WorldWideScience

Sample records for advanced petroleum-based fuels

  1. Investigation of Non-Petroleum Based Fuels

    Science.gov (United States)

    2005-09-01

    in-house HCCI engine and fuels program, and to develop a test plan for the 1.9-liter camless engine . Parties involved were Sturman Industries, VW...that Volkswagen’s previous HCCI research on the same engine would be used as a starting point for this work. Lawrence Livermore National Laboratory...was contacted about the capabilities of existing HCCI ignition and combustion models, for use in guiding the engine development work. 4 3.1

  2. Chemical Kinetic Modeling of Advanced Transportation Fuels

    Energy Technology Data Exchange (ETDEWEB)

    PItz, W J; Westbrook, C K; Herbinet, O

    2009-01-20

    Development of detailed chemical kinetic models for advanced petroleum-based and nonpetroleum based fuels is a difficult challenge because of the hundreds to thousands of different components in these fuels and because some of these fuels contain components that have not been considered in the past. It is important to develop detailed chemical kinetic models for these fuels since the models can be put into engine simulation codes used for optimizing engine design for maximum efficiency and minimal pollutant emissions. For example, these chemistry-enabled engine codes can be used to optimize combustion chamber shape and fuel injection timing. They also allow insight into how the composition of advanced petroleum-based and non-petroleum based fuels affect engine performance characteristics. Additionally, chemical kinetic models can be used separately to interpret important in-cylinder experimental data and gain insight into advanced engine combustion processes such as HCCI and lean burn engines. The objectives are: (1) Develop detailed chemical kinetic reaction models for components of advanced petroleum-based and non-petroleum based fuels. These fuels models include components from vegetable-oil-derived biodiesel, oil-sand derived fuel, alcohol fuels and other advanced bio-based and alternative fuels. (2) Develop detailed chemical kinetic reaction models for mixtures of non-petroleum and petroleum-based components to represent real fuels and lead to efficient reduced combustion models needed for engine modeling codes. (3) Characterize the role of fuel composition on efficiency and pollutant emissions from practical automotive engines.

  3. Advanced Petroleum-Based Fuels - Diesel Emissions Project (APBF-DEC): 2,000-Hour Performance of a NOx Adsorber Catalyst and Diesel Particle Filter System for a Medium-Duty, Pick-Up Diesel Engine Platform; Final Report

    Energy Technology Data Exchange (ETDEWEB)

    2007-03-01

    Presents the results of a 2,000-hour test of an emissions control system consisting of a nitrogen oxides adsorber catalyst in combination with a diesel particle filter, advanced fuels, and advanced engine controls in an SUV/pick-up truck vehicle platform.

  4. Synthesis of Petroleum-Based Fuel from Waste Plastics and Performance Analysis in a CI Engine

    Directory of Open Access Journals (Sweden)

    Christine Cleetus

    2013-01-01

    Full Text Available The present work involves the synthesis of a petroleum-based fuel by the catalytic pyrolysis of waste plastics. Catalytic pyrolysis involves the degradation of the polymeric materials by heating them in the absence of oxygen and in the presence of a catalyst. In the present study different oil samples are produced using different catalysts under different reaction conditions from waste plastics. The synthesized oil samples are subjected to a parametric study based on the oil yield, selectivity of the oil, fuel properties, and reaction temperature. Depending on the results from the above study, an optimization of the catalyst and reaction conditions was done. Gas chromatography-mass spectrometry of the selected optimized sample was done to find out its chemical composition. Finally, performance analysis of the selected oil sample was carried out on a compression ignition (CI engine. Polythene bags are selected as the source of waste plastics. The catalysts used for the study include silica, alumina, Y zeolite, barium carbonate, zeolite, and their combinations. The pyrolysis reaction was carried at polymer to catalyst ratio of 10 : 1. The reaction temperature ranges between 400°C and 550°C. The inert atmosphere for the pyrolysis was provided by using nitrogen as a carrier gas.

  5. Non-Petroleum-Based Fuels: Report on the Relationship Between Molecular Structure and Compression Ignition Fuels, Both Conventional and HCCI

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, Joshua [National Renewable Energy Lab. (NREL), Golden, CO (United States); McCormick, Robert [National Renewable Energy Lab. (NREL), Golden, CO (United States); Clark, Wendy [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2004-08-01

    The U.S. Department of Energy (DOE) is committed to increasing our nation’s energy security by decreasing our dependence on imported petroleum. The Fuels Technologies Subprogram within DOE’s Office of Freedom Car and Vehicle Technology (OFCVT) supports research that allows the United States to develop advanced fuels that enable efficient engines with low emissions. This document reports the completion of NREL FY 2004 Annual Operating Plan milestone 10.2: “Report on the relationship between molecular structure and compression ignition fuels, both conventional and HCCI.” This work is an incremental step toward the OFCVT Multi-Year Program Plan APBF/NPBF Milestone No. 3: “Establish fuel and lubricant constituents that are required for advanced combustion regime engines.”

  6. PM trend study for the 1998 - 2012 period: Impact of Transport and Petroleum-based Fuels in Santiago Chile

    Science.gov (United States)

    Castillo, M. A.; Jhun, I.; Moreno, F.; Oyola, P.; Koutrakis, P.

    2013-05-01

    Santiago is the capital city of Chile and the combination of adverse climatic and geographical conditions, a continuously growing vehicle fleet, and an increasing number of industries, has made Santiago one of the most polluted cities in South America, and has been declared saturated zone for PM10 since 1996. Although there have been important reductions in the PM emissions due the implementation of the "Atmospheric Prevention and Decontamination Plan for the Metropolitan Region" (PPDA) however the efforts have not been enough to meet the actual standards. Currently is approved a standard for PM2.5, where the annual average is 20 μg/m3 and daily average 24 hr is 50 μg/m3. One of the PM2.5 sources are the traffic emission and one of the measures targeted in PPDA has been to regulate this source. In the last 20 years two of the main interventions have been the elimination of Lead in gasoline (2001) and the steadily reduced diesel sulfur content from 5,000 to 50 ppm. In this study we analyzed 14 years of PM2.5 mass and species concentration time's series, from April 1998 to August 2012, elemental chemical analysis was made for approximately 60% of samples using XRF technique at DRI Lab (USA). One of the objectives is evaluate the impact of fuel-related interventions and petroleum-based fuels (PBFs) sales. When was analyzed de lead concentration we found that is present in the environment despite of that was eliminated of gasoline 20 years ago. We analyzed the impact of diesel sulfur on ambient sulfur content, and was constructed a model to verify the relationship between ambient sulfur and diesel sulfur content after controlling for other covariates. The relation between ambient concentration and diesel content sulfur is linear, when the reduction of sulfur in diesel was from 1500 to 50 ppm the concentration decreased from 1.59 to 1.08 μg/m3. To determinate the impact of PBFs sales (gasoline, kerosene, petroleum) on PM2.5 concentration, we estimated PM2

  7. 用于交通运输的石油基燃料(英文)%Petroleum-Based Fuels for Transport

    Institute of Scientific and Technical Information of China (English)

    Gautam KALGHATGI

    2015-01-01

    This paper is a review of global issues inlfuencing future transport fuels. Transport energy comes primarily from petroleum-based liquid fuels and wil continue to do so. The demand wil grow, mainly in developing countries and wil be heavily skewed towards diesel and jet fuel rather than gasoline. There wil be sufifcient oil supply to meet this growing demand over the next few decades. Future fuel properties wil also be affected by engine development trends which need to meet increasingly stringent requirements on efifciency, emissions, cost, and customer expectations. The optimum fuel for future spark ignition engines is gasoline with high RON (Research Octane Numbers) and/or low MON (Motor Octane Numbers) and for compression ignition engines, low octane or low cetane fuel. These changes wil require big investments by the reifning industry and wil increase the availability of low octane components. Therefore, it is important for auto and oil companies and other stakeholders to work together to develop highly efifcient engine/fuel systems which can use low octane fuels.%该文综述了影响世界未来交通燃料的问题。目前,交通能源主要来自石油基液体燃料,这一势头仍将持续。交通能源需求的未来增长,主要是在发展中国家,主要是柴油和航空燃油的增长,而不是汽油。未来几十年内石油供应充足,能够满足这种增长的需求。为了满足对效率、排放、成本和客户期望的日益严格的要求,发动机技术发展趋势将影响对未来燃料品质的要求。适合于未来火花点燃发动机的最佳燃料,是具有高的RON(研究法辛烷值)和低的MON(马达法辛烷值)的汽油;而适合压燃发动机的最佳燃料,是低辛烷值燃料或低十六烷值燃料。为满足这些变化,需要炼油企业巨额投资,并增加低辛烷值燃料组分。因此,十分重要的是,由汽车和石油公司及利益相关方来共同开发可以

  8. Advanced Fuels Campaign 2012 Accomplishments

    Energy Technology Data Exchange (ETDEWEB)

    Not Listed

    2012-11-01

    The Advanced Fuels Campaign (AFC) under the Fuel Cycle Research and Development (FCRD) program is responsible for developing fuels technologies to support the various fuel cycle options defined in the DOE Nuclear Energy Research and Development Roadmap, Report to Congress, April 2010. The fiscal year 2012 (FY 2012) accomplishments are highlighted below. Kemal Pasamehmetoglu is the National Technical Director for AFC.

  9. Metallic fuels for advanced reactors

    Science.gov (United States)

    Carmack, W. J.; Porter, D. L.; Chang, Y. I.; Hayes, S. L.; Meyer, M. K.; Burkes, D. E.; Lee, C. B.; Mizuno, T.; Delage, F.; Somers, J.

    2009-07-01

    In the framework of the Generation IV Sodium Fast Reactor Program, the Advanced Fuel Project has conducted an evaluation of the available fuel systems supporting future sodium cooled fast reactors. This paper presents an evaluation of metallic alloy fuels. Early US fast reactor developers originally favored metal alloy fuel due to its high fissile density and compatibility with sodium. The goal of fast reactor fuel development programs is to develop and qualify a nuclear fuel system that performs all of the functions of a conventional fast spectrum nuclear fuel while destroying recycled actinides. This will provide a mechanism for closure of the nuclear fuel cycle. Metal fuels are candidates for this application, based on documented performance of metallic fast reactor fuels and the early results of tests currently being conducted in US and international transmutation fuel development programs.

  10. Natural Gas for Advanced Dual-Fuel Combustion Strategies

    Science.gov (United States)

    Walker, Nicholas Ryan

    Natural gas fuels represent the next evolution of low-carbon energy feedstocks powering human activity worldwide. The internal combustion engine, the energy conversion device widely used by society for more than one century, is capable of utilizing advanced combustion strategies in pursuit of ultra-high efficiency and ultra-low emissions. Yet many emerging advanced combustion strategies depend upon traditional petroleum-based fuels for their operation. In this research the use of natural gas, namely methane, is applied to both conventional and advanced dual-fuel combustion strategies. In the first part of this work both computational and experimental studies are undertaken to examine the viability of utilizing methane as the premixed low reactivity fuel in reactivity controlled compression ignition, a leading advanced dual-fuel combustion strategy. As a result, methane is shown to be capable of significantly extending the load limits for dual-fuel reactivity controlled compression ignition in both light- and heavy-duty engines. In the second part of this work heavy-duty single-cylinder engine experiments are performed to research the performance of both conventional dual-fuel (diesel pilot ignition) and advanced dual-fuel (reactivity controlled compression ignition) combustion strategies using methane as the premixed low reactivity fuel. Both strategies are strongly influenced by equivalence ratio; diesel pilot ignition offers best performance at higher equivalence ratios and higher premixed methane ratios, whereas reactivity controlled compression ignition offers superior performance at lower equivalence ratios and lower premixed methane ratios. In the third part of this work experiments are performed in order to determine the dominant mode of heat release for both dual-fuel combustion strategies. By studying the dual-fuel homogeneous charge compression ignition and single-fuel spark ignition, strategies representative of autoignition and flame propagation

  11. Advanced thermally stable jet fuels

    Energy Technology Data Exchange (ETDEWEB)

    Schobert, H.H.

    1999-01-31

    The Pennsylvania State University program in advanced thermally stable coal-based jet fuels has five broad objectives: (1) Development of mechanisms of degradation and solids formation; (2) Quantitative measurement of growth of sub-micrometer and micrometer-sized particles suspended in fuels during thermal stressing; (3) Characterization of carbonaceous deposits by various instrumental and microscopic methods; (4) Elucidation of the role of additives in retarding the formation of carbonaceous solids; (5) Assessment of the potential of production of high yields of cycloalkanes by direct liquefaction of coal. Future high-Mach aircraft will place severe thermal demands on jet fuels, requiring the development of novel, hybrid fuel mixtures capable of withstanding temperatures in the range of 400--500 C. In the new aircraft, jet fuel will serve as both an energy source and a heat sink for cooling the airframe, engine, and system components. The ultimate development of such advanced fuels requires a thorough understanding of the thermal decomposition behavior of jet fuels under supercritical conditions. Considering that jet fuels consist of hundreds of compounds, this task must begin with a study of the thermal degradation behavior of select model compounds under supercritical conditions. The research performed by The Pennsylvania State University was focused on five major tasks that reflect the objectives stated above: Task 1: Investigation of the Quantitative Degradation of Fuels; Task 2: Investigation of Incipient Deposition; Task 3: Characterization of Solid Gums, Sediments, and Carbonaceous Deposits; Task 4: Coal-Based Fuel Stabilization Studies; and Task 5: Exploratory Studies on the Direct Conversion of Coal to High Quality Jet Fuels. The major findings of each of these tasks are presented in this executive summary. A description of the sub-tasks performed under each of these tasks and the findings of those studies are provided in the remainder of this volume

  12. ADVANCED FUELS CAMPAIGN 2013 ACCOMPLISHMENTS

    Energy Technology Data Exchange (ETDEWEB)

    Not Listed

    2013-10-01

    The mission of the Advanced Fuels Campaign (AFC) is to perform Research, Development, and Demonstration (RD&D) activities for advanced fuel forms (including cladding) to enhance the performance and safety of the nation’s current and future reactors; enhance proliferation resistance of nuclear fuel; effectively utilize nuclear energy resources; and address the longer-term waste management challenges. This includes development of a state-of-the art Research and Development (R&D) infrastructure to support the use of “goal-oriented science-based approach.” In support of the Fuel Cycle Research and Development (FCRD) program, AFC is responsible for developing advanced fuels technologies to support the various fuel cycle options defined in the Department of Energy (DOE) Nuclear Energy Research and Development Roadmap, Report to Congress, April 2010. Accomplishments made during fiscal year (FY) 2013 are highlighted in this report, which focuses on completed work and results. The process details leading up to the results are not included; however, the technical contact is provided for each section.

  13. Advanced Fuels Campaign Execution Plan

    Energy Technology Data Exchange (ETDEWEB)

    Kemal Pasamehmetoglu

    2011-09-01

    The purpose of the Advanced Fuels Campaign (AFC) Execution Plan is to communicate the structure and management of research, development, and demonstration (RD&D) activities within the Fuel Cycle Research and Development (FCRD) program. Included in this document is an overview of the FCRD program, a description of the difference between revolutionary and evolutionary approaches to nuclear fuel development, the meaning of science-based development of nuclear fuels, and the 'Grand Challenge' for the AFC that would, if achieved, provide a transformational technology to the nuclear industry in the form of a high performance, high reliability nuclear fuel system. The activities that will be conducted by the AFC to achieve success towards this grand challenge are described and the goals and milestones over the next 20 to 40 year period of research and development are established.

  14. Advanced Fuels Campaign Execution Plan

    Energy Technology Data Exchange (ETDEWEB)

    Kemal Pasamehmetoglu

    2010-10-01

    The purpose of the Advanced Fuels Campaign (AFC) Execution Plan is to communicate the structure and management of research, development, and demonstration (RD&D) activities within the Fuel Cycle Research and Development (FCRD) program. Included in this document is an overview of the FCRD program, a description of the difference between revolutionary and evolutionary approaches to nuclear fuel development, the meaning of science-based development of nuclear fuels, and the “Grand Challenge” for the AFC that would, if achieved, provide a transformational technology to the nuclear industry in the form of a high performance, high reliability nuclear fuel system. The activities that will be conducted by the AFC to achieve success towards this grand challenge are described and the goals and milestones over the next 20 to 40 year period of research and development are established.

  15. Advanced fuel chemistry for advanced engines.

    Energy Technology Data Exchange (ETDEWEB)

    Taatjes, Craig A.; Jusinski, Leonard E.; Zador, Judit; Fernandes, Ravi X.; Miller, James A.

    2009-09-01

    Autoignition chemistry is central to predictive modeling of many advanced engine designs that combine high efficiency and low inherent pollutant emissions. This chemistry, and especially its pressure dependence, is poorly known for fuels derived from heavy petroleum and for biofuels, both of which are becoming increasingly prominent in the nation's fuel stream. We have investigated the pressure dependence of key ignition reactions for a series of molecules representative of non-traditional and alternative fuels. These investigations combined experimental characterization of hydroxyl radical production in well-controlled photolytically initiated oxidation and a hybrid modeling strategy that linked detailed quantum chemistry and computational kinetics of critical reactions with rate-equation models of the global chemical system. Comprehensive mechanisms for autoignition generally ignore the pressure dependence of branching fractions in the important alkyl + O{sub 2} reaction systems; however we have demonstrated that pressure-dependent 'formally direct' pathways persist at in-cylinder pressures.

  16. Advanced Fuel Cycle Cost Basis

    Energy Technology Data Exchange (ETDEWEB)

    D. E. Shropshire; K. A. Williams; W. B. Boore; J. D. Smith; B. W. Dixon; M. Dunzik-Gougar; R. D. Adams; D. Gombert; E. Schneider

    2009-12-01

    This report, commissioned by the U.S. Department of Energy (DOE), provides a comprehensive set of cost data supporting a cost analysis for the relative economic comparison of options for use in the Advanced Fuel Cycle Initiative (AFCI) Program. The report describes the AFCI cost basis development process, reference information on AFCI cost modules, a procedure for estimating fuel cycle costs, economic evaluation guidelines, and a discussion on the integration of cost data into economic computer models. This report contains reference cost data for 25 cost modules—23 fuel cycle cost modules and 2 reactor modules. The cost modules were developed in the areas of natural uranium mining and milling, conversion, enrichment, depleted uranium disposition, fuel fabrication, interim spent fuel storage, reprocessing, waste conditioning, spent nuclear fuel (SNF) packaging, long-term monitored retrievable storage, near surface disposal of low-level waste (LLW), geologic repository and other disposal concepts, and transportation processes for nuclear fuel, LLW, SNF, transuranic, and high-level waste.

  17. Advanced Fuel Cycle Cost Basis

    Energy Technology Data Exchange (ETDEWEB)

    D. E. Shropshire; K. A. Williams; W. B. Boore; J. D. Smith; B. W. Dixon; M. Dunzik-Gougar; R. D. Adams; D. Gombert

    2007-04-01

    This report, commissioned by the U.S. Department of Energy (DOE), provides a comprehensive set of cost data supporting a cost analysis for the relative economic comparison of options for use in the Advanced Fuel Cycle Initiative (AFCI) Program. The report describes the AFCI cost basis development process, reference information on AFCI cost modules, a procedure for estimating fuel cycle costs, economic evaluation guidelines, and a discussion on the integration of cost data into economic computer models. This report contains reference cost data for 26 cost modules—24 fuel cycle cost modules and 2 reactor modules. The cost modules were developed in the areas of natural uranium mining and milling, conversion, enrichment, depleted uranium disposition, fuel fabrication, interim spent fuel storage, reprocessing, waste conditioning, spent nuclear fuel (SNF) packaging, long-term monitored retrievable storage, near surface disposal of low-level waste (LLW), geologic repository and other disposal concepts, and transportation processes for nuclear fuel, LLW, SNF, and high-level waste.

  18. Advanced Fuel Cycle Cost Basis

    Energy Technology Data Exchange (ETDEWEB)

    D. E. Shropshire; K. A. Williams; W. B. Boore; J. D. Smith; B. W. Dixon; M. Dunzik-Gougar; R. D. Adams; D. Gombert; E. Schneider

    2008-03-01

    This report, commissioned by the U.S. Department of Energy (DOE), provides a comprehensive set of cost data supporting a cost analysis for the relative economic comparison of options for use in the Advanced Fuel Cycle Initiative (AFCI) Program. The report describes the AFCI cost basis development process, reference information on AFCI cost modules, a procedure for estimating fuel cycle costs, economic evaluation guidelines, and a discussion on the integration of cost data into economic computer models. This report contains reference cost data for 25 cost modules—23 fuel cycle cost modules and 2 reactor modules. The cost modules were developed in the areas of natural uranium mining and milling, conversion, enrichment, depleted uranium disposition, fuel fabrication, interim spent fuel storage, reprocessing, waste conditioning, spent nuclear fuel (SNF) packaging, long-term monitored retrievable storage, near surface disposal of low-level waste (LLW), geologic repository and other disposal concepts, and transportation processes for nuclear fuel, LLW, SNF, transuranic, and high-level waste.

  19. Advanced fuels for thermal spectrum reactors

    OpenAIRE

    Zakova, Jitka

    2012-01-01

    The advanced fuels investigated in this thesis comprise fuels non− conventional in their design/form (TRISO), their composition (high content of plutonium and minor actinides) or their use in a reactor type, in which they have not been used before (e.g. nitride fuel in BWR). These fuels come with a promise of improved characteristics such as safe, high temperature operation, spent fuel transmutation or fuel cycle extension, for which reasons their potentialis worth assessment and investigatio...

  20. Advanced research reactor fuel development

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Chang Kyu; Pak, H. D.; Kim, K. H. [and others

    2000-05-01

    -plates will be conducted in the Advanced Test Reactor(ATR). 49 compacts with a uranium density of 8 gU/cc consist of 7 different atomized uranium-molybdenum alloy powders. The tensile strength increased and the elongation decreased with increasing the volume fraction of U-10Mo powders in dispersion fuel. The tensile strength was lower and elongation was larger in dispersion fuel using atomized U-10Mo powders than that using comminuted fuel powders. The green strength of the comminuted powder compacts was about twice as large as that of the atomized powder compacts. It is suggested that the compacting condition required to fabricate the atomized powder compacts is over the 350MPa. The comminuted irregular shaped particles and smaller particle size of fuel powders showed improved homogeneity of powder mixture. The homogeneity of powder mixtures increased to a minimum at approximately 0.10 wt% moisture and then decreased with moisture content.

  1. Advanced Fuels Campaign FY 2015 Accomplishments Report

    Energy Technology Data Exchange (ETDEWEB)

    Braase, Lori Ann [Idaho National Lab. (INL), Idaho Falls, ID (United States); Carmack, William Jonathan [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-10-29

    The mission of the Advanced Fuels Campaign (AFC) is to perform research, development, and demonstration (RD&D) activities for advanced fuel forms (including cladding) to enhance the performance and safety of the nation’s current and future reactors; enhance proliferation resistance of nuclear fuel; effectively utilize nuclear energy resources; and address the longer-term waste management challenges. This report is a compilation of technical accomplishment summaries for FY-15. Emphasis is on advanced accident-tolerant LWR fuel systems, advanced transmutation fuels technologies, and capability development.

  2. Uncertainty Analyses of Advanced Fuel Cycles

    Energy Technology Data Exchange (ETDEWEB)

    Laurence F. Miller; J. Preston; G. Sweder; T. Anderson; S. Janson; M. Humberstone; J. MConn; J. Clark

    2008-12-12

    The Department of Energy is developing technology, experimental protocols, computational methods, systems analysis software, and many other capabilities in order to advance the nuclear power infrastructure through the Advanced Fuel Cycle Initiative (AFDI). Our project, is intended to facilitate will-informed decision making for the selection of fuel cycle options and facilities for development.

  3. Advanced Fuels Campaign FY 2014 Accomplishments Report

    Energy Technology Data Exchange (ETDEWEB)

    Braase, Lori [Idaho National Lab. (INL), Idaho Falls, ID (United States). INL Systems Analyses; May, W. Edgar [Idaho National Lab. (INL), Idaho Falls, ID (United States). INL Systems Analyses

    2014-10-01

    The mission of the Advanced Fuels Campaign (AFC) is to perform Research, Development, and Demonstration (RD&D) activities for advanced fuel forms (including cladding) to enhance the performance and safety of the nation’s current and future reactors; enhance proliferation resistance of nuclear fuel; effectively utilize nuclear energy resources; and address the longer-term waste management challenges. This includes development of a state-of-the art Research and Development (R&D) infrastructure to support the use of a “goal-oriented science-based approach.” In support of the Fuel Cycle Research and Development (FCRD) program, AFC is responsible for developing advanced fuels technologies to support the various fuel cycle options defined in the Department of Energy (DOE) Nuclear Energy Research and Development Roadmap, Report to Congress, April 2010. AFC uses a “goal-oriented, science-based approach” aimed at a fundamental understanding of fuel and cladding fabrication methods and performance under irradiation, enabling the pursuit of multiple fuel forms for future fuel cycle options. This approach includes fundamental experiments, theory, and advanced modeling and simulation. The modeling and simulation activities for fuel performance are carried out under the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program, which is closely coordinated with AFC. In this report, the word “fuel” is used generically to include fuels, targets, and their associated cladding materials. R&D of light water reactor (LWR) fuels with enhanced accident tolerance is also conducted by AFC. These fuel systems are designed to achieve significantly higher fuel and plant performance to allow operation to significantly higher burnup, and to provide enhanced safety during design basis and beyond design basis accident conditions. The overarching goal is to develop advanced nuclear fuels and materials that are robust, have high performance capability, and are more tolerant to

  4. Advanced Fuels Campaign FY 2011 Accomplishments Report

    Energy Technology Data Exchange (ETDEWEB)

    Not Listed

    2011-11-01

    One of the major research and development (R&D) areas under the Fuel Cycle Research and Development (FCRD) program is advanced fuels development. The Advanced Fuels Campaign (AFC) has the responsibility to develop advanced fuel technologies for the Department of Energy (DOE) using a science-based approach focusing on developing a microstructural understanding of nuclear fuels and materials. Accomplishments made during fiscal year (FY 20) 2011 are highlighted in this report, which focuses on completed work and results. The process details leading up to the results are not included; however, the technical contact is provided for each section. The order of the accomplishments in this report is consistent with the AFC work breakdown structure (WBS).

  5. Verification tests for CANDU advanced fuel

    Energy Technology Data Exchange (ETDEWEB)

    Chung, Chang Hwan; Chang, S.K.; Hong, S.D. [and others

    1997-07-01

    For the development of a CANDU advanced fuel, the CANFLEX-NU fuel bundles were tested under reactor operating conditions at the CANDU-Hot test loop. This report describes test results and test methods in the performance verification tests for the CANFLEX-NU bundle design. The main items described in the report are as follows. - Fuel bundle cross-flow test - Endurance fretting/vibration test - Freon CHF test - Production of technical document. (author). 25 refs., 45 tabs., 46 figs.

  6. Advanced Fuels Campaign FY 2010 Accomplishments Report

    Energy Technology Data Exchange (ETDEWEB)

    Lori Braase

    2010-12-01

    The Fuel Cycle Research and Development (FCRD) Advanced Fuels Campaign (AFC) Accomplishment Report documents the high-level research and development results achieved in fiscal year 2010. The AFC program has been given responsibility to develop advanced fuel technologies for the Department of Energy (DOE) using a science-based approach focusing on developing a microstructural understanding of nuclear fuels and materials. The science-based approach combines theory, experiments, and multi-scale modeling and simulation aimed at a fundamental understanding of the fuel fabrication processes and fuel and clad performance under irradiation. The scope of the AFC includes evaluation and development of multiple fuel forms to support the three fuel cycle options described in the Sustainable Fuel Cycle Implementation Plan4: Once-Through Cycle, Modified-Open Cycle, and Continuous Recycle. The word “fuel” is used generically to include fuels, targets, and their associated cladding materials. This document includes a brief overview of the management and integration activities; but is primarily focused on the technical accomplishments for FY-10. Each technical section provides a high level overview of the activity, results, technical points of contact, and applicable references.

  7. Advanced Fuels Campaign Cladding & Coatings Meeting Summary

    Energy Technology Data Exchange (ETDEWEB)

    Not Listed

    2013-03-01

    The Fuel Cycle Research and Development (FCRD) Advanced Fuels Campaign (AFC) organized a Cladding and Coatings operational meeting February 12-13, 2013, at Oak Ridge National Laboratory (ORNL). Representatives from the U.S. Department of Energy (DOE), national laboratories, industry, and universities attended the two-day meeting. The purpose of the meeting was to discuss advanced cladding and cladding coating research and development (R&D); review experimental testing capabilities for assessing accident tolerant fuels; and review industry/university plans and experience in light water reactor (LWR) cladding and coating R&D.

  8. Biofuels Fuels Technology Pathway Options for Advanced Drop-in Biofuels Production

    Energy Technology Data Exchange (ETDEWEB)

    Kevin L Kenney

    2011-09-01

    Advanced drop-in hydrocarbon biofuels require biofuel alternatives for refinery products other than gasoline. Candidate biofuels must have performance characteristics equivalent to conventional petroleum-based fuels. The technology pathways for biofuel alternatives also must be plausible, sustainable (e.g., positive energy balance, environmentally benign, etc.), and demonstrate a reasonable pathway to economic viability and end-user affordability. Viable biofuels technology pathways must address feedstock production and environmental issues through to the fuel or chemical end products. Potential end products include compatible replacement fuel products (e.g., gasoline, diesel, and JP8 and JP5 jet fuel) and other petroleum products or chemicals typically produced from a barrel of crude. Considering the complexity and technology diversity of a complete biofuels supply chain, no single entity or technology provider is capable of addressing in depth all aspects of any given pathway; however, all the necessary expert entities exist. As such, we propose the assembly of a team capable of conducting an in-depth technology pathway options analysis (including sustainability indicators and complete LCA) to identify and define the domestic biofuel pathways for a Green Fleet. This team is not only capable of conducting in-depth analyses on technology pathways, but collectively they are able to trouble shoot and/or engineer solutions that would give industrial technology providers the highest potential for success. Such a team would provide the greatest possible down-side protection for high-risk advanced drop-in biofuels procurement(s).

  9. Future Transient Testing of Advanced Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Jon Carmack

    2009-09-01

    The transient in-reactor fuels testing workshop was held on May 4–5, 2009 at Idaho National Laboratory. The purpose of this meeting was to provide a forum where technical experts in transient testing of nuclear fuels could meet directly with technical instrumentation experts and nuclear fuel modeling and simulation experts to discuss needed advancements in transient testing to support a basic understanding of nuclear fuel behavior under off-normal conditions. The workshop was attended by representatives from Commissariat à l'Énergie Atomique CEA, Japanese Atomic Energy Agency (JAEA), Department of Energy (DOE), AREVA, General Electric – Global Nuclear Fuels (GE-GNF), Westinghouse, Electric Power Research Institute (EPRI), universities, and several DOE national laboratories. Transient testing of fuels and materials generates information required for advanced fuels in future nuclear power plants. Future nuclear power plants will rely heavily on advanced computer modeling and simulation that describes fuel behavior under off-normal conditions. TREAT is an ideal facility for this testing because of its flexibility, proven operation and material condition. The opportunity exists to develop advanced instrumentation and data collection that can support modeling and simulation needs much better than was possible in the past. In order to take advantage of these opportunities, test programs must be carefully designed to yield basic information to support modeling before conducting integral performance tests. An early start of TREAT and operation at low power would provide significant dividends in training, development of instrumentation, and checkout of reactor systems. Early start of TREAT (2015) is needed to support the requirements of potential users of TREAT and include the testing of full length fuel irradiated in the FFTF reactor. The capabilities provided by TREAT are needed for the development of nuclear power and the following benefits will be realized by

  10. Advanced fuel hydrocarbon remediation national test location - biocell treatment of petroleum contaminated soils

    Energy Technology Data Exchange (ETDEWEB)

    Heath, J.; Lory, E.

    1997-03-01

    Biocells are engineered systems that use naturally occurring microbes to degrade fuels and oils into simpler, nonhazardous, and nontoxic compounds. Biocells are able to treat soils contaminated with petroleum based fuels and lubricants, including diesel, jet fuel, and lubricating and hydraulic oils. The microbes use the contaminants as a food source and thus destroy them. By carefully monitoring and controlling air and moisture levels, degradation rates can be increased and total treatment time reduced over natural systems.

  11. Computational Design of Advanced Nuclear Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Savrasov, Sergey [Univ. of California, Davis, CA (United States); Kotliar, Gabriel [Rutgers Univ., Piscataway, NJ (United States); Haule, Kristjan [Rutgers Univ., Piscataway, NJ (United States)

    2014-06-03

    The objective of the project was to develop a method for theoretical understanding of nuclear fuel materials whose physical and thermophysical properties can be predicted from first principles using a novel dynamical mean field method for electronic structure calculations. We concentrated our study on uranium, plutonium, their oxides, nitrides, carbides, as well as some rare earth materials whose 4f eletrons provide a simplified framework for understanding complex behavior of the f electrons. We addressed the issues connected to the electronic structure, lattice instabilities, phonon and magnon dynamics as well as thermal conductivity. This allowed us to evaluate characteristics of advanced nuclear fuel systems using computer based simulations and avoid costly experiments.

  12. Nanocomposites for advanced fuel cell technology.

    Science.gov (United States)

    Zhu, Bin

    2011-10-01

    NANOCOFC (Nanocomposites for advanced fuel cell technology) is a research platform/network established based on the FP6 EC-China project www.nanocofc.org. This paper reviews major achievements on two-phase nanocomposites for advanced low temperature (300-600 degrees C) solid oxide fuel cells (SOFCs), where the ceria-salt and ceria-oxide composites are common. A typical functional nanocomposite structure is a core-shell type, in which the ceria forms a core and the salt or another oxide form the shell layer. Both of them are in the nano-scale and the functional components. The high resolution TEM analysis has proven a clear interface in the ceria-based two-phase nanocomposites. Such interface and interfacial function has resulted in superionic conductivity, above 0.1 S/cm at around 300 degrees C, being comparable to that of conventional SOFC YSZ at 1000 degrees C. Against conventional material design from the structure the advanced nanocomposites are designed by non-structure factors, i.e., the interfaces, and by creating interfacial functionalities between the two constituent phases. These new functional materials show indeed a breakthrough in the SOFC materials with great potential.

  13. Evolutionary developments of advanced PWR nuclear fuels and cladding materials

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kyu-Tae, E-mail: ktkim@dongguk.ac.kr

    2013-10-15

    Highlights: • PWR fuel and cladding materials development processes are provided. • Evolution of PWR advanced fuel in U.S.A. and in Korea is described. • Cutting-edge design features against grid-to-rod fretting and debris are explained. • High performance data of advanced grids, debris filters and claddings are given. -- Abstract: The evolutionary developments of advanced PWR fuels and cladding materials are explained with outstanding design features of nuclear fuel assembly components and zirconium-base cladding materials. The advanced PWR fuel and cladding materials development processes are also provided along with verification tests, which can be used as guidelines for newcomers planning to develop an advanced fuel for the first time. The up-to-date advanced fuels with the advanced cladding materials may provide a high level of economic utilization and reliable performance even under current and upcoming aggressive operating conditions. To be specific, nuclear fuel vendors may achieve high fuel burnup capability of between 45,000 and 65,000 MWD/MTU batch average, overpower thermal margin of as much as 15% and longer cycle length up to 24 months on the one hand and fuel failure rates of around 10{sup −6} on the other hand. However, there is still a need for better understanding of grid-to-rod fretting wear mechanisms leading to major PWR fuel defects in the world and subsequently a driving force for developing innovative spacer grid designs with zero fretting wear-induced fuel failure.

  14. Advanced Coal-Fueled Gas Turbine Program

    Energy Technology Data Exchange (ETDEWEB)

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  15. Conceptual design study of advanced fuel fabrication systems

    Energy Technology Data Exchange (ETDEWEB)

    Ken-ya, Tanaka; Shusaku, Kono; Kiyoshi, Ono [Japan Nuclear Cycle Development JNC, Fuel Fabrication System Group, O-Arai Engineering Center, Ibaraki (Japan)

    2001-07-01

    The fuel fabrication plant images based on the advanced equipment with availability to operate in hot-cell facility are constructed. The characteristics of each fuel fabrication system for economical and environmental are evaluated roughly. The advanced fuel fabrication routes such as simplified pelletizing, vibration compaction and casting process would have the potential for reducing plant construction cost and minimizing the radioactive waste generated from fuel fabrication process. (author)

  16. IEA-Advanced Motor Fuels Annual Report 2010

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-12-02

    The annual report from the IEA implementing agreement on Advanced Motor Fuels (AMF) describes the agreement, activities, and projects for the year. A section on the global situation for Advanced Motor Fuels includes country reports from each participating AMF member. A status report on each active annex for the agreement is also included, as is a message from the AMF Chairman. Final sections include an Outlook for Advanced Motor Fuels, further information, and a glossary of terms.

  17. Advanced membrane electrode assemblies for fuel cells

    Science.gov (United States)

    Kim, Yu Seung; Pivovar, Bryan S

    2014-02-25

    A method of preparing advanced membrane electrode assemblies (MEA) for use in fuel cells. A base polymer is selected for a base membrane. An electrode composition is selected to optimize properties exhibited by the membrane electrode assembly based on the selection of the base polymer. A property-tuning coating layer composition is selected based on compatibility with the base polymer and the electrode composition. A solvent is selected based on the interaction of the solvent with the base polymer and the property-tuning coating layer composition. The MEA is assembled by preparing the base membrane and then applying the property-tuning coating layer to form a composite membrane. Finally, a catalyst is applied to the composite membrane.

  18. Advanced-capability alkaline fuel cell powerplant

    Science.gov (United States)

    Deronck, Henry J.

    The alkaline fuel cell powerplant utilized in the Space Shuttle Orbiter has established an excellent performance and reliability record over the past decade. Recent AFC technology programs have demonstrated significant advances in cell durability and power density. These capabilities provide the basis for substantial improvement of the Orbiter powerplant, enabling new mission applications as well as enhancing performance in the Orbiter. Improved durability would extend the powerplant's time between overhaul fivefold, and permit longer-duration missions. The powerplant would also be a strong candidate for lunar/planetary surface power systems. Higher power capability would enable replacement of the Orbiter's auxiliary power units with electric motors, and benefits mass-critical applications such as the National AeroSpace Plane.

  19. Advanced methods of solid oxide fuel cell modeling

    CERN Document Server

    Milewski, Jaroslaw; Santarelli, Massimo; Leone, Pierluigi

    2011-01-01

    Fuel cells are widely regarded as the future of the power and transportation industries. Intensive research in this area now requires new methods of fuel cell operation modeling and cell design. Typical mathematical models are based on the physical process description of fuel cells and require a detailed knowledge of the microscopic properties that govern both chemical and electrochemical reactions. ""Advanced Methods of Solid Oxide Fuel Cell Modeling"" proposes the alternative methodology of generalized artificial neural networks (ANN) solid oxide fuel cell (SOFC) modeling. ""Advanced Methods

  20. Advanced Combustion and Fuels; NREL (National Renewable Energy Laboratory)

    Energy Technology Data Exchange (ETDEWEB)

    Zigler, Brad

    2015-06-08

    Presented at the U.S. Department of Energy Vehicle Technologies Office 2015 Annual Merit Review and Peer Evaluation Meeting, held June 8-12, 2015, in Arlington, Virginia. It addresses technical barriers of inadequate data and predictive tools for fuel and lubricant effects on advanced combustion engines, with the strategy being through collaboration, develop techniques, tools, and data to quantify critical fuel physico-chemical effects to enable development of advanced combustion engines that use alternative fuels.

  1. CANDU RU fuel manufacturing basic technology development and advanced fuel verification tests

    Energy Technology Data Exchange (ETDEWEB)

    Chung, Chang Hwan; Chang, S.K.; Hong, S.D. [and others

    1999-04-01

    A PHWR advanced fuel named the CANFLEX fuel has been developed through a KAERI/AECL joint Program. The KAERI made fuel bundle was tested at the KAERI Hot Test Loop for the performance verification of the bundle design. The major test activities were the fuel bundle cross-flow test, the endurance fretting/vibration test, the freon CHF test, and the fuel bundle heat-up test. KAERI also has developing a more advanced PHWR fuel, the CANFLEX-RU fuel, using recovered uranium to extend fuel burn-up in the CANDU reactors. For the purpose of proving safety of the RU handling techniques and appraising feasibility of the CANFLEX-RU fuel fabrication in near future, a physical, chemical and radiological characterization of the RU powder and pellets was performed. (author). 54 refs., 46 tabs., 62 figs.

  2. Status of advanced carbide fuels: Past, present, and future

    Science.gov (United States)

    Anghaie, Samim; Knight, Travis

    2002-01-01

    Solid solution, mixed uranium/refractory metal carbide fuels such as (U, Zr, Nb)C, so called ternary carbide or tri-carbide fuels have great potential for applications in next generation advanced nuclear power reactors. Because of their high melting points, high thermal conductivity, improved resistance to hot hydrogen corrosion, and good fission product retention, these advanced nuclear fuels have great potential for high performance reactors with increased safety margins. Despite these many benefits, some concerns regarding carbide fuels include compatibility issues with coolant and/or cladding materials and their endurance under the extreme conditions associated with nuclear thermal propulsion. The status of these fuels is reviewed to characterize their performance for space nuclear power applications. Results of current investigations are presented and as well as future directions of study for these advanced nuclear fuels. .

  3. Development of advanced LWR fuel cladding

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Yong Hwan; Park, S. Y.; Lee, M. H. [and others

    2000-04-01

    This report describes the results from evaluating the preliminary Zr-based alloys to develop the advanced Zr-based alloys for the nuclear fuel claddings, which should have good corrosion resistance and mechanical properties at high burn-up over 70,000MWD/MTU. It also includes the results from the basic studies for optimizing the processes which are involved in the development of the advanced Zr-based alloys. Ten(10) kinds of candidates for the alloys of which performance is over that of the existing Zircaloy-4 or ZIRLO alloy were selected out of the preliminary alloys of 150 kinds which were newly designed and repeatedly manufactured and evaluated to find out the promising alloys. First of all, the corrosion tests on the preliminary alloys were carried out to evaluate their performance in both pure water and LiOH solution at 360 deg C and in steam at 400 deg C. The tensile tests were performed on the alloys which proved to be good in the corrosion resistance. The creep behaviors were tested at 400 deg C for 10 days with the application of constant load on the samples which showed good performance in the corrosion resistance and tensile properties. The effect of the final heat treatment and A-parameters as well as Sn or Nb on the corrosion resistance, tensile properties, hardness, microstructures of the alloys was evaluated for some alloys interested. The other basic researches on the oxides, electrochemical properties, corrosion mechanism, and the establishment of the phase diagrams of some alloys were also carried out.

  4. Mitsubishi PWR nuclear fuel with advanced design features

    Energy Technology Data Exchange (ETDEWEB)

    Kaua Goe, Toshiy Uki; Nuno kawa, Koi Chi [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan)

    2008-10-15

    In the last few decades, the global warming has been a big issue. As the breakthrough in this crisis, advanced operations of the water reactor such as higher burn up, longer cycle, and up rating could be effective ways. From this viewpoint, Mitsubishi Heavy Industries (MHI) has developed the fuel for burn up extension, whose assembly burn-up limit is 55GWd/t(A), with the original and advanced designs such as corrosion resistant cladding material MDA, and supplied to Japanese PWR utilities. On the other hand, MHI intends to supply more advanced fuel assemblies not only to domestic market but to the global market. Actually MHI has submitted the application for standard design certification of USA . Advanced Pressurized Water Reactor on Jan. 2nd 2008. The fuel assembly for US APWR is 17x17 type with active fuel length of 14ft, characterized with three features, to {sup E}nhance Fuel Economy{sup ,} {sup E}nable Flexible Core Operation{sup ,} and to {sup I}mprove Reliability{sup .} MHI has also been conducting development activities for more advanced products, such as 70GWd/t(A) burn up limit fuel with cladding, guide thimble and spacer grid made from M-MDATM alloy that is new material with higher corrosion resistance, such as 12ft and 14ft active length fuel, such as fuel with countermeasure against grid fretting, debris fretting, and IRI. MHI will present its activities and advanced designs.

  5. Development of Advanced Spent Fuel Management Process

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Chung Seok; Choi, I. K.; Kwon, S. G. (and others)

    2007-06-15

    As a part of research efforts to develop an advanced spent fuel management process, this project focused on the electrochemical reduction technology which can replace the original Li reduction technology of ANL, and we have successfully built a 20 kgHM/batch scale demonstration system. The performance tests of the system in the ACPF hot cell showed more than a 99% reduction yield of SIMFUEL, a current density of 100 mA/cm{sup 2} and a current efficiency of 80%. For an optimization of the process, the prevention of a voltage drop in an integrated cathode, a minimization of the anodic effect and an improvement of the hot cell operability by a modulation and simplization of the unit apparatuses were achieved. Basic research using a bench-scale system was also carried out by focusing on a measurement of the electrochemical reduction rate of the surrogates, an elucidation of the reaction mechanism, collecting data on the partition coefficients of the major nuclides, quantitative measurement of mass transfer rates and diffusion coefficients of oxygen and metal ions in molten salts. When compared to the PYROX process of INL, the electrochemical reduction system developed in this project has comparative advantages in its application of a flexible reaction mechanism, relatively short reaction times and increased process yields.

  6. Advanced Fuel Cell System Thermal Management for NASA Exploration Missions

    Science.gov (United States)

    Burke, Kenneth A.

    2009-01-01

    The NASA Glenn Research Center is developing advanced passive thermal management technology to reduce the mass and improve the reliability of space fuel cell systems for the NASA exploration program. An analysis of a state-of-the-art fuel cell cooling systems was done to benchmark the portion of a fuel cell system s mass that is dedicated to thermal management. Additional analysis was done to determine the key performance targets of the advanced passive thermal management technology that would substantially reduce fuel cell system mass.

  7. Advanced Safeguards Approaches for New TRU Fuel Fabrication Facilities

    Energy Technology Data Exchange (ETDEWEB)

    Durst, Philip C.; Ehinger, Michael H.; Boyer, Brian; Therios, Ike; Bean, Robert; Dougan, A.; Tolk, K.

    2007-12-15

    This second report in a series of three reviews possible safeguards approaches for the new transuranic (TRU) fuel fabrication processes to be deployed at AFCF – specifically, the ceramic TRU (MOX) fuel fabrication line and the metallic (pyroprocessing) line. The most common TRU fuel has been fuel composed of mixed plutonium and uranium dioxide, referred to as “MOX”. However, under the Advanced Fuel Cycle projects custom-made fuels with higher contents of neptunium, americium, and curium may also be produced to evaluate if these “minor actinides” can be effectively burned and transmuted through irradiation in the ABR. A third and final report in this series will evaluate and review the advanced safeguards approach options for the ABR. In reviewing and developing the advanced safeguards approach for the new TRU fuel fabrication processes envisioned for AFCF, the existing international (IAEA) safeguards approach at the Plutonium Fuel Production Facility (PFPF) and the conceptual approach planned for the new J-MOX facility in Japan have been considered as a starting point of reference. The pyro-metallurgical reprocessing and fuel fabrication process at EBR-II near Idaho Falls also provided insight for safeguarding the additional metallic pyroprocessing fuel fabrication line planned for AFCF.

  8. Advanced Fuels Campaign FY 2014 Accomplishments Report

    Energy Technology Data Exchange (ETDEWEB)

    Lori Braase; W. Edgar May

    2014-10-01

    The overall goal of ATF development is to identify alternative fuel system technologies to further enhance the safety, competitiveness, and economics of commercial nuclear power. The complex multiphysics behavior of LWR nuclear fuel in the integrated reactor system makes defining specific material or design improvements difficult; as such, establishing desirable performance attributes is critical in guiding the design and development of fuels and cladding with enhanced accident tolerance.

  9. Basic research and industrialization of CANDU advanced fuel

    Energy Technology Data Exchange (ETDEWEB)

    Chun, Suk Ho; Park, Joo Hwan; Jun, Ji Su [and others

    2000-04-01

    Wolsong Unit 1 as the first heavy water reactor in Korea has been in service for 17 years since 1983. It would be about the time to prepare a plan for the solution of problems due to aging of the reactor. The aging of CANDU reactor could lead especially to the steam generator cruding and pressure tube sagging and creep and then decreases the operation margin to make some problems on reactor operations and safety. The counterplan could be made in two ways. One is to repair or modify reactor itself. The other is to develop new advanced fuel to increase of CANDU operation margin effectively, so as to compensate the reduced operation margin. Therefore, the first objectives in the present R and D is to develop the CANFLEX-NU (CANDU Flexible fuelling-Natural Uranium) fuel as a CANDU advanced fuel. The second objectives is to develop CANDU advanced fuel bundle to utilize advanced fuel cycles such as recovered uranium, slightly enriched uranium, etc. and so to raise adaptability for change in situation of uranium market. Also, it is to develop CANDU advanced fuel technology which improve uranium utilization to cope with a world-wide imbalance between uranium supply and demand, without significant modification of nuclear reactor design and refuelling strategies. As the implementations to achieve the above R and D goal, the work contents and scope of technology development of CANDU advanced fuel using natural uranium (CANFLEX-NU) are the fuel element/bundle designs, the nuclear design and fuel management analysis, the thermalhydraulic analysis, the safety analysis, fuel fabrication technologies, the out-pile thermalhydraulic test and in-pile irradiation tests performed. At the next, the work scopes and contents of feasibility study of CANDU advanced fuel using recycled uranium (CANFLEX-RU) are the fuel element/bundle designs, the reactor physics analysis, the thermalhydraulic analysis, the basic safety analysis of a CANDU-6 reactor with CANFLEX-RU fuel, the fabrication and

  10. Development of advanced mixed oxide fuels for plutonium management

    Energy Technology Data Exchange (ETDEWEB)

    Eaton, S.; Beard, C.; Buksa, J.; Butt, D.; Chidester, K.; Havrilla, G.; Ramsey, K.

    1997-06-01

    A number of advanced Mixed Oxide (MOX) fuel forms are currently being investigated at Los Alamos National Laboratory that have the potential to be effective plutonium management tools. Evolutionary Mixed Oxide (EMOX) fuel is a slight perturbation on standard MOX fuel, but achieves greater plutonium destruction rates by employing a fractional nonfertile component. A pure nonfertile fuel is also being studied. Initial calculations show that the fuel can be utilized in existing light water reactors and tailored to address different plutonium management goals (i.e., stabilization or reduction of plutonium inventories residing in spent nuclear fuel). In parallel, experiments are being performed to determine the feasibility of fabrication of such fuels. Initial EMOX pellets have successfully been fabricated using weapons-grade plutonium.

  11. 40 CFR 600.206-08 - Calculation and use of FTP-based and HFET-based fuel economy values for vehicle configurations.

    Science.gov (United States)

    2010-07-01

    ... natural gas test fuel. (b) If only one equivalent petroleum-based fuel economy value exists for an... petroleum-based fuel economy for that configuration. (c) If more than one equivalent petroleum-based fuel... HFET-based fuel economy values for vehicle configurations. 600.206-08 Section 600.206-08 Protection...

  12. Ultraclean Fuels Production and Utilization for the Twenty-First Century: Advances toward Sustainable Transportation Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Fox, Elise B.; Liu, Zhong-Wen; Liu, Zhao-Tie

    2013-11-21

    Ultraclean fuels production has become increasingly important as a method to help decrease emissions and allow the introduction of alternative feed stocks for transportation fuels. Established methods, such as Fischer-Tropsch, have seen a resurgence of interest as natural gas prices drop and existing petroleum resources require more intensive clean-up and purification to meet stringent environmental standards. This review covers some of the advances in deep desulfurization, synthesis gas conversion into fuels and feed stocks that were presented at the 245th American Chemical Society Spring Annual Meeting in New Orleans, LA in the Division of Energy and Fuels symposium on "Ultraclean Fuels Production and Utilization".

  13. Advanced waste forms from spent nuclear fuel

    Energy Technology Data Exchange (ETDEWEB)

    Ackerman, J.P.; McPheeters, C.C.

    1995-12-31

    More than one hundred spent nuclear fuel types, having an aggregate mass of more than 5000 metric tons (2700 metric tons of heavy metal), are stored by the United States Department of Energy. This paper proposes a method for converting this wide variety of fuel types into two waste forms for geologic disposal. The method is based on a molten salt electrorefining technique that was developed for conditioning the sodium-bonded, metallic fuel from the Experimental Breeder Reactor-II (EBR-II) for geologic disposal. The electrorefining method produces two stable, optionally actinide-free, high-level waste forms: an alloy formed from stainless steel, zirconium, and noble metal fission products, and a ceramic waste form containing the reactive metal fission products. Electrorefining and its accompanying head-end process are briefly described, and methods for isolating fission products and fabricating waste forms are discussed.

  14. Advanced composite polymer electrolyte fuel cell membranes

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, M.S.; Zawodzinski, T.A.; Gottesfeld, S.; Kolde, J.A.; Bahar, B.

    1995-09-01

    A new type of reinforced composite perfluorinated polymer electrolyte membrane, GORE-SELECT{trademark} (W.L. Gore & Assoc.), is characterized and tested for fuel cell applications. Very thin membranes (5-20 {mu}m thick) are available. The combination of reinforcement and thinness provides high membrane, conductances (80 S/cm{sup 2} for a 12 {mu}m thick membrane at 25{degrees}C) and improved water distribution in the operating fuel cell without sacrificing longevity or durability. In contrast to nonreinforced perfluorinated membranes, the x-y dimensions of the GORE-SELECT membranes are relatively unaffected by the hydration state. This feature may be important from the viewpoints of membrane/electrode interface stability and fuel cell manufacturability.

  15. Strategic research of advanced fuel cycle technologies in JNC

    Energy Technology Data Exchange (ETDEWEB)

    Kawata, T.; Fukushima, M.; Nomura, S. [Japan Nuclear Cycle Development Institute, Tokai Works (Japan)

    2000-07-01

    Key technologies for the future nuclear fuel cycle have been proposed and are being reviewed in JNC as a part of the Feasibility Study for an Advanced Fuel Cycle, which is to achieve a more flexible energy choice to satisfy a sustainable energy security and global environmental protection. The candidate reprocessing technologies are: 1) aqueous simplified PUREX process, 2) oxide or metallic electrowinning, and 3) fluoride volatilization for oxide, metal, or nitride fuels. The fuel fabrication methods being investigated are: 1) simplified pellet process, 2) sphere/vibro-packed process for MOX/MN fuel, and 3) casting for metal fuel. These candidate technologies are currently being compared based on past experiences, technical issues to be solved, industrial applicability for future plants, feasible options for MA/LLFP separation, and nonproliferation aspects. Alter two years of the present reviewing process, selected key technologies will be developed over the next five years to evaluate industrial applicability of reprocessing and fuel manufacturing processes for the advanced fuel cycle. (authors)

  16. Characterisation of fuels for advanced pressurised combustion

    Energy Technology Data Exchange (ETDEWEB)

    Zevenhoven, R.; Hupa, M.; Backman, P.; Forssen, M.; Karlsson, M.; Kullberg, M.; Sorvari, V.; Uusikartano, T. [Aabo Akademi, Turku (Finland). Combustion Chemistry Research Group; Nurk, M. [Tallinskij Politekhnicheskij Inst., Tallinn (Estonia)

    1997-10-01

    The objective of the research was to determine a set of fuel characteristics which quantify the behaviour of a fuel in a typical pressurised combustor or gasifier environment, especially in hybrid processes such as second generation PFBC. One specific aspect was to cover a wide range of fuels, including several coal types and several grades of peat and biomasses: 7 types of coal, 2 types of peat, 2 types of wood, 2 types of black liquor, Estonian oil shale and Venezuelan Orimulsion were studied. The laboratory facilities used are a pressurised thermogravimetric reactor (PTGR), a pressurised grid heater (PGH) and an atmospheric entrained flow quartz tube reactor, with gas analysis, which can be operated as a fixed bed reactor. A major part of the work was related to fuel devolatilisation in the PGH and sequential devolatilisation and char gasification (with carbon dioxide or steam) in the PTGR. The final part of that work is reported here, with the combustion of Estonian oil shale at AFBC or PFBC conditions as additional subject. Devolatilisation of the fuels at atmospheric pressure in nitrogen while monitoring gaseous exhausts, followed by ultimate analysis of the chars has been reported earlier. Here, results on the analysis of the reduction of NO (with and without CO) on chars at atmospheric pressure in a fixed bed reactor are reported. Finally, a comparison is given between experimental results and direct numerical simulation with several computer codes, i.e. PyroSim, developed at TU Graz, Austria, and the codes Partikkeli, Pisara and Cogas, which were provided by VTT Energy, Jyvaeskylae

  17. Advancing the Limits of Dual Fuel Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Koenigsson, Fredrik

    2012-07-01

    There is a growing interest in alternative transport fuels. There are two underlying reasons for this interest; the desire to decrease the environmental impact of transports and the need to compensate for the declining availability of petroleum. In the light of both these factors the Diesel Dual Fuel, DDF, engine is an attractive concept. The primary fuel of the DDF engine is methane, which can be derived both from renewables and from fossil sources. Methane from organic waste; commonly referred to as biomethane, can provide a reduction in greenhouse gases unmatched by any other fuel. The DDF engine is from a combustion point of view a hybrid between the diesel and the otto engine and it shares characteristics with both. This work identifies the main challenges of DDF operation and suggests methods to overcome them. Injector tip temperature and pre-ignitions have been found to limit performance in addition to the restrictions known from literature such as knock and emissions of NO{sub x} and HC. HC emissions are especially challenging at light load where throttling is required to promote flame propagation. For this reason it is desired to increase the lean limit in the light load range in order to reduce pumping losses and increase efficiency. It is shown that the best results in this area are achieved by using early diesel injection to achieve HCCI/RCCI combustion where combustion phasing is controlled by the ratio between diesel and methane. However, even without committing to HCCI/RCCI combustion and the difficult control issues associated with it, substantial gains are accomplished by splitting the diesel injection into two and allocating most of the diesel fuel to the early injection. HCCI/RCCI and PPCI combustion can be used with great effect to reduce the emissions of unburned hydrocarbons at light load. At high load, the challenges that need to be overcome are mostly related to heat. Injector tip temperatures need to be observed since the cooling effect of

  18. ENHANCING ADVANCED CANDU PROLIFERATION RESISTANCE FUEL WITH MINOR ACTINIDES

    Energy Technology Data Exchange (ETDEWEB)

    Gray S. Chang

    2010-05-01

    The advanced nuclear system will significantly advance the science and technology of nuclear energy systems and to enhance the spent fuel proliferation resistance. Minor actinides (MA) are viewed more as a resource to be recycled, and transmuted to less hazardous and possibly more useful forms, rather than simply disposed of as a waste stream in an expensive repository facility. MAs can play a much larger part in the design of advanced systems and fuel cycles, not only as additional sources of useful energy, but also as direct contributors to the reactivity control of the systems into which they are incorporated. In this work, an Advanced CANDU Reactor (ACR) fuel unit lattice cell model with 43 UO2 fuel rods will be used to investigate the effectiveness of a Minor Actinide Reduction Approach (MARA) for enhancing proliferation resistance and improving the fuel cycle performance. The main MARA objective is to increase the 238Pu / Pu isotope ratio by using the transuranic nuclides (237Np and 241Am) in the high burnup fuel and thereby increase the proliferation resistance even for a very low fuel burnup. As a result, MARA is a very effective approach to enhance the proliferation resistance for the on power refueling ACR system nuclear fuel. The MA transmutation characteristics at different MA loadings were compared and their impact on neutronics criticality assessed. The concept of MARA, significantly increases the 238Pu/Pu ratio for proliferation resistance, as well as serves as a burnable absorber to hold-down the initial excess reactivity. It is believed that MARA can play an important role in atoms for peace and the intermediate term of nuclear energy reconnaissance.

  19. Alternative Fuel and Advanced Technology Commercial Lawn Equipment (Brochure)

    Energy Technology Data Exchange (ETDEWEB)

    2014-10-01

    The U.S. Department of Energy's Clean Cities program produced this guide to help inform the commercial mowing industry about product options and potential benefits. This guide provides information about equipment powered by propane, ethanol, compressed natural gas, biodiesel, and electricity, as well as advanced engine technology. In addition to providing an overview for organizations considering alternative fuel lawn equipment, this guide may also be helpful for organizations that want to consider using additional alternative fueled equipment.

  20. Alternative Fuel and Advanced Technology Commercial Lawn Equipment

    Energy Technology Data Exchange (ETDEWEB)

    None

    2014-10-10

    The U.S. Department of Energy's Clean Cities program produced this guide to help inform the commercial mowing industry about product options and potential benefits. This guide provides information about equipment powered by propane, ethanol, compressed natural gas, biodiesel, and electricity, as well as advanced engine technology. In addition to providing an overview for organizations considering alternative fuel lawn equipment, this guide may also be helpful for organizations that want to consider using additional alternative fueled equipment.

  1. Advanced laser processing in fuel cells production

    Energy Technology Data Exchange (ETDEWEB)

    Stollhof, J.; Havrilla, D.; Schaupp, R. [TRUMPF Inc., Plymouth, MI (United States); Loeffler, K. [TRUMPF Laser und Systemtechnik TLD, Ditzingen (Germany)

    2009-07-01

    This paper discussed TRUMPF methods of joining bipolar plates to create fuel cell stacks and manufacture thin foils using diode pumped solid state lasers (DPSSLs). Beam delivery systems and processing optics were discussed. CW disk lasers were used to allow spot diameters smaller than 30 {mu}m and combined with a Galvo technology-based scanning optics systems to enable welding speeds greater than 1 m/s. A TruFiber 300 diffraction limited fiber laser was used for CW laser cutting. Short and ultra-short laser pulses were used to drill thousands of holes per second without a measurable heat-affected zone. The attributes and specifications of the 3 major TRUMPF lasers developed to manufacture fuel cells were also provided.

  2. Versatile Affordable Advanced Fuels and Combustion Technologies

    Science.gov (United States)

    2010-11-01

    the solution and spin -cast into films using polymethylmethacrylate (PMMA) and tetraethyl orthosilicate (TEOS)-based sol-gel silica as matrix...insert. White colonies, 48 from each fuel sample, were processed using the QIAprep Spin Mini Prep Kit following the manufacturer’s protocol but eluting...assumed, for simplicity, that the activation energy of the surface reaction is the same for all stainless steels considered (SS316 and SS304 ). Computational

  3. Characterisation of fuels for advanced pressurized combustion

    Energy Technology Data Exchange (ETDEWEB)

    Zevenhoven, R.; Hupa, M.; Backman, P.; Karlsson, M.; Kullberg, M.; Sorvari, V. [Aabo Akademi, Turku (Finland); Nurk, M. [Tallinn Univ. (Estonia)

    1996-12-01

    After 2 of the 3 years for this EU Joule 2 extension project, a rough comparison on the devolatilisation behaviour and char reactivity of 11 fossil fuels and 4 biofuels has been obtained. The experimental plan for 1995 has been completed, the laboratory facilities appeared to be well suited for the broad range of analyses presented here. A vast amount of devolatilisation tests in nitrogen at atmospheric pressure with gas analysis and char analysis gave a lot of information on the release of carbon, sulphur, nitrogen and also sodium, chloride and some other elements. Also first-order rate parameters could be determined. Solid pyrolysis yield measurements with the pressurised grid heater show a very good reproducibility except for the fuels with high carbonate content and those with very small char yield. Problems have to be solved considering lower heating rates and the use of folded grids. Fuel pyrolysis followed by gasification (with carbon dioxide or water as oxidising agent) at various temperatures and pressures shows that in general char solid yields and gasification reactivities are higher at elevated pressure. The design and construction of a pressurized single particle reactor, to be operational early 1996 is currently being negotiated. Numerical modelling of coal devolatilisation shows that even for atmospheric pressures the results differ significantly from experimental findings. (author)

  4. 40 CFR 600.206-12 - Calculation and use of FTP-based and HFET-based fuel economy and carbon-related exhaust emission...

    Science.gov (United States)

    2010-07-01

    ... performed using alcohol or natural gas test fuel. (b) If only one equivalent petroleum-based fuel economy... per gallon, will comprise the petroleum-based fuel economy for that configuration. (c) If more than one equivalent petroleum-based fuel economy value exists for an electric vehicle configuration,...

  5. IEA-Advanced Motor Fuels Annual Report 2012

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-06-15

    The annual report from the IEA implementing agreement on Advanced Motor Fuels (AMF) describes what the agreement is about, how to join, various activities of the agreement, a message from the Chairman, and projects/annexes active for the year. An annual section covers the global situation for the topic of advanced motor fuels. Another section includes highlights coming from each country participating in AMF, and major sections relaying activities on each of the ongoing annexes. Information regarding participating delegations, contact information, publications resulting from AMF, and upcoming meetings rounds out the report.

  6. IEA-Advanced Motor Fuels Annual Report 2011

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    The annual report from the IEA implementing agreement on Advanced Motor Fuels (AMF) describes what the agreement is about, how to join, various activities of the agreement, a message from the Chairman, and projects/annexes active for the year. An annual section covers the global situation for the topic of advanced motor fuels. Another section includes highlights coming from each country participating in AMF, and major sections relaying activities on each of the ongoing annexes. Information regarding participating delegations, contact information, publications resulting from AMF, and upcoming meetings rounds out the report.

  7. Component Development - Advanced Fuel Cells for Transportation Applications

    Energy Technology Data Exchange (ETDEWEB)

    Butler, William

    2000-06-19

    Report summarizes results of second phase of development of Vairex air compressor/expander for automotive fuel cell power systems. Project included optimizing key system performance parameters, as well as reducing number of components and the project cost, size and weight of the air system. Objectives were attained. Advanced prototypes are in commercial test environments.

  8. Assessment of Research Needs for Advanced Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Penner, S.S.

    1985-11-01

    The DOE Advanced Fuel Cell Working Group (AFCWG) was formed and asked to perform a scientific evaluation of the current status of fuel cells, with emphasis on identification of long-range research that may have a significant impact on the practical utilization of fuel cells in a variety of applications. The AFCWG held six meetings at locations throughout the country where fuel cell research and development are in progress, for presentations by experts on the status of fuel cell research and development efforts, as well as for inputs on research needs. Subsequent discussions by the AFCWG have resulted in the identification of priority research areas that should be explored over the long term in order to advance the design and performance of fuel cells of all types. Surveys describing the salient features of individual fuel cell types are presented in Chapters 2 to 6 and include elaborations of long-term research needs relating to the expeditious introduction of improved fuel cells. The Introduction and the Summary (Chapter 1) were prepared by AFCWG. They were repeatedly revised in response to comments and criticism. The present version represents the closest approach to a consensus that we were able to reach, which should not be interpreted to mean that each member of AFCWG endorses every statement and every unexpressed deletion. The Introduction and Summary always represent a majority view and, occasionally, a unanimous judgment. Chapters 2 to 6 provide background information and carry the names of identified authors. The identified authors of Chapters 2 to 6, rather than AFCWG as a whole, bear full responsibility for the scientific and technical contents of these chapters.

  9. Design of demonstration facility for advanced spent fuel conditioning process

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, W. M.; Koo, J. H.; Jeo, I. J.; Kook, D. H.; Lee, E. P.; Baek, S. R.; Lee, K. I.; You, K. S.; Park, S. W. [KAERI, Taejon (Korea, Republic of)

    2003-10-01

    The Advanced spent fuel Conditioning Process(ACP) was proposed and developed for effective management of the PWR spent fuel. The detail plan was established for demonstration and verification of the ACP, and an existing hot cell will be modified as {alpha}-{gamma} type hot cell. In this study, the process mechanical flow was analysed for the optimum arrangement to ensure effective process operation in hot cell, and the detail design of hot cell including the auxiliary facility and safety analysis was performed to secure conservative safety of hot cell system. And then, this results will be utilized for hot cell refurbishment and license.

  10. Utilization of spent PWR fuel-advanced nuclear fuel cycle of PWR/CANDU synergism

    Institute of Scientific and Technical Information of China (English)

    HUO Xiao-Dong; XIE Zhong-Sheng

    2004-01-01

    High neutron economy, on line refueling and channel design result in the unsurpassed fuel cycle flexibility and variety for CANDU reactors. According to the Chinese national conditions that China has both PWR and CANDU reactors and the closed cycle policy of reprocessing the spent PWR fuel is adopted, one of the advanced nuclear fuel cycles of PWR/CANDU synergism using the reprocessed uranium of spent PWR fuel in CANDU reactor is proposed, which will save the uranium resource (~22.5%), increase the energy output (~41%), decrease the quantity of spent fuels to be disposed (~2/3) and lower the cost of nuclear power. Because of the inherent flexibility of nuclear fuel cycle in CANDU reactor, and the low radiation level of recycled uranium(RU), which is acceptable for CANDU reactor fuel fabrication, the transition from the natural uranium to the RU can be completed without major modification of the reactor core structure and operation mode. It can be implemented in Qinshan Phase Ⅲ CANDU reactors with little or no requirement of big investment in new design. It can be expected that the reuse of recycled uranium of spent PWR fuel in CANDU reactor is a feasible and desirable strategy in China.

