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Sample records for aespoe pillar stability

Aespoe Pillar Stability Experiment. Modelling of fracture development of APSE by FRACOD

International Nuclear Information System (INIS)

Rinne, Mikael; Baotang Shen; Lee, Hee-Suk

2004-03-01

An in-situ experiment has started at Aespoe HRL to investigate the stability of a pillar between two closely located boreholes of deposition hole scale. This full-scale experiment is named the Aespoe Pillar Stability Experiment (APSE). One of the holes will be pressurized with 0.8 MPa water pressure to simulate confinement by backfill. Thermal stresses will be applied in the pillar by the use of electric heaters to reach the spalling conditions. To quantify the degree of damage during the experiment, an Acoustic Emission (AE) system will be used and strain measurements will be installed. FRACOD is a two dimensional BEM/DDM code for fracturing analysis in rock material. Here it has been used to model the rock mass response during the planned sequences of excavation-confinement-heating. The models predict the stress and displacement fields, fracture initiation and propagation, coalescence and the final failure of the rock mass. The presences of pre-existing fractures, which may have significant influence on the pillar behaviour, have also been considered in the modelling. This report summarises the modelling work using FRACOD to simulate the various experimental stages
Aespoe Pillar Stability Experiment. Final coupled 3D thermo-mechanical modeling. Preliminary particle mechanical modeling

International Nuclear Information System (INIS)

Wanne, Toivo; Johansson, Erik; Potyondy, David

2004-02-01

SKB is planning to perform a large-scale pillar stability experiment called APSE (Aespoe Pillar Stability Experiment) at Aespoe HRL. The study is focused on understanding and control of progressive rock failure in hard crystalline rock and damage caused by high stresses. The elastic thermo-mechanical modeling was carried out in three dimensions because of the complex test geometry and in-situ stress tensor by using a finite-difference modeling software FLAC3D. Cracking and damage formation were modeled in the area of interest (pillar between two large scale holes) in two dimensions by using the Particle Flow Code (PFC), which is based on particle mechanics. FLAC and PFC were coupled to minimize the computer resources and the computing time. According to the modeling the initial temperature rises from 15 deg C to about 65 deg C in the pillar area during the heating period of 120 days. The rising temperature due to thermal expansion induces stresses in the pillar area and after 120 days heating the stresses have increased about 33% from the excavation induced maximum stress of 150 MPa to 200 MPa in the end of the heating period. The results from FLAC3D model showed that only regions where the crack initiation stress has exceeded were identified and they extended to about two meters down the hole wall. These could be considered the areas where damage may occur during the in-situ test. When the other hole is pressurized with a 0.8 MPa confining pressure it yields that 5 MPa more stress is needed to damage the rock than without confining pressure. This makes the damaged area in some degree smaller. High compressive stresses in addition to some tensile stresses might induce some AE (acoustic emission) activity in the upper part of the hole from the very beginning of the test and are thus potential areas where AE activities may be detected. Monitoring like acoustic emissions will be measured during the test execution. The 2D coupled PFC-FLAC modeling indicated that
Aespoe Pillar Stability Experiment. Final coupled 3D thermo-mechanical modeling. Preliminary particle mechanical modeling

Energy Technology Data Exchange (ETDEWEB)

Wanne, Toivo; Johansson, Erik; Potyondy, David [Saanio and Riekkola Oy, Helsinki (Finland)

2004-02-01

SKB is planning to perform a large-scale pillar stability experiment called APSE (Aespoe Pillar Stability Experiment) at Aespoe HRL. The study is focused on understanding and control of progressive rock failure in hard crystalline rock and damage caused by high stresses. The elastic thermo-mechanical modeling was carried out in three dimensions because of the complex test geometry and in-situ stress tensor by using a finite-difference modeling software FLAC3D. Cracking and damage formation were modeled in the area of interest (pillar between two large scale holes) in two dimensions by using the Particle Flow Code (PFC), which is based on particle mechanics. FLAC and PFC were coupled to minimize the computer resources and the computing time. According to the modeling the initial temperature rises from 15 deg C to about 65 deg C in the pillar area during the heating period of 120 days. The rising temperature due to thermal expansion induces stresses in the pillar area and after 120 days heating the stresses have increased about 33% from the excavation induced maximum stress of 150 MPa to 200 MPa in the end of the heating period. The results from FLAC3D model showed that only regions where the crack initiation stress has exceeded were identified and they extended to about two meters down the hole wall. These could be considered the areas where damage may occur during the in-situ test. When the other hole is pressurized with a 0.8 MPa confining pressure it yields that 5 MPa more stress is needed to damage the rock than without confining pressure. This makes the damaged area in some degree smaller. High compressive stresses in addition to some tensile stresses might induce some AE (acoustic emission) activity in the upper part of the hole from the very beginning of the test and are thus potential areas where AE activities may be detected. Monitoring like acoustic emissions will be measured during the test execution. The 2D coupled PFC-FLAC modeling indicated that
Aespoe Pillar Stability Experiment. Final 2D coupled thermo-mechanical modelling

Energy Technology Data Exchange (ETDEWEB)

Fredriksson, Anders; Staub, Isabelle; Outters, Nils [Golder Associates AB, Uppsala (Sweden)

2004-02-01

A site scale Pillar Stability Experiment is planned in the Aespoe Hard Rock Laboratory. One of the experiment's aims is to demonstrate the possibilities of predicting spalling in the fractured rock mass. In order to investigate the probability and conditions for spalling in the pillar 'prior to experiment' numerical simulations have been undertaken. This report presents the results obtained from 2D coupled thermo-mechanical numerical simulations that have been done with the Finite Element based programme JobFem. The 2D numerical simulations were conducted at two different depth levels, 0.5 and 1.5 m below tunnel floor. The in situ stresses have been confirmed with convergence measurements during the excavation of the tunnel. After updating the mechanical and thermal properties of the rock mass the final simulations have been undertaken. According to the modelling results the temperature in the pillar will increase from the initial 15.2 deg up to 58 deg after 120 days of heating. Based on these numerical simulations and on the thermal induced stresses the total stresses are expected to exceed 210 MPa at the border of the pillar for the level at 0.5 m below tunnel floor and might reach 180-182 MPa for the level at 1.5 m below tunnel floor. The stresses are slightly higher at the border of the confined hole. Upon these results and according to the rock mechanical properties the Crack Initiation Stress is exceeded at the border of the pillar already after the excavation phase. These results also illustrate that the Crack Damage Stress is exceeded only for the level at 0.5 m below tunnel floor and after at least 80 days of heating. The interpretation of the results shows that the required level of stress for spalling can be reached in the pillar.
Aespoe Pillar Stability Experiment. Geology and mechanical properties of the rock in TASQ

Energy Technology Data Exchange (ETDEWEB)

Staub, Isabelle [Golder Associates AB, Uppsala (Sweden); Andersson, J. Christer; Magnor, Bjoern

2004-03-01

An extensive characterization programme has been performed in the drift, TASQ, excavated for the Aespoe Pillar Stability Experiment, APSE, including the rock volume that will host the experiment pillar between the two deposition holes. The two major objectives with the characterization has been to 1) derive material properties for the final numerical modelling of the experiment and 2) to ensure that the pillar location is suitable from a structural and rock mechanical point of view. In summary the following activities have been performed: Geological mapping of the drift, the pilot holes cores and deposition hole DQ0066G01. 3D-visualisation of the geological mapping in the experiment (pillar) volume of TASQ. Convergence measurements during the excavation and back calculation of the results for determination of the stress tensor and the rock mass Young's modulus. Laboratory tests on core samples from the 15{phi}76 mm core boreholes drilled around the pillar volume for determination of: compressive strength, thermal properties and fracture properties. P-wave velocity measurements on core samples and between boreholes for estimation of the excavation damaged zone and rock mass properties. The geological mapping and the 3D-visualisation gives a good description of the TASQ drift in general and the experiment volume in the drift in particular. The fracturing of the drift follows the pattern of the rest of Aespoe. Three fracture sets have been mapped in TASQ. The major fracture set is sub-vertical and trending NW, in principle parallel to {sigma}{sub 1}. This set is the most conductive at Aespoe and is the only water bearing set in TASQ. A second less pronounced set is trending NE, parallel to TASQ, and is also sub-vertical. The third set is sub-horizontal. It is interesting to note that the third set is the only one that almost completely consists of sealed fractures. The first two sets have mostly open fractures. One unique feature in the drift is a heavily
Aespoe Pillar Stability Experiment. Geology and mechanical properties of the rock in TASQ

International Nuclear Information System (INIS)

Staub, Isabelle; Andersson, J. Christer; Magnor, Bjoern

2004-03-01

An extensive characterization programme has been performed in the drift, TASQ, excavated for the Aespoe Pillar Stability Experiment, APSE, including the rock volume that will host the experiment pillar between the two deposition holes. The two major objectives with the characterization has been to 1) derive material properties for the final numerical modelling of the experiment and 2) to ensure that the pillar location is suitable from a structural and rock mechanical point of view. In summary the following activities have been performed: Geological mapping of the drift, the pilot holes cores and deposition hole DQ0066G01. 3D-visualisation of the geological mapping in the experiment (pillar) volume of TASQ. Convergence measurements during the excavation and back calculation of the results for determination of the stress tensor and the rock mass Young's modulus. Laboratory tests on core samples from the 15Φ76 mm core boreholes drilled around the pillar volume for determination of: compressive strength, thermal properties and fracture properties. P-wave velocity measurements on core samples and between boreholes for estimation of the excavation damaged zone and rock mass properties. The geological mapping and the 3D-visualisation gives a good description of the TASQ drift in general and the experiment volume in the drift in particular. The fracturing of the drift follows the pattern of the rest of Aespoe. Three fracture sets have been mapped in TASQ. The major fracture set is sub-vertical and trending NW, in principle parallel to σ 1 . This set is the most conductive at Aespoe and is the only water bearing set in TASQ. A second less pronounced set is trending NE, parallel to TASQ, and is also sub-vertical. The third set is sub-horizontal. It is interesting to note that the third set is the only one that almost completely consists of sealed fractures. The first two sets have mostly open fractures. One unique feature in the drift is a heavily oxidized brittle
Aespoe Pillar Stability Experiment. Acoustic emission and ultrasonic monitoring

Energy Technology Data Exchange (ETDEWEB)

Haycox, Jon; Pettitt, Will; Young, R. Paul [Applied Seismology Consultants Ltd., Shrewsbury (United Kingdom)

2005-12-15

This report describes the results from acoustic emission (AE) and ultrasonic monitoring of the Aespoe Pillar Stability Experiment (APSE) at SKB's Hard Rock Laboratory (HRL), Sweden. The APSE is being undertaken to demonstrate the current capability to predict spalling in a fractured rock mass using numerical modelling techniques, and to demonstrate the effect of backfill and confining pressure on the propagation of micro-cracks in rock adjacent to deposition holes within a repository. An ultrasonic acquisition system has provided acoustic emission and ultrasonic survey monitoring throughout the various phases of the experiment. Results from the entire data set are provided with this document so that they can be effectively compared to several numerical modelling studies, and to mechanical and thermal measurements conducted around the pillar volume, in an 'integrated analysis' performed by SKB staff. This document provides an in-depth summary of the AE and ultrasonic survey results for future reference. The pillar has been produced by excavating two 1.8 m diameter deposition holes 1 m apart. These were bored in 0.8 m steps using a Tunnel Boring Machine specially adapted for vertical drilling. The first deposition hole was drilled in December 2003. Preceding this a period of background monitoring was performed so as to obtain a datum for the results. The hole was then confined to 0.7 MPa internal over pressure using a specially designed water-filled bladder. The second deposition hole was excavated in March 2004. Heating of the pillar was performed over a two month period between ending in July 2004, when the confined deposition hole was slowly depressurised. Immediately after depressurisation the pillar was allowed to cool with cessation of monitoring occurring a month later. A total of 36,676 AE triggers were recorded over the reporting period between 13th October 2003 and 14th July 2004. Of these 15,198 have produced AE locations. The AE data set
Aespoe Pillar Stability Experiment. Acoustic emission and ultrasonic monitoring

International Nuclear Information System (INIS)

Haycox, Jon; Pettitt, Will; Young, R. Paul

2005-11-01

This report describes the results from acoustic emission (AE) and ultrasonic monitoring of the Aespoe Pillar Stability Experiment (APSE) at SKB's Hard Rock Laboratory (HRL), Sweden. The APSE is being undertaken to demonstrate the current capability to predict spalling in a fractured rock mass using numerical modelling techniques, and to demonstrate the effect of backfill and confining pressure on the propagation of micro-cracks in rock adjacent to deposition holes within a repository. An ultrasonic acquisition system has provided acoustic emission and ultrasonic survey monitoring throughout the various phases of the experiment. Results from the entire data set are provided with this document so that they can be effectively compared to several numerical modelling studies, and to mechanical and thermal measurements conducted around the pillar volume, in an 'integrated analysis' performed by SKB staff. This document provides an in-depth summary of the AE and ultrasonic survey results for future reference. The pillar has been produced by excavating two 1.8 m diameter deposition holes 1 m apart. These were bored in 0.8 m steps using a Tunnel Boring Machine specially adapted for vertical drilling. The first deposition hole was drilled in December 2003. Preceding this a period of background monitoring was performed so as to obtain a datum for the results. The hole was then confined to 0.7 MPa internal over pressure using a specially designed water-filled bladder. The second deposition hole was excavated in March 2004. Heating of the pillar was performed over a two month period between ending in July 2004, when the confined deposition hole was slowly depressurised. Immediately after depressurisation the pillar was allowed to cool with cessation of monitoring occurring a month later. A total of 36,676 AE triggers were recorded over the reporting period between 13th October 2003 and 14th July 2004. Of these 15,198 have produced AE locations. The AE data set shows an intense
Numerical simulations and analysis for the Aespoe pillar stability experiment. Part 1. Continuum based approaches using finite element method and comparison with other analysis model

International Nuclear Information System (INIS)

Chijimatsu, Masakazu; Koyama, Tomofumi; Shimizu, Hiroyuki; Nakama, Shigeo; Fujita, Tomoo

2013-01-01

DECOVALEX-2011 is an international cooperation project for enhancing the numerical models of radioactive waste repositories. In DECOVALEX-2011 project, the failure mechanism during excavation and heating processes observed in the Aespoe pillar stability experiment, which was carried out at the Aespoe Hard Rock Laboratory by the Swedish Nuclear Fuel and Waste Management Company, were simulated using Finite Element Method. When the calibrated parameters were used, simulation results agree qualitatively well with the experimental results. Therefore, it can be said that the spalling phenomenon is expressible even by the application with the continuum model by the use of the suitable parameters. (author)
Aespoe Pillar Stability Experiment. Summary of preparatory work and predictive modelling

International Nuclear Information System (INIS)

Andersson, J. Christer

2004-11-01

The Aespoe Pillar Stability Experiment, APSE, is a large scale rock mechanics experiment for research of the spalling process and the possibility for numerical modelling of it. The experiment can be summarized in three objectives: Demonstrate the current capability to predict spalling in a fractured rock mass; Demonstrate the effect of backfill (confining pressure) on the rock mass response; and Comparison of 2D and 3D mechanical and thermal predicting capabilities. This report is a summary of the works that has been performed in the experiment prior to the heating of the rock mass. The major activities that have been performed and are discussed herein are: 1) The geology of the experiment drift in general and the experiment volume in particular. 2) The design process of the experiment and thoughts behind some of the important decisions. 3) The monitoring programme and the supporting constructions for the instruments. 4) The numerical modelling, approaches taken and a summary of the predictions. In the end of the report there is a comparison of the results from the different models. Included is also a comparison of the time needed for building, realizing and make changes in the different models
Aespoe Pillar Stability Experiment. Final experiment design, monitoring results and observations

Energy Technology Data Exchange (ETDEWEB)

Andersson, Christer [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden); Eng, Anders [Acuo Engineering AB, Linkoeping (Sweden)

2005-12-15

The field part of the Aespoe Pillar Stability Experiment at the Aespoe Hard Rock Laboratory (HRL) was finished in 2004. The experiment was designed to induce and monitor the process of brittle failure, spalling, in a fractured rock mass under controlled conditions. The field part was successfully conducted and a large data set was obtained. This report presents the final design of the experiment, the results of the monitoring, and the observations made during the spalling process and when the spalled rock was removed. When heating of the rock was initiated the rock responded quickly. After only a few days the spalling process was activated in the notch, as indicated by the acoustic emission system, and shortly thereafter displacement readings were recorded. Contraction (radial expansion) of the rock was recorded by several instruments before the notch reached the instrument levels. This contraction is probably the result of a 3D re-distribution of the stresses. The temperature increase in the system was both slower and reached a steady state much earlier than predicted by the numerical models. The propagation of the notch was therefore halted after approximately one month of heating. The power to the electrical heaters was therefore doubled. Spalling then started up again, and in one month's time it had propagated to a depth of approximately five metres in the hole. A second steady state was now reached, but this time the heater power was kept constant for a while to let the rock settle before the confinement pressure was reduced from 700 kPa to 0 in decrements of 50 kPa. The rock mass response to the pressure drop was very limited until the pressure was lowered to approximately 200 kPa (the atmospheric pressure is not included in the given pressure values). Large displacements and a high acoustic emission hit frequency were then measured in the open hole. After the de-pressurization of the confined hole, the heaters were left on for approximately one week
Long-Term Stability Evaluation and Pillar Design Criterion for Room-and-Pillar Mines

Directory of Open Access Journals (Sweden)

Yang Yu

2017-10-01

Full Text Available The collapse of abandoned room-and-pillar mines is often violent and unpredictable. Safety concerns often resulted in mine closures with no post-mining stability evaluations. As a result, large amounts of land resources over room-and-pillar mines are wasted. This paper attempts to establish an understanding of the long-term stability issues of goafs (abandoned mines. Considering progressive pillar failures and the effect of single pillar failure on surrounding pillars, this paper proposes a pillar peeling model to evaluate the long-term stability of coal mines and the associated criteria for evaluating the long-term stability of room-and-pillar mines. The validity of the peeling model was verified by numerical simulation, and field data from 500 pillar cases from China, South Africa, and India. It is found that the damage level of pillar peeling is affected by the peel angle and pillar height and is controlled by the pillar width–height ratio.
Aespoe Hard Rock Laboratory. Annual Report 2001

International Nuclear Information System (INIS)

2002-09-01

and the work within Task 6, Performance Assessment Modelling Using Site Characterisation Data, has started. The Aespoe HRL makes it possible to demonstrate and perform full-scale tests of the function of different components of the repository system that are important for the performance and the long term safety of a repository. It is also important to show that high quality can be achieved in design, construction, and operation of the repository. To fulfil these tasks several projects are performed, e. g. Demonstration of Repository Technology, Prototype Repository, Backfill and Plug Test, Canister Retrieval Test, Long Term Tests of Buffer Material, and Pillar Stability Experiment. The focus of the Task Force on Engineered Barrier Systems during 2001 has been on modelling of THM processes taking place in the bentonite buffer during saturation. This is also the prime modelling objective in the Prototype Repository and the work has therefore been conducted under the umbrella of the Prototype Repository. The operation of the facility has worked smoothly. A number of new projects concerning safety, security and reliability have been initiated, started or completed during 2001. To meet the need for additional office space to host the staff of the site investigation in Oskarshamn a temporary barrack was built and an application for planning permission for additional extension of the Aespoe surface facility has been submitted. An extensive rock reinforcement programme was finalised in February 2001. The programme comprises complementary shotcreting, injections, bolting and mounting of mesh. Replacement of corroded light equipment in the deeper half of the tunnel, 220-450 m level, and replacement of sealing on the water pipes in the shaft, 350-450 m level, have been completed. The main goal for the information group is to create public acceptance for SKB's activities in co-operation with other departments at SKB. This is achieved by presenting information about SKB, the
Aespoe Hard Rock Laboratory. Annual Report 2001

Energy Technology Data Exchange (ETDEWEB)

NONE

2002-09-01

during 2001 and the work within Task 6, Performance Assessment Modelling Using Site Characterisation Data, has started. The Aespoe HRL makes it possible to demonstrate and perform full-scale tests of the function of different components of the repository system that are important for the performance and the long term safety of a repository. It is also important to show that high quality can be achieved in design, construction, and operation of the repository. To fulfil these tasks several projects are performed, e. g. Demonstration of Repository Technology, Prototype Repository, Backfill and Plug Test, Canister Retrieval Test, Long Term Tests of Buffer Material, and Pillar Stability Experiment. The focus of the Task Force on Engineered Barrier Systems during 2001 has been on modelling of THM processes taking place in the bentonite buffer during saturation. This is also the prime modelling objective in the Prototype Repository and the work has therefore been conducted under the umbrella of the Prototype Repository. The operation of the facility has worked smoothly. A number of new projects concerning safety, security and reliability have been initiated, started or completed during 2001. To meet the need for additional office space to host the staff of the site investigation in Oskarshamn a temporary barrack was built and an application for planning permission for additional extension of the Aespoe surface facility has been submitted. An extensive rock reinforcement programme was finalised in February 2001. The programme comprises complementary shotcreting, injections, bolting and mounting of mesh. Replacement of corroded light equipment in the deeper half of the tunnel, 220-450 m level, and replacement of sealing on the water pipes in the shaft, 350-450 m level, have been completed. The main goal for the information group is to create public acceptance for SKB's activities in co-operation with other departments at SKB. This is achieved by presenting information about
Experiments at the Aespoe Hard Rock Laboratory

International Nuclear Information System (INIS)

2004-12-01

A dress rehearsal is being held in preparation for the construction of a deep repository for spent nuclear fuel at SKB's underground Hard Rock Laboratory (HRL) on Aespoe, outside Oskarshamn. Here we can test different technical solutions on a full scale and in a realistic environment. The Aespoe HRL is also used for field research. We are conducting a number of experiments here in collaboration with Swedish and international experts. In the Zedex experiment we have compared how the rock is affected around a drill-and-blast tunnel versus a bored tunnel. In a new experiment we will investigate how much the rock can take. A narrow pillar between two boreholes will be loaded to the point that the rock's ultimate strength is exceeded (Aespoe Pillar Stability Experiment). In the Demo Test we are demonstrating emplacement of the copper canisters and the surrounding bentonite in the deposition holes. In the Prototype Repository we study what long-term changes occur in the barriers under the conditions prevailing in a deep repository. Horizontal deposition: Is it possible to deposit the canisters horizontally without compromising safety? Backfill and Plug Test: The tunnels in the future deep repository for spent nuclear fuel will be filled with clay and crushed rock and then plugged. Canister Retrieval Test: If the deep repository should not perform satisfactorily for some reason, we want to be able to retrieve the spent fuel. The Lot test is intended to show how the bentonite behaves in an environment similar to that in the future deep repository. The purpose of the TBT test is to determine how the bentonite clay in the buffer is affected by high temperatures. Two-phase flow means that liberated gas in the groundwater flows separately in the fractures in the rock. This reduces the capacity of the rock to conduct water. Lasgit: By pressurizing a canister with helium, we can measure how the gas moves through the surrounding buffer. Colloid Project: Can very small particles
Characterisation, design and execution of two grouting fans at 450 m level, Aespoe HRL

Energy Technology Data Exchange (ETDEWEB)

Emmelin, Ann [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden); Eriksson, Magnus [Royal Inst. of Technology, Stockholm (Sweden); Fransson, Aasa [Chalmers Univ. of Technology, Goeteborg (Sweden)

2004-09-01

During June 2003 a grouting field experiment was carried out at Aespoe HRL, in connection with the construction of a tunnel (TASQ) for the Aespoe Pillar Stability Experiment (APSE). The tunnel is situated in connection to the elevator shaft landing at 450 m depth and runs in direction N/E. The grouting was carried out as part of the ordinary construction work, but was accompanied by extra investigations and analyses during operations and an active adaptation of a basic grouting design to the encountered conditions. The main objectives of this set-up were to Investigate what can be achieved with best available technology, material and knowledge under the current conditions, i.e. a relatively tight crystalline rock mass at great depth; Collect data and evaluate theories resulting from previous research projects on characterisation and predictions on grout spread; Collect data to further develop those above mentioned theories; Contribute to the achievement of good conditions at the experimental site for the pillar stability experiments. The characterization method is based on analyses of stepwise investigations consisting of investigations in an initially drilled core-drill hole followed by probe and grouting boreholes with pressure-build-up tests and measuring of inflow during drilling, all aiming at identifying the singular fractures that are to be sealed. The decision about grouting design is based on the successively up-dated rock description from the characterization and iterative selection and testing of grouting design and grout in a numeric model, resulting in an expected grout spread and sealing effect. Based on investigations and analysis of results from investigations of a core-drilled hole at the site, a basic design was set up, together with conditions for application. Probe boreholes covering the first anticipated fan gave substantially larger inflows than expected, and subsequently the design was changed. A first round was drilled and grouted, sealing
Characterisation, design and execution of two grouting fans at 450 m level, Aespoe HRL

International Nuclear Information System (INIS)

Emmelin, Ann; Eriksson, Magnus; Fransson, Aasa

2004-09-01

During June 2003 a grouting field experiment was carried out at Aespoe HRL, in connection with the construction of a tunnel (TASQ) for the Aespoe Pillar Stability Experiment (APSE). The tunnel is situated in connection to the elevator shaft landing at 450 m depth and runs in direction N/E. The grouting was carried out as part of the ordinary construction work, but was accompanied by extra investigations and analyses during operations and an active adaptation of a basic grouting design to the encountered conditions. The main objectives of this set-up were to Investigate what can be achieved with best available technology, material and knowledge under the current conditions, i.e. a relatively tight crystalline rock mass at great depth; Collect data and evaluate theories resulting from previous research projects on characterisation and predictions on grout spread; Collect data to further develop those above mentioned theories; Contribute to the achievement of good conditions at the experimental site for the pillar stability experiments. The characterization method is based on analyses of stepwise investigations consisting of investigations in an initially drilled core-drill hole followed by probe and grouting boreholes with pressure-build-up tests and measuring of inflow during drilling, all aiming at identifying the singular fractures that are to be sealed. The decision about grouting design is based on the successively up-dated rock description from the characterization and iterative selection and testing of grouting design and grout in a numeric model, resulting in an expected grout spread and sealing effect. Based on investigations and analysis of results from investigations of a core-drilled hole at the site, a basic design was set up, together with conditions for application. Probe boreholes covering the first anticipated fan gave substantially larger inflows than expected, and subsequently the design was changed. A first round was drilled and grouted, sealing
Experiments at the Aespoe Hard Rock Laboratory[Information for the general public

Energy Technology Data Exchange (ETDEWEB)

NONE

2004-12-01

A dress rehearsal is being held in preparation for the construction of a deep repository for spent nuclear fuel at SKB's underground Hard Rock Laboratory (HRL) on Aespoe, outside Oskarshamn. Here we can test different technical solutions on a full scale and in a realistic environment. The Aespoe HRL is also used for field research. We are conducting a number of experiments here in collaboration with Swedish and international experts. In the Zedex experiment we have compared how the rock is affected around a drill-and-blast tunnel versus a bored tunnel. In a new experiment we will investigate how much the rock can take. A narrow pillar between two boreholes will be loaded to the point that the rock's ultimate strength is exceeded (Aespoe Pillar Stability Experiment). In the Demo Test we are demonstrating emplacement of the copper canisters and the surrounding bentonite in the deposition holes. In the Prototype Repository we study what long-term changes occur in the barriers under the conditions prevailing in a deep repository. Horizontal deposition: Is it possible to deposit the canisters horizontally without compromising safety? Backfill and Plug Test: The tunnels in the future deep repository for spent nuclear fuel will be filled with clay and crushed rock and then plugged. Canister Retrieval Test: If the deep repository should not perform satisfactorily for some reason, we want to be able to retrieve the spent fuel. The Lot test is intended to show how the bentonite behaves in an environment similar to that in the future deep repository. The purpose of the TBT test is to determine how the bentonite clay in the buffer is affected by high temperatures. Two-phase flow means that liberated gas in the groundwater flows separately in the fractures in the rock. This reduces the capacity of the rock to conduct water. Lasgit: By pressurizing a canister with helium, we can measure how the gas moves through the surrounding buffer. Colloid Project: Can very small
Causes of falls of hangingwall over gullies adjacent to stabilizing strike pillars

CSIR Research Space (South Africa)

Turner, PA

1987-08-01

Full Text Available This report discusses the occurrence of falls of ground in strike gullies. Falls of hangingwall over strike gullies on the up-dip side of strike stabilizing pillars in longwall mining systems were investigated. Gullies were examined in both...
Aespoe hard rock laboratory. Annual report 2010

Energy Technology Data Exchange (ETDEWEB)

2011-02-15

The Aespoe Hard Rock Laboratory (HRL) is an important part of SKB's work with the design and construction of a deep geological repository for the final disposal of spent nuclear fuel. Aespoe HRL is located in the Simpevarp area in the municipality of Oskarshamn. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create opportunities for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995 and considerable international interest has been shown in its research, as well as in the development and demonstration tasks. A summary of the work performed at Aespoe HRL during 2010 is given below

Aespoe Hard Rock Laboratory. Annual Report 2011

Energy Technology Data Exchange (ETDEWEB)

NONE

2012-03-15

The Aespoe Hard Rock Laboratory (HRL) is an important part of SKB's work with the design and construction of a deep geological repository for the final disposal of spent nuclear fuel. Aespoe HRL is located in the Simpevarp area in the municipality of Oskarshamn. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create opportunities for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995 and considerable international interest has been shown in its research, as well as in the development and demonstration tasks. A summary of the work performed at Aespoe HRL during 2011 is given below.
Aespoe hard rock laboratory. Annual report 2010

International Nuclear Information System (INIS)

2011-02-01

The Aespoe Hard Rock Laboratory (HRL) is an important part of SKB's work with the design and construction of a deep geological repository for the final disposal of spent nuclear fuel. Aespoe HRL is located in the Simpevarp area in the municipality of Oskarshamn. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create opportunities for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995 and considerable international interest has been shown in its research, as well as in the development and demonstration tasks. A summary of the work performed at Aespoe HRL during 2010 is given below
Aespoe Hard Rock Laboratory. Annual Report 2011

International Nuclear Information System (INIS)

2012-03-01

The Aespoe Hard Rock Laboratory (HRL) is an important part of SKB's work with the design and construction of a deep geological repository for the final disposal of spent nuclear fuel. Aespoe HRL is located in the Simpevarp area in the municipality of Oskarshamn. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create opportunities for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995 and considerable international interest has been shown in its research, as well as in the development and demonstration tasks. A summary of the work performed at Aespoe HRL during 2011 is given below
Aespoe hard rock laboratory. Annual report 2010

Energy Technology Data Exchange (ETDEWEB)

2011-02-15

The Aespoe Hard Rock Laboratory (HRL) is an important part of SKB's work with the design and construction of a deep geological repository for the final disposal of spent nuclear fuel. Aespoe HRL is located in the Simpevarp area in the municipality of Oskarshamn. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create opportunities for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995 and considerable international interest has been shown in its research, as well as in the development and demonstration tasks. A summary of the work performed at Aespoe HRL during 2010 is given below
Aespoe hard rock laboratory. Current research projects 1998

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-12-31

In 1986 SKB decided to construct the Aespoe Hard Rock Laboratory (HRL) in order to provide an opportunity for research, development and demonstration in a realistic and undisturbed underground rock environment down to the depth planned for the future deep repository. The focus of current and future work is on development and testing of site characterization methods, verification of models describing the function of the natural and engineered barriers and development, testing, and demonstration of repository technology. The program has been organised so that all important steps in the development of a repository are covered, in other words the Aespoe HRL constitutes a `dress rehearsal` for the Swedish deep geological repository for spent fuel and other long-lived waste. Geoscientific investigations on Aespoe and nearby islands began in 1986. Aespoe was selected as the site for the laboratory in 1988. Construction of the facility, which reaches a depth of 460 m below the surface, began in 1990 and was completed in 1995. A major milestone had been reached in 1996 with the completion of the pre-investigation and construction phases of the Aespoe HRL. The comprehensive research conducted has permitted valuable development and verification of site characterization methods applied from the ground surface, boreholes, and underground excavations. The results of this research are summarised in the book `Aespoe Hard Rock Laboratory - 10 years of Research` published by SKB in 1996. The Operating Phase of the Aespoe HRL began in 1995 and is expected to continue for 15-20 years, that is until the first stage of the development of the Swedish deep geological repository for spent nuclear fuel is expected to be completed. A number of research projects were initiated at the start of the Operating Phase. Most of these projects have made substantial progress since then and important results have been obtained. The purpose of this brochure is to provide a brief presentation of the
Aespoe hard rock laboratory. Current research projects 1998

International Nuclear Information System (INIS)

1998-01-01

In 1986 SKB decided to construct the Aespoe Hard Rock Laboratory (HRL) in order to provide an opportunity for research, development and demonstration in a realistic and undisturbed underground rock environment down to the depth planned for the future deep repository. The focus of current and future work is on development and testing of site characterization methods, verification of models describing the function of the natural and engineered barriers and development, testing, and demonstration of repository technology. The program has been organised so that all important steps in the development of a repository are covered, in other words the Aespoe HRL constitutes a 'dress rehearsal' for the Swedish deep geological repository for spent fuel and other long-lived waste. Geoscientific investigations on Aespoe and nearby islands began in 1986. Aespoe was selected as the site for the laboratory in 1988. Construction of the facility, which reaches a depth of 460 m below the surface, began in 1990 and was completed in 1995. A major milestone had been reached in 1996 with the completion of the pre-investigation and construction phases of the Aespoe HRL. The comprehensive research conducted has permitted valuable development and verification of site characterization methods applied from the ground surface, boreholes, and underground excavations. The results of this research are summarised in the book 'Aespoe Hard Rock Laboratory - 10 years of Research' published by SKB in 1996. The Operating Phase of the Aespoe HRL began in 1995 and is expected to continue for 15-20 years, that is until the first stage of the development of the Swedish deep geological repository for spent nuclear fuel is expected to be completed. A number of research projects were initiated at the start of the Operating Phase. Most of these projects have made substantial progress since then and important results have been obtained. The purpose of this brochure is to provide a brief presentation of the
Aespoe Hard Rock Laboratory. Annual Report 2006

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-06-15

The Aespoe Hard Rock Laboratory (HRL) is an important part of SKB's work with the design and construction of a deep geological repository for the final disposal of spent nuclear fuel. Aespoe HRL is located in the Simpevarp area in the municipality of Oskarshamn. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create opportunities for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995 and considerable international interest has been shown in its research, as well as in the development and demonstration tasks. The work performed at Aespoe HRL during 2006 is in this report described in six chapters: Geo-science - experiments, analysis and modelling to increase the knowledge of the surrounding rock; Natural barriers - experiments, analysis and modelling to increase the knowledge of the repository barriers under natural conditions; Engineered barriers - demonstration of technology for and function of important engineered parts of the repository barrier system; Aespoe facility - operation, maintenance, data management, monitoring, public relations etc; Environmental research; and finally, International co-operation.
Aespoe Hard Rock Laboratory. Annual Report 2006

International Nuclear Information System (INIS)

2006-06-01

The Aespoe Hard Rock Laboratory (HRL) is an important part of SKB's work with the design and construction of a deep geological repository for the final disposal of spent nuclear fuel. Aespoe HRL is located in the Simpevarp area in the municipality of Oskarshamn. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create opportunities for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995 and considerable international interest has been shown in its research, as well as in the development and demonstration tasks. The work performed at Aespoe HRL during 2006 is in this report described in six chapters: Geo-science - experiments, analysis and modelling to increase the knowledge of the surrounding rock; Natural barriers - experiments, analysis and modelling to increase the knowledge of the repository barriers under natural conditions; Engineered barriers - demonstration of technology for and function of important engineered parts of the repository barrier system; Aespoe facility - operation, maintenance, data management, monitoring, public relations etc; Environmental research; and finally, International co-operation
Aespoe HRL - Geoscientific evaluation 1997/5. Models based on site characterization 1986-1995

International Nuclear Information System (INIS)

Rhen, I.; Stanfors, R.; Wikberg, P.

1997-10-01

The pre-investigations for the Aespoe Hard Rock Laboratory were started in 1986 and involved extensive field measurements, aimed at characterizing the rock formations with regard to geology, geohydrology, hydrochemistry and rock mechanics. Predictions for the excavation phase were made prior to excavation of the laboratory which was started in the autumn of 1990. The predictions concern five key issues: lithology and geological structures, groundwater flow, hydrochemistry, transport of solutes and mechanical stability. During 1996 the results from the pre-investigations and the excavation of the Aespoe Hard Rock Laboratory were evaluated and were compiled in geological, mechanical stability, geohydrological, groundwater chemical and transport-of-solutes models. The model concepts and the models of 1996 are presented in this report. The model developments from the pre-investigation phase up to the models made 1996 are also presented briefly
Aespoe HRL - Geoscientific evaluation 1997/5. Models based on site characterization 1986-1995

Energy Technology Data Exchange (ETDEWEB)

Rhen, I. [ed.; Gustafsson, Gunnar [VBB Viak AB, Goeteborg (Sweden); Stanfors, R. [RS Consulting, Lund (Sweden); Wikberg, P. [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden)

1997-10-01

The pre-investigations for the Aespoe Hard Rock Laboratory were started in 1986 and involved extensive field measurements, aimed at characterizing the rock formations with regard to geology, geohydrology, hydrochemistry and rock mechanics. Predictions for the excavation phase were made prior to excavation of the laboratory which was started in the autumn of 1990. The predictions concern five key issues: lithology and geological structures, groundwater flow, hydrochemistry, transport of solutes and mechanical stability. During 1996 the results from the pre-investigations and the excavation of the Aespoe Hard Rock Laboratory were evaluated and were compiled in geological, mechanical stability, geohydrological, groundwater chemical and transport-of-solutes models. The model concepts and the models of 1996 are presented in this report. The model developments from the pre-investigation phase up to the models made 1996 are also presented briefly. 317 refs, figs, tabs.
Aespoe Hard Rock Laboratory. Status Report May - August 2009

International Nuclear Information System (INIS)

2009-11-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD-Programme 2007 /SKB 2007/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2009/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the period May to August 2009
Aespoe Hard Rock Laboratory. Status Report October - December 2008

International Nuclear Information System (INIS)

2009-03-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD-Programme 2007 /SKB 2007/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2008/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the fourth quarter of 2008
Aespoe Hard Rock Laboratory. Status Report. September - December 2009

International Nuclear Information System (INIS)

2010-05-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD Programme 2007 /SKB 2007/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2009/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the period September to December 2009
Aespoe Hard Rock Laboratory. Status Report January - April 2009

International Nuclear Information System (INIS)

2009-09-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD-Programme 2007 /SKB 2007/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2009/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the period January to April 2009
Aespoe Hard Rock Laboratory. Status Report. April - June 2007

Energy Technology Data Exchange (ETDEWEB)

2007-07-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2005- 2010 are presented in SKB's RDandD-Programme 2004 /SKB 2004/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2007/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the second quarter 2007
Aespoe Hard Rock Laboratory. Status Report. April - June 2007

International Nuclear Information System (INIS)

2007-01-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2005- 2010 are presented in SKB's RDandD-Programme 2004 /SKB 2004/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2007/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the second quarter 2007
Aespoe Hard Rock Laboratory. Status Report. July - September 2008

International Nuclear Information System (INIS)

2008-01-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD-Programme 2007 /SKB 2007/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2008/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the third quarter of 2008
Aespoe Hard Rock Laboratory. Status Report. January - April 2010

International Nuclear Information System (INIS)

2010-10-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD Programme 2007 /SKB 2007/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2009/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the period January to April 2010
Aespoe Hard Rock Laboratory Annual report 2003

Energy Technology Data Exchange (ETDEWEB)

NONE

2004-09-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a deep geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site for a deep repository. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create an opportunity for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. Aespoe HRL has been in operation since 1995 and the associated research, development, and demonstration tasks, have so far attracted considerable interest. A summary of work performed at Aespoe HRL during 2003 is given below. Seven organisations from six countries participated in the co-operation at Aespoe HRL during 2003 in addition to SKB. Most of the organisations are interested in groundwater flow, radionuclide transport and rock characterisation. Several of the organisations are participating in the experimental work as well as in the Aespoe Task Force on Modelling of Groundwater Flow and Transport of Solutes. SKB is through Repository Technology co-ordinating three EC contracts and takes part in several EC projects of which the representation in five projects is channelled through Repository Technology. SKB takes also part in work within the IAEA framework.
Aespoe Hard Rock Laboratory Annual report 2003

International Nuclear Information System (INIS)

2004-09-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a deep geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site for a deep repository. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create an opportunity for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. Aespoe HRL has been in operation since 1995 and the associated research, development, and demonstration tasks, have so far attracted considerable interest. A summary of work performed at Aespoe HRL during 2003 is given below. Seven organisations from six countries participated in the co-operation at Aespoe HRL during 2003 in addition to SKB. Most of the organisations are interested in groundwater flow, radionuclide transport and rock characterisation. Several of the organisations are participating in the experimental work as well as in the Aespoe Task Force on Modelling of Groundwater Flow and Transport of Solutes. SKB is through Repository Technology co-ordinating three EC contracts and takes part in several EC projects of which the representation in five projects is channelled through Repository Technology. SKB takes also part in work within the IAEA framework

Aespoe Hard Rock Laboratory. Status Report January - April 2009

Energy Technology Data Exchange (ETDEWEB)

2009-09-15

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD-Programme 2007 /SKB 2007/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2009/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the period January to April 2009.
Aespoe Hard Rock Laboratory. Status Report October - December 2008

Energy Technology Data Exchange (ETDEWEB)

2009-03-15

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD-Programme 2007 /SKB 2007/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2008/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the fourth quarter of 2008.
Aespoe Hard Rock Laboratory. Status Report. September - December 2009

Energy Technology Data Exchange (ETDEWEB)

2010-05-15

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD Programme 2007 /SKB 2007/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2009/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the period September to December 2009
Aespoe Hard Rock Laboratory. Status Report. January - April 2010

Energy Technology Data Exchange (ETDEWEB)

2010-10-15

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD Programme 2007 /SKB 2007/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2009/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the period January to April 2010
Aespoe Hard Rock Laboratory. Status Report May - August 2009

Energy Technology Data Exchange (ETDEWEB)

2009-11-15

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD-Programme 2007 /SKB 2007/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2009/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the period May to August 2009.
Aespoe Hard Rock Laboratory. Status Report May - August 2010

Energy Technology Data Exchange (ETDEWEB)

2011-02-15

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD-Programme 2007 /SKB 2007/. The information given in the RD and D-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2010/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the period May to August 2010.
Aespoe Hard Rock Laboratory. Status Report. April - June 2007

Energy Technology Data Exchange (ETDEWEB)

2007-07-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2005- 2010 are presented in SKB's RDandD-Programme 2004 /SKB 2004/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2007/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the second quarter 2007
Aespoe Hard Rock Laboratory. Status Report May - August 2010

International Nuclear Information System (INIS)

2011-02-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD-Programme 2007 /SKB 2007/. The information given in the RD and D-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2010/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the period May to August 2010
Aespoe Hard Rock Laboratory. Status Report. July - September 2008

Energy Technology Data Exchange (ETDEWEB)

2008-07-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. The plans for SKB's research and development of technique during the period 2008-2013 are presented in SKB's RDandD-Programme 2007 /SKB 2007/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report /SKB 2008/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the third quarter of 2008.
Aespoe hard rock laboratory Sweden

International Nuclear Information System (INIS)

1992-01-01

The aim of the new Aespoe hard rock laboratory is to demonstrate state of the art of technology and evaluation methods before the start of actual construction work on the planned deep repository for spent nuclear fuel. The nine country OECD/NEA project in the Stripa mine in Sweden has been an excellent example of high quality international research co-operation. In Sweden the new Aespoe hard rock laboratory will gradually take over and finalize this work. SKB very much appreciates the continued international participation in Aespoe which is of great value for the quality efficiency, and confidence in this kind of work. We have invited a number of leading experts to this first international seminar to summarize the current state of a number of key questions. The contributions show the great progress that has taken place during the years. The results show that there is a solid scientific basis for using this knowledge on site specific preparation and work on actual repositories. (au)
Aespoe Hard Rock Laboratory. Status Report. September - December 2010

International Nuclear Information System (INIS)

2011-04-01

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. In September 2010, the plans for SKB's research and development of technique during the period 2011-2016 were presented in SKB's RDandD-Programme 2010 /SKB 2010a/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report and the information valid for 2010 is given in /SKB 2010b/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the period September to December 2010
Aespoe Hard Rock Laboratory. Status Report. September - December 2010

Energy Technology Data Exchange (ETDEWEB)

2011-04-15

The Aespoe Hard Rock Laboratory (HRL) constitutes an important part of SKB's work to design and construct a geological repository for spent nuclear fuel and to develop and test methods for characterisation of a suitable site. In September 2010, the plans for SKB's research and development of technique during the period 2011-2016 were presented in SKB's RDandD-Programme 2010 /SKB 2010a/. The information given in the RDandD-Programme related to Aespoe HRL is annually detailed in the Aespoe HRL Planning Report and the information valid for 2010 is given in /SKB 2010b/. This Aespoe HRL Status Report is a collection of the main achievements obtained during the period September to December 2010
The colloid investigations conducted at the Aespoe Hard Rock Laboratory during 2000-2004

Energy Technology Data Exchange (ETDEWEB)

Laaksoharju, Marcus [Geopoint AB, Stockholm (Sweden); Wold, Susanna [Royal Inst. of Tech., Stockholm (Sweden). School of Chemical Science and Engineering, Nuclear Chemistry] (eds.)

2005-12-15

In 2000, SKB decided to initiate an international colloid project at the Aespoe Hard Rock Laboratory in Sweden. The objectives of the colloid project are to: (i) study the role of bentonite as a colloid source, (ii) verify the background colloid concentration at Aespoe HRL and, (iii) investigate the potential for colloid formation/transport in natural groundwater concentrations. The experimental concepts for the colloid project are: laboratory experiments with bentonite, background field measurements of natural colloids, borehole specific bentonite colloid stability experiments and a fracture specific transport experiment. The activities concerning the laboratory experiments and background field measurements are described in this work; the other activities are ongoing or planned. The following conclusions were made: The bentonite colloid stability is strongly dependent on the groundwater ionic strength. Natural colloids are organic degradation products such as humic and fulvic acids, inorganic colloids (clay, calcite, iron hydroxide) and microbes. Microbes form few but large particles and their concentration increase with increasing organic carbon concentrations. The small organic colloids are present in very low concentrations in deep granitic groundwater. The concentrations can be rather high in shallow waters. The colloid concentration decreases with depth and salinity, since colloids are less stable in saline waters. The colloid content at Aespoe is less than 300 ppb. The colloid content at repository level is less than 50 ppb. The groundwater variability obtained in the boreholes reflects well the natural groundwater variability along the whole HRL tunnel.
The colloid investigations conducted at the Aespoe Hard Rock Laboratory during 2000-2004

International Nuclear Information System (INIS)

Laaksoharju, Marcus; Wold, Susanna

2005-12-01

In 2000, SKB decided to initiate an international colloid project at the Aespoe Hard Rock Laboratory in Sweden. The objectives of the colloid project are to: (i) study the role of bentonite as a colloid source, (ii) verify the background colloid concentration at Aespoe HRL and, (iii) investigate the potential for colloid formation/transport in natural groundwater concentrations. The experimental concepts for the colloid project are: laboratory experiments with bentonite, background field measurements of natural colloids, borehole specific bentonite colloid stability experiments and a fracture specific transport experiment. The activities concerning the laboratory experiments and background field measurements are described in this work; the other activities are ongoing or planned. The following conclusions were made: The bentonite colloid stability is strongly dependent on the groundwater ionic strength. Natural colloids are organic degradation products such as humic and fulvic acids, inorganic colloids (clay, calcite, iron hydroxide) and microbes. Microbes form few but large particles and their concentration increase with increasing organic carbon concentrations. The small organic colloids are present in very low concentrations in deep granitic groundwater. The concentrations can be rather high in shallow waters. The colloid concentration decreases with depth and salinity, since colloids are less stable in saline waters. The colloid content at Aespoe is less than 300 ppb. The colloid content at repository level is less than 50 ppb. The groundwater variability obtained in the boreholes reflects well the natural groundwater variability along the whole HRL tunnel
Aespoe Hard Rock Laboratory. Annual Report 2009

International Nuclear Information System (INIS)

2010-12-01

The Aespoe Hard Rock Laboratory (HRL) is an important part of SKB's work with the design and construction of a deep geological repository for the final disposal of spent nuclear fuel. Aespoe HRL is located in the Simpevarp area in the municipality of Oskarshamn. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create opportunities for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995 and considerable international interest has been shown in its research, as well as in the development and demonstration tasks. A summary of the work performed at Aespoe HRL during 2009 is given below. Geoscience Geoscientific research is a basic activity at Aespoe HRL. The aim of the current studies is to develop geoscientific models of the Aespoe HRL and increase the understanding of the rock mass properties as well as knowledge of applicable methods of measurement. A main task within the geoscientific field is the development of the Aespoe Site Descriptive Model (SDM) integrating information from the different fields. The main activities in the geoscientific fields have been: (1) Geology evaluation of geological mapping techniques leading to the decision to develop a SKB mapping system and finalization of the mapping of rock surfaces in the new tunnel, (2) Hydrogeology monitoring and storage of data in the computerised Hydro Monitoring System, (3) Geochemistry sampling of groundwater in the yearly campaign and for specific experiments and (4) Rock Mechanics finalised the field tests on thermally-induced spalling in deposition holes and evaluated the effect of counterforce in the deposition holes. Natural barriers At Aespoe HRL, experiments are
Aespoe Hard Rock Laboratory. Annual Report 2009

Energy Technology Data Exchange (ETDEWEB)

2010-12-15

The Aespoe Hard Rock Laboratory (HRL) is an important part of SKB's work with the design and construction of a deep geological repository for the final disposal of spent nuclear fuel. Aespoe HRL is located in the Simpevarp area in the municipality of Oskarshamn. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create opportunities for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995 and considerable international interest has been shown in its research, as well as in the development and demonstration tasks. A summary of the work performed at Aespoe HRL during 2009 is given below. Geoscience Geoscientific research is a basic activity at Aespoe HRL. The aim of the current studies is to develop geoscientific models of the Aespoe HRL and increase the understanding of the rock mass properties as well as knowledge of applicable methods of measurement. A main task within the geoscientific field is the development of the Aespoe Site Descriptive Model (SDM) integrating information from the different fields. The main activities in the geoscientific fields have been: (1) Geology evaluation of geological mapping techniques leading to the decision to develop a SKB mapping system and finalization of the mapping of rock surfaces in the new tunnel, (2) Hydrogeology monitoring and storage of data in the computerised Hydro Monitoring System, (3) Geochemistry sampling of groundwater in the yearly campaign and for specific experiments and (4) Rock Mechanics finalised the field tests on thermally-induced spalling in deposition holes and evaluated the effect of counterforce in the deposition holes. Natural barriers At Aespoe HRL
Preliminary assessment of potential underground stability (wedge and spalling) at Forsmark, Simpevarp and Laxemar sites

Energy Technology Data Exchange (ETDEWEB)

Martin, Derek [Univ. of Alberta, Edmonton (Canada). Geotechnical Engineering

2005-12-15

In SKB's Underground Design Premises the objective in the early design phase is to estimate if there is sufficient space for the repository at a site. One of the conditions that could limit the space available is stability of the underground openings, i.e., deposition tunnels and deposition boreholes. The purpose of this report is to provide a preliminary assessment of the potential for wedge instability and spalling that may be encountered at the Forsmark, Simpevarp and Laxemar sites based on information from the site investigations program up to July 30, 2004. The rock mass spalling strength was defined using the in-situ results from SKB's Aespoe Pillar Stability Experiment and AECL's Mine-by Experiment. These experiments suggest that the rock mass spalling strength for crystalline rocks can be estimated as 0.57 of the mean laboratory uniaxial compressive strength. A probability-based methodology utilizing this in-situ rock mass spalling strength has been developed for assessing the risk for spalling in a repository at the Forsmark, Simpevarp and Laxemar sites. The in-situ stresses and the uniaxial compressive strength data from these sites were used as the bases for the analyses. Preliminary findings from all sites suggest that, generally, the risk for spalling increases as the depth of the repository increases, simply because the stress magnitudes increase with depth. The depth at which the risk for spalling is significant, depends on the individual sites which are discussed below. The greatest uncertainty in the spalling analyses for Forsmark is related to the uncertainty in the horizontal stress magnitudes and associated stress gradients with depth. The confidence in these analyses can only be increased by increasing the confidence in the stress and geology model for the site. From the analyses completed it appears that spalling in the deposition tunnels can be controlled by orienting the tunnels approximately parallel to the maximum horizontal
Aespoe Hard Rock Laboratory. Annual Report 2007

International Nuclear Information System (INIS)

2008-04-01

The main activities in the geoscientific fields have been: (1) Geology - besides mapping of rock surfaces and drill cores a feasibility study concerning geological mapping techniques is performed, (2) Hydrogeology - completion of the modelling work for the detailed hydro-structural model for the -450 m level and monitoring/storage of data in the computerised Hydro Monitoring System, (3) Geochemistry - sampling of groundwater in the yearly campaign and for specific experiments and (4) Rock Mechanics - field work to determine the stress levels at which core disking occur followed by numerical modelling. Experiments are performed to develop and test methods and models for the description of groundwater flow, radionuclide migration, and chemical conditions at repository depth. The programme includes projects which aim to determine parameter values that are required as input to the conceptual and numerical models. At Aespoe HRL, experiments are performed under the conditions that are expected to prevail at repository depth. The experiments are related to the rock, its properties and in situ environmental conditions. The aim is to provide information about the long-term function of natural and repository barriers. Experiments are performed to develop and test methods and models for the description of groundwater flow, radionuclide migration, and chemical conditions at repository depth. The programme includes projects which aim to determine parameter values that are required as input to the conceptual and numerical models. An important goal is to demonstrate technology for and the function of important parts of the repository system. This implies translation of current scientific knowledge and state-of- the-art technology into engineering practice applicable in a real repository. It is important that development, testing and demonstration of methods and procedures are conducted under realistic conditions and at an appropriate scale. A number of large-scale field
Aespoe Hard Rock Laboratory. Annual Report 2007

Energy Technology Data Exchange (ETDEWEB)

2007-04-15

The main activities in the geoscientific fields have been: (1) Geology - besides mapping of rock surfaces and drill cores a feasibility study concerning geological mapping techniques is performed, (2) Hydrogeology - completion of the modelling work for the detailed hydro-structural model for the -450 m level and monitoring/storage of data in the computerised Hydro Monitoring System, (3) Geochemistry - sampling of groundwater in the yearly campaign and for specific experiments and (4) Rock Mechanics - field work to determine the stress levels at which core disking occur followed by numerical modelling. Experiments are performed to develop and test methods and models for the description of groundwater flow, radionuclide migration, and chemical conditions at repository depth. The programme includes projects which aim to determine parameter values that are required as input to the conceptual and numerical models. At Aespoe HRL, experiments are performed under the conditions that are expected to prevail at repository depth. The experiments are related to the rock, its properties and in situ environmental conditions. The aim is to provide information about the long-term function of natural and repository barriers. Experiments are performed to develop and test methods and models for the description of groundwater flow, radionuclide migration, and chemical conditions at repository depth. The programme includes projects which aim to determine parameter values that are required as input to the conceptual and numerical models. An important goal is to demonstrate technology for and the function of important parts of the repository system. This implies translation of current scientific knowledge and state-of- the-art technology into engineering practice applicable in a real repository. It is important that development, testing and demonstration of methods and procedures are conducted under realistic conditions and at an appropriate scale. A number of large-scale field
Aespoe HRL. Experiences of blasting of the TASQ tunnel

International Nuclear Information System (INIS)

Olsson, Mats; Niklasson, Bengt; Wilson, Lasse; Andersson, Christer; Christiansson, Rolf

2004-11-01

A new tunnel was developed at the Aespoe Hard Rock Laboratory (AHRL) during the spring and summer 2003. The tunnel was specially designed for a rock mechanics experiment, the Aespoe Pillar Stability Experiment (APSE). In this pillar experiment there was a high demand to initiate high in-situ stresses and therefore the tunnel was designed with a large height/ width ratio and with a circular floor. There were high requirements on bore hole precision and of a minimized EDZ (Excavation damaged zone) in the pillar area. This included a maximum borehole deviation of 10 mm/m, a maximum overbreak due to the lookout angle of 0.3 m and an EDZ of 0.3 m. To make a charge control feasible cartridged explosives was prescribed. The initiation was made with Nonel. The last three rounds used electronic initiation to enable studies of possibility to further reduce the EDZ. The collar of the tunnel was very close to installations and shaft and it was very important to avoid fly-rock and vibrations. Special types of stemming were used as well as steel plates and rubber mats. The excavation works was divided in three different phases. The first phase of the tunnel was an ordinary 26 m 2 tunnel. After approximately 30 m a ramp separated the tunnel section into a top heading and a bench, total 33 m 2 . After the last top heading round was excavated and the roof had been reinforced with fibre reinforced shotcrete the bench was taken out with horizontal holes as the third phase. The drilling precision was very good and 95% of all half-pipes fulfilled the demands. The total amount of visible half-pipes in the APSE-tunnel was high and indicated a successful smooth blasting. The EDZ was examined further by cutting slots in the wall and roof. Existing cracks appear very clearly when a dye penetrant is sprayed on the cleaned surface. A typical crack pattern consists of blast cracks, induced cracks (cracks from the distressing caused by blasting) and natural cracks. The maximum crack length in

Aespoe HRL. Experiences of blasting of the TASQ tunnel

Energy Technology Data Exchange (ETDEWEB)

Olsson, Mats [Swebrec, Luleaa (Sweden); Niklasson, Bengt [Skanska Teknik, Stockholm (Sweden); Wilson, Lasse [Skanska Stora Projekt, Stockholm (Sweden); Andersson, Christer; Christiansson, Rolf [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden)

2004-11-01

A new tunnel was developed at the Aespoe Hard Rock Laboratory (AHRL) during the spring and summer 2003. The tunnel was specially designed for a rock mechanics experiment, the Aespoe Pillar Stability Experiment (APSE). In this pillar experiment there was a high demand to initiate high in-situ stresses and therefore the tunnel was designed with a large height/ width ratio and with a circular floor. There were high requirements on bore hole precision and of a minimized EDZ (Excavation damaged zone) in the pillar area. This included a maximum borehole deviation of 10 mm/m, a maximum overbreak due to the lookout angle of 0.3 m and an EDZ of 0.3 m. To make a charge control feasible cartridged explosives was prescribed. The initiation was made with Nonel. The last three rounds used electronic initiation to enable studies of possibility to further reduce the EDZ. The collar of the tunnel was very close to installations and shaft and it was very important to avoid fly-rock and vibrations. Special types of stemming were used as well as steel plates and rubber mats. The excavation works was divided in three different phases. The first phase of the tunnel was an ordinary 26 m{sup 2} tunnel. After approximately 30 m a ramp separated the tunnel section into a top heading and a bench, total 33 m{sup 2}. After the last top heading round was excavated and the roof had been reinforced with fibre reinforced shotcrete the bench was taken out with horizontal holes as the third phase. The drilling precision was very good and 95% of all half-pipes fulfilled the demands. The total amount of visible half-pipes in the APSE-tunnel was high and indicated a successful smooth blasting. The EDZ was examined further by cutting slots in the wall and roof. Existing cracks appear very clearly when a dye penetrant is sprayed on the cleaned surface. A typical crack pattern consists of blast cracks, induced cracks (cracks from the distressing caused by blasting) and natural cracks. The maximum crack
Capabilities: Science Pillars

Science.gov (United States)

Alamos National Laboratory Delivering science and technology to protect our nation and promote world stability Science & Innovation Collaboration Careers Community Environment Science & Innovation Facilities Science Pillars Research Library Science Briefs Science News Science Highlights Lab Organizations
Analysis of Äspö Pillar Stability Experiment: Continuous thermo-mechanical model development and calibration

Czech Academy of Sciences Publication Activity Database

Blaheta, Radim; Byczanski, Petr; Čermák, M.; Hrtus, Rostislav; Kohut, Roman; Kolcun, Alexej; Malík, Josef; Sysala, Stanislav

2013-01-01

Roč. 5, č. 2 (2013), s. 124-135 ISSN 1674-7755 Institutional support: RVO:68145535 Keywords : in situ pillar stability experiment * model calibration by back analysis * continuous mechanics * damage of granite rocks * Finite element method (FEM) Subject RIV: BA - General Mathematics http://www.sciencedirect.com/science/article/pii/S1674775513000103
Rock stability considerations for siting and constructing a KBS-3 repository. Based on experiences from Aespoe HRL, AECL's URL, tunnelling and mining

International Nuclear Information System (INIS)

Martin, C.D.; Christiansson, Rolf; Soederhaell, J.

2001-12-01

Over the past 25 years the international nuclear community has carried out extensive research into the deep geological disposal of nuclear waste in hard rocks. In two cases this research has resulted in the construction of dedicated underground research facilities: SKB's Aespoe Hard Rock Laboratory, Sweden and AECL's Underground Research Laboratory, Canada. Both laboratories are located in hard rocks considered representative of the Fennoscandian and Canadian Shields, respectively. This report is intended to synthesize the important rock mechanics findings from these research programs. In particular the application of these finding to assessing the stability of underground openings. As such the report draws heavily on the published results from the SKB's ZEDEX Experiment in Sweden and AECL's Mine- by Experiment in Canada. The objectives of this report are to: 1. Describe, using the current state of knowledge, the role rock engineering can play in siting and constructing a KBS-3 repository. 2. Define the key rock mechanics parameters that should be determined in order to facilitate repository siting and construction. 3. Discuss possible construction issues, linked to rock stability, that may arise during the excavation of the underground openings of a KBS-3 repository. 4. Form a reference document for the rock stability analysis that has to be carried out as a part of the design works parallel to the site investigations. While there is no unique or single rock mechanics property or condition that would render the performance of a nuclear waste repository unacceptable, certain conditions can be treated as negative factors. Outlined below are major rock mechanics issues that should be addressed during the siting, construction and closure of a nuclear waste repository in Sweden in hard crystalline rock. During the site investigations phase, rock mechanics information will be predominately gathered from examination and testing of the rock core and mapping of the
Aespoe Hard Rock Laboratory. Annual Report 2008

International Nuclear Information System (INIS)

2009-07-01

The Aespoe Hard Rock Laboratory (HRL) is an important part of SKB's work with the design and construction of a deep geological repository for the final disposal of spent nuclear fuel. The main activities in the geoscientific fields have been: (1) Geology - completion of the feasibility study concerning geological mapping techniques and mapping of rock surfaces in the new tunnel, (2) Hydrogeology - monitoring and storage of data in the computerised Hydro Monitoring System, (3) Geochemistry - sampling of groundwater in the yearly campaign and for specific experiments and (4) Rock Mechanics - field tests to evaluate the counterforce needed to prevent thermally-induced spalling in deposition holes. At Aespoe HRL, experiments are performed under the conditions that are expected to prevail at repository depth. The aim is to provide information about the long-term function of natural and repository barriers. Experiments are performed to develop and test methods and models for the description of groundwater flow, radionuclide migration, and chemical conditions at repository depth. The programme includes projects which aim to determine parameter values that are required as input to the conceptual and numerical models. A number of large-scale field experiments and supporting activities concerning Engineered barriers are carried out at Aespoe HRL. The experiments focus on different aspects of engineering technology and performance testing: The Prototype Repository is a demonstration of the integrated function of the repository and provides a full-scale reference for tests of predictive models concerning individual components as well as the complete repository system; The Long Term Test of Buffer Material (Lot-experiment) aims at validating models and hypotheses concerning physical properties in a bentonite buffer material and of related processes regarding microbiology, radionuclide transport, copper corrosion and gas transport; The objective of the project Alternative Buffer
Aespoe Hard Rock Laboratory. Annual Report 2008

Energy Technology Data Exchange (ETDEWEB)

2009-07-15

The Aespoe Hard Rock Laboratory (HRL) is an important part of SKB's work with the design and construction of a deep geological repository for the final disposal of spent nuclear fuel. The main activities in the geoscientific fields have been: (1) Geology - completion of the feasibility study concerning geological mapping techniques and mapping of rock surfaces in the new tunnel, (2) Hydrogeology - monitoring and storage of data in the computerised Hydro Monitoring System, (3) Geochemistry - sampling of groundwater in the yearly campaign and for specific experiments and (4) Rock Mechanics - field tests to evaluate the counterforce needed to prevent thermally-induced spalling in deposition holes. At Aespoe HRL, experiments are performed under the conditions that are expected to prevail at repository depth. The aim is to provide information about the long-term function of natural and repository barriers. Experiments are performed to develop and test methods and models for the description of groundwater flow, radionuclide migration, and chemical conditions at repository depth. The programme includes projects which aim to determine parameter values that are required as input to the conceptual and numerical models. A number of large-scale field experiments and supporting activities concerning Engineered barriers are carried out at Aespoe HRL. The experiments focus on different aspects of engineering technology and performance testing: The Prototype Repository is a demonstration of the integrated function of the repository and provides a full-scale reference for tests of predictive models concerning individual components as well as the complete repository system; The Long Term Test of Buffer Material (Lot-experiment) aims at validating models and hypotheses concerning physical properties in a bentonite buffer material and of related processes regarding microbiology, radionuclide transport, copper corrosion and gas transport; The objective of the project Alternative
Aespoe Hard Rock Laboratory Annual Report 2004

International Nuclear Information System (INIS)

2005-08-01

At Aespoe HRL, methods for characterising a suitable site for a deep repository are being developed and tested. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995. Most of the research is focused on processes of importance for the long-term safety of a future deep repository. To meet the overall time schedule for SKB's RDandD work, the following stage goals were initially defined for the work at the Aespoe HRL. 1. Verify pre-investigation methods. Demonstrate that investigations on the ground surface and in boreholes provide sufficient data on essential safety-related properties of the rock at repository level. 2. Finalise detailed investigation methodology. Refine and verify the methods and the technology needed for characterisation of the rock in the detailed site investigations. 3. Test models for description of the barrier functions at natural conditions. Further develop and at repository depth test methods and models for description of groundwater flow, radionuclide migration, and chemical conditions during operation of a repository and after closure. 4. Demonstrate technology for and function of important parts of the repository system. Test, investigate and demonstrate on full-scale different components of importance for the long-term safety of a deep repository and to show that high quality can be achieved in design, construction, and operation of repository components. Stage goals 1 and 2 have been concluded at Aespoe HRL and the tasks have been transferred to the Site Investigation Department of SKB which performs site investigations at two sites, Simpevarp/Laxemar in the municipality of Oskarshamn and Forsmark in the municipality of Oesthammar. In order to reach present goals the following important tasks are performed at the Aespoe HRL: Develop, test, evaluate and demonstrate
Aespoe Hard Rock Laboratory Annual Report 2004

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-08-01

At Aespoe HRL, methods for characterising a suitable site for a deep repository are being developed and tested. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995. Most of the research is focused on processes of importance for the long-term safety of a future deep repository. To meet the overall time schedule for SKB's RDandD work, the following stage goals were initially defined for the work at the Aespoe HRL. 1. Verify pre-investigation methods. Demonstrate that investigations on the ground surface and in boreholes provide sufficient data on essential safety-related properties of the rock at repository level. 2. Finalise detailed investigation methodology. Refine and verify the methods and the technology needed for characterisation of the rock in the detailed site investigations. 3. Test models for description of the barrier functions at natural conditions. Further develop and at repository depth test methods and models for description of groundwater flow, radionuclide migration, and chemical conditions during operation of a repository and after closure. 4. Demonstrate technology for and function of important parts of the repository system. Test, investigate and demonstrate on full-scale different components of importance for the long-term safety of a deep repository and to show that high quality can be achieved in design, construction, and operation of repository components. Stage goals 1 and 2 have been concluded at Aespoe HRL and the tasks have been transferred to the Site Investigation Department of SKB which performs site investigations at two sites, Simpevarp/Laxemar in the municipality of Oskarshamn and Forsmark in the municipality of Oesthammar. In order to reach present goals the following important tasks are performed at the Aespoe HRL: Develop, test, evaluate and
Aespoe Hard Rock Laboratory. Annual Report 1993

International Nuclear Information System (INIS)

1994-06-01

The Aespoe Hard Rock Laboratory is being constructed in preparation for the deep geological repository of spent fuel in Sweden. This Annual Report 1993 for the Aespoe Hard Rock Laboratory contains an overview of the work conducted. Present work is focused on verification of pre-investigation methods and development of the detailed investigation methodology. Construction of the facility and investigation of the bedrock are carried out in parallel. As of December 1993, 2760 m of the tunnel had been excavated to a depth of 370 m below the surface. An important and integral part of the work is further refinement of conceptual and numerical models for groundwater flow and radionuclide migration. Detailed plans have been prepared for several experiments to be conducted after the end of the construction work. Eight organizations from seven countries are now participating in the work at the Aespoe Hard Rock Laboratory and are contributing in different ways to the results being achieved
Pessimistic Determination of Mechanical Conditions and Micro/macroeconomic Evaluation of Mine Pillar Replacement

Science.gov (United States)

Chen, Qingfa; Zhao, Fuyu

2017-12-01

Numerous pillars are left after mining of underground mineral resources using the open stope method or after the first step of the partial filling method. The mineral recovery rate can, however, be improved by replacement recovery of pillars. In the present study, the relationships among the pillar type, minimum pillar width, and micro/macroeconomic factors were investigated from two perspectives, namely mechanical stability and micro/macroeconomic benefit. Based on the mechanical stability formulas for ore and artificial pillars, the minimum width for a specific pillar type was determined using a pessimistic criterion. The microeconomic benefit c of setting an ore pillar, the microeconomic benefit w of artificial pillar replacement, and the economic net present value (ENPV) of the replacement process were calculated. The values of c and w were compared with respect to ENPV, based on which the appropriate pillar type and economical benefit were determined.
Effect of structural discontinuities on coal pillar strength as a basis for improving safety in the design of coal pillar systems.

