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Sample records for advanced liquefaction processes

  1. Technology for advanced liquefaction processes: Coal/waste coprocessing studies

    Energy Technology Data Exchange (ETDEWEB)

    Cugini, A.V.; Rothenberger, K.S.; Ciocco, M.V. [Pittsburgh Energy Technology Center, PA (United States)] [and others

    1995-12-31

    The efforts in this project are directed toward three areas: (1) novel catalyst (supported and unsupported) research and development, (2) study and optimization of major operating parameters (specifically pressure), and (3) coal/waste coprocessing. The novel catalyst research and development activity has involved testing supported catalysts, dispersed catalysts, and use of catalyst testing units to investigate the effects of operating parameters (the second area) with both supported and unsupported catalysts. Several supported catalysts were tested in a simulated first stage coal liquefaction application at 404{degrees}C during this performance period. A Ni-Mo hydrous titanate catalyst on an Amocat support prepared by Sandia National laboratories was tested. Other baseline experiments using AO-60 and Amocat, both Ni-Mo/Al{sub 2}O{sub 3} supported catalysts, were also made. These experiments were short duration (approximately 12 days) and monitored the initial activity of the catalysts. The results of these tests indicate that the Sandia catalyst performed as well as the commercially prepared catalysts. Future tests are planned with other Sandia preparations. The dispersed catalysts tested include sulfated iron oxide, Bayferrox iron oxide (iron oxide from Miles, Inc.), and Bailey iron oxide (micronized iron oxide from Bailey, Inc.). The effects of space velocity, temperature, and solvent-to-coal ratio on coal liquefaction activity with the dispersed catalysts were investigated. A comparison of the coal liquefaction activity of these catalysts relative to iron catalysts tested earlier, including FeOOH-impregnated coal, was made. These studies are discussed.

  2. Advanced exergetic analysis of five natural gas liquefaction processes

    International Nuclear Information System (INIS)

    Vatani, Ali; Mehrpooya, Mehdi; Palizdar, Ali

    2014-01-01

    Highlights: • Advanced exergetic analysis was investigated for five LNG processes. • Avoidable/unavoidable and endogenous/exogenous irreversibilities were calculated. • Advanced exergetic analysis identifies the potentials for improving the system. - Abstract: Conventional exergy analysis cannot identify portion of inefficiencies which can be avoided. Also this analysis does not have ability to calculate a portion of exergy destruction which has been produced through performance of a component alone. In this study advanced exergetic analysis was performed for five mixed refrigerant LNG processes and four parts of irreversibility (avoidable/unavoidable) and (endogenous/exogenous) were calculated for the components with high inefficiencies. The results showed that portion of endogenous exergy destruction in the components is higher than the exogenous one. In fact interactions among the components do not affect the inefficiencies significantly. Also this analysis showed that structural optimization cannot be useful to decrease the overall process irreversibilities. In compressors high portion of the exergy destruction is related to the avoidable one, thus they have high potential to improve. But in multi stream heat exchangers and air coolers, unavoidable inefficiencies were higher than the other parts. Advanced exergetic analysis can identify the potentials and strategies to improve thermodynamic performance of energy intensive processes

  3. Advances in Seabed Liquefaction and its Implications for Marine Structures

    DEFF Research Database (Denmark)

    Sumer, B. Mutlu

    2013-01-01

    A review is presented of recent advances in seabed liquefaction and its implications for marine structures. The review is organized in seven sections: Residual liquefaction, including the sequence of liquefaction, mathematical modelling, centrifuge modelling and comparison with standard wave-flum......-flume results; Momentary liquefaction; Floatation of buried pipelines; Sinking of pipelines and marine objects; Liquefaction at gravity structures; Stability of rock berms in liquefied soils; and Impact of seismic-induced liquefaction....

  4. Advanced direct liquefaction concepts for PETC generic units

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-01

    In the Advance Coal Liquefaction Concept Proposal (ACLCP) carbon monoxide (CO) and water have been proposed as the primary reagents in the pretreatment process. The main objective of this project is to develop a methodology for pretreating coal under mild conditions based on a combination of existing processes which have shown great promise in liquefaction, extraction and pyrolysis studies. The aim of this pretreatment process is to partially depolymerise the coal, eliminate oxygen and diminish the propensity for retograde reactions during subsequent liquefaction. The desirable outcome of the CO pretreatment step should be: (1) enhanced liquefaction activity and/or selectivity toward products of higher quality due to chemical modification of the coal structure; (2) cleaner downstream products; (3) overall improvement in operability and process economics.

  5. Coal liquefaction process streams characterization and evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-03-01

    CONSOL R D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  6. Advanced direct liquefaction concepts for PETC generic units. Quarterly technical progress report, January--March 1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-01

    In the Advance Coal Liquefaction Concept Proposal (ACLCP) carbon monoxide (CO) and water have been proposed as the primary reagents in the pretreatment process. The main objective of this project is to develop a methodology for pretreating coal under mild conditions based on a combination of existing processes which have shown great promise in liquefaction, extraction and pyrolysis studies. The aim of this pretreatment process is to partially depolymerise the coal, eliminate oxygen and diminish the propensity for retograde reactions during subsequent liquefaction. The desirable outcome of the CO pretreatment step should be: (1) enhanced liquefaction activity and/or selectivity toward products of higher quality due to chemical modification of the coal structure; (2) cleaner downstream products; (3) overall improvement in operability and process economics.

  7. A novel vortex tube-based N2-expander liquefaction process for enhancing the energy efficiency of natural gas liquefaction

    Directory of Open Access Journals (Sweden)

    Qyyum Muhammad Abdul

    2017-01-01

    Full Text Available This research work unfolds a simple, safe, and environment-friendly energy efficient novel vortex tube-based natural gas liquefaction process (LNG. A vortex tube was introduced to the popular N2-expander liquefaction process to enhance the liquefaction efficiency. The process structure and condition were modified and optimized to take a potential advantage of the vortex tube on the natural gas liquefaction cycle. Two commercial simulators ANSYS® and Aspen HYSYS® were used to investigate the application of vortex tube in the refrigeration cycle of LNG process. The Computational fluid dynamics (CFD model was used to simulate the vortex tube with nitrogen (N2 as a working fluid. Subsequently, the results of the CFD model were embedded in the Aspen HYSYS® to validate the proposed LNG liquefaction process. The proposed natural gas liquefaction process was optimized using the knowledge-based optimization (KBO approach. The overall energy consumption was chosen as an objective function for optimization. The performance of the proposed liquefaction process was compared with the conventional N2-expander liquefaction process. The vortex tube-based LNG process showed a significant improvement of energy efficiency by 20% in comparison with the conventional N2-expander liquefaction process. This high energy efficiency was mainly due to the isentropic expansion of the vortex tube. It turned out that the high energy efficiency of vortex tube-based process is totally dependent on the refrigerant cold fraction, operating conditions as well as refrigerant cycle configurations.

  8. A novel vortex tube-based N2-expander liquefaction process for enhancing the energy efficiency of natural gas liquefaction

    Science.gov (United States)

    Qyyum, Muhammad Abdul; Wei, Feng; Hussain, Arif; Ali, Wahid; Sehee, Oh; Lee, Moonyong

    2017-11-01

    This research work unfolds a simple, safe, and environment-friendly energy efficient novel vortex tube-based natural gas liquefaction process (LNG). A vortex tube was introduced to the popular N2-expander liquefaction process to enhance the liquefaction efficiency. The process structure and condition were modified and optimized to take a potential advantage of the vortex tube on the natural gas liquefaction cycle. Two commercial simulators ANSYS® and Aspen HYSYS® were used to investigate the application of vortex tube in the refrigeration cycle of LNG process. The Computational fluid dynamics (CFD) model was used to simulate the vortex tube with nitrogen (N2) as a working fluid. Subsequently, the results of the CFD model were embedded in the Aspen HYSYS® to validate the proposed LNG liquefaction process. The proposed natural gas liquefaction process was optimized using the knowledge-based optimization (KBO) approach. The overall energy consumption was chosen as an objective function for optimization. The performance of the proposed liquefaction process was compared with the conventional N2-expander liquefaction process. The vortex tube-based LNG process showed a significant improvement of energy efficiency by 20% in comparison with the conventional N2-expander liquefaction process. This high energy efficiency was mainly due to the isentropic expansion of the vortex tube. It turned out that the high energy efficiency of vortex tube-based process is totally dependent on the refrigerant cold fraction, operating conditions as well as refrigerant cycle configurations.

  9. Advanced direct liquefaction concepts for PETC generic units. Final report, Phase I

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The Advanced Concepts for Direct Coal Liquefaction program was initiated by the Department of Energy in 1991 to develop technologies that could significantly reduce the cost of producing liquid fuels by the direct liquefaction of coal. The advanced 2-stage liquefaction technology that was developed at Wilsonville over the past 10 years has contributed significantly toward decreasing the cost of producing liquids from coal to about $33/bbl. It remains, however, the objective of DOE to further reduce this cost to a level more competitive with petroleum based products. This project, among others, was initiated to investigate various alternative approaches to develop technologies that might ultimately lead to a 25 % reduction in cost of product. In this project a number of novel concepts were investigated, either individually or in a coupled configuration that had the potential to contribute toward meeting the DOE goal. The concepts included mature technologies or ones closely related to them, such as coal cleaning by oil agglomeration, fluid coking and distillate hydrotreating and dewaxing. Other approaches that were either embryonic or less developed were chemical pretreatment of coal to remove oxygen, and dispersed catalyst development for application in the 2-stage liquefaction process. This report presents the results of this project. It is arranged in four sections which were prepared by participating organizations responsible for that phase of the project. A summary of the overall project and the principal results are given in this section. First, however, an overview of the process economics and the process concepts that were developed during the course of this program is presented.

  10. Hydrothermal liquefaction of biomass: Developments from batch to continuous process

    OpenAIRE

    Elliott, DC; Biller, P; Ross, AB; Schmidt, AJ; Jones, SB

    2015-01-01

    This review describes the recent results in hydrothermal liquefaction (HTL) of biomass in continuous-flow processing systems. Although much has been published about batch reactor tests of biomass HTL, there is only limited information yet available on continuous-flow tests, which can provide a more reasonable basis for process design and scale-up for commercialization. High-moisture biomass feedstocks are the most likely to be used in HTL. These materials are described and results of their pr...

  11. Production of Advanced Biofuels via Liquefaction - Hydrothermal Liquefaction Reactor Design: April 5, 2013

    Energy Technology Data Exchange (ETDEWEB)

    Knorr, D.; Lukas, J.; Schoen, P.

    2013-11-01

    This report provides detailed reactor designs and capital costs, and operating cost estimates for the hydrothermal liquefaction reactor system, used for biomass-to-biofuels conversion, under development at Pacific Northwest National Laboratory. Five cases were developed and the costs associated with all cases ranged from $22 MM/year - $47 MM/year.

  12. An Advanced Wet Expansion Turbine for Hydrogen Liquefaction, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — This proposal is responsive to NASA SBIR Topic X10.01, specifically, the need for efficient small- to medium-scale hydrogen liquefaction technologies including...

  13. Solvent recyclability in a multistep direct liquefaction process

    Energy Technology Data Exchange (ETDEWEB)

    Hetland, M.D.; Rindt, J.R. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-31

    Direct liquefaction research at the Energy & Environmental Research Center (EERC) has, for a number of years, concentrated on developing a direct liquefaction process specifically for low-rank coals (LRCs) through the use of hydrogen-donating solvents and solvents similar to coal-derived liquids, the water/gas shift reaction, and lower-severity reaction conditions. The underlying assumption of all of the research was that advantage could be taken of the reactivity and specific qualities of LRCs to produce a tetrahydrofuran (THF)-soluble material that might be easier to upgrade than the soluble residuum produced during direct liquefaction of high-rank coals. A multistep approach was taken to produce the THF-soluble material, consisting of (1) preconversion treatment to prepare the coal for solubilization, (2) solubilization of the coal in the solvent, and (3) polishing to complete solubilization of the remaining material. The product of these three steps can then be upgraded during a traditional hydrotreatment step. The results of the EERC`s research indicated that additional studies to develop this process more fully were justified. Two areas were targeted for further research: (1) determination of the recyclability of the solvent used during solubilization and (2) determination of the minimum severity required for hydrotreatment of the liquid product. The current project was funded to investigate these two areas.

  14. Development of an extruder-feeder biomass direct liquefaction process

    Energy Technology Data Exchange (ETDEWEB)

    White, D.H.; Wolf, D. (Arizona Univ., Tucson, AZ (United States). Dept. of Chemical Engineering)

    1991-10-01

    As an abundant, renewable, domestic energy resource, biomass could help the United States reduce its dependence on imported oil. Biomass is the only renewable energy technology capable of addressing the national need for liquid transportation fuels. Thus, there is an incentive to develop economic conversion processes for converting biomass, including wood, into liquid fuels. Through research sponsored by the US DOE's Biomass Thermochemical Conversion Program, the University of Arizona has developed a unique biomass direct liquefaction system. The system features a modified single-screw extruder capable of pumping solid slurries containing as high as 60 wt% wood flour in wood oil derived vacuum bottoms at pressures up to 3000 psi. The extruder-feeder has been integrated with a unique reactor by the University to form a system which offers potential for improving high pressure biomass direct liquefaction technology. The extruder-feeder acts simultaneously as both a feed preheater and a pumping device for injecting wood slurries into a high pressure reactor in the biomass liquefaction process. An experimental facility was constructed and following shakedown operations, wood crude oil was produced by mid-1985. By July 1988, a total of 57 experimental continuous biomass liquefaction runs were made using White Birch wood feedstock. Good operability was achieved at slurry feed rates up to 30 lb/hr, reactor pressures from 800 to 3000 psi and temperatures from 350{degree}C to 430{degree}C under conditions covering a range of carbon monoxide feed rates and sodium carbonate catalyst addition. Crude wood oils containing as little as 6--10 wt% residual oxygen were produced. 38 refs., 82 figs., 26 tabs.

  15. Design of generic coal conversion facilities: Process release---Direct coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-01

    The direct liquefaction portion of the PETC generic direct coal liquefaction process development unit (PDU) is being designed to provide maximum operating flexibility. The PDU design will permit catalytic and non-catalytic liquefaction concepts to be investigated at their proof-of-the-concept stages before any larger scale operations are attempted. The principal variations from concept to concept are reactor configurations and types. These include thermal reactor, ebullating bed reactor, slurry phase reactor and fixed bed reactor, as well as different types of catalyst. All of these operating modes are necessary to define and identify the optimum process conditions and configurations for determining improved economical liquefaction technology.

  16. Advanced Direct Liquefaction Concepts for PETC Generic Units - Phase II

    Energy Technology Data Exchange (ETDEWEB)

    None

    1997-09-01

    Reported here are the results of Laboratory and Bench- Scale experiments and supporting technical and economic assessments conducted under DOE Contract No. DE- AC22- 91PC91040 during the period April 1, 1997 to June 30, 1997. This contract is with the University of Kentucky Research Foundation which supports work with the University of Kentucky Center for Applied Energy Research, CONSOL, Inc., LDP Associates, and Hydrocarbon Technologies, Inc. This work involves the introduction into the basic two stage liquefaction process several novel concepts which includes dispersed lower- cost catalysts, coal cleaning by oil agglomeration, and distillate hydrotreating and dewaxing. This report includes a data analysis of the ALC- 2 run which was the second continuous run in which Wyodak Black Thunder coal was fed to a two kg/ h bench- scale unit. One of the objectives of that run was to determine the relative activity of several Mo- based coal impregnated catalyst precursors. The precursors included ammonium heptamolybdate (100 mg Mo/ kg dry coal), which was used alone as well as in combination with ferrous sulfate (1% Fe/ dry coal) and nickel sulfate (50 mg Ni/ kg dry coal). The fourth precursor that was tested was phosphomolybdic acid which was used at a level of 100 mg Mo/ kg dry coal. Because of difficulties in effectively separating solids from the product stream, considerable variation in the feed stream occurred. Although the coal feed rate was nearly constant, the amount of recycle solvent varied which resulted in wide variations of resid, unconverted coal and mineral matter in the feed stream. Unfortunately, steady state was not achieved in any of the four conditions that were run. Earlier it was reported that Ni- Mo catalyst appeared to give the best results based upon speculative steady- state yields that were developed.

  17. Subtask 3.9 - Direct Coal Liquefaction Process Development

    Energy Technology Data Exchange (ETDEWEB)

    Aulich, Ted; Sharma, Ramesh

    2012-07-01

    The Energy and Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from ExxonMobil, undertook Subtask 3.9 to design, build, and preliminarily operate a bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. Fabrication and installation of the DCL system and an accompanying distillation system for off-line fractionation of raw coal liquids into 1) a naphtha middle distillate stream for upgrading and 2) a recycle stream was completed in May 2012. Shakedown of the system was initiated in July 2012. In addition to completing fabrication of the DCL system, the project also produced a 500-milliliter sample of jet fuel derived in part from direct liquefaction of Illinois No. 6 coal, and submitted the sample to the Air Force Research Laboratory (AFRL) at Wright Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with all U.S. Air Force-prescribed alternative aviation fuel initial screening criteria.

  18. Characterization of solid residues from coal liquefaction processes. Phase I

    Energy Technology Data Exchange (ETDEWEB)

    Potter, J.; McDougall, W.M.; Kybett, B.D.; Neufeld, C.

    1981-01-01

    Various coal liquefaction and beneficiation processes are being investigated by independent research groups sponsored by the Canadian Federal Government. These processes include the co-processing of heavy oils and bitumen with coal, oxygen removal and hydrogenation of coal and supercritical gas extraction of coal. The end products, gaseous and liquid fuels and insoluble organic residues, vary with the experimental conditions. The physical properties and origin of the insoluble residue may influence such factors as degree of conversion, efficiency of the process, and ultimately, gaseous and liquid yields. One of the most suitable methods of assessing the nature of the insoluble residues is the use of petrography. This report deals with petrographic assessment of the coals and residues from various coal conversion processes; attempts were made to characterize the solid phases in the residues; to assess them in a quantitative manner and where possible; to correlate the results with experimental data; and to assess their effects on conversion. (30 refs.)

  19. System evaluation of offshore platforms with gas liquefaction processes

    DEFF Research Database (Denmark)

    Nguyen, Tuong-Van; de Oliveira Júnior, Silvio

    2018-01-01

    Abstract Floating, production, storage and offloading plants are facilities used for offshore processing of hydrocarbons in remote locations. At present, the produced gas is injected back into the reservoir instead of being exported. The implementation of refrigeration processes offshore for liqu......Abstract Floating, production, storage and offloading plants are facilities used for offshore processing of hydrocarbons in remote locations. At present, the produced gas is injected back into the reservoir instead of being exported. The implementation of refrigeration processes offshore...... improvements are discussed based on an energy and exergy analysis. Compared to a standard platform where gas is directly injected into the reservoir, the total power consumption increases by up to 50%, and the exergy destruction within the processing plant doubles when a liquefaction system is installed....... It is therefore essential to conduct a careful analysis of the trade-off between the capital costs and operating revenues for such options....

  20. Advanced Direct Liquefaction Concepts for PETC Generic Units - Phase II

    Energy Technology Data Exchange (ETDEWEB)

    None

    1997-12-01

    The results of Laboratory and Bench-Scale experiments and supporting technical and economic assessments conducted under DOE Contract No. DE-AC22-91PC91040 are reported for the period July 1, 1997 to September 30, 1997. This contract is with the University of Kentucky Research Foundation which supports work with the University of Kentucky Center for Applied Energy Research, CONSOL, Inc., LDP Associates, and Hydrocarbon Technologies, Inc. This work involves the introduction into the basic two stage liquefaction process several novel concepts which include dispersed lower-cost catalysts, coal cleaning by oil agglomeration, and distillate hydrotreating and dewaxing. Results are reported from experiments in which various methods were tested to activate dispersed Mo precursors. Several oxothiomolybdates precursors having S/Mo ratios from two to six were prepared. Another having a S/Mo ratio of eleven was also prepared that contained an excess of sulfur. In the catalyst screening test, none of these precursors exhibited an activity enhancement that might suggest that adding sulfur into the structure of the Mo precursors would be beneficial to the process. In another series of experiments, AHM impregnated coal slurried in the reaction mixture was pretreated withH S/H under pressure and successively heated for 30 min at 120, 250 2 2 and 360 C. THF conversions in the catalyst screening test were not affected while resid conversions o increased such that pretreated coals impregnated with 100 ppm Mo gave conversions equivalent to untreated coals impregnated with 300 ppm fresh Mo. Cobalt, nickel and potassium phosphomolybdates were prepared and tested as bimetallic precursors. The thermal stability of these compounds was evaluated in TG/MS to determine whether the presence of the added metal would stabilize the Keggin structure at reaction temperature. Coals impregnated with these salts showed the Ni and Co salts gave the same THF conversion as PMA while the Ni salt gave higher

  1. Novel use of residue from direct coal liquefaction process

    Energy Technology Data Exchange (ETDEWEB)

    Jianli Yang; Zhaixia Wang; Zhenyu Liu; Yuzhen Zhang [Chinese Academy of Sciences, Taiyuan (China). State Key Laboratory of Coal Conversion

    2009-09-15

    Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of direct coal liquefaction processes. This study shows that the DCLR may be used as a pavement asphalt modifier. The modification ability is similar to that of Trinidad Lake Asphalt (TLA), a superior commercial modifier. Asphalts modified by two DCLRs meet the specifications of ASTM D5710 and BSI BS-3690 designated for the TLA-modified asphalts. The required addition amount for the DCLRs tested is less than that for TLA due possibly to the high content of asphaltene in DCLRs. Different compatibility was observed for the asphalts with the same penetration grade but from the different origin. Different components in the DCLR play different roles in the modification. Positive synergetic effects among the fractions were observed, which may due to the formation of the stable colloid structure. Unlike polymer-type modifier, the structure of asphalt-type modifier has a similarity with petroleum asphalts which favors the formation of a stable dispersed polar fluid (DPF) colloid structure and improves the performance of pavement asphalt. 12 refs., 1 fig., 6 tabs.

  2. Zeolites as Catalysts for Fuels Refining after Indirect Liquefaction Processes

    Directory of Open Access Journals (Sweden)

    Arno de Klerk

    2018-01-01

    Full Text Available The use of zeolite catalysts for the refining of products from methanol synthesis and Fisher–Tropsch synthesis was reviewed. The focus was on fuels refining processes and differences in the application to indirect liquefaction products was compared to petroleum, which is often a case of managing different molecules. Processes covered were skeletal isomerisation of n-butenes, hydroisomerisation of n-butane, aliphatic alkylation, alkene oligomerisation, methanol to hydrocarbons, ethanol and heavier alcohols to hydrocarbons, carbonyls to hydrocarbons, etherification of alkenes with alcohols, light naphtha hydroisomerisation, catalytic naphtha reforming, hydroisomerisation of distillate, hydrocracking and fluid catalytic cracking. The zeolite types that are already industrially used were pointed out, as well as zeolite types that have future promise for specific conversion processes.

  3. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, October 1--December 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-03-01

    CONSOL R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  4. A novel process for small-scale pipeline natural gas liquefaction

    International Nuclear Information System (INIS)

    He, T.B.; Ju, Y.L.

    2014-01-01

    Highlights: • A novel process was proposed to liquefy natural gas by utilizing the pressure exergy. • The process is zero energy consumption. • The maximum liquefaction rate of the process is 12.61%. • The maximum exergy utilization rate is 0.1961. • The economic analysis showed that the payback period of the process is quit short. - Abstract: A novel process for small-scale pipeline natural gas liquefaction is designed and presented. The novel process can utilize the pressure exergy of the pipeline to liquefy a part of natural gas without any energy consumption. The thermodynamic analysis including mass, energy balance and exergy analysis are adopted in this paper. The liquefaction rate and exergy utilization rate are chosen as the objective functions. Several key parameters are optimized to approach the maximum liquefaction rate and exergy utilization rate. The optimization results showed that the maximum liquefaction rate is 12.61% and the maximum exergy utilization rate is 0.1961. What is more, the economic performances of the process are also discussed and compared by using the maximum liquefaction rate and exergy utilization rate as indexes. In conclusion, the novel process is suitable for pressure exergy utilization due to its simplicity, zero energy consumption and short payback period

  5. SUMMARY REPORT OF THE DOE DIRECT LIQUEFACTION PROCESS DEVELOPMENT CAMPAIGN OF THE LATE TWENTIETH CENTURY; FINAL

    International Nuclear Information System (INIS)

    F.P. Burke; S.D. Brandes; D.C. McCoy; R.A. Winschel; D. Gray; G. Tomlinson

    2001-01-01

    Following the petroleum price and supply disruptions of 1973, the U.S. government began a substantial program to fund the development of alternative fuels. Direct coal liquefaction was one of the potential routes to alternative fuels. The direct coal liquefaction program was funded at substantial levels through 1982, and at much lower levels thereafter. Those processes that were of most interest during this period were designed to produce primarily distillate fuels. By 1999, U.S. government funding for the development of direct coal liquefaction ended. Now that the end of this campaign has arrived, it is appropriate to summarize the process learnings derived from it. This report is a summary of the process learnings derived from the DOE direct coal liquefaction process development campaign of the late twentieth century. The report concentrates on those process development programs that were designed to produce primarily distillate fuels and were largely funded by DOE and its predecessors in response to the petroleum supply and price disruptions of the 1970s. The report is structured as chapters written by different authors on most of the major individual DOE-funded process development programs. The focus of the report is process learnings, as opposed to, say, fundamental coal liquefaction science or equipment design. As detailed in the overview (Chapter 2), DOE's direct coal liquefaction campaign made substantial progress in improving the process yields and the quality of the distillate product. Much of the progress was made after termination by 1983 of the major demonstration programs of the ''first generation'' (SRC-II, H-Coal, EDS) processes

  6. A Characterization and Evaluation of Coal Liquefaction Process Streams

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-10-01

    An updated assessment of the physico-chemical analytical methodology applicable to coal-liquefaction product streams and a review of the literature dealing with the modeling of fossil-fuel resid conversion to product oils are presented in this document. In addition, a summary is provided for the University of Delaware program conducted under this contract to develop an empirical test to determine relative resid reactivity and to construct a computer model to describe resid structure and predict reactivity.

  7. Reducing capital and operating costs in gas processing, liquefaction, and storage

    Energy Technology Data Exchange (ETDEWEB)

    Krusen, III, L C [Phillips Petroleum Co., Bartlesville, OK (United States). Research Div.

    1997-06-01

    The LNG industry is unanimous that capital costs must be reduced throughout the chain, and especially at the liquefaction facility including associated gas processing and LNG storage. The Ken ai LNG plant provides an example of how both reduced capital and operating costs were attained. This paper will cover cost production strategies that can be applied to liquefaction processes in general, and will than focus on their realization in the Phillips Optimized Cascade LNG process. The paper concludes that reduced LNG plant costs are attainable. (Author).

  8. Reducing capital and operating costs in gas processing, liquefaction, and storage

    International Nuclear Information System (INIS)

    Krusen, L.C. III

    1997-01-01

    The LNG industry is unanimous that capital costs must be reduced throughout the chain, and especially at the liquefaction facility including associated gas processing and LNG storage. The Ken ai LNG plant provides an example of how both reduced capital and operating costs were attained. This paper will cover cost production strategies that can be applied to liquefaction processes in general, and will than focus on their realization in the Phillips Optimized Cascade LNG process. The paper concludes that reduced LNG plant costs are attainable. (Author)

  9. Process Water Recycle in Hydrothermal Liquefaction of Microalgae To Enhance Bio-oil Yield

    NARCIS (Netherlands)

    Ramos-Tercero, E.A.; Bertucco, A.; Brilman, Derk Willem Frederik

    2015-01-01

    In this work, the effect of recycling the process water (PW) of hydrothermal liquefaction (HTL) to the HTL reactor was investigated, with the objective being to recover carbon from the organic content of the PW and to develop a solvent-free process. When recycling twice the PW at 220, 240, and 265

  10. Application of Algae as Cosubstrate To Enhance the Processability of Willow Wood for Continuous Hydrothermal Liquefaction

    DEFF Research Database (Denmark)

    Sintamarean, Iulia-Maria; Pedersen, Thomas Helmer; Zhao, Xueli

    2017-01-01

    This work proposes a novel strategy to improve the continuous processing of wood slurries in hydrothermal liquefaction systems by coprocessing with algae. Of all algae tested, brown seaweeds and microalgae perform best in preventing slurries dewatering, the main reason for pumpability issues...... with wood slurries. Rheological tests (viscosity–shear rate profile) indicate that the addition of these two algae to the wood slurry causes the highest increase in viscosity, which coincides with improved wood slurries stability and pumpability. Hydrothermal liquefaction of wood-algae slurries at 400 °C...

  11. Characteristics of process oils from HTI coal/plastics co-liquefaction runs

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A. [and others

    1995-12-31

    The objective of this project is to provide timely analytical support to DOE`s liquefaction development effort. Specific objectives of the work reported here are presented. During a few operating periods of Run POC-2, HTI co-liquefied mixed plastics with coal, and tire rubber with coal. Although steady-state operation was not achieved during these brief tests periods, the results indicated that a liquefaction plant could operate with these waste materials as feedstocks. CONSOL analyzed 65 process stream samples from coal-only and coal/waste portions of the run. Some results obtained from characterization of samples from Run POC-2 coal/plastics operation are presented.

  12. Analysis of flammability limits for the liquefaction process of oxygen-bearing coal-bed methane

    International Nuclear Information System (INIS)

    Li, Q.Y.; Wang, L.; Ju, Y.L.

    2011-01-01

    Highlights: → A novel liquefaction and distillation process is designed for oxygen bearing coal-bed methane. → Oxygen contained in coal-bed methane is removed in distillation process. → Flammability limits are analyzed for the whole operation process. → We find explosion hazard may exist in distillation tower. → Effective measures are proposed to ensure the operation safety in distillation tower. - Abstract: A novel liquefaction and distillation process has been proposed and designed for the typical oxygen-bearing coal-bed methane (CBM), in which the impurities of the oxygen and nitrogen components are removed in the distillation column. The flammability limit theory combining with HYSYS simulation results are employed to analyze and calculate the flammability limits and the results indicate that no flammability hazard exists in the stages of compression, liquefaction and throttling. However, flammability hazard exists at the top the distillation column because the methane mole fraction decreases to the value below the upper flammability limit (UFL). The safety measures of initially removing oxygen content from the feed gas combining with the control of the bottom flowrate (flowrate of the liquid product at column bottom) are proposed to ensure the operation safety of the liquefaction process. The results reveal that the operation safety of the whole process can be guaranteed, together with high methane recovery rate and high purity of the liquid product. The applicability of the liquefaction process has also been analyzed in this paper. The simulation results can offer references for the separation of oxygen from CBM, the analysis of flammability limits and the safety measures for the whole process.

  13. A preliminary analysis of floating production storage and offloading facilities with gas liquefaction processes

    DEFF Research Database (Denmark)

    Nguyen, Tuong-Van; Carranza-Sánchez, Yamid Alberto; Junior, Silvio de Oliveira

    2016-01-01

    Floating, production, storage and offloading (FPSO) plants are facilities used in upstream petroleum processing. They have gained interest because they are more flexible than conventional plants and can be used for producing oil and gas in deep-water fields. In general, gas export is challenging...... because of the lack of infrastructure in remote locations. The present work investigates the possibility of integrating liquefaction processes on such facilities, considering two mixed-refrigerant and two expansion-based processes suitable for offshore applications. Two FPSO configurations are considered...... in this work, and they were suggested by Brazilian operators for fields processing natural gas with moderate to high content of carbon dioxide. The performance of the combined systems is analysed by conducting energy and exergy analyses. The integration of gas liquefaction results in greater power consumption...

  14. Process for the liquefaction of solid carbonaceous materials wherein nitrogen is separated from hydrogen via ammonia synthesis

    Science.gov (United States)

    Stetka, Steven S.; Nazario, Francisco N.

    1982-01-01

    In a process for the liquefaction of solid carbonaceous materials wherein bottoms residues are upgraded with a process wherein air is employed, the improvement wherein nitrogen buildup in the system is avoided by ammonia synthesis. In a preferred embodiment hydrogen from other portions of the liquefaction process will be combined with hydrogen produced as a result of the bottoms upgrading to increase the H.sub.2 :N.sub.2 ratio in the ammonia reactor.

  15. Combined hydrothermal liquefaction and catalytic hydrothermal gasification system and process for conversion of biomass feedstocks

    Science.gov (United States)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2017-09-12

    A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.

  16. Conceptual study of hydrogen donor solvent in the NEDOL coal liquefaction process

    Energy Technology Data Exchange (ETDEWEB)

    Kouzu, M.; Onozaki, M.; Oi, S. [Mitsui SRC Co Ltd, Tokyo (Japan)

    2002-03-01

    A 150 ton/day coal liquefaction pilot plant (PP) of the NEDOL process, supported by New Energy and Industrial Technology Development Organization (NEDO), was operated successfully for a total of 269 days at Kashima, Japan. With a great number of data obtained through the operation, the design procedure for the NEDOL process was studied. Middle and heavy oils from the coal employed were recycled as a hydrogen-donor solvent after hydrotreatment over Ni Mo/gamma-Al2O{sub 3} in a trickle bed reactor. The hydrogen donating ability of the solvent was high enough to obtain higher oil yield (50-58 wt%) at the aromaticity of ca. 0.45. Life expectancy of solvent hydrotreatment catalyst, requisite to the hydrotreater design, was estimated under PP operating conditions. In addition, physical properties of the solvent required for process design were determined, and hydrodynamics in the liquefaction bubble column reactors were examined. Taking the obtained hydrodynamics and thermal behavior into consideration, a design procedure of the liquefaction bubble column reactors was establsihed using a process simulator (CARD) validated by the product yields of PP. The simulation including distillation and solvent hydrotreatment showed that the content of heavy oil fraction (b.p. 350 - 538{degree} C) in the solvent was a determinant factor in the design of a large scale plant based on the NEDOL process.

  17. Liquefaction of lignohemicellulosic waste by processing with carbon monoxide and water

    Energy Technology Data Exchange (ETDEWEB)

    El-Saied, H

    1977-09-01

    The liquefaction of lignohemicellulosic waste by processing with carbon monoxide and water for 10 minutes at 250/sup 0/-440/sup 0/C and 40 to 70 atm initial pressure in a rocking autoclave produced benzene-soluble heavy oil in yields up to 80%. High conversion and yields were favored by high thermal stress, short reaction times, and sufficient hydrogen to prevent radical recombination in the critical liquefaction stages. The addition of sodium or calcium hydroxide, sodium carbonate, iron oxide, etc. in small amounts gave good oil yields under less severe conditions. Lignins from rice straw, bagasse, and other grasses gave higher yields than the woody lignin obtained from cotton stalks. In products obtained by liquefying black liquor lignohemicellulose from an Eyptian rice straw pulping plant, the hydrogen-carbon atomic ratio was 1.0 to 1.3:1.

  18. Characteristics of the products of hydrothermal liquefaction combined with cellulosic bio-ethanol process

    International Nuclear Information System (INIS)

    Li, Rundong; Xie, Yinghui; Yang, Tianhua; Li, Bingshuo; Zhang, Yang; Kai, Xingping

    2016-01-01

    The integration utilization of fermentation residues from cellulosic bio-ethanol has attracted a great deal of attention to balance the total cost of bio-ethanol production while simultaneously dealing with bio-ethanol wastewater. A process of hydrothermal liquefaction (HTL) of intact materials from cellulosic bio-ethanol in a batch reactor was proposed. The effects of the reaction temperature and time on the liquefaction characteristics were examined. The optimum condition for liquefaction fermentation residues was 370 °C (21.25 MPa) and 30 min with a bio-oil yield of 40.79 wt%. GC-MS results indicated that the major chemical species in the bio-oil were phenols, ketones, long-chain hydrocarbons and fatty acids. Supercritical conditions (375 °C, 23.50 MPa) was favored for the low-molecular-weight species formation compared to subcritical conditions (370 °C, 21.25 MPa), as some long-chain species decreased. This work thus can provide a novel idea for bio-oil production from HTL of cellulosic bio-ethanol fermentation residues. - Highlights: • Bio-oil production via HTL combined with cellulosic bio-ethanol process was proposed. • Optimum condition for HTL of materials from cellulosic bio-ethanol was 370 °C and 30 min. • Bio-oil contained higher content of hydrocarbons and lower contents of organic acids.

  19. Optimisation of expansion liquefaction processes using mixed refrigerant N_2–CH_4

    International Nuclear Information System (INIS)

    Ding, He; Sun, Heng; He, Ming

    2016-01-01

    Highlights: • A refrigerant composition matching method for N_2–CH_4 expansion processes. • Efficiency improvements for propane pre-cooled N_2–CH_4 expansion processes. • The process shows good adaptability to varying natural gas compositions. - Abstract: An expansion process with a pre-cooling system is simulated and optimised by Aspen HYSYS and MATLAB"™. Taking advantage of higher specific refrigeration effect of methane and easily reduced refrigeration temperature of nitrogen, the designed process adopts N_2–CH_4 as a mixed refrigerant. Based on the different thermodynamic properties and sensitivity difference of N_2 and CH_4 over the same heat transfer temperature range, this work proposes a novel method of matching refrigerant composition which aims at single-stage or multi-stage series expansion liquefaction processes with pre-cooling systems. This novel method is applied successfully in propane pre-cooled N_2–CH_4 expansion process, and the unit power consumption is reduced to 7.09 kWh/kmol, which is only 5.35% higher than the global optimised solutions obtained by genetic algorithm. This novel method can fulfil the accomplishments of low energy consumption and high liquefaction rate, and thus decreases the gap between the mixed refrigerant and expansion processes in energy consumption. Furthermore, the high exergy efficiency of the process indicates good adaptability to varying natural gas compositions.

  20. System and process for efficient separation of biocrudes and water in a hydrothermal liquefaction system

    Science.gov (United States)

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Oyler, James R.; Rotness, Jr, Leslie J.; Schmidt, Andrew J.; Zacher, Alan H.

    2016-08-02

    A system and process are described for clean separation of biocrudes and water by-products from hydrothermal liquefaction (HTL) product mixtures of organic and biomass-containing feedstocks at elevated temperatures and pressures. Inorganic compound solids are removed prior to separation of biocrude and water by-product fractions to minimize formation of emulsions that impede separation. Separation may be performed at higher temperatures that reduce heat loss and need to cool product mixtures to ambient. The present invention thus achieves separation efficiencies not achieved in conventional HTL processing.

  1. Thermodynamic Evaluation of Floating Production Storage and Offloading Facilities with Liquefaction Processes

    DEFF Research Database (Denmark)

    Nguyen, Tuong-Van; Sánchez, Yamid Alberto Carranza; Junior, Silvio de Oliveira

    2016-01-01

    Floating, production, storage and offloading (FPSO) plants are facilities used in upstream petroleum processing.They have gained interest because they are more flexible than conventional plants and can be used for producingoil and gas in deep-water fields. In general, gas export is challenging...... because of the lack of infrastructure in remotelocations. The present work investigates the possibility of integrating liquefaction processes on such facilities, consideringfour possible petroleum compositions, which differ in their contents of carbon dioxide, light and heavy hydrocarbons.The performance...

  2. Design and analysis of liquefaction process for offshore associated gas resources

    International Nuclear Information System (INIS)

    Li, Q.Y.; Ju, Y.L.

    2010-01-01

    Liquefaction is the key section on floating platform. Some experts and designers selected mixed refrigerant process for floating platform, while some recommended expander cycle. However, few of them compared the two types of processes systemically before making a choice. In this paper, the liquefaction processes of propane pre-cooled mixed refrigerant cycle (C 3 /MRC), mixed refrigerant cycle (MRC) and nitrogen expander cycle (N 2 expander) for the special offshore associated gases in South China Sea have been designed and studied. These processes have been analyzed and compared systematically considering the main factors including the performance parameters, economic performance, layout, sensitivity to motion, suitability to different gas resources, safety and operability, accounting for the features of the floating production, storage and offloading unit for liquefied natural gas (LNG-FPSO) in marine environment. The results indicated that N 2 expander has higher energy consumption and poorer economic performance, while it has much more advantages than C 3 /MRC and MRC for offshore application because it is simpler and more compact and thus requiring less deck area, less sensitive to LNG-FPSO motion, has better suitability for other gas resources, has higher safety and is easier to operate. Therefore, N 2 expander is the most suitable offshore liquefaction process. In addition, the exergy analysis is conducted for N 2 expander and the results indicate that the compression equipments and after coolers, expanders and LNG heat exchangers are the main contribution to the total exergy losses. The measures to decrease the losses for these equipments are then discussed.

  3. Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oil

    Energy Technology Data Exchange (ETDEWEB)

    Gangwal, Santosh [Southern Research, Durham, NC (United States); Meng, Jiajia [Southern Research, Durham, NC (United States); McCabe, Kevin [Southern Research, Durham, NC (United States); Larson, Eric [Princeton Univ., NJ (United States). Princeton Environmental Inst.; Mastro, Kelly [Southern Research, Durham, NC (United States)

    2016-04-25

    Southern Research (SR) in cooperation with U.S. Department of Energy (DOE), Bioenergy Technology Office (BETO), investigated a biomass liquefaction process for economic production of stabilized refinery-ready bio-oil. The project was awarded by DOE under a Funding Opportunity Announcement (DE-FOA-0000686) for Bio-oil Stabilization and Commoditization that intended to evaluate the feasibility of using bio-oil as a potential feedstock in an existing petroleum refinery. SR investigated Topic Area 1 of the FOA at Technology Readiness Level 2-3 to develop thermochemical liquefaction technologies for producing a bio-oil feedstock from high-impact biomass that can be utilized within a petroleum refinery. Bio-oil obtained from fast pyrolysis of biomass is a green intermediate that can be further upgraded into a biofuel for blending in a petroleum refinery using a hydro-deoxygenation (HDO) route. Co-processing pyrolysis bio-oil in a petroleum refinery is an attractive approach to leverage the refinery’s existing capital. However, the petroleum industry is reluctant to accept pyrolysis bio-oil because of a lack of a standard definition for an acceptable bio-oil feedstock in existing refinery processes. Also per BETO’s multiyear program plan, fast pyrolysis-based bio-fuel is presently not cost competitive with petroleum-based transportation fuels. SR aims to develop and demonstrate a cost-effective low-severity thermal liquefaction and hydrodeoxygenation (HDO) process to convert woody biomass to stabilized bio-oils that can be directly blended with hydrotreater input streams in a petroleum refinery for production of gasoline and/or diesel range hydrocarbons. The specific project objectives are to demonstrate the processes at laboratory scale, characterize the bio-oil product and develop a plan in partnership with a refinery company to move the technology towards commercialization.

  4. Liquefaction of syngas by fischer-tropsch process (abstract)

    International Nuclear Information System (INIS)

    Khalid, N.; Saeed, M.M.; Riaz, M.; Khan, A.S.A.

    2011-01-01

    The Fischer-Tropsch process is a set of chemical reactions that convert syngas into liquid hydrocarbons and is gaining attention under the background of the resource depletion leading to the price hike of the petroleum oil. The diesel fuel obtained from syngas by Fischer-Tropsch process seems to be of high quality and environmental friendly. The present study deals with the optimization of the experimental conditions for the production/synthesis of mineral diesel from syngas by Fischer-Tropsch process. The catalyst was prepared by coating cobalt nitrate on alumina followed by calcinations and characterization by analytical techniques such as BET, SEM/EDXA and X-Ray diffraction. For the conversion of syngas to liquid fuel, the fixed bed column technique was employed. Different operational parameters such as temperature of the column, flow rate and pressure of the syngas were studied. The product formed was verified by comparing the GC/FID spectrum of the synthesized mineral diesel with commercial sample by employing GC analysis. The qualitative results indicate the success of the Fischer-Tropsch process in the present study. (author)

  5. Energy consumption, destruction of exergy and boil off during the process of liquefaction, transport and regasification of liquefied natural gas

    Energy Technology Data Exchange (ETDEWEB)

    Stradioto, Diogo Angelo; Schneider, Paulo Smith [Dept. of Mechanical Engineering. Universidade Federal do Rio Grande do Sul, Porto Alegre (Brazil)], e-mail: pss@mecanica.ufrgs.br

    2010-07-01

    A supply chain of Liquefied Natural Gas (LNG) is composed by several processes like extraction, purification, liquefaction, storage, transport, regasification and distribution. In all these stages, processes need of energy. The main objective of this work is to quantify the energy consumption, mass loss and exergy destruction occurred throughout the chain. Results show that the process of liquefaction is the largest consumer of energy. Storage and transport by ship are responsible for the bigger mass losses and regasification is the process of larger destruction of exergy. A case study is performed considering a stream of pure methane at the input of a liquefaction plant, and evaluates energy along the chain, ending up at the distribution of NG after its regasification. (author)

  6. A CHARACTERIZATION AND EVALUATION OF COAL LIQUEFACTION PROCESS STREAMS

    International Nuclear Information System (INIS)

    G.A. Robbins; R.A. Winschel; S.D. Brandes

    1999-01-01

    This is the first Annual Technical Report of activities under DOE Contract No. DE-AC22-94PC93054. Activities from the first three quarters of the fiscal 1998 year were reported previously as Quarterly Technical Progress Reports (DOE/PC93054-57, DOE/PC93054-61, and DOE/PC93054-66). Activities for the period July 1 through September 30, 1998, are reported here. This report describes CONSOL's characterization of process-derived samples obtained from HTI Run PB-08. These samples were derived from operations with Black Thunder Mine Wyoming subbituminous coal, simulated mixed waste plastics, and pyrolysis oils derived from waste plastics and waste tires. Comparison of characteristics among the PB-08 samples was made to ascertain the effects of feed composition changes. A comparison also was made to samples from a previous test (Run PB-06) made in the same processing unit, with Black Thunder Mine coal, and in one run condition with co-fed mixed plastics

  7. Dispersed catalysts for co-processing and coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Bockrath, B.; Parfitt, D.; Miller, R. [Pittsburgh Energy Technology Center, PA (United States)

    1995-12-31

    The basic goal is to improve dispersed catalysts employed in the production of clean fuels from low value hydrocarbons. The immediate objective is to determine how the properties of the catalysts may be altered to match the demands placed on them by the properties of the feedstock, the qualities of the desired end products, and the economic constraints put upon the process. Several interrelated areas of the application of dispersed catalysts to co-processing and coal conversion are under investigation. The first involves control of the selectivity of MoS{sub 2} catalysts for HDN, HDS, and hydrogenation of aromatics. A second area of research is the development and use of methods to evaluate dispersed catalysts by means of activity and selectivity tests. A micro-flow reactor has been developed for determining intrinsic reactivities using model compounds, and will be used to compare catalysts prepared in different ways. Micro-autoclaves will also be used to develop data in batch experiments at higher partial pressures of hydrogen. The third area under investigation concerns hydrogen spillover reactions between MoS{sub 2} catalysts and carbonaceous supports. Preliminary results obtained by monitoring H{sub 2}/D{sub 2} exchange reactions with a pulse-flow microreactor indicate the presence of spillover between MoS{sub 2} and a graphitic carbon. A more complete study will be made at a later stage of the project. Accomplishments and conclusions are discussed.

  8. Anaerobic digestion of post-hydrothermal liquefaction wastewater for improved energy efficiency of hydrothermal bioenergy processes.

    Science.gov (United States)

    Zhou, Yan; Schideman, Lance; Zheng, Mingxia; Martin-Ryals, Ana; Li, Peng; Tommaso, Giovana; Zhang, Yuanhui

    2015-01-01

    Hydrothermal liquefaction (HTL) is a promising process for converting wet biomass and organic wastes into bio-crude oil. It also produces an aqueous product referred to as post-hydrothermal liquefaction wastewater (PHWW) containing up to 40% of the original feedstock carbon, which reduces the overall energy efficiency of the HTL process. This study investigated the feasibility of using anaerobic digestion (AD) to treat PHWW, with the aid of activated carbon. Results showed that successful AD occurred at relatively low concentrations of PHWW (≤ 6.7%), producing a biogas yield of 0.5 ml/mg CODremoved, and ∼53% energy recovery efficiency. Higher concentrations of PHWW (≥13.3%) had an inhibitory effect on the AD process, as indicated by delayed, slower, or no biogas production. Activated carbon was shown to effectively mitigate this inhibitory effect by enhancing biogas production and allowing digestion to proceed at higher PHWW concentrations (up to 33.3%), likely due to sequestering toxic organic compounds. The addition of activated carbon also increased the net energy recovery efficiency of AD with a relatively high concentration of PHWW (33.3%), taking into account the energy for producing activated carbon. These results suggest that AD is a feasible approach to treat PHWW, and to improve the energy efficiency of the HTL processes.

  9. Coal liquefaction process streams characterization and evaluation: Application of liquid chromatographic separation methods to THF-soluble portions of integrated two-stage coal liquefaction resids

    Energy Technology Data Exchange (ETDEWEB)

    Green, J.B.; Pearson, C.D.; Young, L.L.; Green, J.A. [National Inst. for Petroleum and Energy Research, Bartlesville, OK (United States)

    1992-05-01

    This study demonstrated the feasibility of using non-aqueous ion exchange liquid chromatography (NIELC) for the examination of the tetrahydrofuran (THF)-soluble distillation resids and THF-soluble whole oils derived from direct coal liquefaction. The technique can be used to separate the material into a number of acid, base, and neutral fractions. Each of the fractions obtained by NIELC was analyzed and then further fractionated by high-performance liquid chromatography (HPLC). The separation and analysis schemes are given in the accompanying report. With this approach, differences can be distinguished among samples obtained from different process streams in the liquefaction plant and among samples obtained at the same sampling location, but produced from different feed coals. HPLC was directly applied to one THF-soluble whole process oil without the NIELC preparation, with limited success. The direct HPLC technique used was directed toward the elution of the acid species into defined classes. The non-retained neutral and basic components of the oil were not analyzable by the direct HPLC method because of solubility limitations. Sample solubility is a major concern in the application of these techniques.

  10. Techno-economic optimisation of three gas liquefaction processes for small-scale applications

    DEFF Research Database (Denmark)

    Nguyen, Tuong-Van; Rothuizen, Erasmus Damgaard; Elmegaard, Brian

    2016-01-01

    inventory. The present work investigates three configurations (single-mixed refrigerant, single and dual reverse Brayton cycles) for small-scale applications, which are optimised and evaluated individually. The influences of the refrigerant properties and process technologies are analysed, and the most...... promising cycle setups are identified. The findings illustrate the resulting trade-offs between the system performance and investment costs, which differ significantly with the type of refrigeration cycle. Although these configurations are suitable for small-scale applications, mixed-refrigerant processes...... thermodynamic models leads to relative deviations of up to 1% for the power consumption and 20% for the network conductance. Particular caution should thus be exercised when extrapolating the results of process models to the design of actual gas liquefaction systems....

  11. (Pittsburgh Energy Technology Center): Quarterly technical progress report for the period ending June 30, 1987. [Advanced Coal Research and Technology Development Programs

    Energy Technology Data Exchange (ETDEWEB)

    None

    1988-02-01

    Research programs on coal and coal liquefaction are presented. Topics discussed are: coal science, combustion, kinetics, surface science; advanced technology projects in liquefaction; two stage liquefaction and direct liquefaction; catalysts of liquefaction; Fischer-Tropsch synthesis and thermodynamics; alternative fuels utilization; coal preparation; biodegradation; advanced combustion technology; flue gas cleanup; environmental coordination, and technology transfer. Individual projects are processed separately for the data base. (CBS)

  12. Design optimization of single mixed refrigerant natural gas liquefaction process using the particle swarm paradigm with nonlinear constraints

    International Nuclear Information System (INIS)

    Khan, Mohd Shariq; Lee, Moonyong

    2013-01-01

    The particle swarm paradigm is employed to optimize single mixed refrigerant natural gas liquefaction process. Liquefaction design involves multivariable problem solving and non-optimal execution of these variables can waste energy and contribute to process irreversibilities. Design optimization requires these variables to be optimized simultaneously; minimizing the compression energy requirement is selected as the optimization objective. Liquefaction is modeled using Honeywell UniSim Design ™ and the resulting rigorous model is connected with the particle swarm paradigm coded in MATLAB. Design constraints are folded into the objective function using the penalty function method. Optimization successfully improved efficiency by reducing the compression energy requirement by ca. 10% compared with the base case. -- Highlights: ► The particle swarm paradigm (PSP) is employed for design optimization of SMR NG liquefaction process. ► Rigorous SMR process model based on UniSim is connected with PSP coded in MATLAB. ► Stochastic features of PSP give more confidence in the optimality of complex nonlinear problems. ► Optimization with PSP notably improves energy efficiency of the SMR process.

  13. Indirect liquefaction of coal. [Coal gasification plus Fischer-Tropsch, methanol or Mobil M-gasoline process

    Energy Technology Data Exchange (ETDEWEB)

    None

    1980-06-30

    The most important potential environmental problems uniquely associated with indirect liquefaction appear to be related to the protection of occupational personnel from the toxic and carcinogenic properties of process and waste stream constituents, the potential public health risks from process products, by-products and emissions and the management of potentially hazardous solid wastes. The seriousness of these potential problems is related partially to the severity of potential effects (i.e., human mortality and morbidity), but even more to the uncertainty regarding: (1) the probable chemical characteristics and quantities of process and waste streams; and (2) the effectiveness and efficiencies of control technologies not yet tested on a commercial scale. Based upon current information, it is highly improbable that these potential problems will actually be manifested or pose serious constraints to the development of indirect liquefaction technologies, although their potential severity warrants continued research and evaluation. The siting of indirect liquefaction facilities may be significantly affected by existing federal, state and local regulatory requirements. The possibility of future changes in environmental regulations also represents an area of uncertainty that may develop into constraints for the deployment of indirect liquefaction processes. Out of 20 environmental issues identified as likely candidates for future regulatory action, 13 were reported to have the potential to impact significantly the commercialization of coal synfuel technologies. These issues are listed.

  14. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Rudolf, Andreas

    2011-01-01

    This article reviews the hydrothermal liquefaction of biomass with the aim of describing the current status of the technology. Hydrothermal liquefaction is a medium-temperature, high-pressure thermochemical process, which produces a liquid product, often called bio-oil or bi-crude. During...... the hydrothermal liquefaction process, the macromolecules of the biomass are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive and can recombine into larger ones. During this process, a substantial part of the oxygen in the biomass is removed...... by dehydration or decarboxylation. The chemical properties of bio-oil are highly dependent of the biomass substrate composition. Biomass constitutes of various components such as protein; carbohydrates, lignin and fat, and each of them produce distinct spectra of compounds during hydrothermal liquefaction...

  15. Renewable chemical feedstocks from integrated liquefaction processing of lingocellulosic materials using microwave energy

    Science.gov (United States)

    Junming Xu; Jianchun Jiang; Chung-Yun Hse; Todd F. Shupe

    2012-01-01

    The objective of this investigation was to find a simple method for the production of phenolic rich products and sugar derivatives (biopolyols) via separation of liquefied lingocellulosic materials. Liquefaction of lignocellulosic materials was conducted in methanol at 180 °C for 15 min with the conversion of raw materials at about 75%. After liquefaction, the...

  16. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, July 1--September 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1995-12-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. Some of the contract activities for this quarter are: We completed many of the analyses on the 81 samples received from HTI bench-scale run CMSL-9, in which coal, coal/mixed plastics, and coal/high density polyethylene were fed; Liquid chromatographic separations of the 15 samples in the University of Delaware sample set were completed; and WRI completed CP/MAS {sup 13}C-NMR analyses on the Delaware sample set.

  17. A characterization and evaluation of coal liquefaction process streams. Quarterly report, January 1--March 31, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Heunisch, G.W.; Winschel, R.A.

    1998-08-01

    Described in this report are the following activities: CONSOL characterized process stream samples from HTI Run ALC-2, in which Black Thunder Mine coal was liquefied using four combinations of dispersed catalyst precursors. Oil assays were completed on the HTI Run PB-05 product blend. Fractional distillation of the net product oil of HTI Run POC-1 was completed. CONSOL completed an evaluation of the potential for producing alkylphenyl ethers from coal liquefaction phenols. At the request of DOE, various coal liquid samples and relevant characterization data were supplied to the University of West Virginia and the Federal Energy Technology Center. The University of Delaware is conducting resid reactivity tests and is completing the resid reaction computer model. The University of Delaware was instructed on the form in which the computer model is to be delivered to CONSOL.

  18. EDS Coal Liquefaction Process Development. Phase V. Laboratory evaluation of the characteristics of EDS Illinois bottoms

    Energy Technology Data Exchange (ETDEWEB)

    Lao, T C; Levasseur, A A

    1984-02-01

    This interim report documents work carried out by Combustion Engineering, Inc. under a contract to Exxon Research and Engineering Company to develop a conceptual Hybrid Boiler design fueled by the vacuum distillation residue (vacuum bottoms) derived from Illinois No. 6 coal in the EDS Coal Liquefaction Process. This report was prepared by Combustion Engineering, Inc., and is the first of two reports on the predevelopment phase of the Hybrid Boiler program. This report covers the results of a laboratory investigation to assess the fuel and ash properties of EDS vacuum bottoms. The results of the laboratory testing reported here were used in conjunction with Combustion Engineering's design experience to predict fuel performance and to develop appropriate boiler design parameters. These boiler design parameters were used to prepare the engineering design study reported in EDS Interim Report FE-2893-113, the second of the two reports on the predevelopment phase of the Hybrid Boiler Program. 46 figures, 29 tables.

  19. Hydrothermal Liquefaction of Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.

    2010-12-10

    Hydrothermal liquefaction technology is describes in its relationship to fast pyrolysis of biomass. The scope of work at PNNL is discussed and some intial results are presented. HydroThermal Liquefaction (HTL), called high-pressure liquefaction in earlier years, is an alternative process for conversion of biomass into liquid products. Some experts consider it to be pyrolysis in solvent phase. It is typically performed at about 350 C and 200 atm pressure such that the water carrier for biomass slurry is maintained in a liquid phase, i.e. below super-critical conditions. In some applications catalysts and/or reducing gases have been added to the system with the expectation of producing higher yields of higher quality products. Slurry agents ('carriers') evaluated have included water, various hydrocarbon oils and recycled bio-oil. High-pressure pumping of biomass slurry has been a major limitation in the process development. Process research in this field faded away in the 1990s except for the HydroThermal Upgrading (HTU) effort in the Netherlands, but has new resurgence with other renewable fuels in light of the increased oil prices and climate change concerns. Research restarted at Pacific Northwest National Laboratory (PNNL) in 2007 with a project, 'HydroThermal Liquefaction of Agricultural and Biorefinery Residues' with partners Archer-Daniels-Midland Company and ConocoPhillips. Through bench-scale experimentation in a continuous-flow system this project investigated the bio-oil yield and quality that could be achieved from a range of biomass feedstocks and derivatives. The project was completed earlier this year with the issuance of the final report. HydroThermal Liquefaction research continues within the National Advanced Biofuels Consortium with the effort focused at PNNL. The bench-scale reactor is being used for conversion of lignocellulosic biomass including pine forest residue and corn stover. A complementary project is an international

  20. Prospect of coal liquefaction in Indonesia

    International Nuclear Information System (INIS)

    Hartiniati; Dasuki, A.S.; Artanto, Yu.; Sulaksono, D.; Gunanjar

    1997-01-01

    With the current known oil reserves of about 11 billion barrel and annual production of approximately 500 million barrel, the country's oil reserves will be depleted by 2010, and Indonesia would have become net oil importer if no major oil fields be found somewhere in the archipelago. Under such circumstances the development of new sources of liquid fuel becomes a must, and coal liquefaction can be one possible solution for the future energy problem in Indonesia, particularly in the transportation sector due to the availability of coal in huge amount. This paper present the prospect of coal liquefaction in Indonesia and look at the possibility of integrating the process with HTR as a heat supplier. Evaluation of liquidability of several low grade Indonesian coals will also be presented. Coal from South Banko-Tanjung Enim is found to be one of the most suitable coal for liquefaction. Several studies show that an advanced coal liquefaction technology recently developed has the potential to reduce not only the environmental impact but also the production cost. The price of oil produced in the year 2000 is expected to reach US $ 17.5 ∼ 19.2/barrel and this will compete with the current oil price. Not much conclusion can be drawn from the idea of integrating HTR with coal liquefaction plant due to limited information available. (author). 7 figs, 3 tabs

  1. Applied research and evaluation of process concepts for liquefaction and gasification of western coals. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Wiser, W. H.

    1980-09-01

    Fourteen sections, including five subsections, of the final report covering work done between June 1, 1975 to July 31, 1980 on research programs in coal gasification and liquefaction have been entered individually into EDB and ERA. (LTN)

  2. Achievement report for fiscal 1982 on Sunshine Program. Research and development of coal liquefaction technology (Conceptual designs for coal liquefaction pilot plants - Solvent extraction liquefaction process); 1982 nendo sekitan ekika gijutsu no kenkyu kaihatsu seika hokokusho. Sekitan ekika pilot plant no gainen sekkei (yozai chushutsu ekikaho)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1983-03-01

    This research aims to prepare conceptual designs for a 250t/d-class and 500t/d-class coal liquefaction pilot plants based on the achievement of research on solvent extraction liquefaction of coal. It also aims to define the solvent extraction process and provide decision-making material relative to the development and promotion of coal liquefaction technologies in the future. Development started in 1978 of the technology of solvent extraction liquefaction of coal, and a 1t/d PDU (process development unit) was completed in 1981. Studies through its operation have continued for more than 3000 hours already, and technical data are being accumulated steadily. Techniques acquired through operating the 1t/d PDU have been put together, and rough process conditions are established. A rough process result is achieved of the same conditions. In these two respects, the newly developed process is equal to other processes. The phenomena in this process are roughly grasped. It is deemed that, with the existing technique combined with the technique acquired here, a technological level has been reached where conceptual designs of large pilot plants may be worked out for solvent extraction liquefaction of coal. Under the circumstances, with a view to developing a commercial plant whose main products will be fuel oils, conceptual designs are prepared for large pilot plants, and are compiled into this report. (NEDO)

  3. Hydrothermal processing of fermentation residues in a continuous multistage rig – Operational challenges for liquefaction, salt separation, and catalytic gasification

    International Nuclear Information System (INIS)

    Zöhrer, H.; De Boni, E.; Vogel, F.

    2014-01-01

    Fermentation residues are a waste stream of biomethane production containing substantial amounts of organic matter, and thus representing a primary energy source which is mostly unused. For the first time this feedstock was tested for catalytic gasification in supercritical water (T ≥ 374 °C, p ≥ 22 MPa) for methane production. The processing steps include hydrothermal liquefaction, salt separation, as well as catalytic gasification over a ruthenium catalyst in supercritical water. In continuous experiments at a feed rate of 1 kg h −1 a partial liquefaction and carbonization of some of the solids was observed. Significant amounts of heavy tars were formed. Around 50% of the feed carbon remained in the rig. Furthermore, a homogeneous coke was formed, presumably originating from condensed tars. The mineralization of sulfur and its separation in the salt separator was insufficient, because most of the sulfur was still organically bound after liquefaction. Desalination was observed at a salt separator set point temperature of 450 °C and 28 MPa; however, some of the salts could not be withdrawn as a concentrated brine. At 430 °C no salt separation took place. Higher temperatures in the salt separator were found to promote tar and coke formation, resulting in conflicting process requirements for efficient biomass liquefaction and desalination. In the salt separator effluent, solid crystals identified as struvite (magnesium ammonium phosphate) were found. This is the first report of struvite formation from a supercritical water biomass conversion process and represents an important finding for producing a fertilizer from the separated salt brine. - Highlights: • Continuous processing of fermentation residues in sub- and supercritical water. • Continuous separation of salt brines at supercritical water conditions. • Struvite crystals (magnesium ammonium phosphate) were recovered from the effluent. • Separation of sulfur from the biomass could

  4. Studies on catalytic hydrotreating of recycled solvents from coal liquefaction process. Part 1. Characteristics changes of recycled solvents during hydrotreating

    Energy Technology Data Exchange (ETDEWEB)

    Morimura, Y.; Nakata, S.; Yokota, Y.; Shirota, Y.; Nakamura, M. [Chiyoda Corp., Tokyo (Japan); Mitarai, Y. [Sumitomo Metal Mining Co. Ltd., Tokyo (Japan); Inoue, Y. [Nippon Ketjen Co. Ltd., Tokyo (Japan)

    1995-07-01

    A bituminous coal liquefaction process, called the NEDOL process, is under development by the New Energy and Industrial Technology Development Organization (NEDO). Important features of this process include the capacity to produce hydrogen-donatable solvents, obtained by hydrogenation of middle distillates of coal derived oils, and to recycle these solvents to a liquefaction stage as hydrogen donor solvents. These recycled solvents, obtained by liquefaction of Wandoan coal, and their catalytic hydrotreated oils, have been extensively characterized, using a variety of analytical methods. The following items have been examined and are discussed in this study: (1) Influence of chemical hydrogen consumption on the reactivities of hydrodesulfurization (HDS), hydrodenitrogenation (HDN), hydrodeoxygenation (HDO) and hydrogenation of aromatic-rings, during hydrotreating; (2) Changes in composition of hydrocarbon types, nitrogen- and oxygen-containing compounds, as a function of chemical hydrogen consumption; (3) Changes of average molecular weights; (4) Characteristics changes of oxygen- and nitrogen-containing compounds, and reactivities of HDO and HDN; (5) Characteristics changes of donatable hydrogen as a function of a degree of hydrogenation ({delta}fa). 14 refs., 14 figs., 3 tabs.

