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Sample records for advanced fischer-tropsch technology

  1. Simulation models and designs for advanced Fischer-Tropsch technology

    Energy Technology Data Exchange (ETDEWEB)

    Choi, G.N.; Kramer, S.J.; Tam, S.S. [Bechtel Corp., San Francisco, CA (United States)

    1995-12-31

    Process designs and economics were developed for three grass-roots indirect Fischer-Tropsch coal liquefaction facilities. A baseline and an alternate upgrading design were developed for a mine-mouth plant located in southern Illinois using Illinois No. 6 coal, and one for a mine-mouth plane located in Wyoming using Power River Basin coal. The alternate design used close-coupled ZSM-5 reactors to upgrade the vapor stream leaving the Fischer-Tropsch reactor. ASPEN process simulation models were developed for all three designs. These results have been reported previously. In this study, the ASPEN process simulation model was enhanced to improve the vapor/liquid equilibrium calculations for the products leaving the slurry bed Fischer-Tropsch reactors. This significantly improved the predictions for the alternate ZSM-5 upgrading design. Another model was developed for the Wyoming coal case using ZSM-5 upgrading of the Fischer-Tropsch reactor vapors. To date, this is the best indirect coal liquefaction case. Sensitivity studies showed that additional cost reductions are possible.

  2. Technology development for iron Fischer-Tropsch catalysts

    Energy Technology Data Exchange (ETDEWEB)

    O`Brien, R.J.; Raje, A.; Keogh, R.A. [and others

    1995-12-31

    The objective of this research project is to develop the technology for the production of physically robust iron-based Fischer-Tropsch catalysts that have suitable activity, selectivity and stability to be used in the slurry phase synthesis reactor development. The catalysts that are developed shall be suitable for testing in the Advanced Fuels Development Facility at LaPorte, Texas, to produce either low-or high-alpha product distributions. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the {open_quotes}standard-catalyst{close_quotes} developed by German workers for slurry phase synthesis. In parallel, work will be conducted to design a high-alpha iron catalyst this is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studied at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity and aging characteristics.

  3. TECHNOLOGY DEVELOPMENT FOR IRON FISCHER-TROPSCH CATALYSTS

    Energy Technology Data Exchange (ETDEWEB)

    Davis, B.H.

    1998-07-22

    The goal of the proposed work described in this Final Report was the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The work described here has optimized the catalyst composition and pretreatment operation for a low-alpha catalyst. In parallel, work has been conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies have been conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors have been studied at the laboratory scale. Catalyst performance has been determined for catalysts synthesized in this program for activity, selectivity and aging characteristics.

  4. TECHNOLOGY DEVELOPMENT FOR IRON AND COBALT FISCHER-TROPSCH CATALYSTS

    International Nuclear Information System (INIS)

    The impact of activation procedure on the phase composition of precipitated iron Fischer-Tropsch (FT) catalysts has been studied. Catalyst samples taken during activation and FT synthesis have been characterized by Moessbauer spectroscopy. Formation of iron carbide is necessary for high FT activity. Hydrogen activation of precipitated iron catalysts results in reduction to predominantly metallic iron and Fe(sub 3)O(sub 4). Metallic iron is not stable under FT 3 4 conditions and is rapidly converted to(epsilon)(prime)-Fe(sub 2.2)C. Activation with carbon monoxide or syngas 2.2 with low hydrogen partial pressure reduces catalysts to(chi)-Fe(sub 5)C(sub 2) and a small amount of 5 2 superparamagnetic carbide. Exposure to FT conditions partially oxidizes iron carbide to Fe(sub 3)O(sub 4); however, catalysts promoted with potassium or potassium and copper maintain a constant carbide content and activity after the initial oxidation. An unpromoted iron catalyst which was activated with carbon monoxide to produce 94%(chi)-Fe(sub 5)C(sub 2), deactivated rapidly as the carbide was oxidized to Fe(sub 3)O(sub 4). No difference in activity, stability or deactivation rate was found for(chi)-Fe(sub 5)C(sub 2) and(epsilon)(prime)-Fe(sub 2.2)C

  5. Advances in Fischer-Tropsch wax hydrocracking process%F-T合成蜡油加氢裂解反应过程研究进展

    Institute of Scientific and Technical Information of China (English)

    杨超; 蒋坚; 鲁丹; 曹发海

    2013-01-01

    Fischer-Tropsch synthesis is an important process to convert coal,natural gas and biomass into liquid fuel,and is a promising process for resolving the shortage of petroleum. Mild hydrocracking is an effective route to upgrade the heavy waxy hydrocarbons derived from Fischer-Tropsch synthesis reaction into high value fuels,such as clean,high-quality diesel and jet fuel. In this paper,the recent advances in hydrocracking Fischer-Tropsch wax are reviewed. The mechanism of hydrocracking Fischer-Tropsch wax is introduced,the modeling of hydrocracking Fischer-Tropsch wax through lump and single-event kinetics is discussed,and the catalytic system as well as influence factors of the reaction are analyzed. Reactive distillation process can improve the selectivity of hydrocracking Fischer-Tropsch wax at a high conversion rate toward diesel. Apart from research and development of more effective catalysts,the study and application of Fischer-Tropsch wax hydrocracking reactive distillation process will have significant prospect.%通过F-T合成生产液体燃料是转化利用煤、天然气和生物质并解决石油短缺问题的一种有效途径,采用轻度加氢裂解F-T合成过程中产生的高沸点蜡油可以生产清洁优质的柴油和喷气燃料。本文对近年F-T合成蜡油加氢裂解的研究进展进行了综述,简要介绍了F-T合成蜡油加氢裂解的反应机理,讨论了集总动力学和单事件动力学在F-T合成蜡油加氢裂解中的应用情况,对F-T合成蜡加氢裂解催化剂体系以及反应影响因素进行了分析。反应精馏工艺可以提高F-T合成蜡加氢裂解高转化率时柴油的选择性,除了开发更高效的催化剂以外,F-T合成蜡油加氢裂解反应精馏的研究与应用将具有重大前景。

  6. Novel Attrition-Resistant Fischer Tropsch Catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Weast, Logan, E.; Staats, William, R.

    2009-05-01

    There is a strong national interest in the Fischer-Tropsch synthesis process because it offers the possibility of making liquid hydrocarbon fuels from reformed natural gas or coal and biomass gasification products. This project explored a new approach that had been developed to produce active, attrition-resistant Fischer-Tropsch catalysts that are based on glass-ceramic materials and technology. This novel approach represented a promising solution to the problem of reducing or eliminating catalyst attrition and maximizing catalytic activity, thus reducing costs. The technical objective of the Phase I work was to demonstrate that glass-ceramic based catalytic materials for Fischer-Tropsch synthesis have resistance to catalytic deactivation and reduction of particle size superior to traditional supported Fischer-Tropsch catalyst materials. Additionally, these novel glass-ceramic-based materials were expected to exhibit catalytic activity similar to the traditional materials. If successfully developed, the attrition-resistant Fischer-Tropsch catalyst materials would be expected to result in significant technical, economic, and social benefits for both producers and public consumers of Fischer-Tropsch products such as liquid fuels from coal or biomass gasification. This program demonstrated the anticipated high attrition resistance of the glass-ceramic materials. However, the observed catalytic activity of the materials was not sufficient to justify further development at this time. Additional testing documented that a lack of pore volume in the glass-ceramic materials limited the amount of surface area available for catalysis and consequently limited catalytic activity. However, previous work on glass-ceramic catalysts to promote other reactions demonstrated that commercial levels of activity can be achieved, at least for those reactions. Therefore, we recommend that glass-ceramic materials be considered again as potential Fischer-Tropsch catalysts if it can be

  7. Synthetic gasoline and diesel oil produced by Fischer-Tropsch Technology. A possibility for the future? IEA/AMF annex XXXI

    Energy Technology Data Exchange (ETDEWEB)

    Rehnlund, B., (Atrax Energy AB, Goeteborg (SE)); Blinge, M., (The Swedish Transport Research Institute, TFK (SE)); Schramm, J.; Larsen, Ulrik, (Technical Univ. of Denmark, DTU, Kgs. Lyngby (DK))

    2007-03-15

    This report is the result of an annex (annex XXXI, Fischer-Tropsch Fuels) initiated by the International Energy Agency's Implementing Agreement on Advanced Motor Fuels. The annex has been managed by Atrax Energi AB, Bjorn Rehnlund, acting as the operating agent of the annex. The work in the annex has been carried out in co-operation with the Swedish Transportation Research Institute - TFK, Magnus Blinge and the Technical University of Denmark - DTU, Jesper Schramm and Ulrik Larsen. In this report the possibilities to produce synthetic gasoline and synthetic diesel oil from biomass, and also from natural gas, by Fischer-Tropsch (FT) Technology are analysed and discussed. After an introduction of the technology as such, environmental aspects and the life cycle perspective of synthetic gasoline and diesel oil are discussed, and some possible national/regional scenarios are analysed and presented. Vehicle emission tests with synthetic gasoline carried out at DTU are described and discussed in this report as well. Based on the result of the analysis and the vehicle emission tests presented in the report, a first SWOT analysis of Fischer-Tropsch technology is then presented, and finally some main conclusions are drawn. During the execution of the annex Sasol in South Africa, Nykomb Synergetics in Sweden, Chemrec in Sweden, the Technical University of Denmark, VTT in Finland, the Varnamo gasification research project in Sweden, and the Black liquor gasification project in Pitea, Sweden have been visited. Some of the most important conclusions are that: 1) FT-Fuels such as FT-Diesel (FTD) and FT-Gasoline (FTG) produced through CoalTo-Liquid, (CTL), Gas-To-Liquid (GTL) and Biomass-To-Liquid (BTL) technologies can contribute to reducing the dependency on crude oil. 2) FTD and FTG are attractive for use in neat form and also as components in blends with low quality diesel and gasoline, to upgrade fuels to meet the ever more stringent regulations. 3) Production and use of

  8. Fischer-Tropsch Catalyst for Aviation Fuel Production

    Science.gov (United States)

    DeLaRee, Ana B.; Best, Lauren M.; Bradford, Robyn L.; Gonzalez-Arroyo, Richard; Hepp, Aloysius F.

    2012-01-01

    As the oil supply declines, there is a greater need for cleaner alternative fuels. There will undoubtedly be a shift from crude oil to nonpetroleum sources as a feedstock for aviation (and other transportation) fuels. The Fischer-Tropsch process uses a gas mixture of carbon monoxide and hydrogen which is converted into various liquid hydrocarbons; this versatile gas-to-liquid technology produces a complex product stream of paraffins, olefins, and oxygenated compounds such as alcohols and aldehydes. The Fischer-Tropsch process can produce a cleaner diesel oil fraction with a high cetane number (typically above 70) without any sulfur and aromatic compounds. It is most commonly catalyzed by cobalt supported on alumina, silica, or titania or unsupported alloyed iron powders. Cobalt is typically used more often than iron, in that cobalt is a longer-active catalyst, has lower water-gas shift activity, and lower yield of modified products. Promoters are valuable in improving Fischer-Tropsch catalyst as they can increase cobalt oxide dispersion, enhance the reduction of cobalt oxide to the active metal phase, stabilize a high metal surface area, and improve mechanical properties. Our goal is to build up the specificity of the Fischer-Tropsch catalyst while adding less-costly transition metals as promoters; the more common promoters used in Fischer-Tropsch synthesis are rhenium, platinum, and ruthenium. In this report we will describe our preliminary efforts to design and produce catalyst materials to achieve our goal of preferentially producing C8 to C18 paraffin compounds in the NASA Glenn Research Center Gas-To-Liquid processing plant. Efforts at NASA Glenn Research Center for producing green fuels using non-petroleum feedstocks support both the Sub-sonic Fixed Wing program of Fundamental Aeronautics and the In Situ Resource Utilization program of the Exploration Technology Development and Demonstration program.

  9. Moderated ruthenium fischer-tropsch synthesis catalyst

    Science.gov (United States)

    Abrevaya, Hayim

    1991-01-01

    The subject Fischer-Tropsch catalyst comprises moderated ruthenium on an inorganic oxide support. The preferred moderator is silicon. Preferably the moderator is effectively positioned in relationship to ruthenium particles through simultaneous placement on the support using reverse micelle impregnation.

  10. Novel Fischer-Tropsch catalysts. [DOE patent

    Science.gov (United States)

    Vollhardt, K.P.C.; Perkins, P.

    Novel compounds are described which are used as improved Fischer-Tropsch catalysts particularly for the conversion of CO + H/sub 2/ to gaseous and liquid hydrocarbons at milder conditions than with prior catalysts.

  11. Systematic Staging in Chemical Reactor Design : Fischer-Tropsch

    OpenAIRE

    Foss, Martin Skjærvø

    2013-01-01

    Today, crude oil is the main resource for production of liquid fuels. As the demandincreases, utilization of alternative resources becomes more and more urgent. Thus,the development of new and continued research on established process technologies isimportant.The scope of this Master?s thesis has been the catalytic hydrogenation of CO for production of linear, long chained hydrocarbons, known as the Fischer-Tropsch process. The core of a chemical plant is the reactor, thus the ultimate goal i...

  12. Model catalysts for Fischer-Tropsch synthesis

    OpenAIRE

    Nieto-Sandoval Rodriguez, Julia

    2014-01-01

    Today, Fischer-Tropsch synthesis is the key process in the production of liquid fuels from synthesis gas (a mixture of CO + H2). This mixture can be obtained from fossil fuels (oil, natural gas or coal) and from renewable sources such as biomass. Catalysis has an important role in the reaction since the catalysts can vary the activity and selectivity towards a wide range of products (i.e. methane, olefins, paraffins and alcohols, among others). The scope of this Master s thesis has been t...

  13. A novel water perm-selective membrane dual-type reactor concept for Fischer-Tropsch synthesis of GTL (gas to liquid) technology

    International Nuclear Information System (INIS)

    The present study proposes a novel configuration of Fischer-Tropsch synthesis (FTS) reactors in which a fixed-bed water perm-selective membrane reactor is followed by a fluidized-bed hydrogen perm-selective membrane reactor. This novel concept which has been named fixed-bed membrane reactor followed by fluidized-bed membrane reactor (FMFMDR) produces gasoline from synthesis gas. The walls of the tubes of a fixed-bed reactor (water-cooled reactor) of FMFMDR configuration are coated by a high water perm-selective membrane layer. In this new configuration, two membrane reactors instead of one membrane reactor are developed for FTS reactions. In other words, two different membrane layers are used. In order to investigate the performance of FMFMDR, a one-dimensional heterogeneous model is taken into consideration. The simulation results of three schemes named fluidized-bed membrane dual-type reactor (FMDR), FMFMDR and conventional fixed-bed reactor (CR) are presented. They have been compared in terms of temperature, gasoline and CO2 yields, H2 and CO conversions and the water permeation rate through the membrane layer. Results show that the gasoline yield in FMFMDR is higher than the one in FMDR. The FMFMDR configuration not only decreases the undesired product such as CO2 but also produces more gasoline. -- Research highlights: → The application of H-SOD membrane layer in FTS reactors. → Approximate 7.5% and 37% increase in the gasoline yield in terms of [g/g feed x 100] in comparison with FMDR and CR, respectively. → A remarkable decrease in CO2 emission to the environment. → A good configuration mainly due to reduction in catalysts sintering as a result of in situ water removal.

  14. Fischer-Tropsch Synthesis over Cobalt-based Catalysts for BTL applications

    OpenAIRE

    Lualdi, Matteo

    2012-01-01

    Fischer-Tropsch synthesis is a commercial technology that allows converting synthesis gas, a mixture of CO and H2, into fuels and chemicals. This process could be one of the actors in the reduction of oil dependency of the transportation sector. In fact, it has great potential for producing synthetic fuels also from renewable sources, such as biomass, after its thermochemical conversion (gasification) into synthesis gas. Concerning the quality of a diesel fuel produced with this technology, i...

  15. Fischer-Tropsch catalysts for the production of hydrocarbon fuels with high selectivity.

    Science.gov (United States)

    Zhang, Qinghong; Cheng, Kang; Kang, Jincan; Deng, Weiping; Wang, Ye

    2014-05-01

    Fischer-Tropsch synthesis is a key reaction in the utilization of non-petroleum carbon resources, such as methane (natural gas, shale gas, and biogas), coal, and biomass, for the sustainable production of clean liquid fuels from synthesis gas. Selectivity control is one of the biggest challenges in Fischer-Tropsch synthesis. This Minireview focuses on the development of new catalysts with controllable product selectivities. Recent attempts to increase the selectivity to C5+ hydrocarbons by preparing catalysts with well-defined active phases or with new supports or by optimizing the interaction between the promoter and the active phase are briefly highlighted. Advances in developing bifunctional catalysts capable of catalyzing both CO hydrogenation to heavier hydrocarbons and hydrocracking/isomerization of heavier hydrocarbons are critically reviewed. It is demonstrated that the control of the secondary hydrocracking reactions by using core-shell nanostructures or solid-acid materials, such as mesoporous zeolites and carbon nanotubes with acid functional groups, is an effective strategy to tune the product selectivity of Fischer-Tropsch synthesis. Very promising selectivities to gasoline- and diesel-range hydrocarbons have been attained over some bifunctional catalysts. PMID:24339240

  16. New developments in cobalt-based Fischer-Tropsch catalysis and processes

    Energy Technology Data Exchange (ETDEWEB)

    Singleton, A.H.; Davis, B.E.; Oukaci, R. [Energy International Corp., Pittsburgh, PA (United States)

    1997-12-31

    The Williams Companies, Inc. of Tulsa, Oklahoma, has announced a breakthrough in gas-to-liquids (GTL) technology that revolutionizes the production of transportation fuels from natural gas. Building on its twenty years of research in Fischer-Tropsch (F-T) conversion technology, Williams has developed a new process that significantly outperforms existing GTL technologies for large-scale (ca. 50,000 BPSD) applications and advances the state-of the-art of converting natural gas into high quality liquid transportation fuels. By employing a new generation of cobalt-based catalysts, Williams` GasCat{sup SM} F-T process achieves high productivity, resulting in superior catalytic reactor performance compared to existing F-T techniques. The GasCat process also reduces capital requirements and operating costs by employing advanced slurry bubble column reactor (SBCR) technology. Although the process is applicable to coal derived synthesis gas, GasCat has enormous implications for large remote gas reserves worldwide, due to the limited options previously available for exploiting the potential of such reservoirs. While the paper presents the details and significance of this new development as it relates to natural gas, it obviously has similar significance to the indirect liquefaction of coal.

  17. Alternative Fuel Research in Fischer-Tropsch Synthesis

    Science.gov (United States)

    Surgenor, Angela D.; Klettlinger, Jennifer L.; Yen, Chia H.; Nakley, Leah M.

    2011-01-01

    NASA Glenn Research Center has recently constructed an Alternative Fuels Laboratory which is solely being used to perform Fischer-Tropsch (F-T) reactor studies, novel catalyst development and thermal stability experiments. Facility systems have demonstrated reliability and consistency for continuous and safe operations in Fischer-Tropsch synthesis. The purpose of this test facility is to conduct bench scale Fischer-Tropsch (F-T) catalyst screening experiments while focusing on reducing energy inputs, reducing CO2 emissions and increasing product yields within the F-T process. Fischer-Tropsch synthesis is considered a gas to liquid process which reacts syn-gas (a gaseous mixture of hydrogen and carbon monoxide), over the surface of a catalyst material which is then converted into liquids of various hydrocarbon chain length and product distributions1. These hydrocarbons can then be further processed into higher quality liquid fuels such as gasoline and diesel. The experiments performed in this laboratory will enable the investigation of F-T reaction kinetics to focus on newly formulated catalysts, improved process conditions and enhanced catalyst activation methods. Currently the facility has the capability of performing three simultaneous reactor screening tests, along with a fourth fixed-bed reactor used solely for cobalt catalyst activation.

  18. Overview of Fischer-Tropsch Synthesis in Slurry Reactors

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A brief review of Fischer-Tropsch synthesis specially in slurry reactors ispresented, covering reaction kinetics, activity and selectivity of catalysts, productdistribution, effects of process parameters, mass transfer and solubility of gas. Someimportant aspects of further research are proposed for improving both theories andproduction.

  19. Fischer-Tropsch synthesis on alumina supported cobalt catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Bechara, R.; Balloy, D.; Vanhove, D.

    1997-11-01

    Physico-chemical properties of Co/Al{sub 2}O{sub 3}-gamma were investigated by XRD, XPS, thermogravimetry and catalytic measurements. Interactions between the metal and its support were found for catalysts prepared from alumina with the greater specific area. For the Fischer-Tropsch synthesis, the products distribution appeared not to be sensitive to the cobalt particle size, but seems to depend on the degree of cobalt reduction.

  20. Subtask 3.4 - Fischer - Tropsch Fuels Development

    Energy Technology Data Exchange (ETDEWEB)

    Strege, Joshua; Snyder, Anthony; Laumb, Jason; Stanislowski, Joshua; Swanson, Michael

    2012-05-01

    Under Subtask 3.4, the Energy & Environmental Research Center (EERC) examined the opportunities and challenges facing FischerTropsch (FT) technology in the United States today. Work was completed in two distinct budget periods (BPs). In BP1, the EERC examined the technical feasibility of using modern warm-gas cleanup techniques for FT synthesis. FT synthesis is typically done using more expensive and complex cold-gas sweetening. Warm-gas cleanup could greatly reduce capital and operating costs, making FT synthesis more attractive for domestic fuel production. Syngas was generated from a variety of coal and biomass types; cleaned of sulfur, moisture, and condensables; and then passed over a pilot-scale FT catalyst bed. Laboratory and modeling work done in support of the pilot-scale effort suggested that the catalyst was performing suboptimally with warm-gas cleanup. Long-term trends showed that the catalyst was also quickly deactivating. In BP3, the EERC compared FT catalyst results using warm-gas cleanup to results using cold-gas sweetening. A gas-sweetening absorption system (GSAS) was designed, modeled, and constructed to sweeten syngas between the gasifier and the pilot-scale FT reactor. Results verified that the catalyst performed much better with gas sweetening than it had with warm-gas cleanup. The catalyst also showed no signs of rapid deactivation when the GSAS was running. Laboratory tests in support of this effort verified that the catalyst had deactivated quickly in BP1 because of exposure to syngas, not because of any design flaw with the pilot-scale FT reactor itself. Based on these results, the EERC concludes that the two biggest issues with using syngas treated with warm-gas cleanup for FT synthesis are high concentrations of CO{sub 2} and volatile organic matter. Other catalysts tested by the EERC may be more tolerant of CO{sub 2}, but volatile matter removal is critical to ensuring long-term FT catalyst operation. This subtask was funded through

  1. DEVELOPMENT OF PRECIPITATED IRON FISCHER-TROPSCH CATALYSTS

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Dragomir B. Bukur; Dr. X. Lang; Dr. S. Chokkaram; Dr. L. Nowicki; G. Wei; Dr. Y. Ding; Dr. B. Reddy; Dr. S. Xiao

    1999-07-22

    Despite the current worldwide oil glut, the US will ultimately require large-scale production of liquid (transportation) fuels from coal. Slurry phase Fischer-Tropsch (F-T) technology, with its versatile product slate, may be expected to play a major role in production of transportation fuels via indirect coal liquefaction. Some of the F-T catalysts synthesized and tested at Texas A and M University under DOE Contract No. DE-AC22-89PC89868 were more active than any other known catalysts developed for maximizing production of high molecular weight hydrocarbons (waxes). The objectives of the present contract were to demonstrate repeatability of catalyst performance and reproducibility of preparation procedures of two of these catalysts on a laboratory scale. Improvements in the catalyst performance were attempted through the use of: (a) higher reaction pressure and gas space velocity to maximize the reactor productivity; (b) modifications in catalyst preparation steps; and (c) different pretreatment procedures. Repeatability of catalyst performance and reproducibility of catalyst synthesis procedure have been successfully demonstrated in stirred tank slurry reactor tests. Reactor space-time-yield was increased up to 48% by increasing reaction pressure from 1.48 MPa to 2.17 MPa, while maintaining the gas contact time and synthesis gas conversion at a constant value. Use of calcination temperatures above 300 C, additional CaO promoter, and/or potassium silicate as the source of potassium promoter, instead of potassium bicarbonate, did not result in improved catalyst performance. By using different catalyst activation procedures they were able to increase substantially the catalyst activity, while maintaining low methane and gaseous hydrocarbon selectivities. Catalyst productivity in runs SA-0946 and SA-2186 was 0.71 and 0.86 gHC/g-Fe/h, respectively, and this represents 45-75% improvement in productivity relative to that achieved in Rheinpreussen's demonstration

  2. DEVELOPMENT OF PRECIPITATED IRON FISCHER-TROPSCH CATALYSTS

    International Nuclear Information System (INIS)

    Despite the current worldwide oil glut, the US will ultimately require large-scale production of liquid (transportation) fuels from coal. Slurry phase Fischer-Tropsch (F-T) technology, with its versatile product slate, may be expected to play a major role in production of transportation fuels via indirect coal liquefaction. Some of the F-T catalysts synthesized and tested at Texas A and M University under DOE Contract No. DE-AC22-89PC89868 were more active than any other known catalysts developed for maximizing production of high molecular weight hydrocarbons (waxes). The objectives of the present contract were to demonstrate repeatability of catalyst performance and reproducibility of preparation procedures of two of these catalysts on a laboratory scale. Improvements in the catalyst performance were attempted through the use of: (a) higher reaction pressure and gas space velocity to maximize the reactor productivity; (b) modifications in catalyst preparation steps; and (c) different pretreatment procedures. Repeatability of catalyst performance and reproducibility of catalyst synthesis procedure have been successfully demonstrated in stirred tank slurry reactor tests. Reactor space-time-yield was increased up to 48% by increasing reaction pressure from 1.48 MPa to 2.17 MPa, while maintaining the gas contact time and synthesis gas conversion at a constant value. Use of calcination temperatures above 300 C, additional CaO promoter, and/or potassium silicate as the source of potassium promoter, instead of potassium bicarbonate, did not result in improved catalyst performance. By using different catalyst activation procedures they were able to increase substantially the catalyst activity, while maintaining low methane and gaseous hydrocarbon selectivities. Catalyst productivity in runs SA-0946 and SA-2186 was 0.71 and 0.86 gHC/g-Fe/h, respectively, and this represents 45-75% improvement in productivity relative to that achieved in Rheinpreussen's demonstration plant

  3. The role of additives in Fischer-Tropsch reactions

    OpenAIRE

    Perdjon-Abel, Michal

    2011-01-01

    The Fischer-Tropsch Synthesis (FTS) is an alternative route to produce liquid fuels from a variety of carbon feedstocks including coal and biomass. Typically iron and cobalt based catalysts have been used for the FTS reaction, in which a mixture of CO and H2 (syn-gas) reacts to form hydrocarbons. Enhanced performance has been reported for iron-based systems doped with alkali metals and chalcogenides. Sulfides are considered a poison for most catalytic processes, but sulfur in the form of sulf...

  4. (Pittsburgh Energy Technology Center): Quarterly technical progress report for the period ending June 30, 1987. [Advanced Coal Research and Technology Development Programs

    Energy Technology Data Exchange (ETDEWEB)

    None

    1988-02-01

    Research programs on coal and coal liquefaction are presented. Topics discussed are: coal science, combustion, kinetics, surface science; advanced technology projects in liquefaction; two stage liquefaction and direct liquefaction; catalysts of liquefaction; Fischer-Tropsch synthesis and thermodynamics; alternative fuels utilization; coal preparation; biodegradation; advanced combustion technology; flue gas cleanup; environmental coordination, and technology transfer. Individual projects are processed separately for the data base. (CBS)

  5. Conversion enhancement of tubular fixed-bed reactor for Fischer-Tropsch synthesis using static mixer

    Institute of Scientific and Technical Information of China (English)

    Phavanee Narataruksa; Sabaithip Tungkamani; Karn Pana-Suppamassadu; Phongsak Keeratiwintakorn; Siriluck Nivitchanyong; Piyapong Hunpinyo; Hussanai Sukkathanyawat; Prayut Jiamrittiwong; Visarut Nopparat

    2012-01-01

    Recently,Fischer-Tropsch synthesis (FTS) has become an interesting technology because of its potential role in producing biofuels via Biomassto-Liquids (BTL) processes.In Fischer-Tropsch (FT) section,biomass-derived syngas,mainly composed of a mixture of carbon monoxide (CO)and hydrogen (H2),is converted into various forms of hydrocarbon products over a catalyst at specified temperature and pressure.Fixed-bed reactors are typically used for these processes as conventional FT reactors.The fixed-bed or packed-bed type reactor has its drawbacks,which are heat transfer limitation,i.e.a hot spot problem involved highly exothermic characteristics of FT reaction,and mass transfer limitation due to the condensation of liquid hydrocarbon products occurred on catalyst surface.This work is initiated to develop a new chemical reactor design in which a better distribution of gaseous reactants and hydrocarbon products could be achieved,and led to higher throughput and conversion.The main goal of the research is the enhancement of a fixed-bed reactor,focusing on the application of KenicsTM static mixer insertion in the tubular packed-bed reactor.Two FTS experiments were carried out using two reactors i.e.,with and without static mixer insertion within catalytic beds.The modeled syngas used was a mixed gas composed of H2/CO in 2 ∶ 1 molar ratio that was fed at the rate of 30 mL(STP)·min-1 (GHSV ≈ 136 mL·g-1cat·h-1) into the fixed Ru supported aluminum catalyst bed of weight 13.3 g.The reaction was carried out at 180 ℃ and atmospheric pressure continuously for 36 h for both experiments.Both transient and steady-state conversions (in terms of time on stream) were reported.The results revealed that the steady-state CO conversion for the case using the static mixer was approximately 3.5 times higher than that of the case without static mixer.In both cases,the values of chain growth probability of hydrocarbon products (α) for Fischer-Tropsch synthesis were 0.92 and 0.89 for

  6. Morphological transformation during activation and reaction of an iron Fischer-Tropsch catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Jackson, N.B.; Kohler, S.; Harrington, M. [Sandia National Lab., Albuquerque, NM (United States)] [and others

    1995-12-31

    The purpose of this project is to support the development of slurry-phase bubble column processes being studied at the La Porte Alternative Fuel Development Unit. This paper describes the aspects of Sandia`s recent work regarding the advancement and understanding of the iron catalyst used in the slurry phase process. A number of techniques were used to understand the chemical and physical effects of pretreatment and reaction on the attrition and carbon deposition characteristics of iron catalysts. Unless otherwise stated, the data discussed was derived form experiments carried out on the catalyst chosen for the summer 1994 Fischer-Tropsch run at LaPorte, UCI 1185-78-370, (an L 3950 type) that is 88% Fe{sub 2}O{sub 3}, 11% CuO, and 0.052%K{sub 2}O.

  7. Noble Metal Catalysts for the Hydrocracking of Fischer-Tropsch waxes

    OpenAIRE

    Elorriaga de la Fuente, Ibone

    2012-01-01

    Fischer-Tropsch synthesis enables the production of high quality diesel fuel from biomass derived synthesis gas. In order to increase the overall diesel yield, it is necessary to perform a subsequent hydrocracking of the long-chain linear paraffins. This work is focused on characterization and testing of catalysts for the hydrocracking reaction of Fischer-Tropsch waxes. In particular, noble metal catalyst based on Pt and Pd on amorphous silica-alumina support were tested. Palladium based cata...

  8. Iron on mixed zirconia-titania substrate Fischer-Tropsch catalyst and method of making same

    Science.gov (United States)

    Dyer, Paul N.; Nordquist, Andrew F.; Pierantozzi, Ronald

    1986-01-01

    A Fischer-Tropsch catalyst comprising iron co-deposited with or deposited on particles comprising a mixture of zirconia and titania, preferably formed by co-precipitation of compounds convertible to zirconia and titania, such as zirconium and titanium alkoxide. The invention also comprises the method of making this catalyst and an improved Fischer-Tropsch reaction process in which the catalyst is utilized.

  9. Techno-economic performance analysis of bio-oil based Fischer-Tropsch and CHP synthesis platform

    International Nuclear Information System (INIS)

    The techno-economic potential of the UK poplar wood and imported oil palm empty fruit bunch derived bio-oil integrated gasification and Fischer-Tropsch (BOIG-FT) systems for the generation of transportation fuels and combined heat and power (CHP) was investigated. The bio-oil was represented in terms of main chemical constituents, i.e. acetic acid, acetol and guaiacol. The compositional model of bio-oil was validated based on its performance through a gasification process. Given the availability of large scale gasification and FT technologies and logistic constraints in transporting biomass in large quantities, distributed bio-oil generations using biomass pyrolysis and centralised bio-oil processing in BOIG-FT system are technically more feasible. Heat integration heuristics and composite curve analysis were employed for once-through and full conversion configurations, and for a range of economies of scale, 1 MW, 675 MW and 1350 MW LHV of bio-oil. The economic competitiveness increases with increasing scale. A cost of production of FT liquids of 78.7 Euro/MWh was obtained based on 80.12 Euro/MWh of electricity, 75 Euro/t of bio-oil and 116.3 million Euro/y of annualised capital cost. -- Highlights: → Biomass to liquid process and gas to liquid process synthesis. → Biorefinery economic analysis. → Pyrolysis oil to biofuel. → Gasification and Fischer-Tropsch. → Process integration, pinch analysis and energy efficiency.

  10. Synthesis gas solubility in Fischer-Tropsch slurry: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Chao, K.C.; Lin, H.M.

    1988-01-01

    The objective is to investigate the phase equilibrium behavior of synthesis gases and products in a Fischer-Tropsch slurry reactor. A semi-flow apparatus has been designed and constructed for this purpose. Measurements have been made for hydrogen, cabon monoxide, methane, ethane, ethylene, and carbon dioxide in a heavy n-paraffin at temperatures from 100 to 300)degree)C and pressures 10 to 50 atm. Three n-paraffin waxes: n-eicosane (n-C/sub 20/), n-octacosane )n-C/sub 28/), and n-hexatriacontane (n-C/sub 36/), were studied to model the industrial wax. Solubility of synthesis gas mixtures of H/sub 2/ and CO in n-C/sub 28/ was also determined at two temperatures (200 and 300)degree)C) for each of three gas compositions (40.01, 50.01, and 66.64 mol%) of hydrogen). Measurements were extended to investigate the gas solubility in two industrial Fischer-Tropsch waxes: Mobilwax and SASOL wax. Observed solubility increases in the order: H/sub 2/, CO, CH/sub 4/, CO/sub 2/, C/sub 2/H/sub 4/, C/sub 2/H/sub 6/, at a given temperature pressure, and in the same solvent. Solubility increases with increasing pressure for all the gases. Lighter gases H/sub 2/ and CO show increased solubility with increasing temperature, while the heavier gases CO/sub 2/, ethane, and ethylene show decreased solubility with increasing temperature. The solubility of methane, the intermediate gas, changes little with temperature, and shows a shallow minimum at about 200)degrees)C or somewhat above. Henry's constant and partial molal volume of the gas solute at infinite dilution are determinedfrom the gas solubility data. A correlation is developed from the experimental data in the form on an equation of state. A computer program has been prepared to implement the correlation. 19 refs., 66 figs., 39 tabs.

  11. Reduction and reoxidation of cobalt Fischer-Tropsch catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Hilmen, Anne-Mette

    1996-12-31

    The Fischer-Tropsch synthesis involves the hydrogenation of carbon monoxide to produce mainly hydrocarbons, water and carbon dioxide, but also alcohols, aldehydes and acids are formed. The distribution of these products is determined by the choice of catalyst and synthesis conditions. This thesis studies the reduction and reoxidation of 17%Co/Al{sub 2}O{sub 3} and 17%Co-1%Re/Al{sub 2}O{sub 3} by means of several characterization techniques. The effect of small amounts of Re on the reduction properties of Al{sub 2}O{sub 3}-supported Co catalysts has been studied by temperature-programmed reduction (TPR). An intimate mixture of CoAl{sub 2}O{sub 3} and Re/Al{sub 2}O{sub 3} catalysts showed a promoting effect of Re similar to that for co impregnated CoRe/Al{sub 2}O{sub 3}. A loose mixture of Co/Al{sub 2}O{sub 3} + Re/Al{sub 2}O{sub 3} did not show any effect of Re on the reduction of Co. But a promoting effect was observed if the mixture had been pre-treated with Ar saturated with water before the TPR. It is suggested that Re promotes the reduction of Co oxide by hydrogen spillover. It is shown that a high temperature TPK peak at 1200K assigned to Co aluminate is mainly caused by the diffusion of Co ions during the TPR and not during calcination. The Co particle size measured by x-ray diffraction on oxidized catalysts decreased compared to the particle size on the calcined catalysts, while the dispersion measured by volumetric chemisorption decreased somewhat after the oxidation-reduction treatment. The role of water in the deactivation of Co/Al{sub 2}O{sub 3} and CoRe/Al{sub 2}O{sub 3} Fischer-Tropsch catalysts has been extensively studied. There were significant differences in the reducibility of the phases formed for the two catalysts during exposure to H{sub 2}O/He. 113 refs., 76 figs., 18 tabs.

  12. LIQUID PHASE FISCHER-TROPSCH (III & IV) DEMONSTRATION IN THE LAPORTE ALTERNATIVE FUELS DEVELOPMENT UNIT. Final Topical Report. Volume I/II: Main Report. Task 1: Engineering Modifications (Fischer-Tropsch III & IV Demonstration) and Task 2: AFDU Shakedown, Operations, Deactivation (Shut-Down) and Disposal (Fischer-Tropsch III & IV Demonstration).

    Energy Technology Data Exchange (ETDEWEB)

    Bharat L. Bhatt

    1999-06-01

    Slurry phase Fischer-Tropsch technology was successfully demonstrated in DOE's Alternative Fuels Development Unit (AFDU) at LaPorte, Texas. Earlier work at LaPorte, with iron catalysts in 1992 and 1994, had established proof-of-concept status for the slurry phase process. The third campaign (Fischer-Tropsch III), in 1996, aimed at aggressively extending the operability of the slurry reactor using a proprietary cobalt catalyst. Due to an irreversible plugging of catalyst-wax separation filters as a result of unexpected catalyst fines generation, the operations had to be terminated after seven days on-stream. Following an extensive post-run investigation by the participants, the campaign was successfully completed in March-April 1998, with an improved proprietary cobalt catalyst. These runs were sponsored by the U. S. Department of Energy (DOE), Air Products & Chemicals, Inc., and Shell Synthetic Fuels, Inc. (SSFI). A productivity of approximately 140 grams (gm) of hydrocarbons (HC)/ hour (hr)-liter (lit) of expanded slurry volume was achieved at reasonable system stability during the second trial (Fischer-Tropsch IV). The productivity ranged from 110-140 at various conditions during the 18 days of operations. The catalyst/wax filters performed well throughout the demonstration, producing a clean wax product. For the most part, only one of the four filter housings was needed for catalyst/wax filtration. The filter flux appeared to exceed the design flux. A combination of use of a stronger catalyst and some innovative filtration techniques were responsible for this success. There was no sign of catalyst particle attrition and very little erosion of the slurry pump was observed, in contrast to the Fischer-Tropsch III operations. The reactor operated hydrodynamically stable with uniform temperature profile and gas hold-ups. Nuclear density and differential pressure measurements indicated somewhat higher than expected gas hold-up (45 - 50 vol%) during Fischer-Tropsch

  13. KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS

    International Nuclear Information System (INIS)

    This report covers the second year of this three-year research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict concentrations of all reactants and major product species (H2O, CO2, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the second year of the project we completed the STSR test SB-26203 (275-343 h on stream), which was initiated during the first year of the project, and another STSR test (SB-28603 lasting 341 h). Since the inception of the project we completed 3 STSR tests, and evaluated catalyst under 25 different sets of process conditions. A precipitated iron catalyst obtained from Ruhrchemie AG (Oberhausen-Holten, Germany) was used in all tests. This catalyst was used initially in commercial fixed bed reactors at Sasol in South Africa. Also, during the second year we performed a qualitative analysis of experimental data from all three STSR tests. Effects of process conditions (reaction temperature, pressure, feed composition and gas space velocity) on water-gas-shift (WGS) activity and hydrocarbon product distribution have been determined

  14. KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS

    International Nuclear Information System (INIS)

    This report covers the first year of this three-year research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict concentrations of all reactants and major product species (H2O, CO2, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the reporting period we have completed one STSR test with precipitated iron catalyst obtained from Ruhrchemie AG (Oberhausen-Holten, Germany). This catalyst was initially in commercial fixed bed reactors at Sasol in South Africa. The catalyst was tested at 13 different sets of process conditions, and had experienced a moderate deactivation during the first 500 h of testing (decrease in conversion from 56% to 50% at baseline process conditions). The second STSR test has been initiated and after 270 h on stream, the catalyst was tested at 6 different sets of process conditions

  15. Effects of Fischer-Tropsch diesel fuel on combustion and emissions of direct injection diesel engine

    Institute of Scientific and Technical Information of China (English)

    Yongcheng HUANG; Shangxue WANG; Longbao ZHOU

    2008-01-01

    Effects of Fischer-Tropsch (F-T) diesel fuel on the combustion and emission characteristics of a single-cylinder direct injection diesel engine under different fuel delivery advance angles were investigated. The experi-mental results show that F-T diesel fuel exhibits shorter ignition delay, lower peak values of premixed burning rate, lower combustion pressure and pressure rise rate, and higher peak value of diffusion burning rate than con-ventional diesel fuel when the engine remains unmodified. In addition, the unmodified engine with F-T diesel fuel has lower brake specific fuel consumption and higher effective thermal efficiency, and presents lower HC, CO, NOx and smoke emissions than conventional diesel fuel. When fuel delivery advance angle is retarded by 3 crank angle degrees, the combustion duration is obviously shor-tened; the peak values of premixed burning rate, the com-bustion pressure and pressure rise rate are further reduced; and the peak value of diffusion burning rate is further increased for F-T diesel fuel operation, Moreover, the retardation of fuel delivery advance angle results in a further significant reduction in NOx emissions with no penalty on specific fuel consumption and with much less penalty on HC, CO and smoke emissions.

  16. Fischer-Tropsch Reaction Kinetics of Cobalt Catalyst in Supercritical Phase

    Institute of Scientific and Technical Information of China (English)

    Abdullah Irankhah; Ali Haghtalab; Ebrahim Vasheghani Farahani; Kambiz Sadaghianizadeh

    2007-01-01

    Fischer-Tropsch synthesis under supercritical phase condition was examined in a continuous and a high-pressure fixed bed reactor by employing a cobalt catalyst (Co-Ru/γ-Al2O3). An integral reactor model involving Fischer-Tropsch reaction kinetics in the supercritical fluid n-hexane was used to describe the overall performance. On the basis of Langmuir-Hinshelwood-Hougen-Watson (LHHW) model, the reaction rate constants were obtained for the rate equations of CO conversion to CH4 formation under supercritical conditions.

  17. Emissions from Road Vehicles Fuelled by Fischer Tropsch Based Diesel and Gasoline

    Energy Technology Data Exchange (ETDEWEB)

    Larsen, U.; Lundorf, P.; Ivarsson, A.; Schramm, J. [Technical University of Denmark (Denmark); Rehnlund, B. [Atrax Energi AB (Sweden); Blinge, M. [The Swedish Transport Institute (Sweden)

    2006-11-15

    The described results were carried out under the umbrella of IEA Advanced Motor Fuels Agreement. The purpose was to evaluate the emissions of carbon monoxide (CO), unburned hydrocarbons (HC), nitrogen oxides (NOx), particulate matter (PM) and polycyclic aromatic hydrocarbons (PAH) from vehicles fuelled by Fischer Tropsch (FT) based diesel and gasoline fuel, compared to the emissions from ordinary diesel and gasoline. The comparison for diesel fuels was based on a literature review, whereas the gasoline comparison had to be based on our own experiments, since almost no references were found in this field. In this context measurement according to the Federal Test Procedure (FTP) and the New European Driving Cycle (NEDC) were carried out on a chassis dynamometer with a directly injected gasoline vehicle. Experiments were carried out with a reference fuel, a fuel based 70% on FT and an alkylate fuel (Aspen), which was supposed to be very similar, in many ways, to FT fuel. FT based diesel generally showed good emission performance, whereas the FT based gasoline not necessary lead to lower emissions. On the other hand, the Aspen fuel did show many advantages for the emissions from the gasoline vehicle.

  18. Small-Scale Coal-Biomass to Liquids Production Using Highly Selective Fischer-Tropsch Synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Gangwal, Santosh K. [Southern Research Institute, Durham, NC (United States); McCabe, Kevin [Southern Research Institute, Durham, NC (United States)

    2015-04-30

    The research project advanced coal-to-liquids (CTL) and coal-biomass to liquids (CBTL) processes by testing and validating Chevron’s highly selective and active cobalt-zeolite hybrid Fischer-Tropsch (FT) catalyst to convert gasifier syngas predominantly to gasoline, jet fuel and diesel range hydrocarbon liquids, thereby eliminating expensive wax upgrading operations The National Carbon Capture Center (NCCC) operated by Southern Company (SC) at Wilsonville, Alabama served as the host site for the gasifier slip-stream testing/demonstration. Southern Research designed, installed and commissioned a bench scale skid mounted FT reactor system (SR-CBTL test rig) that was fully integrated with a slip stream from SC/NCCC’s transport integrated gasifier (TRIGTM). The test-rig was designed to receive up to 5 lb/h raw syngas augmented with bottled syngas to adjust the H2/CO molar ratio to 2, clean it to cobalt FT catalyst specifications, and produce liquid FT products at the design capacity of 2 to 4 L/day. It employed a 2-inch diameter boiling water jacketed fixed-bed heat-exchange FT reactor incorporating Chevron’s catalyst in Intramicron’s high thermal conductivity micro-fibrous entrapped catalyst (MFEC) packing to efficiently remove heat produced by the highly exothermic FT reaction.

  19. ULTRA-CLEAN FISCHER-TROPSCH FUELS PRODUCTION AND DEMONSTRATION PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    Steve Bergin

    2003-10-17

    The Syntroleum plant is mechanically complete and currently undergoing start-up. The fuel production and demonstration plan is near completion. The study on the impact of small footprint plant (SFP) fuel on engine performance is about half-completed. Cold start testing has been completed. Preparations have been completed for testing the fuel in diesel electric generators in Alaska. Preparations are in progress for testing the fuel in bus fleets at Denali National Park and the Washington Metropolitan Transit Authority. The experiments and analyses conducted during this project show that Fischer-Tropsch (FT) gas-to-liquid diesel fuel can easily be used in a diesel engine with little to no modifications. Additionally, based on the results and discussion presented, further improvements in performance and emissions can be realized by configuring the engine to take advantage of FT diesel fuel's properties. The FT fuel also shows excellent cold start properties and enabled the engine tested to start at more the ten degrees than traditional fuels would allow. This plant produced through this project will produce large amounts of FT fuel. This will allow the fuel to be tested extensively, in current, prototype, and advanced diesel engines. The fuel may also contribute to the nation's energy security. The military has expressed interest in testing the fuel in aircraft and ground vehicles.

  20. Development of the Fischer-Tropsch Process: From the Reaction Concept to the Process Book

    Directory of Open Access Journals (Sweden)

    Boyer C.

    2016-05-01

    Full Text Available The process development by IFP Energies nouvelles (IFPEN/ENI/Axens of a Fischer-Tropsch process is described. This development is based on upstream process studies to choose the process scheme, reactor technology and operating conditions, and downstream to summarize all development work in a process guide. A large amount of work was devoted to the catalyst performances on one hand and the scale-up of the slurry bubble reactor with dedicated complementary tools on the other hand. Finally, an original approach was implemented to validate both the process and catalyst on an industrial scale by combining a 20 bpd unit in ENI’s Sannazzaro refinery, with cold mock-ups equivalent to 20 and 1 000 bpd at IFPEN and a special “Large Validation Tool” (LVT which reproduces the combined effect of chemical reaction condition stress and mechanical stress equivalent to a 15 000 bpd industrial unit. Dedicated analytical techniques and a dedicated model were developed to simulate the whole process (reactor and separation train, integrating a high level of complexity and phenomena coupling to scale-up the process in a robust reliable base on an industrial scale.

  1. Coupling of glycerol processing with Fischer-Tropsch synthesis for production of liquid fuels

    DEFF Research Database (Denmark)

    Simonetti, D.A.; Rass-Hansen, Jeppe; Kunkes, E.L.;

    2007-01-01

    wt% methanol, ethanol, and acetone, which can be separated from the water by distillation and used in the chemical industry or recycled for conversion to gaseous products. This integrated process has the potential to improve the economics of "green'' Fischer-Tropsch synthesis by reducing capital...

  2. KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYSTHESIS

    Energy Technology Data Exchange (ETDEWEB)

    Dragomir B. Bukur; Gilbert F. Froment; Tomasz Olewski

    2005-09-29

    This report covers the third year of this research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis (FTS) on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict molar flow rates and concentrations of all reactants and major product species (H{sub 2}O, CO{sub 2}, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the reporting period we utilized experimental data from the STSR, that were obtained during the first two years of the project, to perform vapor-liquid equilibrium (VLE) calculations and estimate kinetic parameters. We used a modified Peng-Robinson (PR) equation of state (EOS) with estimated values of binary interaction coefficients for the VLE calculations. Calculated vapor phase compositions were in excellent agreement with experimental values from the STSR under reaction conditions. Occasional discrepancies (for some of the experimental data) between calculated and experimental values of the liquid phase composition were ascribed to experimental errors. The VLE calculations show that the vapor and the liquid are in thermodynamic equilibrium under reaction conditions. Also, we have successfully applied the Levenberg-Marquardt method (Marquardt, 1963) to estimate parameters of a kinetic model proposed earlier by Lox and Froment (1993b) for FTS on an iron catalyst. This kinetic model is well suited for initial studies where the main goal is to learn techniques for parameter estimation and statistical analysis of estimated values of model parameters. It predicts that the chain growth parameter ({alpha}) and olefin to paraffin ratio are independent of carbon number, whereas our experimental data show that they vary with the carbon number

  3. KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS

    Energy Technology Data Exchange (ETDEWEB)

    Dragomir B. Bukur; Gilbert F. Froment; Tomasz Olewski

    2006-09-29

    This report covers the fourth year of a research project conducted under the University Coal Research Program. The overall objective of this project is to develop a comprehensive kinetic model for slurry-phase Fischer-Tropsch synthesis (FTS) employing iron-based catalysts. This model will be validated with experimental data obtained in a stirred-tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict molar flow rates and concentrations of all reactants and major product species (water, carbon dioxide, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the fourth year of the project, an analysis of experimental data collected during the second year of this project was performed. Kinetic parameters were estimated utilizing product distributions from 27 mass balances. During the reporting period two kinetic models were employed: a comprehensive kinetic model of Dr. Li and co-workers (Yang et al., 2003) and a hydrocarbon selectivity model of Van der Laan and Beenackers (1998, 1999) The kinetic model of Yang et al. (2003) has 24 parameters (20 parameters for hydrocarbon formation, and 4 parameters for the water-gas-shift (WGS) reaction). Kinetic parameters for the WGS reaction and FTS synthesis were estimated first separately, and then simultaneously. The estimation of these kinetic parameters employed the Levenberg-Marquardt (LM) method and the trust-region reflective Newton large-scale (LS) method. A genetic algorithm (GA) was incorporated into estimation of parameters for FTS reaction to provide initial estimates of model parameters. All reaction rate constants and activation energies were found to be positive, but at the 95% confidence level the intervals were large. Agreement between predicted and experimental reaction rates has been fair to good. Light hydrocarbons are predicted fairly accurately, whereas the model underpredicts values of higher molecular weight

  4. KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYSTHESIS

    International Nuclear Information System (INIS)

    This report covers the third year of this research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis (FTS) on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict molar flow rates and concentrations of all reactants and major product species (H2O, CO2, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the reporting period we utilized experimental data from the STSR, that were obtained during the first two years of the project, to perform vapor-liquid equilibrium (VLE) calculations and estimate kinetic parameters. We used a modified Peng-Robinson (PR) equation of state (EOS) with estimated values of binary interaction coefficients for the VLE calculations. Calculated vapor phase compositions were in excellent agreement with experimental values from the STSR under reaction conditions. Occasional discrepancies (for some of the experimental data) between calculated and experimental values of the liquid phase composition were ascribed to experimental errors. The VLE calculations show that the vapor and the liquid are in thermodynamic equilibrium under reaction conditions. Also, we have successfully applied the Levenberg-Marquardt method (Marquardt, 1963) to estimate parameters of a kinetic model proposed earlier by Lox and Froment (1993b) for FTS on an iron catalyst. This kinetic model is well suited for initial studies where the main goal is to learn techniques for parameter estimation and statistical analysis of estimated values of model parameters. It predicts that the chain growth parameter (α) and olefin to paraffin ratio are independent of carbon number, whereas our experimental data show that they vary with the carbon number. Predicted molar flow

  5. How to make Fischer-Tropsch catalyst scale-up fully reliable?

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, L.; Heraud, J.P.; Forret, A.; Gazarian, J. [IFP Energies nouvelles, Solaize (France); Cornaro, U. [Eni S.p.A., San Donato Milanese (Italy). R and M Div.; Carugati, A. [Eni S.p.A., San Donato Milanese (Italy). E and P Div.

    2011-07-01

    Several players use Fischer-Tropsch catalysts and technologies industrially [1,2] or declare to be ready for industrial application [e.g. 3]. Present R and D aims to further increase capacities per train [4] or improve catalyst selectivity towards middle distillates [5]. For transforming promising laboratory results into industrial reality, representative catalyst testing is of particular importance for slurry bubble column FT. In the Italian eni's refinery of Sannazzaro, a 20 BPD slurry bubble column pilot plant has cumulated more than 20,000 hours time on stream in different campaigns. Non reactive slurry bubble columns corresponding to reactor capacities between 20 BPD and 1000 BPD permitted to determine the profiles for gas hold up and liquid velocities as a function of gas flow, catalyst loading, reactor diameter and internals. A hydrodynamic model based on those data led to design a Large Validation Tool, which can reproduce under reaction conditions a high mechanical stress on the catalyst equivalent to the one experienced in an industrial 15000 BPD reactor. While those tools have proven to be efficient for developing an industrial scale FT catalyst [3], they predict today in a representative manner fines formation, activity and selectivity of improved catalysts and / or for optimization of operation conditions to increase the capacity per train. We compare the here presented approach to others. We have found that it is mandatory to combine chemical stress from the reaction products with mechanical stress as experienced in an industrial slurry bubble column, in order to evaluate in a reliable way catalyst performance stability and fines formation. The potential of improvements are discussed. (orig.)

  6. Incorporation of catalytic dehydrogenation into fischer-tropsch synthesis to significantly reduce carbon dioxide emissions

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, Gerald P.

    2012-11-13

    A new method of producing liquid transportation fuels from coal and other hydrocarbons that significantly reduces carbon dioxide emissions by combining Fischer-Tropsch synthesis with catalytic dehydrogenation is claimed. Catalytic dehydrogenation (CDH) of the gaseous products (C1-C4) of Fischer-Tropsch synthesis (FTS) can produce large quantities of hydrogen while converting the carbon to multi-walled carbon nanotubes (MWCNT). Incorporation of CDH into a FTS-CDH plant converting coal to liquid fuels can eliminate all or most of the CO.sub.2 emissions from the water-gas shift (WGS) reaction that is currently used to elevate the H.sub.2 level of coal-derived syngas for FTS. Additionally, the FTS-CDH process saves large amounts of water used by the WGS reaction and produces a valuable by-product, MWCNT.

  7. Nitrogen isotope fractionations in the Fischer-Tropsch synthesis and in the Miller-Urey reaction

    Science.gov (United States)

    King, C.-C.; Clayton, R. N.; Hayatsu, R.; Studier, M. H.

    1979-01-01

    Nitrogen isotope fractionations have been measured in Fischer-Tropsch and Miller-Urey reactions in order to determine whether these processes can account for the large N-15/N-14 ratios found in organic matter in carbonaceous chondrites. Polymeric material formed in the Fischer-Tropsch reaction was enriched in N-15 by only 3 per mil relative to the starting material (NH3). The N-15 enrichment in polymers from the Miller-Urey reaction was 10-12 per mil. Both of these fractionations are small compared to the 80-90 per mil differences observed between enstatite chondrites and carbonaceous chondrites. These large differences are apparently due to temporal or spatial variations in the isotopic composition of nitrogen in the solar nebula, rather than to fractionation during the production of organic compounds.

  8. Nitrogen isotope fractionations in the Fischer-Tropsch synthesis and in the Miller-Urey reaction

    International Nuclear Information System (INIS)

    Nitrogen isotope fractionations have been measured in Fischer-Tropsch and Miller-Urey reactions in order to determine whether these processes can account for the large 15N/14N ratios found in organic matter in carbonaceous chondrites. Polymeric material formed in the Fischer-Tropsch reaction was enriched in 15N by only 3 promille relative to the starting material (NH3). The 15N enrichment in polymers from the Miller-Urey reaction was 10-12 promille. Both of these fractionations are small compared to the 80-90 promille differences observed between enstatite chondrites and carbonaceous chondrites. These large differences are apparently due to temporal or spatial variations in the isotopic composition of nitrogen in the solar nebula, rather than to fractionation during the production of organic compounds. (orig.)

  9. Deactivation and Regeneration of Commercial Type Fischer-Tropsch Co-Catalysts—A Mini-Review

    OpenAIRE

    Erling Rytter; Anders Holmen

    2015-01-01

    Deactivation of commercially relevant cobalt catalysts for Low Temperature Fischer-Tropsch (LTFT) synthesis is discussed with a focus on the two main long-term deactivation mechanisms proposed: Carbon deposits covering the catalytic surface and re-oxidation of the cobalt metal. There is a great variety in commercial, demonstration or pilot LTFT operations in terms of reactor systems employed, catalyst formulations and process conditions. Lack of sufficient data makes it difficult to correlat...

  10. On the Deactivation of Cobalt-based Fischer-Tropsch Catalysts

    OpenAIRE

    Cats, K.H.

    2016-01-01

    The Fischer-Tropsch Synthesis (FTS) process is an attractive way to obtain synthetic liquid fuel from alternative energy sources such as natural gas, coal or biomass. However, the deactivation of the catalyst, consisting of cobalt nanoparticles supported on TiO2, currently hampers the industrial application of the process. Despite many years of research, we still lack the fundamental insights into the mechanism of catalyst deactivation necessary to develop the next generation of FTS catalysts...

  11. Hydrocracking of Fischer-Tropsch Products. Optimization of Diesel and Naphtha Cuts

    OpenAIRE

    Teles, U.M.; F. A. N. Fernandes

    2008-01-01

    Hydrocracking of Fischer-Tropsch synthesis products consisting of a mixture of C4–C30 paraffins and olefins over a platinum/amorphous silica–alumina catalyst was analyzed and optimized. A mathematical model of a batch reactor used for hydrocarbon hydrocracking was developed and the process was studied from a modeling point of view based on the kinetics of a bifunctional catalyst. The influence of temperature on the product yield distribution was evaluated. Time and temperature optimization we...

  12. Kinetics of Slurry Phase Fischer-Tropsch Synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Dragomir B. Bukur; Gilbert F. Froment; Tomasz Olewski; Lech Nowicki; Madhav Nayapati

    2006-12-31

    The overall objective of this project is to develop a comprehensive kinetic model for slurry-phase Fischer-Tropsch synthesis (FTS) employing iron-based catalysts. This model will be validated with experimental data obtained in a stirred-tank slurry reactor (STSR) over a wide range of process conditions. Three STSR tests of the Ruhrchemie LP 33/81 catalyst were conducted to collect data on catalyst activity and selectivity under 25 different sets of process conditions. The observed decrease in 1-olefin content and increase in 2-olefin and n-paraffin contents with the increase in conversion are consistent with a concept that 1-olefins participate in secondary reactions (e.g. 1-olefin hydrogenation, isomerization and readsorption), whereas 2-olefins and n-paraffins are formed in these reactions. Carbon number product distribution showed an increase in chain growth probability with increase in chain length. Vapor-liquid equilibrium calculations were made to check validity of the assumption that the gas and liquid phases are in equilibrium during FTS in the STSR. Calculated vapor phase compositions were in excellent agreement with experimental values from the STSR under reaction conditions. Discrepancies between the calculated and experimental values for the liquid-phase composition (for some of the experimental data) are ascribed to experimental errors in the amount of wax collected from the reactor, and the relative amounts of hydrocarbon wax and Durasyn 164 oil (start-up fluid) in the liquid samples. Kinetic parameters of four kinetic models (Lox and Froment, 1993b; Yang et al., 2003; Van der Laan and Beenackers, 1998, 1999; and an extended kinetic model of Van der Laan and Beenackers) were estimated from experimental data in the STSR tests. Two of these kinetic models (Lox and Froment, 1993b; Yang et al., 2003) can predict a complete product distribution (inorganic species and hydrocarbons), whereas the kinetic model of Van der Laan and Beenackers (1998, 1999) can

  13. CHAIN-LIMITING OPERATION OF FISCHER-TROPSCH REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    Apostolos A. Nikolopoulos; Santosh K. Gangwal

    2003-06-01

    The use of pulsing in Fischer-Tropsch (FT) synthesis to limit the hydrocarbon chain growth and maximize the yield of diesel-range (C{sub 10}-C{sub 20}) products was examined on high-chain-growth-probability ({alpha} {ge} 0.9) FT catalysts. Pulsing experiments were conducted using a stainless-steel fixed-bed micro-reactor, equipped with both on-line (for the permanent gases and light hydrocarbons, C{sub 1}-C{sub 15}) and off-line (for the heavier hydrocarbons, C{sub 10}-C{sub 65}) gas chromatography analysis. Additional experiments were performed using a highly active attrition-resistant iron-based FT synthesis catalyst in a 1-liter continuous stirred-tank rector (CSTR). On both a Co-ZrO{sub 2}/SiO{sub 2} and a Co/Al{sub 2}O{sub 3} FT synthesis catalyst application of H{sub 2} pulsing causes significant increase in CO conversion, and only an instantaneous increase in undesirable selectivity to CH{sub 4}. Increasing the frequency of H{sub 2} pulsing enhances the selectivity to C{sub 10}-C{sub 20} compounds but the chain-growth probability {alpha} remains essentially unaffected. Increasing the duration of H{sub 2} pulsing results in enhancing the maximum obtained CO conversion and an instantaneous selectivity to CH{sub 4}. An optimum set of H{sub 2} pulse parameters (pulse frequency, pulse duration) is required for maximizing the yield of desirable diesel-range C{sub 10}-C{sub 20} products. Application of a suitable H{sub 2} pulse in the presence of added steam in the feed is a simple method to overcome the loss in activity and the shift in paraffin vs. olefin selectivity (increase in the olefin/paraffin ratio) caused by the excess steam. A decrease in syngas concentration has a strong suppressing effect on the olefin/paraffin ratio of the light hydrocarbon products. Higher syngas concentration can increase the chain growth probability {alpha} and thus allow for better evaluation of the effect of pulsing on FT synthesis. On a high-{alpha} Fe/K/Cu/SiO{sub 2} FT

  14. A chemical route to the formation of water in circumstellar envelopes around carbon-rich asymptotic branch stars: Fischer-Tropsch catalysis

    Science.gov (United States)

    Willacy, K.