CSIR Research Space (South Africa)

Esterhuizen, GS

1998-12-01

Full Text Available The stability of underground coal mines depends on the integrity of the pillars which are required to support the overlying strata. Should the pillars collapse, the safety of the persons in the workings will be threatened. The strength of a coal...
Aespoe Hard Rock Laboratory. Annual Report 2002

International Nuclear Information System (INIS)

2003-06-01

The Aespoe HRL was opened in 1994 as a research centre and underground laboratory. The experiments performed in Aespoe HRL are related to the rock, its properties, and in situ environmental conditions. Tests of models for groundwater flow, radionuclide migration and chemical/biological processes are some of the main purposes of the Aespoe HRL. The programme includes projects with the aim to evaluate the usefulness and reliability of different models and to develop and test methods for determination of parameters required as input to conceptual and numerical models. The retardation in rock is studied at different experiment scales in a programme called Tracer Retention Understanding Experiments (TRUE). The Long Term Diffusion Experiment constitutes a complement to performed diffusion and sorption laboratory experiments, and is a natural extension of the experiments conducted as part of the TRUE experiments. Radionuclide retention experiments are carried out with the aim to confirm result from laboratory experiments in situ, where conditions representative for the properties of groundwater at repository depth prevail. In CHEMLAB 1 two kinds of experiments to study the influence of radiolysis on the mobility of technetium in bentonite were started in the end of 2002. Experiments to study migration of actinides in natural fractures in drill cores are being carried out in CHELMAB 2. The findings of potential transport of solutes by colloids and access to more sensitive instruments for colloid measurements motivated a Colloid Project at Aespoe HRL. There are presently four specific microbial process areas identified that are of importance for proper repository functions and that are studied in the Microbe Project. The process areas are; biomobilisation of radionuclides, bioimmobilisation of radionuclides, microbial effects on the chemical stability, and microbial corrosion of copper. The main objectives of the Matrix Fluid Chemistry experiment are to understand the
Aespoe Hard Rock Laboratory. Annual Report 2002

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-06-15

The Aespoe Hard Rock Laboratory (HRL), in the Simpevarp area in the municipality of Oskarshamn constitutes an important part of SKB's work with the design and construction of a deep geological repository for final disposal of spent nuclear fuel. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create an opportunity for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995 and considerable international interest has been shown in its associated research, as well as in the development and demonstration tasks. Most of the research is focused on processes of importance for the long-term safety of a final repository for spent nuclear fuel. Demonstration addresses the performance of the engineered barriers and practical means of constructing and operating a repository for spent fuel. To meet the overall time schedule for SKB's RD and D work, the following stage goals were initially defined for the work at the Aespoe HRL: 1. Verify pre-investigation methods. Demonstrate that investigations on the ground surface and in boreholes provide sufficient data on essential safety-related properties of the rock at repository level. 2. Finalise detailed investigation methodology. Refine and verify the methods and the technology needed for characterisation of the rock in the detailed site investigations. 3. Test models for description of the barrier functions at natural conditions. Further develop, and at repository depth, test methods and models for description of groundwater flow, radionuclide migration and chemical conditions during operation of a repository and after closure. 4. Demonstrate technology for and function of important
Aespoe Hard Rock Laboratory. Annual Report 2005

International Nuclear Information System (INIS)

2006-06-01

The Aespoe Hard Rock Laboratory (HRL), in the Simpevarp area in the municipality of Oskarshamn constitutes an important part of SKB's work with the design and construction of a deep geological repository for final disposal of spent nuclear fuel. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create an opportunity for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. The underground part of the laboratory consists of a tunnel from the Simpevarp peninsula to the southern part of Aespoe where the tunnel continues in a spiral down to a depth of 460 m. Aespoe HRL has been in operation since 1995 and considerable international interest has been shown in its associated research, as well as in the development and demonstration tasks. Most of the research is focused on processes of importance for the long-term safety of a final repository for spent nuclear fuel. Demonstration addresses the performance of the engineered barriers and practical means of constructing and operating a repository for spent fuel. To meet the overall time schedule for SKB's RD and D work, the following stage goals were initially defined for the work at the Aespoe HRL: 1. Verify pre-investigation methods. Demonstrate that investigations on the ground surface and in boreholes provide sufficient data on essential safety-related properties of the rock at repository level. 2. Finalise detailed investigation methodology. Refine and verify the methods and the technology needed for characterisation of the rock in the detailed site investigations. 3. Test models for description of the barrier functions at natural conditions. Further develop, and at repository depth, test methods and models for description of groundwater flow, radionuclide migration and chemical conditions during operation of a repository and after closure. 4. Demonstrate technology for and function of important parts of the
Towards a new generation of flow and transport models for the Aespoe Hard Rock Laboratory. Main results from the project Aespoe models 2005

Energy Technology Data Exchange (ETDEWEB)

Svensson, Urban (ed.) (Computer-aided Fluid Engineering AB (CFE AB), SE-602 10 Norrkoeping (Sweden)); Vidstrand, Patrik (Bergab AB, Goeteborg (Sweden)); Neretnieks, Ivars (Dept. of Chemical Engineering and Technology, Royal Inst. of Technology, Stockholm (Sweden)); Wallin, Bill (Geokema, Lidingoe (Sweden))

2008-05-15

This report constitutes the outcome of a project called 'Aespoe models 2005'. The main objective of the project has been to provide a first step towards a new generation of numerical models of flow and transport, for the Aespoe HRL. In order to achieve this goal, work has been carried out along three parallel lines; discussion of basic concepts, compilation and analysis of data and model applications. A number of sub tasks are reported as appendices in the report. In fact, these appendices represent the main achievements of the project: an analysis of fracture properties, compilation of isotope and chemical data, dispersion and mixing in fractured rocks and model results. The conclusion of the project is that significant contributions to a new generation of Aespoe models have been obtained. It has further been demonstrated that working numerical simulations are up and running. Recommendations are provided for the continued work
Towards a new generation of flow and transport models for the Aespoe Hard Rock Laboratory. Main results from the project Aespoe models 2005

International Nuclear Information System (INIS)

Svensson, Urban; Vidstrand, Patrik; Neretnieks, Ivars; Wallin, Bill

2008-05-01

This report constitutes the outcome of a project called 'Aespoe models 2005'. The main objective of the project has been to provide a first step towards a new generation of numerical models of flow and transport, for the Aespoe HRL. In order to achieve this goal, work has been carried out along three parallel lines; discussion of basic concepts, compilation and analysis of data and model applications. A number of sub tasks are reported as appendices in the report. In fact, these appendices represent the main achievements of the project: an analysis of fracture properties, compilation of isotope and chemical data, dispersion and mixing in fractured rocks and model results. The conclusion of the project is that significant contributions to a new generation of Aespoe models have been obtained. It has further been demonstrated that working numerical simulations are up and running. Recommendations are provided for the continued work
Structural conceptual models of water-conducting features at Aespoe

International Nuclear Information System (INIS)

Bossart, P.; Mazurek, M.; Hermansson, Jan

1998-01-01

Within the framework of the Fracture Classification and Characterization Project (FCC), water conducting features (WCF) in the Aespoe tunnel system and on the surface of Aespoe Island are being characterized over a range of scales. The larger-scale hierarchies of WCF are mostly constituted of fault arrays, i.e. brittle structures that accommodated episodes of shear strain. The smaller-scale WCF (contained within blocks 1 m. Structural evidence indicates that the fractures within the TRUE-1 block constitute an interconnected system with a pronounced anisotropy
Aespoe HRL - Geoscientific evaluation 1997/1. Overview of site characterization 1986-1995

International Nuclear Information System (INIS)

Stanfors, R.; Erlstroem, M.; Markstroem, I.

1997-03-01

Geological investigations for the Aespoe Hard Rock Laboratory in the region around Aespoe began in 1986. Aespoe was selected as the laboratory site in 1988 and construction of the underground facility started in october 1990. Construction of the laboratory was completed in the summer of 1995. This report gives a comprehensive compilation of the different investigations performed during the pre-investigation phase 1986-1990 and the excavation phase 1990-1995. The information is mainly compiled in CAD-generated maps, tables and illustrations in which the reader can gather information concerning the scope of work as well as references to more detailed reports for further study. 325 refs., 85 figs
Development and validation of a method to predict coal pillar life in South Africa

Energy Technology Data Exchange (ETDEWEB)

Van Der Merwe, J.N. [Pretoria Univ., Dept. of Mining Engineering (South Africa)

2005-07-01

One of the most difficult aspects of mine closure procedures, is to predict the long term stability of pillars in the case of coal mining. In South African coal mining, pillars have been designed since the late 1960's with the aid of a pillar strength formula based on statistical analysis of failed pillar cases by the well known team of Salamon and Munro. They developed the widely used power formula for pillar strength. Since that time, however, the data base of failed pillars has effectively doubled in size and re-analysis of the new data indicated that the original pillar strength of small pillars may have been over estimated. The data was then extensively re-analysed and a more effective linear formula for pillar strength was found. The most important differences between the two formulae are that the predicted strength of small pillars are lower and the strength of larger pillars, higher with the new formula. However, neither of the two methods explicitly cater for the prediction of the expected time of stability of coal pillars. No direct correlation between the safety factors and the period of stability of pillars could be found. It was then determined that the most frequent mode of pillar failure was by progressive scaling. Using the new formula to determine a minimum value of pillar safety factor (i.e. the safety factor at which failure can be taken as guaranteed to occur), the final sizes - after scaling - at which the failed pillars had to be in order to fail, were determined. The differences between the original dimensions and the postulated final dimensions were then used to calculate a rate of pillar scaling. The rate was then re-applied to the original data bases of both failed and intact pillar cases and distinct differences were found. The projected lives of the failed pillars were substantially shorter than the projected lives of the intact pillars. While this inspired confidence in the procedure, it was still based on an assumed and unproven
Development and validation of a method to predict coal pillar life in South Africa

International Nuclear Information System (INIS)

Van Der Merwe, J.N.

2005-01-01

One of the most difficult aspects of mine closure procedures, is to predict the long term stability of pillars in the case of coal mining. In South African coal mining, pillars have been designed since the late 1960's with the aid of a pillar strength formula based on statistical analysis of failed pillar cases by the well known team of Salamon and Munro. They developed the widely used power formula for pillar strength. Since that time, however, the data base of failed pillars has effectively doubled in size and re-analysis of the new data indicated that the original pillar strength of small pillars may have been over estimated. The data was then extensively re-analysed and a more effective linear formula for pillar strength was found. The most important differences between the two formulae are that the predicted strength of small pillars are lower and the strength of larger pillars, higher with the new formula. However, neither of the two methods explicitly cater for the prediction of the expected time of stability of coal pillars. No direct correlation between the safety factors and the period of stability of pillars could be found. It was then determined that the most frequent mode of pillar failure was by progressive scaling. Using the new formula to determine a minimum value of pillar safety factor (i.e. the safety factor at which failure can be taken as guaranteed to occur), the final sizes - after scaling - at which the failed pillars had to be in order to fail, were determined. The differences between the original dimensions and the postulated final dimensions were then used to calculate a rate of pillar scaling. The rate was then re-applied to the original data bases of both failed and intact pillar cases and distinct differences were found. The projected lives of the failed pillars were substantially shorter than the projected lives of the intact pillars. While this inspired confidence in the procedure, it was still based on an assumed and unproven rate

Real-time monitoring of copper corrosion at the Aespoe HRL

Energy Technology Data Exchange (ETDEWEB)

Rosborg, Bo; Pan, Jinshan [Div. Corrosion Science, Royal Institute of Technology, Drottning Kristinas vaeg 51, SE - 100 44 Stockholm (Sweden); Eden, David [InterCorr International, Inc., 14503 Bammel-N Houston, Suite 300, Houston, TX 77014 (United States); Karnland, Ola [Clay Technology AB, Ideon Research Center, SE - 223 70 Lund (Sweden); Werme, Lars [Svensk Kaernbraenslehantering AB, P.O. Box 5864, SE - 102 40 Stockholm (Sweden)

2004-07-01

In Sweden the principal strategy for high-level radioactive waste disposal is to enclose the spent nuclear fuel in tightly sealed copper canisters that are embedded in bentonite clay about 500 m down in the Swedish bed-rock. Initially, a limited amount of air will be left in a repository after emplacement. The entrapped oxygen will be consumed through reactions with minerals in the rock and the bentonite and also through microbial activity. After the oxygen has been consumed in the repository, after a few hundred years at the very most, corrosion will be controlled completely by the supply of dissolved sulphide to the canister. The present work concerns the oxic period after emplacement. The main hypothesis is that the average corrosion rate of the canister under oxic conditions will be less than 7 {mu}m/year, and that pitting will only be possible under these conditions. The Aespoe Hard Rock Laboratory offers a realistic environment for different experiments and tests under the conditions that will prevail in a deep repository. Real-time monitoring of copper corrosion is presently performed with polarization resistance, harmonic distortion analysis and electrochemical noise techniques. The first two techniques are used to derive information regarding the general corrosion rate and the third to derive information regarding localized corrosion. In order to support these measurements at Aespoe, laboratory work is also performed at the Royal Institute of Technology in Stockholm using the very same corrosion monitoring equipment and also other equipment and techniques. Copper coupons are also exposed at Aespoe. Results from the work at Aespoe and in Stockholm are presented with an emphasis on the gained information concerning localized corrosion. The recorded corrosion rates at Aespoe are well below the value given above, and the recorded localization factors are interpreted as indicating only a slight tendency to local attack. (authors)
Real-time monitoring of copper corrosion at the Aespoe HRL

International Nuclear Information System (INIS)

Rosborg, Bo; Pan, Jinshan; Eden, David; Karnland, Ola; Werme, Lars

2004-01-01

In Sweden the principal strategy for high-level radioactive waste disposal is to enclose the spent nuclear fuel in tightly sealed copper canisters that are embedded in bentonite clay about 500 m down in the Swedish bed-rock. Initially, a limited amount of air will be left in a repository after emplacement. The entrapped oxygen will be consumed through reactions with minerals in the rock and the bentonite and also through microbial activity. After the oxygen has been consumed in the repository, after a few hundred years at the very most, corrosion will be controlled completely by the supply of dissolved sulphide to the canister. The present work concerns the oxic period after emplacement. The main hypothesis is that the average corrosion rate of the canister under oxic conditions will be less than 7 μm/year, and that pitting will only be possible under these conditions. The Aespoe Hard Rock Laboratory offers a realistic environment for different experiments and tests under the conditions that will prevail in a deep repository. Real-time monitoring of copper corrosion is presently performed with polarization resistance, harmonic distortion analysis and electrochemical noise techniques. The first two techniques are used to derive information regarding the general corrosion rate and the third to derive information regarding localized corrosion. In order to support these measurements at Aespoe, laboratory work is also performed at the Royal Institute of Technology in Stockholm using the very same corrosion monitoring equipment and also other equipment and techniques. Copper coupons are also exposed at Aespoe. Results from the work at Aespoe and in Stockholm are presented with an emphasis on the gained information concerning localized corrosion. The recorded corrosion rates at Aespoe are well below the value given above, and the recorded localization factors are interpreted as indicating only a slight tendency to local attack. (authors)
Aespoe hard rock laboratory. Annual report 1992

International Nuclear Information System (INIS)

1993-04-01

The Aespoe hard rock laboratory is being constructed in preparation for the deep geological repository of spent fuel in Sweden. This Annual report 1992 for the Aespoe hard rock laboratory contains an overview of the work conducted. Present work is focused on verification of pre-investigation methods and development of the detailed investigation methodology. Construction of the facility and investigation of the bedrock are being carried out in parallel. December 1992 1925 m of the tunnel has been excavated to a depth of 255 m below surface. An important and integrated part of the work is further refinement of conceptual and numerical models for groundwater flow and radionuclide migration. This work is carried out in cooperation with seven organizations from six countries that participate in the project. (25 refs.)
Determine the need to research the time-related stability decay of bord and pillar systems

CSIR Research Space (South Africa)

Oberholzer, JW

1997-07-01

Full Text Available in decisions regarding research work that could be conducted to investigate the time related decay of bord and pillar workings. As the working consist of pillars of varying shapes and sizes the study concentrated mainly on the aspects of pillar decay...
Pillarization

NARCIS (Netherlands)

Maussen, M.; Stone, J.; Dennis, R.M.; Rizova, P.S.; Smith, A.D.; Hou, X.

2016-01-01

Pillarization describes a society as divided into a number of "pillars," being compartments standing for the networks of organizations belonging to religious and ideological subcultures. Typically the associations cover a broad range of societal domains (education, media, political parties). The
A physical and numerical modelling investigation of the roadway stability in longwall mining, with and without narrow pillar protection

Energy Technology Data Exchange (ETDEWEB)

Yavuz, H.; Fowell, R.J. [Suleyman Demirel University, Isparta (Turkey)

2004-03-01

The drivage of the supply gate of a development panel in the presumed low stress zone adjacent to the loader gate of an excavated panel with a very small width of intervening pillar between the two entries, known as skin-to-skin working, resulted in an extensive fall of the supply gate roof at Bilsthorpe colliery in 1993. This fall left a question over the application of skin-to-skin drivage of gate entries supported primarily by rock bolts. To investigate the possible reasons behind this fall, both physical and numerical modelling studies were carried out. Physical and numerical models were successful in demonstrating the potential danger of the working method with the rock bolt support system employed. Development of a shear failure plane from the rib edge into roof strata of the loader gate and development of the second shear failure plane at the abutment side of the supply gate exposed the supply gate to the fall of large rock blocks released by shear failure zones. Models demonstrated that the fall of the supply gate roof was not due to the inability of the rock bolts to prevent bed separation, but it was the method of working that made the bolts ineffective due to the height of the block delineated by the shear failure planes. Further physical and numerical models were undertaken to investigate the influence of 5, 7.5 and 10 in wide intervening pillars between the entries on the stability of the rock bolt supported supply gate roof. These studies showed that a 7.5 in or 10 in wide pillar would have prevented development of failure zones and fall of the roof while a 5 in pillar was found to be an undersized pillar width causing the development of extensive failure zones in the roof.
Hydraulic method of working large super-drift pillars

Energy Technology Data Exchange (ETDEWEB)

Rad' ko, B.V.; Syroezhkin, P.V.; Durov, V.S.

1987-03-01

Describes the method of hydraulic coal extraction introduced in the Pioneer mine belonging to the Dobropol'eugol' coal association. This method was found to reduce the number of collection and ventilation roadways needed significantly, increase their stability, reduce coal loss and increase safety, particularly when mining pillars up to 80 m high. Large scale diagram of hydraulic mining layout shows: ventilation gate, hydraulic monitors, mine roadway, cross-cut, and collection roadways. A table shows pillar dimensions and depth and economic savings for different seams in the mine.
Aespoe Hard Rock Laboratory. Annual report 1996

International Nuclear Information System (INIS)

1997-04-01

The Aespoe HRL has been constructed as part of the preparations for the deep geological repository for spent nuclear fuel in Sweden. Geoscientific investigations on Aespoe and nearby islands began 1986. Since then, bedrock conditions have been investigated by several deep boreholes. The Aespoe research village has been built and extensive underground construction work has been undertaken in parallel with comprehensive research. This has resulted in a thorough test of methods for investigation and evaluation of bedrock conditions for construction of a deep repository. The objective of the ZEDEX project is to compare the mechanical disturbance to the rock for excavation by tunnel boring and blasting. The results indicate that the role of the EDZ as a preferential pathway to radionuclide transport is limited to the damaged zone. The tracer retention understanding experiments are made to gain a better understanding of radionuclide retention in the rock and create confidence in the radionuclide transport models. During 1996 a series of tracer experiments in radially converging and dipole flow configuration have been performed. A special borehole probe has been designed for different kinds of retention experiments where data can be obtained representative for the in situ properties of groundwater at repository depth. The prototype repository test is focused on testing and demonstrating repository system function, and includes backfill and plug tests and demonstration of methods for deposition and retrieval of canisters in a new tunnel at the 420 m level. The long term tests of buffer material aim to validate models of buffer performance and at quantifying clay buffer alteration processes at adverse conditions. 80 refs, 53 figs, 16 tabs
Aespoe Hard Rock Laboratory. Annual report 1996

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-04-01

The Aespoe HRL has been constructed as part of the preparations for the deep geological repository for spent nuclear fuel in Sweden. Geoscientific investigations on Aespoe and nearby islands began 1986. Since then, bedrock conditions have been investigated by several deep boreholes. The Aespoe research village has been built and extensive underground construction work has been undertaken in parallel with comprehensive research. This has resulted in a thorough test of methods for investigation and evaluation of bedrock conditions for construction of a deep repository. The objective of the ZEDEX project is to compare the mechanical disturbance to the rock for excavation by tunnel boring and blasting. The results indicate that the role of the EDZ as a preferential pathway to radionuclide transport is limited to the damaged zone. The tracer retention understanding experiments are made to gain a better understanding of radionuclide retention in the rock and create confidence in the radionuclide transport models. During 1996 a series of tracer experiments in radially converging and dipole flow configuration have been performed. A special borehole probe has been designed for different kinds of retention experiments where data can be obtained representative for the in situ properties of groundwater at repository depth. The prototype repository test is focused on testing and demonstrating repository system function, and includes backfill and plug tests and demonstration of methods for deposition and retrieval of canisters in a new tunnel at the 420 m level. The long term tests of buffer material aim to validate models of buffer performance and at quantifying clay buffer alteration processes at adverse conditions. 80 refs, 53 figs, 16 tabs.
Numerical Approach for Goaf-Side Entry Layout and Yield Pillar Design in Fractured Ground Conditions

Science.gov (United States)

Jiang, Lishuai; Zhang, Peipeng; Chen, Lianjun; Hao, Zhen; Sainoki, Atsushi; Mitri, Hani S.; Wang, Qingbiao

2017-11-01

Entry driven along goaf-side (EDG), which is the development of an entry of the next longwall panel along the goaf-side and the isolation of the entry from the goaf with a small-width yield pillar, has been widely employed in China over the past several decades . The width of such a yield pillar has a crucial effect on EDG layout in terms of the ground control, isolation effect and resource recovery rate. Based on a case study, this paper presents an approach for evaluating, designing and optimizing EDG and yield pillar by considering the results from numerical simulations and field practice. To rigorously analyze the ground stability, the numerical study begins with the simulation of goaf-side stress and ground conditions. Four global models with identical conditions, except for the width of the yield pillar, are built, and the effect of pillar width on ground stability is investigated by comparing aspects of stress distribution, failure propagation, and displacement evolution during the entire service life of the entry. Based on simulation results, the isolation effect of the pillar acquired from field practice is also considered. The suggested optimal yield pillar design is validated using a field test in the same mine. Thus, the presented numerical approach provides references and can be utilized for the evaluation, design and optimization of EDG and yield pillars under similar geological and geotechnical circumstances.
Aespoe Hard Rock Laboratory. Interpretation of conductive features at the -450 m level, Aespoe

Energy Technology Data Exchange (ETDEWEB)

Markstroem, Ingemar; Bockgaard, Niklas (Golder Associates (Sweden)); Hardenby, Carljohan (Vattenfall Power Consultant, Stockholm (Sweden)); Hultgren, Peter (Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden))

2010-05-15

The interpretation of conductive features at the -450 m described in this report concerns a part of the tunnel system of the Aespoe Hard Rock Laboratory (Aespoe HRL). The result of the modelling work is presented as an RVS-model (Rock Visualization System). When drilling some bore holes for the Mini-Can Project in the NASA3384A niche at Aespoe HRL some highly transmissive structures were penetrated. This gave a pressure drop response particularly in the Micobe experiment area (the end of TASJ-tunnel) but also in some adjacent areas at the same level. To better understand the complex hydraulic conditions of this part of the tunnel system it was understood that a new interpretation of conductive features was needed. The length axis of the model volume runs along the TASA-tunnel from section 3/260-3/600 m (end of tunnel in the Prototype repository). Laterally the model volume reaches 80 m perpendicular to the length axis in both directions and vertically it reaches to the 350 m and 500 m level respectively. All major water-bearing structures recorded by previously performed geological mapping of the tunnels and drifts (TASF, TASI, TASJ, TASG, TASQ and TASA) at this level of the Aespoe HRL were considered and formed the base for the modelling work. Also some potentially water-bearing open fractures in the tunnels were taken into account. Structures considered as large are those that can be traced over most of a tunnel periphery. No particular concern has been taken about deformation zones unless they were water bearing or acted as hydraulic barriers. A total of 212 cored boreholes penetrated or were identified close to the model volume. 39 of these were intersected by the modelled structures. Various features such as open fractures, fractures identified by bore hole radar, RQD, water inflow etc. were used in the modelling work. A number of earlier RVS-models such as the Geomod, the APSE, the Prototype, the TRUE BS model etc. that have been created within or close to
Allowable pillar to diameter ratio for strategic petroleum reserve caverns.

Energy Technology Data Exchange (ETDEWEB)

Ehgartner, Brian L.; Park, Byoung Yoon

2011-05-01

This report compiles 3-D finite element analyses performed to evaluate the stability of Strategic Petroleum Reserve (SPR) caverns over multiple leach cycles. When oil is withdrawn from a cavern in salt using freshwater, the cavern enlarges. As a result, the pillar separating caverns in the SPR fields is reduced over time due to usage of the reserve. The enlarged cavern diameters and smaller pillars reduce underground stability. Advances in geomechanics modeling enable the allowable pillar to diameter ratio (P/D) to be defined. Prior to such modeling capabilities, the allowable P/D was established as 1.78 based on some very limited experience in other cavern fields. While appropriate for 1980, the ratio conservatively limits the allowable number of oil drawdowns and hence limits the overall utility and life of the SPR cavern field. Analyses from all four cavern fields are evaluated along with operating experience gained over the past 30 years to define a new P/D for the reserve. A new ratio of 1.0 is recommended. This ratio is applicable only to existing SPR caverns.
Aespoe Hard Rock Laboratory. Annual Report 2002

Energy Technology Data Exchange (ETDEWEB)

NONE

2003-06-01

The Aespoe HRL was opened in 1994 as a research centre and underground laboratory. The experiments performed in Aespoe HRL are related to the rock, its properties, and in situ environmental conditions. Tests of models for groundwater flow, radionuclide migration and chemical/biological processes are some of the main purposes of the Aespoe HRL. The programme includes projects with the aim to evaluate the usefulness and reliability of different models and to develop and test methods for determination of parameters required as input to conceptual and numerical models. The retardation in rock is studied at different experiment scales in a programme called Tracer Retention Understanding Experiments (TRUE). The Long Term Diffusion Experiment constitutes a complement to performed diffusion and sorption laboratory experiments, and is a natural extension of the experiments conducted as part of the TRUE experiments. Radionuclide retention experiments are carried out with the aim to confirm result from laboratory experiments in situ, where conditions representative for the properties of groundwater at repository depth prevail. In CHEMLAB 1 two kinds of experiments to study the influence of radiolysis on the mobility of technetium in bentonite were started in the end of 2002. Experiments to study migration of actinides in natural fractures in drill cores are being carried out in CHELMAB 2. The findings of potential transport of solutes by colloids and access to more sensitive instruments for colloid measurements motivated a Colloid Project at Aespoe HRL. There are presently four specific microbial process areas identified that are of importance for proper repository functions and that are studied in the Microbe Project. The process areas are; biomobilisation of radionuclides, bioimmobilisation of radionuclides, microbial effects on the chemical stability, and microbial corrosion of copper. The main objectives of the Matrix Fluid Chemistry experiment are to understand the
Flexible Pillared Graphene-Paper Electrodes for High-Performance Electrochemical Supercapacitors

Energy Technology Data Exchange (ETDEWEB)

Wang, Gongkai; Sun, Xiang; Lu, Fengyuan; Sun, Hongtao; Yu, Mingpeng; Jiang, Weilin; Liu, Changsheng; Lian, Jie

2011-12-08

Flexible graphene paper (GP) pillared by carbon black (CB) nanoparticles using a simple vacuum filtration method is developed as a high-performance electrode material for supercapacitors. Through the introduction of CB nanoparticles as spacers, the self-restacking of graphene sheets during the filtration process is mitigated to a great extent. The pillared GP-based supercapacitors exhibit excellent electrochemical performances and cyclic stabilities compared with GP without the addition of CB nanoparticles. At a scan rate of 10 mV s^-1, the specific capacitance of the pillared GP is 138 F g^-1 and 83.2 F g^-1 with negligible 3.85% and 4.35% capacitance degradation after 2000 cycles in aqueous and organic electrolytes, respectively. At an extremely fast scan rate of 500 mV s^-1, the specific capacitance can reach 80 F g^-1 in aqueous electrolyte. No binder is needed for assembling the supercapacitor cells and the pillared GP itself may serve as a current collector due to its intrinsic high electrical conductivity. Finally, the pillared GP has great potential in the development of promising flexible and ultralight-weight supercapacitors for electrochemical energy storage.
Wettability transition of plasma-treated polystyrene micro/nano pillars-aligned patterns

Directory of Open Access Journals (Sweden)

2010-12-01

Full Text Available This paper reports the wettability transition of plasma-treated polystyrene (PS micro/nano pillars-aligned patterns. The micro/nano pillars were prepared using hot embossing on silicon microporous template and alumina nanoporous template, which were fabricated by ultraviolet (UV lithography and inductive coupled plasma (ICP etching, and two-step anodic oxidation, respectively. The results indicate that the combination of micro/nano patterning and plasma irradiation can easily regulate wettabilities of PS surfaces, i.e. from hydrophilicity to hydrophobicity, or from hydrophobicity to superhydrophilicity. During the wettability transition from hydrophobicity to hydrophilicity there is only mild hydrophilicity loss. After plasma irradiation, moreover, the wettability of PS micro/nano pillars-aligned patterns is more stable than that of flat PS surfaces. The observed wettability transition and wettability stability of PS micro/nano pillars-aligned patterns are new phenomena, which may have potential in creating programmable functional polymer surfaces.
Aespoe Hard Rock Laboratory. Interpretation of conductive features at the -450 m level, Aespoe

International Nuclear Information System (INIS)

Markstroem, Ingemar; Bockgaard, Niklas; Hardenby, Carljohan; Hultgren, Peter

2010-05-01

The interpretation of conductive features at the -450 m described in this report concerns a part of the tunnel system of the Aespoe Hard Rock Laboratory (Aespoe HRL). The result of the modelling work is presented as an RVS-model (Rock Visualization System). When drilling some bore holes for the Mini-Can Project in the NASA3384A niche at Aespoe HRL some highly transmissive structures were penetrated. This gave a pressure drop response particularly in the Micobe experiment area (the end of TASJ-tunnel) but also in some adjacent areas at the same level. To better understand the complex hydraulic conditions of this part of the tunnel system it was understood that a new interpretation of conductive features was needed. The length axis of the model volume runs along the TASA-tunnel from section 3/260-3/600 m (end of tunnel in the Prototype repository). Laterally the model volume reaches 80 m perpendicular to the length axis in both directions and vertically it reaches to the 350 m and 500 m level respectively. All major water-bearing structures recorded by previously performed geological mapping of the tunnels and drifts (TASF, TASI, TASJ, TASG, TASQ and TASA) at this level of the Aespoe HRL were considered and formed the base for the modelling work. Also some potentially water-bearing open fractures in the tunnels were taken into account. Structures considered as large are those that can be traced over most of a tunnel periphery. No particular concern has been taken about deformation zones unless they were water bearing or acted as hydraulic barriers. A total of 212 cored boreholes penetrated or were identified close to the model volume. 39 of these were intersected by the modelled structures. Various features such as open fractures, fractures identified by bore hole radar, RQD, water inflow etc. were used in the modelling work. A number of earlier RVS-models such as the Geomod, the APSE, the Prototype, the TRUE BS model etc. that have been created within or close to
A site scale analysis of groundwater flow and salinity distribution in the Aespoe area

International Nuclear Information System (INIS)

Svensson, Urban

1997-10-01

The objective of the study is to develop, calibrate and apply a numerical simulation model of the Aespoe area. An area of 1.8 x 1.8 km 2 , centred around the Aespoe Hard Rock Laboratory (HRL), gives the horizontal extent of the model. In the vertical direction the model follows the topography at the upper boundary and has a lower boundary at 1000 metres below sea level. The model is based on a mathematical model that includes equations for the Darcy velocities, mass conservation and salinity distribution. Gravitational effects are thus fully accounted for. A regional groundwater model was used to generate boundary conditions for vertical and bottom boundaries. Transmissivities of fracture zones and conductivities for the rock in between, as used in the model, are based on field data. An extensive calibration of the model is carried out, using data for natural conditions (i.e. prior to the construction of the Aespoe HRL), drawdowns from a pump test and data collected during the excavation of the tunnel. A satisfactory agreement with field data is obtained by the calibration. Main results from the model include vertical and horizontal sections of flow, salinity and hydraulic head distributions for natural conditions and for completed tunnel. A sensitivity study, where boundary conditions and material properties are modified, is also carried out. The model is also used to describe some characteristic features of the site like infiltration rates, flux statistics at a depth of 450 metres, salinity of inflows to the tunnel and flow and salinity distributions in fracture zones. The general conclusion of the study is that the model developed can simulate the conditions at Aespoe, both natural and with Aespoe HRL present, in a realistic manner
Aespoe Hard Rock Laboratory. Annual Report 1995

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-04-01

The construction of the laboratory was completed during 1995 and the operating phase has now begun. During the construction data has been collected from the tunnel and boreholes drilled from the tunnel. Results from these investigations have been reported and a comprehensive evaluation is in progress. The results will be used to design the site characterization program for the deep repository. Ten organizations from nine countries participate in the work at the laboratory. An important part of the cooperative work is performed within the framework of the task force on groundwater flow and transport of solutes. An evaluation has been made of the long term pumping test which was performed at Aespoe some years ago. It showed that the modelling tools that exist today have the ability to give a three-dimensional description of groundwater flow at a site like Aespoe. The task force will perform predictive modelling of the tracer experiments performed within the TRUE project. Characterization of the experimental site for TRUE and preparations for the tracer tests were completed during 1995. Tests of the engineering barriers have been started with the test of technology for backfilling of deposition tunnels. 55 refs, 36 figs, 7 tabs.
Aespoe Hard Rock Laboratory. Annual Report 1995

International Nuclear Information System (INIS)

1996-04-01

The construction of the laboratory was completed during 1995 and the operating phase has now begun. During the construction data has been collected from the tunnel and boreholes drilled from the tunnel. Results from these investigations have been reported and a comprehensive evaluation is in progress. The results will be used to design the site characterization program for the deep repository. Ten organizations from nine countries participate in the work at the laboratory. An important part of the cooperative work is performed within the framework of the task force on groundwater flow and transport of solutes. An evaluation has been made of the long term pumping test which was performed at Aespoe some years ago. It showed that the modelling tools that exist today have the ability to give a three-dimensional description of groundwater flow at a site like Aespoe. The task force will perform predictive modelling of the tracer experiments performed within the TRUE project. Characterization of the experimental site for TRUE and preparations for the tracer tests were completed during 1995. Tests of the engineering barriers have been started with the test of technology for backfilling of deposition tunnels. 55 refs, 36 figs, 7 tabs
Thermal properties at Aespoe HRL. Analysis of distribution and scale factors

International Nuclear Information System (INIS)

Sundberg, Jan

2003-04-01

A thermal model for the Aespoe HRL as well as a general strategy for thermal modelling is under development. As a part of that work, thermal conductivities have been modelled from reference values of thermal conductivity of different minerals and from the mineral composition of all Aespoe samples in the Sicada database. The produced thermal conductivity database has been analysed in terms of frequency, type of distribution, spatial distribution, variogram etc. A correction factor has been estimated to compensate for discrepancies between measured and calculated values. The calculated values have been corrected according to measured values. The data has been analysed according to different rock types. However, there are uncertainties in the base material of rock classification, mainly due to problem to distinguish between Aespoe diorite and Aevroe granite, but also because of different classification systems. There is a relationship between thermal conductivity and density for the rock types at Aespoe. Equations of the relationship have been developed based on all thermal conductivity, heat capacity and density measurements. The equations have been tested on two bore holes at Aespoe with promising results. It may be possible to evaluate the spatial distribution of the thermal properties from density loggings. However, more work is needed to develop a complete model including the handling of high and low density zones. There is an insufficient knowledge in the variation of thermal properties at different scales. If the whole variation within a rock type is in the cm-m scale the thermal influence on the canister is small. This is due to the fact that the small-scale variation in thermal properties is mainly averaged out in the 5-10 m scale. If the main variation within rock types is in the 5-10 m scale there is probably a significant effect on the canister temperature. However, it is likely that the observed variation occurs in both these scales. Simulation has been

Flexible pillared graphene-paper electrodes for high-performance electrochemical supercapacitors.

Science.gov (United States)

Wang, Gongkai; Sun, Xiang; Lu, Fengyuan; Sun, Hongtao; Yu, Mingpeng; Jiang, Weilin; Liu, Changsheng; Lian, Jie

2012-02-06

Flexible graphene paper (GP) pillared by carbon black (CB) nanoparticles using a simple vacuum filtration method is developed as a high-performance electrode material for supercapacitors. Through the introduction of CB nanoparticles as spacers, the self-restacking of graphene sheets during the filtration process is mitigated to a great extent. The pillared GP-based supercapacitors exhibit excellent electrochemical performances and cyclic stabilities compared with GP without the addition of CB nanoparticles. At a scan rate of 10 mV s(-1) , the specific capacitance of the pillared GP is 138 F g(-1) and 83.2 F g(-1) with negligible 3.85% and 4.35% capacitance degradation after 2000 cycles in aqueous and organic electrolytes, respectively. At an extremely fast scan rate of 500 mV s (-1) , the specific capacitance can reach 80 F g(-1) in aqueous electrolyte. No binder is needed for assembling the supercapacitor cells and the pillared GP itself may serve as a current collector due to its intrinsic high electrical conductivity. The pillared GP has great potential in the development of promising flexible and ultralight-weight supercapacitors for electrochemical energy storage. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Aespoe modelling task force - experiences of the site specific flow and transport modelling (in detailed and site scale)

Energy Technology Data Exchange (ETDEWEB)

Gustafson, Gunnar [Chalmers Univ. of Technology, Goeteborg (Sweden); Stroem, A.; Wikberg, P. [Swedish Nuclear Fuel and Waste Management Co. , Stockholm (Sweden)

1998-09-01

The Aespoe Task Force on modelling of groundwater flow and transport of solutes was initiated in 1992. The Task Force shall be a forum for the organisations supporting the Aespoe Hard Rock Laboratory Project to interact in the area of conceptual and numerical modelling of groundwater flow and solute transport in fractured rock. Much emphasis is put on building of confidence in the approaches and methods in use for modelling of groundwater flow and nuclide migration in order to demonstrate their use for performance and safety assessment. The modelling work within the Task Force is linked to the experiments performed at the Aespoe Laboratory. As the first Modelling Task, a large scale pumping and tracer experiment called LPT2 was chosen. This was the final part of the characterisation work for the Aespoe site before the construction of the laboratory in 1990. The construction of the Aespoe HRL access tunnel caused an even larger hydraulic disturbance on a much larger scale than that caused by the LPT2 pumping test. This was regarded as an interesting test case for the conceptual and numerical models of the Aespoe site developed during Task No 1, and was chosen as the third Modelling Task. The aim of Task 3 can be seen from two different perspectives. The Aespoe HRL project saw it as a test of their ability to define a conceptual and structural model of the site that can be utilised by independent modelling groups and be transformed to a predictive groundwater flow model. The modelling groups saw it as a means of understanding groundwater flow in a large fractured rock volume and of testing their computational tools. A general conclusion is that Task 3 has served these purposes well. Non-sorbing tracers tests, made as a part of the TRUE-experiments were chosen as the next predictive modelling task. A preliminary comparison between model predictions made by the Aespoe Task Force and the experimental results, shows that most modelling teams predicted breakthrough from
Aespoe HRL - Geoscientific evaluation 1997/2. Results from pre-investigation and detailed site characterization. Summary report

International Nuclear Information System (INIS)

Rhen, I.; Baeckbom, G.; Stanfors, R.; Wikberg, P.

1997-05-01

The work at Aespoe Hard rock laboratory provides an important scientific and technical basis for implementing and operating a future deep repository in Sweden. A milestone has now been reached with the completion of the pre investigation and construction phases at Aespoe HRL. The present data base at Aespoe HRL is one of the most comprehensive data bases in the world for crystalline rock properties, containing data from a large number of investigation methods from the surface down to 1700 m below ground level. Site characterization in conjunction with construction work has basically confirmed the pre-construction models. The site characterization has been a realistic 'dress rehearsal' that is invaluable for planning and execution of surface and underground characterization of sites for the deep repository for spent nuclear fuel in Sweden
Aespoe HRL - Geoscientific evaluation 1997/2. Results from pre-investigation and detailed site characterization. Summary report

Energy Technology Data Exchange (ETDEWEB)

Rhen, I. [VBB Viak, Goeteborg (Sweden); Baeckbom, G. [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden)] [eds.; Gustafsson, Gunnar [VBB Viak, Goeteborg (Sweden) and Chalmers Univ. of Technology, Goeteborg (Sweden); Stanfors, R. [RS Consulting, Lund (Sweden); Wikberg, P. [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden)

1997-05-01

The work at Aespoe Hard rock laboratory provides an important scientific and technical basis for implementing and operating a future deep repository in Sweden. A milestone has now been reached with the completion of the pre investigation and construction phases at Aespoe HRL. The present data base at Aespoe HRL is one of the most comprehensive data bases in the world for crystalline rock properties, containing data from a large number of investigation methods from the surface down to 1700 m below ground level. Site characterization in conjunction with construction work has basically confirmed the pre-construction models. The site characterization has been a realistic `dress rehearsal` that is invaluable for planning and execution of surface and underground characterization of sites for the deep repository for spent nuclear fuel in Sweden. 502 refs, 114 figs, 30 tabs.
Develop guidelines for the design of pillar systems for shallow and intermediate depth, tabular, hard rock mines and provide a methodology for assessing hangingwall stability and support requirements for the panels between pillars

CSIR Research Space (South Africa)

York, G

1998-12-01

Full Text Available The design of hard rock pillars, in shallow to intermediate depth hard rock mines, has been redefined as the determination of the pillar system load bearing capacity. This entails the ability to design each of the components of the pillar system...
Rock stability considerations for siting and constructing a KBS-3 repository. Based on experiences from Aespoe HRL, AECL's URL, tunnelling and mining

Energy Technology Data Exchange (ETDEWEB)

Martin, C.D. [Univ. of Alberta, Edmonton (Canada); Christiansson, Rolf [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden); Soederhaell, J. [VBB VIAK AB, Stockholm (Sweden)

2001-12-01

Over the past 25 years the international nuclear community has carried out extensive research into the deep geological disposal of nuclear waste in hard rocks. In two cases this research has resulted in the construction of dedicated underground research facilities: SKB's Aespoe Hard Rock Laboratory, Sweden and AECL's Underground Research Laboratory, Canada. Both laboratories are located in hard rocks considered representative of the Fennoscandian and Canadian Shields, respectively. This report is intended to synthesize the important rock mechanics findings from these research programs. In particular the application of these finding to assessing the stability of underground openings. As such the report draws heavily on the published results from the SKB's ZEDEX Experiment in Sweden and AECL's Mine- by Experiment in Canada. The objectives of this report are to: 1. Describe, using the current state of knowledge, the role rock engineering can play in siting and constructing a KBS-3 repository. 2. Define the key rock mechanics parameters that should be determined in order to facilitate repository siting and construction. 3. Discuss possible construction issues, linked to rock stability, that may arise during the excavation of the underground openings of a KBS-3 repository. 4. Form a reference document for the rock stability analysis that has to be carried out as a part of the design works parallel to the site investigations. While there is no unique or single rock mechanics property or condition that would render the performance of a nuclear waste repository unacceptable, certain conditions can be treated as negative factors. Outlined below are major rock mechanics issues that should be addressed during the siting, construction and closure of a nuclear waste repository in Sweden in hard crystalline rock. During the site investigations phase, rock mechanics information will be predominately gathered from examination and testing of the rock core and
Simple evaluation of groundwater flow and radionuclide transport at Aespoe

International Nuclear Information System (INIS)

Dverstorp, B.; Geier, J.; Voss, C.

1996-12-01

A simple evaluation of groundwater flux and potential for radionuclide transport at the Aespoe site, from fundamental hydrologic principles, indicates that, based upon data that are available from surface-based investigations, it is not possible to confirm that the bedrock has a high capacity to retard radionuclide release to the surface environment. This result is primarily due to the high spatial variability of hydraulic conductivity, and high uncertainty regarding the relationship among hydrologic and transport parameters within conductive elements of the bedrock. A comparison between Aespoe and seven other study sites in Sweden indicates that it is difficult or impossible to discriminate among these sites in terms of the geologic barrier function, based upon the types of data that are available from present-day methods of site characterization. Groundwater flux is evaluated by a one-dimensional application of Darcy's law to a set of simple, potential pathways for groundwater flow from the repository, which are chosen to yield an appraisal of the wide bounds of possible system behaviour. The configurations of the pathways are specified based on simple assumptions of flow-field structure, and hydraulic driving forces are specified from consideration of regional and local topographic differences. Results are expressed in terms of a parameter group that has been shown to control the barrier function. Comparisons with more detailed hydrological modelling of Aespoe show that, although a reduction in uncertainty is achieved, this reduction is not sufficient to distinguish between good and poor performance of the geologic barrier at the site. 38 refs
Evaluation of used methodology/methods in Aespoe HRL. Sections 0/700-1/475 and 1/475-2/265

International Nuclear Information System (INIS)

Andersson, Kjell; Sundquist, U.; Torssander, P.

1997-01-01

Some of the main objectives with the Aespoe Hard Rock Laboratory is reviewing and verifying the suitability of different investigations methods regarding bedrock characterization, test methods for detailed site investigations and to evaluate factors of importance for safety in realistic conditions. The SKB evaluation will result in a strategy planned to be used in the forthcoming site selection of a repository for high level radioactive waste. This report presents an evaluation of the methods used by SKB in the prediction of the bedrock prior to excavation. The prediction was based on the pre investigations carried out during 1986-1990. The review has followed the SKB classification of issue areas: geological/structural model, groundwater flow, groundwater chemistry, transport of solutes and mechanical stability. The review concerns SKB's objectives with the prediction and the different criteria for selection of variables - considering the demands of the performance assessment. This report includes evaluation of two tunnel sections, 0/700 - 1/475 and 1/475 - 2/265, comprising used data, prediction methods and prediction accuracy. By way of comparing predictions before excavation and outcome in the tunnel, a strict validation was performed. Based on the results from the validation, the applicability of different methods was estimated and the predictability of different subjects was assessed. It should be emphasised that the Aespoe predictions have not been directly intended for performance assessment purposes. However, it is of interest to see how the predictions relate to the information needs of performance assessment. By this it is possible to identify areas where more work needs to be done in the future, either in the operational phases at Aespoe or in other parts of the SKB program, thereby setting the predictions in an overall perspective from the point of view of performance assessment
In situ measurements of Merensky pillar behaviour at Impala Platinum

CSIR Research Space (South Africa)

Watson, BP

2009-12-01

Full Text Available to stabilize the stoping excavations. This paper describes the in situ measurement, of stress within a Merensky pillar from Impala Platinum. These measurements were used to derive a stress-strain curve that includes pre and post failure behaviour. 2D FLAC...
2D and 3D modelling of magnetic and resistivity data from Aespoe

International Nuclear Information System (INIS)

Mattsson, Haakan

2011-05-01

This report presents results from modelling of geophysical data. Ground magnetic and geo electric data were collected in 1988 as part of the pre-investigations carried out before the construction of the Aespoe Hard Rock Laboratory (HRL). The work presented in this report is an evaluation of the magnetic and geo electric data with the focus on estimating variations in geometry and dip of some of the possible deformation zones indicated in lineament interpretations presented earlier. This was done by 2D forward magnetic modelling, 2D forward resistivity modelling and 3D inversion of the magnetic data. The specific aims of this work are: 1. Produce magnetic 2D forward models across 12 selected linked lineaments. 2. Produce a 3D susceptibility model of the entire data set of Aespoe. 3. Use 2D forward resistivity modelling to produce electric anomaly response diagrams for a dipole-dipole survey across low resistivity zones with various dips. The results of the modelling work will mainly be used as supportive information for deterministic geological modelling of deformation zones and rock units in the vicinity of the Aespoe HRL. The results of the 2D forward modelling of magnetic data show geologically reasonable solutions, and in most cases it is possible to make reliable estimates of the width and orientation of the cause of the targeted lineament. The possible deformation zones generally dip steeply (80 deg-90 deg) and have a width of c. 30-50 m. In some cases the modelled lineament has a diffuse character with low amplitude, which makes the model solution uncertain. Two 3D susceptibility models were created by use of inversion of the ground magnetic data; one coarse model of the entire Island of Aespoe and one more detailed model of the south-eastern peninsula of the Island, covering the volume of the Aespoe HRL. The two models fit nicely to the measured data and they are geologically realistic. It is possible to identify well-defined bodies (rock volumes) of
Numerical modeling for longwall pillar design: a case study from a typical longwall panel in China

Science.gov (United States)

Zhang, Guangchao; Liang, Saijiang; Tan, Yunliang; Xie, Fuxing; Chen, Shaojie; Jia, Hongguo

2018-02-01

This paper presents a new numerical modeling procedure and design principle for longwall pillar design with the assistance of numerical simulation of FLAC3D. A coal mine located in Yanzhou city, Shandong Province, China, was selected for this case study. A meticulously validated numerical model was developed to investigate the stress changes across the longwall pillar with various sizes. In order to improve the reliability of the numerical modeling, a calibration procedure is undertaken to match the Salamon and Munro pillar strength formula for the coal pillar, while a similar calibration procedure is used to estimate the stress-strain response of a gob. The model results demonstrated that when the coal pillar width was 7-8 m, most of the vertical load was carried by the panel rib, whilst the gateroad was overall in a relatively low stress environment and could keep its stability with proper supports. Thus, the rational longwall pillar width was set as 8 m and the field monitoring results confirmed the feasibility of this pillar size. The proposed numerical simulation procedure and design principle presented in this study could be a viable alternative approach for longwall pillar design for other similar projects.
Treatment and final disposal of nuclear waste. Aespoe hard rock laboratory

International Nuclear Information System (INIS)

1992-09-01

The scientific investigations within SBK's research programme are a part of the work of designing a deep repository and identifying and investigating a suitable site. A balanced appraisal of the facts, requirements and assessments presented in connection with the preparation of R and D-programme 86 led to the proposal to construct an underground research laboratory. This proposal was presented in the aforementioned research programme and was very positively recived by the reviewing bodies. In the autumn of 1986, SKB initiated the field work for the siting of an underground laboratory, the Aespoe hard rock laboratory, in the Simpevarp area in the municipality of Oskarshamn. At the end of 1988, SKB arrived at a decision in principle to site the facility on southern Aespoe about 2 km north of the Oskarshamn nuclear power station. After regulatory review, SKB ordered the excavation of the access tunnel to the Aespoe hard rock laboratory to commence in the autumn of 1990. In conjunction with the tunneling work, which has now (September 1992) reached a depth of more than 200 m, a large number of investigations have been carried out. This background report to SKB's RD and D-programme 92 is based on the previous and 89 /2/. The report provides a general background and presents goals, projects results obtained to date and future work. Compared to the previous background reports, more space is devoted here to experiment planning and the future demonstration programme. (au)
Stress reduction for pillar filled structures

Science.gov (United States)

Nikolic, Rebecca J.; Conway, Adam; Shao, Qinghui; Voss, Lars; Cheung, Chin Li; Dar, Mushtaq A.

2015-09-01

According to one embodiment, an apparatus for detecting neutrons includes an array of pillars, wherein each of the pillars comprises a rounded cross sectional shape where the cross section is taken perpendicular to a longitudinal axis of the respective pillar, a cavity region between each of the pillars, and a neutron sensitive material located in each cavity region.
Aespoe hard rock laboratory. Annual report 2000

International Nuclear Information System (INIS)

2001-06-01

The Aespoe Hard Rock Laboratory constitutes an important component of SKB's work to design, construct, and implement a deep geological repository for spent nuclear fuel and to develop and test methods for characterisation of selected repository sites. The retention effect of the rock has been studied by tracer tests in the Tracer Retention Understanding Experiments (TRUE) and the TRUE Block Scale (TRUE BS). These tests are supplemented by the new Long Term Diffusion Experiment (LTDE). During year 2000 the field experiments of TRUE BS (50 m scale) were completed and preparations made for the LTDE (migration through a fracture wall and into the rock), including boring of approximately 10 m deep hole with 300 mm diameter. Laboratory investigations have difficulties in simulating natural conditions and need supplementary field studies to support validation exercises. A special borehole probe, CHEMLAB, has therefore been designed for different kinds of validation experiments where data can be obtained representative for the in-situ properties of groundwater at repository depth. During 2000 migration experiments were made with actinides (Am, Np and Pu) in CHEMLAB 2, the simplified supplement to CHEMLAB 1. Colloids of nuclides as well as of bentonite might affect the migration of released radionuclides and a separate project was planned during 2000 to assess the existence, stability and mobility of colloids. The development of numerical modelling tools continues with the general objective to improve the numerical models in terms of flow and transport and to update the site-scale and laboratory scale models for the Aespoe HRL. The Matrix Fluid Chemistry project aims at determining the origin and age of matrix fluids and the experiment has been designed to sample matrix fluids from predetermined, isolated borehole sections by specialised equipment. The Aespoe HRL also has the task to demonstrate and perform full scale tests of the function of different components of the
Aespoe Hard Rock Laboratory. The TASS-tunnel. Geological mapping

Energy Technology Data Exchange (ETDEWEB)

Hardenby, Carljohan (Vattenfall Power Consultant AB (Sweden)); Sigurdsson, Oskar (HAskGeokonsult AB (Sweden))

2010-12-15

The project entitled 'Sealing of tunnel at great depth' (Fintaetning av tunnel paa stort djup) needed a new tunnel in an area as undisturbed as possible and with cross-cutting water-bearing structures. The new tunnel, which was given the name TASS, was excavated on the -450 m level of SKB's Aespoe Hard Rock Laboratory (Aespoe HRL). The length of the tunnel is approximately 80 m and the theoretical tunnel area 19 m2. As is the case with all the other tunnels of the Aespoe HRL, the new tunnel has been geologically mapped. In addition, laser scanning combined with digital photography has been carried out. The tunnel was also used to test various types of explosives, borehole layouts and drilling techniques. The geological mapping of tunnel floor, walls and roof took place on four major occasions when a halt was made in tunnel excavation to allow for various tests. Before the mapping started on these occasions, laser scanning took place. The tunnel faces were mapped after each round (drilling, blasting and unloading). The present report describes the geological features of the tunnel and briefly how the laser scanning was performed. Water-bearing structures have been compared to similar structures in the neighbouring tunnels. The rock type names used here follow the old established Aespoe HRL nomenclature. Narrow (<0.1 m wide) dykes are normally mapped as fracture fillings. The dominating rock type is Aespoe diorite, which constitutes some 90 % of the rock mass. It is mostly mapped as fresh rock. . Minor constituents of the rock mass are fine-grained granite, hybrid rock, pegmatite, quartz veins/lenses and undifferentiated mafic rock. The mapping of fractures and deformation zones considers a number of parameters such as number of fractures, open/healed, width, length, description of fracture surfaces (roughness, planarity, etc), fracture filling, alteration and water. The deformation zones are discriminated into two main categories (&apos
Aespoe Hard Rock Laboratory. The TASS-tunnel. Geological mapping

International Nuclear Information System (INIS)

Hardenby, Carljohan; Sigurdsson, Oskar

2010-12-01

The project entitled 'Sealing of tunnel at great depth' (Fintaetning av tunnel paa stort djup) needed a new tunnel in an area as undisturbed as possible and with cross-cutting water-bearing structures. The new tunnel, which was given the name TASS, was excavated on the -450 m level of SKB's Aespoe Hard Rock Laboratory (Aespoe HRL). The length of the tunnel is approximately 80 m and the theoretical tunnel area 19 m 2 . As is the case with all the other tunnels of the Aespoe HRL, the new tunnel has been geologically mapped. In addition, laser scanning combined with digital photography has been carried out. The tunnel was also used to test various types of explosives, borehole layouts and drilling techniques. The geological mapping of tunnel floor, walls and roof took place on four major occasions when a halt was made in tunnel excavation to allow for various tests. Before the mapping started on these occasions, laser scanning took place. The tunnel faces were mapped after each round (drilling, blasting and unloading). The present report describes the geological features of the tunnel and briefly how the laser scanning was performed. Water-bearing structures have been compared to similar structures in the neighbouring tunnels. The rock type names used here follow the old established Aespoe HRL nomenclature. Narrow (<0.1 m wide) dykes are normally mapped as fracture fillings. The dominating rock type is Aespoe diorite, which constitutes some 90 % of the rock mass. It is mostly mapped as fresh rock. . Minor constituents of the rock mass are fine-grained granite, hybrid rock, pegmatite, quartz veins/lenses and undifferentiated mafic rock. The mapping of fractures and deformation zones considers a number of parameters such as number of fractures, open/healed, width, length, description of fracture surfaces (roughness, planarity, etc), fracture filling, alteration and water. The deformation zones are discriminated into two main categories ('increased fracturing' and
The role of the nature of pillars in the structural and magnetic properties of magnetic pillared vlays

DEFF Research Database (Denmark)

Bachir, Cherifa; Lan, Yanhua; Mereacre, Valeriu

2011-01-01

of pillared clays by examining in detail the influence of the calcination temperature and the nature of different pillared clays on these properties. Magnetic layered systems from different pillared clays were prepared and characterized. Firstly, Ti-, Al-, and Zr-pillared clays (Ti-PILCs, Al-PILCs, and Zr......-PILCs, respectively) were produced at different calcination temperatures and then magnetic pillared clays (Ti-M-PILCs, Al-M-PILCs, and Zr-M-PILCs) were prepared at ambient temperature. The synthesis involves a reduction in aqueous solution of the original Fe-exchanged pillared clay using NaBH4. The structural....... Similar experiments with Al- and Zr-pillars have been discussed. A correlation between the XRF data, porosity, FF calculation, and magnetic properties led to the conclusion that the sample Al-M-PILC previously calcined at 500 degrees C was the most stable material after the magnetization process. The same...
Stress-state monitoring of coal pillars during room and pillar extraction

Czech Academy of Sciences Publication Activity Database

Waclawik, Petr; Ptáček, Jiří; Koníček, Petr; Kukutsch, Radovan; Němčík, J.

2016-01-01

Roč. 15, č. 2 (2016), s. 49-56 ISSN 2300-3960 R&D Projects: GA MŠk(CZ) LO1406; GA MŠk ED2.1.00/03.0082 Institutional support: RVO:68145535 Keywords : stress-state monitoring * room and pillar * coal pillar Subject RIV: DH - Mining , incl. Coal Mining http://www.sciencedirect.com/science/article/pii/S2300396016300180
pillared and un-pillared bentonite clays

African Journals Online (AJOL)

BARTH EKWUEME

2011-07-29

Jul 29, 2011 ... A pseudo-second order kinetic model was used to characterize the metal ion transport ... may endanger human health through consumption of sea food and ... widely reported. The pillared clays are two – dimensional zeolite.
Aespoe Hard Rock Laboratory. Annual report 1997

International Nuclear Information System (INIS)

1998-05-01

The Aespoe Hard Rock Laboratory has been constructed as part of the preparations for the deep geological repository for spent nuclear fuel in Sweden. The surface and borehole investigations and the research work performed in parallel with construction have provided a thorough test of methods for investigation and evaluation of bedrock conditions for construction of a deep repository. The Tracer Retention Understanding Experiments are made to gain a better understanding of radionuclide retention in the rock and create confidence in the radionuclide transport models that are intended to be used in the licensing of a deep repository for spent fuel. The experimental results of the first tracer test with sorbing radioactive tracers have been obtained. These tests have been subject to blind predictions by the Aespoe Task Force on groundwater flow and transports of solutes. The manufacturing of the CHEMLAB probe was completed during 1996, and the first experiments were started early in 1997. During 1997 three experiments on diffusion in bentonite using 57 Co, 114 Cs, 85 Sr, 99 Tc, and 131 I were conducted. The Prototype Repository Test is focused on testing and demonstrating repository system function. A full scale prototype including six deposition holes with canisters with electric heaters surrounded by highly compacted bentonite will be built and instrumented. The characterization of the rock mass in the area of the prototype repository is in progress. The objectives of the Demonstration of Repository Technology are to develop, test, and demonstrate methodology and equipment for encapsulation and deposition of spent nuclear fuel. The demonstration of handling and deposition will be made in a new drift. The Backfill and Plug Test includes tests of backfill materials and emplacement methods and a test of a full scale plug. The backfill and rock will be instrumented with about 230 transducers for measuring the thermo-hydro-mechanical processes. The Retrieval Test is

The interaction of sorbing and non-sorbing tracers with different Aespoe rock types. Sorption and diffusion experiments in the laboratory scale

International Nuclear Information System (INIS)

Byegaard, J.; Johansson, Henrik; Skaalberg, M.

1998-11-01

Laboratory experiments studying the sorption and diffusivity of different tracers in Aespoe Hard Rock Laboratory (Aespoe HRL) site specific conditions have been performed. The experiments were conducted by applying both the batch sorption and the through diffusion technique. The investigation was focused on slightly sorbing tracers, i e, alkaline metals (Na + , Rb + and Cs + ) and alkaline earth metals (Ca 2+ , Sr 2+ and Ba 2+ ), but some presumed non-sorbing species have also been included. The dominating generic rock material from Aespoe HRL, Aespoe-diorite and fine-grained granite, were used as well as some altered wall rock and mylonite from the Feature A fracture, the fracture where in situ migration studies have been performed. Synthetic groundwater was used; similar to the high saline groundwater found at the 350m level at Aespoe HRL and at the Feature A site. The results of batch experiments show that the sorption of the tracers increase in the order Na + in the order of (4-30)x10 -6 m 3 /kg and for Cs + in the range of (I-400)x10 -3 m 3 /kg. The variations in sorption coefficients are due to differences in the composition of the geological material, contact time and particle size. Sorption is generally stronger for the Aespoe-diorite than for the fine-grained granite which is explained by the much higher concentration of biotite in Aespoe diorite than in fine-grained granite. In the altered material the biotite has been transformed to chlorite and a lower sorptivity is shown for those material compared to the fresh diorite and granite, respectively. Attempts to explain the sorption and desorption results to a surface sorption - diffusion model are presented. The diffusion results show that the tracers were retarded in the same order as was expected from the measured batch sorption coefficients. Furthermore, the largest size fraction was the most representative when comparing batch sorption coefficients with sorption coefficients evaluated from the
Experience gained from the site characterisation strategy used at the Aespoe hard rock laboratory

Energy Technology Data Exchange (ETDEWEB)

Baeckblom, G. [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden)

1998-09-01

The Aespoe Hard Rock Laboratory is a `dress-rehearsal` facility to test, develop and demonstrate technology and models prior to applications at the actual deep repository site in Sweden. Site characterisation methodology has for more than a decade been a main issue at the Aespoe Hard Rock Laboratory (HRL). At the start of site investigations in 1987 the following strategy was adopted: Comprehensive surface and surface-based investigations; Multi-disciplinary data collection in batches; Staged integrated evaluations on selected key issues closely tied to existing knowledge of the geology of the site; Iterative modelling on several geometrical scales based on existing (scarce) data; `Predictive approach` to model updating. During the construction phase of the Aespoe HRL (1990 - 1995), a multitude of data was collected to test and to increase the details of the models made prior to construction. Several things have been learned regarding the appropriateness of the adopted approach to site characterisation. These findings concern e.g. data collection methods from surface and underground, construction/test-integration, choice of useful and feasible model concepts, data flow and document management. The acquired understanding, knowledge, skill and know-how are very valuable for planning useful and feasible site characterisation for the deep repository in Sweden
Experience gained from the site characterisation strategy used at the Aespoe hard rock laboratory

International Nuclear Information System (INIS)

Baeckblom, G.

1998-01-01

The Aespoe Hard Rock Laboratory is a 'dress-rehearsal' facility to test, develop and demonstrate technology and models prior to applications at the actual deep repository site in Sweden. Site characterisation methodology has for more than a decade been a main issue at the Aespoe Hard Rock Laboratory (HRL). At the start of site investigations in 1987 the following strategy was adopted: Comprehensive surface and surface-based investigations; Multi-disciplinary data collection in batches; Staged integrated evaluations on selected key issues closely tied to existing knowledge of the geology of the site; Iterative modelling on several geometrical scales based on existing (scarce) data; 'Predictive approach' to model updating. During the construction phase of the Aespoe HRL (1990 - 1995), a multitude of data was collected to test and to increase the details of the models made prior to construction. Several things have been learned regarding the appropriateness of the adopted approach to site characterisation. These findings concern e.g. data collection methods from surface and underground, construction/test-integration, choice of useful and feasible model concepts, data flow and document management. The acquired understanding, knowledge, skill and know-how are very valuable for planning useful and feasible site characterisation for the deep repository in Sweden
High-aspect-ratio, silicon oxide-enclosed pillar structures in microfluidic liquid chromatography.

Science.gov (United States)

Taylor, Lisa C; Lavrik, Nickolay V; Sepaniak, Michael J

2010-11-15

The present paper discusses the ability to separate chemical species using high-aspect-ratio, silicon oxide-enclosed pillar arrays. These miniaturized chromatographic systems require smaller sample volumes, experience less flow resistance, and generate superior separation efficiency over traditional packed bed liquid chromatographic columns, improvements controlled by the increased order and decreased pore size of the systems. In our distinctive fabrication sequence, plasma-enhanced chemical vapor deposition (PECVD) of silicon oxide is used to alter the surface and structural properties of the pillars for facile surface modification while improving the pillar mechanical stability and increasing surface area. The separation behavior of model compounds within our pillar systems indicated an unexpected hydrophobic-like separation mechanism. The effects of organic modifier, ionic concentration, and pressure-driven flow rate were studied. A decrease in the organic content of the mobile phase increased peak resolution while detrimentally effecting peak shape. A resolution of 4.7 (RSD = 3.7%) was obtained for nearly perfect Gaussian shaped peaks, exhibiting plate heights as low as 1.1 and 1.8 μm for fluorescein and sulforhodamine B, respectively. Contact angle measurements and DART mass spectrometry analysis indicate that our employed elastomeric soft bonding technique modifies pillar properties, creating a fortuitous stationary phase. This discovery provides evidence supporting the ability to easily functionalize PECVD oxide surfaces by gas-phase reactions.
Pillar-type acoustic metasurface

DEFF Research Database (Denmark)

Jin, Yabin; Bonello, Bernard; Moiseyenko, Rayisa

2017-01-01

We theoretically investigate acoustic metasurfaces consisting of either a single pillar or a line of identical pillars on a thin plate, and we report on the dependence on the geometrical parameters of both the monopolar compressional and dipolar bending modes. We show that for specific dimensions...
Imaging of the cervical articular pillar

Energy Technology Data Exchange (ETDEWEB)

Yeomans, E. [Orange Base Hospital, Orange, NSW (Australia)

1998-12-01

The cervical articular pillar, due to the complex anatomical structure of the cervical spine, is not well demonstrated in routine plain radiographic views. Dedicated views have been devised to demonstrate the pillar, yet their performance has abated considerably since the inception of Computed Tomography (CT) in the 1970`s. It is the consideration that CT does not image the articular pillar with a 10 per cent accuracy that poses the question: Is there still a need for plain radiography of the cervical articular pillar? This paper studies the anatomy, plain radiography, and incidence of injury to the cervical articular pillar. It discusses (with reference to current and historic literature) the efficacy of current imaging protocols in depicting this injury. It deals with plain radiography, CT, complex tomography, and Magnetic Resonance Imaging (MRI) of the cervical spine to conclude there may still be a position in current imaging protocols for plain radiography of the cervical articular pillar. Copyright (1998) Australian Institute of Radiography 43 refs., 5 figs.
Aespoe Hard Rock Laboratory. Planning Report for 2011

International Nuclear Information System (INIS)

2011-02-01

This report presents the planned activities for the year 2011. The report is revised annually and details the programme carried out in the Aespoe Hard Rock Laboratory as described in SKB's Research, Development and Demonstration Programme 2010, and serves as a basis for the management of the laboratory. The role of the Planning Report is to present the plans and scope of work for each project. Background information on the projects is given in the Annual Report as well as findings and results
Measurements of colloid concentrations in the fracture zone, Aespoe Hard Rock Laboratory, Sweden

International Nuclear Information System (INIS)

Ledin, A.; Dueker, A.; Karlsson, Stefan; Allard, B.

1995-06-01

The applicability of light scattering in combination with photon correlation spectroscopy (PCS) for determination of concentration and size distribution of colloidal matter in a deep groundwater was tested in situ and on-line. Well-defined reference colloids of Fe 2 O 3 , Al(OH) 3 , SiO 2 , kaolinite, illite and a high molecular humic acid in aqueous media were used as model substances for calibration of the PCS instrument. The intensity of scattered light was found to be dependent on the composition of the colloids. The colloid concentration in the rather saline groundwater was below the detection limit for the PCS equipment used, which corresponds to a colloid concentration not higher than 0.5 mg/l and probably below 0.1 mg/l according to the measurements on-line and in situ at Aespoe and in comparison to the calibrations performed with reference colloids. The results clearly demonstrated that the stability, concentration and composition of a colloid-size suspended phase in the anoxic groundwater with high content of Fe(II), like the one in Aespoe, is extremely sensitive to exposure to atmospheric conditions during sample handling and preparation. Diffusion of air into the closed measuring cuvette was enough to alter the colloid content significantly within 6 hours. A particle fraction with the size distribution in the range 170-700 nm was formed within 45 min when air was allowed to diffuse into the aqueous phase from the air filled upper part of the cuvette. The corresponding time to generate a significant colloid precipitate was less than 1 min when a stream of air was bubbled through the water samples. The precipitated colloid phase consisted of a mixture of ferric (hydr)oxide and calcium carbonate in all three cases. 53 refs, 8 figs, 2 tabs
The interaction of sorbing and non-sorbing tracers with different Aespoe rock types. Sorption and diffusion experiments in the laboratory scale

Energy Technology Data Exchange (ETDEWEB)

Byegaard, J.; Johansson, Henrik; Skaalberg, M. [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Nuclear Chemistry; Tullborg, E.L. [Terralogica AB, Graabo (Sweden)

1998-11-01

Laboratory experiments studying the sorption and diffusivity of different tracers in Aespoe Hard Rock Laboratory (Aespoe HRL) site specific conditions have been performed. The experiments were conducted by applying both the batch sorption and the through diffusion technique. The investigation was focused on slightly sorbing tracers, i e, alkaline metals (Na{sup +}, Rb{sup +} and Cs{sup +}) and alkaline earth metals (Ca{sup 2+}, Sr{sup 2+} and Ba{sup 2+}), but some presumed non-sorbing species have also been included. The dominating generic rock material from Aespoe HRL, Aespoe-diorite and fine-grained granite, were used as well as some altered wall rock and mylonite from the Feature A fracture, the fracture where in situ migration studies have been performed. Synthetic groundwater was used; similar to the high saline groundwater found at the 350m level at Aespoe HRL and at the Feature A site. The results of batch experiments show that the sorption of the tracers increase in the order NaAespoe-diorite than for the fine-grained granite which is explained by the much higher concentration of biotite in Aespoe diorite than in fine-grained granite. In the altered material the biotite has been transformed to chlorite and a lower sorptivity is shown for those material compared to the fresh diorite and granite, respectively. Attempts to explain the sorption and desorption results to a surface sorption - diffusion model are presented. The diffusion results show that the tracers were retarded in the same order as was expected from the measured batch sorption coefficients. Furthermore, the largest size fraction was the most
30 CFR 75.207 - Pillar recovery.

Science.gov (United States)

2010-07-01

... SAFETY STANDARDS-UNDERGROUND COAL MINES Roof Support § 75.207 Pillar recovery. Pillar recovery shall be... be left in place. (b) Before mining is started in a pillar split or lift— (1) At least two rows of breaker posts or equivalent support shall be installed— (i) As close to the initial intended breakline as...
SITE-94. Discrete-feature modelling of the Aespoe site: 2. Development of the integrated site-scale model

International Nuclear Information System (INIS)

Geier, J.E.

