WorldWideScience

Sample records for advanced thin ionization

  1. Ionization Modeling Astrophysical Gaseous Structures. I. The Optically Thin Regime

    CERN Document Server

    Churchill, Christopher W; Medina, Amber; Vliet, Jacob R Vander

    2014-01-01

    We present a code for modelling the ionization conditions of optically thin astrophysical gas structures. Given the gas hydrogen density, equilibrium temperature, elemental abundances, and the ionizing spectrum, the code solves the equilibrium ionization fractions and number densities for all ions from hydrogen to zinc. The included processes are photoionization, Auger ionization, direct collisional ionization, excitation auto-ionization, charge exchange ionization, two-body radiative recombination, dielectronic recombination, and charge exchange recombination. The ionizing spectrum can be generalized to include the ultraviolet background (UVB) and/or Starburst99 stellar populations of various masses, ages, metallicities, and distances. The ultimate goal with the code is to provide fast computation of the ionization conditions of gas in N-body + hydrodynamics cosmological simulations, in particular adaptive mesh refinement codes, in order to facilitate absorption line analysis of the simulated gas for compari...

  2. Thin films deposited by laser ablation for the measurement of the ionizing and non-ionizing radiation

    International Nuclear Information System (INIS)

    In this work the obtained results to synthesize thin films of amorphous carbon with incorporated nitrogen and hydrogen are presented, as well as thin films of aluminium oxide using the laser ablation technique. The thin films were exposed to ionizing radiation (gamma rays of a 60 Co source, beta radiation of a 90 Sr source) and a non-ionizing radiation (UV radiation). The obtained results show that it is possible to obtain materials in thin film form with thickness of hundreds of nanometers, which present thermoluminescent response when being irradiated with ionizing radiation and non-ionizing radiation. (Author)

  3. Physics of thin films advances in research and development

    CERN Document Server

    Hass, Georg; Vossen, John L

    2013-01-01

    Physics of Thin Films: Advances in Research and Development, Volume 12 reviews advances that have been made in research and development concerning the physics of thin films. This volume covers a wide range of preparative approaches, physics phenomena, and applications related to thin films. This book is comprised of four chapters and begins with a discussion on metal coatings and protective layers for front surface mirrors used at various angles of incidence from the ultraviolet to the far infrared. Thin-film materials and deposition conditions suitable for minimizing reflectance changes with

  4. Thin Films for Advanced Glazing Applications

    Directory of Open Access Journals (Sweden)

    Ann-Louise Anderson

    2016-09-01

    Full Text Available Functional thin films provide many opportunities for advanced glazing systems. This can be achieved by adding additional functionalities such as self-cleaning or power generation, or alternately by providing energy demand reduction through the management or modulation of solar heat gain or blackbody radiation using spectrally selective films or chromogenic materials. Self-cleaning materials have been generating increasing interest for the past two decades. They may be based on hydrophobic or hydrophilic systems and are often inspired by nature, for example hydrophobic systems based on mimicking the lotus leaf. These materials help to maintain the aesthetic properties of the building, help to maintain a comfortable working environment and in the case of photocatalytic materials, may provide external pollutant remediation. Power generation through window coatings is a relatively new idea and is based around the use of semi-transparent solar cells as windows. In this fashion, energy can be generated whilst also absorbing some solar heat. There is also the possibility, in the case of dye sensitized solar cells, to tune the coloration of the window that provides unheralded external aesthetic possibilities. Materials and coatings for energy demand reduction is highly desirable in an increasingly energy intensive world. We discuss new developments with low emissivity coatings as the need to replace scarce indium becomes more apparent. We go on to discuss thermochromic systems based on vanadium dioxide films. Such systems are dynamic in nature and present a more sophisticated and potentially more beneficial approach to reducing energy demand than static systems such as low emissivity and solar control coatings. The ability to be able to tune some of the material parameters in order to optimize the film performance for a given climate provides exciting opportunities for future technologies. In this article, we review recent progress and challenges in

  5. Cross-Field Current Instabilities in Thin Ionization Layers and the Enhanced Aurora

    Energy Technology Data Exchange (ETDEWEB)

    Jay R. Johnson and Hideo Okuda

    2008-05-20

    Nearly half of the time, auroral displays exhibit thin, bright layers known as \\enhanced aurora." There is a substantial body of evidence that connects these displays with thin, dense, heavy ion layers in the E-region. Based on the spectral characteristics of the enhanced layers, it is believed that they result when wave-particle interaction heats ambient electrons to energies at or just above the 17 eV ionization energy of N2. While there are several possible instabilities that could produce suprathermal electrons in thin layers, there has been no clear theoretical investigation which examines in detail how wave instabilities in the thin ionization layers could develop and produce the suprathermal electrons. We examine instabilities which would occur in thin, dense, heavy ion layers using extensive analytical analysis combined with particle simulations. We analyze a cross field current instability that is found to be strongly unstable in the heavy ion layers. Electrostatic simulations show that substantial heating of the ambient electrons occurs with energization at or above the N2 ionization energy.

  6. Cross-Field Current Instabilities in Thin Ionization Layers and the Enhanced Aurora

    International Nuclear Information System (INIS)

    Nearly half of the time, auroral displays exhibit thin, bright layers known as 'enhanced aurora'. There is a substantial body of evidence that connects these displays with thin, dense, heavy ion layers in the E-region. Based on the spectral characteristics of the enhanced layers, it is believed that they result when wave-particle interaction heats ambient electrons to energies at or just above the 17 eV ionization energy of N2. While there are several possible instabilities that could produce suprathermal electrons in thin layers, there has been no clear theoretical investigation which examines in detail how wave instabilities in the thin ionization layers could develop and produce the suprathermal electrons. We examine instabilities which would occur in thin, dense, heavy ion layers using extensive analytical analysis combined with particle simulations. We analyze a cross field current instability that is found to be strongly unstable in the heavy ion layers. Electrostatic simulations show that substantial heating of the ambient electrons occurs with energization at or above the N2 ionization energy.

  7. Advances in CZTS thin films and nanostructured

    Science.gov (United States)

    Ali, N.; Ahmed, R.; Bakhtiar-Ul-Haq; Shaari, A.

    2015-06-01

    Already published data for the optical band gap (Eg) of thin films and nanostructured copper zinc tin sulphide (CZTS) have been reviewed and combined. The vacuum (physical) and non-vacuum (chemical) processes are focused in the study for band gap comparison. The results are accumulated for thin films and nanostructured in different tables. It is inferred from the re- view that the nanostructured material has plenty of worth by engineering the band gap for capturing the maximum photons from solar spectrum.

  8. Thin film characterisation by advanced X-ray diffraction techniques

    International Nuclear Information System (INIS)

    The Fifth School on X-ray diffraction from polycrystalline materials was devoted to thin film characterization by advanced X-ray diffraction techniques. Twenty contributions are contained in this volume; all twenty are recorded in the INIS Database. X-ray diffraction is known to be a powerful analytical tool for characterizing materials and understanding their structural features. The aim of these articles is to illustrate the fundamental contribution of modern diffraction techniques (grazing incidence, surface analysis, standing waves, etc.) to the characterization of thin and ultra-thin films, which have become important in many advanced technologies

  9. Advances in thin-film solar cells

    CERN Document Server

    Dharmadasa, I M

    2012-01-01

    This book concentrates on the latest developments in our understanding of solid-state device physics. The material presented is mainly experimental and based on CdTe thin-film solar cells. It extends these new findings to CIGS thin-film solar cells and presents a new device design based on graded bandgap multilayer solar cells. This design has been experimentally tested using the well-researched GaAs/AlGaAs system and initial devices have shown impressive device parameters. These devices are capable of absorbing all radiation (UV, visible, and infra-red) within the solar spectrum and combines

  10. Advanced quantification of plutonium ionization potential to support nuclear forensic evaluations by resonance ionization mass spectrometry

    OpenAIRE

    Lensegrav, Craig T.

    2015-01-01

    Approved for public release; distribution is unlimited Ongoing work seeks to apply the technology of resonance ionization mass spectrometry (RIMS) to problems related to nuclear forensics and, in particular, to the analysis and quantification of the debris from nuclear detonations. As part of this effort, modeling and simulation methods are being applied to analyze and predict the potential for ionization by laser excitation of isotopes of both uranium and plutonium. Early work focused on ...

  11. Recent technological advances in thin film solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Ullal, H.S.; Zwelbel, K.; Surek, T.

    1990-03-01

    High-efficiency, low-cost thin film solar cells are an exciting photovoltaic technology option for generating cost-effective electricity in 1995 and beyond. This paper reviews the substantial advances made by several thin film solar cell technologies, namely, amorphous silicon, copper indium diselenide, cadmium telluride, and polycrystalline silicon. Recent examples of utility demonstration projects of these emerging materials are also discussed. 8 refs., 4 figs.

  12. Preface: Advanced Thin Film Developments and Nano Structures

    Institute of Scientific and Technical Information of China (English)

    Ray Y.Lin

    2005-01-01

    @@ In this special issue, we invited a few leading materials researchers to present topics in thin films, coatings, and nano structures. Readers will find most recent developments in topics, including recent advances in hard, tough, and low friction nanocomposite coatings; thin films for coating nanomaterials; electroless plating of silver thin films on porous Al2O3 substrate; CrN/Nano Cr interlayer coatings; nano-structured carbide derived carbon (CDC) films and their tribology; predicting interdiffusion in high-temperature coatings; gallium-catalyzed silica nanowire growth; and corrosion protection properties of organofunctional silanes. Authors are from both national laboratories and academia.

  13. Thin films deposited by laser ablation for the measurement of the ionizing and non-ionizing radiation; Peliculas delgadas depositadas por ablacion laser para la medicion de radiacion ionizante y no ionizante

    Energy Technology Data Exchange (ETDEWEB)

    Villarreal B, J.E.; Escobar A, L.; Camps, E.; Romero, S.; Gonzalez, P.; Salinas, B. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    2001-07-01

    In this work the obtained results to synthesize thin films of amorphous carbon with incorporated nitrogen and hydrogen are presented, as well as thin films of aluminium oxide using the laser ablation technique. The thin films were exposed to ionizing radiation (gamma rays of a {sup 60} Co source, beta radiation of a {sup 90} Sr source) and a non-ionizing radiation (UV radiation). The obtained results show that it is possible to obtain materials in thin film form with thickness of hundreds of nanometers, which present thermoluminescent response when being irradiated with ionizing radiation and non-ionizing radiation. (Author)

  14. Relation between molecule ionization energy, film thickness and morphology of two indandione derivatives thin films

    Science.gov (United States)

    Grzibovskis, Raitis; Vembris, Aivars; Pudzs, Kaspars

    2016-08-01

    Nowadays most organic devices consist of thin (below 100 nm) layers. Information about the morphology and energy levels of thin films at such thickness is essential for the high efficiency devices. In this work we have investigated thin films of 2-(4-[N,N-dimethylamino]-benzylidene)-indene-1,3-dione (DMABI) and 2-(4-(bis(2-(trityloxy)ethyl)amino)benzylidene)-2H-indene-1,3-dione (DMABI-6Ph). DMABI-6Ph is the same DMABI molecule with attached bulky groups which assist formation of amorphous films from solutions. Polycrystalline structure was obtained for the DMABI thin films prepared by thermal evaporation in vacuum and amorphous structure for the DMABI-6Ph films prepared by spin-coating method. Images taken by SEM showed separate crystals or islands at the thickness of the samples below 100 nm. The ionization energy of the studied compounds was determined using photoemission yield spectroscopy. A vacuum level shift of 0.40 eV was observed when ITO electrode was covered with the thin film of the organic compound. Despite of the same active part of the investigated molecules the ITO/DMABI interface is blocking electrons while ITO/DMABI-6Ph interface is blocking holes.

  15. Electronic properties of ion implanted crystalline polymer thin film deposited by ionized cluster beam

    International Nuclear Information System (INIS)

    Polyethylene thin film deposited by the ionized cluster beam deposition technique shows preferential crystal orientation at optimum deposit condition, and the lattice parameters of the crystalline PE film are in good agreement with those of the single crystal PE. The crystalline PE film reveals that the number of side chains is reduced. The conductivity of Li+, Na+ and K+ implanted crystalline PE films has a close correlation with defects generated by ion irradiation, and the conduction mechanism turns out to be the one-dimensional hopping conduction. (orig.)

  16. Advances in small intestinal ionizing radiation injury research

    International Nuclear Information System (INIS)

    Intestinal ionising radiation injuries are a dose limiting factor in the course of radiotherapy of abdominal and pelvic malignancies. In this paper it is reviewed that ionizing radiation injuries of small intestine,including clinical symptoms, epithelium and submucosa changes, signal molecular expression changes, histological and ultrastructure changes. The ongoing works of our laboratory on subjects of intestinal injuries induced by heavy ions and protection against these injuries are also presented. (authors)

  17. Development of thin gaseous ionization detectors for measurements of high-energy hadron beams

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Kyong Sei; Hong, Byung Sik; Lee, Ki Soo; Park, Sung Keun; Yu, Jae Hee [Korea University, Seoul (Korea, Republic of); Kim, Sang Yeol [NoticeKorea, Anyang (Korea, Republic of)

    2014-04-15

    Thin gaseous ionization detectors have been developed based on a current-integration mode for measurements of high-energy hadron beams. In the present detector R and D, two different types of prototype detectors with an active area of 16 x 16 cm{sup 2}, each equipped with 256-signal processing channels, were manufactured and tested with 43-MeV protons provided by the MC50 proton cyclotron at the Korea Institute of Radiological and Medical Science (KIRAMS). The first one was equipped with a single gas electron multiplier (GEM), and the second one was a thin-plane ionization detector without the GEM foil loaded. The linearities of the detector responses for both detectors were examined for various proton-beam intensities. The quantitative accuracies for the channel-response data and for the total detector responses measured for 43-MeV protons were 0.4% and 0.34%, respectively. We conclude from the beam test that operating both types of detectors in the current-integration mode will allow quality measurements of dynamic-mode hadron beams to be performed with accuracies of better than 1%.

  18. Thin-layer chromatography with flame ionization detection in the characterization of pitches

    Energy Technology Data Exchange (ETDEWEB)

    Cebolla, V.L.; Membrado, L.; Vela, J. [Instituto de Carboquimica, Zaragoza (Spain)] [and others

    1995-12-31

    TLC-FID is a rapid, quality-control oriented technique which joins the advantages of Thin-Layer (TLC) with the possibility of quantification of the separated peaks using a Flame Ionization Detector (FID). In the case of heavy fossil fuels, group-type analysis can be achieved with the possibility of a direct quantification of heavy/polar groups, without any preseparation, and in short analysis times with regard to the current techniques. However, although TLC-FID has been used since the eighties in many fields of Chemistry, results were demonstrated to depend on the technique (analytical system plus methodology) used. This work intends to analyze the fundamental parameters involved in TLC-FID technique using adequate technology and methodology, and to lay the groundwork for a correct group-type characterization of pitches.

  19. Investigation of thin ZnO layers in view of laser desorption-ionization

    Science.gov (United States)

    Grechnikov, A. A.; Georgieva, V. B.; Alimpiev, S. S.; Borodkov, A. S.; Nikiforov, S. M.; Simanovsky, Ya O.; Dimova-Malinovska, D.; Angelov, O. I.

    2010-04-01

    Thin zinc oxide films (ZnO) were developed as a matrix-free platform for surface assisted laser desorption-ionization (SALDI) time-of-flight mass spectrometry. The ZnO films were deposited by RF magnetron sputtering of ZnO ceramic targets in Ar atmospheres on monocrystalline silicon. The generation under UV (355 nm) laser irradiation of positive ions of atenolol, reserpine and gramicidin S from the ZnO layers deposited was studied. All analytes tested were detected as protonated molecules with no or very structure-specific fragmentation. The mass spectra obtained showed low levels of chemical background noise. All ZnO films studied exhibited high stability and good reproducibility. The detection limits for test analytes are in the 10 femtomol range.

  20. Molecular Ionization-Desorption Analysis Source (MIDAS) for Mass Spectrometry: Thin-Layer Chromatography

    Science.gov (United States)

    Winter, Gregory T.; Wilhide, Joshua A.; LaCourse, William R.

    2016-02-01

    Molecular ionization-desorption analysis source (MIDAS), which is a desorption atmospheric pressure chemical ionization (DAPCI) type source, for mass spectrometry has been developed as a multi-functional platform for the direct sampling of surfaces. In this article, its utility for the analysis of thin-layer chromatography (TLC) plates is highlighted. Amino acids, which are difficult to visualize without staining reagents or charring, were detected and identified directly from a TLC plate. To demonstrate the full potential of MIDAS, all active ingredients from an analgesic tablet, separated on a TLC plate, were successfully detected using both positive and negative ion modes. The identity of each of the compounds was confirmed from their mass spectra and compared against standards. Post separation, the chemical signal (blue permanent marker) as reference marks placed at the origin and solvent front were used to calculate retention factor (Rf) values from the resulting ion chromatogram. The quantitative capabilities of the device were exhibited by scanning caffeine spots on a TLC plate of increasing sample amount. A linear curve based on peak are, R2 = 0.994, was generated for seven spots ranging from 50 to 1000 ng of caffeine per spot.

  1. Adsorption of Emerging Ionizable Contaminants on Carbon Nanotubes: Advancements and Challenges.

    Science.gov (United States)

    Ma, Xingmao; Agarwal, Sarang

    2016-01-01

    The superior adsorption capacity of carbon nanotubes has been well recognized and there is a wealth of information in the literature concerning the adsorption of unionized organic pollutants on carbon nanotubes. Recently, the adsorption of emerging environmental pollutants, most of which are ionizable, has attracted increasing attention due to the heightened concerns about the accumulation of these emerging contaminants in the environment. These recent studies suggest that the adsorption of emerging ionizable contaminants on carbon nanotubes exhibit different characteristics than unionized ones. For example, a new charge-assisted intermolecular force has been proposed for ionizable compounds because some adsorption phenomenon cannot be easily explained by the conventional force theory. The adsorption of ionizable compounds also displayed much stronger dependence on solution pH and ionic strength than unionized compounds. This article aims to present a brief review on the current understanding of the adsorption of emerging ionizable contaminants to carbon nanotubes and discuss further research needs required to advance the mechanistic understanding of the interactions between ionizable contaminants and carbon nanotubes. PMID:27187338

  2. Adsorption of Emerging Ionizable Contaminants on Carbon Nanotubes: Advancements and Challenges

    Directory of Open Access Journals (Sweden)

    Xingmao Ma

    2016-05-01

    Full Text Available The superior adsorption capacity of carbon nanotubes has been well recognized and there is a wealth of information in the literature concerning the adsorption of unionized organic pollutants on carbon nanotubes. Recently, the adsorption of emerging environmental pollutants, most of which are ionizable, has attracted increasing attention due to the heightened concerns about the accumulation of these emerging contaminants in the environment. These recent studies suggest that the adsorption of emerging ionizable contaminants on carbon nanotubes exhibit different characteristics than unionized ones. For example, a new charge-assisted intermolecular force has been proposed for ionizable compounds because some adsorption phenomenon cannot be easily explained by the conventional force theory. The adsorption of ionizable compounds also displayed much stronger dependence on solution pH and ionic strength than unionized compounds. This article aims to present a brief review on the current understanding of the adsorption of emerging ionizable contaminants to carbon nanotubes and discuss further research needs required to advance the mechanistic understanding of the interactions between ionizable contaminants and carbon nanotubes.

  3. Thin-Layer Chromatography/Desorption Electrospray Ionization Mass Spectrometry: Investigation of Goldenseal Alkaloids

    Energy Technology Data Exchange (ETDEWEB)

    Van Berkel, Gary J [ORNL; Tomkins, Bruce A [ORNL; Kertesz, Vilmos [ORNL

    2007-01-01

    Desorption electrospray ionization mass spectrometry was investigated as a means to qualitatively identify and to quantify analytes directly from developed normal-phase thin layer chromatography plates. The atmospheric sampling capillary of a commercial ion trap mass spectrometer was extended to permit sampling and ionization of analytes in bands separated on intact TLC plates (up to 10 cm x 10 cm). A surface positioning software package and the appropriate hardware enabled computer-controlled surface scanning along the length of development lanes or at fixed RF value across the plates versus the stationary desorption electrospray emitter. Goldenseal (Hydrastis canadensis) and related alkaloids and commercial dietary supplements were used as standards and samples. Alkaloid standards and samples were spotted and separated on aluminum- or glass-backed plates using established literature methods. The mass spectral signal levels as a function of desorption spray solvent were investigated with acetonitrile proving superior to methanol. The detection levels (ca. 5 ng each or 14 -28 pmol) in mass spectral full scan mode were determined statistically from the calibration curves (2.5 - 100 pmol) for the standards berberine, palmatine and hydrastinine spotted as a mixture and separated on the plates. Qualitative screening of the major alkaloids present in six different over-the-counter "goldenseal" dietary supplements was accomplished by obtaining full scan mass spectra during surface scans along the development lane in the direction of increasing RF value. In one sample, alkaloids were detected that strongly suggested the presence of at least one additional herb undeclared on the product label. These same data indicated the misidentification of one of the alkaloids in the TLC literature. Quantities of the alkaloids present in two of the samples determined using the mass spectral data were in reasonable agreement with the label values indicating the quantitative ability of

  4. Grain growth in thin Al films during deposition from partially ionized vapor

    Science.gov (United States)

    Gusev, I. V.; Mokhniuk, A. A.

    2016-07-01

    Grain growth in thin Al films during deposition from partially ionized vapor flux with simultaneous self-ion bombardment was studied in this work. The films were deposited at constant ion energy of 940 eV and total specific power of 0.4 W/cm2 while the deposition time t of 6 s to 246 s and the resulting substrate temperature (Ts/Tm of 0.35-0.96) were varied. Thin continuous Al films exhibited normal grain growth through the entire experimental range of deposition time without limitation of grain growth by the film thickness effect. Three kinetic stages of the grain growth were observed within 100 s of deposition time: the first one exhibits very slow grain growth, accelerated grain growth occurs in the second stage and then it rapidly changes to a retardation and stagnation mode in the third stage. Large average grain sizes Dg up to 11.3 μm at film thickness of 1.4 μm and integral grain growth rates up to 0.16 μm/s were observed in this study. The experimental results were evaluated against various mechanisms of inhibition of grain growth. An estimate of the effective activation energy of the grain growth yields a value of 0.27 eV which is lower than that of the bulk Al and much higher than the activation energy of surface self-diffusion on (1 1 1)Al monocrystal. The power law Dg = (k t)0.5 gives good match with experimental results in the initial deposition phase preceding the grain growth retardation, while another model that is based on the grain size dependent pinning force adequately explains the entire grain size dependence on time. It is deemed both ion enhanced film/surface interaction and impurities on one side and thermal grooves on another side contribute to the rapid retardation of the grain grooves commencing the second growth stage.

  5. Thin layer chromatography coupled to paper spray ionization mass spectrometry for cocaine and its adulterants analysis.

    Science.gov (United States)

    De Carvalho, Thays C; Tosato, Flavia; Souza, Lindamara M; Santos, Heloa; Merlo, Bianca B; Ortiz, Rafael S; Rodrigues, Rayza R T; Filgueiras, Paulo R; França, Hildegardo S; Augusti, Rodinei; Romão, Wanderson; Vaz, Boniek G

    2016-05-01

    Thin layer chromatography (TLC) is a simple and inexpensive type of chromatography that is extensively used in forensic laboratories for drugs of abuse analysis. In this work, TLC is optimized to analyze cocaine and its adulterants (caffeine, benzocaine, lidocaine and phenacetin) in which the sensitivity (visual determination of LOD from 0.5 to 14mgmL(-1)) and the selectivity (from the study of three different eluents: CHCl3:CH3OH:HCOOHglacial (75:20:5v%), (C2H5)2O:CHCl3 (50:50v%) and CH3OH:NH4OH (100:1.5v%)) were evaluated. Aiming to improve these figures of merit, the TLC spots were identified and quantified (linearity with R(2)>0.98) by the paper spray ionization mass spectrometry (PS-MS), reaching now lower LOD values (>1.0μgmL(-1)). The method developed in this work open up perspective of enhancing the reliability of traditional and routine TLC analysis employed in the criminal expertise units. Higher sensitivity, selectivity and rapidity can be provided in forensic reports, besides the possibility of quantitative analysis. Due to the great simplicity, the PS(+)-MS technique can also be coupled directly to other separation techniques such as the paper chromatography and can still be used in analyses of LSD blotter, documents and synthetic drugs. PMID:26970868

  6. High-throughput analysis of drugs in biological fluids by desorption electrospray ionization mass spectrometry coupled with thin liquid membrane extraction

    DEFF Research Database (Denmark)

    Rosting, Cecilie; Pedersen-Bjergaard, Stig; Hansen, Steen Honore';

    2013-01-01

    Biological fluids such as urine, saliva and whole blood were analyzed for contents of drugs by a new combination of desorption electrospray ionization mass spectrometry (DESI-MS) and thin liquid membrane extraction (TLME). Analytes from the sample were extracted into a thin liquid membrane...

  7. Advances in targetry with thin diamond-like carbon foils

    CERN Document Server

    Liechtenstein, V K; Olshanski, E D; Repnow, R; Levin, J; Hellborg, R; Persson, P; Schenkel, T

    2002-01-01

    Thin and stable diamond-like carbon (DLC) foils, which were fabricated at the Kurchatov Institute by sputter deposition, have proved recently to be advantageous for stripping and secondary electron timing of high energy heavy ions in a number of accelerator experiments. This resulted in expanding applications of these DLC foils which necessitated further development efforts directed toward the following applications of DLC targetry: (i) thin stripper foils for lower energy tandem accelerators, (ii) enlarged (up to 66 mm in diameter) stop foils for improved time-of-flight elastic recoil detection ion beam analysis, and (iii) ultra-thin (about 0.6 mu g/cm sup 2) DLC foils for some fundamental and applied physics experiments. Along with the fabrication of thin DLC stripper foils for tandem accelerators, much thicker (up to 200 mu g/cm sup 2) foils for post-stripping of heavy-ion beams in higher energy linacs, are within reach.

  8. Bias-induced migration of ionized donors in amorphous oxide semiconductor thin-film transistors with full bottom-gate and partial top-gate structures

    Directory of Open Access Journals (Sweden)

    Mallory Mativenga

    2012-09-01

    Full Text Available Bias-induced charge migration in amorphous oxide semiconductor thin-film transistors (TFTs confirmed by overshoots of mobility after bias stressing dual gated TFTs is presented. The overshoots in mobility are reversible and only occur in TFTs with a full bottom-gate (covers the whole channel and partial top-gate (covers only a portion of the channel, indicating a bias-induced uneven distribution of ionized donors: Ionized donors migrate towards the region of the channel that is located underneath the partial top-gate and the decrease in the density of ionized donors in the uncovered portion results in the reversible increase in mobility.

  9. Fabrication and characterization of advanced Organic Thin Film Transistors

    OpenAIRE

    Scaldaferri, Rossana

    2009-01-01

    The thesis aims to the development of Organic Thin Film Transistors and more complex devices based on organic materials. The experimental work demonstrates the possibility to manufacture transistors and more complex circuits with innovative polymers and technologies, leading to an experimental validation of the possibility to realize all-organic devices.

  10. Advances in polycrystalline thin-film photovoltaics for space applications

    Science.gov (United States)

    Lanning, Bruce R.; Armstrong, Joseph H.; Misra, Mohan S.

    1994-01-01

    Polycrystalline, thin-film photovoltaics represent one of the few (if not the only) renewable power sources which has the potential to satisfy the demanding technical requirements for future space applications. The demand in space is for deployable, flexible arrays with high power-to-weight ratios and long-term stability (15-20 years). In addition, there is also the demand that these arrays be produced by scalable, low-cost, high yield, processes. An approach to significantly reduce costs and increase reliability is to interconnect individual cells series via monolithic integration. Both CIS and CdTe semiconductor films are optimum absorber materials for thin-film n-p heterojunction solar cells, having band gaps between 0.9-1.5 ev and demonstrated small area efficiencies, with cadmium sulfide window layers, above 16.5 percent. Both CIS and CdTe polycrystalline thin-film cells have been produced on a laboratory scale by a variety of physical and chemical deposition methods, including evaporation, sputtering, and electrodeposition. Translating laboratory processes which yield these high efficiency, small area cells into the design of a manufacturing process capable of producing 1-sq ft modules, however, requires a quantitative understanding of each individual step in the process and its (each step) effect on overall module performance. With a proper quantification and understanding of material transport and reactivity for each individual step, manufacturing process can be designed that is not 'reactor-specific' and can be controlled intelligently with the design parameters of the process. The objective of this paper is to present an overview of the current efforts at MMC to develop large-scale manufacturing processes for both CIS and CdTe thin-film polycrystalline modules. CIS cells/modules are fabricated in a 'substrate configuration' by physical vapor deposition techniques and CdTe cells/modules are fabricated in a 'superstrate configuration' by wet chemical

  11. Physics of thin films advances in research and development, v.6

    CERN Document Server

    Francombe, Maurice H

    1971-01-01

    Physics of Thin Films: Advances in Research and Development, Volume 6 reviews the rapid progress that has been made in research and development concerning the physics of thin films, with emphasis on metallic films. Topics covered include anodic oxide films, thin metal films and wires, and multilayer magnetic films. This volume is comprised of five chapters and begins with a discussion on the dielectric properties and the technique of plasma anodization which are relevant to the applications of anodic oxide films in electronic devices. Conduction, polarization, and dielectric breakdown effects

  12. Advanced morphological analysis of patterns of thin anodic porous alumina

    International Nuclear Information System (INIS)

    Different conditions of fabrication of thin anodic porous alumina on glass substrates have been explored, obtaining two sets of samples with varying pore density and porosity, respectively. The patterns of pores have been imaged by high resolution scanning electron microscopy and analyzed by innovative methods. The regularity ratio has been extracted from radial profiles of the fast Fourier transforms of the images. Additionally, the Minkowski measures have been calculated. It was first observed that the regularity ratio averaged across all directions is properly corrected by the coefficient previously determined in the literature. Furthermore, the angularly averaged regularity ratio for the thin porous alumina made during short single-step anodizations is lower than that of hexagonal patterns of pores as for thick porous alumina from aluminum electropolishing and two-step anodization. Therefore, the regularity ratio represents a reliable measure of pattern order. At the same time, the lower angular spread of the regularity ratio shows that disordered porous alumina is more isotropic. Within each set, when changing either pore density or porosity, both regularity and isotropy remain rather constant, showing consistent fabrication quality of the experimental patterns. Minor deviations are tentatively discussed with the aid of the Minkowski measures, and the slight decrease in both regularity and isotropy for the final data-points of the porosity set is ascribed to excess pore opening and consequent pore merging. - Highlights: • Thin porous alumina is partly self-ordered and pattern analysis is required. • Regularity ratio is often misused: we fix the averaging and consider its spread. • We also apply the mathematical tool of Minkowski measures, new in this field. • Regularity ratio shows pattern isotropy and Minkowski helps in assessment. • General agreement with perfect artificial patterns confirms the good manufacturing

  13. Advanced morphological analysis of patterns of thin anodic porous alumina

    Energy Technology Data Exchange (ETDEWEB)

    Toccafondi, C. [Istituto Italiano di Tecnologia, Department of Nanophysics, Via Morego 30, Genova I 16163 (Italy); Istituto Italiano di Tecnologia, Department of Nanostructures, Via Morego 30, Genova I 16163 (Italy); Stępniowski, W.J. [Department of Advanced Materials and Technologies, Faculty of Advanced Technologies and Chemistry, Military University of Technology, 2 Kaliskiego Str., 00-908 Warszawa (Poland); Leoncini, M. [Istituto Italiano di Tecnologia, Department of Nanostructures, Via Morego 30, Genova I 16163 (Italy); Salerno, M., E-mail: marco.salerno@iit.it [Istituto Italiano di Tecnologia, Department of Nanophysics, Via Morego 30, Genova I 16163 (Italy)

    2014-08-15

    Different conditions of fabrication of thin anodic porous alumina on glass substrates have been explored, obtaining two sets of samples with varying pore density and porosity, respectively. The patterns of pores have been imaged by high resolution scanning electron microscopy and analyzed by innovative methods. The regularity ratio has been extracted from radial profiles of the fast Fourier transforms of the images. Additionally, the Minkowski measures have been calculated. It was first observed that the regularity ratio averaged across all directions is properly corrected by the coefficient previously determined in the literature. Furthermore, the angularly averaged regularity ratio for the thin porous alumina made during short single-step anodizations is lower than that of hexagonal patterns of pores as for thick porous alumina from aluminum electropolishing and two-step anodization. Therefore, the regularity ratio represents a reliable measure of pattern order. At the same time, the lower angular spread of the regularity ratio shows that disordered porous alumina is more isotropic. Within each set, when changing either pore density or porosity, both regularity and isotropy remain rather constant, showing consistent fabrication quality of the experimental patterns. Minor deviations are tentatively discussed with the aid of the Minkowski measures, and the slight decrease in both regularity and isotropy for the final data-points of the porosity set is ascribed to excess pore opening and consequent pore merging. - Highlights: • Thin porous alumina is partly self-ordered and pattern analysis is required. • Regularity ratio is often misused: we fix the averaging and consider its spread. • We also apply the mathematical tool of Minkowski measures, new in this field. • Regularity ratio shows pattern isotropy and Minkowski helps in assessment. • General agreement with perfect artificial patterns confirms the good manufacturing.

  14. Advanced characterization techniques for thin film solar cells

    CERN Document Server

    Rau, Uwe; Kirchartz, Thomas

    2011-01-01

    Written by scientists from leading institutes in Germany, USA and Spain who use these techniques as the core of their scientific work and who have a precise idea of what is relevant for photovoltaic devices, this text contains concise and comprehensive lecture-like chapters on specific research methods.They focus on emerging, specialized techniques that are new to the field of photovoltaics yet have a proven relevance. However, since new methods need to be judged according to their implications for photovoltaic devices, a clear introductory chapter describes the basic physics of thin-film

  15. Antimicrobial nanospheres thin coatings prepared by advanced pulsed laser technique

    Directory of Open Access Journals (Sweden)

    Alina Maria Holban

    2014-06-01

    Full Text Available We report on the fabrication of thin coatings based on polylactic acid-chitosan-magnetite-eugenol (PLA-CS-Fe3O4@EUG nanospheres by matrix assisted pulsed laser evaporation (MAPLE. Transmission electron microscopy (TEM and scanning electron microscopy (SEM investigation proved that the homogenous Fe3O4@EUG nanoparticles have an average diameter of about 7 nm, while the PLA-CS-Fe3O4@EUG nanospheres diameter sizes range between 20 and 80 nm. These MAPLE-deposited coatings acted as bioactive nanosystems and exhibited a great antimicrobial effect by impairing the adherence and biofilm formation of Staphylococcus aureus (S. aureus and Pseudomonas aeruginosa (P. aeruginosa bacteria strains. Moreover, the obtained nano-coatings showed a good biocompatibility and facilitated the normal development of human endothelial cells. These nanosystems may be used as efficient alternatives in treating and preventing bacterial infections.

  16. Thin film design for advanced thermochromic smart radiator devices

    Institute of Scientific and Technical Information of China (English)

    Feng Yu-Dong; Wang Zhi-Min; Ma Ya-Li; Zhang Fu-Jia

    2007-01-01

    This paper describes the research on the materials and design methods for advanced smart radiator devices (SRDs) on large-area flexible substrates utilized on spacecraft. The functional material is thermochromic vanadium dioxide. The coating design of 3RD is similar to the design of broadband filter coatings in a mid-infrared region. The multilayer coatings have complex structures. Coating materials must be highly transparent in a required spectrum region and also mechanically robust enough to endure the influence from the rigorous environments of outer space. The number of layers must be very small, suitable for the deposition on large-area flexible substrates. All the coatings are designed initially based on optical calculation and practical experience, and then optimized by the TFCALC software. Several designs are described and compared with each other. The results show that the emittance variability of the designed SRDs is great than 400%, more advanced than the reported ones.

  17. Advances in thin-film solar cells for lightweight space photovoltaic power

    Science.gov (United States)

    Landis, Geoffrey A.; Bailey, Sheila G.; Flood, Dennis J.

    1989-01-01

    The present stature and current research directions of photovoltaic arrays as primary power systems for space are reviewed. There have recently been great advances in the technology of thin-film solar cells for terrestrial applications. In a thin-film solar cell the thickness of the active element is only a few microns; transfer of this technology to space arrays could result in ultralow-weight solar arrays with potentially large gains in specific power. Recent advances in thin-film solar cells are reviewed, including polycrystalline copper-indium selenide (CuInSe2) and related I-III-VI2 compounds, polycrystalline cadmium telluride and related II-VI compounds, and amorphous silicon:hydrogen and alloys. The best experimental efficiency on thin-film solar cells to date is 12 percent AMO for CuIn Se2. This efficiency is likely to be increased in the next few years. The radiation tolerance of thin-film materials is far greater than that of single-crystal materials. CuIn Se2 shows no degradation when exposed to 1 MeV electrons. Experimental evidence also suggests that most of all of the radiation damage on thin-films can be removed by a low temperature anneal. The possibility of thin-film multibandgap cascade solar cells is discussed, including the tradeoffs between monolithic and mechanically stacked cells. The best current efficiency for a cascade is 12.5 percent AMO for an amorphous silicon on CuInSe2 multibandgap combination. Higher efficiencies are expected in the future. For several missions, including solar-electric propulsion, a manned Mars mission, and lunar exploration and manufacturing, thin-film photovolatic arrays may be a mission-enabling technology.

  18. Physics of Partially Ionized Plasmas

    Science.gov (United States)

    Krishan, Vinod

    2016-05-01

    Figures; Preface; 1. Partially ionized plasmas here and everywhere; 2. Multifluid description of partially ionized plasmas; 3. Equilibrium of partially ionized plasmas; 4. Waves in partially ionized plasmas; 5. Advanced topics in partially ionized plasmas; 6. Research problems in partially ionized plasmas; Supplementary matter; Index.

  19. NATO Advanced Research Workshop on Thin Film Growth Techniques for Low-Dimensional Structures

    CERN Document Server

    Parkin, S; Dobson, P; Neave, J; Arrott, A

    1987-01-01

    This work represents the account of a NATO Advanced Research Workshop on "Thin Film Growth Techniques for Low Dimensional Structures", held at the University of Sussex, Brighton, England from 15-19 Sept. 1986. The objective of the workshop was to review the problems of the growth and characterisation of thin semiconductor and metal layers. Recent advances in deposition techniques have made it possible to design new material which is based on ultra-thin layers and this is now posing challenges for scientists, technologists and engineers in the assessment and utilisation of such new material. Molecular beam epitaxy (MBE) has become well established as a method for growing thin single crystal layers of semiconductors. Until recently, MBE was confined to the growth of III-V compounds and alloys, but now it is being used for group IV semiconductors and II-VI compounds. Examples of such work are given in this volume. MBE has one major advantage over other crystal growth techniques in that the structure of the growi...

  20. Using electrospray-assisted laser desorption/ionization mass spectrometry to characterize organic compounds separated on thin-layer chromatography plates.

    Science.gov (United States)

    Lin, Shu-Yao; Huang, Min-Zong; Chang, Hui-Chiu; Shiea, Jentaie

    2007-11-15

    Electrospray-assisted laser desorption/ionization (ELDI), an ionization method that combines laser desorption and electrospray ionization (ESI), can be used under ambient conditions to characterize organic compounds (including FD&C dyes, amines, extracts of a drug tablet) separated in the central track on a thin-layer chromatography (TLC) plate coated with either reversed-phase C18 particles or normal-phase silica gel. After drying, the TLC plate was placed on an acrylic sample holder set in front of the sampling skimmer of an ion trap mass analyzer. The chemicals at the center of the TLC plate were analyzed by pushing the sample holder into the path of a laser beam with a syringe pump. The molecules in the sample spot were desorbed by continuously irradiating the surface of the TLC plate with a pulsed nitrogen laser. Then, the desorbed sample molecules entered an ESI plume where they were ionized through the reactions with the charged species (including protons, hydronium ions and their cluster ions, solvent ions, and charged droplets) generated by electrospraying a methanol/water solution. MS/MS analyses were also performed to further characterize the analytes. The detection limit of TLC/ELDI/MS is approximately 10(-6) M. This was evaluated by using FD&C red dye as the standard. A linear relationship was found for the calibration curve with the concentration of FD&C red dye ranged from 10(-3) to 10(-6) M. PMID:17929897

  1. Spray-on Thin Film PV Solar Cells: Advances, Potentials and Challenges

    Directory of Open Access Journals (Sweden)

    Morteza Eslamian

    2014-01-01

    Full Text Available The capability to fabricate photovoltaic (PV solar cells on a large scale and at a competitive price is a milestone waiting to be achieved. Currently, such a fabrication method is lacking because the effective methods are either difficult to scale up or expensive due to the necessity for fabrication in a vacuum environment. Nevertheless, for a class of thin film solar cells, in which the solar cell materials can be processed in a solution, up scalable and vacuum-free fabrication techniques can be envisioned. In this context, all or some layers of polymer, dye-sensitized, quantum dot, and copper indium gallium selenide thin film solar cells illustrate some examples that may be processed in solution. The solution-processed materials may be transferred to the substrate by atomizing the solution and carrying the spray droplets to the substrate, a process that will form a thin film after evaporation of the solvent. Spray coating is performed at atmospheric pressure using low cost equipment with a roll-to-roll process capability, making it an attractive fabrication technique, provided that fairly uniform layers with high charge carrier separation and transport capability can be made. In this paper, the feasibility, the recent advances and challenges of fabricating spray-on thin film solar cells, the dynamics of spray and droplet impaction on the substrate, the photo-induced electron transfer in spray-on solar cells, the challenges on characterization and simulation, and the commercialization status of spray-on solar cells are discussed.

  2. Nanotechnological Advances in Catalytic Thin Films for Green Large-Area Surfaces

    Directory of Open Access Journals (Sweden)

    Suzan Biran Ay

    2015-01-01

    Full Text Available Large-area catalytic thin films offer great potential for green technology applications in order to save energy, combat pollution, and reduce global warming. These films, either embedded with nanoparticles, shaped with nanostructuring techniques, hybridized with other systems, or functionalized with bionanotechnological methods, can include many different surface properties including photocatalytic, antifouling, abrasion resistant and mechanically resistive, self-cleaning, antibacterial, hydrophobic, and oleophobic features. Thus, surface functionalization with such advanced structuring methods is of significance to increase the performance and wide usage of large-area thin film coatings specifically for environmental remediation. In this review, we focus on methods to increase the efficiency of catalytic reactions in thin film and hence improve the performance in relevant applications while eliminating high cost with the purpose of widespread usage. However, we also include the most recent hybrid architectures, which have potential to make a transformational change in surface applications as soon as high quality and large area production techniques are available. Hence, we present and discuss research studies regarding both organic and inorganic methods that are used to structure thin films that have potential for large-area and eco-friendly coatings.

  3. Recent advances in ZnO nanostructures and thin films for biosensor applications: Review

    International Nuclear Information System (INIS)

    Graphical abstract: ZnO nanostructures have shown binding of biomolecules in desired orientation with improved conformation and high biological activity, resulting in enhanced sensing characteristics. Furthermore, their compatibility with complementary metal oxide semiconductor technology for constructing integrated circuits makes them suitable candidate for future small integrated biosensor devices. This review highlights various approaches to synthesize ZnO nanostructures and thin films, and their applications in biosensor technology. Highlights: ► This review highlights various approaches to synthesize ZnO nanostructures and thin films. ► Article highlights the importance of ZnO nanostructures as biosensor matrix. ► Article highlights the advances in various biosensors based on ZnO nanostructures. ► Article describes the potential of ZnO based biosensor for new generation healthcare devices. - Abstract: Biosensors have shown great potential for health care and environmental monitoring. The performance of biosensors depends on their components, among which the matrix material, i.e., the layer between the recognition layer of biomolecule and transducer, plays a crucial role in defining the stability, sensitivity and shelf-life of a biosensor. Recently, zinc oxide (ZnO) nanostructures and thin films have attracted much interest as materials for biosensors due to their biocompatibility, chemical stability, high isoelectric point, electrochemical activity, high electron mobility, ease of synthesis by diverse methods and high surface-to-volume ratio. ZnO nanostructures have shown the binding of biomolecules in desired orientations with improved conformation and high biological activity, resulting in enhanced sensing characteristics. Furthermore, compatibility with complementary metal oxide semiconductor technology for constructing integrated circuits makes ZnO nanostructures suitable candidate for future small integrated biosensor devices. This review

  4. Semiconductor thin film transfer by wafer bonding and advanced ion implantation layer splitting technologies

    Science.gov (United States)

    Lee, Tien-Hsi

    Wafer bonding is an attractive technology for modern semiconductor and microelectronic industry due to its variability in allowing combination of materials. Initially, the bonding of wafers of the same material, such as silicon-silicon wafer bonding has been major interest. In the meantime, research interest has shifted to the bonding of dissimilar materials such as silicon to quartz or to sapphire. Thermal stress coming from the different expansion coefficients usually is a barrier to the success of dissimilar material bonding. Thermal stress may cause debonding, sliding, cracking, thermal misfit dislocations, or film wrinkle to impair the quality of the transferred layer. This dissertation presents several effective approaches to solve the thermal stress problem. These approaches concern bonding processes (low vacuum bonding and storage), thinning (advanced ion implantation layer splitting), and annealing processes (accumulative effect of blister generation) and are combined to design the best heat-treatment cycle. For this propose the concept of hot bonding is used in order to effectively minimize the thermal mismatch of dissimilar material bonding during the bonding and thinning procedures. During the initial bonding and bond strengthening phase, the difference in the temperature between bonding and annealing processes should be decreased as much as possible to avoid excessive thermal stresses. This concept can be realized either by increasing the bonding temperature or by decreasing the annealing temperature. A thinning technique has to employed that can thin the device wafer before debonding occurs due to the thermal stress generated either from the cooling-down process in the first case or by the annealing process itself in the late case. The ion implantation layer splitting method, also known as the Smart-cutsp°ler process, developed by Bruel at LEIT in France is a practical thinning technique which satisfies the above requirement. In the study, an

  5. Preparation of porous styrenics-based monolithic layers for thin layer chromatography coupled with matrix-assisted laser-desorption/ionization time-of-flight mass spectrometric detection.

    Science.gov (United States)

    Lv, Yongqin; Lin, Zhixing; Tan, Tianwei; Svec, Frantisek

    2013-11-01

    Monolithic 50 μm thin poly(4-methylstyrene-co-chloromethylstyrene-co-divinylbenzene) layers attached to 6.0 cm × 3.3 cm glass plates have been prepared, using a thermally initiated polymerization process. These layers had a well-defined porous structure with a globular morphology demonstrated with SEM images and exhibited superhydrophobic properties characterized with a water contact angle of 157°. They were then used for thin-layer chromatography of peptides and proteins fluorescently labeled with fluorescamine. The spots of individual separated compounds were visualized using UV light, and their identities were confirmed with a matrix-assisted laser desorption/ionization time of flight mass spectrometry. The presence of chloromethylstyrene units in the polymer enabled hypercrosslinking via a Friedel-Crafts alkylation reaction, and led to monoliths with much larger surface areas, which were suitable for separations of small dye molecules.

  6. Monitoring of monooctanoyl phosphatidylcholine synthesis by enzymatic acidolysis between soybean phosphatidylcholine and caprylic acid by thin-layer chromatography with a flame ionization detector

    DEFF Research Database (Denmark)

    Vikbjerg, Anders Falk; Mu, Huiling; Xu, Xuebing

    2005-01-01

    migration is taking place during reaction since the lipase is claimed to be 1,3-specific. The TLC-FID method offers a simple and cheap technique for elucidation of product and by-product formation during enzyme-catalyzed reactions for production of phospholipids containing mixtures of long- and medium......Thin-layer chromatography with flame ionization detector (TLC-FID) method was used for monitoring the production of structured phospholipids (ML-type: L-long chain fatty acids; M-medium chain fatty acids) by enzyme-catalyzed acidolysis between soybean phosphatidylcholine (PC) and caprylic acid....... It was found that the structured PC fractionated into 2-3 distinct bands on both plate thin layer chromatography (TLC) and Chromarod TLC. These 3 bands represented PC of LL-type, ML-type and MM-type, respectively. The TLC-FID method was applied in the present study to examine the influence of enzyme dosage...

  7. Effect of total ionizing dose radiation on the 0.25μm RF PDSOI nMOSFETs with thin gate oxide

    Institute of Scientific and Technical Information of China (English)

    Liu Mengxin; Han Zhengsheng; Bi Jinshun; Fan Xuemei; Liu Gang; Du Huan

    2009-01-01

    Thin gate oxide radio frequency (RF) PDSOI nMOSFETs that are suitable for integration with 0.1 μm SO1 CMOS technology are fabricated, and the total ionizing dose radiation responses of the nMOSFETs having four different device structures are characterized and compared for an equivalent gamma dose up to 1 Mrad (Si), using the front and back gate threshold voltages, off-state leakage, transconductance and output characteristics to assess direct current (DC) performance. Moreover, the frequency response of these devices under total ionizing dose radiation is presented, such as small-signal current gain and maximum available/stable gain. The results indicate that all the RF PDSOI nMOSFETs show significant degradation in both DC and RF characteristics after radiation, in particular to the float body nMOS. By comparison with the gate backside body contact (GBBC) structure and the body tied to source (BTS) contact structure, the low barrier body contact (LBBC) structure is more effective and excellent in the hardness of total ionizing dose radiation although there are some sacrifices in drive current, switching speed and high frequency response.

  8. Collisional Ionization Equilibrium for Optically Thin Plasmas. I. Updated Recombination Rate Coefficients for Bare though Sodium-like Ions

    CERN Document Server

    Bryans, P; Gorczyca, T W; Laming, J M; Mitthumsiri, W; Savin, D W

    2006-01-01

    Reliably interpreting spectra from electron-ionized cosmic plasmas requires accurate ionization balance calculations for the plasma in question. However, much of the atomic data needed for these calculations have not been generated using modern theoretical methods and are often highly suspect. This translates directly into the reliability of the collisional ionization equilibrium (CIE) calculations. We make use of state-of-the-art calculations of dielectronic recombination (DR) rate coefficients for the hydrogenic through Na-like ions of all elements from He up to and including Zn. We also make use of state-of-the-art radiative recombination (RR) rate coefficient calculations for the bare through Na-like ions of all elements from H through to Zn. Here we present improved CIE calculations for temperatures from $10^4$ to $10^9$ K using our data and the recommended electron impact ionization data of \\citet{Mazz98a} for elements up to and including Ni and Mazzotta (private communication) for Cu and Zn. DR and RR ...

  9. Advanced methods for light trapping in optically thin silicon solar cells

    Science.gov (United States)

    Nagel, James Richard

    2011-12-01

    The field of light trapping is the study of how best to absorb light in a thin film of material when most light either reflects away at the surface or transmits straight through to the other side. This has tremendous application to the field of photovoltaics where thin silicon films can be manufactured cheaply, but also fail to capture all of the available photons in the solar spectrum. Advancements in light trapping therefore bring us closer to the day when photovoltaic devices may reach grid parity with traditional fossil fuels on the electrical energy market. This dissertation advances our understanding of light trapping by first modeling the effects of loss in planar dielectric waveguides. The mathematical framework developed here can be used to model any arbitrary three-layer structure with mixed gain or loss and then extract the total field solution for the guided modes. It is found that lossy waveguides possess a greater number of eigenmodes than their lossless counterparts, and that these "loss guided" modes attenuate much more rapidly than conventional modes. Another contribution from this dissertation is the exploration of light trapping through the use of dielectric nanospheres embedded directly within the active layer of a thin silicon film. The primary benefit to this approach is that the device can utilize a surface nitride layer serving as an antireflective coating while still retaining the benefits of light trapping within the film. The end result is that light trapping and light injection are effectively decoupled from each other and may be independently optimized within a single photovoltaic device. The final contribution from this work is a direct numerical comparison between multiple light trapping schemes. This allows us to quantify the relative performances of various design techniques against one another and objectively determine which ideas tend to capture the most light. Using numerical simulation, this work directly compares the absorption

  10. Recent advances and remaining challenges in thin-film silicon photovoltaic technology

    Directory of Open Access Journals (Sweden)

    F. Meillaud

    2015-09-01

    Full Text Available This contribution reviews some of the latest achievements and challenges in thin-film silicon photovoltaic (PV technology based on amorphous and nanocrystalline silicon and their alloys. We address material and device developments, including (i improved plasma deposition processes to achieve high-quality dense absorber materials; (ii absorber layers based on silicon tetrafluoride, which lead to enhanced absorption in the near-infrared and yield outstanding short-circuit current densities; (iii dedicated optimization of the interfaces and device architecture, as well as (iv enhanced light harvesting by means of multi-scale textured substrates and reduced parasitic absorption in the non-active layers. This paper will describe how, by combining all of these advances along with precise control of plasmas over large areas, key results have been achieved in recent years, at both the cell and large-area module level, with stabilized efficiencies of over 13 and 12%, respectively.

  11. Non-ionizing energy loss calculations for modeling electron-induced degradation of Cu(In, Ga)Se2 thin-film solar cells

    Science.gov (United States)

    Lu, Ming; Xu, Jing; Huang, Jian-Wei

    2016-09-01

    The lowest energies which make Cu, In, Ga, and Se atoms composing Cu(In, Ga)Se2 (CIGS) material displaced from their lattice sites are evaluated, respectively. The non-ionizing energy loss (NIEL) for electron in CIGS material is calculated analytically using the Mott differential cross section. The relation of the introduction rate (k) of the recombination centers to NIEL is modified, then the values of k at different electron energies are calculated. Degradation modeling of CIGS thin-film solar cells irradiated with various-energy electrons is performed according to the characterization of solar cells and the recombination centers. The validity of the modeling approach is verified by comparison with the experimental data. Project supported by the National Natural Science Foundation of China (Grant No. 11547151).

  12. Ru-Based Thin Film Temperature Sensor for Space Environments: Microfabrication and Characterization under Total Ionizing Dose

    Directory of Open Access Journals (Sweden)

    S. I. Ravelo Arias

    2016-01-01

    Full Text Available The paper shows the microfabrication processes of a Ruthenium-based resistance temperature detector and its behavior in response to irradiation at ambient temperature. The radiation test was done in a public hospital facility and followed the procedures based on the ESA specification ESCC 22900. The instrumentation system used for the test is detailed in the work describing the sensors resistance evolution before, during, and after the exposure. A total irradiation dose of 43 krad with 36 krad/h dose rate was applied and a subsequent characterization was performed once the Ru sensors were submitted to an 80°C annealing process during a period of 168 h. The experimental measurements have shown the stability of this sensor against total ionizing dose (TID tests, not only in their resistance absolute values during the irradiation phase but also in the relative deviation from their values before irradiation.

  13. Advanced fabrication method for the preparation of MOF thin films: Liquid-phase epitaxy approach meets spin coating method.

    KAUST Repository

    Chernikova, Valeriya

    2016-07-14

    Here we report a new and advanced method for the fabrication of highly oriented/polycrystalline metal-organic framework (MOF) thin films. Building on the attractive features of the liquid-phase epitaxy (LPE) approach, a facile spin coating method was implemented to generate MOF thin films in a high-throughput fashion. Advantageously, this approach offers a great prospective to cost-effectively construct thin-films with a significantly shortened preparation time and a lessened chemicals and solvents consumption, as compared to the conventional LPE-process. Certainly, this new spin-coating approach has been implemented successfully to construct various MOF thin films, ranging in thickness from a few micrometers down to the nanometer scale, spanning 2-D and 3-D benchmark MOF materials including Cu2(bdc)2•xH2O, Zn2(bdc)2•xH2O, HKUST-1 and ZIF-8. This method was appraised and proved effective on a variety of substrates comprising functionalized gold, silicon, glass, porous stainless steel and aluminum oxide. The facile, high-throughput and cost-effective nature of this approach, coupled with the successful thin film growth and substrate versatility, represents the next generation of methods for MOF thin film fabrication. Thereby paving the way for these unique MOF materials to address a wide range of challenges in the areas of sensing devices and membrane technology.