  5. Report on results for fiscal 1997 on development of coal liquefaction technology . Development of liquefaction base technology (studies on development and internationalization of environmentally benign coal liquefaction technology); 1997 nendo sekitan ekika gijutsu seika hokokusho. Ekika kiban gijutsu no kaihatsu (kankyo chowagata sekitan ekika gijutsu no kaihatsu oyobi kokusaika kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The research objective is the development of environmentally benign coal liquefaction technology and the studies on internationalization of coal liquefaction technology. Implemented for the former are (1) research on improvement and rationalization of liquefaction process and (2) research on advancement of liquefaction base technology. In (1), studies were made on in-oil preprocessing technology and scale suppressing measures for the purpose of obtaining reform/high grade of coal, and on improvement of liquefied oil collecting ratio, sophistication of coal slurry and attainment of light oil/high grade from liquefied crude oil for the purpose of optimizing liquefaction reactive conditions and improving a solvent. In (2), in developing high activity/high dispersion type new catalysts, catalytic sufurization behavior and activity manifestation mechanism were explored, as were iron hydroxide based iron ore properties and liquefaction reactive characteristics. The initial reactive characteristics of liquefaction for example were investigated for the purpose of collecting basic data for expanding kinds of coal. In order to attain the latter objective of the research, a feasibility study of liquefaction location was conducted, as were the investigation including sampling of iron ore for catalytic material and the investigation of coal gasification technology. After the completion of the Australian brown coal liquefaction project, the development of the coal liquefaction technology commenced in fiscal 1994 produced a number of useful records and ended in 1997. (NEDO)

  6. Coal liquefaction process streams characterization and evaluation: Estimation of total phenol concentrations in coal liquefaction resids by {sup 31}P NMR spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Mohan, J.T.; Verkade, J.G. [Ames Lab., IA (United States)

    1992-11-01

    In this study, Iowa State University researchers used {sub 31}P-tagged reagents to derivatize the labile hydrogen functional groups in the THF-soluble portion of 850{degrees}F{sup +} distillation resid materials and the THF-soluble portion of process oils derived from direct coal liquefaction.{sup 31}P-NMR was used to analyze the derivatized samples. NMR peak assignments can be made by comparison to model compounds similarly derivatized. Species can be quantified by integration of the NMR signals. Different {sup 31}P-NMR tagged reagents can be used to produce different degrees of peak resolution in the NMR spectrum. This, in turn, partially dictates the degree of speciation and/or quantification of species, or classes of compounds, that can be accomplished. Iowa State chose a {sup 31}P-tagged reagent (ClPOCMe{sub 2}CMe{sub 2}O) which was shown previously to be particularly useful in the derivatization of phenols. The derivatized samples all exhibited a small group of peaks attributed to amines and a broad group of peaks in the phenol region. The presence of paramagnetic species in the samples caused the NMR signals to broaden. Electron paramagnetic resonance (EPR) spectra confirmed the presence of paramagnetic organic free radicals in selected samples. Various methods were employed to process the NMR data. The complexity and broadness of the phenol peak, however, made speciation of the phenols impractical.

  7. Coal liquefaction process streams characterization and evaluation: Estimation of total phenol concentrations in coal liquefaction resids by [sup 31]P NMR spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Mohan, J.T.; Verkade, J.G. (Ames Lab., IA (United States))

    1992-11-01

    In this study, Iowa State University researchers used [sub 31]P-tagged reagents to derivatize the labile hydrogen functional groups in the THF-soluble portion of 850[degrees]F[sup +] distillation resid materials and the THF-soluble portion of process oils derived from direct coal liquefaction.[sup 31]P-NMR was used to analyze the derivatized samples. NMR peak assignments can be made by comparison to model compounds similarly derivatized. Species can be quantified by integration of the NMR signals. Different [sup 31]P-NMR tagged reagents can be used to produce different degrees of peak resolution in the NMR spectrum. This, in turn, partially dictates the degree of speciation and/or quantification of species, or classes of compounds, that can be accomplished. Iowa State chose a [sup 31]P-tagged reagent (ClPOCMe[sub 2]CMe[sub 2]O) which was shown previously to be particularly useful in the derivatization of phenols. The derivatized samples all exhibited a small group of peaks attributed to amines and a broad group of peaks in the phenol region. The presence of paramagnetic species in the samples caused the NMR signals to broaden. Electron paramagnetic resonance (EPR) spectra confirmed the presence of paramagnetic organic free radicals in selected samples. Various methods were employed to process the NMR data. The complexity and broadness of the phenol peak, however, made speciation of the phenols impractical.

  8. Plasma electrolytic liquefaction of cellulosic biomass

    Science.gov (United States)

    Dingliang, TANG; Xianhui, ZHANG; Si-ze, YANG

    2018-04-01

    In this paper, the rapid liquefaction of a corncob was achieved by plasma electrolysis, providing a new method for cellulosic biomass liquefaction. The liquefaction rate of the corncob was 95% after 5 min with polyethylene glycol and glycerol as the liquefying agent. The experiments not only showed that H+ ions catalyzed the liquefaction of the corncob, but also that using accelerated H+ ions, which were accelerated by an electric field, could effectively improve the liquefaction efficiency. There was an obvious discharge phenomenon, in which the generated radicals efficiently heated the solution and liquefied the biomass, in the process of plasma electrolytic liquefaction. Finally, the optimum parameters of the corncob liquefaction were obtained by experimentation, and the liquefaction products were analyzed.

  9. Cooperative research in coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, G.P.; Sendlein, L.V.A. (eds.)

    1991-05-28

    Significant progress was made in the May 1990--May 1991 contract period in three primary coal liquefaction research areas: catalysis, structure-reactivity studies, and novel liquefaction processes. A brief summary of the accomplishments in the past year in each of these areas is given.

  10. Development of an extruder-feeder biomass direct liquefaction process. Volume 2, Parts 4--8: Final report

    Energy Technology Data Exchange (ETDEWEB)

    White, D.H.; Wolf, D. [Arizona Univ., Tucson, AZ (United States). Dept. of Chemical Engineering

    1991-10-01

    As an abundant, renewable, domestic energy resource, biomass could help the United States reduce its dependence on imported oil. Biomass is the only renewable energy technology capable of addressing the national need for liquid transportation fuels. Thus, there is an incentive to develop economic conversion processes for converting biomass, including wood, into liquid fuels. Through research sponsored by the US DOE`s Biomass Thermochemical Conversion Program, the University of Arizona has developed a unique biomass direct liquefaction system. The system features a modified single-screw extruder capable of pumping solid slurries containing as high as 60 wt% wood flour in wood oil derived vacuum bottoms at pressures up to 3000 psi. The extruder-feeder has been integrated with a unique reactor by the University to form a system which offers potential for improving high pressure biomass direct liquefaction technology. The extruder-feeder acts simultaneously as both a feed preheater and a pumping device for injecting wood slurries into a high pressure reactor in the biomass liquefaction process. An experimental facility was constructed and following shakedown operations, wood crude oil was produced by mid-1985. By July 1988, a total of 57 experimental continuous biomass liquefaction runs were made using White Birch wood feedstock. Good operability was achieved at slurry feed rates up to 30 lb/hr, reactor pressures from 800 to 3000 psi and temperatures from 350{degree}C to 430{degree}C under conditions covering a range of carbon monoxide feed rates and sodium carbonate catalyst addition. Crude wood oils containing as little as 6--10 wt% residual oxygen were produced. 38 refs., 82 figs., 26 tabs.

  11. Coal liquefaction in early stage of NEDOL process 1t/d PSU; 1t/d PSU ni okeru ekika shoki hanno ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Ikeda, K.; Kawabata, M.; Mochizuki, M.; Imada, K. [Nippon Steel Corp., Tokyo (Japan); Nogami, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan)

    1996-10-28

    To investigate the behavior of coal liquefaction reaction in early stage as a part of studies on the coal liquefaction characteristics using NEDOL process 1 t/d process supporting unit (PSU), coal slurry sample was taken from the outlet of slurry preheater located in the upflow of liquefaction reactors, and was tested. Tanito Harum coal was used for liquefaction. Preheater was operated under the condition of pressure of 170 kg/cm{sup 2}, gas flow rate of 64 Nm{sup 3}/hr, and at temperature up to 410{degree}C at the outlet, in response to the standard test condition. The slurry sample was discharged into a high temperature separator with temperature of 250{degree}C. Liquefaction was not proceeded at the outlet of preheater. Solid residue yielded around 80%, and liquid yielded around 15%. Gases, CO and CO2, and water yielded also small amount around 3%. The solid sample contained much IOM fraction (tetrahydrofuran-insoluble and ash), and the liquid contained much heavy oil fraction. Hydrogenation was not proceeded, and the hydrogen consumption was very low showing below one-tenth of that at the usual operation. Hydrogen sulfide gas was formed at early stage, which suggested that the change of iron sulfide catalyst occur at early stage of liquefaction. 1 ref., 5 figs., 2 tabs.

  12. Effect of process parameters on hydrothermal liquefaction of oil palm biomass for bio-oil production and its life cycle assessment

    International Nuclear Information System (INIS)

    Chan, Yi Herng; Yusup, Suzana; Quitain, Armando T.; Tan, Raymond R.; Sasaki, Mitsuru; Lam, Hon Loong; Uemura, Yoshimitsu

    2015-01-01

    Highlights: • Water is used as a clean solvent to liquefy palm biomass to bio-oil. • The optimum liquefaction condition of oil palm biomass is 390 °C and 25 MPa. • Optimum reaction time for liquefaction of empty fruit bunch and palm mesocarp fiber is 120 min. • Optimum reaction time for liquefaction of palm kernel shell is 240 min. • From the life cycle assessment, a net 2.29 kg CO 2 equivalent is generated per kg of bio-oil produced. - Abstract: This paper presents the studies on the effect of three process parameters; temperature, pressure and reaction time on the subcritical and supercritical hydrothermal liquefaction of oil palm empty fruit bunch, palm mesocarp fiber and palm kernel shell. The effect of temperature (330–390 °C), pressure (25–35 MPa) and reaction time (30–240 min) on bio-oil yields were investigated using a Inconel batch reactor. The optimum liquefaction condition for empty fruit bunch, palm mesocarp fiber and palm kernel shell was at supercritical condition of water; 390 °C and 25 MPa. For the effect of reaction time, bio-oil from empty fruit bunch and palm mesocarp fiber attained maximum yields at 120 min, whereas bio-oil yield from palm kernel shell continued to increase at reaction time of 240 min. Lastly, a life cycle assessment based on a conceptual biomass hydrothermal liquefaction process for bio-oil production was constructed and presented

  13. Simulation and statistical analysis for the optimization of nitrogen liquefaction plant with cryogenic Claude cycle using process modeling tool: ASPEN HYSYS

    International Nuclear Information System (INIS)

    Joshi, D.M.

    2017-01-01

    Cryogenic technology is used for liquefaction of many gases and it has several applications in food process engineering. Temperatures below 123 K are considered to be in the field of cryogenics. Extreme low temperatures are a basic need for many industrial processes and have several applications, such as superconductivity of magnets, space, medicine and gas industries. Several methods can be used to obtain the low temperatures required for liquefaction of gases. The process of cooling or refrigerating a gas to a temperature below its critical temperature so that liquid can be formed at some suitable pressure, which is below the critical pressure, is the basic liquefaction process. Different cryogenic cycle configurations are designed for getting the liquefied form of gases at different temperatures. Each of the cryogenic cycles like Linde cycle, Claude cycle, Kapitza cycle or modified Claude cycle has its own advantages and disadvantages. The placement of heat exchangers, Joule-Thompson valve and turboexpander decides the configuration of a cryogenic cycle. Each configuration has its own efficiency according to the application. Here, a nitrogen liquefaction plant is used for the analysis purpose. The process modeling tool ASPEN HYSYS can provide a software simulation approach before the actual implementation of the plant in the field. This paper presents the simulation and statistical analysis of the Claude cycle with the process modeling tool ASPEN HYSYS. It covers the technique used to optimize the liquefaction of the plant. The simulation results so obtained can be used as a reference for the design and optimization of the nitrogen liquefaction plant. Efficient liquefaction will give the best performance and productivity to the plant.

  14. Simulation and statistical analysis for the optimization of nitrogen liquefaction plant with cryogenic Claude cycle using process modeling tool: ASPEN HYSYS

    Science.gov (United States)

    Joshi, D. M.

    2017-09-01

    Cryogenic technology is used for liquefaction of many gases and it has several applications in food process engineering. Temperatures below 123 K are considered to be in the field of cryogenics. Extreme low temperatures are a basic need for many industrial processes and have several applications, such as superconductivity of magnets, space, medicine and gas industries. Several methods can be used to obtain the low temperatures required for liquefaction of gases. The process of cooling or refrigerating a gas to a temperature below its critical temperature so that liquid can be formed at some suitable pressure, which is below the critical pressure, is the basic liquefaction process. Different cryogenic cycle configurations are designed for getting the liquefied form of gases at different temperatures. Each of the cryogenic cycles like Linde cycle, Claude cycle, Kapitza cycle or modified Claude cycle has its own advantages and disadvantages. The placement of heat exchangers, Joule-Thompson valve and turboexpander decides the configuration of a cryogenic cycle. Each configuration has its own efficiency according to the application. Here, a nitrogen liquefaction plant is used for the analysis purpose. The process modeling tool ASPEN HYSYS can provide a software simulation approach before the actual implementation of the plant in the field. This paper presents the simulation and statistical analysis of the Claude cycle with the process modeling tool ASPEN HYSYS. It covers the technique used to optimize the liquefaction of the plant. The simulation results so obtained can be used as a reference for the design and optimization of the nitrogen liquefaction plant. Efficient liquefaction will give the best performance and productivity to the plant.

  15. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Hoffmann, Jessica

    2014-01-01

    Biomass is one of the most abundant sources of renewable energy, and will be an important part of a more sustainable future energy system. In addition to direct combustion, there is growing attention on conversion of biomass into liquid en-ergy carriers. These conversion methods are divided...... into biochemical/biotechnical methods and thermochemical methods; such as direct combustion, pyrolysis, gasification, liquefaction etc. This chapter will focus on hydrothermal liquefaction, where high pressures and intermediate temperatures together with the presence of water are used to convert biomass...... into liquid biofuels, with the aim of describing the current status and development challenges of the technology. During the hydrothermal liquefaction process, the biomass macromolecules are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive...

  16. Demineralization of Sargassum spp. Macroalgae Biomass: Selective Hydrothermal Liquefaction Process for Bio-Oil Production

    Energy Technology Data Exchange (ETDEWEB)

    Díaz-Vázquez, Liz M., E-mail: limdiaz@uprrp.edu; Rojas-Pérez, Arnulfo; Fuentes-Caraballo, Mariela; Robles, Isis V. [Department of Chemistry, University of Puerto Rico Río Piedras Campus, San Juan, PR (United States); Jena, Umakanta [Bioenergy Laboratory, Desert Research Institute, Reno, NV (United States); Das, K. C. [College of Engineering, University of Georgia, Athens, GA (United States)

    2015-02-11

    Algae biomasses are considered a viable option for the production of biofuel because of their high yields of oil produced per dry weight. Brown macroalgae Sargassum spp. are one of the most abundant species of algae in the shores of Puerto Rico. Its availability in large quantity presents a great opportunity for use as a source of renewable energy. However, high ash content of macroalgae affects the conversion processes and the quality of resulting fuel products. This research studied the effect of different demineralization treatments of Sargassum spp. biomass, subsequent hydrothermal liquefaction (HTL), and bio-oil characterization. Demineralization constituted five different treatments: nanopure water, nitric acid, citric acid, sulfuric acid, and acetic acid. Performance of demineralization was evaluated by analyzing both demineralized biomass and HTL products by the following analyses: total carbohydrates, proteins, lipids, ash content, caloric content, metals analysis, Fourier transform infrared-attenuated total reflectance spectroscopy, energy dispersive spectroscopy, scanning electron microscopy, and GCMS analysis. HTL of Sargassum spp. before and after citric acid treatment was performed in a 1.8 L batch reactor system at 350°C with a holding time of 60 min and high pressures (5–21 MPa). Demineralization treatment with nitric acid was found the most effective in reducing the ash content of the macroalgae biomass from 27.46 to 0.99% followed by citric acid treatment that could reduce the ash content to 7%. Citric acid did not show significant leaching of organic components such as carbohydrates and proteins, and represented a less toxic and hazardous option for demineralization. HTL of untreated and citric acid treated Sargassum spp. resulted in bio-oil yields of 18.4 ± 0.1 and 22.2 ± 0.1% (ash-free dry basis), respectively.

  17. Demineralization of Sargassum spp. Macroalgae Biomass: Selective Hydrothermal Liquefaction Process for Bio-Oil Production

    International Nuclear Information System (INIS)

    Díaz-Vázquez, Liz M.; Rojas-Pérez, Arnulfo; Fuentes-Caraballo, Mariela; Robles, Isis V.; Jena, Umakanta; Das, K. C.

    2015-01-01

    Algae biomasses are considered a viable option for the production of biofuel because of their high yields of oil produced per dry weight. Brown macroalgae Sargassum spp. are one of the most abundant species of algae in the shores of Puerto Rico. Its availability in large quantity presents a great opportunity for use as a source of renewable energy. However, high ash content of macroalgae affects the conversion processes and the quality of resulting fuel products. This research studied the effect of different demineralization treatments of Sargassum spp. biomass, subsequent hydrothermal liquefaction (HTL), and bio-oil characterization. Demineralization constituted five different treatments: nanopure water, nitric acid, citric acid, sulfuric acid, and acetic acid. Performance of demineralization was evaluated by analyzing both demineralized biomass and HTL products by the following analyses: total carbohydrates, proteins, lipids, ash content, caloric content, metals analysis, Fourier transform infrared-attenuated total reflectance spectroscopy, energy dispersive spectroscopy, scanning electron microscopy, and GCMS analysis. HTL of Sargassum spp. before and after citric acid treatment was performed in a 1.8 L batch reactor system at 350°C with a holding time of 60 min and high pressures (5–21 MPa). Demineralization treatment with nitric acid was found the most effective in reducing the ash content of the macroalgae biomass from 27.46 to 0.99% followed by citric acid treatment that could reduce the ash content to 7%. Citric acid did not show significant leaching of organic components such as carbohydrates and proteins, and represented a less toxic and hazardous option for demineralization. HTL of untreated and citric acid treated Sargassum spp. resulted in bio-oil yields of 18.4 ± 0.1 and 22.2 ± 0.1% (ash-free dry basis), respectively.

  18. Demineralization of Sargassum spp. macroalgae biomass: selective hydrothermal liquefaction process for bio-oil production

    Directory of Open Access Journals (Sweden)

    Liz M Díaz-Vázquez

    2015-02-01

    Full Text Available Algae biomasses are considered a viable option for the production of biofuel because of their high yields of oil produced per dry weight. Brown macroalgae Sargassum spp. are one of the most abundant species of algae in the shores of Puerto Rico. Its availability in large quantity presents a great opportunity for use as a source of renewable energy. However, high ash content of macroalgae affects the conversion processes and the quality of resulting fuel products. This research studied the effect of different demineralization treatments of Sargassum spp. biomass, subsequent hydrothermal liquefaction (HTL and bio-oil characterization. Demineralization constituted five different treatments: nanopure water, nitric acid, citric acid, sulfuric acid, and acetic acid. Performance of demineralization was evaluated by analyzing both demineralized biomass and HTL products by the following analyses: total carbohydrates, proteins, lipids, ash content, caloric content, metals analysis, Fourier Transform Infrared - Attenuated Total Reflectance (FTIR-ATR Spectroscopy, Energy Dispersive Spectroscopy (EDS, Scanning Electron Microscopy (SEM, and GCMS analysis. HTL of Sargassum spp. before and after citric acid treatment, was performed in a 1.8 L batch reactor system at 350°C with a holding time of 60 min and high pressures (5-21 MPa. Demineralization treatment with nitric acid was found the most effective in reducing the ash content of the macroalgae biomass from 27.46% to 0.99% followed by citric acid treatment that could reduce the ash content to 7%. Citric acid did not show significant leaching of organic components such as carbohydrates and proteins, and represented a less toxic and hazardous option for demineralization. HTL of untreated and citric acid treated Sargassum spp. resulted in bio-oil yields of 18.4±0.1 % and 22.2±0.1 % (ash free dry basis, respectively.

  19. Effect of process parameters on solvolysis liquefaction of Chlorella pyrenoidosa in ethanol–water system and energy evaluation

    International Nuclear Information System (INIS)

    Peng, Xiaowei; Ma, Xiaoqian; Lin, Yousheng; Wang, Xusheng; Zhang, Xiaoshen; Yang, Cheng

    2016-01-01

    Highlights: • Microalgae liquefaction in ethanol–water promoted bio-oil yield and property. • There existed synergistic effect between ethanol and water. • Ethanol contributed to deoxygenation and hydrogen-donating for bio-oil. • Net energy ratios of 20% and 40% ethanol were larger than pyrolysis technology. - Abstract: In this work, Chlorella pyrenoidosa was converted into bio-oil via solvolysis liquefaction in sub/supercritical ethanol–water system. The influence of reaction temperature (220–300 °C), retention time (0–120 min), solid/liquid ratio (6.3/75–50.0/75 g/mL) and ethanol content (0–100%) on bio-oil yield and property was investigated. The increase of reaction temperature and retention time both improved the bio-oil yield. The bio-oil yield increased firstly and then decreased when the solid/liquid ratio and ethanol content exceeded 18.8/75 g/mL and 80%, respectively. As the reaction temperature <260 °C and retention time <30 min, a soft and unsticky product was insoluble in dichloromethane (DCM) during the extraction process. The chemical composition of the DCM-insoluble product was analyzed by FTIR (Fourier Transform Infrared Spectrometry). The change tendency of O/C and H/C atomic ratio of bio-oil indicated that the addition of ethanol contributed to deoxygenation and hydrogen-donating for bio-oil, due to the dehydration and decarboxylation reaction. "1H NMR (hydrogen-1 nuclear magnetic resonance) analysis indicated that the main chemical compositions of bio-oil were aliphatic functional groups and heteroatomic functionalities (80.00–83.58%). The addition of ethanol enhanced the transesterification to form more ester. The NER (net energy ratio, the ratio of energy output to energy consumption) of solvolysis liquefaction in ethanol–water system (NER < 1) was less than that of hydrothermal liquefaction in sole water system (NER = 1.29), but the NERs of 20% and 40% ethanol content (NER = 0.91, 0.70 for 20% and 40% ethanol content

  20. Advanced uranium enrichment processes

    International Nuclear Information System (INIS)

    Clerc, M.; Plurien, P.

    1986-01-01

    Three advanced Uranium enrichment processes are dealt with in the report: AVLIS (Atomic Vapour LASER Isotope Separation), MLIS (Molecular LASER Isotope Separation) and PSP (Plasma Separation Process). The description of the physical and technical features of the processes constitutes a major part of the report. If further presents comparisons with existing industrially used enrichment technologies, gives information on actual development programmes and budgets and ends with a chapter on perspectives and conclusions. An extensive bibliography of the relevant open literature is added to the different subjects discussed. The report was drawn up by the nuclear research Centre (CEA) Saclay on behalf of the Commission of the European Communities

  1. Advanced information processing system

    Science.gov (United States)

    Lala, J. H.

    1984-01-01

    Design and performance details of the advanced information processing system (AIPS) for fault and damage tolerant data processing on aircraft and spacecraft are presented. AIPS comprises several computers distributed throughout the vehicle and linked by a damage tolerant data bus. Most I/O functions are available to all the computers, which run in a TDMA mode. Each computer performs separate specific tasks in normal operation and assumes other tasks in degraded modes. Redundant software assures that all fault monitoring, logging and reporting are automated, together with control functions. Redundant duplex links and damage-spread limitation provide the fault tolerance. Details of an advanced design of a laboratory-scale proof-of-concept system are described, including functional operations.

  2. Coal liquefaction and gas conversion contractors review conference: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-11-01

    This volume contains 55 papers presented at the conference. They are divided into the following topical sections: Direct liquefaction; Indirect liquefaction; Gas conversion (methane conversion); and Advanced research liquefaction. Papers in this last section deal mostly with coprocessing of coal with petroleum, plastics, and waste tires, and catalyst studies. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

  3. Design and analysis of a small-scale natural gas liquefaction process adopting single nitrogen expansion with carbon dioxide pre-cooling

    International Nuclear Information System (INIS)

    Yuan, Zongming; Cui, Mengmeng; Xie, Ying; Li, Chunlin

    2014-01-01

    With the growth of energy consumption and environmental protection concerns, it is of enormous economic and environmental values for the development of stranded gas. As a means for exploitation and transportation of stranded gas to market, a novel small-scale liquefaction process adopting single nitrogen expansion with carbon dioxide pre-cooling is put up with in this paper. Taking unit energy consumption as the target function, Aspen HYSYS is employed to simulate and optimize the process to achieve the liquefaction rate of 0.77 with unit energy consumption of 9.90 kW/kmol/h. Furthermore, the adaptability of this process under different pressure, temperature and compositions of feed gas is studied. Based on the optimization results, the exergy losses of main equipment in the process are evaluated and analyzed in details. With compact device, safety operation, simple capability, this liquefaction process proves to be suitable for the development of small gas reserves, satellite distribution fields of gas or coalbed methane fields. - Highlights: •A novel small-scale liquefaction process used in stranded gas is designed. •The adaptability of this process under different pressure, temperature and compositions of feed gas is studied. •The exergy analysis of main equipment in the process is analyzed

  4. Design and analysis of a small-scale natural gas liquefaction process adopting single nitrogen expansion with carbon dioxide pre-cooling

    Energy Technology Data Exchange (ETDEWEB)

    Yuan, Zongming; Cui, Mengmeng; Xie, Ying; Li, Chunlin

    2014-03-01

    With the growth of energy consumption and environmental protection concerns, it is of enormous economic and environmental values for the development of stranded gas. As a means for exploitation and transportation of stranded gas to market, a novel small-scale liquefaction process adopting single nitrogen expansion with carbon dioxide pre-cooling is put up with in this paper. Taking unit energy consumption as the target function, Aspen HYSYS is employed to simulate and optimize the process to achieve the liquefaction rate of 0.77 with unit energy consumption of 9.90 kW/kmol/h. Furthermore, the adaptability of this process under different pressure, temperature and compositions of feed gas is studied. Based on the optimization results, the exergy losses of main equipment in the process are evaluated and analyzed in details. With compact device, safety operation, simple capability, this liquefaction process proves to be suitable for the development of small gas reserves, satellite distribution fields of gas or coalbed methane fields. - Highlights: •A novel small-scale liquefaction process used in stranded gas is designed. •The adaptability of this process under different pressure, temperature and compositions of feed gas is studied. •The exergy analysis of main equipment in the process is analyzed.

  5. Use of microalgae to recycle nutrients in aqueous phase derived from hydrothermal liquefaction process.

    Science.gov (United States)

    Leng, Lijian; Li, Jun; Wen, Zhiyou; Zhou, Wenguang

    2018-05-01

    Hydrothermal liquefaction (HTL) of microalgae biomass generates an aqueous phase (AP) byproduct with limited energy value. Recycling the AP solution as a source of nutrients for microalgae cultivation provides an opportunity for a cost-effective production of HTL based biofuel and algal biomass feedstock for HTL, allowing a closed-loop biofuel production in microalgae HTL biofuel system. This paper aims to provide a comprehensive overview of characteristics of AP and its nutrients recycling for algae production. Inhibitory effects resulted from the toxic compounds in AP and alleviation strategies are discussed. Copyright © 2018 Elsevier Ltd. All rights reserved.

  6. Advanced Polymer Processing Facility

    Energy Technology Data Exchange (ETDEWEB)

    Muenchausen, Ross E. [Los Alamos National Laboratory

    2012-07-25

    Some conclusions of this presentation are: (1) Radiation-assisted nanotechnology applications will continue to grow; (2) The APPF will provide a unique focus for radiolytic processing of nanomaterials in support of DOE-DP, other DOE and advanced manufacturing initiatives; (3) {gamma}, X-ray, e-beam and ion beam processing will increasingly be applied for 'green' manufacturing of nanomaterials and nanocomposites; and (4) Biomedical science and engineering may ultimately be the biggest application area for radiation-assisted nanotechnology development.

  7. Advanced oxidation of water soluble organics (WSO) from near- and supercritical hydrothermal liquefaction (HTL) of biomass

    DEFF Research Database (Denmark)

    Arturi, Katarzyna Ratajczyk; Nielsen, Rudi Pankratz; Muff, Jens

    plant at Aalborg University, Denmark. The effectiveness of each process was evaluated concerning the organic content (TOC and COD) as well as the detailed composition of the samples (GCMS). Chosen process parameters were varied in the experiments (electric current - EO, concentration of H2O2 - FO...

  8. Advanced materials processing

    International Nuclear Information System (INIS)

    Giamei, A.F.

    1993-01-01

    Advanced materials will require improved processing methods due to high melting points, low toughness or ductility values, high reactivity with air or ceramics and typically complex crystal structures with significant anisotropy in flow and/or fracture stress. Materials for structural applications at elevated temperature in critical systems will require processing with a high degree of control. This requires an improved understanding of the relationship between process variables and microstructure to enable control systems to achieve consistently high quality. One avenue to the required level of understanding is computer simulation. Past attempts to do process modeling have been hampered by incomplete data regarding thermophysical or mechanical material behavior. Some of the required data can be calculated. Due to the advances in software and hardware, accuracy and costs are in the realm of acquiring experimental data. Such calculations can, for example, be done at an atomic level to compute lattice energy, fault energies, density of states and charge densities. These can lead to fundamental information about the competition between slip and fracture, anisotropy of bond strength (and therefore cleavage strength), cohesive strength, adhesive strength, elastic modulus, thermal expansion and possibly other quantities which are difficult (and therefore expensive to measure). Some of these quantities can be fed into a process model. It is probable that temperature dependencies can be derived numerically as well. Examples are given of the beginnings of such an approach for Ni 3 Al and MoSi 2 . Solidification problems are examples of the state-of-the-art process modeling and adequately demonstrate the need for extensive input data. Such processes can be monitored in terms of interfacial position vs. time, cooling rate and thermal gradient

  9. Reports on 1976 result of Sunshine Project. Investigation on development policy and position of various coal liquefaction processes in Japan; 1976 nendo Nippon ni okeru kakushu sekitan ekika process no kaihatsu hoshin to ichizuke ni kansuru chosa seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1977-03-01

    This report is the summary of the 'investigation results concerning development policy and position of various coal liquefaction processes in Japan'. The purpose of this investigative research is primarily to clarify the position of coal energy in the future energy supply, technologies of converting coal to clean fuel as the form of coal energy utilization most suitable for Japan, and the position of coal liquefaction in such converting technologies, and also to decide on the policy of R and D on coal liquefaction process in Japan at present. Accordingly, this paper investigates the status quo of various liquefaction processes including the coal liquefaction technologies for which R and D are conducted under the Sunshine Project; making analysis/assessment from such viewpoint as clean process as environmental safeguard and a precondition for coal energy utilization, technical problems concerning coal import and transportation, and suitability for the present energy consumption structure centering on oil; and further, examining the position of coal liquefaction in the general effective utilization of coal as organic carbonaceous resources in the distant future. (NEDO)

  10. Coal liquefaction and gas conversion: Proceedings. Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-31

    Volume I contains papers presented at the following sessions: AR-Coal Liquefaction; Gas to Liquids; and Direct Liquefaction. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  11. Advanced direct liquefaction concepts for PETC generic units. Quarterly technical progress report, April 1992--June 1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-08-01

    CAER/UK: Detail coal and starting solvents from Wilsonville were analyzed to develop the data necessary to conduct process studies in the CO Pretreatment and Catalyst Evaluation segment of this program. A comparison of the solvent separation analysis with the distillation/separation used at Wilsonville showed that the residual solvent components contained a large amount of residual pentane soluble products. The ashy resid contained 3% iron and 400 ppM molybdenum. Although the iron content in the distillate and deashed resid was much less, namely about 200 ppM., the molybdenum concentrations in these fractions were not significantly reduced over the concentration in the ashy resid, i.e., 200 ppM in each. The pretreatment of coal with CO/H{sub 2}O in the presence of NaOH and Na{sub 2}CO{sub 3} has been shown to give a product which is lower in oxygen content and higher in hydrogen content compared to the raw coal. The atomic H/C ratios of the H{sub 2}O-insolubles, THF insolubles and the PA+A fractions of the products-together with the hydrogen consumption data suggested that the raw coal has been substantially depolymerized and hydrogenated via the WGS reaction during the pretreatment process. The extensive amount of molecular reconstruction that has occurred in the solid product was evident from the ease of solubilization of the product into pyridine. The result of the pretreatment process is a product which is highly reactive under hydroliquefaction conditions at 400{degrees}C. Reaction rates seem to be much faster than the raw coal, especially at shorter reaction times, providing the opportunity for major reductions in plant vessel sizes, and preliminary data has led us to believe that better efficiency in hydrogen utilization is achieved.

  12. Advanced microwave processing concepts

    Energy Technology Data Exchange (ETDEWEB)

    Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L. [Oak Ridge National Laboratory, TN (United States)

    1995-05-01

    The purpose of this work is to explore the feasibility of several advanced microwave processing concepts to develop new energy-efficient materials and processes. The project includes two tasks: (1) commercialization of the variable-frequency microwave furnace; and (2) microwave curing of polymer composites. The variable frequency microwave furnace, whose initial conception and design was funded by the AIC Materials Program, will allow us, for the first time, to conduct microwave processing studies over a wide frequency range. This novel design uses a high-power traveling wave tube (TWT) originally developed for electronic warfare. By using this microwave source, one can not only select individual microwave frequencies for particular experiments, but also achieve uniform power densities over a large area by the superposition of many different frequencies. Microwave curing of thermoset resins will be studied because it hold the potential of in-situ curing of continuous-fiber composites for strong, lightweight components. Microwave heating can shorten curing times, provided issues of scaleup, uniformity, and thermal management can be adequately addressed.

  13. AN ADVANCED OXIDATION PROCESS : FENTON PROCESS

    Directory of Open Access Journals (Sweden)

    Engin GÜRTEKİN

    2008-03-01

    Full Text Available Biological wastewater treatment is not effective treatment method if raw wastewater contains toxic and refractory organics. Advanced oxidation processes are applied before or after biological treatment for the detoxification and reclamation of this kind of wastewaters. The advanced oxidation processes are based on the formation of powerful hydroxyl radicals. Among advanced oxidation processes Fenton process is one of the most promising methods. Because application of Fenton process is simple and cost effective and also reaction occurs in a short time period. Fenton process is applied for many different proposes. In this study, Fenton process was evaluated as an advanced oxidation process in wastewater treatment.

  14. A novel conceptual design of parallel nitrogen expansion liquefaction process for small-scale LNG (liquefied natural gas) plant in skid-mount packages

    International Nuclear Information System (INIS)

    He, Tianbiao; Ju, Yonglin

    2014-01-01

    The utilization of unconventional natural gas is still a great challenge for China due to its distribution locations and small reserves. Thus, liquefying the unconventional natural gas by using small-scale LNG plant in skid-mount packages is a good choice with great economic benefits. A novel conceptual design of parallel nitrogen expansion liquefaction process for small-scale plant in skid-mount packages has been proposed. It first designs a process configuration. Then, thermodynamic analysis of the process is conducted. Next, an optimization model with genetic algorithm method is developed to optimize the process. Finally, the flexibilities of the process are tested by two different feed gases. In conclusion, the proposed parallel nitrogen expansion liquefaction process can be used in small-scale LNG plant in skid-mount packages with high exergy efficiency and great economic benefits. - Highlights: • A novel design of parallel nitrogen expansion liquefaction process is proposed. • Genetic algorithm is applied to optimize the novel process. • The unit energy consumption of optimized process is 0.5163 kWh/Nm 3 . • The exergy efficiency of the optimized case is 0.3683. • The novel process has a good flexibility for different feed gas conditions

  15. Report on the achievements in research and development of a coal liquefaction technology in the Sunshine Project in fiscal 1981. Development of a solvolysis liquefaction plant (development of a 1 t/d experimental plant and research on solvolysis liquefaction process); Sekitan ekika gijutsu no kenkyu kaihatsu, solvolysis ekika plant no kaihatsu seika hokokusho. 1t/nichi jikken plant no kaihatsu (solvolysis ekika process no kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    This paper describes the achievements in the Sunshine Project in fiscal 1981 in development of a solvolysis liquefaction plant. The solvolysis process is characterized by performing the first stage reaction (liquefaction) in a short time by using hydrogenated heavy solvent produced spontaneously in the process. This short-time liquefaction reaction was carried out continuously by using a 1-t/d experimental plant, and a prospect was obtained on smooth operation and realization of the device. A test using a testing device allowing the temperature to rise within several minutes was performed on the effectiveness of a hydrogenated coal based heavy solvent (fractions of a hydrogenated heavy anthracene as a model) as a study on the first stage reaction. Partially hydrogenated materials of polycyclic condensed aromatics in the heavy solvent is largely involved in the initial reaction. In the solid-liquid separation, solids and heavy fractions are selected and removed from the first stage reaction products, and the light fraction is supplied into the second stage reaction (hydrogenation). The solvent deliming process was tested by using a batch type solid-liquid separator, whose effectiveness was verified. Studies were performed by using Australian sub-bituminous coal on operation of a continuous operation device consisted of systems for the first stage reaction (liquefaction), solid-liquid separation, second stage reaction (hydrogenation), and solvent circulation. (NEDO)

  16. Report on the achievements in research and development of a coal liquefaction technology in the Sunshine Project in fiscal 1981. Development of a solvent extraction and liquefaction plant (development of a 1-t/d experimental plant and research on the solvent extraction and liquefaction process); 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu, yozai chushutsu ekika plant no kaihatsu seika hokokusho. 1t/d jikken plant no kaihatsu (yozai chushutsu ekika process no kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    Among the items of the solvent extraction and liquefaction plant technologies in the Sunshine Project in fiscal 1981, this paper describes the achievements in developing a 1-t/d experimental plant and the solvent extraction and liquefaction process. Basic facilities were completed by giving expansion constructions on the extraction reaction column, gas-liquid separation column, and hydrogenation reaction column. The operation was performed with the primary object placed on verifying the effect of measures on problems that have been extracted, and checking the solvent balance. The conversion rate at an extraction reaction temperature of 450 degrees C was 83%, agreeing with the result of the fundamental study. The solvent has turned light as a result of 153-hour continuous operation, but circulating use was possible. Progress of the reaction has become easily controllable in the hydrogenation system. Fundamental discussions were given on engineering aspects, which require further accumulation of data. In the research of the solvent extraction and liquefaction process, fiscal 1981 has performed discussions on liquefaction catalysts, and on the effect of the hydrogen donating solvents. The discussions were for the fundamental research to establish adequate conditions for the 1-t/d experimental plant by operating a small continuous operation facility to its full extent, and by using a batch type reaction device. Screening was also carried out on catalysts. (NEDO)

  17. Development of liquefaction process of coal and biomass in supercritical water; Chorinkaisui wo mochiita sekitan biomass doji ekika process no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Nonaka, H.; Matsumura, Y.; Tsutsumi, A.; Yoshida, K. [The University of Tokyo, Tokyo (Japan). Faculty of Engineering; Masuno, Y.; Inaba, A. [National Institute for Resources and Environment, Tsukuba (Japan)

    1996-10-28

    Liquefaction of coal and biomass in supercritical water has been investigated, in which strong solubilization force of supercritical water against hydrocarbons is utilized. Free radicals are formed through the cleavage of covalent bonds in coal under the heating condition at around 400{degree}C during coal liquefaction. It is important to stabilize these unstable intermediate products by hydrogen transfer. On the other hand, hydrogen is not required for the liquefaction of biomass having higher H/C atomic ratio and oxygen content than those of coal. Co-liquefaction of coal and biomass was conducted using supercritical water, in which excess hydrogen from the liquefaction of biomass would be transferred to coal, resulting in the effective liquefaction of coal. Mixture of coal and cellulose was liquefied in supercritical water at 390{degree}C under the pressure of 25 MPa using a semi-continuous reactor, and the results were compared with those from the separate liquefaction of them. The co-liquefaction of coal and cellulose did not show any difference in the residue yield from the separate liquefaction of these, but led to the increased production of compounds with lower molecular weight. The liquefaction was completed in 15 minutes. 5 refs., 3 figs., 3 tabs.

  18. Experimental study on CO2 frosting and clogging in a brazed plate heat exchanger for natural gas liquefaction process

    Science.gov (United States)

    Wu, Jitan; He, Tianbiao; Ju, Yonglin

    2018-04-01

    The plate-fin heat exchanger (PFHE), which has been widely used in natural gas liquefaction (LNG) industry at present, has some disadvantages such as being sensitive to the impurities in the feed gas, such as water, CO2 and H2S. Compared with the PFHE, the brazed plate heat exchanger (BPHE), which has been applied in some boil off gas (BOG) recycling LNG plants of small to middle size, has simpler inherent structure and higher impurity tolerance. In this study the BPHE is suggested to replace the PFHE to simplify or even omit the massive CO2 purification equipment for the LNG process. A set of experimental apparatus is designed and constructed to investigate the influence of the CO2 concentration of the natural gas on solid precipitation inside a typical BPHE meanly by considering the flow resistance throughout the LNG process. The results show that the maximum allowable CO2 concentration of the natural gas liquefied in the BPHE is two orders of magnitude higher than that in the PFHE under the same condition. In addition, the solid-liquid separation for the CO2 impurity is studied and the reasonable separating temperature is obtained. The solid CO2 should be separated below 135 K under the pressure of 3 MPa.

  19. The direct liquefaction proof of concept program

    Energy Technology Data Exchange (ETDEWEB)

    Comolli, A.G.; Lee, L.K.; Pradhan, V.R.; Stalzer, R.H. [New York & Puritan Avenues, Lawrenceville, NJ (United States)

    1995-12-31

    The goal of the Proof of Concept (POC) Program is to develop Direct Coal Liquefaction and associated transitional technologies towards commercial readiness for economically producing premium liquid fuels from coal in an environmentally acceptable manner. The program focuses on developing the two-stage liquefaction (TSL) process by utilizing geographically strategic feedstocks, commercially feasible catalysts, new prototype equipment, and testing co-processing or alternate feedstocks and improved process configurations. Other high priority objectives include dispersed catalyst studies, demonstrating low rank coal liquefaction without solids deposition, improving distillate yields on a unit reactor volume basis, demonstrating ebullated bed operations while obtaining scale-up data, demonstrating optimum catalyst consumption using new concepts (e.g. regeneration, cascading), producing premium products through on-line hydrotreating, demonstrating improved hydrogen utilization for low rank coals using novel heteroatom removal methods, defining and demonstrating two-stage product properties for upgrading; demonstrating efficient and economic solid separation methods, examining the merits of integrated coal cleaning, demonstrating co-processing, studying interactions between the preheater and first and second-stage reactors, improving process operability by testing and incorporating advanced equipment and instrumentation, and demonstrating operation with alternate coal feedstocks. During the past two years major PDU Proof of Concept runs were completed. POC-1 with Illinois No. 6 coal and POC-2 with Black Thunder sub-bituminous coal. Results from these operations are continuing under review and the products are being further refined and upgraded. This paper will update the results from these operations and discuss future plans for the POC program.

  20. Fiscal 1997 achievement report. Coal liquefaction technology development - Bituminous coal liquefaction technology development - Study for supporting pilot plant - Study using 1t/d PSU (Study of operation using PSU); 1997 nendo seika hokokusho. Sekitan ekika gijutsu kaihatsu - Rekiseitan ekika gijutsu no kaihatsu - Pilot plant no shien kenkyu - 1t/d process support unit (PSU) ni yoru kenkyu (PSU ni yoru unten kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The operation of a 1t/d PSU (process support unit) was studied for the NEDOL coal liquefaction process. In the modification of facilities, equipment and devices were procured for the product oil reforming facilities and their installation was partly accomplished. In the coal injection operation, a 60-day slurry operation was conducted, using coal types of the upper limit and lower limit qualities, for expanding the scope of coal types applicable to the NEDOL process and for exploring optimum conditions, and another operation of 37 days was conducted using Chinese coal and Chinese-prepared liquefaction catalysts, and the two operations were studied for difference in yields and in operationality. Characteristics of the liquefaction reactors were investigated and basic studies were made relative to the physical property of the yielded coal oil. In the operation for maintenance, the 1st liquefaction reactor was singly operated for an 8-day slurry operation, which was to check the progress of liquefaction in a 1-reactor setup. Concerning the reforming of the product oil, the hydrogenation reactors were checked for their response to temperature control. Moreover, hydrogenation solvents were produced for the PSU and for China. (NEDO)

  1. Fiscal 1996 achievement report. Coal liquefaction technology development - Bituminous coal liquefaction technology development - Study for supporting pilot plant - Study using 1t/d PSU (Study of operation using PSU); 1996 nendo seika hokokusho. Sekitan ekika gijutsu kaihatsu - Rekiseitan ekika gijutsu no kaihatsu - Pilot plant no shien kenkyu - 1t/d process support unit (PSU) ni yoru kenkyu (PSU ni yoru unten kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The operation of a 1t/d PSU (process support unit) was studied for the NEDOL coal liquefaction process. In the modification of facilities, detailed designs were prepared for product oil reforming facilities and some equipment and devices were procured. In addition, the 3rd liquefaction reactor cone section and the neutron attenuation-aided measuring device were refurbished. In the injection of coal, a 62-day and 23-day slurry injection operations were accomplished using Tanito Harum coal, when the impact imposed on the yield of the product, etc., by the change of liquefaction catalysts and by gas phase hydrogen concentration enriching conditions was investigated, and the unit was examined for operationality. During a 42-day operation for maintenance, the unit was operated using only the slurry heater for the investigation of the initial reaction in liquefaction, and studies were conducted about the heater exit temperature, G/L (gas-liquid ratio), and the effect to ensue from the use of a different solvent. In the effort to develop and evaluate new materials, implantation tests were conducted for metallic materials and the 3rd liquefaction reactor was subjected to a non-destructive inspection. Wastewater from the process was examined for quality, and environment-related measurements were performed for the atmosphere. (NEDO)

  2. Advances in Solidification Processing

    Directory of Open Access Journals (Sweden)

    Hugo F. Lopez

    2015-08-01

    Full Text Available Melt solidification is the shortest and most viable route to obtain components, starting from the design to the finished products. Hence, a sound knowledge of the solidification of metallic materials is essential for the development of advanced structural metallic components that drive modern technological societies. As a result, there have been innumerable efforts and full conferences dedicated to this important subject [1–6]. In addition, there are various scientific journals fully devoted to investigating the various aspects which give rise to various solidification microstructures [7–9]. [...

  3. FY 1980 Report on results of Sunshine Project. Development of coal liquefaction techniques (Development of 1 T/D test plant, and researches on the solvent-extraction type liquefaction process); 1980 nendo sekitan ekika gijutsu no kaihatsu, yozai chushutsu ekika plant no kaihatsu seika hokokusho. 1t/nichi jikken plant no kaihatsu, yozai chushutsu ekika process no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-03-01

    This program is aimed at establishing the techniques for solvent-extraction type coal liquefaction plant by constructing and operating a 1 T/D test plant to obtain the technical data for the efficient plant. The test plant is operated to confirm the effects of temperature and coal slurry concentration on liquefaction conversion by the solvent-extraction for a short time in the furnace for the extraction unit. The extraction type coal liquefaction tests can be conducted for a reaction time of around 1 hour by the test plant. The recycled solvent purification unit is installed, to regenerate the hydrogen donor solvent. For researches on the solvent-extraction type coal liquefaction process, the continuous extraction is conducted, to investigate the effects of extraction reaction rate at relatively low pressure. The optimum hydrogenation conditions are studied for the test plant. It is confirmed that a Mo-based catalyst is suitable for the hydrogenation. The batch type reaction system is operated to investigate the liquid yield of Wandoan coal, and recycled solvent balances and compositions. (NEDO)

  4. Process Design and Economics for the Conversion of Algal Biomass to Hydrocarbons: Whole Algae Hydrothermal Liquefaction and Upgrading

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Susanne B. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Zhu, Yunhua [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Anderson, Daniel B. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hallen, Richard T. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Elliott, Douglas C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Schmidt, Andrew J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Albrecht, Karl O. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hart, Todd R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Butcher, Mark G. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Drennan, Corinne [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Snowden-Swan, Lesley J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Davis, Ryan [National Renewable Energy Lab. (NREL), Golden, CO (United States); Kinchin, Christopher [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2014-03-20

    This report provides a preliminary analysis of the costs associated with converting whole wet algal biomass into primarily diesel fuel. Hydrothermal liquefaction converts the whole algae into an oil that is then hydrotreated and distilled. The secondary aqueous product containing significant organic material is converted to a medium btu gas via catalytic hydrothermal gasification.

  5. Beam processing of advanced materials

    International Nuclear Information System (INIS)

    Singh, J.; Copley, S.M.

    1993-01-01

    International Conference on Beam Processing of Advanced Materials was held at the Fall TMS/ASM Materials Week at Chicago, Illinois, November 2--5, 1992. The symposium was devoted to the recent advances in processing of materials by an energy source such as laser, electron, ion beams, etc. The symposium served as a forum on the science of beam-induced materials processing and implications of this science to practical implementation. An increased emphasis on obtaining an understanding of the fundamental mechanisms of beam-induced surface processes was a major trend observed at this years symposium. This has resulted in the increased use of advanced diagnostic techniques and modeling studies to determine the rate controlling steps in these processes. Individual papers have been processed separately for inclusion in the appropriate data bases

  6. Direct catalytic hydrothermal liquefaction of spirulina to biofuels with hydrogen

    Science.gov (United States)

    Zeng, Qin; Liao, Hansheng; Zhou, Shiqin; Li, Qiuping; Wang, Lu; Yu, Zhihao; Jing, Li

    2018-01-01

    We report herein on acquiring biofuels from direct catalytic hydrothermal liquefaction of spirulina. The component of bio-oil from direct catalytic hydrothermal liquefaction was similar to that from two independent processes (including liquefaction and upgrading of biocrude). However, one step process has higher carbon recovery, due to the less loss of carbons. It was demonstrated that the yield and HHV of bio-oil from direct catalytic algae with hydrothermal condition is higher than that from two independent processes.

  7. Two-stage coal liquefaction without gas-phase hydrogen

    Science.gov (United States)

    Stephens, H.P.

    1986-06-05

    A process is provided for the production of a hydrogen-donor solvent useful in the liquefaction of coal, wherein the water-gas shift reaction is used to produce hydrogen while simultaneously hydrogenating a donor solvent. A process for the liquefaction of coal using said solvent is also provided. The process enables avoiding the use of a separate water-gas shift reactor as well as high pressure equipment for liquefaction. 3 tabs.

  8. A characterization and evaluation of coal liquefaction process streams. Quarterly report, April 1--June 30, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Brandes, S.D.; Robbins, G.A.; Winschel, R.A.

    1997-12-31

    This is the Technical Progress Report for the twelfth quarter of activities. Described in this report are the following activities: (1) Thirty-nine samples from four run conditions of HTI Run PB-07 were received. Appropriate samples were characterized by proton NMR spectroscopy, Fourier transform infrared spectroscopy, vacuum distillation, and solvent quality tests. (2) The University of Delaware completed their subcontract this quarter. A meeting was held on April 30, 1997 at the University to close out the subcontract. (3) Twelve sets of samples were chosen from the CONSOL sample bank for the study of the insoluble and presumed unreactive material from process stream samples. Each set consists of the whole process stream and the 454 C{sup +} (850 F{sup +}) distillation resid derived from that process stream. Processing data for all samples were compiled. The samples represent four Wilsonville pilot plant runs and two HTI runs.

  9. Demineralization of Sargassum spp. Macroalgae Biomass: Selective Hydrothermal Liquefaction Process for Bio-Oil Production

    OpenAIRE

    Díaz-Vázquez, Liz M.; Rojas-Pérez, Arnulfo; Fuentes-Caraballo, Mariela; Robles, Isis V.; Jena, Umakanta; Das, K. C.

    2015-01-01

    Algae biomasses are considered a viable option for the production of biofuel because of their high yields of oil produced per dry weight. Brown macroalgae Sargassum spp. are one of the most abundant species of algae in the shores of Puerto Rico. Its availability in large quantity presents a great opportunity for use as a source of renewable energy. However, high ash content of macroalgae affects the conversion processes and the quality of resulting fuel products. This research studied the eff...

  10. The hydrothermal upgrading process (HTU) for biomass liquefaction; Het hydrothermal upgrading proces (HTU) voor biomassa liquefactie

    Energy Technology Data Exchange (ETDEWEB)

    Naber, J.E. (ed.) [Biofuel, Heemskerk (Netherlands)

    2001-07-01

    The HTU process has been investigated in 1981-1988 at the Shell Laboratory in Amsterdam, as a reaction to the two oil crises of 1973 and 1980. Due to the commercial circumstances in the late eighties, the research on the promising HTU technology was discontinued with only a few hundred hours of continuous bench-scale operation. While most of the critical elements of the technology were demonstrated in principle, many important data were lacking for a reliable design of the first (semi-) commercial applications, as well as a good understanding of the fundamental backgrounds, the product properties and possibilities/aspects of scaling up. Therefore the purpose and envisaged result of this project is a validated process on pilot plant scale, for a reliable design of the first commercial demonstration(s). Next to fundamental investigations of conversion mechanisms, process dynamics, thermodynamics of the multi-phase system and the water treating, the installation and continuous operation of an integrated pilot plant plays a central role in the project. The latter as well as the pressurizing of the biomass feed were identified as Go/No Go elements. With parallel research on e.g. reactor engineering and high pressure pumps, the HTU process can be scaled-up with confidence to throughputs of 10,000+ tons biomass/year. The pilot plant will be able to produce sufficient product to enable thorough research on various product applications and possibly the further upgrading by hydrodeoxygenation to 'green' transport fuels and/or premium ethylene cracker feedstock. The principle of this upgrading was also established in the R and D at the Shell Laboratory. [Dutch] Het HTU proces is in de jaren 1981-1988 onderzocht op het Shell Laboratorium in Amsterdam, als reactie op de twee olie crises van 1973 en 1980. Door de commerciele omstandigheden in het latere deel van de tachtiger jaren is de tot dan toe veelbelovende ontwikkeling van de HTU technologie vroegtijdig

  11. Methods of natural gas liquefaction and natural gas liquefaction plants utilizing multiple and varying gas streams

    Science.gov (United States)

    Wilding, Bruce M; Turner, Terry D

    2014-12-02

    A method of natural gas liquefaction may include cooling a gaseous NG process stream to form a liquid NG process stream. The method may further include directing the first tail gas stream out of a plant at a first pressure and directing a second tail gas stream out of the plant at a second pressure. An additional method of natural gas liquefaction may include separating CO.sub.2 from a liquid NG process stream and processing the CO.sub.2 to provide a CO.sub.2 product stream. Another method of natural gas liquefaction may include combining a marginal gaseous NG process stream with a secondary substantially pure NG stream to provide an improved gaseous NG process stream. Additionally, a NG liquefaction plant may include a first tail gas outlet, and at least a second tail gas outlet, the at least a second tail gas outlet separate from the first tail gas outlet.

  12. Advances in natural language processing.

    Science.gov (United States)

    Hirschberg, Julia; Manning, Christopher D

    2015-07-17

    Natural language processing employs computational techniques for the purpose of learning, understanding, and producing human language content. Early computational approaches to language research focused on automating the analysis of the linguistic structure of language and developing basic technologies such as machine translation, speech recognition, and speech synthesis. Today's researchers refine and make use of such tools in real-world applications, creating spoken dialogue systems and speech-to-speech translation engines, mining social media for information about health or finance, and identifying sentiment and emotion toward products and services. We describe successes and challenges in this rapidly advancing area. Copyright © 2015, American Association for the Advancement of Science.

  13. Liquefaction technology assessment. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1979-05-01

    A survey of coal liquefaction technology and analysis of projected relative performance of high potential candidates has been completed and the results are reported here. The key objectives of the study included preparation of a broad survey of the status of liquefaction processes under development, selection of a limited number of high potential process candidates for further study, and an analysis of the relative commercial potential of these candidates. Procedures which contributed to the achievement of the above key goals included definition of the characteristics and development status of known major liquefaction process candidates, development of standardized procedures for assessing technical, environmental, economic and product characteristics for the separate candidates, and development of procedures for selecting and comparing high potential processes. The comparisons were made for three production areas and four marketing areas of the US. In view of the broad scope of the objectives the survey was a limited effort. It used the experience gained during preparation of seven comprehensive conceptual designs/economic evaluations plus comprehensive reviews of the designs, construction and operation of several pilot plants. Results and conclusions must be viewed in the perspective of the information available, how this information was treated, and the full context of the economic comparison results. Comparative economics are presented as ratios; they are not intended to be predictors of absolute values. Because the true cost of constructing and operating large coal conversion facilities will be known only after commercialization, relative values are considered more appropriate. (LTN)

  14. Experimental study on the liquefaction of cellulose in supercritical ethanol

    Science.gov (United States)

    Peng, Jinxing; Liu, Xinyuan; Bao, Zhenbo

    2018-03-01

    Cellulose is the major composition of solid waste for producing biofuel; cellulose liquefaction is helpful for realizing biomass supercritical liquefaction process. This paper is taking supercritical ethanol as the medium, liquefied cellulose with the intermittence installation of high press cauldron. Experiments have studied technical condition and the technology parameter of cellulose liquefaction in supercritical ethanol, and the pyrolysis mechanism was analysed based on the pyrolysis product. Results show that cellulose can be liquefied, can get good effect through appropriate technology condition. Under not catalyst, highest liquefaction rate of cellulose can reach 73.5%. The composition of the pyrolysis product was determined by GC-MS.

  15. Production of ethanol from a mixture of waste paper and kitchen waste via a process of successive liquefaction, presaccharification, and simultaneous saccharification and fermentation.

    Science.gov (United States)

    Nishimura, Hiroto; Tan, Li; Kira, Noriko; Tomiyama, Shigeo; Yamada, Kazuo; Sun, Zhao-Yong; Tang, Yue-Qin; Morimura, Shigeru; Kida, Kenji

    2017-09-01

    Efficient ethanol production from waste paper requires the addition of expensive nutrients. To reduce the production cost of ethanol from waste paper, a study on how to produce ethanol efficiently by adding kitchen waste (potentially as a carbon source, nutrient source, and acidity regulator) to waste paper was performed and a process of successive liquefaction, presaccharification, and simultaneous saccharification and fermentation (L+PSSF) was developed. The individual saccharification performances of waste paper and kitchen waste were not influenced by their mixture. Liquefaction of kitchen waste at 90°C prior to presaccharification and simultaneous saccharification and fermentation (PSSF) was essential for efficient ethanol fermentation. Ethanol at concentrations of 46.6 or 43.6g/l was obtained at the laboratory scale after fermentation for 96h, even without pH adjustment and/or the addition of extra nutrients. Similarly, ethanol at a concentration of 45.5g/l was obtained at the pilot scale after fermentation for 48h. The ethanol concentration of L+PSSF of the mixture of waste paper and kitchen waste was comparable to that of PSSF of waste paper with added nutrients (yeast extract and peptone) and pH adjustment using H 2 SO 4 , indicating that kitchen waste is not only a carbon source but also an excellent nutrient source and acidity regulator for fermentation of the mixture of waste paper and kitchen waste. Copyright © 2017. Published by Elsevier Ltd.

  16. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., College Park, PA (United States); Gutterman, C.

    1995-04-01

    Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

  17. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons via Indirect Liquefaction. Thermochemical Research Pathway to High-Octane Gasoline Blendstock Through Methanol/Dimethyl Ether Intermediates

    Energy Technology Data Exchange (ETDEWEB)

    Tan, E. C. D.; Talmadge, M.; Dutta, A.; Hensley, J.; Schaidle, J.; Biddy, M.; Humbird, D.; Snowden-Swan, L. J.; Ross, J.; Sexton, D.; Yap, R.; Lukas, J.

    2015-03-01

    This report was developed as part of the U.S. Department of Energy’s Bioenergy Technologies Office’s (BETO’s) efforts to enable the development of technologies for the production of infrastructure-compatible, cost-competitive liquid hydrocarbon fuels from lignocellulosic biomass feedstocks. The research funded by BETO is designed to advance the state of technology of biomass feedstock supply and logistics, conversion, and overall system sustainability. It is expected that these research improvements will be made within the 2022 timeframe. As part of their involvement in this research and development effort, the National Renewable Energy Laboratory and the Pacific Northwest National Laboratory investigate the economics of conversion pathways through the development of conceptual biorefinery process models and techno-economic analysis models. This report describes in detail one potential conversion process for the production of high-octane gasoline blendstock via indirect liquefaction of biomass. The processing steps of this pathway include the conversion of biomass to synthesis gas or syngas via indirect gasification, gas cleanup, catalytic conversion of syngas to methanol intermediate, methanol dehydration to dimethyl ether (DME), and catalytic conversion of DME to high-octane, gasoline-range hydrocarbon blendstock product. The conversion process configuration leverages technologies previously advanced by research funded by BETO and demonstrated in 2012 with the production of mixed alcohols from biomass. Biomass-derived syngas cleanup via reforming of tars and other hydrocarbons is one of the key technology advancements realized as part of this prior research and 2012 demonstrations. The process described in this report evaluates a new technology area for the downstream utilization of clean biomass-derived syngas for the production of high-octane hydrocarbon products through methanol and DME intermediates. In this process, methanol undergoes dehydration to

  18. Factors influencing the organic matter extraction from the coal by using the process of liquefaction in static system; Fatores que influenciam a extracao da materia organica do carvao mineral atraves do processo de liequefacao em sistema estatico

    Energy Technology Data Exchange (ETDEWEB)

    Assis, Livia Mari; Lancas, Fernando Mauro

    1996-07-01

    This work describes the liquefaction process for extraction of the organic matter from coal, presently researched in Brazil, particularly with supercritical fluids. The extraction can be a future economically viable and environmentally correct alternative for supplying the emerging necessities of fuels, pharmaceuticals and chemicals sources.

  19. Advanced diffusion processes and phenomena

    CERN Document Server

    Öchsner, Andreas; Belova, Irina

    2014-01-01

    This topical volume on Advanced Diffusion Processes and Phenomena addresses diffusion in a wider sense of not only mass diffusion but also heat diffusion in fluids and solids. Both diffusion phenomena play an important role in the characterization of engineering materials and corresponding structures. Understanding these different transport phenomena at many levels, from atomistic to macro, has therefore long attracted the attention of many researchers in materials science and engineering and related disciplines. The present topical volume captures a representative cross-section of some of the

  20. Advanced Information Processing System (AIPS)

    Science.gov (United States)

    Pitts, Felix L.

    1993-01-01

    Advanced Information Processing System (AIPS) is a computer systems philosophy, a set of validated hardware building blocks, and a set of validated services as embodied in system software. The goal of AIPS is to provide the knowledgebase which will allow achievement of validated fault-tolerant distributed computer system architectures, suitable for a broad range of applications, having failure probability requirements of 10E-9 at 10 hours. A background and description is given followed by program accomplishments, the current focus, applications, technology transfer, FY92 accomplishments, and funding.

  1. FY 1994 report on the Coal Liquefaction Committee; 1994 nendo sekitan ekika iinkai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The paper reported the FY 1994 activities of the Coal Liquefaction Committee. The Coal Liquefaction Committee in this fiscal year was held on November 29, 1994 (1st) and March 22, 1995 (2nd), and report was made on the bituminous coal liquefaction study and state of the R and D of liquefaction base technology. Report was also made on the state of construction of bituminous coal liquefaction PP, outline of the results of the PSU operation, outline of the 11th Japan-U.S. JTM, etc. In the liquefaction base study, report/discussion were made about the improvement/rationalization of liquefaction process, study of innovative technology of coal liquefaction, study of coal liquefaction conditions, study for higher liquefaction element technology, project on the internationalization of coal liquefaction technology, etc. As to the relation of the entrained bed coal gasification power plant, report/discussion were made about survey/study on the processing of coal for coal gasification use (survey of coal kind selection, development of information processing system for coal conversion technology). Besides, as a topic, report was made on the economical evaluation/calculation of a commercial plant for brown coal liquefaction. (NEDO)

  2. Fiscal 1998 achievement report. Coal liquefaction technology development - Bituminous coal liquefaction technology development - Study for supporting pilot plant - Study using 1t/d PSU (Study of operation using PSU); 1998 nendo seika hokokusho. Sekitan ekika gijutsu kaihatsu - Rekiseitan ekika gijutsu no kaihatsu - Pilot plant no shien kenkyu - 1t/d process support unit (PSU) ni yoru kenkyu (PSU ni yoru unten kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-06-01

    The operation of a 1t/d PSU (process support unit) was studied for the NEDOL coal liquefaction process. For the modification of facilities, product oil reforming facilities were installed. In the coal injection operation, a 59-day slurry operation was carried out using Tanito Harum coal, which was for the evaluation of the reforming effect under the product reforming conditions, operationality, and liquefaction characteristics. A 37-day slurry operation was also performed using Chinese coal, which was intended to pursue improved cost performance and to collect the light oil fraction in the flow of reforming operation. In the operation for maintenance, investigations were conducted into conditions for hydrogenation in a 1-through operation involving the solvent hydrogenation process and the normal pressure distillation facilities and into the effect of pre-hydrogenation solvent properties, which aimed at grasping the effect of product oil reforming measures and their influence on operationality. In the survey of environments, the properties of wastewater from the liquefaction process using Tanito Harum coal were studied and toxicity evaluation tests were conducted for activated sludge. (NEDO)

  3. Method of start-up operation of a liquefaction and distillation apparatus for processing waste gases containing radioactive rare gases

    International Nuclear Information System (INIS)

    Ota, Masakazu; Tani, Akira; Hashimoto, Hiroshi; An, Bunzai; Kanazawa, Toshio.

