Advancing liquid metal reactor technology with nitride fuels
International Nuclear Information System (INIS)
Lyon, W.F.; Baker, R.B.; Leggett, R.D.; Matthews, R.B.
1991-08-01
A review of the use of nitride fuels in liquid metal fast reactors is presented. Past studies indicate that both uranium nitride and uranium/plutonium nitride possess characteristics that may offer enhanced performance, particularly in the area of passive safety. To further quantify these effects, the analysis of a mixed-nitride fuel system utilizing the geometry and power level of the US Advanced Liquid Metal Reactor as a reference is described. 18 refs., 2 figs., 2 tabs
Performance and safety design of the advanced liquid metal reactor
International Nuclear Information System (INIS)
Berglund, R.C.; Magee, P.M.; Boardman, C.E.; Gyorey, G.L.
1991-01-01
The Advanced Liquid Metal Reactor (ALMR) program led by General Electric is developing, under U.S. Department of Energy sponsorship, a conceptual design for an advanced sodium-cooled liquid metal reactor plant. This design is intended to improve the already excellent level of plant safety achieved by the nuclear power industry while at the same time providing significant reductions in plant construction and operating costs. In this paper, the plant design and performance are reviewed, with emphasis on the ALMR's unique passive design safety features and its capability to utilize as fuel the actinides in LWR spent fuel
Advanced liquid metal reactor plant control system
International Nuclear Information System (INIS)
Dayal, Y.; Wagner, W.; Zizzo, D.; Carroll, D.
1993-01-01
The modular Advanced Liquid Metal Reactor (ALMR) power plant is controlled by an advanced state-of-the-art control system designed to facilitate plant operation, optimize availability, and protect plant investment. The control system features a high degree of automatic control and extensive amount of on-line diagnostics and operator aids. It can be built with today's control technology, and has the flexibility of adding new features that benefit plant operation and reduce O ampersand M costs as the technology matures
Development of Korea advanced liquid metal reactor
International Nuclear Information System (INIS)
Park, C.K.
1998-01-01
Future nuclear power plants should not only have the features of improved safety and economic competitiveness but also provide a means to resolve spent fuel storage problems by minimizing volume of high level wastes. It is widely believed that liquid metal reactors (LMRs) have the highest potential of meeting these requirements. In this context, the LMR development program was launched as a national long-term R and D program in 1992, with a target to introduce a commercial LMR around 2030. Korea Advanced Liquid Metal Reactor (KALIMER), a 150 MWe pool-type sodium cooled prototype reactor, is currently under the conceptual design study with the target schedule to complete its construction by the mid-2010s. This paper summarizes the KALIMER development program and major technical features of the reactor system. (author)
Passive safety and the advanced liquid metal reactors
International Nuclear Information System (INIS)
Hill, D.J.; Pedersen, D.R.; Marchaterre, J.F.
1988-01-01
Advanced Liquid Metal Reactors being developed today in the USA are designed to make maximum use of passive safety features. Much of the LMR safety work at Argonne National Laboratory is concerned with demonstrating, both theoretically and experimentally, the effectiveness of the passive safety features. The characteristics that contribute to passive safety are discussed, with particular emphasis on decay heat removal systems, together with examples of Argonne's theoretical and experimental programs in this area
The US Advanced Liquid-Metal Reactor Program
International Nuclear Information System (INIS)
Brolin, E.C.
1992-01-01
Based on National Energy Strategy projections, utilities will be required to substantially increase electric generating capacity over the next 40 yr to meet economic growth requirements and replace retiring capacity. Although aggressive conservation measures can save up to 85 GW(electric), ∼195 GW(electric) of additional generating capcity will still be needed by 2010. Assuming startup of new plants around 2000, US Department of Energy (DOE) analyses show that nuclear power can contribute 195 GW(electric) of capacity by 2030, or ∼20% of total electric generation. The DOE is involved in a number of strategies designed to revitalize the nuclear power industry and enable it to meet this projected need for additional capacity. Among these is an integrated overall strategy for advanced reactor development and high-level waste management. A high priority in pursuit of this strategy is the Advanced Liquid-Metal Reactor (ALMR) Program
Safety characteristics of the US advanced liquid metal reactor core
International Nuclear Information System (INIS)
Magee, P.M.; Dubberley, A.E.; Gyorey, G.L.; Lipps, A.J.; Wu, T.
1991-01-01
The U.S. Advanced Liquid Metal Reactor (ALMR) design employs innovative, passive features to provide an unprecedented level of public safety and the ability to demonstrate this safety to the public. The key features employed in the core design to produce the desired passive safety characteristics are: a small core with a tight restraint system, the use of metallic U-Pu-Zr fuel, control rod withdrawal limiters, and gas expansion modules. In addition, the reactor vessel and closure are designed to have the capability to withstand, with large margins, the maximum possible core disruptive accident without breach and radiological release. (author)
Performance analysis of a mixed nitride fuel system for an advanced liquid metal reactor
International Nuclear Information System (INIS)
Lyon, W.F.; Baker, R.B.; Leggett, R.D.
1991-01-01
In this paper, the conceptual development and analysis of a proposed mixed nitride driver and blanket fuel system for a prototypic advanced liquid metal reactor design is performed. As a first step, an intensive literature survey is completed on the development and testing of nitride fuel systems. Based on the results of this survey, prototypic mixed nitride fuel and blanket pins is designed and analyzed using the SIEX computer code. The analysis predicts that the nitride fuel consistently operated at peak temperatures and cladding strain levels that compared quite favorably with competing fuel designs. These results, along with data available in the literature on nitride fuel performance, indicate that a nitride fuel system should offer enhanced capabilities for advanced liquid metal reactors
Performance analysis of a mixed nitride fuel system for an advanced liquid metal reactor
International Nuclear Information System (INIS)
Lyon, W.F.; Baker, R.B.; Leggett, R.D.
1990-11-01
The conceptual development and analysis of a proposed mixed nitride driver and blanket fuel system for a prototypic advanced liquid metal reactor design has been performed. As a first step, an intensive literature survey was completed on the development and testing of nitride fuel systems. Based on the results of this survey, prototypic mixed nitride fuel and blanket pins were designed and analyzed using the SIEX computer code. The analysis predicted that the nitride fuel consistently operated at peak temperatures and cladding strain levels that compared quite favorably with competing fuel designs. These results, along with data available in the literature on nitride fuel performance, indicate that a nitride fuel system should offer enhanced capabilities for advanced liquid metal reactors. 13 refs., 10 figs., 2 tabs
Progress of liquid metal technology and application in energy industries
International Nuclear Information System (INIS)
Miyazaki, Keiji; Kamei, Mitsuru; Nei, Hiromichi.
1990-01-01
Liquid metals are excellent energy transport media, and recently remarkable development has been observed in the technology of handling sodium and the machinery and equipment. In nuclear fusion, the development of the use of lithium as the coolant is advanced. For space technology, attention has been paid from the early stage to various liquid metals. For general industries, liquid metals have been used for high temperature heat pipes and the utilization of solar heat, and mercury vapor turbines were manufactured for trial. Besides, attention is paid anew to liquid metal MHD electric power generation. The development of the NaS batteries for electric cars and electric power storage and the interchange of liquid metal technology with the fields of iron and steel, metallurgy and so on advance. It is expected that liquid metal technology bears future advanced energy engineering while deepening the interchange with other advanced fields also in order to reactivate atomic energy technology. Liquid metals have the features of high electric and thermal conductivities, chemical activity and opaque property as metals, and fluidity and relatively high boiling point and melting point as liquids. FBRs, fusion reactors and the power sources for space use are described. (K.I.)
Advances in liquid metal cooled ADS systems, and useful results for the design of IFMIF
International Nuclear Information System (INIS)
Massaut, V.; Debruyn, D.; Decreton, M.
2007-01-01
Full text of publication follows: Liquid metal cooled Accelerator Driven Systems (ADS) have a lot of design commonalities with the design of IFMIF. The use of a powerful accelerator and a liquid metal spallation source makes it similar to the main features of the IFMIF irradiator. Developments in the field of liquid metal ADS can thus be very useful for the design phase of IFMIF, and synergy between both domains should be enhanced to avoid dubbing work already done. The liquid metal ADS facilities are developed for testing materials under high fast (> 1 MeV) neutron flux, and also for studying the transmutation of actinides as foreseen in the P and T (Partitioning and Transmutation) strategy of future fission industry. The ADS are mostly constituted of a sub-critical fission fuel assembly matrix, a spallation source (situated at the centre of the fuel arrangement) and a powerful accelerator targeting the spallation source. In liquid metal ADS, the spallation source is a liquid metal (like Pb-Bi) which is actively cooled to remove the power generated by the particle beam, spallation reactions and neutrons. Based on an advanced ADS design (e.g. the MYRRHA/XT-ADS facility), the paper shows the various topics which are common for both facilities (ADS and IFMIF) and highlights their respective specificities, leading to focused R and D activities. This would certainly cover the common aspects related to high power accelerators, liquid metal targets and beam-target coupling. But problems of safety, radioprotection, source heating and cooling, neutrons shielding, etc... lead also to common features and developments. Results already obtained for the ADS development will illustrate this synergy. This paper will therefore allow to take profit of recent developments in both fission and fusion programs and enhance the collaboration among the R and D teams in both domains. (authors)
Advances in liquid metal cooled ADS systems, and useful results for the design of IFMIF
Energy Technology Data Exchange (ETDEWEB)
Massaut, V.; Debruyn, D. [SCK CEN, Mol (Belgium); Decreton, M. [Ghent Univ., Dept. of Applied Physics (Belgium)
2007-07-01
Full text of publication follows: Liquid metal cooled Accelerator Driven Systems (ADS) have a lot of design commonalities with the design of IFMIF. The use of a powerful accelerator and a liquid metal spallation source makes it similar to the main features of the IFMIF irradiator. Developments in the field of liquid metal ADS can thus be very useful for the design phase of IFMIF, and synergy between both domains should be enhanced to avoid dubbing work already done. The liquid metal ADS facilities are developed for testing materials under high fast (> 1 MeV) neutron flux, and also for studying the transmutation of actinides as foreseen in the P and T (Partitioning and Transmutation) strategy of future fission industry. The ADS are mostly constituted of a sub-critical fission fuel assembly matrix, a spallation source (situated at the centre of the fuel arrangement) and a powerful accelerator targeting the spallation source. In liquid metal ADS, the spallation source is a liquid metal (like Pb-Bi) which is actively cooled to remove the power generated by the particle beam, spallation reactions and neutrons. Based on an advanced ADS design (e.g. the MYRRHA/XT-ADS facility), the paper shows the various topics which are common for both facilities (ADS and IFMIF) and highlights their respective specificities, leading to focused R and D activities. This would certainly cover the common aspects related to high power accelerators, liquid metal targets and beam-target coupling. But problems of safety, radioprotection, source heating and cooling, neutrons shielding, etc... lead also to common features and developments. Results already obtained for the ADS development will illustrate this synergy. This paper will therefore allow to take profit of recent developments in both fission and fusion programs and enhance the collaboration among the R and D teams in both domains. (authors)
Safety design analyses of Korea Advanced Liquid Metal Reactor
International Nuclear Information System (INIS)
Suk, S.D.; Park, C.K.
2000-01-01
The national long-term R and D program updated in 1997 requires Korea Atomic Energy Research Institute (KAERI) to complete by the year 2006 the basic design of Korea Advanced Liquid Metal Reactor (KALIMER), along with supporting R and D work, with the capability of resolving the issue of spent fuel storage as well as with significantly enhanced safety. KALIMER is a 150 MWe pool-type sodium cooled prototype reactor that uses metallic fuel. The conceptual design is currently under way to establish a self consistent design meeting a set of the major safety design requirements for accident prevention. Some of current emphasis include those for inherent and passive means of negative reactivity insertion and decay heat removal, high shutdown reliability, prevention of and protection from sodium chemical reaction, and high seismic margin, among others. All of these requirements affect the reactor design significantly and involve supporting R and D programs of substance. This paper summarizes some of the results of engineering and design analyses performed for the safety of KALIMER. (author)
Directory of Open Access Journals (Sweden)
Xuelin Wang
2016-11-01
Full Text Available This article presents an overview on typical properties, technologies, and applications of liquid metal based flexible printed electronics. The core manufacturing material—room-temperature liquid metal, currently mainly represented by gallium and its alloys with the properties of excellent resistivity, enormous bendability, low adhesion, and large surface tension, was focused on in particular. In addition, a series of recently developed printing technologies spanning from personal electronic circuit printing (direct painting or writing, mechanical system printing, mask layer based printing, high-resolution nanoimprinting, etc. to 3D room temperature liquid metal printing is comprehensively reviewed. Applications of these planar or three-dimensional printing technologies and the related liquid metal alloy inks in making flexible electronics, such as electronical components, health care sensors, and other functional devices were discussed. The significantly different adhesions of liquid metal inks on various substrates under different oxidation degrees, weakness of circuits, difficulty of fabricating high-accuracy devices, and low rate of good product—all of which are challenges faced by current liquid metal flexible printed electronics—are discussed. Prospects for liquid metal flexible printed electronics to develop ending user electronics and more extensive applications in the future are given.
Liquid metal thermal-hydraulics
International Nuclear Information System (INIS)
Kottowski-Duemenil, H.M.
1994-01-01
This textbook is a report of the 26 years activity of the Liquid Metal Boiling Working Group (LMBWG). It summarizes the state of the art of liquid metal thermo-hydraulics achieved through the collaboration of scientists concerned with the development of the Fast Breeder Reactor. The first chapter entitled ''Liquid Metal Boiling Behaviour'', presents the background and boiling mechanisms. This section gives the reader a brief but thorough survey on the superheat phenomena in liquid metals. The second chapter of the text, ''A Review of Single and Two-Phase Flow Pressure Drop Studies and Application to Flow Stability Analysis of Boiling Liquid Metal Systems'' summarizes the difficulty of pressure drop simulation of boiling sodium in core bundles. The third chapter ''Liquid Metal Dry-Out Data for Flow in Tubes and Bundles'' describes the conditions of critical heat flux which limits the coolability of the reactor core. The fourth chapter dealing with the LMFBR specific topic of ''Natural Convection Cooling of Liquid Metal Systems''. This chapter gives a review of both plant experiments and out-of-pile experiments and shows the advances in the development of computing power over the past decade of mathematical modelling ''Subassembly Blockages Suties'' are discussed in chapter five. Chapter six is entitled ''A Review of the Methods and Codes Available for the Calculation on Thermal-Hydraulics in Rod-Cluster and other Geometries, Steady state and Transient Boiling Flow Regimes, and the Validation achieves''. Codes available for the calculation of thermal-hydraulics in rod-clusters and other geometries are reviewed. Chapter seven, ''Comparative Studies of Thermohydraulic Computer Code Simulations of Sodium Boiling under Loss of Flow Conditions'', represents one of the key activities of the LMBWG. Several benchmark exercises were performed with the aim of transient sodium boiling simulation in single channels and bundle blockages under steady state conditions and loss of
Comparative sodium void effects for different advanced liquid metal reactor fuel and core designs
International Nuclear Information System (INIS)
Dobbin, K.D.; Kessler, S.F.; Nelson, J.V.; Gedeon, S.R.; Omberg, R.P.
1991-01-01
An analysis of metal-, oxide-, and nitride-fueled advanced liquid metal reactor cores was performed to investigate the calculated differences in sodium void reactivity, and to determine the relationship between sodium void reactivity and burnup reactivity swing using the three fuel types. The results of this analysis indicate that nitride fuel has the least positive sodium void reactivity for any given burnup reactivity swing. Thus, it appears that a good design compromise between transient overpower and loss of flow response is obtained using nitride fuel. Additional studies were made to understand these and other nitride advantages. (author)
Safety aspects of the US advanced LMR [liquid metal reactor] design
International Nuclear Information System (INIS)
Pedersen, D.R.; Gyorey, G.L.; Marchaterre, J.F.; Rosen, S.
1989-01-01
The cornerstones of the United States Advanced Liquid Metal Cooled Reactor (ALMR) program sponsored by the Department of Energy are: the plant design program at General Electric based on the PRISM (Power Reactor Innovative Small Module) concept, and the Integral Fast Reactor program (IFR) at Argonne National Laboratory (ANL). The goal of the US program is to produce a standard, commercial ALMR, including the associated fuel cycle. This paper discusses the US regulatory framework for design of an ALMR, safety aspects of the IFR program at ANL, the IFR fuel cycle and actinide recycle, and the ALMR plant design program at GE. 6 refs., 5 figs
Experimental testing facilities for ultrasonic measurements in heavy liquid metal
International Nuclear Information System (INIS)
Cojocaru, V.; Ionescu, V.; Nicolescu, D.; Nitu, A.
2016-01-01
The thermo-physical properties of Heavy Liquid Metals (HLM), like lead or its alloy, Lead Bismuth Eutectic (LBE), makes them attractive as coolant candidates in advanced nuclear systems. The opaqueness, that is common to all liquid metals, disables all optical methods. For this reason ultrasound waves are used in different applications in heavy liquid metal technology, for example for flow and velocity measurements and for inspection techniques. The practical use of ultrasound in heavy liquid metals still needs to be demonstrated by experiments. This goal requires heavy liquid metal technology facility especially adapted to this task. In this paper is presented an experimental testing facility for investigations of Heavy Liquid Metals acoustic properties, designed and constructed in RATEN ICN. (authors)
Ionic imbalance induced self-propulsion of liquid metals
Zavabeti, Ali; Daeneke, Torben; Chrimes, Adam F.; O'Mullane, Anthony P.; Zhen Ou, Jian; Mitchell, Arnan; Khoshmanesh, Khashayar; Kalantar-Zadeh, Kourosh
2016-08-01
Components with self-propelling abilities are important building blocks of small autonomous systems and the characteristics of liquid metals are capable of fulfilling self-propulsion criteria. To date, there has been no exploration regarding the effect of electrolyte ionic content surrounding a liquid metal for symmetry breaking that generates motion. Here we show the controlled actuation of liquid metal droplets using only the ionic properties of the aqueous electrolyte. We demonstrate that pH or ionic concentration gradients across a liquid metal droplet induce both deformation and surface Marangoni flow. We show that the Lippmann dominated deformation results in maximum velocity for the self-propulsion of liquid metal droplets and illustrate several key applications, which take advantage of such electrolyte-induced motion. With this finding, it is possible to conceive the propulsion of small entities that are constructed and controlled entirely with fluids, progressing towards more advanced soft systems.
Potential applications of robotics in advanced liquid-metal reactors
International Nuclear Information System (INIS)
Carroll, D.G.; Thompson, M.L.
1990-01-01
The advanced liquid-metal reactor (ALMR) design includes a range of robots and automation devices. They extend from stationary robots that are a part of the current design to more exotic concepts with mobile, autonomous units, which may become part of the design. Development of robotic application requirements is enhanced by using computer models of work spaces in three dimensions. The primary goals of the more autonomous machines are to: (1) extent and/or enhance one's capabilities in a hazardous environment; some tasks could encounter high temperatures (up to 800 degree F), high radiation (fields up to several hundred thousand roentgens per hour), rooms filled with inert gas and/or sodium aerosol, or combinations of these; (2) reduce operating and maintenance cost through inservice inspection (ISI) of various parts of the reactor, through consideration of as-low-as-reasonably achievable radiation levels, and through automation of some maintenance/processing operations. This paper discusses some applications in the fuel cycle, in refueling operations, and in inspection
Conceptual safety design analysis of Korea advanced liquid metal reactor
International Nuclear Information System (INIS)
Suk, S. D.; Park, C. K.
1999-01-01
The national long-term R and D program, updated in 1977, requires Korea Atomic Energy Research Institute (KAERI) to complete by the year 2006 the basic design of Korea Advanced Liquid Metal Reactor (KALIMER), along with supporting R and D work, with the capability of resolving the issue of spent fuel storage as well as with significantly enhanced safety. KALIMER is a 150 Mwe pool-type sodium cooled prototype reactor that uses metallic fuel. The conceptual design is currently under way to establish a self-consistent design meeting a set of major safety design requirements for accident prevention. Some of the current emphasis includes those for inherent and passive means of negative reactivity insertion and decay heat removal, high shutdown reliability, prevention of and protection from sodium chemical reaction, and high seismic margin, among others. All of these requirements affect the reactor design significantly and involve extensive supporting R and D programs. This paper summarizes some of the results of conceptual engineering and design analyses performed for the safety of KALIMER in the area of inherent safety, passive decay heat removal, sodium water reaction, and seismic isolation. (author)
A decade of advances in metallic fuel
International Nuclear Information System (INIS)
Lahm, C.E.; Pahl, R.G.; Porter, D.L.; Tsai, H.; Seidel, B.R.; Batte, G.L.; Dodds, N.E.; Hofman, G.L.; Walters, L.C.
1991-01-01
Significant advances in the understanding of behavior and performance of metallic fuels to high burnup have been achieved over the past four decades. Metallic fuels were the first fuels for liquid-metal-cooled fast reactors (LMR) but in the late 1960's worldwide interest turned toward ceramic fuels before the full potential of metallic fuel could be achieved. Now metallic fuels are recognized as a preferred viable option with regard to safety, integral fuel cycle, waste minimization and deployment economics. This paper reviews the key advances in the last decade and highlights the behavior and performance features which have demonstrated a much greater potential than previously expected
Wang, Xiao-Dong; Jiang, Jian-Zhong
2017-11-01
The relationship between the structural evolution and properties of metallic liquids is a long-standing hot issue in condensed-matter physics and materials science. Here, recent progress is reviewed in several fundamental aspects of metallic liquids, including the methods to study their atomic structures, liquid-liquid transition, physical properties, fragility, and their correlations with local structures, together with potential applications of liquid metals at room temperature. Involved with more experimentally and theoretically advanced techniques, these studies provide more in-depth understanding of the structure-property relationship of metallic liquids and promote the design of new metallic materials with superior properties. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
International Nuclear Information System (INIS)
Burstein, S.; Gibbons, J.P.; High, M.D.; O'Boyle, D.R.; Pickens, T.A.; Pilmer, D.F.; Tomonto, J.R.; Weinberg, C.J.
1990-02-01
A team of utility industry representatives evaluated the liquid metal reactor metal fuel process and facility conceptual design being developed by Argonne National Laboratory (ANL) under Department of Energy sponsorship. The utility team concluded that a highly competent ANL team was making impressive progress in developing high performance advanced metal fuel and an economic processing and fabrication technology. The utility team concluded that the potential benefits of advanced metal fuel justified the development program, but that, at this early stage, there are considerable uncertainties in predicting the net overall economic benefit of metal fuel. Specific comments and recommendations are provided as a contribution towards enhancing the development program. 6 refs
A decade of advances in metallic fuel
International Nuclear Information System (INIS)
Seidel, B.R.; Batte, G.L.; Dodds, N.E.; Hofman, G.L.; Lahm, C.E.; Pahl, R.G.; Porter, D.L.; Tsai, H.; Walters, L.C.
1990-01-01
Significant advances in the understanding of behavior and performance of metallic fuels to high burnup have been achieved over the past four decades. Metallic fuels were the first fuels for liquid-metal-cooled fast reactors (LMR) but in the late 1960s worldwide interest turned toward ceramic fuels before the full potential of metallic fuel could be achieved. Now metallic fuels are recognized as a preferred viable option with regard to safety, integral fuel cycle, waste minimization and deployment economics. This paper reviews the key advances in the last decade and highlights the behavior and performance features which have demonstrated a much greater potential than previously expected. 28 refs., 2 figs., 1 tab
Application of probabilistic risk assessment to advanced liquid metal reactor designs
International Nuclear Information System (INIS)
Carroll, W.P.; Temme, M.I.
1987-01-01
The United States Department of Energy (US DOE) has been active in the development and application of probabilistic risk assessment methods within its liquid metal breeder reactor development program for the past eleven years. These methods have been applied to comparative risk evaluations, the selection of design features for reactor concepts, the selection and emphasis of research and development programs, and regulatory discussions. The application of probabilistic methods to reactors which are in the conceptual design stage presents unique data base, modeling, and timing challenges, and excellent opportunities to improve the final design. We provide here the background and insights on the experience which the US DOE liquid metal breeder reactor program has had in its application of probabilistic methods to the Clinch River Breeder Reactor Plant project, the Conceptual Design State of the Large Development Plant, and updates on this design. Plans for future applications of probabilistic risk assessment methods are also discussed. The US DOE is embarking on an innovative design program for liquid metal reactors. (author)
Status of development and licensing support for advanced liquid metal reactors in the United States
Energy Technology Data Exchange (ETDEWEB)
Pedersen, D R [Argonne National Laboratory, Argonne, IL (United States); Gyorey, G [General Electric, San Jose, CA (United States)
1991-07-01
The cornerstones of the United States Advanced Liquid Metal Cooled Reactor (ALMR) program sponsored by the Department of Energy are: the ALMR plant design program at General Electric based on the PRISM (Power Reactor Innovative Small Module) concept, and the Integral Fast Reactor program (IFR) at Argonne National Laboratory (ANL). The goal of the U.S. program is to produce a standard, commercial ALMR, including the associated fuel cycle. The paper addresses the status of the IFR program, the ALMR program and the interaction of the ALMR program with the regulatory environment. (author)
Status of development and licensing support for advanced liquid metal reactors in the United States
International Nuclear Information System (INIS)
Pedersen, D.R.; Gyorey, G.
1991-01-01
The cornerstones of the United States Advanced Liquid Metal Cooled Reactor (ALMR) program sponsored by the Department of Energy are: the ALMR plant design program at General Electric based on the PRISM (Power Reactor Innovative Small Module) concept, and the Integral Fast Reactor program (IFR) at Argonne National Laboratory (ANL). The goal of the US program is to produce a standard, commercial ALMR, including the associated fuel cycle. The paper addresses the status of the IFR program, the ALMR program and the interaction of the ALMR program with the regulatory environment
Status of development and licensing support for advanced liquid metal reactors in the United States
International Nuclear Information System (INIS)
Pedersen, D.R.; Gyorey, G.
1991-01-01
The cornerstones of the United States Advanced Liquid Metal Cooled Reactor (ALMR) program sponsored by the Department of Energy are: the ALMR plant design program at General Electric based on the PRISM (Power Reactor Innovative Small Module) concept, and the Integral Fast Reactor program (IFR) at Argonne National Laboratory (ANL). The goal of the U.S. program is to produce a standard, commercial ALMR, including the associated fuel cycle. The paper addresses the status of the IFR program, the ALMR program and the interaction of the ALMR program with the regulatory environment. (author)
International Nuclear Information System (INIS)
Hundal, R.
1976-01-01
A cold trap assembly for removing impurities from a liquid metal is described. A hole between the incoming impure liquid metal and purified outgoing liquid metal acts as a continuous bleed means and thus prevents the accumulation of cover gases within the cold trap assembly
Sheng, Lei; Zhang, Jie; Liu, Jing
2014-01-01
The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series...
International Nuclear Information System (INIS)
Wolowodiuk, W.
1975-01-01
A liquid metal heated steam generator is described which in the event of a tube failure quickly exhausts out of the steam generator the products of the reaction between the water and the liquid metal. The steam is generated in a plurality of bayonet tubes which are heated by liquid metal flowing over them between an inner cylinder and an outer cylinder. The inner cylinder extends above the level of liquid metal but below the main tube sheet. A central pipe extends down into the inner cylinder with a centrifugal separator between it and the inner cylinder at its lower end and an involute deflector plate above the separator so that the products of a reaction between the liquid metal and the water will be deflected downwardly by the deflector plate and through the separator so that the liquid metal will flow outwardly and away from the central pipe through which the steam and gaseous reaction products are exhausted. (U.S.)
Technology which led to the westinghouse inherently safe liquid metal reactor
International Nuclear Information System (INIS)
Schmidt, J.E.; Coffield, R.D.; Doncals, R.A.; Kalinowski, J.E.; Markley, R.A.
1985-01-01
The Fast Flux Test Facility (FFTF) and the Clinch River Breeder Reactor programs resulted in an understanding of liquid metal reactor behavior that is being used to design inherent safety capability into liquid metal reactors. Technological advances give the same beneficial operating characteristics of conventional liquid metal reactors, however, the addition of inherently safe design features precludes the initiation of hypothetical core disruptive accidents. These innovative features permit inherent safety capability to be demonstrated with more than adequate margins. Also, the variety of inherent safety features provides the designers with options in selecting inherent design features for a specific reactor application
Liquid metal purification device
International Nuclear Information System (INIS)
Sakai, Takao; Shimoyashiki, Shigehiro.
1992-01-01
The device of the present invention concerns a liquid metal purification device for removing and purifying impuries in liquid metal sodium used as coolants of an FBR type reactor. A vessel having a group of pipes made of hydrogen permeable metal at the inside thereof is disposed to the inlet pipeline of a cold trap. The group of hydrogen permeable metal pipes is connected to an exhaust pipe and a vacuum pump, so that the inside of the pipes is exhausted. Liquid metal sodium branched from the main pipeline of a coolant system passes through the outer side of the group of the hydrogen permeable metal pipes. In this cae, hydrogen contained as impurities in the liquid metal sodium diffuses and permeates the hydrogen permeation metal pipes and enters into the pipe group and is discharged out of the system by the vacuum pump. This can mitigate the hydrogen removing burden of the cold trap, to extend the device life time. (I.N.)
International Nuclear Information System (INIS)
Wootan, D.W.; Omberg, R.P.
2015-01-01
Significant cost and safety improvements can be realized in advanced liquid metal reactor (LMR) designs by emphasizing inherent or passive safety through crediting the beneficial reactivity feedbacks associated with core and structural movement. This passive safety approach was adopted for the Fast Flux Test Facility (FFTF), and an experimental program was conducted to characterize the structural reactivity feedback. Testing at the Rapsodie and EBR-II reactors had demonstrated the beneficial effect of reactivity feedback caused by changes in fuel temperature and core geometry mechanisms in a liquid metal fast reactor in a holistic sense. The FFTF passive safety testing program was developed to examine how specific design elements influenced dynamic reactivity feedback in response to a reactivity input and to demonstrate the scalability of reactivity feedback results from smaller cores like Rapsodie and EBR-II to reactor cores that were more prototypic in scale to reactors of current interest. The U.S. Department of Energy, Office of Nuclear Energy Advanced Reactor Technology program is in the process of preserving, protecting, securing, and placing in electronic format information and data from the FFTF, including the core configurations and data collected during the passive safety tests. Evaluation of these actual test data could provide insight to improve analytical methods which may be used to support future licensing applications for LMRs. (authors)
US/DOE Man-Machine Integration program for liquid metal reactors
International Nuclear Information System (INIS)
D'Zmura, A.P.; Seeman, S.E.
1985-03-01
The United States Department of Energy (DOE) Man-Machine Integration program was started in 1980 as an addition to the existing Liquid Metal Fast Breeder Reactor safety base technology program. The overall goal of the DOE program is to enhance the operational safety of liquid metal reactors by optimum integration of humans and machines in the overall reactor plant system and by application of the principles of human-factors engineering to the design of equipment, subsystems, facilities, operational aids, procedures and environments. In the four years since its inception the program has concentrated on understanding the control process for Liquid Metal Reactors (LMRs) and on applying advanced computer concepts to this process. This paper describes the products that have been developed in this program, present computer-related programs, and plans for the future
The US Liquid Metal Reactor Development Program
International Nuclear Information System (INIS)
Till, C.E.; Arnold, W.H.; Griffith, J.D.
1988-01-01
The US Liquid Metal Reactor Development Program has been restructured to take advantage of the opportunity today to carry out R and D on truly advanced reactor technology. The program gives particular emphasis to improvements to reactor safety. The new directions are based on the technology of the Integral Fast Reactor (IFR). Much of the basis for superior safety performance using IFR technology has been experimentally verified and aggressive programs continue in EBR-II and TREAT. Progress has been made in demonstrating both the metallic fuel and the new electrochemical processes of the IFR. The FFTF facility is converting to metallic fuel; however, FFTF also maintains a considerable US program in oxide fuels. In addition, generic programs are continuing in steam generator testing, materials development, and, with international cooperation, aqueous reprocessing. Design studies are carried out in conjunction with the IFR technology development program. In summary, the US maintains an active development program in Liquid Metal Reactor technology, and new directions in reactor safety are central to the program
The chemistry of the liquid alkali metals
International Nuclear Information System (INIS)
Addison, C.C.
1984-01-01
A study of liquid alkali metals. It encourages comparison with molecular solvents in chapter covering the nature and reactivity of dissolved species, solvation, solubility and electrical conductivity of solutions. It demonstrates lab techniques unique to liquid alkali metals. It discusses large-scale applications from storage batteries to sodium-cooled reactors and future fusion reactors, and associated technological problems. Contents: Some Basic Physical and Chemical Properties; Manipulation of the Liquids; The Chemistry of Purification Methods; Species Formed by Dissolved Elements; Solubilities and Analytical Methods; Alkali Metal Mixtures; Solvation in Liquid Metal; Reactions Between Liquid Alkali Metals and Water; Reactions of Nitrogen with Lithium and the Group II Metals in Liquid Sodium; The Formation, Dissociation and Stability of Heteronuclear Polyatomic Anions; Reactions of the Liquid Alkali Metals and Their Alloys with Simple Alipatic Hydrocarbons; Reactions of the Liquid Alkali Metals with Some Halogen Compounds; Hydrogen, Oxygen and Carbon Meters; Surface Chemistry and Wetting; Corrosion of Transition Metals by the Liquid Alkali Metals; Modern Applications of the Liquid Alkali Metals
International Nuclear Information System (INIS)
Le Frere, J.P.
1984-01-01
Pumps used to pump liquid metals depend on the liquid metal and on the type of application concerned. One deals more particularly with electromagnetic pumps, the main pumps used with mechanical pumps. To pump sodium in the nuclear field, these two types of pumps are used; the pumps of different circuits of Super Phenix are presented and described [fr
Liquid Metals as Plasma-facing Materials for Fusion Energy Systems: From Atoms to Tokamaks
Energy Technology Data Exchange (ETDEWEB)
Stone, Howard A. [Princeton Univ., NJ (United States); Koel, Bruce E. [Princeton Univ., NJ (United States); Bernasek, Steven L. [Princeton Univ., NJ (United States); Carter, Emily A. [Princeton Univ., NJ (United States); Debenedetti, Pablo G. [Princeton Univ., NJ (United States); Panagiotopoulos, Athanassios Z. [Princeton Univ., NJ (United States)
2017-06-23
The objective of our studies was to advance our fundamental understanding of liquid metals as plasma-facing materials for fusion energy systems, with a broad scope: from atoms to tokamaks. The flow of liquid metals offers solutions to significant problems of the plasma-facing materials for fusion energy systems. Candidate metals include lithium, tin, gallium, and their eutectic combinations. However, such liquid metal solutions can only be designed efficiently if a range of scientific and engineering issues are resolved that require advances in fundamental fluid dynamics, materials science and surface science. In our research we investigated a range of significant and timely problems relevant to current and proposed engineering designs for fusion reactors, including high-heat flux configurations that are being considered by leading fusion energy groups world-wide. Using experimental and theoretical tools spanning atomistic to continuum descriptions of liquid metals, and bridging surface chemistry, wetting/dewetting and flow, our research has advanced the science and engineering of fusion energy materials and systems. Specifically, we developed a combined experimental and theoretical program to investigate flows of liquid metals in fusion-relevant geometries, including equilibrium and stability of thin-film flows, e.g. wetting and dewetting, effects of electromagnetic and thermocapillary fields on liquid metal thin-film flows, and how chemical interactions and the properties of the surface are influenced by impurities and in turn affect the surface wetting characteristics, the surface tension, and its gradients. Because high-heat flux configurations produce evaporation and sputtering, which forces rearrangement of the liquid, and any dewetting exposes the substrate to damage from the plasma, our studies addressed such evaporatively driven liquid flows and measured and simulated properties of the different bulk phases and material interfaces. The range of our studies
International Nuclear Information System (INIS)
Caldwell-Nichols, C.J.; Roach, P.F.
1982-01-01
A liquid metal monitor of the by-pass plugging meter kind described in British Patent 1,308,466, is further provided with a pump arranged to oppose flow through a by-pass thereby to provide a constant pressure difference across an orifice and improve the sensitivity of the instrument. The monitor estimates the impurity content in a liquid metal stream. (author)
Actively convected liquid metal divertor
International Nuclear Information System (INIS)
Shimada, Michiya; Hirooka, Yoshi
2014-01-01
The use of actively convected liquid metals with j × B force is proposed to facilitate heat handling by the divertor, a challenging issue associated with magnetic fusion experiments such as ITER. This issue will be aggravated even more for DEMO and power reactors because the divertor heat load will be significantly higher and yet the use of copper would not be allowed as the heat sink material. Instead, reduced activation ferritic/martensitic steel alloys with heat conductivities substantially lower than that of copper, will be used as the structural materials. The present proposal is to fill the lower part of the vacuum vessel with liquid metals with relatively low melting points and low chemical activities including Ga and Sn. The divertor modules, equipped with electrodes and cooling tubes, are immersed in the liquid metal. The electrode, placed in the middle of the liquid metal, can be biased positively or negatively with respect to the module. The j × B force due to the current between the electrode and the module provides a rotating motion for the liquid metal around the electrodes. The rise in liquid temperature at the separatrix hit point can be maintained at acceptable levels from the operation point of view. As the rotation speed increases, the current in the liquid metal is expected to decrease due to the v × B electromotive force. This rotating motion in the poloidal plane will reduce the divertor heat load significantly. Another important benefit of the convected liquid metal divertor is the fast recovery from unmitigated disruptions. Also, the liquid metal divertor concept eliminates the erosion problem. (letter)
Mechanisms of liquid-metal embrittlement
International Nuclear Information System (INIS)
Popovich, V.V.
1979-01-01
The mechanism of the embrittlement of metals and alloys during deformation in contact with liquid metals are discussed. With 20Kh13 steel in a Pb-Sn melt and polycrystalline Al in the presence of various mercury solutions a.s examples, considered are the three main processes - adsorption, corrosion (dissolution), formation of new phases which cause the disintegration of materials under the action of liquid-metallic media. Presented are data on plastic ductile and strength properties of the above materials in the presence of liquid-metallic media. A model is described that takes into account the effect of the medium upon the plastic deformation and the part the medium plays in liquid-metallic embrittlement
Application of liquid metals for the extraction of solid metals
International Nuclear Information System (INIS)
Borgstedt, H.U.
1996-01-01
Liquid metals dissolve several solid metals in considerable amounts at moderate temperatures. The dissolution processes may be based upon simple physical solubility, formation of intermetallic phases. Even chemical reactions are often observed in which non-metallic elements might be involved. Thus, the capacity to dissolve metals and chemical properties of the liquid metals play a role in these processes. Besides the solubility also chemical properties and thermochemical data are of importance. The dissolution of metals in liquid metals can be applied to separate the solutes from other metals or non-metallic phases. Relatively noble metals can be chemically reduced by the liquid phases. Such solution processes can be applied in the extractive metallurgy, for instance to extract metals from metallic waste. The recycling of metals is of high economical and ecological importance. Examples of possible processes are discussed. (author)
Energy Technology Data Exchange (ETDEWEB)
Watanabe, T
1968-05-22
In a pipe system which transfers liquid metal, inert gas (cover gas) is packed above the surface of the liquid metal to prevent oxidization of the liquid. If the metal vapor is contained in such cover gas, the circulating system of the cover gas is blocked due to condensation of liquid metal inside the system. The present invention relates to an improvement in vapor trap to remove the metal vapor from the cover gas. The trap consists of a cylindrical outer body, an inlet nozzle which is deeply inserted inside the outer body and has a number of holes to inject the cove gas into the body, metal mesh or steel wool which covers the exterior of the nozzle and on which the condensation of the metal gas takes place, and a heater wire hich is wound around the nozzle to prevent condensation of the metal vapor at the inner peripheral side of the mesh.
Safety aspects of LMR [liquid metal-cooled reactor] core design
International Nuclear Information System (INIS)
Cahalan, J.E.
1986-01-01
Features contributing to increased safety margins in liquid metal-cooled reactor (LMR) design are identified. The technical basis is presented for the performance of a pool-type reactor system with an advanced metallic alloy fuel in unprotected accidents. Results are presented from analyses of anticipated transients without scram, including loss-of-flow (LOF), transient overpower (TOP), and loss-of-heat-sink (LOHS) accidents
Liquid metal Flow Meter - Final Report
Energy Technology Data Exchange (ETDEWEB)
Andersen, C.; Hoogendoom, S.; Hudson, B.; Prince, J.; Teichert, K.; Wood, J.; Chase, K.
2007-01-30
Measuring the flow of liquid metal presents serious challenges. Current commercially-available flow meters use ultrasonic, electromagnetic, and other technologies to measure flow, but are inadequate for liquid metal flow measurement because of the high temperatures required by most liquid metals. As a result of the reactivity and high temperatures of most liquid metals, corrosion and leakage become very serious safety concerns. The purpose of this project is to develop a flow meter for Lockheed Martin that measures the flow rate of molten metal in a conduit.
Multipurpose sampler device for liquid metal
International Nuclear Information System (INIS)
Nelson, P.A.; Kolba, V.M.; Holmes, J.T.
1975-01-01
A device for collecting samples or examining a flow of liquid metal is provided for use with such as a liquid-metal-cooled nuclear reactor. The sampler device includes a casing surrounded by an external heater for establishing an upper isothermal zone and a lower zone for heating the entering liquid metal. One of various inserts is suspended into the isothermal zone where it is surrounded by a shroud tube for directing liquid-metal flow from the heating zone into the top of the insert. Discharge flow from the insert gravitates through a helically wound tube in heat exchange contact with entering liquid-metal flow within the heating zone. The inserts comprise an overflow cup with upper and lower freeze seals, a filter for removing particulate matter, and a fixture for maintaining various sample materials in equilibrium with liquid-metal flow. (U.S.)
International Nuclear Information System (INIS)
Cha, Kyung Ho; Park, Gun Ok; Suh, Sang Moon; Kim, Jang Yeol; Kwon, Kee Choon
1998-01-01
The DAta management and Communication NETworks(DACONET), which it is designed as a subsystem for Man-Machine Interface System of Korea Advanced LIquid MEtal Reactor(KALIMER MMIS) and advanced design concept is approached, is described. The DACONET has its roles of providing the real-time data transmission and communication paths between MMIS systems, providing the quality data for protection, monitoring and control of KALIMER and logging the static and dynamic behavioral data during KALIMER operation. The DACONET is characterized as the distributed real-time system architecture with high performance. Future direction, in which advanced technology is being continually applied to Man-Machine Interface System development and communication networks of KALIMER MMIS
Energy Technology Data Exchange (ETDEWEB)
Cha, Kyung Ho; Park, Gun Ok; Suh, Sang Moon; Kim, Jang Yeol; Kwon, Kee Choon [KAERI, Taejon (Korea, Republic of)
1998-05-01
The DAta management and Communication NETworks(DACONET), which it is designed as a subsystem for Man-Machine Interface System of Korea Advanced LIquid MEtal Reactor(KALIMER MMIS) and advanced design concept is approached, is described. The DACONET has its roles of providing the real-time data transmission and communication paths between MMIS systems, providing the quality data for protection, monitoring and control of KALIMER and logging the static and dynamic behavioral data during KALIMER operation. The DACONET is characterized as the distributed real-time system architecture with high performance. Future direction, in which advanced technology is being continually applied to Man-Machine Interface System development and communication networks of KALIMER MMIS.
The thermophysical properties of metallic liquids
Iida, Takamichi
2015-01-01
The main purpose of materials science and engineering is to make the best use of all the elements in the periodic table. This leads to the effective use and conservation of natural resources. For this purpose, in any liquid metallic processing operation, accurate data for the thermophysical properties of all metallic liquids (i.e. liquid metals, semimetals, and semiconductors) is needed. However, in addition, a clear understanding of the essence of their thermophysical properties, based on these data, is indispensable. The second volume continues from the first volume to provide explanations for the thermophysical properties of metallic liquids. The two volumes identify new dimensionless parameters, extracted from the velocity of sound. In spite of being simple parameters, they provide useful information on the nature and behaviour of metallic liquids. This volume covers several basic concepts needed to understand the thermophysical properties of metallic liquids and for developing reliable models to accurate...
Advanced liquid metal reactor development at Argonne National Laboratory during the 1980s
International Nuclear Information System (INIS)
Wade, D.C.
1990-01-01
Argonne National Laboratory's (ANL'S) effort to pursue the exploitation of liquid metal cooled reactor (LMR) characteristics has given rise to the Integral Fast Reactor (IFR) concept, and has produced substantial technical advancement in concept implementation which includes demonstration of high burnup capability of metallic fuel, demonstration of injection casting fabrication, integral demonstration of passive safety response, and technical feasibility of pyroprocessing. The first half decade of the 90's will host demonstration of the IFR closed fuel cycle technology at the prototype scale. The EBR-II reactor will be fueled with ternary alloy fuel in HT-9 cladding and ducts, and pyroprocessing and injection casting refabrication of EBR-II fuel will be conducted using near-commercial sized equipment at the Fuel cycle Facility (FCF) which is co-located adjacent to EBR-II. Demonstration will start in 1992. The demonstration of passive safety response achievable with the IFR design concept, (already done in EBR-II in 1986) will be repeated in the mid 90's using the IFR prototype recycle fuel from the FCF. The demonstration of scrubbing of the reprocessing fission product waste stream, with recycle of the transuranics to the reactor for consumption, will also occur in the mid 90's. 30 refs
Water tube liquid metal control
International Nuclear Information System (INIS)
Campbell, J.W.E.
1981-01-01
An improved heat exchanger for use in liquid metal cooled nuclear power reactors is described in which the heat is transferred between the flow of liquid metal which is to be cooled and a forced flow of liquid which is wholly or partly evaporated. (U.K.)
The PFR challenge: how to dispose of 1500t of liquid metal
International Nuclear Information System (INIS)
Anon.
1996-01-01
The decommissioning of liquid metal cooled FBRs presents many interesting challenges requiring innovative engineering solutions. In advance of the Prototype Fast Reactor (PFR) at Dounreay in Scotland being shut down in 1994 the owners, UKAEA, commissioned a series of risk and cost assessment studies to determine the least risk, lowest cost long term strategy. This concluded that a priority was safe disposal of the large inventories of liquid metal coolant. UK companies were invited to take up the challenge. (author)
Liquid metal cooling of synchrotron optics
International Nuclear Information System (INIS)
Smither, R.K.
1993-01-01
The installation of insertion devices at existing synchrotron facilities around the world has stimulated the development of new ways to cool the optical elements in the associated x-ray beamlines. Argonne has been a leader in the development of liquid metal cooling for high heat load x-ray optics for the next generation of synchrotron facilities. The high thermal conductivity, high volume specific heat, low kinematic viscosity, and large working temperature range make liquid metals a very efficient heat transfer fluid. A wide range of liquid metals were considered in the initial phase of this work. The most promising liquid metal cooling fluid identified to date is liquid gallium, which appears to have all the desired properties and the fewest number of undesired features of the liquid metals examined. Besides the special features of liquid metals that make them good heat transfer fluids, the very low vapor pressure over a large working temperature range make liquid gallium an ideal cooling fluid for use in a high vacuum environment. A leak of the liquid gallium into the high vacuum and even into very high vacuum areas will not result in any detectable vapor pressure and may even improve the vacuum environment as the liquid gallium combines with any water vapor or oxygen present in the system. The practical use of a liquid metal for cooling silicon crystals and other high heat load applications depends on having a convenient and efficient delivery system. The requirements for a typical cooling system for a silicon crystal used in a monochromator are pumping speeds of 2 to 5 gpm (120 cc per sec to 600 cc per sec) at pressures up to 100 psi. No liquid metal pump with these capabilities was available commercially when this project was started, so it was necessary to develop a suitable pump in house
Chemistry and physics at liquid alkali metal/solid metal interfaces
International Nuclear Information System (INIS)
Barker, M.G.
1977-01-01
This paper describes the chemistry of processes which take place at the interface between liquid alkali metals and solid metal surfaces. A brief review of wetting data for liquid sodium is given and the significance of critical wetting temperatures discussed on the basis of an oxide-film reduction mechanism. The reactions of metal oxides with liquid metals are outlined and a correlation with wetting data established. The transfer of dissolved species from the liquid metal across the interface to form solid phases on the solid metal surface is well recognised. The principal features of such processes are described and a simple thermodynamic explanation is outlined. The reverse process, the removal of solid material into solution, is also considered. (author)
Heat transfer on liquid-liquid interface of molten-metal and water
International Nuclear Information System (INIS)
Tanaka, T.; Saito, Yasushi; Mishima, Kaichiro
2001-01-01
Molten-core pool had been formed in the lower-head of TMI-2 pressure vessel at the severe accident. The lower head, however, didn't receive any damage by reactor core cooling. Heat transfer at outside of the lower head and boiling heat transfer at liquid-liquid interface of molten-metal and water, however, are important for initial cooling process of the molten-core pool. The heat transfer experiments for the liquid-liquid interface of molten-metal and water are carried out over the range of natural convection to film boiling region. Phenomenon on the heat transfer experiments are visualized by using of high speed video camera. Wood's metal and U-alloy 78 are used as molten-metal. The test section of the experiments consists of a copper block with heater, wood's metal, and water. Three thermocouple probes are used for temperature measurement of water side and the molten-metal side. Stability of the liquid-liquid interface is depended on the wetness of container wall for molten metal and the temperature distribution of the interface. Entrainment phenomena of molten-metal occurs by a fluctuation of the interface after boiling on the container wall surface. The boiling curves obtained from the liquid-liquid interface experiments are agree with the nucleate boiling and the film boiling correlations of solid-liquid system. (Suetake, M.)
FLIT: Flowing LIquid metal Torus
Kolemen, Egemen; Majeski, Richard; Maingi, Rajesh; Hvasta, Michael
2017-10-01
The design and construction of FLIT, Flowing LIquid Torus, at PPPL is presented. FLIT focuses on a liquid metal divertor system suitable for implementation and testing in present-day fusion systems, such as NSTX-U. It is designed as a proof-of-concept fast-flowing liquid metal divertor that can handle heat flux of 10 MW/m2 without an additional cooling system. The 72 cm wide by 107 cm tall torus system consisting of 12 rectangular coils that give 1 Tesla magnetic field in the center and it can operate for greater than 10 seconds at this field. Initially, 30 gallons Galinstan (Ga-In-Sn) will be recirculated using 6 jxB pumps and flow velocities of up to 10 m/s will be achieved on the fully annular divertor plate. FLIT is designed as a flexible machine that will allow experimental testing of various liquid metal injection techniques, study of flow instabilities, and their control in order to prove the feasibility of liquid metal divertor concept for fusion reactors. FLIT: Flowing LIquid metal Torus. This work is supported by the US DOE Contract No. DE-AC02-09CH11466.
Metal extraction by solid-liquid agglomerates
International Nuclear Information System (INIS)
Fuller, E.F.
1980-01-01
Dissolved metal values are extracted from a liquid e.g. uranium from phosphoric acid by contacting the liquid with agglomerates for a time to load the agglomerate with the metal value, separating the loaded agglomerates from the liquid phase and stripping the metal value from the loaded agglomerate. The agglomerate may be made by combining finely divided solid particles with a binding liquid to form a paste, adding a suspending liquid to form a mixture, the suspending liquid and binding liquid being immiscible in each other and the solid particles being insoluble in the suspending liquid and shearing the mixture to form the agglomerate. (author)
Liquid metals: fundamentals and applications in chemistry.
Daeneke, T; Khoshmanesh, K; Mahmood, N; de Castro, I A; Esrafilzadeh, D; Barrow, S J; Dickey, M D; Kalantar-Zadeh, K
2018-04-03
Post-transition elements, together with zinc-group metals and their alloys belong to an emerging class of materials with fascinating characteristics originating from their simultaneous metallic and liquid natures. These metals and alloys are characterised by having low melting points (i.e. between room temperature and 300 °C), making their liquid state accessible to practical applications in various fields of physical chemistry and synthesis. These materials can offer extraordinary capabilities in the synthesis of new materials, catalysis and can also enable novel applications including microfluidics, flexible electronics and drug delivery. However, surprisingly liquid metals have been somewhat neglected by the wider research community. In this review, we provide a comprehensive overview of the fundamentals underlying liquid metal research, including liquid metal synthesis, surface functionalisation and liquid metal enabled chemistry. Furthermore, we discuss phenomena that warrant further investigations in relevant fields and outline how liquid metals can contribute to exciting future applications.
Pair potentials in liquid metals
International Nuclear Information System (INIS)
Faber, T.E.
1980-01-01
The argument which justifies the use of a pair potential to describe the structure-dependent term in the energy of liquid metals is briefly reviewed. Because there is an additional term in the energy which depends upon volume rather than structure, and because the pair potential itself is volume-dependent, the relationship between pair potential and observable properties such as pressure, bulk modulus and pair distribution function is more complicated for liquid metals than it is for molecular liquids. Perhaps for this reason, the agreement between pair potentials inferred from observable properties and pair potentials calculated by means of pseudo-potential theory is still far from complete. The pair potential concept is applicable only to simple liquid metals, in which the electron-ion interaction is weak. No attempt is made to discuss liquid transition and rare-earth metals, which are not simple in this sense. (author)
International Nuclear Information System (INIS)
King, T.L.; Landry, R.R.; Throm, E.D.; Wilson, J.N.
1991-12-01
This safety evaluation report (SER) presents the final results of a preapplication design review for the Sodium Advanced Fast Reactor (SAFR) liquid metal reactor (Project 673). The SAFR conceptual design was submitted by the US Department of Energy (DOE) in accordance with the US Nuclear Regulatory Commission (NRC) ''Statement of Policy for the Regulation of Advanced Nuclear Power Plants'' (51 FR 24643 which provides for the early Commission review and interaction). The standard SAFR plant design consists of four identical reactor modules, referred to as ''paks,'' each with a thermal output rating of 900 MWt, coupled with four steam turbine-generator sets. The total electrical output was held to be 1400 MWe. This SER represents the NRC staff's preliminary technical evaluation of the safety features in the SAFR design. It must be recognized that final conclusions in all matters discussed in this SER require approval by the Commission. During the NRC staff review of the SAFR conceptual design, DOE terminated work on this design in September 1988. This SER documents the work done to that date and no additional work is planned for the SAFR
International Nuclear Information System (INIS)
Pennell, W.E.
1981-01-01
A liquid metal pump comprising a shaft support structure which is isolated from the pump housing for better preservation of alignment of shaft bearings. The shaft carries an impeller and the support structure carries an impeller cage which is slidably disposed in a diffuser so as to allow complete removal of pump internals for inspection and repair. The diffuser is concentrically supported in the pump housing which also takes up all reaction forces generated by the discharge of the liquid metal from the diffuser, with floating seals arranged between impeller cage and the diffuser. The space between the diffuser and the pump housing permits the incoming liquid to essentially surround the diffuser. (author)
International Nuclear Information System (INIS)
Van Tuyle, G.J.; Slovik, G.C.; Chan, B.C.; Kennett, R.J.; Cheng, H.S.; Kroeger, P.G.
1989-10-01
In support of the US Nuclear Regulatory Commission (NRC), Brookhaven National Laboratory (BNL) has performed independent analyses of two advanced Liquid Metal Reactor (LMR) concepts. The designs, sponsored by the US Department of Energy (DOE), the Power Reactor Inherently Safe Module (PRISM) [Berglund, 1987] and the Sodium Advanced Fast Reactor (SAFR) [Baumeister, 1987], were developed primarily by General Electric (GE) and Rockwell International (RI), respectively. Technical support was provided to DOE, RI, and GE, by the Argonne National Laboratory (ANL), particularly with respect to the characteristics of the metal fuels. There are several examples in both PRISM and SAFR where inherent or passive systems provide for a safe response to off-normal conditions. This is in contrast to the engineered safety systems utilized on current US Light Water Reactor (LWR) designs. One important design inherency in the LMRs is the ''inherent shutdown'', which refers to the tendency of the reactor to transition to a much lower power level whenever temperatures rise significantly. This type of behavior was demonstrated in a series of unscrammed tests at EBR-II [NED, 1986]. The second key design feature is the passive air cooling of the vessel to remove decay heat. These systems, designated RVACS in PRISM and RACS in SAFR, always operate and are believed to be able to prevent core damage in the event that no other means of heat removal is available. 27 refs., 78 figs., 3 tabs
Technique for detecting liquid metal leaks
International Nuclear Information System (INIS)
Bauerle, J.E.
1979-01-01
In a system employing flowing liquid metal as a heat transfer medium in contact with tubular members containing a working fluid, i.e., steam, liquid metal leaks through the wall of the tubular member are detected by dislodging the liquid metal compounds forming in the tubular member at the leak locations and subsequently transporting the dislodged compound in the form of an aerosol to a detector responsive to the liquid metal compound. In the application to a sodium cooled tubular member, the detector would consist of a sodium responsive device, such as a sodium ion detector
Archive-cup insert for liquid-metal sampling
International Nuclear Information System (INIS)
Nelson, P.A.; Kolba, V.M.; Filewicz, E.C.; Holmes, J.T.
1975-01-01
An insert for collecting liquid-metal samples within a vertical casing including an elongated housing with an upper and a lower overflow seal of annular shape is described. The lower seal includes a centrally located pedestal on which a sample cup is disposed. Liquid metal enters the annulus of the upper seal and overflows into the cup which fills and overflows into the lower seal. Liquid-metal overflow from the lower seal is discharged from the insert. On cooling, the liquid metal trapped within the seals solidifies to hermetically isolate the metal sample within the cup. The device is particularly applicable for use with sampling systems on liquid metal-cooled reactors. (U.S.)
International Nuclear Information System (INIS)
Lee, Yong Bum
1994-02-01
The critical heat flux (CHF) phenomenon in the two-phase convective flows has been an important issue in the fields of design and safety analysis of light water reactor (LWR) as well as sodium cooled liquid metal fast breeder reactor (LMFBR). Especially in the LWR application many physical aspects of the CHF phenomenon are understood and reliable correlations and mechanistic models to predict the CHF condition have been proposed. However, there are few correlations and models which are applicable to liquid metals. Compared with water, liquid metals show a divergent picture for boiling pattern. Therefore, the CHF conditions obtained from investigations with water cannot be applied to liquid metals. In this work a mechanistic model to predict the CHF of water and a correlation for liquid metals are developed. First, a mechanistic model to predict the CHF in flow boiling at low quality was developed based on the liquid sublayer dryout mechanism. In this approach the CHF is assumed to occur when a vapor blanket isolates the liquid sublayer from bulk liquid and then the liquid entering the sublayer falls short of balancing the rate of sublayer dryout by vaporization. Therefore, the vapor blanket velocity is the key parameter. In this work the vapor blanket velocity is theoretically determined based on mass, energy, and momentum balance and finally the mechanistic model to predict the CHF in flow boiling at low quality is developed. The accuracy of the present model is evaluated by comparing model predictions with the experimental data and tabular data of look-up tables. The predictions of the present model agree well with extensive CHF data. In the latter part a correlation to predict the CHF for liquid metals is developed based on the flow excursion mechanism. By using Baroczy two-phase frictional pressure drop correlation and Ledinegg instability criterion, the relationship between the CHF of liquid metals and the principal parameters is derived and finally the
Metal fire implications for advanced reactors. Part 1, literature review
International Nuclear Information System (INIS)
Nowlen, Steven Patrick; Radel, Ross F.; Hewson, John C.; Olivier, Tara Jean; Blanchat, Thomas K.