  14. New ion-assisted filtered cathodic arc deposition (IFCAD) technology for producing advanced thin films on temperature-sensitive substrates

    Science.gov (United States)

    Fulton, Michael L.

    1999-10-01

    An innovative Ion-Assisted Filtered Cathodic Arc Deposition (IFCAD) system has been developed for low temperature production of thin-film coatings. The IFCAD system employs electro-magnetic and mechanical filtering techniques to remove unwanted macroparticles and neutral atoms from the plasma stream. Therefore, only ions within a defined energy range arrive at the substrate surface, depositing thin-films with excellent mechanical and optical properties. Ion- Assisted-Deposition is coupled with Filtered Cathodic Arc technology to enhance and modify the arc deposited thin- films. Using an advanced computer controlled plasma beam scanning system, high quality, large area, uniform IFCAD multi-layer film structures are attained. Amorphous Diamond- Like-Carbon films (up to 85% sp3 bonded carbon; and micro- hardness greater than 50 GPa) have been deposited in multi- layer thin-film combinations with other IFCAD source materials (such as: Al2O3) for optical and tribological applications. Rutile TiO2 (refractive index of 2.8 at 500 nm) has been deposited with this technology for advanced optical filter applications. The new IFCAD technology has been included in development programs, such as: plastic and glass lens coatings for optical systems; wear resistant coatings on various metal substrates, ultra smooth, durable, surface hydrophobic coatings for aircraft windows; EUV coatings for space instrumentation; transparent conductive coatings; and UV protective coatings for solar cell concentrator plastic Fresnel lens elements for space power.

  15. High-resolution computed tomography for flaw detection in advanced thin-layer ceramics for fuel cells

    International Nuclear Information System (INIS)

    Advanced monolithic solid oxide fuel cells are being assembled from thin (∼50 μm) tape-cast ceramic layers with highly tailored mechanical properties. The layers need to be free of cracks and nonbonds. A high-resolution computed tomography system with a Ir-192 source was investigated as a tool for detecting cracks and nonbonds. Results suggest that channel sizes, including internal channels, can be determined but small in-plane cracks cannot be detected

  16. The thin-film equation: recent advances and some new perspectives

    International Nuclear Information System (INIS)

    This paper is concerned with mathematical aspects of lubrication equations. In the first part, we discuss recent analytical achievements for various types of thin-film equations. Of interest are issues like (non-)uniqueness, wetting behaviour and contact line motion, in particular optimal propagation rates and waiting time or dead core phenomena. In the second part, we shall present novel numerical results for thin-film flow on heterogeneous substrates based on entropy consistent schemes. Finally, we will be concerned with new algorithmic concepts for the simulation of thin-film flow of shear-thinning liquids

  17. Advances on the compositional analysis of glycosphingolipids combining thin-layer chromatography with mass spectrometry.

    Science.gov (United States)

    Müthing, Johannes; Distler, Ute

    2010-01-01

    Glycosphingolipids (GSLs), composed of a hydrophilic carbohydrate chain and a lipophilic ceramide anchor, play pivotal roles in countless biological processes, including infectious diseases and the development of cancer. Knowledge of the number and sequence of monosaccharides and their anomeric configuration and linkage type, which make up the principal items of the glyco code of biologically active carbohydrate chains, is essential for exploring the function of GSLs. As part of the investigation of the vertebrate glycome, GSL analysis is undergoing rapid expansion owing to the application of novel biochemical and biophysical technologies. Mass spectrometry (MS) takes part in the network of collaborations to further unravel structural and functional aspects within the fascinating world of GSLs with the ultimate aim to better define their role in human health and disease. However, a single-method analytical MS technique without supporting tools is limited yielding only partial structural information. Because of its superior resolving power, robustness, and easy handling, high-performance thin-layer chromatography (TLC) is widely used as an invaluable tool in GSL analysis. The intention of this review is to give an insight into current advances obtained by coupling supplementary techniques such as TLC and mass spectrometry. A retrospective view of the development of this concept and the recent improvements by merging (1) TLC separation of GSLs, (2) their detection with oligosaccharide-specific proteins, and (3) in situ MS analysis of protein-detected GSLs directly on the TLC plate, are provided. The procedure works on a nanogram scale and was successfully applied to the identification of cancer-associated GSLs in several types of human tumors. The combination of these two supplementary techniques opens new doors by delivering specific structural information of trace quantities of GSLs with only limited investment in sample preparation. PMID:19609886

  18. Ionization state of ultra-thin carb on film irradiated by ultra-short intense laser pulse%超短超强激光脉冲辐照超薄碳膜电离状态研究∗

    Institute of Scientific and Technical Information of China (English)

    白春江; 崔万照; 余金清

    2016-01-01

    Ion acceleration is of interest for applications in fast ignition, compact particle sources, medical science, and others. The formation of plasma is of fundamental importance for understanding ion acceleration driven by intense laser. In order to further understand the solid dense material ionization dynamics under ultra-strong field, we use two-dimensional particle-in-cell code to study the ionization process of ultra-thin carbon film, driven by ultra-short intense laser pulse, particularly to see the plasma generation and distribution during the interaction. When an ultra-intense short pulse laser irradiates a solid dense nm-thick film target, the collisional ionization can be ignored for such a thin film target. If the target thickness is larger than laser pulse skin depth, the formation of plasma is contributed from laser field direct ionization and the ionization of electrostatic field inside the target, both of which are discussed and compared by the simulation results in this work. The ionization directly stimulated by laser field happens only near the laser-target interaction surface. After the generation of plasma on the target surface, electrons are accelerated into the target because of laser ponderomotive force. A huge electrostatic field is formed inside the target as a result of hot electron transport in it, and ionizes the target far from the interaction surface. It is found that a bigger fraction of ionization is contributed from electrostatic field ionization inside the target. The effect of laser pulse intensity on ionization is studied in detail, in which the laser pulse intensity is changed from 1 × 1018 W/cm2 to 1 × 1020 W/cm2. Comparing the results obtained under different intensities, we can see that higher intensity results in higher ionization speed, and much higher-order ions can be generated. At an intensity of 1 × 1020 W/cm2, although the intensity much higher than the threshold can generate C+6, only a small part of ions can be

  19. A review on the understanding and fabrication advancement of MgB2 thin and thick films by HPCVD

    International Nuclear Information System (INIS)

    MgB2 thin films with superior superconducting properties are very promising for superconducting magnets, electronic devices and coated conductor electric power applications. A clear understanding of flux pinning mechanism in MgB2 films could be a big aid in improving the performance of MgB2 by the enhancement of Jc. The fabrication advancement and the understanding of flux pinning mechanism of MgB2 thin and thick films fabricated by using hybrid physical-chemical vapor deposition (HPCVD) are reviewed. The distinct kind of MgB2 films, such as single-crystal like MgB2 thin films, MgB2 epitaxial columnar thick films, and a-axis-oriented MgB2 films are included for flux pinning mechanism investigation. Various attempts made by researchers to improve further the flux pinning property and Jc performance by means of doping in MgB2 thin films by using HPCVD are also summarized

  20. Guided ionization waves: Theory and experiments

    Energy Technology Data Exchange (ETDEWEB)

    Lu, X., E-mail: luxinpei@hotmail.com [State Key Laboratory of Advanced Electromagnetic Engineering and Technology, Huazhong University of Science and Technology, Wuhan, Hubei 430030 (China); Naidis, G.V. [Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow 125412 (Russian Federation); Laroussi, M. [Laser and Plasma Engineering Institute, Old Dominion University, Norfolk, VA 23529 (United States); Ostrikov, K. [CSIRO Materials Science and Engineering, P.O. Box 218, Lindfield, NSW 2070 (Australia); School of Physics, The University of Sydney, Sydney, NSW 2006 (Australia)

    2014-07-01

    This review focuses on one of the fundamental phenomena that occur upon application of sufficiently strong electric fields to gases, namely the formation and propagation of ionization waves–streamers. The dynamics of streamers is controlled by strongly nonlinear coupling, in localized streamer tip regions, between enhanced (due to charge separation) electric field and ionization and transport of charged species in the enhanced field. Streamers appear in nature (as initial stages of sparks and lightning, as huge structures—sprites above thunderclouds), and are also found in numerous technological applications of electrical discharges. Here we discuss the fundamental physics of the guided streamer-like structures—plasma bullets which are produced in cold atmospheric-pressure plasma jets. Plasma bullets are guided ionization waves moving in a thin column of a jet of plasma forming gases (e.g., He or Ar) expanding into ambient air. In contrast to streamers in a free (unbounded) space that propagate in a stochastic manner and often branch, guided ionization waves are repetitive and highly-reproducible and propagate along the same path—the jet axis. This property of guided streamers, in comparison with streamers in a free space, enables many advanced time-resolved experimental studies of ionization waves with nanosecond precision. In particular, experimental studies on manipulation of streamers by external electric fields and streamer interactions are critically examined. This review also introduces the basic theories and recent advances on the experimental and computational studies of guided streamers, in particular related to the propagation dynamics of ionization waves and the various parameters of relevance to plasma streamers. This knowledge is very useful to optimize the efficacy of applications of plasma streamer discharges in various fields ranging from health care and medicine to materials science and nanotechnology.

  1. Guided ionization waves: Theory and experiments

    International Nuclear Information System (INIS)

    This review focuses on one of the fundamental phenomena that occur upon application of sufficiently strong electric fields to gases, namely the formation and propagation of ionization waves–streamers. The dynamics of streamers is controlled by strongly nonlinear coupling, in localized streamer tip regions, between enhanced (due to charge separation) electric field and ionization and transport of charged species in the enhanced field. Streamers appear in nature (as initial stages of sparks and lightning, as huge structures—sprites above thunderclouds), and are also found in numerous technological applications of electrical discharges. Here we discuss the fundamental physics of the guided streamer-like structures—plasma bullets which are produced in cold atmospheric-pressure plasma jets. Plasma bullets are guided ionization waves moving in a thin column of a jet of plasma forming gases (e.g., He or Ar) expanding into ambient air. In contrast to streamers in a free (unbounded) space that propagate in a stochastic manner and often branch, guided ionization waves are repetitive and highly-reproducible and propagate along the same path—the jet axis. This property of guided streamers, in comparison with streamers in a free space, enables many advanced time-resolved experimental studies of ionization waves with nanosecond precision. In particular, experimental studies on manipulation of streamers by external electric fields and streamer interactions are critically examined. This review also introduces the basic theories and recent advances on the experimental and computational studies of guided streamers, in particular related to the propagation dynamics of ionization waves and the various parameters of relevance to plasma streamers. This knowledge is very useful to optimize the efficacy of applications of plasma streamer discharges in various fields ranging from health care and medicine to materials science and nanotechnology

  2. Development of advanced catalytic layer based on vertically aligned conductive polymer arrays for thin-film fuel cell electrodes

    Science.gov (United States)

    Jiang, Shangfeng; Yi, Baolian; Cao, Longsheng; Song, Wei; Zhao, Qing; Yu, Hongmei; Shao, Zhigang

    2016-10-01

    The degradation of carbon supports significantly influences the performance of proton exchange membrane fuel cells (PEMFCs), particularly in the cathode, which must be overcome for the wide application of fuel cells. In this study, advanced catalytic layer with electronic conductive polymer-polypyrrole (PPy) nanowire as ordered catalyst supports for PEMFCs is prepared. A platinum-palladium (PtPd) catalyst thin layer with whiskerette shapes forms along the long axis of the PPy nanowires. The resulting arrays are hot-pressed on both sides of a Nafion® membrane to construct a membrane electrode assembly (without additional ionomer). The ordered thin catalyst layer (approximately 1.1 μm) is applied in a single cell as the anode and the cathode without additional Nafion® ionomer. The single cell yields a maximum performance of 762.1 mW cm-2 with a low Pt loading (0.241 mg Pt cm-2, anode + cathode). The advanced catalyst layer indicates better mass transfer in high current density than that of commercial Pt/C-based electrode. The mass activity is 1.08-fold greater than that of DOE 2017 target. Thus, the as-prepared electrodes have the potential for application in fuel cells.

  3. Recent advances in the transparent conducting ZnO for thin-film Si solar cells

    Science.gov (United States)

    Moon, Taeho; Shin, Gwang Su; Park, Byungwoo

    2015-11-01

    The key challenge for solar-cell development lies in the improvement of power-conversion efficiency and the reduction of fabrication cost. For thin-film Si solar cells, researches have been especially focused on the light trapping for the breakthrough in the saturated efficiencies. The ZnO-based transparent conducting oxides (TCOs) have therefore received strong attention because of their excellent light-scattering capability by the texture-etched surface and cost effectiveness through in-house fabrication. Here, we have highlighted our recent studies on the transparent conducting ZnO for thin-film Si solar cells. From the electrical properties and their degradation mechanisms, bilayer deposition and organic-acid texturing approaches for enhancing the light trapping, and finally the relation between textured ZnO and electrical cell performances are sequentially introduced in this review article. [Figure not available: see fulltext.

  4. Deposition of thin titanium-copper films with antimicrobial effect by advanced magnetron sputtering methods

    Energy Technology Data Exchange (ETDEWEB)

    Stranak, V., E-mail: stranak@physik.uni-greifswald.de [University of Greifswald, Institute of Physics, Felix-Hausdorff Str. 6, 17489 Greifswald (Germany); Wulff, H. [University of Greifswald, Institute of Physics, Felix-Hausdorff Str. 6, 17489 Greifswald (Germany); Rebl, H. [University of Rostock, Biomedical Res. Center, Dept. of Cell Biology, Schillingallee 69, 18057 Rostock (Germany); Zietz, C. [University of Rostock, Dept. of Orthopaedics, Doberaner Str. 142, 18057 Rostock (Germany); Arndt, K. [University of Rostock, Dept. of Med. Microbiol., Virology and Hygiene, Schillingallee 70, 18057 Rostock (Germany); Bogdanowicz, R. [University of Greifswald, Institute of Physics, Felix-Hausdorff Str. 6, 17489 Greifswald (Germany); Nebe, B. [University of Rostock, Biomedical Res. Center, Dept. of Cell Biology, Schillingallee 69, 18057 Rostock (Germany); Bader, R. [University of Rostock, Dept. of Orthopaedics, Doberaner Str. 142, 18057 Rostock (Germany); Podbielski, A. [University of Rostock, Dept. of Med. Microbiol., Virology and Hygiene, Schillingallee 70, 18057 Rostock (Germany); Hubicka, Z. [Academy of Sciences of the Czech Republic, Institute of Physics, Na Slovance 2, 180 00 Prague (Czech Republic); Hippler, R. [University of Greifswald, Institute of Physics, Felix-Hausdorff Str. 6, 17489 Greifswald (Germany)

    2011-10-10

    The antibacterial effect of thin titanium-copper (Ti-Cu) films combined with sufficient growth of human osteoblastic cells is reported in the paper. Thin Ti-Cu films were prepared by three different plasma-assisted magnetron sputtering methods: direct current magnetron sputtering (dc-MS), dual magnetron sputtering (dual-MS) as well as dual high power impulse magnetron sputtering (dual-HiPIMS). The antimicrobial effect is caused by copper released from the metallic Ti-Cu films, which was measured by atomic absorption spectroscopy (AAS). The copper release is influenced by the chemical and physical properties of the deposited films and was investigated by X-ray diffractometry and X-ray reflectometry (GIXD and XR) techniques. It was found that, within the first 24 h the amount of Cu released from dual-HiPIMS films (about 250 {mu}g) was much higher than from dc-MS and dual-MS films. In vitro planktonic growth tests on Ti-Cu surfaces for Staphylococcus epidermidis and S. aureus demonstrated the killing of both bacteria using the Ti-Cu films prepared using the dual-HiPIMS technique. The killing effects on biofilm bacteria were less obvious. After the total release of copper from the Ti-Cu film the vitality of exposed human osteoblast MG-63 cells increased significantly. An initial cytotoxic effect followed by the growth of osteoblastic cells was demonstrated. The cytotoxic effect combined with growth of osteoblastic cells could be used in joint replacement surgery to reduce the possibility of infection and to increase adoption of the implants. Highlights: {yields} Ti-Cu films with significant cytotoxic effect were prepared by dual-HiPIMS technique. {yields} The cytotoxic effect is caused by total release of copper species from thin films. {yields} The copper release is influenced by crystallography and chemical properties of thin films. {yields} Sufficient growth of osteoblastic cells follows after copper release.

  5. Simulation of Thin-Film Damping and Thermal Mechanical Noise Spectra for Advanced Micromachined Microphone Structures

    OpenAIRE

    Hall, Neal A.; Okandan, Murat; Littrell, Robert; Bicen, Baris; Degertekin, F. Levent

    2008-01-01

    In many micromachined sensors the thin (2–10 μm thick) air film between a compliant diaphragm and backplate electrode plays a dominant role in shaping both the dynamic and thermal noise characteristics of the device. Silicon microphone structures used in grating-based optical-interference microphones have recently been introduced that employ backplates with minimal area to achieve low damping and low thermal noise levels. Finite-element based modeling procedures based on 2-D discretization of...

  6. Advances in Thin-Film Si Solar Cells by Means of SiOx Alloys

    OpenAIRE

    Lucia V. Mercaldo; Iurie Usatii; Paola Delli Veneri

    2016-01-01

    The conversion efficiency of thin-film silicon solar cells needs to be improved to be competitive with respect to other technologies. For a more efficient use of light across the solar spectrum, multi-junction architectures are being considered. Light-management considerations are also crucial in order to maximize light absorption in the active regions with a minimum of parasitic optical losses in the supportive layers. Intrinsic and doped silicon oxide alloys can be advantageously applied wi...

  7. Advances in Thin-Film Si Solar Cells by Means of SiOx Alloys

    Directory of Open Access Journals (Sweden)

    Lucia V. Mercaldo

    2016-03-01

    Full Text Available The conversion efficiency of thin-film silicon solar cells needs to be improved to be competitive with respect to other technologies. For a more efficient use of light across the solar spectrum, multi-junction architectures are being considered. Light-management considerations are also crucial in order to maximize light absorption in the active regions with a minimum of parasitic optical losses in the supportive layers. Intrinsic and doped silicon oxide alloys can be advantageously applied within thin-film Si solar cells for these purposes. Intrinsic a-SiOx:H films have been fabricated and characterized as a promising wide gap absorber for application in triple-junction solar cells. Single-junction test devices with open circuit voltage up to 950 mV and ~1 V have been demonstrated, in case of rough and flat front electrodes, respectively. Doped silicon oxide alloys with mixed-phase structure have been developed, characterized by considerably lower absorption and refractive index with respect to standard Si-based films, accompanied by electrical conductivity above 10−5 S/cm. These layers have been successfully applied both into single-junction and micromorph tandem solar cells as superior doped layers with additional functionalities.

  8. Advances in CuInSe sub 2 and CdTe thin film solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Shafarmann, W.N.; Birkmire, R.W.; Farding, D.A.; McCandless, B.E.; Mondal, A.; Phillips, J.E.; Varrin, R.D. Jr. (Delaware Univ., Newark (USA). Inst. of Energy Conversion)

    1991-05-01

    Research on CuInSe{sub 2} and CdTe thin film solar cells is discussed. CuInSe{sub 2} was deposited by selenization of Cu/In layers and was used to make a 10% efficient CuInSe{sub 2}/(CdZn)S cell. Characterization of the reaction mechanisms is described. The open-circuit voltage V{sub oc} of CuInSe{sub 2}/(CdZn)S cells is dominated by recombination in the space charge region, so increassing the band gap or decreasing the width of this region should increase V{sub oc}. Increasing the band gap with a thin Cu(InGa)Se{sub 2} layer at the CuInSe{sub 2} surface has demonstrated increased V{sub oc} with collection out to the CuInSe{sub 2} band gap. A post-deposition treatment and contacting process for evaporated CdS/CdTe cells was developed and high efficiency cells were made. Several steps in the process, including a CdCl{sub 2} coating, a 400deg C heat treatment, and a contact containing copper are critical. ZnTe films were deposited from an aqueous solution as a contact to CdTe. (orig.).

  9. Tungsten oxide (WO3) thin films for application in advanced energy systems

    International Nuclear Information System (INIS)

    Inherent processes in coal gasification plants produce hazardous hydrogen sulfide (H2S), which must be continuously and efficiently detected and removed before the fuel is used for power generation. An attempt has been made in this work to fabricate tungsten oxide (WO3) thin films by radio-frequency reactive magnetron-sputter deposition. The impetus being the use of WO3 films for H2S sensors in coal gasification plants. The effect of growth temperature, which is varied in the range of 30-500 deg. C, on the growth and microstructure of WO3 thin films is investigated. Characterizations made using scanning electron microscopy (SEM) and x-ray diffraction (XRD) indicate that the effect of temperature is significant on the microstructure of WO3 films. XRD and SEM results indicate that the WO3 films grown at room temperature are amorphous, whereas films grown at higher temperatures are nanocrystalline. The average grain-size increases with increasing temperature. WO3 films exhibit smooth morphology at growth temperatures ≤300 deg. C while relatively rough at >300 deg. C. The analyses indicate that the nanocrystalline WO3 films grown at 100-300 deg. C could be the potential candidates for H2S sensor development for application in coal gasification systems.

  10. Radiation dependent ionization model

    International Nuclear Information System (INIS)

    For laser created plasma simulation, hydrodynamics codes need a non-LTE atomic physics package for both EOS and optical properties (emissivity and opacity). However in XRL targets as in some ICF targets, high Z material can be found. In these cases radiation trapping can induce a significant departure from the optically thin ionization description. The authors present a method to change an existing LTE code into a non-LTE code with coupling of ionization to radiation. This method has very low CPU cost and can be used in 2D simulations

  11. Thin film silicon solar cells: advanced processing and characterization - Final report

    Energy Technology Data Exchange (ETDEWEB)

    Ballif, Ch.

    2008-04-15

    This final report elaborated for the Swiss Federal Office of Energy (SFOE) takes a look at the results of a project carried out at the photovoltaics laboratory at the University of Neuchatel in Switzerland. The project aimed to demonstrate the production of high-efficiency thin-film silicon devices on flexible substrates using low cost processes. New ways of improving processing and characterisation are examined. The process and manufacturing know-how necessary to provide support for industrial partners within the framework of further projects is discussed. The authors state that the efficiency of most devices was significantly improved, both on glass substrates and on flexible plastic foils. The process reproducibility was also improved and the interactions between the different layers in the device are now said to be better understood. The report presents the results obtained and discusses substrate materials, transparent conductors, defect analyses and new characterisation tools. Finally, the laboratory infrastructure is described.

  12. Modified Separator Using Thin Carbon Layer Obtained from Its Cathode for Advanced Lithium Sulfur Batteries.

    Science.gov (United States)

    Liu, Naiqiang; Huang, Bicheng; Wang, Weikun; Shao, Hongyuan; Li, Chengming; Zhang, Hao; Wang, Anbang; Yuan, Keguo; Huang, Yaqin

    2016-06-29

    The realization of a practical lithium sulfur battery system, despite its high theoretical specific capacity, is severely limited by fast capacity decay, which is mainly attributed to polysulfide dissolution and shuttle effect. To address this issue, we designed a thin cathode inactive material interlayer modified separator to block polysulfides. There are two advantages for this strategy. First, the coating material totally comes from the cathode, thus avoids the additional weights involved. Second, the cathode inactive material modified separator improve the reversible capacity and cycle performance by combining gelatin to chemically bond polysulfides and the carbon layer to physically block polysulfides. The research results confirm that with the cathode inactive material modified separator, the batteries retain a reversible capacity of 644 mAh g(-1) after 150 cycles, showing a low capacity decay of about 0.11% per circle at the rate of 0.5C. PMID:27267483

  13. Advances in thin film diffraction instrumentation by X-ray optics

    Energy Technology Data Exchange (ETDEWEB)

    Haase, A. [Rich. Seifert and Co., Analytical X-ray Systems, Ahrensburg (Germany)

    1996-09-01

    The structural characterisation of thin films requires a parallel X-ray beam of high intensity. Parallel beam geometry is commonly used in high resolution and single crystal experiments, but also in the field of X-ray diffraction for polycrystalline material (e.g. in phase, texture and stress analysis). For grazing incidence diffraction (GID), the use of small slits on the primary side and of long soller slits with a flat monochromator on the secondary side is standard. New optical elements have been introduced with polychromatic or monochromatic radiation. By means of different applications the results are compared with those of classical beam optics. X-ray fiber optics utilize total external reflection of X-rays on smooth surfaces. Effects of monochromatization are presented. In many fields of application, fiber optics may replace conventional collimators. The use of primary and secondary channel cut crystals can also produce a high parallel monochromatic X-ray beam. A parabolically bent graded multilayer produces a monochromatic parallel beam of high intensity. Compared with classical Bragg-Brentano (focussing) geometry, excellent results have been obtained, especially for samples with an irregular shape. In combination with a channel cut monochromator there is a substantial gain in intensity leading to an increase of the dynamic intensity range of rocking curves.

  14. Recent technical advances in thin-film CdS/CdTe solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Omura, K.; Hanahusa, A.; Arita, T.; Higuchi, H.; Aramoto, T.; Nishio, T.; Sibutani, S.; Kumazawa, S.; Murozono, M. [Matsushita Battery Industrial Co., Ltd., Osaka (Japan). PV Research and Development Center; Yabuuchi, Y. [Matsushita Technoresearch Inc., Osaka (Japan); Takakura, H. [Toyama Prefectural University, Toyama (Japan)

    1996-05-01

    CeS/CdTe solar cells have attracted attention recently for their potential as low-cost, high-efficiency solar cells of the future. It is because the CdTe layer (used for photoelectric conversion) has a bandgap energy of 1.51 eV, which corresponds well to sunlight spectra, and the direct transition type energy band structure enables formation of thinner films. We have already industrialized CdS/CdTe solar cells in mass production stage using a printing-sintering process, as large-area modules for electric power generation (Higuchi et al., 1993, Omura et al., 1991), and as cells for indoor applications (primarily in calculators, Suyama et al., 1986). However, this solar cell has a conversion efficiency of approximately 6%. Recently, there has been considerable research into thin-film CdS/CdTe solar cells which have a thinner CdS film formed by CVD or CBD (Britt et al., 1993) process, and thus are photosensitive to light with wavelengths of 500 nm or less. At present stage of our art, in solar cells formed by the CSS with a CdTe film on CVD CdS, a conversion efficiency of 15.05% has been obtained in cells with an area of 1 cm{sup 2}(verified at JQA). (author)

  15. Photoluminescence of radiation-induced color centers in lithium fluoride thin films for advanced diagnostics of proton beams

    International Nuclear Information System (INIS)

    Systematic irradiation of thermally evaporated 0.8 μm thick polycrystalline lithium fluoride films on glass was performed by proton beams of 3 and 7 MeV energies, produced by a linear accelerator, in a fluence range from 1011 to 1015 protons/cm2. The visible photoluminescence spectra of radiation-induced F2 and F3+ laser active color centers, which possess almost overlapping absorption bands at about 450 nm, were measured under laser pumping at 458 nm. On the basis of simulations of the linear energy transfer with proton penetration depth in LiF, it was possible to obtain the behavior of the measured integrated photoluminescence intensity of proton irradiated LiF films as a function of the deposited dose. The photoluminescence signal is linearly dependent on the deposited dose in the interval from 103 to about 106 Gy, independently from the used proton energies. This behavior is very encouraging for the development of advanced solid state radiation detectors based on optically transparent LiF thin films for proton beam diagnostics and two-dimensional dose mapping

  16. Photoluminescence of radiation-induced color centers in lithium fluoride thin films for advanced diagnostics of proton beams

    Energy Technology Data Exchange (ETDEWEB)

    Piccinini, M., E-mail: massimo.piccinini@enea.it; Ampollini, A.; Picardi, L.; Ronsivalle, C.; Bonfigli, F.; Libera, S.; Vincenti, M. A.; Montereali, R. M. [ENEA, C.R. Frascati, UTAPRAD, Technical Unit for Development and Applications of Radiations, Via E. Fermi 45, 00044 Frascati (Rome) (Italy); Ambrosini, F. [University Sapienza-Roma I, Piazzale Aldo Moro 5, 00185 Rome (Italy); Nichelatti, E. [ENEA, C.R. Casaccia, UTTMAT, Technical Unit for Materials Technologies, Via Anguillarese 301, 00123 S. Maria di Galeria (Rome) (Italy)

    2015-06-29

    Systematic irradiation of thermally evaporated 0.8 μm thick polycrystalline lithium fluoride films on glass was performed by proton beams of 3 and 7 MeV energies, produced by a linear accelerator, in a fluence range from 10{sup 11} to 10{sup 15} protons/cm{sup 2}. The visible photoluminescence spectra of radiation-induced F{sub 2} and F{sub 3}{sup +} laser active color centers, which possess almost overlapping absorption bands at about 450 nm, were measured under laser pumping at 458 nm. On the basis of simulations of the linear energy transfer with proton penetration depth in LiF, it was possible to obtain the behavior of the measured integrated photoluminescence intensity of proton irradiated LiF films as a function of the deposited dose. The photoluminescence signal is linearly dependent on the deposited dose in the interval from 10{sup 3} to about 10{sup 6 }Gy, independently from the used proton energies. This behavior is very encouraging for the development of advanced solid state radiation detectors based on optically transparent LiF thin films for proton beam diagnostics and two-dimensional dose mapping.

  17. Transient terahertz photoconductivity measurements of minority-carrier lifetime in tin sulfide thin films: Advanced metrology for an early-stage photovoltaic material

    OpenAIRE

    Jaramillo, R.; Sher, Meng-Ju; Ofori-Okai, Benjamin K.; Steinmann, V; Yang, Chuanxi; Hartman, Katy; Nelson, Keith A.; Lindenberg, Aaron M.; Gordon, Roy G.; Buonassisi, T.

    2015-01-01

    Materials research with a focus on enhancing the minority-carrier lifetime of the light-absorbing semiconductor is key to advancing solar energy technology for both early-stage and mature material platforms alike. Tin sulfide (SnS) is an absorber material with several clear advantages for manufacturing and deployment, but the record power conversion efficiency remains below 5%. We report measurements of bulk and interface minority-carrier recombination rates in SnS thin films using optical-pu...

  18. IRAS 13197-1627 has them all: Compton-thin absorption, photo-ionized gas, thermal plasmas, and a broad Fe line

    OpenAIRE

    G. Miniutti(Centro de Astrobiologia); Ponti, G; Dadina, M.; Cappi, M.; Malaguti, G.

    2006-01-01

    We report results from the XMM-Newton observation of IRAS 13197-1627, a luminous IR galaxy with a Seyfert 1.8 nucleus. The hard X-ray spectrum is steep and is absorbed by Compton-thin neutral gas. We detect an Fe emission line at 6.4 keV, consistent with transmission through the absorber. The most striking result of our spectral analysis is the detection of a dominant X-ray reflection component and broad Fe line from the inner accretion disc. The reflection-dominated hard X-ray spectrum is co...

  19. Ionizing radiations

    International Nuclear Information System (INIS)

    The purpose of this article is to simplify some of the relevant points of legislation, biological effects and protection for the benefit of the occupational health nurse not familiar with the nuclear industries. The subject is dealt with under the following headings; Understanding atoms. What is meant by ionizing radiation. Types of ionizing radiation. Effects of radiation: long and short term somatic effects, genetic effects. Control of radiation: occupational exposure, women of reproductive age, medical aspects, principles of control. The occupational health nurse's role. Emergency arrangements: national arrangements for incidents involving radiation, action to be taken by the nurse. Decontamination procedures: external and internal contamination. (U.K.)

  20. III. Penning ionization, associative ionization and chemi-ionization processes

    International Nuclear Information System (INIS)

    Physical mechanisms of three important ionization processes in a cold plasma and the methods of their experimental study are discussed. An apparatus for the investigation of the Penning ionization using ionization processes of long lived metastable rare gas atoms is described. Methods of determining interaction energies and ionization rates from the measured energy spectra of the originating electrons are described and illustrated by several examples. Typical associative ionization processes are listed and the ionization rates are compared with those of the Penning ionization. Interactions with short-lived excited particles and the transfer of excitation without ionization are discussed. (J.U.)

  1. Qualitative and quantitative two-dimensional thin-layer chromatography/high performance liquid chromatography/diode-array/electrospray-ionization-time-of-flight mass spectrometry of cholinesterase inhibitors.

    Science.gov (United States)

    Mroczek, Tomasz

    2016-09-10

    Recently launched thin-layer chromatography-mass spectrometry (TLC-MS) interface enabling extraction of compounds directly from TLC plates into MS ion source was unusually extended into two-dimensional thin-layer chromatography/high performance liquid chromatography (2D, TLC/HPLC) system by its a direct connection to a rapid resolution 50×2.1mm, I.D. C18 column compartment followed by detection by diode array (DAD) and electrospray ionisation time-of-flight mass spectrometry (ESI-TOF-MS). In this way, even not separated bands of complicated mixtures of natural compounds could be analysed structurally, only within 1-2min after development of TLC plates. In comparison to typically applied TLC-MS interface, no ion suppression for acidic mobile phases was observed. Also, substantial increase in ESI-TOF-MS sensitivities and quality of spectra, were noticed. It has been utilised in combination with TLC- based bioautographic approaches of acetylcholinesterase (AChE) inhibitors, However, it can be also applied in any other procedures related to bioactivity (e.g. 2,2-Diphenyl-1-picryl-hydrazyl-DPPH screen test for radicals). This system has been also used for determination of half maximal inhibitory concentration (IC50 values) of the active inhibitor-galanthamine, as an example. Moreover, AChE inhibitory potencies of some of purified plant extracts, never studied before, have been quantitatively measured. This is first report of usage such the 2D TLC/HPLC/MS system both for qualitative and quantitative evaluation of cholinesterase inhibitors in biological matrices.

  2. IRAS 13197-1627 has them all: Compton-thin absorption, photo-ionized gas, thermal plasmas, and a broad Fe line

    CERN Document Server

    Miniutti, G; Dadina, M; Cappi, M; Malaguti, G

    2006-01-01

    We report results from the XMM-Newton observation of IRAS 13197-1627, a luminous IR galaxy with a Seyfert 1.8 nucleus. The hard X-ray spectrum is steep and is absorbed by Compton-thin neutral gas. We detect an Fe emission line at 6.4 keV, consistent with transmission through the absorber. The most striking result of our spectral analysis is the detection of a dominant X-ray reflection component and broad Fe line from the inner accretion disc. The reflection-dominated hard X-ray spectrum is confirmed by the strong Compton hump seen in a previous BeppoSAX observation and could be the sign that most of the primary X-rays are radiated from a compact corona (or e.g. base of the jet) within a few gravitational radii from the black hole. We also detect a relatively strong absorption line at 6.81 keV which, if interpreted as Fe xxv resonant absorption intrinsic to the source, implies an outflow with velocity of about 5000 km/s. In the soft energy band, the high-resolution RGS and the CCD-resolution data show the pres...

  3. Suitability of thin-layer chromatography-flame ionization detection with regard to quantitative characterization of different fossil fuel products. II. Calibration methods concerning quantitative hydrocarbon-group type analysis

    Energy Technology Data Exchange (ETDEWEB)

    Vela, J.; Membrado, L.; Cebolla, V.L.; Ferrando, A.C. [CSIC, Zaragoza (Spain). Inst. de Carboquimica, Dept. de Procesos Quimicos

    1998-10-01

    Time-consuming external standard-based calibration methods are usually performed for hydrocarbon group type analysis (HGTA) of fossil fuels, regardless of the instrumental chromatographic technique. HGTA of a broad variety of coal and petroleum products was performed using a modern thin-layer chromatography-flame ionization detection (TLC-FID) system and a rapid method based on internal normalization. Repeatability, linear intervals, and sample load ranges for quantitative application of this method are given, namely a heavy oil and its derived hydrocracked products, raw and chemically-modified petroleum asphaltenes, a coal-tar pitch, several coal extracts, and coal hydroliquefaction products. Results from external standard calibration and a normalization method (both obtained by TLC-FID) are in agreement, and they are validated using TLC-ultraviolet scanning. The use of the latter demonstrates that TLC-FID can also be applied to products such as coal extracts and hydroliquefaction products, despite these products being more volatile than petroleum asphaltenes or heavy oils. 14 refs., 3 figs., 5 tabs.

  4. Thin film deposition at atmospheric pressure using dielectric barrier discharges: Advances on three-dimensional porous substrates and functional coatings

    Science.gov (United States)

    Fanelli, Fiorenza; Bosso, Piera; Mastrangelo, Anna Maria; Fracassi, Francesco

    2016-07-01

    Surface processing of materials by atmospheric pressure dielectric barrier discharges (DBDs) has experienced significant growth in recent years. Considerable research efforts have been directed for instance to develop a large variety of processes which exploit different DBD electrode geometries for the direct and remote deposition of thin films from precursors in gas, vapor and aerosol form. This article briefly reviews our recent progress in thin film deposition by DBDs with particular focus on process optimization. The following examples are provided: (i) the plasma-enhanced chemical vapor deposition of thin films on an open-cell foam accomplished by igniting the DBD throughout the entire three-dimensional (3D) porous structure of the substrate, (ii) the preparation of hybrid organic/inorganic nanocomposite coatings using an aerosol-assisted process, (iii) the DBD jet deposition of coatings containing carboxylic acid groups and the improvement of their chemical and morphological stability upon immersion in water.

  5. Atomic layer deposition: a key technology for the controlled growth of oxide thin films for advanced applications

    International Nuclear Information System (INIS)

    Atomic layer deposition (ALD), also referred to as atomic layer epitaxy (ALE), was originally developed to process thin film electroluminescent structures for flat panel displays, which include as core components also insulating oxide layers such as alumina and aluminium titanium oxide. Another early application of oxide ALD was the processing of overlayers for catalysts. More recently, a major breakthrough for the ALD technology is the use of oxide thin films in microelectronics as gate and dynamic random access memory capacitor dielectrics. Besides giving a brief introduction to the ALD/ALE technology, the paper will address the present status of depositing binary and more complex (i.e. perovskite-type) metal oxides emphasizing precursor chemistry. (author)

  6. Ionization gage

    International Nuclear Information System (INIS)

    An ionization manometer is proposed which contains a transducer consisting of an anode, a directly heated cathode and a collector, a power source, a cathode emission current stabilizer, an ionic current amplifier connected to a recorder, and a cathode emission current modulator. To increase the accuracy of measurements under conditions of vacuum evaporation of materials, the modulator has been designed to comprise a source of controlling electric unipolar pulses of a specified duration and frequency and a blocking device connected to the collector. The output of the source of controlling electric unipolar pulses is connected to the emission current stabilizer and to the second input of the blocking device whose output is connected to the ionic current amplifier. The amount of pressure exerted in the vacuum chamber is estimated from the magnitude of the variable constituent of the collector signal

  7. Thin film CIGS photovoltaic modules: monolithic integration and advanced packaging for high performance, high reliability and low cost

    Science.gov (United States)

    Eldada, Louay

    2011-01-01

    In recent years, thin-film photovoltaic companies started realizing their low manufacturing cost potential, and have been grabbing an increasingly larger market share. Copper Indium Gallium Selenide (CIGS) is the most promising thin-film PV material, having demonstrated the highest energy conversion efficiency in both cells and modules. However, most CIGS manufacturers still face the challenge of delivering a reliable and rapid manufacturing process that can scale effectively and deliver on the promise of this material system. HelioVolt has developed a reactive transfer process for CIGS absorber formation that has the benefits of good compositional control, and a fast high-quality CIGS reaction. The reactive transfer process is a two stage CIGS fabrication method. Precursor films are deposited onto substrates and reusable cover plates in the first stage, while in the second stage the CIGS layer is formed by rapid heating with Se confinement. HelioVolt also developed best-in-class packaging technologies that provide unparalleled environmental stability. High quality CIGS films with large grains were fabricated on the production line, and high-performance highreliability monolithic modules with a form factor of 120 cm × 60 cm are being produced at high yield and low cost. With conversion efficiency levels around 14% for cells and 12% for modules, HelioVolt is commercializing the process on its first production line with 20 MW capacity, and is planning its next GW-scale factory.

  8. Sol-gel optical thin films for an advanced megajoule-class Nd:glass laser ICF-driver

    International Nuclear Information System (INIS)

    It is well established by manufacturers and users that optical coatings are generally prepared by the well known Physical Vapor Deposition (PVD) technology. In the authors' opinion sol-gel technology is an effective and competitive alternative. The aim of this paper is to emphasize on the sol-gel thin film work carried out at Centre d'Etudes de Limeil-Valenton (CEL-V) and concerning the technology for high power lasers. The authors will briefly discuss the chemistry of the sol-gel process, the production of optical coatings and the related deposition techniques. Finally, the paper describes the preparation and performance of sol-gel optical coatings they have developed to fulfill the requirements of a future 2 MJ/500 TW (351 nm) pulsed Nd:glass laser so-called LMJ (Laser MegaJoules). This powerful laser is to be used for their national Inertial Confinement Fusion (ICF) program, to demonstrate at the laboratory scale, ignition of deuterium-tritium fusion fuel. Moreover, the aim of this article is, hopefully, to provide a convincing argument that coatings and particularly optical coatings, are some of the useful products available from sol-gel technology, and that exciting developments in other areas are almost certain to emerge within the coming decade

  9. Electrical properties of radio-frequency sputtered HfO2 thin films for advanced CMOS technology

    International Nuclear Information System (INIS)

    The Hafnium oxide (HfO2) high-k thin films have been deposited by radio frequency (rf) sputtering technique on p-type Si (100) substrate. The thickness, composition and phases of films in relation to annealing temperatures have been investigated by using cross sectional FE-SEM (Field Emission Scanning Electron Microscope) and grazing incidence x-ray diffraction (GI-XRD), respectively. GI-XRD analysis revealed that at annealing temperatures of 350°C, films phases change to crystalline from amorphous. The capacitance-voltage (C-V) and current-voltage (I-V) characteristics of the annealed HfO2 film have been studied employing Al/HfO2/p-Si metal–oxide–semiconductor (MOS) structures. The electrical properties such as dielectric constant, interface trap density and leakage current density have been also extracted from C-V and I-V Measurements. The value of dielectric constant, interface trap density and leakage current density of annealed HfO2 film is obtained as 23,7.57×1011eV−1 cm−2 and 2.7×10−5 Acm−2, respectively. In this work we also reported the influence of post deposition annealing onto the trapping properties of hafnium oxide and optimized conditions under which no charge trapping is observed into the dielectric stack

  10. Advanced stored waveform inverse Fourier transform technique for a matrix-assisted laser desorption/ionization quadrupole ion trap mass spectrometer.

    Science.gov (United States)

    Doroshenko, V M; Cotter, R J

    1996-01-01

    The stored waveform inverse Fourier transform (SWIFT) technique is used for broadband excitation of ions in an ion-trap mass spectrometer to perform mass-selective accumulation, isolation, and fragmentation of peptide ions formed by matrix-assisted laser desorption/ionization. Unit mass resolution is achieved for isolation of ions in the range of m/z up to 1300 using a two-step isolation technique with stretched-in-time narrow band SWIFT pulses at the second stage. The effect of 'stretched-in-time' waveforms is similar to that observed previously for mass-scan-rate reduction. The asymmetry phenomenon resulting from the stretched ion-trap electrode geometry is observed during application of normal and time-reversed waveforms and is similar to the asymmetry effects observed for forward and reverse mass scans in the resonance ejection mode. Mass-selective accumulation of ions from multiple laser shots was accomplished using a method described earlier that involves increasing the trapping voltage during ion introduction for more efficient trapping of ions.

  11. Wafer-Scale Integration of Inverted Nanopyramid Arrays for Advanced Light Trapping in Crystalline Silicon Thin Film Solar Cells.

    Science.gov (United States)

    Zhou, Suqiong; Yang, Zhenhai; Gao, Pingqi; Li, Xiaofeng; Yang, Xi; Wang, Dan; He, Jian; Ying, Zhiqin; Ye, Jichun

    2016-12-01

    Crystalline silicon thin film (c-Si TF) solar cells with an active layer thickness of a few micrometers may provide a viable pathway for further sustainable development of photovoltaic technology, because of its potentials in cost reduction and high efficiency. However, the performance of such cells is largely constrained by the deteriorated light absorption of the ultrathin photoactive material. Here, we report an efficient light-trapping strategy in c-Si TFs (~20 μm in thickness) that utilizes two-dimensional (2D) arrays of inverted nanopyramid (INP) as surface texturing. Three types of INP arrays with typical periodicities of 300, 670, and 1400 nm, either on front, rear, or both surfaces of the c-Si TFs, are fabricated by scalable colloidal lithography and anisotropic wet etch technique. With the extra aid of antireflection coating, the sufficient optical absorption of 20-μm-thick c-Si with a double-sided 1400-nm INP arrays yields a photocurrent density of 39.86 mA/cm(2), which is about 76 % higher than the flat counterpart (22.63 mA/cm(2)) and is only 3 % lower than the value of Lambertian limit (41.10 mA/cm(2)). The novel surface texturing scheme with 2D INP arrays has the advantages of excellent antireflection and light-trapping capabilities, an inherent low parasitic surface area, a negligible surface damage, and a good compatibility for subsequent process steps, making it a good alternative for high-performance c-Si TF solar cells. PMID:27071681

  12. Designing nanoscale constructs from atomic thin sheets of graphene, boron nitride and gold nanoparticles for advanced material applications

    Science.gov (United States)

    Jasuja, Kabeer

    2011-12-01

    Nanoscale materials invite immense interest from diverse scientific disciplines as these provide access to precisely understand the physical world at their most fundamental atomic level. In concert with this aim of enhancing our understanding of the fundamental behavior at nanoscale, this dissertation presents research on three nanomaterials: Gold nanoparticles (GNPs), Graphene and ultra-thin Boron Nitride sheets (UTBNSs). The three-fold goals which drive this research are: incorporating mobility in nanoparticle based single-electron junction constructs, developing effective strategies to functionalize graphene with nano-forms of metal, and exfoliating ultrathin sheets of Boron Nitride. Gold nanoparticle based electronic constructs can achieve a new degree of operational freedom if nanoscale mobility is incorporated in their design. We achieved such a nano-electromechanical construct by incorporating elastic polymer molecules between GNPs to form 2-dimensional (2-D) molecular junctions which show a nanoscale reversible motion on applying macro scale forces. This GNP-polymer assembly works like a molecular spring opening avenues to maneuver nano components and store energy at nano-scale. Graphene is the first isolated nanomaterial that displays single-atom thickness. It exhibits quantum confinement that enables it to possess a unique combination of fascinating electronic, optical, and mechanical properties. Modifying the surface of graphene is extremely significant to enable its incorporation into applications of interest. We demonstrated the ability of chemically modified graphene sheets to act as GNP stabilizing templates in solution, and utilized this to process GNP composites of graphene. We discovered that GNPs synthesized by chemical or microwave reduction stabilize on graphene-oxide sheets to form snow-flake morphologies and bare-surfaces respectively. These hybrid nano constructs were extensively studied to understand the effect and nature of GNPs

  13. Transient terahertz photoconductivity measurements of minority-carrier lifetime in tin sulfide thin films: Advanced metrology for an early stage photovoltaic material

    Science.gov (United States)

    Jaramillo, R.; Sher, Meng-Ju; Ofori-Okai, Benjamin K.; Steinmann, V.; Yang, Chuanxi; Hartman, Katy; Nelson, Keith A.; Lindenberg, Aaron M.; Gordon, Roy G.; Buonassisi, T.

    2016-01-01

    Materials research with a focus on enhancing the minority-carrier lifetime of the light-absorbing semiconductor is key to advancing solar energy technology for both early stage and mature material platforms alike. Tin sulfide (SnS) is an absorber material with several clear advantages for manufacturing and deployment, but the record power conversion efficiency remains below 5%. We report measurements of bulk and interface minority-carrier recombination rates in SnS thin films using optical-pump, terahertz-probe transient photoconductivity (TPC) measurements. Post-growth thermal annealing in H2S gas increases the minority-carrier lifetime, and oxidation of the surface reduces the surface recombination velocity. However, the minority-carrier lifetime remains below 100 ps for all tested combinations of growth technique and post-growth processing. Significant improvement in SnS solar cell performance will hinge on finding and mitigating as-yet-unknown recombination-active defects. We describe in detail our methodology for TPC experiments, and we share our data analysis routines in the form freely available software.

  14. Foodstuffs preservation by ionization

    International Nuclear Information System (INIS)

    This document contains all the papers presented at the meeting on foodstuffs preservation by ionization. These papers deal especially with the food ionization process, its development and the view of the food industry on ionization. Refs and figs (F.M.)

  15. Ionization Energies of Lanthanides

    Science.gov (United States)

    Lang, Peter F.; Smith, Barry C.

    2010-01-01

    This article describes how data are used to analyze the pattern of ionization energies of the lanthanide elements. Different observed pathways of ionization between different ground states are discussed, and the effects of pairing, exchange, and orbital interactions on ionization energies of the lanthanides are evaluated. When all the above…

  16. New constraints on the escape of ionizing photons from starburst galaxies using ionization-parameter mapping

    Energy Technology Data Exchange (ETDEWEB)

    Zastrow, Jordan; Oey, M. S. [Department of Astronomy, University of Michigan, 500 Church Street, 830 Dennison, Ann Arbor, MI 48109-1042 (United States); Veilleux, Sylvain [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); McDonald, Michael, E-mail: jazast@umich.edu [Kavli Institute for Astrophysics and Space Research, MIT, Cambridge, MA 02139 (United States)

    2013-12-10

    The fate of ionizing radiation in starburst galaxies is key to understanding cosmic reionization. However, the galactic parameters on which the escape fraction of ionizing radiation depend are not well understood. Ionization-parameter mapping provides a simple, yet effective, way to study the radiative transfer in starburst galaxies. We obtain emission-line ratio maps of [S III]/[S II] for six, nearby, dwarf starbursts: NGC 178, NGC 1482, NGC 1705, NGC 3125, NGC 7126, and He 2-10. The narrowband images are obtained with the Maryland-Magellan Tunable Filter at Las Campanas Observatory. Using these data, we previously reported the discovery of an optically thin ionization cone in NGC 5253, and here we also discover a similar ionization cone in NGC 3125. This latter cone has an opening angle of 40° ± 5° (0.4 sr), indicating that the passageways through which ionizing radiation may travel correspond to a small solid angle. Additionally, there are three sample galaxies that have winds and/or superbubble activity, which should be conducive to escaping radiation, yet they are optically thick. These results support the scenario that an orientation bias limits our ability to directly detect escaping Lyman continuum in many starburst galaxies. A comparison of the star formation properties and histories of the optically thin and thick galaxies is consistent with the model that high escape fractions are limited to galaxies that are old enough (≳3 Myr) for mechanical feedback to have cleared optically thin passageways in the interstellar medium, but young enough (≲5 Myr) that the ionizing stars are still present.

  17. Resonance ionization spectroscopy 1986

    International Nuclear Information System (INIS)

    The paper presents the proceedings of the Third International Symposium on Resonance Ionization Spectroscopy and its Applications, held at the University College of Swansea, Wales, 1986. The Symposium is divided into eight main sections entitled: photophysics and spectroscopy, noble gas atom counting, resonance ionization mass spectrometry, materials and surface analysis, small molecules, medical and environmental applications, resonance ionization and materials separation, and elementary particles and nuclear physics. Thirty papers were chosen for INIS and indexed separately. (U.K.)

  18. Ionizing Radiation and Life

    OpenAIRE

    Dartnell, L. R.

    2011-01-01

    Ionizing radiation is a ubiquitous feature of the Cosmos, from exogenous cosmic rays (CR) to the intrinsic mineral radioactivity of a habitable world, and its influences on the emergence and persistence of life are wide-ranging and profound. Much attention has already been focused on the deleterious effects of ionizing radiation on organisms and the complex molecules of life, but ionizing radiation also performs many crucial functions in the generation of habitable planetary environments and ...

  19. Abnormal ionization in sonoluminescence

    Institute of Scientific and Technical Information of China (English)

    张文娟; 安宇

    2015-01-01

    Sonoluminescence is a complex phenomenon, the mechanism of which remains unclear. The present study reveals that an abnormal ionization process is likely to be present in the sonoluminescing bubble. To fit the experimental data of previous studies, we assume that the ionization energies of the molecules and atoms in the bubble decrease as the gas density increases and that the decrease of the ionization energy reaches about 60%–70%as the bubble flashes, which is difficult to explain by using previous models.

  20. High spatial resolution dosimetric response maps for radiotherapy ionization chambers measured using kilovoltage synchrotron radiation

    Science.gov (United States)

    Butler, D. J.; Stevenson, A. W.; Wright, T. E.; Harty, P. D.; Lehmann, J.; Livingstone, J.; Crosbie, J. C.

    2015-11-01

    Small circular beams of synchrotron radiation (0.1 mm and 0.4 mm in diameter) were used to irradiate ionization chambers of the types commonly used in radiotherapy. By scanning the chamber through the beam and measuring the ionization current, a spatial map of the dosimetric response of the chamber was recorded. The technique is able to distinguish contributions to the large-field ionization current from the chamber walls, central electrode and chamber stem. Scans were recorded for the NE 2571 Farmer chamber, the PTW 30013, IBA FC65-G Farmer-type chambers, the NE 2611A and IBA CC13 thimble chambers, the PTW 31006 and 31014 pinpoint chambers, the PTW Roos and Advanced Markus plane-parallel chambers, and the PTW 23342 thin-window soft x-ray chamber. In all cases, large contributions to the response arise from areas where the incident beam grazes the cavity surfaces. Quantitative as well as qualitative information about the relative chamber response was extracted from the maps, including the relative contribution of the central electrode. Line scans using monochromatic beams show the effect of the photon energy on the chamber response. For Farmer-type chambers, a simple Monte Carlo model was in good agreement with the measured response.

  1. High spatial resolution dosimetric response maps for radiotherapy ionization chambers measured using kilovoltage synchrotron radiation.