  11. Simulations of Failure via Three-Dimensional Cracking in Fuel Cladding for Advanced Nuclear Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Hongbing [Univ. of Texas, Austin, TX (United States); Bukkapatnam, Satish; Harimkar, Sandip; Singh, Raman; Bardenhagen, Scott

    2014-01-09

    Enhancing performance of fuel cladding and duct alloys is a key means of increasing fuel burnup. This project will address the failure of fuel cladding via three-dimensional cracking models. Researchers will develop a simulation code for the failure of the fuel cladding and validate the code through experiments. The objective is to develop an algorithm to determine the failure of fuel cladding in the form of three-dimensional cracking due to prolonged exposure under varying conditions of pressure, temperature, chemical environment, and irradiation. This project encompasses the following tasks: 1. Simulate 3D crack initiation and growth under instantaneous and/or fatigue loads using a new variant of the material point method (MPM); 2. Simulate debonding of the materials in the crack path using cohesive elements, considering normal and shear traction separation laws; 3. Determine the crack propagation path, considering damage of the materials incorporated in the cohesive elements to allow the energy release rate to be minimized; 4. Simulate the three-dimensional fatigue crack growth as a function of loading histories; 5. Verify the simulation code by comparing results to theoretical and numerical studies available in the literature; 6. Conduct experiments to observe the crack path and surface profile in unused fuel cladding and validate against simulation results; and 7. Expand the adaptive mesh refinement infrastructure parallel processing environment to allow adaptive mesh refinement at the 3D crack fronts and adaptive mesh merging in the wake of cracks. Fuel cladding is made of materials such as stainless steels and ferritic steels with added alloying elements, which increase stability and durability under irradiation. As fuel cladding is subjected to water, chemicals, fission gas, pressure, high temperatures, and irradiation while in service, understanding performance is essential. In the fast fuel used in advanced burner reactors, simulations of the nuclear

  12. Cycle update : advanced fuels and technologies for emissions reduction

    Energy Technology Data Exchange (ETDEWEB)

    Smallwood, G. [National Research Council of Canada, Ottawa, ON (Canada)

    2009-07-01

    This paper provided a summary of key achievements of the Program of Energy Research and Development advanced fuels and technologies for emissions reduction (AFTER) program over the funding cycle from fiscal year 2005/2006 to 2008/2009. The purpose of the paper was to inform interested parties of recent advances in knowledge and in science and technology capacities in a concise manner. The paper discussed the high level research and development themes of the AFTER program through the following 4 overarching questions: how could advanced fuels and internal combustion engine designs influence emissions; how could emissions be reduced through the use of engine hardware including aftertreatment devices; how do real-world duty cycles and advanced technology vehicles operating on Canadian fuels compare with existing technologies, models and estimates; and what are the health risks associated with transportation-related emissions. It was concluded that the main issues regarding the use of biodiesel blends in current technology diesel engines are the lack of consistency in product quality; shorter shelf life of biodiesel due to poorer oxidative stability; and a need to develop characterization methods for the final oxygenated product because most standard methods are developed for hydrocarbons and are therefore inadequate. 2 tabs., 13 figs.

  13. Advanced modeling of oxy-fuel combustion of natural gas

    Energy Technology Data Exchange (ETDEWEB)

    Chungen Yin

    2011-01-15

    The main goal of this small-scale project is to investigate oxy-combustion of natural gas (NG) through advanced modeling, in which radiation, chemistry and mixing will be reasonably resolved. 1) A state-of-the-art review was given regarding the latest R and D achievements and status of oxy-fuel technology. The modeling and simulation status and achievements in the field of oxy-fuel combustion were also summarized; 2) A computer code in standard c++, using the exponential wide band model (EWBM) to evaluate the emissivity and absorptivity of any gas mixture at any condition, was developed and validated in detail against data in literature. A new, complete, and accurate WSGGM, applicable to both air-fuel and oxy-fuel combustion modeling and applicable to both gray and non-gray calculation, was successfully derived, by using the validated EWBM code as the reference mode. The new WSGGM was implemented in CFD modeling of two different oxy-fuel furnaces, through which its great, unique advantages over the currently most widely used WSGGM were demonstrated. 3) Chemical equilibrium calculations were performed for oxy-NG flame and air-NG flame, in which dissociation effects were considered to different degrees. Remarkable differences in oxy-fuel and air-fuel combustion were revealed, and main intermediate species that play key roles in oxy-fuel flames were identified. Different combustion mechanisms are compared, e.g., the most widely used 2-step global mechanism, refined 4-step global mechanism, a global mechanism developed for oxy-fuel using detailed chemical kinetic modeling (CHEMKIN) as reference. 4) Over 15 CFD simulations were done for oxy-NG combustion, in which radiation, chemistry, mixing, turbulence-chemistry interactions, and so on were thoroughly investigated. Among all the simulations, RANS combined with 2-step and refined 4-step mechanism, RANS combined with CHEMKIN-based new global mechanism for oxy-fuel modeling, and LES combined with different combustion

  14. Combustion behaviors of a compression-ignition engine fueled with diesel/methanol blends under various fuel delivery advance angles.

    Science.gov (United States)

    Huang, Zuohua; Lu, Hongbing; Jiang, Deming; Zeng, Ke; Liu, Bing; Zhang, Junqiang; Wang, Xibin

    2004-12-01

    A stabilized diesel/methanol blend was described and the basic combustion behaviors based on the cylinder pressure analysis was conducted in a compression-ignition engine. The study showed that increasing methanol mass fraction of the diesel/methanol blends would increase the heat release rate in the premixed burning phase and shorten the combustion duration of the diffusive burning phase. The ignition delay increased with the advancing of the fuel delivery advance angle for both the diesel fuel and the diesel/methanol blends. For a specific fuel delivery advance angle, the ignition delay increased with the increase of the methanol mass fraction (oxygen mass fraction) in the fuel blends and the behaviors were more obvious at low engine load and/or high engine speed. The rapid burn duration and the total combustion duration increased with the advancing of the fuel delivery advance angle. The centre of the heat release curve was close to the top-dead-centre with the advancing of the fuel delivery advance angle. Maximum cylinder gas pressure increased with the advancing of the fuel delivery advance angle, and the maximum cylinder gas pressure of the diesel/methanol blends gave a higher value than that of the diesel fuel. The maximum mean gas temperature remained almost unchanged or had a slight increase with the advancing of the fuel delivery advance angle, and it only slightly increased for the diesel/methanol blends compared to that of the diesel fuel. The maximum rate of pressure rise and the maximum rate of heat release increased with the advancing of the fuel delivery advance angle of the diesel/methanol blends and the value was highest for the diesel/methanol blends.

  15. Advanced coal-fueled industrial cogeneration gas turbine system

    Energy Technology Data Exchange (ETDEWEB)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  16. Advanced materials for alternative fuel capable directly fired heat engines

    Energy Technology Data Exchange (ETDEWEB)

    Fairbanks, J.W.; Stringer, J. (eds.)

    1979-12-01

    The first conference on advanced materials for alternative fuel capable directly fired heat engines was held at the Maine Maritime Academy, Castine, Maine. It was sponsored by the US Department of Energy, (Assistant Secretary for Fossil Energy) and the Electric Power Research Institute, (Division of Fossil Fuel and Advanced Systems). Forty-four papers from the proceedings have been entered into EDB and ERA and one also into EAPA; three had been entered previously from other sources. The papers are concerned with US DOE research programs in this area, coal gasification, coal liquefaction, gas turbines, fluidized-bed combustion and the materials used in these processes or equipments. The materials papers involve alloys, ceramics, coatings, cladding, etc., and the fabrication and materials listing of such materials and studies involving corrosion, erosion, deposition, etc. (LTN)

  17. Recovery Act: Advanced Direct Methanol Fuel Cell for Mobile Computing

    Energy Technology Data Exchange (ETDEWEB)

    Fletcher, James H. [University of North Florida; Cox, Philip [University of North Florida; Harrington, William J [University of North Florida; Campbell, Joseph L [University of North Florida

    2013-09-03

    ABSTRACT Project Title: Recovery Act: Advanced Direct Methanol Fuel Cell for Mobile Computing PROJECT OBJECTIVE The objective of the project was to advance portable fuel cell system technology towards the commercial targets of power density, energy density and lifetime. These targets were laid out in the DOE’s R&D roadmap to develop an advanced direct methanol fuel cell power supply that meets commercial entry requirements. Such a power supply will enable mobile computers to operate non-stop, unplugged from the wall power outlet, by using the high energy density of methanol fuel contained in a replaceable fuel cartridge. Specifically this project focused on balance-of-plant component integration and miniaturization, as well as extensive component, subassembly and integrated system durability and validation testing. This design has resulted in a pre-production power supply design and a prototype that meet the rigorous demands of consumer electronic applications. PROJECT TASKS The proposed work plan was designed to meet the project objectives, which corresponded directly with the objectives outlined in the Funding Opportunity Announcement: To engineer the fuel cell balance-of-plant and packaging to meet the needs of consumer electronic systems, specifically at power levels required for mobile computing. UNF used existing balance-of-plant component technologies developed under its current US Army CERDEC project, as well as a previous DOE project completed by PolyFuel, to further refine them to both miniaturize and integrate their functionality to increase the system power density and energy density. Benefits of UNF’s novel passive water recycling MEA (membrane electrode assembly) and the simplified system architecture it enabled formed the foundation of the design approach. The package design was hardened to address orientation independence, shock, vibration, and environmental requirements. Fuel cartridge and fuel subsystems were improved to ensure effective fuel

  18. Advanced Nuclear Fuel Cycle Transitions: Optimization, Modeling Choices, and Disruptions

    Science.gov (United States)

    Carlsen, Robert W.

    Many nuclear fuel cycle simulators have evolved over time to help understan the nuclear industry/ecosystem at a macroscopic level. Cyclus is one of th first fuel cycle simulators to accommodate larger-scale analysis with it liberal open-source licensing and first-class Linux support. Cyclus also ha features that uniquely enable investigating the effects of modeling choices o fuel cycle simulators and scenarios. This work is divided into thre experiments focusing on optimization, effects of modeling choices, and fue cycle uncertainty. Effective optimization techniques are developed for automatically determinin desirable facility deployment schedules with Cyclus. A novel method fo mapping optimization variables to deployment schedules is developed. Thi allows relationships between reactor types and scenario constraints to b represented implicitly in the variable definitions enabling the usage o optimizers lacking constraint support. It also prevents wasting computationa resources evaluating infeasible deployment schedules. Deployed power capacit over time and deployment of non-reactor facilities are also included a optimization variables There are many fuel cycle simulators built with different combinations o modeling choices. Comparing results between them is often difficult. Cyclus flexibility allows comparing effects of many such modeling choices. Reacto refueling cycle synchronization and inter-facility competition among othe effects are compared in four cases each using combinations of fleet of individually modeled reactors with 1-month or 3-month time steps. There are noticeable differences in results for the different cases. The larges differences occur during periods of constrained reactor fuel availability This and similar work can help improve the quality of fuel cycle analysi generally There is significant uncertainty associated deploying new nuclear technologie such as time-frames for technology availability and the cost of buildin advanced reactors

  19. Advanced Gas Reactor (AGR)-5/6/7 Fuel Irradiation Experiments in the Advanced Test Reactor

    Energy Technology Data Exchange (ETDEWEB)

    A. Joseph Palmer; David A. Petti; S. Blaine Grover

    2014-04-01

    The United States Department of Energy’s Very High Temperature Reactor (VHTR) Advanced Gas Reactor (AGR) Fuel Development and Qualification Program will be irradiating up to seven separate low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which each consist of at least five separate capsules, are being irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gases also have on-line fission product monitoring the effluent from each capsule to track performance of the fuel during irradiation. The first two experiments (designated AGR-1 and AGR-2), have been completed. The third and fourth experiments have been combined into a single experiment designated AGR-3/4, which started its irradiation in December 2011 and is currently scheduled to be completed in April 2014. The design of the fuel qualification experiment, designated AGR-5/6/7, is well underway and incorporates lessons learned from the three previous experiments. Various design issues will be discussed with particular details related to selection of thermometry.

  20. Microbial engineering for the production of advanced biofuels.

    Science.gov (United States)

    Peralta-Yahya, Pamela P; Zhang, Fuzhong; del Cardayre, Stephen B; Keasling, Jay D

    2012-08-16

    Advanced biofuels produced by microorganisms have similar properties to petroleum-based fuels, and can 'drop in' to the existing transportation infrastructure. However, producing these biofuels in yields high enough to be useful requires the engineering of the microorganism's metabolism. Such engineering is not based on just one specific feedstock or host organism. Data-driven and synthetic-biology approaches can be used to optimize both the host and pathways to maximize fuel production. Despite some success, challenges still need to be met to move advanced biofuels towards commercialization, and to compete with more conventional fuels.

  1. Recovery Act: Advanced Direct Methanol Fuel Cell for Mobile Computing

    Energy Technology Data Exchange (ETDEWEB)

    Fletcher, James H. [University of North Florida; Cox, Philip [University of North Florida; Harrington, William J [University of North Florida; Campbell, Joseph L [University of North Florida

    2013-09-03

    ABSTRACT Project Title: Recovery Act: Advanced Direct Methanol Fuel Cell for Mobile Computing PROJECT OBJECTIVE The objective of the project was to advance portable fuel cell system technology towards the commercial targets of power density, energy density and lifetime. These targets were laid out in the DOE’s R&D roadmap to develop an advanced direct methanol fuel cell power supply that meets commercial entry requirements. Such a power supply will enable mobile computers to operate non-stop, unplugged from the wall power outlet, by using the high energy density of methanol fuel contained in a replaceable fuel cartridge. Specifically this project focused on balance-of-plant component integration and miniaturization, as well as extensive component, subassembly and integrated system durability and validation testing. This design has resulted in a pre-production power supply design and a prototype that meet the rigorous demands of consumer electronic applications. PROJECT TASKS The proposed work plan was designed to meet the project objectives, which corresponded directly with the objectives outlined in the Funding Opportunity Announcement: To engineer the fuel cell balance-of-plant and packaging to meet the needs of consumer electronic systems, specifically at power levels required for mobile computing. UNF used existing balance-of-plant component technologies developed under its current US Army CERDEC project, as well as a previous DOE project completed by PolyFuel, to further refine them to both miniaturize and integrate their functionality to increase the system power density and energy density. Benefits of UNF’s novel passive water recycling MEA (membrane electrode assembly) and the simplified system architecture it enabled formed the foundation of the design approach. The package design was hardened to address orientation independence, shock, vibration, and environmental requirements. Fuel cartridge and fuel subsystems were improved to ensure effective fuel

  2. Development of Kinetic Mechanisms for Next-Generation Fuels and CFD Simulation of Advanced Combustion Engines

    Energy Technology Data Exchange (ETDEWEB)

    Pitz, William J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); McNenly, Matt J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Whitesides, Russell [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Mehl, Marco [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Killingsworth, Nick J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Westbrook, Charles K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2015-12-17

    Predictive chemical kinetic models are needed to represent next-generation fuel components and their mixtures with conventional gasoline and diesel fuels. These kinetic models will allow the prediction of the effect of alternative fuel blends in CFD simulations of advanced spark-ignition and compression-ignition engines. Enabled by kinetic models, CFD simulations can be used to optimize fuel formulations for advanced combustion engines so that maximum engine efficiency, fossil fuel displacement goals, and low pollutant emission goals can be achieved.

  3. Advanced PWR in-core fuel management with optimized gadolinia fuel designs

    Energy Technology Data Exchange (ETDEWEB)

    Berger, H.D.; Neufert, A. [Siemens AG / Power Generation KWU, Nuclear Fuel Cycle, Erlangen (Germany)

    1999-07-01

    Utilities operating LWRs require fuel assemblies and in-core fuel management service, which ensure safe, flexible and cost-effective production of electricity. With the reliability of the fuel having been always the most important requirement, advanced measures to minimize fuel cycle costs are receiving increasing attention in the light of the pressure on costs within the de-regulated power generation markets. The role of in-core fuel management in supporting the goal to minimize fuel cycle costs consists in the development of more demanding core loading strategies, i.e. in the first place more advanced low leakage loading patterns. A prerequisite for this type of loading pattern is the use of an optimized burnable absorber design. Gadolinia as integrated burnable absorber is a very effective means for limiting the critical boron concentration and power peaking factors. Siemens has accumulated extensive experience with Gd-fuel for almost 20 years with e.g. more than 5500 Gd-FA's delivered for PWRs and irradiated up to 65 MWd/kg{sub HM}. Current development efforts for optimizing Gd-fuel are focused on the reduction of the inherent penalties of today's Gd-Fa designs, i.e. reduced average FA enrichment and heavy metal content as well as residual reactivity binding. The most effective way to overcome these drawbacks is the reduction of the Gd{sub 2}O{sub 3} concentration to values of approximately 2 w/o, for which according to recent measurements of the heat conductivity of modern Gd-fuels the reduction of the fissile content in the Gd-rods is no longer necessary. Various feasibility studies have been performed to evaluate the consequences of low-Gd designs for both Siemens PWRs and Non-Siemens PWRs, for which more restrictive boundary conditions with respect to critical boron concentration and peaking factors have to be fulfilled. These studies as well as the first realization of an extended reactor cycle using a low Gd-Fa reload design confirm that the in

  4. Application of the Advanced Distillation Curve Method to Fuels for Advanced Combustion Engine Gasolines

    KAUST Repository

    Burger, Jessica L.

    2015-07-16

    © This article not subject to U.S. Copyright. Published 2015 by the American Chemical Society. Incremental but fundamental changes are currently being made to fuel composition and combustion strategies to diversify energy feedstocks, decrease pollution, and increase engine efficiency. The increase in parameter space (by having many variables in play simultaneously) makes it difficult at best to propose strategic changes to engine and fuel design by use of conventional build-and-test methodology. To make changes in the most time- and cost-effective manner, it is imperative that new computational tools and surrogate fuels are developed. Currently, sets of fuels are being characterized by industry groups, such as the Coordinating Research Council (CRC) and other entities, so that researchers in different laboratories have access to fuels with consistent properties. In this work, six gasolines (FACE A, C, F, G, I, and J) are characterized by the advanced distillation curve (ADC) method to determine the composition and enthalpy of combustion in various distillate volume fractions. Tracking the composition and enthalpy of distillate fractions provides valuable information for determining structure property relationships, and moreover, it provides the basis for the development of equations of state that can describe the thermodynamic properties of these complex mixtures and lead to development of surrogate fuels composed of major hydrocarbon classes found in target fuels.

  5. THE MISSION AND ACCOMPLISHMENTS FROM DOE’S FUEL CYCLE RESEARCH AND DEVELOPMENT (FCRD) ADVANCED FUELS CAMPAIGN

    Energy Technology Data Exchange (ETDEWEB)

    J. Carmack; L. Braase; F. Goldner

    2015-09-01

    The mission of the Advanced Fuels Campaign (AFC) is to perform Research, Development, and Demonstration (RD&D) activities for advanced fuel forms (including cladding) to enhance the performance and safety of the nation’s current and future reactors, enhance proliferation resistance of nuclear fuel, effectively utilize nuclear energy resources, and address the longer-term waste management challenges. This includes development of a state of the art Research and Development (R&D) infrastructure to support the use of a “goal oriented science based approach.” AFC uses a “goal oriented, science based approach” aimed at a fundamental understanding of fuel and cladding fabrication methods and performance under irradiation, enabling the pursuit of multiple fuel forms for future fuel cycle options. This approach includes fundamental experiments, theory, and advanced modeling and simulation. One of the most challenging aspects of AFC is the management, integration, and coordination of major R&D activities across multiple organizations. AFC interfaces and collaborates with Fuel Cycle Technologies (FCT) campaigns, universities, industry, various DOE programs and laboratories, federal agencies (e.g., Nuclear Regulatory Commission [NRC]), and international organizations. Key challenges are the development of fuel technologies to enable major increases in fuel performance (safety, reliability, power and burnup) beyond current technologies, and development of characterization methods and predictive fuel performance models to enable more efficient development and licensing of advanced fuels. Challenged with the research and development of fuels for two different reactor technology platforms, AFC targeted transmutation fuel development and focused ceramic fuel development for Advanced LWR Fuels.

  6. Advanced Fuels Campaign Light Water Reactor Accident Tolerant Fuel Performance Metrics

    Energy Technology Data Exchange (ETDEWEB)

    Brad Merrill; Melissa Teague; Robert Youngblood; Larry Ott; Kevin Robb; Michael Todosow; Chris Stanek; Mitchell Farmer; Michael Billone; Robert Montgomery; Nicholas Brown; Shannon Bragg-Sitton

    2014-02-01

    The safe, reliable and economic operation of the nation’s nuclear power reactor fleet has always been a top priority for the United States’ nuclear industry. As a result, continual improvement of technology, including advanced materials and nuclear fuels, remains central to industry’s success. Decades of research combined with continual operation have produced steady advancements in technology and yielded an extensive base of data, experience, and knowledge on light water reactor (LWR) fuel performance under both normal and accident conditions. In 2011, following the Great East Japan Earthquake, resulting tsunami, and subsequent damage to the Fukushima Daiichi nuclear power plant complex, enhancing the accident tolerance of LWRs became a topic of serious discussion. As a result of direction from the U.S. Congress, the U.S. Department of Energy Office of Nuclear Energy (DOE-NE) initiated an Accident Tolerant Fuel (ATF) Development program. The complex multiphysics behavior of LWR nuclear fuel makes defining specific material or design improvements difficult; as such, establishing qualitative attributes is critical to guide the design and development of fuels and cladding with enhanced accident tolerance. This report summarizes a common set of technical evaluation metrics to aid in the optimization and down selection of candidate designs. As used herein, “metrics” describe a set of technical bases by which multiple concepts can be fairly evaluated against a common baseline and against one another. Furthermore, this report describes a proposed technical evaluation methodology that can be applied to assess the ability of each concept to meet performance and safety goals relative to the current UO2 – zirconium alloy system and relative to one another. The resultant ranked evaluation can then inform concept down-selection, such that the most promising accident tolerant fuel design option(s) can continue to be developed for lead test rod or lead test assembly

  7. The DOE advanced gas reactor fuel development and qualification program

    Science.gov (United States)

    Petti, David; Maki, John; Hunn, John; Pappano, Pete; Barnes, Charles; Saurwein, John; Nagley, Scott; Kendall, Jim; Hobbins, Richard

    2010-09-01

    The high outlet temperatures and high thermal-energy conversion efficiency of modular high-temperature gas-cooled reactors (HTGRs) enable an efficient and cost-effective integration of the reactor system with non-electricity-generation applications, such as process heat and/or hydrogen production, for the many petrochemical and other industrial processes that require temperatures between 300°C and 900°C. The U.S. Department of Energy (DOE) has selected the HTGR concept for the Next Generation Nuclear Plant (NGNP) Project as a transformative application of nuclear energy that will demonstrate emissions-free nuclear-assisted electricity, process heat, and hydrogen production, thereby reducing greenhouse-gas emissions and enhancing energy security. The objective of the DOE Advanced Gas Reactor (AGR) Fuel Development and Qualification program is to qualify tristructural isotropic (TRISO)-coated particle fuel for use in HTGRs. An overview of the program and recent progress is presented.

  8. 40 CFR 600.206-93 - Calculation and use of fuel economy values for gasoline-fueled, diesel-fueled, electric, alcohol...

    Science.gov (United States)

    2010-07-01

    ... gallon, will compose the petroleum-based fuel economy for that configuration. (c) If more than one equivalent petroleum-based fuel economy value exists for an electric vehicle configuration, all values for... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Calculation and use of fuel...

  9. Assessment of SFR fuel pin performance codes under advanced fuel for minor actinide transmutation

    Energy Technology Data Exchange (ETDEWEB)

    Bouineau, V.; Lainet, M.; Chauvin, N.; Pelletier, M. [French Alternative Energies and Atomic Energy Commission - CEA, CEA Cadarache, DEN/DEC/SESC, 13108 Saint Paul lez Durance (France); Di Marcello, V.; Van Uffelen, P.; Walker, C. [European Commission, Joint Research Centre, Institute for Transuranium Elements, Hermann-von-Helmholtz-Platz 1, D- 76344 Eggenstein-Leopoldshafen (Germany)

    2013-07-01

    Americium is a strong contributor to the long term radiotoxicity of high activity nuclear waste. Transmutation by irradiation in nuclear reactors of long-lived nuclides like {sup 241}Am is, therefore, an option for the reduction of radiotoxicity and residual power packages as well as the repository area. In the SUPERFACT Experiment four different oxide fuels containing high and low concentrations of {sup 237}Np and {sup 241}Am, representing the homogeneous and heterogeneous in-pile recycling concepts, were irradiated in the PHENIX reactor. The behavior of advanced fuel materials with minor actinide needs to be fully characterized, understood and modeled in order to optimize the design of this kind of fuel elements and to evaluate its performances. This paper assesses the current predictability of fuel performance codes TRANSURANUS and GERMINAL V2 on the basis of post irradiation examinations of the SUPERFACT experiment for pins with low minor actinide content. Their predictions have been compared to measured data in terms of geometrical changes of fuel and cladding, fission gases behavior and actinide and fission product distributions. The results are in good agreement with the experimental results, although improvements are also pointed out for further studies, especially if larger content of minor actinide will be taken into account in the codes. (authors)

  10. Development of the advanced PHWR technology -Design and analysis of CANDU advanced fuel-

    Energy Technology Data Exchange (ETDEWEB)

    Suk, Hoh Chun; Shim, Kee Sub; Byun, Taek Sang; Park, Kwang Suk; Kang, Heui Yung; Kim, Bong Kee; Jung, Chang Joon; Lee, Yung Wook; Bae, Chang Joon; Kwon, Oh Sun; Oh, Duk Joo; Im, Hong Sik; Ohn, Myung Ryong; Lee, Kang Moon; Park, Joo Hwan; Lee, Eui Joon [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1995-07-01

    This is the `94 annual report of the CANDU advanced fuel design and analysis project, and describes CANFLEX fuel design and mechanical integrity analysis, reactor physics analysis and safety analysis of the CANDU-6 with the CANFLEX-NU. The following is the R and D scope of this fiscal year : (1) Detail design of CANFLEX-NU and detail analysis on the fuel integrity, reactor physics and safety. (a) Detail design and mechanical integrity analysis of the bundle (b) CANDU-6 refueling simulation, and analysis on the Xe transients and adjuster system capability (c) Licensing strategy establishment and safety analysis for the CANFLEX-NU demonstration demonstration irradiation in a commercial CANDU-6. (2) Production and revision of CANFLEX-NU fuel design documents (a) Production and approval of CANFLEX-NU reference drawing, and revisions of fuel design manual and technical specifications (b) Production of draft physics design manual. (3) Basic research on CANFLEX-SEU fuel. 55 figs, 21 tabs, 45 refs. (Author).

  11. The Adoption of Advanced Fuel Cycle Technology Under a Single Repository Policy

    Energy Technology Data Exchange (ETDEWEB)

    Paul Wilson

    2009-11-02

    Develops the tools to investiage the hypothesis that the savings in repository space associated with the implementation of advanced nuclear fuel cycles can result in sufficient cost savings to offset the higher costs of those fuel cycles.

  12. 40 CFR 600.206-86 - Calculation and use of fuel economy values for gasoline-fueled, diesel, and electric vehicle...

    Science.gov (United States)

    2010-07-01

    ... part. (b) If only one equivalent petroleum-based fuel economy value exists for an electric... fuel economy for that configuration. (c) If more than one equivalent petroleum-based fuel economy value... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Calculation and use of fuel...

  13. Advanced Coal-Fueled Gas Turbine Program. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  14. Advanced proton-exchange materials for energy efficient fuel cells.

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, Cy H.; Grest, Gary Stephen; Hickner, Michael A.; Cornelius, Christopher James; Staiger, Chad Lynn; Hibbs, Michael R.

    2005-12-01

    The ''Advanced Proton-Exchange Materials for Energy Efficient Fuel Cells'' Laboratory Directed Research and Development (LDRD) project began in October 2002 and ended in September 2005. This LDRD was funded by the Energy Efficiency and Renewable Energy strategic business unit. The purpose of this LDRD was to initiate the fundamental research necessary for the development of a novel proton-exchange membranes (PEM) to overcome the material and performance limitations of the ''state of the art'' Nafion that is used in both hydrogen and methanol fuel cells. An atomistic modeling effort was added to this LDRD in order to establish a frame work between predicted morphology and observed PEM morphology in order to relate it to fuel cell performance. Significant progress was made in the area of PEM material design, development, and demonstration during this LDRD. A fundamental understanding involving the role of the structure of the PEM material as a function of sulfonic acid content, polymer topology, chemical composition, molecular weight, and electrode electrolyte ink development was demonstrated during this LDRD. PEM materials based upon random and block polyimides, polybenzimidazoles, and polyphenylenes were created and evaluated for improvements in proton conductivity, reduced swelling, reduced O{sub 2} and H{sub 2} permeability, and increased thermal stability. Results from this work reveal that the family of polyphenylenes potentially solves several technical challenges associated with obtaining a high temperature PEM membrane. Fuel cell relevant properties such as high proton conductivity (>120 mS/cm), good thermal stability, and mechanical robustness were demonstrated during this LDRD. This report summarizes the technical accomplishments and results of this LDRD.

  15. Metabolic engineering of microorganisms for biofuels production: from bugs to synthetic biology to fuels

    Energy Technology Data Exchange (ETDEWEB)

    Kuk Lee, Sung; Chou, Howard; Ham, Timothy S.; Soon Lee, Taek; Keasling, Jay D.

    2009-12-02

    The ability to generate microorganisms that can produce biofuels similar to petroleum-based transportation fuels would allow the use of existing engines and infrastructure and would save an enormous amount of capital required for replacing the current infrastructure to accommodate biofuels that have properties significantly different from petroleum-based fuels. Several groups have demonstrated the feasibility of manipulating microbes to produce molecules similar to petroleum-derived products, albeit at relatively low productivity (e.g. maximum butanol production is around 20 g/L). For cost-effective production of biofuels, the fuel-producing hosts and pathways must be engineered and optimized. Advances in metabolic engineering and synthetic biology will provide new tools for metabolic engineers to better understand how to rewire the cell in order to create the desired phenotypes for the production of economically viable biofuels.

  16. Advanced LWR Nuclear Fuel Cladding System Development Trade-Off Study

    Energy Technology Data Exchange (ETDEWEB)

    Kristine Barrett; Shannon Bragg-Sitton

    2012-09-01

    The Advanced Light Water Reactor (LWR) Nuclear Fuel Development Research and Development (R&D) Pathway encompasses strategic research focused on improving reactor core economics and safety margins through the development of an advanced fuel cladding system. To achieve significant operating improvements while remaining within safety boundaries, significant steps beyond incremental improvements in the current generation of nuclear fuel are required. Fundamental improvements are required in the areas of nuclear fuel composition, cladding integrity, and the fuel/cladding interaction to allow power uprates and increased fuel burn-up allowance while potentially improving safety margin through the adoption of an “accident tolerant” fuel system that would offer improved coping time under accident scenarios. With a development time of about 20 – 25 years, advanced fuel designs must be started today and proven in current reactors if future reactor designs are to be able to use them with confidence.

  17. Assessment of Startup Fuel Options for the GNEP Advanced Burner Reactor (ABR)

    Energy Technology Data Exchange (ETDEWEB)

    Jon Carmack (062056); Kemal O. Pasamehmetoglu (103171); David Alberstein

    2008-02-01

    The Global Nuclear Energy Program (GNEP) includes a program element for the development and construction of an advanced sodium cooled fast reactor to demonstrate the burning (transmutation) of significant quantities of minor actinides obtained from a separations process and fabricated into a transuranic bearing fuel assembly. To demonstrate and qualify transuranic (TRU) fuel in a fast reactor, an Advanced Burner Reactor (ABR) prototype is needed. The ABR would necessarily be started up using conventional metal alloy or oxide (U or U, Pu) fuel. Startup fuel is needed for the ABR for the first 2 to 4 core loads of fuel in the ABR. Following start up, a series of advanced TRU bearing fuel assemblies will be irradiated in qualification lead test assemblies in the ABR. There are multiple options for this startup fuel. This report provides a description of the possible startup fuel options as well as possible fabrication alternatives available to the program in the current domestic and international facilities and infrastructure.

  18. Advanced Fuel Cycle Economic Tools, Algorithms, and Methodologies

    Energy Technology Data Exchange (ETDEWEB)

    David E. Shropshire

    2009-05-01

    The Advanced Fuel Cycle Initiative (AFCI) Systems Analysis supports engineering economic analyses and trade-studies, and requires a requisite reference cost basis to support adequate analysis rigor. In this regard, the AFCI program has created a reference set of economic documentation. The documentation consists of the “Advanced Fuel Cycle (AFC) Cost Basis” report (Shropshire, et al. 2007), “AFCI Economic Analysis” report, and the “AFCI Economic Tools, Algorithms, and Methodologies Report.” Together, these documents provide the reference cost basis, cost modeling basis, and methodologies needed to support AFCI economic analysis. The application of the reference cost data in the cost and econometric systems analysis models will be supported by this report. These methodologies include: the energy/environment/economic evaluation of nuclear technology penetration in the energy market—domestic and internationally—and impacts on AFCI facility deployment, uranium resource modeling to inform the front-end fuel cycle costs, facility first-of-a-kind to nth-of-a-kind learning with application to deployment of AFCI facilities, cost tradeoffs to meet nuclear non-proliferation requirements, and international nuclear facility supply/demand analysis. The economic analysis will be performed using two cost models. VISION.ECON will be used to evaluate and compare costs under dynamic conditions, consistent with the cases and analysis performed by the AFCI Systems Analysis team. Generation IV Excel Calculations of Nuclear Systems (G4-ECONS) will provide static (snapshot-in-time) cost analysis and will provide a check on the dynamic results. In future analysis, additional AFCI measures may be developed to show the value of AFCI in closing the fuel cycle. Comparisons can show AFCI in terms of reduced global proliferation (e.g., reduction in enrichment), greater sustainability through preservation of a natural resource (e.g., reduction in uranium ore depletion), value from

  19. Science based integrated approach to advanced nuclear fuel development - vision, approach, and overview

    Energy Technology Data Exchange (ETDEWEB)

    Unal, Cetin [Los Alamos National Laboratory; Pasamehmetoglu, Kemal [IDAHO NATIONAL LAB; Carmack, Jon [IDAHO NATIONAL LAB

    2010-01-01

    Advancing the performance of Light Water Reactors, Advanced Nuclear Fuel Cycles, and Advanced Rcactors, such as the Next Generation Nuclear Power Plants, requires enhancing our fundamental understanding of fuel and materials behavior under irradiation. The capability to accurately model the nuclear fuel systems is critical. In order to understand specific aspects of the nuclear fuel, fully coupled fuel simulation codes are required to achieve licensing of specific nuclear fuel designs for operation. The backbone of these codes, models, and simulations is a fundamental understanding and predictive capability for simulating the phase and microstructural behavior of the nuclear fuel system materials and matrices. The purpose of this paper is to identify the modeling and simulation approach in order to deliver predictive tools for advanced fuels development. The coordination between experimental nuclear fuel design, development technical experts, and computational fuel modeling and simulation technical experts is a critical aspect of the approach and naturally leads to an integrated, goal-oriented science-based R & D approach and strengthens both the experimental and computational efforts. The Advanced Fuels Campaign (AFC) and Nuclear Energy Advanced Modeling and Simulation (NEAMS) Fuels Integrated Performance and Safety Code (IPSC) are working together to determine experimental data and modeling needs. The primary objective of the NEAMS fuels IPSC project is to deliver a coupled, three-dimensional, predictive computational platform for modeling the fabrication and both normal and abnormal operation of nuclear fuel pins and assemblies, applicable to both existing and future reactor fuel designs. The science based program is pursuing the development of an integrated multi-scale and multi-physics modeling and simulation platform for nuclear fuels. This overview paper discusses the vision, goals and approaches how to develop and implement the new approach.

  20. Enabling Advanced Modeling and Simulations for Fuel-Flexible Combustors

    Energy Technology Data Exchange (ETDEWEB)

    Heinz Pitsch

    2010-05-31

    The overall goal of the present project is to enable advanced modeling and simulations for the design and optimization of fuel-flexible turbine combustors. For this purpose we use a high-fidelity, extensively-tested large-eddy simulation (LES) code and state-of-the-art models for premixed/partially-premixed turbulent combustion developed in the PI's group. In the frame of the present project, these techniques are applied, assessed, and improved for hydrogen enriched premixed and partially premixed gas-turbine combustion. Our innovative approaches include a completely consistent description of flame propagation, a coupled progress variable/level set method to resolve the detailed flame structure, and incorporation of thermal-diffusion (non-unity Lewis number) effects. In addition, we have developed a general flamelet-type transformation holding in the limits of both non-premixed and premixed burning. As a result, a model for partially premixed combustion has been derived. The coupled progress variable/level method and the general flamelet tranformation were validated by LES of a lean-premixed low-swirl burner that has been studied experimentally at Lawrence Berkeley National Laboratory. The model is extended to include the non-unity Lewis number effects, which play a critical role in fuel-flexible combustor with high hydrogen content fuel. More specifically, a two-scalar model for lean hydrogen and hydrogen-enriched combustion is developed and validated against experimental and direct numerical simulation (DNS) data. Results are presented to emphasize the importance of non-unity Lewis number effects in the lean-premixed low-swirl burner of interest in this project. The proposed model gives improved results, which shows that the inclusion of the non-unity Lewis number effects is essential for accurate prediction of the lean-premixed low-swirl flame.

  1. Enabling Advanced Modeling and Simulations for Fuel-Flexible Combustors

    Energy Technology Data Exchange (ETDEWEB)

    Pitsch, Heinz

    2010-05-31

    The overall goal of the present project is to enable advanced modeling and simulations for the design and optimization of fuel-flexible turbine combustors. For this purpose we use a high fidelity, extensively-tested large-eddy simulation (LES) code and state-of-the-art models for premixed/partially-premixed turbulent combustion developed in the PI's group. In the frame of the present project, these techniques are applied, assessed, and improved for hydrogen enriched premixed and partially premixed gas-turbine combustion. Our innovative approaches include a completely consistent description of flame propagation; a coupled progress variable/level set method to resolve the detailed flame structure, and incorporation of thermal-diffusion (non-unity Lewis number) effects. In addition, we have developed a general flamelet-type transformation holding in the limits of both non-premixed and premixed burning. As a result, a model for partially premixed combustion has been derived. The coupled progress variable/level method and the general flamelet transformation were validated by LES of a lean-premixed low-swirl burner that has been studied experimentally at Lawrence Berkeley National Laboratory. The model is extended to include the non-unity Lewis number effects, which play a critical role in fuel-flexible combustor with high hydrogen content fuel. More specifically, a two-scalar model for lean hydrogen and hydrogen-enriched combustion is developed and validated against experimental and direct numerical simulation (DNS) data. Results are presented to emphasize the importance of non-unity Lewis number effects in the lean-premixed low-swirl burner of interest in this project. The proposed model gives improved results, which shows that the inclusion of the non-unity Lewis number effects is essential for accurate prediction of the lean-premixed low-swirl flame.

  2. Development of Advanced High Uranium Density Fuels for Light Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Blanchard, James [Univ. of Wisconsin, Madison, WI (United States); Butt, Darryl [Boise State Univ., ID (United States); Meyer, Mitchell [Idaho National Lab. (INL), Idaho Falls, ID (United States); Xu, Peng [Westinghouse Electric Corporation, Pittsburgh, PA (United States)

    2016-02-15

    This work conducts basic materials research (fabrication, radiation resistance, thermal conductivity, and corrosion response) on U3Si2 and UN, two high uranium density fuel forms that have a high potential for success as advanced light water reactor (LWR) fuels. The outcome of this proposed work will serve as the basis for the development of advance LWR fuels, and utilization of such fuel forms can lead to the optimization of the fuel performance related plant operating limits such as power density, power ramp rate and cycle length.

  3. Reactor Physics and Criticality Benchmark Evaluations for Advanced Nuclear Fuel - Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    William Anderson; James Tulenko; Bradley Rearden; Gary Harms

    2008-09-11

    The nuclear industry interest in advanced fuel and reactor design often drives towards fuel with uranium enrichments greater than 5 wt% 235U. Unfortunately, little data exists, in the form of reactor physics and criticality benchmarks, for uranium enrichments ranging between 5 and 10 wt% 235U. The primary purpose of this project is to provide benchmarks for fuel similar to what may be required for advanced light water reactors (LWRs). These experiments will ultimately provide additional information for application to the criticality-safety bases for commercial fuel facilities handling greater than 5 wt% 235U fuel.

  4. Meeting Summary Advanced Light Water Reactor Fuels Industry Meeting Washington DC October 27 - 28, 2011

    Energy Technology Data Exchange (ETDEWEB)

    Not Listed

    2011-11-01

    The Advanced LWR Fuel Working Group first met in November of 2010 with the objective of looking 20 years ahead to the role that advanced fuels could play in improving light water reactor technology, such as waste reduction and economics. When the group met again in March 2011, the Fukushima incident was still unfolding. After the March meeting, the focus of the program changed to determining what we could do in the near term to improve fuel accident tolerance. Any discussion of fuels with enhanced accident tolerance will likely need to consider an advanced light water reactor with enhanced accident tolerance, along with the fuel. The Advanced LWR Fuel Working Group met in Washington D.C. on October 72-18, 2011 to continue discussions on this important topic.

  5. Econometric comparisons of liquid rocket engines for dual-fuel advanced earth-to-orbit shuttles

    Science.gov (United States)

    Martin, J. A.

    1978-01-01

    Econometric analyses of advanced Earth-to-orbit vehicles indicate that there are economic benefits from development of new vehicles beyond the space shuttle as traffic increases. Vehicle studies indicate the advantage of the dual-fuel propulsion in single-stage vehicles. This paper shows the economic effect of incorporating dual-fuel propulsion in advanced vehicles. Several dual-fuel propulsion systems are compared to a baseline hydrogen and oxygen system.

  6. Extending the world's uranium resources through advanced CANDU fuel cycles

    Energy Technology Data Exchange (ETDEWEB)

    De Vuono, Tony; Yee, Frank; Aleyaseen, Val; Kuran, Sermet; Cottrell, Catherine

    2010-09-15

    The growing demand for nuclear power will encourage many countries to undertake initiatives to ensure a self-reliant fuel source supply. Uranium is currently the only fuel utilized in nuclear reactors. There are increasing concerns that primary uranium sources will not be enough to meet future needs. AECL has developed a fuel cycle vision that incorporates other sources of advanced fuels to be adaptable to its CANDU technology.

  7. A review on the development of the advanced fuel fabrication technology

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jung Won; Lee, Yung Woo; Sohn, Dong Sung; Yang, Myung Seung; Bae, Kee Kwang; Nah, Sang Hoh; Kim, Han Soo; Kim, Bong Koo; Song, Keun Woo; Kim, See Hyung [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1995-07-01

    In this state-of art report, the development status of the advanced nuclear fuel was investigated. The current fabrication technology for coated particle fuel and non-oxide fuel such as sol-gel technology, coating technology, and carbothermic reduction reaction has also been examined. In the view point of inherent safety and efficiency in the operation of power plant, the coated particle fuel will keep going on its reputation as nuclear fuel for a high temperature gas cooled reactor, and the nitride fuel is very prospective for the next liquid metal fast breeder reactor. 43 figs., 17 tabs., 96 refs. (Author).

  8. Masters Study in Advanced Energy and Fuels Management

    Energy Technology Data Exchange (ETDEWEB)

    Mondal, Kanchan [Southern Illinois Univ., Carbondale, IL (United States)

    2014-12-08

    There are currently three key drivers for the US energy sector a) increasing energy demand and b) environmental stewardship in energy production for sustainability and c) general public and governmental desire for domestic resources. These drivers are also true for energy nation globally. As a result, this sector is rapidly diversifying to alternate sources that would supplement or replace fossil fuels. These changes have created a need for a highly trained workforce with a the understanding of both conventional and emerging energy resources and technology to lead and facilitate the reinvention of the US energy production, rational deployment of alternate energy technologies based on scientific and business criteria while invigorating the overall economy. In addition, the current trends focus on the the need of Science, Technology, Engineering and Math (STEM) graduate education to move beyond academia and be more responsive to the workforce needs of businesses and the industry. The SIUC PSM in Advanced Energy and Fuels Management (AEFM) program was developed in response to the industries stated need for employees who combine technical competencies and workforce skills similar to all PSM degree programs. The SIUC AEFM program was designed to provide the STEM graduates with advanced technical training in energy resources and technology while simultaneously equipping them with the business management skills required by professional employers in the energy sector. Technical training include core skills in energy resources, technology and management for both conventional and emerging energy technologies. Business skills training include financial, personnel and project management. A capstone internship is also built into the program to train students such that they are acclimatized to the real world scenarios in research laboratories, in energy companies and in government agencies. The current curriculum in the SIUC AEFM will help fill the need for training both recent

  9. Alternative Fuel and Advanced Technology Commercial Lawn Equipment (Spanish version); Clean Cities, Energy Efficiency & Renewable Energy (EERE)

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, Erik

    2015-06-01

    Powering commercial lawn equipment with alternative fuels or advanced engine technology is an effective way to reduce U.S. dependence on petroleum, reduce harmful emissions, and lessen the environmental impacts of commercial lawn mowing. Numerous alternative fuel and fuel-efficient advanced technology mowers are available. Owners turn to these mowers because they may save on fuel and maintenance costs, extend mower life, reduce fuel spillage and fuel theft, and demonstrate their commitment to sustainability.

  10. Recent Advances in Enzymatic Fuel Cells: Experiments and Modeling

    Directory of Open Access Journals (Sweden)

    Ivan Ivanov

    2010-04-01

    Full Text Available Enzymatic fuel cells convert the chemical energy of biofuels into electrical energy. Unlike traditional fuel cell types, which are mainly based on metal catalysts, the enzymatic fuel cells employ enzymes as catalysts. This fuel cell type can be used as an implantable power source for a variety of medical devices used in modern medicine to administer drugs, treat ailments and monitor bodily functions. Some advantages in comparison to conventional fuel cells include a simple fuel cell design and lower cost of the main fuel cell components, however they suffer from severe kinetic limitations mainly due to inefficiency in electron transfer between the enzyme and the electrode surface. In this review article, the major research activities concerned with the enzymatic fuel cells (anode and cathode development, system design, modeling by highlighting the current problems (low cell voltage, low current density, stability will be presented.

  11. Fuel economy screening study of advanced automotive gas turbine engines

    Science.gov (United States)

    Klann, J. L.

    1980-01-01

    Fuel economy potentials were calculated and compared among ten turbomachinery configurations. All gas turbine engines were evaluated with a continuously variable transmission in a 1978 compact car. A reference fuel economy was calculated for the car with its conventional spark ignition piston engine and three speed automatic transmission. Two promising engine/transmission combinations, using gasoline, had 55 to 60 percent gains over the reference fuel economy. Fuel economy sensitivities to engine design parameter changes were also calculated for these two combinations.

  12. Advanced manufacturing technologies for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Uhlenbruck, S.; Nedelec, R.; Buchkremer, H.P.; Bram, M.; Menzler, N.H.; Stover, D. [Forschungszentrum Julich GmbH, Julich (Germany). Inst. of Energy Research

    2009-07-01

    Advances in manufacturing technologies play an important role for the marketability of solid oxide fuel cells (SOFC). Highly cost-effective mass production methods are necessary in order to meet the industry's demands for both stationary and mobile application. Sol-gel methods have already been used for several years as a method of producing thin mesoporous and microporous membrane films of several materials including electrolyte materials. This paper discussed the use of a colloidal sol to create a first layer on top of a standard Julich coatmix-substrate with the spin-coating technique. The experimental methods were described with particular reference to the electrochemical characterization of cells produced; synchronization of roll-coating transport; and scanning electron microscopy. It was concluded that thin-film technologies like sol-gel, roll-coating and physical vapour phase deposition are promising candidates for producing SOFCs with high-performance at low operating temperatures. It was possible to demonstrate the potential of thin film technology for sputtered strontium-diffusion barriers, but optimization of the current ceramic coating methods is still necessary for the electrolyte layers. 3 refs., 8 figs.

  13. Development of advanced fuel cell system, phase 3

    Science.gov (United States)

    Handley, L. M.; Meyer, A. P.; Bell, W. F.

    1975-01-01

    A multiple task research and development program was performed to improve the weight, life, and performance characteristics of hydrogen-oxygen alkaline fuel cells for advanced power systems. Gradual wetting of the anode structure and subsequent long-term performance loss was determined to be caused by deposition of a silicon-containing material on the anode. This deposit was attributed to degradation of the asbestos matrix, and attention was therefore placed on development of a substitute matrix of potassium titanate. An 80 percent gold 20 percent platinum catalyst cathode was developed which has the same performance and stability as the standard 90 percent gold - 10 percent platinum cathode but at half the loading. A hybrid polysulfone/epoxy-glass fiber frame was developed which combines the resistance to the cell environment of pure polysulfone with the fabricating ease of epoxy-glass fiber laminate. These cell components were evaluated in various configurations of full-size cells. The ways in which the baseline engineering model system would be modified to accommodate the requirements of the space tug application are identified.

  14. The DOE Advanced Gas Reactor (AGR) Fuel Development and Qualification Program

    Energy Technology Data Exchange (ETDEWEB)

    David Petti; Hans Gougar; Gary Bell

    2005-05-01

    The Department of Energy has established the Advanced Gas Reactor Fuel Development and Qualification Program to address the following overall goals: Provide a baseline fuel qualification data set in support of the licensing and operation of the Next Generation Nuclear Plant (NGNP). Gas-reactor fuel performance demonstration and qualification comprise the longest duration research and development (R&D) task for the NGNP feasibility. The baseline fuel form is to be demonstrated and qualified for a peak fuel centerline temperature of 1250°C. Support near-term deployment of an NGNP by reducing market entry risks posed by technical uncertainties associated with fuel production and qualification. Utilize international collaboration mechanisms to extend the value of DOE resources. The Advanced Gas Reactor Fuel Development and Qualification Program consists of five elements: fuel manufacture, fuel and materials irradiations, postirradiation examination (PIE) and safety testing, fuel performance modeling, and fission product transport and source term evaluation. An underlying theme for the fuel development work is the need to develop a more complete fundamental understanding of the relationship between the fuel fabrication process, key fuel properties, the irradiation performance of the fuel, and the release and transport of fission products in the NGNP primary coolant system. Fuel performance modeling and analysis of the fission product behavior in the primary circuit are important aspects of this work. The performance models are considered essential for several reasons, including guidance for the plant designer in establishing the core design and operating limits, and demonstration to the licensing authority that the applicant has a thorough understanding of the in-service behavior of the fuel system. The fission product behavior task will also provide primary source term data needed for licensing. An overview of the program and recent progress will be presented.

  15. 40 CFR 600.207-08 - Calculation and use of vehicle-specific 5-cycle-based fuel economy values for vehicle...

    Science.gov (United States)

    2010-07-01

    .... (b) If only one equivalent petroleum-based fuel economy value exists for an electric configuration...-cycle fuel economy for that configuration. (c) If more than one equivalent petroleum-based 5-cycle fuel...-specific 5-cycle-based fuel economy values for vehicle configurations. 600.207-08 Section...

  16. Fuel fragmentation model advances using TEXAS-V

    Energy Technology Data Exchange (ETDEWEB)

    Corradini, M.L.; El-Beshbeeshy, M.; Nilsuwankowsit, S.; Tang, J. [Wisconsin Univ., Madison, WI (United States). Dept. of Nuclear Engineering and Engineering Physics

    1998-01-01

    Because an energetic fuel-coolant interaction may be a safety hazard, experiments are being conducted to investigate the fuel-coolant mixing/quenching process (FARO) as well as the energetics of vapor explosion propagation for high temperature fuel melt simulants (KROTOS, WFCI, ZrEX). In both types of experiments, the dynamic breakup of the fuel is one of the key aspects that must be fundamentally understood to better estimate the magnitude of the mixing/quenching process or the explosion energetics. To aid our understanding the TEXAS fuel-coolant interaction computer model has been developed and is being used to analyze these experiments. Recently, the models for dynamic fuel fragmentation during the mixing and explosion phases of the FCI have been improved by further insights into these processes. The purpose of this paper is to describe these enhancements and to demonstrate their improvements by analysis of particular JRC FCI data. (author)

  17. JAEA key facilities for global advanced fuel cycle R and D

    Energy Technology Data Exchange (ETDEWEB)

    Nomura, Shigeo; Yamamoto, Ryuichi [Nuclear Fuel Cycle Engineering Labos, JAEA, 4-33 Tokai-mura, Ibaraki, 319-1194 (Japan)

    2008-07-01

    Advanced fuel cycle will be realized with the mid and long term R and D during the long-term transition period from LWR cycle to advanced reactor fuel cycle. Most of JAEA facilities have been utilized to establish the current LWR and FBR (Fast Breeder Reactor) fuel cycle by implementing evolutionary R and D. An assessment of today's state experimental facilities concerning the following research issues: reprocessing, Mox fuel fabrication, irradiation and post-irradiation examination, waste management and nuclear data measurement, is made. The revolutionary R and D requests new issues to be studied: the TRU multi-recycling, minor actinide recycling, the assessment of proliferation resistance and the assessment of cost reduction. To implement the revolutionary R and D for advanced fuel cycle, however, these facilities should be refurbished to install new machines and process equipment to provide more flexible testing parameters.

  18. Metabolic engineering of microbial pathways for advanced biofuels production.

    Science.gov (United States)

    Zhang, Fuzhong; Rodriguez, Sarah; Keasling, Jay D

    2011-12-01

    Production of biofuels from renewable resources such as cellulosic biomass provides a source of liquid transportation fuel to replace petroleum-based fuels. This endeavor requires the conversion of cellulosic biomass into simple sugars, and the conversion of simple sugars into biofuels. Recently, microorganisms have been engineered to convert simple sugars into several types of biofuels, such as alcohols, fatty acid alkyl esters, alkanes, and terpenes, with high titers and yields. Here, we review recently engineered biosynthetic pathways from the well-characterized microorganisms Escherichia coli and Saccharomyces cerevisiae for the production of several advanced biofuels.

  19. Advanced Composite Bipolar Plate for Unitized Regenerative Fuel Cell/Electrolyzer Systems Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Development of an advanced composite bipolar plate is proposed for a unitized regenerative fuel cell and electrolyzer system that operates on pure feed streams...

  20. CHF Enhancement of Advanced 37-Element Fuel Bundles

    Directory of Open Access Journals (Sweden)

    Joo Hwan Park

    2015-01-01

    Full Text Available A standard 37-element fuel bundle (37S fuel bundle has been used in commercial CANDU reactors for over 40 years as a reference fuel bundle. Most CHF of a 37S fuel bundle have occurred at the elements arranged in the inner pitch circle for high flows and at the elements arranged in the outer pitch circle for low flows. It should be noted that a 37S fuel bundle has a relatively small flow area and high flow resistance at the peripheral subchannels of its center element compared to the other subchannels. The configuration of a fuel bundle is one of the important factors affecting the local CHF occurrence. Considering the CHF characteristics of a 37S fuel bundle in terms of CHF enhancement, there can be two approaches to enlarge the flow areas of the peripheral subchannels of a center element in order to enhance CHF of a 37S fuel bundle. To increase the center subchannel areas, one approach is the reduction of the diameter of a center element, and the other is an increase of the inner pitch circle. The former can increase the total flow area of a fuel bundle and redistributes the power density of all fuel elements as well as the CHF. On the other hand, the latter can reduce the gap between the elements located in the middle and inner pitch circles owing to the increasing inner pitch circle. This can also affect the enthalpy redistribution of the fuel bundle and finally enhance CHF or dry-out power. In this study, the above two approaches, which are proposed to enlarge the flow areas of the center subchannels, were considered to investigate the impact of the flow area changes of the center subchannels on the CHF enhancement as well as the thermal characteristics by applying a subchannel analysis method.

  1. An examination of the elastic structural response of the Advanced Neutron Source fuel plates

    Energy Technology Data Exchange (ETDEWEB)

    Swinson, W.F.; Luttrell, C.R.; Yahr, G.T.

    1994-09-01

    Procedures for evaluating the elastic structural response of the Advanced Neutron Source (ANS) fuel plates to coolant flow and to temperature variations are presented in this report. Calculations are made that predict the maximum deflection and the maximum stress for a representative plate from the upper and from the lower fuel elements.

  2. 10 CFR 71.97 - Advance notification of shipment of irradiated reactor fuel and nuclear waste.

    Science.gov (United States)

    2010-01-01

    ... fuel and nuclear waste. 71.97 Section 71.97 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) PACKAGING... notification of shipment of irradiated reactor fuel and nuclear waste. (a) As specified in paragraphs (b), (c... advance notification of transportation of nuclear waste was published in the Federal Register on June...

  3. Advanced fuel developments for an industrial accelerator driven system prototype

    Energy Technology Data Exchange (ETDEWEB)

    Delage, Fabienne; Ottaviani, Jean Pierre [Commissariat a l' Energie Atomique CEA (France); Fernandez-Carretero, Asuncion; Staicu, Dragos [JRC-ITU (Germany); Boccaccini, Claudia-Matzerath; Chen, Xue-Nong; Mascheck, Werner; Rineiski, Andrei [Forschungszentrum Karlsruhe - FZK (Germany); D' Agata, Elio [JRC-IE (Netherlands); Klaassen, Frodo [NRG, PO Box 25, NL-1755 ZG Petten (Netherlands); Sobolev, Vitaly [SCK-CEN (Belgium); Wallenius, Janne [KTH Royal Institute of Technology (Sweden); Abram, T. [National Nuclear Laboratory - NNL (United Kingdom)

    2009-06-15

    Fuel to be used in an Accelerator Driven System (ADS) for transmutation in a fast spectrum, can be described as a highly innovative concept in comparison with fuels used in critical cores. ADS fuel is not fertile, so as to improve the transmutation performance. It necessarily contains a high concentration ({approx}50%) of minor actinides and plutonium. This unusual fuel composition results in high gamma and neutron emissions during its fabrication, as well as degraded core performance. So, an optimal ADS fuel is based on finding the best compromise between thermal, mechanical, chemical, neutronic and technological constraints. CERCER and CERMET composite fuels consisting of particles of (Pu,MA)O{sub 2} phases dispersed in a magnesia or molybdenum matrix are under investigation within the frame of the ongoing European Integrated Project EUROTRANS (European Research programme for Transmutation) which aims at performing a conceptual design of a 400 MWth transmuter: the European Facility for Industrial Transmutation (EFIT). Performances and safety of EFIT cores loaded with CERCER and CERMET fuels have been evaluated. Out-of-pile and in-pile experiments are carried out to gain knowledge on the properties and the behaviour of these fuels. The current paper gives an overview of the work progress. (authors)

  4. Dimethyl ether (DME) as an alternative fuel

    Science.gov (United States)

    Semelsberger, Troy A.; Borup, Rodney L.; Greene, Howard L.

    With ever growing concerns on environmental pollution, energy security, and future oil supplies, the global community is seeking non-petroleum based alternative fuels, along with more advanced energy technologies (e.g., fuel cells) to increase the efficiency of energy use. The most promising alternative fuel will be the fuel that has the greatest impact on society. The major impact areas include well-to-wheel greenhouse gas emissions, non-petroleum feed stocks, well-to-wheel efficiencies, fuel versatility, infrastructure, availability, economics, and safety. Compared to some of the other leading alternative fuel candidates (i.e., methane, methanol, ethanol, and Fischer-Tropsch fuels), dimethyl ether appears to have the largest potential impact on society, and should be considered as the fuel of choice for eliminating the dependency on petroleum. DME can be used as a clean high-efficiency compression ignition fuel with reduced NO x, SO x, and particulate matter, it can be efficiently reformed to hydrogen at low temperatures, and does not have large issues with toxicity, production, infrastructure, and transportation as do various other fuels. The literature relevant to DME use is reviewed and summarized to demonstrate the viability of DME as an alternative fuel.

  5. Advanced Diagnostics in Oxy-Fuel Combustion Processes

    DEFF Research Database (Denmark)

    Brix, Jacob; Toftegaard, Maja Bøg; Clausen, Sønnik

    , formed the basis of a publication and it is part of two PhD dissertations. The name of the conference the journal and the dissertations are listed below. - Joint Meeting of the Scandinavian-Nordic and French Sections of the Combustion Institute, Combustion of Char Particles under Oxy-Fuel Conditions......: Formation of NO and Particle Temperature, Copenhagen, 9-10 November 2009. - Brix J, Navascués LG, Joachim, Nielsen JB, Bonnek PL, Larsen HE, Clausen S, Glarborg P, Jensen AD, Oxy-Fuel Combustion of Coal Char: Particle Temperature and NO Formation, Submitted to Fuel on the 19th of November 2010. - Brix J......, Oxy-Fuel Combustion of Coal, Ph.D. Thesis, CHEC Research Centre – Technical University of Denmark, 2011. - Toftegaard, MB, OxyFuel Combustion of Coal and Biomass, Ph.D. Thesis, CHEC Research Centre – Technical University of Denmark, 2011. In addition two students projects have been carried out...

  6. Advanced anodes for high-temperature fuel cells

    DEFF Research Database (Denmark)

    Atkinson, A.; Barnett, S.; Gorte, R.J.;

    2004-01-01

    Fuel cells will undoubtedly find widespread use in this new millennium in the conversion of chemical to electrical energy, as they offer very high efficiencies and have unique scalability in electricity-generation applications. The solid-oxide fuel cell (SOFC) is one of the most exciting...... of these energy technologies; it is an all-ceramic device that operates at temperatures in the range 500-1,000degreesC. The SOFC offers certain advantages over lower temperature fuel cells, notably its ability to use carbon monoxide as a fuel rather than being poisoned by it, and the availability of high......-grade exhaust heat for combined heat and power, or combined cycle gas-turbine applications. Although cost is clearly the most important barrier to widespread SOFC implementation, perhaps the most important technical barriers currently being addressed relate to the electrodes, particularly the fuel electrode...

  7. Screening of advanced cladding materials and UN-U3Si5 fuel

    Science.gov (United States)

    Brown, Nicholas R.; Todosow, Michael; Cuadra, Arantxa

    2015-07-01

    In the aftermath of Fukushima, a focus of the DOE-NE Advanced Fuels Campaign has been the development of advanced nuclear fuel and cladding options with the potential for improved performance in an accident. Uranium dioxide (UO2) fuels with various advanced cladding materials were analyzed to provide a reference for cladding performance impacts. For advanced cladding options with UO2 fuel, most of the cladding materials have some reactivity and discharge burn-up penalty (in GWd/t). Silicon carbide is one exception in that the reactor physics performance is predicted to be very similar to zirconium alloy cladding. Most candidate claddings performed similar to UO2-Zr fuel-cladding in terms of safety coefficients. The clear exception is that Mo-based materials were identified as potentially challenging from a reactor physics perspective due to high resonance absorption. This paper also includes evaluation of UN-U3Si5 fuels with Kanthal AF or APMT cladding. The objective of the U3Si5 phase in the UN-U3Si5 fuel concept is to shield the nitride phase from water. It was shown that UN-U3Si5 fuels with Kanthal AF or APMT cladding have similar reactor physics and fuel management performance over a wide parameter space of phase fractions when compared to UO2-Zr fuel-cladding. There will be a marginal penalty in discharge burn-up (in GWd/t) and the sensitivity to 14N content in UN ceramic composites is high. Analysis of the rim effect due to self-shielding in the fuel shows that the UN-based ceramic fuels are not expected to have significantly different relative burn-up distributions at discharge relative to the UO2 reference fuel. However, the overall harder spectrum in the UN ceramic composite fuels increases transuranic build-up, which will increase long-term activity in a once-thru fuel cycle but is expected to be a significant advantage in a fuel cycle with continuous recycling of transuranic material. It is recognized that the fuel and cladding properties assumed in

  8. Organic coal-water fuel: Problems and advances (Review)

    Science.gov (United States)

    Glushkov, D. O.; Strizhak, P. A.; Chernetskii, M. Yu.

    2016-10-01

    The study results of ignition of organic coal-water fuel (OCWF) compositions were considered. The main problems associated with investigation of these processes were identified. Historical perspectives of the development of coal-water composite fuel technologies in Russia and worldwide are presented. The advantages of the OCWF use as a power-plant fuel in comparison with the common coal-water fuels (CWF) were emphasized. The factors (component ratio, grinding degree of solid (coal) component, limiting temperature of oxidizer, properties of liquid and solid components, procedure and time of suspension preparation, etc.) affecting inertia and stability of the ignition processes of suspensions based on the products of coaland oil processing (coals of various types and metamorphism degree, filter cakes, waste motor, transformer, and turbine oils, water-oil emulsions, fuel-oil, etc.) were analyzed. The promising directions for the development of modern notions on the OCWF ignition processes were determined. The main reasons limiting active application of the OCWF in power generation were identified. Characteristics of ignition and combustion of coal-water and organic coal-water slurry fuels were compared. The effect of water in the composite coal fuels on the energy characteristics of their ignition and combustion, as well as ecological features of these processes, were elucidated. The current problems associated with pulverization of composite coal fuels in power plants, as well as the effect of characteristics of the pulverization process on the combustion parameters of fuel, were considered. The problems hindering the development of models of ignition and combustion of OCWF were analyzed. It was established that the main one was the lack of reliable experimental data on the processes of heating, evaporation, ignition, and combustion of OCWF droplets. It was concluded that the use of high-speed video recording systems and low-inertia sensors of temperature and gas

  9. Evaluation of Particle Counter Technology for Detection of Fuel Contamination Detection Utilizing Advanced Aviation Forward Area Refueling System

    Science.gov (United States)

    2014-01-24

    UNCLASSIFIED 6 UNCLASSIFIED Receipt Vehicle Fuel Tank Fuel Injector Aviation Fuel DEF (AUST) 5695B 18/16/13 Parker 18/16/13 14/10/7 Pamas... Alcohol to Jet (ATJ) fuel flight testing at Redstone Test Center, TARDEC was afforded the opportunity to evaluate light obscuration particle counters on...Advanced Aviation Forward Area Refueling System (AAFARS) setup for Alcohol to Jet (ATJ) fuel flight testing. Figure 2. AAFARS fuel sampling port

  10. ACSEPT, Toward the Future Demonstration of Advanced Fuel Treatments

    Energy Technology Data Exchange (ETDEWEB)

    Bourg, Stephane; Hill, Clement [CEA/DEN/MAR/DRCP, Marcoule, BP17171, 30207 Bagnols/ceze (France); Caravaca, Concha [CIEMAT (Spain); Ekberg, Christian [CHALMERS University (Sweden); Rhodes, Chris [Nuclear National Laboratory (United Kingdom)

    2009-06-15

    Actinide recycling by separation and transmutation is considered worldwide and particularly in several European countries as one of the most promising strategies to reduce the inventory of radioactive waste and to optimize the use of natural resources, thus contributing to making nuclear energy sustainable. In accordance with the Strategic Research Agenda (SRA) of the Sustainable Nuclear Energy Technology Platform (SNE-TP), the timelines of the FP7-EURATOM project ACSEPT (2008-2012) should allow the offering of technical solutions in terms of advanced closed fuel cycle technologies including the recycling of actinides and that may be reviewed by Governments, European utilities as well as Technology Providers at the time horizon 2012. By joining in its consortium 34 partners from 12 European countries plus Australia and Japan, ACSEPT is thus an essential contribution to the demonstration, in the long term, of the potential benefits of actinide recycling. To succeed, ACSEPT is organized into three technical domains: (i) Considering technically mature aqueous separation processes, ACSEPT works to optimize and select the most promising ones dedicated either to actinide partitioning or to grouped actinide separation. A substantial review was undertaken either to be sure that the right molecule families are being studied, or, on the contrary, to identify new candidates. After 18 months, results of the first hot tests should allow the validation of some process options. In addition, the first results on dissolution studies will be available as well as the progress in conversion techniques. (ii) Concerning pyrochemical separation processes, ACSEPT is focused on the enhancement of the two reference cores of process selected within EUROPART with specific attention to the exhaustive electrolysis in molten chloride (quantitative recovery of the actinides with the lowest amount of fission products) and to actinide back-extraction from an An-Al alloy. R and D efforts are also

  11. Advanced Space Power Systems (ASPS): Regenerative Fuel Cells (RFC) Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The objective of the regenerative fuel cell project element is to develop power and energy storage technologies that enable new capabilities for future human space...

