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Sample records for advanced fine coal

  1. Coal surface control for advanced physical fine coal cleaning technologies

    Energy Technology Data Exchange (ETDEWEB)

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-01-01

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO[sub 2] emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  2. Advanced froth flotation techniques for fine coal cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, R.H.; Luttrell, G.H. [Virginia Polytechnic Institute and State Univ., Blacksburg, VA (United States)

    1994-12-31

    Advanced column flotation cells offer many potential advantages for the treatment of fine coal. The most important of these is the ability to achieve high separation efficiencies using only a single stage of processing. Unfortunately, industrial flotation columns often suffer from poor recovery, low throughput and high maintenance requirements as compared to mechanically-agitated conventional cells. These problems can usually be attributed to poorly-designed air sparging systems. This article examines the problems of air sparging in greater detail and offers useful guidelines for designing bubble generators for industrial flotation columns. The application of these principles in the design of a successful advanced fine coal flotation circuit is also presented.

  3. Coal surface control for advanced fine coal flotation

    Energy Technology Data Exchange (ETDEWEB)

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. (California Univ., Berkeley, CA (United States)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (United States)); Hu, W.; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (United States)); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. (Praxis Engineers, Inc., Milpitas, CA (United States))

    1992-03-01

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal's emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  4. Coal surface control for advanced fine coal flotation

    Energy Technology Data Exchange (ETDEWEB)

    Fuerstenau, D.W.; Sastry, K.V.S.; Hanson, J.S.; Harris, G.; Sotillo, F.; Diao, J. (California Univ., Berkeley, CA (USA)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (USA)); Hu, Weibai; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (USA)); Choudhry, V.; Sehgal, R.; Ghosh, A. (Praxis Engineers, Inc., Milpitas, CA (USA))

    1990-08-15

    The primary objective of this research project is to develop advanced flotation methods for coal cleaning in order to achieve near total pyritic-sulfur removal at 90% Btu recovery, using coal samples procured from six major US coal seams. Concomitantly, the ash content of these coals is to be reduced to 6% or less. Work this quarter concentrated on the following: washability studies, which included particle size distribution of the washability samples, and chemical analysis of washability test samples; characterization studies of induction time measurements, correlation between yield, combustible-material recovery (CMR), and heating-value recovery (HVR), and QA/QC for standard flotation tests and coal analyses; surface modification and control including testing of surface-modifying reagents, restoration of hydrophobicity to lab-oxidized coals, pH effects on coal flotation, and depression of pyritic sulfur in which pyrite depression with calcium cyanide and pyrite depression with xanthated reagents was investigated; flotation optimization and circuitry included staged reagent addition, cleaning and scavenging, and scavenging and middling recycling. Weathering studies are also discussed. 19 figs., 28 tabs.

  5. Economic benefits of plant optimization and advanced fine coal cleaning

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    Patwardhan, A.; Honaker, R.Q.; Sevim, H. [Engineering Southern Illinois University-Carbondale, Carbondale, IL (United States). Dept. of Mining and Mineral Resources

    2002-07-01

    Advanced fine coal cleaning (AFCC) technologies such as flotation columns provide metallurgical performances that are superior to those obtained by conventional cleaning devices. However, their implementation into operating preparation plants has been limited due to dewatering and handling concerns and the effect on overall plant economics. To evaluate the impacts of AFCC technologies on overall plant performance, a coal plant model has been developed that optimizes the plant operation based on the constant incremental product quality approach while assessing the improvements in plant mass yield. Also, an empirical model relating the probable error of separation (E{sub p}) to the specific gravity of separation (d{sub 50}) and particle size has been developed for simulating unit operation separation performance. From the analysis of two coal processing plants, the installation of flotation columns for treating the fine coal was found to substantially improve plant yield, and, thus, overall mine profitability over a range of product quality. However, the magnitude of the techno-economical benefits was a function of the feed characteristics, especially particle size-by-size washabilities and inherent moisture. 24 refs., 8 figs., 3 tabs.

  6. Fine coal circuitry using advanced physical cleaning processes

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q.; Mohanty, M.K.; Wang, D. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mining Engineering; Ho, K. [Illinois Clean Coal Inst., Carterville, IL (United States)

    1996-12-31

    Recent investigations have found that enhanced gravity separators (EGS) and flotation columns are highly efficient for cleaning fine coal. The test results presented in this publication show that a circuit comprised of two advanced gravity separators, i.e., a hindered-bed classifier and an EGS, and a flotation column provides an enhanced cleaning efficiency for the treatment of {minus}16 mesh coal. From in-plant experiments, the hindered-bed classifier was found to be a more efficient separation device (E{sub p} = 0.12) than coal spirals (E{sub p} = 0.18) for the treatment of a nominally 16 x 100 mesh coal. Since its efficiency declines for particle sizes less than 48 mesh, the hindered-bed classifier overflow was screened to produce a final +48 mesh concentrate and a {minus}48 mesh fraction that was subsequently treated by circuits incorporating the EGS and flotation column in combination and separately. The best overall circuits in terms of both ash and total sulfur reductions for treating the -16 mesh coal was found to be the Hindered Bed-EGS-EGS and Hindered Bed-EGS-Column circuits. Both circuits rejected over 70% of the ash and over 60% of the pyritic sulfur while recovering over 85% of the combustible material.

  7. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    Energy Technology Data Exchange (ETDEWEB)

    Smit, F.J.; Jha, M.C.; Phillips, D.I.; Yoon, R.H.

    1997-04-25

    The goal of this project is engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. Its scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design and construction of a 2 t/h process development unit (PDU). Large lots of clean coal are to be produced in the PDU from three project coals. Investigation of the near-term applicability of the two advanced fine coal cleaning processes in an existing coal preparation plant is another goal of the project and is the subject of this report.

  8. High quality coal extraction and environmental remediation of fine coal refuse ponds using advanced cleaning technologies

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q.; Mohanty, M.K.; Patwardhan, A. [Department of Mining Engineering, Southern Illinois University-Carbondale, Carbondale, Illinois (United States)

    1998-07-01

    A vast number of coal refuse ponds represent a significant economical resource base that are also considered to be environmentally harmful. Significant amounts of cleanable fine coal generally exist in the refuse ponds due to the inability of conventional technologies to effectively separate the fine coal from the associated gangue particles. In addition, acid generation, generally a result of pyrite oxidation, has potential to adversely affect the surrounding environment. An integrated processing strategy of simultaneously recovering high quality coal and pyrite-rich products from the treatment of a coal refuse pond slurry has been successfully evaluated using an advanced physical cleaning circuit. A clean coal product having ash and pyritic sulfur contents of 10.1% and 0.41% was recovered with a mass yield of nearly 49%. In addition, a pyrite-rich product containing nearly 83% of the coal pyrite particles present in the refuse pond material was generated for neutralization purposes for the environmental remediation of the slurry pond. 4 refs.

  9. POC-scale testing of an advanced fine coal dewatering equipment/technique

    Energy Technology Data Exchange (ETDEWEB)

    Groppo, J.G.; Parekh, B.K. [Univ. of Kentucky, Lexington, KY (United States); Rawls, P. [Department of Energy, Pittsburgh, PA (United States)

    1995-11-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. As the contract title suggests, the main focus of the program is on proof-of-concept testing of a dewatering technique for a fine clean coal product. The coal industry is reluctant to use the advanced fine coal recovery technology due to the non-availability of an economical dewatering process. in fact, in a recent survey conducted by U.S. DOE and Battelle, dewatering of fine clean coal was identified as the number one priority for the coal industry. This project will attempt to demonstrate an efficient and economic fine clean coal slurry dewatering process.

  10. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO[sub 2] per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO[sub 2] emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  11. Coal surface control for advanced physical fine coal cleaning technologies. Final report, September 19, 1988--August 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-12-31

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO{sub 2} emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R&D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  12. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    Energy Technology Data Exchange (ETDEWEB)

    Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-08-28

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction and operation of 2 t/hr process development unit (PDU). This report represents the findings of the PDU Advanced Column Flotation Testing and Evaluation phase of the program and includes a discussion of the design and construction of the PDU. Three compliance steam coals, Taggart, Indiana VII and Hiawatha, were processed in the PDU to determine performance and design parameters for commercial production of premium fuel by advanced flotation. Consistent, reliable performance of the PDU was demonstrated by 72-hr production runs on each of the test coals. Its capacity generally was limited by the dewatering capacity of the clean coal filters during the production runs rather than by the flotation capacity of the Microcel column. The residual concentrations of As, Pb, and Cl were reduced by at least 25% on a heating value basis from their concentrations in the test coals. The reduction in the concentrations of Be, Cd, Cr, Co, Mn, Hg, Ni and Se varied from coal to coal but the concentrations of most were greatly reduced from the concentrations in the ROM parent coals. The ash fusion temperatures of the Taggart and Indiana VII coals, and to a much lesser extent the Hiawatha coal, were decreased by the cleaning.

  13. An Advanced Control System for Fine Coal Floatation

    Energy Technology Data Exchange (ETDEWEB)

    Luttrell, G H; Adel, G T

    1998-06-01

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of ash content. Then, based on the economic and metallurgical performance of the circuit, variables such as collector dosage, frother dosage, and pulp level are adjusted using model-based control algorithms to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the eighth quarter of this project, the analysis of data collected during Task 2 (Sampling and Data Analysis) was completed, and significant progress was made on Task 3 (Model Building and Computer Simulation). Previously, a plant sampling campaign had been conducted at Pittston's Moss No. 3 preparation plant to provide data for the development of a mathematical process model and a model-based control system. During this campaign, a one-half factorial design experiment, blocked into low and high feed rates, was conducted to investigate the effects of collector, frother, and pulp level on model parameters. In addition, samples were collected during the transient period following each change in the manipulated variables to provide data for confirmation of the dynamic process simulator. A residence time distribution (RTD) test was also conducted to estimate the mean residence time. This is a critical piece of information since no feed flowrate measurement is available, and the mean residence time can be used to estimate the feed flowrate. Feed samples were taken at timed intervals and floated in a laboratory flotation cell to investigate the magnitude of feed property disturbances and their duration.

  14. Advanced physical fine coal cleaning spherical agglomeration. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1990-09-01

    The project included process development, engineering, construction, and operation of a 1/3 tph proof-of-concept (POC) spherical agglomeration test module. The POC tests demonstrated that physical cleaning of ultrafine coal by agglomeration using heptane can achieve: (1) Pyritic sulfur reductions beyond that possible with conventional coal cleaning methods; (2) coal ash contents below those which can be obtained by conventional coal cleaning methods at comparable energy recoveries; (3) energy recoveries of 80 percent or greater measured against the raw coal energy content; (4) complete recovery of the heptane bridging liquid from the agglomerates; and (5) production of agglomerates with 3/8-inch size and less than 30 percent moisture. Test results met or exceeded all of the program objectives. Nominal 3/8-inch size agglomerates with less than 20 percent moisture were produced. The clean coal ash content varied between 1.5 to 5.5 percent by weight (dry basis) depending on feed coal type. Ash reductions of the run-of-mine (ROM) coal were 77 to 83 percent. ROM pyritic sulfur reductions varied from 86 to 90 percent for the three test coals, equating to total sulfur reductions of 47 to 72 percent.

  15. Coal surface control for advanced fine coal flotation. Final report, October 1, 1988--March 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. [California Univ., Berkeley, CA (United States); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. [Columbia Univ., New York, NY (United States); Hu, W.; Zou, Y.; Chen, W. [Utah Univ., Salt Lake City, UT (United States); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. [Praxis Engineers, Inc., Milpitas, CA (United States)

    1992-03-01

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal`s emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  16. Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications

    Energy Technology Data Exchange (ETDEWEB)

    Smit, Frank J; Schields, Gene L; Jha, Mehesh C; Moro, Nick

    1997-09-26

    The ash in six common bituminous coals, Taggart, Winifrede, Elkhorn No. 3, Indiana VII, Sunnyside and Hiawatha, could be liberated by fine grinding to allow preparation of clean coal meeting premium fuel specifications (< 1- 2 lb/ MBtu ash and <0.6 lb/ MBtu sulfur) by laboratory and bench- scale column flotation or selective agglomeration. Over 2,100 tons of coal were cleaned in the PDU at feed rates between 2,500 and 6,000 lb/ h by Microcel™ column flotation and by selective agglomeration using recycled heptane as the bridging liquid. Parametric testing of each process and 72- hr productions runs were completed on each of the three test coals. The following results were achieved after optimization of the operating parameters: The primary objective was to develop the design base for commercial fine coal cleaning facilities for producing ultra- clean coals which can be converted into coal-water slurry premium fuel. The coal cleaning technologies to be developed were advanced column flotation and selective agglomeration, and the goal was to produce fuel meeting the following specifications.

  17. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    Energy Technology Data Exchange (ETDEWEB)

    1990-01-01

    An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. This is being accomplished by utilization the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. The conceptual flowsheet must be examined to identify critical areas that need additional design data. This data will then be developed using batch and semi-continuous bench scale testing. In addition to actual bench scale testing other unit operations from other industries processing fine material will be reviewed for potential application and incorporated into the design if appropriate. 31 figs., 22 tabs.

  18. ENGINEERING DEVELOPMENT OF ADVANCED PHYSICAL FINE COAL CLEANING FOR PREMIUM FUEL APPLICATIONS

    Energy Technology Data Exchange (ETDEWEB)

    none,

    1997-06-01

    Bechtel, together with Amax Research and Development Center (Amax R&D), has prepared this study which provides conceptual cost estimates for the production of premium quality coal-water slurry fuel (CWF) in a commercial plant. Two scenarios are presented, one using column flotation technology and the other the selective agglomeration to clean the coal to the required quality specifications. This study forms part of US Department of Energy program "Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications," (Contract No. DE-AC22- 92PC92208), under Task 11, Project Final Report. The primary objective of the Department of Energy program is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to stable and highly loaded CWF. The fuels should contain less than 2 lb ash/MBtu (860 grams ash/GJ) of HHV and preferably less than 1 lb ash/MBtu (430 grams ash/GJ). The advanced fine coal cleaning technologies to be employed are advanced column froth flotation and selective agglomeration. It is further stipulated that operating conditions during the advanced cleaning process should recover not less than 80 percent of the carbon content (heating value) in the run-of-mine source coal. These goals for ultra-clean coal quality are to be met under the constraint that annualized coal production costs does not exceed $2.5 /MBtu ($ 2.37/GJ), including the mine mouth cost of the raw coal. A further objective of the program is to determine the distribution of a selected suite of eleven toxic trace elements between product CWF and the refuse stream of the cleaning processes. Laboratory, bench-scale and Process Development Unit (PDU) tests to evaluate advanced column flotation and selective agglomeration were completed earlier under this program with selected coal samples. A PDU with a capacity of 2 st/h was designed by Bechtel and installed at Amax R

  19. Engineering development of advance physical fine coal cleaning for premium fuel applications

    Energy Technology Data Exchange (ETDEWEB)

    Jha, M.C.; Smit, F.J.; Shields, G.L. [AMAX R& D Center/ENTECH Global Inc., Golden, CO (United States)

    1995-11-01

    The objective of this project is to develop the engineering design base for prototype fine coal cleaning plants based on Advanced Column Flotation and Selective Agglomeration processes for premium fuel and near-term applications. Removal of toxic trace elements is also being investigated. The scope of the project includes laboratory research and bench-scale testing of each process on six coals followed by design, construction, and operation of a 2 tons/hour process development unit (PDU). Three coals will be cleaned in tonnage quantity and provided to DOE and its contractors for combustion evaluation. Amax R&D (now a subsidiary of Cyprus Amax Mineral Company) is the prime contractor. Entech Global is managing the project and performing most of the research and development work as an on-site subcontractor. Other participants in the project are Cyprus Amax Coal Company, Arcanum, Bechtel, TIC, University of Kentucky and Virginia Tech. Drs. Keller of Syracuse and Dooher of Adelphi University are consultants.

  20. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly report, April 1--June 30, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-12-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). Accomplishments during the quarter are described on the following tasks and subtasks: Development of near-term applications (engineering development and dewatering studies); Engineering development of selective agglomeration (bench-scale testing and process scale-up); PDU and advanced column flotation module (coal selection and procurement and advanced flotation topical report); Selective agglomeration module (module operation and clean coal production with Hiawatha, Taggart, and Indiana 7 coals); Disposition of the PDU; and Project final report. Plans for next quarter are discussed and agglomeration results of the three tested coals are presented.

  1. Engineering development of advanced physical fine coal cleaning technologies - froth flotation

    Energy Technology Data Exchange (ETDEWEB)

    Ferris, D.D.; Bencho, J.R. [ICF Kaiser Engineers, Inc., Pittsburgh, PA (United States)

    1995-11-01

    In 1988, ICF Kaiser Engineers was awarded DOE Contract No. DE-AC22-88PC88881 to research, develop, engineer and design a commercially acceptable advanced froth flotation coal cleaning technology. The DOE initiative is in support of the continued utilization of our most abundant energy resource. Besides the goal of commercialability, coal cleaning performance and product quality goals were established by the DOE for this and similar projects. primary among these were the goals of 85 percent energy recovery and 85 percent pyrite rejection. Three nationally important coal resources were used for this project: the Pittsburgh No. 8 coal, the Upper Freeport coal, and the Illinois No. 6 coal. Following is a summary of the key findings of this project.

  2. POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE

    Energy Technology Data Exchange (ETDEWEB)

    X.H. Wang; J. Wiseman; D.J. Sung; D. McLean; William Peters; Jim Mullins; John Hugh; G. Evans; Vince Hamilton; Kenneth Robinette; Tim Krim; Michael Fleet

    1999-08-01

    Dewatering of ultra-fine (minus 150 {micro}m) coal slurry to less than 20% moisture is difficult using the conventional dewatering techniques. The main objective of the project was to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions and surfactants in combination for the dewatering of ultra-fine clean-coal slurries using various dewatering techniques on a proof-of-concept (POC) scale of 0.5 to 2 tons per hour. The addition of conventional reagents and the application of coal surface modification technique were evaluated using vacuum filtration, hyperbaric (pressure) filtration, ceramic plate filtration and screen-bowl centrifuge techniques. The laboratory and pilot-scale dewatering studies were conducted using the fine-size, clean-coal slurry produced in the column flotation circuit at the Powell Mountain Coal Company, St. Charles, VA. The pilot-scale studies were conducted at the Mayflower preparation plant in St. Charles, VA. The program consisted of nine tasks, namely, Task 1--Project Work Planning, Task 2--Laboratory Testing, Task 3--Engineering Design, Task 4--Procurement and Fabrication, Task 5--Installation and Shakedown, Task 6--System Operation, Task 7--Process Evaluation, Task 8--Equipment Removal, and Task 9--Reporting.

  3. Comparative economics, of advanced fine-coal cleaning in refuse pond recovery and active mine applications

    Energy Technology Data Exchange (ETDEWEB)

    Patwardhan, A.; Chugh, Y.P; Mohanty, M.K.; Sevim, H. [South Illinois University, Carbondale, IL (United States). Dept. of Mining & Mineral Resources

    2003-08-01

    The economics of 'conventional' and 'advanced fine-coal cleaning' (AFCC) circuits for refuse pond reclamation as well as active mine applications were evaluated. The benefit of an innovative tailings-management scheme on the profitability of mining enterprises was also evaluated. Analyses were conducted for two scenarios involving the generation of 5.81% product ash, a quality obtained during AFCC circuit operation at SIU, and a more typical 8% product ash. The inability of the conventional circuits to achieve profitability while producing the lower-ash product is revealed from this approach. On the other hand, the AFCC circuits achieve a return on investment in excess of 50% in the water-only mode as well as the dense-medium mode, both with and without tailings management. The comparison of water-only and dense-medium applications of the AFCC circuit indicates a better suitability for the dense-medium circuit for producing premium-quality products. As a result of reduced overhead costs and the use of existing material-handling facilities, the application of AFCC circuits in active mines provides for better economics when compared to applications in refuse pond recovery operations. Sensitivity analysis reveals the significance of capacity utilization on project economics.

  4. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 16, July 1, 1992--September 30, 1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-31

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  5. Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications: Task 9 - Selective agglomeration Module Testing and Evaluation.

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.` Jha, M.C.

    1997-09-29

    The primary goal of this project was the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and bench-scale testing of both processes on six coals to optimize the processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by September 1997. This report summarizes the findings of all the selective agglomeration (SA) test work performed with emphasis on the results of the PDU SA Module testing. Two light hydrocarbons, heptane and pentane, were tested as agglomerants in the laboratory research program which investigated two reactor design concepts: a conventional two-stage agglomeration circuit and a unitized reactor that combined the high- and low-shear operations in one vessel. The results were used to design and build a 25 lb/hr bench-scale unit with two-stage agglomeration. The unit also included a steam stripping and condensation circuit for recovery and recycle of heptane. It was tested on six coals to determine the optimum grind and other process conditions that resulted in the recovery of about 99% of the energy while producing low ash (1-2 lb/MBtu) products. The fineness of the grind was the most important variable with the D80 (80% passing size) varying in the 12 to 68 micron range. All the clean coals could be formulated into coal-water-slurry-fuels with acceptable properties. The bench-scale results were used for the conceptual and detailed design of the PDU SA Module which was integrated with the existing grinding and dewatering circuits. The PDU was operated for about 9 months. During the first three months, the shakedown testing was performed to fine tune the operation and control of various equipment. This was followed by parametric testing, optimization/confirmatory testing, and finally a

  6. Pyrite surface characterization and control for advanced fine coal desulfurization technologies

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xiang-Huai.

    1991-01-01

    The objective of this project is to conduct extensive studies on the surface reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of pyrite rejection in coal flotation. The products as well as their structure, the mechanisms and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. The surface chemical studies and the studies of floatability of coal-pyrite and the effect of various parameters such as grinding media and environment, aging under different atmospheres, etc. on thereof, are directed at identifying the causes and possible solutions of the pyrite rejection problems in coal cleaning.

  7. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report 2, January 1995--March 1995

    Energy Technology Data Exchange (ETDEWEB)

    Groppo, J.G.; Parekh, B.K.