    Science.gov (United States)

    Butler, D J; Stevenson, A W; Wright, T E; Harty, P D; Lehmann, J; Livingstone, J; Crosbie, J C

    2015-11-21

    Small circular beams of synchrotron radiation (0.1 mm and 0.4 mm in diameter) were used to irradiate ionization chambers of the types commonly used in radiotherapy. By scanning the chamber through the beam and measuring the ionization current, a spatial map of the dosimetric response of the chamber was recorded. The technique is able to distinguish contributions to the large-field ionization current from the chamber walls, central electrode and chamber stem. Scans were recorded for the NE 2571 Farmer chamber, the PTW 30013, IBA FC65-G Farmer-type chambers, the NE 2611A and IBA CC13 thimble chambers, the PTW 31006 and 31014 pinpoint chambers, the PTW Roos and Advanced Markus plane-parallel chambers, and the PTW 23342 thin-window soft x-ray chamber. In all cases, large contributions to the response arise from areas where the incident beam grazes the cavity surfaces. Quantitative as well as qualitative information about the relative chamber response was extracted from the maps, including the relative contribution of the central electrode. Line scans using monochromatic beams show the effect of the photon energy on the chamber response. For Farmer-type chambers, a simple Monte Carlo model was in good agreement with the measured response. PMID:26510214

  2. High spatial resolution dosimetric response maps for radiotherapy ionization chambers measured using kilovoltage synchrotron radiation

    International Nuclear Information System (INIS)

    Small circular beams of synchrotron radiation (0.1 mm and 0.4 mm in diameter) were used to irradiate ionization chambers of the types commonly used in radiotherapy. By scanning the chamber through the beam and measuring the ionization current, a spatial map of the dosimetric response of the chamber was recorded. The technique is able to distinguish contributions to the large-field ionization current from the chamber walls, central electrode and chamber stem. Scans were recorded for the NE 2571 Farmer chamber, the PTW 30013, IBA FC65-G Farmer-type chambers, the NE 2611A and IBA CC13 thimble chambers, the PTW 31006 and 31014 pinpoint chambers, the PTW Roos and Advanced Markus plane-parallel chambers, and the PTW 23342 thin-window soft x-ray chamber. In all cases, large contributions to the response arise from areas where the incident beam grazes the cavity surfaces. Quantitative as well as qualitative information about the relative chamber response was extracted from the maps, including the relative contribution of the central electrode. Line scans using monochromatic beams show the effect of the photon energy on the chamber response. For Farmer-type chambers, a simple Monte Carlo model was in good agreement with the measured response. (paper)

  3. Multiphoton ionization of atoms

    International Nuclear Information System (INIS)

    The paper is devoted to the analysis of high intensity effects which result from multiphoton ionization of atoms in a high laser intensity, ranging from 1010 to 1015 W cm-2. Resonant multiphoton ionization of atoms, the production of multiply charged ions, and electron energy spectra, are all discussed. (U.K.)

  4. Application of ionizing radiation

    International Nuclear Information System (INIS)

    Fundamental studies by the Nuclear Research Institute concerning the use of ionizing radiations are reported. The ROZA irradiation plant is used for sterilization in medicine and for historic objects preservation. Ionizing radiation is used in the radiation treatment of cables and drinking water. Radiopharmaceuticals are developed. The Institute is an all-state centre for research and development of semiconductor detectors. (M.S.)

  5. Multiphoton ionization of atoms

    International Nuclear Information System (INIS)

    This article provides an overview of the current understanding of multiphoton ionization of atoms. It begins with an introductory section to explain the background of the subject. Then the article develops the three topics which have been central themes of discussion in multiphoton ionization of atoms these past few years: multiply charged ion production, very high order harmonic generation, and above-threshold ionization, a name given to the absorption of a very large number of photons by an already ionized electron. A large part of the review is devoted to some theoretical aspects of multiphoton ionization of atoms and especially non-perturbative theories. Finally the article considers the very near future prospects of laser-electron interactions and more generally laser-matter interactions at 1018 -1019 W cm-2, an intensity range now within reach due to new short pulse laser technology. (author)

  6. New Constraints on the Escape of Ionizing Photons From Starburst Galaxies Using Ionization-Parameter Mapping

    CERN Document Server

    Zastrow, Jordan; Veilleux, Sylvain; McDonald, Michael

    2013-01-01

    The fate of ionizing radiation in starburst galaxies is key to understanding cosmic reionization. However, the galactic parameters on which the escape fraction of ionizing radiation depend are not well understood. Ionization-parameter mapping provides a simple, yet effective, way to study the radiative transfer in starburst galaxies. We obtain emission-line ratio maps of [SIII]/[SII] for six, nearby, dwarf starbursts: NGC 178, NGC 1482, NGC 1705, NGC 3125, NGC 7126, and He 2-10. The narrow-band images are obtained with the Maryland-Magellan Tunable Filter at Las Campanas Observatory. Using these data, we previously reported the discovery of an optically thin ionization cone in NGC 5253, and here we also discover a similar ionization cone in NGC 3125. This latter cone has an opening angle of 40+/-5 degrees (0.4 ster), indicating that the passageways through which ionizing radiation may travel correspond to a small solid angle. Additionally, there are three sample galaxies that have winds and/or superbubble act...

  7. SYNTHESIZED SPECTRA OF OPTICALLY THIN EMISSION LINES PRODUCED BY THE BIFROST STELLAR ATMOSPHERE CODE, INCLUDING NONEQUILIBRIUM IONIZATION EFFECTS: A STUDY OF THE INTENSITY, NONTHERMAL LINE WIDTHS, AND DOPPLER SHIFTS

    Energy Technology Data Exchange (ETDEWEB)

    Olluri, K.; Gudiksen, B. V.; Hansteen, V. H.; Pontieu, B. De, E-mail: kosovare.olluri@astro.uio.no [Institute of Theoretical Astrophysics, University of Oslo, P. O. Box 1029 Blindern, NO-0315 Oslo (Norway)

    2015-03-20

    In recent years realistic 3D numerical models of the solar atmosphere have become available. The models attempt to recreate the solar atmosphere and mimic observations in the best way, in order to make it possible to couple complicated observations with physical properties such as the temperatures, densities, velocities, and magnetic fields. We here present a study of synthetic spectra created using the Bifrost code in order to assess how well they fit with previously taken solar data. A study of the synthetic intensity, nonthermal line widths, Doppler shifts, and correlations between any two of these three components of the spectra first assuming statistical equilibrium is made, followed by a report on some of the effects nonequilibrium ionization will have on the synthesized spectra. We find that the synthetic intensities compare well with the observations. The synthetic observations depend on the assumed resolution and point-spread function (PSF) of the instrument, and we find a large effect on the results, especially for intensity and nonthermal line width. The Doppler shifts produce the reported persistent redshifts for the transition region (TR) lines and blueshifts for the upper TR and corona lines. The nonthermal line widths reproduce the well-known turnoff point around (2–3) × 10{sup 5} K, but with much lower values than those observed. The nonthermal line widths tend to increase with decreasing assumed instrumental resolution, also when nonequilibrium ionization is included. Correlations between the nonthermal line width of any two TR line studies as reported by Chae et al. are reproduced, while the correlations of intensity to line width are reproduced only after applying a PSF to the data. Doppler shift correlations reported by Doschek for the TR lines and correlations of Doppler shift to nonthermal line width of the Fe xii{sub 19.5} line reported by Doschek et al. are reproduced.

  8. Biological Effects of Ionizing Radiation

    Science.gov (United States)

    Ingram, M.; Mason, W. B.; Whipple, G. H.; Howland, J. W.

    1952-04-07

    This report presents a review of present knowledge and concepts of the biological effects of ionizing radiations. Among the topics discussed are the physical and chemical effects of ionizing radiation on biological systems, morphological and physiological changes observed in biological systems subjected to ionizing radiations, physiological changes in the intact animal, latent changes following exposure of biological systems to ionizing radiations, factors influencing the biological response to ionizing radiation, relative effects of various ionizing radiations, and biological dosimetry.

  9. Abnormal ionization in sonoluminescence

    Science.gov (United States)

    Zhang, Wen-Juan; An, Yu

    2015-04-01

    Sonoluminescence is a complex phenomenon, the mechanism of which remains unclear. The present study reveals that an abnormal ionization process is likely to be present in the sonoluminescing bubble. To fit the experimental data of previous studies, we assume that the ionization energies of the molecules and atoms in the bubble decrease as the gas density increases and that the decrease of the ionization energy reaches about 60%-70% as the bubble flashes, which is difficult to explain by using previous models. Project supported by the Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20120002110031) and the National Natural Science Foundation of China (Grant No. 11334005).

  10. Quantitation of repaglinide and metabolites in mouse whole-body thin tissue sections using droplet-based liquid microjunction surface sampling-high-performance liquid chromatography-electrospray ionization tandem mass spectrometry.

    Science.gov (United States)

    Chen, Weiqi; Wang, Lifei; Van Berkel, Gary J; Kertesz, Vilmos; Gan, Jinping

    2016-03-25

    Herein, quantitation aspects of a fully automated autosampler/HPLC-MS/MS system applied for unattended droplet-based surface sampling of repaglinide dosed thin tissue sections with subsequent HPLC separation and mass spectrometric analysis of parent drug and various drug metabolites were studied. Major organs (brain, lung, liver, kidney and muscle) from whole-body thin tissue sections and corresponding organ homogenates prepared from repaglinide dosed mice were sampled by surface sampling and by bulk extraction, respectively, and analyzed by HPLC-MS/MS. A semi-quantitative agreement between data obtained by surface sampling and that by employing organ homogenate extraction was observed. Drug concentrations obtained by the two methods followed the same patterns for post-dose time points (0.25, 0.5, 1 and 2 h). Drug amounts determined in the specific tissues was typically higher when analyzing extracts from the organ homogenates. In addition, relative comparison of the levels of individual metabolites between the two analytical methods also revealed good semi-quantitative agreement. PMID:26589943

  11. Chemical synthesis of α-La{sub 2}S{sub 3} thin film as an advanced electrode material for supercapacitor application

    Energy Technology Data Exchange (ETDEWEB)

    Patil, S.J.; Kumbhar, V.S.; Patil, B.H.; Bulakhe, R.N.; Lokhande, C.D., E-mail: l_chandrakant@yahoo.com

    2014-10-25

    Highlights: • The simple, chemical method used for synthesis of lanthanum sulphide thin films. • The lanthanum sulphide thin film surface exhibited porous microstructure. • The lanthanum sulphide thin film electrode is used for supercapacitor application. - Abstract: α-La{sub 2}S{sub 3} thin films have been synthesized for the first time by successive ionic layer adsorption and reaction (SILAR) method and used for supercapacitor application. These films are characterized for crystal structure, surface morphology and wettability studies using X-ray diffraction (XRD), Fourier Transform-Raman (FT-Raman) spectroscopy, scanning electron microscopy (SEM) and contact angle measurements. The electrochemical supercapacitive performance of α-La{sub 2}S{sub 3} electrode is evaluated by cyclic voltammetry (CV), galvanostatic charge discharge (GCD) and electrochemical impedance spectroscopy (EIS) techniques. From the electrochemical study, it is seen that α-La{sub 2}S{sub 3} electrode delivers high specific capacitance of 256 F g{sup −1} at scan rate of 5 mV s{sup −1} with cycling stability of 85% over 1000 cycles. Such La{sub 2}S{sub 3} electrode has great application in supercapacitor device for energy storage.

  12. MULTIPHOTON IONIZATION OF ATOMS

    OpenAIRE

    Mainfray, G.

    1985-01-01

    Multiphoton ionization of one-electron atoms, such as atomic hydrogen and alkaline atoms, is well understood and correctly described by rigorous theoretical models. The present paper will be devoted to collisionless multiphoton ionization of many-electron atoms as rare gases. It induces removal of several electrons and the production of multiply charged ions. Up to Xe5+ ions are produced in Xe atoms. Doubly charged ions can be produced, either by simultaneous excitation of two electrons, or b...

  13. "Magic" Ionization Mass Spectrometry.

    Science.gov (United States)

    Trimpin, Sarah

    2016-01-01

    The systematic study of the temperature and pressure dependence of matrix-assisted ionization (MAI) led us to the discovery of the seemingly impossible, initially explained by some reviewers as either sleight of hand or the misinterpretation by an overzealous young scientist of results reported many years before and having little utility. The “magic” that we were attempting to report was that with matrix assistance, molecules, at least as large as bovine serum albumin (66 kDa), are lifted into the gas phase as multiply charged ions simply by exposure of the matrix:analyte sample to the vacuum of a mass spectrometer. Applied heat, a laser, or voltages are not necessary to achieve charge states and ion abundances only previously observed with electrospray ionization (ESI). The fundamentals of how solid phase volatile or nonvolatile compounds are converted to gas-phase ions without added energy currently involves speculation providing a great opportunity to rethink mechanistic understanding of ionization processes used in mass spectrometry. Improved understanding of the mechanism(s) of these processes and their connection to ESI and matrix-assisted laser desorption/ionization may provide opportunities to further develop new ionization strategies for traditional and yet unforeseen applications of mass spectrometry. This Critical Insights article covers developments leading to the discovery of a seemingly magic ionization process that is simple to use, fast, sensitive, robust, and can be directly applied to surface characterization using portable or high performance mass spectrometers. PMID:26486514

  14. "Magic" Ionization Mass Spectrometry

    Science.gov (United States)

    Trimpin, Sarah

    2016-01-01

    The systematic study of the temperature and pressure dependence of matrix-assisted ionization (MAI) led us to the discovery of the seemingly impossible, initially explained by some reviewers as either sleight of hand or the misinterpretation by an overzealous young scientist of results reported many years before and having little utility. The "magic" that we were attempting to report was that with matrix assistance, molecules, at least as large as bovine serum albumin (66 kDa), are lifted into the gas phase as multiply charged ions simply by exposure of the matrix:analyte sample to the vacuum of a mass spectrometer. Applied heat, a laser, or voltages are not necessary to achieve charge states and ion abundances only previously observed with electrospray ionization (ESI). The fundamentals of how solid phase volatile or nonvolatile compounds are converted to gas-phase ions without added energy currently involves speculation providing a great opportunity to rethink mechanistic understanding of ionization processes used in mass spectrometry. Improved understanding of the mechanism(s) of these processes and their connection to ESI and matrix-assisted laser desorption/ionization may provide opportunities to further develop new ionization strategies for traditional and yet unforeseen applications of mass spectrometry. This Critical Insights article covers developments leading to the discovery of a seemingly magic ionization process that is simple to use, fast, sensitive, robust, and can be directly applied to surface characterization using portable or high performance mass spectrometers.

  15. The GODDESS ionization chamber: developing robust windows

    Science.gov (United States)

    Blanchard, Rose; Baugher, Travis; Cizewski, Jolie; Pain, Steven; Ratkiewicz, Andrew; Goddess Collaboration

    2015-10-01

    Reaction studies of nuclei far from stability require high-efficiency arrays of detectors and the ability to identify beam-like particles, especially when the beam is a cocktail beam. The Gammasphere ORRUBA Dual Detectors for Experimental Structure Studies (GODDESS) is made up of the Oak Ridge-Rutgers University Barrel Array (ORRUBA) of silicon detectors for charged particles inside of the gamma-ray detector array Gammasphere. A high-rate ionization chamber is being developed to identify beam-like particles. Consisting of twenty-one alternating anode and cathode grids, the ionization chamber sits downstream of the target chamber and is used to measure the energy loss of recoiling ions. A critical component of the system is a thin and robust mylar window which serves to separate the gas-filled ionization chamber from the vacuum of the target chamber with minimal energy loss. After construction, windows were tested to assure that they would not break below the required pressure, causing harm to the wire grids. This presentation will summarize the status of the ionization chamber and the results of the first tests with beams. This work is supported in part by the U.S. Department of Energy and National Science Foundation.

  16. Ionization Front Instabilities in Primordial H II Regions

    CERN Document Server

    Whalen, Daniel

    2007-01-01

    Radiative cooling by metals in shocked gas mediates the formation of ionization front instabilities in the galaxy today that are responsible for a variety of phenomena in the interstellar medium, from the morphologies of nebulae to triggered star formation in molecular clouds. An important question in early reionization and chemical enrichment of the intergalactic medium is whether such instabilities arose in the H II regions of the first stars and primeval galaxies, which were devoid of metals. We present three-dimensional numerical simulations that reveal both shadow and thin-shell instabilities readily formed in primordial gas. We find that the hard UV spectra of Population III stars broadened primordial ionization fronts, causing H2 formation capable of inciting violent thin- shell instabilities in D-type fronts, even in the presence of intense Lyman-Werner flux. The high post- front gas temperatures associated with He ionization sustained and exacerbated shadow instabilities, unaided by molecular hydroge...

  17. Research Advances in Chemical Thinning of Flowers and Fruits in Fruit Tree%果树化学疏花疏果研究进展

    Institute of Scientific and Technical Information of China (English)

    薛晓敏; 路超; 聂佩显; 王翠玲; 王金政

    2012-01-01

    首先综述了世界各国常用的化学疏花疏果剂,如西维因、石硫合剂、萘乙酸等,归纳总结了各自的研究进展、作用机理、使用方法和优缺点等;进而探讨了新型疏花疏果剂的种类和应用情况;最后讨论了化学疏花疏果剂今后的发展趋势.%This paper firstly summarized the widely used flower and fruit thinning chemicals for fruit tree in the world, such as sevin, lime sulfur, NAA and so on, concluded the research progress, mechanism of action, method of application, advantages and disadvantages of each chemical, then discussed the type and application status of new flower and fruit thinning chemicals, and finally pointed out the developmental trend of flower and fruit thinning chemicals in the future.

  18. Fuel cell with ionization membrane

    Science.gov (United States)

    Hartley, Frank T. (Inventor)

    2007-01-01

    A fuel cell is disclosed comprising an ionization membrane having at least one area through which gas is passed, and which ionizes the gas passing therethrough, and a cathode for receiving the ions generated by the ionization membrane. The ionization membrane may include one or more openings in the membrane with electrodes that are located closer than a mean free path of molecules within the gas to be ionized. Methods of manufacture are also provided.

  19. Stochastic processes in muon ionization cooling

    Science.gov (United States)

    Errede, D.; Makino, K.; Berz, M.; Johnstone, C. J.; Van Ginneken, A.

    2004-02-01

    A muon ionization cooling channel consists of three major components: the magnet optics, an acceleration cavity, and an energy absorber. The absorber of liquid hydrogen contained by thin aluminum windows is the only component which introduces stochastic processes into the otherwise deterministic acceleration system. The scattering dynamics of the transverse coordinates is described by Gaussian distributions. The asymmetric energy loss function is represented by the Vavilov distribution characterized by the minimum number of collisions necessary for a particle undergoing loss of the energy distribution average resulting from the Bethe-Bloch formula. Examples of the interplay between stochastic processes and deterministic beam dynamics are given.

  20. Effect of post-deposition annealing temperature on RF-sputtered HfO2 thin film for advanced CMOS technology

    Science.gov (United States)

    Khairnar, A. G.; Mahajan, A. M.

    2013-01-01

    Structural and electrical properties of HfO2 gate-dielectric metal-oxide-semiconductor (MOS) capacitors deposited by sputtering are investigated. The HfO2 high-k thin films have been deposited on p-type silicon wafer using RF-Magnetron sputtering technique. The Ellipsometric, FTIR and AFM characterizations have been done. The thickness of the as deposited film is measured to be 35.38 nm. Post deposition annealing in N2 ambient is carried out at 350, 550, 750 °C. The chemical bonding and surface morphology of the film is verified using FTIR and AFM respectively. The structural characterization confirmed that the thin film was free of physical defects and root mean square surface roughness decreased as the annealing temperature increased. The smooth surface HfO2 thin films were used for Al/HfO2/p-Si MOS structures fabrication. The fabricated Al/HfO2/p-Si structure had been used for extracting electrical properties such as dielectric constant, EOT, interface trap density and leakage current density through capacitance voltage and current voltage measurements. The interface state density extracted from the G-V measurement using Hill Coleman method. Sample annealed at 750 °C showed the lowest interface trap density (3.48 × 1011 eV-1 cm-2), effective oxide charge (1.33 × 1012 cm-2) and low leakage current density (3.39 × 10-9 A cm-2) at 1.5 V.

  1. The critical ionization velocity

    International Nuclear Information System (INIS)

    The critical ionization velocity effect was first proposed in the context of space plasmas. This effect occurs for a neutral gas moving through a magnetized plasma and leads to rapid ionization and braking of the relative motion when a marginal velocity, 'the critical velocity', is exceeded. Laboratory experiments have clearly established the significance of the critical velocity and have provided evidence for an underlying mechanism which relies on the combined action of electron impact ionization and a collective plasma interaction heating electrons. There is experimental support for such a mechanism based on the heating of electrons by the modified two-stream instability as part of a feedback process. Several applications to space plasmas have been proposed and the possibility of space experiments has been discussed. (author)

  2. The ionizing treatment of food

    International Nuclear Information System (INIS)

    This book of proceedings contains the talks given by the members of the Society of chemical experts of France (SECF) and by various specialists of the ionizing treatment during the scientific days of September 25-26, 1997. The aim of this meeting was to reconsider the effects of ionization from a scientific point of view and apart from the polemics generated by this domain. The following topics were discussed successively: source and characterization of a ionizing treatment, biological effects of ionization on food and the expected consequences, the ionizing treatment and the reduction of the vitamin C content of fruits and vegetables, is it safe to eat irradiated food?, the organoleptic modifications of food after ionization, quality assurance of dosimetry measurements in an industrial installation of food ionization, the French and European regulations in food ionization, the detection of irradiated foodstuffs, processed food and complex lipid matrices, sterilization of dishes for immuno-depressed patients using ionization. (J.S.)

  3. Kesterite thin-film solar cells: advances in materials modelling of Cu{sub 2}ZnSnS{sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Walsh, Aron [Centre for Sustainable Chemical Technologies and Department of Chemistry, University of Bath, Claverton Down, Bath (United Kingdom); Chen, Shiyou [Key Laboratory for Computational Physical Sciences (MOE), Fudan University, Shanghai (China); Surface Physics Laboratory, Fudan University, Shanghai (China); Key Laboratory of Polar Materials and Devices (MOE), East China Normal University, Shanghai (China); Wei, Su-Huai [National Renewable Energy Laboratory, Golden, Colorado (United States); Gong, Xin-Gao [Key Laboratory for Computational Physical Sciences (MOE), Fudan University, Shanghai (China); Surface Physics Laboratory, Fudan University, Shanghai (China)

    2012-04-15

    Quaternary semiconducting materials based on the kesterite (A{sub 2}BCX{sub 4}) mineral structure are the most promising candidates to overtake the current generation of light-absorbing materials for thin-film solar cells. Cu{sub 2}ZnSnS{sub 4} (CZTS), Cu{sub 2}ZnSnSe{sub 4} (CZTSe) and their alloy Cu{sub 2}ZnSn(Se,S){sub 4} consist of abundant, low-cost and non-toxic elements, unlike current CdTe and Cu(In,Ga)Se{sub 2} based technologies. Zinc-blende related structures are formed by quaternary compounds, but the complexity associated with the multi-component system introduces difficulties in material growth, characterization, and application. First-principles electronic structure simulations, performed over the past five years, that address the structural, electronic, and defect properties of this family of compounds are reviewed. Initial predictions of the bandgaps and crystal structures have recently been verified experimentally. The calculations highlight the role of atomic disorder on the cation sub-lattice, as well as phase separation of Cu{sub 2}ZnSnS{sub 4} into ZnS and CuSnS{sub 3}, on the material performance for light-to-electricity conversion in photovoltaic devices. Finally, the current grand challenges for materials modeling of thin-film solar cells are highlighted. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  4. Fundamental Materials Research and Advanced Process Development for Thin-Film CIS-Based Photovoltaics: Final Technical Report, 2 October 2001 - 30 September 2005

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, T. J.; Li, S. S.; Crisalle, O. D.; Craciun, V.

    2006-09-01

    The objectives for this thin-film copper-indium-diselenide (CIS) solar cell project cover the following areas: Develop and characterize buffer layers for CIS-based solar cell; grow and characterize chemical-bath deposition of Znx Cd1-xS buffer layers grown on CIGS absorbers; study effects of buffer-layer processing on CIGS thin films characterized by the dual-beam optical modulation technique; grow epitaxial CuInSe2 at high temperature; study the defect structure of CGS by photoluminescence spectroscopy; investigate deep-level defects in Cu(In,Ga)Se2 solar cells by deep-level transient spectroscopy; conduct thermodynamic modeling of the isothermal 500 C section of the Cu-In-Se system using a defect model; form alpha-CuInSe2 by rapid thermal processing of a stacked binary compound bilayer; investigate pulsed non-melt laser annealing on the film properties and performance of Cu(In,Ga)Se2 solar cells; and conduct device modeling and simulation of CIGS solar cells.

  5. Polyacrylonitrile block copolymers for the preparation of a thin carbon coating around TiO2 nanorods for advanced lithium-ion batteries.

    Science.gov (United States)

    Oschmann, Bernd; Bresser, Dominic; Tahir, Muhammad Nawaz; Fischer, Karl; Tremel, Wolfgang; Passerini, Stefano; Zentel, Rudolf

    2013-11-01

    Herein, a new method for the realization of a thin and homogenous carbonaceous particle coating, made by carbonizing RAFT polymerization derived block copolymers anchored on anatase TiO2 nanorods, is presented. These block copolymers consist of a short anchor block (based on dopamine) and a long, easily graphitizable block of polyacrylonitrile. The grafting of such block copolymers to TiO2 nanorods creates a polymer shell, which can be visualized by atomic force microscopy (AFM). Thermal treatment at 700 °C converts the polyacrylonitrile block to partially graphitic structures (as determined by Raman spectroscopy), establishing a thin carbon coating (as determined by transmission electron microscopy, TEM, analysis). The carbon-coated TiO2 nanorods show improved electrochemical performance in terms of achievable specific capacity and, particularly, long-term cycling stability by reducing the average capacity fading per cycle from 0.252 mAh g(-1) to only 0.075 mAh g(-1) . PMID:24115201

  6. Thin films and nanomaterials

    International Nuclear Information System (INIS)

    The objective of this book is to disseminate the most recent research in Thin Films, Nanomaterials, Corrosion and Metallurgy presented at the International Conference on Advanced Materials (ICAM 2011) held in PSG College of Technology, Coimbatore, India during 12-16 December 2011. The book is a compilation of 113 chapters written by active researchers providing information and critical insights into the recent advancements that have taken place. Important new applications are possible today in the fields of microelectronics, opto-electronics, metallurgy and energy by the application of thin films on solid surfaces. Recent progress in high vacuum technology and new materials has a remarkable effect in thin film quality and cost. This has led to the development of new single or multi-layered thin film devices with diverse applications in a multitude of production areas, such as optics, thermal barrier coatings and wear protections, enhancing service life of tools and to protect materials against thermal and atmospheric influence. On the other hand, thin film process techniques and research are strongly related to the basic research activities in nano technology, an increasingly important field with countless opportunities for applications due to the emergence of new properties at the nanoscale level. Materials and structures that are designed and fabricated at the nano scale level, offer the potential to produce new devices and processes that may enhance efficiencies and reduce costs in many areas, as photovoltaic systems, hydrogen storage, fuel cells and solar thermal systems. In the book, the contributed papers are classified under two sections i) thin films and ii) nanomaterials. The thin film section includes single or multi layer conducting, insulating or semiconducting films synthesized by a wide variety of physical or chemical techniques and characterized or analyzed for different applications. The nanomaterials section deals with novel or exciting materials

  7. Ionization chamber smoke detectors

    International Nuclear Information System (INIS)

    One kind of smoke detector, the ionization-type, is regulated by the Atomic Energy Control Board (AECB) because it uses a radioactive substance in its mechanism. Radioactivity and radiation are natural phenomena, but they are not very familiar to the average householder. This has led to a number of questions being asked of the AECB. These questions and AECB responses are outlined

  8. Alkali ionization detector

    Science.gov (United States)

    Hrizo, John; Bauerle, James E.; Witkowski, Robert E.

    1982-01-01

    A calibration filament containing a sodium-bearing compound is included in combination with the sensing filament and ion collector plate of a sodium ionization detector to permit periodic generation of sodium atoms for the in-situ calibration of the detector.

  9. Applications of ionizing radiations

    International Nuclear Information System (INIS)

    The R and D activities of the application of Ionizing Radiations Program is comprised to four subprograms: Food and Agricultural Productions Irradiation; Radiation and Radioisotopes Applications in Industry and Environment; Radioactive Sources and Radiation Applications in Human Health; and Radioactive Facilities and Equipment for Nuclear Techniques Applications

  10. Ionization beam scanner

    CERN Multimedia

    CERN PhotoLab

    1973-01-01

    Inner structure of an ionization beam scanner, a rather intricate piece of apparatus which permits one to measure the density distribution of the proton beam passing through it. On the outside of the tank wall there is the coil for the longitudinal magnetic field, on the inside, one can see the arrangement of electrodes creating a highly homogeneous transverse electric field.

  11. All short pulse multiphoton ionization is resonant ionization

    International Nuclear Information System (INIS)

    Energy resolved photoelectron spectra of multiphoton ionization taken with a 300 fs laser pulse at 616 nm shows that the ionization probability is highly structured as a function of laser intensity. The spectrum is consistent with all of the ionization occurring at intensity resonances

  12. Thin film processes

    CERN Document Server

    Vossen, John L

    1978-01-01

    Remarkable advances have been made in recent years in the science and technology of thin film processes for deposition and etching. It is the purpose of this book to bring together tutorial reviews of selected filmdeposition and etching processes from a process viewpoint. Emphasis is placed on the practical use of the processes to provide working guidelines for their implementation, a guide to the literature, and an overview of each process.

  13. Transient terahertz photoconductivity measurements of minority-carrier lifetime in tin sulfide thin films: Advanced metrology for an early stage photovoltaic material

    OpenAIRE

    Jaramillo, R.; Sher, Meng-Ju; Ofori-Okai, Benjamin; Steinmann, V; Yang, Chuanxi; Hartman, Katy; Nelson, Keith; Lindenberg, Aaron; Gordon, Roy Gerald; Buonsassisi, T

    2016-01-01

    Materials research with a focus on enhancing the minority-carrier lifetime of the light-absorbing semiconductor is key to advancing solar energy technology for both early stage and mature material platforms alike. Tin sulfide (SnS) is an absorber material with several clear advantages for manufacturing and deployment, but the record power conversion efficiency remains below 5%. We report measurements of bulk and interface minority-carrier recombination rates in SnSthin films using optical-pum...

  14. Electrochemical reactions and ionization processes

    OpenAIRE

    Girault, Hubert; Liu, Baohong; Qiao, Liang; Bi, Hongyan; Prudent, Michel; Lion, Niels; Abonnenc, Mélanie

    2010-01-01

    Electrochemical or photo-electrochemical reactions in both electrospray ionization and laser desorption ionization are discussed stressing the role of the electrode reaction in influencing the ionization process. In particular, upon application of a high voltage during electrospray ionization, the emitter includes a working electrode, where redox reactions are observed, such as electro-generation of benzoquinone and metal ions. In contrast, the target plate in laser-induced desorption ionizat...

  15. Multiphoton ionization of polarized atoms

    International Nuclear Information System (INIS)

    A theory is derived for the multiphoton ionization of polarized atoms. The angular distributions of the differential and total ionization probabilities are studied for various polarizations of the electromagnetic radiation. The circular dichroism is also studied. The multiphoton ionization of oriented s-state atoms near a resonance is studied separately. Some relevant experiments which might be carried out are discussed

  16. Multiphoton ionization of polarized atoms

    International Nuclear Information System (INIS)

    A theory of multiphoton ionization of polarized atoms is developed. The angular dependences of the different and total ionization probabilities for various polarizations of the radiation and the circular dichroism effect are investigated. Multiphoton ionization of oriented in the s-states near resonance is considered separately

  17. L-Shell Ionization Study of Tungsten by Electron Impact

    Institute of Scientific and Technical Information of China (English)

    彭秀峰; 何福庆; 龙先灌; 安竹; 罗正明

    2001-01-01

    L-shell partial production cross sections of Lα-, Lβ- , Lγ- rays by electron impact were measured by observing the counts of x-rays from an impacted thin tungsten target. The total production cross sections and mean ionization cross sections were deduced from the measured results. The electron beam energy range was found to be 11-36 keV. The influence of electrons reflected by the backing on ionization cross sections has been corrected. The experimental results agree well with the theoretical predictions.

  18. Physics of ionized gases

    CERN Document Server

    Smirnov, Boris M

    2001-01-01

    A comprehensive textbook and reference for the study of the physics of ionized gasesThe intent of this book is to provide deep physical insight into the behavior of gases containing atoms and molecules from which one or more electrons have been ionized. The study of these so-called plasmas begins with an overview of plasmas as they are found in nature and created in the laboratory. This serves as a prelude to a comprehensive study of plasmas, beginning with low temperature and "ideal" plasmas and extending to radiation and particle transport phenomena, the response of plasmas to external fields, and an insightful treatment of plasma waves, plasma instabilities, nonlinear phenomena in plasmas, and the study of plasma interactions with surfaces

  19. 液基膜式薄层细胞学技术进展%Advance of liquid polyimides type thin layer cytology technology

    Institute of Scientific and Technical Information of China (English)

    马福军; 王占红; 刘海波; 刘铁军

    2011-01-01

    @@ 液基膜式薄层细胞学技术是正在探索的一项新技术,它是将细胞收集在保存液中,利用计算机控制的自动化技术制备薄层细胞涂片.其中较有代表性的是在制片中采用了微孔薄膜过滤方法的TCT技术.1996-05美国食品及药物管理局(FDA)批准把此法用于临床.1999 年被引入国内,也称TCT (ThinPrep Cytology Test) 检测.现在TCT技术已被广泛应用于宫颈癌的筛查工作中,因其具有背景干净,没有血细胞及炎细胞干扰,细胞保存完好,结构清晰等特点,亦被用于体腔积液、尿液、纤维支气管刷片、细针穿刺细胞学等其他脱落细胞学检查中[1-4].为了提高对TCT 的认识,笔者特作综述如下.

  20. Ionization by nuclear transitions

    International Nuclear Information System (INIS)

    A phenomenological description of ionization events is given that applies to both shaking transitions of the composite nucleus-atom system and the process in which the charged particles emitted in a nuclear decay transfer energy by a relatively slow ''direct collision'' final state interaction with atomic electrons. Specific areas covered include shakeoff in internal conversion, shakeoff in electron capture, shakeoff in beta decay, and inner electron ejection in alpha decay. (5 figs., 1 table)

  1. Electrospray Ionization Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Kelly, Ryan T.; Marginean, Ioan; Tang, Keqi

    2014-06-13

    Electrospray Ionization (ESI) is a process whereby gas phase ions are created from molecules in solution. As a solution exits a narrow tube in the presence of a strong electric field, an aerosol of charged droplets are is formed that produces gas phase ions as they it desolvates. ESI-MS comprises the creation of ions by ESI and the determination of their mass to charge ratio (m/z) by MS.

  2. Application of ionizing radiations

    International Nuclear Information System (INIS)

    The main subject of the application of Ionizing Radiations Program is to disseminate and consolidate techniques leading to the use of the radiation technology and radioisotopes application in Industry, Human Health, Agriculture and Environmental Preservation. This Program is divided into four subprograms: 1) Food and Agricultural Products Irradiation; 2) Radiation and Radioisotopes Applications in Industry and Environment; Radioactive Sources and Radiation Applications in Human Health; Radioactive Facilities and Equipment for Nuclear Techniques Applications

  3. Pregnancy and ionizing radiation

    International Nuclear Information System (INIS)

    Full text: In this report there will be presented the effects of ionizing radiation at the fetus and the necessary radioprotection. The biological results on the fetus, caused by the irradiation, depend on the dose of ionizing radiation that it receives and the phase of its evolution. The imminent effects of the irradiation can cause the fetus death, abnormalities and mental retardation, which are the result of overdose. The effects are carcinogenesis and leukemia, which are relative to the acceptable irradiating dose at the fetus and accounts about 0,015 % per 1 mSv. The effects of ionizing radiation depend on the phase of the fetus evolution: 1st phase (1st - 2nd week): presence of low danger; 2nd phase (3rd - 8th week): for doses >100 mSv there is the possibility of dysplasia; 3rd phase (8th week - birth): this phase concerns the results with a percentage 0,015 % per 1 mSv. We always must follow some rules of radioprotection and especially at Classical radiation use of necessary protocols (low dose), at Nuclear Medicine use of the right radioisotope and the relative field of irradiation for the protection of the adjacent healthy tissues and at Radiotherapy extreme caution is required regarding the dose and the treatment. In any case, it is forbidden to end a pregnancy when the pregnant undergoes medical exams, in which the uterus is in the beam of irradiation. The radiographer must always discuss the possibility of pregnancy. (author)

  4. Collisional ionization of Na atoms excited by one- and two-photon absorption in H2---O2---Ar flames

    NARCIS (Netherlands)

    Dijk, C.A. van; Alkemade, C.T.J.

    1980-01-01

    An ionization signal was detected when a flashlamp-pumped dye laser was tuned on resonance with various one- or two-photon transitions of Na atoms in an H2---O2---Ar flame of 1800 K at atmospheric pressure. Ionization signals were obtained by collecting the electric charge with two thin iridium prob

  5. A Miniature Laser Desorption/Ionization Time-of-Flight Mass Spectrometer for in Situ Analysis of Mars Surface Composition and Identification of Hazard in Advance of Future Manned Exploration

    Science.gov (United States)

    Getty, S. A.; Brinckerhoff, W. B.; Arevalo, R. D.; Floyd, M. M.; Li, X.; Cornish, T.; Ecelberger, S. A.

    2012-01-01

    Future landed missions to Mars will be guided by two strategic directions: (1) sample return to Earth, for comprehensive compositional analyses, as recommended by the 2011 NRC Planetary Decadal Survey; and (2) preparation for human exploration in the 2030s and beyond, as laid out by US space policy. The resultant mission architecture will likely require high-fidelity in situ chemical/organic sample analyses within an extremely constrained resource envelope. Both science goals (e.g., MEPAG Goal 1, return sample selection, etc.) as well as identification of any potential toxic and biological hazards to humans, must be addressed. Over the past several years of instrument development, we have found that the adaptable, compact, and highly capable technique of laser desorption/ionization time-of-flight mass spectrometry (LD-TOF-MS) has significant potential to contribute substantially to these dual objectives. This concept thus addresses Challenge Area 1: instrumentation and Investigation Approaches.

  6. Laser desorption/ionization mass spectrometry on nanostructured semiconductor substrates: DIOS(TM) and QuickMass(TM)

    Science.gov (United States)

    Law, K. P.

    2010-02-01

    In the era of systems biology, new analytical platforms are under demand. Desorption/ionization on silicon mass spectrometry (DIOS-MS) is a promising high throughput laser mass spectrometry approach that has attracted a lot of attention, and has been commercialized. Another substrate material manufactured by physical method has also been made commercially available under the trade name of QuickMass(TM). These two commercial substrates, DIOS(TM) and QuickMass(TM), were investigated independently from the manufacturers and were characterized by a number of advanced surface techniques. This work determined (1) the correlation between the substrate physicochemical properties and their LDI activity, (2) the feasibility of metabolic profiling from complex biological matrices and (3) the laser desorption/ionization mechanism. The DIOS(TM) substrate was characterized with a thick nano-sized porous layer, a high surface concentration of fluorocarbon and silicon oxides and super-hydrophobicity. In contrast, the QuickMass(TM) substrate consisted of a non-porous germanium thin-film. The relatively high ionization efficiency obtained from the DIOS(TM) substrate was contributed to the fluorosilane manufacturing processes and its porous morphology. Despite the QuickMass(TM) substrate being less effective, it was noted that the use of germanium affords a self-cleaning mechanism and suppresses background interference of mass spectra. The suitability of DIOS(TM) substrates for metabolic profiling of complex biological matrices was demonstrated. DIOS mass spectra of human blood plasma, human urine and animal liver tissue extracts were produced. Suitable extraction methods were found to be important, but relatively simplified approaches were sufficient. Further investigations of the DIOS desorption/ionization mechanism were carried out. The previously proposed sub-surface state reaction could be a molten-solid interfacial state reaction of the substrate and this had a significant

  7. Epicyclic helical channels for parametric resonance ionization cooling

    Energy Technology Data Exchange (ETDEWEB)

    Johson, Rolland Paul [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Derbenev, Yaroslav [Muons, Inc., Batavia, IL (United States)

    2015-08-23

    Proposed next-generation muon colliders will require major technical advances to achieve rapid muon beam cooling requirements. Parametric-resonance Ionization Cooling (PIC) is proposed as the final 6D cooling stage of a high-luminosity muon collider. In PIC, a half-integer parametric resonance causes strong focusing of a muon beam at appropriately placed energy absorbers while ionization cooling limits the beam’s angular spread. Combining muon ionization cooling with parametric resonant dynamics in this way should then allow much smaller final transverse muon beam sizes than conventional ionization cooling alone. One of the PIC challenges is compensation of beam aberrations over a sufficiently wide parameter range while maintaining the dynamical stability with correlated behavior of the horizontal and vertical betatron motion and dispersion. We explore use of a coupling resonance to reduce the dimensionality of the problem and to shift the dynamics away from non-linear resonances. PIC simulations are presented.

  8. Engineered Ionizable Side Chains.

    Science.gov (United States)

    Cymes, Gisela D; Grosman, Claudio

    2015-01-01

    One of the great challenges of mechanistic ion-channel biology is to obtain structural information from well-defined functional states. In the case of neurotransmitter-gated ion channels, the open-channel conformation is particularly elusive owing to its transient nature and brief mean lifetime. In this Chapter, we show how the analysis of single-channel currents recorded from mutants engineered to contain single ionizable side chains in the transmembrane region can provide specific information about the open-channel conformation without any interference from the closed or desensitized conformations. The method takes advantage of the fact that the alternate binding and unbinding of protons to and from an ionizable side chain causes the charge of the protein to fluctuate by 1 unit. We show that, in mutant muscle acetylcholine nicotinic receptors (AChRs), this fluctuating charge affects the rate of ion conduction in such a way that individual proton-transfer events can be identified in a most straightforward manner. From the extent to which the single-channel current amplitude is reduced every time a proton binds, we can learn about the proximity of the engineered side chain to the lumen of the pore. And from the kinetics of proton binding and unbinding, we can calculate the side-chain's affinity for protons (pK a), and hence, we can learn about the electrostatic properties of the microenvironment around the introduced ionizable group. The application of this method to systematically mutated AChRs allowed us to identify unambiguously the stripes of the M1, M2 and M3 transmembrane α-helices that face the pore's lumen in the open-channel conformation in the context of a native membrane. PMID:26381938

  9. Ionized helium afterglow study

    International Nuclear Information System (INIS)

    In order to take into account the characteristics of ionized helium, under relaxation conditions, in the determination of the unknown coefficients of the reaction rates and more particularly those of the recombination of H2+ ions, a method has been developed which consists in recovering, using a system of differential equations with coupled partial derivatives, the set of all the physical quantities which can at the moment be measured as a function of time in a helium after-discharge. The energy balance of the maxwellian electrons and the speed distribution function of the electrons were studied in details and calculated as a function of time and location in space. The non-maxwellian electrons were included in the calculations. Measurements were made over a large range of experimental conditions using 5 different diagnoses: UHF interferometry in the X band, UHF radiometry in the X band, mass spectrometry, optical absorption spectrometry and optical emission spectrometry. All experimental data, obtained at 293 deg K and at seven different pressures ranging from 5 to 100 Torr were perfectly reproduced by the proposed system of differential equations, with the same reaction rate coefficients and the same constants. The method developed here gives a complete solution for the helium after-discharge at room temperature over a wide range of experimental conditions. It underlines the important reactions within the ionized gas, gives the absolute value and the dependences of the electron-He2+ ion recombination coefficient and allows the determination of the elementary mechanisms causing these dependences. It also gives the coefficients and the reaction rates of all the other elementary mechanisms which, besides recombination, determine the relaxation of ionized helium

  10. Resonance ionization spectroscopy

    International Nuclear Information System (INIS)

    The subject of resonance ionization spectroscopy (RIS) from its inception to the present is summarized. The uses of RIS are principally analytical, and these uses are classified in several different ways for this report. The classifications are: (1) basic ways of counting atoms; (2) RIS applications according to the type of particle detector; (3) applications according to source preparation; (4) applications in chemical physics and chemistry; and (5) applications involving daughter atom detection. Each classification is discussed in some detail, and examples of specific applications are mentioned under each classification. Some other potential applications not necessarily related to these classifications are also mentioned

  11. Resonant Alfven waves in partially ionized plasmas of the solar atmosphere

    CERN Document Server

    Soler, R; Goossens, M

    2011-01-01

    Context. Magnetohydrodynamic (MHD) waves are ubiquitous in the solar atmosphere. In magnetic waveguides resonant absorption due to plasma inhomogeneity naturally transfers wave energy from large-scale motions to small-scale motions. In the cooler parts of the solar atmosphere as, e.g., the chromosphere, effects due to partial ionization may be relevant for wave dynamics and heating. Aims. We study resonant Alfven waves in partially ionized plasmas. Methods. We use the multifluid equations in the cold plasma approximation. We investigate propagating resonant MHD waves in partially ionized flux tubes. We use approximate analytical theory based on normal modes in the thin tube and thin boundary approximations along with numerical eigenvalue computations. Results. We find that the jumps of the wave perturbations across the resonant layer are the same as in fully ionized plasmas. The damping length due to resonant absorption is inversely proportional to the frequency, while that due to ion-neutral collisions is in...

  12. Advances in photovoltaic technology

    Science.gov (United States)

    Landis, G. A.; Bailey, S. G.

    1992-01-01

    The advances in solar cell efficiency, radiation tolerance, and cost in the last 10 years are presented. The potential performance of thin-film solar cells in space is examined, and the cost and the historical trends in production capability of the photovoltaics industry are considered with respect to the needs of satellite solar power systems. Attention is given to single-crystal cells, concentrator and cascade cells, and thin-film solar cells.

  13. Thin Places

    OpenAIRE

    Lockwood, Sandra Elizabeth

    2013-01-01

    This inquiry into the three great quests of the twentieth century–the South Pole, Mount Everest, and the Moon–examines our motivations to venture into these sublime, yet life-taking places. The Thin Place was once the destination of the religious pilgrim seeking transcendence in an extreme environment. In our age, the Thin Place quest has morphed into a challenge to evolve beyond the confines of our own physiology; through human ingenuity and invention, we reach places not meant to accommod...

  14. Thin book

    DEFF Research Database (Denmark)

    En lille bog om teater og organisationer, med bidrag fra 19 teoretikere og praktikere, der deltog i en "Thin Book Summit" i Danmark i 2005. Bogen bidrager med en state-of-the-art antologi om forskellige former for samarbejde imellem teater og organisationer. Bogen fokuserer både på muligheder og...

  15. Applications of ionizing radiations

    International Nuclear Information System (INIS)

    Developments in standard applications and brand new nuclear technologies, with high impact on the future of the agriculture, medicine, industry and the environmental preservation. The Radiation Technology Center (CTR) mission is to apply the radiation and radioisotope technologies in Industry, Health, Agriculture, and Environmental Protection, expanding the scientific knowledge, improving human power resources, transferring technology, generating products and offering services for the Brazilian society. The CTR main R and D activities are in consonance with the IPEN Director Plan (2011-2013) and the Applications of Ionizing Radiation Program, with four subprograms: Irradiation of Food and Agricultural Products; Radiation and Radioisotopes Applications in Industry and Environment; Radioactive Sources and Radiation Applications in Human Health; and Radioactive Facilities and Equipment for the Applications of Nuclear Techniques

  16. Multiphoton ionization of Uracil

    Science.gov (United States)

    Prieto, Eladio; Martinez, Denhi; Guerrero, Alfonso; Alvarez, Ignacio; Cisneros, Carmen

    2016-05-01

    Multiphoton ionization and dissociation of Uracil using a Reflectron time of flight spectrometer was performed along with radiation from the second harmonic of a Nd:YAG laser. Uracil is one of the four nitrogen bases that belong to RNA. The last years special interest has been concentrated on the study of the effects under UV radiation in nucleic acids1 and also in the role that this molecule could have played in the origin and development of life on our planet.2 The MPI mass spectra show that the presence and intensity of the resulting ions strongly depend on the density power. The identification of the ions in the mass spectra is presented. The results are compared with those obtained in other laboratories under different experimental conditions and some of them show partial agreement.3 The present work was supported by CONACYT-Mexico Grant 165410 and DGAPA UNAM Grant IN101215 and IN102613.

  17. Applications of ionizing radiations

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2014-07-01

    Developments in standard applications and brand new nuclear technologies, with high impact on the future of the agriculture, medicine, industry and the environmental preservation. The Radiation Technology Center (CTR) mission is to apply the radiation and radioisotope technologies in Industry, Health, Agriculture, and Environmental Protection, expanding the scientific knowledge, improving human power resources, transferring technology, generating products and offering services for the Brazilian society. The CTR main R and D activities are in consonance with the IPEN Director Plan (2011-2013) and the Applications of Ionizing Radiation Program, with four subprograms: Irradiation of Food and Agricultural Products; Radiation and Radioisotopes Applications in Industry and Environment; Radioactive Sources and Radiation Applications in Human Health; and Radioactive Facilities and Equipment for the Applications of Nuclear Techniques.

  18. The Escape Fraction of Ionizing Radiation from Primordial Galaxies

    CERN Document Server

    Benson, Andrew; Shull, J Michael

    2012-01-01

    The escape of ionizing radiation from galaxies plays a critical role in the evolution of gas in galaxies, and the heating and ionization history of the intergalactic medium. Here, we present semi-analytic calculations of the escape fraction of ionizing radiation for both hydrogen and helium from primordial galaxies, as well as analytic derivations of these quantities. We consider variations in the galaxy density profile, source type, location, and spectrum, and gas clumping/distribution factors. For sufficiently hard first-light sources, the helium ionization fronts closely track or even advance beyond that of hydrogen. Key new results in this work include calculations of the escape fractions for He I and He II ionizing radiation, and the impact of partial ionization from X-rays from early AGN or stellar clusters on the escape fractions from primordial halos. When factoring in frequency-dependent effects, we find that X-rays play an important role in boosting the escape fractions for both hydrogen and helium,...

  19. Simulation of various ionization effects in overdense plasmas irradiated by a subpicosecond pulse laser

    Energy Technology Data Exchange (ETDEWEB)

    Zhidkov, A.; Sasaki, Akira; Tajima, Toshiki [Advanced Photon Research Center, Japan Atomic Energy Research Institute, Neyagawa, Osaka (Japan)

    2000-07-01

    The effects of the elastic collisions and ionization under non-LET on the absorption efficiency, heat transfer, and particle acceleration in short pulse laser irradiated overdense plasmas are studied. We present a newly developed hybrid electromagnetic particle-in-cell method (in 1D) employing the nonlinear Langevin equation to account for Coulomb collisions and the average ion model to calculate the plasma transient ionization. The collisional and field ionization are included. Interaction between solid targets and thin foils with an arbitrary polarized, intense (I=10{sup 16}-10{sup 20} W/cm{sup 2}) laser pulse are investigated. (author)

  20. Testing a ring-shaped ionization chamber in standard beta radiation

    International Nuclear Information System (INIS)

    A ring-shaped ionization chamber, developed at Instituto de Pesquisas Energeticas e Nucleares, was tested in standard beta radiation fields. This ionization chamber was primarily developed to be used as a monitor chamber in X-ray diagnostic radiology beams. It has a large sensitive volume and parallel-plate aluminium electrode. Its entrance window is made of a thin aluminized polyester foil, which allows the collection of electrons. The ring-shaped monitor chamber was already tested in X radiation beams, showing a good performance. The aim of this work was to verify the applicability of the ionization chamber for beta radiation field dosimetry at calibration distances. (author)

  1. On ionization energy losses of ultra-relativistic half-bare electron

    Science.gov (United States)

    Shul'ga, N. F.; Trofymenko, S. V.

    2012-11-01

    The problem of ionization energy losses of relativistic electron after its emission from substance into vacuum and subsequent traversal of thin dielectric plate is considered. It is shown that with the increase of distance between the plate and the substance the gradual increase of electron ionization energy losses in the plate from the value defined by Fermi formula to the value defined by Bethe-Bloch formula complemented by radiation contribution to ionization occurs. It is highlighted that such change of energy losses is defined by reconstruction of the field around the electron and may occur on macroscopic distances along its trajectory.

  2. Ionization detection system for aerosols

    Science.gov (United States)

    Jacobs, Martin E.

    1977-01-01

    This invention relates to an improved smoke-detection system of the ionization-chamber type. In the preferred embodiment, the system utilizes a conventional detector head comprising a measuring ionization chamber, a reference ionization chamber, and a normally non-conductive gas triode for discharging when a threshold concentration of airborne particulates is present in the measuring chamber. The improved system utilizes a measuring ionization chamber which is modified to minimize false alarms and reductions in sensitivity resulting from changes in ambient temperature. In the preferred form of the modification, an annular radiation shield is mounted about the usual radiation source provided to effect ionization in the measuring chamber. The shield is supported by a bimetallic strip which flexes in response to changes in ambient temperature, moving the shield relative to the source so as to vary the radiative area of the source in a manner offsetting temperature-induced variations in the sensitivity of the chamber.

  3. Pixelized Gas Micro-well Detectors for Advanced Gamma-ray Telescopes

    CERN Document Server

    Bloser, P F

    2004-01-01

    We describe possible applications of pixelized micro-well detectors (PMWDs) as three-dimensional charged particle trackers in advanced gamma-ray telescope concepts. A micro-well detector consists of an array of individual micro-patterned gas proportional counters opposite a planar drift electrode. When combined with pixelized thin film transistor (TFT) array readouts, large gas volumes may be imaged with very good spatial and energy resolution at reasonable cost. The third dimension is determined by timing the drift of the ionization electrons. The primary advantage of this technique is the very low scattering that the charged particles experience in a gas tracking volume, and the very accurate determination of the initial particle momenta that is thus achieved. We consider two applications of PMWDs to gamma-ray astronomy: 1) A tracker for an Advanced Compton Telescope (ACT) in which the recoil electron from the initial Compton scatter may be accurately tracked, greatly reducing the telescope's point spread f...

  4. Ionization box type radiation detector

    International Nuclear Information System (INIS)

    An ionization box for monitoring radiation rays, a first amplification circuit of a multi-stage amplification circuit employing a MOS type FET as an initial stage amplification device, a second amplification circuit employing a junction type FET as an initial stage amplification device, a first change-over switch for switching ionization current depending on input signals, a second change-over switch for switching output signals, and a signal level discrimination circuit are constituted integrally. When radiation dose rate is low, the ionization current is inputted to the first amplification circuit and outputted as a radiation ray monitor signal and, when the radiation dose rate is increased to higher than a predetermined value, the ionization current is inputted to the second amplification circuit and outputted as a radiation ray monitor signal. That is, monitoring accuracy is high when the ionization current is low since the MOS type FET of high input impedance is used. If the ionization current is higher than a predetermined value, there is no worry that the detection becomes impossible since the junction type FET having less worry of causing characteristic change due to high radiation dose rate is used. Accordingly, ionization box type monitor at a high monitoring reliability can be obtained. (N.H.)

  5. Photoionization effects in ionization fronts

    Energy Technology Data Exchange (ETDEWEB)

    Arrayas, Manuel [Departamento de Electromagnetismo, Universidad Rey Juan Carlos, Tulipan s/n, 28933 Mostoles, Madrid (Spain); Fontelos, Marco A [Departamento de Matematicas, Instituto de Matematicas y Fisica Fundamental, Consejo Superior de Investigaciones CientIficas, C/Serrano 123, 28006 Madrid (Spain); Trueba, Jose L [Departamento de Electromagnetismo, Universidad Rey Juan Carlos, Tulipan s/n, 28933 Mostoles, Madrid (Spain)

    2006-12-21

    In this paper we study the effects of photoionization processes on the propagation of both negative and positive ionization fronts in streamer discharge. We show that negative fronts accelerate in the presence of photoionization events. The appearance and propagation of positive ionization fronts travelling with constant velocity is explained as the result of the combined effects of photoionization and electron diffusion. The photoionization range plays an important role in the selection of the velocity of the ionization front as we show in this work.