    1975-01-01

    Object: To enable reduction of cooling time, simplification of maintenance, and release of cooling gas outside system. Structure: In starting of the liquefaction and distillation apparatus, liquid nitrogen is introduced into the tower bottom of a rectification tower from a liquid nitrogen tank through a liquid nitrogen supply line to vaporize the liquid nitrogen with help of heat entered from outside and a heater. The vaporized nitrogen gas moves up while cooling the interior of the rectification tower and is guided by a vacuum pump from the top of tower toward the purifying gas line and low temperature heat exchanger and disharging into atmosphere. When the interior of the apparatus is sufficiently cooled in a manner as described above, the liquid nitrogen supply line is closed, the liquid nitrogen is fed to a condenser, and the waste gases containing the radioactive rare gases from the raw exhaust supply line are introduced into the rectification tower for entry of normal operation. (Kamimura, M.)

  4. Coal liquefaction with preasphaltene recycle

    Science.gov (United States)

    Weimer, Robert F.; Miller, Robert N.

    1986-01-01

    A coal liquefaction system is disclosed with a novel preasphaltene recycle from a supercritical extraction unit to the slurry mix tank wherein the recycle stream contains at least 90% preasphaltenes (benzene insoluble, pyridine soluble organics) with other residual materials such as unconverted coal and ash. This subject process results in the production of asphaltene materials which can be subjected to hydrotreating to acquire a substitute for No. 6 fuel oil. The preasphaltene-predominant recycle reduces the hydrogen consumption for a process where asphaltene material is being sought.

  5. Advanced direct liquefaction concepts for PETC generic units. [Mainly, the effect of preteatment of coal with carbon monoxide and steam

    Energy Technology Data Exchange (ETDEWEB)

    1992-08-01

    CAER/UK: Detail coal and starting solvents from Wilsonville were analyzed to develop the data necessary to conduct process studies in the CO Pretreatment and Catalyst Evaluation segment of this program. A comparison of the solvent separation analysis with the distillation/separation used at Wilsonville showed that the residual solvent components contained a large amount of residual pentane soluble products. The ashy resid contained 3% iron and 400 ppM molybdenum. Although the iron content in the distillate and deashed resid was much less, namely about 200 ppM., the molybdenum concentrations in these fractions were not significantly reduced over the concentration in the ashy resid, i.e., 200 ppM in each. The pretreatment of coal with CO/H{sub 2}O in the presence of NaOH and Na{sub 2}CO{sub 3} has been shown to give a product which is lower in oxygen content and higher in hydrogen content compared to the raw coal. The atomic H/C ratios of the H{sub 2}O-insolubles, THF insolubles and the PA+A fractions of the products-together with the hydrogen consumption data suggested that the raw coal has been substantially depolymerized and hydrogenated via the WGS reaction during the pretreatment process. The extensive amount of molecular reconstruction that has occurred in the solid product was evident from the ease of solubilization of the product into pyridine. The result of the pretreatment process is a product which is highly reactive under hydroliquefaction conditions at 400{degrees}C. Reaction rates seem to be much faster than the raw coal, especially at shorter reaction times, providing the opportunity for major reductions in plant vessel sizes, and preliminary data has led us to believe that better efficiency in hydrogen utilization is achieved.

  6. Electrochromic Windows: Advanced Processing Technology

    Energy Technology Data Exchange (ETDEWEB)

    SAGE Electrochromics, Inc

    2006-12-13

    This project addresses the development of advanced fabrication capabilities for energy saving electrochromic (EC) windows. SAGE EC windows consist of an inorganic stack of thin films deposited onto a glass substrate. The window tint can be reversibly changed by the application of a low power dc voltage. This property can be used to modulate the amount of light and heat entering buildings (or vehicles) through the glazings. By judicious management of this so-called solar heat gain, it is possible to derive significant energy savings due to reductions in heating lighting, and air conditioning (HVAC). Several areas of SAGE’s production were targeted during this project to allow significant improvements to processing throughput, yield and overall quality of the processing, in an effort to reduce the cost and thereby improve the market penetration. First, the overall thin film process was optimized to allow a more robust set of operating points to be used, thereby maximizing the yield due to the thin film deposition themselves. Other significant efforts aimed at improving yield were relating to implementing new procedures and processes for the manufacturing process, to improve the quality of the substrate preparation, and the quality of the IGU fabrication. Furthermore, methods for reworking defective devices were developed, to enable devices which would otherwise be scrapped to be made into useful product. This involved the in-house development of some customized equipment. Finally, the improvements made during this project were validated to ensure that they did not impact the exceptional durability of the SageGlass® products. Given conservative estimates for cost and market penetration, energy savings due to EC windows in residences in the US are calculated to be of the order 0.026 quad (0.026×1015BTU/yr) by the year 2017.

  7. Studies of initial stage in coal liquefaction. Effect of prethermal treatment condition with process solvent to increase oil yields; Ekika hanno no shoki katei ni kansuru kenkyu. Sekitan no maeshori joken to yozai koka

    Energy Technology Data Exchange (ETDEWEB)

    Shindo, T.; Komatsu, N.; Kishimoto, M.; Okui, T.; Kaneko, T.; Shimasaki, K. [Nippon Brown Coal Liquefaction Co. ltd., Tokyo (Japan)

    1996-10-28

    Process solvent was hydrogenated in the brown coal liquefaction, to investigate the influence of it on the prethermal treatment and liquefaction. Consequently, it was found that the n-hexane soluble (HS) yield was improved. In this study, capacity of hydrogen transfer from solvent during prethermal treatment and effects of catalyst were investigated. Since prethermal treatment in oil was effective for improving the oil yield in the presence of hydrogen/catalyst or high hydrogen-donor solvent, influence of hydrogen-donor performance of solvent or addition of catalyst on the hydrogenation behavior of coal and the characteristics of products during prethermal treatment were investigated in relation to successive liquefaction results. As a result, it was found that the increase of HS yield was due to the acceleration of conversion of THF-insoluble using high hydrogen-donor solvent and/or by adding catalyst. It was also found that the use of high hydrogen-donor solvent and highly active catalyst at the stage of prethermal treatment before the successive liquefaction was effective for improving the HS yield, i.e., liquefied oil yield. 2 refs., 5 figs., 1 tab.

  8. Residual liquefaction of seabed under standing waves

    DEFF Research Database (Denmark)

    Kirca, V.S. Ozgur; Sumer, B. Mutlu; Fredsøe, Jørgen

    2013-01-01

    This paper presents the results of an experimental study of the seabed liquefaction beneath standing waves. Silt (with d50 =0.070mm) was used in the experiments. Two kinds of measurements were carried out: pore water pressure measurements and water surface elevation measurements. These measurements...... were synchronized with video recording of the liquefaction process from the side. The ranges of the various quantities in the experiments were wave height H= 5.9-12.0 cm, wave period T= 1.09s, and water depth h=30 cm. The experiments show that the seabed liquefaction under standing waves, although...... qualitatively similar, show features different from that caused by progressive waves. The pore water pressure builds up (or accumulated) in the areas around the node and subsequently spreads out toward the antinodes. The experimental results imply that this transport is caused by a diffusion mechanism...

  9. Coal liquefaction becomes viable

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-11-15

    In 2003 the May/June issue of CoalTrans International speculated that coal liquefaction would become viable due to falling coal prices. This has not proved the case but the sustained high oil price is sparking new interest. A survey by Energy Intelligence and Marketing Research during November 2005 revealed a growth in the number of projects under development or at the feasibility stage. The article reports projects in China, the USA, Australia, New Zealand, the Philippines and India. China is commissioning the first wave of large liquefaction plants. The key question is whether other countries, particularly the USA, will follow.

  10. Report on the achievements in the Sunshine Project in fiscal 1987. Collection of data from coal liquefaction processes, and development of a disposal system; 1987 nendo sekitan ekika process nado no data no shushu, shori system nado no kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1988-03-01

    The present study is intended to investigate the current status of the information control system in the coal liquefaction technology development project, and structure a coal liquefaction database system to manage and utilize comprehensively the items of information provided by the system. Section 2 shows the result of epitomizing opinions on the purpose of the coal liquefaction database by means of a questionnaire survey to NEDO, and opinions of people of experience and academic standing. Section 3 depicts the basic conception of a coal database total system. Section 4 summarizes the conceptual idea of the fundamental database by washing out the data input and output, and the contents recorded in the database. Section 5 summarizes the basic sub-system required for management and utilization of the database, and different application systems for data analysis required in each stage of performing the coal liquefaction technology development, and for operation assistance. Section 6 summarizes a general technological information retrieval system, in which general information on coal liquefaction is recorded, processed, and registered and accumulated in the database, and then the information retrieval and the original information providing service are carried out. Section 7 summarizes philosophies on development and operation of the coal liquefaction database, operating institutions, and problems to be solved. (NEDO)

  11. Survey report for fiscal 1993 on development of coal and brown coal liquefaction technologies. Part 2. Survey of economic efficiency of brown coal liquefaction process; 1993 nendo sekitan ekika gijutsu kaihatsu kattan ekika gijutsu no kaihatsu chosa hokokusho. 2. Kattan ekika process no keizaisei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    Financial assessment is carried out by estimating the liquefaction product cost (selling price) at which the predetermined rate of return on investment is to be earned, which is calculated by the DCF (discount cash flow) method. The cash flow is determined from the net after taxes for each business year, and the balance after the subtraction of long- and short-term borrowings is converted to the present worth as of the operation commencement year at the predetermined discount rate, and a total is calculated for the period. When the difference between the total and the equity does not vanish, the coal liquid selling price is changed, and this process is repeated until the difference vanishes. If a 20% reduction in the plant construction cost is feasible, the coal liquefaction product will be competing with the crude oil in the market in around 2030. Although the financial analysis is a profitability analysis from the fund providers' viewpoint, the benefit as seen from the project siting country needs to be assessed by an economic analysis, and probabilities are that, in the presence of great profits, the project will materialize if the two are found to earn more than average after the profits are impartially divided. Japan's benefits and expenditures are compared and subjected to an economic analysis, and a result of 6-15% is obtained. This means that the project will realize in case EIRR (economic internal rate of return) is higher than the fund procuring cost of 11%. (NEDO)

  12. Survey report for fiscal 1993 on development of coal and brown coal liquefaction technologies. Part 2. Survey of economic efficiency of brown coal liquefaction process; 1993 nendo sekitan ekika gijutsu kaihatsu kattan ekika gijutsu no kaihatsu chosa hokokusho. 2. Kattan ekika process no keizaisei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    Financial assessment is carried out by estimating the liquefaction product cost (selling price) at which the predetermined rate of return on investment is to be earned, which is calculated by the DCF (discount cash flow) method. The cash flow is determined from the net after taxes for each business year, and the balance after the subtraction of long- and short-term borrowings is converted to the present worth as of the operation commencement year at the predetermined discount rate, and a total is calculated for the period. When the difference between the total and the equity does not vanish, the coal liquid selling price is changed, and this process is repeated until the difference vanishes. If a 20% reduction in the plant construction cost is feasible, the coal liquefaction product will be competing with the crude oil in the market in around 2030. Although the financial analysis is a profitability analysis from the fund providers' viewpoint, the benefit as seen from the project siting country needs to be assessed by an economic analysis, and probabilities are that, in the presence of great profits, the project will materialize if the two are found to earn more than average after the profits are impartially divided. Japan's benefits and expenditures are compared and subjected to an economic analysis, and a result of 6-15% is obtained. This means that the project will realize in case EIRR (economic internal rate of return) is higher than the fund procuring cost of 11%. (NEDO)

  13. Proposal and design of a natural gas liquefaction process recovering the energy obtained from the pressure reducing stations of high-pressure pipelines

    Science.gov (United States)

    Tan, Hongbo; Zhao, Qingxuan; Sun, Nannan; Li, Yanzhong

    2016-12-01

    Taking advantage of the refrigerating effect in the expansion at an appropriate temperature, a fraction of high-pressure natural gas transported by pipelines could be liquefied in a city gate station through a well-organized pressure reducing process without consuming any extra energy. The authors proposed such a new process, which mainly consists of a turbo-expander driven booster, throttle valves, multi-stream heat exchangers and separators, to yield liquefied natural gas (LNG) and liquid light hydrocarbons (LLHs) utilizing the high-pressure of the pipelines. Based on the assessment of the effects of several key parameters on the system performance by a steady-state simulation in Aspen HYSYS, an optimal design condition of the proposed process was determined. The results showed that the new process is more appropriate to be applied in a pressure reducing station (PRS) for the pipelines with higher pressure. For the feed gas at the pressure of 10 MPa, the maximum total liquefaction rate (ytot) of 15.4% and the maximum exergy utilizing rate (EUR) of 21.7% could be reached at the optimal condition. The present process could be used as a small-scale natural gas liquefying and peak-shaving plant at a city gate station.

  14. Report on the FY 1998 results of the New Sunshine Project (B version). Data attached 2. Development of coal liquefaction technology (Development of base technology of liquefaction (Project on internationalization of coal liquefaction technology)); 1998 nendo sekitan ekika gijutsu kaihatsu seika hokokusho (B ban). Ekika kiban gijutsu no kaihatsu (sekitan ekika gijutsu no kokusaika jigyo (fuzoku shiryo 2))

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    As a part of the project for internationalization of coal liquefaction technology, this paper reported on the potential survey for location of Indonesian low grade coal liquefaction (study of applicability of the improved BCL process and survey of hydrogen production technology using coal gasification). The survey was conducted of a locational possibility of a coal liquefaction commercial plant to be located at mine site in South Sumatra for Banko coal raw material. The improved BCL process was applied in which the results of the study by NBCL Takasago Research Institute were reflected. Further, the hydrogen production was studied by gasification of Banko coal, and the comparison was made with the conventional natural gas reforming method. As a result of the study using information/knowledge obtained during the conceptual design of Australian brown coal, the construction cost of commercial scale liquefaction plant with the Banko coal processing amount of 30,000 tons/day became 549.8 billion yen in the case of using natural gas as raw material for hydrogen production. This construction cost is the lowest as compared with 601.7 billion yen in the demonstrative BCL process and with 577.1 billion yen in the advanced BCL process. This is a process making use of features of Banko coal. The process for hydrogen production by the steam reforming method using natural gas has an advantage of increasing the production amount of coal-derived liquid the most of the three other methods. (NEDO)

  15. Report on the FY 1998 results of the New Sunshine Project (B version). Data attached 1. Development of coal liquefaction technology (Development of base technology of liquefaction (Project on internationalization of coal liquefaction technology)); 1998 nendo sekitan ekika gijutsu kaihatsu seika hokokusho (B ban). Ekika kiban gijutsu no kaihatsu (sekitan ekika gijutsu no kokusaika jigyo (fuzoku shiryo-1))

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    As a part of the project for internationalization of coal liquefaction technology, this paper reported on the potential survey for location of Indonesian low grade coal liquefaction (study of applicability of the improved BCL process and survey of hydrogen production technology using coal gasification). The survey was conducted of a locational possibility of a coal liquefaction commercial plant to be located at mine site in South Sumatra for Banko coal raw material. The improved BCL process was applied in which the results of the study by NBCL Takasago Research Institute were reflected. Further, the hydrogen production was studied by gasification of Banko coal, and the comparison was made with the conventional natural gas reforming method. As a result of the study using information/knowledge obtained during the conceptual design of Australian brown coal, the construction cost of commercial scale liquefaction plant with the Banko coal processing amount of 30,000 tons/day became 549.8 billion yen in the case of using natural gas as raw material for hydrogen production. This construction cost is the lowest as compared with 601.7 billion yen in the demonstrative BCL process and with 577.1 billion yen in the advanced BCL process. This is a process making use of features of Banko coal. The process for hydrogen production by the steam reforming method using natural gas has an advantage of increasing the production amount of coal-derived liquid the most of the three other methods. (NEDO)

  16. Liquefaction of uranium tailings

    International Nuclear Information System (INIS)

    1992-02-01

    Numerical methods for assessing the liquefaction potential of soils are reviewed with a view to their application to uranium tailings. The method can be divided into two categories: total stress analysis, where changes in pore pressure are not considered in the soil model, and effective stress analysis, where changes in pore pressure are included in the soil model. Effective stress analysis is more realistic, but few computer programs exist for such analysis in two or three dimensions. A simple linearized, two-dimensional, finite element effective stress analysis which incorporates volumetric compaction due to shear motion is described and implemented. The new program is applied to the assessment of liquefaction potential of tailings in the Quirke Mine tailings area near Elliot Lake, Ontario. The results are compared with those of a total stress analysis. Both analyses indicate liquefaction would occur if a magnitude 6.0 earthquake were to occur near the area. However, the extent of liquefaction predicted by the effective stress analysis is much less than that predicted by the total stress analysis. The results of both methods are sensitive to assumed material properties and to the method used to determine the cyclic shear strength of the tailings. Further analysis, incorporating more in situ and/or laboratory data, is recommended before conclusions can be made concerning the dynamic stability of these tailings

  17. Hydrothermal Liquefaction of the Microalgae Phaeodactylum tricornutum

    DEFF Research Database (Denmark)

    Sigaard Christensen, Per; Peng, Gaël; Vogel, Frédéric

    2014-01-01

    The microalgae Phaeodactylum tricornutum was processed by hydrothermal liquefaction in order to assess the influence of reaction temperature and reaction time on the product and elemental distribution. The experiments were carried out at different reaction times (5 and 15 min) and over a wide range...

  18. Liquefaction of torrefied wood using microwave irradiation

    Science.gov (United States)

    Mengchao Zhou; Thomas Eberhardt; Pingping Xin; Chung-Yun Hse; Hui Pan

    2016-01-01

    Torrefaction is an effective pretreatment method to improve the uniformity and quality of lignocellulosic biomass before further thermal processing (e.g., gasification, combustion). The objective of this study was to determine the impacts of torrefaction as a pretreatment before liquefaction. Wood chips were torrefied for 2 h at three different temperatures (230, 260,...

  19. Advances in uranium enrichment processes

    International Nuclear Information System (INIS)

    Rae, H.K.; Melvin, J.G.; Slater, J.B.

    1986-05-01

    Advances in gas centrifuges and development of the atomic vapour laser isotope separation process promise substantial reductions in the cost of enriched uranium. The resulting reduction in LWR fuel costs could seriously erode the economic advantage of CANDU, and in combination with LWR design improvements, shortened construction times and increased operational reliability could allow the LWR to overtake CANDU. CANDU's traditional advantages of neutron economy and high reliability may no longer be sufficient - this is the challenge. The responses include: combining neutron economy and dollar economy by optimizing CANDU for slightly enriched uranium fuel; developing cost-reducing improvements in design, manufacture and construction; and reducing the cost of heavy water. Technology is a renewable resource which must be continually applied to a product for it to remain competitive in the decades to come. Such innovation is a prerequisite to Canada increasing her share of the international market for nuclear power stations. The higher burn-up achievable with enriched fuel in CANDU can reduce the fuel cycle costs by 20 to 40 percent for a likely range of costs for yellowcake and separative work. Alternatively, some of the benefits of a higher fissile content can take the form of a cheaper reactor core containing fewer fuel channels and less heavy water, and needing only a single fuelling machine. An opportunity that is linked to this need to introduce an enriched uranium fuel cycle into CANDU is to build an enrichment business in Canada. This could offer greater value added to our uranium exports, security of supply for enriched CANDUs, technological growth in Canada and new employment opportunities. AECL has a study in progress to define this opportunity

  20. Assessment of liquefaction-induced hazards using Bayesian networks based on standard penetration test data

    Science.gov (United States)

    Tang, Xiao-Wei; Bai, Xu; Hu, Ji-Lei; Qiu, Jiang-Nan

    2018-05-01

    Liquefaction-induced hazards such as sand boils, ground cracks, settlement, and lateral spreading are responsible for considerable damage to engineering structures during major earthquakes. Presently, there is no effective empirical approach that can assess different liquefaction-induced hazards in one model. This is because of the uncertainties and complexity of the factors related to seismic liquefaction and liquefaction-induced hazards. In this study, Bayesian networks (BNs) are used to integrate multiple factors related to seismic liquefaction, sand boils, ground cracks, settlement, and lateral spreading into a model based on standard penetration test data. The constructed BN model can assess four different liquefaction-induced hazards together. In a case study, the BN method outperforms an artificial neural network and Ishihara and Yoshimine's simplified method in terms of accuracy, Brier score, recall, precision, and area under the curve (AUC) of the receiver operating characteristic (ROC). This demonstrates that the BN method is a good alternative tool for the risk assessment of liquefaction-induced hazards. Furthermore, the performance of the BN model in estimating liquefaction-induced hazards in Japan's 2011 Tōhoku earthquake confirms its correctness and reliability compared with the liquefaction potential index approach. The proposed BN model can also predict whether the soil becomes liquefied after an earthquake and can deduce the chain reaction process of liquefaction-induced hazards and perform backward reasoning. The assessment results from the proposed model provide informative guidelines for decision-makers to detect the damage state of a field following liquefaction.

  1. Report on the coal liquefaction committee in fiscal 1992; 1992 nendo sekitan ekika iinkai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-03-01

    This paper reports the activities of the coal liquefaction committee in fiscal 1992. The first committee meeting was held on August 21. After having confirmed the minutes of the previous meeting, an explanation was given on the research and development plans in fiscal 1992. The explanation covered the general explanation, bituminous coal liquefaction, brown coal liquefaction, and the common and fundamental aspects. The presented topics included the achievements in the operations using a bituminous coal liquefaction PSU and a small device, the status of compiling the achievements in the brown coal liquefaction project, preparation of the basic policy on developing the common basic technologies, and structuring of a coal liquefaction technology package. The second meeting was held on March 18, 1993. The meeting verified the minutes of the previous meeting, and gave the sub-committee reports for fiscal 1992. The sub-committees include those for bituminous coal liquefaction, brown coal liquefaction, environmental safety evaluation, and separation and refining technologies. As the summary of the achievements in fiscal 1992, descriptions were given on the bituminous coal liquefaction, brown coal liquefaction, and common and basic aspects. The fiscal 1993 plan presented included the budget aspect. A description was given as a topic on the economic performance evaluation and the working scheme (the execution plan) for the brown coal liquefaction process. (NEDO)

  2. Technical and economic aspects of brown coal gasification and liquefaction

    International Nuclear Information System (INIS)

    Speich, P.

    1980-01-01

    A number of gasification and liquefaction processes for Rhenish brown coal are investigated along with the technical and economic aspects of coal beneficiation. The status of coal beneficiation and the major R + D activities are reviewed. (orig.) [de

  3. Coal liquefaction committee report for fiscal 1981; 1981 nendo sekitan ekika iinkai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    For the assurance of smooth progress of coal technology development endeavors, the New Energy and Industrial Technology Development Organization (NEDO) has installed coal technology development committees (general committee on coal technologies, coal liquefaction committee, plant materials committee, coal type survey committee, total system committee, and coal gasification committee). The coal liquefaction committee deliberates and evaluates liquefaction technology and propels forward smoothly the efforts to develop the technology. Under the coal liquefaction committee, there are four subcommittees, which are the 1st subcommittee (primary liquefaction subcommittee), 2nd subcommittee (solid/liquid separation subcommittee), 3rd subcommittee (secondary hydrogenation subcommittee), and the 4th subcommittee (brown coal liquefaction subcommittee). The 2nd and 3rd subcommittees deal with common tasks as they were studied in fiscal 1980. The 1st subcommittee incorporates into itself the old subcommittees that respectively worked on the three liquefaction processes (the direct hydrogenation process, the solvent extraction process, and the Solvolysis process), and is designed to provide a site for information exchange. A brown coal liquefaction committee is incorporated into the coal liquefaction committee as the 4th subcommittee. This report is a compilation of the agendas of the respective subcommittees of the coal liquefaction committee. (NEDO)

  4. Coal liquefaction technologies for producing ultra clean fuel

    International Nuclear Information System (INIS)

    Tahir, M.S.; Haq, N.U.; Nasir, H.; Islam, N.

    2011-01-01

    The expanding demand for petroleum, accompanied by the diminishing petroleum reserves and the energy security, has intensified the significance in coal liquefaction technologies (CTL) globally and specially in Pakistan. Pakistan is rich in coal resources, but short of petroleum. The Geological Survey of Pakistan based on wide spread drilling over an area of 9000 sq. km, a total of 175 billion tons of coal resource potential has been assessed. This paper overviews a general introduction on the mechanisms and processes of CLT such as direct coal liquefaction (DCL) and indirect coal liquefaction (ICL) technologies. (author)

  5. Influence of clay content on wave-induced liquefaction

    DEFF Research Database (Denmark)

    Kirca, V.S. Ozgur; Sumer, B. Mutlu; Fredsøe, Jørgen

    2014-01-01

    of measurements were carried out: (1) pore-water pressure measurements across the soil depth and (2) water-surface elevation measurements. These measurements were synchronized with video recordings of the liquefaction process from the side. The ranges of the various quantities in the experiments were wave height...... of silt and clay was not liquefied. Sand may become prone to liquefaction with the introduction of clay, contrary to the general perception that this type of sediment is normally liquefaction-resistant under waves. For instance, sand with d50 50:4 mmwas liquefied with CC510:8%, whereas sand with d50 50...

  6. Fiscal 1994 achievement report 1/2. Coal liquefaction technology development - Bituminous coal liquefaction technology development - Study for supporting pilot plant - Study using 1t/d PSU (Study of operation using PSU); 1994 nendo seika hokokusho 1/2. Sekitan ekika gijutsu kaihatsu - Rekiseitan ekika gijutsu no kaihatsu - Pilot plant no shien kenkyu - 1t/d process support unit (PSU) ni yoru kenkyu (PSU ni yoru unten kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The operation of a 1t/d PSU (process support unit) was studied in the NEDOL coal liquefaction process. Modification was made, which involved the installation of a high-temperature/high-pressure sampling device for observing reaction and fluidity in the liquefaction reactor, a differential pressure measuring device, and a neutron attenuation-aided measuring device. Relative to coal injection, a 49.5-day and 49.3-day slurry injections were carried out using Tanito Harum coal, when impacts on the product yield and the operability of the unit were examined. A verification test was conducted for an improved hydrogenation catalyst, and liquefaction reactor characteristics were investigated. During a 19-day operation for the study of maintenance, newly installed equipment and devices were verified for function, and operating methods were probed into. In the survey of environments, characteristics were examined of the wastewater discharged from the Tanito Harum coal liquefaction process, and wastewater treatment methods were studied. The air, odor, and tar mist were examined with the PSU in operation, and the measured values were found to be below the management limits showing that its operation did not pose any problems relating to working environments. (NEDO)

  7. Residual Liquefaction under Standing Waves

    DEFF Research Database (Denmark)

    Kirca, V.S. Ozgur; Sumer, B. Mutlu; Fredsøe, Jørgen

    2012-01-01

    This paper summarizes the results of an experimental study which deals with the residual liquefaction of seabed under standing waves. It is shown that the seabed liquefaction under standing waves, although qualitatively similar, exhibits features different from that caused by progressive waves....... The experimental results show that the buildup of pore-water pressure and the resulting liquefaction first starts at the nodal section and spreads towards the antinodal section. The number of waves to cause liquefaction at the nodal section appears to be equal to that experienced in progressive waves for the same...

  8. Studies in coal liquefaction with application to the SRC and related processes. Quarterly report, August 1981-October 1981. [Using model compounds

    Energy Technology Data Exchange (ETDEWEB)

    Tarrer, A. R.; Guin, J. A.; Curtis, C. W.

    1981-01-01

    Model compound reactions were studied to evaluate the effects of mass transfer, solvent type, solvent blending, hydrogen partial pressure, temperature, reactant concentration, additive loading and its preparation, etc. Naphthalene hydrogenation and benzothiophene hydrodesulfurization were investigated under the conditions comparable to commercial coal liquefaction and related processes. Both of these reaction systems were observed to be surface reaction controlled under the reaction conditions used in this work. Certain aromatic compounds were observed to cause a reduction in the reaction rates of naphthalene and benzothiophene. Single stage coal dissolution was investigated using tetralin as a hydrogen donor solvent and a commercial cobalt-molybdate catalyst. A spinning basket system was developed to allow injection of the catalyst at a desired time in the reaction cycle. This catalyst injection technique proved to be reliable for the exploratory work done here. The degree of catalyst deactivation was rated by comparing the activities of the spent catalyst for model compound (naphthalene and cumene) reactivities relative to those of the fresh catalyst. No substantial reduction in deactivation was observed to result with delayed contacting of the catalyst with the coal-tetralin reaction mixture. The effect of reaction temperature on the initial rate of catalyst deactivation was also studied.

  9. Report on the coal group in the Sunshine Project in fiscal 1988. Studies on a coal treatment technology in the initial process in liquefaction; 1989 nendo ekika shoki kotei ni okeru sekitan shori gijutsu no kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-03-01

    This paper reports the achievements in the Sunshine Project in fiscal 1988 in studies on the studies of the initial process in liquefaction. It is intended to identify the swelling phenomenon in coal particles in the coal slurry preparation and preheating processes, and change in the slurry viscosity associated with the heating. The slurry viscosity starts decreasing from around 300 degrees C at which the liquefying reaction begins, and decreases sharply at around 350 degrees C. Therefore, rise in the viscosity at temperatures below 300 degrees C is caused by factors other than the liquefying reaction. The rise starting at 100 to 120 degrees C is due to absorption of the solvent by coal. The rise starting at 210 to 260 degrees C requires further discussions. The equilibrium swelling ratio was measured on different types of coals by using the hydrogenated anthracene oil solvent. No coals swelled at 100 degrees C. The temperature of 200 degrees C largely divides coals into those swelling and those not swelling. At 300 degrees C, the coals were divided into those shrinking after largely swelling, those not swelling and those swelling monotonously. For consideration of the utilization as an auxiliary solvent, petroleum-based heavy oil was used to perform coal liquefaction to discuss effects of the solvent on the liquefaction rates. (NEDO)

  10. Nontraditional machining processes research advances

    CERN Document Server

    2013-01-01

    Nontraditional machining employs processes that remove material by various methods involving thermal, electrical, chemical and mechanical energy or even combinations of these. Nontraditional Machining Processes covers recent research and development in techniques and processes which focus on achieving high accuracies and good surface finishes, parts machined without burrs or residual stresses especially with materials that cannot be machined by conventional methods. With applications to the automotive, aircraft and mould and die industries, Nontraditional Machining Processes explores different aspects and processes through dedicated chapters. The seven chapters explore recent research into a range of topics including laser assisted manufacturing, abrasive water jet milling and hybrid processes. Students and researchers will find the practical examples and new processes useful for both reference and for developing further processes. Industry professionals and materials engineers will also find Nontraditional M...

  11. Advanced methods for processing ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Carter, W.B. [Georgia Institute of Technology, Atlanta, GA (United States)

    1995-05-01

    Combustion chemical vapor deposition (CCVD) is a flame assisted, open air chemical vapor deposition (CVD) process. The process is capable of producing textured, epitaxial coatings on single crystal substrates using low cost reagents. Combustion chemical vapor deposition is a relatively inexpensive, alternative thin film deposition process with potential to replace conventional coating technologies for certain applications. The goals of this project are to develop the CCVD process to the point that potential industrial applications can be identified and reliably assessed.

  12. Advanced methods for processing ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Carter, W.B. [Georgia Institute of Technology, Atlanta, GA (United States)

    1997-04-01

    Combustion chemical vapor deposition (combustion CVD) is being developed for the deposition of high temperature oxide coatings. The process is being evaluated as an alternative to more capital intensive conventional coating processes. The thrusts during this reporting period were the development of the combustion CVD process for depositing lanthanum monazite, the determination of the influence of aerosol size on coating morphology, the incorporation of combustion CVD coatings into thermal barrier coatings (TBCs) and related oxidation research, and continued work on the deposition of zirconia-yttria coatings.

  13. Cooperative research in coal liquefaction infratechnology and generic technology development: Final report, October 1, 1985 to December 31, 1986

    Energy Technology Data Exchange (ETDEWEB)

    Sendlein, L.V.A.

    1987-06-29

    During the first year of its research program, the Consortium for Fossil Fuel Liquefaction Science has made significant progress in many areas of coal liquefaction and coal structure research. Research topics for which substantial progress has been made include integrated coal structure and liquefaction studies, investigation of differential liquefaction processes, development and application of sophisticated techniques for structural analysis, computer analysis of multivariate data, biodesulfurization of coal, catalysis studies, co-processing of coal and crude oil, coal dissolution and extraction processes, coal depolymerization, determination of the liquefaction characteristics of many US coals for use in a liquefaction database, and completion of a retrospective technology assessment for direct coal liquefaction. These and related topics are discussed in considerably more detail in the remainder of this report. Individual projects are processed separately for the data base.

  14. Advancements in Big Data Processing

    CERN Document Server

    Vaniachine, A; The ATLAS collaboration

    2012-01-01

    The ever-increasing volumes of scientific data present new challenges for Distributed Computing and Grid-technologies. The emerging Big Data revolution drives new discoveries in scientific fields including nanotechnology, astrophysics, high-energy physics, biology and medicine. New initiatives are transforming data-driven scientific fields by pushing Bid Data limits enabling massive data analysis in new ways. In petascale data processing scientists deal with datasets, not individual files. As a result, a task (comprised of many jobs) became a unit of petascale data processing on the Grid. Splitting of a large data processing task into jobs enabled fine-granularity checkpointing analogous to the splitting of a large file into smaller TCP/IP packets during data transfers. Transferring large data in small packets achieves reliability through automatic re-sending of the dropped TCP/IP packets. Similarly, transient job failures on the Grid can be recovered by automatic re-tries to achieve reliable Six Sigma produc...

  15. Advanced Electrorefining Process at KAERI

    International Nuclear Information System (INIS)

    Hansoo Lee; Jong Hyun Lee; Sung Bin Park; Yoon Sang Lee; Eung Ho Kim; Sung Won Park

    2008-01-01

    In order to enhance the throughput of a pyro-processing in which electrochemical processes are mostly engaged, the design of a continuous concept is required. The graphite cathode in the electro-refiner enables the uranium deposit on the cathodes to be stripped off spontaneously, resulting in a continuous reaction. The collected uranium deposits at the bottom of the inner cone of the reactor are transferred by a conveyor. The residuals in the anode basket after the uranium is depleted are noble metals. These are also collected at the bottom of the outer shell of the reactor, and conveyed from the reactor for a further treatment. This work addresses the design of the electro-refiner for a continuous operation. The behavior of particles such as uranium dendrites or noble metals was analyzed to achieve the proper operating conditions. The operating conditions for the cathode processor in which molten salt is distilled were also investigated. (authors)

  16. Two-stage liquefaction of a Spanish subbituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, M.T.; Fernandez, I.; Benito, A.M.; Cebolla, V.; Miranda, J.L.; Oelert, H.H. (Instituto de Carboquimica, Zaragoza (Spain))

    1993-05-01

    A Spanish subbituminous coal has been processed in two-stage liquefaction in a non-integrated process. The first-stage coal liquefaction has been carried out in a continuous pilot plant in Germany at Clausthal Technical University at 400[degree]C, 20 MPa hydrogen pressure and anthracene oil as solvent. The second-stage coal liquefaction has been performed in continuous operation in a hydroprocessing unit at the Instituto de Carboquimica at 450[degree]C and 10 MPa hydrogen pressure, with two commercial catalysts: Harshaw HT-400E (Co-Mo/Al[sub 2]O[sub 3]) and HT-500E (Ni-Mo/Al[sub 2]O[sub 3]). The total conversion for the first-stage coal liquefaction was 75.41 wt% (coal d.a.f.), being 3.79 wt% gases, 2.58 wt% primary condensate and 69.04 wt% heavy liquids. The heteroatoms removal for the second-stage liquefaction was 97-99 wt% of S, 85-87 wt% of N and 93-100 wt% of O. The hydroprocessed liquids have about 70% of compounds with boiling point below 350[degree]C, and meet the sulphur and nitrogen specifications for refinery feedstocks. Liquids from two-stage coal liquefaction have been distilled, and the naphtha, kerosene and diesel fractions obtained have been characterized. 39 refs., 3 figs., 8 tabs.

  17. The Laboratory for Advanced Materials Processing

    Data.gov (United States)

    Federal Laboratory Consortium — The Laboratory for Advanced Materials Processing - LAMP - is a clean-room research facility run and operated by Pr. Gary Rubloff's group. Research activities focus...

  18. Advanced oxidation processes: overall models

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, M. [Univ. de los Andes, Escuela Basica de Ingenieria, La Hechicera, Merida (Venezuela); Curco, D.; Addardak, A.; Gimenez, J.; Esplugas, S. [Dept. de Ingenieria Quimica. Univ. de Barcelona, Barcelona (Spain)

    2003-07-01

    Modelling AOPs implies to consider all the steps included in the process, that means, mass transfer, kinetic (reaction) and luminic steps. In this way, recent works develop models which relate the global reaction rate to catalyst concentration and radiation absorption. However, the application of such models requires to know what is the controlling step for the overall process. In this paper, a simple method is explained which allows to determine the controlling step. Thus, it is assumed that reactor is divided in two hypothetical zones (dark and illuminated), and according to the experimental results, obtained by varying only the reaction volume, it can be decided if reaction occurs only in the illuminated zone or in the all reactor, including dark zone. The photocatalytic degradation of phenol, by using titania degussa P-25 as catalyst, is studied as reaction model. The preliminary results obtained are presented here, showing that it seems that, in this case, reaction only occurs in the illuminated zone of photoreactor. A model is developed to explain this behaviour. (orig.)

  19. Traditional machining processes research advances

    CERN Document Server

    2015-01-01

    This book collects several examples of research in machining processes. Chapter 1 provides information on polycrystalline diamond tool material and its emerging applications. Chapter 2 is dedicated to the analysis of orthogonal cutting experiments using diamond-coated tools with force and temperature measurements. Chapter 3 describes the estimation of cutting forces and tool wear using modified mechanistic models in high performance turning. Chapter 4 contains information on cutting under gas shields for industrial applications. Chapter 5 is dedicated to the machinability of magnesium and its alloys. Chapter 6 provides information on grinding science. Finally, chapter 7 is dedicated to flexible integration of shape and functional modelling of machine tool spindles in a design framework.    

  20. Japan's New Sunshine Project. 1994 annual summary of coal liquefaction and gasification

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-01

    This paper summarizes the report for fiscal 1994 on research and development related to coal liquefaction and gasification. In the research and development of coal liquefaction technologies, reports were given on research of liquefaction characteristics of different coals and liquefaction process thereof, and on research of catalysts for the coal liquefaction. In the research and development of coal gasification technologies, reports were given on fundamental studies on gasification characteristics of different coals. In the research and development of liquefaction technologies for bituminous coal, reports were given on design, construction and operation of a bituminous coal liquefaction pilot plant with a capacity of 150 t/d, and the operation supporting studies on the pilot plant. In the fundamental research on the coal liquefaction process, reports were given on refining technologies and utilization of the refined materials, and studies on environment preservation in applying the coal liquefaction technologies. In the research on hydrogen manufacturing technologies by using the fundamental coal technology, reports were given on design, construction and operational studies of a pilot plant. In the research and development of the coal gasification technologies, reports were given on development of a jet-flow gasified coal electric power plant, selection of coals, and development of a data processing system. (NEDO)

  1. Japan's New Sunshine Project. 1994 annual summary of coal liquefaction and gasification

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-01

    This paper summarizes the report for fiscal 1994 on research and development related to coal liquefaction and gasification. In the research and development of coal liquefaction technologies, reports were given on research of liquefaction characteristics of different coals and liquefaction process thereof, and on research of catalysts for the coal liquefaction. In the research and development of coal gasification technologies, reports were given on fundamental studies on gasification characteristics of different coals. In the research and development of liquefaction technologies for bituminous coal, reports were given on design, construction and operation of a bituminous coal liquefaction pilot plant with a capacity of 150 t/d, and the operation supporting studies on the pilot plant. In the fundamental research on the coal liquefaction process, reports were given on refining technologies and utilization of the refined materials, and studies on environment preservation in applying the coal liquefaction technologies. In the research on hydrogen manufacturing technologies by using the fundamental coal technology, reports were given on design, construction and operational studies of a pilot plant. In the research and development of the coal gasification technologies, reports were given on development of a jet-flow gasified coal electric power plant, selection of coals, and development of a data processing system. (NEDO)

  2. Potential of soil liquefaction at Perlis, northern region of Malalysia

    Science.gov (United States)

    Ghazaly, Zuhayr Md; Rahim, Mustaqqim Abdul; Nasir, Mohamad Amzar Bin Mhd; Isa, Nur Fitriah; Zaki, Mohd Faiz Mohammad; Hassan, Zulkarnain Bin; Ismail, Zul-Atfi Bin

    2017-09-01

    Soil liquefaction is earthquake's secondary effect which could cause fatal damages and structures instability. Despite Malaysia been located in stable zone of Pacific Ring of Fire, few significant surrounded quakes like Sumatra-Andaman earthquake had prompted Malaysian's public concern, especially in Perlis area, on local seismic resistant. Hence, this research presents the analysis result of liquefaction potential of the soils, as the secondary effect of earthquake, within Perlis, northern region of Malaysia; the next strong and sustainable metropolis by using semi-empirical procedures introduced by Seed and Idriss. The study consists of two stages which were determination of the local geological and geotechnical site conditions within Perlis and analysis of soil liquefaction susceptibility by using various methods and liquefaction potential by using Simplified Procedure developed by Seed and Idriss on stress approach. There were consist of four phases implemented in order to achieve the objectives targeted for the study after problem being identified. Firstly, a comprehensive review of literature on liquefaction at Perlis was carried out. Second phase was data collection process that includes collection of Site Investigation (SI) report. Thirdly, data analysis was carried out by utilizing suitable method. The final phase was to draw conclusion and recommendation for this study. It can be concluded that the overall Perlis due to earthquake moment magnitude below 7.5 has no potential to soil liquefaction. However, with the range of liquefaction potential of 1.60 to 5.64 in Kuala Perlis area, it is liquefiable. The development of liquefaction severity map of Perlis, Malaysia in this research, may be used by others as a reference for seismic design and standard safety measures as well as for further research work.

  3. Advanced Materials and Processing 2010

    Science.gov (United States)

    Zhang, Yunfeng; Su, Chun Wei; Xia, Hui; Xiao, Pengfei

    2011-06-01

    Strain sensors made from MWNT/polymer nanocomposites / Gang Yin, Ning Hu and Yuan Li -- Shear band evolution and nanostructure formation in titanium by cold rolling / Dengke Yang, Peter D. Hodgson and Cuie Wen -- Biodegradable Mg-Zr-Ca alloys for bone implant materials / Yuncang Li ... [et al.] -- Hydroxyapatite synthesized from nanosized calcium carbonate via hydrothermal method / Yu-Shiang Wu, Wen-Ku Chang and Min Jou -- Modeling of the magnetization process and orthogonal fluxgate sensitivity of ferromagnetic micro-wire arrays / Fan Jie ... [et al.] -- Fabrication of silicon oxide nanowires on Ni coated silicon substrate by simple heating process / Bo Peng and Kwon-Koo Cho -- Deposition of TiOxNy thin films with various nitrogen flow rate: growth behavior and structural properties / S.-J. Cho ... [et al.] -- Observation on photoluminescence evolution in 300 KeV self-ion implanted and annealed silicon / Yu Yang ... [et al.] -- Facile synthesis of lithium niobate from a novel precursor H[symbol] / Meinan Liu ... [et al.] -- Effects of the buffer layers on the adhesion and antimicrobial properties of the amorphous ZrAlNiCuSi films / Pai-Tsung Chiang ... [et al.] -- Fabrication of ZnO nanorods by electrochemical deposition process and its photovoltaic properties / Jin-Hwa Kim ... [et al.] -- Cryogenic resistivities of NbTiAlVTaLax, CoCrFeNiCu and CoCrFeNiAl high entropy alloys / Xiao Yang and Yong Zhang -- Modeling of centrifugal force field and the effect on filling and solidification in centrifugal casting / Wenbin Sheng, Chunxue Ma and Wanli Gu -- Electrochemical properties of TiO[symbol] nanotube arrays film prepared by anodic oxidation / Young-Jin Choi ... [et al.] -- Effect of Ce additions on high temperature properties of Mg-5Sn-3Al-1Zn alloy / Byoung Soo Kang ... [et al.] -- Sono-electroless plating of Ni-Mo-P film / Atsushi Chiba, Masato Kanou and Wen-Chang Wu -- Diameter dependence of giant magneto-impedance effect in co-based melt extracted amorphous

  4. Emerging materials by advanced processing

    International Nuclear Information System (INIS)

    Kaysser, W.A.; Weber-Bock, J.

    1989-01-01

    This volume contains 36 contributions with following subjects (selection): Densification of highly reactive aluminium titanate powders; influence of precursor history on carbon fiber characteristics; influence of water removal rate during calcination on the crystallization of ZrO2 from amorphous hydrous precipitates; tape casting of AlN; influence of processing on the properties of beta-SiC powders; corrosion of SiSiC by gases and basic slag at high temperature; influence of sintering and thermomechanical treatment on microstructure and properties of W-Ni-Fe alloys; mechanical alloying for development of sintered steels with high hard phase content (NbC); early stages of mechanical alloying in Ni-Ti and Ni-Al powder mixtures; growth and microstructural development of melt-oxidation derived Al2O3/Al-base composites; fabrication of RSBN composites; synthesis of high density coridierite bodies; comparative studies on post-HIP and sinter-HIP treatments on transformation thoughened ceramics; sinter HIP of SiC; precipitation mixing of Si3N4 with bimetallic oxides; temperature dependence of the interfacial energies in Al2O3-liquid metal systems; synthesis and microstructural examination of Synroc B; solid state investigation of ceramic-metal bonding; thermophysical properties of MgAl2O4; preparation, sintering and thermal expansion of MgAl2O4; microstructural studies on alumina-zirconia and metallized alumina ceramics; electrodeposition of metals (e.g. Ti, Mo, In) and metal oxides from molten salts; electrochemical deposition of Ti from nonaqueous media (DMSO, DMF); lithium as anode material in power sources (passivation); reduction of chromium(VI) when solar selective black chromium is deposited; thermodynamic optimization of phase diagrams (computer calculations); optimization of Na-Tl phase diagram; phase relations in the Y-Si-Al-O-N system: Controlled manufacturing of alpha/beta-SIALON composites. (MM)

  5. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, Mary J.; Davis, Ryan; Jones, Susanne B.; Zhu, Yunhua

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  6. EXPLORATORY RESEARCH ON NOVEL COAL LIQUEFACTION CONCEPT

    Energy Technology Data Exchange (ETDEWEB)

    Brandes, S.D.; Winschel, R.A.

    1998-11-30

    The report presents a summary the work performed under DOE Contract No. DE-AC22-95PC95050. Investigations performed under Task 4--Integrated Flow Sheet Testing are detailed. In this program, a novel direct coal liquefaction technology was investigated by CONSOL Inc. with the University of Kentucky Center for Applied Energy Research and LDP Associates. The process concept explored consists of a first-stage coal dissolution step in which the coal is solubilized by hydride ion donation. In the second stage, the products are catalytically upgraded to refinery feedstocks. Integrated first-stage and solids-separation steps were used to prepare feedstocks for second-stage catalytic upgrading. An engineering and economic evaluation was conducted concurrently with experimental work throughout the program. Approaches to reduce costs for a conceptual commercial plant were recommended at the conclusion of Task 3. These approaches were investigated in Task 4. The economic analysis of the process as it was defined at the conclusion of Task 4, indicates that the production of refined product (gasoline) via this novel direct liquefaction technology is higher than the cost associated with conventional two-stage liquefaction technologies.

  7. Advanced digital signal processing and noise reduction

    CERN Document Server

    Vaseghi, Saeed V

    2008-01-01

    Digital signal processing plays a central role in the development of modern communication and information processing systems. The theory and application of signal processing is concerned with the identification, modelling and utilisation of patterns and structures in a signal process. The observation signals are often distorted, incomplete and noisy and therefore noise reduction, the removal of channel distortion, and replacement of lost samples are important parts of a signal processing system. The fourth edition of Advanced Digital Signal Processing and Noise Reduction updates an

  8. Characteristics estimation of coal liquefaction residue; Sekitan ekika zansa seijo no suisan ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Itonaga, M.; Imada, K. [Nippon Steel Corp., Tokyo (Japan); Okada, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan)

    1996-10-28

    The paper studied a possibility of estimating characteristics of coal liquefaction residue from liquefaction conditions in the case of fixing coal kind in the NEDOL process coal liquefaction PSU. Wyoming coal was used for the study, and the already proposed simplified liquefaction reaction models were used. Among material balances explained by the models, those of asphaltene, preasphaltene, THF insoluble matters are concerned with residue composition. Ash content is separately calculated from ash balance. Reaction velocity constants of simplified liquefaction reaction models which influence the residue composition were obtained by the multiple regression method from experimental results in the past. The estimation expression of residue viscosity was introduced from residue ash/composition. When the residue composition is estimated by the model from liquefaction conditions, and the residue viscosity is obtained using it, the higher the liquefaction temperature is, the higher the residue viscosity is. The result obtained well agreed the measuring result. The simplified liquefaction model of a certain coal kind has been established, and characteristics of residue can be estimated even at liquefaction conditions which have never been experienced before if there is a certain amount of the accumulated data on residue composition/characteristics. 4 refs., 4 figs., 4 tabs.

  9. FY 1992 report on the Coal Liquefaction Committee; 1992 nendo sekitan ekika iinkai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-03-01

    The paper reported activities of the Coal Liquefaction Committee in FY 1992. In the 1st committee meeting, report/discussion were made of the summary of the FY 1992 R and D plan on the bituminous coal liquefaction, brown coal liquefaction and the common/basic technology. Further, the following were reported as topics: results of the operation by bituminous coal liquefaction PSU and small equipment, state of arrangement of the results of the brown coal liquefaction project, making of the basic policy for development of the common/basic technology, construction of package of coal liquefaction technology. In the 2nd committee meeting, the summary of the results of the FY 1992 R and D was reported/discussed. As to the development of bituminous coal liquefaction technology, study using pilot plant and support study were reported. Concerning the development of brown coal liquefaction technology, study using a 50t/d pilot plant and complementary study of operation. Relating to the development of the common/basic technology, trial manufacture/development of plant equipment/materials, survey of selection of coal kind, etc. The paper also reported a scheme on the evaluation of efficiency of the brown coal liquefaction process. (NEDO)

  10. Secondary liquefaction in ethanol production

    DEFF Research Database (Denmark)

    2007-01-01

    The invention relates to a method of producing ethanol by fermentation, said method comprising a secondary liquefaction step in the presence of a themostable acid alpha-amylase or, a themostable maltogenic acid alpha-amylase.......The invention relates to a method of producing ethanol by fermentation, said method comprising a secondary liquefaction step in the presence of a themostable acid alpha-amylase or, a themostable maltogenic acid alpha-amylase....

  11. Advances in radiation processing of polymeric materials

    International Nuclear Information System (INIS)

    Makuuchi, K.; Sasak, T.; Vikis, A.C.; Singh, A.

    1993-12-01

    In this paper we review recent advances in industrial applications of electron-beam irradiation in the field of polymer processing at the Takasaki Radiation Chemistry Research Establishment (TRCRE) of JAERI (Japan Atomic Energy Research Institute), and the Whiteshell Laboratories of AECL Research, Canada. Irradiation of a substrate with ionizing radiation produces free radicals through ionization and excitation events. The subsequent chemistry of these radicals is used in radiation processing as a substitute for conventional processing techniques based on heating and/or the addition of chemicals. The advantages of radiation processing include the formation of novel products with desirable material properties, favourable overall process economics and, often, environmental benefits

  12. Magnetic refrigerator for hydrogen liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Numazawa, T [National Institute for Materials Science, Tsukuba (Japan); Kamlya, K. [Japan Atomic Energy Agency, Naka (Japan); Utaki, T. [Osaka University, Osaka (Japan); Matsumoto, K. [Kanazawa University, Kanazawa (Japan)

    2013-06-15

    This paper reviews the development status of magnetic refrigeration system for hydrogen liquefaction. There is no doubt that hydrogen is one of most important energy sources in the near future. In particular, liquid hydrogen can be utilized for infrastructure construction consisting of storage and transportation. Liquid hydrogen is in cryogenic temperatures and therefore high efficient liquefaction method must be studied. Magnetic refrigeration which uses the magneto-caloric effect has potential to realize not only the higher liquefaction efficiency > 50 %, but also to be environmentally friendly and cost effective. Our hydrogen magnetic refrigeration system consists of Carnot cycle for liquefaction stage and AMR (active magnetic regenerator) cycle for precooling stages. For the Carnot cycle, we develop the high efficient system > 80 % liquefaction efficiency by using the heat pipe. For the AMR cycle, we studied two kinds of displacer systems, which transferred the working fluid. We confirmed the AMR effect with the cooling temperature span of 12 K for 1.8 T of the magnetic field and 6 second of the cycle. By using the simulation, we estimate the total efficiency of the hydrogen liquefaction plant for 10 kg/day. A FOM of 0.47 is obtained in the magnetic refrigeration system operation temperature between 20 K and 77 K including LN2 work input.

  13. BP and NCB to collaborate in coal liquefaction study. [Supercritical gas extraction; dissolution in anthracene oil

    Energy Technology Data Exchange (ETDEWEB)

    1978-02-17

    British Petroleum and NCB are collaborating in a two year study of coal liquefaction which could result in a demonstration plant being built. The two liquefaction techniques which the NCB is developing at present are supercritical extraction, and dissolution in anthracene oil. A disadvantage of the latter process is that high grade coking coals must be used.

  14. Dynamic dielectric properties of a wood liquefaction system using polyethylene glycol and glycerol

    Science.gov (United States)

    Mengchao Zhou; Thomas L. Eberhardt; Bo Cai; Chung-Yun Hse; Hui Pan

    2017-01-01

    Microwave-assisted liquefaction has shown potential for rapid thermal processing of lignocellulosic biomass. The efficiency of microwave heating depends largely on the dielectric properties of the materials being heated. The objective of this study was to investigate the dynamic interactions between microwave energy and the reaction system during the liquefaction of a...

  15. Process simulation for advanced composites production

    Energy Technology Data Exchange (ETDEWEB)

    Allendorf, M.D.; Ferko, S.M.; Griffiths, S. [Sandia National Labs., Livermore, CA (United States)] [and others

    1997-04-01

    The objective of this project is to improve the efficiency and lower the cost of chemical vapor deposition (CVD) processes used to manufacture advanced ceramics by providing the physical and chemical understanding necessary to optimize and control these processes. Project deliverables include: numerical process models; databases of thermodynamic and kinetic information related to the deposition process; and process sensors and software algorithms that can be used for process control. Target manufacturing techniques include CVD fiber coating technologies (used to deposit interfacial coatings on continuous fiber ceramic preforms), chemical vapor infiltration, thin-film deposition processes used in the glass industry, and coating techniques used to deposit wear-, abrasion-, and corrosion-resistant coatings for use in the pulp and paper, metals processing, and aluminum industries.

  16. Advanced Methods of Biomedical Signal Processing

    CERN Document Server

    Cerutti, Sergio

    2011-01-01

    This book grew out of the IEEE-EMBS Summer Schools on Biomedical Signal Processing, which have been held annually since 2002 to provide the participants state-of-the-art knowledge on emerging areas in biomedical engineering. Prominent experts in the areas of biomedical signal processing, biomedical data treatment, medicine, signal processing, system biology, and applied physiology introduce novel techniques and algorithms as well as their clinical or physiological applications. The book provides an overview of a compelling group of advanced biomedical signal processing techniques, such as mult

  17. Ion beam processing of advanced electronic materials

    International Nuclear Information System (INIS)

    Cheung, N.W.; Marwick, A.D.; Roberto, J.B.

    1989-01-01

    This report contains research programs discussed at the materials research society symposia on ion beam processing of advanced electronic materials. Major topics include: shallow implantation and solid-phase epitaxy; damage effects; focused ion beams; MeV implantation; high-dose implantation; implantation in III-V materials and multilayers; and implantation in electronic materials. Individual projects are processed separately for the data bases

  18. Hydrothermal liquefaction of microalgae's for bio oil production

    DEFF Research Database (Denmark)

    Toor, Saqib; Reddy, Harvind; Deng, Shuguang

    process water for algae cultivation. GC-MS, elemental analyzer, calorimeter and nutrient analysis were used to analyze bio-crude, lipid-extracted algae and water samples produced in the hydrothermal liquefaction process. The highest bio-oil yield of 46% was obtained on Nannochloropsis salina at 310 °C...... and 107 bar. For Spirulina platensis algae sample, the highest bio-oil yield is 38% at 350 °C and 195 bar. Preliminary data also indicate that a lipid-extracted algae solid residue sample obtained in the hydrothermal liquefaction process contains a high level of proteins...

  19. [Nursing process in advanced cardiopulmonary resuscitation].

    Science.gov (United States)

    Lucio Peña, Gerardo; Fuentes Leonardo, Ana María

    2002-01-01

    The process male nurse is a systematic and organized method to offer effective and efficient cares guided to the achievement of solving real problems of health, reducing the incidence and the duration. It is organized and systematic for that consists of five sequential and interrelated steps: Valuation, diagnostic, planning, execution and evaluation, in which are carried out interrelated actions, thought to maximize the long term results. The nurse process is based on the notion that the success of the cares is measured by the degree of effectiveness and the degree of satisfaction and the patient's progress. Applying this method in the Advanced Cardiac Live Support (ACLS) the identification of a cardiovascular or cardiopulmonary urgency was achieved that implies advanced treatment of the air road, defibrillation and appropriate medications to the circumstances. The ACLS challenges the nurses in charge from the patient's attention to make decisions quick low pressure and in dramatic scenes. Reason why it develops the flowing process male nurse in the advanced cardiopulmonary reanimation due to the incidence of these events in the National Institute of Cardiology Ignacio Chávez, which should guarantee the benefit of services in basic and advanced cardiopulmonary reanimation for personal with a high formation level in all the units of intensive cares and services of hospitalization in integrated form and stratified this way to avoid that it progresses to situations that cause the death or leave irreversible sequels since in the central nervous system the time it is a factor critical for the treatment of this events.

  20. Shielding analysis of the advanced voloxidation process

    Energy Technology Data Exchange (ETDEWEB)

    Park, Chang Je; Park, J. J.; Lee, J. W.; Shin, J. M.; Park, G. I.; Song, K. C

    2008-09-15

    This report deals describes how much a shielding benefit can be obtained by the Advanced Voloxidation process. The calculation was performed with the MCNPX code and a simple problem was modeled with a spent fuel source which was surrounded by a concrete wall. The source terms were estimated with the ORIGEN-ARP code and the gamma spectrum and the neutron spectrum were also obtained. The thickness of the concrete wall was estimated before and after the voloxidation process. From the results, the gamma spectrum after the voloxidation process was estimated as a 67% reduction compared with that of before the voloxidation process due to the removal of several gamma emission elements such as cesium and rubidium. The MCNPX calculations provided that the thickness of the general concrete wall could be reduced by 12% after the voloxidation process. And the heavy concrete wall provided a 28% reduction in the shielding of the source term after the voloxidation process. This can be explained in that there lots of gamma emission isotopes still exist after the advanced voloxidation process such as Pu-241, Y-90, and Sr-90 which are independent of the voloxidation process.

  1. Advancing the Assessment of Dynamic Psychological Processes.

    Science.gov (United States)

    Wright, Aidan G C; Hopwood, Christopher J

    2016-08-01

    Most commonly used clinical assessment tools cannot fully capture the dynamic psychological processes often hypothesized as core mechanisms of psychopathology and psychotherapy. There is therefore a gap between our theories of problems and interventions for those problems and the tools we use to understand clients. The purpose of this special issue is to connect theory about clinical dynamics to practice by focusing on methods for collecting dynamic data, statistical models for analyzing dynamic data, and conceptual schemes for implementing dynamic data in applied settings. In this introductory article, we argue for the importance of assessing dynamic processes, highlight recent advances in assessment science that enable their measurement, review challenges in using these advances in applied practice, and adumbrate the articles in this issue.

  2. Advanced parallel processing with supercomputer architectures

    International Nuclear Information System (INIS)

    Hwang, K.

    1987-01-01

    This paper investigates advanced parallel processing techniques and innovative hardware/software architectures that can be applied to boost the performance of supercomputers. Critical issues on architectural choices, parallel languages, compiling techniques, resource management, concurrency control, programming environment, parallel algorithms, and performance enhancement methods are examined and the best answers are presented. The authors cover advanced processing techniques suitable for supercomputers, high-end mainframes, minisupers, and array processors. The coverage emphasizes vectorization, multitasking, multiprocessing, and distributed computing. In order to achieve these operation modes, parallel languages, smart compilers, synchronization mechanisms, load balancing methods, mapping parallel algorithms, operating system functions, application library, and multidiscipline interactions are investigated to ensure high performance. At the end, they assess the potentials of optical and neural technologies for developing future supercomputers

  3. Hydrothermal liquefaction of barley straw to bio-crude oil

    DEFF Research Database (Denmark)

    Zhu, Zhe; Rosendahl, Lasse; Toor, Saqib

    2015-01-01

    Hydrothermal liquefaction (HTL) of barley straw with K2CO3 at different temperatures (280–400 C) was conducted and compared to optimize its process conditions; the aqueous phase as a co-product from this process was recycled to explore the feasibility of implementing wastewater reuse for bio...

  4. Japan`s sunshine project. 17.. 1992 annual summary of coal liquefaction and gasification

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    This report describes the achievement of coal liquefaction and gasification technology development in the Sunshine Project for FY 1992. It presents the research and development of coal liquefaction which includes studies on reaction mechanism of coal liquefaction and catalysts for coal liquefaction, the research and development of coal gasification technologies which includes studies on gasification characteristics of various coals and improvement of coal gasification efficiency, the development of bituminous coal liquefaction which includes engineering, construction and operation of a bituminous coal liquefaction pilot plant and research by a process supporting unit (PSU), the development of brown coal liquefaction which includes research on brown coal liquefaction with a pilot plant and development of techniques for upgrading coal oil from brown coal, the development of common base technologies which includes development of slurry letdown valves and study on upgrading technology of coal-derived distillates, the development of coal-based hydrogen production technology with a pilot plant, the development of technology for entrained flow coal gasification, the assessment of coal hydrogasification, and the international co-operation. 4 refs., 125 figs., 39 tabs.

  5. Human factors challenges for advanced process control

    International Nuclear Information System (INIS)

    Stubler, W.F.; O'Hara, J..M.

    1996-01-01

    New human-system interface technologies provide opportunities for improving operator and plant performance. However, if these technologies are not properly implemented, they may introduce new challenges to performance and safety. This paper reports the results from a survey of human factors considerations that arise in the implementation of advanced human-system interface technologies in process control and other complex systems. General trends were identified for several areas based on a review of technical literature and a combination of interviews and site visits with process control organizations. Human factors considerations are discussed for two of these areas, automation and controls

  6. ADVANCED OXIDATION PROCESSES (AOX) TEXTILE WASTEWATER

    OpenAIRE

    Salas C., G.

    2014-01-01

    Advanced Oxidation Processes (AOX) are based on the in situ generation of hydroxyradicals (·OH), which have a high oxidation potential. In the case of Fenton processes !he generation of hydroxy radicals takes place by the combination of an oxidation agent (H202) with a catalyst (Fe(II)). These radicals are not selective and they react very fast with the organic matter,being able to oxidize a high variety of organic compounds. This property allows the degradation of pollutants into more biodeg...

  7. Liquefaction resistance of calcareous sands

    International Nuclear Information System (INIS)

    Sandoval Vallejo, Eimar

    2012-01-01

    Calcareous sands are unique in terms of their origin, mineralogy, shape, fragility and intra particle porosity. This article presents results from an experimental program carried out to study the liquefaction resistance of a calcareous sand retrieved from Cabo Rojo at Puerto Rico. The experimental program included mineralogical characterization, index properties, and undrained cyclic triaxial tests on isotropically consolidated reconstituted samples. Due to the large variation in the calcareous sand properties, results are compared with previous researches carried out on other calcareous sands around the world. Results showed a wide range in the liquefaction resistance of the studied calcareous sands. Cabo Rojo sand experienced greater liquefaction resistance than most of the calcareous sands used for comparison. Important differences in the excess pore pressure generation characteristics were also found.

