented by the excavations carried out by the Superintendency for Cultural Goods of Catania in the church of “Sant’Agata al Carcere”, located in the heart of down town Catania. The most important discovery of the archaeological campaign was part of a ruined archaic wall in polygonal technique, located in the western side of the sacristy of the “Sant’Agata al Carcere” church. Furthermore, a late hellenistic votive deposit located within a pit, contained two small jars and a lidded stamnos, was discovered between the stones of the fallen wall. The excavations were performed during the restoration of the church. After the restoration, due to the special function of the building, it was necessary to quickly re-open the churches, thereby hiding the archaeological monuments from public view. In this perspective, a virtual museum project was implemented by an equipe of archaeologists and information technologists of the Archeomatica Project of Catania University, in order to display the important discoveries from the sacristy, which were covered up by the re-location of the floor in situ, applying both laser-scanner and 3D modelling techniques.

  1. Using 3D spatial correlations to improve the noise robustness of multi component analysis of 3D multi echo quantitative T2 relaxometry data.

    Science.gov (United States)

    Kumar, Dushyant; Hariharan, Hari; Faizy, Tobias D; Borchert, Patrick; Siemonsen, Susanne; Fiehler, Jens; Reddy, Ravinder; Sedlacik, Jan

    2018-05-12

    We present a computationally feasible and iterative multi-voxel spatially regularized algorithm for myelin water fraction (MWF) reconstruction. This method utilizes 3D spatial correlations present in anatomical/pathological tissues and underlying B1 + -inhomogeneity or flip angle inhomogeneity to enhance the noise robustness of the reconstruction while intrinsically accounting for stimulated echo contributions using T2-distribution data alone. Simulated data and in vivo data acquired using 3D non-selective multi-echo spin echo (3DNS-MESE) were used to compare the reconstruction quality of the proposed approach against those of the popular algorithm (the method by Prasloski et al.) and our previously proposed 2D multi-slice spatial regularization spatial regularization approach. We also investigated whether the inter-sequence correlations and agreements improved as a result of the proposed approach. MWF-quantifications from two sequences, 3DNS-MESE vs 3DNS-gradient and spin echo (3DNS-GRASE), were compared for both reconstruction approaches to assess correlations and agreements between inter-sequence MWF-value pairs. MWF values from whole-brain data of six volunteers and two multiple sclerosis patients are being reported as well. In comparison with competing approaches such as Prasloski's method or our previously proposed 2D multi-slice spatial regularization method, the proposed method showed better agreements with simulated truths using regression analyses and Bland-Altman analyses. For 3DNS-MESE data, MWF-maps reconstructed using the proposed algorithm provided better depictions of white matter structures in subcortical areas adjoining gray matter which agreed more closely with corresponding contrasts on T2-weighted images than MWF-maps reconstructed with the method by Prasloski et al. We also achieved a higher level of correlations and agreements between inter-sequence (3DNS-MESE vs 3DNS-GRASE) MWF-value pairs. The proposed algorithm provides more noise

  2. Propuesta de un proceso de enseñanza-aprendizaje para la asignatura Diseño de Software como proceso de software

    Directory of Open Access Journals (Sweden)

    Lund, María Inés

    2014-04-01

    Full Text Available La cátedra Diseño de Software se dicta actualmente en 4º año de las carreras del Departamento de Informática de la Facultad de Ciencias Exactas, Físicas y Naturales (FCEFN de la Universidad Nacional de San Juan (UNSJ. Esta materia se enfoca principalmente al Diseño Orientado a Objetos (DOO, brindando conceptos y conocimientos desarrollados en forma teórica y con un fuerte componente práctico, de todos los diagramas de modelado de software que provee el Lenguaje de Modelado Unificado (UML, con el fin de comprender acabadamente el objetivo que se persigue con cada uno de ellos y en qué casos es conveniente o útil aplicarlos. El presente trabajo se sustenta de la experiencia adquirida en la práctica aplicada para la enseñanza de DOO, utilizando UML para el modelado, donde las actividades prácticas abarcan desde el análisis hasta llegar a una propuesta de diseño de implementación. Se presenta un modelo de proceso de enseñanza aprendizaje, como proceso de software, y los artefactos utilizados para guiar al alumno en la resolución de un problema de desarrollo de software específico, utilizando para su especificación el lenguaje de metamodelado de procesos SPEM 2.0 y para generar el modelado del proceso de software la herramienta Eclipse Process Framework Composer (EPFC.