  6. Ionization in liquids

    International Nuclear Information System (INIS)

    During the 1987--1990 reporting period, studies were conducted that entailed the direct measurement of the transport and reaction properties of excess electrons in nonpolar liquids through the use of pulse-conductivity techniques. The results obtained from these studies should be applicable toward the development of a better understanding of the primary ionizing event in liquids as well as to providing physico-chemical information that is pertinent to electron-transfer processes that are ubiquitous in biological systems. Progress was also made in developing a better understanding of electron attachment reactions in liquids through measurements of the electron attachment rate constants, kes, of a variety of electron-attaching solutes. The effects of several functional groups substituted at different positions on benzene were studied in liquid cyclohexane and isooctane. The electron-attaching properties of chemicals having well characterized carcinogenic properties were studied in cyclohexane to determine if the measure of electron-accepting potential that ke provides can elucidate the role that electrons play in the initiation step of carcinogenesis. The kes that were measured indicate that the ke-carcinogenicity correlation that was observed can be used to complement short-term carcinogen-screening bioassays to identify potential carcinogens. 115 refs., 6 tabs

  7. Optical ionization detector

    Science.gov (United States)

    Wuest, Craig R.; Lowry, Mark E.

    1994-01-01

    An optical ionization detector wherein a beam of light is split so that one arm passes through a fiber optics and the other arm passes through a gas-filled region, and uses interferometry to detect density changes in a gas when charged particles pass through it. The gas-filled region of the detector is subjected to a high electric field and as a charged particle traverses this gas region electrons are freed from the cathode and accelerated so as to generate an electron avalanche which is collected on the anode. The gas density is effected by the electron avalanche formation and if the index or refraction is proportional to the gas density the index will change accordingly. The detector uses this index change by modulating the one arm of the split light beam passing through the gas, with respect to the other arm that is passed through the fiber optic. Upon recombining of the beams, interference fringe changes as a function of the index change indicates the passage of charged particles through the gaseous medium.

  8. Advanced Structural Characterization of Organic Thin Films

    DEFF Research Database (Denmark)

    Gu, Yun

    In this thesis, the structural characterizations of three organic film systems are described. Several X-ray based techniques have been utilized for the characterizations for different research goals. The structures of N,N',N-trioctyltriazatriangulenium (Oct3-TATA+) salts have been investigated...... by optical, surface and X-ray method. We describe the production of Langmuir-Blodgett film and how the absorption spectroscopy is a powerful tool to identify layer of monomer and dimer. X-ray refelctometry has been applied as a method for the study of the multilayer film and interface structure. A separation...... of small molecule and polymer layers is indicated by Flory- Huggins theory for the triisopropylsilylethynl pentacene (TIPS-PEN) and polystyrene blend films. In order to investigate the phase separated layers in the ink-jet printed films, we propose a method to measure diraction Bragg peaks by X...

  9. Large Area Thin Film Silicon: Synergy between Displays and Solar Cells

    NARCIS (Netherlands)

    Schropp, R.E.I.

    2012-01-01

    Thin-film silicon technology has changed our society, owing to the rapid advance of its two major application fields in communication (thin-film displays) and sustainable energy (thin-film solar cells). Throughout its development, advances in these application fields have always benefitted each othe

  10. Theory of resonance ionization spectroscopy

    International Nuclear Information System (INIS)

    Resonance Ionization Spectroscopy (RIS) can be defined as a state selective detection process in which pulsed tunable lasers are used to promote transitions from the selected state of the atoms or molecules in question to higher states, one of which will be ionized by the absorption of another photon. At least one resonance step is used in the stepwise ionization process, and it has been shown that the ionization probability of the spectroscopically selected species can nearly always be made close to unity. Since measurements of the number of photoelectrons or ions can be made very precisely and even one electron (or under vacuum conditions, one ion) can be detected, the technique can be used to make quantitative measurements of very small populations of the state-selected species

  11. Ionization of impurities in silicon

    Science.gov (United States)

    Kuźmicz, Wiesław

    1986-12-01

    A model for calculation of the percentage of ionized dopant atoms as a function of the doping concentration and temperature is proposed. The results are compared with experiment. Analytical approximations that facilitate practical applications of the model are given.

  12. Calculation of multiphoton ionization processes

    Science.gov (United States)

    Chang, T. N.; Poe, R. T.

    1976-01-01

    We propose an accurate and efficient procedure in the calculation of multiphoton ionization processes. In addition to the calculational advantage, this procedure also enables us to study the relative contributions of the resonant and nonresonant intermediate states.

  13. Strong Ionization in carbon Nanowires

    CERN Document Server

    Kaymak, Vural; Shlyaptsev, Vyacheslav N; Rocca, Jorge J

    2015-01-01

    Surfaces covered with nanostructures, such as nanowire arrays, have shown to facilitate a significantly higher absorption of laser energy as compared to flat surfaces. Due to the efficient coupling of the laser energy, highly energetic electrons are produced, which in turn can emit intense ultrafast X-ray pulses. In the present work we use full three dimensional PIC simulations to analyze the behavior of arrays of carbon nanowires $400 nm$ in diameter, irradiated by a $\\lambda_0 = 400 nm$ laser pulse of $60 fs$ duration at FWHM and a vector potential of $a_0 = 18$. We analyze the ionization dynamics of the nanowires. We investigate the difference of the ionization strength and structure between linearly and circularly polarized laser beam. The nanowires are found to be fully ionized after about 30 laser cycles. Circularly polarized light reveals a slightly stronger ionization effect.

  14. Multi-chamber ionization detector

    International Nuclear Information System (INIS)

    For the detector a single beta ionization source and a double- or three-chamber set-up is used, the chambers being designed in the shape of a truncated cone and facing each other with their bases. The source can be positioned with respect to the common center or modal electrode, the adjustment of the ionization in each chamber this becoming easier. The center or modal electrode also can be adjusted with respect to the source. (DG)

  15. Multiphoton double ionization of barium

    International Nuclear Information System (INIS)

    The authors report the observation of the wavelength spectrum of the double ionization of Ba from ∼ 280 nm to nearly 700 nm, using laser pulses 5ns long of peak intensity ∼ 1010 W/cm2. All the strong resonances can be assigned to Ba+ transitions, and many of the assignments have been verified by pump-probe techniques. Thus, the Ba++ observed is due to sequential ionization. The shortest wavelengths used are not as effective as λ ∼ 500 nm

  16. Laser ionization mass spectroscopy

    Science.gov (United States)

    Bernardez, Luis J., III; Siekhaus, W. J.

    1989-10-01

    Laser Ionization Mass Spectroscopy (LIMS) is a simple technique with several advantages and disadvantages over standard mass spectroscopy techniques. The LIMS technique uses a laser to vaporize a small portion of a sample. The vapor from the sample consists of a mixture of charged and neutral atoms or fragments. Using electrostatic grids, the ions (positive or negative) are given a known amount of kinetic energy and sent down a time-of-flight tube. The time it takes the ions to travel down the flight tube is recorded. Knowing the ions' energy, the length of the flight tube, and the time it takes the ions to travel that distance, the masses of the ions can be calculated. The instrument used is a LIMA 3 made by Cambridge Mass Spectrometry. It has a Quanta Ray DCR-11 Nd:YAG laser, which was frequency-quadrupled to 266 nm. The laser spot size is typically between 2 and 5 microns in diameter and the pulse width is between 5 and 10 nanoseconds. The energy of the laser is continually variable between 0.1 and 3.0 millijoules. The detector is a 17-stage venetian-blind multiplier made by Thorn EMI. The analysis is carried out under vacuum, usually between 10(exp -8) and 10(exp -9) Torr. The LIMA 3 has several useful features such as: a He-Ne pilot laser used to target the Nd:YAG laser; a microscope (which is used to view the sample through the laser optics); and a precision sample stage for accurate sample alignment.

  17. MULTIPLE IONIZATION OF ATOMS THROUGH MULTIPHOTON ABSORPTION

    OpenAIRE

    L'Huillier, A

    1987-01-01

    We review the main aspects of multiple ionization of rare gases in strong laser fields (above 1012W.cm-2). We discuss the mechanisms responsible for the multi-electron ejection : inner-shell ionization or outer-shell ionization, one-step or multi-step. We show the differences between one-photon and multi-photon multiple ionization.

  18. Ionization of Hafnium L-Shell by Electron Impact

    Institute of Scientific and Technical Information of China (English)

    罗正明; 傅玉川; 安竹; 彭秀峰; 何福庆; 龙先灌

    2002-01-01

    A lower-energy electron beam has been directed on to a hafnium thin target with thick backing to investigate the process of L-shell ionization. By using a Si(Li) detector to count the x-raysfrom the L-subshell, the partial and total production cross sections and mean ionization cross sections versus electron energies have been deduced simultaneously (from threshold to 36keV). The influence of the electron reflected from the backing on measurements has been corrected. The path of the electron multi-scattered in the target itself has also been calculated by using the Monte Carlo programme (EGS4). A comparison with both theoretical predictions is given.

  19. Thin films and froth flotation

    International Nuclear Information System (INIS)

    The properties of thin, aqueous films on solid surfaces and their central role in the froth flotation process are discussed. The stability of these films can generally be described in terms of electrostatic and van der Waals forces. Significant experimental and theoretical advances are required in many areas (e.g. short range forces, film drainage) before a clear picture of the collision of, adhesion between and detachment of bubbles and particles will emerge. (orig.)

  20. Isotope separation with improved selective ionization

    International Nuclear Information System (INIS)

    Method and apparatus for isotope separation by selective ionization of a desired isotope in an environment of plural isotopes without corresponding ionization of the other isotopes in the environment. The selective ionization is achieved through a three step excitation of atoms of the desired isotope in response to laser radiations applied to the environment. The transition for each step is selected to be less than one half the ionization potential for the isotopes to avoid two step nonselective ionization

  1. Accelerated C-N Bond Formation in Dropcast Thin Films on Ambient Surfaces

    Science.gov (United States)

    Badu-Tawiah, Abraham K.; Campbell, Dahlia I.; Cooks, R. Graham

    2012-09-01

    The aza-Michael addition and the Mannich condensation occur in thin films deposited on ambient surfaces. The reagents for both C-N bond formation reactions were transferred onto the surface by drop-casting using a micropipette. The surface reactions were found to be much more efficient than the corresponding bulk solution-phase reactions performed on the same scale in the same acetonitrile solvent. The increase in rate of product formation in the thin film is attributed to solvent evaporation in the open air which results in reagent concentration and produces rate acceleration similar to that seen in evaporating droplets in desorption electrospray ionization. This thin film procedure has potential for the rapid synthesis of reaction products on a small scale, as well as allowing rapid derivatization of analytes to produce forms that are easily ionized by electrospray ionization. Analysis of the derivatized sample directly from the reaction surface through the use of desorption electrospray ionization is also demonstrated.

  2. Controlled-Resonant Surface Tapping-Mode Scanning Probe Electrospray Ionization Mass Spectrometry Imaging

    Energy Technology Data Exchange (ETDEWEB)

    Lorenz, Matthias [ORNL; Ovchinnikova, Olga S [ORNL; Kertesz, Vilmos [ORNL; Van Berkel, Gary J [ORNL

    2014-01-01

    This paper reports on the advancement of a controlled-resonance surface tapping-mode single capillary liquid junction extraction/ESI emitter for mass spectrometry imaging. The basic instrumental setup and the general operation of the system were discussed and optimized performance metrics were presented. The ability to spot sample, lane scan and chemically image in an automated and controlled fashion were demonstrated. Rapid, automated spot sampling was demonstrated for a variety of compound types including the cationic dye basic blue 7, the oligosaccharide cellopentaose, and the protein equine heart cytochrome c. The system was used for lane scanning and chemical imaging of the cationic dye crystal violet in inked lines on glass and for lipid distributions in mouse brain thin tissue sections. Imaging of the lipids in mouse brain tissue under optimized conditions provided a spatial resolution of approximately 35 m based on the ability to distinguish between features observed both in the optical and mass spectral chemical images. The sampling spatial resolution of this system was comparable to the best resolution that has been reported for other types of atmospheric pressure liquid extraction-based surface sampling/ionization techniques used for mass spectrometry imaging.

  3. Ambient ionization mass spectrometry: A tutorial

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Min-Zong; Cheng, Sy-Chi; Cho, Yi-Tzu [Department of Chemistry, National Sun Yat-Sen University, Kaohsiung, Taiwan (China); Shiea, Jentaie, E-mail: jetea@fac.nsysu.edu.tw [Department of Chemistry, National Sun Yat-Sen University, Kaohsiung, Taiwan (China); Cancer Center, Kaohsiung Medical University, Kaohsiung, Taiwan (China)

    2011-09-19

    Highlights: {yields} Ambient ionization technique allows the direct analysis of sample surfaces with little or no sample pretreatment. {yields} We sort ambient ionization techniques into three main analytical strategies, direct ionization, direct desorption/ionization, and two-step ionization. {yields} The underlying principles of operation, ionization processes, detecting mass ranges, sensitivity, and representative applications of these techniques are described and compared. - Abstract: Ambient ionization is a set of mass spectrometric ionization techniques performed under ambient conditions that allows the direct analysis of sample surfaces with little or no sample pretreatment. Using combinations of different types of sample introduction systems and ionization methods, several novel techniques have been developed over the last few years with many applications (e.g., food safety screening; detection of pharmaceuticals and drug abuse; monitoring of environmental pollutants; detection of explosives for antiterrorism and forensics; characterization of biological compounds for proteomics and metabolomics; molecular imaging analysis; and monitoring chemical and biochemical reactions). Electrospray ionization and atmospheric pressure chemical ionization are the two main ionization principles most commonly used in ambient ionization mass spectrometry. This tutorial paper provides a review of the publications related to ambient ionization techniques. We describe and compare the underlying principles of operation, ionization processes, detecting mass ranges, sensitivity, and representative applications of these techniques.

  4. One-atom detection in individual ionization tracks

    International Nuclear Information System (INIS)

    A major advance in one-atom detection using laser photoionization makes it possible to detect with microsecond time resolution single neutral atoms resulting from the stopping of energetic heavy ions in a buffer gas. This detection at the one-atom level, which gives the first direct evidence of nearly complete charge neutralization of stopped energetic ions, is shown to be possible even under the extremely adverse conditons associated with a densely ionized particle track

  5. Applications of thin-film photovoltaics for space

    Science.gov (United States)

    Landis, Geoffrey A.; Hepp, Aloysius F.

    1991-01-01

    The authors discuss the potential applications of thin-film polycrystalline and amorphous cells for space. There have been great advances in thin-film solar cells for terrestrial applications. Transfer of this technology to space applications could result in ultra low-weight solar arrays with potentially large gains in specific power. Recent advances in thin-film solar cells are reviewed, including polycrystalline copper indium selenide and related I-III-VI2 compounds, polycrystalline cadmium telluride and related II-VI compounds, and amorphous silicon arrays. The possibility of using thin-film multi-bandgap cascade solar cells is discussed.

  6. Thin-Film Photovoltaics: Status and Applications to Space Power

    Science.gov (United States)

    Landis, Geoffrey A.; Hepp, Aloysius F.

    1991-01-01

    The potential applications of thin film polycrystalline and amorphous cells for space are discussed. There have been great advances in thin film solar cells for terrestrial applications; transfer of this technology to space applications could result in ultra low weight solar arrays with potentially large gains in specific power. Recent advances in thin film solar cells are reviewed, including polycrystalline copper iridium selenide and related I-III-VI2 compounds, polycrystalline cadmium telluride and related II-VI compounds, and amorphous silicon alloys. The possibility of thin film multi bandgap cascade solar cells is discussed.

  7. Health effects of ionizing radiation

    International Nuclear Information System (INIS)

    Ionizing radiation is energy that travels through space as electromagnetic waves or a stream of fast moving particles. In the workplace, the sources of ionizing radiation are radioactive substances, nuclear power plants, x-ray machines and nuclear devices used in medicine, research and industry. Commonly encountered types of radiation are alpha particles, beta particles and gamma rays. Alpha particles have very little penetrating power and pose a risk only when the radioactive substance is deposited inside the body. Beta particles are more penetrating than alpha particles and can penetrate the outer body tissues causing damage to the skin and the eyes. Gamma rays are highly penetrating and can cause radiation damage to the whole body. The probability of radiation-induced disease depends on the accumulated amount of radiation dose. The main health effects of ionizing radiation are cancers in exposed persons and genetic disorders in the children, grandchildren and subsequent generations of the exposed parents. The fetus is highly sensitive to radiation-induced abnormalities. At high doses, radiation can cause cataracts in the eyes. There is no firm evidence that ionizing radiation causes premature aging. Radiation-induced sterility is highly unlikely for occupational doses. The data on the combined effect of ionizing radiation and other cancer-causing physical and chemical agents are inconclusive

  8. Models for multiphoton ionization processes

    International Nuclear Information System (INIS)

    Using the Fourier transform method, several analytical models for multiphoton processes have been developed, which emphasize the non-perturbative regime of C-C transitions. It was found that the population trapping of continuum-continuum (C-C) transitions can occurs under general conditions: for two continua with energy-dependent matrix elements, and for an infinite number of structureless continua with coupled bands. A above-threshold ionization model with two-frequency smooth pulses for hydrogenic atom was first proposed. This model give a simple form for analytical solutions if an ionization threshold is negligible. The results predict that (a) there is no trapping or saturation of the bound-continuum transition and that the ionization rate is independent of the redistribution among the continua for the C-C matrix element chosen; (b) There are peak switch in photoelectron energy spectra which depends on not only redistribution laser intensity, but also the pulses shape and their overlap in time, as well as the coupling between the bound state and continua; (c) peaks about the ionization energy in the photoelectron spectra are symmetric and only appear during the ionization process; (d) as the laser intensity is increased, the total angular photoelectrons distribution peak strongly in forward and backward direction of the redistribution laser polarization; and the minima of this distribution are not zero for higher laser intensity. The photon spectrum is also investigated

  9. Low-level measurements of Ra-226/Rn-222 by pulse ionization chambers

    Science.gov (United States)

    El-Daoushy, Fand; Garcia-Tenorio, Rafael

    1988-10-01

    Characteristics of two ionization chambers have been studied and the chambers utilized for 226Ra/ 222Rn measurements for more than ten years. The results obtained show that coating of internal surfaces with a pure and thin Ag-layer enhances the background of ionization chambers in spite of some improvements at the early stages of operation. In addition to previously known parameters influencing the accuracy in routine measurements, new correction factors are suggested. 226Ra impurities in the body of ionization chambers are found to act not only as a permanent, but also as a temperature-dependent source of background. Earlier accuracies of 226Ra/ 222Rn measurements have been considerably improved by assuring long-term mechanical and thermal stability of the ionization chambers.

  10. L-SHELL IONIZATION MEASUREMENT OF TUNGSTEN BY ELECTRON IMPACT

    Institute of Scientific and Technical Information of China (English)

    PENG XIU-FENG; HE FU-QING; LONG XIAN-GUAN

    2000-01-01

    L-shell partial production cross sections of Lα- , Lβ-, Lγ- rays by electron impact were measured by observing the counts of X-ray from impacted thin tungsten target. Total production cross sections and mean ionization cross sections were deduced from these measured results. The electron beam energy range was from 11 to 36 keV. Tungsten was sputtered onto a carbon backing to reduce bremsstrahlung of the backing. The effect of electrons reflected by the backing has been corrected. Comparison with two theoretical calculations has performed. The experimental results agree rather well with the theoretical predications.

  11. Atomic Ionization by Electron Impact

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The field of atomic ionization by electron impact is several decades old. In that period of time, significant progress has been made in several aspects of the problem and we have learned a lot about ionizing collisions as a result of this work. Over the years, both the experiments and theories have improved dramatically. Experiments are now able to measure absolute triple differential cross sections for both in-plane or out-of-plane geometries. Theories have been getting better and better at including all the 3-body interactions in the wavefunction for the system. However, during the history of the field, experiment has been ahead of theory and it is just very recently that theory has started to catch up. In this paper, we will show that theory is now able to accurately predict the results of electron impact ionization of hydrogen for intermediate and higher energies.

  12. Theory of dissociative tunneling ionization

    CERN Document Server

    Svensmark, Jens; Madsen, Lars Bojer

    2016-01-01

    We present a theoretical study of the dissociative tunneling ionization process. Analytic expressions for the nuclear kinetic energy distribution of the ionization rates are derived. A particularly simple expression for the spectrum is found by using the Born-Oppenheimer (BO) approximation in conjunction with the reflection principle. These spectra are compared to exact non-BO ab initio spectra obtained through model calculations with a quantum mechanical treatment of both the electronic and nuclear degrees freedom. In the regime where the BO approximation is applicable imaging of the BO nuclear wave function is demonstrated to be possible through reverse use of the reflection principle, when accounting appropriately for the electronic ionization rate. A qualitative difference between the exact and BO wave functions in the asymptotic region of large electronic distances is shown. Additionally the behavior of the wave function across the turning line is seen to be reminiscent of light refraction. For weak fiel...

  13. Radiative feedback from ionized gas

    CERN Document Server

    Glover, S C O

    2007-01-01

    H2 formation in metal-free gas occurs via the intermediate H- or H2+ ions. Destruction of these ions by photodissociation therefore serves to suppress H2 formation. In this paper, I highlight the fact that several processes that occur in ionized primordial gas produce photons energetic enough to photodissociate H- or H2+ and outline how to compute the photodissociation rates produced by a particular distribution of ionized gas. I also show that there are circumstances of interest, such as during the growth of HII regions around the first stars, in which this previously overlooked form of radiative feedback is of considerable importance.

  14. Trends in resonance ionization spectroscopy

    International Nuclear Information System (INIS)

    The author reviews the history of resonance ionization spectroscopy and then comments on the delineations of RIS with reference to many related laser processes. The substance of the paper deals with the trends in RIS and especially how the needs for sensitive analytical methods have overshadowed the orginal plan to study excited species. 9 refs., 1 fig

  15. Theory of resonance ionization spectroscopy

    International Nuclear Information System (INIS)

    Resonance Ionization Spectroscopy (RIS) can be defined as a state selective detection process in which pulsed tunable lasers are used to promote transitions from the selected state of the atoms or molecules in question to higher states, one of which will be ionized by the absorption of another photon. The ability to make saturated RIS measurements opens up a wide variety of applications to both basic and applied research. In reviews of RIS the subject was treated generally, including the underlying photophysics applications, the ability to use it to count single atoms, and its applications to measurements in atomic and molecular physics. They view resonance ionization spectroscopy as a specific type of multiphoton ionization in which the goal is to make quantitative measurements of quantum-selected populations in atomic or molecular systems. This goal attained by requiring that the selective excitation steps be resonant in nature and involve only one- or two-photon (only one-photon if at all possible) absorption processes, thereby allowing the entire process to be carried to saturation without loss of spectroscopic selectivity due to laser power induced shifts or broadening

  16. Negative chemical ionization mass spectrometry

    International Nuclear Information System (INIS)

    This thesis describes some aspects of Negative Chemical Ionization (NCI) mass spectrometry. The reasons for the growing interest in NCI are: (i) to extend the basic knowledge of negative ions and their reactions in the gas phase; (ii) to investigate whether or not this knowledge of negative ions can be used successfully to elucidate the structure of molecules by mass spectrometry. (Auth.)

  17. Electronic measurements of ionization currents

    Energy Technology Data Exchange (ETDEWEB)

    Hutyra, F.; Knapp, K.; Gregor, J. (Tesla, Premysleni (Czechoslovakia). Vyzkumny Ustav Pristroju Jaderne Techniky)

    1982-02-01

    Measurements are discussed of very low currents from ionization chambers. The currents range between 10/sup -15/ and 10/sup -9/ A. Two methods are discussed. A description is given of a dynamic and a semiconductor electrometers. Both meters are parts of dosimetric instruments for monitoring the dose rate (NB 9201) and the neutron-gamma mixed radiation dose rate (NDK 601).

  18. Ionization Potentials for Isoelectronic Series.

    Science.gov (United States)

    Agmon, Noam

    1988-01-01

    Presents a quantitative treatment of ionization potentials of isoelectronic atoms. By looking at the single-electron view of calculating the total energy of an atom, trends in the screening and effective quantum number parameters are examined. Approaches the question of determining electron affinities. (CW)

  19. Advance in alloy thin-film pressure sensor for high-temperature environment%合金薄膜高温压力传感器研究进展

    Institute of Scientific and Technical Information of China (English)

    李伟; 陈怀礼

    2011-01-01

    The alloy thin-film pressure sensor has overcome the shortcomings of stickup pressure sensor,has more excellent performances and is suitble for harsh environments.The working principle of the alloy thin-film pressure senso is introduced in this paper.The advantages and disadvantages of several pressure sensors are compared.Taking the sensor's working temperature as an assessment index,the characteristics and development status of nickel-chromium(NiCr),platinum-tungsten (PtW) and palladium-chromium(PdCr) thin-film pressure sensors are elaborated.The conclusions are: NiCr thin-film pressure sensor is suitable for pressure measurement in the range of-269℃~ +350℃;PtW and PdCr thin-film pressure sensors are applied to pressure measurement at high temperature.The key technology and the application of alloy thin-film pressure sensor are reviewed.%合金薄膜压力传感器克服了粘贴式应变压力传感器的缺点,性能更优良,适应恶劣环境压力测量要求。对合金薄膜压力传感器的工作原理进行了介绍,比较了几种压力传感器的优缺点,并以应用温度范围这一指标为中心论述了镍铬、铂钨及钯铬薄膜压力传感器的性能特点及研究现状。镍铬薄膜传感器适用于中、低温介质压力测量,而铂钨、钯铬薄膜传感器适用于更高温度环境下的压力测量。

  20. Ionization Thresholds of Small Carbon Clusters: Tunable VUVExperiments and Theory

    Energy Technology Data Exchange (ETDEWEB)

    Belau, Leonid; Wheeler, Steven E.; Ticknor, Brian W.; Ahmed,Musahid; Leone, Stephen R.; Allen, Wesley D.; Schaefer III, Henry F.; Duncan, Michael A.

    2007-07-31

    Small carbon clusters (Cn, n = 2-15) are produced in amolecular beam by pulsed laser vaporization and studied with vacuumultraviolet (VUV) photoionization mass spectrometry. The required VUVradiation in the 8-12 eV range is provided by the Advanced Light Source(ALS) at the Lawrence Berkeley National Laboratory. Mass spectra atvarious ionization energies reveal the qualitative relative abundances ofthe neutral carbon clusters produced. By far the most abundant species isC3. Using the tunability of the ALS, ionization threshold spectra arerecorded for the clusters up to 15 atoms in size. The ionizationthresholds are compared to those measured previously with charge-transferbracketing methods. To interpret the ionization thresholds for differentcluster sizes, new ab initio calculations are carried out on the clustersfor n = 4-10. Geometric structures are optimized at the CCSD(T) levelwith cc-pVTZ (or cc-pVDZ) basis sets, and focal point extrapolations areapplied to both neutral and cation species to determine adiabatic andvertical ionization potentials. The comparison of computed and measuredionization potentials makes it possible to investigate the isomericstructures of the neutral clusters produced in this experiment. Themeasurements are inconclusive for the n = 4-6 species because ofunquenched excited electronic states. However, the data provide evidencefor the prominence of linear structures for the n = 7, 9, 11, 13 speciesand the presence of cyclic C10.

  1. Nuclear Propulsion using Thin Foiled Fuel

    Science.gov (United States)

    Takahashi, H.

    1998-11-01

    A new way to produce plasma for nuclear propulsion is proposed. A thin foiled fuel can be used for converting fission energy to propulsion energy efficiently. The fission products coming out of the thin foil directly ionize the hydrogen molecules which are used for propulsion. Thus very small portion of fission energy deposited in the thin foil, and integrity of the thin foiled fuel can be maintained even in high nuclear power. Fuel material with large thermal fission cross-section is preferable to make thin foiled fuel and the heat deposition in the foil can be reduced. To get high power from the foiled fuel assembly, thermal neutrons which are created out from the assembly can be supplied, or the assembly itself can create the high intensity thermal neutrons by self-multiplication. A flexible design of a highly efficient nuclear propulsion system can be made. The thickness of the foil and the maintenance of the thermo-mechanical integrity can be determined from the fission cross-section and the slowing down power for fission products. The talk discusses the issues related to heat removal from the assembly.

  2. Five-photon double ionization of helium

    Science.gov (United States)

    Li, Y.; Pindzola, M. S.; Colgan, J.

    2016-03-01

    A time-dependent close-coupling method is used to calculate the five-photon double ionization of He. It is found that the generalized cross section used in the past for two-photon double ionization of He cannot be extended to five-photon double ionization of He. Therefore only five-photon double ionization probabilities that depend on specific radiation field pulses can be calculated.

  3. LARGE VOLUME IONIZATION CHAMBER USED AS LABORATORY REFERENCE FOR LOW ENERGY X—RAY MEASUREMENT

    Institute of Scientific and Technical Information of China (English)

    杨国山; 薛永库; 等

    1994-01-01

    A large volume spherical ionization chamber of 195mm diameter and 0.36mg/cm2 wall thickness made from conducting carbon-fibre epoxy composite material has been developed.The mechanical intensity of the chamber is satisfactory for a good longterm volume stability.Owing to its large volume and thin wall,the chamber is sensitive to low energy photon beams and has excellent energy-response characteristics.This ionization chamber is suitable not only for a laboratory reference but also for measurement of low energy photon beam exposure rates at protection-level.

  4. Rip-Stop Reinforced Thin Film Sun Shield Structure Project

    Data.gov (United States)

    National Aeronautics and Space Administration — During a proposed Phase I and Phase II program, PSI will advance the TRL from 3 to 6 for the ripstop reinforcement of thin film membranes used for large deployable...

  5. Management of advanced corneal ectasias.

    Science.gov (United States)

    Maharana, Prafulla K; Dubey, Aditi; Jhanji, Vishal; Sharma, Namrata; Das, Sujata; Vajpayee, Rasik B

    2016-01-01

    Corneal ectasias include a group of disorders characterised by progressive thinning, bulging and distortion of the cornea. Keratoconus is the most common disease in this group. Other manifestations include pellucid marginal degeneration, Terrien's marginal degeneration, keratoglobus and ectasias following surgery. Advanced ectasias usually present with loss of vision due to high irregular astigmatism. Management of these disorders is difficult due to the peripheral location of ectasia and associated severe corneal thinning. Newer contact lenses such as scleral lenses are helpful in a selected group of patients. A majority of these cases requires surgical intervention. This review provides an update on the current treatment modalities available for management of advanced corneal ectasias. PMID:26294106

  6. Thermoluminescence of thin films deposited by laser ablation; Termoluminiscencia de peliculas delgadas depositadas por ablacion laser

    Energy Technology Data Exchange (ETDEWEB)

    Escobar A, L.; Camps, E.; Arrieta, A.; Romero, S.; Gonzalez, P.R.; Olea M, O.; Diaz E, R. [Depto. de Fisica, ININ, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    2003-07-01

    Materials in thin film form have received great attention in the last few years mainly because of their singular properties, which may differ significantly from their bulk attributes making them attractive for a wide variety of applications. In particular, thermoluminescence (Tl) properties of thin films have been studied recently owing to their potential applications in detection for both ionizing and non ionizing radiation. The aim of the present work is to report the synthesis and characterization of C Nx, aluminum oxide and titanium oxide thin films. Thermoluminescence response of the obtained thin films was studied after subject thin films to UV radiation (254 nm) as well as to gamma radiation (Co-60). Thermoluminescence glow curves exhibited a peak centered at 150 C for CN{sub x} whereas for titanium oxide the glow curve shows a maximum peaking at 171 C. Characterization of the physical properties of the deposited materials is presented. (Author)

  7. Thin films of soft matter

    CERN Document Server

    Kalliadasis, Serafim

    2007-01-01

    A detailed overview and comprehensive analysis of the main theoretical and experimental advances on free surface thin film and jet flows of soft matter is given. At the theoretical front the book outlines the basic equations and boundary conditions and the derivation of low-dimensional models for the evolution of the free surface. Such models include long-wave expansions and equations of the boundary layer type and are analyzed via linear stability analysis, weakly nonlinear theories and strongly nonlinear analysis including construction of stationary periodic and solitary wave and similarity solutions. At the experimental front a variety of very recent experimental developments is outlined and the link between theory and experiments is illustrated. Such experiments include spreading drops and bubbles, imbibitions, singularity formation at interfaces and experimental characterization of thin films using atomic force microscopy, ellipsometry and contact angle measurements and analysis of patterns using Minkows...

  8. Ionization potentials some variations, implications and applications

    CERN Document Server

    Ahrens, L H

    1983-01-01

    Ionization Potentials: Some Variations, Implications and Applications covers several aspects of ionization potential that is a highly significant parameter in controlling the properties of electric discharge. Comprised of 17 chapters, the book covers topic relevant to ionization potentials, such as properties, concepts, and applications, in order to understand and fully comprehend all aspects of ionization potential. The opening chapter is a review of ionization potentials and a discussion of trends and features. The succeeding chapters then tackle complex topics such as the s and p electrons;

  9. Biological effects of ionizing radiation

    Energy Technology Data Exchange (ETDEWEB)

    Blaylock, B.G. [SENES Oak Ridge Inc., Oak Ridge, TN (United States); Theodorakis, C.W.; Shugart, L.R. [Oak Ridge National Lab., Oak Ridge, TN (United States). Environmental Sciences Division

    1996-12-31

    Natural populations have always been exposed to background levels of ionizing radiation; however, with the event of the nuclear age, studies about the effects of higher-than-background levels of ionizing radiation on individuals or populations of organisms became important. Originally, concern was focused on survival after large, acute radiation doses, and numerous studies document the somatic and genetic effects of acute ionizing radiation. However, there is a growing realization that chronic long-term exposure to higher-than-background levels of environmental radiation is more likely than is large acute exposure. Less than 10% of the literature on ionizing radiation effects deals with chronic long-term effects, and very few studies involve natural populations. In 1977, mosquito fish, Gambusia affinis, were experimentally introduced into a 0,45 ha, decommissioned, radioactive waste pond where the measured dose at the sediment-water interface was 1,150 rad/year. One year later, the fecundity of the population had not changed significantly. Eighteen years later, studies of the fish showed an inverse correlation between DNA strand breakage and fecundity in the contaminated pond. More recent studies have provided evidence that genetic diversity of the fish has increased in the contaminated site. These fish also have a greater prevalence of certain DNA banding patterns. Individuals displaying these banding patterns have a higher fecundity and lower degree of DNA strand breakage than individuals with less common banding patterns. Gambusia affinis has apparently adapted to the high background radiation, successfully surviving for approximately 50 generations. 31 refs, 5 figs.

  10. The dosimetry of ionizing radiation

    CERN Document Server

    1990-01-01

    A continuation of the treatise The Dosimetry of Ionizing Radiation, Volume III builds upon the foundations of Volumes I and II and the tradition of the preceeding treatise Radiation Dosimetry. Volume III contains three comprehensive chapters on the applications of radiation dosimetry in particular research and medical settings, a chapter on unique and useful detectors, and two chapters on Monte Carlo techniques and their applications.

  11. Risks Associated with Ionizing Radiations

    International Nuclear Information System (INIS)

    Medical use of ionizing radiations implies certain risks which are widely balanced by their diagnostic and therapeutic benefits. Nevertheless, knowledge about these risks and how to diagnose and prevent them minimizes their disadvantages and optimizes the quality and safety of the method. This article describes the aspects related to skin dose (nonstochastic effects), the importance of dose limit, the physiopathology of biological damage and, finally, the prevention measures.

  12. Nuclear worker and ionizing radiation

    International Nuclear Information System (INIS)

    Research on medical X-ray exposure sheds light on the health effects expected for workers exposed to ionizing radiation. Factual information confirming this relationship and also demonstrating the need for reviewing permissible exposure levels for workers is given. Suggestions for more sophisticated health monitoring of workers exposed to hazardous technologies are made, and the question of occupational hazards which threaten the worker's family is raised

  13. Laser resonance ionization mass spectrometer

    International Nuclear Information System (INIS)

    The setup is elaborated for the trace detection of transuranium elements by the three-step laser resonance ionization combined with the time-of-flight mass spectrometry. The setup efficiency for detection of plutonium was measured to be about 0.5 centre dot 10-8 ion/atom, and its selectivity relative to atoms of another elements has the order of 1013 atom/atom

  14. Energy distributions for ionization in ion-atom collisions

    CERN Document Server

    Amaya-Tapia, A

    2016-01-01

    In this paper we discuss how through the process of applying the Fourier transform to solutions of the Schr\\"odinger equation in the Close Coupling approach, good results for the ionization differential cross section in energy for electrons ejected in ion-atom collisions are obtained. The differential distributions are time dependent and through their time average, the comparison with experimental and theoretical data reported in the literature can be made. The procedure is illustrated with reasonable success in two systems, $p+H$ and $p+He$, and is expected to be extended without inherent difficulties to more complex systems. This allows advancing in the understanding of the calculation of ionization processes in ion-atom collisions.

  15. Ionization of H Rydberg atoms

    International Nuclear Information System (INIS)

    Concepts from the theory of transient chaos are applied to study the classical ionization process of one dimensional model of kicked hydrogen Rydberg atoms. The phase-space dynamics is represented by a mapping T which is proved to be hyperbolic. The fraction of atoms not ionized after time t, PB(t), decays asymptotically according to PB(t)∼t-α with α ∼ 1.65. The observed algebraic decay, which seems to contradict the hyperbolicity of T, is explained by (i) the symbolic dynamics of T consists of a countably infinite number of symbols and (ii) the invariant manifold of phase-space points which never ionize is an anomalously scaling fractal. Therefore, the one-dimensional kicked hydrogen atom provides a counterexample to the hypothesis that algebraic decay marks regular dynamics, whereas hyperbolic systems decay exponentially. The algebraic decay is reproduced by an analytically solvable diffusion model which predicts α = 3/2. Replacing zero-width δ-kicks by smooth finite-width pulses, the mapping T is no longer completely hyperbolic, and a subset of phase-space is regular. For this case we observe that PB(t) shows a transition between two power-law decays with α ∼ 1.65 for short times and α ∼ 2.1 for long times where the effect of the regular domain is felt. (author)

  16. Theory of dissociative tunneling ionization

    Science.gov (United States)

    Svensmark, Jens; Tolstikhin, Oleg I.; Madsen, Lars Bojer

    2016-05-01

    We present a theoretical study of the dissociative tunneling ionization process. Analytic expressions for the nuclear kinetic energy distribution of the ionization rates are derived. A particularly simple expression for the spectrum is found by using the Born-Oppenheimer (BO) approximation in conjunction with the reflection principle. These spectra are compared to exact non-BO ab initio spectra obtained through model calculations with a quantum mechanical treatment of both the electronic and nuclear degrees of freedom. In the regime where the BO approximation is applicable, imaging of the BO nuclear wave function is demonstrated to be possible through reverse use of the reflection principle, when accounting appropriately for the electronic ionization rate. A qualitative difference between the exact and BO wave functions in the asymptotic region of large electronic distances is shown. Additionally, the behavior of the wave function across the turning line is seen to be reminiscent of light refraction. For weak fields, where the BO approximation does not apply, the weak-field asymptotic theory describes the spectrum accurately.

  17. TiO2 thin film photocatalyst

    Institute of Scientific and Technical Information of China (English)

    YU Jiaguo

    2004-01-01

    It is well known that the photocatalytic activity of TiO2 thin films strongly depends on the preparing methods and post-treatment conditions, since they have a decisive influence on the chemical and physical properties of TiO2 thin films.Therefore, it is necessary to elucidate the influence of the preparation process and post-treatment conditions on the photocatalytic activity and surface microstructures of the films. This review deals with the preparation of TiO2 thin film photocatalysts by wet-chemical methods (such as sol-gel, reverse micellar and liquid phase deposition) and the comparison of various preparation methods as well as their advantage and disadvantage. Furthermore, it is discussed that the advancement of photocatalytic activity, super-hydrophilicity and bactericidal activity of TiO2 thin film photocatalyst in recent years.

  18. Similarity of ionized gas nebulae around unobscured and obscured quasars

    Science.gov (United States)

    Liu, Guilin; Zakamska, Nadia L.; Greene, Jenny E.

    2014-08-01

    Quasar feedback is suspected to play a key role in the evolution of massive galaxies, by removing or reheating gas in quasar host galaxies and thus limiting the amount of star formation. In this paper, we continue our investigation of quasar-driven winds on galaxy-wide scales. We conduct Gemini Integral Field Unit spectroscopy of a sample of luminous unobscured (type 1) quasars, to determine the morphology and kinematics of ionized gas around these objects, predominantly via observations of the [O III] λ5007 Å emission line. We find that ionized gas nebulae extend out to ˜13 kpc from the quasar, that they are smooth and round, and that their kinematics are inconsistent with gas in dynamical equilibrium with the host galaxy. The observed morphological and kinematic properties are strikingly similar to those of ionized gas around obscured (type 2) quasars with matched [O III] luminosity, with marginal evidence that nebulae around unobscured quasars are slightly more compact. Therefore, in samples of obscured and unobscured quasars carefully matched in [O III] luminosity, we find support for the standard geometry-based unification model of active galactic nuclei, in that the intrinsic properties of the quasars, of their hosts and of their ionized gas appear to be very similar. Given the apparent ubiquity of extended ionized regions, we are forced to conclude that either the quasar is at least partially illuminating pre-existing gas or that both samples of quasars are seen during advanced stages of quasar feedback. In the latter case, we may be biased by our [O III]-based selection against quasars in the early `blow-out' phase, for example due to dust obscuration.

  19. Measurement and Correction of K-Shell Ionization Cross Sections for Copper and Gallium by Electron Impact

    Institute of Scientific and Technical Information of China (English)

    周长庚; 安竹; 罗正明

    2001-01-01

    The K-shell ionization cross sections of Cu and Ga are measured by electron impact and the data of Ga arereported for the first time. The method of a thin chemical compound target with a thick substrate is formallyused in the experiment. The influence of electrons reflected from the substrate is corrected by means of acalculation of electron transport.

  20. Abstracts from the fourth annual meeting of the council on ionizing radiation measurements and standards (CIRMS)

    International Nuclear Information System (INIS)

    The Council on Ionizing Radiation Measurements and Standards held its fourth annual meeting at the National Institute of Standards and Technology, Gaithersburg, Maryland on November 28-30, 1995. The organization represents thousands of users of ionizing radiation and radioactive sources engaged in industrial radiation processing and sterilization, medical radiation diagnostics and therapy, nuclear power, and worker radiation protection programs. CIRMS provides a forum for discussing ionizing radiation issues; identifying, defining and prioritizing needed work; disseminating information on standards; and organizing workshops and meetings to advance ionizing radiation technology. Over 100 participants attended the meeting, which highlighted advanced techniques in radiation dosimetry and radioactivity measurements for the different ionizing radiation communities. Representatives attended from 28 corporations, 10 federal agencies, 8 national laboratories, 12 universities, and 1 state. Advanced techniques and future measurement needs were discussed in four sessions: (I) Medical Dosimetry, Radiology and Nuclear Medicine, (II) Occupational and Radiation Protection Dosimetry, (III) Measurement Techniques for Public and Environmental Radiation Protection, and (IV) Measurement Techniques for Radiation Effects on Materials. An additional session (Session V) was added to this annual meeting on the implementation of ISO 9000 for those CIRMS members involved in instrument and product manufacturing, and those providing radiation measurement services. Abstracts are also included from the poster session (Session VI) held on the final day of the meeting. The 4th Annual Meeting was organized by the Chairman of the Science and Technology Committee, Mr. Joseph C. McDonald of the Battelle Pacific Northwest Laboratory

  1. Development and Applications of Liquid Sample Desorption Electrospray Ionization Mass Spectrometry

    Science.gov (United States)

    Zheng, Qiuling; Chen, Hao

    2016-06-01

    Desorption electrospray ionization mass spectrometry (DESI-MS) is a recent advance in the field of analytical chemistry. This review surveys the development of liquid sample DESI-MS (LS-DESI-MS), a variant form of DESI-MS that focuses on fast analysis of liquid samples, and its novel analy-tical applications in bioanalysis, proteomics, and reaction kinetics. Due to the capability of directly ionizing liquid samples, liquid sample DESI (LS-DESI) has been successfully used to couple MS with various analytical techniques, such as microfluidics, microextraction, electrochemistry, and chromatography. This review also covers these hyphenated techniques. In addition, several closely related ionization methods, including transmission mode DESI, thermally assisted DESI, and continuous flow–extractive DESI, are briefly discussed. The capabilities of LS-DESI extend and/or complement the utilities of traditional DESI and electrospray ionization and will find extensive and valuable analytical application in the future.

  2. Femtosecond Laser Ionization of Organic Amines with Very Low Ionization Potential.

    Science.gov (United States)

    Yatsuhashi, Tomoyuki; Obayashi, Takashi; Tanaka, Michinori; Murakami, Masanao; Nakashima, Nobuaki

    2006-03-01

    The interaction between high intensity femtosecond laser and molecules is one of the most attractive areas in laser chemistry and ionization is the most fundamental subject. Theoretical consideration successfully reproduced the ionization behavior of rare gases. However, the understanding of ionization mechanisms of large molecules is difficult more than those of rare gases due to their complexity. Generally speaking, molecules are harder to ionize than rare gases even if they have the same ionization potential. The suppressed ionization phenomena are one of the important features of molecular ionization. Hankin et al. examined 23 organic molecules with ionization potentials between 8.25 and 11.52 eV. We have examined ionization and/ or fragmentation of many organic molecules, including aromatic compounds, halogenated compounds, methane derivatives etc. at various wavelengths below 10^16 Wcm-2. In order to investigate the nature of molecular ionization, it is interesting to examine a variety of molecule in a wide range of ionization potential. In this study, we examined several organic amines because we can explore the uninvestigated ionization potential range down to 5.95 eV. In addition to the significant suppression of the ionization rates, stepwise ionization behavior, which was not observed in rare gases, was observed.

  3. Recent Methods for the Automatic Evaluation of Thin-Layer and Paper Chromatograms of Labelled Substances

    International Nuclear Information System (INIS)

    The development and results obtained with a new instrument for the automatic scanning of thin-layer and paper chromatograms of labelled substances is described. Using a novel type of gas-flow detector, it is possible to measure all beta-emitters, including 3H, without contact with the probe. Essentially the apparatus consists of a detector and a transport mechanism passing the chromatogram below the detector diaphragm. In view of the small half-value layer of beta-particles in air (approx. 0.3 mm) a strong dependence on distance between detector and chromatogram would be expected. However, there is practically no dependence between 0.5 and 2 mm distance. The explanation presented is that because of the special counter parameters the electrical field extends through the opening of the diaphragm into the space between counter and chromatogram, thereby pulling negative charge carriers produced by ionizing radiation even outside the counter volume into the region of gas amplification around the anode wire. Therefore, the instrument allows fast, direct and non-destructive measurement of thin-layer plates even for 3H, as opposed to the common practice of scraping off small areas of the thin layer and measuring the radioactivity in a liquid scintillation counter. The transport mechanism in its most recent version allows two-dimensional automatic scanning, with continuous or stepwise advance, and correspondingly analogous or digital registration. A ''dot'' recording allows simple visualization of the chromatogram, similar to an autoradiograph, however, in a much shorter time. Small available diaphragm openings down to 0.2 x 2 mm make the instrument useful also for histological preparations and small animal scanning. The instrument is also used for evaluating doubly-labelled chromatograms, for instance separate measurement of 3H and 14C activity in one chromatogram. (author)

  4. The Time Response of Glass Resistive Plate Chambers to Heavily Ionizing Particles

    CERN Document Server

    Artamonov, A; Bogomilov, M; Booth, C; Borghi, S; Catanesi, M G; Chimenti, P; Gastaldi, Ugo; Giani, S; Graulich, J S; Grégoire, G; Grossheim, A; Guglielmi, A; Ivantchenko, V; Kolev, D; Meurer, C; Mezzetto, M; Panman, J; Popov, B; Radicioni, E; Schroeter, R; Temnikov, P; Chernyaev, E; Tsenov, R; Tsukerman, I; Wiebusch, C

    2007-01-01

    The HARP system of resistive plate chambers (RPCs) was designed to perform particle identification by the measurement of the difference in the time-of-flight of different particles. In previous papers an apparent discrepancy was shown between the response of the RPCs to minimum ionizing pions and heavily ionizing protons. Using the kinematics of elastic scattering off a hydrogen target a controlled beam of low momentum recoil protons was directed onto the chambers. With this method the trajectory and momentum, and hence the time-of-flight of the protons can be precisely predicted without need for a measurement of momentum of the protons. It is demonstrated that the measurement of the time-of-arrival of particles by the thin gas-gap glass RPC system of the HARP experiment depends on the primary ionization deposited by the particle in the detector.

  5. Development of an Ionization Chamber for the SPIDER Fission Fragment Detector

    Science.gov (United States)

    Meierbachtol, K.; Tovesson, F.; Arnold, C. W.; Laptev, A. B.; Bredeweg, T. A.; Jandel, M.; Nelson, R. O.; White, M. C.

    2014-05-01

    The ionization chamber component of the SPIDER detector has been designed to measure energy loss and kinetic energy of fragments produced through neutron-induced fission with energy resolutions of <1% and a time-dependent signal collection. Important design elements implemented are an axial configuration of the electrodes for improved energy loss and measurement and a thin silicon nitride entrance window to minimize both energy loss and energy straggling of the incoming fragments. High energy resolution and improved charge resolution from the ionization chamber are combined with the high precision of the upstream time-of-flight component of SPIDER to achieve resolutions in mass and nuclear charge of 1 AMU and Z=1. A discussion of the present resolution capabilities of the ionization chamber will be presented.

  6. Chiral atomically thin films

    Science.gov (United States)

    Kim, Cheol-Joo; Sánchez-Castillo, A.; Ziegler, Zack; Ogawa, Yui; Noguez, Cecilia; Park, Jiwoong

    2016-06-01

    Chiral materials possess left- and right-handed counterparts linked by mirror symmetry. These materials are useful for advanced applications in polarization optics, stereochemistry and spintronics. In particular, the realization of spatially uniform chiral films with atomic-scale control of their handedness could provide a powerful means for developing nanodevices with novel chiral properties. However, previous approaches based on natural or grown films, or arrays of fabricated building blocks, could not offer a direct means to program intrinsic chiral properties of the film on the atomic scale. Here, we report a chiral stacking approach, where two-dimensional materials are positioned layer-by-layer with precise control of the interlayer rotation (θ) and polarity, resulting in tunable chiral properties of the final stack. Using this method, we produce left- and right-handed bilayer graphene, that is, a two-atom-thick chiral film. The film displays one of the highest intrinsic ellipticity values (6.5 deg μm-1) ever reported, and a remarkably strong circular dichroism (CD) with the peak energy and sign tuned by θ and polarity. We show that these chiral properties originate from the large in-plane magnetic moment associated with the interlayer optical transition. Furthermore, we show that we can program the chiral properties of atomically thin films layer-by-layer by producing three-layer graphene films with structurally controlled CD spectra.

  7. Advanced Magnetic Nanostructures

    CERN Document Server

    Sellmyer, David

    2006-01-01

    Advanced Magnetic Nanostructures is devoted to the fabrication, characterization, experimental investigation, theoretical understanding, and utilization of advanced magnetic nanostructures. Focus is on various types of 'bottom-up' and 'top-down' artificial nanostructures, as contrasted to naturally occurring magnetic nanostructures, such as iron-oxide inclusions in magnetic rocks, and to structures such as perfect thin films. Chapter 1 is an introduction into some basic concepts, such as the definitions of basic magnetic quantities. Chapters 2-4 are devoted to the theory of magnetic nanostructures, Chapter 5 deals with the characterization of the structures, and Chapters 6-10 are devoted to specific systems. Applications of advanced magnetic nanostructures are discussed in Chapters11-15 and, finally, the appendix lists and briefly discusses magnetic properties of typical starting materials. Industrial and academic researchers in magnetism and related areas such as nanotechnology, materials science, and theore...

  8. Energy expenditure for water molecule ionization by electron impact in weakly ionized plasma

    International Nuclear Information System (INIS)

    The energy balance of the water molecule ionization by a monoenergetic electron beam with the energy of primary electrons in the interval of 15-1000 eV has been calculated. The dependences of the ionization cost on the water ionization degree within the interval from 0 to 0.1 are obtained. The ionization cost is shown to increase with the ionization degree. In particular, for a primary electron energy of 1000 eV, it increases from 25.26 to 52.45 eV in the examined ionization degree interval

  9. Thin film processes II

    CERN Document Server

    Kern, Werner

    1991-01-01

    This sequel to the 1978 classic, Thin Film Processes, gives a clear, practical exposition of important thin film deposition and etching processes that have not yet been adequately reviewed. It discusses selected processes in tutorial overviews with implementation guide lines and an introduction to the literature. Though edited to stand alone, when taken together, Thin Film Processes II and its predecessor present a thorough grounding in modern thin film techniques.Key Features* Provides an all-new sequel to the 1978 classic, Thin Film Processes* Introduces new topics, and sever

  10. Pyrolyzed thin film carbon

    Science.gov (United States)

    Tai, Yu-Chong (Inventor); Liger, Matthieu (Inventor); Harder, Theodore (Inventor); Konishi, Satoshi (Inventor); Miserendino, Scott (Inventor)

    2010-01-01

    A method of making carbon thin films comprises depositing a catalyst on a substrate, depositing a hydrocarbon in contact with the catalyst and pyrolyzing the hydrocarbon. A method of controlling a carbon thin film density comprises etching a cavity into a substrate, depositing a hydrocarbon into the cavity, and pyrolyzing the hydrocarbon while in the cavity to form a carbon thin film. Controlling a carbon thin film density is achieved by changing the volume of the cavity. Methods of making carbon containing patterned structures are also provided. Carbon thin films and carbon containing patterned structures can be used in NEMS, MEMS, liquid chromatography, and sensor devices.

  11. Multiphoton ionization of uranium hexafluoride

    International Nuclear Information System (INIS)

    Multiphoton ionization (MPI) time-of-flight mass spectroscopy (TOFMS) and photoelectron spectroscopy (PES) studies of UF6 are reported using focused light from the Nd:YAG laser fundamental (λ=1064 nm) and its harmonics (λ=532, 355, or 266 nm), as well as other wavelengths provided by a tunable dye laser. The MPI mass spectra are dominated by the singly and multiply charged uranium ions rather than by the UF+x fragment ions, even at the lowest laser power densities at which signal could be detected. In general, the doubly charged uranium ion (U2+) intensity is much greater than that of the singly charged uranium ion (U+). For the case of the tunable dye laser experiments, the Un+ (n=1--4) wavelength dependence is relatively unstructured and does not show observable resonance enhancement at known atomic uranium excitation wavelengths. The MPI-PES studies reveal only very slow electrons (≤0.5 eV) for all wavelengths investigated. The dominance of the U2+ ion, the absence or very small intensities of UF+x (x=1--3) fragments, the unstructured wavelength dependence, and the preponderance of slow electrons all indicate that mechanisms may exist other than ionization of bare U atoms following the stepwise photodissociation of F atoms from the parent molecule. The data also argue against stepwise photodissociation of UF+x (x=5,6) ions. Neither of the traditional MPI mechanisms (''neutral ladder'' or the ''ionic ladder'') are believed to adequately describe the ionization phenomena observed. We propose that the multiphoton excitation of UF6 under these experimental conditions results in a highly excited molecule, superexcited UF6**

  12. XUV ionization of aligned molecules

    Energy Technology Data Exchange (ETDEWEB)

    Kelkensberg, F.; Siu, W.; Gademann, G. [FOM Institute AMOLF, Science Park 104, NL-1098 XG Amsterdam (Netherlands); Rouzee, A.; Vrakking, M. J. J. [FOM Institute AMOLF, Science Park 104, NL-1098 XG Amsterdam (Netherlands); Max-Born-Institut, Max-Born Strasse 2A, D-12489 Berlin (Germany); Johnsson, P. [FOM Institute AMOLF, Science Park 104, NL-1098 XG Amsterdam (Netherlands); Department of Physics, Lund University, Post Office Box 118, SE-221 00 Lund (Sweden); Lucchini, M. [Department of Physics, Politecnico di Milano, Istituto di Fotonica e Nanotecnologie CNR-IFN, Piazza Leonardo da Vinci 32, 20133 Milano (Italy); Lucchese, R. R. [Department of Chemistry, Texas A and M University, College Station, Texas 77843-3255 (United States)

    2011-11-15

    New extreme-ultraviolet (XUV) light sources such as high-order-harmonic generation (HHG) and free-electron lasers (FELs), combined with laser-induced alignment techniques, enable novel methods for making molecular movies based on measuring molecular frame photoelectron angular distributions. Experiments are presented where CO{sub 2} molecules were impulsively aligned using a near-infrared laser and ionized using femtosecond XUV pulses obtained by HHG. Measured electron angular distributions reveal contributions from four orbitals and the onset of the influence of the molecular structure.