    2004-01-01

    Fischer-Tropsch catalysis has been suggested as a means of driving hydrocarbon chemistry in oxygen rich regions such as the protosolar nebula. In addition to producing hydrocarbons, Fischer-Tropsch catalysis also produces water, and it is therefore possible that such processes could account for the recent observations of water in the circumstellar envelope of asymptotic giant branch star IRC +10216.

  15. Hydroprocessing of Fischer-Tropsch biowaxes to second-generation biofuels

    Energy Technology Data Exchange (ETDEWEB)

    Schablitzky, Harald Walter; Hafner, C. [OMV Refining and Marketing, Centre of Excellence-Fuels, Innovation and Quality, Schwechat (Austria); Lichtscheidl, J.; Hutter, K. [OMV Refining and Marketing, New Technology, Schwechat (Austria); Rauch, R. [Bioenergy, Graz (Austria); Hofbauer, H. [Bioenergy, Graz (Austria); Vienna University of Technology, Institute of Chemical Engineering, Vienna (Austria)

    2011-03-15

    Upgrading of Fischer-Tropsch (FT) biowaxes to second-generation biofuels via hydroprocessing is the final step for increasing the fuel amount of the overall biomass conversion route: gasification of lignocellulosic biomass, FT synthesis, and hydroprocessing. The typical FT product portfolio consists of high molecular weight paraffinic waxes as the main product and FT fuels in the diesel and naphtha boiling range. OMV's objective and contribution to the project focus on achieving coprocessing of FT biowaxes with fossil feedstock using existing hydrotreating plants of crude oil refineries. Various test runs have been examined with a conventional refining catalyst under mild conditions (380-390 C, 5.8 MPa; WHSV, 0.7-1.3 h{sup -1}) in a pilot plant. Pure FT biowax is converted to gases, fuels, and an oil/waxy residue in a fixed-bed reactor with a porous catalyst layer technology. The presence of hydrogen in the reaction chamber reduces the fast deactivation of the catalyst caused by the formation of a coke layer around the catalyst particle surface and saturates cracked hydrocarbon fragments. Another approach is the creation of synthetic biodiesel components with excellent fuel properties for premium fuel application. Basically, premium diesel fuel differs from standard diesel quality by cetane number and cold flow properties. Hydroprocessed synthetic biodiesel (HPFT diesel) has compared to conventional diesel advantages in many aspects. Depending on the catalyst selected, premium diesel quality can be obtained by shifting cold flow operability properties of HPFT fuels to a range capable even under extreme cold conditions. In addition, a high-quality kerosene fraction is obtained to create bio jet fuels with an extremely deep freezing point, as low as -80 C. The isomerization degree, as well as the carbon number distribution of high paraffinic profile, and the branching degree have a major impact on the cold flow properties and cetane number. FT diesel has

  16. Study on the Precursor Phase Composition of Fused Iron Catalyst for Fischer-Tropsch Synthesis

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    The effect of the precursor composition of fused iron catalyst on the performance of Fischer-Tropsch synthesis was investigated. XRD, BET and CO2 adsorption experiments were carried out to provide better insight into the relationship therein. The results showed that the selectivity of C5+ hydrocarbon products was dependent on the mole ratio of Fe2+/Fe3+, which was represented by a hump-shaped curve. Catalysts with precursors containing Fe3O4 phase favored the magnetite spinal formation during F-T reaction, while Fe1-xO-based catalysts were more likely to favor the formation and growth of the iron carbide crystals.

  17. Structural framework of a medium Fischer-Tropsch wax fraction determined by electron crystallography

    Science.gov (United States)

    Dorset, Douglas L.; Basson, Ilsa

    2000-10-01

    The structural framework of a medium hardness Fischer-Tropsch wax distillate is established quantitatively by electron crystallography and compared to model paraffin assemblies with a similar Gaussian distribution of chain lengths. The lamellar packing closely resembles the crystal structure of refined petroleum waxes with a similar distribution of defects near the lamellar interface. Nevertheless, clear differences associated with the absorption of smaller chains within the lamellar interface, detected by NMR, are not resolved by these diffraction measurements, perhaps due to artefacts induced by the high vacuum of the experiment and/or specimen preparation.

  18. Synthetic production of fuels by the Fischer Tropsch reaction using iron catalysts

    International Nuclear Information System (INIS)

    A series of iron catalysts were prepared on three different types of supports: alumina and two activated carbons from eucalyptus woods and tagua seeds. Potassium was used as promoter and palladium was deposited by the excess wetness impregnation method. The catalysts were characterized by N2 adsorption at 77 K, XRD and TPR analysis and evaluated as Fischer-Tropsch catalysts. The carbon supported catalysts favour the production of liquid hydrocarbons and decrease the aqueous phase. Those supported with alumina form gases and aqueous phase as the main products. The αp parameters of the Schulz-Flory distribution show hydrocarbons between gasoline and diesel

  19. Insight on Biomass Supply and Feedstock Definition for Fischer-Tropsch Based BTL Processes

    International Nuclear Information System (INIS)

    Process chains of thermo chemical conversion of lignocellulosic biomass through gasification and Fischer-Tropsch synthesis (known as BTL) represent promising alternatives for biofuels production. Since biomass is heterogeneous and not homogeneously spread over territories, one of the major technological stakes of the project is to develop a flexible industrial chain capable of co-treating the widest possible range of biomass and fossil fuel feedstock. The present study aims at characterizing biomass diversity (availability and potentials by area, cost and mineral composition) by carrying out a state of the art, as a preliminary step in order to define a series of biomass to be tested in the demonstration plant and therefore define specifications for the process. Fifty different biomass were considered for their bio-energy application potential and were finally classified into four categories: agricultural by-products, dedicated energy crops, (Very) Short Rotation Coppice ((V)SRC) and forestry biomass. Biomass availability and potentials were investigated by the mean of a literature review of past and current projects (e.g. RENEW project, Biomass Energy Europe Project, etc.) and scientific articles. Most collected data are technical potentials, meaning that they take into account biophysical limits of crops and forests, technological possibilities, competition with other land uses and ecological constraints (e.g. natural reserves). Results show various emerging markets: North and South America have considerable amounts of agricultural by-products, forest residues, and large land areas which could be dedicated to energy crops; Africa shows relevant possibilities to grow Short Rotation Forestry (SRF) and energy crops; Russia has large available quantities of agricultural by-products and forest residues, as well as little valuable land where energy crops and SRC could be grown, and Asia shows relevant amounts of forest residues and possibilities of growing SRC, as well

  20. Fischer-Tropsch diesel production in a well-to-wheel perspective: A carbon, energy flow and cost analysis

    Energy Technology Data Exchange (ETDEWEB)

    Vliet, Oscar P.R. van [University Utrecht, Copernicus Institute, Science, Technology and Society Group, Heidelberglaan 2, 3584 CS Utrecht (Netherlands)], E-mail: o.p.r.vanvliet@uu.nl; Faaij, Andre P.C.; Turkenburg, Wim C. [University Utrecht, Copernicus Institute, Science, Technology and Society Group, Heidelberglaan 2, 3584 CS Utrecht (Netherlands)

    2009-04-15

    We calculated carbon and energy balances and costs of 14 different Fischer-Tropsch (FT) fuel production plants in 17 complete well-to-wheel (WTW) chains. The FT plants can use natural gas, coal, biomass or mixtures as feedstock. Technical data, and technological and economic assumptions for developments for 2020 were derived from the literature, recalculating to 2005 euros for (capital) costs. Our best-guess WTW estimates indicate BTL production costs break even when oil prices rise above $75/bbl, CTL above $60/bbl and GTL at $36/bbl. CTL, and GTL without carbon capture and storage (CCS), will emit more CO{sub 2} than diesel from conventional oil. Driving on fuel from GTL with CCS may reduce GHG emissions to around 123 g CO{sub 2}/km. Driving on BTL may cause emissions of 32-63 g CO{sub 2}/km and these can be made negative by application of CCS. It is possible to have net climate neutral driving by combining fuels produced from fossil resources with around 50% BTL with CCS, if biomass gasification and CCS can be made to work on an industrial scale and the feedstock is obtained in a climate-neutral manner. However, the uncertainties in these numbers are in the order of tens of percents, due to uncertainty in the data for component costs, variability in prices of feedstocks and by-products, and the GHG impact of producing biomass.

  1. Fischer-Tropsch diesel production in a well-to-wheel perspective: A carbon, energy flow and cost analysis

    International Nuclear Information System (INIS)

    We calculated carbon and energy balances and costs of 14 different Fischer-Tropsch (FT) fuel production plants in 17 complete well-to-wheel (WTW) chains. The FT plants can use natural gas, coal, biomass or mixtures as feedstock. Technical data, and technological and economic assumptions for developments for 2020 were derived from the literature, recalculating to 2005 euros for (capital) costs. Our best-guess WTW estimates indicate BTL production costs break even when oil prices rise above $75/bbl, CTL above $60/bbl and GTL at $36/bbl. CTL, and GTL without carbon capture and storage (CCS), will emit more CO2 than diesel from conventional oil. Driving on fuel from GTL with CCS may reduce GHG emissions to around 123 g CO2/km. Driving on BTL may cause emissions of 32-63 g CO2/km and these can be made negative by application of CCS. It is possible to have net climate neutral driving by combining fuels produced from fossil resources with around 50% BTL with CCS, if biomass gasification and CCS can be made to work on an industrial scale and the feedstock is obtained in a climate-neutral manner. However, the uncertainties in these numbers are in the order of tens of percents, due to uncertainty in the data for component costs, variability in prices of feedstocks and by-products, and the GHG impact of producing biomass. (author)

  2. Fischer-Tropsch diesel production in a well-to-wheel perspective: A carbon, energy flow and cost analysis

    Energy Technology Data Exchange (ETDEWEB)

    van Vliet, Oscar P.R.; Faaij, Andre P.C.; Turkenburg, Wim C. [University Utrecht, Copernicus Institute, Science, Technology and Society Group, Heidelberglaan 2, 3584 CS Utrecht (Netherlands)

    2009-04-15

    We calculated carbon and energy balances and costs of 14 different Fischer-Tropsch (FT) fuel production plants in 17 complete well-to-wheel (WTW) chains. The FT plants can use natural gas, coal, biomass or mixtures as feedstock. Technical data, and technological and economic assumptions for developments for 2020 were derived from the literature, recalculating to 2005 euros for (capital) costs. Our best-guess WTW estimates indicate BTL production costs break even when oil prices rise above $75/bbl, CTL above $60/bbl and GTL at $36/bbl. CTL, and GTL without carbon capture and storage (CCS), will emit more CO{sub 2} than diesel from conventional oil. Driving on fuel from GTL with CCS may reduce GHG emissions to around 123 g CO{sub 2}/km. Driving on BTL may cause emissions of 32-63 g CO{sub 2}/km and these can be made negative by application of CCS. It is possible to have net climate neutral driving by combining fuels produced from fossil resources with around 50% BTL with CCS, if biomass gasification and CCS can be made to work on an industrial scale and the feedstock is obtained in a climate-neutral manner. However, the uncertainties in these numbers are in the order of tens of percents, due to uncertainty in the data for component costs, variability in prices of feedstocks and by-products, and the GHG impact of producing biomass. (author)

  3. Co-Zn-Al based hydrotalcites as catalysts for Fischer-Tropsch process

    Energy Technology Data Exchange (ETDEWEB)

    Bianchi, C.L.; Pirola, C.; Boffito, D.C.; Di Fronzo, A. [Univ. degli Studi di Milano (Italy). Dipt. di Chimica Fisica ed Elettrochimica; Di Michele, A. [Univ. degli Studi di Perugia (Italy). Dipt. di Fisica; Vivani, R.; Nocchetti, M.; Bastianini, M.; Gatto, S. [Univ. degli Studi di Perugia (Italy). Dipt. di Chimica

    2011-07-01

    Co-Zn-Al based hydrotalcites have been investigated as catalysts for the well-known Fischer- Tropsch synthesis. A series of ternary hydrotalcites in nitrate form was prepared with the urea method in order to obtain active catalysts for the above mentioned process. The thermal activation at 350 C gives raise to finely dispersed metallic Co on the mixed oxides, so resulting in retaining the metal distribution of the parent compounds. An optimization study concerning the amount of cobalt of the prepared catalysts (range 15-70% mol, metal based) and the reaction temperature (220-260 C) is reported. All the samples have been fully characterized (BET, ICP-OES, XRPD, TG-DTA, FT-IR, SEM and TEM) and tested in a laboratory pilot plant. Tests to evaluate the stability of these materials were carried out in stressed conditions concerning both the activation and the operating temperatures and pressures (up to 350 C and 2.0 MPa). The obtained results suggest the possibility of using synthetic hydrotalcites as suitable Co-based catalysts for the Fischer-Tropsch synthesis. (orig.)

  4. Cerium Modified Pillared Montmorillonite Supported Cobalt Catalysts for Fischer Tropsch Synthesis

    International Nuclear Information System (INIS)

    Fischer-Tropsch (FT) synthesis was accomplished over Al-pillared Montmorillonite supported 20 wt% Co modified with different weight% of cerium catalysts. These catalysts were prepared by impregnation method while structural characterizations of the prepared samples were performed by XRD, TPR, NH/sub 3/TPD, TGA, BET, XRF and SEM techniques. The Fischer Tropsch reaction was studied in fixed bed micro catalytic reactor at temperature range of 220, 260 and 275 degree C and at different pressure (1, 5 and 10 bars). From the activity results, it was found that by pillaring NaMMT with Al higher catalytic activity and lower methane selectivity of NaMMT was achieved. Furthermore, the results of FT synthesis reaction revealed that cerium incorporation increased the dispersion of Co/sub 3/O/sub 4/ on the surface and consequently resulted in enhanced catalytic activity. Additionally, the C/sub 5/-C/sub 12/ hydrocarbons and methane selectivity increased while C/sub 22+/ hydrocarbons selectivity was decreased over cerium modified catalysts. Higher reaction temperature (>220 degree C) resulted in significant enhancement in CO conversion and methane selectivity. Though, increase in pressure from 1 to 10 bars eventually resulted in increase in C/sub 5+/ hydrocarbons and decrease in methane and C/sub 2/-C/sub 5/ hydrocarbons selectivity. (author)

  5. Large-scale production of Fischer-Tropsch diesel from biomass. Optimal gasification and gas cleaning systems

    International Nuclear Information System (INIS)

    The paper is presented in the form of copies of overhead sheets. The contents concern definitions, an overview of Integrated biomass gasification and Fischer Tropsch (FT) systems (state-of-the-art, gas cleaning and biosyngas production, experimental demonstration and conclusions), some aspects of large-scale systems (motivation, biomass import) and an outlook

  6. 40 CFR 721.10103 - Naphtha (Fischer-Tropsch), C4-11-alkane, branched and linear.

    Science.gov (United States)

    2010-07-01

    ...-alkane, branched and linear. 721.10103 Section 721.10103 Protection of Environment ENVIRONMENTAL..., branched and linear. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified as naphtha (fischer-tropsch), C4-11-alkane, branched and linear (PMN P-04-235; CAS...

  7. The role of zeolites in the deactivation of multifunctional Fischer-Tropsch Synthesis catalysts: the interaction between HZSM-5 and Fe-based FT-catalysts

    International Nuclear Information System (INIS)

    In order to produce gasoline directly from syngas, HZSM-5 can be added to the Fischer-Tropsch catalyst. However, this catalytic system shows an important deactivation rate. Aiming at describing this phenomenon, Fe-based catalysts and physical mixtures containing these catalysts and HZSM-5 were employed in this reaction. All these systems were characterized using the following techniques: XRD, XPS, TPR and TPD of CO. This work shows that HZSM-5 interacts with the Fe-based Fischer-Tropsch catalyst during the reduction step, decreasing the Fe concentration on the catalytic surface and thus lowering the activity of the catalytic system in the Fischer-Tropsch Synthesis. (author)

  8. The role of zeolites in the deactivation of multifunctional fischer-tropsch synthesis catalysts: the interaction between HZSM-5 and Fe-based Ft-catalysts

    Directory of Open Access Journals (Sweden)

    P. C. Zonetti

    2013-12-01

    Full Text Available In order to produce gasoline directly from syngas, HZSM-5 can be added to the Fischer-Tropsch catalyst. However, this catalytic system shows an important deactivation rate. Aiming at describing this phenomenon, Fe-based catalysts and physical mixtures containing these catalysts and HZSM-5 were employed in this reaction. All these systems were characterized using the following techniques: XRD, XPS, TPR and TPD of CO. This work shows that HZSM-5 interacts with the Fe-based Fischer-Tropsch catalyst during the reduction step, decreasing the Fe concentration on the catalytic surface and thus lowering the activity of the catalytic system in the Fischer-Tropsch Synthesis.

  9. The role of zeolites in the deactivation of multifunctional Fischer-Tropsch Synthesis catalysts: the interaction between HZSM-5 and Fe-based FT-catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Zonetti, P.C.; Gaspar, A.B.; Mendes, F.M.T.; Appel, L.G., E-mail: lucia.appel@int.gov.br [Instituto Nacional de Tecnologia (INT/MCT), Rio de Janeiro, RJ (Brazil); Avillez, R. R. de [Pontificia Universidade Catolica do Rio de Janeiro (PUC-Rio), RJ (Brazil); Sousa-Aguiar, E.F. [Centro de Pesquisa Leopoldo Americo Miguez de Mello (CENPES/PETROBRAS), Rio de Janeiro, RJ (Brazil)

    2013-10-15

    In order to produce gasoline directly from syngas, HZSM-5 can be added to the Fischer-Tropsch catalyst. However, this catalytic system shows an important deactivation rate. Aiming at describing this phenomenon, Fe-based catalysts and physical mixtures containing these catalysts and HZSM-5 were employed in this reaction. All these systems were characterized using the following techniques: XRD, XPS, TPR and TPD of CO. This work shows that HZSM-5 interacts with the Fe-based Fischer-Tropsch catalyst during the reduction step, decreasing the Fe concentration on the catalytic surface and thus lowering the activity of the catalytic system in the Fischer-Tropsch Synthesis. (author)

  10. Wabash Valley Integrated Gasification Combined Cycle, Coal to Fischer Tropsch Jet Fuel Conversion Study

    Energy Technology Data Exchange (ETDEWEB)

    Shah, Jayesh [Lummus Technology Inc., Bloomfield, NJ (United States); Hess, Fernando [Lummus Technology Inc., Bloomfield, NJ (United States); Horzen, Wessel van [Lummus Technology Inc., Bloomfield, NJ (United States); Williams, Daniel [Lummus Technology Inc., Bloomfield, NJ (United States); Peevor, Andy [JM Davy, London (United Kingdom); Dyer, Andy [JM Davy, London (United Kingdom); Frankel, Louis [Canonsburgh, PA (United States)

    2016-06-01

    This reports examines the feasibility of converting the existing Wabash Integrated Gasification Combined Cycle (IGCC) plant into a liquid fuel facility, with the goal of maximizing jet fuel production. The fuels produced are required to be in compliance with Section 526 of the Energy Independence and Security Act of 2007 (EISA 2007 §526) lifecycle greenhouse gas (GHG) emissions requirements, so lifecycle GHG emissions from the fuel must be equal to or better than conventional fuels. Retrofitting an existing gasification facility reduces the technical risk and capital costs associated with a coal to liquids project, leading to a higher probability of implementation and more competitive liquid fuel prices. The existing combustion turbine will continue to operate on low cost natural gas and low carbon fuel gas from the gasification facility. The gasification technology utilized at Wabash is the E-Gas™ Technology and has been in commercial operation since 1995. In order to minimize capital costs, the study maximizes reuse of existing equipment with minimal modifications. Plant data and process models were used to develop process data for downstream units. Process modeling was utilized for the syngas conditioning, acid gas removal, CO2 compression and utility units. Syngas conversion to Fischer Tropsch (FT) liquids and upgrading of the liquids was modeled and designed by Johnson Matthey Davy Technologies (JM Davy). In order to maintain the GHG emission profile below that of conventional fuels, the CO2 from the process must be captured and exported for sequestration or enhanced oil recovery. In addition the power utilized for the plant’s auxiliary loads had to be supplied by a low carbon fuel source. Since the process produces a fuel gas with sufficient energy content to power the plant’s loads, this fuel gas was converted to hydrogen and exported to the existing gas turbine for low carbon power production. Utilizing low carbon fuel gas and

  11. The role of electrophilic species in the Fischer-Tropsch reaction.

    Science.gov (United States)

    Maitlis, Peter M; Zanotti, Valerio

    2009-04-01

    The heterogeneously catalysed Fischer-Tropsch (FT) synthesis converts syngas (CO+H2) into long chain hydrocarbons and is a key step in the economically important transformation of natural gas, coal, or biomass into liquid fuels, such as diesel. Catalyst surface studies indicate that the FT reaction starts when CO is activated at imperfections on the surfaces of late transition metals (Fe, Ru, Co, or Rh) and at interfaces with "islands" of promoters (Lewis acid oxides such as alumina or titania). Activation involves CO cleavage to generate a surface carbide, C(ad), which is sequentially hydrogenated to CHx(ad) species (x=1-4). An overview of practical aspects of the FT synthesis is followed by a discussion of the chief mechanisms that have been proposed for the formation of 1-alkenes by polymerisation of surface C1 species. These mechanisms have traditionally postulated rather non-polar intermediates, such as CH2(ad) and CH3(ad). However, electrophiles and nucleophiles are well-known to play key roles in the reactions of organic and organometallic compounds, and also in many reactions homogeneously catalysed by soluble metal complexes, including olefin polymerisation. We have now extended these concepts to the Fischer-Tropsch reaction, and show that the polymerisation reactions at polarising surfaces, such as oxide-metal interfaces, can be understood if the reactive chain carrier is an electrophilic species, such as the cationic methylidyne, CH(delta+)(ad). It is proposed that the key coupling step in C-C bond formation involves the interaction of the electrophilic methylidyne with an alkylidene (RCH(ad), R=H, alkyl), followed by an H-transfer to generate the homologous alkylidene: CHdelta+(ad)+RCH(ad)-->RCHCH(ad) and RCHCH(ad)+H(ad)-->RCH2CH(ad). If the reactions occur on non-polarising surfaces, an alternative C-C bond forming reaction such as the alkenyl+methylene, RCH=CH(ad)+CH2(ad)-->RCH=CHCH2(ad), can take place. This approach explains important aspects of the

  12. Metal organic framework-mediated synthesis of highly active and stable Fischer-Tropsch catalysts.

    Science.gov (United States)

    Santos, Vera P; Wezendonk, Tim A; Jaén, Juan José Delgado; Dugulan, A Iulian; Nasalevich, Maxim A; Islam, Husn-Ubayda; Chojecki, Adam; Sartipi, Sina; Sun, Xiaohui; Hakeem, Abrar A; Koeken, Ard C J; Ruitenbeek, Matthijs; Davidian, Thomas; Meima, Garry R; Sankar, Gopinathan; Kapteijn, Freek; Makkee, Michiel; Gascon, Jorge

    2015-01-01

    Depletion of crude oil resources and environmental concerns have driven a worldwide research on alternative processes for the production of commodity chemicals. Fischer-Tropsch synthesis is a process for flexible production of key chemicals from synthesis gas originating from non-petroleum-based sources. Although the use of iron-based catalysts would be preferred over the widely used cobalt, manufacturing methods that prevent their fast deactivation because of sintering, carbon deposition and phase changes have proven challenging. Here we present a strategy to produce highly dispersed iron carbides embedded in a matrix of porous carbon. Very high iron loadings (>40 wt %) are achieved while maintaining an optimal dispersion of the active iron carbide phase when a metal organic framework is used as catalyst precursor. The unique iron spatial confinement and the absence of large iron particles in the obtained solids minimize catalyst deactivation, resulting in high active and stable operation. PMID:25740709

  13. Development of niobium-promoted cobalt catalysts on carbon nanotubes for Fischer-Tropsch synthesis

    Institute of Scientific and Technical Information of China (English)

    Sardar Ali; Noor Asmawati Mohd Zabidi; Duvvuri Subbarao

    2011-01-01

    Cobalt-based catalysts were prepared by a wet impregnation method on carbon nanotubes (CNTs) support and promoted with niobium.Samples were characterized by nitrogen adsorption,TEM,XRD,TPR,TPO and H2-TPD.Addition of niobium increased the dispersion of cobalt but decreased the catalysts reducibility.Fischer-Tropsch synthesis (FTS) was carried out in a fixed-bed microreactor at 543 K,1 atm and H2/CO =2 for 5 h.Addition of niobium enhanced the C5+ hydrocarbons selectivity by 39% and reduced methane selectivity by 59%.These effects were more pronounced for 0.04%Nb/Co/CNTs catalyst,compared with those observed for other niobium compositions.

  14. Alkali promotion effect in Fischer-Tropsch cobalt-alumina catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Eliseev, O.L.; Tsapkina, M.V.; Davydov, P.E.; Kazantsev, R.V. [Russian Academy of Sciences, Moscow (Russian Federation). N.D. Zelinsky Inst. of Organic Chemistry; Belousova, O.S.; Lapidus, A.L. [Gubkin Russian State Univ. of Oil and Gas, Moscow (Russian Federation)

    2011-07-01

    Promoting Co-alumina Fischer-Tropsch synthesis catalysts with alkali and alkaline-earth metals was studied. XRD, oxygen titration and CO chemisorption were used for the characterization of the catalysts. The best results in terms of catalyst selectivity and long-chain alkanes content in synthesized products were obtained with K-promoted catalyst. Catalytic performance strongly depends on K:Co atomic ratio as well as preparation procedure. Effect of K loading on selectivities is non-linear with extreme point at K:Co=0.01. Significant increase in C{sub 5+} selectivity of K-promoted catalyst may be explained as a result of strong CO adsorption on the catalyst surface, as was confirmed in CO chemisorption experiments. (orig.)

  15. Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles

    Energy Technology Data Exchange (ETDEWEB)

    Amitava Sarkar; James K. Neathery; Burtron H. Davis

    2006-12-31

    A fundamental filtration study was started to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. Slurry-phase FTS in slurry bubble column reactor systems is the preferred mode of operation since the reaction is highly exothermic. Consequently, heavy wax products in one approach may be separated from catalyst particles before being removed from the reactor system. Achieving an efficient wax product separation from iron-based catalysts is one of the most challenging technical problems associated with slurry-phase iron-based FTS and is a key factor for optimizing operating costs. The separation problem is further compounded by attrition of iron catalyst particles and the formation of ultra-fine particles.

  16. Optimisation of the Fischer-Tropsch process using zeolites for tail gas separation.

    Science.gov (United States)

    Perez-Carbajo, J; Gómez-Álvarez, P; Bueno-Perez, R; Merkling, P J; Calero, S

    2014-03-28

    This work is aimed at optimizing a Fischer-Tropsch Gas To Liquid (GTL) process by recycling compounds of the expelled gas mixture using zeolites for the separation. To that end, we have performed a computational study on four structures widely used in industry. A range of Si/Al ratios have been explored and the effects of their distribution assessed. The ability of the considered force fields and molecular models to reproduce experimental results has been widely proved in previously reported studies. Since this tail gas is formed by a five-component mixture, namely carbon dioxide, methane, carbon monoxide, nitrogen and hydrogen, molecular simulations present clear advantages over experiments. In addition, the viability of the Ideal Adsorption Solution Theory (IAST) has been evaluated to easily handle further separation steps. On the basis of the obtained results, we provide a separation scheme to perform sequentially the separation of CO2, CH4, CO, N2 and H2. PMID:24522290

  17. Preparation of Fischer-Tropsch catalysts from cobalt/iron hydrotalcites

    Energy Technology Data Exchange (ETDEWEB)

    Howard, B.H.; Boff, J.J.; Zarochak, M.F. [Pittsburgh Energy Technology Center, PA (United States)] [and others

    1995-12-31

    Compounds with the (hydrotalcites) have properties that make them attractive as precursors for Fischer-Tropsch catalysts. A series of single-phase hydrotalcites with cobalt/iron atom ratios ranging from 75/25 to 25/75 has been synthesized. Mixed cobalt/iron oxides have been prepared from these hydrotalcites by controlled thermal decomposition. Thermal decomposition at temperatures below 600 {degrees}C typically produced a single-phase mixed metal oxide with a spinel structure. The BET surface areas of the spinal samples have been found to be as high as about 150 m{sup 2}/g. Appropriate reducing pretreatments have been developed for several of these spinels and their activity, selectivity, and activity and selectivity maintenance have been examined at 13 MPa in a fixed-bed microreactor.

  18. Study on iron-manganese catalysts for Fischer-Tropsch synthesis

    Institute of Scientific and Technical Information of China (English)

    MOSTAFA FEYZI; FATANEH JAFARI

    2012-01-01

    Iron-manganese catalysts were prepared by co-precipitation method.Characterization of catalysts was carried out by using X-ray diffraction (XRD),scanning electron microscopy (SEM),temperature program reduction (TPR),N2 adsorptiondesorption measurements.The results from catalytic performance tests in Fischer-Tropsch synthesis showed that the iron-manganese catalysts are supersensitive to catalyst composition and materials source.It was found that C2~4 light olefins increased while CH4 and CO2 decreased by using iron-manganese catalyst prepared from iron (Ⅱ) sulfate (A catalyst).The activity and selectivity of A catalyst was studied in different operational conditions.The results showed that the best operational conditions for C2~4 light olefins production were H2/CO=1/1 (GHSV=2 400 h-1) at 260 ℃ under 0.3 MPa total pressure.

  19. Immobilised carbon nanotubes as carrier for Co-Fischer-Tropsch synthesis catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Thiessen, J.; Rose, A.; Kiendl, I.; Jess, A. [Bayreuth Univ. (Germany). Dept. of Chemical Engineering; Curulla-Ferre, D. [Total S.A., Gas and Power, Paris La Defense (France)

    2011-07-01

    A possibility to immobilise carbon nanotubes (CNT) to make them applicable in a technical scale fixed bed reactor is studied. The approach to fabricate millimetre scale composites containing CNT presented in this work is to confine the nano-carbon in macro porous ceramic particles. Thus CNT were grown on the inner surface of silica and alumina pellets and spheres, respectively. Cobalt nano particles were successfully deposited on the carbon surface inside the two types of ceramic carriers and the systems were tested in Fischer - Tropsch synthesis (FTS). The cobalt mass related activity of these novel catalysts is similar to a conventional system. The selectivities of the Co/CNT/ceramic composites were compared with non supported CNT and carbon nanofibres (CNF). (orig.)

  20. Emissions from Diesel and Gasoline Vehicles Fuelled by Fischer-Tropsch Fuels and Similar Fuels

    DEFF Research Database (Denmark)

    Larsen, Ulrik; Lundorff, Peter; Ivarsson, Anders;

    2007-01-01

    vehicles fuelled by Fischer Tropsch (FT) based diesel and gasoline fuel, compared to the emissions from ordinary diesel and gasoline. The comparison for diesel fuels was based on a literature review, whereas the gasoline comparison had to be based on our own experiments, since almost no references were...... found in this field. In this context measurement according to the Federal Test Procedure (FTP) and the New European Driving Cycle (NEDC) were carried out on a chassis dynamometer with a directly injected gasoline vehicle. Experiments were carried out with a reference fuel, a fuel based 70% on FT and an...... alkylate fuel (Aspen), which was taken to be the ultimate formula of FT gasoline. FT based diesel generally showed good emission performance, whereas the FT based gasoline not necessary lead to lower emissions. On the other hand, the Aspen fuel did show many advantages for the emissions from the gasoline...

  1. Carbon Isotopic Fractionation in Fischer-Tropsch Type Reactions and Relevance to Meteorite Organics

    Science.gov (United States)

    Johnson, Natasha M; Elsila, Jamie E.; Kopstein, Mickey; Nuth, Joseph A., III

    2012-01-01

    Fischer-Tropsch-Type (FTT) reactions have been hypothesized to contribute to the formation of organic compounds in the early solar system, but it has been difficult to identify a signature of such reactions in meteoritic organics. The work reported here examined whether temperature-dependent carbon isotopic fractionation of FTT reactions might provide such a signature. Analyses of bulk organic deposits resulting from FTT experiments show a slight trend towards lighter carbon isotopic ratios with increasing temperature. It is unlikely, however, that these carbon isotopic signatures could provide definitive provenance for organic compounds in solar system materials produced through FTT reactions, because of the small scale of the observed fractionations and the possibility that signatures from many different temperatures may be present in any specific grain.

  2. Modeling of Fischer-Tropsch Synthesis in a Slurry Reactor with Water Permeable Membrane

    Institute of Scientific and Technical Information of China (English)

    Fabiano A. N. Fernandes

    2007-01-01

    Fischer-Tropsch synthesis is an important chemical process for the production of liquid fuels and olefins. In recent years, the abundant availability of natural gas and the increasing demand of olefins, diesel, and waxes have led to a high interest to further develop this process. A mathematical model of a slurry membrane reactor used for syngas polymerization was developed to simulate and compare the maximum yields and operating conditions in the reactor with that in a conventional slurry reactor.The carbon polymerization was studied from a modeling point of view in a slurry reactor with a water permeable membrane and a conventional slurry reactor. Simulation results show that different parameters affect syngas conversion and carbon product distribution, such as the hydrogen to carbon monoxide ratio,and the membrane parameters such as membrane permeance.

  3. Particle size effects in Fischer-Tropsch synthesis by Co catalyst supported on carbon nanotubes

    Institute of Scientific and Technical Information of China (English)

    Ali Nakhaei Pour; Elham Hosaini; Mohammad Izadyar; Mohammad Reza Housaindokht

    2015-01-01

    The effect of Co particle size on the Fischer-Tropsch synthesis (FTS) activity of carbon nanotube (CNT)-supported Co catalysts was investigated. Microemulsion (using water-to-surfactant molar ratios of 2 to12) and impregnation techniques were used to prepare catalysts with different Co particle sizes. Kinetic studies were performed to understand the effect of Co particle size on catalytic activity. Size-dependent kinetic parameters were developed using a thermodynamic method, to evaluate the structural sensitivity of the CNT-supported Co catalysts. The size-independent FTS reaction rate constant and size-independent adsorption parameter increased with increasing reac-tion temperature. The Polani parameter also depended on catalyst particle size, because of changes in the catalyst surface coverage.

  4. Characterization of waxes derived from Fischer-Tropsch reactors: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Sturm, G.P. Jr.; Anderson, R.P.; Grigsby, R.D.; Vogh, J.W.; Doughty, D.A.

    1988-12-01

    Methods are described for improved characterization of Fischer-Tropsch (f-T) waxes. With these methods, detailed composition of F-T waxes can be determined, which may lead to improved understanding of the Fischer-Tropsch process and of the processing required to upgrade the waxes into higher value products. The characterization involved separation of the wax into neutral and polar fractions using high performance liquid chromatography on wide port silica with 1.0% (volume) n-propanol in heptane as eluant at 60(degree) to 80(degree)C. the neutral fraction was further spearted into alkanes and alkenes using a silver-loaded, sulfonic-acid-boned silica column with 0.5 to 2.0% (volume) toluene in heptane as eluant at 60(degree) to 80(degree)C. the whole wax and separated fractions were analyzed by infrared, nuclear magnetic resonance, and mass spectrometry. Sample introduction in the mass spectrometry experiments was by probe microdistillation. Results indicated good spearation with some very minor amounts of cycloparfin and virtually no oxygenated compounds in the alkane fraction. The alkene fraction contained mostly alkenes with small amounts of alkanes or oxygen compound and dioxygen compounds (C/sub n/H/sub 2n/O/sub 2/), probably esters or unsaturated diethers. Modifications to and extension of several computer programs made in the course of this study are described in an appendix. this computer software significantly decreased the time and effort involved in processing and interpreting the vast quantity of data acquired in the probe microdistillation mass spectral analysis of the F-T waxes and spearted fractions. 19 refs., 25 figs., 6 tabs.

  5. Isotopic tracer studies of Fischer-Tropsch Synthesis over Ru/TiO sub 2 catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Krishna, K.R.

    1992-01-01

    Fischer-Tropsch synthesis is a process in which CO and H{sub 2} react to give predominantly liquid hydrocarbons. The reaction can be considered a special type of polymerization in which the monomer is produced in situ, and chain growth occurs by a sequence of independently repeated additions of the monomer to the growing chain. A investigation has been conducted to study the CO hydrogenation reaction in order to better understand catalyst deactivation and the elementary surface processes involved in chain growth. Isotopic tracers are used in conjunction with transient-response techniques in this study of Fischer-Tropsch synthesis over Ru/TiO{sub 2} catalysts. Experiments are conducted at a total pressure of 1 atmosphere, reaction temperatures of 453--498 K and D{sub 2}/CO (or H{sub 2}/CO) ratios of 2--5. Synthesis products are analyzed by gas chromatography or isotope-ratio gas chromatography-mass spectrometry. Rate constants for chain initiation, propagation and termination are evaluated under steady-state reaction conditions by using transients in isotopic composition. The activation energy for chain termination is much higher than that for propagation, accounting for the observed decrease in the chain growth parameter are also estimated. Coverages by reaction intermediates are also estimated. When small amounts of {sup 12}C-labelled ethylene are added to {sup 13}CO/H{sub 2} synthesis gas, ethylene acts as the sole chain initiator. Ethylene-derived carbon also accounts for 45% of the C{sub 1} monomer pool. 102 refs., 29 figs., 11 tabs.

  6. Isotopic tracer studies of Fischer-Tropsch Synthesis over Ru/TiO{sub 2} catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Krishna, K.R.

    1992-01-01

    Fischer-Tropsch synthesis is a process in which CO and H{sub 2} react to give predominantly liquid hydrocarbons. The reaction can be considered a special type of polymerization in which the monomer is produced in situ, and chain growth occurs by a sequence of independently repeated additions of the monomer to the growing chain. A investigation has been conducted to study the CO hydrogenation reaction in order to better understand catalyst deactivation and the elementary surface processes involved in chain growth. Isotopic tracers are used in conjunction with transient-response techniques in this study of Fischer-Tropsch synthesis over Ru/TiO{sub 2} catalysts. Experiments are conducted at a total pressure of 1 atmosphere, reaction temperatures of 453--498 K and D{sub 2}/CO (or H{sub 2}/CO) ratios of 2--5. Synthesis products are analyzed by gas chromatography or isotope-ratio gas chromatography-mass spectrometry. Rate constants for chain initiation, propagation and termination are evaluated under steady-state reaction conditions by using transients in isotopic composition. The activation energy for chain termination is much higher than that for propagation, accounting for the observed decrease in the chain growth parameter are also estimated. Coverages by reaction intermediates are also estimated. When small amounts of {sup 12}C-labelled ethylene are added to {sup 13}CO/H{sub 2} synthesis gas, ethylene acts as the sole chain initiator. Ethylene-derived carbon also accounts for 45% of the C{sub 1} monomer pool. 102 refs., 29 figs., 11 tabs.

  7. Computational Fluid Dynamics Study of Channel Geometric Effect for Fischer-Tropsch Microchannel Reactor

    International Nuclear Information System (INIS)

    Driven by both environmental and economic reasons, the development of small to medium scale GTL(gas-to-liquid) process for offshore applications and for utilizing other stranded or associated gas has recently been studied increasingly. Microchannel GTL reactors have been preferred over the conventional GTL reactors for such applications, due to its compactness, and additional advantages of small heat and mass transfer distance desired for high heat transfer performance and reactor conversion. In this work, multi-microchannel reactor was simulated by using commercial CFD code, ANSYS FLUENT, to study the geometric effect of the microchannels on the heat transfer phenomena. A heat generation curve was first calculated by modeling a Fischer-Tropsch reaction in a single-microchannel reactor model using Matlab-ASPEN integration platform. The calculated heat generation curve was implemented to the CFD model. Four design variables based on the microchannel geometry namely coolant channel width, coolant channel height, coolant channel to process channel distance, and coolant channel to coolant channel distance, were selected for calculating three dependent variables namely, heat flux, maximum temperature of coolant channel, and maximum temperature of process channel. The simulation results were visualized to understand the effects of the design variables on the dependent variables. Heat flux and maximum temperature of cooling channel and process channel were found to be increasing when coolant channel width and height were decreased. Coolant channel to process channel distance was found to have no effect on the heat transfer phenomena. Finally, total heat flux was found to be increasing and maximum coolant channel temperature to be decreasing when coolant channel to coolant channel distance was decreased. Using the qualitative trend revealed from the present study, an appropriate process channel and coolant channel geometry along with the distance between the adjacent

  8. Computational Fluid Dynamics Study of Channel Geometric Effect for Fischer-Tropsch Microchannel Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Na, Jonggeol; Jung, Ikhwan; Kshetrimayum, Krishnadash S.; Park, Seongho; Park, Chansaem; Han, Chonghun [Seoul National University, Seoul (Korea, Republic of)

    2014-12-15

    Driven by both environmental and economic reasons, the development of small to medium scale GTL(gas-to-liquid) process for offshore applications and for utilizing other stranded or associated gas has recently been studied increasingly. Microchannel GTL reactors have been preferred over the conventional GTL reactors for such applications, due to its compactness, and additional advantages of small heat and mass transfer distance desired for high heat transfer performance and reactor conversion. In this work, multi-microchannel reactor was simulated by using commercial CFD code, ANSYS FLUENT, to study the geometric effect of the microchannels on the heat transfer phenomena. A heat generation curve was first calculated by modeling a Fischer-Tropsch reaction in a single-microchannel reactor model using Matlab-ASPEN integration platform. The calculated heat generation curve was implemented to the CFD model. Four design variables based on the microchannel geometry namely coolant channel width, coolant channel height, coolant channel to process channel distance, and coolant channel to coolant channel distance, were selected for calculating three dependent variables namely, heat flux, maximum temperature of coolant channel, and maximum temperature of process channel. The simulation results were visualized to understand the effects of the design variables on the dependent variables. Heat flux and maximum temperature of cooling channel and process channel were found to be increasing when coolant channel width and height were decreased. Coolant channel to process channel distance was found to have no effect on the heat transfer phenomena. Finally, total heat flux was found to be increasing and maximum coolant channel temperature to be decreasing when coolant channel to coolant channel distance was decreased. Using the qualitative trend revealed from the present study, an appropriate process channel and coolant channel geometry along with the distance between the adjacent

  9. Incentivizing wood-based Fischer-Tropsch diesel through financial policy instruments: An economic assessment for Norway

    International Nuclear Information System (INIS)

    The objective of this study is to evaluate a select set of financial incentive instruments that can be employed by the Norwegian government for encouraging early investment and production experience in wood-based Fischer-Tropsch diesel (FTD) technologies as a means to accelerate reductions in greenhouse gas emissions (GHG) stemming from road-based transport. We start by performing an economic analysis of FTD produced from Norwegian forest biomass at a pioneer commercial plant in Norway, followed with a cost growth analysis to estimate production costs after uncertainty in early plant performance and capital cost estimates are considered. Results after the cost growth analysis imply that the initial production cost estimates for a pioneer producer may be underestimated by up to 30%. Using the revised estimate we then assess, through scenarios, how various financial support mechanisms designed to encourage near-term investment would affect production costs over a range of uncertain future oil prices. For all policy scenarios considered, we evaluate trade-offs between the levels of public expenditure, or subsidy, and private investor profitability. When considering the net present value of the subsidy required to incentivize commercial investment during a future of low oil prices, we find that GHG mitigation via wood-FTD is likely to be considered cost-ineffective. However, should the government expect that mean oil prices in the coming two decades will hover between $97 and 127/bbl, all the incentive policies considered would likely spur investment at net present values ≤$-100/tonne-fossil-CO2-equivalent avoided.

  10. Incentivizing wood-based Fischer-Tropsch diesel through financial policy instruments. An economic assessment for Norway

    International Nuclear Information System (INIS)

    The objective of this study is to evaluate a select set of financial incentive instruments that can be employed by the Norwegian government for encouraging early investment and production experience in wood-based Fischer-Tropsch diesel (FTD) technologies as a means to accelerate reductions in greenhouse gas emissions (GHG) stemming from road-based transport. We start by performing an economic analysis of FTD produced from Norwegian forest biomass at a pioneer commercial plant in Norway, followed with a cost growth analysis to estimate production costs after uncertainty in early plant performance and capital cost estimates are considered. Results after the cost growth analysis imply that the initial production cost estimates for a pioneer producer may be underestimated by up to 30%. Using the revised estimate we then assess, through scenarios, how various financial support mechanisms designed to encourage near-term investment would affect production costs over a range of uncertain future oil prices. For all policy scenarios considered, we evaluate trade-offs between the levels of public expenditure, or subsidy, and private investor profitability. When considering the net present value of the subsidy required to incentivize commercial investment during a future of low oil prices, we find that GHG mitigation via wood-FTD is likely to be considered cost-ineffective. However, should the government expect that mean oil prices in the coming two decades will hover between $97 and 127/bbl, all the incentive policies considered would likely spur investment at net present values ≤$-100/tonne-fossil-CO2-equivalent avoided. (author)

  11. Elementary steps in Fischer-Tropsch synthesis: CO bond scission, CO oxidation and surface carbiding on Co(0001)

    Science.gov (United States)

    Weststrate, C. J.; van Helden, P.; van de Loosdrecht, J.; Niemantsverdriet, J. W.

    2016-06-01

    Dissociation of CO on a Co(0001) surface is explored in the context of Fischer-Tropsch synthesis on cobalt catalysts. Experiments show that CO dissociation can occur on defect sites around 330 K, with an estimated barrier between 90 and 104 kJ mol- 1. Despite the ease of CO dissociation on defect sites, extensive carbon deposition onto the cobalt surface up to 0.33 ML requires a combination of high surface temperature and a relatively high CO pressure. Experimental data on the CO oxidation reaction indicate a high reaction barrier for the CO + O reaction, and it is argued that, due to the rather strong Co-O bond, (i) oxygen removal is the rate-limiting step during surface carbidization and (ii) in the context of Fischer-Tropsch synthesis, removal of surface oxygen rather than CO bond scission might be limiting the overall reaction rate.

  12. Development of a CO2 Tolerant Fischer-Tropsch Catalyst:from Laboratory to Commercial-Scale Demonstration in Alaska

    Institute of Scientific and Technical Information of China (English)

    Joep J H M Font Freide; Tim D Gamlin; J Richard Hensman; Barry Nay; Christopher Sharp

    2004-01-01

    This article describes the development of BP's Fischer-Tropsch catalyst, used for the conversion of carbon monoxide and hydrogen into liquid hydrocarbons. It covers the 18 year period from the early eighties, when laboratory scale preparations and micro-reactors were heavily used, right through to the present day with the commercial scale manufacture and proving of the finished catalyst in BP's new $86 million gas to liquids demonstration facility in Nikiski, Alaska. Extensive performance testing and scale-up experiments have been successfully carried out, all proof that a laboratory preparation can indeed be translated into a commercial manufacturing process. In addition, the resulting catalyst does not only meet the process design targets, but also exhibits enhanced stability and is tolerant to carbon dioxide.Above all, a commercial scale, fixed bed Fischer-Tropsch catalyst is now available and ready for licensing.Manufacturing procedures and quality control have all been successfully detailed and transferred to the commercial manufacturer.

  13. Iron-based Fischer-Tropsch Synthesis : new insights from in-situ (micro)spectroscopy, diffraction and theory

    OpenAIRE

    Smit, E.

    2010-01-01

    The Fe-based Fischer-Tropsch synthesis (FTS) catalyst, which converts CO and H2 into longer hydrocarbon chains through a catalytic surface polymerization reaction, is one of the oldest and perhaps most studied systems known in heterogeneous catalysis. However, even though the different Fe bulk phases present during FTS have been identified in the earliest studies, precise structural data of these phases, especially iron carbides, and their role in the activation and deactivation of Fe-based F...

  14. Ruthenium promotion of Co/SBA-15 catalysts for Fischer-Tropsch synthesis in slurry-phase reactors

    Institute of Scientific and Technical Information of China (English)

    Jocielys Jovelino Rodrigues; Gina Pecchi; Fabiano André Narciso Fernandes; Meiry Gláucia Freire Rodrigues

    2012-01-01

    The aim of this work was to evaluate the catalytic properties of a Ru promoted Co/SBA-15 catalyst for Fischer-Tropsch synthesis (FTS).The Ru promoted Co/SBA-15 catalyst was prepared by wet impregnation method and was characterized by X-ray diffraction,X-ray energy dispersion spectrophotometer,N2 adsorption-desorption,temperature-programmed reduction and transmission electron microscopy.The Fischer-Tropsch synthesis using the catalyst was carried out to evaluate the catalyst activity and its effect on FTS product distribution.The synthesis was carried out in a slurry reactor operating at 513 K,20 atm,CO ∶ H2 molar ratio of 1 ∶ 1.X-ray diffraction showed that the calcined cobalt catalyst did not modify the structure of SBA-15,proving that Co was present in the form of Co3O4 in the catalyst.The addition of cobalt in SBA-15 decreased the specific superficial area of the molecular sieve.Fischer-Tropsch synthesis activity and C5+ hydrocarbon selectivity increased with the addition of Ru.The increases in activity and selectivity were attributed to the increased number of active sites resulting from higher reducibility and the synergetic effect of Ru and Co.Ru/Co/SBA-15 catalysts showed moderate conversion (40%) and high selectivity towards the production of C5+ (80 wt%).

  15. Metal (Fe, Co, Ni) supported on different aluminas as Fischer-Tropsch catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Dahlan [Chemistry Education Study Program, Universitas Halu Oleo, Jl. HEA Mokodompit, Kendari 93232 (Indonesia); Marsih, I. Nyoman, E-mail: nyoman@chem.itb.ac.id; Ismunandar [Inorganic and Physical Chemistry Division, Departement of Chemistry, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia); Makertihartha, I. G. B. N. [Department of Chemical Engineering, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia); Praserthdam, Piyasan; Panpranot, Joongjai [Center of Excellence on Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Chulalongkorn University, 254 Phayathai Road, Bangkok 10330 (Thailand)

    2015-09-30

    This research aimed to compare the physico-chemical properties of the same metal M (M = iron, cobalt, nickel) supported on aluminas with different morphology and pore size as Fischer-Tropsch catalyst. The aluminas applied as support were alumina synthesized through hydrothermal process, alumina formed by pretreatment of catapal and commercial alumina which named as Ahy, Aca, and Aco respectively. Ahy has uniform morphology of nanotubes while Aca and Aco showed non-uniform morphology of particle lumps. The particle lumps of Aca were larger than those of Aco. Ahy, Aca, and Aco respectively has average pore diameter of 2.75, 2.86 and 2.9 nm. Metals were deposited on the supports by incipient-wetness impregnation method. The catalysts were characterized by XRD, H{sub 2}-TPR, and H{sub 2} chemisorption. Catalyst acitivity test for Fischer-Tropsch reaction was carried out in a micro reactor at 200 °C and 1 atm, and molar ratio of H{sub 2}/CO = 2:1. The metal oxide particle size increased in the order M/Aco < M/Aca < M/Ahy. The catalysts reducibility also increased according to the order M/Aco < M/Aca < M/Ahy suggesting that the larger metal oxide particles are more reducible. The number of active site was not proportional to the reducibility because during the reduction, larger metal oxide particles were converted into larger metal particles. On the other hand, the number of active sites was inversely proportional to the particle sizes. The number of active site increased in the order M/Ahy < M/Aco < M/Aca. The catalytic activity also increased in the following order M/Ahy < M/Aco < M/Aca. The activity per active site increased according to the order M/Aca < M/Aco < M/Ahy meaning that for M/Ahy, a little increase in active site will lead to a significance increase in catalytic activity. It showed that Ahy has potential for the better support.

  16. Metal (Fe, Co, Ni) supported on different aluminas as Fischer-Tropsch catalyst

    International Nuclear Information System (INIS)

    This research aimed to compare the physico-chemical properties of the same metal M (M = iron, cobalt, nickel) supported on aluminas with different morphology and pore size as Fischer-Tropsch catalyst. The aluminas applied as support were alumina synthesized through hydrothermal process, alumina formed by pretreatment of catapal and commercial alumina which named as Ahy, Aca, and Aco respectively. Ahy has uniform morphology of nanotubes while Aca and Aco showed non-uniform morphology of particle lumps. The particle lumps of Aca were larger than those of Aco. Ahy, Aca, and Aco respectively has average pore diameter of 2.75, 2.86 and 2.9 nm. Metals were deposited on the supports by incipient-wetness impregnation method. The catalysts were characterized by XRD, H2-TPR, and H2 chemisorption. Catalyst acitivity test for Fischer-Tropsch reaction was carried out in a micro reactor at 200 °C and 1 atm, and molar ratio of H2/CO = 2:1. The metal oxide particle size increased in the order M/Aco < M/Aca < M/Ahy. The catalysts reducibility also increased according to the order M/Aco < M/Aca < M/Ahy suggesting that the larger metal oxide particles are more reducible. The number of active site was not proportional to the reducibility because during the reduction, larger metal oxide particles were converted into larger metal particles. On the other hand, the number of active sites was inversely proportional to the particle sizes. The number of active site increased in the order M/Ahy < M/Aco < M/Aca. The catalytic activity also increased in the following order M/Ahy < M/Aco < M/Aca. The activity per active site increased according to the order M/Aca < M/Aco < M/Ahy meaning that for M/Ahy, a little increase in active site will lead to a significance increase in catalytic activity. It showed that Ahy has potential for the better support

  17. An Ab Initio Approach Towards Engineering Fischer-Tropsch Surface Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Matthew Neurock

    2006-09-11

    One of the greatest societal challenges over the next decade is the production of cheap, renewable energy for the 10 billion people that inhabit the earth. This will require the development of various energy sources which will likely include fuels derived from methane, coal, and biomass and alternatives sources such as solar, wind and nuclear energy. One approach will be to synthesize gasoline and other fuels from simpler hydrocarbons such as CO derived from methane or other U.S. based sources such as coal. Syngas (CO and H{sub 2}) can be readily converted into higher molecular weight hydrocarbons through Fischer-Tropsch synthesis. Fischer-Tropsch (FT) synthesis involves the adsorption and the activation of CO and H{sub 2}, the subsequent propagation steps including hydrogenation and carbon-carbon coupling, followed by chain termination reactions. The current commercial catalysts are supported Co and Co-alloys particles. This project set out with the following objectives in mind: (1) understand the reaction mechanisms that control FT kinetics, (2) predict how the intrinsic metal-adsorbate bond affects the sequence of elementary steps in FT, (3) establish the effects of the reaction environment on catalytic activity and selectivity, (4) construct a first-principles based algorithm that can incorporate the detailed atomic surface structure and simulate the kinetics for the myriad of elementary pathways that make up FT chemistry, and (5) suggest a set of optimal features such as alloy composition and spatial configuration, oxide support, distribution of defect sites. As part of this effort we devoted a significant portion of time to develop an ab initio based kinetic Monte Carlo simulation which can be used to follow FT surface chemistry over different transition metal and alloy surfaces defined by the user. Over the life of this program, we have used theory and have developed and applied stochastic Monte Carlo simulations in order to establish the fundamental

  18. Deactivation and Regeneration of Commercial Type Fischer-Tropsch Co-Catalysts—A Mini-Review

    Directory of Open Access Journals (Sweden)

    Erling Rytter

    2015-03-01

    Full Text Available Deactivation of commercially relevant cobalt catalysts for Low Temperature Fischer-Tropsch (LTFT synthesis is discussed with a focus on the two main long-term deactivation mechanisms proposed: Carbon deposits covering the catalytic surface and re-oxidation of the cobalt metal. There is a great variety in commercial, demonstration or pilot LTFT operations in terms of reactor systems employed, catalyst formulations and process conditions. Lack of sufficient data makes it difficult to correlate the deactivation mechanism with the actual process and catalyst design. It is well known that long term catalyst deactivation is sensitive to the conditions the actual catalyst experiences in the reactor. Therefore, great care should be taken during start-up, shutdown and upsets to monitor and control process variables such as reactant concentrations, pressure and temperature which greatly affect deactivation mechanism and rate. Nevertheless, evidence so far shows that carbon deposition is the main long-term deactivation mechanism for most LTFT operations. It is intriguing that some reports indicate a low deactivation rate for multi-channel micro-reactors. In situ rejuvenation and regeneration of Co catalysts are economically necessary for extending their life to several years. The review covers information from open sources, but with a particular focus on patent literature.

  19. Pyrolysis-GCMS Analysis of Solid Organic Products from Catalytic Fischer-Tropsch Synthesis Experiments

    Science.gov (United States)

    Locke, Darren R.; Yazzie, Cyriah A.; Burton, Aaron S.; Niles, Paul B.; Johnson, Natasha M.

    2015-01-01

    Abiotic synthesis of complex organic compounds in the early solar nebula that formed our solar system is hypothesized to occur via a Fischer-Tropsch type (FTT) synthesis involving the reaction of hydrogen and carbon monoxide gases over metal and metal oxide catalysts. In general, at low temperatures (less than 200 C), FTT synthesis is expected to form abundant alkane compounds while at higher temperatures (greater than 200 C) it is expected to product lesser amounts of n-alkanes and greater amounts of alkene, alcohol, and polycyclic aromatic hydrocarbons (PAHs). Experiments utilizing a closed-gas circulation system to study the effects of FTT reaction temperature, catalysts, and number of experimental cycles on the resulting solid insoluble organic products are being performed in the laboratory at NASA Goddard Space Flight Center. These experiments aim to determine whether or not FTT reactions on grain surfaces in the protosolar nebula could be the source of the insoluble organic matter observed in meteorites. The resulting solid organic products are being analyzed at NASA Johnson Space Center by pyrolysis gas chromatography mass spectrometry (PY-GCMS). PY-GCMS yields the types and distribution of organic compounds released from the insoluble organic matter generated from the FTT reactions. Previously, exploratory work utilizing PY-GCMS to characterize the deposited organic materials from these reactions has been reported. Presented here are new organic analyses using magnetite catalyst to produce solid insoluble organic FTT products with varying reaction temperatures and number of experimental cycles.

  20. Effect of niobium promoter on iron-based catalyst for Fischer-Tropsch reaction

    Institute of Scientific and Technical Information of China (English)

    Sardar ALI; Noor Asmawati MOHD ZABIDI; Duvvuri SUBBARAO

    2012-01-01

    Niobium-promoted Fe/CNTs catalysts were prepared using a wet impregnation method.Samples were characterized by nitrogen adsorption,H2-TPR,TPD,XRD and TEM.The Fischer-Tropsch Synthesis (FTS) was carried out in a fixed-bed microreactor at 220 ℃,1 atm and H2/CO =2 for 5 h.Addition of niobium into Fe/CNTs increased the dispersion,decreased the average size of iron oxide nanoparticles and the catalyst reducibility.Niobium-promoted Fe catalyst resulted in appreciable increase in the selectivity of C5+ hydrocarbons and suppressed methane formation.These effects were more pronounced for the 0.04% Nb/Fe/CNTs catalyst,compared to those observed from other niobium compositions.The 0.04% Nb/Fe/CNTs catalyst enhanced the C5+ hydrocarbons selectivity by a factor of 67.5% and reduced the methane selectivity by a factor of 59.2%.

  1. Greenhouse impact assessment of peat-based Fischer-Tropsch diesel life-cycle

    Energy Technology Data Exchange (ETDEWEB)

    Kirkinen, Johanna; Soimakallio, Sampo; Maekinen, Tuula; Savolainen, Ilkka [VTT Technical Research Centre of Finland, P.O. Box 1000, FI-02044 VTT (Finland)

    2010-01-15

    New raw materials for transportation fuels need to be introduced, in order to fight against climate change and also to cope with increasing risks of availability and price of oil. Peat has been recognised suitable raw material option for diesel produced by gasification and Fischer-Tropsch (FT) synthesis. The energy content of Finnish peat reserves is remarkable. In this study, the greenhouse impact of peat-based FT diesel production and utilisation in Finland was assessed from the life-cycle point of view. In 100 year's time horizon the greenhouse impact of peat-based FT diesel is likely larger than the impact of fossil diesel. The impact can somewhat be lowered by producing peat from the agricultural peatland (strong greenhouse gas emissions from the decaying peatlayer are avoided) with new peat production technique, and utilising the produced biomass from the after-treatment area for diesel also. If diesel production is integrated with pulp and paper mill to achieve energy efficiency benefits and if the electricity demand can be covered by zero emission electricity, the greenhouse impact of peat-based FT diesel reduces to the level of fossil diesel when agricultural peatland is used, and is somewhat higher when forestry-drained peatland is used as raw material source. (author)

  2. The effect of zirconium on cobalt catalyst in fischer-tropsch synthesis

    International Nuclear Information System (INIS)

    A series of 10 wt % Co/SiO2 catalysts with different loading ratios of zirconia (0, 5, 10, 15, 20) has been prepared through an original pseudo sol-gel method. All catalysts were characterized by BET, XRD, SEM, and TPR experiments. The catalytic performance of the catalysts for the so-called fischer- tropsch synthesis was examined under H2/CO=2 at 230digC and 8 bar in a fixed bed microreactor. By increasing zirconia, the Co-SiO2 interaction decreases and is replaced by Co-Zr interaction which favours reduction of the catalyst at lower temperatures. While it leads to a higher degree of reduction and as increase in the metallic cobalt atoms on the surface. The activity of the promoted catalysts increases with the addition of zirconia (max. by a factor 2.5). The C10+ selectivity increased with the addition of zirconia (from 42.3% in unpromoted catalyst to 68.8 % in the 20 % ZrO2 promoted. This can be attributed to the higher amount of the surface Cobalt metal present and to the larger Cobalt particle size

  3. Fischer-Tropsch Cobalt Catalyst Activation and Handling Through Wax Enclosure Methods

    Science.gov (United States)

    Klettlinger, Jennifer L. S.; Yen, Chia H.; Nakley, Leah M.; Surgenor, Angela D.