  12. SunLine Transit Agency Advanced Technology Fuel Cell Bus Evaluation: First Results Report

    Energy Technology Data Exchange (ETDEWEB)

    Eudy, L.; Chandler, K.

    2011-03-01

    This report describes operations at SunLine Transit Agency for their newest prototype fuel cell bus and five compressed natural gas (CNG) buses. In May 2010, SunLine began operating its sixth-generation hydrogen fueled bus, an Advanced Technology (AT) fuel cell bus that incorporates the latest design improvements to reduce weight and increase reliability and performance. The agency is collaborating with the U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) to evaluate the bus in revenue service. This report provides the early data results and implementation experience of the AT fuel cell bus since it was placed in service.

  13. Advances in the development of a hydrogen/oxygen PEM fuel cell stack

    Energy Technology Data Exchange (ETDEWEB)

    Tori, C.; Garaventta, G.; Visintin, A.; Triaca, W.E. [Instituto de Investigaciones Fisicoquimicas Teoricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CC 16, Suc. 4 (1900) La Plata (Argentina); Baleztena, M.; Peralta, C.; Calzada, R.; Jorge, E. [Grupo de Investigacion en Energias Sustentables y Eficiencia Energetica (GIESEE), Departamento de Electrotecnia, Universidad Tecnologica Nacional, Facultad Regional La Plata, Av. 60 esq. 124 (1900) La Plata (Argentina); Barsellini, D. [Instituto de Investigaciones Fisicoquimicas Teoricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CC 16, Suc. 4 (1900) La Plata (Argentina); Grupo de Investigacion en Energias Sustentables y Eficiencia Energetica (GIESEE), Departamento de Electrotecnia, Universidad Tecnologica Nacional, Facultad Regional La Plata, Av. 60 esq. 124 (1900) La Plata (Argentina)

    2008-07-15

    Recent advances in the design and construction of a hydrogen/oxygen PEM fuel cell stack are presented. A test bench including measurement and control devices to monitor the fuel cell operating parameters was mounted. The influence of the characteristics of the membrane electrode assembly, bipolar plates, etc., on the performance of the fuel cell stack was studied. The behavior of the fuel cell stack with a different number of cells in series was evaluated. In order to identify and minimize the energy losses a critical analysis of the results was done. (author)

  14. Advanced and In Situ Analytical Methods for Solar Fuel Materials.

    Science.gov (United States)

    Chan, Candace K; Tüysüz, Harun; Braun, Artur; Ranjan, Chinmoy; La Mantia, Fabio; Miller, Benjamin K; Zhang, Liuxian; Crozier, Peter A; Haber, Joel A; Gregoire, John M; Park, Hyun S; Batchellor, Adam S; Trotochaud, Lena; Boettcher, Shannon W

    2016-01-01

    In situ and operando techniques can play important roles in the development of better performing photoelectrodes, photocatalysts, and electrocatalysts by helping to elucidate crucial intermediates and mechanistic steps. The development of high throughput screening methods has also accelerated the evaluation of relevant photoelectrochemical and electrochemical properties for new solar fuel materials. In this chapter, several in situ and high throughput characterization tools are discussed in detail along with their impact on our understanding of solar fuel materials.

  15. Advanced reactors and associated fuel cycle facilities: safety and environmental impacts.

    Science.gov (United States)

    Hill, R N; Nutt, W M; Laidler, J J

    2011-01-01

    The safety and environmental impacts of new technology and fuel cycle approaches being considered in current U.S. nuclear research programs are contrasted to conventional technology options in this paper. Two advanced reactor technologies, the sodium-cooled fast reactor (SFR) and the very high temperature gas-cooled reactor (VHTR), are being developed. In general, the new reactor technologies exploit inherent features for enhanced safety performance. A key distinction of advanced fuel cycles is spent fuel recycle facilities and new waste forms. In this paper, the performance of existing fuel cycle facilities and applicable regulatory limits are reviewed. Technology options to improve recycle efficiency, restrict emissions, and/or improve safety are identified. For a closed fuel cycle, potential benefits in waste management are significant, and key waste form technology alternatives are described.

  16. A practical fabrication method for the advanced heterogeneous fuel with magnesia containing minor actinides

    Energy Technology Data Exchange (ETDEWEB)

    Miwa, Shuhei [Oarai Research and Development Center, Japan Atomic Energy Agency, 4002 Narita-cho, Oarai-machi, Higashi-ibaraki-gun, Ibaraki 311-1393 (Japan)], E-mail: miwa.shuhei@jaea.go.jp; Osaka, Masahiko [Oarai Research and Development Center, Japan Atomic Energy Agency, 4002 Narita-cho, Oarai-machi, Higashi-ibaraki-gun, Ibaraki 311-1393 (Japan)

    2009-03-15

    Fabrication tests on advanced heterogeneous fuel with MgO were carried out for the purpose of establishing a practical fabrication method. Advanced heterogeneous fuel consists of spheres (diameter greater than 100 {mu}m) of a minor actinide oxide and MgO inert matrix (macro-dispersed type fuel). Macro-dispersed type fuel pellets with a high density above 90% T.D. were successfully fabricated. In addition, the fabricated pellets showed a homogeneous dispersion of near spherical host phase granules. These were attained by optimization of the fabrication process and conditions; i.e. a preliminary heat treatment of raw powders of host phase, an adjustment of pressure at the granulation process, deployment of a spray-dry process for MgO sphere preparation and sintering in a He atmosphere. From these results, a practical fabrication method for MgO-based macro-dispersed type fuel based on a simple powder metallurgical technique was established.

  17. Constituent Redistribution in U-Zr Metallic Fuel Using the Advanced Fuel Performance Code BISON

    Energy Technology Data Exchange (ETDEWEB)

    Galloway, Jack D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Unal, Cetin [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Matthews, Christopher [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-09-30

    Previous work done by Galloway, et. al. on EBR-II ternary (U-Pu-Zr) fuel constituent redistribution yielded accurate simulation data for the limited data sets of Zr redistribution. The data sets included EPMA scans of two different irradiated rods. First, T179, which was irradiated to 1.9 at% burnup, was analyzed. Second, DP16, which was irradiated to 11 at% burnup, was analyzed. One set of parameters that most accurately represented the zirconium profiles for both experiments was determined. Since the binary fuel (U-Zr) has previously been used as the driver fuel for sodium fast reactors (SFR) as well as being the likely driver fuel if a new SFR is constructed, this same process has been initiated on the binary fuel form. From limited binary EPMA scans as well as other fuel characterization techniques, it has been observed that zirconium redistribution also occurs in the binary fuel, albeit at a reduced rate compared to observation in the ternary fuel, as noted by Kim et. al. While the rate of redistribution has been observed to be slower, numerous metallographs of U-Zr fuel show distinct zone formations.

  18. Gasoline Ultra Efficient Fuel Vehicle with Advanced Low Temperature Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Confer, Keith [Delphi Automotive Systems, LLC, Troy, MI (United States)

    2014-12-18

    The objective of this program was to develop, implement and demonstrate fuel consumption reduction technologies which are focused on reduction of friction and parasitic losses and on the improvement of thermal efficiency from in-cylinder combustion. The program was executed in two phases. The conclusion of each phase was marked by an on-vehicle technology demonstration. Phase I concentrated on short term goals to achieve technologies to reduce friction and parasitic losses. The duration of Phase I was approximately two years and the target fuel economy improvement over the baseline was 20% for the Phase I demonstration. Phase II was focused on the development and demonstration of a breakthrough low temperature combustion process called Gasoline Direct- Injection Compression Ignition (GDCI). The duration of Phase II was approximately four years and the targeted fuel economy improvement was 35% over the baseline for the Phase II demonstration vehicle. The targeted tailpipe emissions for this demonstration were Tier 2 Bin 2 emissions standards.

  19. Gasoline Ultra Efficient Fuel Vehicle with Advanced Low Temperature Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Confer, Keith

    2014-09-30

    The objective of this program was to develop, implement and demonstrate fuel consumption reduction technologies which are focused on reduction of friction and parasitic losses and on the improvement of thermal efficiency from in-cylinder combustion. The program was executed in two phases. The conclusion of each phase was marked by an on-vehicle technology demonstration. Phase I concentrated on short term goals to achieve technologies to reduce friction and parasitic losses. The duration of Phase I was approximately two years and the target fuel economy improvement over the baseline was 20% for the Phase I demonstration. Phase II was focused on the development and demonstration of a breakthrough low temperature combustion process called Gasoline Direct- Injection Compression Ignition (GDCI). The duration of Phase II was approximately four years and the targeted fuel economy improvement was 35% over the baseline for the Phase II demonstration vehicle. The targeted tailpipe emissions for this demonstration were Tier 2 Bin 2 emissions standards.

  20. Advanced diagnostics in oxy-fuel combustion processes

    Energy Technology Data Exchange (ETDEWEB)

    Brix, J.; Clausen, Soennik; Degn Jensen, A. (Technical Univ. of Denmark. CHEC Research Centre, Kgs. Lyngby (Denmark)); Boeg Toftegaard, M. (DONG Energy Power, Hvidovre (Denmark))

    2012-07-01

    This report sums up the findings in PSO-project 010069, ''Advanced Diagnostics in Oxy-Fuel Combustion Processes''. Three areas of optic diagnostics are covered in this work: - FTIR measurements in a 30 kW swirl burner. - IR measurements in a 30 kW swirl burner. - IR measurements in a laboratory scale fixed bed reactor. The results obtained in the swirl burner have proved the FTIR method as a valuable technique for gas phase temperature measurements. When its efficacy is evaluated against traditional thermocouple measurements, two cases, with and without probe beam stop, must however be treated separately. When the FTIR probe is operated with the purpose of gas phase concentration measurements the probe needs to operate with a beam stop mounted in front of it. With this beam stop in place it was shown that the measured gas phase temperature was affected by cooling, induced by the cooled beam stop. Hence, for a more accurate determination of gas phase temperatures the probe needed to operate without the beam stop. When this was the case, the FTIR probe showed superior to traditional temperature measurements using a thermocouple as it could measure the fast temperature fluctuations. With the beam stop in place the efficacy of the FTIR probe for gas temperature determination was comparable to the use of a traditional thermocouple. The evaluation of the FTIR technique regarding estimation of gas phase concentrations of H{sub 2}O, CO{sub 2} and CO showed that the method is reliable though it cannot be stated as particularly accurate. The accuracy of the method is dependent on the similarity of the reference emission spectra of the gases with those obtained in the experiments, as the transmittance intensity is not a linear function of concentration. The length of the optical path also affects the steadiness of the measurements. The length of the optical path is difficult to adjust on the small scales that are the focus of this work. However

  1. Analysis of Advanced Fuel Assemblies and Core Designs for the Current and Next Generations of LWRs

    Energy Technology Data Exchange (ETDEWEB)

    Ragusa, Jean; Vierow, Karen

    2011-09-01

    The objective of the project is to design and analyze advanced fuel assemblies for use in current and future light water reactors and to assess their ability to reduce the inventory of transuranic elements, while preserving operational safety. The reprocessing of spent nuclear fuel can delay or avoid the need for a second geological repository in the US. Current light water reactor fuel assembly designs under investigation could reduce the plutonium inventory of reprocessed fuel. Nevertheless, these designs are not effective in stabilizing or reducing the inventory of minor actinides. In the course of this project, we developed and analyzed advanced fuel assembly designs with improved thermal transmutation capability regarding transuranic elements and especially minor actinides. These designs will be intended for use in thermal spectrum (e.g., current and future fleet of light water reactors in the US). We investigated various fuel types, namely high burn-up advanced mixed oxides and inert matrix fuels, in various geometrical designs that are compliant with the core internals of current and future light water reactors. Neutronic/thermal hydraulic effects were included. Transmutation efficiency and safety parameters were used to rank and down-select the various designs.

  2. Advanced catalyst supports for PEM fuel cell cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Du, Lei; Shao, Yuyan; Sun, Junming; Yin, Geping; Liu, Jun; Wang, Yong

    2016-11-01

    Electrocatalyst support materials are key components for polymer exchange membrane (PEM) fuel cells, which play a critical role in determining electrocatalyst durability and activity, mass transfer and water management. The commonly-used supports, e.g. porous carbon black, cannot meet all the requirements under the harsh operation condition of PEM fuel cells. Great efforts have been made in the last few years in developing alternative support materials. In this paper, we selectively review recent progress on three types of important support materials: carbon, non-carbon and hybrid carbon-oxides nanocomposites. A perspective on future R&D of electrocatalyst support materials is also provided.

  3. Microwave Processing of Simulated Advanced Nuclear Fuel Pellets

    Energy Technology Data Exchange (ETDEWEB)

    D.E. Clark; D.C. Folz

    2010-08-29

    Throughout the three-year project funded by the Department of Energy (DOE) and lead by Virginia Tech (VT), project tasks were modified by consensus to fit the changing needs of the DOE with respect to developing new inert matrix fuel processing techniques. The focus throughout the project was on the use of microwave energy to sinter fully stabilized zirconia pellets using microwave energy and to evaluate the effectiveness of techniques that were developed. Additionally, the research team was to propose fundamental concepts as to processing radioactive fuels based on the effectiveness of the microwave process in sintering the simulated matrix material.

  4. Advances in PEM fuel cells with CFD techniques

    Energy Technology Data Exchange (ETDEWEB)

    Robalinho, Eric; Cunha, Edgar Ferrari da; Zararya, Ahmed; Linardi, Marcelo [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)], Email: eric@ipen.br; Cekinski, Efrain [Instituto de Pesquisas Tecnologicas (IPT), Sao Paulo, SP (Brazil)

    2010-07-01

    This paper presents some applications of computational fluid dynamics techniques in the optimization of Proton Exchange Membrane Fuel Cell (PEMFC) designs. The results concern: modeling of gas distribution channels, the study for both porous anode and cathode and the three-dimensional modeling of a partial geometry layer containing catalytic Gas Diffusion Layers (GDL) and membrane. Numerical results of the simulations of graphite plates flow channels, using ethanol as fuel, are also presented. Some experimental results are compared to the corresponding numerical ones for several cases, demonstrating the importance and usefulness of this computational tool. (author)

  5. Advanced energy analysis of high temperature fuel cell systems

    NARCIS (Netherlands)

    De Groot, A.

    2004-01-01

    In this thesis the performance of high temperature fuel cell systems is studied using a new method of exergy analysis. The thesis consists of three parts: ⢠In the first part a new analysis method is developed, which not only considers the total exergy losses in a unit operation, but which distingu

  6. Screening of advanced cladding materials and UN–U{sub 3}Si{sub 5} fuel

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Nicholas R., E-mail: nbrown@bnl.gov; Todosow, Michael; Cuadra, Arantxa

    2015-07-15

    Highlights: • Screening methodology for advanced fuel and cladding. • Cladding candidates, except for silicon carbide, exhibit reactivity penalty versus zirconium alloy. • UN–U{sub 3}Si{sub 5} fuels have the potential to exhibit reactor physics and fuel management performance similar to UO{sub 2}. • Harder spectrum in the UN ceramic composite fuel increases transuranic build-up. • Fuel and cladding properties assumed in these assessments are preliminary. - Abstract: In the aftermath of Fukushima, a focus of the DOE-NE Advanced Fuels Campaign has been the development of advanced nuclear fuel and cladding options with the potential for improved performance in an accident. Uranium dioxide (UO{sub 2}) fuels with various advanced cladding materials were analyzed to provide a reference for cladding performance impacts. For advanced cladding options with UO{sub 2} fuel, most of the cladding materials have some reactivity and discharge burn-up penalty (in GWd/t). Silicon carbide is one exception in that the reactor physics performance is predicted to be very similar to zirconium alloy cladding. Most candidate claddings performed similar to UO{sub 2}–Zr fuel–cladding in terms of safety coefficients. The clear exception is that Mo-based materials were identified as potentially challenging from a reactor physics perspective due to high resonance absorption. This paper also includes evaluation of UN–U{sub 3}Si{sub 5} fuels with Kanthal AF or APMT cladding. The objective of the U{sub 3}Si{sub 5} phase in the UN–U{sub 3}Si{sub 5} fuel concept is to shield the nitride phase from water. It was shown that UN–U{sub 3}Si{sub 5} fuels with Kanthal AF or APMT cladding have similar reactor physics and fuel management performance over a wide parameter space of phase fractions when compared to UO{sub 2}–Zr fuel–cladding. There will be a marginal penalty in discharge burn-up (in GWd/t) and the sensitivity to {sup 14}N content in UN ceramic composites is high

  7. Advanced Fuel Cycle Economic Analysis of Symbiotic Light-Water Reactor and Fast Burner Reactor Systems

    Energy Technology Data Exchange (ETDEWEB)

    D. E. Shropshire

    2009-01-01

    The Advanced Fuel Cycle Economic Analysis of Symbiotic Light-Water Reactor and Fast Burner Reactor Systems, prepared to support the U.S. Advanced Fuel Cycle Initiative (AFCI) systems analysis, provides a technology-oriented baseline system cost comparison between the open fuel cycle and closed fuel cycle systems. The intent is to understand their overall cost trends, cost sensitivities, and trade-offs. This analysis also improves the AFCI Program’s understanding of the cost drivers that will determine nuclear power’s cost competitiveness vis-a-vis other baseload generation systems. The common reactor-related costs consist of capital, operating, and decontamination and decommissioning costs. Fuel cycle costs include front-end (pre-irradiation) and back-end (post-iradiation) costs, as well as costs specifically associated with fuel recycling. This analysis reveals that there are large cost uncertainties associated with all the fuel cycle strategies, and that overall systems (reactor plus fuel cycle) using a closed fuel cycle are about 10% more expensive in terms of electricity generation cost than open cycle systems. The study concludes that further U.S. and joint international-based design studies are needed to reduce the cost uncertainties with respect to fast reactor, fuel separation and fabrication, and waste disposition. The results of this work can help provide insight to the cost-related factors and conditions needed to keep nuclear energy (including closed fuel cycles) economically competitive in the U.S. and worldwide. These results may be updated over time based on new cost information, revised assumptions, and feedback received from additional reviews.

  8. Systems Analysis of an Advanced Nuclear Fuel Cycle Based on a Modified UREX+3c Process

    Energy Technology Data Exchange (ETDEWEB)

    E. R. Johnson; R. E. Best

    2009-12-28

    The research described in this report was performed under a grant from the U.S. Department of Energy (DOE) to describe and compare the merits of two advanced alternative nuclear fuel cycles -- named by this study as the “UREX+3c fuel cycle” and the “Alternative Fuel Cycle” (AFC). Both fuel cycles were assumed to support 100 1,000 MWe light water reactor (LWR) nuclear power plants operating over the period 2020 through 2100, and the fast reactors (FRs) necessary to burn the plutonium and minor actinides generated by the LWRs. Reprocessing in both fuel cycles is assumed to be based on the UREX+3c process reported in earlier work by the DOE. Conceptually, the UREX+3c process provides nearly complete separation of the various components of spent nuclear fuel in order to enable recycle of reusable nuclear materials, and the storage, conversion, transmutation and/or disposal of other recovered components. Output of the process contains substantially all of the plutonium, which is recovered as a 5:1 uranium/plutonium mixture, in order to discourage plutonium diversion. Mixed oxide (MOX) fuel for recycle in LWRs is made using this 5:1 U/Pu mixture plus appropriate makeup uranium. A second process output contains all of the recovered uranium except the uranium in the 5:1 U/Pu mixture. The several other process outputs are various waste streams, including a stream of minor actinides that are stored until they are consumed in future FRs. For this study, the UREX+3c fuel cycle is assumed to recycle only the 5:1 U/Pu mixture to be used in LWR MOX fuel and to use depleted uranium (tails) for the makeup uranium. This fuel cycle is assumed not to use the recovered uranium output stream but to discard it instead. On the other hand, the AFC is assumed to recycle both the 5:1 U/Pu mixture and all of the recovered uranium. In this case, the recovered uranium is reenriched with the level of enrichment being determined by the amount of recovered plutonium and the combined amount

  9. Advanced ECU Software Development Method for Fuel Cell Systems

    Institute of Scientific and Technical Information of China (English)

    TIAN Shuo; LIU Yuan; XIA Wenchuan; LI Jianqiu; YANG Minggao

    2005-01-01

    The electronic control unit (ECU) in electrical powered hybrid and fuel cell vehicles is exceedingly complex. Rapid prototyping control is used to reduce development time and eliminate errors during software development. This paper describes a high-efficiency development method and a flexible tool chain suitable for various applications in automotive engineering. The control algorithm can be deployed directly from a Matlab/Simulink/Stateflow environment into the ECU hardware together with an OSEK real-time operating system (RTOS). The system has been successfully used to develop a 20-kW fuel cell system ECU based on a Motorola PowerPC 555 (MPC555) microcontroller. The total software development time is greatly reduced and the code quality and reliability are greatly enhanced.

  10. Advances in the generation of a new emulsified fuel

    Energy Technology Data Exchange (ETDEWEB)

    Chavez, A. [Technical Consultancy, Energy Plus UC, Huitzilac, Morelos (Mexico); Ramirez, M. [Instituto Mexicano del Petroleo, Programa de Aseguramiento de Hidrocarburos, Mexico, D.F. (Mexico); Medina, E. [Universidad Nacional Autonoma de Mexico, Departamento de Termofluidos, Facultad de Ingenieria, Mexico, D.F. (Mexico); Bolado, R.; Mora, J. [Instituto Mexicano del Petroleo, Laboratorio de Combustion, Veracruz (Mexico)

    2011-08-15

    The development of a new emulsified fuel is described, from the conceptual idea to the semi-industrial tests of the final product. The starting point was the necessity to lower the particulate matter (PM) emissions produced by the combustion of more than 200 MBD of heavy fuel oil (HFO) used for electric power conversion. The major component of HFO is a vacuum residue of the oil refining process mixed with light cycle oils to make it pumpable. An alternative to handle and burn the high viscosity residue (solid at room temperature) is by converting it in an oil-in-water emulsion. The best emulsions resulted of 70% residue in 30% water, Sauter Mean Diameter of 10-20 {mu}m and a stability of more than 90 days. Spray burning tests of the emulsion against HFO in a semi-industrial 500 kW furnace showed a reduction in PM emissions of 24-36%. (orig.)

  11. Recent advances in Carbon Nanotube based Enzymatic Fuel Cells

    Directory of Open Access Journals (Sweden)

    Serge eCosnier

    2014-10-01

    Full Text Available This review summarizes recent trends in the field of enzymatic fuel cells. Thanks to the high specificity of enzymes, biofuel cells can generate electrical energy by oxidation of a targeted fuel (sugars, alcohols or hydrogen at the anode and reduction of oxidants (O2, H2O2 at the cathode in complex media. The combination of carbon nanotubes, enzymes and redox mediators was widely exploited to develop biofuel cells since the electrons, involved in the bio-electrocatalytic processes, can be efficiently transferred from or to an external circuit. Original approaches to construct electron transfer based CNT-bioelectrodes and impressive biofuel cell performances are reported as well as biomedical applications.

  12. Functional nanocomposites for advanced fuel cell technology and polygeneration

    OpenAIRE

    Raza, Rizwan

    2011-01-01

    In recent decades, the use of fossil fuels has increased exponentially with a corresponding sharp increase in the pollution of the environment. The need for clean and sustainable technologies for the generation of power with reduced or zero environment impact has become critical. A number of attempts have been made to address this problem; one of the most promising attempts is polygeneration. Polygeneration technology is highly efficient and produces lower emissions than conventional methods ...

  13. Advanced Thermally Stable Coal-Based Jet Fuels

    Science.gov (United States)

    2009-09-30

    hydrotreating to remove sulfur and then by hydrogenation for partial or complete ring saturation. Although this approach leads to a fuel of excellent quality...contributed by this coal were mainly two- and three-ring compounds. With hydrotreating to reduce sulfur and nitrogen and saturation of the aromatics...it could be a useful solvent for process configurations that couple coal conversion upstream with standard downstream hydrotreating , aromatics

  14. SunLine Transit Agency Advanced Technology Fuel Cell Bus Evaluation: Fourth Results Report

    Energy Technology Data Exchange (ETDEWEB)

    Eudy, L.; Chandler, K.

    2013-01-01

    SunLine Transit Agency, which provides public transit services to the Coachella Valley area of California, has demonstrated hydrogen and fuel cell bus technologies for more than 10 years. In May 2010, SunLine began demonstrating the advanced technology (AT) fuel cell bus with a hybrid electric propulsion system, fuel cell power system, and lithium-based hybrid batteries. This report describes operations at SunLine for the AT fuel cell bus and five compressed natural gas buses. The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) is working with SunLine to evaluate the bus in real-world service to document the results and help determine the progress toward technology readiness. NREL has previously published three reports documenting the operation of the fuel cell bus in service. This report provides a summary of the results with a focus on the bus operation from February 2012 through November 2012.

  15. The conceptual analysis of MBA and KMP for advanced spent fuel management process

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Sang Yoon; Ko, Won Il; Ha, Jang Ho; Kim, Ho Dong; Koo, Dae Seo [Korea Atomic Energy Research Institute, Taejeon (Korea)

    2002-03-01

    This report describes the concept of dry reprocessing of molten salt which is proposed as nuclear fuel cycle with nuclear proliferation resistance. These basic researches in Japan, U. S., Russia are in progress, and Republic of Korea is performing basic research of metallic conversion fabrication of molten salt of uranium dioxide fuels through nuclear research project. In this report, we have performed conceptual analysis and establishment of MBA and KMP for nuclear material safeguards in order to accomplish metallic conversion research of molten salt of uranium dioxide fuels. This report will contribute to the implementation of nuclear material safeguards of advanced spent fuel management process, and also the usage of basic data of nuclear material safeguards for spent fuel recycling process of native country. 11 refs., 17 figs., 8 tabs. (Author)

  16. Vibration behavior of fuel-element vibration suppressors for the advanced power reactor

    Science.gov (United States)

    Adams, D. W.; Fiero, I. B.

    1973-01-01

    Preliminary shock and vibration tests were performed on vibration suppressors for the advanced power reactor for space application. These suppressors position the fuel pellets in a pin type fuel element. The test determined the effect of varying axial clearance on the behavior of the suppressors when subjected to shock and vibratory loading. The full-size suppressor was tested in a mockup model of fuel and clad which required scaling of test conditions. The test data were correlated with theoretical predictions for suppressor failure. Good agreement was obtained. The maximum difference with damping neglected was about 30 percent. Neglecting damping would result in a conservative design.

  17. Recovery of Information from the Fast Flux Test Facility for the Advanced Fuel Cycle Initiative

    Energy Technology Data Exchange (ETDEWEB)

    Nielsen, Deborah L.; Makenas, Bruce J.; Wootan, David W.; Butner, R. Scott; Omberg, Ronald P.

    2009-09-30

    The Fast Flux Test Facility is the most recent Liquid Metal Reactor to operate in the United States. Information from the design, construction, and operation of this reactor was at risk as the facilities associated with the reactor are being shut down. The Advanced Fuel Cycle Initiative is a program managed by the Office of Nuclear Energy of the U.S. Department of Energy with a mission to develop new fuel cycle technologies to support both current and advanced reactors. Securing and preserving the knowledge gained from operation and testing in the Fast Flux Test Facility is an important part of the Knowledge Preservation activity in this program.

  18. Use of freeze-casting in advanced burner reactor fuel design

    Energy Technology Data Exchange (ETDEWEB)

    Lang, A. L.; Yablinsky, C. A.; Allen, T. R. [Dept. of Engineering Physics, Univ. of Wisconsin Madison, 1500 Engineering Drive, Madison, WI 53711 (United States); Burger, J.; Hunger, P. M.; Wegst, U. G. K. [Thayer School of Engineering, Dartmouth College, 8000 Cummings Hall, Hanover, NH 03755 (United States)

    2012-07-01

    This paper will detail the modeling of a fast reactor with fuel pins created using a freeze-casting process. Freeze-casting is a method of creating an inert scaffold within a fuel pin. The scaffold is created using a directional solidification process and results in open porosity for emplacement of fuel, with pores ranging in size from 300 microns to 500 microns in diameter. These pores allow multiple fuel types and enrichments to be loaded into one fuel pin. Also, each pore could be filled with varying amounts of fuel to allow for the specific volume of fission gases created by that fuel type. Currently fast reactors, including advanced burner reactors (ABR's), are not economically feasible due to the high cost of operating the reactors and of reprocessing the fuel. However, if the fuel could be very precisely placed, such as within a freeze-cast scaffold, this could increase fuel performance and result in a valid design with a much lower cost per megawatt. In addition to competitive costs, freeze-cast fuel would also allow for selective breeding or burning of actinides within specific locations in fast reactors. For example, fast flux peak locations could be utilized on a minute scale to target specific actinides for transmutation. Freeze-cast fuel is extremely flexible and has great potential in a variety of applications. This paper performs initial modeling of freeze-cast fuel, with the generic fast reactor parameters for this model based on EBR-II. The core has an assumed power of 62.5 MWt. The neutronics code used was Monte Carlo N-Particle (MCNP5) transport code. Uniform pore sizes were used in increments of 100 microns. Two different freeze-cast scaffold materials were used: ceramic (MgO-ZrO{sub 2}) and steel (SS316L). Separate models were needed for each material because the freeze-cast ceramic and metal scaffolds have different structural characteristics and overall porosities. Basic criticality results were compiled for the various models

  19. Advanced Automotive Fuels Research, Development, and Commercialization Cluster (OH)

    Energy Technology Data Exchange (ETDEWEB)

    Linkous, Clovis; Hripko, Michael; Abraham, Martin; Balendiran, Ganesaratnam; Hunter, Allen; Lovelace-Cameron, Sherri; Mette, Howard; Price, Douglas; Walker, Gary; Wang, Ruigang

    2013-08-31

    Technical aspects of producing alternative fuels that may eventually supplement or replace conventional the petroleum-derived fuels that are presently used in vehicular transportation have been investigated. The work was centered around three projects: 1) deriving butanol as a fuel additive from bacterial action on sugars produced from decomposition of aqueous suspensions of wood cellulose under elevated temperature and pressure; 2) using highly ordered, openly structured molecules known as metal-organic framework (MOF) compounds as adsorbents for gas separations in fuel processing operations; and 3) developing a photocatalytic membrane for solar-driven water decomposition to generate pure hydrogen fuel. Several departments within the STEM College at YSU contributed to the effort: Chemistry, Biology, and Chemical Engineering. In the butanol project, sawdust was blended with water at variable pH and temperature (150 – 250{degrees}C), and heated inside a pressure vessel for specified periods of time. Analysis of the extracts showed a wide variety of compounds, including simple sugars that bacteria are known to thrive upon. Samples of the cellulose hydrolysate were fed to colonies of Clostridium beijerinckii, which are known to convert sugars to a mixture of compounds, principally butanol. While the bacteria were active toward additions of pure sugar solutions, the cellulose extract appeared to inhibit butanol production, and furthermore encouraged the Clostridium to become dormant. Proteomic analysis showed that the bacteria had changed their genetic code to where it was becoming sporulated, i.e., the bacteria were trying to go dormant. This finding may be an opportunity, as it may be possible to genetically engineer bacteria that resist the butanol-driven triggering mechanism to stop further fuel production. Another way of handling the cellulosic hydrolysates was to simply add the enzymes responsible for butanol synthesis to the hydrolytic extract ex-vivo. These

  20. Applying Advanced Neutron Transport Calculations for Improving Fuel Performance Codes

    Energy Technology Data Exchange (ETDEWEB)

    Botazzoli, P.; Luzzi, L. [Politecnico di Milano, Department of Energy, Nuclear Engineering Division - CeSNEF, Milano (Italy); Schubert, A.; Van Uffelen, P. [European Commission, Joint Research Centre, Institute for Transuranium Elements, Karlsruhe (Germany); Haeck, W. [Institute de Radioprotection et de Surete Nucleaire, Fontenay-aux-Roses (France)

    2009-06-15

    TRANSURANUS is a computer code for the thermal and mechanical analysis of fuel rods in nuclear reactors. As part of the code, the TUBRNP model calculates the local concentration of the actinides (U, Pu, Am, Cm), the main fission products (Xe, Kr, Cs and Nd) and {sup 4}He produced during the irradiation as a function of the radial position across a fuel pellet (radial profiles). These local quantities are required for the determination of the local power density, the local burn-up, and the source term of fission products and other inert gases. In previous works the neutronic code ALEPH has been used to validate the models for the actinides and fission products concentrations in UO{sub 2} fuels. A similar approach has been adopted in the present work for verifying the Helium production. The present paper focuses on the modelling of the Helium production in PWR oxide fuels (MOX and UO{sub 2}). A reliable prediction of the Helium production and release in LWR oxide fuels is of great interest in case of increasing burn-up, linear heat generation rates and Plutonium content. The contribution of the Helium released plays a fundamental role in the gap pressure and subsequently in the mechanical behaviour of the fuel rod, in particular during the storage of the high burn-up spent fuel. Helium is produced in oxide fuels by three main paths: (i) alpha decay of the actinides (the main contribution is due to {sup 242}Cm, {sup 238}Pu and {sup 244}Cm); (ii) (n,{alpha}) reactions; and (iii) ternary fission. In the present work, the contributions due to ternary fission and the (n,{alpha}) reaction on {sup 16}O as well as some refinements in the {sup 241}Am burn-up chain have been included in TUBRNP. The VESTA neutronic code has been used for the validation of the He production model. The generic VESTA Monte Carlo depletion interface developed at IRSN allows us to couple different Monte Carlo codes with a depletion module. It currently allows for combining the ORIGEN 2.2 isotope

  1. Electrocatalyst advances for hydrogen oxidation in phosphoric acid fuel cells

    Science.gov (United States)

    Stonehart, P.

    1984-01-01

    The important considerations that presently exist for achieving commercial acceptance of fuel cells are centered on cost (which translates to efficiency) and lifetime. This paper addresses the questions of electrocatalyst utilization within porous electrode structures and the preparation of low-cost noble metal electrocatalyst combinations with extreme dispersions of the metal. Now that electrocatalyst particles can be prepared with dimensions of 10 A, either singly or in alloy combinations, a very large percentage of the noble metal atoms in a crystallite are available for reaction. The cost savings for such electrocatalysts in the present commercially driven environment are considerable.

  2. Advancements in the behavioral modeling of fuel elements and related structures

    Energy Technology Data Exchange (ETDEWEB)

    Billone, M.C.; Montgomery, R.O.; Rashid, Y.R.; Head, J.L. (Argonne National Lab., IL (USA); ANATECH Research Corp., San Diego, CA (USA); Royal Naval Coll., Greenwich (UK))

    1989-01-01

    An important aspect of the design and analysis of nuclear reactors is the ability to predict the behavior of fuel elements in the adverse environment of a reactor system. By understanding the thermomechanical behavior of the different materials which constitute a nuclear fuel element, analysis and predictions can be made regarding the integrity and reliability of fuel element designs. The SMiRT conference series, through the division on fuel elements and the post-conference seminars on fuel element modeling, provided technical forums for the international participation in the exchange of knowledge concerning the thermomechanical modeling of fuel elements. This paper discusses the technical advances in the behavioral modeling of fuel elements presented at the SMiRT conference series since its inception in 1971. Progress in the areas of material properties and constitutive relationships, modeling methodologies, and integral modeling approaches was reviewed and is summarized in light of their impact on the thermomechanical modeling of nuclear fuel elements. 34 refs., 5 tabs.

  3. Status of advanced fuel candidates for Sodium Fast Reactor within the Generation IV International Forum

    Science.gov (United States)

    Delage, F.; Carmack, J.; Lee, C. B.; Mizuno, T.; Pelletier, M.; Somers, J.

    2013-10-01

    The main challenge for fuels for future Sodium Fast Reactor systems is the development and qualification of a nuclear fuel sub-assembly which meets the Generation IV International Forum goals. The Advanced Fuel project investigates high burn-up minor actinide bearing fuels as well as claddings and wrappers to withstand high neutron doses and temperatures. The R&D outcome of national and collaborative programs has been collected and shared between the AF project members in order to review the capability of sub-assembly material and fuel candidates, to identify the issues and select the viable options. Based on historical experience and knowledge, both oxide and metal fuels emerge as primary options to meet the performance and the reliability goals of Generation IV SFR systems. There is a significant positive experience on carbide fuels but major issues remain to be overcome: strong in-pile swelling, atmosphere required for fabrication as well as Pu and Am losses. The irradiation performance database for nitride fuels is limited with longer term R&D activities still required. The promising core material candidates are Ferritic/Martensitic (F/M) and Oxide Dispersed Strengthened (ODS) steels.

  4. Fission Product Monitoring of TRISO Coated Fuel For The Advanced Gas Reactor -1 Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Dawn M. Scates; John (Jack) K Hartwell; John B. Walter

    2008-09-01

    The US Department of Energy has embarked on a series of tests of TRISO-coated particle reactor fuel intended for use in the Very High Temperature Reactor (VHTR) as part of the Advanced Gas Reactor (AGR) program. The AGR-1 TRISO fuel experiment, currently underway, is the first in a series of eight fuel tests planned for irradiation in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The AGR-1 experiment reached a peak compact averaged burn up of 9% FIMA with no known TRISO fuel particle failures in March 2008. The burnup goal for the majority of the fuel compacts is to have a compact averaged burnup greater than 18% FIMA and a minimum compact averaged burnup of 14% FIMA. At the INL the TRISO fuel in the AGR-1 experiment is closely monitored while it is being irradiated in the ATR. The effluent monitoring system used for the AGR-1 fuel is the Fission Product Monitoring System (FPMS). The FPMS is a valuable tool that provides near real-time data indicative of the AGR-1 test fuel performance and incorporates both high-purity germanium (HPGe) gamma-ray spectrometers and sodium iodide [NaI(Tl)] scintillation detector-based gross radiation monitors. To quantify the fuel performance, release-to-birth ratios (R/B’s) of radioactive fission gases are computed. The gamma-ray spectra acquired by the AGR-1 FPMS are analyzed and used to determine the released activities of specific fission gases, while a dedicated detector provides near-real time count rate information. Isotopic build up and depletion calculations provide the associated isotopic birth rates. This paper highlights the features of the FPMS, encompassing the equipment, methods and measures that enable the calculation of the release-to-birth ratios. Some preliminary results from the AGR-1 experiment are also presented.

  5. Status of the NGNP Fuel Experiment AGR-2 Irradiated in the Advanced Test Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Blaine Grover

    2012-10-01

    The United States Department of Energy’s Next Generation Nuclear Plant (NGNP) Advanced Gas Reactor (AGR) Fuel Development and Qualification Program will be irradiating up to seven separate low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States, and will be irradiated over the next several years to demonstrate and qualify new TRISO coated particle fuel for use in high temperature gas reactors. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which will each consist of at least six separate capsules, will be irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gas will also have on-line fission product monitoring on its effluent to track performance of the fuel in each individual capsule during irradiation. The first experiment (designated AGR-1) started irradiation in December 2006 and was completed in November 2009. The second experiment (AGR-2), which utilized the same experiment design as well as control and monitoring systems as AGR-1, started irradiation in June 2010 and is currently scheduled to be completed in April 2013. The design of this experiment and support systems will be briefly discussed, followed by the progress and status of the experiment to date.

  6. Advances in Ceramic Supports for Polymer Electrolyte Fuel Cells

    Directory of Open Access Journals (Sweden)

    Oran Lori

    2015-08-01

    Full Text Available Durability of catalyst supports is a technical barrier for both stationary and transportation applications of polymer-electrolyte-membrane fuel cells. New classes of non-carbon-based materials were developed in order to overcome the current limitations of the state-of-the-art carbon supports. Some of these materials are designed and tested to exceed the US DOE lifetime goals of 5000 or 40,000 hrs for transportation and stationary applications, respectively. In addition to their increased durability, the interactions between some new support materials and metal catalysts such as Pt result in increased catalyst activity. In this review, we will cover the latest studies conducted with ceramic supports based on carbides, oxides, nitrides, borides, and some composite materials.

  7. Ambient Laboratory Coater for Advanced Gas Reactor Fuel Development

    Energy Technology Data Exchange (ETDEWEB)

    Duane D. Bruns; Robert M. Counce; Irma D. Lima Rojas

    2010-06-09

    this research is targeted at developing improved experimentally-based scaling relationships for the hydrodynamics of shallow, gas-spouted beds of dense particles. The work is motivated by the need to more effctively scale up shallow spouted beds used in processes such as in the coating of nuclear fuel particles where precise control of solids and gas circulation is critically important. Experimental results reported here are for a 50 mm diameter spouted bed containing two different types of bed solids (alumina and zirconia) at different static bed depths and fluidized by air and helium. Measurements of multiple local average pressures, inlet gas pressure fluctuations, and spout height were used to characterize the bed hydrodynamics for each operating condition. Follow-on studies are planned that include additional variations in bed size, particle properties, and fluidizing gas. The ultimate objective is to identify the most important non-dimensional hydrodynamic scaling groups and possible spouted-bed design correlations based on these groups.

  8. Advanced Materials for PEM-Based Fuel Cell Systems

    Energy Technology Data Exchange (ETDEWEB)

    James E. McGrath

    2005-10-26

    Proton exchange membrane fuel cells (PEMFCs) are quickly becoming attractive alternative energy sources for transportation, stationary power, and small electronics due to the increasing cost and environmental hazards of traditional fossil fuels. Two main classes of PEMFCs include hydrogen/air or hydrogen/oxygen fuel cells and direct methanol fuel cells (DMFCs). The current benchmark membrane for both types of PEMFCs is Nafion, a perfluorinated sulfonated copolymer made by DuPont. Nafion copolymers exhibit good thermal and chemical stability, as well as very high proton conductivity under hydrated conditions at temperatures below 80 °C. However, application of these membranes is limited due to their high methanol permeability and loss of conductivity at high temperatures and low relative humidities. These deficiencies have led to the search for improved materials for proton exchange membranes. Potential PEMs should have good thermal, hydrolytic, and oxidative stability, high proton conductivity, selective permeability, and mechanical durability over long periods of time. Poly(arylene ether)s, polyimides, polybenzimidazoles, and polyphenylenes are among the most widely investigated candidates for PEMs. Poly(arylene ether)s are a promising class of proton exchange membranes due to their excellent thermal and chemical stability and high glass transition temperatures. High proton conductivity can be achieved through post-sulfonation of poly(arylene ether) materials, but this most often results in very high water sorption or even water solubility. Our research has shown that directly polymerized poly(arylene ether) copolymers show important advantages over traditional post-sulfonated systems and also address the concerns with Nafion membranes. These properties were evaluated and correlated with morphology, structure-property relationships, and

  9. Advanced Materials for PEM-Based Fuel Cell Systems

    Energy Technology Data Exchange (ETDEWEB)

    James E. McGrath; Donald G. Baird; Michael von Spakovsky

    2005-10-26

    Proton exchange membrane fuel cells (PEMFCs) are quickly becoming attractive alternative energy sources for transportation, stationary power, and small electronics due to the increasing cost and environmental hazards of traditional fossil fuels. Two main classes of PEMFCs include hydrogen/air or hydrogen/oxygen fuel cells and direct methanol fuel cells (DMFCs). The current benchmark membrane for both types of PEMFCs is Nafion, a perfluorinated sulfonated copolymer made by DuPont. Nafion copolymers exhibit good thermal and chemical stability, as well as very high proton conductivity under hydrated conditions at temperatures below 80 degrees C. However, application of these membranes is limited due to their high methanol permeability and loss of conductivity at high temperatures and low relative humidities. These deficiencies have led to the search for improved materials for proton exchange membranes. Potential PEMs should have good thermal, hydrolytic, and oxidative stability, high proton conductivity, selective permeability, and mechanical durability over long periods of time. Poly(arylene ether)s, polyimides, polybenzimidazoles, and polyphenylenes are among the most widely investigated candidates for PEMs. Poly(arylene ether)s are a promising class of proton exchange membranes due to their excellent thermal and chemical stability and high glass transition temperatures. High proton conductivity can be achieved through post-sulfonation of poly(arylene ether) materials, but this most often results in very high water sorption or even water solubility. Our research has shown that directly polymerized poly(arylene ether) copolymers show important advantages over traditional post-sulfonated systems and also address the concerns with Nafion membranes. These properties were evaluated and correlated with morphology, structure-property relationships, and states of water in the membranes. Further improvements in properties were achieved through incorporation of inorganic

  10. Stress analysis for the candidate of lower end fitting of advanced LWR fuel using FEM

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S. S.; Moon, Y. C. [Korea University of Technology and Education, Chonan (Korea, Republic of); Kim, H. K. [Korea Nuclear Fuel Company, Taejon (Korea, Republic of)

    2002-10-01

    The geometric modeling has been conducted for the candidate of advanced LWR fuel using the three-dimensional solid modeler. Then the three-dimensional stress analysis using MSC/NASTRAN has been performed. The evaluation for the mechanical integrity of the candidate has been performed based on the stress distribution obtained from the finite elements analysis.

  11. SunLine Transit Agency Advanced Technology Fuel Cell Bus Evaluation: Third Results Reports

    Energy Technology Data Exchange (ETDEWEB)

    Eudy, L.; Chandler, K.

    2012-05-01

    This report describes operations at SunLine Transit Agency for their newest prototype fuel cell bus and five compressed natural gas (CNG) buses. In May 2010, SunLine began operating its sixth-generation hydrogen fueled bus, an Advanced Technology (AT) fuel cell bus that incorporates the latest design improvements to reduce weight and increase reliability and performance. The agency is collaborating with the U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) to evaluate the bus in revenue service. NREL has previously published two reports documenting the operation of the fuel cell bus in service. This report provides a summary of the results with a focus on the bus operation from July 2011 through January 2012.

  12. SunLine Transit Agency Advanced Technology Fuel Cell Bus Evaluation: Second Results Report and Appendices

    Energy Technology Data Exchange (ETDEWEB)

    Eudy, L.; Chandler, K.

    2011-10-01

    This report describes operations at SunLine Transit Agency for their newest prototype fuel cell bus and five compressed natural gas (CNG) buses. In May 2010, SunLine began operating its sixth-generation hydrogen fueled bus, an Advanced Technology (AT) fuel cell bus that incorporates the latest design improvements to reduce weight and increase reliability and performance. The agency is collaborating with the U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) to evaluate the bus in revenue service. This is the second results report for the AT fuel cell bus since it was placed in service, and it focuses on the newest data analysis and lessons learned since the previous report. The appendices, referenced in the main report, provide the full background for the evaluation. They will be updated as new information is collected but will contain the original background material from the first report.

  13. Clean Cities Guide to Alternative Fuel and Advanced Medium- and Heavy-Duty Vehicles (Book)

    Energy Technology Data Exchange (ETDEWEB)

    2013-08-01

    Today's fleets are increasingly interested in medium-duty and heavy-duty vehicles that use alternative fuels or advanced technologies that can help reduce operating costs, meet emissions requirements, improve fleet sustainability, and support U.S. energy independence. Vehicle and engine manufacturers are responding to this interest with a wide range of options across a steadily growing number of vehicle applications. This guide provides an overview of alternative fuel power systems?including engines, microturbines, electric motors, and fuel cells?and hybrid propulsion systems. The guide also offers a list of individual medium- and heavy-duty vehicle models listed by application, along with associated manufacturer contact information, fuel type(s), power source(s), and related information.

  14. Clean Cities Guide to Alternative Fuel and Advanced Medium- and Heavy-Duty Vehicles

    Energy Technology Data Exchange (ETDEWEB)

    None

    2013-08-01

    Today's fleets are increasingly interested in medium-duty and heavy-duty vehicles that use alternative fuels or advanced technologies that can help reduce operating costs, meet emissions requirements, improve fleet sustainability, and support U.S. energy independence. Vehicle and engine manufacturers are responding to this interest with a wide range of options across a steadily growing number of vehicle applications. This guide provides an overview of alternative fuel power systems--including engines, microturbines, electric motors, and fuel cells--and hybrid propulsion systems. The guide also offers a list of individual medium- and heavy-duty vehicle models listed by application, along with associated manufacturer contact information, fuel type(s), power source(s), and related information.

  15. Systems Analysis of an Advanced Nuclear Fuel Cycle Based on a Modified UREX+3c Process

    Energy Technology Data Exchange (ETDEWEB)

    E. R. Johnson; R. E. Best

    2009-12-28

    The research described in this report was performed under a grant from the U.S. Department of Energy (DOE) to describe and compare the merits of two advanced alternative nuclear fuel cycles -- named by this study as the “UREX+3c fuel cycle” and the “Alternative Fuel Cycle” (AFC). Both fuel cycles were assumed to support 100 1,000 MWe light water reactor (LWR) nuclear power plants operating over the period 2020 through 2100, and the fast reactors (FRs) necessary to burn the plutonium and minor actinides generated by the LWRs. Reprocessing in both fuel cycles is assumed to be based on the UREX+3c process reported in earlier work by the DOE. Conceptually, the UREX+3c process provides nearly complete separation of the various components of spent nuclear fuel in order to enable recycle of reusable nuclear materials, and the storage, conversion, transmutation and/or disposal of other recovered components. Output of the process contains substantially all of the plutonium, which is recovered as a 5:1 uranium/plutonium mixture, in order to discourage plutonium diversion. Mixed oxide (MOX) fuel for recycle in LWRs is made using this 5:1 U/Pu mixture plus appropriate makeup uranium. A second process output contains all of the recovered uranium except the uranium in the 5:1 U/Pu mixture. The several other process outputs are various waste streams, including a stream of minor actinides that are stored until they are consumed in future FRs. For this study, the UREX+3c fuel cycle is assumed to recycle only the 5:1 U/Pu mixture to be used in LWR MOX fuel and to use depleted uranium (tails) for the makeup uranium. This fuel cycle is assumed not to use the recovered uranium output stream but to discard it instead. On the other hand, the AFC is assumed to recycle both the 5:1 U/Pu mixture and all of the recovered uranium. In this case, the recovered uranium is reenriched with the level of enrichment being determined by the amount of recovered plutonium and the combined amount

  16. Annual Report: Advanced Energy Systems Fuel Cells (30 September 2013)

    Energy Technology Data Exchange (ETDEWEB)

    Gerdes, Kirk; Richards, George

    2014-04-16

    The comprehensive research plan for Fuel Cells focused on Solid State Energy Conversion Alliance (SECA) programmatic targets and included objectives in two primary and focused areas: (1) investigation of degradation modes exhibited by the anode/electrolyte/cathode (AEC), development of computational models describing the associated degradation rates, and generation of a modeling tool predicting long term AEC degradation response; and (2) generation of novel electrode materials and microstructures and implementation of the improved electrode technology to enhance performance. In these areas, the National Energy Technology Laboratory (NETL) Regional University Alliance (RUA) team has completed and reported research that is significant to the SECA program, and SECA continued to engage all SECA core and SECA industry teams. Examination of degradation in an operational solid oxide fuel cell (SOFC) requires a logical organization of research effort into activities such as fundamental data gathering, tool development, theoretical framework construction, computational modeling, and experimental data collection and validation. Discrete research activity in each of these categories was completed throughout the year and documented in quarterly reports, and researchers established a framework to assemble component research activities into a single operational modeling tool. The modeling framework describes a scheme for categorizing the component processes affecting the temporal evolution of cell performance, and provides a taxonomical structure of known degradation processes. The framework is an organizational tool that can be populated by existing studies, new research completed in conjunction with SECA, or independently obtained. The Fuel Cell Team also leveraged multiple tools to create cell performance and degradation predictions that illustrate the combined utility of the discrete modeling activity. Researchers first generated 800 continuous hours of SOFC experimental

  17. IRRADIATION TESTING OF THE RERTR FUEL MINIPLATES WITH BURNABLE ABSORBERS IN THE ADVANCED TEST REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    I. Glagolenko; D. Wachs; N. Woolstenhulme; G. Chang; B. Rabin; C. Clark; T. Wiencek

    2010-10-01

    Based on the results of the reactor physics assessment, conversion of the Advanced Test Reactor (ATR) at the Idaho National Laboratory (INL) can be potentially accomplished in two ways, by either using U-10Mo monolithic or U-7Mo dispersion type plates in the ATR fuel element. Both designs, however, would require incorporation of the burnable absorber in several plates of the fuel element to compensate for the excess reactivity and to flatten the radial power profile. Several different types of burnable absorbers were considered initially, but only borated compounds, such as B4C, ZrB2 and Al-B alloys, were selected for testing primarily due to the length of the ATR fuel cycle and fuel manufacturing constraints. To assess and compare irradiation performance of the U-Mo fuels with different burnable absorbers we have designed and manufactured 28 RERTR miniplates (20 fueled and 8 non-fueled) containing fore-mentioned borated compounds. These miniplates will be tested in the ATR as part of the RERTR-13 experiment, which is described in this paper. Detailed plate design, compositions and irradiations conditions are discussed.

  18. Criticality safety evaluation for the Advanced Test Reactor enhanced low enriched uranium fuel elements

    Energy Technology Data Exchange (ETDEWEB)

    Montierth, Leland M. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-07-19

    The Global Threat Reduction Initiative (GTRI) convert program is developing a high uranium density fuel based on a low enriched uranium (LEU) uranium-molybdenum alloy. Testing of prototypic GTRI fuel elements is necessary to demonstrate integrated fuel performance behavior and scale-up of fabrication techniques. GTRI Enhanced LEU Fuel (ELF) elements based on the ATR-Standard Size elements (all plates fueled) are to be fabricated for testing in the Advanced Test Reactor (ATR). While a specific ELF element design will eventually be provided for detailed analyses and in-core testing, this criticality safety evaluation (CSE) is intended to evaluate a hypothetical ELF element design for criticality safety purposes. Existing criticality analyses have analyzed Standard (HEU) ATR elements from which controls have been derived. This CSE documents analysis that determines the reactivity of the hypothetical ELF fuel elements relative to HEU ATR elements and whether the existing HEU ATR element controls bound the ELF element. The initial calculations presented in this CSE analyzed the original ELF design, now referred to as Mod 0.1. In addition as part of a fuel meat thickness optimization effort for reactor performance other designs have been evaluated. As of early 2014 the most current conceptual designs are Mk1A and Mk1B that were previously referred to as conceptual designs Mod 0.10 and Mod 0.11, respectively. Revision 1 evaluates the reactivity of the ATR HEU Mark IV elements for a comparison with the Mark VII elements.

  19. Enhanced Low-Enriched Uranium Fuel Element for the Advanced Test Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Pope, M. A. [Idaho National Lab. (INL), Idaho Falls, ID (United States); DeHart, M. D. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Morrell, S. R. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Jamison, R. K. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Nef, E. C. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Nigg, D. W. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-03-01

    Under the current US Department of Energy (DOE) policy and planning scenario, the Advanced Test Reactor (ATR) and its associated critical facility (ATRC) will be reconfigured to operate on low-enriched uranium (LEU) fuel. This effort has produced a conceptual design for an Enhanced LEU Fuel (ELF) element. This fuel features monolithic U-10Mo fuel foils and aluminum cladding separated by a thin zirconium barrier. As with previous iterations of the ELF design, radial power peaking is managed using different U-10Mo foil thicknesses in different plates of the element. The lead fuel element design, ELF Mk1A, features only three fuel meat thicknesses, a reduction from the previous iterations meant to simplify manufacturing. Evaluation of the ELF Mk1A fuel design against reactor performance requirements is ongoing, as are investigations of the impact of manufacturing uncertainty on safety margins. The element design has been evaluated in what are expected to be the most demanding design basis accident scenarios and has met all initial thermal-hydraulic criteria.

  20. Criticality safety evaluation for the Advanced Test Reactor enhanced low enriched uranium fuel elements

    Energy Technology Data Exchange (ETDEWEB)

    Montierth, Leland M. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-07-19

    The Global Threat Reduction Initiative (GTRI) convert program is developing a high uranium density fuel based on a low enriched uranium (LEU) uranium-molybdenum alloy. Testing of prototypic GTRI fuel elements is necessary to demonstrate integrated fuel performance behavior and scale-up of fabrication techniques. GTRI Enhanced LEU Fuel (ELF) elements based on the ATR-Standard Size elements (all plates fueled) are to be fabricated for testing in the Advanced Test Reactor (ATR). While a specific ELF element design will eventually be provided for detailed analyses and in-core testing, this criticality safety evaluation (CSE) is intended to evaluate a hypothetical ELF element design for criticality safety purposes. Existing criticality analyses have analyzed Standard (HEU) ATR elements from which controls have been derived. This CSE documents analysis that determines the reactivity of the hypothetical ELF fuel elements relative to HEU ATR elements and whether the existing HEU ATR element controls bound the ELF element. The initial calculations presented in this CSE analyzed the original ELF design, now referred to as Mod 0.1. In addition, as part of a fuel meat thickness optimization effort for reactor performance, other designs have been evaluated. As of early 2014 the most current conceptual designs are Mk1A and Mk1B, that were previously referred to as conceptual designs Mod 0.10 and Mod 0.11, respectively. Revision 1 evaluates the reactivity of the ATR HEU Mark IV elements for a comparison with the Mark VII elements.

  1. Fuel Distribution Estimate via Spin Period to Precession Period Ratio for the Advanced Composition Explorer

    Science.gov (United States)

    DeHart, Russell; Smith, Eric; Lakin, John

    2015-01-01

    The spin period to precession period ratio of a non-axisymmetric spin-stabilized spacecraft, the Advanced Composition Explorer (ACE), was used to estimate the remaining mass and distribution of fuel within its propulsion system. This analysis was undertaken once telemetry suggested that two of the four fuel tanks had no propellant remaining, contrary to pre-launch expectations of the propulsion system performance. Numerical integration of possible fuel distributions was used to calculate moments of inertia for the spinning spacecraft. A Fast Fourier Transform (FFT) of output from a dynamics simulation was employed to relate calculated moments of inertia to spin and precession periods. The resulting modeled ratios were compared to the actual spin period to precession period ratio derived from the effect of post-maneuver nutation angle on sun sensor measurements. A Monte Carlo search was performed to tune free parameters using the observed spin period to precession period ratio over the life of the mission. This novel analysis of spin and precession periods indicates that at the time of launch, propellant was distributed unevenly between the two pairs of fuel tanks, with one pair having approximately 20% more propellant than the other pair. Furthermore, it indicates the pair of the tanks with less fuel expelled all of its propellant by 2014 and that approximately 46 kg of propellant remains in the other two tanks, an amount that closely matches the operational fuel accounting estimate. Keywords: Fuel Distribution, Moments of Inertia, Precession, Spin, Nutation

  2. Fuel, Structural Material and Coolant for an Advanced Fast Micro-Reactor

    Science.gov (United States)

    Do Nascimento, J. A.; Duimarães, L. N. F.; Ono, S.

    The use of nuclear reactors in space, seabed or other Earth hostile environment in the future is a vision that some Brazilian nuclear researchers share. Currently, the USA, a leader in space exploration, has as long-term objectives the establishment of a permanent Moon base and to launch a manned mission to Mars. A nuclear micro-reactor is the power source chosen to provide energy for life support, electricity for systems, in these missions. A strategy to develop an advanced micro-reactor technologies may consider the current fast reactor technologies as back-up and the development of advanced fuel, structural and coolant materials. The next generation reactors (GEN-IV) for terrestrial applications will operate with high output temperature to allow advanced conversion cycle, such as Brayton, and hydrogen production, among others. The development of an advanced fast micro-reactor may create a synergy between the GEN-IV and space reactor technologies. Considering a set of basic requirements and materials properties this paper discusses the choice of advanced fuel, structural and coolant materials for a fast micro-reactor. The chosen candidate materials are: nitride, oxide as back-up, for fuel, lead, tin and gallium for coolant, ferritic MA-ODS and Mo alloys for core structures. The next step will be the neutronic and burnup evaluation of core concepts with this set of materials.

  3. Impact of fuel properties on advanced power systems

    Energy Technology Data Exchange (ETDEWEB)

    Sondreal, E.A.; Jones, M.L.; Hurley, J.P.; Benson, S.A.; Willson, W.G. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-01

    Advanced coal-fired combined-cycle power systems currently in development and demonstration have the goal of increasing generating efficiency to a level approaching 50% while reducing the cost of electricity from new plants by 20% and meeting stringent standards on emissions of SO{sub x} NO{sub x} fine particulates, and air toxic metals. Achieving these benefits requires that clean hot gas be delivered to a gas turbine at a temperature approaching 1350{degrees}C, while minimizing energy losses in the gasification, combustion, heat transfer, and/or gas cleaning equipment used to generate the hot gas. Minimizing capital cost also requires that the different stages of the system be integrated as simply and compactly as possible. Second-generation technologies including integrated gasification combined cycle (IGCC), pressurized fluidized-bed combustion (PFBC), externally fired combined cycle (EFCC), and other advanced combustion systems rely on different high-temperature combinations of heat exchange, gas filtration, and sulfur capture to meet these requirements. This paper describes the various properties of lignite and brown coals.

  4. Radiation Damage in Nuclear Fuel for Advanced Burner Reactors: Modeling and Experimental Validation

    Energy Technology Data Exchange (ETDEWEB)

    Jensen, Niels Gronbech; Asta, Mark; Ozolins, Nigel Browning' Vidvuds; de Walle, Axel van; Wolverton, Christopher

    2011-12-29

    The consortium has completed its existence and we are here highlighting work and accomplishments. As outlined in the proposal, the objective of the work was to advance the theoretical understanding of advanced nuclear fuel materials (oxides) toward a comprehensive modeling strategy that incorporates the different relevant scales involved in radiation damage in oxide fuels. Approaching this we set out to investigate and develop a set of directions: 1) Fission fragment and ion trajectory studies through advanced molecular dynamics methods that allow for statistical multi-scale simulations. This work also includes an investigation of appropriate interatomic force fields useful for the energetic multi-scale phenomena of high energy collisions; 2) Studies of defect and gas bubble formation through electronic structure and Monte Carlo simulations; and 3) an experimental component for the characterization of materials such that comparisons can be obtained between theory and experiment.

  5. Future of petroleum-based adhesives polymers and tackifiers

    Energy Technology Data Exchange (ETDEWEB)

    De Stefano, J.M. [De Witt and Company, Venice, FL (United States)

    1995-12-31

    The growth of the adhesives business rests with the continuing availability of petroleum derived styrenic copolymers and hydrocarbon resin tackifiers. Within the past year, the styrene block copolymer market has gone ballistic due to an accident at one supplier plant and a delayed start-up at another. While there is a near-adequate supply of some copolymers, there is concern about the long term availability of the more popular styrene-isoprene-styrene (SIS) grades used in hot-melt adhesive formulations. Styrene may be tight at this moment but it will always be available because of its broad product base and favorable profit margin. However, the availability of isoprene, the key comonomer in SIS production, is very tight and prices are increasing. To a lesser degree, but equally important is the availability of suitable tackifying resins that are uniquely compatible with SIS. Currently these tackifiers are based on piperylene and cyclopentadiene feed stock. All three products; isoprene, piperylene and cyclopentadiene are pentadiene by-products produced in the dehydrogenation of ethane to ethylene. Ethylene is the most important petrochemical product in the world today. It drives the petrochemical industry. The objective of this paper is to help chemists and their managers understand the critical linkage of pentadiene building blocks with the macro-supply trains in the petrochemical and fuel industries.

  6. Results from the DOE Advanced Gas Reactor Fuel Development and Qualification Program

    Energy Technology Data Exchange (ETDEWEB)

    David Petti

    2014-06-01

    Modular HTGR designs were developed to provide natural safety, which prevents core damage under all design basis accidents and presently envisioned severe accidents. The principle that guides their design concepts is to passively maintain core temperatures below fission product release thresholds under all accident scenarios. This level of fuel performance and fission product retention reduces the radioactive source term by many orders of magnitude and allows potential elimination of the need for evacuation and sheltering beyond a small exclusion area. This level, however, is predicated on exceptionally high fuel fabrication quality and performance under normal operation and accident conditions. Germany produced and demonstrated high quality fuel for their pebble bed HTGRs in the 1980s, but no U.S. manufactured fuel had exhibited equivalent performance prior to the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program. The design goal of the modular HTGRs is to allow elimination of an exclusion zone and an emergency planning zone outside the plant boundary fence, typically interpreted as being about 400 meters from the reactor. To achieve this, the reactor design concepts require a level of fuel integrity that is better than that claimed for all prior US manufactured TRISO fuel, by a few orders of magnitude. The improved performance level is about a factor of three better than qualified for German TRISO fuel in the 1980’s. At the start of the AGR program, without a reactor design concept selected, the AGR fuel program selected to qualify fuel to an operating envelope that would bound both pebble bed and prismatic options. This resulted in needing a fuel form that could survive at peak fuel temperatures of 1250°C on a time-averaged basis and high burnups in the range of 150 to 200 GWd/MTHM (metric tons of heavy metal) or 16.4 to 21.8% fissions per initial metal atom (FIMA). Although Germany has demonstrated excellent performance of TRISO-coated UO

  7. Optimally Controlled Flexible Fuel Powertrain System

    Energy Technology Data Exchange (ETDEWEB)

    Duncan Sheppard; Bruce Woodrow; Paul Kilmurray; Simon Thwaite

    2011-06-30

    ) developed the Renewable Fuels Standard (RFS) under the Energy Policy Act of 2005. The RFS specifies targets for the amount of renewable fuel to be blended into petroleum based transportation fuels. The goal is to blend 36 billion gallons of renewable fuels into transportation fuels by 2022 (9 billion gallons were blended in 2008). The RFS also requires that the renewable fuels emit fewer greenhouse gasses than the petroleum fuels replaced. Thus the goal of the EPA is to have a more fuel efficient national fleet, less dependent on petroleum based fuels. The limit to the implementation of certain technologies employed was the requirement to run the developed powertrain on gasoline with minimal performance degradation. The addition of ethanol to gasoline fuels improves the fuels octane rating and increases the fuels evaporative cooling. Both of these fuel property enhancements make gasoline / ethanol blends more suitable than straight gasoline for use in downsized engines or engines with increased compression ratio. The use of engine downsizing and high compression ratios as well as direct injection (DI), dual independent cam phasing, external EGR, and downspeeding were fundamental to the fuel economy improvements targeted in this project. The developed powertrain specification utilized the MAHLE DI3 gasoline downsizing research engine. It was a turbocharged, intercooled, DI engine with dual independent cam phasing utilizing a compression ratio of 11.25 : 1 and a 15% reduction in final drive ratio. When compared to a gasoline fuelled 2.2L Ecotec engine in a Chevrolet HHR, vehicle drive cycle predictions indicate that the optimized powertrain operating on E85 would result in a reduced volume based drive cycle fuel economy penalty of 6% compared to an approximately 30% penalty for current technology engines.

  8. Intergovernmental Advanced Stationary PEM Fuel Cell System Demonstration Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Rich Chartrand

    2011-08-31

    efficiency and reducing costs of PEMFC based power systems using LPG fuel and continues to makes steps towards meeting DOE's targets. Plug Power would like to thank DOE for their support of this program.

  9. Research on advanced aqueous reprocessing of spent nuclear fuel: literature study

    Energy Technology Data Exchange (ETDEWEB)

    Van Hecke, K.; Goethals, P.

    2006-07-15

    The goal of the partitioning and transmutation strategy is to reduce the radiotoxicity of spent nuclear fuel to the level of natural uranium in a short period of time (about 1000 years) and thus the required containment period of radioactive material in a repository. Furthermore, it aims to reduce the volume of waste requiring deep geological disposal and hence the associated space requirements and costs. Several aqueous as well as pyrochemical separation processes have been developed for the partitioning of the long-lived radionuclides from the remaining of the spent fuel. This report aims to describe and compare advanced aqueous reprocessing methods.