  13. Tunneling Ionization of Diatomic Molecules

    DEFF Research Database (Denmark)

    Svensmark, Jens Søren Sieg

    2016-01-01

    When a molecule is subject to a strong laser field, there is a probability that an electron can escape, even though the electrons are bound by a large potential barrier. This is possible because electrons are quantum mechanical in nature, and they are therefore able to tunnel through potential...... of tunneling ionizaion of molecules is presented and the results of numerical calculations are shown. One perhaps surprising result is, that the frequently used Born-Oppenheimer approximation breaks down for weak fields when describing tunneling ionization. An analytic theory applicable in the weak-field limit...

  14. Quasi free mechanism in single photon double ionization of helium

    International Nuclear Information System (INIS)

    Double ionization of Helium by a single photon is widely believed to proceed through two mechanisms: knock-off (TS1) or shake-off, with the last one dominating at high photon energies. A new mechanism, termed ''Quasi Free Mechanism'' (QFM) was predicted 35 years ago by Amusia and coworkers, but escaped experimental observation till today. Here we provide the first proof of this mechanism using 800 eV photons from the Advanced Light Source. Fragments (electrons and ions) were measured in coincidence using momentum spectroscopy (COLTRIMS). He(2+) ions with zero momentum were found - the fingerprint for the QFM.

  15. Multiphoton ionization with femtosecond laser pulses

    International Nuclear Information System (INIS)

    There are a number of reasons to use subpicosecond pulses in multiphoton ionization experiments. Pulses with shorter risetimes make it possible to study processes with higher rates before one runs into the problem of depletion of target atoms. Furthermore, the momentum of the electron does not change between the point of ionization and the detector if the pulse expires before the electron has time to sample the spatial inhomogeneity of the light intensity. This makes it possible to identify the intensity at which an electron was formed from the energy with which it reaches the detector. Yet another advantage is the fact that the primary ionization products are subject to the ionizing radiation for only a short amount of time, thus reducing the probability of sequential ionization as compared to direct processes. In this paper the experimental results on the multiphoton ionization of xenon with pulses of 100 fs, that were obtained during the preceding year at ENSTA, Palaiseau, will be presented

  16. Influence of multiple ionization in laser filamentation

    International Nuclear Information System (INIS)

    Laser filaments in gases result from the nonlinear balance between optical Kerr self-focusing and plasma generation in the single ionization limit, i.e., the pulse intensity is supposed to remain moderate enough (∼1014 W cm−2) to apply photo-ionization theories valid for an averaged ion charge less than unity. However, no theory has attempted so far to consider how an ionization model allowing a priori multiple-charged states could impact the standard filamentation scenario. Here, we discuss a multiple photo-ionization scheme that relies on probabilities assuming successive single-electron ionizations. We numerically show that a multiple ionization scheme can increase the clamping intensity, the peak electron density and supercontinuum generation in gases with high binding energy, e.g., helium. (paper)

  17. Spatially discontinuous ionization phenomenon in inhomogeneous soil

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    By using X-ray film imaging technology,a phenomenon of discontinuous ionization was observed in the inhomogeneous soil around the grounding electrode on which a surge voltage was applied.A simplified two-phase solid-gas model was built to study the electric field distribution in the soil to explain the discontinuous ionization phenomenon.Analysis showed the differences of the dielectric properties,the shapes and sizes of soil particles can cause discontinuous ionization in the soil.

  18. Quantum electrodynamic perspective on multiphoton ionization

    International Nuclear Information System (INIS)

    A fully quantum nonperturbative method is developed to describe multiphoton ionization in intense fields. It is shown that, treating the radiation field with quantum electrodynamic (QED) theory enables the authors to obtain the above-threshold ionization energy distribution spectrum in analytical form firstly. Moreover, in addition to the well-known semiclassical theory, the framework presented here, derived from a QED perspective, provides a new picture of the multiphoton ionization

  19. ATOMS INTERACTING WITH ELECTROMAGNETIC FIELDS, MULTIPHOTON IONIZATION

    OpenAIRE

    Mainfray, G

    1982-01-01

    The non linear interaction between an intense laser radiation and atoms leads to ionization through the absorption of N photons from the laser radiation via laser-induced virtual states. The multiphoton ionization rate varies as a function of the laser intensity I as IN. We discuss the two most important effects which govern multiphoton ionization processes : resonance effects and laser-coherence effects. In a moderate laser intensity range (107 - 109 W cm-2) corresponding to the two, three o...

  20. Ionizing radiation and orthopaedic prostheses

    Science.gov (United States)

    Rimnac, Clare M.; Kurtz, Steven M.

    2005-07-01

    Ultra high molecular weight polyethylene (UHMWPE) materials have been used successfully as one half of the bearing couple (against metallic alloys or ceramics) in total hip and total knee joint replacements for four decades. This review describes the impact of ionizing radiation (used for sterilization and for microstructural modification via crosslinking) on the performance of UHMWPE total joint replacement components. Gamma radiation sterilization in air leads to oxidative degradation of UHMWPE joint components that occurs during shelf-aging and also during in vivo use. Efforts to mitigate oxidative degradation of UHMWPE joint components include gamma radiation sterilization in inert barrier-packaging and processing treatments to reduce free radicals. Ionizing radiation (both gamma and electron-beam) has recently been used to form highly crosslinked UHMWPEs that have better adhesive and abrasive wear resistance than non-crosslinked UHMWPE, thereby potentially improving the long-term performance of total joint replacements. Along with increased wear resistance, however, there are deleterious changes to ductility and fracture resistance of UHMWPE, and an increased risk of fracture of these components remains a clinical concern.

  1. Biological effects of ionizing radiation

    International Nuclear Information System (INIS)

    It has been emphasised the importance of DNA as the main target for ionizing radiation, that can induce damage by its direct action on this molecule or by an indirect effect mediated by free-radicals generated by water radiolysis. Biological effects of ionizing radiation are influenced not only by the dose but also by the dose-rate and the radiation quality. Radiation induced damage, mainly DNA single and double strand breaks, is detected by molecular sensors which in turn trigger signalling cascades leading to cell cycle arrest to allow DNA repair or programmed cell death (apoptosis). Those effects related with cell death, named deterministic, exhibits a dose-threshold below which they are not observed. Acute radiation syndrome and radiological burns are examples of this kind of effects. Other radiation induced effects, called stochastic, are the consequence of cell transformation and do not exhibit a dose-threshold. This is the case of cancer induction and hereditary effects. The aim of this presentation is briefly describe the main aspects of deterministic and stochastic effects from the point of view of radiobiology and radio pathology. (author)

  2. K-shell ionization by antiprotons

    International Nuclear Information System (INIS)

    We present first calculations for the impact parameter dependence of K-shell ionization rates in anti pCu and in anti pAg collisions at various projectile energies. We show that the effect of the attractive Coulomb potential on the Rutherford trajectory and the anti-binding effect caused by the negative charge of the antiproton result in a considerable increase of the ionization probability. Total ionization cross-sections for proton and antiproton projectiles are compared with each other and with experimental ionization cross-sections for protons. (orig.)

  3. K-shell ionization by antiprotons

    Energy Technology Data Exchange (ETDEWEB)

    Mehler, G.; Mueller, B.; Greiner, W.; Soff, G.

    1987-08-01

    We present calculations for the impact-parameter dependence of K-shell ionization rates in p-bar-Cu and in p-bar-Ag collisions at various projectile energies. We show that the effect of the attractive Coulomb potential on the Rutherford trajectory and the antibinding effect caused by the negative charge of the antiproton result in a considerable increase of the ionization probability. Total ionization cross sections for proton and antiproton projectiles are compared with each other and with experimental ionization cross sections for protons.

  4. Development of dielectric-barrier-discharge ionization.

    Science.gov (United States)

    Guo, Cheng'an; Tang, Fei; Chen, Jin; Wang, Xiaohao; Zhang, Sichun; Zhang, Xinrong

    2015-03-01

    Dielectric-barrier-discharge ionization is an ambient-ionization technique. Since its first description in 2007, it has attracted much attention in such fields as biological analysis, food safety, mass-spectrometry imaging, forensic identification, and reaction monitoring for its advantages, e.g., low energy consumption, solvent-free method, and easy miniaturization. In this review a brief introduction to dielectric barrier discharge is provided, and then a detailed introduction to the dielectric-barrier-discharge-ionization technique is given, including instrumentation, applications, and mechanistic studies. Based on the summary of reported work, possible future uses of this type of ionization source are discussed at the end. PMID:25510973

  5. Tunneling Ionization Time Resolved by Backpropagation

    Science.gov (United States)

    Ni, Hongcheng; Saalmann, Ulf; Rost, Jan-Michael

    2016-07-01

    We determine the ionization time in tunneling ionization by an elliptically polarized light pulse relative to its maximum. This is achieved by a full quantum propagation of the electron wave function forward in time, followed by a classical backpropagation to identify tunneling parameters, in particular, the fraction of electrons that has tunneled out. We find that the ionization time is close to zero for single active electrons in helium and in hydrogen if the fraction of tunneled electrons is large. We expect our analysis to be essential to quantify ionization times for correlated electron motion.

  6. Ionization probes of molecular structure and chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, P.M. [State Univ. of New York, Stony Brook (United States)

    1993-12-01

    Various photoionization processes provide very sensitive probes for the detection and understanding of the spectra of molecules relevant to combustion processes. The detection of ionization can be selective by using resonant multiphoton ionization or by exploiting the fact that different molecules have different sets of ionization potentials. Therefore, the structure and dynamics of individual molecules can be studied even in a mixed sample. The authors are continuing to develop methods for the selective spectroscopic detection of molecules by ionization, and to use these methods for the study of some molecules of combustion interest.

  7. Non-sequential double ionization of molecules

    CERN Document Server

    Prauzner-Bechcicki, J S; Eckhardt, B; Zakrzewski, J; Prauzner-Bechcicki, Jakub S.; Sacha, Krzysztof; Eckhardt, Bruno; Zakrzewski, Jakub

    2004-01-01

    Double ionization of diatomic molecules by short linearly polarized laser pulses is analyzed. We consider the final stage of the ionization process, that is the decay of a highly excited two electron molecule, which is formed after re-scattering. The saddles of the effective adiabatic potential energy close to which simultaneous escape of electrons takes place are identified. Numerical simulations of the ionization of molecules show that the process can be dominated by either sequential or non-sequential events. In order to increase the ratio of non-sequential to sequential ionizations very short laser pulses should be applied.

  8. Effect of p-Layer and i-Layer Properties on the Electrical Behaviour of Advanced a-Si:H/a-SiGe:H Thin Film Solar Cell from Numerical Modeling Prospect

    Directory of Open Access Journals (Sweden)

    Peyman Jelodarian

    2012-01-01

    Full Text Available The effect of p-layer and i-layer characteristics such as thickness and doping concentration on the electrical behaviors of the a-Si:H/a-SiGe:H thin film heterostructure solar cells such as electric field, photogeneration rate, and recombination rate through the cell is investigated. Introducing Ge atoms to the Si lattice in Si-based solar cells is an effective approach in improving their characteristics. In particular, current density of the cell can be enhanced without deteriorating its open-circuit voltage. Optimization shows that for an appropriate Ge concentration, the efficiency of a-Si:H/a-SiGe solar cell is improved by about 6% compared with the traditional a-Si:H solar cell. This work presents a novel numerical evaluation and optimization of amorphous silicon double-junction (a-Si:H/a-SiGe:H thin film solar cells and focuses on optimization of a-SiGe:H midgap single-junction solar cell based on the optimization of the doping concentration of the p-layer, thicknesses of the p-layer and i-layer, and Ge content in the film. Maximum efficiency of 23.5%, with short-circuit current density of 267 A/m2 and open-circuit voltage of 1.13 V for double-junction solar cell has been achieved.

  9. Influence of renormalization shielding on the electron-impact ionization process in dense partially ionized plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Song, Mi-Young; Yoon, Jung-Sik [Plasma Technology Research Center, National Fusion Research Institute, 814-2 Osikdo-Dong, Gunsan-City, Jeollabuk-Do 573-540 (Korea, Republic of); Jung, Young-Dae, E-mail: ydjung@hanyang.ac.kr [Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, 110 8th Street, Troy, New York 12180-3590 (United States); Department of Applied Physics and Department of Bionanotechnology, Hanyang University, Ansan, Kyunggi-Do 426-791 (Korea, Republic of)

    2015-04-15

    The renormalization shielding effects on the electron-impact ionization of hydrogen atom are investigated in dense partially ionized plasmas. The effective projectile-target interaction Hamiltonian and the semiclassical trajectory method are employed to obtain the transition amplitude as well as the ionization probability as functions of the impact parameter, the collision energy, and the renormalization parameter. It is found that the renormalization shielding effect suppresses the transition amplitude for the electron-impact ionization process in dense partially ionized plasmas. It is also found that the renormalization effect suppresses the differential ionization cross section in the peak impact parameter region. In addition, it is found that the influence of renormalization shielding on the ionization cross section decreases with an increase of the relative collision energy. The variations of the renormalization shielding effects on the electron-impact ionization cross section are also discussed.

  10. Renormalization shielding effect on the electron-impact ionization process in dense partially ionized plasmas

    Science.gov (United States)

    Jung, Young-Dae

    2016-05-01

    The influence of renormalization shielding on the electron-impact ionization process is investigated in dense partially ionized plasmas. The effective projectile-target interaction Hamiltonian and the semiclassical trajectory method are employed to obtain the transition amplitude as well as the ionization probability as functions of the impact parameter, the collision energy, and the renormalization parameter. It is found that the renormalization shielding effect suppresses the transition amplitude for the electron-impact ionization process in dense partially ionized plasmas. It is also found that the renormalization effect suppresses the differential ionization cross section in the peak impact parameter region. In addition, it is found that the influence of renormalization shielding on the ionization cross section decreases with an increase of the relative collision energy. The variations of the renormalization shielding effects on the electron-impact ionization cross section are also discussed.

  11. Influence of renormalization shielding on the electron-impact ionization process in dense partially ionized plasmas

    Science.gov (United States)

    Song, Mi-Young; Yoon, Jung-Sik; Jung, Young-Dae

    2015-04-01

    The renormalization shielding effects on the electron-impact ionization of hydrogen atom are investigated in dense partially ionized plasmas. The effective projectile-target interaction Hamiltonian and the semiclassical trajectory method are employed to obtain the transition amplitude as well as the ionization probability as functions of the impact parameter, the collision energy, and the renormalization parameter. It is found that the renormalization shielding effect suppresses the transition amplitude for the electron-impact ionization process in dense partially ionized plasmas. It is also found that the renormalization effect suppresses the differential ionization cross section in the peak impact parameter region. In addition, it is found that the influence of renormalization shielding on the ionization cross section decreases with an increase of the relative collision energy. The variations of the renormalization shielding effects on the electron-impact ionization cross section are also discussed.

  12. Composite electron propagator methods for calculating ionization energies

    Science.gov (United States)

    Díaz-Tinoco, Manuel; Dolgounitcheva, O.; Zakrzewski, V. G.; Ortiz, J. V.

    2016-06-01

    Accurate ionization energies of molecules may be determined efficiently with composite electron-propagator (CEP) techniques. These methods estimate the results of a calculation with an advanced correlation method and a large basis set by performing a series of more tractable calculations in which large basis sets are used with simpler approximations and small basis sets are paired with more demanding correlation techniques. The performance of several CEP methods, in which diagonal, second-order electron propagator results with large basis sets are combined with higher-order results obtained with smaller basis sets, has been tested for the ionization energies of closed-shell molecules from the G2 set. Useful compromises of accuracy and computational efficiency employ complete-basis-set extrapolation for second-order results and small basis sets in third-order, partial third-order, renormalized partial-third order, or outer valence Green's function calculations. Analysis of results for vertical as well as adiabatic ionization energies leads to specific recommendations on the best use of regular and composite methods. Results for 22 organic molecules of interest in the design of photovoltaic devices, benzo[a]pyrene, Mg-octaethylporphyrin, and C60 illustrate the capabilities of CEP methods for calculations on large molecules.

  13. Composite electron propagator methods for calculating ionization energies.

    Science.gov (United States)

    Díaz-Tinoco, Manuel; Dolgounitcheva, O; Zakrzewski, V G; Ortiz, J V

    2016-06-14

    Accurate ionization energies of molecules may be determined efficiently with composite electron-propagator (CEP) techniques. These methods estimate the results of a calculation with an advanced correlation method and a large basis set by performing a series of more tractable calculations in which large basis sets are used with simpler approximations and small basis sets are paired with more demanding correlation techniques. The performance of several CEP methods, in which diagonal, second-order electron propagator results with large basis sets are combined with higher-order results obtained with smaller basis sets, has been tested for the ionization energies of closed-shell molecules from the G2 set. Useful compromises of accuracy and computational efficiency employ complete-basis-set extrapolation for second-order results and small basis sets in third-order, partial third-order, renormalized partial-third order, or outer valence Green's function calculations. Analysis of results for vertical as well as adiabatic ionization energies leads to specific recommendations on the best use of regular and composite methods. Results for 22 organic molecules of interest in the design of photovoltaic devices, benzo[a]pyrene, Mg-octaethylporphyrin, and C60 illustrate the capabilities of CEP methods for calculations on large molecules. PMID:27305999

  14. New thin materials for electronics.

    Energy Technology Data Exchange (ETDEWEB)

    Schwartzberg, Adam

    2012-02-01

    The work described in this report is from an Early Career LDRD to develop and investigate novel thin film organic conductors with drastically improved electronic properties over the current state of the art. In collaboration with the Molecular Foundry at Lawrence Berkeley National Laboratory a Langmuir-Blodgett trough (LB) was built from scavenged parts and added to a scanning Raman microscope at LBNL. First order thin peptoid film samples were fabricated for testing Raman and photoluminescence imagining techniques. Tests showed that a single peptoid sheet can be successfully imaged using confocal Raman spectroscopy and a peptoid sheet can be successfully imaged using near-field photoluminescence at a resolution less than 70 nm. These results have helped position Sandia for advances in this area of MOF film creation. In collaboration with the Molecular Foundry at Lawrence Berkeley National Laboratory, a Langmuir-Blodgett trough (LB) was built and added to a scanning Raman microscope at LBNL. Thin peptoid film samples were fabricated for testing Raman and photoluminescence imagining techniques. Tests showed that a single peptoid sheet can be successfully imaged using confocal Raman spectroscopy, and a peptoid sheet can be successfully imaged using near-field photoluminescence at a resolution less than 70 nm. These results have positioned Sandia for advance in this area of MOF film creation. The interactions with LBNL also led to award of two user projects at the Molecular Foundry at LBNL led by current Sandia staff and the appointment of a current Sandia staff to the Molecular Foundry User Executive Committee.

  15. Current-voltage characteristic of parallel-plane ionization chamber with inhomogeneous ionization

    CERN Document Server

    Stoyanov, Dimitar G

    2007-01-01

    The balances of particles and charges in the volume of parallel-plane ionization chamber are considered. Differential equations describing the distribution of current densities in the chamber volume are obtained. As a result of the differential equations solution an analytical form of the current-voltage characteristic of parallel-plane ionization chamber with inhomogeneous ionization in the volume is got.

  16. Current-voltage characteristic of parallel-plane ionization chamber with inhomogeneous ionization

    Energy Technology Data Exchange (ETDEWEB)

    Stoyanov, D G [Faculty of Engineering and Pedagogy in Sliven, Technical University of Sofia, 59, Bourgasko Shaussee Blvd, 8800 Sliven (Bulgaria)

    2007-08-15

    The balances of particles and charges in the volume of parallel-plane ionization chamber are considered. Differential equations describing the distribution of current densities in the chamber volume are obtained. As a result of the differential equations solution an analytical form of the current-voltage characteristic of parallel-plane ionization chamber with inhomogeneous ionization in the volume is obtained.

  17. Desorption and ionization processes in laser mass spectrometry

    International Nuclear Information System (INIS)

    In this thesis results are reported from a study on the desorption- and ionization process initiated by infra-red laser irradiation (LDMS) or ion bombardment (SIMS) of thin organic sample layers. The study is especially focused on the formation of quasimolecular ions under these conditions. Results of these investigations can be used for a better optimization of the LDMS and SIMS techniques in organic mass spectrometry. First, an overview is given of laser desorption mass spectrometry. Next, the coupling of the laser energy into the organic sample layer is investigated. It is concluded that the laser energy is primarily absorbed by the substrate material and not by the organic overlayer. The formation of quasi-molecular ions, either in the gas phase or in the substrate surface is investigated. The final section reports kinetic energy distributions for ions sputtered from organic solids and liquids. (Auth.)

  18. Ionized carbon in side-illuminated molecular clouds

    International Nuclear Information System (INIS)

    The C II fine-structure line has been observed in five sources for which the ionization front/molecular cloud interface is viewed approximately edge-on. The LSR velocity of the C II emission is generally in good agreement with that observed for molecular species such as CO. However, the observed linewidths of 3-14 km/s are typically wider than those of molecular lines and often show rapid spatial variations in the observed regions. The C II brightness temperature are typically equal to or slightly higher than the dust temperature at all locations observed. In the optically thin approximation, C II excitation temperatures are 100 K or more and column densities are 10 to the 18th/sq cm for all sources except M17, which has a more intense and complicated line profile with a larger spatial extent than any other source observed. 58 refs

  19. Ionization caused by β-emitters and its applications

    International Nuclear Information System (INIS)

    Ionization caused by β-decay of hydrogen-3 (tritium) and strontium-90 has been studied by means of a pulse-counting mode of mass spectrometer. Radiation sources are a titanium plate (10 mm x 15 mm) carrying 150 mCi tritium in the form of titanium hydride, and a silver plate (12.5 mm2) with 5 mCi strontium-90 protected by an extremely thin layer of gold. Target materials are H2 and He gases with the natural abundance ratios. The dependence of the ion peak height on the gas pressure has been examined in the range of 10-4 to approximately 10-7 Torr, and two types of expression, linear and of cube root, were obtained. The mechanism of ion formation in this system is discussed, and its tempting applications are presented. (author)

  20. Multiphoton ionization of uranium hexafluoride

    Science.gov (United States)

    Armstrong, D. P.; Harkins, D. A.; Compton, R. N.; Ding, D.

    1994-01-01

    Multiphoton ionization (MPI) time-of-flight mass spectroscopy (TOFMS) and photoelectron spectroscopy (PES) studies of UF6 are reported using focused light from the Nd:YAG laser fundamental (λ=1064 nm) and its harmonics (λ=532, 355, or 266 nm), as well as other wavelengths provided by a tunable dye laser. The MPI mass spectra are dominated by the singly and multiply charged uranium ions rather than by the UF+x fragment ions, even at the lowest laser power densities at which signal could be detected. In general, the doubly charged uranium ion (U2+) intensity is much greater than that of the singly charged uranium ion (U+). For the case of the tunable dye laser experiments, the Un+ (n=1-4) wavelength dependence is relatively unstructured and does not show observable resonance enhancement at known atomic uranium excitation wavelengths. The MPI-PES studies reveal only very slow electrons (≤0.5 eV) for all wavelengths investigated. The dominance of the U2+ ion, the absence or very small intensities of UF+x (x=1-3) fragments, the unstructured wavelength dependence, and the preponderance of slow electrons all indicate that mechanisms may exist other than ionization of bare U atoms following the stepwise photodissociation of F atoms from the parent molecule. The data also argue against stepwise photodissociation of UF+x (x=5,6) ions. Neither of the traditional MPI mechanisms (``neutral ladder'' or the ``ionic ladder'') are believed to adequately describe the ionization phenomena observed. We propose that the multiphoton excitation of UF6 under these experimental conditions results in a highly excited molecule, superexcited UF6**. The excitation of highly excited UF6** is proposed to be facilitated by the well known ``giant resonance,'' whose energy level lies in the range of 12-14 eV above that of ground state UF6. The highly excited molecule then primarily dissociates, via multiple channels, into Un+, UF+x, fluorine atoms, and ``slow'' electrons, although dissociation

  1. Social trust and ionizing radiation

    International Nuclear Information System (INIS)

    The linkages that exist between the environmental risks associated with nuclear energy production (both perceived and real) and the myriad of social and political issues and processes that influence social trust are a current issue in literature, but are not well explored, particularly for the Canadian context. This paper will examine one particular issue and its relationship with social trust: ionizing radiation and public health. Social trust is defined for this paper as including interpersonal trust, but having a much broader focus, extending to public trust in governments, institutions, corporations, and the power elite, and across whole societies. Of particular interest for the nuclear energy issue is how waning social trust may impact the functioning of democratic decision-making processes, particularly those associated with the siting of waste facilities. Social trust is a central issue in the management of environmental risks, particularly those related to high technology; its absence is seen as a major cause of intractable conflict in decisions related to nuclear power generation and waste disposal. Understanding the dynamics of social trust is important if a resolution is to be found to the nuclear waste management debate in Canada, that is, one that involves broad public, or social, support. For instance, what factors cause distrust to emerge, and when distrust emerges, what authorities do members of affected communities seek out for information and support? This paper begins to examine social trust in relation to human health and ionizing radiation, particularly low dose radiation from radioactive wastes resulting from uranium and radium processing activities in Port Hope, Ontario. These activities date back to the 1930s and are of great concern to community members. This paper looks at some of the roots of public concern, for example, scientific uncertainty around whether or not human health is compromised by exposure to low dose ionizing radiation

  2. Surface-assisted laser desorption ionization mass spectrometry techniques for application in forensics.

    Science.gov (United States)

    Guinan, Taryn; Kirkbride, Paul; Pigou, Paul E; Ronci, Maurizio; Kobus, Hilton; Voelcker, Nicolas H

    2015-01-01

    Matrix-assisted laser desorption ionization (MALDI) mass spectrometry (MS) is an excellent analytical technique for the rapid and sensitive analysis of macromolecules (>700 Da), such as peptides, proteins, nucleic acids, and synthetic polymers. However, the detection of smaller organic molecules with masses below 700 Da using MALDI-MS is challenging due to the appearance of matrix adducts and matrix fragment peaks in the same spectral range. Recently, nanostructured substrates have been developed that facilitate matrix-free laser desorption ionization (LDI), contributing to an emerging analytical paradigm referred to as surface-assisted laser desorption ionization (SALDI) MS. Since SALDI enables the detection of small organic molecules, it is rapidly growing in popularity, including in the field of forensics. At the same time, SALDI also holds significant potential as a high throughput analytical tool in roadside, work place and athlete drug testing. In this review, we discuss recent advances in SALDI techniques such as desorption ionization on porous silicon (DIOS), nano-initiator mass spectrometry (NIMS) and nano assisted laser desorption ionization (NALDI™) and compare their strengths and weaknesses with particular focus on forensic applications. These include the detection of illicit drug molecules and their metabolites in biological matrices and small molecule detection from forensic samples including banknotes and fingerprints. Finally, the review highlights recent advances in mass spectrometry imaging (MSI) using SALDI techniques.

  3. Sodium ionization detector and sensor

    International Nuclear Information System (INIS)

    Work conducted on a basic technology development effort with the Westinghouse Sodium Ionization Detector (SID) sensor is reported. Included are results obtained for three task areas: (1) On-line operational response testing - in-situ calibration techniques; (2) Performance-reliability characteristics of aged filaments; and (3) Evaluation of chemical interference effects. The results showed that a calibrator filament coated with a sodium compound, when activated, does supply the necessary sodium atoms to provide a valid operational in-situ test. The life time of new Cr203-protected SID sensor filaments can be extended by operating at a reduced temperature. However, there also is a reduction in the sensitivity. Non-sodium species, such as products from a smoldering fire and organic aerosols, produce an interference response from the sensor comparable to a typical sodium response

  4. Ionization tube simmer current circuit

    Science.gov (United States)

    Steinkraus, Jr., Robert F.

    1994-01-01

    A highly efficient flash lamp simmer current circuit utilizes a fifty percent duty cycle square wave pulse generator to pass a current over a current limiting inductor to a full wave rectifier. The DC output of the rectifier is then passed over a voltage smoothing capacitor through a reverse current blocking diode to a flash lamp tube to sustain ionization in the tube between discharges via a small simmer current. An alternate embodiment of the circuit combines the pulse generator and inductor in the form of an FET off line square wave generator with an impedance limited step up output transformer which is then applied to the full wave rectifier as before to yield a similar simmer current.

  5. Modeling of associative ionization reactions in hypersonic rarefied flows

    Science.gov (United States)

    Boyd, Iain D.

    2007-09-01

    When vehicles reenter the Earth's atmosphere from space, the hypersonic conditions are sufficiently energetic to generate ionizing reactions. The production of a thin plasma layer around a hypersonic vehicle can block radio waves sent to and from the vehicle, leading to communications blackout. For Earth entry from orbit, the maximum energy involved in molecular collisions requires only associative ionization of air-species to be considered. In the present study, the modeling of such reactions is considered in detail using the direct simulation Monte Carlo (DSMC) method. For typical Earth entry conditions, with a velocity near 8km/s, it is shown that the average ionizing reaction probabilities are small. Special numerical techniques must therefore be used in the DSMC technique in order to numerically resolve these reactions. Additional simulation problems arise from the relatively small mass of the electrons in comparison to the other atoms and molecules in these flow fields. Artificially increasing the electron mass greatly increases computational efficiency, and the viability of this approach is investigated. Simulation results are presented for conditions corresponding to the RAM-C II hypersonic flight experiment that gathered measurements of electron number density. It is demonstrated that simulation results for electron number density in this energy regime are relatively insensitive to the mass of the electrons. Direct comparison of DSMC results with the RAM-C II measurements for electron number density shows excellent agreement. These satisfactory comparisons represent the first direct verification of the ability of the DSMC technique to successfully predict the weak plasma generated around a hypersonic vehicle.

  6. A search for ionized jets towards massive young stellar objects

    CERN Document Server

    Purser, S J D; Hoare, M G; Urquhart, J S; Cunningham, N; Purcell, C R; Brooks, K J; Garay, G; Gúzman, A E; Voronkov, M A

    2016-01-01

    Radio continuum observations using the Australia telescope compact array at 5.5, 9.0, 17.0 and 22.8 GHz have detected free-free emission associated with 45 of 49 massive young stellar objects and HII regions. Of these, 26 sources are classified as ionized jets (12 of which are candidates), 2 as ambiguous jets or disc winds, 1 as a disc-wind, 14 as HII regions and 2 were unable to be categorised. Classification as ionized jets is based upon morphology, radio flux and spectral index, in conjunction with previous observational results at other wavelengths. Radio-luminosity and momentum are found to scale with bolometric luminosity in the same way as low-mass jets, indicating a common mechanism for jet production across all masses. In 13 of the jets, we see associated non-thermal/optically-thin lobes resulting from shocks either internal to the jet and/or at working surfaces. Ten jets display non-thermal (synchrotron emission) spectra in their lobes, with an average spectral index of -0.55 consistent with Fermi a...

  7. Ionization in antiproton-hydrogen collisions

    International Nuclear Information System (INIS)

    Employing the semiclassical approximation we calculate within the coupled-state formalism the ionization probability in antiproton-hydrogen (anti p+H) collisions. In particular we investigate the adiabatic ionization at the distance of closest approach in almost central collisions. Striking differences in the electron excitation probability compared with proton-hydrogen (p+H) collisions are predicted. (orig.)

  8. An ionization chamber with magnetic levitated electrodes

    CERN Document Server

    Kawaguchi, T

    1999-01-01

    A new type of ionization chamber which has magnetically levitated electrodes has been developed. The electrodes are supplied voltages for the repelling of ions by a battery which is also levitated with the electrodes. The characteristics of this ionization chamber are investigated in this paper.

  9. Strong Turbulence in Partially Ionized Plasmas

    DEFF Research Database (Denmark)

    Mikkelsen, Torben; Pécseli, Hans

    1980-01-01

    Experimental investigations of strong turbulence in partially ionized, low-β plasmas are reported. The observed spectra are interpreted by applying Taylor's hypothesis and related to turbulent fluctuations in the ionosphere.......Experimental investigations of strong turbulence in partially ionized, low-β plasmas are reported. The observed spectra are interpreted by applying Taylor's hypothesis and related to turbulent fluctuations in the ionosphere....

  10. Multicomponent transport in weakly ionized mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Giovangigli, V [CMAP, CNRS, Ecole Polytechnique, 91128 Palaiseau (France); Graille, B [Laboratoire de Mathematiques, Universite Paris-Sud, 91405, Orsay (France); Magin, T [Center for Turbulence Research, Stanford University, CA 94305 (United States); Massot, M, E-mail: vincent.giovangigli@polytechnique.f [Laboratoire EM2C, Ecole Centrale de Paris, 92295 Chatenay-Malabry (France)

    2010-06-15

    We discuss transport coefficients in weakly ionized mixtures. We investigate the situations of weak and strong magnetic fields as well as electron temperature nonequilibrium. We present in each regime the Boltzmann equations, examples of transport fluxes, the structure of transport linear systems and discuss their solution by efficient iterative techniques. Numerical simulations are presented for partially ionized high-temperature air.

  11. Ionization and photofragmentation of Ru3(CO)12 and Os3(CO)12

    International Nuclear Information System (INIS)

    In this paper, we use a combination of photoelectron spectroscopy, mass spectrometry, and density functional theory calculations to get a detailed understanding of valence single and double ionization and the subsequent dissociation processes. This is exemplified on benchmark systems, trimetallo-dodecacarbonyls M3(CO)12 with M = Ru, Os, where the energy remaining in the molecule after photoionization can be retrieved by measuring the degree of fragmentation of the molecular ion. The intensity of different mass peaks can thus be directly related to ionization cross sections obtained by photoelectron spectroscopy. We find that the M—CO dissociation energy rises as the number of CO ligands decreases due to dissociation. Moreover, ionization of the CO ligands has a higher cross section than that of the metal center for both single and double ionization. After advanced fragmentation, a CO bond can break and the carbon atom remains bonded to the metal core. In addition, we found that the valence ionization cross sections of M3(CO)12 are maximal at about 40 eV photon energy thus showing a more pronounced shape resonance than Ru and Os-complexes with a single metal atom center. Finally, an np → nd giant resonance absorption causes a significant increase of the ionization cross section above 50 eV for Ru3(CO)12

  12. Ionization and photofragmentation of Ru3(CO)12 and Os3(CO)12

    Science.gov (United States)

    Schalk, Oliver; Josefsson, Ida; Richter, Robert; Prince, Kevin C.; Odelius, Michael; Mucke, Melanie

    2015-10-01

    In this paper, we use a combination of photoelectron spectroscopy, mass spectrometry, and density functional theory calculations to get a detailed understanding of valence single and double ionization and the subsequent dissociation processes. This is exemplified on benchmark systems, trimetallo-dodecacarbonyls M3(CO)12 with M = Ru, Os, where the energy remaining in the molecule after photoionization can be retrieved by measuring the degree of fragmentation of the molecular ion. The intensity of different mass peaks can thus be directly related to ionization cross sections obtained by photoelectron spectroscopy. We find that the M—CO dissociation energy rises as the number of CO ligands decreases due to dissociation. Moreover, ionization of the CO ligands has a higher cross section than that of the metal center for both single and double ionization. After advanced fragmentation, a CO bond can break and the carbon atom remains bonded to the metal core. In addition, we found that the valence ionization cross sections of M3(CO)12 are maximal at about 40 eV photon energy thus showing a more pronounced shape resonance than Ru and Os-complexes with a single metal atom center. Finally, an np → nd giant resonance absorption causes a significant increase of the ionization cross section above 50 eV for Ru3(CO)12.

  13. nvestigation on influencing factors in determination of hydrocarbons in heavy oils by thin-layer chromatography flame/ionization detector.%棒状薄层色谱/氢火焰离子化检测器法测定重油烃族组成影响因素的探讨

    Institute of Scientific and Technical Information of China (English)

    杨海鹰; 顾洁; 蔺玉贵

    2001-01-01

    The influencing factors in the determination of hydrocarbons (saturates, aromatics, resins) in heavy oils by thin layer chromatography/flame ionization detection (TLC/FID) were investigated. It has been found that the solvent co -volatization may cause sample loss during the spotting and developing process, and that the quantitative calibration factors can not be used universally. Because the flame temperature of TLC/FLD is much lower than that of GC/FID, the transformation of different compounds in the flame of FID is varied.%对应用棒状薄层色谱/氢火焰离子化检测器(TLC/FID)测定重油烃族组成(饱和烃、芳烃、胶质)时的影响因素作了探讨。研究发现,在点样及展开过程中,溶剂共挥发可引起样品损失;而且,由于TLC/FID的火焰温度远低于一般GC条件下FID的火焰温度,使不同化合物在FID上的燃烧转化情况有差异,因而其定量校正因子不具有通用性。

  14. Radiation sensitivity of graphene field effect transistors and other thin film architectures

    Science.gov (United States)

    Cazalas, Edward

    An important contemporary motivation for advancing radiation detection science and technology is the need for interdiction of nuclear and radiological materials, which may be used to fabricate weapons of mass destruction. The detection of such materials by nuclear techniques relies on achieving high sensitivity and selectivity to X-rays, gamma-rays, and neutrons. To be attractive in field deployable instruments, it is desirable for detectors to be lightweight, inexpensive, operate at low voltage, and consume low power. To address the relatively low particle flux in most passive measurements for nuclear security applications, detectors scalable to large areas that can meet the high absolute detection efficiency requirements are needed. Graphene-based and thin-film-based radiation detectors represent attractive technologies that could meet the need for inexpensive, low-power, size-scalable detection architectures, which are sensitive to X-rays, gamma-rays, and neutrons. The utilization of graphene to detect ionizing radiation relies on the modulation of graphene charge carrier density by changes in local electric field, i.e. the field effect in graphene. Built on the principle of a conventional field effect transistor, the graphene-based field effect transistor (GFET) utilizes graphene as a channel and a semiconducting substrate as an absorber medium with which the ionizing radiation interacts. A radiation interaction event that deposits energy within the substrate creates electron-hole pairs, which modify the electric field and modulate graphene charge carrier density. A detection event in a GFET is therefore measured as a change in graphene resistance or current. Thin (micron-scale) films can also be utilized for radiation detection of thermal neutrons provided nuclides with high neutron absorption cross section are present with appreciable density. Detection in thin-film detectors could be realized through the collection of charge carriers generated within the

  15. Multiorbital tunneling ionization of the CO molecule

    CERN Document Server

    Wu, J; Kunitski, M; Meckel, M; Voss, S; Sann, H; Kim, H; Jahnke, T; Czasch, A; Dörner, R

    2012-01-01

    We coincidently measure the molecular frame photoelectron angular distribution and the ion sum-momentum distribution of single and double ionization of CO molecules by using circularly and elliptically polarized femtosecond laser pulses, respectively. The orientation dependent ionization rates for various kinetic energy releases allow us to individually identify the ionizations of multiple orbitals, ranging from the highest occupied to the next two lower-lying molecular orbitals for various channels observed in our experiments. Not only the emission of a single electron, but also the sequential tunneling dynamics of two electrons from multiple orbitals are traced step by step. Our results confirm that the shape of the ionizing orbitals determine the strong laser field tunneling ionization in the CO molecule, whereas the linear Stark effect plays a minor role.

  16. Ionization Scheme Development at the ISOLDE RILIS

    Science.gov (United States)

    Fedosseev, V. N.; Marsh, B. A.; Fedorov, D. V.; Köster, U.; Tengborn, E.

    2005-04-01

    The resonance ionization laser ion source (RILIS) of the ISOLDE on-line isotope separation facility is based on the method of laser step-wise resonance ionization of atoms in a hot metal cavity. The atomic selectivity of the RILIS complements the mass selection process of the ISOLDE separator magnets to provide beams of a chosen isotope with greatly reduced isobaric contamination. Using a system of dye lasers pumped by copper vapour lasers, ion beams of 24 elements have been generated at ISOLDE with ionization efficiencies in the range of 0.5-15%. As part of the ongoing RILIS development off-line resonance ionization spectroscopy studies carried out in 2003 and 2004 have determined the optimal three-step ionization schemes for scandium, antimony, dysprosium and yttrium.

  17. Ionization Scheme Development at the ISOLDE RILIS

    International Nuclear Information System (INIS)

    The resonance ionization laser ion source (RILIS) of the ISOLDE on-line isotope separation facility is based on the method of laser step-wise resonance ionization of atoms in a hot metal cavity. The atomic selectivity of the RILIS complements the mass selection process of the ISOLDE separator magnets to provide beams of a chosen isotope with greatly reduced isobaric contamination. Using a system of dye lasers pumped by copper vapour lasers, ion beams of 24 elements have been generated at ISOLDE with ionization efficiencies in the range of 0.5-15%. As part of the ongoing RILIS development off-line resonance ionization spectroscopy studies carried out in 2003 and 2004 have determined the optimal three-step ionization schemes for scandium, antimony, dysprosium and yttrium.

  18. Thin wall ductile and austempered iron castings

    Directory of Open Access Journals (Sweden)

    E. Fraś

    2010-07-01

    Full Text Available It has been shown that it is possible to produce thin wall castings made of ductile iron with wall thickness in the range of 1.2 to 2.9 mm(without chills, cold laps and misruns. Thin wall ductile iron castings can be lighter (380 g than their substitutes made of aluminium alloys (580g. The kinetics of austenitising transformation was studied in unalloyed ductile iron. The advance of transformations during austenitising was monitored by measurement the fraction of martensite and also by dilatometic studies. It has been shown that in thin wall ductile iron castings austenitising at 880 oC for 20 minutes is adequate to obtain the austenite matrix at the end of the first stage of austempering heat treatment cycle.

  19. Electron impact ionization and multiphoton ionization of doped superfluid helium droplets: A comparison.

    Science.gov (United States)

    He, Yunteng; Zhang, Jie; Kong, Wei

    2016-02-28

    We compare characteristics of electron impact ionization (EI) and multiphoton ionization (MPI) of doped superfluid helium droplets using the same droplet source. Selected dopant ion fragments from the two ionization schemes demonstrate different dependence on the doping pressure, which could be attributed to the different ionization mechanisms. While EI directly ionizes helium atoms in a droplet therefore has higher yields for bigger droplets (within a limited size range), MPI is insensitive to the helium in a droplet and is only dependent on the number of dopant molecules. The optimal timing of the ionization pulse also varies with the doping pressure, implying a velocity slip among different sized droplets. Calculations of the doping statistics and ionization probabilities qualitatively agree with the experimental data. Our results offer a word of caution in interpreting the pressure and timing dependence of superfluid helium droplets, and we also devise a scheme in achieving a high degree of doping while limiting the contribution of dopant clusters. PMID:26931697

  20. Advanced Ceramics

    International Nuclear Information System (INIS)

    The First Florida-Brazil Seminar on Materials and the Second State Meeting about new materials in Rio de Janeiro State show the specific technical contribution in advanced ceramic sector. The others main topics discussed for the development of the country are the advanced ceramic programs the market, the national technic-scientific capacitation, the advanced ceramic patents, etc. (C.G.C.)

  1. Positronium formation and ionization in slow positron-hydrogen atom collisions

    International Nuclear Information System (INIS)

    The electron capture and ionization processes in slow collisions of positrons with hydrogen atoms are considered within the advanced adiabatic approach to atomic collisions. The mass asymmetry of the (p,e-,e+) collision system is properly taken into account. The calculated positronium formation and ionization cross sections compare favourably with the available experimental data in the adiabatic energy region. It is shown that the potential energy curve of the 2p σ molecular state supports a quasi-bound level of the three-particle (p,e+,e-) system with an energy of -0.3 eV and decay width of 0.15 eV, approximately. (author)

  2. Thin Magnetically Soft Wires for Magnetic Microsensors

    Directory of Open Access Journals (Sweden)

    Arcady Zhukov

    2009-11-01

    Full Text Available Recent advances in technology involving magnetic materials require development of novel advanced magnetic materials with improved magnetic and magneto-transport properties and with reduced dimensionality. Therefore magnetic materials with outstanding magnetic characteristics and reduced dimensionality have recently gained much attention. Among these magnetic materials a family of thin wires with reduced geometrical dimensions (of order of 1–30 μm in diameter have gained importance within the last few years. These thin wires combine excellent soft magnetic properties (with coercivities up to 4 A/m with attractive magneto-transport properties (Giant Magneto-impedance effect, GMI, Giant Magneto-resistance effect, GMR and an unusual re-magnetization process in positive magnetostriction compositions exhibiting quite fast domain wall propagation. In this paper we overview the magnetic and magneto-transport properties of these microwires that make them suitable for microsensor applications.

  3. Laser desorption/ionization from nanostructured surfaces: nanowires, nanoparticle films and silicon microcolumn arrays

    International Nuclear Information System (INIS)

    Due to their optical properties and morphology, thin films formed of nanoparticles are potentially new platforms for soft laser desorption/ionization (SLDI) mass spectrometry. Thin films of gold nanoparticles (with 12±1 nm particle size) were prepared by evaporation-driven vertical colloidal deposition and used to analyze a series of directly deposited polypeptide samples. In this new SLDI method, the required laser fluence for ion detection was equal or less than what was needed for matrix-assisted laser desorption/ionization (MALDI) but the resulting spectra were free of matrix interferences. A silicon microcolumn array-based substrate (a.k.a. black silicon) was developed as a new matrix-free laser desorption ionization surface. When low-resistivity silicon wafers were processed with a 22 ps pulse length 3xω Nd:YAG laser in air, SF6 or water environment, regularly arranged conical spikes emerged. The radii of the spike tips varied with the processing environment, ranging from approximately 500 nm in water, to ∼2 μm in SF6 gas and to ∼5 μm in air. Peptide mass spectra directly induced by a nitrogen laser showed the formation of protonated ions of angiotensin I and II, substance P, bradykinin fragment 1-7, synthetic peptide, pro14-arg, and insulin from the processed silicon surfaces but not from the unprocessed areas. Threshold fluences for desorption/ionization were similar to those used in MALDI. Although compared to silicon nanowires the threshold laser pulse energy for ionization is significantly (∼10x) higher, the ease of production and robustness of microcolumn arrays offer complementary benefits

  4. Laser desorption/ionization from nanostructured surfaces: nanowires, nanoparticle films and silicon microcolumn arrays

    Energy Technology Data Exchange (ETDEWEB)

    Chen Yong [Department of Chemistry, George Washington University, Washington, DC 20052 (United States); Luo Guanghong [Department of Chemistry, George Washington University, Washington, DC 20052 (United States); Diao Jiajie [Department of Physics, George Washington University, Washington, DC 20052 (United States); Chornoguz, Olesya [Department of Chemistry, George Washington University, Washington, DC 20052 (United States); Reeves, Mark [Department of Physics, George Washington University, Washington, DC 20052 (United States); Vertes, Akos [Department of Chemistry, George Washington University, Washington, DC 20052 (United States)

    2007-04-15

    Due to their optical properties and morphology, thin films formed of nanoparticles are potentially new platforms for soft laser desorption/ionization (SLDI) mass spectrometry. Thin films of gold nanoparticles (with 12{+-}1 nm particle size) were prepared by evaporation-driven vertical colloidal deposition and used to analyze a series of directly deposited polypeptide samples. In this new SLDI method, the required laser fluence for ion detection was equal or less than what was needed for matrix-assisted laser desorption/ionization (MALDI) but the resulting spectra were free of matrix interferences. A silicon microcolumn array-based substrate (a.k.a. black silicon) was developed as a new matrix-free laser desorption ionization surface. When low-resistivity silicon wafers were processed with a 22 ps pulse length 3x{omega} Nd:YAG laser in air, SF{sub 6} or water environment, regularly arranged conical spikes emerged. The radii of the spike tips varied with the processing environment, ranging from approximately 500 nm in water, to {approx}2 {mu}m in SF{sub 6} gas and to {approx}5 {mu}m in air. Peptide mass spectra directly induced by a nitrogen laser showed the formation of protonated ions of angiotensin I and II, substance P, bradykinin fragment 1-7, synthetic peptide, pro14-arg, and insulin from the processed silicon surfaces but not from the unprocessed areas. Threshold fluences for desorption/ionization were similar to those used in MALDI. Although compared to silicon nanowires the threshold laser pulse energy for ionization is significantly ({approx}10x) higher, the ease of production and robustness of microcolumn arrays offer complementary benefits.

  5. 'Active' Thin Sections

    NARCIS (Netherlands)

    De Rooij, M.R.; Bijen, J.M.J.M.

    1999-01-01

    Optical microscopy using thin sections has become more and more important over the last decade to study concrete. Unfortunately, this technique is not capable of studying actually hydrating cement paste. At Delft University of Technology a new technique has been developed using 'active' thin section

  6. Thin films on cantilevers

    NARCIS (Netherlands)

    Nazeer, Hammad

    2012-01-01

    The main goal of the work compiled in this thesis is to investigate thin films for integration in micro electromechanical systems (MEMS). The miniaturization of MEMS actuators and sensors without compromising their performance requires thin films of different active materials with specific propertie

  7. Ionization Cooling using Parametric Resonances

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Rolland P.

    2008-06-07

    Ionization Cooling using Parametric Resonances was an SBIR project begun in July 2004 and ended in January 2008 with Muons, Inc., (Dr. Rolland Johnson, PI), and Thomas Jefferson National Accelerator Facility (JLab) (Dr. Yaroslav Derbenev, Subcontract PI). The project was to develop the theory and simulations of Parametric-resonance Ionization Cooling (PIC) so that it could be used to provide the extra transverse cooling needed for muon colliders in order to relax the requirements on the proton driver, reduce the site boundary radiation, and provide a better environment for experiments. During the course of the project, the theoretical understanding of PIC was developed and a final exposition is ready for publication. Workshops were sponsored by Muons, Inc. in May and September of 2007 that were devoted to the PIC technique. One outcome of the workshops was the interesting and somewhat unexpected realization that the beam emittances using the PIC technique can get small enough that space charge forces can be important. A parallel effort to develop our G4beamline simulation program to include space charge effects was initiated to address this problem. A method of compensating for chromatic aberrations by employing synchrotron motion was developed and simulated. A method of compensating for spherical aberrations using beamline symmetry was also developed and simulated. Different optics designs have been developed using the OptiM program in preparation for applying our G4beamline simulation program, which contains all the power of the Geant4 toolkit. However, no PIC channel design that has been developed has had the desired cooling performance when subjected to the complete G4beamline simulation program. This is believed to be the consequence of the difficulties of correcting the aberrations associated with the naturally large beam angles and beam sizes of the PIC method that are exacerbated by the fringe fields of the rather complicated channel designs that have been

  8. Lipids of the ultra-thin square halophilic archaeon Haloquadratum walsbyi

    OpenAIRE

    Simona LoBasso; Patrizia LoPalco; Giuseppe Mascolo; Angela Corcelli

    2008-01-01

    The lipid composition of the extremely halophilic archaeon Haloquadratum walsbyi was investigated by thin-layer chromatography and electrospray ionization-mass spectrometry. The analysis of neutral lipids showed the presence of vitamin MK-8, squalene, carotene, bacterioruberin and several retinal isomers. The major polar lipids were phosphatidylglycerophosphate methyl ester, phosphatidylglycerosulfate, phosphatidylg...

  9. Radiation protection training for users of ionizing radiation in Hungary

    International Nuclear Information System (INIS)

    According to the current and previous regulation related to the safety use of ionizing radiation, the personnel involved must obtain special qualification in radiation protection. In Hungary the radiation protection training are performed by appropriately certified training centers on basic, advanced and comprehensive levels. Certification of the training centers is given by the competent radiological health/radiation protection authority. The office of the Chief Medical Officer is the certifying authority for advanced and comprehensive levels training, as well as competent Regional Radiological Health Authority is responsible for basic level courses. The content and length of courses are specified in the regulation for all three levels of industrial, laboratory and medical users, in general. Some of the universities, technical and medical oriented are certified for advanced training for students as gradual course. Recently in Hungary there are 47 certified training centers for advanced and comprehensive courses, where the trainers should have a five years job experience in radiation protection and successful completion of comprehensive level course in radiation protection. (authors)

  10. Electrospray ionization and matrix assisted laser desorption/ionization mass spectrometry: powerful analytical tools in recombinant protein chemistry

    DEFF Research Database (Denmark)

    Andersen, Jens S.; Svensson, B; Roepstorff, P

    1996-01-01

    Electrospray ionization and matrix assisted laser desorption/ionization are effective ionization methods for mass spectrometry of biomolecules. Here we describe the capabilities of these methods for peptide and protein characterization in biotechnology. An integrated analytical strategy is presen......Electrospray ionization and matrix assisted laser desorption/ionization are effective ionization methods for mass spectrometry of biomolecules. Here we describe the capabilities of these methods for peptide and protein characterization in biotechnology. An integrated analytical strategy...

  11. Photoelectron angular distributions from two-photon ionization of atoms near ionization threshold

    Institute of Scientific and Technical Information of China (English)

    Lihua Bai; Tingting Cui; Yuheng Liu; Yan Wang; Dongmei Deng; Jihui Tao

    2011-01-01

    @@ Photoelectron angular distributions (PADs) from two-photon ionization of atoms in linearly polarized strong laser fields are obtained in accordance with the nonperturbative quantum scattering theory. We also study the influence of laser wavelength on PADs. For two-photon ionization very close to the ionization threshold, most of the ionized electrons are vertically ejected to the laser polarization. PADs from twophoton ionization of atoms are determined by the second order generalized phased Bessel function at which the ponderomotive parameter plays a key role. In terms of dependence of PADs on laser wavelength,corresponding variations for the ponderomotive parameter are demonstrated.%Photoelectron angular distributions (PADs) from two-photon ionization of atoms in linearly polarized strong laser fields are obtained in accordance with the nonperturbative quantum scattering theory. We also study the influence of laser wavelength on PADs. For two-photon ionization very close to the ionization threshold, most of the ionized electrons are vertically ejected to the laser polarization. PADs from twophoton ionization of atoms are determined by the second order generalized phased Bessel function at which the ponderomotive parameter plays a key role. In terms of dependence of PADs on laser wavelength,corresponding variations for the ponderomotive parameter are demonstrated.

  12. Non-equilibrium ionized blast wave

    Science.gov (United States)

    Wu, S. T.

    1974-01-01

    The structure of a cylindrical blast wave with ionization at non-LTE conditions was calculated using equations previously developed by Wu and Fu (1970). The degree of ionization was predicted by a modified Saha equation. Temperature profiles show that the temperature at non-LTE conditions is lower than at LTE near the shock front. This corresponds to a higher degree of ionization for the non-LTE limit, which indicates that the neutral gas absorption is much more efficient at non-LTE than at the LTE limit. The decaying velocity under non-LTE is approximately 15% less than under LTE.