    1995-05-05

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1 to March 31, 1995.

  8. Recent Advances in Precombustion Coal Cleaning Processes

    Institute of Scientific and Technical Information of China (English)

    Shiao-HungChiang; DaxinHe

    1994-01-01

    The mineral matter in coal constitutes a major impediment to the direct use of coal in power plants.A concerted effort has been mounted to reduce the ash/sulfur contents in product coal to meet the ever more stringent environmental regulations.In recent years,significant advances have taken place in fine coal cleaning technologies.A review of recent developments in aveanced physical,chemical and biological processes for deep-cleaning of fine coal is presented.

  9. Pelletization of fine coals. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Sastry, K.V.S.

    1995-12-31

    Coal is one of the most abundant energy resources in the US with nearly 800 million tons of it being mined annually. Process and environmental demands for low-ash, low-sulfur coals and economic constraints for high productivity are leading the coal industry to use such modern mining methods as longwall mining and such newer coal processing techniques as froth flotation, oil agglomeration, chemical cleaning and synthetic fuel production. All these processes are faced with one common problem area--fine coals. Dealing effectively with these fine coals during handling, storage, transportation, and/or processing continues to be a challenge facing the industry. Agglomeration by the unit operation of pelletization consists of tumbling moist fines in drums or discs. Past experimental work and limited commercial practice have shown that pelletization can alleviate the problems associated with fine coals. However, it was recognized that there exists a serious need for delineating the fundamental principles of fine coal pelletization. Accordingly, a research program has been carried involving four specific topics: (i) experimental investigation of coal pelletization kinetics, (ii) understanding the surface principles of coal pelletization, (iii) modeling of coal pelletization processes, and (iv) simulation of fine coal pelletization circuits. This report summarizes the major findings and provides relevant details of the research effort.

  10. AQUEOUS BIPHASE EXTRACTION FOR PROCESSING OF FINE COAL

    Energy Technology Data Exchange (ETDEWEB)

    K. Osseo-Asare; X. Zeng

    2002-01-01

    The objective of this research project is to develop an aqueous biphase extraction process for the treatment of fine coals. Aqueous biphase extraction is an advanced separation technology that relies on the ability of an aqueous system consisting of a water-soluble polymer and another component, e.g., another polymer, an inorganic salt, or a nonionic surfactant, to separate into two immiscible aqueous phases. The principle behind the partition of solid particles in aqueous biphase systems is the physicochemical interaction between the solid surface and the surrounding liquid solution. In order to remove sulfur and mineral matter from fine coal with aqueous biphasic extraction, it is necessary to know the partitioning behavior of coal, as well as the inorganic mineral components. Therefore, in this research emphasis was placed on the partitioning behavior of fine coal particles as well as model fine inorganic particles in aqueous biphase systems.

  11. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 12, July--September 1995

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-10-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction and operation of a 2-t/hr process development unit. The project began in October, 1992, and is scheduled for completion by June, 1997. During Quarter 12 (July--September 1995), work continued on the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at Lady Dunn. Under Subtask 4.4, additional toxic trace element analysis of column flotation samples finalized the data set. Data analysis indicates that reasonably good mass balances were achieved for most elements. The final Subtask 6.3 Selective Agglomeration Process Optimization topical report was issued this quarter. Preliminary Subtask 6.4 work investigating coal-water-fuel slurry formulation indicated that selective agglomeration products formulate slurries with lower viscosities than advanced flotation products. Work continued on Subtask 6.5 agglomeration bench-scale testing. Results indicate that a 2 lb ash/MBtu product could be produced at a 100-mesh topsize with the Elkhorn No. 3 coal. The detailed design of the 2 t/hr selective agglomeration module neared completion this quarter with the completion of additional revisions of both the process flow, and the process piping and instrument diagrams. Construction of the 2 t/hr PDU and advanced flotation module was completed this quarter and startup and shakedown testing began.

  12. Process for treating moisture laden coal fines

    Science.gov (United States)

    Davis, Burl E.; Henry, Raymond M.; Trivett, Gordon S.; Albaugh, Edgar W.

    1993-01-01

    A process is provided for making a free flowing granular product from moisture laden caked coal fines, such as wet cake, by mixing a water immiscible substance, such as oil, with the caked coal, preferably under low shear forces for a period of time sufficient to produce a plurality of free flowing granules. Each granule is preferably comprised of a dry appearing admixture of one or more coal particle, 2-50% by weight water and the water immiscible substance.

  13. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 9, October 1, 1994--December 31, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C. [AMAX Research and Development Center, Golden, CO (United States)

    1995-01-25

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 ton lots of each of three project coals, by each process. The project began in October, 1992 and is scheduled for completion by March, 1997. During Quarter 9 (October--December, 1995), parametric and optimization testing was completed for the Taggart, Sunnyside, and Indiana VII coal using a 12-inch Microcel{trademark} flotation column. The detailed design of the 2-t/hr PDU grinding, flotation, and dewatering circuits neared completion with the specification of the major pieces of capital equipment to be purchased for these areas. Selective agglomeration test work investigated the properties of various industrial grades of heptane for use during bench- and PDU-scale testing. It was decided to use a hydrotreated grade of commercial heptane due to its low cost and low concentration of aromatic compounds. The final Subtask 6.4 CWF Formulation Studies Test Plan was issued. A draft version of the Subtask 6.5 Preliminary Design and Test Plan Report was also issued, discussing the progress made in the design of the bench-scale selective agglomeration unit. PDU construction work moved forward through the issuing of 26 request for quotations and 21 award packages for capital equipment.

  14. Dewatering of fine coal using hyperbaric centrifugation

    Energy Technology Data Exchange (ETDEWEB)

    Ramazan Asmatulu; Gerald H. Luttrell; Roe-Hoan Yoon [Virginia Polytechnic Institute and State University, Blacksburg, VA (US). Center for Advanced Separation Technologies

    2005-09-01

    Many coal preparation plants are forced to discard their fine coal because of the inability of existing technologies to reduce the moisture content of this product to an acceptable level. In an effort to overcome this problem, a new mechanical dewatering method has been developed that combines centrifugation with pressure filtration. The process, which may be referred to as hyperbaric centrifugation, is capable of producing a drier product than can be achieved using either filtration or centrifugation alone. The test data obtained from batch experiments show that the new method can reduce cake moisture to 10% or below for many fine coal product streams.

  15. Evaluation of a novel fine coal dry cleaning process at Greenfields Coal Company

    Energy Technology Data Exchange (ETDEWEB)

    Bratton, R.; Luttrell, G.; Kasindorf, H.; McGraw, G.; Robbins, R. [Virginia Polytechnic Institute & State University, Blacksburg, VA (United States)

    2010-07-01

    Coal mining and processing operations have in the past and continue to create large tonnages of fine coal and waste particles. While technological advances in wet processing has made it possible to efficiently recover coal fines, difficulties associated with dewatering make these fine particles unattractive economically for most coal markets. A novel system has been developed for cleaning fine raw coal utilizing a multistage dry classification process that removes the clay particles that are typically much smaller than the majority of the clean coal particles and that reduces the product surface moisture to as low as 1%. In this article, the novel dry coal-cleaning process under license to Greenfields Coal Company was evaluated. The classification process offers a viable alternative to traditional wet processing and dewatering of the fine particles, especially for operations recovering abandoned impoundments where a sufficient water source and/or a waste slurry disposal site are unavailable. This article presents the separation performance and operating results obtained from field testing with a 2t/hr pilot-scale unit located at an abandoned impoundment in southern West Virginia.

  16. Pyrite surface characterization and control for advanced fine coal desulfurization technologies. First annual report, September 1, 1990--August 30, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xiang-Huai

    1991-12-31

    The objective of this project is to conduct extensive studies on the surface reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of pyrite rejection in coal flotation. The products as well as their structure, the mechanisms and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. The surface chemical studies and the studies of floatability of coal-pyrite and the effect of various parameters such as grinding media and environment, aging under different atmospheres, etc. on thereof, are directed at identifying the causes and possible solutions of the pyrite rejection problems in coal cleaning.

  17. Advanced development of fine coal desulfurization and recovery technology. Quarterly technical progress report, October 1, 1976--December 31, 1976. [53 references

    Energy Technology Data Exchange (ETDEWEB)

    Fisher, R.W.; Wheelock, T.D.

    1977-02-01

    The improvement and technical development of promising methods for desulfurizing and recovering fine coal underway includes froth flotation, selective oil agglomeration, pelletization, and a chemical desulfurization process which involves leaching fine coal with a hot dilute solution of sodium carbonate containing dissolved oxygen under pressure. A preliminary assessment of the state of the art and review of the technical literature has been made. Equipment and apparatus have been assembled for small-scale laboratory experiments in froth flotation, oil agglomeration and chemical desulfurization. Preliminary froth flotation tests have been carried out on an Iowa coal to establish baseline data. Quite unexpectedly these tests indicated that aluminum nitrate may be an activator for coal because it served to increase the recovery of coal. Several potential flotation depressants for pyrite have been screened by measurement at the zeta potential and floatability of pyrite or coal in aqueous suspensions containing the potential depressants. The following reagents show some promise as pyrite depressants: ferric chloride, sodium cyanide, ammonium thiocyanate, and the disodium salt of ethylenediaminetetraacetic acid. Preliminary plans have been prepared for a continuous flow bench-scale system to demonstrate the process. This system will include equipment for grinding and pretreating the coal as well as equipment for demonstrating froth flotation, selective oil agglomeration and pelletization. An investigation of coal microstructure as it relates to coal beneficiation methods has also been initiated. The distribution of various forms of pyrite by size and crystal structure has been determined for two cannel samples of coal through application of scanning electron microscope techniques.

  18. Advanced reclamation of coal refuse ponds

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q.; Chugh, Y.P.; Patwardhan, A. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mining and Mineral Resources Engineering

    1998-12-31

    A vast number of coal refuse ponds represent a significant economical resource base that may also be considered to be environmentally harmful. The fine coal fraction in a preparation plant consists of the purest particles in the entire preparation plant and, thus, if recovered, could enhance the quality of the plant product. However, until recently, the ability to effectively recover fine coal has been limited due to the lack of efficient fine particle separation technologies. As a result, a large portion of the fine coal produced in the US during this century has been disposed into refuse pond along with the acid producing components of the associated gangue material. Research conducted by Southern Illinois University scientists has found that advanced fine coal cleaning technologies can be used to recover high quality coal from refuse ponds while also utilizing a novel technique for neutralizing the acid generation potential of the pyrite-rich reject stream. Various circuitry arrangements will be discussed and metallurgical results presented in this publication.

  19. Advanced Fine Particulate Characterization Methods

    Energy Technology Data Exchange (ETDEWEB)

    Steven Benson; Lingbu Kong; Alexander Azenkeng; Jason Laumb; Robert Jensen; Edwin Olson; Jill MacKenzie; A.M. Rokanuzzaman

    2007-01-31

    The characterization and control of emissions from combustion sources are of significant importance in improving local and regional air quality. Such emissions include fine particulate matter, organic carbon compounds, and NO{sub x} and SO{sub 2} gases, along with mercury and other toxic metals. This project involved four activities including Further Development of Analytical Techniques for PM{sub 10} and PM{sub 2.5} Characterization and Source Apportionment and Management, Organic Carbonaceous Particulate and Metal Speciation for Source Apportionment Studies, Quantum Modeling, and High-Potassium Carbon Production with Biomass-Coal Blending. The key accomplishments included the development of improved automated methods to characterize the inorganic and organic components particulate matter. The methods involved the use of scanning electron microscopy and x-ray microanalysis for the inorganic fraction and a combination of extractive methods combined with near-edge x-ray absorption fine structure to characterize the organic fraction. These methods have direction application for source apportionment studies of PM because they provide detailed inorganic analysis along with total organic and elemental carbon (OC/EC) quantification. Quantum modeling using density functional theory (DFT) calculations was used to further elucidate a recently developed mechanistic model for mercury speciation in coal combustion systems and interactions on activated carbon. Reaction energies, enthalpies, free energies and binding energies of Hg species to the prototype molecules were derived from the data obtained in these calculations. Bimolecular rate constants for the various elementary steps in the mechanism have been estimated using the hard-sphere collision theory approximation, and the results seem to indicate that extremely fast kinetics could be involved in these surface reactions. Activated carbon was produced from a blend of lignite coal from the Center Mine in North Dakota and

  20. Fine coal measurement needs for improved control

    Energy Technology Data Exchange (ETDEWEB)

    Firth, B.; O' Brien, M. [CSIRO, Brisbane, Qld. (Australia). Division of Energy Technology

    2010-07-01

    The monitoring and management of fine coal circuits in coal preparation plants is limited in current practice. As part of the Australian Coal Association Research Program (ACARP) Intelligent Plant Project (C11069), the relationships between the main operational and control factors for the unit operations and the circuit and the performance indicators have been identified. The unit operations examined included desliming (hydrocyclones and sieve bends), small coal cleaning (spirals and hydraulic separators), flotation, and dewatering (vacuum filters, centrifuges, and thickeners). These relationships were then used to assist in the identification of the important parameters to be measured and the preferred level of accuracy required to be useful. An important issue was the interconnection between the various unit operations and the potential impact of an upstream problem on the subsequent performance of downstream units. Analysis with the relationships showed that the flow rate of respective feed slurries and the solids content were found to be significant variables. This article will discuss this analysis and provide some case studies.

  1. Plant practices in fine coal column flotation

    Energy Technology Data Exchange (ETDEWEB)

    Davis, V.L. Jr.; Bethell, P.J.; Stanley, F.L. [Pittston Coal Management Co., Lebanon, VA (United States); Luttrell, G.H. [Virginia Polytechnic Institute and State Univ., Blacksburg, VA (United States). Dept. of Mining and Minerals Engineering

    1995-10-01

    Five 3 m (10 ft) diameter Microcel{trademark} flotation columns were installed at Clinchfield Coal Company`s Middle Fork preparation facility in order to reduce product ash and increase recovery and plant capacity. The Middle Fork facility is utilized for the recovery of fine coal from a feed stream that consists primarily of 1.5 mm x 0 material. The columns replaced conventional flotation cells for the treatment of the minus 150 {micro}m fraction while spirals are used to upgrade the plus 150 {micro}m material in the plant feed. The addition of the column flotation circuit resulted in an increase in plant capacity in excess of 20 percent while reducing the flotation product ash content by approximately 7 percentage points. Flotation circuit combustible recovery wa increased by 17 percentage points. This paper discusses circuit design, commissioning, and sparging system design. Circuit instrumentation, level control, reagent system control, performance comparisons with conventional flotation, and general operating procedures are also discussed.

  2. Improvement of storage, handling, and transportability of fine coal. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Maxwell, R.C. Jr.; Jamison, P.R.

    1996-03-01

    The Mulled Coal process is a technology which has evolved from a line of investigations which began in the 1970`s. There was a major breakthrough in 1990, and since then, with significant support from DOE-PETC, the technology has progressed from the conceptual stage to a proven laboratory process. It is a simple process which involves the addition of a low cost specifically formulated reagent to wet fine coal by mixing the two in a pug mill. Although the converted material (Mulled Coal) retains some of its original surface moisture, it handles, transports, and stores like dry coal. But, unlike thermally dried fine coal Mulled Coal is not dusty, it will not rewet, and it causes no fugitive dust problems. This project was designed to advance the technology from the status of a process which works well in the laboratory to the status of a technology which is fully ready for commercialization. Project objectives were to: 1. Prove the concept that the technology can be used to produce Mulled Coal of a consistent quality, on a continuous basis, at a convincing rate of production, and at a major preparation plant which produces fine clean coal on a commercial basis. 2. Prove the concept that Mulled Coal, either as a blend with coarser clean coal or as a stand-alone fuel will successfully pass through a representative cross section of conventional coal storage, handling and transportation environments without causing any of the problems normally associated with wet fine coal. 3 Test the design and reliability of Mulled Coal circuit equipment and controls. 4. Test the circuit over a wide range of operating conditions. 5. Project scale-up designs for major equipment components and control circuits. 6. Forecast capital and operating costs for commercial circuits ranging from 25 TPH to 75 TPH. This report describes the work, the test results, and conclusions at each step along the way.

  3. Carbon burnout project-coal fineness effects

    Energy Technology Data Exchange (ETDEWEB)

    Mike Celechin [Powergen UK plc, Nottingham (United Kingdom)

    2004-02-01

    The aim of this DTI project is to establish good quality plant and rig data to demonstrate the effect of changing coal fineness on carbon burnout in a controlled manner, which can then be used to support computational fluid dynamics (CFD) and engineering models of the process. The modelling elements of the project were completed by Mitsui Babcock Energy Ltd., and validated using the data produced by the other partners. The full scale plant trials were successfully completed at Powergen's Kingsnorth Power Station and a full set of tests were also completed on Powergen's CTF. During these test both carbon-in-ash and NOx levels were seen to increase with increasing fuel particle size. Laboratory analysis of fly ash produced during the plant and rig trials revealed that only small differences in char morphology and reactivity could be detected in samples produced under significantly different operating conditions. Thermo Gravimetric Analysis was also undertaken on a range of PF size fractions collected form mills operating at different conditions. 3 refs., 13 figs., 1 tab.

  4. Surface Modification Mechanism of Fine Coal by Electrochemical Methods

    Institute of Scientific and Technical Information of China (English)

    ZHU Hong; WANG Fang-hui; WANG Dian-zuo; OU Ze-shen

    2006-01-01

    In order to reveal the surface modification mechanism of fine coal by electrochemical methods, the structural changes of the coal surface before and after electrochemical modification were investigated by Fourier Transform Infrared Spectra (FTIR) and Raman Spectra. The results show that under certain electrochemical conditions, the oxygen-containing functional group in the coal structure and the oxygen content of absorption could be reduced and the floatability of coal improved. At the same time, the sulfur in the coal was reduced to the hydrophilic S2- which could be separated easily from coal. Thus electrochemical modification methods could be used to change the structure and functional group on the coal surface and to enhance the floatability of coal.

  5. Recovery bituminous coal fines: a discussion on the production of coal-water slurry fuels and its relationship to fine coal cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Morrison, J.L.; Scaroni, A.W.; Battista, J.J. [Pennsylvania State University, University Park, PA (United States)

    1998-12-31

    The recovery of bituminous coal fines from slurry impoundments and fine coal cleaning circuits has received considerable attention over the last decade from both coal suppliers and coal-fired utilities. Several coal-fired utilities are presently determining whether a low-solids, low viscosity coal-water slurry fuel (CWSF) produced from fine coal can be co-fired with their normal coal feedstock in order to lower their fuel cost and reduce their NO{sub x} emissions. One of the most visible CWSF demonstration programs in the United States is being conducted by GPU Generating, Inc. (GPU Genco). GPU Genco has conducted intermittent demonstration co-fire testing at their 218 MWe-Seward Station since 1993. These tests successfully demonstrate that a low-solids CWSF can be co-fired with pulverized coal in wall-and tangentially-fired boilers. The majority of the CWSF tested at Seward has been prepared from impounded coal fines cleaned via froth flotation and, on a more limited basis, a CWSF prepared from coal fines concentrated from a screen-bowl centrifuge effluent. The production of alow-solids CWSF from wet, fine coal provides an alternative to dewatering. This paper summarizes several fine coal recovery and utilization programs conducted by Pennsylvania State University (Penn State) and GPU Genco during the last five years. These programs range from performing bench-to-pilot-scale cleanability and pilot-scale combustion testing to full-scale utility demonstration tests. All of these successful programs have a common thread of integrating and addressing the issues of fine coal characterization, cleaning handling, and the combustion performance of the CWSF. 8 refs., 1 fig., 1 tab.

  6. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T. [Virginia Polytechnic Institute and State Univ., Blacksburg, VA (United States)

    1995-11-01

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both the ash and sulfur contents of run-of-mine coals. The extent of cleaning depends on the liberation characteristics of the coal, which generally improve with reducing particle size. however, since most of the advanced technologies are wet processes, the clean coal product must be dewatered before it can be transported and burned in conventional boilers. This additional treatment step significantly increases the processing cost and makes the industrial applicability of these advanced technologies much less attractive. In order to avoid problems associated with fine coal dewatering, researchers at the Pittsburgh Energy Technology Center (PETC) developed a novel triboelectrostatic separation (TES) process that can remove mineral matter from dry coal. In this technique, finely pulverized coal is brought into contact with a material (such as copper) having a work function intermediate to that of the carbonaceous material and associated mineral matter. Carbonaceous particles having a relatively low work function become positively charged, while particles of mineral matter having significantly higher work functions become negatively charged. once the particles become selectively charged, a separation can be achieved by passing the particle stream through an electrically charged field. Details related to the triboelectrostatic charging phenomenon have been discussed elsewhere (Inculet, 1984).

  7. Coal-sand attrition system and its importance in fine coal cleaning. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Mehta, R.K.; Zhu, Qinsheng

    1993-08-01

    It is known that ultra-fine coals are prerequisite for the deep cleaning of most US coal seams if environmental pollution arising from the use of such coals is to be minimized. Therefore, the production of finely liberated coal particles in conjunction with reduced heavy metal contaminants at low costs is desirable, if not mandatory. The liberation of intimately disseminated impurities from the coal matrix therefore, demands that the material be ground to a high degree of fineness. Similarily, some technologies for coal utilization require superfine particles (i.e., sizes less than ten microns). This implies additional costs for coal preparation plants due to the high energy and media costs associated with fine grinding operations. Besides, there are problems such as severe product contaminations due to media wear and impairment of the quality of coal. Hence, proper choice of grinding media type is important from the viewpoints of cost reduction and product quality. The use of natural quartz sand as grinding media in the comminution of industrial minerals in stirred ball mills has been indicated. The advantages of natural sand compared to steel media include low specific energy inputs, elimination of heavy metal contaminants and low media costs. In this work, the effect of rotor speed, solids concentration and feed-size are studied on four coals in conjunction with silica sand and steel shot. The results obtained are used to evaluate the suitability of silica sands as an alternative grinding media. for coal. Coal-sand and coal-steel systems are compared in terms of specific energy consumption, product fineness, media/wear contaminationanalysis and calorific values, liberation spectrum and particle shape characteristics. In general cleaner flotation concentrate was obtained from coals when they were ground with sand media. The zeta potential of coals was found to be different and lower when they ground with sand.