    2016-01-01

    Fischer-Tropsch (F-T) synthesis is considered a gas to liquid process which converts syn-gas, a gaseous mixture of hydrogen and carbon monoxide, into liquids of various hydrocarbon chain length and product distributions. Cobalt based catalysts are used in F-T synthesis and are the focus of this paper. One key concern with handling cobalt based catalysts is that the active form of catalyst is in a reduced state, metallic cobalt, which oxidizes readily in air. In laboratory experiments, the precursor cobalt oxide catalyst is activated in a fixed bed at 350 ?C then transferred into a continuous stirred tank reactor (CSTR) with inert gas. NASA has developed a process which involves the enclosure of active cobalt catalyst in a wax mold to prevent oxidation during storage and handling. This improved method allows for precise catalyst loading and delivery into a CSTR. Preliminary results indicate similar activity levels in the F-T reaction in comparison to the direct injection method. The work in this paper was supported by the NASA Fundamental Aeronautics Subsonics Fixed Wing Project.

  4. Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis to lower carbon dioxide emissions

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, Gerald P

    2012-09-18

    A method for producing liquid fuels includes the steps of gasifying a starting material selected from a group consisting of coal, biomass, carbon nanotubes and mixtures thereof to produce a syngas, subjecting that syngas to Fischer-Tropsch synthesis (FTS) to produce a hyrdrocarbon product stream, separating that hydrocarbon product stream into C1-C4 hydrocarbons and C5+ hydrocarbons to be used as liquid fuels and subjecting the C1-C4 hydrocarbons to catalytic dehydrogenation (CDH) to produce hydrogen and carbon nanotubes. The hydrogen produced by CDH is recycled to be mixed with the syngas incident to the FTS reactor in order to raise the hydrogen to carbon monoxide ratio of the syngas to values of 2 or higher, which is required to produce liquid hydrocarbon fuels. This is accomplished with little or no production of carbon dioxide, a greenhouse gas. The carbon is captured in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWNT), while huge emissions of carbon dioxide are avoided and very large quantities of water employed for the water-gas shift in traditional FTS systems are saved.

  5. Potential for Coal-to-Liquids Conversion in the United States-Fischer-Tropsch Synthesis

    International Nuclear Information System (INIS)

    The United States has the world's largest coal reserves and Montana the highest potential for mega-mine development. Consequently, a large-scale effort to convert coal to liquids (CTL) has been proposed to create a major source of domestic transportation fuels from coal, and some prominent Montanans want to be at the center of that effort. We calculate that the energy efficiency of the best existing Fischer-Tropsch (FT) process applied to average coal in Montana is less than 1/2 of the corresponding efficiency of an average crude oil refining process. The resulting CO2 emissions are 20 times (2000%) higher for CTL than for conventional petroleum products. One barrel of the FT fuel requires roughly 800 kg of coal and 800 kg of water. The minimum energy cost of subsurface CO2 sequestration would be at least 40% of the FT fuel energy, essentially halving energy efficiency of the process. We argue therefore that CTL conversion is not the most valuable use for the coal, nor will it ever be, as long as it is economical to use natural gas for electric power generation. This finding results from the low efficiency inherent in FT synthesis, and is independent of the monumental FT plant construction costs, mine construction costs, acute lack of water, and the associated environmental impacts for Montana

  6. Influence of liquid medium on the activity of a low-alpha Fischer-Tropsch catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Gormley, R.J.; Zarochak, M.F.; Deffenbaugh, P.W.; Rao, K.R.P.M.

    1995-12-31

    The purpose of this research was to measure activity, selectivity, and the maintenance of these properties in slurry autoclave experiments with a Fischer-Tropsch (FT) catalyst that was used in the {open_quotes}FT II{close_quotes} bubble-column test, conducted at the Alternative Fuels Development Unit (AFDU) at LaPorte, Texas during May 1994. The catalyst contained iron, copper, and potassium and was formulated to produce mainly hydrocarbons in the gasoline range with lesser production of diesel-range products and wax. The probability of chain growth was thus deliberately kept low. Principal goals of the autoclave work have been to find the true activity of this catalyst in a stirred tank reactor, unhindered by heat or mass transfer effects, and to obtain a steady conversion and selectivity over the approximately 15 days of each test. Slurry autoclave testing of the catalyst in heavier waxes also allows insight into operation of larger slurry bubble column reactors. The stability of reactor operation in these experiments, particularly at loadings exceeding 20 weight %, suggests the likely stability of operations on a larger scale.

  7. The role of palladium in iron based Fischer-Tropsch catalysts prepared by flame spray pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Minnermann, M.; Zielasek, V.; Baeumer, M. [Bremen Univ. (DE). Inst. of Applied and Physical Chemistry (IAPC); Pokhrei, S.; Maedler, L. [Bremen Univ. (DE). Foundation Inst. of Materials Science (IWT); Thiel, K. [Fraunhofer Institute for Manufactoring Technology and Applied Materials Research, Bremen (Germany)

    2011-07-01

    Flame spray pyrolysis (FSP) is a novel technique for the fabrication of nanostructured catalysts with far-reaching options to control structure and composition even in cases where complex composites need to be prepared. In this study, we took advantage of this technique to synthesize highly dispersed pure and Pd-doped iron oxide nanoparticles and investigated them as Fischer-Tropsch (FT) catalysts. By systematically varying the Pd content over a large range from 0.1 wt % to 10 wt %, we were able to directly analyze the influence of the Pd content on activity and selectivity. In addition to catalytic measurements, the structure and composition of the particles were characterized before and after these measurements, using transmission electron microscopy, adsorption measurements, X-ray diffraction and EXAFS. The comparison revealed, on the one hand, that small Pd clusters (diameter: 1-2 nm) evolve from initially homogeneously distributed Pd and, on the other hand, that the iron oxide transforms into iron carbides depending on the Pd content. The presence of Pd influences the particle size in the pristine samples (8 - 11 nm), resulting in specific surface areas that increase as the Pd content increases. However, after activation and reaction the specific surface areas become similar due to partial agglomeration and sintering. In a fixed bed FT reaction test, enhanced FT activity was observed with increasing Pd content while the selectivity shifts to longer chain hydrocarbons, mainly paraffins. (orig.)

  8. In situ reduction study of cobalt model Fischer-Tropsch synthesis catalysts.

    Science.gov (United States)

    du Plessis, Hester Esna; Forbes, Roy Peter; Barnard, Werner; Erasmus, Willem Johannes; Steuwer, Axel

    2013-07-28

    Fischer-Tropsch (FT) synthesis is an important process to manufacture hydrocarbons and oxygenated hydrocarbons from mixtures of carbon monoxide and hydrogen (syngas). The catalysis process occurs on, for example, cobalt metal surfaces at elevated temperatures and pressures. A fundamental understanding of the reduction pathway of supported cobalt oxides, and the intermediate species present during the activation, can assist in developing improved industrial supported cobalt catalysts. Hard synchrotron X-rays have the unique ability to probe atomic processes both in terms of phases present as well as the crystallographic and local structure (using the pair distribution function approach) under realistic conditions. In this manuscript we present results from measurements during in situ hydrogen activation of a model Co/alumina catalyst using in situ synchrotron X-ray powder diffraction and pair-distribution function (PDF) analysis on beam line ID31 at the ESRF in Grenoble, France. The PDF analysis showed a substantially improved understanding of the reduction of cobalt oxides, as for the first time all cobalt could be accounted for by using total scattering analysis. PMID:23752408

  9. Synthesis, Modeling and Exergy Analysis of Atmospheric Air Blown Biomass Gasification for Fischer-Tropsch Process

    Directory of Open Access Journals (Sweden)

    K. D. Panopoulos

    2009-12-01

    Full Text Available

    The main objective of the present work is to investigate the combination of an atmospheric and a pressurised air blown biomass gasifier towards Fischer-Tropsch (FT synthesis of second generation biofuels and co-production of power. The complete process was simulated in AspenPlusTM software including sub-models for the gasification, gas cleaning and conditioning as well as for the FT reactor. A sensitivity analysis on exergetic performance was performed mainly examining the recycling of FT-tail gas. For the base case of 80% FT CO conversion without any recirculation, the exergetic efficiency was found to be 34.3% with atmospheric gasification and 30.64% for pressurised gasification. Recirculation of the non-reacted CO, H2 as well as light gas products of the FT-reactor back to the atmospheric gasifier can increase the overall efficiency up to 48.1 %.

    • This paper is an updated version of a paper published in the ECOS'08 proceedings.

  10. Combustion characteristics of a direct-injection diesel engine fueled with Fischer-Tropsch diesel

    Institute of Scientific and Technical Information of China (English)

    HUANG Yongcheng; ZHOU Longbao; PAN Keyu

    2007-01-01

    Fischer-Tropsch (F-T) diesel fuel is characterized by a high cetane number, a near-zero sulphur content and a very low aromatic level. On the basis of the recorded incylinder pressures and injector needle lifts, the combustion characteristics of an unmodified single-cylinder directinjection diesel engine operating on F-T diesel fuel are analyzed and compared with those of conventional diesel fuel operation. The results show that F-T diesel fuel exhibits a slightly longer injection delay and injection duration, an average of 18.7% shorter ignition delay, and a comparable total combustion duration when compared to those of conventional diesel fuel. Meanwhile, F-T diesel fuel displays an average of 26.8% lower peak value of premixed burning rate and a higher peak value of diffusive burning rate. In addition, the F-T diesel engine has a slightly lower peak combustion pressure, a far lower rate of pressure rise, and a lower mechanical load and combustion noise than the conventional diesel engine. The brake specific fuel consumption is lower and the effective thermal efficiency is higher for F-T diesel fuel operation.

  11. Product distributions of Fischer-Tropsch synthesis over Co/AC catalyst

    Institute of Scientific and Technical Information of China (English)

    Weixin Qian; Haitao Zhang; Weiyong Ying; Dingye Fang

    2011-01-01

    The product distributions of Fischer-Tropsch synthesis over Co/AC catalyst are investigated under different reaction conditions in an integral fixed bed reactor.It is found that the product distributions deviate from the ASF distribution.The deviation from ASF distribution is analyzed by taking the readsorption of alkenes and the following secondary reaction into consideration.It is noted that the contents of alcohol,alkene and alkane decline with the increasing carbon number,showing a slighter declining tendency of alkanes than those of alkenes and alcohols.It is also found that high temperature,space velocity,H2/CO in feed gas and low pressure are preferential for light hydrocarbons and alcohols while against the chain propagation.The effect of space velocity on the product distributions especially on the light products is not obvious.It is noticed that low temperature,space velocity,H2/CO and high pressure lead to high contents of alcohols; high temperature,H2/CO and low space velocity lead to high contents of alkanes.The effect of pressure on the amounts of alkanes is not significant; high space velocity and low temperature,pressure,H2/CO are preferential for alkenes.

  12. Cobalt Fischer-Tropsch catalysts: influence of cobalt dispersion and titanium oxides promotion

    Energy Technology Data Exchange (ETDEWEB)

    Azib, H.

    1996-04-10

    The aim of this work is to study the effect of Sol-Gel preparation parameters which occur in silica supported cobalt catalysts synthesis. These catalysts are particularly used for the waxes production in natural gas processing. The solids have been characterized by several techniques: transmission electron microscopy (TEM), X-ray absorption near edge spectroscopy (XANES), programmed temperature reduction (TPR), infrared spectroscopy (IR), ultraviolet spectroscopy (UV), Magnetism, thermodesorption of H{sub 2} (TPD). The results indicate that the control of the cobalt dispersion and oxide phases nature is possible by modifying Sol-Gel parameters. The catalytic tests in Fischer-Tropsch synthesis were conducted on a pilot unit under pressure (20 atm) and suggested that turnover rates were independent of Co crystallite size, Co phases in the solids (Co deg., cobalt silicate) and titanium oxide promotion. On the other methane, the C{sub 3}{sup +} hydrocarbon selectivity is increased with increasing crystallite size. Inversely, the methane production is favoured by very small crystallites, cobalt silicate increase and titanium addition. However, the latter, used as a cobalt promoter, has a benefic effect on the active phase stability during the synthesis. (author). 149 refs., 102 figs., 71 tabs.

  13. Meteorites, Organics and Fischer-Tropsch Type Reaction: Production and Destruction

    Science.gov (United States)

    Johnson, Natasha M.; Burton, A. S.; Nurth, J. A., III

    2011-01-01

    There has been an ongoing debate about the relative importance about the various chemical reactions that fonned organics in the early solar system. One proposed method that has long been recognized as a potential source of organics is Fischer-Tropsch type (FTT) synthesis. This process is commonly used in industry to produce fuels (i.e., complex hydrocarbons) by catalytic hydrogenation of carbon monoxide. Hill and Nuth were the first to publish results of FTT experiments that also included Haber-Bosch (HB) processes (hydrogenation of nitrogen. Their findings included the production of nitrilebearing compounds as well as trace amounts of methyl amine. Previous experience with these reactions revealed that the organic coating deposited on the grains is also an efficient catalyst and that the coating is composed of insoluble organic matter (10M) and could be reminiscent of the organic matrix found in some meteorites. This current set of FTT-styled experiments tracks the evolution of a set of organics, amino acids, in detail.

  14. Two-Bubble Class Model for Churn-Turbulent Regime in a Bubble Column Slurry Reactor of Fischer-Tropsch Synthesis

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A model for a bubble column slurry reactor is developed based on the experiment of Rhenpreussen Koppers demonstration plant for slurry phase Fischer-Tropsch synthesis reported by Koelble et al. This model is applicable to the operation in the churn-turbulent regime and incorporates the information on the bubble size. The axial dispersion model is adopted to describe the flow characteristics of the Fischer-Tropsch slurry reactor. With the model developed, simulations are performed to identify the steady state behavior of a Fischer-Tropsch slurry reactor of commercial size. Predictions of the two-bubble class model is compared with that of the conventional single- bubble class model. The results show that under a variety of conditions, the two-bubble class model gives results different from those for the single-bubble class model.

  15. Effect of Lanthanum as a Promoter on Fe-Co/SiO2 Catalyst for Fischer-Tropsch Synthesis

    Directory of Open Access Journals (Sweden)

    Ali Abbasi

    2014-03-01

    Full Text Available Iron-Cobalt catalyst is well known from both operational and economical aspects for Fischer-Tropsch synthesis. Effort to increase the efficiency of this kind of catalyst is an important research topic. In this work, the effect of lanthanum on characteristic behavior, conversion and selectivity of a Fe-Co/SiO2 Fischer-Tropsch catalyst was studied. The Fe-Co-La/SiO2 Catalysts were prepared using an incipient wetness impregnation method. These catalysts were then characterized by XRF-EDAX, BET and TPR techniques, and their performance were evaluated in a lab-scale reactor at 250ºC, H2/CO = 1.8 of molar ratio, 16 barg pressure and GHSV=600 h-1. TPR analysis showed that the addition of La lowered the reduction temperature of Fe-Co catalyst, and due to a lower temperature, the sintering of the catalyst can be mitigated. Furthermore, from the micro reactor tests (about 4 days, it was found that lanthanum promoted catalyst had higher selectivity toward hydrocarbons, and lower selectivity toward CO2.Received: 8th July 2013; Revised: 18th November 2013; Accepted: 1st December 2013[How to Cite: Abbasi, A., Ghasemi, M., Sadighi, S. (2014. Effect of Lanthanum as a Promoter on Fe-Co/SiO2 Catalyst for Fischer-Tropsch Synthesis. Bulletin of Chemical Reaction Engineering & Catalysis, 9 (1: 23-27. (doi:10.9767/bcrec.9.1.5142.23-27][Permalink/DOI: http://dx.doi.org/10.9767/bcrec.9.1.5142.23-27

  16. A combined in situ XAS-XRPD-Raman study of Fischer-Tropsch synthesis over a carbon supported Co catalyst

    DEFF Research Database (Denmark)

    Tsakoumis, Nikolaos E.; Dehghan, Roya; Johnsen, Rune;

    2013-01-01

    A cobalt based Fischer-Tropsch synthesis (FTS) catalyst, supported on a carbon nanofibers/carbon felt composite (Co/CNF/CF) was studied in situ at realistic conditions. The catalyst was monitored by Xray absorption spectroscopy (XAS), high-resolution X-ray powder diffraction (HR-XRPD) and Raman...... spectroscopy, while changes in the gas phase were observed by mass spectrometry (MS). Transmission electron microscopy (TEM) was also applied to characterise the catalyst. The catalyst has a bimodal particle size distribution and exhibits a high deactivation rate. During the in situ study the catalyst appears...

  17. DEVELOPMENT OF ATTRITION RESISTANT IRON-BASED FISCHER-TROPSCH CATALYSTS

    International Nuclear Information System (INIS)

    The Fischer-Tropsch (F-T) reaction provides a way of converting coal-derived synthesis gas (CO+H2) to liquid fuels. Since the reaction is highly exothermic, one of the major problems in control of the reaction is heat removal. Recent work has shown that the use of slurry bubble column reactors (SBCRs) can largely solve this problem. The use of iron-based catalysts is attractive not only due to their low cost and ready availability, but also due to their high water-gas shift activity which makes it possible to use these catalysts with low H2/CO ratios. However, a serious problem with use of Fe catalysts in a SBCR is their tendency to undergo attrition. This can cause fouling/plugging of downstream filters and equipment, makes the separation of catalyst from the oil/wax product very difficult if not impossible, and results in a steady loss of catalyst from the reactor. Recently, fundamental understanding of physical attrition is being addressed by incorporating suitable binders into the catalyst recipe. This has resulted in the preparation of a spray dried Fe-based catalyst having aps of 70 mm with high attrition resistance. This Fe-based attrition resistant, active and selective catalyst gave 95% CO conversion through 125 hours of testing in a fixed-bed at 270 C, 1.48 MPa, H2/CO=0.67 and 2.0 NL/g-cat/h with C5+ selectivity of >78% and methane selectivity of <5%. However, further development of the catalyst is needed to address the chemical attrition due to phase changes that any Fe-catalyst goes through potentially causing internal stresses within the particle and resulting in weakening, spalling or cracking. The objective of this research is to develop robust iron-based Fischer-Tropsch catalysts that have suitable activity, selectivity and stability to be used in the slurry bubble column reactor. Specifically we aim to develop to: (i) improve the performance and preparation procedure of the high activity, high attrition resistant, high alpha iron-based catalysts

  18. Process analysis for polygeneration of Fischer-Tropsch liquids and power with CO{sub 2} capture based on coal gasification

    Energy Technology Data Exchange (ETDEWEB)

    Ge-wen Yu; Yuan-yuan Xu; Xu Hao; Yong-wang Li; Guang-qi Liu [Chinese Academy of Sciences, Taiyuan (China). State Key Laboratory of Coal Conversion

    2010-05-15

    This paper designs four cases to investigate the performances of the polygeneration processes, which depend on the commercially ready technology to convert coal to liquid fuels (CTL) and electricity with CO{sub 2} sequestration. With Excel-Aspen Plus based models, mass and energy conversion are calculated in detail. The simulation shows that the thermal efficiency is down with the synfuels yield decrease though the electricity generation is increased. It also suggests that the largest low heat value (LHV) loss of coal occurs in the gasification unit. From the comparison of the four cases, prominent differences of coal energy transition appear in water-gas shift (WGS) units, Fischer-Tropsch (FT) synthesis and combined cycle processes. CO{sub 2} capture and vent are discussed and the results show that the vent amount of CO{sub 2} increases with the increase of percentage of the syngas going to produce electricity. The results also show that the ratio of carbon captured to total carbon increases from 58% to 93% which is an important contribution to cutting down the greenhouse gas vent. 40 refs., 3 figs., 4 tabs.

  19. Toward a more comprehensive greenhouse gas emissions assessment of biofuels: the case of forest-based fischer-tropsch diesel production in Finland.

    Science.gov (United States)

    Soimakallio, Sampo

    2014-01-01

    Increasing the use of biofuels influences atmospheric greenhouse gas concentrations. Although widely recognized, uncertainties related to the particular impacts are typically ignored or only partly considered. In this paper, various sources of uncertainty related to the GHG emission savings of biofuels are considered comprehensively and transparently through scenario analysis and stochastic simulation. Technology and feedstock production chain-specific factors, market-mediated factors and climate policy time frame issues are reflected using as a case study Fischer-Tropsch diesel derived from boreal forest biomass in Finland. This case study shows that the GHG emission savings may be positive or negative in many of the cases studied, and are subject to significant uncertainties, which are mainly determined by market-mediated factors related to fossil diesel substitution. Regardless of the considerable uncertainties, some robust conclusions could be drawn; it was likely of achieving some sort of but unlikely of achieving significant savings in the GHG emissions within the 100 year time frame in many cases. Logging residues (branches) performed better than stumps and living stem wood in terms of the GHG emission savings, which could be increased mainly by blocking carbon leakage. Forest carbon stock changes also significantly contributed to the GHG emission savings. PMID:24528291

  20. Impact of Contaminants Present in Coal-Biomass Derived Synthesis Gas on Water-gas Shift and Fischer-Tropsch Synthesis Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Alptekin, Gokhan [TDA Research, Inc., Wheat Ridge, CO (United States)

    2013-02-15

    Co-gasification of biomass and coal in large-scale, Integrated Gasification Combined Cycle (IGCC) plants increases the efficiency and reduces the environmental impact of making synthesis gas ("syngas") that can be used in Coal-Biomass-to-Liquids (CBTL) processes for producing transportation fuels. However, the water-gas shift (WGS) and Fischer-Tropsch synthesis (FTS) catalysts used in these processes may be poisoned by multiple contaminants found in coal-biomass derived syngas; sulfur species, trace toxic metals, halides, nitrogen species, the vapors of alkali metals and their salts (e.g., KCl and NaCl), ammonia, and phosphorous. Thus, it is essential to develop a fundamental understanding of poisoning/inhibition mechanisms before investing in the development of any costly mitigation technologies. We therefore investigated the impact of potential contaminants (H2S, NH3, HCN, AsH3, PH3, HCl, NaCl, KCl, AS3, NH4NO3, NH4OH, KNO3, HBr, HF, and HNO3) on the performance and lifetime of commercially available and generic (prepared in-house) WGS and FT catalysts.

  1. SEPARATION OF FISCHER-TROPSCH WAX PRODUCTS FROM ULTRAFINE IRON CATALYST PARTICLES

    Energy Technology Data Exchange (ETDEWEB)

    James K. Neathery; Gary Jacobs; Burtron H. Davis

    2005-03-31

    In this reporting period, a fundamental filtration study was continued to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. The overall focus of the program is with slurry-phase FTS in slurry bubble column reactor systems. Hydrocarbon products must be separated from catalyst particles before being removed from the reactor system. An efficient wax product/catalyst separation system is a key factor for optimizing operating costs for iron-based slurry-phase FTS. Previous work has focused on catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. With the current study, we are investigating how the filtration properties are affected by these chemical and physical changes of the catalyst slurry during activation/synthesis. In this reporting period, a series of crossflow filtration experiments were initiated to study the effect of olefins and oxygenates on the filtration flux and membrane performance. Iron-based FTS reactor waxes contain a significant amount of oxygenates, depending on the catalyst formulation and operating conditions. Mono-olefins and aliphatic alcohols were doped into an activated iron catalyst slurry (with Polywax) to test their influence on filtration properties. The olefins were varied from 5 to 25 wt% and oxygenates from 6 to 17 wt% to simulate a range of reactor slurries reported in the literature. The addition of an alcohol (1-dodecanol) was found to decrease the permeation rate while the olefin added (1-hexadecene) had no effect on the permeation rate. A passive flux maintenance technique was tested that can temporarily increase the permeate rate for 24 hours.

  2. Correlation between Fischer-Tropsch catalytic activity and composition of catalysts

    Directory of Open Access Journals (Sweden)

    Subbarao Duvvuri

    2011-11-01

    Full Text Available Abstract This paper presents the synthesis and characterization of monometallic and bimetallic cobalt and iron nanoparticles supported on alumina. The catalysts were prepared by a wet impregnation method. Samples were characterized using temperature-programmed reduction (TPR, temperature-programmed oxidation (TPO, CO-chemisorption, transmission electron microscopy (TEM, field emission scanning electron microscopy (FESEM-EDX and N2-adsorption analysis. Fischer-Tropsch synthesis (FTS was carried out in a fixed-bed microreactor at 543 K and 1 atm, with H2/CO = 2 v/v and space velocity, SV = 12L/g.h. The physicochemical properties and the FTS activity of the bimetallic catalysts were analyzed and compared with those of monometallic cobalt and iron catalysts at similar operating conditions. H2-TPR analysis of cobalt catalyst indicated three temperature regions at 506°C (low, 650°C (medium and 731°C (high. The incorporation of iron up to 30% into cobalt catalysts increased the reduction, CO chemisorption and number of cobalt active sites of the catalyst while an opposite trend was observed for the iron-riched bimetallic catalysts. The CO conversion was 6.3% and 4.6%, over the monometallic cobalt and iron catalysts, respectively. Bimetallic catalysts enhanced the CO conversion. Amongst the catalysts studied, bimetallic catalyst with the composition of 70Co30Fe showed the highest CO conversion (8.1% while exhibiting the same product selectivity as that of monometallic Co catalyst. Monometallic iron catalyst showed the lowest selectivity for C5+ hydrocarbons (1.6%.

  3. Mechanism and kinetics of Fischer-Tropsch synthesis over supported ruthenium catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Kellner, C.S.

    1981-06-01

    A detailed study of the kinetics of the Fischer-Tropsch synthesis of hydrocarbons, methanol, and acetaldehyde, over alumina- and silica-supported ruthenium catalysts has been carried out over a broad range of reaction conditions. Based on these results and information taken from the literature, mechanisms for the formation of normal paraffins, ..cap alpha..-olefins, methanol, and acetaldehyde have been proposed. Rate data were obtained between 448 and 548K, 1 and 10 atm, and H/sub 2//CO ratios between 1 and 3, utilizing a micro flow reactor operated at very low conversions. In addition to the studies performed with H/sub 2//CO mixtures, a series of experiments were carried out utilizing D/sub 2//CO mixtures. These studies were used to help identify rate limited steps and steps that were at equilibrium. A complementary investigation, carried out by in situ infrared spectroscopy, was performed using a Fourier Transform spectrometer. The spectra obtained were used to identify the modes of CO adsorption, the CO coverage, and the relative reactivity of different forms of adsorbed CO. It was established that CO adsorbs on alumina-supported Ru in, at least, two forms: (i) Ru-CO and (ii) OC-Ru-CO. Only the first of these forms participates in CO hydrogenation. The coverage of this species is described by a simple Langmuir isotherm. A reaction mechanism is presented for interpreting the kinetics of hydrocarbon synthesis, the olefin to paraffin ratio for each product, and the probability of chain propagation. Rate expressions based on this mechanism are reasonably consistent with the experimental data. Acetaldehyde, obtained mainly over silica-supported Ru, appears to be formed by a mechanism related to that for hydroformulation of olefins. The effect of the dispersion of Ru/Al/sub 2/O/sub 3/ catalysts on their specific activity and selectivity was also investigated. The specific activity for all products decreased rapidly with increasing dispersions.

  4. Thermodynamic optimization of biomass gasification for decentralized power generation and Fischer-Tropsch synthesis

    International Nuclear Information System (INIS)

    In recent years, biomass gasification has emerged as a viable option for decentralized power generation, especially in developing countries. Another potential use of producer gas from biomass gasification is in terms of feedstock for Fischer-Tropsch (FT) synthesis - a process for manufacture of synthetic gasoline and diesel. This paper reports optimization of biomass gasification process for these two applications. Using the non-stoichometric equilibrium model (SOLGASMIX), we have assessed the outcome of gasification process for different combinations of operating conditions. Four key parameters have been used for optimization, viz. biomass type (saw dust, rice husk, bamboo dust), air or equivalence ratio (AR = 0, 0.2, 0.4, 0.6, 0.8 and 1), temperature of gasification (T = 400, 500, 600, 700, 800, 900 and 1000 oC), and gasification medium (air, air-steam 10% mole/mole mixture, air-steam 30%mole/mole mixture). Performance of the gasification process has been assessed with four measures, viz. molar content of H2 and CO in the producer gas, H2/CO molar ratio, LHV of producer gas and overall efficiency of gasifier. The optimum sets of operating conditions for gasifier for FT synthesis are: AR = 0.2-0.4, Temp = 800-1000 oC, and gasification medium as air. The optimum sets of operating conditions for decentralized power generation are: AR = 0.3-0.4, Temp = 700-800 oC with gasification medium being air. The thermodynamic model and methodology presented in this work also presents a general framework, which could be extended for optimization of biomass gasification for any other application.

  5. An investigation of the physical and chemical changes occuring in a Fischer-Tropsch fixed bed catalyst during hydrocarbon synthesis

    International Nuclear Information System (INIS)

    Deactivation studies: making use of fixed bed reactors, wet chemical analysis, surface area, pore volume determinations and X-ray diffraction spectrometry, scanning electron microscope spectrometry and secondary ion mass spectrometry techniques; were performed on a low temperature iron Fischer-Tropsch catalyst. It was revealed that this catalyst is mainly deactivated by sulphur poisoning, oxidation of the catalytic reactive phases, sintering of the iron crystallites and to a lesser extent deactivation through fouling of the catalytic surface by carbonaceous deposits. It was found that the top entry section of the catalyst bed deactivated relatively fast, the bottom exit section also deactivated, but not as fast as the top section. The central portion of the catalyst bed was least affected. Sulphur contaminants in the feed gas, even though present in only minute quantities, results in a loss of catalyst performance of the top section of the catalyst bed, while water, produced as a product from the Fischer-Tropsch reaction, oxidized and sintered the catalyst over the bottom section of the catalyst bed. 88 figs., 7 tabs., 224 refs

  6. Fuzzy model prediction of Co (Ⅲ)/Al2O3 catalytic behavior in Fischer-Tropsch synthesis

    Institute of Scientific and Technical Information of China (English)

    Mohammad Ali Takassi; Mahdi Koolivand Salooki; Morteza Esfandyari

    2011-01-01

    The application of Co (Ⅲ)/Al2O3 catalyst in Fischer-Tropsch synthesis (FTS) was studied in a wide range of synthesis gas conversions and compared with Fuzzy Simulation results.Present study applies fuzzy model to predicting the product composition of CH4,CO2 and CO in Fischer-Tropsch process for natural gas synthesis,in which the input vector was 4-dimension including four variables (operating pressure,operating temperature,time and CO/H2 ratio) of 70 different experim.ents and the output product is a composition of CO2,CO and CH4.The Mamdani algorithm has been applied to the training of the fuzzy system and the test set was used to evaluate the performance of the system including R2,ARE,AARE and SD.The results demonstrated that the predicted values from the model were in good consistency with the experimental data.The work indicates how fuzzy inference system (FIS),as a promising predicting technique,would be effectively used in FTS.

  7. Combined EXAFS and STEM-EELS study of the electronic state and location of Mn as promoter in Co-based Fischer-Tropsch catalysts

    NARCIS (Netherlands)

    Morales, F; Grandjean, D; de Groot, FMF; Stephan, O; Weckhuysen, BM

    2005-01-01

    STEM-EELS and EXAFS have been used to investigate the location and electronic state of Mn as promoter in TiO2- supported cobalt Fischer Tropsch catalysts prepared by two different procedures. It was found that the extent of interaction between Mn and the active Co phase as well as the level of Mn di

  8. Moessbauer study of iron-carbide growth and Fischer-Tropsch activity

    Energy Technology Data Exchange (ETDEWEB)

    Rao, K.R.P.M.; Huggins, F.E.; Huffman, G.P. [Univ. of Kentucky, Lexington, (United States)] [and others

    1995-12-31

    There is a need to establish a correlation between the Fischer-Tropsch (FT) activity of an iron-based catalyst and the catalyst phase during FT synthesis. The nature of iron phases formed during activation and FT synthesis is influenced by the nature of the gas and pressure apart from other parameters like temperature, flow rate etc., used for activation. Moessbauer investigations of iron-based catalysts subjected to pretreatment at two different pressures in gas atmospheres containing mixtures of CO, H{sub 2}, and He have been carried out. Studies on UCI 1185-57 (64%Fe{sub 2}O{sub 3}/5%CuO/1%K{sub 2}O/30% Kaolin) catalyst indicate that activation of the catalyst in CO at 12 atms. leads to the formation of 100% magnetite and the magnetite formed gets rapidly converted to at least 90% of {chi}-Fe{sub 5}C{sub 2} during activation. The FT activity was found to be good at 70-80% of (H{sub 2}+CO) conversion. On the other hand, activation. The FT activity was found to be good at 70-80% of (H{sub 2}+CO) conversion. On the other hand, activation of the catalyst in synthesis gas at 12 atms. leads to formation of Fe{sub 3}O{sub 4} and it gets sluggishly converted to {chi}-Fe{sub 5}C{sub 2} and {epsilon}-Fe{sub 2.2}C during activation and both continue to grow slowly during FT synthesis. FT activity is found to be poor. Pretreatment of the catalyst, 100fe/3.6Si/0.71K at a low pressure of 1 atms. in syngas gave rise to the formation of {chi}-Fe{sub 5}C{sub 2} and good FT activity. On the other hand, pretreatment of the catalyst, 100Fe/3.6Si/0.71K at a relatively high pressure of 12 atms. in syngas did not give rise to the formation any carbide and FT activity was poor.

  9. PROGRESS TOWARDS MODELING OF FISCHER TROPSCH SYNTHESIS IN A SLURRY BUBBLE COLUMN REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    Donna Post Guillen; Tami Grimmett; Anastasia M. Gandrik; Steven P. Antal

    2010-11-01

    The Hybrid Energy Systems Testing (HYTEST) Laboratory is being established at the Idaho National Laboratory to develop and test hybrid energy systems with the principal objective to safeguard U.S. Energy Security by reducing dependence on foreign petroleum. A central component of the HYTEST is the slurry bubble column reactor (SBCR) in which the gas-to-liquid reactions will be performed to synthesize transportation fuels using the Fischer Tropsch (FT) process. SBCRs are cylindrical vessels in which gaseous reactants (for example, synthesis gas or syngas) is sparged into a slurry of liquid reaction products and finely dispersed catalyst particles. The catalyst particles are suspended in the slurry by the rising gas bubbles and serve to promote the chemical reaction that converts syngas to a spectrum of longer chain hydrocarbon products, which can be upgraded to gasoline, diesel or jet fuel. These SBCRs operate in the churn-turbulent flow regime which is characterized by complex hydrodynamics, coupled with reacting flow chemistry and heat transfer, that effect reactor performance. The purpose of this work is to develop a computational multiphase fluid dynamic (CMFD) model to aid in understanding the physico-chemical processes occurring in the SBCR. Our team is developing a robust methodology to couple reaction kinetics and mass transfer into a four-field model (consisting of the bulk liquid, small bubbles, large bubbles and solid catalyst particles) that includes twelve species: (1) CO reactant, (2) H2 reactant, (3) hydrocarbon product, and (4) H2O product in small bubbles, large bubbles, and the bulk fluid. Properties of the hydrocarbon product were specified by vapor liquid equilibrium calculations. The absorption and kinetic models, specifically changes in species concentrations, have been incorporated into the mass continuity equation. The reaction rate is determined based on the macrokinetic model for a cobalt catalyst developed by Yates and Satterfield [1]. The

  10. KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS. FOURTH ANNUAL TECHNICAL PROGRESS REPORT

    International Nuclear Information System (INIS)

    This report covers the fourth year of a research project conducted under the University Coal Research Program. The overall objective of this project is to develop a comprehensive kinetic model for slurry-phase Fischer-Tropsch synthesis (FTS) employing iron-based catalysts. This model will be validated with experimental data obtained in a stirred-tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict molar flow rates and concentrations of all reactants and major product species (water, carbon dioxide, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the fourth year of the project, an analysis of experimental data collected during the second year of this project was performed. Kinetic parameters were estimated utilizing product distributions from 27 mass balances. During the reporting period two kinetic models were employed: a comprehensive kinetic model of Dr. Li and co-workers (Yang et al., 2003) and a hydrocarbon selectivity model of Van der Laan and Beenackers (1998, 1999) The kinetic model of Yang et al. (2003) has 24 parameters (20 parameters for hydrocarbon formation, and 4 parameters for the water-gas-shift (WGS) reaction). Kinetic parameters for the WGS reaction and FTS synthesis were estimated first separately, and then simultaneously. The estimation of these kinetic parameters employed the Levenberg-Marquardt (LM) method and the trust-region reflective Newton large-scale (LS) method. A genetic algorithm (GA) was incorporated into estimation of parameters for FTS reaction to provide initial estimates of model parameters. All reaction rate constants and activation energies were found to be positive, but at the 95% confidence level the intervals were large. Agreement between predicted and experimental reaction rates has been fair to good. Light hydrocarbons are predicted fairly accurately, whereas the model underpredicts values of higher molecular weight

  11. New perspectives in the Fischer-Tropsch synthesis using cobalt supported on mesoporous molecular sieves; Novas perspectivas na sintese de Fischer-Tropsch usando cobalto suportado em peneiras moleculares mesoporosas

    Energy Technology Data Exchange (ETDEWEB)

    Souza, M.J.B.; Silva, A.O.S. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Dept. de Engenharia Quimica; Fernandes Junior, V.J.; Araujo, A.S. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Dept. de Quimica

    2004-07-01

    The conversion of synthesis gas to liquid products via Fischer-Tropsch synthesis (FTS) is an important process in the generation of clean fuels of sulfur and nitrogen compounds. Catalysts based on iron are very used in the conventional process due its cheap manufacture price. Recently the use of cobalt as promoter gave good results. MCM-41 mesoporous materials were discovered by Mobil scientists in the nineties and ever since they have great successes as support and catalyst in several processes of the oil industry as catalytic cracking, reformer and hydrotreating. In this work are presented new alternatives for FTS with the use of cobalt supported on molecular sieves of the type MCM-41. A comparative study with the usual catalysts based on silica was accomplished with different levels of cobalt. (author)

  12. A preliminary plant design study for the production of diesel from coal via fischer-tropsch synthesis

    International Nuclear Information System (INIS)

    Pakistan's reliance on conventional means of producing energy has proven to be an inadequate strategy for overcoming it. The situation direly demands diversification of our energy resources not only to overcome current fiasco but also in planning for future. Among the other alternative sources, coal is the main source for producing cheaper electricity being available as huge reserves. This paper presents the preliminary plant design and cost estimation for the production of diesel from coal via coal gasification and fischer-Tropschs synthesis. Prelimnary design calculations and cost estimation are presented along with underlying assumptions. The results reveal that the diesel produced from this process might be cheaper than the crude oil based diesel. (author)

  13. Fischer-Tropsch synthesis over ruthenium-promoted Co/Al2O3 catalyst with different reduction procedures

    Institute of Scientific and Technical Information of China (English)

    Ali Karimi; Ali Nakhaei Pour; Farshad Torabi; Behnam Hatami; Ahmad Tavasoli; Mohammad Reza Alaei; Mohammad Irani

    2010-01-01

    The effect of reduction procedure on catalyst properties,activity and products selectivity of ruthenium-promoted Co/γ-Al2O3 catalyst in Fischer-Tropsch synthesis(FTS)was investigated.Catalyst samples were reduced with different reduction gas compositions and passivated before being characterized by TPR and XRD techniques.Different activity and product selectivity analyses were also performed.These results showed that the catalyst dispersion,particle size,and the degree of reduction changed with different reduction gas compositions,which were resulted from the water partial pressures in reduction process that give varying degrees of interaction with the support.It has been suggested that the FTS activity of cobalt catalyst was directly dependent on the catalyst reducibility.A reduction gas with a molar ratio of H2/He = 1 was used to prevent the formation of Co-support compound during catalyst reduction.

  14. Studies on the Role of Nitrogen in the Feed for Fischer-Tropsch Synthesis Under Fixed-Bed Reactor System.

    Science.gov (United States)

    Hong, Gi Hoon; Jung, Jae-Sun; Kim, Na-Young; Lee, Sang Yong; Moon, Dong Ju

    2016-02-01

    In this study, Co/Al203 catalyst for Fischer-Tropsch synthesis was prepared via slurry impregnation method and the catalyst was characterized by various techniques such as TPR, XRD, TGA and N2 physisorption. To dissolve the wax, after-reaction catalyst was dewaxed using n-Hexane at 60 *C. The experiments were performed in a bench-scale fixed-bed reactor, under the reaction condition of 230 degrees C, 20 bar and feed volume ratio of H2:CO:N2 = 2:1:0.5-1.5. The methane selectivity and the ratio of olefin to paraffin among C2-C4 hydrocarbons were increased with higher contents of nitrogen in feed gas which result in higher partial pressure ratio of H2 to CO, and also affect methane selectivity which has a significant role in increased CO conversion. PMID:27433695

  15. Effect of Surface Modification by Chelating Agents on Fischer- Tropsch Performance of Co/SiO{sub 2} Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Bambal, Ashish S.; Kugler, Edwin L.; Gardner, Todd H.; Dadyburjor, Dady B.

    2013-11-14

    The silica support of a Co-based catalyst for Fischer-Tropsch (FT) synthesis was modified by the chelating agents (CAs) nitrilotriacetic acid (NTA) and ethylenediaminetetraacetic acid (EDTA). After the modification, characterization of the fresh and spent catalysts show reduced crystallite sizes, a better-dispersed Co₃O₄ phase on the calcined samples, and increased metal dispersions for the reduced samples. The CA-modified catalysts display higher CO conversions, product yields, reaction rates and rate constants. The improved FT performance of CA-modified catalysts is attributed to the formation of stable complexes with Co. The superior performance of the EDTA-modified catalyst in comparison to the NTA-modified catalyst is due to the higher affinity of the former for complex formation with Co ions.

  16. TPR and TPD studies of effects of Cu and Ca promotion on Fe-Zn-based Fischer-Tropsch catalysts

    Indian Academy of Sciences (India)

    Olusola O James; Biswajit Chowdhury; Sudip Maity

    2013-05-01

    Temperature-programmed reduction (TPR) and temperature-programmed desorption (TPD) were used to study the effects of Cu and Ca promotion on Fe-Zn-based Fischer-Tropsch catalysts. The reduction temperature for Fe2O3 → Fe3O4 was unaffected by Ca addition but decreased when promoted with Cu. Fe-Zn promoted with Cu and Ca showed even much lower reduction temperature for Fe2O3→Fe3O4. Ca promotion enhances carburization and increases surface acidity and basicity of the Fe-Zn oxide precursor. While Cu inhibits carburization and decreases the surface acidity and basicity of the Fe-Zn oxide precursor. The implications of these effects on the application of catalysts for FT are discussed.

  17. Effect of operating conditions and potassium content on Fischer-Tropsch liquid products produced by potassium-promoted iron catalysts

    Institute of Scientific and Technical Information of China (English)

    Francisco E. M. Farias; Fernando G. Sales; Fabiano A. N. Fernandes

    2008-01-01

    The dependencies of Fischer-Tropsch synthesis liquid hydrocarbon product distribution on operating pressure and temperature have been studied over three potassium-promoted iron catalysts with increasing potassium molar content. The study followed an experimental planning and the results were analyzed based on surface response methodology. The effects of different operating conditions and potassium contents on the liquid product distribution were compared based on number average carbon number and dispersion. Results showed that high pressures (25 to 30 atm) favored the production of waxes that could be converted into liquid fuels through hydrocracking, while greater direct selectivity towards diesel was favored by low pressure (20 atm) using catalysts with low potassium to iron molar ratios. The liquid product distribution produced using an iron catalyst with high potassium content presented higher number-average number of carbons when compared to the distribution obtained using an iron catalyst with low potassium content.

  18. Preparation, characterization and testing of SiC-based catalytic sponges as structured catalysts for Fischer-Tropsch synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Baudry, A.; Schaub, G. [Karlsruhe Institute of Technology (KIT), Karlsruhe (Germany). Engler-Bunte-Inst.

    2011-07-01

    Solid sponges (open-cell foams) may be used as catalyst support, due to favorable thermal properties and low pressure drop. As an example, they may lead to improved temperature control in Fischer-Tropsch applications, if compared to fixed beds of catalyst particles. The aim of this study was to develop and test a wet method for impregnating ceramic foam materials with a CoRe/{gamma}-Al{sub 2}O{sub 3} catalyst. Defined catalyst layers were generated on 20 ppi SiC-sponges. Resulting catalytic activities are nearly identical to those of the corresponding powder catalyst material. The difference observed can be explained by either mass transfer limitation or backmixing in the fixed bed configuration used. (orig.)

  19. Ultra-clean Fischer-Tropsch (F-T) Fuels Production and Demonstration Project

    Energy Technology Data Exchange (ETDEWEB)

    Stephen P. Bergin

    2006-06-30

    The objective of the DOE-NETL Fischer-Tropsch (F-T) Production and Demonstration Program was to produce and evaluate F-T fuel derived from domestic natural gas. The project had two primary phases: (1) fuel production of ultra-clean diesel transportation fuels from domestic fossil resources; and (2) demonstration and performance testing of these fuels in engines. The project also included a well-to-wheels economic analysis and a feasibility study of small-footprint F-T plants (SFPs) for remote locations such as rural Alaska. During the fuel production phase, ICRC partnered and cost-shared with Syntroleum Corporation to complete the mechanical design, construction, and operation of a modular SFP that converts natural gas, via F-T and hydro-processing reactions, into hydrogensaturated diesel fuel. Construction of the Tulsa, Oklahoma plant started in August 2002 and culminated in the production of over 100,000 gallons of F-T diesel fuel (S-2) through 2004, specifically for this project. That fuel formed the basis of extensive demonstrations and evaluations that followed. The ultra-clean F-T fuels produced had virtually no sulfur (less than 1 ppm) and were of the highest quality in terms of ignition quality, saturation content, backend volatility, etc. Lubricity concerns were investigated to verify that commercially available lubricity additive treatment would be adequate to protect fuel injection system components. In the fuel demonstration and testing phase, two separate bus fleets were utilized. The Washington DC Metropolitan Area Transit Authority (WMATA) and Denali National Park bus fleets were used because they represented nearly opposite ends of several spectra, including: climate, topography, engine load factor, mean distance between stops, and composition of normally used conventional diesel fuel. Fuel evaluations in addition to bus fleet demonstrations included: bus fleet emission measurements; F-T fuel cold weather performance; controlled engine dynamometer

  20. Quantification of trace O-containing compounds in GTL process samples via Fischer-Tropsch reaction by comprehensive two-dimensional gas chromatography/mass spectrometry.

    Science.gov (United States)

    Fernandes, Daniella R; Pereira, Vinícius B; Stelzer, Karen T; Gomes, Alexandre O; Neto, Francisco R Aquino; Azevedo, Débora A

    2015-11-01

    Comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (GC×GC-TOFMS) was successfully applied to eight real Brazilian Fischer-Tropsch (FT) product samples for the quantitative analysis of O-containing compounds. It not only allowed identifying and quantifying simultaneously a large number of O-containing compounds but also resolved many co-eluting components, such as carboxylic acids, which co-elute in one-dimensional gas chromatography. The homologous series of alcohols and carboxylic acids as trimethylsilyl derivatives were detected and identified at trace levels. The absolute quantification of each compound was accomplished with reliability using analytical curves. Linear alcohols (from C5 to C19), branched alcohols (C6-C13) and carboxylic acids (C4 to C12) were obtained in the range of 1.58 mg g(-1) to 14.75 mg g(-1), 0.51 mg g(-1) to 1.12 mg g(-1) and 0.21 mg g(-1) to 1.63 mg g(-1) of FT product samples, respectively. GC×GC-TOFMS provided a linear range (from 0.3 ng µL(-1) to 10 ng µL(-1)), good precision (<8%), and excellent accuracy (recovery range of 77% to 118%) for quantification of individual O-containing compounds in FT product samples. The results can benefit the development of gas-to-liquid technologies from natural gas and guide the choice of an FT conversion process that generates clean products with higher added value. PMID:26452870

  1. Ruthenium Modification on Mn and Zr-Modified Co/SiO2 Catalysts for Slurry-Phase Fischer-Tropsch Synthesis

    Directory of Open Access Journals (Sweden)

    Tomohisa Miyazawa

    2015-01-01

    Full Text Available The addition of Ru to Mn and Zr-modified Co/SiO2 catalysts, while applying different preparation orders and loading amounts, was investigated as a means of enhancing the Fischer-Tropsch synthesis reaction. The coimpregnation of Zr/SiO2 with Co, Mn and Ru gave the most attractive catalytic properties. This can be attributed to the higher dispersion of Co metal resulting from the coimpregnation of Co and Mn as well as enhanced reducibility due to the presence of Ru. The addition of a moderate amount of Ru together with the appropriate order of addition affected both the Co reducibility and the catalytic activity, primarily because of increased reducibility. The addition of even 0.1 wt.% Ru resulted in an obvious enhancement of Fischer-Tropsch synthesis activity.

  2. Comparative study of regulated and unregulated gaseous emissions during NEDC in a light-duty diesel engine fuelled with Fischer Tropsch and biodiesel fuels

    OpenAIRE

    2010-01-01

    Abstract In this study, regulated and unregulated gaseous emissions and fuel consumption with five different fuels were tested in a 4-cylinder, light-duty diesel EURO IV typically used for the automotive vehicles in Europe. Three different biodiesel fuels obtained from soybean oil, rapeseed oil and palm oil, a Fischer Tropsch fuel and an ultra low sulphur diesel were studied. The test used was the New European Driving Cycle (NEDC), this allowed tests to be carried out on an engine ...

  3. Influencia del soporte catalítico en la producción de combustibles sintéticos vía Fischer-Tropsch

    OpenAIRE

    Díaz López, José Antonio

    2014-01-01

    The present work is part of a research program that deals with the study of catalysts and their use in high-pressure reactions of industrial interest that is being developed in the Department of Chemical Engineering at the University of Castilla-la Mancha. Fischer-Tropsch synthesis (FTS) is a heterogeneously catalyzed polymerization process, which converts syngas (CO and H2) into a wide variety of hydrocarbons. In this reaction, a great number of desired (paraffins, olefins and alcohols) ...

  4. Model studies of secondary hydrogenation in Fischer-Tropsch synthesis studied by cobalt catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Aaserud, Christian

    2003-07-01

    Mass transfer effects are very important in Fischer-Tropsch (FT) synthesis. In order to study the FT synthesis without the influence of any transport limitations, cobalt foils have been used as model catalysts. The effect of pretreatment (number of calcinations and different reduction times) for cobalt foil catalysts at 220 {sup o}C, 1 bar and H{sub 2}/CO = 3 has been studied in a microreactor. The foils were examined by Scanning electron microscopy (SEM). It was found that the catalytic activity of the cobalt foil increases with the number of pretreatments possibly due to an increase in the surface area of the cobalt foil. The SEM results support the assumption that the surface area of the cobalt foil increases with the number of pretreatments. The reduction time was also found to influence the catalytic activity of the cobalt foil. Highest activity was obtained using a reduction time of only five min (compared to one and thirty min). The decrease in activity after reduction for thirty min compared to five min was suggested to be due to restructuring of the surface of the cobalt foil and a reduction time of only 1 min was not enough to reduce the cobalt foil sufficiently. Time of reduction did also influence the product distribution. Increased reduction time resulted in a lower selectivity to light products and increased selectivity to heavier components. The paraffin/olefin ratio increased with increasing CO-conversion also for cobalt foils. The paraffin/olefin ratio also increased when the reduction period of the cobalt foil was increased at a given CO-conversion. Hydrogenation of propene to propane has been studied as a model reaction for secondary hydrogenation of olefins in the FT synthesis. The study has involved promoted and unpromoted cobalt FT catalysts supported on different types of supports and also unsupported cobalt. Hydrogenation of propene was carried out at 120 {sup o}C, 1.8 bar and H{sub 2}/C{sub 3}H{sub 6} 6 in a fixed bed microreactor. The rate

  5. Study of (Fe/HZM-5) catalyst be used in the Fischer-Tropsch synthesis: preparation and characterization; Estudo do catalisador (Fe/HZSM-5) a ser utilizado na sintese de Fischer-Tropsch: preparacao e caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    Gonzaga, Arthur C. [Universidade Estadual do Maranhao (UEMA0), MA (Brazil); Sousa, Bianca V. de; Lima, Wellington S.; Rodrigues, Meiry G.F. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia Quimica

    2008-07-01

    In this work it was developed an iron catalyst supported on the ZSM-5 zeolite to be used in the Fischer-Tropsch Synthesis (FTS). The NH{sub 4}{sup +}ZSM-5 zeolitic support was submitted to the wet impregnation, using the 0.1 M of the Fe(NO{sub 3}){sub 3}.9H{sub 2}O solution to obtain the Fe/NH{sub 4}{sup +}ZSM-5 sample in the content of iron 5% wt. After, the material was submitted for the drying process and in the following, for the calcination one, obtaining the Fe/HZSM-5 form. The EDS characterization analyses showed that in the Fe/HZSM-5 sample the iron is in the Fe{sub 2}O{sub 3} form and that the impregnation and calcination processes did not cause significant exchanges in the zeolitic support framework. The results of the N{sub 2} physical adsorption of the 5% Fe/HZSM-5 showed the presence of the micropores and mesopores. From these results, the obtained material (5% Fe/HZSM-5) presents a great potential to be used like a catalyst in the FTS. (author)

  6. Studies on accelerated deactivation of ruthenium-promoted alumina-supported alkalized cobalt Fischer-Tropsch synthesis catalyst

    Institute of Scientific and Technical Information of China (English)

    Shohreh Tehrani; Mohamad Irani; Ahmad Tavasoli; Yadollah Mortazavi; Abbas A.Khodadadi; Ali Nakhaei Pour

    2011-01-01

    Accelerated deactivation of ruthenium-promoted alumina-supported alkalized cobalt(K-Ru-Co/-γ-Al2O3)Fischer-Tropsch(FT)synthesis catalyst along the catalytic bed over 120 h of time-on-stream(TOS)was investigated.Catalytic bed was divided into three parts and structural changes of the spent catalysts collected from each catalytic bed after FT synthesis were studied using different techniques.Rapid deactivation was observed during the reaction due to high reaction temperature and low feed flow rates.The physico-chemical properties of the catalyst charged in the Bed #1 of the reactor did not change significantly.Interaction of cobalt with alumina and the formation of CoAl2O4 increased along the catalytic bed.Reducibility percentage decreased by 4.5%,7.5% and 12.9% for the catalysts in the Beds #1,#2 and #3,respectively.Dispersion decreased by 8.8%,14.4% and 26.6% for the catalysts in the Beds #1,#2 and #3,respectively.Particle diameter increased by 0.6%,2.4% and 10.4% for the catalysts in the Beds #1,#2 and #3,respectively,suggesting higher rate of sintering at the last catalytic bed.The amount of coke at the last catalytic bed was significantly higher than those of Beds #1 and #2.

  7. Raising distillate selectivity and catalyst life time in Fischer-Tropsch synthesis by using a novel dual-bed reactor

    International Nuclear Information System (INIS)

    In a novel dual bed reactor Fischer-Tropsch synthesis was studied by using two diff rent cobalt catalysts. An alkali-promoted cobalt catalyst was used in the first bed of a fixed-bed reactor followed by a Raiment promoted cobalt catalyst in the second bed. The activity, product selectivity and accelerated deactivation of the system were assessed and compared with a conventional single bed reactor system. The methane selectivity in the dual-bed reactor was about 18.9% less compared to that of the single-bed reactor. The C5+ selectivity for the dual-bed reactor was 10.9% higher than that of the single-bed reactor. Accelerated deactivation of the catalysts in the dual-bed reactor was 42% lower than that of the single-bed reactor. It was revealed that the amount of catalysts activity recovery after regeneration at 400degC in the dual-bed system is higher than that of the single-bed system

  8. Effect of Potassium Addition on Coprecipitated Iron Catalysts for Fischer-Tropsch Synthesis Using Bio-oil-syngas

    Science.gov (United States)

    Wang, Zhao-xiang; Dong, Ting; Kan, Tao; Li, Quan-xin

    2008-04-01

    The effects of potassium addition and the potassium content on the activity and selectivity of coprecipitated iron catalyst for Fischer-Tropsch synthesis (FTS) were studied in a fixed bed reactor at 1.5 MPa, 300°C, and contact time (W/F) of 12.5 gcath/mol using the model bio-oil-syngas of H2/CO/CO2/N2 (62/8/25/5, vol%). It was found that potassium addition increases the catalyst activity for FTS and the reverse water gas shift reaction. Moreover, potassium increases the average molecular weight (chain length) of the hydrocarbon products. With the increase of potassium content, it was found that CH4 selectivity decreases and the selectivity of liquid phase products (C5+) increases. The characteristics of FTS catalysts with different potassium content were also investigated by various characterization measurements including X-ray diffraction, X-ray photoelectron spectroscopy and Brunauer-Emmett-Teller surface area. Based on experimental results, 100Fe/6Cu/16Al/6K (weight ratio) was selected as the optimal catalyst for FTS from bio-oil-syngas. The results indicate that the 100Fe/6Cu/16Al/6K catalyst is one of the most promising candidates to directly synthesize liquid bio-fuel using bio-oil-syngas.

  9. Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis of liquid fuels from coal to minimize carbon dioxide emissions

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman [University of Kentucky, Lexington, KY (United States). Consortium for Fossil Fuel Science and Department of Chemical & Materials Engineering

    2011-08-15

    Synthesis gas (syngas) produced from coal typically has hydrogen to carbon monoxide ratios in the range of approximately 0.7-1.1, depending on the gasification method. In order to produce liquid fuels from this syngas by Fischer-Tropsch synthesis (FTS), these ratios must be raised to 2.0 or higher. If this is accomplished by the water-gas shift reaction, the traditional method, large emissions of carbon dioxide are produced. In this paper, it is shown that catalytic dehydrogenation (CDH) of the gaseous C1-C4 products of FT synthesis and recycling of the resulting hydrogen to the syngas feed-stream can increase the H{sub 2}/CO ratio to the desired values with little or no production of carbon dioxide. All carbon from the CDH reaction is in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWCNT). The amounts of hydrogen and MWCNT produced, carbon dioxide emissions avoided, and water saved are calculated for a 50,000 bbl/day FTS-CDH plant and it is demonstrated that the energy balance for the process is favorable. Methods of utilizing the large quantity of MWCNT produced are discussed. 50 refs., 6 figs., 3 tabs.

  10. Organic Analysis of Catalytic Fischer-Tropsch Type Synthesis Products: Are they Similar to Organics in Chondritic Meteorites?

    Science.gov (United States)

    Yazzie, Cyriah A.; Locke, Darren R.; Johnson, Natasha M.

    2014-01-01

    Fischer-Tropsch Type (FTT) synthesis of organic compounds has been hypothesized to occur in the early solar nebula that formed our Solar System. FTT is a collection of abiotic chemical reactions that convert a mixture of carbon monoxide and hydrogen over nano-catalysts into hydrocarbons and other more complex aromatic compounds. We hypothesized that FTT can generate similar organic compounds as those seen in chondritic meteorites; fragments of asteroids that are characteristic of the early solar system. Specific goals for this project included: 1) determining the effects of different FTT catalyst, reaction temperature, and cycles on organic compounds produced, 2) imaging of organic coatings found on the catalyst, and 3) comparison of organic compounds produced experimentally by FTT synthesis and those found in the ordinary chondrite LL5 Chelyabinsk meteorite. We used Pyrolysis Gas Chromatography Mass Spectrometry (PY-GCMS) to release organic compounds present in experimental FTT and meteorite samples, and Scanning Electron Microscopy (SEM) to take images of organic films on catalyst grains.

  11. Effect of Potassium Addition on Coprecipitated Iron Catalysts for Fischer-Tropsch Synthesis Using Bio-oil-syngas

    Institute of Scientific and Technical Information of China (English)

    Zhao-xiang Wang; Ting Dong; Tao Kan; Quan-xin Li

    2008-01-01

    The effects of potassium addition and the potassium content on the activity and selectivity of coprecipitated iron catalyst for Fischer-Tropsch synthesis (FTS) were studied in a fixed bed reactor at 1.5 MPa,300℃, and contact time (W/F) of 12.5 gcath/mol using the model bio-oil-syngas of H2/CO/CO2/N2 (62/8/25/5, vol%).It was found that potassium addition increases the catalyst activity for FTS and the reverse water gas shift reaction.Moreover,potassium increases the average molecular weight (chain length) of the hydrocarbon products.With the increase of potassium content,it was found that CH4 selectivity decreases and the selectivity of liquid phase products (C5+) increases.The characteristics of FTS catalysts with different potassium content were also investigated by various characterization measurements including X-ray diffraction,X-ray photoelectron spectroscopy and Brunauer-Emmett-Teller surface area.Based on experimental results,100Fe/6Cu/16Al/6K (weight ratio) was selected as the optimal catalyst for FTS from bio-oil-syngas. The results indicate that the 100Fe/6Cu/16Al/6K catalyst is one of the most promising candidates to directly synthesize liquid bio-fuel using bio-oil-syngas.

  12. Incorporation of Reaction Kinetics into a Multiphase, Hydrodynamic Model of a Fischer Tropsch Slurry Bubble Column Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Donna Guillen, PhD; Anastasia Gribik; Daniel Ginosar, PhD; Steven P. Antal, PhD

    2008-11-01

    This paper describes the development of a computational multiphase fluid dynamics (CMFD) model of the Fischer Tropsch (FT) process in a Slurry Bubble Column Reactor (SBCR). The CMFD model is fundamentally based which allows it to be applied to different industrial processes and reactor geometries. The NPHASE CMFD solver [1] is used as the robust computational platform. Results from the CMFD model include gas distribution, species concentration profiles, and local temperatures within the SBCR. This type of model can provide valuable information for process design, operations and troubleshooting of FT plants. An ensemble-averaged, turbulent, multi-fluid solution algorithm for the multiphase, reacting flow with heat transfer was employed. Mechanistic models applicable to churn turbulent flow have been developed to provide a fundamentally based closure set for the equations. In this four-field model formulation, two of the fields are used to track the gas phase (i.e., small spherical and large slug/cap bubbles), and the other two fields are used for the liquid and catalyst particles. Reaction kinetics for a cobalt catalyst is based upon values reported in the published literature. An initial, reaction kinetics model has been developed and exercised to demonstrate viability of the overall solution scheme. The model will continue to be developed with improved physics added in stages.