  8. Kinetics of coal liquefaction during heating-up and isothermal stages

    Energy Technology Data Exchange (ETDEWEB)

    Xian Li; Haoquan Hu; Shengwei Zhu; Shuxun Hu; Bo Wu; Meng Meng [Dalian University of Technology, Dalian (China). Institute of Coal Chemical Engineering

    2008-04-15

    Direct liquefaction of Shenhua bituminous coal was carried out in a 500 ml autoclave with iron catalyst and coal liquefaction cycle-oil as solvent at initial hydrogen of 8.0 MPa, residence time of 0-90 min. To investigate the liquefaction kinetics, a model for heating-up and isothermal stages was developed to estimate the rate constants of both stages. In the model, the coal was divided into three parts, easy reactive part, hard reactive part and unreactive part, and four kinetic constants were used to describe the reaction mechanism. The results showed that the model is valid for both heating-up and isothermal stages of liquefaction perfectly. The rate-controlled process for coal liquefaction is the reaction of preasphaltene plus asphaltene (PAA) to oil plus gas (O + G). The upper-limiting conversion of isothermal stage was estimated by the kinetic calculation. 21 refs., 4 figs., 4 tabs.

  9. The sequence of sediment behaviour during wave-induced liquefaction

    DEFF Research Database (Denmark)

    Sumer, B. Mutlu; Hatipoglu, Figen; Fredsøe, Jørgen

    2006-01-01

    to be in agreement with recent centrifuge wave-tank experiments. As for the final stage of the sequence of processes (formation of ripples), the ripple steepness (normalized with the angle of repose) for sediment with liquefaction history is found to be the same as that in sediment with no liquefaction history.......This paper presents the results of an experimental investigation of the complete sequence of sediment behaviour beneath progressive waves. The sediment was silty with d(50) = 0.060 mm. Two kinds of measurements were carried out: pore-water pressure measurements (across the sediment depth...... of liquefaction and compaction fronts in the sediment and (iii) the characteristics of the orbital motion of the liquefied sediment including the motion of the interface between the water body and the sediment. The ranges of the various quantities in the tests were: wave height, H = 9-17 cm, wave period, T = 1...

  10. Case studies on direct liquefaction of low rank Wyoming coal

    Energy Technology Data Exchange (ETDEWEB)

    Adler, P.; Kramer, S.J.; Poddar, S.K. [Bechtel Corp., San Francisco, CA (United States)

    1995-12-31

    Previous Studies have developed process designs, costs, and economics for the direct liquefaction of Illinois No. 6 and Wyoming Black Thunder coals at mine-mouth plants. This investigation concerns two case studies related to the liquefaction of Wyoming Black Thunder coal. The first study showed that reducing the coal liquefaction reactor design pressure from 3300 to 1000 psig could reduce the crude oil equivalent price by 2.1 $/bbl provided equivalent performing catalysts can be developed. The second one showed that incentives may exist for locating a facility that liquifies Wyoming coal on the Gulf Coast because of lower construction costs and higher labor productivity. These incentives are dependent upon the relative values of the cost of shipping the coal to the Gulf Coast and the increased product revenues that may be obtained by distributing the liquid products among several nearby refineries.

  11. Hydrothermal Liquefaction Treatment Preliminary Hazard Analysis Report

    Energy Technology Data Exchange (ETDEWEB)

    Lowry, Peter P.; Wagner, Katie A.

    2015-08-31

    A preliminary hazard assessment was completed during February 2015 to evaluate the conceptual design of the modular hydrothermal liquefaction treatment system. The hazard assessment was performed in 2 stages. An initial assessment utilizing Hazard Identification and Preliminary Hazards Analysis (PHA) techniques identified areas with significant or unique hazards (process safety-related hazards) that fall outside of the normal operating envelope of PNNL and warranted additional analysis. The subsequent assessment was based on a qualitative What-If analysis. This analysis was augmented, as necessary, by additional quantitative analysis for scenarios involving a release of hazardous material or energy with the potential for affecting the public.

  12. Recent advances in nonlinear speech processing

    CERN Document Server

    Faundez-Zanuy, Marcos; Esposito, Antonietta; Cordasco, Gennaro; Drugman, Thomas; Solé-Casals, Jordi; Morabito, Francesco

    2016-01-01

    This book presents recent advances in nonlinear speech processing beyond nonlinear techniques. It shows that it exploits heuristic and psychological models of human interaction in order to succeed in the implementations of socially believable VUIs and applications for human health and psychological support. The book takes into account the multifunctional role of speech and what is “outside of the box” (see Björn Schuller’s foreword). To this aim, the book is organized in 6 sections, each collecting a small number of short chapters reporting advances “inside” and “outside” themes related to nonlinear speech research. The themes emphasize theoretical and practical issues for modelling socially believable speech interfaces, ranging from efforts to capture the nature of sound changes in linguistic contexts and the timing nature of speech; labors to identify and detect speech features that help in the diagnosis of psychological and neuronal disease, attempts to improve the effectiveness and performa...

  13. Transport fuels from two-stage coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Benito, A.; Cebolla, V.; Fernandez, I.; Martinez, M.T.; Miranda, J.L.; Oelert, H.; Prado, J.G. (Instituto de Carboquimica CSIC, Zaragoza (Spain))

    1994-03-01

    Four Spanish lignites and their vitrinite concentrates were evaluated for coal liquefaction. Correlationships between the content of vitrinite and conversion in direct liquefaction were observed for the lignites but not for the vitrinite concentrates. The most reactive of the four coals was processed in two-stage liquefaction at a higher scale. First-stage coal liquefaction was carried out in a continuous unit at Clausthal University at a temperature of 400[degree]C at 20 MPa hydrogen pressure and with anthracene oil as a solvent. The coal conversion obtained was 75.41% being 3.79% gases, 2.58% primary condensate and 69.04% heavy liquids. A hydroprocessing unit was built at the Instituto de Carboquimica for the second-stage coal liquefaction. Whole and deasphalted liquids from the first-stage liquefaction were processed at 450[degree]C and 10 MPa hydrogen pressure, with two commercial catalysts: Harshaw HT-400E (Co-Mo/Al[sub 2]O[sub 3]) and HT-500E (Ni-Mo/Al[sub 2]O[sub 3]). The effects of liquid hourly space velocity (LHSV), temperature, gas/liquid ratio and catalyst on the heteroatom liquids, and levels of 5 ppm of nitrogen and 52 ppm of sulphur were reached at 450[degree]C, 10 MPa hydrogen pressure, 0.08 kg H[sub 2]/kg feedstock and with Harshaw HT-500E catalyst. The liquids obtained were hydroprocessed again at 420[degree]C, 10 MPa hydrogen pressure and 0.06 kg H[sub 2]/kg feedstock to hydrogenate the aromatic structures. In these conditions, the aromaticity was reduced considerably, and 39% of naphthas and 35% of kerosene fractions were obtained. 18 refs., 4 figs., 4 tabs.

  14. Advanced Signal Processing for Wireless Multimedia Communications

    Directory of Open Access Journals (Sweden)

    Xiaodong Wang

    2000-01-01

    Full Text Available There is at present a worldwide effort to develop next-generation wireless communication systems. It is envisioned that many of the future wireless systems will incorporate considerable signal-processing intelligence in order to provide advanced services such as multimedia transmission. In general, wireless channels can be very hostile media through which to communicate, due to substantial physical impediments, primarily radio-frequency interference and time-arying nature of the channel. The need of providing universal wireless access at high data-rate (which is the aim of many merging wireless applications presents a major technical challenge, and meeting this challenge necessitates the development of advanced signal processing techniques for multiple-access communications in non-stationary interference-rich environments. In this paper, we present some key advanced signal processing methodologies that have been developed in recent years for interference suppression in wireless networks. We will focus primarily on the problem of jointly suppressing multiple-access interference (MAI and intersymbol interference (ISI, which are the limiting sources of interference for the high data-rate wireless systems being proposed for many emerging application areas, such as wireless multimedia. We first present a signal subspace approach to blind joint suppression of MAI and ISI. We then discuss a powerful iterative technique for joint interference suppression and decoding, so-called Turbo multiuser detection, that is especially useful for wireless multimedia packet communications. We also discuss space-time processing methods that employ multiple antennas for interference rejection and signal enhancement. Finally, we touch briefly on the problems of suppressing narrowband interference and impulsive ambient noise, two other sources of radio-frequency interference present in wireless multimedia networks.

  15. Direct liquefaction proof-of-concept facility

    Energy Technology Data Exchange (ETDEWEB)

    Alfred G. Comolli; Peizheng Zhou; HTI Staff

    2000-01-01

    The main objective of the U.S. DOE, Office of Fossil Energy, is to ensure the US a secure energy supply at an affordable price. An integral part of this program was the demonstration of fully developed coal liquefaction processes that could be implemented if market and supply considerations so required, Demonstration of the technology, even if not commercialized, provides a security factor for the country if it is known that the coal to liquid processes are proven and readily available. Direct liquefaction breaks down and rearranges complex hydrocarbon molecules from coal, adds hydrogen, and cracks the large molecules to those in the fuel range, removes hetero-atoms and gives the liquids characteristics comparable to petroleum derived fuels. The current processes being scaled and demonstrated are based on two reactor stages that increase conversion efficiency and improve quality by providing the flexibility to adjust process conditions to accommodate favorable reactions. The first stage conditions promote hydrogenation and some oxygen, sulfur and nitrogen removal. The second stage hydrocracks and speeds the conversion to liquids while removing the remaining sulfur and nitrogen. A third hydrotreatment stage can be used to upgrade the liquids to clean specification fuels.

  16. Advances in Packaging Methods, Processes and Systems

    Directory of Open Access Journals (Sweden)

    Nitaigour Premchand Mahalik

    2014-10-01

    Full Text Available The food processing and packaging industry is becoming a multi-trillion dollar global business. The reason is that the recent increase in incomes in traditionally less economically developed countries has led to a rise in standards of living that includes a significantly higher consumption of packaged foods. As a result, food safety guidelines have been more stringent than ever. At the same time, the number of research and educational institutions—that is, the number of potential researchers and stakeholders—has increased in the recent past. This paper reviews recent developments in food processing and packaging (FPP, keeping in view the aforementioned advancements and bearing in mind that FPP is an interdisciplinary area in that materials, safety, systems, regulation, and supply chains play vital roles. In particular, the review covers processing and packaging principles, standards, interfaces, techniques, methods, and state-of-the-art technologies that are currently in use or in development. Recent advances such as smart packaging, non-destructive inspection methods, printing techniques, application of robotics and machineries, automation architecture, software systems and interfaces are reviewed.

  17. Survey on development of brown coal liquefaction techniques; Kattan ekika gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1980-09-01

    Described herein are results of literature survey on brown coal liquefaction reactions and elementary techniques. Liquefaction of brown coal in the presence of CO and steam, or CO, H{sub 2} and steam has been investigated. It is not clear by the literature survey whether it is superior to the normal process which uses hydrogen. Brown coal contains moisture at high contents, and the drying techniques are necessary to be developed for its liquefaction. The future coal liquefaction plant will be much larger than the past one, and there are a number of problems to be solved, such as those involved in the designs of large-sized high-pressure slurry pumps, heat exchangers and preheaters. It is also necessary to develop the materials of and production techniques for large reactors which are serviceable under severe conditions. The solid-liquid separation for liquefaction products involves a number of the elementary techniques characteristic of coal liquefaction processes, and needs many technological developments. The one-stage brown coal liquefaction process is compared with the two-stage process for the secondary hydrogenation of SCR, but no clear conclusions are reached. (NEDO)

  18. Fundamental studies of coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    1995-01-01

    The authors have examined the pyrolysis of Argonne samples of Wyodak and Illinois No. 6 coal in argon, undecane, Tetralin, and water. The effects of the pyrolysis on individual particles of coal were monitored visually in a cell with diamond windows capable of operation to temperature and pressures in excess of 500{degrees}C and 3000 psi. The changes in the particles from ambient to 460{degrees}C were recorded in real time on video tape, and images were then taken from the tape record and analyzed. The study showed that in argon both coals developed tars at 350{degrees}-370{degrees}C. The tars then quickly evaporated, leaving core particles remarkably similar in size and shape to the initial particles. These observations suggest that coal does not melt nor become fully liquid when heated. Nor does the softened coal undergo crosslinking to generate coke. Rather the simple loss of volatiles leaves behind the core residue as coke. Contrary to the common view, there appears to be no link between the bond-breaking processes yielding tar and the interaction of the coal with H-donors leading to liquefaction. Water as a medium was surprising in its effect. Both coals began to shrink at 300{degrees}-350{degrees}C, with the effect appearing to be more of an erosion rather than a uniform loss of substance as seen in Tetralin. The Wyodak continued to shrink to 460{degrees}C to about half its initial size. With the Illinois No. 6 coal, however, the process reversed at around 420{degrees}C, and the particles appeared to grow with the evolution of a tar, continuing to 460{degrees}C. The authors submit that this final observation is evidence for hydrothermal synthesis of hydrocarbons at these conditions.

  19. Advanced monitoring with complex stream processing

    CERN Multimedia

    CERN. Geneva

    2015-01-01

    Making sense of metrics and logs for service monitoring can be a complicated task. Valuable information is normally scattered across several streams of monitoring data, requiring aggregation, correlation and time-based analysis to promptly detect problems and failures. This presentations shows a solution which is used to support the advanced monitoring of the messaging services provided by the IT Department. It uses Esper, an open-source software product for Complex Event Processing (CEP), that analyses series of events for deriving conclusions from them.

  20. Summary of FY 1980 results of Sunshine Project. Development of coal liquefaction techniques; 1980 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho. Sunshine keikaku itaku kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-03-01

    This report summarizes the results of the 3 R and D themes for coal liquefaction techniques, pursued by the Sunshine Project; (1) development of solvent extraction type liquefaction plant, and brown coal liquefaction technique R and D demonstration surveys, (2) development of solvolysis type liquefaction plant, and (3) development of direct hydrogenation type liquefaction plant. For the theme (1), the 1 T/D test plant, solid/liquid separator and small-size continuous settlement separator are constructed, and partly completed. The elementary studies include solvent extraction type liquefaction process, materials for coal liquefaction plant and solid/liquid separation. Australia's Victoria brown coal and Chinese coal are studied to clarify the possible problems involved in liquefaction of these coal species for commercialization of the liquefaction techniques in the early stage. The elementary techniques studied include dehydration of brown coal, milling at high temperature in oil, de-ashing, and secondary and primary hydrogenation. For the theme (2), the 1 T/D plant is inspected and maintained to clarify the problems involved in the continuous operation, revamped and repaired as necessary, given preventive maintenance, and tested for operability confirmation. The elementary studies include solvolysis type liquefaction process, scale-up, hydrogenation plant for solvolysis pitch. For the item (3), the 2.4 T/D test plant is constructed, and the elementary studies are conducted, for, e.g., liquefaction reactions in the presence of an iron-based catalyst. (NEDO)

  1. Summary of FY 1980 results of Sunshine Project. Development of coal liquefaction techniques; 1980 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho. Sunshine keikaku itaku kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-03-01

    This report summarizes the results of the 3 R and D themes for coal liquefaction techniques, pursued by the Sunshine Project; (1) development of solvent extraction type liquefaction plant, and brown coal liquefaction technique R and D demonstration surveys, (2) development of solvolysis type liquefaction plant, and (3) development of direct hydrogenation type liquefaction plant. For the theme (1), the 1 T/D test plant, solid/liquid separator and small-size continuous settlement separator are constructed, and partly completed. The elementary studies include solvent extraction type liquefaction process, materials for coal liquefaction plant and solid/liquid separation. Australia's Victoria brown coal and Chinese coal are studied to clarify the possible problems involved in liquefaction of these coal species for commercialization of the liquefaction techniques in the early stage. The elementary techniques studied include dehydration of brown coal, milling at high temperature in oil, de-ashing, and secondary and primary hydrogenation. For the theme (2), the 1 T/D plant is inspected and maintained to clarify the problems involved in the continuous operation, revamped and repaired as necessary, given preventive maintenance, and tested for operability confirmation. The elementary studies include solvolysis type liquefaction process, scale-up, hydrogenation plant for solvolysis pitch. For the item (3), the 2.4 T/D test plant is constructed, and the elementary studies are conducted, for, e.g., liquefaction reactions in the presence of an iron-based catalyst. (NEDO)

  2. EARTHQUAKE INDUCED LIQUEFACTION ANALYSIS OF

    African Journals Online (AJOL)

    liquefaction analysis of Tendaho earth-fill dam, which is part ... sugar cane plantation in an area of 60,000 hectares. The project .... The model is prepared using the QUAKE/W program for the ..... Geo-slope International, Ltd., Canada. Dynamic ...

  3. The making of Andersen’s liquefaction chart

    DEFF Research Database (Denmark)

    Sabaliauskas, Tomas; Ibsen, Lars Bo

    Andersen’s chart (Andersen & Berre, 1999) is a graphical method of observing cyclic soil response. It allows observing soil response to various stress amplitudes that can lead to liquefaction, excess plastic deformation stabilizing soil response.The process of obtaining the original chart has been...

  4. Development of advanced spent fuel management process. System analysis of advanced spent fuel management process

    International Nuclear Information System (INIS)

    Ro, S.G.; Kang, D.S.; Seo, C.S.; Lee, H.H.; Shin, Y.J.; Park, S.W.

    1999-03-01

    The system analysis of an advanced spent fuel management process to establish a non-proliferation model for the long-term spent fuel management is performed by comparing the several dry processes, such as a salt transport process, a lithium process, the IFR process developed in America, and DDP developed in Russia. In our system analysis, the non-proliferation concept is focused on the separation factor between uranium and plutonium and decontamination factors of products in each process, and the non-proliferation model for the long-term spent fuel management has finally been introduced. (Author). 29 refs., 17 tabs., 12 figs

  5. Report for fiscal 1995 by basic liquefaction technology subcommittee; 1995 nendo ekika kiban gijutsu bukai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Delivered at the 1st meeting are a report on the fiscal 1995 research plan and an interim report, involving the use of coal-derived oils, research on refining technology using a PDU (process developing unit), reforming technology and petroleum blending technology for coal-derived oils, development of new reforming catalysts, technology of heterocompound separation, and the development of applications. Reported in relation with the development of environmentally friendly coal liquefaction technology are the study of coal liquefaction conditions, study of the upgrading of basic liquefaction techniques for the improvement and rationalization of the liquefaction process, and a project of liquefaction technology internationalization. A report is also given on a liquefaction catalyst study meeting. At the 2nd meeting, reports are delivered on the development of environmentally friendly coal liquefaction technology, including a briefing on the situation in general, designing of highly active catalysts, elucidation of the mechanism of emergence of activity, achievement of the marginal yield of coal-derived oils, and the properties of catalyst attached to coal. Delivered in relation with the use of coal-derived oils and technology for their refining are a briefing on the situation in general and reports on the blockup to occur in the naphtha fraction process and measures to counter the problem, control of the metamorphosis of active metals in reaction, heterocompound separation technology, and the development of applications. (NEDO)

  6. Development of advanced spent fuel management process

    International Nuclear Information System (INIS)

    Ro, Seung Gy; Shin, Y. J.; Do, J. B.; You, G. S.; Seo, J. S.; Lee, H. G.

    1998-03-01

    This study is to develop an advanced spent fuel management process for countries which have not yet decided a back-end nuclear fuel cycle policy. The aims of this process development based on the pyroreduction technology of PWR spent fuels with molten lithium, are to reduce the storage volume by a quarter and to reduce the storage cooling load in half by the preferential removal of highly radioactive decay-heat elements such as Cs-137 and Sr-90 only. From the experimental results which confirm the feasibility of metallization technology, it is concluded that there are no problems in aspects of reaction kinetics and equilibrium. However, the operating performance test of each equipment on an engineering scale still remain and will be conducted in 1999. (author). 21 refs., 45 tabs., 119 figs

  7. Development of advanced spent fuel management process

    International Nuclear Information System (INIS)

    Park, Seong Won; Shin, Y. J.; Cho, S. H.

    2004-03-01

    The research on spent fuel management focuses on the maximization of the disposal efficiency by a volume reduction, the improvement of the environmental friendliness by the partitioning and transmutation of the long lived nuclides, and the recycling of the spent fuel for an efficient utilization of the uranium source. In the second phase which started in 2001, the performance test of the advanced spent fuel management process consisting of voloxidation, reduction of spent fuel and the lithium recovery process has been completed successfully on a laboratory scale. The world-premier spent fuel reduction hot test of a 5 kgHM/batch has been performed successfully by joint research with Russia and the valuable data on the actinides and FPs material balance and the characteristics of the metal product were obtained with experience to help design an engineering scale reduction system. The electrolytic reduction technology which integrates uranium oxide reduction in a molten LiCl-Li 2 O system and Li 2 O electrolysis is developed and a unique reaction system is also devised. Design data such as the treatment capacity, current density and mass transfer behavior obtained from the performance test of a 5 kgU/batch electrolytic reduction system pave the way for the third phase of the hot cell demonstration of the advanced spent fuel management technology

  8. Economically viable large-scale hydrogen liquefaction

    Science.gov (United States)

    Cardella, U.; Decker, L.; Klein, H.

    2017-02-01

    The liquid hydrogen demand, particularly driven by clean energy applications, will rise in the near future. As industrial large scale liquefiers will play a major role within the hydrogen supply chain, production capacity will have to increase by a multiple of today’s typical sizes. The main goal is to reduce the total cost of ownership for these plants by increasing energy efficiency with innovative and simple process designs, optimized in capital expenditure. New concepts must ensure a manageable plant complexity and flexible operability. In the phase of process development and selection, a dimensioning of key equipment for large scale liquefiers, such as turbines and compressors as well as heat exchangers, must be performed iteratively to ensure technological feasibility and maturity. Further critical aspects related to hydrogen liquefaction, e.g. fluid properties, ortho-para hydrogen conversion, and coldbox configuration, must be analysed in detail. This paper provides an overview on the approach, challenges and preliminary results in the development of efficient as well as economically viable concepts for large-scale hydrogen liquefaction.

  9. Radiation Processing of Advanced Composite Materials

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Phil Hyun; Jeun, Joonpyo; Nho, Young Chang [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2008-04-15

    Advanced composites, such as carbon-fiber-reinforced plastics, are being used widely for many applications. Carbon fiber/epoxies composites have attracted special attention from the aircraft, aerospace, marine engineering, sporting goods and transportation industries, because they have useful mechanical properties including high strength-to-weight and stiffness-to-weight ratios, a corrosion resistant, impact and damage tolerance characteristics and wear properties. Thermal curing has been the dominant industrial process for advanced composites until now, however, a radiation curing process using UV, microwave x-ray, electron-beam(E-beam) and {gamma}-ray has emerged as a better alternative in recent years. These processes are compatible with the manufacturing of composites using traditional fabrication methods including a filament/tape winding, pultrusion, resin transfer moulding and hand lay-up. In this study, E-beam curable carbon fiber/epoxy composites were manufactured, and their mechanical properties were investigated. Two epoxy resins (bisphenol-A, bisphenol-F) containing photo-initiators (tri aryl sulfonium hexafluorophosphate, tri aryl sulfonium hexafluoroantimonate) were used as a matrix and a 4H-satin carbon woven fabric was used as a reinforcement. And then an electron beam irradiated the composites up to 200 kGy in a vacuum and an inert atmosphere. The cure cycle was optimized and the properties of composites were evaluated and analyzed via a differential scanning calorimetry, scanning electron microscopy, sol-gel extractions, FT-NIR, universal test machine, and an impact tester. The gel content, glass transition temperature and mechanical strength of the irradiated composites were increased with an increasing radiation dose.

  10. Advanced Technology Composite Fuselage - Materials and Processes

    Science.gov (United States)

    Scholz, D. B.; Dost, E. F.; Flynn, B. W.; Ilcewicz, L. B.; Nelson, K. M.; Sawicki, A. J.; Walker, T. H.; Lakes, R. S.

    1997-01-01

    The goal of Boeing's Advanced Technology Composite Aircraft Structures (ATCAS) program was to develop the technology required for cost and weight efficient use of composite materials in transport fuselage structure. This contractor report describes results of material and process selection, development, and characterization activities. Carbon fiber reinforced epoxy was chosen for fuselage skins and stiffening elements and for passenger and cargo floor structures. The automated fiber placement (AFP) process was selected for fabrication of monolithic and sandwich skin panels. Circumferential frames and window frames were braided and resin transfer molded (RTM'd). Pultrusion was selected for fabrication of floor beams and constant section stiffening elements. Drape forming was chosen for stringers and other stiffening elements. Significant development efforts were expended on the AFP, braiding, and RTM processes. Sandwich core materials and core edge close-out design concepts were evaluated. Autoclave cure processes were developed for stiffened skin and sandwich structures. The stiffness, strength, notch sensitivity, and bearing/bypass properties of fiber-placed skin materials and braided/RTM'd circumferential frame materials were characterized. The strength and durability of cocured and cobonded joints were evaluated. Impact damage resistance of stiffened skin and sandwich structures typical of fuselage panels was investigated. Fluid penetration and migration mechanisms for sandwich panels were studied.

  11. Development of Advanced Spent Fuel Management Process

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Chung Seok; Choi, I. K.; Kwon, S. G. (and others)

    2007-06-15

    As a part of research efforts to develop an advanced spent fuel management process, this project focused on the electrochemical reduction technology which can replace the original Li reduction technology of ANL, and we have successfully built a 20 kgHM/batch scale demonstration system. The performance tests of the system in the ACPF hot cell showed more than a 99% reduction yield of SIMFUEL, a current density of 100 mA/cm{sup 2} and a current efficiency of 80%. For an optimization of the process, the prevention of a voltage drop in an integrated cathode, a minimization of the anodic effect and an improvement of the hot cell operability by a modulation and simplization of the unit apparatuses were achieved. Basic research using a bench-scale system was also carried out by focusing on a measurement of the electrochemical reduction rate of the surrogates, an elucidation of the reaction mechanism, collecting data on the partition coefficients of the major nuclides, quantitative measurement of mass transfer rates and diffusion coefficients of oxygen and metal ions in molten salts. When compared to the PYROX process of INL, the electrochemical reduction system developed in this project has comparative advantages in its application of a flexible reaction mechanism, relatively short reaction times and increased process yields.

  12. Development of Advanced Spent Fuel Management Process

    International Nuclear Information System (INIS)

    Seo, Chung Seok; Choi, I. K.; Kwon, S. G.

    2007-06-01

    As a part of research efforts to develop an advanced spent fuel management process, this project focused on the electrochemical reduction technology which can replace the original Li reduction technology of ANL, and we have successfully built a 20 kgHM/batch scale demonstration system. The performance tests of the system in the ACPF hot cell showed more than a 99% reduction yield of SIMFUEL, a current density of 100 mA/cm 2 and a current efficiency of 80%. For an optimization of the process, the prevention of a voltage drop in an integrated cathode, a minimization of the anodic effect and an improvement of the hot cell operability by a modulation and simplization of the unit apparatuses were achieved. Basic research using a bench-scale system was also carried out by focusing on a measurement of the electrochemical reduction rate of the surrogates, an elucidation of the reaction mechanism, collecting data on the partition coefficients of the major nuclides, quantitative measurement of mass transfer rates and diffusion coefficients of oxygen and metal ions in molten salts. When compared to the PYROX process of INL, the electrochemical reduction system developed in this project has comparative advantages in its application of a flexible reaction mechanism, relatively short reaction times and increased process yields

  13. Mineral catalysis of oil producing reactions in coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Shridharani, K.G.

    1983-01-01

    This work was concerned primarily with the development of a relatively inexpensive, readily available, high activity catalyst that can be used as a disposable catalyst in coal liquefaction processes. For a fair evaluation of the developmental mineral catalyst (presulfided iron oxide), it was necessary to determine at different stages of this work, whether catalyst inhibition, deactivation or activity was the limiting factor in coal liquefaction catalysis. First, different routes were explored to prepare a high hydrogenation activity, iron-based catalyst. Naphthalene hydrogenation was used as a model reaction to rate the hydrogenation activities of different additives. Presulfiding of iron oxide with H/sub 2/S, under controlled conditions, rendered the highest hydrogenation activity mineral catalyst, which had a hydrogenation activity even greater than that of commercial CoMo/Al/sub 2/O/sub 3/ catalyst sulfided with creosote oil and hydrogen. Sulfiding of CoMo/Al/sub 2/O/sub 3/ catalyst with H/sub 2/S remarkably improved its initial hydrogenation activity. Second, the catalyst inhibition and deactivation during liquefaction were studied. Liquefaction-process solvents contain a number of compounds that can either deactivate or inhibit the hydrogenation activity of a catalyst. Finally, the hydrocracking activity of the presulfided iron oxide catalyst was compared with that of commercial catalysts, CoMo/Al/sub 2/O/sub 3/ and low alumina FCC catalyst.

  14. Liquefaction of ground tire rubber at low temperature.

    Science.gov (United States)

    Cheng, Xiangyun; Song, Pan; Zhao, Xinyu; Peng, Zonglin; Wang, Shifeng

    2018-01-01

    Low-temperature liquefaction has been investigated as a novel method for recycling ground tire rubber (GTR) into liquid using an environmentally benign process. The liquefaction was carried out at different temperatures (140, 160 and 180 °C) over variable time ranges (2-24 h) by blending the GTR with aromatic oil in a range from 0 to 100 parts per hundred rubber (phr). The liquefied GTR was separated into sol (the soluble fraction of rubber which can be extracted with toluene) and gel fractions (the solid fraction obtained after extraction) to evaluate the reclaiming efficiency. It was discovered that the percentage of the sol fraction increased with time, swelling ratio and temperature. Liquefied rubber was obtained with a high sol fraction (68.34 wt%) at 140 °C. Simultaneously, separation of nano-sized carbon black from the rubber networks occurred. The separation of carbon black from the network is the result of significant damage to the cross-linked-network that occurs throughout the liquefaction process. During liquefaction, a competitive reaction between main chain scission and cross-link bond breakage takes place. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. Advanced Color Image Processing and Analysis

    CERN Document Server

    2013-01-01

    This volume does much more than survey modern advanced color processing. Starting with a historical perspective on ways we have classified color, it sets out the latest numerical techniques for analyzing and processing colors, the leading edge in our search to accurately record and print what we see. The human eye perceives only a fraction of available light wavelengths, yet we live in a multicolor world of myriad shining hues. Colors rich in metaphorical associations make us “purple with rage” or “green with envy” and cause us to “see red.” Defining colors has been the work of centuries, culminating in today’s complex mathematical coding that nonetheless remains a work in progress: only recently have we possessed the computing capacity to process the algebraic matrices that reproduce color more accurately. With chapters on dihedral color and image spectrometers, this book provides technicians and researchers with the knowledge they need to grasp the intricacies of today’s color imaging.

  16. Outline of research achievement of fiscal 1983. Development of coal liquefaction technologies; Sekitan ekika gijutsu kaihatsu. 1983 nendo kenkyu seika no gaiyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1983-07-01

    Reported are the results of (1) the development of bituminous coal liquefaction technology, (2) development of brown coal liquefaction technology, (3) experimental fabrication and development of plant equipment and materials therefor, and (4) a survey on coal type selection. The goals of the development are mentioned below. Under Item (1), an optimum liquefaction process and a solid/liquid separation process are to be defined, the effect of iron-based catalysts upon liquefaction reaction is to be elucidated, a technology for constructing a direct hydroliquefaction unit is to be established, and a plant using such a unit is to be developed. Under Item (2), an optimum liquefaction technology is to be established, high in economic efficiency and reliability, by subjecting Australia's Victoria brown coal to the direct liquefaction process. In particular, a new brown coal liquefaction technology is to be established, which will be an organic combination of a novel, raw brown coal slurry dehydration technology, a solvent deashing technology, and the secondary hydrogenation technology, all centering on the basic technology of primary hydrogenation. Under Item (3), reactor materials, accessory materials, slurry pumps, etc., are to be experimentally manufactured and developed further. Under Item (4), data are to be collected on coal resources, coal quality, liquefaction characteristics, etc., during the process of technology development for liquefaction, etc. Furthermore, methods are to be established for the effective utilization of liquefaction products and for their optimum refining. (NEDO)

  17. Cooperative research program in coal liquefaction. Quarterly report, May 1, 1993--October 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, G.P. [ed.

    1994-07-01

    This report summarizes progress in four areas of research under the general heading of Coal Liquefaction. Results of studies concerning the coliquefaction of coal with waste organic polymers or chemical products of these polymers were reported. Secondly, studies of catalytic systems for the production of clean transportation fuels from coal were discussed. Thirdly, investigations of the chemical composition of coals and their dehydrogenated counterparts were presented. These studies were directed toward elucidation of coal liquefaction processes on the chemical level. Finally, analytical methodologies developed for in situ monitoring of coal liquefaction were reported. Techniques utilizing model reactions and methods based on XAFS, ESR, and GC/MS are discussed.

  18. Isolation and characterization of cellulose nanofibers from bamboo using microwave liquefaction combined with chemical treatment and ultrasonication

    Science.gov (United States)

    Jiulong Xie; Chung Hse; Cornelis F. De Hoop; Tingxing Hu; Jinqiu Qi; Todd F. Shupe

    2016-01-01

    Cellulose nanofibers were successfully isolated from bamboo using microwave liquefaction combinedwith chemical treatment and ultrasonic nanofibrillation processes. The microwave liquefaction couldeliminate almost all the lignin in bamboo, resulting in high cellulose content residues within 7 min, andthe cellulose enriched residues could be readily purified by...

  19. Two-stage alkaline hydrothermal liquefaction of wood to biocrude in a continuous bench-scale system

    DEFF Research Database (Denmark)

    Sintamarean, Iulia-Maria; Grigoras, Ionela; Jensen, Claus Uhrenholt

    2017-01-01

    unit. In total, 100 kg of wood paste with 25% dry matter is processed at 400 °C and 30 MPa, demonstrating the usefulness of this two-stage liquefaction strategy. An additional advantage liquefaction of such pretreated wood shows increased biocrude yields with approximately 10% compared to the case...

  20. Safeguardability of advanced spent fuel conditioning process

    Energy Technology Data Exchange (ETDEWEB)

    Li, T. K. (Tien K.); Lee, S. Y. (Sang Yoon); Burr, Tom; Russo, P. A. (Phyllis A.); Menlove, Howard O.; Kim, H. D.; Ko, W. I. (Won Il); Park, S. W.; Park, H. S.

    2004-01-01

    The Advanced Spent Fuel Conditioning Process (ACP) is an electro-metallurgical treatment technique to convert oxide-type spent nuclear fuel into a metallic form. The Korea Atomic Energy Research Institute (KAERI) has been developing this technology since 1977 for the purpose of spent fuel management and is planning to perform a lab-scale demonstration in 2006. By using of this technology, a significant reduction of the volume and heat load of spent fuel is expected, which would lighten the burden of final disposal in terms of disposal size, safety and economics. In the framework of collaboration agreement to develop the safeguards system for the ACP, a joint study on the safeguardability of the ACP technology has been performed by the Los Alamos National Laboratory (LANL) and the KAERI since 2002. In this study, the safeguardability of the ACP technology was examined for the pilot-scale facility. The process and material flows were conceptually designed, and the uncertainties in material accounting were estimated with international target values.

  1. Coal liquefaction still a dream

    Energy Technology Data Exchange (ETDEWEB)

    Overberg, H

    1982-03-19

    Liquefaction of coal is not profitable in West Germany and will not be so far some time to coal. This is true for West German and imported coal. The result may be improved but not changed by combined conversion of coal and top residues of distilleries. These are the main statements of a study carried out by Messrs. Veba Oel AG, Gelsenkirchen, on behalf of the Federal Minister for Research and Technology. The results of the study are presented in 20 volumes.

  2. Exergy analysis of helium liquefaction systems based on modified Claude cycle with two-expanders

    Science.gov (United States)

    Thomas, Rijo Jacob; Ghosh, Parthasarathi; Chowdhury, Kanchan

    2011-06-01

    Large-scale helium liquefaction systems, being energy-intensive, demand judicious selection of process parameters. An effective tool for design and analysis of thermodynamic cycles for these systems is exergy analysis, which is used to study the behavior of a helium liquefaction system based on modified Claude cycle. Parametric evaluation using process simulator Aspen HYSYS® helps to identify the effects of cycle pressure ratio and expander flow fraction on the exergetic efficiency of the liquefaction cycle. The study computes the distribution of losses at different refrigeration stages of the cycle and helps in selecting optimum cycle pressures, operating temperature levels of expanders and mass flow rates through them. Results from the analysis may help evolving guidelines for designing appropriate thermodynamic cycles for practical helium liquefaction systems.

  3. Natural language processing and advanced information management

    Science.gov (United States)

    Hoard, James E.

    1989-01-01

    Integrating diverse information sources and application software in a principled and general manner will require a very capable advanced information management (AIM) system. In particular, such a system will need a comprehensive addressing scheme to locate the material in its docuverse. It will also need a natural language processing (NLP) system of great sophistication. It seems that the NLP system must serve three functions. First, it provides an natural language interface (NLI) for the users. Second, it serves as the core component that understands and makes use of the real-world interpretations (RWIs) contained in the docuverse. Third, it enables the reasoning specialists (RSs) to arrive at conclusions that can be transformed into procedures that will satisfy the users' requests. The best candidate for an intelligent agent that can satisfactorily make use of RSs and transform documents (TDs) appears to be an object oriented data base (OODB). OODBs have, apparently, an inherent capacity to use the large numbers of RSs and TDs that will be required by an AIM system and an inherent capacity to use them in an effective way.

  4. Alkaline hydrothermal liquefaction of swine carcasses to bio-oil

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Ji-Lu, E-mail: triace@163.com; Zhu, Ming-Qiang; Wu, Hai-tang

    2015-09-15

    Highlights: • Swine carcasses can be converted to bio-oil by alkaline hydrothermal liquefaction. • It seems that the use of the bio-oil for heat or CHP is technically suitable. • Some valuable chemicals were found in the bio-oils. • The bio-oil and the solid residue constituted an energy efficiency of 93.63% for the feedstock. • The solid residue can be used as a soil amendment, to sequester C and for preparing activated carbon. - Abstract: It is imperative that swine carcasses are disposed of safely, practically and economically. Alkaline hydrothermal liquefaction of swine carcasses to bio-oil was performed. Firstly, the effects of temperature, reaction time and pH value on the yield of each liquefaction product were determined. Secondly, liquefaction products, including bio-oil and solid residue, were characterized. Finally, the energy recovery ratio (ERR), which was defined as the energy of the resultant products compared to the energy input of the material, was investigated. Our experiment shows that reaction time had certain influence on the yield of liquefaction products, but temperature and pH value had bigger influence on the yield of liquefaction products. Yields of 62.2 wt% bio-oil, having a high heating value of 32.35 MJ/kg and a viscosity of 305cp, and 22 wt% solid residue were realized at a liquefaction temperature of 250 °C, a reaction time of 60 min and a pH value of 9.0. The bio-oil contained up to hundreds of different chemical components that may be classified according to functional groups. Typical compound classes in the bio-oil were hydrocarbons, organic acids, esters, ketones and heterocyclics. The energy recovery ratio (ERR) reached 93.63%. The bio-oil is expected to contribute to fossil fuel replacement in stationary applications, including boilers and furnaces, and upgrading processes for the bio-oil may be used to obtain liquid transport fuels.

  5. Alkaline hydrothermal liquefaction of swine carcasses to bio-oil

    International Nuclear Information System (INIS)

    Zheng, Ji-Lu; Zhu, Ming-Qiang; Wu, Hai-tang

    2015-01-01

    Highlights: • Swine carcasses can be converted to bio-oil by alkaline hydrothermal liquefaction. • It seems that the use of the bio-oil for heat or CHP is technically suitable. • Some valuable chemicals were found in the bio-oils. • The bio-oil and the solid residue constituted an energy efficiency of 93.63% for the feedstock. • The solid residue can be used as a soil amendment, to sequester C and for preparing activated carbon. - Abstract: It is imperative that swine carcasses are disposed of safely, practically and economically. Alkaline hydrothermal liquefaction of swine carcasses to bio-oil was performed. Firstly, the effects of temperature, reaction time and pH value on the yield of each liquefaction product were determined. Secondly, liquefaction products, including bio-oil and solid residue, were characterized. Finally, the energy recovery ratio (ERR), which was defined as the energy of the resultant products compared to the energy input of the material, was investigated. Our experiment shows that reaction time had certain influence on the yield of liquefaction products, but temperature and pH value had bigger influence on the yield of liquefaction products. Yields of 62.2 wt% bio-oil, having a high heating value of 32.35 MJ/kg and a viscosity of 305cp, and 22 wt% solid residue were realized at a liquefaction temperature of 250 °C, a reaction time of 60 min and a pH value of 9.0. The bio-oil contained up to hundreds of different chemical components that may be classified according to functional groups. Typical compound classes in the bio-oil were hydrocarbons, organic acids, esters, ketones and heterocyclics. The energy recovery ratio (ERR) reached 93.63%. The bio-oil is expected to contribute to fossil fuel replacement in stationary applications, including boilers and furnaces, and upgrading processes for the bio-oil may be used to obtain liquid transport fuels

  6. Liquefaction macrophenomena in the great Wenchuan earthquake

    Science.gov (United States)

    Chen, Longwei; Yuan, Xiaoming; Cao, Zhenzhong; Hou, Longqing; Sun, Rui; Dong, Lin; Wang, Weiming; Meng, Fanchao; Chen, Hongjuan

    2009-06-01

    On May 12, 2008 at 14:28, a catastrophic magnitude M s 8.0 earthquake struck the Sichuan Province of China. The epicenter was located at Wenchuan (31.00°N, 103.40°E). Liquefaction macrophenomena and corresponding destruction was observed throughout a vast area of 500 km long and 200 km wide following the earthquake. This paper illustrates the geographic distribution of the liquefaction and the relationship between liquefaction behavior and seismic intensity, and summarizes the liquefaction macrophenomena, including sandboils and waterspouts, ground subsidence, ground fissures etc., and relevant liquefaction features. A brief summary of the structural damage caused by liquefaction is presented and discussed. Based on comparisons with liquefaction phenomena observed in the 1976 Tangshan and 1975 Haicheng earthquakes, preliminary analyses were performed, which revealed some new features of liquefaction behavior and associated issues arising from this event. The site investigation indicated that the spatial non-uniformity of liquefaction distribution was obvious and most of the liquefied sites were located in regions of seismic intensity VIII. However, liquefaction phenomena at ten different sites in regions of seismic intensity VI were also observed for the first time in China mainland. Sandboils and waterspouts ranged from centimeters to tens of meters, with most between 1 m to 3 m. Dramatically high water/sand ejections, e.g., more than 10 m, were observed at four different sites. The sand ejections included silty sand, fine sand, medium sand, course sand and gravel, but the ejected sand amount was less than that in the 1976 Tangshan earthquake. Possible liquefaction of natural gravel soils was observed for the first time in China mainland.

  7. Report for fiscal 1994 by subcommittee on coal liquefaction basic technology; 1994 nendo ekika kiban gijutsu bukai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    This report covers the proceedings of subcommittee meetings. Using PDUs (process development unit), comparison is made between bituminous coal-derived oils (150t/d plant for the Indonesian coal) and brown coal-derived oils (50t/d plant for the Yallourn coal), product quality is improved by a 2-stage refining process, engines are tested, etc., all these demonstration and research efforts intended to win social recognition for coal liquefaction products. Among basic studies, there are the development of technologies for reforming coal-derived oils and for mixing them will petroleum, development of new catalysts for reforming, development of a technology for separating heterocompounds and the like, and the development of their applications. Furthermore, technologies are developed for environmentally friendly coal liquefaction, feasibility of coal liquefaction technology internationalization is deliberated, and technical researches and joint researches are conducted. At the second meeting of the subcommittee, achievements relative to the refining and applications of liquefaction products are presented, including the hydrorefining of naphtha, heating oil, and light oil; development of new catalysts; heterocompound separation technology; and the development of new applications. In relation with the development of environmentally friendly coal liquefaction technologies, studies are presented on liquefaction conditions and on the upgrading of basic technologies of liquefaction. Also referred to are the reports delivered at a meeting on liquefaction catalysts (January 1995). (NEDO)

  8. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, M.; Davis, R.; Jones, S.

    2013-03-01

    This technology pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

  9. Wave liquefaction in soils with clay content

    DEFF Research Database (Denmark)

    Kirca, Özgür; Sumer, B. Mutlu; Fredsøe, Jørgen

    2012-01-01

    The paper presents the results of an experimental study of the influence of clay content (in silt-clay and sand-clay mixtures) on liquefaction beneath progressive waves. The experiments showed that the influence of clay content is very significant. Susceptibility of silt to liquefaction is increa...

  10. Plan for advanced microelectronics processing technology application

    Energy Technology Data Exchange (ETDEWEB)

    Goland, A.N.

    1990-10-01

    The ultimate objective of the tasks described in the research agreement was to identify resources primarily, but not exclusively, within New York State that are available for the development of a Center for Advanced Microelectronics Processing (CAMP). Identification of those resources would enable Brookhaven National Laboratory to prepare a program plan for the CAMP. In order to achieve the stated goal, the principal investigators undertook to meet the key personnel in relevant NYS industrial and academic organizations to discuss the potential for economic development that could accompany such a Center and to gauge the extent of participation that could be expected from each interested party. Integrated of these discussions was to be achieved through a workshop convened in the summer of 1990. The culmination of this workshop was to be a report (the final report) outlining a plan for implementing a Center in the state. As events unfolded, it became possible to identify the elements of a major center for x-ray lithography on Lone Island at Brookhaven National Laboratory. The principal investigators were than advised to substitute a working document based upon that concept in place of a report based upon the more general CAMP workshop originally envisioned. Following that suggestion from the New York State Science and Technology Foundation, the principals established a working group consisting of representatives of the Grumman Corporation, Columbia University, the State University of New York at Stony Brook, and Brookhaven National Laboratory. Regular meetings and additional communications between these collaborators have produced a preproposal that constitutes the main body of the final report required by the contract. Other components of this final report include the interim report and a brief description of the activities which followed the establishment of the X-ray Lithography Center working group.

  11. Subtask 3.3 - Feasibility of Direct Coal Liquefaction in the Modern Economic Climate

    Energy Technology Data Exchange (ETDEWEB)

    Benjamin Oster; Joshua Strege; Marc Kurz; Anthony Snyder; Melanie Jensen

    2009-06-15

    Coal liquefaction provides an alternative to petroleum for the production of liquid hydrocarbon-based fuels. There are two main processes to liquefy coal: direct coal liquefaction (DCL) and indirect coal liquefaction (ICL). Because ICL has been demonstrated to a greater extent than DCL, ICL may be viewed as the lower-risk option when it comes to building a coal liquefaction facility. However, a closer look, based on conversion efficiencies and economics, is necessary to determine the optimal technology. This report summarizes historical DCL efforts in the United States, describes the technical challenges facing DCL, overviews Shenhua's current DCL project in China, provides a DCL conceptual cost estimate based on a literature review, and compares the carbon dioxide emissions from a DCL facility to those from an ICL facility.

  12. Thermodynamic design of natural gas liquefaction cycles for offshore application

    Science.gov (United States)

    Chang, Ho-Myung; Lim, Hye Su; Choe, Kun Hyung

    2014-09-01

    A thermodynamic study is carried out for natural gas liquefaction cycles applicable to offshore floating plants, as partial efforts of an ongoing governmental project in Korea. For offshore liquefaction, the most suitable cycle may be different from the on-land LNG processes under operation, because compactness and simple operation are important as well as thermodynamic efficiency. As a turbine-based cycle, closed Claude cycle is proposed to use NG (natural gas) itself as refrigerant. The optimal condition for NG Claude cycle is determined with a process simulator (Aspen HYSYS), and the results are compared with fully-developed C3-MR (propane pre-cooled mixed refrigerant) JT cycles and various N2 (nitrogen) Brayton cycles in terms of efficiency and compactness. The newly proposed NG Claude cycle could be a good candidate for offshore LNG processes.

  13. A case study of liquefaction risk analysis based on the thickness and depth of the liquefaction layer using CPT and electric resistivity data in the Hinode area, Itako City, Ibaraki Prefecture, Japan

    Science.gov (United States)

    Jinguuji, Motoharu; Toprak, Selcuk

    2017-12-01

    The Hinode area of Itako City in Ibaraki Prefecture, Japan, suffered some of the most severe liquefaction damage of any areas in the Great Eastern Japan Earthquake in 2011. This liquefaction damage has been investigated by Itako City, as well as by universities and research institutes in Japan. The National Institute of Advanced Industrial Science and Technology (AIST) has carried out numerous investigations along the Tone River, and in particular, intensive surveys were done in the Hinode area. We have conducted a risk analysis based on the thickness and depth of the liquefaction layer measured using cone penetration testing (CPT) data and electric resistivity data obtained in the Hinode area. The distribution of the risk estimated from CPT at 143 points, and that obtained from analysis of the resistivity survey data, agreed with the distribution of actual damage. We also carried out conventional risk analyses method using the liquefaction resistance factor (FL) and liquefaction potential index (PL) methods with CPT data. The results show high PL values over the entire area, but their distribution did not agree well with actual damage in some parts of the study area. Because the analysis of the thickness and depth of the liquefaction layer, using geophysical prospecting methods, can cover a widespread area, this method will be very useful in investigating liquefaction risk, especially for gas and water pipelines.

  14. Nitrogen expander cycles for large capacity liquefaction of natural gas

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Ho-Myung; Park, Jae Hoon; Gwak, Kyung Hyun [Hong Ik University, Department of Mechanical Engineering, Seoul, 121-791 (Korea, Republic of); Choe, Kun Hyung [Korea Gas Corporation, Incheon, 406-130 (Korea, Republic of)

    2014-01-29

    Thermodynamic study is performed on nitrogen expander cycles for large capacity liquefaction of natural gas. In order to substantially increase the capacity, a Brayton refrigeration cycle with nitrogen expander was recently added to the cold end of the reputable propane pre-cooled mixed-refrigerant (C3-MR) process. Similar modifications with a nitrogen expander cycle are extensively investigated on a variety of cycle configurations. The existing and modified cycles are simulated with commercial process software (Aspen HYSYS) based on selected specifications. The results are compared in terms of thermodynamic efficiency, liquefaction capacity, and estimated size of heat exchangers. The combination of C3-MR with partial regeneration and pre-cooling of nitrogen expander cycle is recommended to have a great potential for high efficiency and large capacity.

  15. Nitrogen expander cycles for large capacity liquefaction of natural gas

    Science.gov (United States)

    Chang, Ho-Myung; Park, Jae Hoon; Gwak, Kyung Hyun; Choe, Kun Hyung

    2014-01-01

    Thermodynamic study is performed on nitrogen expander cycles for large capacity liquefaction of natural gas. In order to substantially increase the capacity, a Brayton refrigeration cycle with nitrogen expander was recently added to the cold end of the reputable propane pre-cooled mixed-refrigerant (C3-MR) process. Similar modifications with a nitrogen expander cycle are extensively investigated on a variety of cycle configurations. The existing and modified cycles are simulated with commercial process software (Aspen HYSYS) based on selected specifications. The results are compared in terms of thermodynamic efficiency, liquefaction capacity, and estimated size of heat exchangers. The combination of C3-MR with partial regeneration and pre-cooling of nitrogen expander cycle is recommended to have a great potential for high efficiency and large capacity.

  16. Nitrogen expander cycles for large capacity liquefaction of natural gas

    International Nuclear Information System (INIS)

    Chang, Ho-Myung; Park, Jae Hoon; Gwak, Kyung Hyun; Choe, Kun Hyung

    2014-01-01

    Thermodynamic study is performed on nitrogen expander cycles for large capacity liquefaction of natural gas. In order to substantially increase the capacity, a Brayton refrigeration cycle with nitrogen expander was recently added to the cold end of the reputable propane pre-cooled mixed-refrigerant (C3-MR) process. Similar modifications with a nitrogen expander cycle are extensively investigated on a variety of cycle configurations. The existing and modified cycles are simulated with commercial process software (Aspen HYSYS) based on selected specifications. The results are compared in terms of thermodynamic efficiency, liquefaction capacity, and estimated size of heat exchangers. The combination of C3-MR with partial regeneration and pre-cooling of nitrogen expander cycle is recommended to have a great potential for high efficiency and large capacity

  17. Advanced Manufacturing Office Clean Water Processing Technologies

    Energy Technology Data Exchange (ETDEWEB)

    None

    2018-03-01

    The DOE Office of Energy Efficiency and Renewable Energy (EERE)’s Advanced Manufacturing Office partners with industry, small business, universities, and other stakeholders to identify and invest in emerging technologies with the potential to create high-quality domestic manufacturing jobs and enhance the global competitiveness of the United States.

  18. The making of Andersen’s liquefaction chart

    OpenAIRE

    Sabaliauskas, Tomas; Ibsen, Lars Bo

    2017-01-01

    Andersen’s chart (Andersen & Berre, 1999) is a graphical method of observing cyclic soil response. It allows observing soil response to various stress amplitudes that can lead to liquefaction, excess plastic deformation stabilizing soil response.The process of obtaining the original chart has been improved. Algorithm based approximation is introduced. Pore pressure dependent ultimate bearing capacity normalization factor is introduced to normalize the chart.

  19. Thermodynamic Analysis on of Skid-Mounted Coal-bed Methane Liquefaction Device using Cryogenic Turbo-Expander

    Science.gov (United States)

    Chen, Shuangtao; Niu, Lu; Zeng, Qiang; Li, Xiaojiang; Lou, Fang; Chen, Liang; Hou, Yu

    2017-12-01

    Coal-bed methane (CBM) reserves are rich in Sinkiang of China, and liquefaction is a critical step for the CBM exploration and utilization. Different from other CBM gas fields in China, CBM distribution in Sinkiang is widespread but scattered, and the pressure, flow-rate and nitrogen content of CBM feed vary significantly. The skid-mounted liquefaction device is suggested as an efficient and economical way to recover methane. Turbo-expander is one of the most important parts which generates the cooling capacity for the cryogenic liquefaction system. Using turbo-expander, more cooling capacity and higher liquefied fraction can be achieved. In this study, skid-mounted CBM liquefaction processes based on Claude cycle are established. Cryogenic turbo-expander with high expansion ratio is employed to improve the efficiency of CBM liquefaction process. The unit power consumption per liquefaction mole flow-rate for CBM feed gas is used as the object function for process optimization, compressor discharge pressure, flow ratio of feed gas to turbo-expander and nitrogen friction are analyzed, and optimum operation range of the liquefaction processes are obtained.

  20. Thermal properties of biopolyol from oil palm fruit fibre (OPFF) using solvolysis liquefaction technique

    Science.gov (United States)

    Kormin, Shaharuddin; Rus, Anika Zafiah M.; Azahari, M. Shafiq M.

    2017-09-01

    Liquefaction is known to be an effective method for converting biomass into a biopolyol. The biomass liquefaction of oil palm fruit waste (PFW) in the presence of liquefaction solvent/polyhydric alcohol (PA): polyethylene glycol 400 (PEG400) using sulfuric acid as catalyst was studied. For all experiments, the liquefaction was conducted at 150°C and atmospheric pressure. The mass ratio of OPFW to liquefaction solvents used in all the experiments was, 1/3. Thermogravimetric analyses (TGA) were used to analyze their biopolyol and residue behaviors. It was found that thermal stability of oil palm mesocarp fibre (PM), oil palm shell (PS) and oil palm kernel (PK) fibre exhibited the first degradation of hard segment at (232, 104, 230°C) and the second degradation of soft segment at (314, 226, 412°C) as compared to PM, PS and PK residue which (229, 102, 227°C) of hard segment and (310, 219, 299°C) of segment, respectively. This behavior of thermal degradation of the hard segment and soft segment of biopolyol was changes after undergo solvolysis liquefaction process. The result analysis showed that the resulting biopolyol and its residue was suitable monomer for polyurethane (PU) synthesis for the production of PU foams.

  1. Japan`s New Sunshine Project. 20. 1995 annual summary of coal liquefaction and gasification

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    The paper described a summary of the 1995 study on coal liquefaction and gasification under the New Sunshine Project. As for coal liquefaction, a study was made of liquefaction characteristics and catalysts of various coals. Also studied were liquefaction conditions for quality improvement of liquefaction products, an evaluation method of quality of coal liquid, and a utilization method of coal liquid. In order to prevent carbonization and realize effective liquefaction, a study was conducted for elucidation of the reaction mechanism of high pressure hydrogenation. In a 150t/d pilot plant using hydrogen transfer hydrogenation solvents, the NEDOL method was studied using various catalysts and kinds of coals. This is a step prior to data acquisition for engineering, actual construction of equipment and operation. A 1t/d process supporting unit is a unit to support it. The unit conducts studies on slurry letdown valves and synthetic iron sulfide catalysts, screening of Chinese coals, etc. As to coal gasification, the paper added to the basic research the combined cycle power generation using entrained flow coal gasification for improvement of thermal efficiency and environmental acceptability and the HYCOL method for hydrogen production. 68 refs., 40 figs.

  2. Earthquake-induced liquefaction in Ferland, Quebec

    International Nuclear Information System (INIS)

    Tuttle, M.; Seeber, L.

    1991-02-01

    Detailed geological investigations are under way at a number of liquefaction sites in the Ferland-Boilleau valley, Quebec, where sand boils, ground cracks and liquefaction-related damages to homes were documented immediately following the Ms=6.0, Mblg=6.5 Saguenay earthquake of November 25, 1988. To date, results obtained from these subsurface investigations of sand boils at two sites in Ferland, located about 26 km from the epicentre, indicate that: the Saguenay earthquake induced liquefaction in late-Pleistocene and Holocene sediments which was recorded as sand dikes, sills and vents in near-surface sediments and soils; earthquake-induced liquefaction and ground failure have occurred in this area at least three times in the past 10,000 years; and, the size and morphology of liquefaction features and the liquefaction susceptibility of source layers of the features may be indicative of the intensity of ground shaking. These preliminary results are very promising and suggest that with continued research liquefaction features will become a useful tool in glaciated terrains, such as northeastern North America, for determining not only the timing and location but also the size of past earthquakes

  3. Advanced Functional Nanomaterials for Biological Processes

    Science.gov (United States)

    2014-01-01

    regeneration based on HA, gold nanoparticles, and graphene. We devised a one-step method in which Au and hydroxyapatite were used as a catalytic system in a...magnetic and spectroscopic properties. They were linked with targeting agents and used for successful Radio- Frequency (RF) driven thermal ablation of...State University (KSU). This work encompassed outstanding research at the nanostructural level and the use of advanced multifunctiona l nanomaterials in

  4. Treeline advance - driving processes and adverse factors

    Directory of Open Access Journals (Sweden)

    F.-K. Holtmeier

    2007-06-01

    Full Text Available The general trend of climatically-driven treeline advance is modified by regional, local and temporal variations. Treelines will not advance in a closed front parallel to the shift of any isotherm to higher elevations and more northern latitudes. The effects of varying topography on site conditions and the after-effects of historical disturbances by natural and anthropogenic factors may override the effects of slightly higher average temperatures. Moreover, the varying treeline-forming species respond in different ways to a changing climate. Forest advance upwards and northwards primarily depends on successful regeneration and survival of young growth rather than on increasing growth rates of mature trees. Every assessment of treeline response to future climate change must consider the effects of local site conditions and feedbacks of in-creasing tree population in modulating the climatically-driven change. Treeline-shift will influence regional and local climates, pedogenesis, plant communities, animal populations and biodiversity as well as having a considerable effect on economic changes in primary production. A better understanding of the functional relationships between the many treeline-relevant factors and treeline dynamics can be achieved only by extensive research at different scales within different climatic regions supported by as many as possible experimental studies in the field together with laboratory and remote sensing techniques.

  5. Proton Testing of Advanced Stellar Compass Digital Processing Unit

    DEFF Research Database (Denmark)

    Thuesen, Gøsta; Denver, Troelz; Jørgensen, Finn E

    1999-01-01

    The Advanced Stellar Compass Digital Processing Unit was radiation tested with 300 MeV protons at Proton Irradiation Facility (PIF), Paul Scherrer Institute, Switzerland.......The Advanced Stellar Compass Digital Processing Unit was radiation tested with 300 MeV protons at Proton Irradiation Facility (PIF), Paul Scherrer Institute, Switzerland....

  6. BASELINE DESIGN/ECONOMICS FOR ADVANCED FISCHER-TROPSCH TECHNOLOGY; FINAL

    International Nuclear Information System (INIS)

    None

    1998-01-01

    Bechtel, along with Amoco as the main subcontractor, developed a Baseline design, two alternative designs, and computer process simulation models for indirect coal liquefaction based on advanced Fischer-Tropsch (F-T) technology for the U. S. Department of Energy's (DOE's) Federal Energy Technology Center (FETC)

  7. Direct liquefaction of low-rank coals under mild conditions

    Energy Technology Data Exchange (ETDEWEB)

    Braun, N.; Rinaldi, R. [Max-Planck-Institut fuer Kohlenforschung, Muelheim an der Ruhr (Germany)

    2013-11-01

    Due to decreasing of petroleum reserves, direct coal liquefaction is attracting renewed interest as an alternative process to produce liquid fuels. The combination of hydrogen peroxide and coal is not a new one. In the early 1980, Vasilakos and Clinton described a procedure for desulfurization by leaching coal with solutions of sulphuric acid/H{sub 2}O{sub 2}. But so far, H{sub 2}O{sub 2} has never been ascribed a major role in coal liquefaction. Herein, we describe a novel approach for liquefying low-rank coals using a solution of H{sub 2}O{sub 2} in presence of a soluble non-transition metal catalyst. (orig.)

  8. Project T.E.A.M. (Technical Education Advancement Modules). Advanced Statistical Process Control.

    Science.gov (United States)

    Dunlap, Dale

    This instructional guide, one of a series developed by the Technical Education Advancement Modules (TEAM) project, is a 20-hour advanced statistical process control (SPC) and quality improvement course designed to develop the following competencies: (1) understanding quality systems; (2) knowing the process; (3) solving quality problems; and (4)…

  9. Survey on peripheral techniques of brown coal liquefaction techniques; Kattan ekika gijutsu ni kansuru shuhen gijutsu no chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1980-09-01

    Described herein are results of survey on brown coal liquefaction techniques and peripheral techniques, centered by COSTEAM process under development in USA, solubilization by alcohol and liquefaction and cracking with the aid of tetrahydroquinoline as the hydrogen donor under development in Japan, and low-temperature carbonization and new promising techniques. The COSTEAM process shows higher reaction rates, conversions and oil yields for brown coal liquefaction than the one using hydrogen gas. Some of the problems involved in this process high viscosity and oxygenated compound content of the product oil. The product oil is acceptable as fuel for power generating plants and can be produced at a moderate cost, but may be unsuitable as vehicle fuel. Coal liquefaction and solubilization processes are mainly represented by those which use hydrogen. The hydrogen cost, which is high, determines the product price. The processes which use alcohol or tetrahydroquinoline are still in the experimental stage. (NEDO)

  10. Advanced coking process control at Rautaruukki Steel

    Energy Technology Data Exchange (ETDEWEB)

    Ritamaki, O.; Luhtaniemi, H. [Rautaruukki Engineering (Finland)

    1999-12-01

    The paper presents the latest development of the Coking Process Management System (CPMS) at Raahe Steel. The latest third generation system is based on the previous system with the addition of fuzzy logic controllers. (The previous second generation system was based simultaneous feed forward and feedback control.) The system development has resulted in balanced coke oven battery heating, decreased variation in process regulation between shifts and increase of process information for operators. The economic results are very satisfactory. 7 figs.

  11. Advances in heuristic signal processing and applications

    CERN Document Server

    Chatterjee, Amitava; Siarry, Patrick

    2013-01-01

    There have been significant developments in the design and application of algorithms for both one-dimensional signal processing and multidimensional signal processing, namely image and video processing, with the recent focus changing from a step-by-step procedure of designing the algorithm first and following up with in-depth analysis and performance improvement to instead applying heuristic-based methods to solve signal-processing problems. In this book the contributing authors demonstrate both general-purpose algorithms and those aimed at solving specialized application problems, with a spec

  12. Histotripsy Liquefaction of Large Hematomas.

    Science.gov (United States)

    Khokhlova, Tatiana D; Monsky, Wayne L; Haider, Yasser A; Maxwell, Adam D; Wang, Yak-Nam; Matula, Thomas J

    2016-07-01

    Intra- and extra-muscular hematomas result from repetitive injury as well as sharp and blunt limb trauma. The clinical consequences can be serious, including debilitating pain and functional deficit. There are currently no short-term treatment options for large hematomas, only lengthy conservative treatment. The goal of this work was to evaluate the feasibility of a high intensity focused ultrasound (HIFU)-based technique, termed histotripsy, for rapid (within a clinically relevant timeframe of 15-20 min) liquefaction of large volume (up to 20 mL) extra-vascular hematomas for subsequent fine-needle aspiration. Experiments were performed using in vitro extravascular hematoma phantoms-fresh bovine blood poured into 50 mL molds and allowed to clot. The resulting phantoms were treated by boiling histotripsy (BH), cavitation histotripsy (CH) or a combination in a degassed water tank under ultrasound guidance. Two different transducers operating at 1 MHz and 1.5 MHz with f-number = 1 were used. The liquefied lysate was aspirated and analyzed by histology and sized in a Coulter Counter. The peak instantaneous power to achieve BH was lower than (at 1.5 MHz) or equal to (at 1 MHz) that which was required to initiate CH. Under the same exposure duration, BH-induced cavities were one and a half to two times larger than the CH-induced cavities, but the CH-induced cavities were more regularly shaped, facilitating easier aspiration. The lysates contained a small amount of debris larger than 70 μm, and 99% of particulates were smaller than 10 μm. A combination treatment of BH (for initial debulking) and CH (for liquefaction of small residual fragments) yielded 20 mL of lysate within 17.5 minutes of treatment and was found to be most optimal for liquefaction of large extravascular hematomas. Copyright © 2016 World Federation for Ultrasound in Medicine & Biology. Published by Elsevier Inc. All rights reserved.