  13. Ion and electron impact ionization cross sections

    International Nuclear Information System (INIS)

    Several current projects are described in which cross sections of interest to radiation physics are being measured. These include total and multiple ionization cross sections for protons on several gases covering a wide energy range, the measurement of cross sections differential in the angle and energy of ejected electrons for several gases including water vapor, and a review of proton ionization data. The work on water vapor has also been extended to electron and neutral hydrogen impact. A brief discussion is also given of some systematics of ionization cross sections. 13 references

  14. Ionized Gas in the Smith Cloud

    OpenAIRE

    Hill, Alex S.; Haffner, L. Matthew; Reynolds, Ronald J.

    2009-01-01

    We present WHAM observations of Halpha, [N II], and [S II] in the Smith Cloud. A map of Halpha emission from the cloud shows ionized gas coincident with the brightest H I emission, but nearly-as-bright Halpha in some regions with faint H I. The ionized mass of the cloud is at least as large as the neutral mass, > 10^6 M_sun. Ionized gas in the core of the Smith Cloud has an electron temperature 6000 K < T < 16000 K. The observed ratio [N II] / Halpha = 0.39 \\pm 0.09 shows that the cloud has a...

  15. Ionizing photon budget: constraints from galaxies

    Science.gov (United States)

    Östlin, Göran

    2015-08-01

    I will discuss the the production and propagation of ionizing photons in galaxies. Multi wavelength HST imaging and spectroscopy of local starbursts, including candidate Lyman continuum leakers, from the UV to the i-band plus Halpha and Hbeta are used to investigate where ionizing protons are produced and absorbed. We add IFU data, e.g. from MUSE, to further constrain the optical depth to Lyman continuum photons. I will further discuss rest frame UV observations of galaxies at higher redshifts, and their implications for the ionizing photon budget.

  16. Re-ionization and decaying dark matter

    Science.gov (United States)

    Dodelson, Scott; Jubas, Jay M.

    1991-01-01

    Gunn-Peterson tests suggest that the Universe was reionized after the standard recombination epoch. A systematic treatment is presented of the ionization process by deriving the Boltzmann equations appropriate to this regime. A compact solution for the photon spectrum is found in terms of the ionization ratio. These equations are then solved numerically for the Decaying Dark Matter scenario, wherein neutrinos with mass of order 30 eV radiatively decay producing photons which ionize the intergalactic medium. It was found that the neutrino mass and lifetime are severely constrained by Gunn-Peterson tests, observations of the diffuse photon spectrum in the ultraviolet regime, and the Hubble parameter.

  17. Thermochromic behaviors and ionization potentials of organopolysilanes

    Science.gov (United States)

    Yokoyama, Kenji; Yokoyama, Masaaki

    1989-04-01

    Ionization potentials of organopolysilanes with different kinds of substituents were evaluated from the low energy photo-electron emission measurements in air. An aryl-substituted organopolysilane capable of σ - π mixing between Si backbone σ and side-group π electrons gave smaller ionization potential by about 0.1˜0.15 eV compared with alkyl-substituted organopolysilanes. The value of ionization potentials in some alkyl-substituted organopolysilanes which showed thermochromic behaviors was found to vary substantially with thermally induced reversible changes in polymer backbone conformation, indicating that the effective conjugation length of σ electrons decreases above the thermochromic transition temperature.

  18. Intense-field multiphoton ionization of helium

    International Nuclear Information System (INIS)

    The dynamics of multiphoton ionization of helium are investigated through numerical integration of the two-electron time-dependent Schroedinger equation. Using this work as a benchmark, a new single-active-electron model is introduced that gives agreement with He ionization rates to within a few per cent on average, and gives good agreement with He harmonic generation spectra over a laser intensity range of 0.5x1014 to 8.0x1014 W cm-2, and frequencies corresponding to four- and five-photon ionization. (author). Letter-to-the-editor

  19. Electron impact single ionization of copper

    Indian Academy of Sciences (India)

    L K Jha; O P Roy; B N Roy

    2000-09-01

    Electron impact single ionization cross sections of copper have been calculated in the binary encounter approximation using accurate expression for as given by Vriens and Hartree–Fock momentum distribution for the target electron. The BEA calculation based on the usual procedure does not show satisfactory agreement with experiment in this case but a striking modification is found to be successful in explaining the experimental observations. The discrepancy is linked with the ionization of the 310 electrons and probably effective single ionization does not take place from 3 shell of copper leading to smaller values of experimental cross sections.

  20. Biological Effects of Ionizing Radiation

    International Nuclear Information System (INIS)

    The aim of this work is to verify the existence of the adaptive response phenomenon induced by low doses of ionizing radiation in living cells.A wild-type yeast Saccharomyces cerevisiae (Baker's yeast) was chosen as the biological target.As a parameter to quantify the sensibility of the target to radiation, the Lethal Dose 50 (LD50 ) was observed. In our experimental condition a value of (60 ± 1) Gy was measured for LD50 with Dose Rate of (0.44 ± 0.03) Gy/min. The method employed to show up the adaptive response phenomenon consisted in exposing the sample to low ''conditioning'' doses, which would initiate these mechanisms. Later the samples with and without conditioning were exposed to higher ''challenging'' doses (such as LD50), and the surviving fractions were compared. In order to maximize the differences, the doses and the time between irradiations were varied. The best results were obtained with both a conditioning dose of (0.44 ± 0.03) Gy and a waiting time of 2 hs until the application of the challenging dose. Following this procedures the 80% of the conditioned samples has survived, after receiving the application of the LD50. The adaptive response phenomenon was also verified for a wide range of challenging doses

  1. Advances in radiation processing of polymeric materials

    International Nuclear Information System (INIS)

    In this paper we review recent advances in industrial applications of electron-beam irradiation in the field of polymer processing at the Takasaki Radiation Chemistry Research Establishment (TRCRE) of JAERI (Japan Atomic Energy Research Institute), and the Whiteshell Laboratories of AECL Research, Canada. Irradiation of a substrate with ionizing radiation produces free radicals through ionization and excitation events. The subsequent chemistry of these radicals is used in radiation processing as a substitute for conventional processing techniques based on heating and/or the addition of chemicals. The advantages of radiation processing include the formation of novel products with desirable material properties, favourable overall process economics and, often, environmental benefits

  2. Advances in nuclear science and technology

    CERN Document Server

    Greebler, Paul

    1968-01-01

    Advances in Nuclear Science and Technology Volume 4 provides information pertinent to the fundamental aspects of advanced reactor concepts. This book discusses the advances in various areas of general applicability, including modern perturbation theory, optimal control theory, and industrial application of ionizing radiations.Organized into seven chapters, this volume begins with an overview of the technology of sodium-cooled fast breeder power reactors and gas-cooled power reactors. This text then examines the key role of reactor safety in the development of fast breeder reactors. Other chapt

  3. Wave-packet analysis of strong-field ionization of sodium in the quasistatic regime*

    Science.gov (United States)

    Bunjac, Andrej; Popović, Duška B.; Simonović, Nenad S.

    2016-05-01

    Strong field ionization of the sodium atom in the tunnelling and over-the-barrier regimes is studied by examining the valence electron wave-packet dynamics in the static electric field. The lowest state energy and the ionization rate determined by this method for different strengths of the applied field agree well with the results obtained using other methods. The initial period of the nonstationary decay after switching the field on is analyzed and discussed. It is demonstrated that, if the Keldysh parameter is significantly lower than one (quasistatic regime), the probability of ionization by a laser pulse can be obtained from the static rates. Contribution to the Topical Issue "Advances in Positron and Electron Scattering", edited by Paulo Limao-Vieira, Gustavo Garcia, E. Krishnakumar, James Sullivan, Hajime Tanuma and Zoran Petrovic.

  4. 3D Modeling of Laser Propagation in Ionizing Gas and Plasma

    Science.gov (United States)

    Cooley, J.; Antonsen, T., Jr.; Huang, C.; Mori, W.

    2003-10-01

    The interaction of a high intensity laser with ionizing gas and plasmas is of current interest for both Laser Wakefield Accelerators and x-ray generation. We have developed a 3D fluid simulation code based on the same quasistatic approximation used in the 2D code WAKE [1]. The object oriented structure of the code also allows it to couple to the quickPIC particle code [2]. We will present 3D studies of the ionization scattering instability [3], which occurs when a laser pulse propagates in an ionizing gas. [1] P. Mora and T. Antonsen, Jr., Phys. Plasmas 4(1), January 1997 [2] J. Cooley, T. Antonsen, Jr., C. Huang, etal., Proceedings, Advanced Accelerator Concepts, 2002 [3] Z. Bian and T. Antonsen, Jr., Phys. Plasmas 8(7), July 2001 * work supported by NSF and DOE

  5. Nanocoatings and ultra-thin films technologies and applications

    CERN Document Server

    Tiginyanu, Ion

    2011-01-01

    Gives a comprehensive account of the developments of nanocoatings and ultra-thin films. This book covers the fundamentals, processes of deposition and characterisation of nanocoatings, as well as the applications. It is suitable for the glass and glazing, automotive, electronics, aerospace, construction and biomedical industries in particular.$bCoatings are used for a wide range of applications, from anti-fogging coatings for glass through to corrosion control in the aerospace and automotive industries. Nanocoatings and ultra-thin films provides an up-to-date review of the fundamentals, processes of deposition, characterisation and applications of nanocoatings. Part one covers technologies used in the creation and analysis of thin films, including chapters on current and advanced coating technologies in industry, nanostructured thin films from amphiphilic molecules, chemical and physical vapour deposition methods and methods for analysing nanocoatings and ultra-thin films. Part two focuses on the applications...

  6. Thinning Invariant Partition Structures

    CERN Document Server

    Starr, Shannon

    2011-01-01

    A partition structure is a random point process on $[0,1]$ whose points sum to 1, almost surely. In the case that there are infinitely many points to begin with, we consider a thinning action by: first, removing points independently, such that each point survives with probability $p>0$; and, secondly, rescaling the remaining points by an overall factor to normalize the sum again to 1. We prove that the partition structures which are "thinning divisible" for a sequence of $p$'s converging to 0 are mixtures of the Poisson-Kingman partition structures. We also consider the property of being "thinning invariant" for all $p \\in (0,1)$.

  7. Biomimetic thin film synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Graff, G.L.; Campbell, A.A.; Gordon, N.R.

    1995-05-01

    The purpose of this program is to develop a new process for forming thin film coatings and to demonstrate that the biomimetic thin film technology developed at PNL is useful for industrial applications. In the biomimetic process, mineral deposition from aqueous solution is controlled by organic functional groups attached to the underlying substrate surface. The coatings process is simple, benign, inexpensive, energy efficient, and particularly suited for temperature sensitive substrate materials (such as polymers). In addition, biomimetic thin films can be deposited uniformly on complex shaped and porous substrates providing a unique capability over more traditional line-of-sight methods.

  8. The critical ionization velocity - a bibliography

    International Nuclear Information System (INIS)

    A list of all relevant contributions, known to the authors, concerning the critical ionization velocity phenomena is presented. The contributions are classified and described in a few sentences. (Authors)

  9. Multiple ionization of atoms by ion impact

    International Nuclear Information System (INIS)

    In order to model the energy deposition of fast ions as they slow down in gaseous media, information about the ionization occurring in collisions between ions and target atoms/molecules is required. Our measurements of doubly differential electron emission cross sections provide detailed information about the ionization process but do not provide any information about the final states of the target. They also do not distinguish between the emission of one or more target electrons in a single collision. It is important to know the relative importance of multiple-, with respect to single-, target ionization in order to accurately model the energy deposition. To date, multiple ionization of He, Ne, Ar, Kr, and Xe targets has been studied. Primarily, H and He ions were used, although some data for heavier ions (C,N and O) have also been obtained

  10. Electron impact ionization of large krypton clusters

    Institute of Scientific and Technical Information of China (English)

    Li Shao-Hui; Li Ru-Xin; Ni Guo-Quan; Xu Zhi-Zhan

    2004-01-01

    We show that the detection of ionization of very large van der Waals clusters in a pulsed jet or a beam can be realized by using a fast ion gauge. Rapid positive feedback electron impact ionization and fragmentation processes,which are initially ignited by electron impact ionization of the krypton clusters with the electron current of the ion gauge, result in the appearance of a progressional oscillation-like ion spectrum, or just of a single fast event under critical conditions. Each line in the spectrum represents a correlated explosion or avalanche ionization of the clusters.The phenomena have been analysed qualitatively along with a Rayleigh scattering experiment of the corresponding cluster jet.

  11. Classification of the LHC BLM Ionization Chamber

    CERN Document Server

    Stockner, M; Fabjan, Christian Wolfgang; Holzer, E B; Kramer, Daniel

    2008-01-01

    The LHC beam loss monitoring (BLM) system must prevent the super conducting magnets from quenching and protect the machine components from damage. The main monitor type is an ionization chamber. About 4000 of them will be installed around the ring. The lost beam particles initiate hadronic showers through the magnets and other machine components. These shower particles are measured by the monitors installed on the outside of the accelerator equipment. For the calibration of the BLM system the signal response of the ionization chamber is simulated in GEANT4 for all relevant particle types and energies (keV to TeV range). For validation, the simulations are compared to measurements using protons, neutrons, photons and mixed radiation fields at various energies and intensities. This paper will focus on the signal response of the ionization chamber to various particle types and energies including space charge effects at high ionization densities.

  12. High-Temperature Ionization in Protoplanetary Disks

    CERN Document Server

    Desch, Steven J

    2015-01-01

    We calculate the abundances of electrons and ions in the hot (> 500 K), dusty parts of protoplanetary disks, treating for the first time the effects of thermionic and ion emission from the dust grains. High-temperature ionization modeling has involved simply assuming that alkali elements such as potassium occur as gas-phase atoms and are collisionally ionized following the Saha equation. We show that the Saha equation often does not hold, because free charges are produced by thermionic and ion emission and destroyed when they stick to grain surfaces. This means the ionization state depends not on the first ionization potential of the alkali atoms, but rather on the grains' work functions. The charged species' abundances typically rise abruptly above about 800 K, with little qualitative dependence on the work function, gas density, or dust-to-gas mass ratio. Applying our results, we find that protoplanetary disks' dead zone, where high diffusivities stifle magnetorotational turbulence, has its inner edge locat...

  13. Ionization applications in food industry - Generalities

    International Nuclear Information System (INIS)

    This paper outlines different applications of the ionization in food treatments and their purposes. Irradiation of food with low doses (below 1 kgy) is used for germination inhibition, insects sterilization, disinfestation and senescence delays. Applications with medium doses (from 1 to 10 kgy) are used for extension of shelf life, elimination of pathogenic microorganisms and improving technological properties. Applications with high doses (superior to 10 Kgy) are used for food sterilization, only in some specific cases. Necessary doses in various applications of food ionization are given as well as minimal doses for food sterilization. In some cases where treatment of food by only ionization do not permit to attain the fixed object, ionizing treatment is combined with an other type of treatment as: refrigeration, heat treatments, packing, dehydration and chemical treatments. 3 tabs., 5 refs. (F.M.)

  14. Assembly and Applications of Carbon Nanotube Thin Films

    Institute of Scientific and Technical Information of China (English)

    Hongwei ZHU; Bingqing WEI

    2008-01-01

    The ultimate goal of current research on carbon nanotubes (CNTs) is to make breakthroughs that advance nanotechnological applications of bulk CNT materials. Especially, there has been growing interest in CNT thin films because of their unique and usually enhanced properties and tremendous potential as components for use in nano-electronic and nano-mechanical device applications or as structural elements in various devices. If a synthetic or a post processing method can produce high yield of nanotube thin films, these structures will provide tremendous potential for fundamental research on these devices. This review will address the synthesis, the post processing and the device applications of self-assembled nanotube thin films.

  15. Ionization energy of acetone by vacuum ultraviolet mass-analyzed threshold ionization spectrometry

    International Nuclear Information System (INIS)

    Mass-analyzed threshold ionization (MATI) time-of-flight mass spectrometer using coherent vacuum ultraviolet (VUV) laser generated by four-wave difference frequency mixing (FWDFM) in Kr has been constructed and utilized to obtain the accurate ionization energy of acetone. From the MATI onsets measured from various applied pulsed fields, the ionization energy to the ionic ground state of acetone has been determined to be 9.7074 ± 0.0019 eV.

  16. A correction to Birks' Law in liquid argon ionization chamber simulations for highly ionizing particles

    International Nuclear Information System (INIS)

    We present a study of the performance of Birks' Law in liquid argon ionization chamber simulations as applied to highly ionizing particles, such as particles with multiple electric charges or with magnetic charge. We used Birks' Law to model recombination effects in a GEANT4 simulation of heavy ions in a liquid argon calorimeter. We then compared the simulation to published heavy-ion data to extract a highly ionizing particle correction to Birks' Law.

  17. Positron impact ionization of atomic hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Jones, G.O.; Charlton, M.; Slevin, J.; Laricchia, G.; Kover, A.; Poulsen, M.R.; Chormaic, S.N. (University Coll., London (United Kingdom). Dept. of Physics and Astronomy)

    1993-08-14

    Ionization cross sections for positrons impacting on atomic hydrogen have been measured for kinetic energies in the range 15-700 eV. This has been done in a crossed-beam geometry where a magnetically guided positron beam intersects a hydrogen gas jet emanating from a radio frequency discharge tube. Electron impact ionization cross sections were also measured with the same apparatus thus facilitating comparison with, and normalization to, published results. (author).

  18. Positron impact ionization of atomic hydrogen

    International Nuclear Information System (INIS)

    Ionization cross sections for positrons impacting on atomic hydrogen have been measured for kinetic energies in the range 15-700 eV. This has been done in a crossed-beam geometry where a magnetically guided positron beam intersects a hydrogen gas jet emanating from a radio frequency discharge tube. Electron impact ionization cross sections were also measured with the same apparatus thus facilitating comparison with, and normalization to, published results. (author)

  19. Inner-shell ionization and stopping power

    International Nuclear Information System (INIS)

    For better understanding of various aspects in stopping phenomena such as Z13-dependence, shell correction, geometrical effect, direction dependence etc., it seems to be helpful to examine theoretically and experimentally the elementary processes which include plasmon excitation, single electron excitation and inner-shell excitation/ionization. In the present, impact-parameter dependent stopping power is discussed in connection with inner-shell ionization

  20. The warm ionized medium in spiral galaxies

    CERN Document Server

    Haffner, L M; Beckman, J E; Wood, K; Slavin, J D; Giammanco, C; Madsen, G J; Zurita, A; Reynolds, R J

    2009-01-01

    This article reviews observations and models of the diffuse ionized gas that permeates the disk and halo of our Galaxy and others. It was inspired by a series of invited talks presented during an afternoon scientific session of the 65th birthday celebration for Professor Carl Heiles held at Arecibo Observatory in August 2004. This review is in recognition of Carl's long standing interest in and advocacy for studies of the ionized as well as the neutral components of the interstellar medium.

  1. Fundamental studies of molecular multiphoton ionization

    International Nuclear Information System (INIS)

    For several years the authors have performed fundamental studies of molecular multiphoton ionization (MPI). We will present a potpourri of techniques and results chosen to illustrate the interesting complexities of molecular MPI. Techniques used include time-of-flight mass spectroscopy, photoelectron spectroscopy, supersonic expansion cooling of molecular beams, harmonic generation, two-color laser MPI, and polarization spectroscopy. Whenever possible the relevance of these results to resonance ionization spectroscopy schemes will be delineated. 23 references, 10 figures

  2. Drift waves in a weakly ionized plasma

    DEFF Research Database (Denmark)

    Popovic, M.; Melchior, H.

    1968-01-01

    A dispersion relation for low frequency drift waves in a weakly ionized plasma has been derived, and through numerical calculations the effect of collisions between the charged and the neutral particles is estimated.......A dispersion relation for low frequency drift waves in a weakly ionized plasma has been derived, and through numerical calculations the effect of collisions between the charged and the neutral particles is estimated....

  3. How periodic orbit bifurcations drive multiphoton ionization

    OpenAIRE

    Huang, S.; Chandre, C; Uzer, T.

    2006-01-01

    The multiphoton ionization of hydrogen by a strong bichromatic microwave field is a complex process prototypical for atomic control research. Periodic orbit analysis captures this complexity: Through the stability of periodic orbits we can match qualitatively the variation of experimental ionization rates with a control parameter, the relative phase between the two modes of the field. Moreover, an empirical formula reproduces quantum simulations to a high degree of accuracy. This quantitative...

  4. Advance care directives

    Science.gov (United States)

    ... advance directive; Do-not-resuscitate - advance directive; Durable power of attorney - advance care directive; POA - advance care directive; Health care agent - advance care directive; Health care proxy - ...

  5. Two-photon ionization thresholds of matrix-assisted laser desorption/ionization matrix clusters.

    Science.gov (United States)

    Lin, Q; Knochenmuss, R

    2001-01-01

    Direct two-photon ionization of the matrix has been considered a likely primary ionization mechanism in matrix-assisted laser desorption/ionization (MALDI) mass spectrometry. This mechanism requires that the vertical ionization threshold of matrix materials be below twice the laser photon energy. Because dimers and larger aggregates may be numerous in the early stages of the MALDI plume expansion, their ionization thresholds are important as well. We have used two-color two-photon ionization to determine the ionization thresholds of jet cooled clusters of an important matrix, 2,5-dihydroxy benzoic acid (DHB), and mixed clusters with the thermal decomposition product of DHB, hydroquinone. The thresholds of the clusters were reduced by only a few tenths of an eV compared to the monomers, to an apparent limit of 7.82 eV for pure DHB clusters. None of the investigated clusters can be directly ionized by two nitrogen laser photons (7.36 eV), and the ionization efficiency at the thresholds is low. PMID:11507754

  6. Commercial applications of food ionization in France

    International Nuclear Information System (INIS)

    Due to the long history of nuclear energy in France, French public is not frightened by nuclear applications in its everyday life. The first industrial initiative on food ionization dates back to 1956. In 1980, the Joint Expert Committee on Food Ionization concluded that food ionization up to a certain maximum dose presented neither toxicological nor nutritional hazard. This opened the new era for the industrial development. But in 1988, a draft directive to harmonize national legislations was issued by the Commission of European Communities. This stopped many industrial initiatives due to uncertainty. It is estimated that nearly 14,000 tons of various food items have been ionized in France in 1991. About 40% are spices, followed by dry fruit, vegetables, and deboned poultry meat. Most of the present applications are intended to eliminate microorganisms. In 1992, 8 industrial facilities were in operation, mostly using gamma sources. Local research associations were founded to promote food ionization. Food ionization development in the past 30 years has been rapid and important, but the future of this process depends on the European harmonization of legislations. (K.I.)

  7. New standards for ionizing radiation measurements

    International Nuclear Information System (INIS)

    The Ionizing Radiation Division has developed new national standards for mammographic X rays and for brachytherapy sources, such as iodine-125. The Attix chamber, a variable volume free-air ionization chamber, has been established as the primary national standard for mammographic X rays. The Attix chamber resides in the newly developed NIST Mammography Calibration Range and will be used to perform routine calibrations. The wide-angle free-air ionization chamber utilizes a large volume and a novel electric field configuration in order to circumvent the limitations of conventional free-air chambers. Seventeen beam qualities for X rays from molybdenum (Mo) and rhodium (Rh) anodes have been parameterized for the calibration of mammographic ionization chambers. The beam qualities available include anode/filter combinations of Mo/Mo, Mo/Rh and Rh/Rh. The mammography range was developed in collaborations with the U.S. Food and Drug Administration's (FDA) Center for Devices and Radiological Health, the implementors of the Mammography Quality Standards Act (MQSA) of 1992. The wide-angle free-air ionization chamber has been used to measure the output of two types of iodine-125 seeds, those with resin balls and those with silver wire. Both free-air chambers have been intercompared with the Ritz parallel-plate free-air ionization chamber

  8. Multiple ionization of argon by helium ions

    Science.gov (United States)

    Montanari, C. C.; Miraglia, J. E.

    2016-09-01

    We apply the continuum distorted-wave eikonal initial state and the independent electron model to describe the multiple ionization of Ar by He2+ and He+ in the energy range 0.1-10 Mev amu-1. Auger-like post collisional processes are included, which enhance the high energy multiple ionization cross sections via ionization of the inner shells. All Ar electrons (K, L and M-shells) have been included in these calculations. The results agree well with the experimental data at high energies, where the post-collisional ionization is the main contribution. At intermediate impact energies the description is also good though it tends to overestimate the triple and quadruple ionization data at intermediate energies. We analyze this by comparing the present results for He+2 in Ar, with previous ones for He+2 in Ne and Kr. It was found that the theoretical description improves from Ne to Ar and Kr, with the latter being nicely described even at intermediate energies. The present formalism is also tested for Ar inner shell and total ionization cross sections. In all the cases the results above 0.1 MeV amu-1 are quite reasonable, as compared with the experimental data available and with the ECPSSR values.

  9. Thin Solid Oxide Cell

    DEFF Research Database (Denmark)

    2010-01-01

    The present invention relates to a thin and in principle unsupported solid oxide cell, comprising at least a porous anode layer, an electrolyte layer and a porous cathode layer, wherein the anode layer and the cathode layer comprise an electrolyte material, at least one metal and a catalyst...... material, and wherein the overall thickness of the thin reversible cell is about 150 [mu]m or less, and to a method for producing same. The present invention also relates to a thin and in principle unsupported solid oxide cell, comprising at least a porous anode layer, an electrolyte layer and a porous...... cathode layer, wherein the anode layer and the cathode layer comprise an electrolyte material and a catalyst material, wherein the electrolyte material is doper zirconia, and wherein the overall thickness of the thin reversible cell is about 150 [mu]m or less, and to a method for producing same...

  10. Thin film device applications

    CERN Document Server

    Kaur, Inderjeet

    1983-01-01

    Two-dimensional materials created ab initio by the process of condensation of atoms, molecules, or ions, called thin films, have unique properties significantly different from the corresponding bulk materials as a result of their physical dimensions, geometry, nonequilibrium microstructure, and metallurgy. Further, these characteristic features of thin films can be drasti­ cally modified and tailored to obtain the desired and required physical characteristics. These features form the basis of development of a host of extraordinary active and passive thin film device applications in the last two decades. On the one extreme, these applications are in the submicron dimensions in such areas as very large scale integration (VLSI), Josephson junction quantum interference devices, magnetic bubbles, and integrated optics. On the other extreme, large-area thin films are being used as selective coatings for solar thermal conversion, solar cells for photovoltaic conver­ sion, and protection and passivating layers. Ind...

  11. Ceramic Composite Thin Films

    Science.gov (United States)

    Ruoff, Rodney S. (Inventor); Stankovich, Sasha (Inventor); Dikin, Dmitriy A. (Inventor); Nguyen, SonBinh T. (Inventor)

    2013-01-01

    A ceramic composite thin film or layer includes individual graphene oxide and/or electrically conductive graphene sheets dispersed in a ceramic (e.g. silica) matrix. The thin film or layer can be electrically conductive film or layer depending the amount of graphene sheets present. The composite films or layers are transparent, chemically inert and compatible with both glass and hydrophilic SiOx/silicon substrates. The composite film or layer can be produced by making a suspension of graphene oxide sheet fragments, introducing a silica-precursor or silica to the suspension to form a sol, depositing the sol on a substrate as thin film or layer, at least partially reducing the graphene oxide sheets to conductive graphene sheets, and thermally consolidating the thin film or layer to form a silica matrix in which the graphene oxide and/or graphene sheets are dispersed.

  12. Rotation planar chromatography coupled on-line with atmospheric pressure chemical ionization mass spectrometry.

    Science.gov (United States)

    Van Berkel, Gary J; Llave, Jonathan J; De Apadoca, Marilyn F; Ford, Michael J

    2004-01-15

    The coupling of a rotation planar preparative thin-layer chromatography system on-line with mass spectrometry is demonstrated using a simple plumbing scheme and a self-aspirating heated nebulizer probe of a corona discharge atmospheric pressure chemical ionization source. The self-aspiration of the heated nebulizer delivers approximately 20 microL/min of the 3.0 mL/min eluate stream to the mass spectrometer, eliminating the need for an external pump in the system. The viability of the coupling is demonstrated with a three-dye mixture composed of fat red 7B, solvent green 3, and solvent blue 35 separated and eluted from a silica gel-coated rotor using toluene. The real-time characterization of the dyes eluting from the rotor is illustrated in positive ion full-scan mode. Other self-aspirating ion source systems including atmospheric pressure photoionization, electrospray ionization, and inductively coupled plasma ionization, for example, might be configured and used in a similar manner coupled to the chromatograph to expand the types of analytes that could be ionized, detected, and characterized effectively.

  13. DC field response of one-dimensional flames using an ionized layer model

    KAUST Repository

    Xiong, Yuan

    2015-11-18

    We develop a simplified model to better explain electric current response when direct current (DC) is applied to a flame. In particular, different current responses have been observed by changing the polarity of the DC in a sub-saturated current regime that results from the presence of ions and electrons in the flame zone. A flame zone was modeled as a thin, ionized layer located in one-dimensional DC electric fields. We derived simplified model-governing equations from species equations by implementing mobility differences dependent on the type of charged particle, particularly between ions and electrons; we performed experiments to substantiate the model. Results showed that the sub-saturated current and local field intensity were significantly influenced by the polarity of the DC because of the combined effect of unequal mobility of charged particles and the position of the ionized layer in the gap relative to two electrodes. When an energized electrode is close to the ionized layer, applying a negative DC causes a more rapid increase in current than by applying a positive DC to the same electrode. Results from our experimental measurement of current using counterflow diffusion flames agreed qualitatively well with the model predictions. A sensitivity analysis using dimensional and non-dimensional parameters also supported the importance of the mobility difference and the relative location of the ionized layer on the electric current response.

  14. Nanostructured silicon surface modifications for as a selective matrix-free laser desorption/ionization mass spectrometry.

    Science.gov (United States)

    Tsao, C W; Lin, C H; Cheng, Y C; Chien, C C; Chang, C C; Chen, W Y

    2012-06-01

    Matrix-assisted laser desorption/ionization mass spectrometry is an established soft ionization method that is widely applied to analyze biomolecules. The UV-absorbing organic matrix is essential for biomolecule ionization; however, it also creates matrix background interference, which results in problematic analyses of biomolecules of less than 700 Da. Therefore, this study investigates hydrophilic, hydrophobic cationic, anionic and immobilized metal ion surface chemical modifications to advance nanostructured silicon mass spectrometry performance (nSi-MS). This investigation provides information required for a possible novel mass spectroscopy that combines surface-enhanced and nanostructured silicon surface-assisted laser desorption/ionization mass spectrometry for the selective detection of specific compounds of a mixture. PMID:22531330

  15. Statistical approach to multiphoton multielectron ionization of atoms

    International Nuclear Information System (INIS)

    State density and temperature of excited atom were found. Diffusion equation with sink was suggested for describing ionization process. It was shown that possibility of multielectron ionization was dictated by the competition of atom heating by external field and evaporation ionization. Numerical calculation of xenon atom ionization was conducted and correlation with experimental results was given

  16. Measurement and Multiple Scattering Correction of K-Shell Ionization Cross Sections of Silver by Electron Impact

    Institute of Scientific and Technical Information of China (English)

    ZHOU Chang-Geng; FU Yu-Chuan; AN Zhu; TANG Chang-Huan; LUO Zheng-Ming

    2001-01-01

    The K-shell ionization cross sections of silver have been measured by electron impact. In order to overcomethe difliculties in. Preparing a self-supporting thin targets, a thin target with a thick substrate was used inour experiments. The influence of electrons reflected from the substrate was corrected by means of a detailed calculation of electron transport. The path of the electrons passing through the silver target of 31.2 μg/cm2 wascalculated by the EGS4 Monte Carlo program. This method of correction for the measurement is reported for the first time.

  17. VELO RF foil thinning

    CERN Document Server

    Van Dieten, Derk

    2013-01-01

    An overview of the project in thinning an aluminium foil for the VELO section of the LHCb experiment. The foil was to be thinned from 0.3 mm to 0.1 mm and this report describes the very first tests. Approximate etching was used and a vacuum test and metrology test was performed. The first results look promising as the piece remains vacuum tight after etching and the first metrology data shows a good etch with further development required

  18. Recent Advances in Solar Cell Technology

    Science.gov (United States)

    Landis, Geoffrey A.; Bailey, Sheila G.; Piszczor, Michael F., Jr.

    1996-01-01

    The advances in solar cell efficiency, radiation tolerance, and cost over the last decade are reviewed. Potential performance of thin-film solar cells in space are discussed, and the cost and the historical trends in production capability of the photovoltaics industry are considered with respect to the requirements of space power systems. Concentrator cells with conversion efficiency over 30%, and nonconcentrating solar cells with efficiency over 25% are now available, and advanced radiation-tolerant cells and lightweight, thin-film arrays are both being developed. Nonsolar applications of solar cells, including thermophotovoltaics, alpha- and betavoltaics, and laser power receivers, are also discussed.

  19. Advanced Optical Metrology for XRAY Replication Mandrels and Mirrors Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Advanced x-ray observatories such as IXO and GenX will require thousands of thin shell mirror segments produced by replication using convex mandrels. Quality and...

  20. Growth of CdTe on Si(100) surface by ionized cluster beam technique: Experimental and molecular dynamics simulation

    Science.gov (United States)

    Araghi, Houshang; Zabihi, Zabiholah; Nayebi, Payman; Ehsani, Mohammad Mahdi

    2016-10-01

    II-VI semiconductor CdTe was grown on the Si(100) substrate surface by the ionized cluster beam (ICB) technique. In the ICB method, when vapors of solid materials such as CdTe were ejected through a nozzle of a heated crucible into a vacuum region, nanoclusters were created by an adiabatic expansion phenomenon. The clusters thus obtained were partially ionized by electron bombardment and then accelerated onto the silicon substrate at 473 K by high potentials. The cluster size was determined using a retarding field energy analyzer. The results of X-ray diffraction measurements indicate the cubic zinc blende (ZB) crystalline structure of the CdTe thin film on the silicon substrate. The CdTe thin film prepared by the ICB method had high crystalline quality. The microscopic processes involved in the ICB deposition technique, such as impact and coalescence processes, have been studied in detail by molecular dynamics (MD) simulation.

  1. Epidermal electronics with advanced capabilities in near-field communication.

    Science.gov (United States)

    Kim, Jeonghyun; Banks, Anthony; Cheng, Huanyu; Xie, Zhaoqian; Xu, Sheng; Jang, Kyung-In; Lee, Jung Woo; Liu, Zhuangjian; Gutruf, Philipp; Huang, Xian; Wei, Pinghung; Liu, Fei; Li, Kan; Dalal, Mitul; Ghaffari, Roozbeh; Feng, Xue; Huang, Yonggang; Gupta, Sanjay; Paik, Ungyu; Rogers, John A

    2015-02-25

    Epidermal electronics with advanced capabilities in near field communications (NFC) are presented. The systems include stretchable coils and thinned NFC chips on thin, low modulus stretchable adhesives, to allow seamless, conformal contact with the skin and simultaneous capabilities for wireless interfaces to any standard, NFC-enabled smartphone, even under extreme deformation and after/during normal daily activities.

  2. Optical nonlinearity in Ar and N$_2$ near the ionization threshold

    CERN Document Server

    Wahlstrand, J K; Milchberg, H M

    2011-01-01

    We directly measure the nonlinear refractive index in argon and nitrogen in a thin gas target at laser intensities near the ionization threshold. No instantaneous negative nonlinear refractive index is observed, nor is saturation, in contrast with a previous measurement [Loriot et al., Opt. Express v. 17, 13429 (2009)] and calculations [Br\\'ee et al., Phys. Rev. Lett. v. 106, 183902 (2011)]. In addition, we are able to cleanly separate the electronic and rotational components of the nonlinear response in nitrogen. In both Ar and N$_2$, we observe the peak instantaneous index response scale linearly with the laser intensity until the point of ionization, whereupon it turns abruptly negative and ~constant, consistent with plasma generation.

  3. Ionization for Hf-and W-L-shell by electron impact

    Institute of Scientific and Technical Information of China (English)

    Yang Dai-Lun; Luo Xiao-Bing; Fu Yu-Chuan; He Fu-Qing; Long Xian-Guan; Peng Xiu-Feng; Luo Zheng-Ming

    2004-01-01

    Electron-induced Hf-, W-L-shell partial, total production cross sections, mean ionization cross sections and HfLa-shell ionization cross sections (at two energies) have been measured as functions of electron energies (from near threshold to 36keV). The influence of electrons reflected from the backing of the thin targets on measured results was corrected using a model to relate to the electron transport process. The mean paths of electron multi-scattered in the target itself (including forward and backward scattering) were calculated by means of Monte Carlo program (EGS4)and they were used to correct measured results. A comparison with both theoretical predictions was given.

  4. Evidence for DCO+ as a probe of ionization in the warm disk surface

    CERN Document Server

    Favre, Cécile; Cleeves, L Ilsedore; Hersant, Franck; Qi, Chunhua; Aikawa, Yuri

    2015-01-01

    In this Letter we model the chemistry of DCO$^{+}$ in protoplanetary disks. We find that the overall distribution of the DCO$^{+}$ abundance is qualitatively similar to that of CO but is dominated by thin layer located at the inner disk surface. To understand its distribution, we investigate the different key gas-phase deuteration pathways that can lead to the formation of DCO$^{+}$. Our analysis shows that the recent update in the exothermicity of the reaction involving CH$_2$D$^{+}$ as a parent molecule of DCO$^{+}$ favors deuterium fractionation in warmer conditions. As a result the formation of DCO$^{+}$ is enhanced in the inner warm surface layers of the disk where X-ray ionization occurs. Our analysis points out that DCO$^{+}$ is not a reliable tracer of the CO snow line as previously suggested. We thus predict that DCO$^{+}$ is a tracer of active deuterium and in particular X-ray ionization of the inner disk.

  5. Shotgun Approach for Quantitative Imaging of Phospholipids Using Nanospray Desorption Electrospray Ionization Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Lanekoff, Ingela T.; Thomas, Mathew; Laskin, Julia

    2014-02-04

    Mass spectrometry imaging (MSI) has been extensively used for determining spatial distributions of molecules in biological samples, and there is increasing interest in using MSI for quantification. Nanospray desorption electrospray ionization, or nano-DESI, is an ambient MSI technique where a solvent is used for localized extraction of molecules followed by nanoelectrospray ionization. Doping the nano-DESI solvent with carefully selected standards enables online quantification during MSI experiments. In this proof-of-principle study, we demonstrate this quantification approach can be extended to provide shotgun-like quantification of phospholipids in thin brain tissue sections. Specifically, two phosphatidylcholine (PC) standards were added to the nano-DESI solvent for simultaneous imaging and quantification of 22 PC species observed in nano-DESI MSI. Furthermore, by combining the quantitative data obtained in the individual pixels, we demonstrate quantification of these PC species in seven different regions of a rat brain tissue section.

  6. Observations of Absorption Lines from Highly Ionized Atoms

    Science.gov (United States)

    Jenkins, E. B.

    1984-01-01

    In the ultraviolet spectra of hot stars, absorption lines can be seen from highly ionized species in the interstellar medium. Observations of these features which have been very influential in revising the perception of the medium's various physical states, are discussed. The pervasiveness of O 6 absorption lines, coupled with complementary observations of a diffuse background in soft X-rays and EUV radiation, shows that there is an extensive network of low density gas (n approx. fewX 0.001/cucm) existing at coronal temperatures, 5.3 or = log T or = 6.3. Shocks created by supernova explosions or mass loss from early-type stars can propagate freely through space and eventually transfer a large amount of energy to the medium. To create the coronal temperatures, the shocks must have velocities in excess of 150 km/sec; shocks at somewhat lower velocity 9v or = 100 km/sec) can be directly observed in the lines of Si3. Observations of other lines in the ultraviolet, such as Si 4V and C 5, may highlight the widespread presence of energetic uv radiation from very hot, dward stars. More advanced techniques in visible and X-ray astronomical spectroscopy may open up for inspection selected lines from atoms in much higher stages of ionization.

  7. Materials characterization using ion bombardment and multiphoton resonance ionization

    International Nuclear Information System (INIS)

    The combination of energetic ion bombardment with multiphoton resonance ionization (MPRI) spectroscopy has proven to be an important advancement in surface science. The goal of this project is continuing the development of MPRI of desorbed neutrals as a surface analytical tool. The method for accomplishing this is a detailed examination of the factors which govern a measurement and the implementation of the optimum experimental approach. Initially, a review of the progress in laser post-ionization of desorbed neutral particles is presented. This is followed by a description of the newly redesigned instrument, emphasizing detailed characterization of the high current ion source and the reflecting time-of-flight mass spectrometer. Using the new apparatus, the quantitative aspects of the measurement are examined and the fractions of desorbed ions and neutrals are determined using several matrices. The In concentration in a set of silicon wafers is measured, yielding a detection limit of 9 parts-per-trillion. Finally, the prospects for employing this experiment for measuring the half-life of the rare double beta decay of 136Xe to 136Ba are assessed

  8. Multistage Reactive Transmission-Mode Desorption Electrospray Ionization Mass Spectrometry

    Science.gov (United States)

    Peters, Kevin C.; Comi, Troy J.; Perry, Richard H.

    2015-09-01

    Elucidating reaction mechanisms is important for advancing many areas of science such as catalyst development. It is often difficult to probe fast reactions at ambient conditions with high temporal resolution. In addition, systems involving reagents that cross-react require analytical methods that can minimize interaction time and specify their order of introduction into the reacting system. Here, we explore the utility of transmission mode desorption electrospray ionization (TM-DESI) for reaction monitoring by directing a microdroplet spray towards a series of meshes with micrometer-sized openings coated with reagents, an approach we call multistage reactive TM-DESI (TM n -DESI, where n refers to the number of meshes; n = 2 in this report). Various stages of the reaction are initiated at each mesh surface, generating intermediates and products in microdroplet reaction vessels traveling towards the mass spectrometer. Using this method, we investigated the reactivity of iron porphyrin catalytic hydroxylation of propranolol and other substrates. Our experimental results indicate that TM n -DESI provides the ability to spatially separate reagents and control their order of introduction into the reacting system, thereby minimizing unwanted reactions that lead to catalyst deactivation and degradation products. In addition, comparison with DESI-MS analyses (the Zare and Latour laboratories published results suggesting accessible reaction times desorption/ionization per MS scan, increasing the number of analytes and reactions that can be characterized in a single experiment.

  9. Ametryne degradation by ionizing radiation

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Debora Cristina de; Mori, Manoel Nunes; Duarte, Celina Lopes [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)]. E-mails: deboracandrade@globo.com; mnmori@ipen.br; clduarte@ipen.br; Melo, Rita Paiva [Technological and Nuclear Institute (ITN), Sacavem (Portugal)]. E-mail: ritamelo@itn.pt

    2007-07-01

    Ametryne may be released to the environment during its manufacture, transport, storage, formulation and use as selective herbicide for the control of annual broadleaf and grass weeds. It is applied as an aqueous suspension for preemergence or post-directed applications on crops. Depending on the pesticide formulation and type of application, ametryne residues may be detectable in water, soil and on the surfaces for months or years. The herbicide used to this study was Ametryne (commercial name, Gesapax 500), commonly used on field crops and on corn and commercialized since 1975. Ametryne was analyzed by gas chromatography (GC Shimadzu 17A), after extraction with hexane/dichloromethane (1:1 v/v) solution. The calibration curve was obtained with a regression coefficient of 0.9871. In addition, the relative standard deviation was lower than 10%. The radiation-processing yield was evaluated by the destruction G-value (Gd) (Eq. 1), that is defined by the number of destroyed molecules by absorption of 100 eV of energy from ionizing radiation. Different concentrations of the herbicide (11.4 mol L{sup -1}; 22.7 mol L{sup -1}; 34.1 mol L{sup -1} and 45.5 mol L{sup -1}) were irradiated at the AECL 'Gammacell 220' {sup 60}Co source, with 1 kGy, 3 kGy, 6 kGy, 9 kGy, 12 kGy, 15 kGy and 30 kGy absorbed doses. After irradiation processing, the ametryne highest reduction rate occurs at low doses of radiation: at 6 kGy more than 85-90% of all ametryne compounds were removed. Two products of incomplete degradation of ametryne were identified as s-triazyne isomers. However, further work is needed in order to fully understand the ametryne degradation mechanisms the degradation yield of ametryne depends on its initial concentration and the process seems to be more efficient at higher concentrations. (author)

  10. Application of Solid Phase Microextraction followed by Chromatograph-Flame Ionization Detector for Sampling and Analysis of Acetonitrile in Air

    OpenAIRE

    NEMATULLAH KURD; ABDULRAHMAN BAHRAMI; FARSHID GHORBANI-SHAHNA; MAHMOUD HEIDARI

    2015-01-01

    Acetonitrile used as a solvent in manufactures and affects to central nervous system from inhalation exposure. The aim of this study was to develop a micro-solid phase extraction method for the determination of acetonitrile in the air matrix. The sampling was performed with a small diameter fused silica fiber coated with a thin film of stationary phase and was subsequently desorbed and analyzed by gas chromatograph equipped with a flame ionization detector (GC/FID). The effects of laboratory ...

  11. Detailed Investigations of Interactions between Ionizing Radiation and Neutral Gases

    Energy Technology Data Exchange (ETDEWEB)

    Landers, Allen L

    2014-03-31

    We are investigating phenomena that stem from the many body dynamics associated with ionization of an atom or molecule by photon or charged particle. Our program is funded through the Department of Energy EPSCoR Laboratory Partnership Award in collaboration with Lawrence Berkeley National Laboratory. We are using variations on the well established COLTRIMS technique to measure ions and electrons ejected during these interactions. Photoionization measurements take place at the Advanced Light Source at LBNL as part of the ALS-COLTRIMS collaboration with the groups of Reinhard Dörner at Frankfurt and Ali Belkacem at LBNL. Additional experiments on charged particle impact are conducted locally at Auburn University where we are studying the dissociative molecular dynamics following interactions with either ions or electrons over a velocity range of 1 to 12 atomic units.

  12. Ionization in Atmospheres of Brown Dwarfs and Extrasolar Planets V: Alfv\\'{e}n Ionization

    CERN Document Server

    Stark, Craig R; Diver, Declan A; Rimmer, Paul B

    2013-01-01

    Observations of continuous radio and sporadic X-ray emission from low-mass objects suggest they harbour localized plasmas in their atmospheric environments. For low-mass objects, the degree of thermal ionization is insufficient to qualify the ionized component as a plasma, posing the question: what ionization processes can efficiently produce the required plasma that is the source of the radiation? We propose Alfv\\'{e}n ionization as a mechanism for producing localized pockets of ionized gas in the atmosphere, having sufficient degrees of ionization ($\\geq10^{-7}$) that they constitute plasmas. We outline the criteria required for Alfv\\'{e}n ionization and demonstrate it's applicability in the atmospheres of low-mass objects such as giant gas planets, brown dwarfs and M-dwarfs for both solar and sub-solar metallicities. We find that Alfv\\'{e}n ionization is most efficient at mid to low atmospheric pressures where a seed plasma is easier to magnetize and the pressure gradients needed to drive the required neut...

  13. Mass spectrometry of solid samples in open air using combined laser ionization and ambient metastable ionization

    Science.gov (United States)

    He, X. N.; Xie, Z. Q.; Gao, Y.; Hu, W.; Guo, L. B.; Jiang, L.; Lu, Y. F.

    2012-01-01

    Mass spectrometry of solid samples in open air was carried out using combined laser ionization and metastable ionization time-of-flight mass spectrometry (LI-MI-TOFMS) in ambient environment for qualitative and semiquantitative (relative analyte information, not absolute information) analysis. Ambient metastable ionization using a direct analysis in realtime (DART) ion source was combined with laser ionization time-of-flight mass spectrometry (LI-TOFMS) to study the effects of combining metastable and laser ionization. A series of metallic samples from the National Institute of Standards and Technology (NIST 494, 495, 498, 499, and 500) and a pure carbon target were characterized using LI-TOFMS in open air. LI-MI-TOFMS was found to be superior to laser-induced breakdown spectroscopy (LIBS). Laser pulse energies between 10 and 200 mJ at the second harmonic (532 nm) of an Nd:YAG laser were applied in the experiment to obtain a high degree of ionization in plasmas. Higher laser pulse energy improves signal intensities of trace elements (such as Fe, Cr, Mn, Ni, Ca, Al, and Ag). Data were analyzed by numerically calculating relative sensitivity coefficients (RSCs) and limit of detections (LODs) from mass spectrometry (MS) and LIBS spectra. Different parameters, such as boiling point, ionization potential, RSC, LOD, and atomic weight, were shown to analyze the ionization and MS detection processes in open air.

  14. Highly efficient ionization of phosphopeptides at low pH by desorption electrospray ionization mass spectrometry†

    OpenAIRE

    Pan, Ning; Liu, Pengyuan; Cui, Weidong; Tang, Bo; Shi, Jingmin; Chen, Hao

    2013-01-01

    A fast and novel strategy for efficient ionization of phosphopeptides in mixtures is reported, in which the sample is acidified to low pH to suppress the deprotonation of phosphate groups and then followed by direct analysis using liquid sample desorption electrospray ionization mass spectrometry (DESI-MS).

  15. A search for ionized jets towards massive young stellar objects

    Science.gov (United States)

    Purser, S. J. D.; Lumsden, S. L.; Hoare, M. G.; Urquhart, J. S.; Cunningham, N.; Purcell, C. R.; Brooks, K. J.; Garay, G.; Gúzman, A. E.; Voronkov, M. A.

    2016-07-01

    Radio continuum observations using the Australia telescope compact array at 5.5, 9.0, 17.0 and 22.8 GHz have detected free-free emission associated with 45 of 49 massive young stellar objects and H II regions. Of these, 26 sources are classified as ionized jets (12 of which are candidates), 2 as ambiguous jets or disc winds, 1 as a disc-wind, 14 as H II regions and 2 were unable to be categorized. Classification as ionized jets is based upon morphology, radio flux and spectral index, in conjunction with previous observational results at other wavelengths. Radio luminosity and momentum are found to scale with bolometric luminosity in the same way as low-mass jets, indicating a common mechanism for jet production across all masses. In 13 of the jets, we see associated non-thermal/optically thin lobes resulting from shocks either internal to the jet and/or at working surfaces. 10 jets display non-thermal (synchrotron emission) spectra in their lobes, with an average spectral index of α = -0.55 consistent with Fermi acceleration in shocks. This shows that magnetic fields are present, in agreement with models of jet formation incorporating magnetic fields. Since the production of collimated radio jets is associated with accretion processes, the results presented in this paper support the picture of disc-mediated accretion for the formation of massive stars with an upper limit on the jet phase lasting approximately 6.5 × 104 yr. Typical mass-loss rates in the jet are found to be 1.4 × 10-5 M⊙ yr-1 with associated momentum rates of the order of (1-2) × 10-2 M⊙ km s-1 yr-1.

  16. Vibrational Distribution of Hydrogen Molecular Ions in High-Energy Ionization Processes

    Institute of Scientific and Technical Information of China (English)

    CHEN Shao-Hao; HE Chun-Long; CHEN Chao; LI Jia-Ming

    2005-01-01

    @@ A theoretical time-dependent wave-packet dynamics method is applied to calculate the distribution of vibrational states of hydrogen molecular ions produced in high-energy ionization processes of hydrogen molecules. The isotope effect is elucidated in agreement with the available experimental measurements. Our proposed method should be readily applied in other atomic and molecular processes considering great advances in electronic computation science and technology.

  17. ADVANCE PAYMENTS

    CERN Multimedia

    Human Resources Division

    2002-01-01

    Administrative Circular Nº 8 makes provision for the granting of advance payments, repayable in several monthly instalments, by the Organization to the members of its personnel. Members of the personnel are reminded that these advances are only authorized in exceptional circumstances and at the discretion of the Director-General. In view of the current financial situation of the Organization, and in particular the loans it will have to incur, the Directorate has decided to restrict the granting of such advances to exceptional or unforeseen circumstances entailing heavy expenditure and more specifically those pertaining to social issues. Human Resources Division Tel. 73962

  18. Advance payments

    CERN Multimedia

    Human Resources Division

    2003-01-01

    Administrative Circular N 8 makes provision for the granting of advance payments, repayable in several monthly instalments, by the Organization to the members of its personnel. Members of the personnel are reminded that these advances are only authorized in exceptional circumstances and at the discretion of the Director-General. In view of the current financial situation of the Organization, and in particular the loans it will have to incur, the Directorate has decided to restrict the granting of such advances to exceptional or unforeseen circumstances entailing heavy expenditure and more specifically those pertaining to social issues. Human Resources Division Tel. 73962

  19. US Polycrystalline Thin Film Solar Cells Program

    Science.gov (United States)

    Ullal, Harin S.; Zweibel, Kenneth; Mitchell, Richard L.

    1989-11-01

    The Polycrystalline Thin Film Solar Cells Program, part of the United States National Photovoltaic Program, performs R and D on copper indium diselenide and cadmium telluride thin films. The objective of the program is to support research to develop cells and modules that meet the U.S. Department of Energy's long-term goals by achieving high efficiencies (15 to 20 percent), low-cost ($50/m(sup 2)), and long-time reliability (30 years). The importance of work in this area is due to the fact that the polycrystalline thin-film CuInSe2 and CdTe solar cells and modules have made rapid advances. They have become the leading thin films for PV in terms of efficiency and stability. The U.S. Department of Energy has increased its funding through an initiative through the Solar Energy Research Institute in CuInSe2 and CdTe with subcontracts to start in spring 1990.

  20. US polycrystalline thin film solar cells program

    Energy Technology Data Exchange (ETDEWEB)

    Ullal, H S; Zweibel, K; Mitchell, R L [Solar Energy Research Inst., Golden, CO (USA)

    1989-11-01

    The Polycrystalline Thin Film Solar Cells Program, part of the United States National Photovoltaic Program, performs R D on copper indium diselenide and cadmium telluride thin films. The objective of the Program is to support research to develop cells and modules that meet the US Department of Energy's long-term goals by achieving high efficiencies (15%-20%), low-cost ($50/m{sup 2}), and long-time reliability (30 years). The importance of work in this area is due to the fact that the polycrystalline thin-film CuInSe{sub 2} and CdTe solar cells and modules have made rapid advances. They have become the leading thin films for PV in terms of efficiency and stability. The US Department of Energy has increased its funding through an initiative through the Solar Energy Research Institute in CuInSe{sub 2} and CdTe with subcontracts to start in Spring 1990. 23 refs., 5 figs.