  13. Purification Influence of Synthesis Gas Derived from Methanol Cracking on the Performance of Cobalt Catalyst in Fischer-Tropsch Synthesis

    Institute of Scientific and Technical Information of China (English)

    Wei Zhou; Shengying Liu; Yulan Wang; Kegong Fang; Jiangang Chen; Yuhan Sun

    2005-01-01

    Synthesis gas derived from methanol cracking (SGMC) was applied as simulating feedstock of Fischer-Tropsch synthesis (FTS) in laboratory. With MS and GC detector, a trifle of sulfur compounds,a small amount of oxygenates including H2O, CH3OH, DME and CO2 as well as a few of low carbon alkanes were found in the SGMC. After purification, the sulfur compounds, H2O, CH3OH and DME could be eliminated efficiently from the SGMC while CO2 and the low carbon alkanes were partly removed.When the unpurified SGMC, the desufurized SGMC and the totally purified SGMC were sequentially applied in cobalt-based FTS, the catalytic performance of Co/ZrO2/SiO2 catalyst was gradually improved corresponding to the degree of purification. The untreated SGMC led to the serious deactivation of the cobalt catalyst, the partially treated SGMC slowed down the deactivation rate and the totally purified SGMC resulted in little deactivation of the catalyst, which was similar to what the pure synthesis gas(the mixture of pure H2 and CO) did. The results indicated that the SGMC should be purified and the purification course used in this paper was effective for the SGMC. Furthermore, the totally purified SGMC could substitute for the pure synthesis gas in cobalt FTS.

  14. Isothermal Kinetics Modelling of the Fischer-Tropsch Synthesis over the Spray-Dried Fe-Cu-K Catalyst

    Institute of Scientific and Technical Information of China (English)

    Xiaohui Guo; Ying Liu; Jie Chang; Liang Bai; Yuanyuan Xu; Hongwei Xiang; Yongwang Li

    2006-01-01

    The isothermal kinetics of the Fischer-Tropsch synthesis (FTS) over Fe-Cu-K spray-dried catalyst was studied in a spinning basket reactor. The experiments were carried out at a constant temperature of 523 K, n(H2)/n(CO) feed ratios of 0.8-2.0, reactor pressures of 1.1-2.5 MPa, and space velocity of 0.556× 10-3 Nm3/kgcat.s. Kinetic model for hydrocarbon formation was derived on the basis of simplified carbide mechanism to reduce the number of parameters. Two individual rate constants for methane and ethene were considered. Furthermore, the model was modified empirically by non-intrinsic effect, such as physisorption and fictitious olefin pressures that were taken into account, and the influences of secondary reaction of α-olefins on product distribution. The simulation results showed that the experimental phenomena of FTS and the deviations from ASF distribution, such as the relatively high yield of methane and low yield of ethene observed experimentally could be depicted basically.

  15. Performance characterization of CNTs and γ-Al2O3 supported cobalt catalysts in Fischer-Tropsch reaction

    International Nuclear Information System (INIS)

    Catalysts were prepared via a wet impregnation method. Different physicochemical properties of the samples were revealed by transmission electron microscope (TEM), temperature programmed reduction (H2-TPR) and carbon dioxide desorption (CO2-desorption). Fischer-Tropsch reaction (FTS) was carried out in a fixed-bed microreactor at 220°C and 1 atm, with H2/CO = 2v/v and space velocity, SV of 12L/g.h for 5 h. Various characterization techniques revealed that there was a stronger interaction between Co and Al2O3 support compared to that of CNTs support. CNTs support increased the reducibility and decreased Co particle size. A significant increase in % CO conversion and FTS reaction rate was observed over CNTs support compared to that of Co/Al2O3. Co/CNTs resulted in higher C5+ hydrocarbons selectivity compared to that of Co/Al2O3 catalyst. CNTs are a better support for Co compared to Al2O3

  16. Determination of the Effect of Coal/Biomass-Derived Syngas Contaminants on the Performance of Fischer-Tropsch and Water-Gas-Shift Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Trembly, Jason; Cooper, Matthew; Farmer, Justin; Turk, Brian; Gupta, Raghubir

    2010-12-31

    Today, nearly all liquid fuels and commodity chemicals are produced from non-renewable resources such as crude oil and natural gas. Because of increasing scrutiny of carbon dioxide (CO{sub 2}) emissions produced using traditional fossil-fuel resources, the utilization of alternative feedstocks for the production of power, hydrogen, value-added chemicals, and high-quality hydrocarbon fuels such as diesel and substitute natural gas (SNG) is critical to meeting the rapidly growing energy needs of modern society. Coal and biomass are particularly attractive as alternative feedstocks because of the abundant reserves of these resources worldwide. The strategy of co-gasification of coal/biomass (CB) mixtures to produce syngas for synthesis of Fischer-Tropsch (FT) fuels offers distinct advantages over gasification of either coal or biomass alone. Co-feeding coal with biomass offers the opportunity to exploit economies of scale that are difficult to achieve in biomass gasification, while the addition of biomass to the coal gasifier feed leverages proven coal gasification technology and allows CO{sub 2} credit benefits. Syngas generated from CB mixtures will have a unique contaminant composition because coal and biomass possess different concentrations and types of contaminants, and the final syngas composition is also strongly influenced by the gasification technology used. Syngas cleanup for gasification of CB mixtures will need to address this unique contaminant composition to support downstream processing and equipment. To investigate the impact of CB gasification on the production of transportation fuels by FT synthesis, RTI International conducted thermodynamic studies to identify trace contaminants that will react with water-gas-shift and FT catalysts and built several automated microreactor systems to investigate the effect of single components and the synergistic effects of multiple contaminants on water-gas-shift and FT catalyst performance. The contaminants

  17. Effect of K promoter on the structure and catalytic behavior of supported iron-based catalysts in fischer-tropsch synthesis

    Directory of Open Access Journals (Sweden)

    F. E. M Farias

    2011-09-01

    Full Text Available Effects of K addition on the performance of supported Fe catalysts for Fischer - Tropsch synthesis (FTS were studied in a slurry reactor at 240 to 270ºC, 2.0 to 4.0 MPa and syngas H2/CO = 1.0. The catalysts were characterized by N2 adsorption, H2 temperature programmed reduction, X - ray diffraction, X - ray fluorescence, thermogravimetric analysis, scanning electron microscopy and dispersive X - ray spectroscopy. A strong interaction was observed between Fe and K, which inhibited the reduction of Fe catalyst. Addition of potassium increased the production of heavy hydrocarbons (C20+.

  18. Lump Kinetic Analysis of Syngas Composition Effect on Fischer-Tropsch Synthesis over Cobalt and Cobalt-Rhenium Alumina Supported Catalyst

    Directory of Open Access Journals (Sweden)

    Dewi Tristantini

    2016-03-01

    Received: 10th November 2015; Revised: 10th February 2016; Accepted: 16th February 2016 How to Cite: Tristantini, D., Suwignjo, R.K. (2016. Lump Kinetic Analysis of Syngas Composition Effect on Fischer-Tropsch Synthesis over Cobalt and Cobalt-Rhenium Alumina Supported Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1: 84-92. (doi:10.9767/bcrec.11.1.424.84-92 Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.1.424.84-92

  19. Effects of Catalyst Preparation on Hydrocarbon Product Distribution in Hydrocracking of the Fischer-Tropsch Product with Low Pt-Loaded Catalysts

    OpenAIRE

    Toshiaki Hanaoka; Tomohisa Miyazawa; Katsuya Shimura; Satoshi Hirata

    2015-01-01

    For the effective production of hydrocarbon liquid fuel in the hydrocracking of the Fischer-Tropsch (FT) product, the catalytic performance of Pt-loaded catalysts with low Pt content was investigated using an autoclave at 250 °C, an initial H2 pressure of 0.5 MPa, and a reaction time of 1 h. A screening study using Pt-loaded catalysts with a Pt content of 0.1 wt. % indicated that zeolite supports were more favorable for jet fuel (carbon numbers 9–15) production than amorphous oxide supports....

  20. Kinetically Relevant Steps and H2/D2 Isotope Effects in Fischer-Tropsch Synthesis on Fe and Co Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Ojeda, Manuel; Li, Anwu; Nabar, Rahul P.; Nilekar, Anand U.; Mavrikakis, Manos; Iglesia, Enrique

    2010-11-25

    H2/D2 isotope effects on Fischer-Tropsch synthesis (FTS) rate and selectivity are examined here by combining measured values on Fe and Co at conditions leading to high C5+ yields with theoretical estimates on model Fe(110) and Co(0001) surfaces with high coverages of chemisorbed CO (CO*). Inverse isotope effects (rH/rD < 1) are observed on Co and Fe catalysts as a result of compensating thermodynamic (H2 dissociation to H*; H* addition to CO* species to form HCO*) and kinetic (H* reaction with HCO*) isotope effects. These isotopic effects and their rigorous mechanistic interpretation confirm the prevalence of H-assisted CO dissociation routes on both Fe and Co catalysts, instead of unassisted pathways that would lead to similar rates with H2 and D2 reactants. The small contributions from unassisted pathways to CO conversion rates on Fe are indeed independent of the dihydrogen isotope, as is also the case for the rates of primary reactions that form CO2 as the sole oxygen rejection route in unassisted CO dissociation paths. Isotopic effects on the selectivity to C5+ and CH4 products are small, and D2 leads to a more paraffinic product than does H2, apparently because it leads to preference for chain termination via hydrogen addition over abstraction. These results are consistent with FTS pathways limited by H-assisted CO dissociation on both Fe and Co and illustrate the importance of thermodynamic contributions to inverse isotope effects for reactions involving quasi-equilibrated H2 dissociation and the subsequent addition of H* in hydrogenation catalysis, as illustrated here by theory and experiment for the specific case of CO hydrogenation.

  1. Effect of mass transfer limitations on catalyst performance during reduction and carburization of iron based Fischer-Tropsch synthesis catalysts

    Institute of Scientific and Technical Information of China (English)

    Akbar; Zamaniyan; Yadollah; Mortazavi; Abbas; Ali; Khodadadi; Ali; Nakhaei; Pour

    2013-01-01

    Existence of intraparticle mass transfer limitations under typical Fischer-Tropsch synthesis has been reported previously,but there is no suitable study on the existence of intraparticle diffusion limitations under pretreatment steps (reduction and activation) and their effect on catalytic performance for iron based catalysts.In this study,Fe-Cu-La-SiO2 catalysts were prepared by co-precipitation method.To investigate the intraparticle mass transfer limitation under reduction,activation and reaction steps,and its effect on catalytic performance,catalyst pellets with different sizes of 6,3,1 and 0.5 mm have been prepared.All catalysts were calcined,pretreated and tested under similar conditions.The catalysts were activated in hydrogen (5%H2in N2) at 450℃ for 3 h and exposed to syngas (H2/CO=1) at 270℃ and atmospheric pressure for 40 h.Afterwards,FTS reaction tests were performed for approximately 120 h to reach steady state conditions at 290℃,17 bar and a feed flow (syngas H2/CO=1) rate of 3 L/h (STP).Using small pellets resulted in higher CO conversion,FT reaction rate and C5+ productivity as compared with larger pellets.The small pellets reached steady state conditions just 20 h after starting the reaction.Whereas for larger pellets,CO conversion,FT reaction rate and C5+ productivity increased gradually,and reached steady state and maximum values after 120 h of operation.The results illustrate that mass transfer limitations exist not only for FTS reaction but also for the reduction and carburization steps which lead to various phase formation through catalyst activation.Also the results indicate that some effects of mass transfer limitations in activation step,can be compensated in the reaction step.The results can be used for better design of iron based catalyst to improve the process economy.

  2. Comparative study of regulated and unregulated gaseous emissions during NEDC in a light-duty diesel engine fuelled with Fischer Tropsch and biodiesel fuels

    Energy Technology Data Exchange (ETDEWEB)

    Bermudez, Vicente; Lujan, Jose M.; Pla, Benjamin; Linares, Waldemar G. [CMT-Motores Termicos, Universidad Politecnica de Valencia, Camino de Vera s/n, 46022 Valencia (Spain)

    2011-02-15

    In this study, regulated and unregulated gaseous emissions and fuel consumption with five different fuels were tested in a 4-cylinder, light-duty diesel EURO IV typically used for the automotive vehicles in Europe. Three different biodiesel fuels obtained from soybean oil, rapeseed oil and palm oil, a Fischer Tropsch fuel and an ultra low sulphur diesel were studied. The test used was the New European Driving Cycle (NEDC), this allowed tests to be carried out on an engine warmed up beforehand to avoid the effect of cold starts and several tests a day. Regulated emissions of NO{sub X}, CO, HC and CO{sub 2} were measured for each fuel. Unburned Hydrocarbon Speciation and formaldehyde were also measured in order to determine the maximum incremental reactivity (MIR) of the gaseous emissions. Pollutants were measured without the diesel oxidation catalyst (DOC) to gather data about raw emissions. When biodiesel was used, increases in regulated and unregulated emissions were observed and also significant increases in engine fuel consumption. The use of Fischer Tropsch fuel, however, caused lower regulated and unregulated emissions and fuel consumption than diesel. (author)

  3. DEVELOPMENT OF A COMPUTATIONAL MULTIPHASE FLOW MODEL FOR FISCHER TROPSCH SYNTHESIS IN A SLURRY BUBBLE COLUMN REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    Donna Post Guillen; Tami Grimmett; Anastasia M. Gribik; Steven P. Antal

    2010-09-01

    The Hybrid Energy Systems Testing (HYTEST) Laboratory is being established at the Idaho National Laboratory to develop and test hybrid energy systems with the principal objective to safeguard U.S. Energy Security by reducing dependence on foreign petroleum. A central component of the HYTEST is the slurry bubble column reactor (SBCR) in which the gas-to-liquid reactions will be performed to synthesize transportation fuels using the Fischer Tropsch (FT) process. SBCRs are cylindrical vessels in which gaseous reactants (for example, synthesis gas or syngas) is sparged into a slurry of liquid reaction products and finely dispersed catalyst particles. The catalyst particles are suspended in the slurry by the rising gas bubbles and serve to promote the chemical reaction that converts syngas to a spectrum of longer chain hydrocarbon products, which can be upgraded to gasoline, diesel or jet fuel. These SBCRs operate in the churn-turbulent flow regime which is characterized by complex hydrodynamics, coupled with reacting flow chemistry and heat transfer, that effect reactor performance. The purpose of this work is to develop a computational multiphase fluid dynamic (CMFD) model to aid in understanding the physico-chemical processes occurring in the SBCR. Our team is developing a robust methodology to couple reaction kinetics and mass transfer into a four-field model (consisting of the bulk liquid, small bubbles, large bubbles and solid catalyst particles) that includes twelve species: (1) CO reactant, (2) H2 reactant, (3) hydrocarbon product, and (4) H2O product in small bubbles, large bubbles, and the bulk fluid. Properties of the hydrocarbon product were specified by vapor liquid equilibrium calculations. The absorption and kinetic models, specifically changes in species concentrations, have been incorporated into the mass continuity equation. The reaction rate is determined based on the macrokinetic model for a cobalt catalyst developed by Yates and Satterfield [1]. The

  4. Development of an Innovative XRD-DRIFTS Prototype Allowing Operando Characterizations during Fischer-Tropsch Synthesis over Cobalt-Based Catalysts under Representative Conditions

    Directory of Open Access Journals (Sweden)

    Scalbert Julien

    2015-03-01

    Full Text Available An original system combining both X-Ray Diffraction and diffuse reflectance infrared Fourier transform spectroscopy was developed with the aim to characterize Fischer-Tropsch catalysts in relevant reaction conditions. The catalytic properties of a model PtCo/silica catalyst tested with this prototype have shown to be in the same range of those obtained in similar conditions with classical fixed-bed reactors. No bulk cobalt oxidation nor sintering were observed on operando XRD patterns. The formation of linear carbonyls and adsorbed hydrocarbons species at the surface of the catalyst was observed on operando DRIFT spectra. The surface of the catalyst was also suspected to be covered with carbon species inducing unfavorable changes in selectivity.

  5. A History of Fischer-Tropsch Wax Upgrading at BP--from Catalyst Screening Studies to Full Scale Demonstration in Alaska

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Conversion of Fischer-Tropsch wax into high quality synthetic crude or finished transportation fuels such as premium diesel has been studied over the past 15 years within BP. Catalyst screening and selection was carried out in dedicated micro-reactors and pilot plants, whose designs are critical to the performance selection. Variation in catalyst composition and defining the gas to oil feed ratios with the operating temperature are a few of the parameters studied. Product selection and maximizing diesel yield combined with stability (catalyst life) were the ultimate drivers. The selected catalyst was then tested under commercial conditions in a dedicated 300 barrel per day demonstration plant. The products were also tested in engines to assess their combustion characteristics.

  6. Fischer-Tropsch Cobalt Catalyst Improvements with the Presence of TiO2, La2O3, and ZrO2 on an Alumina Support

    Science.gov (United States)

    Klettlinger, Jennifer Lindsey Suder

    2012-01-01

    The objective of this study was to evaluate the effect of titanium oxide, lanthanum oxide, and zirconium oxide on alumina supported cobalt catalysts. The hypothesis was that the presence of lanthanum oxide, titanium oxide, and zirconium oxide would reduce the interaction between cobalt and the alumina support. This was of interest because an optimized weakened interaction could lead to the most advantageous cobalt dispersion, particle size, and reducibility. The presence of these oxides on the support were investigated using a wide range of characterization techniques such as SEM, nitrogen adsorption, x-ray diffraction (XRD), temperature programmed reduction (TPR), temperature programmed reduction after reduction (TPR-AR), and hydrogen chemisorptions/pulse reoxidation. Results indicated that both La2O3 and TiO2 doped supports facilitated the reduction of cobalt oxide species in reference to pure alumina supported cobalt catalysts, however further investigation is needed to determine the effect of ZrO2 on the reduction profile. Results showed an increased corrected cluster size for all three doped supported catalysts in comparison to their reference catalysts. The increase in reduction and an increase in the cluster size led to the conclusion that the support-metal interaction weakened by the addition of TiO2 and La2O3. It is also likely that the interaction decreased upon presence of ZrO2 on the alumina, but further research is necessary. Preliminary results have indicated that the alumina-supported catalysts with titanium oxide and lanthanum oxide present are of interest because of the weakened cobalt support interaction. These catalysts showed an increased extent of reduction, therefore more metallic cobalt is present on the support. However, whether or not there is more cobalt available to participate in the Fischer-Tropsch synthesis reaction (cobalt surface atoms) depends also on the cluster size. On one hand, increasing cluster size alone tends to decrease the

  7. Organic Analysis of Catalytic Fischer-Tropsch Synthesis Products and Ordinary Chondrite Meteorites by Stepwise Pyrolysis-GCMS: Organics in the Early Solar Nebula

    Science.gov (United States)

    Locke, Darren R.; Yazzie, Cyriah A.; Burton, Aaron S.; Niles, Paul B.; Johnson, Natasha M.

    2014-01-01

    Abiotic generation of complex organic compounds, in the early solar nebula that formed our solar system, is hypothesized by some to occur via Fischer-Tropsch (FT) synthesis. In its simplest form, FT synthesis involves the low temperature (300degC) produces FT products that include lesser amounts of n-alkanes and greater alkene, alcohol, and polycyclic aromatic hydrocarbon (PAH) compounds. We have begun to experimentally investigate FT synthesis in the context of abiotic generation of organic compounds in the early solar nebula. It is generally thought that the early solar nebula included abundant hydrogen and carbon monoxide gases and nano-particulate matter such as iron and metal silicates that could have catalyzed the FT reaction. The effect of FT reaction temperature, catalyst type, and experiment duration on the resulting products is being investigated. These solid organic products are analyzed by thermal-stepwise pyrolysis-GCMS and yield the types and distribution of hydrocarbon compounds released as a function of temperature. We show how the FT products vary by reaction temperature, catalyst type, and experimental duration and compare these products to organic compounds found to be indigenous to ordinary chondrite meteorites. We hypothesize that the origin of organics in some chondritic meteorites, that represent an aggregation of materials from the early solar system, may at least in part be from FT synthesis that occurred in the early solar nebula.

  8. Performance characterization of CNTs and γ-Al{sub 2}O{sub 3} supported cobalt catalysts in Fischer-Tropsch reaction

    Energy Technology Data Exchange (ETDEWEB)

    Ali, Sardar, E-mail: alikhan-635@yahoo.com [Centralized Analytical Laboratory, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia); Zabidi, Noor Asmawati Mohd, E-mail: noorasmawati-mzabidi@petronas.com.my [Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia); Subbarao, Duvvuri, E-mail: duvvuri-subbarao@petronas.com.my [Department of Chemical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia)

    2014-10-24

    Catalysts were prepared via a wet impregnation method. Different physicochemical properties of the samples were revealed by transmission electron microscope (TEM), temperature programmed reduction (H{sub 2}-TPR) and carbon dioxide desorption (CO{sub 2}-desorption). Fischer-Tropsch reaction (FTS) was carried out in a fixed-bed microreactor at 220°C and 1 atm, with H{sub 2}/CO = 2v/v and space velocity, SV of 12L/g.h for 5 h. Various characterization techniques revealed that there was a stronger interaction between Co and Al{sub 2}O{sub 3} support compared to that of CNTs support. CNTs support increased the reducibility and decreased Co particle size. A significant increase in % CO conversion and FTS reaction rate was observed over CNTs support compared to that of Co/Al{sub 2}O{sub 3}. Co/CNTs resulted in higher C{sub 5+} hydrocarbons selectivity compared to that of Co/Al{sub 2}O{sub 3} catalyst. CNTs are a better support for Co compared to Al{sub 2}O{sub 3}.

  9. Six-flow operations for catalyst development in Fischer-Tropsch synthesis: Bridging the gap between high-throughput experimentation and extensive product evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Sartipi, Sina, E-mail: S.Sartipi@tudelft.nl, E-mail: J.Gascon@tudelft.nl; Jansma, Harrie; Bosma, Duco; Boshuizen, Bart; Makkee, Michiel; Gascon, Jorge, E-mail: S.Sartipi@tudelft.nl, E-mail: J.Gascon@tudelft.nl; Kapteijn, Freek [Department of Chemical Engineering, Catalysis Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft (Netherlands)

    2013-12-15

    Design and operation of a “six-flow fixed-bed microreactor” setup for Fischer-Tropsch synthesis (FTS) is described. The unit consists of feed and mixing, flow division, reaction, separation, and analysis sections. The reactor system is made of five heating blocks with individual temperature controllers, assuring an identical isothermal zone of at least 10 cm along six fixed-bed microreactor inserts (4 mm inner diameter). Such a lab-scale setup allows running six experiments in parallel, under equal feed composition, reaction temperature, and conditions of separation and analysis equipment. It permits separate collection of wax and liquid samples (from each flow line), allowing operation with high productivities of C5+ hydrocarbons. The latter is crucial for a complete understanding of FTS product compositions and will represent an advantage over high-throughput setups with more than ten flows where such instrumental considerations lead to elevated equipment volume, cost, and operation complexity. The identical performance (of the six flows) under similar reaction conditions was assured by testing a same catalyst batch, loaded in all microreactors.

  10. Effects of Catalyst Preparation on Hydrocarbon Product Distribution in Hydrocracking of the Fischer-Tropsch Product with Low Pt-Loaded Catalysts

    Directory of Open Access Journals (Sweden)

    Toshiaki Hanaoka

    2015-11-01

    Full Text Available For the effective production of hydrocarbon liquid fuel in the hydrocracking of the Fischer-Tropsch (FT product, the catalytic performance of Pt-loaded catalysts with low Pt content was investigated using an autoclave at 250 °C, an initial H2 pressure of 0.5 MPa, and a reaction time of 1 h. A screening study using Pt-loaded catalysts with a Pt content of 0.1 wt. % indicated that zeolite supports were more favorable for jet fuel (carbon numbers 9–15 production than amorphous oxide supports. The small particle size of the supported Pt particles and the high amount of medium acid sites for the supports led to higher performance of the Pt-loaded zeolite catalysts. In the hydrocracking reaction over Pt catalysts using the zeolite support with the high amount of medium acid sites, the yields of the corresponding jet fuel at 0.02 and 0.1 wt. % were almost the same. Pt-loaded catalysts with a Pt content of 0.02 wt. % were prepared using water-in-oil (w/o microemulsions and their particle size was controlled between 1.0 and 2.6 nm. While the yield of the corresponding jet fuel was independent of Pt particle size, smaller Pt particles typically promoted the production of lighter hydrocarbons.

  11. [Emission characteristics of a diesel car fueled with coal based Fischer-Tropsch (F-T) diesel and fossil diesel blends].

    Science.gov (United States)

    Hu, Zhi-Yuan; Cheng, Liang; Tan, Pi-Qiang; Lou, Di-Ming

    2012-11-01

    According to the first type test cycle of China national standard GB 18352.3-2005, the CO, NO(x), HC, PM and CO2 emission characteristics of a PASSAT diesel car fueled with Shanghai local IV diesel, coal based Fischer-Tropsch (F-T) diesel, and the blends of coal based F-T diesel and Shanghai local IV diesel up to 10% and 50% by volume were analyzed respectively. And the environmental impacts such as decreased air quality, health impact, photochemical ozone, global warming, and acidification that could be caused by CO, NO(x), HC, PM and CO2 emission of the diesel car were also assessed. The results showed that under GB 18352.3-2005 No. 1 test driving cycle, which consisted of four urban driving cycles and one extra urban driving cycle, the CO, HC, PM and CO2 emissions were released mainly in the urban driving cycles whereas the NO(x) emissions occurred mainly in the extra urban driving cycle. Compared with Shanghai local IV diesel, all of the CO, NO(x), HC, PM and CO2 emissions of the diesel car decreased to different extents when fueled with coal based F-T diesel blends. Moreover, the aerosol generation potential, global warming potential and acidification potential of F-T diesel fueled diesel car were also reduced. To sum up, coal based F-T diesel would be one of the alternative fuels to diesel in China. PMID:23323400

  12. Preparation of Fe-Mn/K/Al2O3 Fischer-Tropsch Catalyst and Its Catalytic Kinetics for the Hydrogenation of Carbon Monoxide

    Institute of Scientific and Technical Information of China (English)

    F.Fazlollahi; M.Sarkari; H.Gharebaghi; H.Atashi; M.M.Zarei; A.A.Mirzaei; W.C.Hecker

    2013-01-01

    A K promoted iron-manganese catalyst was prepared by sol-gel method,and subsequently was tested for hydrogenation of carbon monoxide to light olefins.The kinetic experiments on a well-characterized Fe-Mn/K/Al2O3 catalyst were performed in a fixed-bed micro-reactor in a temperature range of 280-380 ℃,pressure range of 0.1-1.2 MPa,H2/CO feed molar ratio range of 1-2.1 and a space velocity range of 2000-7200 h-1.Considering the mechanism of the process and Langmuir-Hinshelwood-Hogan-Watson (LHHW) approach,unassisted CO dissociation and H-assisted CO dissociation mechanisms were defined.The best models were obtained using non-linear regression analysis and Levenberg-Marquardt algorithm.Consequently,4 models were considered as the preferred models based on the carbide mechanism.Finally,a model was proposed as a best model that assumed the following kinetically relevant steps in the iron-Fischer-Tropsch (FT) synthesis:(1) CO dissociation occurred without hydrogen interaction and was not a rate-limiting step; (2) the first hydrogen addition to surface carbon was the rate-determining steps.The activation energy and adsorption enthalpy were calculated 40.0 and-30.2 kJ· mol-1,respectively.

  13. On the Use of Fourier Transform Infrared (FT-IR) Spectroscopy and Synthetic Calibration Spectra to Quantify Gas Concentrations in a Fischer-Tropsch Catalyst System

    Science.gov (United States)

    Ferguson, Frank T.; Johnson, Natasha M.; Nuth, Joseph A., III

    2015-01-01

    One possible origin of prebiotic organic material is that these compounds were formed via Fischer-Tropsch-type (FTT) reactions of carbon monoxide and hydrogen on silicate and oxide grains in the warm, inner-solar nebula. To investigate this possibility, an experimental system has been built in which the catalytic efficiency of different grain-analog materials can be tested. During such runs, the gas phase above these grain analogs is sampled using Fourier transform infrared (FT-IR) spectroscopy. To provide quantitative estimates of the concentration of these gases, a technique in which high-resolution spectra of the gases are calculated using the high-resolution transmission molecular absorption (HITRAN) database is used. Next, these spectra are processed via a method that mimics the processes giving rise to the instrumental line shape of the FT-IR spectrometer, including apodization, self-apodization, and broadening due to the finite resolution. The result is a very close match between the measured and computed spectra. This technique was tested using four major gases found in the FTT reactions: carbon monoxide, methane, carbon dioxide, and water. For the ranges typical of the FTT reactions, the carbon monoxide results were found to be accurate to within 5% and the remaining gases accurate to within 10%. These spectra can then be used to generate synthetic calibration data, allowing the rapid computation of the gas concentrations in the FTT experiments.

  14. Preparation for Pt-Loaded Zeolite Catalysts Using w/o Microemulsion and Their Hydrocracking Behaviors on Fischer-Tropsch Product

    Directory of Open Access Journals (Sweden)

    Toshiaki Hanaoka

    2015-02-01

    Full Text Available Pt-loaded β-type zeolite catalysts with constant Pt content (0.11 wt.% and similar pore structure were prepared using a water-in-oil (w/o microemulsion. The effect of Pt particle synthesis conditions using microemulsion (a type of Pt complex-forming agents and the molar ratio of complex-forming agent to Pt4+ on loaded Pt particle size was investigated. The Pt particle size of the Pt catalyst using tetraethylammonium chloride (TEAC as a complex-forming agent with the molar TEAC/Pt ratio 10 was the minimum value (3.8 nm, and was much smaller than that (6.7 nm prepared by the impregnation method. The utilization of the complex-forming agent of which hydrophobic groups occupied a small volume and the appropriate complex-forming agent/Pt ratio were favorable for synthesis of small Pt particles. The effect of loaded Pt particle size on the hydrocracking of the Fischer-Tropsch (FT product was investigated using the Pt-loaded zeolite catalysts at 250 °C with an initial H2 pressure of 0.5 MPa, and reaction time of 1 h. The Pt catalyst with a Pt particle size of 4.2 nm prepared using the microemulsion exhibited the maximum corresponding jet fuel yield (30.0%, which was higher than that of the impregnated catalyst.

  15. On the Use of Fourier Transform Infrared (FT-IR) Spectroscopy and Synthetic Calibration Spectra to Quantify Gas Concentrations in a Fischer-Tropsch Catalyst System.

    Science.gov (United States)

    Ferguson, Frank T; Johnson, Natasha M; Nuth, Joseph A

    2015-10-01

    One possible origin of prebiotic organic material is that these compounds were formed via Fischer-Tropsch-type (FTT) reactions of carbon monoxide and hydrogen on silicate and oxide grains in the warm, inner-solar nebula. To investigate this possibility, an experimental system has been built in which the catalytic efficiency of different grain-analog materials can be tested. During such runs, the gas phase above these grain analogs is sampled using Fourier transform infrared (FT-IR) spectroscopy. To provide quantitative estimates of the concentration of these gases, a technique in which high-resolution spectra of the gases are calculated using the High-Resolution Transmission Molecular Absorption (HITRAN) database is used. Next, these spectra are processed via a method that mimics the processes giving rise to the instrumental line shape of the FT-IR spectrometer, including apodization, self-apodization, and broadening due to the finite resolution. The result is a very close match between the measured and computed spectra. This technique was tested using four major gases found in the FTT reactions: carbon monoxide, methane, carbon dioxide, and water. For the ranges typical of the FTT reactions, the carbon monoxide results were found to be accurate to within 5% and the remaining gases accurate to within 10%. These spectra can then be used to generate synthetic calibration data, allowing the rapid computation of the gas concentrations in the FTT experiments. PMID:26449809

  16. Advance in Supercritical Phase Fischer-Tropsch Synthesis%超临界费-托合成进展

    Institute of Scientific and Technical Information of China (English)

    唐浩东; 韩文锋; 沈菊李; 刘化章

    2005-01-01

      综述了近年来有关超临界相费-托合成的研究进展,主要介绍了气相、液相和超临界费-托合成对 CO 转化率、产物选择性、催化剂床层局部过热等方面的影响。同时介绍了超临界介质种类、催化剂种类、助剂、压力以及体系中加入α-烯烃等因素对超临界费-托合成反应活性和产物选择性的影响。超临界介质能使反应物和产物在催化剂颗粒内部快速传递并使蜡在催化剂表面原位萃取,使合成气的转化率、α-烯烃和大分子产物的选择性较气相和液相反应有所增加。同时由于超临界介质有利于减轻催化剂床层的局部过热,使甲烷和CO2的选择性降低,且延长了催化剂使用寿命。%  The development of supercritical phase F-T synthesis has been reviewed in this paper. It compares the CO conversion, selectivity of products, local superheating of catalyst surface in gas-phase, liquid-phase and supercritical-phase F-T synthesis. The effects of supercritical medium, catalysts, promoter, pressure and α-olefin co-feeding on the activity and selectivity in supercritical- phase F-T synthesis were introduced. In the supercritical phase F-T reaction, rapid transportation of reactants and products to the inside of catalyst bed and pellet and in situ wax extraction from catalyst by supercritical fluid were accomplished. It was observed that syngas conversion, α-olefin selectivity, and heavy hydrocarbon production could be enhanced in supercritical-phase F-T synthesis process compared to gas-phase and liquid-phase F-T synthesis. In addition, local superheating of catalyst surface was alleviated in supercritical phase F-T synthesis and decreasing of selectivity of methane and CO2 and longer catalyst lifetime resulted.

  17. Effects of the ratio of Fe to Co over Fe-Co/SiO2 bimetallic catalysts on their catalytic performance for Fischer-Tropsch synthesis

    Institute of Scientific and Technical Information of China (English)

    Xiangdong Ma; Qiwen Sun; Weiyong Ying; Dingye Fang

    2009-01-01

    The Fe-Co/SiO2 bimetallic catalysts with different ratios of Fe to Co were prepared by aqueous incipient wetness impregnation. The catalysts of 10%Fe:0%Co/SiO2, 10%Fe:6%Co/SiO2, 10%Fe:2%Co/SiO2, 10%Fe: 10%Co/SiO2, 6%Fe: 10%Co/SiO2, 2%Fe: 10%Co/SiO2 and 0%Fe: 10%Co/SiO2 by mass were tested in a fixed reactor by the Fischer-Tropsch synthesis. Activity and hydrocarbon distribution were found to be determined by the ratio of iron to cobalt of the catalysts. Higher iron content inhibited the activity, whereas higher cobalt content enhanced the activity of the Fe-Co/SiO2 catalysts. On the other hand, for the catalysts of 10%Fe:6%Co/SiO2, 10%Fe: 10%Co/SiO2, 6%Fe: 10%Co/SiO2, and 2%Fe: 10%Co/SiO2, the total C2-C4 fraction increased (from 10.65% to 26.78%) and C5+ fraction decreased (from 75.75% to 57.63%) at 523 K. Temperature programmed reduction revealed that the addition of cobalt enhanced the reducibility of the Fe-Co/SiO2 catalyst. Metal oxides were present in those catalysts as shown by XRD. The Fe-Co alloy phase was found in the 2%Fe: 10%Co/SiO2, 6%Fe: 10%Co/SiO2, 10%Fe:10%Co/SiO2, 10%Fe:6%Co/SiO2 catalysts and their crystals were perfect.

  18. Gaseous product mixture from Fischer-Tropsch synthesis as an efficient carbon feedstock for low temperature CVD growth of carbon nanotube carpets.

    Science.gov (United States)

    Almkhelfe, Haider; Carpena-Núñez, Jennifer; Back, Tyson C; Amama, Placidus B

    2016-07-21

    Low-temperature chemical vapor deposition (CVD) growth of carbon nanotube (CNT) carpets from Fe and Fe-Cu catalysts using a gaseous product mixture from Fischer-Tropsch synthesis (FTS-GP) as a superior carbon feedstock is demonstrated. This growth approach addresses a persistent issue of obtaining thick CNT carpets on temperature-sensitive substrates at low temperatures using a non-plasma CVD approach without catalyst pretreatment and/or preheating of the carbon feedstock. The efficiency of the process is evidenced by the highly dense, vertically aligned CNT structures from both Fe and Fe-Cu catalysts even at temperatures as low as 400 °C - a record low growth temperature for CNT carpets obtained via conventional thermal CVD. The grown CNTs exhibit a straight morphology with hollow interior and parallel graphitic planes along the tube walls. The apparent activation energies for CNT carpet growth on Fe and Fe-Cu catalysts are 0.71 and 0.54 eV, respectively. The synergistic effect of Fe and Cu show a strong dependence on the growth temperature, with Cu being more influential at temperatures higher than 450 °C. The low activation energies and long catalyst lifetimes observed are rationalized based on the unique composition of FTS-GP and Gibbs free energies for the decomposition reactions of the hydrocarbon components. The use of FTS-GP facilitates low-temperature growth of CNT carpets on traditional (alumina film) and nontraditional substrates (aluminum foil) and has the potential of enhancing CNT quality, catalyst lifetime, and scalability. PMID:27353432

  19. Effect of CO{sub 2} and H{sub 2}O content in syngas on activity and selectivity of a cobalt based Fischer-Tropsch synthesis catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Poehlmann, F.; Kaiser, P.; Kern, C.; Jess, A. [Bayreuth Univ. (Germany). Dept. of Chemical Engineering

    2013-11-01

    When liquid hydrocarbons are to be used as CO{sub 2} neutral storage media for electrical energy, it is necessary to convert CO{sub 2} from e.g. flue gas and hydrogen from water electrolysis to synthesis gas (CO/H{sub 2}). This can be achieved by a high temperature reverse water gas shift (RWGS) reaction. Due to thermodynamic limitations, the product gas of RWGS reactors operated at technically feasible temperatures of around 900 C will always contain significant amounts of water and carbon dioxide, which can influence the activity of Fischer-Tropsch synthesis (FTS) catalysts for the actual hydrocarbon production. In this study, a commercial cobalt catalyst was investigated under low temperature FTS conditions (2.5 MPa, 215 C) regard to activity and selectivity in the presence of H{sub 2}O and CO{sub 2}. A continuous flow apparatus including a fixed-bed reactor for the synthesis step was used to conduct all experiments. The experimental data reveals that the CO/CO{sub 2}-ratio does not affect the activity and product selectivity until the CO{sub 2}-concentration reaches 75 vol.-% (CO{sub 2}/(CO+CO{sub 2})). On increasing the carbon dioxide concentration to 100 vol.-% (H{sub 2}/CO{sub 2} = 2), the methane selectivity rose up to 70 % and even above. Addition of water caused an initial loss of activity. After the initial loss of activity the FT catalyst activity was found to remain constant, irrespectively of if the water was removed from the feed or not. Thus, the deactivation was permanent. (orig.)

  20. Reductions in greenhouse gas emissions and oil use by DME (di-methyl ether) and FT (Fischer-Tropsch) diesel production in chemical pulp mills

    International Nuclear Information System (INIS)

    Using energy systems analysis, we examine the potential to reduce CO2 emissions and oil use by integrating motor biofuel production with pulp mills. BLG-DME (black liquor gasification with di-methyl ether production) is compared with solid biomass gasification with BIG-FT (solid biomass gasification with Fischer-Tropsch fuel production). The studied systems are expanded with stand-alone production of biomass-based electricity and motor fuel so that they yield the same functional unit in terms of motor fuel and electricity as well as pulp or paper product, in order to facilitate comparison. More motor biofuel can be produced in integration with the studied mills with BLG-DME than with BIG-FT because the black liquor flow is large compared with other fuel streams in the mill and the integration potential for BIG-FT is limited by the mill’s heat demand. When both systems are required to produce the same functional unit, the BLG-DME system achieves higher system efficiency and larger reductions in CO2 emissions and oil use per unit of biomass consumed. In general, integration of motor biofuel production with a pulp mill is more efficient than stand-alone motor biofuel production. Larger reductions in CO2 emissions or oil use can, however, be achieved if biomass replaces coal or oil in stationary applications. -- Highlights: ► CO2 emission and oil use reductions quantified for pulp mill-based biorefineries. ► Black liquor gasification gives larger reductions than solid biomass gasification. ► Lower mill steam demand increases the black liquor gasification advantage. ► Biomass directly replacing coal or oil in stationary plants gives larger reductions.

  1. Thermodynamics of hydrocracking and isomerization reaction of Fischer-Tropsch syncrude%费托合成油品加氢裂化异构化反应的热力学

    Institute of Scientific and Technical Information of China (English)

    吴建民; 孙启文; 张宗森; 庞利峰

    2014-01-01

    利用 Benson 基团贡献法和 ABWY 法计算了费托合成油品的标准摩尔生成焓、标准熵及摩尔定压热容等基础数据,在298-750 K,对费托合成油品加氢裂化异构化反应体系的反应焓、吉布斯自由能以及平衡常数等热力学数据进行了计算;对体系中各反应的热力学可能性与生成顺序进行了判断以及各反应的热力平衡与限度进行了分析。结果表明:费托合成油品加氢裂化异构化反应是放热反应,低温时大部分反应在热力学上均能够自发的进行,且平衡常数均较大,能够进行到较高的程度;从热力学上看,升高温度不利于加氢裂化异构化反应的进行,适宜反应温度的选择应兼顾各种反应的进行;烯烃比烷烃更容易发生加氢裂化异构化反应;所获得的热力学数据可为费托合成油品加氢裂化异构化工艺研究、反应器开发以及新型催化剂研制等提供理论依据。%The standard molar enthalpy of formation,the standard entropy and isobaric molar heat capacity of Fischer-Tropsch syncrude were estimated by Benson group contribution method and ABWY method.The enthalpy change,Gibbs free energy change and equilibrium constant of hydrocracking and isomerization reaction of Fischer-Tropsch syncrude were calculated as a function of the temperature from 298 K to 750 K.The thermodynamic possibility and formation sequences of hydrocracking and isomerization reaction of Fischer-Tropsch syncrude were judged.Meanwhile,the thermodynamic equilibrium and the limit of different reaction steps were also analyzed. The results show that the hydrocracking and isomerization reaction of Fischer-Tropsch syncrude is an exothermic reaction,most of which are spontaneous at low temperature and can reach to a deep extent.Improving the temperature is not good for hydrocracking and isomerization reaction from a thermodynamic point of view.The choice of the suitable temperature should take

  2. Fischer-Tropsch synthesis in slurry-phase reactors over Mn- and Zr-modified Co/SiO2 catalysts

    International Nuclear Information System (INIS)

    Fischer-Tropsch (F-T) synthesis was carried out in a gas-flowed slurry-phase reaction system over Mn- and Zr-modified Co/SiO2 catalysts. A 0.5 L stirred tank slurry reactor (STSR) was used for catalyst screening and a 12.5 L slurry bubble column reactor (SBCR) was used for trial pilot operation. While using the 0.5 L reactor for catalyst screening, Co supported on the SiO2 with an average pore size of 10 nm showed a high catalytic performance for the F-T synthesis due to the suitable Co particle size in the catalyst. Zr promoter improved the activity and Mn promoter improved the stability of Co/SiO2 catalyst for the F-T synthesis. H2-TPR profiles indicated that Zr and Mn promoters improved the reduction degree of Co3O4 particles (on SiO2 surface) to Co0 active species in H2 flow at low temperature. While using the 12.5 L reactor for trial pilot operation over Mn-Zr-Co/SiO2 catalyst, the space-time yield (STY) of C5+ hydrocarbons (liquid fuel) showed almost the same values when various solvents (n-C16H34, n-C14H30, diesel from petrol station, F-T crude oil) were used. Diesel and F-T crude oil are suitable for using in a large-scaled F-T synthesis plant owing to the low prices. Mn-Zr-Co/SiO2 catalyst achieved a STY of C5+ hydrocarbons larger than 1000 g-C5+ kg-cat-1 h-1 in the 12.5 L reactor. The production capacity of liquid fuel from the 12.5 L reactor reached to 15.6 L per day (assumed for 24 h continuous operation). The stirring was very important for the F-T synthesis both reaction in the 0.5 L reactor and reaction in the 12.5 L reactor. The shape of slurry reactor also influenced the CO conversion for the F-T synthesis: reaction in the 12.5 L SBCR gave a higher CO conversion than that of reaction in the 0.5 L STSR (at the same W/F value under the same stirring speed) because the slender column reactor (SBCR) extended the residue time of reaction gas in the slurry-phase containing catalyst. (author)

  3. Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Burton Davis; Gary Jacobs; Wenping Ma; Dennis Sparks; Khalid Azzam; Janet Chakkamadathil Mohandas; Wilson Shafer; Venkat Ramana Rao Pendyala

    2011-09-30

    There has been a recent shift in interest in converting not only natural gas and coal derived syngas to Fischer-Tropsch synthesis products, but also converting biomass-derived syngas, as well as syngas derived from coal and biomass mixtures. As such, conventional catalysts based on iron and cobalt may not be suitable without proper development. This is because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using entrained-flow oxygen-blown gasifier gasification gasification) than solely from coal, other compounds may actually be increased. Of particular concern are compounds containing alkali chemicals like the chlorides of sodium and potassium. In the first year, University of Kentucky Center for Applied Energy Research (UK-CAER) researchers completed a number of tasks aimed at evaluating the sensitivity of cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts and a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to alkali halides. This included the preparation of large batches of 0.5%Pt-25%Co/Al{sub 2}O{sub 3} and 100Fe: 5.1Si: 3.0K: 2.0Cu (high alpha) catalysts that were split up among the four different entities participating in the overall project; the testing of the catalysts under clean FT and WGS conditions; the testing of the Fe-Cr WGS catalyst under conditions of co-feeding NaCl and KCl; and the construction and start-up of the continuously stirred tank reactors (CSTRs) for poisoning investigations. In the second and third years, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H

  4. Extension of the Single-Event Methodology to Metal Catalysis: Application to Fischer-Tropsch Synthesis Extension de la méthodologie des événements constitutifs à la catalyse métallique : Application à la synthèse Fischer-Tropsch

    Directory of Open Access Journals (Sweden)

    Lozano-Blanco G.

    2010-10-01

    Full Text Available The single-event methodology has been extended to metal catalysis using Fischer-Tropsch synthesis on an iron-based catalyst as case study. The reaction mechanism has been assessed in terms of elementary steps that could be categorized in reaction families such as reductive elimination, β-hydride elimination and methylene insertion. A computer code has been developed for the generation of the reaction network containing these elementary steps. The representation of reacting and intermediate species explicitly takes into account metal-carbon bonds as well as the presence of oxygen. The model has been validated using iron-based catalytic data at 623 K, 0.6 to 2.1 MPa, inlet molar H2/CO ratio between 2 and 6. 14 parameters, among which 10 activation energies and 4 atomic chemisorption enthalpies have been adjusted to the experimental data. Experimentally observed trends in alkane and 1-alkene product yields with the carbon number were adequately reproduced as well as the individual molar yields of the non-hydrocarbon products. La méthodologie par événements constitutifs a été étendue à la catalyse métallique en utilisant la synthèse Fischer-Tropsch sur un catalyseur au fer comme cas d'étude. Le mécanisme réactionnel a été décomposé en étapes élémentaires qui peuvent être classées par type de réactions, telles que l'élimination réductrice, l'élimination d'hydrure en β, et l'insertion de groupe méthylène. Un code de calcul a été développé pour générer le réseau réactionnel impliquant ces étapes élémentaires. La représentation des réactifs et des espèces intermédiaires prend en compte explicitement les liaisons carbone-métal et inclut la présence d'atomes d'oxygène. Le modèle a été validé sur une base de données obtenues sur un catalyseur à base de fer à 623 K, sur une plage de 0,6 à 2,1 MPa, un ratio H2/CO en entrée variant de 2 à 6. Quatorze paramètres, dont 10 énergies d'activation et 4

  5. The application of inelastic neutron scattering to explore the significance of a magnetic transition in an iron based Fischer-Tropsch catalyst that is active for the hydrogenation of CO

    Energy Technology Data Exchange (ETDEWEB)

    Warringham, Robbie; McFarlane, Andrew R.; Lennon, David, E-mail: David.Lennon@Glasgow.ac.uk [School of Chemistry, University of Glasgow, Joseph Black Building, Glasgow, Scotland G12 8QQ (United Kingdom); MacLaren, Donald A. [School of Physics and Astronomy, University of Glasgow, The Kelvin Building, Glasgow, Scotland G12 8QQ (United Kingdom); Webb, Paul B.; Tooze, Robert P. [Sasol Technology UK Ltd., Purdie Building, North Haugh, St Andrews, Fife KY16 9ST (United Kingdom); Taylor, Jon; Ewings, Russell A.; Parker, Stewart F. [ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Didcot, Oxon OX11 0QX (United Kingdom)

    2015-11-07

    An iron based Fischer-Tropsch synthesis catalyst is evaluated using CO hydrogenation at ambient pressure as a test reaction and is characterised by a combination of inelastic neutron scattering (INS), powder X-ray diffraction, temperature-programmed oxidation, Raman scattering, and transmission electron microscopy. The INS spectrum of the as-prepared bulk iron oxide pre-catalyst (hematite, α-Fe{sub 2}O{sub 3}) is distinguished by a relatively intense band at 810 cm{sup −1}, which has previously been tentatively assigned as a magnon (spinon) feature. An analysis of the neutron scattering intensity of this band as a function of momentum transfer unambiguously confirms this assignment. Post-reaction, the spinon feature disappears and the INS spectrum is characterised by the presence of a hydrocarbonaceous overlayer. A role for the application of INS in magnetic characterisation of iron based FTS catalysts is briefly considered.

  6. The application of inelastic neutron scattering to explore the significance of a magnetic transition in an iron based Fischer-Tropsch catalyst that is active for the hydrogenation of CO

    International Nuclear Information System (INIS)

    An iron based Fischer-Tropsch synthesis catalyst is evaluated using CO hydrogenation at ambient pressure as a test reaction and is characterised by a combination of inelastic neutron scattering (INS), powder X-ray diffraction, temperature-programmed oxidation, Raman scattering, and transmission electron microscopy. The INS spectrum of the as-prepared bulk iron oxide pre-catalyst (hematite, α-Fe2O3) is distinguished by a relatively intense band at 810 cm−1, which has previously been tentatively assigned as a magnon (spinon) feature. An analysis of the neutron scattering intensity of this band as a function of momentum transfer unambiguously confirms this assignment. Post-reaction, the spinon feature disappears and the INS spectrum is characterised by the presence of a hydrocarbonaceous overlayer. A role for the application of INS in magnetic characterisation of iron based FTS catalysts is briefly considered

  7. Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalystes to Poisons form High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Burton Davis; Gary Jacobs; Wenping Ma; Khalid Azzam; Janet ChakkamadathilMohandas; Wilson Shafer

    2009-09-30

    There has been a recent shift in interest in converting not only natural gas and coal derived syngas to Fischer-Tropsch synthesis products, but also converting biomass-derived syngas, as well as syngas derived from coal and biomass mixtures. As such, conventional catalysts based on iron and cobalt may not be suitable without proper development. This is because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using entrained-flow oxygen-blown gasifier gasification gasification) than solely from coal, other compounds may actually be increased. Of particular concern are compounds containing alkali chemicals like the chlorides of sodium and potassium. In the first year, University of Kentucky Center for Applied Energy Research (UK-CAER) researchers completed a number of tasks aimed at evaluating the sensitivity of cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts and a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to alkali halides. This included the preparation of large batches of 0.5%Pt-25%Co/Al{sub 2}O{sub 3} and 100Fe: 5.1Si: 3.0K: 2.0Cu (high alpha) catalysts that were split up among the four different entities participating in the overall project; the testing of the catalysts under clean FT and WGS conditions; the testing of the Fe-Cr WGS catalyst under conditions of co-feeding NaCl and KCl; and the construction and start-up of the continuously stirred tank reactors (CSTRs) for poisoning investigations.

  8. Fischer-Tropsch Synthesis (FTS) catalytic evaluation of a 10%Co/Nb{sub 2}O{sub 5} catalyst in a agitated slurry reactor; Avaliacao catalitica do catalisador 10%Co/Nb{sub 2}O{sub 5} na Sintese de Fischer-Tropsch (SFT) em um reator em leito de lama agitado

    Energy Technology Data Exchange (ETDEWEB)

    Castro, Gustavo P.; Meza, Lucas P.; Spigao Junior, Antonio C.S.; Soares, Ricardo R. [Universidade Federal de Uberlandia, MG (Brazil)

    2004-07-01

    The objective of this work was to evaluate the performance of a Co/Nb{sub 2}O{sub 5} catalyst in the Fischer-Tropsch Synthesis (FTS) in an agitated slurry reactor, using a methodology and reaction unit developed by the authors. Besides this, an evaluation of the reaction kinetic parameters, from the literature, was accomplished. The catalyst was prepared by the homogeneous precipitation method to obtain a cobalt content of 10 wt%. The reactions were accomplished, after ex-situ reduction, at 500 deg C, of 20 g of 10% Co/Nb{sub 2}O{sub 5} catalyst, in a 500 mL slurry reactor, loaded with 150 g of octacosane solvent (C{sub 28}H{sub 58}). The reaction temperature was varied from 180 to 220 deg C and the initial reaction mixture flow rate from 20 to 60 mL/min. The used reaction pressure was 20 bar. The selectivities were calculated by gaseous effluent chromatographic analysis, relating these effluent molar fractions with the slurry composition by an asymmetric model of the liquid - vapor equilibrium. An evaluation of the carbon chain growth probability parameter ({alpha}) was accomplished using the Anderson-Schulz-Flory products distribution model. The parameters of both kinetic models, with a possible reaction mechanism, were estimated by non linear regression analysis. The obtained results showed that the 10%Co/Nb{sub 2}O{sub 5} catalyst presented high stability within few hours of reaction, little selectivity for methane and CO{sub 2}, and high selectivity for C{sub 5+}, specially for gasoline (C{sub 5} - C{sub 11}) and diesel (C{sub 12} - C{sub 20}). The {alpha} calculated values were all grater than 0.75. The estimated parameters for both kinetic models were slightly smaller than the others cobalt catalysts parameters, from the literature. This models adjustment to the experimental data was satisfactory, showing correlation coefficients grater than 0.97. (author)

  9. Synthesis of Hydrocarbons from H2-Deficient Syngas in Fischer-Tropsch Synthesis over Co-Based Catalyst Coupled with Fe-Based Catalyst as Water-Gas Shift Reaction

    Directory of Open Access Journals (Sweden)

    Ting Ma

    2015-01-01

    Full Text Available The effects of metal species in an Fe-based catalyst on structural properties were investigated through the synthesis of Fe-based catalysts containing various metal species such, as Mn, Zr, and Ce. The addition of the metal species to the Fe-based catalyst resulted in high dispersions of the Fe species and high surface areas due to the formation of mesoporous voids about 2–4 nm surrounded by the catalyst particles. The metal-added Fe-based catalysts were employed together with Co-loaded beta zeolite for the synthesis of hydrocarbons from syngas with a lower H2/CO ratio of 1 than the stoichiometric H2/CO ratio of 2 for the Fischer-Tropsch synthesis (FTS. Among the catalysts, the Mn-added Fe-based catalyst exhibited a high activity for the water-gas shift (WGS reaction with a comparative durability, leading to the enhancement of the CO hydrogenation in the FTS in comparison with Co-loaded beta zeolite alone. Furthermore, the loading of Pd on the Mn-added Fe-based catalyst enhanced the catalytic durability due to the hydrogenation of carbonaceous species by the hydrogen activated over Pd.

  10. ACR-700 advanced technologies

    International Nuclear Information System (INIS)

    A successful advanced reactor plant will have optimized economics including reduced operating and maintenance costs, improved performance, and enhanced safety. Incorporating improvements based on advanced technologies ensures cost, safety and operational competitiveness of the ACR-700. These advanced technologies include modern configuration management; construction technologies; operational technology for the control centre and information systems for plant monitoring and analysis. This paper summarizes the advanced technologies used to achieve construction and operational improvements to enhance plant economic competitiveness, advances in the operational technology used for reactor control, and presents the development of the Smart CANDU suite of tools and its application to existing operating reactors and to the ACR-700. (author)

  11. Editorial: Advanced learning technologies

    OpenAIRE

    Yu-Ju Lan; Gang-Shan Fu; Stephen J.H. Yang; Jeff J.S. Huang

    2012-01-01

    Recent rapid development of advanced information technology brings high expectations of its potential to improvement and innovations in learning. This special issue is devoted to using some of the emerging technologies issues related to the topic of education and knowledge sharing, involving several cutting edge research outcomes from recent advancement of learning technologies. Advanced learning technologies are the composition of various related technologies and concepts such as mobile tech...

  12. Advanced Manufacturing Technologies

    Science.gov (United States)

    Fikes, John

    2016-01-01

    Advanced Manufacturing Technologies (AMT) is developing and maturing innovative and advanced manufacturing technologies that will enable more capable and lower-cost spacecraft, launch vehicles and infrastructure to enable exploration missions. The technologies will utilize cutting edge materials and emerging capabilities including metallic processes, additive manufacturing, composites, and digital manufacturing. The AMT project supports the National Manufacturing Initiative involving collaboration with other government agencies.

  13. Effects of Co/AC catalyst on alcohol products of Fischer-Tropsch synthesis%Co/AC催化剂对F-T合成醇产物的影响

    Institute of Scientific and Technical Information of China (English)

    熊亮; 于广欣; 孙玉平

    2015-01-01

    Activated carbon supported cobalt based catalyst for Fischer-Tropsch synthesis was prepared by vacuum impregnation method. The influence of reaction temperatures,reaction pressure and raw gas space velocity on alcohol product of F-T synthesis was invetigated in a slurry reactor. The results showed that the increase of reaction temperature was beneficial to the production of long-chain hydrocarbon and alcohols;the selectivity to alcohols enhanced with the increase of reaction pressure,but the selectivity to alcohols changed little when the reaction pressure was increased to 3 . 0 MPa;although the content of alcohols in the liquid products enhanced with the increase of GHSV,the distribution of alcohols was not changed.%以活性炭为载体,采用真空浸渍法制备Co/AC催化剂,在浆态床反应器中考察反应温度、反应压力和空速等条件对F-T合成醇产物的影响.结果表明,升高反应温度对长链烃和醇的生成有利,醇类的选择性随着反应压力的增大而提高,但反应压力增至3 . 0 MPa后,继续增加反应压力对醇类选择性变化不大;随着空速的增大,液相产物中醇含量虽然增加,但醇的分布无变化.

  14. Editorial: Advanced learning technologies

    Directory of Open Access Journals (Sweden)

    Yu-Ju Lan

    2012-03-01

    Full Text Available Recent rapid development of advanced information technology brings high expectations of its potential to improvement and innovations in learning. This special issue is devoted to using some of the emerging technologies issues related to the topic of education and knowledge sharing, involving several cutting edge research outcomes from recent advancement of learning technologies. Advanced learning technologies are the composition of various related technologies and concepts such as mobile technologies and social media towards learner centered learning. This editorial note provides an overview of relevant issues discussed in this special issue.

  15. Advanced uranium enrichment technologies

    International Nuclear Information System (INIS)

    The Advanced Gas Centrifuge and Atomic Vapor Laser Isotope Separation methods are described. The status and potential of the technologies are summarized, the programs outlined, and the economic incentives are noted. How the advanced technologies, once demonstrated, might be deployed so that SWV costs in the 1990s can be significantly reduced is described

  16. An Investigation into the Effects of Mn Promotion on the Activity and Selectivity of Co/SiO2 for Fischer - Tropsch Synthesis: Evidence for Enhanced CO Adsorption and Dissociation

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Gregory R.; Werner, Sebastian; Bell, Alexis T. (LBNL); (UCB)

    2016-03-04

    Mn is an effective promoter for improving the activity and selectivity of Co-based Fischer-Tropsch synthesis (FTS) catalysts, but the mechanism by which this promoter functions is poorly understood. The work reported here was aimed at defining the manner in which Mn interacts with Co and determining how these interactions affect the activity and selectivity of Co. Detailed measurements are reported for the kinetics of FTS as a function of Mn/Co ratio, temperature, and reactant partial pressure. These data are described by a single, two-parameter rate expression. Mn promotion was found to increase both the apparent rate constant for CO consumption and the CO adsorption constant. Further evidence for enhanced CO adsorption and dissociation was obtained from measurements of temperature-programmed desorption of CO and CO disproportionation rates, respectively. Our quantitative analysis of elemental maps obtained by STEM-EDS revealed that the promoter accumulates preferentially on the surface of Co nanoparticles at low Mn loadings, resulting in a rapid onset of improvements in the product selectivity as the Mn loading increases. For catalysts prepared with loadings higher than Mn/Co = 0.1, the additional Mn accumulates in the form of nanometer-scale particles of MnO on the support. In situ IR spectra of adsorbed CO show that Mn promotion increases the abundance of adsorbed CO with weakened C-O bonds. Furthermore, it is proposed that the cleavage of the C-O bond is promoted through Lewis acid-base interactions between the Mn2+ cations located at the edges of MnO islands covering the Co nanoparticles and the O atom of CO adsorbates adjacent to the MnO islands. The observed decrease in selectivity to CH4 and the increased selectivity to C5+ products with increasing Mn/Co ratio are attributed to a decrease in the ratio of adsorbed H to CO on the surface of the supported Co nanoparticles.

  17. Technological advances transforming rheumatology

    OpenAIRE

    Robinson, William H.; Mao, Rong

    2015-01-01

    Technological advances over the past decade have revolutionized many areas of rheumatology, ranging from diagnosis, prognosis and therapeutic development to the mechanistic understanding of rheumatic diseases. This overview highlights key technological innovations and discusses the major impact that these developments are having on research and clinical practice.