1996-12-01

A 3-dimensional, discrete-feature hydrological model is developed. The model integrates structural and hydrologic data for the Aespoe site, on scales ranging from semi regional fracture zones to individual fractures in the vicinity of the nuclear waste canisters. Hydrologic properties of the large-scale structures are initially estimated from cross-hole hydrologic test data, and automatically calibrated by numerical simulation of network flow, and comparison with undisturbed heads and observed drawdown in selected cross-hole tests. The calibrated model is combined with a separately derived fracture network model, to yield the integrated model. This model is partly validated by simulation of transient responses to a long-term pumping test and a convergent tracer test, based on the LPT2 experiment at Aespoe. The integrated model predicts that discharge from the SITE-94 repository is predominantly via fracture zones along the eastern shore of Aespoe. Similar discharge loci are produced by numerous model variants that explore uncertainty with regard to effective semi regional boundary conditions, hydrologic properties of the site-scale structures, and alternative structural/hydrological interpretations. 32 refs
SITE-94. Discrete-feature modelling of the Aespoe site: 2. Development of the integrated site-scale model

Energy Technology Data Exchange (ETDEWEB)

Geier, J.E. [Golder Associates AB, Uppsala (Sweden)

1996-12-01

A 3-dimensional, discrete-feature hydrological model is developed. The model integrates structural and hydrologic data for the Aespoe site, on scales ranging from semi regional fracture zones to individual fractures in the vicinity of the nuclear waste canisters. Hydrologic properties of the large-scale structures are initially estimated from cross-hole hydrologic test data, and automatically calibrated by numerical simulation of network flow, and comparison with undisturbed heads and observed drawdown in selected cross-hole tests. The calibrated model is combined with a separately derived fracture network model, to yield the integrated model. This model is partly validated by simulation of transient responses to a long-term pumping test and a convergent tracer test, based on the LPT2 experiment at Aespoe. The integrated model predicts that discharge from the SITE-94 repository is predominantly via fracture zones along the eastern shore of Aespoe. Similar discharge loci are produced by numerous model variants that explore uncertainty with regard to effective semi regional boundary conditions, hydrologic properties of the site-scale structures, and alternative structural/hydrological interpretations. 32 refs.
Aespoe Hard Rock Laboratory. Annual report 1997

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-05-01

The Aespoe Hard Rock Laboratory has been constructed as part of the preparations for the deep geological repository for spent nuclear fuel in Sweden. The surface and borehole investigations and the research work performed in parallel with construction have provided a thorough test of methods for investigation and evaluation of bedrock conditions for construction of a deep repository. The Tracer Retention Understanding Experiments are made to gain a better understanding of radionuclide retention in the rock and create confidence in the radionuclide transport models that are intended to be used in the licensing of a deep repository for spent fuel. The experimental results of the first tracer test with sorbing radioactive tracers have been obtained. These tests have been subject to blind predictions by the Aespoe Task Force on groundwater flow and transports of solutes. The manufacturing of the CHEMLAB probe was completed during 1996, and the first experiments were started early in 1997. During 1997 three experiments on diffusion in bentonite using {sup 57}Co, {sup 114}Cs,{sup 85}Sr, {sup 99}Tc, and {sup 131}I were conducted. The Prototype Repository Test is focused on testing and demonstrating repository system function. A full scale prototype including six deposition holes with canisters with electric heaters surrounded by highly compacted bentonite will be built and instrumented. The characterization of the rock mass in the area of the prototype repository is in progress. The objectives of the Demonstration of Repository Technology are to develop, test, and demonstrate methodology and equipment for encapsulation and deposition of spent nuclear fuel. The demonstration of handling and deposition will be made in a new drift. The Backfill and Plug Test includes tests of backfill materials and emplacement methods and a test of a full scale plug. The backfill and rock will be instrumented with about 230 transducers for measuring the thermo-hydro-mechanical processes. The
Aespoe Hard Rock Laboratory. Planning Report for 2011

Energy Technology Data Exchange (ETDEWEB)

2011-02-15

This report presents the planned activities for the year 2011. The report is revised annually and details the programme carried out in the Aespoe Hard Rock Laboratory as described in SKB's Research, Development and Demonstration Programme 2010, and serves as a basis for the management of the laboratory. The role of the Planning Report is to present the plans and scope of work for each project. Background information on the projects is given in the Annual Report as well as findings and results.
Thermoelectric properties of silicon nano pillars

Energy Technology Data Exchange (ETDEWEB)

Stranz, Andrej; Soekmen, Uensal; Waag, Andreas; Peiner, Erwin [Institute of Semiconductor Technology, Braunschweig (Germany)

2010-07-01

In order to establish silicon as a efficient thermoelectric material, its high thermal conductivity has to be reduced which is feasible, e.g., by nano structuring. Therefore, in this study Si-based sub-micron pillars of various dimensions were investigated. Using anisotropic etching followed by thermal oxidation we could fabricate pillars of diameters <500 nm, about 25 {mu}m in height with aspect ratios of more than 50. The distance between the pillars was varied from 500 nm to 10 micron. Besides the fabrication and structural characterization of sub-micron silicon pillars, and adequate metrology for measuring their thermoelectric properties was implemented. Commercial tungsten probes and self-made gold probes, as well as Wollaston wire probes were used for electrical and thermal conductivity, as well as Seebeck voltage measurements on single pillars in a scanning electron microscope equipped with nano manipulators.
Pillar support for a wind power plant

Energy Technology Data Exchange (ETDEWEB)

Dietz, A

1978-08-24

The invention concerns a stationary pillar for a wind power plant with vertical rotors in the outside walls of individual parts of the structure, which are arranged above one antoher and which can turn together freely as a pillar facade. There are problems in such a stationary pillar because of storm forces on the one hand, which try to buckle the pillar, and, on the other hand, the pillar should be easy to mount without difficult fishplates or screwed connections. In order to solve this problem, the invention provides that tension elements run from the top ring of the pillar to the foundation through all the spars and through the connecting rings inside the spars, whose tension forces not only counteract buckling of the pillar, but also pull the intersections of the spars together in tension and independently of the screwed connections also provided. The connecting rings at the connections to the spars have half sleeves, which are pushed into a sleeve of the spar coming from below. The tension elements can consist of bundles of steel wires or a wire rope.
Water condensation on ultrahydrophobic flexible micro pillar surface

Science.gov (United States)

Narhe, Ramchandra

2016-05-01

We investigated the growth dynamics of water drops in controlled condensation on ultrahydrophobic geometrically patterned polydimethylsiloxane (PDMS) cylindrical micro pillars. At the beginning, the condensed drops size is comparable to the pattern dimensions. The interesting phenomenon we observe is that, as the condensation progresses, water drops between the pillars become unstable and enforced to grow in the upward direction along the pillars surface. The capillary force of these drops is of the order of μ\\text{N} and acts on neighboring pillars. That results into bending of the pillars. Pillars bending enhances the condensation and favors the most energetically stable Wenzel state.
Empirical pillar design methods review report: Final report

International Nuclear Information System (INIS)

1988-02-01

This report summarizes and evaluates empirical pillar design methods that may be of use during the conceptual design of a high-level nuclear waste repository in salt. The methods are discussed according to category (i.e, main, submain, and panel pillars; barrier pillars; and shaft pillars). Of the 21 identified for main, submain, and panel pillars, one method, the Confined Core Method, is evaluated as being most appropriate for conceptual design. Five methods are considered potentially applicable. Of six methods identified for barrier pillars, one method based on the Load Transfer Distance concept is considered most appropriate for design. Based on the evaluation of 25 methods identified for shaft pillars, an approximate sizing criterion is proposed for use in conceptual design. Aspects of pillar performance relating to creep, ground deformation, interaction with roof and floor rock, and response to high temperature environments are not adequately addressed by existing empirical design methods. 152 refs., 22 figs., 14 tabs
Preliminary creep and pillar closure data for shales

International Nuclear Information System (INIS)

Lomenick, T.F.; Russell, J.E.

1987-10-01

The results of fourteen laboratory creep tests on model pillars of four different shales are reported. Initial pillar stresses range from 6.9 MPa (1000 psi) to 69 MPa (10,000 psi) and temperatures range from ambient to 100 0 C. Laboratory response data are used to evaluate the parameters in the transient power-law pillar closure equation similar to that previously used for model pillars of rock salt. The response of the model pillars of shale shows many of the same characteristics as for rock salt. Deformation is enhanced by higher stresses and temperatures, although the shale pillars are not as sensitive to either stress or temperature as are pillars of rock salt. These test results must be considered very preliminary since they represent the initial, or scoping, phase of a comprehensive model pillar test program that will lead to the development and validation of creep laws for clay-rich rocks. 11 refs., 9 figs., 7 tabs
Measurements of copper corrosion in the LOT Project at the Aespoe Hard Rock Laboratory

International Nuclear Information System (INIS)

Rosborg, B.; Karnland, O.; Quirk, G.; Werme, L.

2003-01-01

Real-time monitoring, of corrosion by means of electrochemical noise and other electrochemical techniques may offer interesting possibilities to estimate the kind and degree of corrosion in a sample or component, and further visualize the corrosion resistance of pure copper in repository environments. As a pilot effort, three cylindrical copper electrodes for such measurements, each of about 100 cm 2 surface area, have been installed in a test parcel in the Aespoe Hard Rock Laboratory and electrochemical measurements using InterCorr's SmartCET system were initiated in May 2001. The first results from real-time monitoring of copper corrosion in the Aespoe HRL under actual repository environment conditions by means of linear polarisation resistance, harmonic distortion analysis and electrochemical noise techniques are presented, and compared with the results obtained from one of the retrieved test parcels. (authors)

Planning maximum extraction of a safety pillar in the Most surface mine

Energy Technology Data Exchange (ETDEWEB)

Helis, P; Hess, L; Kubiznak, K [SHR - Banske Projekty, Teplice (Czechoslovakia)

1990-11-01

Discusses planned coal surface mining in the Most mine in the area of the Hnevin safety pillar with coal reserves amounting to about 7.5 Mt. The following aspects are evaluated: coal reserves and their distribution in the pillar, coal seam thickness and dip angles, water conditions, water influx rates, mechanical properties of the overburden and strata situated in the seam floor, slope stability and hazards of landslides, effects of water influx on landslide hazards, types of bucket wheel excavators used for overburden removal and mining, types of belt conveyors used for mine haulage, stackers, position of mining equipment in the mine. A scheme developed by Banske Projekty Teplice for partial extraction of the safety pillar would result in extraction of 4.5 Mt coal. About 1.7 Mt coal would be left in a safety coal layer about 10.0 m thick situated in the floor in zones with landslide hazards. KU 300 bucket wheel excavators, belt conveyors 1,200 mm wide and ZP 2,500 stackers would be used. 4 refs.
Aespoe Hard Rock Laboratory. Hydro Monitoring Program. Report for 2008

Energy Technology Data Exchange (ETDEWEB)

Wass, Eva; Nyberg, Goeran (GEOSIGMA, Uppsala (Sweden))

2009-08-15

The Aespoe island is situated close to the nuclear power plant of Simpevarp in southeastern Sweden. As part of the pre-investigations preceding excavation of the Aespoe Hard Rock Laboratory, registrations of the groundwater levels and electrical conductivity in packed-off borehole sections and levels in open boreholes started in 1987. The investigations are still ongoing and are planned to continue for a long period of time. As the tunnel excavation went on from the autumn 1990 and onwards, new boreholes were drilled in the tunnel and instrumented to enable groundwater pressure monitoring in packed-off sections. In addition, other hydro-related measurements such as water flow in the tunnel, electrical conductivity of tunnel water and inflow and outflow of water through tunnel pipes have been performed. This report is a summary of the monitoring during 2008. In order to allow for comparison with factors that may influence the groundwater level/pressure and flow, meteorological data are also presented in the report. From the end of 1991, the disturbance from the tunnel is the dominating factor influencing groundwater levels in the area. In one chapter, activities that may have an influence on the ground water situation are listed and briefly discussed.
Aespoe Hard Rock Laboratory. Hydro Monitoring Program. Report for 2009

Energy Technology Data Exchange (ETDEWEB)

Wass, Eva; Nyberg, Goeran (GEOSIGMA, Uppsala (Sweden))

2010-05-15

The Aespoe island is situated close to the nuclear power plant of Simpevarp in southeastern Sweden. As part of the pre-investigations preceding excavation of the Aespoe Hard Rock Laboratory, registrations of the groundwater levels and electrical conductivity in packed-off borehole sections and levels in open boreholes started in 1987. The investigations are still ongoing and are planned to continue for a long period of time. As the tunnel excavation went on from the autumn 1990 and onwards, new boreholes were drilled in the tunnel and instrumented to enable groundwater pressure monitoring in packed-off sections. In addition, other hydro-related measurements such as water flow in the tunnel, electrical conductivity of tunnel water and inflow and outflow of water through tunnel pipes have been performed. This report is a summary of the monitoring during 2009. In order to allow for comparison with factors that may influence the groundwater level/pressure and flow, meteorological data are also presented in the report. From the end of 1991, the disturbance from the tunnel is the dominating factor influencing groundwater levels in the area. In one chapter, activities that may have an influence on the ground water situation are listed and briefly discussed
Aespoe Hard Rock Laboratory. Hydro Monitoring Program. Report for 2008

International Nuclear Information System (INIS)

Wass, Eva; Nyberg, Goeran

2009-08-01

The Aespoe island is situated close to the nuclear power plant of Simpevarp in southeastern Sweden. As part of the pre-investigations preceding excavation of the Aespoe Hard Rock Laboratory, registrations of the groundwater levels and electrical conductivity in packed-off borehole sections and levels in open boreholes started in 1987. The investigations are still ongoing and are planned to continue for a long period of time. As the tunnel excavation went on from the autumn 1990 and onwards, new boreholes were drilled in the tunnel and instrumented to enable groundwater pressure monitoring in packed-off sections. In addition, other hydro-related measurements such as water flow in the tunnel, electrical conductivity of tunnel water and inflow and outflow of water through tunnel pipes have been performed. This report is a summary of the monitoring during 2008. In order to allow for comparison with factors that may influence the groundwater level/pressure and flow, meteorological data are also presented in the report. From the end of 1991, the disturbance from the tunnel is the dominating factor influencing groundwater levels in the area. In one chapter, activities that may have an influence on the ground water situation are listed and briefly discussed
Aespoe Hard Rock Laboratory. Hydro Monitoring Program. Report for 2009

International Nuclear Information System (INIS)

Wass, Eva; Nyberg, Goeran

2010-05-01

The Aespoe island is situated close to the nuclear power plant of Simpevarp in southeastern Sweden. As part of the pre-investigations preceding excavation of the Aespoe Hard Rock Laboratory, registrations of the groundwater levels and electrical conductivity in packed-off borehole sections and levels in open boreholes started in 1987. The investigations are still ongoing and are planned to continue for a long period of time. As the tunnel excavation went on from the autumn 1990 and onwards, new boreholes were drilled in the tunnel and instrumented to enable groundwater pressure monitoring in packed-off sections. In addition, other hydro-related measurements such as water flow in the tunnel, electrical conductivity of tunnel water and inflow and outflow of water through tunnel pipes have been performed. This report is a summary of the monitoring during 2009. In order to allow for comparison with factors that may influence the groundwater level/pressure and flow, meteorological data are also presented in the report. From the end of 1991, the disturbance from the tunnel is the dominating factor influencing groundwater levels in the area. In one chapter, activities that may have an influence on the ground water situation are listed and briefly discussed
Simulations of pressure and salinity fields at Aespoe

Energy Technology Data Exchange (ETDEWEB)

Loefman, J. [VTT Energy, Espoo (Finland)

1997-04-01

The primary objective of this study was to examine whether the geochemical field data from Aespoe could be interpreted and understood by means of numerical simulations for flow and transport. A site-specific simulation model for groundwater flow and salt transport was developed on the basis of the field investigations. Both steady-state and transient simulations of flow and transport were performed. In the transient simulations, land uplift and the effect of diffusion into/from the matrix blocks with stagnant water were taken into account. The computational results were evaluated on the basis of the experimental values for the pressure and salt concentration.
Simulations of pressure and salinity fields at Aespoe

International Nuclear Information System (INIS)

Loefman, J.

1997-01-01

The primary objective of this study was to examine whether the geochemical field data from Aespoe could be interpreted and understood by means of numerical simulations for flow and transport. A site-specific simulation model for groundwater flow and salt transport was developed on the basis of the field investigations. Both steady-state and transient simulations of flow and transport were performed. In the transient simulations, land uplift and the effect of diffusion into/from the matrix blocks with stagnant water were taken into account. The computational results were evaluated on the basis of the experimental values for the pressure and salt concentration
SITE-94. Mineralogy of the Aespoe site

International Nuclear Information System (INIS)

Andersson, Karin

1996-12-01

The water composition has several impacts on the repository. It will influence the behaviour of the engineered materials (e.g. corrosion). It may also determine the possible solubility and speciation of released radionuclides. It also acts as a transport medium for the released elements. The groundwater composition and the potential development of the composition due to the presence of the repository as well as due to external variations is thus an important issue in a safety analysis. The development of the groundwater composition is strongly dependent on reactions with the minerals present in water bearing fractures. Here equilibrium chemistry may be of importance, but also reaction kinetics is important to the long-term behaviour. Within the SITE-94 project, a safety analysis is performed for the conditions at the Aespoe site. The mineralogy of the area has been evaluated from drill cores at various places at the site. In this report a recommendation for selection of mineralogy to be used in geochemical modelling of the repository is given. Calcite and iron containing minerals dominate the fracture filling mineralogy at the Aespoe site. Some typical fracture filling mineralogies may be identified in the fractures: epidote, chlorite, calcite, hematite, some illite/smectite + quartz, fluorite, pyrite and goethite. In addition to these a number of minor minerals are found in the fractures. Uncertainties in the fracture filling data may be due to problems when taking out the drill cores. Drilling water may remove important clay minerals and sealed fractures may be reopened mechanically and treated as water conducting fractures. The problem of determining the variability of the mineralogy along the flow paths also remains. This problem will never be solved when the investigation is performed by drilling investigation holes
Effects of pillar height and junction depth on the performance of radially doped silicon pillar arrays for solar energy applications

NARCIS (Netherlands)

Elbersen, R.; Vijselaar, Wouter Jan, Cornelis; Tiggelaar, Roald M.; Gardeniers, Johannes G.E.; Huskens, Jurriaan

2016-01-01

The effects of pillar height and junction depth on solar cell characteristics are investigated to provide design rules for arrays of such pillars in solar energy applications. Radially doped silicon pillar arrays are fabricated by deep reactive ion etching of silicon substrates followed by the
THE SYNTHESIS OF Cr2O3-PILLARED MONTMORILLONITE (CrPM AND ITS USAGE FOR HOST MATERIAL OF p-NITROANILINE

Directory of Open Access Journals (Sweden)

Karna Wijaya

2010-06-01

Full Text Available The synthesis of Cr2O3-pillared montmorillonite (CrPM and its usage for host material of p-nitroaniline have been conducted. The Cr2O3-pillared montmorillonite clays was prepared by a direct ion exchange method. First, the polyhydroxychromium as a pillaring spesies was intercalated into the interlayer region of the montmorillonite clays (purified clay in the monocation form, result in a montmorillonite-polyoxychromium intercalation compound. The precursors/pillaring spesies was not stable, hence it must be stabilized by calcination in order to transform the polyoxychromium via dehydration and dehydroxylation processes into Cr2O3. This oxide constituts the so-called pillar that prop the clay layers apart to a relatively large distance. The Cr2O3-pillared clays as a host material was added into ethanol solution saturated with p-nitroaniline, and mixture was stirred for 24 h at room temperature. The Na-montmorillonite, Cr2O3-pillared clay and p-nitroaniline-Cr2O3-pillared clay (pNA-CrPM were characterized by X-Ray Diffraction (XRD, Gas Sorption Analysis, Infrared Spectroscopy (FTIR and Activated Neutron Analysis (ANA methods. The result of research showed that basal spacing (d001 of Cr2O3-pillared montmorillonite (CrPM was 18,55 Å, meanwhile the basal spacing of the hydrated Na-montmorillonite was 14,43 Å. The specific surface area of the Cr2O3-pillared montmorillonite was 174,308 m2/g, whereas p-nitroaniline-Cr2O3-pillared clay (pNA-CrPM was 133,331641 m2/g. This fact indicated that p-nitroaniline has been included into the pore of the Cr2O3-pillared clay. Keyword: montmorillonite, pillared-clay, ion exchange, intercalate.
Design of Merensky Reef crush pillars

CSIR Research Space (South Africa)

Watson, BP

2010-10-01

Full Text Available appear stiff enough. However, evidence from the pillar bursts suggests that unfailed pillars located at 10 m or more from the face are in a dangerous, soft-loading situation and may burst if failure takes place. From the evidence of the few collapses... reached a deformation of 32 mm during the initial failure and all failed in a reasonably stable manner. The unacceptable stiffness of the surrounding strata is about 5.0 mm/GN. Most of the measured pillars failed under loading conditions where...
Aespoe hard rock laboratory. Evaluation and conceptual modelling based on the pre-investigations 1986-1990

International Nuclear Information System (INIS)

Wikberg, P.; Gustafson, G.; Rhen, I.; Stanfors, R.

1991-06-01

The investigations have been grouped to several geometric scales under the disciplines of geology, geohydrology and groundwater chemistry, transport of solutes and mechanical stability. Geological mapping and geophysical measurements have been made both on a regional and on a site scale. On the site scale additional surface measurements, drilling of 35 percussion boreholes and 19 cored boreholes was made. The results of the geological investigations show that the Aespoe bedrock is a complex mixture between Smaaland granite, Aespoe diorite and fine grained granite. Hydraulic and chemical data was collected from existing well records within the Kalmar County. Hydraulic conductivity measurement and interference pumping tests were made in the core drilled holes and to some extent in the percussion holes. The hydraulic conductors are basically the fracture zones, but one of the most important is a NNW striking system of single fractures which is difficult to distinguish geologically. The chemical conditions of the groundwater and the fracture minerals form water bearing sections of the core drilled holes have been examined. Water samples were collected from percussion boreholes. The groundwater can be divided into three categories. Fresh water down to approximately 50 m depth. Mixed fresh and seawater 50-100 m, present and/or relict seawater 100-500 m and old (relict) seawater below a depth of 500 m. An important task in the evaluations is to set up 'conceptual models'. These models are the basis for calculation of the ambient groundwater situation and the way in which the hydrological regime will change during the excavation of the laboratory. In order to allow for different levels of detail the conceptual models are established on different scales. The geometrical scales chosen are 500 m, 50 m and 5 m. (au)
Aespoe HRL - Geoscientific evaluation 1997/4. Results from pre-investigation and detailed site characterization. Comparison of predictions and observations. Hydrogeology, groundwater chemistry and transport of solutes

Energy Technology Data Exchange (ETDEWEB)

Rhen, I; Gustafson, Gunnar [VBB Viak AB, Goeteborg (Sweden); Wikberg, P [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden)

1997-06-01

The pre-investigations for the Aespoe Hard Rock Laboratory were started in 1986 and involved extensive field measurements, aimed at characterizing the rock formations with regard to geology, hydrogeology, hydrochemistry and rock mechanics. Prior to the excavation in 1990 predictions were made for the excavation phase concerning: geology, ground water flow and chemistry, transport of solutes and mechanical stability. This report presents a comparison between these predictions and the observations made during the excavation. Also, investigation methods for the 700-2874 m sections of the tunnel are evaluated. 157 refs, 190 figs, 37 tabs.
Aespoe HRL - Geoscientific evaluation 1997/4. Results from pre-investigation and detailed site characterization. Comparison of predictions and observations. Hydrogeology, groundwater chemistry and transport of solutes

International Nuclear Information System (INIS)

Rhen, I.; Gustafson, Gunnar; Wikberg, P.

1997-06-01

The pre-investigations for the Aespoe Hard Rock Laboratory were started in 1986 and involved extensive field measurements, aimed at characterizing the rock formations with regard to geology, hydrogeology, hydrochemistry and rock mechanics. Prior to the excavation in 1990 predictions were made for the excavation phase concerning: geology, ground water flow and chemistry, transport of solutes and mechanical stability. This report presents a comparison between these predictions and the observations made during the excavation. Also, investigation methods for the 700-2874 m sections of the tunnel are evaluated
Reassessment of coal pillar design procedure

CSIR Research Space (South Africa)

Madden, BJ

1995-12-01

Full Text Available The SIMRAC project COL 021A entitled “a reassessment of coal pillar design procedures” set out to achieve a coal pillar design procedure that takes cognisance of different geological and structural factors as well as the influence...
Barrier pillar between production panels in coal mine

Energy Technology Data Exchange (ETDEWEB)

Zingano, Andre Cezar; Koppe, Jair Carlos; Costa, Joao Felipe C.L. [Universidade Federal do Rio Grande do Sul, Porto Alegre (Brazil)

2007-07-01

The function of the barrier pillar is to protect the mining panel in activity from the abutment load of adjacent mining panels that were mined. In the case of underground mines in Santa Catarina State, the barrier pillar has functioned to protect the main entries of the mine against pillar failure from old mining panels. The objective of this paper is to verify the application of the empirical method to design barrier pillars as proposed by Peng (1986), using numerical simulation following the mining geometry of the coal mines in Santa Catarina State. Two-dimensional numerical models were built taking into account the geometry of the main entries and mining panels for different overburden thickness, and considering the geomechanical properties for the rock mass that forms the roof-pillar-floor system for the Bonito coal vein. The results of the simulations showed that the empirical method to determine the barrier pillar width is valid for the studied coal vein and considered mine geometry. Neither did the pillar at the main entry become overstressed due to adjacent mine panels, nor did the roof present any failure due to stress redistribution. 9 refs., 6 figs., 5 tabs.
Periodically structured Si pillars for high-performing heterojunction photodetectors

Science.gov (United States)

Melvin David Kumar, M.; Yun, Ju-Hyung; Kim, Joondong

2015-03-01

A periodical array of silicon (Si) micro pillar structures was fabricated on Si substrates using PR etching process. Indium tin oxide (ITO) layer of 80 nm thickness was deposited over patterned Si substrates so as to make ITO/n-Si heterojunction devices. The influences of width and period of pillars on the optical and electrical properties of prepared devices were investigated. The surface morphology of the Si substrates revealed the uniform array of pillar structures. The 5/10 (width/period) Si pillar pattern reduced the optical reflectance to 6.5% from 17% which is of 5/7 pillar pattern. The current rectifying ratio was found higher for the device in which the pillars are situated in optimum periods. At both visible (600 nm) and near infrared (900 nm) range of wavelengths, the 5/7 and 5/10 pillar patterned device exhibited the better photoresponses which are suitable for making advanced photodetectors. This highly transmittance and photoresponsive pillar patterned Si substrates with an ITO layer would be a promising device for various photoelectric applications.
Coal pillar design procedures

CSIR Research Space (South Africa)

York, G

2000-03-01

Full Text Available Final Project Report Coal pillar design procedures G. York, I. Canbulat, B.W. Jack Research agency: CSIR Mining Technology Project number: COL 337 Date: March 2000 2 Executive Summary Examination of collapsed pillar cases outside of the empirical... in strength occurs with increasing specimen size. 45 40 35 30 25 20 15 10 5 0 20 40 60 80 100 120 140 160 UNIAX IA L COMPR EHEN SIV E S TR ENG TH (M Pa ) CUBE SIZE (cm) Figure 1...
Three Philosophical Pillars That Support Collaborative Learning.

Science.gov (United States)

Maltese, Ralph

1991-01-01

Discusses three philosophical pillars that support collaborative learning: "spaces of appearance," active engagement, and ownership. Describes classroom experiences with collaborative learning supported by these pillars. (PRA)
SITE-94. Discrete-feature modelling of the Aespoe site: 4. Source data and detailed analysis procedures

Energy Technology Data Exchange (ETDEWEB)

Geier, J E [Golder Associates AB, Uppsala (Sweden)

1996-12-01

Specific procedures and source data are described for the construction and application of discrete-feature hydrological models for the vicinity of Aespoe. Documentation is given for all major phases of the work, including: Statistical analyses to develop and validate discrete-fracture network models, Preliminary evaluation, construction, and calibration of the site-scale model based on the SITE-94 structural model of Aespoe, Simulation of multiple realizations of the integrated model, and variations, to predict groundwater flow, and Evaluation of near-field and far-field parameters for performance assessment calculations. Procedures are documented in terms of the computer batch files and executable scripts that were used to perform the main steps in these analyses, to provide for traceability of results that are used in the SITE-94 performance assessment calculations. 43 refs.

SITE-94. Discrete-feature modelling of the Aespoe site: 4. Source data and detailed analysis procedures

International Nuclear Information System (INIS)

Geier, J.E.

1996-12-01

Specific procedures and source data are described for the construction and application of discrete-feature hydrological models for the vicinity of Aespoe. Documentation is given for all major phases of the work, including: Statistical analyses to develop and validate discrete-fracture network models, Preliminary evaluation, construction, and calibration of the site-scale model based on the SITE-94 structural model of Aespoe, Simulation of multiple realizations of the integrated model, and variations, to predict groundwater flow, and Evaluation of near-field and far-field parameters for performance assessment calculations. Procedures are documented in terms of the computer batch files and executable scripts that were used to perform the main steps in these analyses, to provide for traceability of results that are used in the SITE-94 performance assessment calculations. 43 refs
Aespoe Hard Rock Laboratory. Annual report 1998

International Nuclear Information System (INIS)

1999-05-01

The Aespoe Hard Rock Laboratory has been constructed as part of the preparations for the deep geological repository for spent nuclear fuel in Sweden. The Tracer Retention Understanding Experiments are made to gain a better understanding of radionuclide retention in the rock and create confidence in the radionuclide transport models that are intended to be used in the licensing of a deep repository for spent fuel. Experiments with sorbing radioactive tracers have been completed in a single fracture over a distance of about 5 m. These tests have been subject to blind predictions by the Aespoe Task Force on groundwater flow and transports of solutes. Breakthrough of sorbing tracers in the TRUE-I tests is retarded more strongly than would be expected based on laboratory data alone. Results are consistent for all tracers and tracer tests. The main objective of the TRUE Block Scale Experiment is to increase understanding and our ability to predict tracer transport in a fracture network over spatial scales of 10 to 50 m. The total duration of the project is approximately 4.5 years with a scheduled finish at the end of the year 2000. The REX project focuses on the reduction of oxygen in a repository after closure due to reactions with rock minerals and microbial activity. Results show that oxygen is consumed within a few days both for the field and laboratory experiments. The project Degassing of groundwater and two phase flow was initiated to improve our understanding of observations of hydraulic conditions made in drifts and interpretation of experiments performed close to drifts. The analysis performed so far shows that the experimentally observed flow reductions indeed are consistent with the degassing hypothesis. The Prototype Repository Test is focused on testing and demonstrating repository system function. A full-scale prototype including six deposition holes with canisters with electric heaters surrounded by highly compacted bentonite will be built and
Aespoe Hard Rock Laboratory. Annual report 1998

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-05-01

The Aespoe Hard Rock Laboratory has been constructed as part of the preparations for the deep geological repository for spent nuclear fuel in Sweden. The Tracer Retention Understanding Experiments are made to gain a better understanding of radionuclide retention in the rock and create confidence in the radionuclide transport models that are intended to be used in the licensing of a deep repository for spent fuel. Experiments with sorbing radioactive tracers have been completed in a single fracture over a distance of about 5 m. These tests have been subject to blind predictions by the Aespoe Task Force on groundwater flow and transports of solutes. Breakthrough of sorbing tracers in the TRUE-I tests is retarded more strongly than would be expected based on laboratory data alone. Results are consistent for all tracers and tracer tests. The main objective of the TRUE Block Scale Experiment is to increase understanding and our ability to predict tracer transport in a fracture network over spatial scales of 10 to 50 m. The total duration of the project is approximately 4.5 years with a scheduled finish at the end of the year 2000. The REX project focuses on the reduction of oxygen in a repository after closure due to reactions with rock minerals and microbial activity. Results show that oxygen is consumed within a few days both for the field and laboratory experiments. The project Degassing of groundwater and two phase flow was initiated to improve our understanding of observations of hydraulic conditions made in drifts and interpretation of experiments performed close to drifts. The analysis performed so far shows that the experimentally observed flow reductions indeed are consistent with the degassing hypothesis. The Prototype Repository Test is focused on testing and demonstrating repository system function. A full-scale prototype including six deposition holes with canisters with electric heaters surrounded by highly compacted bentonite will be built and
Formation of Pillars at the Boundaries between HII Regions and Molecular Clouds

International Nuclear Information System (INIS)

Mizuta, A; Kane, J O; Pound, M W; Remington, B A; Ryutov, D D; Takabe, H

2006-01-01

We investigate numerically the hydrodynamic instability of an ionization front (IF) accelerating into a molecular cloud, with imposed initial perturbations of different amplitudes. When the initial amplitude is small, the imposed perturbation is completely stabilized and does not grow. When the initial perturbation amplitude is large enough, roughly the ratio of the initial amplitude to wavelength is greater than 0.02, portions of the IF temporarily separate from the molecular cloud surface, locally decreasing the ablation pressure. This causes the appearance of a large, warm HI region and triggers nonlinear dynamics of the IF. The local difference of the ablation pressure and acceleration enhances the appearance and growth of a multimode perturbation. The stabilization usually seen at the IF in the linear regimes does not work due to the mismatch of the modes of the perturbations at the cloud surface and in density in HII region above the cloud surface. Molecular pillars are observed in the late stages of the large amplitude perturbation case. The velocity gradient in the pillars is in reasonably good agreement with that observed in the Eagle Nebula. The initial perturbation is imposed in three different ways: in density, in incident photon number flux, and in the surface shape. All cases show both stabilization for a small initial perturbation and large growth of the second harmonic by increasing amplitude of the initial perturbation above a critical value
A regional analysis of groundwater flow and salinity distribution in the Aespoe area

International Nuclear Information System (INIS)

Svensson, Urban

1997-05-01

A regional groundwater model of the Aespoe area has been formulated and applied. The model is three-dimensional, based on a grid of 100x100x36 cells and covers an area of 10x10 km 2 and a depth of 3 km. Equations are solved for the Darcy velocities and the salinity distribution, gravitational effects are thus fully accounted for. The model is used to simulate the general hydrology of the area as well as the influence of the Aespoe Hard Rock Laboratory (HRL). A specific task of the study is to evaluate relevant boundary conditions for the site-model and to show how these are influenced by Aespoe HRL. Studies of the stochastic conductivity field and the effect of density stratification are also reported. The general conclusion of the study is that the model provides a realistic and consistent picture of the area studied. Main arguments for this statement are: The formulation of the model is based on relevant conservation laws and embodies all physical processes believed to be important for the problem considered. The importance of gravitational forces is emphasised. A high resolution grid, which resolves topographical features and at the same time can simulate the effect of the HRL is used. Transmissivities and conductivities used in the model are based on field data. The model has been calibrated, using measured groundwater levels and salinity distributions with good results. A range of sensitivity studies has been carried out. These demonstrate that the model responds to variations in input data, for example the conductivity field in a realistic way. The model can thus be used to generate boundary conditions for a site scale model. The basic objective, to account for the regional influence in a site model, can hence be achieved. 7 refs, 32 figs
Aespoe Hard Rock Laboratory. Planning Report for 2009

Energy Technology Data Exchange (ETDEWEB)

2009-02-15

This report presents the planned activities for the year 2009. The report is revised annually and details the programme carried out in the Aespoe Hard Rock Laboratory as described in SKB's Research, Development and Demonstration Programme 2007, and serves as a basis for the management of the laboratory. The role of the Planning Report is to present the plans and scope of work for each project. Thereby the Status Reports may concentrate on work in progress and refers to this Planning Report for scope of work over the year. Background information on the projects is given in the Annual Report as well as findings and results.
Aespoe Hard Rock Laboratory. Planning Report for 2010

Energy Technology Data Exchange (ETDEWEB)

2010-05-15

This report presents the planned activities for the year 2010. The report is revised annually and details the programme carried out in the Aespoe Hard Rock Laboratory as described in SKB's Research, Development and Demonstration Programme 2007, and serves as a basis for the management of the laboratory. The role of the Planning Report is to present the plans and scope of work for each project. Thereby the Status Reports may concentrate on work in progress and refers to this Planning Report for scope of work over the year. Background information on the projects is given in the Annual Report as well as findings and results
Aespoe Hard Rock Laboratory. Planning Report for 2009

International Nuclear Information System (INIS)

2009-02-01

This report presents the planned activities for the year 2009. The report is revised annually and details the programme carried out in the Aespoe Hard Rock Laboratory as described in SKB's Research, Development and Demonstration Programme 2007, and serves as a basis for the management of the laboratory. The role of the Planning Report is to present the plans and scope of work for each project. Thereby the Status Reports may concentrate on work in progress and refers to this Planning Report for scope of work over the year. Background information on the projects is given in the Annual Report as well as findings and results
Aespoe Hard Rock Laboratory. Planning Report for 2010

International Nuclear Information System (INIS)

2010-05-01

This report presents the planned activities for the year 2010. The report is revised annually and details the programme carried out in the Aespoe Hard Rock Laboratory as described in SKB's Research, Development and Demonstration Programme 2007, and serves as a basis for the management of the laboratory. The role of the Planning Report is to present the plans and scope of work for each project. Thereby the Status Reports may concentrate on work in progress and refers to this Planning Report for scope of work over the year. Background information on the projects is given in the Annual Report as well as findings and results
A numerical simulation of the origin and composition of the groundwater below Aespoe

International Nuclear Information System (INIS)

Svensson, Urban

1999-02-01

An attempt is made to calculate the origin (in the time and space) of the waters found below Aespoe. It is assumed that the present water composition is due to the conditions prevailing after the last glaciation (initial conditions) and the hydrological events after this time (resulting in transient boundary conditions). The total time span simulated is from 10,000 years BP to 5 000 years AP. The different water types are tracked by solving an advection/diffusion equation for each of the identified water types. This novel technique is called the 'fluid population method' and is a simple and straightforward computational technique. Results from the simulation include the distribution of different water types in space and time and some detailed results for the conditions at 450 metres below Aespoe (water composition transport time to ground level). The main conclusion from the study is that the simulation model gives plausible results. However, the uncertainties about the basic conceptual model and the boundary conditions do not presently make a direct comparison with field data meaningful
A laboratory scale analysis of groundwater flow and salinity distribution in the Aespoe area

International Nuclear Information System (INIS)

Svensson, Urban

1999-12-01

This report concerns a study which was conducted for SKB. The conclusions and viewpoints presented in the report are those of the author(s) and do not necessarily coincide with those of the client. The objective of the study is to develop, calibrate and apply a numerical simulation model of the Aespoe Hard Rock Laboratory (HRL). An area of 800 x 600 centred around the HRL, gives the horizontal extent of the model. In the vertical direction the model covers the depth interval from 200 to 560 metres. The model is based on a mathematical model that includes equations for the Darcy velocities, mass conservation and salinity distribution. Gravitational effects are thus fully accounted for. A site scale groundwater model was used to generate boundary conditions for all boundaries. Transmissivities of major fracture zones are based on field data. Fractures and fracture zones with a length scale between 5 and 320 metres are accounted for by a novel method that is based on a discrete fracture network. A small background conductivity is added to account for fractures smaller than the grid size, which is metres. A calibration of the model is carried out, using field data from the Aespoe HRL. A satisfactory agreement with field data is obtained. Main results from the model include vertical and horizontal sections of flow, salinity and hydraulic head distributions for completed tunnel. A sensitivity study, where the properties of the conductivity field are modified, is also carried out. The general conclusion of the study is that the model developed can simulate the conditions at the Aespoe HRL in a realistic manner
Deformation-driven diffusion and plastic flow in amorphous granular pillars.

Science.gov (United States)

Li, Wenbin; Rieser, Jennifer M; Liu, Andrea J; Durian, Douglas J; Li, Ju

2015-06-01

We report a combined experimental and simulation study of deformation-induced diffusion in compacted quasi-two-dimensional amorphous granular pillars, in which thermal fluctuations play a negligible role. The pillars, consisting of bidisperse cylindrical acetal plastic particles standing upright on a substrate, are deformed uniaxially and quasistatically by a rigid bar moving at a constant speed. The plastic flow and particle rearrangements in the pillars are characterized by computing the best-fit affine transformation strain and nonaffine displacement associated with each particle between two stages of deformation. The nonaffine displacement exhibits exponential crossover from ballistic to diffusive behavior with respect to the cumulative deviatoric strain, indicating that in athermal granular packings, the cumulative deviatoric strain plays the role of time in thermal systems and drives effective particle diffusion. We further study the size-dependent deformation of the granular pillars by simulation, and find that different-sized pillars follow self-similar shape evolution during deformation. In addition, the yield stress of the pillars increases linearly with pillar size. Formation of transient shear lines in the pillars during deformation becomes more evident as pillar size increases. The width of these elementary shear bands is about twice the diameter of a particle, and does not vary with pillar size.
Mechanical properties of pillared-graphene nanostructures using molecular dynamics simulations

International Nuclear Information System (INIS)

Wang, Chih-Hao; Fang, Te-Hua; Sun, Wei-Li

2014-01-01

The deformation behaviour and mechanical properties of three-dimensional (3D) pillared graphene are investigated using molecular dynamics simulations. The Tersoff–Brenner many-body potential model is employed to evaluate the interactions between 3D pillared-graphene carbon atoms and nanotube carbons. The Lennard-Jones potential model is used to compute the interactions between a conical indenter and 3D pillared-graphene carbon atoms. The effects of the size and geometric structure of 3D pillared-graphene are evaluated in terms of the indentation force and contact stiffness. The simulation results for an armchair nanotube of 3D pillared graphene show that the contact stiffness increases with increasing chiral vector of the 3D-pillared graphene. However, the adhesive force sharply decreases with increasing chiral vector of the 3D-pillared graphene. A zigzag nanotube of 3D-pillared graphene exhibits better mechanical properties compared with those of the armchair nanotube. (paper)
PEDOT pillar fabrication using DOD inkjet system

Science.gov (United States)

Cui, Wei; Chang, Cheng-Ling; Wang, Wei-Chih

2012-04-01

In this paper, we present our preliminary results of high aspect ratio 3D PEDOT pillar study by drop-on demand (DOD) direct printing system. Design of the experimental setup and the fabrication of the DOD PEDOT pillar are introduced. Currently, the system can achieve a PEDOT pillar with a height of 300 μm and 80 μm in diameter. The proposed PEDOT 3D printing process has a wide range of potential applications in the eletronics and display industry.
Aespoe Hard Rock Laboratory. Overview of the investigations 1986-1990

International Nuclear Information System (INIS)

Stanfors, R.; Erlstroem, M.; Markstroem, I.

1991-06-01

In order to prepare for the siting and licensing of a spent fuel repository SKB has decided to construct a new underground research laboratory. The pre-investigations for the Aespoe Hard Rock Laboratory started in late 1986. This report gives a comprehensive compilation of the different investigations performed during the pre-investigation phase (1986-1990). The information is mainly compiled in CAD-generated maps and illustrations in which the reader can gather information concerning the scope of work as well as references to more detailed reports for further study. (au)
SITE-94. Geochemical characterization of Simpevarp ground waters near the Aespoe Hard Rock Laboratory

International Nuclear Information System (INIS)

Glynn, P.D.; Voss, C.I.

1999-09-01

The present report analyzes the geochemical data in order to evaluate collection and interpretation techniques that will be used to site the repository and to assess its safety. Ground waters near the Aespoe Hard Rock Laboratory (HRL) may be grouped into five chemically and isotopically distinct water types, on the basis of their deuterium and chloride contents: 1) recent waters, 2) 5 g/L chloride waters, 3) deep waters, 4) seawater imprint waters, and 5) glacial melt waters. The sampled ground waters show a progressive change from a predominantly NaHCO 3 composition at shallow depth to a CaCl 2 -rich composition at depth. Despite the proximity of the Baltic, relatively few of the sampled ground waters contain any evidence of a seawater component. This finding, together with the rather shallow depths at which saline waters were found, indicates that Aespoe island is presently in a regional ground-water discharge area. The chemical and isotopic composition of the sampled waters also indicates that local recharge of dilute recent waters occurs only down to shallow depths (generally less than 100 in). The Aespoe ground waters are sulfidic and do not presently contain any dissolved oxygen. Measured E H values are generally near -300 mV, and on average are only about 50 mV lower than E H values calculated from the sulfide/sulfate couple. Maintenance of reducing conditions, such as presently found at the Aespoe HRL, is an important consideration in assessing the performance of nuclear waste disposal sites. Measurements of dissolved radon and of uranium concentrations in fracture-fill materials were used to calculate an average effective flow-wetted surface area of 3.1 m 2 per liter of water for the Aespoe site. Estimation of flow-wetted surface areas is essential in determining the importance of matrix diffusion and surface sorption processes for radionuclide release calculations. The Rn calculation technique shows promise in helping narrow the possible range of values
Further validation of bracket pillar design methodology

CSIR Research Space (South Africa)

Vieira, F

1998-07-01

Full Text Available Design charts for bracket pillar design were developed under a previous SIMRAC project GAP 223 to provide rock mechanics engineers with an initial estimate of bracket pillar sizes for clearly identified geological discontinuities, based on mining...
Structural and neural network analyses of fracture systems at the Aespoe Hard Rock Laboratory, SE Sweden

International Nuclear Information System (INIS)

Sirat, M.

1999-01-01

The > 10,000 fractures documented in the 450 m deep Aespoe Hard Rock Laboratory (HRL) provide a unique opportunity to study brittle deformation of a Swedish bedrock mass. The fracture population consists of six major sets, one sub-horizontal and five sub-vertical. A classical structural analysis explored the interrelations between geometry and frequency of both dry and wet fractures with respect to depth and in-situ stresses. Three main findings are: In-situ stresses govern frequency distributions of dilated, hence water-bearing fractures. About 68.5% of sub-horizontal fractures are dilated in the thrust regime above a depth of ca. 230 m while 53% of sub-vertical fractures are dilated in the underlying wrench regime. Fractures curve both horizontally and vertically, a finding confirmed by the application of artificial neural networks that included Back-Propagation and Self-Organizing (Kohonen) networks. The asymmetry of the total fracture population and tilts of the sub-Cambrian peneplain demonstrates that multiple reactivations of fractures have tilted the Aespoe rock mass 6 deg to the west. The potential space problem raised by this tilt is negated by systematic curvature of steep fractures, some of which sole out to gently dipping fracture zones. Fractures probably developed their curvature when they formed deep in crystalline crust in Precambrian times but have since reactivated at shallow depths. These findings add significantly to the conceptual model of Aespoe and should be taken into account in future studies regarding the isolation of Sweden's high-grade radioactive waste in crystalline bedrock
Discussing three pillars of corporate governance

OpenAIRE

Andrei STĂNCULESCU; Eugen MITRICĂ

2015-01-01

This paper is a meaningful attempt to critically analyze the cohesion and relationship between three fundamental pillars of the corporate governance system: the shareholders, the board of directors and the employees. We present the characteristics of each pillar and discuss its relevance in corporate governance. A couple of world-renowned corporate governance models are considered. A synthetic conclusion is drawn based on information presented.
Suspension of Water Droplets on Individual Pillars

DEFF Research Database (Denmark)

Tóth, T.; Ferraro, D.; Chiarello, E.

2011-01-01

We report results of extensive experimental and numerical studies on the suspension of water drops deposited on cylindrical pillars having circular and square cross sections and different wettabilities. In the case of circular pillars, the drop contact line is pinned to the whole edge contour unt...

The Aespoe Hard Rock Laboratory: Final evaluation of the hydrogeochemical pre-investigations in relation to existing geologic and hydraulic conditions

International Nuclear Information System (INIS)

Smellie, J.; Laaksoharju, M.

1992-11-01

The Swedish Nuclear Fuel and Management Company (SKB) is currently excavating the access tunnel to an underground experimental laboratory, the Aespoe Hard Rock Laboratory, planned to be located some 500 m below the island of Aespoe which is located in the Simpevarp area, southeast Sweden. The construction of an underground laboratory forms part of the overall SKB strategy to test, not only the construction techniques for deep excavation, but also the various methods and protocols required to obtain a three-dimensional model of the geology and groundwater flow and chemistry, within a fractured crystalline bedrock similar to that envisaged for the final disposal of spent fuel. Aespoe was chosen because it geologically represents a variety of typical crystalline bedrock environments. The hydrogeochemical activities described and interpreted in this report form part of the initial pre-investigation phase (from the surface to around 1000 metres depth) aimed at siting the laboratory, describing the natural hydrogeological and hydrogeochemical conditions in the bedrock and predicting the changes that will occur during excavation and construction of the laboratory. Hydrogeochemical interpretation has therefore been closely integrated with the hydrogeological investigations and other disciplines of major influence, in particular, bedrock geology and geochemistry and fracture mineralogy and chemistry. A large section of this report has been devoted to the detailed investigation of each individual zone hydraulically selected, tested and sampled for hydrogeochemical characterization. The data have been used to describe the chemistry and origin of the Aespoe groundwaters, models have been developed to illustrate groundwater mixing and standard geochemical modelling approaches have been employed to understand rock/water interaction processes. An attempt has been made to integrate the hydrogeochemical information with known geological and hydrogeological parameters to construct a
Aespoe hard rock laboratory. Annual report 2000

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-06-01

The Aespoe Hard Rock Laboratory constitutes an important component of SKB's work to design, construct, and implement a deep geological repository for spent nuclear fuel and to develop and test methods for characterisation of selected repository sites. The retention effect of the rock has been studied by tracer tests in the Tracer Retention Understanding Experiments (TRUE) and the TRUE Block Scale (TRUE BS). These tests are supplemented by the new Long Term Diffusion Experiment (LTDE). During year 2000 the field experiments of TRUE BS (50 m scale) were completed and preparations made for the LTDE (migration through a fracture wall and into the rock), including boring of approximately 10 m deep hole with 300 mm diameter. Laboratory investigations have difficulties in simulating natural conditions and need supplementary field studies to support validation exercises. A special borehole probe, CHEMLAB, has therefore been designed for different kinds of validation experiments where data can be obtained representative for the in-situ properties of groundwater at repository depth. During 2000 migration experiments were made with actinides (Am, Np and Pu) in CHEMLAB 2, the simplified supplement to CHEMLAB 1. Colloids of nuclides as well as of bentonite might affect the migration of released radionuclides and a separate project was planned during 2000 to assess the existence, stability and mobility of colloids. The development of numerical modelling tools continues with the general objective to improve the numerical models in terms of flow and transport and to update the site-scale and laboratory scale models for the Aespoe HRL. The Matrix Fluid Chemistry project aims at determining the origin and age of matrix fluids and the experiment has been designed to sample matrix fluids from predetermined, isolated borehole sections by specialised equipment. The Aespoe HRL also has the task to demonstrate and perform full scale tests of the function of different components of
Merensky pillar strength formulae based on back-analysis of pillar failures at Impala Platinum

CSIR Research Space (South Africa)

Watson, BP

2008-08-01

Full Text Available , with and without a large flanking area of mining. Such factors were generally less than 1.2 (20% correction), and were, where feasible, checked using Equation [1]4. This equation may be used if there is a large sea of mining with roughly uniform convergence... for pillars that are allowed to punch, as well as for pillars that are surrounded by an infinitely strong rock mass; high density mesh and varying brittleness Table IV Material and model properties �3 Co �0 �res �pr �0 �res (MPa) (MPa) (m�) A 2 15 55 50...
The Three Pillars of Machine Programming

OpenAIRE

Gottschlich, Justin; Solar-Lezama, Armando; Tatbul, Nesime; Carbin, Michael; Rinard, Martin; Barzilay, Regina; Amarasinghe, Saman; Tenenbaum, Joshua B; Mattson, Tim

2018-01-01

In this position paper, we describe our vision of the future of machine programming through a categorical examination of three pillars of research. Those pillars are: (i) intention, (ii) invention, and(iii) adaptation. Intention emphasizes advancements in the human-to-computer and computer-to-machine-learning interfaces. Invention emphasizes the creation or refinement of algorithms or core hardware and software building blocks through machine learning (ML). Adaptation emphasizes advances in t...
FEBEX bentonite colloid stability in ground water

Energy Technology Data Exchange (ETDEWEB)

Seher, H.; Schaefer, T.; Geckeis, H. [Inst. fuer Nukleare Entsorgung (INE), Forschungszentrum Karlsruhe, 76021 Karlsruhe (Germany)]. e-mail: holger.seher@ine.fzk .de; Fanghaenel, T. [Ruprecht-Karls-Univ. Heidelberg, Physikalisch-Chemisches In st., D-69120 Heidelberg (Germany)

2007-06-15

Coagulation experiments are accomplished to identify the geochemical conditions for the stability of Febex bentonite colloids in granite ground water. The experiments are carried out by varying pH, ionic strength and type of electrolyte. The dynamic light scattering technique (photon correlation spectroscopy) is used to measure the size evolution of the colloids with time. Agglomeration rates are higher in MgCl{sub 2} and CaCl{sub 2} than in NaCl solution. Relative agglomeration rates follow approximately the Schulze-Hardy rule. Increasing agglomeration rates at pH>8 are observed in experiments with MgCl{sub 2} and CaCl{sub 2} which are, however, caused by coprecipitation phenomena. Bentonite colloid stability fields derived from the colloid agglomeration experiments predict low colloid stabilization in granite ground water taken from Aespoe, Sweden, and relatively high colloid stability in Grimsel ground water (Switzerland)
POROUS MEMBRANE TEMPLATED SYNTHESIS OF POLYMER PILLARED LAYER

Institute of Scientific and Technical Information of China (English)

Zhong-wei Niu; Dan Li; Zhen-zhong Yang

2003-01-01

The anodic porous alumina membranes with a definite pore diameter and aspect ratio were used as templates to synthesize polymer pillared layer structures. The pillared polymer was produced in the template membrane pores, and the layer on the template surfaces. Rigid cured epoxy resin, polystyrene and soft hydrogel were chosen to confirm the methodology. The pillars were in the form of either tubes or fibers, which were controlled by the alumina membrane pore surface wettability. The structural features were confirmed by scanning electron microscopy results.
Removal of nitrate by zero-valent iron and pillared bentonite

International Nuclear Information System (INIS)

Li Jianfa; Li Yimin; Meng Qingling

2010-01-01

The pillared bentonite prepared by intercalating poly(hydroxo Al(III)) cations into bentonite interlayers was used together with Fe(0) for removing nitrate in column experiments. The obvious synergetic effect on nitrate removal was exhibited through uniformly mixing the pillared bentonite with Fe(0). In such a mixing manner, the nitrate was 100% removed, and the removal efficiency was much higher than the simple summation of adsorption by the pillared bentonite and reduction by Fe(0). The influencing factors such as bentonite type, amount of the pillared bentonite and initial pH of nitrate solutions were investigated. In this uniform mixture, the pillared bentonite could adsorb nitrate ions, and facilitated the mass transfer of nitrate onto Fe(0) surface, then accelerated the nitrate reduction. The pillared bentonite could also act as the proton-donor, and helped to keep the complete nitrate removal for at least 10 h even when the nitrate solution was fed at nearly neutral pH.
Current practice and guidelines for the safe design of water barrier pillars

CSIR Research Space (South Africa)

Rangasamy, T

2001-08-01

Full Text Available adjacent to barrier pillars was conducted to ascertain the relationship between compartment water head, barrier pillar width and flow rates for combinations of roof bound, coal bound and floor bound flow. The results obtained from the instrumentation... pillars. A survey of South African Collieries revealed that water leakage associated with barrier pillars can be classed into seven predominant geotechnical flow categories. Through extensive numerical modelling and case history matching, barrier pillar...
Rib-pillar mining at Sigma Colliery

Energy Technology Data Exchange (ETDEWEB)

De Beer, J J.S.; Hunter, F; Neethling, A F [Sigma Colliery, Sasolburg (South Africa)

1991-06-01

The paper describes the rib-pillar extraction method now used at Sigma Colliery in the Orange Free State. In this method, access roadways (with a high safety factor) are developed into a block of coal suitable for total extraction; pillars that have a low safety factor are then formed and extracted immediately. The method, together with the current practices of labour management, has resulted in better utilization of the coal resources and capital, increased production and labour productivity, and improved safety. 11 figs.
Stability assessment of the stopes and crown pillar of the S’Argentera abandoned mines (Ibiza, Spain) using geomechanical classifications, an empirical approach and numerical analysis focused on a possible tourist exploitation

International Nuclear Information System (INIS)

Jordá-Bordehore, L.; Jordá-Bordehore, R.; Durán Valsero, J.J.; Romero-Crespo, P.L.

2017-01-01

The argentiferous lead mines of S’Argentera in Ibiza (Balearic Islands, Spain) are some abandoned underground workings from the first decade of the 20th century. The stability of the main stopes and the crown pillar of the mines has been evaluated - part of which is located below the road between Santa Eulalia and San Carles de Peralta. The possibility of allowing public access to the surface of the mining area and setting up a project of a “show mine” on the underground stopes and galleries is analysed. The stability is assessed with an empirical approach using the O index, the scaled span method and a stability graph together with a numerical approach. Results show that the stopes of the mines are globally stable but some lack an adequate safety factor. Therefore some local reinforcements and monitoring are needed. The finite element modelling in two dimensions yields realistic results on the current stope stability and possible rock falls which have already occurred. [es
Acid–base properties of pillared interlayered clays with single and mixed Zr–Al oxide pillars prepared from Tunisian-interstratified illite–smectite

Directory of Open Access Journals (Sweden)

Saida Mnasri

2017-12-01

Full Text Available Interstratified illite–smectite clay samples from Tunisia have been used in order to prepare Al, Zr and Zr–Al-pillared clays. Several Al/metal, OH/metal ratios were used in order to investigate the effect on the chemical and physical properties, specifically the point of zero charge (PZC of the synthesized pillared clays. The structure of the pillared materials is studied by XRD and cationic exchange capacity. The textural property is investigated by the nitrogen adsorption/desorption method. The acid–base chemistry “surface acidity” of these products was analysed by using mass and potentiometric titration in order to determine the PZC and the equilibrium constants (pKa of each sample. The resulting materials exhibited basal spacings in the range of 17.4–20.5 Å, with high surface areas (134–199 m2 g−1. Titration curves obtained by acid–base potentiometric titration for the starting material showed an indistinct cross-over point at about pH = 7.3, whereas in the case of pillared samples, points were observed at the acidic region between 4 and 6. In addition, the calculated pKas values of pillared clays show a shifting to the acidic values compared to the untreated sample.
Fold catastrophe model of dynamic pillar failure in asymmetric mining

Energy Technology Data Exchange (ETDEWEB)

Yue Pan; Ai-wu Li; Yun-song Qi [Qingdao Technological University, Qingdao (China). College of Civil Engineering

2009-01-15

A rock burst disaster not only destroys the pit facilities and results in economic loss but it also threatens the life of the miners. Pillar rock burst has a higher frequency of occurrence in the pit compared to other kinds of rock burst. Understanding the cause, magnitude and prevention of pillar rock burst is a significant undertaking. Equations describing the bending moment and displacement of the rock beam in asymmetric mining have been deduced for simplified asymmetric beam-pillar systems. Using the symbolic operation software MAPLE 9.5 a catastrophe model of the dynamic failure of an asymmetric rock-beam pillar system has been established. The differential form of the total potential function deduced from the law of conservation of energy was used for this deduction. The critical conditions and the initial and final positions of the pillar during failure have been given in analytical form. The amount of elastic energy released by the rock beam at the instant of failure is determined as well. A diagrammatic form showing the pillar failure was plotted using MATLAB software. This graph contains a wealth of information and is important for understanding the behavior during each deformation phase of the rock-beam pillar system. The graphic also aids in distinguishing the equivalent stiffness of the rock beam in different directions. 11 refs., 8 figs.
Aespoe Hard Rock Laboratory Annual Report 1994

International Nuclear Information System (INIS)

1995-04-01

The Aespoe Hard Rock Laboratory is being constructed as part of the preparations for the deep geological repository of spent nuclear fuel in Sweden. The annual report 1994 contains an overview of the work conducted. Present work is focused on verification of pre-investigation methods and development of detailed investigation methodology which is applied during tunnel construction. Construction of the facility and detailed characterization of the bedrock are performed in parallel. Excavation of the main access tunnel was completed during 1994 and at the end of the year only minor excavation work remained. The last 400 m of the main tunnel, which has a total length of 3600 m, was excavated by a 5 m diameter boring machine. The tunnel reaches a depth of 450 m below ground. Preparations for the operating phase have started and detailed plans have been prepared for several experiments. Nine organizations, including SKB, from eight countries are now participating in the work at the laboratory. 50 refs, 28 figs
Aespoe Hard Rock Laboratory Annual Report 1994

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-04-01

The Aespoe Hard Rock Laboratory is being constructed as part of the preparations for the deep geological repository of spent nuclear fuel in Sweden. The annual report 1994 contains an overview of the work conducted. Present work is focused on verification of pre-investigation methods and development of detailed investigation methodology which is applied during tunnel construction. Construction of the facility and detailed characterization of the bedrock are performed in parallel. Excavation of the main access tunnel was completed during 1994 and at the end of the year only minor excavation work remained. The last 400 m of the main tunnel, which has a total length of 3600 m, was excavated by a 5 m diameter boring machine. The tunnel reaches a depth of 450 m below ground. Preparations for the operating phase have started and detailed plans have been prepared for several experiments. Nine organizations, including SKB, from eight countries are now participating in the work at the laboratory. 50 refs, 28 figs.
Mechanisms for redox control and their effects upon modelled properties of Aespoe groundwaters

International Nuclear Information System (INIS)

Emren, A.T.

1996-01-01

In the literature, one finds several models for control of redox properties in groundwater. The proposals for redox controlling substances include iron oxides, chlorites, methane, pyrite and polysulphides. The CRACKER program, which has been successful in modelling of observed Aespoe groundwaters has been used to investigate the influence of several redox control models on the modelled properties of present and possible future Aespoe groundwaters. In the simulations, one or more of the possible redox reactions have been prevented from occurring. The groundwater has then been assumed to react with minerals distributed in the fracture walls. Due to the discreteness of mineral grains, a certain amount of fluctuations in groundwater properties is occurring. The process of sampling water for measurement has been simulated by letting about 900 waters from different locations mix. It has been found that some of the models have difficulties in explaining important groundwater properties, while other models perform quite well. With identical mineral sets, the properties of future groundwaters have been simulated. It is found that some changes in groundwater properties at elevated temperatures may be of importance for assessment of the safety of a future repository for spent nuclear fuel. The difference in behaviour is caused mostly by the fact that the solubility increases with temperature for some minerals, while it decreases for other minerals. (author)
Aespoe Hard Rock Laboratory. Studies of factors that affect and controls the Excavation Damaged/Disturbed Zone

International Nuclear Information System (INIS)

Jonsson, Martin; Baeckstroem, Ann; Quanhong Feng; Berglund, Johan; Johansson, Malin; Mas Ivars, Diego; Olsson, Mats

2009-05-01

A tunnel was developed at the Aespoe Hard Rock Laboratory (HRL) in 2003 purposely for a large in-situ rock mechanics experiment, the Aespoe Pillar Stability Experiment (APSE). The tunnel had a large height/width ratio with a circular floor, primarily to control the stress situation around the tunnel and concentrate the stresses under the floor. An extensive set of data for understanding the Excavation Damaged Zone (EDZ) was collected within section 47 of the tunnel. It consist of the blast design, blast sequences, convergence measurements during excavation, geological mapping of tunnel and cores, 3D-laser scanning of the tunnel geometry etc. Furthermore, in 2006, ultrasonic measurements along eight boreholes were carried out in order to estimate the extent of the EDZ in the tunnel. The collection of all these different information provides an opportunity to evaluate the mechanical damages caused by the excavation work. The overall aim with this project is to give feed-back to future planning of tunnelling on issues of importance for requirements with respect to minimising the EDZ in crystalline rock from the drill and blast method. A combination of the mapped geological features (tunnel and cores) and the geometry of the blasted tunnel obtained from the 3D-laser scanning were used to build a 3D model of the geology with emphasis on the geometry of the natural fractures. The rock mechanic response to the tunnelling was evaluated in a numerical model including the as-built geometry in combination with the 3D model of the geology. The modelling of the rock mechanical processes of importance for the EDZ could be calibrated against actual measurements. From observed changes in the ultrasonic wave velocity along the boreholes it was found that the locations of the velocity changes corresponded well with the location of the mapped fractures in the drill cores. This indicates that EDZ can be detected using the ultrasonic method with high accuracy. Furthermore, the
Aespoe Hard Rock Laboratory. Studies of factors that affect and controls the Excavation Damaged/Disturbed Zone

Energy Technology Data Exchange (ETDEWEB)

Jonsson, Martin; Baeckstroem, Ann; Quanhong Feng (AaF - Berg och Maetteknik, Stockholm (Sweden)); Berglund, Johan (Vattenfall Power Consultant, Stockholm (Sweden)); Johansson, Malin; Mas Ivars, Diego (Itasca Geomekanik AB, Solna (Sweden)); Olsson, Mats (SweBefo, Stockholm (Sweden))

2009-07-15

A tunnel was developed at the Aespoe Hard Rock Laboratory (HRL) in 2003 purposely for a large in-situ rock mechanics experiment, the Aespoe Pillar Stability Experiment (APSE). The tunnel had a large height/width ratio with a circular floor, primarily to control the stress situation around the tunnel and concentrate the stresses under the floor. An extensive set of data for understanding the Excavation Damaged Zone (EDZ) was collected within section 47 of the tunnel. It consist of the blast design, blast sequences, convergence measurements during excavation, geological mapping of tunnel and cores, 3D-laser scanning of the tunnel geometry etc. Furthermore, in 2006, ultrasonic measurements along eight boreholes were carried out in order to estimate the extent of the EDZ in the tunnel. The collection of all these different information provides an opportunity to evaluate the mechanical damages caused by the excavation work. The overall aim with this project is to give feed-back to future planning of tunnelling on issues of importance for requirements with respect to minimising the EDZ in crystalline rock from the drill and blast method. A combination of the mapped geological features (tunnel and cores) and the geometry of the blasted tunnel obtained from the 3D-laser scanning were used to build a 3D model of the geology with emphasis on the geometry of the natural fractures. The rock mechanic response to the tunnelling was evaluated in a numerical model including the as-built geometry in combination with the 3D model of the geology. The modelling of the rock mechanical processes of importance for the EDZ could be calibrated against actual measurements. From observed changes in the ultrasonic wave velocity along the boreholes it was found that the locations of the velocity changes corresponded well with the location of the mapped fractures in the drill cores. This indicates that EDZ can be detected using the ultrasonic method with high accuracy. Furthermore, the
SITE-94. Geochemical characterization of Simpevarp ground waters near the Aespoe Hard Rock Laboratory

Energy Technology Data Exchange (ETDEWEB)

Glynn, P D; Voss, C I [US Geological Survey, Reston, VA (United States)

1999-09-01

The present report analyzes the geochemical data in order to evaluate collection and interpretation techniques that will be used to site the repository and to assess its safety. Ground waters near the Aespoe Hard Rock Laboratory (HRL) may be grouped into five chemically and isotopically distinct water types, on the basis of their deuterium and chloride contents: 1) recent waters, 2) 5 g/L chloride waters, 3) deep waters, 4) seawater imprint waters, and 5) glacial melt waters. The sampled ground waters show a progressive change from a predominantly NaHCO{sub 3} composition at shallow depth to a CaCl{sub 2}-rich composition at depth. Despite the proximity of the Baltic, relatively few of the sampled ground waters contain any evidence of a seawater component. This finding, together with the rather shallow depths at which saline waters were found, indicates that Aespoe island is presently in a regional ground-water discharge area. The chemical and isotopic composition of the sampled waters also indicates that local recharge of dilute recent waters occurs only down to shallow depths (generally less than 100 in). The Aespoe ground waters are sulfidic and do not presently contain any dissolved oxygen. Measured E{sub H} values are generally near -300 mV, and on average are only about 50 mV lower than E{sub H} values calculated from the sulfide/sulfate couple. Maintenance of reducing conditions, such as presently found at the Aespoe HRL, is an important consideration in assessing the performance of nuclear waste disposal sites. Measurements of dissolved radon and of uranium concentrations in fracture-fill materials were used to calculate an average effective flow-wetted surface area of 3.1 m{sup 2} per liter of water for the Aespoe site. Estimation of flow-wetted surface areas is essential in determining the importance of matrix diffusion and surface sorption processes for radionuclide release calculations. The Rn calculation technique shows promise in helping narrow the
Aluminium - Cobalt-Pillared Clay for Dye Filtration Membrane

Science.gov (United States)

Darmawan, A.; Widiarsih

2018-04-01

The manufacture of membrane support from cobalt aluminium pillared clay has been conducted. This research was conducted by mixing a clay suspension with pillared solution prepared from the mixture of Co(NO3)2.6H2O and AlCl3.6H2O. The molar ratio between Al and Co was 75:25 and the ratio of [OH-]/[metal] was 2. The clay suspension was stirred for 24 hours at room temperature, filtered and dried. The dried clay was then calcined at 200°C, 300°C and 400°C with a ramp rate of 2°C/min. Aluminium-cobalt-pillared clay was then characterized by XRD and GSA and moulded become a membrane support for subsequent tests on dye filtration. The XRD analysis showed that basal spacing (d 001) value of aluminium cobalt was 19.49 Å, which was higher than the natural clay of 15.08Å however, the basal spacing decreased with increasing calcination temperature. The result of the GSA analysis showed that the pore diameter of the aluminium cobalt pillared clay membrane was almost the same as that of natural clay that were 34.5Å and 34.2Å, respectively. Nevertheless, the pillared clay has a more uniform pore size distribution. The results of methylene blue filtration measurements demonstrated that the membrane filter support could well which shown by a clear filtrate at all concentrations tested. The value of rejection and flux decreased with the increasing concentration of methylene blue. The values of dye rejection and water flux reached 99.89% and 5. 80 x 10-6 kg min-1, respectively but they decreased with increasing concentration of methylene blue. The results of this study indicates that the aluminium-pillared clay cobalt could be used as membrane materials especially for ultrafiltration.
Develop guidelines for the design of pillar systems for shallow and intermediate depth, tabular, hard rock mines and provide methodology for assessing hangingwall stability and support requirements for the panels between pillars

CSIR Research Space (South Africa)

Haile, AT

1995-12-01

Full Text Available The overall view of the research being conducted at Impala platinum was to improve pillar design techniques through a rock testing programme, underground instrumentation and back analysis. The laboratory rock testing programme has provided a useful...