  3. ALS1 and ALS3 gene expression and biofilm formation in Candida albicans isolated from vulvovaginal candidiasis

    Directory of Open Access Journals (Sweden)

    Shahla Roudbarmohammadi

    2016-01-01

    Conclusion: The results attained indicated that there is an association between the expression of ALS1 and ALS3 genes and fluconazole resistance in C. albicans. A considerable percent of the isolates expressing the ALS1 and ALS3 genes may have contributed to their adherence to vagina and biofilm formation.

  4. Jihâd dalam Pandangan Muhammad ‘Abd al-Salâm Faraj

    Directory of Open Access Journals (Sweden)

    Abdul Muis Naharong

    2014-01-01

    Full Text Available Jihâd is one of the Islamic teachings which has been extensively discussed since the last few decades due to the increasing acts of violence perpetrated by some Muslims. This article tries to join this discussion by presenting Muh ammad ‘Abd al-Salâm Faraj’s concept of jihâd and his ideas of Islamic state and Caliphate by referring to his al-Farîd ah al-Ghâ’ibah (the Neglected Duty. We argue that Faraj’s basic perception of the Egyptian politics and society at the time shaped his whole concept of state and Caliphate. We hence contend that his proposal of jihâd is born out of his disappointment of the Egyptian government and even society as far as applying Islamic law is concerned. He uncompromisingly believed that the government and society are hypocrite and apostate for distancing themselves from the divine law of God. This belief prompted four members of Jihâd Organization to which Faraj belongs, to assassinate President Sadat in October 1981. By jihad, Faraj means fighting and confrontation against enemies even through bloodshed. And by enemies he means anyone who is not willing to apply God’s law on earth. The most controversial idea that Faraj has tried to pose is that jihâd is considered to the sixth pillar of Islam, which has to be carried out by each and every member of Muslim ummah.

  5. Synthesis, physical properties and band structure of non-magnetic Y{sub 3}AlC

    Energy Technology Data Exchange (ETDEWEB)

    Ghule, S.S. [Bharati Vidyapeeth Deemed University College of Engineering, Pune-Satara Road, Pune 411043 (India); Garde, C.S., E-mail: gardecs@gmail.com [Vishwakarma Institute of Information Technology, S. no. 2/3/4, Kondhwa(Bk), Pune 411048 (India); Ramakrishnan, S. [Tata Institute of Fundamental Research, Navynagar, Mumbai 400005 (India); Singh, S. [Indian Institute of Science Education and Research, Dr Homi Bhabha Road, Pashan, Pune 411008 (India); Rajarajan, A.K. [Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India); Laad, Meena [Symbiosis Institute of Technology (SIT), Symbiosis International University (SIU), Lavale, Pune 412115 (India)

    2016-10-01

    Y{sub 3}AlC has been synthesized by arc melting and subsequent annealing. Rietveld analysis of the powder x-ray diffraction (XRD) data confirms cubic Pm-3m structure. Electrical resistivity (ρ) of Y{sub 3}AlC exhibits metallic behaviour. No sign of superconductivity is observed down to the lowest measurement temperatures of 4.2 K in ρ, and 2 K in magnetic susceptibility (χ) and specific heat (C{sub p}) measurements. The value of the electronic specific heat coefficient γ is 1.36 mJ/K{sup 2} mol from which the density of states (DOS) at the Fermi energy (E{sub F}) is obtained as 0.57 states/eV.unit cell. The value of Debye temperature θ{sub D} is estimated to be 315 K. Electronic band structure calculations of Y{sub 3}AlC reveal a pseudo-gap in the DOS at E{sub F} leading to a small value of 0.5 states/eV unit cell which matches quite well with that obtained from γ. Non-zero value of the DOS indicates metallic behaviour as confirmed by our ρ data. Covalent and ionic bonding seem to co-exist with metallic bonding in Y{sub 3}AlC as indicated by van Arkel- Ketelaar triangle for Zintl-like systems.