  8. Improved techniques for hyperbaric filtration of fine coal slurry

    Energy Technology Data Exchange (ETDEWEB)

    Yang, J.; Wang, X.H.; Parekh, B.K. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    2010-07-01

    Dewatering of fine clean coal slurry is one of the most important unit operations of a coal-cleaning circuit. However, an efficient and economic dewatering method is still eluding the coal industry. In this study hyperbaric (high pressure) filtration studies were conducted on a froth flotation product obtained from a coal preparation plant processing Pittsburgh No. 8 seam coal. The fine coal slurry (42 weight percent minus 25 {mu}m) could be dewatered to a low moisture (24%) using 482kPa (70psi) pressure. This article describes two novel approaches for improving dewatering of the fine coal slurry using hyperbaric filtration, such as using a modified filter support and split-size dewatering. The modified filter support system and the split-sizing at 25 {mu}m (500mesh) provided 21.5% and 15.9% moisture filter cake, which was about 10% and 34% improvement in moisture reduction in the filter cake moisture, respectively. Combining both the approaches with the addition of a nonionic flocculant provided a filter cake with 10.5% moisture, which was about a 56% improvement in moisture reduction.

  9. Dewatering studies of fine clean coal. Final technical report, September 1, 1991--August 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K. [Kentucky Univ., Lexington, KY (United States). Center for Applied Energy Research

    1992-12-31

    Physical cleaning of ultra-fine coal using advanced froth flotation technique provides a low ash product; however, the amount of water associated with clean coal is high. Economic removal of water from the froth will be important for commercial applicability of the advanced flotation processes. The main objective of the present research program is to study and understand dewatering characteristics of ultra-fine clean coal and to develop process parameters to effectively reduce the moisture to less than 20 percent in the clean coal product. The research approach utilized synergistic effect of metal ions and surfactant addition to lower the moisture of clean coal using the conventional vacuum dewatering technique. The studies have identified a combinations of metal ions and surfactants in providing a 22 percent moisture filter cake. Surface chemical study indicated a direct correlation between the point-of-zero charge (PZC) of metal ion/fine coal system and lowering of moisture in the filter cake. Adsorption of either metal ions or surfactants alone did not provide a significant reduction of moisture in the filter cake. However, a combination of the two provided a filter cake containing about 22 percent moisture. Filtration tests conducted using a laboratory vacuum drum filter indicated that the results obtained in batch filtration could be reproduced on a continuous filtration unit. FT-IR studies indicated that anionic surfactant and metal ions form complex species which adsorbs on the fine coal and results in improved moisture reduction during filtration. Recommendations are offered for testing this novel dewatering process on a pilot scale at a coal preparation plant in Illinois.

  10. Hydrophobic Dewatering of Fine Coal. Topical report, March 1, 1995-March 31, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, R.; Sohn, S.; Luttrell, J.; Phillips, D.

    1997-12-31

    Many advanced fine coal cleaning technologies have been developed in recent years under the auspices of the U.S. Department of Energy. However, they are not as widely deployed in industry as originally anticipated. An important reason for this problem is that the cleaned coal product is difficult to dewater because of the large surface area associated with fine particles. Typically, mechanical dewatering, such as vacuum filtration and centrifugation, can reduce the moisture to 20-35% level, while thermal drying is costly. To address this important industrial problem, Virginia Tech has developed a novel dewatering process, in which water is displaced from the surface of fine particulate materials by liquid butane. Since the process is driven by the hydrophobic interaction between coal and liquid butane, it was referred to as hydrophobic dewatering (HD). A fine coal sample with 21.4 pm median size was subjected to a series of bench-scale HD tests. It was a mid-vol bituminous coal obtained from the Microcel flotation columns operating at the Middle Fork coal preparation plant, Virginia. All of the test results showed that the HD process can reduce the moisture to substantially less than 10%. The process is sensitive to the amount of liquid butane used in the process relative to the solids concentration in the feed stream. Neither the intensity nor the time of agitation is critical for the process. Also, the process does not require long time for phase separation. Under optimal operating conditions, the moisture of the fine coal can be reduced to 1% by weight of coal.

  11. Possibilities of raising the rate of fine coal flotation

    Energy Technology Data Exchange (ETDEWEB)

    Rubinstein, J.B.; Molchanov, A.E.; Chanturiya, V.A.; Guzenko, A.I. [Institute of Solid Fossil Fuels Preparation, Moscow (Russian Federation). Department of Flotation Equipment and Technological Processes Optimization

    1995-08-01

    The physical and chemical properties of coal particles change after fine grinding. A series of tests with narrow size fractions shows their floatability and the effect of fines content on the flotation response. Floatability distribution functions obtained using different reagents show that the flocculation-flotation method and flotation columns are highly efficient for upgrading coal. The methods include selective coagulation, selective flocculation, and oil agglomeration. For the flocculation-flotation process using latex (200-300 g/t), the concentrate ash was reduced by 2-3 percent, while tailings ash increased by 6-8 percent compared to conventional flotation. 11 refs., 7 figs., 2 tabs.

  12. Study of the inner structure of fine coal filter cake

    Energy Technology Data Exchange (ETDEWEB)

    Shi Chang-sheng; Xie Guang-yuan; Zhang Yue-qiu [China University of Mining & Technology, Xuzhou (China). School of Environmental Sciences and Spatial Informatics

    2006-07-01

    The dewatering of fine coal in coal processing is very important. Based on the theories of dewatering, the inner structure of the filter cake was analyzed using the scanning-electron microscope. The porosity, the maximal diameter of voids and the average area of voids were analyzed in detail. Genuine causes influencing final moisture of the cake were identified. The results show that the porosity of the filter cake increased from 3.87 % to 15.46 % with the increasing of size of fine coal from 0.045 mm to 0.5 mm, and the average area of the void increased from 2.14{mu}m{sup 2} to 8.24 {mu}m{sup 2}. 8 refs., 8 figs., 5 tabs.

  13. Development, testing, and demonstration of an optimal fine coal cleaning circuit

    Energy Technology Data Exchange (ETDEWEB)

    Mishra, M.; Placha, M.; Bethell, P. [and others

    1995-11-01

    The overall objective of this project is to improve the efficiency of fine coal cleaning. The project will be completed in two phases: bench-scale testing and demonstration of four advanced flotation cells and; in-plant proof-of-concept (POC) pilot plant testing of two flotation cells individually and in two-stage combinations. The goal is to ascertain if a two-stage circuit can result in reduced capital and operating costs while achieving improved separation efficiency. The plant selected for this project, Cyprus Emerald Coal Preparation plant, cleans 1200 tph of raw coal. The plant produces approximately 4 million tonnes of clean coal per year at an average as received energy content of 30.2 MJ/Kg (13,000 Btu/lb).

  14. Evaluation of hyperbaric filtration for fine coal dewatering. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K. [Univ. of Kentucky, Lexington, KY (United States); Hogg, R. [Pennsylvania State Univ., University Park, PA (United States); Fonseca, A. [CONSOL Inc. (United States)

    1996-08-15

    The main objectives of the project were to investigate the fundamental aspects of particle-liquid interaction in fine coal dewatering, to conduct laboratory and pilot plant studies on the applicability of hyperbaric filter systems and to develop process conditions for dewatering of fine clean coal to less than 20% moisture. The program consisted of three phases, namely Phase 1 -- Model Development, Phase 2 -- Laboratory Studies, Phase 3 -- Pilot Plant Testing. The Pennsylvania State University led efforts in Phase 1, the University of Kentucky in Phase 2, and CONSOL Inc. in Phase 3 of the program. All three organizations were involved in all the three phases of the program. The Pennsylvania State University developed a theoretical model for hyperbaric filtration systems, whereas the University of Kentucky conducted experimental studies to investigate fundamental aspects of particle-liquid interaction and application of high pressure filter in fine coal dewatering. The optimum filtration conditions identified in Phase 1 and 2 were tested in two of the CONSOL Inc. coal preparation plants using an Andritz Ruthner portable hyperbaric filtration unit.

  15. Energy-Saving Vibration Impulse Coal Degradation at Finely Dispersed Coal-Water Slurry Preparation

    Directory of Open Access Journals (Sweden)

    Moiseev V.A.

    2015-01-01

    Full Text Available Theoretical and experimental research results of processes of finely dispersed coal-water slurry preparation for further generation of energetic gas in direct flow and vortex gas generator plants have been presented. It has been stated that frequency parameters of parabolic vibration impulse mill influence degradation degree. Pressure influence on coal parameters in grinding cavity has been proven. Experimental researches have proven efficiency of vibration impulse mill with unbalanced mass vibrator generator development. Conditions of development on intergranular walls of coal cracks have been defined.

  16. Low-rank coal research: Volume 2, Advanced research and technology development: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Mann, M.D.; Swanson, M.L.; Benson, S.A.; Radonovich, L.; Steadman, E.N.; Sweeny, P.G.; McCollor, D.P.; Kleesattel, D.; Grow, D.; Falcone, S.K.

    1987-04-01

    Volume II contains articles on advanced combustion phenomena, combustion inorganic transformation; coal/char reactivity; liquefaction reactivity of low-rank coals, gasification ash and slag characterization, and fine particulate emissions. These articles have been entered individually into EDB and ERA. (LTN)

  17. Development of an Ultra-fine Coal Dewatering Technology and an Integrated Flotation-Dewatering System for Coal Preparation Plants

    Energy Technology Data Exchange (ETDEWEB)

    Wu Zhang; David Yang; Amar Amarnath; Iftikhar Huq; Scott O' Brien; Jim Williams

    2006-12-22

    The project proposal was approved for only the phase I period. The goal for this Phase I project was to develop an industrial model that can perform continuous and efficient dewatering of fine coal slurries of the previous flotation process to fine coal cake of {approx}15% water content from 50-70%. The feasibility of this model should be demonstrated experimentally using a lab scale setup. The Phase I project was originally for one year, from May 2005 to May 2006. With DOE approval, the project was extended to Dec. 2006 without additional cost from DOE to accomplish the work. Water has been used in mining for a number of purposes such as a carrier, washing liquid, dust-catching media, fire-retardation media, temperature-control media, and solvent. When coal is cleaned in wet-processing circuits, waste streams containing water, fine coal, and noncombustible particles (ash-forming minerals) are produced. In many coal preparation plants, the fine waste stream is fed into a series of selection processes where fine coal particles are recovered from the mixture to form diluted coal fine slurries. A dewatering process is then needed to reduce the water content to about 15%-20% so that the product is marketable. However, in the dewatering process currently used in coal preparation plants, coal fines smaller than 45 micrometers are lost, and in many other plants, coal fines up to 100 micrometers are also wasted. These not-recovered coal fines are mixed with water and mineral particles of the similar particle size range and discharged to impoundment. The wasted water from coal preparation plants containing unrecoverable coal fine and mineral particles are called tailings. With time the amount of wastewater accumulates occupying vast land space while it appears as threat to the environment. This project developed a special extruder and demonstrated its application in solid-liquid separation of coal slurry, tailings containing coal fines mostly less than 50 micron. The

  18. Enhanced column flotation performance for fine coal cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q.; Mohanty, M.K. [Southern Illinois University at Carbondale, Carbondale, IL (United States). Dept. of Mining Engineering

    1996-09-01

    Experimental and theoretical results have indicated that the use of multi-stage cleaning circuits enhance the separation performance achieved by flotation columns while treating fine coal. This improvement is basically due to the excellent ability of the flotation process to float particles that contain a very small amount of hydrophobic material. Single stage treatment of a -48 mesh Illinois No. 5 coal sample found that 25% of the heavy middling in the +400 mesh size fraction were recovered to the froth concentrate, which occurred despite the use of a deep froth of 3 m. The use of a cleaner stage reduced the overall recovery of heavy middlings to approximately 10% and reduced the product ash content from 9% in the rougher stage to about 6.5% in the cleaner stage while recovering 80% of the combustible material. Subsequent treatment of the cleaner product further improved the recovery-grade curve. A similar finding was also obtained from the treatment of an Illinois No. 6 coal sample using a different flotation column. 10 refs., 9 figs., 7 tabs.

  19. Controlling air toxics through advanced coal preparation

    Energy Technology Data Exchange (ETDEWEB)

    Straszheim, W.E.; Buttermore, W.H.; Pollard, J.L. [Iowa State Univ., Ames, IA (United States)

    1995-11-01

    This project involves the assessment of advanced coal preparation methods for removing trace elements from coal to reduce the potential for air toxic emissions upon combustion. Scanning electron microscopy-based automated image analysis (SEM-AIA) and advanced washability analyses are being applied with state-of-the-art analytical procedures to predict the removal of elements of concern by advanced column flotation and to confirm the effectiveness of preparation on the quality of quantity of clean coal produced. Specific objectives are to maintain an acceptable recovery of combustible product, while improving the rejection of mineral-associated trace elements. Current work has focused on determining conditions for controlling column flotation system across its operating range and on selection and analysis of samples for determining trace element cleanability.

  20. A comparative overview of coal-water slurry fuels produced from waste coal fines for utility-scale co-firing applications

    Energy Technology Data Exchange (ETDEWEB)

    Morrison, J.L.; Miller, B.G.; Scaroni, A.W. [Pennsylvania State Univ., University Park, PA (United States)] [and others

    1997-07-01

    The recovery and utilization of coal fines, both impounded and in cleaning plant effluent streams, have received close attention from both coal producers and coal-fixed utilities during the last few years. Many coal producers view impounded fines as an environmental liability and the discarded fines in plant effluent streams as contributing to a loss in Btu recovery. In addition, the rejected coal fines increase the quantity and cost of refuse disposal. The handleability of fine coal has always been a problem. Dewatering cleaned fine coal is costly. Excessive fugitive dust emissions are commonly associated with handling dry fine coal. Wet fine coal sticks to conveyor belts, blocks fuel chutes, and may limit pulverizer capacity. The preparation of coal water slurry fuel (CWSF) from wet coal fines alleviates the necessity of drying while at the same time eliminates the flow problems that wet fine coal poses to the end user. Furthermore, the utilization of CWSF as an opportunity fuel converts coal fines into a revenue source rather than a liability. Several utilities are evaluating the co-firing of low solids, low viscosity CWSF with their normal coal feedstock in an effort to lower fuel cost and/or as a NO{sub x} reduction technique. The utilization of this opportunity fuel is being driven by a changing electric industry in which utilities continually strive to reduce plant emissions while simultaneously reducing their operating costs to become more competitive as the generation side of the industry prepares for deregulation.

  1. GEOTECHNICAL/GEOCHEMICAL CHARACTERIZATION OF ADVANCED COAL PROCESS WASTE STREAMS

    Energy Technology Data Exchange (ETDEWEB)

    Edwin S. Olson; Charles J. Moretti

    1999-11-01

    Thirteen solid wastes, six coals and one unreacted sorbent produced from seven advanced coal utilization processes were characterized for task three of this project. The advanced processes from which samples were obtained included a gas-reburning sorbent injection process, a pressurized fluidized-bed coal combustion process, a coal-reburning process, a SO{sub x}, NO{sub x}, RO{sub x}, BOX process, an advanced flue desulfurization process, and an advanced coal cleaning process. The waste samples ranged from coarse materials, such as bottom ashes and spent bed materials, to fine materials such as fly ashes and cyclone ashes. Based on the results of the waste characterizations, an analysis of appropriate waste management practices for the advanced process wastes was done. The analysis indicated that using conventional waste management technology should be possible for disposal of all the advanced process wastes studied for task three. However, some wastes did possess properties that could present special problems for conventional waste management systems. Several task three wastes were self-hardening materials and one was self-heating. Self-hardening is caused by cementitious and pozzolanic reactions that occur when water is added to the waste. All of the self-hardening wastes setup slowly (in a matter of hours or days rather than minutes). Thus these wastes can still be handled with conventional management systems if care is taken not to allow them to setup in storage bins or transport vehicles. Waste self-heating is caused by the exothermic hydration of lime when the waste is mixed with conditioning water. If enough lime is present, the temperature of the waste will rise until steam is produced. It is recommended that self-heating wastes be conditioned in a controlled manner so that the heat will be safely dissipated before the material is transported to an ultimate disposal site. Waste utilization is important because an advanced process waste will not require

  2. An advanced coal gasification desulfurization process

    Energy Technology Data Exchange (ETDEWEB)

    Abbasian, J.; Rehmat, A. (Institute of Gas Technology, Chicago, IL (USA)); Leppin, D. (Gas Research Inst., Chicago, IL (USA)); Banerjee, D.D. (Center for Research on Sulfur in Coal, Carterville, IL (USA))

    1990-01-01

    The Institute of Gas Technology (IGT) is in the process of developing an advanced coal gasification desulfurization process in which a calcium-based sorbent such as limestone or dolomite is injected into the fluidized-bed gasifier with coal to achieve in-bed desulfurization of coal as it is converted into clean fuel gas. The reactions involving calcium-based sorbents takes place in two steps. In the first step, the desulfurization reaction takes place between hydrogen sulfide and calcium oxide in the reducing zone of the reactor to produce calcium sulfide. The latter subsequently reacts with oxygen in the oxidizing zone of the reactor to produce calcium sulfate which can be safely disposed of along with the coal ash. This process will reduce the capital requirement for coal gasification plants and provide cost effective alternatives to scrubbers for industrial and utility use of high-sulfur coal. This paper addresses the basic research being conducted at IGT to confirm the viability of this process. 9 refs., 3 figs., 1 tab.

  3. Economics of coal conversion processing. Advances in coal gasification: support research. Advances in coal gasification: process development and analysis

    Energy Technology Data Exchange (ETDEWEB)

    1978-01-01

    The fall meeting of the American Chemical Society, Division of Fuel Chemistry, was held at Miami Beach, Florida, September 10-15, 1978. Papers involved the economics of coal conversion processing and advances in coal gasification, especially support research and process development and analysis. Fourteen papers have been entered individually into EDB and ERA; three papers had been entered previously from other sources. (LTN)

  4. AN INVESTIGATION OF THE HYDROPHOBIC AGGLOMERATION CHARACTERISTICS OF EASY DEGRADATION COAL FINES IN WATER

    Institute of Scientific and Technical Information of China (English)

    王力; 陈鹏

    1997-01-01

    The separation of ultrafine coal from three Chinese coal samples of easy degradation coal fines in water has been investigated by the application of a hydrophobic agglomeration process. In addition to yielding clean coal with high recovery, this process requires significantly less oil concentration for agglomeration (less than 0.4% in oil-water weight ratio) and produces stabler agglomerates than general oil agglomeration process, the cost of the oil would no longer be an important consideration for its commercial application. Neutral diesel oil was used to make oleophilic coal particles agglomerated with good rejection of clay minerals under little oil consumption and certain agitation speed at 2000 r/min. An important advantage of this process compared with other cleaning fine coal methods is that it can extremely reduce or eliminate the effects of coal degradation and some clay minerals on coal preparation.

  5. Advanced coal-fired power plants

    Energy Technology Data Exchange (ETDEWEB)

    Hebel, G.; Weirich, P.H.

    1988-02-01

    Reconstruction of coal-fired power plants under the aspects of higher economic efficiency and lower emissions has become more interesting as the petroleum and natural gas reserves have become shorter. A number of advanced concepts have been presented in the last few years and tested in experimental facilities, pilot plants and demonstration plants. If construction is envisaged within the next five years, better steam processes and coal gas turbines should be employed. Supercharged steam generators, which will bring about further improvements, will be available by the mid-Nineties.

  6. Advanced clean coal utilization technologies

    Energy Technology Data Exchange (ETDEWEB)

    Moritomi, Hiroshi [National Inst. for Resources and Environment, Tsukuba, Ibaraki (Japan)

    1993-12-31

    The most important greenhouse gas is CO{sub 2} from coal utilization. Ways of mitigating CO{sub 2} emissions include the use of alternative fuels, using renewable resources and increasing the efficiency of power generation and end use. Adding to such greenhouse gas mitigation technologies, post combustion control by removing CO{sub 2} from power station flue gases and then storing or disposing it will be available. Although the post combustion control have to be evaluated in a systematic manner relating them to whether they are presently available technology, to be available in the near future or long term prospects requiring considerable development, it is considered to be a less promising option owing to the high cost and energy penalty. By contrast, abatement technologies aimed at improving conversion efficiency or reducing energy consumption will reduce emissions while having their own commercial justification.

  7. TRW Advanced Slagging Coal Combustor Utility Demonstration

    Energy Technology Data Exchange (ETDEWEB)

    1989-01-01

    The TRW Advanced Slagging Coal Combustor Demonstration Project consists of retrofitting Orange and Rockland (O R) Utility Corporation's Lovett Plant Unit No. 3 with four (4) slagging combustors which will allow the gas/ou desip unit to fire 2.5 sulfur coal. The slogging combustor process will provide NO[sub x] and SO[sub x] emissions that meet NSPS and New York State Envirommental Standards. TRW-CBU scope of work includes the engineering, design and supply of the slogging combustors, coal and limestone feed systems and a control system for these components. During this report period, the design activities for all systems progressed to permit the release of specifications and requests for proposals. Award of contracts for long-delivery items and major equipment are being placed to meet the revised program schedule.

  8. Advanced systems for producing superclean coal

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.

    1990-08-01

    The purpose of this project was to develop several advanced separation processes for producing superclean coal containing 0.4--2.0% ash and very little pyritic sulfur. Three physical and physico-chemical processes were studied: microbubble flotation, selective hydrophobic coagulation, and electrochemical coal cleaning. Information has been collected from bench-scale experiments in order to determine the basic mechanisms of all three processes. Additionally, because microbubble flotation has already been proven on a bench scale, preliminary scale-up models have been developed for this process. A fundamental study of the electrochemistry of coal pyrite has also been conducted in conjunction with this scale-up effort in order to provide information useful for improving sulfur rejection. The effects of additives (NaCl and kerosene) were also investigated. 94 refs., 167 figs., 25 tabs.