Hydrogeological pre-modelling exercises. Assessment of impact of the Aespoe Hard Rock Laboratory. Sensitivities of palaeo-hydrogeology. Development of a local near-surface Hydro-DFN for KLX09B-F. Site descriptive modelling SDM-Site Laxemar

International Nuclear Information System (INIS)

Hartley, Lee; Jackson, Peter; Joyce, Steve; Roberts, David; Shevelan, John; Swift, Ben; Gylling, Bjoern; Marsic, Niko; Hermanson, Jan; Oehman, Johan

2007-12-01

Numerical modelling has been used to investigate the potential impact of the Aespoe HRL on regional groundwater flow and hydro-geochemistry in the Laxemar study area. The numerical models have been adapted for this application from the ones use in the site-descriptive modelling (SDM) and SR-Can assessment modelling based on Laxemar version 1.2. In order to test the robustness of the simulation results, sensitivities were studied with respect to different flow boundary conditions and the hydraulic properties of the Quaternary deposits, particularly those beneath the sea around the Aespoe island. The simulations show that the Aespoe HRL has a local effect on the groundwater situation. Typically, in the simulations, the rock under the Aespoe island, the bays around it and the Aevroe area (mainly western part of the islands of Aevroe, Mjaelen and Haaloe) are influenced. In the sensitivity study, visualisations of the drawdown caused by the HRL tunnel system show small differences in the results for head versus flux top boundary conditions, little sensitivity to a change in the surface infiltration rate, but most sensitivity to the contact between the sea and the bedrock beneath the seabed sediments. For all simulation cases considered, results suggest that the Aespoe HRL has not been in operation sufficiently long to have affected the chemistry of samples collected at Laxemar and Simpevarp, though there is some possibility that Aevroe samples have been altered, at least for boreholes in the western part of Aevroe, Mjaelen and Haaloe. The distribution of flow and discharge areas around the bay at Aespoe is clearly affected by the HRL for all cases. Using the drawdown in percussion drilled boreholes around Aespoe as an interference test suggests that there is a partial reduction in the hydraulic contact between the sea and the groundwater system in the bedrock beneath. It is recommended that the conclusions about appropriate hydraulic properties for Quaternary sediments
Hydrogeological pre-modelling exercises. Assessment of impact of the Aespoe Hard Rock Laboratory. Sensitivities of palaeo-hydrogeology. Development of a local near-surface Hydro-DFN for KLX09B-F. Site descriptive modelling SDM-Site Laxemar

Energy Technology Data Exchange (ETDEWEB)

Hartley, Lee; Jackson, Peter; Joyce, Steve; Roberts, David; Shevelan, John; Swift, Ben (Serco Assurance, Harwell (GB)); Gylling, Bjoern; Marsic, Niko (Kemakta Konsult AB, Stockholm (SE)); Hermanson, Jan; Oehman, Johan (Golders Associates (SE))

2007-12-15

Numerical modelling has been used to investigate the potential impact of the Aespoe HRL on regional groundwater flow and hydro-geochemistry in the Laxemar study area. The numerical models have been adapted for this application from the ones use in the site-descriptive modelling (SDM) and SR-Can assessment modelling based on Laxemar version 1.2. In order to test the robustness of the simulation results, sensitivities were studied with respect to different flow boundary conditions and the hydraulic properties of the Quaternary deposits, particularly those beneath the sea around the Aespoe island. The simulations show that the Aespoe HRL has a local effect on the groundwater situation. Typically, in the simulations, the rock under the Aespoe island, the bays around it and the Aevroe area (mainly western part of the islands of Aevroe, Mjaelen and Haaloe) are influenced. In the sensitivity study, visualisations of the drawdown caused by the HRL tunnel system show small differences in the results for head versus flux top boundary conditions, little sensitivity to a change in the surface infiltration rate, but most sensitivity to the contact between the sea and the bedrock beneath the seabed sediments. For all simulation cases considered, results suggest that the Aespoe HRL has not been in operation sufficiently long to have affected the chemistry of samples collected at Laxemar and Simpevarp, though there is some possibility that Aevroe samples have been altered, at least for boreholes in the western part of Aevroe, Mjaelen and Haaloe. The distribution of flow and discharge areas around the bay at Aespoe is clearly affected by the HRL for all cases. Using the drawdown in percussion drilled boreholes around Aespoe as an interference test suggests that there is a partial reduction in the hydraulic contact between the sea and the groundwater system in the bedrock beneath. It is recommended that the conclusions about appropriate hydraulic properties for Quaternary sediments
Superhydrophobic analyte concentration utilizing colloid-pillar array SERS substrates.

Science.gov (United States)

Wallace, Ryan A; Charlton, Jennifer J; Kirchner, Teresa B; Lavrik, Nickolay V; Datskos, Panos G; Sepaniak, Michael J

2014-12-02

The ability to detect a few molecules present in a large sample is of great interest for the detection of trace components in both medicinal and environmental samples. Surface enhanced Raman spectroscopy (SERS) is a technique that can be utilized to detect molecules at very low absolute numbers. However, detection at trace concentration levels in real samples requires properly designed delivery and detection systems. The following work involves superhydrophobic surfaces that have as a framework deterministic or stochastic silicon pillar arrays formed by lithographic or metal dewetting protocols, respectively. In order to generate the necessary plasmonic substrate for SERS detection, simple and flow stable Ag colloid was added to the functionalized pillar array system via soaking. Native pillars and pillars with hydrophobic modification are used. The pillars provide a means to concentrate analyte via superhydrophobic droplet evaporation effects. A ≥ 100-fold concentration of analyte was estimated, with a limit of detection of 2.9 × 10(-12) M for mitoxantrone dihydrochloride. Additionally, analytes were delivered to the surface via a multiplex approach in order to demonstrate an ability to control droplet size and placement for scaled-up uses in real world applications. Finally, a concentration process involving transport and sequestration based on surface treatment selective wicking is demonstrated.
Numerical Analysis on Failure Modes and Mechanisms of Mine Pillars under Shear Loading

Directory of Open Access Journals (Sweden)

Tianhui Ma

2016-01-01

Full Text Available Severe damage occurs frequently in mine pillars subjected to shear stresses. The empirical design charts or formulas for mine pillars are not applicable to orebodies under shear. In this paper, the failure process of pillars under shear stresses was investigated by numerical simulations using the rock failure process analysis (RFPA 2D software. The numerical simulation results indicate that the strength of mine pillars and the corresponding failure mode vary with different width-to-height ratios and dip angles. With increasing dip angle, stress concentration first occurs at the intersection between the pillar and the roof, leading to formation of microcracks. Damage gradually develops from the surface to the core of the pillar. The damage process is tracked with acoustic emission monitoring. The study in this paper can provide an effective means for understanding the failure mechanism, planning, and design of mine pillars.
Discrete-feature modelling of the Aespoe Site: 1. Discrete-fracture network models for the repository scale

International Nuclear Information System (INIS)

Geier, J.E.; Thomas, A.L.

1996-08-01

This report describes the statistical derivation and partial validation of discrete-fracture network (DFN) models for the rock beneath the island of Aespoe in southeastern Sweden. The purpose was to develop DFN representations of the rock mass within a hypothetical, spent-fuel repository, located under Aespoe. Analyses are presented for four major lithologic types, with separate analyses of the rock within fracture zones, the rock excluding fracture zones, and all rock. Complete DFN models are proposed as descriptions of the rock mass in the near field. The procedure for validation, by comparison between actual and simulated packer tests, was found to be useful for discriminating among candidate DFN models. In particular, the validation approach was shown to be sensitive to a change in the fracture location (clustering) model, and to a change in the variance of single-fracture transmissivity. The proposed models are defined in terms of stochastic processes and statistical distributions, and thus are descriptive of the variability of the fracture system. This report includes discussion of the numerous sources of uncertainty in the models, including uncertainty that results from the variability of the natural system. 62 refs
Active containment systems incorporating modified pillared clays

International Nuclear Information System (INIS)

Lundie, P.; McLeod, N.

1997-01-01

The application of treatment technologies in active containment systems provides a more advanced and effective method for the remediation of contaminated sites. These treatment technologies can be applied in permeable reactive walls and/or funnel and gate systems. The application of modified pillared clays in active containment systems provides a mechanism for producing permeable reactive walls with versatile properties. These pillared clays are suitably modified to incorporate reactive intercalatants capable of reacting with both a broad range of organic pollutants of varying molecular size, polarity and reactivity. Heavy metals can be removed from contaminated water by conventional ion-exchange and other reactive processes within the clay structure. Complex contamination problems can be addressed by the application of more than one modified clay on a site specific basis. This paper briefly describes the active containment system and the structure/chemistry of the modified pillared clay technology, illustrating potential applications of the in-situ treatment process for contaminated site remediation
Asymmetric liquid wetting and spreading on surfaces with slanted micro-pillar arrays

KAUST Repository

Yang, Xiaoming

2013-01-01

Uni-directional liquid spreading on asymmetric silicone-fabricated nanostructured surfaces has recently been reported. In this work, uniformly deflected polydimethylsiloxane (PDMS) micro-pillars covered with silver films were fabricated. Asymmetric liquid wetting and spreading behaviors in a preferential direction were observed on the slanted micro-pillar surfaces and a micro-scale thin liquid film advancing ahead of the bulk liquid droplet was clearly observed by high-speed video imaging. It is found that the slanted micro-pillar array is able to promote or inhibit the propagation of this thin liquid film in different directions by the asymmetric capillary force. The spreading behavior of the bulk liquid was guided and finally controlled by this micro-scale liquid film. Different spreading regimes are defined by the relationship between the liquid intrinsic contact angle and the critical angles, which were determined by the pillar height, pillar deflection angle and inter-pillar spacing. © The Royal Society of Chemistry 2013.
Scattering of spermatozoa off cylindrical pillars

Science.gov (United States)

Bukatin, Anton; Lushi, Enkeleida; Kantsler, Vasily

2017-11-01

The motion of micro-swimmers in structured environments, even though crucial in processes such as in vivo and in vitro egg fertilization, is still not completely understood. We combine microfluidic experiments with mathematical modeling of 3D swimming near convex surfaces to quantify the dynamics of individual sperm cells in the proximity of cylindrical pillars. Our results show that the hydrodynamic and contact forces that account for the shape asymmetry and flagellar motion, are crucial in correctly describing the dynamics observed in the experiments. Last, we discuss how the size of the cylindrical obstacles determines whether the swimmers scatter off or get trapped circling the pillar.
Analysis and Optimization of Entry Stability in Underground Longwall Mining

Directory of Open Access Journals (Sweden)

Yubing Gao

2017-11-01

Full Text Available For sustainable utilization of limited coal resources, it is important to increase the coal recovery rate and reduce mine accidents, especially those occurring in the entry (gateroad. Entry stabilities are vital for ventilation, transportation and other essential services in underground coal mining. In the present study, a finite difference model was built to investigate stress evolutions around the entry, and true triaxial tests were carried out at the laboratory to explore entry wall stabilities under different mining conditions. The modeling and experimental results indicated that a wide coal pillar was favorable for entry stabilities, but oversize pillars caused a serious waste of coal resources. As the width of the entry wall decreased, the integrated vertical stress, induced by two adjacent mining panels, coupled with each other and experienced an increase on the entry wall, which inevitably weakened the stability of the entry. Therefore, mining with coal pillars always involves a tradeoff between economy and safety. To address this problem, an innovative non-pillar mining technique by optimizing the entry surrounding structures was proposed. Numerical simulation showed that the deformation of the entry roof decreased by approximately 66% after adopting the new approach, compared with that using the conventional mining method. Field monitoring indicated that the stress condition of the entry was signiﬁcantly improved and the average roof pressure decreased by appropriately 60.33% after adopting the new technique. This work provides an economical and effective approach to achieve sustainable exploitation of underground coal resources.
Aespoe Hard Rock Laboratory. Analysis of fracture networks based on the integration of structural and hydrogeological observations on different scales

Energy Technology Data Exchange (ETDEWEB)

Bossart, P. [Geotechnical Inst. Ltd., Bern (Switzerland); Hermanson, Jan [Golder Associates, Stockholm (Sweden); Mazurek, M. [Univ. of Bern (Switzerland)

2001-05-01

Fracture networks at Aespoe have been studied for several rock types exhibiting different degrees of ductile and brittle deformation, as well as on different scales. Mesoscopic fault systems have been characterised and classified in an earlier report, this report focuses mainly on fracture networks derived on smaller scales, but also includes mesoscopic and larger scales. The TRUE-1 block has been selected for detailed structural analysis on a small scale due to the high density of relevant information. In addition to the data obtained from core materials, structural maps, BIP data and the results of hydro tests were synthesised to derive a conceptual structural model. The approach used to derive this conceptual model is based on the integration of deterministic structural evidence, probabilistic information and both upscaling and downscaling of observations and concepts derived on different scales. Twelve fracture networks mapped at different sites and scales and exhibiting various styles of tectonic deformation were analysed for fractal properties and structural and hydraulic interconnectedness. It was shown that these analysed fracture networks are not self-similar. An important result is the structural and hydraulic interconnectedness of fracture networks on all scales in the Aespoe rocks, which is further corroborated by geochemical evidence. Due to the structural and hydraulic interconnectedness of fracture systems on all scales at Aespoe, contaminants from waste canisters placed in tectonically low deformation environments would be transported - after having passed through the engineered barriers -from low-permeability fractures towards higher permeability fractures and may thus eventually reach high-permeability features.
Aespoe Hard Rock Laboratory. Analysis of fracture networks based on the integration of structural and hydrogeological observations on different scales

International Nuclear Information System (INIS)

Bossart, P.; Hermanson, Jan; Mazurek, M.

2001-05-01

Fracture networks at Aespoe have been studied for several rock types exhibiting different degrees of ductile and brittle deformation, as well as on different scales. Mesoscopic fault systems have been characterised and classified in an earlier report, this report focuses mainly on fracture networks derived on smaller scales, but also includes mesoscopic and larger scales. The TRUE-1 block has been selected for detailed structural analysis on a small scale due to the high density of relevant information. In addition to the data obtained from core materials, structural maps, BIP data and the results of hydro tests were synthesised to derive a conceptual structural model. The approach used to derive this conceptual model is based on the integration of deterministic structural evidence, probabilistic information and both upscaling and downscaling of observations and concepts derived on different scales. Twelve fracture networks mapped at different sites and scales and exhibiting various styles of tectonic deformation were analysed for fractal properties and structural and hydraulic interconnectedness. It was shown that these analysed fracture networks are not self-similar. An important result is the structural and hydraulic interconnectedness of fracture networks on all scales in the Aespoe rocks, which is further corroborated by geochemical evidence. Due to the structural and hydraulic interconnectedness of fracture systems on all scales at Aespoe, contaminants from waste canisters placed in tectonically low deformation environments would be transported - after having passed through the engineered barriers -from low-permeability fractures towards higher permeability fractures and may thus eventually reach high-permeability features
Field emission from a single nanomechanical pillar

International Nuclear Information System (INIS)

Kim, Hyun S; Qin Hua; Westphall, Michael S; Smith, Lloyd M; Blick, Robert H

2007-01-01

We measured field emission from a silicon nanopillar mechanically oscillating between two electrodes. The pillar has a height of about 200 nm and a diameter of 50 nm, allowing resonant mechanical excitations at radio frequencies. The tunnelling barriers for field emission are mechanically modulated via displacement of the gold island on top of the pillar. We present a rich frequency-dependent response of the emission current in the frequency range of 300-400 MHz at room temperature. Modified Fowler-Nordheim field emission is observed and attributed to the mechanical oscillations of the nanopillar
Overall evaluation of the modelling of the TRUE-1 tracer tests - Task 4. The Aespoe Task Force on Modelling of Groundwater Flow and Transport of Solutes

International Nuclear Information System (INIS)

Marschall, Paul; Elert, Mark

2003-09-01

The Aespoe Task Force on Modelling of Groundwater Flow and Transport of Solutes is a forum for the international organisations supporting the Aespoe HRL Project. The purpose of the Task Force is to interact in the area of conceptual and numerical modelling of groundwater flow and solute transport in fractured rock. Task 4 of the Aespoe Modelling Task Force consists of modelling exercises in support of the TRUE-1 tracer tests. The task was carried out in 1995-2000 and consisted of several modelling exercises in support of the TRUE-1 tracer tests, including predictive modelling where experimental results were not available beforehand. This report presents an overall evaluation of the achievements of Task 4. The specific objectives of the overall evaluation were to highlight innovative and successful modelling approaches developed, to assess the stages of the task which proved most beneficial for conceptual understanding of transport processes at the TRUE-1 site and to assess the success of various steering tools. A concise summary of scientific achievements is given and conclusions drawn with respect to unresolved technical issues. Recommendations are presented that can optimise the management of future modelling tasks
Aespoe Hard Rock Laboratory Annual Report 1999

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-08-01

The Aespoe Hard Rock Laboratory has been constructed as part of the preparations for the deep geological repository for spent nuclear fuel in Sweden. The Tracer Retention Understanding Experiments are made to gain a better understanding of radionuclide retention in the rock and create confidence in the radionuclide transport models that are intended to be used in the licensing of a deep repository for spent fuel. The TRUE -1 experiment including tests with sorbing radioactive tracers in a single fracture over a distance of about 5 m has been completed. Diffusion and sorption in the rock matrix is the dominant retention mechanism over the time scales of the experiments. The main objective of the TRUE Block Scale Experiment is to increase understanding and our ability to predict tracer transport in a fracture network over spatial scales of 10 to 50 m. In total six boreholes have been drilled into the experimental volume located at the 450 m level. The Long-Term Diffusion Experiment is intended as a complement to the dynamic in-situ experiments and the laboratory experiments performed in the TRUE Programme. Diffusion from a fracture into the rock matrix will be studied in situ. The REX project focuses on the reduction of oxygen in a repository after closure due to reactions with rock minerals and microbial activity. Results show that oxygen is consumed within a few days both for the field and laboratory experiments. A new site for the CHEMLAB experiments was selected and prepared during 1999. All future experiment will be conducted in the J niche at 450 m depth. The Prototype Repository Test is focused on testing and demonstrating repository system function. A full-scale prototype including six deposition holes with canisters with electric heaters surrounded by highly compacted bentonite will be built and instrumented. Characterisation of the rock mass in the area of the Prototype repository is completed and the six deposition holes have been drilled. The Backfill and
Aespoe Hard Rock Laboratory Annual Report 1999

International Nuclear Information System (INIS)

2000-08-01

The Aespoe Hard Rock Laboratory has been constructed as part of the preparations for the deep geological repository for spent nuclear fuel in Sweden. The Tracer Retention Understanding Experiments are made to gain a better understanding of radionuclide retention in the rock and create confidence in the radionuclide transport models that are intended to be used in the licensing of a deep repository for spent fuel. The TRUE -1 experiment including tests with sorbing radioactive tracers in a single fracture over a distance of about 5 m has been completed. Diffusion and sorption in the rock matrix is the dominant retention mechanism over the time scales of the experiments. The main objective of the TRUE Block Scale Experiment is to increase understanding and our ability to predict tracer transport in a fracture network over spatial scales of 10 to 50 m. In total six boreholes have been drilled into the experimental volume located at the 450 m level. The Long-Term Diffusion Experiment is intended as a complement to the dynamic in-situ experiments and the laboratory experiments performed in the TRUE Programme. Diffusion from a fracture into the rock matrix will be studied in situ. The REX project focuses on the reduction of oxygen in a repository after closure due to reactions with rock minerals and microbial activity. Results show that oxygen is consumed within a few days both for the field and laboratory experiments. A new site for the CHEMLAB experiments was selected and prepared during 1999. All future experiment will be conducted in the J niche at 450 m depth. The Prototype Repository Test is focused on testing and demonstrating repository system function. A full-scale prototype including six deposition holes with canisters with electric heaters surrounded by highly compacted bentonite will be built and instrumented. Characterisation of the rock mass in the area of the Prototype repository is completed and the six deposition holes have been drilled. The Backfill and
Estimation of effective block conductivities based on discrete network analyses using data from the Aespoe site

International Nuclear Information System (INIS)

La Pointe, P.R.; Wallmann, P.; Follin, S.

1995-09-01

Numerical continuum codes may be used for assessing the role of regional groundwater flow in far-field safety analyses of a nuclear waste repository at depth. The focus of this project is to develop and evaluate one method based on Discrete Fracture Network (DFN) models to estimate block-scale permeability values for continuum codes. Data from the Aespoe HRL and surrounding area are used. 57 refs, 76 figs, 15 tabs
Ordered microporous layered lanthanide 1,3,5-benzenetriphosphonates pillared with cationic organic molecules.

Science.gov (United States)

Araki, Takahiro; Kondo, Atsushi; Maeda, Kazuyuki

2015-04-13

Novel isomorphous pillared-layer-type crystalline lanthanide 1,3,5-benzenetriphosphonates were prepared with bpy and dbo as organic pillars (LnBP-bpy and LnBP-dbo; Ln: Ce, Pr, and Nd). Ab initio crystal structure solution using synchrotron X-ray powder diffraction data revealed that the organic pillars do not exist as neutral coordinating ligands but as cationic molecules. Especially the LnBP-dbo phases have ordered interlayer space filled with water molecules between the dbo pillars, and the interlayer water is successfully removed by heating under vacuum with slightly distorted but basically retained pillared layer structures. Microporosity of the materials is confirmed by adsorption of nitrogen, carbon dioxide, and hydrogen gases. Such microporous layered metal phosphonates pillared with cationic molecules should be unprecedented and should offer new strategies to design ordered microporous materials. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Aespoe Hard Rock Laboratory. Characterisation methods and instruments. Experiences from the construction phase

International Nuclear Information System (INIS)

Almen, Karl-Erik; Stenberg, Leif

2005-12-01

This report describes the different investigation methods used during the Aespoe HRL construction phase which commenced 1990 and ended 1995. The investigation methods are described with respect to performance, errors, uncertainty and usefulness in determined, analysed and/or calculated parameter values or other kind of geoscientific information. Moreover, other comments of the different methods, like those related to the practical performance of the measurements or tests are given. The practical performance is a major task as most of the investigations were conducted in parallel with the construction work. Much of the wide range of investigations carried out during the tunnelling work required special efforts of the personnel involved. Experiences and comments on these operations are presented in the report. The pre-investigation methods have been evaluated by comparing predictions based on pre-investigation models with data and results from the construction phase and updated geoscientific models. In 1997 a package of reports describe the general results of the pre-investigations. The investigation methods are in this report evaluated with respect to usefulness for underground characterisation of a rock volume, concerning geological, geohydrological, hydrochemical and rock mechanical properties. The report describes out opinion of the methods after the construction phase, i.e. the same platform of knowledge as for the package of reports of 1997. The evaluation of usefulness of the underground investigation methods are structured according to the key issues used for the preinvestigation modelling and predictions, i.e. Geological-structural model, Groundwater flow (hydrogeology), Groundwater chemistry (hydrochemistry), Transport of solutes and Mechanical stability models (or rock mechanics). The investigation methods selected for the different subjects for which the predictions were made are presented. Some of the subjects were slightly modified or adjusted during
Aespoe Hard Rock Laboratory. Characterisation methods and instruments. Experiences from the construction phase

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-12-15

This report describes the different investigation methods used during the Aespoe HRL construction phase which commenced 1990 and ended 1995. The investigation methods are described with respect to performance, errors, uncertainty and usefulness in determined, analysed and/or calculated parameter values or other kind of geoscientific information. Moreover, other comments of the different methods, like those related to the practical performance of the measurements or tests are given. The practical performance is a major task as most of the investigations were conducted in parallel with the construction work. Much of the wide range of investigations carried out during the tunnelling work required special efforts of the personnel involved. Experiences and comments on these operations are presented in the report. The pre-investigation methods have been evaluated by comparing predictions based on pre-investigation models with data and results from the construction phase and updated geoscientific models. In 1997 a package of reports describe the general results of the pre-investigations. The investigation methods are in this report evaluated with respect to usefulness for underground characterisation of a rock volume, concerning geological, geohydrological, hydrochemical and rock mechanical properties. The report describes out opinion of the methods after the construction phase, i.e. the same platform of knowledge as for the package of reports of 1997. The evaluation of usefulness of the underground investigation methods are structured according to the key issues used for the preinvestigation modelling and predictions, i.e. Geological-structural model, Groundwater flow (hydrogeology), Groundwater chemistry (hydrochemistry), Transport of solutes and Mechanical stability models (or rock mechanics). The investigation methods selected for the different subjects for which the predictions were made are presented. Some of the subjects were slightly modified or adjusted during
Low-temperature pyrolysis of oily sludge: roles of Fe/Al-pillared bentonites

Directory of Open Access Journals (Sweden)

Jia Hanzhong

2017-09-01

Full Text Available Pyrolysis is potentially an effective treatment of oily sludge for oil recovery, and the addition of a catalyst is expected to affect its pyrolysis behavior. In the present study, Fe/Al-pillared bentonite with various Fe/Al ratios as pyrolysis catalyst is prepared and characterized by XRD, N2 adsorption, and NH3-TPD. The integration of Al and Fe in the bentonite interlayers to form pillared clay is evidenced by increase in the basal spacing. As a result, a critical ratio of Fe/Al exists in the Fe/Al-pillared bentonite catalytic pyrolysis for oil recovery from the sludge. The oil yield increases with respect to increase in Fe/Al ratio of catalysts, then decreases with further increasing of Fe/Al ratio. The optimum oil yield using 2.0 wt% of Fe/Al 0.5-pillared bentonite as catalyst attains to 52.46% compared to 29.23% without catalyst addition in the present study. In addition, the addition of Fe/Al-pillared bentonite catalyst also improves the quality of pyrolysis-produced oil and promotes the formation of CH4. Fe/Al-pillared bentonite provides acid center in the inner surface, which is beneficial to the cracking reaction of oil molecules in pyrolysis process. The present work implies that Fe/Al-pillared bentonite as addictive holds great potential in industrial pyrolysis of oily sludge.

Extending and implementing the Persistent ID pillars

Science.gov (United States)

Car, Nicholas; Golodoniuc, Pavel; Klump, Jens

2017-04-01

The recent double decade anniversary of scholarly persistent identifier use has triggered journal special editions such as "20 Years of Persistent Identifiers". For such a publication, it is apt to consider the longevity of some persistent identifier (PID) mechanisms (Digital Object Identifiers) and the partial disappearance of others (Life Sciences IDs). We have previously postulated a set of "PID Pillars" [1] which are design principles aimed at ensuring PIDs can survive technology and social change and thus persist for the long term that we have drawn from our observations of PIDs at work over many years. The principles: describe how to ensure identifiers' system and organisation independence; codify the delivery of essential PID system functions; mandate a separation of PID functions from data delivery mechanisms; and require generation of policies detailing how change is handled. In this presentation, first we extend on our previous work of introducing the pillars by refining their descriptions, giving specific suggestions for each and presenting some work that addresses them. Second, we propose a baseline data model for persistent identifiers that, if used, would assist the separation of PID metadata and PID system functioning. This would allow PID system function specifics to change over time (e.g. resolver services or even resolution protocols) and yet preserve the PIDs themselves. Third, we detail our existing PID system — the PID Service [2] — that partially implements the pillars and describe both its successes and shortcomings. Finally, we describe our planned next-generation system that will aim to use the baseline data model and fully implement the pillars.
HRL Aespoe - two-phase flow experiment - gas and water flow in fractured crystalline rock

International Nuclear Information System (INIS)

Kull, H.; Liedtke, L.

1998-01-01

(The full text of the contribution follows:) Gas generated from radioactive waste may influence the hydraulic and mechanical properties of the man-made barriers and the immediate surroundings of the repository. Prediction of alteration in fractured crystalline rock is difficult. There is a lack of experimental data, and calibrated models are not yet available. Because of the general importance of this matter the German Federal Ministry for Education, Science, Research and Technology decided to conduct a two-phase flow study at HRL Aespoe within the scope of the co-operation agreement with SKB. Within the presentation an overview of field experiments and modelling studies scheduled until end of '99 are given. Conceptual models for one- and two-phase flow, methodologies and with respect to numerical calculations necessary parameter set-ups are discussed. Common objective of in-situ experiments is to calibrate flow models to improve the reliability of predictions for gas migration through fractured rock mass. Hence, in a defined dipole flow field in niche 2/715 at HRL Aespoe effective hydraulic parameters are evaluated. Numerical modelling of non-isothermal, two-phase, two-component processes is feasible only for two-dimensional representation of a porous medium. To overcome this restriction a computer program will be developed to model three-dimensional, fractured, porous media. Rational aspects of two-phase flow studies are for the designing of geotechnical barriers and for the long-term safety analysis of potential radionuclide transport in a future repository required for the licensing process
Argilas pilarizadas - uma introdução An introduction to pillared clays

Directory of Open Access Journals (Sweden)

Fernando J. Luna

1999-02-01

Full Text Available The synthesis, characterization and some applications in catalysis of pillared clays are described at an introductory level. The use of x-ray diffraction, surface area measurements, thermal analysis, IR spectrophotometry and solid-state NMR in the characterization of pillared clays is briefly discussed. Pillarization followed by doping or introduction of metal clusters into clays could lead to the development of selective heterogeneous catalysts.
Optimization of pillar electrodes in subretinal prosthesis for enhanced proximity to target neurons

Science.gov (United States)

Flores, Thomas; Lei, Xin; Huang, Tiffany; Lorach, Henri; Dalal, Roopa; Galambos, Ludwig; Kamins, Theodore; Mathieson, Keith; Palanker, Daniel

2018-06-01

Objective. High-resolution prosthetic vision requires dense stimulating arrays with small electrodes. However, such miniaturization reduces electrode capacitance and penetration of electric field into tissue. We evaluate potential solutions to these problems with subretinal implants based on utilization of pillar electrodes. Approach. To study integration of three-dimensional (3D) implants with retinal tissue, we fabricated arrays with varying pillar diameter, pitch, and height, and implanted beneath the degenerate retina in rats (Royal College of Surgeons, RCS). Tissue integration was evaluated six weeks post-op using histology and whole-mount confocal fluorescence imaging. The electric field generated by various electrode configurations was calculated in COMSOL, and stimulation thresholds assessed using a model of network-mediated retinal response. Main results. Retinal tissue migrated into the space between pillars with no visible gliosis in 90% of implanted arrays. Pillars with 10 μm height reached the middle of the inner nuclear layer (INL), while 22 μm pillars reached the upper portion of the INL. Electroplated pillars with dome-shaped caps increase the active electrode surface area. Selective deposition of sputtered iridium oxide onto the cap ensures localization of the current injection to the pillar top, obviating the need to insulate the pillar sidewall. According to computational model, pillars having a cathodic return electrode above the INL and active anodic ring electrode at the surface of the implant would enable six times lower stimulation threshold, compared to planar arrays with circumferential return, but suffer from greater cross-talk between the neighboring pixels. Significance. 3D electrodes in subretinal prostheses help reduce electrode-tissue separation and decrease stimulation thresholds to enable smaller pixels, and thereby improve visual acuity of prosthetic vision.
A microfluidic device with pillars

DEFF Research Database (Denmark)

2014-01-01

The invention provides a microfluidic device for mixing liquid reagents, the device comprises, a chip forming at least one reaction chamber between a bottom and a top and extending between an inlet and an outlet. To enable manufacturing from less rigid materials, the device comprises pillars...
Surface tension-induced PDMS micro-pillars with controllable tips and tilt angles

KAUST Repository

Li, Huawei; Fan, Yiqiang; Conchouso Gonzalez, David; Foulds, Ian G.

2013-01-01

This paper reports a novel method to fabricate three-dimensional (3D) polydimethylsiloxane (PDMS) micro-pillars using a CO2 laser-machined poly(methyl methacrylate) (PMMA) mold with through-holes. This method eliminates the requirements of expensive and complicated facilities to fabricate a 3D mold. The micro-pillars were formed by the capillary force that draws PDMS into the through-holes of the PMMA mold. The tilt angles of the micro-pillars depend on the tilt angles of the through-holes in the mold, and the concave and convex micro-lens tip shapes of the PDMS micro-pillars can be modified by changing the surface wettability of the PMMA through-holes.
Surface tension-induced PDMS micro-pillars with controllable tips and tilt angles

KAUST Repository

Li, Huawei

2013-12-21

This paper reports a novel method to fabricate three-dimensional (3D) polydimethylsiloxane (PDMS) micro-pillars using a CO2 laser-machined poly(methyl methacrylate) (PMMA) mold with through-holes. This method eliminates the requirements of expensive and complicated facilities to fabricate a 3D mold. The micro-pillars were formed by the capillary force that draws PDMS into the through-holes of the PMMA mold. The tilt angles of the micro-pillars depend on the tilt angles of the through-holes in the mold, and the concave and convex micro-lens tip shapes of the PDMS micro-pillars can be modified by changing the surface wettability of the PMMA through-holes.
A statistical physics consideration about the strength of small size metallic glass pillars

NARCIS (Netherlands)

Chen, Changqiang; Pei, Yutao; De Hosson, Jeff Th. M.; Skrotzki, W; Oertel, CG; Biermann, H; Heilmaier, M

2010-01-01

We have fabricated micro-/nano-pillars of a Zr-based metallic glass, Zr(50)Ti(16.5)Cu(15)Ni(18.5), with pillar tip diameters ranging from similar to 750 nm to similar to 110 nm. These pillars were mechanically tested quantitatively in-situ in a Transmission Electron Microscope (TEM). Due to a slight
Study of global stability of tall buildings with prestressed slabs

Directory of Open Access Journals (Sweden)

L. A. Feitosa

Full Text Available The use of prestressed concrete flat slabs in buildings has been increasing in recent years in the Brazilian market. Since the implementation of tall and slender buildings a trend in civil engineering and architecture fields, arises from the use of prestressed slabs a difficulty in ensuring the overall stability of a building without beams. In order to evaluate the efficiency of the main bracing systems used in this type of building, namely pillars in formed "U" in elevator shafts and stairs, and pillars in which the lengths are significantly larger than their widths, was elaborated a computational models of fictional buildings, which were processed and analyzed using the software CAD/TQS. From the variation of parameters such as: geometry of the pillars, thick slabs, characteristic strength of the concrete, reduceofthe coefficient of inertia for consideration of non-linearities of the physical elements, stiffness of the connections between slabs and pillars, among others, to analyze the influence of these variables on the overall stability of the building from the facing of instability parameter Gama Z, under Brazilian standard NBR 6118, in addition to performing the processing of building using the P-Delta iterative calculation method for the same purpose.
Analysis of rock stress and rock stress measurements with application to Aespoe HRL

International Nuclear Information System (INIS)

Lundholm, Beatrice

2000-11-01

The process of choosing a site for a nuclear waste repository means that many aspects have to be taken into consideration. One of these is that the repository has to be mechanically stable for a long time. The mechanical stability of the rock is very difficult to determine. One of several factors, which determine the mechanical stability, is the virgin state of stress. The thesis project consists of two parts. In the first part the state of stress at Aespoe Hard Rock Laboratory had to be defined. This was done based on earlier rock stress measurements conducted during the years 1988 to 1997. Two different measurement techniques have been used, hydraulic fracturing and overcoring. During the overcoring two types of cells have been used, CSIRO HI-cell and a cell developed by the Swedish State Power Board (SSPB). In the second part of the project, investigation of the correlation between the stress and geological structures are made using numerical modelling tools such as FLAC, UDEC and 3DEC. The rock stress measurements using the hydraulic fracturing gave orientations of the horizontal stress that coincide with earlier hydraulic fracturing measurements conducted in Scandinavia. The magnitudes of rock stresses are slightly lower than the earlier reported stress magnitudes for the Scandinavian part of the earth crust. The rock stresses obtained from the overcoring resulted in higher stresses than what was predicted by the hydraulic fracturing measurements. However, the orientation of the maximum horizontal stresses coincides well between the two techniques. The orientation is also more or less constant with respect to increasing depth. The state of stress at Aespoe is defined by using the results from the hydraulic fracturing and the measurements conducted by SSPB-cell. The measurements from the SSPB-cell are used since these have a Poisson's ratio that corresponds well with the uniaxial tests of rock samples and since the measurements have been done at a distance from
Relations between Eastern four pillars theory and Western measures of personality traits.

Science.gov (United States)

Jung, Seung Ah; Yang, Chang Soon

2015-05-01

The present study investigated the validity of personality classification using four pillars theory, a tradition in China and northeastern Asia. Four pillars analyses were performed for 148 adults on the basis of their birth year, month, day, and hour. Participants completed two personality tests, the Korean version of Temperament and Character Inventory-Revised-Short Version (TCI) and the Korean Inventory of Interpersonal Problems; scores were correlated with four pillars classification elements. Mean difference tests (e.g., t-test, ANOVA) were compared with groups classified by four pillars index. There were no significant correlations between personality scale scores and total yin/yang number (i.e., the 8 heavenly or earthly stems), and no significant between-groups results for classifications by yin/yang day stem and the five elements. There were significant but weak (r=0.18-0.29) correlations between the five elements and personality scale scores. For the six gods and personality scales, there were significant but weak (r=0.18-0.25) correlations. Features predicted by four pillars theory were most consistent when participants were grouped according to the yin/yang of the day stem and dominance of yin/yang numbers in the eight heavenly or earthly stems. Although the major criteria of four pillars theory were not independently correlated with personality scale scores, correlations emerged when participants were grouped according to the composite yin/yang variable. Our results suggest the utility of four pillars theory (beyond fortune telling or astrology) for classifying personality traits and making behavioral predictions.
Relations between Eastern Four Pillars Theory and Western Measures of Personality Traits

Science.gov (United States)

Jung, Seung Ah

2015-01-01

Purpose The present study investigated the validity of personality classification using four pillars theory, a tradition in China and northeastern Asia. Materials and Methods Four pillars analyses were performed for 148 adults on the basis of their birth year, month, day, and hour. Participants completed two personality tests, the Korean version of Temperament and Character Inventory-Revised-Short Version (TCI) and the Korean Inventory of Interpersonal Problems; scores were correlated with four pillars classification elements. Mean difference tests (e.g., t-test, ANOVA) were compared with groups classified by four pillars index. Results There were no significant correlations between personality scale scores and total yin/yang number (i.e., the 8 heavenly or earthly stems), and no significant between-groups results for classifications by yin/yang day stem and the five elements. There were significant but weak (r=0.18-0.29) correlations between the five elements and personality scale scores. For the six gods and personality scales, there were significant but weak (r=0.18-0.25) correlations. Features predicted by four pillars theory were most consistent when participants were grouped according to the yin/yang of the day stem and dominance of yin/yang numbers in the eight heavenly or earthly stems. Conclusion Although the major criteria of four pillars theory were not independently correlated with personality scale scores, correlations emerged when participants were grouped according to the composite yin/yang variable. Our results suggest the utility of four pillars theory (beyond fortune telling or astrology) for classifying personality traits and making behavioral predictions. PMID:25837175
Design and construction of porous metal-organic frameworks based on flexible BPH pillars

Energy Technology Data Exchange (ETDEWEB)

Hao, Xiang-Rong; Yang, Guang-sheng; Shao, Kui-Zhan [Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, Jilin (China); Su, Zhong-Min, E-mail: zmsu@nenu.edu.cn [Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, Jilin (China); Yuan, Gang; Wang, Xin-Long [Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, Jilin (China)

2013-02-15

Three metal-organic frameworks (MOFs), [Co{sub 2}(BPDC){sub 2}(4-BPH){center_dot}3DMF]{sub n} (1), [Cd{sub 2}(BPDC){sub 2}(4-BPH){sub 2}{center_dot}2DMF]{sub n} (2) and [Ni{sub 2}(BDC){sub 2}(3-BPH){sub 2} (H{sub 2}O){center_dot}4DMF]{sub n} (3) (H{sub 2}BPDC=biphenyl-4,4 Prime -dicarboxylic acid, H{sub 2}BDC=terephthalic acid, BPH=bis(pyridinylethylidene)hydrazine and DMF=N,N Prime -dimethylformamide), have been solvothermally synthesized based on the insertion of heterogeneous BPH pillars. Framework 1 has 'single-pillared' MOF-5-like motif with inner cage diameters of up to 18.6 A. Framework 2 has 'double pillared' MOF-5-like motif with cage diameters of 19.2 A while 3 has 'double pillared' 8-connected framework with channel diameters of 11.0 A. Powder X-ray diffraction (PXRD) shows that 3 is a dynamic porous framework. - Graphical abstract: By insertion of flexible BPH pillars based on 'pillaring' strategy, three metal-organic frameworks are obtained showing that the porous frameworks can be constructed in a much greater variety. Highlights: Black-Right-Pointing-Pointer Frameworks 1 and 2 have MOF-5 like motif. Black-Right-Pointing-Pointer The cube-like cages in 1 and 2 are quite large, comparable to the IRMOF-10. Black-Right-Pointing-Pointer Framework 1 is 'single-pillared' mode while 2 is 'double-pillared' mode. Black-Right-Pointing-Pointer PXRD and gas adsorption analysis show that 3 is a dynamic porous framework.
Hierarchical ZnO@MnO2 Core-Shell Pillar Arrays on Ni Foam for Binder-Free Supercapacitor Electrodes

KAUST Repository

Huang, Ming; Li, Fei; Zhao, Xiao Li; Luo, Da; You, Xue Qiu; Zhang, Yu Xin; Li, Gang

2015-01-01

© 2014 Elsevier Ltd. All rights reserved. Hierarchical ZnO@MnO2 core-shell pillar arrays on Ni foam have been fabricated by a facile two-step hydrothermal approach and further investigated as the binder-free electrode for supercapacitors. The core-shell hybrid nanostructure is achieved by decorating ultrathin self-standing MnO2 nanosheets on ZnO pillar arrays grown radically on Nickel foam. This unique well-designed binder-free electrode exhibits a high specific capacitance (423.5 F g-1 at a current density of 0.5 A g-1), and excellent cycling stability (92% capacitance retention after 3000 cycles). The improved electrochemical results show that the ZnO@MnO2 core-shell nanostructure electrode is promising for high-performance supercapacitors. The facile design of the unique core-shell array architectures provides a new and effective approach to fabricate high-performance binder-free electrode for supercapacitors.
Pilarização de esmectita brasileira para fins catalíticos. Emprego de argila pilarizada na alquilação de benzeno com 1-dodeceno Pillarization of Brazilian smectite for the catalytic of purpose. Use of pillared clay in the alkylation of benzene with 1-dodecene

Directory of Open Access Journals (Sweden)

Sidnei Quezada M. Leite

2000-04-01

Full Text Available Al-pillared clay was prepared with a Brazilian bentonite from the Campina Grande region (Paraíba, BRAZIL. It was intercalated at 298 K, during 48 hours, with a solution containing [Al3+] = 0.10 mol/L and molar ratio OH/Al = 2.0 prepared at 333 K, and was calcined at 773K. The catalytic activity was evaluated by alkylation of benzene with 1-dodecene. The characterization methods were: X-ray fluorescence and diffraction analysis; 27Al, 29Si and 23Na MAS NMR and textural analysis by N2 adsorption. The thermal stability of the natural clay was improved by the pillaring procedure, as well as the catalytic activity. The intercalated clay presented the highest initial rate of reaction among the systems tested.
Evolution and Engineering of Precisely Controlled Ge Nanostructures on Scalable Array of Ordered Si Nano-pillars

Science.gov (United States)

Wang, Shuguang; Zhou, Tong; Li, Dehui; Zhong, Zhenyang

2016-06-01

The scalable array of ordered nano-pillars with precisely controllable quantum nanostructures (QNs) are ideal candidates for the exploration of the fundamental features of cavity quantum electrodynamics. It also has a great potential in the applications of innovative nano-optoelectronic devices for the future quantum communication and integrated photon circuits. Here, we present a synthesis of such hybrid system in combination of the nanosphere lithography and the self-assembly during heteroepitaxy. The precise positioning and controllable evolution of self-assembled Ge QNs, including quantum dot necklace(QDN), QD molecule(QDM) and quantum ring(QR), on Si nano-pillars are readily achieved. Considering the strain relaxation and the non-uniform Ge growth due to the thickness-dependent and anisotropic surface diffusion of adatoms on the pillars, the comprehensive scenario of the Ge growth on Si pillars is discovered. It clarifies the inherent mechanism underlying the controllable growth of the QNs on the pillar. Moreover, it inspires a deliberate two-step growth procedure to engineer the controllable QNs on the pillar. Our results pave a promising avenue to the achievement of desired nano-pillar-QNs system that facilitates the strong light-matter interaction due to both spectra and spatial coupling between the QNs and the cavity modes of a single pillar and the periodic pillars.
Cu Pillar Low Temperature Bonding and Interconnection Technology of for 3D RF Microsystem

Science.gov (United States)

Shi, G. X.; Qian, K. Q.; Huang, M.; Yu, Y. W.; Zhu, J.

2018-03-01

In this paper 3D interconnects technologies used Cu pillars are discussed with respect to RF microsystem. While 2.5D Si interposer and 3D packaging seem to rely to cu pillars for the coming years, RF microsystem used the heterogeneous chip such as GaAs integration with Si interposers should be at low temperature. The pillars were constituted by Cu (2 micron) -Ni (2 micron) -Cu (3 micron) -Sn (1 micron) multilayer metal and total height is 8 micron on the front-side of the wafer by using electroplating. The wafer backside Cu pillar is obtained by temporary bonding, thinning and silicon surface etching. The RF interposers are stacked by Cu-Sn eutectic bonding at 260 °C. Analyzed the reliability of different pillar bonding structure.
High-performance field emission device utilizing vertically aligned carbon nanotubes-based pillar architectures

Science.gov (United States)

Gupta, Bipin Kumar; Kedawat, Garima; Gangwar, Amit Kumar; Nagpal, Kanika; Kashyap, Pradeep Kumar; Srivastava, Shubhda; Singh, Satbir; Kumar, Pawan; Suryawanshi, Sachin R.; Seo, Deok Min; Tripathi, Prashant; More, Mahendra A.; Srivastava, O. N.; Hahm, Myung Gwan; Late, Dattatray J.

2018-01-01

The vertical aligned carbon nanotubes (CNTs)-based pillar architectures were created on laminated silicon oxide/silicon (SiO2/Si) wafer substrate at 775 °C by using water-assisted chemical vapor deposition under low pressure process condition. The lamination was carried out by aluminum (Al, 10.0 nm thickness) as a barrier layer and iron (Fe, 1.5 nm thickness) as a catalyst precursor layer sequentially on a silicon wafer substrate. Scanning electron microscope (SEM) images show that synthesized CNTs are vertically aligned and uniformly distributed with a high density. The CNTs have approximately 2-30 walls with an inner diameter of 3-8 nm. Raman spectrum analysis shows G-band at 1580 cm-1 and D-band at 1340 cm-1. The G-band is higher than D-band, which indicates that CNTs are highly graphitized. The field emission analysis of the CNTs revealed high field emission current density (4mA/cm2 at 1.2V/μm), low turn-on field (0.6 V/μm) and field enhancement factor (6917) with better stability and longer lifetime. Emitter morphology resulting in improved promising field emission performances, which is a crucial factor for the fabrication of pillared shaped vertical aligned CNTs bundles as practical electron sources.
High-performance field emission device utilizing vertically aligned carbon nanotubes-based pillar architectures

Directory of Open Access Journals (Sweden)

Bipin Kumar Gupta

2018-01-01

Full Text Available The vertical aligned carbon nanotubes (CNTs-based pillar architectures were created on laminated silicon oxide/silicon (SiO2/Si wafer substrate at 775 °C by using water-assisted chemical vapor deposition under low pressure process condition. The lamination was carried out by aluminum (Al, 10.0 nm thickness as a barrier layer and iron (Fe, 1.5 nm thickness as a catalyst precursor layer sequentially on a silicon wafer substrate. Scanning electron microscope (SEM images show that synthesized CNTs are vertically aligned and uniformly distributed with a high density. The CNTs have approximately 2–30 walls with an inner diameter of 3–8 nm. Raman spectrum analysis shows G-band at 1580 cm−1 and D-band at 1340 cm−1. The G-band is higher than D-band, which indicates that CNTs are highly graphitized. The field emission analysis of the CNTs revealed high field emission current density (4mA/cm2 at 1.2V/μm, low turn-on field (0.6 V/μm and field enhancement factor (6917 with better stability and longer lifetime. Emitter morphology resulting in improved promising field emission performances, which is a crucial factor for the fabrication of pillared shaped vertical aligned CNTs bundles as practical electron sources.
The effect of the depth and groundwater on the formation of sinkholes or ground subsidence associated with abandoned room and pillar lignite mines under static and dynamic conditions

Directory of Open Access Journals (Sweden)

Ö. Aydan

2015-11-01

Full Text Available It is well known that some sinkholes or subsidence take place from time to time in the areas where abandoned room and pillar type mines exist. The author has been involved with the stability of abandoned mines beneath urbanized residential areas in Tokai region and there is a great concern about the stability of these abandoned mines during large earthquakes as well as in the long term. The 2003 Miyagi Hokubu and 2011 Great East Japan earthquakes caused great damage to abandoned mines and resulted in many collapses. The author presents the effect of the depth and groundwater on the formation of sinkholes or ground subsidence associated with abandoned room and pillar lignite mines under static and dynamic conditions and discusses the implications on the areas above abandoned lignite mines in this paper.

Monitoring the bedrock stability in Olkiluoto. Summary of campaign based GPS measurements in 1996-2011

International Nuclear Information System (INIS)

Nyberg, S.; Kallio, U.; Haekli, P.; Jokela, J.; Koivula, H.; Saaranen, V.; Rouhiainen, P.

2013-12-01

The Finnish Geodetic Institute has monitored crustal deformations in Olkiluoto since mid-1990s. This is a final report of campaign based GPS measurements carried out in 1996-2011. The aim of the research has been monitoring the bedrock stability in the Olkiluoto area. The research were started in 1995, when a local GPS network of ten pillars, called inner network, was established on Olkiluoto Island. The research area was expanded in 2003- 2005 with four new pillars (outer network) established at 5-10 km distances from the inner network. One of the pillar points is the Olkiluoto permanent GPS station. Regular biannual measurement campaigns have been carried out on other pillar points
Deep proton writing of high aspect ratio SU-8 micro-pillars on glass

Energy Technology Data Exchange (ETDEWEB)

Ebraert, Evert, E-mail: eebraert@b-phot.org; Rwamucyo, Ben; Thienpont, Hugo; Van Erps, Jürgen

2016-12-15

Deep proton writing (DPW) is a fabrication technology developed for the rapid prototyping of polymer micro-structures. We use SU-8, a negative resist, spincoated in a layer up to 720 μm-thick in a single step on borosilicate glass, for irradiation with a collimated 12 MeV energy proton beam. Micro-pillars with a slightly conical profile are irradiated in the SU-8 layer. We determine the optimal proton fluence to be 1.02 × 10{sup 4} μm{sup −2}, with which we are able to repeatably achieve micro-pillars with a top-diameter of 138 ± 1 μm and a bottom-diameter of 151 ± 3 μm. The smallest fabricated pillars have a top-diameter of 57 ± 5 μm. We achieved a root-mean-square sidewall surface roughness between 19 nm and 35 nm for the fabricated micro-pillars, measured over an area of 5 × 63.7 μm. We briefly discuss initial testing of two potential applications of the fabricated micro-pillars. Using ∼100 μm-diameter pillars as waveguides for gigascale integration optical interconnect applications, has shown a 4.7 dB improvement in optical multimode fiber-to-fiber coupling as compared to the case where an air–gap is present between the fibers at the telecom wavelength of 1550 nm. The ∼140 μm-diameter pillars were used for mold fabrication with silicone casting. The resulting mold can be used for hydrogel casting, to obtain hydrogel replicas mimicking human tissue for in vitro bio-chemical applications.
Study on the optimum design of bus window pillar join40t; Bus window pillar ketsugo buzai no saiteki sekkei ni kansuru kenkyu

Energy Technology Data Exchange (ETDEWEB)

Tomioka, N [Nihon University, Tokyo (Japan); Lim, S; Kim, M; Lee, H; Kang, S; Bae, D

1997-10-01

Automobile body structure is generally assembled using various spot welded box sectional members. Especially, in the case of the bus, the shape of window pillar joint is assembled m T-type. This T-type member has some problem such as high stress concentration, low fatigue strength and structural rigidity. Therefore, in this report, performed a study on the optimum design of the bus window pillar joint for such problem by FEM analysis and experiments. 1 ref., 10 figs., 2 tabs.
Mechanism of the Topotactic Formation of gamma-Zirconium Phosphate Covalently Pillared with Diphosphonate Groups.

Science.gov (United States)

Alberti, G.; Giontella, E.; Murcia-Mascarós, S.; Vivani, R.

1998-09-07

The topotactic reaction of gamma-ZrPO(4)[O(2)P(OH)(2)].2H(2)O (gamma-ZrP) with benzenediphosphonic acid was examined in water and in acetone-water mixtures. This reaction was found to take place in water only on the external surface of the microcrystals, and pillared compounds were never obtained, even after very long reaction times. On the contrary, covalently pillared compounds were quickly obtained in acetone-water mixtures. The mechanism of the latter topotactic reaction was investigated by determining the rate of the phosphate groups released and the rate of the benzenediphosphonates taken up by gamma-ZrP over a long time (50 days). These data showed that pillared derivatives of gamma-ZrP can be obtained because colloidal dispersions of exfoliated lamellae are formed in acetone-water mixtures. The diphosphonate group acts initially as a monovalent species, replacing only one dihydrogen phosphate group on the surface of the exfoliated gamma-lamellae. The colloidal and partially derivatized lamellae thus formed can interact with each other by forming polylamellar pillared systems. When the number of pillared lamellae exceeds a given value (usually 5-6), flocculation of the colloidal gamma-ZrP takes place. Topotactic reactions between packets of pillared lamellae may also continue in the flocculated system. Therefore, the average number of the pillared lamellae slowly increases over time.
Development of a method to estimate coal pillar loading

CSIR Research Space (South Africa)

Roberts, DP

2002-09-01

Full Text Available to the panel width to depth ratio, the percentage extraction and the stiffness of the surrounding strata influence the validity of the tributary area method. An underground test was conducted to assess the magnitude of changes in pillar stress. Various... stress measurement devices were installed in test pillars just prior to mining. The stress changes were monitored and compared with numerical modelling results. It was found that stresses increased by between 0.3 MPa and 0.5 MPa and that the stresses...
USHPRR FUEL FABRICATION PILLAR: FABRICATION STATUS, PROCESS OPTIMIZATIONS, AND FUTURE PLANS

Energy Technology Data Exchange (ETDEWEB)

Wight, Jared M.; Joshi, Vineet V.; Lavender, Curt A.

2018-03-12

The Fuel Fabrication (FF) Pillar, a project within the U.S. High Performance Research Reactor Conversion program of the National Nuclear Security Administration’s Office of Material Management and Minimization, is tasked with the scale-up and commercialization of high-density monolithic U-Mo fuel for the conversion of appropriate research reactors to use of low-enriched fuel. The FF Pillar has made significant steps to demonstrate and optimize the baseline co-rolling process using commercial-scale equipment at both the Y-12 National Security Complex (Y-12) and BWX Technologies (BWXT). These demonstrations include the fabrication of the next irradiation experiment, Mini-Plate 1 (MP-1), and casting optimizations at Y-12. The FF Pillar uses a detailed process flow diagram to identify potential gaps in processing knowledge or demonstration, which helps direct the strategic research agenda of the FF Pillar. This paper describes the significant progress made toward understanding the fuel characteristics, and models developed to make informed decisions, increase process yield, and decrease lifecycle waste and costs.
Supercapacitors based on pillared graphene nanostructures.

Science.gov (United States)

Lin, Jian; Zhong, Jiebin; Bao, Duoduo; Reiber-Kyle, Jennifer; Wang, Wei; Vullev, Valentine; Ozkan, Mihrimah; Ozkan, Cengiz S

2012-03-01

We describe the fabrication of highly conductive and large-area three dimensional pillared graphene nanostructure (PGN) films from assembly of vertically aligned CNT pillars on flexible copper foils for applications in electric double layer capacitors (EDLC). The PGN films synthesized via a one-step chemical vapor deposition process on flexible copper foils exhibit high conductivity with sheet resistance as low as 1.6 ohms per square and possessing high mechanical flexibility. Raman spectroscopy indicates the presence of multi walled carbon nanotubes (MWCNT) and their morphology can be controlled by the growth conditions. It was discovered that nitric acid treatment can significantly increase the specific capacitance of the devices. EDLC devices based on PGN electrodes (surface area of 565 m2/g) demonstrate enhanced performance with specific capacitance value as high as 330 F/g extracted from the current density-voltage (CV) measurements and energy density value of 45.8 Wh/kg. The hybrid graphene-CNT nanostructures are attractive for applications including supercapacitors, fuel cells and batteries.
Width design for gobs and isolated coal pillars based on overall burst-instability prevention in coal mines

Directory of Open Access Journals (Sweden)

Junfei Zhang

2016-08-01

Full Text Available An investigation was conducted on the overall burst-instability of isolated coal pillars by means of the possibility index diagnosis method (PIDM. First, the abutment pressure calculation model of the gob in side direction was established to derive the abutment pressure distribution curve of the isolated coal pillar. Second, the overall burst-instability ratio of the isolated coal pillars was defined. Finally, the PIDM was utilized to judge the possibility of overall burst-instability and recoverability of isolated coal pillars. The results show that an overall burst-instability may occur due to a large gob width or a small pillar width. If the width of the isolated coal pillar is not large enough, the shallow coal seam will be damaged at first, and then the high abutment pressure will be transferred to the deep coal seam, which may cause an overall burst-instability accident. This approach can be adopted to design widths of gobs and isolated coal pillars and to evaluate whether an existing isolated coal pillar is recoverable in skip-mining mines.
Aespoe Hard Rock Laboratory. BIPS logging in borehole KAS09

Energy Technology Data Exchange (ETDEWEB)

Gustafsson, Jaana; Gustafsson, Christer (Malaa Geoscience AB (Sweden))

2010-01-15

This report includes the data gained in BIPS logging performed at the Aespoe Hard Rock Laboratory. The logging operation presented here includes BIPS logging in the core drilled borehole KAS09. The objective for the BIPS logging was to observe the condition of KAS09 in order to restore the borehole in the hydrogeological monitoring programme.All measurements were conducted by Malaa Geoscience AB on October 9th 2009. The objective of the BIPS logging is to achieve information of the borehole including occurrence of rock types as well as determination of fracture distribution and orientation. This report describes the equipment used as well as the measurement procedures and data gained. For the BIPS survey, the result is presented as images. The basic conditions of the BIPS logging for geological mapping and orientation of structures are satisfying for borehole KAS09, although induced affects from the drilling on the borehole walls limit the visibility
Aespoe Hard Rock Laboratory. BIPS logging in borehole KAS09

International Nuclear Information System (INIS)

Gustafsson, Jaana; Gustafsson, Christer

2010-01-01

This report includes the data gained in BIPS logging performed at the Aespoe Hard Rock Laboratory. The logging operation presented here includes BIPS logging in the core drilled borehole KAS09. The objective for the BIPS logging was to observe the condition of KAS09 in order to restore the borehole in the hydrogeological monitoring programme.All measurements were conducted by Malaa Geoscience AB on October 9th 2009. The objective of the BIPS logging is to achieve information of the borehole including occurrence of rock types as well as determination of fracture distribution and orientation. This report describes the equipment used as well as the measurement procedures and data gained. For the BIPS survey, the result is presented as images. The basic conditions of the BIPS logging for geological mapping and orientation of structures are satisfying for borehole KAS09, although induced affects from the drilling on the borehole walls limit the visibility
Non-lithographic method of forming ordered arrays of silicon pillars and macropores

International Nuclear Information System (INIS)

Mills, David; Kolasinski, Kurt W

2005-01-01

Micrometre-scale Si pillars are formed by chemically enhanced laser ablation using nanosecond excimer laser irradiation of a Si single crystal in the presence of SF 6 . We demonstrate the importance of precursor holes in determining the positioning of the pillars and show that we can control the initiation of precursor holes by ruling a grating into the Si substrate prior to irradiation. A rule defines an edge from which the laser light diffracts. Near-field amplification of the laser intensity enhances the formation of the precursor holes and aligns them parallel to the rule. The pillars can be thinned and eventually removed by wet chemical etching in aqueous KOH, resulting first in ordered arrays of extremely high aspect ratio pillars (e.g. tens of micrometres in length, with ∼ 10 nm tips) and then macropores. The shape of the macropore is determined by crystallography and the anisotropy of the wet etchant
Rock mechanics of crown pillars between cut-and-fill stopes at the Mount Isa mine

Energy Technology Data Exchange (ETDEWEB)

Lee, M. F.; Bridges, M. C.

1980-05-15

At both levels, the leading stopes experienced bad ground conditions due to high stresses in the stope's backs when the crown pillars were about 35 m high. At 9 level, cut-and-fill mining stopped and most of the crown pillars were extracted by a slot-and-massfire method. At 11 level, cut-and-fill mining continued. Shear displacement along bedding planes began within and around the crown pillars of the leading stopes at 11 level, and spread through other crown pillars and to the hangingwall of the stoping system. Destressing and good ground conditions occurred where shear occurred, with further concentrations of stress in other areas. Crown pillars are being extracted to leave minimal 1:2 height to width diaphragms under the stopes above. Ground behavior of the 11 level crown pillars was investigated by observation, stress measurement, regional surveying of displacement and finite element models. An explanation of the ground behavior has evolved from this work. Bedding planes with an estimated angle of sliding friction of 10/sup 0/ were the main factor determining the behavior of this area.
Pillared Graphene: A New 3-D Innovative Network Nanostructure Augments Hydrogen Storage

Science.gov (United States)

Georgios, Dimitrakakis K.; Emmanuel, Tylianakis; George, Froudakis E.

2009-08-01

same orientation. In addition, the structure has no expanding limits and this is shown by the unfinished CNTs on the top and bottom of the structure (Figure 1). Obviously, the length and the intertube distance of the CNTs can be changed at will in order to have a material with tunable pores. This tailored porosity is a key aspect of our material and thus its usage can be extended to other applications besides hydrogen storage. The stability of the structure was determined by DFT calculations using the Turbomole ab-initio package. As it was shown by these calculations, our material is stable and in principle it can be formed. Its hydrogen storage capacity was then evaluated by Grand Canonical Monte Carlo (GCMC) calculations and the results showed a spectacular increase when Pillared Graphene was doped with lithium atoms. The increment on the loading when lithium atoms were present was so high that our material was able to store 6.1% wt. and 41 gr./L of hydrogen under ambient conditions.
Landslides in the area of the Jastrzebie town protective pillar

Energy Technology Data Exchange (ETDEWEB)

Rybicki, S

1986-01-01

Analyzes 76 landslides in the area of the safety pillar of Jastrzebie in the Rybnik coal region. Of 76 landslides 60% fell on natural slopes with an angle of 25-50 degrees, 22% on natural slopes with a 5-25 degree angle, 10% on man-made cuts and 8% on embankments. About 78% of the landslides was associated with water bearing layers. Of the 76 landslides 32 were situated in the safety pillar and 44 close to the pillar. Thirty-three landslides were closely associated with underground mining: 30 landslides were caused by longwall mining (landslide position was related to working face position), a further 3 were associated with mining in general. Statistical data on landslides associated with underground coal mining are analyzed: landslide area, angle of slope inclination, height, landslide range, water conditions, types of soils, types of mining areas classified according to effects of mining damage. 8 refs.
Methods for polarized light emission from CdSe quantum dot based monolithic pillar microcavities

Energy Technology Data Exchange (ETDEWEB)

Seyfried, Moritz; Kalden, Joachim; Sebald, Kathrin; Gutowski, Juergen; Kruse, Carsten; Hommel, Detlef [Institute of Solid State Physics, University of Bremen (Germany)

2010-07-01

A lifting of the polarization degeneracy of the fundamental cavity mode in pillar microcavities (MCs) would allow for controlling the polarization state of the emitted photons. Therefore, monolithic VCSEL structures were grown by molecular beam epitaxy containing either one CdSe/ZnSSe quantum dot layer or three quantum well layers as active material. By using focused-ion-beam etching, MC pillars with different geometries were prepared out of the planar samples. Among these are circularly shaped pillar MCs with diameters in the range from 500 nm up to 4 {mu}m and quality factors of up to 7860, elliptically shaped MCs, and so-called photonic molecules consisting of circular pillar MCs which are connected by small bars. Polarization dependent photoluminescence investigations of the fundamental cavity mode reveal a lifting of the polarization degeneracy for all three types of MCs. The energy splitting of up to 0.42 meV in the circularly shaped pillar MCs is probably caused by anisotropic strain conditions within the sample and directly dependent on the pillar diameter, whereas the larger energy splitting of up to 0.72 meV for the photonic molecules or even 4.5 meV for the elliptically shaped MC is based on their asymmetric cross sections.
Beyond DSM-5 and IQ Scores: Integrating the Four Pillars to Forensic Evaluations.

Science.gov (United States)

Delgado, Sergio V; Barzman, Drew H

2017-03-01

The current adult and child forensic psychiatrist is well trained, familiar, and comfortable with the use of the semi-structured Diagnostic and Statistical Manual of Mental Disorders, 5th Edition, APA 2013 (DSM-5) [In APA, 2003] interview style. The author's assertion is not that this method is invalid or unreliable; rather, that it can be complemented by integrating elements of the defendant's four pillar assessment. Assessing the four pillars expands on the information provided by a semi-structured DSM-5-style interview in psychiatry. The four pillars are the foundation of a person's personality; temperament, cognition (learning abilities or weaknesses), cognitive flexibility (theory of mind) and internal working models of attachment, within the backdrop of the family and of the social and cultural environment in which they have lived. The importance of the study of four pillars is based on the understanding that human behavior and psychopathology as a complex and multifaceted process that includes the level of social-emotional maturity and cognitive abilities (In Delgado et al. Contemporary Psychodynamic Psychotherapy for Children and Adolescents: Integrating Intersubjectivity and Neuroscience. Springer, Berlin, 2015). The four pillars are not new concepts, rather they had been studied by separate non-clinical disciplines, and had not been integrated to the clinical practice. As far as we know, it wasn't until Delgado et al. (Contemporary Psychodynamic Psychotherapy for Children and Adolescents: Integrating Intersubjectivity and Neuroscience. Springer, Berlin, 2015) incorporated the four pillars in a user-friendly manner to clinical practice.
Sulphate reduction in the Aespoe HRL tunnel

International Nuclear Information System (INIS)

Gustafson, G.; Pedersen, K.; Tullborg, E.L.; Wallin, B.; Wikberg, P.

1995-12-01

Evidence and indications of sulphate reduction based on geological, hydrogeological, groundwater, isotope and microbial data gathered in and around the Aespoe Hard Rock Laboratory tunnel have been evaluated. This integrated investigation showed that sulphate reduction had taken place in the past but is most likely also an ongoing process. Anaerobic sulphate-reducing bacteria can live in marine sediments, in the tunnel sections under the sea and in deep groundwaters, since there is no access to oxygen. The sulphate-reducing bacteria seem to thrive when the Cl - concentration of the groundwater is 4000-6000 mg/l. Sulphate reduction is an in situ process but the resulting hydrogen-sulphide rich water can be transported to other locations. A more vigorous sulphate reduction takes place when the organic content in the groundwater is high (>10 mg/l DOC) which is the case in the sediments and in the groundwaters under the sea. Some bacteria use hydrogen as an electron donor instead of organic carbon and can therefore live in deep environments where access to organic material is limited. The sulphate-reducing bacteria seem to adapt to changing flow situations caused by the tunnel construction relatively fast. Sulphate reduction seems to have occurred and will probably occur where conditions are favourable for the sulphate-reducing bacteria such as anaerobic brackish groundwater with dissolved sulphate and organic carbon or hydrogen. 59 refs, 37 figs, 6 tabs
Eco-Friendly Magnetic Iron Oxide Pillared Montmorillonite for Advanced Catalytic Degradation of Dichlorophenol

Science.gov (United States)

Eco-friendly pillared montmorillonites, in which the pillars consist of iron oxide are expected to have interesting and unusual magnetic properties that are applicable for environmental decontamination. Completely “green” and effective composite was synthesized using mild reactio...
Manipulating the optical properties of CdSe/ZnSSe quantum dot based monolithic pillar microcavities

Energy Technology Data Exchange (ETDEWEB)

Seyfried, Moritz; Kalden, Joachim; Lohmeyer, Henning; Sebald, Kathrin; Gutowski, Juergen [Semiconductor Optics, Institute of Solid state Physics, University of Bremen (Germany); Kruse, Carsten; Hommel, Detlef, E-mail: Seyfried@ifp.uni-bremen.d [Semiconductor Epitaxy, Institute of Solid state Physics, University of Bremen (Germany)

2010-02-01

A customization of the optical properties of pillar microcavities on the desired applications is essential for their future use as quantum-optical devices. Therefore, all-epitaxial cavities with CdSe quantum dot embedded in pillar structures with different geometries have been realized by focused-ion-beam etching. The quality factors of circularly shaped pillar microcavities have been measured and their dependence on the excitation power is discussed. As a possibility to achieve polarized light emission, asymmetrically shaped microcavities are presented. Examples of an elliptically shaped pillar as well as of photonic molecules are investigated with respect to their photoluminescence characteristics and polarization.
The Sloan-C Pillars: Towards a Balanced Approach to Measuring Organizational Learning

Science.gov (United States)

Yeo, Kee Meng; Mayadas, A. Frank

2010-01-01

The Sloan Pillars have set the standard for university-wide online learning program assessment for more than a dozen years. In this paper, the authors propose the extension of the Pillars to corporate e-learning, offering an alternative to traditional enterprise learning assessments. Claiming that conventional methods stress individual courses or…

Design and construction of porous metal-organic frameworks based on flexible BPH pillars

Science.gov (United States)

Hao, Xiang-Rong; Yang, Guang-sheng; Shao, Kui-Zhan; Su, Zhong-Min; Yuan, Gang; Wang, Xin-Long

2013-02-01

Three metal-organic frameworks (MOFs), [Co2(BPDC)2(4-BPH)·3DMF]n (1), [Cd2(BPDC)2(4-BPH)2·2DMF]n (2) and [Ni2(BDC)2(3-BPH)2 (H2O)·4DMF]n (3) (H2BPDC=biphenyl-4,4'-dicarboxylic acid, H2BDC=terephthalic acid, BPH=bis(pyridinylethylidene)hydrazine and DMF=N,N'-dimethylformamide), have been solvothermally synthesized based on the insertion of heterogeneous BPH pillars. Framework 1 has "single-pillared" MOF-5-like motif with inner cage diameters of up to 18.6 Å. Framework 2 has "double pillared" MOF-5-like motif with cage diameters of 19.2 Å while 3 has "double pillared" 8-connected framework with channel diameters of 11.0 Å. Powder X-ray diffraction (PXRD) shows that 3 is a dynamic porous framework.
Xenon-129 NMR study of the microporous structure of clays and pillared clays

International Nuclear Information System (INIS)

Tsiao, C.; Carrado, K.A.