  10. ADVANCING THE FUNDAMENTAL UNDERSTANDING AND SCALE-UP OF TRISO FUEL COATERS VIA ADVANCED MEASUREMENT AND COMPUTATIONAL TECHNIQUES

    Energy Technology Data Exchange (ETDEWEB)

    Biswas, Pratim; Al-Dahhan, Muthanna

    2012-11-01

    Tri-isotropic (TRISO) fuel particle coating is critical for the future use of nuclear energy produced byadvanced gas reactors (AGRs). The fuel kernels are coated using chemical vapor deposition in a spouted fluidized bed. The challenges encountered in operating TRISO fuel coaters are due to the fact that in modern AGRs, such as High Temperature Gas Reactors (HTGRs), the acceptable level of defective/failed coated particles is essentially zero. This specification requires processes that produce coated spherical particles with even coatings having extremely low defect fractions. Unfortunately, the scale-up and design of the current processes and coaters have been based on empirical approaches and are operated as black boxes. Hence, a voluminous amount of experimental development and trial and error work has been conducted. It has been clearly demonstrated that the quality of the coating applied to the fuel kernels is impacted by the hydrodynamics, solids flow field, and flow regime characteristics of the spouted bed coaters, which themselves are influenced by design parameters and operating variables. Further complicating the outlook for future fuel-coating technology and nuclear energy production is the fact that a variety of new concepts will involve fuel kernels of different sizes and with compositions of different densities. Therefore, without a fundamental understanding the underlying phenomena of the spouted bed TRISO coater, a significant amount of effort is required for production of each type of particle with a significant risk of not meeting the specifications. This difficulty will significantly and negatively impact the applications of AGRs for power generation and cause further challenges to them as an alternative source of commercial energy production. Accordingly, the proposed work seeks to overcome such hurdles and advance the scale-up, design, and performance of TRISO fuel particle spouted bed coaters. The overall objectives of the proposed work are

  11. ADVANCING THE FUNDAMENTAL UNDERSTANDING AND SCALE-UP OF TRISO FUEL COATERS VIA ADVANCED MEASUREMENT AND COMPUTATIONAL TECHNIQUES

    Energy Technology Data Exchange (ETDEWEB)

    Biswas, Pratim; Al-Dahhan, Muthanna

    2012-11-01

    Tri-isotropic (TRISO) fuel particle coating is critical for the future use of nuclear energy produced byadvanced gas reactors (AGRs). The fuel kernels are coated using chemical vapor deposition in a spouted fluidized bed. The challenges encountered in operating TRISO fuel coaters are due to the fact that in modern AGRs, such as High Temperature Gas Reactors (HTGRs), the acceptable level of defective/failed coated particles is essentially zero. This specification requires processes that produce coated spherical particles with even coatings having extremely low defect fractions. Unfortunately, the scale-up and design of the current processes and coaters have been based on empirical approaches and are operated as black boxes. Hence, a voluminous amount of experimental development and trial and error work has been conducted. It has been clearly demonstrated that the quality of the coating applied to the fuel kernels is impacted by the hydrodynamics, solids flow field, and flow regime characteristics of the spouted bed coaters, which themselves are influenced by design parameters and operating variables. Further complicating the outlook for future fuel-coating technology and nuclear energy production is the fact that a variety of new concepts will involve fuel kernels of different sizes and with compositions of different densities. Therefore, without a fundamental understanding the underlying phenomena of the spouted bed TRISO coater, a significant amount of effort is required for production of each type of particle with a significant risk of not meeting the specifications. This difficulty will significantly and negatively impact the applications of AGRs for power generation and cause further challenges to them as an alternative source of commercial energy production. Accordingly, the proposed work seeks to overcome such hurdles and advance the scale-up, design, and performance of TRISO fuel particle spouted bed coaters. The overall objectives of the proposed work are

  12. Reactor Physics Scoping and Characterization Study on Implementation of TRIGA Fuel in the Advanced Test Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Jennifer Lyons; Wade R. Marcum; Mark D. DeHart; Sean R. Morrell

    2014-01-01

    The Advanced Test Reactor (ATR), under the Reduced Enrichment for Research and Test Reactors (RERTR) Program and the Global Threat Reduction Initiative (GTRI), is conducting feasibility studies for the conversion of its fuel from a highly enriched uranium (HEU) composition to a low enriched uranium (LEU) composition. These studies have considered a wide variety of LEU plate-type fuels to replace the current HEU fuel. Continuing to investigate potential alternatives to the present HEU fuel form, this study presents a preliminary analysis of TRIGA® fuel within the current ATR fuel envelopes and compares it to the functional requirements delineated by the Naval Reactors Program, which includes: greater than 4.8E+14 fissions/s/g of 235U, a fast to thermal neutron flux ratio that is less than 5% deviation of its current value, a constant cycle power within the corner lobes, and an operational cycle length of 56 days at 120 MW. Other parameters outside those put forth by the Naval Reactors Program which are investigated herein include axial and radial power profiles, effective delayed neutron fraction, and mean neutron generation time.

  13. Advanced coal-fueled gas turbine systems: Subscale combustion testing. Topical report, Task 3.1

    Energy Technology Data Exchange (ETDEWEB)

    1993-05-01

    This is the final report on the Subscale Combustor Testing performed at Textron Defense Systems` (TDS) Haverhill Combustion Laboratories for the Advanced Coal-Fueled Gas Turbine System Program of the Westinghouse Electric Corp. This program was initiated by the Department of Energy in 1986 as an R&D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular staged, rich-lean-quench, Toroidal Vortex Slogging Combustor (TVC) concept. Fuel-rich conditions in the first stage inhibit NO{sub x} formation from fuel-bound nitrogen; molten coal ash and sulfated sorbent are removed, tapped and quenched from the combustion gases by inertial separation in the second stage. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The primary objective of this work was to verify the feasibility of a direct coal-fueled combustion system for combustion turbine applications. This has been accomplished by the design, fabrication, testing and operation of a subscale development-type coal-fired combustor. Because this was a complete departure from present-day turbine combustors and fuels, it was considered necessary to make a thorough evaluation of this design, and its operation in subscale, before applying it in commercial combustion turbine power systems.

  14. The Advanced High-Temperature Reactor (AHTR) for Producing Hydrogen to Manufacture Liquid Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Forsberg, C.W.; Peterson, P.F.; Ott, L.

    2004-10-06

    Conventional world oil production is expected to peak within a decade. Shortfalls in production of liquid fuels (gasoline, diesel, and jet fuel) from conventional oil sources are expected to be offset by increased production of fuels from heavy oils and tar sands that are primarily located in the Western Hemisphere (Canada, Venezuela, the United States, and Mexico). Simultaneously, there is a renewed interest in liquid fuels from biomass, such as alcohol; but, biomass production requires fertilizer. Massive quantities of hydrogen (H2) are required (1) to convert heavy oils and tar sands to liquid fuels and (2) to produce fertilizer for production of biomass that can be converted to liquid fuels. If these liquid fuels are to be used while simultaneously minimizing greenhouse emissions, nonfossil methods for the production of H2 are required. Nuclear energy can be used to produce H2. The most efficient methods to produce H2 from nuclear energy involve thermochemical cycles in which high-temperature heat (700 to 850 C) and water are converted to H2 and oxygen. The peak nuclear reactor fuel and coolant temperatures must be significantly higher than the chemical process temperatures to transport heat from the reactor core to an intermediate heat transfer loop and from the intermediate heat transfer loop to the chemical plant. The reactor temperatures required for H2 production are at the limits of practical engineering materials. A new high-temperature reactor concept is being developed for H2 and electricity production: the Advanced High-Temperature Reactor (AHTR). The fuel is a graphite-matrix, coated-particle fuel, the same type that is used in modular high-temperature gas-cooled reactors (MHTGRs). The coolant is a clean molten fluoride salt with a boiling point near 1400 C. The use of a liquid coolant, rather than helium, reduces peak reactor fuel and coolant temperatures 100 to 200 C relative to those of a MHTGR. Liquids are better heat transfer fluids than gases

  15. Axisymmetric whole pin life modelling of advanced gas-cooled reactor nuclear fuel

    Science.gov (United States)

    Mella, R.; Wenman, M. R.

    2013-06-01

    Thermo-mechanical contributions to pellet-clad interaction (PCI) in advanced gas-cooled reactors (AGRs) are modelled in the ABAQUS finite element (FE) code. User supplied sub-routines permit the modelling of the non-linear behaviour of AGR fuel through life. Through utilisation of ABAQUS's well-developed pre- and post-processing ability, the behaviour of the axially constrained steel clad fuel was modelled. The 2D axisymmetric model includes thermo-mechanical behaviour of the fuel with time and condition dependent material properties. Pellet cladding gap dynamics and thermal behaviour are also modelled. The model treats heat up as a fully coupled temperature-displacement study. Dwell time and direct power cycling was applied to model the impact of online refuelling, a key feature of the AGR. The model includes the visco-plastic behaviour of the fuel under the stress and irradiation conditions within an AGR core and a non-linear heat transfer model. A multiscale fission gas release model is applied to compute pin pressure; this model is coupled to the PCI gap model through an explicit fission gas inventory code. Whole pin, whole life, models are able to show the impact of the fuel on all segments of cladding including weld end caps and cladding pellet locking mechanisms (unique to AGR fuel). The development of this model in a commercial FE package shows that the development of a potentially verified and future-proof fuel performance code can be created and used. The usability of a FE based fuel performance code would be an enhancement over past codes. Pre- and post-processors have lowered the entry barrier for the development of a fuel performance model to permit the ability to model complicated systems. Typical runtimes for a 5 year axisymmetric model takes less than one hour on a single core workstation. The current model has implemented: Non-linear fuel thermal behaviour, including a complex description of heat flow in the fuel. Coupled with a variety of

  16. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1990--June 1991

    Energy Technology Data Exchange (ETDEWEB)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  17. Recent advances in direct methanol fuel cells at Los Alamos National Laboratory

    Science.gov (United States)

    Ren, Xiaoming; Zelenay, Piotr; Thomas, Sharon; Davey, John; Gottesfeld, Shimshon

    This paper describes recent advances in the science and technology of direct methanol fuel cells (DMFCs) made at Los Alamos National Laboratory (LANL). The effort on DMFCs at LANL includes work devoted to portable power applications, funded by the Defense Advanced Research Project Agency (DARPA), and work devoted to potential transport applications, funded by the US DOE. We describe recent results with a new type of DMFC stack hardware that allows to lower the pitch per cell to 2 mm while allowing low air flow and air pressure drops. Such stack technology lends itself to both portable power and potential transport applications. Power densities of 300 W/l and 1 kW/l seem achievable under conditions applicable to portable power and transport applications, respectively. DMFC power system analysis based on the performance of this stack, under conditions applying to transport applications (joint effort with U.C. Davis), has shown that, in terms of overall system efficiency and system packaging requirements, a power source for a passenger vehicle based on a DMFC could compete favorably with a hydrogen-fueled fuel cell system, as well as with fuel cell systems based on fuel processing on board. As part of more fundamental studies performed, we describe optimization of anode catalyst layers in terms of PtRu catalyst nature, loading and catalyst layer composition and structure. We specifically show that, optimized content of recast ionic conductor added to the catalyst layer is a sensitive function of the nature of the catalyst. Other elements of membrane/electrode assembly (MEA) optimization efforts are also described, highlighting our ability to resolve, to a large degree, a well-documented problem of polymer electrolyte DMFCs, namely "methanol crossover". This was achieved by appropriate cell design, enabling fuel utilization as high as 90% in highly performing DMFCs.

  18. Advanced chemical hydride-based hydrogen generation/storage system for fuel cell vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Breault, R.W.; Rolfe, J. [Thermo Power Corp., Waltham, MA (United States)

    1998-08-01

    Because of the inherent advantages of high efficiency, environmental acceptability, and high modularity, fuel cells are potentially attractive power supplies. Worldwide concerns over clean environments have revitalized research efforts on developing fuel cell vehicles (FCV). As a result of intensive research efforts, most of the subsystem technology for FCV`s are currently well established. These include: high power density PEM fuel cells, control systems, thermal management technology, and secondary power sources for hybrid operation. For mobile applications, however, supply of hydrogen or fuel for fuel cell operation poses a significant logistic problem. To supply high purity hydrogen for FCV operation, Thermo Power`s Advanced Technology Group is developing an advanced hydrogen storage technology. In this approach, a metal hydride/organic slurry is used as the hydrogen carrier and storage media. At the point of use, high purity hydrogen will be produced by reacting the metal hydride/organic slurry with water. In addition, Thermo Power has conceived the paths for recovery and regeneration of the spent hydride (practically metal hydroxide). The fluid-like nature of the spent hydride/organic slurry will provide a unique opportunity for pumping, transporting, and storing these materials. The final product of the program will be a user-friendly and relatively high energy storage density hydrogen supply system for fuel cell operation. In addition, the spent hydride can relatively easily be collected at the pumping station and regenerated utilizing renewable sources, such as biomass, natural, or coal, at the central processing plants. Therefore, the entire process will be economically favorable and environmentally friendly.

  19. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    Energy Technology Data Exchange (ETDEWEB)

    Smit, F.J.; Jha, M.C.; Phillips, D.I.; Yoon, R.H.

    1997-04-25

    The goal of this project is engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. Its scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design and construction of a 2 t/h process development unit (PDU). Large lots of clean coal are to be produced in the PDU from three project coals. Investigation of the near-term applicability of the two advanced fine coal cleaning processes in an existing coal preparation plant is another goal of the project and is the subject of this report.

  20. Status of the Combined Third and Fourth NGNP Fuel Irradiations In the Advanced Test Reactor

    Energy Technology Data Exchange (ETDEWEB)

    S. Blaine Grover; David A. Petti; Michael E. Davenport

    2013-07-01

    The United States Department of Energy’s Next Generation Nuclear Plant (NGNP) Advanced Gas Reactor (AGR) Fuel Development and Qualification Program is irradiating up to seven low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States. The experiments will be irradiated over the next several years to demonstrate and qualify new TRISO coated particle fuel for use in high temperature gas reactors. The goals of the experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which will each consist of several independent capsules, will be irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gas will also have on-line fission product monitoring on its effluent to track performance of the fuel in each individual capsule during irradiation. The first experiment (designated AGR-1) started irradiation in December 2006 and was completed in November 2009. The second experiment (AGR-2) started irradiation in June 2010 and is currently scheduled to be completed in September 2013. The third and fourth experiments have been combined into a single experiment designated (AGR-3/4), which started its irradiation in December 2011 and is currently scheduled to be completed in April 2014. Since the purpose of this combined experiment is to provide data on fission product migration and retention in the NGNP reactor, the design of this experiment is

  1. Fabrication and Comparison of Fuels for Advanced Gas Reactor Irradiation Tests

    Energy Technology Data Exchange (ETDEWEB)

    Jeffrey Phillips; Charles Barnes; John Hunn

    2010-10-01

    As part of the program to demonstrate TRISO-coated fuel for the Next Generation Nuclear Plant, a series of irradiation tests of Advanced Gas Reactor (AGR) fuel are being performed in the Advanced Test Reactor (ATR) at the Idaho National Laboratory. In the first test, called “AGR-1,” graphite compacts containing approximately 300,000 coated particles were irradiated from December 2006 until November 2009. Development of AGR-1 fuel sought to replicate the properties of German TRISO-coated particles. No particle failures were seen in the nearly 3-year irradiation to a burn up of 19%. The AGR-1 particles were coated in a two-inch diameter coater. Following fabrication of AGR-1 fuel, process improvements and changes were made in each of the fabrication processes. Changes in the kernel fabrication process included replacing the carbon black powder feed with a surface-modified carbon slurry and shortening the sintering schedule. AGR-2 TRISO particles were produced in a six-inch diameter coater using a change size about twenty-one times that of the two-inch diameter coater used to coat AGR-1 particles. Changes were also made in the compacting process, including increasing the temperature and pressure of pressing and using a different type of press. Irradiation of AGR-2 fuel began in late spring 2010. Properties of AGR-2 fuel compare favorably with AGR-1 and historic German fuel. Kernels are more homogeneous in shape, chemistry and density. TRISO-particle sphericity, layer thickness standard deviations, and defect fractions are also comparable. In a sample of 317,000 particles from deconsolidated AGR-2 compacts, 3 exposed kernels were found in a leach test. No SiC defects were found in a sample of 250,000 deconsolidated particles, and no IPyC defects in a sample of 64,000 particles. The primary difference in properties between AGR-1 and AGR-2 compacts is that AGR-2 compacts have a higher matrix density, 1.6 g/cm3 compared to about 1.3 g/cm3 for AGR-1 compacts. Based on

  2. Advances in medium and high temperature solid oxide fuel cell technology

    CERN Document Server

    Salvatore, Aricò

    2017-01-01

    In this book well-known experts highlight cutting-edge research priorities and discuss the state of the art in the field of solid oxide fuel cells giving an update on specific subjects such as protonic conductors, interconnects, electrocatalytic and catalytic processes and modelling approaches. Fundamentals and advances in this field are illustrated to help young researchers address issues in the characterization of materials and in the analysis of processes, not often tackled in scholarly books.

  3. Advanced combustion, emission control, health impacts, and fuels merit review and peer evaluation

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2006-10-01

    This report is a summary and analysis of comments from the Advisory Panel at the FY 2006 DOE National Laboratory Advanced Combustion, Emission Control, Health Impacts, and Fuels Merit Review and Peer Evaluation, held May 15-18, 2006 at Argonne National Laboratory. The work evaluated in this document supports the FreedomCAR and Vehicle Technologies Program. The results of this merit review and peer evaluation are major inputs used by DOE in making its funding decisions for the upcoming fiscal year.

  4. Environmental assessment for decontaminating and decommissioning the Westinghouse Advanced Reactors Division Plutonium Fuel Laboratories, Cheswick, PA

    Energy Technology Data Exchange (ETDEWEB)

    1980-12-01

    The Department of Energy has prepared an environmental assessment on the proposed decontamination and decommissioning of the Westinghouse Advanced Reactors Division Plutonium Fuel Laboratories, Cheswick, Pennsylvania. Based on the environmental assessment, which is available to the public on request, the Department has determined that the proposed action does not constitute a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act of 1969, 42 USC 4321 et seq. Therefore, no environmental impact statement is required. The proposed action is to decontaminate and decommission the Westinghouse Advanced Reactors Division fuel fabrication facilities (the Plutonium Laboratory - Building 7, and the Advanced Fuels Laboratory - Building 8). Decontamination and decommissioning of the facilities would require removal of all process equipment, the associated service lines, and decontamination of the interior surfaces of the buildings so that the empty buildings could be released for unrestricted use. Radioactive waste generated during these activities would be transported in licensed containers by truck for disposal at the Department's facility at Hanford, Washington. Useable non-radioactive materials would be sold as excess material, and non-radioactive waste would be disposed of by burial as sanitary landfill at an approved site.

  5. Reclaimation of petroleum-based wastewater by noval ozone immobilized biological activated carbon process

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Wastewater reclamation in the petroleum industries in Northern China is important because of the shortage of water resource. Conventional treatment technology used in treating petroleum-based wastewater,namely the 3-phase biological process, typically removes COD, BOD, grease, volatile hydrobenzenes, cyanides, sulfides and suspended solids. However, the process is often ineffective in ammonia-nitrogen removal,and thus the treated effluent quantity can't meet the required standards for reuse. This paper investigated a novel ozone immobilized biological activated carbon (O3-IBAC) process for ammonia nitrogen removal from petroleum-based wastewater. Operated at a HRT (Hydraulic Retention Time) of 15 minutes in IBAC1 and 27 minutes in IBAC2, the O3-IBAC process achieved ammonia nitrogen removal efficiency of 91%. In addition, the removal efficiencies of COD, volatile hydrobenzenes, suspended solids, turbidity and petroleum-based micropollutants were all above 90%. Competition between the autotrophs and heterotrophs was observed, which was indicated by an increase of ammonia nitrogen removal with a decrease of COD removal, and vise versa. Nitrite accumulation in IBAC1 followed by erobic shortcut denitrification in IBAC2 led to 28% of the Total Nitrogen removal efficiency. Pollutant reduction in the IBAC process was achieved by a rapid physical adsorption and biodegradation on the activated carbon, which effectively retained the pollutants in the system despite the short hydraulic retention time.

  6. Advanced characterization of MIMAS MOX fuel microstructure to quantify the HBS formation

    Energy Technology Data Exchange (ETDEWEB)

    Bouloré, Antoine, E-mail: antoine.boulore@cea.fr [CEA, DEN, DEC Fuel Research Department, Cadarache, F13108 Saint-Paul-lez-Durance (France); Aufore, Laurence; Federici, Eric [CEA, DEN, DEC Fuel Research Department, Cadarache, F13108 Saint-Paul-lez-Durance (France); Blanpain, Patrick [AREVA NP SAS, 10 rue Juliette Récamier, F-69456 Lyon (France); Blachier, Rémi [EDF, SEPTEN, 12-14 Av. Dutrievoz, F-69628 Villeurbanne (France)

    2015-01-15

    Highlights: • An advanced characterization of MIMAS MOX fuel based only on fresh fuel pellet characterization. • A probabilistic approach to model the High Burnup Structure formation in oxide fuels. • Validation of the method by comparing to experimental data obtained on fuel irradiated in the Halden reactor. - Abstract: Fission gas behaviour in accidental situations is closely related to the location of fission gas before the accident. More precisely, most of the fission gas in intergranular position is released during the accident and HBS zones contribute a lot to this intergranular quantity. So a methodology to characterize the HBS zones a priori from examination of unirradiated pellet has been developed at CEA. Characterization of plutonium distribution in MIMAS MOX fresh fuel pellets can be performed by image analysis on 1 mm{sup 2} X-ray mappings of plutonium acquired using Electron Probe Micro Analysis (EPMA). The specific software developed to describe the fuel using Pu X-ray mapping (ANACONDA) has been improved in order to simulate the fission products (FP) production and recoil during a given irradiation of the fuel, taking into account the evolution of the plutonium due to neutron irradiation. This simulation results from calculations with our fuel performance code ALCYONE combined with image processing. The final result is a mapping of local burn-up, but also the distribution of the relative FP concentration as a function of the local burn-up. A validation of this simulation process has been done by comparing the simulated mapping of neodymium to one measured on the same fuel batch after irradiation. Using previous studies of mechanisms for HBS formation, a probabilistic criterion for HBS formation has been proposed, based on the EPMA measurements of the decrease of the xenon signal as a function of the local burn-up. Combining the simulated FP cartography with this probabilistic HBS formation criterion, it is possible to calculate the surface

  7. Cadmium Depletion Impacts on Hardening Neutron6 Spectrum for Advanced Fuel Testing in ATR

    Energy Technology Data Exchange (ETDEWEB)

    Gray S. Chang

    2011-05-01

    For transmuting long-lived isotopes contained in spent nuclear fuel into shorter-lived fission products effectively is in a fast neutron spectrum reactor. In the absence of a fast spectrum test reactor in the United States of America (USA), initial irradiation testing of candidate fuels can be performed in a thermal test reactor that has been modified to produce a test region with a hardened neutron spectrum. A test region is achieved with a Cadmium (Cd) filter which can harden the neutron spectrum to a spectrum similar (although still somewhat softer) to that of the liquid metal fast breeder reactor (LMFBR). A fuel test loop with a Cd-filter has been installed within the East Flux Trap (EFT) of the Advanced Test Reactor (ATR) at the Idaho National Laboratory (INL). A detailed comparison analyses between the cadmium (Cd) filter hardened neutron spectrum in the ATR and the LMFBR fast neutron spectrum have been performed using MCWO. MCWO is a set of scripting tools that are used to couple the Monte Carlo transport code MCNP with the isotope depletion and buildup code ORIGEN-2.2. The MCWO-calculated results indicate that the Cd-filter can effectively flatten the Rim-Effect and reduce the linear heat rate (LHGR) to meet the advanced fuel testing project requirements at the beginning of irradiation (BOI). However, the filtering characteristics of Cd as a strong absorber quickly depletes over time, and the Cd-filter must be replaced for every two typical operating cycles within the EFT of the ATR. The designed Cd-filter can effectively depress the LHGR in experimental fuels and harden the neutron spectrum enough to adequately flatten the Rim Effect in the test region.

  8. Recent advances in microbial production of fuels and chemicals using tools and strategies of systems metabolic engineering

    DEFF Research Database (Denmark)

    Cho, Changhee; Choi, So Young; Luo, Zi Wei;

    2015-01-01

    The advent of various systems metabolic engineering tools and strategies has enabled more sophisticated engineering of microorganisms for the production of industrially useful fuels and chemicals. Advances in systems metabolic engineering have been made in overproducing natural chemicals and prod......The advent of various systems metabolic engineering tools and strategies has enabled more sophisticated engineering of microorganisms for the production of industrially useful fuels and chemicals. Advances in systems metabolic engineering have been made in overproducing natural chemicals...

  9. Design and verification of shielding for the advanced spent fuel conditioning process facility.

    Science.gov (United States)

    Cho, I J; Kook, D H; Kwon, K C; Lee, E P; Choung, W M; You, G S

    2008-05-01

    An Advanced spent fuel Conditioning Process Facility (ACPF) has recently been constructed by a modification of previously unused cells. ACPF is a hot cell with two rooms located in the basement of the Irradiated Materials Experiment Facility (IMEF) at the Korea Atomic Energy Research Institute. This is for demonstrating the advanced spent fuel conditioning process being proposed in Korea, which is an electrolytic reduction process of spent oxide fuels into a metallic form. The ACPF was designed with a more than 90 cm thick high density concrete shield wall to handle 1.38 PBq (37,430 Ci) of radioactive materials with dose rates lower than 10 muSv h in the operational areas (7,000 zone) and 150 muSv h in the service areas (8,000 zone). In Monte Carlo calculations with a design basis source inventory, the results for the bounding wall showed a maximum of 3 muSv h dose rate at an exterior surface of the ACPF for gamma radiation and 0.76 muSv h for neutrons. All the bounding structures of the ACPF were investigated to check on the shielding performance of the facility to ensure the radiation safety of the facility. A test was performed with a 2.96 TBq (80 Ci) 60Co source unit and the test results were compared with the calculation results. A few failure points were discovered and carefully fixed to meet the design criteria. After fixing the problems, the failure points were rechecked and the safety of the shielding structures was confirmed. In conclusion, it was confirmed that all the investigated parts of the ACPF passed the shielding safety limits by using this program and the ACPF is ready to fulfill its tasks for the advanced spent fuel conditioning process.

  10. Coated Particles Fuel Compact-General Purpose Heat Source for Advanced Radioisotope Power Systems

    Science.gov (United States)

    El-Genk, Mohamed S.; Tournier, Jean-Michel

    2003-01-01

    Coated Particles Fuel Compacts (CPFC) have recently been shown to offer performance advantage for use in Radioisotope Heater Units (RHUs) and design flexibility for integrating at high thermal efficiency with Stirling Engine converters, currently being considered for 100 We. Advanced Radioisotope Power Systems (ARPS). The particles in the compact consist of 238PuO2 fuel kernels with 5-μm thick PyC inner coating and a strong ZrC outer coating, whose thickness depends on the maximum fuel temperature during reentry, the fuel kernel diameter, and the fraction of helium gas released from the kernels and fully contained by the ZrC coating. In addition to containing the helium generated by radioactive decay of 238Pu for up to 10 years before launch and 10-15 years mission lifetime, the kernels are intentionally sized (>= 300 μm in diameter) to prevent any adverse radiological effects on reentry. This paper investigates the advantage of replacing the four iridium-clad 238PuO2 fuel pellets, the two floating graphite membranes, and the two graphite impact shells in current State-Of-The-Art (SOA) General Purpose Heat Source (GPHS) with CPFC. The total mass, thermal power, and specific power of the CPFC-GPHS are calculated as functions of the helium release fraction from the fuel kernels and maximum fuel temperature during reentry from 1500 K to 2400 K. For the same total mass and volume as SOA GPHS, the generated thermal power by single-size particles CPFC-GPHS is 260 W at Beginning-Of-Mission (BOM), versus 231 W for the GPHS. For an additional 10% increase in total mass, the CPFC-GPHS could generate 340 W BOM; 48% higher than SOA GPHS. The corresponding specific thermal power is 214 W/kg, versus 160 W/kg for SOA GPHS; a 34% increase. Therefore, for the same thermal power, the CPFC-GPHS is lighter than SOA GPHS, while it uses the same amount of 238PuO2 fuel and same aeroshell. For the same helium release fraction and fuel temperature, binary-size particles CPFC-GPHS could

  11. Analysis of advanced european nuclear fuel cycle scenarios including transmutation and economical estimates

    Energy Technology Data Exchange (ETDEWEB)

    Merino Rodriguez, I.; Alvarez-Velarde, F.; Martin-Fuertes, F. [CIEMAT, Avda. Complutense, 40, 28040 Madrid (Spain)

    2013-07-01

    In this work the transition from the existing Light Water Reactors (LWR) to the advanced reactors is analyzed, including Generation III+ reactors in a European framework. Four European fuel cycle scenarios involving transmutation options have been addressed. The first scenario (i.e., reference) is the current fleet using LWR technology and open fuel cycle. The second scenario assumes a full replacement of the initial fleet with Fast Reactors (FR) burning U-Pu MOX fuel. The third scenario is a modification of the second one introducing Minor Actinide (MA) transmutation in a fraction of the FR fleet. Finally, in the fourth scenario, the LWR fleet is replaced using FR with MOX fuel as well as Accelerator Driven Systems (ADS) for MA transmutation. All scenarios consider an intermediate period of GEN-III+ LWR deployment and they extend for a period of 200 years looking for equilibrium mass flows. The simulations were made using the TR-EVOL code, a tool for fuel cycle studies developed by CIEMAT. The results reveal that all scenarios are feasible according to nuclear resources demand (U and Pu). Concerning to no transmutation cases, the second scenario reduces considerably the Pu inventory in repositories compared to the reference scenario, although the MA inventory increases. The transmutation scenarios show that elimination of the LWR MA legacy requires on one hand a maximum of 33% fraction (i.e., a peak value of 26 FR units) of the FR fleet dedicated to transmutation (MA in MOX fuel, homogeneous transmutation). On the other hand a maximum number of ADS plants accounting for 5% of electricity generation are predicted in the fourth scenario (i.e., 35 ADS units). Regarding the economic analysis, the estimations show an increase of LCOE (Levelized cost of electricity) - averaged over the whole period - with respect to the reference scenario of 21% and 29% for FR and FR with transmutation scenarios respectively, and 34% for the fourth scenario. (authors)

  12. Advanced Fuel Cycle Initiative (AFCI) Repository Impact Evaluation FY-05 Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Halsey, W G

    2005-09-12

    An important long-term objective of advanced nuclear fuel cycle (AFC) technologies is to provide improvement in the long-term management of radioactive waste. Compared to a once-thru fuel cycle, it is possible to generate far less waste, and potentially easier waste to manage, with advanced fuel cycles. However, the precise extent and value of these benefits are complex and difficult to quantify. This document presents a status report of efforts within AFCI Systems Analysis to define and quantify the AFC benefits to geologic disposal, development of cooperative efforts with the US repository program, and participation with international evaluations of AFC impacts on waste management. The primary analysis of repository benefits is conducted by ANL. This year repository impact evaluations have included: (1) Continued evaluation of LWR recycle benefits in support of scenario analysis. (2) Extension of repository analyses to consider long-term dose reductions. (3) Developing the opportunity for cooperation with the U.S. repository program. (4) International cooperation with OECD-NEA.

  13. Monolithic solid oxide fuel cell technology advancement for coal-based power generation

    Science.gov (United States)

    1994-05-01

    This project has successfully advanced the technology for MSOFC's for coal-based power generation. Major advances include: tape-calendering processing technology, leading to 3X improved performance at 1000 C; stack materials formulations and designs with sufficiently close thermal expansion match for no stack damage after repeated thermal cycling in air; electrically conducting bonding with excellent structural robustness; and sealants that form good mechanical seals for forming manifold structures. A stack testing facility was built for high-spower MSOFC stacks. Comprehensive models were developed for fuel cell performance and for analyzing structural stresses in multicell stacks and electrical resistance of various stack configurations. Mechanical and chemical compatibility properties of fuel cell components were measured; they show that the baseline Ca-, Co-doped interconnect expands and weakens in hydrogen fuel. This and the failure to develop adequate sealants were the reason for performance shortfalls in large stacks. Small (1-in. footprint) two-cell stacks were fabricated which achieved good performance (average area-specific-resistance 1.0 ohm-sq cm per cell); however, larger stacks had stress-induced structural defects causing poor performance.

  14. Advanced aqueous reprocessing in P and T strategies: process demonstrations on genuine fuels and targets

    Energy Technology Data Exchange (ETDEWEB)

    Satmark, B.; Apostolidis, C.; Courson, O.; Malmbeck, R.; Carlos, R.; Pagliosa, G.; Romer, K.; Glatz, J.P. [European Commission, DG-JRC, Institute for Transuranium Elements, Hot Cell Technology, Karlsruhe (Germany)

    2000-07-01

    In the present work the performance of several processes used for advanced reprocessing of commercial LWR fuels as well as transmutation targets is compared. As a first step uranium and plutonium were recovered by PUREX type reprocessing. The raffinate, containing fission products, lanthanides and the minor actinides (MA) were used as feed for the second step in which minor actinides and lanthanides were separated from the bulk of the fission products. The five different processes tested use CMPO, DIDPA, TRPO, Diamide and CYANEX 923 as extractant. In the third step MA are separated from lanthanides. Here three processes were tested, i.e. using CYANEX 301, the synergistic mixture of di-chloro substituted CYANEX 301 and TOPO, and BTP solvents. Column-, batch- and continuous counter-current extraction techniques were used for the tests. The different processes will be described and discussed in terms of performances and efficiencies for Am and Cm. Efficient separation of MA from different genuine fuel solutions could be demonstrated and thereby also the possibility of closing a future transmutation fuel cycle. The combination, Diamide and BTP was found to be the best among extractants tested to achieve an efficient MA recovery from spent fuel. (authors)

  15. Advanced aqueous reprocessing in P and T strategies: process demonstrations on genuine fuels and targets

    Energy Technology Data Exchange (ETDEWEB)

    Christiansen, B.; Apostolidis, C.; Carlos, R.; Courson, O.; Glatz, J.P.; Malmbeck, R.; Pagliosa, G.; Roemer, K.; Serrano-Purroy, D. [European Commission, JRC, Inst. for Transuranium Elements, Karlsruhe (Germany)

    2004-07-01

    In the present work the performance of several processes used for advanced reprocessing of commercial LWR fuels as well as transmutation targets is compared. As a first step uranium and plutonium were recovered by PUREX type reprocessing. The raffinate, containing fission products including lanthanides and the minor actinides (MA) was used as feed for the second step in which minor actinides and lanthanides were separated from the bulk of the fission products. The five different processes tested use CMPO, DIDPA, TRPO, diamide and CYANEX 923 as extractants. In the third step MA are separated from lanthanides. Here three processes were tested, i.e. using CYANEX 301, the synergistic mixture of di-chloro substituted CYANEX 301 and TOPO, and BTP solvents. Column-, batch- and continuous counter-current extraction techniques were used for the tests. The different processes will be described and discussed in terms of performances and efficiencies for Am and Cm separation. Efficient separation of MA from different genuine fuel solutions could be demonstrated and thereby also the possibility of closing a future transmutation fuel cycle. The combination of diamide and BTP seems to be the best, among extractants tested, to achieve an efficient MA recovery from spent fuel. (orig.)

  16. REVA Advanced Fuel Design and Codes and Methods - Increasing Reliability, Operating Margin and Efficiency in Operation

    Energy Technology Data Exchange (ETDEWEB)

    Frichet, A.; Mollard, P.; Gentet, G.; Lippert, H. J.; Curva-Tivig, F.; Cole, S.; Garner, N.

    2014-07-01

    Since three decades, AREVA has been incrementally implementing upgrades in the BWR and PWR Fuel design and codes and methods leading to an ever greater fuel efficiency and easier licensing. For PWRs, AREVA is implementing upgraded versions of its HTP{sup T}M and AFA 3G technologies called HTP{sup T}M-I and AFA3G-I. These fuel assemblies feature improved robustness and dimensional stability through the ultimate optimization of their hold down system, the use of Q12, the AREVA advanced quaternary alloy for guide tube, the increase in their wall thickness and the stiffening of the spacer to guide tube connection. But an even bigger step forward has been achieved a s AREVA has successfully developed and introduces to the market the GAIA product which maintains the resistance to grid to rod fretting (GTRF) of the HTP{sup T}M product while providing addition al thermal-hydraulic margin and high resistance to Fuel Assembly bow. (Author)

  17. Development of a System Dynamics Model for Evaluating the Economics of an Advanced CANDU Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Jong Yeob; Park, Joo Hwan [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2009-10-15

    Since the early 1990's, the Korea Atomic Energy Research Institute (KAERI) and the Atomic Energy of Canada Limited (AECL) have cooperated to develop, verify, and demonstrate the advanced CANDU fuel, so called CANFLEX-NU (Natural Uranium). The CANFLEX-NU fuel bundle consists of 43 fuel elements and has the buttons on the outer surface of the fuel elements for improving the CHF (Critical-Heat-Flux) characteristics. Because of this features of CANFLEXNU fuel, it offers higher operating and safety margins than current 37-element fuel. Recently, the interest for a CANFLEX-NU has been increased because of the power de-rating due to aging of CANDU reactors. Wolsong Unit 1 CANDU reactor has been operated over 25 years and the operating power at the present time is less than 90% of a full power because of a reduction of the margin of ROP trip set point. The most appropriate way to overcome such a power de-rating due to a crept pressure tube is the introduction of a CANFLEX-NU fuel into a CANDU reactor. Now, a CANFLEX-NU fuel is ready to be commercialized in a CANDU-6 reactor because the design and demonstration irradiation have been completed in both Korea and Canada. Economic evaluation for commercializing a CANFLEX-NU fuel in Wolsong Units was carried out by calculating the unit prime cost of electricity production. Throughout the economic evaluation, it was found that the introduction of CANFLEX-NU fuel into Wolsong Units would have much economic benefits due to a better operating performance. However, the amount of economic profit due to introducing CANFLEX-NU fuel depends on several parameters such as the required time to get license from regulatory institute before commercializing, licensing cost, failure probability of commercializing etc. Therefore, it is necessary to determine the optimum condition to get the highest economic profit. In this paper, an economic evaluation was carried out based on the starting year of the licensing study with considering the

  18. Materials Research Advances towards High-Capacity Battery/Fuel Cell Devices (Invited paper)

    Institute of Scientific and Technical Information of China (English)

    Wei-Dong He; Lu-Han Ye; Ke-Chun Wen; Ya-Chun Liang; Wei-Qiang Lv; Gao-Long Zhu; Kelvin H. L. Zhang

    2016-01-01

    The world has entered an era featured with fast transportations, instant communications, and prompt technological revolutions, the further advancement of which all relies fundamentally, yet, on the development of cost-effective energy resources allowing for durable and high-rate energy supply. Current battery and fuel cell systems are challenged by a few issues characterized either by insufficient energy capacity or by operation instability and, thus, are not ideal for such highly-demanded applications as electrical vehicles and portable electronic devices. In this mini-review, we present, from materials perspectives, a few selected important breakthroughs in energy resources employed in these applications. Prospectives are then given to look towards future research activities for seeking viable materials solutions for addressing the capacity, durability, and cost shortcomings associated with current battery/fuel cell devices.

  19. The development of technical database of advanced spent fuel management process

    Energy Technology Data Exchange (ETDEWEB)

    Ro, Seung Gy; Byeon, Kee Hoh; Song, Dae Yong; Park, Seong Won; Shin, Young Jun

    1999-03-01

    The purpose of this study is to develop the technical database system to provide useful information to researchers who study on the back end nuclear fuel cycle. Technical database of advanced spent fuel management process was developed for a prototype system in 1997. In 1998, this database system is improved into multi-user systems and appended special database which is composed of thermochemical formation data and reaction data. In this report, the detailed specification of our system design is described and the operating methods are illustrated as a user's manual. Also, expanding current system, or interfacing between this system and other system, this report is very useful as a reference. (Author). 10 refs., 18 tabs., 46 fig.

  20. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    Energy Technology Data Exchange (ETDEWEB)

    Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-08-28

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction and operation of 2 t/hr process development unit (PDU). This report represents the findings of the PDU Advanced Column Flotation Testing and Evaluation phase of the program and includes a discussion of the design and construction of the PDU. Three compliance steam coals, Taggart, Indiana VII and Hiawatha, were processed in the PDU to determine performance and design parameters for commercial production of premium fuel by advanced flotation. Consistent, reliable performance of the PDU was demonstrated by 72-hr production runs on each of the test coals. Its capacity generally was limited by the dewatering capacity of the clean coal filters during the production runs rather than by the flotation capacity of the Microcel column. The residual concentrations of As, Pb, and Cl were reduced by at least 25% on a heating value basis from their concentrations in the test coals. The reduction in the concentrations of Be, Cd, Cr, Co, Mn, Hg, Ni and Se varied from coal to coal but the concentrations of most were greatly reduced from the concentrations in the ROM parent coals. The ash fusion temperatures of the Taggart and Indiana VII coals, and to a much lesser extent the Hiawatha coal, were decreased by the cleaning.

  1. Novel approaches in advanced combustion characterization of fuels for advanced pressurized combustion

    Energy Technology Data Exchange (ETDEWEB)

    Aho, M.; Haemaelaeinen, J. [VTT Energy (Finland); Joutsenoja, T. [Tampere Univ. of Technology (Finland)

    1996-12-01

    This project is a part of the EU Joule 2 (extension) programme. The objective of the research of Technical Research Centre of Finland (VTT) is to produce experimental results of the effects of pressure and other important parameters on the combustion of pulverized coals and their char derivates. The results can be utilized in modelling of pressurized combustion and in planning pilot-scale reactors. The coals to be studied are Polish hvb coal, French lignite (Gardanne), German anthracite (Niederberg) and German (Goettelbom) hvb coal. The samples are combusted in an electrically heated, pressurized entrained flow reactor (PEFR), where the experimental conditions are controlled with a high precision. The particle size of the fuel can vary between 100 and 300 {mu}m. The studied things are combustion rates, temperatures and sizes of burning single coal and char particles. The latter measurements are performed with a method developed by Tampere University of Technology, Finland. In some of the experiments, mass loss and elemental composition of the char residue are studied in more details as the function of time to find out the combustion mechanism. Combustion rate of pulverized (140-180 {mu}m) Gardanne lignite and Niederberg anthracite were measured and compared with the data obtained earlier with Polish hvb coal at various pressures, gas temperatures, oxygen partial pressures and partial pressures of carbon dioxide in the second working period. In addition, particle temperatures were measured with anthracite. The experimental results were treated with multivariable partial least squares (PLS) method to find regression equation between the measured things and the experimental variables. (author)

  2. Monolithic solid oxide fuel cell technology advancement for coal-based power generation

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-14

    The program is conducted by a team consisting of AiResearch Los Angeles Division of Allied-Signal Aerospace Company and Argonne National Laboratory (ANL). The objective of the program is to advance materials and fabrication methodologies to develop a monolithic solid oxide fuel cell (MSOFC) system capable of meeting performance, life, and cost goals for coal-based power generation. The program focuses on materials research and development, fabrication process development, cell/stack performance testing and characterization, cost and system analysis, and quality development.

  3. Dataset for petroleum based stock markets and GAUSS codes for SAMEM.

    Science.gov (United States)

    Khalifa, Ahmed A A; Bertuccelli, Pietro; Otranto, Edoardo

    2017-02-01

    This article includes a unique data set of a balanced daily (Monday, Tuesday and Wednesday) for oil and natural gas volatility and the oil rich economies' stock markets for Saudi Arabia, Qatar, Kuwait, Abu Dhabi, Dubai, Bahrain and Oman, using daily data over the period spanning Oct. 18, 2006-July 30, 2015. Additionally, we have included unique GAUSS codes for estimating the spillover asymmetric multiplicative error model (SAMEM) with application to Petroleum-Based Stock Market. The data, the model and the codes have many applications in business and social science.

  4. Dataset for petroleum based stock markets and GAUSS codes for SAMEM

    Directory of Open Access Journals (Sweden)

    Ahmed A.A. Khalifa

    2017-02-01

    Full Text Available This article includes a unique data set of a balanced daily (Monday, Tuesday and Wednesday for oil and natural gas volatility and the oil rich economies’ stock markets for Saudi Arabia, Qatar, Kuwait, Abu Dhabi, Dubai, Bahrain and Oman, using daily data over the period spanning Oct. 18, 2006–July 30, 2015. Additionally, we have included unique GAUSS codes for estimating the spillover asymmetric multiplicative error model (SAMEM with application to Petroleum-Based Stock Market. The data, the model and the codes have many applications in business and social science.

  5. Results of studies on application of CCMHD to advanced fossil fuel power plant cycles

    Energy Technology Data Exchange (ETDEWEB)

    Foote, J.P.; Wu, Y.C.L.S.; Lineberry, J.T.

    1998-07-01

    A study was conducted to assess the potential for application of a Closed Cycle MHD disk generator (CCMHD) in advanced fossil fuel power generation systems. Cycle analyses were conducted for a variety of candidate power cycles, including simple cycle CCMHD (MHD); a cycle combining CCMHD and gas turbines (MHD/GT); and a triple combined cycle including CCMHD, gas turbines, and steam turbines (MHD/GT/ST). The above cycles were previously considered in cycle studies reported by Japanese researchers. Also considered was a CCMHD cycle incorporating thermochemical heat recovery through reforming of the fuel stream (MHD/REF), which is the first consideration of this approach. A gas turbine/steam turbine combined cycle (GT/ST) was also analyzed for baseline comparison. The only fuel considered in the study was CH4. Component heat and pressure losses were neglected, and the potential for NOx emission due to high combustion temperatures was not considered. Likewise, engineering limitations for cycle components, particularly the high temperature argon heater, were not considered. This approach was adopted to simplify the analysis for preliminary screening of candidate cycles. Cycle calculations were performed using in-house code. Ideal gas thermodynamic properties were calculated using the NASA SP- 273 data base, and thermodynamic properties for steam were calculated using the computerized ASME Steam Tables. High temperature equilibrium compositions for combustion gas were calculated using tabulated values of the equilibrium constants for the important reactions.

  6. Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications

    Energy Technology Data Exchange (ETDEWEB)

    Smit, Frank J; Schields, Gene L; Jha, Mehesh C; Moro, Nick

    1997-09-26

    The ash in six common bituminous coals, Taggart, Winifrede, Elkhorn No. 3, Indiana VII, Sunnyside and Hiawatha, could be liberated by fine grinding to allow preparation of clean coal meeting premium fuel specifications (< 1- 2 lb/ MBtu ash and <0.6 lb/ MBtu sulfur) by laboratory and bench- scale column flotation or selective agglomeration. Over 2,100 tons of coal were cleaned in the PDU at feed rates between 2,500 and 6,000 lb/ h by Microcel™ column flotation and by selective agglomeration using recycled heptane as the bridging liquid. Parametric testing of each process and 72- hr productions runs were completed on each of the three test coals. The following results were achieved after optimization of the operating parameters: The primary objective was to develop the design base for commercial fine coal cleaning facilities for producing ultra- clean coals which can be converted into coal-water slurry premium fuel. The coal cleaning technologies to be developed were advanced column flotation and selective agglomeration, and the goal was to produce fuel meeting the following specifications.

  7. Advances in solid polymer electrolyte fuel cell technology with low-platinum-loading electrodes

    Science.gov (United States)

    Srinivasan, Supramaniam; Ticianelli, E. A.; Derouin, C. R.; Redondo, A.

    1987-01-01

    The Gemini Space program demonstrated the first major application of fuel cell systems. Solid polymer electrolyte fuel cells were used as auxiliary power sources in the spacecraft. There has been considerable progress in this technology since then, particularly with the substitution of Nafion for the polystyrene sulfonate membrane as the electrolyte. Until recently the performance was good only with high platinum loading (4 mg/sq cm) electrodes. Methods are presented to advance the technology by (1) use of low platinum loading (0.35 mg/sq cm) electrodes; (2) optimization of anode/membrane/cathode interfaces by hot pressing; (3) pressurization of reactant gases, which is most important when air is used as cathodic reactant; and (4) adequate humidification of reactant gases to overcome the water management problem. The high performance of the fuel cell with the low loading of platinum appears to be due to the extension of the three dimensional reaction zone by introduction of a proton conductor, Nafion. This was confirmed by cyclic voltammetry.

  8. ENGINEERING DEVELOPMENT OF ADVANCED PHYSICAL FINE COAL CLEANING FOR PREMIUM FUEL APPLICATIONS

    Energy Technology Data Exchange (ETDEWEB)

    none,

    1997-06-01

    Bechtel, together with Amax Research and Development Center (Amax R&D), has prepared this study which provides conceptual cost estimates for the production of premium quality coal-water slurry fuel (CWF) in a commercial plant. Two scenarios are presented, one using column flotation technology and the other the selective agglomeration to clean the coal to the required quality specifications. This study forms part of US Department of Energy program "Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications," (Contract No. DE-AC22- 92PC92208), under Task 11, Project Final Report. The primary objective of the Department of Energy program is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to stable and highly loaded CWF. The fuels should contain less than 2 lb ash/MBtu (860 grams ash/GJ) of HHV and preferably less than 1 lb ash/MBtu (430 grams ash/GJ). The advanced fine coal cleaning technologies to be employed are advanced column froth flotation and selective agglomeration. It is further stipulated that operating conditions during the advanced cleaning process should recover not less than 80 percent of the carbon content (heating value) in the run-of-mine source coal. These goals for ultra-clean coal quality are to be met under the constraint that annualized coal production costs does not exceed $2.5 /MBtu ($ 2.37/GJ), including the mine mouth cost of the raw coal. A further objective of the program is to determine the distribution of a selected suite of eleven toxic trace elements between product CWF and the refuse stream of the cleaning processes. Laboratory, bench-scale and Process Development Unit (PDU) tests to evaluate advanced column flotation and selective agglomeration were completed earlier under this program with selected coal samples. A PDU with a capacity of 2 st/h was designed by Bechtel and installed at Amax R

  9. System analysis with improved thermo-mechanical fuel rod models for modeling current and advanced LWR materials in accident scenarios

    Science.gov (United States)

    Porter, Ian Edward

    A nuclear reactor systems code has the ability to model the system response in an accident scenario based on known initial conditions at the onset of the transient. However, there has been a tendency for these codes to lack the detailed thermo-mechanical fuel rod response models needed for accurate prediction of fuel rod failure. This proposed work will couple today's most widely used steady-state (FRAPCON) and transient (FRAPTRAN) fuel rod models with a systems code TRACE for best-estimate modeling of system response in accident scenarios such as a loss of coolant accident (LOCA). In doing so, code modifications will be made to model gamma heating in LWRs during steady-state and accident conditions and to improve fuel rod thermal/mechanical analysis by allowing axial nodalization of burnup-dependent phenomena such as swelling, cladding creep and oxidation. With the ability to model both burnup-dependent parameters and transient fuel rod response, a fuel dispersal study will be conducted using a hypothetical accident scenario under both PWR and BWR conditions to determine the amount of fuel dispersed under varying conditions. Due to the fuel fragmentation size and internal rod pressure both being dependent on burnup, this analysis will be conducted at beginning, middle and end of cycle to examine the effects that cycle time can play on fuel rod failure and dispersal. Current fuel rod and system codes used by the Nuclear Regulatory Commission (NRC) are compilations of legacy codes with only commonly used light water reactor materials, Uranium Dioxide (UO2), Mixed Oxide (U/PuO 2) and zirconium alloys. However, the events at Fukushima Daiichi and Three Mile Island accident have shown the need for exploration into advanced materials possessing improved accident tolerance. This work looks to further modify the NRC codes to include silicon carbide (SiC), an advanced cladding material proposed by current DOE funded research on accident tolerant fuels (ATF). Several

  10. Advanced fuel cycle cost estimation model and its cost estimation results for three nuclear fuel cycles using a dynamic model in Korea

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sungki, E-mail: sgkim1@kaeri.re.kr [Korea Atomic Energy Research Institute, 1045 Daedeokdaero, Yuseong-gu, Daejeon 305-353 (Korea, Republic of); Ko, Wonil [Korea Atomic Energy Research Institute, 1045 Daedeokdaero, Yuseong-gu, Daejeon 305-353 (Korea, Republic of); Youn, Saerom; Gao, Ruxing [University of Science and Technology, 217 Gajungro, Yuseong-gu, Daejeon 305-350 (Korea, Republic of); Bang, Sungsig, E-mail: ssbang@kaist.ac.kr [Korea Advanced Institute of Science and Technology, Department of Business and Technology Management, 291 Deahak-ro, Yuseong-gu, Daejeon 305-701 (Korea, Republic of)

    2015-11-15

    Highlights: • The nuclear fuel cycle cost using a new cost estimation model was analyzed. • The material flows of three nuclear fuel cycle options were calculated. • The generation cost of once-through was estimated to be 66.88 mills/kW h. • The generation cost of pyro-SFR recycling was estimated to be 78.06 mills/kW h. • The reactor cost was identified as the main cost driver of pyro-SFR recycling. - Abstract: The present study analyzes advanced nuclear fuel cycle cost estimation models such as the different discount rate model and its cost estimation results. To do so, an analysis of the nuclear fuel cycle cost of three options (direct disposal (once through), PWR–MOX (Mixed OXide fuel), and Pyro-SFR (Sodium-cooled Fast Reactor)) from the viewpoint of economic sense, focusing on the cost estimation model, was conducted using a dynamic model. From an analysis of the fuel cycle cost estimation results, it was found that some cost gap exists between the traditional same discount rate model and the advanced different discount rate model. However, this gap does not change the priority of the nuclear fuel cycle option from the viewpoint of economics. In addition, the fuel cycle costs of OT (Once-Through) and Pyro-SFR recycling based on the most likely value using a probabilistic cost estimation except for reactor costs were calculated to be 8.75 mills/kW h and 8.30 mills/kW h, respectively. Namely, the Pyro-SFR recycling option was more economical than the direct disposal option. However, if the reactor cost is considered, the economic sense in the generation cost between the two options (direct disposal vs. Pyro-SFR recycling) can be changed because of the high reactor cost of an SFR.

  11. Design and manufacturing of non-instrumented capsule for advanced PWR fuel pellet irradiation test in HANARO

    Energy Technology Data Exchange (ETDEWEB)

    Kim, D. H.; Lee, C. B.; Song, K. W. [Korea Atomic Energy Research Institute, Taejeon (Korea)

    2002-04-01

    This project is preparing to irradiation test of the developed large grain UO{sub 2} fuel pellet in HANARO for pursuit fuel safety and high burn-up in 'Advanced LWR Fuel Technology Development Project' as a part Nuclear Mid and Long-term R and D Program. On the basis test rod is performed the nuclei property and preliminary fuel performance analysis, test rod and non-instrumented capsule are designed and manufactured for irradiation test in HANARO. This non-instrumented irradiation capsule of Advanced PWR Fuel pellet was referred the non-instrumented capsule for an irradiation test of simulated DUPIC fuel in HANARO(DUPIC Rig-001) and 18-element HANARO fuel, was designed to ensure the integrity and the endurance of non-instrumented capsule during the long term(2.5 years) irradiation. To irradiate the UO{sub 2} pellets up to the burn-up 70 MWD/kgU, need the time about 60 months and ensure the integrity of non-instrumented capsule for 30 months until replace the new capsule. This non-instrumented irradiation capsule will be based to develope the non-instrumented capsule for the more long term irradiation in HANARO. 22 refs., 13 figs., 5 tabs. (Author)

  12. PEM Fuel Cells with Bio-Ethanol Processor Systems A Multidisciplinary Study of Modelling, Simulation, Fault Diagnosis and Advanced Control

    CERN Document Server

    Feroldi, Diego; Outbib, Rachid

    2012-01-01

    An apparently appropriate control scheme for PEM fuel cells may actually lead to an inoperable plant when it is connected to other unit operations in a process with recycle streams and energy integration. PEM Fuel Cells with Bio-Ethanol Processor Systems presents a control system design that provides basic regulation of the hydrogen production process with PEM fuel cells. It then goes on to construct a fault diagnosis system to improve plant safety above this control structure. PEM Fuel Cells with Bio-Ethanol Processor Systems is divided into two parts: the first covers fuel cells and the second discusses plants for hydrogen production from bio-ethanol to feed PEM fuel cells. Both parts give detailed analyses of modeling, simulation, advanced control, and fault diagnosis. They give an extensive, in-depth discussion of the problems that can occur in fuel cell systems and propose a way to control these systems through advanced control algorithms. A significant part of the book is also given over to computer-aid...

  13. Heat Transfer and Thermal Stability Research for Advanced Hydrocarbon Fuel Technologies

    Science.gov (United States)

    DeWitt, Kenneth; Stiegemeier, Benjamin

    2005-01-01

    In recent years there has been increased interest in the development of a new generation of high performance boost rocket engines. These efforts, which will represent a substantial advancement in boost engine technology over that developed for the Space Shuttle Main Engines in the early 1970s, are being pursued both at NASA and the United States Air Force. NASA, under its Space Launch Initiative s Next Generation Launch Technology Program, is investigating the feasibility of developing a highly reliable, long-life, liquid oxygen/kerosene (RP-1) rocket engine for launch vehicles. One of the top technical risks to any engine program employing hydrocarbon fuels is the potential for fuel thermal stability and material compatibility problems to occur under the high-pressure, high-temperature conditions required for regenerative fuel cooling of the engine combustion chamber and nozzle. Decreased heat transfer due to carbon deposits forming on wetted fuel components, corrosion of materials common in engine construction (copper based alloys), and corrosion induced pressure drop increases have all been observed in laboratory tests simulating rocket engine cooling channels. To mitigate these risks, the knowledge of how these fuels behave in high temperature environments must be obtained. Currently, due to the complexity of the physical and chemical process occurring, the only way to accomplish this is empirically. Heated tube testing is a well-established method of experimentally determining the thermal stability and heat transfer characteristics of hydrocarbon fuels. The popularity of this method stems from the low cost incurred in testing when compared to hot fire engine tests, the ability to have greater control over experimental conditions, and the accessibility of the test section, facilitating easy instrumentation. These benefits make heated tube testing the best alternative to hot fire engine testing for thermal stability and heat transfer research. This investigation

  14. Advanced thermally stable jet fuels. Technical progress report, January 1996--March 1996

    Energy Technology Data Exchange (ETDEWEB)

    Schobert, H.H.; Eser, S.; Song, C. [and others

    1996-08-01

    A reactive structure index was developed to correlate the molecular structures of saturated hydrocarbons with their reactivities using a linear group contribution method. The index is composed of several sub-indices determined from the structure, including carbon group indices, ring index, and conformation index. The effects on decomposition of ring structure, side-chain length, steric isomers, and branching were examined. Good correlations were obtained for two sets of saturated hydrocarbons. The reactivity of alkanes and cycloalkanes increases with increasing chain or side-chain length. Cycloalkanes are desirable components of advanced jet fuels, in terms of having higher thermal stability and density than n-alkanes of the same carbon number. The cis-isomer is usually more reactive than the trans-isomer, except for cis-1,3-dimethylcyclohexane. which is more stable than its trans-isomer. The presence of a branch or branches appears to decrease the decomposition rate compared to n-alkanes.

  15. Advanced thermally stable jet fuels. Technical progress report, April 1993--June 1993

    Energy Technology Data Exchange (ETDEWEB)

    Schobert, H.H.; Eser, S.; Song, C. [and others

    1993-10-01

    The Penn State program in advanced thermally stable coal-based jet fuels has five broad objectives: (1) development of mechanisms of degradation and solids formation; (2) quantitative measurement of growth of sub-micrometer and micrometer-sized particles suspended in fuels during thermal stressing; (3) characterization of carbonaceous deposits by various instrumental and microscopic methods; (4) elucidation of the role of additives in retarding the formation of carbonaceous solids; and (5) assessment of the potential of production of high yields of cycloalkanes by direct liquefaction of coal. Some of our accomplishments and findings are: The product distribution and reaction mechanisms for pyrolysis of alkylcyclohexanes at 450{degree}C have been investigated in detail. In this report we present results of pyrolysis of cyclohexane and a variety of alkylcyclohexanes in nitrogen atmospheres, along with pseudo-first order rate constants, and possible reaction mechanisms for the origin of major pyrolysis products are presented. Addition of PX-21 activated carbon effectively stops the formation of carbonaceous solids on reactor walls during thermal stressing of JPTS. A review of physical and chemical interactions in supercritical fluids has been completed. Work has begun on thermal stability studies of a second generation of fuel additives, 1,2,3,4-tetrahydro-l-naphthol, 9,10-phenanthrenediol, phthalan, and 1,2-benzenedimethanol, and with careful selection of the feedstock, it is possible to achieve 85--95% conversion of coal to liquids, with 40--50% of the dichloromethane-soluble products being naphthalenes. (Further hydrogenation of the naphthalenes should produce the desired highly stable decalins.)

  16. Assessment of methane-related fuels for automotive fleet vehicles: technical, supply, and economic assessments

    Energy Technology Data Exchange (ETDEWEB)

    1982-02-01

    The use of methane-related fuels, derived from a variety of sources, in highway vehicles is assessed. Methane, as used here, includes natural gas (NG) as well as synthetic natural gas (SNG). Methanol is included because it can be produced from NG or the same resources as SNG, and because it is a liquid fuel at normal ambient conditions. Technological, operational, efficiency, petroleum displacement, supply, safety, and economic issues are analyzed. In principle, both NG and methanol allow more efficient engine operation than gasoline. In practice, engines are at present rarely optimized for NG and methanol. On the basis of energy expended from resource extraction to end use, only optimized LNG vehicles are more efficient than their gasoline counterparts. By 1985, up to 16% of total petroleum-based highway vehicle fuel could be displaced by large fleets with central NG fueling depots. Excluding diesel vehicles, which need technology advances to use NG, savings of 8% are projected. Methanol use by large fleets could displace up to 8% of petroleum-based highway vehicle fuel from spark-ignition vehicles and another 9% from diesel vehicles with technology advances. The US NG supply appears adequate to accommodate fleet use. Supply projections, future price differential versus gasoline, and user economics are uncertain. In many cases, attractive paybacks can occur. Compressed NG now costs on average about $0.65 less than gasoline, per energy-equivalent gallon. Methanol supply projections, future prices, and user economics are even more uncertain. Current and projected near-term methanol supplies are far from adequate to support fleet use. Methanol presently costs more than gasoline on an equal-energy basis, but is projected to cost less if produced from coal instead of NG or petroleum.

  17. Advanced fuel cell development. Progress Report, April-June 1980. [LiAlO/sub 2/

    Energy Technology Data Exchange (ETDEWEB)

    Pierce, R.D.; Arons, R.M.; Dusek, J.T.; Fraioli, A.V.; Kucera, G.H.; Poeppel, R.B.; Sim, J.W.; Smith, J.L.

    1980-11-01

    Advanced fuel cell research and development activities at Argonne National Laboratory (ANL) during the period April-June 1980 are described. These efforts have been directed toward understanding and improving components of molten carbonate fuel cells and have included operation of a 10-cm square cell. Studies have continued on the development of electrolyte structures (LiAlO/sub 2/ and Li/sub 2/CO/sub 3/-K/sub 2/CO/sub 3/). This effort is being concentrated on the preparation of sintered LiAl0/sub 2/ as electrolyte support. Tape casting is presently under investigation as a method for producing green bodies to be sintered; this technique may be an improvement over cold pressing, which was used in the past to produce green bodies. The transition temperature for the ..beta..- to ..gamma..-LiAlO/sub 2/ allotropic transformation is being determined using differential thermal analysis. Work is continuing on the development of preoxidized, prelithiated NiO cathodes. Two techniques, one of which is simpler than the other, have been developed to fabricate plates of Li/sub 0/ /sub 05/Ni/sub 0/ /sub 95/O. In addition, electroless nickel plating is being investigated as a means of providing corrosion protection to structural hardware. To improve its cell testing capability, ANL has constructed a device for improved resistance measurements by the current-interruption technique.

  18. Advances and recent trends in heterogeneous photo(electro)-catalysis for solar fuels and chemicals.

    Science.gov (United States)

    Highfield, James

    2015-04-15

    In the context of a future renewable energy system based on hydrogen storage as energy-dense liquid alcohols co-synthesized from recycled CO2, this article reviews advances in photocatalysis and photoelectrocatalysis that exploit solar (photonic) primary energy in relevant endergonic processes, viz., H2 generation by water splitting, bio-oxygenate photoreforming, and artificial photosynthesis (CO2 reduction). Attainment of the efficiency (>10%) mandated for viable techno-economics (USD 2.00-4.00 per kg H2) and implementation on a global scale hinges on the development of photo(electro)catalysts and co-catalysts composed of earth-abundant elements offering visible-light-driven charge separation and surface redox chemistry in high quantum yield, while retaining the chemical and photo-stability typical of titanium dioxide, a ubiquitous oxide semiconductor and performance "benchmark". The dye-sensitized TiO2 solar cell and multi-junction Si are key "voltage-biasing" components in hybrid photovoltaic/photoelectrochemical (PV/PEC) devices that currently lead the field in performance. Prospects and limitations of visible-absorbing particulates, e.g., nanotextured crystalline α-Fe2O3, g-C3N4, and TiO2 sensitized by C/N-based dopants, multilayer composites, and plasmonic metals, are also considered. An interesting trend in water splitting is towards hydrogen peroxide as a solar fuel and value-added green reagent. Fundamental and technical hurdles impeding the advance towards pre-commercial solar fuels demonstration units are considered.

  19. Advances and Recent Trends in Heterogeneous Photo(Electro-Catalysis for Solar Fuels and Chemicals

    Directory of Open Access Journals (Sweden)

    James Highfield

    2015-04-01

    Full Text Available In the context of a future renewable energy system based on hydrogen storage as energy-dense liquid alcohols co-synthesized from recycled CO2, this article reviews advances in photocatalysis and photoelectrocatalysis that exploit solar (photonic primary energy in relevant endergonic processes, viz., H2 generation by water splitting, bio-oxygenate photoreforming, and artificial photosynthesis (CO2 reduction. Attainment of the efficiency (>10% mandated for viable techno-economics (USD 2.00–4.00 per kg H2 and implementation on a global scale hinges on the development of photo(electrocatalysts and co-catalysts composed of earth-abundant elements offering visible-light-driven charge separation and surface redox chemistry in high quantum yield, while retaining the chemical and photo-stability typical of titanium dioxide, a ubiquitous oxide semiconductor and performance “benchmark”. The dye-sensitized TiO2 solar cell and multi-junction Si are key “voltage-biasing” components in hybrid photovoltaic/photoelectrochemical (PV/PEC devices that currently lead the field in performance. Prospects and limitations of visible-absorbing particulates, e.g., nanotextured crystalline α-Fe2O3, g-C3N4, and TiO2 sensitized by C/N-based dopants, multilayer composites, and plasmonic metals, are also considered. An interesting trend in water splitting is towards hydrogen peroxide as a solar fuel and value-added green reagent. Fundamental and technical hurdles impeding the advance towards pre-commercial solar fuels demonstration units are considered.