  9. Developmental research study of coal-fines agglomeration for fixed-bed gasification. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Elmquist, S.A.; Girimont, J.A.; Korosi, F.A.; Kuby, O.A.; Nelson, S.G.; Paulin, M.O.; Peterson, C.A.; Baker, R.L.; Saller, E.

    1983-05-31

    This report presents the results of an intensive program to develop and evaluate agglomerates made from coal fines for use in a fixed-bed gasifier. There were several tasks completed earlier and their results published prior to this final report. These included: Task 1-A, a literature survey of coal agglomeration, binders and techniques used in coal agglomeration, coal and binder treatments and the results of work done by others; Task 1-B, an examination of performance of lump coals in coal gasification, testing and evaluation of the properties of these coals, and evaluation of mine site coal upgrading methods; and Task 1-C/D, a laboratory investigation of coal agglomerates, including wafers, briquettes and pellets, in which the agglomerated coal fines were formed and tested, and the performance of various coal/binder combinations was recorded and evaluated, and factors affecting commercial scale coal agglomeration and gasification were evaluated. These three prior tasks are presented in this report in condensed form.

  10. Ultra fine tantalum powder for advanced capacitors

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    @@ Ultra fine tantalum and niobium powders are applicable in many areas of engineering. Of particular significance are high purity powders that are usable in production of high capacitance capacitors and superconductors.

  11. Ultra fine tantalum powder for advanced capacitors

    Institute of Scientific and Technical Information of China (English)

    Nebera; A.; Markusbkin; Yu.; Azarov; V.; Ermolaev; N.

    2005-01-01

    Ultra fine tantalum and niobium powders are applicable in many areas of engineering. Of particular significance are high purity powders that are usable in production of high capacitance capacitors and superconductors.……

  12. Assessment of Advanced Coal Gasification Processes

    Science.gov (United States)

    McCarthy, John; Ferrall, Joseph; Charng, Thomas; Houseman, John

    1981-01-01

    This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process; Bell Single-Stage High Mass Flux (HMF) Process; Cities Service/Rockwell (CS/R) Hydrogasification Process; Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic, fluidbed reactor producing all of the raw product methane in the gasifier. The report makes the following assessments: 1) while each process has significant potential as coal gasifiers, the CS/R and Exxon processes are better suited for SNG production; 2) the Exxon process is the closest to a commercial level for near-term SNG production; and 3) the SRT processes require significant development including scale-up and turndown demonstration, char processing and/or utilization demonstration, and reactor control and safety features development.

  13. ELECTROKINETIC DENSIFICATION OF COAL FINES IN WASTE PONDS

    Energy Technology Data Exchange (ETDEWEB)

    E. James Davis

    1999-12-18

    The objective of this research was to demonstrate that electrokinetics can be used to remove colloidal coal and mineral particles from coal-washing ponds and lakes without the addition of chemical additives such as salts and polymeric flocculants. The specific objectives were: Design and develop a scaleable electrophoresis apparatus to clarify suspensions of colloidal coal and clay particles; Demonstrate the separation process using polluted waste water from the coal-washing facilities at the coal-fired power plants in Centralia, WA; Develop a mathematical model of the process to predict the rate of clarification and the suspension electrical properties needed for scale up.

  14. Grafted polysaccharides - new generation polymeric flocculants for treatment of coal fines suspension

    Energy Technology Data Exchange (ETDEWEB)

    Karmakar, N.C. [Indian School of Mines, Dhanbad (India)

    2002-07-01

    Though washing of coking coal for steel plant use is a standard practice, washing of non-coking coal is also fast picking up for the end use in thermal power plants. The effluent from coal washery contains high percentage of coal fines, which is not only of economic concern but also is a potential source of river water pollution. Lots of research works have been and are being carried out to formulate suitable flocculants for the treatment of coal washing effluent in the thickener. Nowadays, synthetic polymers have mostly replaced the inorganic and organic polymers. So far mostly linear synthetic polymers have been tried and their performance is not up to the satisfaction especially for non-coking coals. In the present work, a series of new generation graft copolymers have been synthesised by grafting polyacrylamide chains onto the strong backbone of polysaccharides, namely starch, amylose, amylopectin, sodium algenate and CMC. It is observed that all the graft copolymers possess good flocculation quality on coal fines suspension. Amylopectin-g-polyacrylamide has performed the best on both coking as well as non-coking coal fines suspension, and hence, has the potential for application in the treatment of effluent generated from coal washing plants. 6 refs., 6 figs., 1 tab.

  15. Advanced coal-fired power plant technology

    Energy Technology Data Exchange (ETDEWEB)

    Klauke, F. [Babcock Borsig Power Energy GmbH (Germany)

    2001-07-01

    This paper presents the joint efforts of a large European group of manufacturers, utilities and institutes co-operating in a phased long-term project named 'Advanced 700{degree}C PF Power Plant'. Net efficiences of more than 50% will be reached through development of a super critical steam cycle operating at maximum steam temperatures in the range of 700{degree}C. The principal efforts are based on development of creep resistent nickel-based materials named super-alloys for the hottest areas of the water/steam cycle. The Advanced 700{degree}C PF Power Plant project will improve the competitiveness of coal-fired power generation. Furthermore, it will provide a major reduction of CO{sub 2} from coal-fired power plants in the range of 15% from the best PF power plants presently and up to 40% from older plants. The demonstration programme will leave the possibility of any plant output between 400 and 1000 MW. The project will run to the end of 2003. 8 figs.

  16. An enhanced-gravity method to recover ultra-fine coal from tailings: Falcon concentrator

    Energy Technology Data Exchange (ETDEWEB)

    Filiz Oruc; Selcuk Ozgen; Eyup Sabah [Afyon Kocatepe University, Afyonkarahisar (Turkey). Department of Mining Engineering

    2010-09-15

    The Falcon concentrator is an enhanced-gravity separator used for the concentration of fine and ultra-fine minerals. This study was conducted to evaluate the effects of different process variables on the performance of the Falcon SB-40 concentrator for beneficiation of tailings to recover ultra-fine coal. Various operating and design conditions such as bowl speed (G force), water pressure, pulp solid ratio and pulp feed rate were investigated. A hydrocyclone was used for pre-enrichment with the Falcon concentrator. Operation parameters of the hydrocyclone, namely feed solids, inlet pressure, vortex finder and apex diameters were investigated. In order to produce fine coal concentrates, regression equations were derived by applying the least squares method using Minitab 15 software. Response functions were produced for the ash content and the recovery of the clean coal concentrates for the performance of the hydrocyclone and Falcon concentrator under different operating conditions. Predicted values were found with the experimental values giving R{sup 2} values of between 0.73 and 0.58 for ash content and between 0.65 and 0.39 for recovery of the clean coal. It was shown that under optimized conditions the Falcon concentrator can produce a clean coal with an ash value of 36% from a feed coal of about 66% ash. 19 refs., 7 figs., 5 tabs.

  17. Additives for granulating and removing ash from finely dispersed coal

    Energy Technology Data Exchange (ETDEWEB)

    Ivabutin, K.; Fukuda, T.; Goto, M.; Miva, K.; Murata, T.; Taguti, D.

    1982-07-31

    One to thirty percent of a 0.01 to 10 percent solution of synthetic polymers (SPL) of ethylene and vinylacetate or methacrylate, polybutadiene rubbers, resins based on vinylchloride, low molecular PA and so on in an organic solvent mixed with high boiling point bottoms of coal distillation or that of crude oil and or an inorganic electrolyte (a sulfate or phosphate of an alkaline metal) is added to an aqueous suspension of coal powder in order to utilize the dust particles of the coal and to make low ash granules from them.

  18. Bench-scale testing of a micronized magnetite, fine-coal cleaning process

    Energy Technology Data Exchange (ETDEWEB)

    Suardini, P.J. [Custom Coals, International, Pittsburgh, PA (United States)

    1995-11-01

    Custom Coals, International has installed and is presently testing a 500 lb/hr. micronized-magnetite, fine-coal cleaning circuit at PETC`s Process Research Facility (PRF). The cost-shared project was awarded as part of the Coal Preparation Program`s, High Efficiency Preparation Subprogram. The project includes design, construction, testing, and decommissioning of a fully-integrated, bench-scale circuit, complete with feed coal classification to remove the minus 30 micron slimes, dense medium cycloning of the 300 by 30 micron feed coal using a nominal minus 10 micron size magnetite medium, and medium recovery using drain and rinse screens and various stages and types of magnetic separators. This paper describes the project circuit and goals, including a description of the current project status and the sources of coal and magnetite which are being tested.

  19. Mercury speciation and fine particle size distribution on combustion of Chinese coals

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Lei; Wang, Shuxiao; Hao, Jiming [Tsinghua Univ., Beijing (China). Dept. of Environmental Science and Engineering and State Key Joint Lab. of Environment Simulation and Pollution Control; Daukoru, Michael; Torkamani, Sarah; Biswas, Pratim [Washington Univ., St. Louis, MO (United States). Aerosol and Air Quality Research Lab.

    2013-07-01

    Coal combustion is the dominant anthropogenic mercury emission source of the world. Electrostatic precipitator (ESP) can remove almost all the particulate mercury (Hg{sub p}), and wet flue gas desulfurization (WFGD) can retain a large part of the gaseous oxidized mercury (Hg{sup 2+}). Only a small percentage of gaseous elemental mercury (Hg{sup 0}) can be abated by the air pollution control devices (APCDs). Therefore, the mercury behavior across APCDs largely depends on the mercury speciation in the flue gas exhausting from the coal combustor. To better understand the formation process of three mercury species, i.e. Hg{sup 0}, Hg{sup 2+} and Hg{sub p}, in gaseous phase and fine particles, bench-scale measurements for the flue gas exhausting from combustion of different types of coal in a drop-tube furnace set-up, were carried out. It was observed that with the limitation of reaction kinetics, higher mercury concentration in flue gas will lead to lower Hg{sup 2+} proportion. The concentration of chlorine has the opposite effect, not as significantly as that of mercury though. With the chlorine concentration increasing, the proportion of Hg{sup 2+} increases. Combusting the finer coal powder results in the formation of more Hg{sup 2+}. Mineral composition of coal and coal particle size has a great impact on fine particle formation. Al in coal is in favor of finer particle formation, while Fe in coal can benefit the formation of larger particles. The coexistence of Al and Si can strengthen the particle coagulation process. This process can also be improved by the feeding of more or finer coal powder. The oxy-coal condition can make for both the mercury oxidation process and the metal oxidation in the fine particle formation process.

  20. Geochemistry of ultra-fine and nano-compounds in coal gasification ashes: a synoptic view.

    Science.gov (United States)

    Kronbauer, Marcio A; Izquierdo, Maria; Dai, Shifeng; Waanders, Frans B; Wagner, Nicola J; Mastalerz, Maria; Hower, James C; Oliveira, Marcos L S; Taffarel, Silvio R; Bizani, Delmar; Silva, Luis F O

    2013-07-01

    The nano-mineralogy, petrology, and chemistry of coal gasification products have not been studied as extensively as the products of the more widely used pulverized-coal combustion. The solid residues from the gasification of a low- to medium-sulfur, inertinite-rich, volatile A bituminous coal, and a high sulfur, vitrinite-rich, volatile C bituminous coal were investigated. Multifaceted chemical characterization by XRD, Raman spectroscopy, petrology, FE-SEM/EDS, and HR-TEM/SEAD/FFT/EDS provided an in-depth understanding of coal gasification ash-forming processes. The petrology of the residues generally reflected the rank and maceral composition of the feed coals, with the higher rank, high-inertinite coal having anisotropic carbons and inertinite in the residue, and the lower rank coal-derived residue containing isotropic carbons. The feed coal chemistry determines the mineralogy of the non-glass, non-carbon portions of the residues, with the proportions of CaCO₃ versus Al₂O₃ determining the tendency towards the neoformation of anorthite versus mullite, respectively. Electron beam studies showed the presence of a number of potentially hazardous elements in nanoparticles. Some of the neoformed ultra-fine/nano-minerals found in the coal ashes are the same as those commonly associated with oxidation/transformation of sulfides and sulfates.

  1. Advanced Coal-Fueled Gas Turbine Program

    Energy Technology Data Exchange (ETDEWEB)

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  2. Briquetting of coal fines and sawdust. Part 1: binder and briquetting-parameters evaluations

    Energy Technology Data Exchange (ETDEWEB)

    D. Taulbee; D.P. Patil; Rick Q. Honaker; B.K. Parekh [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    2009-01-15

    Various technical and economic aspects relating to the briquetting of fine coal with sawdust have been evaluated with the results for two segments of that study presented here: binder and briquetting-parameter evaluations. Approximately 50 potential binder formulations were subjected to a series of screening evaluations to identify three formulations that were the most cost effective for briquetting fine coal with sawdust. Two of the binders, guar gum and wheat starch, were selected as most suitable for the pulverized coal market while the third formulation, lignosulfonate/lime, was targeted for the stoker market. Following binder selection, a number of briquetting parameters including binder and sawdust concentration, sawdust type, briquetting pressure and dwell time, coal and sawdust particle size, clay content, moisture content, and cure temperature and cure time were evaluated. Briquetting pressure and dwell time have the least impact while binder and sawdust concentrations, sawdust type, and curing conditions exerted the greatest influence on briquette quality. 7 refs.

  3. Experimental Research on Desulfurization of Fine Coal Using an Enhanced Centrifugal Gravity Separator

    Institute of Scientific and Technical Information of China (English)

    TAO You-jun; LUO Zhen-fu; ZHAO Yue-min; TAO Daniel

    2006-01-01

    A desulphurization experimental study under the effects of compounding physical force fields has been described for < 0.5 mm fine particles of high sulfur coal. A statistical test using the Box-Behnken Design of experiments was conducted to evaluate the effects of individual operating variables and their interactions on desulfurization of fine coal using an enhanced centrifugal gravity separator. A model describing the relation between desulphurization efficiency of pyrite sulfur and different operating variables has been designed. The interactions between different factors on the pyrite sulfur desulphurization efficiency have been analysed. The optimal test conditions for desulfarization are extracted from the Design-Expert 6.0 software. Finally, the advantage of centrifugal gravity separation for fine coal is pointed out.

  4. Geochemistry of ultra-fine and nano-compounds in coal gasification ashes: A synoptic view

    Energy Technology Data Exchange (ETDEWEB)

    Kronbauer, Marcio A. [Centro Universitário La Salle, Mestrado em Avaliação de Impactos Ambientais em Mineração, Victor Barreto, 2288 Centro, 92010-000 Canoas, RS (Brazil); Universidade Federal do Rio Grande do Sul, Escola de Engenharia, Departamento de Metalurgia, Centro de Tecnologia, Av. Bento Gonçalves, 9500, Bairro Agronomia, CEP: 91501-970, Porto Alegre, RS (Brazil); Izquierdo, Maria [School of Applied Sciences, Cranfield University, Bedfordshire MK43 0AL (United Kingdom); Dai, Shifeng [State Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology, Beijing 100083 (China); Waanders, Frans B. [School of Chemical and Minerals Engineering, North West University (Potchefstroom campus), Potchefstroom 2531 (South Africa); Wagner, Nicola J. [School of Chemical and Metallurgical Engineering, University of the Witwatersrand, Johannesburg (South Africa); Mastalerz, Maria [Indiana Geological Survey, Indiana University, Bloomington, IN 47405-2208 (United States); Hower, James C. [University of Kentucky Center for Applied Energy Research, 2540 Research Park Drive, Lexington, KY 40511 (United States); Oliveira, Marcos L.S. [Environmental Science and Nanotechnology Department, Catarinense Institute of Environmental Research and Human Development, IPADHC, Capivari de Baixo, Santa Catarina (Brazil); Taffarel, Silvio R.; Bizani, Delmar [Centro Universitário La Salle, Mestrado em Avaliação de Impactos Ambientais em Mineração, Victor Barreto, 2288 Centro, 92010-000 Canoas, RS (Brazil); and others

    2013-07-01

    The nano-mineralogy, petrology, and chemistry of coal gasification products have not been studied as extensively as the products of the more widely used pulverized-coal combustion. The solid residues from the gasification of a low- to medium-sulfur, inertinite-rich, volatile A bituminous coal, and a high sulfur, vitrinite-rich, volatile C bituminous coal were investigated. Multifaceted chemical characterization by XRD, Raman spectroscopy, petrology, FE-SEM/EDS, and HR-TEM/SEAD/FFT/EDS provided an in-depth understanding of coal gasification ash-forming processes. The petrology of the residues generally reflected the rank and maceral composition of the feed coals, with the higher rank, high-inertinite coal having anisotropic carbons and inertinite in the residue, and the lower rank coal-derived residue containing isotropic carbons. The feed coal chemistry determines the mineralogy of the non-glass, non-carbon portions of the residues, with the proportions of CaCO{sub 3} versus Al{sub 2}O{sub 3} determining the tendency towards the neoformation of anorthite versus mullite, respectively. Electron beam studies showed the presence of a number of potentially hazardous elements in nanoparticles. Some of the neoformed ultra-fine/nano-minerals found in the coal ashes are the same as those commonly associated with oxidation/transformation of sulfides and sulfates. - Highlights: • Coal waste geochemisty can provide increased environmental information in coal-mining areas. • Oxidation is the major process for mineral transformation in coal ashes. • The electron bean methodology has been applied to investigate neoformed minerals.

  5. Ceramic membrane filters for fine particulate removal in coal-fired industrial boilers

    Energy Technology Data Exchange (ETDEWEB)

    Miller, B.G.; Wincek, R.T.; Glick, D.C.; Scaroni, A.W.; Makris, P.; Krecker, J.; Jung, G.; Stubblefield, D.J.

    1998-07-01

    Strategies are being developed at Penn Sate to produce ultralow emissions when firing coal-based fuel, i.e., micronized coal and coal-water slurry fuel (CWSF), in industrial boilers. The research is being conducted at the bench, pilot, and demonstration scale, and the emissions being addressed are SO{sub 2}, NO{sub x}, fine particulate matter (PM{sub 10} and PM{sub 2.5}), and air toxics (trace elements and volatile organic compounds). Specific activities are identifying/developing a low-temperature NO{sub x} reduction catalyst, studying the occurrence of nitrogen in coal and the fundamental mechanisms of NO{sub x} production, characterizing air toxic emissions, investigating the use of BioLime{trademark} for simultaneous SO{sub 2}/NO{sub x} reduction, and evaluating a ceramic filter for fine particulate control. Results from trace element and polynuclear aromatic hydrocarbon emissions testing when firing coal-based fuels are reported elsewhere in these proceedings. This paper discusses the preliminary results obtained using ceramic membrane filters for fine particulate removal when firing micronized coal in a package boiler.

  6. Effects of Fine Gangue on Strength, Resistivity, and Microscopic Properties of Cemented Coal Gangue Backfill for Coal Mining

    Directory of Open Access Journals (Sweden)

    Tingye Qi

    2015-01-01

    Full Text Available The cemented coal gangue backfill (CGB in coal mining is normally made of gangue (particle size of 0–15 mm, fly ash, cement, and water. In this study, the effects of the weight content (ranging from 20% to 60% of fine gangue (0–5 mm on the microscopic characteristics, resistivity, and compressive strength of CGB were investigated at 3 d and 28 d curing times, respectively. The test results indicate that the strengths of the CGB, regardless of the curing time, increased with fine gangue content changing from 20% up to 40%. Further increase in fine gangue introduced a decrease in the strength. Another observation is that, at 3 days, a general increasing trend of CGB resistivity was noted with fine gangue content. At 28 days, the resistivity of CGB decreased with increase in the fine gangue content. Correlations between the resistivity and compression strength of CGB show a concave pattern, which attribute to the various micromechanism influenced on the resistivity and strength of CGB with different fine gangue content. It indicates that using resistivity to derive strength of CGB is not appropriate.

  7. Advanced physical coal cleaning to comply with potential air toxic regulations. Quarterly report, 1 March 1995--31 May 1995

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q.; Paul, B.C.; Mohanty, M.K.; Wang, D.

    1995-12-31

    Studies have indicated that the potentially hazardous trace elements found in coal have a strong affinity for coal pyrite. Thus, by maximizing the rejection of pyrite, one can minimize the trace element content of a given coal while also reducing sulfur emissions. The pyrite in most Illinois Basin coals, however, is finely disseminated within the coal matrix. Therefore, to remove the pyrite using physical coal cleaning techniques, the pyrite must be liberated by grinding the coal to ultrafine particle sizes. Fortunately, the coals being fed to pulverized coal boilers (PCB) are already ground to a very fine size, i.e., 70% passing 200 mesh. Therefore, this research project will investigate the use of advanced fine coal cleaning technologies for cleaning PCB feed as a compliance strategy. Work in this quarter has focused on the processing of a run-of-mine coal sample collected from Amax Coal Company`s Delta Coal mine using column flotation and an enhanced gravity separator as separate units and in circuitry arrangements. The {minus}60 mesh run-of-mine sample having an ash content of about 22% was cleaned to 6% while achieving a very high energy recovery of about 87% and a sulfur rejection value of 53% in a single stage column flotation operation. Enhanced gravity treatment is believed to be providing excellent total sulfur rejection values, although with inferior ash rejection for the {minus}400 mesh size fraction. The circuitry arrangement with the Falcon concentrator as the primary cleaner followed by the Packed-Column resulted in an excellent ash rejection performance, which out performed the release analysis. Trace element analyses of the samples collected from these tests will be conducted during the next report period.

  8. Advanced physical coal cleaning to comply with potential air toxic regulations. [Quarterly] technical report, September 1--November 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q.; Paul, B.C.; Wang, D. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mining Engineering

    1994-12-31

    This research project will investigate the use of advanced fine coal cleaning technologies for cleaning PCB feed as a compliance strategy. Trace elements considered in this project will include mercury, selenium, cadmium, and chlorine. Work in the first quarter has focused on trace element analysis procedures and sample acquisition. Several experts in the field of trace element analysis of coal have been consulted and these procedures are presently being evaluated.