  13. APROMORE : an advanced process model repository

    NARCIS (Netherlands)

    La Rosa, M.; Reijers, H.A.; Aalst, van der W.M.P.; Dijkman, R.M.; Mendling, J.; Dumas, M.; García-Bañuelos, L.

    2011-01-01

    Business process models are becoming available in large numbers due to their widespread use in many industrial applications such as enterprise and quality engineering projects. On the one hand, this raises a challenge as to their proper management: how can it be ensured that the proper process model

  14. Helium refrigeration system for hydrogen liquefaction applications

    Science.gov (United States)

    Nair, J. Kumar, Sr.; Menon, RS; Goyal, M.; Ansari, NA; Chakravarty, A.; Joemon, V.

    2017-02-01

    Liquid hydrogen around 20 K is used as cold moderator for generating “cold neutron beam” in nuclear research reactors. A cryogenic helium refrigeration system is the core upon which such hydrogen liquefaction applications are built. A thermodynamic process based on reversed Brayton cycle with two stage expansion using high speed cryogenic turboexpanders (TEX) along with a pair of compact high effectiveness process heat exchangers (HX), is well suited for such applications. An existing helium refrigeration system, which had earlier demonstrated a refrigeration capacity of 470 W at around 20 K, is modified based on past operational experiences and newer application requirements. Modifications include addition of a new heat exchanger to simulate cryogenic process load and two other heat exchangers for controlling the temperatures of helium streams leading out to the application system. To incorporate these changes, cryogenic piping inside the cold box is suitably modified. This paper presents process simulation, sizing of new heat exchangers as well as fabrication aspects of the modified cryogenic process piping.

  15. Modeling and Advanced Control for Sustainable Process ...

    Science.gov (United States)

    This book chapter introduces a novel process systems engineering framework that integrates process control with sustainability assessment tools for the simultaneous evaluation and optimization of process operations. The implemented control strategy consists of a biologically-inspired, multi-agent-based method. The sustainability and performance assessment of process operating points is carried out using the U.S. E.P.A.’s GREENSCOPE assessment tool that provides scores for the selected economic, material management, environmental and energy indicators. The indicator results supply information on whether the implementation of the controller is moving the process towards a more sustainable operation. The effectiveness of the proposed framework is illustrated through a case study of a continuous bioethanol fermentation process whose dynamics are characterized by steady-state multiplicity and oscillatory behavior. This book chapter contribution demonstrates the application of novel process control strategies for sustainability by increasing material management, energy efficiency, and pollution prevention, as needed for SHC Sustainable Uses of Wastes and Materials Management.

  16. Assessment and mitigation of liquefaction

    International Nuclear Information System (INIS)

    Czelada, J. A.; Melentijevic, S.

    2014-01-01

    The simplified empirical procedure in its original form presented in Youd et al (2001) and some further developments given in Idriss and Boulanger (2006) for evaluating liquefaction resistance of soils is presented in this paper only for the criteria based on standard penetration test (SPT). Methods for estimating the ground improvement techniques by stone columns and dynamics compaction are presented. For stone columns Priebe method (1995) and homogenized method (equivalent parameters) are present. for dynamic compaction methods proposed by Recomendacion Geotecnica para las Obras Maritimas y/o Porturaria - ROM 0.5-05 (2005) and Nashed et al. (2009) are described. These analysis methods for each ground improvement technique are compared in two different case histories showing similar results in each one. (Author)

  17. Advanced Secure Optical Image Processing for Communications

    Science.gov (United States)

    Al Falou, Ayman

    2018-04-01

    New image processing tools and data-processing network systems have considerably increased the volume of transmitted information such as 2D and 3D images with high resolution. Thus, more complex networks and long processing times become necessary, and high image quality and transmission speeds are requested for an increasing number of applications. To satisfy these two requests, several either numerical or optical solutions were offered separately. This book explores both alternatives and describes research works that are converging towards optical/numerical hybrid solutions for high volume signal and image processing and transmission. Without being limited to hybrid approaches, the latter are particularly investigated in this book in the purpose of combining the advantages of both techniques. Additionally, pure numerical or optical solutions are also considered since they emphasize the advantages of one of the two approaches separately.

  18. Advanced Materials Growth and Processing Facility

    Data.gov (United States)

    Federal Laboratory Consortium — This most extensive of U.S. Army materials growth and processing facilities houses seven dedicated, state-of-the-art, molecular beam epitaxy and three metal organic...

  19. Advances in Nuclear Power Process Heat Applications

    International Nuclear Information System (INIS)

    2012-05-01

    Following an IAEA coordinated research project, this publication compiles the findings of research and development activities related to practical nuclear process heat applications. An overview of current progress on high temperature gas cooled reactors coupling schemes for different process heat applications, such as hydrogen production and desalination is included. The associated safety aspects are also highlighted. The summary report documents the results and conclusions of the project.

  20. Development of advanced spent fuel management process

    International Nuclear Information System (INIS)

    Shin, Young Joon; Cho, S. H.; You, G. S.

    2001-04-01

    Currently, the economic advantage of any known approach to the back end fuel cycle of a nuclear power reactor has not been well established. Thus the long term storage of the spent fuel in a safe manner is one of the important issues to be resolved in countries where the nuclear power has a relatively heavy weight in power production of that country. At KAERI, as a solution to this particular issue midterm storage of the spent fuel, an alternative approach has been developed. This approach includes the decladding and pulverization process of the spent PWR fuel rod, the reducing process from the uranium oxide to a metallic uranium powder using Li metal in a LiCl salt, the continuous casting process of the reduced metal, and the recovery process of Li from mixed salts by the electrolysis. We conducted the laboratory scale tests of each processes for the technical feasibility and determination for the operational conditions for this approach. Also, we performed the theoretical safety analysis and conducted integral tests for the equipment integration through the Mock-up facility with non-radioactive samples. There were no major issues in the approach, however, material incompatibility of the alkaline metal and oxide in a salt at a high temperature and the reactor that contains the salt became a show stopper of the process. Also the difficulty of the clear separation of the salt with metals reduced from the oxide became a major issue

  1. Practical Implementations of Advanced Process Control for Linear Systems

    DEFF Research Database (Denmark)

    Knudsen, Jørgen K . H.; Huusom, Jakob Kjøbsted; Jørgensen, John Bagterp

    2013-01-01

    This paper describes some practical problems encountered, when implementing Advanced Process Control, APC, schemes on linear processes. The implemented APC controllers discussed will be LQR, Riccati MPC and Condensed MPC controllers illustrated by simulation of the Four Tank Process and a lineari......This paper describes some practical problems encountered, when implementing Advanced Process Control, APC, schemes on linear processes. The implemented APC controllers discussed will be LQR, Riccati MPC and Condensed MPC controllers illustrated by simulation of the Four Tank Process...... on pilot plant equipment on the department of Chemical Engineering DTU Lyngby....

  2. Advanced metrology by offline SEM data processing

    Science.gov (United States)

    Lakcher, Amine; Schneider, Loïc.; Le-Gratiet, Bertrand; Ducoté, Julien; Farys, Vincent; Besacier, Maxime

    2017-06-01

    Today's technology nodes contain more and more complex designs bringing increasing challenges to chip manufacturing process steps. It is necessary to have an efficient metrology to assess process variability of these complex patterns and thus extract relevant data to generate process aware design rules and to improve OPC models. Today process variability is mostly addressed through the analysis of in-line monitoring features which are often designed to support robust measurements and as a consequence are not always very representative of critical design rules. CD-SEM is the main CD metrology technique used in chip manufacturing process but it is challenged when it comes to measure metrics like tip to tip, tip to line, areas or necking in high quantity and with robustness. CD-SEM images contain a lot of information that is not always used in metrology. Suppliers have provided tools that allow engineers to extract the SEM contours of their features and to convert them into a GDS. Contours can be seen as the signature of the shape as it contains all the dimensional data. Thus the methodology is to use the CD-SEM to take high quality images then generate SEM contours and create a data base out of them. Contours are used to feed an offline metrology tool that will process them to extract different metrics. It was shown in two previous papers that it is possible to perform complex measurements on hotspots at different process steps (lithography, etch, copper CMP) by using SEM contours with an in-house offline metrology tool. In the current paper, the methodology presented previously will be expanded to improve its robustness and combined with the use of phylogeny to classify the SEM images according to their geometrical proximities.

  3. Comparative techno-economic analysis and process design for indirect liquefaction pathways to distillate-range fuels via biomass-derived oxygenated intermediates upgrading: Liquid Transportation Fuel Production via Biomass-derived Oxygenated Intermediates Upgrading

    Energy Technology Data Exchange (ETDEWEB)

    Tan, Eric C. D. [National Renewable Energy Laboratory, Golden CO USA; Snowden-Swan, Lesley J. [Pacific Northwest National Laboratory, Richland WA USA; Talmadge, Michael [National Renewable Energy Laboratory, Golden CO USA; Dutta, Abhijit [National Renewable Energy Laboratory, Golden CO USA; Jones, Susanne [Pacific Northwest National Laboratory, Richland WA USA; Ramasamy, Karthikeyan K. [Pacific Northwest National Laboratory, Richland WA USA; Gray, Michel [Pacific Northwest National Laboratory, Richland WA USA; Dagle, Robert [Pacific Northwest National Laboratory, Richland WA USA; Padmaperuma, Asanga [Pacific Northwest National Laboratory, Richland WA USA; Gerber, Mark [Pacific Northwest National Laboratory, Richland WA USA; Sahir, Asad H. [National Renewable Energy Laboratory, Golden CO USA; Tao, Ling [National Renewable Energy Laboratory, Golden CO USA; Zhang, Yanan [National Renewable Energy Laboratory, Golden CO USA

    2016-09-27

    This paper presents a comparative techno-economic analysis (TEA) of five conversion pathways from biomass to gasoline-, jet-, and diesel-range hydrocarbons via indirect liquefaction with specific focus on pathways utilizing oxygenated intermediates. The four emerging pathways of interest are compared with one conventional pathway (Fischer-Tropsch) for the production of the hydrocarbon blendstocks. The processing steps of the four emerging pathways include: biomass to syngas via indirect gasification, gas cleanup, conversion of syngas to alcohols/oxygenates followed by conversion of alcohols/oxygenates to hydrocarbon blendstocks via dehydration, oligomerization, and hydrogenation. Conversion of biomass-derived syngas to oxygenated intermediates occurs via three different pathways, producing: 1) mixed alcohols over a MoS2 catalyst, 2) mixed oxygenates (a mixture of C2+ oxygenated compounds, predominantly ethanol, acetic acid, acetaldehyde, ethyl acetate) using an Rh-based catalyst, and 3) ethanol from syngas fermentation. This is followed by the conversion of oxygenates/alcohols to fuel-range olefins in two approaches: 1) mixed alcohols/ethanol to 1-butanol rich mixture via Guerbet reaction, followed by alcohol dehydration, oligomerization, and hydrogenation, and 2) mixed oxygenates/ethanol to isobutene rich mixture and followed by oligomerization and hydrogenation. The design features a processing capacity of 2,000 tonnes/day (2,205 short tons) of dry biomass. The minimum fuel selling prices (MFSPs) for the four developing pathways range from $3.40 to $5.04 per gasoline-gallon equivalent (GGE), in 2011 US dollars. Sensitivity studies show that MFSPs can be improved with co-product credits and are comparable to the commercial Fischer-Tropsch benchmark ($3.58/GGE). Overall, this comparative TEA study documents potential economics for the developmental biofuel pathways via mixed oxygenates.

  4. Advances in process research by radionuclide techniques

    International Nuclear Information System (INIS)

    Merz, A.; Vogg, H.

    1978-01-01

    Modifications and transformations of materials and their technical implementation in process systems require movement of materials. Radionuclide techniques can greatly help in understanding and describing these mechanisms. The specialized measuring technique is demonstrated by three examples selected from various fields of process technology. Radioactive tracer studies performed on a rotary kiln helped, inter alia, to establish a subdivision into process zones and to pinpoint areas of dust generation. Mixing and feeding actions were studied in a twin screw extruder equipped with a special screw and mixer disk arrangement. Tracer experiments conducted in two secondary settling basins indicate the differences in the mechanisms of movement of the aqueous phase if the mean residence time and the residence time distribution may be influenced not only by hydraulic loads, but also by design variants of the overflow flumes. (orig./HP) [de

  5. Advanced Fuels and Combustion Processes for Propulsion

    Science.gov (United States)

    2010-09-01

    production from biomass steam reforming – Conduct a feasibility analysis of the proposed integrated process Energia Technologies - D. Nguyen & K. Parimi...strength foam material development by Ultramet – Combustion experiments performed U. Of Alabama – End-user input provided by Solar Turbines Major

  6. Recent advances in radiation processing of food

    International Nuclear Information System (INIS)

    Sharma, Arun

    2013-01-01

    Commercial application of radiation technology for food processing started in the nineties after it was approved by FAO/IAEA/WHO and Codex Alimentarius Commission in the eighties. Sanitary applications were initially explored commercially with microbial decontamination of spices and dry ingredients as the primary commodities to be processed on a large scale. Subsequently, with the emergence of E.coli O157:H7 as the potential food poisoning risk in ground beef, irradiation of meat was initiated in the late nineties in the USA. Since then irradiation, has become a very useful food safety tool and the technology has been approved for addressing food safety risks in moluscan shellfish and vegetables like lettuce, spinach, and more recently for raw uncooked meat by USFDA. Phytosanitary applications assumed importance after USFDA approved irradiation as a method of phytosanitary treatment and subsequent endorsement of the process by International Plant Protection Convention (IPPC) in 2003. These approvals were responsible for development of international trade in agricultural commodities. The first to demonstrate the feasibility of the process were India and Australia, the countries that exported mangoes to New Zealand and USA, respectively. As far as the source of radiation is concerned, the world is slowly moving towards deployment of machine sources, thereby reducing its dependence on radioisotopes for commercial irradiation. (author)

  7. Advances in the Application of Image Processing Fruit Grading

    OpenAIRE

    Fang , Chengjun; Hua , Chunjian

    2013-01-01

    International audience; In the perspective of actual production, the paper presents the advances in the application of image processing fruit grading from several aspects, such as processing precision and processing speed of image processing technology. Furthermore, the different algorithms about detecting size, shape, color and defects are combined effectively to reduce the complexity of each algorithm and achieve a balance between the processing precision and processing speed are keys to au...

  8. Influence of the void ratio and the confining on the static liquefaction in slopes in shangi sand

    Directory of Open Access Journals (Sweden)

    Alfonso Mariano Ramos Cañón

    2015-01-01

    Full Text Available A numerical study on the onset of static liquefaction in slopes under undrained conditions of loading was developed based on a general liquefaction flow instability criterion for elastoplastic soils based on the concept of loss of controllability. The criterion is applied to the case of axisymmetric loading to detect the onset of static liquefaction. The criterion is used in conjunction with an elastoplastic model for sands and is tested by means of numerical simulations of element tests. The numerical results are compared with experimental evidence obtaining good agreement. A quantitative study of the influence of the mean pressure, void ratio and the anisotropy of stress on the onset of static liquefaction is presented for the Changi sand. From the analysis of the numerical results, it can be concluded that: a. the mobilized friction angle at the onset of liquefaction is not an intrinsic property of the material, but is a state variable b. Despite of the multiple variables involved in the process of generation of undrained instability, the state of stresses at the onset of static liquefaction can be conveniently represented by a linear relation between Dq/po and no . This graphical representation can be used in the practice of geotechnical engineering to quantify the margin of security against the static liquefaction of a sandy slope.

  9. FY 2000 report on the results of the regional consortium R and D project - Regional consortium energy R and D field. First year report. Commercialization of depth dechlorination/debromination refining catalyst of waste plastic derived oil and the liquefaction process; 2000 nendo chiiki consortium kenkyu kaihatsu jigyo - chiiki consortium kenkyu kaihatsu bun'ya. Hai plastic bunkaiyu no shindo datsuenso dasshuso seisei shokubai oyobi yuka process no jitsuyoka (dai 1 nendo) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The development was proceeded with of technology to produce iron oxide/porous carbon composite catalyst which promotes dehalogenation of thermal-degraded oil at low cost and in large quantity. This catalyst enables the improvement in operability and safety in the liquefaction process for mixed plastic and in quality of oil product. The development is also made of a regional distributed small batch liquefaction system with processing ability of 1t/day. Studies were made in the following 6 fields: 1) analysis of the dehalogenation performance of catalyst and the evaluation; 2) development of a method to industrially produce halogen compound refining catalyst; 3) R and D of a method to analyze environmental components; 4) evaluation study of halogen resistant materials and halogen resistant technology; 5) development of a small test device for commercialization of the liquefaction/degradation process; 6) comprehensive investigational study. In 1), the performance of prototype catalyst was confirmed, and the structure was analyzed. Also developed was iron chloride/SiO{sub 2} catalyst which converts organic halogen to inorganic halogen. (NEDO)

  10. ADVANCED OXIDATION PROCESSES FOR FOOD INDUSTRIAL WASTEWATER DECONTAMINATION

    Directory of Open Access Journals (Sweden)

    Dorota Krzemińska

    2015-02-01

    Full Text Available High organic matter content is a basic problem in food industry wastewaters. Typically, the amount and composition of the effluent varies considerably. In the article four groups of advanced processes and their combination of food industry wastewater treatment have been reviewed: electrochemical oxidation (EC, Fenton’s process, ozonation of water and photocatalytic processes. All advanced oxidation processes (AOP`s are characterized by a common chemical feature: the capability of exploiting high reactivity of HO• radicals in driving oxidation processes which are suitable for achieving decolonization and odour reduction, and the complete mineralization or increase of bioavailability of recalcitrant organic pollutants.

  11. Research on mechanism of and catalysts for extraction liquefaction of coal using coal-based solvents; Sekitankei yozai ni yoru sekitan no chushutsu ekika kiko to shokubai no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-07-01

    Papers of Professor Yoshio Kamiya of Tokyo University are compiled into this report. The list of the papers includes (1) Synthesis of heavy fuel oils from coal; (2) Research and development of coal liquefaction; (3) Dissolution reaction of coal by hydrogen-donating aromatic solvents (I); (4) Effect of hydrogen-donor solvent on the liquefaction of coal; (5) Recent studies on the chemical structure of solvent refined coal; (6) Dissolution reaction of coal by hydrogen-donating aromatic solvents (II); (7) Future of coal as energy material; (8), (9), (10) same as (6) in the subject discussed; (11) Recent studies on coal liquefaction catalysts; (12) Environmental problems and drain treatment to accompany processes of converting fossil resources into fuels; (13) Chemistry of coal oxidation; (14) Fractionation and analysis of solvent refined coal by gel permeation chromatography; (15) Current state of research and development of coal liquefaction; (16) Properties and components of coal oils from coal liquefaction processes under development; (17) Solvent effect of coal derived aromatic compounds on the liquefaction of Akabira coal; (18) Chemistry of coal liquefaction; (19) Research and development of coal liquefaction in the U.S.; (20) Thermal treatment of coal-related aromatic ethers in tetralin solution; (21) Recent technology of utilizing heavy carbon resources; (22) Chemical properties and reactivity of coal; (23) Current state and future of development of coal liquefaction processes; and (24) Development of overseas coal liquefaction projects. (NEDO)

  12. Report on the FY 1998 results of the New Sunshine Project (B version). Development of coal liquefaction technology (Development of base technology of liquefaction (Project on internationalization of coal liquefaction technology)); 1998 nendo sekitan ekika gijutsu kaihatsu seika hokokusho (B ban). Ekika kiban gijutsu no kaihatsu (sekitan ekika gijutsu no kokusaika jigyo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    In 1994, a memorandum on the research cooperation was agreed between NEDO and BPPT (The Agency for the Assessment and Application Technology) in Indonesia, based on the request for the coal liquefaction technology cooperation from BPPT. It includes the following items: conference for professionals to be held, invitation and training of Indonesian engineers, activity for joint field survey and potential survey of location of coal liquefaction commercial plant. Further in 1997, the secondary memorandum was concluded for the potential survey for securing the hydrogen required for coal liquefaction by coal gasification. The survey was summarized as the potential survey for location of coal liquefaction. In the testing study for improving economical efficiency of liquefaction process, it was made clear that the higher the Fe content of Banko coal is, the higher the reaction of liquefaction is, and that Fe compounds in coal show catalysis. In the Soroako area in Sulawesi island, there are the nickel mine run by PT. Inco. Soroako limonite is promising as catalyst material for commercial-scale coal liquefaction. In the gasification method, the plant construction cost increases, but the production amount of coal-derived liquid can be increased. That is more profitable than the production of hydrogen from natural gas. (NEDO)

  13. Review and experimental study on pyrolysis and hydrothermal liquefaction of microalgae for biofuel production

    International Nuclear Information System (INIS)

    Chiaramonti, David; Prussi, Matteo; Buffi, Marco; Rizzo, Andrea Maria; Pari, Luigi

    2017-01-01

    Highlights: • A review of microalgae thermochemical conversion to bioliquids was carried out. • We focused on pyrolysis and hydrothermal liquefaction for biocrude/biofuels. • Original experimental research on microalgae pyrolysis was also carried out. • Starvation does not impact significant on the energy content of the biocrude. • This result is relevant for designing full scale microalgae production plants. - Abstract: Advanced Biofuels steadily developed during recent year, with several highly innovative processes and technologies explored at various scales: among these, lignocellulosic ethanol and CTO (Crude Tall Oil)-biofuel technologies already achieved early-commercial status, while hydrotreating of vegetable oils is today fully commercial, with almost 3.5 Mt/y installed capacity worldwide. In this context, microalgae grown in salt-water and arid areas represent a promising sustainable chain for advanced biofuel production but, at the same time, they also represent a considerable challenge. Processing microalgae in an economic way into a viable and sustainable liquid biofuel (a low-cost mass-product) is not trivial. So far, the most studied microalgae-based biofuel chain is composed by microorganism cultivation, lipid accumulation, oil extraction, co-product valorization, and algae oil conversion through conventional esterification into Fatty Acids Methyl Esters (FAME), i.e. Biodiesel, or Hydrotreated Esters and Fatty Acids (HEFA), the latter representing a very high quality drop-in biofuel (suitable either for road transport or for aviation). However, extracting the algae oil at low cost and industrial scale is not yet a mature process, and there is not yet industrial production of algae-biofuel from these two lipid-based chains. Another option can however be considered: processing the algae through dedicated thermochemical reactors into advanced biofuels, thus approaching the downstream processing of algae in a completely different way than

  14. Optical Multiple Access Network (OMAN) for advanced processing satellite applications

    Science.gov (United States)

    Mendez, Antonio J.; Gagliardi, Robert M.; Park, Eugene; Ivancic, William D.; Sherman, Bradley D.

    1991-01-01

    An OMAN breadboard for exploring advanced processing satellite circuit switch applications is introduced. Network architecture, hardware trade offs, and multiple user interference issues are presented. The breadboard test set up and experimental results are discussed.

  15. Advanced alarm systems: Display and processing issues

    Energy Technology Data Exchange (ETDEWEB)

    O`Hara, J.M. [Brookhaven National Lab., Upton, NY (United States); Wachtel, J.; Perensky, J. [US Nuclear Regulatory Commission, Washington, DC (United States). Office of Nuclear Regulatory Research

    1995-05-01

    This paper describes a research program sponsored by the US Nuclear Regulatory Commission to address the human factors engineering (HFE) deficiencies associated with nuclear power plant alarm systems. The overall objective of the study is to develop HFE review guidance for alarm systems. In support of this objective, human performance issues needing additional research were identified. Among the important issues were alarm processing strategies and alarm display techniques. This paper will discuss these issues and briefly describe our current research plan to address them.

  16. Basic studies on coal liquefaction reaction, reforming and utilization of liquefaction products

    Energy Technology Data Exchange (ETDEWEB)

    Shiraishi, M. (National Institute for Resources and Environment, Tsukuba (Japan))

    1993-09-01

    This report describes the achievement of research and development of coal liquefaction technologies in the Sunshine Project for FY 1992, regarding the coal liquefaction reaction, reforming and utilization of liquefaction products. For the fundamental study on coal liquefaction reaction, were investigated effect of asphaltene in petroleum residue on coprocessing, pretreatment effect in coprocessing of Taiheiyo coal and tarsand bitumen using oil soluble catalyst, solubilization and liquefaction of Taiheiyo coal at mild conditions with the aid of super acid, and flash hydropyrolysis of finely pulverized swollen coal under high hydrogen pressure. On the other hand, for the study on hydrotreatment of coal derived liquid, were investigated catalytic hydroprocessing of Wandoan coal liquids, production of gasoline from coal liquids by fluid catalytic cracking, solvent extraction of phenolic compounds from coal liquids, and separation of hetero compounds in coal liquid by means of high pressure crystallization. Further progress in these studies has been confirmed. 9 figs., 6 tabs.

  17. Recent Advancements in Semiconductor-based Optical Signal Processing

    DEFF Research Database (Denmark)

    Nielsen, M L; Mørk, Jesper

    2006-01-01

    Significant advancements in technology and basic understanding of device physics are bringing optical signal processing closer to a commercial breakthrough. In this paper we describe the main challenges in high-speed SOA-based switching.......Significant advancements in technology and basic understanding of device physics are bringing optical signal processing closer to a commercial breakthrough. In this paper we describe the main challenges in high-speed SOA-based switching....

  18. Biomass Direct Liquefaction Options. TechnoEconomic and Life Cycle Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Tews, Iva J.; Zhu, Yunhua; Drennan, Corinne; Elliott, Douglas C.; Snowden-Swan, Lesley J.; Onarheim, Kristin; Solantausta, Yrjo; Beckman, David

    2014-07-31

    The purpose of this work was to assess the competitiveness of two biomass to transportation fuel processing routes, which were under development in Finland, the U.S. and elsewhere. Concepts included fast pyrolysis (FP), and hydrothermal liquefaction (HTL), both followed by hydrodeoxygenation, and final product refining. This work was carried out as a collaboration between VTT (Finland), and PNNL (USA). The public funding agents for the work were Tekes in Finland and the Bioenergy Technologies Office of the U.S. Department of Energy. The effort was proposed as an update of the earlier comparative technoeconomic assessment performed by the IEA Bioenergy Direct Biomass Liquefaction Task in the 1980s. New developments in HTL and the upgrading of the HTL biocrude product triggered the interest in reinvestigating this comparison of these biomass liquefaction processes. In addition, developments in FP bio-oil upgrading had provided additional definition of this process option, which could provide an interesting comparison.

  19. Subcritical hydrothermal liquefaction of barley straw in fresh water and recycled aqueous phase

    DEFF Research Database (Denmark)

    Zhu, Zhe; Toor, Saqib; Rosendahl, Lasse

    2014-01-01

    This project focuses on the investigation of addition of aqueous phase in the production of biofuel from biomass through hydrothermal liquefaction (HTL) technology. Hydrothermal liquefaction is a wet thermal conversion process, which can convert all kinds of biomass to fuels. In this study, barley...... straw was first liquefied in fresh distilled water with the presence of K2CO3 catalyst at 300 C as the reference run. Afterwards, the aqueous phase which is obtained from liquefaction process in the previous run was recycled and used as the reaction medium from the second to the fourth run....... With the addition of recycling aqueous phase in HTL process, it is expected that the amount of the waste water and energy consumption can be reduced. The effect of water recirculation on product yield and properties was investigated in this study. The results showed that bio-oil yield was 34.85 wt% when the barley...

  20. Advances in cost effective processing of titanium

    International Nuclear Information System (INIS)

    Nelson, O.E.

    1993-01-01

    Recently an industry expert pointed out that one of the greatest hindrances to the growth of titanium usage has been the low percentage of material usable in the final product. Due to the extensive processing, forming, and machining operations typically performed on titanium, yield losses are high. This is especially true in aerospace applications where most titanium is used. In engine components, the start to finish ratio, known as the buy to fly ratio, is often as high as 7 to 1. This can be illustrated by looking at the use of titanium in Pratt and Whitney engines. In the JT-8D-217 used on Boeing's 737-200, the titanium buyweight is 5,385 pounds, whereas the finished titanium, flyweight is just 758 pounds. This start to finish ratio is 7.1:1, giving titanium 17.0% of total engine weight. (orig.)

  1. Advances in modeling plastic waste pyrolysis processes

    Energy Technology Data Exchange (ETDEWEB)

    Safadi, Y. [Department of Mechanical Engineering, American University of Beirut, PO Box 11-0236, Beirut (Lebanon); Zeaiter, J. [Chemical Engineering Program, American University of Beirut, PO Box 11-0236, Beirut (Lebanon)

    2013-07-01

    The tertiary recycling of plastics via pyrolysis is recently gaining momentum due to promising economic returns from the generated products that can be used as a chemical feedstock or fuel. The need for prediction models to simulate such processes is essential in understanding in depth the mechanisms that take place during the thermal or catalytic degradation of the waste polymer. This paper presents key different models used successfully in literature so far. Three modeling schemes are identified: Power-Law, Lumped-Empirical, and Population-Balance based equations. The categorization is based mainly on the level of detail and prediction capability from each modeling scheme. The data shows that the reliability of these modeling approaches vary with the degree of details the experimental work and product analysis are trying to achieve.

  2. Structural health monitoring an advanced signal processing perspective

    CERN Document Server

    Chen, Xuefeng; Mukhopadhyay, Subhas

    2017-01-01

    This book highlights the latest advances and trends in advanced signal processing (such as wavelet theory, time-frequency analysis, empirical mode decomposition, compressive sensing and sparse representation, and stochastic resonance) for structural health monitoring (SHM). Its primary focus is on the utilization of advanced signal processing techniques to help monitor the health status of critical structures and machines encountered in our daily lives: wind turbines, gas turbines, machine tools, etc. As such, it offers a key reference guide for researchers, graduate students, and industry professionals who work in the field of SHM.

  3. Catalytic multi-stage liquefaction (CMSL)

    Energy Technology Data Exchange (ETDEWEB)

    Comolli, A.G.; Ganguli, P.; Karolkiewicz, W.F.; Lee, T.L.K.; Pradhan, V.R.; Popper, G.; Smith, T.; Stalzer, R.H.

    1996-11-01

    Reported herein are the details and the results of laboratory and bench scale experiments that were conducted at Hydrocarbon Technologies, Inc. under DOE Contract No. DE-AC22-93PC92147 during the period of October 1, 1992, to December 31, 1995. The program results described herein build on the previous technology base and investigating additional methods to improve the economics of producing transportation fuels from coal. This included purely physical parameters, coal treatment and variation in solvent to coal ratio, the use of syngas to replace part of the hydrogen as the reducing gas, the use of dispersed catalyst in addition to and replacing the supported catalyst, and the co-processing of coal with plastic waste material. The overall objective of this program is to produce liquid fuels from direct coal liquefaction at a cost that is competitive with conventional fuels. The report includes the results of an economic assessment of the various process strategies that were evaluated during this program. A summary of the technical/economic evaluations is given in Volume I, Section II of this report. The experimental details of the eleven run of the program are given in Volume I, Section III and Volume II of this report. The details of the technical evaluations are given in the Volume III of the report.

  4. Hydrothermal Liquefaction Treatment Hazard Analysis Report

    Energy Technology Data Exchange (ETDEWEB)

    Lowry, Peter P. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wagner, Katie A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-09-12

    Hazard analyses were performed to evaluate the modular hydrothermal liquefaction treatment system. The hazard assessment process was performed in 2 stages. An initial assessment utilizing Hazard Identification and Preliminary Hazards Analysis (PHA) techniques identified areas with significant or unique hazards (process safety-related hazards) that fall outside of the normal operating envelope of PNNL and warranted additional analysis. The subsequent assessment was based on a qualitative What-If analysis. The analysis was augmented, as necessary, by additional quantitative analysis for scenarios involving a release of hazardous material or energy with the potential for affecting the public. The following selected hazardous scenarios received increased attention: •Scenarios involving a release of hazardous material or energy, controls were identified in the What-If analysis table that prevent the occurrence or mitigate the effects of the release. •Scenarios with significant consequences that could impact personnel outside the immediate operations area, quantitative analyses were performed to determine the potential magnitude of the scenario. The set of “critical controls” were identified for these scenarios (see Section 4) which prevent the occurrence or mitigate the effects of the release of events with significant consequences.

  5. Catalytic activity of pyrite for coal liquefaction reaction; Tennen pyrite no shokubai seino ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Hirano, K.; Kozu, M.; Okada, T.; Kobayashi, M. [Nippon Coal Oil Co. Ltd., Tokyo (Japan)

    1996-10-28

    Since natural pyrite is easy to obtain and cheap as coal liquefaction catalyst, it is to be used for the 150 t/d scale NEDOL process bituminous coal liquefaction pilot plant. NEDO and NCOL have investigated the improvement of catalytic activity of pulverized natural pyrite for enhancing performance and economy of the NEDOL process. In this study, coal liquefaction tests were conducted using natural pyrite catalyst pulverized by dry-type bowl mill under nitrogen atmosphere. Mechanism of catalytic reaction of the natural pyrite was discussed from relations between properties of the catalyst and liquefaction product. The natural pyrite provided an activity to transfer gaseous hydrogen into the liquefaction product. It was considered that pulverized pyrite promotes the hydrogenation reaction of asphaltene because pulverization increases its contact rate with reactant and the amount of active points on its surface. It was inferred that catalytic activity of pyrite is affected greatly by the chemical state of Fe and S on its surface. 3 refs., 4 figs., 1 tab.

  6. Fiscal 1989 report. Coal liquefaction committee; 1989 nendo sekitan ekika iinkai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-03-01

    The committee in this fiscal year had its 1st meeting in June 1989 and 2nd meeting in March 1990, when fiscal 1989 research and development programs and fiscal 1989 research and development results, etc., were reported and discussed. The operating status of the 1 ton/day PSU (process supporting unit) for bituminous coal liquefaction was reported and discussed. The report included its 1st operation for the demonstration of a long-term stable run under standard conditions that continued for trouble-free 50 days, the 2nd operation for the investigation of the effect of liquefaction reaction temperature in which the liquefaction yield recorded the maximum at 450 degrees C with the collection of coal oils of 55 wt.% on the average, and the 3rd operation for the investigation of the effects of liquefaction reaction pressure and catalyst injection size whose details were being analyzed. Reported in relation with the brown coal liquefaction pilot plant was a comprehensive operation of a series of 1st hydrogenation, solvent deashing, and 2nd hydrogenation processes completed after a continuous operation of 460 hours establishing a total operating time of 1050 hours. (NEDO)

  7. Report on the achievements in research and development of a coal liquefaction technology in the Sunshine Project in fiscal 1981. Development of a solvent extraction and liquefaction plant (research and development of solid-liquid separation process); Sekitan ekika gijutsu no kenkyu kaihatsu, yozai chushutsu ekika plant no kaihatsu, koeki bunriho no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    Among researches on solvent extraction and liquefaction technologies in the Sunshine Project in fiscal 1981, this paper describes the achievements in development of a solid-liquid separation technology. In the research of operation of a centrifugal separation device, a solid-liquid separation test was performed on slurry extracted from the Australian Wandoan coal being sub-bituminous coal. The deliming rate has reached 99% equilibrium at an addition rate of 20% by weight of anti-solvent (a kind of normal paraffin, which reduces solubility of part of coal extracts and enhances removal rates of ash and solids by utilizing coagulating action of the extracts). Asphaltene among the liquefaction formed materials may be recovered nearly completely, but the recovery rate for pre-asphaltene was lower. An operation test was also carried out by using slurry extracted in a 1 t/d experimental plant. In the study on operation of a 5-l/h continuous sedimentation and separation device, a maximum effect was derived with addition of anti-solvent at 25% by weight and at a stirring rate of 700 rpm. The solid-liquid separability changes depending on the kind of slurry. The low conversion rate slurry becomes difficult of separation because its viscosity is high and the difference in density between solids and liquid is small. Furthermore, the high conversion rate slurry has become difficult of separation due to small particle size of the solids. (NEDO)

  8. Overview of advanced process control in welding within ERDA

    International Nuclear Information System (INIS)

    Armstrong, R.E.

    1977-01-01

    The special kinds of demands placed on ERDA weapons and reactors require them to have very reliable welds. Process control is critical in achieving this reliability. ERDA has a number of advanced process control projects underway with much of the emphasis being on electron beam welding. These include projects on voltage measurement, beam-current control, beam focusing, beam spot tracking, spike suppression, and computer control. A general discussion of process control in welding is followed by specific examples of some of the advanced joining process control projects in ERDA

  9. Optical metrology for advanced process control: full module metrology solutions

    Science.gov (United States)

    Bozdog, Cornel; Turovets, Igor

    2016-03-01

    Optical metrology is the workhorse metrology in manufacturing and key enabler to patterning process control. Recent advances in device architecture are gradually shifting the need for process control from the lithography module to other patterning processes (etch, trim, clean, LER/LWR treatments, etc..). Complex multi-patterning integration solutions, where the final pattern is the result of multiple process steps require a step-by-step holistic process control and a uniformly accurate holistic metrology solution for pattern transfer for the entire module. For effective process control, more process "knobs" are needed, and a tighter integration of metrology with process architecture.

  10. Advanced information processing system for advanced launch system: Avionics architecture synthesis

    Science.gov (United States)

    Lala, Jaynarayan H.; Harper, Richard E.; Jaskowiak, Kenneth R.; Rosch, Gene; Alger, Linda S.; Schor, Andrei L.

    1991-01-01

    The Advanced Information Processing System (AIPS) is a fault-tolerant distributed computer system architecture that was developed to meet the real time computational needs of advanced aerospace vehicles. One such vehicle is the Advanced Launch System (ALS) being developed jointly by NASA and the Department of Defense to launch heavy payloads into low earth orbit at one tenth the cost (per pound of payload) of the current launch vehicles. An avionics architecture that utilizes the AIPS hardware and software building blocks was synthesized for ALS. The AIPS for ALS architecture synthesis process starting with the ALS mission requirements and ending with an analysis of the candidate ALS avionics architecture is described.

  11. Advance care planning in CKD/ESRD: an evolving process.

    Science.gov (United States)

    Holley, Jean L

    2012-06-01

    Advance care planning was historically considered to be simply the completion of a proxy (health care surrogate designation) or instruction (living will) directive that resulted from a conversation between a patient and his or her physician. We now know that advance care planning is a much more comprehensive and dynamic patient-centered process used by patients and families to strengthen relationships, achieve control over medical care, prepare for death, and clarify goals of care. Some advance directives, notably designated health care proxy documents, remain appropriate expressions of advance care planning. Moreover, although physician orders, such as do-not-resuscitate orders and Physician Orders for Life-Sustaining Treatment, may not be strictly defined as advance directives, their completion, when appropriate, is an integral component of advance care planning. The changing health circumstances and illness trajectory characteristic of ESRD mandate that advance care planning discussions adapt to a patient's situation and therefore must be readdressed at appropriate times and intervals. The options of withholding and withdrawing dialysis add ESRD-specific issues to advance care planning in this population and are events each nephrologist will at some time confront. Advance care planning is important throughout the spectrum of ESRD and is a part of nephrology practice that can be rewarding to nephrologists and beneficial to patients and their families.

  12. Report for fiscal 1981 of Sunshine Program coal group. Basic research on Solvolysis liquefaction technology; 1981 nendo solvolysis ekika gijutsu no kiso kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    Basic research is conducted on the Solvolysis liquefaction process for the purpose of producing from coal an ashless, low-sulfur, pollution-free liquid fuel. In the research on the Solvolysis liquefaction (1st stage liquefaction) of coal using a hydrogenation solvent, the Solvolysis liquefaction of coal is studied, for which a refined Solvolysis pitch containing coal substances and a hydride of solvent refined coal are used as Solvolysis liquefaction solvents for the 1st stage. In the research on the 1st stage liquefaction reaction conditions using a high-temperature closed process, two methods are employed. One is a method that uses a mini-pump type reactor in which a small hermetic container is submerged in a high-temperature solvent for rapid heating and the other is a method that uses a pipe type reactor in which coal slurry is caused to travel through a pipe heated to a high temperature. For the analysis of the 2nd stage liquefaction (hydrogenation) reaction conditions, the properties of the 2nd coal liquid, and the constitution of the 2nd coal liquid, and the for the research on the 1st stage liquefaction capacity, the hydrogenation of anthracene oil and solvent refined coal as recyclable solvent models is studied. (NEDO)

  13. Development of continuous bench scale unit for direct liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Wang Lai [Korea Inst. of Energy and Resources, Daeduk (Korea, Republic of)

    1996-12-31

    Batch coal liquefaction experiments using tubing bombs and continuous experiments by cell liquefaction test facility were carried out. The main purpose was to maximize the coal liquefaction yields by improving the activity of coal dissolution catalysts which are oil soluble transition metal naphthenate and to supplement the incomplete research results. In the meantime, the study on the reaction characteristics of coal liquefaction and coal liquid upgrading catalyst upon sulfiding conditions and phosphorous addition have been conducted (author). 102 refs., 35 figs.

  14. Development of continuous bench scale unit for direct liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Wang Lai [Korea Inst. of Energy and Resources, Daeduk (Korea, Republic of)

    1995-12-31

    Batch coal liquefaction experiments using tubing bombs and continuous experiments by cell liquefaction test facility were carried out. The main purpose was to maximize the coal liquefaction yields by improving the activity of coal dissolution catalysts which are oil soluble transition metal naphthenate and to supplement the incomplete research results. In the meantime, the study on the reaction characteristics of coal liquefaction and coal liquid upgrading catalyst upon sulfiding conditions and phosphorous addition have been conducted (author). 102 refs., 35 figs.

  15. Hydrothermal Liquefaction of Wastewater Treatment Plant Solids

    Energy Technology Data Exchange (ETDEWEB)

    Billing, Justin M.

    2016-10-16

    Feedstock cost is the greatest barrier to the commercial production of biofuels. The merits of any thermochemical or biological conversion process are constrained by their applicability to the lowest cost feedstocks. At PNNL, a recent resource assessment of wet waste feedstocks led to the identification of waste water treatment plant (WWTP) solids as a cost-negative source of biomass. WWTP solids disposal is a growing environmental concern [1, 2] and can account for up to half of WWTP operating costs. The high moisture content is well-suited for hydrothermal liquefaction (HTL), avoiding the costs and parasitic energy losses associated with drying the feedstock for incineration. The yield and quality of biocrude and upgraded biocrude from WWTP solids is comparable to that obtained from algae feedstocks but the feedstock cost is $500-1200 less per dry ton. A collaborative project was initiated and directed by the Water Environment & Reuse Foundation (WERF) and included feedstock identification, dewatering, shipping to PNNL, conversion to biocrude by HTL, and catalytic hydrothermal gasification of the aqueous byproduct. Additional testing at PNNL included biocrude upgrading by catalytic hydrotreatment, characterization of the hydrotreated product, and a preliminary techno-economic analysis (TEA) based on empirical results. This short article will cover HTL conversion and biocrude upgrading. The WERF project report with complete HTL results is now available through the WERF website [3]. The preliminary TEA is available as a PNNL report [4].

  16. A spotlight on liquefaction: evidence from clinical settings and experimental models in tuberculosis.

    Science.gov (United States)

    Cardona, Pere-Joan

    2011-01-01

    Liquefaction is one of the most intriguing aspects of human tuberculosis. It is a major cause of the transition from the infection to active disease (tuberculosis, TB) as well as the transmission of M. tuberculosis to other persons. This paper reviews the natural history of liquefaction in humans from a pathological and radiological point of view and discusses how the experimental models available can be used to address the topic of liquefaction and cavity formation. Different concepts that have been related to liquefaction, from the influence of immune response to mechanical factors, are reviewed. Synchronic necrosis or apoptosis of infected macrophages in a close area, together with an ineffective fibrosis, appears to be clue in this process, in which macrophages, the immune response, and bacillary load interact usually in a particular scenario: the upper lobes of the lung. The summary would be that even if being a stochastic effect, liquefaction would result if the organization of the intragranulomatous necrosis (by means of fibrosis) would be disturbed.

  17. A Spotlight on Liquefaction: Evidence from Clinical Settings and Experimental Models in Tuberculosis

    Directory of Open Access Journals (Sweden)

    Pere-Joan Cardona

    2011-01-01

    Full Text Available Liquefaction is one of the most intriguing aspects of human tuberculosis. It is a major cause of the transition from the infection to active disease (tuberculosis, TB as well as the transmission of M. tuberculosis to other persons. This paper reviews the natural history of liquefaction in humans from a pathological and radiological point of view and discusses how the experimental models available can be used to address the topic of liquefaction and cavity formation. Different concepts that have been related to liquefaction, from the influence of immune response to mechanical factors, are reviewed. Synchronic necrosis or apoptosis of infected macrophages in a close area, together with an ineffective fibrosis, appears to be clue in this process, in which macrophages, the immune response, and bacillary load interact usually in a particular scenario: the upper lobes of the lung. The summary would be that even if being a stochastic effect, liquefaction would result if the organization of the intragranulomatous necrosis (by means of fibrosis would be disturbed.

  18. Advanced Manufacturing Systems in Food Processing and Packaging Industry

    International Nuclear Information System (INIS)

    Sani, Mohd Shafie; Aziz, Faieza Abdul

    2013-01-01

    In this paper, several advanced manufacturing systems in food processing and packaging industry are reviewed, including: biodegradable smart packaging and Nano composites, advanced automation control system consists of fieldbus technology, distributed control system and food safety inspection features. The main purpose of current technology in food processing and packaging industry is discussed due to major concern on efficiency of the plant process, productivity, quality, as well as safety. These application were chosen because they are robust, flexible, reconfigurable, preserve the quality of the food, and efficient.

  19. Advanced Manufacturing Systems in Food Processing and Packaging Industry

    Science.gov (United States)

    Shafie Sani, Mohd; Aziz, Faieza Abdul

    2013-06-01

    In this paper, several advanced manufacturing systems in food processing and packaging industry are reviewed, including: biodegradable smart packaging and Nano composites, advanced automation control system consists of fieldbus technology, distributed control system and food safety inspection features. The main purpose of current technology in food processing and packaging industry is discussed due to major concern on efficiency of the plant process, productivity, quality, as well as safety. These application were chosen because they are robust, flexible, reconfigurable, preserve the quality of the food, and efficient.

  20. Recent advances in processing and applications of microwave ferrites

    International Nuclear Information System (INIS)

    Harris, Vincent G.; Geiler, Anton; Chen Yajie; Yoon, Soack Dae; Wu Mingzhong; Yang, Aria; Chen Zhaohui; He Peng; Parimi, Patanjali V.; Zuo Xu; Patton, Carl E.; Abe, Manasori; Acher, Olivier

    2009-01-01

    Next generation magnetic microwave devices will be planar, smaller, weigh less, and perform well beyond the present state-of-the-art. For this to become a reality advances in ferrite materials must first be realized. These advances include self-bias magnetization, tunability of the magnetic anisotropy, low microwave loss, and volumetric and weight reduction. To achieve these goals one must turn to novel materials processing methods. Here, we review recent advances in the processing of microwave ferrites. Attention is paid to the processing of ferrite films by pulsed laser deposition, liquid phase epitaxy, spin spray ferrite plating, screen printing, and compaction of quasi-single crystals. Conventional and novel applications of ferrite materials, including microwave non-reciprocal passive devices, microwave signal processing, negative index metamaterial-based electronics, and electromagnetic interference suppression are discussed.

  1. TECHNOLOGY SUMMARY ADVANCING TANK WASTE RETRIEVAL AND PROCESSING

    Energy Technology Data Exchange (ETDEWEB)

    SAMS TL; MENDOZA RE

    2010-08-11

    This technology overview provides a high-level summary of technologies being investigated and developed by Washington River Protection Solutions (WRPS) to advance Hanford Site tank waste retrieval and processing. Technology solutions are outlined, along with processes and priorities for selecting and developing them.

  2. TECHNOLOGY SUMMARY ADVANCING TANK WASTE RETREIVAL AND PROCESSING

    Energy Technology Data Exchange (ETDEWEB)

    SAMS TL

    2010-07-07

    This technology overview provides a high-level summary of technologies being investigated and developed by Washington River Protection Solutions (WRPS) to advance Hanford Site tank waste retrieval and processing. Technology solutions are outlined, along with processes and priorities for selecting and developing them.

  3. Advances in the Process Development of Biocatalytic Processes

    DEFF Research Database (Denmark)

    Tufvesson, Pär; Lima Ramos, Joana; Al-Haque, Naweed

    2013-01-01

    Biocatalysis is already established in chemical synthesis on an industrial scale, in particular in the pharmaceutical sector. However, the wider implementation of biocatalysis is currently hindered by the extensive effort required to develop a competitive process. In order that resources spent...

  4. Spatial Analysis of Depots for Advanced Biomass Processing

    Energy Technology Data Exchange (ETDEWEB)

    Hilliard, Michael R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Brandt, Craig C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Webb, Erin [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Sokhansanj, Shahabaddine [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Eaton, Laurence M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Martinez Gonzalez, Maria I. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2014-09-01

    The objective of this work was to perform a spatial analysis of the total feedstock cost at the conversion reactor for biomass supplied by a conventional system and an advanced system with depots to densify biomass into pellets. From these cost estimates, the conditions (feedstock cost and availability) for which advanced processing depots make it possible to achieve cost and volume targets can be identified.

  5. Hydrothermal liquefaction of Spirulina and Nannochloropsis Salina under subcritical and supercritical water conditions

    DEFF Research Database (Denmark)

    Toor, Saqib; Reddy, H.; Deng, S.

    2013-01-01

    residue, and recycling process water for algae cultivation. GC-MS, elemental analyzer, FT-IR, calorimeter and nutrient analysis were used to analyze bio-crude, lipid-extracted algae and water samples produced in the hydrothermal liquefaction process. The highest bio-crude yield of 46% was obtained...

  6. Report on results of R and D of coal liquefaction technology in fiscal 1981; 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu seika setsumeisho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    This paper explains the results of development of coal liquefaction technology under the Sunshine Project in fiscal 1981. In connection with solvent extraction and liquefaction, an 1 t/day experimental plant was completed for bituminous coals and operated continuously for 153 hours. An examination also started for the development of a 250 t/day pilot plant. As the element studies, R and D is in progress on the solvent extraction and liquefaction process, solid-liquid separation, secondary hydrogenation, and plant materials. In brown coals, the construction work of a 50 t/day pilot plant started for the purpose of establishing liquefaction technology for brown coal in Victoria State, Australia, with a part of the equipment manufactured. As the element studies, research was conducted on primary hydrogenation, deliming, secondary hydrogenation, dehydration and catalysts. In solvolysis liquefaction, a short-time concluding liquefaction reaction was continuously performed by a plant of 1 t/day scale. In direct hydro-liquefaction, a 2.4 t/day experimental plant was constructed, with the element studies conducted successively. In other words, researches were carried out by the bench scale plant on liquefaction, solid-liquid separation, iron-based catalysts, catalyst and reutilization, motive force recovery system by hydrohoist, and effect of preheating and deaeration. (NEDO)

  7. Development of Operational Parameters for Advanced Voloxidation Process at KAERI

    International Nuclear Information System (INIS)

    Lee, Jae Won; Park, J. J.; Shin, J. M.; Yun, Y. W.; Park, G. I.; Lee, J. W.

    2010-10-01

    KAERI has been developing a voloxidation process as a head-end process of pyroprocessing technology with INL (Idaho National Laboratory). The work scope of KAERI is to develop the operation parameters for advanced voloxidation process at KAERI using surrogate materials and SIMFUEL. In order to evaluate operation conditions of an advanced voloxidation process, oxidation and vaporization behavior of metals and Cs compounds was investigated in terms of thermal treatment atmosphere and temperature by using thermodynamic data. And also, the oxidation and vaporization behavior of semi-volatile fission products with process pressure and temperature was investigated using surrogate materials. Particle size control for U 3 O 8 powder was investigated using SIMFUEL and a rotary voloxidizer. According to analysis of KAERI works, the operation conditions for advanced voloxiation process may be consisted of the following four steps: 1) oxidation of UO 2 pellet into U 3 O 8 powder at 500 .deg. C in oxidative atmosphere, 2) additional oxidation of noble metal alloy and vaporization of high vapor pressure of fission products at 700 .deg. C in oxidative atmosphere, 3) granulation of U 3 O 8 powder and vaporization of Cs compounds at 1200 .deg. C in an atmosphere of argon, and 4) reduction of UO 2+x granules into UO 2 granules at 1000 .deg. C in an atmosphere of 4%H 2 -Ar. This report will be used as a useful means for determining the operation parameters for advanced voloxidation process

  8. Assessment of materials selection and performance for direct-coal- liquefaction plants in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Olsen, A.R.; Judkins, R.R.; Keiser, J.R.

    1996-09-01

    Several direct coal liquefaction processes have been demonstrated at the pilot plant level in the United States. Presently only one plant remains operational, namely, the Hydrocarbon Technologies, Inc., 4.0- ton-per-day process development unit in Lawrenceville, New Jersey. The period from 1974 to 1982 saw the greatest amount of development of direct coal liquefaction in the United States with four major pilot plants being devoted to variants of this technology. The plants included the SRC-I plant at Wilsonville, Alabama, which operated from 1974 to 1992; the SRC-I/II plant at Fort Lewis, Washington, which operated from 1974 to 1981; the H-Coal plant at Catlettsburg, Kentucky, which operated from 1980 to 1982; and the Exxon Coal Liquefaction Pilot Plant at Baytown, Texas, which operated from 1980 to 1982. Oak Ridge National Laboratory scientists and engineers were actively involved in many phases and technical disciplines at all four of these plants, especially in materials testing, evaluation, and failure analyses. In addition, ORNL materials scientists and engineers conducted reviews of the demonstration and commercial plant designs for materials selections. The ORNL staff members worked closely with materials engineers at the pilot plants in identifying causes of materials degradation and failures, and in identifying solutions to these problems. This report provides a comprehensive summary of those materials activities. Materials performance data from laboratory and coal liquefaction pilot plant tests, failure analyses, and analyses of components after use in pilot plants were reviewed and assessed to determine the extent and causes of materials degradation in direct coal liquefaction process environments. Reviews of demonstration and commercial plant design documents for materials selections were conducted. These reviews and assessments are presented to capture the knowledge base on the most likely materials of construction for direct coal liquefaction plants.

  9. Thermostable endoglucanases in the liquefaction of hydrothermally pretreated wheat straw

    Directory of Open Access Journals (Sweden)

    Siika-aho Matti

    2011-01-01

    Full Text Available Abstract Background Thermostable enzymes have several benefits in lignocellulose processing. In particular, they potentially allow the use of increased substrate concentrations (because the substrate viscosity decreases as the temperature increases, resulting in improved product yields and reduced capital and processing costs. A short pre-hydrolysis step at an elevated temperature using thermostable enzymes aimed at rapid liquefaction of the feedstock is seen as an attractive way to overcome the technical problems (such as poor mixing and mass transfer properties connected with high initial solid loadings in the lignocellulose to ethanol process. Results The capability of novel thermostable enzymes to reduce the viscosity of high-solid biomass suspensions using a real-time viscometric measurement method was investigated. Heterologously expressed enzymes from various thermophilic organisms were compared for their ability to liquefy the lignocellulosic substrate, hydrothermally pretreated wheat straw. Once the best enzymes were identified, the optimal temperatures for these enzymes to decrease substrate viscosity were compared. The combined hydrolytic properties of the thermostable preparations were tested in hydrolysis experiments. The studied mixtures were primarily designed to have good liquefaction potential, and therefore contained an enhanced proportion of the key liquefying enzyme, EGII/Cel5A. Conclusions Endoglucanases were shown to have a superior ability to rapidly reduce the viscosity of the 15% (w/w; dry matter hydrothermally pretreated wheat straw. Based on temperature profiling studies, Thermoascus aurantiacus EGII/Cel5A was the most promising enzyme for biomass liquefaction. Even though they were not optimized for saccharification, many of the thermostable enzyme mixtures had superior hydrolytic properties compared with the commercial reference enzymes at 55°C.

  10. Numerical analysis of stone columns in mitigating liquefaction effects in embankment fills

    Energy Technology Data Exchange (ETDEWEB)

    Borghei, Z.; Soroush, A. [Amirkabir University of Technology, Tehran, (Iran, Islamic Republic of); Noorzad, A. [Power and Water University of Technology, Tehran, (Iran, Islamic Republic of)

    2010-07-01

    The traditional approach to liquefaction in embankment fills is to use in-situ densification. The use of stone columns offers the possibility of preventing liquefaction and associated settlements while reducing the cost and time required for treatment. This paper investigated the behaviour of stone columns using a numerical method. The study focused on a case study, a sand layer beneath two wall tanks, butane and propane NGL, located on Siri Island, Persian Gulf, Iran. Numerical analyses were carried out to evaluate the rate of excess pore pressure build-up in the improved ground. The numerical model results were compared to the simulation results from a centrifuge test for a uniform 19m-thick liquefiable sand layer. The numerical methodology was verified. The results showed that the stone columns can significantly increase the rate of pore pressure dissipation and reduce the settlement. It was found that the installation process densifies the surrounding soil, decreasing the liquefaction potential.

  11. Efficient direct coal liquefaction of a premium brown coal catalyzed by cobalt-promoted fumed oxides

    Energy Technology Data Exchange (ETDEWEB)

    Trautmann, M.; Loewe, A.; Traa, Y. [Stuttgart Univ. (Germany). Inst. of Chemical Technology

    2013-11-01

    The search for alternatives in the fuel sector is an important technological challenge. An interim solution could be provided by direct coal liquefaction. Hydrogen economy and the lack of an efficient catalyst are the main obstacles for this process. We used a premium German brown coal with a high H/C molar ratio of 1.25 and nanostructured cobalt catalysts to improve the efficiency of direct coal liquefaction. We were able to recover and recycle the catalyst efficiently and reached good brown coal conversions and oil yields with single-stage coal liquefaction. The oil quality observed almost reached that of a conventional crude oil considering higher heating value (HHV), H/C molar ratio and aliphatic content. (orig.)

  12. Economics of coal conversion processing. Advances in coal gasification: support research. Advances in coal gasification: process development and analysis

    Energy Technology Data Exchange (ETDEWEB)

    1978-01-01

    The fall meeting of the American Chemical Society, Division of Fuel Chemistry, was held at Miami Beach, Florida, September 10-15, 1978. Papers involved the economics of coal conversion processing and advances in coal gasification, especially support research and process development and analysis. Fourteen papers have been entered individually into EDB and ERA; three papers had been entered previously from other sources. (LTN)

  13. GEOTECHNICAL/GEOCHEMICAL CHARACTERIZATION OF ADVANCED COAL PROCESS WASTE STREAMS

    Energy Technology Data Exchange (ETDEWEB)

    Edwin S. Olson; Charles J. Moretti

    1999-11-01

    Thirteen solid wastes, six coals and one unreacted sorbent produced from seven advanced coal utilization processes were characterized for task three of this project. The advanced processes from which samples were obtained included a gas-reburning sorbent injection process, a pressurized fluidized-bed coal combustion process, a coal-reburning process, a SO{sub x}, NO{sub x}, RO{sub x}, BOX process, an advanced flue desulfurization process, and an advanced coal cleaning process. The waste samples ranged from coarse materials, such as bottom ashes and spent bed materials, to fine materials such as fly ashes and cyclone ashes. Based on the results of the waste characterizations, an analysis of appropriate waste management practices for the advanced process wastes was done. The analysis indicated that using conventional waste management technology should be possible for disposal of all the advanced process wastes studied for task three. However, some wastes did possess properties that could present special problems for conventional waste management systems. Several task three wastes were self-hardening materials and one was self-heating. Self-hardening is caused by cementitious and pozzolanic reactions that occur when water is added to the waste. All of the self-hardening wastes setup slowly (in a matter of hours or days rather than minutes). Thus these wastes can still be handled with conventional management systems if care is taken not to allow them to setup in storage bins or transport vehicles. Waste self-heating is caused by the exothermic hydration of lime when the waste is mixed with conditioning water. If enough lime is present, the temperature of the waste will rise until steam is produced. It is recommended that self-heating wastes be conditioned in a controlled manner so that the heat will be safely dissipated before the material is transported to an ultimate disposal site. Waste utilization is important because an advanced process waste will not require

  14. Biomass Indirect Liquefaction Strategy Workshop Summary Report

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2014-07-01

    This report is based on the proceedings of the U.S. Department of Energy Bioenergy Technologies Office Biomass Indirect Liquefaction Strategy Workshop. The workshop, held March 20–21, 2014, in Golden, Colorado, discussed and detailed the research and development needs for biomass indirect liquefaction. Discussions focused on pathways that convert biomass-based syngas (or any carbon monoxide, hydrogen gaseous stream) to liquid intermediates (alcohols or acids) and further synthesize those intermediates to liquid hydrocarbons that are compatible as either a refinery feed or neat fuel.

  15. Liquefaction chemistry and kinetics: Hydrogen utilization studies

    Energy Technology Data Exchange (ETDEWEB)

    Rothenberger, K.S.; Warzinski, R.P.; Cugini, A.V. [Pittsburgh Energy Technology Center, PA (United States)] [and others

    1995-12-31

    The objectives of this project are to investigate the chemistry and kinetics that occur in the initial stages of coal liquefaction and to determine the effects of hydrogen pressure, catalyst activity, and solvent type on the quantity and quality of the products produced. The project comprises three tasks: (1) preconversion chemistry and kinetics, (2) hydrogen utilization studies, and (3) assessment of kinetic models for liquefaction. The hydrogen utilization studies work will be the main topic of this report. However, the other tasks are briefly described.

  16. Liquefaction of Saturated Soil and the Diffusion Equation

    Science.gov (United States)

    Sawicki, Andrzej; Sławińska, Justyna

    2015-06-01

    The paper deals with the diffusion equation for pore water pressures with the source term, which is widely promoted in the marine engineering literature. It is shown that such an equation cannot be derived in a consistent way from the mass balance and the Darcy law. The shortcomings of the artificial source term are pointed out, including inconsistencies with experimental data. It is concluded that liquefaction and the preceding process of pore pressure generation and the weakening of the soil skeleton should be described by constitutive equations within the well-known framework of applied mechanics. Relevant references are provided

  17. Rationale for continuing R&D in indirect coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Gray, D.; Tomlinson, G. [MITRE Corp., McLean, VA (United States)

    1995-12-31

    The objective of this analysis is to use the world energy demand/supply model developed at MITRE to examine future liquid fuels supply scenarios both for the world and for the United States. This analysis has determined the probable extent of future oil resource shortages and the likely time frame in which the shortages will occur. The role that coal liquefaction could play in helping to alleviate this liquid fuels shortfall is also examined. The importance of continuing R&D to improve process performance and reduce the costs of coal-derived transportation fuel is quantified in terms of reducing the time when coal liquids will become competitive with petroleum.

  18. Adding structure to the transition process to advanced mathematical activity

    Science.gov (United States)

    Engelbrecht, Johann

    2010-03-01

    The transition process to advanced mathematical thinking is experienced as traumatic by many students. Experiences that students had of school mathematics differ greatly to what is expected from them at university. Success in school mathematics meant application of different methods to get an answer. Students are not familiar with logical deductive reasoning, required in advanced mathematics. It is necessary to assist students in this transition process, in moving from general to mathematical thinking. In this article some structure is suggested for this transition period. This essay is an argumentative exposition supported by personal experience and international literature. This makes this study theoretical rather than empirical.

  19. Report on the achievements in the Sunshine Project in fiscal 1988. Development of a collection and processing system for data of the coal liquefaction process; 1988 nendo sekitan ekika process nado no data no shushu, shori system nado no kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1989-03-01

    Storing and managing comprehensively a huge amount of data acquired in developing the coal liquefaction technologies would greatly contribute to moving forward the development of the coal liquefaction technologies, and realizing a commercial plant being the ultimate goal. It is intended to investigate the current status of information management systems used for development projects being implemented or planned in developing the coal liquefaction technologies. It is also intended to structure a coal liquefaction database system to utilize comprehensively and effective the information discovered by the above investigation. The current fiscal year has performed developments on the following items to structure a coal liquefaction database system by using a computer: (1) conceptual design of the fundamental database, and (2) basic design on a general technological information retrieval system. The development during the current fiscal year established a method to classify levels of data accommodation for the fundamental database based on the investigation and analysis of the experimental data. In addition, with regard to the general technological information retrieval system, summarization was performed on the specifications of the hardware and software, the basic configuration, the input and output specifications, and the retrieval screens. (NEDO)

  20. Electron processing of fibre-reinforced advanced composites

    International Nuclear Information System (INIS)

    Singh, A.; Saunders, C.B.; Barnard, J.W.; Lopata, V.J.; Kremers, W.; McDougall, T.E.; Chung, M.; Tateishi, Miyoko

    1996-01-01

    Advanced composites, such as carbon-fibre-reinforced epoxies, are used in the aircraft, aerospace, sporting goods, and transportation industries. Though thermal curing is the dominant industrial process for advanced composites, electron curing of similar composites containing acrylated epoxy matrices has been demonstrated by our work. The main attraction of electron processing technology over thermal technology is the advantages it offers which include ambient temperature curing, reduced curing times, reduced volatile emissions, better material handling, and reduced costs. Electron curing technology allows for the curing of many types of products, such as complex shaped, those containing different types of fibres and up to 15 cm thick. Our work has been done principally with the AECL's 10 MeV, 1 kW electron accelerator; we have also done some comparative work with an AECL Gammacell 220. In this paper we briefly review our work on the various aspects of electron curing of advanced composites and their properties. (Author)

  1. Electron processing of fibre-reinforced advanced composites

    Energy Technology Data Exchange (ETDEWEB)

    Singh, A.; Saunders, C.B.; Barnard, J.W.; Lopata, V.J.; Kremers, W.; McDougall, T.E.; Chung, M.; Tateishi, Miyoko [Atomic Energy of Canada Ltd., Pinawa, MB (Canada). Whiteshell Labs.