1990-01-01

129 Xe NMR studies have been carried out using xenon gas adsorbed in clays and pillared clays. Data from the measurements provide information on the pore structure of clays before and after pillaring. The results indicate that the effective pore diameter of montmorillonite increases, for example, from 5.4 Angstrom to 8.0 Angstrom after pillaring cheto-montmorillonite with aluminum polyoxohydroxy Keggin cations. The data are consistent with X-ray powder diffraction results, which show a corresponding increase in the interlamellar gallery height from 5.6 Angstrom to 8.4 Angstrom
Bacterial sulphate reduction and mixing processes at the Aespoe Hard Rock Laboratory indicated by groundwater δ34S isotope signatures

International Nuclear Information System (INIS)

Wallin, Bill

2011-04-01

This report includes data mostly obtained from δ 34 S isotope measurements of groundwater at the Aespoe Island and one sampling from the Laxemar site, southeastern Sweden, during tunnel construction. Early sampling at Aespoe (up to 1992), before tunnel excavation, indicates a groundwater system with multiple sulphur sources. The isotope changes over time in the dissolved sulphate were studied during a sampling campaign in the monitoring phase from 1993 to 1995. A total of 88 samples were collected by SKB between 1992 and 1995 from core-drilled surface boreholes and from boreholes drilled in the tunnel (34 of these samples were collected from the tunnel boreholes). The results of the analyses have been the focus of discussion of the isotope changes with time in the dissolved sulphate (SO 4 2- ). The results indicate that the sulphur isotope signatures in the dissolved sulphate of the groundwater and those from fracture-filling sulphides at Aespoe originate from multiple sulphur sources in the groundwater at Aespoe and Laxemar. The data may be grouped as follows: a) typically homogeneous marine signatures of dissolved SO 4 2- are observed, with δ 34 S values of approximately +21 per mille CDT at intermediate depths of approximately 100-250 m; b) dissolved sulphate in the groundwater at greater depths (below 600 m) with average values of approximately +10 per mille CDT; and c) a dissolved SO 4 2- originating from a mixture of these sulphur sources (100-600m), although there is a difference between a mixture and modification by reduction. Reduced sulphur with low δ 34 S values is also recorded in fracture-filling sulphides, with δ 34 S values of approximately 0 to -10 per mille CDT. This may contribute to small changes in the isotope signature of the dissolved SO 4 2- , probably by sulphide oxidation in the past. The changes in the δ 34 S isotope data for dissolved SO 4 2- over the 1992-1996 period suggest a complex situation, indicating both sulphate reduction by
Mine flooding and barrier pillar hydrology in the Pittsburgh basin

International Nuclear Information System (INIS)

Leavitt, B.R.

1999-01-01

Pennsylvania began requiring barrier pillars between mines as early as 1930. The Ashley formula, resulting from a early commission on the problem, requires 20 feet of coal plus a thickness of coal equal to four times the seam height plus an additional thickness of coal equal to one tenth of the overburden thickness, or the maximum potential hydraulic head. For a 6-foot thick coal seam under 400 feet of cover, the barrier would be 20+24+40=84 feet. The Ashley formula is intended to protect coal miners from a catastrophic failure of a barrier pillar which has a high head of water impounded behind it. The paper gives several examples of flooded and unflooded mines and the performance of their barrier pillars with respect to acid mine drainage. It is concluded that for all practical purposes, barrier pillars designed with the Ashley formula are able to hydrologically isolate mines from one another. This hydrologic isolation promotes the inundation of closed mines. Inundation effectively stops acid formation, thus, fully inundated mines do not represent a perpetual source of acid mine drainage. Infiltrating ground water improves the mine water chemistry resulting in a net alkaline discharge which has greatly lowered iron concentrations. The best locations for acid mine drainage treatment plants is at the lowest surface elevation above the mine with mine flooded to near that elevation
Subglacial groundwater flow at Aespoe as governed by basal melting and ice tunnels

International Nuclear Information System (INIS)

Svensson, Urban

1999-02-01

A high resolution three dimensional numerical model of subglacial groundwater flow is described. The model uses conductivity data from the Aespoe region and is thus site specific. It is assumed that the groundwater flow is governed by the basal melting and ice tunnels; ice surface melting is not considered. Results are presented for the meltwater transport time (to the ice margin) and maximum penetration depth. Conditions at repository depth, i.e. about 500 metres, are also analysed. The general conclusion from the study is that the model presented gives plausible results, considering the basic conceptual assumptions made. It is however questioned if the hydraulics of the ice tunnels is well enough understood; this is a topic that is suggested for further studies
Fabrication of Pillar Shaped Electrode Arrays for Artificial Retinal Implants

Directory of Open Access Journals (Sweden)

Sung June Kim

2008-09-01

Full Text Available Polyimide has been widely applied to neural prosthetic devices, such as the retinal implants, due to its well-known biocompatibility and ability to be micropatterned. However, planar films of polyimide that are typically employed show a limited ability in reducing the distance between electrodes and targeting cell layers, which limits site resolution for effective multi-channel stimulation. In this paper, we report a newly designed device with a pillar structure that more effectively interfaces with the target. Electrode arrays were successfully fabricated and safely implanted inside the rabbit eye in suprachoroidal space. Optical Coherence Tomography (OCT showed well-preserved pillar structures of the electrode without damage. Bipolar stimulation was applied through paired sites (6:1 and the neural responses were successfully recorded from several regions in the visual cortex. Electrically evoked cortical potential by the pillar electrode array stimulation were compared to visual evoked potential under full-field light stimulation.
Strain relief InGaN/GaN MQW micro-pillars for high brightness LEDs

KAUST Repository

Shen, Chao

2013-01-01

Micro-structured group-III-nitrides are considered as promising strain relief structures for high efficiency solid state lighting. In this work, the strain field in InGaN/GaN multi-quantum wells (MQWs) micro-pillars is investigated using micro-Raman spectroscopy and the design of micro-pillars were studied experimentally. We distinguished the strained and strain-relieved signatures of the GaN layer from the E2 phonon peak split from the Raman scattering signatures at 572 cm-1 and 568 cm-1, respectively. The extent of strain relief is examined considering the height and size of micro-pillars fabricated using focused ion beam (FIB) micro-machining technique. A significant strain relief can be achieved when one micro-machined through the entire epi-layers, 3 μm in our study. The dependence of strain relief on micro-pillar diameter (D) suggested that micro-pillar with D < 3 μm showed high degree of strain relief. Our results shed new insights into designing strain-relieved InGaN/GaN microstructures for high brightness light emitting diode arrays. © 2013 IEEE.
Electrical characterization of Ge–Sb–Te phase change nano-pillars using conductive atomic force microscopy

International Nuclear Information System (INIS)

Bae, Byeong-Ju; Hong, Sung-Hoon; Hwang, Seon-Yong; Hwang, Jae-Yeon; Yang, Ki-Yeon; Lee, Heon

2009-01-01

The electrical characteristic of phase change material was studied in nano-scale using nanoimprint lithography and a conducting atomic force microscopy measurement system. Nanoimprint lithography was used to fabricate the nano-scale phase change material pattern. A Pt-coated AFM tip was used as a top electrode to measure the electrical characteristics of the GST nano-pillar. The GST nano-pillar, which is 200 nm in diameter, was amorphized by 2 V and 5 ns reset pulse and was then brought back to the crystalline phase by applying 1.3 V and 150 ns set pulse. Using this measurement system, the GST nano-pillar was switched between the amorphous and crystalline phases more than five times. The results of the reset and the set current measurement with the GST nano-pillar sizes show that the reset and the set currents also decreased with the decrease of the GST pillar size
Silicon based near infrared photodetector using self-assembled organic crystalline nano-pillars

Energy Technology Data Exchange (ETDEWEB)

Ajiki, Yoshiharu, E-mail: yoshiharu-ajiki@ot.olympus.co.jp, E-mail: isao@i.u-tokyo.ac.jp [Micromachine Center, 67 Kanda Sakumagashi, Chiyoda-ku, Tokyo 100-0026 (Japan); Kan, Tetsuo [Department of Mechano-Informatics, Graduate School of Information Science and Technology, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan); Yahiro, Masayuki; Hamada, Akiko; Adachi, Chihaya [Center for Organic Photonics and Electronics Research (OPERA), Kyushu University, 744 Motooka, Nishi, Fukuoka 819-0395 (Japan); Adachi, Junji [Office for Strategic Research Planning, Kyushu University, 6-10-1 Hakozaki, Higashi, Fukuoka 812-8581 (Japan); Matsumoto, Kiyoshi [IRT Research Initiative, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan); Shimoyama, Isao, E-mail: yoshiharu-ajiki@ot.olympus.co.jp, E-mail: isao@i.u-tokyo.ac.jp [Department of Mechano-Informatics, Graduate School of Information Science and Technology, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan); IRT Research Initiative, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan)

2016-04-11

We propose a silicon (Si) based near-infrared photodetector using self-assembled organic crystalline nano-pillars, which were formed on an n-type Si substrate and were covered with an Au thin-film. These structures act as antennas for near-infrared light, resulting in an enhancement of the light absorption on the Au film. Because the Schottky junction is formed between the Au/n-type Si, the electron excited by the absorbed light can be detected as photocurrent. The optical measurement revealed that the nano-pillar structures enhanced the responsivity for the near-infrared light by 89 (14.5 mA/W) and 16 (0.433 mA/W) times compared with those of the photodetector without nano-pillars at the wavelengths of 1.2 and 1.3 μm, respectively. Moreover, no polarization dependency of the responsivity was observed, and the acceptable incident angle ranged from 0° to 30°. These broad responses were likely to be due to the organic nano-pillar structures' having variation in their orientation, which is advantageous for near-infrared detector uses.
Comparison of the SKI, SKB, and SKN geological and structural models of the Aespoe area

International Nuclear Information System (INIS)

Tiren, S.A.

1996-06-01

Three sets of geological and structural models produced by three different groups are compared. The same set of basic data has been available to each of the groups. The models, all of which are 2 by 2 km by 1 km deep - or smaller, are based entirely on surface-based investigations. The modelled area is centered on the island of Aespoe, where SKB has built the Hard Rock Laboratory (HRL) in plutonic bedrock at a depth of 500 m. SKB (Swedish Nuclear Fuel and Waste Management Co) has recorded the basic data during the period 1986 to 1991, before starting the underground work. One of the main tasks in the SKB characterization of the HRL rock mass was to predict which of the geological structures will have the greatest rock-mechanical and hydraulic significance. The National Board for Spent Nuclear Fuel (SKN) constructed alternative models in 1992 to verify the SKB model. However, the SKN models were subsequently modified and converted into a hydrogeological model. The Swedish Nuclear Inspectorate (SKI) chose Aespoe as a hypothetical site for storage of nuclear waste in their SITE 94 project. The objective of the project is to assist SKI in their future review of SKB's application for a license to dispose of spent nuclear fuel underground. The agreement of the three models is found to be best where the density of information is greatest. The main difference between the two geological models is related to the inferred effects of block faulting on the rock type distribution. The correlation of moderately to gently inclined zones between the models is relatively poor at depth
Comparison of the SKI, SKB, and SKN geological and structural models of the Aespoe area

Energy Technology Data Exchange (ETDEWEB)

Tiren, S.A. [Geosigma AB, Uppsala (Sweden)

1996-06-01

Three sets of geological and structural models produced by three different groups are compared. The same set of basic data has been available to each of the groups. The models, all of which are 2 by 2 km by 1 km deep - or smaller, are based entirely on surface-based investigations. The modelled area is centered on the island of Aespoe, where SKB has built the Hard Rock Laboratory (HRL) in plutonic bedrock at a depth of 500 m. SKB (Swedish Nuclear Fuel and Waste Management Co) has recorded the basic data during the period 1986 to 1991, before starting the underground work. One of the main tasks in the SKB characterization of the HRL rock mass was to predict which of the geological structures will have the greatest rock-mechanical and hydraulic significance. The National Board for Spent Nuclear Fuel (SKN) constructed alternative models in 1992 to verify the SKB model. However, the SKN models were subsequently modified and converted into a hydrogeological model. The Swedish Nuclear Inspectorate (SKI) chose Aespoe as a hypothetical site for storage of nuclear waste in their SITE 94 project. The objective of the project is to assist SKI in their future review of SKB`s application for a license to dispose of spent nuclear fuel underground. The agreement of the three models is found to be best where the density of information is greatest. The main difference between the two geological models is related to the inferred effects of block faulting on the rock type distribution. The correlation of moderately to gently inclined zones between the models is relatively poor at depth. 46 refs, 30 figs, 18 tabs.
Applications of a computer model to the analysis of rock-backfill interaction in pillar recovery operations

Energy Technology Data Exchange (ETDEWEB)

Sinclair, T. J.E. [Dames and Moore, London, England, United Kingdom; Shillabeer, J. H. [Dames and Moore, Toronto (Canada); Herget, G. [CANMET, Ottawa (Canada)

1980-05-15

This paper describes the application of a computer model to the analysis of backfill stability in pillar recovery operations with particular reference to two case studies. An explicit finite difference computer program was developed for the purpose of modelling the three-dimensional interaction of rock and backfill in underground excavations. Of particular interest was the mechanics of stress transfer from the rock mass to the pillars and then the backfill. The need, therefore, for a model to allow for the three-dimensional effects and the sequence of operations is evident. The paper gives a brief description of the computer program, descriptions of the mines, the sequences of operations and how they were modelled, and the results of the analyses in graphical form. For both case studies, failure of the backfill was predicted at certain stages. Subsequent reports from the mines indicate that such failures did not occur at the relevant stage. The paper discusses the validity of the model and concludes that the approach accurately represents the principles of rock mechanics in cut-and-fill mining and that further research should be directed towards determining the input parameters to an equal degree of sophistication.
Aespoe hard rock laboratory. Field investigation methodology and instruments used in the preinvestigation phase, 1986-1990

International Nuclear Information System (INIS)

Almen, K.E.; Zellman, O.

1991-12-01

The Aespoe hard rock laboratory project started in 1986. The pre-investigation phase, 1986-1990, involved extensive field measurements from the surface as well as from boreholes, aimed at characterizing the rock formation with regard to geology, geohydrology, hydrochemistry and rock mechanics. The field investigation methodology used in the project was based on experience from and developments during the previous SKB study site investigation programme. However, in some respects the techniques were changed or modified. Major changes have been possible due to a new drilling technique, telescope-type drilling. This report describes the logistics of the investigation programme, characterized to a large extent by multi-purpose planning and performance of the activities in order to optimize the use of available resources; time, personnel and equipment. Preliminary hydraulic testing and groundwater sampling were conducted during the drilling of each borehole. When the drilling was completed an extensive set of singlehole investigations were carried out: geophysical logging, borehole radar, hydraulic tests of different kinds, water sampling and rock stress measurements. Multipackers were installed in the boreholes as soon as possible after the borehole investigations. The system enables monitoring of groundwater pressure, water sampling and groundwater flow measurements to be performed by means of dilution tests and tracer injection. Boreholes with such equipment were used as observation holes during interference pumping tests and long term hydraulic and tracer tests. The monitoring programme will continue during the subsequent phases of construction and operation of the Aespoe hard rock laboratory. (83 refs., 94 figs.) (au)
InGaN micro-LED-pillar as the building block for high brightness emitters

KAUST Repository

Shen, Chao; Cha, Dong Kyu; Ng, Tien Khee; Ooi, Boon S.; Yang, Yang

2013-01-01

In summary, we confirmed the improved electrical and optical characteristics, with reduced efficiency droop in InGaN μLED-pillars when these devices were scaled down in size. We demonstrated that strain relief contributed to further improvement in EQE characteristics in small InGaN μLED-pillars (D < 50 μm), apart from the current spreading effect. The μLED-pillar can be deployed as the building block for large effective-area, high brightness emitter. © 2013 IEEE.
Effect of ultrasound on the structural and textural properties of copper-impregnated cerium-modified zirconium-pillared bentonite

International Nuclear Information System (INIS)

Tomul, Fatma

2011-01-01

In this study, the synthesis of zirconium-pillared bentonite modified with cerium was performed via two different methods by the application of conventional and ultrasonic treatments during the intercalation stage. To synthesise copper-impregnated pillared clays by wet impregnation, cerium-modified zirconium-pillared clays were used as supportive materials after being calcined at 300 °C. Ultrasonic treatment significantly decreased the required processing time compared with the conventional treatment of the synthesised pillared bentonites. Chemical analysis confirmed the incorporation of Zr 4+ , Ce 4+ and Cu 2+ species into the pillared bentonites. X-ray diffraction (XRD) patterns of zirconium- and cerium/zirconium-pillared bentonites prepared by conventional treatment show that one large d-spacing above 3.5 nm corresponds to the mesoporous delaminated part, and another small d-spacing above 1.7 nm is indicative of the microporous pillared part. Zirconium- and cerium/zirconium-pillared bentonites prepared via ultrasonic treatment exhibited similar results, with the same high d-spacing but with a second low-intensity d-spacing above 1.9 nm. The delaminated structures of the pillared bentonites synthesised by both methods were conserved after copper impregnation. Nitrogen-adsorption isotherm analysis showed that the textural characteristics of products synthesised by ultrasonic treatment were comparable to those of products synthesised by conventional treatment. Fourier-transform infrared spectroscopy (FTIR) analyses showed the presence of Brønsted- and Lewis-acid sites, and zirconium-pillared clays synthesised by conventional treatment exhibited increased numbers of Brønsted- and Lewis-acid sites after cerium addition and copper impregnation. However, the products synthesised by ultrasonic treatment exhibited an increased number of Brønsted- and Lewis-acid sites after cerium addition, but a decreased number of acid sites after copper impregnation.
Trajectory generation algorithm for smooth movement of a hybrid-type robot Rocker-Pillar

Energy Technology Data Exchange (ETDEWEB)

Jung, Seung Min; Choi, Dong Kyu; Kim, Jong Won [School of Mechanical and Aerospace Engineering, Seoul National University, Seoul (Korea, Republic of); Kim, Hwa Soo [Dept. of Mechanical System Engineering, Kyonggi University, Suwon (Korea, Republic of)

2016-11-15

While traveling on rough terrain, smooth movement of a mobile robot plays an important role in carrying out the given tasks successfully. This paper describes the trajectory generation algorithm for smooth movement of hybrid-type mobile robot Rocker-Pillar by adjusting the angular velocity of its caterpillar as well as each wheel velocity in such a manner to minimize a proper index for smoothness. To this end, a new Smoothness index (SI) is first suggested to evaluate the smoothness of movement of Rocker-Pillar. Then, the trajectory generation algorithm is proposed to reduce the undesired oscillations of its Center of mass (CoM). The experiment are performed to examine the movement of Rocker-Pillar climbing up the step whose height is twice larger than its wheel radius. It is verified that the resulting SI is improved by more than 40 % so that the movement of Rocker-Pillar becomes much smoother by the proposed trajectory algorithm.
Application of the multi-rate diffusion approach in tracer test studies at Aespoe HRL. Final report

International Nuclear Information System (INIS)

Haggerty, R.

1999-11-01

This report summarizes an investigation into heterogeneous diffusivity and associated parameters within granitic rocks at the Aespoe Hard Rock Laboratory (HRL). Our tasks for this investigation were: (1) to assess the potential for either anomalous or multi-rate diffusion within Aespoe rocks; (2) to evaluate existing data relating to anomalous and multi-rate diffusion within Aespoe rocks; (3) to perform scoping calculations in support of a Long Term Diffusion Experiment (LTDE) design; and (4) to begin developing a mathematical and computer model for solute advection in the presence of anomalous matrix diffusion. In addition to carrying out these tasks, we also report on (5) the late-time behavior of breakthrough curves. First, in regard to the potential for anomalous and multi-rate diffusion and analyses of existing data, we find that (1) in a literature review of 100 column experiments in various types of rock and sediment, rate coefficients decrease with experimental observation time. This is precisely what would be expected of both multi-rate and anomalous diffusion. (2) Three sets of through-diffusion experiments in Fenno-Scandian granitic rock found decreasing effective diffusivity, D e , with sample length, while one set did not. (3) Based on diffusivity and sorption data, and speculation on matrix block size variability, the total variability of D a /a 2 may reasonably be expected to exceed 4 orders of magnitude. (4) Analyses of two-well tracer data completed to date are ambiguous with respect to multi-rate diffusion. Analyses of TRUE data are currently underway and may support multi-rate diffusion. Second, in regard to the potential consequences of multi-rate and anomalous diffusion on nuclear waste disposal, we found the following key points: (1) No single value of diffusivity can represent the diffusion process at all time- or length-scales if diffusion is truly anomalous, while a single value of diffusivity will represent diffusion adequately for some
Application of the multi-rate diffusion approach in tracer test studies at Aespoe HRL. Final report

Energy Technology Data Exchange (ETDEWEB)

Haggerty, R. [Oregon State Univ., Corvallis, OR (United States). Dept. of Geosciences

1999-11-01

This report summarizes an investigation into heterogeneous diffusivity and associated parameters within granitic rocks at the Aespoe Hard Rock Laboratory (HRL). Our tasks for this investigation were: (1) to assess the potential for either anomalous or multi-rate diffusion within Aespoe rocks; (2) to evaluate existing data relating to anomalous and multi-rate diffusion within Aespoe rocks; (3) to perform scoping calculations in support of a Long Term Diffusion Experiment (LTDE) design; and (4) to begin developing a mathematical and computer model for solute advection in the presence of anomalous matrix diffusion. In addition to carrying out these tasks, we also report on (5) the late-time behavior of breakthrough curves. First, in regard to the potential for anomalous and multi-rate diffusion and analyses of existing data, we find that (1) in a literature review of 100 column experiments in various types of rock and sediment, rate coefficients decrease with experimental observation time. This is precisely what would be expected of both multi-rate and anomalous diffusion. (2) Three sets of through-diffusion experiments in Fenno-Scandian granitic rock found decreasing effective diffusivity, D{sub e}, with sample length, while one set did not. (3) Based on diffusivity and sorption data, and speculation on matrix block size variability, the total variability of D{sub a}/a{sup 2} may reasonably be expected to exceed 4 orders of magnitude. (4) Analyses of two-well tracer data completed to date are ambiguous with respect to multi-rate diffusion. Analyses of TRUE data are currently underway and may support multi-rate diffusion. Second, in regard to the potential consequences of multi-rate and anomalous diffusion on nuclear waste disposal, we found the following key points: (1) No single value of diffusivity can represent the diffusion process at all time- or length-scales if diffusion is truly anomalous, while a single value of diffusivity will represent diffusion
Reverse engineering of B-pillar with 3D optical scanning for manufacturing of non-uniform thickness part

OpenAIRE

Islam Md. Tasbirul; Abdullah A.B.; Mahmud Mohamad Zihad

2017-01-01

This paper presents reverse engineering (RE) of a complex automobile structural part, B-pillar. As a major part of the automobile body-in white (BiW), B-pillar has substantial opportunity for weight reduction by introducing variable thickness across its sections. To leverage such potential, an existing B-pillar was reverse engineered with a 3D optical scanner and computer aided design (CAD) application. First, digital data (i.e. in meshes) of exiting B-pillar was obtained by the scanner, and ...
Effect of orientation and loading rate on compression behavior of small-scale Mo pillars

International Nuclear Information System (INIS)

Schneider, A.S.; Clark, B.G.; Frick, C.P.; Gruber, P.A.; Arzt, E.

2009-01-01

Recently, much work has focused on the size effect in face centered cubic (fcc) structures, however few pillar studies have focused on body centered cubic (bcc) metals. This paper explores the role of bcc crystal structure on the size effect, through compression testing of [001] and [235] Molybdenum (Mo) small-scale pillars manufactured by focused ion beam (FIB). The pillar diameters ranged from 200 nm to 5 μm. Results show that the relationship between yield stress and diameter exhibits an inverse relationship (σ y ∝ d -0.22 for [001] Mo and σ y ∝ d -0.34 for [235] Mo) weaker than that observed for face centered cubic (fcc) metals (σ y ∝ d -0.6to-1.0 ). Additional tests at various loading rates revealed that small-scale Mo pillars exhibit a strain rate sensitivity similar to bulk Mo.

The possibility of increasing the efficiency of accessible coal deposits by optimizing dimensions of protective pillars or the scope of exploitation

Science.gov (United States)

Bańka, Piotr; Badura, Henryk; Wesołowski, Marek

2017-11-01

One of the ways to protect objects exposed to the influences of mining exploitation is establishing protective pillars for them. Properly determined pillar provides effective protection of the object for which it was established. Determining correct dimensions of a pillar requires taking into account contradictory requirements. Protection measures against the excessive influences of mining exploitation require designing the largest possible pillars, whereas economic requirements suggest a maximum reduction of the size of resources left in the pillar. This paper presents algorithms and programs developed for determining optimal dimensions of protective pillars for surface objects and shafts. The issue of designing a protective pillar was treated as a nonlinear programming task. The objective function are the resources left in a pillar while nonlinear limitations are the deformation values evoked by the mining exploitation. Resources in the pillar may be weighted e.g. by calorific value or by the inverse of output costs. The possibility of designing pillars of any polygon shape was taken into account. Because of the applied exploitation technologies the rectangular pillar shape should be considered more advantageous than the oval one, though it does not ensure the minimization of resources left in a pillar. In this article there is also presented a different approach to the design of protective pillars, which instead of fixing the pillar boundaries in subsequent seams, the length of longwall panels of the designed mining exploitation is limited in a way that ensures the effective protection of an object while maximizing the extraction ratio of the deposit.
Crystallography of Representative MOFs Based on Pillared Cyanonickelate (PICNIC Architecture

Directory of Open Access Journals (Sweden)

Winnie Wong-Ng

2016-09-01

Full Text Available The pillared layer motif is a commonly used route to porous coordination polymers or metal organic frameworks (MOFs. Materials based on the pillared cyano-bridged architecture, [Ni’(LNi(CN4]n (L = pillar organic ligands, also known as PICNICs, have been shown to be especially diverse where pore size and pore functionality can be varied by the choice of pillar organic ligand. In addition, a number of PICNICs form soft porous structures that show reversible structure transitions during the adsorption and desorption of guests. The structural flexibility in these materials can be affected by relatively minor differences in ligand design, and the physical driving force for variations in host-guest behavior in these materials is still not known. One key to understanding this diversity is a detailed investigation of the crystal structures of both rigid and flexible PICNIC derivatives. This article gives a brief review of flexible MOFs. It also reports the crystal structures of five PICNICS from our laboratories including three 3-D porous frameworks (Ni-Bpene, NI-BpyMe, Ni-BpyNH2, one 2-D layer (Ni-Bpy, and one 1-D chain (Ni-Naph compound. The sorption data of BpyMe for CO2, CH4 and N2 is described. The important role of NH3 (from the solvent of crystallization as blocking ligands which prevent the polymerization of the 1-D chains and 2-D layers to become 3D porous frameworks in the Ni-Bpy and Ni-Naph compounds is also addressed.
Ion sorption onto hydrous ferric oxides: Effect on major element fluid chemistry at Aespoe, Sweden

International Nuclear Information System (INIS)

Bruton, C.J.; Viani, B.E.

1996-06-01

The observed variability of fluid chemistry at the Aespoe Hard Rock Laboratory is not fully described by conservative fluid mixing models. Ion exchange may account for some of the observed discrepancies. It is also possible that variably charged solids such as oxyhydroxides of Fe can serve as sources and sinks of anions and cations through surface complexation. Surface complexation reactions on hydrous ferric oxides involve sorption of both cations and anions. Geochemical modeling of the surface chemistry of hydrous ferric oxides (HFOs) in equilibrium with shallow HBH02 and deep KA0483A waters shows that HFOs can serve as significant, pH-sensitive sources and sinks for cations and anions. Carbonate sorption is favored especially at below-neutral pH. A greater mass of carbonate is sorbed onto HFO surfaces than is contained in the fluid when 10 g goethite, used as a proxy for HFOs, is in contact with 1 kg H 2 O. The masses of sorbent required to significantly impact fluid chemistry through sorption/desorption reactions seem to be reasonable when compared to the occurrences of HFOs at Aespoe. Thus, it is possible that small changes in fluid chemistry can cause significant releases of cations or anions from HFOs into the fluid phase or, alternately, result in uptake of aqueous species onto HFO surfaces. Simulations of the mixing of shallow HBH02 and native KA0483A waters in the presence of a fixed mass of goethite show that surface complexation does not cause the concentrations of Ca, Sr, and SO 4 to deviate from those that are predicted using conservative mixing models. Results for HCO 3 are more difficult to interpret and cannot be addressed adequately at this time
Palaeohydrological implications in the Baltic area and its relation to the groundwater at Aespoe, south-eastern Sweden - A literature study

International Nuclear Information System (INIS)

Wallin, B.

1995-03-01

A literature study of different groundwaters in the circum Baltic region is presented in this work. The study is mainly focused on the isotopic signatures observed in different groundwaters in Sweden and Finland. Several saline groundwaters in the Baltic region at depth of 150 to 500m depth show stable (δD, δ 13 C, δ 18 O) and radiogenic (δ 87 Sr) isotope assembly which is suggestive of a marine origin. However, a discrepancy is sometimes observed between the stable as well as radiogenic isotopes of the intermediate groundwater, which suggest a mixture of fossil marine water and a post-glacial runoff of melt water. In order to explain this phenomenon, the initial setting in δ 18 O may have been depleted due to large input of high latitude marine water or cold melt waters. A solution to the contradiction between the strontium (δ 87 Sr) and stable isotope (δD, δ 13 C, δ 18 O) signatures of the groundwater and of the calcite fracture fillings at Aespoe and other places is attained, if it is assumed that the strontium in Baltic Sea water has undergone a significant decrease in δ 87 Sr since the last glaciation. A scenario can be constructed to suggest that the Baltic Sea during the initial stage of the Litorina sea (8000 to 5000 Y B.P.) contained strontium with much larger δ 87 Sr values. Another explanation for the positive δ 87 Sr values may be due to water/rock interaction between the groundwater and the abundant fracture clay minerals, which are observed at Aespoe. Typically most of the saline groundwaters occur both in Sweden and Finland below the highest marine shore line during the Holocene. Almost all inland groundwaters show a totally different pattern which is typically non marine, meteoric in origin. This study also summarises the stable isotope (δ 13 C,δ 18 O) geochemistry dependence of the important global and regional environmental changes which may have influenced of the palaeohydrology as well as groundwater formation and in the Baltic
Workshops around the pillar system design computer program produced in SIMRAC project GAP334

CSIR Research Space (South Africa)

York, G

2000-03-01

Full Text Available with the actual Pillar System Design program. Four workshops were held, three in the Bushveld Complex, and one at the Conference Centre at CSIR Miningtek. The delegates comprised most of the industry rock mechanics practitioners who deal with pillar system design...
A Monte Carlo model for the intermittent plasticity of micro-pillars

International Nuclear Information System (INIS)

Ng, K S; Ngan, A H W

2008-01-01

Earlier compression experiments on micrometre-sized aluminium pillars, fabricated by focused-ion beam milling, using a flat-punch nanoindenter revealed that post-yield deformation during constant-rate loading was jerky with interspersing strain bursts and linear elastic segments. Under load hold, the pillars crept mainly by means of sporadic strain bursts. In this work, a Monte Carlo simulation model is developed, with two statistics gathered from the load-ramp experiments as input, to account for the jerky deformation during the load ramp as well as load hold. Under load-ramp conditions, the simulations successfully captured other experimental observations made independently from the two inputs, namely, the diverging behaviour of the jerky stress–strain response at higher stresses, the increase in burst frequency and burst size with stress and the overall power-law distribution of the burst size. The model also predicts creep behaviour agreeable with the experimental observations, namely, the occurrence of sporadic bursts with frequency depending on stress, creep time and pillar dimensions
In-plane confinement and waveguiding of surface acoustic waves through line defects in pillars-based phononic crystal

Directory of Open Access Journals (Sweden)

Abdelkrim Khelif

2011-12-01

Full Text Available We present a theoretical analysis of an in-plane confinement and a waveguiding of surface acoustic waves in pillars-based phononic crystal. The artificial crystal is made up of cylindrical pillars placed on a semi-infinite medium and arranged in a square array. With a well-chosen of the geometrical parameters, this pillars-based system can display two kinds of complete band gaps for guided waves propagating near the surface, a low frequency gap based on locally resonant mode of pillars as well as a higher frequency gap appearing at Bragg scattering regime. In addition, we demonstrate a waveguiding of surface acoustic wave inside an extended linear defect created by removing rows of pillars in the perfect crystal. We discuss the transmission and the polarization of such confined mode appearing in the higher frequency band gap. We highlight the strong similarity of such defect mode and the Rayleigh wave of free surface medium. An efficient finite element analysis is used to simulate the propagation of guided waves through silicon pillars on a silicon substrate.
A diabetic retinopathy detection method using an improved pillar K-means algorithm.

Science.gov (United States)

Gogula, Susmitha Valli; Divakar, Ch; Satyanarayana, Ch; Rao, Allam Appa

2014-01-01

The paper presents a new approach for medical image segmentation. Exudates are a visible sign of diabetic retinopathy that is the major reason of vision loss in patients with diabetes. If the exudates extend into the macular area, blindness may occur. Automated detection of exudates will assist ophthalmologists in early diagnosis. This segmentation process includes a new mechanism for clustering the elements of high-resolution images in order to improve precision and reduce computation time. The system applies K-means clustering to the image segmentation after getting optimized by Pillar algorithm; pillars are constructed in such a way that they can withstand the pressure. Improved pillar algorithm can optimize the K-means clustering for image segmentation in aspects of precision and computation time. This evaluates the proposed approach for image segmentation by comparing with Kmeans and Fuzzy C-means in a medical image. Using this method, identification of dark spot in the retina becomes easier and the proposed algorithm is applied on diabetic retinal images of all stages to identify hard and soft exudates, where the existing pillar K-means is more appropriate for brain MRI images. This proposed system help the doctors to identify the problem in the early stage and can suggest a better drug for preventing further retinal damage.
Unusual mechanism of capillary condensation in pores modified with chains forming pillars.

Science.gov (United States)

Borówko, M; Patrykiejew, A; Sokołowski, S

2011-08-07

Density functional approach is applied to study the phase behavior of Lennard-Jones(12,6) fluid in pillared slit-like pores. Our focus is in the evaluation of phase transitions in fluid adsorbed in the pore of a fixed width. If the length of pillars is sufficiently large, we observe additional phase transitions of the first and second order due to the symmetry breaking of the distribution of chain segments and fluid species with respect to the slit-like pore center. Re-entrant symmetry changes and additional critical, critical end points and tricritical points then are observed. The scenario of phase changes is sensitive to the energy of fluid-solid interaction, the amount, and the length of the pillars. Quantitative trends and qualitative changes of the phase diagrams topology are examined depending on the values of these parameters.
Magnetic Reversal and Thermal Stability of CoFeB Perpendicular Magnetic Tunnel Junction Arrays Patterned by Block Copolymer Lithography

KAUST Repository

Tu, Kun-Hua

2018-04-10

Dense arrays of pillars, with diameters of 64 and 25 nm, were made from a perpendicular CoFeB magnetic tunnel junction thin film stack using block copolymer lithography. While the soft layer and hard layer in the 64 nm pillars reverse at different fields, the reversal of the two layers in the 25 nm pillars could not be distinguished, attributed to the strong interlayer magnetostatic coupling. First order reversal curves were used to identify the steps that occur during switching, and the thermal stability and effective switching volume were determined from scan rate dependent hysteresis measurements.
Microscopic Pillars and Tubes Fabricated by Using Fish Dentine as a Molding Template

Directory of Open Access Journals (Sweden)

Weiqun Li

2014-08-01

Full Text Available Biomaterials in nature exhibit delicate structures that are greatly beyond the capability of the current manufacturing techniques. Duplicating these structures and applying them in engineering may help enhance the performance of traditional functional materials and structures. Inspired by gecko’s hierarchical micro- and nano-fibrillar structures for adhesion, in this work we fabricated micro-pillars and tubes by adopting the tubular dentine of black carp fish teeth as molding template. The adhesion performances of the fabricated micro-pillars and tubes were characterized and compared. It was found that the pull-off force of a single pillar was about twice of that of the tube with comparable size. Such unexpected discrepancy in adhesion was analyzed based on the contact mechanics theories.
Organically pillared layered zinc hydroxides

International Nuclear Information System (INIS)

Kongshaug, K.O.; Fjellvaag, Helmer

2004-01-01

The two organically pillared layered zinc hydroxides [Zn 2 (OH) 2 (ndc)], CPO-6, and [Zn 3 (OH) 4 (bpdc)], CPO-7, were obtained in hydrothermal reactions between 2,6-naphthalenedicarboxylic acid (ndc) and zinc nitrate (CPO-6) and 4,4'biphenyldicarboxylate (bpdc) and zinc nitrate (CPO-7), respectively. In CPO-6, the tetrahedral zinc atoms are connected by two μ 2 -OH groups and two carboxylate oxygen atoms, forming infinite layers extending parallel to the bc-plane. These layers are pillared by ndc to form a three-dimensional structure. In CPO-7, the zinc hydroxide layers are containing four-, five- and six coordinated zinc atoms, and the layers are built like stairways running along the [001] direction. Each step is composed of three infinite chains running in the [010] direction. Both crystal structures were solved from conventional single crystal data. Crystal data for CPO-6: Monoclinic space group P2 1 /c (No. 14), a=11.9703(7), b=7.8154(5), c=6.2428(4) A, β=90.816(2) deg., V=583.97(6) A 3 and Z=4. Crystal data for CPO-7: Monoclinic space group C2/c (No. 15), a=35.220(4), b=6.2658(8), c=14.8888(17) A, β=112.580(4) deg., V=3033.8(6) A 3 and Z=8. The compounds were further characterized by thermogravimetric- and chemical analysis
SITE-94. The SKN conceptual model of Aespoe. Based on pre-investigations 1986-1990

International Nuclear Information System (INIS)

Sundquist, U.; Torssander, P.

1996-12-01

The present report describes the SKN (National Board for Spent Nuclear Fuel) conceptual model, which is a combined structural, hydrogeological and geochemical model. The development of the model has been carried out by stages with commencement in 1990. This report summarizes the main parts of the work performed. Initially, the development of the model was part of the program of SKN regarding review of SKB R and D work at Aespoe Hard Rock Laboratory. At a later stage, the SKN model was further developed and integrated into SITE-94. This development comprised evaluation of additional hydrogeological and geochemical data in order to strengthen the model. This report summarizes two earlier reports by SKN written in Swedish. Furthermore, a comprehensive description of the hydrogeological and geochemical evaluation is presented. 58 refs
SITE-94. The SKN conceptual model of Aespoe. Based on pre-investigations 1986-1990

Energy Technology Data Exchange (ETDEWEB)

Sundquist, U.; Torssander, P. [Bergab, Goeteborg (Sweden)

1996-12-01

The present report describes the SKN (National Board for Spent Nuclear Fuel) conceptual model, which is a combined structural, hydrogeological and geochemical model. The development of the model has been carried out by stages with commencement in 1990. This report summarizes the main parts of the work performed. Initially, the development of the model was part of the program of SKN regarding review of SKB R and D work at Aespoe Hard Rock Laboratory. At a later stage, the SKN model was further developed and integrated into SITE-94. This development comprised evaluation of additional hydrogeological and geochemical data in order to strengthen the model. This report summarizes two earlier reports by SKN written in Swedish. Furthermore, a comprehensive description of the hydrogeological and geochemical evaluation is presented. 58 refs.
Solving the critical thermal bowing in 3C-SiC/Si(111) by a tilting Si pillar architecture

Science.gov (United States)

Albani, Marco; Marzegalli, Anna; Bergamaschini, Roberto; Mauceri, Marco; Crippa, Danilo; La Via, Francesco; von Känel, Hans; Miglio, Leo

2018-05-01

The exceptionally large thermal strain in few-micrometers-thick 3C-SiC films on Si(111), causing severe wafer bending and cracking, is demonstrated to be elastically quenched by substrate patterning in finite arrays of Si micro-pillars, sufficiently large in aspect ratio to allow for lateral pillar tilting, both by simulations and by preliminary experiments. In suspended SiC patches, the mechanical problem is addressed by finite element method: both the strain relaxation and the wafer curvature are calculated at different pillar height, array size, and film thickness. Patches as large as required by power electronic devices (500-1000 μm in size) show a remarkable residual strain in the central area, unless the pillar aspect ratio is made sufficiently large to allow peripheral pillars to accommodate the full film retraction. A sublinear relationship between the pillar aspect ratio and the patch size, guaranteeing a minimal curvature radius, as required for wafer processing and micro-crack prevention, is shown to be valid for any heteroepitaxial system.
PS buildings : reinforced concrete structure for shielding "bridge" pillar

CERN Multimedia

CERN PhotoLab

1956-01-01

The PS ring traverses the region between the experimental halls South and North (buildings Nos 150 and 151) under massive bridge-shaped concrete beams. This pillar stands at the S-W end of the structure.
Surface displacements and pillar stresses associated with nuclear waste disposal in salt

International Nuclear Information System (INIS)

Hardy, M.P.; St John, C.M.

1977-01-01

A numerical model for regional analysis of stresses and displacement, resulting from heat generating waste placement in underground salt excavations, is presented. The model, which is an extension of that described by McClain and Starfield (1971), is based upon the displacement discontinuity method of stress analysis. It incorporates an empirical characterization of creep behavior of material on the excavation horizon and accounts for thermally induced stresses and displacements. The versatility of this approach is illustrated by the results of three relatively short simulations of test scale disposal facilities at shallow and greater depths. In addition, a three-dimensional code was used to evaluate the surface displacement history for a full-scale repository. This latter code, a thermoelastic analysis, gives an upper bound for the surface movements. It is concluded that the pillar stresses are the result of a complex non-linear interaction of many variables, and the maximum pillar stress can reach several multiples of the tributory-area pillar stress
Aespoe Hard Rock Laboratory. Evaluation of scaling records for TASA access tunnel

International Nuclear Information System (INIS)

Ittner, Henrik

2009-01-01

This report presents the result of a project accomplished during the summer 2009. It introduces a method to estimate the magnitude, mass distribution and cause of scaled blocks by tunnel mapping and evaluation of scaling data records. These issues are important for understanding the impact of the excavation method on the surrounding rock mass during excavation of the planned underground repository for spent nuclear fuel. The project includes mapping of the 3120 m drill and blast excavated part of the TASA access tunnel in the Aespoe Hard Rock Laboratory (HRL). In addition it includes development of a method for evaluation of the collected material together with scaling data records from the Site Characterization Database (SICADA). An interview has also been held with Erik Gabrielsson, who has been in charge of tunnel maintenance at Aespoe for many years. The mapping focused on to identify size and cause of areas with significant overbreaks in the tunnel roof. By distributing documented scaled volume in a tunnel section on several mapped overbreak areas in the same section it is possible to reconstruct the size of scaled blocks. The observed overbreak areas have been categorized in five different area types, depending on the cause of scaling: two geologically induced, one blast induced, one induced from a combination of geology and blasting and one unable to place in any category. For the calculated mass distribution the number of observations is declining with increasing block mass. 11% of the total blocks exceeding 400 Kg and 75% of the scaled blocks weights under 200 Kg. Most of the blocks are however lighter with 34% weighting 50 Kg or less. There is a relation between the mapped area type and the size distribution among the mapped overbreak areas. For example the areas caused by the end of blasting rounds are more frequently appearing then the other types but most of them are small in relation to the others The impression achieved from the tunnel mapping is
Aespoe Hard Rock Laboratory. Evaluation of scaling records for TASA access tunnel

Energy Technology Data Exchange (ETDEWEB)

Ittner, Henrik (Chalmers Univ. of Technology, Goeteborg (Sweden))

2009-07-01

This report presents the result of a project accomplished during the summer 2009. It introduces a method to estimate the magnitude, mass distribution and cause of scaled blocks by tunnel mapping and evaluation of scaling data records. These issues are important for understanding the impact of the excavation method on the surrounding rock mass during excavation of the planned underground repository for spent nuclear fuel. The project includes mapping of the 3120 m drill and blast excavated part of the TASA access tunnel in the Aespoe Hard Rock Laboratory (HRL). In addition it includes development of a method for evaluation of the collected material together with scaling data records from the Site Characterization Database (SICADA). An interview has also been held with Erik Gabrielsson, who has been in charge of tunnel maintenance at Aespoe for many years. The mapping focused on to identify size and cause of areas with significant overbreaks in the tunnel roof. By distributing documented scaled volume in a tunnel section on several mapped overbreak areas in the same section it is possible to reconstruct the size of scaled blocks. The observed overbreak areas have been categorized in five different area types, depending on the cause of scaling: two geologically induced, one blast induced, one induced from a combination of geology and blasting and one unable to place in any category. For the calculated mass distribution the number of observations is declining with increasing block mass. 11% of the total blocks exceeding 400 Kg and 75% of the scaled blocks weights under 200 Kg. Most of the blocks are however lighter with 34% weighting 50 Kg or less. There is a relation between the mapped area type and the size distribution among the mapped overbreak areas. For example the areas caused by the end of blasting rounds are more frequently appearing then the other types but most of them are small in relation to the others The impression achieved from the tunnel mapping is
Estimating the coordinates of pillars and posts in the parking lots for intelligent parking assist system

Science.gov (United States)

Choi, Jae Hyung; Kuk, Jung Gap; Kim, Young Il; Cho, Nam Ik

2012-01-01

This paper proposes an algorithm for the detection of pillars or posts in the video captured by a single camera implemented on the fore side of a room mirror in a car. The main purpose of this algorithm is to complement the weakness of current ultrasonic parking assist system, which does not well find the exact position of pillars or does not recognize narrow posts. The proposed algorithm is consisted of three steps: straight line detection, line tracking, and the estimation of 3D position of pillars. In the first step, the strong lines are found by the Hough transform. Second step is the combination of detection and tracking, and the third is the calculation of 3D position of the line by the analysis of trajectory of relative positions and the parameters of camera. Experiments on synthetic and real images show that the proposed method successfully locates and tracks the position of pillars, which helps the ultrasonic system to correctly locate the edges of pillars. It is believed that the proposed algorithm can also be employed as a basic element for vision based autonomous driving system.

Reverse engineering of B-pillar with 3D optical scanning for manufacturing of non-uniform thickness part

Directory of Open Access Journals (Sweden)

Islam Md. Tasbirul

2017-01-01

Full Text Available This paper presents reverse engineering (RE of a complex automobile structural part, B-pillar. As a major part of the automobile body-in white (BiW, B-pillar has substantial opportunity for weight reduction by introducing variable thickness across its sections. To leverage such potential, an existing B-pillar was reverse engineered with a 3D optical scanner and computer aided design (CAD application. First, digital data (i.e. in meshes of exiting B-pillar was obtained by the scanner, and subsequently, this information was utilized in developing a complete 3D CAD model. CATIA V5 was used in the modeling where some of the essential work benches were “Digitized Shape Editor”, “Quick Surface Reconstruction”, “Wireframe and Surface Design”, “Freestyle”, “Generation Shape Design” and “Part design”. In the final CAD design, five different thicknesses were incorporated successfully in order to get a B-pillar with non-uniform sections. This research opened opportunities for thickness optimization and mold tooling design in real time manufacturing.
Study of colloidal properties of natural and Al-pillared smectite and removal of copper ions from an aqueous solution.

Science.gov (United States)

Sartor, Lucas Resmini; de Azevedo, Antonio Carlos; Andrade, Gabriel Ramatis Pugliese

2015-01-01

In this study, an Al-pillared smectite was synthesized and changes in its colloidal properties were investigated. The pillaring solution was prepared by mixing 0.4 mol L(-1) NaOH and 0.2 mol L(-1) AlCl3.6H2O solutions. Intercalated clays were heated to obtain the pillared clay, and X-ray diffractometry (XRD), X-ray fluorescence (XRF), Fourier transform infrared (FTIR) spectroscopy and N2 sorption/desorption isotherms analysis were done to characterize the changes in clay properties. Moreover, adsorption experiments were carried out in order to evaluate the capacity of the pillared clays to remove Cu2+ from an aqueous solution and to characterize the interaction between adsorbent and adsorbate. The results indicate that the natural clay has a basal spacing of 1.26 nm, whereas the pillared clays reached 1.78 nm (500°C) and 1.80 nm (350°C) after calcination. XRF analysis revealed an increase in the Al3+ in the pillared clay as compared to the natural clay. The surface area and pore volume (micro and mesoporous) were higher for the pillared clays. Experimental data from the adsorption experiment were fit to Langmuir and Freundlich and Temkin adsorption models, and the former one was the best fit (highest r2 value) for all the clays and lower standard deviation (Δg%) for the natural clay. On the other hand, the Temkin model exhibited Δg% value lower for the pillared clays. Thermodynamics parameters demonstrate that the Cu2+ adsorption process is spontaneous for all the clays, but with higher values for the pillared materials. In addition, application of the Dubinin-Radushkevich model revealed that the bond between the metal and the clay are weak, characterizing a physisorption.
Aespoe Hard Rock Laboratory. Ground magnetic survey at site for planned facility for calibration of borehole orientation equipment at Aespoe

Energy Technology Data Exchange (ETDEWEB)

Mattsson, Haakan (GeoVista AB (Sweden))

2012-01-15

This report presents survey description and results of ground magnetic measurements carried out by GeoVista AB at Aespoe in December, 2011. The purpose of the ground magnetic measurement was to measure variations in the earth magnetic field and to gain knowledge of the magnetization of the bedrock in an area where SKB plan to build a facility for calibration of equipment for measurements of borehole orientation. A total of 312 data points were collected along three survey lines, 104 points/profile. The data show nice and smooth variations that appear to be natural. There is a clear consistency of the magnetic field variations between the three survey lines, which indicates that the variations in the magnetic field reflect geological variations related to lithology and content of magnetic minerals. There are no indications of artifacts or erroneous data. The anomaly field averages at -32 nT with peak values of Min = -1,016 nT and Max = +572 nT. The strongest anomalies occur at profile length c. 130-140 m. Adding the background field of 50,823 nT, measured at a base station located close to the survey area, the total magnetic field averages at 50,791+-226 nT. The ground magnetic measurement gives background information before the construction of the calibration facility. The magnetic anomaly at c. 130-140 m give possibilities to control disturbances of magnetic-accelerometer based instruments. The magnetic measurements show that it is possible to construct the facility at the site
Aespoe Hard Rock Laboratory. Ground magnetic survey at site for planned facility for calibration of borehole orientation equipment at Aespoe

International Nuclear Information System (INIS)

Mattsson, Haakan

2012-01-01

This report presents survey description and results of ground magnetic measurements carried out by GeoVista AB at Aespoe in December, 2011. The purpose of the ground magnetic measurement was to measure variations in the earth magnetic field and to gain knowledge of the magnetization of the bedrock in an area where SKB plan to build a facility for calibration of equipment for measurements of borehole orientation. A total of 312 data points were collected along three survey lines, 104 points/profile. The data show nice and smooth variations that appear to be natural. There is a clear consistency of the magnetic field variations between the three survey lines, which indicates that the variations in the magnetic field reflect geological variations related to lithology and content of magnetic minerals. There are no indications of artifacts or erroneous data. The anomaly field averages at -32 nT with peak values of Min = -1,016 nT and Max = +572 nT. The strongest anomalies occur at profile length c. 130-140 m. Adding the background field of 50,823 nT, measured at a base station located close to the survey area, the total magnetic field averages at 50,791±226 nT. The ground magnetic measurement gives background information before the construction of the calibration facility. The magnetic anomaly at c. 130-140 m give possibilities to control disturbances of magnetic-accelerometer based instruments. The magnetic measurements show that it is possible to construct the facility at the site
Aespoe Hard Rock Laboratory - feasibility and usefulness of site investigation methods. Experiences from the pre-investigation phase

Energy Technology Data Exchange (ETDEWEB)

Almen, K E [ed.; KEA GEO-Konsult (Sweden); Olsson, Paer [SKANSKA, (Sweden); Rhen, I [VBB VIAK AB, Malmoe (Sweden); Stanfors, R [RS Consulting, (Sweden); Wikberg, P [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden)

1994-08-01

One of the main goals set up by SKB for the Aespoe HRL project is to `test the quality and appropriateness of different methods for characterizing the bedrock with respect to conditions of importance for a final repository`. An extensive investigation programme was carried out during the projects pre-investigation phase that in part was based in experience from SKBs previous site investigations and in part entailed the testing of new or other unestablished methods. Previous technical reports have described the methods that have been used and the results, models and predictions that have been produced. All the methods used are discussed in the present report in terms of how they have contributed in different analysis stages to the total geoscientific characterization of the rock at Aespoe. The usefulness of each method for modelling and prediction in different scales is evaluated, and aspects of the practical execution of the methods under different conditions are discussed. The report sheds light on the importance of dividing large investigation programmes such as this one into suitable stages to get an opportunity to evaluate the results obtained and plan in detail the investigations in the next stage. Furthermore, the way in which the characterization/modelling work in different geometric scales has been done for the different investigation stages is discussed, along with whether this has been found to be a suitable approach. The importance of pursuing an interdisciplinary strategy throughout the pre-investigation process cannot be overemphasized. For the planning, execution, analysis and reporting of the results of the pre-investigations, this has been guaranteed by an organization in which an interdisciplinary group has been in charge of the investigations, together with the project manager. 52 refs, numerous tabs and figs.
Numerical Simulations of Pillar Structured Solid State Thermal Neutron Detector Efficiency and Gamma Discrimination

Energy Technology Data Exchange (ETDEWEB)

Conway, A; Wang, T; Deo, N; Cheung, C; Nikolic, R

2008-06-24

This work reports numerical simulations of a novel three-dimensionally integrated, {sup 10}boron ({sup 10}B) and silicon p+, intrinsic, n+ (PIN) diode micropillar array for thermal neutron detection. The inter-digitated device structure has a high probability of interaction between the Si PIN pillars and the charged particles (alpha and {sup 7}Li) created from the neutron - {sup 10}B reaction. In this work, the effect of both the 3-D geometry (including pillar diameter, separation and height) and energy loss mechanisms are investigated via simulations to predict the neutron detection efficiency and gamma discrimination of this structure. The simulation results are demonstrated to compare well with the measurement results. This indicates that upon scaling the pillar height, a high efficiency thermal neutron detector is possible.
Strength Reduction of Coal Pillar after CO2 Sequestration in Abandoned Coal Mines

Directory of Open Access Journals (Sweden)

Qiuhao Du

2017-02-01

Full Text Available CO2 geosequestration is currently considered to be the most effective and economical method to dispose of artificial greenhouse gases. There are a large number of coal mines that will be scrapped, and some of them are located in deep formations in China. CO2 storage in abandoned coal mines will be a potential option for greenhouse gas disposal. However, CO2 trapping in deep coal pillars would induce swelling effects of coal matrix. Adsorption-induced swelling not only modifies the volume and permeability of coal mass, but also causes the basic physical and mechanical properties changing, such as elastic modulus and Poisson ratio. It eventually results in some reduction in pillar strength. Based on the fractional swelling as a function of time and different loading pressure steps, the relationship between volumetric stress and adsorption pressure increment is acquired. Eventually, this paper presents a theory model to analyze the pillar strength reduction after CO2 adsorption. The model provides a method to quantitatively describe the interrelation of volumetric strain, swelling stress, and mechanical strength reduction after gas adsorption under the condition of step-by-step pressure loading and the non-Langmuir isothermal model. The model might have a significantly important implication for predicting the swelling stress and mechanical behaviors of coal pillars during CO2 sequestration in abandoned coal mines.
Some Thoughts about Literature as a Means of Advancing Sustainable Unity and Stability in the Contemporary Nigerian State

Science.gov (United States)

Anaso, George Nwaorah; Nwabudike, Christopher Eziafa

2014-01-01

An in-depth investigation was conducted on the possibility of literature employed to enhance cohesion, sustainable unity, national stability, and security of lives and property in the contemporary Nigeria. These three elements--unity, national stability, and security of lives and property are considered the key pillars of a modern state, the…
Improvement of thermoelectric properties induced by uniquely ordered lattice field in Bi2Se0.5Te2.5 pillar array

International Nuclear Information System (INIS)

Tan, Ming; Hao, Yanming; Wang, Gangzhi

2014-01-01

In this study, it was found that uniquely ordered lattice field favors transport of carriers but hinder that of phonons. The n-Bi 2 Se 0.5 Te 2.5 pillar array film was successfully achieved by a simple ion beam assisted deposition technique. This oriented pillar array structure is clear with pillar diameter of about 30 nm, exhibiting a uniquely ordered lattice field. The properties of the ordered Bi 2 Se 0.5 Te 2.5 pillar array were greatly enhanced in comparison with those of the ordinary film. The Bi 2 Se 0.5 Te 2.5 pillar array with a thermoelectric dimensionless figure-of-merit ZT=1.28 was obtained at room temperature. The in-plane transport mechanisms of the ordered pillar array and the ordinary structures, lattice field model, are proposed and investigated. The specially ordered lattice field is the main reason for the properties enhancement observed in the Bi 2 Se 0.5 Te 2.5 film. Introduction of such ordered lattice field into TE films is therefore a very promising approach. - Graphical abstract: In this study, it was found that uniquely ordered lattice field favors transport of carriers but hinder that of phonons. The Bi 2 Se 0.5 Te 2.5 pillar array film with a thermoelectric dimensionless figure-of-merit ZT=1.28 was obtained at room temperature. The in-plane transport mechanisms of the ordered pillar array and the ordinary structures, the lattice field model, are proposed and investigated. The specially ordered lattice field is the main reason for the properties enhancement observed in the Bi 2 Se 0.5 Te 2.5 pillar array. Introduction of such uniquely ordered lattice field into TE films is therefore a very promising approach. In (a) TEM and (b) HRTEM images of the ordered Bi 2 Se 0.5 Te 2.5 column array. - Highlights: • Uniquely ordered Bi 2 Se 0.5 Te 2.5 pillar array was achieved by an IBAD method. • The pillar array with an ordered lattice field exhibits attractive TE property. • The transport mechanism of such ordered pillar array is proposed and
Charge transport in nanoscale vertical organic semiconductor pillar devices

NARCIS (Netherlands)

Wilbers, J.G.E.; Xu, B.; Bobbert, P.A.; de Jong, M.P.; van der Wiel, W.G.

2017-01-01

We report charge transport measurements in nanoscale vertical pillar structures incorporating ultrathin layers of the organic semiconductor poly(3-hexylthiophene) (P3HT). P3HT layers with thickness down to 5 nm are gently top-contacted using wedging transfer, yielding highly reproducible, robust
Investigations into the residual strength of a 2.5 m wide Bushveld Merensky Reef crush pillar

CSIR Research Space (South Africa)

Watson, BP

2008-08-01

Full Text Available of falls of ground in already dangerous areas, and the larger pillars decrease the extraction ratio. This paper describes the evaluation of stress measurements conducted in two boreholes over a crush pillar with dimensions 2.5 m x 4.0 m, and a height of 1...
Cell motility regulation on a stepped micro pillar array device (SMPAD) with a discrete stiffness gradient.

Science.gov (United States)

Lee, Sujin; Hong, Juhee; Lee, Junghoon

2016-02-28

Our tissues consist of individual cells that respond to the elasticity of their environment, which varies between and within tissues. To better understand mechanically driven cell migration, it is necessary to manipulate the stiffness gradient across a substrate. Here, we have demonstrated a new variant of the microfabricated polymeric pillar array platform that can decouple the stiffness gradient from the ECM protein area. This goal is achieved via a "stepped" micro pillar array device (SMPAD) in which the contact area with the cell was kept constant while the diameter of the pillar bodies was altered to attain the proper mechanical stiffness. Using double-step SU-8 mold fabrication, the diameter of the top of every pillar was kept uniform, whereas that of the bottom was changed, to achieve the desired substrate rigidity. Fibronectin was immobilized on the pillar tops, providing a focal adhesion site for cells. C2C12, HeLa and NIH3T3 cells were cultured on the SMPAD, and the motion of the cells was observed by time-lapse microscopy. Using this simple platform, which produces a purely physical stimulus, we observed that various types of cell behavior are affected by the mechanical stimulus of the environment. We also demonstrated directed cell migration guided by a discrete rigidity gradient by varying stiffness. Interestingly, cell velocity was highest at the highest stiffness. Our approach enables the regulation of the mechanical properties of the polymeric pillar array device and eliminates the effects of the size of the contact area. This technique is a unique tool for studying cellular motion and behavior relative to various stiffness gradients in the environment.
Aespoe Hard Rock Laboratory. Final report of the first stage of the tracer retention understanding experiments

Energy Technology Data Exchange (ETDEWEB)

Winberg, A. [Conterra AB, Uppsala (Sweden); Andersson, Peter [Geosigma AB, Uppsala (Sweden); Hermanson, Jan [Golder Grundteknik, Solna (Sweden); Byegaard, Johan [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Nuclear Chemistry; Cvetkovic, V. [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Water Resources Engineering; Birgersson, Lars [Kemakta Konsult AB, Stockholm (Sweden)

2000-03-15

The first stage of the Tracer Retention Understanding Experiments (TRUE) was performed as a SKB funded project. The overall objectives of TRUE are to develop the understanding of radionuclide migration and retention in fractured rock, to evaluate the realism in applied model concepts, and to assess whether the necessary input data to the models can be collected from site characterisation. Further, to evaluate the usefulness and feasibility of different model approaches, and finally to provide in situ data on radionuclide migration and retention. The strive for address with multiple approaches is facilitated through a close collaboration with the Aespoe Task Force on Modelling of Groundwater Flow and Transport of Solutes. The TRUE programme is a staged programme which addresses various scales from laboratory (< 0.5 m), detailed scale (< 10 m) and block scale (10-50 m). The First TRUE Stage was performed in the detailed scale with the specific objectives of providing data and conceptualising the investigated feature using conservative and sorbing tracers. Further, to improve methodologies for performing tracer tests, and to develop and test a methodology for obtaining pore volume/aperture data from epoxy resin injection, excavation and subsequent analyses. The experimental site is located at approximately 400 m depth in the northeastern part of the Aespoe Hard Rock Laboratory. The identification of conductive fractures and the target feature has benefited from the use of BIPS borehole TV imaging combined with detailed flow logging. The assessment of the conductive geometry has been further sustained by cross-hole pressure interference data. The investigated target feature (Feature A) is a reactivated mylonite which has later undergone brittle deformation. The feature is oriented northwest, along the principal horizontal stress orientation, and is a typical conductor for Aespoe conditions. Hydraulic characterisation shows that the feature is relatively well isolated
Template-directed synthesis of pillared-porous carbon nanosheet architectures: High-performance electrode materials for supercapacitors

Energy Technology Data Exchange (ETDEWEB)

Fan, Zhuangjun; Liu, Yang; Yan, Jun; Wang, Qian; Wei, Tong [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin (China); Ning, Guoqing [State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, Changping (China); Zhi, Linjie [National Center for Nanoscience and Technology of China, Zhongguancun, Beijing (China); Wei, Fei [Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing (China)

2012-04-15

3D pillared-porous carbon nanosheets with supporting carbon pillars between the carbon layers is prepared by the carbonization of pitch on porous MgO templates. This unique structure endows the high-rate transportation of electrolyte ions and electrons throughout the electrode matrix, resulting in excellent electrochemical performance. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Quality factors of nonideal micro pillars

DEFF Research Database (Denmark)

Gregersen, Niels; Nielsen, Torben Roland; Tromborg, Bjarne

2007-01-01

The influence of fabrication-induced imperfections and material absorption on the quality (Q) factor of a microcavity pillar is studied numerically. The dependence on sidewall inclination, selective underetch, and intrinsic loss is quantified. The authors show that imperfections can lead to an im...... to an improvement in Q and that a sidewall inclination angle of less than 1° causes a dramatic change in the Q factor. The variations in Q can be attributed to a delicate balance between effective index contrasts, mode overlap, and higher-order mode contributions....
Interactions of Microbes found at Aespoe Underground Lab with Actinides such as Curium, Plutonium and Uranium

Energy Technology Data Exchange (ETDEWEB)

Moll, H.; Merroun, M.; Geipel, G.; Rossberg, A.; Hennig, C.; Selenska-Pobell , S.; Bernhard, G. [Forschungszentrum Dresden-Rossendorf e.V., Inst. fuer Radioc hemie, 01314 Dresden (Germany)]. e-mail: h.moll@fzd.de; Stumpf, Th. [Forschungszentru m Karlsruhe, Inst. fuer Nukleare Entsorgung, 76021 Karlsruhe (Germany)

2007-06-15

Sulfate-reducing bacteria (SRB) frequently occur in the deep granitic rock aquifers at the Aespoe Hard Rock Laboratory (Aespoe HRL), Sweden. The new SRB strain Desulfovibrio aespoeensis could be isolated. Results describing the basic interaction mechanisms of uranium, curium, and plutonium with cells of D. aespoeensis DSM 10631T will be presented. The interaction experiments with the actinides showed that the cells are able to remove all three actinides from the surrounding solution. The amount of removed actinide and the interaction mechanism varied among the different actinides. The main U(VI) removal occurred after the first 24 h. The contact time, pH and [U(VI)]initial influence the U removal efficiency. The presence of uranium caused a damaging of the cell membranes. TEM revealed an accumulation of U inside the bacterial cell. D. aespoeensis are able to form U(IV). A complex interaction mechanism takes place consisting of biosorption, bioreduction and bioaccumulation. In the case of {sup 242}Pu, solvent extractions, UV-vis- and XANES spectroscopy were used to determine the speciation of the Pu oxidation states. In the first step, the Pu(VI) and Pu(IV)-polymers are bound to the biomass. Solvent extractions showed that 97 % of the initially present Pu(VI) is reduced to Pu(V) due to the activity of the cells within the first 24 h. Most of the formed Pu(V) dissolves from the cell envelope back to the aqueous solution due to the weak complexing properties of this plutonium oxidation state. In the case of curium at a much lower metal concentration of 3x10{sup -7} M, a pure biosorption of Cm(III) on the cell envelope forming an inner-sphere surface complex most likely with organic phosphate groups was detected. To summarize, the strength of the interaction of D. aespoeensis with the selected actinides at pH 5 and actinide concentrations = 10 mg/L ([Cm] 0.07 mg/L) follows the pattern: Cm > U > Pu >> Np.
New developments of the Integrated Stress Determination Method and application to the Aespoe Hard Rock Laboratory, Sweden

International Nuclear Information System (INIS)

Ask, Daniel

2004-04-01

This thesis presents new developments of the Integrated Stress Determination Method (ISDM) with application to the Aespoe Hard Rock Laboratory (HRL), Oskarshamn, Sweden. The new developments involve a 12-parameter representation of the regional stress field in the rock mass. The method is applicable to data from hydraulic fracturing, hydraulic tests on pre-existing fractures (HTPF), and overcoring data from CSIR- and CSIRO-type of devices. When hydraulic fracturing/HTPF data are combined with overcoring data, the former may be used to constrain the elastic parameters, i.e. the problem involves 14 model parameters. The Swedish Nuclear Fuel and Waste Management Co. (SKB), have conducted a vast amount of rock stress measurements at the Aespoe HRL since the late 1980s. However, despite the large number of stress measurement data collected in this limited rock volume, variability in the stress field exists. Not only does the result vary depending on measuring technique, e.g. overcoring data indicated larger stress magnitudes compared to hydraulic fracturing data; the results are also affected by existing discontinuities, indicated by non-linear stress magnitudes and orientations versus depth. The objectives for this study are therefore threefold: (1) find explanations to the observed differences between existing hydraulic and overcoring stress data at the Aspo HRL; (2) explain the non-linear stress distribution indicated by existing stress data; and (3) apply the ISDM, including the new developments, based on the results obtained in step 1 and 2. To evaluate the observed differences between existing hydraulic and overcoring stress data, a detailed re-interpretation was conducted. Several measurement-related uncertainties were identified and corrected for when possible, which effectively reduced the discrepancies between the hydraulic and overcoring measuring results. Modeling studies managed by SKB have shown that the redistribution of the stresses at Aespoe HRL to a
Strategy for a Rock Mechanics Site Descriptive Model. A test case based on data from the Aespoe HRL

International Nuclear Information System (INIS)

Hudson, John A

2002-06-01

In anticipation of the SKB Site Investigations for radioactive waste disposal, an approach has been developed for the Rock Mechanics Site Descriptive Model. This approach was tested by predicting the rock mechanics properties of a 600 m x 180 m x 120 m rock volume at the Aespoe Hard Rock Laboratory (HRL) using limited borehole data of the type typically obtained during a site investigation. These predicted properties were then compared with 'best estimate' properties obtained from a study of the test rock volume using additional information, mainly tunnel data. The exercise was known as the Test Case, and is the subject of this Report. Three modelling techniques were used to predict the rock properties: the 'empirical approach' - the rock properties were estimated using rock mass classification schemes and empirical correlation formulae; the 'theoretical approach' - the rock properties were estimated using numerical modelling techniques; and the 'stress approach' - the rock stress state was estimated using primary data and numerical modelling. These approaches are described separately and respectively. Following an explanation of the context for the Test Case within the strategy for developing the Rock Mechanics Site Descriptive Model, conditions at the Aespoe HRL are described in Chapter 2. The Test Case organization and the suite of nine Protocols used to ensure that the work was appropriately guided and co-ordinated are described in Chapter 3. The methods for predicting the rock properties and the rock stress, and comparisons with the 'best estimate' properties of the actual conditions, are presented in Chapters 4 and 5. Finally, the conclusions from this Test Case exercise are given in Chapter 6. General recommendations for the management of this type of Test Case are also included
Strategy for a Rock Mechanics Site Descriptive Model. A test case based on data from the Aespoe HRL

Energy Technology Data Exchange (ETDEWEB)

Hudson, John A (ed.) [Rock Engineering Consultants, Welwyn Garden City (United Kingdom)

2002-06-01

In anticipation of the SKB Site Investigations for radioactive waste disposal, an approach has been developed for the Rock Mechanics Site Descriptive Model. This approach was tested by predicting the rock mechanics properties of a 600 m x 180 m x 120 m rock volume at the Aespoe Hard Rock Laboratory (HRL) using limited borehole data of the type typically obtained during a site investigation. These predicted properties were then compared with 'best estimate' properties obtained from a study of the test rock volume using additional information, mainly tunnel data. The exercise was known as the Test Case, and is the subject of this Report. Three modelling techniques were used to predict the rock properties: the 'empirical approach' - the rock properties were estimated using rock mass classification schemes and empirical correlation formulae; the 'theoretical approach' - the rock properties were estimated using numerical modelling techniques; and the 'stress approach' - the rock stress state was estimated using primary data and numerical modelling. These approaches are described separately and respectively. Following an explanation of the context for the Test Case within the strategy for developing the Rock Mechanics Site Descriptive Model, conditions at the Aespoe HRL are described in Chapter 2. The Test Case organization and the suite of nine Protocols used to ensure that the work was appropriately guided and co-ordinated are described in Chapter 3. The methods for predicting the rock properties and the rock stress, and comparisons with the 'best estimate' properties of the actual conditions, are presented in Chapters 4 and 5. Finally, the conclusions from this Test Case exercise are given in Chapter 6. General recommendations for the management of this type of Test Case are also included.
Empirical approach for designing of support system in mechanized coal pillar mining

Energy Technology Data Exchange (ETDEWEB)

Kushwaha, A.; Singh, S.K.; Tewari, S.; Sinha, A. [Central Institute of Mining & Fuel Research, Dhanbad (India)

2010-10-15

Mechanized room-and-pillar system of coal pillar mining using side dump loading machine or load haul dumper machine, or by continuous miner, is the presently most dominant under ground method of extraction in India. Under this method of extraction, strata control is a major problem affecting safety and productivity of the mine. As per existing Director General of Mine Safety guidelines, systematic support rules must be followed at the depillaring faces irrespective of immediate roof rock type and competency. Therefore, there is a high chance that sometimes these systematic support rules give unnecessarily high support, or sometimes inadequate support, which may lead to roof failure at the face. As a result, there is a big loss of life and material including coal in terms of left-outribs/stooks and other associated mining equipment deployed at the faces. Therefore, in the present paper, authors attempted to develop generalized empirical equations for estimating the required support load density at different places of the face based on geotechnical parameters of the mine and physico-mechanical properties of the immediate roof rocks for designing of support system during mechanized coal pillar mining.