  9. In-plant testing of a novel coal cleaning circuit using advanced technologies, Quarterly report, March 1 - May 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q. [Southern Illinois Univ., Carbondale, IL (United States); Reed, S.; Mohanty, M.K. [Kerr-McGee Coal Corp., Oklahoma City, OK (United States)

    1996-12-31

    Research conducted at Southern Illinois University at Carbondale over the past two years has identified highly efficient methods for treating fine coal (i.e., -28 mesh). In this study, a circuit comprised of the three advanced fine coal cleaning technologies is being tested in an operating preparation plant to evaluate circuit performance and to compare the performance with the current technologies used to treat -16 mesh fine coal. The circuit integrated a Floatex hydrosizer, a Falcon concentrator and a Jameson froth flotation cell. The Floatex hydrosizer is being used as a primary cleaner for the nominally -16 mesh Illinois No. 5 fine coal circuit feed. The overflow of the Floatex is screened at 48 mesh using a Sizetec vibratory screen to produce a clean coal product from the screen overflow. The screen overflow is further treated by the Falcon and Jameson Cell. During this reporting period, tests were initiated on the fine coal circuit installed at the Kerr-McGee Galatia preparation plant. The circuit was found to reduce both the ash content and the pyritic sulfur content. Additional in-plant circuitry tests are ongoing.

  10. AN ADVANCED COAL DESULFURIZATION PROCESS——SELECTIVE FLOCCULATION

    Institute of Scientific and Technical Information of China (English)

    蔡璋; 刘红缨; 吴军; 陈彩茶

    1997-01-01

    Selective flocculation is an idea separation method to separate ultrafine pyrite from coal. A number of selective flocculation separation tests under different conditions have been done and the results are very encouraging. The results also show that desulfurization and deashing can be finished simultaneously in selective flocculation process. It is an advanced coal desulfurization process.

  11. Determination of free and bound water in fine coal filter cake

    Energy Technology Data Exchange (ETDEWEB)

    D.P. Patil; B.K. Parekh [Center for Applied Energy Research, Lexington, KY (US)

    2004-12-01

    The bound water in fine coal filter cake represents the water that cannot be removed using mechanical dewatering techniques. The amount of bound water in a fine coal filter cake, in other words, represents the moisture content achievable by an ideal dewatering technique. In this study the dilatometer technique was used to measure the bound and free water in a fine coal filter cake. Results showed that addition of cationic and non-ionic surfactants reduced the bound water content in the filter cake from 13.73% to 3.72% and 8.28%, respectively. Decrease in bound water content was attributed to the adsorption of surfactants on the coal surface, which increased the coal hydrophobicity. Addition of 10 g/t of cationic and anionic flocculants also reduced the bound water content from 13.73% to 4.58% and 6.63%, respectively, which was attributed to the replacement of surface water molecules with the polymer. Based on the free and bound water data, ideal dewatering curves were developed for both surfactants and flocculants.

  12. Hydrophobic aggregation of fine particles in high muddied coal slurry water.

    Science.gov (United States)

    Chen, Jun; Min, Fanfei; Liu, Lingyun; Peng, Chenliang; Lu, Fangqin

    2016-01-01

    The hydrophobic aggregation of fine particles in high muddied coal slurry water in the presence of four quaternary ammonium salts of 1231(dodecyl trimethyl ammonium chloride), 1431(tetradecyl trimethyl ammonium chloride), 1631(cetyl trimethyl ammonium chloride) and 1831(octadecyl trimethyl ammonium chloride) was investigated through the measurement of contact angles, zeta potentials, aggregation observation, adsorption and sedimentation. The results show that quaternary ammonium salts can enhance the hydrophobicity and reduce the electronegativity of particle surface, and thus induce a strong hydrophobic aggregation of slurry fine particles which promotes the settlement of coal slurry water. The adsorption of quaternary ammonium salts on slurry particles increases with the increase of alkyl chain length and reagent dosage, and will reach equilibrium when the dosage reaches a certain value. Weak alkaline conditions also can promote quaternary ammonium salts to be adsorbed on the coal slurry fine particles. In addition, reasonable energy input and a chemical environment of weak alkaline solution are conducive to hydrophobic aggregation settlement of high muddied coal slurry water with quaternary ammonium salts. The main mechanism of hydrophobic aggregation of coal slurry particles with quaternary ammonium salts is 'adsorption charge neutralization' and hydrophobic interaction.

  13. Production of a pellet fuel from Illinois coal fines. Technical report, September 1--November 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Rapp, D.; Lytle, J.; Berger, R.

    1994-12-31

    The primary goal of this research is to produce a pellet fuel from low-sulfur Illinois coal fines which could burn with emissions of less than 1.8 lbs SO{sub 2}/10{sup 6} Btu in stoker-fired boilers. The significance of 1.8 lbs SO{sub 2}/10{sup 6} Btu is that in the Chicago (9 counties) and St. Louis (2 counties) metropolitan areas, industrial users of coal currently must comply with this level of emissions. Stokers are an attractive market for pellets because pellets are well-suited for this application and because western coal is not a competitor in the stoker market. Compliance stoker fuels come from locations such as Kentucky and West Virginia and the price for fuels from these locations is high relative to the current price of Illinois coal. This market offers the most attractive near-term economic environment for commercialization of pelletization technology. For this effort, the authors will be investigating the use of fines from two Illinois mines which currently mine relatively low-sulfur reserves and that discard their fines fraction (minus 100 mesh). The research will involve investigation of multiple unit operations including column flotation, filtration and pellet production. The end result of the effort will allow for an evaluation of the commercial viability of the approach. This quarter pellet production work commenced and planning for collection and processing of a preparation plant fines fraction is underway.

  14. The aerodynamic resistance of the reciprocating grates used for burning coal fines

    Energy Technology Data Exchange (ETDEWEB)

    Panoiu, N.; Mihailescu, L.; Popescu, L.; Grecu, T.; Neaga, C.; Oprea, I.; Simon, D.; Gheorghe, C.

    1987-02-01

    In order to test the burning possibilities of coal fines on boilers equipped with reciprocating grates, tests have been carried out on a stand modelled according to the 10 t/h reciprocating grate boiler. 2 refs., 6 figs., 2 tabs.

  15. Advanced Hydrogen Transport Membrane for Coal Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Schwartz, Joseph [Praxair, Inc., Tonawanda, NY (United States); Porter, Jason [Colorado School of Mines, Golden, CO (United States); Patki, Neil [Colorado School of Mines, Golden, CO (United States); Kelley, Madison [Colorado School of Mines, Golden, CO (United States); Stanislowski, Josh [Univ. of North Dakota, Grand Forks, ND (United States); Tolbert, Scott [Univ. of North Dakota, Grand Forks, ND (United States); Way, J. Douglas [Colorado School of Mines, Golden, CO (United States); Makuch, David [Praxair, Inc., Tonawanda, NY (United States)

    2015-12-23

    A pilot-scale hydrogen transport membrane (HTM) separator was built that incorporated 98 membranes that were each 24 inches long. This separator used an advanced design to minimize the impact of concentration polarization and separated over 1000 scfh of hydrogen from a hydrogen-nitrogen feed of 5000 scfh that contained 30% hydrogen. This mixture was chosen because it was representative of the hydrogen concentration expected in coal gasification. When tested with an operating gasifier, the hydrogen concentration was lower and contaminants in the syngas adversely impacted membrane performance. All 98 membranes survived the test, but flux was lower than expected. Improved ceramic substrates were produced that have small surface pores to enable membrane production and large pores in the bulk of the substrate to allow high flux. Pd-Au was chosen as the membrane alloy because of its resistance to sulfur contamination and good flux. Processes were developed to produce a large quantity of long membranes for use in the demonstration test.

  16. Carbon cycle in advanced coal chemical engineering.

    Science.gov (United States)

    Yi, Qun; Li, Wenying; Feng, Jie; Xie, Kechang

    2015-08-07

    This review summarizes how the carbon cycle occurs and how to reduce CO2 emissions in highly efficient carbon utilization from the most abundant carbon source, coal. Nowadays, more and more attention has been paid to CO2 emissions and its myriad of sources. Much research has been undertaken on fossil energy and renewable energy and current existing problems, challenges and opportunities in controlling and reducing CO2 emission with technologies of CO2 capture, utilization, and storage. The coal chemical industry is a crucial area in the (CO2 value chain) Carbon Cycle. The realization of clean and effective conversion of coal resources, improving the utilization and efficiency of resources, whilst reducing CO2 emissions is a key area for further development and investigation by the coal chemical industry. Under a weak carbon mitigation policy, the value and price of products from coal conversion are suggested in the carbon cycle.

  17. Formation of fine particles in co-combustion of coal and solid recovered fuel in a pulverized coal-fired power station

    DEFF Research Database (Denmark)

    Wu, Hao; Pedersen, Anne Juul; Glarborg, Peter

    2011-01-01

    Fine particles formed from combustion of a bituminous coal and co-combustion of coal with 7 th% (thermal percentage) solid recovered fuel (SRF) in a pulverized coal-fired power plant were sampled and characterized in this study. The particles from dedicated coal combustion and co-combustion both...... appear to be an important formation mechanism. The elemental composition of the particles from coal combustion showed that S and Ca were significantly enriched in ultrafine particles and P was also enriched considerably. However, compared with supermicron particles, the contents of Al, Si and K were...

  18. THE STUDY OF THE BASIC THEORY AND THE APPLICATION OF REMOVAL PYRITE AND ASH FROM FINE COAL WITH ELECTROSTATIC SEPARATOR

    Institute of Scientific and Technical Information of China (English)

    章新喜; 陈清加

    1996-01-01

    The effect of removing pyrite and ash from fine coal with electrostatic separator is determined by the electric property of coal, the distribution of corona ion and electrostatic field, and the disperse and even feed. The dielectric constant of coal and mineral matter is studied in this paper and the amendment has been made to survey theory. The oscillogram is adopted to study the distribution of corona ion and electrostatic field. The paper details the study of remoing pyrite and ash from fine coal, and the test results demonstrate the high efficiency of removing pyrite and ash with electrostatic separator.

  19. Advanced physical coal cleaning to comply with potential air toxic regulations. Quarterly report, 1 December 1994--28 February 1995

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q.; Paul, B.C.; Wang, D.

    1995-12-31

    Studies have indicated that the potentially hazardous trace elements found in coal have a strong affinity for coal pyrite. Thus, by maximizing the rejection of pyrite, one can minimize the trace element content of a given coal while also reducing sulfur emissions. The pyrite in most Illinois Basin coals, however, is finely disseminated within the coal matrix. Therefore, to remove the pyrite using physical coal cleaning techniques, the pyrite must be liberated by grinding the coal to ultrafine particle sizes. Fortunately, the coals being fed to pulverized coal boilers (PCB) are already ground to a very fine size, i.e., 70% passing 200 mesh. Therefore, this research project will investigate the use of advanced fine coal cleaning technologies for cleaning PCB feed as a compliance strategy. Work in this quarter has focused on the processing of a PCB feed sample collected from Central Illinois Power`s Newton Power Station using column flotation and an enhanced gravity separator as separate units and in a circuitry arrangement. The PCB feed sample having a low ash content of about 12% was further cleaned to 6% while achieving a very high energy recovery of about 90% in a single stage column flotation operation. Enhanced gravity treatment is believed to be providing excellent total sulfur rejection values, although with inferior ash rejection for the {minus}400 mesh size fraction. The circuitry arrangement with the Falcon concentrator as the primary cleaner followed by the Microcel column resulted in an excellent ash rejection performance, which out performed the release analysis. Trace element analyses of the samples collected from these tests will be conducted during the next report period.

  20. Fine coal dewatering enhancement using mechanical thermal techniques

    Energy Technology Data Exchange (ETDEWEB)

    Patwardhan, A.; Mondal, K.; Chugh, Y.P.; Ping, H.; Singh, N. [Southern Illinois University-Carbondale, Carbondale, IL (USA). Department of Mining & Mineral Resources Engineering

    2002-07-01

    Studies were conducted in a laboratory pressure filter to evaluate and enhance the dewatering potential of thickener underflow samples from two operating coal mines in Illinois mining the No. 6 and No. 5 seams. Physical properties such as, size distribution, zeta potential variation with pH, microstructure and particle shape and ash content were characterized. In addition cake microstructure data was obtained through scanning electron microscopy. Experiments were conducted at a pressure of 42 psig. The initial solids content was varied from 8 to 30% to determine the impact of initial solids concentration on dewatering performance. A host of chemical treatments involving different surfactants and electrolytes were evaluated. In addition, mechanical agitation of cake and hot water treatment of the slurry was attempted. The introduction of copper ions into the slurry resulted in enhanced filtration rates due to reduced specific resistance to filtrate flow and increased porosity of the cake. Use of cationic and anionic surfactants reduced the total residual moisture by over 4%. The combined effect of a surfactant and copper ion resulted in further reduction in cake moisture along with significant improvement in dewatering rates. Elevating the temperature of the slurry to 55{degree}C showed only a slight improvement in filtration rate but produced the most compact cake with the lowest moisture content. Significant improvement in the dewatering kinetics from addition of electrolytes was also observed for the Illinois No. 5 seam sample. Statistical analysis of experimental data indicates dewatering enhancements as a result of electrolyte addition, hot water treatment and mechanical agitation. 20 refs., 5 figs., 7 tabs.

  1. Coal and char studies by advanced EMR techniques

    Energy Technology Data Exchange (ETDEWEB)

    Belford, R.L.; Clarkson, R.B.; Odintsov, B.M.

    1999-03-31

    Advanced magnetic resonance (EMR) methods are used to examine properties of coals, chars, and molecular species related to constituents of coal. During this grant period, further progress was made on proton NMR and low-frequency dynamic nuclear polarization (DNP) to examine the interaction between fluids such as water and the surface of suspended char particles. Effects of char particle size and type on water nuclear spin relaxation, T2, were measured and modeled.

  2. Synergistic Utilization of Coal Fines and Municipal Solid Waste in Coal-Fired Boilers. Phase I Final Report

    Energy Technology Data Exchange (ETDEWEB)

    V. Zamansky; P. Maly; M. Klosky

    1998-06-12

    A feasibility study was performed on a novel concept: to synergistically utilize a blend of waste coal fines with so-called E-fuel for cofiring and reburning in utility and industrial boilers. The E-fuel is produced from MSW by the patented EnerTech's slurry carbonization process. The slurry carbonization technology economically converts MSW to a uniform, low-ash, low-sulfur, and essentially chlorine-free fuel with energy content of about 14,800 Btu/lb.

  3. DEVELOPMENT OF DEWATERING AIDS FOR MINERALS AND COAL FINES

    Energy Technology Data Exchange (ETDEWEB)

    Roe-Hoam Yoon; Ramazan Asmatulu; Ismail Yildirim; William Jansen; Jinmig Zhang; Brad Atkinson; Jeff Havens

    2004-07-01

    MCT has developed a suite of novel dewatering chemicals (or aids) that are designed to cause a decrease in the capillary pressures of the water trapped in a filter cake by (1) decreasing the surface tension of water, (2) increasing the contact angles of the particles to be dewatered, and (3) causing the particles to coagulate, all at the same time. The decrease in capillary pressure in turn causes an increase in the rate filtration, an increase in throughput, and a decrease in pressure drop requirement for filtration. The reagents are used frequently as blends of different chemicals in order to bring about the changes in all of the process variables noted above. The minerals and coal samples tested in the present work included copper sulfide, lead sulfide, zinc sulfide, kaolin clay, talc, and silica. The laboratory-scale test work included studies of reagent types, drying cycle times, cake thickness, slurry temperature, conditioning intensity and time, solid content, and reagent dosages. To better understand the mechanisms involved, fundamental studies were also conducted. These included the measurements of the contact angles of the particles to be dewatered (which are the measures of particle hydrophobicity) and the surface tensions of the filtrates produced from dewatering tests. The results of the laboratory-scale filtration experiments showed that the use of the novel dewatering aids can reduce the moistures of the filter cake by 30 to 50% over what can be achieved using no dewatering aids. In many cases, such high levels of moisture reductions are sufficient to obviate the needs for thermal drying, which is costly and energy intensive. Furthermore, the use of the novel dewatering aids cause a substantial increase in the kinetics of dewatering, which in turn results in increased throughput. As a result of these technological advantages, the novel dewatering aids have been licensed to Nalco, which is one of the largest mining chemicals companies of the world. At

  4. Fine analysis on advanced detection of transient electromagnetic method

    Institute of Scientific and Technical Information of China (English)

    Wang Bo; Liu Shengdong; Yang Zhen; Wang Zhijun; Huang Lanying

    2012-01-01

    Fault fracture zones and water-bearing bodies in front of the driving head are the main disasters in mine laneways,thus it is important to perform their advanced detection and prediction in advance in order to provide reliable technical support for the excavation.Based on the electromagnetic induction theory,we analyzed the characteristics of primary and secondary fields with a positive and negative wave form of current,proposed the fine processing of the advanced detection with variation rate of apparent resistivity and introduced in detail the computational formulae and procedures.The result of physical simulation experiments illustrate that the tectonic interface of modules can be judged by first-order rate of apparent resistivity with a boundary error of 5%,and the position of water body determined by the fine analysis method agrees well with the result of borehole drilling.This shows that in terms of distinguishing structure and aqueous anomalies,the first-order rate of apparent resistivity is more sensitive than the secondorder rate of apparent resistivity.However,some remaining problems are suggested for future solutions.

  5. Cake forming and filtering time in the spiral discharging fine coal filtering centrifuge

    Institute of Scientific and Technical Information of China (English)

    ZHANG Wen-jun; LI Yan-feng; TANG Jie

    2012-01-01

    Based on the realization of moving-bed cake filtering,the concepts of static-bed filtering time and moving-bed filtering time in the helical-conveyor fine coal filtering centrifuge were proposed,and the mathematic relations between the time defined and the main factors related were studied in detail.The results show that the static-bed filtering time is the function of the spiral heads and the rotation rate deference between the spiral and the porous drum,while the moving-bed filtering time is the function of the cone angle of the porous drum,the radius of the porous drum,the spiral angle,and the rotation rate deference.The functions deduced are of great significance for fine coal filtering centrifuge's parameters determining and optimizing.It is shown that the filtering centrifuge with smaller spiral angle,smaller rotation rate deference,and smaller cone angle may do a better job for fine coal dewatering.

  6. 21st Century Coal: Advanced Technology and Global Energy Solution

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-06-01

    Coal currently supplies with more than 40% of the world electricity consumption and it essential input of around 70% of world steel production, representing around 30% of the world primary energy supply. This is because coal is cheap, abundant, accessible, widely distributed and easy energy to transport, store and use. For these features, coal is projected to be intensively used in the future. Production and use of coal present a series of issues throughout the whole value chain. While existing technology allows addressing most of them (safety at work, land restoration, mercury, NOx and sulphur emissions avoidance, etc.), CO2 emissions continues to be the biggest challenge for coal use in the future. This report focuses on the technology path to near-zero emissions including useful insights in advanced coal power generation technologies and Carbon Capture, Utilisation and Storage, a promising technology with a large potential which can push Carbon Capture and Storage competitiveness. In addition, the report shows the features of the new generation of coal-fired power plants in terms of flexibility for dynamic operation and grid stability, requirements increasingly needed to operate on grids with significant wind and solar generation.

  7. Advanced coal-fueled industrial cogeneration gas turbine system

    Energy Technology Data Exchange (ETDEWEB)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  8. Regional price targets appropriate for advanced coal extraction

    Science.gov (United States)

    Terasawa, K. L.; Whipple, D. M.

    1980-01-01

    A methodology is presented for predicting coal prices in regional markets for the target time frames 1985 and 2000 that could subsequently be used to guide the development of an advanced coal extraction system. The model constructed is a supply and demand model that focuses on underground mining since the advanced technology is expected to be developed for these reserves by the target years. Coal reserve data and the cost of operating a mine are used to obtain the minimum acceptable selling price that would induce the producer to bring the mine into production. Based on this information, market supply curves can be generated. Demand by region is calculated based on an EEA methodology that emphasizes demand by electric utilities and demand by industry. The demand and supply curves are then used to obtain the price targets. The results show a growth in the size of the markets for compliance and low sulphur coal regions. A significant rise in the real price of coal is not expected even by the year 2000. The model predicts heavy reliance on mines with thick seams, larger block size and deep overburden.

  9. Potential of Hazardous Waste Encapsulation in Concrete Compound Combination with Coal Ash and Quarry Fine Additives.

    Science.gov (United States)

    Lieberman, Roy Nir; Anker, Yaakov; Font, Oriol; Querol, Xavier; Mastai, Yitzhak; Knop, Yaniv; Cohen, Haim

    2015-12-15

    Coal power plants are producing huge amounts of coal ash that may be applied to a variety of secondary uses. Class F fly ash may act as an excellent scrubber and fixation reagent for highly acidic wastes, which might also contain several toxic trace elements. This paper evaluates the potential of using Class F fly ashes (quarry industry as a fixation reagent. The analysis included leaching experiments (EN12457-2) and several analytical techniques (ICP, SEM, XRD, etc.), which were used in order to investigate the fixation procedure. The fine sludge is used as a partial substitute in concrete that can be used in civil engineering projects, as it an environmentally safe product.

  10. Altair jig: an in-plant evaluation for fine coal cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Mohanty, M.K.; Honaker, R.Q.; Patwardhan, A. [South Illinois University, Carbondale, IL (United States). Dept. of Mining & Mineral Resources Engineers

    2002-03-01

    The Altair centrifugal jig is an enhanced gravity technology, whose suitability for fine coal cleaning has been demonstrated through an in-plant study as reported in this paper. A relatively low specific gravity cut-point of 1.50 with a probable error value of 0.11 over a wide particle size range 1 mm x 45 {mu}m is indicative of the excellent separation performance achievable from the Altair jig. Tests performed with and without ragging material were performed with the goal that the latter would provide enhanced throughput capacities. However, although the performance was close to the theoretical limits over the broad range of product grades generated, the no-ragging experiments resulted in a significant loss in coal recovery under the given conditions. Overall, the centrifugal jig achieved 80% ash rejection and 50% total sulfur rejection while recovering nearly 80% of the combustibles.