  6. Influence of electric current on microstructure evolution in Ti/Al and Ti/TiAl{sub 3} during spark plasma sintering

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Y. [Department of Materials Science and Engineering, Institute of Materials Science, University of Connecticut, Storrs, CT 06269-3136 (United States); Haley, J. [Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616-5294 (United States); Kulkarni, K. [Department of Materials Science and Engineering, Indian Institute of Technology, Kanpur 208016, UP (India); Aindow, M. [Department of Materials Science and Engineering, Institute of Materials Science, University of Connecticut, Storrs, CT 06269-3136 (United States); Lavernia, E.J., E-mail: lavernia@ucdavis.edu [Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616-5294 (United States); Department of Chemical Engineering and Materials Science, University of California, Irvine, CA 92697-2575 (United States)

    2015-11-05

    The synthesis of γ-TiAl from elemental metals via solid-state reactive diffusion processing routes involves multiple reaction steps with the formation of various intermediate intermetallic compounds, starting with TiAl{sub 3} because this phase is favored kinetically. To understand the processes by which the TiAl{sub 3} intermediate is eliminated during synthesis of γ-TiAl alloy via spark plasma sintering (SPS), the reaction between Ti and TiAl{sub 3} during SPS was studied with emphasis on the effects of the applied electric current and starting TiAl{sub 3} microstructure on the reaction kinetics and the underlying diffusion mechanisms. The intermediate intermetallic phases Ti{sub 3}Al, TiAl and TiAl{sub 2} were formed between the Ti and TiAl{sub 3} upon SPS processing at 900 °C. The applied electric current did not alter the character of the phases formation in the Ti/TiAl{sub 3} system, but thermodynamic calculations suggest that the activation energy for the nucleation of TiAl{sub 2} is reduced significantly with an electric current flowing. Moreover, the kinetics of the reactions between Ti and TiAl{sub 3} were enhanced when the starting TiAl{sub 3} microstructure was refined. The electric field also had a more significant influence on the grain growth kinetics for TiAl{sub 2} and TiAl in powder blend compacts with refined microstructures. - Highlights: • Reaction between Ti and TiAl{sub 3} during spark plasma sintering was studied. • Refined starting TiAl{sub 3} microstructure enhanced the reactions kinetics. • The nucleation barrier of TiAl{sub 2} was reduced by the applied electric field. • The applied electric field restrained the grain growth of TiAl and TiAl{sub 2}.

  7. The Impacts of 3-D Earth Structure on GIA-Induced Crustal Deformation and Future Sea-Level Change in the Antarctic

    Science.gov (United States)

    Powell, E. M.; Hay, C.; Latychev, K.; Gomez, N. A.; Mitrovica, J. X.

    2017-12-01

    Glacial Isostatic Adjustment (GIA) models used to constrain the extent of past ice sheets and viscoelastic Earth structure, or to correct geodetic and geological observables for ice age effects, generally only consider depth-dependent variations in Earth viscosity and lithospheric structure. A et al. [2013] argued that 3-D Earth structure could impact GIA observables in Antarctica, but concluded that the presence of such structure contributes less to GIA uncertainty than do differences in Antarctic deglaciation histories. New seismic and geological evidence, however, indicates the Antarctic is underlain by complex, high amplitude variability in viscoelastic structure, including a low viscosity zone (LVZ) under West Antarctica. Hay et al. [2016] showed that sea-level fingerprints of modern melting calculated using such Earth models differ from those based on elastic or 1-D viscoelastic Earth models within decades of melting. Our investigation is motivated by two questions: (1) How does 3-D Earth structure, especially this LVZ, impact observations of GIA-induced crustal deformation associated with the last deglaciation? (2) How will 3-D Earth structure affect predictions of future sea-level rise in Antarctica? We compute the gravitationally self-consistent sea level, uplift, and gravity changes using the finite volume treatment of Latychev et al. [2005]. We consider four viscoelastic Earth models: a global 1-D model; a regional, West Antarctic-like 1-D model; a 3-D model where the lithospheric thickness varies laterally; and a 3-D model where both viscosity and lithospheric thickness vary laterally. For our Last Glacial Maximum to present investigations we employ ICE6g [Peltier et al., 2015]. For our present-future investigations we consider a melt scenario consistent with GRACE satellite gravity derived solutions [Harig et al., 2015]. Our calculations indicate that predictions of crustal deformations due to both GIA and ongoing melting are strongly influenced by 3-D

  8. Synthesis and properties of γ-Ga2O3-Al2O3 solid solutions

    Science.gov (United States)

    Afonasenko, T. N.; Leont'eva, N. N.; Talzi, V. P.; Smirnova, N. S.; Savel'eva, G. G.; Shilova, A. V.; Tsyrul'nikov, P. G.