  20. ACSEPT a European project for a new step in the future demonstration of advanced fuel processing

    Energy Technology Data Exchange (ETDEWEB)

    Bourg, S.; Hill, C. [CEA, DRCP - Bat 181, CEA Marcoule, BP17171, 30207 Bagnols/Ceze (France); Caravaca, C.; Espartero, A. [CIEMAT, Avda. Complutense, 22 - 28040 Madrid (Spain); Rhodes, C.; Taylor, R.; Harrison, M. [National Nuclear Laboratory, Sellafield, Seascale, Cumbria, CA20 1PG (United Kingdom); EKBERG, C. [Chalmers tekniska hoegskola, Institutionen foer kemi- och bioteknik, Aemnesomraadets namn, 412 96 Goeteborg (Sweden); GEIST, A. [Forschungszentrum Karlsruhe, Institut fuer Nukleare Entsorgungstechnik, P.O.B. 3640, D-76021 Karlsruhe (Germany); Modolo, G. [Forschungszentrum Juelich - FZJ, D-52425 Juelich (Germany); Cassayre, L. [CNRS, Laboratoire de Genie Chimique, Toulouse (France); Malmbeck, R. [JRC-ITU, Karlsruhe (Germany); De Angelis, G. [ENEA, Casaccia, Rome (Italy); Bouvet, S. [Rio Tinto Alcan, Centre de Recherche de Voreppe, Voreppe (France); Klaassen, F. [NRG, PO Box 25, NL-1755 ZG Petten (Netherlands)

    2010-07-01

    For more than fifteen years, a European scientific community has joined its effort to develop and optimise processes for the partitioning of actinides from fission products. In an international context of 'nuclear renaissance', the upcoming of a new generation of nuclear reactor (Gen IV) will require the development of associated advanced closed fuel cycles which answer the needs of a sustainable nuclear energy: the minimization of the production of long lived radioactive waste but also the optimization of the use of natural resources with an increased resistance to proliferation. Actually, Partitioning and Transmutation (P and T), associated to a multi-recycling of all transuranics (TRUs), should play a key role in the development of this sustainable nuclear energy. By joining together 34 Partners coming from European universities, nuclear research bodies and major industrial players in a multidisciplinary consortium, the FP7 EURATOM-Fission Collaborative Project ACSEPT (Actinide recycling by Separation and Transmutation), started in 2008 for four year duration, provides the sound basis and fundamental improvements for future demonstrations of fuel treatment in strong connection with fuel fabrication techniques. Consistently with potentially viable recycling strategies, ACSEPT therefore provides a structured R and D framework to develop chemical separation processes compatible with fuel fabrication techniques, with a view to their future demonstration at the pilot level. ACSEPT is organized into three technical domains: (i) Considering technically mature aqueous separation processes, ACSEPT works to optimize and select the most promising ones dedicated either to actinide partitioning or to group actinide separation. (ii) Concerning high temperature pyrochemical separation processes, ACSEPT focuses on the enhancement of the two reference cores of process selected within previous projects. R and D efforts are now devoted to key scientific and technical

  1. Experimental research subject and renovation of chemical processing facility (CPF) for advanced fast reactor fuel reprocessing technology development

    Energy Technology Data Exchange (ETDEWEB)

    Koyama, Tomozo; Shinozaki, Tadahiro; Nomura, Kazunori; Koma, Yoshikazu; Miyachi, Shigehiko; Ichige, Yoshiaki; Kobayashi, Tsuguyuki; Nemoto, Shin-ichi [Japan Nuclear Cycle Development Inst., Tokai Works, Tokai, Ibaraki (Japan)

    2002-12-01

    In order to enhance economical efficiency, environmental impact and nuclear nonproliferation resistance, the Advanced Reprocessing Technology, such as simplification and optimization of process, and applicability evaluation of the innovative technology that was not adopted up to now, has been developed for the reprocessing of the irradiated fuel taken out from a fast reactor. Renovation of the hot cell interior equipments, establishment and updating of glove boxes, installation of various analytical equipments, etc. in the Chemical Processing Facility (CPF) was done to utilize the CPF more positivity which is the center of the experimental field, where actual fuel can be used, for research and development towards establishment of the Advanced Reprocessing Technology development. The hot trials using the irradiated fuel pins of the experimental fast reactor 'JOYO' for studies on improved aqueous reprocessing technology, MA separation technology, dry process technology, etc. are scheduled to be carried out with these new equipments. (author)

  2. Waste Classification based on Waste Form Heat Generation in Advanced Nuclear Fuel Cycles Using the Fuel-Cycle Integration and Tradeoffs (FIT) Model

    Energy Technology Data Exchange (ETDEWEB)

    Denia Djokic; Steven J. Piet; Layne F. Pincock; Nick R. Soelberg

    2013-02-01

    This study explores the impact of wastes generated from potential future fuel cycles and the issues presented by classifying these under current classification criteria, and discusses the possibility of a comprehensive and consistent characteristics-based classification framework based on new waste streams created from advanced fuel cycles. A static mass flow model, Fuel-Cycle Integration and Tradeoffs (FIT), was used to calculate the composition of waste streams resulting from different nuclear fuel cycle choices. This analysis focuses on the impact of waste form heat load on waste classification practices, although classifying by metrics of radiotoxicity, mass, and volume is also possible. The value of separation of heat-generating fission products and actinides in different fuel cycles is discussed. It was shown that the benefits of reducing the short-term fission-product heat load of waste destined for geologic disposal are neglected under the current source-based radioactive waste classification system , and that it is useful to classify waste streams based on how favorable the impact of interim storage is in increasing repository capacity.

  3. Vegetable oil-based diesel fuels: Overview and current trends

    Science.gov (United States)

    Since the energy crises of the 1970's and early 1980's, feedstocks and fuels with the potential to reduce dependence on petroleum-based energy and fuels have found increasing interest. Materials with triacylglycerols (triglycerides; esters of glycerol with fatty acids) as major components, such as ...

  4. Design and fabrication of an advanced TRISO fuel with ZrC coating

    Energy Technology Data Exchange (ETDEWEB)

    Porter, Ian E., E-mail: porteri@email.sc.edu [University of South Carolina, Mechanical Engineering Department, 300 Main Street, Columbia, SC 29208, United Sates (United States); Knight, Travis W., E-mail: knighttw@cec.sc.edu [University of South Carolina, Mechanical Engineering Department, 300 Main Street, Columbia, SC 29208, United Sates (United States); Dulude, Michael C., E-mail: dulude@email.sc.edu [University of South Carolina, Mechanical Engineering Department, 300 Main Street, Columbia, SC 29208, United Sates (United States); Roberts, Elwyn, E-mail: robertse@cec.sc.edu [University of South Carolina, Mechanical Engineering Department, 300 Main Street, Columbia, SC 29208, United Sates (United States); Hobbs, Jim, E-mail: JSHobbs@nuclearfuelservices.com [Nuclear Fuel Services, Inc., 1205 Banner Hill Road, Erwin, TN 37650 (United States)

    2013-06-15

    Highlights: • Zirconium carbide was deposited on surrogate zirconia and UO{sub 2} kernels. • Deposition rates were found to be dependent on temperature and gas concentration. • Calcining and sintering parameters were optimized to reduce cracking in UO{sub 2} kernel production. -- Abstract: Very high temperature reactors (VHTRs) are expected to achieve coolant outlet temperatures up to 1000 °C, allowing for increased plant efficiency as well as the ability to use the process heat for hydrogen production and various uses in the process chemical industry. The feasibility of using VHTRs as part of the next generation of nuclear reactors greatly depends on the reliability of tri-structural isotropic (TRISO) fuel particles to retain both gaseous and metallic fission products created in irradiated uranium dioxide (UO{sub 2}). This work sought the deposition parameters necessary to produce an additional zirconium carbide (ZrC) layer used in advanced coated particle fuels. The additional ZrC layer will act as an oxygen getter to prevent typical TRISO failure mechanisms including over pressurization of the particle and kernel migration of the kernel within the particle, also known as the amoeba effect. In this study, ZrC coatings were applied to surrogate zirconia kernels as well as UO{sub 2} kernels using a chemical vapor deposition (CVD) fluidized bed reactor, and the deposition characteristics were analyzed via scanning electron microscopy (SEM) techniques. The ZrC layer was confirmed through X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The calcining and sintering of urania kernels for use in these coating experiments is also discussed.

  5. Advanced Fuels Reactor using Aneutronic Rodless Ultra Low Aspect Ratio Tokamak Hydrogenic Plasmas

    Science.gov (United States)

    Ribeiro, Celso

    2015-11-01

    The use of advanced fuels for fusion reactor is conventionally envisaged for field reversed configuration (FRC) devices. It is proposed here a preliminary study about the use of these fuels but on an aneutronic Rodless Ultra Low Aspect Ratio (RULART) hydrogenic plasmas. The idea is to inject micro-size boron pellets vertically at the inboard side (HFS, where TF is very high and the tokamak electron temperature is relatively low because of profile), synchronised with a proton NBI pointed to this region. Therefore, p-B reactions should occur and alpha particles produced. These pellets will act as an edge-like disturbance only (cp. killer pellet, although the vertical HFS should make this less critical, since the unablated part should appear in the bottom of the device). The boron cloud will appear at midplance, possibly as a MARFE-look like. Scaling of the p-B reactions by varying the NBI energy should be compared with the predictions of nuclear physics. This could be an alternative to the FRC approach, without the difficulties of the optimization of the FRC low confinement time. Instead, a robust good tokamak confinement with high local HFS TF (enhanced due to the ultra low aspect ratio and low pitch angle) is used. The plasma central post makes the RULART concept attractive because of the proximity of NBI path and also because a fraction of born alphas will cross the plasma post and dragged into it in the direction of the central plasma post current, escaping vertically into a hole in the bias plate and reaching the direct electricity converter, such as in the FRC concept.

  6. Implications of Results from the Advanced Gas Reactor Fuel Development and Qualification Program on Licensing of Modular HTGRs

    Energy Technology Data Exchange (ETDEWEB)

    David Petti

    2001-10-01

    The high level of safety of modular high temperature gas-cooled reactor (HTGR) designs is achieved by passively maintaining core temperatures below fission product release thresholds under all envisioned accident scenarios. This level of fuel performance and fission product retention reduces the radioactive source term by many orders of magnitude relative to other reactor types but is predicated on exceptionally high coated-particle fuel fabrication quality and excellent fuel performance under normal operation and accident conditions. The Advanced Gas Reactor Fuel Development and Qualification (AGR) Program decided to qualify for uranium oxide/uranium carbide (UCO) TRISO coated-particle fuel in an operating envelope that would bound both pebble bed and prismatic modular HTGR options. By using a mixture of uranium oxide and uranium carbide, the kernel composition is engineered to minimize CO formation and fuel kernel migration, which is key to maintain to fuel integrity at the higher burnups, temperatures, and temperature gradients anticipated in prismatic HTGRs. Fuel fabrication conducted at both laboratory and engineering scale has demonstrated the ability to fabricate high quality UCO TRISO fuel with very low defects. The first irradiation (AGR 1) exposed about 300,000 TRISO fuel particles to a peak burnup of 19.6% FIMA, a peak fast-neutron fluence of about 4.3 × 1025 n/m2, and a maximum time-averaged fuel temperature of about 1,200°C without a single particle failure. The very low release of key metallic fission products (except silver) measured in post-irradiation examination (PIE) confirms the excellent performance measured under irradiation. Very low releases have been measured in accident simulation heatup testing (''safety testing'') after hundreds of hours at 1600 and 1700°C and no particle failures (no noble gas release measured) have been observed. Even after hundreds of hours at 1800°C, the releases are

  7. Development of an Advanced Fluid Mechanics Measurement Facility for Flame Studies of Neat Fuels, Jet Fuels, and their Surrogates

    Science.gov (United States)

    2009-08-26

    through the use of hot - wire anemometry . Implementing a DPIV system in flames and achieving the level of accuracy of LDV is a challenge, particularly...temperature at the hot boundary for a given strain rate and fuel concentration in the fuel jet. Law and coworkers (e.g., Law et al. 1986; Law 1988... wired into a single USB LaVision PTU timing box to share a single LaVision acquisition license through partitioning of the dongle with a USB switch

  8. Advanced fast reactor fuels program. Second annual progress report, July 1, 1975--September 30, 1976

    Energy Technology Data Exchange (ETDEWEB)

    Baker, R.D. (comp.)

    1978-12-01

    Results of steady-state (EBR-II) irradiation testing, off-normal irradiation design and testing, fuel-cladding compatibility, and chemical stability of uranium--plutonium carbide and nitride fuels are presented.

  9. Ethanol as a fuel for road transportation. Main report; Contribution to IEA Implementing Agreement on Advanced Motor Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Larsen, Ulrik; Johansen, T.; Schramm, J.

    2009-05-15

    Bioethanol as a motor fuel in the transportation sector, mainly for road transportation, has been subject to many studies and much discussion. Furthermore, the topic involves not only the application and engine technical aspects, but also the understanding of the entire life cycle of the fuel, well-to-wheels, including economical, environmental, and social aspects. It is not, however, the aim of this report to assess every single one of these aspects. The present report aims to address the technical potential and problems as well as the central issues related to the general application of bioethanol as an energy carrier in the near future. In discussions of the advantages and drawbacks of ethanol, the type of application is important. Generalization is not possible, because ethanol can be used in many forms. Furthermore, a wide range of ethanol/gasoline blends has not yet been investigated sufficiently. The most favorable type of application is determined by infrastructural factors, especially vehicle fleet configuration. From a technical point of view, optimal usage involves a high degree of water content in the ethanol, and this excludes low-percentage-ethanol fuels. The benefits seem strongly related to the amount of ethanol in a given blend, that is, the more the better. Both engine efficiencies and emissions improve with more ethanol in the fuel. Wet ethanol constitutes an even cleaner fuel in both the production and application phases. In summary, ethanol application has many possibilities, but with each type of application comes a set of challenges. Nevertheless, technical solutions for each challenge are available. (ln)

  10. Engineering development of advance physical fine coal cleaning for premium fuel applications

    Energy Technology Data Exchange (ETDEWEB)

    Jha, M.C.; Smit, F.J.; Shields, G.L. [AMAX R& D Center/ENTECH Global Inc., Golden, CO (United States)

    1995-11-01

    The objective of this project is to develop the engineering design base for prototype fine coal cleaning plants based on Advanced Column Flotation and Selective Agglomeration processes for premium fuel and near-term applications. Removal of toxic trace elements is also being investigated. The scope of the project includes laboratory research and bench-scale testing of each process on six coals followed by design, construction, and operation of a 2 tons/hour process development unit (PDU). Three coals will be cleaned in tonnage quantity and provided to DOE and its contractors for combustion evaluation. Amax R&D (now a subsidiary of Cyprus Amax Mineral Company) is the prime contractor. Entech Global is managing the project and performing most of the research and development work as an on-site subcontractor. Other participants in the project are Cyprus Amax Coal Company, Arcanum, Bechtel, TIC, University of Kentucky and Virginia Tech. Drs. Keller of Syracuse and Dooher of Adelphi University are consultants.

  11. Diamond and Hydrogenated Carbons for Advanced Batteries and Fuel Cells: Fundamental Studies and Applications.

    Energy Technology Data Exchange (ETDEWEB)

    Swain; Greg M.

    2009-04-13

    The original funding under this project number was awarded for a period 12/1999 until 12/2002 under the project title Diamond and Hydrogenated Carbons for Advanced Batteries and Fuel Cells: Fundamental Studies and Applications. The project was extended until 06/2003 at which time a renewal proposal was awarded for a period 06/2003 until 06/2008 under the project title Metal/Diamond Composite Thin-Film Electrodes: New Carbon Supported Catalytic Electrodes. The work under DE-FG02-01ER15120 was initiated about the time the PI moved his research group from the Department of Chemistry at Utah State University to the Department of Chemistry at Michigan State University. This DOE-funded research was focused on (i) understanding structure-function relationships at boron-doped diamond thin-film electrodes, (ii) understanding metal phase formation on diamond thin films and developing electrochemical approaches for producing highly dispersed electrocatalyst particles (e.g., Pt) of small nominal particle size, (iii) studying the electrochemical activity of the electrocatalytic electrodes for hydrogen oxidation and oxygen reduction and (iv) conducting the initial synthesis of high surface area diamond powders and evaluating their electrical and electrochemical properties when mixed with a Teflon binder.

  12. Advanced DC-DC converter for power conditioning in hydrogen fuel cell systems

    Energy Technology Data Exchange (ETDEWEB)

    Kovacevic, G.; Tenconi, A.; Bojoi, R. [Department of Electrical Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino (Italy)

    2008-06-15

    The fuel cell (FC) generators can produce electric energy directly from hydrogen and oxygen. The DC voltage generated by FC is generally low amplitude and it is not constant, depending on the operating conditions. Furthermore, FC systems have dynamic response that is slower than the transient responses typically requested by the load. For this reason, in many applications the FC generators must be interfaced with other energy/power sources by means of an electronic power converter. An advanced full-bridge (FB) DC-DC converter, which effectively achieves zero-voltage switching and zero-current switching (ZVS-ZCS), is proposed for power-conditioning (PC) in hydrogen FC applications. The operation and features of the converter are analyzed and verified by simulations results. The ZVS-ZCS operation is obtained by means of a simple auxiliary circuit. Introduction of the soft-switching operation in PC unit brings improvements not only from the converter efficiency point of view, but also in terms of increased converter power density. Quantitative analysis of hard and soft-switching operating of the proposed converter is also made, bringing in evidence the benefits of soft-switching operation mode. The proposed converter can be a suitable solution for PC in hydrogen FC systems, especially for the medium to high-power applications. (author)

  13. Advanced and flexible genetic algorithms for BWR fuel loading pattern optimization

    Energy Technology Data Exchange (ETDEWEB)

    Martin-del-Campo, Cecilia [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532, Jiutepec, Mor., 62550 (Mexico)], E-mail: cmcm@fi-b.unam.mx; Palomera-Perez, Miguel-Angel [Instituto de Investigaciones en Matematicas Aplicadas y Sistemas, Universidad Nacional Autonoma de Mexico, Circuito Escolar, Ciudad Universitaria, 04510 DF (Mexico)], E-mail: mapp@uxmcc2.iimas.unam.mx; Francois, Juan-Luis [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532, Jiutepec, Mor., 62550 (Mexico)], E-mail: jlfl@fi-b.unam.mx

    2009-10-15

    This work proposes advances in the implementation of a flexible genetic algorithm (GA) for fuel loading pattern optimization for Boiling Water Reactors (BWRs). In order to avoid specific implementations of genetic operators and to obtain a more flexible treatment, a binary representation of the solution was implemented; this representation had to take into account that a little change in the genotype must correspond to a little change in the phenotype. An identifier number is assigned to each assembly by means of a Gray Code of 7 bits and the solution (the loading pattern) is represented by a binary chain of 777 bits of length. Another important contribution is the use of a Fitness Function which includes a Heuristic Function and an Objective Function. The Heuristic Function which is defined to give flexibility on the application of a set of positioning rules based on knowledge, and the Objective Function that contains all the parameters which qualify the neutronic and thermal hydraulic performances of each loading pattern. Experimental results illustrating the effectiveness and flexibility of this optimization algorithm are presented and discussed.

  14. Recent advances on the production and utilization trends of bio-fuels: A global perspective

    Energy Technology Data Exchange (ETDEWEB)

    Demirbas, M.F. [P. K. 216, 61035 Trabzon (Turkey); Balat, Mustafa [Polatoglu ap Kat 6, Besikduzu, Trabzon (Turkey)

    2006-09-15

    Bio-fuels are important because they replace petroleum fuels. There are many benefits for the environment, economy and consumers in using bio-fuels. Bio-oil can be used as a substitute for fossil fuels to generate heat, power and/or chemicals. Upgrading of bio-oil to a transportation fuel is technically feasible, but needs further development. Bio-fuels are made from biomass through thermochemical processes such as pyrolysis, gasification, liquefaction and supercritical fluid extraction or biochemical. Biochemical conversion of biomass is completed through alcoholic fermentation to produce liquid fuels and anaerobic digestion or fermentation, resulting in biogas. In wood derived pyrolysis oil, specific oxygenated compounds are present in relatively large amounts. Basically, the recovery of pure compounds from the complex bio-oil is technically feasible but probably economically unattractive because of the high costs for recovery of the chemical and its low concentration in the oil. (author)

  15. Replacement of petroleum based hydraulic fluids with a soybean-based alternative

    Energy Technology Data Exchange (ETDEWEB)

    Rose, B.; Rivera, P.

    1998-05-01

    Despite the best preventative measures, ruptured hoses, spills and leaks occur with use of all hydraulic equipment. Although these releases do not usually produce a RCRA regulated waste, they are often a reportable occurrence. Clean-up and subsequent administrative procedure involves additional costs, labor and work delays. Concerns over these releases, especially related to Sandia National Laboratories (SNL) vehicles hauling waste on public roads prompted Fleet Services (FS) to seek an alternative to the standard petroleum based hydraulic fluid. Since 1996 SNL has participated in a pilot program with the University of Iowa (UNI) and selected vehicle manufacturers, notably John Deere, to field test hydraulic fluid produced from soybean oil in twenty of its vehicles. The vehicles included loaders, graders, sweepers, forklifts and garbage trucks. Research was conducted for several years at UNI to modify and market soybean oils for industrial uses. Soybean oil ranks first in worldwide production of vegetable oils (29%), and represents a tremendous renewable resource. Initial tests with soybean oil showed excellent lubrication and wear protection properties. Lack of oxidative stability and polymerization of the oil were concerns. These concerns were being addressed through genetic alteration, chemical modification and use of various additives, and the improved lubricant is in the field testing stage.

  16. Microbial enzymes for the recycling of recalcitrant petroleum-based plastics: how far are we?

    Science.gov (United States)

    Wei, Ren; Zimmermann, Wolfgang

    2017-03-28

    Petroleum-based plastics have replaced many natural materials in their former applications. With their excellent properties, they have found widespread uses in almost every area of human life. However, the high recalcitrance of many synthetic plastics results in their long persistence in the environment, and the growing amount of plastic waste ending up in landfills and in the oceans has become a global concern. In recent years, a number of microbial enzymes capable of modifying or degrading recalcitrant synthetic polymers have been identified. They are emerging as candidates for the development of biocatalytic plastic recycling processes, by which valuable raw materials can be recovered in an environmentally sustainable way. This review is focused on microbial biocatalysts involved in the degradation of the synthetic plastics polyethylene, polystyrene, polyurethane and polyethylene terephthalate (PET). Recent progress in the application of polyester hydrolases for the recovery of PET building blocks and challenges for the application of these enzymes in alternative plastic waste recycling processes will be discussed.

  17. Recent advances in microbial production of fuels and chemicals using tools and strategies of systems metabolic engineering.

    Science.gov (United States)

    Cho, Changhee; Choi, So Young; Luo, Zi Wei; Lee, Sang Yup

    2015-11-15

    The advent of various systems metabolic engineering tools and strategies has enabled more sophisticated engineering of microorganisms for the production of industrially useful fuels and chemicals. Advances in systems metabolic engineering have been made in overproducing natural chemicals and producing novel non-natural chemicals. In this paper, we review the tools and strategies of systems metabolic engineering employed for the development of microorganisms for the production of various industrially useful chemicals belonging to fuels, building block chemicals, and specialty chemicals, in particular focusing on those reported in the last three years. It was aimed at providing the current landscape of systems metabolic engineering and suggesting directions to address future challenges towards successfully establishing processes for the bio-based production of fuels and chemicals from renewable resources.

  18. Hydrogen as a fuel for today and tomorrow: expectations for advanced hydrogen storage materials/systems research.

    Science.gov (United States)

    Hirose, Katsuhiko

    2011-01-01

    History shows that the evolution of vehicles is promoted by several environmental restraints very similar to the evolution of life. The latest environmental strain is sustainability. Transport vehicles are now facing again the need to advance to use sustainable fuels such as hydrogen. Hydrogen fuel cell vehicles are being prepared for commercialization in 2015. Despite intensive research by the world's scientists and engineers and recent advances in our understanding of hydrogen behavior in materials, the only engineering phase technology which will be available for 2015 is high pressure storage. Thus industry has decided to implement the high pressure tank storage system. However the necessity of smart hydrogen storage is not decreasing but rather increasing because high market penetration of hydrogen fuel cell vehicles is expected from around 2025 onward. In order to bring more vehicles onto the market, cheaper and more compact hydrogen storage is inevitable. The year 2025 seems a long way away but considering the field tests and large scale preparation required, there is little time available for research. Finding smart materials within the next 5 years is very important to the success of fuel cells towards a low carbon sustainable world.

  19. Design and Status of the NGNP Fuel Experiment AGR-3/4 Irradiated in the Advanced Test Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Blaine Grover

    2012-10-01

    The United States Department of Energy’s Next Generation Nuclear Plant (NGNP) Advanced Gas Reactor (AGR) Fuel Development and Qualification Program will be irradiating up to seven separate low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States, and will be irradiated over the next several years to demonstrate and qualify new TRISO coated particle fuel for use in high temperature gas reactors. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which will each consist of at least six separate capsules, will be irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gas will also have on-line fission product monitoring on its effluent to track performance of the fuel in each individual capsule during irradiation. The first experiment (designated AGR-1) started irradiation in December 2006 and was completed in November 2009. The second experiment (AGR-2) started irradiation in June 2010 and is currently scheduled to be completed in April 2013. The third and fourth experiments have been combined into a single experiment designated AGR-3/4, which started its irradiation in December 2011 and is currently scheduled to be completed in November 2013. Since the purpose of this experiment is to provide data on fission product migration and retention in the NGNP reactor, the design of this experiment is

  20. DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion Engines

    Energy Technology Data Exchange (ETDEWEB)

    Bunting, Bruce G [ORNL; Bunce, Michael [ORNL

    2012-01-01

    Research in 2011 was focused on diesel range fuels and diesel combustion and fuels evaluated in 2011 included a series of oxygenated biofuels fuels from University of Maine, oxygenated fuel compounds representing materials which could be made from sewage, oxygenated marine diesel fuels for low emissions, and a new series of FACE fuel surrogates and FACE fuels with detailed exhaust chemistry and particulate size measurements. Fuels obtained in late 2011, which will be evaluated in 2012, include a series of oil shale derived fuels from PNNL, green diesel fuel (hydrotreated vegetable oil) from UOP, University of Maine cellulosic biofuel (levulene), and pyrolysis derived fuels from UOP pyrolysis oil, upgraded at University of Georgia. We were able to demonstrate, through a project with University of Wisconsin, that a hybrid strategy for fuel surrogates provided both accurate and rapid CFD combustion modeling for diesel HCCI. In this strategy, high molecular weight compounds are used to more accurately represent physical processes and smaller molecular weight compounds are used for chemistry to speed chemical calculations. We conducted a small collaboration with sp3H, a French company developing an on-board fuel quality sensor based on near infrared analysis to determine how to use fuel property and chemistry information for engine control. We were able to show that selected outputs from the sensor correlated to both fuel properties and to engine performance. This collaboration leveraged our past statistical analysis work and further work will be done as opportunity permits. We conducted blending experiments to determine characteristics of ethanol blends based on the gasoline characteristics used for blending. Results indicate that much of the octane benefits gained by high level ethanol blending can be negated by use of low octane gasoline blend stocks, as allowed by ASTM D5798. This may limit ability to optimize engines for improved efficiency with ethanol fuels

  1. Rapid Response Research and Development (R&D) for the Aerospace Systems Directorate. Delivery Order 0021: Engineering Research and Technical Analyses of Advanced Airbreathing Propulsion Fuels, Subtask: Fit-for-Purpose (FFP) and Dynamic Seal Testing of Alternative Aviation Fuels

    Science.gov (United States)

    2014-08-01

    equal part by weight mixture of the following individual FAME components: • Palm Oil Methyl Ester (POME) • Rapeseed Methyl Ester (RME) • Soy(bean...Research and Technical Analyses of Advanced Airbreathing Propulsion Fuels Subtask: Fit-For-Purpose (FFP) and Dynamic Seal Testing of Alternative ...Technical Analyses of Advanced Airbreathing Propulsion Fuels Subtask: Fit-For-Purpose (FFP) and Dynamic Seal Testing of Alternative Aviation

  2. Development of CANDU advanced fuel fabrication technology - A development of amorphous alloys for the solder of nuclear reactor materials

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jai Young; Lee, Ki Young; Kim, Yoon Kee; Jung, Jae Han; Yu, Ji Sang; Kim, Hae Yeol; Han, Young Su [Korea Advanced Institute of Science and Technology, Taejon (Korea, Republic of)

    1996-07-01

    In the case of advanced CANDU fuel being useful in future, the fabrication processes for soundness insurance of a improved nuclear fuel bundle must be developed at the same time because it have three times combustibility as existing fuel. In particular, as the improved nuclear fuel bundle in which a coated layer thickness is thinner than existing that, firmity of a joint part is very important. Therefore, we need to develop a joint technique using new solder which can settle a potential problem in current joining method. As the Zr-Be alloy system and the Ti-Be system are composed with the elements having high neutron permeability, they are suitable for joint of nuclear fuel pack. The various compositions Zr-Be and Ti-Be binary metallic glass alloys were applicable to the joining the nuclear fuel bundles. The thickness of joint layer using the Zr{sub 1-x} Be{sub x} amorphous ribbon as a solder is thinner than that using physical vapor deposited Be. Among the Zr{sub 1-x} Be{sub x} amorphous binary alloys, Zr{sub 0.7} Be{sub 0.3} binary alloy is the most appropriated for joint of nuclear fuel bundle because its joint layer is smooth and thin due to low degree of Be diffusion. The microstructures of brazed layer using Ti{sub 1-y} Be{sub y} alloy, however, a solid-solution layer composed with Zr and Ti is formed toward the Zr cladding sheath and many of Zr is detected in the joint lever. 20 refs., 8 tabs., 23 figs. (author)

  3. The Economic, repository and proliferation implications of advanced nuclear fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Deinert, Mark; Cady, K B

    2011-09-04

    The goal of this project was to compare the effects of recycling actinides using fast burner reactors, with recycle that would be done using inert matrix fuel burned in conventional light water reactors. In the fast reactor option, actinides from both spent light water and fast reactor fuel would be recycled. In the inert matrix fuel option, actinides from spent light water fuel would be recycled, but the spent inert matrix fuel would not be reprocessed. The comparison was done over a limited 100-year time horizon. The economic, repository and proliferation implications of these options all hinge on the composition of isotopic byproducts of power production. We took the perspective that back-end economics would be affected by the cost of spent fuel reprocessing (whether conventional uranium dioxide fuel, or fast reactor fuel), fuel manufacture, and ultimate disposal of high level waste in a Yucca Mountain like geological repository. Central to understanding these costs was determining the overall amount of reprocessing needed to implement a fast burner, or inert matrix fuel, recycle program. The total quantity of high level waste requiring geological disposal (along with its thermal output), and the cost of reprocessing were also analyzed. A major advantage of the inert matrix fuel option is that it could in principle be implemented using the existing fleet of commercial power reactors. A central finding of this project was that recycling actinides using an inert matrix fuel could achieve reductions in overall actinide production that are nearly very close to those that could be achieved by recycling the actinides using a fast burner reactor.

  4. Advanced thermally stable jet fuels: Technical progress report, October 1994--December 1994

    Energy Technology Data Exchange (ETDEWEB)

    Schobert, H.H.; Eser, S.; Song, C.; Hatcher, P.G.; Boehman, A.; Coleman, M.M.

    1995-02-01

    There are five tasks within this project on thermally stable coal-based jet fuels. Progress on each of the tasks is described. Task 1, Investigation of the quantitative degradation chemistry of fuels, has 5 subtasks which are described: Literature review on thermal stability of jet fuels; Pyrolytic and catalytic reactions of potential endothermic fuels: cis- and trans-decalin; Use of site specific {sup 13}C-labeling to examine the thermal stressing of 1-phenylhexane: A case study for the determination of reaction kinetics in complex fuel mixtures versus model compound studies; Estimation of critical temperatures of jet fuels; and Surface effects on deposit formation in a flow reactor system. Under Task 2, Investigation of incipient deposition, the subtask reported is Uncertainty analysis on growth and deposition of particles during heating of coal-derived aviation gas turbine fuels; under Task 3, Characterization of solid gums, sediments, and carbonaceous deposits, is subtask, Studies of surface chemistry of PX-21 activated carbon during thermal degradation of jet A-1 fuel and n-dodecane; under Task 4, Coal-based fuel stabilization studies, is subtask, Exploratory screening and development potential of jet fuel thermal stabilizers over 400 C; and under Task 5, Exploratory studies on the direct conversion of coal to high quality jet fuels, are 4 subtasks: Novel approaches to low-severity coal liquefaction and coal/resid co-processing using water and dispersed catalysts; Shape-selective naphthalene hydrogenation for production of thermally stable jet fuels; Design of a batch mode and a continuous mode three-phase reactor system for the liquefaction of coal and upgrading of coal liquids; and Exploratory studies on coal liquids upgrading using mesopores molecular sieve catalysts. 136 refs., 69 figs., 24 tabs.

  5. Recent advances on Zeolite modification for direct alcohol fuel cells (DAFCs)

    Science.gov (United States)

    Makertihartha, I. G. B. N.; Zunita, M.; Rizki, Z.; Dharmawijaya, P. T.

    2017-03-01

    The increase of energy demand and global warming issues has driven studies of alternative energy sources. The polymer electrolyte membrane fuel cell (PEMFC) can be an alternative energy source by (partially) replacing the use of fossil fuel which is in line with the green technology concept. However, the usage of hydrogen as a fuel has several disadvantages mainly transportation and storage related to its safety aspects. Recently, alcohol has gained attention as an energy source for fuel cell application, namely direct alcohol fuel cell (DAFC). Among alcohols, high-mass energy density methanol and ethanol are widely used as direct methanol fuel cell (DMFC) and direct ethanol fuel cell (DEFC), respectively. Currently, the performance of DMFC is still rudimentary. Furthermore, the use of ethanol gives some additional privileges such as non-toxic property, renewable, ease of production in great quantity by the fermentation of sugar-containing raw materials. Direct alcohol fuel cell (DAFC) still has weakness in the low proton conductivity and high alcohol crossover. Therefore, to increase the performance of DAFC, modification using zeolite has been performed to improve proton conductivity and decrease alcohol crossover. Zeolite also has high thermal resistance properties, thereby increasing DAFC performance. This paper will discuss briefly about modification of catalyst and membrane for DAFC using zeolite. Zeolite modification effect on fuel cell performance especially proton conductivity and alcohol crossover will be presented in detail.

  6. Development of Advanced Low Emission Injectors and High-Bandwidth Fuel Flow Modulation Valves

    Science.gov (United States)

    Mansour, Adel

    2015-01-01

    Parker Hannifin Corporation developed the 3-Zone fuel nozzle for NASA's Environmentally Responsible Aviation Program to meet NASAs target of 75 LTO NOx reduction from CAEP6 regulation. The nozzle concept was envisioned as a drop-in replacement for currently used fuel nozzle stem, and is built up from laminates to provide energetic mixing suitable for lean direct injection mode at high combustor pressure. A high frequency fuel valve was also developed to provide fuel modulation for the pilot injector. Final testing result shows the LTO NOx level falling just shy of NASAs goal at 31.

  7. Advanced thermally stable jet fuels: Technical progress report, July 1994--September 1994

    Energy Technology Data Exchange (ETDEWEB)

    Schobert, H.H.; Eser, S.; Song, C.; Hatcher, P.G.; Boehman, A.; Coleman, M.M.

    1994-07-01

    There are five tasks within this project on thermally stable coal-based jet fuels. Progress on each of the tasks is described. Task 1, Investigation of the quantitative degradation chemistry of fuels, has 3 subtasks which are described: Pyrolysis of n-alkylbenzenes; Thermal decomposition of n-tetradecane in near-critical region; and Re-examining the effects of reactant and inert gas pressure on tetradecane pyrolysis--Effect of cold volume in batch reactor. Under Task 2, Investigation of incipient deposition, the subtask reported is Uncertainty analysis on growth and deposition of particles during heating of coal-derived aviation gas turbine fuels; under Task 3, Investigation of the quantitative degradation chemistry of fuels, is subtask, Effects of high surface area activated carbon and decalin on thermal degradation of jet A-1 fuel and n-dodecane; under Task 4, Coal-based fuel stabilization studies, is subtask, Screening potential jet fuel stabilizers using the model compound dodecane; and under Task 5, Exploratory studies on the direct conversion of coal to high quality jet fuels, is subtask, Shape-selective naphthalene hydrogenation for production of thermally stable jet fuels. 25 refs., 64 figs., 22 tabs.

  8. Environmental analysis of plastic production processes: comparing petroleum-based polypropylene and polyethylene with biologically-based poly-beta-hydroxybutyric acid using life cycle analysis.

    Science.gov (United States)

    Harding, K G; Dennis, J S; von Blottnitz, H; Harrison, S T L

    2007-05-31

    Polymers based on olefins have wide commercial applicability. However, they are made from non-renewable resources and are characterised by difficulty in disposal where recycle and re-use is not feasible. Poly-beta-hydroxybutyric acid (PHB) provides one example of a polymer made from renewable resources. Before motivating its widespread use, the advantages of a renewable polymer must be weighed against the environmental aspects of its production. Previous studies relating the environmental impacts of petroleum-based and bio-plastics have centred on the impact categories of global warming and fossil fuel depletion. Cradle-to-grave studies report equivalent or reduced global warming impacts, in comparison to equivalent polyolefin processes. This stems from a perceived CO(2) neutral status of the renewable resource. Indeed, no previous work has reported the results of a life cycle assessment (LCA) giving the environmental impacts in all major categories. This study investigates a cradle-to-gate LCA of PHB production taking into account net CO(2) generation and all major impact categories. It compares the findings with similar studies of polypropylene (PP) and polyethylene (PE). It is found that, in all of the life cycle categories, PHB is superior to PP. Energy requirements are slightly lower than previously observed and significantly lower than those for polyolefin production. PE impacts are lower than PHB values in acidification and eutrophication.

  9. A feasibility and optimization study to determine cooling time and burnup of advanced test reactor fuels using a nondestructive technique

    Energy Technology Data Exchange (ETDEWEB)

    Navarro, Jorge [Univ. of Utah, Salt Lake City, UT (United States)

    2013-12-01

    The goal of this study presented is to determine the best available non-destructive technique necessary to collect validation data as well as to determine burn-up and cooling time of the fuel elements onsite at the Advanced Test Reactor (ATR) canal. This study makes a recommendation of the viability of implementing a permanent fuel scanning system at the ATR canal and leads3 to the full design of a permanent fuel scan system. The study consisted at first in determining if it was possible and which equipment was necessary to collect useful spectra from ATR fuel elements at the canal adjacent to the reactor. Once it was establish that useful spectra can be obtained at the ATR canal the next step was to determine which detector and which configuration was better suited to predict burnup and cooling time of fuel elements non-destructively. Three different detectors of High Purity Germanium (HPGe), Lanthanum Bromide (LaBr3), and High Pressure Xenon (HPXe) in two system configurations of above and below the water pool were used during the study. The data collected and analyzed was used to create burnup and cooling time calibration prediction curves for ATR fuel. The next stage of the study was to determine which of the three detectors tested was better suited for the permanent system. From spectra taken and the calibration curves obtained, it was determined that although the HPGe detector yielded better results, a detector that could better withstand the harsh environment of the ATR canal was needed. The in-situ nature of the measurements required a rugged fuel scanning system, low in maintenance and easy to control system. Based on the ATR canal feasibility measurements and calibration results it was determined that the LaBr3 detector was the best alternative for canal in-situ measurements; however in order to enhance the quality of the spectra collected using this scintillator a deconvolution method was developed. Following the development of the deconvolution method

  10. Evaluation of the Use of Synroc to Solidify the Cesium and Strontium Separations Product from Advanced Aqueous Reprocessing of Spent Nuclear Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Julia Tripp; Vince Maio

    2006-03-01

    This report is a literature evaluation on the Synroc process for determining the potential for application to solidification of the Cs/Sr strip product from advanced aqueous fuel separations activities.

  11. Evaluation and Testing of the Suitability of a Coal-Based Jet Fuel

    Science.gov (United States)

    2008-06-01

    oxidative thermal stability was attributed to the lack of heteroatomic species, which contribute to deposition in petroleum -derived fuels...exists, petroleum -based fuels have more desirable low temperature properties, while at extremely low temperatures (<-50C) where solidification...production than the petroleum -derived fuel, but more than the coal-based fuel. In both the engine tests and the research combustor, the synthetic fuel

  12. The role of advanced calculation and simulation tools in the evolution of fuel; El papel de las herramientas avanzadas de calculo y simulacion en la evolucion del combustible

    Energy Technology Data Exchange (ETDEWEB)

    Munoz-Reja, C.; Cerracin, A.; Corpa, R.

    2015-07-01

    This article is focused on the role of the advanced calculation/simulation tools on the development of the fuel designs as well as in the assessment of the effect of the changes in the operation. With this purpose, the article describes and shows some examples of the use by ENUSA of some of these tools in the fuel engineering. To conclude, the future on the evolution of the advanced tools is also presented. (Author)

  13. Science based integrated approach to advanced nuclear fuel development - integrated multi-scale multi-physics hierarchical modeling and simulation framework Part III: cladding

    Energy Technology Data Exchange (ETDEWEB)

    Tome, Carlos N [Los Alamos National Laboratory; Caro, J A [Los Alamos National Laboratory; Lebensohn, R A [Los Alamos National Laboratory; Unal, Cetin [Los Alamos National Laboratory; Arsenlis, A [LLNL; Marian, J [LLNL; Pasamehmetoglu, K [INL

    2010-01-01

    Advancing the performance of Light Water Reactors, Advanced Nuclear Fuel Cycles, and Advanced Reactors, such as the Next Generation Nuclear Power Plants, requires enhancing our fundamental understanding of fuel and materials behavior under irradiation. The capability to accurately model the nuclear fuel systems to develop predictive tools is critical. Not only are fabrication and performance models needed to understand specific aspects of the nuclear fuel, fully coupled fuel simulation codes are required to achieve licensing of specific nuclear fuel designs for operation. The backbone of these codes, models, and simulations is a fundamental understanding and predictive capability for simulating the phase and microstructural behavior of the nuclear fuel system materials and matrices. In this paper we review the current status of the advanced modeling and simulation of nuclear reactor cladding, with emphasis on what is available and what is to be developed in each scale of the project, how we propose to pass information from one scale to the next, and what experimental information is required for benchmarking and advancing the modeling at each scale level.

  14. Advanced fuels modeling: Evaluating the steady-state performance of carbide fuel in helium-cooled reactors using FRAPCON 3.4

    Science.gov (United States)

    Hallman, Luther, Jr.

    Uranium carbide (UC) has long been considered a potential alternative to uranium dioxide (UO2) fuel, especially in the context of Gen IV gas-cooled reactors. It has shown promise because of its high uranium density, good irradiation stability, and especially high thermal conductivity. Despite its many benefits, UC is known to swell at a rate twice that of UO2. However, the swelling phenomenon is not well understood, and we are limited to a weak empirical understanding of the swelling mechanism. One suggested cladding for UC is silicon carbide (SiC), a ceramic that demonstrates a number of desirable properties. Among them are an increased corrosion resistance, high mechanical strength, and irradiation stability. However, with increased temperatures, SiC exhibits an extremely brittle nature. The brittle behavior of SiC is not fully understood and thus it is unknown how SiC would respond to the added stress of a swelling UC fuel. To better understand the interaction between these advanced materials, each has been implemented into FRAPCON, the preferred fuel performance code of the Nuclear Regulatory Commission (NRC); additionally, the material properties for a helium coolant have been incorporated. The implementation of UC within FRAPCON required the development of material models that described not only the thermophysical properties of UC, such as thermal conductivity and thermal expansion, but also models for the swelling, densification, and fission gas release associated with the fuel's irradiation behavior. This research is intended to supplement ongoing analysis of the performance and behavior of uranium carbide and silicon carbide in a helium-cooled reactor.

  15. H2FIRST: A partnership to advance hydrogen fueling station technology driving an optimal consumer experience.

    Energy Technology Data Exchange (ETDEWEB)

    Moen, Christopher D.; Dedrick, Daniel E.; Pratt, Joseph William; Balfour, Bruce; Noma, Edwin Yoichi; Somerday, Brian P.; San Marchi, Christopher W.; K. Wipke; J. Kurtz; D. Terlip; K. Harrison; S. Sprik

    2014-03-01

    The US Department of Energy (DOE) Energy Efficiency and Renewable Energy (EERE) Office of Fuel Cell Technologies Office (FCTO) is establishing the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) partnership, led by the National Renewable Energy Laboratory (NREL) and Sandia National Laboratories (SNL). FCTO is establishing this partnership and the associated capabilities in support of H2USA, the public/private partnership launched in 2013. The H2FIRST partnership provides the research and technology acceleration support to enable the widespread deployment of hydrogen infrastructure for the robust fueling of light-duty fuel cell electric vehicles (FCEV). H2FIRST will focus on improving private-sector economics, safety, availability and reliability, and consumer confidence for hydrogen fueling. This whitepaper outlines the goals, scope, activities associated with the H2FIRST partnership.

  16. Recent advances in the detection and quantification of microbial contamination in fuel systems

    Energy Technology Data Exchange (ETDEWEB)

    Passman, Frederick J. [Biodeterioration Control Associates, Inc., Princeton, NJ (United States); Maradukhel, Gulerana; Merks, Michael [LuminUltra Technologies Ltd., Fredericton, NB (Canada)

    2013-06-01

    Quantification of adenosine triphosphate (ATP) in fuels and fuel-associated waters was first presented at the 6th International Fuels Colloquium in 2007. At the time, two issues limited the overall usefulness of A TP as a test parameter: inability to detect dormant microbes and inability to differentiate between bacteria and fungi. Recent research has addressed both of these issues. This paper presents protocols for detecting dormant microbes - identified as microbes that are not metabolically active in the sampled fluid, but which can become active under appropriate conditions - and for differentiating fungi from bacteria. The newly developed protocols achieve > 90% detection of bacterial endospores in fuels and fuel-associated water. They also provide > 90% differentiation between bacterial and fungal contaminants in these fluids. (orig.)

  17. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly report, April 1--June 30, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-12-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). Accomplishments during the quarter are described on the following tasks and subtasks: Development of near-term applications (engineering development and dewatering studies); Engineering development of selective agglomeration (bench-scale testing and process scale-up); PDU and advanced column flotation module (coal selection and procurement and advanced flotation topical report); Selective agglomeration module (module operation and clean coal production with Hiawatha, Taggart, and Indiana 7 coals); Disposition of the PDU; and Project final report. Plans for next quarter are discussed and agglomeration results of the three tested coals are presented.

  18. A physical description of fission product behavior fuels for advanced power reactors.

    Energy Technology Data Exchange (ETDEWEB)

    Kaganas, G.; Rest, J.; Nuclear Engineering Division; Florida International Univ.

    2007-10-18

    The Global Nuclear Energy Partnership (GNEP) is considering a list of reactors and nuclear fuels as part of its chartered initiative. Because many of the candidate materials have not been explored experimentally under the conditions of interest, and in order to economize on program costs, analytical support in the form of combined first principle and mechanistic modeling is highly desirable. The present work is a compilation of mechanistic models developed in order to describe the fission product behavior of irradiated nuclear fuel. The mechanistic nature of the model development allows for the possibility of describing a range of nuclear fuels under varying operating conditions. Key sources include the FASTGRASS code with an application to UO{sub 2} power reactor fuel and the Dispersion Analysis Research Tool (DART ) with an application to uranium-silicide and uranium-molybdenum research reactor fuel. Described behavior mechanisms are divided into subdivisions treating fundamental materials processes under normal operation as well as the effect of transient heating conditions on these processes. Model topics discussed include intra- and intergranular gas-atom and bubble diffusion, bubble nucleation and growth, gas-atom re-solution, fuel swelling and ?scion gas release. In addition, the effect of an evolving microstructure on these processes (e.g., irradiation-induced recrystallization) is considered. The uranium-alloy fuel, U-xPu-Zr, is investigated and behavior mechanisms are proposed for swelling in the {alpha}-, intermediate- and {gamma}-uranium zones of this fuel. The work reviews the FASTGRASS kinetic/mechanistic description of volatile ?scion products and, separately, the basis for the DART calculation of bubble behavior in amorphous fuels. Development areas and applications for physical nuclear fuel models are identified.

  19. Fuel from Tobacco and Arundo Donax: Synthetic Crop for Direct Drop-in Biofuel Production through Re-routing the Photorespiration Intermediates and Engineering Terpenoid Pathways

    Energy Technology Data Exchange (ETDEWEB)

    None

    2012-02-15

    PETRO Project: Biofuels offer renewable alternatives to petroleum-based fuels that reduce net greenhouse gas emissions to nearly zero. However, traditional biofuels production is limited not only by the small amount of solar energy that plants convert through photosynthesis into biological materials, but also by inefficient processes for converting these biological materials into fuels. Farm-ready, non-food crops are needed that produce fuels or fuel-like precursors at significantly lower costs with significantly higher productivity. To make biofuels cost-competitive with petroleum-based fuels, biofuels production costs must be cut in half.

  20. Plan for fully decontaminating and decommissioning of the Westinghouse Advanced Reactors Division Fuel Laboratories at Cheswick, Revision 3

    Energy Technology Data Exchange (ETDEWEB)

    1982-01-01

    The project scope of work included the complete decontamination and decommissioning (D and D) of the Westinghouse ARD Fuel Laboratories at the Cheswick Site in the shortest possible time. This has been accomplished in the following four phases: (1) preparation of documents and necessary paperwork; packaging and shipping of all special nuclear materials in an acceptable form to a reprocessing agency; (2) decontamination of all facilities, glove boxes and equipment; loading of generated waste into bins, barrels and strong wooden boxes; (3) shipping of all bins, barrels and boxes containing waste to the designated burial site; removal of all utility services from the laboratories; (4) final survey of remaining facilities and certification for nonrestricted use; preparation of final report. This volume contains the following 3 attachments: (1) Plan for Fully Decontamination and Decommissioning of the Westinghouse Advanced Reactors Division Fuel Laboratories at Cheswick; (2) Environmental Assessment for Decontamination and Decommissioning the Westinghouse Advanced Reactors Division Plutonium Fuel Laboratories, Cheswick, PA; and (3) WARD-386, Quality Assurance Program Description for Decontamination and Decommissioning Activities.

  1. Development of advanced catalytic layer based on vertically aligned conductive polymer arrays for thin-film fuel cell electrodes

    Science.gov (United States)

    Jiang, Shangfeng; Yi, Baolian; Cao, Longsheng; Song, Wei; Zhao, Qing; Yu, Hongmei; Shao, Zhigang

    2016-10-01

    The degradation of carbon supports significantly influences the performance of proton exchange membrane fuel cells (PEMFCs), particularly in the cathode, which must be overcome for the wide application of fuel cells. In this study, advanced catalytic layer with electronic conductive polymer-polypyrrole (PPy) nanowire as ordered catalyst supports for PEMFCs is prepared. A platinum-palladium (PtPd) catalyst thin layer with whiskerette shapes forms along the long axis of the PPy nanowires. The resulting arrays are hot-pressed on both sides of a Nafion® membrane to construct a membrane electrode assembly (without additional ionomer). The ordered thin catalyst layer (approximately 1.1 μm) is applied in a single cell as the anode and the cathode without additional Nafion® ionomer. The single cell yields a maximum performance of 762.1 mW cm-2 with a low Pt loading (0.241 mg Pt cm-2, anode + cathode). The advanced catalyst layer indicates better mass transfer in high current density than that of commercial Pt/C-based electrode. The mass activity is 1.08-fold greater than that of DOE 2017 target. Thus, the as-prepared electrodes have the potential for application in fuel cells.

  2. Thermalhydraulics of advanced 37-element fuel bundle in crept pressure tubes

    Directory of Open Access Journals (Sweden)

    Park Joo Hwan

    2016-01-01

    Full Text Available A CANDU-6 reactor, which has 380 fuel channels of a pressure tube type, is suffering from aging or creep of the pressure tubes. Most of the aging effects for the CANDU primary heat transport system were originated from the horizontal crept pressure tubes. As the operating years of a CANDU reactor proceed, a pressure tube experiences high neutron irradiation damage under high temperature and pressure. The crept pressure tube can deteriorate the Critical Heat Flux (CHF of a fuel channel and finally worsen the reactor operating performance and thermal margin. Recently, the modification of the central subchannel area with increasing inner pitch length of a standard 37-element fuel bundle was proposed and studied in terms of the dryout power enhancement for the uncrept pressure tube since a standard 37-element fuel bundle has a relatively small flow area and high flow resistance at the central region. This study introduced a subchannel analysis for the crept pressure tubes loaded with the inner pitch length modification of a standard 37-element fuel bundle. In addition, the subchannel characteristics were investigated according to the flow area change of the center subchannels for the crept pressure tubes. Also, it was discussed how much the crept pressure tubes affected the thermalhydraulic characteristics of the fuel channel as well as the dryout power for the modification of a standard 37-element fuel bundle.

  3. An Advanced Option for Sodium Cooled TRU Burner Loaded with Uranium-Free Fuels

    Energy Technology Data Exchange (ETDEWEB)

    You, WuSeung; Hong, Ser Gi [Kyung Hee University, Yongin (Korea, Republic of)

    2015-05-15

    The sodium cooled fast reactors of this kind that are called burners are designed to have low conversion ratio by reducing fuel volume fraction or reducing neutron leakage or increasing neutron absorption. However, the typical SFR burners have a limited ability of TRU burning rate due to the fact that they use metallic or oxide fuels containing fertile nuclides such as {sup 238}U and {sup 232}Th and these fertile nuclides generate fissile nuclides through neutron capture even if they are designed to have low conversion ratio (e.g., 0.6). To further enhance the TRU burning rate, the removal of the fertile nuclides from the initial fuels is required and it will accelerate the reduction of TRUs that are accumulated in storages of LWR spent fuels. However, it has been well-known 4 that the removals of the fertile nuclides from the fuel degrade the inherent safety of the SFR burner cores through the significant decrease of the fuel Doppler effect, the increase of sodium void reactivity worth, and reduction of delayed neutron fraction. In this work, new option for the sodium cooled fast TRU burner cores loaded with fertile-free metallic fuels was proposed and the new cores were designed by using the suggested option. The cores were designed to enhance the inherent safety characteristics by using axially central absorber region and 6 or 12 ZrH1.8 moderator rods per fuel assembly. For each option, we considered two different types of fertile-free ternary metallic fuel (i.e., TRU-W-10Zr and TRU-Ni-10Zr). Also, we performed the BOR (Balance of Reactivity) analyses to show the self-controllability under ATWS as a measure of inherent safety. The core performance analysis showed that the new cores using axially central absorber region substantially improve the core performance parameters such as burnup reactivity swing and sodium void reactivity worth.

  4. Status report on high temperature fuel cells in Poland – Recent advances and achievements

    DEFF Research Database (Denmark)

    Molenda, J.; Kupecki, J.; Baron, R.

    2017-01-01

    . National efforts are covering wide range of aspects both in the fundamental research and the applied research. The review present the areas of (i) novel materials for SOFC including ZrO2-based electrolytes, CeO2-based electrolytes, Bi2O3 based electrolytes and proton conducting electrolytes, (ii) cathode...... active in the field of solid oxide fuel cells (SOFC) and molten carbonate fuel cell (MCFC) is presented and discussed. The review is oriented towards presenting key achievements in the technology at the scale from microstructure up to a complete power system based on electrochemical fuel oxidation...

  5. Integrated Advanced Reciprocating Internal Combustion Engine System for Increased Utilization of Gaseous Opportunity Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Pratapas, John; Zelepouga, Serguei; Gnatenko, Vitaliy; Saveliev, Alexei; Jangale, Vilas; Li, Hailin; Getz, Timothy; Mather, Daniel

    2013-08-31

    The project is addressing barriers to or opportunities for increasing distributed generation (DG)/combined heat and power (CHP) use in industrial applications using renewable/opportunity fuels. This project brings together novel gas quality sensor (GQS) technology with engine management for opportunity fuels such as landfill gas, digester gas and coal bed methane. By providing the capability for near real-time monitoring of the composition of these opportunity fuels, the GQS output can be used to improve the performance, increase efficiency, raise system reliability, and provide improved project economics and reduced emissions for engines used in distributed generation and combined heat and power.

  6. The Baleen Whales’ Saving Grace: The Introduction of Petroleum Based Products in the Market and Its Impact on the Whaling Industry

    OpenAIRE

    Henry F. Check; John McCollough

    2010-01-01

    This paper presents empirical evidence which indicates that the introduction of petroleum based products on the American markets was a significant factor in reducing the demand for whale oil. As a result, the whaling industry, America’s 5th largest industry at the time, soon collapsed. A counterfactual study is then presented which suggests that if the introduction of petroleum based products had been delayed, then the increase in demand as a result of rising GDP per capita, as well as rapid ...

  7. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Smith, V.E.

    1994-05-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  8. Surrogate fuel formulation for light naphtha combustion in advanced combustion engines

    KAUST Repository

    Ahmed, Ahfaz

    2015-03-30

    Crude oil once recovered is further separated in to several distinct fractions to produce a range of energy and chemical products. One of the less processed fractions is light naphtha (LN), hence they are more economical to produce than their gasoline and diesel counterparts. Recent efforts have demonstrated usage of LN as transportation fuel for internal combustion engines with slight modifications. In this study, a multicomponent surrogate fuel has been developed for light naphtha fuel using a multi-variable nonlinear constrained optimization scheme. The surrogate, consisting of palette species n-pentane, 2-methylhexane, 2-methylbutane, n-heptane and toluene, was validated against the LN using ignition quality tester following ASTM D6890 methodology. Comparison of LN and the surrogate fuel demonstrated satisfactory agreement.

  9. Project Description Advanced Fuel Cycle Initiative AFC-2A and AFC-2B Experiments

    Energy Technology Data Exchange (ETDEWEB)

    AFCI AFC-2A and AFC-2B Experiments Project Executi

    2007-03-01

    The proposed AFC-2A and AFC-2B irradiation experiments are a continuation of the AFC-1 fuel test series currently in progress in the ATR. This document discusses the experiments and the planned activities that will take place.

  10. Recent advances in solid polymer electrolyte fuel cell technology with low platinum loading electrodes

    Science.gov (United States)

    Srinivasan, Supramaniam; Manko, David J.; Koch, Hermann; Enayetullah, Mohammad A.; Appleby, A. John

    1989-01-01

    Of all the fuel cell systems only alkaline and solid polymer electrolyte fuel cells are capable of achieving high power densities (greater than 1 W/sq cm) required for terrestrial and extraterrestrial applications. Electrode kinetic criteria for attaining such high power densities are discussed. Attainment of high power densities in solid polymer electrolyte fuel cells has been demonstrated earlier by different groups using high platinum loading electrodes (4 mg/sq cm). Recent works at Los Alamos National Laboratory and at Texas A and M University (TAMU) demonstrated similar performance for solid polymer electrolyte fuel cells with ten times lower platinum loading (0.45 mg/sq cm) in the electrodes. Some of the results obtained are discussed in terms of the effects of type and thickness of membrane and of the methods platinum localization in the electrodes on the performance of a single cell.

  11. Pumped lithium loop test to evaluate advanced refractory metal alloys and simulated nuclear fuel elements

    Science.gov (United States)

    Brandenburf, G. P.; Hoffman, E. E.; Smith, J. P.

    1974-01-01

    The performance was determined of refractory metal alloys and uranium nitride fuel element specimens in flowing 1900F (1083C) lithium. The results demonstrate the suitability of the selected materials to perform satisfactorily from a chemical compatibility standpoint.

  12. Low NO/x/ combustion systems for burning heavy residual fuels and high-fuel-bound nitrogen fuels

    Science.gov (United States)

    White, D. J.; Batakis, A.; Lecren, R. T.; Yacobucci, H. G.

    1981-01-01

    Design concepts are presented for lean-lean and staged rich-lean combustors. The combustors are designed for the dry reduction of thermal NO(x), control of NO(x) from fuels containing high levels of organic nitrogen, and control of smoke from low hydrogen content fuels. The combustor concepts are tested with a wide variety of fuels including a middle distillate, a petroleum based heavy residual, a coal derived synthetic, and ratios of blends of these fuels. The configurations of the lean-lean and rich-lean combustion systems are provided along with a description of the test rig and test procedure.

  13. Task 3.3: Warm Syngas Cleanup and Catalytic Processes for Syngas Conversion to Fuels Subtask 3: Advanced Syngas Conversion to Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Lebarbier Dagel, Vanessa M.; Li, J.; Taylor, Charles E.; Wang, Yong; Dagle, Robert A.; Deshmane, Chinmay A.; Bao, Xinhe

    2014-03-31

    activity was to develop methods and enabling materials for syngas conversion to SNG with readily CO2 separation. Suitable methanation catalyst and CO2 sorbent materials were developed. Successful proof-of-concept for the combined reaction-sorption process was demonstrated, which culminated in a research publication. With successful demonstration, a decision was made to switch focus to an area of fuels research of more interest to all three research institutions (CAS-NETL-PNNL). Syngas-to-Hydrocarbon Fuels through Higher Alcohol Intermediates There are two types of processes in syngas conversion to fuels that are attracting R&D interest: 1) syngas conversion to mixed alcohols; and 2) syngas conversion to gasoline via the methanol-to-gasoline process developed by Exxon-Mobil in the 1970s. The focus of this task was to develop a one-step conversion technology by effectively incorporating both processes, which is expected to reduce the capital and operational cost associated with the conversion of coal-derived syngas to liquid fuels. It should be noted that this work did not further study the classic Fischer-Tropsch reaction pathway. Rather, we focused on the studies for unique catalyst pathways that involve the direct liquid fuel synthesis enabled by oxygenated intermediates. Recent advances made in the area of higher alcohol synthesis including the novel catalytic composite materials recently developed by CAS using base metal catalysts were used.

  14. Studies on sulfur poisoning and development of advanced anodic materials for waste-to-energy fuel cells applications

    Science.gov (United States)

    Zaza, Fabio; Paoletti, Claudia; LoPresti, Roberto; Simonetti, Elisabetta; Pasquali, Mauro

    Biomass is the renewable energy source with the most potential penetration in energy market for its positive environmental and socio-economic consequences: biomass live cycles for energy production is carbon neutral; energy crops promote alternative and productive utilizations of rural sites creating new economic opportunities; bioenergy productions promote local energy independence and global energy security defined as availability of energy resource supply. Different technologies are currently available for energy production from biomass, but a key role is played by fuel cells which have both low environmental impacts and high efficiencies. High temperature fuel cells, such as molten carbonate fuel cells (MCFC), are particularly suitable for bioenergy production because it can be directly fed with biogas: in fact, among its principal constituents, methane can be transformed to hydrogen by internal reforming; carbon dioxide is a safe diluent; carbon monoxide is not a poison, but both a fuel, because it can be discharged at the anode, and a hydrogen supplier, because it can produce hydrogen via the water-gas shift reaction. However, the utilization of biomass derived fuels in MCFC presents different problems not yet solved, such as the poisoning of the anode due to byproducts of biofuel chemical processing. The chemical compound with the major negative effects on cell performances is hydrogen sulfide. It reacts with nickel, the main anodic constituent, forming sulfides and blocking catalytic sites for electrode reactions. The aim of this work is to study the hydrogen sulfide effects on MCFC performances for defining the poisoning mechanisms of conventional nickel-based anode, recommending selection criteria of sulfur-tolerant materials, and selecting advanced anodes for MCFC fed with biogas.

  15. Extrapolating power-ramp performance criteria for current and advanced CANDU fuels

    Energy Technology Data Exchange (ETDEWEB)

    Tayal, M.; Chassie, G.G

    2000-06-01

    To improve the precision and accuracy of power-ramp performance criteria for high-burnup fuel, we have examined in-reactor fuel performance data as well as out-reactor test data. The data are consistent with some of the concepts used in the current formulations for defining fuel failure thresholds, such as size of power-ramp and extent of burnup. Our review indicates that there is a need to modify some other aspects of the current formulations; therefore, a modified formulation is presented in this paper. The improvements mainly concern corrodent concentration and its relationships with threshold stress for failure. The new formulation is consistent with known and expected trends such as strength of Zircaloy in corrosive environment, timing of the release of fission products to the pellet-to-sheath gap, CANLUB coating, and fuel burnup. Because of the increased precision and accuracy, the new formulation is better able to identify operational regimes that are at risk of power-ramp failures; this predictive ability provides enhanced protection to fuel against power-ramp defects. At die same time, by removing unnecessary conservatisms in other areas, the new formulation permits a greater range of defect-free operational envelope as well as larger operating margins in regions that are, in fact, not prone to power-ramp failures. (author)

  16. Advanced Microbial Fuel Cell Development, Miniaturization and Energy and Power Density Enhancement

    Science.gov (United States)

    2007-04-30

    fuel cell development, miniaturization, and energy and power density enhancement. The anode is very important in the performance of a microbial fuel cell "MFC", and is often the limiting factor for a high power output. In present work, we used the CNT/PANI composite as the anode materials of MFCs for the first time and investigated the electrocatalytic properties of the composite associated with the bacterium biocatalyst. A method was developed to fabricate a nanostructured CNT/PANI composite anode for

  17. A Linear Model for the Estimation of Fuel Consumption and the Impact Evaluation of Advanced Driving Assistance Systems

    Directory of Open Access Journals (Sweden)

    Gennaro Nicola Bifulco

    2015-10-01

    Full Text Available Reduction of the environmental impact of cars represents one of the biggest transport industry challenges. Beyond more efficient engines, a promising approach is to use eco-driving technologies that help drivers achieve lower fuel consumption and emission levels. In this study, a real-time microscopic fuel consumption model was developed. It was designed to be integrated into simulation platforms for the design and testing of Advanced Driving Assistance Systems (ADAS, aimed at keeping the vehicle within the environmentally friendly driving zone and hence reducing harmful exhaust gases. To allow integration in platforms employed at early stages of ADAS development and testing, the model was kept very simple and dependent on a few easily computable variables. To show the feasibility of the identification of the model (and to validate it, a large experiment involving more than 100 drivers and about 8000 km of driving was carried out using an instrumented vehicle. An instantaneous model was identified based on vehicle speed, acceleration level and gas pedal excursion, applicable in an extra-urban traffic context. Both instantaneous and aggregate validation was performed and the model was shown to estimate vehicle fuel consumption consistently with in-field instantaneous measurements. Very accurate estimations were also shown for the aggregate consumption of each driving session.

  18. Effect of jet-fuel exposure on advanced aerospace composites, II: Mechanical properties. Final report, May-December 1989

    Energy Technology Data Exchange (ETDEWEB)

    Curliss, D.B.; Carlin, D.M.

    1990-08-01

    The sensitivity of several advanced aerospace composite materials to military jet fuel, JP-4, was investigated in this study. The following commercially available fiber/matrix prepreg materials were used in this investigation: AS-4/3501-6; IM7/8551-7A; IM7/977-2 (1377-2T); IM7/5250-4; IM8HTA; and AS-4/PEEK(APC-2). The materials were chosen as representative state-of-the-art materials in their classes of standard epoxy, toughened epoxy, toughened BMI, and thermoplastic matrix composites respectively. The materials were processed into (+ or - 45)2S, (0)12T laminates using the manufacturer's recommended process cycle and standard quality assurance checks were performed on the panels. Standard geometry coupons were fabricated from the panels and divided into a control set and test set. The test coupons were immersed in JP-4 in a sealed pressure vessel at 180 F. The weight gain was recorded as a function of the square root of time and the jet fuel was exchanged each time the coupon weight was recorded. In general, the thermoset matrix composites did not pick-up significant levels of fuel in any lay-up examined; while the thermoplastics did absorb JP-4. The amount of JP-4 absorbed by the thermoplastic matrix composites was dependent on the lay-up. After 1680 hours of total exposure time the mechanical properties of the coupons were evaluated.

  19. Advanced fuel cell development. Progress report, July--September 1978. [. gamma. -LiAlO/sub 2/ electrolyte

    Energy Technology Data Exchange (ETDEWEB)

    Finn, P.A.; Kinoshita, K.; Kucera, G.H.; Pierce, R.D.; Sim, J.W.

    1979-05-01

    This report describes advanced fuel cell research and development activities at Argonne National Laboratory (ANL) during the period July--September 1978. These efforts have been directed toward understanding and improving the components of molten-carbonate-electrolyte fuel cells operated at temperatures near 925 K. The primary focus of this work has been the development of electrolyte structures that have good electrolyte retention and mechanical properties as well as long term stability, and on developing methods of synthesis amenable to mass production. The characterization of these structures and their stability is an integral part of this effort. Synthesis studies have concentrated on the use of low-cost starting material to synthesize ..gamma..-LiAlO/sub 2/, the most stable allotrope of LiAlO/sub 2/ for the fuel cell conditions. Thermal stability and thermomechanical tests were performed on electrolyte mixtures to determine the effect of cell operating conditions on electrolyte tile longevity. A square cell (10.6 cm) with an electrolyte tile containing ..gamma..-LiAlO/sub 2/ was tested. This tile was reinforced by a wire screen. Post-test examination of this cell after 1000 h of operation showed that the reinforced tile was considerably stronger than un-reinforced tiles. Future cells will utilize tiles with metal screen reinforcement.

  20. ACSEPT: a new FP7-Euratom Collaborative Project in the field of partitioning processes for advanced fuel cycles

    Energy Technology Data Exchange (ETDEWEB)

    Bourg, Stephane; Touron, Emmanuel; Caravaca, Concha; Ekberg, Christian; Gaubert, Emmanuel; Hill, Clement [CEA/DEN/MAR/DRCP, Bat 181, CEA Marcoule, BP 17171, 30207 Bagnols/Ceze Cedex (France)

    2008-07-01

    Actinide recycling by separation and transmutation is considered worldwide and particularly in several European countries as one of the most promising strategies to reduce the inventory of radioactive waste, thus contributing to the sustainability of nuclear energy. Consistently with potentially viable recycling strategies, the Collaborative Project ACSEPT will provide a structured research and development framework to develop chemical separation processes compatible with fuel fabrication techniques, with a view to their future demonstration at the pilot level. Two strategies are proposed for the recycling of the actinides issuing from various forms of future nuclear fuels: -) their homogeneous recycling in mixed fuels via a prior group separation of the actinides and -) their heterogeneous recycling in targets or core blankets via their selective separation from fission products. Two major technologies are considered to meet these challenges: hydrometallurgical processes and pyrochemical processes. A training and education programme will also be implemented to share the knowledge among communities and generations so as to maintain the nuclear expertise at the fore-front of Europe. The challenging objectives of ACSEPT will be addressed by a multi-disciplinary consortium composed of European universities, nuclear research bodies and major industrial players. This consortium will generate fundamental improvements for the future design of a potential Advanced Processing Pilot Unit.