    1996-08-01

    Advanced composites, such as carbon-fibre-reinforced epoxies, are used in the aircraft, aerospace, sporting goods, and transportation industries. Though thermal curing is the dominant industrial process for advanced composites, electron curing of similar composites containing acrylated epoxy matrices has been demonstrated by our work. The main attraction of electron processing technology over thermal technology is the advantages it offers which include ambient temperature curing, reduced curing times, reduced volatile emissions, better material handling, and reduced costs. Electron curing technology allows for the curing of many types of products, such as complex shaped, those containing different types of fibres and up to 15 cm thick. Our work has been done principally with the AECL`s 10 MeV, 1 kW electron accelerator; we have also done some comparative work with an AECL Gammacell 220. In this paper we briefly review our work on the various aspects of electron curing of advanced composites and their properties. (Author).

  2. Improvements on mapping soil liquefaction at a regional scale

    Science.gov (United States)

    Zhu, Jing

    Earthquake induced soil liquefaction is an important secondary hazard during earthquakes and can lead to significant damage to infrastructure. Mapping liquefaction hazard is important in both planning for earthquake events and guiding relief efforts by positioning resources once the events have occurred. This dissertation addresses two aspects of liquefaction hazard mapping at a regional scale including 1) predictive liquefaction hazard mapping and 2) post-liquefaction cataloging. First, current predictive hazard liquefaction mapping relies on detailed geologic maps and geotechnical data, which are not always available in at-risk regions. This dissertation improves the predictive liquefaction hazard mapping by the development and validation of geospatial liquefaction models (Chapter 2 and 3) that predict liquefaction extent and are appropriate for global application. The geospatial liquefaction models are developed using logistic regression from a liquefaction database consisting of the data from 27 earthquake events from six countries. The model that performs best over the entire dataset includes peak ground velocity (PGV), VS30, distance to river, distance to coast, and precipitation. The model that performs best over the noncoastal dataset includes PGV, VS30, water table depth, distance to water body, and precipitation. Second, post-earthquake liquefaction cataloging historically relies on field investigation that is often limited by time and expense, and therefore results in limited and incomplete liquefaction inventories. This dissertation improves the post-earthquake cataloging by the development and validation of a remote sensing-based method that can be quickly applied over a broad region after an earthquake and provide a detailed map of liquefaction surface effects (Chapter 4). Our method uses the optical satellite images before and after an earthquake event from the WorldView-2 satellite with 2 m spatial resolution and eight spectral bands. Our method

  3. An advanced purex process based on salt-free reductants

    Energy Technology Data Exchange (ETDEWEB)

    He, Hui; Ye, Guoan; Tang, Hongbin; Zheng, Weifang; Li, Gaoliang; Lin, Rushan [China Institute of Atomic Energy, Beijing (China). Dept. of Radiochemistry

    2014-04-01

    An advanced plutonium and uranium recovery process has been established based on two organic reductants, N,N-dimethylhydroxylamine (DMHAN) and methylhydrazine (MH), as U/Pu separation reagents. This Advanced Purex process based on Organic Reductants (APOR) is composed of three cycles, including U/Pu co-decontamination/separation cycle, uranium purification cycle and plutonium purification cycle. Using DMHAN and MH as plutonium stripping reagents in the U/Pu co-decontamination/separation cycle and plutonium purification cycle, the APOR process exhibits high performance with following highlights: (1) the process is much simpler because of the elimination of Tc scrubbing operation and the supplement extraction operation, (2) high efficiency of U/Pu separation can be achieved in the first cycle, (3) plutonium product solution of high concentration can be obtained in the Pu purification cycle with a simple extraction operation instead of circumfluent extraction or evaporation of the plutonium solution. (orig.)

  4. Microeconomics of advanced process window control for 50-nm gates

    Science.gov (United States)

    Monahan, Kevin M.; Chen, Xuemei; Falessi, Georges; Garvin, Craig; Hankinson, Matt; Lev, Amir; Levy, Ady; Slessor, Michael D.

    2002-07-01

    Fundamentally, advanced process control enables accelerated design-rule reduction, but simple microeconomic models that directly link the effects of advanced process control to profitability are rare or non-existent. In this work, we derive these links using a simplified model for the rate of profit generated by the semiconductor manufacturing process. We use it to explain why and how microprocessor manufacturers strive to avoid commoditization by producing only the number of dies required to satisfy the time-varying demand in each performance segment. This strategy is realized using the tactic known as speed binning, the deliberate creation of an unnatural distribution of microprocessor performance that varies according to market demand. We show that the ability of APC to achieve these economic objectives may be limited by variability in the larger manufacturing context, including measurement delays and process window variation.

  5. Advanced Process Control Application and Optimization in Industrial Facilities

    Directory of Open Access Journals (Sweden)

    Howes S.

    2015-01-01

    Full Text Available This paper describes application of the new method and tool for system identification and PID tuning/advanced process control (APC optimization using the new 3G (geometric, gradient, gravity optimization method. It helps to design and implement control schemes directly inside the distributed control system (DCS or programmable logic controller (PLC. Also, the algorithm helps to identify process dynamics in closed-loop mode, optimizes controller parameters, and helps to develop adaptive control and model-based control (MBC. Application of the new 3G algorithm for designing and implementing APC schemes is presented. Optimization of primary and advanced control schemes stabilizes the process and allows the plant to run closer to process, equipment and economic constraints. This increases production rates, minimizes operating costs and improves product quality.

  6. Evaluation of the effect of advanced coagulation process to optimize ...

    African Journals Online (AJOL)

    Evaluation of the effect of advanced coagulation process to optimize the removal of natural organic matter in water (Case study: drinking water of Mashhad's ... and in addition to giving taste, color and odor to the water, they can intervene in the oxidization and removal of heavy metals such as arsenic, iron and manganese.

  7. Adding Structure to the Transition Process to Advanced Mathematical Activity

    Science.gov (United States)

    Engelbrecht, Johann

    2010-01-01

    The transition process to advanced mathematical thinking is experienced as traumatic by many students. Experiences that students had of school mathematics differ greatly to what is expected from them at university. Success in school mathematics meant application of different methods to get an answer. Students are not familiar with logical…

  8. Advanced multiresponse process optimisation an intelligent and integrated approach

    CERN Document Server

    Šibalija, Tatjana V

    2016-01-01

    This book presents an intelligent, integrated, problem-independent method for multiresponse process optimization. In contrast to traditional approaches, the idea of this method is to provide a unique model for the optimization of various processes, without imposition of assumptions relating to the type of process, the type and number of process parameters and responses, or interdependences among them. The presented method for experimental design of processes with multiple correlated responses is composed of three modules: an expert system that selects the experimental plan based on the orthogonal arrays; the factor effects approach, which performs processing of experimental data based on Taguchi’s quality loss function and multivariate statistical methods; and process modeling and optimization based on artificial neural networks and metaheuristic optimization algorithms. The implementation is demonstrated using four case studies relating to high-tech industries and advanced, non-conventional processes.

  9. Advanced Purex process for the new French reprocessing plants

    International Nuclear Information System (INIS)

    Viala, M.; Ledermann, P.; Pradel, P.

    1993-01-01

    The paper describes the main process innovations of the new Cogema reprocessing plants of La Hague (UP3 and UP2 800). Major improvements of process like the use of rotary dissolvers and annular columns, and also entirely new processes like solvent distillation and plutonium oxidizing dissolution, yield an advanced Purex process. The results of these innovations are significant improvements for throughput, end-products purification performances and waste minimization. They contribute also to limit personnel exposure. The main results of the first three years of operation are described. (author). 3 refs., 5 figs

  10. Status of health and environmental research relative to direct coal liquefaction: 1976 to the present

    Energy Technology Data Exchange (ETDEWEB)

    Gray, R.H.; Cowser, K.E. (eds.)

    1982-06-01

    This document describes the status of health and environmental research efforts, supported by the US Department of Energy (DOE), to assist in the development of environmentally acceptable coal liquefaction processes. Four major direct coal liquefaction processes are currently in (or have been investigated at) the pilot plant stage of development. Two solvent refined coal processes (SRC-I and -II), H-coal (a catalytic liquefaction process) and Exxon donor solvent (EDS). The Pacific Northwest Laboratory was assigned responsibility for evaluating SRC process materials and prepared comprehensive health and environmental effects research program plans for SRC-I and -II. A similar program plan was prepared for H-coal process materials by the Oak Ridge National Laboratory. A program has been developed for EDS process materials by Exxon Research and Engineering Co. The program includes short-term screening of coal-derived materials for potential health and ecological effects. Longer-term assays are used to evaluate materials considered most representative of potential commercial practice and with greatest potential for human exposure or release to the environment. Effects of process modification, control technologies and changing operational conditions on potential health and ecological effects are also being evaluated. These assessments are being conducted to assist in formulating cost-effective environmental research programs and to estimate health and environmental risks associated with a large-scale coal liquefaction industry. Significant results of DOE's health and environmental research efforts relative to coal liquefaction include the following: chemical characterization, health effects, ecological fate and effects, amelioration and risk assessment.

  11. Dispersed-phase catalysis in coal liquefaction

    International Nuclear Information System (INIS)

    Utz, B.R.; Cugini, A.V.; Frommell, E.A.

    1990-01-01

    This paper reports that the specific reaction (activation) conditions for the conversion of catalyst precursors to unsupported catalyst have a direct effect on the catalytic activity and dispersion. The importance of reaction intermediates in decomposition of ammonium heptamolybdate and ammonium tetrathiomolybdate, and the sensitivity of these intermediates to reaction conditions, were studied in coal liquefaction systems. Recent results indicate that optimization of activation conditions facilitates the formation of a highly dispersed and active form of molybdenum disulfide for coal liquefaction. The use of the catalyst precursors ammonium heptamolybdate, ammonium tetrathiomolybdate, and molybdenum trisulfide for the conversion of coal to soluble products will be discussed. The use of an unsupported dispersed-phase catalyst for direct coal liquefaction is not a novel concept and has been employed in may studies with varying success. Dispersed-phase catalysts soluble and oil-soluble salts, and as finely divided powders. While some methods of catalyst introduction give higher dispersion of the catalyst and greater activity for the liquefaction of coal, all of the techniques allow the formation of a finely dispersed inorganic phase

  12. Evaluating liquefaction potential. A case history

    International Nuclear Information System (INIS)

    Blystra, A.R.

    1991-01-01

    Several earthen hydropower embankment dams in the midwestern United States were constructed using hydraulic fill methods and are liable to liquefaction during an earthquake due to the use of very loose, saturated sand in the embankment or foundations. A case history is presented describing the methodology used in evaluating the liquefaction potential of the largest earthfill dam in Michigan. The methodology includes the use of standard penetration and cone penetration test data in the formulation of a simplified procedure. Field investigations, laboratory testing, and analyses used are described. In addition to the drilling program, field work included an extensive ground penetrating radar survey, acoustic emission testing, and an electrical resistivity survey. It was found that the lowest calculated factor of safety against liquefaction is 0.63 for a loose zone ca 140 feet below the top of the embankment, and the factor of safety against slope failure, should the zone liquefy, is 1.49. It was concluded that while liquefaction is possible, post earthquake stability is adequate. 6 refs., 3 figs., 1 tab

  13. Renewable hydrocarbon fuels from hydrothermal liquefaction: A techno-economic analysis

    DEFF Research Database (Denmark)

    Pedersen, Thomas Helmer; Hansen, Nick Høy; Pérez, Oscar Miralles

    2018-01-01

    This study demonstrates the economic feasibility of producing renewable transportation drop-in fuels from lignocellulosic biomass through hydrothermal liquefaction and upgrading. An Aspen Plus® process model is developed based on extensive experimental data to document a techno-economic assessmen...

  14. Advances in chemical engineering in nuclear and process industries

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-06-01

    Symposium on Advances in Chemical Engineering in Nuclear and Process Industries dealt with a wide spectrum of areas encompassing various industries such as nuclear, fertilizer, petrochemical, refinery and cement. The topics covered in the symposium dealt with the advancements in the existing fields of science and technologies as well as in some of the emerging technologies such as membrane technology, bio-chemical and photo-chemical engineering etc. with a special emphasis on nuclear related aspects. Papers relevant to INIS are indexed separately.

  15. Advances in chemical engineering in nuclear and process industries

    International Nuclear Information System (INIS)

    1994-06-01

    Symposium on Advances in Chemical Engineering in Nuclear and Process Industries dealt with a wide spectrum of areas encompassing various industries such as nuclear, fertilizer, petrochemical, refinery and cement. The topics covered in the symposium dealt with the advancements in the existing fields of science and technologies as well as in some of the emerging technologies such as membrane technology, bio-chemical and photo-chemical engineering etc. with a special emphasis on nuclear related aspects. Papers relevant to INIS are indexed separately

  16. Recent advances in fuel product and manufacturing process development

    International Nuclear Information System (INIS)

    Slember, R.J.; Doshi, P.K.

    1987-01-01

    This paper discusses advancements in commercial nuclear fuel products and manufacturing made by the Westinghouse Electric Corporation in response to the commercial nuclear fuel industry's demand for high reliability, increased plant availability and improved operating flexibility. The features and benefits of Westinghouse's most advanced fuel products--VANTAGE 5 for PWR plants and QUAD+ for BWR plants--are described, as well as 'high performance' fuel concepts now under development for delivery in the late 1980s. The paper also disusses the importance of in-process quality control throughout manufacturing towards reducing product variability and improving fuel reliability. (author)

  17. Simulation and Optimization of an Innovative Dual Mixed Component Refrigerant Cycle (DMRC) for Natural Gas Offshore Liquefaction Plants

    International Nuclear Information System (INIS)

    SHAHBA, L.A.; Fahmy, M.F.M.

    2004-01-01

    Simulation and optimization of an innovative liquefaction process used for the LNG production , namely the Dual Mixed Refrigerant Process (DMRC) has been conducted using the HYSYS simulator .This new process is especially suitable for off shore natural gas liquefaction plants. A numerical optimization technique has been used to determine the optimum conditions for Egyptian natural gas feed source. The investigation of the effect of different compositions of the Mixed refrigerants used was conducted. Meanwhile, the investigation of the influence of the temperature of cooling water used was conducted. The best optimum conditions for the DMRC process were determined .The optimum results achieved for the DMRC process revealed that the DMRC process can be successfully applied as a promising technique for off shore natural gas liquefaction plants

  18. FY 1974 report on the results of the Sunshine Project. Study on a system to refine/transport/store hydrogen and the safety technology (Investigational study of behavior of trace impurities in the liquefaction process); 1974 nendo suiso no seisei, yuso, chozo system oyobi hoan gijutsu ni kansuru kenkyu seika hokokusho. Ekika katei ni okeru biryo fujunbutsu no kyodo ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1975-05-28

    Hydrogen gas as material is produced mostly by steam reforming of hydrocarbons, and includes a considerable amount of impurities such as carbon dioxide, nitrogen and oxygen. The concentration of impurities in the refined gas is approximately 1ppm. In the liquefaction process of hydrogen liquefaction plant, the gases entering the low temperature portion near the free expansion valve (J-T valve) are mostly oxygen and nitrogen. When oxygen is solidified, attached, accumulated near J-T valve, it incurs a possibility of exploding for reason of impact force, etc. by contact with the valve portion. A mixture of hydrogen and oxygen ignites at the minimum value of approximately 0.02 milli-joule, and therefore it has great danger of explosion. As viewed from a point of danger prevention, there is a possibility of explosion when the hydrogen-oxidizing agent mixture is formed. Accordingly, it is necessary to conduct an experiment for confirming the explosion at J-T valve portion. From viewpoints of prevention of explosion accident and running operation, it is necessary to experimentally grasp the definite allowable oxygen concentration. Further, it is necessary to establish a technology to continuously and accurately measure the concentration of trace impurities in hydrogen gas. (NEDO)

  19. Low-Cost Methane Liquefaction Plant and Vehicle Refueling Station

    International Nuclear Information System (INIS)

    Wilding, B.; Bramwell, D.

    1999-01-01

    The Idaho National Engineering and Environmental Laboratory (INEEL) is currently negotiating a collaborative effort with Pacific Gas and Electric (PG and E) that will advance the use of liquefied natural gas (LNG) as a vehicle fuel. We plan to develop and demonstrate a small-scale methane liquefaction plant (production of 5,000 to 10,000 gallons per day) and a low-cost ($150,000) LNG refueling station to supply fuel to LNG-powered transit buses and other heavy-duty vehicles. INEEL will perform the research and development work. PG and E will deploy the new facilities commercially in two demonstration projects, one in northern California, and one in southern California

  20. Advanced Signal Processing for MIMO-OFDM Receivers

    DEFF Research Database (Denmark)

    Manchón, Carles Navarro

    This thesis deals with a wide range of topics within the research area of advanced baseband receiver design for wireless communication systems. In particular, the work focuses on signal processing algorithms for receivers in multiple-input multiple-output (MIMO) orthogonal frequency-division mult......This thesis deals with a wide range of topics within the research area of advanced baseband receiver design for wireless communication systems. In particular, the work focuses on signal processing algorithms for receivers in multiple-input multiple-output (MIMO) orthogonal frequency...... the structure of the receiver with the hope that the resulting heuristic architecture will exhibit the desired behavior and performance. On the other hand, one can employ analytical frameworks to pose the problem as the optimization of a global objective function subject to certain constraints. This work...

  1. Fiscal 1994 report. Liquefaction key technology subcommittee; 1994 nendo ekika kiban gijutsu bukai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The subcommittee held the 1st meeting in August 1994 and the 2nd in March 1995, when preceding fiscal year's research results, fiscal 1994 research plans, fiscal 1994 research results, etc., were introduced, and deliberated. In the study of hydrorefining of naphtha, kerosene, and light oil fractions, a nitrogen concentration level of not more than 5 ppm was achieved by refining oils from Indonesian coal. Studies were also made about the two-step hydrorefining system, the relationship between the coal oil refining level and sludge formation, etc. In the research for the development of novel catalysts for upgrading coal oil, the active life of a nickel-supporting catalyst for hydrogenation at the 1st step was somewhat prolonged with an increase in the amount of nickel. In the study of coal liquefaction conditions, an AWIP method was deliberated, wherein liquefaction process waste water was utilized as one of catalytic component adjusting materials. For upgrading liquefaction key technologies, studies were made for catalyst improvement and pretreatment method development, and about the behavior of liquefaction reaction in a high boiling solvent-aided process. (NEDO)

  2. Supply Chain Sustainability Analysis of Indirect Liquefaction of Blended Biomass to Produce High Octane Gasoline

    Energy Technology Data Exchange (ETDEWEB)

    Cai, Hao [Argonne National Lab. (ANL), Argonne, IL (United States); Canter, Christina E. [Argonne National Lab. (ANL), Argonne, IL (United States); Dunn, Jennifer B. [Argonne National Lab. (ANL), Argonne, IL (United States); Tan, Eric [National Renewable Energy Lab. (NREL), Golden, CO (United States); Biddy, Mary [National Renewable Energy Lab. (NREL), Golden, CO (United States); Talmadge, Michael [National Renewable Energy Lab. (NREL), Golden, CO (United States); Hartley, Damon [Idaho National Lab. (INL), Idaho Falls, ID (United States); Searcy, Erin [Idaho National Lab. (INL), Idaho Falls, ID (United States); Snowden-Swan, Lesley [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-03-01

    This report describes the SCSA of the production of renewable high octane gasoline (HOG) via indirect liquefaction (IDL) of lignocellulosic biomass. This SCSA was developed for both the 2015 SOT (Hartley et al., 2015; ANL, 2016; DOE, 2016) and the 2017 design case for feedstock logistics (INL, 2014) and for both the 2015 SOT (Tan et al., 2015a) and the 2022 target case for HOG production via IDL (Tan et al., 2015b). The design includes advancements that are likely and targeted to be achieved by 2017 for the feedstock logistics and 2022 for the IDL conversion process. In the SCSA, the 2015 SOT case for the conversion process, as modeled in Tan et al. (2015b), uses the 2015 SOT feedstock blend of pulpwood, wood residue, and construction and demolition waste (C&D). Moreover, the 2022 design case for the conversion process, as described in Tan et al. (2015a), uses the 2017 design case blend of pulpwood, wood residue, switchgrass, and C&D. The performance characteristics of this blend are consistent with those of a single woody feedstock (e.g., pine or poplar). We also examined the influence of using a single feedstock type on SCSA results for the design case. These single feedstock scenarios could be viewed as bounding SCSA results given that the different components of the feedstock blend have varying energy and material demands for production and logistics.

  3. Advanced information processing system: Input/output network management software

    Science.gov (United States)

    Nagle, Gail; Alger, Linda; Kemp, Alexander

    1988-01-01

    The purpose of this document is to provide the software requirements and specifications for the Input/Output Network Management Services for the Advanced Information Processing System. This introduction and overview section is provided to briefly outline the overall architecture and software requirements of the AIPS system before discussing the details of the design requirements and specifications of the AIPS I/O Network Management software. A brief overview of the AIPS architecture followed by a more detailed description of the network architecture.

  4. Efficient Air Desulfurization Catalysts Derived from Pig Manure Liquefaction Char

    Directory of Open Access Journals (Sweden)

    Rajiv Wallace

    2017-11-01

    Full Text Available Biochar from the liquefaction of pig manure was used as a precursor of H2S desulfurization adsorbents. In its inorganic matter, it contains marked quantities of calcium, magnesium and iron, which are known as hydrogen sulfide oxidation catalysts. The char was used either as-received or mixed with 10% nanographite. The latter was added to increase both the content of the carbon phase and conductivity. ZnCl2 in two different ratios of char to an activation agent (1:1 and 1:2 was used to create the porosity in the carbon phase. The content of the later was between 18–45%. The activated samples adsorbed 144 mg/g H2S. Sulfur was the predominant product of reactive adsorption. Its deposition in the pore system and blockage of the most active pores ceased the materials’ activity. The presence of the catalytic phase was necessary but not sufficient to guarantee good performance. The developed porosity, which can store oxidation products in the resulting composite, is essential for the good performance of the desulfurization process. The surface of the composite with nanographite showed the highest catalytic activity, similar to that of the commercial Midas® carbon catalyst. The results obtained indicate that a high quality reactive adsorbent/catalyst for H2S removal can be obtained from pig manure liquefaction wastes.

  5. Raw materials for advanced ceramics: rare earths separation processes

    International Nuclear Information System (INIS)

    Ricci, D.R.; Nobre, J.S.M.; Paschoal, J.O.A.

    1990-01-01

    The importance of obtaining purified rare earths oxidesis related, mainly to the increasing use of these compounds as raw materials for advanced ceramics. Processes of rare earths separation and purification are almost always based on the solvent extraction, fractional precipitation and ion exchange chromatography techniques, whose association depends on the initial concentrate and on the desired purity. This paper describes some steps of fractionation of didymium carbonate by using the solvent extraction and fractional precipitation techniques. The experimental conditions presented here have enable the production of lantanium, neodimium - praseodimium, samarium - gadolinium and ytrium concentrates, which constitute the intermediate fractions of the overall process to obtain high purity rare earths. (author) [pt

  6. Smelting Associated with the Advanced Spent Fuel Conditioning Process

    International Nuclear Information System (INIS)

    Hur, J-M.; Jeong, M-S.; Lee, W-K.; Cho, S-H.; Seo, C-S.; Park, S-W.

    2004-01-01

    The smelting process associated with the advanced spent fuel conditioning process (ACP) of Korea Atomic Energy Research Institute was studied by using surrogate materials. Considering the vaporization behaviors of input materials, the operation procedure of smelting was set up as (1) removal of residual salts, (2) melting of metal powder, and (3) removal of dross from a metal ingot. The behaviors of porous MgO crucible during smelting were tested and the chemical stability of MgO in the salt-being atmosphere was confirmed

  7. Achievement report for fiscal 1981 on Sunshine Program-assisted project. Development of coal liquefaction plant (Research on total system); 1981 nendo sekitan ekika plant no kaihatsu (total system no kenkyu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    For a quantitative analysis of a coal liquefaction process and its constituent sub-processes from both engineering and economic viewpoints, research is conducted for the development of a coal liquefaction process simulator. In the development of a liquefaction simulator, surveys and studies are performed relative to a coal liquefaction process, which is the object of this development effort, its system, existing like simulators, computation for the estimation of the physical properties that a liquefaction simulator should be equipped with, liquefaction yield prediction model, unit operation model, etc. Based on the results of these studies, a conceptual system design is drawn, which is the first step toward the programming of a more concrete software program. Also compiled into this book are the contents of advice and guidance provided by the total system committee in the period September 1981-February 1982 on the research for the development of a liquefaction simulator, and reports by researchers who were dispatched to the U.S. etc. for the development of a coal liquefaction simulator. (NEDO)

  8. Advances and applications of optimised algorithms in image processing

    CERN Document Server

    Oliva, Diego

    2017-01-01

    This book presents a study of the use of optimization algorithms in complex image processing problems. The problems selected explore areas ranging from the theory of image segmentation to the detection of complex objects in medical images. Furthermore, the concepts of machine learning and optimization are analyzed to provide an overview of the application of these tools in image processing. The material has been compiled from a teaching perspective. Accordingly, the book is primarily intended for undergraduate and postgraduate students of Science, Engineering, and Computational Mathematics, and can be used for courses on Artificial Intelligence, Advanced Image Processing, Computational Intelligence, etc. Likewise, the material can be useful for research from the evolutionary computation, artificial intelligence and image processing co.

  9. Titanium alloys. Advances in alloys, processes, products and applications

    International Nuclear Information System (INIS)

    Blenkinsop, P.A.

    1993-01-01

    The last few years have been a period of consolidation of existing alloys and processes. While the aerospace industry remains the principal driving force for alloy development, the paper illustrates examples of new markets being established in 'older' alloys, by a combination of product/process development and a re-examination of engineering design parameters. Considerable attention is still being directed towards the titanium aluminide systems, but other more conventional alloy developments are underway aimed at specific engineering and process requirements, both in the aerospace and non-aerospace sectors. Both the advanced high temperature and conventional alloy developments are considered, before the paper goes on to assess the potential of new processes and products, like spray-forming, metal matrix composites and shaped-plate rolling. (orig.)

  10. The advances in radiation processing technology and some suggestion

    International Nuclear Information System (INIS)

    Wu Jilan; Wei Genshuan; Ha Hongfei

    1992-01-01

    Radiation processing technology has been made great advances in the last decade especially in the developed countries. According to the conservative evaluation, the total sales of radiation processing products approached about 2-3 billion U.S. dollar in 1981, there after, the processing capacity at least doubles. Now, the intensities of 60 Co in use for radiation processing are (5.55-7.40) x 10 18 Bq and there are about 600 sets of electron accelerators for radiation processing. The total sales of radiation processing products are supposed to be over 10 billion U.S. dollar in 1989. However, there are only several fields commercialized. In great scale, such as radiation crosslinked heat shrinkable materials, radiation crosslinked electric cables and wires, and radiation sterilization of medical articles. In China, the radiation processing technology has been developed rapidly in the past years, but the processing capacity is still lower in comparing with developed countries. We suggest that much attention should be devoted to the training of the workers, technicians and managers. The basic theoretical and new technological researches are the keys for developing radiation processing technology at high speed in our country

  11. Fiscal 1989 report on the bituminous coal liquefaction section meeting; 1989 nendo rekiseitan ekika bukai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-03-01

    At the 1st, 2nd, and 3rd group meetings held for the fiscal year, reports are given and discussions are made about the progress of research and development. Reported and discussed in relation to the progress of the pilot plant support research are studies with the 1t/d PSU (process supporting unit) (Nippon Steel Corporation, Mitsui Coal Liquefaction Co., Ltd., and Japan Coal Oil Co., Ltd.); improvement on distillate distribution (Sumitomo Metal Industries, Ltd.); development of an optimum decalcification technique (Sumitomo Coal Mining Co., Ltd., and Sumitomo Metal Industries, Ltd.); studies of solvent hydrogenation catalysts (Sumitomo Metal Mining Co., Ltd., and Chiyoda Corp.); and studies of coal liquefaction conditions (Mitsui Engineering and Shipbuilding Co., Ltd.). In relation to studies using a bituminous coal liquefaction pilot plant, the progress of the 150t/d PP (pilot plant) effort (Japan Coal Oil, Co., Ltd.) and the outlines of pilot surveys (Japan Coal Oil Co., Ltd.) are reported and discussed, the latter covering liquefaction solvent performance optimization, slurry preheating furnaces, coal slurry properties, and so forth. (NEDO)

  12. Fiscal 1990 report on the bituminous coal liquefaction section meeting; 1990 nendo rekiseitan ekika bukai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    At the 1st, 2nd, and 3rd group meetings held for the fiscal year, reports are delivered and discussions are made concerning the progress of research and development activities. Reported and discussed in relation to the pilot plant support research, etc., are studies with the 1t/d PSU (process supporting unit) (Nippon Steel Corporation, Mitsui Coal Liquefaction Co., Ltd., and Japan Coal Oil Co., Ltd.); development of an optimum coal refining technique (Sumitomo Coal Mining Co., Ltd.); development of an optimum pretreatment technique and improvement on distillate distribution (Sumitomo Metal Industries, Ltd.); studies of coal liquefaction conditions (Mitsui Engineering and Shipbuilding Co., Ltd.); and studies of solvent hydrogenation catalysts (Sumitomo Metal Mining Co., Ltd., and Chiyoda Corp.). Reported and discussed in relation to researches using a bituminous coal liquefaction pilot plant are the progress of the 150t/d PP (pilot plant) effort (Japan Coal Oil Co., Ltd.) and the outlines of pilot surveys (Japan Coal Oil Co., Ltd.), the latter covering liquefaction solvent performance optimization, slurry pre-heating furnaces, coal slurry properties, and so forth. (NEDO)

  13. Fiscal 1993 report. Coal liquefaction committee; 1993 nendo sekitan ekika iinkai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    The committee in this fiscal year had the 1st meeting in July 1993, the 2nd in December 1993, and the 3rd in March 1994, when fiscal 1993 research and development programs and results were reported and discussed. Reported and discussed at the 2nd meeting were the compilation of brown coal liquefaction technology development project results, evaluation report on the same, hydrorefining of oil from brown coal and the research and development of application technologies for the same, and an environmental safety evaluation test on the same. In selecting a standard coal for the operation of the 150 ton/day pilot plant, PSU (process supporting unit)-aided studies were made on the analytical values presented by coals, yield of the liquid, yield of the liquefaction residue, yield of the generated gas, amount of the hydrogen consumed, coal oil properties, liquefaction residue properties, operationality, etc. On-site investigations were conducted also in Indonesia, and a conclusion was reached that Tanito Harum coal would be the most suitable for the pilot plant. Concerning the liquefaction catalyst for the pilot plant, a report was given on a comparison made between the activity of a synthetic iron sulfide and that of natural pyrite. (NEDO)

  14. Quantitative characterization of the aqueous fraction from hydrothermal liquefaction of algae

    Energy Technology Data Exchange (ETDEWEB)

    Maddi, Balakrishna; Panisko, Ellen; Wietsma, Thomas; Lemmon, Teresa; Swita, Marie; Albrecht, Karl; Howe, Daniel

    2016-10-01

    Aqueous streams generated from hydrothermal liquefaction contain approximately 30% of the total carbon present from the algal feed. Hence, this aqueous carbon must be utilized to produce liquid fuels and/or specialty chemicals for economic sustainability of hydrothermal liquefaction on industrial scale. In this study, aqueous fractions produced from the hydrothermal liquefaction of fresh water and saline water algal cultures were analyzed using a wide variety of analytical instruments to determine their compositional characteristics. This study will also inform researchers designing catalysts for down-stream processing such as high-pressure catalytic conversion of organics in aqueous phase, catalytic hydrothermal gasification, and biological conversions. Organic chemical compounds present in all eight aqueous fractions were identified using two-dimensional gas chromatography equipped with time-of-flight mass spectrometry. Identified compounds include organic acids, nitrogen compounds and aldehydes/ketones. Conventional gas chromatography and liquid chromatography methods were utilized to quantify the identified compounds. Inorganic species in the aqueous stream of hydrothermal liquefaction of algae were identified using ion chromatography and inductively coupled plasma optical emission spectrometer. The concentrations of organic chemical compounds and inorganic species are reported. The amount quantified carbon ranged from 45 to 72 % of total carbon in the aqueous fractions.

  15. Electrochemical advanced oxidation processes: today and tomorrow. A review.

    Science.gov (United States)

    Sirés, Ignasi; Brillas, Enric; Oturan, Mehmet A; Rodrigo, Manuel A; Panizza, Marco

    2014-01-01

    In recent years, new advanced oxidation processes based on the electrochemical technology, the so-called electrochemical advanced oxidation processes (EAOPs), have been developed for the prevention and remediation of environmental pollution, especially focusing on water streams. These methods are based on the electrochemical generation of a very powerful oxidizing agent, such as the hydroxyl radical ((•)OH) in solution, which is then able to destroy organics up to their mineralization. EAOPs include heterogeneous processes like anodic oxidation and photoelectrocatalysis methods, in which (•)OH are generated at the anode surface either electrochemically or photochemically, and homogeneous processes like electro-Fenton, photoelectro-Fenton, and sonoelectrolysis, in which (•)OH are produced in the bulk solution. This paper presents a general overview of the application of EAOPs on the removal of aqueous organic pollutants, first reviewing the most recent works and then looking to the future. A global perspective on the fundamentals and experimental setups is offered, and laboratory-scale and pilot-scale experiments are examined and discussed.

  16. Advanced Photonic Processes for Photovoltaic and Energy Storage Systems.

    Science.gov (United States)

    Sygletou, Maria; Petridis, Constantinos; Kymakis, Emmanuel; Stratakis, Emmanuel

    2017-10-01

    Solar-energy harvesting through photovoltaic (PV) conversion is the most promising technology for long-term renewable energy production. At the same time, significant progress has been made in the development of energy-storage (ES) systems, which are essential components within the cycle of energy generation, transmission, and usage. Toward commercial applications, the enhancement of the performance and competitiveness of PV and ES systems requires the adoption of precise, but simple and low-cost manufacturing solutions, compatible with large-scale and high-throughput production lines. Photonic processes enable cost-efficient, noncontact, highly precise, and selective engineering of materials via photothermal, photochemical, or photophysical routes. Laser-based processes, in particular, provide access to a plethora of processing parameters that can be tuned with a remarkably high degree of precision to enable innovative processing routes that cannot be attained by conventional approaches. The focus here is on the application of advanced light-driven approaches for the fabrication, as well as the synthesis, of materials and components relevant to PV and ES systems. Besides presenting recent advances on recent achievements, the existing limitations are outlined and future possibilities and emerging prospects discussed. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Co-Liquefaction of Elbistan Lignite with Manure Biomass; Part 3 - Effect of Reaction Time and Temperature

    Science.gov (United States)

    Koyunoglu, Cemil; Karaca, Hüseyin

    2017-12-01

    Most of the liquefaction process were carried out in a batch reactor, in which the residence time of the liquefaction products is long enough to favour the retrogressive reactions. To minimize retrogressive reactions, the liquefaction of coal was carried out in a flowing solvent reactor in which a fixed bed of coal is continuously permeated by hot solvent. Solvent flowing through the coal bed carries the liquefaction products out of the reactor. Unlike experiments carried out under similar conditions in a batch reactor no increase in solid residue is observed during long time high temperature runs in the flowing solvent reactor. There is a greater appreciation of the importance of retrograde, or polymerization, reactions. If the free radicals formed when coal breaks down are not quickly capped with hydrogen, they react with each other to form large molecules that are much harder to break down than the original coal. Reaction time impacts both the co-liquefaction cost and the product yield. So as to study this idea, the experiments of Elbistan Lignite (EL) with manure co-liquefaction carried out by changing the reaction time from 30 to 120 minutes. As a result, the greatest oil products yields obtained at 60 minutes. Therefore, by thinking about the oil products yield values acquired, the optimal reaction time was obtained to be 60 minutes for Elbistan lignite (EL) with manure liquefied with the temperature of 350°C and 400°C. Above 425°C did not examine because solvent (tetraline) loses its function after 425 °C. The obtained optimum temperature found 400°C due to higher total conversion of liquefaction products and also oil+gas yields.

  18. Technology advancement of the static feed water electrolysis process

    Science.gov (United States)

    Schubert, F. H.; Wynveen, R. A.

    1977-01-01

    A program to advance the technology of oxygen- and hydrogen-generating subsystems based on water electrolysis was studied. Major emphasis was placed on static feed water electrolysis, a concept characterized by low power consumption and high intrinsic reliability. The static feed based oxygen generation subsystem consists basically of three subassemblies: (1) a combined water electrolysis and product gas dehumidifier module; (2) a product gas pressure controller and; (3) a cyclically filled water feed tank. Development activities were completed at the subsystem as well as at the component level. An extensive test program including single cell, subsystem and integrated system testing was completed with the required test support accessories designed, fabricated, and assembled. Mini-product assurance activities were included throughout all phases of program activities. An extensive number of supporting technology studies were conducted to advance the technology base of the static feed water electrolysis process and to resolve problems.

  19. Selection of parameters for advanced machining processes using firefly algorithm

    Directory of Open Access Journals (Sweden)

    Rajkamal Shukla

    2017-02-01

    Full Text Available Advanced machining processes (AMPs are widely utilized in industries for machining complex geometries and intricate profiles. In this paper, two significant processes such as electric discharge machining (EDM and abrasive water jet machining (AWJM are considered to get the optimum values of responses for the given range of process parameters. The firefly algorithm (FA is attempted to the considered processes to obtain optimized parameters and the results obtained are compared with the results given by previous researchers. The variation of process parameters with respect to the responses are plotted to confirm the optimum results obtained using FA. In EDM process, the performance parameter “MRR” is increased from 159.70 gm/min to 181.6723 gm/min, while “Ra” and “REWR” are decreased from 6.21 μm to 3.6767 μm and 6.21% to 6.324 × 10−5% respectively. In AWJM process, the value of the “kerf” and “Ra” are decreased from 0.858 mm to 0.3704 mm and 5.41 mm to 4.443 mm respectively. In both the processes, the obtained results show a significant improvement in the responses.

  20. Liquefaction of Semen Generates and Later Degrades a Conserved Semenogelin Peptide That Enhances HIV Infection

    Science.gov (United States)

    Liu, Haichuan; Usmani, Shariq M.; Neidleman, Jason; Müller, Janis A.; Avila-Herrera, Aram; Gawanbacht, Ali; Zirafi, Onofrio; Chu, Simon; Dong, Ming; Kumar, Senthil T.; Smith, James F.; Pollard, Katherine S.; Fändrich, Marcus; Kirchhoff, Frank; Münch, Jan; Witkowska, H. Ewa; Greene, Warner C.

    2014-01-01

    ABSTRACT Semen enhances HIV infection in vitro, but how long it retains this activity has not been carefully examined. Immediately postejaculation, semen exists as a semisolid coagulum, which then converts to a more liquid form in a process termed liquefaction. We demonstrate that early during liquefaction, semen exhibits maximal HIV-enhancing activity that gradually declines upon further incubation. The decline in HIV-enhancing activity parallels the degradation of peptide fragments derived from the semenogelins (SEMs), the major components of the coagulum that are cleaved in a site-specific and progressive manner upon initiation of liquefaction. Because amyloid fibrils generated from SEM fragments were recently demonstrated to enhance HIV infection, we set out to determine whether any of the liquefaction-generated SEM fragments associate with the presence of HIV-enhancing activity. We identify SEM1 from amino acids 86 to 107 [SEM1(86-107)] to be a short, cationic, amyloidogenic SEM peptide that is generated early in the process of liquefaction but that, conversely, is lost during prolonged liquefaction due to the activity of serine proteases. Synthetic SEM1(86-107) amyloids directly bind HIV-1 virions and are sufficient to enhance HIV infection of permissive cells. Furthermore, endogenous seminal levels of SEM1(86-107) correlate with donor-dependent variations in viral enhancement activity, and antibodies generated against SEM1(86-107) recognize endogenous amyloids in human semen. The amyloidogenic potential of SEM1(86-107) and its virus-enhancing properties are conserved among great apes, suggesting an evolutionarily conserved function. These studies identify SEM1(86-107) to be a key, HIV-enhancing amyloid species in human semen and underscore the dynamic nature of semen's HIV-enhancing activity. IMPORTANCE Semen, the most common vehicle for HIV transmission, enhances HIV infection in vitro, but how long it retains this activity has not been investigated. Semen

  1. Report on 1979 result of Sunshine Project (detailed design). Part 1. Forty t/day solvolysis coal liquefaction pilot plant; 1979 nendo 40T/nichi solvolysis sekitan pilot plant shosai sekkei. 1

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1980-03-01

    The subject design documents are the compilation of the result of the design operation for the 'detailed design of 40 t/day class solvolysis coal liquefaction pilot plant'. The design of this pilot plant was conducted using, as the fundamental reference, the basic data provided by Kyushu National Industrial Research Institute and Kyushu University and the results of a contract research on '1 t/day class solvolysis coal liquefaction plant'. The subject detailed design was intended for Phase 1 centering on a single stage liquefaction - coal liquefaction (transformation into pitch) by solvolysis liquefaction reaction. The areas covered consists of the pre-treatment process, material mixing process, reaction process, reaction freezing process, coke separation process, SR recovery process, pitch refining process, utility facilities, and waste water treatment facilities. Incidentally, the processes for which the design operation has been completed this year, particularly the reaction process, coke separation process, SR recovery process, etc., are in the field untrodden technologically in the world; therefore, their design method is supposed to be established from the results of the R and D on coal liquefaction, '1 t/day class solvolysis coal liquefaction plant.' (NEDO)

  2. Report on 1979 result of Sunshine Project (detailed design). Part 1. Forty t/day solvolysis coal liquefaction pilot plant; 1979 nendo 40T/nichi solvolysis sekitan pilot plant shosai sekkei. 1

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1980-03-01

    The subject design documents are the compilation of the result of the design operation for the 'detailed design of 40 t/day class solvolysis coal liquefaction pilot plant'. The design of this pilot plant was conducted using, as the fundamental reference, the basic data provided by Kyushu National Industrial Research Institute and Kyushu University and the results of a contract research on '1 t/day class solvolysis coal liquefaction plant'. The subject detailed design was intended for Phase 1 centering on a single stage liquefaction - coal liquefaction (transformation into pitch) by solvolysis liquefaction reaction. The areas covered consists of the pre-treatment process, material mixing process, reaction process, reaction freezing process, coke separation process, SR recovery process, pitch refining process, utility facilities, and waste water treatment facilities. Incidentally, the processes for which the design operation has been completed this year, particularly the reaction process, coke separation process, SR recovery process, etc., are in the field untrodden technologically in the world; therefore, their design method is supposed to be established from the results of the R and D on coal liquefaction, '1 t/day class solvolysis coal liquefaction plant.' (NEDO)

  3. Assessment of thermodynamic models for the design, analysis and optimisation of gas liquefaction systems

    International Nuclear Information System (INIS)

    Nguyen, Tuong-Van; Elmegaard, Brian

    2016-01-01

    Highlights: • Six thermodynamic models used for evaluating gas liquefaction systems are compared. • Three gas liquefaction systems are modelled, assessed and optimised for each equation of state. • The predictions of thermophysical properties and energy flows are significantly different. • The GERG-2008 model is the only consistent one, while cubic, virial and statistical equations are unsatisfying. - Abstract: Natural gas liquefaction systems are based on refrigeration cycles – they consist of the same operations such as heat exchange, compression and expansion, but they have different layouts, components and working fluids. The design of these systems requires a preliminary simulation and evaluation of their performance. However, the thermodynamic models used for this purpose are characterised by different mathematical formulations, ranges of application and levels of accuracy. This may lead to inconsistent results when estimating hydrocarbon properties and assessing the efficiency of a given process. This paper presents a thorough comparison of six equations of state widely used in the academia and industry, including the GERG-2008 model, which has recently been adopted as an ISO standard for natural gases. These models are used to (i) estimate the thermophysical properties of a Danish natural gas, (ii) simulate, and (iii) optimise liquefaction systems. Three case studies are considered: a cascade layout with three pure refrigerants, a single mixed-refrigerant unit, and an expander-based configuration. Significant deviations are found between all property models, and in all case studies. The main discrepancies are related to the prediction of the energy flows (up to 7%) and to the heat exchanger conductances (up to 11%), and they are not systematic errors. The results illustrate the superiority of using the GERG-2008 model for designing gas processes in real applications, with the aim of reducing their energy use. They demonstrate as well that

  4. High-power ultrasonic processing: Recent developments and prospective advances

    Science.gov (United States)

    Gallego-Juarez, Juan A.

    2010-01-01

    Although the application of ultrasonic energy to produce or to enhance a wide variety of processes have been explored since about the middle of the 20th century, only a reduced number of ultrasonic processes have been established at industrial level. However, during the last ten years the interest in ultrasonic processing has revived particularly in industrial sectors where the ultrasonic technology may represent a clean and efficient tool to improve classical existing processes or an innovation alternative for the development of new processes. Such seems to be the case of relevant sectors such as food industry, environment, pharmaceuticals and chemicals manufacture, machinery, mining, etc where power ultrasound is becoming an emerging technology for process development. The possible major problem in the application of high-intensity ultrasound on industrial processing is the design and development of efficient power ultrasonic systems (generators and reactors) capable of large scale successful operation specifically adapted to each individual process. In the area of ultrasonic processing in fluid media and more specifically in gases, the development of the steppedplate transducers and other power ge with extensive radiating surface has strongly contributed to the implementation at semi-industrial and industrial stage of several commercial applications, in sectors such as food and beverage industry (defoaming, drying, extraction, etc), environment (air cleaning, sludge filtration, etc...), machinery and process for manufacturing (textile washing, paint manufacture, etc). The development of different cavitational reactors for liquid treatment in continuous flow is helping to introduce into industry the wide potential of the area of sonochemistry. Processes such as water and effluent treatment, crystallization, soil remediation, etc have been already implemented at semi-industrial and/or industrial stage. Other single advances in sectors like mining or energy have

  5. Advanced automation for in-space vehicle processing

    Science.gov (United States)

    Sklar, Michael; Wegerif, D.

    1990-01-01

    The primary objective of this 3-year planned study is to assure that the fully evolved Space Station Freedom (SSF) can support automated processing of exploratory mission vehicles. Current study assessments show that required extravehicular activity (EVA) and to some extent intravehicular activity (IVA) manpower requirements for required processing tasks far exceeds the available manpower. Furthermore, many processing tasks are either hazardous operations or they exceed EVA capability. Thus, automation is essential for SSF transportation node functionality. Here, advanced automation represents the replacement of human performed tasks beyond the planned baseline automated tasks. Both physical tasks such as manipulation, assembly and actuation, and cognitive tasks such as visual inspection, monitoring and diagnosis, and task planning are considered. During this first year of activity both the Phobos/Gateway Mars Expedition and Lunar Evolution missions proposed by the Office of Exploration have been evaluated. A methodology for choosing optimal tasks to be automated has been developed. Processing tasks for both missions have been ranked on the basis of automation potential. The underlying concept in evaluating and describing processing tasks has been the use of a common set of 'Primitive' task descriptions. Primitive or standard tasks have been developed both for manual or crew processing and automated machine processing.

  6. Advanced Manufacturing Processes Laboratory Building 878 hazards assessment document

    International Nuclear Information System (INIS)

    Wood, C.; Thornton, W.; Swihart, A.; Gilman, T.

    1994-07-01

    The introduction of the hazards assessment process is to document the impact of the release of hazards at the Advanced Manufacturing Processes Laboratory (AMPL) that are significant enough to warrant consideration in Sandia National Laboratories' operational emergency management program. This hazards assessment is prepared in accordance with the Department of Energy Order 5500.3A requirement that facility-specific hazards assessments be prepared, maintained, and used for emergency planning purposes. This hazards assessment provides an analysis of the potential airborne release of chemicals associated with the operations and processes at the AMPL. This research and development laboratory develops advanced manufacturing technologies, practices, and unique equipment and provides the fabrication of prototype hardware to meet the needs of Sandia National Laboratories, Albuquerque, New Mexico (SNL/NM). The focus of the hazards assessment is the airborne release of materials because this requires the most rapid, coordinated emergency response on the part of the AMPL, SNL/NM, collocated facilities, and surrounding jurisdiction to protect workers, the public, and the environment

  7. Advanced Manufacturing Processes Laboratory Building 878 hazards assessment document

    Energy Technology Data Exchange (ETDEWEB)

    Wood, C.; Thornton, W.; Swihart, A.; Gilman, T.

    1994-07-01

    The introduction of the hazards assessment process is to document the impact of the release of hazards at the Advanced Manufacturing Processes Laboratory (AMPL) that are significant enough to warrant consideration in Sandia National Laboratories` operational emergency management program. This hazards assessment is prepared in accordance with the Department of Energy Order 5500.3A requirement that facility-specific hazards assessments be prepared, maintained, and used for emergency planning purposes. This hazards assessment provides an analysis of the potential airborne release of chemicals associated with the operations and processes at the AMPL. This research and development laboratory develops advanced manufacturing technologies, practices, and unique equipment and provides the fabrication of prototype hardware to meet the needs of Sandia National Laboratories, Albuquerque, New Mexico (SNL/NM). The focus of the hazards assessment is the airborne release of materials because this requires the most rapid, coordinated emergency response on the part of the AMPL, SNL/NM, collocated facilities, and surrounding jurisdiction to protect workers, the public, and the environment.

  8. Metrology aspects of SIMS depth profiling for advanced ULSI processes

    International Nuclear Information System (INIS)

    Budrevich, Andre; Hunter, Jerry

    1998-01-01

    As the semiconductor industry roadmap passes through the 0.1 μm technology node, the junction depth of the transistor source/drain extension will be required to be less than 20 nm and the well doping will be near 1.0 μm in depth. The development of advanced ULSI processing techniques requires the evolution of new metrology tools to ensure process capability. High sensitivity (ppb) coupled with excellent depth resolution (1 nm) makes SIMS the technique of choice for measuring the in-depth chemical distribution of these dopants with high precision and accuracy. This paper will discuss the issues, which impact the accuracy and precision of SIMS measurements of ion implants (both shallow and deep). First this paper will discuss common uses of the SIMS technique in the technology development and manufacturing of advanced ULSI processes. In the second part of this paper the ability of SIMS to make high precision measurements of ion implant depth profiles will be studied

  9. H Scan/AHP advanced technology proposal evaluation process

    Energy Technology Data Exchange (ETDEWEB)

    Mack, S. [Energetics, Inc., Columbia, MD (United States); Valladares, M.R.S. de [National Renewable Energy Lab., Washington, DC (United States)

    1996-10-01

    It is anticipated that a family of high value/impact projects will be funded by the Hydrogen Program to field test hydrogen technologies that are at advanced stages of development. These projects will add substantial value to the Program in several ways, by: demonstrating successful integration of multiple advanced technologies, providing critical insight on issues of larger scale equipment design, construction and operations management, yielding cost and performance data for competitive analysis, refining and deploying enhanced safety measures. These projects will be selected through a competitive proposal evaluation process. Because of the significant scope and funding levels of projects at these development phases, Program management has indicated the need for an augmented proposal evaluation strategy to ensure that supported projects are implemented by capable investigative teams and that their successful completion will optimally advance programmatic objectives. These objectives comprise a complex set of both quantitative and qualitative factors, many of which can only be estimated using expert judgment and opinion. To meet the above need, the National Renewable Energy Laboratory (NREL) and Energetics Inc. have jointly developed a proposal evaluation methodology called H Scan/AHP. The H Scan component of the process was developed by NREL. It is a two-part survey instrument that substantially augments the type and scope of information collected in a traditional proposal package. The AHP (Analytic Hierarchy Process) component was developed by Energetics. The AHP is an established decision support methodology that allows the Program decision makers to evaluate proposals relatively based on a unique set of weighted criteria that they have determined.

  10. Sustaining high energy efficiency in existing processes with advanced process integration technology

    International Nuclear Information System (INIS)

    Zhang, Nan; Smith, Robin; Bulatov, Igor; Klemeš, Jiří Jaromír

    2013-01-01

    Highlights: ► Process integration with better modelling and more advanced solution methods. ► Operational changes for better environmental performance through optimisation. ► Identification of process integration technology for operational optimisation. ► Systematic implementation procedure of process integration technology. ► A case study with crude oil distillation to demonstrate the operational flexibility. -- Abstract: To reduce emissions in the process industry, much emphasis has been put on making step changes in emission reduction, by developing new process technology and making renewable energy more affordable. However, the energy saving potential of existing systems cannot be simply ignored. In recent years, there have been significant advances in process integration technology with better modelling techniques and more advanced solution methods. These methods have been applied to the new design and retrofit studies in the process industry. Here attempts are made to apply these technologies to improve the environmental performance of existing facilities with operational changes. An industrial project was carried out to demonstrate the importance and effectiveness of exploiting the operational flexibility for energy conservation. By applying advanced optimisation technique to integrate the operation of distillation and heat recovery in a crude oil distillation unit, the energy consumption was reduced by 8% without capital expenditure. It shows that with correctly identified technology and the proper execution procedure, significant energy savings and emission reduction can be achieved very quickly without major capital expenditure. This allows the industry to improve its economic and environment performance at the same time.

  11. FY 1980 Report on results of Sunshine Project by Coal Group. Basic researches on coal liquefaction techniques by solvolysis; 1980 nendo sunshine keikaku sekitanhan hokokusho. Sekitan no solvolysis ekika gijutsu no kiso kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-07-01

    The basic experimental researches were carried out for coal liquefaction by solvolysis. The studied items include hydrogenation conditions for treating the primary liquefied products, asphalt, pitch and model solvents (e.g., anthracene oil) in the presence of a commercial catalyst, solvolysis conditions for finely divided, molten coal using a hydrogenation recycled solvent, hydrotreating solvents, analysis of solvolysis-liquefied products, and liquefaction capacity of fractionated solvents for finely divided, molten coal. The studied items for separation of minerals include settlement at high temperature of the solid residue from the first liquefaction stage, and changed coal particle size distribution as a result of the first-stage liquefaction reactions in the presence of a hydrogenation solvent. The experimental study results indicate that conversion of finely divided molten coal into asphaltenes and preasphaltenes is notably accelerated in the phase-II coal liquefaction process by solvolysis, when a hydrotreating solvent is used for the first stage solvolysis process. (NEDO)

  12. Recent Technological Advances in Natural Language Processing and Artificial Intelligence

    OpenAIRE

    Shah, Nishal Pradeepkumar

    2012-01-01

    A recent advance in computer technology has permitted scientists to implement and test algorithms that were known from quite some time (or not) but which were computationally expensive. Two such projects are IBM's Jeopardy as a part of its DeepQA project [1] and Wolfram's Wolframalpha[2]. Both these methods implement natural language processing (another goal of AI scientists) and try to answer questions as asked by the user. Though the goal of the two projects is similar, both of them have a ...

  13. Structural analysis of advanced spent fuel conditioning process

    International Nuclear Information System (INIS)

    Gu, J. H.; Jung, W. M.; Jo, I. J.; Gug, D. H.; Yoo, K. S.

    2003-01-01

    An advanced spent fuel conditioning process (ACP) is developing for the safe and effective management of spent fuels which arising from the domestic nuclear power plants. And its demonstration facility is under design. This facility will be prepared by modifying IMEF's reserve hot cell facility which reserved for future usage by considering the characteristics of ACP. This study presents a basic structural architecture design and analysis results of ACP hot cell including modification of the IMEF. The results of this study will be used for the detail design of ACP demonstration facility, and utilized as basic data for the licensing of the ACP facility

  14. Advanced computational modelling for drying processes – A review

    International Nuclear Information System (INIS)

    Defraeye, Thijs

    2014-01-01

    Highlights: • Understanding the product dehydration process is a key aspect in drying technology. • Advanced modelling thereof plays an increasingly important role for developing next-generation drying technology. • Dehydration modelling should be more energy-oriented. • An integrated “nexus” modelling approach is needed to produce more energy-smart products. • Multi-objective process optimisation requires development of more complete multiphysics models. - Abstract: Drying is one of the most complex and energy-consuming chemical unit operations. R and D efforts in drying technology have skyrocketed in the past decades, as new drivers emerged in this industry next to procuring prime product quality and high throughput, namely reduction of energy consumption and carbon footprint as well as improving food safety and security. Solutions are sought in optimising existing technologies or developing new ones which increase energy and resource efficiency, use renewable energy, recuperate waste heat and reduce product loss, thus also the embodied energy therein. Novel tools are required to push such technological innovations and their subsequent implementation. Particularly computer-aided drying process engineering has a large potential to develop next-generation drying technology, including more energy-smart and environmentally-friendly products and dryers systems. This review paper deals with rapidly emerging advanced computational methods for modelling dehydration of porous materials, particularly for foods. Drying is approached as a combined multiphysics, multiscale and multiphase problem. These advanced methods include computational fluid dynamics, several multiphysics modelling methods (e.g. conjugate modelling), multiscale modelling and modelling of material properties and the associated propagation of material property variability. Apart from the current challenges for each of these, future perspectives should be directed towards material property

  15. Further assessment studies of the Advanced Cold Process Canister

    International Nuclear Information System (INIS)

    Henshaw, J.; Hoch, A.; Sharland, S.M.

    1990-08-01

    A preliminary assessment of the performance of the Advanced Cold Process Canister (ACPC) was carried out recently by Marsh. The aim of the study presented in this report is to re-examine the validity of some of the assumptions made, and re-evaluate the canister performance as appropriate. Two areas were highlighted in the preliminary study as requiring more detailed quantitative evaluation. 1) Assessment of the risk of internal stress-corrosion cracking induced by irradiation of moist air inside the canister if, under fault conditions, significant water was carried into the canister before sealing. 2) Evaluation of the corrosion behaviour subsequent to first breach of outer container. (author)

  16. Advances in biohydrogen production processes: An approach towards commercialization

    Energy Technology Data Exchange (ETDEWEB)

    Das, Debabrata [Department of Biotechnology, Indian Institute of Technology, Kharagpur 721302, West Bengal (India)

    2009-09-15

    Biological H{sub 2} production has an edge over its chemical counterpart mainly because it is environmentally benign. Despite having simpler technology, higher evolution rate of H{sub 2} and the wide spectrum of substrate utilization, the major deterrent of anaerobic dark fermentation process stems from its lower achievable yields. Theoretically, the maximum H{sub 2} yield is 4 mol H{sub 2}/mol glucose when glucose is completely metabolized to acetate or acetone in the anaerobic process. But it is somewhat difficult to achieve the complete degradation of glucose to carbon dioxide and H{sub 2} through anaerobic dark fermentation. Moreover, this yield appears too low to be economically viable as an alternative to the existing chemical or electrochemical processes of hydrogen generation. Intensive research studies have already been carried out on the advancement of these processes, such as the development of genetically modified microorganism, improvement of the reactor designs, use of different solid matrices for the immobilization of whole cells, development of two-stage processes, and higher H{sub 2} production rates. Maximum H{sub 2} yield is found to be 5.1 mol H{sub 2}/mol glucose. However, major bottlenecks for the commercialization of these processes are lower H{sub 2} yield and rate of H{sub 2} production. Competent microbial cultures are required to handle waste materials efficiently, which are usually complex in nature. This will serve dual purposes: clean energy generation and bioremediation. Scale-up studies on fermentative H{sub 2} production processes have been done successfully. Pilot plant trials of the photo-fermentation processes require more attention. Use of cheaper raw materials and efficient biological H{sub 2} production processes will surely make them more competitive with the conventional H{sub 2} generation processes in near future. (author)

  17. Behavior of catalyst and mineral matter in coal liquefaction; Sekitan ekika hannochu no kobusshitsu to shokubai no kyodo

    Energy Technology Data Exchange (ETDEWEB)

    Iwasaki, K.; Wang, J.; Tomita, A. [Tohoku University, Sendai (Japan). Institute for Chemical Reaction Science

    1996-10-28

    Mineral matter in coals is important in various senses for coal liquefaction. It is possible that the catalytic activity is affected by the interaction between catalyst and mineral matter. Iron-based catalyst forms pyrrhotite in the process of liquefaction, but the interaction between it and mineral matter is not known in detail. In this study, the interaction between mineral matter and catalyst and the selective reaction between them were investigated. Tanito Harum coal was used for this study. This coal contains a slight amount of siderite and jarosite besides pyrite as iron compounds. Liquefaction samples were obtained from the 1 t/d NEDOL process PSU. The solid deposits in the reactor mainly contained pyrrhotite and quartz. A slight amount of kaolinite was observed, and pyrite was little remained. It was found that the catalyst (pyrrhotite) often coexisted with quartz, clay and calcite. 8 figs., 2 tabs.

  18. Effects of relative density and accumulated shear strain on post-liquefaction residual deformation

    Directory of Open Access Journals (Sweden)

    J. Kim

    2013-10-01

    Full Text Available The damage caused by liquefaction, which occurs following an earthquake, is usually because of settlement and lateral spreading. Generally, the evaluation of liquefaction has been centered on settlement, that is, residual volumetric strain. However, in actual soil, residual shear and residual volumetric deformations occur simultaneously after an earthquake. Therefore, the simultaneous evaluation of the two phenomena and the clarification of their relationship are likely to evaluate post-liquefaction soil behaviors more accurately. Hence, a quantitative evaluation of post-liquefaction damage will also be possible. In this study, the effects of relative density and accumulated shear strain on post-liquefaction residual deformations were reviewed through a series of lateral constrained-control hollow cylindrical torsion tests under undrained conditions. In order to identify the relationship between residual shear and residual volumetric strains, this study proposed a new test method that integrates monotonic loading after cyclic loading, and K0-drain after cyclic loading – in other words, the combination of cyclic loading, monotonic loading, and the K0 drain. In addition, a control that maintained the lateral constrained condition across all the processes of consolidation, cyclic loading, monotonic loading, and drainage was used to reproduce the anisotropy of in situ ground. This lateral constrain control was performed by controlling the axial strain, based on the assumption that under undrained conditions, axial and lateral strains occur simultaneously, and unless axial strain occurs, lateral strain does not occur. The test results confirmed that the recovery of effective stresses, which occur during monotonic loading and drainage after cyclic loading, respectively, result from mutually different structural restoration characteristics. In addition, in the ranges of 40–60% relative density and 50–100% accumulated shear strain, relative

  19. Comparison of oxygen liquefaction methods for use on the Martian surface

    Science.gov (United States)

    Johnson, W. L.; Hauser, D. M.; Plachta, D. W.; Wang, X.-Y. J.; Banker, B. F.; Desai, P. S.; Stephens, J. R.; Swanger, A. M.

    2018-03-01

    In order to use oxygen that is produced on the surface of Mars from In-Situ production processes in a chemical propulsion system, the oxygen must first be converted from vapor phase to liquid phase and then stored within the propellant tanks of the propulsions system. There are multiple ways that this can be accomplished, from simply attaching a liquefaction system onto the propellant tanks to carrying separate tanks for liquefaction and storage of the propellant and loading just prior to launch (the way that traditional rocket launches occur on Earth). A study was done into these various methods by which the oxygen (and methane) could be liquefied and stored on the Martian surface. Five different architectures or cycles were considered: Tube-on-Tank (also known as Broad Area Cooling or Distributed Refrigeration), Tube-in-Tank (also known as Integrated Refrigeration and Storage), a modified Linde open liquefaction/refrigeration cycle, the direct mounting of a pulse tube cryocooler onto the tank, and an in-line liquefier at ambient pressure. Models of each architecture were developed to give insight into the performance and losses of each of the options. The results were then compared across eight categories: Mass, Power (both input and heat rejection), Operability, Cost, Manufacturability, Reliability, Volume-ility, and Scalability. The result was that Tube-on-Tank and Tube-in-Tank architectures were the most attractive solutions, with NASA's engineering management choosing to pursue tube on tank development rather than further differentiate the two. As a result NASA is focusing its Martian surface liquefaction activities and technology development on Tube-on-Tank liquefaction cycles.