2007-01-01
Public safety and acceptance is extremely important for the nuclear power renaissance to get started. The Advanced Burner Reactor and other potential designs utilize liquid sodium as a primary coolant which provides distinct challenges to the nuclear power industry. Fire is a dominant contributor to total nuclear plant risk events for current generation nuclear power plants. Utilizing past experience to develop suitable safety systems and procedures will minimize the chance of sodium leaks and the associated consequences in the next generation. An advanced understanding of metal fire behavior in regards to the new designs will benefit both science and industry. This report presents an extensive literature review that captures past experiences, new advanced reactor designs, and the current state-of-knowledge related to liquid sodium combustion behavior
Energy Technology Data Exchange (ETDEWEB)
Cha, Kyung Ho; Park, Gun Ok; Suh, Sang Moon; Kim, Jang Yeol; Kwon, Kee Choon [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)
1999-12-31
The DAta management and COmmunication NETworks(DACONET), which it is designed as a subsystem for Man-Machine Interface System of Korea Advanced LIquid MEtal Reactor (KALIMER MMIS) and advanced design concept is approached, is described. The DACONET has its roles of providing the real-time data transmission and communication paths between MMIS systems, providing the quality data for protection, monitoring and control of KALIMER and logging the static and dynamic behavioral data during KALIMER operation. The DACONET is characterized as the distributed real-time system architecture with high performance. Future direction, in which advanced technology is being continually applied to Man-Machine Interface System development of Nuclear Power Plants, will be considered for designing data management and communication networks of KALIMER MMIS. 9 refs., 1 fig. (Author)
Energy Technology Data Exchange (ETDEWEB)
Cha, Kyung Ho; Park, Gun Ok; Suh, Sang Moon; Kim, Jang Yeol; Kwon, Kee Choon [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)
1998-12-31
The DAta management and COmmunication NETworks(DACONET), which it is designed as a subsystem for Man-Machine Interface System of Korea Advanced LIquid MEtal Reactor (KALIMER MMIS) and advanced design concept is approached, is described. The DACONET has its roles of providing the real-time data transmission and communication paths between MMIS systems, providing the quality data for protection, monitoring and control of KALIMER and logging the static and dynamic behavioral data during KALIMER operation. The DACONET is characterized as the distributed real-time system architecture with high performance. Future direction, in which advanced technology is being continually applied to Man-Machine Interface System development of Nuclear Power Plants, will be considered for designing data management and communication networks of KALIMER MMIS. 9 refs., 1 fig. (Author)
Specificity in liquid metal induced embrittlement
CSIR Research Space (South Africa)
Fernandes, PJL
1996-12-01
Full Text Available One of the most intriguing features of liquid metal induced embrittlement (LMIE) is the observation that some liquid metal-solid metal couples are susceptible to embrittlement, while others appear to be immune. This is referred to as the specificity...
Forces in Liquid Metal Contacts
DEFF Research Database (Denmark)
Duggen, Lars; Mátéfi-Tempfli, Stefan
2014-01-01
Using rather well known theory about capillary bridges between two electrodes we calculate the tensile force that can be applied to liquid metal contacts in the micrometer regime. Assuming circular symmetry, full wetting of the electrodes, and neglecting gravity, we present a brief review of the ...... of the necessary theory and find numerically the forces to be in the 100μN range for liquid metals as mercury and liquid Gallium suspended between electrodes of 20μm radius.......Using rather well known theory about capillary bridges between two electrodes we calculate the tensile force that can be applied to liquid metal contacts in the micrometer regime. Assuming circular symmetry, full wetting of the electrodes, and neglecting gravity, we present a brief review...
Liquid Metal Engineering and Technology. Volume 1
International Nuclear Information System (INIS)
1988-01-01
These proceedings of the fourth international conference on liquid metal engineering and technology volume 1, are devided into 3 sections bearing on: - Apparatus and components for liquid metal (29 papers) - Liquid metal leaks, fires and fumes (10 papers) - Cleaning, decontamination, waste disposal (14 papers) [fr
Pennell, William E.
1982-01-01
The liquid metal pump comprises floating seal rings and attachment of the pump diffuser to the pump bowl for isolating structural deflections from the pump shaft bearings. The seal rings also eliminate precision machining on large assemblies by eliminating the need for a close tolerance fit between the mounting surfaces of the pump and the seals. The liquid metal pump also comprises a shaft support structure that is isolated from the pump housing for better preservation of alignment of shaft bearings. The shaft support structure also allows for complete removal of pump internals for inspection and repair.
International Nuclear Information System (INIS)
Pennell, W.E.
1982-01-01
The liquid metal pump comprises floating seal rings and attachment of the pump diffuser to the pump bowl for isolating structural deflections from the pump shaft bearings. The seal rings also eliminate precision machining on large assemblies by eliminating the need for a close tolerance fit between the mounting surfaces of the pump and the seals. The liquid metal pump also comprises a shaft support structure that is isolated from the pump housing for better preservation of alignment of shaft bearings. The shaft support structure also allows for complete removal of pump internals for inspection and repair
Liquid Metallic Hydrogen: A Building Block for the Liquid Sun
Directory of Open Access Journals (Sweden)
Robitaille P.-M.
2011-07-01
Full Text Available Liquid metallic hydrogen provides a compelling material for constructing a condensed matter model of the Sun and the photosphere. Like diamond, metallic hydrogen might have the potential to be a metastable substance requiring high pressures for forma- tion. Once created, it would remain stable even at lower pressures. The metallic form of hydrogen was initially conceived in 1935 by Eugene Wigner and Hillard B. Huntington who indirectly anticipated its elevated critical temperature for liquefaction (Wigner E. and Huntington H.B. On the possibility of a metallic modification of hydro- gen. J. Chem. Phys. , 1935, v.3, 764–770. At that time, solid metallic hydrogen was hypothesized to exist as a body centered cubic, although a more energetically accessible layered graphite-like lattice was also envisioned. Relative to solar emission, this struc- tural resemblance between graphite and layered metallic hydrogen should not be easily dismissed. In the laboratory, metallic hydrogen remains an elusive material. However, given the extensive observational evidence for a condensed Sun composed primarily of hydrogen, it is appropriate to consider metallic hydrogen as a solar building block. It is anticipated that solar liquid metallic hydrogen should possess at least some layered order. Since layered liquid metallic hydrogen would be essentially incompressible, its invocation as a solar constituent brings into question much of current stellar physics. The central proof of a liquid state remains the thermal spectrum of the Sun itself. Its proper understanding brings together all the great forces which shaped modern physics. Although other proofs exist for a liquid photosphere, our focus remains solidly on the generation of this light.
Liquid metals fire control engineering handbook
International Nuclear Information System (INIS)
Ballif, J.L.
1979-02-01
This handbook reviews the basic requirements of the use of liquid metals with emphasis on sodium which has the greatest current usage. It delineates the concepts necessary to design facilities both radioactive and nonradioactive for use with liquid metals. It further reviews the state-of-the-art in fire extinguishers and leak detection equipment and comments on their application and sensitivity. It also provides details on some engineering features of value to the designer of liquid metal facilities
Liquid metal corrosion considerations in alloy development
International Nuclear Information System (INIS)
Tortorelli, P.F.; DeVan, J.H.
1984-01-01
Liquid metal corrosion can be an important consideration in developing alloys for fusion and fast breeder reactors and other applications. Because of the many different forms of liquid metal corrosion (dissolution, alloying, carbon transfer, etc.), alloy optimization based on corrosion resistance depends on a number of factors such as the application temperatures, the particular liquid metal, and the level and nature of impurities in the liquid and solid metals. The present paper reviews the various forms of corrosion by lithium, lead, and sodium and indicates how such corrosion reactions can influence the alloy development process
LIQUID METAL COMPOSITIONS CONTAINING URANIUM
Teitel, R.J.
1959-04-21
Liquid metal compositions containing a solid uranium compound dispersed therein is described. Uranium combines with tin to form the intermetallic compound USn/sub 3/. It has been found that this compound may be incorporated into a liquid bath containing bismuth and lead-bismuth components, if a relatively small percentage of tin is also included in the bath. The composition has a low thermal neutron cross section which makes it suitable for use in a liquid metal fueled nuclear reactor.
Task-specific ionic liquids for solubilizing metal compounds
Thijs, Ben
2007-01-01
The main goal of this PhD thesis was to design new task-specific ionic liquids with the ability to dissolve metal compounds. Despite the large quantity of papers published on ionic liquids, not much is known about the mechanisms of dissolving metals in ionic liquids or about metal-containing ionic liquids. Additionally, many of the commercially available ionic liquids exhibit a very limited solubilizing power for metal compounds, although this is for many applications like electrodeposition a...
Liquid metal cooled divertor for ARIES
International Nuclear Information System (INIS)
Muraviev, E.
1995-01-01
A liquid metal, Ga-cooled divertor design was completed for the double null ARIES-II divertor design. The design analysis indicated a surface heat flux removal capability of up to 15 MW/m 2 , and its relative easy maintenance. Design issues of configuration, thermal hydraulics, thermal stresses, liquid metal loop and safety effects were evaluated. For coolant flow control, it was found that it is necessary to use some part of the blanket cooling ducts for the draining of liquid metal from the top divertor. In order to minimize the inventory of Ga, it was recommended that the liquid metal loop equipment should be located as close to the torus as possible. More detailed analysis of transient conditions especially under accident conditions was identified as an issue that will need to be addressed
International Nuclear Information System (INIS)
2013-01-01
The objective of the Technical Meeting is to present and discuss innovative liquid metal fast reactor (LMFR) core designs with special focus on the choice, development, testing and qualification of advanced reactor core structural materials
International Nuclear Information System (INIS)
Narula, M.; Abdou, M.A.; Ying, A.; Morley, N.B.; Ni, M.; Miraghaie, R.; Burris, J.
2006-01-01
The use of fast moving liquid metal streams or 'liquid walls' as a plasma contact surface is a very attractive option and has been looked upon with considerable interest over the past several years, both by the plasma physics and fusion engineering programs. Flowing liquid walls provide an ever replenishing contact surface to the plasma, leading to very effective particle pumping and surface heat flux removal. A key feasibility issue for flowing liquid metal plasma facing component (PFC) systems, pertains to their magnetohydrodynamic (MHD) behavior under the spatially varying magnetic field environment, typical of a fusion device. MHD forces hinder the development of a smooth and controllable liquid metal flow needed for PFC applications. The present study builds up on the ongoing research effort at UCLA, directed towards providing qualitative and quantitative data on liquid metal free surface flow behavior under fusion relevant magnetic fields
Status of liquid metal reactor development in the United States of America
International Nuclear Information System (INIS)
Griffith, J.D.; Horton, K.E.
1990-01-01
The United States have made substantial progress in achieving Advanced Liquid Metal Reactor (ALMR) program objectives. A decision was made in 1988 to select the General Electric ALMR concept known as PRISM (Power Reactor Innovative Safe Module) for advanced conceptual design. A 3-year contract was awarded to General Electric in January of last year for concentrated trade-off studies and advanced design development. The strategy is to integrate those advancements that best meet program objectives into a national ALMR system concept. (author). 10 figs, 1 tab
Properties of structural materials in liquid metal environment
International Nuclear Information System (INIS)
Borgstedt, H.U.
1991-12-01
The proceedings contain 16 contributions to the following topics: 1. Creep-Rupture Behaviour of Structural Materials in Liquid Metal Environment; 2. Behaviour of Materials in Liquid Metal Environment under Off-Normal Conditions; 3. Fatigue and Creep-Fatigue of Structural Materials in Liquid Metal Environment; and 4. Crack Propagation in Liquid Sodium. (MM)
International Nuclear Information System (INIS)
2013-01-01
The objective of the TM on “Liquid metal reactor concept: core design and structural materials” was to present and discuss innovative liquid metal fast reactor (LMFR) core designs with special focus on the choice, development, testing and qualification of advanced reactor core structural materials. Main results arising from national and international R&D programmes and projects in the field were reviewed, and new activities to be carried out under the IAEA aegis were identified on the basis of the analysis of current research and technology gaps
Liquid metal magnetohydrodynamic convertor
International Nuclear Information System (INIS)
Aladiev, I.T.; Dzhamardzhashvili, V.A.
1981-01-01
This invention relates to the generation of electrical energy by direct conversion from thermal or electrical energy and notably to liquid metal magnetohydrodynamic convertors. The convertor described in this invention can be successfully used as a source of electrical energy for space vessels, for underwater vessels, for aeronautics and for the generation of electrical energy in thermal or atomic power plants. This liquid metal convertor consists of a heat source, a two phase nozzle, a separator, a steam diffuser and a condenser. These elements are connected together hydraulically in series. The condenser is connected hydraulically to a heat source, a liquid diffuser and a magnetohydrodynamic generator. These elements are interconnected hydraulically to the separator and heat source [fr
MHD power conversion employing liquid metals
International Nuclear Information System (INIS)
Houben, J.W.M.A.; Massee, P.
1969-02-01
The work performed in the field of MHD generation of electricity by means of liquid metals is described. It is shown that the study of two-phase flows is essential in this topic of research; two-phase flows are therefore described. Two types of generators which can be utilized with liquid metals have been studied. The results of this study are described. A short survey of the prospects of other liquid metal systems which emerge from a study of the literature is given. Finally, conclusions are drawn concerning possibilities for further investigation
International Nuclear Information System (INIS)
Brauer, S.; Rodricks, B.; Assoufid, L.; Beno, M.A.; Knapp, G.S.
1996-06-01
The authors describe a horizontally focusing curved-crystal monochromator that invokes a 4-point bending scheme and a liquid-metal cooling bath. The device has been designed for dispersive diffraction and spectroscopy in the 5--20 keV range, with a predicted focal spot size of ≤ 100 microm. To minimize thermal distortions and thermal equilibration time, the 355 x 32 x 0.8 mm crystal will be nearly half submerged in a bath of Ga-In-Sn-Zn alloy. The liquid metal thermally couples the crystal to the water-cooled Cu frame, while permitting the required crystal bending. Calculated thermal profiles and anticipated focusing properties are discussed
Liquid metal cooled nuclear reactor
International Nuclear Information System (INIS)
Leigh, K.M.
1980-01-01
A liquid metal cooled nuclear reactor is described, wherein coolant is arranged to be flowed upwardly through a fuel assembly and having one or more baffles located above the coolant exit of the fuel assembly, the baffles being arranged so as to convert the upwardly directed motion of liquid metal coolant leaving the fuel assembly into a substantially horizontal motion. (author)
International Nuclear Information System (INIS)
Dunn, P.F.
1978-01-01
The basic features of the two-phase liquid-metal MHD energy conversion under development at Argonne National Laboratory are presented. The results of system studies on the Rankine-cycle and the open-cycle coal-fired cycle options are discussed. The liquid-metal MHD experimental facilities are described in addition to the system's major components, the generator, mixer and nozzle-separator-diffuser
Liquid metal heat transfer issues
International Nuclear Information System (INIS)
Hoffman, H.W.; Yoder, G.L.
1984-01-01
An alkali liquid metal cooled nuclear reactor coupled with an alkali metal Rankine cycle provides a practicable option for space systems/missions requiring power in the 1 to 100 MW(e) range. Thermal issues relative to the use of alkali liquid metals for this purpose are identified as these result from the nature of the alkali metal fluid itself, from uncertainties in the available heat transfer correlations, and from design and performance requirements for system components operating in the earth orbital microgravity environment. It is noted that, while these issues require further attention to achieve optimum system performance, none are of such magnitude as to invalidate this particular space power concept
International Nuclear Information System (INIS)
Baumeister, E.B.
1987-01-01
The Sodium Advanced Fast Reactor (SAFR) modular reactor concept is being developed by the team of Rockwell International, Combustion Engineering, and Bechtel under the U.S. Department of Energy's (DOE's) Advanced Liquid Metal Reactor (LMR) program. The SAFR plant would provide a viable alternate to light water reactors, especially for applications favoring small incremental capacity additions. SAFR is also a logical step to facilitate the later transition to LMFBRs. The SAFR plant concept employs multiple 350-MWe LMR Power Pak modules. Each Power Pak is a standardized, shop-fabricated unit that can be barge-shipped to the plant site for installation. The 350-MWe size allows SAFR to capitalize on all the inherent safety features provided by small reactors and factory fabrication, while still preserving some economy of scale. Shop fabrication minimizes nuclear-grade field fabrication and minimizes the overall plant construction schedule and capital cost. Each Power Pak consists of one reactor assembly and associated heat transfer equipment coupled to a single turbine generator. The reactor core employs mixed uranium-plutonium zirconium alloy metal fuel. The metal-alloy fuel (which has been used in EBR-II) has cost, safety, and safeguard advantages. The intrinsic properties of the sodium coolant (e.g., high boiling point, low vapor pressure, and strong natural convection), blended together with the pool-type LMR concept and the metal fuel, result in an inherently safe plant. Passive inherent features provide both public safety and plant investment protection. Refueling is carried out annually on each Power Pak, replacing one-fourth of the core over a 6-day refueling outage. A colocated pyroprocessing fuel cycle facility can be accommodated at the site such that no off-site shipments are required. (J.P.N.)
Low temperature wetting and cleanup of alkali metal-advanced electrical machine systems
International Nuclear Information System (INIS)
Gass, W.R.; Witkowski, R.E.; Burrow, G.C.
1980-01-01
Advanced homopolar electrical machines employing high electrical current density, liquid metal sliprings for current transfer utilize NaK/sub 78/ (78 w/o potassium, 22 w/o sodium) for the conducting fluid. Experiments have been performed to improve alkali metal/oxide clean-up procedures. Studies have also confirmed chemical and materials compatibility between barium doped NaK/sub 78/ and typical machine structural materials. 4 refs
Oxidation-Mediated Fingering in Liquid Metals
Eaker, Collin B.; Hight, David C.; O'Regan, John D.; Dickey, Michael D.; Daniels, Karen E.
2017-10-01
We identify and characterize a new class of fingering instabilities in liquid metals; these instabilities are unexpected due to the large interfacial tension of metals. Electrochemical oxidation lowers the effective interfacial tension of a gallium-based liquid metal alloy to values approaching zero, thereby inducing drastic shape changes, including the formation of fractals. The measured fractal dimension (D =1.3 ±0.05 ) places the instability in a different universality class than other fingering instabilities. By characterizing changes in morphology and dynamics as a function of droplet volume and applied electric potential, we identify the three main forces involved in this process: interfacial tension, gravity, and oxidative stress. Importantly, we find that electrochemical oxidation can generate compressive interfacial forces that oppose the tensile forces at a liquid interface. The surface oxide layer ultimately provides a physical and electrochemical barrier that halts the instabilities at larger positive potentials. Controlling the competition between interfacial tension and oxidative (compressive) stresses at the interface is important for the development of reconfigurable electronic, electromagnetic, and optical devices that take advantage of the metallic properties of liquid metals.
International Nuclear Information System (INIS)
Hutchins, B.A.; Quinn, J.E.; Thompson, M.L.
1991-01-01
This paper presents a cost effective approach to providing a major contribution to the electricity needs of the United States in the early 21st century through an integrated Advanced Liquid Metal Reactor System (ALMRS). This system has several synergistic components which are under development by the United States Department of Energy (DOE): the modular, passively safe ALMR reactor design; metal fuel recycle (aka IFR); and the processing of LWR spent fuel to use as startup fuel for the ALMR. Each of these components contributes to an overall system behavior that will be able to provide an important portion of the United States' electrical energy needs beginning about the year 2010, while at the same time translating some fuel wastes of the LWR spent fuel to an asset. This paper describes each of these components and their synergism. Economic projections and busbar costs for this system are also presented
Structural disorder in metallic glass-forming liquids.
Pan, Shao-Peng; Feng, Shi-Dong; Wang, Li-Min; Qiao, Jun-Wei; Niu, Xiao-Feng; Dong, Bang-Shao; Wang, Wei-Min; Qin, Jing-Yu
2016-06-09
We investigated structural disorder by a new structural parameter, quasi-nearest atom (QNA), in atomistic configurations of eight metallic glass-forming systems generated through molecular dynamics simulations at various temperatures. Structural analysis reveals that the scaled distribution of the number of QNA appears to be an universal property of metallic liquids and the spatial distribution of the number of QNA displays to be clearly heterogeneous. Furthermore, the new parameter can be directly correlated with potential energy and structural relaxation at the atomic level. Some straightforward relationships between QNA and other properties (per-atom potential energy and α-relaxation time) are introduced to reflect structure-property relationship in metallic liquids. We believe that the new structural parameter can well reflect structure disorder in metallic liquids and play an important role in understanding various properties in metallic liquids.
Ionic Liquids as Extraction Media for Metal Ions
Hirayama, Naoki
In solvent extraction separation of metal ions, recently, many researchers have investigated possible use of hydrophobic ionic liquids as extraction media instead of organic solvents. Ionic liquids are salts of liquid state around room temperature and can act not only as solvents but also as ion-exchangers. Therefore, the extraction mechanism of metal ions into ionic liquids is complicated. This review presents current overview and perspective on evaluation of nature of hydrophobic ionic liquids as extraction media for metal ions.
Evaluating advanced LMR [liquid metal reactor] reactivity feedbacks using SSC
International Nuclear Information System (INIS)
Slovik, G.C.; Van Tuyle, G.J.; Kennett, R.J.; Cheng, H.S.
1988-01-01
Analyses of the PRISM and SAFR Liquid Metal Reactors with SSC are discussed from a safety and licensing perspective. The PRISM and SAFR reactors with metal fuel are designed for inherent shutdown responses to loss-of-flow and loss-of-heat-sink events. The demonstration of this technology was performed by EBR-II during experiments in April 1986 by ANL (Planchon, et al.). Response to postulated TOPs (control rod withdrawal) are made acceptable largely by reducing reactivity swings, and therefore minimizing the size of possible ractivity insertions. Analyses by DOE and the contractors GE, RI, and ANL take credit for several reactivity feedback mechanisms during transient calculations. These feedbacks include Doppler, sodium density, and thermal expansion of the grid plates, the load pads, the fuel (axial) and the control rod which are now factored into the BNL SSC analyses. The bowing feedback mechanism is not presently modeled in the SSC due to its complexity and subsequent large uncertainty. The analysis is conservative by not taking credit for this negative feedback mechanism. Comparisons of BNL predictions with DOE contractors are provided
Novel routes to metal nanoparticles : electrodeposition and reactions at liquid-liquid interfaces
Johans, Christoffer
2003-01-01
This thesis considers the nucleation and growth, synthesis, and catalytic application of metallic nanoparticles at liquid|liquid interfaces. It comprises five publications, a previously unpublished synthesis of polymer coated palladium nanoparticles, and an introduction to the relevant literature. Three publications are concerned with electrodeposition of metal nanoparticles at liquid|liquid interfaces. One publication and the results presented here consider the synthesis of silver and pallad...
Method of charging instruments into liquid metal coolant
International Nuclear Information System (INIS)
Yamazaki, Hiroshi
1980-01-01
Purpose: To alleviate the thermal shock of a reactor charging machine when charging the machine into liquid metal coolant after the machine is preheated in cover gas. Method: When a reactor fueling machine reaches at the lowermost portion the position immediately above liquid metal coolant surface level, the machine is stopped moving down. The reactor fueling machine is heated at the lowermost portion by thermal radiation from the surface of the liquid metal coolant. After the machine is thus preheated in cover gas, it is again steadily moved down by a winch and charged into the liquid metal coolant. Therefore, the thermal shock of the machine becomes low when charging the machine into the liquid metal coolant to eliminate the damage and deformation at the machine. (Yoshihara, H.)
Some Issues in Liquid Metals Research
Directory of Open Access Journals (Sweden)
Maria José Caturla
2015-11-01
Full Text Available The ten articles [1–10] included in this Special Issue on “Liquid Metals” do not intend to comprehensively cover this extensive field, but, rather, to highlight recent discoveries that have greatly broadened the scope of technological applications of these materials. Improvements in understanding the physics of liquid metals are, to a large extent, due to the powerful theoretical tools in the hands of scientists, either semi-empirical [1,5,6] or ab initio (molecular dynamics, see [7]. Surface tension and wetting at metal/ceramic interfaces is an everlasting field of fundamental research with important technological implications. The review of [2] is broad enough, as the work carried out at Grenoble covers almost all interesting matters in the field. Some issues of interest in geophysics and astrophysics are discussed in [3]. The recently discovered liquid–liquid transition in several metals is dealt with in [4]. The fifth contribution [5] discusses the role of icosahedral superclusters in crystallization. In [6], thermodynamic calculations are carried out to identify the regions of the ternary phase diagram of Al-Cu-Y, where the formation of amorphous alloys is most probable. Experimental data and ab initio calculations are presented in [7] to show that an optimal microstructure is obtained if Mg is added to the Al-Si melt before than the modifier AlP alloy. Shock-induced melting of metals by means of laser driven compression is discussed in [8]. With respect to recent discoveries, one of the most outstanding developments is that of gallium alloys that are liquid at room temperature [9], and that, due to the oxide layer that readily cover their surface, maintain some “stiffness”. This has opened the possibility of 3D printing with liquid metals. The last article in this Special Issue [10] describes nano-liquid metals, a suspension of liquid metal and its alloy containing nanometer-sized particles. A room-temperature nano-liquid metal
Column liquid chromatography applied to concentrating, separating, and determining platinum metals
International Nuclear Information System (INIS)
Alimarin, I.P.; Basova, E.M.; Bol'shova, T.A.; Ivanov, V.M.
1986-01-01
The present survey deals with high-performance liquid chromatography (HPLC) in relation to the chromatographic behavior of the platinum metals, including separation and determination. The data shows that HPLC is the most promising and effective method of separating metals, including platinum ones. The method provides efficient separation of microgram amoounts of mixtures with a resolving power 3-20 times that of thin-layer chromatography. It is shown that the most promising line of advance in HPLC for inorganic systems lies in the separation and determination of metals as chelates by absorption or ion-pair chromatography. Examples of using HPLC for determining noble metals in particular cases indicate that the metrological characteristics are favorable
Detection of gas entrainment into liquid metals
Energy Technology Data Exchange (ETDEWEB)
Vogt, T., E-mail: t.vogt@hzdr.de [Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Institute of Fluid Dynamics, 01328 Dresden (Germany); Boden, S. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Institute of Fluid Dynamics, 01328 Dresden (Germany); Andruszkiewicz, A. [Faculty of Mechanical and Power Engineering, Wroclaw University of Technology (Poland); Eckert, K. [Technische Universität Dresden, Institute of Fluid Mechanics, 01062 Dresden (Germany); Eckert, S.; Gerbeth, G. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Institute of Fluid Dynamics, 01328 Dresden (Germany)
2015-12-01
Highlights: • We present liquid metal experiments dedicated to gas entrainment on the free surface. • Ultrasonic and X-ray attenuation techniques have been used to study the mechanisms of gas entrainment. • A comparison between bubbly flow in water and GaInSn showed substantial differences. • Our results emphasize the importance of liquid metal experiments which are able to provide a suitable data base for numerical code validation. - Abstract: Entrainment of cover gas into the liquid metal coolant is one of the principal safety issues in the design of innovative liquid metal-cooled fast reactors. We present generic experimental studies of this phenomenon in low-melting metals. Ultrasonic and X-ray diagnostic tools were considered for a visualization of gas entrainment at the free surface of the melt. Laboratory experiments were conducted using the eutectic alloy GaInSn, which is liquid at room temperature. Vortex-activated entrainment of air at the free surface of a rotating flow was revealed by ultrasonic techniques. X-ray radioscopy was used to visualize the behavior of argon bubbles inside a slit geometry. The measurements reveal distinct differences between water and GaInSn, especially with respect to the process of bubble formation and the coalescence and breakup of bubbles. Our results emphasize the importance of liquid metal experiments which are able to provide a suitable data base for numerical code validation.
Microstructured liquid metal electron and ion sources (MILMES/MILMIS)
Energy Technology Data Exchange (ETDEWEB)
Mitterauer, J [Technische Universitaet Wien (Austria). Institut fuer Allgemeine Elektrotechnik und Elektronik
1997-12-31
Ion or electron beams can be emitted from liquid metal wetted needles, or from capillaries or slits into which the liquid metal is allowed to flow. Large-area liquid metal field emission sources have been proposed recently, using either two-dimensional, regular arrays of cones or capillaries, or even a substrate with an intrinsically microstructured surface covered by a liquid metal film. This latter concept has been realized in a pilot experiment by in situ wicking and wetting of a porous sintered metal disc. Microstructured liquid metal ion or electron sources are capable of operating in a pulsed mode at a current level which is orders of magnitude above that for steady-state operation. (author). 3 figs., 10 refs.
Measurement of the differential pressure of liquid metals
International Nuclear Information System (INIS)
Metz, H.J.
1975-01-01
This patent relates to an improved means for measuring the differential pressure between any two points in a process liquid metal coolant loop, wherein the flow of liquid metal in a pipe is opposed by a permanent magnet liquid metal pump until there is almost zero flow shown by a magnetic type flowmeter. The pressure producing the liquid metal flow is inferred from the rate of rotation of the permanent magnet pump. In an alternate embodiment, a differential pressure transducer is coupled to a process pipeline by means of high-temperature bellows or diaphragm seals, and a permanent magnet liquid metal pump in the high-pressure transmission line to the pressure transducer can be utilized either for calibration of the transducer or for determining the process differential pressure as a function of the magnet pump speed
Measurement of the differential pressure of liquid metals
Metz, H.J.
1975-09-01
This patent relates to an improved means for measuring the differential pressure between any two points in a process liquid metal coolant loop, wherein the flow of liquid metal in a pipe is opposed by a permanent magnet liquid metal pump until there is almost zero flow shown by a magnetic type flowmeter. The pressure producing the liquid metal flow is inferred from the rate of rotation of the permanent magnet pump. In an alternate embodiment, a differential pressure transducer is coupled to a process pipeline by means of high-temperature bellows or diaphragm seals, and a permanent magnet liquid metal pump in the high-pressure transmission line to the pressure transducer can be utilized either for calibration of the transducer or for determining the process differential pressure as a function of the magnet pump speed. (auth)
A method of measuring a molten metal liquid pool volume
Garcia, G.V.; Carlson, N.M., Donaldson, A.D.
1990-12-12
A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid. 3 figs.
Stretchable and Soft Electronics using Liquid Metals.
Dickey, Michael D
2017-07-01
The use of liquid metals based on gallium for soft and stretchable electronics is discussed. This emerging class of electronics is motivated, in part, by the new opportunities that arise from devices that have mechanical properties similar to those encountered in the human experience, such as skin, tissue, textiles, and clothing. These types of electronics (e.g., wearable or implantable electronics, sensors for soft robotics, e-skin) must operate during deformation. Liquid metals are compelling materials for these applications because, in principle, they are infinitely deformable while retaining metallic conductivity. Liquid metals have been used for stretchable wires and interconnects, reconfigurable antennas, soft sensors, self-healing circuits, and conformal electrodes. In contrast to Hg, liquid metals based on gallium have low toxicity and essentially no vapor pressure and are therefore considered safe to handle. Whereas most liquids bead up to minimize surface energy, the presence of a surface oxide on these metals makes it possible to pattern them into useful shapes using a variety of techniques, including fluidic injection and 3D printing. In addition to forming excellent conductors, these metals can be used actively to form memory devices, sensors, and diodes that are completely built from soft materials. The properties of these materials, their applications within soft and stretchable electronics, and future opportunities and challenges are considered. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Liquid metal actuation by electrical control of interfacial tension
Energy Technology Data Exchange (ETDEWEB)
Eaker, Collin B.; Dickey, Michael D., E-mail: michael-dickey@ncsu.edu [Department of Chemical and Biomolecular Engineering, North Carolina State University, 911 Partners Way, Raleigh, North Carolina 27695 (United States)
2016-09-15
By combining metallic electrical conductivity with low viscosity, liquid metals and liquid metal alloys offer new and exciting opportunities to serve as reconfigurable components of electronic, microfluidic, and electromagnetic devices. Here, we review the physics and applications of techniques that utilize voltage to manipulate the interfacial tension of liquid metals; such techniques include electrocapillarity, continuous electrowetting, electrowetting-on-dielectric, and electrochemistry. These techniques lower the interfacial tension between liquid metals and a surrounding electrolyte by driving charged species (or in the case of electrochemistry, chemical species) to the interface. The techniques are useful for manipulating and actuating liquid metals at sub-mm length scales where interfacial forces dominate. We focus on metals and alloys that are liquid near or below room temperature (mercury, gallium, and gallium-based alloys). The review includes discussion of mercury—despite its toxicity—because it has been utilized in numerous applications and it offers a way of introducing several phenomena without the complications associated with the oxide layer that forms on gallium and its alloys. The review focuses on the advantages, applications, opportunities, challenges, and limitations of utilizing voltage to control interfacial tension as a method to manipulate liquid metals.
Liquid Metal Machine Triggered Violin-Like Wire Oscillator.
Yuan, Bin; Wang, Lei; Yang, Xiaohu; Ding, Yujie; Tan, Sicong; Yi, Liting; He, Zhizhu; Liu, Jing
2016-10-01
The first ever oscillation phenomenon of a copper wire embraced inside a self-powered liquid metal machine is discovered. When contacting a copper wire to liquid metal machine, it would be swallowed inside and then reciprocally moves back and forth, just like a violin bow. Such oscillation could be easily regulated by touching a steel needle on the liquid metal surface.
Flow balancing in liquid metal blankets
International Nuclear Information System (INIS)
Tillack, M.S.; Morley, N.B.
1995-01-01
Non-uniform flow distribution between parallel channels is one of the most serious concerns for self-cooled liquid metal blankets with electrically insulated walls. We show that uncertainties in flow distribution can be dramatically reduced by relatively simple design modifications. Several design features which impose flow uniformity by electrically coupling parallel channels are surveyed. Basic mechanisms for ''flow balancing'' are described, and a particular self-regulating concept using discrete passive electrodes is proposed for the US ITER advanced blanket concept. Scoping calculations suggest that this simple technique can be very powerful in equalizing the flow, even with massive insulator failures in individual channels. More detailed analyses and experimental verification will be required to demonstrate this concept for ITER. (orig.)
Corrosion by liquid metals - Application to liquid sodium
International Nuclear Information System (INIS)
Lavielle, Lisette.
1978-10-01
In this bibliographic review on the corrosion by liquid metals, the first part is devoted to the theoretical aspects of the problem and the second part concerns the corrosion of steels by liquid sodium, as example. Obvious the numerous works now published, the mechanisms are still leaving bad known [fr
Liquid phase and supercooled liquid phase welding of bulk metallic glasses
International Nuclear Information System (INIS)
Kawamura, Y.
2004-01-01
Recent progress on welding in bulk metallic glasses (BMGs) has been reviewed. BMGs have been successfully welded to BMGs or crystalline metals by liquid phase welding using explosion, pulse-current and electron-beam methods, and by supercooled liquid phase welding using friction method. Successful welding of the liquid phase methods was due to the high glass-forming ability of the BMGs and the high concentration of welding energy in these methods. In contrast, the supercooled liquid phase welding was successful due to the thermally stable supercooled liquid state of the BMGs and the superplasticity and viscous flow of the supercooled liquid. The successful welding of BMGs to BMGs and crystalline materials is promising for the future development of BMGs as engineering materials
Properties of structural materials in liquid metal environment. Proceedings
Energy Technology Data Exchange (ETDEWEB)
Borgstedt, H U [ed.
1991-12-15
The International Working Group on Fast Reactors (IWGFR) Specialists Meeting on Properties of Structural Materials in Liquid Metal Environment was held during June 18 to June 20, 1991, at the Nuclear Research Centre (Kernforschungszentrum) in Karlsruhe, Germany. The Specialists Meeting was divided into five technical sessions which addressed topics as follows: Creep-Rupture Behaviour of Structural Materials in Liquid Metal Environment; Behaviour of Materials in Liquid Metal Environments under Off-Normal Conditions;Fatigue and Creep-Fatigue of Structural Materials in Liquid Metal Environment; Crack Propagation in Liquid Sodium; and Conclusions and recommendations. Individual papers have been cataloged separately.
PFR liquid metals disposal at Dounreay
International Nuclear Information System (INIS)
McIntyre, A.W.
1997-01-01
When the Prototype Fast Reactor (PFR) at Dounreay was shut down in 1994, the UKAEA commissioned a series of studies to determine the least cost, lowest risk option for dealing with the liquid metal coolants, i.e. the sodium from the primary and secondary circuits and the NaK from the decay heat removal system. The studies concluded that leaving the liquid metals in situ was not a viable option. Removing the liquid metals had three options, provision of long term external storage facilities, re-use in other projects or treatment for final disposal. The UKAEA invited companies to bid for the challenging task of disposing of more than 1500 t of liquid metals. In 1995 UKAEA awarded NNC Ltd. one of the largest decommissioning projects ever to be let competitively in the UK. During the first year of the contract, the challenges have focused on solving design problems and a number of innovative solutions have been developed by NNC and its subcontractors. From January 1997 the focus has moved to construction on site at Dounreay, and the manufacturing and installation of the mechanical components of the plant
Liquid metal batteries - materials selection and fluid dynamics
Weier, T.; Bund, A.; El-Mofid, W.; Horstmann, G. M.; Lalau, C.-C.; Landgraf, S.; Nimtz, M.; Starace, M.; Stefani, F.; Weber, N.
2017-07-01
Liquid metal batteries are possible candidates for massive and economically feasible large-scale stationary storage and as such could be key components of future energy systems based mainly or exclusively on intermittent renewable electricity sources. The completely liquid interior of liquid metal batteries and the high current densities give rise to a multitude of fluid flow phenomena that will primarily influence the operation of future large cells, but might be important for today’s smaller cells as well. The paper at hand starts with a discussion of the relative merits of using molten salts or ionic liquids as electrolytes for liquid metal cells and touches the choice of electrode materials. This excursus into electrochemistry is followed by an overview of investigations on magnetohydrodynamic instabilities in liquid metal batteries, namely the Tayler instability and electromagnetically excited gravity waves. A section on electro-vortex flows complements the discussion of flow phenomena. Focus of the flow related investigations lies on the integrity of the electrolyte layer and related critical parameters.
The US Advanced Liquid Metal Reactor and the Fast Flux Test Facility Phase IIA passive safety tests
International Nuclear Information System (INIS)
Shen, P.K.; Harris, R.A.; Campbell, L.R.; Dautel, W.A.; Dubberley, A.E.; Gluekler, E.L.
1992-07-01
This report discusses the safety approach of the Advanced Liquid Metal reactor program, sponsored by the US Department of Energy, which relies upon passive reactor responses to off-normal condition to limit power and temperature excursions to levels that allow safety margins. Gas expansion modules (GEM) have included in the design to provide negative reactivity to enhance these margins in the extremely unlikely event that pumping power is lost and the highly reliable scram system fails to operate. The feasibility and beneficial features of these devices were first demonstrated in the core of the Fast Flux Test Facility (FFTF) in 1986. Preapplication safety evaluations by the US Nuclear Regulatory Commission have identified areas that must be addressed if these devices are to be relied on. One of these areas is the response of the reactor when it is critical and the pumps are turned on, resulting in positive reactivity being added to the core. Tests to examine such transients have been performed as part of the continuing FFTF program to confirm the passive safety characteristics of liquid metal reactors (LMR). The primary tests consisted of starting the main coolant pumps, which forced sodium coolant into the GEMS, decreasing neutron leakage and adding positive reactivity. The resulting transients were shown to be benign and easily mitigated by the reactivity feedbacks inherent in the FFTF and all LMRs. Steady-state auxiliary tests of the GEM and feedback reactivity worths accurately predicted the transient results. The auxiliary GEM worth tests also demonstrated that the worth can be determined at a subcritical state, which allows for a verification of the GEM's availability prior to ascending to power
Liquid metal flows in insulating elements of self-cooled blankets
International Nuclear Information System (INIS)
Molokov, S.
1995-01-01
Liquid metal flows in insulating rectangular ducts in strong magnetic fields are considered with reference to poloidal concepts of self-cooled blankets. Although the major part of the flow in poloidal blanket concepts is close to being fully developed, manifolds, expansions, contractions, elbows, etc., which are necessary elements in blanket designs, cause three-dimensional effects. The present investigation demonstrates the flow pattern in basic insulating geometries for actual and more advanced liquid metal blanket concepts and discusses the ways to avoid pressure losses caused by flow redistribution. Flows in several geometries, such as symmetric and non-symmetric 180 turns with and without manifolds, sharp and linear expansions with and without manifolds, etc., have been considered. They demonstrate the attractiveness of poloidal concepts of liquid metal blankets, since they guarantee uniform conditions for heat transfer. If changes in the duct cross-section occur in the plane perpendicular to the magnetic field (ideally a coolant should always flow in the radial-poloidal plane), the disturbances are local and the slug velocity profile is reached roughly at a distance equivalent to one duct width from the manifolds, expansions, etc. The effects of inertia in these flows are unimportant for the determination of the pressure drop and velocity profiles in the core of the flow but may favour heat transfer characteristics via instabilities and strongly anisotropic turbulence. (orig.)
Metal fires and their implications for advanced reactors.
Energy Technology Data Exchange (ETDEWEB)
Nowlen, Steven Patrick; Figueroa, Victor G.; Olivier, Tara Jean; Hewson, John C.; Blanchat, Thomas K.
2010-10-01
This report details the primary results of the Laboratory Directed Research and Development project (LDRD 08-0857) Metal Fires and Their Implications for Advance Reactors. Advanced reactors may employ liquid metal coolants, typically sodium, because of their many desirable qualities. This project addressed some of the significant challenges associated with the use of liquid metal coolants, primary among these being the extremely rapid oxidation (combustion) that occurs at the high operating temperatures in reactors. The project has identified a number of areas for which gaps existed in knowledge pertinent to reactor safety analyses. Experimental and analysis capabilities were developed in these areas to varying degrees. In conjunction with team participation in a DOE gap analysis panel, focus was on the oxidation of spilled sodium on thermally massive surfaces. These are spills onto surfaces that substantially cool the sodium during the oxidation process, and they are relevant because standard risk mitigation procedures seek to move spill environments into this regime through rapid draining of spilled sodium. While the spilled sodium is not quenched, the burning mode is different in that there is a transition to a smoldering mode that has not been comprehensively described previously. Prior work has described spilled sodium as a pool fire, but there is a crucial, experimentally-observed transition to a smoldering mode of oxidation. A series of experimental measurements have comprehensively described the thermal evolution of this type of sodium fire for the first time. A new physics-based model has been developed that also predicts the thermal evolution of this type of sodium fire for the first time. The model introduces smoldering oxidation through porous oxide layers to go beyond traditional pool fire analyses that have been carried out previously in order to predict experimentally observed trends. Combined, these developments add significantly to the safety
The coalescence of heterogeneous liquid metal on nano substrate
Wang, Long; Li, Yifan; Zhou, Xuyan; Li, Tao; Li, Hui
2017-06-01
Molecular dynamics simulation has been performed to study the asymmetric coalescence of heterogeneous liquid metal on graphene. Simulation results show that the anomalies in the drop coalescence is mainly caused by the wettability of heterogeneous liquid metal. The silver atoms incline to distribute on the outer layer of the gold and copper droplets, revealing that the structure is determined by the interaction between different metal atoms. The coalescence and fusion of heterogeneous liquid metal drop can be predicted by comparing the wettability and the atomic mass of metallic liquid drops, which has important implications in the industrial application such as ink-jet printing and metallurgy.
Corrosion and compatibility in liquid alkali metals
International Nuclear Information System (INIS)
Anon.
1978-01-01
The literature dealing with liquid alkali metal corrosion of vanadium and its alloys is reviewed in the following subsections. Attention is given to both lithium and sodium data. Preceding this review, a brief outline of the current state of understanding of liquid metal corrosion mechanisms is provided
Liquid metal cooling concepts in solar power application
International Nuclear Information System (INIS)
Deegan, P.B.; Mangus, J.D.; Whitlow, G.A.
1978-01-01
The thermodynamic and thermophysical properties and proven technology of a liquid sodium heat transport system provide numerous advantages and benefits for application in a central receiver solar thermal power plant concept. The major advantages of utilizing liquid sodium are: attainment of high thermodynamic cycle efficiencies, reduced relative costs, and achievement of these goals by the mid-1980's through the utilization of proven liquid metal technology developed in the power industry, without the need for extensive development programs. The utilization of liquid sodium reduces the complexity of the design of these systems, thus providing confidence in system reliability. The implementation of the proven technology in liquid metal systems also provides assurance of reliability. In addition, the ease of transition from liquid metal breeder reactor systems to solar application provides immediate availability of this technology
Equipment for liquid metal pressure measurement
International Nuclear Information System (INIS)
Jung, J.
1977-01-01
Equipment is proposed for measuring liquid metal pressure in piping or a tank. An auxiliary piping is connected to the piping or tank at the measuring point. The auxiliary piping transports liquid metal to a container by means of an electromagnetic pump. The piping also houses an electromagnetic flow ratemeter connected to an electric comparator. The comparator and the electromagnetic pump are connected to the pump output generator. (Z.M.)
Status of liquid metal reactor development in the United States of America
Energy Technology Data Exchange (ETDEWEB)
Griffith, Jerry D [Reactor Systems Development and Technology, Office of Nuclear Energy, U.S. Department of Energy (United States); Horton, Kenneth E [Division of International Programs, Office of Nuclear Energy, U.S. Department of Energy (United States)
1992-07-01
The U.S. civilian nuclear power research and development program continues to focus on advanced large and mid-size light water reactors, advanced liquid metal fast reactors, and modular high temperature gas cooled reactors. This paper discusses the Advanced Liquid Metal Reactor program, which is composed of a small, passively safe fast reactor coupled with a metal fuel cycle that incorporates actinide recycle, and an emerging effort to process LWR spent fuel for LMR fissile material, and to enhance the LWR waste management. The liquid metal reactor concept has a sound technology base, with some three decades of research and development both in this and other countries. An existing network of government and industry research facilities and engineering test centers in the United States is currently providing test capabilities and the technical expertise required to conduct an aggressive advanced reactor development program. Notable among the research facilities is the Experimental Breeder Reactor-Il (EBR-II) at Argonne National Laboratory (ANL) in Idaho and the Fast Flux Test Facility (FFTF) at Hanford, Washington. Subsequent to the DOE directive to shut down the Fast Flux Test Facility in early 1990, significant effort was placed in finding international financial support for this reactor. This initiative was not successful. Therefore, although there may be a potential future mission for the FFTF, the Secretary of Energy announced on March 13, 1992 that the FFTF will be put in a standby condition starting April 1, 1992. Current U.S. Advanced Liquid Metal Reactor (ALMR) activity is focused on providing a reactor and fuel cycle system with improved safety margins, better economics, and an attractive waste management (actinide recycle) option. Special attention is being directed to passive safety features, large design margins, modular plant construction, standardized plant design leading to simplified licensing and shorter construction schedules, factory fabrication
Status of liquid metal reactor development in the United States of America
International Nuclear Information System (INIS)
Griffith, Jerry D.; Horton, Kenneth E.
1992-01-01
The U.S. civilian nuclear power research and development program continues to focus on advanced large and mid-size light water reactors, advanced liquid metal fast reactors, and modular high temperature gas cooled reactors. This paper discusses the Advanced Liquid Metal Reactor program, which is composed of a small, passively safe fast reactor coupled with a metal fuel cycle that incorporates actinide recycle, and an emerging effort to process LWR spent fuel for LMR fissile material, and to enhance the LWR waste management. The liquid metal reactor concept has a sound technology base, with some three decades of research and development both in this and other countries. An existing network of government and industry research facilities and engineering test centers in the United States is currently providing test capabilities and the technical expertise required to conduct an aggressive advanced reactor development program. Notable among the research facilities is the Experimental Breeder Reactor-Il (EBR-II) at Argonne National Laboratory (ANL) in Idaho and the Fast Flux Test Facility (FFTF) at Hanford, Washington. Subsequent to the DOE directive to shut down the Fast Flux Test Facility in early 1990, significant effort was placed in finding international financial support for this reactor. This initiative was not successful. Therefore, although there may be a potential future mission for the FFTF, the Secretary of Energy announced on March 13, 1992 that the FFTF will be put in a standby condition starting April 1, 1992. Current U.S. Advanced Liquid Metal Reactor (ALMR) activity is focused on providing a reactor and fuel cycle system with improved safety margins, better economics, and an attractive waste management (actinide recycle) option. Special attention is being directed to passive safety features, large design margins, modular plant construction, standardized plant design leading to simplified licensing and shorter construction schedules, factory fabrication
Evolution of the liquid metal reactor: The Integral Fast Reactor (IFR) concept
International Nuclear Information System (INIS)
Till, C.E.; Chang, Y.I.
1989-01-01
The Integral Fast Reactor (IFR) concept has been under development at Argonne National Laboratory since 1984. A key feature of the IFR concept is the metallic fuel. Metallic fuel was the original choice in early liquid metal reactor development. Solid technical accomplishments have been accumulating year after year in all aspects of the IFR development program. But as we make technical progress, the ultimate potential offered by the IFR concept as a next generation advanced reactor becomes clearer and clearer. The IFR concept can meet all three fundamental requirements needed in a next generation reactor. This document discusses these requirements: breeding, safety, and waste management. 5 refs., 4 figs
Clad buffer rod sensors for liquid metals
International Nuclear Information System (INIS)
Jen, C.-K.; Ihara, I.
1999-01-01
Clad buffer rods, consisting of a core and a cladding, have been developed for ultrasonic monitoring of liquid metal processing. The cores of these rods are made of low ultrasonic-loss materials and the claddings are fabricated by thermal spray techniques. The clad geometry ensures proper ultrasonic guidance. The lengths of these rods ranges from tens of centimeters to 1m. On-line ultrasonic level measurements in liquid metals such as magnesium at 700 deg C and aluminum at 960 deg C are presented to demonstrate their operation at high temperature and their high ultrasonic performance. A spherical concave lens is machined at the rod end for improving the spatial resolution. High quality ultrasonic images have been obtained in the liquid zinc at 600 deg C. High spatial resolution is needed for the detection of inclusions in liquid metals during processing. We also show that the elastic properties such as density, longitudinal and shear wave velocities of liquid metals can be measured using a transducer which generates and receives both longitudinal and shear waves and is mounted at the end of a clad buffer rod. (author)
International Nuclear Information System (INIS)
Strand, Gary; Vance, Jene N.
1997-01-01
Molten Metal Technologies (MMT) has recently acquired a proprietary filtration process for specific use in radioactive liquid waste processing systems. The filtration system has been incorporated in to a PWR liquid radwaste system which is currently being designed for the ComEd Byron Nuclear Station. It has also been adopted as the prefiltration step up from of the two RO systems which were part of the VECTRA acquisition and which are currently installed in the ComEd Dresden and Lacily Nuclear Stations. The filtration process has been successfully pilot-tested at both Byron and Dresden and is currently being tested at LaSalle. The important features of the filtration process are the high removal efficiencies for particulates, including colloidal particles, and the low solid waste volume generation per gallon filtered which translates into very small annual solid waste volumes. This filtration process system has been coupled with the use of selective ion exchange media in the PWR processing system to reduce the solid waste volumes generated compared to the current processing methods and to reduce the curie quantities discharged to the environs. In the BWR processing system, this filtration method allows the coupling of an RO system to provide for recycling greater than 95% of the liquid radwaste back to the plant for reuse while significantly reducing the solid waste volumes and operating costs. This paper discusses the process system configurations for the MMT Advanced Waste Processing Systems for both PWRs and BWRs. In addition, the pilot test data and full-scale performance projections for the filtration system are discussed which demonstrate the important features of the filtration process
Diverse transformations of liquid metals between different morphologies.
Sheng, Lei; Zhang, Jie; Liu, Jing
2014-09-10
Transformation from a film into a sphere, rapid merging of separate objects, controlled self-rotation, and planar locomotion are the very unusual phenomena observed in liquid metals under application of an electric field to a liquid metal immersed in or sprayed with water. A mechanism for these effects is suggested and potential applications - for example the recovery of liquid metal previously injected into the body for therapeutic purposes - are outlined. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Kim, Min-Gu; Alrowais, Hommood; Kim, Choongsoon; Yeon, Pyungwoo; Ghovanloo, Maysam; Brand, Oliver
2017-06-27
Lightweight, flexible, stretchable, and wireless sensing platforms have gained significant attention for personal healthcare and environmental monitoring applications. This paper introduces an all-soft (flexible and stretchable), battery-free, and wireless chemical microsystem using gallium-based liquid metal (eutectic gallium-indium alloy, EGaIn) and poly(dimethylsiloxane) (PDMS), fabricated using an advanced liquid metal thin-line patterning technique based on soft lithography. Considering its flexible, stretchable, and lightweight characteristics, the proposed sensing platform is well suited for wearable sensing applications either on the skin or on clothing. Using the microfluidic sensing platform, detection of liquid-phase and gas-phase volatile organic compounds (VOC) is demonstrated using the same design, which gives an opportunity to have the sensor operate under different working conditions and environments. In the case of liquid-phase chemical sensing, the wireless sensing performance and microfluidic capacitance tunability for different dielectric liquids are evaluated using analytical, numerical, and experimental approaches. In the case of gas-phase chemical sensing, PDMS is used both as a substrate and a sensing material. The gas sensing performance is evaluated and compared to a silicon-based, solid-state gas sensor with a PDMS sensing film.
International Nuclear Information System (INIS)
Hattori, Shuji; Kurachi, Hiroaki; Inoue, Fumitaka; Watashi, Katsumi; Tsukimori, Kazuyuki; Yada, Hiroki; Hashimoto, Takashi
2009-02-01
Cavitation erosion, which possibly occurs on the surfaces of fluid machineries and components contacting flowing liquid and causes sponge-like damage on the material surface, is important problem, since it may become the cause of performance deduction, life shortening, noise, vibration of mechanical components and moreover failure of machine. Research on cavitation erosion in liquid metal is very important to confirm the safety of fast breeder reactor using sodium coolant and to avoid serious damage of the target vessel of spallation neutron source containing liquid-mercury. But the research on cavitation erosion in liquid metal has been hardly performed because of its specially in comparison with that in water. In this study, a cavitation erosion test apparatus was developed to carry out the erosion tests in low-temperature liquid metals. Cavitation erosion tests were carried out in liquid lead-bismuth alloy and in deionized water. We discuss the effect of liquid parameters and temperature effects on the erosion rate. We reach to the following conclusions. The erosion rate was evaluated in terms of a relative temperature which was defind as the percentage between freezing and boiling points. At 14degC relative temperature, the erosion rate is 10 times in lead-bismuth alloy, and 2 to 5 times in sodium, compared with that in deionized water. At 14degC relative temperature, the erosion rate can be evaluated in terms of the following parameter. 1 / (1/ρ L /C L +1/ρ S C S )√ρ L . Where ρ is the material density and c is the velocity of sound, L and S denote liquid and solid. In the relative temperature between 14 and 30degC, the temperature dependence on the erosion rate is due to the increase in vapor pressure. (author)
Dynamic interactions of Leidenfrost droplets on liquid metal surface
Ding, Yujie; Liu, Jing
2016-09-01
Leidenfrost dynamic interaction effects of the isopentane droplets on the surface of heated liquid metal were disclosed. Unlike conventional rigid metal, such conductive and deformable liquid metal surface enables the levitating droplets to demonstrate rather abundant and complex dynamics. The Leidenfrost droplets at different diameters present diverse morphologies and behaviors like rotation and oscillation. Depending on the distance between the evaporating droplets, they attract and repulse each other through the curved surfaces beneath them and their vapor flows. With high boiling point up to 2000 °C, liquid metal offers a unique platform for testing the evaporating properties of a wide variety of liquid even solid.
Tokamak with liquid metal toroidal field coil
International Nuclear Information System (INIS)
Ohkawa, T.; Schaffer, M.J.
1981-01-01
Tokamak apparatus includes a pressure vessel for defining a reservoir and confining liquid therein. A toroidal liner disposed within the pressure vessel defines a toroidal space within the liner. Liquid metal fills the reservoir outside said liner. Electric current is passed through the liquid metal over a conductive path linking the toroidal space to produce a toroidal magnetic field within the toroidal space about the major axis thereof. Toroidal plasma is developed within the toroidal space about the major axis thereof
Compact device to heat up a liquid metal
International Nuclear Information System (INIS)
Blanc, R.; Pelloux, L.
1981-01-01
Device for heating a liquid metal, sodium for instance, this device being in one piece and capable of being introduced in one go into the tank containing the liquid metal and comprising heating rods and an electromagnetic pump [fr
Recent Advances in Liquid Metal Manipulation toward Soft Robotics and Biotechnologies.
Yu, Yue; Miyako, Eijiro
2018-04-06
Interest has grown significantly in the field of soft robotics, which seeks to develop machinery capable of duplicating the elastic and rheological properties of typically polymeric or elastomeric biological tissues and organs. As a result of a number of unique properties, gallium-based liquid metals (LMs) are emerging as materials used in the forefront of soft robotics research. Finding methods to enable the sophisticated manipulation of LMs will be essential for further progress in the field. This review provides a critical discussion of the manipulation of LMs and on important biotechnological applications of LMs including microfluidics, healthcare devices, biomaterials, and nanomedicines. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Testing of seismic isolation bearings for advanced liquid metal reactor prism
International Nuclear Information System (INIS)
Tajirian, F.F.; Kelly, J.M.
1988-01-01
Seismic isolation can significantly mitigate earthquake loads on liquid metal reactors (LMR), thus reducing the impact of seismic loads on design. This improves plant safety margins for beyond-design basis seismic events and enhances adaptability of a standardized design to a variety of sites, with potential cost benefits. The PRISM (Power Reactor Inherently Safe Module) LMR incorporates a horizontal isolation system which consists of high damping steel laminated rubber bearings. The results of an experimental program to determine the mechanical properties of the rubber compound and the bearing performance under different loading conditions are presented. The test results demonstrate the excellent performance of the bearings and their suitability for isolating compact LMR plants
Bulk viscosity and ultrasonic attenuation in liquid metals
International Nuclear Information System (INIS)
Awasthi, O.N.; Murthy, B.V.S.
1984-11-01
Ultrasonic attenuation in simple liquid metals has been investigated using the thermodynamic theory of relaxation processes incorporating the concept of a two state model for the liquid near the melting point. Agreement of the results with the experimental values of the ultrasonic attenuation and bulk viscosity indicates that this might be an appropriate approach to explain the excess attenuation of ultrasonic waves in liquid metals. (author)
A pump/intermediate heat exchanger assembly for a liquid metal reactor
International Nuclear Information System (INIS)
Nathenson, R.D.; Alexion, C.C.; Sumpman, W.C.
1987-01-01
A heat exchanger and electromagnetic pump assembly is disclosed comprising a heat exchanger housing defining an annularly shaped cavity and supporting therein a plurality of heat transfer tubes. An electromagnetic pump disposed beneath the heat exchanger comprises a circular array of flow couplers. Each flow coupler comprises a pump duct receiving primary liquid metal and a generator duct receiving a pumped intermediate liquid metal. A first plenum chamber is in communication with the generator ducts of all the flow couplers and receives intermediate liquid metal from inlet duct. The generator ducts exit their flows of intermediate liquid metal to a second plenum chamber in communication with the heat exchanger annularly shaped cavity to permit the flow of the intermediate liquid metal therethrough. A third plenum chamber receives collectively the flows of the primary liquid metal from the tubes and directs the primary liquid metal to the pump ducts of the flow couplers. The annular magnetic field of the electromagnetic pump is produced by a circular array of electromagnets having hollow windings cooled by a flow of intermediate liquid metal via tubes and manifolds. The leads to the electromagnets pass through an annular space around the inlet duct. (author)
Liquid metals as electrodes in polymer light emitting diodes
Andersson, G.G.; Gommans, H.H.P.; Denier van der Gon, A.W.; Brongersma, H.H.
2003-01-01
We demonstrate that liquid metals can be used as cathodes in light emitting diodes (pLEDs). The main difference between the use of liquid cathodes and evaporated cathodes is the sharpness of the metal–polymer interface. Liquid metal cathodes result in significantly sharper metal–organic interfaces
Temperature-dependent liquid metal flowrate control device
International Nuclear Information System (INIS)
Carlson, R.D.
1978-01-01
A temperature-dependent liquid metal flowrate control device includes a magnet and a ferromagnetic member defining therebetween a flow path for liquid metal, the ferromagnetic member being formed of a material having a curie temperature at which a change in the flow rate of the liquid metal is desired. According to the preferred embodiment the magnet is a cylindrical rod magnet axially disposed within a cylindrical member formed of a curie material and having iron pole pieces at the ends. A cylindrical iron shunt and a thin wall stainless steel barrier are disposed in the annulus between magnet and curie material. Below the curie temperature flow between steel barrier and curie material is impeded and above the curie temperature flow impedance is reduced
Soft Multifunctional Composites and Emulsions with Liquid Metals.