  1. ACSEPT, a European project for a new step in the future demonstration of advanced fuel processing

    Energy Technology Data Exchange (ETDEWEB)

    Bourg, S. [CEA Marcoule 30 (France); Hill, C. [CEA Saclay, 91 - Gif sur Yvette (France); Caravaca, C.; Espartero, A. [Ciemat, Madrid (Spain); Rhodes, C.; Taylor, R.; Harrison, M. [National Nuclear Laboratory (United Kingdom); Geist, A. [Fachinformationszentrum Karlsruhe - INE (Germany); Modolo, G. [Forschungszentrum Juelich - FZJ (Germany); Cassayre, L. [Centre National de la Recherche Scientifique (CNRS), 91 - Orsay (France); Malmbeck, R. [Joint Research Centre (JRC) - Institute for Transuranium Elements (ITU) (Germany); De Angelis, G. [ENEA, Bologna (Italy); Bouvet, S. [Alcan, 92 - Courbevoie (France); Klaassen, F. [Nuclear Research and consultancy Group (NRG) (Netherlands); Ekber, C.

    2010-11-15

    Partitioning and transmutation, associated to a multi-recycling of all transuranics should play a key role in the development of sustainable nuclear energy. By joining together 34 partners coming from European universities, nuclear research laboratories and major industrial players, in a multi-disciplinary consortium, the FP7-Euratom-Fission collaborative project ACSEPT (Actinide recycling by separation and transmutation), provides the sound basis and future improvements for future demonstrations of fuel treatment in strong connection with fuel fabrication techniques. ACSEPT is organized into 3 technical domains: 1) selecting and optimizing mature aqueous separation processes (Diamex-Sanex, Ganex); 2) high temperature pyrochemical separation processes, and 3) carrying out engineering and systems studies on hydro- and pyro-chemical processes to prepare for future demonstration at a pilot level. After 2 years of work, 2 successful hot-tests were performed in hydrometallurgy, validating the Sanex and i-Sanex routes. Efforts are now devoted to the Ganex concept. Progress was also made in fuel dissolution and fuel re-fabrication. In pyrometallurgy, promising routes are almost demonstrated for the actinide recovery from aluminium. (A.C.)

  2. WaterTransport in PEM Fuel Cells: Advanced Modeling, Material Selection, Testing and Design Optimization

    Energy Technology Data Exchange (ETDEWEB)

    J. Vernon Cole; Abhra Roy; Ashok Damle; Hari Dahr; Sanjiv Kumar; Kunal Jain; Ned Djilai

    2012-10-02

    Water management in Proton Exchange Membrane, PEM, Fuel Cells is challenging because of the inherent conflicts between the requirements for efficient low and high power operation. Particularly at low powers, adequate water must be supplied to sufficiently humidify the membrane or protons will not move through it adequately and resistance losses will decrease the cell efficiency. At high power density operation, more water is produced at the cathode than is necessary for membrane hydration. This excess water must be removed effectively or it will accumulate in the Gas Diffusion Layers, GDLs, between the gas channels and catalysts, blocking diffusion paths for reactants to reach the catalysts and potentially flooding the electrode. As power density of the cells is increased, the challenges arising from water management are expected to become more difficult to overcome simply due to the increased rate of liquid water generation relative to fuel cell volume. Thus, effectively addressing water management based issues is a key challenge in successful application of PEMFC systems. In this project, CFDRC and our partners used a combination of experimental characterization, controlled experimental studies of important processes governing how water moves through the fuel cell materials, and detailed models and simulations to improve understanding of water management in operating hydrogen PEM fuel cells. The characterization studies provided key data that is used as inputs to all state-of-the-art models for commercially important GDL materials. Experimental studies and microscopic scale models of how water moves through the GDLs showed that the water follows preferential paths, not branching like a river, as it moves toward the surface of the material. Experimental studies and detailed models of water and airflow in fuel cells channels demonstrated that such models can be used as an effective design tool to reduce operating pressure drop in the channels and the associated

  3. Feasibility and Safety Assessment for Advanced Reactor Concepts Using Vented Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Klein, Andrew [Oregon State Univ., Corvallis, OR (United States). Nuclear Engineering and Radiation Health Physics; Matthews, Topher [Oregon State Univ., Corvallis, OR (United States); Lenhof, Renae [Oregon State Univ., Corvallis, OR (United States); Deason, Wesley [Oregon State Univ., Corvallis, OR (United States); Harter, Jackson [Oregon State Univ., Corvallis, OR (United States)

    2015-01-16

    Recent interest in fast reactor technology has led to renewed analysis of past reactor concepts such as Gas Fast Reactors and Sodium Fast Reactors. In an effort to make these reactors more economic, the fuel is required to stay in the reactor for extended periods of time; the longer the fuel stays within the core, the more fertile material is converted into usable fissile material. However, as burnup of the fuel-rod increases, so does the internal pressure buildup due to gaseous fission products. In order to reach the 30 year lifetime requirements of some reactor designs, the fuel pins must have a vented-type design to allow the buildup of fission products to escape. The present work aims to progress the understanding of the feasibility and safety issues related to gas reactors that incorporate vented fuel. The work was separated into three different work-scopes: 1. Quantitatively determine fission gas release from uranium carbide in a representative helium cooled fast reactor; 2. Model the fission gas behavior, transport, and collection in a Fission Product Vent System; and, 3. Perform a safety analysis of the Fission Product Vent System. Each task relied on results from the previous task, culminating in a limited scope Probabilistic Risk Assessment (PRA) of the Fission Product Vent System. Within each task, many key parameters lack the fidelity needed for comprehensive or accurate analysis. In the process of completing each task, the data or methods that were lacking were identified and compiled in a Gap Analysis included at the end of the report.

  4. CANDU advanced fuel R and D programs for 1997 - 2006 in Korea

    Energy Technology Data Exchange (ETDEWEB)

    Suk, H.C.; Yang, M.S.; Sim, K-S.; Yoo, K.J. [Korea Atomic Energy Research Inst., Yusong, Taejon (Korea, Republic of)

    1997-07-01

    KAERI has a comprehensive product development program of CANFLEX and DUPIC fuels to introduce them into CANDU reactors in Korea and a clear vision of how the product will evolve over the next 10 years. CANDU reactors are not the majority of nuclear power plants in Korea, but they produce significant electricity to contribute Korea's economic growth as well as to satisfy the need for energy. The key targets of the development program are safety enhancement, reduction of spent fuel volume, and economic improvements, using the inherent characteristics and advantages of CANDU technology The CANFLEX and DUPIC R and D programs are conducted currently under the second stage of Korea's Nuclear Energy R and D Project as a national mid- and long-term program over the next 10 years from 1997 to 2006. The specific activities of the programs have taken account of the domestic and international environment concerning on non-proliferation in the Peninsula of Korea. As the first of the development products in the short-term, the CANFLEX-NU fuel will be completely developed jointly by KAERI/AECL and will be useful for the older CANDU-6 Wolsong unit 1. As the second product, the CANFLEX-0.9 % equivalent SEU fuel is expected to be completely developed within the next decade. It will be used in CANDU-6 reactors in Korea immediately after the development, if the existing RU in the world is price competitive with natural uranium. The DUPIC R and D program, as a long term program, is expected to demonstrate the possibility of use of used PWR fuel in CANDU reactors in Korea during the next 10 years. The pilot scale fabrication facility would be completed around 2010. (author)

  5. Advanced reactors and novel reactions for the conversion of triglyceride based oils into high quality renewable transportation fuels

    Science.gov (United States)

    Linnen, Michael James

    Sustainable energy continues to grow more important to all societies, leading to the research and development of a variety of alternative and renewable energy technologies. Of these, renewable liquid transportation fuels may be the most visible to consumers, and this visibility is further magnified by the long-term trend of increasingly expensive petroleum fuels that the public consumes. While first-generation biofuels such as biodiesel and fuel ethanol have been integrated into the existing fuel infrastructures of several countries, the chemical differences between them and their petroleum counterparts reduce their effectiveness. This gives rise to the development and commercialization of second generation biofuels, many of which are intended to have equivalent properties to those of their petroleum counterparts. In this dissertation, the primary reactions for a second-generation biofuel process, known herein as the University of North Dakota noncatalytic cracking process (NCP), have been studied at the fundamental level and improved. The NCP is capable of producing renewable fuels and chemicals that are virtually the same as their petroleum counterparts in performance and quality (i.e., petroleum-equivalent). In addition, a novel analytical method, FIMSDIST was developed which, within certain limitations, can increase the elution capabilities of GC analysis and decrease sample processing times compared to other high resolution methods. These advances are particularly useful for studies of highly heterogeneous fuel and/or organic chemical intermediates, such as those studied for the NCP. However the data from FIMSDIST must be supplemented with data from other methods such as for certain carboxylic acid, to provide accurate, comprehensive results, From a series of TAG cracking experiments that were performed, it was found that coke formation during cracking is most likely the result of excessive temperature and/or residence time in a cracking reactor. Based on this

  6. Fuel cell commercialization issues for light-duty vehicle applications

    Science.gov (United States)

    Borroni-Bird, Christopher E.

    The major challenges facing fuel cells in light-duty vehicle applications relate to the high cost of the fuel cell stack components (membrane, electro-catalyst and bipolar plate) which dictate that new manufacturing processes and materials must be developed. Initially, the best fuel for a mass market light-duty vehicle will probably not be the best fuel for the fuel cell (hydrogen); refueling infrastructure and energy density concerns may demand the use of an on-board fuel processor for petroleum-based fuels since this will increase customer acceptance. The use of fuel processors does, however, reduce the fuel cell system's efficiency. Moreover, if such fuels are used then the emissions benefit associated with fuel cells may come with a significant penalty in terms of added complexity, weight, size and cost. However, ultimately, fuel cells powered by hydrogen do promise to be the most efficient and cleanest of automotive powertrains.

  7. Deployment of advanced MACSTOR dry spent fuel storage technology in Korea - A joint development program

    Energy Technology Data Exchange (ETDEWEB)

    Cobanoglu, M. M.; Pattantyus, P. [Atomic Energy Canada Limited, Ottawa (Canada); Song, M. J.; Lee, H. Y. [KHNP/NETEC, Daejeon (Korea, Republic of)

    2002-04-15

    KHNP/NETEC's (K/N) and Atomic Energy of Canada Limited (AECL) are undertaking to jointly develop a high capacity dry storage structure made of reinforced concrete that uses the MACSTOR storage module concept. This effort is based on AECL's experience and on the successful deployment of concrete canisters at Wolsong and on the deployment of air-cooled MACSTOR modules at the Gentilly 2 reactor in Canada. The proposed approach addresses the conditions specific to the Wolsong site: large yearly fuel throughput, space limitations and the need for an economical dry storage structure that can store lifetime spent fuel inventories expected from the four CANDU units. The selected configuration is a 4-row MACSTOR module with a capacity of 24,000 bundles stored in 400 baskets, each holding 60 spent fuel bundles. The module is thus termed MACSTOR/KN-400 and is expected to offer a repetitive storage density increase by a factor of approximately 3, compared to concrete canisters presently used. The four Wolsong units generate spent fuel bundles that, with the high capacity factors achieved, are in the order of 20,000 bundles or more per year. At all Korean nuclear facilities, space limitations dictate the need for storage structures having high storage density. Storage density increases have to be accomplished while maintaining safety parameters during the full term storage of nuclear fuel. During the early 1990's AECL has proceeded with the development of a 2-row MACSTOR storage module that offered a higher storage density and a more economical solution compared to the stand alone concrete canister used at Wolsong 1. These modules are in use at Gentilly since the mid 1990's and operate at a capacity of 200 baskets. The selection of a MACSTOR module with 4 rows of storage cylinders is the natural evolution of the already deployed configuration. It can be developed without additional thermal testing as the fuel is maintained within the existing licensing

  8. Modeling RP-1 Fuel Advanced Distillation Data using Comprehensive Two-Dimensional Gas Chromatography Coupled with Time-of-Flight Mass Spectrometry and Partial Least Squares Analysis

    Science.gov (United States)

    2014-05-07

    Advanced Distillation Data using Comprehensive Two- Dimensional Gas Chromatography coupled with Time-of-Flight Mass Spectrometry and Partial Least Squares...that included comprehensive two-dimensional gas chromatography combined with time-of-flight mass spectrometry (GC × GC –TOFMS) to analyze RP-1 fuels...each RP-1 fuel with good precision and accuracy. The predictive power of the overall method via PLS modeling was assessed using leave -one-out cross

  9. Advanced Product Water Removal and Management (APWR) Fuel Cell System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed innovation is a passive, self-regulating, gravity-independent Advanced Product Water Removal and management (APWR) system for incorporation into Polymer...

  10. Advanced Product Water Removal and Management (APWR) Fuel Cell System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed innovation is a passive, self-regulating, gravity-independent Advanced Product Water Removal (APWR) system for Polymer Electrolyte Membrane (PEM)...

  11. Subtask 3.11 - Production of CBTL-Based Jet Fuels from Biomass-Based Feedstocks and Montana Coal

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Ramesh

    2014-06-01

    The Energy & Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from Exxon Mobil, undertook Subtask 3.11 to use a recently installed bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. The process involves liquefaction of Rosebud mine coal (Montana coal) coupled with an upgrading scheme to produce a naphthenic fuel. The upgrading comprises catalytic hydrotreating and saturation to produce naphthenic fuel. A synthetic jet fuel was prepared by blending equal volumes of naphthenic fuel with similar aliphatic fuel derived from biomass and 11 volume % of aromatic hydrocarbons. The synthetic fuel was tested using standard ASTM International techniques to determine compliance with JP-8 fuel. The composite fuel thus produced not only meets but exceeds the military aviation fuel-screening criteria. A 500-milliliter synthetic jet fuel sample which met internal screening criteria was submitted to the Air Force Research Laboratory (AFRL) at Wright–Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with U.S. Air Force-prescribed alternative aviation fuel initial screening criteria. The results show that this fuel meets or exceeds the key specification parameters for JP-8, a petroleum-based jet fuel widely used by the U.S. military. JP-8 specifications include parameters such as freeze point, density, flash point, and others; all of which were met by the EERC fuel sample. The fuel also exceeds the thermal stability specification of JP-8 fuel as determined by the quartz crystalline microbalance (QCM) test also performed at an independent laboratory as well as AFRL. This means that the EERC fuel looks and acts identically to petroleum-derived jet fuel and can be used

  12. Final Report - Advanced Cathode Catalysts and Supports for PEM Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Debe, Mark

    2012-09-28

    The principal objectives of the program were development of a durable, low cost, high performance cathode electrode (catalyst and support), that is fully integrated into a fuel cell membrane electrode assembly with gas diffusion media, fabricated by high volume capable processes, and is able to meet or exceed the 2015 DOE targets. Work completed in this contract was an extension of the developments under three preceding cooperative agreements/grants Nos. DE-FC-02-97EE50473, DE-FC-99EE50582 and DE-FC36- 02AL67621 which investigated catalyzed membrane electrode assemblies for PEM fuel cells based on a fundamentally new, nanostructured thin film catalyst and support system, and demonstrated the feasibility for high volume manufacturability.

  13. Advances in the high performance polymer electrolyte membranes for fuel cells.

    Science.gov (United States)

    Zhang, Hongwei; Shen, Pei Kang

    2012-03-21

    This critical review tersely and concisely reviews the recent development of the polymer electrolyte membranes and the relationship between their properties and affecting factors like operation temperature. In the first section, the advantages and shortcomings of the corresponding polymer electrolyte membrane fuel cells are analyzed. Then, the limitations of Nafion membranes and their alternatives to large-scale commercial applications are discussed. Secondly, the concepts and approaches of the alternative proton exchange membranes for low temperature and high temperature fuel cells are described. The highlights of the current scientific achievements are given for various aspects of approaches. Thirdly, the progress of anion exchange membranes is presented. Finally, the perspectives of future trends on polymer electrolyte membranes for different applications are commented on (400 references).

  14. Self-ignition of an advanced fuel field-reversed configuration reactor by fusion product heating

    Energy Technology Data Exchange (ETDEWEB)

    Ohnishi, M.; Ohi, S.; Okamoto, M.; Momota, H.; Wakabayashi, J.

    1987-09-01

    A self-ignition of a deuterium-deuterium (D-D)-/sup 3/He fuel field-reversed configuration (FRC) plasma by fusion product heating is studied by using the point plasma model, where an FRC plasma equilibrium is taken into account. It is numerically demonstrated that the D-D-/sup 3/He plasma can be evolved from a deuterium-tritium burning plasma in a controlled manner by means of a compression-decompression control as well as a fueling control. It is also indicated that the increase of a trapped flux is effective for suppressing the excessive elongation of a plasma during the transition. The proposed method may provide a solution to the problem on plasma heating to attain a D-D-/sup 3/He self-ignition.

  15. Preparation and evaluation of advanced catalysts for phosphoric acid fuel cells

    Science.gov (United States)

    Stonehart, P.; Baris, J.; Hockmuth, J.; Pagliaro, P.

    1984-01-01

    The platinum electrocatalysts were characterized for their crystallite sizes and the degree of dispersion on the carbon supports. One application of these electrocatalysts was for anodic oxidation of hydrogen in hot phosphoric acid fuel cells, coupled with the influence of low concentrations of carbon monoxide in the fuel gas stream. In a similar way, these platinum on carbon electrocatalysts were evaluated for oxygen reduction in hot phosphoric acid. Binary noble metal alloys were prepared for anodic oxidation of hydrogen and noble metal-refractory metal mixtures were prepared for oxygen reduction. An exemplar alloy of platinum and palladium (50/50 atom %) was discovered for anodic oxidation of hydrogen in the presence of carbon monoxide, and patent disclosures were submitted. For the cathode, platinum-vanadium alloys were prepared showing improved performance over pure platinum. Preliminary experiments on electrocatalyst utilization in electrode structures showed low utilization of the noble metal when the electrocatalyst loading exceeded one weight percent on the carbon.

  16. ASSERT-PV 3.2: Advanced subchannel thermalhydraulics code for CANDU fuel bundles

    Energy Technology Data Exchange (ETDEWEB)

    Rao, Y.F., E-mail: raoy@aecl.ca; Cheng, Z., E-mail: chengz@aecl.ca; Waddington, G.M., E-mail: waddingg@aecl.ca; Nava-Dominguez, A., E-mail: navadoma@aecl.ca

    2014-08-15

    Highlights: • Introduction to a new version of the Canadian subchannel code, ASSERT-PV 3.2. • Enhanced models for flow-distribution, CHF and post-dryout heat transfer prediction. • Model changes focused on unique features of horizontal CANDU bundles. • Detailed description of model changes for all major thermalhydraulics models. • Discussion on rationale and limitation of the model changes. - Abstract: Atomic Energy of Canada Limited (AECL) has developed the subchannel thermalhydraulics code ASSERT-PV for the Canadian nuclear industry. The most recent release version, ASSERT-PV 3.2 has enhanced phenomenon models for improved predictions of flow distribution, dryout power and CHF location, and post-dryout (PDO) sheath temperature in horizontal CANDU fuel bundles. The focus of the improvements is mainly on modeling considerations for the unique features of CANDU bundles such as horizontal flows, small pitch to diameter ratios, high mass fluxes, and mixed and irregular subchannel geometries, compared to PWR/BWR fuel assemblies. This paper provides a general introduction to ASSERT-PV 3.2, and describes the model changes or additions in the new version to improve predictions of flow distribution, dryout power and CHF location, and PDO sheath temperatures in CANDU fuel bundles.

  17. Advanced Core Design And Fuel Management For Pebble-Bed Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Hans D. Gougar; Abderrafi M. Ougouag; William K. Terry

    2004-10-01

    A method for designing and optimizing recirculating pebble-bed reactor cores is presented. At the heart of the method is a new reactor physics computer code, PEBBED, which accurately and efficiently computes the neutronic and material properties of the asymptotic (equilibrium) fuel cycle. This core state is shown to be unique for a given core geometry, power level, discharge burnup, and fuel circulation policy. Fuel circulation in the pebble-bed can be described in terms of a few well?defined parameters and expressed as a recirculation matrix. The implementation of a few heat?transfer relations suitable for high-temperature gas-cooled reactors allows for the rapid estimation of thermal properties critical for safe operation. Thus, modeling and design optimization of a given pebble-bed core can be performed quickly and efficiently via the manipulation of a limited number key parameters. Automation of the optimization process is achieved by manipulation of these parameters using a genetic algorithm. The end result is an economical, passively safe, proliferation-resistant nuclear power plant.

  18. The internal propagation of fusion flame with the strong shock of a laser driven plasma block for advanced nuclear fuel ignition

    Institute of Scientific and Technical Information of China (English)

    B.Malekynia; S.S.Razavipour

    2013-01-01

    An accelerated skin layer may be used to ignite solid state fuels.Detailed analyses were clarified by solving the hydrodynamic equations for nonlinear force driven plasma block ignition.In this paper,the complementary mechanisms are included for the advanced fuel ignition:external factors such as lasers,compression,shock waves,and sparks.The other category is created within the plasma fusion as reheating of an alpha particle,the Bremsstrahlung absorption,expansion,conduction,and shock waves generated by explosions.With the new condition for the control of shock waves,the spherical deuterium-tritium fuel density should be increased to 75 times that of the solid state.The threshold ignition energy flux density for advanced fuel ignition may be obtained using temperature equations,including the ones for the density profile obtained through the continuity equation and the expansion velocity for the r ≠ 0 layers.These thresholds are significantly reduced in comparison with the ignition thresholds at x =0 for solid advanced fuels.The quantum correction for the collision frequency is applied in the case of the delay in ion heating.Under the shock wave condition,the spherical protonboron and proton-lithium fuel densities should be increased to densities 120 and 180 times that of the solid state.These plasma compressions are achieved through a longer duration laser pulse or X-ray.

  19. Agronomic comparison of several brassica species in the U.S. Corn Belt as feedstock for hydrotreated jet fuel

    Science.gov (United States)

    Through a patented process developed in the U.S., hydrotreated renewable jet fuel (HRJ) derived from plant oils has been commercially demonstrated. However, full-scale production has not yet come to fruition because HRJ is not economically competitive with petroleum-based fuels due to high feedstock...

  20. Performance of advanced automotive fuel cell systems with heat rejection constraint

    Science.gov (United States)

    Ahluwalia, R. K.; Wang, X.; Steinbach, A. J.

    2016-03-01

    Although maintaining polymer electrolyte fuel cells (PEFC) at temperatures below 80 °C is desirable for extended durability and enhanced performance, the automotive application also requires the PEFC stacks to operate at elevated temperatures and meet the heat rejection constraint, stated as Q/ΔT catalysts in the membrane electrode assemblies. In the illustrative example, stack coolant temperatures >90 °C, stack inlet pressures >2 atm, and cathode stoichiometries cell at the same cell voltage (663 mV) and pressure (2.5 atm) but lower temperature (85 °C), higher cathode stoichiometry (2), and 100% relative humidity.

  1. Partial Substitution of Fuel Alcohol for Oil Consumption

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    @@ With the rapid development of the national economy in the 21st century, China has constantly increased its oil consumption and already depends on imported oil for close to 50% of its supply. Due to various factors, the price of oil keeps increasing. Various biological energy sources have therefore aroused people's interest. As fuel alcohol was developed ahead of the pack, and its technology has now matured worldwide, it has become a focus as a partial substitute in petroleum based fuels.

  2. A Demonstration of Advanced Safety Analysis Tools and Methods Applied to Large Break LOCA and Fuel Analysis for PWRs

    Energy Technology Data Exchange (ETDEWEB)

    Szilard, Ronaldo Henriques [Idaho National Laboratory; Smith, Curtis Lee [Idaho National Laboratory; Martineau, Richard Charles [Idaho National Laboratory

    2016-03-01

    The U.S. Nuclear Regulatory Commission (NRC) is currently proposing a rulemaking designated as 10 CFR 50.46c to revise the loss-of-coolant accident (LOCA)/emergency core cooling system acceptance criteria to include the effects of higher burnup on fuel/cladding performance. We propose a demonstration problem of a representative four-loop PWR plant to study the impact of this new rule in the US nuclear fleet. Within the scope of evaluation for the 10 CFR 50.46c rule, aspects of safety, operations, and economics are considered in the industry application demonstration presented in this paper. An advanced safety analysis approach is used, by integrating the probabilistic element with deterministic methods for LOCA analysis, a novel approach to solving these types of multi-physics, multi-scale problems.

  3. HEAPA Filter Bank In-Place Leak Test for ACUs of Advanced Fuel Science Building in 2010

    Energy Technology Data Exchange (ETDEWEB)

    Ji, Chul Goo; Bae, Sang Oh [KAERI, Daejeon (Korea, Republic of)

    2010-12-15

    Air cleaning units installed in the Advanced Fuel Science Building were performed visual inspection, airflow capacity test, and HEAPA filter bank in-place leak test in accordance with ASME N-510-1989. All the above inspections was acceptable. Visual inspection was satisfied to AUC-556 and AUC-557. Airflow capacity was 96%(30,240 m{sup 3}/h) of design airflow capacity(31,500 m{sup 3}/h) for AUC-556 and was 97%(22,800 m{sup 3}/h) of design airflow capacity(22,800 m{sup 3}/h) for AUC-557, and was maintained within {+-}10% of the specified value. Penetration of HEAPA filter bank in-place leak test was 0.009% for AUC-556 and was 0.013% for AUC-557 and these values were maintained less than the acceptance criteria(0.05%)

  4. Preliminary conceptual designs for advanced packages for the geologic disposal of spent fuel

    Energy Technology Data Exchange (ETDEWEB)

    Westerman, R.E.

    1979-04-01

    The present study assumes that the spent fuel will be disposed of in mined repositories in continental geologic formations, and that the post-emplacement control of the radioactive species will be accomplished independently by both the natural barrier, i.e., the geosphere, and the engineered barrier system, i.e., the package components consisting of the stabilizer, the canister, and the overpack; and the barrier components external to the package consisting of the hole sleeve and the backfill medium. The present document provides an overview of the nature of the spent fuel waste; the general approach to waste containment, using the defense-in-depth philosophy; material options, both metallic and nonmetallic, for the components of the engineered barrier system; a set of strawman criteria to guide the development of package/engineered barrier systems; and four preliminary concepts representing differing approaches to the solution of the containment problem. These concepts use: a corrosion-resistant meta canister in a special backfill (2 barriers); a mild steel canister in a corrosion-resistant metallic or nonmetallic hole sleeve, surrounded by a special backfill (2 barriers); a corrosion-resistant canister and a corrosion-resistant overpack (or hole sleeve) in a special backfill (3 barriers); and a mild steel canister in a massive corrosion-resistant bore sleeve surrounded by a polymer layer and a special backfill (3 barriers). The lack of definitive performance requirements makes it impossible to evaluate these concepts on a functional basis at the present time.

  5. Advanced biological treatment of aqueous effluent from the nuclear fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Pitt, Jr., W. W.; Hancher, C. W.; Patton, B. D.; Shumate, II, S. E.

    1979-01-01

    Many of the processing steps in the nuclear fuel cycle generate aqueous effluent streams bearing contaminants that can, because of their chemical or radiological properties, pose an environmental hazard. Concentration of such contaminants must be reduced to acceptable levels before the streams can be discharged to the environment. Two classes of contaminants, nitrates and heavy metals, are addressed in this study. Specific techniques aimed at the removal of nitrates and radioactive heavy metals by biological processes are being developed, tested, and demonstrated. Although cost comparisons between biological processes and current treatment methods are presented, these comparisons may be misleading because biological processes yield environmentally better end results which are difficult to price. However, a strong case is made for the use of biological processes for removing nitrates and heavy metals fron nuclear fuel cycle effluents. The estimated costs for these methods are as low as, or lower than, those for alternate processes. In addition, the resulting disposal products - nitrogen gas, CO/sub 2/, and heavy metals incorporated into microorganisms - are much more ecologically desirable than the end products of other waste treatment methods.

  6. FURTHER ASSESSMENTS OF THE ATTRACTIVENESS OF MATERIALS IN ADVANCED NUCLEAR FUEL CYCLES FROM A SAFEGUARDS PERSPECTIVE

    Energy Technology Data Exchange (ETDEWEB)

    Bathke, C. G.; Jarvinen, G. D.; Wallace, R. K.; Ireland, J. R.; Johnson, M. W.; Sleaford, Brad W.; Ebbinghaus, B. B.; Bradley, Keith S.; Collins, Brian A.; Smith, Brian W.; Prichard, Andrew W.

    2008-10-01

    This paper summarizes the results of an extension to an earlier study [ ] that examined the attractiveness of materials mixtures containing special nuclear materials (SNM) associated with the PUREX, UREX+, and COEX reprocessing schemes. This study focuses on the materials associated with the UREX, COEX, THOREX, and PYROX reprocessing schemes. This study also examines what is required to render plutonium as “unattractive.” Furthermore, combining the results of this study with those from the earlier study permits a comparison of the uranium and thorium based fuel cycles on the basis of the attractiveness of the SNM associated with each fuel cycle. Both studies were performed at the request of the United States Department of Energy (DOE), and are based on the calculation of “attractiveness levels” that has been couched in terms chosen for consistency with those normally used for nuclear materials in DOE nuclear facilities [ ]. The methodology and key findings will be presented. Additionally, how these attractiveness levels relate to proliferation resistance (e.g. by increasing impediments to the diversion, theft, undeclared production of SNM for the purpose of acquiring a nuclear weapon), and how they could be used to help inform policy makers, will be discussed.

  7. Bioremediation of petroleum based contaminants with biosurfactant produced by a newly isolated petroleum oil degrading bacterial strain

    Directory of Open Access Journals (Sweden)

    Debajit Borah

    2017-03-01

    Full Text Available Petroleum based hydrocarbon degrading and biosurfactant producing bacterial strain was isolated from an automobile engine. The strain was identified as Bacillus cereus DRDU1 on the basis of 16S rDNA sequencing analysis. The strain was found to be efficiently degrading 96% of kerosene making it a potential tool for bioremediation of petroleum based contaminants. Production and optimization of the biosurfactant produced by the isolate were also carried out. Surface hydrophobicity trait of isolate was found to be 60.67 ± 1.53% and foaming percentage of the crude biosurfactant was found to be 31.33 ± 0.58%. The presence of amino acids and sugar moieties in the biosurfactant was confirmed by biochemical tests and were further validated by FTIR (the Fourier transform infrared spectrometric analysis revealing the presence of υOH, υCOO, υCOOH, υCH (stretching, υNH, υCH2, υCH3, and υCH (bending, and υCO (ester in the surfactant. The decrease in contact angle of hydrocarbon oil from (30.67 ± 1.15° to (21.3 ± 1.53° respectively after 3 and 6 days of incubation reveals its potential to emulsify petroleum oil. Further, emulsification index (E24 of biosurfactant against kerosene, crude oil, and used engine oil were determined to be 55.33 ± 1.53%, 29.67 ± 1.53%, and 20 ± 1% respectively which attracts its future application in MEOR (microbial enhanced oil recovery process.

  8. OSMOSE an experimental program for improving neutronic predictions of advanced nuclear fuels.

    Energy Technology Data Exchange (ETDEWEB)

    Klann, R. T.; Aliberti, G.; Zhong, Z.; Graczyk, D.; Loussi, A.; Nuclear Engineering Division; Commissariat a l Energie Atomique

    2007-10-18

    This report describes the technical results of tasks and activities conducted in FY07 to support the DOE-CEA collaboration on the OSMOSE program. The activities are divided into five high-level tasks: reactor modeling and pre-experiment analysis, sample fabrication and analysis, reactor experiments, data treatment and analysis, and assessment for relevance to high priority advanced reactor programs (such as GNEP and Gen-IV).

  9. Development of Head-end Pyrochemical Reduction Process for Advanced Oxide Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Park, B. H.; Seo, C. S.; Hur, J. M.; Jeong, S. M.; Hong, S. S.; Choi, I. K.; Choung, W. M.; Kwon, K. C.; Lee, I. W. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2008-12-15

    The development of an electrolytic reduction technology for spent fuels in the form of oxide is of essence to introduce LWR SFs to a pyroprocessing. In this research, the technology was investigated to scale a reactor up, the electrochemical behaviors of FPs were studied to understand the process and a reaction rate data by using U{sub 3}O{sub 8} was obtained with a bench scale reactor. In a scale of 20 kgHM/batch reactor, U{sub 3}O{sub 8} and Simfuel were successfully reduced into metals. Electrochemical characteristics of LiBr, LiI and Li{sub 2}Se were measured in a bench scale reactor and an electrolytic reduction cell was modeled by a computational tool.

  10. AB INITIO STUDY OF ADVANCED METALLIC NUCLEAR FUELS FOR FAST BREEDER REACTORS

    Energy Technology Data Exchange (ETDEWEB)

    Landa, A; Soderlind, P; Grabowski, B; Turchi, P A; Ruban, A V; Vitos, L

    2012-04-23

    Density-functional formalism is applied to study the ground state properties of {gamma}-U-Zr and {gamma}-U-Mo solid solutions. Calculated heats of formation are compared with CALPHAD assessments. We discuss how the heat of formation in both alloys correlates with the charge transfer between the alloy components. The decomposition curves for {gamma}-based U-Zr and U-Mo solid solutions are derived from Ising-type Monte Carlo simulations. We explore the idea of stabilization of the {delta}-UZr{sub 2} compound against the {alpha}-Zr (hcp) structure due to increase of Zr d-band occupancy by the addition of U to Zr. We discuss how the specific behavior of the electronic density of states in the vicinity of the Fermi level promotes the stabilization of the U{sub 2}Mo compound. The mechanism of possible Am redistribution in the U-Zr and U-Mo fuels is also discussed.

  11. Preparation and evaluation of advanced electrocatalysts for phosphoric acid fuel cells

    Science.gov (United States)

    Stonehart, P.; Baris, J.; Hochmuth, J.; Pagliaro, P.

    1981-01-01

    Two cooperative phenomena are required the development of highly efficient porous electrocatalysts: (1) is an increase in the electrocatalytic activity of the catalyst particle; and (2) is the availability of that electrocatalyst particle for the electromechanical reaction. The two processes interact with each other so that improvements in the electrochemical activity must be coupled with improvements in the availability of the electrocatalyst for reaction. Cost effective and highly reactive electrocatalysts were developed. The utilization of the electrocatalyst particles in the porous electrode structures was analyzed. It is shown that a large percentage of the electrocatalyst in anode structures is not utilized. This low utilization translates directly into a noble metal cost penalty for the fuel cell.

  12. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    Energy Technology Data Exchange (ETDEWEB)

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  13. Development and Utilization of mathematical Optimization in Advanced Fuel Cycle Systems Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Turinsky, Paul; Hays, Ross

    2011-09-02

    Over the past sixty years, a wide variety of nuclear power technologies have been theorized, investigated and tested to various degrees. These technologies, if properly applied, could provide a stable, long-term, economical source of CO2-free electric power. However, the recycling of nuclear fuel introduces a degree of coupling between reactor systems which must be accounted for when making long term strategic plans. This work investigates the use of a simulated annealing optimization algorithm coupled together with the VISION fuel cycle simulation model in order to identify attractive strategies from economic, evironmental, non-proliferation and waste-disposal perspectives, which each have associated an objective function. The simulated annealing optimization algorithm works by perturbing the fraction of new reactor capacity allocated to each available reactor type (using a set of heuristic rules) then evaluating the resulting deployment scenario outcomes using the VISION model and the chosen objective functions. These new scenarios, which are either accepted or rejected according the the Metropolis Criterion, are then used as the basis for further perturbations. By repeating this process several thousand times, a family of near-optimal solutions are obtained. Preliminary results from this work using a two-step, Once-through LWR to Full-recycle/FRburner deployment scenario with exponentially increasing electric demand indicate that the algorithm is capable of nding reactor deployment pro les that reduce the long-term-heat waste disposal burden relative to an initial reference scenario. Further work is under way to re ne the current results and to extend them to include the other objective functions and to examine the optimization trade-o s that exist between these di erent objectives.

  14. FY2001 Final Report Laboratory Directed Research and Development (LDRD) on Advanced Nuclear Fuel Design in the Future Nuclear Energy Market

    Energy Technology Data Exchange (ETDEWEB)

    Christensen, D.; Choi, J.-S.; DiSabatino, A.; Wirth, B.

    2001-09-30

    This study is to research the maturity of advanced nuclear fuel and cladding technology and to explore the suitability of existing technology for addressing the emerging requirements for Generation IV reactors and emerging thermal/fast spectrum reactors, while simultaneously addressing nuclear waste management, and proliferation resistance concerns.

  15. Proceedings of the joint contractors meeting: FE/EE Advanced Turbine Systems conference FE fuel cells and coal-fired heat engines conference

    Energy Technology Data Exchange (ETDEWEB)

    Geiling, D.W. [ed.

    1993-08-01

    The joint contractors meeting: FE/EE Advanced Turbine Systems conference FEE fuel cells and coal-fired heat engines conference; was sponsored by the US Department of Energy Office of Fossil Energy and held at the Morgantown Energy Technology Center, P.O. Box 880, Morgantown, West Virginia 26507-0880, August 3--5, 1993. Individual papers have been entered separately.

  16. Comparative analysis of the production costs and life-cycle GHG emissions of FT liquid fuels from coal and natural gas.

    Science.gov (United States)

    Jaramillo, Paulina; Griffin, W Michael; Matthews, H Scott

    2008-10-15

    Liquid transportation fuels derived from coal and natural gas could helpthe United States reduce its dependence on petroleum. The fuels could be produced domestically or imported from fossil fuel-rich countries. The goal of this paper is to determine the life-cycle GHG emissions of coal- and natural gas-based Fischer-Tropsch (FT) liquids, as well as to compare production costs. The results show that the use of coal- or natural gas-based FT liquids will likely lead to significant increases in greenhouse gas (GHG) emissions compared to petroleum-based fuels. In a best-case scenario, coal- or natural gas-based FT-liquids have emissions only comparable to petroleum-based fuels. In addition, the economic advantages of gas-to-liquid (GTL) fuels are not obvious: there is a narrow range of petroleum and natural gas prices at which GTL fuels would be competitive with petroleum-based fuels. CTLfuels are generally cheaper than petroleum-based fuels. However, recent reports suggest there is uncertainty about the availability of economically viable coal resources in the United States. If the U.S. has a goal of increasing its energy security, and at the same time significantly reducing its GHG emissions, neither CTL nor GTL consumption seem a reasonable path to follow.

  17. Requirements for a Dynamic Solvent Extraction Module to Support Development of Advanced Technologies for the Recycle of Used Nuclear Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Jack Law; Veronica Rutledge; Candido Pereira; Jackie Copple; Kurt Frey; John Krebs; Laura Maggos; Kevin Nichols; Kent Wardle; Pratap Sadasivan; Valmor DeAlmieda; David Depaoli

    2011-06-01

    The Department of Energy's Nuclear Energy Advanced Modeling and Simulation (NEAMS) Program has been established to create and deploy next generation, verified and validated nuclear energy modeling and simulation capabilities for the design, implementation, and operation of future nuclear energy systems to improve the U.S. energy security. As part of the NEAMS program, Integrated Performance and Safety Codes (IPSC's) are being produced to significantly advance the status of modeling and simulation of energy systems beyond what is currently available to the extent that the new codes be readily functional in the short term and extensible in the longer term. The four IPSC areas include Safeguards and Separations, Reactors, Fuels, and Waste Forms. As part of the Safeguards and Separations (SafeSeps) IPSC effort, interoperable process models are being developed that enable dynamic simulation of an advanced separations plant. A SafeSepss IPSC 'toolkit' is in development to enable the integration of separation process modules and safeguards tools into the design process by providing an environment to compose, verify and validate a simulation application to be used for analysis of various plant configurations and operating conditions. The modules of this toolkit will be implemented on a modern, expandable architecture with the flexibility to explore and evaluate a wide range of process options while preserving their stand-alone usability. Modules implemented at the plant-level will initially incorporate relatively simple representations for each process through a reduced modeling approach. Final versions will incorporate the capability to bridge to subscale models to provide required fidelity in chemical and physical processes. A dynamic solvent extraction model and its module implementation are needed to support the development of this integrated plant model. As a stand-alone application, it will also support solvent development of extraction flowsheets

  18. Research advance on methanol-diesel emulsifying fuel%甲醇-柴油乳化燃料的研究进展

    Institute of Scientific and Technical Information of China (English)

    冯国琳; 焦纬洲; 高璟; 于娜娜; 王笃政

    2012-01-01

    概述了甲醇-柴油乳化燃料的发展情况,介绍了甲醇-柴油乳化燃料的乳化、节能机理,重点介绍了甲醇-柴油乳化燃料的乳化剂和乳化设备及其燃烧特性研究进展,最后对甲醇-柴油乳化燃料的发展趋势进行了展望。%The development of methanol-diesel emulsifying fuel was summarized. The mechanism on emulsi lying and energy saving of methanol diesel emulsifying fuel was introduced. The advance in emulsifier, emulsif ying equipment and combustion characteristic of methanol-diesel emulsifying fuel were stressly described. Finally, the future development tendency of methanol-diesel emulsifying fuel was proposed.

  19. Microstructural Characterization of a Mg Matrix U-Mo Dispersion Fuel Plate Irradiated in the Advanced Test Reactor to High Fission Density: SEM Results

    Science.gov (United States)

    Keiser, Dennis D.; Jue, Jan-Fong; Miller, Brandon D.; Gan, Jian; Robinson, Adam B.; Medvedev, Pavel G.; Madden, James W.; Moore, Glenn A.

    2016-06-01

    Low-enriched (U-235 reactors. In most cases, fuel plates with Al or Al-Si alloy matrices have been tested in the Advanced Test Reactor to support this development. In addition, fuel plates with Mg as the matrix have also been tested. The benefit of using Mg as the matrix is that it potentially will not chemically interact with the U-Mo fuel particles during fabrication or irradiation, whereas with Al and Al-Si alloys such interactions will occur. Fuel plate R9R010 is a Mg matrix fuel plate that was aggressively irradiated in ATR. This fuel plate was irradiated as part of the RERTR-8 experiment at high temperature, high fission rate, and high power, up to high fission density. This paper describes the results of the scanning electron microscopy (SEM) analysis of an irradiated fuel plate using polished samples and those produced with a focused ion beam. A follow-up paper will discuss the results of transmission electron microscopy (TEM) analysis. Using SEM, it was observed that even at very aggressive irradiation conditions, negligible chemical interaction occurred between the irradiated U-7Mo fuel particles and Mg matrix; no interconnection of fission gas bubbles from fuel particle to fuel particle was observed; the interconnected fission gas bubbles that were observed in the irradiated U-7Mo particles resulted in some transport of solid fission products to the U-7Mo/Mg interface; the presence of microstructural pathways in some U-9.1 Mo particles that could allow for transport of fission gases did not result in the apparent presence of large porosity at the U-7Mo/Mg interface; and, the Mg-Al interaction layers that were present at the Mg matrix/Al 6061 cladding interface exhibited good radiation stability, i.e. no large pores.

  20. Premium Fuel Production From Mining and Timber Waste Using Advanced Separation and Pelletizing Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R. Q.; Taulbee, D.; Parekh, B. K.; Tao, D.

    2005-12-05

    The Commonwealth of Kentucky is one of the leading states in the production of both coal and timber. As a result of mining and processing coal, an estimated 3 million tons of fine coal are disposed annually to waste-slurry impoundments with an additional 500 million tons stored at a number of disposal sites around the state due to past practices. Likewise, the Kentucky timber industry discards nearly 35,000 tons of sawdust on the production site due to unfavorable economics of transporting the material to industrial boilers for use as a fuel. With an average heating value of 6,700 Btu/lb, the monetary value of the energy disposed in the form of sawdust is approximately $490,000 annually. Since the two industries are typically in close proximity, one promising avenue is to selectively recover and dewater the fine-coal particles and then briquette them with sawdust to produce a high-value fuel. The benefits are i) a premium fuel product that is low in moisture and can be handled, transported, and utilized in existing infrastructure, thereby avoiding significant additional capital investment and ii) a reduction in the amount of fine-waste material produced by the two industries that must now be disposed at a significant financial and environmental price. As such, the goal of this project was to evaluate the feasibility of producing a premium fuel with a heating value greater than 10,000 Btu/lb from waste materials generated by the coal and timber industries. Laboratory and pilot-scale testing of the briquetting process indicated that the goal was successfully achieved. Low-ash briquettes containing 5% to 10% sawdust were produced with energy values that were well in excess of 12,000 Btu/lb. A major economic hurdle associated with commercially briquetting coal is binder cost. Approximately fifty binder formulations, both with and without lime, were subjected to an extensive laboratory evaluation to assess their relative technical and economical effectiveness as binding

  1. Premium Fuel Production From Mining and Timber Waste Using Advanced Separation and Pelletizing Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R. Q.; Taulbee, D.; Parekh, B. K.; Tao, D.

    2005-12-05

    The Commonwealth of Kentucky is one of the leading states in the production of both coal and timber. As a result of mining and processing coal, an estimated 3 million tons of fine coal are disposed annually to waste-slurry impoundments with an additional 500 million tons stored at a number of disposal sites around the state due to past practices. Likewise, the Kentucky timber industry discards nearly 35,000 tons of sawdust on the production site due to unfavorable economics of transporting the material to industrial boilers for use as a fuel. With an average heating value of 6,700 Btu/lb, the monetary value of the energy disposed in the form of sawdust is approximately $490,000 annually. Since the two industries are typically in close proximity, one promising avenue is to selectively recover and dewater the fine-coal particles and then briquette them with sawdust to produce a high-value fuel. The benefits are i) a premium fuel product that is low in moisture and can be handled, transported, and utilized in existing infrastructure, thereby avoiding significant additional capital investment and ii) a reduction in the amount of fine-waste material produced by the two industries that must now be disposed at a significant financial and environmental price. As such, the goal of this project was to evaluate the feasibility of producing a premium fuel with a heating value greater than 10,000 Btu/lb from waste materials generated by the coal and timber industries. Laboratory and pilot-scale testing of the briquetting process indicated that the goal was successfully achieved. Low-ash briquettes containing 5% to 10% sawdust were produced with energy values that were well in excess of 12,000 Btu/lb. A major economic hurdle associated with commercially briquetting coal is binder cost. Approximately fifty binder formulations, both with and without lime, were subjected to an extensive laboratory evaluation to assess their relative technical and economical effectiveness as binding

  2. Preliminary ecotoxicity assessment of new generation alternative fuels in seawater.

    Science.gov (United States)

    Rosen, Gunther; Dolecal, Renee E; Colvin, Marienne A; George, Robert D

    2014-06-01

    The United States Navy (USN) is currently demonstrating the viability of environmentally sustainable alternative fuels to power its fleet comprised of aircraft and ships. As with any fuel used in a maritime setting, there is potential for introduction into the environment through transport, storage, and spills. However, while alternative fuels are often presumed to be eco-friendly relative to conventional petroleum-based fuels, their environmental fate and effects on marine environments are essentially unknown. Here, standard laboratory-based toxicity experiments were conducted for two alternative fuels, jet fuel derived from Camelina sativa (wild flax) seeds (HRJ5) and diesel fuel derived from algae (HRD76), and two conventional counterparts, jet fuel (JP5) and ship diesel (F76). Initial toxicity tests performed on water-accommodated fractions (WAF) from neat fuels partitioned into seawater, using four standard marine species in acute and chronic/sublethal tests, indicate that the alternative fuels are significantly less toxic to marine organisms.

  3. Expanding Robust HCCI Operation with Advanced Valve and Fuel Control Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Szybist, J. P. [Oak Ridge National Lab., Oak Ridge, TN (United States); Confer, K. [Delphi Automotive Systems (United States)

    2012-09-11

    Delphi Automotive Systems and ORNL established this CRADA to advance the commercialization potential of the homogeneous charge compression ignition (HCCI) advanced combustion strategy for gasoline engine platforms. HCCI combustion has been shown by others to produce high diesel-like efficiency on a gasoline engine platform while simultaneously producing low NOX and particulate matter emissions. However, the commercialization barriers that face HCCI combustion are significant, with requirements for a more active engine control system, likely with next-cycle closed-loop feedback control, and with advanced valve train technologies to enable negative valve overlap conditions. In the partnership between Delphi and ORNL, each organization brought a unique and complementary set of skills to the project. Delphi has made a number of breakthroughs with production-intent valve train technologies and controls in recent years to make a part time production-intent HCCI engine plausible. ORNL has extensive knowledge and expertise with HCCI combustion, and also has a versatile research engine with hydraulic valve actuation (HVA) that is useful for guiding production of a cam-based HCCI system. Partnering these knowledge bases and capabilities was essential towards making progress to better understand HCCI combustion and the commercialization barriers that it faces. ORNL and Delphi maintained strong collaboration throughout the project. Meetings were held regularly, with additional reports, presentations, and meetings as necessary to maintain progress. Delphi provided guidance to ORNL regarding operational strategies to investigate on their single-cylinder research engine with HVA and data from their experimental multi-cylinder engine for modeling. ORNL provided single-cylinder engine data and modeling results.

  4. Multi level optimization of burnable poison utilization for advanced PWR fuel management

    Science.gov (United States)

    Yilmaz, Serkan

    The objective of this study was to develop an unique methodology and a practical tool for designing burnable poison (BP) pattern for a given PWR core. Two techniques were studied in developing this tool. First, the deterministic technique called Modified Power Shape Forced Diffusion (MPSFD) method followed by a fine tuning algorithm, based on some heuristic rules, was developed to achieve this goal. Second, an efficient and a practical genetic algorithm (GA) tool was developed and applied successfully to Burnable Poisons (BPs) placement optimization problem for a reference Three Mile Island-1 (TMI-1) core. This thesis presents the step by step progress in developing such a tool. The developed deterministic method appeared to perform as expected. The GA technique produced excellent BP designs. It was discovered that the Beginning of Cycle (BOC) Kinf of a BP fuel assembly (FA) design is a good filter to eliminate invalid BP designs created during the optimization process. By eliminating all BP designs having BOC Kinf above a set limit, the computational time was greatly reduced since the evaluation process with reactor physics calculations for an invalid solution is canceled. Moreover, the GA was applied to develop the BP loading pattern to minimize the total Gadolinium (Gd) amount in the core together with the residual binding at End-of-Cycle (EOC) and to keep the maximum peak pin power during core depletion and Soluble boron concentration at BOC both less than their limit values. The number of UO2/Gd2O3 pins and Gd 2O3 concentrations for each fresh fuel location in the core are the decision variables and the total amount of the Gd in the core and maximum peak pin power during core depletion are in the fitness functions. The use of different fitness function definition and forcing the solution movement towards to desired region in the solution space accelerated the GA runs. Special emphasize is given to minimizing the residual binding to increase core lifetime as

  5. Advanced process control for solid fuel boilers. Phase 2; Avancerad processtyrning av fastbraensleeldade rostpannor. Etapp 2

    Energy Technology Data Exchange (ETDEWEB)

    Ehleskog, Rickard; Lundborg, Rickard; Schuster, Robert; Wrangensten, Lars [AaF-Energikonsult AB, Stockholm (Sweden)

    2002-04-01

    AaF-Energikonsult AB runs within the research programme 'Applied combustion technology' a bigger project under the title 'Possibilities to improved operation of forest-industrial bark boilers by optimised combustion control'. In the project several measures have been identified, that can help to improve the conditions favourable for the combustion and fluid dynamic, for four selected reference grate boilers and grate boilers in general. The boiler at Billerud's paper mill, which is underlying to this project in several ways, is now being rebuilt. During the modifications of the boiler the existing control system will be modified with modern technique to enable operation with low emissions. The new control system consists of several parts, of witch the IR-based ones for fuel input and grate feeding are two totally separated systems. The pressure of the dome, i.e. the effect of the boiler, is the most superior parameter, and is regulated with the combustion air. Amounts of secondary and tertiary air are quoted to the total combustion airflow. The primary oxygen level is primarily regulated with the tertiary air. But if this won't be done without the tertiary air to diverge from de defined working area, the secondary air will assist. The oxygen set point is constantly decreasing until the CO-level exceeds a defined level. Then, the set point will be momentary increased. CFD-calculations have been performed for the modified boiler in Karlsborg for two different loads. The simulations clearly show that the flue gases have a more even retention time in the modified boiler and that the flow pattern is significantly improved. However, concentration gradients of oxygen and temperature gradients still exist. The conclusion is that there is a potential for further improving of the air and flue gas control strategies. The following new control strategies are proposed in the project based on conventional analyse technology; If the furnace

  6. Basic research and industrialization of CANDU advanced fuel - Effect of transverse convex curvature on boiling heat transfer and ONB point of nucleate fuel rods

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kyung Chun; Lee, Young; Lee, Sung Hong [Pusan National University, Pusan (Korea)

    2000-04-01

    Recently, the effect of convex curvature on heat transfer should not be ignored when the radius of curvature tends to be small and/or associated with high heat transfer rate cases. Both analytical and experimental studies were performed to prove the effect of transverse convex curvature on the boiling heat transfer in concentric annuli flows. The effect of the transverse convex surface curvature on ONB are studied analytically in the case of reactor and evaporator. It is seen that the inner wall heat flux depends on R/sub i/, Rc, Re, Pr, {alpha}, and the {theta} of working fluid. An experimental study on the incipience of nucleate boiling is performed as a verification ad extension of previous analyses. Through flow visualization, the results show that the most dominant parameter to affect the heat flux at ONB is found to be the surface curvature. The heat flux data at ONB increases with the Re and the subcooling, and the effect of subcooling on ONB becomes smaller with decreasing Re. The heat flux at ONB increases rapidly as increase in {alpha} due to higher convective motion of bulk flow. Comparison between both results are accomplished with respect to the relative enhancement due to the convex curvature. The relative heat transfer enhancement ratio shows a good agreement between theory and experiment qualitatively and quantitatively. In conclusion, the obtained results suggest that the effect transverse convex curvature appears significantly in the boiling heat transfer. Therefore, it can be clearly expected that the effect should be more strong at the case of critical heat flux condition which is the most important design goal of the advanced nuclear fuel rods. 30 refs., 78 figs. (Author)

  7. Advances in Forecasting and Prevention of Resonances Between Coolant Acoustical Oscillations and Fuel Rod Vibrations

    Energy Technology Data Exchange (ETDEWEB)

    Proskuryakov, Konstantin Nicolaevich [NPP, NPEI, 14, Krasnokazarmennaya str. Moscow, 111250 (Russian Federation)

    2009-06-15

    To prevent the appearance of the conditions for resonance interaction between the fluid flow and the reactor internals (RI), fuel rod (FR ) and fuel assemblies (FA) it is necessary to de-tune Eigen frequency of coolant pressure oscillations (EFCPO) and natural frequency of mechanical element's oscillations and also of the system which is formed by the comprising of these elements. Other words it is necessary to de-tune acoustic resonance frequency and natural frequencies of RI, FR and FA. While solving these problems it is necessary to have a theoretical and settlement substantiation of an oscillation frequency band of the coolant outside of which there is no resonant interaction with structure vibrations. The presented work is devoted to finding the solution of this problem. There are results of an estimation of width of such band as well as the examples of a preliminary quantitative estimation of Q - factors of coolant acoustic oscillatory circuit formed by the equipment of the NPP. Abnormal growth of intensity of pressure pulsations in a mode with definite value of reactor capacity have been found out by measurements on VVER - 1000 reactor. This phenomenon has been found out casually and its original reason had not been identified. Paper shows that disappearance of this effect could be reached by realizing outlet of EFCPO from so-called, pass bands of frequencies (PBF). PBF is located symmetrical on both parties from frequency of own oscillations of FA. Methods, algorithms of calculations and quantitative estimations are developed for EFCPO, Q and PBF in various modes of operation NPP with VVER-1000. Results of calculations allow specifying area of resonant interaction EFCPO with vibrations of FR, FA and a basket of reactor core. For practical realization of the received results it is offered to make corresponding additions to the design documentation and maintenance instructions of the equipment of the NPP with VVER-1000. The improvement of these documents

  8. Microbial electricity generation in rice paddy fields: recent advances and perspectives in rhizosphere microbial fuel cells.

    Science.gov (United States)

    Kouzuma, Atsushi; Kaku, Nobuo; Watanabe, Kazuya

    2014-12-01

    Microbial fuel cells (MFCs) are devices that use living microbes for the conversion of organic matter into electricity. MFC systems can be applied to the generation of electricity at water/sediment interfaces in the environment, such as bay areas, wetlands, and rice paddy fields. Using these systems, electricity generation in paddy fields as high as ∼80 mW m(-2) (based on the projected anode area) has been demonstrated, and evidence suggests that rhizosphere microbes preferentially utilize organic exudates from rice roots for generating electricity. Phylogenetic and metagenomic analyses have been conducted to identify the microbial species and catabolic pathways that are involved in the conversion of root exudates into electricity, suggesting the importance of syntrophic interactions. In parallel, pot cultures of rice and other aquatic plants have been used for rhizosphere MFC experiments under controlled laboratory conditions. The findings from these studies have demonstrated the potential of electricity generation for mitigating methane emission from the rhizosphere. Notably, however, the presence of large amounts of organics in the rhizosphere drastically reduces the effect of electricity generation on methane production. Further studies are necessary to evaluate the potential of these systems for mitigating methane emission from rice paddy fields. We suggest that paddy-field MFCs represent a promising approach for harvesting latent energy of the natural world.

  9. Development of advanced BWR fuel bundle with spectral shift rod - BWR core characteristics with SSR

    Energy Technology Data Exchange (ETDEWEB)

    Hino, T.; Kondo, T.; Chaki, M.; Ohga, Y. [Hitachi-GE Nuclear Energy, Ltd., 1-1, Saiwai-cho, 3-chome, Hitachi-shi, Ibaraki-ken, 317-0073 (Japan); Makigami, T. [Tokyo Electric Power Company Inc., 1-1-3, Uchisaiwai-cho, Chiyoda-ku, Tokyo, 100-0011 (Japan)

    2012-07-01

    The neutron energy spectrum can be varied during an operation cycle to generate and utilize more plutonium from the non-fissile {sup 238}U by changing the void fraction in the core through control of the core coolant flow rate. This operation method, which is called a spectral shift operation, is practiced in BWRs to save natural uranium. A new component called a spectral shift rod (SSR), which is utilized instead of a conventional water rod, has been introduced to amplify the void fraction change and increase the spectral shift effect. In this study, fuel bundle design with the SSR and core design were carried out for the ABWR and the next generation BWR, HP-ABWR (High-Performance ABWR).The core characteristics with the SSR were evaluated and compared with those when using the conventional water rod. Influences of uncertainty of the water level in the SSR on the safety limit minimum critical power ratio (SLMCPR) were considered for evaluation of the uranium saving effect attained by the SSR. As a result, it was found that the amount of natural uranium needed for an operation cycle could be reduced more than 3% with 20% core coolant flow change and more than 5% with 30% core coolant flow change, in the form of increased discharge exposure by using the SSR compared with the conventional water rod use. (authors)

  10. Advanced CFD simulations of turbulent flows around appendages in CANDU fuel bundles

    Energy Technology Data Exchange (ETDEWEB)

    Abbasian, F.; Hadaller, G.I.; Fortman, R.A., E-mail: fabbasian@sternlab.com [Stern Laboratories Inc., Hamilton, Ontario (Canada)

    2013-07-01

    Computational Fluid Dynamics (CFD) was used to simulate the coolant flow in a modified 37-element CANDU fuel bundle, in order to investigate the effects of the appendages on the flow field. First, a subchannel model was created to qualitatively analyze the capabilities of different turbulence models such as k.ε, Reynolds Normalization Group (RNG), Shear Stress Transport (SST) and Large Eddy Simulation (LES). Then, the turbulence model with the acceptable quality was used to investigate the effects of positioning appendages, normally used in CANDU 37-element Critical Heat Flux (CHF) experiments, on the flow field. It was concluded that the RNG and SST models both show improvements over the k.ε method by predicting cross flow rates closer to those predicted by the LES model. Also the turbulence effects in the k.ε model dissipate quickly downstream of the appendages, while in the RNG and SST models appear at longer distances similar to the LES model. The RNG method simulation time was relatively feasible and as a result was chosen for the bundle model simulations. In the bundle model simulations it was shown that the tunnel spacers and leaf springs, used to position the bundles inside the pressure tubes in the experiments, have no measureable dominant effects on the flow field. The flow disturbances are localized and disappear at relatively short streamwise distances. (author)

  11. First-principles modelling of radiation defects in advanced nuclear fuels

    Science.gov (United States)

    Kotomin, E. A.; Gryaznov, D.; Grimes, R. W.; Parfitt, D.; Zhukovskii, Yu. F.; Mastrikov, Yu. A.; Van Uffelen, P.; Rondinella, V. V.; Konings, R. J. M.

    2008-06-01

    We present and discuss the results of the first-principles calculations of Frenkel defects and O impurities in uranium mononitride (UN) perspective for fast reactor nuclear fuels. Special attention is paid to the calculation of defect migration energies. We demonstrate that the interstitialcy mechanism (with the formation of a N-N dumbbell along the [1 1 1] axis) is energetically more favorable than the direct [1 0 0] hops. As a result, for the interstitial N ions we predict a diffusion mechanism similar to that known in isostructural fcc materials with a different chemical nature (KCl, MgO). The calculated effective N charge considerably depends on the ion position and environment (a host lattice site, interstitial or saddle point) which strongly limits the applicability of classical defect modelling based on formal invariant charges. Lastly, the calculated migration energy for the interstitial impurity O ions is quite low (2.84 eV), which indicates their high mobility and ability for reactions with other defects.

  12. Advanced thermally stable jet fuels. Technical progress report, November 1992--January 1993

    Energy Technology Data Exchange (ETDEWEB)

    Schobert, H.H.; Eser, S.; Song, C.; Hatcher, P.G.; Walsh, P.M.; Coleman, M.M.; Arumugam, R.; Bortiatynski, J.; Dutta, R.; Gergova, K.; Hou, L.; Lai, W-C.; Li, J.; McKinney, D.; Peng, Y.; Sanghani, P.; Selvaraj, L.; Sobkowiak, M.

    1993-03-01

    The pyrolysis of octylbenzene (OB) at various temperatures, 400{degrees}C, 425{degrees}C and 450{degrees}C, has been studied. This work represents a continuous effort in the study of the effects of alkylbenzenes in the high temperature thermal degradation of jet fuels, following up the detailed study of the behavior of four isomers of butylbenzenes (1). There are some general similarities in the reactions of OB and butylbenzenes. For example, both produce a large amount of smaller alkylbenzenes during pyrolysis. Reaction kinetics of OB have been calculated based on the temperature range mentioned above, and the major chemical process in its thermal reactions have been analyzed. As expected, temperature plays the most significant role in the degradation process, as shown in Figure 1. The reaction shows only a moderate rate at 400{degrees}C, 8.18 mol% of OB remaining after 16 hours of stressing. At 450{degrees}C, however, there is virtually no OB left after 8 hours of stressing. Rough comparison of the yields (wt%) of gaseous, liquid and solid products formed (Figures 2, 3 and 4) shows a uniform change in this temperature range. For example, a steady increase of the yields (wt%) of gas and solid formation can be observed in Figures 2 and 3. Global kinetics of the reaction of octylbenzene have been calculated.

  13. Advanced fuel cell development. Progress report for October--December 1978. [LiAlO/sub 2/

    Energy Technology Data Exchange (ETDEWEB)

    Finn, P A; Kinoshita, K; Kucera, G H; Sim, J W; Pierce, R D

    1979-06-01

    Advanced fuel cell research activities at Argonne National laboratory during the period of October--December 1978 are described. These efforts have been directed toward understanding and improving the components of molten--carbonate--electrolyte fuel cells operated at temperatures near 925/sup 0/K. The primary focus of this work has been the development of electrolyte structures that have good electrolyte retention and mechanical properties as well as long-term stability, and on developing methods of synthesis amendable to mass production. The characterization of these structures and their stability is an integral part of this effort. Current electrolyte structures are comprised of LiAlO/sub 2/ particles and an eutectic of Li/sub 2/CO/sub 3/ and K/sub 2/CO/sub 3/. The development of procedures for synthesizing LiAlO/sub 2/ from low cost materials is being pursued. The thermal stability of cold-pressed pellets of LiAlO/sub 2/ and carbonate eutectic has been tested at 925/sup 0/K for 22 to 2400 h in air, CO/sub 2/, and H/sub 2/--CO/sub 2/--H/sub 2/O. In general, under these test conditions the allotropic form of the LiAlO/sub 2/ particles remained stable, but their surface area decreased with time of heat treatment. Thermomechanical tests indicated that the strength of LiAlO/sub 2/ pellets increases with increased particle surface area. Several small (94 cm/sup 2/) cells have been operated in which the electrolyte tiles contained alkali carbonates and LiAlO/sub 2/, primarily the ..gamma.. allotrope. The performance of these cells was improved by using a high carbonate content (69 vol %) in the tiles and the mechanical strength of the tiles was improved by the use of a metal screen.

  14. Advancing Plug-In Hybrid Technology and Flex Fuel Application on a Chrysler Minivan

    Energy Technology Data Exchange (ETDEWEB)

    Bazzi, Abdullah [Chrysler Group LLC, Auburn Hills, MI (United States); Barnhart, Steven [Chrysler Group LLC, Auburn Hills, MI (United States)

    2014-12-31

    FCA US LLC viewed this DOE funding as a historic opportunity to begin the process of achieving required economies of scale on technologies for electric vehicles. The funding supported FCA US LLC’s light-duty electric drive vehicle and charging infrastructure-testing activities and enabled FCA US LLC to utilize the funding on advancing Plug-in Hybrid Electric Vehicle (PHEV) technologies to future programs. FCA US LLC intended to develop the next generations of electric drive and energy batteries through a properly paced convergence of standards, technology, components, and common modules, as well as first-responder training and battery recycling. To support the development of a strong, commercially viable supplier base, FCA US LLC also used this opportunity to evaluate various designated component and sub-system suppliers. The original project proposal was submitted in December 2009 and selected in January 2010. The project ended in December 2014.

  15. Battery-free Wireless Sensor Network For Advanced Fossil-Fuel Based Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    Yi Jia

    2011-02-28

    This report summarizes technical progress achieved during the project supported by the Department of Energy under Award Number DE-FG26-07NT4306. The aim of the project was to conduct basic research into battery-free wireless sensing mechanism in order to develop novel wireless sensors and sensor network for physical and chemical parameter monitoring in a harsh environment. Passive wireless sensing platform and five wireless sensors including temperature sensor, pressure sensor, humidity sensor, crack sensor and networked sensors developed and demonstrated in our laboratory setup have achieved the objective for the monitoring of various physical and chemical parameters in a harsh environment through remote power and wireless sensor communication, which is critical to intelligent control of advanced power generation system. This report is organized by the sensors developed as detailed in each progress report.

  16. DEVELOPMENT OF CERAMIC WASTE FORMS FOR AN ADVANCED NUCLEAR FUEL CYCLE

    Energy Technology Data Exchange (ETDEWEB)

    Marra, J.; Billings, A.; Brinkman, K.; Fox, K.

    2010-11-30

    A series of ceramic waste forms were developed and characterized for the immobilization of a Cesium/Lanthanide (CS/LN) waste stream anticipated to result from nuclear fuel reprocessing. Simple raw materials, including Al{sub 2}O{sub 3} and TiO{sub 2} were combined with simulated waste components to produce multiphase ceramics containing hollandite-type phases, perovskites (particularly BaTiO{sub 3}), pyrochlores and other minor metal titanate phases. Three fabrication methodologies were used, including melting and crystallizing, pressing and sintering, and Spark Plasma Sintering (SPS), with the intent of studying phase evolution under various sintering conditions. X-Ray Diffraction (XRD) and Scanning Electron Microscopy coupled with Energy Dispersive Spectroscopy (SEM/EDS) results showed that the partitioning of the waste elements in the sintered materials was very similar, despite varying stoichiometry of the phases formed. Identification of excess Al{sub 2}O{sub 3} via XRD and SEM/EDS in the first series of compositions led to a Phase II study, with significantly reduced Al{sub 2}O{sub 3} concentrations and increased waste loadings. The Phase II compositions generally contained a reduced amount of unreacted Al{sub 2}O{sub 3} as identified by XRD. Chemical composition measurements showed no significant issues with meeting the target compositions. However, volatilization of Cs and Mo was identified, particularly during melting, since sintering of the pressed pellets and SPS were performed at lower temperatures. Partitioning of some of the waste components was difficult to determine via XRD. SEM/EDS mapping showed that those elements, which were generally present in small concentrations, were well distributed throughout the waste forms.