PREPARATION AND CATALYTIC ACTIVITY FOR ISOPROPYL BENZENE CRACKING OF Co, Mo AND Co/Mo-Al2O3-PILLARED MONTMORILLONITE CATALYSTS

Directory of Open Access Journals (Sweden)

Hasanudin Hasanudin

2010-06-01

Full Text Available It has been prepared Co, Mo and Co/Mo-Al2O3-pillared montmorillonite catalysts using montmorillonite clay as raw material. The structure and porosity of the catalysts were determined using N2 adsorption-desorption and FT-IR spectroscopy analysis methods. Isopropyl benzene cracking using these catalysts were used to test the catalytic activity and performance of Co, Mo and Co/Mo-Al2O3-pillared montmorillonites. Characterization results showed that pillarization resulted in the increase of the total pore volume and specific surface area of the clay. Meanwhile, transition metals (Co, Mo and Co/Mo loaded on Al2O3-pillared monmorillonites could increase the catalytic activity of the catalysts for isopropyl benzene cracking significantly. Keywords: pillared monmorillonite, isopropyl benzene and cracking catalyst
An array of ordered pillars with retentive properties for pressure-driven liquid chromatography fabricated directly from an unmodified cyclo olefin polymer

NARCIS (Netherlands)

Illa, Xavi; de Malsche, Wim; Bomer, Johan G.; Gardeniers, Johannes G.E.; Eijkel, Jan C.T.; Morante, Joan Ramon; Romano-Rodriguez, Albert; Desmet, Gert

2009-01-01

The current paper describes the development and characterization of a pillar array chip that is constructed out of a sandwich of cyclo olefin polymer (COP) sheets. The silicon master of a 5 cm long pillar array was embossed into the COP, yielding 4.3 µm deep pillars of 15.3 µm diameter with an
Material versatility using replica molding for large-scale fabrication of high aspect-ratio, high density arrays of nano-pillars

International Nuclear Information System (INIS)

Li, Y; Menon, C; Ng, H W; Gates, B D

2014-01-01

Arrays of high aspect-ratio (AR) nano-pillars have attracted a lot of interest for various applications, such as for use in solar cells, surface acoustic sensors, tissue engineering, bio-inspired adhesives and anti-reflective surfaces. Each application may require a different structural material, which can vary in the required chemical composition and mechanical properties. In this paper, a low cost fabrication procedure is proposed for large scale, high AR and high density arrays of nano-pillars. The proposed method enables the replication of a master with high fidelity, using the subsequent replica molds multiple times, and preparing arrays of nano-pillars in a variety of different materials. As an example applied to bio-inspired dry adhesion, polymeric arrays of nano-pillars are prepared in this work. Thermoset and thermoplastic nano-pillar arrays are examined using an atomic force microscope to assess their adhesion strength and its uniformity. Results indicate the proposed method is robust and can be used to reliably prepare nano-structures with a high AR. (paper)
Experimental study of the retention properties of a cyclo olefin polymer pillar array column in reversed-phase mode

NARCIS (Netherlands)

Illa, Xavi; de Malsche, Wim; Gardeniers, Johannes G.E.; Desmet, Gert; Romano-Rodriguez, Albert

2010-01-01

Experimental measurements to study the retention capacity and band broadening under retentive conditions using micromachined non-porous pillar array columns fabricated in cyclo olefin polymer are presented. In particular, three columns with different depths but with the same pillar structure have
Rockburst Disaster Prediction of Isolated Coal Pillar by Electromagnetic Radiation Based on Frictional Effect

Science.gov (United States)

Zhao, Tongbin; Yin, Yanchun; Xiao, Fukun; Tan, Yunliang; Zou, Jianchao

2014-01-01

Based on the understanding that charges generated during coal cracking are due to coal particle friction, a microstructure model was developed by considering four different variation laws of friction coefficient. Firstly, the frictional energy release of coal sample during uniaxial compressive tests was investigated and discussed. Then electromagnetic radiation method was used to predict the potential rockburst disaster in isolated coal pillar mining face, Muchengjian Colliery. The results indicate that the friction coefficient of coal particles decreases linearly with the increase of axial loading force. In predicting the strain-type rockburst, the high stress state of coal must be closely monitored. Field monitoring shows that electromagnetic radiation signal became abnormal before the occurrence of rockburst during isolated coal pillar mining. Furthermore, rockburst tends to occur at the early and ending stages of isolated coal pillar extraction. Mine-site investigation shows the occurrence zone of rockburst is consistent with the prediction, proving the reliability of the electromagnetic radiation method to predict strain-type rockburst disaster. PMID:25054186
Rockburst Disaster Prediction of Isolated Coal Pillar by Electromagnetic Radiation Based on Frictional Effect

Directory of Open Access Journals (Sweden)

Tongbin Zhao

2014-01-01

Full Text Available Based on the understanding that charges generated during coal cracking are due to coal particle friction, a microstructure model was developed by considering four different variation laws of friction coefficient. Firstly, the frictional energy release of coal sample during uniaxial compressive tests was investigated and discussed. Then electromagnetic radiation method was used to predict the potential rockburst disaster in isolated coal pillar mining face, Muchengjian Colliery. The results indicate that the friction coefficient of coal particles decreases linearly with the increase of axial loading force. In predicting the strain-type rockburst, the high stress state of coal must be closely monitored. Field monitoring shows that electromagnetic radiation signal became abnormal before the occurrence of rockburst during isolated coal pillar mining. Furthermore, rockburst tends to occur at the early and ending stages of isolated coal pillar extraction. Mine-site investigation shows the occurrence zone of rockburst is consistent with the prediction, proving the reliability of the electromagnetic radiation method to predict strain-type rockburst disaster.
Catalytic Wastewater Treatment Using Pillared Clays

Science.gov (United States)

Perathoner, Siglinda; Centi, Gabriele

After introduction on the use of solid catalysts in wastewater treatment technologies, particularly advanced oxidation processes (AOPs), this review discussed the use of pillared clay (PILC) materials in three applications: (i) wet air catalytic oxidation (WACO), (ii) wet hydrogen peroxide catalytic oxidation (WHPCO) on Cu-PILC and Fe-PILC, and (iii) behavior of Ti-PILC and Fe-PILC in the photocatalytic or photo-Fenton conversion of pollutants. Literature data are critically analyzed to evidence the main direction to further investigate, in particularly with reference to the possible practical application of these technologies to treat industrial, municipal, or agro-food production wastewater.
A micro-pillar array to trap magnetic beads in microfluidic systems

KAUST Repository

Gooneratne, Chinthaka Pasan

2012-12-01

A micro-pillar array (MPA) is proposed in this paper to trap and separate magnetic beads (MBs) in microfluidic systems. MBs are used in many biomedical applications due to being compatible in dimension to biomolecules, the large surface area available to attach biomolecules, and the fact that they can be controlled by a magnetic field. Trapping and separating these labeled biomolecules is an important step toward achieving reliable and accurate quantification for disease diagnostics. Nickel Iron (Ni50Fe 50) micro-pillars were fabricated on a Silicon (Si) substrate by standard microfabrication techniques. Experimental results showed that MBs could be trapped on the MPA at the single bead level and separated from other non-target particles. This principle can easily be extended to trap and separate target biomolecules in heterogeneous biological samples. © 2012 IEEE.
Modeling plastic deformation of post-irradiated copper micro-pillars

Energy Technology Data Exchange (ETDEWEB)

Crosby, Tamer, E-mail: tcrosby@ucla.edu; Po, Giacomo, E-mail: gpo@ucla.edu; Ghoniem, Nasr M., E-mail: ghoniem@ucla.edu

2014-12-15

We present here an application of a fundamentally new theoretical framework for description of the simultaneous evolution of radiation damage and plasticity that can describe both in situ and ex situ deformation of structural materials [1]. The theory is based on the variational principle of maximum entropy production rate; with constraints on dislocation climb motion that are imposed by point defect fluxes as a result of irradiation. The developed theory is implemented in a new computational code that facilitates the simulation of irradiated and unirradiated materials alike in a consistent fashion [2]. Discrete Dislocation Dynamics (DDD) computer simulations are presented here for irradiated fcc metals that address the phenomenon of dislocation channel formation in post-irradiated copper. The focus of the simulations is on the role of micro-pillar boundaries and the statistics of dislocation pinning by stacking-fault tetrahedra (SFTs) on the onset of dislocation channel and incipient surface crack formation. The simulations show that the spatial heterogeneity in the distribution of SFTs naturally leads to localized plastic deformation and incipient surface fracture of micro-pillars.
Investigation of excavation stability in a finite repository

International Nuclear Information System (INIS)

St John, C.M.; Mitchell, S.J.

1987-05-01

Two-dimensional thermal-mechanical analyses of a hypothetical repository in tuff were performed using a boundary-element computer code, with the objective of investigating the relative stability of several waste emplacement panel access drifts. The drifts were assumed to be located within a central shaft pillar, within a small pillar between adjacent panels, or at the repository perimeter. The results of analyses indicate that matrix failure is unlikely and that the extent of activation of pre-existing joints is influenced by the drift location and the initial state of stress. The results also show that several years after waste emplacement the influence of the initial State of Stress is small compared to the influence of thermally induced stresses. Regions of joint activation are seen to be most extensive around the drifts between adjacent panels. The predicted extent of such activation was small when it was assumed that the joints were vertical or near vertical. More extensive regions of activation of shallow dipping joints were noted. However, joints of such orientation are believed to occur relatively infrequently in the candidate horizon for waste emplacement and the activation of the shallow dipping joints does not necessarily lead to drift stability concerns. 3 refs., 24 figs., 7 tabs
Experimental study of the retention properties of a cyclo olefin polymer pillar array column in reversed-phase mode.

Science.gov (United States)

Illa, Xavi; De Malsche, Wim; Gardeniers, Han; Desmet, Gert; Romano-Rodríguez, Albert

2010-11-01

Experimental measurements to study the retention capacity and band broadening under retentive conditions using micromachined non-porous pillar array columns fabricated in cyclo olefin polymer are presented. In particular, three columns with different depths but with the same pillar structure have been fabricated via hot embossing and pressure-assisted thermal bonding. Separations of a mixture of four coumarins using varying mobile phase compositions have been monitored to study the relation between the retention factor and the ratio of organic solvent in the aqueous mobile phase. Moreover, the linear relation between the retention and the surface/volume ratio predicted in theory has been observed, achieving retention factors up to k=2.5. Under the same retentive conditions, minimal reduced plate height values of h(min)=0.4 have been obtained at retention factors of k=1.2. These experimental results are compared with the case of non-porous and porous silicon pillars. Similar results for the plate heights are achieved while retention factors are higher than the non-porous silicon column and considerably smaller than the porous pillar column, given the non-porous nature of the used cyclo olefin polymer. The feasibility of using this polymer column as an alternative to the pillar array silicon columns is corroborated.
Use of site specific data from Aespoe - preliminary results from the on-going safety analysis SR 97

International Nuclear Information System (INIS)

Stroem, A.; Selroos, J.O.; Andersson, Johan

1998-01-01

This paper discusses an on-going safety assessment study of SKB as well as the use of field data from Aespoe for obtaining input parameters for flow and radionuclide transport modelling in the geosphere. In the on-going Safety Assessment study SR 97, three individual sites in Sweden are used for exemplifying site specific conditions on overall repository performance. Thus, models capable of reproducing site specific characteristics are utilised. This is primarily obtained by implementing the geologic structural models in suitable conceptual models for groundwater flow on both regional and local scales. The models for flow incorporate observed and/or inferred water conducting features as well as other site-specific characteristics necessary for realistic descriptions of flow at the sites. The flow modelling thus aims at realism; the results obtained for present day conditions should not in any serious aspect conflict with observations at the site. Agreement between observed and modelled entities provides confidence in that a sound understanding of the site is obtained. Aespoe is one of the three sites providing site-specific conditions in SR 97. Transport is subsequently modelled using a stream tube approach where the 'travel times', for non-sorbing species, and discharge locations of a set of one-dimensional stream tubes are obtained from particle tracking in the flow model. The resulting distribution of 'travel times' in a single model realisation reflects the spatial variability and spatial extent of the repository, whereas the ensemble travel time distribution (over several realisations) for a given canister location reflects the uncertainty in travel time. The actual transport paths used in the transport modelling are thus dependent on site specific information such as e.g. existence of water conductive features. Other input parameters to the transport model are based on more generic and/or conservative arguments. However, the goal in a safety assessment
Fabrication and characterization of Au dimer antennas on glass pillars with enhanced plasmonic response

Directory of Open Access Journals (Sweden)

Sadeghi Pedram

2017-06-01

Full Text Available We report on the fabrication and dark-field spectroscopy characterization of Au dimer nanoantennas placed on top of SiO2 nanopillars. The reported process enables the fabrication of nanopillar dimers with gaps down to 15 nm and heights up to 1 μm. A clear dependence of the plasmonic resonance position on the dimer gap is observed for smaller pillar heights, showing the high uniformity and reproducibility of the process. It is shown how increasing the height of nanopillars significantly affects the recorded elastic scattering spectra from Au nanoantennas. The results are compared to finite-difference time-domain (FDTD and finite-element method (FEM simulations. Additionally, measured spectra are accompanied by dark-field microscopy images of the dimers, showing the pronounced change in color. Placing nanoantennas on nanopillars with a height comparable to the in-plane dimer dimensions results in an enhancement of the scattering response, which can be understood through reduced interaction of the near-fields with the substrate. When increasing the pillar height further, scattering by the pillars themselves manifests itself as a strong tail at lower wavelengths. Additionally, strong directional scattering is expected as a result of the interface between the nanoantennas and nanopillars, which is taken into account in simulations. For pillars of height close to the plasmonic resonance wavelength, the scattering spectra become more complex due to additional scattering peaks as a result of larger geometrical nonuniformities.
Macroprudential policy and financial stability

Directory of Open Access Journals (Sweden)

Bogdan CHIRIACESCU

2013-02-01

Full Text Available This paper tries a conceptual framing of the issue of financial stability in economic theory and also to identify solutions to address episodes of financial instability. An essential reference is Minsky's financial instability hypothesis, which argues that a fundamental feature of the financial system is that it swings between robustness and fragility and these pendulum swings are an integral part of the process that generates the business cycle. Studies show that the effects of banking crises on economic activity are important both in magnitude and duration. Recently, macroprudential policy stood out as a central pillar in promoting financial stability in a broad sense. Regarding specific objectives of macroprudential policy, the prevalent vision refers to limiting systemic risk and macroeconomic costs of financial crises, but there are also important nuances.
A comparative UV-vis-diffuse reflectance study on the location and interaction of cerium ions in Al- and Zr-pillared montmorillonite clays

International Nuclear Information System (INIS)

Rao, G. Ranga; Mishra, Braja Gopal

2005-01-01

The environment, location and interaction of the Ce 3+ ions in the micropores of Al- and Zr-pillared clays have been studied by UV-vis-diffuse reflectance spectroscopy (UV-vis-DRS). The DRS spectra show that the chemical environment of the Ce 3+ ions in cerium exchanged clay is different from that of the Al- and Zr-pillared clays. The Al-Ce pillared clays (Al-Ce-PM) show four distinct absorption bands at 224, 263, 294 and 342 nm in the UV region which are attributed to 4f → 5d interconfigurational transitions of Ce 3+ ions associated with alumina pillars. The O 2- → Ce 3+ charge transfer band observed at 263 nm for Ce-exchanged and Al-Ce-PM clays is blue shifted by 10 nm for Ce-Zr-pillared clays (Ce-Zr-PM) due to fully hydrated Ce 3+ ions. The Ce 3+ ions are incorporated in the Al- and Zr-pillars possibly as AlCeO 3 and Ce x Zr 1-x O 2 particles upon heat treatment
Numerical Analysis of Warpage Induced by Thermo-Compression Bonding Process of Cu Pillar Bump Flip Chip Package

Energy Technology Data Exchange (ETDEWEB)

Kwon, Oh Young; Jung, Hoon Sun; Lee, Jung Hoon; Choa, Sung-Hoon [Seoul Nat’l Univ. of Science and Technology, Seoul (Korea, Republic of)

2017-06-15

In flip chip technology, the conventional solder bump has been replaced with a copper (Cu) pillar bump owing to its higher input/output (I/O) density, finer pitch, and higher reliability. However, Cu pillar bump technology faces several issues, such as interconnect shorting and higher low-k stress due to stiffer Cu pillar structure when the conventional reflow process is used. Therefore, the thermal compression bonding (TCB) process has been adopted in the flip chip attachment process in order to reduce the package warpage and stress. In this study, we investigated the package warpage induced during the TCB process using a numerical analysis. The warpage of the TCB process was compared with that of the reflow process.
Evaluating 8 pillars of Total Productive Maintenance (TPM) implementation and their contribution to manufacturing performance

Science.gov (United States)

Adesta, E. Y. T.; Prabowo, H. A.; Agusman, D.

2018-01-01

TPM is one method to improve manufacturing performance through an emphasis on maintenance that involves everyone in the organization. Research on the application of TPM and its relevance to the manufacturing performance has been performed quite a lot. However, to the best of our knowledge, a study that deliberates how the application of 8 pillars TPM (especially in developing countries) is still hard to find. This paper attempts to evaluate in more detail about how the 8 pillars of TPM are applied in Indonesia and their impact on manufacturing performance. This research is a pilot study with a target of 50 companies. From the results of data collection, only 22 companies (44%) are eligible to process. Data processing was performed using SPSS and Smart PLS tools. From the validity and reliability tests, it can be seen that all items/indicators for TPM pillars are valid and reliable with correlation value (R) of 0.614 - 0.914 and with Cronbach’s alpha equal to 0.753. As for the Manufacturing Performance construct, the Delivery indicator was not valid. In overall, the model is reliable with Cronbach’s alpha of 0.710. From the results of Confirmatory Factors Analysis (CFA) for TPM, it can be seen that four indicators (pillars) are highly significant while four other indicators are less significant. For MP, three indicators are significant, and two are not significant. In general, the structural model of the relationship between TPM and MP is relatively strong and positive with values R = 0.791, and R squared = 0.626. This means that the TPM Pillars can explain 62.6% MP variability construct variable, while the other 37.4% can be explained by unrelated variables.
Determination of concrete cover thickness in a reinforced concrete pillar by observation of the scattered electromagnetic field

Science.gov (United States)

Di Gregorio, Pietro Paolo; Frezza, Fabrizio; Mangini, Fabio; Pajewski, Lara

2017-04-01

The electromagnetic scattered field by a reinforced concrete structure is calculated by means of frequency-domain numerical simulations and by making use of the scattered-field formulation. The concrete pillar, used as supporting architectural element, is modelled as a parallelepiped shell made of concrete material inside which are present steel bars. In order to make the model simpler, the steel bars are supposed running parallel to the air-pillar interface. To excite the model, a linearly-polarized plane wave impinging normally with respect to the pillars surface, is adopted. We consider two different polarizations in order to determine the most useful in terms of scattered-field sensitivity. Moreover, a preliminary frequency sweep allows us to choose the most suitable operating frequency depending on the dimensions of the pillar cross-section, the steel bars cross-section and the concrete cover. All the three components of the scattered field are monitored along a line just above the interface air-pillar. The electromagnetic properties of the materials employed in this study are present in the literature and, since a frequency-domain technique is adopted, no further approximation is needed. The results obtained for different values of the concrete cover are compared, with the goal of determining the scattered field dependence on the concrete cover thickness. Considering different concrete cover thicknesses, we want to provide an electromagnetic method to obtain this useful parameter by observation of the scattered electromagnetic field. One of the practical applications of this study in the field of Civil Engineering may be the use of ground penetrating radar (GPR) techniques to monitor the thickness of the concrete that separates the metal bars embedded in the pillar from the outer surface. A correct distance is useful because the concrete cover serves as a protection against external agents avoiding corrosion of the bars that might prejudice the reinforced
Pretest parametric calculations for the heated pillar experiment in the WIPP In-Situ Experimental Area

International Nuclear Information System (INIS)

Branstetter, L.J.

1983-03-01

Results are presented for a pretest parametric study of several configurations and heat loads for the heated pillar experiment (Room H) in the Waste Isolation Pilot Plant (WIPP) In Situ Experimental Area. The purpose of this study is to serve as a basis for selection of a final experiment geometry and heat load. The experiment consists of a pillar of undisturbed rock salt surrounded by an excavated annular room. The pillar surface is covered by a blanket heat source which is externally insulated. A total of five thermal and ten structural calculations are described in a four to five year experimental time frame. Results are presented which include relevant temperature-time histories, deformations, rock salt stress component and effective stress profiles, and maximum stresses in anhydrite layers which are in close proximity to the room. Also included are predicted contours of a conservative post-processed measure of potential salt failure. Observed displacement histories are seen to be highly dependent on pillar and room height, but insensitive to other geometrical variations. The use of a tensile cutoff across slidelines is seen to produce more accurate predictions of anhydrite maximum stress, but to have little effect on rock salt stresses. The potential for salt failure is seen to be small in each case for the time frame of interest, and is only seen at longer times in the center of the room floor
Mechanical properties of nano and bulk Fe pillars using molecular dynamics and dislocation dynamics simulation

Directory of Open Access Journals (Sweden)

S. K. Deb Nath

2017-10-01

Full Text Available Using molecular dynamics simulation, tension and bending tests of a Fe nanopillar are carried out to obtain its Young’s modulus and yield strength. Then the comparative study of Young’s modulus and yield strength of a Fe nanopillar under bending and tension are carried out varying its diameter in the range of diameter 1-15nm. We find out the reasons why bending Young’s modulus and yield strength of a Fe nanopillar are higher than those of tension Young’s modulus and yield strength of a Fe nanopillar. Using the mobility parameters of bulk Fe from the experimental study [N. Urabe and J. Weertman, Materials Science and Engineering 18, 41 (1975], its temperature dependent stress-strain relationship, yield strength and strain hardening modulus are obtained from the dislocation dynamics simulations. Strain rate dependent yield strength and strain hardening modulus of bulk Fe pillars under tension are studied. Temperature dependent creep behaviors of bulk Fe pillars under tension are also studied. To verify the soundness of the present dislocation dynamics studies of the mechanical properties of bulk Fe pillars under tension, the stress vs. strain relationship and dislocation density vs. strain of bulk Fe pillars obtained by us are compared with the published results obtained by S. Queyreau, G. Monnet, and B. Devincre, International Journal of Plasticity 25, 361 (2009.

A micro-pillar array to trap magnetic beads in microfluidic systems

KAUST Repository

Gooneratne, Chinthaka Pasan; Kosel, Jü rgen

2012-01-01

A micro-pillar array (MPA) is proposed in this paper to trap and separate magnetic beads (MBs) in microfluidic systems. MBs are used in many biomedical applications due to being compatible in dimension to biomolecules, the large surface area
Mean wall-shear stress measurements using the micro-pillar shear-stress sensor MPS3

International Nuclear Information System (INIS)

Große, S; Schröder, W

2008-01-01

A new sensor to measure the mean turbulent wall-shear stress in turbulent flows is described. The wall-shear stress sensor MPS 3 has been tested in a well-defined fully developed turbulent pipe flow at Reynolds numbers Re b based on the bulk velocity U b and the pipe diameter D in the range of Re b = 10 000–20 000. The results demonstrate a convincing agreement of the mean wall-shear stress obtained with the new sensor technique with analytical and experimental results from the literature. The sensor device consists of a flexible micro-pillar that extends from the wall into the viscous sublayer. Bending due to the exerting fluid forces, the pillar-tip deflection serves as a measure for the local wall-shear stress. The sensor concept, calibration techniques, the achievable accuracy and error estimates, the fields of application and the sensor limits will be discussed. Furthermore, a first estimate of the pillar dynamic response will be derived showing the potential of the sensor to also measure the turbulent fluctuating wall-shear stress
The molecular environment of the pillar-like features in the H II region G46.5-0.2

Science.gov (United States)

Paron, S.; Celis Peña, M.; Ortega, M. E.; Fariña, C.; Petriella, A.; Rubio, M.; Ashley, R. P.

2017-10-01

At the interface of H II regions and molecular gas, peculiar structures appear, some of them with pillar-like shapes. Understanding their origin is important for characterizing triggered star formation and the impact of massive stars on the interstellar medium. In order to study the molecular environment and influence of radiation on two pillar-like features related to the H II region G46.5-0.2, we performed molecular line observations with the Atacama Submillimeter Telescope Experiment and spectroscopic optical observations with the Isaac Newton Telescope. From the optical observations, we identified the star that is exciting the H II region as spectral type O4-6. The molecular data allowed us to study the structure of the pillars and an HCO+ cloud lying between them. In this HCO+ cloud, which has no well-defined 12CO counterpart, we found direct evidence of star formation: two molecular outflows and two associated near-IR nebulosities. The outflow axis orientation is perpendicular to the direction of the radiation flow from the H II region. Several Class I sources are also embedded in this HCO+ cloud, showing that it is usual that young stellar objects (YSOs) form large associations occupying a cavity bounded by pillars. On the other hand, it was confirmed that the radiation-driven implosion (RDI) process is not occurring in one of the pillar tips.
Straightforward Generation of Pillared, Microporous Graphene Frameworks for Use in Supercapacitors.

Science.gov (United States)

Yuan, Kai; Xu, Yazhou; Uihlein, Johannes; Brunklaus, Gunther; Shi, Lei; Heiderhoff, Ralf; Que, Mingming; Forster, Michael; Chassé, Thomas; Pichler, Thomas; Riedl, Thomas; Chen, Yiwang; Scherf, Ullrich

2015-11-01

Microporous, pillared graphene-based frameworks are generated in a simple functionalization/coupling procedure starting from reduced graphene oxide. They are used for the fabrication of high-performance supercapacitor devices. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Effects of focused ion beam milling on the compressive behavior of directionally solidified micro-pillars and the nanoindentation response of an electro-polished surface

International Nuclear Information System (INIS)

Shim, Sang Hoon; Bei, Hongbin; Miller, Michael K; Pharr, George Mathews; George, Easo P

2009-01-01

Focused ion beam (FIB) milling is the typical way in which micro-pillars are fabricated to study small-scale plasticity and size effects in uniaxial compression. However, FIB milling can introduce defects into the milled pillars. To investigate the effects of FIB damage on mechanical behavior, we tested Mo-alloy micro-pillars that were FIB milled following directional solidification, and compared their compressive response to pillars that were not FIB milled. We also FIB milled at glancing incidence a Mo-alloy single-crystal surface, and compared its nanoindentation response to an electro-polished surface of the same crystal. Consequences for the interpretation of data obtained from FIB milled micro-pillars are discussed
A family of porous lonsdaleite-e networks obtained through pillaring of decorated kagomé lattice sheets

KAUST Repository

Schoedel, Alexander; Boyette, Wesley; Wojtas, Łukasz; Eddaoudi, Mohamed; Zaworotko, Michael J.

2013-01-01

A new and versatile class of metal-organic materials (MOMs) with augmented lonsdaleite-e (lon-e-a) topology is presented herein. This family of lon-e nets are built by pillaring of hexagonal two-dimensional kagomé (kag) lattices constructed from well-known [Zn2(CO2R)4] paddlewheel molecular building blocks (MBBs) connected by 1,3- benzenedicarboxylate (bdc2-) linkers. The pillars are [Cr 3(μ3-O)(RCO2)]6 trigonal prismatic primary MBBs decorated by six pyridyl moieties (tp-PMBB-1). The three-fold symmetry (D3h) of tp-PMBB-1 is complementary with the alternating orientation of the axial sites of the paddlewheel MBBs and enables triple cross-linking of the kag layers by each pillar. These MOMs represent the first examples of axial-to-axial pillared undulating kag layers, and they are readily fine-tuned because the bdc2- moieties can be varied at their 5-position without changing the overall structure. This lon-e platform possesses functionalized hexagonal channels since the kag lattices are necessarily eclipsed. The effects of the substituent at the 5-positions of the bdc 2- linkers upon gas adsorption, particularly the heats of adsorption of carbon dioxide and methane, were studied. © 2013 American Chemical Society.
A family of porous lonsdaleite-e networks obtained through pillaring of decorated kagomé lattice sheets

KAUST Repository

Schoedel, Alexander

2013-09-25

A new and versatile class of metal-organic materials (MOMs) with augmented lonsdaleite-e (lon-e-a) topology is presented herein. This family of lon-e nets are built by pillaring of hexagonal two-dimensional kagomé (kag) lattices constructed from well-known [Zn2(CO2R)4] paddlewheel molecular building blocks (MBBs) connected by 1,3- benzenedicarboxylate (bdc2-) linkers. The pillars are [Cr 3(μ3-O)(RCO2)]6 trigonal prismatic primary MBBs decorated by six pyridyl moieties (tp-PMBB-1). The three-fold symmetry (D3h) of tp-PMBB-1 is complementary with the alternating orientation of the axial sites of the paddlewheel MBBs and enables triple cross-linking of the kag layers by each pillar. These MOMs represent the first examples of axial-to-axial pillared undulating kag layers, and they are readily fine-tuned because the bdc2- moieties can be varied at their 5-position without changing the overall structure. This lon-e platform possesses functionalized hexagonal channels since the kag lattices are necessarily eclipsed. The effects of the substituent at the 5-positions of the bdc 2- linkers upon gas adsorption, particularly the heats of adsorption of carbon dioxide and methane, were studied. © 2013 American Chemical Society.
The Issue of Data Protection and Data Security in the (Pre-Lisbon EU Third Pillar

Directory of Open Access Journals (Sweden)

Maria O'Neill

2010-06-01

Full Text Available The key functional operability in the pre-Lisbon PJCCM pillar of the EU is the exchange of intelligence and information amongst the law enforcement bodies of the EU. The twin issues of data protection and data security within what was the EU’s third pillar legal framework therefore come to the fore. With the Lisbon Treaty reform of the EU, and the increased role of the Commission in PJCCM policy areas, and the integration of the PJCCM provisions with what have traditionally been the pillar I activities of Frontex, the opportunity for streamlining the data protection and data security provisions of the law enforcement bodies of the post-Lisbon EU arises. This is recognised by the Commission in their drafting of an amending regulation for Frontex , when they say that they would prefer “to return to the question of personal data in the context of the overall strategy for information exchange to be presented later this year and also taking into account the reflection to be carried out on how to further develop cooperation between agencies in the justice and home affairs field as requested by the Stockholm programme.” The focus of the literature published on this topic, has for the most part, been on the data protection provisions in Pillar I, EC. While the focus of research has recently sifted to the previously Pillar III PJCCM provisions on data protection, a more focused analysis of the interlocking issues of data protection and data security needs to be made in the context of the law enforcement bodies, particularly with regard to those which were based in the pre-Lisbon third pillar. This paper will make a contribution to that debate, arguing that a review of both the data protection and security provision post-Lisbon is required, not only in order to reinforce individual rights, but also inter-agency operability in combating cross-border EU crime. The EC’s provisions on data protection, as enshrined by Directive 95/46/EC, do not apply
Porous Structures in Stacked, Crumpled and Pillared Graphene-Based 3D Materials.

Science.gov (United States)

Guo, Fei; Creighton, Megan; Chen, Yantao; Hurt, Robert; Külaots, Indrek

2014-01-01

Graphene, an atomically thin material with the theoretical surface area of 2600 m 2 g -1 , has great potential in the fields of catalysis, separation, and gas storage if properly assembled into functional 3D materials at large scale. In ideal non-interacting ensembles of non-porous multilayer graphene plates, the surface area can be adequately estimated using the simple geometric law ~ 2600 m 2 g -1 /N, where N is the number of graphene sheets per plate. Some processing operations, however, lead to secondary plate-plate stacking, folding, crumpling or pillaring, which give rise to more complex structures. Here we show that bulk samples of multilayer graphene plates stack in an irregular fashion that preserves the 2600/N surface area and creates regular slot-like pores with sizes that are multiples of the unit plate thickness. In contrast, graphene oxide deposits into films with massive area loss (2600 to 40 m 2 g -1 ) due to nearly perfect alignment and stacking during the drying process. Pillaring graphene oxide sheets by co-deposition of colloidal-phase particle-based spacers has the potential to partially restore the large monolayer surface. Surface areas as high as 1000 m 2 g -1 are demonstrated here through colloidal-phase deposition of graphene oxide with water-dispersible aryl-sulfonated ultrafine carbon black as a pillaring agent.
Environmental Remediation and Sorption of Metal Cations Using Aluminum Pillared Nano-Bentonite

Science.gov (United States)

Rifai, Rifai; Abou El Safa, Magda

2015-04-01

The release of heavy metal cations into the environment is a potential threat to water and soil quality. Some clay minerals play an important role, as physical and chemical barriers, for the isolation of metal-rich wastes and to adsorb heavy metals as well as to avoid their environmental dispersion. In the present study, the bentonitic clay (southeast El-Hammam City, Egypt) was subjected to pillaring using hydroxyl-aluminum solution. The XRD patterns of the Aluminum Pillared Nano-Bentonite (APNB) showed severe alteration of the crystal structure after pillaring. Poly metal solutions with different metal concentrations of Cu, Co, Ni, Zn, Cd and Pb (0.001, 0.005 and 0.01 moles), and pH (1, 2.5, 5 and 6) were subjected to treatment by the APNB. The removal process is very rapid and spontaneous and the contact time may be short (several minutes) for most adsorption to occur. The criterion for environmental remediation of APNB is less stringent and a short contact time is sufficient. The rate of Cu2+, Zn2+, Co2+, Cd2+, Ni2+ and Pb2+sorption remained higher or equal to the CEC. The sorption of metal ions by APNB are complex and probably involve several mechanisms. In general, APNB can be used to immobilize Cu2+, Zn2+, Co2+, Cd2+, Ni2+ and Pb2+ to any extent. For each metal ion, the most effective immobilization occurs over a particular pH around 5. According to the experimental data obtained, the uptake amount of the studied cations by APNB increased with increasing solution pH, sorbent dose and contact time. The preference of the APNB adsorption for heavy metal ions that are through the cation exchange processes decreases in the order: Cu2+>Zn2+>Co2+>Cd2+ >Ni2+ >Pb2+. Keywords: Bentonitic clay, Egypt, Aluminum Pillared Nano-Bentonite, heavy metal, environmental remediation
Single macroscopic pillars as model system for bioinspired adhesives: influence of tip dimension, aspect ratio, and tilt angle.

Science.gov (United States)

Micciché, Maurizio; Arzt, Eduard; Kroner, Elmar

2014-05-28

The goal of our study is to better understand the design parameters of bioinspired dry adhesives inspired by geckos. For this, we fabricated single macroscopic pillars of 400 μm diameter with different aspect ratios and different tip shapes (i.e., flat tips, spherical tips with different radii, and mushroom tips with different diameters). Tilt-angle-dependent adhesion measurements showed that although the tip shape of the pillars strongly influences the pull-off force, the pull-off strength is similar for flat and mushroom-shaped tips. We found no tilt-angle dependency of adhesion for spherical tip structures and, except for high tilt angle and low preload experiments, no tilt-angle effect for mushroom-tip pillars. For flat-tip pillars, we found a strong influence of tilt angle on adhesion, which decreased linearly with increasing aspect ratio. The experiments show that for the tested aspect ratios between 1 and 5, a linear decrease of tilt-angle dependency is found. The results of our studies will help to design bioinspired adhesives for application on smooth and rough surfaces.
In situ synthesis, characterization, and catalytic performance of tungstophosphoric acid encapsulated into the framework of mesoporous silica pillared clay.

Science.gov (United States)

Li, Baoshan; Liu, Zhenxing; Han, Chunying; Ma, Wei; Zhao, Songjie

2012-07-01

Mesoporous silica pillared clay (SPC) incorporated with tungstophosphoric acid (HPW) has been synthesized via in situ introducing P and W source in the acidic suspension of the clay interlayer template during the formation of the silica pillared clay. The samples were characterized by XRD, XRF, FT-IR, TG-DTA, N(2) adsorption-desorption, and SEM techniques. The results showed that the HPW formed by in situ method has been effectively introduced into the framework of mesoporous silica pillared clay and its Keggin structure remained perfectly after formation of the materials. In addition, samples with similar HPW loadings were also prepared by impregnation method using SPC as the support. HPW in the incorporated samples was better dispersed into the silica pillared clay than in the impregnated samples. The results of catalytic tests indicated that the encapsulated materials demonstrated better catalytic performance than the impregnated samples in oxidative desulfurization (ODS) of dibenzothiophene (DBT). Copyright © 2012 Elsevier Inc. All rights reserved.
Validation of groundwater flow model using the change of groundwater flow caused by the construction of AESPOE hard rock laboratory

International Nuclear Information System (INIS)

Hasegawa, Takuma; Tanaka, Yasuharu

2004-01-01

A numerical model based on results during pre-investigation phases was applied to the groundwater flow change caused by the construction of AEspoe HRL. The drawdowns and chloride concentration during tunnel construction were simulated to validate the numerical model. The groundwater flow was induced by inflow from the Baltic Sea to the tunnel through the hydraulic conductor domain (HCD). The time series of tunnel progress and inflow, boundaries of the Baltic Sea, transmissivity and geometry of HCD are therefore important in representing the groundwater flow. The numerical model roughly represented the groundwater flow during tunnel construction. These simulations were effective in validating the numerical model for groundwater flow and solute transport. (author)
Improving wettability of photo-resistive film surface with plasma surface modification for coplanar copper pillar plating of IC substrates

International Nuclear Information System (INIS)

Xiang, Jing; Wang, Chong; Chen, Yuanming; Wang, Shouxu; Hong, Yan; Zhang, Huaiwu; Gong, Lijun; He, Wei

2017-01-01

Highlights: • Air atmosphere plasmacould generatehydrophilic groups of photo-resistive film. • Better wettability of photo-resistive filmled tohigher plating uniformity of copper pillars. • New flow isreduced cost, simplified process and elevated productivity. - Abstract: The wettability of the photo-resistive film (PF) surfaces undergoing different pretreatments including the O_2−CF_4 low-pressure plasma (OCLP) and air plasma (AP), is investigated by water contact angle measurement instrument (WCAMI) before the bottom-up copper pillar plating. Chemical groups analysis performed by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and X-ray photoelectron spectra (XPS) shows that after the OCLP and wash treatment, the wettability of PF surface is attenuated, because embedded fluorine and decreased oxygen content both enhance hydrophobicity. Compared with OCLP treatment, the PF surface treatment by non-toxic air plasma displays features of C−O, O−C=O, C=O and −NO_2 by AIR-FTIR and XPS, and a promoted wettability by WCAM. Under the identical electroplating condition, the surface with a better wettability allows electrolyte to spontaneously soak all the places of vias, resulting in improved copper pillar uniformity. Statistical analysis of metallographic data shows that more coplanar and flat copper pillars are achieved with the PF treatment of air plasma. Such modified copper-pillar-plating technology meets the requirement of accurate impedance, the high density interconnection for IC substrates.
Adsorption of cadmium onto Al{sub 13}-pillared acid-activated montmorillonite

Energy Technology Data Exchange (ETDEWEB)

Yan Liangguo [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085 (China); Shan Xiaoquan [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085 (China)], E-mail: xiaoquan@rcees.ac.cn; Wen Bei [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085 (China); Owens, Gary [Centre for Environmental Risk Assessment and Remediation, University of South Australia, Mawson Lakes Campus, Mawson Lakes, Boulevard, South Australia 5095 (Australia)

2008-08-15

The optimal preparation conditions for Al{sub 13}-pillared acid-activated Na{sup +}-montmorillonite (Al{sub 13}-PAAMt) were (1) an acid-activated Na{sup +}-montmorillonite (Na{sup +}-Mt) solution of pH 3.0, (2) a OH{sup -}/Al{sup 3+} molar ratio of 2.4 and (3) Al{sup 3+}/Na{sup +}-Mt ratio of 1.0 mmol g{sup -1}. The effects of OH{sup -}/Al{sup 3+} and Al{sup 3+}/Na{sup +}-Mt ratios on the adsorption of Cd{sup 2+} onto Al{sub 13}-PAAMt were studied. A comparison of the adsorption of Cd{sup 2+} onto Al{sub 13}-PAAMt, Al{sub 13}-pillared Na{sup +}-montmorillonite (Al{sub 13}-PMt) and Na{sup +}-Mt suggested that Al{sub 13}-PAAMt had higher adsorption affinity for Cd{sup 2+} than the other two adsorbents. A pseudo-second-order model described the adsorption kinetics well. Cadmium adsorption followed the Langmuir two-site equation, while desorption was hysteretic.
Basel’s Forgotten Pillar: The Myth of Market Discipline on the Forefront of Basel III

Directory of Open Access Journals (Sweden)

Vahit Ferhan Benli

2016-01-01

Full Text Available Although Basel II fortified the first two pillars with market transparency enhancing Pillar III disclosures and encouraged the usage of major Credit Rating Agencies (CRAs such as Moody’s, Standard and Poor’s, and Fitch as quasi governmental authorities to overcome asymmetric informational problems on risk and capital adequacy fronts of the global financial system, the recent global financial crisis has proven just the opposite. The banks and regulators were not in a position to truly assess the risk and capital adequacy frameworks of the global and domestic financial institutions based on the assessments of the rating agencies. To overcome the problem of informational asymmetry for the market participants, the Basel Committee on Banking Supervision set out new proposals for enhanced Pillar III disclosures in the areas of credit risks and capital reporting standards on the forefront of Basel III that would come into effect on April 1, 2016. This paper is a critical evaluation of the new reporting proposals of BCBS within the critical role of the credit rating agencies.
Parallel-plate submicron gap formed by micromachined low-density pillars for near-field radiative heat transfer

International Nuclear Information System (INIS)

Ito, Kota; Miura, Atsushi; Iizuka, Hideo; Toshiyoshi, Hiroshi

2015-01-01

Near-field radiative heat transfer has been a subject of great interest due to the applicability to thermal management and energy conversion. In this letter, a submicron gap between a pair of diced fused quartz substrates is formed by using micromachined low-density pillars to obtain both the parallelism and small parasitic heat conduction. The gap uniformity is validated by the optical interferometry at four corners of the substrates. The heat flux across the gap is measured in a steady-state and is no greater than twice of theoretically predicted radiative heat flux, which indicates that the parasitic heat conduction is suppressed to the level of the radiative heat transfer or less. The heat conduction through the pillars is modeled, and it is found to be limited by the thermal contact resistance between the pillar top and the opposing substrate surface. The methodology to form and evaluate the gap promotes the near-field radiative heat transfer to various applications such as thermal rectification, thermal modulation, and thermophotovoltaics
Parallel-plate submicron gap formed by micromachined low-density pillars for near-field radiative heat transfer

Energy Technology Data Exchange (ETDEWEB)

Ito, Kota, E-mail: kotaito@mosk.tytlabs.co.jp [Toyota Central Research and Development Laboratories, Nagakute, Aichi 480-1192 (Japan); Research Center for Advanced Science and Technology (RCAST), The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8904 (Japan); Miura, Atsushi; Iizuka, Hideo [Toyota Central Research and Development Laboratories, Nagakute, Aichi 480-1192 (Japan); Toshiyoshi, Hiroshi [Research Center for Advanced Science and Technology (RCAST), The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8904 (Japan)

2015-02-23

Near-field radiative heat transfer has been a subject of great interest due to the applicability to thermal management and energy conversion. In this letter, a submicron gap between a pair of diced fused quartz substrates is formed by using micromachined low-density pillars to obtain both the parallelism and small parasitic heat conduction. The gap uniformity is validated by the optical interferometry at four corners of the substrates. The heat flux across the gap is measured in a steady-state and is no greater than twice of theoretically predicted radiative heat flux, which indicates that the parasitic heat conduction is suppressed to the level of the radiative heat transfer or less. The heat conduction through the pillars is modeled, and it is found to be limited by the thermal contact resistance between the pillar top and the opposing substrate surface. The methodology to form and evaluate the gap promotes the near-field radiative heat transfer to various applications such as thermal rectification, thermal modulation, and thermophotovoltaics.
Impact of the limitations of state-of-the-art micro-fabrication processes on the performance of pillar array columns for liquid chromatography.

Science.gov (United States)

Op de Beeck, Jeff; De Malsche, Wim; Tezcan, Deniz S; De Moor, Piet; Desmet, Gert

2012-05-25

We report on the practical limitations of the current state-of-the-art in micro-fabrication technology to produce the small pillar sizes that are needed to obtain high efficiency pillar array columns. For this purpose, nine channels with a different pillar diameter, ranging from 5 to 0.5 μm were fabricated using state-of the-art deep-UV lithography and deep reactive ion etching (DRIE) etching technology. The obtained results strongly deviated from the theoretically expected trend, wherein the minimal plate height (H(min)) would reduce linearly with the pillar diameter. The minimal plate height decreases from 1.7 to 1.2 μm when going from 4.80 to 3.81 μm diameter pillars, but as the dimensions are further reduced, the minimal plate heights rise again to values around 2 μm. The smallest pillar diameter even produced the worst minimal plate height (4 μm). An in-depth scanning electron microscopy (SEM) inspection of the different channels clearly reveals that these findings can be attributed to the micro-fabrication limitations that are inevitably encountered when exploring the limits of deep-UV lithography and DRIE etching processes. When the target dimensions of the design approach the etching resolution limits, the band broadening increases in a strongly non-linear way with the decreased pillar dimensions. This highly non-linear relationship can be understood from first principles: when the machining error is of the order of 100-200 nm and when the target design size for the inter-pillar distance is of the order of 250 nm, this inevitably leads to pores that will range in size between 50 and 450 nm that we want to highlight with our paper highly non-linear relationship. This highly non-linear relationship can be understood from first principles: when the machining error is of the order of 100-200 nm and when the target design size for the inter-pillar distance is of the order of 250 nm, this inevitably leads to pores that will range in size between 50 and 450
Pillar size optimization design of isolated island panel gob-side entry driving in deep inclined coal seam—case study of Pingmei No. 6 coal seam

Science.gov (United States)

Zhang, Shuai; Wang, Xufeng; Fan, Gangwei; Zhang, Dongsheng; Jianbin, Cui

2018-06-01

There is a perception that deep roadways are difficult to maintain. To reverse this and to improve the recovery rate of coal resources, gob-side entry driving is widely used in coal mines, especially deep-mining coal mines, in China. Determination of the reasonable pillar size through in situ observation and experimentation plays a vital role for roadway maintenance. Based on the geological conditions of Pingmei No.6 coal seam, a theoretical analysis, numerical simulation, and industrial experiments are carried out to calculate the reasonable width of chain pillars, analyze the lateral support stress distribution law near the gob side, investigate the relationship between the coal pillar stress distribution, roadway surrounding rock stress distribution, roadway surrounding rock deformation and the coal pillar width. The results indicate that 5 m wide coal pillars can ensure that the chain pillars are at a lower stress level and the deformation of roadway surrounding rock is in a more reasonable range. Industrial experiments show that when the chain pillar width is 5 m, the deformation of roadway surrounding rock can meet the requirements of working face safe production. The numerical results agreed well with field measurement and observations, and the industrial experiments results further validated the results of the numerical simulation.

Effects of PCB Pad Metal Finishes on the Cu-Pillar/Sn-Ag Micro Bump Joint Reliability of Chip-on-Board (COB) Assembly

Science.gov (United States)

Kim, Youngsoon; Lee, Seyong; Shin, Ji-won; Paik, Kyung-Wook

2016-06-01

While solder bumps have been used as the bump structure to form the interconnection during the last few decades, the continuing scaling down of devices has led to a change in the bump structure to Cu-pillar/Sn-Ag micro-bumps. Cu-pillar/Sn-Ag micro-bump interconnections differ from conventional solder bump interconnections in terms of their assembly processing and reliability. A thermo-compression bonding method with pre-applied b-stage non-conductive films has been adopted to form solder joints between Cu pillar/Sn-Ag micro bumps and printed circuit board vehicles, using various pad metal finishes. As a result, various interfacial inter-metallic compounds (IMCs) reactions and stress concentrations occur at the Cu pillar/Sn-Ag micro bumps joints. Therefore, it is necessary to investigate the influence of pad metal finishes on the structural reliability of fine pitch Cu pillar/Sn-Ag micro bumps flip chip packaging. In this study, four different pad surface finishes (Thin Ni ENEPIG, OSP, ENEPIG, ENIG) were evaluated in terms of their interconnection reliability by thermal cycle (T/C) test up to 2000 cycles at temperatures ranging from -55°C to 125°C and high-temperature storage test up to 1000 h at 150°C. The contact resistances of the Cu pillar/Sn-Ag micro bump showed significant differences after the T/C reliability test in the following order: thin Ni ENEPIG > OSP > ENEPIG where the thin Ni ENEPIG pad metal finish provided the best Cu pillar/Sn-Ag micro bump interconnection in terms of bump joint reliability. Various IMCs formed between the bump joint areas can account for the main failure mechanism.
Synthesis of SnO2 pillared carbon using long chain alkylamine grafted graphene oxide: an efficient anode material for lithium ion batteries.

Science.gov (United States)

Reddy, M Jeevan Kumar; Ryu, Sung Hun; Shanmugharaj, A M

2016-01-07

With the objective of developing new advanced composite materials that can be used as anodes for lithium ion batteries (LIBs), herein we describe the synthesis of SnO2 pillared carbon using various alkylamine (hexylamine; dodecylamine and octadecylamine) grafted graphene oxides and butyl trichlorotin precursors followed by its calcination at 500 °C for 2 h. While the grafted alkylamine induces crystalline growth of SnO2 pillars, thermal annealing of alkylamine grafted graphene oxide results in the formation of amorphous carbon coated graphene. Field emission scanning electron microscopy (FE-SEM) results reveal the successful formation of SnO2 pillared carbon on the graphene surface. X-ray diffraction (XRD), transmission electron microscopy (TEM) and Raman spectroscopy characterization corroborates the formation of rutile SnO2 crystals on the graphene surface. A significant rise in the BET surface area is observed for SnO2 pillared carbon, when compared to pristine GO. Electrochemical characterization studies of SnO2 pillared carbon based anode materials showed an enhanced lithium storage capacity and fine cyclic performance in comparison with pristine GO. The initial specific capacities of SnO2 pillared carbon are observed to be 1379 mA h g(-1), 1255 mA h g(-1) and 1360 mA h g(-1) that decrease to 750 mA h g(-1), 643 mA h g(-1) and 560 mA h g(-1) depending upon the chain length of grafted alkylamine on the graphene surface respectively. Electrochemical impedance spectral analysis reveals that the exchange current density of SnO2 pillared carbon based electrodes is higher, corroborating its enhanced electrochemical activity in comparison with GO based electrodes.
Improving wettability of photo-resistive film surface with plasma surface modification for coplanar copper pillar plating of IC substrates

Energy Technology Data Exchange (ETDEWEB)

Xiang, Jing; Wang, Chong; Chen, Yuanming; Wang, Shouxu; Hong, Yan; Zhang, Huaiwu [State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054 (China); Gong, Lijun [Research and Development Department, Guangzhou Fastprint Circuit Tech Co., Ltd., Guangzhou 510663 (China); He, Wei, E-mail: heweiz@uestc.edu.cn [State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054 (China); Research and Development Department, Guangdong Guanghua Sci-Tech Co., Ltd., Shantou 515000 (China)

2017-07-31

Highlights: • Air atmosphere plasmacould generatehydrophilic groups of photo-resistive film. • Better wettability of photo-resistive filmled tohigher plating uniformity of copper pillars. • New flow isreduced cost, simplified process and elevated productivity. - Abstract: The wettability of the photo-resistive film (PF) surfaces undergoing different pretreatments including the O{sub 2}−CF{sub 4} low-pressure plasma (OCLP) and air plasma (AP), is investigated by water contact angle measurement instrument (WCAMI) before the bottom-up copper pillar plating. Chemical groups analysis performed by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and X-ray photoelectron spectra (XPS) shows that after the OCLP and wash treatment, the wettability of PF surface is attenuated, because embedded fluorine and decreased oxygen content both enhance hydrophobicity. Compared with OCLP treatment, the PF surface treatment by non-toxic air plasma displays features of C−O, O−C=O, C=O and −NO{sub 2} by AIR-FTIR and XPS, and a promoted wettability by WCAM. Under the identical electroplating condition, the surface with a better wettability allows electrolyte to spontaneously soak all the places of vias, resulting in improved copper pillar uniformity. Statistical analysis of metallographic data shows that more coplanar and flat copper pillars are achieved with the PF treatment of air plasma. Such modified copper-pillar-plating technology meets the requirement of accurate impedance, the high density interconnection for IC substrates.
High-Q submicron-diameter quantum-dot microcavity pillars for cavity QED experiments

DEFF Research Database (Denmark)

Gregersen, Niels; Lermer, Matthias; Dunzer, Florian

As/AlAs micropillar design where Bloch-wave engineering is employed to significally enhance the cavity mode confinement in the submicron diameter regime. We demonstrate a record-high vacuum Rabi splitting of 85 µeV of the strong coupling for pillars incorporating quantum dots with modest oscillator strength f ≈ 10....... It is well-known that light-matter interaction depends on the photonic environment, and thus proper engineering of the optical mode in microcavity systems is central to obtaining the desired functionality. In the strong coupling regime, the visibility of the Rabi splitting is described by the light...... coupling in micropillars relied on quantum dots with high oscillator strengths f > 50, our advanced design allows for the observation of strong coupling for submicron diameter quantum dot-pillars with standard f ≈ 10 oscillator strength. A quality factor of 13600 and a vacuum Rabi splitting of 85 µe...
Analisis dan Perancangan Aplikasi Berbasis Web E-Procurement di PT Pillar Utama Contrindo

Directory of Open Access Journals (Sweden)

Sartika Kurniali

2012-12-01

Full Text Available The aim of this research is to analyze the current business process at the procurement department at PT Pillar Utama Contrindo as well as develop a web based e-procurement application prototype to supportprocurement process at the company. Interview, survey, as well as analysis and design to develop the prototype are used in the research. The research results in an e-procurement application prototype built to minimize errors on related document filling, help the company to get best price on their supply, and increase control. It can be concluded from the research that the protoype can be implemented to be a tool for the users to decide the best supplier, obtain the best price, and increase control in buying process at PT Pillar Utama Contrindo.
Fabrication method to create high-aspect ratio pillars for photonic coupling of board level interconnects

Science.gov (United States)

Debaes, C.; Van Erps, J.; Karppinen, M.; Hiltunen, J.; Suyal, H.; Last, A.; Lee, M. G.; Karioja, P.; Taghizadeh, M.; Mohr, J.; Thienpont, H.; Glebov, A. L.

2008-04-01

An important challenge that remains to date in board level optical interconnects is the coupling between the optical waveguides on printed wiring boards and the packaged optoelectronics chips, which are preferably surface mountable on the boards. One possible solution is the use of Ball Grid Array (BGA) packages. This approach offers a reliable attachment despite the large CTE mismatch between the organic FR4 board and the semiconductor materials. Collimation via micro-lenses is here typically deployed to couple the light vertically from the waveguide substrate to the optoelectronics while allowing for a small misalignment between board and package. In this work, we explore the fabrication issues of an alternative approach in which the vertical photonic connection between board and package is governed by a micro-optical pillar which is attached both to the board substrate and to the optoelectronic chips. Such an approach allows for high density connections and small, high-speed detector footprints while maintaining an acceptable tolerance between board and package. The pillar should exhibit some flexibility and thus a high-aspect ratio is preferred. This work presents and compares different fabrication methods and applies different materials for such high-aspect ratio pillars. The different fabrication methods are: photolithography, direct laser writing and deep proton writing. The selection of optical materials that was investigated is: SU8, Ormocers, PU and a multifunctional acrylate polymer. The resulting optical pillars have diameters ranging from 20um up to 80um, with total heights ranging between 30um and 100um (symbol for micron). The aspect-ratio of the fabricated structures ranges from 1.5 to 5.
UNESCO: The four pillars of ‘postmodern education’”

OpenAIRE

Silva, Lenildes Ribeiro

2008-01-01

This article sets out to establish a relationship between discussions on education mentioned in the report to UNESCO – Education: a treasure to discover – and Lyotard’s post-modernity discourse. It presents the proposal for education from this report, highlighting the four pillars of education: learning to know, learning to do, learning to be and live together, taking as their starting point the relationship between the process of globalization and the discourse of postmodernity and these pil...
Improving wettability of photo-resistive film surface with plasma surface modification for coplanar copper pillar plating of IC substrates

Science.gov (United States)

Xiang, Jing; Wang, Chong; Chen, Yuanming; Wang, Shouxu; Hong, Yan; Zhang, Huaiwu; Gong, Lijun; He, Wei

2017-07-01

The wettability of the photo-resistive film (PF) surfaces undergoing different pretreatments including the O2sbnd CF4 low-pressure plasma (OCLP) and air plasma (AP), is investigated by water contact angle measurement instrument (WCAMI) before the bottom-up copper pillar plating. Chemical groups analysis performed by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and X-ray photoelectron spectra (XPS) shows that after the OCLP and wash treatment, the wettability of PF surface is attenuated, because embedded fluorine and decreased oxygen content both enhance hydrophobicity. Compared with OCLP treatment, the PF surface treatment by non-toxic air plasma displays features of Csbnd O, Osbnd Cdbnd O, Cdbnd O and sbnd NO2 by AIR-FTIR and XPS, and a promoted wettability by WCAM. Under the identical electroplating condition, the surface with a better wettability allows electrolyte to spontaneously soak all the places of vias, resulting in improved copper pillar uniformity. Statistical analysis of metallographic data shows that more coplanar and flat copper pillars are achieved with the PF treatment of air plasma. Such modified copper-pillar-plating technology meets the requirement of accurate impedance, the high density interconnection for IC substrates.
The role of SiGe buffer in growth and relaxation of Ge on free-standing Si(001) nano-pillars.

Science.gov (United States)

Zaumseil, P; Kozlowski, G; Schubert, M A; Yamamoto, Y; Bauer, J; Schülli, T U; Tillack, B; Schroeder, T

2012-09-07

We study the growth and relaxation processes of Ge nano-clusters selectively grown by chemical vapor deposition on free-standing 90 nm wide Si(001) nano-pillars with a thin Si(0.23)Ge(0.77) buffer layer. We found that the dome-shaped SiGe layer with a height of about 28 nm as well as the Ge dot deposited on top of it partially relaxes, mainly by elastic lattice bending. The Si nano-pillar shows a clear compliance behavior-an elastic response of the substrate on the growing film-with the tensile strained top part of the pillar. Additional annealing at 800 °C leads to the generation of misfit dislocation and reduces the compliance effect significantly. This example demonstrates that despite the compressive strain generated due to the surrounding SiO(2) growth mask it is possible to realize an overall tensile strain in the Si nano-pillar and following a compliant substrate effect by using a SiGe buffer layer. We further show that the SiGe buffer is able to improve the structural quality of the Ge nano-dot.
Large spin current injection in nano-pillar-based lateral spin valve

Energy Technology Data Exchange (ETDEWEB)

Nomura, Tatsuya [Department of Physics, Kyushu University, 744 Motooka, Fukuoka, 819-0395 (Japan); Ohnishi, Kohei; Kimura, Takashi, E-mail: t-kimu@phys.kyushu-u.ac.jp [Department of Physics, Kyushu University, 744 Motooka, Fukuoka, 819-0395 (Japan); Research Center for Quantum Nano-Spin Sciences, Kyushu University, 744 Motooka, Fukuoka, 819-0395 (Japan)

2016-08-26

We have investigated the influence of the injection of a large pure spin current on a magnetization process of a non-locally located ferromagnetic dot in nano-pillar-based lateral spin valves. Here, we prepared two kinds of the nano-pillar-type lateral spin valve based on Py nanodots and CoFeAl nanodots fabricated on a Cu film. In the Py/Cu lateral spin valve, although any significant change of the magnetization process of the Py nanodot has not been observed at room temperature. The magnetization reversal process is found to be modified by injecting a large pure spin current at 77 K. Switching the magnetization by the nonlocal spin injection has also been demonstrated at 77 K. In the CoFeAl/Cu lateral spin valve, a room temperature spin valve signal was strongly enhanced from the Py/Cu lateral spin valve because of the highly spin-polarized CoFeAl electrodes. The room temperature nonlocal switching has been demonstrated in the CoFeAl/Cu lateral spin valve.
Writing and functionalisation of suspended DNA nanowires on superhydrophobic pillar arrays

KAUST Repository

Miele, Ermanno; Accardo, Angelo; Falqui, Andrea; Marini, Monica; Giugni, Andrea; Leoncini, Marco; De Angelis, Francesco De; Krahne, Roman; Di Fabrizio, Enzo M.

2014-01-01

Nanowire arrays and networks with precisely controlled patterns are very interesting for innovative device concepts in mesoscopic physics. In particular, DNA templates have proven to be versatile for the fabrication of complex structures that obtained functionality via combinations with other materials, for example by functionalisation with molecules or nanoparticles, or by coating with metals. Here, the controlled motion of the a three-phase contact line (TCL) of DNA-loaded drops on superhydrophobic substrates is used to fabricate suspended nanowire arrays. In particular, the deposition of DNA wires is imaged in situ, and different patterns are obtained on hexagonal pillar arrays by controlling the TCL velocity and direction. Robust conductive wires and networks are achieved by coating the wires with a thin layer of gold, and as proof of concept conductivity measurements are performed on single suspended wires. The plastic material of the superhydrophobic pillars ensures electrical isolation from the substrate. The more general versatility of these suspended nanowire networks as functional templates is outlined by fabricating hybrid organic-metal-semiconductor nanowires by growing ZnO nanocrystals onto the metal-coated nanowires.
Writing and functionalisation of suspended DNA nanowires on superhydrophobic pillar arrays

KAUST Repository

Miele, Ermanno

2014-08-08

Nanowire arrays and networks with precisely controlled patterns are very interesting for innovative device concepts in mesoscopic physics. In particular, DNA templates have proven to be versatile for the fabrication of complex structures that obtained functionality via combinations with other materials, for example by functionalisation with molecules or nanoparticles, or by coating with metals. Here, the controlled motion of the a three-phase contact line (TCL) of DNA-loaded drops on superhydrophobic substrates is used to fabricate suspended nanowire arrays. In particular, the deposition of DNA wires is imaged in situ, and different patterns are obtained on hexagonal pillar arrays by controlling the TCL velocity and direction. Robust conductive wires and networks are achieved by coating the wires with a thin layer of gold, and as proof of concept conductivity measurements are performed on single suspended wires. The plastic material of the superhydrophobic pillars ensures electrical isolation from the substrate. The more general versatility of these suspended nanowire networks as functional templates is outlined by fabricating hybrid organic-metal-semiconductor nanowires by growing ZnO nanocrystals onto the metal-coated nanowires.
Origin, Development and Decline of Monolithic Pillars and the Continuity of the Tradition in Polylithic, Non-Lithic and Structural Forms

Directory of Open Access Journals (Sweden)

S. Krishnamurthy

2016-02-01

Full Text Available The present paper deals with one such creations of Man, i.e. the tradition of erecting free standing monolithic pillars - its origin, growth and decline and the continuity of the tradition of erecting such pillars in its changed polylithic (from Greek word polloi = many + lithic = stone, non-lithic and structural forms. No exact reason can be found, pointing it to be the exact cause for the decline in the tradition of erecting monolithic pillar and its transformation. In this paper the authors try to analyse various phenomenon likesocio-political, economic and technical aspects which may have lead to their decline and subsequently their continuity in a changed form in Indian context.
SITE 94. Modelling of groundwater chemistry at Aespoe Hard Rock Laboratory

Energy Technology Data Exchange (ETDEWEB)

Emren, A.T. [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Nuclear Chemistry

1999-02-01

of the groundwater appears to be mostly a consequence of chemical reactions between water and fracture filling minerals. This has been studied in simulations where rain has been allowed to enter a fracture. Although there are some differences, the results found in this modelling generally are similar to the observed values. The deviations suggest that the fracture filling minerals alone are not enough to explain the observed groundwater chemistry. This should not be expected, since the old waters found hundreds of meters below the surface have been able to react with other mineral sets as well. In the CRACKER simulations it has been found that the simulated waters are similar to observations with respect to redox properties. The Aespoe groundwaters have iron concentrations which are low compared to those found in other deep Swedish groundwaters. By inhibiting reactions in the simulations, it has been found unlikely that the Fe(II) - Fe(III) redox couple is the main controller of the redox properties in Aespoe groundwaters. Rather, it appears that the redox properties can be maintained even if reactions with this couple are inhibited. According to the simulation results, reactions in which dissolved hydrogen, carbonates and methane are participating are important. This does not mean that iron species and minerals are not involved in redox processes. The simulation methods have been applied to possible future events and processes. As examples of such, the effects of elevated temperature on the groundwater properties have been investigated as well as a prediction on possible effects of Baltic Sea water intrusion 58 refs, figs
SITE 94. Modelling of groundwater chemistry at Aespoe Hard Rock Laboratory

International Nuclear Information System (INIS)

Emren, A.T.

1999-02-01

of the groundwater appears to be mostly a consequence of chemical reactions between water and fracture filling minerals. This has been studied in simulations where rain has been allowed to enter a fracture. Although there are some differences, the results found in this modelling generally are similar to the observed values. The deviations suggest that the fracture filling minerals alone are not enough to explain the observed groundwater chemistry. This should not be expected, since the old waters found hundreds of meters below the surface have been able to react with other mineral sets as well. In the CRACKER simulations it has been found that the simulated waters are similar to observations with respect to redox properties. The Aespoe groundwaters have iron concentrations which are low compared to those found in other deep Swedish groundwaters. By inhibiting reactions in the simulations, it has been found unlikely that the Fe(II) - Fe(III) redox couple is the main controller of the redox properties in Aespoe groundwaters. Rather, it appears that the redox properties can be maintained even if reactions with this couple are inhibited. According to the simulation results, reactions in which dissolved hydrogen, carbonates and methane are participating are important. This does not mean that iron species and minerals are not involved in redox processes. The simulation methods have been applied to possible future events and processes. As examples of such, the effects of elevated temperature on the groundwater properties have been investigated as well as a prediction on possible effects of Baltic Sea water intrusion
PILLARED ZEOLITES AMENDMENTS INFLUENCE FROM POLLUTED SOIL ON HEAVY METALS BIOACCUMULATION IN TOMATOES

Directory of Open Access Journals (Sweden)

SMARANDA MASU

2007-05-01

Full Text Available Due to anthropic activities, the presence of metals in polluted soils has effects on plants development and metals bioaccumulation into trophic levels. In this paper, were followed experiments regarding the tomatoes development into polluted soils with 43.4 – 58.4 mg Cd/kg d.s. and 500- 633 mg Pb/kg d.s. Nickel, zinc and copper content in soils are in the range of diffuse pollution values. Comparatively, an experiment was realized with polluted soils and amended with pillared zeolites. Pillared zeolites change metals distribution in soil fractions and their solubility. Tomato plants grew onto polluted soils, but did not present fruits. Tomatoes from polluted and amended soils presented fruits and metals in tissues (Zn  Cu  Ni. Zinc concentration was five times greater then Ni. Fruits do not accumulate cadmium and lead.
Palaeohydrological implications in the Baltic area and its relation to the groundwater at Aespoe, south-eastern Sweden - A literature study

Energy Technology Data Exchange (ETDEWEB)

Wallin, B [Geokema AB, Lidingoe (Sweden)

1995-03-01

A literature study of different groundwaters in the circum Baltic region is presented in this work. The study is mainly focused on the isotopic signatures observed in different groundwaters in Sweden and Finland. Several saline groundwaters in the Baltic region at depth of 150 to 500m depth show stable ({delta}D, {delta}{sup 13}C, {delta}{sup 18}O) and radiogenic ({delta}{sup 87}Sr) isotope assembly which is suggestive of a marine origin. However, a discrepancy is sometimes observed between the stable as well as radiogenic isotopes of the intermediate groundwater, which suggest a mixture of fossil marine water and a post-glacial runoff of melt water. In order to explain this phenomenon, the initial setting in {delta}{sup 18}O may have been depleted due to large input of high latitude marine water or cold melt waters. A solution to the contradiction between the strontium ({delta}{sup 87}Sr) and stable isotope ({delta}D, {delta}{sup 13}C, {delta}{sup 18}O) signatures of the groundwater and of the calcite fracture fillings at Aespoe and other places is attained, if it is assumed that the strontium in Baltic Sea water has undergone a significant decrease in {delta}{sup 87}Sr since the last glaciation. A scenario can be constructed to suggest that the Baltic Sea during the initial stage of the Litorina sea (8000 to 5000 Y B.P.) contained strontium with much larger {delta}{sup 87}Sr values. Another explanation for the positive {delta}{sup 87}Sr values may be due to water/rock interaction between the groundwater and the abundant fracture clay minerals, which are observed at Aespoe. Typically most of the saline groundwaters occur both in Sweden and Finland below the highest marine shore line during the Holocene. Almost all inland groundwaters show a totally different pattern which is typically non marine, meteoric in origin. (Abstract Truncated)
Real Time Grouting Control Method. Development and application using Aespoe HRL data

International Nuclear Information System (INIS)

Kobayashi, Shinji; Stille, Haakan; Gustafson, Gunnar; Stille, Bjoern

2008-10-01

The spread of grout is governed by a number of complex relations. The desired results, such as grout penetration and sealing of fractures, cannot be directly measured during the grouting process. This means that the issue of how or when the injection of grout should be stopped cannot be answered by simple rules of thumb. This is also the background to the great variety of empirical rules used in the grouting sector worldwide. The research during recent years has given a better understanding of the water-bearing structures of the rock mass as well as analytical solutions. In this report the methodology has been further studied and a method for design and control of rock grouting has been proposed. The concept of what we call the 'Real Time Grouting Control Method' is to calculate the grout penetration and control grouting in real time by applying the development of the theories for grout spread. Our intention is to combine our method with a computerized logging tool to acquire an active tool in order to be able to govern the grout spread in real time during the grouting operation. The objectives of this report are: to further develop the theory concerning the relationship between grout penetration and grouting time to describe the real course of grouting, to establish the concept of 'Real Time Grouting Control Method' for design and control for rock grouting based on the developed theory, and to verify the concept by using the field data from the grouting experiment at the 450 m level in the Aespoe HRL. In this report, the approximations and analysis of dimensionality have been checked and further developments of the theory with respect to varying grouting pressure, time-dependent grout properties, changing grout mixes, and changing the flow dimension of the fracture have been carried out. The concept of 'Real Time Grouting Control Method' has been described in order to calculate the grout penetration and to control grouting in real time by applying developed
Single-step direct fabrication of pillar-on-pore hybrid nanostructures in anodizing aluminum for superior superhydrophobic efficiency.

Science.gov (United States)

Jeong, Chanyoung; Choi, Chang-Hwan

2012-02-01

Conventional electrochemical anodizing processes of metals such as aluminum typically produce planar and homogeneous nanopore structures. If hydrophobically treated, such 2D planar and interconnected pore structures typically result in lower contact angle and larger contact angle hysteresis than 3D disconnected pillar structures and, hence, exhibit inferior superhydrophobic efficiency. In this study, we demonstrate for the first time that the anodizing parameters can be engineered to design novel pillar-on-pore (POP) hybrid nanostructures directly in a simple one-step fabrication process so that superior surface superhydrophobicity can also be realized effectively from the electrochemical anodization process. On the basis of the characteristic of forming a self-ordered porous morphology in a hexagonal array, the modulation of anodizing voltage and duration enabled the formulation of the hybrid-type nanostructures having controlled pillar morphology on top of a porous layer in both mild and hard anodization modes. The hybrid nanostructures of the anodized metal oxide layer initially enhanced the surface hydrophilicity significantly (i.e., superhydrophilic). However, after a hydrophobic monolayer coating, such hybrid nanostructures then showed superior superhydrophobic nonwetting properties not attainable by the plain nanoporous surfaces produced by conventional anodization conditions. The well-regulated anodization process suggests that electrochemical anodizing can expand its usefulness and efficacy to render various metallic substrates with great superhydrophilicity or -hydrophobicity by directly realizing pillar-like structures on top of a self-ordered nanoporous array through a simple one-step fabrication procedure.
Preparation of Al/Fe-Pillared Clays: Effect of the Starting Mineral.