  20. Catalytic subcritical water liquefaction of flax straw for high yield of furfural

    International Nuclear Information System (INIS)

    Harry, Inibehe; Ibrahim, Hussameldin; Thring, Ron; Idem, Raphael

    2014-01-01

    There is substantial interest in the application of biomass as a renewable fuel or for production of chemicals. Flax straw can be converted into valuable chemicals and biofuels via liquefaction in sub-critical water. In this study, the yield of furfural and the kinetics of flax straw liquefaction under sub-critical water conditions were investigated using a high-pressure autoclave reactor. The liquefaction was conducted in the temperature range of 175–325 °C, pressure of 0.1 MPa–8 MPa, retention time in the range of 0 min–120 min, and flax straw mass fraction (w F ) of 5–20 %. Also, the effect of acid catalysts on furfural yield was studied. The kinetic parameters of flax straw liquefaction were determined using nonlinear regression of the experimental data, assuming second-order kinetics. The apparent activation energy was found to be 27.97 kJ mol −1 while the reaction order was 2.0. The optimum condition for furfural yield was at 250 °C, 6.0 MPa, w F of 5% and 0 retention time after reaching set conditions. An acid catalyst was found to selectively favour furfural yield with 40% flax straw conversion. - Highlights: • Flax straw liquefaction in subcritical water. • Creation of a reaction pathway that can be used to optimized furfural production. • Acid catalyst selectively favoured furfural yield with respect to other liquid products. • At the highest process temperature of 325 °C, a carbon conversion of 40% was achieved. • Activation energy and reaction order was 28 kJ/mol and 2.0 respectively

  1. A flexible architecture for advanced process control solutions

    Science.gov (United States)

    Faron, Kamyar; Iourovitski, Ilia

    2005-05-01

    Advanced Process Control (APC) is now mainstream practice in the semiconductor manufacturing industry. Over the past decade and a half APC has evolved from a "good idea", and "wouldn"t it be great" concept to mandatory manufacturing practice. APC developments have primarily dealt with two major thrusts, algorithms and infrastructure, and often the line between them has been blurred. The algorithms have evolved from very simple single variable solutions to sophisticated and cutting edge adaptive multivariable (input and output) solutions. Spending patterns in recent times have demanded that the economics of a comprehensive APC infrastructure be completely justified for any and all cost conscious manufacturers. There are studies suggesting integration costs as high as 60% of the total APC solution costs. Such cost prohibitive figures clearly diminish the return on APC investments. This has limited the acceptance and development of pure APC infrastructure solutions for many fabs. Modern APC solution architectures must satisfy the wide array of requirements from very manual R&D environments to very advanced and automated "lights out" manufacturing facilities. A majority of commercially available control solutions and most in house developed solutions lack important attributes of scalability, flexibility, and adaptability and hence require significant resources for integration, deployment, and maintenance. Many APC improvement efforts have been abandoned and delayed due to legacy systems and inadequate architectural design. Recent advancements (Service Oriented Architectures) in the software industry have delivered ideal technologies for delivering scalable, flexible, and reliable solutions that can seamlessly integrate into any fabs" existing system and business practices. In this publication we shall evaluate the various attributes of the architectures required by fabs and illustrate the benefits of a Service Oriented Architecture to satisfy these requirements. Blue

  2. Fractional Multistage Hydrothermal Liquefaction of Biomass and Catalytic Conversion into Hydrocarbons

    Energy Technology Data Exchange (ETDEWEB)

    Cortright, Randy [Virent, Inc., Madison, WI (United States); Rozmiarek, Robert [Virent, Inc., Madison, WI (United States); Dally, Brice [Virent, Inc., Madison, WI (United States); Holland, Chris [Virent, Inc., Madison, WI (United States)

    2017-08-31

    The objective of this project was to develop an improved multistage process for the hydrothermal liquefaction (HTL) of biomass to serve as a new front-end, deconstruction process ideally suited to feed Virent’s well-proven catalytic technology, which is already being scaled up. This process produced water soluble, partially de-oxygenated intermediates that are ideally suited for catalytic finishing to fungible distillate hydrocarbons. Through this project, Virent, with its partners, demonstrated the conversion of pine wood chips to drop-in hydrocarbon distillate fuels using a multi-stage fractional conversion system that is integrated with Virent’s BioForming® process. The majority of work was in the liquefaction task and included temperature scoping, solvent optimization, and separations.

  3. Thermoeconomic optimization of a cryogenic refrigeration cycle for re-liquefaction of the LNG boil-off gas

    Energy Technology Data Exchange (ETDEWEB)

    Sayyaadi, Hoseyn; Babaelahi, M. [Faculty of Mechanical Engineering-Energy Division, K.N. Toosi University of Technology, P.O. Box: 19395-1999, No. 15-19, Pardis Str., Mollasadra Ave., Vanak Sq., Tehran 1999 143344 (Iran)

    2010-09-15

    The development of the liquefaction process for the Liquefied Natural Gas (LNG) boil-off re-liquefaction plants will be addressed to provide an environmentally friendly and cost effective solution for the gas transportation. In this manner, onboard boil-off gas (BOG) re-liquefaction system as a cryogenic refrigeration cycle is utilized in order to re-liquefy the BOG and returns it to the cargo tanks instead of burning it. In this paper, a thermoeconomic optimization of the LNG-BOG liquefaction system is performed. A thermoeconomic model based on energy and exergy analyses and an economic model according to the total revenue requirement (TRR) are developed. Minimizing of the unit cost of the refrigeration effect as a product of BOG re-liquefaction plant is performed using the genetic algorithm. Results of thermoeconomic optimization are compared with corresponding features of the base case system. Finally, sensitivity of the total cost of the system product with respect to the variation of some operating parameters is studied. (author)

  4. Radiation Monitoring System in Advanced Spent Fuel Conditioning Process Facility

    Energy Technology Data Exchange (ETDEWEB)

    You, Gil Sung; Kook, D. H.; Choung, W. M.; Ku, J. H.; Cho, I. J.; You, G. S.; Kwon, K. C.; Lee, W. K.; Lee, E. P

    2006-09-15

    The Advanced spent fuel Conditioning Process is under development for effective management of spent fuel by converting UO{sub 2} into U-metal. For demonstration of this process, {alpha}-{gamma} type new hot cell was built in the IMEF basement . To secure against radiation hazard, this facility needs radiation monitoring system which will observe the entire operating area before the hot cell and service area at back of it. This system consists of 7 parts; Area Monitor for {gamma}-ray, Room Air Monitor for particulate and iodine in both area, Hot cell Monitor for hot cell inside high radiation and rear door interlock, Duct Monitor for particulate of outlet ventilation, Iodine Monitor for iodine of outlet duct, CCTV for watching workers and material movement, Server for management of whole monitoring system. After installation and test of this, radiation monitoring system will be expected to assist the successful ACP demonstration.

  5. Solar photoassisted advanced oxidation process of azo dyes.

    Science.gov (United States)

    Prato-Garcia, D; Buitrón, G

    2009-01-01

    Advanced oxidation processes assisted with natural solar radiation in CPC type reactors (parabolic collector compound), was applied for the degradation of three azo dyes: acid orange (AO7), acid red 151 (AR151) and acid blue 113 (AB113). Fenton, Fenton like and ferrioxalate-type complexes showed to be effective for degrade the azo linkage and moieties in different extensions. Initially, the best dose of reagents (Fe(3 + )-H(2)O(2)) was determined through a factorial experimental design, next, using response surface methodologies, the reagent consumption was reduced up to 40%, maintaining in all cases high decolourisation percentages (>98%) after 60 min. of phototreatment. In this work, it was also studied the effect of concentration changes of the influent between 100-300 mg/L and the operation of the photocatalytic process near neutral conditions (pH 6.0-6.5) by using ferrioxalate type complex (FeOx).

  6. Advances in low-level color image processing

    CERN Document Server

    Smolka, Bogdan

    2014-01-01

    Color perception plays an important role in object recognition and scene understanding both for humans and intelligent vision systems. Recent advances in digital color imaging and computer hardware technology have led to an explosion in the use of color images in a variety of applications including medical imaging, content-based image retrieval, biometrics, watermarking, digital inpainting, remote sensing, visual quality inspection, among many others. As a result, automated processing and analysis of color images has become an active area of research, to which the large number of publications of the past two decades bears witness. The multivariate nature of color image data presents new challenges for researchers and practitioners as the numerous methods developed for single channel images are often not directly applicable to multichannel  ones. The goal of this volume is to summarize the state-of-the-art in the early stages of the color image processing pipeline.

  7. Evaluation, engineering and development of advanced cyclone processes

    Energy Technology Data Exchange (ETDEWEB)

    Durney, T.E.; Cook, A. [Coal Technology Corporation, Bristol, VA (United States); Ferris, D.D. [ICF Kaiser Engineers, Inc., Pittsburgh, PA (United States)] [and others

    1995-11-01

    This research and development project is one of three seeking to develop advanced, cost-effective, coal cleaning processes to help industry comply with 1990 Clean Air Act Regulations. The specific goal for this project is to develop a cycloning technology that will beneficiate coal to a level approaching 85% pyritic sulfur rejection while retaining 85% of the parent coal`s heating value. A clean coal ash content of less than 6% and a moisture content, for both clean coal and reject, of less than 30% are targeted. The process under development is a physical, gravimetric-based cleaning system that removes ash bearing mineral matter and pyritic sulfur. Since a large portion of the Nation`s coal reserves contain significant amounts of pyrite, physical beneficiation is viewed as a potential near-term, cost effective means of producing an environmentally acceptable fuel.

  8. Radiation Monitoring System in Advanced Spent Fuel Conditioning Process Facility

    International Nuclear Information System (INIS)

    You, Gil Sung; Kook, D. H.; Choung, W. M.; Ku, J. H.; Cho, I. J.; You, G. S.; Kwon, K. C.; Lee, W. K.; Lee, E. P.

    2006-09-01

    The Advanced spent fuel Conditioning Process is under development for effective management of spent fuel by converting UO 2 into U-metal. For demonstration of this process, α-γ type new hot cell was built in the IMEF basement . To secure against radiation hazard, this facility needs radiation monitoring system which will observe the entire operating area before the hot cell and service area at back of it. This system consists of 7 parts; Area Monitor for γ-ray, Room Air Monitor for particulate and iodine in both area, Hot cell Monitor for hot cell inside high radiation and rear door interlock, Duct Monitor for particulate of outlet ventilation, Iodine Monitor for iodine of outlet duct, CCTV for watching workers and material movement, Server for management of whole monitoring system. After installation and test of this, radiation monitoring system will be expected to assist the successful ACP demonstration

  9. Evaluation, engineering and development of advanced cyclone processes

    International Nuclear Information System (INIS)

    Durney, T.E.; Cook, A.; Ferris, D.D.

    1995-01-01

    This research and development project is one of three seeking to develop advanced, cost-effective, coal cleaning processes to help industry comply with 1990 Clean Air Act Regulations. The specific goal for this project is to develop a cycloning technology that will beneficiate coal to a level approaching 85% pyritic sulfur rejection while retaining 85% of the parent coal's heating value. A clean coal ash content of less than 6% and a moisture content, for both clean coal and reject, of less than 30% are targeted. The process under development is a physical, gravimetric-based cleaning system that removes ash bearing mineral matter and pyritic sulfur. Since a large portion of the Nation's coal reserves contain significant amounts of pyrite, physical beneficiation is viewed as a potential near-term, cost effective means of producing an environmentally acceptable fuel

  10. Research on corrosion aspects of the advanced cold process canister

    International Nuclear Information System (INIS)

    Blackwood, D.J.; Hoch, A.R.; Naish, C.C.; Rance, A.

    1994-01-01

    The Advanced Cold Process Canister (ACPC) is a waste canister being developed jointly by SKB and TVO for the disposal of spent nuclear fuel. It comprises an outer copper canister, with a carbon steel canister inside. A concern regarding the use of the ACPC is that, in the unlikely event that the outer copper canister is penetrated, the anaerobic corrosion of the carbon steel container may result in the formation of hydrogen gas bubbles. These bubbles could disrupt the backfill, and thus increase water flow through the near field and the flux of radionuclides to the host geology. A number of factors that influence the rate at which hydrogen evolves as a result of the anaerobic corrosion of carbon steel in artificial granitic groundwaters have been investigated. A previously observed, time-dependent decline in the hydrogen evolution rate has been confirmed as being due to the production of magnetite film. Once the magnetite film is about 0.7-1.0 μm thick, the rate of hydrogen evolution reaches a steady state value. The pH and the ionic strength of the groundwater were both found to influence the long-term hydrogen evolution rate. The results of the experimental programme were used to update a model of the corrosion behaviour and hydrogen production from the Advanced Cold Process Canister. 36 figs, 5 tabs, 13 refs

  11. Conceptual design of an integrated hydrothermal liquefaction and biogas plant for sustainable bioenergy production

    DEFF Research Database (Denmark)

    Hoffmann, Jessica; Rudra, Souman; Toor, Saqib

    2013-01-01

    Initial process studies carried out in Aspen Plus on an integrated thermochemical conversion process are presented herein. In the simulations, a hydrothermal liquefaction (HTL) plant is combined with a biogas plant (BP), such that the digestate from the BP is converted to a biocrude in the HTL...... grid or for CHP. An estimated 62–84% of the biomass energy can be recovered in the biofuels....

  12. Advanced Map For Real-Time Process Control

    Science.gov (United States)

    Shiobara, Yasuhisa; Matsudaira, Takayuki; Sashida, Yoshio; Chikuma, Makoto

    1987-10-01

    MAP, a communications protocol for factory automation proposed by General Motors [1], has been accepted by users throughout the world and is rapidly becoming a user standard. In fact, it is now a LAN standard for factory automation. MAP is intended to interconnect different devices, such as computers and programmable devices, made by different manufacturers, enabling them to exchange information. It is based on the OSI intercomputer com-munications protocol standard under development by the ISO. With progress and standardization, MAP is being investigated for application to process control fields other than factory automation [2]. The transmission response time of the network system and centralized management of data exchanged with various devices for distributed control are import-ant in the case of a real-time process control with programmable controllers, computers, and instruments connected to a LAN system. MAP/EPA and MINI MAP aim at reduced overhead in protocol processing and enhanced transmission response. If applied to real-time process control, a protocol based on point-to-point and request-response transactions limits throughput and transmission response. This paper describes an advanced MAP LAN system applied to real-time process control by adding a new data transmission control that performs multicasting communication voluntarily and periodically in the priority order of data to be exchanged.

  13. Near-field performance of the advanced cold process canister

    International Nuclear Information System (INIS)

    Werme, L.

    1991-12-01

    A near-field performance evaluation of an advanced cold process canister for spent fuel disposal has been performed jointly by TVO, Finland and SKB, Sweden. The canister consists of a steel canister as a load bearing element, with an outer corrosion shield of copper. In the analysis, as well internal (ie corrosion processes from the inside of the canister) as external processes (mechanical and chemical) have been considered both prior to and after canister breach. The major conclusions for the evaluation are: Internal processes cannot cause the canister breach under foreseen conditions, ie local-iced corrosion for the steel or copper canisters can be dismissed as a failure mechanism; The evaluation of the effects of processed outside the canister indicate that there is no rapid mechanism to endanger the integrity of the canister. Consequently the service life of the canister will be several million years. For completeness also evaluation of post-failure behaviour was carried out. Analyses were focussed on low probability phenomena from faults in canisters. Some items were identified where further research is justified in order to increase knowledge of the phenomena and thus strengthen the confidence of safety margins. However, it can be concluded that the risks of these scenarios can be judged to be acceptable. This is due to the fact that firstly, the probability of occurrence of most of these scenarios can be controlled to a large extent through technical measures. Secondly, these analyses indicated that the consequences would not be severe

  14. Technology Summary Advancing Tank Waste Retreival And Processing

    International Nuclear Information System (INIS)

    Sams, T.L.

    2010-01-01

    This technology overview provides a high-level summary of technologies being investigated and developed by Washington River Protection Solutions (WRPS) to advance Hanford Site tank waste retrieval and processing. Technology solutions are outlined, along with processes and priorities for selecting and developing them. Hanford's underground waste storage tanks hold approximately 57 million gallons of radiochemical waste from nuclear defense production - more tank waste than any other site in the United States. In addition, the waste is uniquely complicated since it contains constituents from at least six major radiochemical processes and several lesser processes. It is intermixed and complexed more than any other waste collection known to exist in the world. The multi-faceted nature of Hanford's tank waste means that legally binding agreements in the Federal Facility Agreement and Consent Order (known as the Tri-Party Agreement) and between the Department of Energy (DOE) and its contractors may not be met using current vitrification schedules, plans and methods. WRPS and the DOE are therefore developing, testing, and deploying technologies to ensure that they can meet the necessary commitments and complete the DOE's River Protection Project (RPP) mission within environmentally acceptable requirements. Technology solutions are outlined, along with processes and priorities for selecting and developing them.

  15. Near-field performance of the advanced cold process canister

    International Nuclear Information System (INIS)

    Werme, L.

    1990-09-01

    A near-field performance evaluation of an Advanced Cold Process Canister for spent fuel disposal has been performed jointly by TVO, Finland and SKB, Sweden. The canister consists of a steel canister as a load bearing element, with an outer corrosion shield of copper. The canister design was originally proposed by TVO. In the analysis, as well internal (ie corrosion processes from the inside of the canister) as external processes (mechanical and chemical) have been considered both prior to and after canister breach. Throughout the analysis, present day underground conditions has been assumed to persist during the service life of the canister. The major conclusions for the evaluation are: Internal processes cannot cause the canister breach under foreseen conditions, ie localized corrosion for the steel or copper canisters can be dismissed as a failure mechanism. The evaluation of the effects of processes outside the canister indicate that there is no rapid mechanism to endanger the integrity of the canister. Consequently the service life of the canister will be several million years. This factor will ensure the safety of the concept. (orig.)

  16. Evaluation of advanced hot conditioning process for PHWRS

    International Nuclear Information System (INIS)

    Chandramohan, P.; Srinivasan, M.P.; Velmurugan, S.

    2015-01-01

    Hot-conditioning/hot functional test process is carried out to the PHT system of reactor before reactor going to critical/operational. The process is aimed in checking the component functionalities at high temperature and high pressure conditions, the process also checks/removes the suspended corrosion products in heat transport circuit. This process leads to formation of a passive or corrosion oxide film on the heat transport circuit surfaces which protects/mitigates the corrosion of the system circuits during the operation of plant. Major concerned alloy in the Primary Heat Transport (PHT) system of Indian PHWRs during the hot conditioning process and also during operation is the carbon steel due to its high corrosion. Hot-conditioning process mitigates the corrosion of carbon steel by the formation of iron oxide (Fe 3 O 4 ) as major oxide phase layer on the carbon steel surface with a typical thickness of 1.0 μm with particle size of 1μm after 336 h of process at 250 °C. But this passive oxide film thickness increase with time of operation of system with c.a. 10μm for 2.2 EFYP. The protectiveness of passive layer can be further enhanced by reducing the particle sizes in the passive film to nano meter range. The process can impact on the compactness of passive oxide layer with reduced pores in the oxide layer and properties of the nano nature oxide (transport properties) impacting the corrosion mitigation. The corrosion mitigation reduce the source term in the activated corrosion product generation. To achieve this a new process 'Advanced hot conditioning' was developed in water steam chemistry division, BARC for getting a passive oxide film with a lowered particle size in the passive film. The AHC process with 1g/L of PEG-8000 at 250 °C for 336 h showed a particle size <100 nm. The process was tested under the normal operating conditions as function of the time, the corrosion parameter like oxide film thickness, corrosion rate and metal ion

  17. Technology Summary Advancing Tank Waste Retrieval And Processing

    International Nuclear Information System (INIS)

    Sams, T.L.; Mendoza, R.E.

    2010-01-01

    This technology overview provides a high-level summary of technologies being investigated and developed by Washington River Protection Solutions (WRPS) to advance Hanford Site tank waste retrieval and processing. Technology solutions are outlined, along with processes and priorities for selecting and developing them. This technology overview provides a high-level summary of technologies being investigated, developed, and deployed by WRPS to advance Hanford Site tank waste retrieval and processing. Transformational technologies are needed to complete Hanford tank waste retrieval and treatment by 12/31/2047. Hanford's underground waste storage tanks hold approximately 57 million gallons of radiochemical waste from nuclear defense production - more tank waste than any other site in the United States. In addition, the waste is uniquely complicated because it contains constituents from at least six major radiochemical processes and several lesser processes. It is intermixed and complexed more than any other waste collection known to exist in the world. The multi-faceted nature of Hanford's tank waste means that legally binding agreements in the Federal Facility Agreement and Consent Order (known as the Tri-Party Agreement) and between the Department of Energy (DOE) and its contractors may not be met using current vitrification schedules, plans, and methods. WRPS and the DOE are developing, testing, and deploying technologies to meet the necessary commitments and complete the DOE's River Protection Project (RPP) mission within environmentally acceptable requirements. Technology solutions are outlined, along with processes and priorities for selecting and developing them. DOE's Office of Environmental Management (EM) identifies the environmental management technology needs and the activities necessary to address them. The U.S. Congress then funds these activities through EM or the DOE field offices. Finally, an array of entities that include DOE site prime contractors and

  18. Liquefaction Microzonation of Babol City Using Artificial Neural Network

    DEFF Research Database (Denmark)

    Farrokhzad, F.; Choobbasti, A.J.; Barari, Amin

    2012-01-01

    that will be less susceptible to damage during earthquakes. The scope of present study is to prepare the liquefaction microzonation map for the Babol city based on Seed and Idriss (1983) method using artificial neural network. Artificial neural network (ANN) is one of the artificial intelligence (AI) approaches...... microzonation map is produced for research area. Based on the obtained results, it can be stated that the trained neural network is capable in prediction of liquefaction potential with an acceptable level of confidence. At the end, zoning of the city is carried out based on the prediction of liquefaction...... that can be classified as machine learning. Simplified methods have been practiced by researchers to assess nonlinear liquefaction potential of soil. In order to address the collective knowledge built-up in conventional liquefaction engineering, an alternative general regression neural network model...

  19. Pressure swing adsorption cycle for natural gas pretreatment for liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Mann, R.E.

    1984-01-10

    An improved apparatus and method for a regeneration of a solid adsorbent used to pretreat a gas before liquefaction. The spent adsorbent is subjected to a two-step regenerative process, in the first of which the adsorbent is subjected to a low pressure produced by the use of mechanical vacuum pumps. When the pressure of the atmosphere in contact with the adsorbent has been reduced to a level sufficiently low to insure that the gas will flow under laminar rather than viscous conditions, the adsorbent is exposed to the action of a cryoplate condenser maintained at a sufficiently low temperature to cause any molecules of water which impinge thereon to condense and freeze, thereby reducing the partial pressure of water vapor within the chamber. The reduced partial pressure of the water vapor in turn causes adsorbed water on the adsorbent to be desorbed, thereby effectively removing the water from the adsorbent and depositing it as solid ice on the cryoplate condenser.

  20. Pulsed high-density plasmas for advanced dry etching processes

    International Nuclear Information System (INIS)

    Banna, Samer; Agarwal, Ankur; Cunge, Gilles; Darnon, Maxime; Pargon, Erwine; Joubert, Olivier

    2012-01-01

    Plasma etching processes at the 22 nm technology node and below will have to satisfy multiple stringent scaling requirements of microelectronics fabrication. To satisfy these requirements simultaneously, significant improvements in controlling key plasma parameters are essential. Pulsed plasmas exhibit considerable potential to meet the majority of the scaling challenges, while leveraging the broad expertise developed over the years in conventional continuous wave plasma processing. Comprehending the underlying physics and etching mechanisms in pulsed plasma operation is, however, a complex undertaking; hence the full potential of this strategy has not yet been realized. In this review paper, we first address the general potential of pulsed plasmas for plasma etching processes followed by the dynamics of pulsed plasmas in conventional high-density plasma reactors. The authors reviewed more than 30 years of academic research on pulsed plasmas for microelectronics processing, primarily for silicon and conductor etch applications, highlighting the potential benefits to date and challenges in extending the technology for mass-production. Schemes such as source pulsing, bias pulsing, synchronous pulsing, and others in conventional high-density plasma reactors used in the semiconductor industry have demonstrated greater flexibility in controlling critical plasma parameters such as ion and radical densities, ion energies, and electron temperature. Specifically, plasma pulsing allows for independent control of ion flux and neutral radicals flux to the wafer, which is key to eliminating several feature profile distortions at the nanometer scale. However, such flexibility might also introduce some difficulty in developing new etching processes based on pulsed plasmas. Therefore, the main characteristics of continuous wave plasmas and different pulsing schemes are compared to provide guidelines for implementing different schemes in advanced plasma etching processes based on

  1. Advances in Process Intensification through Multifunctional Reactor Engineering

    Energy Technology Data Exchange (ETDEWEB)

    O' Hern, Timothy [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Engineering Sciences Center; Evans, Lindsay [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Materials Sciences and Engineering Center; Miller, Jim [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Materials Sciences and Engineering Center; Cooper, Marcia [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Energetic Components Realization Center; Torczynski, John [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Pena, Donovan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Gill, Walt [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Engineering Sciences Center

    2011-02-01

    This project was designed to advance the art of process intensification leading to a new generation of multifunctional chemical reactors utilizing pulse flow. Experimental testing was performed in order to fully characterize the hydrodynamic operating regimes associated with pulse flow for implementation in commercial applications. Sandia National Laboratories (SNL) operated a pilot-scale multifunctional reactor experiment for operation with and investigation of pulse flow operation. Validation-quality data sets of the fluid dynamics, heat and mass transfer, and chemical kinetics were acquired and shared with Chemical Research and Licensing (CR&L). Experiments in a two-phase air-water system examined the effects of bead diameter in the packing, and viscosity. Pressure signals were used to detect pulsing. Three-phase experiments used immiscible organic and aqueous liquids, and air or nitrogen as the gas phase. Hydrodynamic studies of flow regimes and holdup were performed for different types of packing, and mass transfer measurements were performed for a woven packing. These studies substantiated the improvements in mass transfer anticipated for pulse flow in multifunctional reactors for the acid-catalyzed C4 paraffin/olefin alkylation process. CR&L developed packings for this alkylation process, utilizing their alkylation process pilot facilities in Pasadena, TX. These packings were evaluated in the pilot-scale multifunctional reactor experiments established by Sandia to develop a more fundamental understanding of their role in process intensification. Lummus utilized the alkylation technology developed by CR&L to design and optimize the full commercial process utilizing multifunctional reactors containing the packings developed by CR&L and evaluated by Sandia. This hydrodynamic information has been developed for multifunctional chemical reactors utilizing pulse flow, for the acid-catalyzed C4 paraffin/olefin alkylation process, and is now accessible for use in

  2. Economic assessment of advanced flue gas desulfurization processes. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

    1981-09-01

    This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final reprot, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluations, was completed in October 1980. A slightly modified and condensed version of that report appears as appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

  3. Recent Advances in Marine Enzymes for Biotechnological Processes.

    Science.gov (United States)

    Lima, R N; Porto, A L M

    In the last decade, new trends in the food and pharmaceutical industries have increased concern for the quality and safety of products. The use of biocatalytic processes using marine enzymes has become an important and useful natural product for biotechnological applications. Bioprocesses using biocatalysts like marine enzymes (fungi, bacteria, plants, animals, algae, etc.) offer hyperthermostability, salt tolerance, barophilicity, cold adaptability, chemoselectivity, regioselectivity, and stereoselectivity. Currently, enzymatic methods are used to produce a large variety of products that humans consume, and the specific nature of the enzymes including processing under mild pH and temperature conditions result in fewer unwanted side-effects and by-products. This offers high selectivity in industrial processes. The marine habitat has been become increasingly studied because it represents a huge source potential biocatalysts. Enzymes include oxidoreductases, hydrolases, transferases, isomerases, ligases, and lyases that can be used in food and pharmaceutical applications. Finally, recent advances in biotechnological processes using enzymes of marine organisms (bacterial, fungi, algal, and sponges) are described and also our work on marine organisms from South America, especially marine-derived fungi and bacteria involved in biotransformations and biodegradation of organic compounds. © 2016 Elsevier Inc. All rights reserved.

  4. Improved cracking characteristics of bitumen through advanced froth treatment process

    Energy Technology Data Exchange (ETDEWEB)

    Ng, S.H. [National Centre for Upgrading Technology, Devon, AB (Canada); Dabros, T. [Natural Resources Canada, Devon, AB (Canada). CANMET Advanced Separation Technologies Laboratory; Humphries, A. [Albemarle Catalysts Co., Houston, TX (United States)

    2006-07-01

    Fluid catalytic cracking (FCC) is the dominant refinery conversion process for producing transportation fuels. Feed to the FCC unit is heavy gas oil (HGO). Its quality depends on the crude used and the processes involved. Bitumen-derived crude (BDC), including synthetic crude oil (SCO) is less superior to produce FCC feed than stocks from conventional sources. As a result, North American refiners have limited the use of BDC in their conventional FCC-based operations. This paper examined the improved cracking characteristics of bitumen through an advanced froth treatment process. This involved processing of the bitumen with paraffinic solvent in froth treatment with removal of some asphaltenes, CCR precursors, and metals. The paper discussed the experimental and subsequent results and discussion, including cracking characteristics; product quality; synergetic effect; and economic benefits. It was concluded that the poisoning effect by some deleterious components such as nitrogen compounds in feeds on the catalyst could be reduced or compensated for by higher C/O ratios (more catalyst per unit weight of feed). In addition, as conversion increased, sulfur in gasoline decreased slightly and linearly with more or less the same magnitude for the two bitumens. 5 refs., 1 tab., 3 figs.

  5. Applying advanced digital signal processing techniques in industrial radioisotopes applications

    International Nuclear Information System (INIS)

    Mahmoud, H.K.A.E.

    2012-01-01

    Radioisotopes can be used to obtain signals or images in order to recognize the information inside the industrial systems. The main problems of using these techniques are the difficulty of identification of the obtained signals or images and the requirement of skilled experts for the interpretation process of the output data of these applications. Now, the interpretation of the output data from these applications is performed mainly manually, depending heavily on the skills and the experience of trained operators. This process is time consuming and the results typically suffer from inconsistency and errors. The objective of the thesis is to apply the advanced digital signal processing techniques for improving the treatment and the interpretation of the output data from the different Industrial Radioisotopes Applications (IRA). This thesis focuses on two IRA; the Residence Time Distribution (RTD) measurement and the defect inspection of welded pipes using a gamma source (gamma radiography). In RTD measurement application, this thesis presents methods for signal pre-processing and modeling of the RTD signals. Simulation results have been presented for two case studies. The first case study is a laboratory experiment for measuring the RTD in a water flow rig. The second case study is an experiment for measuring the RTD in a phosphate production unit. The thesis proposes an approach for RTD signal identification in the presence of noise. In this approach, after signal processing, the Mel Frequency Cepstral Coefficients (MFCCs) and polynomial coefficients are extracted from the processed signal or from one of its transforms. The Discrete Wavelet Transform (DWT), Discrete Cosine Transform (DCT), and Discrete Sine Transform (DST) have been tested and compared for efficient feature extraction. Neural networks have been used for matching of the extracted features. Furthermore, the Power Density Spectrum (PDS) of the RTD signal has been also used instead of the discrete

  6. The use of mixed pyrrhotite/pyrite catalysts for co-liquefaction of coal and waste rubber tires

    Energy Technology Data Exchange (ETDEWEB)

    Dadyburjor, D.B.; Zondlo, J.W.; Sharma, R.K. [West Virginia Univ., Morgantown, WV (United States)] [and others

    1995-12-31

    The overall objective of this research program is to determine the optimum processing conditions for tire/coal co-liquefaction. The catalysts used will be a ferric-sulfide-based materials, as well as promising catalysts from other consortium laboratories. The intent here is to achieve the maximum coal+tire conversion at the mildest conditions of temperature and pressure. Specific objectives include an investigation of the effects of time, temperature, pressure, catalyst and co-solvent on the conversion and product slate of the co-liquefaction. Accomplishments and conclusions are discussed.

  7. Advanced information processing system: Inter-computer communication services

    Science.gov (United States)

    Burkhardt, Laura; Masotto, Tom; Sims, J. Terry; Whittredge, Roy; Alger, Linda S.

    1991-01-01

    The purpose is to document the functional requirements and detailed specifications for the Inter-Computer Communications Services (ICCS) of the Advanced Information Processing System (AIPS). An introductory section is provided to outline the overall architecture and functional requirements of the AIPS and to present an overview of the ICCS. An overview of the AIPS architecture as well as a brief description of the AIPS software is given. The guarantees of the ICCS are provided, and the ICCS is described as a seven-layered International Standards Organization (ISO) Model. The ICCS functional requirements, functional design, and detailed specifications as well as each layer of the ICCS are also described. A summary of results and suggestions for future work are presented.

  8. Advanced Purex process and waste minimization at La Hague

    International Nuclear Information System (INIS)

    Masson, H.; Nouguier, H.; Bernard, C.; Runge, S.

    1993-01-01

    After a brief recall of the different aspects of the commercial irradiated fuel reprocessing, this paper presents the achievements of the recently commissioned UP3 plant at La Hague. The advanced Purex process implemented with a total waste management results in important waste volume minimization, so that the total volume of high-level and transuranic waste is lower than what it would be in a once-through cycle. Moreover, further minimization is still possible, based on an improved waste management. Cogema has launched the necessary program, which will lead to an overall volume of HLW and TRU wastes of less than 1 m 3 /t by the end of the decade, the maximum possible activity being concentrated in the glass

  9. Extra-terrestrial construction processes - Advancements, opportunities and challenges

    Science.gov (United States)

    Lim, Sungwoo; Prabhu, Vibha Levin; Anand, Mahesh; Taylor, Lawrence A.

    2017-10-01

    Government space agencies, including NASA and ESA, are conducting preliminary studies on building alternative space-habitat systems for deep-space exploration. Such studies include development of advanced technologies for planetary surface exploration, including an in-depth understanding of the use of local resources. Currently, NASA plans to land humans on Mars in the 2030s. Similarly, other space agencies from Europe (ESA), Canada (CSA), Russia (Roscosmos), India (ISRO), Japan (JAXA) and China (CNSA) have already initiated or announced their plans for launching a series of lunar missions over the next decade, ranging from orbiters, landers and rovers for extended stays on the lunar surface. As the Space Odyssey is one of humanity's oldest dreams, there has been a series of research works for establishing temporary or permanent settlement on other planetary bodies, including the Moon and Mars. This paper reviews current projects developing extra-terrestrial construction, broadly categorised as: (i) ISRU-based construction materials; (ii) fabrication methods; and (iii) construction processes. It also discusses four categories of challenges to developing an appropriate construction process: (i) lunar simulants; (ii) material fabrication and curing; (iii) microwave-sintering based fabrication; and (iv) fully autonomous and scaled-up construction processes.

  10. Advanced statistics to improve the physical interpretation of atomization processes

    International Nuclear Information System (INIS)

    Panão, Miguel R.O.; Radu, Lucian

    2013-01-01

    Highlights: ► Finite pdf mixtures improves physical interpretation of sprays. ► Bayesian approach using MCMC algorithm is used to find the best finite mixture. ► Statistical method identifies multiple droplet clusters in a spray. ► Multiple drop clusters eventually associated with multiple atomization mechanisms. ► Spray described by drop size distribution and not only its moments. -- Abstract: This paper reports an analysis of the physics of atomization processes using advanced statistical tools. Namely, finite mixtures of probability density functions, which best fitting is found using a Bayesian approach based on a Markov chain Monte Carlo (MCMC) algorithm. This approach takes into account eventual multimodality and heterogeneities in drop size distributions. Therefore, it provides information about the complete probability density function of multimodal drop size distributions and allows the identification of subgroups in the heterogeneous data. This allows improving the physical interpretation of atomization processes. Moreover, it also overcomes the limitations induced by analyzing the spray droplets characteristics through moments alone, particularly, the hindering of different natures of droplet formation. Finally, the method is applied to physically interpret a case-study based on multijet atomization processes

  11. Advanced Manufacturing Technology Implementation Process in SME: Critical Success Factors

    Directory of Open Access Journals (Sweden)

    Jani Rahardjo

    2010-01-01

    Full Text Available The aim of this paper is to present critical factors that constitute a successful implementation of the Advanced Manufacturing Technologies (AMT in Small Medium Enterprise (SME. Many large companies have applied AMT and the applications have shown significant results in this global market era. Conveniently, these phenomenons are also engaged to Small Medium Enterprises (SME that of high demands on performing high quality product, fast delivery, reliable and more flexible. The implementation of AMT follow several processes namely pre installation, installation, improvement and mature. In order to guarantee the succesfull of running these processes, one should consider the Critical Success Factors (CSF. We conducted a survey to 125 SMEs that have implemented AMT, and found that the CSF for each process are moderately different. Good leadership is the main critical success factor for preparing and installation of the AMT. Once the AMT started or installed and arrived at growth stage, the financial availability factor turns into a critical success factor in the AMT implementation. In, mature stage, the support and commitment of top management becomes an important factor for gaining successful implementation. By means of factor analysis, we could point out that strategic factors are the main factors in pre-installation and installation stage. Finally, in the growth stage and mature stage, both tactical and strategic factors are the important factors in the successful of AMT implementation

  12. Liquefaction of Warukin Formation Coal, Barito Basin, South Kalimantan on Low Pressure and Low Temperature

    Directory of Open Access Journals (Sweden)

    Edy Nursanto

    2013-06-01

    Full Text Available Research focusing on the quality of coal in Warukin Formation has been conducted in coal outcrops located on Tabalong area, particularly in 3 coal seams, namely Wara 120 which consists of low rank coal (lignite. Meanwhile, coals in seam Tutupan 210 and Paringin 712 are medium rank coal (sub-bituminous. Coal liquefaction is conducted in an autoclave on low pressure and temperature. Pressure during the process is 14 psi and temperature is 120oC. Catalyst used are alumina, hydrogen donor NaOH and water solvent. Liquefaction is conducted in three times variables of 30 minutes, 60 minutes and 90 minutes. This process shows following yield : Wara seam 120: 25.37% - 51.27%; Tutupan seam 210: 3.02%-15.45% and seam Paringin 712:1.99%-11.95%. The average result of yield shows that coals in seam Wara has higher yield conversion than coals in seam Tutupan and Paringin.

  13. Coupling hydrothermal liquefaction and anaerobic digestion for energy valorization from model biomass feedstocks.

    Science.gov (United States)

    Posmanik, Roy; Labatut, Rodrigo A; Kim, Andrew H; Usack, Joseph G; Tester, Jefferson W; Angenent, Largus T

    2017-06-01

    Hydrothermal liquefaction converts food waste into oil and a carbon-rich hydrothermal aqueous phase. The hydrothermal aqueous phase may be converted to biomethane via anaerobic digestion. Here, the feasibility of coupling hydrothermal liquefaction and anaerobic digestion for the conversion of food waste into energy products was examined. A mixture of polysaccharides, proteins, and lipids, representing food waste, underwent hydrothermal processing at temperatures ranging from 200 to 350°C. The anaerobic biodegradability of the hydrothermal aqueous phase was examined through conducting biochemical methane potential assays. The results demonstrate that the anaerobic biodegradability of the hydrothermal aqueous phase was lower when the temperature of hydrothermal processing increased. The chemical composition of the hydrothermal aqueous phase affected the anaerobic biodegradability. However, no inhibition of biodegradation was observed for most samples. Combining hydrothermal and anaerobic digestion may, therefore, yield a higher energetic return by converting the feedstock into oil and biomethane. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Method for controlling boiling point distribution of coal liquefaction oil product

    Science.gov (United States)

    Anderson, Raymond P.; Schmalzer, David K.; Wright, Charles H.

    1982-12-21

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships.

  15. Safeguards System for the Advanced Spent Fuel Conditioning Process Facility

    International Nuclear Information System (INIS)

    Kim, Ho-dong; Lee, T.H.; Yoon, J.S.; Park, S.W; Lee, S.Y.; Li, T.K.; Menlove, H.; Miller, M.C.; Tolba, A.; Zarucki, R.; Shawky, S.; Kamya, S.

    2007-01-01

    The advanced spent fuel conditioning process (ACP) which is a part of a pyro-processing has been under development at Korean Atomic Energy Research Institute (KAERI) since 1997 to tackle the problem of an accumulation of spent fuel. The concept is to convert spent oxide fuel into a metallic form in a high temperature molten salt in order to reduce the heat energy, volume, and radioactivity of a spent fuel. Since the inactive tests of the ACP have been successfully implemented to confirm the validity of the electrolytic reduction technology, a lab-scale hot test will be undertaken in a couple of years to validate the concept. For this purpose, the KAERI has built the ACP Facility (ACPF) at the basement of the Irradiated Material Examination Facility (IMEF) of KAERI, which already has a reserved hot-cell area. Through the bilateral arrangement between US Department of Energy (DOE) and Korean Ministry of Science and Technology (MOST) for safeguards R and D, the KAERI has developed elements of safeguards system for the ACPF in cooperation with the Los Alamos National Laboratory (LANL). The reference safeguards design conditions and equipment were established for the ACPF. The ACPF safeguards system has many unique design specifications because of the particular characteristics of the pyro-process materials and the restrictions during a facility operation. For the material accounting system, a set of remote operation and maintenance concepts has been introduced for a non-destructive assay (NDA) system. The IAEA has proposed a safeguards approach to the ACPF for the different operational phases. Safeguards measures at the ACPF will be implemented during all operational phases which include a 'Cold Test', a 'Hot Test' and at the end of a 'Hot test'. Optimization of the IAEA's inspection efforts was addressed by designing an effective safeguards approach that relies on, inter alia, remote monitoring using cameras, installed NDA instrumentation, gate monitors and seals

  16. Indirect Liquefaction of Biomass to Transportation Fuels Via Mixed Oxygenated Intermediates

    Energy Technology Data Exchange (ETDEWEB)

    Tan, Eric C.D.

    2016-11-14

    This paper presents a comparative techno-economic analysis of four emerging conversion pathways from biomass to gasoline-, jet-, and diesel-range hydrocarbons via indirect liquefaction with specific focus on pathways utilizing oxygenated intermediates. The processing steps include: biomass-to-syngas via indirect gasification, gas cleanup, conversion of syngas to alcohols/oxygenates followed by conversion of alcohols/oxygenates to hydrocarbon blendstocks via dehydration, oligomerization, and hydrogenation.

  17. Advances in downstream processing of biologics - Spectroscopy: An emerging process analytical technology.

    Science.gov (United States)

    Rüdt, Matthias; Briskot, Till; Hubbuch, Jürgen

    2017-03-24

    Process analytical technologies (PAT) for the manufacturing of biologics have drawn increased interest in the last decade. Besides being encouraged by the Food and Drug Administration's (FDA's) PAT initiative, PAT promises to improve process understanding, reduce overall production costs and help to implement continuous manufacturing. This article focuses on spectroscopic tools for PAT in downstream processing (DSP). Recent advances and future perspectives will be reviewed. In order to exploit the full potential of gathered data, chemometric tools are widely used for the evaluation of complex spectroscopic information. Thus, an introduction into the field will be given. Copyright © 2016 The Authors. Published by Elsevier B.V. All rights reserved.

  18. Mars Propellant Liquefaction Modeling in Thermal Desktop

    Science.gov (United States)

    Desai, Pooja; Hauser, Dan; Sutherlin, Steven

    2017-01-01

    NASAs current Mars architectures are assuming the production and storage of 23 tons of liquid oxygen on the surface of Mars over a duration of 500+ days. In order to do this in a mass efficient manner, an energy efficient refrigeration system will be required. Based on previous analysis NASA has decided to do all liquefaction in the propulsion vehicle storage tanks. In order to allow for transient Martian environmental effects, a propellant liquefaction and storage system for a Mars Ascent Vehicle (MAV) was modeled using Thermal Desktop. The model consisted of a propellant tank containing a broad area cooling loop heat exchanger integrated with a reverse turbo Brayton cryocooler. Cryocooler sizing and performance modeling was conducted using MAV diurnal heat loads and radiator rejection temperatures predicted from a previous thermal model of the MAV. A system was also sized and modeled using an alternative heat rejection system that relies on a forced convection heat exchanger. Cryocooler mass, input power, and heat rejection for both systems were estimated and compared against sizing based on non-transient sizing estimates.

  19. Ultrafast Bessel beams: advanced tools for laser materials processing

    Science.gov (United States)

    Stoian, Razvan; Bhuyan, Manoj K.; Zhang, Guodong; Cheng, Guanghua; Meyer, Remy; Courvoisier, Francois

    2018-05-01

    Ultrafast Bessel beams demonstrate a significant capacity of structuring transparent materials with a high degree of accuracy and exceptional aspect ratio. The ability to localize energy on the nanometer scale (bypassing the 100-nm milestone) makes them ideal tools for advanced laser nanoscale processing on surfaces and in the bulk. This allows to generate and combine micron and nano-sized features into hybrid structures that show novel functionalities. Their high aspect ratio and the accurate location can equally drive an efficient material modification and processing strategy on large dimensions. We review, here, the main concepts of generating and using Bessel non-diffractive beams and their remarkable features, discuss general characteristics of their interaction with matter in ablation and material modification regimes, and advocate their use for obtaining hybrid micro and nanoscale structures in two and three dimensions (2D and 3D) performing complex functions. High-throughput applications are indicated. The example list ranges from surface nanostructuring and laser cutting to ultrafast laser welding and the fabrication of 3D photonic systems embedded in the volume.

  20. Advanced oxide powders processing based on cascade plasma

    International Nuclear Information System (INIS)

    Solonenko, O P; Smirnov, A V

    2014-01-01

    Analysis of the potential advantages offered to thermal spraying and powder processing by the implementation of plasma torches with inter-electrode insert (IEI) or, in other words, cascade plasma torches (CPTs) is presented. The paper provides evidence that the modular designed single cathode CPT helps eliminate the following major disadvantages of conventional plasma torches: plasma parameters drifting, 1-5 kHz pulsing of plasma flow, as well as excessive erosion of electrodes. More stable plasma results in higher quality, homogeneity and reproducibility of plasma sprayed coatings and powders treated. In addition, CPT offers an extremely wide operating window, which allows better control of plasma parameters, particle dwell time and, consequently, particle temperature and velocity within a wide range by generating high enthalpy quasi-laminar plasmas, medium enthalpy transient plasmas, as well as relatively low enthalpy turbulent plasmas. Stable operation, flexibility with plasma gases as well as wide operating window of CPT should help significantly improve the existing plasma spraying processes and coatings, and also help develop new advanced technologies

  1. Acoustic monitoring of rotating machine by advanced signal processing technology

    International Nuclear Information System (INIS)

    Kanemoto, Shigeru

    2010-01-01

    The acoustic data remotely measured by hand held type microphones are investigated for monitoring and diagnosing the rotational machine integrity in nuclear power plants. The plant operator's patrol monitoring is one of the important activities for condition monitoring. However, remotely measured sound has some difficulties to be considered for precise diagnosis or quantitative judgment of rotating machine anomaly, since the measurement sensitivity is different in each measurement, and also, the sensitivity deteriorates in comparison with an attached type sensor. Hence, in the present study, several advanced signal processing methods are examined and compared in order to find optimum anomaly monitoring technology from the viewpoints of both sensitivity and robustness of performance. The dimension of pre-processed signal feature patterns are reduced into two-dimensional space for the visualization by using the standard principal component analysis (PCA) or the kernel based PCA. Then, the normal state is classified by using probabilistic neural network (PNN) or support vector data description (SVDD). By using the mockup test facility of rotating machine, it is shown that the appropriate combination of the above algorithms gives sensitive and robust anomaly monitoring performance. (author)

  2. Recent Advances in Techniques for Hyperspectral Image Processing

    Science.gov (United States)

    Plaza, Antonio; Benediktsson, Jon Atli; Boardman, Joseph W.; Brazile, Jason; Bruzzone, Lorenzo; Camps-Valls, Gustavo; Chanussot, Jocelyn; Fauvel, Mathieu; Gamba, Paolo; Gualtieri, Anthony; hide

    2009-01-01

    Imaging spectroscopy, also known as hyperspectral imaging, has been transformed in less than 30 years from being a sparse research tool into a commodity product available to a broad user community. Currently, there is a need for standardized data processing techniques able to take into account the special properties of hyperspectral data. In this paper, we provide a seminal view on recent advances in techniques for hyperspectral image processing. Our main focus is on the design of techniques able to deal with the highdimensional nature of the data, and to integrate the spatial and spectral information. Performance of the discussed techniques is evaluated in different analysis scenarios. To satisfy time-critical constraints in specific applications, we also develop efficient parallel implementations of some of the discussed algorithms. Combined, these parts provide an excellent snapshot of the state-of-the-art in those areas, and offer a thoughtful perspective on future potentials and emerging challenges in the design of robust hyperspectral imaging algorithms

  3. Bim Automation: Advanced Modeling Generative Process for Complex Structures

    Science.gov (United States)

    Banfi, F.; Fai, S.; Brumana, R.

    2017-08-01

    The new paradigm of the complexity of modern and historic structures, which are characterised by complex forms, morphological and typological variables, is one of the greatest challenges for building information modelling (BIM). Generation of complex parametric models needs new scientific knowledge concerning new digital technologies. These elements are helpful to store a vast quantity of information during the life cycle of buildings (LCB). The latest developments of parametric applications do not provide advanced tools, resulting in time-consuming work for the generation of models. This paper presents a method capable of processing and creating complex parametric Building Information Models (BIM) with Non-Uniform to NURBS) with multiple levels of details (Mixed and ReverseLoD) based on accurate 3D photogrammetric and laser scanning surveys. Complex 3D elements are converted into parametric BIM software and finite element applications (BIM to FEA) using specific exchange formats and new modelling tools. The proposed approach has been applied to different case studies: the BIM of modern structure for the courtyard of West Block on Parliament Hill in Ottawa (Ontario) and the BIM of Masegra Castel in Sondrio (Italy), encouraging the dissemination and interaction of scientific results without losing information during the generative process.

  4. Application of advanced oxidative process in treatment radioactive waste

    International Nuclear Information System (INIS)

    Kim, Catia; Sakata, Solange K.; Ferreira, Rafael V.P.; Marumo, Julio T.

    2009-01-01

    The ion exchange resin is used in the water purification system in both nuclear research and power reactors. Combined with active carbon, the resin removes dissolved elements from water when the nuclear reactor is operating. After its consumption, it becomes a special type of radioactive waste. The usual treatment to this type of waste is the immobilization with Portland cement, which is simple and low cost. However, its low capacity of immobilization and the increase volume of waste have been the challenges. The development of new technologies capable of destroying this waste completely by increasing its solidification is the main target due to the possibility of both volume and cost reduction. The objective of this work was to evaluate ion exchange resin degradation by Advanced Oxidative Process using Fenton's Reagent (H 2 O 2 / Fe +2 ) in different concentration and temperatures. One advantage of this process is that all additional organic compounds or inorganic solids produced are oxidized easily. The degradation experiments were conducted with IRA-400 resin and Fenton's Reagents, varying the H 2O 2 concentration (30% e 50%) and heat temperature (25, 60 and 100 deg C). The resin degradation was confirmed by the presence of BaCO 3 as a white precipitate resulting from the reaction between the Ba(OH) 2 and the CO 2 from the resin degradation. All experiments run in duplicate. Higher degradation was observed with Fenton's Reagent (Fe +2 /H 2 O 2 30%) at 100 deg C after 2 hours. (author)

  5. Techno-economic Analysis of Acid Gas Removal and Liquefaction for Pressurized LNG

    Science.gov (United States)

    Lee, S. H.; Seo, Y. K.; Chang, D. J.

    2018-05-01

    This study estimated the life cycle cost (LCC) of an acid gas removal and a liquefaction processes for Pressurized LNG (PLNG) production and compared the results with the cost of normal LNG production. PLNG is pressurized LNG that is liquefied at a higher pressure and temperature than normal LNG. Due to the high temperature, the energy for liquefaction is reduced. The allowable CO2 concentration in PLNG is increased up to 3 mol% when the product pressure 25 bar. An amine process with 35 wt% of diethanolamine (DEA) aqueous solution and a nitrogen expansion cycle were selected for the acid gas removal and the liquefaction processes, respectively. Two types of CO2 concentration in the feed gas were investigated to analyze their impacts on the acid gas removal unit. When the CO2 concentration was 5 mol%, the acid gas removal unit was required for both LNG and PLNG production. However, the acid gas removal unit was not necessary in PLNG when the concentration was 0.5 mol% and the pressure was higher than 15 bar. The results showed that the LCC of PLNG was reduced by almost 35% relative to that of LNG when the PLNG pressure was higher than 15 bar.

  6. Conversion of Low-Rank Wyoming Coals into Gasoline by Direct Liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Polyakov, Oleg

    2013-12-31

    Under the cooperative agreement program of DOE and funding from Wyoming State’s Clean Coal Task Force, Western Research Institute and Thermosolv LLC studied the direct conversion of Wyoming coals and coal-lignin mixed feeds into liquid fuels in conditions highly relevant to practice. During the Phase I, catalytic direct liquefaction of sub-bituminous Wyoming coals was investigated. The process conditions and catalysts were identified that lead to a significant increase of desirable oil fraction in the products. The Phase II work focused on systematic study of solvothermal depolymerization (STD) and direct liquefaction (DCL) of carbonaceous feedstocks. The effect of the reaction conditions (the nature of solvent, solvent/lignin ratio, temperature, pressure, heating rate, and residence time) on STD was investigated. The effect of a number of various additives (including lignin, model lignin compounds, lignin-derivable chemicals, and inorganic radical initiators), solvents, and catalysts on DCL has been studied. Although a significant progress has been achieved in developing solvothermal depolymerization, the side reactions – formation of considerable amounts of char and gaseous products – as well as other drawbacks do not render aqueous media as the most appropriate choice for commercial implementation of STD for processing coals and lignins. The trends and effects discovered in DCL point at the specific features of liquefaction mechanism that are currently underutilized yet could be exploited to intensify the process. A judicious choice of catalysts, solvents, and additives might enable practical and economically efficient direct conversion of Wyoming coals into liquid fuels.

  7. Advanced Drying Process for Lower Manufacturing Cost of Electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, Iftikhar [Lambda Technologies, Inc., Morrisville, NC (United States); Zhang, Pu [Lambda Technologies, Inc., Morrisville, NC (United States)

    2016-11-30

    For this Vehicle Technologies Incubator/Energy Storage R&D topic, Lambda Technologies teamed with Navitas Systems and proposed a new advanced drying process that promised a 5X reduction in electrode drying time and significant reduction in the cost of large format lithium batteries used in PEV's. The operating principle of the proposed process was to use penetrating radiant energy source Variable Frequency Microwaves (VFM), that are selectively absorbed by the polar water or solvent molecules instantly in the entire volume of the electrode. The solvent molecules are thus driven out of the electrode thickness making the process more efficient and much faster than convective drying method. To evaluate the Advanced Drying Process (ADP) a hybrid prototype system utilizing VFM and hot air flow was designed and fabricated. While VFM drives the solvent out of the electrode thickness, the hot air flow exhausts the solvent vapors out of the chamber. The drying results from this prototype were very encouraging. For water based anodes there is a 5X drying advantage (time & length of oven) in using ADP over standard drying system and for the NMP based cathodes the reduction in drying time has 3X benefit. For energy savings the power consumption measurements were performed to ADP prototype and compared with the convection standard drying oven. The data collected demonstrated over 40% saving in power consumption with ADP as compared to the convection drying systems. The energy savings are one of the operational cost benefits possible with ADP. To further speed up the drying process, the ADP prototype was explored as a booster module before the convection oven and for the electrode material being evaluated it was possible to increase the drying speed by a factor of 4, which could not be accomplished with the standard dryer without surface defects and cracks. The instantaneous penetration of microwave in the entire slurry thickness showed a major advantage in rapid drying of

  8. Advanced modelling, monitoring, and process control of bioconversion systems

    Science.gov (United States)

    Schmitt, Elliott C.

    Production of fuels and chemicals from lignocellulosic biomass is an increasingly important area of research and industrialization throughout the world. In order to be competitive with fossil-based fuels and chemicals, maintaining cost-effectiveness is critical. Advanced process control (APC) and optimization methods could significantly reduce operating costs in the biorefining industry. Two reasons APC has previously proven challenging to implement for bioprocesses include: lack of suitable online sensor technology of key system components, and strongly nonlinear first principal models required to predict bioconversion behavior. To overcome these challenges batch fermentations with the acetogen Moorella thermoacetica were monitored with Raman spectroscopy for the conversion of real lignocellulosic hydrolysates and a kinetic model for the conversion of synthetic sugars was developed. Raman spectroscopy was shown to be effective in monitoring the fermentation of sugarcane bagasse and sugarcane straw hydrolysate, where univariate models predicted acetate concentrations with a root mean square error of prediction (RMSEP) of 1.9 and 1.0 g L-1 for bagasse and straw, respectively. Multivariate partial least squares (PLS) models were employed to predict acetate, xylose, glucose, and total sugar concentrations for both hydrolysate fermentations. The PLS models were more robust than univariate models, and yielded a percent error of approximately 5% for both sugarcane bagasse and sugarcane straw. In addition, a screening technique was discussed for improving Raman spectra of hydrolysate samples prior to collecting fermentation data. Furthermore, a mechanistic model was developed to predict batch fermentation of synthetic glucose, xylose, and a mixture of the two sugars to acetate. The models accurately described the bioconversion process with an RMSEP of approximately 1 g L-1 for each model and provided insights into how kinetic parameters changed during dual substrate

  9. NATO Advanced Study Institute on Chemical Transport in Melasomatic Processes

    CERN Document Server

    1987-01-01

    As indicated on the title page, this book is an outgrowth of the NATO Advanced Study Institute (ASI) on Chemical Transport in Metasomatic Processes, which was held in Greece, June 3-16, 1985. The ASI consisted of five days of invited lectures, poster sessions, and discussion at the Club Poseidon near Loutraki, Corinthia, followed by a two-day field trip in Corinthia and Attica. The second week of the ASI consisted of an excursion aboard M/S Zeus, M/Y Dimitrios II, and the M/S Irini to four of the Cycladic Islands to visit, study, and sample outstanding exposures of metasomatic activity on Syros, Siphnos, Seriphos, and Naxos. Nine­ teen invited lectures and 10 session chairmen/discussion leaders participated in the ASI, which was attended by a total of 92 professional scientists and graduate stu­ dents from 15 countries. Seventeen of the invited lectures and the Field Excursion Guide are included in this volume, together with 10 papers and six abstracts representing contributed poster sessions. Although more...

  10. Pengolahan Limbah Cair Pabrik Pupuk Urea Menggunakan Advanced Oxidation Processes

    Directory of Open Access Journals (Sweden)

    Darmadi Darmadi

    2014-06-01

    Full Text Available Limbah cair pabrik pupuk urea terdiri dari urea dan amonium yang masing-masing mempunyai konsentrasi berkisar antara 1500-10000 ppm dan 400-3000 ppm. Konsentrasi urea yang tinggi di dalam badan air dapat menyebabkan blooming algae dalam ekosistem tersebut yang dapat mengakibatkan kehidupan biota air lain terserang penyakit. Peristiwa ini terjadi karena kurangnya nutrisi bagi biota air dan sedikitnya sinar matahari yang dapat menembusi permukaan air. Disamping kedua hal tersebut di atas, algae juga dapat memproduksi senyawa beracun bagi biota air dan manusia. Penelitian ini bertujuan untuk mengolah urea menggunakan oksidasi konvensional (H2O2 dan Advanced Oxidation Processes (kombinasi H2O2-Fe2+ pada pH 5 dengan parameter yang digunakan adalah variasi konsen-trasi awal H2O2  dan konsentrasi Fe2+. Hasil percobaan menunjukkan bahwa penurunan konsentrasi urea tertinggi diperoleh pada penggunaan reagen fenton (8000 ppm H2O2 dan 500 ppm Fe2+, yaitu dapat menurunkan urea dari konsentrasi awal urea 2566,145 ppm menjadi 0 ppm. Kinetika reaksi dekomposisi urea menjadi amonium dan amonium menjadi nitrit dan nitrat yang diuji mengikuti laju kinetika reaksi orde 1 (satu terhadap urea dan orde satu terhadap amonium dengan konstanta laju reaksi masing-masing k1 = 0,019 dan k2 = 0,022 min-1.

  11. Anvil Forecast Tool in the Advanced Weather Interactive Processing System

    Science.gov (United States)

    Barrett, Joe H., III; Hood, Doris

    2009-01-01

    Meteorologists from the 45th Weather Squadron (45 WS) and National Weather Service Spaceflight Meteorology Group (SMG) have identified anvil forecasting as one of their most challenging tasks when predicting the probability of violations of the Lightning Launch Commit Criteria and Space Shuttle Flight Rules. As a result, the Applied Meteorology Unit (AMU) was tasked to create a graphical overlay tool for the Meteorological Interactive Data Display System (MIDDS) that indicates the threat of thunderstorm anvil clouds, using either observed or model forecast winds as input. The tool creates a graphic depicting the potential location of thunderstorm anvils one, two, and three hours into the future. The locations are based on the average of the upper level observed or forecasted winds. The graphic includes 10 and 20 n mi standoff circles centered at the location of interest, as well as one-, two-, and three-hour arcs in the upwind direction. The arcs extend outward across a 30 sector width based on a previous AMU study that determined thunderstorm anvils move in a direction plus or minus 15 of the upper-level wind direction. The AMU was then tasked to transition the tool to the Advanced Weather Interactive Processing System (AWIPS). SMG later requested the tool be updated to provide more flexibility and quicker access to model data. This presentation describes the work performed by the AMU to transition the tool into AWIPS, as well as the subsequent improvements made to the tool.

  12. Workshop on Processing Physic-Chemistry Advanced – WPPCA

    International Nuclear Information System (INIS)

    2016-01-01

    In the present volume of Journal of Physics: Conference Series we publish the proceedings of the “2nd Workshop on Processing Physic-Chemistry advanced (WPPCA)”, that was held from, April 4-8, 2016, at the Universidad Industrial de Santander (UIS), Bucaramanga, Colombia. The proceedings consist of 17 contributions that were presented as plenary talks at the event. The abstracts of all participants contributions were published in the Abstract Book with ISSN 2500-8420. The scientific program of the 2nd WPPCA consisted of 12 Magisterial Conferences, 28 Poster Presentations and 2 Courses with the participation of undergraduate and graduate students, professors, researchers and entrepreneurs from Colombia, Spain, Unite States of America, Mexico and Chile. Moreover, the 2nd WPPCA allowed to establish a shared culture of the research and innovation that enriches the area of the processing physical-chemistry of the materials and the industrial applications. All papers in these Proceedings refer to one from the following topics: Semiconductors, Superconductivity, Nanostructure Materials and Modelling, Simulation and Diagnostics. The editor hopes that those interested in the area of the science of materials can to enjoy this reading, that reflects a wide variety of current issues. On behalf of the organizing committee of the 2nd WPPCA, we are extremely thankful to all authors for providing their valuable contributions for these Proceedings as well as the reviewers for their constructive recommendations and criticism aiding to improve the presented articles. Besides, especially we appreciate the great support provided by the Sponsors and Partners. (paper)

  13. Technology advancement of the electrochemical CO2 concentrating process

    Science.gov (United States)

    Schubert, F. H.; Heppner, D. B.; Hallick, T. M.; Woods, R. R.

    1979-01-01

    Two multicell, liquid-cooled, advanced electrochemical depolarized carbon dioxide concentrator modules were fabricated. The cells utilized advanced, lightweight, plated anode current collectors, internal liquid cooling and lightweight cell frames. Both were designed to meet the carbon dioxide removal requirements of one-person, i.e., 1.0 kg/d (2.2 lb/d).

  14. Designer silica layers for advanced applications: Processing and properties

    Science.gov (United States)

    Anderson, Adam

    Recently, as scientists have investigated the application of conventional MEMS devices to biological systems, the exciting fields of bio-MEMS and microfluidics have emerged. Due to their small size, bio-MEMS and microfluidics devices offer the advantage of requiring only small sample and reagent volumes, in a potentially low-cost, integrated package. Such devices have the potential to significantly advance point-of-care diagnostics devices and improve overall patient care. However, due to the extremely small feature size, the large surface area-to-volume ratio in these devices makes controlling surface interactions of critical importance. Recently, there has been a shift to polymeric materials for fabrication of microfluidics devices due to their lower cost, ease of device fabrication by various processes, varied and favorable material properties, and, in some cases, pre-existing regulatory agency approvals. As a result, various surface modification strategies for polymeric surfaces have been proposed, but with only limited success. The proven success of organosilicon-based precursors in a wide variety of surface modification strategies has been demonstrated, with a body of knowledge on the general subject dating back nearly fifty years. However, these proven methodologies cannot be transferred to many important polymeric materials due to a lack of sufficient reactive groups on the surface. If any polymer surface could be made reactive by some intermediate treatment, the wide body of knowledge of organosilicon-based surface modification chemistries could be leveraged to advance the state-of-the-art in surface modification for microfluidics applications, where polymeric substrates are commonly encountered. This thesis reports on the processing properties and chemical properties of a vapor deposited silica layer, which is formed from the vapor phase hydrolysis of silicon tetrachloride. This layer can be deposited at low temperatures to a wide variety of substrates

  15. Numerical simulation of liquefaction behaviour of granular materials ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    cles using Discrete Element Method (DEM) is used to study the liquefaction behaviour of ... studies have focussed on the stress-strain relation- ... experimentation still remains quite problematic. ... distorting the periodic cell and changing its vol-.