  17. Advanced biological treatment of aqueous effluent from the nuclear fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Pitt, Jr, W W; Hancher, C W; Patton, B D; Shumate, II, S E

    1980-01-01

    Many of the processing steps in the nuclear fuel cycle generate aqueous effluent streams bearing contaminants that can, because of their chemical or radiological properties, pose an environmental hazard. Concentration of such contaminants must be reduced to acceptable levels before the streams can be discharged to the environment. Two classes of contaminants, nitrates and heavy metals, are addressed in this study. Specific techniques aimed at the removal of nitrates and radioactive heavy metals by biological processes are being developed, tested, and demonstrated. Although cost comparisons between biological processes and current treatment methods will be presented, these comparisons may be misleading because biological processes yield environmentally better end results which are difficult to price. The fluidized-bed biological denitrification process is an environmentally acceptable and economically sound method for the disposal of nonreusable sources of nitrate effluents. A very high denitrification rate can be obtained in a FBR as the result of a high concentration of denitrification bacteria in the bioreactor and the stagewise operation resulting from plug flow in the reactor. The overall denitrification rate in an FBR ranges from 20- to 100-fold greater than that observed for an STR bioreactor. It has been shown that the system can be operated using Ca/sup 2 +/, Na/sup +/, or NH/sub 4//sup +/ cations at nitrate concentrations up to 1 g/liter without inhibition. Biological sorption of uranium and other radionuclides (particularly the actinides) from dilute aqueous waste streams shows considerable promise as a means of recovering these valuable resources and reducing the environmental impact, however, further development efforts are required.

  18. Americium/Lanthanide Separations in Alkaline Solutions for Advanced Nuclear Fuel Cycles

    Energy Technology Data Exchange (ETDEWEB)

    Goff, George S. [Los Alamos National Laboratory; Long, Kristy Marie [Los Alamos National Laboratory; Reilly, Sean D. [Los Alamos National Laboratory; Jarvinen, Gordon D. [Los Alamos National Laboratory; Runde, Wolfgang H. [Los Alamos National Laboratory

    2012-06-11

    Project goals: Can used nuclear fuel be partitioned by dissolution in alkaline aqueous solution to give a solution of uranium, neptunium, plutonium, americium and curium and a filterable solid containing nearly all of the lanthanide fission products and certain other fission products? What is the chemistry of Am/Cm/Ln in oxidative carbonate solutions? Can higher oxidation states of Am be stabilized and exploited? Conclusions: Am(VI) is kinetically stable in 0.5-2.0 M carbonate solutions for hours. Aliquat 336 in toluene has been successfully shown to extract U(VI) and Pu(VI) from carbonate solutions. (Stepanov et al 2011). Higher carbonate concentration gives lower D, SF{sub U/Eu} for = 4 in 1 M K{sub 2}CO{sub 3}. Experiments with Am(VI) were unsuccessful due to reduction by the organics. Multiple sources of reducing organics...more optimization. Reduction experiments of Am(VI) in dodecane/octanol/Aliquat 336 show that after 5 minutes of contact, only 30-40% of the Am(VI) has been reduced. Long enough to perform an extraction. Shorter contact times, lower T, and lower Aliquat 336 concentration still did not result in any significant extraction of Am. Anion exchange experiments using a strong base anion exchanger show uptake of U(VI) with minimal uptake of Nd(III). Experiments with Am(VI) indicate Am sorption with a Kd of 9 (10 minute contact) but sorption mechanism is not yet understood. SF{sub U/Nd} for = 7 and SF{sub U/Eu} for = 19 after 24 hours in 1 M K{sub 2}CO{sub 3}.

  19. THE ATTRACTIVENESS OF MATERIALS IN ADVANCED NUCLEAR FUEL CYCLES FOR VARIOUS PROLIFERATION AND THEFT SCENARIOS

    Energy Technology Data Exchange (ETDEWEB)

    Bathke, C. G.; Ebbinghaus, Bartley B.; Collins, Brian A.; Sleaford, Brad W.; Hase, Kevin R.; Robel, Martin; Wallace, R. K.; Bradley, Keith S.; Ireland, J. R.; Jarvinen, G. D.; Johnson, M. W.; Prichard, Andrew W.; Smith, Brian W.

    2012-08-29

    We must anticipate that the day is approaching when details of nuclear weapons design and fabrication will become common knowledge. On that day we must be particularly certain that all special nuclear materials (SNM) are adequately accounted for and protected and that we have a clear understanding of the utility of nuclear materials to potential adversaries. To this end, this paper examines the attractiveness of materials mixtures containing SNM and alternate nuclear materials associated with the plutonium-uranium reduction extraction (Purex), uranium extraction (UREX), coextraction (COEX), thorium extraction (THOREX), and PYROX (an electrochemical refining method) reprocessing schemes. This paper provides a set of figures of merit for evaluating material attractiveness that covers a broad range of proliferant state and subnational group capabilities. The primary conclusion of this paper is that all fissile material must be rigorously safeguarded to detect diversion by a state and must be provided the highest levels of physical protection to prevent theft by subnational groups; no 'silver bullet' fuel cycle has been found that will permit the relaxation of current international safeguards or national physical security protection levels. The work reported herein has been performed at the request of the U.S. Department of Energy (DOE) and is based on the calculation of 'attractiveness levels' that are expressed in terms consistent with, but normally reserved for, the nuclear materials in DOE nuclear facilities. The methodology and findings are presented. Additionally, how these attractiveness levels relate to proliferation resistance and physical security is discussed.

  20. Propulsion and Power Rapid Response Research and Development (R&D) Support. Delivery Order 0011: Advanced Propulsion Fuels R&D Subtask: Advanced Propulsion Fuels Research and Development Support to AFRL/RQTF

    Science.gov (United States)

    2012-12-01

    aviation fuel; Fischer-Tropsch Fuel (FT); fuel certification; hydrotreated renewable jet (HRJ); iso-paraffinic kerosene (IPK); synthetic paraffinic...of Defense DTIC Defense Technical Information Center FT Fischer-Tropsch HPCR High Pressure Common Rail HRJ Hydrotreated Renewable Jet IPK Iso

  1. PRELIMINARY STUDY OF CERAMICS FOR IMMOBILIZATION OF ADVANCED FUEL CYCLE REPROCESSING WASTES

    Energy Technology Data Exchange (ETDEWEB)

    Fox, K.; Billings, A.; Brinkman, K.; Marra, J.

    2010-09-22

    The Savannah River National Laboratory (SRNL) developed a series of ceramic waste forms for the immobilization of Cesium/Lanthanide (CS/LN) and Cesium/Lanthanide/Transition Metal (CS/LN/TM) waste streams anticipated to result from nuclear fuel reprocessing. Simple raw materials, including Al{sub 2}O{sub 3}, CaO, and TiO{sub 2} were combined with simulated waste components to produce multiphase ceramics containing hollandite-type phases, perovskites (particularly BaTiO{sub 3}), pyrochlores, zirconolite, and other minor metal titanate phases. Identification of excess Al{sub 2}O{sub 3} via X-ray Diffraction (XRD) and Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM/EDS) in the first series of compositions led to a Phase II study, with significantly reduced Al{sub 2}O{sub 3} concentrations and increased waste loadings. Three fabrication methodologies were used, including melting and crystallizing, pressing and sintering, and Spark Plasma Sintering (SPS), with the intent of studying phase evolution under various sintering conditions. XRD and SEM/EDS results showed that the partitioning of the waste elements in the sintered materials was very similar, despite varying stoichiometry of the phases formed. The Phase II compositions generally contained a reduced amount of unreacted Al{sub 2}O{sub 3} as identified by XRD, and had phase assemblages that were closer to the initial targets. Chemical composition measurements showed no significant issues with meeting the target compositions. However, volatilization of Cs and Mo was identified, particularly during melting, since sintering of the pressed pellets and SPS were performed at lower temperatures. Partitioning of some of the waste components was difficult to determine via XRD. SEM/EDS mapping showed that those elements, which were generally present in small concentrations, were well distributed throughout the waste forms. Initial studies of radiation damage tolerance using ion beam irradiation at Los

  2. Advanced ODS FeCrAl alloys for accident-tolerant fuel cladding

    Energy Technology Data Exchange (ETDEWEB)

    Dryepondt, Sebastien N [ORNL; Unocic, Kinga A [ORNL; Hoelzer, David T [ORNL; Pint, Bruce A [ORNL

    2014-09-01

    ODS FeCrAl alloys are being developed with optimum composition and properties for accident tolerant fuel cladding. Two oxide dispersion strengthened (ODS) Fe-15Cr-5Al+Y2O3 alloys were fabricated by ball milling and extrusion of gas atomized metallic powder mixed with Y2O3 powder. To assess the impact of Mo on the alloy mechanical properties, one alloy contained 1%Mo. The hardness and tensile properties of the two alloys were close and higher than the values reported for fine grain PM2000 alloy. This is likely due to the combination of a very fine grain structure and the presence of nano oxide precipitates. The nano oxide dispersion was however not sufficient to prevent grain boundary sliding at 800 C and the creep properties of the alloys were similar or only slightly superior to fine grain PM2000 alloy. Both alloys formed a protective alumina scale at 1200 C in air and steam and the mass gain curves were similar to curves generated with 12Cr-5Al+Y2O3 (+Hf or Zr) ODS alloys fabricated for a different project. To estimate the maximum temperature limit of use for the two alloys in steam, ramp tests at a rate of 5 C/min were carried out in steam. Like other ODS alloys, the two alloys showed a significant increase of the mas gains at T~ 1380 C compared with ~1480 C for wrought alloys of similar composition. The beneficial effect of Yttrium for wrought FeCrAl does not seem effective for most ODS FeCrAl alloys. Characterization of the hardness of annealed specimens revealed that the microstructure of the two alloys was not stable above 1000 C. Concurrent radiation results suggested that Cr levels <15wt% are desirable and the creep and oxidation results from the 12Cr ODS alloys indicate that a lower Cr, high strength ODS alloy with a higher maximum use temperature could be achieved.

  3. Lightweighting Automotive Materials for Increased Fuel Efficiency and Delivering Advanced Modeling and Simulation Capabilities to U.S. Manufacturers

    Energy Technology Data Exchange (ETDEWEB)

    Hale, Steve

    2013-09-11

    Abstract The National Center for Manufacturing Sciences (NCMS) worked with the U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL), to bring together research and development (R&D) collaborations to develop and accelerate the knowledgebase and infrastructure for lightweighting materials and manufacturing processes for their use in structural and applications in the automotive sector. The purpose/importance of this DOE program: • 2016 CAFÉ standards. • Automotive industry technology that shall adopt the insertion of lightweighting material concepts towards manufacturing of production vehicles. • Development and manufacture of advanced research tools for modeling and simulation (M&S) applications to reduce manufacturing and material costs. • U.S. competitiveness that will help drive the development and manufacture of the next generation of materials. NCMS established a focused portfolio of applied R&D projects utilizing lightweighting materials for manufacture into automotive structures and components. Areas that were targeted in this program: • Functionality of new lightweighting materials to meet present safety requirements. • Manufacturability using new lightweighting materials. • Cost reduction for the development and use of new lightweighting materials. The automotive industry’s future continuously evolves through innovation, and lightweight materials are key in achieving a new era of lighter, more efficient vehicles. Lightweight materials are among the technical advances needed to achieve fuel/energy efficiency and reduce carbon dioxide (CO2) emissions: • Establish design criteria methodology to identify the best materials for lightweighting. • Employ state-of-the-art design tools for optimum material development for their specific applications. • Match new manufacturing technology to production volume. • Address new process variability with new production-ready processes.

  4. 76 FR 80832 - Fire Pots and Gel Fuel; Advance Notice of Proposed Rulemaking; Request for Comments and Information

    Science.gov (United States)

    2011-12-27

    ..., the CPSC's Office of Compliance and Field Operations initiated several recalls of pourable alcohol gel... fuel. The products involved in the recalls were alcohol-based gel fuel in containers intended to be... Products The incidents discussed in this ANPR all involve firepots used with alcohol-based gel fuel....

  5. Review and comment on the advanced spent fuel management process (1): Technical aspects and non-proliferation concerns

    Energy Technology Data Exchange (ETDEWEB)

    Song, Yo Taik

    2001-01-01

    Efforts are made to analyze the project, the Advanced Spent Fuel Management Technology (ASFMT), which is currently carried out at Korea Atomic Energy Research Institute, on the technical feasibility and validity as well as on the nuclear non-proliferation concerns. The project is a part of a program under the 'Long and Midterm Nuclear Development Program'. On the technical analysis, reviewed the papers presented at the national and international meetings on the subject by KAERI staffs, and also participated to various technical discussions on the 'Mock-up Test', currently in progress. On the non-proliferation concerns, the ASFMT project was reviewed and analyzed in reference to various programs currently in progress or in a formulation stages in US, such as the DOE TOPS and ATW. Further reviewed the past JASNEC process and programs for possible application of the ASFMT project for JASNEC project. Provided a few thoughts for effectively carrying out the ASFMT project, and a plan for the next phase is presented.

  6. On the extension of modern best-estimate plus uncertainy methodologies to future fast reactor and advanced fuel licensing - initial evaluation of issues

    Energy Technology Data Exchange (ETDEWEB)

    Unal, Cetin [Los Alamos National Laboratory; Mcclure, Patrick R [Los Alamos National Laboratory

    2009-01-01

    Closing the fuel cycle is the major technical challenge to expanding nuclear energy to meet the world's need for benign, environmentally safe electrical power. Closing the fuel cycle means getting the maximum amount of energy possible out of uranium fuel while in turn minimizing the amount of high-level waste that must be stored. DOE's Advance Fuel Cycle Initiative (AFCI) program addresses this challenge by recycling the transuranic (TRU) isotopes contained in spent nuclear fuel; recycling, in turn, minimizes the amount of high-level waste that would require storage in repositories. Developing new fuels and the plants that burn them is a lengthy and expensive process, typically spanning a period of two decades from concept to final licensing. A unique challenge to meeting the AFCI objectives in this area is that the experimental database is seriously incomplete. As such, using a traditional, heavily empirical approach to develop and qualify fuels and plant operation over the operational conditions of a AFCI plant will be very challenging, if not impossible, within the expected schedule and budgetary constraints. To address this concern AFCI has launched an advanced modeling and simulation (M&S) approach to revolutionize fuel development and fast reactor design. This new approach is predicated upon transferring the recent advances in computational sciences and computer technologies into the development of these program elements. The licensing process that has historically been used by the NRC for fuels qualification is based upon using a large body of experimental work to qualify and license a new fuel. If a modeling and simulation approach with more directed experimentation is to be considered as an alternative approach for licensing, then a framework needs to be developed that can be agreed to with the NRC early in the developmental process. The use of modeling and simulation as a means of demonstrating that a design can meet NRC requirements is not new

  7. Reactor physics studies for the Advanced Fuel Cycle Initiative (AFCI) Reactor-Accelerator Coupling Experiments (RACE) Project

    Science.gov (United States)

    Stankovskiy, Evgeny Yuryevich

    In the recently completed RACE Project of the AFCI, accelerator-driven subcritical systems (ADS) experiments were conducted to develop technology of coupling accelerators to nuclear reactors. In these experiments electron accelerators induced photon-neutron reactions in heavy-metal targets to initiate fission reactions in ADS. Although the Idaho State University (ISU) RACE ADS was constructed only to develop measurement techniques for advanced experiments, many reactor kinetics experiments were conducted there. In the research reported in this dissertation, a method was developed to calculate kinetics parameters for measurement and calculation of the reactivity of ADS, a safety parameter that is necessary for control and monitoring of power production. Reactivity is measured in units of fraction of delayed versus prompt neutron from fission, a quantity that cannot be directly measured in far-subcritical reactors such as the ISU RACE configuration. A new technique is reported herein to calculate it accurately and to predict kinetic behavior of a far-subcritical ADS. Experiments conducted at ISU are first described and experimental data are presented before development of the kinetic theory used in the new computational method. Because of the complexity of the ISU ADS, the Monte-Carlo method as applied in the MCNP code is most suitable for modeling reactor kinetics. However, the standard method of calculating the delayed neutron fraction produces inaccurate values. A new method was developed and used herein to evaluate actual experiments. An advantage of this method is that its efficiency is independent of the fission yield of delayed neutrons, which makes it suitable for fuel with a minor actinide component (e.g. transmutation fuels). The implementation of this method is based on a correlated sampling technique which allows the accurate evaluation of delayed and prompt neutrons. The validity of the obtained results is indicated by good agreement between experimental

  8. Outlook for alternative energy sources. [aviation fuels

    Science.gov (United States)

    Card, M. E.

    1980-01-01

    Predictions are made concerning the development of alternative energy sources in the light of the present national energy situation. Particular emphasis is given to the impact of alternative fuels development on aviation fuels. The future outlook for aircraft fuels is that for the near term, there possibly will be no major fuel changes, but minor specification changes may be possible if supplies decrease. In the midterm, a broad cut fuel may be used if current development efforts are successful. As synfuel production levels increase beyond the 1990's there may be some mixtures of petroleum-based and synfuel products with the possibility of some shale distillate and indirect coal liquefaction products near the year 2000.

  9. Experiment Safety Assurance Package for Mixed Oxide Fuel Irradiation in an Average Power Position (I-24) in the Advanced Test Reactor

    Energy Technology Data Exchange (ETDEWEB)

    J. M . Ryskamp; R. C. Howard; R. C. Pedersen; S. T. Khericha

    1998-10-01

    The Fissile Material Disposition Program Light Water Reactor Mixed Oxide Fuel Irradiation Test Project Plan details a series of test irradiations designed to investigate the use of weapons-grade plutonium in MOX fuel for light water reactors (LWR) (Cowell 1996a, Cowell 1997a, Thoms 1997a). Commercial MOX fuel has been successfully used in overseas reactors for many years; however, weapons-derived test fuel contains small amounts of gallium (about 2 parts per million). A concern exists that the gallium may migrate out of the fuel and into the clad, inducing embrittlement. For preliminary out-of-pile experiments, Wilson (1997) states that intermetallic compound formation is the principal interaction mechanism between zircaloy cladding and gallium. This interaction is very limited by the low mass of gallium, so problems are not expected with the zircaloy cladding, but an in-pile experiment is needed to confirm the out-of-pile experiments. Ryskamp (1998) provides an overview of this experiment and its documentation. The purpose of this Experiment Safety Assurance Package (ESAP) is to demonstrate the safe irradiation and handling of the mixed uranium and plutonium oxide (MOX) Fuel Average Power Test (APT) experiment as required by Advanced Test Reactor (ATR) Technical Safety Requirement (TSR) 3.9.1 (LMITCO 1998). This ESAP addresses the specific operation of the MOX Fuel APT experiment with respect to the operating envelope for irradiation established by the Upgraded Final Safety Analysis Report (UFSAR) Lockheed Martin Idaho Technologies Company (LMITCO 1997a). Experiment handling activities are discussed herein.

  10. Advanced turbine systems program conceptual design and product development Task 8.3 - autothermal fuel reformer (ATR). Topical report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-11-01

    Autothermal fuel reforming (ATR) consists of reacting a hydrocarbon fuel such as natural gas or diesel with steam to produce a hydrogen-rich {open_quotes}reformed{close_quotes} fuel. This work has been designed to investigate the fuel reformation and the product gas combustion under gas turbine conditions. The hydrogen-rich gas has a high flammability with a wide range of combustion stability. Being lighter and more reactive than methane, the hydrogen-rich gas mixes readily with air and can be burned at low fuel/air ratios producing inherently low emissions. The reformed fuel also has a low ignition temperature which makes low temperature catalytic combustion possible. ATR can be designed for use with a variety of alternative fuels including heavy crudes, biomass and coal-derived fuels. When the steam required for fuel reforming is raised by using energy from the gas turbine exhaust, cycle efficiency is improved because of the steam and fuel chemically recuperating. Reformation of natural gas or diesel fuels to a homogeneous hydrogen-rich fuel has been demonstrated. Performance tests on screening various reforming catalysts and operating conditions were conducted on a batch-tube reactor. Producing over 70 percent of hydrogen (on a dry basis) in the product stream was obtained using natural gas as a feedstock. Hydrogen concentration is seen to increase with temperature but less rapidly above 1300{degrees}F. The percent reforming increases as the steam to carbon ratio is increased. Two basic groups of reforming catalysts, nickel - and platinum-basis, have been tested for the reforming activity.

  11. Two-Dimensional Mapping of the Calculated Fission Power for the Full-Size Fuel Plate Experiment Irradiated in the Advanced Test Reactor

    Science.gov (United States)

    Chang, G. S.; Lillo, M. A.

    2009-08-01

    The National Nuclear Security Administrations (NNSA) Reduced Enrichment for Research and Test Reactors (RERTR) program assigned to the Idaho National Laboratory (INL) the responsibility of developing and demonstrating high uranium density research reactor fuel forms to enable the use of low enriched uranium (LEU) in research and test reactors around the world. A series of full-size fuel plate experiments have been proposed for irradiation testing in the center flux trap (CFT) position of the Advanced Test Reactor (ATR). These full-size fuel plate tests are designated as the AFIP tests. The AFIP nominal fuel zone is rectangular in shape having a designed length of 21.5-in (54.61-cm), width of 1.6-in (4.064-cm), and uniform thickness of 0.014-in (0.03556-cm). This gives a nominal fuel zone volume of 0.482 in3 (7.89 cm3) per fuel plate. The AFIP test assembly has two test positions. Each test position is designed to hold 2 full-size plates, for a total of 4 full-size plates per test assembly. The AFIP test plates will be irradiated at a peak surface heat flux of about 350 W/cm2 and discharged at a peak U-235 burn-up of about 70 at.%. Based on limited irradiation testing of the monolithic (U-10Mo) fuel form, it is desirable to keep the peak fuel temperature below 250°C to achieve this, it will be necessary to keep plate heat fluxes below 500 W/cm2. Due to the heavy U-235 loading and a plate width of 1.6-in (4.064-cm), the neutron self-shielding will increase the local-to-average-ratio (L2AR) fission power near the sides of the fuel plates. To demonstrate that the AFIP experiment will meet the ATR safety requirements, a very detailed 2-dimensional (2D) Y-Z fission power profile was evaluated in order to best predict the fuel plate temperature distribution. The ability to accurately predict fuel plate power and burnup are essential to both the design of the AFIP tests as well as evaluation of the irradiated fuel performance. To support this need, a detailed MCNP Y

  12. Profile and Perceptions of Biogas as Automobile Fuel : A Study of Svensk Biogas

    OpenAIRE

    Larsson, Anneli

    2008-01-01

    From an environmental- and health perspective, biogas and other biomass-based fuels have several advantages; nevertheless the majority of motorists fill their cars with petroleum-based fuels. This thesis is designed to explore the profile of biogas in relation to its perceptions. It is a study concerning the communication between the biogas producing company Svensk Biogas and their biogas users and non biogas users. To obtain a thorough understanding of the profile and perceptions of biogas a...

  13. Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications: Task 9 - Selective agglomeration Module Testing and Evaluation.

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.` Jha, M.C.

    1997-09-29

    The primary goal of this project was the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and bench-scale testing of both processes on six coals to optimize the processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by September 1997. This report summarizes the findings of all the selective agglomeration (SA) test work performed with emphasis on the results of the PDU SA Module testing. Two light hydrocarbons, heptane and pentane, were tested as agglomerants in the laboratory research program which investigated two reactor design concepts: a conventional two-stage agglomeration circuit and a unitized reactor that combined the high- and low-shear operations in one vessel. The results were used to design and build a 25 lb/hr bench-scale unit with two-stage agglomeration. The unit also included a steam stripping and condensation circuit for recovery and recycle of heptane. It was tested on six coals to determine the optimum grind and other process conditions that resulted in the recovery of about 99% of the energy while producing low ash (1-2 lb/MBtu) products. The fineness of the grind was the most important variable with the D80 (80% passing size) varying in the 12 to 68 micron range. All the clean coals could be formulated into coal-water-slurry-fuels with acceptable properties. The bench-scale results were used for the conceptual and detailed design of the PDU SA Module which was integrated with the existing grinding and dewatering circuits. The PDU was operated for about 9 months. During the first three months, the shakedown testing was performed to fine tune the operation and control of various equipment. This was followed by parametric testing, optimization/confirmatory testing, and finally a

  14. Fuel from microalgae lipid products

    Energy Technology Data Exchange (ETDEWEB)

    Hill, A.M.; Feinberg, D.A.

    1984-04-01

    The large-scale production of microalgae is a promising method of producing a renewable feedstock for a wide variety of fuel products currently refined from crude petroleum. These microalgae-derived products include lipid extraction products (triglycerides, fatty acids, and hydrocarbons) and catalytic conversion products (paraffins and olefins). Microalgal biomass productivity and lipid composition of current experimental systems are estimated at 66.0 metric tons per hectare year and 30% lipid content. Similar yields in a large-scale facility indicate that production costs are approximately six times higher than the average domestic price for crude, well-head petroleum. Based on achievable targets for productivity and production costs, the potential for microalgae as a fuel feedstock is presented in context with selected process refining routes and is compared with conventional and alternative feedstocks (e.g., oilseeds) with which microalgae must compete. 24 references, 9 figures, 4 tables.

  15. Solid Oxide Fuel Cell/Turbine Hybrid Power System for Advanced Aero-propulsion and Power Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Solid oxide fuel cell (SOFC)/ gas turbine hybrid power systems (HPSs) have been recognized by federal agencies and other entities as having the potential to operate...

  16. Advanced manufacturing of intermediate temperature, direct methane oxidation membrane electrode assemblies for durable solid oxide fuel cell Project

    Data.gov (United States)

    National Aeronautics and Space Administration — ITN proposes to create an innovative anode supported membrane electrode assembly (MEA) for solid oxide fuel cells (SOFCs) that is capable of long-term operation at...

  17. ADVANCED NUCLEAR FUEL CYCLE EFFECTS ON THE TREATMENT OF UNCERTAINTY IN THE LONG-TERM ASSESSMENT OF GEOLOGIC DISPOSAL SYSTEMS - EBS INPUT

    Energy Technology Data Exchange (ETDEWEB)

    Sutton, M; Blink, J A; Greenberg, H R; Sharma, M

    2012-04-25

    encapsulated in borosilicate glass. Because the heat load of the glass was much less than the PWR and BWR assemblies, the glass waste form was able to be co-disposed with the open cycle waste, by interspersing glass waste packages among the spent fuel assembly waste packages. In addition, the Yucca Mountain repository was designed to include some research reactor spent fuel and naval reactor spent fuel, within the envelope that was set using the commercial reactor assemblies as the design basis waste form. This milestone report supports Sandia National Laboratory milestone M2FT-12SN0814052, and is intended to be a chapter in that milestone report. The independent technical review of this LLNL milestone was performed at LLNL and is documented in the electronic Information Management (IM) system at LLNL. The objective of this work is to investigate what aspects of quantifying, characterizing, and representing the uncertainty associated with the engineered barrier are affected by implementing different advanced nuclear fuel cycles (e.g., partitioning and transmutation scenarios) together with corresponding designs and thermal constraints.

  18. An analysis of harmful factors to storage stability of the reduced metallic fuel produced by the advanced spent fuel management process

    Energy Technology Data Exchange (ETDEWEB)

    Ju, J. S.; You, G. S.; Cho, I. J.; Kook, D. H.; Lee, J. C.; Seo, G. S.; Lee, E. P.; Seo, H. S. [Korea Atomic Energy Research Institute, Taejeon (Korea)

    2002-03-01

    This study was performed for the selection of alloying elements to make the metallic fuel alloys having a good stability to oxidation. Harmful factors on oxidation were also analyzed. Several basic properties such as microstructure, immiscibility, thermal and fission product effects were surveyed. The oxidation properties of metal uranium and uranium alloys were also studied. The results from this study are applicable to the selection of the alloying elements to stabilize the reduced uranium metal in the 2nd year research in phase 2, and also do an important role to increase the storage temperature. 29 refs., 37 figs., 5 tabs. (Author)

  19. Prototype Demonstration of Gamma- Blind Tensioned Metastable Fluid Neutron/Multiplicity/Alpha Detector – Real Time Methods for Advanced Fuel Cycle Applications

    Energy Technology Data Exchange (ETDEWEB)

    McDeavitt, Sean M. [Texas A & M Univ., College Station, TX (United States)

    2016-12-20

    The content of this report summarizes a multi-year effort to develop prototype detection equipment using the Tensioned Metastable Fluid Detector (TMFD) technology developed by Taleyarkhan [1]. The context of this development effort was to create new methods for evaluating and developing advanced methods for safeguarding nuclear materials along with instrumentation in various stages of the fuel cycle, especially in material balance areas (MBAs) and during reprocessing of used nuclear fuel. One of the challenges related to the implementation of any type of MBA and/or reprocessing technology (e.g., PUREX or UREX) is the real-time quantification and control of the transuranic (TRU) isotopes as they move through the process. Monitoring of higher actinides from their neutron emission (including multiplicity) and alpha signatures during transit in MBAs and in aqueous separations is a critical research area. By providing on-line real-time materials accountability, diversion of the materials becomes much more difficult. The Tensioned Metastable Fluid Detector (TMFD) is a transformational technology that is uniquely capable of both alpha and neutron spectroscopy while being “blind” to the intense gamma field that typically accompanies used fuel – simultaneously with the ability to provide multiplicity information as well [1-3]. The TMFD technology was proven (lab-scale) as part of a 2008 NERI-C program [1-7]. The bulk of this report describes the advancements and demonstrations made in TMFD technology. One final point to present before turning to the TMFD demonstrations is the context for discussing real-time monitoring of SNM. It is useful to review the spectrum of isotopes generated within nuclear fuel during reactor operations. Used nuclear fuel (UNF) from a light water reactor (LWR) contains fission products as well as TRU elements formed through neutron absorption/decay chains. The majority of the fission products are gamma and beta emitters and they represent the

  20. Laminar Burning Velocities of Fuels for Advanced Combustion Engines (FACE) Gasoline and Gasoline Surrogates with and without Ethanol Blending Associated with Octane Rating

    KAUST Repository

    Mannaa, Ossama A.

    2016-05-04

    Laminar burning velocities of fuels for advanced combustion engines (FACE) C gasoline and of several blends of surrogate toluene reference fuels (TRFs) (n-heptane, iso-octane, and toluene mixtures) of the same research octane number are presented. Effects of ethanol addition on laminar flame speed of FACE-C and its surrogate are addressed. Measurements were conducted using a constant volume spherical combustion vessel in the constant pressure, stable flame regime at an initial temperature of 358 K and initial pressures up to 0.6 MPa with the equivalence ratios ranging from 0.8 to 1.6. Comparable values in the laminar burning velocities were measured for the FACE-C gasoline and the proposed surrogate fuel (17.60% n-heptane + 77.40% iso-octane + 5% toluene) over the range of experimental conditions. Sensitivity of flame propagation to total stretch rate effects and thermo-diffusive instability was quantified by determining Markstein length. Two percentages of an oxygenated fuel of ethanol as an additive, namely, 60 vol% and 85 vol% were investigated. The addition of ethanol to FACE-C and its surrogate TRF-1 (17.60% n-heptane + 77.40% iso-octane + 5% toluene) resulted in a relatively similar increase in the laminar burning velocities. The high-pressure measured values of Markstein length for the studied fuels blended with ethanol showed minimal influence of ethanol addition on the flame’s response to stretch rate and thermo-diffusive instability. © 2016 Taylor & Francis.

  1. Monolithic solid oxide fuel cell technology advancement for coal-based power generation. Quarterly technical status report, January--March 1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-14

    The program is conducted by a team consisting of AiResearch Los Angeles Division of Allied-Signal Aerospace Company and Argonne National Laboratory (ANL). The objective of the program is to advance materials and fabrication methodologies to develop a monolithic solid oxide fuel cell (MSOFC) system capable of meeting performance, life, and cost goals for coal-based power generation. The program focuses on materials research and development, fabrication process development, cell/stack performance testing and characterization, cost and system analysis, and quality development.

  2. Gd/sub 2/O/sub 3/ up to 9 weight percent, an established burnable poison for advanced fuel management in pressurized water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Boehm, W.; Kiehlmann, H.D.; Neufert, A.; Peehs, M.

    1987-07-01

    High weight percent Gd/sub 2/O/sub 3/ has given excellent results when applied as burnable poison in pressurized water reactors for advanced fuel management tasks. Poisoning of up to 9 weight% Gd/sub 2/O/sub 3/ has been implemented in commercial reload cores to match the requirements of full low leakage loading and cycle extension strategies. Operational performance has confirmed that the high degree of accuracy achieved for calculational methods for standard loading applications also applies for highly Gd poisoned cores. The UO/sub 2/-Gd/sub 2/O/sub 3/ fabrication process has been rationalized by the use of direct pelletizing.

  3. A Review of Thorium Utilization as an option for Advanced Fuel Cycle--Potential Option for Brazil in the Future

    Energy Technology Data Exchange (ETDEWEB)

    Maiorino, J.R.; Carluccio, T.

    2004-10-03

    Since the beginning of Nuclear Energy Development, Thorium was considered as a potential fuel, mainly due to the potential to produce fissile uranium 233. Several Th/U fuel cycles, using thermal and fast reactors were proposed, such as the Radkwoski once through fuel cycle for PWR and VVER, the thorium fuel cycles for CANDU Reactors, the utilization in Molten Salt Reactors, the utilization of thorium in thermal (AHWR), and fast reactors (FBTR) in India, and more recently in innovative reactors, mainly Accelerator Driven System, in a double strata fuel cycle. All these concepts besides the increase in natural nuclear resources are justified by non proliferation issues (plutonium constrain) and the waste radiological toxicity reduction. The paper intended to summarize these developments, with an emphasis in the Th/U double strata fuel cycle using ADS. Brazil has one of the biggest natural reserves of thorium, estimated in 1.2 millions of tons of ThO{sub 2}, as will be reviewed in this paper, and therefore R&D programs would be of strategically national interest. In fact, in the past there was some projects to utilize Thorium in Reactors, as the ''Instinto/Toruna'' Project, in cooperation with France, to utilize Thorium in Pressurized Heavy Water Reactor, in the mid of sixties to mid of seventies, and the thorium utilization in PWR, in cooperation with German, from 1979-1988. The paper will review these initiatives in Brazil, and will propose to continue in Brazil activities related with Th/U fuel cycle.

  4. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler

  5. Life-cycle analysis of alternative aviation fuels in GREET

    Energy Technology Data Exchange (ETDEWEB)

    Elgowainy, A.; Han, J.; Wang, M.; Carter, N.; Stratton, R.; Hileman, J.; Malwitz, A.; Balasubramanian, S. (Energy Systems)

    2012-07-23

    The Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, developed at Argonne National Laboratory, has been expanded to include well-to-wake (WTWa) analysis of aviation fuels and aircraft. This report documents the key WTWa stages and assumptions for fuels that represent alternatives to petroleum jet fuel. The aviation module in GREET consists of three spreadsheets that present detailed characterizations of well-to-pump and pump-to-wake parameters and WTWa results. By using the expanded GREET version (GREET1{_}2011), we estimate WTWa results for energy use (total, fossil, and petroleum energy) and greenhouse gas (GHG) emissions (carbon dioxide, methane, and nitrous oxide) for (1) each unit of energy (lower heating value) consumed by the aircraft or (2) each unit of distance traveled/ payload carried by the aircraft. The fuel pathways considered in this analysis include petroleum-based jet fuel from conventional and unconventional sources (i.e., oil sands); Fisher-Tropsch (FT) jet fuel from natural gas, coal, and biomass; bio-jet fuel from fast pyrolysis of cellulosic biomass; and bio-jet fuel from vegetable and algal oils, which falls under the American Society for Testing and Materials category of hydroprocessed esters and fatty acids. For aircraft operation, we considered six passenger aircraft classes and four freight aircraft classes in this analysis. Our analysis revealed that, depending on the feedstock source, the fuel conversion technology, and the allocation or displacement credit methodology applied to co-products, alternative bio-jet fuel pathways have the potential to reduce life-cycle GHG emissions by 55-85 percent compared with conventional (petroleum-based) jet fuel. Although producing FT jet fuel from fossil feedstock sources - such as natural gas and coal - could greatly reduce dependence on crude oil, production from such sources (especially coal) produces greater WTWa GHG emissions compared with petroleum jet

  6. Life-Cycle Analysis of Alternative Aviation Fuels in GREET

    Energy Technology Data Exchange (ETDEWEB)

    Elgowainy, A. [Argonne National Lab. (ANL), Argonne, IL (United States); Han, J. [Argonne National Lab. (ANL), Argonne, IL (United States); Wang, M. [Argonne National Lab. (ANL), Argonne, IL (United States); Carter, N. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Stratton, R. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Hileman, J. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Malwitz, A. [Volpe National Transportation Systems Center, Cambridge, MA (United States); Balasubramanian, S. [Volpe National Transportation Systems Center, Cambridge, MA (United States)

    2012-06-01

    The Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, developed at Argonne National Laboratory, has been expanded to include well-to-wake (WTWa) analysis of aviation fuels and aircraft. This report documents the key WTWa stages and assumptions for fuels that represent alternatives to petroleum jet fuel. The aviation module in GREET consists of three spreadsheets that present detailed characterizations of well-to-pump and pump-to-wake parameters and WTWa results. By using the expanded GREET version (GREET1_2011), we estimate WTWa results for energy use (total, fossil, and petroleum energy) and greenhouse gas (GHG) emissions (carbon dioxide, methane, and nitrous oxide) for (1) each unit of energy (lower heating value) consumed by the aircraft or(2) each unit of distance traveled/ payload carried by the aircraft. The fuel pathways considered in this analysis include petroleum-based jet fuel from conventional and unconventional sources (i.e., oil sands); Fisher-Tropsch (FT) jet fuel from natural gas, coal, and biomass; bio-jet fuel from fast pyrolysis of cellulosic biomass; and bio-jet fuel from vegetable and algal oils, which falls under the American Society for Testing and Materials category of hydroprocessed esters and fatty acids. For aircraft operation, we considered six passenger aircraft classes and four freight aircraft classes in this analysis. Our analysis revealed that, depending on the feedstock source, the fuel conversion technology, and the allocation or displacement credit methodology applied to co-products, alternative bio-jet fuel pathways have the potential to reduce life-cycle GHG emissions by 55–85 percent compared with conventional (petroleum-based) jet fuel. Although producing FT jet fuel from fossil feedstock sources — such as natural gas and coal — could greatly reduce dependence on crude oil, production from such sources (especially coal) produces greater WTWa GHG emissions compared with petroleum jet

  7. Process modeling and supply chain design for advanced biofuel production based on bio-oil gasification

    Science.gov (United States)

    Li, Qi

    As a potential substitute for petroleum-based fuel, second generation biofuels are playing an increasingly important role due to their economic, environmental, and social benefits. With the rapid development of biofuel industry, there has been an increasing literature on the techno-economic analysis and supply chain design for biofuel production based on a variety of production pathways. A recently proposed production pathway of advanced biofuel is to convert biomass to bio-oil at widely distributed small-scale fast pyrolysis plants, then gasify the bio-oil to syngas and upgrade the syngas to transportation fuels in centralized biorefinery. This thesis aims to investigate two types of assessments on this bio-oil gasification pathway: techno-economic analysis based on process modeling and literature data; supply chain design with a focus on optimal decisions for number of facilities to build, facility capacities and logistic decisions considering uncertainties. A detailed process modeling with corn stover as feedstock and liquid fuels as the final products is presented. Techno-economic analysis of the bio-oil gasification pathway is also discussed to assess the economic feasibility. Some preliminary results show a capital investment of 438 million dollar and minimum fuel selling price (MSP) of $5.6 per gallon of gasoline equivalent. The sensitivity analysis finds that MSP is most sensitive to internal rate of return (IRR), biomass feedstock cost, and fixed capital cost. A two-stage stochastic programming is formulated to solve the supply chain design problem considering uncertainties in biomass availability, technology advancement, and biofuel price. The first-stage makes the capital investment decisions including the locations and capacities of the decentralized fast pyrolysis plants and the centralized biorefinery while the second-stage determines the biomass and biofuel flows. The numerical results and case study illustrate that considering uncertainties can be

  8. Possible incorporation of petroleum-based carbons in biochemicals produced by bioprocess--biomass carbon ratio measured by accelerator mass spectrometry.

    Science.gov (United States)

    Kunioka, Masao

    2010-06-01

    The biomass carbon ratios of biochemicals related to biomass have been reviewed. Commercial products from biomass were explained. The biomass carbon ratios of biochemical compounds were measured by accelerator mass spectrometry (AMS) based on the (14)C concentration of carbons in the compounds. This measuring method uses the mechanism that biomass carbons include a very low level of (14)C and petroleum carbons do not include (14)C similar to the carbon dating measuring method. It was confirmed that there were some biochemicals synthesized from petroleum-based carbons. This AMS method has a high accuracy with a small standard deviation and can be applied to plastic products.

  9. Subtask 6: Recommended practices for powder characterization. IEA Programme on Advanced Fuel Cells, Annex 2: Modelling and evaluation of Solid Oxide Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Van Heuveln, F.H.; Huijsmans, J.P.P. [eds.

    1992-08-01

    Powders, or precursors of powders, for the fabrication of Solid Oxide Fuel Cell (SOFC) anode-, cathode-, electrolyte- and ceramic interconnect structures are the relevant products to be evaluated. The aim is to provide a standard set of powder properties which have to be measured according to recommended methods and measurement conditions. The set is based on the results of a round robin test for electrolyte powder between five laboratories. The selected powder properties to be measured are chemical composition, phase composition, specific surface, particle size distribution, particle shape, sinterability, powder density, and flowability. The laboratories involved are Cookson Group (United Kingdom), Eniricerche (Italy), Senter for Industriforskning (Norway), Alusuisse/Lonza (Switzerland), and the Netherlands Energy Research Foundation. 2 app., 8 refs.

  10. Effect of Fuel Wobbe Number on Pollutant Emissions from Advanced Technology Residential Water Heaters: Results of Controlled Experiments

    Energy Technology Data Exchange (ETDEWEB)

    Rapp, Vi H.; Singer, Brett C.

    2014-03-01

    The research summarized in this report is part of a larger effort to evaluate the potential air quality impacts of using liquefied natural gas in California. A difference of potential importance between many liquefied natural gas blends and the natural gas blends that have been distributed in California in recent years is the higher Wobbe number of liquefied natural gas. Wobbe number is a measure of the energy delivery rate for appliances that use orifice- or pressure-based fuel metering. The effect of Wobbe number on pollutant emissions from residential water heaters was evaluated in controlled experiments. Experiments were conducted on eight storage water heaters, including five with “ultra low-NO{sub X}” burners, and four on-demand (tankless) water heaters, all of which featured ultra low-NO{sub X} burners. Pollutant emissions were quantified as air-free concentrations in the appliance flue and fuel-based emission factors in units of nanogram of pollutant emitter per joule of fuel energy consumed. Emissions were measured for carbon monoxide (CO), nitrogen oxides (NO{sub X}), nitrogen oxide (NO), formaldehyde and acetaldehyde as the water heaters were operated through defined operating cycles using fuels with varying Wobbe number. The reference fuel was Northern California line gas with Wobbe number ranging from 1344 to 1365. Test fuels had Wobbe numbers of 1360, 1390 and 1420. The most prominent finding was an increase in NO{sub X} emissions with increasing Wobbe number: all five of the ultra low-NO{sub X} storage water heaters and two of the four ultra low-NO{sub X} on-demand water heaters had statistically discernible (p<0.10) increases in NO{sub X} with fuel Wobbe number. The largest percentage increases occurred for the ultra low-NO{sub X} water heaters. There was a discernible change in CO emissions with Wobbe number for all four of the on-demand devices tested. The on-demand water heater with the highest CO emissions also had the largest CO increase

  11. Bio-fuels for the gas turbine: A review

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, K.K. [Mechanical Engineering Department, Medi-Caps Institute of Technology and Management, Pigdamber, Rau, Indore (M.P.) (India); Rehman, A.; Sarviya, R.M. [Department of Mechanical Engineering, MANIT, Bhopal (M.P.) (India)

    2010-12-15

    Due to depletion of fossil fuel, bio-fuels have generated a significant interest as an alternative fuel for the future. The use of bio-fuels to fuel gas turbine seems a viable solution for the problems of decreasing fossil-fuel reserves and environmental concerns. Bio-fuels are alternative fuels, made from renewable sources and having environmental benefit. In recent years, the desire for energy independence, foreseen depletion of nonrenewable fuel resources, fluctuating petroleum fuel costs, the necessity of stimulating agriculture based economy, and the reality of climate change have created an interest in the development of bio-fuels. The application of bio-fuels in automobiles and heating applications is increasing day by day. Therefore the use of these fuels in gas turbines would extend this application to aviation field. The impact of costly petroleum-based aviation fuel on the environment is harmful. So the development of alternative fuels in aviation is important and useful. The use of liquid and gaseous fuels from biomass will help to fulfill the Kyoto targets concerning global warming emissions. In addition, to reduce exhaust emission waste gases and syngas, etc., could be used as a potential gas turbine fuel. The term bio-fuel is referred to alternative fuel which is produced from biomass. Such fuels include bio-diesel, bio-ethanol, bio-methanol, pyrolysis oil, biogas, synthetic gas (dimethyl ether), hydrogen, etc. The bio-ethanol and bio-methanol are petrol additive/substitute. Bio-diesel is an environment friendly alternative liquid fuel for the diesel/aviation fuel. The gas turbine develops steady flame during its combustion; this feature gives a flexibility to use alternative fuels. Therefore so the use of different bio-fuels in gas turbine has been investigated by a good number of researchers. The suitability and modifications in the existing systems are also recommended. (author)

  12. Advanced fuel cell development. Progress report, October--December 1977. [LiAlO/sub 2/ matrix for molten carbonate electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Ackerman, J.P.; Kinoshita, K.; Finn, P.A.; Sim, J.W.; Nelson, P.A.

    1978-03-01

    Advanced fuel cell research and development activities in Argonne National Laboratory (ANL) during the period October to December 1977 are described. This work has been aimed at understanding and improving the performance of fuel cells having molten alkali-carbonate mixtures as electrolytes; the fuel cells operate at temperatures near 925/sup 0/K. The largest part of this effort has been directed toward development of methods for fabricating and evaluating electrolyte structures for these cells. Cell performance, life, and cost are the criteria of optimization. During this quarter, the desirable physical characteristics of LiAlO/sub 2/ particles, which act to retain the molten carbonates in the electrolyte structure of the cell, have been more clearly defined; a low temperature synthesis of the stable ..gamma..-allotrope of LiAlO/sub 2/ has been devised; an extensive study of LiAlO/sub 2/ stability has begun; and analytical methods have been refined for separating LiAlO/sub 2/, in unaltered form, from carbonates. Testing of various electrolyte structures and other components in 7-cm-dia round cells has provided a means for evaluating new electrolyte developments and verifying a previously developed method for protecting the wet-seal areas of a cell from corrosion.

  13. Report on the workshop "Decay spectroscopy at CARIBU: advanced fuel cycle applications, nuclear structure and astrophysics". 14-16 April 2011, Argonne National Laboratory, USA.

    Energy Technology Data Exchange (ETDEWEB)

    Kondev, F.; Carpenter, M.P.; Chowdhury, P.; Clark, J.A.; Lister, C.J.; Nichols, A.L.; Swewryniak, D. (Nuclear Engineering Division); (Univ. of Massachusetts); (Univ. of Surrey)

    2011-10-06

    A workshop on 'Decay Spectroscopy at CARIBU: Advanced Fuel Cycle Applications, Nuclear Structure and Astrophysics' will be held at Argonne National Laboratory on April 14-16, 2011. The aim of the workshop is to discuss opportunities for decay studies at the Californium Rare Isotope Breeder Upgrade (CARIBU) of the ATLAS facility with emphasis on advanced fuel cycle (AFC) applications, nuclear structure and astrophysics research. The workshop will consist of review and contributed talks. Presentations by members of the local groups, outlining the status of relevant in-house projects and availabile equipment, will also be organized. time will also be set aside to discuss and develop working collaborations for future decay studies at CARIBU. Topics of interest include: (1) Decay data of relevance to AFC applications with emphasis on reactor decay heat; (2) Discrete high-resolution gamma-ray spectroscopy following radioactive decya and related topics; (3) Calorimetric studies of neutron-rich fission framgents using Total ABsorption Gamma-Ray Spectrometry (TAGS) technique; (4) Beta-delayed neutron emissions and related topics; and (5) Decay data needs for nuclear astrophysics.

  14. 1990 fuel cell seminar: Program and abstracts

    Energy Technology Data Exchange (ETDEWEB)

    1990-12-31

    This volume contains author prepared short resumes of the presentations at the 1990 Fuel Cell Seminar held November 25-28, 1990 in Phoenix, Arizona. Contained herein are 134 short descriptions organized into topic areas entitled An Environmental Overview, Transportation Applications, Technology Advancements for Molten Carbonate Fuel Cells, Technology Advancements for Solid Fuel Cells, Component Technologies and Systems Analysis, Stationary Power Applications, Marine and Space Applications, Technology Advancements for Acid Type Fuel Cells, and Technology Advancement for Solid Oxide Fuel Cells.

  15. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 2 -- Jointly sponsored research program. Final report, October 1986--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Smith, V.E.

    1994-09-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  16. Alternative Fuels Data Center

    Energy Technology Data Exchange (ETDEWEB)

    None

    2013-06-01

    Fact sheet describes the Alternative Fuels Data Center, which provides information, data, and tools to help fleets and other transportation decision makers find ways to reduce petroleum consumption through the use of alternative and renewable fuels, advanced vehicles, and other fuel-saving measures.

  17. FY2016 Ceramic Fuels Development Annual Highlights

    Energy Technology Data Exchange (ETDEWEB)

    Mcclellan, Kenneth James [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-01-24

    Key challenges for the Advanced Fuels Campaign are the development of fuel technologies to enable major increases in fuel performance (safety, reliability, power and burnup) beyond current technologies, and development of characterization methods and predictive fuel performance models to enable more efficient development and licensing of advanced fuels. Ceramic fuel development activities for fiscal year 2016 fell within the areas of 1) National and International Technical Integration, 2) Advanced Accident Tolerant Ceramic Fuel Development, 3) Advanced Techniques and Reference Materials Development, and 4) Fabrication of Enriched Ceramic Fuels. High uranium density fuels were the focus of the ceramic fuels efforts. Accomplishments for FY16 primarily reflect the prioritization of identification and assessment of new ceramic fuels for light water reactors which have enhanced accident tolerance while also maintaining or improving normal operation performance, and exploration of advanced post irradiation examination techniques which will support more efficient testing and qualification of new fuel systems.

  18. FY2015 ceramic fuels development annual highlights

    Energy Technology Data Exchange (ETDEWEB)

    Mcclellan, Kenneth James [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

    2015-09-22

    Key challenges for the Advanced Fuels Campaign are the development of fuel technologies to enable major increases in fuel performance (safety, reliability, power and burnup) beyond current technologies, and development of characterization methods and predictive fuel performance models to enable more efficient development and licensing of advanced fuels. Ceramic fuel development activities for fiscal year 2015 fell within the areas of 1) National and International Technical Integration, 2) Advanced Accident Tolerant Ceramic Fuel Development, 3) Advanced Techniques and Reference Materials Development, and 4) Fabrication of Enriched Ceramic Fuels. High uranium density fuels were the focus of the ceramic fuels efforts. Accomplishments for FY15 primarily reflect the prioritization of identification and assessment of new ceramic fuels for light water reactors which have enhanced accident tolerance while also maintaining or improving normal operation performance, and exploration of advanced post irradiation examination techniques which will support more efficient testing and qualification of new fuel systems.

  19. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 12, July--September 1995

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-10-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction and operation of a 2-t/hr process development unit. The project began in October, 1992, and is scheduled for completion by June, 1997. During Quarter 12 (July--September 1995), work continued on the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at Lady Dunn. Under Subtask 4.4, additional toxic trace element analysis of column flotation samples finalized the data set. Data analysis indicates that reasonably good mass balances were achieved for most elements. The final Subtask 6.3 Selective Agglomeration Process Optimization topical report was issued this quarter. Preliminary Subtask 6.4 work investigating coal-water-fuel slurry formulation indicated that selective agglomeration products formulate slurries with lower viscosities than advanced flotation products. Work continued on Subtask 6.5 agglomeration bench-scale testing. Results indicate that a 2 lb ash/MBtu product could be produced at a 100-mesh topsize with the Elkhorn No. 3 coal. The detailed design of the 2 t/hr selective agglomeration module neared completion this quarter with the completion of additional revisions of both the process flow, and the process piping and instrument diagrams. Construction of the 2 t/hr PDU and advanced flotation module was completed this quarter and startup and shakedown testing began.

  20. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler

  1. Desulfurization of fuel oils using an advanced oxidation method; Desulfuracion de combustibles usando un metodo de oxidacion avanzada

    Energy Technology Data Exchange (ETDEWEB)

    Flores Velazquez, Roberto; Rodas Grapain, Arturo [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2008-07-01

    In the present work, the oxidative desulfurization of fuel oils assisted by ultrasound was analyzed. It was studied the effect of hydrogen peroxide concentration, the fuel oil to aqueous solution volumetric ratio, and type of catalyst. The Fenton-like catalysts studied were ferric chloride and copper sulfate. [Spanish] En esta investigacion se analiza la desulfuracion oxidativa de combustoleo asistida con ultrasonido. Tambien se estudia el efecto de la concentracion de peroxido de hidrogeno (H{sub 2}O{sub 2}), la relacion volumetrica combustoleo/solucion acuosa y el tipo de catalizador. Los catalizadores tipo Fenton que se estudiaron fueron el cloruro ferrico (FeCl{sub 3}) y el sulfato de cobre (CuSO{sub 4}).

  2. Advanced air staging techniques to improve fuel flexibility, reliability and emissions in fluidized bed co-combustion

    Energy Technology Data Exchange (ETDEWEB)

    Aamand, Lars-Erik; Leckner, Bo [Chalmers Technical Univ., Goeteborg (Sweden); Luecke, Karsten; Werther, Joachim [Technical Univ. of Hamburg-Harburg (Germany)

    2001-12-01

    A joint research project between the Technical University of Hamburg-Harburg and Chalmers Technical University. For operation under co-combustion the following results should be considered: The high ash content of the sewage sludge results in significantly increased ash flows. Although high alkali metal concentrations are found in the sewage sludge ash, no critical concentrations were reached and tendencies to fouling were not observed. The trace metal input rises with increased sludge fraction. However, emissions of metal compounds were well below legal limits. The trace metals tend to accumulate on the fly ash. In general, very low fuel nitrogen conversions to NO and N{sub 2}O of 2 - 4 % are achievable. With coal as a base fuel alternative air staging with secondary air supply after solids separation attains even lower NO emissions than normal staging without strongly affecting CO and SO{sub 2} emissions. Alternative staging also reduces N{sub 2}O emissions. An optimum for the excess air ratio in the riser of 1.05 was found for a total excess air ratio of 1.2. The higher the volatile content of the fuel is, the less effective the NO reduction due to air staging becomes. The measurements suggest that the optimum gas residence time regarding the emissions in CFB combustors is around 6 to 7 s. These times are achieved in commercial scale plants due to their large cyclones that perhaps partly can replace a large afterburner chamber. The circulating fluidized bed boiler can be operated in a very flexible way with various fuel mixtures up to an energy fraction of sludge of 25% without exceeding legal emission limits.

  3. Advanced Characterization Techniques for SiC and PyC Coatings on High-Temperature Reactor Fuel Particles

    OpenAIRE

    Helary, D.; Dugne, O.; Bourrat, Xavier

    2008-01-01

    International audience; Enhancing the safety of high-temperature reactors (HTRs) is based on the quality of the fuel particles, requiring good knowledge of the microstructure of the four-layer particles designed to retain the fission products during irradiation and under accidental conditions. This paper focuses on the intensive research work performed to characterize the micro- and nanostructure of each unirradiated layer (silicon carbide and pyrocarbon coatings). The analytic expertise deve...

  4. Progress Toward Quality Assurance Standards for Advanced Hydrocarbon Fuels Based on Thermal Performance Testing and Chemometric Modeling

    Science.gov (United States)

    2015-12-15

    analyses; (2) Identify class distinguishing features, i.e., chemical compounds in the chromatographic data, that contribute to a fuel’s group ...implemented primarily to identify distinguishing chemical compounds that contribute to a fuel’s group assignment. F-ratio analysis was performed using...hydrocarbon-fueled liquid rocket engines, combustion enthalpy is transferred at high rates to thrust chamber surfaces, which are maintained at acceptably

  5. Advances and challenges in explaining fuel spray impingement: How much of single droplet impact research is useful?

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, A.L.N.; Moita, A.S.; Panao, M.R. [Instituto Superior Tecnico, Laboratory of Thermofluids, Combustion and Energy Systems at IN+, Av Rovisco Pais, 1049 Lisboa, Codex (Portugal)

    2010-10-15

    The impingement of fuel spray onto interposed surfaces in an IC engine, equipped either with a direct or an indirect injection system, is a fundamental issue affecting mixture preparation prior to combustion and, therefore, also affecting engine performance and pollutant emissions. In this context, the development of fuel injection systems relies on accurate knowledge of the fluid dynamic and thermal processes occurring during spray/wall interaction. Injection systems however, are very complex and the background physics requires fundamental studies, performed at simplified flow geometries. In particular, the impact of individual droplets has been extensively used to describe the behaviour of spray impact and to predict its outcome, despite the known fact that a spray does not behave exactly as a summation of individual droplets; then, researchers incorporate all the governing parameters. The present paper offers a critical review of the investigations reported in the literature on spray-wall impact relevant to IC engines, in an attempt to address the rationale of describing spray-wall interactions based on the knowledge of single droplet impacts. Moreover, although the review was first aimed at fuel-spray impingement in IC engines, it also became relevant to provide a systematization of the current state of the art, which can be useful to the scientific community involved with droplet and spray impingement phenomena. (author)

  6. Advanced control of liquid water region in diffusion media of polymer electrolyte fuel cells through a dimensionless number

    Science.gov (United States)

    Wang, Yun; Chen, Ken S.

    2016-05-01

    In the present work, a three-dimension (3-D) model of polymer electrolyte fuel cells (PEFCs) is employed to investigate the complex, non-isothermal, two-phase flow in the gas diffusion layer (GDL). Phase change in gas flow channels is explained, and a simplified approach accounting for phase change is incorporated into the fuel cell model. It is found that the liquid water contours in the GDL are similar along flow channels when the channels are subject to two-phase flow. Analysis is performed on a dimensionless parameter Da0 introduced in our previous paper [Y. Wang and K. S. Chen, Chemical Engineering Science 66 (2011) 3557-3567] and the parameter is further evaluated in a realistic fuel cell. We found that the GDL's liquid water (or liquid-free) region is determined by the Da0 number which lumps several parameters, including the thermal conductivity and operating temperature. By adjusting these factors, a liquid-free GDL zone can be created even though the channel stream is two-phase flow. Such a liquid-free zone is adjacent to the two-phase region, benefiting local water management, namely avoiding both severe flooding and dryness.

  7. Design concepts and advanced telerobotics development for facilities in the back end of the nuclear fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Feldman, M.J.

    1987-01-01

    In the Fuel Recycle Division at the Oak Ridge National Laboratory, a comprehensive remote systems development program has existed for the past seven years. The new remote technology under development is expected to significantly improve remote operations by extending the range of tasks accomplished by remote means and increasing the efficiency of remote work undertaken. Five areas of the development effort are primary contributors to the goal of higher operating efficiency for major facilities for the back end of the nuclear fuel cycle. These areas are the single-cell concept, the low-flow ventilation concept, television viewing, equipment-mounting racks, and force-reflecting manipulation. These somewhat innovative directions are products of a design process where the technical scenario to be accomplished, the remote equipment to accomplish the scenario, and the facility design to house the equipment, are considered in an iterative design process to optimize performance, maximize long-term costs effectiveness, and minimize initial capital outlay. 14 refs., 3 figs.

  8. Life-cycle assessment of corn-based butanol as a potential transportation fuel.

    Energy Technology Data Exchange (ETDEWEB)

    Wu, M.; Wang, M.; Liu, J.; Huo, H.; Energy Systems

    2007-12-31

    Butanol produced from bio-sources (such as corn) could have attractive properties as a transportation fuel. Production of butanol through a fermentation process called acetone-butanol-ethanol (ABE) has been the focus of increasing research and development efforts. Advances in ABE process development in recent years have led to drastic increases in ABE productivity and yields, making butanol production worthy of evaluation for use in motor vehicles. Consequently, chemical/fuel industries have announced their intention to produce butanol from bio-based materials. The purpose of this study is to estimate the potential life-cycle energy and emission effects associated with using bio-butanol as a transportation fuel. The study employs a well-to-wheels analysis tool--the Greenhouse Gases, Regulated Emissions and Energy Use in Transportation (GREET) model developed at Argonne National Laboratory--and the Aspen Plus{reg_sign} model developed by AspenTech. The study describes the butanol production from corn, including grain processing, fermentation, gas stripping, distillation, and adsorption for products separation. The Aspen{reg_sign} results that we obtained for the corn-to-butanol production process provide the basis for GREET modeling to estimate life-cycle energy use and greenhouse gas emissions. The GREET model was expanded to simulate the bio-butanol life cycle, from agricultural chemical production to butanol use in motor vehicles. We then compared the results for bio-butanol with those of conventional gasoline. We also analyzed the bio-acetone that is coproduced with bio-butanol as an alternative to petroleum-based acetone. Our study shows that, while the use of corn-based butanol achieves energy benefits and reduces greenhouse gas emissions, the results are affected by the methods used to treat the acetone that is co-produced in butanol plants.

  9. HTGR fuel and fuel cycle technology

    Energy Technology Data Exchange (ETDEWEB)

    Lotts, A.L.; Coobs, J.H.

    1976-08-01

    The status of fuel and fuel cycle technology for high-temperature gas-cooled reactors (HTGRs) is reviewed. The all-ceramic core of the HTGRs permits high temperatures compared with other reactors. Core outlet temperatures of 740/sup 0/C are now available for the steam cycle. For advanced HTGRs such as are required for direct-cycle power generation and for high-temperature process heat, coolant temperatures as high as 1000/sup 0/C may be expected. The paper discusses the variations of HTGR fuel designs that meet the performance requirements and the requirements of the isotopes to be used in the fuel cycle. Also discussed are the fuel cycle possibilities, which include the low-enrichment cycle, the Th-/sup 233/U cycle, and plutonium utilization in either cycle. The status of fuel and fuel cycle development is summarized.

  10. Motor vehicle fuel economy, the forgotten HC control stragegy?

    Energy Technology Data Exchange (ETDEWEB)

    Deluchi, M.; Wang, Quanlu; Greene, D.L.

    1992-06-01

    Emissions of hydrocarbons from motor vehicles are recognized as major contributors to ozone pollution in urban areas. Petroleum-based motor fuels contain volatile organic compounds (VOC) which, together with oxides of nitrogen, promote the formation of ozone in the troposphere via complex photochemical reactions. VOC emissions from the tailpipe and evaporation from the fuel and engine systems of highway vehicles are believed to account for about 40% of total VOC emissions in any region. But motor fuels also generate emissions throughout the fuel cycle, from crude oil production to refining, storage, transportation, and handling, that can make significant contributions to the total inventory of VOC emissions. Many of these sources of emissions are directly related to the quantity of fuel produced and handled throughout the fuel cycle. It is, therefore, reasonable to expect that a reduction in total fuel throughput might result in a reduction of VOC emissions. In particular, reducing vehicle fuel consumption by increasing vehicle fuel economy should reduce total fuel throughput, thereby cutting total emissions of VOCS. In this report we identify the sources of VOC emissions throughout the motor fuel cycle, quantify them to the extent possible, and describe their dependence on automobile and light truck fuel economy.

  11. Study of advanced professional educational requirements relative to nuclear fuel cycle engineering in industry and government. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Jur, T.A.; Huhns, M.N.; Keating, D.A.; Orloff, D.I.; Rhodes, C.A.; Stanford, T.G.; Stephens, L.M.; Tatterson, G.B.; Van Brunt, V.

    1978-12-01

    Under contract with the U.S. Department of Energy, the College of Engineering at the University of South Carolina has conducted an assessment of educational needs among engineers working in nuclear fuel cycle related areas. The study was initiated as a regional effort focusing on the concentration of nuclear industry in the Southeast. Educational needs addressed were those at the post-baccalaureate professional level. The project was envisioned as providing base line information for the eventual implementation of a program in line with the needs of the Southeast's nuclear community. Specific objectives were to establish the content of such a program and to determine those specialized features which would make the program most attractive and useful.

  12. Study of advanced professional educational requirements relative to nuclear fuel cycle engineering in industry and government. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Jur, T.A.; Huhns, M.N.; Keating, D.A.; Orloff, D.I.; Rhodes, C.A.; Stanford, T.G.; Stephens, L.M.; Tatterson, G.B.; Van Brunt, V.

    1978-12-01

    An assessment was conducted of educational needs among engineers working in nuclear fuel cycle-related areas, focusing on the nuclear industry in the Southeast. Educational needs addressed were those at the post-baccalaureate professional level. As a result of the study, a list of subject areas has been compiled as best representing the current content of an educational program. In addition to identifying subject areas, a set of course descriptions and reference materials has been developed around each subject. Each course description contains information regarding objectives, anticipated audience, and prerequisites and offers a suggested course outline. An initial modest program of implementation is recommended which would continue to concentrate on the Southeast as a target area.

  13. Performance evaluation of an advanced air-fuel ratio controller on a stationary, rich-burn natural gas engine

    Science.gov (United States)

    Kochuparampil, Roshan Joseph

    The advent of an era of abundant natural gas is making it an increasingly economical fuel source against incumbents such as crude oil and coal, in end-use sectors such as power generation, transportation and industrial chemical production, while also offering significant environmental benefits over these incumbents. Equipment manufacturers, in turn, are responding to widespread demand for power plants optimized for operation with natural gas. In several applications such as distributed power generation, gas transmission, and water pumping, stationary, spark-ignited, natural gas fueled internal combustion engines (ICEs) are the power plant of choice (over turbines) owing to their lower equipment and operational costs, higher thermal efficiencies across a wide load range, and the flexibility afforded to end-users when building fine-resolution horsepower topologies: modular size increments ranging from 100 kW -- 2 MW per ICE power plant compared to 2 -- 5 MW per turbine power plant. Under the U.S. Environment Protection Agency's (EPA) New Source Performance Standards (NSPS) and Reciprocating Internal Combustion Engine National Emission Standards for Hazardous Air Pollutants (RICE NESHAP) air quality regulations, these natural gas power plants are required to comply with stringent emission limits, with several states mandating even stricter emissions norms. In the case of rich-burn or stoichiometric natural gas ICEs, very high levels of sustained emissions reduction can be achieved through exhaust after-treatment that utilizes Non Selective Catalyst Reduction (NSCR) systems. The primary operational constraint with these systems is the tight air-fuel ratio (AFR) window of operation that needs to be maintained if the NSCR system is to achieve simultaneous reduction of carbon monoxide (CO), nitrogen oxides (NOx), total hydrocarbons (THC), volatile organic compounds (VOCs), and formaldehyde (CH 2O). Most commercially available AFR controllers utilizing lambda (oxygen

  14. Advanced fuel gas desulfurization (AFGD) demonstration project. Technical progress report No. 19, July 1, 1994--September 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-01

    The {open_quotes}Advanced Flue Gas Desulfurization (AFGD) Demonstration Project{close_quotes} is a $150.5 million cooperative effort between the U.S. Department of Energy and Pure Air, a general partnership of Air Products and Chemicals, Inc. and Mitsubishi Heavy Industries America, Inc. The AFGD process is one of several alternatives to conventional flue gas desulfurization (FGD) being demonstrated under the Department of Energy`s Clean Coal Technology Demonstration Program. The AFGD demonstration project is located at the Northern Indiana Public Service Company`s Bailly Generating Station, about 12 miles northeast of Gary, Indiana.