  18. Advanced Surface Technology

    DEFF Research Database (Denmark)

    Møller, Per; Nielsen, Lars Pleht

    This new significant book on advanced modern surface technology in all its variations, is aimed at both teaching at engineering schools and practical application in industry. The work covers all the significant aspects of modern surface technology and also describes how new advanced techniques make...... the components. It covers everything from biocompatible surfaces of IR absorbent or reflective surfaces to surfaces with specific properties within low friction, hardness, corrosion, colors, etc. The book includes more than 400 pages detailing virtually all analysis methods for examining at surfaces....

  19. Advanced manufacturing: Technology diffusion

    Energy Technology Data Exchange (ETDEWEB)

    Tesar, A.

    1995-12-01

    In this paper we examine how manufacturing technology diffuses rom the developers of technology across national borders to those who do not have the capability or resources to develop advanced technology on their own. None of the wide variety of technology diffusion mechanisms discussed in this paper are new, yet the opportunities to apply these mechanisms are growing. A dramatic increase in technology diffusion occurred over the last decade. The two major trends which probably drive this increase are a worldwide inclination towards ``freer`` markets and diminishing isolation. Technology is most rapidly diffusing from the US In fact, the US is supplying technology for the rest of the world. The value of the technology supplied by the US more than doubled from 1985 to 1992 (see the Introduction for details). History shows us that technology diffusion is inevitable. It is the rates at which technologies diffuse to other countries which can vary considerably. Manufacturers in these countries are increasingly able to absorb technology. Their manufacturing efficiency is expected to progress as technology becomes increasingly available and utilized.

  20. Advanced Environmental Monitoring Technologies

    Science.gov (United States)

    Jan, Darrell

    2004-01-01

    Viewgraphs on Advanced Environmental Monitoring Technologies are presented. The topics include: 1) Monitoring & Controlling the Environment; 2) Illustrative Example: Canary 3) Ground-based Commercial Technology; 4) High Capability & Low Mass/Power + Autonomy = Key to Future SpaceFlight; 5) Current Practice: in Flight; 6) Current Practice: Post Flight; 7) Miniature Mass Spectrometer for Planetary Exploration and Long Duration Human Flight; 8) Hardware and Data Acquisition System; 9) 16S rDNA Phylogenetic Tree; and 10) Preview of Porter.

  1. Fluidized Bed Gasification as a Mature And Reliable Technology for the Production of Bio-Syngas and Applied in the Production of Liquid Transportation Fuels—A Review

    Directory of Open Access Journals (Sweden)

    Adrian H.M. Verkooijen

    2011-03-01

    Full Text Available Biomass is one of the renewable and potentially sustainable energy sources and has many possible applications varying from heat generation to the production of advanced secondary energy carriers. The latter option would allow mobile services like the transportation sector to reduce its dependency on the fossil fuel supply. This article reviews the state-of-the-art of the fluidization technology applied for the gasification of biomass aimed at the production of gas for subsequent synthesis of the liquid energy carriers via, e.g., the Fischer-Tropsch process. It discusses the advantages of the gasification technology over combustion, considers the size of the conversion plant in view of the local biomass availability, assesses the pros and cons of different gasifier types in view of the application of the product gas. Subsequently the article focuses on the fluidized bed technology to discuss the main process parameters and their influence on the product composition and the operability of the gasifier. Finally a synthesis process (FT is introduced shortly to illustrate the necessary gas cleaning steps in view of the purity requirements for the FT feed gas.

  2. 柴油轿车燃用煤基F-T合成油的排放特性%Emission Characteristics of a Diesel Car Fueled with Coal Based Fischer-Tropsch(F-T) Diesel and Fossil Diesel Blends

    Institute of Scientific and Technical Information of China (English)

    胡志远; 程亮; 谭丕强; 楼狄明

    2012-01-01

    依据GB 18352.3-2005Ⅰ型试验循环,对帕萨特柴油轿车燃用沪四柴油、煤基F-T合成油、体积混合比例分别为10%和50%的煤基F-T合成油-沪四柴油混合燃料的CO、NOx、HC、PM和CO2排放特性进行了试验研究,分析了该车燃用F-T合成油尾气污染物排放的环境影响特性.结果表明,GB 18352.3-2005Ⅰ型试验循环中,该车燃用煤基F-T合成油-沪四柴油混合燃料城区行驶循环排放的CO、HC、PM和CO2相对较高,城郊行驶循环排放的NOx相对较高;与沪四柴油比较,该柴油轿车燃用煤基F-T合成油-沪四柴油混合燃料后,其CO、NOx、HC、PM和CO2排放均有不同程度的降低,且产生气溶胶、酸化、全球变暖等环境影响的潜力减小.煤基F-T合成油是一种较理想的柴油替代/补充燃料.%According to the first type test cycle of China national standard GB 18352.3-2005,the CO,NOx,HC,PM and CO2 emission characteristics of a PASSAT diesel car fueled with Shanghai local Ⅳ diesel,coal based Fischer-Tropsch(F-T) diesel,and the blends of coal based F-T diesel and Shanghai local Ⅳ diesel up to 10% and 50% by volume were analyzed respectively.And the environmental impacts such as decreased air quality,health impact,photochemical ozone,global warming,and acidification that could be caused by CO,NOx,HC,PM and CO2 emission of the diesel car were also assessed.The results showed that under GB 18352.3-2005 No.1 test driving cycle,which consisted of four urban driving cycles and one extra urban driving cycle,the CO,HC,PM and CO2 emissions were released mainly in the urban driving cycles whereas the NOx emissions occurred mainly in the extra urban driving cycle.Compared with Shanghai local Ⅳ diesel,all of the CO,NOx,HC,PM and CO2 emissions of the diesel car decreased to different extents when fueled with coal based F-T diesel blends.Moreover,the aerosol generation potential,global warming potential and acidification potential of F-T diesel fueled diesel

  3. Fischer-Tropsch Slurry Reactor modeling

    Energy Technology Data Exchange (ETDEWEB)

    Soong, Y.; Gamwo, I.K.; Harke, F.W. [Pittsburgh Energy Technology Center, PA (United States)] [and others

    1995-12-31

    This paper reports experimental and theoretical results on hydrodynamic studies. The experiments were conducted in a hot-pressurized Slurry-Bubble Column Reactor (SBCR). It includes experimental results of Drakeol-10 oil/nitrogen/glass beads hydrodynamic study and the development of an ultrasonic technique for measuring solids concentration. A model to describe the flow behavior in reactors was developed. The hydrodynamic properties in a 10.16 cm diameter bubble column with a perforated-plate gas distributor were studied at pressures ranging from 0.1 to 1.36 MPa, and at temperatures from 20 to 200{degrees}C, using a dual hot-wire probe with nitrogen, glass beads, and Drakeol-10 oil as the gas, solid, and liquid phase, respectively. It was found that the addition of 20 oil wt% glass beads in the system has a slight effect on the average gas holdup and bubble size. A well-posed three-dimensional model for bed dynamics was developed from an ill-posed model. The new model has computed solid holdup distributions consistent with experimental observations with no artificial {open_quotes}fountain{close_quotes} as predicted by the earlier model. The model can be applied to a variety of multiphase flows of practical interest. An ultrasonic technique is being developed to measure solids concentration in a three-phase slurry reactor. Preliminary measurements have been made on slurries consisting of molten paraffin wax, glass beads, and nitrogen bubbles at 180 {degrees}C and 0.1 MPa. The data show that both the sound speed and attenuation are well-defined functions of both the solid and gas concentrations in the slurries. The results suggest possibilities to directly measure solids concentration during the operation of an autoclave reactor containing molten wax.

  4. Improved Fischer-Tropsch Slurry Reactors

    International Nuclear Information System (INIS)

    The conversion of synthesis gas to hydrocarbons or alcohols involves highly exothermic reactions. Temperature control is a critical issue in these reactors for a number of reasons. Runaway reactions can be a serious safety issue, even raising the possibility of an explosion. Catalyst deactivation rates tend to increase with temperature, particularly of there are hot spots in the reactor. For alcohol synthesis, temperature control is essential because it has a large effect on the selectivity of the catalysts toward desired products. For example, for molybdenum disulfide catalysts unwanted side products such as methane, ethane, and propane are produced in much greater quantities if the temperature increases outside an ideal range. Slurry reactors are widely regarded as an efficient design for these reactions. In a slurry reactor a solid catalyst is suspended in an inert hydrocarbon liquid, synthesis gas is sparged into the bottom of the reactor, un-reacted synthesis gas and light boiling range products are removed as a gas stream, and heavy boiling range products are removed as a liquid stream. This configuration has several positive effects for synthesis gas reactions including: essentially isothermal operation, small catalyst particles to reduce heat and mass transfer effects, capability to remove heat rapidly through liquid vaporization, and improved flexibility on catalyst design through physical mixtures in addition to use of compositions that cannot be pelletized. Disadvantages include additional mass transfer resistance, potential for significant back-mixing on both the liquid and gas phases, and bubble coalescence. In 2001 a multiyear project was proposed to develop improved FT slurry reactors. The planned focus of the work was to improve the reactors by improving mass transfer while considering heat transfer issues. During the first year of the project the work was started and several concepts were developed to prepare for bench-scale testing. PowerEnerCat was unable to raise their cash contribution for the project, and the work was stopped. This report summarizes some of the progress of the project and the concepts that were intended for experimental tests.

  5. Advanced Situation Awareness Technologies Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Advanced Situation Awareness Technologies (ASAT) will facilitate exploration of the moon surface, and other planetary bodies. ASAT will create an Advanced Situation...

  6. Advanced Remediation Technologies

    International Nuclear Information System (INIS)

    The United States Department of Energy (DOE), Office of Environmental Management (EM) is responsible for the cleanup of nation's nuclear weapons program legacy wastes, along with waste associated with nuclear energy programs and research. The EM cleanup efforts continue to progress, however the cleanup continues to be technologically complex, heavily regulated, long-term; and the effort also has a high life cycle cost estimate (LCCE) effort. Over the past few years, the EM program has undergone several changes to accelerate its cleanup efforts with varying degrees of success. This article will provide some insight into the Advanced Remediation Technologies (ART) projects that may enhance cleanup efforts and reduce life cycle costs. (authors)

  7. Ultraclean Fuels Production and Utilization for the Twenty-First Century: Advances toward Sustainable Transportation Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Fox, Elise B.; Liu, Zhong-Wen; Liu, Zhao-Tie

    2013-11-21

    Ultraclean fuels production has become increasingly important as a method to help decrease emissions and allow the introduction of alternative feed stocks for transportation fuels. Established methods, such as Fischer-Tropsch, have seen a resurgence of interest as natural gas prices drop and existing petroleum resources require more intensive clean-up and purification to meet stringent environmental standards. This review covers some of the advances in deep desulfurization, synthesis gas conversion into fuels and feed stocks that were presented at the 245th American Chemical Society Spring Annual Meeting in New Orleans, LA in the Division of Energy and Fuels symposium on "Ultraclean Fuels Production and Utilization".

  8. Advanced Situation Awareness Technologies Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Advanced Situation Awareness Technologies (ASAT) will facilitate exploration of the moon surface, and other planetary bodies. This powerful technology will also...

  9. Buildings for advanced technology

    CERN Document Server

    Teague, E; Murday, James

    2015-01-01

    This book deals with the design and construction of buildings for nanoscale science and engineering research. The information provided in this book is useful for designing and constructing buildings for such advanced technologies as nanotechnology, nanoelectronics and biotechnology. The book outlines the technology challenges unique to each of the building environmental challenges outlined below and provides best practices and examples of engineering approaches to address them: • Establishing and maintaining critical environments: temperature, humidity, and pressure • Structural vibration isolation • Airborne vibration isolation (acoustic noise) • Isolation of mechanical equipment-generated vibration/acoustic noise • Cost-effective power conditioning • Grounding facilities for low electrical interference • Electromagnetic interference (EMI)/Radio frequency interference (RFI) isolation • Airborne particulate contamination • Airborne organic and chemical contamination • Environment, safety a...

  10. Advanced finite element technologies

    CERN Document Server

    Wriggers, Peter

    2016-01-01

    The book presents an overview of the state of research of advanced finite element technologies. Besides the mathematical analysis, the finite element development and their engineering applications are shown to the reader. The authors give a survey of the methods and technologies concerning efficiency, robustness and performance aspects. The book covers the topics of mathematical foundations for variational approaches and the mathematical understanding of the analytical requirements of modern finite element methods. Special attention is paid to finite deformations, adaptive strategies, incompressible, isotropic or anisotropic material behavior and the mathematical and numerical treatment of the well-known locking phenomenon. Beyond that new results for the introduced approaches are presented especially for challenging nonlinear problems.

  11. State Technologies Advancement Collaborative

    Energy Technology Data Exchange (ETDEWEB)

    David S. Terry

    2012-01-30

    The U. S. Department of Energy (DOE), National Association of State Energy Officials (NASEO), and Association of State Energy Research and Technology Transfer Institutions (ASERTTI) signed an intergovernmental agreement on November 14, 2002, that allowed states and territories and the Federal Government to better collaborate on energy research, development, demonstration and deployment (RDD&D) projects. The agreement established the State Technologies Advancement Collaborative (STAC) which allowed the states and DOE to move RDD&D forward using an innovative competitive project selection and funding process. A cooperative agreement between DOE and NASEO served as the contracting instrument for this innovative federal-state partnership obligating funds from DOE's Office of Energy Efficiency and Renewable Energy and Office of Fossil Energy to plan, fund, and implement RDD&D projects that were consistent with the common priorities of the states and DOE. DOE's Golden Field Office provided Federal oversight and guidance for the STAC cooperative agreement. The STAC program was built on the foundation of prior Federal-State efforts to collaborate on and engage in joint planning for RDD&D. Although STAC builds on existing, successful programs, it is important to note that it was not intended to replace other successful joint DOE/State initiatives such as the State Energy Program or EERE Special Projects. Overall the STAC process was used to fund, through three competitive solicitations, 35 successful multi-state research, development, deployment, and demonstration projects with an overall average non-federal cost share of 43%. Twenty-two states were awarded at least one prime contract, and organizations in all 50 states and some territories were involved as subcontractors in at least one STAC project. Projects were funded in seven program areas: (1) Building Technologies, (2) Industrial Technologies, (3) Transportation Technologies, (4) Distributed Energy

  12. Mobility chains analysis of technologies for passenger cars and light duty vehicles fueled with biofuels : application of the Greet model to project the role of biomass in America's energy future (RBAEF) project.

    Energy Technology Data Exchange (ETDEWEB)

    Wu, M.; Wu, Y.; Wang, M; Energy Systems

    2008-01-31

    The Role of Biomass in America's Energy Future (RBAEF) is a multi-institution, multiple-sponsor research project. The primary focus of the project is to analyze and assess the potential of transportation fuels derived from cellulosic biomass in the years 2015 to 2030. For this project, researchers at Dartmouth College and Princeton University designed and simulated an advanced fermentation process to produce fuel ethanol/protein, a thermochemical process to produce Fischer-Tropsch diesel (FTD) and dimethyl ether (DME), and a combined heat and power plant to co-produce steam and electricity using the ASPEN Plus{trademark} model. With support from the U.S. Department of Energy (DOE), Argonne National Laboratory (ANL) conducted, for the RBAEF project, a mobility chains or well-to-wheels (WTW) analysis using the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model developed at ANL. The mobility chains analysis was intended to estimate the energy consumption and emissions associated with the use of different production biofuels in light-duty vehicle technologies.

  13. USMC UGS technology advancements

    Science.gov (United States)

    Hartup, David C.; Barr, Michael E.; Hirz, Philip M.; Kipp, Jason; Fishburn, Thomas A.; Waller, Ezra S.; Marks, Brian A.

    2008-04-01

    Technology advancements for the USMC UGS system are described. Integration of the ARL Blue Radio/CSR into the System Controller and Radio Repeater permit the TRSS system to operate seamlessly within the Family of UGS concept. In addition to the Blue Radio/CSR, the TRSS system provides VHF and SATCOM radio links. The TRSS system is compatible with a wide range of imagers, including those with both analog and digital interfaces. The TRSS System Controller permits simultaneous monitoring of 2 camera inputs. To complement enhanced compatibility and improved processing, the mechanical housing of the TRSS System Controller has been updated. The SDR-II, a system monitoring device, also incorporates four Blue Radio/CSRs along with other communication capabilities, making it an ideal choice for a monitoring station within the Family of UGS. Field testing of L-3 Nova's UGS system at YPG has shown flawless performance, capturing all 126 targets.

  14. Nuclear propulsion technology advanced fuels technology

    Science.gov (United States)

    Stark, Walter A., Jr.

    1993-01-01

    Viewgraphs on advanced fuels technology are presented. Topics covered include: nuclear thermal propulsion reactor and fuel requirements; propulsion efficiency and temperature; uranium fuel compounds; melting point experiments; fabrication techniques; and sintered microspheres.

  15. Advances in FIV vaccine technology

    OpenAIRE

    Uhl, Elizabeth W.; Martin, Marcus; Coleman, James K.; Yamamoto, Janet K

    2008-01-01

    Advances in vaccine technology are occurring in the molecular techniques used to develop vaccines and in the assessment of vaccine efficacy, allowing more complete characterization of vaccine-induced immunity correlating to protection. FIV vaccine development has closely mirrored and occasionally surpassed the development of HIV-1 vaccine, leading to first licensed technology. This review will discuss technological advances in vaccine designs, challenge infection assessment, and characterizat...

  16. Advancement in Engineering Technology

    DEFF Research Database (Denmark)

    Kalia, Kartik; Rehman, M. Atiqur; Hussain, Dil muhammed Akbar;

    2016-01-01

    In this paper we will be discussing about the impact of technology on our daily lives. How everybody is dependent upon technology in one or other way. Methods/Statistical Analysis: Technology has played a significant role in the evolution of the society. Science has produced many new ideas...... but to harvest those ideas, technology is a must. With the huge requirement of engineering equipment's, the industry needs specialists who can manage and operate these technologies. Detailed information about the merits and demerits of technology is also mentioned in this paper. Findings: Technology has affected...... the environment on a great scale; in some cases, technology is even replacing human being or use of manpower. So proper counter measures have been mentioned, which can be used to control and limit harmful effect....

  17. Advanced fuel technology and performance

    International Nuclear Information System (INIS)

    The purpose of the Advisory Group Meeting on Advanced Fuel Technology and Performance was to review the experience of advanced fuel fabrication technology, its performance, peculiarities of the back-end of the nuclear fuel cycle with regard to all types of reactors and to outline the future trends. As a result of the meeting recommendations were made for the future conduct of work on advanced fuel technology and performance. A separate abstract was prepared for each of the 20 papers in this issue

  18. Processor Technological Advancement

    Directory of Open Access Journals (Sweden)

    Sapan kr. Gupta, Manuj Gupta, and Rahul Pandey

    2012-08-01

    Full Text Available During the last decade Intel has introduced several technologies for different generation processors. Different architectures are added featuring enhanced energy efficiency, power management, affordable performance, fast execution, multitasking demands, optimized multithreading, CPU performance boost, higher data throughput, improved virtualization performance, smart security. This paper provides insight into recently added technologies and architectures. This paper discusses about the features enabled by the latest technologies along with the current issues and future prospects. This paper also deals with some constraints and limitations of these technologies highlighting the upcoming solution and the options

  19. Advanced Infrared Technology and Applications

    OpenAIRE

    Ovidio Salvetti; Laura Abbozzo Ronchi; Carlo Corsi; Antoni Rogalski; Marija Strojnik

    2013-01-01

    Nowadays, advanced infrared techniques are a key ingredient in disparate applications, ranging from medical diagnostics and treatment to industrial inspection and environmental monitoring. We believe that the success of such infrared applications highly depends on a continuous exchange between scientific advances and technological progresses.

  20. Advances in production technology

    CERN Document Server

    2015-01-01

    This edited volume contains the selected papers presented at the scientific board meeting of the German Cluster of Excellence on “Integrative Production Technology for High-Wage Countries”,  held in November 2014. The topical structure of the book is clustered in six sessions: Integrative Production Technology, Individualised Production, Virtual Production Systems, Integrated Technologies, Self-Optimising Production Systems and Human Factors in Production Technology. The Aachen perspective on a holistic theory of production is complemented by conference papers from external leading researchers in the fields of production, materials science and bordering disciplines. The target audience primarily comprises research experts and practitioners in the field but the book may also be beneficial for graduate students.

  1. Advances in photovoltaic technology

    Science.gov (United States)

    Landis, G. A.; Bailey, S. G.

    1992-01-01

    The advances in solar cell efficiency, radiation tolerance, and cost in the last 10 years are presented. The potential performance of thin-film solar cells in space is examined, and the cost and the historical trends in production capability of the photovoltaics industry are considered with respect to the needs of satellite solar power systems. Attention is given to single-crystal cells, concentrator and cascade cells, and thin-film solar cells.

  2. Advanced technology in neurosurgery

    International Nuclear Information System (INIS)

    Technological improvements in neurosurgery are discussed. The use of surgical lasers, ultrasound aspirators, bipolar coagulator and operative microscopes for surgery of deep-seated neoplasms and vascular malformations is discussed. Intraoperative monitoring, chronotherapy, chronic neurostimulation and stereotactic interstitial irradiation are covered and indications for interventional neuroradiology are reviewed

  3. Advanced technology in neurosurgery

    Energy Technology Data Exchange (ETDEWEB)

    Pluchino, F.; Broggi, G.

    1987-01-01

    Technological improvements in neurosurgery are discussed. The use of surgical lasers, ultrasound aspirators, bipolar coagulator and operative microscopes for surgery of deep-seated neoplasms and vascular malformations is discussed. Intraoperative monitoring, chronotherapy, chronic neurostimulation and stereotactic interstitial irradiation are covered and indications for interventional neuroradiology are reviewed.

  4. Advanced Metasearch Engine Technology

    CERN Document Server

    Meng, Weiyi

    2010-01-01

    Among the search tools currently on the Web, search engines are the most well known thanks to the popularity of major search engines such as Google and Yahoo!. While extremely successful, these major search engines do have serious limitations. This book introduces large-scale metasearch engine technology, which has the potential to overcome the limitations of the major search engines. Essentially, a metasearch engine is a search system that supports unified access to multiple existing search engines by passing the queries it receives to its component search engines and aggregating the returned

  5. Advances in water resources technology

    Science.gov (United States)

    The presentation of technological advances in the field of water resources will be the focus of Advances in Water Resources Technology, a conference to be held in Athens, Greece, March 20-23, 1991. Organized by the European Committee for Water Resources Management, in cooperation with the National Technical University of Athens, the conference will feature state-of-the art papers, contributed original research papers, and poster papers. Session subjects will include surface water, groundwater, water resources conservation, water quality and reuse, computer modeling and simulation, real-time control of water resources systems, and institutions and methods for technology.The official language of the conference will be English. Special meetings and discussions will be held for investigating methods of effective technology transfer among European countries. For this purpose, a wide representation of research institutions, universities and companies involved in water resources technology will be attempted.

  6. Technological advances at Pelindaba

    International Nuclear Information System (INIS)

    NUCOR has recently established the Nuclear Techniques Industrial Service (NTIS) with the specific purpose of providing a professional service to industry on a commercial basis. In the article some investigations conducted for industry will be briefly described, with neutron radiography as a complementary technique to conventional industrial radiography being dealt with in greater detail. The applications of nuclear technology in industry are very versatile, both in range of applications as well as in the variety of techniques which can be used. It's applications include the following: i) rapid assay of gold purity; behaviour of potassium in a blast furnace; performance of continuous massecuite crystalysers; air-flow measurement in mine shafts; monitoring of electrode length in an electrical arc furnace; monitoring of termite damage in wooden utility poles; behaviour of pollutants in the Crocodile river; distribution of boron in steel and in measuring the dynamic behaviour of materials in processing plants

  7. Advanced information technology

    International Nuclear Information System (INIS)

    The potential risk of critical situations at hazardous industrial plants has drawn increased attention to emergency organisations. The emphasis on these organisations is to minimise the environmental effects of serious, although unlikely, disturbances in operation. Experience gained from previous incidents and emergency drills has revealed the complexity that must be faced in making these organisations work properly. Modern information technology may be used in order to develop more reliable preparedness systems. These problems are being treated in a joint Nordic project, NKA/INF, with participating research institutes from Denmark, Finland, Norway, and Sweden. The project started in 1985 and is expected to be finished in 1989. This report gives an overview of the project and a short description of the conceptual ideas behind the project. (author)

  8. Advanced Aerogel Technology

    Science.gov (United States)

    Jones, Steven

    2013-01-01

    The JPL Aerogel Laboratory has made aerogels for NASA flight missions, e.g., Stardust, 2003 Mars Exploration Rovers and the 2011 Mars Science Laboratory, as well as NASA research projects for the past 14 years. During that time it has produced aerogels of a range of shapes, sizes, densities and compositions. Research is ongoing in the development of aerogels for future sample capture and return missions and for thermal insulation for both spacecraft and scientific instruments. For the past several years, the JPL Aerogel Laboratory has been developing, producing and testing a new composite material for use as the high temperature thermal insulation in the Advanced Sterling Radioisotope Generator (ASRG) being developed by Lockheed Martin and NASA. The composite is made up of a glass fiber felt, silica aerogel, Titania powder, and silica powder. The oxide powders are included to reduce irradiative heat transport at elevated temperatures. These materials have thermal conductivity values that are the same as the best commercially produced high temperature insulation materials, and yet are 40% lighter. By greatly reducing the amount of oxide powder in the composite, the density, and therefore for the value of the thermal conductivity, would be reduced. The JPL Aerogel Laboratory has experimented with using glass fiber felt, expanded glass fiber felt and loose fibers to add structural integrity to silica aerogels. However, this work has been directed toward high temperature applications. By conducting a brief investigation of the optimal combination of fiber reinforcement and aerogel density, a durable, extremely efficient thermal insulation material for ambient temperature applications would be produced. If a transparent thermal insulation is desired, then aerogel is an excellent candidate material. At typical ambient temperatures, silica aerogel prevents the transport of heat via convection and conduction due to its highly porous nature. To prevent irradiative thermal

  9. Advanced solar thermal receiver technology

    Science.gov (United States)

    Kudirka, A. A.; Leibowitz, L. P.

    1980-01-01

    Development of advanced receiver technology for solar thermal receivers designed for electric power generation or for industrial applications, such as fuels and chemical production or industrial process heat, is described. The development of this technology is focused on receivers that operate from 1000 F to 3000 F and above. Development strategy is mapped in terms of application requirements, and the related system and technical requirements. Receiver performance requirements and current development efforts are covered for five classes of receiver applications: high temperature, advanced Brayton, Stirling, and Rankine cycle engines, and fuels and chemicals.

  10. Advanced Technology for Engineering Education

    Science.gov (United States)

    Noor, Ahmed K. (Compiler); Malone, John B. (Compiler)

    1998-01-01

    This document contains the proceedings of the Workshop on Advanced Technology for Engineering Education, held at the Peninsula Graduate Engineering Center, Hampton, Virginia, February 24-25, 1998. The workshop was jointly sponsored by the University of Virginia's Center for Advanced Computational Technology and NASA. Workshop attendees came from NASA, other government agencies, industry and universities. The objectives of the workshop were to assess the status of advanced technologies for engineering education and to explore the possibility of forming a consortium of interested individuals/universities for curriculum reform and development using advanced technologies. The presentations covered novel delivery systems and several implementations of new technologies for engineering education. Certain materials and products are identified in this publication in order to specify adequately the materials and products that were investigated in the research effort. In no case does such identification imply recommendation or endorsement of products by NASA, nor does it imply that the materials and products are the only ones or the best ones available for this purpose. In many cases equivalent materials and products are available and would probably produce equivalent results.

  11. Advancing the technologies of CANDU

    International Nuclear Information System (INIS)

    CANDU standard product design will continue to evolve, building upon the success of current operating units. Progressive improvements and enhancements will continue to be made to the CANDU system with heavy water moderated, pressure tube reactor technology of high neutron efficiency, based on the results of advanced technology R and D and operational experience from operating CANDU stations. The directions of development will respond to customer's requirements for economical, reliable and safe generating stations

  12. Energy Storage (II): Developing Advanced Technologies

    Science.gov (United States)

    Robinson, Arthur L

    1974-01-01

    Energy storage, considered by some scientists to be the best technological and economic advancement after advanced nuclear power, still rates only modest funding for research concerning the development of advanced technologies. (PEB)

  13. Advances in PCB decontamination technologies

    International Nuclear Information System (INIS)

    Since 1985 several million kilograms of PCB equipment and millions of litres of PCB contaminated oil have been processed in Canada for reduction of PCB concentrations below government guidelines. Advances in extraction and metal recovery from electrical equipment, chemical dechlorination and distillation of PCB-contaminated oils were the significant technological options utilized. For example, using the Decontaksolv technology owners of PCB equipment in Canada have decontaminated three million kilograms of electrical equipment, which resulted in the reintegration of 2.7 million kilograms of useful metals (steel, copper, aluminium) into the economic circuit. The equipment decontaminated included transformers, electromagnets, relays, radiators, circuit breakers, tanks, pipes, valves, and drums. The most recent advances in this technology include improvements that makes the economical processing of capacitors, possible. Chemical dechlorination has virtually eliminated PCB-contaminated oils which are normally present in large transformers, to the point where some service companies have curtailed or discontinued their oil decontamination activities in Canada. Recent advances in this technology center around techniques for the decontamination of waste hydrocarbons, and to a lesser extent, dielectric fluids. Two example projects to illustrate recent advances have been briefly described

  14. Advanced Communications Technology Satellite (ACTS)

    Science.gov (United States)

    Gedney, Richard T.; Schertler, Ronald J.

    1989-06-01

    The NASA Advanced Communications Technology Satellite (ACTS) was conceived to help maintain U.S. leadership in the world's communications-satellite market. This experimental satellite is expected to be launched by NASA in 1992 and to furnish the technology necessary for establishing very small aperture terminal digital networks which provide on-demand full-mesh connectivity, and 1.544-MBPS services with only a single hop. Utilizing on-board switching and processing, each individual voice or data circuit can be separately routed to any location in the network. This paper provides an overview of the ACTS and discusses the value of the technology for future communications systems.

  15. SP-100 advanced technology program

    International Nuclear Information System (INIS)

    The goal of the triagency SP-100 Program is to develop long-lived, compact, lightweight, survivable nuclear reactor space power systems for application to the power range 50 kWe to 1 MWe. The successful development of these systems should enable or significantly enhance many of the future NASA civil and commercial missions. The NASA SP-100 Advanced Technology Program strongly augments the parallel SP-100 Ground Engineering System Development program and enhances the chances for success of the overall SP-100 program. The purpose of this paper is to discuss the key technical elements of the Advanced Technology Program and the progress made in the initial year and a half of the project

  16. Large floating structures technological advances

    CERN Document Server

    Wang, BT

    2015-01-01

    This book surveys key projects that have seen the construction of large floating structures or have attained detailed conceptual designs. This compilation of key floating structures in a single volume captures the innovative features that mark the technological advances made in this field of engineering, and will provide a useful reference for ideas, analysis, design, and construction of these unique and emerging urban projects to offshore and marine engineers, urban planners, architects and students.

  17. GT Advanced Technologies Inc. Bankruptcy

    OpenAIRE

    Souply-Pierard, Fernand

    2014-01-01

    GT Advanced Technologies (GTAT), une société américaine de haute technologie produisant du saphir synthétique (fournisseur d’Apple), a fait faillite ce lundi 6 octobre 2014 et s’est placée sous la protection du chapitre 11 de la loi américaine sur la faillite. Cette faillite était-elle prévisible ?

  18. Advanced tufted carpet patterning technology

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    After a review of the tufting industry's development, and a brief introduction to available systems for producing patterned tufted carpets, the principle of ICN (Individually Controlled Needle) and the related advanced tufting technology Colortec are presented. Finally, Colortec machine, Axminster weaving machine, and Wilton loom are compared. It is believed that the Cobble Colortec machine is a significant jump forward in the tufted carpets industry as it now allows access to all major carpet markets in a competitive fashion.

  19. Center for Advanced Separation Technology

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, Rick

    2013-09-30

    The U.S. is the largest producer of mining products in the world. In 2011, U.S. mining operations contributed a total of $232 billion to the nation’s GDP plus $138 billion in labor income. Of this the coal mining industry contributed a total of $97.5 billion to GDP plus $53 billion in labor income. Despite these contributions, the industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Originally set up by Virginia Tech and West Virginia University, CAST is now a five-university consortium – Virginia Tech, West Virginia University, University of Kentucky, University of Utah and Montana Tech, - that is supported through U.S. DOE Cooperative Agreement No. DE-FE0000699, Center for Advanced Separation Technology. Much of the research to be conducted with Cooperative Agreement funds will be longer term, high-risk, basic research and will be carried out in two broad areas: Advanced Pre-Combustion Clean Coal Technologies and Gas-Gas Separations. Distribution of funds is handled via competitive solicitation of research proposals through Site Coordinators at the five member universities. These were reviewed and the selected proposals were forwarded these to the DOE/NETL Project Officer for final review and approval. The successful projects are listed below by category, along with abstracts from their final reports.

  20. Advanced USC technology in Japan

    Energy Technology Data Exchange (ETDEWEB)

    Fukuda, Masafumi [National Institute for Materials Science, Tsukuba, Ibaraki (Japan). High Temperature Materials Center

    2010-07-01

    The 600deg-C class Ultra Super-Critical(USC) steam condition technology was mainly developed through projects led by J-Power in the '80s and 90s'. In 2001, the project was successfully finished with newly developed 9-12% chromium steels. These materials were selected for the major parts of the USC power plants in Japan and almost half of the coal power plants have the USC steam condition today. However, aged plants, which were built in the '70s and early '80s will reach the point where they will need to be rebuilt or refurbished in the near future. The steam temperatures of the older plants are 538 deg-C or 566deg-C. We did a case study, retrofitting these plants with the USC and an advanced USC technology that takes a 700deg-C class steam temperature to increase thermal efficiency and to reduce CO{sub 2} emissions. The study showed that the advanced USC Technology(A-USC) is suitable for the retrofitting of aged plants and can reduce CO{sub 2} emissions by about 15%. The Japanese government launched the ''Cool Earth-Innovative Energy Technology Program'' in 2008 March to promote international cooperation and actively contribute to substantial global greenhouse gas emissions reductions. 21 technologies that will contribute to substantial reductions in CO{sub 2} emissions by efficiency improvement and low carbonization were selected. The A-USC that aims at 46% (net, HHV) thermal efficiency of coal power generation is included in the technologies. We started a large-scale development project of the A-USC technology in 2008 August. 700deg-C class boiler, turbine and valve technologies, which include high temperature material technology, will be developed. Some candidate materials for boilers are being tested. Turbine rotor and casing materials are being developed and tested, as well. Two years from the beginning of the project, we have obtained some useful test results regarding the candidate materials. (orig.)

  1. Advances in Genome Biology & Technology

    Energy Technology Data Exchange (ETDEWEB)

    Thomas J. Albert, Jon R. Armstrong, Raymond K. Auerback, W. Brad Barbazuk, et al.

    2007-12-01

    This year's meeting focused on the latest advances in new DNA sequencing technologies and the applications of genomics to disease areas in biology and biomedicine. Daytime plenary sessions highlighted cutting-edge research in areas such as complex genetic diseases, comparative genomics, medical sequencing, massively parallel DNA sequencing, and synthetic biology. Technical approaches being developed and utilized in contemporary genomics research were presented during evening concurrent sessions. Also, as in previous years, poster sessions bridged the morning and afternoon plenary sessions. In addition, for the third year in a row, the Advances in Genome Biology and Technology (AGBT) meeting was preceded by a pre-meeting workshop that aimed to provide an introductory overview for trainees and other meeting attendees. This year, speakers at the workshop focused on next-generation sequencing technologies, including their experiences, findings, and helpful advise for others contemplating using these platforms in their research. Speakers from genome centers and core sequencing facilities were featured and the workshop ended with a roundtable discussion, during which speakers fielded questions from the audience.

  2. Influence of Preparation Methods on Catalytic Performance of Double Mesoporous Co-Based Catalysts for Fischer-Tropsch Synthesis%制备方法对双介孔钴基催化剂结构及其费-托反应性能的影响

    Institute of Scientific and Technical Information of China (English)

    王俊刚; 孙予罕; 李德宝; 侯博; 贾丽涛; 贾利宏; 孙志强; 刘斌; 郭金刚; 任润厚

    2011-01-01

    A series of cobalt-based catalyst samples supported on double mesoporous MCM-41 for Fischer-Tropsch synthesis (FTS) were prepared using three methods, incipient-wetness impregnation (IWI), vapor-induced hydrolysis (VIH), and excessive impregnation (EI). The catalyst samples were characterized by N2 physisorption, X-ray diffraction (XRD), temperature-programmed reduction (H2-TPR) and Raman spectroscopy. The N2 physisorption results showed that the samples prepared by IWI and VIH retained the double mesoporous character. and the cobalt particles were mainly located in the pore. The FTS results showed that the reducibility and dispersion of active species of the samples prepared by IWI and EI were very high. The catalyst prepared by IWI had the smallest Co3O4 crystallite size and the highest dispersion and showed higher FTS activity, lower CH4 selectivity and higher C5+ selectivity.%以双介孔分布MCM-41分子筛为载体,采用等体积浸渍、氨水气相诱导水解和过量浸渍法制备了费-托合成钴摹催化剂,并考察了它们的孔结构、活性物种分布及费-托合成催化性能.结粜表明,采用等体积浸渍法和氨水气相诱导水解法制备的催化剂都保持了较好的双介孔特性,Co颗粒人部分位于分子筛的孔道内部.过量浸渍法和等体积浸渍法制备的催化剂上Co物种的还原度和分散度均较高,尤其后者上Co分散度更高,因而具有较低的CH4选择性和较高的C5+选择性.

  3. Advanced Artificial Intelligence Technology Testbed

    Science.gov (United States)

    Anken, Craig S.

    1993-01-01

    The Advanced Artificial Intelligence Technology Testbed (AAITT) is a laboratory testbed for the design, analysis, integration, evaluation, and exercising of large-scale, complex, software systems, composed of both knowledge-based and conventional components. The AAITT assists its users in the following ways: configuring various problem-solving application suites; observing and measuring the behavior of these applications and the interactions between their constituent modules; gathering and analyzing statistics about the occurrence of key events; and flexibly and quickly altering the interaction of modules within the applications for further study.

  4. Advanced Modular Inverter Technology Development

    Energy Technology Data Exchange (ETDEWEB)

    Adam Szczepanek

    2006-02-04

    Electric and hybrid-electric vehicle systems require an inverter to convert the direct current (DC) output of the energy generation/storage system (engine, fuel cells, or batteries) to the alternating current (AC) that vehicle propulsion motors use. Vehicle support systems, such as lights and air conditioning, also use the inverter AC output. Distributed energy systems require an inverter to provide the high quality AC output that energy system customers demand. Today's inverters are expensive due to the cost of the power electronics components, and system designers must also tailor the inverter for individual applications. Thus, the benefits of mass production are not available, resulting in high initial procurement costs as well as high inverter maintenance and repair costs. Electricore, Inc. (www.electricore.org) a public good 501 (c) (3) not-for-profit advanced technology development consortium assembled a highly qualified team consisting of AeroVironment Inc. (www.aerovironment.com) and Delphi Automotive Systems LLC (Delphi), (www.delphi.com), as equal tiered technical leads, to develop an advanced, modular construction, inverter packaging technology that will offer a 30% cost reduction over conventional designs adding to the development of energy conversion technologies for crosscutting applications in the building, industry, transportation, and utility sectors. The proposed inverter allows for a reduction of weight and size of power electronics in the above-mentioned sectors and is scalable over the range of 15 to 500kW. The main objective of this program was to optimize existing AeroVironment inverter technology to improve power density, reliability and producibility as well as develop new topology to reduce line filter size. The newly developed inverter design will be used in automotive and distribution generation applications. In the first part of this program the high-density power stages were redesigned, optimized and fabricated. One of the main

  5. Market competitive Fischer-Tropsch diesel production. Techno-economic and environmental analysis of a thermo-chemical Biorefinery process for large scale biosyngas-derived FT-diesel production

    International Nuclear Information System (INIS)

    The contents of the presentation are summarized as follows: Introduction of the Dutch policy framework, Biomass availability and contractibility, and Biomass transportation fuels: current use and perspectives; Next subject concerns Large-scale BioSyngas production: optimum gasification technology; slagging EF-gasifier; identification and modelling biomass-conversion chains; overall energetic chain efficiencies, economics, environmental char; and a comparison with fossil-derived diesel. Further subjects are Current technological SOTA and R, D and D-trajectory; Pre-design 600 MWth demonstration plant; and the Conclusions

  6. Latest Technology Advances in Cosmaceuticals

    Directory of Open Access Journals (Sweden)

    Nageen Arora

    2012-07-01

    Full Text Available World consumers are looking for personal care products that supply multiple benefits with minimal efforts. They also expect the latest technology advances to be incorporated into innovative formulations. The trend toward therapeutic cosmetics will lead to a better understanding of modern ingredients and their assessment techniques. To obtain skin care formulations with real consumer-perceivable benefits and to optimize sensory attributes, formulators are resorting to technology that until recently was exclusively used in cosmetic products. Various formulations comes under special delivery systems like Vesicular, Particulate systems, emulsions type Particulate type and other delivery systems along with their applications are shown in this article, as it results in an economic uplift of cosmetic industry in various parts of the world. Little evidence is seen that nanoparticles in cosmetics and sunscreen might be a problem at this time and its need is further explored for a better understanding of these novel technologies. Thus, novel cosmaceutical delivery systems reviewed here possess enormous potential as next-generation smarter carrier systems.

  7. Synthetic fuels technology overview with health and environmental impacts

    Science.gov (United States)

    Bentz, E. J., Jr.; Salmon, E. J.

    1981-06-01

    An introduction is presented to the following synthetic fuels technologies: (1) the Lurgi gasification of coal; (2) the Fischer-Tropsch liquefaction of coal; (3) coal-methanol conversion; (4) donor solvent gas liquefaction; (5) Tosco surface shale retorting; ethanol production from coal; and (6) the coal-methanol-gasoline conversion process. After establishing the system characteristics of these six technologies, consideration is given to their potential major health, safety, environmental and socio-economic impacts at the global, regional and local levels. It is determined that the main global consequence of synfuels development is climate modification, to which may be added the regional impact of dry and wet deposition of gaseous and particulate pollutants, and land and water quality deterioration due to soil erosion at the local level.

  8. Advances in medical diagnostic technology

    CERN Document Server

    Lai, Khin Wee; Mohamad Salim, Maheza Irna; Ong, Sang-Bing; Utama, Nugraha Priya; Myint, Yin Mon; Mohd Noor, Norliza; Supriyanto, Eko

    2014-01-01

    This book provides the most recent findings and knowledge in advanced diagnostics technology, covering a wide spectrum including brain activity analysis, breast and lung cancer detection, echocardiography, computer aided skeletal assessment to mitochondrial biology imaging at the cellular level. The authors explored magneto acoustic approaches and tissue elasticity imaging for the purpose of breast cancer detection. Perspectives in fetal echocardiography from an image processing angle are included. Diagnostic imaging in the field of mitochondrial diseases as well as the use of Computer-Aided System (CAD) are also discussed in the book. This book will be useful for students, lecturers or professional researchers in the field of biomedical sciences and image processing.

  9. General survey of Korean advanced technology

    International Nuclear Information System (INIS)

    This book includes advanced technology, world trend of advanced technology, technological innovation study for strengthening international competitiveness, patterns of Korea industrialization and its causes, structures of Korea electronic equipment and development direction, middle and long-term prospects of home appliance, the world of computer, current situation and prospect of robot industry, homework for strengthening international competitiveness of machine industry, direction for rationalization of materials industry, current situations of technical textile, future technology of developed countries, and trend of Korea technological activities.

  10. Advanced Technology Composite Fuselage - Manufacturing

    Science.gov (United States)

    Wilden, K. S.; Harris, C. G.; Flynn, B. W.; Gessel, M. G.; Scholz, D. B.; Stawski, S.; Winston, V.

    1997-01-01

    The goal of Boeing's Advanced Technology Composite Aircraft Structures (ATCAS) program is to develop the technology required for cost-and weight-efficient use of composite materials in transport fuselage structure. Carbon fiber reinforced epoxy was chosen for fuselage skins and stiffening elements, and for passenger and cargo floor structures. The automated fiber placement (AFP) process was selected for fabrication of stringer-stiffened and sandwich skin panels. Circumferential and window frames were braided and resin transfer molded (RTM'd). Pultrusion was selected for fabrication of floor beams and constant-section stiffening elements. Drape forming was chosen for stringers and other stiffening elements cocured to skin structures. Significant process development efforts included AFP, braiding, RTM, autoclave cure, and core blanket fabrication for both sandwich and stiffened-skin structure. Outer-mold-line and inner-mold-line tooling was developed for sandwich structures and stiffened-skin structure. The effect of design details, process control and tool design on repeatable, dimensionally stable, structure for low cost barrel assembly was assessed. Subcomponent panels representative of crown, keel, and side quadrant panels were fabricated to assess scale-up effects and manufacturing anomalies for full-scale structures. Manufacturing database including time studies, part quality, and manufacturing plans were generated to support the development of designs and analytical models to access cost, structural performance, and dimensional tolerance.

  11. ADVANCED RECIPROCATING COMPRESSION TECHNOLOGY (ARCT)

    Energy Technology Data Exchange (ETDEWEB)

    Danny M. Deffenbaugh; Klaus Brun; Ralph E. Harris; J. Pete Harrell; Robert J. Mckee; J. Jeffrey Moore; Steven J. Svedeman; Anthony J. Smalley; Eugene L. Broerman; Robert A Hart; Marybeth G. Nored; Ryan S. Gernentz; Shane P. Siebenaler

    2005-12-01

    The U.S. natural gas pipeline industry is facing the twin challenges of increased flexibility and capacity expansion. To meet these challenges, the industry requires improved choices in gas compression to address new construction and enhancement of the currently installed infrastructure. The current fleet of installed reciprocating compression is primarily slow-speed integral machines. Most new reciprocating compression is and will be large, high-speed separable units. The major challenges with the fleet of slow-speed integral machines are: limited flexibility and a large range in performance. In an attempt to increase flexibility, many operators are choosing to single-act cylinders, which are causing reduced reliability and integrity. While the best performing units in the fleet exhibit thermal efficiencies between 90% and 92%, the low performers are running down to 50% with the mean at about 80%. The major cause for this large disparity is due to installation losses in the pulsation control system. In the better performers, the losses are about evenly split between installation losses and valve losses. The major challenges for high-speed machines are: cylinder nozzle pulsations, mechanical vibrations due to cylinder stretch, short valve life, and low thermal performance. To shift nozzle pulsation to higher orders, nozzles are shortened, and to dampen the amplitudes, orifices are added. The shortened nozzles result in mechanical coupling with the cylinder, thereby, causing increased vibration due to the cylinder stretch mode. Valve life is even shorter than for slow speeds and can be on the order of a few months. The thermal efficiency is 10% to 15% lower than slow-speed equipment with the best performance in the 75% to 80% range. The goal of this advanced reciprocating compression program is to develop the technology for both high speed and low speed compression that will expand unit flexibility, increase thermal efficiency, and increase reliability and integrity

  12. Advanced Training Technologies and Learning Environments

    Science.gov (United States)

    Noor, Ahmed K. (Compiler); Malone, John B. (Compiler)

    1999-01-01

    This document contains the proceedings of the Workshop on Advanced Training Technologies and Learning Environments held at NASA Langley Research Center, Hampton, Virginia, March 9-10, 1999. The workshop was jointly sponsored by the University of Virginia's Center for Advanced Computational Technology and NASA. Workshop attendees were from NASA, other government agencies, industry, and universities. The objective of the workshop was to assess the status and effectiveness of different advanced training technologies and learning environments.

  13. Development of Fischer-Tropsch catalysis for gasified biomass

    OpenAIRE

    Lögdberg, Sara

    2007-01-01

    In order to secure the energy supply to an increasing population and at the same time limit the damage to Earth, i.e. avoiding a fatal climate change as a result of anthropogenic emissions of greenhouse gases (primarily CO2), immediate action is necessary. This includes reducing the energy consumption, increasing the energy conversion efficiency, and using renewable energies. The transport sector is the one most dependent on fossil energy and it stands for a significant part of the energy con...

  14. Evaluation of the Advanced Manufacturing Technology Programme

    OpenAIRE

    1995-01-01

    This report provides an evaluation of AMT Ireland - one of the oldest of the Programmes in Advanced Technology. AMT Ireland was established in 1988 as a programme intended to promote industrial development by transferring Advanced Manufacturing Technology (AMT) capabilities from university-based centres into Irish-based industry. The evaluation concludes that AMT Ireland performs an important role in national industrial development by providing technology transfer and consultancy services in ...

  15. JPL Advanced Thermal Control Technology Roadmap - 2012

    Science.gov (United States)

    Birur, Gaj; Rodriguez, Jose I.

    2012-01-01

    NASA's new emphasis on human exploration program for missions beyond LEO requires development of innovative and revolutionary technologies. Thermal control requirements of future NASA science instruments and missions are very challenging and require advanced thermal control technologies. Limited resources requires organizations to cooperate and collaborate; government, industry, universities all need to work together for the successful development of these technologies.

  16. Advanced laptop and small personal computer technology

    Science.gov (United States)

    Johnson, Roger L.

    1991-01-01

    Advanced laptop and small personal computer technology is presented in the form of the viewgraphs. The following areas of hand carried computers and mobile workstation technology are covered: background, applications, high end products, technology trends, requirements for the Control Center application, and recommendations for the future.

  17. Advanced Manufacturing Technologies (AMT): Advanced Near Net Shape Technology Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Develop and mature manufacturing technology to enable fabrication of single-piece integrally-stiffened launch vehicle structures to replace expensive, heavy, and...

  18. Low speed propellers: Impact of advanced technologies

    Science.gov (United States)

    Keiter, I. D.

    1980-01-01

    Sensitivity studies performed to evaluate the potential of several advanced technological elements on propeller performance, noise, weight, and cost for general aviation aircraft are discussed. Studies indicate that the application of advanced technologies to general aviation propellers can reduce fuel consumption in future aircraft an average of ten percent, meeting current regulatory noise limits. Through the use of composite blade construction, up to 25 percent propeller weight reduction can be achieved. This weight reduction in addition to seven percent propeller efficiency improvements through application of advanced technologies result in four percent reduction in direct operating costs, ten percent reduction in aircraft acquisition cost, and seven percent lower gross weight for general aviation aircraft.

  19. Isotope separation and advanced manufacturing technology

    Science.gov (United States)

    Carpenter, J.; Kan, T.

    This is the fourth issue of a semiannual report for the Isotope Separation and Advanced Materials Manufacturing (ISAM) Technology Program at Lawrence Livermore National Laboratory. Primary objectives include: (1) the Uranium Atomic Vapor Laser Isotope Separation (UAVLIS) process, which is being developed and prepared for deployment as an advanced uranium enrichment capability; (2) Advanced manufacturing technologies, which include industrial laser and E-beam material processing and new manufacturing technologies for uranium, plutonium, and other strategically important materials in support of DOE and other national applications. This report features progress in the ISAM Program from October 1993 through March 1994.

  20. Advanced technology for future regional transport aircraft

    Science.gov (United States)

    Williams, L. J.

    1982-01-01

    In connection with a request for a report coming from a U.S. Senate committee, NASA formed a Small Transport Aircraft Technology (STAT) team in 1978. STAT was to obtain information concerning the technical improvements in commuter aircraft that would likely increase their public acceptance. Another area of study was related to questions regarding the help which could be provided by NASA's aeronautical research and development program to commuter aircraft manufacturers with respect to the solution of technical problems. Attention is given to commuter airline growth, current commuter/region aircraft and new aircraft in development, prospects for advanced technology commuter/regional transports, and potential benefits of advanced technology. A list is provided of a number of particular advances appropriate to small transport aircraft, taking into account small gas turbine engine component technology, propeller technology, three-dimensional wing-design technology, airframe aerodynamics/propulsion integration, and composite structure materials.

  1. 75 FR 106 - Visiting Committee on Advanced Technology

    Science.gov (United States)

    2010-01-04

    ... National Institute of Standards and Technology Visiting Committee on Advanced Technology AGENCY: National Institute of Standards and Technology, Department of Commerce. ACTION: Notice of public meeting. SUMMARY... Committee on Advanced Technology (VCAT), National Institute of Standards and Technology (NIST), will...

  2. Advanced location-based technologies and services

    CERN Document Server

    Karimi, Hassan A

    2013-01-01

    Due to the rapid increase in the number of mobile device users worldwide, location-based services (LBSs) have become pervasive, and the demand for them will continue to grow. Exploring recent changes in the technology and its uses, Advanced Location-Based Technologies and Services takes an in-depth look at new and existing technologies, techniques, applications, and opportunities. Under the editorial guidance of Hassan Karimi, with contributions from experts in the field, the book examines the breadth and depth of advanced LBS technologies and techniques. The book provides up-to-date informati

  3. Costs and Benefits of Advanced Aeronautical Technology

    Science.gov (United States)

    Bobick, J. C.; Denny, R. E.

    1983-01-01

    Programs available from COSMIC used to evaluate economic feasibility of applying advanced aeronautical technology to civil aircraft of future. Programs are composed of three major models: Fleet Accounting Module, Airframe manufacturer Module, and Air Carrier Module.

  4. Advanced Manufacturing Technologies (AMT): Manufacturing Initiative Project

    Data.gov (United States)

    National Aeronautics and Space Administration — NASA supports the Advanced Manufacturing National Program Office (AMNPO). Hosted by the National Institute of Standards and Technology (NIST) the AMNPO is...

  5. Advanced technologies for remote handling

    International Nuclear Information System (INIS)

    Master slave manipulators (MSMs), in-cell cranes and power manipulators are the general-purpose remote handling tools used in nuclear industry. In-cell cranes and power manipulators can handle heavy objects; whereas MSMs can handle objects with precision and dexterity. The department had identified the importance of indigenising these technologies and developed a variety of mechanical MSMs and Servo Manipulators. This paper traces the history and evolution of these technologies. It also mentions about the telepresence technologies that are set to transform the operator's experience of manipulation by bringing in visual, haptic and aural immersion in the slave environment. (author)

  6. Innovative Experimental Particle Physics through Technological Advances

    OpenAIRE

    Cheung, Harry W. K.

    2005-01-01

    This mini-course gives an introduction to the techniques used in experimental particle physics with an emphasis on the impact of technological advances. The basic detector types and particle accelerator facilities will be briefly covered with examples of their use and with comparisons. The mini-course ends with what can be expected in the near future from current technology advances. The mini-course is intended for graduate students and post-docs and as an introduction to experimental techniq...

  7. ADVANCED TECHNOLOGY AND KNOWLEDGE TRANSFER

    OpenAIRE

    Tandon, Geetanjali; Sonka, Steven T.

    2002-01-01

    This paper reports on a specific project, employing new technological capabilities to better transfer expert knowledge. The specific project considered for the paper is the World Initiative for Soy in Human Health (WISHH), a Multi Organization Enterprise promoting the use of soy and soy products in humanitarian and development aid around the world. VisIT, which stands for Visualization of Information Technology, is a potentially powerful organizational tool. It is compared against the traditi...

  8. [Advances in genetic modification technologies].

    Science.gov (United States)

    Zhang, Baixue; Sun, Qixin; Li, Haifeng

    2015-08-01

    Genetic modification technology is a new molecular tool for targeted genome modification. It includes zinc finger nucleases (ZFN) technology, transcription activator-like effector nucleases (TALEN) technology and clustered regularly interspaced short palindromic repeat (CRISPR)-associated (Cas) (CRISPR-Cas) nucleases technology. All of these nucleases create DNA double-strand breaks (DSB) at chromosomal targeted sites and induce cell endogenous mechanisms that are primarily repaired by the non-homologous end joining (NHEJ) or homologous recombination (HR) pathway, resulting in targeted endogenous gene knock-out or exogenous gene insertion. In recent years, genetic modification technologies have been successfully applied to bacteria, yeast, human cells, fruit fly, zebra fish, mouse, rat, livestock, cynomolgus monkey, Arabidopsis, rice, tobacco, maize, sorghum, wheat, barley and other organisms, showing its enormous advantage in gene editing field. Especially, the newly developed CRISPR-Cas9 system arose more attention because of its low cost, high effectiveness, simplicity and easiness. We reviewed the principles and the latest research progress of these three technologies, as well as prospect of future research and applications. PMID:26762038

  9. Advanced Technology Lifecycle Analysis System (ATLAS) Technology Tool Box (TTB)

    Science.gov (United States)

    Doyle, Monica; ONeil, Daniel A.; Christensen, Carissa B.

    2005-01-01

    The Advanced Technology Lifecycle Analysis System (ATLAS) is a decision support tool designed to aid program managers and strategic planners in determining how to invest technology research and development dollars. It is an Excel-based modeling package that allows a user to build complex space architectures and evaluate the impact of various technology choices. ATLAS contains system models, cost and operations models, a campaign timeline and a centralized technology database. Technology data for all system models is drawn from a common database, the ATLAS Technology Tool Box (TTB). The TTB provides a comprehensive, architecture-independent technology database that is keyed to current and future timeframes.

  10. Policy issues inherent in advanced technology development

    Energy Technology Data Exchange (ETDEWEB)

    Baumann, P.D.

    1994-12-31

    In the development of advanced technologies, there are several forces which are involved in the success of the development of those technologies. In the overall development of new technologies, a sufficient number of these forces must be present and working in order to have a successful opportunity at developing, introducing and integrating into the marketplace a new technology. This paper discusses some of these forces and how they enter into the equation for success in advanced technology research, development, demonstration, commercialization and deployment. This paper limits itself to programs which are generally governmental funded, which in essence represent most of the technology development efforts that provide defense, energy and environmental technological products. Along with the identification of these forces are some suggestions as to how changes may be brought about to better ensure success in a long term to attempt to minimize time and financial losses.

  11. Advances in Nuclear Monitoring Technologies

    Science.gov (United States)

    Park, Brent

    2006-03-01

    Homeland security requires low-cost, large-area detectors for locating and identifying weapons-usable nuclear materials and monitors for radiological isotopes that are more robust than current systems. Recent advances in electronics materials and nanotechnology, specifically organic semiconductors and inorganic quantum dots, offer potential improvements. We provide an overview of the physical processes involved in radiation detection using these new materials in the design of new device structures. Examples include recent efforts on quantum dots, as well as more traditional radiation-detecting materials such as CdZnTe and high-pressure xenon. Detector improvements demand not only new materials but also enhanced data-analysis tools that reduce false alarms and thus increase the quality of decisions. Additional computing power on hand-held platforms should enable the application of advanced algorithms to radiation-detection problems in the field, reducing the need to transmit data and thus delay analysis.

  12. Advances in gas utilization technologies

    International Nuclear Information System (INIS)

    A review of industrial technologies and their impact on gas consumption was presented. The issue of whether the increased use of these technologies will have a positive impact on emissions was also discussed. Natural gas is regarded as the preferred fuel with regards to the reduction of greenhouse gases because of lower carbon dioxide (CO2) emissions per unit of energy compared to oil, coal or wood fuels. The other way to improve efficiency and to reduce CO2 emissions is to optimize combustion system technologies and to improve heat transfer mechanisms. Some examples of alternative industrial burner technologies which allow a reduction in pollutant emissions were listed and described. These included infrared burners, preheating combustion air, and oxy-fuel combustion. Some of the technologies that increase the useful heat output from hot combustion products are infra-red heat transfer, direct contact water heating and condensing boilers. The substitution of gas for electricity in the use of gas fired scrap metal preheaters was demonstrated. Co-generation systems are also potential contributors to efficiency improvements and CO2 reduction. 1 tab., 8 figs

  13. Advanced clean coal utilization technologies

    Energy Technology Data Exchange (ETDEWEB)

    Moritomi, Hiroshi [National Inst. for Resources and Environment, Tsukuba, Ibaraki (Japan)

    1993-12-31

    The most important greenhouse gas is CO{sub 2} from coal utilization. Ways of mitigating CO{sub 2} emissions include the use of alternative fuels, using renewable resources and increasing the efficiency of power generation and end use. Adding to such greenhouse gas mitigation technologies, post combustion control by removing CO{sub 2} from power station flue gases and then storing or disposing it will be available. Although the post combustion control have to be evaluated in a systematic manner relating them to whether they are presently available technology, to be available in the near future or long term prospects requiring considerable development, it is considered to be a less promising option owing to the high cost and energy penalty. By contrast, abatement technologies aimed at improving conversion efficiency or reducing energy consumption will reduce emissions while having their own commercial justification.

  14. Advances in light water reactor technologies

    CERN Document Server

    Saito, Takehiko; Ishiwatari, Yuki; Oka, Yoshiaki

    2010-01-01

    ""Advances in Light Water Reactor Technologies"" focuses on the design and analysis of advanced nuclear power reactors. This volume provides readers with thorough descriptions of the general characteristics of various advanced light water reactors currently being developed worldwide. Safety, design, development and maintenance of these reactors is the main focus, with key technologies like full MOX core design, next-generation digital I&C systems and seismic design and evaluation described at length. This book is ideal for researchers and engineers working in nuclear power that are interested

  15. Advances in nuclear science and technology

    CERN Document Server

    Greebler, Paul

    1968-01-01

    Advances in Nuclear Science and Technology Volume 4 provides information pertinent to the fundamental aspects of advanced reactor concepts. This book discusses the advances in various areas of general applicability, including modern perturbation theory, optimal control theory, and industrial application of ionizing radiations.Organized into seven chapters, this volume begins with an overview of the technology of sodium-cooled fast breeder power reactors and gas-cooled power reactors. This text then examines the key role of reactor safety in the development of fast breeder reactors. Other chapt

  16. Assurance Technology Challenges of Advanced Space Systems

    Science.gov (United States)

    Chern, E. James

    2004-01-01

    The initiative to explore space and extend a human presence across our solar system to revisit the moon and Mars post enormous technological challenges to the nation's space agency and aerospace industry. Key areas of technology development needs to enable the endeavor include advanced materials, structures and mechanisms; micro/nano sensors and detectors; power generation, storage and management; advanced thermal and cryogenic control; guidance, navigation and control; command and data handling; advanced propulsion; advanced communication; on-board processing; advanced information technology systems; modular and reconfigurable systems; precision formation flying; solar sails; distributed observing systems; space robotics; and etc. Quality assurance concerns such as functional performance, structural integrity, radiation tolerance, health monitoring, diagnosis, maintenance, calibration, and initialization can affect the performance of systems and subsystems. It is thus imperative to employ innovative nondestructive evaluation methodologies to ensure quality and integrity of advanced space systems. Advancements in integrated multi-functional sensor systems, autonomous inspection approaches, distributed embedded sensors, roaming inspectors, and shape adaptive sensors are sought. Concepts in computational models for signal processing and data interpretation to establish quantitative characterization and event determination are also of interest. Prospective evaluation technologies include ultrasonics, laser ultrasonics, optics and fiber optics, shearography, video optics and metrology, thermography, electromagnetics, acoustic emission, x-ray, data management, biomimetics, and nano-scale sensing approaches for structural health monitoring.