  1. Pressurized ionization chamber detectors for industrial use

    International Nuclear Information System (INIS)

    The measurement of the thickness of the sheets made of different materials, e.g. metal, plastic, paper, cellulose, rubber, etc., is one of many industrial applications of nuclear techniques. The ionizing radiation detectors of ionization chamber type are based on measuring the variations in either exposure rate (for gamma radiation) or absorbed dose rate (for beta radiation) occurring in materials of different thickness, placed between the radiation source and the detector. The variations in exposure rate and absorbed dose rate can be traced by using radiation detectors of the ionization chamber type, which convert the exposure rate, X point, or the absorbed dose rate, D point, into a proportional electric current. The more stable the ionization current of the chambers (keeping a constant exposure rate or absorbed dose rate), the slighter the variations that can be detected in either exposure rate or absorbed dose rate, hence in the absorbing material placed between the radiation source and the detector. Based on these facts, several variants of such detectors, including the ionization chamber CIS-P5M-100Kr, CIS-P2M-1000Kr and CIS-P8M-70Kr, have been made. (author)

  2. Conceptual basis of resonance ionization spectroscopy

    International Nuclear Information System (INIS)

    Resonance Ionization Spectroscopy (RIS) can b defined as a state-selective detection process in which tunable lasers are used to promote transitions from the selected state of the atoms or molecules in question to higher states, one of which will be ionized by the absorption of another photon. At least one resonance step is used in the stepwise ionization process, and it has been shown that the ionization probability of the spectroscopically selected species can nearly always be made close to unity. Since measurements of the number of photoelectrons or ions can be made very precisely and even one electron (or under vacuum conditions, one ion) can be detected, the technique can be used to make quantitative measurements of very small populations of the state-selected species. Counting of individual atoms has special meaning for detection of rare events. The ability to make saturated RIS measurements opens up a wide variety of applications to both basic and applied research. We view RIS as a specific type of multi-photon ionization in which the goal is to make quantitative measurements of quantum-selected populations in atomic or molecular systems. 16 references

  3. Multiphoton ionization of large water clusters.

    Science.gov (United States)

    Apicella, B; Li, X; Passaro, M; Spinelli, N; Wang, X

    2014-05-28

    Water clusters are multimers of water molecules held together by hydrogen bonds. In the present work, multiphoton ionization in the UV range coupled with time of flight mass spectrometry has been applied to water clusters with up to 160 molecules in order to obtain information on the electronic states of clusters of different sizes up to dimensions that can approximate the bulk phase. The dependence of ion intensities of water clusters and their metastable fragments produced by laser ionization at 355 nm on laser power density indicates a (3+1)-photon resonance-enhanced multiphoton ionization process. It also explains the large increase of ionization efficiency at 355 nm compared to that at 266 nm. Indeed, it was found, by applying both nanosecond and picosecond laser ionization with the two different UV wavelengths, that no water cluster sequences after n = 9 could be observed at 266 nm, whereas water clusters up to m/z 2000 Th in reflectron mode and m/z 3000 Th in linear mode were detected at 355 nm. The agreement between our findings on clusters of water, especially true in the range with n > 10, and reported data for liquid water supports the hypothesis that clusters above a critical dimension can approximate the liquid phase. It should thus be possible to study clusters just above 10 water molecules, for getting information on the bulk phase structure.

  4. LET measurements with a liquid ionization chamber

    Energy Technology Data Exchange (ETDEWEB)

    Tegami, Sara

    2013-02-08

    Deep-seated tumors can be efficiently treated with heavy charged particles. The characteristic depth dose profile inside the tissue (Bragg peak) allows to deliver a high dose inside the tumor, while sparing the neighboring healthy tissue. As compared to protons, heavy ions like carbon or oxygen produce a higher amount of ionization events along their track (and in particular at the end of the ion beam path), resulting in an irreparable damage to the DNA of the tumor cells. The density of such ionization events is described in terms of Linear Energy Transfer (LET), an important physical quantity, but difficult to be measured directly. The aim of this work is to determine LET of hadrontherapy beams by using Liquid Ionization Chambers (LIC). The ionization signal in LICs is affected by recombination effects that depend on the LET of the incident radiation. Differences in recombination effects in LICs and air-filled ionization chambers can be exploited to obtain the recombination index, which can be related to the LET, calculated by Monte Carlo methods. We thus developed a method to construct a calibration curve, which relates the recombination index with the LET at each depth in water. The result of this work can be used for online monitoring of the ion beam quality.

  5. The primordial abundance of deuterium: ionization correction

    Science.gov (United States)

    Cooke, Ryan; Pettini, Max

    2016-01-01

    We determine the relative ionization of deuterium and hydrogen in low metallicity damped Lyman α (DLA) and sub-DLA systems using a detailed suite of photoionization simulations. We model metal-poor DLAs as clouds of gas in pressure equilibrium with a host dark matter halo, exposed to the Haardt & Madau background radiation of galaxies and quasars at redshift z ≃ 3. Our results indicate that the deuterium ionization correction correlates with the H I column density and the ratio of successive ion stages of the most commonly observed metals. The N(N II)/N(N I) column density ratio provides the most reliable correction factor, being essentially independent of the gas geometry, H I column density, and the radiation field. We provide a series of convenient fitting formulae to calculate the deuterium ionization correction based on observable quantities. The ionization correction typically does not exceed 0.1 per cent for metal-poor DLAs, which is comfortably below the current measurement precision (2 per cent). However, the deuterium ionization correction may need to be applied when a larger sample of D/H measurements becomes available.

  6. Multiphoton ionization of large water clusters

    International Nuclear Information System (INIS)

    Water clusters are multimers of water molecules held together by hydrogen bonds. In the present work, multiphoton ionization in the UV range coupled with time of flight mass spectrometry has been applied to water clusters with up to 160 molecules in order to obtain information on the electronic states of clusters of different sizes up to dimensions that can approximate the bulk phase. The dependence of ion intensities of water clusters and their metastable fragments produced by laser ionization at 355 nm on laser power density indicates a (3+1)-photon resonance-enhanced multiphoton ionization process. It also explains the large increase of ionization efficiency at 355 nm compared to that at 266 nm. Indeed, it was found, by applying both nanosecond and picosecond laser ionization with the two different UV wavelengths, that no water cluster sequences after n = 9 could be observed at 266 nm, whereas water clusters up to m/z 2000 Th in reflectron mode and m/z 3000 Th in linear mode were detected at 355 nm. The agreement between our findings on clusters of water, especially true in the range with n > 10, and reported data for liquid water supports the hypothesis that clusters above a critical dimension can approximate the liquid phase. It should thus be possible to study clusters just above 10 water molecules, for getting information on the bulk phase structure

  7. Generation of slow muon beam by laser resonant ionization of muonium atoms

    International Nuclear Information System (INIS)

    We report first results of re-acceleration of thermal muons, which were generated by laser resonant ionization of muonium atoms. The re-accelerated beam (slow muon beam) has better energy resolution and space distribution compared to initial surface muon beam, and its use will extend the scope of muon spin relaxation technique from bulk material to thin film, multi-layers, surfaces and extremely small samples. The yield of slow muons obtained during the first beam time was 0.03 muons/s

  8. Convoy electron emission following ionization of highly-charged ions excited by resonant coherent excitation

    Science.gov (United States)

    Suda, S.; Nakano, Y.; Metoki, K.; Shindo, T.; Ohtsuki, S.; Azuma, T.; Hatakeyama, A.; Komaki, K.; Nakai, Y.; Takada, E.; Murakami, T.

    2012-11-01

    Projectile ionization of highly-charged Ar and Fe ions in the excited states passing relativistically fast through a thin crystalline foil was experimentally studied. We selectively controlled the population of the excited states of the projectiles, and their alignment by choosing a specific m-state through three-dimensional resonant coherent excitation technique by periodical electric fields in a crystalline. We measured energy-differential spectra of electron emission released from projectiles at zero degree. Under the resonance condition, we found an evident enhancement of the convoy electron yield, which reflects the electron momentum distribution of the initial bound state of the excited ions.

  9. Modeling and simulation of ionizing radiation effect on ferroelectric field-effect transistor

    Science.gov (United States)

    Yan, Shaoan; Li, Gang; Guo, Hongxia; Zhao, Wen; Xiong, Ying; Tang, Minghua; Li, Zheng; Xiao, Yongguang; Zhang, Wanli; Lei, Zhifeng

    2016-04-01

    A theoretical model is developed to investigate the ionizing radiation effect on electrical characteristics of a metal-ferroelectric-insulator-semiconductor structure ferroelectric gate field-effect transistor (MFIS FeFET). Modeling results show that gate capacitance versus gate voltage curves and transfer characteristic curves shift significantly and the memory window becomes worse with the total dose. Moreover, the drain current and I ON/I OFF ratio exhibit a considerable decrease under high incident dose rates. Finally, it is found that radiation-induced degradations can be affected strongly by the insulator layer thickness, and that MFIS FeFETs with a thin insulator buffer layer show a high radiation tolerance.

  10. Laser induced avalanche ionization in gases or gas mixtures with resonantly enhanced multiphoton ionization or femtosecond laser pulse pre-ionization

    International Nuclear Information System (INIS)

    The paper discusses the requirements for avalanche ionization in gas or gas mixtures initiated by REMPI or femtosecond-laser pre-ionization. Numerical examples of dependencies on partial composition for Ar:Xe gas mixture with REMPI of argon and subsequent classic avalanche ionization of Xe are presented.

  11. Advanced nanoelectronics

    CERN Document Server

    Ismail, Razali

    2012-01-01

    While theories based on classical physics have been very successful in helping experimentalists design microelectronic devices, new approaches based on quantum mechanics are required to accurately model nanoscale transistors and to predict their characteristics even before they are fabricated. Advanced Nanoelectronics provides research information on advanced nanoelectronics concepts, with a focus on modeling and simulation. Featuring contributions by researchers actively engaged in nanoelectronics research, it develops and applies analytical formulations to investigate nanoscale devices. The

  12. Usage of Thin-Client/Server Architecture in Computer Aided Education

    Science.gov (United States)

    Cimen, Caghan; Kavurucu, Yusuf; Aydin, Halit

    2014-01-01

    With the advances of technology, thin-client/server architecture has become popular in multi-user/single network environments. Thin-client is a user terminal in which the user can login to a domain and run programs by connecting to a remote server. Recent developments in network and hardware technologies (cloud computing, virtualization, etc.)…

  13. Weak interaction studies using resonance ionization spectroscopy

    International Nuclear Information System (INIS)

    Important developments in laser sources for the vacuum ultraviolet (VUV) region of the spectrum are making it possible to carry out resonance ionization of some of the noble gases. It has already been shown that xenon can be ionized in a two-photon allowed excitation from the ground state. Recently a new method of generating radiation by four-wave mixing in mercury vapor enables excitation of xenon in a one-photon resonance process. With these new laser sources we expect to have effective ionization volumes of 10-3 to 10-2 cm3 for the cases of argon, krypton, and xenon. This has important consequences in weak interaction physics and environmental research

  14. Ionization of atoms by slow heavy particles

    CERN Document Server

    Roberts, B M; Gribakin, G F

    2016-01-01

    Atoms and molecules can become ionized during the scattering of a slow, heavy particle off a bound electron. Such an interaction involving leptophilic weakly interacting massive particles (WIMPs) is a promising possible explanation for the anomalous 9 sigma annual modulation in the DAMA dark matter direct detection experiment [R. Bernabei et al., Eur. Phys. J. C 73, 2648 (2013)]. We demonstrate the applicability of the Born approximation for such an interaction by showing its equivalence to the semiclassical adiabatic treatment of atomic ionization by slow-moving WIMPs. Conventional wisdom has it that the ionization probability for such a process should be exponentially small. We show, however, that due to nonanalytic, cusp-like behaviour of Coulomb functions close to the nucleus this suppression is removed, leading to an effective atomic structure enhancement. We also show that electron relativistic effects actually give the dominant contribution to such a process, meaning that nonrelativistic calculations m...

  15. Nucleation in an ultra low ionization environment

    DEFF Research Database (Denmark)

    Pedersen, Jens Olaf Pepke; Enghoff, Martin Andreas Bødker; Paling, Sean;

    Atmospheric ions can enhance the nucleation of aerosols, as has been established by experiments, observation, and theory. In the clean marine atmosphere ionization is mainly caused by cosmic rays which in turn are controlled by the activity of the Sun, thus providing a potential link between solar...... Laboratory, located 1100 meters below ground, thus reducing the flux of ionizing cosmic radiation by six orders of magnitude. Similarly we have reduced the gamma background by shielding the experiment in lead and copper. Finally we have used air stored for several weeks and passed through an active charcoal...... filter in order to reduce the Radon concentration. In this way we have been able to make nucleation experiments with very low ionizing background, meaning that we can rule out ion induced nucleation as a contributing mechanism. Our experimental setup is a 50 L electropolished stainless steel reactor...

  16. Ionization of atoms by chirped attosecond pulses

    Institute of Scientific and Technical Information of China (English)

    Tan Fang; Peng Liang-You; Gong Qi-Huang

    2009-01-01

    We investigate the ionization dynamics of atoms by chirped attosecond pulses using the strong field approximation method. The pulse parameters are carefully chosen in the regime where the strong field approximation method is valid. We analyse the effects of the chirp of attosecond pulses on the energy distributions and the corresponding left-right asymmetry of the ionized electrons. For a single chirped attosecond pulse, the ionized electrons can be redistributed and the left-right asymmetry shows oscillations because of the introduction of the chirp. For time-delayed double attosecond pulses at different intensities with the weaker one chirped, exchanging the order of the two pulses shows a relative shift of the energy spectra, which can be explained by the different effective time delays of different frequency components because of the chirp.

  17. Code of practice for ionizing radiation

    International Nuclear Information System (INIS)

    Prior to 1984, the use of ionizing radiation in Malaysia was governed by the Radioactive Substances Act of 1968. After 1984, its use came under the control of Act 304, called the Atomic Energy Licensing Act 1984. Under powers vested by the Act, the Radiation Protection (Basic Safety Standards) Regulations 1988 were formulated to regulate its use. These Acts do not provide information on proper working procedures. With the publication of the codes of Practice by The Standards and Industrial Research Institute of Malaysia (SIRIM), the users are now able to follow proper guidelines and use ionizing radiation safely and beneficially. This paper discusses the relevant sections in the following codes: 1. Code of Practice for Radiation Protection (Medical X-ray Diagnosis) MS 838:1983. 2. Code of Practice for Safety in Laboratories Part 4: Ionizing radiation MS 1042: Part 4: 1992. (author)

  18. Ionization-chamber smoke detector system

    Science.gov (United States)

    Roe, Robert F.

    1976-10-19

    This invention relates to an improved smoke-detection system of the ionization-chamber type. In the preferred embodiment, the system utilizes a conventional detector head comprising a measuring ionization chamber, a reference ionization chamber, and a normally non-conductive gas triode for discharging when a threshold concentration of airborne particulates is present in the measuring chamber. The improved system is designed to reduce false alarms caused by fluctuations in ambient temperature. Means are provided for periodically firing the gas discharge triode and each time recording the triggering voltage required. A computer compares each triggering voltage with its predecessor. The computer is programmed to energize an alarm if the difference between the two compared voltages is a relatively large value indicative of particulates in the measuring chamber and to disregard smaller differences typically resulting from changes in ambient temperature.

  19. Multiphoton ionization/dissociation of osmium tetroxide

    International Nuclear Information System (INIS)

    The mechanisms leading to laser multiphoton ionization and dissociation (MPI/MPD) of osmium tetroxide (OsO4) have been investigated from measurements of the kinetic energies of product ions (Os+, Os2+, OsO+, O2+, O+) and photoelectrons as a function of the laser wavelength. Neutral channels, intermediate to the dominant Os+ ionization channel, such as OsO4→OsO4-n+nO are examined using resonance-enhanced multiphoton ionization (REMPI) of the fast O atoms. Equipartition of the available photon energy among the fragments is observed. The wavelength dependence of the Os+ ion signal suggests that one or more of the steps leading to Os+ ions involve molecular ions and/or excited neutral atoms. The observed preponderance of very slow (2+ is shown to result primarily from REMPI of Os+

  20. Capillary electrophoresis electrospray ionization mass spectrometry interface

    Science.gov (United States)

    Smith, Richard D.; Severs, Joanne C.

    1999-01-01

    The present invention is an interface between a capillary electrophoresis separation capillary end and an electrospray ionization mass spectrometry emitter capillary end, for transporting an anolyte sample from a capillary electrophoresis separation capillary to a electrospray ionization mass spectrometry emitter capillary. The interface of the present invention has: (a) a charge transfer fitting enclosing both of the capillary electrophoresis capillary end and the electrospray ionization mass spectrometry emitter capillary end; (b) a reservoir containing an electrolyte surrounding the charge transfer fitting; and (c) an electrode immersed into the electrolyte, the electrode closing a capillary electrophoresis circuit and providing charge transfer across the charge transfer fitting while avoiding substantial bulk fluid transfer across the charge transfer fitting. Advantages of the present invention have been demonstrated as effective in providing high sensitivity and efficient analyses.

  1. Ionizing radiation in the food industry

    International Nuclear Information System (INIS)

    The present state of application of ionizing radiation to food irradiation is surveyed. The nature of ionizing radiation, interactions of radiation with matter, dosimetric procedures, and types of radiation sources are outlined. Ionizing radiation is used for sprout inhibition, sterilization, for killing insects, parasites, moulds and fungi, and for enzyme activity inhibition. Sprouting can be stimulated by using low radiation doses. The chemical and biological changes occurring in irradiated foods are discussed. The irradiation of 49 kinds of food is permitted in 36 countries, and is applied on a commercial basis in 20 countries. Examples of large irradiating facilities over the world are given. Attention is also paid to the legislative basis of this approach. (M.D.). 2 tabs., 17 refs

  2. Electron impact double ionization of Mg+ ions

    International Nuclear Information System (INIS)

    Electron impact ionization of atoms/ions is one of the fundamental atomic collision processes. Absolute cross sections for electron impact single and multiple ionization are of considerable importance in many fields like astrophysics and controlled nuclear fusion. Theoretical studies of electron impact double ionisation cross sections of Mg+ ions have been performed in the binary encounter approximation (BEA). Direct double ionisation has been investigated in the modified double binary encounter model. Ionization cross sections of different shells have been also calculated in order to analyse the contributions to double ionisation from ionisation-autoionization. The effect of the Coulombic field of the target ion on the incident electron has been considered in the present work. Accurate expression of σΔE (cross-section for energy transfer ΔE) and Hartree-Fock velocity distributions for the target electrons have been used throughout the calculations. The theoretical results show satisfactory agreement with the experimental observations. (authors)

  3. Thin film photovoltaics

    Energy Technology Data Exchange (ETDEWEB)

    Zweibel, K; Ullal, H S

    1989-05-01

    Thin films are considered a potentially attractive technological approach to making cost-effective electricity by photovoltaics. Over the last twenty years, many have been investigated and some (cadmium telluride, copper indium diselenide, amorphous silicon) have become leading candidates for future large-scale commercialization. This paper surveys the past development of these key thin films and gives their status and future prospects. In all cases, significant progress toward cost-effective PV electricity has been made. If this progress continues, it appears that thin film PV could provide electricity that is competitive for summer daytime peaking power requirements by the middle of the 1990s; and electricity in a range that is competitive with fossil fuel costs (i.e., 6 cents/kilowatt-hour) should be available from PV around the turn of the century. 22 refs., 9 figs.

  4. Thin film temperature sensor

    Science.gov (United States)

    Grant, H. P.; Przybyszewski, J. S.

    1980-01-01

    Thin film surface temperature sensors were developed. The sensors were made of platinum-platinum/10 percent rhodium thermocouples with associated thin film-to-lead wire connections and sputtered on aluminum oxide coated simulated turbine blades for testing. Tests included exposure to vibration, low velocity hydrocarbon hot gas flow to 1250 K, and furnace calibrations. Thermal electromotive force was typically two percent below standard type S thermocouples. Mean time to failure was 42 hours at a hot gas flow temperature of 1250 K and an average of 15 cycles to room temperature. Failures were mainly due to separation of the platinum thin film from the aluminum oxide surface. Several techniques to improve the adhesion of the platinum are discussed.

  5. AdvancED Flex 4

    CERN Document Server

    Tiwari, Shashank; Schulze, Charlie

    2010-01-01

    AdvancED Flex 4 makes advanced Flex 4 concepts and techniques easy. Ajax, RIA, Web 2.0, mashups, mobile applications, the most sophisticated web tools, and the coolest interactive web applications are all covered with practical, visually oriented recipes. * Completely updated for the new tools in Flex 4* Demonstrates how to use Flex 4 to create robust and scalable enterprise-grade Rich Internet Applications.* Teaches you to build high-performance web applications with interactivity that really engages your users.* What you'll learn Practiced beginners and intermediate users of Flex, especially

  6. Fabrication of MEMS Resonators in Thin SOI

    CERN Document Server

    Grogg, D; Ionescu, Adrian Mihai

    2008-01-01

    A simple and fast process for micro-electromechanical (MEM) resonators with deep sub-micron transduction gaps in thin SOI is presented in this paper. Thin SOI wafers are important for advanced CMOS technology and thus are evaluated as resonator substrates for future co-integration with CMOS circuitry on a single chip. As the transduction capacitance scales with the resonator thickness, it is important to fabricate deep sub-micron trenches in order to achieve a good capacitive coupling. Through the combination of conventional UV-lithography and focused ion beam (FIB) milling the process needs only two lithography steps, enabling therefore a way for fast prototyping of MEM-resonators. Different FIB parameters and etching parameters are compared in this paper and their effect on the process are reported.

  7. Ionization in strong electric fields and dynamics of nanosecond-pulse plasmas

    International Nuclear Information System (INIS)

    The paper describes experimental and computational studies of weakly ionized air plasmas sustained by high repetition rate high-voltage nanosecond pulses. The experimentally determined energy cost per newly produced electron in these diffuse volumetric plasmas is on the order of 100 eV, two orders of magnitude lower than in diffuse quasineutral dc and rf plasmas, and close to that in the cathode sheaths of glow discharges. Modeling of plasma dynamics in high-voltage nanosecond pulses yielded the energy cost of ionization in good agreement with the experimental values. Both experiments and modeling revealed that the ionization cost per electron in these plasmas is relatively insensitive to the gas density. Detailed investigations of the plasma dynamics revealed a critical role of the thin cathode sheath that was found to take up most of the peak voltage applied to the electrodes. The extremely high values of the ratio of electric field strength to the gas number density (E/N), much higher than the Stoletov's field at the Paschen minimum point, result in a very high ionization cost in the sheath. In contrast, the value of E/N in the quasineutral plasma is closer to that associated with the Stoletov's point, resulting in a near-optimal electron generation. This behavior (the reversal of ionization efficiencies in the sheath and in the plasma) is opposite to that in conventional glow discharges. The positive space charge in the sheath and its relatively slow relaxation due to the low ion mobility was also found to result in reversal of electric field direction in the plasma at the tail of the high-voltage pulse

  8. Advanced Magnetoimpedance Sensors

    KAUST Repository

    Li, Bodong

    2015-02-01

    This thesis is concerned with the advanced topics of thin film magnetoimpedance (MI) sensors. The author proposes and develops novel MI sensors that target on the challenges arising from emerging applications such as flexible electronics, passive wireless sensing, etc. In the study of flexible MI sensor, the investigated sensors of NiFe/Cu/NiFe tri-layersare fabricated on three flexible substrates having different surface roughness: Kapton, standard and premiumphotopaper. Sensitivity versus substrate roughness analysis is carried out for the selection of optimal substrate material. The high magnetic sensing performance is achieved by using Kapton substrate. Stress simulation, incorporated with the theory of magnetostriction effect, reveals the material composition of Ni/Fe being as a key factor of the stress dependent MI effect for the flexible MI sensors. In the development of MI-SAW device for passive wireless magnetic field sensing, NiFe/Cu/NiFe tri-layersand interdigital transducers(IDT) are designed and fabricated on a single piece of LiNbO3substrate, providing a high degree of integration and the advantage of standard microfabrication. The double-electrodeIDT has been utilized and proven to have an optimal sensing performance in comparison to the bi-directional IDT design. The optimized high frequency performance of the thin film MI sensor results in a MI-SAW passive wireless magnetic sensor with high magnetic sensitivity comparing to the MI microwire approach. Benefiting from the high degree of integration of the MI thin film element, in the following study, two additional sensing elements are integrated to the SAW device to have a multifunctional passive wireless sensor with extended temperature and humidity sensing capabilities. Analytical models havebeen developed to eliminate the crossovers of different sensing signals through additional reference IDTs, resulting in a multifunctional passive wireless sensor with the capability of detecting all three

  9. Thin film ceramic thermocouples

    Science.gov (United States)

    Gregory, Otto (Inventor); Fralick, Gustave (Inventor); Wrbanek, John (Inventor); You, Tao (Inventor)

    2011-01-01

    A thin film ceramic thermocouple (10) having two ceramic thermocouple (12, 14) that are in contact with each other in at least on point to form a junction, and wherein each element was prepared in a different oxygen/nitrogen/argon plasma. Since each element is prepared under different plasma conditions, they have different electrical conductivity and different charge carrier concentration. The thin film thermocouple (10) can be transparent. A versatile ceramic sensor system having an RTD heat flux sensor can be combined with a thermocouple and a strain sensor to yield a multifunctional ceramic sensor array. The transparent ceramic temperature sensor that could ultimately be used for calibration of optical sensors.

  10. Electron-Impact Ionization Cross Section Database

    Science.gov (United States)

    SRD 107 Electron-Impact Ionization Cross Section Database (Web, free access)   This is a database primarily of total ionization cross sections of molecules by electron impact. The database also includes cross sections for a small number of atoms and energy distributions of ejected electrons for H, He, and H2. The cross sections were calculated using the Binary-Encounter-Bethe (BEB) model, which combines the Mott cross section with the high-incident energy behavior of the Bethe cross section. Selected experimental data are included.

  11. Multiphoton core ionization dynamics of polyatomic molecules

    International Nuclear Information System (INIS)

    The two-photon core ionization dynamics of gas-phase methane, carbon monoxide and nitrogen have been studied with a recent implementation of the lowest order perturbation theory in the framework of density functional theory and a multicentric basis set expansion of bound and scattering states. Ionization cross sections and angular asymmetry parameters have been calculated for the case of a single radiation beam and for both linear and circular light polarizations in the fixed nuclei approximation. Expected resonances due to core valence excitations enhance the cross section by several orders of magnitude. (paper)

  12. Generalized Bessel functions in tunnelling ionization

    CERN Document Server

    Reiss, H R

    2003-01-01

    We develop two new approximations for the generalized Bessel function that frequently arises in the analytical treatment of strong-field processes, especially in non-perturbative multiphoton ionization theories. Both these new forms are applicable to the tunnelling environment in atomic ionization, and are analytically much simpler than the currently used low-frequency asymptotic approximation for the generalized Bessel function. The second of the new forms is an approximation to the first, and it is the second new form that exhibits the well-known tunnelling exponential.

  13. Resonance ionization mass spectroscopy of uranium

    International Nuclear Information System (INIS)

    Resonance ionization mass spectroscopy (RIMS) has been used for the sensitive detection of uranium. The apparatus consists of a laser system with three dye lasers and two pulsed copper vapour lasers and a time-of-flight (TOF) mass spectrometer. The uranium atoms are ionized in a three step excitation with the third step leading to an autoionizing state. Several excitation schemes were investigated and for two schemes all three transitions could be saturated with the available laser power. The hyperfine structure splitting (HFS) of 235U, the isotopic shift (IS) between 235U and 238U as well as isotopic ratios in uranium samples were determined. (Author)

  14. Ionizing radiation effects in MOS oxides

    CERN Document Server

    Oldham, Timothy R

    1999-01-01

    This volume is intended to serve as an updated critical guide to the extensive literature on the basic physical mechanisms controlling the radiation and reliability responses of MOS oxides. The last such guide was Ionizing Radiation Effects in MOS Devices and Circuits, edited by Ma and Dressendorfer and published in 1989. While that book remains an authoritative reference in many areas, there has been a significant amount of more recent work on the nature of the electrically active defects in MOS oxides which are generated by exposure to ionizing radiation. These same defects are also critical

  15. A prototype ionization profile monitor for RHIC

    Energy Technology Data Exchange (ETDEWEB)

    Connolly, R.; Cameron, P.; Ryan, W. [and others

    1997-07-01

    Transverse beam profiles in the Relativistic Heavy-Ion Collider (RHIC) will be measured with ionization profile monitors (IPM`s). Each IPM collects and measures the distribution of electrons in the beamline resulting from residual gas ionization during bunch passage. The electrons are swept transversely from the beamline and collected on strip anodes oriented parallel to the beam axis. At each bunch passage the charge pulses are amplified, integrated, and digitized for display as a profile histogram. A prototype detector was tested in the injection line during the RHIC Sextant Test. This paper describes the detector and gives results from the beam tests.

  16. Experimental and theoretical triple-differential cross sections for tetrahydrofuran ionized by low-energy 26-eV-electron impact

    Science.gov (United States)

    Ali, Esam; Ren, XueGuang; Dorn, Alexander; Ning, Chuangang; Colgan, James; Madison, Don

    2016-06-01

    We report an experimental and theoretical study of low-energy electron-impact ionization of tetrahydrofuran, which is a molecule of biological interest. The experiments were performed using an advanced reaction microscope specially built for electron-impact ionization studies. The theoretical calculations were performed within the molecular three-body distorted-wave model. Reasonably good agreement is found between experiment and theory.

  17. Deconstructing Desorption Electrospray Ionization: Independent Optimization of Desorption and Ionization by Spray Desorption Collection

    Science.gov (United States)

    Douglass, Kevin A.; Jain, Shashank; Brandt, William R.; Venter, Andre R.

    2012-11-01

    Spray desorption collection (SDC) and reflective electrospray ionization (RESI) were used to independently study the desorption and ionization processes that together comprise desorption electrospray ionization (DESI). Both processes depend on several instrumental parameters, including the nebulizing gas flow rate, applied potential, and source geometries. Each of these parameters was optimized for desorption, as represented by the results obtained by SDC, and ionization, as represented by the results obtained by RESI. The optimized conditions were then compared to the optimization results for DESI. Our results confirm that optimal conditions for desorption and ionization are different and that in some cases the optimized DESI conditions are a compromise between both sets. The respective results for DESI, RESI, and SDC for each parameter were compared across the methods to draw conclusions about the contribution of each parameter to desorption and ionization separately and then combined within DESI. Our results indicate that desorption efficiency is (1) independent of the applied potential and (2) the impact zone to inlet distance, and that (3) gas pressure settings and (4) sprayer to impact zone distances above optimal for DESI are detrimental to desorption but beneficial for ionization. In addition, possible interpretations for the observed trends are presented.

  18. Matrix Assisted Ionization in Vacuum, a Sensitive and Widely Applicable Ionization Method for Mass Spectrometry

    Science.gov (United States)

    Trimpin, Sarah; Inutan, Ellen D.

    2013-05-01

    An astonishingly simple new method to produce gas-phase ions of small molecules as well as proteins from the solid state under cold vacuum conditions is described. This matrix assisted ionization vacuum (MAIV) mass spectrometry (MS) method produces multiply charged ions similar to those that typify electrospray ionization (ESI) and uses sample preparation methods that are nearly identical to matrix-assisted laser desorption/ionization (MALDI). Unlike these established methods, MAIV does not require a laser or voltage for ionization, and unlike the recently introduced matrix assisted ionization inlet method, does not require added heat. MAIV-MS requires only introduction of a crystalline mixture of the analyte incorporated with a suitable small molecule matrix compound such as 3-nitrobenzonitrile directly to the vacuum of the mass spectrometer. Vacuum intermediate pressure MALDI sources and modified ESI sources successfully produce ions for analysis by MS with this method. As in ESI-MS, ion formation is continuous and, without a laser, little chemical background is observed. MAIV, operating from a surface offers the possibility of significantly improved sensitivity relative to atmospheric pressure ionization because ions are produced in the vacuum region of the mass spectrometer eliminating losses associated with ion transfer from atmospheric pressure to vacuum. Mechanistic aspects and potential applications for this new ionization method are discussed.

  19. Electron cyclotron resonance microwave ion sources for thin film processing

    International Nuclear Information System (INIS)

    Plasmas created by microwave absorption at the electron cyclotron resonance (ECR) are increasingly used for a variety of plasma processes, including both etching and deposition. ECR sources efficiently couple energy to electrons and use magnetic confinement to maximize the probability of an electron creating an ion or free radical in pressure regimes where the mean free path for ionization is comparable to the ECR source dimensions. The general operating principles of ECR sources are discussed with special emphasis on their use for thin film etching. Data on source performance during Cl base etching of Si using an ECR system are presented. 32 refs., 5 figs

  20. Breakdown voltage in thin III-V avalanche photodiodes

    Science.gov (United States)

    Saleh, Mohammad A.; Hayat, Majeed M.; Kwon, Oh-Hyun; Holmes, Archie L.; Campbell, Joe C.; Saleh, Bahaa E. A.; Teich, Malvin C.

    2001-12-01

    The dead-space multiplication theory of Hayat and Saleh [J. Lightwave Technol. 10, 1415 (1992)], in conjunction with the multiplication-width-independent ionization-coefficient model developed by Saleh et al. [IEEE Trans. Electron Devices 47, 625 (2000)], are shown to accurately predict breakdown voltages for thin avalanche photodiodes of GaAs, InP, In0.52Al0.48As, and Al0.2Ga0.8As, over a broad range of device widths. The breakdown voltage is determined from the analytical expression for the impulse-response-function decay rate.

  1. Secondary ionization process in laser induced breakdown of molecular gases

    International Nuclear Information System (INIS)

    We studied the separate effect of photo-ionization and collisional ionization of the molecular electronic excited states on the ionization growth rate of nitrogen irradiated with 10 ns pulse of Nd-YAG laser radiation at pressures 7.6x102, 1.79x103 and 5.34x103 Torr. It was found that photo-ionization processes play an important role in enhancing the ionization growth rate at pressures of 7.6x102 Torr. At higher pressures, where there is excess of electron density and hence excited molecule density, collisional ionization processes are dominant. (author). 6 refs, 3 figs

  2. Circular dichroism in XUV + IR multiphoton ionization of atoms

    International Nuclear Information System (INIS)

    Circular dichroism (CD) is theoretically considered for two-colour multiphoton ionization of arbitrary atomic subshells. In particular, p-subshell ionization is analysed and compared with s-subshell ionization. Simple analytical expressions for the CD are obtained for both s- and p-subshell ionization. The calculations performed for Ne(2p) ionization by an extreme ultraviolet pulse in the presence of an infrared laser pulse show that the CD in this case is appreciably larger than in previously discussed s-shell ionization. It makes this case favourable for applications as a sensitive tool for measuring the helicity of short-wavelength free-electron laser beams. (paper)

  3. Resonance ionization laser ion sources for on-line isotope separators (invited).

    Science.gov (United States)

    Marsh, B A

    2014-02-01

    A Resonance Ionization Laser Ion Source (RILIS) is today considered an essential component of the majority of Isotope Separator On Line (ISOL) facilities; there are seven laser ion sources currently operational at ISOL facilities worldwide and several more are under development. The ionization mechanism is a highly element selective multi-step resonance photo-absorption process that requires a specifically tailored laser configuration for each chemical element. For some isotopes, isomer selective ionization may even be achieved by exploiting the differences in hyperfine structures of an atomic transition for different nuclear spin states. For many radioactive ion beam experiments, laser resonance ionization is the only means of achieving an acceptable level of beam purity without compromising isotope yield. Furthermore, by performing element selection at the location of the ion source, the propagation of unwanted radioactivity downstream of the target assembly is reduced. Whilst advances in laser technology have improved the performance and reliability of laser ion sources and broadened the range of suitable commercially available laser systems, many recent developments have focused rather on the laser/atom interaction region in the quest for increased selectivity and/or improved spectral resolution. Much of the progress in this area has been achieved by decoupling the laser ionization from competing ionization processes through the use of a laser/atom interaction region that is physically separated from the target chamber. A new application of gas catcher laser ion source technology promises to expand the capabilities of projectile fragmentation facilities through the conversion of otherwise discarded reaction fragments into high-purity low-energy ion beams. A summary of recent RILIS developments and the current status of laser ion sources worldwide is presented.

  4. Resonance ionization laser ion sources for on-line isotope separators (invited)

    International Nuclear Information System (INIS)

    A Resonance Ionization Laser Ion Source (RILIS) is today considered an essential component of the majority of Isotope Separator On Line (ISOL) facilities; there are seven laser ion sources currently operational at ISOL facilities worldwide and several more are under development. The ionization mechanism is a highly element selective multi-step resonance photo-absorption process that requires a specifically tailored laser configuration for each chemical element. For some isotopes, isomer selective ionization may even be achieved by exploiting the differences in hyperfine structures of an atomic transition for different nuclear spin states. For many radioactive ion beam experiments, laser resonance ionization is the only means of achieving an acceptable level of beam purity without compromising isotope yield. Furthermore, by performing element selection at the location of the ion source, the propagation of unwanted radioactivity downstream of the target assembly is reduced. Whilst advances in laser technology have improved the performance and reliability of laser ion sources and broadened the range of suitable commercially available laser systems, many recent developments have focused rather on the laser/atom interaction region in the quest for increased selectivity and/or improved spectral resolution. Much of the progress in this area has been achieved by decoupling the laser ionization from competing ionization processes through the use of a laser/atom interaction region that is physically separated from the target chamber. A new application of gas catcher laser ion source technology promises to expand the capabilities of projectile fragmentation facilities through the conversion of otherwise discarded reaction fragments into high-purity low-energy ion beams. A summary of recent RILIS developments and the current status of laser ion sources worldwide is presented

  5. Electrical characterization of advanced gate dielectrics

    NARCIS (Netherlands)

    Degraeve, R.; Schmitz, J.; Pantisano, L.; Simoen, E.; Houssa, M.; Kaczer, B.; Groeseneken, G.; Baklanov, M.; Green, M.; Maex, K.

    2007-01-01

    The topic of thin films is an area of increasing importance in materials science, electrical engineering and applied solid state physics; with both research and industrial applications in microelectronics, computer manufacturing, and physical devices. Advanced, high-performance computers, high-defin

  6. A broad-based study on hyphenating new ionization technologies with MS/MS for PTMs and tissue characterization.

    Science.gov (United States)

    Marshall, Darrell D; Inutan, Ellen D; Wang, Beixi; Liu, Chih-Wei; Thawoos, Shameemah; Wager-Miller, James; Mackie, Ken; Trimpin, Sarah

    2016-06-01

    Matrix-assisted ionization (MAI) is a newly discovered method for converting compounds from the solid phase to gas-phase ions having charge states similar to electrospray ionization (ESI), but without the need for high-energy sources such as lasers or high voltage. Laserspray ionization (LSI) is a subset of MAI that uses a laser to provide high spatial resolution analyses, but the laser is not directly involved in the ionization process. These methods produce multiply-charged analyte ions that are useful for characterizing compounds directly from surfaces using advanced characterization technologies. Because the multiply-charged ions originate from charged matrix clusters, efficient desolvation of the matrix is a prerequisite. Here, we report on the utility of collision-induced dissociation (CID) and electron transfer dissociation (ETD) coupled to mass spectrometry using several MAI and LSI matrices for peptide and protein characterization employing mass spectrometers from two manufacturers. The information obtained is similar to that using ESI for most analyses and superior to matrix-assisted laser desorption/ionization (MALDI) as is shown for intact proteins and protein digests directly from mouse brain tissue sections. The ionization processes are soft so that posttranslational modification (e.g. phosphorylation) sites are readily determined. Instances where ETD or CID in conjunction with MAI failed are attributed to lack of desolvation of charged matrix:analyte particles. PMID:27093917

  7. Thin Concrete Barrel Vault

    NARCIS (Netherlands)

    Kamerling, M.W.

    2013-01-01

    The paper presents the structural design of a thin barrel vault constructed with Fusée Ceramique infill elements. The load transfer is analyzed and validated. For the structure composed of Fusée Ceramique elements, steel and concrete the stresses are calculated and compared to the stresses given in

  8. Protein Thin Film Machines

    OpenAIRE

    Federici, Stefania; Oliviero, Giulio; Hamad-Schifferli, Kimberly; Bergese, Paolo

    2010-01-01

    We report the first example of microcantilever beams that are reversibly driven by protein thin film machines fuelled by cycling the salt concentration of the surrounding solution. We also show that upon the same salinity stimulus the drive can be completely reversed in its direction by introducing a surface coating ligand. Experimental results are throughout discussed within a general yet simple thermodynamic model.

  9. Plasma polymerised thin films for flexible electronic applications

    Energy Technology Data Exchange (ETDEWEB)

    Jacob, Mohan V., E-mail: mohan.jacob@jcu.edu.au [Electronic Materials Research Lab, School of Engineering and Physical Sciences, James Cook University, Townsville 4811 (Australia); Olsen, Natalie S.; Anderson, Liam J.; Bazaka, Kateryna [Electronic Materials Research Lab, School of Engineering and Physical Sciences, James Cook University, Townsville 4811 (Australia); Shanks, Robert A. [Applied Sciences, RMIT University, GPO Box 2476V, Melbourne 3001 (Australia)

    2013-11-01

    The significant advancement and growth of organic and flexible electronic applications demand materials with enhanced properties. This paper reports the fabrication of a nonsynthetic polymer thin film using radio frequency plasma polymerisation of 3,7-dimethyl-1,6-octadien-3-ol. The fabricated optically transparent thin film exhibited refractive index of approximately 1.55 at 500 nm and rate of deposition was estimated to be 40 nm/min. The surface morphology and chemical properties of the thin films were also reported in this paper. The optical band gap of the material is around 2.8 eV. The force of adhesion and Young's modulus of the linalool polymer thin films were measured using force-displacement curves obtained from a scanning probe microscope. The friction coefficient of linalool polymer thin films was measured using the nanoscratch test. The calculated Young's modulus increased linearly with increase in input power while the friction coefficient decreased. - Highlights: • Fabrication of a novel polymer thin film from non-synthetic source • The surface, optical and chemical properties are reported. • The fabricated thin film is transparent and smooth. • An environmentally friendly material • Candidate for flexible electronics as dielectric layer or as an encapsulation layer.

  10. Modern Thin-Layer Chromatography.

    Science.gov (United States)

    Poole, Colin F.; Poole, Salwa K.

    1989-01-01

    Some of the important modern developments of thin-layer chromatography are introduced. Discussed are the theory and instrumentation of thin-layer chromatography including multidimensional and multimodal techniques. Lists 53 references. (CW)

  11. Thin film metal-oxides

    CERN Document Server

    Ramanathan, Shriram

    2009-01-01

    Presents an account of the fundamental structure-property relations in oxide thin films. This title discusses the functional properties of thin film oxides in the context of applications in the electronics and renewable energy technologies.

  12. Thin films for material engineering

    Science.gov (United States)

    Wasa, Kiyotaka

    2016-07-01

    Thin films are defined as two-dimensional materials formed by condensing one by one atomic/molecular/ionic species of matter in contrast to bulk three-dimensional sintered ceramics. They are grown through atomic collisional chemical reaction on a substrate surface. Thin film growth processes are fascinating for developing innovative exotic materials. On the basis of my long research on sputtering deposition, this paper firstly describes the kinetic energy effect of sputtered adatoms on thin film growth and discusses on a possibility of room-temperature growth of cubic diamond crystallites and the perovskite thin films of binary compound PbTiO3. Secondly, high-performance sputtered ferroelectric thin films with extraordinary excellent crystallinity compatible with MBE deposited thin films are described in relation to a possible application for thin-film MEMS. Finally, the present thin-film technologies are discussed in terms of a future material science and engineering.

  13. Historical survey of resonance ionization spectroscopy

    International Nuclear Information System (INIS)

    We have recently celebrated the 10th birthday of Resonance Ionization Spectroscopy (RIS), and this seems an appropriate time to review the history of its development. Basically, RIS is a photophysics process in which tunable light sources are used to remove a valence electron from an atom of selected atomic number, Z. If appropriate lasers are used as the light source, one electron can be removed from each atom of the selected Z in the laser pulse. This implies that RIS can be a very efficient, as well as selective, ionization process. In what we normally call RIS, laser schemes are employed which preserve both of these features. In contrast, multiphoton ionization (MPI) is more general, although not necessarily Z selective or very efficient because resonances are often not used. Early research completed in the USSR and described as selective two-step photoionization, employed resonances to ionize the rubidium atom and served to guide work on laser isotope separation. 29 references, 8 figures

  14. Composite scintillators for detection of ionizing radiation

    Science.gov (United States)

    Dai, Sheng [Knoxville, TN; Stephan, Andrew Curtis [Knoxville, TN; Brown, Suree S [Knoxville, TN; Wallace, Steven A [Knoxville, TN; Rondinone, Adam J [Knoxville, TN

    2010-12-28

    Applicant's present invention is a composite scintillator having enhanced transparency for detecting ionizing radiation comprising a material having optical transparency wherein said material comprises nano-sized objects having a size in at least one dimension that is less than the wavelength of light emitted by the composite scintillator wherein the composite scintillator is designed to have selected properties suitable for a particular application.

  15. IKAR, a ionization chamber for WA9

    CERN Document Server

    1976-01-01

    This ionization chamber arrived at CERN from Leningrad for a high precision study of hadron elastic scattering by a CERN-Clermont-Ferrand-Leningrad-Lyon-Uppsala Collaboration in the H3 beam (WA9). G.A. Korolev (third from right) looks at the drawings.

  16. Ionization Energy: Implications of Preservice Teachers' Conceptions

    Science.gov (United States)

    Tan, Kim Chwee Daniel; Taber, Keith S.

    2009-01-01

    The results from a study to explore pre-service teachers' understanding of ionization energy, a topic that features in A-level (grade 11 and 12) chemistry courses. in Singapore , is described. A previous study using a two-tier multiple choice diagnostic test has shown that Singapore A-level students have considerable difficulty understanding the…

  17. Limits to Sensitivity in Laser Enhanced Ionization.

    Science.gov (United States)

    Travis, J. C.

    1982-01-01

    Laser enhanced ionization (LEI) occurs when a tunable dye laser is used to excite a specific atomic population in a flame. Explores the origin of LEI's high sensitivity and identifies possible avenues to higher sensitivity by describing instrument used and experimental procedures and discussing ion formation/detection. (Author/JN)

  18. The Primordial Abundance of Deuterium: Ionization correction

    CERN Document Server

    Cooke, Ryan

    2015-01-01

    We determine the relative ionization of deuterium and hydrogen in low metallicity damped Lyman-alpha (DLA) and sub-DLA systems using a detailed suite of photoionization simulations. We model metal-poor DLAs as clouds of gas in pressure equilibrium with a host dark matter halo, exposed to the Haardt & Madau (2012) background radiation of galaxies and quasars at redshift z~3. Our results indicate that the deuterium ionization correction correlates with the H I column density and the ratio of successive ion stages of the most commonly observed metals. The N(N II) / N(N I) column density ratio provides the most reliable correction factor, being essentially independent of the gas geometry, H I column density, and the radiation field. We provide a series of convenient fitting formulae to calculate the deuterium ionization correction based on observable quantities. The ionization correction typically does not exceed 0.1 per cent for metal-poor DLAs, which is comfortably below the current measurement precision (2...

  19. Route to Direct Multiphoton Multiple Ionization

    CERN Document Server

    Lambropoulos, P; Papamihail, K G

    2011-01-01

    We address the concept of direct multiphoton multiple ionization in atoms exposed to intense, short wavelength radiation and explore the conditions under which such processes dominate over the sequential. Their contribution is shown to be quite robust, even under intensity fluctuations and interaction volume integration, and reasonable agreement with experimental data is also found.

  20. Route to direct multiphoton multiple ionization

    International Nuclear Information System (INIS)

    We address the concept of direct multiphoton multiple ionization in atoms exposed to intense, short-wavelength radiation and explore the conditions under which such processes dominate over the sequential. Their contribution is shown to be quite robust, even under intensity fluctuations and interaction volume integration, and reasonable agreement with experimental data is also found.

  1. Chemical protection against ionizing radiation. Final report

    International Nuclear Information System (INIS)

    The scientific literature on radiation-protective drugs is reviewed. Emphasis is placed on the mechanisms involved in determining the sensitivity of biological material to ionizing radiation and mechanisms of chemical radioprotection. In Section I, the types of radiation are described and the effects of ionizing radiation on biological systems are reviewed. The effects of ionizing radiation are briefly contrasted with the effects of non-ionizing radiation. Section II reviews the contributions of various natural factors which influence the inherent radiosensitivity of biological systems. Inlcuded in the list of these factors are water, oxygen, thiols, vitamins and antioxidants. Brief attention is given to the model describing competition between oxygen and natural radioprotective substances (principally, thiols) in determining the net cellular radiosensitivity. Several theories of the mechanism(s) of action of radioprotective drugs are described in Section III. These mechanisms include the production of hypoxia, detoxication of radiochemical reactive species, stabilization of the radiobiological target and the enhancement of damage repair processes. Section IV describes the current strategies for the treatment of radiation injury. Likely areas in which fruitful research might be performed are described in Section V. 495 references

  2. Ionization smoke detector with controlled sensitivity

    International Nuclear Information System (INIS)

    An ionization smoke detector has been developed which has housing and sensing chambers together controlling the flow of detected smoke or aerosols containing particulate matter. This control of the air flow through the sensing chamber maintains the sensitivity to smoke even in the presence of winds or drafts. (DN)

  3. Fluctuation charge effects in ionization fronts

    Energy Technology Data Exchange (ETDEWEB)

    Arrayas, Manuel; Trueba, Jose L [Area de Electromagnetismo, Universidad Rey Juan Carlos, Camino del Molino s/n, 28943 Fuenlabrada, Madrid (Spain); Baltanas, J P [Departamento de Fisica Aplicada II, Universidad de Sevilla, Av. Reina Mercedes 2, 41012 Sevilla (Spain)

    2008-05-21

    In this paper, we study the effects of charge fluctuations on the propagation of both negative and positive ionization fronts in streamer discharges. We show that fronts accelerate when random charge creation events are present. This effect might play a similar role to photoionization in order to make the front move faster.

  4. Properties of Excitons Bound to Ionized Donors

    DEFF Research Database (Denmark)

    Skettrup, Torben; Suffczynski, M.; Gorzkowski, W.

    1971-01-01

    Binding energies, interparticle distances, oscillator strengths, and exchange corrections are calculated for the three-particle complex corresponding to an exciton bound to an ionized donor. The results are given as functions of the mass ratio of the electron and hole. Binding of the complex is o...

  5. Roles of ionizing radiation in cell transformation

    Energy Technology Data Exchange (ETDEWEB)

    Tobias, C.A.; Albright, N.W.; Yang, T.C.

    1983-07-01

    Earlier the authors described a repair misrepair model (RMR-I) which is applicable for radiations of low LET, e.g., x rays and gamma rays. RMR-II was described later. Here is introduced a mathematical modification of the RMR model, RMR-III, which is intended to describe lethal effects caused by heavily ionizing tracks. 31 references, 4 figures.

  6. Historical survey of resonance ionization spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Hurst, G.S.

    1984-04-01

    We have recently celebrated the 10th birthday of Resonance Ionization Spectroscopy (RIS), and this seems an appropriate time to review the history of its development. Basically, RIS is a photophysics process in which tunable light sources are used to remove a valence electron from an atom of selected atomic number, Z. If appropriate lasers are used as the light source, one electron can be removed from each atom of the selected Z in the laser pulse. This implies that RIS can be a very efficient, as well as selective, ionization process. In what we normally call RIS, laser schemes are employed which preserve both of these features. In contrast, multiphoton ionization (MPI) is more general, although not necessarily Z selective or very efficient because resonances are often not used. Early research completed in the USSR and described as selective two-step photoionization, employed resonances to ionize the rubidium atom and served to guide work on laser isotope separation. 29 references, 8 figures.

  7. Liquid ionization chambers for LET determination

    DEFF Research Database (Denmark)

    Kaiser, Franz-Joachim; Bassler, Niels; Tölli, Heikki;

    Liquid ionization chambers [1] (LICs) have have been used in the last decades as background dosemeters. Since a few years LICs are also commercially available for dosimetry and are used for measurements of dose distributions where a high spatial distribution is necessary. Also in the last decades...

  8. Antiproton-impact ionization of H2

    International Nuclear Information System (INIS)

    Ionization processes in antiproton collisions with H2 are studied by direct solution of the time-dependent Schroedinger equation. A time-dependent close-coupling method based on an expansion of a one-electron 3D wavefunction in the field of H+2 is used to calculate single-ionization cross sections at incident energies ranging from 50 keV to 1.5 MeV. Averaging over the molecular orientations, the single-ionization cross sections are in reasonable agreement with time-dependent basis set calculations and experiment. A time-dependent close-coupling method based on an expansion of a two-electron 6D wavefunction in the field of H2+2 is used to calculate single- and double-ionization cross sections at an incident energy of 100 keV. Initiatory 6D results for the H+2 production cross section range are somewhat lower than experiment, while the H+ production cross section range brackets experiment.

  9. Long-term effects of ionizing radiation

    International Nuclear Information System (INIS)

    This paper approaches the long-term effects of ionizing radiation considering the common thought that killing of cells is the basis for deterministic effects and that the subtle changes in genetic information are important in the development of radiation-induced cancer, or genetic effects if these changes are induced in germ cells

  10. Positronium impact ionization of Alkali atoms

    CERN Document Server

    Ghosh, D

    2015-01-01

    Target ionization processes of alkali atoms by Positronium impact are investigated. Calculations are performed in the frame work of model potential formalism using the Coulomb distorted eikonal approximation. Interesting qualitative features are noted both in the scattered Ps and the ejected electron distributions in differential as well as double differential levels of the collision cross sections.

  11. Roles of ionizing radiation in cell transformation

    International Nuclear Information System (INIS)

    Earlier the authors described a repair misrepair model (RMR-I) which is applicable for radiations of low LET, e.g., x rays and gamma rays. RMR-II was described later. Here is introduced a mathematical modification of the RMR model, RMR-III, which is intended to describe lethal effects caused by heavily ionizing tracks. 31 references, 4 figures

  12. Chemical protection against ionizing radiation. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Livesey, J.C.; Reed, D.J.; Adamson, L.F.

    1984-08-01

    The scientific literature on radiation-protective drugs is reviewed. Emphasis is placed on the mechanisms involved in determining the sensitivity of biological material to ionizing radiation and mechanisms of chemical radioprotection. In Section I, the types of radiation are described and the effects of ionizing radiation on biological systems are reviewed. The effects of ionizing radiation are briefly contrasted with the effects of non-ionizing radiation. Section II reviews the contributions of various natural factors which influence the inherent radiosensitivity of biological systems. Inlcuded in the list of these factors are water, oxygen, thiols, vitamins and antioxidants. Brief attention is given to the model describing competition between oxygen and natural radioprotective substances (principally, thiols) in determining the net cellular radiosensitivity. Several theories of the mechanism(s) of action of radioprotective drugs are described in Section III. These mechanisms include the production of hypoxia, detoxication of radiochemical reactive species, stabilization of the radiobiological target and the enhancement of damage repair processes. Section IV describes the current strategies for the treatment of radiation injury. Likely areas in which fruitful research might be performed are described in Section V. 495 references.

  13. The MICE Demonstration of Muon Ionization Cooling

    Energy Technology Data Exchange (ETDEWEB)

    Lagrange, Jean-Baptiste [Imperial Coll., London; Hunt, Christopher [Imperial Coll., London; Palladino, Vittorio [INFN, Naples; Pasternak, Jaroslaw [Imperial Coll., London

    2016-06-01

    Muon beams of low emittance provide the basis for the intense, well-characterised neutrino beams necessary to elucidate the physics of flavour at the Neutrino Factory and to provide lepton-antilepton collisions up to several TeV at the Muon Collider. The international Muon Ionization Cooling Experiment (MICE) will demonstrate muon ionization cooling, the technique proposed to reduce the phase-space volume occupied by the muon beam at such facilities. In an ionization-cooling channel, the muon beam traverses a material (the absorber) loosing energy, which is replaced using RF cavities. The combined effect is to reduce the transverse emittance of the beam (transverse cooling). The configuration of MICE required to deliver the demonstration of ionization cooling is being prepared in parallel to the execution of a programme designed to measure the cooling properties of liquid-hydrogen and lithium hydride. The design of the cooling-demonstration experiment will be presented together with a summary of the performance of each of its components and the cooling performance of the experiment.