  11. Application of ultra-flocculation for improving fine coal concentrate dewatering

    Energy Technology Data Exchange (ETDEWEB)

    N.N. Rulyov; B.Y. Korolyov; N.M. Kovalchuk [Ukrainian National Academy of Sciences, Kiev (Ukraine). Institute of Biocolloid Chemistry

    2006-01-15

    The possibility of significant improvements in vacuum filtration of fine coal suspensions through the application of ultra-flocculation was studied. It was shown theoretically that even when present in quantities of a few percent, the ultrafine particles (<10 microns) highly contributed to the hydraulic resistance of the filter cake. The experiments showed that short-term hydrodynamic treatment of the coal suspension at relatively high medium velocity gradients (750 s{sup -1}) performed immediately upon the introduction of the flocculant resulted in significant improvements in the filtration process due to the effect of specifically binding the finest particles. This treatment decreased the hydraulic resistance of the cake on the screen vacuum filter by roughly 1.6 times, decreased the solids content in the filtrate by 4 times and decreased the flocculant consumption by 2 times.

  12. Measurement and modeling of advanced coal conversion processes

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. (Advanced Fuel Research, Inc., East Hartford, CT (USA)); Smoot, L.D.; Brewster, B.S. (Brigham Young Univ., Provo, UT (USA))

    1990-01-01

    The overall objective of this program is the development of predictive capability for the design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. This technology is important to reduce the technical and economic risks inherent in utilizing coal, a feedstock whose variable and often unexpected behavior presents a significant challenge. This program will merge significant advances made at Advanced Fuel Research, Inc. (AFR) in measuring and quantitatively describing the mechanisms in coal conversion behavior, with technology being developed at Brigham Young University (BYU) in comprehensive computer codes for mechanistic modeling of entrained-bed gasification. Additional capabilities in predicting pollutant formation will be implemented and the technology will be expanded to fixed-bed reactors. The foundation to describe coal-specific conversion behavior is AFR's Functional Group (FG) and Devolatilization, Vaporization, and Crosslinking (DVC) models, developed under previous and on-going METC sponsored programs. These models have demonstrated the capability to describe the time dependent evolution of individual gas species, and the amount and characteristics of tar and char. The combined FG-DVC model will be integrated with BYU's comprehensive two-dimensional reactor model, PCGC-2, which is currently the most widely used reactor simulation for combustion or gasification. Success in this program will be a major step in improving in predictive capabilities for coal conversion processes including: demonstrated accuracy and reliability and a generalized first principles'' treatment of coals based on readily obtained composition data. The progress during the fifteenth quarterly of the program is presented. 56 refs., 41 figs., 5 tabs.

  13. NOx, FINE PARTICLE AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT

    Energy Technology Data Exchange (ETDEWEB)

    Jost O.L. Wendt

    2002-08-15

    This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and coal. The objective is to determine the relationship between (1) fraction sludge in the sludge/coal mixture, and (2) combustion conditions on (a) NOx concentrations in the exhaust, (b) the size segregated fine and ultra-fine particle composition in the exhaust, and (c) the partitioning of toxic metals between vapor and condenses phases, within the process. The proposed study will be conducted in concert with an existing ongoing research on toxic metal partitioning mechanisms for very well characterized pulverized coals alone. Both high NOx and low NOx combustion conditions will be investigated (unstaged and staged combustion). Tradeoffs between CO2 control, NOx control, and inorganic fine particle and toxic metal emissions will be determined. Previous research has yielded data on trace metal partitioning for MSS by itself, with natural gas assist, for coal plus MSS combustion together, and for coal alone. We have re-evaluated the inhalation health effects of ash aerosol from combustion of MSS both by itself and also together with coal. We have concluded that ash from the co-combustion of MSS and coal is very much worse from an inhalation health point of view, than ash from either MSS by itself or coal by itself. The reason is that ZnO is not the ''bad actor'' as had been suspected before, but the culprit is, rather, sulfated Zn. The MSS supplies the Zn and the coal supplies the sulfur, and so it is the combination of coal and MSS that makes that process environmentally bad. If MSS is to be burned, it should be burned without coal, in the absence of sulfur.

  14. DEVELOPMENT AND DEMONSTRATION OF INTEGRATED CARBON RECOVERY SYSTEMS FROM FINE COAL PROCESSING WASTE

    Energy Technology Data Exchange (ETDEWEB)

    Y.P. Chugh; D. Patil; A. Patwardhan; R.Q. Honaker; B.K. Parekh; D. Tao; Latif Khan

    2000-07-01

    The project involves the development of an efficient, environmentally friendly system for the economical recovery of carbon from fine-coal refuse ponds. The project will be conducted in two phases. Phase I was involved in the development and evaluation of process equipment and techniques to be used in carbon recovery, product dewatering and reconstitution, and refuse management. Phase II will integrate the various units into a continuously operating circuit that will be demonstrated at a site selected based on the results presented in this study.

  15. Pre-Concentration of Vanadium from Stone Coal by Gravity Using Fine Mineral Spiral

    Directory of Open Access Journals (Sweden)

    Xin Liu

    2016-08-01

    Full Text Available Due to the low grade of V2O5 in stone coal, the existing vanadium extraction technologies face challenges in terms of large handling capacity, high acid consumption and production cost. The pre-concentration of vanadium from stone coal before the extraction process is an effective method to reduce cost. In this study, detailed mineral characterization of stone coal was investigated. It has been confirmed that the vanadium mainly occurs in muscovite and illite. A significant demand for an effective pre-concentration process with simple manipulation for discarding quartz and other gangue minerals is expected. Based on the mineralogical study, a new vanadium pre-concentration process using a fine mineral spiral was investigated. The experimental results showed that the separation process, which was comprised of a rougher and scavenger, could efficiently discard quartz, pyrite and apatite. A final concentrate with V2O5 grade of 1.02% and recovery of 89.6% could be obtained, with 26.9% of the raw ore being discarded as final tailings.

  16. A LOW COST AND HIGH QUALITY SOLID FUEL FROM BIOMASS AND COAL FINES

    Energy Technology Data Exchange (ETDEWEB)

    John T. Kelly; George Miller; Mehdi Namazian

    2001-07-01

    Use of biomass wastes as fuels in existing boilers would reduce greenhouse gas emissions, SO2 and NOx emissions, while beneficially utilizing wastes. However, the use of biomass has been limited by its low energy content and density, high moisture content, inconsistent configuration and decay characteristics. If biomass is upgraded by conventional methods, the cost of the fuel becomes prohibitive. Altex has identified a process, called the Altex Fuel Pellet (AFP) process, that utilizes a mixture of biomass wastes, including municipal biosolids, and some coal fines, to produce a strong, high energy content, good burning and weather resistant fuel pellet, that is lower in cost than coal. This cost benefit is primarily derived from fees that are collected for accepting municipal biosolids. Besides low cost, the process is also flexible and can incorporate several biomass materials of interest The work reported on herein showed the technical and economic feasibility of the AFP process. Low-cost sawdust wood waste and light fractions of municipal wastes were selected as key biomass wastes to be combined with biosolids and coal fines to produce AFP pellets. The process combines steps of dewatering, pellet extrusion, drying and weatherizing. Prior to pilot-scale tests, bench-scale test equipment was used to produce limited quantities of pellets for characterization. These tests showed which pellet formulations had a high potential. Pilot-scale tests then showed that extremely robust pellets could be produced that have high energy content, good density and adequate weatherability. It was concluded that these pellets could be handled, stored and transported using equipment similar to that used for coal. Tests showed that AFP pellets have a high combustion rate when burned in a stoker type systems. While NOx emissions under stoker type firing conditions was high, a simple air staging approach reduced emissions to below that for coal. In pulverized-fuel-fired tests it was

  17. Advanced coal-fired glass melting development program

    Energy Technology Data Exchange (ETDEWEB)

    1991-05-01

    The objective of Phase 1 of the current contract was to verify the technical feasibility and economic benefits of Vortec's advanced combustion/melting technology using coal as the fuel of choice. The objective of the Phase 2 effort was to improve the performance of the primary components and demonstrate the effective operation of a subscale process heater system integrated with a glass separator/reservoir. (VC)

  18. Materials and welding engineering in advanced coal utilization plants

    Energy Technology Data Exchange (ETDEWEB)

    Schuhmacher, D.; Schulze-Frielinghaus, W.; Puetz, J.; Eichhorn, F.; Gaever, E. van

    1983-08-01

    The authors present the findings of studies on welding methods for high-temperature alloys used in advanced coal gasification plants. They discuss weld preparation, automatic TIG welding, MIG welding (also with pulsed arc) and plasma arc welding. The mechanical properties of welded joints before and after age hardening are investigated, and the results of fatigue and corrosion tests are presented. The welding methods are compared with a view to their suitability for high-temperature materials.

  19. Burnout prediction using advance image analysis coal characterization techniques

    Energy Technology Data Exchange (ETDEWEB)

    Edward Lester; Dave Watts; Michael Cloke [University of Nottingham, Nottingham (United Kingdom). School of Chemical Environmental and Mining Engineering

    2003-07-01

    The link between petrographic composition and burnout has been investigated previously by the authors. However, these predictions were based on 'bulk' properties of the coal, including the proportion of each maceral or the reflectance of the macerals in the whole sample. Combustion studies relating burnout with microlithotype analysis, or similar, remain less common partly because the technique is more complex than maceral analysis. Despite this, it is likely that any burnout prediction based on petrographic characteristics will become more accurate if it includes information about the maceral associations and the size of each particle. Chars from 13 coals, 106-125 micron size fractions, were prepared using a Drop Tube Furnace (DTF) at 1300{degree}C and 200 millisecond and 1% Oxygen. These chars were then refired in the DTF at 1300{degree}C 5% oxygen and residence times of 200, 400 and 600 milliseconds. The progressive burnout of each char was compared with the characteristics of the initial coals. This paper presents an extension of previous studies in that it relates combustion behaviour to coals that have been characterized on a particle by particle basis using advanced image analysis techniques. 13 refs., 7 figs.

  20. A comparison between ceramic membrane filters and conventional fabric filters for fine particulate removal from a coal-fired industrial boiler

    Energy Technology Data Exchange (ETDEWEB)

    Miller, B.G.; Wincek, R.T.; Glick, D.C.; Scaroni, A.W. [Pennsylvania State Univ., University Park, PA (United States); Drury, K. [Corning Inc., Painted Post, NY (United States); Makris [Corning Inc., Acton, MA (United States); Stubblefield, D.J. [Corning Inc., Corning, NY (United States)

    1998-12-31

    Penn State is developing technologies for ultralow emissions when firing coal-based fuels, i.e., micronized coal and coal-water slurry fuel (CWSF) in industrial boilers. Emissions being addressed are SO{sub 2}, NOx, fine particulate matter (PM{sub 10} and PM{sub 2.5}), and air toxics (trace elements and volatile organic compounds). Results from trace element and polynuclear aromatic hydrocarbon emissions testing, when firing coal-based fuels, are reported elsewhere in these proceedings. This paper discusses the evaluation of ceramic membrane filters for fine particulate removal in a package boiler when firing micronized coal and CWSF.

  1. A fine coal circuitry study using column flotation and gravity separation. Quarterly report, 1 March 1995--31 May 1995

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q. [Southern Illinois Univ., Carbondale, IL (United States); Reed, S. [Kerr-McGee Coal Corp., Oklahoma City, OK (United States)

    1995-12-31

    Column flotation provides excellent recovery of ultrafine coal while producing low ash content concentrates. However, column flotation is not efficient for treating fine coal containing significant amounts of mixed-phase particles. Fortunately, enhanced gravity separation has proved to have the ability to treat the mixed-phased particles more effectively. A disadvantage of gravity separation is that ultrafine clay particles are not easily rejected. Thus, a combination of these two technologies may provide a circuit that maximizes both the ash and sulfur rejection that can be achieved by physical coal cleaning while maintaining a high energy recovery. This project is studying the potential of using different combinations of gravity separators, i.e., a Floatex hydrosizer and a Falcon Concentrator, and a proven flotation column, which will be selected based on previous studies by the principle investigator. During this reporting period, an extensive separation performance comparison between a pilot-scale Floatex Density Separator (18{times}18-inch) and an existing spiral circuit has been conducted at Kerf-McGee Coal Preparation plan for the treatment of nominally {minus}16 mesh coal. The results indicate that the Floatex is a more efficient separation device (E{sub p}=0.12) than a conventional coal spiral (E{sub p}=0.18) for Illinois seam coals. In addition, the treatment of {minus}100 mesh Illinois No. 5 fine coal from the same plant using Falcon concentrator, column flotation (Packed-Column) and their different combinations was also evaluated. For a single operation, both Falcon concentrator and column flotation can produce a clean coal product with 90% combustible recovery and 5% ash content. In the case of the combined circuit, column flotation followed by the Falcon achieved a higher combustible recovery value (about 75%) than that obtained by the individual units while maintaining an ash content less than 3%.

  2. Mineral processing and characterization of coal waste to be used as fine aggregates for concrete paving blocks

    Directory of Open Access Journals (Sweden)

    C. R. Santos

    Full Text Available Commercial coal production in the southern region of Brazil has been occurring since the beginning of the twentieth century. Due to the geological characteristics of the region, large amounts of solid wastes are generated. The aim of this work was to evaluate the use of coal waste to produce concrete paving blocks. A procedure to process the coal waste with the purpose of reducing the sulfur content and changing the particle size distribution of the material to meet the specification of fine aggregates was developed. The methodology considered the following steps: (a sampling of a coal mining waste; (b gravity separation of the fraction with specific gravity between 2.4 and 2.8; (c comminution of the material and particle size analysis; (d technological characterization of the material and production of concrete paving blocks; and (e acidity generation prediction (environmental feasibility. The results showed that the coal waste considered in this work can be used to replace conventional sand as a fine aggregate for concrete paving blocks in a proportion of up to 50%. This practice can result in cleaner coal production and reduce the demand for exploitation of sand deposits.

  3. Suppression of fine ash formation in pulverized coal flames. Final technical report, September 30, 1992--January 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Kramlich, J.C.; Chenevert, B.; Park, Jungsung; Hoffman, D.A.; Butcher, E.K.

    1996-07-19

    Coal ash, and particularly fine fly ash, remain one of the principal practical and environmental problems in coal-based power generation. In particular, submicron aerosols are identified with direct inhalation risk. Submicron ash is thought to arise from mineral vaporization during char combustion, followed by nucleation, condensation and coagulation to yield an aerosol. While aerosols are predominantly made out of volatile alkali minerals, they also can include refractory oxides that are chemically reduced to more volatile forms within the char particle and vaporized. Most of the ash of size greater than 1 {mu}m is generated by agglomeration of mineral as the char particle bums out. These two principal mechanisms are thought to account for most of the ash generated in coal combustion. Previous research has shown that various forms of coal treatment can influence the yields of fine ash from combustion. The research reported here investigates various forms of treatment, including physical coal cleaning, aerodynamic sizing, degree of grinding, and combinations of these on both aerosol yields and on yields of fine residual ash (1-4 {mu}m). The work also includes results from the combustion of artificial chars that include individual mineral elements. This research shows that these various forms of coal treatment can significantly change ash characteristics. While none of the treatments affected the bulk of the residual ash size distribution significantly, the yield of the ash aerosol mode (d<0.5 {mu}m) and fine residual ash mode (1-4 {mu}m) are changed by the treatments.

  4. Advanced Portable Fine Water Mist Fire Extinguisher for Spacecraft Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Fine water mist (FWM) is a promising replacement technology for fire suppression on the next generation of manned spacecraft. It offers advantages in performance,...

  5. Development history of coal mine and advanced mining technology; Tanko no rekishi to saitan gijutsu no shinpo

    Energy Technology Data Exchange (ETDEWEB)

    Nohara, H. [Tokyo (Japan)

    2000-04-20

    Japanese coal mine was get a full supply for the construction of the modernize nation in Meiji and the reconstruction of the industry after the second world war. This perfection was completed by the full coal resources and the advanced coal mining technology. But, japanese recent coal seam is too deep for the economical mining. And yet, advanced coal mining technology of japan is necessary for the coal mine of the developing country. (author)

  6. Structure and properties of advanced fine grained steels produced using novel thermal treatments

    OpenAIRE

    Vuorinen, Esa

    2012-01-01

    Fine grained advanced steels exhibit favourable mechanical properties for applications requiring high strength, ductility and impact toughness. These properties result from a microstructure containing a fine distribution of several phases including ferrite, austenite, martensite and bainite. The bainite phase is in the form of fine lamellas of ferrite and carbon-enriched austenite which due to proper control of the chemical composition is lacking the nanometre scaled carbides associated with ...

  7. Evaluation of hyperbaric filtration for fine coal dewatering. Fourth quarterly technical progress report: June 1, 1993--September 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K. [Univ. of Kentucky, Lexington, KY (United States); Hogg, R. [Pennsylvania State Univ., University Park, PA (United States); Fonseca, A. [CONSOL Inc., Library, PA (United States)

    1993-12-31

    The main objectives of the project are to investigate the fundamental aspects of particle-liquid interaction in fine coal dewatering, to conduct laboratory and pilot plant studies on the applicability of hyperbaric filter systems and to develop process conditions for dewatering of fine clean coal to less than 20 percent moisture. The program consist of three phases, Model Development, Laboratory Studies, and Field Testing. The Pennsylvania State University is leading efforts in Phase 1, the University of Kentucky in Phase 2, and Consol Inc. in Phase 3 of the program. All three organizations are involved in all the three phases of the program. The Pennsylvania State University is developing a theoretical model for hyperbaric filtration systems, whereas the University of Kentucky is conducting experimental studies to investigate fundamental aspects of particle-liquid interaction and application of high pressure filter in fine coal dewatering. The optimum filtration conditions identified in phase 1 and 2 will be tested in a Consol Inc. coal preparation plant using an Andritz Ruthner portable hyperbaric filtration unit.

  8. The forms of trace metals in an Illinois basin coal by x-ray absorption fine structure spectroscopy

    Science.gov (United States)

    Chou, I.-Ming; Bruinius, J.A.; Lytle, J.M.; Ruch, R.R.; Huggins, Frank E.; Huffman, G.P.; Ho, K.K.

    1997-01-01

    Utilities burning Illinois coals currently do not consider trace elements in their flue gas emissions. After the US EPA completes an investigation on trace elements, however, this may change and flue gas emission standards may be established. The mode of occurrence of a trace element may determine its cleanability and Hue gas emission potential. X-ray Absorption Fine Structure (XAFS) is a spectroscopic technique that can differentiate the mode of occurrence of an element, even at the low concentrations that trace elements are found in coal. This is principally accomplished by comparing the XAFS spectra of a coal to a database of reference sample spectra. This study evaluated the technique as a potential tool to examine six trace elements in an Illinois #6 coal. For the elements As and Zn, the present database provides a definitive interpretation on their mode of occurrence. For the elements Ti, V, Cr, and Mn the database of XAFS spectra of trace elements in coal was still too limited to allow a definitive interpretation. The data obtained on these elements, however, was sufficient to rule out several of the mineralogical possibilities that have been suggested previously. The results indicate that XAFS is a promising technique for the study of trace elements in coal.

  9. Process development studies on recovery of clean coal from ultra fine hardcoal tailings using enhanced gravity separator

    Energy Technology Data Exchange (ETDEWEB)

    Ozgen, S.; Turksoy, V.O.; Sabah, E.; Oruc, F. [Afyon Kocatepe Univ., Afyonkarahisar (Turkey). Dept. of Mining Engineering

    2009-10-15

    Gravity-based processing methods were used to process and recover clean coal from ultra-fine hardcoal tailings at a site in Turkey. The coal samples were analyzed using X-ray diffraction and X-ray fluorescence. A hydrocyclone was used to conduct classification tests and to separate the clay minerals from the coal. The effects of various operating parameters were also investigated. Regression analysis was used to characterize the relationship between the ash content and coal recovery rate and the feed solid, inlet pressure, diameter of vortex, and diameter of apex variables of the hydrocyclone. The effects of feed pressure were also investigated. The study showed that coal can be economically recovered from hardcoal tailings containing clay minerals. It was concluded that a coal sample with 6.98 per cent ash content and a net calorific value of 28,778 kJ was obtained with a weight recovery of 61.73 per cent. 25 refs., 8 tabs., 18 figs.

  10. Advanced Coal-Fueled Gas Turbine Program. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  11. [Based on Curing Age of Calcined Coal Gangue Fine Aggregate Mortar of X-Ray Diffraction and Scanning Electron Microscopy Analysis].

    Science.gov (United States)

    Dong, Zuo-chao; Xia, Jun-wu; Duan, Xiao-mu; Cao, Ji-chang

    2016-03-01

    By using X-ray diffraction (XRD) and environmental scanning electron microscope (SEM) analysis method, we stud- ied the activity of coal gangue fine aggregate under different calcination temperature. In view of the activity of the highest-700 degrees C high temperature calcined coal gangue fine aggregate mortar of hydration products, microstructure and strength were discussed in this paper, and the change laws of mortar strength with curing age (3, 7, 14, 28, 60 and 90 d) growth were analyzed. Test results showed that coal gangue fine aggregate with the increase of calcination temperature, the active gradually increases. When the calcination temperature reaches 700 degrees C, the activity of coal gangue fine aggregate is the highest. When calcining temperature continues to rise, activity falls. After 700 degrees C high temperature calcined coal gangue fine aggregate has obvious ash activity, the active components of SiO2 and Al2 O3 can be with cement hydration products in a certain degree of secondary hydration reaction. Through on the top of the activity of different curing age 700 degrees C high temperature calcined coal gangue fine aggregate mortar, XRD and SEM analysis showed that with the increase of curing age, secondary hydration reaction will be more fully, and the amount of hydration products also gradually increases. Compared with the early ages of the cement mortar, the products are more stable hydration products filling in mortar microscopic pore, which can further improve the microstructure of mortar, strengthen the interface performance of the mortar. The mortar internal structure is more uniform, calcined coal gangue fine aggregate and cement mortar are more of a strong continuous whole, which increase the later strength of hardened cement mortar, 700 degrees C high temperature calcined coal gangue fine aggregate pozzolanic effect is obvious.