Kazem, Navid; Hellebrekers, Tess; Majidi, Carmel
2017-07-01
Binary mixtures of liquid metal (LM) or low-melting-point alloy (LMPA) in an elastomeric or fluidic carrier medium can exhibit unique combinations of electrical, thermal, and mechanical properties. This emerging class of soft multifunctional composites have potential applications in wearable computing, bio-inspired robotics, and shape-programmable architectures. The dispersion phase can range from dilute droplets to connected networks that support electrical conductivity. In contrast to deterministically patterned LM microfluidics, LMPA- and LM-embedded elastomer (LMEE) composites are statistically homogenous and exhibit effective bulk properties. Eutectic Ga-In (EGaIn) and Ga-In-Sn (Galinstan) alloys are typically used due to their high conductivity, low viscosity, negligible nontoxicity, and ability to wet to nonmetallic materials. Because they are liquid-phase, these alloys can alter the electrical and thermal properties of the composite while preserving the mechanics of the surrounding medium. For composites with LMPA inclusions (e.g., Field's metal, Pb-based solder), mechanical rigidity can be actively tuned with external heating or electrical activation. This progress report, reviews recent experimental and theoretical studies of this emerging class of soft material architectures and identifies current technical challenges and opportunities for further advancement. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Conceptual design strategy for liquid-metal-wall inertial-fusion reactors
International Nuclear Information System (INIS)
Monsler, M.J.; Meier, W.R.
1981-02-01
The liquid-metal-wall chamber has emerged as an attractive reactor concept for inertial fusion energy conversion. The principal feature of this concept is a thick, free-flowing blanket of liquid metal used to protect the structure of the reactor. The development and design of liquid-metal-wall chambers over the past decade provides a basis for formulating a conceptual design strategy for such chambers. Both the attractive and unattractive features of a LMW chamber are enumerated, and a design strategy is formulated which accommodates the engineering constraints while minimizing the liquid-metal flow rate
Direct high-temperature ohmic heating of metals as liquid pipes.
Grosse, A V; Cahill, J A; Liddell, W L; Murphy, W J; Stokes, C S
1968-05-03
When a sufficiently high electric current is passed through a liquid metal, the electromagnetic pressure pinches off the liquid metal and interrupts the flow of current. For the first time the pinch effect has been overcome by use of centrifugal acceleration. By rotation of a pipe of liquid metal, tin or bismuth or their alloys, at sufficiently high speed, it can be heated electrically without intermission of the electric current. One may now heat liquid metallic substances, by resistive (ohmic) heating, to 5000 degrees K and perhaps higher temperatures.
Conceptual design strategy for liquid-metal-wall inertial-fusion reactors
Energy Technology Data Exchange (ETDEWEB)
Monsler, M.J.; Meier, W.R.
1981-02-01
The liquid-metal-wall chamber has emerged as an attractive reactor concept for inertial fusion energy conversion. The principal feature of this concept is a thick, free-flowing blanket of liquid metal used to protect the structure of the reactor. The development and design of liquid-metal-wall chambers over the past decade provides a basis for formulating a conceptual design strategy for such chambers. Both the attractive and unattractive features of a LMW chamber are enumerated, and a design strategy is formulated which accommodates the engineering constraints while minimizing the liquid-metal flow rate.
The US Liquid-Metal Reactor Program - overview and status
International Nuclear Information System (INIS)
Quinn, J.E.; Gyorey, G.L.; Salerno, L.N.
1992-01-01
The US Advanced Liquid-Metal Reactor (ALMR) Program has three major elements being developed in an integrated fashion to produce a system meeting the US long-term nuclear energy needs. Reactor design, one of those elements, is the focus of this paper. The other two elements, the integral fast reactor metal-fuel cycle and the light water reactor (LWR) spent-fuel actinide recycle, will be addressed in companion papers. The ALMR is adaptable to multiple missions with few modifications such as the core arrangements. The missions identified to date are (a) the extension of the existing uranium resources through breeding and highly efficient uranium utilization, (b) the recycle and utilization of the long-life actinides in LWR spent fuel as fissile material for the ALMR, and (c) the conversion of excess weapons fissil material into electricity. In addition to these missions, the reactor design is adaptable to either the metal-fuel cycle or the oxide fuel cycle
Turbulent convection in liquid metal with and without rotation
King, Eric M.; Aurnou, Jonathan M.
2013-01-01
The magnetic fields of Earth and other planets are generated by turbulent, rotating convection in liquid metal. Liquid metals are peculiar in that they diffuse heat more readily than momentum, quantified by their small Prandtl numbers, . Most analog models of planetary dynamos, however, use moderate fluids, and the systematic influence of reducing is not well understood. We perform rotating Rayleigh–Bénard convection experiments in the liquid metal gallium over a range of nondimensional bu...
Advances in metal forming expert system for metal forming
Hingole, Rahulkumar Shivajirao
2015-01-01
This comprehensive book offers a clear account of the theory and applications of advanced metal forming. It provides a detailed discussion of specific forming processes, such as deep drawing, rolling, bending extrusion and stamping. The author highlights recent developments of metal forming technologies and explains sound, new and powerful expert system techniques for solving advanced engineering problems in metal forming. In addition, the basics of expert systems, their importance and applications to metal forming processes, computer-aided analysis of metalworking processes, formability analysis, mathematical modeling and case studies of individual processes are presented.
Compatibility of materials with liquid metal targets for SNS
International Nuclear Information System (INIS)
DiStefano, J.R.; Pawel, S.J.; DeVan, J.H.
1996-01-01
Several heavy liquid metals are candidates as the target in a spallation neutron source: Hg, Pb, Bi, and Pb-Bi eutectic. Systems with these liquid metals have been used in the past and a data-base on compatibility already exists. Two major compatibility issues have been identified when selecting a container material for these liquid metals: temperature gradient mass transfer and liquid metal embrittlement or LME. Temperature gradient mass transfer refers to dissolution of material from the high temperature portions of a system and its deposition in the lower temperature areas. Solution and deposition rate constants along with temperature, ΔT, and velocity are usually the most important parameters. For most candidate materials mass transfer corrosion has been found to be proportionately worse in Bi compared with Hg and Pb. For temperatures to ∼550 degrees C, ferritic/martensitic steels have been satisfactory in Pb or Hg systems and the maximum temperature can be extended to ∼650 degrees C with additions of inhibitors to the liquid metal, e.g. Mg, Ti, Zr. Above ∼600 degrees C, austenitic stainless steels have been reported to be unsatisfactory, largely because of the mass transfer of nickel. Blockage of flow from deposition of material is usually the life-limiting effect of this type of corrosion. However, mass transfer corrosion at lower temperatures has not been studied. At low temperatures (usually < 150 degrees C), LME has been reported for some liquid metal/container alloy combinations. Liquid metal embrittlement, like hydrogen embrittlement, results in brittle fracture of a normally ductile material
Magnetohydrodynamic instability of a cylindrical liquid-metal brush
International Nuclear Information System (INIS)
Hong, S.H.; Wilhelm, H.E.
1976-01-01
The stability of a homopolar generator brush, consisting of a liquid-metal-filled cavity between rotating (rotor) and fixed (stator) cylinder electrodes, is analyzed in the presence of radial current transport and an axial homogeneous magnetic field. Within the frame of linear magnetohydrodynamics, it is shown that the liquid-metal flow in the brush is always unstable if the brush transports current. In the absence of current flow (infinite load) the axial magnetic field stabilizes the liquid-metal flow in the brush if the magnetic energy density is larger than a certain fraction of the energy density of the rotating fluid
Improvements in liquid metal cooled nuclear reactors
International Nuclear Information System (INIS)
Barnes, S.
1980-01-01
Improvements in the design of the thermally insulating material used to shield the concrete containment walls in liquid metal cooled nuclear reactors are described in detail. The insulating material is composed of two layers and is placed between the primary vessel (usually steel) and the steel lined concrete containment vault. The outer layer, which clads the inner wall surface of the vault, is generally impervious to liquid metal coolant whilst the inner layer is pervious to the coolant. In normal operation, both layers protect the concrete from heat radiated from the reactor. In the event of a breach of the containment vessel, the resulting leakage of liquid metal coolant permeates the inner layer of insulating material, provides a means of heat transfer by conduction and hence reduces the overall insulating properties of the two layers. The outer layer continues to protect the wall surface of the vault from substantial direct contact with the liquid metal. Thus the two apparently conflicting requirements of good thermal insulation during normal operation and of heat transfer during loss of coolant accidents are satisfied by this novel design. Suggestions are given for possible materials for use as the insulating layers. (U.K.)
Investigation of two-phase liquid-metal magnetohydrodynamic power systems
International Nuclear Information System (INIS)
Amend, W.E.; Fabris, G.; Cutting, J.
1975-01-01
A two-phase Liquid-Metal MHD (LMMHD) system is under development at the Argonne National Laboratory, and results are presented for detailed cycle analysis and systems studies, the experimental facility, and the thermal and magneto fluid mechanics problems encountered. The studies indicate that the LMMHD cycle will operate efficiently in the temperature range of 1000-1600 0 F (50 percent efficiency with a maximum cycle temperature of 1600 0 F) and is therefore potentially compatible with many advanced heat sources under development such as the LMFBR, fluidized-bed coal combustor, HTGCR and the fusion reactor. Of special interest is the coupling to the LMFBR thereby eliminating the costly, potentially hazardous liquid-metal/water interface. The results of detailed parametric studies of the heat transfer interfaces between an LMMHD power cycle and an LMFBR and a steam bottoming plant are described. Experimental evaluation of the two-phase LMMHD generator was performed in an ambient temperature NaK--N 2 facility at ANL. Results of these experiments, performed to determine the operating characteristics of the device as a function of the various independent parameters and to investigate two-phase flow, are given. (U.S.)
Thermal management of Li-ion battery with liquid metal
International Nuclear Information System (INIS)
Yang, Xiao-Hu; Tan, Si-Cong; Liu, Jing
2016-01-01
Highlights: • Liquid metal is used for power battery pack thermal management. • Better cooling performance and more uniform module temperature is obtained. • Less power consumption is needed. • The proposed liquid metal cooling system is robust and can cope with stressful conditions. - Abstract: Thermal management especially cooling of electric vehicles (EVs) battery pack is of great significance for guaranteeing the performance of the cells as well as safety and high-efficiency working of the EVs. Liquid cooling is a powerful way to keep the battery temperature in a proper range. However, the efficiency of conventional liquid cooling is still limited due to the inherently low thermal conductivity of the coolant which is usually water or aqueous ethanol. In this paper, a new kind of coolant, liquid metal, is proposed to be used for the thermal management of the battery pack. Mathematical analysis and numerical simulations are conducted to evaluate the cooling capability, pump power consumption and module temperature uniformity of the liquid metal cooling system, in comparison with that of water cooling. The results show that under the same flow conditions, a lower and more uniform module temperature can be obtained and less pump power consumption are needed in the liquid metal cooling system. In addition, liquid metal has an excellent cooling capability coping with stressful conditions, such as high power draw, defects in cells, and high ambient temperature. This makes it a promising coolant for the thermal management of high driving force EVs and quick charge batteries.
Energy Technology Data Exchange (ETDEWEB)
Lan, S.; Ma, J. L.; Fan, J. [Department of Physics and Material Science, City University of Hong Kong 83 Tat Chee Ave., Kowloon (Hong Kong); Blodgett, M.; Kelton, K. F. [Department of Physics and Institute of Materials Science and Engineering, Washington University One Brookings Drive, St. Louis, Missouri 63130-4899 (United States); Wang, X.-L., E-mail: xlwang@cityu.edu.hk [Department of Physics and Material Science, City University of Hong Kong 83 Tat Chee Ave., Kowloon (Hong Kong); City University of Hong Kong Shenzhen Research Institute, Shenzhen 518057 (China)
2016-05-23
Time-resolved synchrotron measurements were carried out to capture the structure evolution of an electrostatically levitated metallic-glass-forming liquid during free cooling. The experimental data shows a crossover in the liquid structure at ∼1000 K, about 115 K below the melting temperature and 150 K above the crystallization temperature. The structure change is characterized by a dramatic growth in the extended-range order below the crossover temperature. Molecular dynamics simulations have identified that the growth of the extended-range order was due to an increased correlation between solute atoms. These results provide structural evidence for a liquid-to-liquid-phase-transition in the supercooled metallic liquid.
Evolution of the liquid metal reactor
International Nuclear Information System (INIS)
Till, C.E.; Chang, Y.I.
1989-01-01
This paper reports on the integral fat reactor (IFR) concept. A key feature of the IFR concept is the metallic fuel, the original choice in liquid metal reactor development. An IFR development program is detailed by the authors
Steam water cycle chemistry of liquid metal cooled innovative nuclear power reactors
International Nuclear Information System (INIS)
Yurmanov, Victor; Lemekhov, Vadim; Smykov, Vladimir
2012-09-01
The Federal Target Program (FTP) of Russian Federation 'Nuclear Energy Technologies of the New Generation for 2010-2015 and for Perspective up to 2020' is aimed at development of advanced nuclear energy technologies on the basis of closed fuel cycle with fast reactors. There are advanced fast reactor technologies of the 4. generation with liquid metal cooled reactors. Development stages of maturity of fast sodium cooled reactor technology in Russia includes experimental reactors BR-5/10 (1958-2002) and BOR-60 (since 1969), nuclear power plants (NPPs) with BN-350 (1972-1999), BN-600 (since 1980), BN-800 (under construction), BN-1200 (under development). Further stage of development of fast sodium cooled reactor technology in Russia is commercialization. Lead-bismuth eutectic fast reactor technology has been proven at industrial scale for nuclear submarines in former Soviet Union. Lead based technology is currently under development and need for experimental justification. Current status and prospects of State Corporation 'Rosatom' participation in GIF activities was clarified at the 31. Meeting of Policy Group of the International Forum 'Generation-IV', Moscow, May 12-13, 2011. In June, 2010, 'Rosatom' joined the Sodium Fast Reactor Arrangement as an authorized representative of the Russian Government. It was also announced the intention of 'Rosatom' to sign the Memorandum on Lead Fast Reactor based on Russia's experience with lead-bismuth and lead cooled fast reactors. In accordance with the above FTP some innovative liquid metal cooled reactors of different design are under development in Russia. Gidropress, well known as WER designer, develops innovative lead-bismuth eutectic cooled reactor SVBR-100. NIKIET develops innovative lead cooled reactor BRESTOD-300. Some other nuclear scientific centres are also involved in this activity, e.g. Research and Development Institute for Power Engineering (RDIPE). Optimum
Emergency cooling system for a liquid metal cooled reactor
International Nuclear Information System (INIS)
Murata, Ryoichi; Fujiwara, Toshikatsu.
1980-01-01
Purpose: To suitably cool liquid metal as coolant in emergency in a liquid metal cooled reactor by providing a detector for the pressure loss of the liquid metal passing through a cooling device in a loop in which the liquid metal is flowed and communicating the detector with a coolant flow regulator. Constitution: A nuclear reactor is stopped in nuclear reaction by control element or the like in emergency. If decay heat is continuously generated for a while and secondary coolant is insufficiently cooled with water or steam flowed through a steam and water loop, a cooler is started. That is, low temperature air is supplied by a blower through an inlet damper to the cooler to cool the secondary coolant flowed into the cooler through a bypass pipe so as to finally safely stop an entire plant. Since the liquid metal is altered in its physical properties by the temperature at this time, it is detected to regulate the opening of the valve of the damper according to the detected value. (Sekiya, K.)
International Nuclear Information System (INIS)
Abe, Yoshihito; Imazu, Takayuki; Ueda, Sabuo; Ueya, Katsumi.
1980-01-01
Purpose: To arrange a vapor trapping member of a specific structure at the inlet part of a cylindrical gap formed by the inner peripheral surface of the circular opening of a container and the outer peripheral surface of a rotary plug thereby to prevent ingress of vapor in the upper part of the cylindrical gap for a long period of time. Constitution: A sealing material receiving tray is fitted to the container side of the inlet part of a cylindrical gap, and a partition plate is fitted to the rotary plug side. The tray is filled with a sealing material consisting of a large number of steel balls, mesh wire gages and the like, and the partition plate is placed in the tray thereby to carry out sealing of the container. Liquid metal vapor evaporating from the liquid level of the liquid metal adheres to the sealing material to fill the gap, and therefore ingress of vapor to the upper part of the cylindrical gap is prevented, and there is no possibility of causing seal cutting due to the use for a long period. (Sekiya, K.)
Liquid metal flow measurement by neutron radiography
International Nuclear Information System (INIS)
Takenaka, N.; Ono, A.; Matsubayashi, M.; Tsuruno, A.
1996-01-01
Visualization of a liquid metal flow and image processing methods to measure the vector field are carried out by real-time neutron radiography. The JRR-3M real-time thermal neutron radiography facility in the Japan Atomic Energy Research Institute was used. Lead-bismuth eutectic was used as a working fluid. Particles made from a gold-cadmium intermetallic compound (AuCd 3 ) were used as the tracer for the visualization. The flow vector field was obtained by image processing methods. It was shown that the liquid metal flow vector field was obtainable by real-time neutron radiography when the attenuation of neutron rays due to the liquid metal was less than l/e and the particle size of the tracer was larger than one image element size digitized for the image processing. (orig.)
Advances in chemical physics advances in liquid crystals
Prigogine, Ilya; Vij, Jagdish K
2009-01-01
Prigogine and Rice's highly acclaimed series, Advances in Chemical Physics, provides a forum for critical, authoritative reviews of current topics in every area of chemical physics. Edited by J.K. Vij, this volume focuses on recent advances in liquid crystals with significant, up-to-date chapters authored by internationally recognized researchers in the field.
Liquid metal cooled nuclear reactor
International Nuclear Information System (INIS)
Guidez, Joel; Jarriand, Paul.
1975-01-01
The invention concerns a fast neutron nuclear reactor cooled by a liquid metal driven through by a primary pump of the vertical drive shaft type fitted at its lower end with a blade wheel. To each pump is associated an exchanger, annular in shape, fitted with a central bore through which passes the vertical drive shaft of the pump, its wheel being mounted under the exchanger. A collector placed under the wheel comprises an open upward suction bell for the liquid metal. A hydrostatic bearing is located above the wheel to guide the drive shaft and a non detachable diffuser into which at least one delivery pipe gives, envelopes the wheel [fr
Water storage of liquid-metal fast-breeder-reactor fuel
International Nuclear Information System (INIS)
Meacham, S.A.
1982-01-01
The purpose of this paper is to present a general overview of a concept proposed for receiving and storing liquid metal fast breeder reactor (LMFBR) spent fuel. This work was done as part of the Consolidated Fuel Reprocessing Program (CFRP) at the Oak Ridge National Laboratory (ORNL). The CFRP has as its major objective the development of technology for reprocessing advanced nuclear reactor fuels. The program plans that research and development will be carried through to a sufficient scale, using irradiated spent fuel under plant operating conditions, to establish a basis for confident projection of reprocessing capability to support a breeder industry
Liquid metal-based reconfigurable and stretchable photolithography
International Nuclear Information System (INIS)
Kim, Daeyoung; Yoo, Jun Hyeon; Lee, Jeong-Bong
2016-01-01
Conventional ultraviolet (UV) lithography typically uses a photomask made of a fused silica plate covered with a layer of UV opaque material such as chromium. The photomask has passive binary patterns of UV opaque and UV transparent regions and the pattern is unalterable. We report a novel real-time dynamically reconfigurable photomask technology using a liquid metal (as a UV opaque material) filled in polydimethylsiloxane (PDMS, as a UV transparent material) microfluidic channels. We found that the gallium-based liquid metal (e.g. Galinstan ® ) is opaque in broad spectrum of light in the wavelength from 325 nm to 850 nm while the PDMS is highly transparent in this wide range of spectrum. We made both bright field and dark field microfluidic photomasks and transferred various patterns onto a positive photoresist. A 7-segment display microfluidic channel photomask was also fabricated and decimal numerals (from ‘0’ to ‘9’) were patterned with one photomask by dynamically reconfiguring decimal numeral shapes with on-demand injection and withdrawal of the liquid metal in specific segment microfluidic channels in the photomask. In addition, utilizing mechanical flexibility of the PDMS and the liquid metal, reconfiguration of the patterns in a microfluidic photomask under stretching was successfully tested. (paper)
Ionic liquids used in extraction and separation of metal ions
International Nuclear Information System (INIS)
Shen Xinghai; Xu Chao; Liu Xinqi; Chu Taiwei
2006-01-01
Ionic liquids as green solvents now have become a research hotspot in the field of separation of metal ions by solvent extraction. Experimental results of extraction of various metal ions with ionic liquids as solvents, including that of alkali metals, alkaline earths, transition metals rare earths and actinides are introduced. The extraction of uranium, plutonium and fission products that are involved in spent nuclear fuel reprocessing is also reviewed. The possible extraction mechanisms are discussed. Finally, the prospect of replacement of volatile and/or toxic organic solvents with environmentally benign ionic liquids for solvent extraction and the potency of applications of ionic liquids in solvent extraction are also commented. (authors)
Chernikova, Valeriya; Shekhah, Osama; Eddaoudi, Mohamed
2016-01-01
Here we report a new and advanced method for the fabrication of highly oriented/polycrystalline metal-organic framework (MOF) thin films. Building on the attractive features of the liquid-phase epitaxy (LPE) approach, a facile spin coating method
Conference on heat mass transfer and properties of liquid metals TF-2002
International Nuclear Information System (INIS)
Efanov, A.D.; Kozlov, F.A.
2003-01-01
Results of the conference TF-2002 devoted to the combined approach to problems of harnessing liquid metals as coolants for NPU are presented. The conference takes place in Obninsk, 29 - 31 October, 2002. Papers of the conference involve items on thermal hydraulics, mass transfer and safety of NPU with liquid metal coolants, structure, physical and chemical properties of liquid metal and liquid metal solutions, decommissioning of units and ecology, application of liquid metals divorced with NPU. Most of the papers of the conference are devoted to the investigation into lead and lead-bismuth coolants [ru
Chemistry of liquid metal coolants and sensors
International Nuclear Information System (INIS)
Gnanasekaran, T.
2015-01-01
Liquid sodium is the coolant of choice for the current generation fast breeder reactors. When sodium contains low levels of dissolved non-metallic impurities, it is highly compatible with structural steels. When the dissolved oxygen level is high, corrosion and mass transfer in sodium-steel circuits are enhanced and this involves formation of NaxMyOz type of species (M = alloying components in steels). Experience has shown that this enhancement of corrosion in a sodium circuit with all austenitic steel structural materials would not be encountered if oxygen level in sodium is below ~ 5ppm. For understanding this observation, a complete knowledge on the phase diagrams of Na-M-O systems and the thermochemical data of all relevant NaxMyOz compounds is essential. This presentation would highlight the work carried out at IGCAR on the chemistry of liquid sodium and heavy liquid metal coolants. Work carried out on various sensors for their use in these liquid metal circuits would be described and their current status would be discussed
Evaluation of liquid metal protection of a limiter/divertor in fusion reactors
International Nuclear Information System (INIS)
Hassanein, A.M.; Smith, D.L.
1988-01-01
The liquid metal protection concept is proposed mainly to prolong the lifetime of a divertor or a limiter in a fusion reactor. This attractive idea for protection requires studying a wide range of problems associated with the use of liquid-metals in fusion reactors. In this work the protection by liquid-metals has concentrated on predictions of the loss rate of the film to the plasma, the operating surface temperatures required for the film, and the potential tritium inventory requirement. The effect of plasma disruptions on the liquid metal film is also evaluated. Other problems such as liquid metal compatibility with structural materials, magnetic field effects, and the effect of liquid metal contamination on plasma performance are discussed. Three candidate liquid-metals are evaluated, i.e., lithium, gallium, and tin. A wide range of reactor operating conditions valid for both near term machines (INTOR and ITER) and for the next generation commercial reactors (TPSS) are considered. This study has indicated that the evaporation rate for candidate liquid metals can be kept below the sputtering range for reasonable operating temperatures and plasma edge conditions. At higher temperatures, evaporation dominates the losses. Impurity transport calculations indicate that impurities from the plate should not reach the main plasma. One or two millimeters of liquid films can protect the structure from severe plasma disruptions. Depending on the design of the liquid metal protection system, the tritium inventory in the liquid film is predicted to be on the order of a few grams. 16 refs., 5 figs
Recycling of Metal Containing Waste by Liquid-Liquid Extraction
International Nuclear Information System (INIS)
Reinhardt, H.
1999-01-01
Through the years, a large number of liquid-liquid extraction have been proposed for metal waste recovery and recycling(1,2). However, few of them have achieved commercial application. In fact, relatively little information is available on practical operation and economic feasibility. This presentation will give complementary information by describing and comparing three processes, based on the Am MAR hydrometallurgical concept and representing three different modes of operation
Liquid metal cooled fast breeder nuclear reactors
International Nuclear Information System (INIS)
Durston, J.G.
1976-01-01
It is stated that in a liquid metal cooled fast breeder reactor wherein the core, intermediate heat exchangers and liquid metal pumps are immersed in a pool of coolant such as Na, the intermediate heat exchangers are suspended from the roof, and ducting is provided in the form of a core tank or shroud interconnected with 'pods' housing the intermediate exchangers for directing coolant from the core over the heat exchanger tubes and thence back to the main pool of liquid metal. Seals are provided between the intermediate heat exchanger shells and the walls of their 'pods' to prevent liquid metal flow by-passing the heat exchanger tube bundles. As the heat exchangers must be withdrawable for servicing, and because linear differential thermal expansion of the heat exchanger and its 'pod' must be accommodated the seals hitherto have been of the sliding kind, generally known as 'piston ring type seals'. These present several disadvantages; for example sealing is not absolute, and the metal to metal seal gives rise to wear and fretting by rubbing and vibration. This could lead to seizure or jamming by the deposition of impurities in the coolant. Another difficulty arises in the need to accommodate lateral thermal expansion of the ducting, including the core tank and 'pods'. Hitherto some expansion has been allowed for by the use of expansible bellow pairs in the interconnections, or alternatively by allowing local deformations of the core tank 'pods'. Such bellows must be very flexible and hence constitute a weak section of the ducting, and local deformations give rise to high stress levels that could lead to premature failure. The arrangement described seeks to overcome these difficulties by use of a gas pocket trapping means to effect a seal against vertical liquid flow between the heat exchanger shell and the wall of the heat exchanger housing. Full details of the arrangement are described. (U.K.)
Status of liquid metal cooled fast reactor technology
Energy Technology Data Exchange (ETDEWEB)
NONE
1999-04-01
During the period 1985-1998, there have been substantial advances in fast reactor technology development. Chief among these has been the demonstration of reliable operation by several prototypes and experimental reactors, the reliable operation of fuel at high burnup. At the IAEA meetings on liquid metal cooled fast reactor technology (LMFR), it became evident that there have been significant technological advances as well as changes in the economic and regulatory environment since 1985. Therefore the International working group on Fast Reactors has recommended the preparation of a new status report on fast reactors. The present report intends to provide comprehensive and detailed information on LMFR technology. The focus is on practical issues that are useful to engineers, scientists, managers, university students and professors, on the following topics: experience in construction and operation, reactor physics and safety, sore structural material and fuel technology, fast reactor engineering and activities in progress on LMFR plants Refs, figs, tabs
Status of liquid metal cooled fast reactor technology
International Nuclear Information System (INIS)
1999-04-01
During the period 1985-1998, there have been substantial advances in fast reactor technology development. Chief among these has been the demonstration of reliable operation by several prototypes and experimental reactors, the reliable operation of fuel at high burnup. At the IAEA meetings on liquid metal cooled fast reactor technology (LMFR), it became evident that there have been significant technological advances as well as changes in the economic and regulatory environment since 1985. Therefore the International working group on Fast Reactors has recommended the preparation of a new status report on fast reactors. The present report intends to provide comprehensive and detailed information on LMFR technology. The focus is on practical issues that are useful to engineers, scientists, managers, university students and professors, on the following topics: experience in construction and operation, reactor physics and safety, sore structural material and fuel technology, fast reactor engineering and activities in progress on LMFR plants
Performance of metallic fuels in liquid-metal fast reactors
International Nuclear Information System (INIS)
Seidel, B.R.; Walters, L.C.; Kittel, J.H.
1984-01-01
Interest in metallic fuels for liquid-metal fast reactors has come full circle. Metallic fuels are once again a viable alternative for fast reactors because reactor outlet temperature of interest to industry are well within the range where metallic fuels have demonstrated high burnup and reliable performance. In addition, metallic fuel is very tolerant of off-normal events of its high thermal conductivity and fuel behavior. Futhermore, metallic fuels lend themselves to compact and simplified reprocessing and refabrication technologies, a key feature in a new concept for deployment of fast reactors called the Integral Fast Reactor (IFR). The IFR concept is a metallic-fueled pool reactor(s) coupled to an integral-remote reprocessing and fabrication facility. The purpose of this paper is to review recent metallic fuel performance, much of which was tested and proven during the twenty years of EBR-II operation
Turbulent convection in liquid metal with and without rotation.
King, Eric M; Aurnou, Jonathan M
2013-04-23
The magnetic fields of Earth and other planets are generated by turbulent, rotating convection in liquid metal. Liquid metals are peculiar in that they diffuse heat more readily than momentum, quantified by their small Prandtl numbers, Pr rotating Rayleigh-Bénard convection experiments in the liquid metal gallium (Pr = 0.025) over a range of nondimensional buoyancy forcing (Ra) and rotation periods (E). Our primary diagnostic is the efficiency of convective heat transfer (Nu). In general, we find that the convective behavior of liquid metal differs substantially from that of moderate Pr fluids, such as water. In particular, a transition between rotationally constrained and weakly rotating turbulent states is identified, and this transition differs substantially from that observed in moderate Pr fluids. This difference, we hypothesize, may explain the different classes of magnetic fields observed on the Gas and Ice Giant planets, whose dynamo regions consist of Pr 1 fluids, respectively.
Yang, Yanqin; Sun, Na; Wen, Zhen; Cheng, Ping; Zheng, Hechuang; Shao, Huiyun; Xia, Yujian; Chen, Chen; Lan, Huiwen; Xie, Xinkai; Zhou, Changjie; Zhong, Jun; Sun, Xuhui; Lee, Shuit-Tong
2018-02-27
The rapid advancement of intelligent wearable electronics imposes the emergent requirement for power sources that are deformable, compliant, and stretchable. Power sources with these characteristics are difficult and challenging to achieve. The use of liquid metals as electrodes may provide a viable strategy to produce such power sources. In this work, we propose a liquid-metal-based triboelectric nanogenerator (LM-TENG) by employing Galinstan as the electrode and silicone rubber as the triboelectric and encapsulation layer. The small Young's modulus of the liquid metal ensures the electrode remains continuously conductive under deformations, stretching to a strain as large as ∼300%. The surface oxide layer of Galinstan effectively prevents the liquid Galinstan electrode from further oxidization and permeation into silicone rubber, yielding outstanding device stability. Operating in the single-electrode mode at 3 Hz, the LM-TENG with an area of 6 × 3 cm 2 produces an open-circuit voltage of 354.5 V, transferred short-circuit charge of 123.2 nC, short-circuit current of 15.6 μA, and average power density of 8.43 mW/m 2 , which represent outstanding performance values for TENGs. Further, the LM-TENG maintains stable performance under various deformations, such as stretching, folding, and twisting. LM-TENGs in different forms, such as bulk-shaped, bracelet-like, and textile-like, are all able to harvest mechanical energy from human walking, arm shaking, or hand patting to sustainably drive wearable electronic devices.
Many-Body Potentials For Binary Immiscible liquid Metal Alloys
International Nuclear Information System (INIS)
Karaguelle, H.
2004-01-01
The modified analytic embedded atom method (MAEAM) type many- body potentials have been constructed for three binary liquid immiscible alloy systems: Al-Pb, Ag-Ni, Ag- Cu. The MAEAM potential functions are fitted to both solid and liquid state properties for only liquid pure metals which consist the immiscible alloy. In order to test the reliability of the constructed MAEAM effective potentials, partial structure factors and pair distribution functions of these binary liquid metal alloys have been calculated using the thermodynamically self-consistent variational modified hypernetted chain (VMHNC) theory of liquids. A good agreement with the available experimental data for structure has
Surface studies of liquid metals and alloys
International Nuclear Information System (INIS)
Bastasz, Robert
2003-01-01
Liquid metals and alloys have been proposed for use in nuclear fusion reactors to serve as replaceable plasma-facing surfaces that remove particles and heat from reacting plasmas. Several materials are being considered for this purpose including lithium, gallium, and tin as well as some of the alloys made from these elements. In order to better understand the properties of liquid surfaces, the technique of low-energy ion scattering was used to examine the surface composition of several of these materials in vacuum as a function of temperature. Oxygen is found to rapidly segregate to the surface of several metallic liquids. The segregation process can be interpreted using a simple thermodynamic model based on Gibbs theory. In the case of an alloy of Sn and Li, Li also segregates to the liquid surface. This provides a means to produce a surface enriched in Li, which is more plasma compatible than Sn, without the need to handle large quantities of liquid Li. (author)
Space- and time-resolved resistive measurements of liquid metal wall thickness
Energy Technology Data Exchange (ETDEWEB)
Mirhoseini, S. M. H.; Volpe, F. A., E-mail: fvolpe@columbia.edu [Department of Applied Physics and Applied Mathematics, Columbia University, New York, New York 10027 (United States)
2016-11-15
In a fusion reactor internally coated with liquid metal, it will be important to diagnose the thickness of the liquid at various locations in the vessel, as a function of time, and possibly respond to counteract undesired bulging or depletion. The electrical conductance between electrodes immersed in the liquid metal can be used as a simple proxy for the local thickness. Here a matrix of electrodes is shown to provide spatially and temporally resolved measurements of liquid metal thickness in the absence of plasma. First a theory is developed for m × n electrodes, and then it is experimentally demonstrated for 3 × 1 electrodes, as the liquid stands still or is agitated by means of a shaker. The experiments were carried out with Galinstan, but are easily extended to lithium or other liquid metals.
Space- and time-resolved resistive measurements of liquid metal wall thickness
International Nuclear Information System (INIS)
Mirhoseini, S. M. H.; Volpe, F. A.
2016-01-01
In a fusion reactor internally coated with liquid metal, it will be important to diagnose the thickness of the liquid at various locations in the vessel, as a function of time, and possibly respond to counteract undesired bulging or depletion. The electrical conductance between electrodes immersed in the liquid metal can be used as a simple proxy for the local thickness. Here a matrix of electrodes is shown to provide spatially and temporally resolved measurements of liquid metal thickness in the absence of plasma. First a theory is developed for m × n electrodes, and then it is experimentally demonstrated for 3 × 1 electrodes, as the liquid stands still or is agitated by means of a shaker. The experiments were carried out with Galinstan, but are easily extended to lithium or other liquid metals.
Thermal behaviors of liquid La-based bulk metallic glasses
Energy Technology Data Exchange (ETDEWEB)
Zhang, D. W.; Wang, X. D., E-mail: wangxd@zju.edu.cn, E-mail: jiangjz@zju.edu.cn; Lou, H. B.; Cao, Q. P.; Jiang, J. Z., E-mail: wangxd@zju.edu.cn, E-mail: jiangjz@zju.edu.cn [International Center for New-Structured Materials (ICNSM), Laboratory of New-Structured Materials, State Key Laboratory of Silicon Materials, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Wang, L. W. [Institute of Materials Science and Engineering, Lanzhou University, Lanzhou 730000 (China); Zhang, D. X. [State Key Laboratory of Modern Optical Instrumentation, Zhejiang University, Hangzhou 310027 (China)
2014-12-14
Thermal behaviors of liquid La-based bulk metallic glasses have been measured by using the dilatometer with a self-sealed sample cell. It is demonstrated that the strong glass forming liquid not only has the small thermal expansion coefficient but also shows the slow variation rate. Moreover, the strong glass former has relatively dense atomic packing and also small density change in the liquid state. The results suggest that the high glass forming ability of La-based metallic glasses would be closely related to the slow atomic rearrangements in liquid melts.
Single-magnet rotary flowmeter for liquid metals
Priede, Jānis; Buchenau, Dominique; Gerbeth, Gunter
2010-01-01
We present a theory of single-magnet flowmeter for liquid metals and compare it with experimental results. The flowmeter consists of a freely rotating permanent magnet, which is magnetized perpendicularly to the axle it is mounted on. When such a magnet is placed close to a tube carrying liquid metal flow, it rotates so that the driving torque due to the eddy currents induced by the flow is balanced by the braking torque induced by the rotation itself. The equilibrium rotation rate, which var...
Liquid metal flow control by DC electromagnetic pumps
International Nuclear Information System (INIS)
Borges, Eduardo Madeira; Braz Filho, Francisco Antonio; Guimaraes, Lamartine Nogueira Frutuoso
2006-01-01
The cooling system of high-density thermal power requires fluids of high thermal conductivity, such as liquid metals. Electromagnetic pumps can be used to liquid metal fluid flow control in cooling circuits. The operation of electromagnetic pumps used to flow control is based on Lorentz force. This force can be achieved by magnetic field and electric current interaction, controlled by external independent power supplies. This work presents the electromagnetic pump operational principles, the IEAv development scheme and the BEMC-1 simulation code. The theoretical results of BEMC-1 simulation are compared to electromagnetic pump operation experimental data, validating the BEMC-1 code. This code is used to evaluate the DC electromagnetic pump performance applied to Mercury flow control and others liquid metal such as Sodium, Lead and Bismuth, used in nuclear fast reactors. (author)
Liquid metal degassing in electromagnetic mixing
Energy Technology Data Exchange (ETDEWEB)
Pakhomov, A I; EHL' -FAVAKHRI, KAMAL' -ABD-RABU MOKHAMED [LENINGRADSKIJ POLITEKHNICHESKIJ INST. (USSR)
1977-01-01
Experimental results for laboratory and industrial conditions are presented showing the favourable effect of electromagnetic mixing on hot metal degassing process. It has been found that the intensity and duration of the mixing process increase with the degree of iron and steel degassing. Initiation of cavitation phenomena during hot metal electromagnetic mixing is intensified because of the presence of alien inclusions in the metal reducing the tensile strength of the liquid metal. This is the most substantial factor contributing to the gas content in the process of electromagnetic mixing.
Delayed neutrons in liquid metal spallation targets
International Nuclear Information System (INIS)
Ridikas, D.; Bokov, P.; David, J.C.; Dore, D.; Giacri, M.L.; Van Lauwe, A.; Plukiene, R.; Plukis, A.; Ignatiev, S.; Pankratov, D.
2003-01-01
The next generation spallation neutron sources, neutrino factories or RIB production facilities currently being designed and constructed around the world will increase the average proton beam power on target by a few orders of magnitude. Increased proton beam power results in target thermal hydraulic issues leading to new target designs, very often based on flowing liquid metal targets such as Hg, Pb, Pb-Bi. Radioactive nuclides produced in liquid metal targets are transported into hot cells, past electronics, into pumps with radiation sensitive components, etc. Besides the considerable amount of photon activity in the irradiated liquid metal, a significant amount of the delayed neutron precursor activity can be accumulated in the target fluid. The transit time from the front of a liquid metal target into areas, where delayed neutrons may be important, can be as short as a few seconds, well within one half-life of many delayed neutron precursors. Therefore, it is necessary to evaluate the total neutron flux (including delayed neutrons) as a function of time and determine if delayed neutrons contribute significantly to the dose rate. In this study the multi-particle transport code MCNPX combined with the material evolution program CINDER'90 will be used to evaluate the delayed neutron flux and spectra. The following scientific issues will be addressed in this paper: - Modeling of a typical geometry of the liquid metal spallation target; - Predictions of the prompt neutron fluxes, fission fragment and spallation product distributions; - Comparison of the above parameters with existing experimental data; - Time-dependent calculations of delayed neutron precursors; - Neutron flux estimates due to the prompt and delayed neutron emission; - Proposal of an experimental program to measure delayed neutron spectra from high energy spallation-fission reactions. The results of this study should be directly applicable in the design study of the European MegaPie (1 MW
Advanced Liquid Feed Experiment
Distefano, E.; Noll, C.
1993-06-01
The Advanced Liquid Feed Experiment (ALFE) is a Hitchhiker experiment flown on board the Shuttle of STS-39 as part of the Space Test Payload-1 (STP-1). The purpose of ALFE is to evaluate new propellant management components and operations under the low gravity flight environment of the Space Shuttle for eventual use in an advanced spacecraft feed system. These components and operations include an electronic pressure regulator, an ultrasonic flowmeter, an ultrasonic point sensor gage, and on-orbit refill of an auxiliary propellant tank. The tests are performed with two transparent tanks with dyed Freon 113, observed by a camera and controlled by ground commands and an on-board computer. Results show that the electronic pressure regulator provides smooth pressure ramp-up, sustained pressure control, and the flexibility to change pressure settings in flight. The ultrasonic flowmeter accurately measures flow and detects gas ingestion. The ultrasonic point sensors function well in space, but not as a gage during sustained low-gravity conditions, as they, like other point gages, are subject to the uncertainties of propellant geometry in a given tank. Propellant transfer operations can be performed with liquid-free ullage equalization at a 20 percent fill level, gas-free liquid transfer from 20-65 percent fill level, minimal slosh, and can be automated.
Difference in x-ray scattering between metallic and non-metallic liquids due to conduction electrons
International Nuclear Information System (INIS)
Chihara, Junzo
1987-01-01
X-ray scattered intensity from a liquid metal as an electron-ion mixture is described using the structure factors, which are exactly expressed in terms of the static and dynamic direct correlation functions. This intensity for a metal is shown to differ from the usual scattered intensity from a non-metal in two points: the atomic form factor and the incoherent (Compton) scattering factor. It is shown that the valence electron form factor, which constitutes the atomic form factor in a liquid metal, leads to a determination of the electron-electron and electron-ion structure factors by combining the ionic structure factor. It is also shown that a part of the electron structure factor, which appears as the incoherent x-ray scattering, is usually approximated as the electron structure factor of the jellium model in the case of a simple metal. As a by-product, the x-ray scattered intensity from a crystalline metal and the inelastic scattering from a liquid metal are given by taking account of the presence of conduction electrons. In this way, we clarify some confusion which appeared in the proposal by Egelstaff et al for extracting the electron-electron correlation function in a metal from x-ray and neutron scattering experiments. A procedure to extract the electron-electron and electron-ion structure factors in a liquid metal is proposed on the basis of formula for scattered intensity derived here. (author)
An innovative liquid metal design with worldwide application potential
International Nuclear Information System (INIS)
Quinn, J.E.; Berglund, R.C.
1989-01-01
This paper reports that the United States nuclear program has been faced with major political, economic and technical challenges in recent years. One US program element, the Liquid Metal Reactor, has addressed these challenges in a systematic, focused manner. The result is an innovative modular design incorporating safety features that utilize inherent characteristics. This Advanced Liquid Metal Reactor (ALMR) is based on the PRISM concept, originated by the General Electric Company in 1981. This design should also be attractive in other developed countries that have deployed, and/or are deploying, nuclear power. The design's safety features can achieve neutronic shutdown and decay heat removal without relying on operator action or engineered active safety features. The ALMR utilizes many innovations including: a passive reactor vessel air cooling system for decay heat removal; the use of a sealed reactor assembly; seismic isolation; electromagnetic primary pumps; and an in-vessel fuel transfer machine. The US ALMR design incorporates a metal fuel core as its reference, however, the required safety performance can also be achieved with an oxide core having similar safety features. This flexibility is particularly important when addressing world wide ALMR applications. The reference ALMR reactor module, of which there are nine in a typical 1395 MW e plant, has a -6 meter by -20 meter vessel and a 471 MW thermal output, with a reactor outlet temperature of 485 degrees C and an overall conversion efficiency of 33%. This plant uses a saturated steam cycle and a non-safety grade secondary sodium system
Mechanical pumps for liquid metals; Pompes mecaniques pour metaux liquides
Energy Technology Data Exchange (ETDEWEB)
Baumier, J; Gollion, H J [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires
1964-07-01
The pumping of liquid metals by centrifugal pumps poses two principal problems. These are hermetic sealing of the rotating shaft and, its guidance where immersed in liquid metal. The solutions to the problems used on 13 experimental pumps are given here. The resolution of the guidance problem consists in the majority of cases in the utilisation of hydrostatic bearings. Accordingly, a theoretical study was instituted for the first time to calculate the bearings of the earlier pumps. After this, an experimental study was carried out, to check the theory by water tests. A relation for bearing calculation of pumps with diffusers is proposed. Finally the influence of the bearing elasticity on the shafts critical speed is studied. (authors) [French] Le pompage des metaux liquides, par des pompes centrifuges, pose 2 principaux problemes, qui sont: d'une part, la realisation d'une excellente etancheite au passage de l'arbre, d'autre part, son guidage sur la partie immergee dans le metal liquide. Les solutions retenues pour resoudre ces problemes sur 13 pompes experimentees sont presentees. Le probleme du guidage de l'arbre, a dans la majorite des cas ete resolu en utilisant un palier hydrostatique, aussi l'etude en a d'abord ete approfondie de facon theorique pour calculer les paliers des premieres pompes, puis experimentale pour controler la theorie, en effectuant des essais a l'eau. On propose une relation pour calculer les paliers des pompes a diffuseurs. On a en outre effectue une etude de l'influence de l'elasticite du palier hydrostatique sur la vitesse critique de l'arbre. (auteurs)
On-Chip Production of Size-Controllable Liquid Metal Microdroplets Using Acoustic Waves.
Tang, Shi-Yang; Ayan, Bugra; Nama, Nitesh; Bian, Yusheng; Lata, James P; Guo, Xiasheng; Huang, Tony Jun
2016-07-01
Micro- to nanosized droplets of liquid metals, such as eutectic gallium indium (EGaIn) and Galinstan, have been used for developing a variety of applications in flexible electronics, sensors, catalysts, and drug delivery systems. Currently used methods for producing micro- to nanosized droplets of such liquid metals possess one or several drawbacks, including the lack in ability to control the size of the produced droplets, mass produce droplets, produce smaller droplet sizes, and miniaturize the system. Here, a novel method is introduced using acoustic wave-induced forces for on-chip production of EGaIn liquid-metal microdroplets with controllable size. The size distribution of liquid metal microdroplets is tuned by controlling the interfacial tension of the metal using either electrochemistry or electrocapillarity in the acoustic field. The developed platform is then used for heavy metal ion detection utilizing the produced liquid metal microdroplets as the working electrode. It is also demonstrated that a significant enhancement of the sensing performance is achieved by introducing acoustic streaming during the electrochemical experiments. The demonstrated technique can be used for developing liquid-metal-based systems for a wide range of applications. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Advances in gas-liquid flows 1990
International Nuclear Information System (INIS)
Kim, J.M.; Hashemi, A.
1990-01-01
Gas-liquid two-phase flows commonly occur in nature and industrial applications. Rain, clouds, geysers, and waterfalls are examples of natural gas-liquid flow phenomena, whereas industrial applications can be found in nuclear reactors, steam generators, boilers, condensers, evaporators, fuel atomization, heat pipes, electronic equipment cooling, petroleum engineering, chemical process engineering, and many others. The household-variety phenomena such as garden sprinklers, shower, whirlpool bath, dripping faucet, boiling tea pot, and bubbling beer provide daily experience of gas-liquid flows. The papers presented in this volume reflect the variety and richness of gas-liquid two-phase flow and the increasing role it plays in modern technology. This volume contains papers dealing with some recent development in gas-liquid flow science and technology, covering basic gas-liquid flows, measurements and instrumentation, cavitation and flashing flows, countercurrent flow and flooding, flow in various components and geometries liquid metals and thermocapillary effects, heat transfer, nonlinear phenomena, instability, and other special and general topics related to gas-liquid flows
Single channel double-duct liquid metal electrical generator using a magnetohydrodynamic device
Haaland, Carsten M.; Deeds, W. Edward
1999-01-01
A single channel double-duct liquid metal electrical generator using a magnetohydrodynamic (MHD) device. The single channel device provides useful output AC electric energy. The generator includes a two-cylinder linear-piston engine which drives liquid metal in a single channel looped around one side of the MHD device to form a double-duct contra-flowing liquid metal MHD generator. A flow conduit network and drive mechanism are provided for moving liquid metal with an oscillating flow through a static magnetic field to produce useful AC electric energy at practical voltages and currents. Variable stroke is obtained by controlling the quantity of liquid metal in the channel. High efficiency is obtained over a wide range of frequency and power output.
Energy Technology Data Exchange (ETDEWEB)
Kim, Moo Hwan; Cha, Jae Eun [Pohang University of Science and Technology, Pohang (Korea)
2000-04-01
The technology which models and measures the behavior of bubble in liquid sodium is very important to insure the safety of the liquid metal reactor. In this research, we designed/ manufactured each part and loop of experimental facility for sodium two phase flow, and applied a few possible methods, measured characteristic of two phase flow such as bubbly flow. A air-water loop similar to sodium loop on each measuring condition was designed/manufactured. This air-water loop was utilized to acquire many informations which were necessary in designing the two phase flow of sodium and manufacturing experimental facility. Before the manufacture of a electromagnetic flow meter for sodium, the experiment using each electromagnetic flow mete was developed and the air-water loop was performed to understand flow characteristics. Experiments for observing the signal characteristics of flow were performed by flowing two phase mixture into the electromagnetic flow mete. From these experiments, the electromagnetic flow meter was designed and constructed by virtual electrode, its signal processing circuit and micro electro magnet. It was developed to be applicable to low conductivity fluid very successfully. By this experiment with the electromagnetic flow meter, we observed that the flow signal was very different according to void fraction in two phase flow and that probability density function which was made by statistical signal treatment is also different according to flow patterns. From this result, we confirmed that the electromagnetic flow meter could be used to understand the parameters of two phase flow of sodium. By this study, the experimental facility for two phase flow of sodium was constricted. Also the new electromagnetic flow meter was designed/manufactured, and experimental apparatus for two phase flow of air-water. Finally, this study will be a basic tool for measurement of two phase flow of sodium. As the fundamental technique for the applications of sodium at
Five-fold local symmetry in metallic liquids and glasses
International Nuclear Information System (INIS)
Li M Z; Li F X; Zhang H P; Peng H L; Hu Y C; Wang W H
2017-01-01
The structure of metallic glasses has been a long-standing mystery. Owing to the disordered nature of atomic structures in metallic glasses, it is a great challenge to find a simple structural description, such as periodicity for crystals, for establishing the structure–property relationship in amorphous materials. In this paper, we briefly review the recent developments of the five-fold local symmetry in metallic liquids and glasses and the understanding of the structure–property relationship based on this parameter. Experimental evidence demonstrates that five-fold local symmetry is found to be general in metallic liquids and glasses. Comprehensive molecular dynamics simulations show that the temperature evolution of five-fold local symmetry reflects the structural evolution in glass transition in cooling process, and the structure–property relationship such as relaxation dynamics, dynamic crossover phenomena, glass transition, and mechanical deformation in metallic liquids and glasses can be well understood base on the simple and general structure parameter of five-fold local symmetry. (paper)
Liquid metal-organic frameworks
Gaillac, Romain; Pullumbi, Pluton; Beyer, Kevin A.; Chapman, Karena W.; Keen, David A.; Bennett, Thomas D.; Coudert, François-Xavier
2017-11-01
Metal-organic frameworks (MOFs) are a family of chemically diverse materials, with applications in a wide range of fields, covering engineering, physics, chemistry, biology and medicine. Until recently, research has focused almost entirely on crystalline structures, yet now a clear trend is emerging, shifting the emphasis onto disordered states, including `defective by design’ crystals, as well as amorphous phases such as glasses and gels. Here we introduce a strongly associated MOF liquid, obtained by melting a zeolitic imidazolate framework. We combine in situ variable temperature X-ray, ex situ neutron pair distribution function experiments, and first-principles molecular dynamics simulations to study the melting phenomenon and the nature of the liquid obtained. We demonstrate from structural, dynamical, and thermodynamical information that the chemical configuration, coordinative bonding, and porosity of the parent crystalline framework survive upon formation of the MOF liquid.
Liquid metal level measurement
International Nuclear Information System (INIS)
Hale, J.C.; Leyland, K.S.
1982-01-01
A liquid metal level indicator is described which can be used to measure, in a stainless steel tank, the level of a nuclear reactor coolant such as sodium. The instrument, which is based on the eddy current induction effect, gives readings over substantially the full depth of the tank and indicates the sense of change of level. (U.K.)
3D Printed Wearable Sensors with Liquid Metals for the Pose Detection of Snakelike Soft Robots.
Zhou, Luyu; Gao, Qing; Zhan, Jun-Fu; Xie, Chao-Qi; Fu, Jianzhong; He, Yong
2018-06-18
Liquid metal-based flexible sensors, which utilize advanced liquid conductive material to serve as sensitive element, is emerging as a promising solution to measure large deformations. Nowadays, one of the biggest challenges for precise control of soft robots is the detection of their real time positions. Existing fabrication methods are unable to fabricate flexible sensors that match the shape of soft robots. In this report, we firstly described a novel 3D printed multi-function inductance flexible and stretchable sensor with liquid metals (LMs), which is capable of measuring both axial tension and curvature. This sensor is fabricated with a developed coaxial liquid metal 3D printer by co-printing of silicone rubber and LMs. Due to the solenoid shape, this sensor can be easily installed on snakelike soft robots and can accurately distinguish different degrees of tensile and bending deformation. We determined the structural parameters of the sensor and proved its excellent stability and reliability. As a demonstration, we used this sensor to measure the curvature of a finger and feedback the position of endoscope, a typical snakelike structure. Because of its bending deformation form consistent with the actual working status of the soft robot and unique shape, this sensor has better practical application prospects in the pose detection.
Directory of Open Access Journals (Sweden)
Eun Je Lee
2013-01-01
Full Text Available This study investigates the effect of liquid gallium (Ga on metal foils made of titanium (Ti, niobium (Nb, and molybdenum (Mo. The Ti, Nb, and Mo foils were heated in liquid Ga at 120°C for a maximum of two weeks. After heating, the changes in the morphology and the chemical composition of the metal foils were analyzed by using a field emission scanning electron microscope, energy-dispersive X-ray spectrometer, X-ray diffractometer, and X-ray photoelectron spectrometer. The results of the analysis indicated that the Nb foil showed the minimum adhesion of liquid Ga to the surface while the maximum amount of liquid Ga was observed to adhere to the Ti foil. In addition, the Nb foil was oxidized and the Mo foil was reduced during the heating process. Considering these effects, we conclude that Mo may be used as an alternative encapsulation material for Ga in addition to Nb, which is used as the conventional encapsulation material, due to its chemical resistance against oxidation in hot liquid Ga.
Liquid metals. Coexistence line, critical parameters, compressibility
International Nuclear Information System (INIS)
Filippov, L.P.
1986-01-01
Formulae to calculate four characteristic parameters of liquid metals (density, compressibility, critical temperature and individual parameter) according to four initial data are obtained: two values of vapor density and two values of vapor pressure. Comparison between experimental and calculation results are presented for liquid Cs, Na, Li, K, Rb
Component and Technology Development for Advanced Liquid Metal Reactors
Energy Technology Data Exchange (ETDEWEB)
Anderson, Mark [Univ. of Wisconsin, Madison, WI (United States)
2017-01-30
The following report details the significant developments to Sodium Fast Reactor (SFR) technologies made throughout the course of this funding. This report will begin with an overview of the sodium loop and the improvements made over the course of this research to make it a more advanced and capable facility. These improvements have much to do with oxygen control and diagnostics. Thus a detailed report of advancements with respect to the cold trap, plugging meter, vanadium equilibration loop, and electrochemical oxygen sensor is included. Further analysis of the university’s moving magnet pump was performed and included in a section of this report. A continuous electrical resistance based level sensor was built and tested in the sodium with favorable results. Materials testing was done on diffusion bonded samples of metal and the results are presented here as well. A significant portion of this work went into the development of optical fiber temperature sensors which could be deployed in an SFR environment. Thus, a section of this report presents the work done to develop an encapsulation method for these fibers inside of a stainless steel capillary tube. High temperature testing was then done on the optical fiber ex situ in a furnace. Thermal response time was also explored with the optical fiber temperature sensors. Finally these optical fibers were deployed successfully in a sodium environment for data acquisition. As a test of the sodium deployable optical fiber temperature sensors they were installed in a sub-loop of the sodium facility which was constructed to promote the thermal striping effect in sodium. The optical fibers performed exceptionally well, yielding unprecedented 2 dimensional temperature profiles with good temporal resolution. Finally, this thermal striping loop was used to perform cross correlation velocimetry successfully over a wide range of flow rates.
Liquid metal cooled fast breeder nuclear reactor
International Nuclear Information System (INIS)
Scott, D.
1979-01-01
A liquid metal cooled fast breeder nuclear reactor has a core comprising a plurality of fuel assemblies supported on a diagrid and submerged in a pool of liquid metal coolant within a containment vessel, the diagrid being of triple component construction and formed of a short cylindrical plenum mounted on a conical undershell and loosely embraced by a fuel store carrier. The plenum merely distributes coolant through the fuel assemblies, the load of the assemblies being carried by the undershell by means of struts which penetrate the plenum. The reactor core, fuel store carrier and undershell provide secondary containment for the plenum. (UK)
Review of the critical heat flux correlations for liquid metals
International Nuclear Information System (INIS)
Lee, Yong Bum; Han, H. D.; Chang, W. P.; Kwon, Y. M.
1999-09-01
The CHF phenomenon in the two-phase convective flows has been an important issue in the fields of design and safety analysis of light water reactor (LWR) as well as sodium cooled liquid metal reactor (LMR). Especially in the LWR application, many physical aspects of the CHF phenomenon are understood and reliable correlations and mechanistic models to predict the CHF condition have been proposed over the past three decades. Most of the existing CHF correlations have been developed for light water reactor core applications. Compared with water, liquid metals show a divergent picture of boiling pattern. This can be attributed to the consequence that special CHF conditions obtained from investigations with water cannot be applied to liquid metals. Numerous liquid metal boiling heat transfer and two-phase flow studies have put emphasis on development of models and understanding of the mechanism for improving the CHF predictions. Thus far, no overall analytical solution method has been obtained and the reliable prediction method has remained empirical. The principal objectives of the present report are to review the state of the art in connection with liquid metal critical heat flux under low pressure and low flow conditions and to discuss the basic mechanisms. (author)
Design of self-cooled, liquid-metal blankets for tokamak and tandem mirror reactors
International Nuclear Information System (INIS)
Cha, Y.S.; Gohar, Y.; Hassanein, A.M.; Majumdar, S.; Picologlou, B.F.; Smith, D.L.; Szo, D.K.
1985-01-01
Results of the self-cooled, liquid-metal blanket design from the Blanket Comparison and Selection Study (BCSS) are summarized. The objectives of the BCSS project are to define a small number (about three) of blanket concepts that should be the focus of the blanket research and development (RandD) program, identify and prioritize the critical issues for the leading blanket concepts, and provide technical input necessary to develop a blanket RandD program plan. Two liquid metals (lithium and lithium-lead (17Li-83Pb)) and three structural materials (primary candidate alloy (PCA), ferritic steel (FS) (HT-9), and vanadium alloy (V-15 Cr-5 Ti)) are included in the evaluations for both tokamaks and tandem mirror reactors (TMRs). TMR is of the tube configuration similar to the Mirror Advanced Reactor Study design. Analyses were performed in the following generic areas for each blanket concept: MHD, thermal hydraulics, stress, neutronics, and tritium recovery. Integral analyses were performed to determine the design window for each blanket design. The Li/Li/V blanket for tokamak and the Li/Li/V, LiPb/LiPb/V, and Li/Li/HT-9 blankets for the TMR are judged to be top-rated concepts. Because of its better thermophysical properties and more uniform nuclear heating profile, liquid lithium is a better coolant than liquid 17Li83Pb. From an engineering point of view, vanadium alloy is a better structural material than either FS or PCA since the former has both a higher allowable structural temperature and a higher allowable coolant/structure interface temperature than the latter. Critical feasibility issues and design constraints for the self-cooled, liquid-metal blanket concepts are identified and discussed
A conceptual design strategy for liquid-metal-wall inertial fusion reactors
International Nuclear Information System (INIS)
Monsler, M.J.; Meier, W.R.
1981-01-01
The liquid-metal-wall chamber has emerged as an attractive reactor concept for inertial fusion energy conversion. The principal feature of this concept is a thick, free-flowing blanket of liquid metal used to protect the structure of the reactor. The development and design of liquid-metal-wall chambers over the past decade are reviewed from the perspective of formulating a conceptual design strategy for such chambers. The basis for the design strategy is set by enumerating both the attractive and unattractive features of a LMW chamber. Past concepts are then reviewed to identify conceptual design approaches and physical configurations that enhance the positive aspects and minimize the negative aspects. A detailed description of the engineering considerations is given, including such topics as the selection of a liquid metal, control of radiation damage, selection of structural material, control of tritium breeding and extraction, control of wall stress, and designing for a given rep-rate. Finally, a design strategy is formulated which accomodates the engineering constraints while minimizing the liquid-metal flow rate. (orig.)