  17. TASTEX: Tokai Advanced Safeguards Technology Exercise

    International Nuclear Information System (INIS)

    During the years 1978 to 1981 the Governments of France, Japan and the United States of America cooperated with the International Atomic Energy Agency in the TASTEX (Tokai Advanced Safeguards Technology Exercise) programme. The aim of this programme was to improve the technology for the application of international safeguards at reprocessing facilities, and the results are presented in the present report

  18. Advances in femtosecond laser technology

    Science.gov (United States)

    Callou, Thais Pinheiro; Garcia, Renato; Mukai, Adriana; Giacomin, Natalia T; de Souza, Rodrigo Guimarães; Bechara, Samir J

    2016-01-01

    Femtosecond laser technology has become widely adopted by ophthalmic surgeons. The purpose of this study is to discuss applications and advantages of femtosecond lasers over traditional manual techniques, and related unique complications in cataract surgery and corneal refractive surgical procedures, including: LASIK flap creation, intracorneal ring segment implantation, presbyopic treatments, keratoplasty, astigmatic keratotomy, and intrastromal lenticule procedures. PMID:27143847

  19. Advanced materials and technologies. Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Lindroos, V.K.; Alander, T.K.R. [eds.] [Helsinki Univ. of Technology, Otaniemi (Finland). Lab. of Physical Metallurgy and Materials Science

    1995-12-31

    The contents of the proceedings consist of three chapters, of which, the first discusses common megatrends, both nationally and globally, in different fields of materials technology. The second chapter is dealing with novel production and processing of base metals and, finally, the third chapter is related with current achievements and future goals of electronic, magnetic, optical and coating materials and their processing

  20. Advanced Lost Foam Casting Technology

    Energy Technology Data Exchange (ETDEWEB)

    Charles E. Bates; Harry E. Littleton; Don Askeland; Taras Molibog; Jason Hopper; Ben Vatankhah

    2000-11-30

    This report describes the research done under the six tasks to improve the process and make it more functional in an industrial environment. Task 1: Pattern Pyrolysis Products and Pattern Properties Task 2: Coating Quality Control Task 3: Fill and Solidification Code Task 4: Alternate Pattern Materials Task 5: Casting Distortion Task 6: Technology Transfer

  1. Advances in cold plasma technology

    Science.gov (United States)

    Foodborne pathogens continue to be an issue on a variety of commodities, prompting research into novel interventions. Cold plasma is a nonthermal food processing technology which uses energetic, reactive gases to inactivate contaminating microbes on meats, poultry and fruits and vegetables. The prim...

  2. Advances in spot curing technology

    International Nuclear Information System (INIS)

    A brief review of spot curing technology was presented. The process which a spot of energy of a specific wavelength bandwidth and irradiance is used to cause a coating, encapsulant or adhesive to change from a liquid to a solid state

  3. Advanced Cogeneration Technology Economic Optimization Study (ACTEOS)

    Science.gov (United States)

    Nanda, P.; Ansu, Y.; Manuel, E. H., Jr.; Price, W. G., Jr.

    1980-01-01

    The advanced cogeneration technology economic optimization study (ACTEOS) was undertaken to extend the results of the cogeneration technology alternatives study (CTAS). Cost comparisons were made between designs involving advanced cogeneration technologies and designs involving either conventional cogeneration technologies or not involving cogeneration. For the specific equipment cost and fuel price assumptions made, it was found that: (1) coal based cogeneration systems offered appreciable cost savings over the no cogeneration case, while systems using coal derived liquids offered no costs savings; and (2) the advanced cogeneration systems provided somewhat larger cost savings than the conventional systems. Among the issues considered in the study included: (1) temporal variations in steam and electric demands; (2) requirements for reliability/standby capacity; (3) availability of discrete equipment sizes; (4) regional variations in fuel and electricity prices; (5) off design system performance; and (6) separate demand and energy charges for purchased electricity.

  4. ADVANCED MANUFACTURING TECHNOLOGIES: RUSSIA’S PLACE

    OpenAIRE

    Irina Dezhina

    2014-01-01

    The development of advanced manufacturing technologies is to become a new trend at the intersection of research, technological and industrial policy. The United States, a few EU countries, and China are leading on the development of new measures and approaches in this field. It was not until recently that the issues of “new industrialization” have been extensively discussed in Russia. All related areas such as science, technological development, and public administration are facing problems. ...

  5. Important Advances In Technology: Echocardiography

    OpenAIRE

    Nagueh, Sherif F; Quiñones, Miguel A.

    2014-01-01

    Echocardiography has evolved over the past 45 years from a simple M-mode tracing to an array of technologies that include two-dimensional imaging, pulsed and continuous wave spectral Doppler, color flow and tissue Doppler, and transesophageal echocardiography. Together, these modalities provide a comprehensive anatomic and functional evaluation of cardiac chambers and valves, pericardium, and ascending and descending aorta. The switch from analog to digital signal processing revolutionized th...

  6. Advances in lens implant technology

    OpenAIRE

    Kook, Daniel; Kampik, Anselm; Dexl, Alois K.; Zimmermann, Nicole; Glasser, Adrian; Baumeister, Martin; Kohnen, Thomas

    2013-01-01

    Cataract surgery is one of the oldest and the most frequent outpatient clinic operations in medicine performed worldwide. The clouded human crystalline lens is replaced by an artificial intraocular lens implanted into the capsular bag. During the last six decades, cataract surgery has undergone rapid development from a traumatic, manual surgical procedure with implantation of a simple lens to a minimally invasive intervention increasingly assisted by high technology and a broad variety of imp...

  7. Advances in liquid phase technology

    Energy Technology Data Exchange (ETDEWEB)

    Jijin, P.J.A. [Air Products and Chemicals, Inc., Allentown, PA (United States)

    1997-12-31

    The liquid phase methanol (LPMEOH) process uses a slurry reactor to convert synthesis gas (primarily a mixture of hydrogen and carbon monoxide) to methanol. Through its superior heat management, the process is ultimately suitable to handle synthesis gas generated through gasification of natural gas and other materials, such as coal, petroleum coke, residual oil, wastes and other environmentally disadvantaged hydrocarbon feedstocks. Apart from production of chemical grade methanol, the process provides economic advantages in the Integrated Gasification Combined Cycle (IGCC) power generation application. Coproduction of power and methanol via the IGCC and the LPMEOH process provides opportunities for energy storage for peak-shaving of electrical demand and/or clean fuel for export. The LPMEOH technology has been developed since the 1980`s, extensively proven in a process development unit in LaPorte, Texas and elected for demonstration under The Clean Coal Technology Program. The slurry reactor being demonstrated is also suitable for other exothermic synthesis gas conversion reactions, like synthesis of Dimethyl Ether and other alcohols/oxygenates. This paper presents an overview of LPMEOH and other liquid phase technology aspects and highlights the demonstration project at Eastman Chemical Company`s coal gasification facility in Kingsport, Tennessee. Commercial aspects of the LPMEOH process are also discussed.

  8. Advancement of light water reactor technology

    International Nuclear Information System (INIS)

    The Japanese technology of light water reactors is based on the technology imported from abroad around 1970, and the experience has been accumulated by the construction, operation and repair of light water reactors as well as the countermeasures to various troubles, moreover, the improvement and standardization of light water reactors have been promoted. As the result, recently the high capacity ratio has been attained, and the LWR technology has firmly taken root in Japan. The Subcommittee for the Advancement of Light Water Reactor Technology of the Advisory Committee for Energy has examined the subjects of technical development and the way the development should be in order to decide the strategy to advance LWR technology, and drawn up the interim report. The change of situation around the LWRs in Japan and the necessity to advance the technology, the target of advancing LWR technology and the subjects of the technical development, the system for the technical development and the securement of fund, and international cooperation are reported. The subjects of development are the pursuit of higher reliability and economic efficiency, the extension of plant life, the improvement of repairability and the reduction of radiation exposure, the improvement of operational capability, the reduction of wastes, the techniques for reactor decommissioning and the diversified location. (Kako, I.)

  9. Modern Imaging Technology: Recent Advances

    International Nuclear Information System (INIS)

    This 2-day conference is designed to bring scientist working in nuclear medicine, as well as nuclear medicine practitioners together to discuss the advances in four selected areas of imaging: Biochemical Parameters using Small Animal Imaging, Developments in Small Animal PET Imaging, Cell Labeling, and Imaging Angiogenesis Using Multiple Modality. The presentations will be on molecular imaging applications at the forefront of research, up to date on the status of molecular imaging in nuclear medicine as well as in related imaging areas. Experts will discuss the basic science of imaging techniques, and scheduled participants will engage in an exciting program that emphasizes the current status of molecular imaging as well as the role of DOE funded research in this area

  10. Directions in advanced reactor technology

    International Nuclear Information System (INIS)

    Successful nuclear power plant concepts must simultaneously performance in terms of both safety and economics. To be attractive to both electric utility companies and the public, such plants must produce economical electric energy consistent with a level of safety which is acceptable to both the public and the plant owner. Programs for reactor development worldwide can be classified according to whether the reactor concept pursues improved safety or improved economic performance as the primary objective. When improved safety is the primary goal, safety enters the solution of the design problem as a constraint which restricts the set of allowed solutions. Conversely, when improved economic performance is the primary goal, it is allowed to be pursued only to an extent which is compatible with stringent safety requirements. The three major reactor coolants under consideration for future advanced reactor use are water, helium and sodium. Reactor development programs focuses upon safety and upon economics using each coolant are being pursued worldwide. These programs are discussed

  11. Modern Imaging Technology: Recent Advances

    Energy Technology Data Exchange (ETDEWEB)

    Welch, Michael J.; Eckelman, William C.

    2004-06-18

    This 2-day conference is designed to bring scientist working in nuclear medicine, as well as nuclear medicine practitioners together to discuss the advances in four selected areas of imaging: Biochemical Parameters using Small Animal Imaging, Developments in Small Animal PET Imaging, Cell Labeling, and Imaging Angiogenesis Using Multiple Modality. The presentations will be on molecular imaging applications at the forefront of research, up to date on the status of molecular imaging in nuclear medicine as well as in related imaging areas. Experts will discuss the basic science of imaging techniques, and scheduled participants will engage in an exciting program that emphasizes the current status of molecular imaging as well as the role of DOE funded research in this area.

  12. 75 FR 60082 - Visiting Committee on Advanced Technology

    Science.gov (United States)

    2010-09-29

    ... National Institute of Standards and Technology Visiting Committee on Advanced Technology AGENCY: National Institute of Standards and Technology, Department of Commerce. ACTION: Notice of Public Meeting. SUMMARY: The Visiting Committee on Advanced Technology (VCAT), National Institute of Standards and...

  13. 77 FR 32570 - Visiting Committee on Advanced Technology

    Science.gov (United States)

    2012-06-01

    ... National Institute of Standards and Technology Visiting Committee on Advanced Technology AGENCY: National Institute of Standards and Technology, Department of Commerce. ACTION: Notice of public meeting. SUMMARY: The Visiting Committee on Advanced Technology (VCAT or Committee), National Institute of Standards...

  14. 78 FR 292 - Visiting Committee on Advanced Technology

    Science.gov (United States)

    2013-01-03

    ... National Institute of Standards and Technology Visiting Committee on Advanced Technology AGENCY: National Institute of Standards and Technology, Department of Commerce. ACTION: Notice of Public Meeting. SUMMARY: The Visiting Committee on Advanced Technology (VCAT or Committee), National Institute of Standards...

  15. 78 FR 29704 - Visiting Committee on Advanced Technology

    Science.gov (United States)

    2013-05-21

    ... National Institute of Standards and Technology Visiting Committee on Advanced Technology AGENCY: National Institute of Standards and Technology, Department of Commerce. ACTION: Notice of Public Meeting. SUMMARY: The Visiting Committee on Advanced Technology (VCAT or Committee), National Institute of Standards...

  16. 76 FR 29195 - Visiting Committee on Advanced Technology

    Science.gov (United States)

    2011-05-20

    ... National Institute of Standards and Technology Visiting Committee on Advanced Technology AGENCY: National Institute of Standards and Technology, Department of Commerce. ACTION: Notice of Public Meeting. SUMMARY: The Visiting Committee on Advanced Technology (VCAT or Committee), National Institute of Standards...

  17. 78 FR 57839 - Visiting Committee on Advanced Technology

    Science.gov (United States)

    2013-09-20

    ... National Institute of Standards and Technology Visiting Committee on Advanced Technology AGENCY: National Institute of Standards and Technology, Department of Commerce. ACTION: Notice of public meeting. SUMMARY: The Visiting Committee on Advanced Technology (VCAT or Committee), National Institute of Standards...

  18. 76 FR 59659 - Visiting Committee on Advanced Technology

    Science.gov (United States)

    2011-09-27

    ... National Institute of Standards and Technology Visiting Committee on Advanced Technology AGENCY: National Institute of Standards and Technology, Department of Commerce. ACTION: Notice of public meeting. SUMMARY: The Visiting Committee on Advanced Technology (VCAT or Committee), National Institute of Standards...

  19. 76 FR 2662 - Visiting Committee on Advanced Technology

    Science.gov (United States)

    2011-01-14

    ... National Institute of Standards and Technology Visiting Committee on Advanced Technology AGENCY: National Institute of Standards and Technology, Department of Commerce. ACTION: Notice of partially closed meeting. SUMMARY: The Visiting Committee on Advanced Technology (VCAT), National Institute of Standards...

  20. 77 FR 59592 - Visiting Committee on Advanced Technology

    Science.gov (United States)

    2012-09-28

    ... National Institute of Standards and Technology Visiting Committee on Advanced Technology AGENCY: National Institute of Standards and Technology, Department of Commerce. ACTION: Notice of public meeting. ] SUMMARY: The Visiting Committee on Advanced Technology (VCAT or Committee), National Institute of Standards...

  1. Advances in femtosecond laser technology

    Directory of Open Access Journals (Sweden)

    Callou TP

    2016-04-01

    Full Text Available Thais Pinheiro Callou, Renato Garcia, Adriana Mukai, Natalia T Giacomin, Rodrigo Guimarães de Souza, Samir J Bechara Department of Ophthalmology, University of Sao Paulo, Sao Paulo, Brazil Abstract: Femtosecond laser technology has become widely adopted by ophthalmic surgeons. The purpose of this study is to discuss applications and advantages of femtosecond lasers over traditional manual techniques, and related unique complications in cataract surgery and corneal refractive surgical procedures, including: LASIK flap creation, intracorneal ring segment implantation, presbyopic treatments, keratoplasty, astigmatic keratotomy, and intrastromal lenticule procedures. Keywords: laser therapy, refractive surgical procedures, intracorneal ring, laser in situ keratomileusis, keratoplasty, presbyopia, cataract extraction, astigmatism surgery

  2. Advanced neutral-beam technology

    International Nuclear Information System (INIS)

    Extensive development will be required to achieve the 50- to 75-MW, 175- to 200-keV, 5- to 10-sec pulses of deuterium atoms envisioned for ETF and INTOR. Multi-megawatt injector systems are large (and expansive); they consist of large vacuum tanks with many square meters of cryogenic pumping panels, beam dumps capable of dissipating several megawatts of un-neutralized beam, bending magnets, electrical power systems capable of fast turnoff with low (capacity) stored energy, and, of course, the injector modules (ion sources and accelerators). The technology requirements associated with these components are described

  3. Crosscutting Technology Development at the Center for Advanced Separation Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Christopher E. Hull

    2006-09-30

    This Technical Progress Report describes progress made on the twenty nine subprojects awarded in the second year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

  4. CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Christopher E. Hull

    2005-11-04

    This Technical Progress Report describes progress made on the twenty nine subprojects awarded in the second year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

  5. CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Christopher E. Hull

    2006-05-15

    This Technical Progress Report describes progress made on the twenty nine subprojects awarded in the second year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

  6. Advanced microwave/millimeter-wave imaging technology

    International Nuclear Information System (INIS)

    Millimeter wave technology advances have made possible active and passive millimeter wave imaging for a variety of applications including advanced plasma diagnostics, radio astronomy, atmospheric radiometry, concealed weapon detection, all-weather aircraft landing, contraband goods detection, harbor navigation/surveillance in fog, highway traffic monitoring in fog, helicopter and automotive collision avoidance in fog, and environmental remote sensing data associated with weather, pollution, soil moisture, oil spill detection, and monitoring of forest fires, to name but a few. The primary focus of this paper is on technology advances which have made possible advanced imaging and visualization of magnetohydrodynamic (MHD) fluctuations and microturbulence in fusion plasmas. Topics of particular emphasis include frequency selective surfaces, planar Schottky diode mixer arrays, electronically controlled beam shaping/steering arrays, and high power millimeter wave local oscillator and probe sources. (author)

  7. Robotics Technology Development Program Cross Cutting and Advanced Technology

    International Nuclear Information System (INIS)

    Need-based cross cutting technology is being developed which is broadly applicable to the clean up of hazardous and radioactive waste within the US Department of Energy's complex. Highly modular, reusable technologies which plug into integrated system architectures to meet specific robotic needs result from this research. In addition, advanced technologies which significantly extend current capabilities such as automated planning and sensor-based control in unstructured environments for remote system operation are also being developed and rapidly integrated into operating systems

  8. Electrochromic Windows: Advanced Processing Technology

    Energy Technology Data Exchange (ETDEWEB)

    SAGE Electrochromics, Inc

    2006-12-13

    This project addresses the development of advanced fabrication capabilities for energy saving electrochromic (EC) windows. SAGE EC windows consist of an inorganic stack of thin films deposited onto a glass substrate. The window tint can be reversibly changed by the application of a low power dc voltage. This property can be used to modulate the amount of light and heat entering buildings (or vehicles) through the glazings. By judicious management of this so-called solar heat gain, it is possible to derive significant energy savings due to reductions in heating lighting, and air conditioning (HVAC). Several areas of SAGE’s production were targeted during this project to allow significant improvements to processing throughput, yield and overall quality of the processing, in an effort to reduce the cost and thereby improve the market penetration. First, the overall thin film process was optimized to allow a more robust set of operating points to be used, thereby maximizing the yield due to the thin film deposition themselves. Other significant efforts aimed at improving yield were relating to implementing new procedures and processes for the manufacturing process, to improve the quality of the substrate preparation, and the quality of the IGU fabrication. Furthermore, methods for reworking defective devices were developed, to enable devices which would otherwise be scrapped to be made into useful product. This involved the in-house development of some customized equipment. Finally, the improvements made during this project were validated to ensure that they did not impact the exceptional durability of the SageGlass® products. Given conservative estimates for cost and market penetration, energy savings due to EC windows in residences in the US are calculated to be of the order 0.026 quad (0.026×1015BTU/yr) by the year 2017.

  9. Development of advanced PWR system analysis technology

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, Y. D.; Kim, S. O.; Jung, B. D.; Kim, Y. I.; Chang, M. H.; Lee, Y. J.; Yun, J. H.

    1997-12-31

    The scope of this project is to establish the basic analysis technologies for the advanced designed with the passive and inherent safety concepts. The scope is extended to the application of these technologies to the performance and safety analysis of the passive reactor. Since the different design concepts are applied depending on the reactor power, the study is conducted for the small and medium sized integral reactor as well as the large scale passive reactors by focusing on the analysis technology development for the passive components. The design concepts which can be applied for the safety enhancement of the domestic advanced reactor are developed through evaluating the technical information of the overseas advanced reactor concepts.

  10. Technological Advances in Psychiatric Nursing: An update.

    Science.gov (United States)

    Bostrom, Andrea C

    2016-06-01

    Understanding and treating mental illness has improved in many ways as a result of the fast pace of technological advances. The technologies that have the greatest potential impact are those that (1) increase the knowledge of how the brain functions and changes based on interventions, (2) have the potential to personalize interventions based on understanding genetic factors of drug metabolism and pharmacodynamics, and (3) use information technology to provide treatment in the absence of an adequate mental health workforce. Technologies are explored for psychiatric nurses to consider. Psychiatric nurses are encouraged to consider the experiences of psychiatric patients, including poor health, stigmatization, and suffering. PMID:27229272

  11. Technological advances for studying human behavior

    Science.gov (United States)

    Roske-Hofstrand, Renate J.

    1990-01-01

    Technological advances for studying human behavior are noted in viewgraph form. It is asserted that performance-aiding systems are proliferating without a fundamental understanding of how they would interact with the humans who must control them. Two views of automation research, the hardware view and the human-centered view, are listed. Other viewgraphs give information on vital elements for human-centered research, a continuum of the research process, available technologies, new technologies for persistent problems, a sample research infrastructure, the need for metrics, and examples of data-link technology.

  12. Technologies for Advanced Induction Accelerators

    CERN Document Server

    Hernández, M A; Autrey, D; Duncan, G; Friedman, A; Grote, D P; Halaxa, E; Hanks, R; Kamin, G; Sangster, C; Sharp, W; Williams, C

    2000-01-01

    To harness fusion energy is one of today's greatest technological challenges, and one well worth pursuing. Success in the development of fusion power would result in a virtually inexhaustible source of energy. The fusion reaction, the process that powers the sun and the stars, can be duplicated on Earth. However, to date these fusion processes have been the products of large-scale experimental efforts. They have yet to achieve fusion in a manner that is cost effective and efficient enough to be applied in a commercial reactor. Lawrence Livermore National Laboratory (LLNL) has been centrally involved in the Nation's inertial confinement fusion (ICF) program for over 25 years. Much of the focus of the LLNL ICF Program has been the well-known effort to develop high power, short wavelength laser drivers to create the conditions necessary for the fusion process. But the ICF Program has also been investigating, in collaboration with Lawrence Berkeley National Laboratory (LBNL), the potential of heavy-ion accelerato...

  13. Advances in software science and technology

    CERN Document Server

    Hikita, Teruo; Kakuda, Hiroyasu

    1993-01-01

    Advances in Software Science and Technology, Volume 4 provides information pertinent to the advancement of the science and technology of computer software. This book discusses the various applications for computer systems.Organized into two parts encompassing 10 chapters, this volume begins with an overview of the historical survey of programming languages for vector/parallel computers in Japan and describes compiling methods for supercomputers in Japan. This text then explains the model of a Japanese software factory, which is presented by the logical configuration that has been satisfied by

  14. Advances in software science and technology

    CERN Document Server

    Ohno, Yoshio; Kamimura, Tsutomu

    1991-01-01

    Advances in Software Science and Technology, Volume 2 provides information pertinent to the advancement of the science and technology of computer software. This book discusses the various applications for computer systems.Organized into four parts encompassing 12 chapters, this volume begins with an overview of categorical frameworks that are widely used to represent data types in computer science. This text then provides an algorithm for generating vertices of a smoothed polygonal line from the vertices of a digital curve or polygonal curve whose position contains a certain amount of error. O

  15. Advances in software science and technology

    CERN Document Server

    Kakuda, Hiroyasu; Ohno, Yoshio

    1992-01-01

    Advances in Software Science and Technology, Volume 3 provides information pertinent to the advancement of the science and technology of computer software. This book discusses the various applications for computer systems.Organized into two parts encompassing 11 chapters, this volume begins with an overview of the development of a system of writing tools called SUIKOU that analyzes a machine-readable Japanese document textually. This text then presents the conditioned attribute grammars (CAGs) and a system for evaluating them that can be applied to natural-language processing. Other chapters c

  16. Advanced technologies in trauma critical care management.

    Science.gov (United States)

    Cannon, Jeremy W; Chung, Kevin K; King, David R

    2012-08-01

    Care of critically injured patients has evolved over the 50 years since Shoemaker established one of the first trauma units at Cook County Hospital in 1962. Modern trauma intensive care units offer a high nurse-to-patient ratio, physicians and midlevel providers who manage the patients, and technologically advanced monitors and therapeutic devices designed to optimize the care of patients. This article describes advances that have transformed trauma critical care, including bedside ultrasonography, novel patient monitoring techniques, extracorporeal support, and negative pressure dressings. It also discusses how to evaluate the safety and efficacy of future advances in trauma critical care. PMID:22850154

  17. Development of fabrication technology for CANDU advanced fuel -Development of the advanced CANDU technology-

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Chang Beom; Kim, Hyeong Soo; Kim, Sang Won; Seok, Ho Cheon; Shim, Ki Seop; Byeon, Taek Sang; Jang, Ho Il; Kim, Sang Sik; Choi, Il Kwon; Cho, Dae Sik; Sheo, Seung Won; Lee, Soo Cheol; Kim, Yoon Hoi; Park, Choon Ho; Jeong, Seong Hoon; Kang, Myeong Soo; Park, Kwang Seok; Oh, Hee Kwan; Jang, Hong Seop; Kim, Yang Kon; Shin, Won Cheol; Lee, Do Yeon; Beon, Yeong Cheol; Lee, Sang Uh; Sho, Dal Yeong; Han, Eun Deok; Kim, Bong Soon; Park, Cheol Joo; Lee, Kyu Am; Yeon, Jin Yeong; Choi, Seok Mo; Shon, Jae Moon [Korea Atomic Energy Res. Inst., Taejon (Korea, Republic of)

    1994-07-01

    The present study is to develop the advanced CANDU fuel fabrication technologies by means of applying the R and D results and experiences gained from localization of mass production technologies of CANDU fuels. The annual portion of this year study includes following: 1. manufacturing of demo-fuel bundles for out-of-pile testing 2. development of technologies for the fabrication and inspection of advanced fuels 3. design and munufacturing of fuel fabrication facilities 4. performance of fundamental studies related to the development of advanced fuel fabrication technology.

  18. Recent advances in application of EB Technology

    International Nuclear Information System (INIS)

    In this paper recent advances in application of electron beam technology are presented. Important industrial and scientific achievements of the international community, together with research by Mediscan, Austria, an operator of state-of-the-art electron beam service center and innovator in the field of EB-Technology are reviewed. In addition, areas which may play an important role in the future are identified. Special focus is on the use of X-ray converters and the potential for industrial applications. (author)

  19. TECHcitement: Advances in Technological Education, 2004

    Science.gov (United States)

    American Association of Community Colleges (NJ1), 2004

    2004-01-01

    This edition of "TECHcitement" contains the following articles: (1) ATE Program Leads to Student Success; (2) Doing Whatever It Takes for Aquaculture; (3) The Bridge to Biotech; (4) Girls See What They Can Do With Technology at Camp; (5) Students Advancing Solutions to Business Problems; (6) CREATE Recreates Technical Education in California; (7)…

  20. TECHcitement: Advances in Technology Education, 2008

    Science.gov (United States)

    Patton, Madeline

    2008-01-01

    This publication presents the following articles: (1) Advanced Technological Education (ATE) Develops Student Recruitment and Retention Strategies; (2) Marketer Advises Tech Educators Appeal to Teens' Emotions, Desires to Do Something Important; (3) Digital Bridge Academy Gets At-Risk Students on Paths to Knowledge-Based Careers; (4) Project…

  1. Advanced Stirling Convertor (ASC) Technology Maturation

    Science.gov (United States)

    Wong, Wayne A.; Wilson, Scott; Collins, Josh; Wilson, Kyle

    2016-01-01

    The Advanced Stirling Convertor (ASC) development effort was initiated by NASA Glenn Research Center with contractor Sunpower, Inc., to develop high-efficiency thermal-to-electric power conversion technology for NASA Radioisotope Power Systems (RPSs). Early successful performance demonstrations led to the expansion of the project as well as adoption of the technology by the Department of Energy (DOE) and system integration contractor Lockheed Martin Space Systems Company as part of the Advanced Stirling Radioisotope Generator (ASRG) flight project. The ASRG integrates a pair of ASCs to convert the heat from a pair of General Purpose Heat Source (GPHS) modules into electrical power. The expanded NASA ASC effort included development of several generations of ASC prototypes or engineering units to help prepare the ASC technology and Sunpower for flight implementation. Sunpower later had two parallel contracts allowing the last of the NASA engineering units called ASC-E3 to serve as pathfinders for the ASC-F flight convertors being built for DOE. The ASC-E3 convertors utilized the ASC-F flight specifications and were built using the ASC-F design and process documentation. Shortly after the first ASC-F pair achieved initial operation, due to budget constraints, the DOE ASRG flight development contract was terminated. NASA continues to invest in the development of Stirling RPS technology including continued production of the ASC-E3 convertors, seven of which have been delivered with one additional unit in production. Starting in fiscal year 2015, Stirling Convertor Technology Maturation has been reorganized as an element of the RPS Stirling Cycle Technology Development (SCTD) Project and long-term plans for continued Stirling technology advancement are in reformulation. This paper provides a status on the ASC project, an overview of advancements made in the design and production of the ASC at Sunpower, and a summary of acceptance tests, reliability tests, and tactical

  2. Accelerators for the advanced radiation technology project

    International Nuclear Information System (INIS)

    Ion beam irradiation facilities are now under construction for the advanced radiation technology (ART) project in Takasaki Radiation Chemistry Research Establishment of (Japan Atomic Energy Research Institute) JAERI. The project is intended to make an effective use of ion beams, especially ion beams, in the research field of radiation application technology. The TIARA (Takasaki Ion Accelerators for Advanced Radiation Application) facilities include four ion accelerators to produce almost all kinds of energetic ions in the periodic table. The facilities are also provided with several advanced irradiation means and act as very powerful accelerator complex for material development. Specifically, this report presents an outline of the ART project, features of TIARA as accelerator facilities dedicated to material development, the AVF cyclotron under construction (Sumitomo Heavy Industries, Ltd., Model 930), tandem accelerator, microbeam, and experimental instruments used. (N.K.)

  3. Advanced technologies: Trends and implications for security

    International Nuclear Information System (INIS)

    As the world moves towards the close of the twentieth century, three technological trends will strongly influence security. In order of importance they are: first, the increasing globalization of the ability to develop and use high technology, much of which has both civilian and military applications; secondly, the broad dissemination of militarily-relevant technology world-wide; and thirdly, the continued development by the United States and the USSR (and a few other nations) of advanced technology for military applications. The military balance between the super-Powers and their allies has been strongly rooted in advancing military technology. Great changes in technology have resulted in adjustments -mostly in limited aspects such as the armour/ anti-armour balance - but have not caused it to change wildly. This seems likely to remain the case for the foreseeable future. There are arguments that Western technology has been a prime causative factor behind Soviet willingness to engage in negotiations to reduce forces. They claim that fear of the Strategic Defense Initiative is behind progress in the Strategic Arms Reduction Talks, and that perceived Western mastery of the technology for systems combining quick reaction, deep strike and high kill probabilities led the Soviet Union to reassess its potential for a successful land campaign in Europe. If current arms control negotiations are successful, the momentum is maintained, and other political changes take hold, the military balance could be taken to a point where ft would not be very sensitive to technological change. One should be aware that the arms control negotiations are very complex, primarily because of technological issues, and we should not yet bank on it all working out well. If it fails, the military technical competition will heat up again. Even under a strict arms control regime we can expect the competition to continue as each side seeks to develop counters to what ft sees as the other side

  4. Ceramic Technology for Advanced Heat Engines Project

    Energy Technology Data Exchange (ETDEWEB)

    1990-08-01

    The Ceramic Technology For Advanced Heat Engines Project was developed by the Department of Energy's Office of Transportation Systems (OTS) in Conservation and Renewable Energy. This project, part of the OTS's Advanced Materials Development Program, was developed to meet the ceramic technology requirements of the OTS's automotive technology programs. Significant accomplishments in fabricating ceramic components for the Department of Energy (DOE), National Aeronautics and Space Administration (NASA), and Department of Defense (DOD) advanced heat engine programs have provided evidence that the operation of ceramic parts in high-temperature engine environments is feasible. However, these programs have also demonstrated that additional research is needed in materials and processing development, design methodology, and data base and life prediction before industry will have a sufficient technology base from which to produce reliable cost-effective ceramic engine components commercially. An assessment of needs was completed, and a five year project plan was developed with extensive input from private industry. The objective of the project is to develop the industrial technology base required for reliable ceramics for application in advanced automotive heat engines. The project approach includes determining the mechanisms controlling reliability, improving processes for fabricating existing ceramics, developing new materials with increased reliability, and testing these materials in simulated engine environments to confirm reliability. Although this is a generic materials project, the focus is on structural ceramics for advanced gas turbine and diesel engines, ceramic hearings and attachments, and ceramic coatings for thermal barrier and wear applications in these engines.

  5. Recent advances in imaging technologies in dentistry

    Institute of Scientific and Technical Information of China (English)

    Naseem; Shah; Nikhil; Bansal; Ajay; Logani

    2014-01-01

    Dentistry has witnessed tremendous advances in all its branches over the past three decades. With these advances, the need for more precise diagnostic tools,specially imaging methods, have become mandatory.From the simple intra-oral periapical X-rays, advanced imaging techniques like computed tomography, cone beam computed tomography, magnetic resonance imaging and ultrasound have also found place in modern dentistry. Changing from analogue to digital radiography has not only made the process simpler and faster but also made image storage, manipulation(brightness/contrast, image cropping, etc.) and retrieval easier. The three-dimensional imaging has made the complex cranio-facial structures more accessible for examination and early and accurate diagnosis of deep seated lesions. This paper is to review current advances in imaging technology and their uses in different disciplines of dentistry.

  6. Advanced technology development reducing CO2 emissions

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Dong Sup

    2010-09-15

    Responding to Korean government policies on green growth and global energy/ environmental challenges, SK energy has been developing new technologies to reduce CO2 emissions by 1) CO2 capture and utilization, 2) efficiency improvement, and 3) Li-ion batteries. The paper introduces three advanced technologies developed by SK energy; GreenPol, ACO, and Li-ion battery. Contributing to company vision, a more energy and less CO2, the three technologies are characterized as follows. GreenPol utilizes CO2 as a feedstock for making polymer. Advanced Catalytic Olefin (ACO) reduces CO2 emission by 20% and increase olefin production by 17%. Li-ion Batteries for automotive industries improves CO2 emission.

  7. Development of advanced neutron beam technology

    International Nuclear Information System (INIS)

    The purpose of this work is to timely support the national science and technology policy through development of the advanced application techniques for neutron spectrometers, built in the previous project, in order to improve the neutron spectrometer techniques up to the world-class level in both quantity and quality and to reinforce industrial competitiveness. The importance of the research and development (R and D) is as follows: 1. Technological aspects - Development of a high value-added technology through performing the advanced R and D in the broad research areas from basic to applied science and from hard to soft condensed matter using neutron scattering technique. - Achievement of an important role in development of the new technology for the following industries aerospace, defense industry, atomic energy, hydrogen fuel cell etc. by the non-destructive inspection and analysis using neutron radiography. - Development of a system supporting the academic-industry users for the HANARO facility 2. Economical and Industrial Aspects - Essential technology in the industrial application of neutron spectrometer, in the basic and applied research of the diverse materials sciences, and in NT, BT, and IT areas - Broad impact on the economics and the domestic and international collaborative research by using the neutron instruments in the mega-scale research facility, HANARO, that is a unique source of neutron in Korea. 3. Social Aspects - Creating the scientific knowledge and contributing to the advanced industrial society through the neutron beam application - Improving quality of life and building a national consensus on the application of nuclear power by developing the RT fusion technology using the HANARO facility. - Widening the national research area and strengthening the national R and D capability by performing advanced R and D using the HANARO facility

  8. Development of advanced neutron beam technology

    Energy Technology Data Exchange (ETDEWEB)

    Seong, B. S.; Lee, J. S.; Sim, C. M. (and others)

    2007-06-15

    The purpose of this work is to timely support the national science and technology policy through development of the advanced application techniques for neutron spectrometers, built in the previous project, in order to improve the neutron spectrometer techniques up to the world-class level in both quantity and quality and to reinforce industrial competitiveness. The importance of the research and development (R and D) is as follows: 1. Technological aspects - Development of a high value-added technology through performing the advanced R and D in the broad research areas from basic to applied science and from hard to soft condensed matter using neutron scattering technique. - Achievement of an important role in development of the new technology for the following industries aerospace, defense industry, atomic energy, hydrogen fuel cell etc. by the non-destructive inspection and analysis using neutron radiography. - Development of a system supporting the academic-industry users for the HANARO facility 2. Economical and Industrial Aspects - Essential technology in the industrial application of neutron spectrometer, in the basic and applied research of the diverse materials sciences, and in NT, BT, and IT areas - Broad impact on the economics and the domestic and international collaborative research by using the neutron instruments in the mega-scale research facility, HANARO, that is a unique source of neutron in Korea. 3. Social Aspects - Creating the scientific knowledge and contributing to the advanced industrial society through the neutron beam application - Improving quality of life and building a national consensus on the application of nuclear power by developing the RT fusion technology using the HANARO facility. - Widening the national research area and strengthening the national R and D capability by performing advanced R and D using the HANARO facility.

  9. Development of Advanced Ceramic Manufacturing Technology; FINAL

    International Nuclear Information System (INIS)

    Advanced structural ceramics are enabling materials for new transportation engine systems that have the potential for significantly reducing energy consumption and pollution in automobiles and heavy vehicles. Ceramic component reliability and performance have been demonstrated in previous U.S. DOE initiatives, but high manufacturing cost was recognized as a major barrier to commercialization. Norton Advanced Ceramics (NAC), a division of Saint-Gobain Industrial Ceramics, Inc. (SGIC), was selected to perform a major Advanced Ceramics Manufacturing Technology (ACMT) Program. The overall objectives of NAC's program were to design, develop, and demonstrate advanced manufacturing technology for the production of ceramic exhaust valves for diesel engines. The specific objectives were (1) to reduce the manufacturing cost by an order of magnitude, (2) to develop and demonstrate process capability and reproducibility, and (3) to validate ceramic valve performance, durability, and reliability. I n order to achieve these objectives, NAC, a leading U.S. advanced ceramics component manufacturer, assembled a multidisciplinary, vertically integrated team. This team included: a major diesel engine builder, Detroit Diesel Corporation (DDC); a corporate ceramics research division, SGIC's Northboro R and D Center; intelligent processing system developers, BDM Federal/MATSYS; a furnace equipment company, Centorr/Vacuum Industries; a sintering expert, Wittmer Consultants; a production OEM, Deco-Grand; a wheel manufacturer and grinding operation developer, Norton Company's Higgins Grinding Technology Center (HGTC); a ceramic machine shop, Chand Kare Technical Ceramics; and a manufacturing cost consultant, IBIS Associates. The program was divided into four major tasks: Component Design and Specification, Component Manufacturing Technology Development, Inspection and Testing, and Process Demonstration

  10. Advances in nuclear science and technology

    CERN Document Server

    Henley, Ernest J

    1970-01-01

    Advances in Nuclear Science and Technology, Volume 5 presents the underlying principles and theory, as well as the practical applications of the advances in the nuclear field. This book reviews the specialized applications to such fields as space propulsion.Organized into six chapters, this volume begins with an overview of the design and objective of the Fast Flux Test Facility to provide fast flux irradiation testing facilities. This text then examines the problem in the design of nuclear reactors, which is the analysis of the spatial and temporal behavior of the neutron and temperature dist

  11. Advances in nuclear science and technology

    CERN Document Server

    Greebler, Paul

    1966-01-01

    Advances in Nuclear Science and Technology, Volume 3 provides an authoritative, complete, coherent, and critical review of the nuclear industry. This book presents the advances in the atomic energy field.Organized into six chapters, this volume begins with an overview of the use of pulsed neutron sources for the determination of the thermalization and diffusion properties of moderating as well as multiplying media. This text then examines the effect of nuclear radiation on electronic circuitry and its components. Other chapters consider radiation effects in various inorganic solids, with empha

  12. Lithium batteries advanced technologies and applications

    CERN Document Server

    Scrosati, Bruno; Schalkwijk, Walter A van; Hassoun, Jusef

    2013-01-01

    Explains the current state of the science and points the way to technological advances First developed in the late 1980s, lithium-ion batteries now power everything from tablet computers to power tools to electric cars. Despite tremendous progress in the last two decades in the engineering and manufacturing of lithium-ion batteries, they are currently unable to meet the energy and power demands of many new and emerging devices. This book sets the stage for the development of a new generation of higher-energy density, rechargeable lithium-ion batteries by advancing battery chemistry and ident

  13. POTENCIAL DE LA TECNOLOGÍA "GAS TO LIQUIDS GTL" EN COLOMBIA Potential of the "gas to liquids-GTL" technology in Colombia

    Directory of Open Access Journals (Sweden)

    Julio-César Pérez Angulo

    2005-12-01

    source of energy than petroleum, but having the disadvantage of requiring high costs for its transportation. For this reason many alternatives for the development of reserves have loomed. Among these is the conversion of natural gas into synthetic ultra-clean fuels, called GTL, or Gas-to-liquids. Through this process, Fischer-Tropsch for the production of diesel, naphta and specialized products, which are used not only to effectively utilize natural gas reserves, but also, to cover at the need of more environmentally-friendly fuels. This article will shed light on GTL technologies, presenting on a first instance an analysis of the different stages of the Fischer-Tropsch process, then the current status of this technology, afterwards the costs of investment and the necessary conditions for a project of this kind to be carried out and finally, and analysis of the applicability or projection for this technology in Colombia. Based on recent studies, it has been observed that is technology has surpassed its demonstrations stage and it is now at a maximum point of interest where companies like Sasol (the largest worldwide company in the area of synthetic carbon-based fuels, Chevron Texaco, Syntroleum, ExxonMobil, ConocoPhillips, BP, Rentech and Shell. These companies have performed successful studies for the applicability of the Fischer-Tropsch technology at a large scale, and they will begin to build a number of large plants within the next few years, principally motivated by the low costs of gas and high prices of crude oil.

  14. Ceramic technology for advanced heat engines project

    Energy Technology Data Exchange (ETDEWEB)

    1990-09-01

    The Ceramic Technology for Advanced Heat Engines Project was developed by the Department of Energy's Office of Transportation Systems in Conservation and Renewable Energy. This project was developed to meet the ceramic technology requirements of the OTT's automotive technology programs. This project is managed by ORNL and is closely coordinated with complementary ceramics tasks funded by other DOE offices, NASA, DoD, and industry. Research is discussed under the following topics; Turbomilling of SiC Whiskers; microwave sintering of silicon nitride; and milling characterization; processing of monolithics; silicon nitride matrix; oxide matrix; silicate matrix; thermal and wear coatings; joining; design; contact interfaces; time-dependent behavior; environmental effects; fracture mechanics; nondestructive evaluation; and technology transfer. References, figures, and tables are included with each topic.

  15. Validation and transfer of advanced NDE technologies

    International Nuclear Information System (INIS)

    This paper reports on progress achieved under the Nuclear Regulatory Commission (NRC) program entitled Field Validation, Acceptance and Training for Advanced Nondestructive Testing (NDE) Technology. Work under this program in FY91 has concentrated on validation testing and the transfer of technologies previously developed under NRC supported programs. The objective of these efforts is to provide new beneficial NDE techniques which have been validated in their intended application mode on a reactor(s) and to transfer technologies to the nuclear industry. Program efforts are focused on acoustic emission (AE) for continuous monitoring and the synthetic aperture focusing technique for ultrasonic testing (SAFT-UT). These technologies will benefit nuclear plant regulation by providing timely indication of flaw initiation and growth as it occurs and the reliable detection of flaws with an accurate measure of the flaw size and shape

  16. Cooperative technology development: An approach to advancing energy technology

    International Nuclear Information System (INIS)

    Technology development requires an enormous financial investment over a long period of time. Scarce national and corporate resources, the result of highly competitive markets, decreased profit margins, wide currency fluctuations, and growing debt, often preclude continuous development of energy technology by single entities, i.e., corporations, institutions, or nations. Although the energy needs of the developed world are generally being met by existing institutions, it is becoming increasingly clear that existing capital formation and technology transfer structures have failed to aid developing nations in meeting their growing electricity needs. This paper will describe a method for meeting the electricity needs of the developing world through technology transfer and international cooperative technology development. The role of nuclear power and the advanced passive plant design will be discussed. (author)

  17. Advances in nuclear science and technology

    CERN Document Server

    Henley, Ernest J

    1972-01-01

    Advances in Nuclear Science and Technology, Volume 6 provides information pertinent to the fundamental aspects of nuclear science and technology. This book covers a variety of topics, including nuclear steam generator, oscillations, fast reactor fuel, gas centrifuge, thermal transport system, and fuel cycle.Organized into six chapters, this volume begins with an overview of the high standards of technical safety for Europe's first nuclear-propelled merchant ship. This text then examines the state of knowledge concerning qualitative results on the behavior of the solutions of the nonlinear poin

  18. Advances in nuclear science and technology

    CERN Document Server

    Henley, Ernest J

    1973-01-01

    Advances in Nuclear Science and Technology, Volume 7 provides information pertinent to the fundamental aspects of nuclear science and technology. This book discusses the safe and beneficial development of land-based nuclear power plants.Organized into five chapters, this volume begins with an overview of irradiation-induced void swelling in austenitic stainless steels. This text then examines the importance of various transport processes for fission product redistribution, which depends on the diffusion data, the vaporization properties, and the solubility in the fuel matrix. Other chapters co

  19. Advances in nuclear science and technology

    CERN Document Server

    Henley, Ernest J

    1976-01-01

    Advances in Nuclear Science and Technology, Volume 9 provides information pertinent to the fundamental aspects of nuclear science and technology. This book discusses the safe and beneficial development of land-based nuclear power plants.Organized into five chapters, this volume begins with an overview of the possible consequences of a large-scale release of radioactivity from a nuclear reactor in the event of a serious accident. This text then discusses the extension of conventional perturbation techniques to multidimensional systems and to high-order approximations of the Boltzmann equation.

  20. Advances in HTGR spent fuel treatment technology

    International Nuclear Information System (INIS)

    GA Technologies, Inc. has been investigating the burning of spent reactor graphite under Department of Energy sponsorship since 1969. Several deep fluidized bed burners have been used at the GA pilot plant to develop graphite burning techniques for both spent fuel recovery and volume reduction for waste disposal. Since 1982 this technology has been extended to include more efficient circulating bed burners. This paper includes updates on high-temperature gas-cooled reactor fuel cycle options and current results of spent fuel treatment testing for fluidized and advanced circulating bed burners

  1. Advances in welding science and technology

    International Nuclear Information System (INIS)

    Over the years, welding has been more of an art than a science, but in the last few decades major advances have taken place in welding science and technology. With the development of new methodologies at the crossroads of basic and applied sciences, enormous opportunities and potential exist to develop a science-based design of composition, structure, and properties of welds with intelligent control and automation of the welding processes. In the last several decades, welding has evolved as an interdisciplinary activity requiring synthesis of knowledge from various disciplines and incorporating the most advanced tools of various basic applied sciences. A series of international conferences and other publications have covered the issues, current trends and directions in welding science and technology. In the last few decades, major progress has been made in (i) understanding physical processes in welding, (ii) characterization of microstructure and properties, and (iii) intelligent control and automation of welding. This paper describes some of these developments

  2. Advanced manufacturing: Technology and international competitiveness

    Energy Technology Data Exchange (ETDEWEB)

    Tesar, A.

    1995-02-01

    Dramatic changes in the competitiveness of German and Japanese manufacturing have been most evident since 1988. All three countries are now facing similar challenges, and these challenges are clearly observed in human capital issues. Our comparison of human capital issues in German, Japanese, and US manufacturing leads us to the following key judgments: Manufacturing workforces are undergoing significant changes due to advanced manufacturing technologies. As companies are forced to develop and apply these technologies, the constituency of the manufacturing workforce (especially educational requirements, contingent labor, job content, and continuing knowledge development) is being dramatically and irreversibly altered. The new workforce requirements which result due to advanced manufacturing require a higher level of worker sophistication and responsibility.

  3. Sustainability assessment of advanced wastewater treatment technologies

    DEFF Research Database (Denmark)

    Høibye, Linda; Clauson-Kaas, Jes; Wenzel, Henrik;

    2008-01-01

    As a consequence of the EU Water Framework Directive more focus is now on discharges of hazardous substances from wastewater treatment plants and sewers. Thus, many municipalities in Denmark may have to adopt to future advanced treatment technologies. This paper describes a holistic assessment...... with advanced oxidation. The technical assessment is based on 12 hazardous substances comprising heavy metals, organic pollutants, endocrine disruptors as well as pathogenic microorganisms. The environmental assessment is performed by life cycle assessment (LCA) comprising 9 of the specific hazardous substances...... of sustainability, sand filtration is the most advantageous method based on the technical and environmental assessment due to the low energy consumption and high efficiency with regards to removal of heavy metals. Key words | advanced wastewater treatment, life cycle assessment, MBR, ozone treatment, sand...

  4. Development of Advanced Ceramic Manufacturing Technology

    Energy Technology Data Exchange (ETDEWEB)

    Pujari, V.K.

    2001-04-05

    Advanced structural ceramics are enabling materials for new transportation engine systems that have the potential for significantly reducing energy consumption and pollution in automobiles and heavy vehicles. Ceramic component reliability and performance have been demonstrated in previous U.S. DOE initiatives, but high manufacturing cost was recognized as a major barrier to commercialization. Norton Advanced Ceramics (NAC), a division of Saint-Gobain Industrial Ceramics, Inc. (SGIC), was selected to perform a major Advanced Ceramics Manufacturing Technology (ACMT) Program. The overall objectives of NAC's program were to design, develop, and demonstrate advanced manufacturing technology for the production of ceramic exhaust valves for diesel engines. The specific objectives were (1) to reduce the manufacturing cost by an order of magnitude, (2) to develop and demonstrate process capability and reproducibility, and (3) to validate ceramic valve performance, durability, and reliability. The program was divided into four major tasks: Component Design and Specification, Component Manufacturing Technology Development, Inspection and Testing, and Process Demonstration. A high-power diesel engine valve for the DDC Series 149 engine was chosen as the demonstration part for this program. This was determined to be an ideal component type to demonstrate cost-effective process enhancements, the beneficial impact of advanced ceramics on transportation systems, and near-term commercialization potential. The baseline valve material was NAC's NT451 SiAION. It was replaced, later in the program, by an alternate silicon nitride composition (NT551), which utilized a lower cost raw material and a simplified powder-processing approach. The material specifications were defined based on DDC's engine requirements, and the initial and final component design tasks were completed.

  5. An overview of advanced power generation technologies

    International Nuclear Information System (INIS)

    This paper is intended as a brief review of the technologies currently applied in Australian electricity generation and the technologies which are likely to be employed in the future. The paper opens with a review of the primary energy resources available for the generation of electricity in Australia, and the technologies currently employed. The development of advanced generation technologies around the world is reviewed, and the most likely technologies to be employed in Australia are described. There are a number of renewable and alternative technologies, such as generation from sewage digester, landfill or mine gases. Their impact would, however, be disproportionate because of the strong climate forcing effect of methane. Of the wide range of other emerging renewable technologies examined, solar thermal offers the best prospect of maturing into a financially-competitive technology for large scale generation in the next 20 years. However, will remain unable to compete with non-renewable technologies in normal financial terms, at least until 2005 and probably well beyond that date. Generation using the fission of nuclear fuels is a mature, proven technology. Based on the most likely fuel and other assumptions made in this study, the costs of nuclear generation are only moderately higher than conventional coal-fired options. Nuclear generation is thus a relatively low cost route to reductions in carbon dioxide emission for new plant, at $19/tonne CO2 saved, in comparison with conventional black coal technology, and $13/tonne CO2 compared with conventional brown coal firing. While major considerations of societal acceptance clearly exist, nuclear generation has the necessary technical and financial qualifications for serious consideration as an element in any greenhouse strategy. 5 tab., 2 figs

  6. Technological advances in radiotherapy for esophageal cancer

    Institute of Scientific and Technical Information of China (English)

    Milan; Vosmik; Jiri; Petera; Igor; Sirak; Miroslav; Hodek; Petr; Paluska; Jiri; Dolezal; Marcela; Kopacova

    2010-01-01

    Radiotherapy with concurrent chemotherapy and surgery represent the main treatment modalities in esophageal cancer.The goal of modern radiotherapy approaches,based on recent technological advances,is to minimize post-treatment complications by improving the gross tumor volume definition (positron emission tomography-based planning),reducing interfraction motion (image-guided radiotherapy) and intrafraction motion (respiratory-gated radiotherapy),and by better dose delivery to the precisely defined planning ...

  7. Strategic management of advanced manufacturing technology

    OpenAIRE

    Pandža, Krsto; Polajnar, Andrej; Buchmeister, Borut

    2012-01-01

    The aim of this paper is threefold. First, it discusses the role of advanced manufacturing technology (AMT) within a strategic management context of a manufacturing organisation. Resource-based view is presented as a useful theoretical school for understanding strategic management of AMT. Second, a brief case from a manufacturing organisation is provided to illustrate the debate. In the reported case study, the relevant mechanisms for understanding capability accumulation process and the role...

  8. Advanced Reactor Technology -- Regulatory Technology Development Plan (RTDP)

    International Nuclear Information System (INIS)

    This DOE-NE Advanced Small Modular Reactor (AdvSMR) regulatory technology development plan (RTDP) will link critical DOE nuclear reactor technology development programs to important regulatory and policy-related issues likely to impact a ''critical path'' for establishing a viable commercial AdvSMR presence in the domestic energy market. Accordingly, the regulatory considerations that are set forth in the AdvSMR RTDP will not be limited to any one particular type or subset of advanced reactor technology(s) but rather broadly consider potential regulatory approaches and the licensing implications that accompany all DOE-sponsored research and technology development activity that deal with commercial non-light water reactors. However, it is also important to remember that certain ''minimum'' levels of design and safety approach knowledge concerning these technology(s) must be defined and available to an extent that supports appropriate pre-licensing regulatory analysis within the RTDP. Final resolution to advanced reactor licensing issues is most often predicated on the detailed design information and specific safety approach as documented in a facility license application and submitted for licensing review. Because the AdvSMR RTDP is focused on identifying and assessing the potential regulatory implications of DOE-sponsored reactor technology research very early in the pre-license application development phase, the information necessary to support a comprehensive regulatory analysis of a new reactor technology, and the resolution of resulting issues, will generally not be available. As such, the regulatory considerations documented in the RTDP should be considered an initial ''first step'' in the licensing process which will continue until a license is issued to build and operate the said nuclear facility. Because a facility license application relies heavily on the data and information generated by

  9. Advanced Reactor Technology -- Regulatory Technology Development Plan (RTDP)

    Energy Technology Data Exchange (ETDEWEB)

    Moe, Wayne Leland [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-05-01

    This DOE-NE Advanced Small Modular Reactor (AdvSMR) regulatory technology development plan (RTDP) will link critical DOE nuclear reactor technology development programs to important regulatory and policy-related issues likely to impact a “critical path” for establishing a viable commercial AdvSMR presence in the domestic energy market. Accordingly, the regulatory considerations that are set forth in the AdvSMR RTDP will not be limited to any one particular type or subset of advanced reactor technology(s) but rather broadly consider potential regulatory approaches and the licensing implications that accompany all DOE-sponsored research and technology development activity that deal with commercial non-light water reactors. However, it is also important to remember that certain “minimum” levels of design and safety approach knowledge concerning these technology(s) must be defined and available to an extent that supports appropriate pre-licensing regulatory analysis within the RTDP. Final resolution to advanced reactor licensing issues is most often predicated on the detailed design information and specific safety approach as documented in a facility license application and submitted for licensing review. Because the AdvSMR RTDP is focused on identifying and assessing the potential regulatory implications of DOE-sponsored reactor technology research very early in the pre-license application development phase, the information necessary to support a comprehensive regulatory analysis of a new reactor technology, and the resolution of resulting issues, will generally not be available. As such, the regulatory considerations documented in the RTDP should be considered an initial “first step” in the licensing process which will continue until a license is issued to build and operate the said nuclear facility. Because a facility license application relies heavily on the data and information generated by technology development studies, the anticipated regulatory

  10. Ceramic technology for Advanced Heat Engines Project

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, D.R.

    1991-07-01

    Significant accomplishments in fabricating ceramic components for advanced heat engine programs have provided evidence that the operation of ceramic parts in high-temperature engine environments is feasible. However, these programs have also demonstrated that additional research is needed in materials and processing development, design methodology, and database and life prediction before industry will have a sufficient technology base from which to produce reliable cost-effective ceramic engine components commercially. An assessment of needs was completed, and a five year project plan was developed with extensive input from private industry. The project approach includes determining the mechanisms controlling reliability, improving processes for fabricating existing ceramics, developing new materials with increased reliability, and testing these materials in simulated engine environments to confirm reliability. Although this is a generic materials project, the focus is on the structural ceramics for advanced gas turbine and diesel engines, ceramic bearings and attachments, and ceramic coatings for thermal barrier and wear applications in these engines. To facilitate the rapid transfer of this technology to US industry, the major portion of the work is being done in the ceramic industry, with technological support from government laboratories, other industrial laboratories, and universities. This project is managed by ORNL for the Office of Transportation Technologies, Office of Transportation Materials, and is closely coordinated with complementary ceramics tasks funded by other DOE offices, NASA, DOD, and industry.

  11. JPL Advanced Thermal Control Technology Roadmap - 2008

    Science.gov (United States)

    Birur, Gaj

    2008-01-01

    This slide presentation reviews the status of thermal control technology at JPL and NASA.It shows the active spacecraft that are in vairous positions in the solar syatem, and beyond the solar system and the future missions that are under development. It then describes the challenges that the past missions posed with the thermal control systems. The various solutions that were implemented duirng the decades prior to 1990 are outlined. A review of hte thermal challenges of the future misions is also included. The exploration plan for Mars is then reviewed. The thermal challenges of the Mars Rovers are then outlined. Also the challenges of systems that would be able to be used in to explore Venus, and Titan are described. The future space telescope missions will also need thermal control technological advances. Included is a review of the thermal requirements for manned missions to the Moon. Both Active and passive technologies that have been used and will be used are reviewed. Those that are described are Mechanically Pumped Fluid Loops (MPFL), Loop Heat Pipes, an M3 Passive Cooler, Heat Siwtch for Space and Mars surface applications, phase change material (PCM) technology, a Gas Gap Actuateor using ZrNiH(x), the Planck Sorption Cooler (PCS), vapor compression -- Hybrid two phase loops, advanced pumps for two phase cooling loops, and heat pumps that are lightweight and energy efficient.

  12. Green Propulsion Technologies for Advanced Air Transports

    Science.gov (United States)

    Del Rosario, Ruben

    2015-01-01

    Air transportation is critical to U.S. and Global economic vitality. However, energy and climate issues challenge aviations ability to be sustainable in the long term. Aviation must dramatically reduce fuel use and related emissions. Energy costs to U.S. airlines nearly tripled between 1995 and 2011, and continue to be the highest percentage of operating costs. The NASA Advanced Air Transports Technology Project addresses the comprehensive challenge of enabling revolutionary energy efficiency improvements in subsonic transport aircraft combined with dramatic reductions in harmful emissions and perceived noise to facilitate sustained growth of the air transportation system. Advanced technologies and the development of unconventional aircraft systems offer the potential to achieve these improvements. The presentation will highlight the NASA vision of revolutionary systems and propulsion technologies needed to achieve these challenging goals. Specifically, the primary focus is on the N+3 generation; that is, vehicles that are three generations beyond the current state of the art, requiring mature technology solutions in the 2025-30 timeframe, which are envisioned as being powered by Hybrid Electric Propulsion Systems.

  13. RF Technologies for Advancing Space Communication Infrastructure

    Science.gov (United States)

    Romanofsky, Robert R.; Bibyk, Irene K.; Wintucky, Edwin G.

    2006-01-01

    This paper will address key technologies under development at the NASA Glenn Research Center designed to provide architecture-level impacts. Specifically, we will describe deployable antennas, a new type of phased array antenna and novel power amplifiers. The evaluation of architectural influence can be conducted from two perspectives where said architecture can be analyzed from either the top-down to determine the areas where technology improvements will be most beneficial or from the bottom-up where each technology s performance advancement can affect the overall architecture s performance. This paper will take the latter approach with focus on some technology improvement challenges and address architecture impacts. For example, using data rate as a performance metric, future exploration scenarios are expected to demand data rates possibly exceeding 1 Gbps. To support these advancements in a Mars scenario, as an example, Ka-band and antenna aperture sizes on the order of 10 meters will be required from Mars areostationary platforms. Key technical challenges for a large deployable antenna include maximizing the ratio of deployed-to-packaged volume, minimizing aerial density, maintaining RMS surface accuracy to within 1/20 of a wavelength or better, and developing reflector rigidization techniques. Moreover, the high frequencies and large apertures manifest a new problem for microwave engineers that are familiar to optical communications specialists: pointing. The fine beam widths and long ranges dictate the need for electronic or mechanical feed articulation to compensate for spacecraft attitude control limitations.

  14. CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Hugh W. Rimmer

    2004-05-12

    This Technical Progress Report describes progress made on the seventeen subprojects awarded in the first year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices. Due to the time taken up by the solicitation/selection process, these cover the initial 6-month period of project activity only. The U.S. is the largest producer of mining products in the world. In 1999, U.S. mining operations produced $66.7 billion worth of raw materials that contributed a total of $533 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Originally set up by Virginia Tech and West Virginia University, this endeavor has been expanded into a seven-university consortium--Virginia Tech, West Virginia University, University of Kentucky, University of Utah, Montana Tech, New Mexico Tech and University of Nevada, Reno--that is supported through U.S. DOE Cooperative Agreement No. DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (1) Solid-solid separation (2) Solid-liquid separation (3) Chemical/Biological Extraction (4) Modeling and Control, and (5) Environmental Control.