Science.gov (United States)

Muñoz, Helir-Joseph; Blanco, Carolina; Gil, Antonio; Vicente, Miguel-Ángel; Galeano, Luis-Alejandro

2017-11-28

Four natural clays were modified with mixed polyoxocations of Al/Fe for evaluating the effect of the physicochemical properties of the starting materials (chemical composition, abundance of expandable clay phases, cationic exchange capacity and textural properties) on final physicochemical and catalytic properties of Al/Fe-PILCs. The aluminosilicate denoted C2 exhibited the highest potential as starting material in the preparation of Al/Fe-PILC catalysts, mainly due to its starting cationic exchange capacity (192 meq/100 g) and the dioctahedral nature of the smectite phase. These characteristics favored the intercalation of the mixed (Al 13- x /Fe x ) 7+ Keggin-type polyoxocations, stabilizing a basal spacing of 17.4 Å and high increase of the BET surface (194 m²/g), mainly represented in microporous content. According to H₂-TPR analyses, catalytic performance of the incorporated Fe in the Catalytic Wet Peroxide Oxidation (CWPO) reaction strongly depends on the level of location in mixed Al/Fe pillars. Altogether, such physicochemical characteristics promoted high performance in CWPO catalytic degradation of methyl orange in aqueous medium at very mild reaction temperatures (25.0 ± 1.0 °C) and pressure (76 kPa), achieving TOC removal of 52% and 70% of azo-dye decolourization in only 75 min of reaction under very low concentration of clay catalyst (0.05 g/L).

A superhydrophobic chip based on SU-8 photoresist pillars suspended on a silicon nitride membrane

KAUST Repository

Marinaro, Giovanni; Accardo, Angelo; De Angelis, Francesco; Dane, Thomas; Weinhausen, Britta; Burghammer, Manfred; Riekel, Christian

2014-01-01

We developed a new generation of superhydrophobic chips optimized for probing ultrasmall sample quantities by X-ray scattering and fluorescence techniques. The chips are based on thin Si3N4 membranes with a tailored pattern of SU-8 photoresist pillars. Indeed, aqueous solution droplets can be evaporated and concentrated at predefined positions using a non-periodic pillar pattern. We demonstrated quantitatively the deposition and aggregation of gold glyconanoparticles from the evaporation of a nanomolar droplet in a small spot by raster X-ray nanofluorescence. Further, raster nanocrystallography of biological objects such as rod-like tobacco mosaic virus nanoparticles reveals crystalline macro-domain formation composed of highly oriented nanorods. © 2014 the Partner Organisations.
A superhydrophobic chip based on SU-8 photoresist pillars suspended on a silicon nitride membrane

KAUST Repository

Marinaro, Giovanni

2014-07-28

We developed a new generation of superhydrophobic chips optimized for probing ultrasmall sample quantities by X-ray scattering and fluorescence techniques. The chips are based on thin Si3N4 membranes with a tailored pattern of SU-8 photoresist pillars. Indeed, aqueous solution droplets can be evaporated and concentrated at predefined positions using a non-periodic pillar pattern. We demonstrated quantitatively the deposition and aggregation of gold glyconanoparticles from the evaporation of a nanomolar droplet in a small spot by raster X-ray nanofluorescence. Further, raster nanocrystallography of biological objects such as rod-like tobacco mosaic virus nanoparticles reveals crystalline macro-domain formation composed of highly oriented nanorods. © 2014 the Partner Organisations.
The role of education in the culture of four pillar poverty to establish the nationalism of young generation

Science.gov (United States)

Sarmini; Warsono

2018-01-01

Globalization as an international integration process brings several positive and negative impacts due to the exchange of world views, products, thoughts, and other cultural aspects that can diminish the values of national identity. Four pillars of nationality are needed as a foundation to counteract the negative effects of globalization, therefore a culturally, educative, legal and structural approach is needed so that the younger generation can truly understand and safeguard the four pillars of our nationality. So far the government has also played little role in building the four pillars into an education. This research intends to see how the role of education can build young generation of nationalism by using research design in the form of content analysis. The population in this study is the Education Office of Sidoarjo Regency, which is the level of Junior High School Education Unit. However, given the scope and breadth of the district of Sidoarjo, a representative sample is determined using FGD (Focus Group Discussion) data collection techniques and questionnaires that will be analyzed using written policy descriptions or unwritten policies. Through a series of research stages, it can be concluded that there are still many principals who have not integrated the culture of the four pillars of nationalism into a written and unwritten document covering intracurricular, extracurricular, school culture and through community participation.
The synthesis and application of pillared clays prepared from charge reduced montmorillonite

Science.gov (United States)

Engwall, Erik Edwin

The synthesis of pillared interlayered clays (PILCs) makes use of the cation exchange capacity (CEC) of clay minerals to prop their structures open with large hydroxy-metal cations. Homo-ionic Ca-Montmorillonite with a CEC of 83.9 meq/100 g has been partially exchanged with varied amounts of Li+ and heated to 200°C for 24 hours. These have been used to produce Zr and Al PILCs making use of ethanol/water synthesis solutions to overcome the hydrophobic nature of the clay. For the Zr-PILC system, the d(001) spacings determined by x-ray diffraction (XRD) were relatively constant at 19.0--20.1 A with respect to changing the unpillared CEC. The Zr-PILCs had type I isotherms for argon at 87 K and for benzene, p-xylene and 1,3,5-trimethylbenzene adsorption at 30°C. Several Al-PILC synthesis procedures were evaluated and all produced materials whose adsorption capacity decreased with decreasing unpillared CEC. This reduction in adsorption capacity with unpillared CEC could be partially overcome by the combined use of ethanol/water pillaring solutions with ethanol/water washing. Previously unreported d(001) values in the range of 26.8 to 29.8 A were observed in Al-PILCs and were often bimodal with the expected values of about 18 A. These larger d(001) values were most prevalent at lower CEC values, if pillaring conditions favored the formation of polymeric species other than the Keggin cation. A new micropore size distribution model was developed to better understand PILC pore structure. The new model was compared to the Horvath and Kawazoe (1983) model (HK) and the Cheng and Yang (1994) model (CY) using argon adsorption at 87 K on Zr and Al-PILCs. The interlayer spacings determined by XRD for the test PILCs were 9.5 and 8.5 A for Zr and Al-PILCs respectively. Pore sizes predicted by the new model were 7.5 and 7.3 A for Zr and Al-PILCs respectively. The new model consistently predicts values that are closer to the interlayer spacing than either the HK or CY models. The new
synthesis, characterization and catalytic activity of the pillared molecular sieve MCM-36

NARCIS (Netherlands)

He, Y.; Nivarthy, G.S.; Eder, F.; Eder, F.; Seshan, Kulathuiyer; Lercher, J.A.

1998-01-01

MCM-36 materials were prepared by swelling the layered MCM-22 precursors with large organic molecules and then pillaring the resulting material with polymeric silica. A mesopore region with 0.25–0.3 nm thickness between the microporous layers was identified. The BET surface area obtained for MCM-36
The use of virtual reality to simulate room and pillar operations

Energy Technology Data Exchange (ETDEWEB)

Crawshaw, S A.M.; Denby, B; McClarnon, D [Long-Airdox International Limited, Ilkeston (United Kingdom)

1997-01-01

Virtual Reality systems allow a user to interact with dynamic three-dimensional computer models of real world situations. The authors show how the complexity of room and pillar mining operations may be mirrored in a user-configurable system. Additionally, an understanding is gained of the mining method, and the operation of equipment in the actual working environment. 1 ref., 5 figs.
Mining the 510 coal seam prone to rock bursts and below a coal support pillar in a seam above

Energy Technology Data Exchange (ETDEWEB)

Major, M; Gebala, W

1983-10-01

The 510 coal seam, situated at a depth of 760 m below a support pillar left in an overlying coal seam, was mined by a system of longwall faces from 1979 to 1982. The seam was prone to rock bursts. Energy of rock bursts which occurred in the mine ranged from 10/SUP/5 to 10/SUP/6 J. The coal seam, 10 m thick, was mined by slicing. Faces were 140 m long. Stress concentrations caused by the suppport pillar left in the overlying coal seam were calculated. Curves which describe stress fluctuations were plotted. Rock burst hazards were determined by drilling. Drilling intervals depended on hazard degree and position of the test site in relation to the support pillar in the overlying coal seam. The face was 3 m high. Supports used in 2 gate roads were reinforced by steel and timber supports. Strong timber boards were placed at canopies of powered supports used at the working face. The face was situated at an angle of 10 degrees to the pillar axis. In the zone of critical stresses water infusion and shock blasting were used for rock burst prevention. These methods, plus reinforcement of the supports in gate roads and at the working face, guaranteed safe mining and prevented rock bursts. (8 refs.)
"Learning to Do" as a Pillar of Education and Its Links to Entrepreneurial Studies in Higher Education: European Contexts and Approaches

Science.gov (United States)

Miclea, Mircea

2004-01-01

The author links the "learning to do" pillar, one of the four pillars of the Delors Report of 1996 , "Learning: The Treasure Within", to the principles and purposes of an entrepreneurial university and the aims of the European Commission and the Bologna Process to enhance the employability of graduates of higher education. An entrepreneurial…
Building method (concreting) for an offshore platform equipped with several cantilevered pillars. Fremgangsmaate for fremstilling (stoeping) av en fralandsplattform som har flere mot hverandre hellende stoetteben

Energy Technology Data Exchange (ETDEWEB)

Olsen, O.

1985-07-29

The invention deals with a building method for an offshore platform made of concrete comprising several cantilevered pillars. In accordance with the invention, the building work is to be started in a dry dock, and can be completed in the same place or in deep water. The pillars and the foundation are made as separate structures. The foundation can also be made as separate structures for each of the pillars. The vertical positioned pillars are made by means of moving forms, and finally put into cantilevered position and permanently connected to the foundation and the upper end arrangement. The structure then is to be completed in the normal way. 7 drawings.
The Simulation of the stabilizing process of glass nanoparticle in optical tweezer using series of laser pulses

International Nuclear Information System (INIS)

Ho Quang Quy; Hoang Dinh Hai

2012-01-01

In this article the stable region and stabilizing process of dielectric particle in fluid by the optical tweezer using the series of laser pulses are investigated. The influence of the repetition period and number of laser pulses on the radial variance of particle and the so-called stable space-time pillar is simulated and discussed. (author)
Controlling the photochemical reaction of an azastilbene derivative in water using a water-soluble pillar[6]arene.

Science.gov (United States)

Xia, Danyu; Wang, Pi; Shi, Bingbing

2017-09-20

Photochemistry plays an important role in our lives. It has also been a common tool in the laboratory to construct complicated systems from small molecules. Supramolecular chemistry provides an opportunity to solve some of the problems in controlling photochemical reactions via non-covalent interactions. By using confining media and weak interactions between the medium and the reactant molecule, the excited state behavior of molecules has been successfully manipulated. Pillararenes, a new class of macrocyclic hosts, have rarely been used in the field of photochemical investigations, such as the controlling of photo-induced reactions. Herein, we explore a synthetic macrocyclic host, a water-soluble pillar[6]arene, as a controlling tool to manipulate the photo-induced reactions (hydration) in water. A host-guest system in water based on a water-soluble pillar[6]arene and an azastilbene derivative, (E)-4,4'-dimethyl-4,4'-diazoniastilbene diiodide, has been constructed. Then this water-soluble pillar[6]arene was successfully employed to control the photohydration of the azastilbene derivative in water as a "protective agent".
Formation of zeolite-like zinc 1,3,5-benzenetriphosphonate open-frameworks by topotactic pillaring of anionic layers.

Science.gov (United States)

Maeda, Kazuyuki; Takamatsu, Ryohei; Mochizuki, Miki; Kawawa, Kanako; Kondo, Atsushi

2013-08-07

An ab initio powder X-ray crystal structure analysis revealed that layered zinc 1,3,5-benzenetriphosphonates containing interlayer tetramethylammonium (ZBP-TMA) or 4,4'-bipyridinium cations (ZBP-bpy) are transformed to novel isomorphous 3D open-framework compounds ZBP-M (M: K, Rb, and Cs) by treatment in aqueous alkali metal chloride solutions. ZBP-Ms have a pillared layer-type of anionic framework containing 2D zigzag channels connected with cage-like spaces. The potassium atoms in ZBP-K are located near 8MR windows in the 2D zigzag channels, and the potassium cations are successfully exchanged with ammonium cations retaining the open-framework structure. The ammonium form (ZBP-NH4) showed remarkable cation exchange selectivity for Rb(+) and Cs(+) in a mixture of alkali metal cations. It is assumed that zinc ions partially dissolved from the starting layered ZBP precursors are intercalated in ZBP layers to form pillared layered 3D open-frameworks. These results clearly show that topotactic pillared layer approaches are applicable not only to zeolite-related materials but also to novel open-framework metal organophosphonates.
Policy framework for utilisation. A pillar of better accessibility

International Nuclear Information System (INIS)

2008-01-01

The goals and frameworks for traffic and transport policy for the Netherlands to 2020 are described in the Mobility Document. Whereas government policy previously viewed mobility as a problem or as something permissible, the assumption is now that mobility is a must. Mobility, for people as well as goods, is a prerequisite for society and the economy to function well. The Mobility Document contains ambitious goals to deal with current and anticipated traffic and transport problems: door to door, faster, cleaner and safer. Three interrelated pillars are to help achieve these goals: Building, Pricing and Utilisation. Work is being done on the Building and Pricing pillars; Utilisation is elaborated further in this policy framework. The Policy Framework for Utilisation is an elaboration of the Mobility Document for the 2008-2020 period and aims for faster, cleaner, safer travel from door to door. The purpose of this policy framework is to describe the direction of development of utilisation, in terms of content as well as process, to indicate actions that are required and to provide perspective on the expected effects. The policy framework is in line with current developments or plans, caters to new opportunities (technological and otherwise), encourages the innovative potential of the market and provides room for joint ventures between the government and the market. It will result in actions for the short term and provide direction for activities and developments for the longer term
Development of a time-dependent energy model to calculate the mining-induced stress over gates and pillars

Directory of Open Access Journals (Sweden)

Mohammad Rezaei

2015-06-01

Full Text Available Generally, longwall mining-induced stress results from the stress relaxation due to destressed zone that occurs above the mined panel. Knowledge of induced stress is very important for accurate design of adjacent gateroads and intervening pillars which helps to raise the safety and productivity of longwall mining operations. This study presents a novel time-dependent analytical model for determination of the longwall mining-induced stress and investigates the coefficient of stress concentration over adjacent gates and pillars. The model is developed based on the strain energy balance in longwall mining incorporated to a rheological constitutive model of caved materials with time-varying parameters. The study site is the Tabas coal mine of Iran. In the proposed model, height of destressed zone above the mined panel, total longwall mining-induced stress, abutment angle, induced vertical stress, and coefficient of stress concentration over neighboring gates and intervening pillars are calculated. To evaluate the effect of proposed model parameters on the coefficient of stress concentration due to longwall mining, sensitivity analysis is performed based on the field data and experimental constants. Also, the results of the proposed model are compared with those of existing models. The comparative results confirm a good agreement between the proposed model and the in situ measurements. According to the obtained results, it is concluded that the proposed model can be successfully used to calculate the longwall mining-induced stress. Therefore, the optimum design of gate supports and pillar dimensions would be attainable which helps to increase the mining efficiency.
Evaluation of modelling of the TRUE-1 radially converging and dipole tests with conservative tracers. The Aespoe task force on modelling of groundwater flow and transport of solutes. Tasks 4C and 4D

International Nuclear Information System (INIS)

Elert, M.

1999-05-01

The 'Aespoe task force on modelling of groundwater flow and transport of solutes' is a forum for the international organisations supporting the Aespoe HRL Project. The purpose of the Task Force is to interact in the area of conceptual and numerical modelling of groundwater flow and solute transport in fractured rock. Task 4 of the Aespoe Modelling Task Force consists of modelling exercises in support of the TRUE-1 tracer tests. In this report, the modelling work performed within Tasks 4C and 4D is evaluated, which comprised predictive modelling of the radially converging tracer tests and dipole tracer tests performed within the TRUE-1 tests using non-sorbing tracers. The tests were performed between packed off boreholes penetrating a water-conducting geological feature with a simple structure (Feature A). These tests are to a great extent preparatory steps for the subsequent tests with sorbing radioactive tracers. In Tasks 4E and 4F of the Aespoe Modelling Task Force predictive modelling of the sorbing tracer tests is performed. Eight modelling teams representing seven organisations have performed predictive modelling using different modelling approaches and models. The modelling groups were initially given data from the site characterisation and data on the experimental set-up of the tracer tests. Based on this information model predictions were performed of drawdown, tracer mass recovery and tracer breakthrough. The performed predictions shows that the concept of Feature A as a singular well-connected feature with limited connectivity to its surroundings is quite adequate for predictions of drawdown in boreholes and conservative tracer breakthrough. Reasonable estimates were obtained using relatively simple models. However, more elaborate models with calibration or conditioning of transmissivities and transport apertures are required for more accurate predictions. The general flow and transport processes are well understood, but the methodology to derive the
Evaluation of modelling of the TRUE-1 radially converging and dipole tests with conservative tracers. The Aespoe task force on modelling of groundwater flow and transport of solutes. Tasks 4C and 4D

Energy Technology Data Exchange (ETDEWEB)

Elert, M. [Kemakta Konsult AB, Stockholm (Sweden)

1999-05-01

The `Aespoe task force on modelling of groundwater flow and transport of solutes` is a forum for the international organisations supporting the Aespoe HRL Project. The purpose of the Task Force is to interact in the area of conceptual and numerical modelling of groundwater flow and solute transport in fractured rock. Task 4 of the Aespoe Modelling Task Force consists of modelling exercises in support of the TRUE-1 tracer tests. In this report, the modelling work performed within Tasks 4C and 4D is evaluated, which comprised predictive modelling of the radially converging tracer tests and dipole tracer tests performed within the TRUE-1 tests using non-sorbing tracers. The tests were performed between packed off boreholes penetrating a water-conducting geological feature with a simple structure (Feature A). These tests are to a great extent preparatory steps for the subsequent tests with sorbing radioactive tracers. In Tasks 4E and 4F of the Aespoe Modelling Task Force predictive modelling of the sorbing tracer tests is performed. Eight modelling teams representing seven organisations have performed predictive modelling using different modelling approaches and models. The modelling groups were initially given data from the site characterisation and data on the experimental set-up of the tracer tests. Based on this information model predictions were performed of drawdown, tracer mass recovery and tracer breakthrough. The performed predictions shows that the concept of Feature A as a singular well-connected feature with limited connectivity to its surroundings is quite adequate for predictions of drawdown in boreholes and conservative tracer breakthrough. Reasonable estimates were obtained using relatively simple models. However, more elaborate models with calibration or conditioning of transmissivities and transport apertures are required for more accurate predictions. The general flow and transport processes are well understood, but the methodology to derive the
Enhanced photocatalytic activity of microwave treated TiO2 pillared montmorillonite

International Nuclear Information System (INIS)

Sun Shenmei; Jiang Yinshan; Yu Lixin; Li Fangfei; Yang Zhengwen; Hou Tianyi; Hu Daqiang; Xia Maosheng

2006-01-01

TiO 2 pillared montmorillonite synthesized by microwave irradiation, exhibited good photocatalytic degradation performance of methyl orange, whose pseudo first order reaction rate constant was nearly four times than that of conventional method, because of its enhanced crystalline, preferred anatase phase and improved porosity performance, which were analysed by X-ray diffraction (XRD), far Fourier transform infrared ray spectroscopy (FTIR) and nitrogen adsorption isotherms
Tunable waveguide and cavity in a phononic crystal plate by controlling whispering-gallery modes in hollow pillars

DEFF Research Database (Denmark)

Jin, Yabin; Fernez, Nicolas; Pennec, Yan

2016-01-01

We investigate the properties of a phononic crystal plate with hollow pillars and introduce the existence of whispering-gallery modes (WGMs). We show that by tuning the inner radius of the hollow pillar, these modes can merge inside both Bragg and low frequency band gaps, deserving phononic crystal...... and acoustic metamaterial applications. These modes can be used as narrow pass bands for which the quality factor can be greatly enhanced by the introduction of an additional cylinder between the hollow cylinder and the plate. We discuss some functionalities of these confined WGM in both Bragg and low...
THE EFFECT OF INNER DIAPHRAGMS AND NON-CONTINUOUS SILL SECTION ON THE STIFFNESS OF AUTOMOTIVE B-PILLAR

Directory of Open Access Journals (Sweden)

C.F. Tan

2017-11-01

Full Text Available The paper discusses the knowledge on the behaviour of T-frame under specific loading will be obtained by experimental methods in order to investigate the deflection of the vehicle B-pillar or T-frame. In addition, a series of T-frame were designed with inner diaphragm at various location in the sill member in order to investigate the effect of inner diaphragm and noncontinuous closed hat section in the sill member. Lastly, the results from the experimental tests were compared with the finite element analysis results to demonstrate the effectiveness of the inner diaphragm in the automotive B-pillar.
3D laser scanning techniques applying to tunnel documentation and geological mapping at Aespoe hard rock laboratory, Sweden

International Nuclear Information System (INIS)

Feng, Q.; Wang, G.; Roeshoff, K.

2008-01-01

3D terrestrial laser scanning is nowadays one of the most attractive methods to applying for 3D mapping and documentation of rock faces and tunnels, and shows the most potential to improve the data quality and provide some good solutions in rock engineering projects. In this paper, the state-of-the-art methods are described for different possibility to tunnel documentation and geological mapping based on 3D laser scanning data. Some results are presented from the case study performed at the Hard Rock Laboratory, Aespoe run by SKB, Swedish Nuclear Fuel and Waste Management Co. Comparing to traditional methods, 3D laser scanning techniques can not only provide us with a rapid and 3D digital way for tunnel documentation, but also create a potential chance to achieve high quality data, which might be beneficial to different rock engineering project procedures, including field data acquisition, data processing, data retrieving and management, and also modeling and design. (authors)

Morphology dependent field emission characteristics of ZnS/silicon nanoporous pillar array

Science.gov (United States)

Wang, Ling Li; Zhao, Cheng Zhou; Kang, Li Ping; Liu, De Wei; Zhao, Hui Chun; Hao, Shan Peng; Zhang, Yuan Kai; Chen, Zhen Ping; Li, Xin Jian

2016-10-01

Through depositing zinc sulphide (ZnS) nanoparticals on silicon nanoporous pillar array (Si-NPA) and crater-shaped silicon nanoporous pillar array (c-Si-NPA) by chemical bath deposition (CBD) method, ZnS/Si-NPA and c-ZnS/Si-NPA were prepared and the field emission (FE) properties of them were investigated. The turn-on electric fields of were 3.8 V/mm for ZnS/Si-NPA and 5.0 V/mm for c-ZnS/Si-NPA, respectively. The lower turn-on electric fields of ZnS/Si-NPA than that of c-ZnS/Si-NPA were attributed to the different electric distribution of the field emitters causing by the different surface morphology of the two samples, which was further demonstrated via the simulated results by finite element modeling. The FN curves for the ZnS/Si-NPA showed two-slope behavior. All the results indicate that the morphology play an important role in the FE properties and designing an appropriate top morphology for the emitter is a very efficient way to improve the FE performance.
Model of care for a changing healthcare system: are there foundational pillars for design?

Science.gov (United States)

Booker, Catriona; Turbutt, Adam; Fox, Robyn

2016-04-01

Currently, healthcare organisations are being challenged to provide optimal clinical services within budget limitations while simultaneously being confronted by aging consumers and labour and skill shortages. Within this dynamic and changing environment, the ability to remain responsive to patient needs while managing these issues poses further challenges. Development or review of the model of care (MOC) may provide a possible solution to support efficiencies in service provision. Although MOC are not readily understood or appreciated as an efficiency strategy, they can be more easily explained by considering several recurring pillars when developing or redesigning an MOC. Generic and recurring foundational pillars include integrated care models, team functioning and communication, leadership, change management and lean thinking. These foundational pillars should be incorporated into the development and application of MOC in order to achieve desired outcomes. However, sustainability requires continuous review to enable improvement and must be integrated into routine business. Moreover, successful review of MOC requires collaboration and commitment by all stakeholders. Leaders are critical to motivating clinicians and stakeholders in the review process. Further, it is imperative that leaders engage stakeholders to commit to support the agreed strategies designed to provide efficient and comprehensive healthcare services. Redesign of MOC can significantly improve patient care by applying the agreed strategies. In the current healthcare environment, these strategies can favourably affect healthcare expenditure and, at the same time, improve the quality of interprofessional health services.
Direct fault dating trials at the Aespoe Hard Rock Laboratory

International Nuclear Information System (INIS)

Maddock, R.H.; Hailwood, E.A.

1993-10-01

Over seventy rock samples were collected from fault and fracture zones in the Aespoe Hard Rock Laboratory tunnel for a study of direct fault dating techniques. Following microstructural and mineralogical analysis, isotopic, palaeomagnetic and electron spin resonance (ESR) methods were employed in an attempt to determine the age of the most recent movements on the sampled faults. The larger fracture zones contain faultrock assemblages and microstructures which are consistent with a prolonged and polyphase movement history, although the cumulative displacements involved formation of fault gouge cemented by authigenic 'illite'. Dating studies were targeted particularly at the gouge but also at older fault rock and vein phases. ESR dating of quartz graines, separated from gouge from fracture zones NE-4 and NE-3, strongly indicates that the ESR signals have not been reset by fault movements for a minimum time period of several hundred thousand to one million years. Palaeomagnetic dating of gouge from fracture zone NE-4 shows that a stable component of magnetisation overlaps both Precambrian and Permo-Triassic parts of the apparent polar wander curve. The younger age of magnetisation is preferred on geological grounds and by comparison with the isotopic dating results. The magnetisation may correspond to a diagenetic event following fault movement. Palaeomagnetic ages determined on countryrock and epidote vein samples are largely consistent with independent age constraints. K-Ar dating of clay fractions (<2 to <0.05μm) separated from gouge from four faults, including fracture zones NE-4 and NE-3, gave model ages in the range 706-301Ma. Accounting for the effects of contamination by potassium-bearing porphyroclasts, it is likely that authigenic 'illite' was formed at least 250 million years ago, after the most recent significant fault movements. 100 refs., 60 figs., 26 tabs
An experimental investigation of wind pressures on square pillars in tornado-like vortices

International Nuclear Information System (INIS)

Iwatani, Yoshiharu; Maruta, Eizou; Kanda, Makoto; Hattori, Yousuke; Hamano, Naoki; Matsuura, Takeshi

1992-01-01

This report describes a laboratory simulation of tornado-like vortices and laboratory measurements of steady wind loads on model structures in tornado-like vortices. The variations of wind direction and wind speed of tornado-like vortices and ground surface pressure under tornado-like vortices with the swirl ratio, Reynolds number and the surface roughness were investigated. Wind pressure distributions on square pillars were measured in tornado-like vortices. It was observed in the experiment that the negative pressures on the roof faces of square pillars were high and distributed rather uniformly but these on the side faces differed greatly from place to place and locally became high. The high pressure regions on the side faces were close to ground surface in the case where the model structures stood in the center of tornado-like vortex, and became higher as the increase of distance between the model structures and the center of tornado-like vortices. (author)
Geochemical Investigations of Groundwater Stability

International Nuclear Information System (INIS)

Bath, Adrian

2006-05-01

groundwaters, and also by stable isotopes and uranium isotopes in secondary minerals. Information on timing of water and solute movements is important because it indicates any correlation with the timing of external events that might have perturbed and destabilised the groundwater system in the past, and allows a timescale to be estimated for the persistence of stable conditions. Data from a number of published site investigation projects and research programmes are reviewed to illustrate the patterns of geochemical data and the relationships between them, and how these are interpreted in terms of hydrodynamic stability. Data from Aespoe and Stripa and from exploratory boreholes at Finnsjoen and other sites in Sweden are compiled and discussed. Preliminary data from SKB's ongoing site investigations at Simpevarp/Laxemar and Forsmark are not considered in detail but their general similarities with Aespoe and Finnsjoen/SFR respectively are introduced into the discussion of geochemical evidence for groundwater stability in inland and coastal areas. Relevant data from Finnish sites including Olkiluoto, from the Whiteshell URL area in Canada, from Sellafield in the UK, and from the Tono area and URL in Japan are also summarised in appendices and discussed because they add further insights into the interpretation of geochemical indicators for a range of geological environments. The compiled data provide only limited scope for comparison of groundwater evolution and stability between inland and coastal areas in Sweden, because of the patchiness of representative data especially from early site studies. The external changes that might have perturbed stable groundwater conditions in the past are glaciation (i.e. melt water, mechanical loading/unloading and permafrost) and varying sea water infiltration at coastal sites due to changes in palaeo-Baltic and isostatic conditions. The present distributions of palaeo-Baltic sea water in groundwaters at coastal sites vary, reflecting local
Canister positioning. Influence of fracture system on deposition hole stability

International Nuclear Information System (INIS)

Hoekmark, Harald

2003-11-01

The study concerns the mechanical behaviour of rock surrounding tunnels and deposition holes in a nuclear waste repository. The mechanical effects of tunnel excavation and deposition hole excavation are investigated by use of a tunnel scale numerical model representing a part of a KBS-3 type repository. The excavation geometry, the initial pre-mining state of stress, and the geometrical features of the fracture system are defined according to conditions that prevail in the TBM tunnel rock mass in Aespoe HRL. Comparisons are made between results obtained without consideration of fractures and results obtained with inclusion of the fracture system. The focus is on the region around the intersection of a tunnel and a deposition hole. A general conclusion is that a fracture system of the type found in the TBM rock mass does not have a decisive influence on the stability of the deposition holes. To estimate the expected extent of spalling, information about other conditions, e.g. the orientation of the initial stresses and the strength properties of the intact rock, is more important than detailed information about the fracture system
The pillar of metropolitan greatness: The long making of archeological objects in Paris (1711-2001).

Science.gov (United States)

Van Damme, Stéphane

2017-09-01

Over three centuries after the 1711 discovery in the choir of Notre-Dame in Paris of a square-section stone bas-relief (the Pillar of the Boatmen) with depictions of several deities, both Gaulish and Roman, the blocks comprising it were analyzed as a symbol of Parisian power, if not autonomy, vis-à-vis the Roman Empire. Variously considered as local, national, or imperial representations, the blocks were a constant object of admiration, interrogation, and speculation among antiquarians of the Republic of Letters. They were also boundary objects - products of the emergence of a Parisian archeology dated from 1711. If this science reflected the tensions and ambiguities of a local regime of knowledge situated in a national context, it also helped to coordinate archeological work between different institutions and actors. This paper would like to assess the specific role played by the Pillar of the Boatmen as a fetish object in this process. To what extent could an archeological artifact influence this reshaping of urban representation, this change of scales? By following the three-century career of the pillar's blocks as composite objects, which some have identified as merely stones or a column, it is possible to understand the multiple dimensions that defined the object as archeological - as an artifact that contributed to the relocating of the historical city center - and the multiple approaches that transform existing remains into knowledgeable objects.
Fe/Ti co-pillared clay for enhanced arsenite removal and photo oxidation under UV irradiation

Energy Technology Data Exchange (ETDEWEB)

Li, Yuan [School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China); Guang Dong Electric Power Design Institute, China Energy Engineering Group Co. Ltd., Guangzhou 510663 (China); Cai, Xiaojiao [School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China); Guo, Jingwei [School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China); The 718th Research Institute of CSIC, Handan 056027 (China); Zhou, Shimin [School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China); Na, Ping, E-mail: naping@tju.edu.cn [School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China)

2015-01-01

Graphical abstract: - Highlights: • An iron and titanium co-pillared montmorillonite (Fe-Ti/MMT) was synthesized for arsenite removal. • Variety of characterization results indicated that Fe and Ti species were pillared in MMT. • A possible mechanism of arsenite adsorption/oxidation with UV light was established. • The participation of Fe component can promote the process of photocatalytic oxidation in Fe-Ti/MMT + As(III) system. • Fe-Ti/MMT can function as both photocatalyst and adsorbent for arsenite removal. - Abstract: A series of iron and titanium co-pillared montmorillonites (Fe-Ti/MMT) were prepared using hydrolysis of inserted titanium and different iron content in montmorillonite (MMT). The Fe-Ti/MMT were characterized by X-ray fluorescence, N{sub 2} adsorption and desorption, X-ray diffraction, scanning electron microscopy (SEM) and transmission electron microscopy (TEM), confirming the effective insertion of Fe species and TiO{sub 2} in the MMT. The Fe-Ti/MMT was used to remove arsenite (As(III)) from aqueous solutions under different conditions. The result of As(III) adsorption under UV irradiation showed that the photo activity can be enhanced by incorporating Fe and Ti in MMT. Fourier-transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis indicated that the hydroxyl groups bonded to metal oxide (M–OH) played an important role in the adsorption of As(III)
Evaluation of modelling of the TRUE-1 radially converging tests with sorbing tracers. The Aespoe task force on modelling of groundwater flow and transport of solutes. Tasks 4E and 4F

Energy Technology Data Exchange (ETDEWEB)

Elert, M.; Svensson, Haakan [Kemakta Konsult AB, Stockholm (Sweden)

2001-05-01

The Aespoe Task Force on Modelling of Groundwater Flow and Transport of Solutes is a forum for the international organisations supporting the Aespoe HRL Project. The purpose of the Task Force is to interact in the area of conceptual and numerical modelling of groundwater flow and solute transport in fractured rock. Task 4 of the Aespoe Modelling Task Force consists of modelling exercises in support of the TRUE-1 tracer tests. In this report, the modelling work performed within Tasks 4E and 4F is evaluated, which comprised predictive modelling of the tracer tests (STT-1, STT-1b and STT-2) performed within the TRUE-1 project using sorbing and non-sorbing tracers. The tests were made between packed off boreholes penetrating a water-conducting geological feature with a simple structure (Feature A). Nine modelling teams representing eight organisations have performed predictive modelling of the tracer tests using different modelling approaches and models. The modelling groups were initially given data from the site characterisation, data from preliminary tracer tests performed with non-sorbing tracers and data on the experimental set-up of the sorbing tracer tests. Based on this information, model predictions were made of drawdown, tracer mass recovery and tracer breakthrough. For the predictions of the STT-1b and STT-2 tests results from previous tracer tests with sorbing tracer were also available. The predictions of the sorbing tracer breakthrough in the initial tracer test (STT-1) generally underestimated the breakthrough time, suggesting the need to include additional processes and evaluate the application of the laboratory data. As a result of model calibration and modification the predictions were considerably improved for the latter tracer tests (STT-1b and STT-2). Task 4E and 4F have proved to be very valuable in increasing the understanding of non-sorbing tracer transport in fractured rock. There is a general consensus on the major processes responsible for
Influence of a Large Pillar on the Optimum Roadway Position in an Extremely Close Coal Seam

Directory of Open Access Journals (Sweden)

Li Yang

2016-01-01

Full Text Available Based on the mining practice in an extremely close coal seam, theoretical analysis was conducted on the vertical stress distribution of the floor strata under a large coal pillar. The vertical stress distribution regulation of a No. 5 coal seam was revealed. To obtain the optimum position of the roadway that bears the supporting pressure of a large coal pillar, numerical modeling was applied to analyze the relation among the stress distribution of the roadway surrounding the rock that bears the supporting pressure of a large coal pillar, the plastic zone distribution of the roadway surrounding the rock, the surrounding rock deformation, and the roadway layout position. The theoretical calculation results of the stress value, stress variation rate, and influencing range of the stress influencing angle showed that the reasonable malposition of the No. 5 coal seam roadway was an inner malposition of 4 m. The mining practice showed the following: the layout of No. 25301 panel belt roadway at the position of the inner malposition of 4 m was reasonable, the roadway support performance was favourable without deformation, and ground pressure was not obvious. The research achievement of this study is the provision of a reference for roadway layouts under similar conditions.
Criticality studies: One of the two pillars of criticality safety at the Belgonucleaire MOX plant

International Nuclear Information System (INIS)

Lance, B.; Maldague, T.; Evrard, G.; Renard, A.; Kockerols, P.

2001-01-01

The present paper focuses on the criticality studies performed by the Engineering Division of Belgonucleaire. These are one of the two pillars of the criticality prevention implemented for the Belgonucleaire MOX producing plant. (author)
A randomised controlled trial on the Four Pillars Approach in managing pregnant women with anaemia in Yogyakarta-Indonesia: a study protocol.

Science.gov (United States)

Widyawati, Widyawati; Jans, Suze; Bor, Hans; Siswishanto, Rukmono; van Dillen, Jeroen; Lagro-Janssen, Antoine L M

2014-05-07

Anaemia is a common health problem among pregnant women and a contributing factor with a major influence on maternal mortality in Indonesia. The Four Pillars Approach is a new approach to anaemia in pregnancy, combining four strategies to improve antenatal and delivery care. The primary objective of this study is to measure the effectiveness of the Four Pillars Approach. The barriers, the facilitators, and the patients' as well as the midwives' satisfaction with the Four Pillars Approach will also be measured. This study will use a cluster randomised controlled trial. This intervention study will be conducted in the Public Health Centres with basic emergency obstetric care in Yogyakarta Special Province and in Central Java Province. We will involve all the Public Health Centres (24) with emergency obstetric care in Yogyakarta Special Province. Another 24 Public Health Centres with emergency obstetric care in Central Java Province which have similarities in their demographic, population characteristics, and facilities will also be involved. Each Public Health Centre will be asked to choose two or three nurse-midwives to participate in this study. For the intervention group, the Public Health Centres in Yogyakarta Special Province, training on the Four Pillars Approach will be held prior to the model's implementation. Consecutively, we will recruit 360 pregnant women with anaemia to take part in part in the study to measure the effectiveness of the intervention. The outcome measurements are the differences in haemoglobin levels between the intervention and control groups in the third trimester of pregnancy, the frequency of antenatal care attendance, and the presence of a nurse-midwife during labour. Qualitative data will be used to investigate the barriers and facilitating factors, as to nurse-midwives' satisfaction with the implementation of the Four Pillars Approach. If the Four Pillars Approach is effective in improving the outcome for pregnant women with anaemia
Simple scaling laws for the evaporation of droplets pinned on pillars: Transfer-rate- and diffusion-limited regimes.

Science.gov (United States)

Hernandez-Perez, Ruth; García-Cordero, José L; Escobar, Juan V

2017-12-01

The evaporation of droplets can give rise to a wide range of interesting phenomena in which the dynamics of the evaporation are crucial. In this work, we find simple scaling laws for the evaporation dynamics of axisymmetric droplets pinned on millimeter-sized pillars. Different laws are found depending on whether evaporation is limited by the diffusion of vapor molecules or by the transfer rate across the liquid-vapor interface. For the diffusion-limited regime, we find that a mass-loss rate equal to 3/7 of that of a free-standing evaporating droplet brings a good balance between simplicity and physical correctness. We also find a scaling law for the evaporation of multicomponent solutions. The scaling laws found are validated against experiments of the evaporation of droplets of (1) water, (2) blood plasma, and (3) a mixture of water and polyethylene glycol, pinned on acrylic pillars of different diameters. These results shed light on the macroscopic dynamics of evaporation on pillars as a first step towards the understanding of other complex phenomena that may be taking place during the evaporation process, such as particle transport and chemical reactions.
Simple scaling laws for the evaporation of droplets pinned on pillars: Transfer-rate- and diffusion-limited regimes

Science.gov (United States)

Hernandez-Perez, Ruth; García-Cordero, José L.; Escobar, Juan V.

2017-12-01

The evaporation of droplets can give rise to a wide range of interesting phenomena in which the dynamics of the evaporation are crucial. In this work, we find simple scaling laws for the evaporation dynamics of axisymmetric droplets pinned on millimeter-sized pillars. Different laws are found depending on whether evaporation is limited by the diffusion of vapor molecules or by the transfer rate across the liquid-vapor interface. For the diffusion-limited regime, we find that a mass-loss rate equal to 3/7 of that of a free-standing evaporating droplet brings a good balance between simplicity and physical correctness. We also find a scaling law for the evaporation of multicomponent solutions. The scaling laws found are validated against experiments of the evaporation of droplets of (1) water, (2) blood plasma, and (3) a mixture of water and polyethylene glycol, pinned on acrylic pillars of different diameters. These results shed light on the macroscopic dynamics of evaporation on pillars as a first step towards the understanding of other complex phenomena that may be taking place during the evaporation process, such as particle transport and chemical reactions.
Inclined-wall regular micro-pillar-arrayed surfaces covered entirely with an alumina nanowire forest and their improved superhydrophobicity

International Nuclear Information System (INIS)

Kim, Dae-Ho; Lee, Dongyun; Cho, Chae-Ryong; Kim, Soo-Hyung; Lee, Deug-Woo; Kim, Jong-Man; Kim, Yongsung; Kang, Jae-Wook; Hong, Suck Won

2011-01-01

This paper reports a multiple-scale hierarchically structured superhydrophobic surface that is composed of inclined-wall regular micro-pillar arrays covered entirely with an alumina nanowire forest (ANF) to improve the surface wettability. The multiple-scaled structures were fabricated stably using a simple batch process based on an anisotropic chemical silicon etching process and a subsequent time-controlled anodic aluminum oxide technique. The surface wetting properties of the mono-roughened surfaces with inclined-wall micro-pillar arrays, which are normally in the Wenzel wetting regime, could be transitioned perfectly to the slippery Cassie mode and enhanced greatly in the Wenzel regime in cases of a high- and low-density of the micro-pillars, respectively, by easily amplifying the intrinsic contact angle through the entire coverage of the ANF on the micro-roughened surfaces. The wettability of the proposed multiple-scaled surfaces could also be predicted using analytic surface models and the experimental results agreed greatly with the wetting trends estimated theoretically due to the geometrical regularity of the base micro-structures
Review of subsidence and stabilization techniques

International Nuclear Information System (INIS)

Fernando, D.A.

1988-01-01

In Britain the damage caused by underground coal mining operations approximates to about 100 million pounds Sterling per annum, most of the damage resulting from longwall mining operations. Causes of subsidence can be attributed to the following factors: (1) roof failure (2) pillar failure (3) floor movements. Currently, in Britain, the mining industry is undergoing a state of decline for economic reasons. Consequently, the number of old coal sites available for development schemes has increased. Therefore, the problems associated with subsidence can be segregated into two parts. The first being the mitigation of the effects of subsidence on structures on actively mined areas. The second being the stabilization and rehabilitation of ground over and around old mine sites for new development schemes. In the former case the stabilization techniques employed may be local or global, depending on the problems encountered in any particular area. In the latter case, generally, grouting techniques are employed. This paper aims to review the causes of subsidence and the techniques used to minimize its effect on structures. Also, more economic alternative methods of ground stabilization techniques are described and proposed, to be used in this area of ground engineering
Promoting Family Literacy through the Five Pillars of Family and Community Engagement (FACE)

Science.gov (United States)

Kuo, Nai-Cheng

2016-01-01

Family literacy involves factors beyond what is done at home between parents and children. To help preservice teachers develop their understanding of the multiple dimensions of family literacy, this study uses the five pillars of family and community engagement (FACE)--early literacy, family involvement, access to books, expanded learning, and…
Thermally switchable adhesions of polystyrene-block-poly(n-isopropylacrylamide) copolymer pillar array mimicking climb attitude of geckos

Science.gov (United States)

Chen, Jem-Kun; Wang, Jing-Hong; Chang, Jia-Yaw; Fan, Shih-Kang

2012-09-01

Inspired by the gecko foot pad, we fabricated polystyrene-block-poly(N-isopropylacrylamide) (PS-b-PNIPAAm) copolymer pillar array to mimic climbing attitude of a gecko, alternately attach to and detach from a surface. The pillar array structure of the PS segment significantly enhances both of the hydrophilic and hydrophobic property of PNIPAAm segment tips at 25 and 50 °C, respectively, which could generate alternating adhesive forces of approximately 120 and 11 nN. The dramatic change in adhesive and friction force difference at 25 and 50 °C may guide the design of bio-inspired artificial analogues, which could approach gecko's climbing behavior.
The Decade of Education for Sustainable Development: Towards four pillars of learning

OpenAIRE

Shivali Lawale; Aline Bory-Adams

2010-01-01

Education for sustainable development is a paradigm shift in education which goes beyond the traditional realms of education. Shivali Lawale and Aline Bory-Adams assess how education for sustainable development could build sustainable societies through the Decade of Education for sustainable development. They explore how to build a conceptual framework based on the four pillars of learning proposed by the Delors Report.
Cerium Modified Pillared Montmorillonite Supported Cobalt Catalysts for Fischer Tropsch Synthesis

International Nuclear Information System (INIS)

Ahmad, N.; Ali, Z.; Abbas, S. M.; Hussain, F.

2015-01-01

Fischer-Tropsch (FT) synthesis was accomplished over Al-pillared Montmorillonite supported 20 wt% Co modified with different weight% of cerium catalysts. These catalysts were prepared by impregnation method while structural characterizations of the prepared samples were performed by XRD, TPR, NH/sub 3/TPD, TGA, BET, XRF and SEM techniques. The Fischer Tropsch reaction was studied in fixed bed micro catalytic reactor at temperature range of 220, 260 and 275 degree C and at different pressure (1, 5 and 10 bars). From the activity results, it was found that by pillaring NaMMT with Al higher catalytic activity and lower methane selectivity of NaMMT was achieved. Furthermore, the results of FT synthesis reaction revealed that cerium incorporation increased the dispersion of Co/sub 3/O/sub 4/ on the surface and consequently resulted in enhanced catalytic activity. Additionally, the C/sub 5/-C/sub 12/ hydrocarbons and methane selectivity increased while C/sub 22+/ hydrocarbons selectivity was decreased over cerium modified catalysts. Higher reaction temperature (>220 degree C) resulted in significant enhancement in CO conversion and methane selectivity. Though, increase in pressure from 1 to 10 bars eventually resulted in increase in C/sub 5+/ hydrocarbons and decrease in methane and C/sub 2/-C/sub 5/ hydrocarbons selectivity. (author)

Stability of reinforced cemented backfills

International Nuclear Information System (INIS)

Mitchell, R.J.; Stone, D.M.

1987-01-01

Mining with backfill has been the subject of several international meetings in recent years and a considerable research effort is being applied to improve both mining economics and ore recovery by using backfill for ground support. Classified mill tailings sands are the most commonly used backfill material but these fine sands must be stabilized before full ore pillar recovery can be achieved. Normal portland cement is generally used for stabilization but the high cost of cement prohibits high cement usage. This paper considers the use of reinforcements in cemented fill to reduce the cement usage. It is concluded that strong cemented layers at typical spacings of about 3 meters in a low cement content bulk fill can reinforce the fill and reduce the overall cement usage. Fibre reinforcements introduced into strong layers or into bulk fills are also known to be effective in reducing cement usage. Some development work is needed to produce the ideal type of anchored fibre in order to realize economic gains from fibre-reinforced fills
Three Pillars for the Neural Control of Appetite.

Science.gov (United States)

Sternson, Scott M; Eiselt, Anne-Kathrin

2017-02-10

The neural control of appetite is important for understanding motivated behavior as well as the present rising prevalence of obesity. Over the past several years, new tools for cell type-specific neuron activity monitoring and perturbation have enabled increasingly detailed analyses of the mechanisms underlying appetite-control systems. Three major neural circuits strongly and acutely influence appetite but with notably different characteristics. Although these circuits interact, they have distinct properties and thus appear to contribute to separate but interlinked processes influencing appetite, thereby forming three pillars of appetite control. Here, we summarize some of the key characteristics of appetite circuits that are emerging from recent work and synthesize the findings into a provisional framework that can guide future studies.
Pillarization and Islam: Church-state traditions and Muslim claims for recognition in the Netherlands

NARCIS (Netherlands)

Maussen, M.

2012-01-01

Public policy responses to Muslim immigration in the Netherlands are often presented as crucially shaped by ‘pillarization’. This article takes issue with this perception by challenging two related assumptions. On the one hand, that the Dutch church-state model is essentially about pillarization
Aespoe Task Force on modelling of groundwater flow and transport of solutes. Review of Tasks 6b, 6b and 6b

Energy Technology Data Exchange (ETDEWEB)

Hodgkinson, David [Quintessa, Henley-on-Thames (United Kingdom); Black, John [In Situ Solutions, East Bridgford (United Kingdom)

2005-03-01

This report forms part of an independent review of the specifications, execution and results of Task 6 of the Aespoe Task Force on Modelling of Groundwater Flow and Transport of Solutes, which is seeking to provide a bridge between site characterization and performance assessment approaches to solute transport in fractured rock. The present report is concerned solely with Tasks 6b, 6b and 6b which relate to the transport of tracers on a 5-metre scale in Feature A at the TRUE-1 site. The task objectives, specifications and individual modelling team results are summarised and reviewed, and an evaluation of the overall exercise is presented. The report concludes with assessments of what has been learnt, the implications for the Task 6 objectives, and some possible future directions.
Heterogeneous photo-Fenton decolorization of Orange II over Al-pillared Fe-smectite: Response surface approach, degradation pathway, and toxicity evaluation

Energy Technology Data Exchange (ETDEWEB)

Li, Huiyuan; Li, Yanli [Department of Environmental Engineering, Wuhan University, Wuhan 430079 (China); Xiang, Luojing [Department of Environmental Engineering, Wuhan University, Wuhan 430079 (China); Université de Poitiers, UMR CNRS 7285, IC2MP, ENSIP, B1, 1 rue Marcel Doré, TSA 41105, Poitiers 86073 Cedex 9 (France); Huang, Qianqian; Qiu, Juanjuan [Department of Environmental Engineering, Wuhan University, Wuhan 430079 (China); Zhang, Hui, E-mail: eeng@whu.edu.cn [Department of Environmental Engineering, Wuhan University, Wuhan 430079 (China); Sivaiah, Matte Venkata; Baron, Fabien; Barrault, Joel; Petit, Sabine [Université de Poitiers, UMR CNRS 7285, IC2MP, ENSIP, B1, 1 rue Marcel Doré, TSA 41105, Poitiers 86073 Cedex 9 (France); Valange, Sabine, E-mail: sabine.valange@univ-poitiers.fr [Université de Poitiers, UMR CNRS 7285, IC2MP, ENSIP, B1, 1 rue Marcel Doré, TSA 41105, Poitiers 86073 Cedex 9 (France)

2015-04-28

Highlights: • Al-pillared Fe-smectite was synthesized and used as the photo-Fenton catalyst. • Response surface methodology was used to study the effects of reaction parameters. • The main intermediate products were identified by GC–MS technique. • A possible degradation pathway of Orange II was proposed. • All the generated products of Orange II were less toxic than the original dye. - Abstract: A ferric smectite clay material was synthesized and further intercalated with Al{sub 2}O{sub 3} pillars for the first time with the aim of evaluating its ability to be used as heterogeneous catalyst for the photo-Fenton decolorization of azo dye Orange II. UV irradiation was found to enhance the activity of the catalyst in the heterogeneous photo-Fenton process. Catalyst loading of 0.5 g/L and hydrogen peroxide concentration of 13.5 mM yielded a remarkable color removal, accompanied by excellent catalyst stability. The decolorization of Orange II followed the pseudo-first-order kinetics for initial dye concentrations from 20 to 160 mg/L. The central composite design (CCD) based on the response surface methodology (RSM) was applied to evaluate the effects of several operating parameters, namely initial pH, catalyst loading and hydrogen peroxide concentration, on the decolorization efficiency. The RSM model was derived and the response surface plots were developed based on the results. Moreover, the main intermediate products were separated and identified using gas chromatography–mass spectrometry (GC–MS) and a possible degradation pathway was proposed accordingly. The acute toxicity experiments illustrated that the Daphniamagna immobilization rate continuously decreased during 150 min reaction, indicating that the effluent was suitable for sequential biological treatment.
The Sloan-C Pillars and Boundary Objects As a Framework for Evaluating Blended Learning

Science.gov (United States)

Laumakis, Mark; Graham, Charles; Dziuban, Chuck

2009-01-01

The authors contend that blended learning represents a boundary object; a construct that brings together constituencies from a variety of backgrounds with each of these cohorts defining the object somewhat differently. The Sloan-C Pillars (learning effectiveness, access, cost effectiveness, student satisfaction, and faculty satisfaction) provide…
Porphyrinic supramolecular daisy chains incorporating pillar[5]arene-viologen host-guest interactions

KAUST Repository

Fathalla, Maher; Strutt, Nathan; Srinivasan, Sampath; Katsiev, Khabiboulakh; Hartlieb, Karel J.; Bakr, Osman; Stoddart, J. Fraser

2015-01-01

A porphyrin functionalised with pillar[5]arene and a viologen at its 5- and 15-meso positions assembles in a head-to-tail manner, producing linear supramolecular daisy chains in dichloromethane. At high concentrations, it forms an organogel which has been investigated by electron microscopy and rheological measurements, paving the way for the preparation of other functional supramolecular assemblies which harness viologen"⊂" pillararene host-guest interactions.
Dense high-aspect ratio 3D carbon pillars on interdigitated microelectrode arrays

DEFF Research Database (Denmark)

Amato, Letizia; Heiskanen, Arto; Hansen, Rasmus

2015-01-01

In this work we present high-aspect ratio carbon pillars (1.4 μm in diameter and ∼11 μm in height) on top of interdigitated electrode arrays to be used for electrochemical applications. For this purpose, different types of 2D and 3D pyrolysed carbon structures were fabricated and characterised...... of pyrolysed carbon films with increased film resistance due to oxidation during storage....
Porphyrinic supramolecular daisy chains incorporating pillar[5]arene-viologen host-guest interactions

KAUST Repository

Fathalla, Maher

2015-05-18

A porphyrin functionalised with pillar[5]arene and a viologen at its 5- and 15-meso positions assembles in a head-to-tail manner, producing linear supramolecular daisy chains in dichloromethane. At high concentrations, it forms an organogel which has been investigated by electron microscopy and rheological measurements, paving the way for the preparation of other functional supramolecular assemblies which harness viologen"⊂" pillararene host-guest interactions.
Reduced-Pressure Chemical Vapor Deposition Growth of Isolated Ge Crystals and Suspended Layers on Micrometric Si Pillars.

Science.gov (United States)

Skibitzki, Oliver; Capellini, Giovanni; Yamamoto, Yuji; Zaumseil, Peter; Schubert, Markus Andreas; Schroeder, Thomas; Ballabio, Andrea; Bergamaschini, Roberto; Salvalaglio, Marco; Miglio, Leo; Montalenti, Francesco

2016-10-05

In this work, we demonstrate the growth of Ge crystals and suspended continuous layers on Si(001) substrates deeply patterned in high aspect-ratio pillars. The material deposition was carried out in a commercial reduced-pressure chemical vapor deposition reactor, thus extending the "vertical-heteroepitaxy" technique developed by using the peculiar low-energy plasma-enhanced chemical vapor deposition reactor, to widely available epitaxial tools. The growth process was thoroughly analyzed, from the formation of small initial seeds to the final coalescence into a continuous suspended layer, by means of scanning and transmission electron microscopy, X-ray diffraction, and μ-Raman spectroscopy. The preoxidation of the Si pillar sidewalls and the addition of hydrochloric gas in the reactants proved to be key to achieve highly selective Ge growth on the pillars top only, which, in turn, is needed to promote the formation of a continuous Ge layer. Thanks to continuum growth models, we were able to single out the different roles played by thermodynamics and kinetics in the deposition dynamics. We believe that our findings will open the way to the low-cost realization of tens of micrometers thick heteroepitaxial layer (e.g., Ge, SiC, and GaAs) on Si having high crystal quality.
Counter-rotating type tidal stream power unit boarded on pillar (performances and flow conditions of tandem propellers)

Science.gov (United States)

Usui, Yuta; Kanemoto, Toshiaki; Hiraki, Koju

2013-12-01

The authors have invented the unique counter-rotating type tidal stream power unit composed of the tandem propellers and the double rotational armature type peculiar generator without the traditional stator. The front and the rear propellers counter-drive the inner and the outer armatures of the peculiar generator, respectively. The unit has the fruitful advantages that not only the output is sufficiently higher without supplementary equipment such as a gearbox, but also the rotational moment hardly act on the pillar because the rotational torque of both propellers/armatures are counter-balanced in the unit. This paper discusses experimentally the performances of the power unit and the effects of the propeller rotation on the sea surface. The axial force acting on the pillar increases naturally with the increase of not only the stream velocity but also the drag of the tandem propellers. Besides, the force vertical to the stream also acts on the pillar, which is induced from the Karman vortex street and the dominant frequencies appear owing to the front and the rear propeller rotations. The propeller rotating in close to the sea surface brings the abnormal wave and the amplitude increases as the stream velocity is faster and/or the drag is stronger.
Preparation of C.I. Pigment 52:1 anion-pillared layered double hydroxide and the thermo- and photostability of the resulting intercalated material

Science.gov (United States)

Guo, Shengchang; Evans, David G.; Li, Dianqing

2006-05-01

Intercalation of 2-naphthalenecarboxylic acid, 4-((4-chloro-5-methyl-2-sulfophenyl) azo)-3-hydroxy-, calcium salt (1:1) (C.I. Pigment Red 52:1, also known as New Rubine S6B) into a layered double hydroxide (LDHs) host was carried out using MgAl NO3 LDHs as a precursor in an effort to improve the thermal and photo stability of the pigment. After intercalation, the powder X-ray diffraction (XRD) pattern shows that the basal spacing of the LDHs increased from 0.86 to 1.92 nm. Infrared spectra and TG DTA curves demonstrate that there are supramolecular host guest interactions. It was found that the intercalated material is more stable than the pristine pigment at high temperatures. The pigment anion-pillared LDHs also exhibit much higher photostablity to UV-light than the pristine pigment.
Reproductive natural history and successful juvenile propagation of the threatened Caribbean Pillar Coral Dendrogyra cylindrus

NARCIS (Netherlands)

Marhaver, K.L.; Vermeij, M.J.A.; Medina, M.M.

2015-01-01

Background: The Caribbean pillar coral Dendrogyra cylindrus was recently listed as a threatened species under the United States Endangered Species Act. One of the major threats to this species is its low, virtually undetectable recruitment rate. To our knowledge, sexually-produced recruits have
Preparation and extraction of sloping seams without leaving inter-drift coal pillars

Energy Technology Data Exchange (ETDEWEB)

Artamonov, N S; Bormotov, I N; Brovko, I I

1977-10-01

A description is given of mining three coal seams in the Kuznetsk Basin without leaving coal pillars because they could not withstand the stress of the induced reference pressure. This system reduced coal losses in 1976 in comparison to 1970 and eliminated local accumulations of methane by withdrawing it through the excavated area. The system was noted to have the disadvantage of additional expenditures for timber supports. 2 figures.
Sealing of 300 mm boreholes KXTT3 and KXTT4 at Aespoe HRL. Report of Subproject 3 of Borehole sealing Project

Energy Technology Data Exchange (ETDEWEB)

Pusch, Roland [Drawrite AB, Lund (Sweden); Luleaa Technical Univ., Luleaa (Sweden); Ramqvist, Gunnar [Eltekno AB, Figeholm (Sweden)

2011-11-15

Sealing of two moderately dipping 300 mm diameter holes that had been bored from a niche adjacent to the ramp in the Aespoe URL in conjunction with earlier geohydrological investigations (TRUE Project, Winberg et al. 2000) was successfully completed in early 2010. The work was preceded by a pilot test on the ground surface for investigating if a simple version of sealing by pressing down clay pellets into clay mud is feasible. The borehole was simulated by a steel tube that was filled with smectite mud in which a cage filled with clay pellets was moved down. The experience from this experiment was that the mud used was somewhat too stiff and that strong vibration significantly reduced its viscosity but not sufficiently much. The predicted average density at water saturation was 1,780 kg/m{sup 3} (dry density 1,240 kg/m{sup 3}). The finally selected sealing method comprised casting of concrete plugs where the inflow of water was significant (up to 30 l/min), and to install precompacted blocks of smectite-rich clay where the rock was 'dry'. The finally matured clay plugs will have a density of around 2,000 kg/m{sup 3} (dry density 1,580 kg/m{sup 3}) and a hydraulic conductivity of less than E-12 m/s, which is estimated to be at least one order of magnitude lower than the bulk conductivity of the surrounding rock mass (Pusch 2008). This provides excellent sealing of all parts of the holes deeper than about 1-2 m below the tunnel floor. Groundwater flow in the rock around the clay plugs can cause some minor erosion but this effect is deemed negligible considering the coagulating effect on released clay particles by the brackish Aespoe water. Inspection of the closed upper borehole ends showed accumulation of some very dilute mineral suspension after a few days. A careful analysis of the mineral content showed that it did not contain smectite particles, hence certifying that erosion of the clay plugs in the holes had not taken place. The particles were
Sealing of 300 mm boreholes KXTT3 and KXTT4 at Aespoe HRL. Report of Subproject 3 of Borehole sealing Project

International Nuclear Information System (INIS)

Pusch, Roland; Ramqvist, Gunnar

2011-11-01

Sealing of two moderately dipping 300 mm diameter holes that had been bored from a niche adjacent to the ramp in the Aespoe URL in conjunction with earlier geohydrological investigations (TRUE Project, Winberg et al. 2000) was successfully completed in early 2010. The work was preceded by a pilot test on the ground surface for investigating if a simple version of sealing by pressing down clay pellets into clay mud is feasible. The borehole was simulated by a steel tube that was filled with smectite mud in which a cage filled with clay pellets was moved down. The experience from this experiment was that the mud used was somewhat too stiff and that strong vibration significantly reduced its viscosity but not sufficiently much. The predicted average density at water saturation was 1,780 kg/m 3 (dry density 1,240 kg/m 3 ). The finally selected sealing method comprised casting of concrete plugs where the inflow of water was significant (up to 30 l/min), and to install precompacted blocks of smectite-rich clay where the rock was 'dry'. The finally matured clay plugs will have a density of around 2,000 kg/m 3 (dry density 1,580 kg/m 3 ) and a hydraulic conductivity of less than E-12 m/s, which is estimated to be at least one order of magnitude lower than the bulk conductivity of the surrounding rock mass (Pusch 2008). This provides excellent sealing of all parts of the holes deeper than about 1-2 m below the tunnel floor. Groundwater flow in the rock around the clay plugs can cause some minor erosion but this effect is deemed negligible considering the coagulating effect on released clay particles by the brackish Aespoe water. Inspection of the closed upper borehole ends showed accumulation of some very dilute mineral suspension after a few days. A careful analysis of the mineral content showed that it did not contain smectite particles, hence certifying that erosion of the clay plugs in the holes had not taken place. The particles were concluded to represent fracture
Aespoe Task Force on modelling of groundwater flow and transport of solutes. Review of Tasks 6A, 6B and 6B2

International Nuclear Information System (INIS)

Hodgkinson, David; Black, John

2005-03-01

This report forms part of an independent review of the specifications, execution and results of Task 6 of the Aespoe Task Force on Modelling of Groundwater Flow and Transport of Solutes, which is seeking to provide a bridge between site characterization and performance assessment approaches to solute transport in fractured rock. The present report is concerned solely with Tasks 6b, 6b and 6b which relate to the transport of tracers on a 5-metre scale in Feature A at the TRUE-1 site. The task objectives, specifications and individual modelling team results are summarised and reviewed, and an evaluation of the overall exercise is presented. The report concludes with assessments of what has been learnt, the implications for the Task 6 objectives, and some possible future directions
The 5 Clinical Pillars of Value for Total Joint Arthroplasty in a Bundled Payment Paradigm.

Science.gov (United States)

Kim, Kelvin; Iorio, Richard

2017-06-01

Our large, urban, tertiary, university-based institution reflects on its 4-year experience with Bundled Payments for Care Improvement. We will describe the importance of 5 clinical pillars that have contributed to the early success of our bundled payment initiative. We are convinced that value-based care delivered through bundled payment initiatives is the best method to optimize patient outcomes while rewarding surgeons and hospitals for adapting to the evolving healthcare reforms. We summarize a number of experiences and lessons learned since the implementation of Bundled Payments for Care Improvement at our institution. Our experience has led to the development of more refined clinical pathways and coordination of care through evidence-based approaches. We have established that the success of the bundled payment program rests on the following 5 main clinical pillars: (1) optimizing patient selection and comorbidities; (2) optimizing care coordination, patient education, shared decision making, and patient expectations; (3) using a multimodal pain management protocol and minimizing narcotic use to facilitate rapid rehabilitation; (4) optimizing blood management, and standardizing venous thromboembolic disease prophylaxis treatment by risk standardizing patients and minimizing the use of aggressive anticoagulation; and (5) minimizing post-acute facility and resource utilization, and maximizing home resources for patient recovery. From our extensive experience with bundled payment models, we have established 5 clinical pillars of value for bundled payments. Our hope is that these principles will help ease the transition to value-based care for less-experienced healthcare systems. Copyright © 2017 Elsevier Inc. All rights reserved.
Quantitative determination and monitoring of water distribution in Aespoe granite

International Nuclear Information System (INIS)

Zimmer, U.

1998-01-01

To identify possible zones of two-phase-flow and the extension of the excavation disturbed zone, geoelectric measurements are conducted in the ZEDEX- and the DEMO-tunnel. The electric resistivity of a hard rock is usually determined by its water content, its water salinity and its porosity structure. By calibration measurements of the resistivity on rocks with well known water content, a relation between resistivity and water content for Aespoe granite is determined. This relation is used to correlate the in-situ resistivity with the water content of the rock. To determine the in-situ resistivity between the ZEDEX- and the DEMO-tunnel an electrode array of nearly 300 electrodes was installed along the tunnel walls and in one borehole. With a semiautomatic recording unit which is operated by a telephone connection from the GRS-office in Braunschweig/Germany, the resistivity is monitored between and around the tunnels. To correlate the resistivity with the water content, the measured apparent resistivity has to be converted into a resistivity model of the underground. Since many thin water bearing fractures complicate this inversion process, the accuracy and resolution of the different inversion programs are checked before their application to the data. It was found that an acceptable quantitative reconstruction of the resistivity requires the integration of geometric information about the fracture zones into the inversion process. For a rough estimation of the position of possible fracture zones, a simple inversion without any geometric boundary conditions can be used. Since the maximum investigation area is limited along a single tunnel for profile measurements, tomographic measurements were also applied to estimate the resistivity distribution between the ZEDEX- and the DEMO-tunnel. These tomographic measurements have a lower resolution than the profile measurements due to the required large computer power, but result in reconstructions that give an estimate of
Geochemical Investigations of Groundwater Stability

Energy Technology Data Exchange (ETDEWEB)

Bath, Adrian [Intellisci Ltd., Loughborough (United Kingdom)

2006-05-15

groundwaters, and also by stable isotopes and uranium isotopes in secondary minerals. Information on timing of water and solute movements is important because it indicates any correlation with the timing of external events that might have perturbed and destabilised the groundwater system in the past, and allows a timescale to be estimated for the persistence of stable conditions. Data from a number of published site investigation projects and research programmes are reviewed to illustrate the patterns of geochemical data and the relationships between them, and how these are interpreted in terms of hydrodynamic stability. Data from Aespoe and Stripa and from exploratory boreholes at Finnsjoen and other sites in Sweden are compiled and discussed. Preliminary data from SKB's ongoing site investigations at Simpevarp/Laxemar and Forsmark are not considered in detail but their general similarities with Aespoe and Finnsjoen/SFR respectively are introduced into the discussion of geochemical evidence for groundwater stability in inland and coastal areas. Relevant data from Finnish sites including Olkiluoto, from the Whiteshell URL area in Canada, from Sellafield in the UK, and from the Tono area and URL in Japan are also summarised in appendices and discussed because they add further insights into the interpretation of geochemical indicators for a range of geological environments. The compiled data provide only limited scope for comparison of groundwater evolution and stability between inland and coastal areas in Sweden, because of the patchiness of representative data especially from early site studies. The external changes that might have perturbed stable groundwater conditions in the past are glaciation (i.e. melt water, mechanical loading/unloading and permafrost) and varying sea water infiltration at coastal sites due to changes in palaeo-Baltic and isostatic conditions. The present distributions of palaeo-Baltic sea water in groundwaters at coastal sites vary, reflecting

High acidity unilamellar zeolite MCM-56 and its pillared and delaminated derivatives.

Science.gov (United States)

Gil, Barbara; Makowski, Wacław; Marszalek, Bartosz; Roth, Wieslaw J; Kubu, Martin; Čejka, Jiři; Olejniczak, Zbigniew

2014-07-21

The unilamellar form of zeolite MWW, MCM-56, which is obtained by direct hydrothermal synthesis has been studied with regard to acidity and porosity in its original and post-synthesis modified pillared and delaminated forms. The acidity measured by FTIR was found to be only slightly lower than the highly active 3-D MWW forms, MCM-22 and MCM-49. Pivalonitrile adsorption, which is a measure of spatial openness, showed 50% accessibility vs. MCM-22/49. It highlights the potential of MCM-56 as a layered material with increased access to acid sites because it does not entail laborious post-synthesis modification. Swelling, pillaring and delamination of MCM-56 are facile but result in a reduction in the number of Brønsted acid sites (BAS) while increasing accessibility to pivalonitrile. The delamination procedure involving sonication and acidification of the highly basic mother liquor produces the most visible increase in surface area and access to all BAS. The accompanying doubling of the solid yield and the decrease in absolute number of BAS suggest significant precipitation of dissolved silica generated during swelling and sonication in high pH medium. The viability of separating surfactant covered layers upon sonication with the consequence of exposing hydrophobic hydrocarbon tails to aqueous environment is addressed.
SITE-94. Discrete-feature modelling of the Aespoe Site: 3. Predictions of hydrogeological parameters for performance assessment

International Nuclear Information System (INIS)

Geier, J.E.

1996-12-01

A 3-dimensional, discrete-feature hydrological model is developed. The model integrates structural and hydrologic data for the Aespoe site, on scales ranging from semi regional fracture zones to individual fractures in the vicinity of the nuclear waste canisters. Predicted parameters for the near field include fracture spacing, fracture aperture, and Darcy velocity at each of forty canister deposition holes. Parameters for the far field include discharge location, Darcy velocity, effective longitudinal dispersion coefficient and head gradient, flow porosity, and flow wetted surface, for each canister source that discharges to the biosphere. Results are presented in the form of statistical summaries for a total of 42 calculation cases, which treat a set of 25 model variants in various combinations. The variants for the SITE-94 Reference Case model address conceptual and parametric uncertainty related to the site-scale hydrogeologic model and its properties, the fracture network within the repository, effective semi regional boundary conditions for the model, and the disturbed-rock zone around the repository tunnels and shafts. Two calculation cases simulate hydrologic conditions that are predicted to occur during future glacial episodes. 30 refs
Environmental management as a pillar for sustainable development.