Modeling of liquid-metal corrosion/deposition in a fusion reactor blanket
International Nuclear Information System (INIS)
Malang, S.; Smith, D.L.
1984-04-01
A model has been developed for the investigation of the liquid-metal corrosion and the corrosion product transport in a liquid-metal-cooled fusion reactor blanket. The model describes the two-dimensional transport of wall material in the liquid-metal flow and is based on the following assumptions: (1) parallel flow in a straight circular tube; (2) transport of wall material perpendicular to the flow direction by diffusion and turbulent exchange; in flow direction by the flow motion only; (3) magnetic field causes uniform velocity profile with thin boundary layer and suppresses turbulent mass exchange; and (4) liquid metal at the interface is saturated with wall material. A computer code based on this model has been used to analyze the corrosion of ferritic steel by lithium lead and the deposition of wall material in the cooler part of a loop. Three cases have been investigated: (1) ANL forced convection corrosion experiment (without magnetic field); (2) corrosion in the MARS liquid-metal-cooled blanket (with magnetic field); and (3) deposition of wall material in the corrosion product cleanup system of the MARS blanket loop
Liquid-solid extraction of metallic cations by cationic amphiphiles
International Nuclear Information System (INIS)
Mueller, Wolfram; Sievers, Torsten K.; Zemb, Thomas; Diat, Olivier; Sievers, Torsten K.; Dejugnat, Christophe
2012-01-01
In the field of selective metal ion separation, liquid-liquid extraction is usually conducted through an emulsion mixing of hydrophobic complexants dispersed in an organic phase and acidic water containing the ionic species. Recently, it has been shown that amphiphilic complexants could influence strongly extraction efficiency by enhancing the interfacial interaction between the metal ion in the aqueous and the complexant in the organic phase. Moreover, these amphiphiles can also substitute the organic phase if an appropriate aliphatic chain is chosen. The dispersion of such amphiphilic complexants in an aqueous solution of salt mixtures is not only attractive for studying specific interactions but also to better the understanding of complex formation in aqueous solution of multivalent metal ions, such as lanthanides and actinides. This understanding is of potential interest for a broad range of industries including purification of rare earth metals and pollute treatment e.g. of fission byproducts. This principle can also be applied to liquid-solid extraction, where the final state of the separation is a solid phase containing the selectively extracted ions. Indeed, a novel solid-liquid extraction method exploits the selective precipitation of metal ions from an aqueous salt mixture using a cationic surfactant, below its Krafft point (temperature below which the long aliphatic chains of surfactant crystallize). This technique has been proven to be highly efficient for the separation of actinides and heavy metal using long chain ammonium or pyridinium amphiphiles. The most important point in this process is the recognition of cationic metal ions by cationic surfactants. By computing the free energy of the polar head group per micelle as a function of the different counter-anions, we have demonstrated for the first time that different interactions exist between the micellar surface and the ions. These interactions depend on the nature of the cation but also on
Energy Technology Data Exchange (ETDEWEB)
Kasza, K.; Grandy, C.; Chang, Y.; Khalil, H.; Nuclear Engineering Division
2007-06-30
This white paper provides an overview and status report of the thermal-hydraulic nuclear research and development, both experimental and computational, conducted predominantly at Argonne National Laboratory. Argonne from the early 1970s through the early 1990s was the Department of Energy's (DOE's) lead lab for thermal-hydraulic development of Liquid Metal Reactors (LMRs). During the 1970s and into the mid-1980s, Argonne conducted thermal-hydraulic studies and experiments on individual reactor components supporting the Experimental Breeder Reactor-II (EBR-II), Fast Flux Test Facility (FFTF), and the Clinch River Breeder Reactor (CRBR). From the mid-1980s and into the early 1990s, Argonne conducted studies on phenomena related to forced- and natural-convection thermal buoyancy in complete in-vessel models of the General Electric (GE) Prototype Reactor Inherently Safe Module (PRISM) and Rockwell International (RI) Sodium Advanced Fast Reactor (SAFR). These two reactor initiatives involved Argonne working closely with U.S. industry and DOE. This paper describes the very important impact of thermal hydraulics dominated by thermal buoyancy forces on reactor global operation and on the behavior/performance of individual components during postulated off-normal accident events with low flow. Utilizing Argonne's LMR expertise and design knowledge is vital to the further development of safe, reliable, and high-performance LMRs. Argonne believes there remains an important need for continued research and development on thermal-hydraulic design in support of DOE's and the international community's renewed thrust for developing and demonstrating the Global Nuclear Energy Partnership (GNEP) reactor(s) and the associated Argonne Liquid Metal-Advanced Burner Reactor (LM-ABR). This white paper highlights that further understanding is needed regarding reactor design under coolant low-flow events. These safety-related events are associated with the transition
Generation and characterization of gas bubbles in liquid metals
International Nuclear Information System (INIS)
Eckert, S.; Gerbeth, G.; Witke, W.
1996-01-01
There is an ongoing research performed in the RCR on local transport phenomena in turbulent liquid metal (LM) duct flows exposed to external magnetic fields. In this context so-called MHD flow phenomena can be observed, which are unknown in usual hydraulic engineering. The field of interest covers also the influence of magnetic fields on the behaviour of liquid metal - gas mixtures. Profound knowledge on these LMMHD two-phase flow plays an important role in a variety of technological applications, in particular, in the design of Liquid-Metal MHD generators or for several metallurgical processes employing gas-stirred reactors. However, the highly empirical nature of two-phase flow analysis gives little hope for the prediction of MHD two-phase flows without extensive experimental data. A summary is given about the authors research activities focussing on two directions: (a) Momentum transfer between gas and liquid metal in a bubbly flow regime to investigate the influence of the external magnetic field on the velocity slip ration S (b) Peculiarities of the MHD turbulence to use small gas bubbles as local tracers in order to study the turbulent mass transfer
Dewetting Properties of Metallic Liquid Film on Nanopillared Graphene
Li, Xiongying; He, Yezeng; Wang, Yong; Dong, Jichen; Li, Hui
2014-01-01
In this work, we report simulation evidence that the graphene surface decorated by carbon nanotube pillars shows strong dewettability, which can give it great advantages in dewetting and detaching metallic nanodroplets on the surfaces. Molecular dynamics (MD) simulations show that the ultrathin liquid film first contracts then detaches from the graphene on a time scale of several nanoseconds, as a result of the inertial effect. The detaching velocity is in the order of 10 m/s for the droplet with radii smaller than 50 nm. Moreover, the contracting and detaching behaviors of the liquid film can be effectively controlled by tuning the geometric parameters of the liquid film or pillar. In addition, the temperature effects on the dewetting and detaching of the metallic liquid film are also discussed. Our results show that one can exploit and effectively control the dewetting properties of metallic nanodroplets by decorating the surfaces with nanotube pillars. PMID:24487279
Engineering: Liquid metal pumped at a record temperature
Lambrinou, Konstantina
2017-10-01
Although liquid metals are effective fluids for heat transfer, pumping them at high temperatures is limited by their corrosiveness to solid metals. A clever pump design addresses this challenge using only ceramics. See Article p.199
Natural convection and boiling heat transfer of a liquid metal in a magnetic field
International Nuclear Information System (INIS)
Seki, Masahiro; Kawamura, Hiroshi
1983-02-01
A liquid metal is often assumed as a coolant and a breeding material of a Tokamak fusion reactor. However, many problems on the thermo-hydraulics of a liquid metal in a magnetic field are still remained to be studied. In the present report, natural convection and boiling of a liquid metal in a strong magnetic field are studied to examine a fundamental feasibility of a fusion reactor cooled by a liquid metal. In the experimental study of the natural convection, the circulation of a liquid metal was found to be surpressed even by a magnetic field parallel to the gravity. A numerical study has confirmed the conclusion drawn by the experiment. In the study of boiling heat transfer, stable boiling of a liquid metal has been found also in a strong magnetic field. The burnout heat flux hardly affected by the magnetic field. These indicate a fundamental feasibility of the liquid-metal cooling for a Tokamak fusion reactor. (author)
Melting and liquid structure of polyvalent metal halides
International Nuclear Information System (INIS)
Tosi, M.P.
1992-08-01
A short review is given of recent progress in determining and understanding liquid structure types and melting mechanisms for halides of polyvalent metals. The nature of the preferred local coordination for the polyvalent metal ion in the melt can usually be ascertained from data on liquid mixtures with halogen-donating alkali halides. The stability of these local coordination states and the connectivity that arises between them in the approach to the pure melt determines the character of its short-range and possible medium-range order. A broad classification of structural and melting behaviours can be given on the basis of measured melting parameters and transport coefficients for many compounds, in combination with the available diffraction data on the liquid structure of several compounds. Correlations have been shown to exist with a simple indicator of the nature of the chemical bond and also with appropriate parameters of ionic models, wherever the latter are usefully applicable for semiquantitative calculations of liquid structure. Consequences on the mechanisms for valence electron localization in solutions of metallic elements into strongly structured molten salts are also briefly discussed. (author). 46 refs, 4 figs, 2 tabs
International Nuclear Information System (INIS)
Zhuchkov, I.I.; Filonov, V.S.; Zaitsev, B.I.; Artemiev, L.N.; Rakhimov, V.V.
1976-01-01
A liquid-metal-cooled reactor is described comprising two rotatable plugs, one of them, having at least one hole, being arranged internally of the other, a recharging mechanism with a guide tube adapted to be moved through the hole of the first plug by means of a drive, and a device for detecting stacks with leaky fuel elements, the recharging mechanism tube serving as a sampler
Thermophysical properties of simple liquid metals: A brief review of theory
Stroud, David
1993-01-01
In this paper, we review the current theory of the thermophysical properties of simple liquid metals. The emphasis is on thermodynamic properties, but we also briefly discuss the nonequilibrium properties of liquid metals. We begin by defining a 'simple liquid metal' as one in which the valence electrons interact only weakly with the ionic cores, so that the interaction can be treated by perturbation theory. We then write down the equilibrium Hamiltonian of a liquid metal as a sum of five terms: the bare ion-ion interaction, the electron-electron interaction, the bare electron-ion interaction, and the kinetic energies of electrons and ions. Since the electron-ion interaction can be treated by perturbation, the electronic part contributes in two ways to the Helmholtz free energy: it gives a density-dependent term which is independent of the arrangement of ions, and it acts to screen the ion-ion interaction, giving rise to effective ion-ion pair potentials which are density-dependent, in general. After sketching the form of a typical pair potential, we briefly enumerate some methods for calculating the ionic distribution function and hence the Helmholtz free energy of the liquid: monte Carlo simulations, molecular dynamics simulations, and thermodynamic perturbation theory. The final result is a general expression for the Helmholtz free energy of the liquid metal. It can be used to calculate a wide range of thermodynamic properties of simple metal liquids, which we enumerate. They include not only a range of thermodynamic coefficients of both metals and alloys, but also many aspects of the phase diagram, including freezing curves of pure elements and phase diagrams of liquid alloys (including liquidus and solidus curves). We briefly mention some key discoveries resulting from previous applications of this method, and point out that the same methods work for other materials not normally considered to be liquid metals (such as colloidal suspensions, in which the
Enhanced Endosomal Escape by Light-Fueled Liquid-Metal Transformer.
Lu, Yue; Lin, Yiliang; Chen, Zhaowei; Hu, Quanyin; Liu, Yang; Yu, Shuangjiang; Gao, Wei; Dickey, Michael D; Gu, Zhen
2017-04-12
Effective endosomal escape remains as the "holy grail" for endocytosis-based intracellular drug delivery. To date, most of the endosomal escape strategies rely on small molecules, cationic polymers, or pore-forming proteins, which are often limited by the systemic toxicity and lack of specificity. We describe here a light-fueled liquid-metal transformer for effective endosomal escape-facilitated cargo delivery via a chemical-mechanical process. The nanoscale transformer can be prepared by a simple approach of sonicating a low-toxicity liquid-metal. When coated with graphene quantum dots (GQDs), the resulting nanospheres demonstrate the ability to absorb and convert photoenergy to drive the simultaneous phase separation and morphological transformation of the inner liquid-metal core. The morphological transformation from nanospheres to hollow nanorods with a remarkable change of aspect ratio can physically disrupt the endosomal membrane to promote endosomal escape of payloads. This metal-based nanotransformer equipped with GQDs provides a new strategy for facilitating effective endosomal escape to achieve spatiotemporally controlled drug delivery with enhanced efficacy.
The Oscillatory Nature of Rotating Convection in Liquid Metal
Aurnou, J. M.; Bertin, V. L.; Grannan, A. M.
2016-12-01
Earth's magnetic field is assumed to be generated by fluid motions in its liquid metal core. In this fluid, the heat diffuses significantly more than momentum and thus, the ratio of these two diffusivities, the Prandtl number Pr=ν/Κ, is well below unity. The convective flow dynamics of liquid metal is very different from Pr ≈ 1 fluids like water and those used in current dynamo simulations. In order to characterize rapidly rotating thermal convection in low Pr number fluids, we have performed laboratory experiments in a cylinder using liquid gallium (Pr ≈ 0.023) as the working fluid. The Ekman number, which characterizes the effect of rotation, varies from E = 4 10-5 to 4 10-6 and the dimensionless buoyancy forcing (Rayleigh number, Ra) varies from Ra =3 105 to 2 107. Using heat transfer measurements (Nusselt number, Nu) as well as temperature measurements within the fluid, we characterize the different styles of low Pr rotating convective flow. The convection threshold is first overcome in the form of a container scale inertial oscillatory mode. At stronger forcing, wall-localized modes are identified for the first time in liquid metal laboratory experiments. These wall modes coexist with the bulk inertial oscillatory modes. When the strengh of the buoyancy increases, the bulk flow becomes turbulent while the wall modes remain. Our results imply that rotating convective flows in liquid metals do not develop in the form of quasi-steady columns, as in Pr ≈ 1 dynamo models, but in the form of oscillatory motions. Therefore, the flows that drive thermally-driven dynamo action in low Pr geophysical and astrophysical fluids can differ substantively than those occuring in current-day Pr ≈ 1 numerical models. In addition, our results suggest that relatively low wavenumber, wall-attached modes may be dynamically important in rapidly-rotating convection in liquid metals.
Pumping liquid metal at high temperatures up to 1,673 kelvin
Amy, C.; Budenstein, D.; Bagepalli, M.; England, D.; Deangelis, F.; Wilk, G.; Jarrett, C.; Kelsall, C.; Hirschey, J.; Wen, H.; Chavan, A.; Gilleland, B.; Yuan, C.; Chueh, W. C.; Sandhage, K. H.; Kawajiri, Y.; Henry, A.
2017-10-01
Heat is fundamental to power generation and many industrial processes, and is most useful at high temperatures because it can be converted more efficiently to other types of energy. However, efficient transportation, storage and conversion of heat at extreme temperatures (more than about 1,300 kelvin) is impractical for many applications. Liquid metals can be very effective media for transferring heat at high temperatures, but liquid-metal pumping has been limited by the corrosion of metal infrastructures. Here we demonstrate a ceramic, mechanical pump that can be used to continuously circulate liquid tin at temperatures of around 1,473-1,673 kelvin. Our approach to liquid-metal pumping is enabled by the use of ceramics for the mechanical and sealing components, but owing to the brittle nature of ceramics their use requires careful engineering. Our set-up enables effective heat transfer using a liquid at previously unattainable temperatures, and could be used for thermal storage and transport, electric power production, and chemical or materials processing.
Gallium-Based Room-Temperature Liquid Metals: Actuation and Manipulation of Droplets and Flows
Directory of Open Access Journals (Sweden)
Leily Majidi
2017-08-01
Full Text Available Gallium-based room-temperature liquid metals possess extremely valuable properties, such as low toxicity, low vapor pressure, and high thermal and electrical conductivity enabling them to become suitable substitutes for mercury and beyond in wide range of applications. When exposed to air, a native oxide layer forms on the surface of gallium-based liquid metals which mechanically stabilizes the liquid. By removing or reconstructing the oxide skin, shape and state of liquid metal droplets and flows can be manipulated/actuated desirably. This can occur manually or in the presence/absence of a magnetic/electric field. These methods lead to numerous useful applications such as soft electronics, reconfigurable devices, and soft robots. In this mini-review, we summarize the most recent progresses achieved on liquid metal droplet generation and actuation of gallium-based liquid metals with/without an external force.
Steam generation device with heat exchange between a liquid metal coolant and the feedwater
International Nuclear Information System (INIS)
Malaval, C.
1983-01-01
The invention is particularly applicable to a liquid metal fast breeder reactor plant, the liquid metal being sodium. The steam generation device is described in detail, it allows to get an upper liquid metal level without turbulence and an easier passage for the shock wave towards the steam generator up to the liquid metal level without being laterally reflected back to the intermediate heat exchangers [fr
Analysis of the stability of native oxide films at liquid lead/metal interfaces
International Nuclear Information System (INIS)
Lesueur, C.; Chatain, D.; Gas, P.; Bergman, C.; Baque, F.
2002-01-01
The interface between liquid lead and different metallic solids (pure metals: Al, Fe and Ni, and T91 steel) was investigated below 400 deg C under ultrahigh vacuum (UHV) by wetting experiments. The aim was to check the physical stability of native oxide films grown at the surface of the substrates, along a contact with liquid lead. Two types of metallic substrates were used: i) conventional bulk polycrystals, and ii) nanocrystalline films obtained by e-beam evaporation under UHV. The actual contact between liquid lead and the solid substrates was achieved by preparing lead drops in-situ. Wetting experiments were performed using sessile drop and/or liquid bridge methods. Fresh solid surfaces and former liquid/solid interfaces can be explored by squeezing and stretching a liquid lead bridge formed between two parallel and horizontal substrates. It is shown that the contact with liquid lead produces the detachment of the native oxide films grown on the metallic solids. It is concluded that if oxide coatings are needed to protect a metallic solid from attack by liquid lead, they should be self-renewable. (authors)
Effects of loading variables on fatigue-crack growth in liquid-metal environments
CSIR Research Space (South Africa)
Fernandes, PJL
1995-10-01
Full Text Available Liquid-metal-induced embrittlement (LMIE) refers to the loss of ductility in normally ductile metals and alloys when stressed while in contact with a liquid metal. In this study, the fatigue crack growth behaviour of brass in molten gallium...
Directory of Open Access Journals (Sweden)
Marziye Ebrahimkhani
2016-02-01
Full Text Available Calculation of the core neutronic parameters is one of the key components in all nuclear reactors. In this research, the energy spectrum and spatial distribution of the neutron flux in a uranium target have been calculated. In addition, sensitivity of the core neutronic parameters in accelerator-driven subcritical advanced liquid metal reactors, such as electron beam energy (Ee and source multiplication coefficient (ks, has been investigated. A Monte Carlo code (MCNPX_2.6 has been used to calculate neutronic parameters such as effective multiplication coefficient (keff, net neutron multiplication (M, neutron yield (Yn/e, energy constant gain (G0, energy gain (G, importance of neutron source (φ∗, axial and radial distributions of neutron flux, and power peaking factor (Pmax/Pave in two axial and radial directions of the reactor core for four fuel loading patterns. According to the results, safety margin and accelerator current (Ie have been decreased in the highest case of ks, but G and φ∗ have increased by 88.9% and 21.6%, respectively. In addition, for LP1 loading pattern, with increasing Ee from 100 MeV up to 1 GeV, Yn/e and G improved by 91.09% and 10.21%, and Ie and Pacc decreased by 91.05% and 10.57%, respectively. The results indicate that placement of the Np–Pu assemblies on the periphery allows for a consistent keff because the Np–Pu assemblies experience less burn-up.
Apparatus for sealing a rotatable shield plug in a liquid metal nuclear reactor
International Nuclear Information System (INIS)
Winkleblack, R.K.
1980-01-01
An apparatus for sealing a rotatable shield plug in a nuclear reactor having liquid metal coolant is described. The apparatus includes a dip -ring seal adapted to provide a fluid barrier between the liquid metal and the atmosphere and to permit rotation of the shield plug. The apparatus also includes a static seal for the rotatable shield plug located between the dip-ring seal and the liquid metal. The static seal isolates the dip-ring seal from the liquid metal vapor during operation at power and can be disengaged for rotation of the shield plug
Experimental and numerical investigation of liquid-metal free-surface flows in spallation targets
Energy Technology Data Exchange (ETDEWEB)
Batta, A., E-mail: batta@kit.edu [Karlsruhe Institute of Technology, Germany Hermann-von-Helmholtz-PLATZ 1, 76344 Eggenstein-Leopoldshafen (Germany); Class, A.G.; Litfin, K.; Wetzel, Th. [Karlsruhe Institute of Technology, Germany Hermann-von-Helmholtz-PLATZ 1, 76344 Eggenstein-Leopoldshafen (Germany); Moreau, V.; Massidda, L. [CRS4 Centre for Advanced Studies, Research and Development in Sardinia, Polaris, Edificio 1, 09010 Pula, CA (Italy); Thomas, S.; Lakehal, D. [ASCOMP GmbH Zurich, Zurich (Switzerland); Angeli, D.; Losi, G. [DIEF – Department of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, via Vignolese 905, 41125 Modena (Italy); Mooney, K.G. [University of Massachusetts Amherst, Department of Mechanical and Industrial Engineering, Amherst (United States); Van Tichelen, K. [SCK-CEN, Belgian Nuclear Research Centre, Boeretang 200, 2400 Mol (Belgium)
2015-08-15
Highlights: • Experimental study of free surface for lead bismuth eutectic target. • Numerical investigation of free surface of a liquid metal target. • Advanced free surface modelling. - Abstract: Accelerator Driven Systems (ADS) are extensively investigated for the transmutation of high-level nuclear waste within many worldwide research programs. The first advanced design of an ADS system is currently developed in SCK• CEN, Mol, Belgium: the Multi-purpose hYbrid Research Reactor for High-tech Applications (MYRRHA). Many European research programs support the design of MYRRHA. In the framework of the Euratom project ‘Thermal Hydraulics of Innovative nuclear Systems (THINS)’ a liquid-metal free-surface experiment is performed at the Karlsruhe Liquid Metal Laboratory (KALLA) of Karlsruhe Institute of Technology (KIT). The experiment investigates a full-scale model of the concentric free-surface spallation target of MYRRHA using Lead Bismuth Eutectic (LBE) as coolant. In parallel, numerical free surface models are developed and tested which are reviewed in the article. A volume-of-fluid method, a moving mesh model, a free surface model combining the Level-Set method with Large-Eddy Simulation model and a smoothed-particle hydrodynamics approach are investigated. Verification of the tested models is based on the experimental results obtained within the THINS project and on previous water experiments performed at the University Catholic de Louvain (UCL) within the Euratom project ‘EUROpean Research Programme for the TRANSmutation of High Level Nuclear Waste in Accelerator Driven System (EUROTRANS)’. The design of the target enables a high fluid velocity and a stable surface at the beam entry. The purpose of this paper is to present an overview of both experimental and numerical results obtained for free surface target characterization. Without entering in technical details, the status, the major achievements and lessons for the future with respect to
Transient bowing of core assemblies in advanced liquid metal fast reactors
International Nuclear Information System (INIS)
Kamal, S.A.; Orechwa, Y.
1986-01-01
Two alternative core restraint concepts are considered for a conceptual design of a 900 MWth liquid metal fast reactor core with a heterogeneous layout. The two concepts, known as limited free bowing and free flowering, are evaluated based on core bowing criteria that emphasize the enhancement of inherent reactor safety. The core reactivity change during a postulated loss of flow transient is calculated in terms of the lateral displacements and displacement-reactivity-worths of the individual assemblies. The NUBOW-3D computer code is utilized to determine the assembly deformations and interassembly forces that arise when the assemblies are subjected to temperature gradients and irradiation induced creep and swelling during the reactor operation. The assembly ducts are made of the ferritic steel HT-9 and remain in the reactor core for four-years at full power condition. Whereas both restraint systems meet the bowing criteria, a properly designed limited free bowing system appears to be more advantageous than a free flowering system from the point of view of enhancing the reactor inherent safety
Draining device in an emergency holding floor for leaked liquid metals
International Nuclear Information System (INIS)
Kawakami, Hiroto.
1980-01-01
Purpose: To automatically discharge leaked liquid metals rapidly to a damping tank in LMFBR type reactors, by the provision of freeze-seal mechanisms having materials capable of being fused due to the heat of the leaked liquid metals to a catching pan for leaked liquid metals. Constitution: A freeze seal pot having a double seal against other liquid by the provision of a freeze seal material fusible by the heat of the leaked metallic sodium and a downwardly opening cup-like inner cylinder closed by a rupturing plate to be ruptured by heat or pressure is provided to the catching pot of a catching tank. A drain pipe connecting by way of a pot to the damping tank is connected to the pan. Accordingly, if the seal member is fused due to the heat of the leaked liquid sodium, the rupturing plate is ruptured due to the decrease in the strength by the heat of the leaked liquid sodium and by the pressure, whereby leaked liquid sodium is automatically discharged into the damping tank rapidly and safely, and the temperature increase in the concrete materials is reduced as compared with the case of cooling the concrete by covering with liners. (Seki, T.)
Progress on PRISM, an inherently safe, economic, and testable advanced liquid metal reactor
International Nuclear Information System (INIS)
Tippets, F.E.; Salerno, L.N.; Boardman, C.E.; Kwant, W.; Murata, R.E.; Snyder, C.R.
1987-01-01
This paper reports progress on the design of PRISM (Power Reactor Inherently Safe Module) under the DOE-sponsored innovative reactor program now in its third year at General Electric. The purpose of this program is to develop a design for an inherently safe, reliable, and marketable liquid metal fast reactor power plant. The PRISM design approach includes the following key elements: Compact sodium-cooled pool-type reactor modules that are sized to enable factory fabrication, economical shipment to inland as well as water-side sites, and economical full-scale prototype testing for design certification; Nuclear safety-related envelope limited to the reactor modules and their service systems; Inherent, passive shutdown heat removal for loss-of-cooling events; Inherent, passive reactivity shutdown for failure-to-scram events
Proofs of cluster formation and transitions in liquid metals and alloys
International Nuclear Information System (INIS)
Filippov, E.S.
1985-01-01
Calculational and experimental proofs are presented indicating to existence of clusters in liquid metals and alloys. Systems of liquid alloys both on the base of ferrous metals and non-ferrous metals (Fe-C, Ni-C, Co-C, Fe-Ni, Ni-Mo, Co-Cr, Co-V as well as In-Sn, Bi-Sn, Si-Ge and others) are studied experimentally. It is shown that the general feature of the systems studied is sensitivity of a volume to change in structure, to replacement fcc structure on bcc or to initiation-dissociation of intermetallic compounds AxBy. It is shown that both in pure liquid metals and in their.alloys there are clusters as ordered aggregate of atoms
Determination of Surface Properties of Liquid Transition Metals
International Nuclear Information System (INIS)
Korkmaz, S. D.
2008-01-01
Certain surface properties of liquid simple metals are reported. Using the expression derived by Gosh and coworkers we investigated the surface entropy of liquid transition metals namely Fe, Co and Ni. We have also computed surface tensions of the metals concerned. The pair distribution functions are calculated from the solution of Ornstein-Zernike integral equation with Rogers-Young closure using the individual version of the electron-ion potential proposed by Fioalhais and coworkers which was originally developed for solid state. The predicted values of surface tension and surface entropy are in very good agreement with available experimental data. The present study results show that the expression derived by Gosh and coworkers is very useful for the surface entropy by using Fioalhais pseudopotential and Rogers-Young closure
Liquid-metal pin-fin pressure drop by correlation in cross flow
International Nuclear Information System (INIS)
Wang, Zhibi; Kuzay, T.M.; Assoufid, L.
1994-01-01
The pin-fin configuration is widely used as a heat transfer enhancement method in high-heat-flux applications. Recently, the pin-fin design with liquid-metal coolant was also applied to synchrotron-radiation beamline devices. This paper investigates the pressure drop in a pin-post design beamline mirror with liquid gallium as the coolant. Because the pin-post configuration is a relatively new concept, information in literature about pin-post mirrors or crystals is rare, and information about the pressure drop in pin-post mirrors with liquid metal as the coolant is even more sparse. Due to this the authors considered the cross flow in cylinder-array geometry, which is very similar to that of the pin-post, to examine the pressure drop correlation with liquid metals over pin fins. The cross flow of fluid with various fluid characteristics or properties through a tube bank was studied so that the results can be scaled to the pin-fin geometry with liquid metal as the coolant. Study lead to two major variables to influence the pressure drop: fluid properties, viscosity and density, and the relative length of the posts. Correlation of the pressure drop between long and short posts and the prediction of the pressure drop of liquid metal in the pin-post mirror and comparison with an existing experiment are addressed
Liquid structure and melting of trivalent metal chlorides
International Nuclear Information System (INIS)
Tosi, M.P.; Pastore, G.; Saboungi, M.L.; Price, D.L.
1991-03-01
Many divalent and trivalent metal ions in stoichiometric liquid mixtures of their halides with alkali halides are fourfold or sixfold coordinated by halogens into relatively long-lived ''complexes''. The stability of these local coordination states and the connectivity that arises between them in the approach to the pure polyvalent metal halide melt determines the character of its short-range and possible intermediate-range order. The available evidence on local coordination in some 140 mixtures has been successfully classified by a structure sorting method based on Pettifor's chemical scale of the elements. Within the general phenomenological frame provided by structure sorting, main attention is given in this work to the liquid structure and melting mechanisms of trivalent metal chlorides. The liquid structure of YCl 3 is first discussed on the basis of neutron diffraction measurements and of calculations within a simple ionic model, and the melting mechanisms of YCl 3 and AlCl 3 , which are structurally isomorphous in the crystalline state, are contrasted. By appeal to macroscopic melting parameters and transport coefficients and to liquid structure data on SbCl 3 , it is proposed that the melting mechanisms of these salts may be classified into three main types in correlation with the character of the chemical bond. (author). 31 refs, 1 fig., 3 tabs
Manipulation of Biomolecule-Modified Liquid-Metal Blobs.
Yu, Yue; Miyako, Eijiro
2017-10-23
Soft and deformable liquid metals (LMs) are building components in various systems related to uncertain and dynamic task environments. Herein we describe the development of a biomolecule-triggered external-manipulation method involving LM conjugates for the construction of future innovative soft robotics operating in physiological environments. Functional soft hybrids composed of a liquid-metal droplet, a thiolated ligand, and proteins were synthesized for the expression of diverse macroscopic commands, such as attachment to cells, binary fusion, and self-propelled movement through molecular recognition and enzymatic reactions. Our technology could be used to create new state-of-the-art soft robots for chemical and biomedical engineering applications. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Liquid-metal dip seal with pneumatic spring
International Nuclear Information System (INIS)
Poindexter, A.M.
1977-01-01
An improved liquid-metal dip seal for sealing the annulus between rotating plugs in the reactor vessel head of a liquid-metal fast-breeder nuclear reactor has two legs of differing widths communicating under a seal blade; the wide leg is also in communication with cover gas of the reactor and the narrow leg is also in communication with an isolated plug annulus above the seal. The annulus contains inert gas which acts as a pneumatic spring. Upon increasing cover gas pressure which depresses the level in the wide leg and greatly increases the level in the narrow leg, the pneumatic spring is compressed, and resists further level changes, thus preventing radioactive cover gas from bubbling through the seal
Ionic liquid-modified metal sulfides/graphene oxide nanocomposites for photoelectric conversion
International Nuclear Information System (INIS)
Zhang, Yu; Zhang, Yù; Pei, Qi; Feng, Ting; Mao, Hui; Zhang, Wei; Wu, Shuyao; Liu, Daliang; Wang, Hongyu; Song, Xi-Ming
2015-01-01
Graphical abstract: - Highlights: • Metal sulfide (CdS, ZnS, Ag 2 S)/GO nanocomposites were prepared by electrostatic adherence. • Ionic liquid was used to link the metal sulfide and GO in the electrostatic adherence process. • The as-prepared samples showed enhanced photocurrent and highly efficient photocatalytic activity under visible light irradiation. - Abstract: Ionic liquid-modified metal sulfides/graphene oxide nanocomposites are prepared via a facile electrostatic adsorption. Ionic liquid (IL) is firstly used as surface modifier and structure-directing agent of metal sulfide (MS) crystallization process, obtaining ionic liquid modified-MS (IL-MS) nanoparticles with positive charges on surface. IL-MS/GO is obtained by electrostatic adherence between positively charged IL-MS and negatively charged graphene oxide (GO). The as-prepared sample shows enhanced photocurrent and highly efficient photocatalytic activity under visible light irradiation, indicating IL-MS/GO nanocomposites greatly promoted the separation of photogenerated electron–hole pairs
Assessment of Electromagnetic Stirrer Agitated Liquid Metal Flows by Dynamic Neutron Radiography
Ščepanskis, Mihails; Sarma, Mārtiņš; Vontobel, Peter; Trtik, Pavel; Thomsen, Knud; Jakovičs, Andris; Beinerts, Toms
2017-04-01
This paper presents qualitative and quantitative characterization of two-phase liquid metal flows agitated by the stirrer on rotating permanent magnets. The stirrer was designed to fulfill various eddy flows, which may have different rates of solid particle entrapment from the liquid surface and their homogenization. The flow was characterized by visualization of the tailored tracer particles by means of dynamic neutron radiography, an experimental method well suited for liquid metal flows due to low opacity of some metals for neutrons. The rather high temporal resolution of the image acquisition (32 Hz image acquisition rate) allows for the quantitative investigation of the flows up to 30 cm/s using neutron particle image velocimetry. In situ visualization of the two-phase liquid metal flow is also demonstrated.
Alternative route to metal halide free ionic liquids
International Nuclear Information System (INIS)
Takao, Koichiro; Ikeda, Yasuhisa
2008-01-01
An alternative synthetic route to metal halide free ionic liquids using trialkyloxonium salt is proposed. Utility of this synthetic route has been demonstrated by preparing 1-ethyl-3-methylimidazolium tetrafluoroborate ionic liquid through the reaction between 1-methylimidazole and triethyloxonium tetra-fluoroborate in anhydrous ether. (author)
Liquid metal current collector applications and material compatibility
International Nuclear Information System (INIS)
Carr, S.L.; Stevens, H.O.
1978-01-01
The objective of this paper has been to summarize briefly the material considerations involved in the development of liquid metal current collectors for homopolar machinery applications. A significant amount of data in this regard has been obtained over the last several years by individual researchers for NaK exposure conditions. However, NaK material compatibility data over the entire time and temperature range of interest is highly desirable. At DTNSRDC, a 300 kW superconducting homopolar motor and generator are under test, both utilizing free surface tongue-and-groove current collectors with NaK as the working fluid. In addition to demonstrating the feasibility of other aspects of machine design, the intention is to use these machines as vehicles for testing of the several liquid metal current collector concepts which are considered worthwhile candidates for incorporation in future full-scale machines. It is likely that the optimal collector approach for a large low speed motor may be quite different from that for a smaller high speed generator, possibly involving the use of different liquid metals
International Nuclear Information System (INIS)
Saito, Yasushi; Suzuki, Tohru; Matsubayashi, Masahito
2000-01-01
In a core melt accident of a fast breeder reactor, a possibility of re-criticality is anticipated in the molten fuel-steel mixture pool. One of the mechanisms to suppress the re-criticality is the boiling of steel in the molten fuel-steel mixture pool because of the negative void reactivity effect. To evaluate the reactivity change due to boiling, it is necessary to know the characteristics of gas-liquid two-phase flow in the molten fuel-steel mixture pool. For this purpose, boiling bubbles in a molten fuel-steel mixture pool were simulated by adiabatic gas bubbles in a liquid metal pool to study the basic characteristics of gas-liquid metal two-phase mixture. Visualization of the two-phase mixture and measurements of liquid phase velocity and void fraction were conducted by using neutron radiography and image processing techniques. From these measurements, the basic characteristics of gas-liquid metal two-phase mixture were clarified. (author)
Liquid metal MHD research and development in Israel
International Nuclear Information System (INIS)
Branover, H.
1993-01-01
The study of liquid metal MHD in Israel commenced in 1973. Initially it was concentrated mainly on laminar flows influenced by external magnetic fields. In 1978 a liquid metal MHD energy conversion program was started. This program was developed at the Center for MHD Studies at Ben-Gurion University in Beer-Sheva, with the participation of specialists from the Technion, the Hebrew University of Jerusalem, Israel Atomic Energy Commission, and others. The program was sponsored initially by the Israel Ministry of Energy and Infrastructure, and later by the Ministry of Industry and Trade. Since 1980, Solmecs, a private commercial company has become a major factor in the development of liquid metal MHD in Israel. From the very beginning the program was based on broad international cooperation. A number of overseas institutions and individuals became participants in the program. Through extensive research and evaluation of a number of concepts of liquid metal MHD power generation systems, It was established that the most promising concept, demanding a relatively short period of development, is the gravitational system using heavy metals (lead, lead alloys) as the magneto-hydrodynamic fluid and steam or gases as thermodynamic fluids. This concept was chosen for further development and industrial application, and the program related to such systems was named the Etgar Program. The main directions of research and development activities have been defined as follows: investigations of physical phenomena, development of universal numerical code for parametric studies, optimization and design of the system, material studies, development of engineering components, building and testing of integrated small-scale Etgar type systems, economic evaluation of the system and comparison with conventional technologies, development of moderate scale industrial demonstration plant. At this time 6 items have been fully implemented and activities on the last item were started. (author)
Interfacial transport phenomena and stability in liquid-metal/water systems: scaling considerations
International Nuclear Information System (INIS)
Abdulla, S.; Liu, X.; Anderson, M.; Bonazza, R.; Corradini, M.; Cho, D.
2001-01-01
One concept being considered for steam generation in innovative nuclear reactor applications, involves water coming into direct contact with a circulating molten metal. The vigorous agitation of the two fluids, the direct liquid-liquid contact and the consequent large interfacial area give rise to very high heat transfer coefficients and rapid steam generation. For an optimum design of such direct contact heat exchange and vaporization systems, detailed knowledge is necessary of the various flow regimes, interfacial transport phenomena, heat transfer and operational stability. In this paper we describe current results from the first year of this research that studies the transport phenomena involved with the injection of water into molten metals (e.g., lead alloys). In particular, this work discusses scaling considerations related to direct contact heat exchange, our experimental plans for investigation and a test plan for the important experimental parameters; i.e., the water and liquid metal mass flow rates, the liquid metal pool temperature and the ambient pressure of the direct contact heat exchanger. Past experimental work and initial scaling results suggest that our experiments can directly represent the proper liquid metal pool temperature and the water subcooling. The experimental variation in water and liquid metal flow rates and system pressure (1-10 bar), although smaller than the current conceptual system designs, is sufficient to verify the expected scale effects to demonstrate the phenomena. (authors)
Nitrogen injection in stagnant liquid metal. Eulerian-Eulerian and VOF calculations by fluent
International Nuclear Information System (INIS)
Pena, A.; Esteban, G.A.
2004-01-01
High power spallation sources are devices that can be very useful in different fields, as medicine, material science, and also in the Accelerator Driven Systems (ADS). This devices use Heavy Liquid Metals (HLM) as the spallation target. Furthermore, HLM are thought to be the coolant of those big energy sources produced by the process. Fast breeder reactors, advanced nuclear reactors, as well as the future designs of fusion reactors, also consider HLM as targets or coolants. Gas injection in liquid metal flows allows the enhancement of this coolant circulation. The difference in densities between the gas and the liquid metal is a big challenge for the multiphase models implemented in the Computational Fluid Dynamics (CFD) codes. Also the changing shape of the bubbles involves extra difficulties in the calculations. A N 2 flow in stagnant Lead-Bismuth eutectic (Pb-Bi), experiment available at Forschungszentrum Rossendorf e.V (FZR) in Germany, was used in one of the work-packages of the ASCHLIM project (EU contract number FIKW-CT-2001-80121). In this paper, calculations made by the UPV/EHU (University of the Basque Country) show measuring data compared with numerical results using the CFD (Computational Fluid Dynamics) code FLUENT and two multiphase models: the Eulerian-Eulerian and the Volume of Fluid (VOF). The interpretation of the experimental resulting velocities was difficult, because some parameters were not known, bubble trajectory and bubble shape, for example, as direct optical methods cannot be used, like it is done with water experiments. (author)
Stretchable Metamaterial Absorber Using Liquid Metal-Filled Polydimethylsiloxane (PDMS
Directory of Open Access Journals (Sweden)
Kyeongseob Kim
2016-04-01
Full Text Available A stretchable metamaterial absorber is proposed in this study. The stretchability was achieved by liquid metal and polydimethylsiloxane (PDMS. To inject liquid metal, microfluidic channels were fabricated using PDMS powers and microfluidic-channel frames, which were built using a three-dimensional printer. A top conductive pattern and ground plane were designed after considering the easy injection of liquid metal. The proposed metamaterial absorber comprises three layers of PDMS substrate. The top layer is for the top conductive pattern, and the bottom layer is for the meandered ground plane. Flat PDMS layers were inserted between the top and bottom PDMS layers. The measured absorptivity of the fabricated absorber was 97.8% at 18.5 GHz, and the absorption frequency increased from 18.5 to 18.65 GHz as the absorber was stretched from its original length (5.2 cm to 6.4 cm.
Liquid metal cooled nuclear reactors
International Nuclear Information System (INIS)
Scott, D.
1981-01-01
An improved method of constructing the diagrid used to support fuel assemblies of liquid metal fast breeder reactors, is described. The functions of fuel assembly support and coolant plenum are performed by discrete components of the diagrid each of which can serve the function of the other in the event of failure of one of the components. (U.K.)
Hvasta, M. G.; Kolemen, E.; Fisher, A. E.; Ji, H.
2018-01-01
Plasma-facing components (PFC’s) made from solid materials may not be able to withstand the large heat and particle fluxes that will be produced within next-generation fusion reactors. To address the shortcomings of solid PFC’s, a variety of liquid-metal (LM) PFC concepts have been proposed. Many of the suggested LM-PFC designs rely on electromagnetic restraint (Lorentz force) to keep free-surface, liquid-metal flows adhered to the interior surfaces of a fusion reactor. However, there is very little, if any, experimental data demonstrating that free-surface, LM-PFC’s can actually be electromagnetically controlled. Therefore, in this study, electrical currents were injected into a free-surface liquid-metal that was flowing through a uniform magnetic field. The resultant Lorentz force generated within the liquid-metal affected the velocity and depth of the flow in a controllable manner that closely matched theoretical predictions. These results show the promise of electromagnetic control for LM-PFC’s and suggest that electromagnetic control could be further developed to adjust liquid-metal nozzle output, prevent splashing within a tokamak, and alter heat transfer properties for a wide-range of liquid-metal systems.
Investigation of Liquid Metal Embrittlement of Materials for use in Fusion Reactors
Kennedy, Daniel; Jaworski, Michael
2014-10-01
Liquid metals can provide a continually replenished material for the first wall and extraction blankets of fusion reactors. However, research has shown that solid metal surfaces will experience embrittlement when exposed to liquid metals under stress. Therefore, it is important to understand the changes in structural strength of the solid metal materials and test different surface treatments that can limit embrittlement. Research was conducted to design and build an apparatus for exposing solid metal samples to liquid metal under high stress and temperature. The apparatus design, results of tensile testing, and surface imaging of fractured samples will be presented. This work was supported in part by the U.S. Department of Energy, Office of Science, Office of Workforce Development for Teachers and Scientists (WDTS) under the Science Undergraduate Laboratory Internships Program (SULI).
A low cost liquid metal reactor design
International Nuclear Information System (INIS)
Arnold, W.H.; Anderson, C.A.; Mangus, J.D.
1984-01-01
A new, compact Liquid Metal Reactor (LMR) plant arrangement designed by Westinghouse, featuring factory-fabricated modules and an integrated fuel cycle facility, has made it possible to project a commercially competitive LMR plant for the near future. This innovative liquid metal-cooled plant design will allow a combination of capital, fuel, operation and maintenance costs that could be lower than today's fossil-fueled or light water reactor plant costs, and incorporate features which enhance public safety even beyond current high standards. Following early core loadings, the plant feeds only on depleted uranium. No shipment of fuel is required. And the plant can be tailored to produce enough plutonium to meet its need or to provide fuel for other nuclear plants
Stability analysis for single-phase liquid metal rectangular natural circulation loops
International Nuclear Information System (INIS)
Lu, Daogang; Zhang, Xun; Guo, Chao
2014-01-01
Highlights: • The stability for asymmetric liquid metal natural circulation loops is analyzed. • The Na and NaK loops have higher critical Reynolds number than Pb and LBE loops. • Decreasing the ratio of height to width of loop can increase loop stability. • The length of heater would not affect the loop stability obviously. • Adding the length or heat transfer coefficient of cooler can increase loop stability. - Abstract: Natural circulation systems are preferred in some advanced nuclear power plants as they can simplify the designs and improve the inherent safety. The stability and steady-state characteristics of natural circulation are important for the applications of natural circulation loops (NCLs). A linear stability analysis method was used to study the stability behavior of liquid metal NCLs. The influences of the types of working fluids and loop geometry parameters on the stability of NCLs were evaluated. The liquid sodium (Na) loop and sodium–potassium alloy (NaK) loop would be more stable than lead bismuth eutectics (LBE) loop. The pressure drop could stabilize the loop behavior and also lead an increase of operating temperature for the loop. The NCL with a lower aspect ratio (ratio of vertical center distance between the heating and cooling section to the horizontal length of loop) is supposed to be more stable. It was found that the length of heating section would not have an obvious effect on the stability of NCL. However, the loop behavior could be stabilized by adding the length or heat transfer coefficient of the cooling section
Blanket of a hybrid thermonuclear reactor with liquid- metal cooling
International Nuclear Information System (INIS)
Terent'ev, I.K.; Fedorovich, E.P.; Paramonov, P.M.; Zhokhov, K.A.
1982-01-01
Blanket design of a hybrid thermopuclear reactor with a liquid metal coolant is described. To decrease MHD-resistance for uranium zone fuel elements a cylindrical shape is suggested and movement of liquid-metal coolant in fuel element packets is presumed to be in perpendicular to the magnetic field and fuel element axes direction. The first wall is cooled by water, blanket-by lithium-lead alloy
Liquid metal fast reactor transient design
International Nuclear Information System (INIS)
Horak, C.; Purvis, E. III
2000-01-01
An examination has been made of how the currently available computing capabilities could be used to reduce Liquid Metal Fast Reactor design, manufacturing, and construction cost. While the examination focused on computer analyses some other promising means to reduce costs were also examined. (author)
Quasiparticles and Fermi liquid behaviour in an organic metal
Kiss, T.; Chainani, A.; Yamamoto, H.M.; Miyazaki, T.; Akimoto, T.; Shimojima, T.; Ishizaka, K.; Watanabe, S.; Chen, C.-T.; Fukaya, A.; Kato, R.; Shin, S.
2012-01-01
Many organic metals display exotic properties such as superconductivity, spin-charge separation and so on and have been described as quasi-one-dimensional Luttinger liquids. However, a genuine Fermi liquid behaviour with quasiparticles and Fermi surfaces have not been reported to date for any organic metal. Here, we report the experimental Fermi surface and band structure of an organic metal (BEDT-TTF)3Br(pBIB) obtained using angle-resolved photoelectron spectroscopy, and show its consistency with first-principles band structure calculations. Our results reveal a quasiparticle renormalization at low energy scales (effective mass m*=1.9 me) and ω2 dependence of the imaginary part of the self energy, limited by a kink at ~50 meV arising from coupling to molecular vibrations. The study unambiguously proves that (BEDT-TTF)3Br(pBIB) is a quasi-2D organic Fermi liquid with a Fermi surface consistent with Shubnikov-de Haas results. PMID:23011143
Experimental study of liquid-metal target designs of accelerating-controlled systems
International Nuclear Information System (INIS)
Iarmonov, Mikhail; Makhov, Kirill; Novozhilova, Olga; Meluzov, A.G.; Beznosov, A.V.
2011-01-01
Models of a liquid-metal target of an accelerator-controlled system have been experimentally studied at the Nizhny Novgorod State Technical University to develop an optimal design of the flow part of the target. The main explored variants of liquid-metal targets are: Design with a diaphragm (firm-and-impervious plug) mounted on the pipe tap of particle transport from the accelerator cavity to the working cavity of the liquid-metal target. Design without a diaphragm on the pipe tab of particle transport from the accelerator. The study was carried out in a high-temperature liquid-metal test bench under the conditions close to full-scale ones: the temperature of the eutectic lead-bismuth alloy was 260degC - 400degC, the coolant mass flow was 5-80 t/h, and the rarefaction in the gas cavity was 10 5 Pa, the coefficient of geometric similarity equal to 1. The experimental studies of hydrodynamic characteristics of flow parts in the designs of targets under full-scale conditions indicated high efficiency of a target in triggering, operating, and deactivating modes. Research and technology instructions for designs of the flow part of the liquid-metal target, the target design as a whole, and the target circuit of accelerator-controlled systems were formulated as a result of the studies. (author)
Linking structure to fragility in bulk metallic glass-forming liquids
International Nuclear Information System (INIS)
Wei, Shuai; Stolpe, Moritz; Gross, Oliver; Gallino, Isabella; Hembree, William; Busch, Ralf; Evenson, Zach; Bednarcik, Jozef; Kruzic, Jamie J.
2015-01-01
Using in-situ synchrotron X-ray scattering, we show that the structural evolution of various bulk metallic glass-forming liquids can be quantitatively connected to their viscosity behavior in the supercooled liquid near T g . The structural signature of fragility is identified as the temperature dependence of local dilatation on distinct key atomic length scales. A more fragile behavior results from a more pronounced thermally induced dilatation of the structure on a length scale of about 3 to 4 atomic diameters, coupled with shallower temperature dependence of structural changes in the nearest neighbor environment. These findings shed light on the structural origin of viscous slowdown during undercooling of bulk metallic glass-forming liquids and demonstrate the promise of predicting the properties of bulk metallic glasses from the atomic scale structure
Linking structure to fragility in bulk metallic glass-forming liquids
Energy Technology Data Exchange (ETDEWEB)
Wei, Shuai, E-mail: shuai.wei@asu.edu, E-mail: m.stolpe@mx.uni-saarland.de [Department of Materials Science and Engineering, Saarland University, Campus C63, 66123 Saarbrücken (Germany); Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287 (United States); Stolpe, Moritz, E-mail: shuai.wei@asu.edu, E-mail: m.stolpe@mx.uni-saarland.de; Gross, Oliver; Gallino, Isabella; Hembree, William; Busch, Ralf [Department of Materials Science and Engineering, Saarland University, Campus C63, 66123 Saarbrücken (Germany); Evenson, Zach [Department of Materials Science and Engineering, Saarland University, Campus C63, 66123 Saarbrücken (Germany); Institut für Materialphysik im Weltraum, Deutsches Zentrum für Luft- und Raumfahrt (DLR), 51170 Köln (Germany); Bednarcik, Jozef [Deutsches Elektronen-Synchrotron DESY, Notkestrasse 85, D-22603 Hamburg (Germany); Kruzic, Jamie J. [Material Science, School of Mechanical, Industrial, and Manufacturing Engineering, Oregon State University, Corvallis, Oregon 97331 (United States)
2015-05-04
Using in-situ synchrotron X-ray scattering, we show that the structural evolution of various bulk metallic glass-forming liquids can be quantitatively connected to their viscosity behavior in the supercooled liquid near T{sub g}. The structural signature of fragility is identified as the temperature dependence of local dilatation on distinct key atomic length scales. A more fragile behavior results from a more pronounced thermally induced dilatation of the structure on a length scale of about 3 to 4 atomic diameters, coupled with shallower temperature dependence of structural changes in the nearest neighbor environment. These findings shed light on the structural origin of viscous slowdown during undercooling of bulk metallic glass-forming liquids and demonstrate the promise of predicting the properties of bulk metallic glasses from the atomic scale structure.
Metal-deactivating additives for liquid fuels
Energy Technology Data Exchange (ETDEWEB)
Boneva, M.I. [Institute of Organic Chemistry, Sofia (Bulgaria); Ivanov, S.K.; Kalitchin, Z.D. [SciBulCom, Ltd., Sofia (Bulgaria); Tanielyan, S.K. [Seton Hall Univ., South Orange, NJ (United States); Terebenina, A.; Todorova, O.I. [Institute of Inorganic Chemistry, Sofia (Bulgaria)
1995-05-01
The metal-deactivating and the antioxidant properties of 1-phenyl-3-methylpyrazolone-5 derivatives have been investigated both in the model reaction of low temperature oxidation of ethylbenzene and in gasoline oxidation. The study of the ability of these derivatives to reduce the catalytic effect of copper naphthenate demonstrates that they are promising as metal deactivating additives for light fuels. Some of the pyrazolone compounds appear to be of special interest for the long-term storage of liquid fuels due to their action as multifunctional inhibitors.
Measurement of Liquid-Metal Two-Phase Flow with a Dynamic Neutron Radiography
International Nuclear Information System (INIS)
Cha, J. E.; Lim, I. C.; Kim, H. R.; Kim, C. M.; Nam, H. Y.; Saito, Y.
2005-01-01
The dynamic neutron radiography(DNR) has complementary characteristics to X-ray radiography and is suitable to visualization and measurement of a multi-phase flow research in a metallic duct and liquid metal flow. The flow-field information of liquid metal system is very important for the safety analysis of fast breeder reactor and the design of the spallation target of accelerator driven system. A DNR technique was applied to visualize the flow field in the gas-liquid metal two-phase flow with the HANARO-beam facility. The lead bismuth eutectic and the nitrogen gas were used to construct the two-phase flow field in the natural circulation U-channel. The two-phase flow images in the riser were taken at various combinations of the liquid flow and gas flow with high frame-rate neutron radiography at 1000 fps
Development of oxygen sensors for use in liquid metal
International Nuclear Information System (INIS)
Van Nieuwenhove, Rudi; Ejenstam, Jesper; Szakalos, Peter
2015-01-01
For generation IV reactor concepts, based on liquid metal cooling, there is a need for robust oxygen sensors which can be used in the core of the reactor since corrosion can only be kept sufficiently low by controlling the dissolved oxygen content in the liquid metal. A robust, ceramic membrane type sensor has been developed at IFE/Halden (Norway) and tested in an autoclave system at KTH (Sweden). The sensor has been tested in lead-bismuth at 550 deg. C and performed well. (authors)
Development of oxygen sensors for use in liquid metal
Energy Technology Data Exchange (ETDEWEB)
Van Nieuwenhove, Rudi [Institutt for Energiteknikk, Halden, (Norway); Ejenstam, Jesper; Szakalos, Peter [KTH Royal Institute of Technology, Division of Surface and Corrosion Science, Stockholm, (Sweden)
2015-07-01
For generation IV reactor concepts, based on liquid metal cooling, there is a need for robust oxygen sensors which can be used in the core of the reactor since corrosion can only be kept sufficiently low by controlling the dissolved oxygen content in the liquid metal. A robust, ceramic membrane type sensor has been developed at IFE/Halden (Norway) and tested in an autoclave system at KTH (Sweden). The sensor has been tested in lead-bismuth at 550 deg. C and performed well. (authors)
3-D printing of liquid metals for stretchable and flexible conductors
Trlica, Chris; Parekh, Dishit Paresh; Panich, Lazar; Ladd, Collin; Dickey, Michael D.
2014-06-01
3-D printing is an emerging technology that has been used primarily on small scales for rapid prototyping, but which could also herald a wider movement towards decentralized, highly customizable manufacturing. Polymers are the most common materials to be 3-D printed today, but there is great demand for a way to easily print metals. Existing techniques for 3-D printing metals tend to be expensive and energy-intensive, and usually require high temperatures or pressures, making them incompatible with polymers, organics, soft materials, and biological materials. Here, we describe room temperature liquid metals as complements to polymers for 3-D printing applications. These metals enable the fabrication of soft, flexible, and stretchable devices. We survey potential room temperature liquid metal candidates and describe the benefits of gallium and its alloys for these purposes. We demonstrate the direct printing of a liquid gallium alloy in both 2-D and 3-D and highlight the structures and shapes that can be fabricated using these processes.
Oscillatory Convection in Rotating Liquid Metals
Bertin, Vincent; Grannan, Alex; Aurnou, Jonathan
2016-11-01
We have performed laboratory experiments in a aspect ratio Γ = 2 cylinder using liquid gallium (Pr = 0 . 023) as the working fluid. The Ekman number varies from E = 4 ×10-5 to 4 ×10-6 and the Rayleigh number varies from Ra = 3 ×105 to 2 ×107 . Using heat transfer and temperature measurements within the fluid, we characterize the different styles of low Pr rotating convective flow. The convection threshold is first overcome in the form of a container scale inertial oscillatory mode. At stronger forcing, wall-localized modes develop, coexisting with the inertial oscillatory modes in the bulk. When the strength of the buoyancy increases further, the bulk flow becomes turbulent while the wall modes remain. Our results imply that rotating convective flows in liquid metals do not develop in the form of quasi-steady columns, as in Pr = 1 planetary and stellar dynamo models, but in the form of oscillatory motions. Therefore, convection driven dynamo action in low Pr fluids can differ substantively than that occurring in typical Pr = 1 numerical models. Our results also suggest that low wavenumber, wall modes may be dynamically and observationally important in liquid metal dynamo systems. We thank the NSF Geophysics Program for support of this project.
Isolation of Metals from Liquid Wastes: Reactive in Turbulent Thermal Reactors
International Nuclear Information System (INIS)
Wendt, Jost O.L.
2001-01-01
A Generic Technology for treatment of DOE Metal-Bearing Liquid Waste The DOE metal-bearing liquid waste inventory is large and diverse, both with respect to the metals (heavy metals, transuranics, radionuclides) themselves, and the nature of the other species (annions, organics, etc.) present. Separation and concentration of metals is of interest from the standpoint of reducing the volume of waste that will require special treatment or isolation, as well as, potentially, from the standpoint of returning some materials to commerce by recycling. The variety of metal-bearing liquid waste in the DOE complex is so great that it is unlikely that any one process (or class of processes) will be suitable for all material. However, processes capable of dealing with a wide variety of wastes will have major advantages in terms of process development, capital, and operating costs, as well as in environmental and safety permitting. Moreover, to the extent that a process operates well with a variety of metal-bearing liquid feedwastes, its performance is likely to be relatively robust with respect to the inevitable composition variations in each waste feed. One such class of processes involves high-temperature treatment of atomized liquid waste to promote reactive capture of volatile metallic species on collectible particulate substrates injected downstream of a flame zone. Compared to low-temperature processes that remove metals from the original liquid phase by extraction, precipitation, ion exchange, etc., some of the attractive features of high-temperature reactive scavenging are: The organic constituents of some metal-bearing liquid wastes (in particular, some low-level mixed wastes) must be treated thermally in order to meet the requirements of the Resource Conservation and Recovery Act (RCRA) and Toxic Substances Control Act (TSCA), and the laws of various states. No species need be added to an already complex liquid system. This is especially important in light of the fact
Liquid lens: advances in adaptive optics
Casey, Shawn Patrick
2010-12-01
'Liquid lens' technologies promise significant advancements in machine vision and optical communications systems. Adaptations for machine vision, human vision correction, and optical communications are used to exemplify the versatile nature of this technology. Utilization of liquid lens elements allows the cost effective implementation of optical velocity measurement. The project consists of a custom image processor, camera, and interface. The images are passed into customized pattern recognition and optical character recognition algorithms. A single camera would be used for both speed detection and object recognition.
Temperature-dependent thermo-elastic properties of s-, p- and d-block liquid metals
International Nuclear Information System (INIS)
Singh, R.N.; Arafin, S.; George, A.K.
2007-01-01
Thermodynamic relations involving experimentally known physical quantities are used to determine the ratio of specific heats, γ, for s-block (Na, K, Rb, Cs, Mg), d-block (Fe, Co, Ni, Cu, Ag, Au, Zn, Cd, Hg,) and p-block (Al, Ga, In, Tl, Sn, Pb, Sb, Bi, Se, Te) liquid metals. γ is further utilized to determine reliable values for the isothermal compressibility (κ T ) and the specific heat at constant volume (C V ) for these liquid metals near and above the melting temperatures. These data are of considerable significance for various thermo-physical analysis of liquid metals. We have also evaluated the Grueneisen function and its temperature dependence to establish the correlation between the thermal expansion and the elastic response to thermally induced stress. The values of acoustic impedance for liquid metals are evaluated and its physical significance is discussed for the transmission of elastic waves across metallic interfaces
The solubility of metals in Pb-17Li liquid alloy
International Nuclear Information System (INIS)
Borgstedt, H.U.; Feuerstein, H.