  15. Advances in Information Technology and Industry Applications

    CERN Document Server

    2012-01-01

    With success of ICEEE 2010 in Wuhan, China, and December 4 to 5, 2010, the second International Conference of Electrical and Electronics Engineering (ICEEE 2011) will be held in Macau, China, and December 1 to 2, 2011. ICEEE is an annual conference to call together researchers, engineers, academicians as well as industrial professionals from all over the world to present their research results and development activities in Electrical and Electronics Engineering along with Computer Science and Technology, Communication Technology, Artificial Intelligence, Information Technology, etc.   This year ICEEE is sponsored by International Industrial Electronics Center, Hong Kong. And based on the deserved reputation, more than 750 papers have been submitted to ICEEE 2011, from which about 94 high quality original papers have been selected for the conference presentation and inclusion in the “Advanced Computer, Communication, and Control” book based on the referees’ comments from peer-refereed. All the papers wi...

  16. Biomass energy conversion: conventional and advanced technologies

    International Nuclear Information System (INIS)

    Increasing interest in biomass energy conversion in recent years has focused attention on enhancing the efficiency of technologies converting biomass fuels into heat and power, their capital and operating costs and their environmental emissions. Conventional combustion systems, such as fixed-bed or grate units and entrainment units, deliver lower efficiencies (<25%) than modem coal-fired combustors (30-35%). The gasification of biomass will improve energy conversion efficiency and yield products useful for heat and power generation and chemical synthesis. Advanced biomass gasification technologies using pressurized fluidized-bed systems, including those incorporating hot-gas clean-up for feeding gas turbines or fuel cells, are being demonstrated. However, many biomass gasification processes are derivatives of coal gasification technologies and do not exploit the unique properties of biomass. This paper examines some existing and upcoming technologies for converting biomass into electric power or heat. Small-scale 1-30 MWe units are emphasized, but brief reference is made to larger and smaller systems, including those that bum coal-biomass mixtures and gasifiers that feed pilot-fuelled diesel engines. Promising advanced systems, such as a biomass integrated gasifier/gas turbine (BIG/GT) with combined-cycle operation and a biomass gasifier coupled to a fuel cell, giving cycle efficiencies approaching 50% are also described. These advanced gasifiers, typically fluid-bed designs, may be pressurized and can use a wide variety of biomass materials to generate electricity, process steam and chemical products such as methanol. Low-cost, disposable catalysts are becoming available for hot-gas clean-up (enhanced gas composition) for turbine and fuel cell systems. The advantages, limitations and relative costs of various biomass gasifier systems are briefly discussed. The paper identifies the best known biomass power projects and includes some information on proposed and

  17. International Conference on Computers and Advanced Technology in Education

    CERN Document Server

    Advanced Information Technology in Education

    2012-01-01

    The volume includes a set of selected papers extended and revised from the 2011 International Conference on Computers and Advanced Technology in Education. With the development of computers and advanced technology, the human social activities are changing basically. Education, especially the education reforms in different countries, has been experiencing the great help from the computers and advanced technology. Generally speaking, education is a field which needs more information, while the computers, advanced technology and internet are a good information provider. Also, with the aid of the computer and advanced technology, persons can make the education an effective combination. Therefore, computers and advanced technology should be regarded as an important media in the modern education. Volume Advanced Information Technology in Education is to provide a forum for researchers, educators, engineers, and government officials involved in the general areas of computers and advanced technology in education to d...

  18. Advanced Education and Technology Business Plan, 2010-13

    Science.gov (United States)

    Alberta Advanced Education and Technology, 2010

    2010-01-01

    This paper presents the business plan of the Ministry of Advanced Education and Technology for 2010 to 2013. Advanced Education and Technology supports the advanced learning system by providing funding for advanced learning providers, coordinating and approving programs of study at public institutions, licensing and approving programs at private…

  19. Advanced nuclear reactor types and technologies

    Energy Technology Data Exchange (ETDEWEB)

    Ignatiev, V. [ed.; Feinberg, O.; Morozov, A. [Russian Research Centre `Kurchatov Institute`, Moscow (Russian Federation); Devell, L. [Studsvik Eco and Safety AB, Nykoeping (Sweden)

    1995-07-01

    The document is a comprehensive world-wide catalogue of concepts and designs of advanced fission reactor types and fuel cycle technologies. Two parts have been prepared: Part 1 Reactors for Power Production and Part 2 Heating and Other Reactor Applications. Part 3, which will cover advanced waste management technology, reprocessing and disposal for different nuclear fission options is planned for compilation during 1995. The catalogue was prepared according to a special format which briefly presents the project title, technical approach, development status, application of the technology, reactor type, power output, and organization which developed these designs. Part 1 and 2 cover water cooled reactors, liquid metal fast reactors, gas-cooled reactors and molten salt reactors. Subcritical accelerator-driven systems are also considered. Various reactor applications as power production, heat generation, ship propulsion, space power sources and transmutation of such waste are included. Each project is described within a few pages with the main features of an actual design using a table with main technical data and figure as well as references for additional information. Each chapter starts with an introduction which briefly describes main trends and approaches in this field. Explanations of terms and abbreviations are provided in a glossary.

  20. Advanced nuclear reactor types and technologies

    International Nuclear Information System (INIS)

    The document is a comprehensive world-wide catalogue of concepts and designs of advanced fission reactor types and fuel cycle technologies. Two parts have been prepared: Part 1 Reactors for Power Production and Part 2 Heating and Other Reactor Applications. Part 3, which will cover advanced waste management technology, reprocessing and disposal for different nuclear fission options is planned for compilation during 1995. The catalogue was prepared according to a special format which briefly presents the project title, technical approach, development status, application of the technology, reactor type, power output, and organization which developed these designs. Part 1 and 2 cover water cooled reactors, liquid metal fast reactors, gas-cooled reactors and molten salt reactors. Subcritical accelerator-driven systems are also considered. Various reactor applications as power production, heat generation, ship propulsion, space power sources and transmutation of such waste are included. Each project is described within a few pages with the main features of an actual design using a table with main technical data and figure as well as references for additional information. Each chapter starts with an introduction which briefly describes main trends and approaches in this field. Explanations of terms and abbreviations are provided in a glossary

  1. Overview of biomass conversion technologies

    International Nuclear Information System (INIS)

    A large part of the biomass is used for non-commercial purposes and mostly for cooking and heating, but the use is not sustainable, because it destroys soil-nutrients, causes indoor and outdoor pollution, adds to greenhouse gases, and results in health problems. Commercial use of biomass includes household fuelwood in industrialized countries and bio-char (charcoal) and firewood in urban and industrial areas in developing countries. The most efficient way of biomass utilization is through gasification, in which the gas produced by biomass gasification can either be used to generate power in an ordinary steam-cycle or be converted into motor fuel. In the latter case, there are two alternatives, namely, the synthesis of methanol and methanol-based motor fuels, or Fischer-Tropsch hydrocarbon synthesis. This paper deals with the technological overview of the state-of-the-art key biomass-conversion technologies that can play an important role in the future. The conversion routes for production of Heat, power and transportation fuel have been summarized in this paper, viz. combustion, gasification, pyrolysis, digestion, fermentation and extraction. (author)

  2. 10 CFR 611.3 - Advanced technology vehicle.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 4 2010-01-01 2010-01-01 false Advanced technology vehicle. 611.3 Section 611.3 Energy DEPARTMENT OF ENERGY (CONTINUED) ASSISTANCE REGULATIONS ADVANCED TECHNOLOGY VEHICLES MANUFACTURER ASSISTANCE PROGRAM General § 611.3 Advanced technology vehicle. In order to demonstrate that a vehicle is...

  3. Advanced Technology System Scheduling Governance Model

    Energy Technology Data Exchange (ETDEWEB)

    Ang, Jim [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Carnes, Brian [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Hoang, Thuc [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Vigil, Manuel [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-06-11

    In the fall of 2005, the Advanced Simulation and Computing (ASC) Program appointed a team to formulate a governance model for allocating resources and scheduling the stockpile stewardship workload on ASC capability systems. This update to the original document takes into account the new technical challenges and roles for advanced technology (AT) systems and the new ASC Program workload categories that must be supported. The goal of this updated model is to effectively allocate and schedule AT computing resources among all three National Nuclear Security Administration (NNSA) laboratories for weapons deliverables that merit priority on this class of resource. The process outlined below describes how proposed work can be evaluated and approved for resource allocations while preserving high effective utilization of the systems. This approach will provide the broadest possible benefit to the Stockpile Stewardship Program (SSP).

  4. IPIRG programs - advances in pipe fracture technology

    Energy Technology Data Exchange (ETDEWEB)

    Wilkowski, G.; Olson, R.; Scott, P. [Batelle, Columbus, OH (United States)

    1997-04-01

    This paper presents an overview of the advances made in fracture control technology as a result of the research performed in the International Piping Integrity Research Group (IPIRG) program. The findings from numerous experiments and supporting analyses conducted to investigate the behavior of circumferentially flawed piping and pipe systems subjected to high-rate loading typical of seismic events are summarized. Topics to be discussed include; (1) Seismic loading effects on material properties, (2) Piping system behavior under seismic loads, (3) Advances in elbow fracture evaluations, and (4) {open_quotes}Real{close_quotes} piping system response. The presentation for each topic will be illustrated with data and analytical results. In each case, the state-of-the-art in fracture mechanics prior to the first IPIRG program will be contrasted with the state-of-the-art at the completion of the IPIRG-2 program.

  5. Advanced Technology Development for Stirling Convertors

    Science.gov (United States)

    Thieme, Lanny G.; Schreiber, Jeffrey G.

    2004-01-01

    A high-efficiency Stirling Radioisotope Generator (SRG) for use on potential NASA Space Science missions is being developed by the Department of Energy, Lockheed Martin, Stirling Technology Company, and NASA Glenn Research Center (GRC). These missions may include providing spacecraft onboard electric power for deep space missions or power for unmanned Mars rovers. GRC is also developing advanced technology for Stirling convertors, aimed at substantially improving the specific power and efficiency of the convertor and the overall power system. Performance and mass improvement goals have been established for second- and thirdgeneration Stirling radioisotope power systems. Multiple efforts are underway to achieve these goals, both in-house at GRC and under various grants and contracts. The status and results to date for these efforts will be discussed in this paper. Cleveland State University (CSU) is developing a multi-dimensional Stirling computational fluid dynamics code, capable of modeling complete convertors. A 2-D version of the code is now operational, and validation efforts at both CSU and the University of Minnesota are complementing the code development. A screening of advanced superalloy, refractory metal alloy, and ceramic materials has been completed, and materials have been selected for creep and joining characterization as part of developing a high-temperature heater head. A breadboard characterization is underway for an advanced controller using power electronics for active power factor control with a goal of eliminating the heavy tuning capacitors that are typically needed to achieve near unity power factors. Key Stirling developments just initiated under recent NRA (NASA Research Announcement) awards will also be discussed. These include a lightweight convertor to be developed by Sunpower Inc. and an advanced microfabricated regenerator to be done by CSU.

  6. Physics and Advanced Technologies 2001 Annual Report

    Energy Technology Data Exchange (ETDEWEB)

    Jacobs, R

    2002-05-09

    The Physics and Advanced Technologies (PAT) Directorate was created in July 2000 by Bruce Tarter, Director of Lawrence Livermore National Laboratory (LLNL). The Director called for the new organization to execute and support programs that apply cutting-edge physics and advanced technology to develop integrated solutions to problems in national security, fusion energy, information science, health care, and other national grand challenges. When I was appointed a year later as the PAT Directorate's first Associate Director, I initiated a strategic planning project to develop a vision, mission, and long-term goals for the Directorate. We adopted the goal of becoming a leader in frontier physics and technology for twenty-first-century national security missions: Stockpile Stewardship, homeland security, energy independence, and the exploration of space. Our mission is to: (1) Help ensure the scientific excellence and vitality of the major LLNL programs through its leadership role in performing basic and applied multidisciplinary research and development with programmatic impact, and by recruiting and retaining science and technology leaders; (2) Create future opportunities and directions for LLNL and its major programs by growing new program areas and cutting-edge capabilities that are synergistic with, and supportive of, its national security mission; (3) Provide a direct conduit to the academic and high-tech industrial sectors for LLNL and its national security programs, through which the Laboratory gains access to frontier science and technology, and can impact the science and technology communities; (4) Leverage unique Laboratory capabilities, to advance the state universe. This inaugural PAT Annual Report begins a series that will chronicle our progress towards fulfilling this mission. I believe the report demonstrates that the PAT Directorate has a strong base of capabilities and accomplishments on which to build in meeting its goals. Some of the highlights

  7. Physics and Advanced Technologies 2001 Annual Report

    International Nuclear Information System (INIS)

    The Physics and Advanced Technologies (PAT) Directorate was created in July 2000 by Bruce Tarter, Director of Lawrence Livermore National Laboratory (LLNL). The Director called for the new organization to execute and support programs that apply cutting-edge physics and advanced technology to develop integrated solutions to problems in national security, fusion energy, information science, health care, and other national grand challenges. When I was appointed a year later as the PAT Directorate's first Associate Director, I initiated a strategic planning project to develop a vision, mission, and long-term goals for the Directorate. We adopted the goal of becoming a leader in frontier physics and technology for twenty-first-century national security missions: Stockpile Stewardship, homeland security, energy independence, and the exploration of space. Our mission is to: (1) Help ensure the scientific excellence and vitality of the major LLNL programs through its leadership role in performing basic and applied multidisciplinary research and development with programmatic impact, and by recruiting and retaining science and technology leaders; (2) Create future opportunities and directions for LLNL and its major programs by growing new program areas and cutting-edge capabilities that are synergistic with, and supportive of, its national security mission; (3) Provide a direct conduit to the academic and high-tech industrial sectors for LLNL and its national security programs, through which the Laboratory gains access to frontier science and technology, and can impact the science and technology communities; (4) Leverage unique Laboratory capabilities, to advance the state universe. This inaugural PAT Annual Report begins a series that will chronicle our progress towards fulfilling this mission. I believe the report demonstrates that the PAT Directorate has a strong base of capabilities and accomplishments on which to build in meeting its goals. Some of the highlights

  8. Advances in nuclear science and technology

    CERN Document Server

    Henley, Ernest J

    1962-01-01

    Advances in Nuclear Science and Technology, Volume 1 provides an authoritative, complete, coherent, and critical review of the nuclear industry. This book covers a variety of topics, including nuclear power stations, graft polymerization, diffusion in uranium alloys, and conventional power plants.Organized into seven chapters, this volume begins with an overview of the three stages of the operation of a power plant, either nuclear or conventionally fueled. This text then examines the major problems that face the successful development of commercial nuclear power plants. Other chapters consider

  9. Advances in nuclear science and technology

    CERN Document Server

    Henley, Ernest J

    1975-01-01

    Advances in Nuclear Science and Technology, Volume 8 discusses the development of nuclear power in several countries throughout the world. This book discusses the world's largest program of land-based electricity production in the United States.Organized into six chapters, this volume begins with an overview of the phenomenon of quasi-exponential behavior by examining two mathematical models of the neutron field. This text then discusses the finite element method, which is a method for obtaining approximate solutions to integral or differential equations. Other chapters consider the status of

  10. Recent Advances in Robust Speech Recognition Technology

    CERN Document Server

    Ramírez, Javier

    2011-01-01

    This E-book is a collection of articles that describe advances in speech recognition technology. Robustness in speech recognition refers to the need to maintain high speech recognition accuracy even when the quality of the input speech is degraded, or when the acoustical, articulate, or phonetic characteristics of speech in the training and testing environments differ. Obstacles to robust recognition include acoustical degradations produced by additive noise, the effects of linear filtering, nonlinearities in transduction or transmission, as well as impulsive interfering sources, and diminishe

  11. CENTER FOR ADVANCED SEPARATION TECHNOLOGY (CAST) PROGRAM

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Roe-Hoan; Hull, Christopher

    2014-09-30

    The U.S. is the largest producer of mining products in the world. In 2011, U.S. mining operations contributed a total of $232 billion to the nation’s GDP plus $138 billion in labor income. Of this the coal mining industry contributed a total of $97.5 billion to GDP plus $53 billion in labor income. Despite these contributions, the industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations.

  12. Systematic Discrimination of Advanced Hydrogen Production Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Charles V. Park; Michael W. Patterson

    2010-07-01

    The U.S. Department of Energy, in concert with industry, is developing a high-temperature gas-cooled reactor at the Idaho National Laboratory (INL) to demonstrate high temperature heat applications to produce hydrogen and electricity or to support other industrial applications. A key part of this program is the production of hydrogen from water that would significantly reduce carbon emissions compared to current production using natural gas. In 2009 the INL led the methodical evaluation of promising advanced hydrogen production technologies in order to focus future resources on the most viable processes. This paper describes how the evaluation process was systematically planned and executed. As a result, High-Temperature Steam Electrolysis was selected as the most viable near-term technology to deploy as a part of the Next Generation Nuclear Plant Project.

  13. ADVANCED TECHNOLOGIES FOR STRIPPER GAS WELL ENHANCEMENT

    International Nuclear Information System (INIS)

    As part of Task 1 in Advanced Technologies for Stripper Gas Well Enhancement, Schlumberger-Holditch Reservoir Technologies (H-RT) has joined with two Appalachian Basin producers, Great Lakes Energy Partners, LLC, and Belden and Blake Corporation to develop methodologies for identification and enhancement of stripper wells with economic upside potential. These industry partners have provided us with data for more than 700 wells in northwestern Pennsylvania. Phase 1 goals of this project are to develop and validate methodologies that can quickly and cost-effectively identify wells with enhancement potential. We have continued to enhance and streamline our software, and we are testing the final stages of our new Microsoft(trademark) Access/Excel based software. We are continuing to process this well data and are identifying potential candidate wells that can be used in Phase 2 to validate the new methodologies. In addition, preparation of the final technical report is underway

  14. Advances in material capsule technology in HANARO

    International Nuclear Information System (INIS)

    A material capsule system has been developed for irradiation tests of non-fissile materials in HANARO. This capsule system has been actively utilized for various material irradiation tests requested by users from research institutes, universities, and the industries. Based on the accumulated experience and the user's sophisticated requirements, several advances in material capsule technologies were obtained recently for a more precise control and analysis of the neutron irradiation effect in HANARO. New instrumented capsule technologies for a more precise control of the irradiation temperature and fluence of a specimen, irrespective of the reactor operation, have been developed and out-pile tested. The OR/IP capsule technologies for an irradiation test in the HANARO OR and IP test holes with a relatively lower neutron flux than the CT and IR test holes have also been developed and in-pile tested, successfully. A high temperature irradiation technology up to 1000degC is under development. An evaluation of the DPA (Displacement Per Atom) and activation of irradiated specimens was attempted by using the SPECTOR and ORIGEN2 codes, respectively. A new fluence monitor with a decreased activity was designed to measure the thermal and fast neutron fluences of the irradiated specimens. A friction welded tube using STS304 and Al1050 alloys was introduced to prevent a coolant leakage into a capsule during a capsule cutting process after an irradiation. (author)

  15. Advances in material capsule technology in HANARO

    International Nuclear Information System (INIS)

    A material capsule system has been developed for irradiation tests of non fissile materials in HANARO. This capsule system has been actively utilized for various material irradiation tests requested by users from research institutes, universities, and the industries. Based on the accumulated experience and the user's sophisticated requirements, several advances in material capsule technologies were obtained recently for a more precise control and analysis of the neutron irradiation effect in HANARO. New instrumented capsule technologies for a more precise control of the irradiation temperature and fluence of a specimen, irrespective of the reactor operation, have been developed and out pile tested. The OR/IP capsule technologies for an irradiation test in the HANARO OR and IP test holes with a relatively lower neutron flux than the CT and IR test holes have also been developed and in pile tested, successfully. A high temperature irradiation technology up to 1000 .deg. C is under development. An evaluation of the DPA (Displacement Per Atom) and activation of irradiated specimens was attempted by using the SPECTOR and ORIGEN2 codes, respectively. A new fluence monitor with a decreased activity was designed to measure the thermal and fast neutron fluences of the irradiated specimens. A friction welded tube using STS304 and Al1050 alloys was introduced to prevent a coolant leakage into a capsule during a capsule cutting process after an irradiation

  16. Advanced technologies for power and fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Watts, J.U.; Mann, A.N. [US Department of Energy/National Energy Technology Lab., Pittsburgh, PA (United States)

    2001-07-01

    The Clean Coal Technology Program (CCT) being conducted by the United States Department of Energy (DOE) is a government and industry co-funded effort. The program's purpose is to demonstrate new generation of innovative, environmentally friendly processes that enhance the utilization of coal to meet increasing demand for electric power and fuels. Program demonstration areas include environmental control, advanced power generation, fuels production, and industrial applications. The CCT Program has now grown to maturity, with over 50% of the projects selected having successfully completed their demonstration goals and objectives. Under the CCT Program, nine advanced electric power generation projects and five coal processing for clean fuels projects were selected for full scale commercial demonstration. This paper provides the status, accomplishments and results of the most widely accepted technologies currently being commercialized under these two categories. The projects are (1) Atmospheric Fluidized-Bed Combustion (AFBC) at Jacksonville Electric Authority; (2) Integrated Gasification Combined-cycle (IGCC) at Wabash River, Tampa Electric and Kentucky Pioneer; and (3) Eastman Chemical's production of methanol via coal gasification using the LPMEOH{trademark} process. 7 figs., 7 tabs.

  17. Advancement in Textile Technology for Defence Application

    Directory of Open Access Journals (Sweden)

    Balasubramanian Kandasubramanian

    2013-05-01

    Full Text Available The early development of textiles involved use of natural materials like cotton, wool and flax. The advent of the new technology revolutionized textiles which enables to develop synthetic fibers like lycra®, a segmented polyurethane-urea, which has exceptional elastic properties, Kevlar®, which has ultra high strength properties and is used as bulletproof vest. For the improvement of personal mobility, health care and rehabilitation, it requires to integrate novel sensing and actuating functions to textiles. Fundamental challenge in the development of smart textile is that drapability and manufacturability of smart textiles should not be affected. Textile fabrics embedded with sensors, piezoelectric materials, flame retardant materials, super hydrophobic materials, controlled drug release systems and temperature adaptable materials can play major role in the development of advanced and high-tech military clothes. Advancement in the textile materials has the capacity of improving comfort, mobility and protection in diverse hostile environment. In this study, the advancement in energy harvesting textiles, controlled release textiles and engineering textiles are presented.Defence Science Journal, 2013, 63(3, pp.331-339, DOI:http://dx.doi.org/10.14429/dsj.63.2756

  18. Advancement in Textile Technology for Defence Application

    Directory of Open Access Journals (Sweden)

    Ramdayal

    2013-05-01

    Full Text Available The early development of textiles involved use of natural materials like cotton, wool and flax. The advent of the new technology revolutionized textiles which enables to develop synthetic fibers like lycra®, a segmented polyurethane-urea, which has exceptional elastic properties, Kevlar®, which has ultra high strength properties and is used as bulletproof vest. For the improvement of personal mobility, health care and rehabilitation, it requires to integrate novel sensing and actuating functions to textiles. Fundamental challenge in the development of smart textile is that drapability and manufacturability of smart textiles should not be affected. Textile fabrics embedded with sensors, piezoelectric materials, flame retardant materials, super hydrophobic materials, controlled drug release systems and temperature adaptable materials can play major role in the development of advanced and high-tech military clothes. Advancement in the textile materials has the capacity of improving comfort, mobility and protection in diverse hostile environment. In this study, the advancement in energy harvesting textiles, controlled release textiles and engineering textiles are presented.

  19. Advanced fuel technology - A UK perspective

    International Nuclear Information System (INIS)

    The nuclear power industry in the United Kingdom is perhaps more diverse than in any other country. The diversity in design of stations is matched by a diversity in operating responsibility. The SGHWR and PFR are operated by the United Kingdom Atomic Energy Authority (UKAEA), 2 of the Magnox stations are owned and run by BNFL, 2 of the AGR stations and 1 Magnox station are controlled by the South of Scotland Electricity Board (SSEB), and the remaining reactors (including the Sizewell 'B' PWR) currently come under the responsibility of the Central Electricity Generating Board (CEGB) but will pass into the control of a new state-run company when the rest of the CEGB is privatized in 1990. Against this background of a variety of designs and operational responsibilities, there is clearly a great deal of scope for advances in fuel and fuel component technology. It should be noted, however, that the nuclear energy policy within the United Kingdom, particularly with regard to PWR plants, has been to adopt well proven designs wherever possible. Emphasis is therefore directed towards achieving the successful operation of conservative systems, with research and development work on advanced options for future implementation. The following sections give an overview of the areas where advanced designs are either in production or under development for each of the UK reactor systems in turn, together with an indication of possible future developments

  20. Gas-to-liquid technologies: India's perspective

    International Nuclear Information System (INIS)

    Gas-to-liquid (GTL) technologies are capable of converting gas to clean, useful liquid hydrocarbons and thus suitable for addressing problems of remote gas utilization, increase in crude oil price, depletion of fossil fuel and environmental pollution. The Indian state of Tripura is considered to be the richest province with 26 billion cubic meters of gas reserves. Neighboring country Myanmar has huge gas reserves but these reserves remain unutilized mainly because of land-locked situation. GTL is a well developed and proven technology and it is an important option for moving natural gas to the market place. GTL options include not only the well-known production of Fischer-Tropsch synthesis liquids but also the production of oxygen containing fuels, fuel additives and chemicals, such as methanol and DME. An alternative, promising option to convert surplus gas is the direct route of methane conversion, which is more energy efficient than the indirect route since it bypasses the energy intensive endothermic steam reforming step of syngas formation. On-site conversion to liquid products of commercial importance using direct route would make transportation of these natural deposits much more economical and practical. In this paper an attempt has been made to review recent developments in syngas technologies, direct routes of methane conversion into useful liquids, and status of both existing and future developments in GTL industry around the world. Finally challenges in GTL technology are discussed. (author)

  1. Advances in riser and pipeline technologies

    Energy Technology Data Exchange (ETDEWEB)

    Kan, Wan C.; Mortazavi, Mehrdad; Weir, Michael S. [ExxonMobil Development Company, Dallas, TX (United States)

    2009-12-19

    As oil and gas production continues to move into new frontier areas, novel applications of the existing riser and pipeline technologies need to be developed to meet the often more stringent requirements encountered in these environments. The challenges include ultra deep water, harsh environments, aggressive fluid conditions, and local content objectives, etc. They will require industry to constantly extend, expand, and enhance the broad range of solution options. Also, the existing design criteria in industry may need to be revised or new criteria may need to be developed to satisfy these needs. Exxon Mobil (Em) employs, and works with others in industry to promote robust design and operating practices. This approach requires in-depth understanding, sound engineering principles, advanced analysis, uncertainty management, and supportive qualification test data. It enables confident selection, extrapolation, and innovation of technologies to address new riser system and pipeline challenges. Focus on fundamental is imperative to ensure integrity of the selected systems during fabrication, installation, and operation phases. Recent and past project experience in deep water Gulf of Mexico and West Africa provides many successful examples of this approach. This paper reviews several examples of the key riser system and pipeline technology enhancements recently achieved by EM to provide confidence in addressing technical and project application challenges. Riser system technology enhancements addressed in this paper include steel catenary riser (SCR) application on turret-moored FPSO with severe motions, pipe-in-pipe (PIP) hybrid production riser to effectively manage gas lift and flow assurance requirements, irregular wave analysis methodology for flexible risers and umbilicals to reduce conservatism, and qualification of riser and pipeline VIV prediction and mitigation methods. Pipeline technology enhancements detailed in this paper include lateral buckling prediction

  2. CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Christopher E. Hull

    2005-01-20

    The U.S. is the largest producer of mining products in the world. In 2003, U.S. mining operations produced $57 billion worth of raw materials that contributed a total of $564 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (1) Solid-solid separation; (2) Solid-liquid separation; (3) Chemical/Biological Extraction; (4) Modeling and Control; and (5) Environmental Control.

  3. Crosscutting Technology Development at the Center for Advanced Separation Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Christopher Hull

    2009-10-31

    The U.S. is the largest producer of mining products in the world. In 2003, U.S. mining operations produced $57 billion worth of raw materials that contributed a total of $564 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Originally set up by Virginia Tech and West Virginia University, this endeavor has been expanded into a seven-university consortium -- Virginia Tech, West Virginia University, University of Kentucky, University of Utah, Montana Tech, New Mexico Tech and University of Nevada, Reno - that is supported through U.S. DOE Cooperative Agreement No. DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (1) Solid-solid separation; (2) Solid-liquid separation; (3) Chemical/biological extraction; (4) Modeling and control; and (5) Environmental control. Distribution of funds is handled via competitive solicitation of research proposals through Site Coordinators at the seven member universities. These were first reviewed and ranked by a group of technical reviewers (selected primarily from industry). Based on these reviews, and an assessment of overall program requirements, the CAST Technical Committee made an initial selection/ranking of proposals and forwarded these to the DOE/NETL Project Officer for final review and approval. The successful projects are listed by category, along with brief abstracts of their aims and objectives.

  4. ADVANCED TECHNOLOGIES FOR STRIPPER GAS WELL ENHANCEMENT

    International Nuclear Information System (INIS)

    As part of Task 1 in Advanced Technologies for Stripper Gas Well Enhancement, Schlumberger-Holditch Reservoir Technologies (H-RT) has joined with two Appalachian Basin producers, Great Lakes Energy Partners, LLC, and Belden and Blake Corporation to develop methodologies for identification and enhancement of stripper wells with economic upside potential. These industry partners have provided us with data for more than 700 wells in northwestern Pennsylvania. Phase 1 goals of this project are to develop and validate methodologies that can quickly and cost-effectively identify wells with enhancement potential. We have continued to enhance and streamline our software, and we are testing the final stages of our new Microsoft(trademark) Access/Excel based software. We are continuing to process the information and are identifying potential candidate wells that can be used in Phase 2 to validate the new methodologies. In addition, preparation of the final technical report is underway. During this quarter, we have presented our project and discussed the software to numerous Petroleum Technology Transfer Council (PTTC) workshops located in various regions of the United States

  5. Advanced PWR technology development -Development of advanced PWR system analysis technology-

    Energy Technology Data Exchange (ETDEWEB)

    Jang, Moon Heui; Hwang, Yung Dong; Kim, Sung Oh; Yoon, Joo Hyun; Jung, Bub Dong; Choi, Chul Jin; Lee, Yung Jin; Song, Jin Hoh [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1995-07-01

    The primary scope of this study is to establish the analysis technology for the advanced reactor designed on the basis of the passive and inherent safety concepts. This study is extended to the application of these technology to the safety analysis of the passive reactor. The study was performed for the small and medium sized reactor and the large sized reactor by focusing on the development of the analysis technology for the passive components. Among the identified concepts the once-through steam generator, the natural circulation of the integral reactor, heat pipe for containment cooling, and hydraulic valve were selected as the high priority items to be developed and the related studies are being performed for these items. For the large sized passive reactor, the study plans to extend the applicability of the best estimate computer code RELAP5/MOD3 which is widely used for the safety analyses of the reactor system. The improvement and supplementation study of the analysis modeling and the methodology is planned to be carried out for these purpose. The newly developed technologies are expected to be applied to the domestic advanced reactor design and analysis and these technologies will play a key role in extending the domestic nuclear base technology and consolidating self-reliance in the essential nuclear technology. 72 figs, 15 tabs, 124 refs. (Author).

  6. NASA's Advanced Information Systems Technology (AIST) Program: Advanced Concepts and Disruptive Technologies

    Science.gov (United States)

    Little, M. M.; Moe, K.; Komar, G.

    2014-12-01

    NASA's Earth Science Technology Office (ESTO) manages a wide range of information technology projects under the Advanced Information Systems Technology (AIST) Program. The AIST Program aims to support all phases of NASA's Earth Science program with the goal of enabling new observations and information products, increasing the accessibility and use of Earth observations, and reducing the risk and cost of satellite and ground based information systems. Recent initiatives feature computational technologies to improve information extracted from data streams or model outputs and researchers' tools for Big Data analytics. Data-centric technologies enable research communities to facilitate collaboration and increase the speed with which results are produced and published. In the future NASA anticipates more small satellites (e.g., CubeSats), mobile drones and ground-based in-situ sensors will advance the state-of-the-art regarding how scientific observations are performed, given the flexibility, cost and deployment advantages of new operations technologies. This paper reviews the success of the program and the lessons learned. Infusion of these technologies is challenging and the paper discusses the obstacles and strategies to adoption by the earth science research and application efforts. It also describes alternative perspectives for the future program direction and for realizing the value in the steps to transform observations from sensors to data, to information, and to knowledge, namely: sensor measurement concepts development; data acquisition and management; data product generation; and data exploitation for science and applications.

  7. Advanced PWR technology development -Development of advanced PWR system analysis technology-

    International Nuclear Information System (INIS)

    The primary scope of this study is to establish the analysis technology for the advanced reactor designed on the basis of the passive and inherent safety concepts. This study is extended to the application of these technology to the safety analysis of the passive reactor. The study was performed for the small and medium sized reactor and the large sized reactor by focusing on the development of the analysis technology for the passive components. Among the identified concepts the once-through steam generator, the natural circulation of the integral reactor, heat pipe for containment cooling, and hydraulic valve were selected as the high priority items to be developed and the related studies are being performed for these items. For the large sized passive reactor, the study plans to extend the applicability of the best estimate computer code RELAP5/MOD3 which is widely used for the safety analyses of the reactor system. The improvement and supplementation study of the analysis modeling and the methodology is planned to be carried out for these purpose. The newly developed technologies are expected to be applied to the domestic advanced reactor design and analysis and these technologies will play a key role in extending the domestic nuclear base technology and consolidating self-reliance in the essential nuclear technology. 72 figs, 15 tabs, 124 refs. (Author)

  8. Advanced Education and Technology Business Plan, 2010-13. Highlights

    Science.gov (United States)

    Alberta Advanced Education and Technology, 2010

    2010-01-01

    The Ministry of Advanced Education and Technology envisions Alberta's prosperity through innovation and lifelong learning. Advanced Education and Technology's mission is to lead the development of a knowledge-driven future through a dynamic and integrated advanced learning and innovation system. This paper presents the highlights of the business…

  9. Technological advances in electrospinning of nanofibers

    Directory of Open Access Journals (Sweden)

    Wee-Eong Teo, Ryuji Inai and Seeram Ramakrishna

    2011-01-01

    Full Text Available Progress in the electrospinning techniques has brought new methods for the production and construction of various nanofibrous assemblies. The parameters affecting electrospinning include electrical charges on the emerging jet, charge density and removal, as well as effects of external perturbations. The solvent and the method of fiber collection also affect the construction of the final nanofibrous architecture. Various techniques of yarn spinning using solid and liquid surfaces as well as surface-free collection are described and compared in this review. Recent advances allow production of 3D nanofibrous scaffolds with a desired microstructure. In the area of tissue regeneration and bioengineering, 3D scaffolds should bring nanofibrous technology closer to clinical applications. There is sufficient understanding of the electrospinning process and experimental results to suggest that precision electrospinning is a real possibility.

  10. Advanced information technology: Building stronger databases

    Energy Technology Data Exchange (ETDEWEB)

    Price, D. [Lawrence Livermore National Lab., CA (United States)

    1994-12-01

    This paper discusses the attributes of the Advanced Information Technology (AIT) tool set, a database application builder designed at the Lawrence Livermore National Laboratory. AIT consists of a C library and several utilities that provide referential integrity across a database, interactive menu and field level help, and a code generator for building tightly controlled data entry support. AIT also provides for dynamic menu trees, report generation support, and creation of user groups. Composition of the library and utilities is discussed, along with relative strengths and weaknesses. In addition, an instantiation of the AIT tool set is presented using a specific application. Conclusions about the future and value of the tool set are then drawn based on the use of the tool set with that specific application.

  11. Advanced monolithic pixel sensors using SOI technology

    Science.gov (United States)

    Miyoshi, Toshinobu; Arai, Yasuo; Asano, Mari; Fujita, Yowichi; Hamasaki, Ryutaro; Hara, Kazuhiko; Honda, Shunsuke; Ikegami, Yoichi; Kurachi, Ikuo; Mitsui, Shingo; Nishimura, Ryutaro; Tauchi, Kazuya; Tobita, Naoshi; Tsuboyama, Toru; Yamada, Miho

    2016-07-01

    We are developing advanced pixel sensors using silicon-on-insulator (SOI) technology. A SOI wafer is used; top silicon is used for electric circuit and bottom silicon is used as a sensor. Target applications are high-energy physics, X-ray astronomy, material science, non-destructive inspection, medical application and so on. We have developed two integration-type pixel sensors, FPIXb and INTPIX7. These sensors were processed on single SOI wafers with various substrates in n- or p-type and double SOI wafers. The development status of double SOI sensors and some up-to-date test results of n-type and p-type SOI sensors are shown.

  12. Sustainability assessment of advanced wastewater treatment technologies

    DEFF Research Database (Denmark)

    Høibye, Linda; Clauson-Kaas, Jes; Wenzel, Henrik;

    2007-01-01

    As a consequence of the EU Water Framwork Directive, more focus is now on discharges of hazardous substances from wastewater treatment plants and sewers. Thus, many municipalities in Denmark may have to adopt to future advenced treatment technologies. This paper describes a holistic assessment...... with advanced oxidation. The technical assessment is based on 12 hazardous substances comprising heavy metals, organic pollutants, endocrine disruptors as well as pathogenic microorganisms. The environmental assessment is performed by life cycle assessment (LCA) comprising 9 of the specific hazardous substances...... of sustainability, sand filtration is the most advantageous method based on the technical and environmental assessment due to the low energy consumption and high efficiency with regard to the removal of heavy metals....

  13. Nanoporous metals for advanced energy technologies

    CERN Document Server

    Ding, Yi

    2016-01-01

    This book covers the state-of-the-art research in nanoporous metals for potential applications in advanced energy fields, including proton exchange membrane fuel cells, Li batteries (Li ion, Li-S, and Li-O2), and supercapacitors. The related structural design and performance of nanoporous metals as well as possible mechanisms and challenges are fully addressed. The formation mechanisms of nanoporous metals during dealloying, the microstructures of nanoporous metals and characterization methods, as well as miscrostructural regulation of nanoporous metals through alloy design of precursors and surface diffusion control are also covered in detail. This is an ideal book for researchers, engineers, graduate students, and government/industry officers who are in charge of R&D investments and strategy related to energy technologies.

  14. Advancing colloidal quantum dot photovoltaic technology

    Science.gov (United States)

    Cheng, Yan; Arinze, Ebuka S.; Palmquist, Nathan; Thon, Susanna M.

    2016-06-01

    Colloidal quantum dots (CQDs) are attractive materials for solar cells due to their low cost, ease of fabrication and spectral tunability. Progress in CQD photovoltaic technology over the past decade has resulted in power conversion efficiencies approaching 10%. In this review, we give an overview of this progress, and discuss limiting mechanisms and paths for future improvement in CQD solar cell technology.We briefly summarize nanoparticle synthesis and film processing methods and evaluate the optoelectronic properties of CQD films, including the crucial role that surface ligands play in materials performance. We give an overview of device architecture engineering in CQD solar cells. The compromise between carrier extraction and photon absorption in CQD photovoltaics is analyzed along with different strategies for overcoming this trade-off. We then focus on recent advances in absorption enhancement through innovative device design and the use of nanophotonics. Several light-trapping schemes, which have resulted in large increases in cell photocurrent, are described in detail. In particular, integrating plasmonic elements into CQD devices has emerged as a promising approach to enhance photon absorption through both near-field coupling and far-field scattering effects. We also discuss strategies for overcoming the single junction efficiency limits in CQD solar cells, including tandem architectures, multiple exciton generation and hybrid materials schemes. Finally, we offer a perspective on future directions for the field and the most promising paths for achieving higher device efficiencies.

  15. Advanced Life Support Technologies and Scenarios

    Science.gov (United States)

    Barta, Daniel J.

    2011-01-01

    As NASA looks beyond the International Space Station toward long-duration, deep space missions away from Earth, the current practice of supplying consumables and spares will not be practical nor affordable. New approaches are sought for life support and habitation systems that will reduce dependency on Earth and increase mission sustainability. To reduce launch mass, further closure of Environmental Control and Life Support Systems (ECLSS) beyond the current capability of the ISS will be required. Areas of particular interest include achieving higher degrees of recycling within Atmosphere Revitalization, Water Recovery and Waste Management Systems. NASA is currently investigating advanced carbon dioxide reduction processes that surpass the level of oxygen recovery available from the Sabatier Carbon Dioxide Reduction Assembly (CRA) on the ISS. Improving the efficiency of the recovery of water from spacecraft solid and liquid wastes is possible through use of emerging technologies such as the heat melt compactor and brine dewatering systems. Another significant consumable is that of food. Food production systems based on higher plants may not only contribute significantly to the diet, but also contribute to atmosphere revitalization, water purification and waste utilization. Bioreactors may be potentially utilized for wastewater and solid waste management. The level at which bioregenerative technologies are utilized will depend on their comparative requirements for spacecraft resources including mass, power, volume, heat rejection, crew time and reliability. Planetary protection requirements will need to be considered for missions to other solar system bodies.

  16. Advanced Technology for Isolating Payloads in Microgravity

    Science.gov (United States)

    Alhorn, Dean C.

    1997-01-01

    advances in isolation technology for that particular component. The final section presents some concluding thoughts and a summary of anticipated advances in research and development for isolating microgravity experiments.

  17. ADVANCED RECIPROCATING COMPRESSION TECHNOLOGY (ARCT). FINAL REPORT

    International Nuclear Information System (INIS)

    The U.S. natural gas pipeline industry is facing the twin challenges of increased flexibility and capacity expansion. To meet these challenges, the industry requires improved choices in gas compression to address new construction and enhancement of the currently installed infrastructure. The current fleet of installed reciprocating compression is primarily slow-speed integral machines. Most new reciprocating compression is and will be large, high-speed separable units. The major challenges with the fleet of slow-speed integral machines are: limited flexibility and a large range in performance. In an attempt to increase flexibility, many operators are choosing to single-act cylinders, which are causing reduced reliability and integrity. While the best performing units in the fleet exhibit thermal efficiencies between 90% and 92%, the low performers are running down to 50% with the mean at about 80%. The major cause for this large disparity is due to installation losses in the pulsation control system. In the better performers, the losses are about evenly split between installation losses and valve losses. The major challenges for high-speed machines are: cylinder nozzle pulsations, mechanical vibrations due to cylinder stretch, short valve life, and low thermal performance. To shift nozzle pulsation to higher orders, nozzles are shortened, and to dampen the amplitudes, orifices are added. The shortened nozzles result in mechanical coupling with the cylinder, thereby, causing increased vibration due to the cylinder stretch mode. Valve life is even shorter than for slow speeds and can be on the order of a few months. The thermal efficiency is 10% to 15% lower than slow-speed equipment with the best performance in the 75% to 80% range. The goal of this advanced reciprocating compression program is to develop the technology for both high speed and low speed compression that will expand unit flexibility, increase thermal efficiency, and increase reliability and integrity

  18. The Complete Picture: "Standards for Technological Literacy" and "Advancing Excellence in Technological Literacy."

    Science.gov (United States)

    Technology Teacher, 2003

    2003-01-01

    Provides an overview of the "Standards for Technological Literacy: Content for the Study of Technology" (STL) and "Advancing Excellence in Technological Literacy: Student Assessment, Professional Development, and Program Standards" (AETL). Shows how the documents work together to advance the technological literacy of technology educators and K-12…

  19. The ACTS Flight System - Cost-Effective Advanced Communications Technology. [Advanced Communication Technology Satellite

    Science.gov (United States)

    Holmes, W. M., Jr.; Beck, G. A.

    1984-01-01

    The multibeam communications package (MCP) for the Advanced Communications Technology Satellite (ACTS) to be STS-launched by NASA in 1988 for experimental demonstration of satellite-switched TDMA (at 220 Mbit/sec) and baseband-processor signal routing (at 110 or 27.5 Mbit/sec) is characterized. The developmental history of the ACTS, the program definition, and the spacecraft-bus and MCP parameters are reviewed and illustrated with drawings, block diagrams, and maps of the coverage plan. Advanced features of the MPC include 4.5-dB-noise-figure 30-GHz FET amplifiers and 20-GHz TWTA transmitters which provide either 40-W or 8-W RF output, depending on rain conditions. The technologies being tested in ACTS can give frequency-reuse factors as high as 20, thus greatly expanding the orbit/spectrum resources available for U.S. communications use.

  20. Advanced Technology MEMS-based Acoustic Array Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Interdisciplinary Consulting Corporation proposes a technological advancement of current state-of-the-art acoustic energy harvester for harsh environment...

  1. Coal liquefaction and gas conversion: Proceedings. Volume 2

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-31

    Volume II contains papers presented at the following sessions: Indirect Liquefaction (oxygenated fuels); and Indirect Liquefaction (Fischer-Tropsch technology). Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  2. Recent advances in airborne radiometric technology

    International Nuclear Information System (INIS)

    Since its inception, the DOE Remote Sensing Laboratory has made dramatic innovations in airborne radiometric technology. In the past few years there have been at least four major changes in operational philosophy. (1) The helicopter is now the prime radiation survey vehicle. Surveys are conducted at low speed and low altitude, with lines spaced only a few hundred feet apart. Radiation anomalies and subtle changes in background can be readily identified. (2) Much greater emphasis is now placed on accurate, detailed analysis and interpretation of radiation data. Dramatic improvements in survey hardware and software provide much more data of considerably better quality. (3) Recent Laboratory research has been concentrated on error-free, positive identification of point radiation sources. In the past, the extent and magnitude of dispersed sources were the major concerns. (4) Integrated remote sensing has been strongly emphasized at the Laboratory in recent years. This involves the simultaneous use of radiation detectors, aerial cameras, and the multispectral scanner imagery. The synergistic effects of such data correlation are of significantly greater value in analyzing the terrestrial environment. Many of the changes in operational philosophy are directly traceable to new or dramatically improved hardware and software employed at the Laboratory. Six items have been instrumental in the above technological advances: (1) the UHF Transponder System and its predecessor, the Microwave Ranging System; (2) Model IC of the REDAR data acquisition system; (3) the development of the search algorithm; (4) continued improvements in the REDACA data analysis system; (5) deployment of polyscin sodium iodide radiation detectors; and (6) development of the Graphic Overview System

  3. Physics and Advanced Technologies 2003 Annual Report

    Energy Technology Data Exchange (ETDEWEB)

    Hazi, A; Sketchley, J

    2005-01-20

    The Physics and Advanced Technologies (PAT) Directorate overcame significant challenges in 2003 to deliver a wealth of scientific and programmatic milestones, and move toward closer alignment with programs at Lawrence Livermore National Laboratory. We acted aggressively in enabling the PAT Directorate to contribute to future, growing Lawrence Livermore missions in homeland security and at the National Ignition Facility (NIF). We made heavy investments to bring new capabilities to the Laboratory, to initiate collaborations with major Laboratory programs, and to align with future Laboratory directions. Consistent with our mission, we sought to ensure that Livermore programs have access to the best science and technology, today and tomorrow. For example, in a move aimed at revitalizing the Laboratory's expertise in nuclear and radiation detection, we brought the talented Measurement Sciences Group to Livermore from Lawrence Berkeley National Laboratory, after its mission there had diminished. The transfer to our I Division entailed significant investment by PAT in equipment and infrastructure required by the group. In addition, the move occurred at a time when homeland security funding was expected, but not yet available. By the end of the year, though, the group was making crucial contributions to the radiation detection program at Livermore, and nearly every member was fully engaged in programmatic activities. Our V Division made a move of a different sort, relocating en masse from Building 121 to the NIF complex. This move was designed to enhance interaction and collaboration among high-energy-density experimental scientists at the Laboratory, a goal that is essential to the effective use of NIF in the future. Since then, V Division has become increasingly integrated with NIF activities. Division scientists are heavily involved in diagnostic development and fielding and are poised to perform equation-of-state and high-temperature hohlraum experiments in 2004

  4. Institute for Advanced Learning and Research receives Governor's Technology Award

    OpenAIRE

    Callaway, Curtis

    2006-01-01

    The Institute for Advanced Learning and Research (IALR) received a Governor's Technology Award on September 11 at the Commonwealth of Virginia Innovative Technology Symposium (COVITS) 2006 held in Roanoke.

  5. Radioactive waste management and advanced nuclear fuel cycle technologies

    International Nuclear Information System (INIS)

    In 2007 ENEA's Department of Nuclear Fusion and Fission, and Related Technologies acted according to national policy and the role assigned to ENEA FPN by Law 257/2003 regarding radioactive waste management and advanced nuclear fuel cycle technologies

  6. Current Advancements in Wireless Communication Technology

    Directory of Open Access Journals (Sweden)

    Md Touseef Sumer*1,

    2014-01-01

    Full Text Available Wireless communication is the transfer of any information over some distance without the use of wires. Radio, or the use of radiated electromagnetic waves, is the only practical way of communicating with people or vehicles that move around on land, on the sea, in the air, or in outer space. It is the use of electromagnetic waves that permits the transmission and reception of information over a distance without the use of wires. Market demands for higher cellular density in urban areas, broadband internet wireless, and better data security, while using a minimum amount of frequency spectrum is driving wireless developments forward at an amazing speed. The evolution of wireless communications from analog to digital to broadband has taken longer and cost more money than most industry observers believed. At the same time WLAN “hotspots” are emerging rapidly. At present, the major applications of Wireless communication are Wi-Fi, WiMax and ZigBee. This paper gives an overview of some of the current advancements in Wireless Communication technology.

  7. Advanced ignition and propulsion technology program

    Energy Technology Data Exchange (ETDEWEB)

    Oldenborg, R.; Early, J.; Lester, C.

    1998-11-01

    This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). Reliable engine re-ignition plays a crucial role in enabling commercial and military aircraft to fly safely at high altitudes. This project addressed research elements critical to the optimization of laser-based igniter. The effort initially involved a collaborative research and development agreement with B.F. Goodrich Aerospace and Laser Fare, Inc. The work involved integrated experiments with theoretical modeling to provide a basic understanding of the chemistry and physics controlling the laser-induced ignition of fuel aerosols produced by turbojet engine injectors. In addition, the authors defined advanced laser igniter configurations that minimize laser packaging size, weight, complexity and power consumption. These innovative ignition concepts were shown to reliably ignite jet fuel aerosols over a broad range of fuel/air mixture and a t fuel temperatures as low as -40 deg F. The demonstrated fuel ignition performance was highly superior to that obtained by the state-of-the-art, laser-spark ignition method utilizing comparable laser energy. The authors also developed a laser-based method that effectively removes optically opaque deposits of fuel hydrocarbon combustion residues from laser window surfaces. Seven patents have been either issued or are pending that resulted from the technology developments within this project.

  8. Systemization of Design and Analysis Technology for Advanced Reactor

    International Nuclear Information System (INIS)

    The present study is performed to establish the base for the license application of the original technology by systemization and enhancement of the technology that is indispensable for the design and analysis of the advanced reactors including integral reactors. Technical reports and topical reports are prepared for this purpose on some important design/analysis methodology; design and analysis computer programs, structural integrity evaluation of main components and structures, digital I and C systems and man-machine interface design. PPS design concept is complemented reflecting typical safety analysis results. And test plans and requirements are developed for the verification of the advanced reactor technology. Moreover, studies are performed to draw up plans to apply to current or advanced power reactors the original technologies or base technologies such as patents, computer programs, test results, design concepts of the systems and components of the advanced reactors. Finally, pending issues are studied of the advanced reactors to improve the economics and technology realization

  9. Advanced Technology Lifecycle Analysis System (ATLAS)

    Science.gov (United States)

    O'Neil, Daniel A.; Mankins, John C.

    2004-01-01

    Developing credible mass and cost estimates for space exploration and development architectures require multidisciplinary analysis based on physics calculations, and parametric estimates derived from historical systems. Within the National Aeronautics and Space Administration (NASA), concurrent engineering environment (CEE) activities integrate discipline oriented analysis tools through a computer network and accumulate the results of a multidisciplinary analysis team via a centralized database or spreadsheet Each minute of a design and analysis study within a concurrent engineering environment is expensive due the size of the team and supporting equipment The Advanced Technology Lifecycle Analysis System (ATLAS) reduces the cost of architecture analysis by capturing the knowledge of discipline experts into system oriented spreadsheet models. A framework with a user interface presents a library of system models to an architecture analyst. The analyst selects models of launchers, in-space transportation systems, and excursion vehicles, as well as space and surface infrastructure such as propellant depots, habitats, and solar power satellites. After assembling the architecture from the selected models, the analyst can create a campaign comprised of missions spanning several years. The ATLAS controller passes analyst specified parameters to the models and data among the models. An integrator workbook calls a history based parametric analysis cost model to determine the costs. Also, the integrator estimates the flight rates, launched masses, and architecture benefits over the years of the campaign. An accumulator workbook presents the analytical results in a series of bar graphs. In no way does ATLAS compete with a CEE; instead, ATLAS complements a CEE by ensuring that the time of the experts is well spent Using ATLAS, an architecture analyst can perform technology sensitivity analysis, study many scenarios, and see the impact of design decisions. When the analyst is

  10. Proceedings of the Sixth International Conference on Advanced Learning Technologies

    OpenAIRE

    Kinshuk; Koper, Rob; Kommers, Piet; Kirschner, Paul A.; Sampson, Demetrios; Didderen, Wim

    2006-01-01

    Kinshuk, Koper, R., Kommers, P., Kirschner, P., Sampson, D. G., & Didderen, W. (Eds.) (2006). Advanced Technologies for Life-Long Learning. Proceedings of the 6th IEEE International Conference on Advanced Learning Technologies 2006. July, 5-7, 2006, Kerkrade, The Netherlands. Los Alamitos, CA: IEEE Computer Society (ISBN 0-7695-2632-2).

  11. Advanced Education and Technology Business Plan, 2009-12

    Science.gov (United States)

    Alberta Advanced Education and Technology, 2009

    2009-01-01

    The Ministry of Advanced Education and Technology consists of the following entities for budget purposes: Department of Advanced Education and Technology, the Access to the Future Fund, Alberta Enterprise Corporation, Alberta Research Council Inc., and iCORE Inc. Achieving the Ministry's goals involves the work and coordination of many…

  12. Advanced Education and Technology Business Plan, 2008-11

    Science.gov (United States)

    Alberta Advanced Education and Technology, 2008

    2008-01-01

    The Ministry of Advanced Education and Technology's 2008-11 business plan identifies how it plans to work over the next three years to enhance advanced learning opportunities and innovation for all Albertans. Alberta's advanced learning system is composed of public board-governed institutions, the apprenticeship and industry training system,…

  13. Advanced technology's impact on compressor design and development - A perspective

    Science.gov (United States)

    Ball, Calvin L.

    1989-01-01

    A historical perspective of the impact of advanced technologies on compression system design and development for aircraft gas turbine applications is presented. A bright view of the future is projected in which further advancements in compression system technologies will be made. These advancements will have a significant impact on the ability to meet the ever-more-demanding requirements being imposed on the propulsion system for advanced aircraft. Examples are presented of advanced compression system concepts now being studied. The status and potential impact of transitioning from an empirically derived design system to a computationally oriented system are highlighted. A current NASA Lewis Research Center program to enhance this transitioning is described.

  14. Advanced technologies impact on compressor design and development: A perspective

    Science.gov (United States)

    Ball, Calvin L.

    1989-01-01

    A historical perspective of the impact of advanced technologies on compression system design and development for aircraft gas turbine applications is presented. A bright view of the future is projected in which further advancements in compression system technologies will be made. These advancements will have a significant impact on the ability to meet the ever-more-demanding requirements being imposed on the propulsion system for advanced aircraft. Examples are presented of advanced compression system concepts now being studied. The status and potential impact of transitioning from an empirically derived design system to a computationally oriented system are highlighted. A current NASA Lewis Research Center program to enhance this transitioning is described.

  15. Recent advancements in prosthetic hand technology.

    Science.gov (United States)

    Saikia, Angana; Mazumdar, Sushmi; Sahai, Nitin; Paul, Sudip; Bhatia, Dinesh; Verma, Suresh; Rohilla, Punit Kumar

    2016-07-01

    Recently, significant advances over the past decade have been made in robotics, artificial intelligence and other cognitive related fields, allowing development of highly sophisticated bio-mimetic robotics systems. In addition, enormous number of robots have been designed and assembled by explicitly realising their biological oriented behaviours. To enhance skill behaviours and adequate grasping abilities in these devices, a new phase of dexterous hands has been developed recently with bio-mimetically oriented and bio-inspired functionalities. The aim in writing this review paper is to present a detailed insight towards the development of the bio-mimetic based dexterous robotic multi-fingered artificial hand. An "ideal" upper limb prosthesis should be perceived as a part of their natural body by the amputee and should replicate sensory-motor capabilities of the amputated limb. Upper-limb amputations are most often the result of sudden trauma to the body, although they also can be caused by malignancy, congenital deficiencies and vascular diseases. This paper discusses the different bio-mimetic approaches using a framework that permits for a common description of biological and technical based hand manipulation behaviour. In particular, the review focuses on a number of developments in the inspired robotic systems. In conclusion, the study found that a huge amount of research efforts in terms of kinematics, dynamics, modelling and control methodologies are being put in to improve the present hand technology, thereby providing more functionality to the prosthetic limb of the amputee. This would improve their quality-of-life and help in performing activities of daily living (ADL) tasks with comparative ease in the near future. PMID:27098838

  16. TECHNOLOGICAL ADVANCES IN AGRICULTURAL ECONOMICS CURRICULA

    OpenAIRE

    Schurle, Bryan W.; Comer, Dorothy A.

    1995-01-01

    The potential use of computers and electronic technology have created considerable interest among educators in agricultural economics. This paper provides an overview of the use of electronic technology within agricultural economics curricula; examines areas in which technological development offers promise and examines issues associated with adoption of the technology.

  17. Recent Advances in Precision Machinery and Manufacturing Technology

    OpenAIRE

    Liu, Chien-Hung; Hsieh, Wen-Hsiang; Chang, Zong-Yu; Tzou, Gow-Yi; Hanson, Steen Grüner; Hwang, Yunn-Lin

    2014-01-01

    Precision machinery and manufacturing technology are be- coming more important in current and future technologies. New knowledge in this field will aid in the advancement of various technologies that are needed to gain industrial competitiveness. To this end, the special issue aims to disseminate the latest advancements of relevant fundamental and applied research works of high quality to the inter- national community. The topics of the accepted articles in the special issue include precision...

  18. The State Prize for 1991 Science and Technology Advance

    Institute of Scientific and Technical Information of China (English)

    LINantion; FENGYilun

    1992-01-01

    According to the report in Science and Technology Daily on 10 July 1991, prize winners for the State Prize for 1991 Science and Technology Advance in China have been selected by the Evaluation Committee of the State Prize for 1991 Science and Technology Advance. Among the prizes, eight programs were concerned with rice research: Pathogenetic Types of Rice Bacterial Leaf Blight in China and the Application in Disease-resistant Breeding, by FANG Zhongda,

  19. Technological advances in self-insurance and self-protection

    OpenAIRE

    Chang-Ming Lee

    2015-01-01

    This study investigates how technological advances in self-insurance (or self-protection) affect the optimal level of self-insurance (or self-protection) and that of insurance, if insurance is also taken into account. Conditions are derived for determining the signs of changes in the optimal levels of decision variables due to improved technology. Two cross-derivatives are found to be the key factors. Classification of technological advances is suggested based on the two cross-derivatives. Th...

  20. Advancement in Engineering Technology: A Novel Perspective

    DEFF Research Database (Denmark)

    Kalia, Kartik; Rehman, M. Atiqur; Hussain, Dil muhammed Akbar;

    2016-01-01

    In this paper we will be discussing about the impact of technology on our daily lives. How everybody is dependent upon technology in one or other way. Methods/Statistical Analysis: Technology has played a significant role in the evolution of the society. Science has produced many new ideas but to...... harvest those ideas, technology is a must. With the huge requirement of engineering equipment's, the industry needs specialists who can manage and operate these technologies. Detailed information about the merits and demerits of technology is also mentioned in this paper. Findings: Technology has affected...... the environment on a great scale; in some cases, technology is even replacing human being or use of manpower. So proper counter measures have been mentioned, which can be used to control and limit harmful effect....

  1. CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Hugh W. Rimmer

    2003-11-15

    The U.S. is the largest producer of mining products in the world. In 1999, U.S. mining operations produced $66.7 billion worth of raw materials that contributed a total of $533 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (a) Solid-solid separation (b) Solid-liquid separation (c) Chemical/Biological Extraction (d) Modeling and Control, and (e) Environmental Control. Distribution of funds is being handled via competitive solicitation of research proposals through Site Coordinators at the seven member universities. The first of these solicitations, referred to as the CAST II-Round 1 RFP, was issued on October 28, 2002. Thirty-eight proposals were received by the December 10, 2002 deadline for this RFP-eleven (11) Solid-Solid Separation, seven (7) Solid-Liquid Separation, ten (10) Chemical/Biological Extraction, six (6) Modeling & Control and four (4) Environmental Control. These were first reviewed and ranked by a group of technical reviewers (selected primarily from industry). Based on these reviews, and an assessment of overall program requirements, the CAST Technical Committee made an initial selection/ranking of proposals and forwarded these to the DOE/NETL Project Officer for final review and approval. This process took some 7 months to complete but 17 projects (one joint) were in place at the constituent universities (three at Virginia Tech, two at West Virginia University, three at University of

  2. 2004 Physics and Advanced Technologies In the News

    Energy Technology Data Exchange (ETDEWEB)

    Hazi, A

    2005-11-01

    Several outstanding research activities in the Physics and Advanced Technology Directorate in 2004 were featured in ''Science & Technology Review'', the monthly publication of the Lawrence Livermore National Laboratory. Reprints of those articles accompany this report. Here we summarize other science and technology highlights, as well as the awards and recognition received by members of the Directorate in 2004.

  3. Production of Construction Materials Using Advanced Recycling Technologies

    OpenAIRE

    ECT Team, Purdue

    2007-01-01

    Waste reduction, material reuse, and use of recycle-content products can be focused on the management system somewhat. In contrast, material recycling is the technical issue how to create new materials using wastes. Thus, three advanced recycling technologies; 1) Synthetic Lightweight Aggregate technology (SLA), 2) Clean Coal Technology (CCT), and 3) RP-1 Polymer Identification System are introduced.