  12. Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

    Energy Technology Data Exchange (ETDEWEB)

    Rader, Jeff; Aguilar, Kelly; Aldred, Derek; Chadwick, Ronald; Conchieri,; Dara, Satyadileep; Henson, Victor; Leininger, Tom; Liber, Pawel; Nakazono, Benito; Pan, Edward; Ramirez, Jennifer; Stevenson, John; Venkatraman, Vignesh

    2012-11-30

    This report describes the development of the design of an advanced dry feed system that was carried out under Task 4.0 of Cooperative Agreement DE-FE0007902 with the US DOE, “Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the use of Low- Rank Coal.” The resulting design will be used for the advanced technology IGCC case with 90% carbon capture for sequestration to be developed under Task 5.0 of the same agreement. The scope of work covered coal preparation and feeding up through the gasifier injector. Subcomponents have been broken down into feed preparation (including grinding and drying), low pressure conveyance, pressurization, high pressure conveyance, and injection. Pressurization of the coal feed is done using Posimetric1 Feeders sized for the application. In addition, a secondary feed system is described for preparing and feeding slag additive and recycle fines to the gasifier injector. This report includes information on the basis for the design, requirements for down selection of the key technologies used, the down selection methodology and the final, down selected design for the Posimetric Feed System, or PFS.

  13. Advanced Coal Conversion Process Demonstration Project. Technical progress report, January 1, 1993--December 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-02-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1993, through December 31, 1993. This project demonstrates an advanced, thermal, coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low- rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal processing, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and operated in an extended startup mode through August 10, 1993, when the facility became commercial. Rosebud SynCoal Partnership instituted an aggressive program to overcome startup obstacles and now focuses on supplying product coal to customers. Significant accomplishments in the history of the SynCoal{reg_sign} process development are shown in Appendix A.

  14. Hard Coal Fly Ash and Silica-Effect of Fine Particulate Matter Deposits on Brassica chinensis

    Directory of Open Access Journals (Sweden)

    Christian Ulrichs

    2009-01-01

    Full Text Available Problem statement: One focus in recent atmospheric pollution research is on fine Particle Matter (PM, especially as result of increasing traffic and anthropogenic activity in urban areas. Here, the impact on animal and human health has been in the center of many studies. Despite the fact that PM depositions can affect plants on the long term, there are only few studies about the impact on plants conducted. Approach: Therefore we studied the impact of PM on plants, using naturally occurring silica dusts (diatomaceous earth and hard Coal Fly Ash (CFA from burning processes. Dusts were applied onto Brassica chinensis L. using a simple duster (covering upper leaf surfaces or electrostatically (covering leaf upper and -underside. Results: Main components of the tested CFA are SO42-, K, Ca and NH4+. The pH value of eluates was found to be around 9.5 in CFA and 5.7 in silica. B. chinensis was insensitive towards the high pH and showed no growth reduction when grown in silica or CFA substrate. PM deposition on leaf surfaces results through shading in a reduced photosynthetic activity. The reduction is relatively higher at higher light intensities. Photosynthesis stays reduced after removal of silica PM from leaf surfaces. We assume that stomata get cloaked by small particles and that silica absorbs lipids from the epicuticle resulting in a general stress reaction. Smaller sized silica particles resulted in a higher reduction of CO2-absorption. Next to particle size is the photosynthesis negatively correlated with exposure time for silica PM. The chlorophyll fluorescence data indicate that dust-covered leaves exhibited significantly lower quantum yield of PS II and a reduced quantum efficiency of PS II and therefore supported the gas exchange data. Conclusion: Reduced photosynthetic performance would be expected to reduce growth and productivity of B. chinensis. In contrast to silica hard coal fly ash

  15. Low-rank coal research

    Energy Technology Data Exchange (ETDEWEB)

    Weber, G. F.; Laudal, D. L.

    1989-01-01

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  16. In-plant testing of a novel coal cleaning circuit using advanced technologies. Final technical report, September 1, 1995--August 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mining Engineering; Reed, S.; Mohanty, M.K.

    1997-05-01

    A circuit comprised of advanced fine coal cleaning technologies was evaluated in an operating preparation plant to determine circuit performance and to compare the performance with current technologies used to treat -16 mesh fine coal. The circuit integrated a Floatex hydrosizer, a Falcon enhanced gravity concentrator and a Jameson flotation cell. A Packed-Column was used to provide additional reductions in the pyritic sulfur and ash contents by treatment of the Floatex-Falcon-Jameson circuit product. For a low sulfur Illinois No. 5 coal, the pyritic sulfur content was reduced from 0.67% to 0.34% at a combustible recovery of 93.2%. The ash content was decreased from 27.6% to 5.84%, which equates to an organic efficiency of 95% according to gravity-based washability data. The separation performance achieved on a high sulfur Illinois No. 5 coal resulted in the rejection of 72.7% of the pyritic sulfur and 82.3% of the ash-forming material at a recovery of 8 1 %. Subsequent pulverization of the cleaned product and retreatment in a Falcon concentrator and Packed-Column resulted in overall circuit ash and pyritic sulfur rejections of 89% and 93%, respectively, which yielded a pyritic sulfur content reduction from 2.43% to 0.30%. This separation reduced the sulfur dioxide emission rating of an Illinois No. 5 coal from 6.21 to 1.75 lbs SO{sub 2}/MBTU, which is Phase I compliance coal. A comparison of the results obtained from the Floatex-Falcon-Jameson circuit with those of the existing circuit revealed that the novel fine coal circuit provides 10% to 20% improvement in mass yield to the concentrate while rejecting greater amounts of ash and pyritic sulfur.

  17. Sensor for Individual Burner Control of Coal Firing Rate, Fuel-Air Ratio and Coal Fineness Correlation

    Energy Technology Data Exchange (ETDEWEB)

    R. Demler

    2006-04-01

    Accurate, cost-efficient monitoring instrumentation has long been considered essential to the operation of power plants. Nonetheless, for the monitoring of coal flow, such instrumentation has been sorely lacking and technically difficult to achieve. With more than half of the electrical power in the United States currently supplied by coal, energy generated by this resource is critical to the US economy. The demand for improvement in this area has only increased as a result of the following two situations: First, deregulation has produced a heightened demand for both reduced electrical cost and improved grid connectivity. Second, environmental concerns have simultaneously resulted in a need for both increased efficiency and reduced carbon and NOx emissions. A potential approach to addressing both these needs would be improvement in the area of combustion control. This would result in a better heat rate, reduced unburned carbon in ash, and reduced NOx emissions. However, before feedback control can be implemented, the ability to monitor coal flow to the burners in real-time must be established. While there are several ''commercially available'' products for real-time coal flow measurement, power plant personnel are highly skeptical about the accuracy and longevity of these systems in their current state of development. In fact, following several demonstration projects of in-situ coal flow measurement systems in full scale utility boilers, it became obvious that there were still many unknown influences on these instruments during field applications. Due to the operational environment of the power plant, it has been difficult if not impossible to sort out what parameters could be influencing the various probe technologies. Additionally, it has been recognized for some time that little is known regarding the performance of coal flow splitters, even where rifflers are employed. Often the coal flow distribution from these splitters remains mal

  18. Clean electricity through advanced coal technologies handbook of pollution prevention and cleaner production

    CERN Document Server

    Cheremisinoff, Nicholas P

    2012-01-01

    Coal power is a major cause of air pollution and global warming and has resulted in the release of toxic heavy metals and radionuclides, which place communities at risk for long-term health problems. However, coal-fired power plants also currently fuel 41% of global electricity. Clean Electricity Through Advanced Coal Technologies discusses the environmental issues caused by coal power, such as air pollution, greenhouse gas emissions and toxic solid wastes. This volume focuses on increasingly prevalent newer generation technologies with smaller environmental footprints than the existing c

  19. New coal dewatering technology turns sludge to powder

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-03-15

    Virginian Tech's College of Engineering's Roe-Hoan Yoon and his group have developed a hyperbaric centrifuge that can dewater coal as fine as talcum powder. Such coal fines presently must be discarded by even the most advanced coal cleaning plants because of their high moisture content. The new technology can be used with the Microcel technology to remove ash, to re-mine the fine coal discarded to impoundments and to help minimize waste generation. Virginia Tech has received $1 million in funding from the US Department of State to also help the Indian coal industry produce a cleaner product. 1 photo.

  20. Geotechnical/geochemical characterization of advanced coal process waste streams: Task 2

    Energy Technology Data Exchange (ETDEWEB)

    Moretti, C.J.; Olson, E.S.

    1992-09-01

    Successful disposal practices for solid wastes produced from advanced coal combustion and coal conversion processes must provide for efficient management of relatively large volumes of wastes in a cost-effective and environmentally safe manner. At present, most coal-utilization solid wastes are disposed of using various types of land-based systems, and it is probable that this disposal mode will continue to be widely used in the future for advanced process wastes. Proper design and operation of land-based disposal systems for coal combustion wastes normally require appropriate waste transfer, storage, and conditioning subsystems at the plant to prepare the waste for transport to an ultimate disposal site. Further, the overall waste management plan should include a by-product marketing program to minimize the amount of waste that will require disposal. In order to properly design and operate waste management systems for advanced coal-utilization processes, a fundamental understanding of the physical properties, chemical and mineral compositions, and leaching behaviors of the wastes is required. In order to gain information about the wastes produced by advanced coal-utilization processes, 55 waste samples from 16 different coal gasification, fluidized-bed coal combustion (FBC), and advanced flue gas scrubbing processes were collected. Thirty-four of these wastes were analyzed for their bulk chemical and mineral compositions and tested for a detailed set of disposal-related physical properties. The results of these waste characterizations are presented in this report. In addition to the waste characterization data, this report contains a discussion of potentially useful waste management practices for advanced coal utilization processes.

  1. Advanced liquefaction using coal swelling and catalyst dispersion techniques

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. (Auburn Univ., AL (United States)); Gutterman, C. (Foster Wheeler Development Corp., Livingston, NJ (United States)); Chander, S. (Pennsylvania State Univ., University Park, PA (United States))

    1992-08-26

    Research in this project centers upon developing a new approach to the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates all aspects of the coal liquefaction process including coal selection, pretreatment, coal swelling with catalyst impregnation, coal liquefaction experimentation, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. The project is being carried out under contract to the United States Department of Energy. On May 28, 1992, the Department of Energy authorized starting the experimental aspects of this projects; therefore, experimentation at Amoco started late in this quarterly report period. Research contracts with Auburn University, Pennsylvania State University, and Foster Wheeler Development Corporation were signed during June, 1992, so their work was just getting underway. Their work will be summarized in future quarterly reports. A set of coal samples were sent to Hazen Research for beneficiation. The samples were received and have been analyzed. The literature search covering coal swelling has been up-dated, and preliminary coal swelling experiments were carried out. Further swelling experimentation is underway. An up-date of the literature on the liquefaction of coal using dispersed catalysts is nearing completion; it will be included in the next quarterly report.

  2. Advanced Coal Conversion Process Demonstration Project. Final technical progress report, January 1, 1995--December 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1995 through December 31, 1995. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal Process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal Process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,5000 to 9,000 British thermal units per pound (Btu/lb), by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. During this reporting period, the primary focus for the ACCP Demonstration Project team was to expand SynCoal market awareness and acceptability for both the products and the technology. The ACCP Project team continued to focus on improving the operation, developing commercial markets, and improving the SynCoal products as well as the product`s acceptance.

  3. Thermodynamic Analysis of Desulfurization of Fine Coal by Electrochemical Reduction Flotation

    Institute of Scientific and Technical Information of China (English)

    ZHAO Wei; ZHU Hong; ZHANG Yu

    2003-01-01

    Problems in desulfurization of coal by electrochemical reduction is analyzed and calculated. The result shows that 1) the △rGm function of the reaction of pyrite into FeS and the modifying reaction decreasing the oxygenous functions on coal surface is smaller than zero in a spontaneous reaction, and greater than zero in a nonspontaneous reaction; 2) the △rGm value can be adjusted by pH and the dosage of electrolyte to make it be greater than zero , which is favorable for the modifying reaction and useful for desulfurization of coal. The research has provided a theoretical foundation for determining reasonable technical parameters of desulfurization

  4. Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama. Technical progress report, Run 243 with Illinois 6 coal

    Energy Technology Data Exchange (ETDEWEB)

    1984-02-01

    This report presents the operating results for Run 243 at the Advanced Coal Liquefaction R and D Facility in Wilsonville, Alabama. This run was made in an Integrated Two-Stage Liquefaction (ITSL) mode using Illinois 6 coal from the Burning Star mine. The primary objective was to demonstrate the effect of a dissolver on the ITSL product slate, especially on the net C/sub 1/-C/sub 5/ gas production and hydrogen consumption. Run 243 began on 3 February 1983 and continued through 28 June 1983. During this period, 349.8 tons of coal was fed in 2947 hours of operation. Thirteen special product workup material balances were defined, and the results are presented herein. 29 figures, 19 tables.

  5. Organic coal-water fuel: Problems and advances (Review)

    Science.gov (United States)

    Glushkov, D. O.; Strizhak, P. A.; Chernetskii, M. Yu.

    2016-10-01

    The study results of ignition of organic coal-water fuel (OCWF) compositions were considered. The main problems associated with investigation of these processes were identified. Historical perspectives of the development of coal-water composite fuel technologies in Russia and worldwide are presented. The advantages of the OCWF use as a power-plant fuel in comparison with the common coal-water fuels (CWF) were emphasized. The factors (component ratio, grinding degree of solid (coal) component, limiting temperature of oxidizer, properties of liquid and solid components, procedure and time of suspension preparation, etc.) affecting inertia and stability of the ignition processes of suspensions based on the products of coaland oil processing (coals of various types and metamorphism degree, filter cakes, waste motor, transformer, and turbine oils, water-oil emulsions, fuel-oil, etc.) were analyzed. The promising directions for the development of modern notions on the OCWF ignition processes were determined. The main reasons limiting active application of the OCWF in power generation were identified. Characteristics of ignition and combustion of coal-water and organic coal-water slurry fuels were compared. The effect of water in the composite coal fuels on the energy characteristics of their ignition and combustion, as well as ecological features of these processes, were elucidated. The current problems associated with pulverization of composite coal fuels in power plants, as well as the effect of characteristics of the pulverization process on the combustion parameters of fuel, were considered. The problems hindering the development of models of ignition and combustion of OCWF were analyzed. It was established that the main one was the lack of reliable experimental data on the processes of heating, evaporation, ignition, and combustion of OCWF droplets. It was concluded that the use of high-speed video recording systems and low-inertia sensors of temperature and gas

  6. Direct identification of hazardous elements in ultra-fine and nanominerals from coal fly ash produced during diesel co-firing.

    Science.gov (United States)

    Martinello, Kátia; Oliveira, Marcos L S; Molossi, Fernando A; Ramos, Claudete G; Teixeira, Elba C; Kautzmann, Rubens M; Silva, Luis F O

    2014-02-01

    This study has provided an initial assessment of the environmental impacts and potential health effects associated with coal fly ash produced during diesel co-firing. Many hazardous elements that are typically detected by multifaceted chemical characterization by XRD, petrology, FE-SEM/EDS, and HR-TEM/SEAD/FFT/EDS in ultra-fine compounds and nanominerals from the co-fired coal fly ashes (CFAs). It provided an in-depth understanding of coal ash produced during diesel co-firing. Several of the neoformed ultra-fine compounds and nano-minerals found in the coal ashes are the same as those commonly associated with oxidation/transformation of aluminosilicates, carbonates, sulphides and phosphates.

  7. Adverse effects of coal combustion related fine particulate matter (PM2.5) on nematode Caenorhabditis elegans.

    Science.gov (United States)

    Sun, Lingmei; Lin, Zhiqing; Liao, Kai; Xi, Zhuge; Wang, Dayong

    2015-04-15

    The toxic effects of coal combustion related fine particulate matter (PM2.5), collected from Datong, Shanxi province, China, on nematode Caenorhabditis elegans were investigated. Exposure to PM2.5 resulted in deficits in development, reproduction, locomotion behavior, and lifespan, and induction of intestinal autofluorescence or reactive oxygen species (ROS) production. Prolonged exposure to PM2.5 led to more severe toxicity on nematodes than acute exposure. In addition, exposure to PM2.5 induced altered expression patterns of genes required for the control of oxidative stress. Reduction in mean defecation cycle length and developmental deficits in AVL and DVB neurons, which are involved in the control of defecation behavior, were also triggered by PM2.5 exposure. Thus, oxidative stress and abnormal defecation behavior may contribute greatly to the toxicity of coal combustion related PM2.5 in nematodes. The results also imply that the long-term adverse effects of coal combustion related PM2.5 on environmental organisms should be carefully considered.

  8. Measurement and modeling of advanced coal conversion processes, Volume II

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [and others

    1993-06-01

    A two dimensional, steady-state model for describing a variety of reactive and nonreactive flows, including pulverized coal combustion and gasification, is presented. The model, referred to as 93-PCGC-2 is applicable to cylindrical, axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using a discrete ordinates method. The particle phase is modeled in a lagrangian framework, such that mean paths of particle groups are followed. A new coal-general devolatilization submodel (FG-DVC) with coal swelling and char reactivity submodels has been added.

  9. Advanced Thermally Stable Coal-Based Jet Fuels

    Science.gov (United States)

    2009-09-30

    hydrotreating to remove sulfur and then by hydrogenation for partial or complete ring saturation. Although this approach leads to a fuel of excellent quality...contributed by this coal were mainly two- and three-ring compounds. With hydrotreating to reduce sulfur and nitrogen and saturation of the aromatics...it could be a useful solvent for process configurations that couple coal conversion upstream with standard downstream hydrotreating , aromatics

  10. Combustion characterization of coal fines recovered from the handling plant. Quarterly technical progress report no. 3, April 1, 1995--June 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Houshang, M.; Samudrala, S.R.; Mohannad, O. [and others

    1995-07-01

    The main goal of this research project is to evaluate the combustion characteristics of the slurry fuels prepared from the recovered coal fines and plant coal fines. A specific study will include the combustion behavior, flame stability, ash behavior and emissions of SO{sub x}, NO{sub x} and particulate in a well insulated laboratory scale furnace in which the residence time and temperature history of the burning particles are similar to that of utility boiler furnace at 750,000 Btu/hr input and 20% excess air. The slurry fuel will be prepared at 60% solid to match the generic slurry properties, i.e., viscosity less than 500 cp, 100% of particles passing through 100 mesh and 80-90% of solid particles passing through 200 mesh. The coal blend is prepared using a mix of 15% effluent recovered coal and 85% plant fines. Combustion characteristics of the slurry fuels is determined at three different firing rates 750K, 625K, 500K Btu/hr. Finally a comparison of the results is made to determine the advantages of coal water slurry fuel over the plant coal blended form.

  11. Technology for advanced liquefaction processes: Coal/waste coprocessing studies

    Energy Technology Data Exchange (ETDEWEB)

    Cugini, A.V.; Rothenberger, K.S.; Ciocco, M.V. [Pittsburgh Energy Technology Center, PA (United States)] [and others

    1995-12-31

    The efforts in this project are directed toward three areas: (1) novel catalyst (supported and unsupported) research and development, (2) study and optimization of major operating parameters (specifically pressure), and (3) coal/waste coprocessing. The novel catalyst research and development activity has involved testing supported catalysts, dispersed catalysts, and use of catalyst testing units to investigate the effects of operating parameters (the second area) with both supported and unsupported catalysts. Several supported catalysts were tested in a simulated first stage coal liquefaction application at 404{degrees}C during this performance period. A Ni-Mo hydrous titanate catalyst on an Amocat support prepared by Sandia National laboratories was tested. Other baseline experiments using AO-60 and Amocat, both Ni-Mo/Al{sub 2}O{sub 3} supported catalysts, were also made. These experiments were short duration (approximately 12 days) and monitored the initial activity of the catalysts. The results of these tests indicate that the Sandia catalyst performed as well as the commercially prepared catalysts. Future tests are planned with other Sandia preparations. The dispersed catalysts tested include sulfated iron oxide, Bayferrox iron oxide (iron oxide from Miles, Inc.), and Bailey iron oxide (micronized iron oxide from Bailey, Inc.). The effects of space velocity, temperature, and solvent-to-coal ratio on coal liquefaction activity with the dispersed catalysts were investigated. A comparison of the coal liquefaction activity of these catalysts relative to iron catalysts tested earlier, including FeOOH-impregnated coal, was made. These studies are discussed.

  12. Biomedical implications of altered product composition in advanced coal liquefaction processes

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, B.W.; Mahlum, D.D.; Pelroy, R.A.

    1986-04-01

    Chemical and toxicologic characteristics of direct coal liquefaction materials are highly dependent upon the specific process operations by which the coal liquids were produced, including, in particular, those that affect boiling point range and degree of hydrogen incorporation. Recent advances in direct coal liquefaction technology, such as the use of catalytic hydrogenation, reduced liquefaction severity and lowering the upper temperature cut point for the distillation of fuels, have resulted in products with higher hydrogen-to-carbon ratios and lower heteroatom content. These higher-quality fuels tend to be less mutagenic and carcinogenic in laboratory assays than earlier coal liquefaction products. It is likely that application of postproduction hydrotreatment, as well as restriction of upper distillation temperature, for coal-based fuel products could result in materials that exhibit mutagenic or carcinogenic activity which is no greater than that of their petroleum-derived counterparts. 2 figs., 3 tabs., 46 refs.