1992-01-01
The solubility data of iron in the eutectic alloy Pb-17Li which were evaluated from corrosion tests in a turbulent flow of the molten alloy are discussed in the frame of solubilities of the transition metals in liquid lead. It is shown that the solubility of iron in the alloy is close to that in lead. This is also the fact for several other alloying elements of steels. A comparison of all known data shows that they are in agreement with generally shown trends for the solubility of the transition metals in low melting metals. These trends indicate comparably high solubilities of nickel and manganese in the liquid metals, lower saturation concentration of vanadium, chromium, iron, and cobalt, and extremely low solubility of molybdenum. (orig.)
Normal spectral emissivity of selected liquid metals and improved thermophysical properties
International Nuclear Information System (INIS)
Pottlacher, G.; Seifter, A.
2001-01-01
Full Text: Emissivity measurements on several liquid metals up to temperatures of 6000 K have been successfully established by linking a laser polarimetry technique to our well-known method for performing high speed measurements of thermophysical properties on liquid metal samples during microsecond pulse-heating experiments. Thermophysical properties measured with our experimental setup include temperature dependencies of heat capacity, enthalpy, electrical resistivity, density, thermal diffusivity and thermal conductivity up to the end of the stable liquid phase. During grant P12775-PHY additionally to the above listened properties the measurement of the change of the polarization of laser light reflected from the surface during pulse heating was enabled and thus now the temperature dependence of spectral emissivity at 684.5 nm by methods of ellipsometry is derived also. Several liquid metals and alloys have been investigated within this grant and a review of the data obtained will be given here. (author)
Liquid metal pump for nuclear reactors
International Nuclear Information System (INIS)
Allen, H.G.; Maloney, J.R.
1975-01-01
A pump for use in pumping high temperature liquids at high pressures, particularly liquid metals used to cool nuclear reactors is described. It is of the type in which the rotor is submerged in a sump but is fed by an inlet duct which bypasses the sump. A chamber, kept full of fluid, surrounds the pump casing into which fluid is bled from the pump discharge and from which fluid is fed to the rotor bearings and hence to the sump. This equalizes pressure inside and outside the pump casing and reduces or eliminates the thermal shock to the bearings and sump tank
Two cylinder permanent magnet stirrer for liquid metals
Bojarevičs, A.; Baranovskis, R.; Kaldre, I.; Milgrāvis, M.; Beinerts, T.
2017-07-01
To achieve a uniform liquid metal composition and temperature distribution, stirring is often necessary for industrial processes. Here, a novel permanent magnet system for liquid melt stirring is proposed. It promises very low energy consumption and options for multiple different flow types compared to traditional travelling magnetic field inductors or mechanical stirrers. The proposed system has a simple design: it consists of two rotating permanent magnet cylinders, which are magnetized transversely to the axis of the cylinders. The experimental device was developed and tested under various regimes using GaInSn alloy in a cylindrical crucible. Aluminum stirring by permanent magnets in laboratory scale is tested, and stirring impact on directional solidification of metallic alloys is experimentally investigated.
An overview of FFTF [Fast Flux Test Facility] contributions to Liquid Metal Reactor Safety
International Nuclear Information System (INIS)
Waltar, A.E.; Padilla, A. Jr.
1990-11-01
The Fast Flux Test Facility has provided a very useful framework for testing the advances in Liquid Metal Reactor Safety Technology. During the licensing phase, the switch from a nonmechanistic bounding technique to the mechanistic approach was developed and implemented. During the operational phase, the consideration of new tests and core configurations led to use of the anticipated-transients-without-scram approach for beyond design basis events and the move towards passive safety. The future role of the Fast Flux Test Facility may involve additional passive safety and waste transmutation tests. 26 refs
Review of liquid metal heat pipe work at Los Alamos
International Nuclear Information System (INIS)
Reid, R.S.; Merrigan, M.A.; Sena, J.T.
1990-01-01
A survey of space-power related liquid metal heat pipe work at Los Alamos National Laboratory is presented. Heat pipe development at Los Alamos has been on-going since 1963. Heat pipes were initially developed for thermionic nuclear-electrical power production in space. Since then Los Alamos has developed liquid metal heat pipes for numerous applications related to high temperature systems in both the space and terrestrial environments. Some of these applications include thermionic electrical generators, thermoelectric energy conversion (both in-core and direct radiation), thermal energy storage, hypersonic vehicle leading edge cooling, and heat pipe vapor laser cells. Some of the work performed at Los Alamos has been documented in internal reports that are often little-known. A representative description and summary of progress in space-related liquid metal heat pipe technology is provided followed by a reference section citing sources where these works may be found. 53 refs
A large economic liquid metal reactor for United States utilities
International Nuclear Information System (INIS)
Rodwell, E.
1985-01-01
The United States has demonstrated its ability to build and operate small and medium sized liquid metal reactors and continues to operate the Experimental Breeder Reactor II and the Fast Flux Test Facility to demonstrate long life fuel designs. Similar-sized liquid metal reactors in Europe have been followed by a step-up to the 1200 MWe capacity of the Superphenix plant. To permit the United States to make a similar step-up in capacity, a 1320 MWe liquid metal reactor plant has been designed with the main emphasis on minimizing the specific capital cost in order to be competitive with light water reactor plant and fossil plant alternatives. The design is based on a four parallel heat transport loops arrangement and complies with current regulatory requirements. The primary heat transport loops are now being integrated into the reactor vessel to achieve further reduction in the capital cost
Protected Lithium-Metal Anodes in Batteries: From Liquid to Solid.
Yang, Chunpeng; Fu, Kun; Zhang, Ying; Hitz, Emily; Hu, Liangbing
2017-09-01
High-energy lithium-metal batteries are among the most promising candidates for next-generation energy storage systems. With a high specific capacity and a low reduction potential, the Li-metal anode has attracted extensive interest for decades. Dendritic Li formation, uncontrolled interfacial reactions, and huge volume effect are major hurdles to the commercial application of Li-metal anodes. Recent studies have shown that the performance and safety of Li-metal anodes can be significantly improved via organic electrolyte modification, Li-metal interface protection, Li-electrode framework design, separator coating, and so on. Superior to the liquid electrolytes, solid-state electrolytes are considered able to inhibit problematic Li dendrites and build safe solid Li-metal batteries. Inspired by the bright prospects of solid Li-metal batteries, increasing efforts have been devoted to overcoming the obstacles of solid Li-metal batteries, such as low ionic conductivity of the electrolyte and Li-electrolyte interfacial problems. Here, the approaches to protect Li-metal anodes from liquid batteries to solid-state batteries are outlined and analyzed in detail. Perspectives regarding the strategies for developing Li-metal anodes are discussed to facilitate the practical application of Li-metal batteries. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Thermotropic liquid crystals recent advances
Ramamoorthy, Ayyalusamy
2007-01-01
This book covers developments in the field of thermotropic liquid crystals and their functional importance. It also presents advances related to different sub-areas pertinent to this interdisciplinary area of research. This text brings together research from synthetic scientists and spectroscopists and attempts to bridge the gaps between these areas. New physical techniques that are powerful in characterizing these materials are discussed.
On the self-diffusion process in liquid metals and alloys by the radioactive tracer method
International Nuclear Information System (INIS)
Ganovici, L.
1978-01-01
A theoretical and experimental study of self-diffusion process in liquid metals and alloys is presented. There are only a few pure metals for which diffusion coefficients in a liquid state are known. The thesis aims at increasing the number of liquid metals for which diffusion coefficients are available, by determining these values for liquids: Cd, Tl, Sb and Te. The self-diffusion coefficients of Te in some tellurium based liquid alloys such as Tl 2 Te, PbTe and Bi 90 Te 10 were also determined. Self-diffusion coefficients have been measured using two radioactive tracer methods: a) the capillary-reservoir method; b) the semi-infinite capillary method. The self-diffusion coefficients were derived from the measured radioactive concentration profile, using the solutions of Fick's second law for appropriate initial and limit conditions. The temperature dependence study of self-diffusion coefficients in liquids Cd, Tl, Sb and Te, was used to check some theoretical models on the diffusion mechanism in metallic melts. The experimental diffusion data interpreted in terms of the Arrhenius type temperature dependence, was used to propose two simple empiric relations for determining self diffusion coefficients of group I liquid metals and for liquid semi-metals. It was established a marked decrease of self-diffusion coefficients of liquid Te close to the solidification temperature. The diffusivity of Te in liquid Tl 2 Te points to an important decrease close to the solidification temperature. A simplified model was proposed for the diffusion structural unit in this alloy and the hard sphere model for liquid metals was checked by comparing the theoretical and experimental self-diffusion coefficients. (author)
Advanced breeder cycle uses metallic fuel
International Nuclear Information System (INIS)
Chang, Y.I.
1991-01-01
Scientists from Argonne National Laboratory have been developing a concept called the Integral fast Reactor (IFR). This fast breeder reactor could effectively increase Uranium resources a hundred fold making nuclear power essentially an inexhaustible energy source. The IFR is outlined. In the IFR, the inherent properties of liquid metal cooling are combined with a new metallic fuel which is allowed to swell and gives an improved burnup level and a radically different refining process to allow breakthroughs in passive safety, fuel cycle economics and waste management. (author)
Report on generation IV technical working group 3 : liquid metal reactors
International Nuclear Information System (INIS)
Lineberry, M. J.; Rosen, S. L.; Sagayama, Y.
2002-01-01
This paper reports on the first round of R and D roadmap activities of the Generation IV (Gen IV) Technical Working Group (TWG) 3, on liquid metal-cooled reactors. Liquid metal coolants give rise to fast spectrum systems, and thus the reactor systems considered in this TWG are all fast reactors. Gas-cooled fast reactors are considered in the context of TWG 2. As is noted in other Gen IV papers, this first round activity is termed ''screening for potential'', and includes collecting the most complete set of liquid metal reactor/fuel cycle system concepts possible and evaluating the concepts against the Gen IV principles and goals. Those concepts or concept groups that meet the Gen IV principles and which are deemed to have reasonable potential to meet the Gen IV goals will pass to the next round of evaluation. Although we sometimes use the terms ''reactor'' or ''reactor system'' by themselves, the scope of the investigation by TWG 3 includes not only the reactor systems, but very importantly the closed fuel recycle system inevitably required by fast reactors. The response to the DOE Request for Information (RFI) on liquid metal reactor/fuel cycle systems from principal investigators, laboratories, corporations, and other institutions, was robust and gratifying. Thirty three liquid metal concept descriptions, from eight different countries, were ultimately received. The variation in the scope, depth, and completeness of the responses created a significant challenge for the group, but the TWG made a very significant effort not to screen out concepts early in the process
Liquid metal blanket module testing and design for ITER/TIBER II
International Nuclear Information System (INIS)
Mattas, R.F.; Cha, Y.; Finn, P.A.; Majumdar, S.; Picologlou, B.; Stevens, H.; Turner, L.
1988-05-01
A major goal for ITER is the testing of nuclear components to demonstrate the integrated performance of the most attractive concepts that can lead to a commercial fusion reactor. As part of the ITER/TIBER II study, the test program and design of test models were examined for a number of blanket concepts. The work at Argonne National Laboratory focused on self-cooled liquid metal blankets. A test program for liquid metal blankets was developed based upon the ITER/TIBER II operating schedule and the specific data needs to resolve the key issues for liquid metals. Testing can begin early in reactor operation with liquid metal MHD tests to confirm predictive capability. Combined heat transfer/MHD tests can be performed during initial plasma operation. After acceptable heat transfer performance is verified, tests to determine the integrated high temperature performance in a neutron environment can begin. During the high availability phase operation, long term performance and reliability tests will be performed. It is envisioned that a companion test program will be conducted outside ITER to determine behavior under severe accident conditions and upper performance limits. A detailed design of a liquid metal test module and auxiliary equipment was also developed. The module followed the design of the TPSS blanket. Detailed analysis of the heat transfer and tritium systems were performed, and the overall layout of the systems was determined. In general, the blanket module appears to be capable of addressing most of the testing needs. 8 refs., 27 figs., 11 tabs
Directory of Open Access Journals (Sweden)
Fazli Wahid
2017-11-01
Full Text Available Recently, the rapid emergence of antibiotic-resistant pathogens has caused a serious health problem. Scientists respond to the threat by developing new antimicrobial materials to prevent or control infections caused by these pathogens. Polymer-based nanocomposite hydrogels are versatile materials as an alternative to conventional antimicrobial agents. Cross-linking of polymeric materials by metal ions or the combination of polymeric hydrogels with nanoparticles (metals and metal oxide is a simple and effective approach for obtaining a multicomponent system with diverse functionalities. Several metals and metal oxides such as silver (Ag, gold (Au, zinc oxide (ZnO, copper oxide (CuO, titanium dioxide (TiO2 and magnesium oxide (MgO have been loaded into hydrogels for antimicrobial applications. The incorporation of metals and metal oxide nanoparticles into hydrogels not only enhances the antimicrobial activity of hydrogels, but also improve their mechanical characteristics. Herein, we summarize recent advances in hydrogels containing metal ions, metals and metal oxide nanoparticles with potential antimicrobial properties.
Metal fires and their implications for advanced reactors. Part 3: Experimental and modeling results
International Nuclear Information System (INIS)
Nowlen, Steven Patrick; Figueroa, Victor G.; Olivier, Tara Jean; Hewson, John C.; Blanchat, Thomas K.
2010-01-01
This report details the primary results of the Laboratory Directed Research and Development project (LDRD 08-0857) Metal Fires and Their Implications for Advance Reactors. Advanced reactors may employ liquid metal coolants, typically sodium, because of their many desirable qualities. This project addressed some of the significant challenges associated with the use of liquid metal coolants, primary among these being the extremely rapid oxidation (combustion) that occurs at the high operating temperatures in reactors. The project has identified a number of areas for which gaps existed in knowledge pertinent to reactor safety analyses. Experimental and analysis capabilities were developed in these areas to varying degrees. In conjunction with team participation in a DOE gap analysis panel, focus was on the oxidation of spilled sodium on thermally massive surfaces. These are spills onto surfaces that substantially cool the sodium during the oxidation process, and they are relevant because standard risk mitigation procedures seek to move spill environments into this regime through rapid draining of spilled sodium. While the spilled sodium is not quenched, the burning mode is different in that there is a transition to a smoldering mode that has not been comprehensively described previously. Prior work has described spilled sodium as a pool fire, but there is a crucial, experimentally-observed transition to a smoldering mode of oxidation. A series of experimental measurements have comprehensively described the thermal evolution of this type of sodium fire for the first time. A new physics-based model has been developed that also predicts the thermal evolution of this type of sodium fire for the first time. The model introduces smoldering oxidation through porous oxide layers to go beyond traditional pool fire analyses that have been carried out previously in order to predict experimentally observed trends. Combined, these developments add significantly to the safety
Designing Kitaev Spin Liquids in Metal-Organic Frameworks
Yamada, Masahiko G.; Fujita, Hiroyuki; Oshikawa, Masaki
2017-08-01
Kitaev's honeycomb lattice spin model is a remarkable exactly solvable model, which has a particular type of spin liquid (Kitaev spin liquid) as the ground state. Although its possible realization in iridates and α -RuCl3 has been vigorously discussed recently, these materials have substantial non-Kitaev direct exchange interactions and do not have a spin liquid ground state. We propose metal-organic frameworks (MOFs) with Ru3 + (or Os3 + ), forming the honeycomb lattice as promising candidates for a more ideal realization of Kitaev-type spin models, where the direct exchange interaction is strongly suppressed. The great flexibility of MOFs allows generalization to other three-dimensional lattices for the potential realization of a variety of spin liquids, such as a Weyl spin liquid.
[Applications of atomic emission spectrum from liquid electrode discharge to metal ion detection].
Mao, Xiu-Ling; Wu, Jian; Ying, Yi-Bin
2010-02-01
The fast and precise detection of metal ion is an important research project concerning studies in diverse academic fields and different kinds of detecting technologies. In the present paper, the authors review the research on atomic emission spectrum based on liquid electrode discharge and its applications in the detection of metal ion. In the first part of this paper the principles and characteristics of the methods based on electrochemistry and spectroscopy were introduced. The methods of ion-selective electrode (ISE), anodic stripping voltammetry, atomic emission spectrum and atomic absorption spectrum were included in this part and discussed comparatively. Then the principles and characteristics of liquid electrode spectra for metal ion detection were introduced. The mechanism of the plasma production and the characteristics of the plasma spectrum as well as its advantages compared with other methods were discussed. Secondly, the authors divided the discharge system into two types and named them single liquid-electrode discharge and double-liquid electrode respectively, according to the number of the liquid electrode and the configuration of the discharge system, and the development as well as the present research status of each type was illustrated. Then the characteristics and configurations of the discharge systems including ECGD, SCGD, LS-APGD and capillary discharge were discussed in detail as examples of the two types. By taking advantage of the technology of atomic emission spectrum based on liquid electrode discharge, the detecting limit of heavy metals such as copper, mercury and argent as well as active metal ions including sodium, potass and magnesium can achieve microg x L(-1). Finally, the advantages and problems of the liquid-electrode discharge applied in detection of metal ion were discussed. And the applications of the atomic emission spectrum based on liquid electrode discharge were prospected.
Structural effects on fusion reactor blankets due to liquid metals in magnetic fields
International Nuclear Information System (INIS)
Lehner, J.R.; Reich, M.; Powell, J.R.
1976-01-01
The transient stress distribution caused in the blanket structure when the plasma current suddenly switches off in a time short compared to the L/R decay time of the liquid metal blanket was studied. Poloidal field of the plasma will induce a current to flow in the liquid metal and blanket walls. Since the resistance of the liquid lithium will be much less than that of the metal walls, the current can be considered as flowing around the blanket near the cross section perimeter, but in the lithium
Thermal expansion of metals over the entire liquid range
International Nuclear Information System (INIS)
Shaner, J.W.
1977-01-01
This paper reviews the current state of the art for measuring liquid metal densities. Conventional high precision techniques for use below 2000K as well as new techniques for more extreme temperatures are addressed. Pertinent data, which have appeared since the last critical reviews, for elemental metals are discussed
International Nuclear Information System (INIS)
Zuo Juanli; Tian Wenxi; Qiu Suizheng; Chen Ronghua; Su Guanghui
2011-01-01
The gas-lift pump in liquid metal cooling fast reactor (LMFR) is an innovational conceptual design to enhance the natural circulation ability of reactor core. The two-phase flow character of gas-liquid metal makes significant improvement of the natural circulation capacity and reactor safety. In present basic study, the rising behavior of a single nitrogen bubble in five kinds of liquid metals (lead bismuth alloy, liquid kalium, sodium, potassium sodium alloy and lithium lead alloy) was numerically simulated using moving particle semi-implicit (MPS) method. The whole growing process of single nitrogen bubble in liquid metal was captured. The bubble shape and rising speed of single nitrogen bubble in each liquid metal were compared. The comparison between simulation results using MPS method and Grace graphical correlation shows a good agreement. (authors)
Immersion apparatus and process for an ultrasonic transducer in a liquid metal
International Nuclear Information System (INIS)
Le Baud, P.
1987-01-01
The ultrasonic transducer is introduced in a casing. The coupling zone of the transducer is covered by a layer of liquid metal. This layer is solidified and then the transducer with his coating layer is introduced in the liquid metal under an inert atmosphere. The device for immersing the transducer is claimed [fr
Experimental evidence for Mo isotope fractionation between metal and silicate liquids
Hin, Remco C.; Burkhardt, Christoph; Schmidt, Max W.; Bourdon, Bernard; Kleine, Thorsten
2013-10-01
Stable isotope fractionation of siderophile elements may inform on the conditions and chemical consequences of core-mantle differentiation in planetary objects. The extent to which Mo isotopes fractionate during such metal-silicate segregation, however, is so far unexplored. We have therefore investigated equilibrium fractionation of Mo isotopes between liquid metal and liquid silicate to evaluate the potential of Mo isotopes as a new tool to study core formation. We have performed experiments at 1400 and 1600 °C in a centrifuging piston cylinder. Tin was used to lower the melting temperature of the Fe-based metal alloys to double spike technique. In experiments performed at 1400 °C, the 98Mo/95Mo ratio of silicate is 0.19±0.03‰ (95% confidence interval) heavier than that of metal. This fractionation is not significantly affected by the presence or absence of carbon. Molybdenum isotope fractionation is furthermore independent of oxygen fugacity in the range IW -1.79 to IW +0.47, which are plausible values for core formation. Experiments at 1600 °C show that, at equilibrium, the 98Mo/95Mo ratio of silicate is 0.12±0.02‰ heavier than that of metal and that the presence or absence of Sn does not affect this fractionation. Equilibrium Mo isotope fractionation between liquid metal and liquid silicate as a function of temperature can therefore be described as ΔMoMetal-Silicate98/95=-4.70(±0.59)×105/T2. Our experiments show that Mo isotope fractionation may be resolvable up to metal-silicate equilibration temperatures of about 2500 °C, rendering Mo isotopes a novel tool to investigate the conditions of core formation in objects ranging from planetesimals to Earth sized bodies.
A volatile fluid assisted thermo-pneumatic liquid metal energy harvester
Energy Technology Data Exchange (ETDEWEB)
Tang, Jianbo, E-mail: zhouyuan@mail.ipc.ac.cn, E-mail: jianbotang@mail.ipc.ac.cn [Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Wang, Junjie; Liu, Jing; Zhou, Yuan, E-mail: zhouyuan@mail.ipc.ac.cn, E-mail: jianbotang@mail.ipc.ac.cn [Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)
2016-01-11
A close-cycle self-driving thermal energy harvester using liquid metal as energy carrier fluid has been proposed. The driving force that pushes the liquid metal against flow resistance and gravity is provided by a resistively heated volatile fluid based on thermo-pneumatic principle. The tested harvester prototype demonstrated its capability to extract thermal energy between small temperature gradient, at a scale of 10 °C. During a 5-h operation, it further demonstrated robust liquid metal recirculating performance at a time-average volume flow rate of 14 ml/min with a 12.25 W heating load. The prototype also managed to self-adjust to variable working conditions which indicated the reliability of this method. Advantages of this method include simple-structural design, rigid-motion free operation, and low-temperature actuation. These advantages make it uniquely suited for solar energy and low-grade heat harvesting, high heat flux electronics cooling, as well as autonomous machines actuating.
Biomedical implementation of liquid metal ink as drawable ECG electrode and skin circuit.
Directory of Open Access Journals (Sweden)
Yang Yu
Full Text Available BACKGROUND: Conventional ways of making bio-electrodes are generally complicated, expensive and unconformable. Here we describe for the first time the method of applying Ga-based liquid metal ink as drawable electrocardiogram (ECG electrodes. Such material owns unique merits in both liquid phase conformability and high electrical conductivity, which provides flexible ways for making electrical circuits on skin surface and a prospective substitution of conventional rigid printed circuit boards (PCBs. METHODS: Fundamental measurements of impedance and polarization voltage of the liquid metal ink were carried out to evaluate its basic electrical properties. Conceptual experiments were performed to draw the alloy as bio-electrodes to acquire ECG signals from both rabbit and human via a wireless module developed on the mobile phone. Further, a typical electrical circuit was drawn in the palm with the ink to demonstrate its potential of implementing more sophisticated skin circuits. RESULTS: With an oxide concentration of 0.34%, the resistivity of the liquid metal ink was measured as 44.1 µΩ·cm with quite low reactance in the form of straight line. Its peak polarization voltage with the physiological saline was detected as -0.73 V. The quality of ECG wave detected from the liquid metal electrodes was found as good as that of conventional electrodes, from both rabbit and human experiments. In addition, the circuit drawn with the liquid metal ink in the palm also runs efficiently. When the loop was switched on, all the light emitting diodes (LEDs were lit and emitted colorful lights. CONCLUSIONS: The liquid metal ink promises unique printable electrical properties as both bio-electrodes and electrical wires. The implemented ECG measurement on biological surface and the successfully run skin circuit demonstrated the conformability and attachment of the liquid metal. The present method is expected to innovate future physiological measurement and
The concepts of liquid metal of IV generation
International Nuclear Information System (INIS)
Carbonnier, J. L.
2005-01-01
The concepts of liquid metals, due to their large spectrum, show important possibility of sustainable development: two concepts of liquid metal (Sodium and Lead) were engaged in the frame of the IV generation. The reactors with sodium benefit from considerable background of experience and of important work on projects to aim at the price diminution and the increase of safety (EFR, JSFR). The commitment of Japan as a leader of this concept and the support by France allow to contemplate an industrial deployment from 2015. The lead reactors offer some advantages in the domain of safety but otherwise require a highly important research and development binded to the control of the corrosion, the perspective of deployment of this concept are more hypothetical
International Nuclear Information System (INIS)
Zheng, Lichun; Malfliet, Annelies; Wollants, Patrick; Blanpain, Bart; Guo, Muxing
2016-01-01
The effect of surfactant Te on the behavior of alumina inclusions at advancing solid-liquid interfaces of liquid steel was studied by adding Te to liquid steel before Al deoxidation at 1873 K. After water-quenching, the spatial distribution homogeneity of alumina inclusions in the steel matrix was characterized using the Dirichlet tessellation method. The deterioration of this homogeneity with increasing the addition of Te indicates that Te facilitates pushing of alumina inclusions. This phenomenon was discussed based on the thermodynamics of an asymmetric thin liquid film confined by an advancing solid-liquid interface and a particle. The surface excesses of Te at the solid-liquid and particle-liquid interfaces were theoretically demonstrated to decrease when an alumina inclusion moves towards the solid-liquid interface, thereby weakening the effect of Te on the solid-liquid and particle-liquid interfacial energies. Based on this, effect of surfactants was incorporated in the models predicting the critical velocity V_C.
Liquid uranium contaimment in refractories metals
International Nuclear Information System (INIS)
Duarte, J.L.; Padilha, A.F.
1982-01-01
Tests were performed on metalic materials for liquid uranium containment up to 2100 0 C. The materials Nb, Mo, Ta and W in the form of crucibles were tested at 2100 0 C for one hour in the presence of flowing argon. After testing, the crucibles were etched using HCl and analysed by optical metallography and electron proble microanalysis. The results are discussed in terms of Berthoud equation and indicated that the solubility limit of the crucible material in uranium at the temperature controlls the crucible dissolution by liquid uranium. The various phases formed, the mechanism of dissolution and the possible material for future use are presented and discussed. (Author) [pt
Packaging a liquid metal ESD with micro-scale Mercury droplet.
Energy Technology Data Exchange (ETDEWEB)
Barnard, Casey Anderson
2011-08-01
A liquid metal ESD is being developed to provide electrical switching at different acceleration levels. The metal will act as both proof mass and electric contact. Mercury is chosen to comply with operation parameters. There are many challenges surrounding the deposition and containment of micro scale mercury droplets. Novel methods of micro liquid transfer are developed to deliver controllable amounts of mercury to the appropriate channels in volumes under 1 uL. Issues of hermetic sealing and avoidance of mercury contamination are also addressed.
Metal fuel manufacturing and irradiation performance
International Nuclear Information System (INIS)
Pedersen, D.R.; Walters, L.C.
1992-01-01
The advances in metal fuel by the Integral Fast Reactor Program at Argonne National Laboratory are the subject of this paper. The Integral Fast Reactor (IFR) is an advanced liquid-metal-cooled reactor concept being developed at Argonne National Laboratory. The advances stressed in the paper include fuel irradiation performance, and improved passive safety. The goals and the safety philosophy of the Integral Fast Reactor Program are stressed
Banerjee, Abhinandan; Theron, Robin; Scott, Robert W J
2012-01-09
Gold and palladium nanoparticles were prepared by lithium borohydride reduction of the metal salt precursors in tetraalkylphosphonium halide ionic liquids in the absence of any organic solvents or external nanoparticle stabilizers. These colloidal suspensions remained stable and showed no nanoparticle agglomeration over many months. A combination of electrostatic interactions between the coordinatively unsaturated metal nanoparticle surface and the ionic-liquid anions, bolstered by steric protection offered by the bulky alkylated phosphonium cations, is likely to be the reason behind such stabilization. The halide anion strongly absorbs to the nanoparticle surface, leading to exceptional nanoparticle stability in halide ionic liquids; other tetraalkylphosphonium ionic liquids with non-coordinating anions, such as tosylate and hexafluorophosphate, show considerably lower affinities towards the stabilization of nanoparticles. Palladium nanoparticles stabilized in the tetraalkylphosphonium halide ionic liquid were stable, efficient, and recyclable catalysts for a variety of hydrogenation reactions at ambient pressures with sustained activity. Aerial oxidation of the metal nanoparticles occurred over time and was readily reversed by re-reduction of oxidized metal salts. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Irradiation performance of U-Pu-Zr metal fuels for liquid-metal-cooled reactors
International Nuclear Information System (INIS)
Tsai, H.; Cohen, A.B.; Billone, M.C.; Neimark, L.A.
1994-10-01
This report discusses a fuel system utilizing metallic U-Pu-Zr alloys which has been developed for advanced liquid metal-cooled reactors (LMRs). Result's from extensive irradiation testing conducted in EBR-II show a design having the following key features can achieve both high reliability and high burnup capability: a cast nominally U-20wt %Pu-10wt %Zr slug with the diameter sized to yield a fuel smear density of ∼75% theoretical density, low-swelling tempered martensitic stainless steel cladding, sodium bond filling the initial fuel/cladding gap, and an as-built plenum/fuel volume ratio of ∼1.5. The robust performance capability of this design stems primarily from the negligible loading on the cladding from either fuel/cladding mechanical interaction or fission-gas pressure during the irradiation. The effects of these individual design parameters, e.g., fuel smear density, zirconium content in fuel, plenum volume, and cladding types, on fuel element performance were investigated in a systematic irradiation experiment in EBR-II. The results show that, at the discharge burnup of ∼11 at. %, variations on zirconium content or plenum volume in the ranges tested have no substantial effects on performance. Fuel smear density, on the other hand, has pronounced but countervailing effects: increased density results in greater cladding strain, but lesser cladding wastage from fuel/cladding chemical interaction
Theoretical and Experimental Investigation of Liquid Metal MHD Power Generation
Energy Technology Data Exchange (ETDEWEB)
Elliott, D. G.; Cerini, D. J.; Hays, L. G.; Weinberg, E. [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA (United States)
1966-11-15
Liquid metal magnetohydrodynamic power generation for space is studied. Closed- loop circulation of liquid metal without moving mechanical parts, and generation of electric power from the circulating metal, have been investigated analytically and experimentally, and the attainable cycle efficiencies have been calculated. Recent literature has pointed out the possibility of efficient a.c. generators with liquid metal as the working fluid, and this type of generator is under study. Analysis indicates that efficiencies up to 65% are attainable in a travelling-wave induction generator at the available liquid metal velocities of 100-200 m/sec, provided the generator has a length/gap ratio of no more than 50 for low friction loss, has an electrical length of no more than three wavelengths for low winding loss, and has end-effect compensation for cancelling finite-length effects in the power-generating region. The analysis leading to these conclusions is presented. The type of end-effect correction being studied is the ''compensating-pole'' technique in which an oscillating magnetic field is applied to the fluid entering and leaving the generator to make the flux linkages within the generator the same as those in a rotating or ''infinite'' generator. An experimental one-wavelength generator employing compensating poles has been fabricated, and empty-channel magnetic field measurements have been completed in preparation for tests with NaK. Two types of field measurements were made: d.c. measurements to determine the field profile as a function of phase angle and a.c. measurements to investigate the synchronization of the compensating poles with the travelling wave. The d.c. results showed that the flux linkages in the power generating region can be held close to those in a rotating machine, and the a.c. results showed that the compensating poles can be accurately synchronized with the travelling wave through transformer coupling. The component efficiencies from the
Electromagnetic-acoustic coupling in ferromagnetic metals at liquid-helium temperatures
DEFF Research Database (Denmark)
Gordon, R A
1981-01-01
Electromagnetic-acoustic coupling at the surface and in the bulk of ferromagnetic metals at liquid-helium temperatures has been studied using electromagnetically excited acoustic standing-wave resonances at MHz frequencies in a number of ferromagnetic metals and alloys of commercial interest...
The magnetohydrodynamic force experienced by spherical iron particles in liquid metal
International Nuclear Information System (INIS)
Ščepanskis, Mihails; Jakovičs, Andris
2016-01-01
The paper contains a theoretical investigation of magnetohydrodynamic force experienced by iron particles (well-conducting and ferromagnetic) in well-conducting liquid. The investigation is performed by extending the Leenov and Kolin's theory to take into account the second-order effect. Therefore, the limits of the parent model are taken over to the present results. It is found that the effective conductivity of iron particles in liquid metal, which is important for practical application of the theoretically obtained force, is approximately equal to 1.5·10"6 S/m. The last result is obtained using a quasi-empirical approach – a comparison of experimental results with the results of the numerical simulation that was performed for various conductivities of the iron particles. - Highlights: • We found the expression of an MHD force experienced by a spherical iron particle in a liquid metal taking into account the second order effect additionally to Leenov & Kolin’s theoretical solution. • We found the effective conductivity of an iron particle in a liquid metal in quasi-empirical way equal to 1.5·10"6 S/m. • It is important to use the expression of an MHD force, which takes into account the second-order effect, as well as the correction for effective conductivity of a particle, to describe behaviour of iron particles in liquid metal flows, which are under influence or induced by the Lorentz force.
Liquid metal cooled nuclear reactor constructions
International Nuclear Information System (INIS)
Aspden, G.J.; Allbeson, K.F.
1984-01-01
In a liquid metal cooled nuclear reactor with a nuclear fuel assembly in a coolant-containing primary vessel housed within a concrete containment vault, there is thermal insulation to protect the concrete, the insulation being disposed between vessel and concrete and being hung from metal structure secured to and projecting from the concrete, the insulation consisting of a plurality of adjoining units each unit incorporating a pack of thermal insulating material and defining a contained void co-extensive with said pack and situated between pack and concrete, the void of each unit being connected to the voids of adjoining units so as to form continuous ducting for a fluid coolant. (author)
Seismic isolation development for the US advanced liquid-metal reactor program
International Nuclear Information System (INIS)
Gluekler, E.L.; Bigelow, C.C.; DeVita, V.; Kelly, J.M.; Seidensticker, R.W.; Tajirian, F.F.
1989-01-01
GE Nuclear Energy, in association with a US Industrial Team and support from the US National Laboratories and Universities, is developing a modular liquid-metal reactor concept for the US Department of Energy (DOE). The objective of this development is to provide, by the turn of the century, a reactor concept with optimized passive safety features that is economically competitive with other domestic energy sources, licensable, and ready for commercial deployment. One of the unique features of the concept is the seismic isolation of the reactor modules which decouples the reactor and their safety systems from potentially damaging ground motions and significantly enhances the structural resistance to high energy, as well as long duration earthquakes. Seismic isolation is accomplished with high damping natural rubber bearings. The reactors are located in individual silos below grade level and are supported by the isolator bearings at approximately their center of gravity. This application of seismic isolation is the first for a US nuclear power plant. A development program has been established to assure the full benefits from the utilization of this new approach and to provide adequate system characterization and qualification for licensing certification. The development program is described in this paper and selected results are presented. The initial testing indicated excellent performance of high damping natural rubber bearings
Experiments with Liquid Metal Walls: Status of the Lithium Tokamak Experiment
Boyle, Dennis; Gray, Timothy; Granstedt, Erik; Kozub, Thomas; Berzak, Laura; Hammett, Gregory; Kugel, Henry; Leblanc, Benoit; Logan, Nicholas; Jacobson, Craig M.; Lucia, Matthew; Jones, Andrew; Lundberg, Daniel; Timberlake, John; Majeski, Richard
2010-01-01
Liquid metal walls have been proposed to address the first wall challenge for fusion reactors. The Lithium Tokamak Experiment (LTX) at the Princeton Plasma Physics Laboratory (PPPL) is the first magnetic confinement device to have liquid metal plasma-facing components (PFC's) that encloses virtually the entire plasma. In the Current Drive Experiment-Upgrade (CDX-U), a predecessor to LTX at PPPL, the highest improvement in energy confinement ever observed in Ohmically-heated tokamak plasmas wa...
Liquid-metal plasma-facing component research on the National Spherical Torus Experiment
Jaworski, M. A.; Khodak, A.; Kaita, R.
2013-12-01
Liquid metal plasma-facing components (PFCs) have been proposed as a means of solving several problems facing the creation of economically viable fusion power reactors. Liquid metals face critical issues in three key areas: free-surface stability, material migration and demonstration of integrated scenarios. To date, few demonstrations exist of this approach in a diverted tokamak and we here provide an overview of such work on the National Spherical Torus Experiment (NSTX). The liquid lithium divertor (LLD) was installed and operated for the 2010 run campaign using evaporated coatings as the filling method. Despite a nominal liquid level exceeding the capillary structure and peak current densities into the PFCs exceeding 100 kA m-2, no macroscopic ejection events were observed. The stability can be understood from a Rayleigh-Taylor instability analysis. Capillary restraint and thermal-hydraulic considerations lead to a proposed liquid-metal PFCs scheme of actively-supplied, capillary-restrained systems. Even with state-of-the-art cooling techniques, design studies indicate that the surface temperature with divertor-relevant heat fluxes will still reach temperatures above 700 °C. At this point, one would expect significant vapor production from a liquid leading to a continuously vapor-shielded regime. Such high-temperature liquid lithium PFCs may be possible on the basis of momentum-balance arguments.
[Advances of poly (ionic liquid) materials in separation science].
Liu, Cuicui; Guo, Ting; Su, Rina; Gu, Yuchen; Deng, Qiliang
2015-11-01
Ionic liquids, as novel ionization reagents, possess beneficial characteristics including good solubility, conductivity, thermal stability, biocompatibility, low volatility and non-flammability. Ionic liquids are attracting a mass of attention of analytical chemists. Poly (ionic liquid) materials have common performances of ionic liquids and polymers, and have been successfully applied in separation science area. In this paper, we discuss the interaction mechanisms between the poly(ionic liquid) materials and analytes including hydrophobic/hydrophilic interactions, hydrogen bond, ion exchange, π-π stacking and electrostatic interactions, and summarize the application advances of the poly(ionic liquid) materials in solid phase extraction, chromatographic separation and capillary electrophoresis. At last, we describe the future prospect of poly(ionic liquid) materials.
Nanoporous metals for advanced energy technologies
Ding, Yi
2016-01-01
This book covers the state-of-the-art research in nanoporous metals for potential applications in advanced energy fields, including proton exchange membrane fuel cells, Li batteries (Li ion, Li-S, and Li-O2), and supercapacitors. The related structural design and performance of nanoporous metals as well as possible mechanisms and challenges are fully addressed. The formation mechanisms of nanoporous metals during dealloying, the microstructures of nanoporous metals and characterization methods, as well as miscrostructural regulation of nanoporous metals through alloy design of precursors and surface diffusion control are also covered in detail. This is an ideal book for researchers, engineers, graduate students, and government/industry officers who are in charge of R&D investments and strategy related to energy technologies.
Topology-generating interfacial pattern formation during liquid metal dealloying.
Geslin, Pierre-Antoine; McCue, Ian; Gaskey, Bernard; Erlebacher, Jonah; Karma, Alain
2015-11-19
Liquid metal dealloying has emerged as a novel technique to produce topologically complex nanoporous and nanocomposite structures with ultra-high interfacial area and other unique properties relevant for diverse material applications. This process is empirically known to require the selective dissolution of one element of a multicomponent solid alloy into a liquid metal to obtain desirable structures. However, how structures form is not known. Here we demonstrate, using mesoscale phase-field modelling and experiments, that nano/microstructural pattern formation during dealloying results from the interplay of (i) interfacial spinodal decomposition, forming compositional domain structures enriched in the immiscible element, and (ii) diffusion-coupled growth of the enriched solid phase and the liquid phase into the alloy. We highlight how those two basic mechanisms interact to yield a rich variety of topologically disconnected and connected structures. Moreover, we deduce scaling laws governing microstructural length scales and dealloying kinetics.
Lacoste, Eric; Arvieu, Corinne; Mantaux, Olivier
2018-04-01
One of the technologies used to produce metal matrix composites (MMCs) is liquid route processing. One solution is to inject a liquid metal under pressure or at constant rate through a fibrous preform. This foundry technique overcomes the problem of the wettability of ceramic fibers by liquid metal. The liquid route can also be used to produce semiproducts by coating a filament with a molten metal. These processes involve physical phenomena combined with mass and heat transfer and phase change. The phase change phenomena related to solidification and also to the melting of the metal during the process notably result in modifications to the permeability of porous media, in gaps in impregnation, in the appearance of defects (porosities), and in segregation in the final product. In this article, we provide a state-of-the-art review of numerical models and simulation developed to study these physical phenomena involved in MMC processing by the liquid route.
Determination of stable shapes of a thin liquid metal layer using a boundary integral method
Energy Technology Data Exchange (ETDEWEB)
Hinaje, M [Groupe de Recherche en Electrotechnique et Electronique de Nancy, 2 avenue de la Foret de Haye, 54516 Vandoeuvre-les-Nancy (France); Vinsard, G [Laboratoire d' Energetique et de Mecanique Theorique et Appliquee, 2 avenue de la Foret de Haye, 54516 Vandoeuvre-les-Nancy (France); Dufour, S [Groupe de Recherche en Electrotechnique et Electronique de Nancy, 2 avenue de la Foret de Haye, 54516 Vandoeuvre-les-Nancy (France)
2006-03-21
This paper deals with a thin liquid metal layer submitted to an ac magnetic field. Experimentally, we have noticed that even if the system (inductor+liquid metal) is axisymmetric, when an ac magnetic field is applied the symmetry is broken. The observed deformations of the liquid metal are in three dimensions. Therefore, our aim is to investigate this deformation using a numerical method as boundary element method in three dimensions.
Determination of stable shapes of a thin liquid metal layer using a boundary integral method
International Nuclear Information System (INIS)
Hinaje, M; Vinsard, G; Dufour, S
2006-01-01
This paper deals with a thin liquid metal layer submitted to an ac magnetic field. Experimentally, we have noticed that even if the system (inductor+liquid metal) is axisymmetric, when an ac magnetic field is applied the symmetry is broken. The observed deformations of the liquid metal are in three dimensions. Therefore, our aim is to investigate this deformation using a numerical method as boundary element method in three dimensions
Recent Advances in Discotic Liquid Crystal-Assisted Nanoparticles
Directory of Open Access Journals (Sweden)
Ashwathanarayana Gowda
2018-03-01
Full Text Available This article primarily summarizes recent advancement in the field of discotic liquid crystal (DLC nanocomposites. Discotic liquid crystals are nanostructured materials, usually 2 to 6 nm size and have been recognized as organic semiconducting materials. Recently, it has been observed that the dispersion of small concentration of various functionalized zero-, one- and two-dimensional nanomaterials in the supramolecular order of mesophases of DLCs imparts negligible impact on liquid crystalline properties but enhances their thermal, supramolecular and electronic properties. Synthesis, characterization and dispersion of various nanoparticles in different discotics are presented.
Sorption of radiostrontium from liquid metallic rubidium
International Nuclear Information System (INIS)
Zhujkov, B.L.; Kokhnyuk, V.M.; Vincent, J.S.
2008-01-01
One studied the radiostrontium (in particular, 82 Sr) sorption from the liquid metallic Rb in various inorganic sorbents (both metals and oxides). One studied the temperature dependence and the dynamics of the adsorption and put forward an interpretation of the observed mechanisms. The elaborated approach enables to extract 82 Sr efficiently from the Rb targets upon their irradiation by the accelerated protons. One studies various procedures and the applicability of the process to ensure elaboration of a new highly efficient process to produce 82 Sr, in particular, with the targets of the circulating Rb [ru
Experiments for liquid metal embrittlement of fusion reactor materials by liquid lithium
International Nuclear Information System (INIS)
Grundmann, M.; Borgstedt, H.U.
1984-10-01
The liquid metal embrittlement behaviour of two martensitic-ferritic steels [X22CrMoV121 (Nr. 1.4923) and X18CrMoVNb 121 (Nr. 1,4914)] and one austenite chromium-nickel-steel X5CrNi189 (Nr. 1.4301) was investigated. Tensile tests in liquid lithium at 200 and 250 0 C with two different strain rates on precorroded samples (1000 h at 550 0 C in lithium) were carried out. Reference values were gained from tensile tests in air (RT, 250 0 C). It is concluded that there is sufficient compatibility of the austenitic steel with liquid lithium. The use of the ferritic-martensitic steels in liquid lithium on the other hand, especially at temperatures of about 550 0 C, seems to be problematic. The experimental results led to a better understanding of LME, applying the theory of this material failure. (orig./IHOE) [de
International workshop on measuring techniques for liquid metal flows (MTLM). Abstracts
Energy Technology Data Exchange (ETDEWEB)
Gerbeth, G; Eckert, S [eds.
1999-11-01
The international workshop on 'Measuring techniques in liquid metal flows' (MTLM workshop) was organised in frame of the Dresden 'Innovationskolleg Magnetofluiddynamik'. The subject of the MTLM workshop was limited to methods to determine physical flow quantities such as velocity, pressure, void fraction, inclusion properties, crystallisation fronts etc. The present proceedings contain abstracts and viewgraphs of the oral presentations. During the last decades numerical simulations have become an important tool in industry and research to study the structure of flows and the properties of heat and mass transfer. However, in case of liquid metal flows there exists a significant problem to validate the codes with experimental data due to the lack of available measuring techniques. Due to the material properties (opaque, hot, chemical aggressive) the measurement of flow quantities is much more delicate in liquid metals compared to ordinary water flows. The generalisation of results obtained by means of water models to real liquid metal flows has often to be considered as difficult due to the problems to meet the actual values of n0n-dimensional flow parameters (Re, Pr, Gr, Ha, etc.). Moreover, a strong need has to be noted to make measuring techniques available tomonitor and to control flow processes in real industrial facilities. The objectives of the MTLM workshop were to: Review of existing information on a available techniques and experiences about the use in liquid metal flows, initiate a discussion between developers and potential users with respect to the actual need of information about the flow structure as well as the capabilities of existing and developing measuring techniques. Explore opportunities for co-operative R and D projects to expedite new developments and results, to share expertise and resources. (orig.)
International workshop on measuring techniques for liquid metal flows (MTLM). Abstracts
Energy Technology Data Exchange (ETDEWEB)
Gerbeth, G.; Eckert, S. [eds.
1999-11-01
The international workshop on 'Measuring techniques in liquid metal flows' (MTLM workshop) was organised in frame of the Dresden 'Innovationskolleg Magnetofluiddynamik'. The subject of the MTLM workshop was limited to methods to determine physical flow quantities such as velocity, pressure, void fraction, inclusion properties, crystallisation fronts etc. The present proceedings contain abstracts and viewgraphs of the oral presentations. During the last decades numerical simulations have become an important tool in industry and research to study the structure of flows and the properties of heat and mass transfer. However, in case of liquid metal flows there exists a significant problem to validate the codes with experimental data due to the lack of available measuring techniques. Due to the material properties (opaque, hot, chemical aggressive) the measurement of flow quantities is much more delicate in liquid metals compared to ordinary water flows. The generalisation of results obtained by means of water models to real liquid metal flows has often to be considered as difficult due to the problems to meet the actual values of n0n-dimensional flow parameters (Re, Pr, Gr, Ha, etc.). Moreover, a strong need has to be noted to make measuring techniques available tomonitor and to control flow processes in real industrial facilities. The objectives of the MTLM workshop were to: Review of existing information on a available techniques and experiences about the use in liquid metal flows, initiate a discussion between developers and potential users with respect to the actual need of information about the flow structure as well as the capabilities of existing and developing measuring techniques. Explore opportunities for co-operative R and D projects to expedite new developments and results, to share expertise and resources. (orig.)
National Research Council Canada - National Science Library
Gorland, Sol
1965-01-01
This report presents experimental results pertaining to the design and development of a metallic expulsion diaphragm for single-cycle positive expulsion of high-temperature liquid in an agravity condition...
A Liquid Metal Flume for Free Surface Magnetohydrodynamic Experiments
International Nuclear Information System (INIS)
Nornberg, M.D.; Ji, H.; Peterson, J.L.; Rhoads, J.R.
2008-01-01
We present an experiment designed to study magnetohydrodynamic effects in free-surface channel flow. The wide aspect ratio channel (the width to height ratio is about 15) is completely enclosed in an inert atmosphere to prevent oxidization of the liquid metal. A custom-designed pump reduces entrainment of oxygen, which was found to be a problem with standard centrifugal and gear pumps. Laser Doppler Velocimetry experiments characterize velocity profiles of the flow. Various flow constraints mitigate secondary circulation and end effects on the flow. Measurements of the wave propagation characteristics in the liquid metal demonstrate the surfactant effect of surface oxides and the damping of fluctuations by a cross-channel magnetic field
Model of liquid-metal splashing in the cathode spot of a vacuum arc discharge
International Nuclear Information System (INIS)
Gashkov, M. A.; Zubarev, N. M.; Zubareva, O. V.; Mesyats, G. A.; Uimanov, I. V.
2016-01-01
The formation of microjets is studied during the extrusion of a melted metal by the plasma pressure from craters formed on a cathode in a burning vacuum arc. An analytic model of liquid-metal splashing that includes two stages is proposed. At the first stage, the liquid motion has the axial symmetry and a liquid-metal wall surrounding the crater is formed. At the second stage, the axial symmetry is broken due to the development of the Plateau–Rayleigh instability in the upper part of the wall. The wall breakup process is shown to have a threshold. The minimal plasma pressure and the minimal electric current flowing through the crater required for obtaining the liquid-metal splashing regime are found. The basic spatial and temporal characteristics of the jet formation process are found using the analytic model.
Surface energies of metals in both liquid and solid states
International Nuclear Information System (INIS)
Aqra, Fathi; Ayyad, Ahmed
2011-01-01
Although during the last years one has seen a number of systematic studies of the surface energies of metals, the aim and the scientific meaning of this research is to establish a simple and a straightforward theoretical model to calculate accurately the mechanical and the thermodynamic properties of metal surfaces due to their important application in materials processes and in the understanding of a wide range of surface phenomena. Through extensive theoretical calculations of the surface tension of most of the liquid metals, we found that the fraction of broken bonds in liquid metals (f) is constant which is equal to 0.287. Using our estimated f value, the surface tension (γ m ), surface energy (γ SV ), surface excess entropy (-dγ/dT), surface excess enthalpy (H s ), coefficient of thermal expansion (α m and α b ), sound velocity (c m ) and its temperature coefficient (-dc/dT) have been calculated for more than sixty metals. The results of the calculated quantities agree well with available experimental data.
Metal-organic frameworks based membranes for liquid separation.
Li, Xin; Liu, Yuxin; Wang, Jing; Gascon, Jorge; Li, Jiansheng; Van der Bruggen, Bart
2017-11-27
Metal-organic frameworks (MOFs) represent a fascinating class of solid crystalline materials which can be self-assembled in a straightforward manner by the coordination of metal ions or clusters with organic ligands. Owing to their intrinsic porous characteristics, unique chemical versatility and abundant functionalities, MOFs have received substantial attention for diverse industrial applications, including membrane separation. Exciting research activities ranging from fabrication strategies to separation applications of MOF-based membranes have appeared. Inspired by the marvelous achievements of MOF-based membranes in gas separations, liquid separations are also being explored for the purpose of constructing continuous MOFs membranes or MOF-based mixed matrix membranes. Although these are in an emerging stage of vigorous development, most efforts are directed towards improving the liquid separation efficiency with well-designed MOF-based membranes. Therefore, as an increasing trend in membrane separation, the field of MOF-based membranes for liquid separation is highlighted in this review. The criteria for judicious selection of MOFs in fabricating MOF-based membranes are given. Special attention is paid to rational design strategies for MOF-based membranes, along with the latest application progress in the area of liquid separations, such as pervaporation, water treatment, and organic solvent nanofiltration. Moreover, some attractive dual-function applications of MOF-based membranes in the removal of micropollutants, degradation, and antibacterial activity are also reviewed. Finally, we define the remaining challenges and future opportunities in this field. This Tutorial Review provides an overview and outlook for MOF-based membranes for liquid separations. Further development of MOF-based membranes for liquid separation must consider the demands of strict separation standards and environmental safety for industrial application.
Enhanced metal recovery through oxidation in liquid and/or supercritical carbon dioxide
Blanco, Mario; Buttner, Ulrich
2017-01-01
Process for enhanced metal recovery from, for example, metal-containing feedstock using liquid and/or supercritical fluid carbon dioxide and a source of oxidation. The oxidation agent can be free of complexing agent. The metal-containing feedstock
Complaint liquid metal electrodes for dielectric elastomer actuators
Finkenauer, Lauren R.; Majidi, Carmel
2014-03-01
This work presents a liquid-phase metal electrode to be used with poly(dimethylsiloxane) (PDMS) for a dielectric elastomer actuator (DEA). DEAs are favorable for soft-matter applications where high efficiency and response times are desirable. A consistent challenge faced during the fabrication of these devices is the selection and deposition of electrode material. While numerous designs have been demonstrated with a variety of conductive elastomers and greases, these materials have significant and often intrinsic shortcomings, e.g. low conductivity, hysteresis, incapability of large deformations, and complex fabrication requirements. The liquid metal alloy eutectic Gallium-Indium (EGaIn) is a promising alternative to existing compliant electrodes, having both high conductivity and complete soft-matter functionality. The liquid electrode shares almost the same electrical conductivity as conventional metal wiring and provides no mechanical resistance to bending or stretching of the DEA. This research establishes a straightforward and effective method for quickly depositing EGaIn electrodes, which can be adapted for batch fabrication, and demonstrates the successful actuation of sample curved cantilever elastomer actuators using these electrodes. As with the vast majority of electrostatically actuated elastomer devices, the voltage requirements for these curved DEAs are still quite significant, though modifications to the fabrication process show some improved electrical properties. The ease and speed with which this method can be implemented suggests that the development of a more electronically efficient device is realistic and worthwhile.
Nuclear quadrupole relaxation and viscosity in liquid metals
International Nuclear Information System (INIS)
Schirmacher, W.
1976-01-01
It is shown that the nuclear quadrupole relaxation rate due to the molecular motions in liquid metals is related to the shear and bulk viscosity and hence to the absorption coefficient of ultrasound. Application of the 'extended liquid phonon' model of Ortoleva and Nelkin - which is the third of a series of continued-fraction-approximations for the van Hove neutron scattering function - gives a relation to the self diffusion constant. The predictions of the theory concerning the temperature dependence are compared with quadrupole relaxation measurements of Riegel et al. and Kerlin et al. in liquid gallium. Agreement is found only with the data of Riegel et al. (orig.) [de
Liquid-metal plasma-facing component research on the National Spherical Torus Experiment
International Nuclear Information System (INIS)
Jaworski, M A; Khodak, A; Kaita, R
2013-01-01
Liquid metal plasma-facing components (PFCs) have been proposed as a means of solving several problems facing the creation of economically viable fusion power reactors. Liquid metals face critical issues in three key areas: free-surface stability, material migration and demonstration of integrated scenarios. To date, few demonstrations exist of this approach in a diverted tokamak and we here provide an overview of such work on the National Spherical Torus Experiment (NSTX). The liquid lithium divertor (LLD) was installed and operated for the 2010 run campaign using evaporated coatings as the filling method. Despite a nominal liquid level exceeding the capillary structure and peak current densities into the PFCs exceeding 100 kA m −2 , no macroscopic ejection events were observed. The stability can be understood from a Rayleigh–Taylor instability analysis. Capillary restraint and thermal-hydraulic considerations lead to a proposed liquid-metal PFCs scheme of actively-supplied, capillary-restrained systems. Even with state-of-the-art cooling techniques, design studies indicate that the surface temperature with divertor-relevant heat fluxes will still reach temperatures above 700 °C. At this point, one would expect significant vapor production from a liquid leading to a continuously vapor-shielded regime. Such high-temperature liquid lithium PFCs may be possible on the basis of momentum-balance arguments. (paper)
Liquid metal targets for high-power applications : pulsed heating and shock hydrodynamics
International Nuclear Information System (INIS)
Hassanein, A.
2000-01-01
Significant interest has recently focused on the use of liquid-metal targets flowing with high velocities for various high-power nuclear and high-energy physics applications such as fusion reactor first-walls, the Spallation Neutron Source, Isotope Separation On Line, and Muon Collider projects. This is because the heat generated in solid targets due to beam or plasma bombardment cannot be removed easily and the resulting thermal shock damage could be a serious lifetime problem for long-term operation. More recently, the use of free or open flying-liquid jets has been proposed for higher-power-density applications. The behavior of a free-moving liquid mercury or gallium jet subjected to proton beam deposition in a strong magnetic field has been modeled and analyzed for the Muon Collider project. Free-liquid-metal jets can offer significant advantages over conventional solid targets, particularly for the more demanding and challenging high-power applications. However, the use of free-moving liquid-metal targets raises a number of new and challenging problems such as instabilities of the jet in a strong magnetic field, induced eddy-current effects on jet shape, thermal-shock formation, and possible jet fragmentation. Problems associated with shock heating of liquid jets in a strong magnetic field are analyzed in this study
Hydration forces and liquid-like layer on the ice/metal interface
International Nuclear Information System (INIS)
Daikhin, Leonid; Tsionsky, Vladimir
2007-01-01
A model to describe the phenomenon of the liquid-like layer is proposed. It is based on the theory of the hydration forces proposed by Gruen and Marcelja (1983 J. Chem. Soc. Faraday Trans. II 79 225), taking into account the influence of ions on the free energy of water. The model was applied to experimental data obtained with the quartz-crystal microbalance, in a study of the liquid-like layer between metal and frozen aqueous electrolytes and between metal and ice
Directory of Open Access Journals (Sweden)
Carlos O. Maidana
2017-02-01
Full Text Available Liquid alloy systems have a high degree of thermal conductivity, far superior to ordinary nonmetallic liquids and inherent high densities and electrical conductivities. This results in the use of these materials for specific heat conducting and dissipation applications for the nuclear and space sectors. Uniquely, they can be used to conduct heat and electricity between nonmetallic and metallic surfaces. The motion of liquid metals in strong magnetic fields generally induces electric currents, which, while interacting with the magnetic field, produce electromagnetic forces. Electromagnetic pumps exploit the fact that liquid metals are conducting fluids capable of carrying currents, which is a source of electromagnetic fields useful for pumping and diagnostics. The coupling between the electromagnetics and thermo-fluid mechanical phenomena and the determination of its geometry and electrical configuration, gives rise to complex engineering magnetohydrodynamics problems. The development of tools to model, characterize, design, and build liquid metal thermo-magnetic systems for space, nuclear, and industrial applications are of primordial importance and represent a cross-cutting technology that can provide unique design and development capabilities as well as a better understanding of the physics behind the magneto-hydrodynamics of liquid metals. First studies for the development of computational tools for the design of liquid metal electromagnetic pumps are discussed.
Energy Technology Data Exchange (ETDEWEB)
Maidana, Carlos O.; Nieminen, Juha E. [Maidana Research, Grandville (United States)
2017-02-15
Liquid alloy systems have a high degree of thermal conductivity, far superior to ordinary nonmetallic liquids and inherent high densities and electrical conductivities. This results in the use of these materials for specific heat conducting and dissipation applications for the nuclear and space sectors. Uniquely, they can be used to conduct heat and electricity between nonmetallic and metallic surfaces. The motion of liquid metals in strong magnetic fields generally induces electric currents, which, while interacting with the magnetic field, produce electromagnetic forces. Electromagnetic pumps exploit the fact that liquid metals are conducting fluids capable of carrying currents, which is a source of electromagnetic fields useful for pumping and diagnostics. The coupling between the electromagnetics and thermo-fluid mechanical phenomena and the determination of its geometry and electrical configuration, gives rise to complex engineering magnetohydrodynamics problems. The development of tools to model, characterize, design, and build liquid metal thermo-magnetic systems for space, nuclear, and industrial applications are of primordial importance and represent a cross-cutting technology that can provide unique design and development capabilities as well as a better understanding of the physics behind the magneto-hydrodynamics of liquid metals. First studies for the development of computational tools for the design of liquid metal electromagnetic pumps are discussed.
Density dependent atomic motion in a liquid alkali metal
International Nuclear Information System (INIS)
Pilgrim, W.-C.; Hosokawa, S.; Morkel, C.