  4. TECHNOLOGY SUMMARY ADVANCING TANK WASTE RETRIEVAL AND PROCESSING

    Energy Technology Data Exchange (ETDEWEB)

    SAMS TL; MENDOZA RE

    2010-08-11

    This technology overview provides a high-level summary of technologies being investigated and developed by Washington River Protection Solutions (WRPS) to advance Hanford Site tank waste retrieval and processing. Technology solutions are outlined, along with processes and priorities for selecting and developing them.

  5. Advanced Technology Training Program for the Apparel Industry. Final Report.

    Science.gov (United States)

    El Paso Community Coll., TX.

    A project developed rapid response, advanced technology courses that met the apparel market labor needs of the El Paso (Texas) community. Courses were designed for four options: computerized marker making and pattern grading, computerized front office systems, high technology machinery operation, and high technology machinery mechanics. The…

  6. TECHNOLOGY SUMMARY ADVANCING TANK WASTE RETREIVAL AND PROCESSING

    Energy Technology Data Exchange (ETDEWEB)

    SAMS TL

    2010-07-07

    This technology overview provides a high-level summary of technologies being investigated and developed by Washington River Protection Solutions (WRPS) to advance Hanford Site tank waste retrieval and processing. Technology solutions are outlined, along with processes and priorities for selecting and developing them.

  7. Managing the Perception of Advanced Technology Risks in Mission Proposals

    Science.gov (United States)

    Bellisario, Sebastian Nickolai

    2012-01-01

    Through my work in the project proposal office I became interested in how technology advancement efforts affect competitive mission proposals. Technology development allows for new instruments and functionality. However, including technology advancement in a mission proposal often increases perceived risk. Risk mitigation has a major impact on the overall evaluation of the proposal and whether the mission is selected. In order to evaluate the different approaches proposals took I compared the proposals claims of heritage and technology advancement to the sponsor feedback provided in the NASA debriefs. I examined a set of Discovery 2010 Mission proposals to draw patterns in how they were evaluated and come up with a set of recommendations for future mission proposals in how they should approach technology advancement to reduce the perceived risk.

  8. Development of essential system technologies for advanced reactor

    Energy Technology Data Exchange (ETDEWEB)

    Bae, Y. Y.; Hwang, Y. D.; Cho, B. H. and others

    1999-03-01

    Basic design of SMART adopts the new advanced technologies which were not applied in the existing 1000MWe PWR. However, the R and D experience on these advanced essential technologies is lacking in domestic nuclear industry. Recently, a research on these advanced technologies has been performed as a part of the mid-and-long term nuclear R and D program, but the research was limited only for the small scale fundamental study. The research on these essential technologies such as helically coiled tube steam generator, self pressurizer, core cooling by natural circulation required for the development of integral reactor SMART have not been conducted in full scale. This project, therefore, was performed for the development of analysis models and methodologies, system analysis and thermal hydraulic experiments on the essential technologies to be applied to the 300MWe capacity of integral reactor SMART and the advanced passive reactor expected to be developed in near future with the emphasis on experimental investigation. (author)

  9. Development of essential system technologies for advanced reactor

    International Nuclear Information System (INIS)

    Basic design of SMART adopts the new advanced technologies which were not applied in the existing 1000MWe PWR. However, the R and D experience on these advanced essential technologies is lacking in domestic nuclear industry. Recently, a research on these advanced technologies has been performed as a part of the mid-and-long term nuclear R and D program, but the research was limited only for the small scale fundamental study. The research on these essential technologies such as helically coiled tube steam generator, self pressurizer, core cooling by natural circulation required for the development of integral reactor SMART have not been conducted in full scale. This project, therefore, was performed for the development of analysis models and methodologies, system analysis and thermal hydraulic experiments on the essential technologies to be applied to the 300MWe capacity of integral reactor SMART and the advanced passive reactor expected to be developed in near future with the emphasis on experimental investigation. (author)

  10. Schedule Risks Due to Delays in Advanced Technology Development

    Science.gov (United States)

    Reeves, John D. Jr.; Kayat, Kamal A.; Lim, Evan

    2008-01-01

    This paper discusses a methodology and modeling capability that probabilistically evaluates the likelihood and impacts of delays in advanced technology development prior to the start of design, development, test, and evaluation (DDT&E) of complex space systems. The challenges of understanding and modeling advanced technology development considerations are first outlined, followed by a discussion of the problem in the context of lunar surface architecture analysis. The current and planned methodologies to address the problem are then presented along with sample analyses and results. The methodology discussed herein provides decision-makers a thorough understanding of the schedule impacts resulting from the inclusion of various enabling advanced technology assumptions within system design.

  11. Technology Readiness Levels for Advanced Nuclear Fuels and Materials Development

    Energy Technology Data Exchange (ETDEWEB)

    Jon Carmack

    2014-01-01

    The Technology Readiness Level (TRL) process is used to quantitatively assess the maturity of a given technology. The TRL process has been developed and successfully used by the Department of Defense (DOD) for development and deployment of new technology and systems for defense applications. In addition, NASA has also successfully used the TRL process to develop and deploy new systems for space applications. Advanced nuclear fuels and materials development is a critical technology needed for closing the nuclear fuel cycle. Because the deployment of a new nuclear fuel forms requires a lengthy and expensive research, development, and demonstration program, applying the TRL concept to the advanced fuel development program is very useful as a management and tracking tool. This report provides definition of the technology readiness level assessment process as defined for use in assessing nuclear fuel technology development for the Advanced Fuel Campaign (AFC).

  12. ICONE-4: Proceedings. Volume 1 -- Part B: Basic technological advances

    International Nuclear Information System (INIS)

    The proceedings of this conference are divided into 5 volumes. Volume one is divided into Parts A and B. Here in Part B, the following subjects are covered: advances in thermal hydraulic computer codes for reactor analysis; human health effects of low level radiation; advances in liquid metal reactor technology; computational and experimental developments; two-phase flow and heat transfer fundamentals; advances in flow field analysis and testing; advanced reactor thermal hydraulic safety; thermal hydraulics of nuclear safety and reliability; advances in numerical simulation of steam explosions; and computational and experimental two-phase flow developments. Separate abstracts were prepared for most papers in this volume

  13. Advanced manufacturing technologies on color plasma displays

    Science.gov (United States)

    Betsui, Keiichi

    2000-06-01

    The mass production of the color plasma display started from 1996. However, since the price of the panel is still expensive, PDPs are not in widespread use at home. It is necessary to develop the new and low-cost manufacturing technologies to reduce the price of the panel. This paper describes some of the features of new fabrication technologies of PDPs.

  14. Organizational Considerations for Advanced Manufacturing Technology

    Science.gov (United States)

    DeRuntz, Bruce D.; Turner, Roger M.

    2003-01-01

    In the last several decades, the United States has experienced a decline in productivity, while the world has seen a maturation of the global marketplace. Nations have moved manufacturing strategy and process technology issues to the top of management priority lists. The issues surrounding manufacturing technologies and their implementations have…

  15. A study of advanced vitrification technology

    International Nuclear Information System (INIS)

    JNFL have developed the vitrification technology of a high level liquid waste with a modification in discharge performance of the noble metal by changing the bottom structure and adding heating means. Cold test was conducted by using a full scale mock-up melter which introduced the new vitrification technology. In the cold test, we confirmed the discharge performance of the noble metal. (author)

  16. Advanced Microelectronics Technologies for Future Small Satellite Systems

    Science.gov (United States)

    Alkalai, Leon

    1999-01-01

    Future small satellite systems for both Earth observation as well as deep-space exploration are greatly enabled by the technological advances in deep sub-micron microelectronics technologies. Whereas these technological advances are being fueled by the commercial (non-space) industries, more recently there has been an exciting new synergism evolving between the two otherwise disjointed markets. In other words, both the commercial and space industries are enabled by advances in low-power, highly integrated, miniaturized (low-volume), lightweight, and reliable real-time embedded systems. Recent announcements by commercial semiconductor manufacturers to introduce Silicon On Insulator (SOI) technology into their commercial product lines is driven by the need for high-performance low-power integrated devices. Moreover, SOI has been the technology of choice for many space semiconductor manufacturers where radiation requirements are critical. This technology has inherent radiation latch-up immunity built into the process, which makes it very attractive to space applications. In this paper, we describe the advanced microelectronics and avionics technologies under development by NASA's Deep Space Systems Technology Program (also known as X2000). These technologies are of significant benefit to both the commercial satellite as well as the deep-space and Earth orbiting science missions. Such a synergistic technology roadmap may truly enable quick turn-around, low-cost, and highly capable small satellite systems for both Earth observation as well as deep-space missions.

  17. Enraf Series 854 advanced technology gauge (ATG) acceptance test procedure

    International Nuclear Information System (INIS)

    This Acceptance Test Procedure was written to test the Enraf Series 854 Advanced Technology Gauge (ATG) prior to installation in the Tank Farms. The procedure sets various parameters and verifies that the gauge is functional

  18. JTEL Winter School for Advanced Technologically Enhanced Learning

    NARCIS (Netherlands)

    Glahn, Christian; Gruber, Marion

    2010-01-01

    Glahn, C., & Gruber, M. (2010). JTEL Winter School for Advanced Technologically Enhanced Learning. In ~mail. Das Magazin des Tiroler Bildungsinstituts, 01/10, März (p. 3-4). Innsbruck: Grillhof, Medienzentrum.

  19. Advances in Liquid Phase{trademark} technology

    Energy Technology Data Exchange (ETDEWEB)

    Miller, W.R.; Heydorn, E.C.; Moore, R.B.; Tijm, P.J.A.

    1998-07-01

    The Liquid Phase{trademark} Technology builds on the successful development by Air Products and Chemicals, Inc. of the slurry phase bubble column technology. Air Products and Chemicals Liquid Phase{trademark} technology embodies several chemical processes including Liquid Phase Methanol{trademark} (LPMEOH{trademark}) and the Liquid Phase DiMethyl Ether{trademark} (LPDME{trademark}) and other alcohols/oxygenates. The LPMEOH{trademark} technology was developed during the 1980's with the financial support of the US department of Energy (DOE). The concept was proven in over 7,400 hours of test operation in a DOE-owned, 3,200 gallons (US) of methanol per day process development unit located at LaPorte, Texas. The first commercial-scale demonstration plant for the technology has been constructed, commissioned, and is now being operated at Eastman Chemical Company's coal gasification facility in Kingsport, Tennessee under the DOE's Clean Coal Technology Program. Construction began in October of 1995 and was completed in January of 1997. After commissioning and startup activities were completed, operation began in April of 1997. Currently, the LPMEOH{trademark} plant is producing 80,000 gallons of methanol per day. Over the next four years, a program of operation will demonstrate the commercial advantages of the technology to include simulations of the integrated gasification combined cycle (IGCC) coproduction of power and methanol application. This paper reviews the: Commercial Application for the LPMEOH{trademark} process technology; Operational Plans to demonstrate the commercial advantages of the plant; LPMEOH{trademark} Plant-Status, highlighting the integration of the LPMEOH{trademark} plant at Kingsport, and the accomplishments during the initial operating period; and Highlights of other Liquid Phase{trademark} Technology Developments.

  20. Technology advances for Space Shuttle processing

    Science.gov (United States)

    Wiskerchen, M. J.; Mollakarimi, C. L.

    1988-01-01

    One of the major initial tasks of the Space Systems Integration and Operations Research Applications (SIORA) Program was the application of automation and robotics technology to all aspects of the Shuttle tile processing and inspection system. The SIORA Program selected a nonlinear systems engineering methodology which emphasizes a team approach for defining, developing, and evaluating new concepts and technologies for the operational system. This is achieved by utilizing rapid prototyping testbeds whereby the concepts and technologies can be iteratively tested and evaluated by the team. The present methodology has clear advantages for the design of large complex systems as well as for the upgrading and evolution of existing systems.

  1. Rapid Prototyping: Technologies, Materials and Advances

    Directory of Open Access Journals (Sweden)

    Dudek P.

    2016-06-01

    Full Text Available In the context of product development, the term rapid prototyping (RP is widely used to describe technologies which create physical prototypes directly from digital data. Recently, this technology has become one of the fastest-growing methods of manufacturing parts. The paper provides brief notes on the creation of composites using RP methods, such as stereolithography, selective laser sintering or melting, laminated object modelling, fused deposition modelling or three-dimensional printing. The emphasis of this work is on the methodology of composite fabrication and the variety of materials used in these technologies.

  2. Advanced Manufacturing Technologies in Russia: Outlines of a New Policy

    OpenAIRE

    Irina, Dezhina; Alexey, Ponomarev; Alexander, Frolov

    2015-01-01

    The present article, which continues the discussion of advanced manufacturing technologies initiated in Foresight-Russia issue 2 (2014), evaluates the current state of this field in Russia. The analysis here examines the state of the relevant scientific research and the readiness of industry to adopt the new technologies developed by researchers. The study is based on bibliometric and patent analyses, as well as on expert evaluations of the markets related to different segments of advanced ma...

  3. Advanced Materials in Support of EERE Needs to Advance Clean Energy Technologies Program Implementation

    Energy Technology Data Exchange (ETDEWEB)

    Liby, Alan L [ORNL; Rogers, Hiram [ORNL

    2013-10-01

    The goal of this activity was to carry out program implementation and technical projects in support of the ARRA-funded Advanced Materials in Support of EERE Needs to Advance Clean Energy Technologies Program of the DOE Advanced Manufacturing Office (AMO) (formerly the Industrial Technologies Program (ITP)). The work was organized into eight projects in four materials areas: strategic materials, structural materials, energy storage and production materials, and advanced/field/transient processing. Strategic materials included work on titanium, magnesium and carbon fiber. Structural materials included work on alumina forming austentic (AFA) and CF8C-Plus steels. The advanced batteries and production materials projects included work on advanced batteries and photovoltaic devices. Advanced/field/transient processing included work on magnetic field processing. Details of the work in the eight projects are available in the project final reports which have been previously submitted.

  4. Advanced Education and Technology Business Plan, 2011-14

    Science.gov (United States)

    Alberta Advanced Education and Technology, 2011

    2011-01-01

    Advanced Education and Technology's mission is to lead the development of a knowledge-driven future through a dynamic and integrated advanced learning and innovation system. Its core businesses are to: (1) provide strategic leadership for Campus Alberta and Alberta Innovates; and (2) engage learners, industry and the community in learning…

  5. Advancement on Drilling Technology in Petroleum Industry

    OpenAIRE

    Akpedeye, Kelvin Uruemu

    2011-01-01

    Since the birth of petroleum business, in the mid-19th century, cable tool and rotary drilling have been the only two techniques applied in the drilling phase till date. Although the rotary drilling technique has proved very successful, applying laser technology in this drilling; which is a newer technology that is already at hand, has the potential of displacing both techniques from operation. Cable tool drilling is the first of these techniques. Hole boring is achieved by repeatedly lif...

  6. Infrared detectors: Advances, challenges and new technologies

    International Nuclear Information System (INIS)

    Human knowledge of infrared (IR) radiation is about 200 years old. However it was in the late 20th century that we developed a wide range of smart technologies for detection and started to take advantage for our benefit. Today IR detector technology is in its 3rd generation and comes with challenging demands. Based on the propagation of IR radiation through free space it is divided into different transmission windows. The most interesting for thermal imaging are the mid-wave IR (MWIR) and the long-wave IR (LW IR). Infrared detectors for thermal imaging have a number of applications in industry, security, search and rescue, surveillance, medicine, research, meteorology, climatology and astronomy. Currently high-performance IR imaging technology is mainly based on epitaxially grown structures of the small-bandgap bulk alloy mercury-cadmium-telluride (MCT), indium antimonide (InSb) and GaAs based quantum-well infrared photodetectors (QWIPs), depending on the application and wavelength range. However, they operate at low temperatures requiring costly and bulky cryogenic systems. In addition there is always a need for better performance, which generates possibilities for developing new technologies. Some emerging technologies are quantum dot infrared photodetectors (QDIPs), type-II strained layer super-lattice, and QDIPs with type-II band alignment. In this report a brief review of the current and new technologies for high performance IR detectors, will be presented

  7. Task 3.3: Warm Syngas Cleanup and Catalytic Processes for Syngas Conversion to Fuels Subtask 3: Advanced Syngas Conversion to Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Lebarbier Dagel, Vanessa M.; Li, J.; Taylor, Charles E.; Wang, Yong; Dagle, Robert A.; Deshmane, Chinmay A.; Bao, Xinhe

    2014-03-31

    activity was to develop methods and enabling materials for syngas conversion to SNG with readily CO2 separation. Suitable methanation catalyst and CO2 sorbent materials were developed. Successful proof-of-concept for the combined reaction-sorption process was demonstrated, which culminated in a research publication. With successful demonstration, a decision was made to switch focus to an area of fuels research of more interest to all three research institutions (CAS-NETL-PNNL). Syngas-to-Hydrocarbon Fuels through Higher Alcohol Intermediates There are two types of processes in syngas conversion to fuels that are attracting R&D interest: 1) syngas conversion to mixed alcohols; and 2) syngas conversion to gasoline via the methanol-to-gasoline process developed by Exxon-Mobil in the 1970s. The focus of this task was to develop a one-step conversion technology by effectively incorporating both processes, which is expected to reduce the capital and operational cost associated with the conversion of coal-derived syngas to liquid fuels. It should be noted that this work did not further study the classic Fischer-Tropsch reaction pathway. Rather, we focused on the studies for unique catalyst pathways that involve the direct liquid fuel synthesis enabled by oxygenated intermediates. Recent advances made in the area of higher alcohol synthesis including the novel catalytic composite materials recently developed by CAS using base metal catalysts were used.

  8. Hydroconversion of model Fischer‑Tropsch wax over noble metal/silica-alumina catalysts

    OpenAIRE

    Regali, Francesco

    2013-01-01

    Synthetic fuels produced using the Fischer-Tropsch technology will play an important role in the future of the transportation sector. The Fischer-Tropsch synthesis (FTS) allows converting synthesis gas (CO + H2) into fuels of outstanding quality. The synthesis gas can be obtained from different carbon sources: natural gas, coal and biomass. In order to maximize the yield of middle distillates, the process is carried out in two main steps: the FT-synthesis that produces long-chain hydrocarbons...

  9. Advanced Turbine Technology Applications Project (ATTAP). Annual report 1992

    Energy Technology Data Exchange (ETDEWEB)

    1993-03-01

    This report summarizes work performed by Garrett Auxiliary Power Division (GAPD), a unit of Allied-Signal Aerospace Company, during calendar year 1992, toward development and demonstration of structural ceramic technology for automotive gas turbine engines. This work was performed for the US Department of Energy (DOE) under National Aeronautics and Space Administration (NASA) Contract DEN3-335, Advanced Turbine Technology Applications Project (ATTAP). GAPD utilized the AGT101 regenerated gas turbine engine developed under the previous DOE/NASA Advanced Gas Turbine (AGT) program as the ATTAP test bed for ceramic engine technology demonstration. ATTAP focussed on improving AGT101 test bed reliability, development of ceramic design methodologies, and improvement of fabrication and materials processing technology by domestic US ceramics fabricators. A series of durability tests was conducted to verify technology advancements. This is the fifth in a series of technical summary reports published annually over the course of the five-year contract.

  10. Advances in Liquid Phase{trademark} technology

    Energy Technology Data Exchange (ETDEWEB)

    Miller, W.R.; Heydorn, E.C.; Moore, R.B.; Tijm, P.J.A.

    1998-04-01

    The {open_quotes}Liquid Phase{trademark} Technology{close_quotes} builds on the successful development by Air Products and Chemicals, Inc. of the slurry phase bubble column technology. Air Products and Chemicals Liquid Phase{trademark} technology embodies several chemical processes including Liquid Phase Methanol{trademark} (LPMEOH{trademark}) and the Liquid Phase DiMethyl Ether{trademark} (LPDME{trademark}) and other alcohols/oxygenates. The LPMEOH{trademark} technology was developed during the 1980`s with the financial support of the U.S. Department of Energy (DOE). The concept was proven in over 7,400 hours of test operation in a DOE-owned, 3,200 gallons (U.S.) of methanol per day process development unit located at LaPorte, Texas. The first commercial-scale demonstration plant for the technology has been constructed, commissioned, and is now being operated at Eastman Chemical Company`s coal gasification facility in Kingsport, Tennessee under the DOE`s Clean Coal Technology Program. Construction began in October of 1995 and was completed in January of 1997. After commissioning and startup activities were completed, operation began in April of 1997. Currently, the LPMEOH{trademark} plant is producing 80,000 gallons of methanol per day. Over the next four years, a program of operation will demonstrate the commercial advantages of the technology to include simulations of the integrated gasification combined cycle (IGCC) coproduction of power and methanol application. Air Products and Eastman formed the {open_quotes}Air Products Liquid Phase Conversion Co., L.P.{close_quotes} partnership to execute the commercial-scale demonstration project. Most of the product methanol is refined to chemical-grade quality (99.85 wt% purity via distillation) and used by Eastman as chemical feedstock in the commercial facility. A portion of the product methanol will be withdrawn prior to purification (about 98 wt% purity) and used in off-site product-use tests.

  11. Status of advanced technologies for CANDU reactors

    International Nuclear Information System (INIS)

    The future development of the CANDU reactor is a continuation of a successful series of reactors, the most recent of which are nine CANDU 6 Mk 1* units and four Darlington units. There are three projects underway that continue the development of the CANDU reactor. These new design projects flow from the original reactor designs and are a natural progression of the CANDU 6 Mk 1, two units of which are operating successfully in Canada, one each in Argentina and Korea, with five more being built in Rumania. These new design projects are known as: CANDU 6 Mk 2, an improved version of CANDU 6 Mk 1; CANDU 3, a small, advanced version of the CANDU 6 Mk 1; CANDU 6 Mk 3, a series of advanced CANDU reactors. A short description of modified versions of CANDU reactors is given in this paper. 5 figs

  12. Advanced High-Temperature Engine Materials Technology Progresses

    Science.gov (United States)

    1997-01-01

    The objective of the Advanced High Temperature Engine Materials Technology Program (HITEMP) at the NASA Lewis Research Center is to generate technology for advanced materials and structural analysis that will increase fuel economy, improve reliability, extend life, and reduce operating costs for 21st century civil propulsion systems. The primary focus is on fan and compressor materials (polymer-matrix composites - PMC's), compressor and turbine materials (superalloys, and metal-matrix and intermetallic-matrix composites - MMC's and IMC's), and turbine materials (ceramic-matrix composites - CMC's). These advanced materials are being developed in-house by Lewis researchers and on grants and contracts.

  13. Advanced NDE Technologies for Powder Metal Components

    Energy Technology Data Exchange (ETDEWEB)

    Martin, P; Haskins, J; Thomas, G; Dolan, K

    2003-05-01

    Nondestructive evaluation encompasses numerous technologies that assess materials and determine important properties. This paper demonstrates the applicability of several of these technologies to the field of powder metallurgy. The usual application of nondestructive evaluation is to detect and quantify defects in fully sintered product. But probably its most appealing role is to sense problems earlier in the manufacturing process to avoid making defects at all. Also nondestructive evaluation can be incorporated into the manufacturing processes to monitor important parameters and control the processes to produce defect free product. Nondestructive evaluation can characterize powders, evaluate components in the green state, monitor the sintering process, and inspect the final component.

  14. Advances in software science and technology

    CERN Document Server

    Kamimura, Tsutomu

    1994-01-01

    This serial is a translation of the original works within the Japan Society of Software Science and Technology. A key source of information for computer scientists in the U.S., the serial explores the major areas of research in software and technology in Japan. These volumes are intended to promote worldwide exchange of ideas among professionals.This volume includes original research contributions in such areas as Augmented Language Logic (ALL), distributed C language, Smalltalk 80, and TAMPOPO-an evolutionary learning machine based on the principles of Realtime Minimum Skyline Detection.

  15. 9 Waste Rubber Technologies Passed the Review on Advanced Applicable Technologies by MIIT

    Institute of Scientific and Technical Information of China (English)

    Qiart Bozhang

    2012-01-01

    To promote the development of integrative utilization technologies of industrial solid wastes and to enhance the level of integrative utilization, the Ministry of Industry and Information Technology (MIIT) held Reviewing Meeting of Advanced Applicable Technologies for the Integrative Utilization of Industrial Solid Wastes on April 27. 9 integrative utilization technologies of waste rubber passed this review.

  16. Achievements and prospects of advanced materials processed by powder technology

    OpenAIRE

    Kaysser, W.

    1993-01-01

    In this paper examples from intermetallics, composites with ductile and high strength reinforcements, nanocrystalline and superplastic materials are used to illustrate generic and special achievements and prospects of advanced materials processed by powder technology. Processing technologies include reactive powder metallurgy, nanocrystalline processing, rapid solidification and mechanical alloying.

  17. Cost estimate guidelines for advanced nuclear power technologies

    Energy Technology Data Exchange (ETDEWEB)

    Hudson, C.R. II

    1986-07-01

    To make comparative assessments of competing technologies, consistent ground rules must be applied when developing cost estimates. This document provides a uniform set of assumptions, ground rules, and requirements that can be used in developing cost estimates for advanced nuclear power technologies.

  18. The Advanced Technology Environmental Education Center Summer Fellows Institute.

    Science.gov (United States)

    Depken, Diane E.; Zeman, Catherine L.; Lensch, Ellen Kabat; Brown, Edward J.

    2002-01-01

    Describes the background, activities, and outcomes of the Advanced Technology Environmental Education Center (ATEEC) and its Summer Fellows Institutes as a model for disciplinary and cross-disciplinary infusion of environmental science and technology content, curriculum, and methods into the classroom. Presents experiences, themes, and activities…

  19. Cost estimate guidelines for advanced nuclear power technologies

    International Nuclear Information System (INIS)

    To make comparative assessments of competing technologies, consistent ground rules must be applied when developing cost estimates. This document provides a uniform set of assumptions, ground rules, and requirements that can be used in developing cost estimates for advanced nuclear power technologies

  20. Cost estimate guidelines for advanced nuclear power technologies

    International Nuclear Information System (INIS)

    To make comparative assessments of competing technologies, consistent ground rules must be applied when developing cost estimates. This document provides a uniform set of assumptions, ground rules, and requirements that can be used in developing cost estimates for advanced nuclear power technologies. 10 refs., 8 figs., 32 tabs

  1. IMPACT OF TECHNOLOGICAL ADVANCEMENT ON PEDAGOGY

    Directory of Open Access Journals (Sweden)

    Mounia ABIK

    2012-01-01

    Full Text Available To improve the quality of learning, pedagogues have prescribed different pedagogical approaches (constructivist, cognitivist…. However, the effective implementation of the majority of these approaches has not been possible only after the advent of new forms of learning (E_learning, M-learning.... These forms are closely related to technological development. Later with the emergence of technology (pervasive computing, Artificial Intelligent ... a new form of learning is established. It is called Pervasive Learning "P-Learning”. P-Learning is a social process that connects learners to communities of devices, people, and situations in a transparent and independent manner. This learning form goes far beyond the predictions suggested by pedagogue. Learning can then take part outside the learner via technology, which will be an extension of his brain by unloading the cognitive practices he performs. The aim of this paper is to answer the following questions: What alliance is there between pedagogy and technology? Are we in need of a new pedagogical approach in the new learning environment "P-Learning"? What are the new pedagogical challenges to resolve?

  2. Advancing clean energy technology in Canada

    International Nuclear Information System (INIS)

    This paper discusses the development of clean energy technology in Canada. Energy is a major source of Canadian prosperity. Energy means more to Canada than any other industrialized country. It is the only OECD country with growing oil production. Canada is a stable and secure energy supplier and a major consumer. Promoting clean energy is a priority to make progress in multiple areas.

  3. CNPC's Diversification Business Boosted by Advanced Technology

    Institute of Scientific and Technical Information of China (English)

    Yao Xuemin

    1996-01-01

    @@ The Eighth Five-Year Plan period witnessed rapid the development in the diversification business of China's onshore petroleum industry for five consecutive years mainly as a result of intensified efforts to develop new products and foreign- exchange- earning products by making full use of science and technology. In particular, great achievements were recorded in the following aspects.

  4. Technological advances in radiotherapy of rectal cancer

    DEFF Research Database (Denmark)

    Appelt, Ane L; Sebag-Montefiore, David

    2016-01-01

    , selective sparing of specific organs to enable chemotherapy escalation, and nonsurgical management. SUMMARY: Few prospective studies of IMRT and VMAT exist, which causes uncertainty not just in regards to the clinical benefit of these technologies but also in the optimal use. The priority for future...

  5. Advanced Space Radiation Detector Technology Development

    Science.gov (United States)

    Wrbanek, John D.; Wrbanek, Susan Y.; Fralick, Gustave C.

    2013-01-01

    The advanced space radiation detector development team at the NASA Glenn Research Center (GRC) has the goal of developing unique, more compact radiation detectors that provide improved real-time data on space radiation. The team has performed studies of different detector designs using a variety of combinations of solid-state detectors, which allow higher sensitivity to radiation in a smaller package and operate at lower voltage than traditional detectors. Integration of multiple solid-state detectors will result in an improved detector system in comparison to existing state-of-the-art instruments for the detection and monitoring of the space radiation field for deep space and aerospace applications.

  6. Advanced core monitoring technology for WWER reactors

    International Nuclear Information System (INIS)

    The Westinghouse BEACON online monitoring system has been developed to provide continuous core monitoring and operational support for pressurized water reactor using movable detectors (fission chamber) and core thermocouples. The basic BEACON core monitoring methodology is described. Traditional WWER reactors use rhodium fixed in-core detectors as the means to provide detailed core power distribution for surveillance purposes. An adapted version of the BEACON advanced core monitoring and support system is described which seems to be, due to the different demand/response requirements, the optimal solution (for routine surveillance and anomaly detection) for WWER reactors with existing fixed in-core detectors. (Z.S.) 4 refs

  7. Production of liquid fuels with a high-temperature gas-cooled reactor

    Science.gov (United States)

    Quade, R. N.; Vrable, D. L.; Green, L., Jr.

    An exploration is made of the technical, economic and environmental impact feasibility of integrating coal liquefaction methods directly and indirectly with a nuclear reactor source of process heat, with stress on the production of synthetic jet fuel. Production figures and operating costs are compared for indirect conventional and nuclear processes using Lurgi-Fischer-Tropsch technology with direct conventional and nuclear techniques employing the advanced SRC-II technology, and it is concluded that significant advantages in coal savings and environmental impact can be expected from nuclear reactor integration.

  8. 9th International Conference on Advanced Computing & Communication Technologies

    CERN Document Server

    Mandal, Jyotsna; Auluck, Nitin; Nagarajaram, H

    2016-01-01

    This book highlights a collection of high-quality peer-reviewed research papers presented at the Ninth International Conference on Advanced Computing & Communication Technologies (ICACCT-2015) held at Asia Pacific Institute of Information Technology, Panipat, India during 27–29 November 2015. The book discusses a wide variety of industrial, engineering and scientific applications of the emerging techniques. Researchers from academia and industry present their original work and exchange ideas, information, techniques and applications in the field of Advanced Computing and Communication Technology.

  9. "ATLAS" Advanced Technology Life-cycle Analysis System

    Science.gov (United States)

    Lollar, Louis F.; Mankins, John C.; ONeil, Daniel A.

    2004-01-01

    Making good decisions concerning research and development portfolios-and concerning the best systems concepts to pursue - as early as possible in the life cycle of advanced technologies is a key goal of R&D management This goal depends upon the effective integration of information from a wide variety of sources as well as focused, high-level analyses intended to inform such decisions Life-cycle Analysis System (ATLAS) methodology and tool kit. ATLAS encompasses a wide range of methods and tools. A key foundation for ATLAS is the NASA-created Technology Readiness. The toolkit is largely spreadsheet based (as of August 2003). This product is being funded by the Human and Robotics The presentation provides a summary of the Advanced Technology Level (TRL) systems Technology Program Office, Office of Exploration Systems, NASA Headquarters, Washington D.C. and is being integrated by Dan O Neil of the Advanced Projects Office, NASA/MSFC, Huntsville, AL

  10. MIMO Technologies in 3GPP LTE and LTE-Advanced

    Directory of Open Access Journals (Sweden)

    Zhang Jianzhong(Charlie

    2009-01-01

    Full Text Available Abstract 3rd Generation Partnership Project (3GPP has recently completed the specification of the Long Term Evolution (LTE standard. Majority of the world's operators and vendors are already committed to LTE deployments and developments, making LTE the market leader in the upcoming evolution to 4G wireless communication systems. Multiple input multiple output (MIMO technologies introduced in LTE such as spatial multiplexing, transmit diversity, and beamforming are key components for providing higher peak rate at a better system efficiency, which are essential for supporting future broadband data service over wireless links. Further extension of LTE MIMO technologies is being studied under the 3GPP study item "LTE-Advanced" to meet the requirement of IMT-Advanced set by International Telecommunication Union Radiocommunication Sector (ITU-R. In this paper, we introduce various MIMO technologies employed in LTE and provide a brief overview on the MIMO technologies currently discussed in the LTE-Advanced forum.

  11. Prospect of advanced generation technologies in a competitive market place

    Energy Technology Data Exchange (ETDEWEB)

    Guha, M.; Singh, A.

    1999-07-01

    The US Electric utility industry is undergoing tremendous changes for meeting the challenge of deregulation and customer demands for a free competitive market. Two major forces are driving this market: the deregulation of the industry and customer demands for achieving the lowest cost for electricity, forcing utility companies to position themselves as the low-cost producers. This paper will briefly discuss the status of various advanced generation technologies with respect to their costs, applicability and limitations, where these technologies are expected to be cost-effective and how they compare with the combined cycle plants. Advanced generation technologies may benefit as the environment regulations are tightened. This paper will examine how, when and where the advanced generation technologies would play a role in penetrating the market on their own merits.

  12. Recent Advances in Precision Machinery and Manufacturing Technology

    DEFF Research Database (Denmark)

    Liu, Chien-Hung; Hsieh, Wen-Hsiang; Chang, Zong-Yu;

    2014-01-01

    Precision machinery and manufacturing technology are be- coming more important in current and future technologies. New knowledge in this field will aid in the advancement of various technologies that are needed to gain industrial competitiveness. To this end, the special issue aims to disseminate...... manufacturing systems, sensors and materials, CAD/CAM/CAE for precision machinery, computation/numerical method, intelligent system and ap- proach, vibration engineering, mechanism design, and fluid- dynamics/thermodynamics....

  13. Advances in technology for integrated route analysis

    Energy Technology Data Exchange (ETDEWEB)

    Carey, N.T.; George, P.J.; Khamhawi, K. [SAGE Engineering Ltd., Bath (United Kingdom)

    1998-12-31

    Pipeline and cable routes are becoming ever complex with routes being chosen in increasingly remote and technically demanding areas. Clients now demand greater information and analysis from the surveys and interpretations. By utilising a range of leading edge equipment, greater information can be obtained, visualised and analysed than ever before. Three case studies are presented, indicating how such technology has been employed to provide the client with a greater understanding of complex engineering projects, and what additional technology could have been utilised to further enhance the project. Examples of data, systems and project management used on two major pipe routes and one major cable route are presented. Swath Bathymetry (ISIS), 3D visualisation (Fledermaus), cone penetrometer testing (SAGE Miniature CPT), GIS databases (INfoXProfessional), and the use of pipeline stress analysis, upheaval buckling and rock dump optimisation software (SAFE Profile) are all examined. (author)

  14. Advanced technologies for intelligent transportation systems

    CERN Document Server

    Picone, Marco; Amoretti, Michele; Zanichelli, Francesco; Ferrari, Gianluigi

    2015-01-01

    This book focuses on emerging technologies in the field of Intelligent Transportation Systems (ITSs) namely efficient information dissemination between vehicles, infrastructures, pedestrians and public transportation systems. It covers the state-of-the-art of Vehicular Ad-hoc Networks (VANETs), with centralized and decentralized (Peer-to-Peer) communication architectures, considering several application scenarios. With a detailed treatment of emerging communication paradigms, including cross networking  and distributed algorithms. Unlike most of the existing books, this book presents a multi-layer overview of information dissemination systems, from lower layers (MAC) to high layers (applications). All those aspects are investigated considering the use of mobile devices, such as smartphones/tablets and embedded systems, i.e. technologies that during last years completely changed the current market, the user expectations, and communication networks. The presented networking paradigms are supported and validate...

  15. Recent advances in PIM technology I

    OpenAIRE

    Zlatkov B.S.; Griesmayer E.; Loibl H.; Aleksić O.S.; Danninger H.; Gierl C.; Lukić L.S.

    2008-01-01

    In this article the state of art of the PIM (Powder Injection Moulding) technology is given in brief. The main process flow diagram consisting of four steps: feedstock preparation, injection moulding (green samples forming), the debinding (binder removing) procedure and the sintering process was described. After that the materials for binders and additives for the surface active agents were mentioned in brief. The metal injection moulding (MIM) process was analysed in more detail: MIM- stainl...

  16. Advanced lost foam from casting technology

    Energy Technology Data Exchange (ETDEWEB)

    Bates, C. E.; Littleton, H. E.; Askeland, D.; Griffin, J.; Miller, B. A.; Sheldon, D. S.

    1996-05-01

    Previous research made significant advances in understanding the Lost Foam Casting (LFC) Process and clearly identified areas where additional research was needed to improve the process and make it more functional in an industrial environment. The current project focused on five areas listed as follows: Task 1: Precision Pattern Production Task 2: Pattern Coating Consistency Task 3: Sand Fill and Compaction Effects Task 4: Pattern Gating Task 5: Mechanical Properties of Castings. This report summarizes the work done under the current contract in all five areas in the period of October 1, 1994 through December 31, 1995. Twenty-eight (28) companies jointly participate in the project. These companies represent a variety of disciplines, including pattern designers, pattern producers, coating manufacturers, plant design companies, compaction equipment manufacturers, casting producers, and casting buyers.

  17. Advances in brazing science, technology and applications

    CERN Document Server

    2013-01-01

    Brazing processes offer enhanced control, adaptability and cost-efficiency in the joining of materials. Unsurprisingly, this has lead to great interest and investment in the area. Drawing on important research in the field, Advances in brazing provides a clear guide to the principles, materials, methods and key applications of brazing. Part one introduces the fundamentals of brazing, including molten metal wetting processes, strength and margins of safety of brazed joints, and modeling of associated physical phenomena. Part two goes on to consider specific materials, such as super alloys, filler metals for high temperature brazing, diamonds and cubic boron nitride, and varied ceramics and intermetallics. The brazing of carbon-carbon (C/C) composites to metals is also explored before applications of brazing and brazed materials are discussed in part three. Brazing of cutting materials, use of coating techniques, and metal-nonmetal brazing for electrical, packaging and structural applications are reviewed, alon...

  18. Commercialization of Australian advanced infrared technology

    Science.gov (United States)

    Redpath, John; Brown, Allen; Woods, William F.

    1995-09-01

    For several decades, the main thrust in infrared technology developments in Australia has been in two main sensor technologies: uncooled silicon chip printed bolometric sensors pioneered by DSTO's Kevin Liddiard, and precision engineered high quality Cadmium Mercury Telluride developed at DSTO under the guidance of Dr. Richard Hartley. In late 1993 a low cost infrared imaging device was developed at DSTO as a sensor for guided missiles. The combination of these three innovations made up a unique package that enabled Australian industry to break through the barriers of commercializing infrared technology. The privately owned company, R.J. Optronics Pty Ltd undertook the process of re-engineering a selection of these DSTO developments to be applicable to a wide range of infrared products. The first project was a novel infrared imager based on a Palmer scan (translated circle) mechanism. This device applies a spinning wedge and a single detector, it uses a video processor to convert the image into a standard rectangular format. Originally developed as an imaging seeker for a stand-off weapon, it is producing such high quality images at such a low cost that it is now also being adapted for a wide variety of other military and commercial applications. A technique for electronically stabilizing it has been developed which uses the inertial signals from co-mounted sensors to compensate for platform motions. This enables it to meet the requirements of aircraft, marine vessels and masthead sight applications without the use of gimbals. After tests on a three-axis motion table, several system configurations have now been successfully operated on a number of lightweight platforms, including a Cessna 172 and the Australian made Seabird Seeker aircraft.

  19. Recent advances in Master Curve technology

    International Nuclear Information System (INIS)

    The Master Curve (MC) methodology has evolved, from only being a brittle fracture testing and analysis procedure, to a technological tool capable of addressing many more structural integrity issues like constraint and parameter transferability. One issue that not yet has been covered by the MC is the warm pre-stress (WPS) effect. This effect, which is known to produce an effective increase in fracture toughness may be of great importance for some structural safety assessment situations, where thermal transients are involved. Here, the WPS effect is re-examined and implemented into the MC methodology. (orig.)

  20. ADVANCED TECHNOLOGY WASTEWATER TREATMENT OF NITRITE IONS

    Directory of Open Access Journals (Sweden)

    E.G. Morozov

    2012-06-01

    Full Text Available The main reason for high concentration of nitrite ions in water is the existence of sources of industrial and agricultural pollution. Contamination of drinking water, juices, wine and other liquids of nitrite ions as a result of improper use of nitrogen fertilizers has an adverse effect on living organism, because under the influence of enzymes nitrite ions in living organisms form high carcinogenic nitrosamines, and the interaction of nitrite ions from blood hemoglobin causes such toxicity that leads to disease cyanosis [1]. Therefore removal of nitrite ions from water has received increased attention. The paper discusses an innovative wastewater treatment technology from the nitrite ion with hypochlorite produced during electrolysis.

  1. Ethical aspects of advanced reproductive technologies.

    Science.gov (United States)

    Schenker, Joseph G

    2003-11-01

    The progress achieved during the last 25 years in the assisted reproductive technology field has been phenomenal. Many countries currently practice genetic material donation, human embryo cryopreservation, selective embryo reduction, preimplantation genetic diagnosis, and surrogacy. While embryo research and therapeutic cloning are carried out only in a few centers, thus far human cloning has been universally condemned. Nonetheless, the rapid evolution and progress of these various techniques of assisted reproduction has opened a Pandora's box of ethical issues that must be urgently addressed. PMID:14644805

  2. Ceramics technology for advanced industrial gas turbines

    International Nuclear Information System (INIS)

    Recent developments in the fabrication of high strength ceramic materials and in their application to automotive and aerospace gas turbine engines may lead also to significant improvements in the performance of industrial gas turbines. This paper presents a brief review of the improvements projected in a study initiated by the U.S. Department of Energy. The future costs of power generated by small gas turbines (up to 25 MW) are predicted, as well as the potential for fuel savings. Gas turbines in this size range are used extensively for gas compression and for cogeneration, as well as in a variety of more diverse applications. This paper includes results of analyses of the ways in which changes in gas turbine cost and performance are likely to affect market penetration. These results lead to predictions of future savings in U.S. fuel consumption in the industrial sector that would result. The paper also presents a brief overview of the scope of a suggested R and D program, with an appropriate schedule, which would provide a technical basis for achieving the projected results. Important parts of this program would cover ceramic design and fabrication technology, engine development and demonstration, and combustion technology

  3. Advanced evaporator technology progress report FY 1992

    International Nuclear Information System (INIS)

    This report summarizes the work that was completed in FY 1992 on the program open-quotes Technology Development for Concentrating Process Streams.close quotes The purpose of this program is to evaluate and develop evaporator technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process. Concentrating these streams and minimizing the volume of waste generated can significantly reduce disposal costs; however, equipment to concentrate the streams and recycle the decontaminated condensates must be installed. LICON, Inc., is developing an evaporator that shows a great deal of potential for this application. In this report, concepts that need to be incorporated into the design of an evaporator operated in a radioactive environment are discussed. These concepts include criticality safety, remote operation and maintenance, and materials of construction. Both solubility and vapor-liquid equilibrium data are needed to design an effective process for concentrating process streams. Therefore, literature surveys were completed and are summarized in this report. A model that is being developed to predict vapor phase compositions is described. A laboratory-scale evaporator was purchased and installed to study the evaporation process and to collect additional data. This unit is described in detail. Two new LICON evaporators are being designed for installation at Argonne-East in FY 1993 to process low-level radioactive waste generated throughout the laboratory. They will also provide operating data from a full-sized evaporator processing radioactive solutions. Details on these evaporators are included in this report

  4. Advanced metal-membrane technology-commercialization

    Energy Technology Data Exchange (ETDEWEB)

    Edlund, D.J.

    1995-06-01

    The gasification of coal offers a potentially significant source of hydrogen for use in clean power generation and as a primary chemical feedstock. However, hydrogen derived from coal continues to be more expensive than hydrogen derived from natural gas or petroleum, due in large part to the expense of separating hydrogen from the mixture of gases produced during gasification. At Bend Research, we have been developing a novel hydrogen-permeable metal membrane that promises to be economical for hydrogen separation and purification, including the purification of hydrogen derived from gasifying coal. Furthermore, the membrane is ideally suited for use at high temperatures (200{degrees} to 500{degrees}C), making it feasible to produce pure hydrogen directly from hot gas streams. Through a partnership with Teledyne Wah Chang, we are proceeding with scale-up of prototype membrane modules and field tests to demonstrate the technology to potential users. Additionally, we are working with potential customers to estimate capital savings and operating costs for integrated systems. In this paper, we present some of the operating characteristics of the metal membrane, including its use to drive equilibrium-limited reactions toward complete conversion (e.g., the water-gas-shift reaction). We also describe our activities for commercializing this technology for a variety of applications.

  5. Recent advances in solar photovoltaic technology

    International Nuclear Information System (INIS)

    The current state of the art in recent progress of Japanese photovoltaic activities are overviewed. Firstly, a new strategy for the renewable energy promotion so called Fundamental Principle to promote New Energy Developments and Utilization, and its action planning for PV technology up to year of 2010 are introduced. The program structure and some tangible actions such as tax reduction for investment in the renewable energy plants, government financial support of 2/3 subsidy of PV system developments for public facilities namely as PV Field Test Experiments, and a 1/2 subsidy for the private solar house as PV House Monitor Plan are presented. Secondly, some new topics in the field of solar cell production technology in Japan and also statistics of the solar cell module productions for three kinds of silicon basis solar cells are summarized. Progress of the conversion efficiency in various types of solar cells are also surveyed. In the final part of paper possible new roles to contribute to the global environmental issues by the PV system developments are proposed. (Author)

  6. Brazil advances subsea technology in Marlim pilot

    Energy Technology Data Exchange (ETDEWEB)

    1993-03-29

    Petroleum Brasileiro SA has extended several water depth records for subsea technology during a pilot project in giant Marlim oil field in the Campos basin off Brazil. Petrobras finished the 10 well Marlim pilot last December. The field's pilot phase was intended to begin early production and enable Petrobras to gather more reservoir data. Ten satellite wells, including two prepilot wells, were completed during the Marlim pilot phase with guidelineless (GLL) wet christmas trees designed and fabricated by FMC Corp., Houston, and CBV Industrial Mechanic SA, Rio de Janeiro. The subsea wells are producing 52,000 b/d of oil and 21.19 MMCfd of gas in water depths of 1,847-2,562 ft. Marlim pilot well flow is routed to a permanent semisubmersible floating production system (FPS). Oil moves from the FPS to a monobuoy that offloads to a shuttle tanker. In addition to marking the first successful uses of purpose-built GLL wet trees, FMC said the Marlim pilot project allowed GLL subsea technology to evolve from conceptual status into a proven deepwater completion method. The paper describes the project.

  7. On-wall locomotion technology for advanced robot technology research

    International Nuclear Information System (INIS)

    The robots for extremely severe operation are those doing works in place of men in the environment to which men are unaccessible, for example the high radiation area in nuclear power plants, deep sea where diving is difficult and the high temperature sites due to fires. Agency of Industrial Science and Technology of Ministry of International Trade and Industry has carried out the technical development research on them for eight years from 1983, and the results were published. Wall surface moving technology was studied and developed as one of the elementary technologies for the robots for practical workings in nuclear power facilities. The target of development was the speed of moving on a wall surface of 2 km/h carrying 40 kg load. The development of the elementary technology, the research on the total system and the performance verification test were carried out. The dynamic examination of running adhesion, vacuum seals, the maintenance of stable vacuum, running suckers, the function of the joint trunk, the mechanism of moving on wall surfaces, the handling of the control system for moving on wall surfaces and the control of the transfer from floor to wall, the maintenance of negative pressure and the prevention of fall and the concept of a wall surface robot are reported. (K.I.)

  8. Recent advances in Canadian decontamination technologies

    International Nuclear Information System (INIS)

    From 1973 to 1994, 15 full- and one sub-system decontaminations of CANDU®reactors were carried out using CAN-DECON™ and CAN-DEREM Plus™ processes. The CAN-DECON™ process was developed in the late 1960s and was initially applied in Nuclear Power Demonstration Reactor and Gentilly-1 Nuclear Generating Station on a trial basis, before it was applied as full-system decontamination at Douglas Point in 1975. The decontaminations of the CANDU® reactors, although successful, did highlight some short-comings of the process, and the CAN-DEREM™ and CAN-DEREM Plus™ processes were developed to address these. This paper presents a brief review of the previous decontamination of CANDU® reactors, discussing some key process issues (e.g., carbon steel corrosion, waste volume and low decontamination factors). The paper reviews advances in these decontamination processes, focusing on several major improvements to the process. These include the development of CAN-DEREM™ and CAN-DEREM Plus™ processes to improve process effectiveness, reduction in carbon steel corrosion by use of an effective corrosion inhibitor and the development of a reducing agent to improve process effectiveness. The paper also provides an overview of some of the recent application of the decontamination processes at Chalk River Laboratories, and recent decontamination process qualification for a CANDU® reactor. (author)

  9. Advanced technology for reducing aircraft engine pollution

    Science.gov (United States)

    Jones, R. E.

    1973-01-01

    The proposed EPA regulations covering emissions of gas turbine engines will require extensive combustor development. The NASA is working to develop technology to meet these goals through a wide variety of combustor research programs conducted in-house, by contract, and by university grant. In-house efforts using the swirl-can modular combustor have demonstrated sizable reduction in NO emission levels. Testing to reduce idle pollutants has included the modification of duplex fuel nozzles to air-assisted nozzles and an exploration of the potential improvements possible with combustors using fuel staging and variable geometry. The Experimental Clean Combustor Program, a large contracted effort, is devoted to the testing and development of combustor concepts designed to achieve a large reduction in the levels of all emissions. This effort is planned to be conducted in three phases with the final phase to be an engine demonstration of the best reduced emission concepts.

  10. Advances in solid dosage form manufacturing technology.

    Science.gov (United States)

    Andrews, Gavin P

    2007-12-15

    Currently, the pharmaceutical and healthcare industries are moving through a period of unparalleled change. Major multinational pharmaceutical companies are restructuring, consolidating, merging and more importantly critically assessing their competitiveness to ensure constant growth in an ever-more demanding market where the cost of developing novel products is continuously increasing. The pharmaceutical manufacturing processes currently in existence for the production of solid oral dosage forms are associated with significant disadvantages and in many instances provide many processing problems. Therefore, it is well accepted that there is an increasing need for alternative processes to dramatically improve powder processing, and more importantly to ensure that acceptable, reproducible solid dosage forms can be manufactured. Consequently, pharmaceutical companies are beginning to invest in innovative processes capable of producing solid dosage forms that better meet the needs of the patient while providing efficient manufacturing operations. This article discusses two emerging solid dosage form manufacturing technologies, namely hot-melt extrusion and fluidized hot-melt granulation. PMID:17855217

  11. Advances in Active Radar Seeker Technology

    Directory of Open Access Journals (Sweden)

    Rajatendu Das

    2005-07-01

    Full Text Available Active radar seekers have gained wide applications in the terminal phase of missile guidance to provide hit-to-kill capability. Till recently, coherent monopulse tracker configurations were being used extensively for air-to-air missile seekers as well as surface-to-air missile seekers, while special real-beam technique-based seekers have been employed in antiship and land-attack systems. In this paper, features of active radar seekers have been described against different targets and background conditions to bring out the fact that the seeker design is highly applicationspecific in nature. The emerging trends in radar seeker technology have been identified wrt ever-changing threat scenario coupled with newer electronic countermeasure techniques, including the latest developments in components, subsystems, as well as implementation aspects.

  12. Development of advanced LWR fuel pellet technology

    International Nuclear Information System (INIS)

    A UO2 pellet was designed to have a grain size of larger than 12 μm, and a new duplex design that UO2-Gd2O3 is in the core and UO2-Er2O3 in the periphery was proposed. A master mixing method was developed to make a uniform mixture of UO2 and additives. The open porosity of UO2 pellet was reduced by only mixing AUC-UO2 powder with ADU-UO2 or milled powder. Duplex compaction tools (die and punch) were designed and fabricated, and duplex compacting procedures were developed to fabricate the duplex BA pellet. In UO2 sintering, the relations between sintering variables (additive, sintering gas, sintering temperature) and pellet properties (density, grain size, pore size) were experimentally found. The UO2-U3O8 powder which is inherently not sinterable to high density could be sintered well with the aid of additives. U3O8 single crystals were added to UO2 powder, and homogeneous powder mixture was pressed and sintered in a reducing atmosphere. This technology leads to a large-grained pellet of 12-20 μm. In UO2-Gd2O3 sintering, the relations between sintering variables (additives, sintering gas) and pellet properties (density, grain size) were experimentally found. The developed technology of fabricating a large-grained UO2 pellet has been optimized in a lab scale. Pellet properties were investigated in the fields of (1) creep properties, (2) thermal properties, (3) O/M ratios and (4) unit cell lattice. (author)

  13. Progress in diagnosis of breast cancer: Advances in radiology technology

    Directory of Open Access Journals (Sweden)

    J Mari Beth Linder

    2015-01-01

    Full Text Available Breast cancer is the leading cause of cancer in females between the ages of 15 and 54, and the second leading cause of cancer death in women in the United States. Diagnosis begins with detection by breast examination (clinical breast exam or breast self-exam or by radiologic studies, like mammography. Many advances in the diagnosis of breast cancer have taken place in recent years. This article will review the history of radiologic advances in the diagnosis of breast cancer. Use of technological advancements in digital breast tomosynthesis, magnetic resonance imaging, and ultrasound in breast cancer diagnosis will be presented. Advantages and disadvantages of these diagnostic interventions when compared to older, traditional X-ray films will be discussed. It is important for all nurses, including radiology and oncology nurses, to be well informed about these varied diagnostic modalities, and appreciate the fact that advances in radiologic imaging technologies can yield improved outcomes for breast cancer patients.

  14. Alternative route of process modification for biofuel production by embedding the Fischer-Tropsch plant in existing stand-alone power plant (10 MW) based on biomass gasification - Part I: A conceptual modeling and simulation approach (a case study in Thailand)

    DEFF Research Database (Denmark)

    Hunpinyo, Piyapong; Cheali, Peam; Narataruksa, Phavanee;

    2014-01-01

    sizing incurred several major unit operations is performed for once-through mode (no recycles of unconverted syngas) with electricity co-production. This study provides a detailed base-case model for the synthesis with the capacities of 1, 2 and 3 MW of syngas technology sharing and the comparison......The utilization of syngas shows a highly potential to improve the economic potential of the stand-alone power unit-based gasification plants as well as enhancing the growing demand of transportation fuels. The thermochemical conversion of biomass via gasification to heat and power generations from...

  15. Advanced Mirror Technology Development (AMTD) for Very Large Space Telescopes

    Science.gov (United States)

    Stahl, H. Philip

    2014-01-01

    Advanced Mirror Technology Development (AMTD) is a multi-year effort to systematically mature to TRL-6 the critical technologies needed to produce 4-m or larger flight-qualified UVOIR mirrors by 2018 so that a viable mission can be considered by the 2020 Decadal Review. This technology must enable missions capable of both general astrophysics & ultra-high contrast observations of exoplanets. To accomplish our objective, We use a science-driven systems engineering approach. We mature technologies required to enable the highest priority science AND result in a high-performance low-cost low-risk system.

  16. Interoperable Technologies for Advanced Petascale Simulations (ITAPS)

    Energy Technology Data Exchange (ETDEWEB)

    Shephard, Mark S

    2010-02-05

    Efforts during the past year have contributed to the continued development of the ITAPS interfaces and services as well as specific efforts to support ITAPS applications. The ITAPS interface efforts have two components. The first is working with the ITAPS team on improving the ITAPS software infrastructure and level of compliance of our implementations of ITAPS interfaces (iMesh, iMeshP, iRel and iGeom). The second is being involved with the discussions on the design of the iField fields interface. Efforts to move the ITAPS technologies to petascale computers has identified a number of key technical developments that are required to effectively execute the ITAPS interfaces and services. Research to address these parallel method developments has been a major emphasis of the RPI’s team efforts over the past year. Efforts to move the ITAPS technologies to petascale computers has identified a number of key technical developments that are required to effectively execute the ITAPS interfaces and services. Research to address these parallel method developments has been a major emphasis of the RPI’s team efforts over the past year. The development of parallel unstructured mesh methods has considered the need to scale unstructured mesh solves to massively parallel computers. These efforts, summarized in section 2.1 show that with the addition of the ITAPS procedures described in sections 2.2 and 2.3 we are able to obtain excellent strong scaling with our unstructured mesh CFD code on up to 294,912 cores of IBM Blue Gene/P which is the highest core count machine available. The ITAPS developments that have contributed to the scaling and performance of PHASTA include an iterative migration algorithm to improve the combined region and vertex balance of the mesh partition, which increases scalability, and mesh data reordering, which improves computational performance. The other developments are associated with the further development of the ITAPS parallel unstructured mesh

  17. Development of inherent core technologies for advanced reactor

    International Nuclear Information System (INIS)

    Recently, the developed countries made their effort on developing the advanced reactor which will result in significantly enhanced safety and economy. However, they will protect the advanced reactor and its design technology with patent and proprietary right. Therefore, it is very important to develop our own key core concepts and inherent core design technologies which can form a foundation of indigenous technologies for development of the domestic advanced reactor in order to keep the superiority in the nuclear plant building market among the developing countries. In order to provide the basic technology for the core design of advanced reactor, this project is for developing the inherent core design concepts with enhanced safety and economy, and associated methodologies and technologies for core analyses. The feasibility study of constructing domestic critical facilities are performed by surveying the status and utilization of foreign facilities and by investigating the demand for domestic facilities. The research results developed in this project, such as core analysis methodologies for hexagonal core, conceptual core design based on hexagonal fuel assemblies and soluble boron core design and control strategies, will provide a technical foundation in developing core design of domestic advanced reactor. Furthermore, they will strengthen the competitiveness of Korean nuclear technology. We also expect that some of the design concepts developed in this project to improve the reactor safety and economy can be applicable to the design of advanced reactor. This will significantly reduce the public anxiety on the nuclear power plant, and will contribute to the economy of construction and operation for the future domestic reactors. Even though the critical facility will not be constructed right now, the investigation of the status and utilization of foreign critical facility will contribute to the future critical facility construction. (author). 150 refs., 34 tabs., 103

  18. Development of inherent core technologies for advanced reactor

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Keung Koo; Noh, J.M.; Hwang, D.H. [and others

    1999-03-01

    Recently, the developed countries made their effort on developing the advanced reactor which will result in significantly enhanced safety and economy. However, they will protect the advanced reactor and its design technology with patent and proprietary right. Therefore, it is very important to develop our own key core concepts and inherent core design technologies which can form a foundation of indigenous technologies for development of the domestic advanced reactor in order to keep the superiority in the nuclear plant building market among the developing countries. In order to provide the basic technology for the core design of advanced reactor, this project is for developing the inherent core design concepts with enhanced safety and economy, and associated methodologies and technologies for core analyses. The feasibility study of constructing domestic critical facilities are performed by surveying the status and utilization of foreign facilities and by investigating the demand for domestic facilities. The research results developed in this project, such as core analysis methodologies for hexagonal core, conceptual core design based on hexagonal fuel assemblies and soluble boron core design and control strategies, will provide a technical foundation in developing core design of domestic advanced reactor. Furthermore, they will strengthen the competitiveness of Korean nuclear technology. We also expect that some of the design concepts developed in this project to improve the reactor safety and economy can be applicable to the design of advanced reactor. This will significantly reduce the public anxiety on the nuclear power plant, and will contribute to the economy of construction and operation for the future domestic reactors. Even though the critical facility will not be constructed right now, the investigation of the status and utilization of foreign critical facility will contribute to the future critical facility construction. (author). 150 refs., 34 tabs., 103

  19. Advanced Filter Technology For Nuclear Thermal Propulsion

    Science.gov (United States)

    Castillon, Erick

    2015-01-01

    The Scrubber System focuses on using HEPA filters and carbon filtration to purify the exhaust of a Nuclear Thermal Propulsion engine of its aerosols and radioactive particles; however, new technology may lend itself to alternate filtration options, which may lead to reduction in cost while at the same time have the same filtering, if not greater, filtering capabilities, as its predecessors. Extensive research on various types of filtration methods was conducted with only four showing real promise: ionization, cyclonic separation, classic filtration, and host molecules. With the four methods defined, more research was needed to find the devices suitable for each method. Each filtration option was matched with a device: cyclonic separators for the method of the same name, electrostatic separators for ionization, HEGA filters, and carcerands for the host molecule method. Through many hours of research, the best alternative for aerosol filtration was determined to be the electrostatic precipitator because of its high durability against flow rate and its ability to cleanse up to 99.99% of contaminants as small as 0.001 micron. Carcerands, which are the only alternative to filtering radioactive particles, were found to be non-existent commercially because of their status as a "work in progress" at research institutions. Nevertheless, the conclusions after the research were that HEPA filters is recommended as the best option for filtering aerosols and carbon filtration is best for filtering radioactive particles.

  20. Recent advances in PIM technology I

    Directory of Open Access Journals (Sweden)

    Zlatkov B.S.

    2008-01-01

    Full Text Available In this article the state of art of the PIM (Powder Injection Moulding technology is given in brief. The main process flow diagram consisting of four steps: feedstock preparation, injection moulding (green samples forming, the debinding (binder removing procedure and the sintering process was described. After that the materials for binders and additives for the surface active agents were mentioned in brief. The metal injection moulding (MIM process was analysed in more detail: MIM- stainless steels, MIM-copper and MIM-aluminium as the most metals common in MIM metal parts production. After that our results of MIM stainless steel 316 L and MIM copper are given. The main powder characteristics, the shrinkage and density of the sintered samples were compared for isostatically pressed PM (powder metallurgy samples and MIM formed samples. The SEM fractographs of MIM and PM samples are given for MIM green parts, debinded (brown parts and sintered parts, and PM green parts and sintered parts. The results obtained were compared with literature data before they were applied in metal parts production.