  16. On the risk of liquefaction of buffer and backfill

    Energy Technology Data Exchange (ETDEWEB)

    Pusch, R. [Geodevelopment AB, Lund (Sweden)

    2000-10-01

    The necessary prerequisites for liquefaction of buffers and backfills in a KBS-3 repository exist but the stress conditions and intended densities practically eliminate the risk of liquefaction for single earthquakes with magnitudes up to M=8 and normal duration. For buffers rich in expandable minerals it would be possible to reduce the density at water saturation to 1,700 - 1,800 kg/m{sup 3} or even less without any significant risk of liquefaction, while the density at saturation of backfills with 10 - 15% expandable clay should not be reduced to less than about 1,900 kg/m{sup 3}. Since the proposed densities of both buffers and backfills will significantly exceed these minimum values it is concluded that there is no risk of liquefaction of the engineered soil barriers in a KBS-3 repository even for very significant earthquakes.

  17. On the risk of liquefaction of buffer and backfill

    International Nuclear Information System (INIS)

    Pusch, R.

    2000-10-01

    The necessary prerequisites for liquefaction of buffers and backfills in a KBS-3 repository exist but the stress conditions and intended densities practically eliminate the risk of liquefaction for single earthquakes with magnitudes up to M=8 and normal duration. For buffers rich in expandable minerals it would be possible to reduce the density at water saturation to 1,700 - 1,800 kg/m 3 or even less without any significant risk of liquefaction, while the density at saturation of backfills with 10 - 15% expandable clay should not be reduced to less than about 1,900 kg/m 3 . Since the proposed densities of both buffers and backfills will significantly exceed these minimum values it is concluded that there is no risk of liquefaction of the engineered soil barriers in a KBS-3 repository even for very significant earthquakes

  18. Initial Earthquake Centrifuge Model Experiments for the Study of Liquefaction

    National Research Council Canada - National Science Library

    Steedman, R

    1998-01-01

    .... These are intended to gather data suitable for the development of improved design approaches for the prediction of liquefaction under earthquake loading using the new centrifuge facility at the WES...

  19. Whole Algae Hydrothermal Liquefaction: 2014 State of Technology

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Susanne B.; Zhu, Yunhua; Snowden-Swan, Lesley J.; Anderson, Daniel; Hallen, Richard T.; Schmidt, Andrew J.; Albrecht, Karl O.; Elliott, Douglas C.

    2014-07-30

    This report describes the base case yields and operating conditions for converting whole microalgae via hydrothermal liquefaction and upgrading to liquid fuels. This serves as the basis against which future technical improvements will be measured.

  20. Assessment of Soil Liquefaction Potential Based on Numerical Method

    DEFF Research Database (Denmark)

    Choobasti, A. Janalizadeh; Vahdatirad, Mohammad Javad; Torabi, M.

    2012-01-01

    Paying special attention to geotechnical hazards such as liquefaction in huge civil projects like urban railways especially in susceptible regions to liquefaction is of great importance. A number of approaches to evaluate the potential for initiation of liquefaction, such as Seed and Idriss...... simplified method have been developed over the years. Although simplified methods are available in calculating the liquefaction potential of a soil deposit and shear stresses induced at any point in the ground due to earthquake loading, these methods cannot be applied to all earthquakes with the same...... accuracy, also they lack the potential to predict the pore pressure developed in the soil. Therefore, it is necessary to carry out a ground response analysis to obtain pore pressures and shear stresses in the soil due to earthquake loading. Using soil historical, geological and compositional criteria...

  1. New method for evaluating liquefaction potential

    Energy Technology Data Exchange (ETDEWEB)

    Arulmoli, K.; Arulanandan, K.; Seed, H.B.

    1985-01-01

    A new method of indexing the grain and aggregate properties of sand using electrical parameters is described. Correlations are established between these parameters and relative density, D /sub r/ , cyclic stress ratio, /tau//sigma'/sub 0/, and K2 /sub max/ . An electrical probe, used to predict these parameters from in-situ electrical measurements, is described. Evaluations are made of D /sub r/ and /tau//sigma/sub 0/, which are compared with values measured independently from controlled laboratory tests. Reasonable agreement is found between predicted and measured values. The potential applicability of the electrical probe in the field is shown by evaluation of liquefaction and nonliquefaction at sites affected by the 1906 San Francisco, Niigata and Tangshan earthquakes.

  2. Liquefaction Potential for Soil Deposits in Muscat, Oman

    Science.gov (United States)

    El Hussain, I. W.; Deif, A.; Girgis, M.; Al-Rawas, G.; Mohamed, A.; Al-Jabri, K.; Al-Habsi, Z.

    2015-12-01

    Muscat is located in the northeastern part of Oman on a narrow strip between Oman coast and Oman Mountains, which is the place for at least four earthquakes of order of 5.2 magnitude in the last 1300 years. The near surface geology of Muscat varies from hard rocks in the eastern, southern and western parts to dense and lose sediments in the middle and northern parts. Liquefaction occurs in saturated cohesionless soils when its shear strength decreased to zero due to the increase of pore pressure. More than 500 boreholes in Muscat area were examined for their liquefaction susceptibility based on the soil characteristics data. Only soils susceptible to liquefaction are further considered for liquefaction hazard assessment. Liquefaction occurs if the cyclic stress ratio (CSR) caused by the earthquake is higher than the cyclic resistance ratio (CRR) of the soil. CSR values were evaluated using PGA values at the surface obtained from previously conducted seismic hazard and microzonation studies. CRR for Muscat region is conducted using N values of SPT tests from numerous borehole data and the shear wave velocity results from 99 MASW surveys over the entire region. All the required corrections are conducted to get standardized (N1) 60 values, to correct shear-wave velocity, and scale the results for Mw 6.0 instead of the proposed 7.5 (magnitude scaling factor). Liquefaction hazard maps are generated using the minimum factor of safety (FS) at each site as a representative of the FS against liquefaction at that location. Results indicate that under the current level of seismic hazard, liquefaction potential is possible at few sites along the northern coast where alluvial soils and shallow ground water table are present. The expected soft soil settlement is also evaluated at each liquefiable site.

  3. A new boil-off gas re-liquefaction system for LNG carriers based on dual mixed refrigerant cycle

    Science.gov (United States)

    Tan, Hongbo; Shan, Siyu; Nie, Yang; Zhao, Qingxuan

    2018-06-01

    A new boil-off gas (BOG) re-liquefaction system for LNG carriers has been proposed to improve the system energy efficiency. Two cascade mixed refrigerant cycles (or dual mixed refrigerant cycle, DMR) are used to provide the cooling capacity for the re-liquefaction of BOG. The performance of the new system is analysed on the basis of the thermodynamic data obtained in the process simulation in Aspen HYSYS software. The results show that the power consumed in the BOG compressor and the high-temperature mixed refrigerant compressor could be saved greatly due to the reduced mass flow rates of the processed fluids. Assuming the re-liquefaction capacity of the investigated system is 4557.6 kg/h, it is found that the total power consumption can be reduced by 25%, from 3444 kW in the existing system to 2585.8 kW in the proposed system. The coefficient of performance (COP) of 0.25, exergy efficiency of 41.3% and the specific energy consumption (SEC) of 0.589 kWh/kg(LNG) could be achieved in the new system. It exhibits 33% of improvement in the COP and exergy efficiency in comparison with the corresponding values of the existing system. It indicates that employing the DMR based BOG re-liquefaction system could improve the system energy efficiency of LNG carriers substantially.

  4. Report on the bituminous coal liquefaction sub-committee in fiscal 1992; 1992 nendo rekiseitan ekika bukai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-03-01

    This paper reports the activities of the bituminous coal liquefaction sub-committee in the Sunshine Project in fiscal 1992. With an intention of developing a technology on the process (NEDOL) suitable for liquefaction of wide range of coal types placing sub-bituminous coal at the center, researches were carried out by using a pilot plant, and engineering data purposed for practical application of the technology were acquired. The construction of the pilot plant was launched in fiscal 1991. It is necessary to execute the pilot plant plan steadily in the future, and at the same time, reliably acquire different data by means of supportive researches. Economic performance of the process is also important. The first sub-committee meeting presented the following agenda: the status of constructing the 150-t/d pilot plant, tests and investigations thereon, research works by using a 1-t/d PSU, development of the most suitable coal refining technology, development of a coal pretreatment technology, improvement of the distilled oil distribution, studies on coal liquefaction conditions, and studies on solvent hydrogenating catalysts. The second sub-committee meeting presented the following agenda: the status of constructing the pilot plant, tests and investigations on improving the performance of natural pylite catalyst and circulating solvent, technological investigations on structuring a liquefying reaction data analyzing system, studies using a 1-t/d PSU, development of the most suitable coal refining technology, studies on coal liquefaction conditions, and studies on solvent hydrogenating catalysts. (NEDO)

  5. Role of expanders in helium liquefaction cycles: Parametric studies using Collins cycle

    International Nuclear Information System (INIS)

    Thomas, Rijo Jacob; Ghosh, Parthasarathi; Chowdhury, Kanchan

    2011-01-01

    Large scale helium liquefaction/refrigeration plant is a key subsystem of fusion devices. Performance of these plants is dependent on a number of geometric and operating parameters of its constituting components such as compressors, heat exchangers, expanders, valves, etc. Expander has been chosen as the subject matter of analyses in the present study. As the sensible cold of helium vapor is lost in liquefiers, the expanders in liquefaction cycles have to provide more refrigeration than those in refrigeration cycles. The expander parameters such as rate of mass flow, operating pressure, inlet temperature, etc. are inter-dependent, and hence, it is difficult to predict the system behavior with variation of a particular parameter. This necessitates the use of process simulators. Parametric studies have been performed on Collins helium liquefaction cycle using Aspen HYSYS. Collins cycle has all the basic characteristics of a large-scale helium liquefier and the results of this study may be extrapolated to understand the behavior of large scale helium liquefiers. The study shows that the maximum liquid production is obtained when 80% of the compressor flow is diverted through the expanders and it is equally distributed between the two expanders. The relationships between the liquid production and the isentropic efficiency of expanders are almost linear and both the higher and lower temperature expanders exhibit similar trends.

  6. Role of expanders in helium liquefaction cycles: Parametric studies using Collins cycle

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, Rijo Jacob, E-mail: rijojthomas@gmail.com [Cryogenic Engineering Centre, Indian Institute of Technology, Kharagpur, West Bengal 721302 (India); Ghosh, Parthasarathi; Chowdhury, Kanchan [Cryogenic Engineering Centre, Indian Institute of Technology, Kharagpur, West Bengal 721302 (India)

    2011-06-15

    Large scale helium liquefaction/refrigeration plant is a key subsystem of fusion devices. Performance of these plants is dependent on a number of geometric and operating parameters of its constituting components such as compressors, heat exchangers, expanders, valves, etc. Expander has been chosen as the subject matter of analyses in the present study. As the sensible cold of helium vapor is lost in liquefiers, the expanders in liquefaction cycles have to provide more refrigeration than those in refrigeration cycles. The expander parameters such as rate of mass flow, operating pressure, inlet temperature, etc. are inter-dependent, and hence, it is difficult to predict the system behavior with variation of a particular parameter. This necessitates the use of process simulators. Parametric studies have been performed on Collins helium liquefaction cycle using Aspen HYSYS. Collins cycle has all the basic characteristics of a large-scale helium liquefier and the results of this study may be extrapolated to understand the behavior of large scale helium liquefiers. The study shows that the maximum liquid production is obtained when 80% of the compressor flow is diverted through the expanders and it is equally distributed between the two expanders. The relationships between the liquid production and the isentropic efficiency of expanders are almost linear and both the higher and lower temperature expanders exhibit similar trends.

  7. Fiscal 1995 report. Liquefaction key technology subcommittee; 1995 nendo ekika kiban gijutsu bukai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The subcommittee held the 1st meeting in September 1955 and the 2nd in March 1996, when fiscal 1995 research plans and research results were introduced and deliberated. In the study for designing a high-dispersion catalyst and the elucidation of the mechanism of activity expression, catalysts of highly dispersed iron supported on the brown coal surface in various ways were compared with each other in terms of liquefaction activity. Furthermore, geometric changes in the iron catalyst during the sulfurizing process were examined using the XRD (X-ray diffraction) and TEM (transient electromagnetic) methods. An improved catalyst was found to achieve a liquefaction yield near the Yallourn coal liquefaction limit in a high boiling solvent system. Concerning the study of coal oil product applications and refining technologies, reports were delivered on research results relating to the problem of blocking to occur during naphtha fraction refining and measures therefor, inhibition of active metal geometric changes during reaction, methods for separating hetero-compounds from coal oil and application thereof, and so forth. (NEDO)

  8. Rotating disk atomization of Gd and Gd-Y for hydrogen liquefaction via magnetocaloric cooling

    Energy Technology Data Exchange (ETDEWEB)

    Slinger, Tyler [Iowa State Univ., Ames, IA (United States)

    2016-12-17

    In order to enable liquid hydrogen fuel cell technologies for vehicles the cost of hydrogen liquefaction should be lowered. The current method of hydrogen liquefaction is the Claude cycle that has a figure of merit (FOM) of 0.3-0.35. New magnetocaloric hydrogen liquefaction devices have been proposed with a FOM>0.5, which is a significant improvement. A significant hurdle to realizing these devices is the synthesis of spherical rare earth based alloy powders of 200μm in diameter. In this study a centrifugal atomization method that used a rotating disk with a rotating oil quench bath was developed to make gadolinium and gadolinium-yttrium spheres. The composition of the spherical powders included pure Gd and Gd0.91Y0.09. The effect of atomization parameters, such as superheat, melt properties, disk shape, disk speed, and melt system materials and design, were investigated on the size distribution and morphology of the resulting spheres. The carbon, nitrogen, and oxygen impurity levels also were analyzed and compared with the magnetic performance of the alloys. The magnetic properties of the charge material as well as the resulting powders were measured using a vibrating sample magnetometer. The saturation magnetization and Curie temperature were the target properties for the resulting spheres. These values were compared with measurements taken on the charge material in order to investigate the effect of atomization processing on the alloys.

  9. Environmental assessment of different solar driven advanced oxidation processes

    Energy Technology Data Exchange (ETDEWEB)

    Munoz, Ivan; Rieradevall, Joan [Institut de Ciencia i Tecnologia Ambientals (ICTA), Universitat Autonoma de Barcelona, 08193 Bellaterra (Barcelona) (Spain); Torrades, Francesc [Departament d' Enginyeria Quimica, ETSEI de Terrassa, Universitat Politecnica de Catalunya, 08222 Terrassa (Barcelona) (Spain); Peral, Jose; Domenech, Xavier [Departament de Quimica, Universitat Autonoma de Barcelona, 08193 Bellaterra (Barcelona) (Spain)

    2005-10-01

    In this work a comparative environmental assessment of different advanced oxidation processes (AOP's) is performed. Two energy scenarios have been considered according to the energy source used: solar energy and electricity (UVA lamp). A life cycle assessment (LCA) is carried out in order to quantify the environmental impacts of the AOP's. The treatments considered are heterogenous photocatalysis, photo-Fenton reactions, the coupling of heterogeneous photocatalysis and photo-Fenton, and heterogeneous photocatalysis in combination with hydrogen peroxide. These AOP's are applied to the treatment of kraft mill bleaching wastewaters. The system under study includes the production of the catalysts, reagents as well as the production of electricity; eight environmental impact categories are assessed for each AOP: global warming, ozone depletion, aquatic eutrophication, acidification, human toxicity, freshwater aquatic toxicity, photochemical ozone formation, and abiotic resource depletion. the results of the LCA show that the environmental impact of AOP's is caused mainly by the amount of electricity consumed, whereas the impact of producing the reagents and catalysts is comparatively low. For this reason, the solar energy scenario reduces the impact more than 90% for almost all AOP's and impact categories. None of the solar driven AOP's can be identified as the best in all impact categories, but heterogenous photocatalysis and photo-Fenton reactions obtain better results than the remaining treatments, since these treatments do not consume simultaneously both TiO{sub 2} and H{sub 2}O{sub 2}, the chemicals with highest environmental burdens in the system. (author)

  10. Plan for advanced microelectronics processing technology application. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Goland, A.N.

    1990-10-01

    The ultimate objective of the tasks described in the research agreement was to identify resources primarily, but not exclusively, within New York State that are available for the development of a Center for Advanced Microelectronics Processing (CAMP). Identification of those resources would enable Brookhaven National Laboratory to prepare a program plan for the CAMP. In order to achieve the stated goal, the principal investigators undertook to meet the key personnel in relevant NYS industrial and academic organizations to discuss the potential for economic development that could accompany such a Center and to gauge the extent of participation that could be expected from each interested party. Integrated of these discussions was to be achieved through a workshop convened in the summer of 1990. The culmination of this workshop was to be a report (the final report) outlining a plan for implementing a Center in the state. As events unfolded, it became possible to identify the elements of a major center for x-ray lithography on Lone Island at Brookhaven National Laboratory. The principal investigators were than advised to substitute a working document based upon that concept in place of a report based upon the more general CAMP workshop originally envisioned. Following that suggestion from the New York State Science and Technology Foundation, the principals established a working group consisting of representatives of the Grumman Corporation, Columbia University, the State University of New York at Stony Brook, and Brookhaven National Laboratory. Regular meetings and additional communications between these collaborators have produced a preproposal that constitutes the main body of the final report required by the contract. Other components of this final report include the interim report and a brief description of the activities which followed the establishment of the X-ray Lithography Center working group.

  11. The Liquefaction of Hydrogen and Helium Using Small Coolers

    International Nuclear Information System (INIS)

    Green, Michael A.

    2006-01-01

    This report discusses the history of the liquefaction of hydrogen and helium using small coolers. This history dates form the 1960's when two stage GM coolers capable of reaching 7 K were used to liquefy helium and hydrogen by suing an added compressor and J-T circuit. Liquefaction using the added circuit failed to become mainstream because the J-T valve and heat exchanger clogged because of impurities in the gas being liquefied. Liquefaction using a GM cooler without an added J-T circuit proved to be difficult because the first stage was not used to pre-cool the gas coming to the second stage of the cooler. Once the gas being liquefied was pre-cooled using the cooler first stage, improvements in the liquefaction rates were noted. The advent of low temperature pulse tube cooler (down to 2.5 K) permitted one to achieve dramatic improvement is the liquefactions rates for helium. Similar but less dramatic improvements are expected for hydrogen as well. Using the PT-415 cooler, one can expect liquefaction rates of 15 to 20 liters per day for helium or hydrogen provided the heat leak into the cooler and the storage vessel is low. A hydrogen liquefier for MICE is presented at the end of this report

  12. Mongolian coal liquefaction test; Mongorutan no ekika tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, H.; Kubo, H. [Mitsui SRC Development Co. Ltd., Tokyo (Japan); Tsedevsuren, T. [National Research Center of Chemistry and Technology of Coal in Mongoria (Mongolia)

    1996-10-28

    This paper describes the results of liquefaction tests of Mongolian coals using an autoclave and a flow micro reactor. Uvdughudag coal, Hootiinhonhor coal, and Shivee-Ovoo coal were used for liquefaction tests with an autoclave. Oil yields of Uvdughudag and Hootiinhonhor coals were 55.56 wt% and 55.29 wt%, respectively, which were similar to that of Wyoming coal. Similar results were obtained, as to produced gas and water yields. These coals were found to be suitable for coal liquefaction. Lower oil yield, 42.55 wt% was obtained for Shivee-Ovoo coal, which was not suitable for liquefaction. Liquefaction tests were conducted for Uvdughudag coal with a flow micro reactor. The oil yield was 55.7 wt%, which was also similar to that of Wyoming coal, 56.1 wt%. Hydrogen consumption of Uvdughudag coal was also similar to that of Wyoming coal. From these, Uvdughudag coal can be a prospective coal for liquefaction. From the distillation distribution of oil, distillate fraction yield below 350{degree}C of Uvdughudag coal was 50.7 wt%, which was much higher than that of Wyoming coal, 35.6 wt%. Uvdughudag coal is a coal with high light oil fraction yield. 2 figs., 5 tabs.

  13. U.S. DOE indirect coal liquefaction program: An overview

    Energy Technology Data Exchange (ETDEWEB)

    Shen, J.; Schmetz, E.; Winslow, J.; Tischer, R. [Dept. of Energy, Germantown, MD (United States); Srivastava, R.

    1997-12-31

    Coal is the most abundant domestic energy resource in the United States. The Fossil Energy Organization within the US Department of Energy (DOE) has been supporting a coal liquefaction program to develop improved technologies to convert coal to clean and cost-effective liquid fuels to complement the dwindling supply of domestic petroleum crude. The goal of this program is to produce coal liquids that are competitive with crude at $20 to $25 per barrel. Indirect and direct liquefaction routes are the two technologies being pursued under the DOE coal liquefaction program. This paper will give an overview of the DOE indirect liquefaction program. More detailed discussions will be given to the F-T diesel and DME fuels which have shown great promises as clean burning alternative diesel fuels. The authors also will briefly discuss the economics of indirect liquefaction and the hurdles and opportunities for the early commercial deployment of these technologies. Discussions will be preceded by two brief reviews on the liquid versus gas phase reactors and the natural gas versus coal based indirect liquefaction.

  14. Supply Chain Sustainability Analysis of Indirect Liquefaction of Blended Biomass to Produce High Octane Gasoline

    Energy Technology Data Exchange (ETDEWEB)

    Cai, Hao [Argonne National Lab. (ANL), Argonne, IL (United States); Canter, Christina E. [Argonne National Lab. (ANL), Argonne, IL (United States); Dunn, Jennifer B. [Argonne National Lab. (ANL), Argonne, IL (United States); Tan, Eric [National Renewable Energy Lab. (NREL), Golden, CO (United States); Biddy, Mary [National Renewable Energy Lab. (NREL), Golden, CO (United States); Talmadge, Michael [National Renewable Energy Lab. (NREL), Golden, CO (United States); Hartley, Damon S. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Snowden-Swan, Lesley [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-09-01

    The Department of Energy’s (DOE) Bioenergy Technologies Office (BETO) aims at developing and deploying technologies to transform renewable biomass resources into commercially viable, high-performance biofuels, bioproducts and biopower through public and private partnerships (DOE, 2015). BETO also performs a supply chain sustainability analysis (SCSA). This report describes the SCSA of the production of renewable high octane gasoline (HOG) via indirect liquefaction (IDL) of lignocellulosic biomass. This SCSA was developed for the 2017 design case for feedstock logistics (INL, 2014) and for the 2022 target case for HOG production via IDL (Tan et al., 2015). The design includes advancements that are likely and targeted to be achieved by 2017 for the feedstock logistics and 2022 for the IDL conversion process. The 2017 design case for feedstock logistics demonstrated a delivered feedstock cost of $80 per dry U.S. short ton by the year 2017 (INL, 2014). The 2022 design case for the conversion process, as modeled in Tan et al. (2015), uses the feedstock 2017 design case blend of biomass feedstocks consisting of pulpwood, wood residue, switchgrass, and construction and demolition waste (C&D) with performance properties consistent with a sole woody feedstock type (e.g., pine or poplar). The HOG SCSA case considers the 2017 feedstock design case (the blend) as well as individual feedstock cases separately as alternative scenarios when the feedstock blend ratio varies as a result of a change in feedstock availability. These scenarios could be viewed as bounding SCSA results because of distinctive requirements for energy and chemical inputs for the production and logistics of different components of the blend feedstocks.

  15. Control system design specification of advanced spent fuel management process units

    Energy Technology Data Exchange (ETDEWEB)

    Ahn, S. H.; Kim, S. H.; Yoon, J. S

    2003-06-01

    In this study, the design specifications of instrumentation and control system for advanced spent fuel management process units are presented. The advanced spent fuel management process consists of several process units such as slitting device, dry pulverizing/mixing device, metallizer, etc. In this study, the control and operation characteristics of the advanced spent fuel management mockup process devices and the process devices developed in 2001 and 2002 are analysed. Also, a integral processing system of the unit process control signals is proposed, which the operation efficiency is improved. And a redundant PLC control system is constructed which the reliability is improved. A control scheme is proposed for the time delayed systems compensating the control performance degradation caused by time delay. The control system design specification is presented for the advanced spent fuel management process units. This design specifications can be effectively used for the detail design of the advanced spent fuel management process.

  16. SULFATE RADICAL-BASED ADVANCED OXIDATION PROCESSES- ACS MEETING

    Science.gov (United States)

    This paper will present an overview of sulfate radical-based advanced oxidation technologies for the destruction of environmentally toxic chemicals in wastewater, industrial water, groundwater and sources of water supply. The paper will include fundamental aspects of the generati...

  17. Measurement and modeling of advanced coal conversion processes

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.; Smoot, L.D.; Brewster, B.S. (Advanced Fuel Research, Inc., East Hartford, CT (United States) Brigham Young Univ., Provo, UT (United States))

    1991-01-01

    The overall objective of this program is the development of predictive capability for the design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. This program will merge significant advances made in measuring and quantitatively describing the mechanisms in coal conversion behavior. Comprehensive computer codes for mechanistic modeling of entrained-bed gasification. Additional capabilities in predicting pollutant formation will be implemented and the technology will be expanded to fixed-bed reactors.

  18. Experimental Advanced Airborne Research Lidar (EAARL) Data Processing Manual

    Science.gov (United States)

    Bonisteel, Jamie M.; Nayegandhi, Amar; Wright, C. Wayne; Brock, John C.; Nagle, David

    2009-01-01

    The Experimental Advanced Airborne Research Lidar (EAARL) is an example of a Light Detection and Ranging (Lidar) system that utilizes a blue-green wavelength (532 nanometers) to determine the distance to an object. The distance is determined by recording the travel time of a transmitted pulse at the speed of light (fig. 1). This system uses raster laser scanning with full-waveform (multi-peak) resolving capabilities to measure submerged topography and adjacent coastal land elevations simultaneously (Nayegandhi and others, 2009). This document reviews procedures for the post-processing of EAARL data using the custom-built Airborne Lidar Processing System (ALPS). ALPS software was developed in an open-source programming environment operated on a Linux platform. It has the ability to combine the laser return backscatter digitized at 1-nanosecond intervals with aircraft positioning information. This solution enables the exploration and processing of the EAARL data in an interactive or batch mode. ALPS also includes modules for the creation of bare earth, canopy-top, and submerged topography Digital Elevation Models (DEMs). The EAARL system uses an Earth-centered coordinate and reference system that removes the necessity to reference submerged topography data relative to water level or tide gages (Nayegandhi and others, 2006). The EAARL system can be mounted in an array of small twin-engine aircraft that operate at 300 meters above ground level (AGL) at a speed of 60 meters per second (117 knots). While other systems strive to maximize operational depth limits, EAARL has a narrow transmit beam and receiver field of view (1.5 to 2 milliradians), which improves the depth-measurement accuracy in shallow, clear water but limits the maximum depth to about 1.5 Secchi disk depth (~20 meters) in clear water. The laser transmitter [Continuum EPO-5000 yttrium aluminum garnet (YAG)] produces up to 5,000 short-duration (1.2 nanosecond), low-power (70 microjoules) pulses each second

  19. Advanced research and development for plasma processing of polymers with combinatorial plasma-process analyzer

    International Nuclear Information System (INIS)

    Setsuhara, Yuichi; Cho, Ken; Takenaka, Kosuke; Shiratani, Masaharu; Sekine, Makoto; Hori, Masaru

    2010-01-01

    A plasma-process analyzer has been developed on the basis of combinatorial method, in which process examinations with continuous variations of plasma-process conditions can be carried out on a substrate holder with an inclined distribution of process parameters. Combinatorial plasma-process analyses have been demonstrated for examinations of plasma-polymer interactions in terms of etching characteristics and surface morphologies in order to show feasibility and effectiveness of the methodology as advanced research and development for next-generation plasma nano processes. The etching properties and surface morphologies have been investigated for polyethylene terephthalate (PET) films exposed to argon-oxygen mixture plasmas. The etching depth data obtained from three independent batches of the experiments showed universal and almost linear dependence with increasing product of (ion saturation current) x (exposure time); i.e. ion dose. Surface roughness of the polymer slightly increased with increasing ion dose, while the mean spacing after plasma exposure was found to decrease monotonically with increasing ion dose but was saturated at the level of approximately 250 nm.

  20. Redesign of the Advanced Education processes in the United States Coast Guard

    OpenAIRE

    Johnson, Lamar V.; Sanders, Marc F.

    1999-01-01

    The processes used in the operation of the Coast Guard Advanced Education Program have evolved as most business processes that were developed prior to the introduction of information technology. These processes include the selection, management, assignment and tracking of advanced education students. These processes are still fully dependent on physical files and the mail system. The Coast Guard has an information technology infrastructure that supports better processes, however it is not bei...

  1. Feasibility and comparative studies of thermochemical liquefaction of Camellia oleifera cake in different supercritical organic solvents for producing bio-oil

    International Nuclear Information System (INIS)

    Chen, Hongmei; Zhai, Yunbo; Xu, Bibo; Xiang, Bobin; Zhu, Lu; Li, Ping; Liu, Xiaoting; Li, Caiting; Zeng, Guangming

    2015-01-01

    Highlights: • Thermochemical liquefaction of COC was a prominent process for producing bio-oil. • Type of solvent affected the yield and composition of bio-oil considerably. • Liquefaction of COC in SCEL at 300 °C was preferred for producing bio-oil. - Abstract: Thermochemical liquefaction of Camellia oleifera cake (COC) for producing bio-oil was conducted in supercritical methanol (SCML), ethanol (SCEL) and acetone (SCAL), respectively. GC–MS, elemental analysis and ICP-OES were used to characterize properties of bio-oil. Results showed that thermochemical liquefaction of COC was a prominent process for generating bio-oil. Increase of temperature was beneficial to the increase of bio-oil yield, and yield of bio-oil followed the sequence of SCAL > SCEL > SCML. In spite of the highest bio-oil yield, the lowest calorific value and highest contents of Zn, Pb, Cd, Ni, Fe, Mn, and Cr were found in bio-oil from SCAL. Though SCML has very similar bio-oil composition and calorific value with SCEL, higher bio-oil yield and lower contents of heavy metals could be obtained with SCEL, especially in bio-oil from SCEL at 300 °C. Moreover, the origin of ethanol could make the bio-oil product totally renewable. Therefore, liquefaction of COC in SCEL at 300 °C could have great potential in generating bio-oil

  2. Effects of Long-Duration Ground Motions on Liquefaction Hazards

    Science.gov (United States)

    Greenfield, Michael W.

    Soil liquefaction during past earthquakes has caused extensive damage to buildings, bridges, dam, pipelines and other elements of infrastructure. Geotechnical engineers use empirical observations from earthquake case histories in conjunction with soil mechanics to predict the behavior of liquefiable soils. However, current empirical databases are insufficient to evaluate the behavior of soils subject to long-duration earthquakes, such as a possible Mw = 9.0 Cascadia Subduction Zone earthquake. The objective of this research is to develop insight into the triggering and effects of liquefaction due to long-duration ground motions and to provide recommendations for analysis and design. Recorded ground motions from 21 case histories with surficial evidence of liquefaction showed marked differences in soil behavior before and after liquefaction was triggered. In some cases, strong shaking continued for several minutes after the soil liquefied, and a variety of behaviors were observed including dilation pulses, continued softening due to soil fabric degradation, and soil stiffening due to pore pressure dissipation and drainage. Supplemental field and laboratory investigations were performed at three sites that liquefied during the 2011 Mw = 9.0 Tohoku earthquake. The recorded ground motions and field investigation data were used in conjunction with laboratory observations, analytical models, and numerical models to evaluate the behavior of liquefiable soils subjected to long-duration ground motions. Observations from the case histories inspired a framework to predict ground deformations based on the differences in soil behavior before and after liquefaction has triggered. This framework decouples the intensity of shaking necessary to trigger liquefaction from the intensity of shaking that drives deformation by identifying the time when liquefaction triggers. The timing-based framework promises to dramatically reduce the uncertainty in deformation estimates compared to

  3. Sinking during earthquakes: Critical acceleration criteria control drained soil liquefaction

    Science.gov (United States)

    Clément, C.; Toussaint, R.; Stojanova, M.; Aharonov, E.

    2018-02-01

    This article focuses on liquefaction of saturated granular soils, triggered by earthquakes. Liquefaction is defined here as the transition from a rigid state, in which the granular soil layer supports structures placed on its surface, to a fluidlike state, in which structures placed initially on the surface sink to their isostatic depth within the granular layer. We suggest a simple theoretical model for soil liquefaction and show that buoyancy caused by the presence of water inside a granular medium has a dramatic influence on the stability of an intruder resting at the surface of the medium. We confirm this hypothesis by comparison with laboratory experiments and discrete-element numerical simulations. The external excitation representing ground motion during earthquakes is simulated via horizontal sinusoidal oscillations of controlled frequency and amplitude. In the experiments, we use particles only slightly denser than water, which as predicted theoretically increases the effect of liquefaction and allows clear depth-of-sinking measurements. In the simulations, a micromechanical model simulates grains using molecular dynamics with friction between neighbors. The effect of the fluid is captured by taking into account buoyancy effects on the grains when they are immersed. We show that the motion of an intruder inside a granular medium is mainly dependent on the peak acceleration of the ground motion and establish a phase diagram for the conditions under which liquefaction happens, depending on the soil bulk density, friction properties, presence of water, and peak acceleration of the imposed large-scale soil vibrations. We establish that in liquefaction conditions, most cases relax toward an equilibrium position following an exponential in time. We also show that the equilibrium position itself, for most liquefaction regimes, corresponds to the isostatic equilibrium of the intruder inside a medium of effective density. The characteristic time to relaxation is

  4. Advanced diagnostics in oxy-fuel combustion processes

    Energy Technology Data Exchange (ETDEWEB)

    Brix, J.; Clausen, Soennik; Degn Jensen, A. (Technical Univ. of Denmark. CHEC Research Centre, Kgs. Lyngby (Denmark)); Boeg Toftegaard, M. (DONG Energy Power, Hvidovre (Denmark))

    2012-07-01

    This report sums up the findings in PSO-project 010069, ''Advanced Diagnostics in Oxy-Fuel Combustion Processes''. Three areas of optic diagnostics are covered in this work: - FTIR measurements in a 30 kW swirl burner. - IR measurements in a 30 kW swirl burner. - IR measurements in a laboratory scale fixed bed reactor. The results obtained in the swirl burner have proved the FTIR method as a valuable technique for gas phase temperature measurements. When its efficacy is evaluated against traditional thermocouple measurements, two cases, with and without probe beam stop, must however be treated separately. When the FTIR probe is operated with the purpose of gas phase concentration measurements the probe needs to operate with a beam stop mounted in front of it. With this beam stop in place it was shown that the measured gas phase temperature was affected by cooling, induced by the cooled beam stop. Hence, for a more accurate determination of gas phase temperatures the probe needed to operate without the beam stop. When this was the case, the FTIR probe showed superior to traditional temperature measurements using a thermocouple as it could measure the fast temperature fluctuations. With the beam stop in place the efficacy of the FTIR probe for gas temperature determination was comparable to the use of a traditional thermocouple. The evaluation of the FTIR technique regarding estimation of gas phase concentrations of H{sub 2}O, CO{sub 2} and CO showed that the method is reliable though it cannot be stated as particularly accurate. The accuracy of the method is dependent on the similarity of the reference emission spectra of the gases with those obtained in the experiments, as the transmittance intensity is not a linear function of concentration. The length of the optical path also affects the steadiness of the measurements. The length of the optical path is difficult to adjust on the small scales that are the focus of this work. However

  5. Designing Advanced Ceramic Waste Forms for Electrochemical Processing Salt Waste

    International Nuclear Information System (INIS)

    Ebert, W. L.; Snyder, C. T.; Frank, Steven; Riley, Brian

    2016-01-01

    This report describes the scientific basis underlying the approach being followed to design and develop ''advanced'' glass-bonded sodalite ceramic waste form (ACWF) materials that can (1) accommodate higher salt waste loadings than the waste form developed in the 1990s for EBR-II waste salt and (2) provide greater flexibility for immobilizing extreme waste salt compositions. This is accomplished by using a binder glass having a much higher Na_2O content than glass compositions used previously to provide enough Na+ to react with all of the Cl- in the waste salt and generate the maximum amount of sodalite. The phase compositions and degradation behaviors of prototype ACWF products that were made using five new binder glass formulations and with 11-14 mass% representative LiCl/KCl-based salt waste were evaluated and compared with results of similar tests run with CWF products made using the original binder glass with 8 mass% of the same salt to demonstrate the approach and select a composition for further studies. About twice the amount of sodalite was generated in all ACWF materials and the microstructures and degradation behaviors confirmed our understanding of the reactions occurring during waste form production and the efficacy of the approach. However, the porosities of the resulting ACWF materials were higher than is desired. These results indicate the capacity of these ACWF waste forms to accommodate LiCl/KCl-based salt wastes becomes limited by porosity due to the low glass-to-sodalite volume ratio. Three of the new binder glass compositions were acceptable and there is no benefit to further increasing the Na content as initially planned. Instead, further studies are needed to develop and evaluate alternative production methods to decrease the porosity, such as by increasing the amount of binder glass in the formulation or by processing waste forms in a hot isostatic press. Increasing the amount of binder glass to eliminate porosity will decrease the waste

  6. Potential use of advanced process control for safety purposes during attack of a process plant

    International Nuclear Information System (INIS)

    Whiteley, James R.

    2006-01-01

    Many refineries and commodity chemical plants employ advanced process control (APC) systems to improve throughputs and yields. These APC systems utilize empirical process models for control purposes and enable operation closer to constraints than can be achieved with traditional PID regulatory feedback control. Substantial economic benefits are typically realized from the addition of APC systems. This paper considers leveraging the control capabilities of existing APC systems to minimize the potential impact of a terrorist attack on a process plant (e.g., petroleum refinery). Two potential uses of APC are described. The first is a conventional application of APC and involves automatically moving the process to a reduced operating rate when an attack first begins. The second is a non-conventional application and involves reconfiguring the APC system to optimize safety rather than economics. The underlying intent in both cases is to reduce the demands on the operator to allow focus on situation assessment and optimal response planning. An overview of APC is provided along with a brief description of the modifications required for the proposed new applications of the technology

  7. Advanced hybrid process with solvent extraction and pyro-chemical process of spent fuel reprocessing for LWR to FBR

    International Nuclear Information System (INIS)

    Fujita, Reiko; Mizuguchi, Koji; Fuse, Kouki; Saso, Michitaka; Utsunomiya, Kazuhiro; Arie, Kazuo

    2008-01-01

    Toshiba has been proposing a new fuel cycle concept of a transition from LWR to FBR. The new fuel cycle concept has better economical process of the LWR spent fuel reprocessing than the present Purex Process and the proliferation resistance for FBR cycle of plutonium with minor actinides after 2040. Toshiba has been developing a new Advanced Hybrid Process with Solvent Extraction and Pyrochemical process of spent fuel reprocessing for LWR to FBR. The Advanced Hybrid Process combines the solvent extraction process of the LWR spent fuel in nitric acid with the recovery of high pure uranium for LWR fuel and the pyro-chemical process in molten salts of impure plutonium recovery with minor actinides for metallic FBR fuel, which is the FBR spent fuel recycle system after FBR age based on the electrorefining process in molten salts since 1988. The new Advanced Hybrid Process enables the decrease of the high-level waste and the secondary waste from the spent fuel reprocessing plants. The R and D costs in the new Advanced Hybrid Process might be reduced because of the mutual Pyro-chemical process in molten salts. This paper describes the new fuel cycle concept of a transition from LWR to FBR and the feasibility of the new Advanced Hybrid Process by fundamental experiments. (author)

  8. Advanced Solid-State Joining Processes for 2219 Aluminum Alloys, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Thermal Stir Welding (TSW) advances the more conventional Friction Stir Welding (C-FSW) process by separating the primary process variables of metal stirring and...

  9. Hydrothermal liquefaction of microalgae to produce biofuels: state of the art and future prospects

    Science.gov (United States)

    Vlaskin, M. S.; Chernova, N. I.; Kiseleva, S. V.; Popel', O. S.; Zhuk, A. Z.

    2017-09-01

    The article presents a review of the state of the art and lines of research on hydrothermal liquefaction (HTL) of microalgae (MA). The main advantages of this technology for production of biofuel are that it does not require predrying of the feedstock and ensures a relatively high product yield—the ratio of the end product weight to the feedstock weight—owing to the fact that all the microalgal components, viz., lipids, proteins, and carbohydrates, are converted into biofuel. MA hydrothermal liquefaction is considered to be a promising technology for conversion of biomass and is a subject of a series of research studies and, judging by the available publications, the scope of research in this field is expanding currently. However, many significant problems remain unsolved. In particular, an active searched is being conducted for suitable strains that will ensure not only a high lipid yield—necessary to convert microalgae into biodiesel—but also higher biomass productivity and a higher biofuel yield; the chemical reactions that occur during the hydrothermal treatment are being studied; and the effect of significant process variables, such as temperature, heating rate, holdup time at the maximum temperature, biomass concentration in the water suspension, biochemical and elemental compositions of the microalgae, use of catalysts, etc., on the liquefaction processes is being studied. One of the urgent tasks is also the reduction of the nitrogen content in the resulting biofuel. Studies aimed at the development of a continuous process and rational heat-processing plants for thermal microalgal conversion are being conducted to increase the energy efficiency of the HTL process, in particular, to provide the heat recovery and separation of the end product.

  10. Small scale demand type neon liquefaction plant

    International Nuclear Information System (INIS)

    Dube, W.P.; Slifka, A.J.; Bitsy, R.M.; Sparks, L.L.; Johnson, K.B.

    1990-01-01

    Low-temperature measurement of the thermal conductivity of insulating materials is generally made using a boil-off calorimetry technique involving liquid hydrogen (LH2). Liquid neon (LNe) has nearly the same normal boiling point as LH2, but has a much larger heat of vaporization, allowing extended run times. The main drawback of using LNe has been its excessive cost; $170.00 versus $1.50/l for LH2 (1989 prices). A neon liquefaction plant has been designed and constructed to capture, purify, and refrigerate the neon boil-off from calorimetry experiments. Recycling the neon reduces operating costs to approximately $20/l. The system consists of a purification section, a heat exchanger, LNe and LH2 storage dewars, and a fully automated control system. After purification, neon is liquified in the heat exchanger by LH2 flowing countercurrently through stainless steel cooling coils. Hydrogen flow is automatically adjusted to keep the neon at its normal saturation temperature, 27 K. The liquid neon is then stored in a dewar placed directly below the heat exchanger

  11. Assessment of liquefaction potential during earthquakes by arias intensity

    Science.gov (United States)

    Kayen, R.E.; Mitchell, J.K.

    1997-01-01

    An Arias intensity approach to assess the liquefaction potential of soil deposits during earthquakes is proposed, using an energy-based measure of the severity of earthquake-shaking recorded on seismograms of the two horizontal components of ground motion. Values representing the severity of strong motion at depth in the soil column are associated with the liquefaction resistance of that layer, as measured by in situ penetration testing (SPT, CPT). This association results in a magnitude-independent boundary that envelopes initial liquefaction of soil in Arias intensity-normalized penetration resistance space. The Arias intensity approach is simple to apply and has proven to be highly reliable in assessing liquefaction potential. The advantages of using Arias intensity as a measure of earthquake-shaking severity in liquefaction assessment are: Arias intensity is derived from integration of the entire seismogram wave form, incorporating both the amplitude and duration elements of ground motion; all frequencies of recorded motion are considered; and Arias intensity is an appropriate measure to use when evaluating field penetration test methodologies that are inherently energy-based. Predictor equations describing the attenuation of Arias intensity as a function of earthquake magnitude and source distance are presented for rock, deep-stiff alluvium, and soft soil sites.

  12. Energy-based numerical models for assessment of soil liquefaction

    Directory of Open Access Journals (Sweden)

    Amir Hossein Alavi

    2012-07-01

    Full Text Available This study presents promising variants of genetic programming (GP, namely linear genetic programming (LGP and multi expression programming (MEP to evaluate the liquefaction resistance of sandy soils. Generalized LGP and MEP-based relationships were developed between the strain energy density required to trigger liquefaction (capacity energy and the factors affecting the liquefaction characteristics of sands. The correlations were established based on well established and widely dispersed experimental results obtained from the literature. To verify the applicability of the derived models, they were employed to estimate the capacity energy values of parts of the test results that were not included in the analysis. The external validation of the models was verified using statistical criteria recommended by researchers. Sensitivity and parametric analyses were performed for further verification of the correlations. The results indicate that the proposed correlations are effectively capable of capturing the liquefaction resistance of a number of sandy soils. The developed correlations provide a significantly better prediction performance than the models found in the literature. Furthermore, the best LGP and MEP models perform superior than the optimal traditional GP model. The verification phases confirm the efficiency of the derived correlations for their general application to the assessment of the strain energy at the onset of liquefaction.

  13. Advanced social features in a recommendation system for process modeling

    NARCIS (Netherlands)

    Koschmider, A.; Song, M.S.; Reijers, H.A.; Abramowicz, W.

    2009-01-01

    Social software is known to stimulate the exchange and sharing of information among peers. This paper describes how an existing system that supports process builders in completing a business process can be enhanced with various social features. In that way, it is easier for process modeler to become

  14. FNet : An Index for Advanced Business Process Querying

    NARCIS (Netherlands)

    Yan, Z.; Dijkman, R.M.; Grefen, P.W.P.J.; Barros, A.; Gal, A.; Kindler, E.

    2012-01-01

    Nowadays, more and more organizations describe their operations in terms of business processes. Consequently, it is common for organizations to have collections of hundreds or even thousands of business process models. This calls for techniques to quickly retrieve business process models that

  15. FNet : an index for advanced business process querying

    NARCIS (Netherlands)

    Yan, Z.; Dijkman, R.M.; Grefen, P.W.P.J.

    2012-01-01

    Nowadays, more and more organizations describe their operations in terms of business processes. Consequently, it is common for organizations to have collections of hundreds or even thousands of business process models. This calls for techniques to quickly retrieve business process models that

  16. Seismic behavior of breakwaters on complex ground by numerical tests: Liquefaction and post liquefaction ground settlements

    Science.gov (United States)

    Gu, Linlin; Zhang, Feng; Bao, Xiaohua; Shi, Zhenming; Ye, Guanlin; Ling, Xianzhang

    2018-04-01

    A large number of breakwaters have been constructed along coasts to protect humans and infrastructures from tsunamis. There is a risk that foundation soils of these structures may liquefy, or partially liquefy during the earthquake preceding a tsunami, which would greatly reduce the structures' capacity to resist the tsunami. It is necessary to consider not only the soil's liquefaction behavior due to earthquake motions but also its post-liquefaction behavior because this behavior will affect the breakwater's capacity to resist an incoming tsunami. In this study, numerical tests based on a sophisticated constitutive model and a soil-water coupled finite element method are used to predict the mechanical behavior of breakwaters and the surrounding soils. Two real breakwaters subjected to two different seismic excitations are examined through numerical simulation. The simulation results show that, earthquakes affect not only the immediate behavior of breakwaters and the surrounding soils but also their long-term settlements due to post-earthquake consolidation. A soil profile with thick clayey layers beneath liquefied soil is more vulnerable to tsunami than a soil profile with only sandy layers. Therefore, quantitatively evaluating the seismic behavior of breakwaters and surrounding soils is important for the design of breakwater structures to resist tsunamis.

  17. Optimization for microwave-assisted direct liquefaction of bamboo residue in glycerol/methanol mixtures

    Science.gov (United States)

    Jiulong Xie; Jinqiu Qi; Chungyun Hse; Todd F. Shupe

    2015-01-01

    Bamboo residues were liquefied in a mixture of glycerol and methanol in the presence of sulfuric acid using microwave energy. We investigated the effects of liquefaction conditions, including glycerol/methanol ratio, liquefaction temperature, and reaction time on the conversion yield. The optimal liquefaction conditions were under the temperature of 120

  18. Liquefaction behaviors of bamboo residues in a glycerol-based solvent using microwave energy

    Science.gov (United States)

    Jiulong Xie; Chung-Yun Hse; Todd F. Shupe; Jinqiu Qi; Hui Pan

    2014-01-01

    Liquefaction of bamboo was performed in glycerol–methanol as co-solvent using microwave energy and was evaluated by characterizing the liquefied residues. High efficiency conversion of bamboo was achieved under mild reaction conditions. Liquefaction temperature and time interacted to affect the liquefaction reaction. Fourier transform infrared analyzes of the residues...

  19. Review and Assessment of Commercial Vendors/Options for Feeding and Pumping Biomass Slurries for Hydrothermal Liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Berglin, Eric J.; Enderlin, Carl W.; Schmidt, Andrew J.

    2012-11-01

    The National Advanced Biofuels Consortium is working to develop improved methods for producing high-value hydrocarbon fuels. The development of one such method, the hydrothermal liquefaction (HTL) process, is being led by the Pacific Northwest National Laboratory (PNNL). The HTL process uses a wet biomass slurry at elevated temperatures (i.e., 300 to 360°C [570 to 680°F]) and pressures above the vapor pressure of water (i.e., 15 to 20 MPa [2200 to 3000 psi] at these temperatures) to facilitate a condensed-phase reaction medium. The process has been successfully tested at bench-scale and development and testing at a larger scale is required to prove the viability of the process at production levels. Near-term development plans include a pilot-scale system on the order of 0.5 to 40 gpm, followed by a larger production-scale system on the order of 2000 dry metric tons per day (DMTPD). A significant challenge to the scale-up of the HTL process is feeding a highly viscous fibrous biomass wood/corn stover feedstock into a pump system that provides the required 3000 psi of pressure for downstream processing. In October 2011, PNNL began investigating commercial feed and pumping options that would meet these HTL process requirements. Initial efforts focused on generating a HTL feed and pump specification and then providing the specification to prospective vendors to determine the suitability of their pumps for the pilot-scale and production-scale plants. Six vendors were identified that could provide viable equipment to meet HTL feed and/or pump needs. Those six vendors provided options consisting three types of positive displacement pumps (i.e., diaphragm, piston, and lobe pumps). Vendors provided capabilities and equipment related to HTL application. This information was collected, assessed, and summarized and is provided as appendices to this report.

  20. 3D data processing with advanced computer graphics tools

    Science.gov (United States)

    Zhang, Song; Ekstrand, Laura; Grieve, Taylor; Eisenmann, David J.; Chumbley, L. Scott

    2012-09-01

    Often, the 3-D raw data coming from an optical profilometer contains spiky noises and irregular grid, which make it difficult to analyze and difficult to store because of the enormously large size. This paper is to address these two issues for an optical profilometer by substantially reducing the spiky noise of the 3-D raw data from an optical profilometer, and by rapidly re-sampling the raw data into regular grids at any pixel size and any orientation with advanced computer graphics tools. Experimental results will be presented to demonstrate the effectiveness of the proposed approach.

  1. Production process for advanced space satellite system cables/interconnects.

    Energy Technology Data Exchange (ETDEWEB)

    Mendoza, Luis A.

    2007-12-01

    This production process was generated for the satellite system program cables/interconnects group, which in essences had no well defined production process. The driver for the development of a formalized process was based on the set backs, problem areas, challenges, and need improvements faced from within the program at Sandia National Laboratories. In addition, the formal production process was developed from the Master's program of Engineering Management for New Mexico Institute of Mining and Technology in Socorro New Mexico and submitted as a thesis to meet the institute's graduating requirements.

  2. Research on chemical vapor deposition processes for advanced ceramic coatings

    Science.gov (United States)

    Rosner, Daniel E.

    1993-01-01

    Our interdisciplinary background and fundamentally-oriented studies of the laws governing multi-component chemical vapor deposition (VD), particle deposition (PD), and their interactions, put the Yale University HTCRE Laboratory in a unique position to significantly advance the 'state-of-the-art' of chemical vapor deposition (CVD) R&D. With NASA-Lewis RC financial support, we initiated a program in March of 1988 that has led to the advances described in this report (Section 2) in predicting chemical vapor transport in high temperature systems relevant to the fabrication of refractory ceramic coatings for turbine engine components. This Final Report covers our principal results and activities for the total NASA grant of $190,000. over the 4.67 year period: 1 March 1988-1 November 1992. Since our methods and the technical details are contained in the publications listed (9 Abstracts are given as Appendices) our emphasis here is on broad conclusions/implications and administrative data, including personnel, talks, interactions with industry, and some known applications of our work.

  3. Report on 1979 result of R and D under Sunshine Project. Development of coal liquefaction technology (development of solvent treatment and liquefaction plant); 1979 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho. Yozai shori ekika plant no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1980-03-01

    A report was made on the result for fiscal 1979 of the development of a coal solvent treatment and liquefaction plant. With the purpose of establishing a technology of making equipment for a coal liquefaction plant by a solvent treatment method, R and D were conducted on a solid liquid separation method and on the construction and operation of an experimental equipment having a scale of the maximum 1 t/day coal processing, providing technical data for the construction of an efficient coal liquefaction equipment. In studying the operation of a centrifugal separator, it was run using heating solvent, dummy slurry and coal extraction slurry, with no abnormality found in each equipment and with knowledge obtained of the separation state of the solid. The machine is capable of obtaining SRC of 0.2-0.3% low ash contents. Water operation was performed for the extraction processing device (agitation tank, heating furnace, compression pump, circulation pump, etc.) of the 1 t/day experimental plant and, as a result, a relation was confirmed between a water flow rate and pressure loss of the piping part. The detailed design, manufacture and installation were completed for a part (pulverizer, solvent tank, feeding pump, etc.) of the equipment for the coal pre-processing slurry making process and the extraction process, with a trial run implemented for adjustment and confirmation of the operation. The cold/hot continuous trial run by a solvent smoothly proceeded, proving the performance to be the same as the specifications. (NEDO)

  4. Liquefaction under drained condition, from the lab to reality ?

    Science.gov (United States)

    Clément, Cécile; Aharonov, Einat; Stojanova, Menka; Toussaint, Renaud

    2015-04-01

    Liquefaction constitutes a significant natural hazard in relation to earthquakes and landslides. This effect can cause buildings to tilt or sink into the soil, mud-volcanoes, floatation of buried objects, long-runout landslides, etc. In this work we present a new understanding regarding the mechanism by which buildings sink and tilt during liquefaction caused by earthquakes. Conventional understanding of liquefaction explains most observed cases as occurring in an undrained, under-compacted, layer of sandy soil saturated with water [1]: According to that understanding, the under compacted sandy layer has the tendency to compact when a load is applied. In our case the load comes from ground shaking during an earthquake. When the soil compacts, the fluid pore pressure rises. Because in undrained conditions the fluid cannot flow out, the pore pressure builds up. The weight of buildings is in this case transferred from the grains of the soil to the pore water. The soil loses its rigidity and it flows like a liquid. From this model scientists made theoretical and empirical laws for geotechnical use and buildings construction. Despite the success of this conventional model in many cases, liquefied soils were also observed under drained conditions, and in previously compacted soils, which doesn't agree with the assumption of the model quoted above. One of the famous liquefaction events is the Kobe port destruction during the 1995 earthquake. A simple calculation of the Deborah number following Goren et al ([2][3]) shows that the undrained constraint was not met below the Kobe port during the 1995 earthquake. We propose another model, of liquefaction in drained granular media. According to our model the mere presence of water in granular media is enough to cause liquefaction during an earthquake, provided that the water reaches close to the surface. Our computations are based on the buoyancy force, and we take into account the static fluid pressure only. For small

  5. Ground motions estimates for a cascadia earthquake from liquefaction evidence

    Science.gov (United States)

    Dickenson, S.E.; Obermeier, S.F.

    1998-01-01

    Paleoseismic studies conducted in the coastal regions of the Pacific Northwest in the past decade have revealed evidence of crustal downdropping and subsequent tsunami inundation, attributable to a large earthquake along the Cascadia subduction zone which occurred approximately 300 years ago, and most likely in 1700 AD. In order to characterize the severity of ground motions from this earthquake, we report on results of a field search for seismically induced liquefaction features. The search was made chiefly along the coastal portions of several river valleys in Washington, rivers along the central Oregon coast, as well as on islands in the Columbia River of Oregon and Washington. In this paper we focus only on the results of the Columbia River investigation. Numerous liquefaction features were found in some regions, but not in others. The regional distribution of liquefaction features is evaluated as a function of geologic and geotechnical factors at each site in order to estimate the intensity of ground shaking.

  6. Dual-Process Theories and Cognitive Development: Advances and Challenges

    Science.gov (United States)

    Barrouillet, Pierre

    2011-01-01

    Dual-process theories have gained increasing importance in psychology. The contrast that they describe between an old intuitive and a new deliberative mind seems to make these theories especially suited to account for development. Accordingly, this special issue aims at presenting the latest applications of dual-process theories to cognitive…

  7. Dissolution process for advanced-PWR-type fuels

    International Nuclear Information System (INIS)

    Black, D.E.; Decker, L.A.; Pearson, L.G.

    1979-01-01

    The new Fluorinel Dissolution Process and Fuel Storage (FAST) Facility at ICPP will provide underwater storage of spent PWR fuel and a new head-end process for fuel dissolution. The dissolution will be two-stage, using HF and HNO 3 , with an intermittent H 2 SO 4 dissolution for removing stainless steel components. Equipment operation is described

  8. Measurement and modeling of advanced coal conversion processes

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. (Advanced Fuel Research, Inc., East Hartford, CT (United States)); Smoot, L.D.; Brewster, B.S. (Brigham Young Univ., Provo, UT (United States))

    1991-01-01

    The objective of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines.

  9. Measurement and modeling of advanced coal conversion processes

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. (Advanced Fuel Research, Inc., East Hartford, CT (United States)); Smoot, L.D.; Brewster, B.S. (Brigham Young Univ., Provo, UT (United States))

    1991-09-25

    The objectives of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. (VC)

  10. Dual-Process Theories of Higher Cognition: Advancing the Debate.

    Science.gov (United States)

    Evans, Jonathan St B T; Stanovich, Keith E

    2013-05-01

    Dual-process and dual-system theories in both cognitive and social psychology have been subjected to a number of recently published criticisms. However, they have been attacked as a category, incorrectly assuming there is a generic version that applies to all. We identify and respond to 5 main lines of argument made by such critics. We agree that some of these arguments have force against some of the theories in the literature but believe them to be overstated. We argue that the dual-processing distinction is supported by much recent evidence in cognitive science. Our preferred theoretical approach is one in which rapid autonomous processes (Type 1) are assumed to yield default responses unless intervened on by distinctive higher order reasoning processes (Type 2). What defines the difference is that Type 2 processing supports hypothetical thinking and load heavily on working memory. © The Author(s) 2013.

  11. Advanced laser processing for industrial solar cell manufacturing (ALPINISM)

    Energy Technology Data Exchange (ETDEWEB)

    Mason, N.B.; Fieret, J. [Exitech Ltd. (United Kingdom)

    2006-05-04

    The study was aimed at improving methods for the manufacture of high efficiency solar cells and thereby increase production rates. The project focused on the laser grooved buried contact solar cell (LGBC) which is produced by high-speed laser machining. The specific objectives were (i) to optimise the laser technology for high speed processing; (ii) to optimise the solar cell process conditions for high speed processing; (iii) to produce a prototype tool and demonstrate high throughput; and (iv) to demonstrate increased cell efficiency using laser processing of rear contact. Essentially, all the objectives were met and Exitech have already sold six production tools and one research tool developed in this study. In addition, it was found that laser processing at the rear cell surface offers the prospect of LGBC solar cells with an efficiency of 20 per cent. BP Solar Limited carried out this work under contract to the DTI.

  12. Cosmetic wastewater treatment by coagulation and advanced oxidation processes.

    Science.gov (United States)

    Naumczyk, Jeremi; Bogacki, Jan; Marcinowski, Piotr; Kowalik, Paweł

    2014-01-01

    In this study, the treatment process of three cosmetic wastewater types has been investigated. Coagulation allowed to achieve chemical oxygen demand (COD) removal of 74.6%, 37.7% and 74.0% for samples A (Al2(SO4)3), B (Brentafloc F3) and C (PAX 16), respectively. The Fenton process proved to be effective as well - COD removal was equal to 75.1%, 44.7% and 68.1%, respectively. Coagulation with FeCl3 and the subsequent photo-Fenton process resulted in the best values of final COD removal equal to 92.4%, 62.8% and 90.2%. In case of the Fenton process, after coagulation these values were equal to 74.9%, 50.1% and 84.8%, while in case of the H2O2/UV process, the obtained COD removal was 83.8%, 36.2% and 80.9%. High value of COD removal in the Fenton process carried out for A and C wastewater samples was caused by a significant contribution of the final neutralization/coagulation. Very small effect of the oxidation reaction in the Fenton process in case of sample A resulting from the presence of antioxidants, 'OH radical scavengers' in the wastewater.

  13. Advanced treatment and reuse system developed for oilfield process water

    Energy Technology Data Exchange (ETDEWEB)

    Conroy, Kevin

    2011-01-15

    An innovative plant to treat oilfield produced wastewater is being constructed in Trinidad and Tobago following recent regulations and industrial water supply challenges. The 4,100m3/day treatment system, developed by Golder Associates, will produce water for industrial reuse and effluent that meets new regulations. The treatment stages include: oil-water separation by gravity, equalization with a two-day capacity basin, dissolved air flotation, cooling, biotreatment/settling with immobilized cell bioreactors (ICB) technology, prefiltration/reverse osmosis and effluent storage/transfer. This advanced system will provide several important benefits including the elimination of inland discharge of minimally-treated water and the reduction of environmental and public health concerns. In addition, it will provide a new source of industrial water, resulting in a decrease in demand for fresh water. The success of this plant could lead to additional facilities in other oil field locations, expanding economic and environmental benefits of water reuse.

  14. Advanced Diagnostics in Oxy-Fuel Combustion Processes

    DEFF Research Database (Denmark)

    Brix, Jacob; Toftegaard, Maja Bøg; Clausen, Sønnik

    This report sums up the findings in PSO-project 010069, “Advanced Diagnostics in Oxy- Fuel Combustion Processes”. Three areas of optic diagnostics are covered in this work: - FTIR measurements in a 30 kW swirl burner. - IR measurements in a 30 kW swirl burner. - IR measurements in a laboratory...... technique was an invaluable tool in the discussion of data obtained by gas analysis, and it allowed for estimation of combustion times in O2/CO2 where the high CO2 concentration prevents the use of the carbon mass balance for that purpose. During the project the data have been presented at a conference......, formed the basis of a publication and it is part of two PhD dissertations. The name of the conference the journal and the dissertations are listed below. - Joint Meeting of the Scandinavian-Nordic and French Sections of the Combustion Institute, Combustion of Char Particles under Oxy-Fuel Conditions...

  15. Liquefaction of solid carbonaceous material with catalyst recycle

    Science.gov (United States)

    Gupta, Avinash; Greene, Marvin I.

    1992-01-01

    In the two stage liquefaction of a carbonaceous solid such as coal wherein coal is liquefied in a first stage in the presence of a liquefaction solvent and the first stage effluent is hydrogenated in the presence of a supported hydrogenation catalyst in a second stage, catalyst which has been previously employed in the second stage and comminuted to a particle size distribution equivalent to 100% passing through U.S. 100 Mesh, is passed to the first stage to improve the overall operation.

  16. New advances in processing ore and minerals underground

    International Nuclear Information System (INIS)

    Lloyd, P.J.D.

    1979-01-01

    An outline of the basis for the design of a process for the efficient concentration of gold, uranium and pyrite is carried out underground. Practical steps of comminution, concentration and classification are described and probable further development is considered

  17. Advanced business process management in networked E-business scenarios

    NARCIS (Netherlands)

    Grefen, P.W.P.J.; Türetken, O.

    2017-01-01

    In the modern economy, we see a shift towards networked business scenarios. In many contemporary situations, the operation of multiple organizations is tightly coupled in collaborative business networks. To allow this tightly coupled collaboration, business process management (BPM) in these

  18. Process Heat Exchanger Options for the Advanced High Temperature Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Piyush Sabharwall; Eung Soo Kim; Michael McKellar; Nolan Anderson

    2011-06-01

    The work reported herein is a significant intermediate step in reaching the final goal of commercial-scale deployment and usage of molten salt as the heat transport medium for process heat applications. The primary purpose of this study is to aid in the development and selection of the required heat exchanger for power production and process heat application, which would support large-scale deployment.

  19. Advanced optical signal processing of broadband parallel data signals

    DEFF Research Database (Denmark)

    Oxenløwe, Leif Katsuo; Hu, Hao; Kjøller, Niels-Kristian

    2016-01-01

    Optical signal processing may aid in reducing the number of active components in communication systems with many parallel channels, by e.g. using telescopic time lens arrangements to perform format conversion and allow for WDM regeneration.......Optical signal processing may aid in reducing the number of active components in communication systems with many parallel channels, by e.g. using telescopic time lens arrangements to perform format conversion and allow for WDM regeneration....

  20. Cooperative research in coal liquefaction. Final report, May 1, 1990-- April 30, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, G.P. [ed.

    1992-02-15

    The Consortium for Fossil Fuel Liquefaction Science (CFFLS) is currently engaged in a three year contract with the US Department of Energy investigating a range of research topics dealing with direct coal liquefaction. This report summarizes the results of this program in its second year, from May 1, 1990 to April 30, 1991. Accomplishments for this period are presented for the following tasks: Iron-based catalysts for coal liquefaction, exploratory research on coal conversion, novel coal liquefaction concepts, and novel catalysts for coal liquefaction.