2001-01-01
Inelastic X-ray and neutron scattering results obtained from liquid sodium and rubidium are presented. They cover the entire liquid range between melting and liquid vapour critical point. At high densities the dynamics of the liquid metal is characterized by collective excitations. The corresponding dispersion relations indicate the existence of surprisingly stable next neighbouring shells leading to an increase of the propagation speed for the collective modes. Below 2ρ crit. the dynamics changes from collective to localized indicating the existence of molecular aggregates. This interpretation is in accord with a simple model where the properties of a Rb- and a Rb 2 - lattice are calculated using density functional theory. (orig.)
International Nuclear Information System (INIS)
Dickinson, R.J.; Pennell, W.E.; Wasko, J.
1984-01-01
A liquid metal pump bearing support comprises a series of tangentially oriented spokes that connect the bearing cylinder to the pump internals structure. The spokes may be arranged in a plurality of planes extending from the bearing cylinder to the pump internals with the spokes in one plane being arranged alternately with those in the next plane. The bearing support structure provides the pump with sufficient lateral support for the bearing structure together with the capability of accommodating differential thermal expansion without adversely affecting pump performance
Liquid metal reactor absorber technology
International Nuclear Information System (INIS)
Pitner, A.L.
1990-10-01
The selection of boron carbide as the reference liquid metal reactor absorber material is supported by results presented for irradiation performance, reactivity worth compatibility, and benign failure consequences. Scram response requirements are met easily with current control rod configurations. The trend in absorber design development is toward larger sized pins with fewer pins per bundle, providing economic savings and improved hydraulic characteristics. Very long-life absorber designs appear to be attainable with the application of vented pin and sodium-bonded concepts. 3 refs., 3 figs
Inducer pumps for liquid metal reactor plants
International Nuclear Information System (INIS)
Jackson, E.D.
2002-01-01
Pumps proposed for liquid metal reactor plants typically use centrifugal impellers as the rotating element and are required to maintain a relatively low speed to keep the suction specific speed low enough to operate at the available net positive suction head (HPSH) and to avoid cavitation damage. These low speeds of operation require that the pump diameter increase and/or multiple stages be used to achieve the design head. This frequently results in a large, heavy, complex pump design. In addition, the low speed results in a larger drive motor size so that the resultant penalty to the plant designer is multiplied. The heavier pump can also result in further complications as, e.g., the difficulty in maintaining the first critical speed sufficiently above the pump operating range to provide margin for rotor dynamic stability. To overcome some of these disadvantages, it was proposed the use of inducer pumps for Liquid Metal Fast Breeder Reactor (LMFBR) plants. This paper discusses some of the advantages of the inducer pump and the development history of designing and testing these pumps both in water and sodium. The inducer pump is seen to be a sound concept with a strong technology base derived from the aerospace and ship propulsion industries. The superior suction performance capability of the inducer offers significant system design advantages, primarily a smaller, lighter weight, less complex pump design with resulting saving in cost. Extensive testing of these pumps has been conducted in both sodium and water to demonstrate the long-life capability with no cavitation damage occurring in those designs based on Rockwell's current design criteria. These tests have utilized multiple inspection and measurement approaches to accurately assess and identify any potential for cavitation damage, and these approaches have all concluded that no damage is occurring. Therefore, it is concluded that inducer pumps can be safely designed for long life operation in sodium with
Conceptual design of the liquid metal laboratory of the TECHNOFUSION facility
International Nuclear Information System (INIS)
Abánades, A.; García, A.; Casal, N.; Perlado, J.M.; Ibarra, A.
2012-01-01
Highlights: ► Conceptual design of a liquid Li facility. ► Components and cost estimation. ► Liquid metal laboratory into TEHNOFUSION proposal. - Abstract: The application of liquid metal technology in fusion devices requires R and D related to many phenomena: interaction between liquid metals and structural material as corrosion, erosion and passivation techniques; magneto-hydrodynamics; free surface fluid-dynamics and any other physical aspect that will be needed for their safe reliable operation. In particular, there is a significant shortage of experimental facilities dedicated to the development of the lithium technology. In the framework of the TECHNOFUSION project, an experimental laboratory devoted to the lithium technology development is proposed, in order to shed some light in the path to IFMIF and the design of chamber's first wall and divertors. The conceptual design foresee a development in two stages, the first one consisting on a material testing loop. The second stage proposes the construction of a mock-up of the IFMIF target that will allow to assess the behaviour of a free-surface lithium target under vacuum conditions. In this paper, such conceptual design is addressed.
Souza Macêdo, L.; Stellwagen, D.R.; Teixeira da Silva, V.; Bitter, J.H.
2015-01-01
Transition-metal carbides have been employed for biobased conversions aiming to replace the rare noble metals. However, when reactions are in liquid phase, many authors have observed catalyst deactivation. The main routes of deactivation in liquid phase biobased conversions are coke deposition,
Conceptual design studies for the liquid metal target META:LIC
International Nuclear Information System (INIS)
Class, A.G.; Fazio, C.; Fetzer, J.R.; Gordeev, S.
2014-01-01
When the construction of ESS (European Spallation Source) in Sweden was initiated, the target station concept selection group decided to reevaluate a variety of target designs to respect new developments in their selection process. The META:LIC (MEgawatt TArget:Lead bIsmuth Cooled) target concept was developed following an extensive analysis of existing and new proposed designs and reached the level of proof of principle within only 2 years. ESS selected META:LIC as comparative target option for licensing purposes during the design update phase of ESS. The present work describes the design motivation of META:LIC referring to properties and design features of other targets. Therefore, META:LIC design is an evolutionary target which incorporates the extensive experience of liquid metal targets. The modular LBE (Lead Bismuth Eutectic) target concept with focus on the target module is introduced. Both, a window target option for the start of operation and a windowless option with extended lifetime are foreseen. Thermohydraulic simulations show that adequate window cooling can be realized. The stability of the free surface in the windowless option has been shown. Robust target module instrumentation based on free surface levels and the MEGAPIE experience is proposed for target control. Since the META:LIC concept foresees a horizontal extraction for both moderators and target from the monolith a safety concept based on the SNS and JSNS experience is proposed
Thermodynamically self-consistent integral equations and the structure of liquid metals
International Nuclear Information System (INIS)
Pastore, G.; Kahl, G.
1987-01-01
We discuss the application of the new thermodynamically self-consistent integral equations for the determination of the structural properties of liquid metals. We present a detailed comparison of the structure (S(q) and g(r)) for models of liquid alkali metals as obtained from two thermodynamically self-consistent integral equations and some published exact computer simulation results; the range of states extends from the triple point to the expanded metal. The theories which only impose thermodynamic self-consistency without any fitting of external data show an excellent agreement with the simulation results, thus demonstrating that this new type of integral equation is definitely superior to the conventional ones (hypernetted chain, Percus-Yevick, mean spherical approximation, etc). (author)
Research on Liquid Forming Process of Nickel Superalloys Thin Sheet Metals
Directory of Open Access Journals (Sweden)
Hyrcza-Michalska M.
2017-12-01
Full Text Available The paper presents the study of drawability of thin sheet metals made of a nickel superalloy Inconel type. The manufacturing process of axisymmetric cup – cone and a closed section profile in the form of a circular tube were designed and analyzed. In both cases, working fluid-oil was used in place of the rigid tools. The process of forming liquid is currently the only alternative method for obtaining complex shapes, coatings, and especially if we do it with high-strength materials. In the case of nickel superalloys the search for efficient methods to manufacture of the shaped shell is one of the most considerable problems in aircraft industry [1-5]. However, the automotive industries have the same problem with so-called advanced high-strength steels (AHSS. Due to this, both industrial problems have been examined and the emphasis have been put on the process of liquid forming (hydroforming. The study includes physical tests and the corresponding numerical simulations performed, using the software Eta/Dynaform 5.9. Numerical analysis of the qualitative and quantitative forecasting enables the formability of materials with complex and unusual characteristics of the mechanical properties and forming technology. It has been found that only the computer aided design based on physical and numerical modeling, makes efficient plastic processing possible using a method of hydroforming. Drawability evaluation based on the determination of the mechanical properties of complex characteristics is an indispensable element of this design in the best practice of industrial manufacturing products made of thin sheet metals.
Economizer Based Data Center Liquid Cooling with Advanced Metal Interfaces
Energy Technology Data Exchange (ETDEWEB)
Timothy Chainer
2012-11-30
A new chiller-less data center liquid cooling system utilizing the outside air environment has been shown to achieve up to 90% reduction in cooling energy compared to traditional chiller based data center cooling systems. The system removes heat from Volume servers inside a Sealed Rack and transports the heat using a liquid loop to an Outdoor Heat Exchanger which rejects the heat to the outdoor ambient environment. The servers in the rack are cooled using a hybrid cooling system by removing the majority of the heat generated by the processors and memory by direct thermal conduction using coldplates and the heat generated by the remaining components using forced air convection to an air- to- liquid heat exchanger inside the Sealed Rack. The anticipated benefits of such energy-centric configurations are significant energy savings at the data center level. When compared to a traditional 10 MW data center, which typically uses 25% of its total data center energy consumption for cooling this technology could potentially enable a cost savings of up to $800,000-$2,200,000/year (assuming electricity costs of 4 to 11 cents per kilowatt-hour) through the reduction in electrical energy usage.
Dynamics of liquid metal droplets and jets influenced by a strong axial magnetic field
Hernández, D.; Karcher, Ch
2017-07-01
Non-contact electromagnetic control and shaping of liquid metal free surfaces is crucial in a number of high-temperature metallurgical processes like levitation melting and electromagnetic sealing, among others. Other examples are the electromagnetic bending or stabilization of liquid metal jets that frequently occur in casting or fusion applications. Within this context, we experimentally study the influence of strong axial magnetic fields on the dynamics of falling metal droplets and liquid metal jets. GaInSn in eutectic composition is used as test melt being liquid at room temperature. In the experiments, we use a cryogen-free superconducting magnet (CFM) providing steady homogeneous fields of up to 5 T and allowing a tilt angle between the falling melt and the magnet axis. We vary the magnetic flux density, the tilt angle, the liquid metal flow rate, and the diameter and material of the nozzle (electrically conducting/insulating). Hence, the experiments cover a parameter range of Hartmann numbers Ha, Reynolds numbers Re, and Weber numbers We within 0 rotation ceases and the droplets are stretched in the field direction. Moreover, we observe that the jet breakup into droplets (spheroidization) is suppressed, and in the case of electrically conducting nozzles and tilt, the jets are bent towards the field axis.
High-power spallation target using a heavy liquid metal free surface flow
International Nuclear Information System (INIS)
Litfin, K.; Fetzer, J.R.; Batta, A.; Class, A.G.; Wetzel, Th.
2015-01-01
A prototype of a heavy liquid metal free surface target as proposed for the multi-purpose hybrid research reactor for high-tech applications in Mol, Belgium, has been set up and experimentally investigated at the Karlsruhe Liquid Metal Laboratory. A stable operation was demonstrated in a wide range of operating conditions and the surface shape was detected and compared with numerical pre-calculations employing Star-CD. Results show a very good agreement of experiment and numerical predictions which is an essential input for other windowless target designs like the META:LIC target for the European Spallation Source. (author)
Liquid metal-to-gas leak-detection instruments
International Nuclear Information System (INIS)
Matlin, E.; Witherspoon, J.E.; Johnson, J.L.
1982-01-01
It is desirable for liquid-metal-cooled reactors that small liquid metal-to-gas leaks be reliably detected. Testing has been performed on a number of detection systems to evaluate their sensitivity, response time, and performance characteristics. This testing has been scheduled in three phases. The first phase was aimed at screening out the least suitable detectors and optimizing the performance of the most promising. In the second phase, candidates were tested in a 1500 ft 3 walk-in type enclosure in which leaks were simulated on 24-in. and 3-in. piping. In the third phase of testing, selected type detectors were tested in the 1500-ft 3 enclosure with Clinch River Breeder Reactor Plant (CRBRP) pipe insulation configurations and detector tubing configuration with cell gas recirculation simulated. Endurance testing of detection equipment was also performed as part of this effort. Test results have been shown that aerosol-type detectors will reliably detect leaks as small as a few grams per hour when sampling pipe insulation annuli
The mechanism of liquid metal jet formation in the cathode spot of vacuum arc discharge
Gashkov, M. A.; Zubarev, N. M.; Mesyats, G. A.; Uimanov, I. V.
2016-08-01
We have theoretically studied the dynamics of molten metal during crater formation in the cathode spot of vacuum arc discharge. At the initial stage, a liquid-metal ridge is formed around the crater. This process has been numerically simulated in the framework of the two-dimensional axisymmetric heat and mass transfer problem in the approximation of viscous incompressible liquid. At a more developed stage, the motion of liquid metal loses axial symmetry, which corresponds to a tendency toward jet formation. The development of azimuthal instabilities of the ridge is analyzed in terms of dispersion relations for surface waves. It is shown that maximum increments correspond to instability of the Rayleigh-Plateau type. Estimations of the time of formation of liquid metal jets and their probable number are obtained.
Lime treatment of liquid waste containing heavy metals, radionuclides and organics
International Nuclear Information System (INIS)
DuPont, A.
1990-01-01
This paper reports on lime treatment of liquid waste containing heavy metals, radio nuclides and organics. Lime is wellknown for its use in softening drinking water the treatment of municipal wastewaters. It is becoming important in the treatment of industrial wastewater and liquid inorganic hazardous waste; however, there are many questions regarding the use of lime for the treatment of liquid hazardous waste
Liquid metals replace water steam
Energy Technology Data Exchange (ETDEWEB)
Kozlov, V
1976-12-01
The techniques are described of power generation with regard to their effectiveness which depends on the efficiency of the conversion of thermal energy into electric energy. The magnetohydrodynamic conversion of energy is based on the use of induced electromotive force which results from the movement of the conductor in the magnetic field. The use of liquid metal as the working medium makes it possible to increase the initial temperature of the magnetohydrodynamic cycle to the limit of the highest technically attainable temperatures. The total efficiency of energy conversion in magnetohydrodynamic converters is 2 to 6%.
Electromagnetic device for confining a liquid metal and regulating the flow rate
International Nuclear Information System (INIS)
Garnier, Marcel; Moreau, R.J.
1977-01-01
The description is given of a device for confining a liquid metal jet, characterized in that it comprises in combination, at the jet outlet nozzle, (a) means for producing a high pressure in the jet composed of a coil around the nozzle and located on its outlet, in combination with facilities for passing a high frequency alternating current through the coil and (b) means for suppressing this high pressure. It is stated that this device has many uses, particularly for allowing the use of a relatively large diameter orifice, hence not subject to the risk of clogging, in order to produce a jet with a relatively small diameter. This invention particularly concerns the application of this device for regulating a flow of liquid metal at an outlet orifice located at the lower end of a receptacle containing this liquid metal [fr
Directory of Open Access Journals (Sweden)
Ludovic F. Dumée
2015-10-01
Full Text Available The formation of purely metallic meso-porous metal thin films by partial interface coalescence of self-assembled metal nano-particles across aqueous solutions of Pluronics triblock lyotropic liquid crystals is demonstrated for the first time. Small angle X-ray scattering was used to study the influence of the thin film composition and processing conditions on the ordered structures. The structural characteristics of the meso-structures formed demonstrated to primarily rely on the lyotropic liquid crystal properties while the nature of the metal nano-particles used as well as the their diameters were found to affect the ordered structure formation. The impact of the annealing temperature on the nano-particle coalescence and efficiency at removing the templating lyotropic liquid crystals was also analysed. It is demonstrated that the lyotropic liquid crystal is rendered slightly less thermally stable, upon mixing with metal nano-particles and that low annealing temperatures are sufficient to form purely metallic frameworks with average pore size distributions smaller than 500 nm and porosity around 45% with potential application in sensing, catalysis, nanoscale heat exchange, and molecular separation.
An overview of IPPE research on liquid metal fast reactor thermohydraulics
International Nuclear Information System (INIS)
Sorokin, A. P.; Efanov, A. D.; Zhukov, A. V.; Bogoslovskaia, G. P.
2003-01-01
The paper presents brief information on the most significant researches in the fields of liquid metal hydrodynamics and heat transfer performed in the State Scientific Center of Russian Federation 'Institute for Physics and Power Engineering' named after A.I.Leypunski applied to sodium-cooled fast reactors. Experimental methods for studying liquid metal thermohydraulics and applied measurement techniques are overviewed briefly in the paper. Some results of fundamental thermohydraulic investigations, such as quasi-universal character of velocity and temperature profile in liquid metals, if considered normally to the channel wall etc. are presented. Specific features of heat transfer in liquid metal cooled fuel subassembly are mentioned, among them there are: high level of coolant temperature; significant influence of an interchannel exchange on velocity and temperature distribution; an availability of contact thermal resistance; large azimuthal non-uniformity of velocity and temperature; 'conjugate' problem of heat transfer in combined geometry of fuel pin; an absence of stabilization of heat transfer in non-standard channels; an influence of non-uniform heat generation. Special attention is given to the temperature fields in fuel subassembly subjected to deformation because of radioactive swelling and creeping, as well as in case of blockage of a part of subassembly cross section. Some results of thermohydraulic investigation are demonstrated for intermediate heat exchangers, pressurized head collectors. Also the developed methods and codes of thermohydraulic calculations applied to fast reactor core are considered: subchannel approach, porous body model
Metal corrosion in a supercritical carbon dioxide - liquid sodium power cycle.
Energy Technology Data Exchange (ETDEWEB)
Moore, Robert Charles; Conboy, Thomas M.
2012-02-01
A liquid sodium cooled fast reactor coupled to a supercritical carbon dioxide Brayton power cycle is a promising combination for the next generation nuclear power production process. For optimum efficiency, a microchannel heat exchanger, constructed by diffusion bonding, can be used for heat transfer from the liquid sodium reactor coolant to the supercritical carbon dioxide. In this work, we have reviewed the literature on corrosion of metals in liquid sodium and carbon dioxide. The main conclusions are (1) pure, dry CO{sub 2} is virtually inert but can be highly corrosive in the presence of even ppm concentrations of water, (2) carburization and decarburization are very significant mechanism for corrosion in liquid sodium especially at high temperature and the mechanism is not well understood, and (3) very little information could be located on corrosion of diffusion bonded metals. Significantly more research is needed in all of these areas.
Graphite-based extinguishants for liquid metal fires
International Nuclear Information System (INIS)
Simpson, J.M.; Gardener, N.J.L.
1987-01-01
Effective extinguishants for liquid alkali metal fires must be provided for all LMFBRs. Traditional sodium salt based extinguishants have disadvantages. An intercalation compound of graphite was identified as a possible alternative. Following successful tests on fires of up to 25 m 2 area the graphite based extinguishant has been introduced by the UKAEA at Dounreay. (author)
Compact, Lightweight Electromagnetic Pump for Liquid Metal
Godfroy, Thomas; Palzin, Kurt
2010-01-01
A proposed direct-current electromagnetic pump for circulating a molten alkali metal alloy would be smaller and lighter and would demand less input power, relative to currently available pumps of this type. (Molten alkali metals are used as heat-transfer fluids in high-temperature stages of some nuclear reactors.) The principle of operation of this or any such pump involves exploitation of the electrical conductivity of the molten metal: An electric current is made to pass through the liquid metal along an axis perpendicular to the longitudinal axis of the flow channel, and a magnetic field perpendicular to both the longitudinal axis and the electric current is superimposed on the flowchannel region containing the electric current. The interaction between the electric current and the magnetic field produces the pumping force along the longitudinal axis. The advantages of the proposed pump over other such pumps would accrue from design features that address overlapping thermal and magnetic issues.
Consequence analysis of core meltdown accidents in liquid metal fast reactor
International Nuclear Information System (INIS)
Suk, S.D.; Hahn, D.
2001-01-01
Core disruptive accidents have been investigated at Korea Atomic Energy Research Institute(KAERI) as part of work to demonstrate the inherent and ultimate safety of the conceptual design of the Korea Advanced Liquid Metal Reactor(KALIMER), a 150 Mw pool-type sodium cooled prototype fast reactor that uses U-Pu-Zr metallic fuel. In this study, a simple method was developed using a modified Bethe-Tait method to simulate the kinetics and hydraulic behavior of a homogeneous spherical core over the period of the super-prompt critical power excursion induced by the ramp reactivity insertion. Calculations of energy release during excursions in the sodium-voided core of the KALIMER were subsequently performed using the method for various reactivity insertion rates up to 100 $/s, which has been widely considered to be the upper limit of ramp rates due to fuel compaction. Benchmark calculations were made to compare with the results of more detailed analysis for core meltdown energetics of the oxide fuelled fast reactor. A set of parametric studies was also performed to investigate the sensitivity of the results on the various thermodynamics and reactor parameters. (author)
Dual-plane ultrasound flow measurements in liquid metals
International Nuclear Information System (INIS)
Büttner, Lars; Nauber, Richard; Burger, Markus; Czarske, Jürgen; Räbiger, Dirk; Franke, Sven; Eckert, Sven
2013-01-01
An ultrasound measurement system for dual-plane, two-component flow velocity measurements especially in opaque liquids is presented. Present-day techniques for measuring local flow structures in opaque liquids disclose considerable drawbacks concerning line-wise measurement of single ultrasound probes. For studying time-varying flow patterns, conventional ultrasound techniques are either limited by time-consuming mechanical traversing or by the sequential operation of single probes. The measurement system presented within this paper employs four transducer arrays with a total of 100 single elements which allows for flow mapping without mechanical traversing. A high frame rate of several 10 Hz has been achieved due to an efficient parallelization scheme using time-division multiplexing realized by a microcontroller-based electronic switching matrix. The functionality and capability of the measurement system are demonstrated on a liquid metal flow at room temperature inside a cube driven by a rotating magnetic field (RMF). For the first time, the primary and the secondary flow have been studied in detail and simultaneously using a configuration with two crossed measurement planes. The experimental data confirm predictions made by numeric simulation. After a sudden switching on of the RMF, inertial oscillations of the secondary flow were observed by means of a time-resolved measurement with a frame rate of 3.4 Hz. The experiments demonstrate that the presented measurement system is able to investigate complex and transient flow structures in opaque liquids. Due to its ability to study the temporal evolution of local flow structures, the measurement system could provide considerable progress for fluid dynamics research, in particular for applications in the food industry or liquid metal technologies. (paper)
Dual-plane ultrasound flow measurements in liquid metals
Büttner, Lars; Nauber, Richard; Burger, Markus; Räbiger, Dirk; Franke, Sven; Eckert, Sven; Czarske, Jürgen
2013-05-01
An ultrasound measurement system for dual-plane, two-component flow velocity measurements especially in opaque liquids is presented. Present-day techniques for measuring local flow structures in opaque liquids disclose considerable drawbacks concerning line-wise measurement of single ultrasound probes. For studying time-varying flow patterns, conventional ultrasound techniques are either limited by time-consuming mechanical traversing or by the sequential operation of single probes. The measurement system presented within this paper employs four transducer arrays with a total of 100 single elements which allows for flow mapping without mechanical traversing. A high frame rate of several 10 Hz has been achieved due to an efficient parallelization scheme using time-division multiplexing realized by a microcontroller-based electronic switching matrix. The functionality and capability of the measurement system are demonstrated on a liquid metal flow at room temperature inside a cube driven by a rotating magnetic field (RMF). For the first time, the primary and the secondary flow have been studied in detail and simultaneously using a configuration with two crossed measurement planes. The experimental data confirm predictions made by numeric simulation. After a sudden switching on of the RMF, inertial oscillations of the secondary flow were observed by means of a time-resolved measurement with a frame rate of 3.4 Hz. The experiments demonstrate that the presented measurement system is able to investigate complex and transient flow structures in opaque liquids. Due to its ability to study the temporal evolution of local flow structures, the measurement system could provide considerable progress for fluid dynamics research, in particular for applications in the food industry or liquid metal technologies.
Seismic isolation development for the US advanced liquid-metal reactor program
International Nuclear Information System (INIS)
Gluekler, E.L.; Bigelow, C.C.; DeVita, V.; Kelly, J.M.; Seidensticker, R.W.; Tajirian, F.F.
1991-01-01
GE Nuclear Energy, in association with a US Industrial Team and support from the US National Laboratories and Universities, is developing a modular liquid-metal reactor concept for the US DOE. The objective of this development is to provide, by the turn of the century, a reactor with optimized passive safety features that is economically competitive with other domestic energy sources, licensable, and ready for commercial deployment. One of the unique features of the concept is the seismic isolation of the reactor modules which decouples the reactors and their safety systems from potentially damaging ground motions and significantly enhances the structural resistance to high energy, as well as long-duration earthquakes. Seismic isolation is accomplished with high-damping natural-rubber bearings. The reactors are located in individual silos below grade level and are supported by the isolator bearings at approximately their center of gravity. This application of seismic isolation is the first for a US nuclear power plant. A development program has been established to assure the full benefits from the utilization of this new approach and to provide adequate system characterization and qualification for licensing certification. The development program, which is supported by the US DOE, ANL, Energy Technology Engineering Center (ETEC), the University of California at Berkeley (UC-Berkeley), GE, and Bechtel National, Inc. (BNI), is described and selected results are presented. The initial testing indicated excellent performance of high-damping natural-rubber bearings. The development of seismic isolation guidelines is in progress as a joint activity between ENEA of Italy and the GE Team. (orig./HP)
Feasible homopolar dynamo with sliding liquid-metal contacts
Priede, Jānis; Avalos-Zúñiga, Raúl
2013-01-01
We present a feasible homopolar dynamo design consisting of a flat, multi-arm spiral coil, which is placed above a fast-spinning metal ring and connected to the latter by sliding liquid-metal electrical contacts. Using a simple, analytically solvable axisymmetric model, we determine the optimal design of such a setup. For small contact resistance, the lowest magnetic Reynolds number, Rm~34.6, at which the dynamo can work, is attained at the optimal ratio of the outer and inner radii of the ri...
Study of MHD problems in liquid metal blankets of fusion reactors
International Nuclear Information System (INIS)
Michael, I.
1984-12-01
This study describes in a concise form the state of knowledge regarding MHD problems to be expected in case of use of liquid metal in the blankets of fusion reactors with magnetic confinement. MHD pressure losses and MHD friction coefficients in the straight channel, in bent sections and in case of variation of the channel cross section play a major role because the high MHD flow resistances call for high pumping powers. Influencing the velocity profile transverse to the main flow direction of the liquid metal by application of an external, strong magnetic field bears consequences on the release and transport of corrosion products in the liquid metal circuit and on the heat transfer. Possibilities of reducing the MHD effects are discussed. However, it becomes obvious that an account of the lack of experimental results there are still major gaps in the knowledge of MHD effects occurring in strong magnetic fields. These gaps can be greatly reduced by implementation of an experimental program as proposed in this report. (orig.) [de
Improvements in liquid metal cooled nuclear reactors
International Nuclear Information System (INIS)
Barnes, S.
1980-01-01
A concrete containment vault for a liquid metal cooled nuclear reactor is described which is lined with thermal insulation to protect the vault against heat radiated from the reactor during normal operation of the reactor but whose efficiency of heat insulation is reduced in an emergency to enable excessive heat from the reactor to be dissipated through the vault. (UK)
Pseudoclassical approach to electron and ion density correlations in simple liquid metals
International Nuclear Information System (INIS)
Vericat, F.; Tosi, M.P.; Pastore, G.
1986-04-01
Electron-electron and electron-ion structural correlations in simple liquid metals are treated by using effective pair potentials to incorporate quantal effects into a pseudoclassical description of the electron fluid. An effective pair potential between simultaneous electron density fluctuations is first constructed from known properties of the degenerate jellium model, which are the plasmon sum rule, the Kimball-Niklasson relation and Yasuhara's values of the electron pair distribution function at contact. An analytic expression is thereby obtained in the Debye-Hueckel approximation for the electronic structure factor in jellium over a range of density appropriate to metals, with results which compare favourably with those of fully quantal evaluations. A simple pseudoclassical model is then set up for a liquid metal: this involves a model of charged hard spheres for the ion-ion potential and an empty core model for the electron-ion potential, the Coulombic tails being scaled as required by the relation between the long-wavelength partial structure factors and the isothermal compressibility of the metal. The model is solved analytically by a pseudoclassical linear response treatment of the electron-ion coupling and numerical results are reported for partial structure factors in liquid sodium and liquid beryllium. Contact is made for the latter system with data on the electron-electron structure factor in the crystal from inelastic X-ray scattering experiments of Eisenberger, Marra and Brown. (author)
Alloying of Yb-Cu and Yb-Ag utilizing liquid ammonia metal solutions of ytterbium
International Nuclear Information System (INIS)
Imamura, H.; Yoshimura, T.; Sakata, Y.
2003-01-01
In the course of the studies on preparation of novel compounds using the dissolution of Eu or Yb metals in liquid ammonia, the formation of Yb-Cu and Yb-Ag intermetallic films has been found. When Cu or Ag metal powders were placed in a reactor containing a solution of Yb metal in liquid ammonia, the dissolved Yb readily react with the Cu or Ag metal particles to form surface alloy compounds. X-ray diffraction of Yb-Cu showed that upon thermal treatment above 673 K, the Yb metal deposited on the Cu particles reacted together to be transformed into the YbCu 6.5 intermetallic compound. A characteristic endothermic peak at 749 K, due to alloying of Yb-Cu, was observed by the differential scanning calorimeter measurements. By use of the high reactivity of liquid ammonia metal solutions of ytterbium, it was found that the ytterbium intermetallic films were readily formed under mild conditions. Yb-Cu and Yb-Ag exhibited enhanced catalytic activity for the hydrogenation of ethene as a result of alloying
Acoustical study of electro- and thermal conductivity of liquid metals
International Nuclear Information System (INIS)
Tekuchev, V.V.; Rygalov, L.N.; Ivanova, I.V.; Barashkov, B.I.
2003-01-01
One established a link between electrical, elastic and structural properties of electronic smelts. One calculated polyterms of resistance and thermal conductivity of liquid metals (Be, Cd, U, V, Mo, Cr, rare-earth metals) on the basis of data covering both melting and boiling points. For some metals the values were obtained for the first time. To analyze kinetic properties of metals under high temperatures one should apply complex many-particles model representations and efficient computing equipment. It is pointed out that essential problems blocking efforts to tackle the mentioned task result in necessity to find simple though approximate models describing satisfactorily properties of metals [ru
Molecular dynamics simulation of self-diffusion coefficients for liquid metals
International Nuclear Information System (INIS)
Ju Yuan-Yuan; Zhang Qing-Ming; Gong Zi-Zheng; Ji Guang-Fu
2013-01-01
The temperature-dependent coefficients of self-diffusion for liquid metals are simulated by molecular dynamics methods based on the embedded-atom-method (EAM) potential function. The simulated results show that a good inverse linear relation exists between the natural logarithm of self-diffusion coefficients and temperature, though the results in the literature vary somewhat, due to the employment of different potential functions. The estimated activation energy of liquid metals obtained by fitting the Arrhenius formula is close to the experimental data. The temperature-dependent shear-viscosities obtained from the Stokes—Einstein relation in conjunction with the results of molecular dynamics simulation are generally consistent with other values in the literature. (atomic and molecular physics)
Liquid metal reactor core material HT9
International Nuclear Information System (INIS)
Kim, S. H.; Kuk, I. H.; Ryu, W. S. and others
1998-03-01
A state-of-the art is surveyed on the liquid metal reactor core materials HT9. The purpose of this report is to give an insight for choosing and developing the materials to be applied to the KAERI prototype liquid metal reactor which is planned for the year of 2010. In-core stability of cladding materials is important to the extension of fuel burnup. Austenitic stainless steel (AISI 316) has been used as core material in the early LMR due to the good mechanical properties at high temperatures, but it has been found to show a poor swelling resistance. So many efforts have been made to solve this problem that HT9 have been developed. HT9 is 12Cr-1MoVW steel. The microstructure of HT9 consisted of tempered martensite with dispersed carbide. HT9 has superior irradiation swelling resistance as other BCC metals, and good sodium compatibility. HT9 has also a good irradiation creep properties below 500 dg C, but irradiation creep properties are degraded above 500 dg C. Researches are currently in progress to modify the HT9 in order to improve the irradiation creep properties above 500 dg C. New design studies for decreasing the core temperature below 500 dg C are needed to use HT9 as a core material. On the contrary, decrease of the thermal efficiency may occur due to lower-down of the operation temperature. (author). 51 refs., 6 tabs., 19 figs
An Electrochemical Investigation of the Chemical Diffusivity in Liquid Metal Alloys
Barriga, Salvador A.
The liquid metal battery has been shown to be a viable candidate for grid-scale energy storage, due to its fast kinetics and ability to be constructed from economically feasible materials. Various of the liquid metal couples that form high stable voltages, such as the calcium chemistries, are rate limited because they tend to form solid intermetallic compounds with high melting points. In order to understand and better engineer these batteries, the kinetic properties of these liquid alloys, in particular the chemical diffusivity, must be known accurately so that it can be used as input in computational simulations to avoid the nucleation of any solids. Unfortunately, the dominant experimental methods for measuring diffusion in liquid metals today are unreliable because the measurement timescales are on the order of days, require long capillaries susceptible to buoyancy-driven flow from temperature fluctuations, and composition analysis must be done ex-situ as a solid. To counter all these problems, a new and novel method for measuring the chemical diffusivity of metals in liquid alloys derived from electrochemical principles is presented in this thesis. This new method has the advantage of operating in shorter times scales of minutes rather than days, and requires the use of small capillaries which collectively minimize the effect of convectively-driven flow caused from temperature gradients. This new method was derived by solving the same boundary conditions required by the galvanostatic intermittent titration technique for solid-state electrodes. To verify the validity of the new theoretical derivation, the method was used to measure the chemical diffusivity of calcium in liquid bismuth within the temperature range of 550 - 700 °C using a three-electrode setup with a ternary molten salt electrolyte. Three compositions where studied (5% Ca-Bi, 10% Ca-Bi, and 15% Ca-Bi) for comparison. The chemical diffusion coefficient was found to range between (6.77 +/- 0.21)x
Liquid metals replace water steam
International Nuclear Information System (INIS)
Kozlov, V.
1976-01-01
The techniques are described of power generation with regard to their effectiveness which depends on the efficiency of the conversion of thermal energy into electric energy. The magnetohydrodynamic conversion of energy is based on the use of induced electromotive force which results from the movement of the conductor in the magnetic field. The use of liquid metal as the working medium makes it possible to increase the initial temperature of the magnetohydrodynamic cycle to the limit of the highest technically attainable temperatures. The total efficiency of energy conversion in magnetohydrodynamic converters is 2 to 6%. (J.B.)
Ionic Liquid/Metal-Organic Framework Composites: From Synthesis to Applications.
Kinik, Fatma Pelin; Uzun, Alper; Keskin, Seda
2017-07-21
Metal-organic frameworks (MOFs) have been widely studied for different applications owing to their fascinating properties such as large surface areas, high porosities, tunable pore sizes, and acceptable thermal and chemical stabilities. Ionic liquids (ILs) have been recently incorporated into the pores of MOFs as cavity occupants to change the physicochemical properties and gas affinities of MOFs. Several recent studies have shown that IL/MOF composites show superior performances compared with pristine MOFs in various fields, such as gas storage, adsorption and membrane-based gas separation, catalysis, and ionic conductivity. In this review, we address the recent advances in syntheses of IL/MOF composites and provide a comprehensive overview of their applications. Opportunities and challenges of using IL/MOF composites in many applications are reviewed and the requirements for the utilization of these composite materials in real industrial processes are discussed to define the future directions in this field. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Dispersion relations of the acoustic modes in divalent liquid metals
Directory of Open Access Journals (Sweden)
Inui Masanori
2017-01-01
Full Text Available Collective dynamics in liquid Ca and liquid Cd was studied by inelastic x-ray scattering (IXS. Using our experimental technique to prepare proper sample cells and high performance of an IXS beamline (BL35XU at SPring-8 in Japan, the dynamic structure factor with reasonable statistics was obtained for these divalent liquid metals. For both liquids, the dynamic structure factor at low Q exhibits a central peak with a shoulder or small hump clearly visible on each side, and the inelastic excitation energy determined using the model function composed of Lorentzian and the damped harmonic oscillator function disperses with increasing Q. The dispersion curves of these liquids were compared with that of the longitudinal acoustic phonon in each crystalline phase. From these results, clear difference in the interatomic interaction be- tween liquid Ca and liquid Cd was inferred.
Separation of some metal ions using coupled transport supported liquid membranes
International Nuclear Information System (INIS)
Chaudhary, M.A.
1993-01-01
Liquid membrane extraction processes has become very popular due to their superiority in many ways over other separation techniques. In coupled transport membranes the metal ions can be transported across the membrane against their concentration gradient under the influence of chemical potential difference. Liquid membranes consisting of a carrier-cum-diluent, supported in microporous polymeric hydrophobic films have been studied for transport of metal ions like U(VI), Cr(VI), Be(II), V(V), Ti(IV), Zn(II), Cd(II), Hf(IV), W(VI), and Co(II). The present paper presents basic data with respect to flux and permeabilities of these metal ions across membranes based on experimental results and theoretical equations, using different carriers and diluents and provides a brief reference to possibility of such membranes for large scale applications. (author)
The questions of liquid metal two-phase flow modelling in the FBR core channels
International Nuclear Information System (INIS)
Martsiniouk, D.Ye.; Sorokin, A.P.
2000-01-01
The two-fluid model representation for calculations of two-phase flow characteristics in the FBR fuel pin bundles with liquid metal cooling is presented and analysed. Two conservation equations systems of the mass, momentum and energy have been written for each phase. Components accounted the mass-, momentum- and heat transfer throughout the interface occur in the macro-field equations after the averaging procedure realisation. The pattern map and correlations for two-fluid model in vertical liquid metal flows are presented. The description of processes interphase mass- and heat exchange and interphase friction is determined by the two-phase flow regime. The opportunity of the liquid metal two-phase flow regime definition is analysed. (author)
Corrosion experiment in the first liquid metal LiPb loop of China
International Nuclear Information System (INIS)
Huang Qunying; Zhang Maolian; Zhu Zhiqiang; Gao Sheng; Wu Yican; Li Yanfen; Song Yong; Li Chunjing; Kong Mingguang
2007-01-01
The liquid metal LiPb blanket design is one of the most promising designs for future fusion power reactors and under wide research in the world. The first liquid metal LiPb loop in China named DRAGON-I was built in 2005 in order to do research on characteristics of liquid metal LiPb such as its corrosion to structural materials of the blankets and so on. The first corrosion experiment in flowing LiPb with a speed of 0.08 m/s at 480 deg. C for 500 h was done in October 2005 on CLAM (China low activation martensitic) steel and 316L stainless steel for comparison. The weights and compositions, etc. of the specimens before and after corrosion experiment were tested and analyzed, the microstructures of the specimens were also inspected by SEM. The results show that the corrosion of CLAM steel is relatively slight, while that for 316L is obvious and very serious. Further study on corrosion behavior of CLAM for longer time experiment in liquid LiPb at different temperatures and flow speeds will be carried out in the near future
International Nuclear Information System (INIS)
Fan, Li-Wu; Wu, Yu-Yue; Xiao, Yu-Qi; Zeng, Yi; Zhang, Yi-Ling; Yu, Zi-Tao
2016-01-01
Highlights: • A liquid metal is adopted as the PCM in a thermal energy storage-based heat sink. • Transient performance of the heat sink is tested in comparison to an organic PCM. • The liquid metal has a similar volumetric latent heat of fusion to the organic PCM. • Outperformance of the liquid metal is found due to its higher thermal conductivity. • Liquid metals are preferred when the system weight is less important than volume. - Abstract: In this Technical Note, the use of a liquid metal, i.e., a low melting point Pb–Sn–In–Bi alloy, as the phase change material (PCM) in thermal energy storage-based heat sinks is tested in comparison to an organic PCM (1-octadecanol) having a similar melting point of ∼60 °C. The thermophysical properties of the two types of PCM are characterized, revealing that the liquid metal is much more conductive while both have nearly identical volumetric latent heat of fusion (∼215 MJ/m"3). By using at the same volume of 80 mL, i.e., the same energy storage capacity, the liquid metal is shown to outperform significantly over the organic PCM under the various heating powers up to 105.3 W/cm"2. During the heating period, the use of the liquid metal leads to a remarkable extension of the effective protection time to nearly twice longer as well as a reduction of the highest overheating temperature by up to 50 °C. The cool-down period can also be shortened significantly by taking advantage of the much higher thermal conductivity of the liquid metal. These findings suggest that liquid metals could serve as a promising PCM candidate for particular applications where the volume limit is very rigorous and the penalty in weight increment is acceptable.
Advanced fuels safety comparisons
International Nuclear Information System (INIS)
Grolmes, M.A.
1977-01-01
The safety considerations of advanced fuels are described relative to the present understanding of the safety of oxide fueled Liquid Metal Fast Breeder Reactors (LMFBR). Safety considerations important for the successful implementation of advanced fueled reactors must early on focus on the accident energetics issues of fuel coolant interactions and recriticality associated with core disruptive accidents. It is in these areas where the thermal physical property differences of the advanced fuel have the greatest significance
Association of solvent extraction and liquid-liquid flotation processes for metal recovery
International Nuclear Information System (INIS)
Puget, Flavia P.; Mendonca, Luciano A. de; Massarani, Giulio
2000-01-01
From the batch solvent extraction process, in this work it has been carried out a preliminary study aiming the determination of the optimal operating conditions for zirconium recovery (10 ppm) using alamine 336 (tricaprylylamine) as extractor. The results have shown that the extraction takes place instantaneously (5s of manual agitation) and that at pH around 2.0 the extraction efficiency is up to 98-99% for an aqueous/organic phase volumetric ratio of 10. Based on these results, it is proposed to evaluate the possibility of using of a pioneering technology for metal recovery at low concentrations, using a experimental set-up that associates standard solvent extraction process with liquid-liquid flotation process. (author)
High pressure gas driven liquid metal MHD homopolar generator
International Nuclear Information System (INIS)
Itoh, Yasuyuki
1988-01-01
A liquid metal MHD homopolar generator is proposed to be used as a high repetition rate pulsed power supply. In the generator, the thermal energy stored in a high pressure gas (He) reservoir is rapidly converted into kinetic energy of a rotating liquid metal (NaK) cylinder which is contracted by a gas driven annular free piston. The rotational kinetic energy is converted into electrical energy by making use of the homopolar generator principle. The conversion efficiency is calculated to be 47% in generating electrical energy of 20 kJ/pulse (1.7 MW peak power) at a repetition rate of 7 Hz. From the viewpoint of energy storage, the high pressure gas reservoir with a charging pressure of 15 MPa is considered to ''electrically'' store the energy at a density of 10 MJ/m 3 . (author)
Production of Liquid Metal Spheres by Molding
Directory of Open Access Journals (Sweden)
Mohammed G. Mohammed
2014-10-01
Full Text Available This paper demonstrates a molding technique for producing spheres composed of eutectic gallium-indium (EGaIn with diameters ranging from hundreds of microns to a couple millimeters. The technique starts by spreading EGaIn across an elastomeric sheet featuring cylindrical reservoirs defined by replica molding. The metal flows into these features during spreading. The spontaneous formation of a thin oxide layer on the liquid metal keeps the metal flush inside these reservoirs. Subsequent exposure to acid removes the oxide and causes the metal to bead up into a sphere with a size dictated by the volume of the reservoirs. This technique allows for the production and patterning of droplets with a wide range of volumes, from tens of nanoliters up to a few microliters. EGaIn spheres can be embedded or encased subsequently in polymer matrices using this technique. These spheres may be useful as solder bumps, electrodes, thermal contacts or components in microfluidic devices (valves, switches, pumps. The ease of parallel-processing and the ability to control the location of the droplets during their formation distinguishes this technique.
Conventional and advanced liquid biofuels
Directory of Open Access Journals (Sweden)
Đurišić-Mladenović Nataša L.
2016-01-01
Full Text Available Energy security and independence, increase and fluctuation of the oil price, fossil fuel resources depletion and global climate change are some of the greatest challanges facing societies today and in incoming decades. Sustainable economic and industrial growth of every country and the world in general requires safe and renewable resources of energy. It has been expected that re-arrangement of economies towards biofuels would mitigate at least partially problems arised from fossil fuel consumption and create more sustainable development. Of the renewable energy sources, bioenergy draws major and particular development endeavors, primarily due to the extensive availability of biomass, already-existence of biomass production technologies and infrastructure, and biomass being the sole feedstock for liquid fuels. The evolution of biofuels is classified into four generations (from 1st to 4th in accordance to the feedstock origin; if the technologies of feedstock processing are taken into account, than there are two classes of biofuels - conventional and advanced. The conventional biofuels, also known as the 1st generation biofuels, are those produced currently in large quantities using well known, commercially-practiced technologies. The major feedstocks for these biofuels are cereals or oleaginous plants, used also in the food or feed production. Thus, viability of the 1st generation biofuels is questionable due to the conflict with food supply and high feedstocks’ cost. This limitation favoured the search for non-edible biomass for the production of the advanced biofuels. In a general and comparative way, this paper discusses about various definitions of biomass, classification of biofuels, and brief overview of the biomass conversion routes to liquid biofuels depending on the main constituents of the biomass. Liquid biofuels covered by this paper are those compatible with existing infrastructure for gasoline and diesel and ready to be used in
Numerical issues for liquid-metal boiling transient analysis
International Nuclear Information System (INIS)
Rowe, D.S.
1986-01-01
The large liquid-to-vapor density ratio of a boiling liquid-metal leads to a very abrupt change of the two-phase mixture density at the inception of boiling. Unfortunately, the strong dependence of mixture density on pressure leads to a key numerical issue that adversely affects the behavior of numerical solutions. The difficulties can be reduced by using techniques that acknowledge this functional behavior at the start of boiling. Some of the methods used include a spatially averaged density function, mathematical smoothing, and under relaxation. Nonequilibrium two-fluid models also seem to offer aid in obtaining reliable numerical solutions. (author)
Limets 2: a hot-cell test set-up for Liquid Metal Embrittlement (LME) studies in liquid lead alloys
International Nuclear Information System (INIS)
Van den Bosch, J.; Bosch, R.W.; Al Mazouzi, A.
2008-01-01
Full text of publication follows. In the nuclear energy sector one of the main candidate designs for the accelerator driven system (ADS) uses liquid lead or lead bismuth eutectic both as a coolant and as spallation target. In the fusion community liquid lead lithium eutectic is considered as a possible coolant for the blanket and as a tritium source. Therefore the candidate materials for such structural components should not only comply with the operating conditions but in addition need to guarantee chemical and physical integrity when coming into contact with the lead alloys. The latter phenomena can be manifested in terms of erosion/corrosion. and/or of the so called liquid metal embrittlement (LME). Thus the susceptibility to LME of the structural materials under consideration to be used in such applications should be investigated in contact with the various lead alloys. LME, if occurring in any solid metal/liquid meta] couple, is likely to increase with irradiation hardening as localised stresses and crack initiations can promote it. To investigate the mechanical response of irradiated materials in contact with a liquid metal under representative conditions, a dedicated testing facility has recently been developed and built at our centre. It consists of an instrumented hot cell. equipped with a testing machine that allows mechanical testing of active materials in contact with active liquid lead lithium and liquid lead bismuth under well controlled chemistry conditions. The specificity of the installation is to handle highly activated and contaminated samples. Also a dedicated dismantling set-up has been developed that allows to retrieve the samples from the irradiation rig without any supplementary damage. In this presentation we will focus on the technical design of this new installation, its special features that have been developed to allow testing in a hot environment and the modifications and actions that have been taken to allow testing in liquid lead
Liquid-solid extraction of cationic metals by cationic amphiphiles
International Nuclear Information System (INIS)
Muller, W.
2010-01-01
In the field of selective separation for recycling of spent nuclear fuel, liquid-liquid extraction processes are widely used (PUREX, DIAMEX..) in industrial scale. In order to guarantee a sustainable nuclear energy for the forthcoming generations, alternative reprocessing techniques are under development. One of them bases on the studies from Heckmann et al in the 80's and consists in selectively precipitating actinides from aqueous waste solutions by cationic surfactants (liquid-solid extraction). This technique has some interesting advantages over liquid-liquid extraction techniques, because several steps are omitted like stripping or solvent washing. Moreover, the amount of waste is decreased considerably, since no contaminated organic solvent is produced. In this thesis, we have carried out a physico-chemical study to understand the specific interactions between the metallic cations with the cationic surfactant. First, we have analysed the specific effect of the different counter-ions (Cl - , NO 3 - , C 2 O 4 2- ) and then the effect of alkaline cations on the structural properties of the surfactant aggregation in varying thermodynamical conditions. Finally, different multivalent cations (Cu 2+ , Zn 2+ , UO 2 2+ , Fe 3+ , Nd 3+ , Eu 3+ , Th 4+ ) were considered; we have concluded that depending on the anionic complex of these metals formed in acidic media, we can observe either an adsorption at the micellar interface or not. This adsorption has a large influence of the surfactant aggregation properties and determines the limits of the application in term of ionic strength, temperature and surfactant concentration. (author) [fr
Liquid state properties of certain noble and transition metals
International Nuclear Information System (INIS)
Bhuiyan, G.M.; Rahman, A.; Khaleque, M.A.; Rashid, R.I.M.A.; Mujibur Rahman, S.M.
1998-07-01
Certain structural, thermodynamic and atomic transport properties of a number of liquid noble and transition metals are reported. The underlying theory combines together a simple form of the N-body potential and the thermodynamically self-consistent variational modified hypernetted chain (VMHNC) theory of liquid. The static structure factors calculated by using the VMHNC resemble the hard sphere (HS) values. Consequently the HS model is used to calculate the thermodynamic properties viz. specific heat, entropy, isothermal compressibility and atomic transport properties. (author)
Advances in Metal Supported Cells in the METSOFC EU Consortium
DEFF Research Database (Denmark)
McKenna, Brandon J.; Christiansen, Niels; Schauperl, Richard
2012-01-01
Employing a mechanically robust metal support as the structural element in SOFC has been the objective of various development efforts. The EU-sponsored project “METSOFC”, completed at the end of 2011, resulted in a number of advancements towards implementing this strategy. These include robust me...... outcomes of the METSOFC consortium are covered, along with associated work supported by the Danish National Advanced Technology Foundation.......Employing a mechanically robust metal support as the structural element in SOFC has been the objective of various development efforts. The EU-sponsored project “METSOFC”, completed at the end of 2011, resulted in a number of advancements towards implementing this strategy. These include robust...... metal supported cells (MSCs) having low ASR at low temperature, incorporation into small stacks of powers approaching ½kW, and stack tolerance to various operation cycles. DTU Energy Conversion's (formerly Risø DTU) research into planar MSCs has produced an advanced cell design with high performance...
The effect of advanced treatment of sewage effluents on metal speciation and (bio)availability.
Peters, A; Merrington, G; Leverett, D; Ellor, B; Lofts, S; Gravell, A
2014-02-01
The bioavailability of metals can be strongly influenced by dissolved organic carbon (DOC). Wastewater treatment effluents add considerable quantities of DOC and metals to receiving waters, and as effluent controls become more stringent advanced effluent treatments may be needed. We assessed the effects of two types of advanced treatment processes on metal availability in wastewater effluents. Trace metal availability was assessed using diffuse gradients in thin films and predicted through speciation modelling. The results show little difference in metal availability post-advanced treatment. EDTA-like compounds are important metal complexants in the effluents.
Structural properties of low-density liquid alkali metals
Indian Academy of Sciences (India)
The static structure factors of liquid alkali metals have been modelled at temperatures close to their melting points and a few higher temperatures using the reverse Monte Carlo (RMC) method. The positions of 5000 atoms in a box, with full periodicity, were altered until the experimental diffraction data of the structure factor ...
Liquid Metal Oscillation and Arc Behaviour during Welding
Yudodibroto, B.Y.B.
2010-01-01
The purpose of this research is to obtain insight into the oscillation behaviour of the liquid metal and the arc behaviour during GMA welding. Observations of the weld pool and the arc were undertaken by visual means using a high-speed video and by analysis of the voltage. To deal with the complex
Investigation of heat transfer in liquid-metal flows under fusion-reactor conditions
Energy Technology Data Exchange (ETDEWEB)
Poddubnyi, I. I., E-mail: poddubnyyii@nikiet.ru [Joint Stock Company Dollezhal Research and Development Institute of Power Engineering (JSC NIKIET) (Russian Federation); Pyatnitskaya, N. Yu.; Razuvanov, N. G.; Sviridov, V. G.; Sviridov, E. V. [Russian Academy of Science, Joint Institute of High Temperatures (Russian Federation); Leshukov, A. Yu. [Joint Stock Company Dollezhal Research and Development Institute of Power Engineering (JSC NIKIET) (Russian Federation); Aleskovskiy, K. V. [National Research University Moscow Power Engineering Institute (MPEI) (Russian Federation); Obukhov, D. M. [Joint Stock Company Efremov Institute of Electrophysical Apparatus (Russian Federation)
2016-12-15
The effect discovered in studying a downward liquid-metal flow in vertical pipe and in a channel of rectangular cross section in, respectively, a transverse and a coplanar magnetic field is analyzed. In test blanket modules (TBM), which are prototypes of a blanket for a demonstration fusion reactor (DEMO) and which are intended for experimental investigations at the International Thermonuclear Experimental Reactor (ITER), liquid metals are assumed to fulfil simultaneously the functions of (i) a tritium breeder, (ii) a coolant, and (iii) neutron moderator and multiplier. This approach to testing experimentally design solutions is motivated by plans to employ, in the majority of the currently developed DEMO blanket projects, liquid metals pumped through pipes and/or rectangular channels in a transvers magnetic field. At the present time, experiments that would directly simulate liquid-metal flows under conditions of ITER TBM and/or DEMO blanket operation (irradiation with thermonuclear neutrons, a cyclic temperature regime, and a magnetic-field strength of about 4 to 10 T) are not implementable for want of equipment that could reproduce simultaneously the aforementioned effects exerted by thermonuclear plasmas. This is the reason why use is made of an iterative approach to experimentally estimating the performance of design solutions for liquid-metal channels via simulating one or simultaneously two of the aforementioned factors. Therefore, the investigations reported in the present article are of considerable topical interest. The respective experiments were performed on the basis of the mercury magneto hydrodynamic (MHD) loop that is included in the structure of the MPEI—JIHT MHD experimental facility. Temperature fields were measured under conditions of two- and one-sided heating, and data on averaged-temperature fields, distributions of the wall temperature, and statistical fluctuation features were obtained. A substantial effect of counter thermo gravitational
Directory of Open Access Journals (Sweden)
Adolfo Ribeiro
2015-03-01
Full Text Available Planets and stars are often capable of generating their own magnetic fields. This occurs through dynamo processes occurring via turbulent convective stirring of their respective molten metal-rich cores and plasma-based convection zones. Present-day numerical models of planetary and stellar dynamo action are not carried out using fluids properties that mimic the essential properties of liquid metals and plasmas (e.g., using fluids with thermal Prandtl numbers Pr < 1 and magnetic Prandtl numbers Pm ≪ 1. Metal dynamo simulations should become possible, though, within the next decade. In order then to understand the turbulent convection phenomena occurring in geophysical or astrophysical fluids and next-generation numerical models thereof, we present here canonical, end-member examples of thermally-driven convection in liquid gallium, first with no magnetic field or rotation present, then with the inclusion of a background magnetic field and then in a rotating system (without an imposed magnetic field. In doing so, we demonstrate the essential behaviors of convecting liquid metals that are necessary for building, as well as benchmarking, accurate, robust models of magnetohydrodynamic processes in Pm ≪ Pr < 1 geophysical and astrophysical systems. Our study results also show strong agreement between laboratory and numerical experiments, demonstrating that high resolution numerical simulations can be made capable of modeling the liquid metal convective turbulence needed in accurate next-generation dynamo models.
Experience on the removal of impurities from liquid metal systems by cold-trapping
Energy Technology Data Exchange (ETDEWEB)
Bray, J. A.
1963-10-15
Experience in impurity removal by cold-trapping, which was obtained on DFR and its associated liquid metal rigs, is reviewed. The development of the present DFR cold-trapping system is outlined, and the operation of the additional pumped loops, which were required in order to control the reactor impurity levels, are described. Operation of the liquid metal rigs ancillary to the reactor project is discussed with particular reference to the control of impurity levels. (auth)
NATO Advanced Study Institute on Metal Hydrides
1981-01-01
In the last five years, the study of metal hydrides has ex panded enormously due to the potential technological importance of this class of materials in hydrogen based energy conversion schemes. The scope of this activity has been worldwide among the industrially advanced nations. There has been a consensus among researchers in both fundamental and applied areas that a more basic understanding of the properties of metal/hydrogen syster;,s is required in order to provide a rational basis for the selection of materials for specific applications. The current worldwide need for and interest in research in metal hydrides indicated the timeliness of an Advanced Study Insti tute to provide an in-depth view of the field for those active in its various aspects. The inclusion of speakers from non-NATO coun tries provided the opportunity for cross-fertilization of ideas for future research. While the emphasis of the Institute was on basic properties, there was a conscious effort to stimulate interest in the applic...
Lu, Yingying; Das, Shyamal K.; Moganty, Surya S.; Archer, Lynden A.
2012-01-01
Ionic liquid-tethered nanoparticle hybrid electrolytes comprised of silica nanoparticles densely grafted with imidazolium-based ionic liquid chains are shown to retard lithium dendrite growth in rechargeable batteries with metallic lithium anodes
Conductor of high electrical current at high temperature in oxygen and liquid metal environment
Powell, IV, Adam Clayton; Pati, Soobhankar; Derezinski, Stephen Joseph; Lau, Garrett; Pal, Uday B.; Guan, Xiaofei; Gopalan, Srikanth
2016-01-12
In one aspect, the present invention is directed to apparatuses for and methods of conducting electrical current in an oxygen and liquid metal environment. In another aspect, the invention relates to methods for production of metals from their oxides comprising providing a cathode in electrical contact with a molten electrolyte, providing a liquid metal anode separated from the cathode and the molten electrolyte by a solid oxygen ion conducting membrane, providing a current collector at the anode, and establishing a potential between the cathode and the anode.
International Nuclear Information System (INIS)
Sackett, J.I.
1983-01-01
This lecture considers instrumentation for liquid-metal-cooled fast breeder reactors (LMFBR's). Included is instrumentation to measure sodium flow, pressure, temperature, acoustic noise, and sodium purity. It is divided into three major parts: (1) measurement requirements for sodium cooled reactor systems, (2) in-core and out-of-core measurements in liquid metal systems, and (3) performance measurements of water steam generators
Metal Advanced Manufacturing Bot-Assisted Assembly (MAMBA) Process, Phase I
National Aeronautics and Space Administration — Tethers Unlimited, Inc. (TUI) proposes to develop the Metal Advanced Manufacturing Bot-Assisted Assembly (MAMBA) Process, a robotically managed metal press and...
Precious-metal-base advanced materials
International Nuclear Information System (INIS)
Nowicki, T.; Carbonnaux, C.
1993-01-01
Precious metals constitute also the base of several advanced materials used in the industry in hundreds of metric tons. Platinum alloys have been used as structural materials for equipments in the glass industry. The essential reason for this is the excellent resistance of platinum alloys to oxidation and electrolytical corrosion in molten glasses at temperatures as high as 1200-1500 C. The major drawback is a weak creep resistance. The unique way for significant improvement of platinum base materials creep resistance is a strengthening by an oxide dispersion (ODS). In the case of CLAL's patented ''Plativer'' materials, 0.05 wt% of Y 2 O 3 is incorporated within the alloy matrix by the flame spraying process. Further improvement of platinum base materials is related, in the authors opinion, to the development of precious metals base intermetallics. Another interesting applications of precious metals are silver base electrical contacts. They are in fact silver matrix composites containing varying amounts of well-dispersed particles of constituents such as CdO, SnO 2 , Ni, WC or C. In the case of such materials, particular properties are required and tested : resistance to arc erosion, resistance to welding and contact resistance. Many other technically fascinating precious metals base materials exist: brazing alloys for assembling metals, superconductors and ceramics; dental materials including magnetic biocompatible alloys; silver composites for superconductor wire jackets. The observation of current evolution indicates very clearly that precious metals cannot be replaced by common metals because of their unique characteristics due to their atomic level properties
Thermal bonding of light water reactor fuel using nonalkaline liquid-metal alloy
International Nuclear Information System (INIS)
Wright, R.F.; Tulenko, J.S.; Schoessow, G.J.; Connell, R.G. Jr.; Dubecky, M.A.; Adams, T.