Science.gov (United States)

Mikulčić, Hrvoje; Duić, Neven; Dewil, Raf

2017-12-01

There is a growing concern about how to minimize the impact of human activities on the environment. Already nowadays, in some places adaptation efforts are needed in order to avoid the irreversibility of negative human activities. Due to climate changes, and corresponding environmental and social changes, there is a great need for a more sustainable development of mankind. Over the years, research studies that analyzed the sustainable development of different communities with a multi-disciplinary approach, stressed the necessity of preserving the environment for next generations. Therefore, responsible and conscientious management of the environment is a pillar of the sustainable development concept. This review introduction article provides an overview of the recent top scientific publications related to sustainable development that mostly originated from previous SDEWES conferences. Copyright © 2017 Elsevier Ltd. All rights reserved.
Degradation of methylene blue using pillared TiO2 on de-oiled spent bleaching clay

Science.gov (United States)

Hindryawati, N.; Panggabean, A. S.; Fadillah, N. D.; Erwin; Daniel

2018-04-01

Degradation of methylene blue (MB) using pillared TiO2 onto spent bleaching clay has been conducted. Activation of deoiled spent bleaching clay (DSBC) has been done using acid, followed by pillarization with TiO2 using rarasaponin from Klerak fruit as surfactant. From the X-ray diffraction results show the mineral on DSBC is rectorite with dioctahedral mica layer and dioctahedral smectite with ratio 2:1. This molecule have formula Na.Al4(Si, Al)8.O20.(OH)4. H2O and after calcinations the pattern TiO2 was appearance at 2θ: 27.4460°, 36.0850°, 54.3216° and 56.6403°. In order to test the catalytic performance of Ti-DSBC for photodegradation of MB under UV light was conducted under several reaction conditions. The highest degradation of MB was 90 % within 50 minutes and Ti-DSBC can be reused until 5 cycles with percent degradation MB was 84 %.
Preparación y propiedades de una arcilla montmorillonita pilareada con polihidroxicationes de aluminio Preparation and properties of a montmorillonite clay pillared with aluminium polyhydroxications

Directory of Open Access Journals (Sweden)

Sibele B. C. Pergher

1999-09-01

Full Text Available Montmorillonite clay from Brazil was pillared with aluminium polyhydroxications. The influence of Al/Mont ratio and calcination temperature in the properties of the prepared materials was studied. Results showed that the pillarization process increases the basal spaces of the natural clay from 9,7 to 18,5Å and the superficial area from 41 to ~230m2/g. The calcination process at different temperatures showed that the pillared material was stable until 600oC but the adequate temperature for calcination was 450oC. Materials prepared with different Al/Mont ratios showed the maximum Al incorporation for ratios >10meq Al/g and a good distribution for rations >15meq Al/g.
Large scale gas injection test (Lasgit) performed at the Aespoe Hard Rock Laboratory. Summary report 2008

International Nuclear Information System (INIS)

Cuss, R.J.; Harrington, J.F.; Noy, D.J.

2010-02-01

This report describes the set-up, operation and observations from the first 1,385 days (3.8 years) of the large scale gas injection test (Lasgit) experiment conducted at the Aespoe Hard Rock Laboratory. During this time the bentonite buffer has been artificially hydrated and has given new insight into the evolution of the buffer. After 2 years (849 days) of artificial hydration a canister filter was identified to perform a series of hydraulic and gas tests, a period that lasted 268 days. The results from the gas test showed that the full-scale bentonite buffer behaved in a similar way to previous laboratory experiments. This confirms the up-scaling of laboratory observations with the addition of considerable information on the stress responses throughout the deposition hole. During the gas testing stage, the buffer was continued to artificially hydrate. Hydraulic results, from controlled and uncontrolled events, show that the buffer continues to mature and has yet to reach full maturation. Lasgit has yielded high quality data relating to the hydration of the bentonite and the evolution in hydrogeological properties adjacent to the deposition hole. The initial hydraulic and gas injection tests confirm the correct working of all control and data acquisition systems. Lasgit has been in successful operation for in excess of 1,385 days
Large scale gas injection test (Lasgit) performed at the Aespoe Hard Rock Laboratory. Summary report 2008

Energy Technology Data Exchange (ETDEWEB)

Cuss, R.J.; Harrington, J.F.; Noy, D.J. (British Geological Survey (United Kingdom))

2010-02-15

This report describes the set-up, operation and observations from the first 1,385 days (3.8 years) of the large scale gas injection test (Lasgit) experiment conducted at the Aespoe Hard Rock Laboratory. During this time the bentonite buffer has been artificially hydrated and has given new insight into the evolution of the buffer. After 2 years (849 days) of artificial hydration a canister filter was identified to perform a series of hydraulic and gas tests, a period that lasted 268 days. The results from the gas test showed that the full-scale bentonite buffer behaved in a similar way to previous laboratory experiments. This confirms the up-scaling of laboratory observations with the addition of considerable information on the stress responses throughout the deposition hole. During the gas testing stage, the buffer was continued to artificially hydrate. Hydraulic results, from controlled and uncontrolled events, show that the buffer continues to mature and has yet to reach full maturation. Lasgit has yielded high quality data relating to the hydration of the bentonite and the evolution in hydrogeological properties adjacent to the deposition hole. The initial hydraulic and gas injection tests confirm the correct working of all control and data acquisition systems. Lasgit has been in successful operation for in excess of 1,385 days
Globules and pillars in Cygnus X. I. Herschel far-infrared imaging of the Cygnus OB2 environment

Science.gov (United States)

Schneider, N.; Bontemps, S.; Motte, F.; Blazere, A.; André, Ph.; Anderson, L. D.; Arzoumanian, D.; Comerón, F.; Didelon, P.; Di Francesco, J.; Duarte-Cabral, A.; Guarcello, M. G.; Hennemann, M.; Hill, T.; Könyves, V.; Marston, A.; Minier, V.; Rygl, K. L. J.; Röllig, M.; Roy, A.; Spinoglio, L.; Tremblin, P.; White, G. J.; Wright, N. J.

2016-06-01

The radiative feedback of massive stars on molecular clouds creates pillars, globules and other features at the interface between the H II region and molecular cloud. Optical and near-infrared observations from the ground as well as with the Hubble or Spitzer satellites have revealed numerous examples of such cloud structures. We present here Herschel far-infrared observations between 70 μm and 500 μm of the immediate environment of the rich Cygnus OB2 association, performed within the Herschel imaging survey of OB Young Stellar objects (HOBYS) program. All of the observed irradiated structures were detected based on their appearance at 70 μm, and have been classified as pillars, globules, evaporating gasous globules (EGGs), proplyd-like objects, and condensations. From the 70 μm and 160 μm flux maps, we derive the local far-ultraviolet (FUV) field on the photon dominated surfaces. In parallel, we use a census of the O-stars to estimate the overall FUV-field, that is 103-104 G0 (Habing field) close to the central OB cluster (within 10 pc) and decreases down to a few tens G0, in a distance of 50 pc. From a spectral energy distribution (SED) fit to the four longest Herschel wavelengths, we determine column density and temperature maps and derive masses, volume densities and surface densities for these structures. We find that the morphological classification corresponds to distinct physical properties. Pillars and globules are massive (~500 M⊙) and large (equivalent radius r ~ 0.6 pc) structures, corresponding to what is defined as "clumps" for molecular clouds. EGGs and proplyd-likeobjects are smaller (r ~ 0.1 and 0.2 pc) and less massive (~10 and ~30 M⊙). Cloud condensations are small (~0.1 pc), have an average mass of 35 M⊙, are dense (~6 × 104 cm-3), and can thus be described as molecular cloud "cores". All pillars and globules are oriented toward the Cyg OB2 association center and have the longest estimated photoevaporation lifetimes, a few million
Aespoe Task Force on modelling of groundwater flow and transport of solutes. Review of Task 6C

International Nuclear Information System (INIS)

Black, John; Hodgkinson, David

2005-03-01

This report forms part of an independent review of the specifications, execution and results of Task 6 of the Aespoe Task Force on Modelling of Groundwater Flow and Transport of Solutes, which is seeking to provide a bridge between site characterization (SC) and performance assessment (PA) approaches to solute transport in fractured rock. The present report is concerned solely with Task 6C, which relates to the construction and parametrisation of a block-scale hydrostructural model of the TRUE Block Scale region of the Aespoe Hard Rock laboratory. The task objectives, specifications and outcome are summarised and reviewed. Also, consideration is given to how the hydrostructural model might affect the outcomes of Task 6D and 6E. The main conclusions of this review are summarised below: The Task 6C hydrostructural model is a more comprehensive approach to quantitatively describing a volume of fractured rock than has been achieved hitherto. The idea of including solute retention characteristics as indices attached to individual fractures is an efficient device resulting in a whole volume of fractured rock described by a few spreadsheets. The hydrostructural model is clearly defined and provides a useful test bed for Tasks 6D and 6E. It would have been beneficial if the specifications for Task 6C had been more clearly defined as a hierarchy of requirements, and performance measures had been defined and evaluated to allow comparison of alternative approaches. The device used to reduce connectivity, namely reducing the average size of background fractures, has the effect of producing a final model with an 'unnatural' gap in the overall distribution of fracture sizes. It appears that the exploratory boreholes could be important conductive structures within the region of the 200 m block even though they are segmented into shorter sections by packers. If correct, this implies that the boreholes should be included explicitly in the model if close replication of TRUE Block
International criminal justice: a pillar for the international rule of law

Directory of Open Access Journals (Sweden)

Gonzalo Aguilar Cavallo

2012-12-01

Full Text Available The international criminal justice has experienced a rapid change over the past years. This circumstance has underscored the need for interaction and complementation between international and domestic law. Some authors consider that the international criminal justice, and the activities of its tribunals, jeopardize the legality of international law. Our vision is that international criminal justice is a central pillar of the rule of law, at the national and the international levels. Far from undermining the legality of international law, international criminal justice paves the way towards a true international public order.
A continuous flow micro filtration device for plasma/blood separation using submicron vertical pillar gap structures

International Nuclear Information System (INIS)

Kang, Tae Goo; Ji, Hongmiao; Lim, Pei Yi; Chen, Yu; Yoon, Yong-Jin

2014-01-01

This work demonstrates a continuous flow plasma/blood separator using a vertical submicron pillar gap structure. The working principle of the proposed separator is based on size exclusion of cells through cross-flow filtration, in which only plasma is allowed to pass through submicron vertical pillars located tangential to the main flow path of the blood sample. The maximum filtration efficiency of 99.9% was recorded with a plasma collection rate of 0.67 µl min −1 for an input blood flow rate of 12.5 µl min −1 . The hemolysis phenomenon was observed for an input blood flow rate above 30 µl min −1 . Based on the experimental results, we can conclude that the proposed device shows potential for the application of on-chip plasma/blood separation as a part of integrated point-of-care (POC) diagnostics systems. (technical note)
Stability of Large Parallel Tunnels Excavated in Weak Rocks: A Case Study

Science.gov (United States)

Ding, Xiuli; Weng, Yonghong; Zhang, Yuting; Xu, Tangjin; Wang, Tuanle; Rao, Zhiwen; Qi, Zufang

2017-09-01

Diversion tunnels are important structures for hydropower projects but are always placed in locations with less favorable geological conditions than those in which other structures are placed. Because diversion tunnels are usually large and closely spaced, the rock pillar between adjacent tunnels in weak rocks is affected on both sides, and conventional support measures may not be adequate to achieve the required stability. Thus, appropriate reinforcement support measures are needed, and the design philosophy regarding large parallel tunnels in weak rocks should be updated. This paper reports a recent case in which two large parallel diversion tunnels are excavated. The rock masses are thin- to ultra-thin-layered strata coated with phyllitic films, which significantly decrease the soundness and strength of the strata and weaken the rocks. The behaviors of the surrounding rock masses under original (and conventional) support measures are detailed in terms of rock mass deformation, anchor bolt stress, and the extent of the excavation disturbed zone (EDZ), as obtained from safety monitoring and field testing. In situ observed phenomena and their interpretation are also included. The sidewall deformations exhibit significant time-dependent characteristics, and large magnitudes are recorded. The stresses in the anchor bolts are small, but the extents of the EDZs are large. The stability condition under the original support measures is evaluated as poor. To enhance rock mass stability, attempts are made to reinforce support design and improve safety monitoring programs. The main feature of these attempts is the use of prestressed cables that run through the rock pillar between the parallel tunnels. The efficacy of reinforcement support measures is verified by further safety monitoring data and field test results. Numerical analysis is constantly performed during the construction process to provide a useful reference for decision making. The calculated deformations are in
Thermal Emission of Alkali Metal Ions from Al30-Pillared Montmorillonite Studied by Mass Spectrometric Method.

Science.gov (United States)

Motalov, V B; Karasev, N S; Ovchinnikov, N L; Butman, M F

2017-01-01

The thermal emission of alkali metal ions from Al 30 -pillared montmorillonite in comparison with its natural form was studied by mass spectrometry in the temperature range 770-930 K. The measurements were carried out on a magnetic mass spectrometer MI-1201. For natural montmorillonite, the densities of the emission currents ( j ) decrease in the mass spectrum in the following sequence (T = 805 K, A/cm 2 ): K + (4.55 · 10 -14 ), Cs + (9.72 · 10 -15 ), Rb + (1.13 · 10 -15 ), Na + (1.75 · 10 -16 ), Li + (3.37 · 10 -17 ). For Al 30 -pillared montmorillonite, thermionic emission undergoes temperature-time changes. In the low-temperature section of the investigated range (770-805 K), the value of j increases substantially for all ions in comparison with natural montmorillonite (T = 805 K, A/cm 2 ): Cs + (6.47 · 10 -13 ), K + (9.44 · 10 -14 ), Na + (3.34 · 10 -15 ), Rb + (1.77 · 10 -15 ), and Li + (4.59 · 10 -16 ). A reversible anomaly is observed in the temperature range 805-832 K: with increasing temperature, the value of j of alkaline ions falls abruptly. This effect increases with increasing ionic radius of M + . After a long heating-up period, this anomaly disappears and the ln j - 1/ T dependence acquires a classical linear form. The results are interpreted from the point of view of the dependence of the efficiency of thermionic emission on the phase transformations of pillars.
Stability of GNSS Monumentation: Analysis of Co-Located Monuments in the UNAVCO Plate Boundary Observatory

Science.gov (United States)

Blume, F.; Herring, T.; Mattioli, G. S.; Feaux, K.; Walls, C. P.; Austin, K. E.; Dittmann, S. T.

2017-12-01

Geodetic-quality permanent GNSS stations have used a number of different monument styles for the purpose of ensuring that the motions of the GNSS antenna reflect those of the Earth's crust while minimizing non-tectonic motions near the surface. Monuments range from simple masts mounted on buildings or drilled into bedrock, costing a few hundred dollars to machine-drilled-braced monuments in soil costing tens of thousands. The stability of an individual monument will depend on its design, the construction techniques used to install it, and the local surface geology where it is installed. Previous studies have separately investigated pairs of identical monuments at a single site, monument type performance using global statistical analysis, and multiple monument styles at a single site, yet the stability of different monument types in similar geologic conditions has not been adequately determined. To better characterize the stability of various monument styles in diverse geologic conditions UNAVCO constructed two additional monuments at five existing PBO stations in 2013. Deep drilled-braced, short drilled-braced, and single mast type monuments were installed at sites with bedrock at the surface; deep drilled-braced, short driven-braced and pillar type monuments were installed at sites with alluvium or soil at the surface. The sites include a variety of geographic, hydrologic, and geologic conditions. Data collected from the PBO Multi-Monument Experiment have been analyzed using a variety of methods. Each site is characterized using quality-control parameters such as multipath, signal-to-noise and previously determined seasonal variations. High-precision processing by PBO Analysis Centers with GAMIT and GIPSY use regional and global schemes and yield time-series with millimeter-level that determine noise content, overall site stability relative to other PBO sites and differential motions between the individual monuments. Sub-millimeter results from single
The Los Alamos Science Pillars The Science of Signatures

Energy Technology Data Exchange (ETDEWEB)

Smith, Joshua E. [Los Alamos National Laboratory; Peterson, Eugene J. [Los Alamos National Laboratory

2012-09-13

As a national security science laboratory, Los Alamos is often asked to detect and measure the characteristics of complex systems and to use the resulting information to quantify the system's behavior. The Science of Signatures (SoS) pillar is the broad suite of technical expertise and capability that we use to accomplish this task. With it, we discover new signatures, develop new methods for detecting or measuring signatures, and deploy new detection technologies. The breadth of work at Los Alamos National Laboratory (LANL) in SoS is impressive and spans from the initial understanding of nuclear weapon performance during the Manhattan Project, to unraveling the human genome, to deploying laser spectroscopy instrumentation on Mars. Clearly, SoS is a primary science area for the Laboratory and we foresee that as it matures, new regimes of signatures will be discovered and new ways of extracting information from existing data streams will be developed. These advances will in turn drive the development of sensing instrumentation and sensor deployment. The Science of Signatures is one of three science pillars championed by the Laboratory and vital to supporting our status as a leading national security science laboratory. As with the other two pillars, Materials for the Future and Information Science and Technology for Predictive Science (IS&T), SoS relies on the integration of technical disciplines and the multidisciplinary science and engineering that is our hallmark to tackle the most difficult national security challenges. Over nine months in 2011 and 2012, a team of science leaders from across the Laboratory has worked to develop a SoS strategy that positions us for the future. The crafting of this strategy has been championed by the Chemistry, Life, and Earth Sciences Directorate, but as you will see from this document, SoS is truly an Institution-wide effort and it has engagement from every organization at the Laboratory. This process tapped the insight and
Pillarization of layer double hydroxides (Mg/Al with keggin type K4[α-SiW12O40]•nH2O and its application as adsorbent of procion red dye

Directory of Open Access Journals (Sweden)

Intan Permata Sari

2017-07-01

Full Text Available Pillarization of layered double hydroxides with polyoxometalate K4[α-SiW12O40]•nH2O at various times i.e. 3, 6, 9, 12, 24, 36 and 48 hours has been done. The pillared product was characterized by FT-IR spectrophotometer and XRD. The optimum pillared layered double hydroxides of polyoxometalate K4[α-SiW12O40]•nH2O was used as an adsorbent of procion red dye. The results of characterization using FT-IR spectrophotometer is not yet show the optimum pillarization process. The characterisation using XRD the successfully of pillared layered double hydroxides of polyoxometalate K4[α-SiW12O40]•nH2O showing the existence of diffraction angle 8.5o with intensity 355. Furthermore, the pillared layered double hydroxides of polyoxometalate K4[α-SiW12O40]•nH2O with time variation of 12 hours was applied as an adsorbent of procion red dye. The results show the adsorption rate was 0.523 min-1, the highest of absorption capacity at 70oC was 10.8 mol/g, the highest energy of absorption 70 oC was 125 kJ/mol. The enthalpy (∆H and entropy (∆S, decrease as the increasing concentration of procion red dye. Keywords: layered double hydroxides, polyoxometalate, pillaration, procion red, adsorption
Thermal conductivity of pillared graphene-epoxy nanocomposites using molecular dynamics

Science.gov (United States)

Lakshmanan, A.; Srivastava, S.; Ramazani, A.; Sundararaghavan, V.

2018-04-01

Thermal conductivity in a pillared graphene-epoxy nanocomposite (PGEN) is studied using equilibrium molecular dynamics simulations. PGEN is a proposed material for advanced thermal management applications because it combines high in-plane conductivity of graphene with high axial conductivity of a nanotube to significantly enhance the overall conductivity of the epoxy matrix material. Anisotropic conductivity of PGEN has been compared with that of pristine and functionalized carbon nanotube-epoxy nanocomposites, showcasing the advantages of the unique hierarchical structure of PGEN. Compared to pure carbon allotropes, embedding the epoxy matrix also promotes a weaker dependence of conductivity on thermal variations. These features make this an attractive material for thermal management applications.
Constraint effects of model coal pillar geometry on its strength

Energy Technology Data Exchange (ETDEWEB)

Wahab Khair, A.; Danqing Xu (West Virgina University, Morgantown, WV (United States))

1994-06-01

Coal and rock specimens with various diameter/height ratios (D/H) were subjected to compressive test in the laboratory. The deformation and failure characteristics of specimens were studied. The study showed that the D/H ratio of specimens significantly affects the deformation, failure characteristics, and the strength of material. The results provide a better understanding of the mechanism of D/H ratio effect on the strength of materials. The magnitude and mechanism of D/H ratio effect was compared with the effect of confining pressure, and contrasted to size effect. The application of the study to pillar design is discussed. 3 refs., 10 figs.
Effect of the platinum content on the microstructure and micropore size distribution of Pt/alumina-pillared clays.

Science.gov (United States)

Barrera-Vargas, M; Valencia-Rios, J; Vicente, M A; Korili, S A; Gil, A

2005-12-15

The aim of this work is to study the effect of the platinum content (0-1.8 wt % Pt) on the microstructure of an alumina-pillared clay. For this purpose, the nitrogen physisorption data at -196 degrees C, the micropore size distributions of the supported platinum catalysts, and the hydrogen chemisorption results at 30 degrees C have been analyzed and compared. The preparation of the catalysts has modified the textural properties of the Al-pillared clay support, giving rise to a loss of surface area and micropore volume. After reduction at 420 degrees C, the presence of dispersed metallic platinum with mean crystallite size in the 22-55 A range has been found by hydrogen adsorption. Comparison of all results reveals that the platinum species block the micropore entrances by steric hindrance to nitrogen access as the platinum content increases.
Studies of adsorption of pillarized and organofunctionalized smectite clay for Th"4"+ removal

International Nuclear Information System (INIS)

Guerra, D.J.L.; Menonca, E.S.; Silva, R.A.R.; Lara, W.

2012-01-01

A natural smectite clay sample was taken from the Amazon region, Amazonas State, Brazil. Zirconium polyoxycations were inserted into the smectite structure in a pillaring process. The pillarized smectite was organofunctionalized with the compound 3-mercaptopropyltrimethoxysilane. The natural and modified clay samples were used for the adsorption of tetravalent thorium cation from aqueous solution in a batch process. The adsorption process was fitted to equilibrium and kinetic models. The effects of stirring time, adsorbent dosage and pH on the adsorption capacity demonstrated that 90 min is sufficient to reach equilibrium at room temperature at pH 6.0. From the cation/basic center interactions for each smectite at the solid-liquid interface, the equilibrium constant and exothermic thermal effects were calculated with calorimetric methodology. By considering the net interactive number of moles for thorium cation and the equilibrium constant, the enthalpy, (-7.2 ± 0.11 to -7.0 ± 0.11 kJ mol"-"1) and negative Gibbs free energy, (-22.4 ± 0.1 to -23.1 ± 0.1 kJ mol"-"1) were calculated. These values enabled determination of the positive entropy, (51.2 ± 0.1 to 54.1 ± 0.1 JK"-"1mol"-"1). All liquid/solid interface adsorptions were spontaneous in nature and enthalpically driven.

The next chapter in MOF pillaring strategies: Trigonal heterofunctional ligands to access targeted high-connected three dimensional nets, isoreticular platforms

KAUST Repository

Eubank, Jarrod F.

2011-11-09

A new pillaring strategy, based on a ligand-to-axial approach that combines the two previous common techniques, axial-to-axial and ligand-to-ligand, and permits design, access, and construction of higher dimensional MOFs, is introduced and validated. Trigonal heterofunctional ligands, in this case isophthalic acid cores functionalized at the 5-position with N-donor (e.g., pyridyl- or triazolyl-type) moieties, are designed and utilized to pillar pretargeted two-dimensional layers (supermolecular building layers, SBLs). These SBLs, based on edge transitive Kagomé and square lattices, are cross-linked into predicted three-dimensional MOFs with tunable large cavities, resulting in isoreticular platforms. © 2011 American Chemical Society.
The next chapter in MOF pillaring strategies: Trigonal heterofunctional ligands to access targeted high-connected three dimensional nets, isoreticular platforms

KAUST Repository

Eubank, Jarrod F.; Wojtas, Łukasz; Hight, Matthew R.; Bousquet, Till; Kravtsov, Victor Ch H; Eddaoudi, Mohamed

2011-01-01

A new pillaring strategy, based on a ligand-to-axial approach that combines the two previous common techniques, axial-to-axial and ligand-to-ligand, and permits design, access, and construction of higher dimensional MOFs, is introduced and validated. Trigonal heterofunctional ligands, in this case isophthalic acid cores functionalized at the 5-position with N-donor (e.g., pyridyl- or triazolyl-type) moieties, are designed and utilized to pillar pretargeted two-dimensional layers (supermolecular building layers, SBLs). These SBLs, based on edge transitive Kagomé and square lattices, are cross-linked into predicted three-dimensional MOFs with tunable large cavities, resulting in isoreticular platforms. © 2011 American Chemical Society.
Effect of Manganese Promotion on Al-Pillared Montmorillonite Supported Cobalt Nanoparticles for Fischer-Tropsch Synthesis

International Nuclear Information System (INIS)

Ahmad, N.; Hussain, S. T.; Abbas, S. M.; Khan, Y.; Muhammad, B.; Ali, N.

2013-01-01

The effect of Mn-promotion on high surface area Al-pillared montmorillonite (AlMMT) supported Co nanoparticles prepared by hydrothermal method have been investigated. A series of different weight% Mn-promoted Co nanoparticles were prepared and characterized by XRD, TPR, TGA, BET and SEM techniques. An increase in the surface area of MMT is observed with Al-pillaring. Fischer-Tropsch catalytic activity of the as prepared catalysts was studied in a fixed bed micro reactor at 225 .deg. C, H 2 /CO = 2 and at 1 atm pressure. The data showed that by the addition of Mn the selectivity of C 1 dropped drastically while that of C 2 -C 12 hydrocarbons increased significantly over all the Mn-promoted Co/AlMMT catalysts. The C 13 -C 20 hydrocarbons remained almost same for all the catalysts while the selectivity of C 21+ long chain hydrocarbons decreased considerably with the addition of Mn. The catalyst with 3.5%Mn showed lowest C 21+ and highest C 2 -C 12 hydrocarbons selectivity due to cracking of long chain hydrocarbons over acidic sites of MMT
Use of Pillared Clay-Based Catalysts for Wastewater Treatment through Fenton-Like Processes

OpenAIRE

J. Herney-Ramírez; Luis M. Madeira

2010-01-01

Clays, both natural and physical-chemically modified, are attractive materials for the preparation of supported catalysts. In this chapter, a review is made regarding the use of pillared interlayered clays (PILCs) in heterogeneous Fenton-like advanced oxidation processes. Their applications in pollutants degradation is summarized, with particular emphasis on the effect of the main operating conditions (e.g., initial H2O2 or parent compound concentration, catalyst load, pH, or temperature) on ...
A framework for work-based learning: basic pillars and the interactions between them

OpenAIRE

Ferrández Berrueco, María Reina; Kekale, Tauno; Devins, David

2016-01-01

Purpose – European policy is placing an increasing emphasis on involving employers and labour market institutions in the design and delivery of higher education (HE) programmes that match curricula to current and future needs of the economy. The purpose of this paper is to investigate the curriculum development process for work-based learning (WBL) programmes and to connect it to the basic pillars, organizational and pedagogical strategies and key stages that enable higher education instit...
Structure and use of conceptual models in the Aespoe site investigations

International Nuclear Information System (INIS)

Gustafsson, Gunnar

1998-01-01

Early in the Aespoe project a need for structuring and clarification of the models used for different purposes was identified. The problem lied not in the numerical codes or the data base used for the modelling but rather in the process of how the real world was conceptualized into descriptive and predictive models. A proposal on how to structure these conceptual assumptions was made on which a standardised representation of used models was worked out. An essential objective has been to condensate the model descriptions to one page and still present the essential aspects of each model. It is hoped that in this way it is easier to obtain an overview of the assumptions underlying each model and facilitate comparison between different models. The base for the description is the 'intended use of the model'. Based on the intended use the next step is to identify what 'physical' processes should be included in the model. In some cases these processes can be represented by constitutive equations. The next step is to define the 'concepts' needed to solve the problem. The concepts may be separated into four groups. Firstly, the type of 'geometrical framework' and the framework-related parameters have to be defined. Secondly, the type of 'material properties' to be assigned to the domains defined by the geometrical framework must be decided. Thirdly, the 'spatial assignment method' of the material properties within a domain has to be described. Finally, the model normally has a limited extent and the 'boundary conditions' have to be defined to compute or judge the effects within the model. For a real case the data can now be defined for the four groups of concepts by analysing measurements representing the actual case. If needed a 'numerical or mathematical tool' that handles the processes and concepts should the be chosen. 'Output parameters' of interest for model purposes must then be defined
A pillar-layered metal-organic framework as luminescent sensor for selective and reversible response of chloroform

Energy Technology Data Exchange (ETDEWEB)

Wang, Kun; Li, Shuni; Jiang, Yucheng; Hu, Mancheng; Zhai, Quan-Guo, E-mail: zhaiqg@snnu.edu.cn

2017-03-15

A new 3D metal-organic framework, namely, (Zn{sub 4}(H{sub 2}BPTC){sub 2}(HCOO){sub 4}){sub n} (SNNU-1, H{sub 4}BPTC=biphenyl-3,3',5,5'-tetracarboxylic acid, SNNU=Shaanxi Normal University) has been solvothermal synthesized. Four independent tetrahedral Zn atoms are connected by organic ligands to form a 2D Zn-H{sub 2}BPTC layer, which is further bridged by in-situ generated HCOO{sup -} to give the 3D pillar-layered framework of SNNU-1. Unique Zn and H{sub 2}BPTC all act as 4-connected nodes leading to a new 4,4,4-connected topological net with point symbol of (4·5·6{sup 2}·8{sup 2})(4·5{sup 2}·6{sup 2}·8)(5{sup 2}·6{sup 3}·7). Notably, intense blue emission band is observed for SNNU-1, which exhibits solvent-dependent effect. Compared to other common organic solvents, chloroform can specially improve the photoluminescent intensity of SNNU-1. Further repeated response and release experiments clearly showed that SNNU-1 can act as luminescent sensor for selective and reversible detection of chloroform. - Graphical abstract: Zn{sup 2+} ions are bridged by aromatic tetracarboxylate ligands and inorganic formate anions to give a microporous pillar layered open-framework, which exhibits not only strong photoluminescence but also selective and reversible luminescent sensing for chloroform. - Highlights: • Novel Zn-tetracarboxylate-formate microporous pillar layered open-framework. • New 4,4,4-connected topology and rod-packing net. • Solvent-dependent photoluminescent intensity. • Selective and reversible response for chloroform.
Thermal Emission of Alkali Metal Ions from Al30-Pillared Montmorillonite Studied by Mass Spectrometric Method

Directory of Open Access Journals (Sweden)

V. B. Motalov

2017-01-01

Full Text Available The thermal emission of alkali metal ions from Al30-pillared montmorillonite in comparison with its natural form was studied by mass spectrometry in the temperature range 770–930 K. The measurements were carried out on a magnetic mass spectrometer MI-1201. For natural montmorillonite, the densities of the emission currents (j decrease in the mass spectrum in the following sequence (T = 805 K, A/cm2: K+ (4.55 · 10−14, Cs+ (9.72 · 10−15, Rb+ (1.13 · 10−15, Na+ (1.75 · 10−16, Li+ (3.37 · 10−17. For Al30-pillared montmorillonite, thermionic emission undergoes temperature-time changes. In the low-temperature section of the investigated range (770–805 K, the value of j increases substantially for all ions in comparison with natural montmorillonite (T = 805 K, A/cm2: Cs+ (6.47 · 10−13, K+ (9.44 · 10−14, Na+ (3.34 · 10−15, Rb+ (1.77 · 10−15, and Li+ (4.59 · 10−16. A reversible anomaly is observed in the temperature range 805–832 K: with increasing temperature, the value of j of alkaline ions falls abruptly. This effect increases with increasing ionic radius of M+. After a long heating-up period, this anomaly disappears and the lnj-1/T dependence acquires a classical linear form. The results are interpreted from the point of view of the dependence of the efficiency of thermionic emission on the phase transformations of pillars.
THE EVALUATION OF EIGHT PILLARS TOTAL PRODUCTIVE MAINTENANCE (TPM IMPLEMENTATION AND THEIR IMPACT ON OVERALL EQUIPMENT EFFECTIVENESS (OEE AND WASTE

Directory of Open Access Journals (Sweden)

Herry Agung Prabowo

2018-02-01

Full Text Available In this global era where the level of competition is higher, in addition to the influence of the suitable marketing strategy is also required strategy from the side of production/productivity. PT. XYZ is a company engaged in the manufacturing of snacks especially biscuits. The problem that often occurs in this company is the number of biscuits that are not in accordance with the standard and the production does not reach the target set because the machine suddenly breaks down frequently. To overcome the problems PT. XYZ then choose to implement the Total Productive Maintenance (TPM strategy. This study aims to evaluate the implementation of 8 TPM Pillars and measure the effects on manufacturing performance in the form of Overall Equipment Effectiveness (OEE and Waste. This study uses questionnaire-based survey method. The number of samples distributed is 40 units. Which returned and filled 33 questionnaires and which is worth to be processed as many as 30 samples. Then tested the validity and reliability of data using SPSS program. Validity critical value R = 0.361 for n = 30 and error rate 5%. For reliability test, R value = 0.60 was selected. From the validity test, there are 7 items of questions that are not valid so it is not included in the next process. For the reliability test of the questionnaire is quite reliable with the value of Cronbach's alpha of 0.811. From the CFA analysis, only 6 of 8 TPM pillars are significant while for manufacturing performance only OEE variable is significant. Correlation between 8 Pillars of TPM and manufacturing performance is Strong enough with a value of R = 0.862, which also means 74.3% (R2 variable manufacturing performance can be explained/influenced by variable 8 Pillar TPM and 26.7% the rest by other variables.
Integrated analysis of rock mass deformation within shaft protective pillar

Directory of Open Access Journals (Sweden)

Ewa Warchala

2016-01-01

Full Text Available The paper presents an analysis of the rock mass deformation resulting from mining in the vicinity of the shaft protection pillar. A methodology of deformation prediction is based on a deterministic method using Finite Element Method (FEM. The FEM solution is based on the knowledge of the geomechanical properties of the various geological formations, tectonic faults, types of mining systems, and the complexity of the behaviour of the rock mass. The analysis gave the stress and displacement fields in the rock mass. Results of the analysis will allow for design of an optimal mining system. The analysis is illustrated by an example of the shaft R-VIII Rudna Mine KGHM Polish Copper SA.
Microbial O2 consumption in the Aespoe tunnel

International Nuclear Information System (INIS)

Kotelnikova, S.; Pedersen, Karsten

1998-04-01

The report presents data on microbial O 2 reduction activities by microorganisms obtained with different techniques: Winkler method, gas chromatography, most probable numbering, enrichment technique, inhibitor analysis and radiotracer measurements. The samples were collected from boreholes and open funnel ponds at Aespoe in 1996-1998. The evaluation of the microbial activities in open ponds predicts the future microbial activities after the O 2 intrusion around the future repository. The metabolic potential of the microbial population inhabiting groundwater was evaluated on the basis of electron donors available and microbial 16S rRNA gene diversity. The contribution of different microbial groups to the O 2 reduction was elucidated using specific inhibitors selectively affecting different microbial groups. Our experiments show that microbial O 2 reduction occurs in deep groundwater. Carbon dioxide was produced concurrently with O 2 reduction confirming the biogenic nature of the reduction. The populations developed O 2 reduction rates and capacity depending on the initial concentration of dissolved O 2 reduction. Rates of O 2 reduction ranged from 0.32 to 4.5 μM/day. Depending on temperature and the type of groundwater the approximate time needed for consumption of 500 μM of dissolved O 2 ranged from 0.31 to 3.99 years. After approximately a 2 weeks period the microbial population in vitro was able to consume O 2 both at 30 deg C and 60 deg C. At 16 deg C no delay in O 2 consumption was observed. Our results demonstrated that methanotrophs survive in deep groundwater and that they were induced by O 2 . Some bacteria use Hg or CH 4 as electron donor instead of organic matter, which means that microbial O 2 reduction will occur also in deep groundwaters where the availability of organic carbon is limited. Specific CH 4 oxidation rates ranged between 3.00 and 220 nM CH 4 per litre per day. Comparison of the total O 2 reducing activities by gas chromatography and
Evaporation-driven clustering of microscale pillars and lamellae

Energy Technology Data Exchange (ETDEWEB)

Kim, Tae-Hong; Kim, Jungchul; Kim, Ho-Young, E-mail: hyk@snu.ac.kr [Department of Mechanical and Aerospace Engineering, Seoul National University, Seoul 08826 (Korea, Republic of)

2016-02-15

As a liquid film covering an array of micro- or nanoscale pillars or lamellae evaporates, its meniscus pulls the elastic patterns together because of capillary effects, leading to clustering of the slender microstructures. While this elastocapillary coalescence may imply various useful applications, it is detrimental to a semiconductor manufacturing process called the spin drying, where a liquid film rinses patterned wafers until drying. To understand the transient mechanism underlying such self-organization during and after liquid evaporation, we visualize the clustering dynamics of polymer micropatterns. Our visualization experiments reveal that the patterns clumped during liquid evaporation can be re-separated when completely dried in some cases. This restoration behavior is explained by considering adhesion energy of the patterns as well as capillary forces, which leads to a regime map to predict whether permanent stiction would occur. This work does not only extend our understanding of micropattern stiction, but also suggests a novel path to control and prevent pattern clustering.
Synthesis of pillar and microsphere-like magnesium oxide particles and their fluoride adsorption performance in aqueous solutions

Energy Technology Data Exchange (ETDEWEB)

Lee, Sang Gool; Ha, Jong-Wook; Sohn, Eun-Ho; Park, In Jun; Lee, Soo-Bok [Korea Research Institute of Chemical Technology, Daejeon (Korea, Republic of)

2017-10-15

We synthesized pillar and microsphere-like MgO particles and their fluoride removal performance. Samples of MgO were synthesized by calcination of precursors derived from MgCO{sub 3}·3H{sub 2}O and characterized using field emission scanning electron microscopy, X-ray diffraction, and N{sub 2} adsorption-desorption isotherms. The fluoride removal performance of the MgO samples was investigated in terms of adsorption kinetics and adsorption equilibrium. The effects of pH and the presence of other anions on the fluoride adsorption were also considered. The adsorption capacities of pillar and microsphere-like MgO particles were 151.51 and 166.66mg/g, respectively. The pH of the aqueous solutions did not significantly affect the fluoride adsorption at pH 9 or lower. Except for phosphate, the effect of co-existing anions on fluoride adsorption was not considerable. Fluoride removal occurred through the substitution of hydroxyl groups on the surface of MgO with fluorides.
Electrolytic Manganese Dioxide Coatings on High Aspect Ratio Micro-Pillar Arrays for 3D Thin Film Lithium Ion Batteries

Directory of Open Access Journals (Sweden)

Yafa Zargouni

2017-05-01

Full Text Available In this work, we present the electrochemical deposition of manganese dioxide (MnO2 thin films on carbon-coated TiN/Si micro-pillars. The carbon buffer layer, grown by plasma enhanced chemical vapor deposition (PECVD, is used as a protective coating for the underlying TiN current collector from oxidation, during the film deposition, while improving the electrical conductivity of the stack. A conformal electrolytic MnO2 (EMD coating is successfully achieved on high aspect ratio C/TiN/Si pillar arrays by tailoring the deposition process. Lithiation/Delithiation cycling tests have been performed. Reversible insertion and extraction of Li+ through EMD structure are observed. The fabricated stack is thus considered as a good candidate not only for 3D micorbatteries but also for other energy storage applications.
Electrolytic Manganese Dioxide Coatings on High Aspect Ratio Micro-Pillar Arrays for 3D Thin Film Lithium Ion Batteries.

Science.gov (United States)

Zargouni, Yafa; Deheryan, Stella; Radisic, Alex; Alouani, Khaled; Vereecken, Philippe M

2017-05-27

In this work, we present the electrochemical deposition of manganese dioxide (MnO₂) thin films on carbon-coated TiN/Si micro-pillars. The carbon buffer layer, grown by plasma enhanced chemical vapor deposition (PECVD), is used as a protective coating for the underlying TiN current collector from oxidation, during the film deposition, while improving the electrical conductivity of the stack. A conformal electrolytic MnO₂ (EMD) coating is successfully achieved on high aspect ratio C/TiN/Si pillar arrays by tailoring the deposition process. Lithiation/Delithiation cycling tests have been performed. Reversible insertion and extraction of Li⁺ through EMD structure are observed. The fabricated stack is thus considered as a good candidate not only for 3D micorbatteries but also for other energy storage applications.
A case study of multi-seam coal mine entry stability analysis with strength reduction method.

Science.gov (United States)

Tulu, Ihsan Berk; Esterhuizen, Gabriel S; Klemetti, Ted; Murphy, Michael M; Sumner, James; Sloan, Michael

2016-03-01

In this paper, the advantage of using numerical models with the strength reduction method (SRM) to evaluate entry stability in complex multiple-seam conditions is demonstrated. A coal mine under variable topography from the Central Appalachian region is used as a case study. At this mine, unexpected roof conditions were encountered during development below previously mined panels. Stress mapping and observation of ground conditions were used to quantify the success of entry support systems in three room-and-pillar panels. Numerical model analyses were initially conducted to estimate the stresses induced by the multiple-seam mining at the locations of the affected entries. The SRM was used to quantify the stability factor of the supported roof of the entries at selected locations. The SRM-calculated stability factors were compared with observations made during the site visits, and the results demonstrate that the SRM adequately identifies the unexpected roof conditions in this complex case. It is concluded that the SRM can be used to effectively evaluate the likely success of roof supports and the stability condition of entries in coal mines.
Teaching population health and community-based care across diverse clinical experiences: integration of conceptual pillars and constructivist learning.

Science.gov (United States)

Valentine-Maher, Sarah K; Van Dyk, Elizabeth J; Aktan, Nadine M; Bliss, Julie Beshore

2014-03-01

Nursing programs are challenged to prepare future nurses to provide care and affect determinants of health for individuals and populations. This article advances a pedagogical model for clinical education that builds concepts related to both population-level care and direct care in the community through a contextual learning approach. Because the conceptual pillars and hybrid constructivist approach allow for conceptual learning consistency across experiences, the model expands programmatic capacity to use diverse community clinical sites that accept only small numbers of students. The concept-based and hybrid constructivist learning approach is expected to contribute to the development of broad intellectual skills and lifelong learning. The pillar concepts include determinants of health and nursing care of population aggregates; direct care, based on evidence and best practices; appreciation of lived experience of health and illness; public health nursing roles and relationship to ethical and professional formation; and multidisciplinary collaboration. Copyright 2014, SLACK Incorporated.
Rock mechanical conditions at the Aespoe HRL. A study of the correlation between geology, tunnel maintenance and tunnel shape

International Nuclear Information System (INIS)

Andersson, Christer; Soederhaell, Joergen

2001-12-01

Maintenance records including scaling, shotcreting and bolting have been kept since the excavation start of Aespoe HRL 1990 together with records of groundwater flow and all other activities taking place in the tunnels. When the facility was constructed one objective was to limit the rock support as much as possible. The reason for this was that it should be possible to go back and easily study the exposed rock surface. Support during the operational phase has only been carried out where and when necessary. This type of maintenance and its location is documented in the digital database each time. The maintenance records have been compiled and areas requiring more maintenance than average noted. An interview has also been held with one of the miners conducting scaling and bolting in the tunnel. His experiences together with the study of the database maintenance records led to the selection of certain areas in the tunnel to be studied by numerical modelling. The probable reason for the need of additional maintenance in all areas, not only these numerically modelled, has been investigated. Almost all maintenance in the main tunnel both during construction and the operational phase has been located in the widened curves of the access tunnel. The maintenance is also located in areas containing veins or intrusions of Smaaland granite or fine-grained granite. These areas are often located in fracture zones of different sizes or show an increasing fracture frequency. The areas numerically modelled indicate stress concentrations or unloaded stress conditions. The stress concentrations are created by the geometry of the niches and side-tunnels in relation to the in situ stress field. The angle between the tunnel and the major principal stress has an impact on the need for maintenance. The areas with the largest angles towards the principal stress direction need more maintenance than the areas almost parallel to the major principal stress direction. The maintenance work in
Theoretical Investigations of CO 2 and H 2 Sorption in an Interpenetrated Square-Pillared Metal–Organic Material

KAUST Repository

Pham, Tony; Forrest, Katherine A.; McLaughlin, Keith; Tudor, Brant; Nugent, Patrick; Hogan, Adam; Mullen, Ashley; Cioce, Christian R.; Zaworotko, Michael J.; Space, Brian

2013-01-01

Simulations of CO2 and H2 sorption and separation were performed in [Cu(dpa)2SiF6-i], a metal-organic material (MOM) consisting of an interpenetrated square grid of Cu2+ ions coordinated to 4,4′-dipyridylacetylene (dpa) rings and pillars of SiF6 2
Multiwavelength Imaging Of YSOs With Disk In South Pillars Of Eta Carina

Science.gov (United States)

Reyes, J. A.; Porras, B. A.

2013-04-01

We present multiwavelength imaginery and spectral energy distributions (SEDs) of 15 Young Stellar Objects (YSOs) with disk components lying on the South Pillars region close to Eta Carina (η Car). The SEDs include IR fluxes from 2MASS, IRAC, MSX, AKARI, and MIPS-24 μm, and 1.1 mm flux from AzTEC camera at the ASTE antenna. Millimeter fluxes help to constrain the number of fitted models, which provide the list of physical parameters for the star, the disk and the envelope. We then compare the parameters of the YSOs and their spatial location within the star forming region.

The old pillars of new retailing.

Science.gov (United States)

Berry, L L

2001-04-01

Despite the harsh realities of retailing, the illusion persists that magical tools can help companies overcome the problems of fickle consumers, price-slashing competitors, and mood swings in the economy. Such wishful thinking holds that retailers will thrive if only they communicate better with customers through e-mail, employ hidden cameras to learn how customers make purchase decisions, and analyze scanner data to tailor special offers and manage inventory. But the truth is, there are no quick fixes. In the course of his extensive research on dozens of retailers, Leonard Berry found that the best companies create value for their customers in five interlocking ways. Whether you're running a physical store, a catalog business, an e-commerce site, or a combination of the three, you have to offer your customers superior solutions to their needs, treat them with respect, and connect with them on an emotional level. You also have to set prices fairly and make it easy for people to find what they need, pay for it quickly, and then move on. None of these pillars is new, and each sounds exceedingly simple, but don't be fooled--implementing these axioms in the real world is surprisingly difficult. The author illustrates how some retailers have built successful operations by attending to these commonsense ways of dealing with their customers and how others have failed to do so.
Design and construction of porous metal–organic frameworks based on flexible BPH pillars

International Nuclear Information System (INIS)

Hao, Xiang-Rong; Yang, Guang-sheng; Shao, Kui-Zhan; Su, Zhong-Min; Yuan, Gang; Wang, Xin-Long

2013-01-01

Three metal–organic frameworks (MOFs), [Co 2 (BPDC) 2 (4-BPH)·3DMF] n (1), [Cd 2 (BPDC) 2 (4-BPH) 2 ·2DMF] n (2) and [Ni 2 (BDC) 2 (3-BPH) 2 (H 2 O)·4DMF] n (3) (H 2 BPDC=biphenyl-4,4′-dicarboxylic acid, H 2 BDC=terephthalic acid, BPH=bis(pyridinylethylidene)hydrazine and DMF=N,N′-dimethylformamide), have been solvothermally synthesized based on the insertion of heterogeneous BPH pillars. Framework 1 has “single-pillared” MOF-5-like motif with inner cage diameters of up to 18.6 Å. Framework 2 has “double pillared” MOF-5-like motif with cage diameters of 19.2 Å while 3 has “double pillared” 8-connected framework with channel diameters of 11.0 Å. Powder X-ray diffraction (PXRD) shows that 3 is a dynamic porous framework. - Graphical abstract: By insertion of flexible BPH pillars based on “pillaring” strategy, three metal–organic frameworks are obtained showing that the porous frameworks can be constructed in a much greater variety. Highlights: ► Frameworks 1 and 2 have MOF-5 like motif. ► The cube-like cages in 1 and 2 are quite large, comparable to the IRMOF-10. ► Framework 1 is “single-pillared” mode while 2 is “double-pillared” mode. ► PXRD and gas adsorption analysis show that 3 is a dynamic porous framework.
Removal of aqueous Pb(II) by adsorption on Al{sub 2}O{sub 3}-pillared layered MnO{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Zhang, Haipeng; Gu, Liqin; Zhang, Ling; Zheng, Shourong; Wan, Haiqin; Sun, Jingya [State Key Laboratory of Pollution Control and Resource Reuse, Jiangsu Key Laboratory of Vehicle Emissions Control, School of the Environment, Nanjing University, Nanjing 210023 (China); Zhu, Dongqiang [School of Urban and Environmental Sciences, Peking University, Beijing 100871 (China); Xu, Zhaoyi, E-mail: zhaoyixu@nju.edu.cn [State Key Laboratory of Pollution Control and Resource Reuse, Jiangsu Key Laboratory of Vehicle Emissions Control, School of the Environment, Nanjing University, Nanjing 210023 (China)

2017-06-01

Highlights: • Al{sub 2}O{sub 3}-pillared layered MnO{sub 2} (p-MnO{sub 2}) was prepared from δ-MnO{sub 2} precursor. • p-MnO{sub 2} showed markedly higher Pb(II) adsorption capacity than pristine δ-MnO{sub 2.}. • Pillaring of Al{sub 2}O{sub 3} into the layer of δ-MnO{sub 2} enhanced the Pb(II) adsorption. - Abstract: In the present study, Al{sub 2}O{sub 3}-pillared layered MnO{sub 2} (p-MnO{sub 2}) was synthesized using δ-MnO{sub 2} as precursor and Pb(II) adsorption on p-MnO{sub 2} and δ-MnO{sub 2} was investigated. To clarify the adsorption mechanism, Al{sub 2}O{sub 3} was also prepared as an additional sorbent. The adsorbents were characterized by X-ray fluorescence analysis, powder X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy and N{sub 2} adsorption-desorption. Results showed that in comparison with pristine δ-MnO{sub 2}, Al{sub 2}O{sub 3} pillaring led to increased BET surface area of 166.3 m{sup 2} g{sup −1} and enlarged basal spacing of 0.85 nm. Accordingly, p-MnO{sub 2} exhibited a higher adsorption capacity of Pb(II) than δ-MnO{sub 2}. The adsorption isotherms of Pb(II) on δ-MnO{sub 2} and Al{sub 2}O{sub 3} pillar fitted well to the Freundlich model, while the adsorption isotherm of Pb(II) on p-MnO{sub 2} could be well described using a dual-adsorption model, attributed to Pb(II) adsorption on both δ-MnO{sub 2} and Al{sub 2}O{sub 3}. Additionally, Pb(II) adsorption on δ-MnO{sub 2} and p-MnO{sub 2} followed the pseudo second-order kinetics, and a lower adsorption rate was observed on p-MnO{sub 2} than δ-MnO{sub 2}. The Pb(II) adsorption capacity of p-MnO{sub 2} increased with solution pH and co-existing cation concentration, and the presence of dissolved humic acid (10.2 mg L{sup −1}) did not markedly impact Pb(II) adsorption. p-MnO{sub 2} also displayed good adsorption capacities for aqueous Cu(II) and Cd(II). Findings in this study indicate that p-MnO{sub 2} could be used as a highly effective
Four pillars of radio astronomy Mills, Christiansen, Wild, Bracewell

CERN Document Server

Frater, R H; Wendt, H W

2017-01-01

This is the story of Bernie Mills, Chris Christiansen, Paul Wild and Ron Bracewell, members of a team of radio astronomers that would lead Australia, and the world, into this new field of research. Each of the four is remembered for his remarkable work: Mills for the development the cross type instrument that now bears his name; Christiansen for the application of rotational synthesis techniques; Wild for the masterful joining of observations and theory to elicit the nature of the solar atmosphere; Bracewell for his contribution to imaging theory. As well, these Four Pillars are remembered for creating a remarkable environment for scientific discovery and for influencing the careers of future generations. Their pursuit of basic science helped pave the way for technological developments in areas ranging from Wi-Fi to sonar to medical imaging to air navigation, and for underpinning the foundations of modern cosmology and astrophysics.
Integrated pillar scatterers for speeding up classification of cell holograms.

Science.gov (United States)

Lugnan, Alessio; Dambre, Joni; Bienstman, Peter

2017-11-27

The computational power required to classify cell holograms is a major limit to the throughput of label-free cell sorting based on digital holographic microscopy. In this work, a simple integrated photonic stage comprising a collection of silica pillar scatterers is proposed as an effective nonlinear mixing interface between the light scattered by a cell and an image sensor. The light processing provided by the photonic stage allows for the use of a simple linear classifier implemented in the electric domain and applied on a limited number of pixels. A proof-of-concept of the presented machine learning technique, which is based on the extreme learning machine (ELM) paradigm, is provided by the classification results on samples generated by 2D FDTD simulations of cells in a microfluidic channel.
Subsidence prediction in Estonia's oil shale mines

International Nuclear Information System (INIS)

Pastarus, J.R.; Toomik, A.

2000-01-01

This paper analysis the stability of the mining blocks in Estonian oil shale mines, where the room-and-pillar mining system is used. The pillars are arranged in a singular grid. The oil shale bed is embedded at the depth of 40-75 m. The processes in overburden rocks and pillars have caused the subsidence of the ground surface. The conditional thickness and sliding rectangle methods performed calculations. The results are presented by conditional thickness contours. Error does not exceed 4%. Model allows determining the parameters of spontaneous collapse of the pillars and surface subsidence. The surface subsidence parameters will be determined by conventional calculation scheme. Proposed method suits for stability analysis, failure prognosis and monitoring. 8 refs
Electrosprayed heterojunction WO{sub 3}/BiVO{sub 4} films with nanotextured pillar structure for enhanced photoelectrochemical water splitting

Energy Technology Data Exchange (ETDEWEB)

Mali, Mukund G.; Yoon, Hyun; Yoon, Sam S., E-mail: skyoon@korea.ac.kr [School of Mechanical Engineering, Korea University, Seoul 136-713 (Korea, Republic of); Kim, Min-woo [School of Mechanical Engineering, Korea University, Seoul 136-713 (Korea, Republic of); Green School, Korea University, Seoul 136-713 (Korea, Republic of); Swihart, Mark T. [Department of Chemistry and Biological Engineering, University at Buffalo (SUNY), Buffalo, New York 14260 (United States); Al-Deyab, Salem S. [Department of Chemistry, College of Science, King Saud University, Riyadh 11451 (Saudi Arabia)

2015-04-13

We demonstrate that the addition of a tungsten oxide (WO{sub 3}) layer beneath a bismuth vanadate (BiVO{sub 4}) photocatalyst layer with a nanotextured pillar morphology significantly increases the photocurrent density in photoelectrochemical water splitting. The WO{sub 3}-BiVO{sub 4} bilayer films produced a photocurrent of up to 3.3 mA/cm{sup 2} under illumination at 100 mW/cm{sup 2} (AM1.5 spectrum). The bilayer film was characterized by scanning electron microscopy, X-ray diffraction, and photoelectrochemical methods, which confirmed the superiority of the bilayer film in terms of its morphology and charge separation and transport ability. Both WO{sub 3} and BiVO{sub 4} were deposited by electrostatic spraying under open-air conditions, which resulted in nanotextured pillars of BiVO{sub 4} atop a smooth WO{sub 3} film. The optimal coating conditions are also reported.
The Effect of Mining Activity on the Surface in the Safety Shaft Pillar Area of Mayrau Mine

Czech Academy of Sciences Publication Activity Database

Živor, Roman; Klos, Pavel; Pechoč, Jiří; Brož, Milan

M-24(340) (2002), s. 227-235 ISSN 0138-015X. [Polish-Czech-Slovakian Symposium on Mining Geophysics /28./. Niedzica, 11.06.2001-13.06.2001] R&D Projects: GA AV ČR IBS3086005 Institutional research plan: CEZ:AV0Z3046908 Keywords : shaft pillar * mining * surface subsidence Subject RIV: DH - Mining, incl. Coal Mining
Analysis of the situation in the textile industry in Мacedonia through four quality pillars

OpenAIRE

Mitreva, Elizabeta; Risteski, Sanja; Srebrenkoska, Vineta; Lazarevski, Ilija

2016-01-01

In this paper is elaborated and confirmed the need of projection and implementation of total quality management (TQM) system within Macedonian textile factories. Quality should be required not only in the production process, but in all parts of the business processes, even in the way the employees behave. An analysis is made on the situation in the textile industry in Macedonia and its progress through the four quality pillars: internal standardization, statistical process control appliance, ...
Verification of the fulfilment of the purposes of Basel II, Pillar 3 through application of the web log mining methods

Directory of Open Access Journals (Sweden)

M. Munk

2012-01-01

Full Text Available The objective of the paper is the verification of the fulfilment of the purposes of Basel II, Pillar 3 – market discipline during the recent financial crisis. The objective of the paper is to describe the current state of the working out of the project that is focused on the analysis of the market participants’ interest in mandatory disclosure of financial information by a commercial bank by means of advanced methods of web log mining. The output of the realized project will be the verification of the assumptions related to the purposes of Basel III by means of the web mining methods, the recommendations for possible reduction of mandatory disclosure of information under Basel II and III, the proposal of the methodology for data preparation for web log mining in this application domain and the generalised procedure for users’ behaviour modelling dependent on time. The schedule of the project has been divided into three phases. The paper deals with its first phase that is focusing on the data pre-processing, analysis and evaluation of the required information under Basel II, Pillar 3 since 2008 and its disclosure into the web site of a commercial bank. The authors introduce the methodologies for data preparation and known heuristic methods for path completion into web log files with respect to the particularity of investigated application domain. They propose scientific methods for modelling users’ behaviour of the webpages related to Pillar 3 with respect to time.
Construction experiences from underground works at Oskarshamn. Compilation report

International Nuclear Information System (INIS)

Carlsson, Anders; Christiansson, Rolf

2007-12-01

The main objective with this report is to compile experiences from the underground works carried out at Oskarshamn, primarily construction experiences from the tunnelling of the cooling water tunnels of the Oskarshamn nuclear power units 1,2 and 3, from the underground excavations of Clab 1 and 2 (Central Interim Storage Facility for Spent Nuclear Fuel), and Aespoe Hard Rock Laboratory. In addition, an account is given of the operational experience of Clab 1 and 2 and of the Aespoe HRL on primarily scaling and rock support solutions. This report, as being a compilation report, is in its substance based on earlier published material as presented in the list of references. Approximately 8,000 m of tunnels including three major rock caverns with a total volume of about 550,000 m 3 have been excavated. The excavation works of the various tunnels and rock caverns were carried out during the period of 1966-2000. In addition, minor excavation works were carried out at the Aespoe HRL in 2003. The depth location of the underground structures varies from near surface down to 450 m. As an overall conclusion it may be said that the rock mass conditions in the area are well suited for underground construction. This conclusion is supported by the experiences from the rock excavation works in the Simpevarp and Aespoe area. These works have shown that no major problems occurred during the excavation works; nor have any stability or other rock engineering problems of significance been identified after the commissioning of the Oskarshamn nuclear power units O1, O2 and O3, BFA, Clab 1 and 2, and Aespoe Hard Rock Laboratory. The underground structures of these facilities were built according to plan, and since than been operated as planned. Thus, the quality of the rock mass within the construction area is such that it lends itself to excavation of large rock caverns with a minimum of rock support
Construction experiences from underground works at Oskarshamn. Compilation report

Energy Technology Data Exchange (ETDEWEB)

Carlsson, Anders (Vattenfall Power Consultant AB, Stockholm (SE)); Christiansson, Rolf (Swedish Nuclear Fuel and Waste Management Co., Stockholm (SE))

2007-12-15

The main objective with this report is to compile experiences from the underground works carried out at Oskarshamn, primarily construction experiences from the tunnelling of the cooling water tunnels of the Oskarshamn nuclear power units 1,2 and 3, from the underground excavations of Clab 1 and 2 (Central Interim Storage Facility for Spent Nuclear Fuel), and Aespoe Hard Rock Laboratory. In addition, an account is given of the operational experience of Clab 1 and 2 and of the Aespoe HRL on primarily scaling and rock support solutions. This report, as being a compilation report, is in its substance based on earlier published material as presented in the list of references. Approximately 8,000 m of tunnels including three major rock caverns with a total volume of about 550,000 m3 have been excavated. The excavation works of the various tunnels and rock caverns were carried out during the period of 1966-2000. In addition, minor excavation works were carried out at the Aespoe HRL in 2003. The depth location of the underground structures varies from near surface down to 450 m. As an overall conclusion it may be said that the rock mass conditions in the area are well suited for underground construction. This conclusion is supported by the experiences from the rock excavation works in the Simpevarp and Aespoe area. These works have shown that no major problems occurred during the excavation works; nor have any stability or other rock engineering problems of significance been identified after the commissioning of the Oskarshamn nuclear power units O1, O2 and O3, BFA, Clab 1 and 2, and Aespoe Hard Rock Laboratory. The underground structures of these facilities were built according to plan, and since than been operated as planned. Thus, the quality of the rock mass within the construction area is such that it lends itself to excavation of large rock caverns with a minimum of rock support
Microbial O{sub 2} consumption in the Aespoe tunnel

Energy Technology Data Exchange (ETDEWEB)

Kotelnikova, S.; Pedersen, Karsten [Goeteborg Univ. (Sweden). Dept. of Cell and Molecular Biology, Microbiology

1998-04-01

The report presents data on microbial O{sub 2} reduction activities by microorganisms obtained with different techniques: Winkler method, gas chromatography, most probable numbering, enrichment technique, inhibitor analysis and radiotracer measurements. The samples were collected from boreholes and open funnel ponds at Aespoe in 1996-1998. The evaluation of the microbial activities in open ponds predicts the future microbial activities after the O{sub 2} intrusion around the future repository. The metabolic potential of the microbial population inhabiting groundwater was evaluated on the basis of electron donors available and microbial 16S rRNA gene diversity. The contribution of different microbial groups to the O{sub 2} reduction was elucidated using specific inhibitors selectively affecting different microbial groups. Our experiments show that microbial O{sub 2} reduction occurs in deep groundwater. Carbon dioxide was produced concurrently with O{sub 2} reduction confirming the biogenic nature of the reduction. The populations developed O{sub 2} reduction rates and capacity depending on the initial concentration of dissolved O{sub 2} reduction. Rates of O{sub 2} reduction ranged from 0.32 to 4.5 {mu}M/day. Depending on temperature and the type of groundwater the approximate time needed for consumption of 500 {mu}M of dissolved O{sub 2} ranged from 0.31 to 3.99 years. After approximately a 2 weeks period the microbial population in vitro was able to consume O{sub 2} both at 30 deg C and 60 deg C. At 16 deg C no delay in O{sub 2} consumption was observed. Our results demonstrated that methanotrophs survive in deep groundwater and that they were induced by O{sub 2}. Some bacteria use Hg or CH{sub 4} as electron donor instead of organic matter, which means that microbial O{sub 2} reduction will occur also in deep groundwaters where the availability of organic carbon is limited. Specific CH{sub 4} oxidation rates ranged between 3.00 and 220 nM CH{sub 4} per litre per
Investigation of activated Al-pillared clay efficiency in vegetable oil purification

Directory of Open Access Journals (Sweden)

Lomić Gizela A.

2004-01-01

Full Text Available This paper represents a contribution to the applicability of natural clays and their derivates as adsorbents in the process of purification of vegetable oil. Investigation of textural properties of raw and purified clay samples reveals that during acid activation and Al-pillaring, BET and micropore surface area increases significantly. However, bleaching capacity of clay and its derivates is not determined by using sample surface area, but rather sample total pore volume. Surface area, especially micropore surface area contributes to removal of smaller molecules. This was confirmed by successful elimination of moisture and volatile materials by samples with an appropriate micropore structure. Used samples of clay and its derivates do not significantly influence acid and peroxide values of raw sunflower oil during its treatment.
Evaluation of stationary and non-stationary geostatistical models for inferring hydraulic conductivity values at Aespoe

International Nuclear Information System (INIS)

La Pointe, P.R.

1994-11-01

This report describes the comparison of stationary and non-stationary geostatistical models for the purpose of inferring block-scale hydraulic conductivity values from packer tests at Aespoe. The comparison between models is made through the evaluation of cross-validation statistics for three experimental designs. The first experiment consisted of a 'Delete-1' test previously used at Finnsjoen. The second test consisted of 'Delete-10%' and the third test was a 'Delete-50%' test. Preliminary data analysis showed that the 3 m and 30 m packer test data can be treated as a sample from a single population for the purposes of geostatistical analyses. Analysis of the 3 m data does not indicate that there are any systematic statistical changes with depth, rock type, fracture zone vs non-fracture zone or other mappable factor. Directional variograms are ambiguous to interpret due to the clustered nature of the data, but do not show any obvious anisotropy that should be accounted for in geostatistical analysis. Stationary analysis suggested that there exists a sizeable spatially uncorrelated component ('Nugget Effect') in the 3 m data, on the order of 60% of the observed variance for the various models fitted. Four different nested models were automatically fit to the data. Results for all models in terms of cross-validation statistics were very similar for the first set of validation tests. Non-stationary analysis established that both the order of drift and the order of the intrinsic random functions is low. This study also suggests that conventional cross-validation studies and automatic variogram fitting are not necessarily evaluating how well a model will infer block scale hydraulic conductivity values. 20 refs, 20 figs, 14 tabs
Ensuring Support for Research and Quality Improvement (QI) Networks: Four Pillars of Sustainability?An Emerging Framework

OpenAIRE

Holve, Erin

2013-01-01

Multi-institutional research and quality improvement (QI) projects using electronic clinical data (ECD) hold great promise for improving quality of care and patient outcomes but typically require significant infrastructure investments both to initiate and maintain the project over its duration. Consequently, it is important for these projects to think holistically about sustainability to ensure their long-term success. Four ?pillars? of sustainability are discussed based on the experiences of...
Effect of PW12–GPK on the acid characteristics of Ni-, Pd- and Pt- catalysts deposited onto pillared Al montmorillonite

Directory of Open Access Journals (Sweden)

D. Zhumadullaev

2012-03-01

Full Text Available Acid characteristics of Ni-, Pd-, Pt- catalyzers , deposited to Al pillared CaH montmorillonite modified by heteropolyacid H3PW12O40·xH2O (PW12 by ammonia thermoadsorbtion method has been studied.
Haiti’s Army, Stabilization and Security Sector Governance

Directory of Open Access Journals (Sweden)

Geoff Burt

2016-09-01

Full Text Available Haiti’s long and difficult security sector reform (SSR process has entered a new phase. The reinstatement of the Haitian armed forces, nearly 20 years after former President Jean-Bertrand Aristide disbanded them, adds a new set of actors and more complexity to a process already struggling to deliver results amidst a seemingly endless series of political crises. The armed forces must be an impartial and apolitical institution if they are to contribute to stability in Haiti – an uncertain proposition given their past inability to stay out of the political arena. Building on a summary of the latest developments in the reinstatement process, this paper discusses its implications for Haiti’s prolonged international engagement. In particular, the paper focuses on the process to develop a new White Paper on Defence and National Security in Haiti. This process has the potential to contribute to two of the most significant shortcomings of SSR in Haiti, a limited focus on security sector governance and a lack of local ownership. The reinstatement process has been an interesting test case of the international donor community’s commitment to the concept of local ownership, long held to be a moral and practical pillar of international engagement. Though reinstatement has been driven by Haitian authorities, the process has struggled to make progress without donor support, raising questions about the appropriate role of international actors in strategic decision-making at the national level. Regardless of their initial reaction to reinstatement, Haiti’s international donors risk missing an opportunity to influence the development of an important pillar of Haiti’s post-MINUSTAH security sector by choosing to remain on the sidelines.
Effect of greater trochanteric epiphysiodesis after femoral varus osteotomy for lateral pillar classification B and B/C border Legg-Calvé-Perthes disease: A retrospective observational study.

Science.gov (United States)

Kwon, Keun-Sang; Wang, Sung Il; Lee, Ju-Hyung; Moon, Young Jae; Kim, Jung Ryul

2017-08-01

This is a retrospective observational study. Greater trochanteric epiphysiodesis (GTE) has been recommended to prevent Trendelenburg gait and limitation of the hip joint motion due to trochanteric overgrowth after femoral varus osteotomy (FVO) in Legg-Calvé-Perthes disease (LCPD). However, capital femoral physeal arrest frequently occurs in patients with severe disease (lateral pillar C), so GTE might not be as effective in these patients. The aim of this study was to compare trochanteric growth inhibition due to GTE after FVO between 2 age groups (8 years) in patients with lateral pillar B and B/C border LCPD and evaluate the effectiveness of GTE compared with the normal, unaffected hip.This study included 19 children with lateral pillar B and B/C border LCPD in 1 leg who underwent FVO followed by GTE. Of the 19 children, 9 underwent GTE before the age of 8 years and 10 underwent GTE after 8 years of age. On radiographs taken at the immediate postoperative period and at skeletal maturity, the articulo-trochanteric distance (ATD), center-trochanteric distance (CTD), and neck-shaft angle (NSA) were compared between the 2 age groups. The amount of correction was compared between groups. The contralateral, unaffected hip was used as a control for trochanteric growth. The patients were clinically evaluated with Iowa hip score at the final follow-up.There was no significant difference between the 2 age groups in terms of time to GTE, length of follow-up, or lateral pillar classification. In the affected hip, the amount of correction of the ATD, CTD, and NSA was significantly greater in patients 8 years. However, in the unaffected hip, the change in the ATD, CTD, and NSA did not differ significantly between the 2 groups.We suggest that FVO followed by GTE for lateral pillar B and B/C border LCPD in patients under the age of 8 years can affect growth of the greater trochanter. However, effective growth inhibition due to GTE was not achieved after 8 years of age.
Synthesis of titania modified silica-pillared clay (SPC) with highly ordered interlayered mesoporous structure for removing toxic metal ion Cr(VI) from aqueous state

International Nuclear Information System (INIS)

Mao, Huihui; Zhu, Kongnan; Li, Baoshan; Yao, Chao; Kong, Yong

2014-01-01

Titanium-functionalized silica-pillared clays synthesized through post synthetic route was utilized as adsorbers for the removal of Cr(VI) ions from aqueous solutions under different temperatures and initial concentrations. The starting mesostructured silica-pillared clay is assembled by intragallery ammonia-catalyzed hydrolysis of tetraethoxysilane using cationic surfactant as gallery template, and subsequently, the formed interlayered pore walls were decorated with nano-sized TiO 2 particle through organic titanium functionalization process. The kind of structural transformation has been confirmed by X-ray diffraction (XRD), nitrogen adsorption–desorption isotherms, Fourier transform infrared (FT-IR) analysis, UV–vis diffuse reflectance spectroscopy (DRS), elemental analysis (XRF), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Such results indicate that most of the grafted titanium species was combined with Si–OH on the surface of gallery pores. By changing the concentration of organic titanium source during synthesis, the porous structure system is effected. Under suitable conditions, these materials exhibit high adsorption capacity and efficiency. Qualitative estimates of the thermodynamic parameters showed that the overall adsorption process is spontaneous (ΔG° 0). The adsorption isotherms of Cr(VI) on titanium-functionalized silica-pillared clay were best fitted by Redlich–Peterson models. Detail results of thermodynamics and kinetics are also presented.

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