    2017-10-01

    The textural and structural properties of mixed oxides Ga2O3-Al2O3, obtained via impregnating γ-Al2O3 with a solution of Ga(NO3)3 and subsequent heat treatment, are studied. According to the results from X-ray powder diffraction, gallium ions are incorporated into the structure of aluminum oxide to form a solid solution of spinel-type γ-Ga2O3-Al2O3 up to a Ga2O3 content of 50 wt % of the total weight of the sample, accompanied by a reduction in the specific surface area, volume, and average pore diameter. It is concluded that when the Ga2O3 content exceeds 50 wt %, the β-Ga2O3 phase is observed along with γ-Ga2O3-Al2O3 solid solution. 71Ga and 27Al NMR spectroscopy shows that gallium replaces aluminum atoms from the tetrahedral position to the octahedral coordination in the structure of γ-Ga2O3-Al2O3.

  9. Crystal structure and luminescence properties of a novel red-emitting phosphor BaAlBO{sub 3}F{sub 2}:Eu{sup 3+}

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Wanping, E-mail: cwp0918@aliyun.com; Zhou, Ahong; Liu, Yan; Dai, Xiaoyan; Yang, Xin

    2014-12-15

    A series of novel red-emitting phosphors BaAlBO{sub 3}F{sub 2}:xEu{sup 3+} (0.001≤x≤0.08) were first synthesized via a high temperature solid-state reaction. X-ray diffraction and photoluminescence spectroscopy were used to characterize the crystal structure and photoluminescence properties of the phosphor, respectively. The phosphor can be effectively excited with a 395 nm light, and shows a dominant {sup 5}D{sub 0}−{sup 7}F{sub 2} emission with chromatic coordination of 0.628 and 0.372. The optimal doping concentration is about 0.04. Rietveld refinement results and the luminescence behavior of Eu{sup 3+} indicate that the Eu{sup 3+} ion occupies a C{sub 3} symmetry site, and the host BaAlBO{sub 3}F{sub 2} has a hexagonal structure with P-6 space group. In addition, the phosphor could be a potential candidate as red-emitting phosphor for application in white light-emitting diode. - Graphical abstract: The luminescence behavior and Rietveld refinement of BaAlBO{sub 3}F{sub 2}:Eu{sup 3+} indicate that the red-emitting phosphor has potential application in white LED and the host has a hexagonal structure with P-6 space group. - Highlights: • A novel red-emitting phosphor BaAlBO{sub 3}F{sub 2}:Eu{sup 3+} is first synthesized. • The crystal structure of BaAlBO{sub 3}F{sub 2} is confirmed. • The phosphor shows potential application in white LED.

  10. First-principles calculations of 5d atoms doped hexagonal-AlN sheets: Geometry, magnetic property and the influence of symmetry and symmetry-breaking on the electronic structure

    International Nuclear Information System (INIS)

    Zhang Zhao-Fu; Zhou Tie-Ge; Zhao Hai-Yang; Wei Xiang-Lei

    2014-01-01

    The geometry, electronic structure and magnetic property of the hexagonal AlN (h-AlN) sheet doped by 5d atoms (Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au and Hg) are investigated by first-principles calculations based on the density functional theory. The influence of symmetry and symmetry-breaking is also studied. There are two types of local symmetries of the doped systems: C 3v and D 3h . The symmetry will deviate from exact C 3v and D 3h for some particular dopants after optimization. The total magnetic moments of the doped systems are 0μ B for Lu, Ta and Ir; 1μ B for Hf, W, Pt and Hg; 2μ B for Re and Au; and 3μ B for Os and Al-vacancy. The total densities of state are presented, where impurity energy levels exist. The impurity energy levels and total magnetic moments can be explained by the splitting of 5d orbitals or molecular orbitals under different symmetries. (condensed matter: structural, mechanical, and thermal properties)

  11. Highly Efficient Four-Wave Mixing in an AlGaAs-On-Insulator (AlGaAsOI) Nano-Waveguide

    DEFF Research Database (Denmark)

    Pu, Minhao; Ottaviano, Luisa; Semenova, Elizaveta

    2015-01-01

    We propose an AlGaAs-on-insulator platform for nonlinear integrated photonics. We demonstrate highly efficient four-wave mixing in a 3-mm long AlGaAs-on-insulator nanowaveguide. A conversion efficiency of -21.1 dB is obtained with only a 45-mW pump......We propose an AlGaAs-on-insulator platform for nonlinear integrated photonics. We demonstrate highly efficient four-wave mixing in a 3-mm long AlGaAs-on-insulator nanowaveguide. A conversion efficiency of -21.1 dB is obtained with only a 45-mW pump...

  12. Synthesis of Mg–Al2O3 nanocomposites by mechanical alloying

    Internation