1996-01-01
Light water reactor (LWR) fuel performance is limited by thermal and mechanical constraints associated with the design, fabrication, and operation of fuel in a nuclear reactor. A technique is explored that extends fuel performance by thermally bonding LWR fuel with a nonalkaline liquid-metal alloy. Current LWR fuel rod designs consist of enriched uranium oxide fuel pellets enclosed in a zirconium alloy cylindrical clad. The space between the pellets and the clad is filled by an inert gas. Because of the low thermal conductivity of the gas, the gas space thermally insulates the fuel pellets from the reactor coolant outside the fuel rod, elevating the fuel temperatures. Filling the gap between the fuel and clad with a high-conductivity liquid metal thermally bonds the fuel to the cladding and eliminates the large temperature change across the gap while preserving the expansion and pellet-loading capabilities. The application of liquid-bonding techniques to LWR fuel is explored to increase LWR fuel performance and safety. A modified version of the ESCORE fuel performance code (ESBOND) is developed to analyze the in-reactor performance of the liquid-metal-bonded fuel. An assessment of the technical feasibility of this concept for LWR fuel is presented, including the results of research into materials compatibility testing and the predicted lifetime performance of liquid-bonded LWR fuel. The results show that liquid-bonded boiling water reactor peak fuel temperatures are 400 F lower at beginning of life and 200 F lower at end of life compared with conventional fuel
International Nuclear Information System (INIS)
Le Frere, J.P.
1976-01-01
The invention is related to a method for pumping of liquid metals having a low electrical conductivity. To lower the resistance of the conductive spire containing liquid metal to be pumped, a tape formed by a conductive metal such as copper or nickel is inserted in that spire. The tape is interrupted at the level of the air gap of the main magnetic circuit at least when the conductive spire passes through that air gap
Determination of liquid metal density using X-radiography
International Nuclear Information System (INIS)
Mel'nik, B.A.
1978-01-01
A method for measuring molten metal densities based on the determination of the critical angle of complete external X-ray reflection angle is proposed. A good agreement between the experimental and reported data is exemplified by density measurements of liquid Ga, In and Hg at different temperatures. The theoretical method accuracy is 0.2%
Porous Metal Filters for Gas and Liquid Applications in the Nuclear Industry
International Nuclear Information System (INIS)
Kenneth, Rubow
2009-01-01
Sintered metal media are ideally suited for use in the most demanding industrial applications where long life is required and often other media are not cost-effective solution. As examples, filtration technology utilizing sintered metal media provides excellent performance in numerous liquid/solids and gas/solid separation applications found in the handling and processing of fluids containing radioactive materials. Many types of filter media, ranging from single use (disposable) to semi-permanent, are utilized today for separation of particulate matter. However, semi-permanent media are usually cleanable, either on or off-line, and are intended for sustainable, often multi-year, operating life in harsh environments. These harsh environments, which may involve corrosive fluids, high temperatures, high pressures or pressure spikes, often requiring continuous filtration service, are ideally suited for all-metal filtration systems employing semi-permanent sintered metal media. Sintered metal media, usually fabricated into tubular metal elements, have proven high particle removal efficiency and demonstrated reliability that uniquely afford excellent performance for demanding liquid/solids and gas/solids separation processes. The filter element and, in certain cases, the entire filter are weldable; therefore, the inherent sealing eliminates the need for potentially problematic seals. These media provide a positive barrier to ensure particulate removal to protect downstream equipment, for product separation, and/or to meet health, safety and environmental regulations. Typical applications for sintered metal media include: 1) gas and liquid filter systems used in various nuclear and radioactive waste processing applications, 2) an all-metal High Efficiency Particulate Air (HEPA) filter developed under Department of Energy (DOE) funding as an alternative to traditional HEPA filters fabricated with conventional glass fibers used on High Level Waste (HLW) tank ventilation
Liquid metal cooled fast breeder nuclear reactors
International Nuclear Information System (INIS)
Gatley, J.A.
1979-01-01
Breeder fuel sub-assemblies with electromagnetic brakes and fluidic valves for liquid metal cooled fast breeder reactors are described. The electromagnetic brakes are of relatively small proportions and the valves are of the controlled vortex type. The outlet coolant temperature of at least some of the breeder sub-assemblies are maintained by these means substantially constant throughout the life of the fuel assembly without severely pressurising the sub-assembly. (UK)
Rapid-action valve especially for liquid metal
International Nuclear Information System (INIS)
Velek, V.; Cejka, J.; Jakl, J.
1976-01-01
A rapid-action large-diameter valve and control fitting was designed for cooling circuits of nuclear power plants with fast liquid metal cooled reactors, namely sodium cooled. The design meets the requirements for axial symmetry about the flow axis and secures the equilibrium of hydraulic and hydrodynamic forces observing the uniformity of the thickness of the fitting walls which is a pre-requisite for good resistance to thermal shock. (F.M.)
Liquid metal cooled fast breeder nuclear reactors
International Nuclear Information System (INIS)
Thatcher, G.; Mitchell, A.J.
1981-01-01
Fuel sub-assemblies for liquid metal-cooled fast breeder reactors are described which each incorporate a fluid flow control valve for regulating the rate of flow through the sub-assembly. These small electro-magnetic valves seek to maintain the outlet coolant temperature of at least some of the breeder sub-assemblies substantially constant throughout the life of the fuel assembly without severely pressurising the sub-assembly. (U.K.)
A homopolar disc dynamo experiment with liquid metal contacts
Avalos-Zúñiga, R. A.; Priede, J.; Bello-Morales, C. E.
2017-01-01
We present experimental results of a homopolar disc dynamo constructed at CICATA-Quer\\'etaro in Mexico. The device consists of a flat, multi-arm spiral coil which is placed above a fast-spinning metal disc and connected to the latter by sliding liquid-metal electrical contacts. Theoretically, self-excitation of the magnetic field is expected at the critical magnetic Reynolds number Rm~45, which corresponds to a critical rotation rate of about 10 Hz. We measured the magnetic field above the di...
Liquid-metal aspects of HYLIFE
International Nuclear Information System (INIS)
Meier, W.R.; Hoffman, N.J.; McDowell, M.W.
1980-01-01
The High Yield Lithium Injection Fusion Energy (HYLIFE) converter is a reactor concept for an inertial fusion electric power plant. In this concept, flowing molten lithium protects the structures of the fusion chamber from the deleterious effects of deuterium-tritium (DT) fusion reactions and converts the pulsed fusion energy into steay thermal power. Lithium is circulated as the primary coolant to transfer heat to an intermediate sodium loop which drives a superheated steam cycle. Lithium is also the source of the tritium fuel which is recovered via a molten-salt extraction process. The liquid-metal aspects of the HYLIFE plant with particular emphasis on the lithium systems
Analytical modelling of a thin liquid metal layer submitted to an ac magnetic field
Energy Technology Data Exchange (ETDEWEB)
Hinaje, M [Groupe de Recherche en Electrotechnique et Electronique de Nancy, 2 avenue de la Foret de Haye, 54516 Vandoeuvre-les-Nancy (France); Vinsard, G [Laboratoire d' Energetique et de Mecanique Theorique et Appliquee, 2 avenue de la Foret de Haye, 54516 Vandoeuvre-les-Nancy (France); Dufour, S [Laboratoire d' Energetique et de Mecanique Theorique et Appliquee, 2 avenue de la Foret de Haye, 54516 Vandoeuvre-les-Nancy (France)
2006-07-07
A cylindrical thin liquid metal layer is submitted to a uniform ac magnetic field. When the intensity of the electromagnetic field exceeds a critical value, an opening in the liquid is shaped from outside to inside. At a given intensity of the electromagnetic field, this opening is in a frozen state, that is, the liquid metal layer reaches a new equilibrium shape. In this paper, we show that this equilibrium corresponds to a minimum of the total energy of the system. This total energy is equal to the sum of the magnetic energy and the mechanical energy. The magnetic energy is computed by assuming that the induced eddy current flowing through the liquid metal layer is concentrated in the cross-section S{sub c} equal to the product of the skin depth and the thickness of the layer. This assumption leads us to study an equivalent electrical circuit. The mechanical energy is composed of the potential energy and the surface energy.
Analytical modelling of a thin liquid metal layer submitted to an ac magnetic field
International Nuclear Information System (INIS)
Hinaje, M; Vinsard, G; Dufour, S
2006-01-01
A cylindrical thin liquid metal layer is submitted to a uniform ac magnetic field. When the intensity of the electromagnetic field exceeds a critical value, an opening in the liquid is shaped from outside to inside. At a given intensity of the electromagnetic field, this opening is in a frozen state, that is, the liquid metal layer reaches a new equilibrium shape. In this paper, we show that this equilibrium corresponds to a minimum of the total energy of the system. This total energy is equal to the sum of the magnetic energy and the mechanical energy. The magnetic energy is computed by assuming that the induced eddy current flowing through the liquid metal layer is concentrated in the cross-section S c equal to the product of the skin depth and the thickness of the layer. This assumption leads us to study an equivalent electrical circuit. The mechanical energy is composed of the potential energy and the surface energy
Manufacturing processes of cellular metals. Part I. Liquid route processes
International Nuclear Information System (INIS)
Fernandez, P.; Cruz, L. J.; Coleto, J.
2008-01-01
With its interesting and particular characteristics, cellular metals are taking part of the great family of new materials. They can have open or closed porosity. At the present time, the major challenge for the materials researchers is based in the manufacturing techniques improvement in order to obtain reproducible and reliable cellular metals with quality. In the present paper, the different production methods to manufacture cellular metals by liquid route are reviewed; making a short description about the main parameters involved and the advantages and drawbacks in each of them. (Author) 106 refs
International Nuclear Information System (INIS)
Ohira, H.; Ara, K.
2002-11-01
Advanced electromagnetic components are investigated in Feasibility Studies on Commercialized FR Cycle System to apply to the main cooling systems of Liquid Metal Fast Reactor. Although a lot of experiments and numerical analysis were carried out on both high Reynolds numbers and high magnetic Reynolds numbers, the complex phenomena could not be evaluated in detail. As the first step of the development of the numerical methods for the liquid metal magnetohydrodynamics, we investigated numerical methods that could be applied to the electromagnetic components with both complex structures and high magnetic turbulent field. As a result, we selected GSMAC (Generalized-Simplified MArker and Cell) method for calculating the liquid metal fluid dynamics because it could be easily applied to the complex flow field. We also selected the vector-FEM for calculating the magnetic field of the large components because the method had no interaction procedure. In the high magnetic turbulent field, the dynamic-SGS models would be also a promising model for the good estimation, because it could calculate the field directly without any experimental constant. In order to verify the GSMAC and the vector-FEM, we developed the 2D numerical models and calculated the magnetohydrodynamics in the large electromagnetic pump. It was estimated from these results that the methods were basically reasonable, because the calculated pressure differences had the similar tendencies to the experimental ones. (author)
Patterned Liquid Metal Contacts for Printed Carbon Nanotube Transistors.
Andrews, Joseph B; Mondal, Kunal; Neumann, Taylor V; Cardenas, Jorge A; Wang, Justin; Parekh, Dishit P; Lin, Yiliang; Ballentine, Peter; Dickey, Michael D; Franklin, Aaron D
2018-05-14
Flexible and stretchable electronics are poised to enable many applications that cannot be realized with traditional, rigid devices. One of the most promising options for low-cost stretchable transistors are printed carbon nanotubes (CNTs). However, a major limiting factor in stretchable CNT devices is the lack of a stable and versatile contact material that forms both the interconnects and contact electrodes. In this work, we introduce the use of eutectic gallium-indium (EGaIn) liquid metal for electrical contacts to printed CNT channels. We analyze thin-film transistors (TFTs) fabricated using two different liquid metal deposition techniques-vacuum-filling polydimethylsiloxane (PDMS) microchannel structures and direct-writing liquid metals on the CNTs. The highest performing CNT-TFT was realized using vacuum-filled microchannel deposition with an in situ annealing temperature of 150 °C. This device exhibited an on/off ratio of more than 10 4 and on-currents as high as 150 μA/mm-metrics that are on par with other printed CNT-TFTs. Additionally, we observed that at room temperature the contact resistances of the vacuum-filled microchannel structures were 50% lower than those of the direct-write structures, likely due to the poor adhesion between the materials observed during the direct-writing process. The insights gained in this study show that stretchable electronics can be realized using low-cost and solely solution processing techniques. Furthermore, we demonstrate methods that can be used to electrically characterize semiconducting materials as transistors without requiring elevated temperatures or cleanroom processes.
Numerical modelling of inert gas bubble rising in liquid metal pool
International Nuclear Information System (INIS)
Pradeep, Arjun; Sharma, Anil Kumar; Ponraju, D.; Nashine, B K.
2016-01-01
Two-phase flow finds several applications in safe operation of Sodium-cooled Fast Reactor (SFR). Numerical modelling of bubble rise dynamics in liquid metal pool of SFR is essential for the evaluation of residence time and shape changes, which are of utmost importance for simulating associated heat and mass transfer processes involved in reactor safety. A numerical model has been developed based on OpenFOAM for the evaluation of two-dimensional inert gas bubble rise dynamics in stagnant liquid metal pool. The governing model equations are discretized and solved using the Volume of Fluid based solver available in OpenFOAM with appropriate initial and boundary conditions. The model has been validated with available numerical benchmark results for laminar transient two-phase flow. The model has been used to evaluate velocity and rise trajectory of argon gas bubble with different diameters through a pool of liquid sodium. (author)
International Nuclear Information System (INIS)
Shim, J-B.; Lee, J-H.; Kwon, S-W.; Ahn, B-G.; Woo, M-S.; Lee, B-J.; Kim, E-H.; Park, H-S.; Yoo, J-H.
2005-01-01
A pyrochemical partitioning system uses liquid metals such as cadmium and bismuth in order to recover the actinide metals from a molten salt mixture containing rare earth fission product metals. The liquid metals play roles as a cathode in the electrowinning or an extracting phase in the reductive extraction operation. The product resulting from the above operations is metal-cadmium or-bismuth alloy, which should contain the rare earth element amounts as low as possible for a transmutation purpose. In this study, the electrodeposition behaviours of uranium and lanthanide elements such as La, Ce and Nd were investigated for solid molybdenum and liquid cadmium electrodes in a molten LiCl-KCl eutectic salt. Electrochemical methods used are a cyclic voltammetry (CV) and a chronopotentiometry for monitoring the salt phase and recovering the metals, respectively. The CV graphs for monitoring the oxidizing agent CdCl 2 in the salt phase were obtained. These show a time dependently disappearance of the oxidizing agent corresponding to the formation of UCl 3 by inserting the uranium metal into the salt. Also, a sequential oxidation technique which is added at a controlled amount of the oxidizing agents into the salt phase was applied. It was found that this method is feasible for the selective reduction of the rare earths content in liquid metal alloys. (author)
International Nuclear Information System (INIS)
Ogihara, Wataru; Sun Jiazeng; Forsyth, Maria; MacFarlane, Douglas R.; Yoshizawa, Masahiro; Ohno, Hiroyuki
2004-01-01
We have prepared polymer gel electrolytes with alkali metal ionic liquids (AMILs) that inherently contain alkali metal ions. The AMIL consisted of sulfate anion, imidazolium cation, and alkali metal cation. AMILs were mixed directly with poly(3-sulfopropyl acrylate) lithium salt or poly(2-acrylamido-2-methylpropanesulfonic acid) lithium salt to form polymer gels. The ionic conductivity of these gels decreased with increasing polymer fraction, as in general ionic liquid/polymer mixed systems. At low polymer concentrations, these gels displayed excellent ionic conductivity of 10 -4 to 10 -3 S cm -1 at room temperature. Gelation was found to cause little change in the 7 Li diffusion coefficient of the ionic liquid, as measured by pulse-field-gradient NMR. These data strongly suggest that the lithium cation migrates in successive pathways provided by the ionic liquids
Advanced Gasification Mercury/Trace Metal Control with Monolith Traps
Energy Technology Data Exchange (ETDEWEB)
Musich, Mark; Swanson, Michael; Dunham, Grant; Stanislowski, Joshua
2010-10-05
Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400°F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be the best monolith tested to date. The Corning SR Liquid monolith concept continues to be a strong candidate for mercury capture. Both monolith types allowed mercury reduction to below 5-μg/m{sup 3} (~5 ppb), a current U.S. Department of Energy (DOE) goal for trace metal control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center (EERC)-prepared Noncarbon Sorbents 1 and 2 appeared to offer potential for sustained and significant reduction of mercury concentration in the simulated fuel gas. The Noncarbon Sorbent 1 allowed sustained mercury reduction to below 5-μg/m{sup 3} (~5 ppb). The non-carbon-based sorbent appeared to offer the potential for regeneration, that is, desorption of mercury by temperature swing (using nitrogen and steam at temperatures above where adsorption takes place). A Corning cordierite monolith treated with a Group IB metal offered limited potential as a mercury sorbent. However, a Corning carbon-based monolith containing prereduced metallic species similar to those found on the noncarbon sorbents did not exhibit significant or sustained mercury reduction. EERC sorbents prepared with Group IB and IIB selenide appeared to have some promise for mercury capture. Unfortunately, these sorbents also released Se, as was evidenced by the measurement of H2Se in the effluent gas. All sorbents tested with arsine or hydrogen selenide, including Corning monoliths and the Group IB and IIB metal-based materials, showed an ability to capture arsine or hydrogen selenide at 400°F and 600 psig. Based on current testing, the noncarbon metal-based sorbents appear to be the most
ADVANCED GASIFICATION MERCURY/TRACE METAL CONTROL WITH MONOLITH TRAPS
Energy Technology Data Exchange (ETDEWEB)
Mark A. Musich; Michael L. Swanson; Grant E. Dunham; Joshua J. Stanislowski
2010-07-31
Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400°F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be the best monolith tested to date. The Corning SR Liquid monolith concept continues to be a strong candidate for mercury capture. Both monolith types allowed mercury reduction to below 5-μg/m3 (~5 ppb), a current U.S. Department of Energy (DOE) goal for trace metal control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center (EERC)-prepared Noncarbon Sorbents 1 and 2 appeared to offer potential for sustained and significant reduction of mercury concentration in the simulated fuel gas. The Noncarbon Sorbent 1 allowed sustained mercury reduction to below 5-μg/m3 (~5 ppb). The non-carbon-based sorbent appeared to offer the potential for regeneration, that is, desorption of mercury by temperature swing (using nitrogen and steam at temperatures above where adsorption takes place). A Corning cordierite monolith treated with a Group IB metal offered limited potential as a mercury sorbent. However, a Corning carbon-based monolith containing prereduced metallic species similar to those found on the noncarbon sorbents did not exhibit significant or sustained mercury reduction. EERC sorbents prepared with Group IB and IIB selenide appeared to have some promise for mercury capture. Unfortunately, these sorbents also released Se, as was evidenced by the measurement of H2Se in the effluent gas. All sorbents tested with arsine or hydrogen selenide, including Corning monoliths and the Group IB and IIB metal-based materials, showed an ability to capture arsine or hydrogen selenide at 400°F and 600 psig. Based on current testing, the noncarbon metal-based sorbents appear to be the most effective arsine
Experiments with liquid metal walls: Status of the lithium tokamak experiment
Energy Technology Data Exchange (ETDEWEB)
Kaita, Robert, E-mail: kaita@pppl.gov [Princeton Plasma Physics Laboratory, Princeton, NJ (United States); Berzak, Laura; Boyle, Dennis; Gray, Timothy; Granstedt, Erik; Hammett, Gregory; Jacobson, Craig M.; Jones, Andrew; Kozub, Thomas; Kugel, Henry; Leblanc, Benoit; Logan, Nicholas; Lucia, Matthew; Lundberg, Daniel; Majeski, Richard; Mansfield, Dennis; Menard, Jonathan; Spaleta, Jeffrey; Strickler, Trevor; Timberlake, John [Princeton Plasma Physics Laboratory, Princeton, NJ (United States)
2010-11-15
Abstarct: Liquid metal walls have been proposed to address the first wall challenge for fusion reactors. The lithium tokamak experiment (LTX) at the Princeton Plasma Physics Laboratory (PPPL) is the first magnetic confinement device to have liquid metal plasma-facing components (PFC's) that encloses virtually the entire plasma. In the current drive experiment-upgrade (CDX-U), a predecessor to LTX at PPPL, the highest improvement in energy confinement ever observed in ohmically heated tokamak plasmas was achieved with a toroidal liquid lithium limiter. The LTX extends this liquid lithium PFC by using a conducting conformal shell that almost completely surrounds the plasma. By heating the shell, a lithium coating on the plasma-facing side can be kept liquefied. A consequence of the low-recycling conditions from liquid lithium walls is the need for efficient plasma fueling. For this purpose, a molecular cluster injector is being developed. Future plans include the installation of a neutral beam for core plasma fueling, and also ion temperature measurements using charge-exchange recombination spectroscopy (CHERS). Low edge recycling is also predicted to reduce temperature gradients that drive drift wave turbulence. Gyrokinetic simulations are in progress to calculate fluctuation levels and transport for LTX plasmas, and new fluctuation diagnostics are under development to test these predictions.
Experiments with Liquid Metal Walls: Status of the Lithium Tokamak Experiment
International Nuclear Information System (INIS)
Kaita, Robert; Berzak, Laura; Boyle, Dennis; Gray, Timothy; Granstedt, Erik; Hammett, Gregory; Jacobson, Craig M.; Jones, Andrew; Kozub, Thomas; Kugel, Henry; Leblanc, Benoit; Logan, Nicholas; Lucia, Matthew; Lundberg, Daniel; Majeski, Richard; Mansfield, Dennis; Menard, Jonathan; Spaleta, Jeffrey; Strickler, Trevor; Timberlak, John
2010-01-01
Liquid metal walls have been proposed to address the first wall challenge for fusion reactors. The Lithium Tokamak Experiment (LTX) at the Princeton Plasma Physics Laboratory (PPPL) is the first magnetic confinement device to have liquid metal plasma-facing components (PFC's) that encloses virtually the entire plasma. In the Current Drive Experiment-Upgrade (CDX-U), a predecessor to LTX at PPPL, the highest improvement in energy confinement ever observed in Ohmically-heated tokamak plasmas was achieved with a toroidal liquid lithium limiter. The LTX extends this liquid lithium PFC by using a conducting conformal shell that almost completely surrounds the plasma. By heating the shell, a lithium coating on the plasma-facing side can be kept liquefied. A consequence of the low-recycling conditions from liquid lithium walls is the need for efficient plasma fueling. For this purpose, a molecular cluster injector is being developed. Future plans include the installation of a neutral beam for core plasma fueling, and also ion temperature measurements using charge-exchange recombination spectroscopy. Low edge recycling is also predicted to reduce temperature gradients that drive drift wave turbulence. Gyrokinetic simulations are in progress to calculate fluctuation levels and transport for LTX plasmas, and new fluctuation diagnostics are under development to test these predictions.
Oscillatory vapour shielding of liquid metal walls in nuclear fusion devices.
van Eden, G G; Kvon, V; van de Sanden, M C M; Morgan, T W
2017-08-04
Providing an efficacious plasma facing surface between the extreme plasma heat exhaust and the structural materials of nuclear fusion devices is a major challenge on the road to electricity production by fusion power plants. The performance of solid plasma facing surfaces may become critically reduced over time due to progressing damage accumulation. Liquid metals, however, are now gaining interest in solving the challenge of extreme heat flux hitting the reactor walls. A key advantage of liquid metals is the use of vapour shielding to reduce the plasma exhaust. Here we demonstrate that this phenomenon is oscillatory by nature. The dynamics of a Sn vapour cloud are investigated by exposing liquid Sn targets to H and He plasmas at heat fluxes greater than 5 MW m -2 . The observations indicate the presence of a dynamic equilibrium between the plasma and liquid target ruled by recombinatory processes in the plasma, leading to an approximately stable surface temperature.Vapour shielding is one of the interesting mechanisms for reducing the heat load to plasma facing components in fusion reactors. Here the authors report on the observation of a dynamic equilibrium between the plasma and the divertor liquid Sn surface leading to an overall stable surface temperature.
Infrared Spectroscopy as Molecular Probe of the Macroscopic Metal-Liquid Interface
Directory of Open Access Journals (Sweden)
Johannes Kiefer
2017-11-01
Full Text Available Metal-liquid interfaces are of the utmost importance in a number of scientific areas, including electrochemistry and catalysis. However, complicated analytical methods and sample preparation are usually required to study the interfacial phenomena. We propose an infrared spectroscopic approach that enables investigating the molecular interactions at the interface, but needing only minimal or no sample preparation. For this purpose, the internal reflection element (IRE is wetted with a solution as first step. Second, a small plate of the metal of interest is put on top and pressed onto the IRE. The tiny amount of liquid that is remaining between the IRE and the metal is sufficient to produce an IR spectrum with good signal to noise ratio, from which information about molecular interactions, such as hydrogen bonding, can be deduced. Proof-of-concept experiments were carried out with aqueous salt and acid solutions and an aluminum plate.
Trial fabrication and preliminary characterization of electrical insulator for liquid metal system
International Nuclear Information System (INIS)
Nakamichi, Masaru; Kawamura, Hiroshi; Oyamada, Rokuro
1995-03-01
In the design of the liquid metal blanket, MHD pressure drop is one of critical issues. Ceramic coating on the surface of structural material is considered as an electrical insulator to reduce the MHD pressure drop. Ceramic coating such as Y 2 O 3 is a promising electrical insulator due to its high electrical resistivity and good compatibility with liquid lithium. This report describes the trial fabrication and preliminary characterization of electrical insulator for a design study of the liquid metal system. From the results of trial fabrication and preliminary characterization, it is concluded that densified atmospheric plasma spray Y 2 O 3 coating with 410SS undercoating between 316SS substrate and Y 2 O 3 coating is suitable for Y 2 O 3 coating fabrication. (author)
Pool type liquid metal fast breeder reactors
International Nuclear Information System (INIS)
Guthrie, B.M.
1978-08-01
Various technical aspects of the liquid metal fast breeder reactor (LMFBR), specifically pool type LMFBR's, are summarized. The information presented, for the most part, draws upon existing data. Special sections are devoted to design, technical feasibility (normal operating conditions), and safety (accident conditions). A survey of world fast reactors is presented in tabular form, as are two sets of reference reactor parameters based on available data from present and conceptual LMFBR's. (auth)
Advances by the Integral Fast Reactor Program
International Nuclear Information System (INIS)
Lineberry, M.J.; Pedersen, D.R.; Walters, L.C.; Cahalan, J.E.
1991-01-01
The advances by the Integral Fast Reactor Program at Argonne National Laboratory are the subject of this paper. The Integral Fast Reactor (IFR) is an advanced liquid-metal-cooled reactor concept being developed at Argonne National Laboratory. The advances stressed in the paper include fuel irradiation performance, improved passive safety, and the development of a prototype fuel cycle facility. 14 refs
Study on novel ionic liquids as extracting agent for priority metals from waste waters
International Nuclear Information System (INIS)
Fischer, L.; Falta, T.; Stingeder, G.; Koellensperger, G.; Hann, S.; Kogelnig, D.; Stojanovic, A.; Krachler, R.; Keppler, B.K.
2009-01-01
Full text: As the new EU Water Framework Directive (2000/60/EC) sets high environmental quality standards for priority substances in surface water, effective procedures for wastewater treatment are required. The characteristics of ionic liquids (IL) can be adjusted by modifying their ionic composition for liquid-liquid extraction of metals and metal containing compounds (Cd, Hg, Ni, Pb, tributyltin, cancerostatic platinum compounds) from the water phase. The potential of novel IL for selective removal of the above mentioned substances regarding extraction time, pH and matrix were determined by ICPSFMS, HPLC-ICPMS and GC-ICPMS measurements. (author)
Updated reference design of a liquid metal cooled tandem mirror fusion breeder
International Nuclear Information System (INIS)
Berwald, D.H.; Whitley, R.H.; Garner, J.K.
1985-09-01
Detailed studies of key techinical issues for liquid metal cooled fusion breeder (fusion-fission hybrid blankets) have been performed during the period 1983-4. Based upon the results of these studies, the 1982 reference liquid metal cooled tandem mirror fusion breeder blanket design was updated and is described. The updated reference blankets provides increased breeding and lower technological risk in comparison with the original reference blanket. In addition to the blanket design revisions, a plant concept, cost, and fuel cycle economics assessment is provided. The fusion breeder continues to promise an economical source of fissile fuel for the indefinite future
Updated reference design of a liquid metal cooled tandem mirror fusion breeder
Energy Technology Data Exchange (ETDEWEB)
Berwald, D.H.; Whitley, R.H.; Garner, J.K.; Gromada, R.J.; McCarville, T.J.; Moir, R.W.; Lee, J.D.; Bandini, B.R.; Fulton, F.J.; Wong, C.P.C.; Maya, I.; Hoot, C.G.; Schultz, K.R.; Miller, L.G.; Beeston, J.M.; Harris, B.L.; Westman, R.A.; Ghoniem, N.M.; Orient, G.; Wolfer, M.; DeVan, J.H.; Torterelli, P.
1985-09-01
Detailed studies of key techinical issues for liquid metal cooled fusion breeder (fusion-fission hybrid blankets) have been performed during the period 1983-4. Based upon the results of these studies, the 1982 reference liquid metal cooled tandem mirror fusion breeder blanket design was updated and is described. The updated reference blankets provides increased breeding and lower technological risk in comparison with the original reference blanket. In addition to the blanket design revisions, a plant concept, cost, and fuel cycle economics assessment is provided. The fusion breeder continues to promise an economical source of fissile fuel for the indefinite future.
Liquid metal reactor head designs in the USA - heat and mass transfer considerations
International Nuclear Information System (INIS)
Burke, T.M.
1986-01-01
Development of liquid metal reactor plants in the United States over the past 30 years has resulted in an evolution of reactor head designs as reflected in the SRE, Hallam, EBR-II and FFTF plants. This evolution has probably been affected to some extent by the fact that, in contrast to most other countries, there is no single organization in the United States which has been responsible for the design of liquid metal reactor plants. The current U.S. LMR design efforts involve two innovative design consortiums (guided by the US Department of Energy) and a joint industry venture on the Large Scale Prototype Breeder. It is therefore somewhat difficult to provide a statement on the philosophy of the reactor head design in the U.S. This paper however briefly describes the existing and proposed U.S. liquid metal reactor head designs and in the process, attempt to provide some insight on the basis for those designs
Experimental study of the features of the running part liquid metal target on lead-bismuth alloy
International Nuclear Information System (INIS)
Beznosov, A.V.; Meluzov, A.G.; Novozhilova, O.O.; Efanov, A.D.
2007-01-01
The results of experimental investigations of the through part of a full-scale liquid metal target of an accelerator-control system, where the working cavity of the target communicates directly with the particle accelerator cavity, are presented. Two design variants were investigated - with vertical and horizontal orientation of the target axis in space and spinning of the flow in front of the nozzle adapter located in front of the entrance of the eutectic into the working cavity of the target. The profiles obtained for the free coolant surface with liquid metal flowing through vertically and horizontally positioned targets are presented. It is confirmed that when the pressure of the free surface of the liquid metal corresponds to the pressure in the accelerator cavity it is possible that liquid metal will not flow into the cavity simulating the connecting piece for inflow of accelerated particles with the piece oriented vertically or horizontally [ru
International Nuclear Information System (INIS)
Yang, Fan; Kubota, Fukiko; Baba, Yuzo; Kamiya, Noriho; Goto, Masahiro
2013-01-01
Highlights: • Recycling of rare earth metals from fluorescent lamps was conducted by ionic liquid-mediated extraction. • Acid leaching from a waste phosphor powder was carried out using sulfuric and nitric acids. • An ionic liquid was used as extracting solvent for the rare earth metals. • Selective extraction of rare earth metals from leach solutions was attained. •The extracting ionic liquid phase was recyclable in the recovery process. -- Abstract: The recycling of rare earth metals from phosphor powders in waste fluorescent lamps by solvent extraction using ionic liquids was studied. Acid leaching of rare earth metals from the waste phosphor powder was examined first. Yttrium (Y) and europium (Eu) dissolved readily in the acid solution; however, the leaching of other rare earth metals required substantial energy input. Ionization of target rare earth metals from the waste phosphor powders into the leach solution was critical for their successful recovery. As a high temperature was required for the complete leaching of all rare earth metals, ionic liquids, for which vapor pressure is negligible, were used as an alternative extracting phase to the conventional organic diluent. An extractant, N, N-dioctyldiglycol amic acid (DODGAA), which was recently developed, showed a high affinity for rare earth metal ions in liquid–liquid extraction although a conventional commercial phosphonic extractant did not. An effective recovery of the rare earth metals, Y, Eu, La and Ce, from the metal impurities, Fe, Al and Zn, was achieved from the acidic leach solution of phosphor powders using an ionic liquid containing DODGAA as novel extractant system
Energy Technology Data Exchange (ETDEWEB)
Yang, Fan; Kubota, Fukiko; Baba, Yuzo [Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Fukuoka 819-0395 (Japan); Kamiya, Noriho [Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Fukuoka 819-0395 (Japan); Center for Future Chemistry, Kyushu University, 744 Motooka, Fukuoka 819-0395 (Japan); Goto, Masahiro, E-mail: m-goto@mail.cstm.kyushu-u.ac.jp [Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Fukuoka 819-0395 (Japan); Center for Future Chemistry, Kyushu University, 744 Motooka, Fukuoka 819-0395 (Japan)
2013-06-15
Highlights: • Recycling of rare earth metals from fluorescent lamps was conducted by ionic liquid-mediated extraction. • Acid leaching from a waste phosphor powder was carried out using sulfuric and nitric acids. • An ionic liquid was used as extracting solvent for the rare earth metals. • Selective extraction of rare earth metals from leach solutions was attained. •The extracting ionic liquid phase was recyclable in the recovery process. -- Abstract: The recycling of rare earth metals from phosphor powders in waste fluorescent lamps by solvent extraction using ionic liquids was studied. Acid leaching of rare earth metals from the waste phosphor powder was examined first. Yttrium (Y) and europium (Eu) dissolved readily in the acid solution; however, the leaching of other rare earth metals required substantial energy input. Ionization of target rare earth metals from the waste phosphor powders into the leach solution was critical for their successful recovery. As a high temperature was required for the complete leaching of all rare earth metals, ionic liquids, for which vapor pressure is negligible, were used as an alternative extracting phase to the conventional organic diluent. An extractant, N, N-dioctyldiglycol amic acid (DODGAA), which was recently developed, showed a high affinity for rare earth metal ions in liquid–liquid extraction although a conventional commercial phosphonic extractant did not. An effective recovery of the rare earth metals, Y, Eu, La and Ce, from the metal impurities, Fe, Al and Zn, was achieved from the acidic leach solution of phosphor powders using an ionic liquid containing DODGAA as novel extractant system.
Magnetorotational Instability in a Rotating Liquid Metal Annulus
International Nuclear Information System (INIS)
Hantao Ji; Jeremy Goodman; Akira Kageyama
2001-01-01
Although the magnetorotational instability (MRI) has been widely accepted as a powerful accretion mechanism in magnetized accretion disks, it has not been realized in the laboratory. The possibility of studying MRI in a rotating liquid-metal annulus (Couette flow) is explored by local and global stability analysis and magnetohydrodynamic (MHD) simulations. Stability diagrams are drawn in dimensionless parameters, and also in terms of the angular velocities at the inner and outer cylinders. It is shown that MRI can be triggered in a moderately rapidly rotating table-top apparatus, using easy-to-handle metals such as gallium. Practical issues of this proposed experiment are discussed
Liquid-metal-jet anode electron-impact x-ray source
International Nuclear Information System (INIS)
Hemberg, O.; Otendal, M.; Hertz, H.M.
2003-01-01
We demonstrate an anode concept, based on a liquid-metal jet, for improved brightness in compact electron-impact x-ray sources. The source is demonstrated in a proof-of-principle experiment where a 50 keV, ∼100 W electron beam is focused on a 75 μm liquid-solder jet. The generated x-ray flux and brightness is quantitatively measured in the 7-50 keV spectral region and found to agree with theory. Compared to rotating-anode sources, whose brightness is limited by intrinsic thermal properties, the liquid-jet anode could potentially be scaled to achieve a brightness >100x higher than current state-of-the-art sources. Applications such as mammography, angiography, and diffraction would benefit from such a compact high-brightness source
Development of thermohydraulic codes for modeling liquid metal boiling in LMR fuel subassemblies
International Nuclear Information System (INIS)
Sorokin, G.A.; Avdeev, E.F.; Zhukov, A.V.; Bogoslovskaya, G.P.; Sorokin, A.P.
2000-01-01
An investigation into the reactor core accident cooling, which are associated with the power grow up or switch off circulation pumps in the event of the protective equipment comes into action, results in the problem of liquid metal boiling heat transfer. Considerable study has been given over the last 30 years to alkaline metal boiling including researches of heat transfer, boiling patterns, hydraulic resistance, crisis of heat transfer, initial heating up, boiling onset and instability of boiling. The results of these investigations have shown that the process of liquid metal boiling has substantial features in comparison with water boiling. Mathematical modeling of two phase flows in fast reactor fuel subassemblies have been developed intensively. Significant success has been achieved in formulation of two phase flow through the pin bundle and in their numerical realization. Currently a set of codes for thermohydraulic analysis of two phase flows in fast reactor subassembly have been developed with 3D macrotransfer governing equations. These codes are used for analysis of boiling onset and liquid metals boiling in fuel subassemblies during loss-of-coolant accidents, of warming up of reactor core, of blockage of some part of flow cross section in fuel subassembly. (author)
Narula, Manmeet Singh
Innovative concepts using fast flowing thin films of liquid metals (like lithium) have been proposed for the protection of the divertor surface in magnetic fusion devices. However, concerns exist about the possibility of establishing the required flow of liquid metal thin films because of the presence of strong magnetic fields which can cause flow disrupting MHD effects. A plan is underway to design liquid lithium based divertor protection concepts for NSTX, a small spherical torus experiment at Princeton. Of these, a promising concept is the use of modularized fast flowing liquid lithium film zones, as the divertor (called the NSTX liquid surface module concept or NSTX LSM). The dynamic response of the liquid metal film flow in a spatially varying magnetic field configuration is still unknown and it is suspected that some unpredicted effects might be lurking. The primary goal of the research work being reported in this dissertation is to provide qualitative and quantitative information on the liquid metal film flow dynamics under spatially varying magnetic field conditions, typical of the divertor region of a magnetic fusion device. The liquid metal film flow dynamics have been studied through a synergic experimental and numerical modeling effort. The Magneto Thermofluid Omnibus Research (MTOR) facility at UCLA has been used to design several experiments to study the MHD interaction of liquid gallium films under a scaled NSTX outboard divertor magnetic field environment. A 3D multi-material, free surface MHD modeling capability is under development in collaboration with HyPerComp Inc., an SBIR vendor. This numerical code called HIMAG provides a unique capability to model the equations of incompressible MHD with a free surface. Some parts of this modeling capability have been developed in this research work, in the form of subroutines for HIMAG. Extensive code debugging and benchmarking exercise has also been carried out. Finally, HIMAG has been used to study the
Structure factor of liquid alkali metals using a classical-plasma reference system
Pastore, G.; Tosi, M. P.
1984-06-01
This paper presents calculations of the liquid structure factor of the alkali metals near freezing, starting from the classical plasma of bare ions as reference liquid. The indirect ion-ion interaction arising from electronic screening is treated by an optimized random phase approximation (ORPA), imposing physical requirements as in the original ORPA scheme developed by Weeks, Chandler and Andersen for liquids with strongly repulsive core potentials. A comparison of the results with computer simulation data for a model of liquid rubidium shows that the present approach overcomes the well-known difficulties met in applying to these metals the standard ORPA based on a reference liquid of neutral hard spheres. The optimization scheme is also shown to be equivalent to a reduction of the range of the indirect interaction in momentum space, as proposed empirically in an earlier work. Comparison with experiment for the other alkalis shows that a good overall representation of the data can be obtained for sodium, potassium and cesium, but not for lithium, when one uses a very simple form of the electron-ion potential adjusted to the liquid compressibility. The small-angle scattering region is finally examined more carefully in the light of recent data of Waseda, with a view to possible refinements of the pseudopotential model.
Liquid metal/metal oxide frameworks with incorporated Ga2O3 for photocatalysis.
Zhang, Wei; Naidu, Boddu S; Ou, Jian Zhen; O'Mullane, Anthony P; Chrimes, Adam F; Carey, Benjamin J; Wang, Yichao; Tang, Shi-Yang; Sivan, Vijay; Mitchell, Arnan; Bhargava, Suresh K; Kalantar-Zadeh, Kourosh
2015-01-28
Solvothermally synthesized Ga2O3 nanoparticles are incorporated into liquid metal/metal oxide (LM/MO) frameworks in order to form enhanced photocatalytic systems. The LM/MO frameworks, both with and without incorporated Ga2O3 nanoparticles, show photocatalytic activity due to a plasmonic effect where performance is related to the loading of Ga2O3 nanoparticles. Optimum photocatalytic efficiency is obtained with 1 wt % incorporation of Ga2O3 nanoparticles. This can be attributed to the sub-bandgap states of LM/MO frameworks, contributing to pseudo-ohmic contacts which reduce the free carrier injection barrier to Ga2O3.
A perturbed Lennard-Jones chain equation of state for liquid metals
Energy Technology Data Exchange (ETDEWEB)
Mousazadeh, M H; Marageh, M Ghanadi [AEOI, JIH Research Laboratory, 11365/8486, Tehran (Iran, Islamic Republic of)
2006-05-24
The perturbed Lennard-Jones chain (PLJC) equation of state is formulated based on first-order variational perturbation theory. The model uses two parameters for a monatomic system, segment size, {sigma}, and segment energy, {epsilon}/k. In this work, we employed the PLJC equation to calculate the liquid density of 26 metals, including alkali and alkali earth metals, iron, cobalt, nickel, copper, silver, gold, zinc, cadmium, mercury, aluminium, gallium, indium, thallium, tin, lead, antimony, and bismuth, for which accurate experimental data exist in the literature. The calculations cover a broad range of temperatures ranging from the melting point to close to the critical point and pressures ranging from the vapour-pressure curve up to pressures as high as 2000 bar. The average absolute deviation in the liquid density predicted by the PLJC equation of state in the saturation line compared with experimental data is 1.26%. Also, using the normal melting temperature and liquid density at melting point (T{sub m}, {rho}{sub m}) as input data for the estimation of the equation of state parameters provides a good correlation of liquid density at saturated and compressed pressures.
Effective interionic pair potentials in liquid alkali metals
International Nuclear Information System (INIS)
Kumaravadivel, R.
1984-06-01
Information on the effective pair potential of liquid alkali metals is obtained from liquid structure factor data by the combination of two approximate methods in the theory of liquids. One method stems from treating the indirect ion-ion interaction in the optimised random phase approximation (ORPA) and the other uses the modified hypernetted chain (MHNC) equation. It is shown that, in the region of the main attractive well, the effective pair potential is bracketed by the results obtained from these two methods. The MHNC inversion scheme does not fare well in providing information on the potential in the region of interionic distance in the tail of the interionic potential. A cross-over from the hard-sphere bridge function to the mean spherical approximation (MSA) bridge function for the long range behaviour of the bridge term in the MHNC equation does not provide appreciable improvement. (author)
Dispersion forces and small-angle neutron scattering from liquid noble metals
International Nuclear Information System (INIS)
March, N.H.
1988-01-01
Maggs and Ashcroft [Phys. Rev. letts., 59,113 (1987)] have re-opened the question of the analogy between the cohesion of a molecular crystal, in which dispersion forces play a major role, and that in a metal crystal with polarizable ion cores. It is pointed out that small-angle neutron scattering from liquid noble metals could be used to test their predictions. (author)
Disintegration of liquid metals by low pressure water blasting
International Nuclear Information System (INIS)
Heshmatpour, B.; Copeland, G.L.
1981-01-01
The feasibility of disintegrating metals by a low cost system and subsequently incorporating them into grout mixtures has been demonstrated. A low pressure water blasting technique consisting of multiple nozzles and a converging-line jet stream was developed to disintegrate liquid metals and produce coarse metal powder and shot. Molten iron resulted in spherical shot, while copper, aluminum, and tin produced irregular shaped particles. The particle size was between 0.05 and 3 mm (0.002 and 0.1 in.), and about half the particles were smaller than 1 mm (0.04 in.) in all cases. The water consumption was rather low, while the production rate was relatively high. The method proved to be simple and reliable. The coarse metal powders were suspendable in grout fluids, indicating that they are probably disposable by the shale hydrofracture technique
A multi-slice sliding cell technique for diffusion measurements in liquid metals
Zhong, Langxiang; Hu, Jinliang; Geng, Yongliang; Zhu, Chunao; Zhang, Bo
2017-09-01
The long capillary and shear-cell techniques are traditionally used for diffusion measurements in liquid metals. Inspired by the idea of the shear-cell method, we have built a multi-slice sliding cell device for inter-diffusion measurements in liquid metals. The device is designed based on a linear sliding movement rather than a rotational shearing as used in the traditional shear-cell method. Compared with the normal shear-cell method, the present device is a more compact setup thus easier to handle. Also, it is expected to be easier to monitor with X-rays or neutrons if used in in situ experiments. A series of benchmark time-dependent diffusion experiments in Al-Cu melts carried out with the present technique reveal that accurate diffusion constants can be achieved only after a sufficient time. For short annealing times, the initial shearing process causing convective flow dominates the measurement and leads to an increase of the measured diffusion coefficient by a factor three. The diffusion data obtained for Al-Cu liquids are consistent with the most accurate data measured by the in situ X-ray radiography method under well controlled conditions of no temperature gradient or other perturbation. High accuracy and easy handling as well as superior adaptability make the present technique suitable for diffusion studies in liquid metals.
Localization of electromagnetic field on the “Brouwer-island” and liquid metal embrittlement
Energy Technology Data Exchange (ETDEWEB)
Maksimenko, V.V.; Zagaynov, V.A. [National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), 31, Kashirskoe shosse, 115409 Moscow (Russian Federation); Karpov Institute of Physical Chemistry, Vorontsovo Pole, 10, 105064 Moscow (Russian Federation); Agranovski, I.E., E-mail: I.Agranovski@griffith.edu.au [National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), 31, Kashirskoe shosse, 115409 Moscow (Russian Federation); School of Engineering, Griffith University, Brisbane, 4111 QLD (Australia)
2015-03-01
Liquid metal embrittlement (LME) manifests itself as a sudden destruction of a metal sample if it is covered by a thin liquid film of eutectic mixture of specially selected metals. The proposed theoretical model of this phenomenon is based on an assumption related to the possibility of electromagnetic field localization in folds of interface between the phases or components of eutectic mixture filling cracks in solid metal surface (the typical example is In–Ga eutectic on Al-surface). Based on simultaneous presence of three different components in each space point of eutectic mixture (homogeneous In + Ga melt, solid In, and solid Ga), the system of interface folds could be simulated by the Brouwer surface – well known in topology. This surface separates three different components presented at each of its point. Such fractal surfaces posses by a finite volume. The volume occupied by the surface is defined as a difference between the eutectic mixture volume and the sum of volumes of its components. We investigate localization of external electromagnetic radiation in this system of folds. Due to very large magnitude of effective dielectric permeability of the considered system, at relative small volume change and fractal dimension of interface close to the value 3, the wave length of incident radiation inside the system is considerably decreased and multiscale folds are filled with localized photons. A probability of this process and the life time of the localized photons are calculated. The localized photons play crucial role in destruction of primary cracks in the metal surface. They are capable “to switch of” the Coulomb attraction of charge fluctuations on opposite “banks” of the crack filled with the eutectic. As a result, the crack could break down. - Highlights: • A new theoretical model of liquid metal embrittlement has been developed. • Light localization has a strong influence on liquid metal embrittlement. • Light is localized in folds at
Localization of electromagnetic field on the “Brouwer-island” and liquid metal embrittlement
International Nuclear Information System (INIS)
Maksimenko, V.V.; Zagaynov, V.A.; Agranovski, I.E.
2015-01-01
Liquid metal embrittlement (LME) manifests itself as a sudden destruction of a metal sample if it is covered by a thin liquid film of eutectic mixture of specially selected metals. The proposed theoretical model of this phenomenon is based on an assumption related to the possibility of electromagnetic field localization in folds of interface between the phases or components of eutectic mixture filling cracks in solid metal surface (the typical example is In–Ga eutectic on Al-surface). Based on simultaneous presence of three different components in each space point of eutectic mixture (homogeneous In + Ga melt, solid In, and solid Ga), the system of interface folds could be simulated by the Brouwer surface – well known in topology. This surface separates three different components presented at each of its point. Such fractal surfaces posses by a finite volume. The volume occupied by the surface is defined as a difference between the eutectic mixture volume and the sum of volumes of its components. We investigate localization of external electromagnetic radiation in this system of folds. Due to very large magnitude of effective dielectric permeability of the considered system, at relative small volume change and fractal dimension of interface close to the value 3, the wave length of incident radiation inside the system is considerably decreased and multiscale folds are filled with localized photons. A probability of this process and the life time of the localized photons are calculated. The localized photons play crucial role in destruction of primary cracks in the metal surface. They are capable “to switch of” the Coulomb attraction of charge fluctuations on opposite “banks” of the crack filled with the eutectic. As a result, the crack could break down. - Highlights: • A new theoretical model of liquid metal embrittlement has been developed. • Light localization has a strong influence on liquid metal embrittlement. • Light is localized in folds at
Freezing of liquid alkali metals as screened ionic plasmas
International Nuclear Information System (INIS)
Badirkhan, Z.; Rovere, M.; Tosi, M.P.
1990-08-01
The relationship between Wigner crystallization of the classical ionic plasma and the liquid-solid transition of alkali metals is examined within the density wave theory of freezing. Freezing of the classical plasma on a rigid neutralizing background into the bcc structure is first re-evaluated, in view of recent progress in the determination of its thermodynamic functions by simulation and of the known difficulties of the theory relating to the order parameter at the (200) star of reciprocal lattice vectors. Freezing into the fcc structure is also considered in this context and found to be unfavoured. On allowing for long-wavelength deformability of the background, the ensuing appearance of a volume change on freezing into the bcc structure is accompanied by reduced stability of the fluid phase and by an increase in the entropy of melting. Freezing of alkali metals into the bcc structure is next evaluated, taking their ionic pair structure as that of an ionic plasma reference fluid screened by conduction electrons and asking that the correct ionic coupling strength at liquid-solid coexistence should be approximately reproduced. The ensuring values of the volume and entropy changes across the phase transition, as estimated from the theory by two alternative routes, are in reasonable agreement with experiment. The order parameters of the phase transition, excepting the (200) one, conform rather closely to a Gaussian behaviour and yield a Lindemann ratio in reasonable agreement with the empirical value for melting of bcc crystals. It is suggested that ionic ordering at the (200) star in the metal may be (i) assisted by medium range ordering in the conduction electrons, as indicated by differences in X-ray and neutron diffraction intensities from the liquid, and/or (ii) quite small in the hot bcc solid. Such a possible premelting behaviour of bcc metals should be worth testing experimentally by diffraction. (author). 48 refs, 1 fig., 1 tab
Ab initio study of the atomic motion in liquid metal surfaces: comparison with Lennard-Jones systems
International Nuclear Information System (INIS)
Gonzalez, Luis E; Gonzalez, David J
2006-01-01
It is established that liquid metals exhibit surface layering at the liquid-vapour interface, while dielectric simple systems, like those interacting through Lennard-Jones potentials, show a monotonic decay from the liquid density to that of the vapour. First principles molecular dynamics simulations of the free liquid surface of several liquid metals (Li, Na, K, Rb, Cs, Mg, Ba, Al, Tl and Si), and the Na 3 K 7 alloy near their triple points have been performed in order to study the atomic motion at the interface, mainly at the outer layer. Comparison with the results of classical molecular dynamics simulations of a Lennard-Jones system shows interesting differences and similarities. The probability distribution function of the time of residence in a layer shows a peak at very short times and a long-lasting tail. The mean residence time in a layer increases when approaching the interfacial region, slightly in the Lennard-Jones system but strongly in the metallic systems. The motion within the layers, parallel to the interface, can be described as diffusion enhanced (strongly in the case of the outermost layer) with respect to the bulk, for both types of systems, despite its reduced dimensionality in metals
Nanoparticle dispersion in liquid metals by electromagnetically induced acoustic cavitation
International Nuclear Information System (INIS)
Kaldre, Imants; Bojarevičs, Andris; Grants, Ilmārs; Beinerts, Toms; Kalvāns, Matīss; Milgrāvis, Mikus; Gerbeth, Gunter
2016-01-01
Aim of this study is to investigate experimentally the effect of magnetically induced cavitation applied for the purpose of nanoparticle dispersion in liquid metals. The oscillating magnetic force due to the azimuthal induction currents and the axial magnetic field excites power ultrasound in the sample. If the fields are sufficiently high then it is possible to achieve the acoustic cavitation threshold in liquid metals. Cavitation bubble collapses are known to create microscale jets with a potential to break nanoparticle agglomerates and disperse them. The samples are solidified under the contactless ultrasonic treatment and later analyzed by electron microscopy and energy-dispersive X-ray spectroscopy (EDX). It is observed that SiC nanoparticles are dispersed in an aluminum magnesium alloy, whereas in tin the same particles remain agglomerated in micron-sized clusters despite a more intense cavitation.
Liquid-metal-gas heat exchanger for HTGR type reactors
International Nuclear Information System (INIS)
Werth, G.
1980-01-01
The aim of this study is to investigate the heat transfer characteristics of a liquid metal heat exchanger (HE) for a helium-cooled high temperature reactor. A tube-type heat exchanger is considered as well as two direct exchangers: a bubble-type heat exchanger and a heat exchanger according to the spray principle. Experiments are made in order to determine the gas content of bubble-type heat exchangers, the dependence of the droplet diameter on the nozzle diameter, the falling speed of the droplets, the velocity of the liquid jet, and the temperature variation of liquid jets. The computer codes developed for HE calculation are structured so that they may be used for gas/liquid HE, too. Each type of HE that is dealt with is designed by accousting for a technical and an economic assessment. The liquid-lead jet spray is preferred to all other types because of its small space occupied and its simple design. It shall be used in near future in the HTR by the name of lead/helium HE. (GL) [de
International Nuclear Information System (INIS)
Molokov, S.
1994-01-01
It is demonstrated the flow pattern in basic insulating 3-D geometries for the actual and for more advanced liquid-metal blanket concepts and discussed the ways to avoid pressure losses caused by flow redistribution. Flows in several geometries, such as symmetric and non-symmetric 180 turns with and without manifolds, sharp elbows, sharp and linear expansions with and without manifolds, T-junction, etc., have been calculated. They demonstrate high reliability of poloidal concepts of liquid-metal blankets, since they guarantee uniform conditions for heat transfer. If changes of the duct cross-section occur in the plane perpendicular to the magnetic field (ideally a coolant should flow always in the radial-poloidal plane) the disturbances are local and the slug velocity profile is reached roughly at the distance equivalent to one duct width from the manifolds, expansions, etc. The effects of inertia in these flows are unimportant for the determination of the pressure drop and mean velocity profiles in the core of the flow but may favour heat transfer characteristics via instabilities and strongly anisotropic turbulence. (orig./HP) [de
International Nuclear Information System (INIS)
Malang, S.; Mattas, R.
1994-06-01
Liquid metals are attractive candidates for both near-term and long-term fusion applications. The subjects of this comparison are the differences between the two candidate liquid metal breeder materials Li and LiPb for use in breeding blankets in the areas of neutronics, magnetohydrodynamics, tritium control, compatibility with structural materials, heat extraction system, safety, and required R ampersand D program. Both candidates appear to be promising for use in self-cooled breeding blankets which have inherent simplicity with the liquid metal serving as both breeders and coolant. The remaining feasibility question for both breeder materials is the electrical insulation between liquid metal and duct walls. Different ceramic coatings are required for the two breeders, and their crucial issues, namely self-healing of insulator cracks and radiation induced electrical degradation are not yet demonstrated. Each liquid metal breeder has advantages and concerns associated with it, and further development is needed to resolve these concerns
Lattice model of ionic liquid confined by metal electrodes
Girotto, Matheus; Malossi, Rodrigo M.; dos Santos, Alexandre P.; Levin, Yan
2018-05-01
We study, using Monte Carlo simulations, the density profiles and differential capacitance of ionic liquids confined by metal electrodes. To compute the electrostatic energy, we use the recently developed approach based on periodic Green's functions. The method also allows us to easily calculate the induced charge on the electrodes permitting an efficient implementation of simulations in a constant electrostatic potential ensemble. To speed up the simulations further, we model the ionic liquid as a lattice Coulomb gas and precalculate the interaction potential between the ions. We show that the lattice model captures the transition between camel-shaped and bell-shaped capacitance curves—the latter characteristic of ionic liquids (strong coupling limit) and the former of electrolytes (weak coupling). We observe the appearance of a second peak in the differential capacitance at ≈0.5 V for 2:1 ionic liquids, as the packing fraction is increased. Finally, we show that ionic size asymmetry decreases substantially the capacitance maximum, when all other parameters are kept fixed.
Novel thiosalicylate-based ionic liquids for heavy metal extractions
Energy Technology Data Exchange (ETDEWEB)
Leyma, Raphlin; Platzer, Sonja [Institute of Inorganic Chemistry, Faculty of Chemistry, University of Vienna, Waehringer Str. 42, A-1090 Vienna (Austria); Jirsa, Franz [Institute of Inorganic Chemistry, Faculty of Chemistry, University of Vienna, Waehringer Str. 42, A-1090 Vienna (Austria); Department of Zoology, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg (South Africa); Kandioller, Wolfgang, E-mail: wolfgang.kandioller@univie.ac.at [Institute of Inorganic Chemistry, Faculty of Chemistry, University of Vienna, Waehringer Str. 42, A-1090 Vienna (Austria); Krachler, Regina; Keppler, Bernhard K. [Institute of Inorganic Chemistry, Faculty of Chemistry, University of Vienna, Waehringer Str. 42, A-1090 Vienna (Austria)
2016-08-15
Highlights: • Six thiosalicylate-based ammonium and phosphonium ionic liquids (ILs) were newly synthesized. • ILs showed good extraction of cadmium, copper, and zinc. • Phosphonium ILs showed better extraction efficiencies than their ammonium counterparts. - Abstract: This study aims to develop novel ammonium and phosphonium ionic liquids (ILs) with thiosalicylate (TS) derivatives as anions and evaluate their extracting efficiencies towards heavy metals in aqueous solutions. Six ILs were synthesized, characterized, and investigated for their extracting efficacies for cadmium, copper, and zinc. Liquid-liquid extractions of Cu, Zn, or Cd with ILs after 1–24 h using model solutions (pH 7; 0.1 M CaCl{sub 2}) were assessed using flame atomic absorption spectroscopy (F-AAS). Phosphonium-based ILs trihexyltetradecylphosphonium 2-(propylthio)benzoate [P{sub 66614}][PTB] and 2-(benzylthio)benzoate [P{sub 66614}][BTB] showed best extraction efficiency for copper and cadmium, respectively and zinc was extracted to a high degree by [P{sub 66614}][BTB] exclusively.
Equilibrium of current driven rotating liquid metal
International Nuclear Information System (INIS)
Velikhov, E.P.; Ivanov, A.A.; Zakharov, S.V.; Zakharov, V.S.; Livadny, A.O.; Serebrennikov, K.S.
2006-01-01
In view of great importance of magneto-rotational instability (MRI) as a fundamental mechanism for angular momentum transfer in magnetized stellar accretion disks, several research centers are involved in experimental study of MRI under laboratory conditions. The idea of the experiment is to investigate the rotation dynamics of well conducting liquid (liquid metal) between two cylinders in axial magnetic field. In this Letter, an experimental scheme with immovable cylinders and fluid rotation driven by radial current is considered. The analytical solution of a stationary flow was found taking into account the external current. Results of axially symmetric numerical simulations of current driven fluid dynamics in experimental setup geometry are presented. The analytical solution and numerical simulations show that the current driven fluid rotation in axial magnetic field provides the axially homogeneous velocity profile suitable for MRI study in classical statement
Thermodynamics and structure of liquid alkali metals from the charged-hard-sphere reference fluid
International Nuclear Information System (INIS)
Lai, S.K.; Akinlade, O.; Tosi, M.P.