  15. Summary of thermocouple performance during advanced gas reactor fuel irradiation experiments in the advanced test reactor and out-of-pile thermocouple testing in support of such experiments

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, A. J.; Haggard, DC; Herter, J. W.; Swank, W. D.; Knudson, D. L.; Cherry, R. S. [Idaho National Laboratory, P.O. Box 1625, MS 4112, Idaho Falls, ID, (United States); Scervini, M. [University of Cambridge, Department of Material Science and Metallurgy, 27 Charles Babbage Road, CB3 0FS, Cambridge, (United Kingdom)

    2015-07-01

    High temperature gas reactor experiments create unique challenges for thermocouple-based temperature measurements. As a result of the interaction with neutrons, the thermoelements of the thermocouples undergo transmutation, which produces a time-dependent change in composition and, as a consequence, a time-dependent drift of the thermocouple signal. This drift is particularly severe for high temperature platinum-rhodium thermocouples (Types S, R, and B) and tungsten-rhenium thermocouples (Type C). For lower temperature applications, previous experiences with Type K thermocouples in nuclear reactors have shown that they are affected by neutron irradiation only to a limited extent. Similarly, Type N thermocouples are expected to be only slightly affected by neutron fluence. Currently, the use of these nickel-based thermocouples is limited when the temperature exceeds 1000 deg. C due to drift related to phenomena other than nuclear irradiation. High rates of open-circuit failure are also typical. Over the past 10 years, three long-term Advanced Gas Reactor experiments have been conducted with measured temperatures ranging from 700 deg. C - 1200 deg. C. A variety of standard Type N and specialty thermocouple designs have been used in these experiments with mixed results. A brief summary of thermocouple performance in these experiments is provided. Most recently, out-of-pile testing has been conducted on a variety of Type N thermocouple designs at the following (nominal) temperatures and durations: 1150 deg. C and 1200 deg. C for 2,000 hours at each temperature, followed by 200 hours at 1250 deg. C and 200 hours at 1300 deg. C. The standard Type N design utilizes high purity, crushed MgO insulation and an Inconel 600 sheath. Several variations on the standard Type N design were tested, including a Haynes 214 alloy sheath, spinel (MgAl{sub 2}O{sub 4}) insulation instead of MgO, a customized sheath developed at the University of Cambridge, and finally a loose assembly

  16. Summary of Thermocouple Performance During Advanced Gas Reactor Fuel Irradiation Experiments in the Advanced Test Reactor and Out-of-Pile Thermocouple Testing in Support of Such Experiments

    Energy Technology Data Exchange (ETDEWEB)

    A. J. Palmer; DC Haggard; J. W. Herter; M. Scervini; W. D. Swank; D. L. Knudson; R. S. Cherry

    2011-07-01

    High temperature gas reactor experiments create unique challenges for thermocouple based temperature measurements. As a result of the interaction with neutrons, the thermoelements of the thermocouples undergo transmutation, which produces a time dependent change in composition and, as a consequence, a time dependent drift of the thermocouple signal. This drift is particularly severe for high temperature platinum-rhodium thermocouples (Types S, R, and B); and tungsten-rhenium thermocouples (Types C and W). For lower temperature applications, previous experiences with type K thermocouples in nuclear reactors have shown that they are affected by neutron irradiation only to a limited extent. Similarly type N thermocouples are expected to be only slightly affected by neutron fluxes. Currently the use of these Nickel based thermocouples is limited when the temperature exceeds 1000°C due to drift related to phenomena other than nuclear irradiation. High rates of open-circuit failure are also typical. Over the past ten years, three long-term Advanced Gas Reactor (AGR) experiments have been conducted with measured temperatures ranging from 700oC – 1200oC. A variety of standard Type N and specialty thermocouple designs have been used in these experiments with mixed results. A brief summary of thermocouple performance in these experiments is provided. Most recently, out of pile testing has been conducted on a variety of Type N thermocouple designs at the following (nominal) temperatures and durations: 1150oC and 1200oC for 2000 hours at each temperature, followed by 200 hours at 1250oC, and 200 hours at 1300oC. The standard Type N design utilizes high purity crushed MgO insulation and an Inconel 600 sheath. Several variations on the standard Type N design were tested, including Haynes 214 alloy sheath, spinel (MgAl2O4) insulation instead of MgO, a customized sheath developed at the University of Cambridge, and finally a loose assembly thermocouple with hard fired alumina

  17. Bio-inspired Construction of Advanced Fuel Cell Cathode with Pt Anchored in Ordered Hybrid Polymer Matrix

    Science.gov (United States)

    Xia, Zhangxun; Wang, Suli; Jiang, Luhua; Sun, Hai; Liu, Shuang; Fu, Xudong; Zhang, Bingsen; Sheng Su, Dang; Wang, Jianqiang; Sun, Gongquan

    2015-01-01

    The significant use of platinum for catalyzing the cathodic oxygen reduction reactions (ORRs) has hampered the widespread use of polymer electrolyte membrane fuel cells (PEMFCs). The construction of well-defined electrode architecture in nanoscale with enhanced utilization and catalytic performance of Pt might be a promising approach to address such barrier. Inspired by the highly efficient catalytic processes in enzymes with active centers embedded in charge transport pathways, here we demonstrate for the first time a design that allocates platinum nanoparticles (Pt NPs) at the boundaries with dual-functions of conducting both electrons by aid of polypyrrole and protons via Nafion® ionomer within hierarchical nanoarrays. By mimicking enzymes functionally, an impressive ORR activity and stability is achieved. Using this brand new electrode architecture as the cathode and the anode of a PEMFC, a high mass specific power density of 5.23 W mg−1Pt is achieved, with remarkable durability. These improvements are ascribed to not only the electron decoration and the anchoring effects from the Nafion® ionomer decorated PPy substrate to the supported Pt NPs, but also the fast charge and mass transport facilitated by the electron and proton pathways within the electrode architecture. PMID:26537781

  18. Advanced cathode materials for polymer electrolyte fuel cells based on pt/ metal oxides: from model electrodes to catalyst systems.

    Science.gov (United States)

    Fabbri, Emiliana; Pătru, Alexandra; Rabis, Annett; Kötz, Rüdiger; Schmidt, Thomas J

    2014-01-01

    The development of stable catalyst systems for application at the cathode side of polymer electrolyte fuel cells (PEFCs) requires the substitution of the state-of-the-art carbon supports with materials showing high corrosion resistance in a strongly oxidizing environment. Metal oxides in their highest oxidation state can represent viable support materials for the next generation PEFC cathodes. In the present work a multilevel approach has been adopted to investigate the kinetics and the activity of Pt nanoparticles supported on SnO2-based metal oxides. Particularly, model electrodes made of SnO2 thin films supporting Pt nanoparticles, and porous catalyst systems made of Pt nanoparticles supported on Sb-doped SnO2 high surface area powders have been investigated. The present results indicate that SnO2-based supports do not modify the oxygen reduction reaction mechanism on the Pt nanoparticle surface, but rather lead to catalysts with enhanced specific activity compared to Pt/carbon systems. Different reasons for the enhancement in the specific activity are considered and discussed.

  19. Pd-on-Au Supra-nanostructures Decorated Graphene Oxide: An Advanced Electrocatalyst for Fuel Cell Application.

    Science.gov (United States)

    Tao, Yingzhou; Dandapat, Anirban; Chen, Liming; Huang, Youju; Sasson, Yoel; Lin, Zhenyu; Zhang, Jiawei; Guo, Longhua; Chen, Tao

    2016-08-30

    We report a very easy and effective approach for synthesizing unique palladium-on-gold supra-nanostructure (Au@Pd-SprNS)-decorated graphene oxide (GO) nanosheets. The SprNSs comprising Au nanorods as core and a unique close-packed assembly of tiny anisotropic Pd nanoparticles (NPs) as shell were homogeneously distributed on the GO surface via electrostatic self-assembly. Compared with the traditional one-pot method for synthesis of metal NPs on GO sheets, the size and shape of core-shell Au@Pd SprNSs can be finely controlled and uniformly distributed on the GO carrier. Interestingly, this Au@Pd-SprNSs/GO nanocomposite displayed high electrocatalytic activities toward the oxidation of methanol, ethanol, and formic acid, which can be attributed to the abundance of intrinsic active sites including high density of atomic steps, ledges and kinks, Au-Pd heterojunctions and cooperative action of the two metals of the SprNSs. Additionally, uniform dispersion of the SprNSs over the GO nanosheets prevent agglomeration between the SprNSs, which is of great significance to enhance the long-term stability of catalyst. This work will introduce a highly efficient Pd-based nanoelectrocatalyst to be used in fuel cell application.

  20. Fuel Quality/Processing Study. Volume II. Appendix, Task I, literature survey

    Energy Technology Data Exchange (ETDEWEB)

    O' Hara, J B; Bela, A; Jentz, N E; Klumpe, H W; Kessler, R E; Kotzot, H T; Loran, B I

    1981-04-01

    This activity was begun with the assembly of information from Parsons' files and from contacts in the development and commercial fields. A further more extensive literature search was carried out using the Energy Data Base and the American Petroleum Institute Data Base. These are part of the DOE/RECON system. Approximately 6000 references and abstracts were obtained from the EDB search. These were reviewed and the especially pertinent documents, approximately 300, were acquired in the form of paper copy or microfiche. A Fuel Properties form was developed for listing information pertinent to gas turbine liquid fuel properties specifications. Fuel properties data for liquid fuels from selected synfuel processes, deemed to be successful candidates for near future commercial plants were tabulated on the forms. The processes selected consisted of H-Coal, SRC-II and Exxon Donor Solvent (EDS) coal liquefaction processes plus Paraho and Tosco shale oil processes. Fuel properties analyses for crude and distillate syncrude process products are contained in Section 2. Analyses representing synthetic fuels given refinery treatments, mostly bench scale hydrotreating, are contained in Section 3. Section 4 discusses gas turbine fuel specifications based on petroleum source fuels as developed by the major gas turbine manufacturers. Section 5 presents the on-site gas turbine fuel treatments applicable to petroleum base fuels impurities content in order to prevent adverse contaminant effects. Section 7 relates the environmental aspects of gas turbine fuel usage and combustion performance. It appears that the near future stationary industrial gas turbine fuel market will require that some of the synthetic fuels be refined to the point that they resemble petroleum based fuels.

  1. Fuel cell transit bus development & commercialization programs at Gerogetown University

    Energy Technology Data Exchange (ETDEWEB)

    Wimmer, R.; Larkins, J.; Romano, S. [Georgetown Univ., Washington, DC (United States)

    1996-12-31

    Fourteen years ago, Georgetown University (GU) perceived the need for a clean, efficient power systems for transportation that could operate on non-petroleum based fuels. The transit bus application was selected to begin system development. GU recognized the range and recharge constraints of a pure battery powered transit bus. A Fuel Cell power system would circumvent these limitations and, with an on board reformer, accommodate liquid fuel for rapid refueling. Feasibility studies for Fuel Cell power systems for transit buses were conducted with the Los Alamos National Laboratory in 1983. Successful results of this investigation resulted in the DOT/DOE Fuel Cell transit bus development program. The first task was to prove that small Fuel Cell power plants were possible. This was achieved with the Phase I development of two 25 kW Phosphoric Acid Fuel Cell (PAFC) brassboard systems. A liquid cooled version was selected for the Phase II activity in which three 30-foot Fuel Cell powered Test Bed Buses (TBBs) were fabricated. The first of these TBBs was delivered in the spring of 1994. All three of these development vehicles are now in Phase III of the program to conduct testing and evaluation, is conducting operational testing of the buses. The test will involve two fuel cell-operated buses; one with a proton exchange fuel cell and the other with a phosphoric acid fuel cell.

  2. 燃料电池及其相关材料新进展(三)%Novel Advances in Fuel Cells and Their Relevant Materials

    Institute of Scientific and Technical Information of China (English)

    杨遇春

    1999-01-01

    Fuel cells as a high efficient, non-polluting electricity generation system are already at a near-commercial or sub-commercial stage. To meet the need for the revolution of electricity industry based fuel cells within the next few years, principal types of fuel cell systems (phosphoric acid fuel cell - PAFC, proton exchange membrane fuel cell - PEMFC, Molten carbonate fuel cell - MCFC, Solid oxide fuel cell - SOFC), their development status and economic significance were introduced. Materials and their performance requirements in fuel cell development and current status and problems in material technologies were described also. It is suggested that the domestic development goal concerning fuel cells is direct at the development of SOFC and PEMFC incorporating the superionrity of our mineral resources.

  3. DOE perspective on fuel cells in transportation

    Energy Technology Data Exchange (ETDEWEB)

    Kost, R.

    1996-04-01

    Fuel cells are one of the most promising technologies for meeting the rapidly growing demand for transportation services while minimizing adverse energy and environmental impacts. This paper reviews the benefits of introducing fuel cells into the transportation sector; in addition to dramatically reduced vehicle emissions, fuel cells offer the flexibility than use petroleum-based or alternative fuels, have significantly greater energy efficiency than internal combustion engines, and greatly reduce noise levels during operation. The rationale leading to the emphasis on proton-exchange-membrane fuel cells for transportation applications is reviewed as are the development issues requiring resolution to achieve adequate performance, packaging, and cost for use in automobiles. Technical targets for power density, specific power, platinum loading on the electrodes, cost, and other factors that become increasingly more demanding over time have been established. Fuel choice issues and pathways to reduced costs and to a renewable energy future are explored. One such path initially introduces fuel cell vehicles using reformed gasoline while-on-board hydrogen storage technology is developed to the point of allowing adequate range (350 miles) and refueling convenience. This scenario also allows time for renewable hydrogen production technologies and the required supply infrastructure to develop. Finally, the DOE Fuel Cells in Transportation program is described. The program, whose goal is to establish the technology for fuel cell vehicles as rapidly as possible, is being implemented by means of the United States Fuel Cell Alliance, a Government-industry alliance that includes Detroit`s Big Three automakers, fuel cell and other component suppliers, the national laboratories, and universities.

  4. 液体闪烁计数法鉴别生物质基泡沫材料%Identification of the Bio-based and Petroleum Based Foam

    Institute of Scientific and Technical Information of China (English)

    邓坤明; 马艳; 王宏晓; 沈娟章; 谭卫红

    2016-01-01

    The 14C content in the bio-based foam was determined by liquid scintillation based on ASTM D6866 method. Identification of the bio-based and petroleum based foam was based on the different biobased content. In this experiment, the sample quality is determined by the elemental analysis. The temperature of the ignition experiment is dependent on TG. After combustion,the sample was converted to carbon dioxide. Through a series of chemical reactions,it was synthesised to be liquid benzene. Through the determination of radioactive carbon isotope,content of 14C in benzene was used to identify biomass based foams and petroleum based foam. The background coal and standard substance sugar carbon were detected simultaneously. The results showed that the 14 C radioactivity values of sugar carbon were the standard value,and the results of biobased content result is in agreement with that of the American Beta laboratory by using accelerator mass spectrometry ( AMS) method. The bio-based content of four kinds of foam samples are 18. 77%,23. 51%,5. 39% and 11. 13%,respectively . They all are bio-based foam. It indicates that the bio-based foam and the petroleum based foam can be identified by this method.%基于美国材料实验协会ASTM D6866标准,利用超低本底液体闪烁技术,测定不同原料来源的泡沫材料中放射性碳同位素14C含量,转化为生物基含量,从而用于鉴别生物基泡沫材料。实验中,分别利用元素分析和热重分析确定样品用量及其氧化燃烧温度,样品燃烧后产生的二氧化碳经过一系列化学反应合成为液体苯,通过测定合成苯中的放射性碳同位素14C含量来区别鉴定生物质基泡沫材料和石油基泡沫材料,同时测定本底物质煤炭和标准物质糖碳中的14C含量。结果表明:采用该方法测定的糖碳标准物质的14C放射性活度值与标准值一致,由生物质基泡沫材料的14C放射性活度值测定结果计

  5. Advances in microreaction technology for portable fuel cell applications: Wall coating of thin catalytic films in microreactors

    Science.gov (United States)

    Bravo Bersano, Jaime Cristian

    This research has focused on the need to coat microreactor systems composed of channels in the micron size range of 100 to 1000 mum. The experimental procedures and learning are outlined in terms of slurry and surface preparation requirements which are detailed in the experimental section. This system is motivated and applied to micro methanol steam reformers. Thus, a detailed discussion on the driving motivation is given in the introduction. The low temperatures required for steam-reforming of methanol ˜ 493°K (220°C) make it possible to utilize the reformate as a feed to the fuel cell anode. The group of catalysts that shows the highest activity for methanol steam reforming (SR) at low temperature has composition of CuO/ZnO/Al 2O3, which is also the catalyst used for methanol synthesis. Steam reforming of methanol is a highly endothermic process. Conventional reactor configurations, such as a packed bed reactor, operate in a heat transfer limited mode for this reaction. Using catalyst in packed bed form for portable devices is also not convenient due to high pressure drop and possible channeling of gases in addition to poor heat transfer. A wall-coated catalyst represents a superior geometry since it provides lower pressure drop and ease of manufacturing. Due to their small size, microreactors are especially suited for endothermic reactions whose reactivity depends on the rate of heat input. A brief review on microreaction technology is given with a comprehensive survey for catalyst integration into microreactors for catalytic heterogeneous gas phase reactions. The strength of this research is the model that was developed to coat the interior of micron sized capillaries with coats of CuO/ZnO/Al2O 3 slurries as thick as 25 mum in the dry state. The details of the model are given in terms Taylor's theory and Rayleigh's theory. A model is presented that can predict the coat thickness based on experimental conditions The model combines Taylor's experimental work

  6. Engineering organisms for industrial fuel production.

    Science.gov (United States)

    Berry, David A

    2010-01-01

    Volatile fuel costs, the need to reduce greenhouse gas emissions and fuel security concerns are driving efforts to produce sustainable renewable fuels and chemicals. Petroleum comes from sunlight, CO(2) and water converted via a biological intermediate into fuel over a several million year timescale. It stands to reason that using biology to short-circuit this time cycle offers an attractive alternative--but only with relevant products at or below market prices. The state of the art of biological engineering over the past five years has progressed to allow for market needs to drive innovation rather than trying to adapt existing approaches to the market. This report describes two innovations using synthetic biology to dis-intermediate fuel production. LS9 is developing a means to convert biological intermediates such as cellulosic hydrolysates into drop-in hydrocarbon product replacements such as diesel. Joule Unlimited is pioneering approaches to eliminate feedstock dependency by efficiently capturing sunlight, CO(2) and water to produce fuels and chemicals. The innovations behind these companies are built with the market in mind, focused on low cost biosynthesis of existing products of the petroleum industry. Through successful deployment of technologies such as those behind LS9 and Joule Unlimited, alternative sources of petroleum products will mitigate many of the issues faced with our petroleum-based economy.

  7. Production of bio-jet fuel from microalgae

    Science.gov (United States)

    Elmoraghy, Marian

    The increase in petroleum-based aviation fuel consumption, the decrease in petroleum resources, the fluctuation of the crude oil price, the increase in greenhouse gas emission and the need for energy security are motivating the development of an alternate jet fuel. Bio-jet fuel has to be a drop in fuel, technically and economically feasible, environmentally friendly, greener than jet fuel, produced locally and low gallon per Btu. Bic jet fuel has been produced by blending petro-based jet fuel with microalgae biodiesel (Fatty Acid Methyl Ester, or simply FAME). Indoor microalgae growth, lipids extraction and transetrification to biodiesel are energy and fresh water intensive and time consuming. In addition, the quality of the biodiesel product and the physical properties of the bio-jet fuel blends are unknown. This work addressed these challenges. Minimizing the energy requirements and making microalgae growth process greener were accomplished by replacing fluorescent lights with light emitting diodes (LEDs). Reducing fresh water footprint in algae growth was accomplished by waste water use. Microalgae biodiesel production time was reduced using the one-step (in-situ transestrification) process. Yields up to 56.82 mg FAME/g dry algae were obtained. Predicted physical properties of in-situ FAME satisfied European and American standards confirming its quality. Lipid triggering by nitrogen deprivation was accomplished in order to increase the FAME production. Bio-jet fuel freezing points and heating values were measured for different jet fuel to biodiesel blend ratios.

  8. Comparison of Coal-Based Dimethyl Ether and Diesel as Vehicle Fuels from Well to Wheel in China

    Institute of Scientific and Technical Information of China (English)

    ZHANG Liang; HUANG Zhen

    2009-01-01

    With life cycle assessment (LCA) methodology, a life cycle model of coal-based vehicle fuels (CBVFs) including coal-based dimethyl ether (CBDME) and coal-based diesel (CBD) is established. Their primary energy consumption (PEC) and global warming potential (GWP) from well to wheel including feedstock extraction, fuel production, fuel consumption in vehicle and energy transportation are calculated and compared. Results show that the life cycle PEC and GWP of CBD pathway are 1.17 and 1.34 times as CBDME pathway. Based on the above results, CBDME will become a choice with great potential to replace conventional petroleum-based diesel (CPBD) in China.

  9. Well-to-Wheels Analysis of Advanced Fuel/Vehicle Systems: A North American Study of Energy Use, Greenhouse Gas Emissions, and Criteria Pollutant Emissions

    Energy Technology Data Exchange (ETDEWEB)

    Brinkman, Norman [General Moters Corporation, Flint, MI (United States); Wang, Michael [Argonne National Lab. (ANL), Argonne, IL (United States); Weber, Trudy [General Moters Corporation, Flint, MI (United States); Darlington, Thomas [Air Improvement Resource, Inc., Novi, MI (United States)

    2005-05-01

    An accurate assessment of future fuel/propulsion system options requires a complete vehicle fuel-cycle analysis, commonly called a well-to-wheels (WTW) analysis. This WTW study analyzes energy use and emissions associated with fuel production (or well-to-tank [WTT]) activities and energy use and emissions associated with vehicle operation (or tank-to-wheels [TTW]) activities.

  10. Life Cycle GHG of NG-Based Fuel and Electric Vehicle in China

    Directory of Open Access Journals (Sweden)

    Qian Zhang

    2013-05-01

    Full Text Available This paper compares the greenhouse gas (GHG emissions of natural gas (NG- based fuels to the GHG emissions of electric vehicles (EVs powered with NG-to-electricity in China. A life-cycle model is used to account for full fuel cycle and use-phase emissions, as well as vehicle cycle and battery manufacturing. The reduction of life-cycle GHG emissions of EVs charged by electricity generated from NG, without utilizing carbon dioxide capture and storage (CCS technology can be 36%–47% when compared to gasoline vehicles. The large range change in emissions reduction potential is driven by the different generation technologies that could in the future be used to generate electricity in China. When CCS is employed in power plants, the GHG emission reductions increase to about 71%–73% compared to gasoline vehicles. It is found that compressed NG (CNG and liquefied NG (LNG fuels can save about 10% of carbon as compared to gasoline vehicles. However, gas-to-liquid (GTL fuel made through the Fischer-Tropsch method will likely lead to a life-cycle GHG emissions increase, potentially 3%–15% higher than gasoline, but roughly equal to petroleum-based diesel. When CCS is utilized, the GTL fueled vehicles emit roughly equal GHG emissions to petroleum-based diesel fuel high-efficient hybrid electric vehicle from the life-cycle perspective.

  11. Application of Spatial Data Modeling Systems, Geographical Information Systems (GIS), and Transportation Routing Optimization Methods for Evaluating Integrated Deployment of Interim Spent Fuel Storage Installations and Advanced Nuclear Plants

    Energy Technology Data Exchange (ETDEWEB)

    Mays, Gary T [ORNL; Belles, Randy [ORNL; Cetiner, Sacit M [ORNL; Howard, Rob L [ORNL; Liu, Cheng [ORNL; Mueller, Don [ORNL; Omitaomu, Olufemi A [ORNL; Peterson, Steven K [ORNL; Scaglione, John M [ORNL

    2012-06-01

    The objective of this siting study work is to support DOE in evaluating integrated advanced nuclear plant and ISFSI deployment options in the future. This study looks at several nuclear power plant growth scenarios that consider the locations of existing and planned commercial nuclear power plants integrated with the establishment of consolidated interim spent fuel storage installations (ISFSIs). This research project is aimed at providing methodologies, information, and insights that inform the process for determining and optimizing candidate areas for new advanced nuclear power generation plants and consolidated ISFSIs to meet projected US electric power demands for the future.

  12. Development of PEM fuel cell technology at international fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Wheeler, D.J.

    1996-04-01

    The PEM technology has not developed to the level of phosphoric acid fuel cells. Several factors have held the technology development back such as high membrane cost, sensitivity of PEM fuel cells to low level of carbon monoxide impurities, the requirement to maintain full humidification of the cell, and the need to pressurize the fuel cell in order to achieve the performance targets. International Fuel Cells has identified a hydrogen fueled PEM fuel cell concept that leverages recent research advances to overcome major economic and technical obstacles.

  13. A Brief Literature Overview of Various Routes to Biorenewable Fuels from Lipids for the National Alliance for Advanced Biofuels and Bio-products (NAABB) Consortium

    Energy Technology Data Exchange (ETDEWEB)

    Albrecht, Karl O.; Hallen, Richard T.

    2011-03-29

    Renewable methods of producing transportation fuels are currently the focus of numerous large research efforts across the globe. Renewable fuel produced from algal lipids is one aspect of this research that could have profound implications on future transportation fuel requirements. However, technical challenges remain in several areas of algal-lipid-based fuels. These challenges include the identification and development of robust and productive algal species as well as extraction methods to recover the produced lipids. Not the least of these technical challenges is the conversion of the algae lipids to fungible fuels. This brief literature review focuses primarily on state-of-the-art “downstream” applications of producing fuel from fats and lipids, which can be applied to ongoing research with algae-derived lipids.

  14. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 9, October 1, 1994--December 31, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C. [AMAX Research and Development Center, Golden, CO (United States)

    1995-01-25

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 ton lots of each of three project coals, by each process. The project began in October, 1992 and is scheduled for completion by March, 1997. During Quarter 9 (October--December, 1995), parametric and optimization testing was completed for the Taggart, Sunnyside, and Indiana VII coal using a 12-inch Microcel{trademark} flotation column. The detailed design of the 2-t/hr PDU grinding, flotation, and dewatering circuits neared completion with the specification of the major pieces of capital equipment to be purchased for these areas. Selective agglomeration test work investigated the properties of various industrial grades of heptane for use during bench- and PDU-scale testing. It was decided to use a hydrotreated grade of commercial heptane due to its low cost and low concentration of aromatic compounds. The final Subtask 6.4 CWF Formulation Studies Test Plan was issued. A draft version of the Subtask 6.5 Preliminary Design and Test Plan Report was also issued, discussing the progress made in the design of the bench-scale selective agglomeration unit. PDU construction work moved forward through the issuing of 26 request for quotations and 21 award packages for capital equipment.

  15. Advanced Fuel Properties. Phase 1

    Science.gov (United States)

    1989-12-01

    normal and branched carboxylic acids, aromatic carboxylic acids, anhydrides , various kinds of esters, halogenated compounds, amines and imines...ACIDS 19 22 OTHER ALIPHATIC ACIDS 33 23 AROMATIC CARBOXYLIC ACIDS 37 24 ANHYDRIDES 9 25 FORMATES & ACETATES 27 26 N-ALKYL ESTERS 50 27 UNSATURATED...NIPER NAMEN2 The second 60 characters of the NIPER name NAMEI The chemical name according to IUPAC nomenclature rules These are the fields in the

  16. Fabrication and Pre-irradiation Characterization of a Minor Actinide and Rare Earth Containing Fast Reactor Fuel Experiment for Irradiation in the Advanced Test Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Timothy A. Hyde

    2012-06-01

    The United States Department of Energy, seeks to develop and demonstrate the technologies needed to transmute the long-lived transuranic actinide isotopes contained in spent nuclear fuel into shorter lived fission products, thereby decreasing the volume of material requiring disposal and reducing the long-term radiotoxicity and heat load of high-level waste sent to a geologic repository. This transmutation of the long lived actinides plutonium, neptunium, americium and curium can be accomplished by first separating them from spent Light Water Reactor fuel using a pyro-metalurgical process, then reprocessing them into new fuel with fresh uranium additions, and then transmuted to short lived nuclides in a liquid metal cooled fast reactor. An important component of the technology is developing actinide-bearing fuel forms containing plutonium, neptunium, americium and curium isotopes that meet the stringent requirements of reactor fuels and materials.

  17. Transportation Energy Futures Series: Alternative Fuel Infrastructure Expansion: Costs, Resources, Production Capacity, and Retail Availability for Low-Carbon Scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Melaina, W. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Heath, Garvin [National Renewable Energy Lab. (NREL), Golden, CO (United States); Sandor, Debra [National Renewable Energy Lab. (NREL), Golden, CO (United States); Steward, Darlene [National Renewable Energy Lab. (NREL), Golden, CO (United States); Vimmerstedt, Laura [National Renewable Energy Lab. (NREL), Golden, CO (United States); Warner, Ethan [National Renewable Energy Lab. (NREL), Golden, CO (United States); Webster, Karen W. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2013-04-01

    The petroleum-based transportation fuel system is complex and highly developed, in contrast to the nascent low-petroleum, low-carbon alternative fuel system. This report examines how expansion of the low-carbon transportation fuel infrastructure could contribute to deep reductions in petroleum use and greenhouse gas (GHG) emissions across the U.S. transportation sector. Three low-carbon scenarios, each using a different combination of low-carbon fuels, were developed to explore infrastructure expansion trends consistent with a study goal of reducing transportation sector GHG emissions to 80% less than 2005 levels by 2050.These scenarios were compared to a business-as-usual (BAU) scenario and were evaluated with respect to four criteria: fuel cost estimates, resource availability, fuel production capacity expansion, and retail infrastructure expansion.

  18. Third international symposium on alcohol fuels technology

    Energy Technology Data Exchange (ETDEWEB)

    None

    1980-04-01

    At the opening of the Symposium, Dr. Sharrah, Senior Vice President of Continental Oil Company, addressed the attendees, and his remarks are included in this volume. The Symposium was concluded by workshops which addressed specific topics. The topical titles are as follows: alcohol uses; production; environment and safety; and socio-economic. The workshops reflected a growing confidence among the attendees that the alcohols from coal, remote natural gas and biomass do offer alternatives to petroleum fuels. Further, they may, in the long run, prove to be equal or superior to the petroleum fuels when the aspects of performance, environment, health and safety are combined with the renewable aspect of the biomass derived alcohols. Although considerable activity in the production and use of alcohols is now appearing in many parts of the world, the absence of strong, broad scale assessment and support for these fuels by the United States Federal Government was a noted point of concern by the attendees. The environmental consequence of using alcohols continues to be more benign in general than the petroleum based fuels. The exception is the family of aldehydes. Although the aldehydes are easily suppressed by catalysts, it is important to understand their production in the combustion process. Progress is being made in this regard. Of course, the goal is to burn the alcohols so cleanly that catalytic equipment can be eliminated. Separate abstracts are prepared for the Energy Data Base for individual presentations.

  19. Mechanistic Model for Atomization of Superheated Liquid Jet Fuel Project

    Data.gov (United States)

    National Aeronautics and Space Administration — As air-breathing combustion applications advance, increased use of fuel for cooling, combined with cycle advancements, leads to a situation where the fuel can...

  20. Mechanistic Model for Atomization of Superheated Liquid Jet Fuel Project

    Data.gov (United States)

    National Aeronautics and Space Administration — As air-breathing combustion applications advance, increased use of fuel for cooling, combined with cycle advancements, leads to a situation where the fuel can become...

  1. Motor vehicle fuel economy, the forgotten HC control stragegy. [Hydrocarbon (HC)

    Energy Technology Data Exchange (ETDEWEB)

    Deluchi, M.; Wang, Quanlu; Greene, D.L.

    1992-06-01

    Emissions of hydrocarbons from motor vehicles are recognized as major contributors to ozone pollution in urban areas. Petroleum-based motor fuels contain volatile organic compounds (VOC) which, together with oxides of nitrogen, promote the formation of ozone in the troposphere via complex photochemical reactions. VOC emissions from the tailpipe and evaporation from the fuel and engine systems of highway vehicles are believed to account for about 40% of total VOC emissions in any region. But motor fuels also generate emissions throughout the fuel cycle, from crude oil production to refining, storage, transportation, and handling, that can make significant contributions to the total inventory of VOC emissions. Many of these sources of emissions are directly related to the quantity of fuel produced and handled throughout the fuel cycle. It is, therefore, reasonable to expect that a reduction in total fuel throughput might result in a reduction of VOC emissions. In particular, reducing vehicle fuel consumption by increasing vehicle fuel economy should reduce total fuel throughput, thereby cutting total emissions of VOCS. In this report we identify the sources of VOC emissions throughout the motor fuel cycle, quantify them to the extent possible, and describe their dependence on automobile and light truck fuel economy.

  2. Advanced Proliferation Resistant, Lower Cost, Uranium-Thorium Dioxide Fuels for Light Water Reactors (Progress report for work through June 2002, 12th quarterly report)

    Energy Technology Data Exchange (ETDEWEB)

    Mac Donald, Philip Elsworth

    2002-09-01

    The overall objective of this NERI project is to evaluate the potential advantages and disadvantages of an optimized thorium-uranium dioxide (ThO2/UO2) fuel design for light water reactors (LWRs). The project is led by the Idaho National Engineering and Environmental Laboratory (INEEL), with the collaboration of three universities, the University of Florida, Massachusetts Institute of Technology (MIT), and Purdue University; Argonne National Laboratory; and all of the Pressurized Water Reactor (PWR) fuel vendors in the United States (Framatome, Siemens, and Westinghouse). In addition, a number of researchers at the Korean Atomic Energy Research Institute and Professor Kwangheon Park at Kyunghee University are active collaborators with Korean Ministry of Science and Technology funding. The project has been organized into five tasks: · Task 1 consists of fuel cycle neutronics and economics analysis to determine the economic viability of various ThO2/UO2 fuel designs in PWRs, · Task 2 will determine whether or not ThO2/UO2 fuel can be manufactured economically, · Task 3 will evaluate the behavior of ThO2/UO2 fuel during normal, off-normal, and accident conditions and compare the results with the results of previous UO2 fuel evaluations and U.S. Nuclear Regulatory Commission (NRC) licensing standards, · Task 4 will determine the long-term stability of ThO2/UO2 high-level waste, and · Task 5 consists of the Korean work on core design, fuel performance analysis, and xenon diffusivity measurements.

  3. Advanced direct liquefaction concepts for PETC generic units. Final report, Phase I

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The Advanced Concepts for Direct Coal Liquefaction program was initiated by the Department of Energy in 1991 to develop technologies that could significantly reduce the cost of producing liquid fuels by the direct liquefaction of coal. The advanced 2-stage liquefaction technology that was developed at Wilsonville over the past 10 years has contributed significantly toward decreasing the cost of producing liquids from coal to about $33/bbl. It remains, however, the objective of DOE to further reduce this cost to a level more competitive with petroleum based products. This project, among others, was initiated to investigate various alternative approaches to develop technologies that might ultimately lead to a 25 % reduction in cost of product. In this project a number of novel concepts were investigated, either individually or in a coupled configuration that had the potential to contribute toward meeting the DOE goal. The concepts included mature technologies or ones closely related to them, such as coal cleaning by oil agglomeration, fluid coking and distillate hydrotreating and dewaxing. Other approaches that were either embryonic or less developed were chemical pretreatment of coal to remove oxygen, and dispersed catalyst development for application in the 2-stage liquefaction process. This report presents the results of this project. It is arranged in four sections which were prepared by participating organizations responsible for that phase of the project. A summary of the overall project and the principal results are given in this section. First, however, an overview of the process economics and the process concepts that were developed during the course of this program is presented.

  4. Advanced Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, Gordon R. [NETL

    2013-03-11

    The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

  5. Sipping fuel and saving lives: increasing fuel economy withoutsacrificing safety

    Energy Technology Data Exchange (ETDEWEB)

    Gordon, Deborah; Greene, David L.; Ross, Marc H.; Wenzel, Tom P.

    2007-06-11

    The public, automakers, and policymakers have long worried about trade-offs between increased fuel economy in motor vehicles and reduced safety. The conclusion of a broad group of experts on safety and fuel economy in the auto sector is that no trade-off is required. There are a wide variety of technologies and approaches available to advance vehicle fuel economy that have no effect on vehicle safety. Conversely, there are many technologies and approaches available to advance vehicle safety that are not detrimental to vehicle fuel economy. Congress is considering new policies to increase the fuel economy of new automobiles in order to reduce oil dependence and reduce greenhouse gas emissions. The findings reported here offer reassurance on an important dimension of that work: It is possible to significantly increase the fuel economy of motor vehicles without compromising their safety. Automobiles on the road today demonstrate that higher fuel economy and greater safety can co-exist. Some of the safest vehicles have higher fuel economy, while some of the least safe vehicles driven today--heavy, large trucks and SUVs--have the lowest fuel economy. At an October 3, 2006 workshop, leading researchers from national laboratories, academia, auto manufacturers, insurance research industry, consumer and environmental groups, material supply industries, and the federal government agreed that vehicles could be designed to simultaneously improve safety and fuel economy. The real question is not whether we can realize this goal, but the best path to get there. The experts' studies reveal important new conclusions about fuel economy and safety, including: (1) Vehicle fuel economy can be increased without affecting safety, and vice versa; (2) Reducing the weight and height of the heaviest SUVs and pickup trucks will simultaneously increase both their fuel economy and overall safety; and (3) Advanced materials can decouple size from mass, creating important new possibilities

  6. Georgia Tech Studies of Sub-Critical Advanced Burner Reactors with a D-T Fusion Tokamak Neutron Source for the Transmutation of Spent Nuclear Fuel

    Science.gov (United States)

    Stacey, W. M.

    2009-09-01

    The possibility that a tokamak D-T fusion neutron source, based on ITER physics and technology, could be used to drive sub-critical, fast-spectrum nuclear reactors fueled with the transuranics (TRU) in spent nuclear fuel discharged from conventional nuclear reactors has been investigated at Georgia Tech in a series of studies which are summarized in this paper. It is found that sub-critical operation of such fast transmutation reactors is advantageous in allowing longer fuel residence time, hence greater TRU burnup between fuel reprocessing stages, and in allowing higher TRU loading without compromising safety, relative to what could be achieved in a similar critical transmutation reactor. The required plasma and fusion technology operating parameter range of the fusion neutron source is generally within the anticipated operational range of ITER. The implications of these results for fusion development policy, if they hold up under more extensive and detailed analysis, is that a D-T fusion tokamak neutron source for a sub-critical transmutation reactor, built on the basis of the ITER operating experience, could possibly be a logical next step after ITER on the path to fusion electrical power reactors. At the same time, such an application would allow fusion to contribute to meeting the nation's energy needs at an earlier stage by helping to close the fission reactor nuclear fuel cycle.

  7. Multiple Irradiation Capsule Experiment (MICE)-3B Irradiation Test of Space Fuel Specimens in the Advanced Test Reactor (ATR) - Close Out Documentation for Naval Reactors (NR) Information

    Energy Technology Data Exchange (ETDEWEB)

    M. Chen; CM Regan; D. Noe

    2006-01-09

    Few data exist for UO{sub 2} or UN within the notional design space for the Prometheus-1 reactor (low fission rate, high temperature, long duration). As such, basic testing is required to validate predictions (and in some cases determine) performance aspects of these fuels. Therefore, the MICE-3B test of UO{sub 2} pellets was designed to provide data on gas release, unrestrained swelling, and restrained swelling at the upper range of fission rates expected for a space reactor. These data would be compared with model predictions and used to determine adequacy of a space reactor design basis relative to fission gas release and swelling of UO{sub 2} fuel and to assess potential pellet-clad interactions. A primary goal of an irradiation test for UN fuel was to assess performance issues currently associated with this fuel type such as gas release, swelling and transient performance. Information learned from this effort may have enabled use of UN fuel for future applications.

  8. 微生物燃料电池的研究应用进展%Research and application advances in microbial fuel cell

    Institute of Scientific and Technical Information of China (English)

    王维大; 李浩然; 冯雅丽; 唐新华; 杜竹玮; 杜云龙

    2014-01-01

    微生物燃料电池是利用微生物作为催化剂,氧化分解生物质同时输出电能的一种新装置,因其可将生物质中化学能直接转化为电能,可获得更高的能量转化效率,是未来缓解能源和环境问题的有效途径,引起了科研工作者的广泛关注。本文结合近几年微生物燃料电池的发展,综述了产电微生物种类、电池材料及其改性、反应器的放大以及微生物燃料电池应用方面的研究进展,分析了该领域未来发展的主要方向及面临的问题,指出筛选和诱导产电菌对不同有机底物的耐受性,开发高效价廉的电极材料以及构建易于放大的电池模式,是微生物燃料电池未来研究的重点。在此基础上,应该着重于反应器放大,深入研究其在废水处理、产氢、微生物电化学合成以及传感器方面的应用,确定其实际应用的相关参数和模型,为微生物燃料电池早日实际应用打下坚实基础。%Microbial fuel cell (MFC) was a tool for generating electrical currents via oxidizing organic compounds by using microorganisms as a biocatalyst. It was an effective approach to alleviate energy and environmental problems in the future,because it can convert chemical energy directly to electrical energy with biomass reactions,with higher energy conversion efficiency. This paper reviewed the new advances of electrogenesis microorganism species application , electrode materials and their modifications in MFC. The main developing directions and problems in this field were analyzed. The screening and mutagenesis of electrogenesis microorganisms to the tolerance of different organic substrates,the development of high efficiency and low price electrode materials and the construction of easy scale-up model of MFC were the focuses of research. The development of MFC should be focused on the scale-up of reactor in wastewater treatment,hydrogen production

  9. Fuel Cell Handbook, Fourth Edition

    Energy Technology Data Exchange (ETDEWEB)

    Stauffer, D.B; Hirschenhofer, J.H.; Klett, M.G.; Engleman, R.R.

    1998-11-01

    Robust progress has been made in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in January 1994. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultra high efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 6 describe the four major fuel cell types and their performance based on cell operating conditions. The section on polymer electrolyte membrane fuel cells has been added to reflect their emergence as a significant fuel cell technology. Phosphoric acid, molten carbonate, and solid oxide fuel cell technology description sections have been updated from the previous edition. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 7, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 8 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

  10. Fuel Efficiency in Truck Industry

    Directory of Open Access Journals (Sweden)

    Ştefan Farkas

    2010-12-01

    Full Text Available This paper reports range of activities and offer information regarding activities performed at Paccar Inc. truck’s plant in order to reduce of fuel consumption in truck industry. There are six major areas investigated: Aerodynamics, Component Spec’ing, Advanced Technology, Route Management, Driver Behaviour, Proper Maintenance. New technologies to improve vehicle fuel efficiency are also reported.

  11. Self Regulating Fiber Fuel Cell

    Science.gov (United States)

    2010-08-16

    energy numbers are 2.3X and 5.7X the theoretical values for lithium thionyl chloride respectively (1100 Whr/liter and 590 Whr/kg), which has the...REPORT Self Regulating Fiber Fuel Cell 14. ABSTRACT 16. SECURITY CLASSIFICATION OF: Advances in lithium primary battery technology, which serves as the...Prescribed by ANSI Std. Z39.18 - 16-Aug-2010 Self Regulating Fiber Fuel Cell Report Title ABSTRACT Advances in lithium primary battery technology

  12. Chemical Engineering Division Fuel Cycle Programs. Quarterly progress report, April-June 1978. [Advanced solvent extraction; accidents; pyrochemical; radwaste in metal matrix; waste migration

    Energy Technology Data Exchange (ETDEWEB)

    Steindler, M. J.; Ader, M.; Barletta, R. E.

    1979-12-01

    Fuel cycle studies reported include development of centrifugal contactors for Purex processes. Tricaprylmethyl-ammonium nitrate and di-n-amyl-n-amylphosphonate are being evaluated as Thorex extractants. Dispersion of uranium and plutonium by fires, and mechanisms for subdividing and dispersing liquids and solids were reviewed. In the pyrochemical and dry processing program, a facility for testing containment materials is under construction; a flowsheet for carbide fuel processing has been designed and studies of carbide reactions in bismuth are underway; salt transport processes are being studied; process-size refractory metal vessels are being fabricated; the feasibility of AIROX reprocessing is being determined; the solubility of UO/sub 2/, UO/sub 2/ + fission products, and PuO/sub 2/ in molten alkali metal nitrates, has been investigated; a flowsheet was developed for reprocessing actinide oxides in molten salts; preparation of Th-U carbide from the oxide is being studied; new flowsheets based on the Dow Aluminum Pyrometallurgical process for reprocessing of spent uranium metal fuel have been prepared; the chloride volitility processing of thorium-based fuels is being studied; the reprocessing of (Th,U)O/sub 2/ solid solution in KCl-LiCl-ThCl/sub 4/-Th is being studied; and a flowsheet for processing spent nuclear fuel in molten tin has been constructed. Leach rates of simulated encapsulated waste forms in a metal matrix were studied. Nine criteria for handling waste cladding hulls were established. Strontium and tin migration in glauconite columns was measured. Radioactive Sr in a stream of water moved through oolitic limestone as rapidly as water, but in a stream of water equilibrated with the limestone, Sr moved through the limestone one-tenth as fast. Migration of trace quantities of Cs and I through kaolinite was studied. 88 figures, 53 tables.

  13. 75 FR 76789 - Regulation of Fuels and Fuel Additives: 2011 Renewable Fuel Standards

    Science.gov (United States)

    2010-12-09

    ... qualifying domestic corn ethanol production capacity to meet the balance of the total renewable fuel standard... biomass-based diesels, advanced biofuels, and other conventional renewable fuels such as corn-ethanol... capacity of 250,000 gallons of ethanol per year and uses an enzymatic hydrolysis process to convert...

  14. 78 FR 49793 - Regulation of Fuels and Fuel Additives: 2013 Renewable Fuel Standards

    Science.gov (United States)

    2013-08-15

    ... renewable fuel volume of 16.55 bill gal. \\4\\ Non-advanced is composed primarily of corn ethanol, but may.... We believe there will be sufficient volumes of conventional renewable fuel including corn ethanol... specified in the Act. For instance, current corn ethanol production capacity is 14.5 bill gal, compared...

  15. Fuel services; Servicios de combustible

    Energy Technology Data Exchange (ETDEWEB)

    Marta, H.; Alvarez, P.; Jimenez, J.

    2006-07-01

    Refuelling outages comprise a number of maintenance tasks scheduled long in advance to assure a reliable operation throughout the next cycle and, in the long run, a safer and more efficient plant. Most of these tasks are routine service of mechanical and electrical system and likewise fuel an be considered a critical component as to handling, inspection, cleaning and repair. ENUSA-ENWESA AIE has been working in this area since 1995 growing from fuel repair to a more integrated service that includes new and spent fuel handling, inserts, failed fuel rod detection systems, ultrasonic fuel cleaning,fuel repair and a comprehensive array of inspection and tests related to the reliability of the mechanical components in the fuel assembly, all this, performed in compliance with quality, safety, health physics and any other nuclear standard. (Author)

  16. Fuel Cell Handbook, Fifth Edition

    Energy Technology Data Exchange (ETDEWEB)

    Energy and Environmental Solutions

    2000-10-31

    Progress continues in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in November 1998. Uppermost, polymer electrolyte fuel cells, molten carbonate fuel cells, and solid oxide fuel cells have been demonstrated at commercial size in power plants. The previously demonstrated phosphoric acid fuel cells have entered the marketplace with more than 220 power plants delivered. Highlighting this commercial entry, the phosphoric acid power plant fleet has demonstrated 95+% availability and several units have passed 40,000 hours of operation. One unit has operated over 49,000 hours. Early expectations of very low emissions and relatively high efficiencies have been met in power plants with each type of fuel cell. Fuel flexibility has been demonstrated using natural gas, propane, landfill gas, anaerobic digester gas, military logistic fuels, and coal gas, greatly expanding market opportunities. Transportation markets worldwide have shown remarkable interest in fuel cells; nearly every major vehicle manufacturer in the U.S., Europe, and the Far East is supporting development. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultrahigh efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 8 describe the six major fuel cell types and their performance based on cell operating conditions. Alkaline and intermediate solid state fuel cells were added to this edition of the Handbook. New information indicates that manufacturers have stayed

  17. Alternative Fuels Data Center (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2013-07-01

    Fact sheet describes the Alternative Fuels Data Center, which provides information, data, and tools to help fleets and other transportation decision makers find ways to reduce petroleum consumption through the use of alternative and renewable fuels, advanced vehicles, and other fuel-saving measures.

  18. Hydrogen as a fuel

    Energy Technology Data Exchange (ETDEWEB)

    1979-01-01

    A panel of the Committee on Advanced Energy Storage Systems of the Assembly of Engineering has examined the status and problems of hydrogen manufacturing methods, hydrogen transmission and distribution networks, and hydrogen storage systems. This examination, culminating at a time when rapidly changing conditions are having noticeable impact on fuel and energy availability and prices, was undertaken with a view to determining suitable criteria for establishing the pace, timing, and technical content of appropriate federally sponsored hydrogen R and D programs. The increasing urgency to develop new sources and forms of fuel and energy may well impact on the scale and timing of potential future hydrogen uses. The findings of the panel are presented. Chapters are devoted to hydrogen sources, hydrogen as a feedstock, hydrogen transport and storage, hydrogen as a heating fuel, automotive uses of hydrogen, aircraft use of hydrogen, the fuel cell in hydrogen energy systems, hydrogen research and development evaluation, and international hydrogen programs.

  19. An Applied Study of Implementation of the Advanced Decommissioning Costing Methodology for Intermediate Storage Facility for Spent Fuel in Studsvik, Sweden with special emphasis to the application of the Omega code

    Energy Technology Data Exchange (ETDEWEB)

    Kristofova, Kristina; Vasko, Marek; Daniska, Vladimir; Ondra, Frantisek; Bezak, Peter [DECOM Slovakia, spol. s.r.o., J. Bottu 2, SK-917 01 Trnava (Slovakia); Lindskog, Staffan [Swedish Nuclear Power Inspectorate, Stockholm (Sweden)

    2007-01-15

    The presented study is focused on an analysis of decommissioning costs for the Intermediate Storage Facility for Spent Fuel (FA) facility in Studsvik prepared by SVAFO and a proposal of the advanced decommissioning costing methodology application. Therefore, this applied study concentrates particularly in the following areas: 1. Analysis of FA facility cost estimates prepared by SVAFO including description of FA facility in Studsvik, summarised input data, applied cost estimates methodology and summarised results from SVAFO study. 2. Discussion of results of the SVAFO analysis, proposals for enhanced cost estimating methodology and upgraded structure of inputs/outputs for decommissioning study for FA facility. 3. Review of costing methodologies with the special emphasis on the advanced costing methodology and cost calculation code OMEGA. 4. Discussion on implementation of the advanced costing methodology for FA facility in Studsvik together with: - identification of areas of implementation; - analyses of local decommissioning infrastructure; - adaptation of the data for the calculation database; - inventory database; and - implementation of the style of work with the computer code OMEGA.

  20. Renewable Fuels and Lubricants Laboratory (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2014-08-01

    This fact sheet describes the Renewable Fuels and Lubricants (ReFUEL) Laboratory at the U.S. Department of Energy National Renewable Energy Laboratory (NREL) is a state-of-the-art research and testing facility for advanced fuels and vehicles. Research and development aims to improve vehicle efficiency and overcome barriers to the increased use of renewable diesel and other nonpetroleum-based fuels, such as biodiesel and synthetic diesel derived from biomass. The ReFUEL Laboratory features a chassis dynamometer for vehicle performance and emissions research, two engine dynamometer test cells for advanced fuels research, and precise emissions analysis equipment. As a complement to these capabilities, detailed studies of fuel properties, with a focus on ignition quality, are performed at NREL's Fuel Chemistry Laboratory.

  1. Reactor Physics Methods and Preconceptual Core Design Analyses for Conversion of the Advanced Test Reactor to Low-Enriched Uranium Fuel Annual Report for Fiscal Year 2012

    Energy Technology Data Exchange (ETDEWEB)

    David W. Nigg; Sean R. Morrell

    2012-09-01

    Under the current long-term DOE policy and planning scenario, both the ATR and the ATRC will be reconfigured at an appropriate time within the next several years to operate with low-enriched uranium (LEU) fuel. This will be accomplished under the auspices of the Reduced Enrichment Research and Test Reactor (RERTR) Program, administered by the DOE National Nuclear Security Administration (NNSA). At a minimum, the internal design and composition of the fuel element plates and support structure will change, to accommodate the need for low enrichment in a manner that maintains total core excess reactivity at a suitable level for anticipated operational needs throughout each cycle while respecting all control and shutdown margin requirements and power distribution limits. The complete engineering design and optimization of LEU cores for the ATR and the ATRC will require significant multi-year efforts in the areas of fuel design, development and testing, as well as a complete re-analysis of the relevant reactor physics parameters for a core composed of LEU fuel, with possible control system modifications. Ultimately, revalidation of the computational physics parameters per applicable national and international standards against data from experimental measurements for prototypes of the new ATR and ATRC core designs will also be required for Safety Analysis Report (SAR) changes to support routine operations with LEU. This report is focused on reactor physics analyses conducted during Fiscal Year (FY) 2012 to support the initial development of several potential preconceptual fuel element designs that are suitable candidates for further study and refinement during FY-2013 and beyond. In a separate, but related, effort in the general area of computational support for ATR operations, the Idaho National Laboratory (INL) is conducting a focused multiyear effort to introduce modern high-fidelity computational reactor physics software and associated validation protocols to replace

  2. Fuels and Combustion Technology for Advanced Aircraft Engines (Les Propergols et les Systemes de Combustion pour les Moteurs d’Aeronefs)

    Science.gov (United States)

    1993-09-01

    poiametteuse. En For a given fuel and air split, the combustor size can’ be peffet, avec cc concept technologique , le compromi~s entre les reduced without...Figure 4Chamobre It g6omdtrie variabie secteur 2D Ronfrci ddbts-’les En lplus de ces Etudes plusicurs concepts diff~rents de veilles ont Wt caractdrisEi...MaIgrE Ia relative compit-itet technologique induite, leg syst~mes j g~eontric varipble permetter’t de r~scudre ces difficult~s. LeA aute=r remercient

  3. Fossil Fuels.

    Science.gov (United States)

    Crank, Ron

    This instructional unit is one of 10 developed by students on various energy-related areas that deals specifically with fossil fuels. Some topics covered are historic facts, development of fuels, history of oil production, current and future trends of the oil industry, refining fossil fuels, and environmental problems. Material in each unit may…

  4. Advanced bioreactor concepts for gaseous substrates: Conversion of synthesis gas to liquid fuels and removal of SO{sub x} and NO{sub x} from coal combustion gases. CRADA final report

    Energy Technology Data Exchange (ETDEWEB)

    Kaufman, E.N.; Selvaraj, P.T.

    1997-10-01

    The purpose of the proposed research program was the development and demonstration of a new generation of gaseous substrate-based bioreactors for the production of liquid fuels from coal synthesis gas and the removal of NO{sub x} and SO{sub x} species from coal combustion flue gas. This study addressed the further investigation of optimal bacterial strains, growth media and kinetics for the biocatalytic conversion of coal synthesis gas to liquid fuel such as ethanol and the reduction of gaseous flue gas constituents. The primary emphasis was on the development of advanced bioreactor systems coupled with innovative biocatalytic systems that will provide increased productivity under controlled conditions. It was hoped that this would result in bioprocessing options that have both technical and economic feasibility, thus, ensuring early industrial use. Predictive mathematical models were formulated to accommodate hydrodynamics, mass transport, and conversion kinetics, and provide the data base for design and scale-up. The program was separated into four tasks: (1) Optimization of Biocatalytic Kinetics; (2) Development of Well-mixed and Columnar Reactors; (3) Development of Predictive Mathematical Models; and (4) Industrial Demonstration. Research activities addressing both synthesis gas conversion and flue gas removal were conducted in parallel by BRI and ORNL respectively.

  5. Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, Task 17208: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Amoroso, J. W. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Marra, J. C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-08-26

    A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics) over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).

  6. Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, task 17208: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Amoroso, J. W. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Marra, J. C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-08-26

    A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics) over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).

  7. Proceedings of the Water Reactor Fuel Performance Meeting - WRFPM / Top Fuel 2009

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-06-15

    SFEN, ENS, SNR, ANS, AESJ, CNS KNS, IAEA and NEA are jointly organizing the 2009 International Water Reactor Fuel Performance / TopFuel 2009 Meeting following the 2008 KNS Water Reactor Performance Meeting held during October 19-23, 2008 in Seoul, Korea. This meeting is held annually on a tri-annual rotational basis in Europe, USA and Asia. In 2009, this meeting will be held in Paris, September 6-10, 2009 in coordination with the Global 2009 Conference at the same date and place. That would lead to a common opening session, some common technical presentations, a common exhibition and common social events. The technical scope of the meeting includes all aspects of nuclear fuel from fuel rod to core design as well as manufacturing, performance in commercial and test reactors or on-going and future developments and trends. Emphasis will be placed on fuel reliability in the general context of nuclear 'Renaissance' and recycling perspective. The meeting includes selectively front and/or back end issues that impact fuel designs and performance. In this frame, the conference track devoted to 'Concepts for transportation and interim storage of spent fuels and conditioned waste' will be shared with 'GLOBAL' conference. Technical Tracks: - 1. Fuel Performance, Reliability and Operational Experience: Fuel operating experience and performance; experience with high burn-up fuels; water side corrosion; stress corrosion cracking; MOX fuel performance; post irradiation data on lead fuel assemblies; radiation effects; water chemistry and corrosion counter-measures. - 2. Transient Fuel Behaviour and Safety Related Issues: Transient fuel behavior and criteria (RIA, LOCA, ATWS, Ramp tests..). Fuel safety-related issues such as PCI (pellet cladding interaction), transient fission gas releases and cladding bursting/ballooning during transient events - Advances in fuel performance modeling and core reload methodology, small and large-scale fuel testing

  8. Proceedings of the fifth international conference on CANDU fuel. V.1,2

    Energy Technology Data Exchange (ETDEWEB)

    Lau, J.H. [ed.

    1997-07-01

    The First International Conference on CANDU Fuel was held in Chalk River in 1986. The CANDU Fuel community has gathered every three years since. The papers presented include topics on international experience, CANFLEX fuel bundles, Fuel design, Fuel modelling, Manufacturing and Quality assurance, Fuel performance and Safety, Fuel cycles and Spent Fuel management. Volume One was published in advance of the conference and Volume Two was printed after the conference.

  9. Hybrid Fuel Cell Technology Overview

    Energy Technology Data Exchange (ETDEWEB)

    None available

    2001-05-31

    For the purpose of this STI product and unless otherwise stated, hybrid fuel cell systems are power generation systems in which a high temperature fuel cell is combined with another power generating technology. The resulting system exhibits a synergism in which the combination performs with an efficiency far greater than can be provided by either system alone. Hybrid fuel cell designs under development include fuel cell with gas turbine, fuel cell with reciprocating (piston) engine, and designs that combine different fuel cell technologies. Hybrid systems have been extensively analyzed and studied over the past five years by the Department of Energy (DOE), industry, and others. These efforts have revealed that this combination is capable of providing remarkably high efficiencies. This attribute, combined with an inherent low level of pollutant emission, suggests that hybrid systems are likely to serve as the next generation of advanced power generation systems.

  10. 植物微生物燃料电池技术的研究进展%Advances in Research of Plant-Microbial Fuel Cells

    Institute of Scientific and Technical Information of China (English)

    劳慧敏; 李金页; 贾玉平

    2016-01-01

    植物微生物燃料电池(plant-microbial fuel cell,P-MFC)是一项新型的能源技术,该技术利用植物的光合作用,为具备产电能力的微生物持续提供基质,由此源源不断的输出电能,实现太阳能至电能的转化。植物微生物燃料电池能够与多项现有环境治理技术和能源工程技术相结合,对环境友好,具有良好的应用前景。%The plant-microbial fuel cell (P-MFC) is an innovative technology for solar energy utilization, the plant can supply sufficient substrates to the microorganisms who can generate electricity through photosynthesis, and the solar energy is converted to electricity in this way. P-MFC can be applied with many present technologies to gain extra benefits, and is environmental friendly as well, which has a good prospect to the applications.

  11. The effect of clove oil and diesel fuel blends on the engine performance and exhaust emissions of a compression-ignition engine

    Energy Technology Data Exchange (ETDEWEB)

    Mbarawa, Makame [Department of Mechanical Engineering, Tshwane University of Technology, Private Bag X680, Pretoria 0001 (South Africa)

    2010-11-15

    Diesel engines provide the major power source for transportation in the world and contribute to the prosperity of the worldwide economy. However, recent concerns over the environment, increasing fuel prices and the scarcity of fuel supplies have promoted considerable interest in searching for alternatives to petroleum based fuels. Based on this background, the main purpose of this investigation is to evaluate clove stem oil (CSO) as an alternative fuel for diesel engines. To this end, an experimental investigation was performed on a four-stroke, four-cylinder water-cooled direct injection diesel engine to study the performance and emissions of an engine operated using the CSO-diesel blended fuels. The effects of the CSO-diesel blended fuels on the engine brake thermal efficiency, brake specific fuel consumption (BSFC), specific energy consumption (SEC), exhaust gas temperatures and exhaust emissions were investigated. The experimental results reveal that the engine brake thermal efficiency and BSFC of the CSO-diesel blended fuels were higher than the pure diesel fuel while at the same time they exhibited a lower SEC than the latter over the entire engine load range. The variations in exhaust gas temperatures between the tested fuels were significant only at medium speed operating conditions. Furthermore, the HC emissions were lower for the CSO-diesel blended fuels than the pure diesel fuel whereas the NO{sub x} emissions were increased remarkably when the engine was fuelled with the 50% CSO-diesel blended fuel. (author)

  12. Fuel cell engineering

    CERN Document Server

    Sundmacher

    2012-01-01

    Fuel cells are attractive electrochemical energy converters featuring potentially very high thermodynamic efficiency factors. The focus of this volume of Advances in Chemical Engineering is on quantitative approaches, particularly based on chemical engineering principles, to analyze, control and optimize the steady state and dynamic behavior of low and high temperature fuel cells (PEMFC, DMFC, SOFC) to be applied in mobile and stationary systems. * Updates and informs the reader on the latest research findings using original reviews * Written by leading industry experts and scholars * Review

  13. Highly selective condensation of biomass-derived methyl ketones as a source of aviation fuel.

    Science.gov (United States)

    Sacia, Eric R; Balakrishnan, Madhesan; Deaner, Matthew H; Goulas, Konstantinos A; Toste, F Dean; Bell, Alexis T

    2015-05-22

    Aviation fuel (i.e., jet fuel) requires a mixture of C9 -C16 hydrocarbons having both a high energy density and a low freezing point. While jet fuel is currently produced from petroleum, increasing concern with the release of CO2 into the atmosphere from the combustion of petroleum-based fuels has led to policy changes mandating the inclusion of biomass-based fuels into the fuel pool. Here we report a novel way to produce a mixture of branched cyclohexane derivatives in very high yield (>94 %) that match or exceed many required properties of jet fuel. As starting materials, we use a mixture of n-alkyl methyl ketones and their derivatives obtained from biomass. These synthons are condensed into trimers via base-catalyzed aldol condensation and Michael addition. Hydrodeoxygenation of these products yields mixtures of C12 -C21 branched, cyclic alkanes. Using models for predicting the carbon number distribution obtained from a mixture of n-alkyl methyl ketones and for predicting the boiling point distribution of the final mixture of cyclic alkanes, we show that it is possible to define the mixture of synthons that will closely reproduce the distillation curve of traditional jet fuel.

  14. Design and construction of a prototype advanced on-line fuel burn-up monitoring system for the modular pebble bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Su, Bingjing; Hawari, Ayman, I.

    2004-03-30

    Modular Pebble Bed Reactor (MPBR) is a high temperature gas-cooled nuclear power reactor currently under study as a next generation reactor system. In addition to its inherently safe design, a unique feature of this reactor is its multi-pass fuel circulation in which the fuel pebbles are randomly loaded and continuously cycled through the core until they reach their prescribed End-of-Life burn-up limit. Unlike the situation with a conventional light water reactor, depending solely on computational methods to perform in-core fuel management for MPBR will be highly inaccurate. An on-line measurement system is needed to accurately assess whether a given pebble has reached its End-of-Life burn-up limit and thereby provide an on-line, automated go/no-go decision on fuel disposition on a pebble-by-pebble basis. This project investigated approaches to analyzing fuel pebbles in real time using gamma spectroscopy and possibly using passive neutron counting of spontaneous fission neutrons to provide the speed, accuracy, and burn-up range required for burnup determination of MPBR. It involved all phases necessary to develop and construct a burn-up monitor, including a review of the design requirements of the system, identification of detection methodologies, modeling and development of potential designs, and finally, the construction and testing of an operational detector system. Based upon the research work performed in this project, the following conclusions are made. In terms of using gamma spectrometry, two possible approaches were identified for burnup assay. The first approach is based on the measurement of the absolute activity of Cs-137. However, due to spectral interference and the need for absolute calibration of the spectrometer, the uncertainty in burnup determination using this approach was found to range from {approx} {+-}40% at beginning of life to {approx} {+-}10% at the discharge burnup. An alternative approach is to use a relative burnup indicator. In this

  15. Fuel distribution

    Energy Technology Data Exchange (ETDEWEB)

    Tison, R.R.; Baker, N.R.; Blazek, C.F.

    1979-07-01

    Distribution of fuel is considered from a supply point to the secondary conversion sites and ultimate end users. All distribution is intracity with the maximum distance between the supply point and end-use site generally considered to be 15 mi. The fuels discussed are: coal or coal-like solids, methanol, No. 2 fuel oil, No. 6 fuel oil, high-Btu gas, medium-Btu gas, and low-Btu gas. Although the fuel state, i.e., gas, liquid, etc., can have a major impact on the distribution system, the source of these fuels (e.g., naturally-occurring or coal-derived) does not. Single-source, single-termination point and single-source, multi-termination point systems for liquid, gaseous, and solid fuel distribution are considered. Transport modes and the fuels associated with each mode are: by truck - coal, methanol, No. 2 fuel oil, and No. 6 fuel oil; and by pipeline - coal, methane, No. 2 fuel oil, No. 6 oil, high-Btu gas, medium-Btu gas, and low-Btu gas. Data provided for each distribution system include component makeup and initial costs.

  16. Advanced treatment of fuel ethanol production wastewater by iron-carbon micro-electrolysis technology%铁炭微电解法深度处理燃料乙醇生产废水

    Institute of Scientific and Technical Information of China (English)

    李涛; 鲍锦磊; 于淼; 袁先艳; 任保增

    2013-01-01

    The fuel ethanol production wastewater was advancedly treated by iron-carbon micro-electrolysis technology. The effects of the initial pH value, hydraulic retention time(HRT) ,iron to carbon quality ratio and aeration rate on the wastewater treatment performance were investigated. And the economy of advanced treatment of fuel ethanol production wastewater with the technology was evaluated. The results showed that the better treatment effects were achieved under following reactor conditions; initial pH value of 3. 5,HRT of 40 min, iron-carbon quality ratio of 2' 1 and aeration rate of 1 m /h. The treated wastewater indexes were COD of 37. 8 mg/L, BOD5 of 13. 9 mg/L,chroma of 10. 1 , turbidity of 1. 2,respectively, which met the national standard of industrial water reuse(GB/T 19923-2005). The treatment cost is about 1. 46 yuan/ton,by using the technology for treatment of fuel ethanol production wastewater with significant social, economic and environmental effect.%采用铁炭微电解法深度处理燃料乙醇生产废水,考察了初始pH、水力停留时间、铁炭质量比和曝气量对废水处理效果的影响,并对该技术应用于燃料乙醇废水深度处理的经济性进行了评价.结果表明,在初始pH值3.5、水力停留时间40 min、铁炭质量比2∶1、曝气量为1 m3/h时,获得了较好的处理效果,废水经处理后,COD均值为37.8 mg/L,BOD5为13.9 mg/L,色度为10.1倍,浊度为1.2 NTU,达到工业用水回用的标准(GB/T 19923-2005).将此工艺应用于燃料乙醇生产废水的处理,处理费用约为1.46元/t,具有较好的社会、经济和环保效益.

  17. Advanced biotechnology: metabolically engineered cells for the bio-based production of chemicals and fuels, materials, and health-care products.

    Science.gov (United States)

    Becker, Judith; Wittmann, Christoph

    2015-03-09

    Corynebacterium glutamicum, Escherichia coli, and Saccharomyces cerevisiae in particular, have become established as important industrial workhorses in biotechnology. Recent years have seen tremendous progress in their advance into tailor-made producers, driven by the upcoming demand for sustainable pro