  14. Advanced calculus

    CERN Document Server

    Nickerson, HK; Steenrod, NE

    2011-01-01

    ""This book is a radical departure from all previous concepts of advanced calculus,"" declared the Bulletin of the American Mathematics Society, ""and the nature of this departure merits serious study of the book by everyone interested in undergraduate education in mathematics."" Classroom-tested in a Princeton University honors course, it offers students a unified introduction to advanced calculus. Starting with an abstract treatment of vector spaces and linear transforms, the authors introduce a single basic derivative in an invariant form. All other derivatives - gradient, divergent, curl,

  15. Rare Earth Oxide Thin Films

    CERN Document Server

    Fanciulli, Marco

    2007-01-01

    Thin rare earth (RE) oxide films are emerging materials for microelectronic, nanoelectronic, and spintronic applications. The state-of-the-art of thin film deposition techniques as well as the structural, physical, chemical, and electrical properties of thin RE oxide films and of their interface with semiconducting substrates are discussed. The aim is to identify proper methodologies for the development of RE oxides thin films and to evaluate their effectiveness as innovative materials in different applications.

  16. Heterogeneity in Polymer Thin Films

    OpenAIRE

    Kanaya, Toshiji; Inoue, Rintaro; Nishida, Koji

    2011-01-01

    In the last two decades very extensive studies have been performed on polymer thin films to reveal very interesting but unusual properties. One of the most interesting findings is the decrease in glass transition temperature Tg with film thickness in polystyrene (PS) thin film supported on Si substrate. Another interesting finding is apparent negative thermal expansivity in glassy state for thin films below ∼25 nm. In order to understand the unusual properties of polymer thin films we have st...

  17. NMR characterization of thin films

    Science.gov (United States)

    Gerald, II, Rex E.; Klingler, Robert J.; Rathke, Jerome W.; Diaz, Rocio; Vukovic, Lela

    2008-11-25

    A method, apparatus, and system for characterizing thin film materials. The method, apparatus, and system includes a container for receiving a starting material, applying a gravitational force, a magnetic force, and an electric force or combinations thereof to at least the starting material, forming a thin film material, sensing an NMR signal from the thin film material and analyzing the NMR signal to characterize the thin film of material.

  18. Radiation protection and dosimetry issues in the medical applications of ionizing radiation

    Science.gov (United States)

    Vaz, Pedro

    2014-11-01

    The technological advances that occurred during the last few decades paved the way to the dissemination of CT-based procedures in radiology, to an increasing number of procedures in interventional radiology and cardiology as well as to new techniques and hybrid modalities in nuclear medicine and in radiotherapy. These technological advances encompass the exposure of patients and medical staff to unprecedentedly high dose values that are a cause for concern due to the potential detrimental effects of ionizing radiation to the human health. As a consequence, new issues and challenges in radiological protection and dosimetry in the medical applications of ionizing radiation have emerged. The scientific knowledge of the radiosensitivity of individuals as a function of age, gender and other factors has also contributed to raising the awareness of scientists, medical staff, regulators, decision makers and other stakeholders (including the patients and the public) for the need to correctly and accurately assess the radiation induced long-term health effects after medical exposure. Pediatric exposures and their late effects became a cause of great concern. The scientific communities of experts involved in the study of the biological effects of ionizing radiation have made a strong case about the need to undertake low dose radiation research and the International System of Radiological Protection is being challenged to address and incorporate issues such as the individual sensitivities, the shape of dose-response relationship and tissue sensitivity for cancer and non-cancer effects. Some of the answers to the radiation protection and dosimetry issues and challenges in the medical applications of ionizing radiation lie in computational studies using Monte Carlo or hybrid methods to model and simulate particle transport in the organs and tissues of the human body. The development of sophisticated Monte Carlo computer programs and voxel phantoms paves the way to an accurate

  19. The MICE Demonstration of Ionization Cooling

    Energy Technology Data Exchange (ETDEWEB)

    Pasternak, J.; Blackmore, V.; Hunt, C.; Lagrange, J-B.; Long, K.; Collomb, N.; Snopok, P.

    2015-05-01

    Muon beams of low emittance provide the basis for the intense, well-characterised neutrino beams necessary to elucidate the physics of flavour at the Neutrino Factory and to provide lepton-antilepton collisions at energies of up to several TeV at the Muon Collider. The International Muon Ionization Cooling Experiment (MICE) will demonstrate ionization cooling, the technique by which it is proposed to reduce the phase-space volume occupied by the muon beam at such facilities. In an ionization cooling channel, the muon beam passes through a material (the absorber) in which it loses energy. The energy lost is then replaced using RF cavities. The combined effect of energy loss and re-acceleration is to reduce the transverse emittance of the beam (transverse cooling). A major revision of the scope of the project was carried out over the summer of 2014. The revised project plan, which has received the formal endorsement of the international MICE Project Board and the international MICE Funding Agency Committee, will deliver a demonstration of ionization cooling by September 2017. In the revised configuration a central lithium-hydride absorber provides the cooling effect. The magnetic lattice is provided by the two superconducting focus coils and acceleration is provided by two 201 MHz single-cavity modules. The phase space of the muons entering and leaving the cooling cell will be measured by two solenoidal spectrometers. All the superconducting magnets for the ionization cooling demonstration are available at the Rutherford Appleton Laboratory and the first single-cavity prototype is under test in the MuCool Test Area at Fermilab. The design of the cooling demonstration experiment will be described together with a summary of the performance of each of its components. The cooling performance of the revised configuration will also be presented.

  20. Detoxification of snake venom using ionizing radiation

    International Nuclear Information System (INIS)

    It is generally recognized that energy absorbed by ionizing radiation (gamma rays) can inactivate biological material in tow ways. A direct effects occurs when the primary event, i.e., ionization, is produced in the molecule itself. This is the case when a compound is irradiated in dry state. When a compound is irradiated in a solution, the indirect effect joins the direct. Since water is the most abundant constituent of biological material, it is important to consider the species produced by excitation and ionization of water itself, and the reaction of these species with the target molecules of biological importance. This indirect effect results from the reactions among the studied molecules and the products of radiation interaction with water or other solvents. Highly reactive compounds, the so-called free radicals, which are formed many reactions among themselves, with the dissolved gas, and with other molecules in the solution. With water, the excitation is less important than ionization which is followed within picosecond by the formation of free hydroxyl radicals and hydrated electrons. Alexander and Hamilton showed that irradiation of proteins has revealed damage to aminoacid side chains, production of new groups, splitting of peptide bonds and formation of intramolecular and intermolecular cross-links. With these results it would be possible to use ionizing radiation to change those proteins molecules in order to improve some of their properties according to the necessity. On the other hand, it is recognized that venoms in general are poorly immunogenic, yet fairly toxic. This cause problems because serotherapy is the treatment of choice in snakebite envenomations, and horse antivenom availability is dependent upon. (author)

  1. The multiphoton ionization of uranium hexafluoride

    International Nuclear Information System (INIS)

    Multiphoton ionization (MPI) time-of-flight mass spectroscopy and photoelectron spectroscopy studies of UF6 have been conducted using focused light from the Nd:YAG laser fundamental (λ = 1064 nm) and its harmonics (λ = 532, 355, or 266 nm), as well as other wavelengths provided by a tunable dye laser. The MPI mass spectra are dominated by the singly and multiply charged uranium ions rather than by the UFx+ fragment ions. The laser power dependence of Un+ ion signals indicates that saturation can occur for many of the steps required for their ionization. The doubly-charged uranium ion (U2+) intensity is much greater than that of the singly-charged uranium ion (U+). For the case of the tunable dye laser experiments, the Un+ (n=1-4) wavelength dependence is relatively unstructured and does not show observable resonance enhancement at known atomic uranium excitation wavelengths. The dominance of the U2+ ion and the absence or very small intensities of UFx+ fragments, along with the unstructured wavelength dependence, indicate that mechanisms may exist other than ionization of bare U atoms after the stepwise photodissociation of F atoms from the parent molecule. The data argue against step-wise photodissociation of UFx+ (x = 5,6) ions. Neither the neutral ladder nor the ion ladder mechanisms adequately describe the ionization phenomena observed. These results suggest an alternate mechanism which better explains the multiphoton excitation and dissociative ionization of UF6. It is likely that the multiphoton excitation of UF6 under these experimental conditions results in a superexcited molecule, UF6**, which primarily dissociates into Un+ (through multiple channels), fluorine atoms, and slow electrons. The excitation of such superexcited molecules may be facilitated by the existence of a previously reported giant resonance at 12-14 eV

  2. Detoxification of snake venom using ionizing radiation

    Energy Technology Data Exchange (ETDEWEB)

    Rogero, J.R.; Nascimento, N. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil). Supervisao de Radiobiologia

    1995-07-01

    It is generally recognized that energy absorbed by ionizing radiation (gamma rays) can inactivate biological material in tow ways. A direct effects occurs when the primary event, i.e., ionization, is produced in the molecule itself. This is the case when a compound is irradiated in dry state. When a compound is irradiated in a solution, the indirect effect joins the direct. Since water is the most abundant constituent of biological material, it is important to consider the species produced by excitation and ionization of water itself, and the reaction of these species with the target molecules of biological importance. This indirect effect results from the reactions among the studied molecules and the products of radiation interaction with water or other solvents. Highly reactive compounds, the so-called free radicals, which are formed many reactions among themselves, with the dissolved gas, and with other molecules in the solution. With water, the excitation is less important than ionization which is followed within picosecond by the formation of free hydroxyl radicals and hydrated electrons. Alexander and Hamilton showed that irradiation of proteins has revealed damage to aminoacid side chains, production of new groups, splitting of peptide bonds and formation of intramolecular and intermolecular cross-links. With these results it would be possible to use ionizing radiation to change those proteins molecules in order to improve some of their properties according to the necessity. On the other hand, it is recognized that venoms in general are poorly immunogenic, yet fairly toxic. This cause problems because serotherapy is the treatment of choice in snakebite envenomations, and horse antivenom availability is dependent upon. (author)

  3. Amplitude distribution of ionization jerks in ionization-chamber ASK-1 according long-term measurements

    Science.gov (United States)

    Timofeev, Vladislav

    2016-07-01

    As part of the Yakut complex systems by measuring the intensity of cosmic rays has a unique device spherical - ionization chamber ASK-1 with a lead screen thickness of 12 cm. The camera allows you to explore the physical characteristics of the so-called "ionization jerks " - sharp increases ionization current caused by the passage through the device much ionizing particles of cosmic origin. Due to a large increase in current nuclear cascade "showers", formed mainly by particles of cosmic rays in the camera screen. Over the entire period of observation (50 years old) camera ASK-1 was registered 59125 aftershocks. Their nature and properties still does not sufficiently studied, especially in medium and large amplitudes.

  4. Measurement of the first ionization potential of astatine by laser ionization spectroscopy

    CERN Document Server

    Rothe, S; Antalic, S; Borschevsky, A; Capponi, L; Cocolios, T E; De Witte, H; Eliav, E; Fedorov, D V; Fedosseev, V N; Fink, D A; Fritzsche, S; Ghys, L; Huyse, M; Imai, N; Kaldor, U; Kudryavtsev, Yu; Köster, U; Lane, J; Lassen, J; Liberati, V; Lynch, K M; Marsh, B A; Nishio, K; Pauwels, D; Pershina, V; Popescu, L; Procter, T J; Radulov, D; Raeder, S; Rajabali, M M; Rapisarda, E; Rossel, R E; Sandhu, K; Seliverstov, M D; Sjödin, A M; Van den Bergh, P; Van Duppen, P; Venhart, M; Wakabayashi, Y; Wendt K D A

    2013-01-01

    The radioactive element astatine exists only in trace amounts in nature. Its properties can therefore only be explored by study of smallest quantities of artificially produced isotopes or by performing theoretical calculations. One of the most important properties influencing the chemical behaviour is the energy required to remove one electron from the valence shell, referred to as the ionization potential. Here we use laser spectroscopy to probe the optical spectrum of astatine near the ionization threshold. The observed series of Rydberg states enabled the first determination of the ionization potential of the astatine atom, 9.317510(8) eV. New ab initio calculations were performed to support the experimental result. The measured value serves as a benchmark for quantum chemistry calculations of the properties of astatine as well as for the theoretical prediction of the ionization potential of super-heavy element 117, the heaviest homologue of astatine.

  5. Rydberg atom ionization by slow collisions with alkali element atoms

    International Nuclear Information System (INIS)

    A new mechanism for ionization of highexcited atoms due to the electron capture into the autoionization state of a negative ion is suggested. Calculations of cross-sections and the ionization rate for sodium and lithium atoms collisions are performed

  6. The Flatness and Sudden Evolution of the Intergalactic Ionizing Background

    CERN Document Server

    Muñoz, Joseph A; Davies, Frederick B; Furlanetto, Steven R

    2014-01-01

    The ionizing background of cosmic hydrogen is an important probe of the sources and absorbers of ionizing radiation, their evolution and relationship, in the post-reionization universe. Previous studies show that the ionization rate should be very sensitive to changes in the source population: as the emissivity rises, absorbers shrink in size, increasing the ionizing mean free path and, hence, the ionizing background. By contrast, observations of the ionizing background find a very flat evolution from z~2-5, before falling precipitously at z~6. We resolve this discrepancy by pointing out that, at z~2-5, neutral absorbers are associated with the same collapsed halos that additionally host ionizing galactic sources. Thus, an increasing abundance of galaxies is compensated for by a corresponding increase in the absorber population, which moderates the instability in the ionizing background. However, by z~5-6, gas outside of halos dominates the absorption, the coupling between sources and absorbers is lost, and t...

  7. Fully differential cross sections for heavy particle impact ionization

    Energy Technology Data Exchange (ETDEWEB)

    McGovern, M; Walters, H R J [Department of Applied Mathematics and Theoretical Physics, Queen' s University, Belfast BT7 1NN (United Kingdom); Assafrao, D; Mohallem, J R [Laboratorio de Atomos e Moleculas Especiais, Departamento de Fisica, ICEx, Universidade Federal de Minas Gerais, P.O Box 702, 30123-970 Belo Horizonte, MG (Brazil); Whelan, Colm T, E-mail: mmcgovern06@qub.ac.u [Department of Physics, Old Dominion University, Norfolk, VA 23529-0116 (United States)

    2009-11-15

    We describe a procedure for extracting fully differential ionization cross sections from an impact parameter coupled pseudostate treatment of the collision. Some examples from antiproton impact ionization of atomic Hydrogen are given.

  8. Ground Levels and Ionization Energies for the Neutral Atoms

    Science.gov (United States)

    SRD 111 Ground Levels and Ionization Energies for the Neutral Atoms (Web, free access)   Data for ground state electron configurations and ionization energies for the neutral atoms (Z = 1-104) including references.

  9. Creation of prompt and thin-sheet splashing by varying surface roughness or increasing air pressure

    CERN Document Server

    Latka, Andrzej; Driscoll, Michelle M; Stevens, Cacey S; Nagel, Sidney R

    2012-01-01

    A liquid drop impacting a solid surface may splash by emitting a thin liquid sheet that subsequently breaks apart or by promptly ejecting droplets from the advancing liquid-solid contact line. Using high-speed imaging, we show that air pressure and surface roughness influence both splash mechanisms. Roughness increases prompt splashing at the advancing contact line but inhibits the formation of the thin sheet. If the air pressure is lowered, droplet ejection is suppressed not only during thin-sheet formation but for prompt splashing as well. The threshold pressure depends on impact velocity, liquid viscosity and surface roughness.

  10. The ultraviolet and blue luminescence properties of ZnO:Zn thin film

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The ultraviolet (UV) and blue luminescence of Zn-rich zinc oxide thin film deposited by electron-beam evaporation have been investigated at room temperature (RT). We observed that the UV and blue electroluminescence (EL) emission band centered around 480 nm which is blue shifted in comparison with that of the ZnO thin film prepared by low pressure metal organic chemical vapor deposition (LP MOCVD). The UV emission is much stronger than blue emission in the photoluminescence (PL) spectra. The field-induced ionization of excited luminescent centers of ZnO:Zn thin film at high electric field and the difference between PL and EL are discussed. The experiments show that the ZnO:Zn thin film provides a hopeful new mechanism to obtain UV and blue emission.

  11. Two-photon ionization of atomic hydrogen above the one-photon ionization threshold

    Energy Technology Data Exchange (ETDEWEB)

    Jayadevan, A.P. [Department of Physics, Cochin University of Science and Technology, Kochi (India); Thayyullathil, Ramesh Babu [Department of Physics, Cochin University of Science and Technology, Kochi (India)]. E-mail: rbt@cusat.ac.in

    2001-02-28

    An alternative method is presented for the evaluation of the two-photon ionization transition amplitude and transition rates of atomic hydrogen in the ground state above the one-photon ionization threshold. In this approach it is straightforward to calculate the angular distribution of the emitted electrons. These angular distributions are plotted and calculated transition rates are compared with the previously reported results. (author)

  12. On the Primary Ionization Mechanism(s) in Matrix-Assisted Laser Desorption Ionization

    OpenAIRE

    Laura Molin; Roberta Seraglia; Zbigniew Czarnocki; Maurin, Jan K; Franciszek A. Pluciński; Pietro Traldi

    2012-01-01

    A mechanism is proposed for the first step of ionization occurring in matrix-assisted laser desorption ionization, leading to protonated and deprotonated matrix (Ma) molecules ([Ma + H]+ and [Ma − H]− ions). It is based on observation that in solid state, for carboxyl-containing MALDI matrices, the molecules form strong hydrogen bonds and their carboxylic groups can act as both donors and acceptors. This behavior leads to stable dimeric structures. The laser irradiation leads to the cleavage ...

  13. Matrix Assisted Ionization Vacuum (MAIV), a New Ionization Method for Biological Materials Analysis Using Mass Spectrometry*

    OpenAIRE

    Inutan, Ellen D.; Trimpin, Sarah

    2012-01-01

    The introduction of electrospray ionization (ESI) and matrix-assisted laser desorption/ionization (MALDI) for the mass spectrometric analysis of peptides and proteins had a dramatic impact on biological science. We now report that a wide variety of compounds, including peptides, proteins, and protein complexes, are transported directly from a solid-state small molecule matrix to gas-phase ions when placed into the vacuum of a mass spectrometer without the use of high voltage, a laser, or adde...

  14. A Multistep Algorithm for the Radiation Hydrodynamical Transport of Cosmological Ionization Fronts and Ionized Flows

    OpenAIRE

    Daniel J. Whalen; Norman, Michael L.

    2005-01-01

    Radiation hydrodynamical transport of ionization fronts in the next generation of cosmological reionization simulations holds the promise of predicting UV escape fractions from first principles as well as investigating the role of photoionization in feedback processes and structure formation. We present a multistep integration scheme for radiative transfer and hydrodynamics for accurate propagation of I-fronts and ionized flows from a point source in cosmological simulations. The algorithm is...

  15. Technological Advancements

    Science.gov (United States)

    Kennedy, Mike

    2010-01-01

    The influx of technology has brought significant improvements to school facilities. Many of those advancements can be found in classrooms, but when students head down the hall to use the washrooms, they are likely to find a host of technological innovations that have improved conditions in that part of the building. This article describes modern…

  16. Advanced ferroelectricity

    CERN Document Server

    Blinc, R

    2011-01-01

    Advances in the field of ferroelectricity have implications both for basic physics and for technological applications such as memory devices, spintronic applications and electro-optic devices, as well as in acoustics, robotics, telecommunications and medicine. This book provides an account of recent developments in the field.

  17. Smart ionization chamber for gamma-ray monitoring

    OpenAIRE

    Drndarević Vujo R.; Jevtić Nenad J.; Rajović Vladimir M.; Stanković Srboljub J.

    2014-01-01

    A design and implementation of a smart ionization chamber suitable for connection into gamma radiation monitoring networks is presented in this paper. The smart ionization chamber consists of air-equivalent one liter ionization chamber with associated electronics and a built-in memory for storage of electronic data specifications. Generally, operating and measurement characteristics of the used ionization chamber are written into the memory chip attached to...

  18. Single and double ionization of gallium by electron impact

    Indian Academy of Sciences (India)

    L K Jha

    2002-09-01

    Electron impact single and double ionization cross sections of gallium have been calculated in the binary encounter approximation using accurate expression for including exchange and interference as given by Vriens and Hartree–Fock velocity distributions for the target electrons throughout the calculations. It is concluded that the ionization of 3d shell contributes partly to single ionization and partly to double ionization. The results so obtained show reasonably good agreement with the experimental data.

  19. Statistic approach to multiphoton, multielectron ionization of atoms

    International Nuclear Information System (INIS)

    The density of states and the excitation temperature of an atom are found. To describe the ionization process, a diffusion equation with ejection is proposed. It is shown that the possibility of multielectron ionization is determined by the competition of the heating of an atom by an external field and evaporative ionization. A numerical calculation is made of the ionization of xenon atoms and a comparison with experimental results is given

  20. High-Order Harmonic Generation in the Ionization Process

    Institute of Scientific and Technical Information of China (English)

    CHEN Jing; CHEN Shi-Gang; LIU Jie

    2000-01-01

    Based on the nonperturbative quantum electrodynamics scattering theory for multiphoton ionization developed recently, high-order harmonic generated in the ionization process is discussed. The influence of the Coulomb potential is treated as a perturbation in the expansion of the transition matrix. It is deduced that the harmonic photons are emitted in the resonant process during ionization and the width of the harmonic peaks is just the ionization rate of the atom.

  1. Mechanism of delayed double ionization in a strong laser field

    OpenAIRE

    Mauger, Francois; Kamor, Adam; Chandre, Cristel; UZer, Turgay

    2011-01-01

    When intense laser pulses release correlated electrons, the time delay between the ionizations may last more than one laser cycle. We show that this "Recollision-Excitation with Subsequent Ionization" pathway originates from the inner electron being promoted to a sticky region by a recollision where it is trapped for a long time before ionizing. We identify the mechanism which regulates this region, and predict oscillations in the double ionization yield with laser intensity.

  2. EXCITATION AND IONIZATION OF LASER-PUMPED Ba VAPOUR

    OpenAIRE

    Huber, M.; Jahreiss, L.

    1985-01-01

    We describe the excitation and ionization of dense Ba vapour (1019 to 2021 m-3) by resonant (λ = 553.5 nm) laser radiation and discuss the processes responsible for the transfer of energy from the laser-excited atoms into ionization. Ionization was found to be density-dependent and this pointed to collision-dominated ionization mechanisms. It has been established that seed electrons were heated in superelastic collisions with laser-excited atoms, and that subsequent electron-impact excitation...

  3. Ionizing energy in food processing and pest control. 1. Wholesomeness of food treated with ionizing energy

    International Nuclear Information System (INIS)

    Congressional concerns about the use of ionizing energy for food preservation and to control pests in food products for export and domestic use promoted the preparation of this report by a special task force of the Council for Agricultural Science and Technology (CAST). An overview surveys research conducted on the toxicological safety, nutritional quality, and microbiological safety of foods treated with ionizing energy. Background information is provided on various types of electromagnetic radiation, effects of ionizing energy level and dose, sources of natural background radiation and induced radioactivity, and the nature and safety of various radiolytic products. Objectives, methodologies, and problems associated with feeding studies of toxicological safety are outlined; results of scientific studies, U.S. government wholesomeness studies, and international feeding studies are summarized. Studies on the nutritional value of food products processed using ionized energy have examined the effects of ionizing energy on 1) composite diets, 2) carbohydrates, 3) fats, 4) proteins and amino acids, 5) vitamins (potatoes, onions, fruits, meat, seafood, cereals, vegetables, dairy products, oils), 6) antivitamins, and 7) minerals. The report concludes that currently available scientific evidence indicates that foods exposed to ionizing energy under the conditions proposed for commercial application are 1) wholesome (safe to eat) and 2) comparable in nutritional adequacy to fresh or conventionally processed foods

  4. Determination of collisional ionization rate and ionization yield from excited levels of cesium in a flame

    International Nuclear Information System (INIS)

    A method is proposed for determining the rate constants of collisional ionization and the ionization yield from excited levels of cesium atoms in a flame, using experimental curves of optical saturation and laser-stimulated ionization of excited atoms. It is shown that deviations of the shape of the saturation curves from ideal shape are due to the time dependence of the trailing edge of the exciting laser pulse. The ionization yield of cesium in an acetylene--air flame during its one-step excitation to the 6p2p1/2 level was 0.95%, rising to 50% for two-step excitation to the 8d2D3/2 level. The corresponding values of the rate constants of collisional ionization were 3.2x105 and 3.3x107 sec-1. From the known value of the ionization yield in the two-step excitation scheme, estimates of the atomization coefficient of cesium in the flame were made. The proposed method can be used for other elements in different flames

  5. Proton beam dosimetry: a comparison between a plastic scintillator, ionization chamber and Faraday cup.

    Science.gov (United States)

    Ghergherehchi, Mitra; Afarideh, Hossein; Ghannadi, Mohammad; Mohammadzadeh, Ahmad; Aslani, Golam Reza; Boghrati, Behzad

    2010-01-01

    In this study, a comparison was made between a plastic scintillator (BC400), a Faraday Cup (FC) and an ionization chamber (IC) used for routine proton dosimetry. Thin scintillators can be applied to proton dosimetry and consequently to proton therapy as relative dosimeters because of their water-equivalent nature, high energy-light conversion efficiency, low dimensions and good proportionality to the absorbed dose at low stopping powers. To employ such scintillators as relative dosimeters in proton therapy, the corrective factors must be applied to correct the quenching luminescence at the Bragg peak. A fine linear proportionality between the luminescence light yield Y and the proton flux in a thin (0.5 mm) scintillator for the 20 and 30 MeV proton beams were observed. The experimental peak/plateau ratios of Bragg Curve for 2, 1 and 0.5 mm scintillators with an accuracy of 0.5% were obtained to be 1.87, 1.91 and 2.30, respectively. With combination of the Markus chamber and the CR-39 detector, the peak/plateau ratio was improved to 3.26. The obtained data of the luminescence yield as a function of the specific energy loss is in agreement with the Craun-Birk's theory. Results show that the FC and Markus ionization chamber are in agreement within 4%, while the FC gives a lower dose evaluation. For a defined beam, the data for the fluence measurements are reproducible within a good accuracy.

  6. Thin Film Heat Flux Sensor Development for Ceramic Matrix Composite (CMC) Systems

    Science.gov (United States)

    Wrbanek, John D.; Fralick, Gustave C.; Hunter, Gary W.; Zhu, Dongming; Laster, Kimala L.; Gonzalez, Jose M.; Gregory, Otto J.

    2010-01-01

    The NASA Glenn Research Center (GRC) has an on-going effort for developing high temperature thin film sensors for advanced turbine engine components. Stable, high temperature thin film ceramic thermocouples have been demonstrated in the lab, and novel methods of fabricating sensors have been developed. To fabricate thin film heat flux sensors for Ceramic Matrix Composite (CMC) systems, the rough and porous nature of the CMC system posed a significant challenge for patterning the fine features required. The status of the effort to develop thin film heat flux sensors specifically for use on silicon carbide (SiC) CMC systems with these new technologies is described.

  7. L-subshell ionization cross sections for Hf, Ta and W by H+ and He+ bombardment

    International Nuclear Information System (INIS)

    X-rays resulting from L-subshell vacancies in Hf, Ta and W produced by bombarding thin targets with H+(0.6 - 2.5 MeV) and He (1.2 - 4.2 MeV) were detected by Si(Li) spectrometry. Ionization cross sections were obtained by using the above measurements, branching ratios from theoretical calculations and values of the fluorescence yields and Coster-Kronig factors obtained by interpolating from experimental data. The observed projectile energy dependence of the L sub(II) subshell ionization cross section is reasonably well reproduced by the plane wave Born approximation (PWBA) but the introduction of relativistic, trajectory and binding corrections (PWBA-BTR) are essential for the description of the L sub(I) and L sub (III) data. Scaling of the H+ and He+ data shows good agreement one with the other. The behavior of the ionization cross section versus bombarding energy is correlated with some special features of the electronic bound-state wave functions. (author)

  8. Merits of online electrochemistry liquid sample desorption electrospray ionization mass spectrometry (EC/LS DESI MS).

    Science.gov (United States)

    Looi, Wen Donq; Brown, Blake; Chamand, Laura; Brajter-Toth, Anna

    2016-03-01

    A new online electrochemistry/liquid sample desorption electrospray ionization mass spectrometry (EC/LS DESI MS) system with a simple electrochemical thin-layer flow-through cell was developed and tested using N,N-dimethyl-p-phenylenediamine (DMPA) as a model probe. Although oxidation of DMPA is observed as a result of ionization of LS in positive ion mode LS DESI, application of voltage to the online electrochemical (EC) cell in EC/LS DESI MS increases yields of oxidation products. An advantage of LS DESI MS is its sensitivity in aqueous electrolyte solutions, which improves efficiency of electrochemical reactions in EC/LS DESI MS. In highly conductive low pH aqueous buffer solutions, oxidation efficiency is close to 100%. EC/ESI MS typically requires mixed aqueous/organic solvents and low electrolyte concentrations for efficient ionization in MS, limiting efficiency of electrochemistry online with MS. Independently, the results verify higher electrochemical oxidation efficiency during positive mode ESI than during LS DESI.

  9. Merits of online electrochemistry liquid sample desorption electrospray ionization mass spectrometry (EC/LS DESI MS).

    Science.gov (United States)

    Looi, Wen Donq; Brown, Blake; Chamand, Laura; Brajter-Toth, Anna

    2016-03-01

    A new online electrochemistry/liquid sample desorption electrospray ionization mass spectrometry (EC/LS DESI MS) system with a simple electrochemical thin-layer flow-through cell was developed and tested using N,N-dimethyl-p-phenylenediamine (DMPA) as a model probe. Although oxidation of DMPA is observed as a result of ionization of LS in positive ion mode LS DESI, application of voltage to the online electrochemical (EC) cell in EC/LS DESI MS increases yields of oxidation products. An advantage of LS DESI MS is its sensitivity in aqueous electrolyte solutions, which improves efficiency of electrochemical reactions in EC/LS DESI MS. In highly conductive low pH aqueous buffer solutions, oxidation efficiency is close to 100%. EC/ESI MS typically requires mixed aqueous/organic solvents and low electrolyte concentrations for efficient ionization in MS, limiting efficiency of electrochemistry online with MS. Independently, the results verify higher electrochemical oxidation efficiency during positive mode ESI than during LS DESI. PMID:26886744

  10. High order fluid model for ionization fronts in streamer discharges

    NARCIS (Netherlands)

    Markosyan, A.; Dujko, S.; Hundsdorfer, W.; Ebert, U.

    2011-01-01

    When non-ionized or lowly ionized matter is exposed to high electric fields, non-equilibrium ionization processes, streamer discharges, can develop. Streamers occur in nature and as well in many industrial applications such as the treatment of exhaust gasses, polluted water or biogas. A third order

  11. Thin Film Microbatteries

    International Nuclear Information System (INIS)

    Thin film batteries are built layer by layer by vapor deposition. The resulting battery is formed of parallel plates, much as an ordinary battery construction, just much thinner. The figure (Fig. 1) shows an example of a thin film battery layout where films are deposited symmetrically onto both sides of a supporting substrate. The full stack of films is only 10 to 15 (micro)m thick, but including the support at least doubles the overall battery thickness. When the support is thin, the entire battery can be flexible. At least six companies have commercialized or are very close to commercializing such all-solid-state thin film batteries and market research predicts a growing market and a variety of applications including sensors, RFID tags, and smarter cards. In principle with a large deposition system, a thin film battery might cover a square meter, but in practice, most development is targeting individual cells with active areas less than 25 cm2. For very small battery areas, 2, microfabrication processes have been developed. Typically the assembled batteries have capacities from 0.1 to 5 mAh. The operation of a thin film battery is depicted in the schematic diagram (Fig. 2). Very simply, when the battery is allowed to discharge, a Li+ ion migrates from the anode to the cathode film by diffusing through the solid electrolyte. When the anode and cathode reactions are reversible, as for an intercalation compound or alloy, the battery can be recharged by reversing the current. The difference in the electrochemical potential of the lithium determines the cell voltage. Most of the thin films used in current commercial variations of this thin film battery are deposited in vacuum chambers by RF and DC magnetron sputtering and by thermal evaporation onto unheated substrates. In addition, many publications report exploring a variety of other physical and chemical vapor deposition processes, such as pulsed laser deposition, electron cyclotron resonance sputtering, and

  12. Thin film characterisation by advanced X-ray diffraction techniques

    Energy Technology Data Exchange (ETDEWEB)

    Cappuccio, G.; Terranova, M.L. [eds.] [INFN, Laboratori Nazionali di Frascati, Rome (Italy)

    1996-09-01

    This report described the papers presented at the 5. School on X-ray diffraction from polycrystalline materials held at Frascati (Rome) in 2-5 October 1996. A separate abstract was prepared for each of the papers.

  13. Intensity dependence of strong field double ionization mechanisms: from field-assisted recollision ionization to recollision-assisted field ionization

    CERN Document Server

    Emmanouilidou, A

    2009-01-01

    Using a three-dimensional quasiclassical technique we explore molecular double ionization by a linearly polarized, infrared (800 nm) and ultrashort (6 fs) laser pulse. We first focus on intensities corresponding to the tunneling regime and identify the main ionization mechanisms in this regime. We devise a selection of observables, such as, the correlated momenta and the sum of the momenta parallel to the laser field as a function of the inter-electronic angle of escape where all the main mechanisms have distinct traces. Secondly, we address intensities above but close to the over-the-barrier intensity regime. We find a surprising anti-correlation of electron momenta similar to the experimental observations reported in Phys. Rev. Lett. \\textbf{101}, 053001 (2008). There, however, the anti-correlation was observed in very low intensities corresponding to the multiphoton regime. We discuss the mechanism responsible for the anti-parallel two-electron escape.

  14. [Spectral emissivity of thin films].

    Science.gov (United States)

    Zhong, D

    2001-02-01

    In this paper, the contribution of multiple reflections in thin film to the spectral emissivity of thin films of low absorption is discussed. The expression of emissivity of thin films derived here is related to the thin film thickness d and the optical constants n(lambda) and k(lambda). It is shown that in the special case d-->infinity the emissivity of thin films is equivalent to that of the bulk material. Realistic numerical and more precise general numerical results for the dependence of the emissivity on d, n(lambda) and k(lambda) are given.

  15. Multistage Reactive Transmission-Mode Desorption Electrospray Ionization Mass Spectrometry.

    Science.gov (United States)

    Peters, Kevin C; Comi, Troy J; Perry, Richard H

    2015-09-01

    Elucidating reaction mechanisms is important for advancing many areas of science such as catalyst development. It is often difficult to probe fast reactions at ambient conditions with high temporal resolution. In addition, systems involving reagents that cross-react require analytical methods that can minimize interaction time and specify their order of introduction into the reacting system. Here, we explore the utility of transmission mode desorption electrospray ionization (TM-DESI) for reaction monitoring by directing a microdroplet spray towards a series of meshes with micrometer-sized openings coated with reagents, an approach we call multistage reactive TM-DESI (TM (n) -DESI, where n refers to the number of meshes; n = 2 in this report). Various stages of the reaction are initiated at each mesh surface, generating intermediates and products in microdroplet reaction vessels traveling towards the mass spectrometer. Using this method, we investigated the reactivity of iron porphyrin catalytic hydroxylation of propranolol and other substrates. Our experimental results indicate that TM (n) -DESI provides the ability to spatially separate reagents and control their order of introduction into the reacting system, thereby minimizing unwanted reactions that lead to catalyst deactivation and degradation products. In addition, comparison with DESI-MS analyses (the Zare and Latour laboratories published results suggesting accessible reaction times <1 ms) of the reduction of dichlorophenolindophenol by L-ascorbic acid suggest that TM (1) -DESI can access reaction times less than 1 ms. Multiple meshes allow sequential stages of desorption/ionization per MS scan, increasing the number of analytes and reactions that can be characterized in a single experiment. PMID:26091888

  16. Biomimetic thin film deposition

    Energy Technology Data Exchange (ETDEWEB)

    Rieke, P.R.; Graff, G.E.; Campbell, A.A.; Bunker, B.C.; Baskaran, S.; Song, L.; Tarasevich, B.J.; Fryxell, G.E.

    1995-09-01

    Biological mineral deposition for the formation of bone, mollusk shell and other hard tissues provides materials scientists with illustrative materials processing strategies. This presentation will review the key features of biomineralization and how these features can be of technical importance. We have adapted existing knowledge of biomineralization to develop a unique method of depositing inorganic thin films and coating. Our approach to thin film deposition is to modify substrate surfaces to imitate the proteins found in nature that are responsible for controlling mineral deposition. These biomimetic surfaces control the nucleation and growth of the mineral from a supersaturated aqueous solution. This has many processing advantages including simple processing equipment, environmentally benign reagents, uniform coating of highly complex shapes, and enhanced adherence of coating. Many different types of metal oxide, hydroxide, sulfide and phosphate materials with useful mechanical, optical, electronic and biomedical properties can be deposited.

  17. Thin film superfluid optomechanics

    CERN Document Server

    Baker, Christopher G; McAuslan, David L; Sachkou, Yauhen; He, Xin; Bowen, Warwick P

    2016-01-01

    Excitations in superfluid helium represent attractive mechanical degrees of freedom for cavity optomechanics schemes. Here we numerically and analytically investigate the properties of optomechanical resonators formed by thin films of superfluid $^4$He covering micrometer-scale whispering gallery mode cavities. We predict that through proper optimization of the interaction between film and optical field, large optomechanical coupling rates $g_0>2\\pi \\times 100$ kHz and single photon cooperativities $C_0>10$ are achievable. Our analytical model reveals the unconventional behaviour of these thin films, such as thicker and heavier films exhibiting smaller effective mass and larger zero point motion. The optomechanical system outlined here provides access to unusual regimes such as $g_0>\\Omega_M$ and opens the prospect of laser cooling a liquid into its quantum ground state.

  18. The Cryogenic Dark Matter Search low ionization-threshold experiment

    Energy Technology Data Exchange (ETDEWEB)

    Basu Thakur, Ritoban [Univ. of Illinois, Urbana-Champaign, IL (United States)

    2014-01-01

    Over 80 years ago we discovered the presence of Dark Matter in our universe. Endeavors in astronomy and cosmology are in consensus with ever improving precision that Dark Matter constitutes an essential 27% of our universe. The Standard Model of Particle Physics does not provide any answers to the Dark Matter problem. It is imperative that we understand Dark Matter and discover its fundamental nature. This is because, alongside other important factors, Dark Matter is responsible for formation of structure in our universe. The very construct in which we sit is defined by its abundance. The Milky Way galaxy, hence life, wouldn't have formed if small over densities of Dark Matter had not caused sufficient accretion of stellar material. Marvelous experiments have been designed based on basic notions to directly and in-directly study Dark Matter, and the Cryogenic Dark Matter Search (CDMS) experiment has been a pioneer and forerunner in the direct detection field. Generations of the CDMS experiment were designed with advanced scientific upgrades to detect Dark Matter particles of mass O(100) GeV/c2. This mass-scale was set primarily by predictions from Super Symmetry. Around 2013 the canonical SUSY predictions were losing some ground and several observations (rather hints of signals) from various experiments indicated to the possibility of lighter Dark Matter of mass O(10) GeV/c2. While the SuperCDMS experiment was probing the regular parameter space, the CDMSlite experiment was conceived to dedicatedly search for light Dark Matter using a novel technology. "CDMSlite" stands for CDMS - low ionization threshold experiment. Here we utilize a unique electron phonon coupling mechanism to measure ionization generated by scattering of light particles. Typically signals from such low energy recoils would be washed under instrumental noise. In CDMSlite via generation of Luke-Neganov phonons we can detect the small ionization energies, amplified in

  19. Evaporated VOx Thin Films

    Science.gov (United States)

    Stapinski, Tomasz; Leja, E.

    1989-03-01

    VOx thin films on glass were obtained by thermal evaporation of V205, powder. The structural investigations were carried out with the use of X-ray diffractometer. The electrical properties of the film were examined by means of temperature measurements of resistivity for the samples heat-treated in various conditions. Optical transmission and reflection spectra of VOX films of various composition showed the influence of the heat treatment.

  20. Thin film superconductor magnetic bearings

    Science.gov (United States)

    Weinberger, Bernard R.

    1995-12-26

    A superconductor magnetic bearing includes a shaft (10) that is subject to a load (L) and rotatable around an axis of rotation, a magnet (12) mounted to the shaft, and a stator (14) in proximity to the shaft. The stator (14) has a superconductor thin film assembly (16) positioned to interact with the magnet (12) to produce a levitation force on the shaft (10) that supports the load (L). The thin film assembly (16) includes at least two superconductor thin films (18) and at least one substrate (20). Each thin film (18) is positioned on a substrate (20) and all the thin films are positioned such that an applied magnetic field from the magnet (12) passes through all the thin films. A similar bearing in which the thin film assembly (16) is mounted on the shaft (10) and the magnet (12) is part of the stator (14) also can be constructed.

  1. Thin shell model revisited

    CERN Document Server

    Gao, Sijie

    2014-01-01

    We reconsider some fundamental problems of the thin shell model. First, we point out that the "cut and paste" construction does not guarantee a well-defined manifold because there is no overlap of coordinates across the shell. When one requires that the spacetime metric across the thin shell is continuous, it also provides a way to specify the tangent space and the manifold. Other authors have shown that this specification leads to the conservation laws when shells collide. On the other hand, the well-known areal radius $r$ seems to be a perfect coordinate covering all regions of a spherically symmetric spacetime. However, we show by simple but rigorous arguments that $r$ fails to be a coordinate covering a neighborhood of the thin shell if the metric across the shell is continuous. When two spherical shells collide and merge into one, we show that it is possible that $r$ remains to be a good coordinate and the conservation laws hold. To make this happen, different spacetime regions divided by the shells must...

  2. Advanced Virgo

    CERN Multimedia

    Virgo, a first-generation interferometric gravitational wave (GW) detector, located in the European Gravitational Observatory, EGO, Cascina (Pisa-Italy) and constructed by the collaboration of French and Italian institutes (CNRS and INFN) has successfully completed its long-duration data taking runs. It is now undergoing a fundamental upgrade that exploits available cutting edges technology to open an exciting new window on the universe, with the first detection of a gravitational wave signal. Advanced Virgo (AdV) is the project to upgrade the Virgo detector to a second-generation instrument. AdV will be able to scan a volume of the Universe 1000 times larger than initial Virgo. AdV will be hosted in the same infrastructures as Virgo. The Advanced VIRGO project is funded and at present carried on by a larger collaboration of institutes belonging to CNRS- France , RMKI - Hungary, INFN- Italy, Nikhef - The Netherlands Polish Academy of Science - Poland.

  3. Canadian Educational Approaches for the Advancement of Pharmacy Practice

    OpenAIRE

    Frankel, Grace; Louizos, Christopher; Austin, Zubin

    2014-01-01

    Canadian faculties (schools) of pharmacy are actively engaged in the advancement and restructuring of their programs in response to the shift in pharmacy to pharmacists having/assuming an advanced practitioner role. Unfortunately, there is a paucity of evidence outlining optimal strategies for accomplishing this task. This review explores several educational changes proposed in the literature to aid in the advancement of pharmacy education such as program admission requirements, critical-thin...

  4. Advanced Nanoemulsions

    Science.gov (United States)

    Fryd, Michael M.; Mason, Thomas G.

    2012-05-01

    Recent advances in the growing field of nanoemulsions are opening up new applications in many areas such as pharmaceuticals, foods, and cosmetics. Moreover, highly controlled nanoemulsions can also serve as excellent model systems for investigating basic scientific questions about soft matter. Here, we highlight some of the most recent developments in nanoemulsions, focusing on methods of formation, surface modification, material properties, and characterization. These developments provide insight into the substantial advantages that nanoemulsions can offer over their microscale emulsion counterparts.

  5. Advanced LIGO

    OpenAIRE

    Aasi, J.; Abbott, B.; Abbott, R.; Abbott, T.; Abernathy, M; Ackley, K.; Adams, C.; Adams, T.; Addesso, P.; Adhikari, R.; Adya, V.; Affeldt, C.; Aggarwal, N.; Aguiar, O.; Ain, A.

    2014-01-01

    The Advanced LIGO gravitational wave detectors are second-generation instruments designed and built for the two LIGO observatories in Hanford, WA and Livingston, LA, USA. The two instruments are identical in design, and are specialized versions of a Michelson interferometer with 4 km long arms. As in Initial LIGO, Fabry–Perot cavities are used in the arms to increase the interaction time with a gravitational wave, and power recycling is used to increase the effective laser power. Signal recyc...

  6. Advanced Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, Gordon R. [NETL

    2013-03-11

    The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

  7. Theoretical studies of highly ionized species

    Science.gov (United States)

    Dalgarno, A.; Victor, G. A.

    1980-10-01

    The calculations of the charge transfer recombination and ionization rate coefficients for a wide range of ionic systems in collision with hydrogen and helium at thermal energies were completed. For the carbon ions in hydrogen, the calculations were extended to energies of 100 ev. The importance of the processes in ionized plasmas was demonstrated by studies of the solar corona and of shock waves. Preliminary results were obtained on cross sections for the excitation of fine structure transitions by proton impacts. The mechanisms leading to the photodissociation of alkali metal dimers were identified and quantitative predictions were made for Li2. Calculations using the model potential method of properties of the Cu and Zn sequences were brought to a conclusion. Applications of the relativistic random phase approximation were made to the calculation of photoionization cross sections of magnesium-like and zinc-like ions and of oscillator strengths of mercury.

  8. Secondary ionization and heating by fast electrons

    CERN Document Server

    Furlanetto, Steven

    2009-01-01

    We examine the fate of fast electrons (with energies E>10 eV) in a thermal gas of primordial composition. To follow their interactions with the background gas, we construct a Monte Carlo model that includes: (1) electron-electron scattering (which transforms the electron kinetic energy into heat), (2) collisional ionization of hydrogen and helium (which produces secondary electrons that themselves scatter through the medium), and (3) collisional excitation (which produces secondary photons, whose fates we also follow approximately). For the last process, we explicitly include all transitions to upper levels n<=4, together with a well-motivated extrapolation to higher levels. In all cases, we use recent calculated cross-sections at E<1 keV and the Bethe approximation to extrapolate to higher energies. We compute the fractions of energy deposited as heat, ionization (tracking HI and the helium species separately), and excitation (tracking HI Lyman-alpha separately) under a broad range of conditions approp...

  9. Communication: Electron ionization of DNA bases

    Science.gov (United States)

    Rahman, M. A.; Krishnakumar, E.

    2016-04-01

    No reliable experimental data exist for the partial and total electron ionization cross sections for DNA bases, which are very crucial for modeling radiation damage in genetic material of living cell. We have measured a complete set of absolute partial electron ionization cross sections up to 500 eV for DNA bases for the first time by using the relative flow technique. These partial cross sections are summed to obtain total ion cross sections for all the four bases and are compared with the existing theoretical calculations and the only set of measured absolute cross sections. Our measurements clearly resolve the existing discrepancy between the theoretical and experimental results, thereby providing for the first time reliable numbers for partial and total ion cross sections for these molecules. The results on fragmentation analysis of adenine supports the theory of its formation in space.

  10. Shock Wave Dynamics in Weakly Ionized Plasmas

    Science.gov (United States)

    Johnson, Joseph A., III

    1999-01-01

    An investigation of the dynamics of shock waves in weakly ionized argon plasmas has been performed using a pressure ruptured shock tube. The velocity of the shock is observed to increase when the shock traverses the plasma. The observed increases cannot be accounted for by thermal effects alone. Possible mechanisms that could explain the anomalous behavior include a vibrational/translational relaxation in the nonequilibrium plasma, electron diffusion across the shock front resulting from high electron mobility, and the propagation of ion-acoustic waves generated at the shock front. Using a turbulence model based on reduced kinetic theory, analysis of the observed results suggest a role for turbulence in anomalous shock dynamics in weakly ionized media and plasma-induced hypersonic drag reduction.

  11. Upper Hybrid Effects in Artificial Ionization

    Science.gov (United States)

    Papadopoulos, K.; Eliasson, B. E.

    2014-12-01

    A most fascinating result of recent ionospheric experiments has been the discovery of artificial ionization by Pedersen et al. (GRL, 37, L02106, 2010). The Artificial Ionospheric Layers (AIL) were the result of F-region O-mode HF irradiation using the HAARP ionospheric heater operating at 3.6 MW power. As demonstrated by Eliasson et al. (JGR, 117, A10321, 2012) the physics controlling the observed phenomenon and its threshold can be summarized as: " Collisional ionization due to high energy (~ 20 eV) electron tails generated by the interaction of strong Langmuir turbulence with plasma heated at the upper hybrid resonance and transported at the reflection height". The objective of the current presentation is to explore the role of the upper hybrid heating in the formation of AIL and its implications to future experiments involving HF heaters operating in middle and equatorial latitudes.

  12. Ionization and Dust Charging in Protoplanetary Disks

    CERN Document Server

    Ivlev, A V; Caselli, P

    2016-01-01

    Ionization-recombination balance in dense interstellar and circumstellar environments is a key factor for a variety of important physical processes, such as chemical reactions, dust charging and coagulation, coupling of the gas with magnetic field and the development of magnetorotational instability in protoplanetary disks. We present a self-consistent analytical model which allows us to exactly calculate abundances of charged species in dusty gas, in the regime where the dust-phase recombination dominates over the gas-phase recombination. The model is employed to verify applicability of a conventional approximation of low dust charges in protoplanetary disks, and to discuss the implications for the dust coagulation and the development of the "dead zone" in the disk. Furthermore, the importance of mutually consistent models for the ionization and dust evolution is addressed: These processes are coupled via several mechanisms operating in the disk, and therefore their interplay can be crucial for the ultimate ...

  13. Electrostatic-spray ionization mass spectrometry.

    Science.gov (United States)

    Qiao, Liang; Sartor, Romain; Gasilova, Natalia; Lu, Yu; Tobolkina, Elena; Liu, Baohong; Girault, Hubert H

    2012-09-01

    An electrostatic-spray ionization (ESTASI) method has been used for mass spectrometry (MS) analysis of samples deposited in or on an insulating substrate. The ionization is induced by a capacitive coupling between an electrode and the sample. In practice, a metallic electrode is placed close to but not in direct contact with the sample. Upon application of a high voltage pulse to the electrode, an electrostatic charging of the sample occurs leading to a bipolar spray pulse. When the voltage is positive, the bipolar spray pulse consists first of cations and then of anions. This method has been applied to a wide range of geometries to emit ions from samples in a silica capillary, in a disposable pipet tip, in a polymer microchannel, or from samples deposited as droplets on a polymer plate. Fractions from capillary electrophoresis were collected on a polymer plate for ESTASI MS analysis. PMID:22876737

  14. HCO(+) ionization from SGR1806-20

    Science.gov (United States)

    Hannikainen, D.; Durouchoux, P.; Vilhu, O.; Huovelin, J.; Corbel, S.; Wallyn, P.

    1997-01-01

    The region surrounding the soft gamma ray repeater SGR 1806-20 in the HCO(+) (J = 1-0) transition was observed. Previous observations of compact Galactic objects suggest that a link exists between these objects and molecular clouds in which they are possibly embedded. Such a link would help explain some of the phenomena observed from these objects. A measure of the ionization rate as a function of distance from the source implies that the cloud is associated with the source. The abundance of HCO(+), which varies with increasing or decreasing ionization rates, is considered to be an ideal tool for this measurement. The observations acquired in the direction of the nebula surrounding SGR 1806-20 are presented, and the resulting 7 x 12 arcmin map derived from the HCO(+) data is shown.

  15. Communication: Electron ionization of DNA bases.

    Science.gov (United States)

    Rahman, M A; Krishnakumar, E

    2016-04-28

    No reliable experimental data exist for the partial and total electron ionization cross sections for DNA bases, which are very crucial for modeling radiation damage in genetic material of living cell. We have measured a complete set of absolute partial electron ionization cross sections up to 500 eV for DNA bases for the first time by using the relative flow technique. These partial cross sections are summed to obtain total ion cross sections for all the four bases and are compared with the existing theoretical calculations and the only set of measured absolute cross sections. Our measurements clearly resolve the existing discrepancy between the theoretical and experimental results, thereby providing for the first time reliable numbers for partial and total ion cross sections for these molecules. The results on fragmentation analysis of adenine supports the theory of its formation in space. PMID:27131520

  16. Multiphoton dissociative ionization of molecular deuterium

    International Nuclear Information System (INIS)

    The kinetic energy spectra of deuterium ions produced from D2 arising from collision-free subpicosecond irradiation at 248 nm with intensities spanning the 10/sup 13/--10/sup 16/-W/cm2 range have been measured by time-of-flight analysis. The behaviors of the kinetic energy distributions of the fragments and the relative abundances of atomic (D+) and molecular (D2+) ions reveal the presence of two mechanisms of multiphoton dissociative ionization. Calibration of the energy scale for D+ is facilitated by comparison with He/sup 2+/. For intensities in the 10/sup 13/--10/sup 15/-W/cm2 region, intermediate three-photon resonances and the optical Stark shift play important roles. At an intensity /similar to/0/sup 16/ W/cm2, a direct transition from the molecular ground state to the dissociative ionic level appears as a significant channel. No evidence of direct double ionization was observed

  17. Atomic tunneling ionization in a photon picture

    Science.gov (United States)

    Wang, Yujun; Esry, B. D.

    2015-05-01

    Above-threshold ionization (ATI) and high-harmonic generation (HHG) are studied by the photon-phase formalism in the tunneling regime. Different from the commonly used three-step model for understanding such strong-field phenomena, we show that each order of the ATI or HHG peaks is strongly associated with a single ``photon channel'' in the photon-phase picture. This simplicity allows an identification of pathways for each of the orders. This picture not only provides a convenient means to understand the electron dynamics in the strong field, but also gives insights that may help engineer laser pulses to manipulate the output of the ATI or HHG. We apply this method to quantify the strong-field-induced ionization threshold shift and study the carrier-envelope phase dependence of the HHG. Supported by the Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy

  18. Electrospray Ionization Mass Spectra of Dipeptide Derivatives

    Institute of Scientific and Technical Information of China (English)

    LUO, Zaigang; ZENG, Chengchu; YANG, Daoshan; HUANG, Yali; WANG, Fang; DU, Hongguang; HU, Liming

    2009-01-01

    Based on the structure of the HIV integrase core domain, dipeptide derivatives, as a type of HIV integrase in- hibitor, were synthesized, and their fragmentation pathways were investigated by electrospray ionization mass spec- trometry (ESI-MSN) in conjunction with tandem mass spectrometry (MS/MS). In order to better understand the fragmentation pathways, the MS2 and MS3 spectra of the title compound were obtained. The main fragmentation pathways occur by the cleavage of the C-CO bonds between N-(benzothiazol-2-yl)aminocarbonyl and methylene, NH-CO bonds between the NH groups and carbonyl groups. Electrospray ionization was proven to be a good method for the structural characterization and identification of this kind of compound.

  19. The electron-atom ionization problem

    Energy Technology Data Exchange (ETDEWEB)

    McCarthy, I.E.

    1995-02-01

    Methods of calculating electron-atom ionization as a three-body problem with Coulomb boundary conditions are considered. In the absence of a fully-valid computational method for a time-independent experiment the approximation is made that the incident electron experiences a screened potential. Approximations involving a final state that obeys the three-body Coulomb boundary condition are compared with the distorted-wave Born approximation and the convergent close-coupling method. 24 refs., 6 figs.

  20. Sputter-initiated resonance ionization spectroscopy

    International Nuclear Information System (INIS)

    A new technique, sputter-initiated resonance ionization spectroscopy (SIRIS), which provides an ultrasensitive analysis of solid samples for all elements except helium and neon is described in this paper. Sensitivities down to 1 part in 1012 should be available in routine SIRIS analysis, and greater sensitivities should be available for special cases. The basic concepts of this technology and early results in the development of the new SIRIS process and apparatus are presented. (Auth.)