1989-12-01
The evaluation of thermodynamic properties of liquid alkali metals is re-examined in the approach based on the Gibbs-Bogoliubov inequality and using the fluid of charged hard spheres in the mean spherical approximation as reference system, with a view to achieving consistency with the liquid structure factor. The perturbative variational calculation of the Helmholtz free energy is based on an ab initio and highly reliable nonlocal pseudopotential. Only limited improvement is found in the calculated thermodynamic functions, even when full advantage is taken of the two variational parameters inherent in this approach. The role of thermodynamic self-consistency between the equations of state of the reference fluid derived from the routes of the internal energy and of the virial theorem is then discussed, using previous results by Hoye and Stell. An approximate evaluation of the corresponding contribution to the free energy of liquid alkali metals yields appreciable improvements in both the thermodynamic functions and the liquid structure factor. It thus appears that an accurate treatment of thermodynamic self-consistency in the charged-hard-sphere system may help to resolve some of the difficulties that are commonly met in the evaluation of thermodynamic and structural properties of liquid metals. (author). 55 refs, 4 figs, 4 tabs
Acoustic investigation of magnetic susceptibility of liquid metals
International Nuclear Information System (INIS)
Tekuchev, V.V.; Barashkov, B.I.; Ivanova, I.V.; Rygalov, L.N.
2008-01-01
An acoustic method is proposed for studying the specific magnetic susceptibility of metal melts. For the first time, magnetic susceptibilities of francium, beryllium, scandium, yttrium, vanadium, niobium, rhenium, palladium, and platinum in the liquid phase at their melting points, as well as temperature dependences of magnetic susceptibilities of cesium, yttrium, and vanadium over the temperature range from melting points to boiling points have been estimated [ru
Fuel transfer manipulator for liquid metal nuclear reactors
International Nuclear Information System (INIS)
Sturges, R.H.
1983-01-01
A manipulator for transferring fuel assemblies between inclined fuel chutes of a liquid metal nuclear reactor installation. Hoisting means are mounted on a mount supported by beams pivotably attached by pins to the mount and to the floor in such a manner that pivoting of the beams causes movement and tilting of a hoist tube between positions of alignment with the inclined chutes. (author)
Liquid alkali metals and alkali-based alloys as electron-ion plasmas
International Nuclear Information System (INIS)
Tosi, M.P.
1981-06-01
The article reviews the theory of thermodynamic and structural properties of liquid alkali metals and alkali-based alloys, within the framework of linear screening theory for the electron-ion interactions. (author)
Energy driven self-organization in nanoscale metallic liquid films.
Krishna, H; Shirato, N; Favazza, C; Kalyanaraman, R
2009-10-01
Nanometre thick metallic liquid films on inert substrates can spontaneously dewet and self-organize into complex nanomorphologies and nanostructures with well-defined length scales. Nanosecond pulses of an ultraviolet laser can capture the dewetting evolution and ensuing nanomorphologies, as well as introduce dramatic changes to dewetting length scales due to the nanoscopic nature of film heating. Here, we show theoretically that the self-organization principle, based on equating the rate of transfer of thermodynamic free energy to rate of loss in liquid flow, accurately describes the spontaneous dewetting. Experimental measurements of laser dewetting of Ag and Co liquid films on SiO(2) substrates confirm this principle. This energy transfer approach could be useful for analyzing the behavior of nanomaterials and chemical processes in which spontaneous changes are important.
Angular and mass resolved energy distribution measurements with a gallium liquid metal ion source
International Nuclear Information System (INIS)
Marriott, Philip
1987-06-01
Ionisation and energy broadening mechanisms relevant to liquid metal ion sources are discussed. A review of experimental results giving a picture of source operation and a discussion of the emission mechanisms thought to occur for the ionic species and droplets emitted is presented. Further work is suggested by this review and an analysis system for angular and mass resolved energy distribution measurements of liquid metal ion source beams has been constructed. The energy analyser has been calibrated and a series of measurements, both on and off the beam axis, of 69 Ga + , Ga ++ and Ga 2 + ions emitted at various currents from a gallium source has been performed. A comparison is made between these results and published work where possible, and the results are discussed with the aim of determining the emission and energy spread mechanisms operating in the gallium liquid metal ion source. (author)
Directory of Open Access Journals (Sweden)
López-López J. A.
2013-04-01
Full Text Available Heavy metals are normally found, in natural waters, in very low concentrations. Some of them are essential for life in low level; however, in higher level they are toxic. Therefore, analyzing their bio-available fraction is of main interest. Standard methodology is based in the collection of a number of samples from a water body. Collected samples must be stored, pre-treated and then analyzed. Pre-treatment usually involves pre-concentrating the metal, with the corresponding risk of contamination or loss of analyte. This way, punctual information is obtained from every sampling campaign. As an alternative, passive sampling techniques allow the continuous and coupled sampling-pre-treatment for heavy metals analysis, giving a better approach in the characterization of the studied water body. Liquid phase micro-extraction (LPME is a green analytical alternative for liquid-liquid extraction that promotes a reduction of sample volume, solvent needed and waste generation. Using these systems, polypropylene hollow fibers (HF with pores in their walls can be used. A few micro-liters of organic solvent are supported in the pores. The sample is placed in the outer part of the fiber and a receiving phase is placed in its inner part, allowing continuous liquid extraction of the metal from the sample. Several fibers with different physical features have been employed to analyzed total concentration and bio-availability of some heavy metals (Ag, Ni, Cu in natural water samples. Thanks to fibers configuration, devices for passive sampling based in HF-LPME could be designed. Advantages of this methodology over existing ones are supported because the receiving phase is liquid. As a consequence, retained metals do not need to be eluted from the acceptor prior to instrumental analysis.
Yang, Fan; Kubota, Fukiko; Baba, Yuzo; Kamiya, Noriho; Goto, Masahiro
2013-06-15
The recycling of rare earth metals from phosphor powders in waste fluorescent lamps by solvent extraction using ionic liquids was studied. Acid leaching of rare earth metals from the waste phosphor powder was examined first. Yttrium (Y) and europium (Eu) dissolved readily in the acid solution; however, the leaching of other rare earth metals required substantial energy input. Ionization of target rare earth metals from the waste phosphor powders into the leach solution was critical for their successful recovery. As a high temperature was required for the complete leaching of all rare earth metals, ionic liquids, for which vapor pressure is negligible, were used as an alternative extracting phase to the conventional organic diluent. An extractant, N, N-dioctyldiglycol amic acid (DODGAA), which was recently developed, showed a high affinity for rare earth metal ions in liquid-liquid extraction although a conventional commercial phosphonic extractant did not. An effective recovery of the rare earth metals, Y, Eu, La and Ce, from the metal impurities, Fe, Al and Zn, was achieved from the acidic leach solution of phosphor powders using an ionic liquid containing DODGAA as novel extractant system. Copyright © 2013 Elsevier B.V. All rights reserved.
Liquid metal MHD studies with non-magnetic and ferro-magnetic structural material
Energy Technology Data Exchange (ETDEWEB)
Patel, A., E-mail: anipatel2009@gmail.com [Institute of Plasma Research, Gandhinagar 382428, Gujarat (India); Bhattacharyay, R. [Institute of Plasma Research, Gandhinagar 382428, Gujarat (India); Swain, P.K.; Satyamurthy, P. [Bhabha Atomic Research Center, Mumbai 400085, Maharashtra (India); Sahu, S.; Rajendrakumar, E. [Institute of Plasma Research, Gandhinagar 382428, Gujarat (India); Ivanov, S.; Shishko, A.; Platacis, E.; Ziks, A. [Institute of Physics, University of Latvia, Salaspils 2169 (Latvia)
2014-10-15
Highlights: • Effect of structural material on liquid metal MHD phenomena is studied. • Two identical test sections, one made of SS316L (non-magnetic) and other made of SS430 (ferromagnetic) structural material, are considered. • Wall electric potential and liquid metal pressure drop are compared under various experimental conditions. • Experimental results suggest screening of external magnetic field for SS430 material below the saturation magnetic field. - Abstract: In most of the liquid metal MHD experiments reported in the literature to study liquid breeder blanket performance, SS316/SS304 grade steels are used as the structural material which is non-magnetic. On the other hand, the structural material for fusion blanket systems has been proposed to be ferritic martensitic grade steel (FMS) which is ferromagnetic in nature. In the recent experimental campaign, liquid metal MHD experiments have been carried out with two identical test sections: one made of SS316L (non-magnetic) and another with SS430 (ferromagnetic), to compare the effect of structural materials on MHD phenomena for various magnetic fields (up to 4 T). The maximum Hartmann number and interaction number are 1047 and 300, respectively. Each test section consists of square channel (25 mm × 25 mm) cross-section with two U bends, with inlet and outlet at the middle portion of two horizontal legs, respectively. Pb–Li enters into the test section through a square duct and distributed into two parallel paths through a partition plate. In each parallel path, it travels ∼0.28 m length in plane perpendicular to the magnetic field and faces two 90° bends before coming out of the test section through a single square duct. The wall electrical potential and MHD pressure drop across the test sections are compared under identical experimental conditions. Similar MHD behavior is observed with both the test section at higher value of the magnetic field (>2 T)
Mechanical annealing in the flow of supercooled metallic liquid
International Nuclear Information System (INIS)
Zhang, Meng; Dai, Lan Hong; Liu, Lin
2014-01-01
Flow induced structural evolution in a supercooled metallic liquid Vit106a (Zr 58.5 Cu 15.6 Al 10.3 Ni 12.8 Nb 2.8 , at. %) was investigated via uni-axial compression combined with differential scanning calorimeter (DSC). Compression tests at strain rates covering the transition from Newtonian flow to non-Newtonian flow and at the same strain rate 2 × 10 −1 s −1 to different strains were performed at the end of glass transition (T g-end = 703 K). The relaxation enthalpies measured by DSC indicate that the samples underwent non-Newtonian flow contain more free volume than the thermally annealed sample (703 K, 4 min), while the samples underwent Newtonian flow contain less, namely, the free volume of supercooled metallic liquids increases in non-Newtonian flow, while decreases in Newtonian flow. The oscillated variation of the relaxation enthalpies of the samples deformed at the same strain rate 2 × 10 −1 s −1 to different strains confirms that the decrease of free volume was caused by flow stress, i.e., “mechanical annealing.” Micro-hardness tests were also performed to show a similar structural evolution tendency. Based on the obtained results, the stress-temperature scaling in the glass transition of metallic glasses are supported experimentally, as stress plays a role similar to temperature in the creation and annihilation of free volume. In addition, a widening perspective angle on the glass transition of metallic glasses by exploring the 3-dimensional stress-temperature-enthalpy phase diagram is presented. The implications of the observed mechanical annealing effect on the amorphous structure and the work-hardening mechanism of metallic glasses are elucidated based on atomic level stress model
NATO Advanced Research Workshop on Incommensurate Crystals, Liquid Crystals, and Quasi-Crystals
Clark, N
1988-01-01
In this NATO-sponsored Advanced Research Workshop we succeeded in bringing together approximately forty scientists working in the three main areas of structurally incommensurate materials: incommensurate crystals (primarily ferroelectric insulators), incommensurate liquid crystals, and metallic quasi-crystals. Although these three classes of materials are quite distinct, the commonality of the physics of the origin and descrip tion of these incommensurate structures is striking and evident in these proceedings. A measure of the success of this conference was the degree to which interaction among the three subgroups occurred; this was facili tated by approximately equal amounts of theory and experiment in the papers presented. We thank the University of Colorado for providing pleasant housing and conference facilities at a modest cost, and we are especially grate ful to Ann Underwood, who retyped all the manuscripts into camera-ready form. J. F. Scott Boulder, Colorado N. A. Clark v CONTENTS PART I: INCO...
Liquid metal MHD generator systems
International Nuclear Information System (INIS)
Satyamurthy, P.; Dixit, N.S.; Venkataramani, N.; Rohatgi, V.K.
1985-01-01
Liquid Metal MHD (LMMHD) Generator Systems are becoming increasingly important in space and terrestrial applications due to their compactness and versatility. This report gives the current status and economic viability of LMMHD generators coupled to solar collectors, fast breeder reactors, low grade heat sources and conventional high grade heat sources. The various thermodynamic cycles in the temperatures range of 100degC-2000degC have been examined. The report also discusses the present understanding of various loss mechanisms inherent in LMMHD systems and the techniques for overcoming these losses. A small mercury-air LMMHD experimental facility being set up in Plasma Physics Division along with proposals for future development of this new technology is also presented in this report. (author)
Poisoning of liquid membrane carriers in extraction of metal ions
International Nuclear Information System (INIS)
Wang, Yuchun; Wang, Dexian
1992-01-01
As means of effective separation and preconcentration, emulsion liquid membranes (ELMs) have found application in many fields including biochemical separation, wastewater treatment, hydrometallurgy, and preconcentration in analytical chemistry. In the extraction of desired metal (scandium, mixed rare earths) ions using chelating extractants (TTA, HDEHP) as liquid membrane carriers, the carriers will become poisoned owing to the presence of even minute quantity of certain high ionic potential ions in the feed solution. The reason for the poisoning of carriers is that those ions have so much greater affinity than the desired ions for the membrane carrier that the ion-carrier coordination compound cannot be stripped at the interior interface of the membrane and gradually no more free carrier transports any metal ions across the membrane. The calculated results are in agreement with the experiments, and methods to avoid the poisoning are given in the paper
Metal nanoparticles in liquid phase catalysis; from recent advances to future goals.
Zahmakıran, Mehmet; Ozkar, Saim
2011-09-01
Metal nanoparticles have attracted much attention over the last decade owing to their unique properties, different to their bulk counterparts, which pave the way for their application in different fields from materials science and engineering to biomedical applications. Of particular interest, the use of metal nanoparticles in catalysis has brought superior efficiency in terms of activity, selectivity and lifetime to heterogeneous catalysis. This article reviews the recent developments in the synthesis routes and the catalytic performance of metal nanoparticles depending on the solvent used for various organic and inorganic transformations. Additionally, we also discuss the prevalent complications and their possible solutions plus future prospects in the field of nanocatalysis.
The Recovery of Zinc Heavy Metal from Industrial Liquid Waste
International Nuclear Information System (INIS)
Panggabean, Sahat M.
2000-01-01
It had been studied the recovery of zinc heavy metal from liquid waste of electroplating industry located at East Jakarta. The aim of this study was to minimize the waste arisen from industrial activities by taking out zinc metal in order to reused on-site. The method of recovery was two steps precipitation using NaOH reagent and pH variation. The first step of precipitation at pH optimum around 6 yielded iron metal. The second step at pH optimum around 10 yielded zinc metal. The zinc metal was taken out assessed to the possibility of reused at that fabric. By applying its, it will yield the volume reduction of sludge waste about 36.1% or 53.2% of zinc metal containing in the waste. It means the cost of waste treatment will be lower. Beside its, the effluent arisen from the method had fulfill the maximum limit and it allowed to release to the environment. (author)
Structure of liquid alkali metals as electron-ion plasmas
International Nuclear Information System (INIS)
Chaturvedi, D.K.; Senatore, G.; Tosi, M.P.
1980-08-01
The static structure factor of liquid alkali metals near freezing, and its dependence on temperature and pressure, are evaluated in an electron-ion plasma model from an accurate theoretical determination of the structure factor of the one-component classical plasma and electron-screening theory. Very good agreement is obtained with the available experimental data. (author)
International Nuclear Information System (INIS)
Kassikova, N.I.; Kassikov, A.G.; Balabanov, Yu.I.; Petrov, V.B.; Kalinnikov, V.T.
2003-01-01
Such rare metals as niobium and tantalum are important strategic materials underlying many of the modern advanced technologies. Since the extraction and processing of rare metal concentrates from own deposits has diminished abruptly in recent years, it is essential to look into the possibility of extracting these elements from various production wastes. This work discusses liquid-liquid extraction and purification of niobium, tantalum and titanium from process solutions of loparite, perovskite and sphene concentrate decomposition with sulphuric and hydrochloric acids; niobium from lithium niobate production wastes decomposed by hydrochloric acid; and tantalum from tantalum capacitor and heat-resistant alloy wastes. (Original)
Heaters to simulate fuel pins for heat transfer tests in single-phase liquid-metal-flow
International Nuclear Information System (INIS)
Casal, V.; Graf, E.; Hartmann, W.
1976-09-01
The development of heaters for thermal simulation of the fuel elements of liquid metal cooled fast breeder reactors (SNR) is reported. Beginning with the experimental demands various heating methods are discussed for thermodynamic investigations of the heat transfer in liquid metals. Then a preferred heater rod is derived to simulate the fuel pins of a SNR. Finally it is reported on the fabrication and the operation practice. (orig.) [de
Point dipole as a magnetic obstacle in liquid metal duct flow
Tympel, Saskia; Boeck, Thomas; Krasnov, Dmitry; Schumacher, Jörg
2011-11-01
Lorentz force velocimetry is a new contactless technique to measure the velocities of hot and agressive conductiong liquids. The measurement of the Lorentz force on the magnet is highly sensitive to the velocity profile that is influenced by the magnetic field. Thus the knowlegde of the flow transformation and the influence of an inhomogeneous local magnetic field on liquid metal flow is essential for obtaining velocity information from the measured forces. We consider liquid metal flow in a square duct with electrically insulating walls under the influence of a magnetic point dipole using three-dimensional direct numerical simulations with a finite-difference method. The dipole acts as a magnetic obstacle. A wide range of parameters affects the created wake. In this canonical setting, we study the modification of the flow for different Hartmann and Reynolds numbers. We observe a strong dependence of the magnetic obstacle effect and the corresponding Lorentz force on the orientation of the dipole as well as on its position. The authors acknowledge the support of the Deutsche Forschungsgemeinschaft.
Calcium-Antimony Alloys as Electrodes for Liquid Metal Batteries
Energy Technology Data Exchange (ETDEWEB)
Ouchi, T; Kim, H; Ning, XH; Sadoway, DR
2014-08-08
The performance of a calcium-antimony (Ca-Sb) alloy serving as the positive electrode in a Ca vertical bar vertical bar Sb liquid metal battery was investigated in an electrochemical cell, Ca(in Bi) vertical bar LiCl-NaCl-CaCl2 vertical bar Ca(in Sb). The equilibrium potential of the Ca-Sb electrode was found to lie on the interval, 1.2-0.95 V versus Ca, in good agreement with electromotive force (emf) measurements in the literature. During both alloying and dealloying of Ca at the Sb electrode, the charge transfer and mass transport at the interface are facile enough that the electrode potential varies linearly from 0.95 to 0.75 V vs Ca(s) as current density varies from 50 to 500 mA cm(-2). The discharge capacity of the Ca vertical bar vertical bar Sb cells increases as the operating temperature increases due to the higher solubility and diffusivity of Ca in Sb. The cell was successfully cycled with high coulombic efficiency (similar to 100%) and small fade rate (<0.01% cycle(-1)). These data combined with the favorable costs of these metals and salts make the Ca vertical bar vertical bar Sb liquid metal battery attractive for grid-scale energy storage. (C) The Author(s) 2014. Published by ECS. All rights reserved.
The Advanced Neutron Source liquid deuterium cold source
International Nuclear Information System (INIS)
Lucas, A.T.
1995-08-01
The Advanced Neutron Source will employ two cold sources to moderate neutrons to low energy (<10 meV). The cold neutrons produced are then passed through beam guides to various experiment stations. Each cold source moderator is a sphere of 410-mm internal diameter. The moderator material is liquid deuterium flowing at a rate of 1 kg/s and maintained at subcooled temperatures at all points of the circuit, to prevent boiling. Nuclear beat deposited within the liquid deuterium and its containment structure totals more than 30 kW. All of this heat is removed by the liquid deuterium, which raises its temperature by 5 K. The liquid prime mover is a cryogenic circulator that is situated in the return leg of the flow loop. This arrangement minimizes the heat added to the liquid between the heat exchanger and the moderator vessel, allowing the moderator to be operated at the minimum practical temperature. This report describes the latest thinking at the time of project termination. It also includes the status of various systems at that time and outlines anticipated directions in which the design would have progressed. In this regard, some detail differences between this report and official design documents reflect ideas that were not approved at the time of closure but are considered noteworthy
Analysis of gas-liquid metal two-phase flows using a reactor safety analysis code SIMMER-III
International Nuclear Information System (INIS)
Suzuki, Tohru; Tobita, Yoshiharu; Kondo, Satoru; Saito, Yasushi; Mishima, Kaichiro
2003-01-01
SIMMER-III, a safety analysis code for liquid-metal fast reactors (LMFRs), includes a momentum exchange model based on conventional correlations for ordinary gas-liquid flows, such as an air-water system. From the viewpoint of safety evaluation of core disruptive accidents (CDAs) in LMFRs, we need to confirm that the code can predict the two-phase flow behaviors with high liquid-to-gas density ratios formed during a CDA. In the present study, the momentum exchange model of SIMMER-III was assessed and improved using experimental data of two-phase flows containing liquid metal, on which fundamental information, such as bubble shapes, void fractions and velocity fields, has been lacking. It was found that the original SIMMER-III can suitably represent high liquid-to-gas density ratio flows including ellipsoidal bubbles as seen in lower gas fluxes. In addition, the employment of Kataoka-Ishii's correlation has improved the accuracy of SIMMER-III for gas-liquid metal flows with cap-shape bubbles as identified in higher gas fluxes. Moreover, a new procedure, in which an appropriate drag coefficient can be automatically selected according to bubble shape, was developed. Through this work, the reliability and the precision of SIMMER-III have been much raised with regard to bubbly flows for various liquid-to-gas density ratios
Continuous process for selective metal extraction with an ionic liquid
Parmentier, D.; Paradis, S.; Metz, S.J.; Wiedmer, S.K.; Kroon, M.C.
2016-01-01
This work describes for the first time a continuous process for selective metal extraction with an ionic liquid (IL) at room temperature. The hydrophobic fatty acid based IL tetraoctylphosphonium oleate ([P8888][oleate]) was specifically chosen for its low viscosity and high selectivity towards
International Nuclear Information System (INIS)
2013-05-01
The International Project on Innovative Nuclear Reactors and Fuel Cycles (INPRO) was launched in 2000, based on a resolution by the IAEA General Conference (GC(44)/RES/21). INPRO aims at helping to ensure that nuclear energy is available in the twenty-first century in a sustainable manner, and seeks to bring together all interested Member States, both technology holders and technology users, to jointly consider actions to achieve desired innovations. INPRO is taking care of the specific needs of developing countries. One of the aims of INPRO is to develop options for enhanced sustainability through promotion of technical and institutional innovations in nuclear energy technology through collaborative projects among IAEA Member States. Collaboration among INPRO members is fostered on selected innovative nuclear technologies to bridge technology gaps. Collaborative projects have been selected so that they complement other national and international R and D activities. The INPRO Collaborative Project COOL on Investigation of Technological Challenges Related to the Removal of Heat by Liquid Metal and Molten Salt Coolants from Reactor Cores Operating at High Temperatures investigated the technological challenges of cooling reactor cores that operate at high temperatures in advanced fast reactors, high temperature reactors and accelerator driven systems by using liquid metals and molten salts as coolants. The project was initiated in 2008 and was led by India; experts from Brazil, China, Germany, India, Italy and the Republic of Korea participated and provided chapters of this report. The INPRO Collaborative Project COOL addressed the following fields of research regarding liquid metal and molten salt coolants: (i) survey of thermophysical properties; (ii) experimental investigations and computational fluid dynamics studies on thermohydraulics, specifically pressure drop and heat transfer under different operating conditions; (iii) monitoring and control of coolant
International Nuclear Information System (INIS)
Saito, Masaki
2000-03-01
Feasibility study of the liquid-metal MHD power generation system combined with the high-density two-phase natural circulation has been performed for the applicability to the simple, autonomic energy conversion system of the liquid-metal cooled fast reactor. The present system has many promising aspects not only in the energy conversion process, but also in safety and economical improvements of the liquid-metal cooled fast reactor. For example, the high cycle efficiency can be expected because of the similarity of the present cycle to the Ericsson cycle. Sodium-Water Interaction problem can be excluded by proper combination of the working fluids. As the economical feature, the present system is so simple that the liquid-metal main circular pump, the steam turbine generator, and even the steam generator can be excluded if the thermodynamic working fluid is injected directly into the high temperature liquid metal MHD working fluid. In addition, the present system has the potential to be applied to various heat sources including solar energy because of the high flexibility of the operation temperature. In the present paper, as the first step of the feasibility study, the cycle analyses were performed to examine the effects of the main system parameters on the fundamental characteristics of the system. It is found that the cycle efficiency of the present system is enough competitive with that of the conventional steam turbine system. It is, however, found that the cycle efficiency depends strongly on the gas-liquid slip ratio in the two-phase flow channel. As the conclusions, it is recommended to perform experimental study to obtain the fundamental data, such as the gas-liquid slip ratio in the high-density liquid-metal two-phase natural circulation. (author)
Developing remote techniques for liquid metal reactors
International Nuclear Information System (INIS)
Fenemore, Peter
1987-01-01
Three devices have been designed in Britain to meet the need for special remote equipment and techniques required to inspect the reactor vessel and internals of liquid metal reactors. The ''Links Manipulator Under-Sodium Viewing System'' - a device to be used for the surveillance of reactor internals, which are submerged in sodium. An ''Automatic Guided Vehicle'' - a free roving vehicle to be used to survey the externals of the reactor vessel. The ''Snake Manipulator'' - an articulated arm used to gain access to restricted areas. (author)
Design analysis of liquid metal pipe supports
International Nuclear Information System (INIS)
Margolin, L.L.; LaSalle, F.R.
1979-02-01
Design guidelines pertinent to liquid metal pipe supports are presented. The numerous complex conditions affecting the support stiffness and strength are addressed in detail. Topics covered include modeling of supports for natural frequency and stiffness calculations, support hardware components, formulas for deflection due to torsion, plate bending, and out-of-plane flexibility. A sample analysis and a discussion on stress analysis of supports are included. Also presented are recommendations for design improvements for increasing the stiffness of pipe supports and which were utilized in the FFTF system
Performance of metal and oxide fuels during accidents in a large liquid metal cooled reactor
International Nuclear Information System (INIS)
Cahalan, J.; Wigeland, R.; Friedel, G.; Kussmaul, G.; Royl, P.; Moreau, J.; Perks, M.
1990-01-01
In a cooperative effort among European and US analysts, an assessment of the comparative safety performance of metal and oxide fuels during accidents in a large (3500 MWt), pool-type, liquid-metal-cooled reactor (LMR) was performed. The study focused on three accident initiators with failure to scram: the unprotected loss-of-flow (ULOF), the unprotected transient overpower (UTOP), and the unprotected loss-of-heat-sink (ULOHS). Emphasis was placed on identification of design features that provide passive, self-limiting responses to upset conditions, and quantification of relative safety margins. The analyses show that in ULOF and ULOHS sequences, metal-fueled LMRs with pool-type primary systems provide larger temperature margins to coolant boiling than oxide-fueled reactors of the same design. 3 refs., 4 figs
Effect of electromagnetic coupling on MHD flow in the manifold of fusion liquid metal blanket
Energy Technology Data Exchange (ETDEWEB)
Chen, Hongli, E-mail: hlchen1@ustc.edu.cn; Meng, Zi; Feng, Jingchao; He, Qingyun
2014-10-15
In fusion liquid metal (LM) blanket, magnetohydrodynamics (MHD) effects will dominate the flow patterns and the heat transfer characteristics of the liquid metal flow. Manifold is a key component in LM blanket in charge of distributing or collecting the liquid metal coolant. In this region, the complex three dimensional MHD phenomena will be occurred, and the velocity, pressure and flow rate distributions may be dramatically influenced. One important aspect is the electromagnetic coupling effect resulting from an exchange of electric currents between two neighboring fluid domains that can lead to modifications of flow distribution and pressure drop compared to that in electrical separated channels. Understanding the electromagnetic coupling effect in manifold is necessary to optimize the liquid metal blanket design. In this work, a numerical study was carried out to investigate the effect of electromagnetic coupling on MHD flow in a manifold region. The typical manifold geometry in LM blanket was considered, a rectangular supply duct entering a rectangular expansion area, finally feeding into 3 rectangular parallel channels. This paper investigated the effect of electromagnetic coupling on MHD flow in a manifold region. Different electromagnetic coupling modes with different combinations of electrical conductivity of walls were studied numerically. The flow distribution and pressure drop of these modes have been evaluated.
International Nuclear Information System (INIS)
Suarez, Francisco; Parekh, Dishit P.; Ladd, Collin; Vashaee, Daryoosh; Dickey, Michael D.; Öztürk, Mehmet C.
2017-01-01
Highlights: •Flexible thermoelectric generator (TEG) with bulk legs. •Flexible thermoelectric generator with liquid metal interconnects. •Flexible TEG with potential to match the performance of rigid TEGs. •Flexible TEG for wearable electronics. -- Abstract: Interest in wearable electronics for continuous, long-term health and performance monitoring is rapidly increasing. The reduction in power levels consumed by sensors and electronic circuits accompanied by the advances in energy harvesting methods allows for the realization of self-powered monitoring systems that do not have to rely on batteries. For wearable electronics, thermoelectric generators (TEGs) offer the unique ability to continuously convert body heat into usable energy. For body harvesting, it is preferable to have TEGs that are thin, soft and flexible. Unfortunately, the performances of flexible modules reported to date have been far behind those of their rigid counterparts. This is largely due to lower efficiencies of the thermoelectric materials, electrical or thermal parasitic losses and limitations on leg dimensions posed by the synthesis techniques. In this work, we present an entirely new approach and explore the possibility of using standard bulk legs in a flexible package. Bulk thermoelectric legs cut from solid ingots are far superior to thermoelectric materials synthesized using other techniques. A key enabler of the proposed technology is the use of EGaIn liquid metal interconnects, which not only provide extremely low interconnect resistance but also stretchability with self-healing, both of which are essential for flexible TE modules. The results suggest that this novel approach can finally produce flexible TEGs that have the potential to challenge the rigid TEGs and provide a pathway for the realization of self-powered wearable electronics.
Thermal hydraulic considerations in liquid-metal-cooled components of tokamak fusion reactors
International Nuclear Information System (INIS)
Picologlou, B.F.; Reed, C.B.; Hua, T.Q.
1989-01-01
The basic considerations of MHD thermal hydraulics for liquid-metal-cooled blankets and first walls of tokamak fusion reactors are discussed. The liquid-metal MHD program of Argonne National Laboratory (ANL) dedicated to analytical and experimental investigations of reactor relevant MHD flows and development of relevant thermal hydraulic design tools is presented. The status of the experimental program and examples of local velocity measurements are given. An account of the MHD codes developed to date at ANL is also presented as is an example of a 3-D thermal hydraulic analysis carried out with such codes. Finally, near term plans for experimental investigations and code development are outlined. 20 refs., 8 figs., 1 tab
Heat-driven liquid metal cooling device for the thermal management of a computer chip
Energy Technology Data Exchange (ETDEWEB)
Ma Kunquan; Liu Jing [Cryogenic Laboratory, PO Box 2711, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080 (China)
2007-08-07
The tremendous heat generated in a computer chip or very large scale integrated circuit raises many challenging issues to be solved. Recently, liquid metal with a low melting point was established as the most conductive coolant for efficiently cooling the computer chip. Here, by making full use of the double merits of the liquid metal, i.e. superior heat transfer performance and electromagnetically drivable ability, we demonstrate for the first time the liquid-cooling concept for the thermal management of a computer chip using waste heat to power the thermoelectric generator (TEG) and thus the flow of the liquid metal. Such a device consumes no external net energy, which warrants it a self-supporting and completely silent liquid-cooling module. Experiments on devices driven by one or two stage TEGs indicate that a dramatic temperature drop on the simulating chip has been realized without the aid of any fans. The higher the heat load, the larger will be the temperature decrease caused by the cooling device. Further, the two TEGs will generate a larger current if a copper plate is sandwiched between them to enhance heat dissipation there. This new method is expected to be significant in future thermal management of a desk or notebook computer, where both efficient cooling and extremely low energy consumption are of major concern.
Heat-driven liquid metal cooling device for the thermal management of a computer chip
International Nuclear Information System (INIS)
Ma Kunquan; Liu Jing
2007-01-01
The tremendous heat generated in a computer chip or very large scale integrated circuit raises many challenging issues to be solved. Recently, liquid metal with a low melting point was established as the most conductive coolant for efficiently cooling the computer chip. Here, by making full use of the double merits of the liquid metal, i.e. superior heat transfer performance and electromagnetically drivable ability, we demonstrate for the first time the liquid-cooling concept for the thermal management of a computer chip using waste heat to power the thermoelectric generator (TEG) and thus the flow of the liquid metal. Such a device consumes no external net energy, which warrants it a self-supporting and completely silent liquid-cooling module. Experiments on devices driven by one or two stage TEGs indicate that a dramatic temperature drop on the simulating chip has been realized without the aid of any fans. The higher the heat load, the larger will be the temperature decrease caused by the cooling device. Further, the two TEGs will generate a larger current if a copper plate is sandwiched between them to enhance heat dissipation there. This new method is expected to be significant in future thermal management of a desk or notebook computer, where both efficient cooling and extremely low energy consumption are of major concern
PREFACE: 13th International Conference on Liquid and Amorphous Metals
Popel, Pjotr; Gelchinskii, Boris; Sidorov, Valeriy; Son, Leonid; Sabirzjanov, Alexandre
2007-06-01
The state of the art in the field of liquid and amorphous metals and alloys is regularly updated through two series of complementary international conferences, the LAM (Liquid and Amorphous Metals) and the RQ (Rapidly Quenched Materials). The first series of the conferences started as LM-1 in 1966 at Brookhaven for the basic understanding of liquid metals. The subsequent LM conferences were held in Tokyo (1972) and Bristol (1976). The conference was renewed in Grenoble (1980) as a LAM conference including amorphous metals and continued in Los Angeles (1983), Garmisch-Partenkirchen (1986), Kyoto (1989), Vienna (1992), Chicago (1995), Dortmund (1998), Yokohama (2001) and Metz (2004). The conferences are mainly devoted to liquid and amorphous metals and alloys. However, communications on some non-metallic systems such as semi conductors, quasicrystals etc, were accepted as well. The conference tradition strongly encourages the participation of junior researchers and graduate students. The 13th conference of the LAM series was organized in Ekaterinburg, Russia, by the Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences (IMet UB RAS) and Ural State Pedagogical University (USPU) and held on 8-13 July 2007 under the chairmanship of Professors Pjotr Popel (USPU) and Boris Gelchinskii (IMet UB RAS). There were 242 active and about 60 guest participants from 20 countries who attended the conference. There were no parallel sessions and all oral reports were separated into three groups: invited talks (40 min), full-scale (25 min) and brief (15 min) oral reports. The program included 10 sessions, ranging from purely theoretical subjects to technological application of molten and amorphous alloys. The following sessions took place: A) Electronic structure and transport, magnetic properties; B) Phase transitions; C) Structure; D) Atomic dynamics and transport; E) Thermodynamics; F) Modelling, simulation; G) Surface and interface; H) Mechanical properties
International Nuclear Information System (INIS)
Endo, H.; Ninokata, H.; Netchaev, A.; Sawada, T.
2001-01-01
Nuclear energy is the only effective alternative energy source to fossil fuels in the next century. Therefore future nuclear power plants should satisfy the following three requirements: i) multiple energy conversion capability with high temperature not only for electricity generation but also for hydrogen production, ii) extended siting capability so as to eliminate on-site refuelling, and iii) passive safety features. An aim of this paper is to describe the basic concept of the multi-purpose liquid metallic fuelled fast reactor system (MPFR). The MPFR introduces the U-Pu-X (X: Mn, Fe, Co) liquid metallic alloy with Ta and Ta/TaC structural materials, and satisfies all of the conditions listed above based on the following characteristics of the liquid metallic fuel: high temperature operation between 650 deg C (sodium-cooled system) and 1 200 deg C (lead-cooled system), a core lifetime of 15-30 years without radiation damage of fuel materials, and enhanced passive safety by the thermal expansion of liquid fuel and the avoidance of re-criticality due to local core fuel dispersion at fuel failure events. (authors)
International Nuclear Information System (INIS)
Wang Li; Liu Xiangfa; Zhang Yanning; Yang Hua; Chen Ying; Bian Xiufang
2003-01-01
Much more attention has been paid to the microstructure of liquid metal under non-ordinary condition recently. In this Letter, the pair correlation function (PCF), together with internal energy of sheared super-cooled liquid Co as a function of temperature has been calculated by molecular dynamics simulation based upon the embedded atom method (EAM) and analyzed compared to that under normal condition. The finding indicates that there exist three obvious peaks of PCF for liquid Co; while as the shear stress is applied to the liquid, the first and second peaks of PCF become lower, the third peak disappeared. The concentric shell structure representing short-range order of liquid still exists, however, it is weakened by the addition of shear stress, leading to the increases of disordering degree of liquid metal. The curves of energy versus temperature suggest the higher crystalline temperature compared to that under normal condition at the same cooling rate. In addition, the viscosity of super-liquid Co is calculated by non-equilibrium molecular dynamics (NEMD)
International Nuclear Information System (INIS)
Manojkumar, Kasina; Sivaramakrishna, Akella; Vijayakrishna, Kari
2016-01-01
Metal nanoparticles (NPs) are a subject of global interest in research community due to their diverse applications in various fields of science. The stabilization of these metal NPs is of great concern in order to avoid their agglomerization during their applications. There is a huge pool of cations and anions available for the selection of ionic liquids (ILs) as stabilizers for the synthesis of metal NPs. ILs are known for their tunable nature allowing the fine tuning of NPs size and solubility by varying the substitutions on the heteroatom as well as the counter anions. However, there has been a debate over the stability of metal NPs stabilized by ILs over a long period of time and also upon their recycling and reuse in organocatalytic reactions. ILs covalently attached to solid supports (SILLPs) have given a new dimension for the stabilization of metal NPs as well as their separation, recovery, and reuse in organocatalytic reactions. Poly(ILs) (PILs) or polyelectrolytes have created a significant revolution in the polymer science owing to their characteristic properties of polymers as well as ILs. This dual behavior of PILs has facilitated the stabilization of PIL-stabilized metal NPs over a long period of time with negligible or no change in particle size, stability, and size distribution upon recycling in catalysis. This review provides an insight into the different types of imidazolium-based ILs, supported ILs, and PILs used so far for the stabilization of metal NPs and their applications as a function of their cations and counter anions.
Thermoelectric-Driven Liquid-Metal Plasma-Facing Structures (TELS) Final Report
Energy Technology Data Exchange (ETDEWEB)
Ruzic, David [Univ. of Illinois, Urbana-Champaign, IL (United States)
2016-12-17
The Thermoelectric-Driven Liquid-Metal Plasma-Facing Structures (TELS) project was able to establish the experimental conditions necessary for flowing liquid metal surfaces in order to be utilized as surfaces facing fusion relevant energetic plasma flux. The work has also addressed additional developments along with progressing along the timeline detailed in the proposal. A no-cost extension was requested to conduct other relevant experiment- specifically regarding the characterization droplet ejection during energetic plasma flux impact. A specially designed trench module, which could accommodate trenches with different aspect ratios was fabricated and installed in the TELS setup and plasma gun experiments were performed. Droplet ejection was characterized using high speed image acquisition and also surface mounted probes were used to characterize the plasma. The Gantt chart below had been provided with the original proposal, indicating the tasks to be performed in the third year of funding. These tasks are listed above in the progress report outline, and their progress status is detailed below.
A Handy Liquid Metal Based Non-Invasive Electrophoretic Particle Microtrap
Directory of Open Access Journals (Sweden)
Lu Tian
2018-05-01
Full Text Available A handy liquid metal based non-invasive particle microtrap was proposed and demonstrated in this work. This kind of microtrap can be easily designed and fabricated at any location of a microfluidic chip to perform precise particle trapping and releasing without disturbing the microchannel itself. The microsystem demonstrated in this work utilized silicon oil as the continuous phase and fluorescent particles (PE-Cy5, SPHEROTM Fluorescent Particles, BioLegend, San Diego, CA, USA, 10.5 μm as the target particles. To perform the particle trapping, the micro system utilized liquid-metal-filled microchannels as noncontact electrodes to generate different patterns of electric field inside the fluid channel. According to the experimental results, the target particle can be selectively trapped and released by switching the electric field patterns. For a better understanding the control mechanism, a numerical simulation of the electric field was performed to explain the trapping mechanism. In order to verify the model, additional experiments were performed and are discussed.
Specific power of liquid-metal-cooled reactors
International Nuclear Information System (INIS)
Dobranich, D.
1987-10-01
Calculations of the core specific power for conceptual space-based liquid-metal-cooled reactors, based on heat transfer considerations, are presented for three different fuel types: (1) pin-type fuel; (2) cermet fuel; and (3) thermionic fuel. The calculations are based on simple models and are intended to provide preliminary comparative results. The specific power is of interest because it is a measure of the core mass required to produce a given amount of power. Potential problems concerning zero-g critical heat flux and loss-of-coolant accidents are also discussed because these concerns may limit the core specific power. Insufficient experimental data exists to accurately determine the critical heat flux of liquid-metal-cooled reactors in space; however, preliminary calculations indicate that it may be a concern. Results also indicate that the specific power of the pin-type fuels can be increased significantly if the gap between the fuel and the clad is eliminated. Cermet reactors offer the highest specific power because of the excellent thermal conductivity of the core matrix material. However, it may not be possible to take fuel advantage of this characteristic when loss-of-coolant accidents are considered in the final core design. The specific power of the thermionic fuels is dependent mainly on the emitter temperature. The small diameter thermionic fuels have specific powers comparable to those of pin-type fuels. 11 refs., 12 figs, 2 tabs
Characterization of liquid metal reactor materials
International Nuclear Information System (INIS)
Kuk, I. H.; Ryu, W. S.; Kim, H. H. and others
1999-03-01
The objectives of this report were to assess the material requirements for LMR environment, to select the optimum candidates for KALIMER components, to characterize the performance for establishing a database of the structural materials for KALIMER, and to develop the basic material technologies for the localization of the advanced materials. Stainless steel ingots were melted by VIM and hot-rolled to plate with the thickness of 15mm. The plate was solution-treated for 1 hr at 1100 deg C and then water-quenched. Specimens were taken parallel to the rolling direction of the plate. The effects of nitrogen and phosphorus were analyzed on the high temperature mechanical properties of 316MRP (Liquid Metal Reactor, Primary candidate material) stainless steels with the different nitrogen content from 0.04 to 0.15% and with the different phosphorus content from 0.002 to 0.02%. Heat treatment was performed to investigate the changes in microstructure and mechanical properties of Cr-Mo steels for LMR heat transfer tube materials and core materials. The Cr-Mo steels were normalized at the temperatures between 900 deg C and 1200 deg C for 1hrs and tempered at the temperatures between 500 deg C and 800 deg C for 2hrs. Conventional optical and electron micrographic studies were carried out to investigate the martensite lath structure, carbide indentification and carbide shape. Vickers microhardness was measured at room temperature using 10g load. Tensile properties were tested at high temperature. Charpy V-notch impact tests were also carried out at temperature between -120 deg C and +180 deg C. (author). 72 refs., 28 tabs., 244 figs
International Nuclear Information System (INIS)
Gorecki, J.
1982-09-01
The application of the effective medium approximation (EMA) to the muffin-tin model of liquid metal is considered. The triple correlation function is included in the expression for electrical resistivity. Good agreement with experimental data can be expected for liquid noble metals. (author)
Advanced nuclear reactor and nuclear fusion power generation
International Nuclear Information System (INIS)
2000-04-01
This book comprised of two issues. The first one is a advanced nuclear reactor which describes nuclear fuel cycle and advanced nuclear reactor like liquid-metal reactor, advanced converter, HTR and extra advanced nuclear reactors. The second one is nuclear fusion for generation energy, which explains practical conditions for nuclear fusion, principle of multiple magnetic field, current situation of research on nuclear fusion, conception for nuclear fusion reactor and economics on nuclear fusion reactor.
Extreme Toughening of Soft Materials with Liquid Metal.
Kazem, Navid; Bartlett, Michael D; Majidi, Carmel
2018-05-01
Soft and tough materials are critical for engineering applications in medical devices, stretchable and wearable electronics, and soft robotics. Toughness in synthetic materials is mostly accomplished by increasing energy dissipation near the crack tip with various energy dissipation techniques. However, bio-materials exhibit extreme toughness by combining multi-scale energy dissipation with the ability to deflect and blunt an advancing crack tip. Here, we demonstrate a synthetic materials architecture that also exhibits multi-modal toughening, whereby embedding a suspension of micron sized and highly deformable liquid metal (LM) droplets inside a soft elastomer, the fracture energy dramatically increases by up to 50x (from 250 ± 50 J m -2 to 11,900 ± 2600 J m -2 ) over an unfilled polymer. For some LM-embedded elastomer (LMEE) compositions, the toughness is measured to be 33,500 ± 4300 J m -2 , which far exceeds the highest value previously reported for a soft elastic material. This extreme toughening is achieved by (i) increasing energy dissipation, (ii) adaptive crack movement, and (iii) effective elimination of the crack tip. Such properties arise from the deformability of the LM inclusions during loading, providing a new mechanism to not only prevent crack initiation, but also resist the propagation of existing tears for ultra tough, soft materials. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
[Research advances in heavy metals pollution ecology of diatom].
Ding, Teng-Da; Ni, Wan-Min; Zhang, Jian-Ying
2012-03-01
Diatom, due to its high sensitivity to environmental change, is one of the bio-indicators of aquatic ecosystem health, and some typical diatom species have been applied to indicate the heavy metals pollution of water body. With the focus on the surface water heavy metals pollution, this paper reviewed the research advances in the toxic effect of heavy metals pollution on diatom, biosorption and bioaccumulation of heavy metals by diatom, ecological adaptation mechanisms of diatom to heavy metals pollution, and roles of diatom as bio-indicator and in ecological restoration of heavy metals pollution. The growth tendency of diatom and the morphological change of frustule under heavy metals pollution as well as the differences in heavy metals biosorption and bioaccumulation by diatom, the ecological adaptation mechanisms of diatom on heavy metals surface complexation and ion exchange, and the roles of diatom as bio-indicator and in ecological restoration of heavy metals polluted water body were also discussed. This review could provide scientific evidences for the prevention of aquatic ecosystems heavy metals pollution and related early warning techniques.
Quantum State-Resolved Collision Dynamics of Nitric Oxide at Ionic Liquid and Molten Metal Surfaces
Zutz, Amelia Marie
Detailed molecular scale interactions at the gas-liquid interface are explored with quantum state-to-state resolved scattering of a jet-cooled beam of NO(2pi1/2; N = 0) from ionic liquid and molten metal surfaces. The scattered distributions are probed via laser-induced fluorescence methods, which yield rotational and spin-orbit state populations that elucidate the dynamics of energy transfer at the gas-liquid interface. These collision dynamics are explored as a function of incident collision energy, surface temperature, scattering angle, and liquid identity, all of which are found to substantially affect the degree of rotational, electronic and vibrational excitation of NO via collisions at the liquid surface. Rotational distributions observed reveal two distinct scattering pathways, (i) molecules that trap, thermalize and eventually desorb from the surface (trapping-desorption, TD), and (ii) those that undergo prompt recoil (impulsive scattering, IS) prior to complete equilibration with the liquid surface. Thermally desorbing NO molecules are found to have rotational temperatures close to, but slightly cooler than the surface temperature, indicative of rotational dependent sticking probabilities on liquid surfaces. Nitric oxide is a radical with multiple low-lying electronic states that serves as an ideal candidate for exploring nonadiabatic state-changing collision dynamics at the gas-liquid interface, which induce significant excitation from ground (2pi1/2) to excited (2pi 3/2) spin-orbit states. Molecular beam scattering of supersonically cooled NO from hot molten metals (Ga and Au, Ts = 300 - 1400 K) is also explored, which provide preliminary evidence for vibrational excitation of NO mediated by thermally populated electron-hole pairs in the hot, conducting liquid metals. The results highlight the presence of electronically nonadiabatic effects and build toward a more complete characterization of energy transfer dynamics at gas-liquid interfaces.
Development of insulating coatings for liquid metal blankets
International Nuclear Information System (INIS)
Malang, S.; Borgstedt, H.U.; Farnum, E.H.; Natesan, K.; Vitkovski, I.V.
1994-07-01
It is shown that self-cooled liquid metal blankets are feasible only with electrically insulating coatings at the duct walls. The requirements on the insulation properties are estimated by simple analytical models. Candidate insulator materials are selected based on insulating properties and thermodynamic consideration. Different fabrication technologies for insulating coatings are described. The status of the knowledge on the most crucial feasibility issue, the degradation of the resisivity under irradiation, is reviewed
Fatigue behaviour of a 9Cr1MoNbV martensitic steel in a liquid metal
Energy Technology Data Exchange (ETDEWEB)
Vogt, Jean-Bernard; Serre, Ingrid [Ecole National Superieure de Chimie de Lille (France); Verleene, Arnaud [Ecole National Superieure de Chimie de Lille (France); Michelin, Clermond Ferrand (France)
2009-07-01
The low cycle fatigue behaviour of the T91 martensitic steel is studied in the range {delta}{epsilon}{sub t} from 0.4% to 2.4%, at 300 C, in air and in liquid Lead Bismuth Eutectic (LBE). It is shown that the cyclic stress response consists of a cyclic softening that is not modified by the environment. However, the fatigue life is reduced after fatigue in LBE as compared to air and the effect is especially marked at high strain range. Metallographic analysis of the external surfaces and of transverse cross sections of specimen show that the short crack density is very low in the specimen failed in liquid metal while it is high for tests in air. Fracture surface observations show that multiple crack initiations occurred in air. In liquid metal, the fracture surfaces were flat and contained widely spaced fatigue striations. Strain localization promoted by the liquid metal is responsible for the decrease in fatigue resistance. (orig.)
Utility industry evaluation of the Sodium Advanced Fast Reactor
International Nuclear Information System (INIS)
Burstein, S.; DelGeorge, L.O.; Tramm, T.R.; Gibbons, J.P.; High, M.D.; Neils, G.H.; Pilmer, D.F.; Tomonto, J.R.; Wells, J.T.
1990-02-01
A team of utility industry representatives evaluated the Sodium Advanced Fast Reactor plant design, a current liquid metal reactor design created by an industrial team led by Rockwell International under Department of Energy sponsorship. The utility industry team concluded that the plant design offers several attractive characteristics, especially in the safety arena, as well as preserving the traditional attraction of liquid metal reactors, very high fuel utilization. Specific comments and recommendations are provided as a contribution towards improving an already attractive plant design. 18 refs
Performance investigations of liquid-metal heat pipes for space and terrestrial applications
International Nuclear Information System (INIS)
Kemme, J.E.; Keddy, E.S.; Phillips, J.R.
1978-01-01
The high heat transfer capacity of liquid-metal heat pipes is demonstrated in performance tests with mercury, potassium, sodium, and lithium working fluids and wick structures which serve to minimize liquid pressure losses and vapor/liquid interactions. Appropriate wicks for horizontal and vertical operation are described. It is shown that heat-transfer with these wicks is limited by vapor flow effects. Examples are given of particular effects associated with a long adiabatic section between evaporator and condenser and with a heat source of uniform temperature as opposed to a source of uniform power
SWEEP, a computer program for the analysis of CDA energetics in liquid metal reactors
International Nuclear Information System (INIS)
Suk, Soo Dong; Lee, Yong Bum; Hahn, Do Hee
2003-12-01
The SWEEP computer code was developed in this study to evaluate the work energy arising from two-phase expansion of fuel or sodium during core disruptive accidents in KALIMER. In the SWEEP program, scoping calculations with a modified Bethe-Tait method is first carried out using SCHAMBETA module to provide the initial thermodynamic conditions for the subsequent analyses to estimate the mechanical work energy generated in the reactor system. To estimate the work energy due to fuel-vapor expansion, a bounding approach is adopted to calculate the work potential assuming isentropic expansion to atmospheric pressure during super-prompt critical power excursions. Work potentials are also calculated in the SWEEP code for sodium expansion using the simple thermodynamic models including the infinite heat transfer model during expansion(Hicks and Menzies method) or more realistic zero heat transfer model for a typical initial condition of core disruptive accident. Core disruptive accidents have been investigated at Korea Atomic Energy Research Institute(KAERI) as part of the work to demonstrate the inherent and ultimate safety of conceptual design of the Korea Advanced Liquid Metal Reactor(KALIMER), a 150 MWe pool-type sodium cooled prototype fast reactor that uses U-TRU-Zr metallic fuel
The ion-electron correlation function in liquid metals
International Nuclear Information System (INIS)
Takeda, S.; Tamaki, S.; Waseda, Y.
1985-01-01
The structure factors of liquid Zn at 723 K, Sn at 523 K and Bi at 573 K have been determined by neutron diffraction with sufficient accuracy and compared with those of X-ray diffraction. A remarkable difference in the structural information between the two methods is clearly found around the first peak region as well as in the slightly varied peak positions, and it is apparently larger than the experimental errors. With these facts in mind, a new method evaluating the ion-electron correlation function in liquid metals has been proposed by using the measured structural data of X-rays and neutrons, with the help of theoretical values of the electron-electron correlation function by he Utsumi-Ichimaru scheme. This method has been applied to liquid Zn, Sn and Bi, and the radial distribution function of valence electrons around an ion has been estimated, from which the ionic radius and the schematic diagram of the electron distribution map are obtained. The ionic radii evaluated in this work have been found to agree well with those proposed by Pauling. (author)
Thermohydraulic behavior of liquid metal pool submitted to electronic bombardment
International Nuclear Information System (INIS)
Brun, Patrice
1998-01-01
This thesis deals with the thermohydraulics of liquid metal molten by an electron beam. We study the relationship between the liquid metal pool and the vapor rate. The aim is to find good conditions increasing the metal vapor rate. In first place, energy losses are identified. Mains are convection (buoyancy and thermo-capillary) strengthen by the deformation of the molten pool. The first action is to reduce the liquid interface deformation with a transient spot realized by scanning the electron beam. I find that in this case, the optimum vapor rate is obtained when the crossing time of the beam is smaller than characteristic time of formation of the cavity, but greater than the heating time of the surface. Secondly, I impose forces to change the morphology of the flow. Two actions are tried: magnetic field application and rotating motion of the crucible. External magnetic field application may reduce convective flow, by the creation of a magnetic brake. But in my experiment, magnetic field deteriorates electron beam before to be effective. Results obtained by the rotating motion of the crucible approve this choice to reduce energy losses and increase vapor rate. This growth of vapor rate is due to an expansion of the emitted vapor source and an increase of the central temperature of the molten pool. Nevertheless with the increase of the rotation velocity and after the optimum vapor rate, I note that the flow is not axisymmetric. My observation give to think about instabilities that are developed by baroclinic waves. The comparison of my works with the Eady's linear theory gives good results. (author) [fr
Direct writing of flexible electronics through room temperature liquid metal ink.
Gao, Yunxia; Li, Haiyan; Liu, Jing
2012-01-01
Conventional approaches of making a flexible circuit are generally complex, environment unfriendly, time and energy consuming, and thus expensive. Here, we describe for the first time the method of using high-performance GaIn(10)-based electrical ink, a significantly neglected room temperature liquid metal, as both electrical conductors and interconnects, for directly writing flexible electronics via a rather easy going and cost effective way. The new generation electric ink was made and its wettability with various materials was modified to be easily written on a group of either soft or rigid substrates such as epoxy resin board, glass, plastic, silica gel, paper, cotton, textiles, cloth and fiber etc. Conceptual experiments were performed to demonstrate and evaluate the capability of directly writing the electrical circuits via the invented metal ink. Mechanisms involved were interpreted through a series of fundamental measurements. The electrical resistivity of the fluid like GaIn(10)-based material was measured as 34.5 µΩ·cm at 297 K by four point probe method and increased with addition of the oxygen quantity, which indicates it as an excellent metal ink. The conductive line can be written with features that are approximately 10 µm thick. Several functional devices such as a light emitting diode (LED) array showing designed lighting patterns and electrical fan were made to work by directly writing the liquid metal on the specific flexible substrates. And satisfactory performances were obtained. The present method opens the way to directly and quickly writing flexible electronics which can be as simple as signing a name or drawing a picture on the paper. The unique merit of the GaIn(10)-based liquid metal ink lies in its low melting temperature, well controlled wettability, high electrical conductivity and good biocompability. The new electronics writing strategy and basic principle has generalized purpose and can be extended to more industrial areas, even
Direct writing of flexible electronics through room temperature liquid metal ink.
Directory of Open Access Journals (Sweden)
Yunxia Gao
Full Text Available BACKGROUND: Conventional approaches of making a flexible circuit are generally complex, environment unfriendly, time and energy consuming, and thus expensive. Here, we describe for the first time the method of using high-performance GaIn(10-based electrical ink, a significantly neglected room temperature liquid metal, as both electrical conductors and interconnects, for directly writing flexible electronics via a rather easy going and cost effective way. METHODS: The new generation electric ink was made and its wettability with various materials was modified to be easily written on a group of either soft or rigid substrates such as epoxy resin board, glass, plastic, silica gel, paper, cotton, textiles, cloth and fiber etc. Conceptual experiments were performed to demonstrate and evaluate the capability of directly writing the electrical circuits via the invented metal ink. Mechanisms involved were interpreted through a series of fundamental measurements. RESULTS: The electrical resistivity of the fluid like GaIn(10-based material was measured as 34.5 µΩ·cm at 297 K by four point probe method and increased with addition of the oxygen quantity, which indicates it as an excellent metal ink. The conductive line can be written with features that are approximately 10 µm thick. Several functional devices such as a light emitting diode (LED array showing designed lighting patterns and electrical fan were made to work by directly writing the liquid metal on the specific flexible substrates. And satisfactory performances were obtained. CONCLUSIONS: The present method opens the way to directly and quickly writing flexible electronics which can be as simple as signing a name or drawing a picture on the paper. The unique merit of the GaIn(10-based liquid metal ink lies in its low melting temperature, well controlled wettability, high electrical conductivity and good biocompability. The new electronics writing strategy and basic principle has generalized
The Dounreay PFR Liquid-Metal Disposal Project
International Nuclear Information System (INIS)
Sherwood, D.V.; Comline, A.; Small, J.; Blyth, J.
2005-01-01
The UKAEA Prototype Fast Reactor at Dounreay had a liquid sodium-cooled core. Following its shutdown in 1994, the liquid metal is being removed from the reactor and other vessels by means of specialized equipment and reacted with an aqueous solution of sodium hydroxide in a special vessel. The reaction products are neutralized with hydrochloric acid to produce a saline solution.The reactor sodium delivery and processing equipment is all of novel design. As sodium has been withdrawn from the vessel, it has been necessary to switch off the primary sodium pumps (used to heat the sodium), and the reactor is now kept at temperature by a purpose-designed electric heater and a NaK loop heater.A primary sodium extract pump has currently removed [approximately]450 tonnes of primary sodium from the reactor. As the level falls special equipment will be used to punch a hole in the primary circuit pipe work and to drill the strongback to allow trapped sodium to drain for extraction
Field-Controlled Electrical Switch with Liquid Metal.
Wissman, James; Dickey, Michael D; Majidi, Carmel
2017-12-01
When immersed in an electrolyte, droplets of Ga-based liquid metal (LM) alloy can be manipulated in ways not possible with conventional electrocapillarity or electrowetting. This study demonstrates how LM electrochemistry can be exploited to coalesce and separate droplets under moderate voltages of ~1-10 V. This novel approach to droplet interaction can be explained with a theory that accounts for oxidation and reduction as well as fluidic instabilities. Based on simulations and experimental analysis, this study finds that droplet separation is governed by a unique limit-point instability that arises from gradients in bipolar electrochemical reactions that lead to gradients in interfacial tension. The LM coalescence and separation are used to create a field-programmable electrical switch. As with conventional relays or flip-flop latch circuits, the system can transition between bistable (separated or coalesced) states, making it useful for memory storage, logic, and shape-programmable circuitry using entirely liquids instead of solid-state materials.
The effects of microstructure on crack initiation in liquid-metal environments
CSIR Research Space (South Africa)
Fernandes, PJL
1997-09-01
Full Text Available Liquid-metal-induced embrittlement under tensile test conditions is identified by the existence of a characteristic ductility trough. In this study, the effect of molten gallium on the behaviour of two brass alloys with different microstructures...