  13. A fine coal circuitry study using column flotation and gravity separation. Quarterly report, 1 December 1994--28 February 1995

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q. [Southern Illinois Univ., Carbondale, IL (United States); Reed, S. [Kerr-McGee Coal Corp., Oklahoma City, OK (United States)

    1995-12-31

    Column flotation provides excellent recovery of ultrafine coal while producing low ash content concentrates. However, column flotation is not efficient for treating fine coal containing significant amounts of mixed-phase particles. Fortunately, enhanced gravity separation has proved to have the ability to treat the mixed-phased particles more effectively. A disadvantage of gravity separation is that ultrafine clay particles are not easily rejected. Thus, a combination of these two technologies may provide a circuit that maximizes both the ash and sulfur rejection that can be achieved by physical coal cleaning while maintaining a high energy recovery. This project is studying the potential of using different combinations of gravity separators, i.e., a Floatex hydrosizer and a Falcon Concentrator, and a proven flotation column, which will be selected based on previous studies by the principle investigator. During this reporting period, an in-plant Box-Behnken test program of the Floatex hydrosizer has been conducted at Kerr-McGee`s Galatia preparation plant. The results have shown that the Floatex hydrosizer can be successfully used to reject most of coarser ({plus}100 mesh) pyrite and mineral matter in the coal stream to the plant. With a single operation, ash rejection of 63% and total sulfur rejection of 43% have been achieved while maintaining a combustible recovery as high as 90.5%. A long term duration test under the optimum operating conditions determined from Box-Behnken test results has also been conducted. The feed samples for the following enhanced gravity - column flotation studies, which will be carried out in the next reporting period, have been collected.

  14. Recent advances in coal geologyoutcome of the 10th Coal Geology Conference

    Institute of Scientific and Technical Information of China (English)

    JiriPesek; StanislavOplustil

    2005-01-01

    The 10th Coal Geology Conference, jointly organized by the Faculty of Science of the Charles University in Prague, the Czech Geological Survey and the Institute of Geology of the Academy of Sciences of the Czech Republic, took place in June 7-11, 2004, at the Faculty of Science. The coal geology conferences have been held at the faculty every three or four years since 1972. They were preceded by coal geology seminars which began even earlier, in January 1968.These seminars and conferences provided an excellent opportunity to exchange knowledge and new information on coal geology and related fields and, above all, to bring together people from various fields starting with science and ending up with a wide spectrum of interests.

  15. High performance flocculating agents based on cationic polysaccharides in relation to coal fine suspension

    Energy Technology Data Exchange (ETDEWEB)

    Pal, S.; Sen, G.; Karmakar, N.C.; Mal, D.; Singh, R.P. [Birla Institute of Technology, Ranchi (India). Dept. of Applied Chemistry

    2008-11-04

    Five polysaccharides namely amylopectin, amylose, glycogen, guar gum and starch have been cationized by grafting with N-(3-chloro-2-hydroxypropyl) trimethyl ammonium chloride and studied for their flocculation behaviors. Of them, cationic glycogen (Cat Gly) is found to be the best for flocculation of coal suspended sample amongst cationic polysaccharides. Cat Gly was compared with some of the commercial flocculants.

  16. Measurement and modeling of advanced coal conversion processes, Volume III

    Energy Technology Data Exchange (ETDEWEB)

    Ghani, M.U.; Hobbs, M.L.; Hamblen, D.G. [and others

    1993-08-01

    A generalized one-dimensional, heterogeneous, steady-state, fixed-bed model for coal gasification and combustion is presented. The model, FBED-1, is a design and analysis tool that can be used to simulate a variety of gasification, devolatilization, and combustion processes. The model considers separate gas and solid temperatures, axially variable solid and gas flow rates, variable bed void fraction, coal drying, devolatilization based on chemical functional group composition, depolymerization, vaporization and crosslinking, oxidation, and gasification of char, and partial equilibrium in the gas phase.

  17. The theory and technology of enclosure dust-laying model in speeded advance of coal road

    Energy Technology Data Exchange (ETDEWEB)

    Wei-Min Cheng; Xiang-Sheng Liu; Guo-Qiang Ruan; Yun-Xiang Guo; Gang Wang [Shandong University of Science and Technology, Qingdao (China). Key Laboratory of Mine Disaster Prevention and Control

    2009-02-15

    In order to solve the problem of high dust concentration caused by the rapid advance of coal roadways using the ABM20 development machine, a method suitable for the rapid advance of coal roadways in China was proposed. By using the mathematic model method to contrast the wind current field and dust field of the drivage face under different drivage velocities, an optimized drivage velocity of the fully-mechanized development machine was obtained. The theories were tested in an industry experiment. Analysis of the data indicates that the proposed enclosure dust-laying system can significantly lower the dust concentration at the heading face. It also has some advantages in accomplishing the effective advance of coal mines. 9 refs., 5 figs.

  18. Technical, environmental, and economic assessment of deploying advanced coal power technologies in the Chinese context

    Energy Technology Data Exchange (ETDEWEB)

    Zhao Lifeng [Energy Technology Innovation Policy, Belfer Center for Science and International Affairs, John F. Kennedy School of Government, Harvard University, 79 John F. Kennedy Street, Cambridge, MA 02138 (United States); Key Laboratory of Advanced Energy and Power, Chinese Academy of Sciences, Institute of Engineering Thermophysics, 11 Beisihuan West Road, Beijing 100190 (China)], E-mail: lifeng_zhao@ksg.harvard.edu; Xiao Yunhan [Key Laboratory of Advanced Energy and Power, Chinese Academy of Sciences, Institute of Engineering Thermophysics, 11 Beisihuan West Road, Beijing 100190 (China); Gallagher, Kelly Sims [Energy Technology Innovation Policy, Belfer Center for Science and International Affairs, John F. Kennedy School of Government, Harvard University, 79 John F. Kennedy Street, Cambridge, MA 02138 (United States); Wang Bo; Xu Xiang [Key Laboratory of Advanced Energy and Power, Chinese Academy of Sciences, Institute of Engineering Thermophysics, 11 Beisihuan West Road, Beijing 100190 (China)

    2008-07-15

    The goal of this study is to evaluate the technical, environmental, and economic dimensions of deploying advanced coal-fired power technologies in China. In particular, we estimate the differences in capital cost and overall cost of electricity (COE) for a variety of advanced coal-power technologies based on the technological and economic levels in 2006 in China. This paper explores the economic gaps between Integrated Gasification Combined Cycle (IGCC) and other advanced coal power technologies, and compares 12 different power plant configurations using advanced coal power technologies. Super critical (SC) and ultra super critical (USC) pulverized coal (PC) power generation technologies coupled with pollution control technologies can meet the emission requirements. These technologies are highly efficient, technically mature, and cost-effective. From the point of view of efficiency, SC and USC units are good choices for power industry. The net plant efficiency for IGCC has reached 45%, and it has the best environmental performance overall. The cost of IGCC is much higher, however, than that of other power generation technologies, so the development of IGCC is slow throughout the world. Incentive policies are needed if IGCC is to be deployed in China.

  19. Improvement of storage, handling, and transportability of fine coal. Quarterly technical progress report No. 4, October 1, 1994--December 31, 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-08-20

    The objectives of this project are to demonstrate that: The Mulled Coal process, which has been proven to work on a wide range of wet fine coals at bench scale, will work equally well on a continuous basis, producing consistent quality at a convincing rate of production in a commercial coal preparation plant. The wet product from a fine coal cleaning circuit can be converted to a solid fuel form for ease of handling and cost savings in storage and rail car transportation. A wet fine coal product thus converted to a solid fuel form, can be stored, shipped, and burned with conventional fuel handling, transportation, and combustion systems. During this fourth quarter of the contract period, activities were underway under Tasks 2 and 3. Sufficient characterization of the bench-scale testing and pilot-plant testing results enabled the design and procurement activities to move forward. On that basis, activities in the areas of design and procurement that had been initiated during the previous quarter were conducted and completed.

  20. Advanced coal conversion process demonstration. Technical progress report, April 1--June 30, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-01

    This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high moisture, low rank coals to a high quality, low sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep bed stratifier cleaning process to separate the pyrite rich ash from the coal. The SynCoal process enhances low rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,500 to 9,000 Btu/lb, by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. The 45 ton per hour unit is located adjacent to a unit train load out facility at Western Energy Company`s Rosebud coal mine near Colstrip, Montana. The demonstration plant is sized at about one-tenth the projected throughput of a multiple processing train commercial facility. During this report period the primary focus has been to continue the operation of the demonstration facility. Production has been going to area power plants. Modifications and maintenance work was also performed this quarter.

  1. Overall requirements for an advanced underground coal extraction system

    Energy Technology Data Exchange (ETDEWEB)

    Goldsmith, M.; Lavin, M.L.

    1980-10-15

    This report presents overall requirements on underground mining systems suitable for coal seams exploitable in the year 2000, with particular relevance to the resources of Central Appalachia. These requirements may be summarized as follows: (1) Production Cost: demonstrate a return on incremental investment of 1.5 to 2.5 times the value required by a low-risk capital project. (2) Miner Safety: achieve at least a 50% reduction in deaths and disabling injuries per million man-hours. (3) Miner Health: meet the intent of all applicable regulations, with particular attention to coal dust, carcinogens, and mutagens; and with continued emphasis on acceptable levels of noise and vibration, lighting, humidity and temperature, and adequate work space. (4) Environmental Impact: maintain the value of mined and adjacent lands at the pre-mining value following reclamation; mitigation of off-site impacts should not cost more than the procedures used in contemporary mining. (5) Coal Conservation: the recovery of coal from the seam being mined should be at least as good as the best available contemporary technology operating in comparable conditions. No significant trade-offs between production cost and other performance indices were found.

  2. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    Energy Technology Data Exchange (ETDEWEB)

    Kevin Crist

    2004-04-02

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc. (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal-fired power plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic

  3. Evaluation of the Emission, Transport, and Deposition of Mercury and Fine Particulate Matter from Coal-Based Power Plants in the Ohio River Valley Region

    Energy Technology Data Exchange (ETDEWEB)

    Kevin Crist

    2008-12-31

    As stated in the proposal: Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, evaluated the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury and associated fine particulate matter. This evaluation involved two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring included the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station contains sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO2, O3, etc.). Laboratory analyses of time-integrated samples were used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Nearreal- time measurements were used to measure the ambient concentrations of PM mass and all gaseous species including Hg0 and RGM. Approximately 30 months of field data were collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data provides mercury, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis includes (1) development of updated inventories of mercury emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg0, RGM, and fine particulate matter in the different sectors of the study region to identify key transport

  4. Advanced char burnout models for the simulation of pulverized coal fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    T. Severin; S. Wirtz; V. Scherer [Ruhr-University, Bochum (Germany). Institute of Energy Plant Technology (LEAT)

    2005-07-01

    The numerical simulation of coal combustion processes is widely used as an efficient means to predict burner or system behaviour. In this paper an approach to improve CFD simulations of pulverized coal fired boilers with advanced coal combustion models is presented. In simple coal combustion models, first order Arrhenius rate equations are used for devolatilization and char burnout. The accuracy of such simple models is sufficient for the basic aspects of heat release. The prediction of carbon-in-ash is one aspect of special interest in the simulation of pulverized coal fired boilers. To determine the carbon-in-ash levels in the fly ash of coal fired furnaces, the char burnout model has to be more detailed. It was tested, in how far changing operating conditions affect the carbon-in-ash prediction of the simulation. To run several test cases in a short time, a simplified cellnet model was applied. To use a cellnet model for simulations of pulverized coal fired boilers, it was coupled with a Lagrangian particle model, used in CFD simulations, too. 18 refs., 5 figs., 5 tabs.

  5. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1990--June 1991

    Energy Technology Data Exchange (ETDEWEB)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  6. Cancer risk from polycyclic aromatic compounds in fine particulate matter generated from household coal combustion in Xuanwei, China.

    Science.gov (United States)

    Lui, K H; Bandowe, Benjamin A Musa; Tian, Linwei; Chan, Chi-Sing; Cao, Jun-Ji; Ning, Zhi; Lee, S C; Ho, K F

    2017-02-01

    Polycyclic aromatic hydrocarbons (PAHs) and their polar derivatives (oxygenated PAHs: OPAHs and azaarenes: AZAs) were characterized in fine particulates (PM2.5) emitted from indoor coal combustion. Samples were collected in Xuanwei (Yunnan Province), a region in China with a high rate of lung cancer. A sample from the community with the highest mortality contained the highest total concentration of PAHs, OPAHs and AZAs and posed the highest excess cancer risk from a lifetime of inhaling fine particulates. Positive correlations between total carbonyl-OPAHs, total AZAs and total PAHs implied that the emissions were dependent on similar factors, regardless of sample location and type. The calculated cancer risk ranged from 5.23-10.7 × 10(-3), which is higher than the national average. The risk in each sample was ∼1-2 orders of magnitude higher than that deemed high risk, suggesting that the safety of these households is in jeopardy. The lack of potency equivalency factors for the PAH derivatives could possibly have underestimated the overall cancer risk.

  7. Mechanical Properties of High Strength Concrete Containing Coal Bottom Ash and Oil-Palm Boiler Clinker as Fine Aggregates

    Directory of Open Access Journals (Sweden)

    Soofinajafi Mahmood

    2016-01-01

    Full Text Available This research aims to utilize Coal Furnace Bottom ash (CBA and Oil-Palm Boiler Clinker (OPBC as fine aggregate in concrete mix proportions. They are solid wastes from power plant and Oil Palm industry, respectively. Since these by-products do not have any primary use and are pure waste, an opportunity to use them as aggregate in concrete industry not only is economical but also will be an environmental friendly opportunity leading towards a more sustainable production chain. CBA and OPBC sands had similar grading to normal sand but have lower density and higher water absorption. In a high strength concrete, normal sand was replaced up to 25% with either CBA or OPBC. Test results showed that although water absorption of these wastes was more than normal sand but the slump value of concrete containing each of these wastes showed that these concretes had good workability. All mixes containing these wastes had slightly lower compressive strength at early ages and equivalent or higher compressive strength at later ages compared to control mix. The 28-day compressive strength of these concretes was in the range of 69–76 MPa which can be categorized as high strength concrete. In general, the performance of OPBC was better than CBA at 25% replacement level. However, it is recommended that at least 12.5% of total volume of fine aggregate in a high strength concrete is used of CBA or OPBC.

  8. Advanced coal conversion process demonstration. Technical progress report for the period July 1, 1995--September 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from July 1, 1995 through September 30, 1995. The ACCP Demonstration Project is a US Department of Energy (DOE) Clean Coal Technology Project. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the cola is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

  9. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research

    Energy Technology Data Exchange (ETDEWEB)

    Speight, J.G.

    1992-01-01

    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.

  10. Formation of CoAl2O4 Nanoparticles via Low-Temperature Solid-State Reaction of Fine Gibbsite and Cobalt Precursor

    OpenAIRE

    Natpakan Srisawad; Wasu Chaitree; Okorn Mekasuwandumrong; Piyasan Praserthdam; Joongjai Panpranot

    2012-01-01

    Nanocrystalline cobalt aluminate (CoAl2O4) was synthesized by the solid-state reaction method with cobalt chloride hexahydrate (CoCl2 · 6H2O) as the source of Co and gibbsite (Al(OH)3) as the source of Al, respectively. The effects of particle size of the starting fine gibbsite (0.6 and 13 μm) and calcination temperatures (450, 550, and 650°C) on the properties of CoAl2O4 were investigated by means of X-ray diffraction (XRD), thermogravimetry analysis and differential thermal analysis (TG/DT...

  11. Advanced CFB for clean and efficient coal power

    Energy Technology Data Exchange (ETDEWEB)

    H. Nevalainen; J. Saastamoinen; M. Jegoroff (and others) [VTT, Jyvaskyla (Finland)

    2009-07-01

    The European Union's Clefco project (2004-06) aimed to promote the development of once through steam cycle (OTSC) CFB technology. This was carried out by increasing the process knowledge that is essential for successful boiler design and demonstration of the multi-fuel flexibility of the process. To fulfil the development needs of OTSC CFB technology, a comprehensive understanding of CFB combustion processes needed to be achieved. Intensive research in laboratory, pilot and full-scale combustors was required to fulfil the abovementioned objectives. In the project, each partner worked in its own field of research. Cooperation between partners enabled the best-possible understanding of the process. In order to study different process characteristics and verify measurements and simulations, experiments were carried out with different size reactors - VTT's laboratory scale CFB reactor, VTT's 50 kW pilot CFB reactor, Chalmers' 12 MW CFB boiler, cold rig and several commercial boilers. To find out possibilities for end-use of ash, national legislations and standards were studied. Knowledge was applied to ash management possibilities for coal combustion and co-combustion of coal and biomass. The studies were based on the ash characterisation, which was carried out for ash samples collected during the projects' combustion tests. 52 refs., 122 figs., 42 tabs.

  12. Computer simulation of an advanced combustor for clean coal technology

    Energy Technology Data Exchange (ETDEWEB)

    Chang, S.L.; Lottes, S.A.

    1992-01-01

    Magnetohydrodynamic (MHD) power generation is a clean coal technology because of its higher thermal efficiency and lower pollutant emission. Argonne National Laboratory used a comprehensive integral combustion computer code to aid the development of a TRW's second stage combustor for MHD power generation. The integral combustion code is a computer code for two-phase, two-dimensional, steady state, turbulent, and reacting flows, based on mass, momentum, and energy conservation laws for multiple gas species and solid particles of variable sizes. In the MHD second stage combustor, opposed jets of oxidizer are injected into a confined cross-stream coal gas flow laden with seed particles. The performance of the downstream MHD power generation channel depends mainly on the degree and the uniformity of gas ionization, which, in turn, depends on the uniformity of temperature and seed vapor distributions leaving the combustor. The simulation provides in-depth information of flow, combustion, and heat transfer patterns in the combustor, which is used to predict ranges of combustor operating conditions for optimum performance of the MHD system.

  13. Computer simulation of an advanced combustor for clean coal technology

    Energy Technology Data Exchange (ETDEWEB)

    Chang, S.L.; Lottes, S.A.

    1992-09-01

    Magnetohydrodynamic (MHD) power generation is a clean coal technology because of its higher thermal efficiency and lower pollutant emission. Argonne National Laboratory used a comprehensive integral combustion computer code to aid the development of a TRW`s second stage combustor for MHD power generation. The integral combustion code is a computer code for two-phase, two-dimensional, steady state, turbulent, and reacting flows, based on mass, momentum, and energy conservation laws for multiple gas species and solid particles of variable sizes. In the MHD second stage combustor, opposed jets of oxidizer are injected into a confined cross-stream coal gas flow laden with seed particles. The performance of the downstream MHD power generation channel depends mainly on the degree and the uniformity of gas ionization, which, in turn, depends on the uniformity of temperature and seed vapor distributions leaving the combustor. The simulation provides in-depth information of flow, combustion, and heat transfer patterns in the combustor, which is used to predict ranges of combustor operating conditions for optimum performance of the MHD system.

  14. Advances in the development of wire mesh reactor for coal gasification studies.

    Science.gov (United States)

    Zeng, Cai; Chen, Lei; Liu, Gang; Li, Wenhua; Huang, Baoming; Zhu, Hongdong; Zhang, Bing; Zamansky, Vladimir

    2008-08-01

    In an effort to further understand the coal gasification behavior in entrained-flow gasifiers, a high pressure and high temperature wire mesh reactor with new features was recently built. An advanced LABVIEW-based temperature measurement and control system were adapted. Molybdenum wire mesh with aperture smaller than 70 mum and type D thermocouple were used to enable high carbon conversion (>90%) at temperatures >1000 degrees C. Gaseous species from wire mesh reactor were quantified using a high sensitivity gas chromatography. The material balance of coal pyrolysis in wire mesh reactor was demonstrated for the first time by improving the volatile's quantification techniques.

  15. An analysis of cost effective incentives for initial commercial deployment of advanced clean coal technologies

    Energy Technology Data Exchange (ETDEWEB)

    Spencer, D.F. [SIMTECHE, Half Moon Bay, CA (United States)

    1997-12-31

    This analysis evaluates the incentives necessary to introduce commercial scale Advanced Clean Coal Technologies, specifically Integrated Coal Gasification Combined Cycle (ICGCC) and Pressurized Fluidized Bed Combustion (PFBC) powerplants. The incentives required to support the initial introduction of these systems are based on competitive busbar electricity costs with natural gas fired combined cycle powerplants, in baseload service. A federal government price guarantee program for up to 10 Advanced Clean Coal Technology powerplants, 5 each ICGCC and PFBC systems is recommended in order to establish the commercial viability of these systems by 2010. By utilizing a decreasing incentives approach as the technologies mature (plants 1--5 of each type), and considering the additional federal government benefits of these plants versus natural gas fired combined cycle powerplants, federal government net financial exposure is minimized. Annual net incentive outlays of approximately 150 million annually over a 20 year period could be necessary. Based on increased demand for Advanced Clean Coal Technologies beyond 2010, the federal government would be revenue neutral within 10 years of the incentives program completion.

  16. Design manual for management of solid by-products from advanced coal technologies

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-10-01

    Developing coal conversion technologies face major obstacles in byproduct management. This project has developed several management strategies based on field trials of small-scale landfills in an earlier phase of the project, as well as on published/unpublished sources detailing regulatory issues, current industry practice, and reuse opportunities. Field testing, which forms the basis for several of the disposal alternatives presented in this design manual, was limited to byproducts from Ca-based dry SO{sub 2} control technologies, circulating fluidized bed combustion ash, and bubbling bed fluidized bed combustion ash. Data on byproducts from other advanced coal technologies and on reuse opportunities are drawn from other sources (citations following Chapter 3). Field results from the 5 test cases examined under this project, together with results from other ongoing research, provide a basis for predictive modeling of long-term performance of some advanced coal byproducts on exposure to ambient environment. This manual is intended to provide a reference database and development plan for designing, permitting, and operating facilities where advanced coal technology byproducts are managed.

  17. TRW Advanced Slagging Coal Combustor Utility Demonstration. Fourth Quarterly progress report, August 1989--October 1989

    Energy Technology Data Exchange (ETDEWEB)

    1989-12-31

    The TRW Advanced Slagging Coal Combustor Demonstration Project consists of retrofitting Orange and Rockland (O&R) Utility Corporation`s Lovett Plant Unit No. 3 with four (4) slagging combustors which will allow the gas/ou desip unit to fire 2.5 sulfur coal. The slogging combustor process will provide NO{sub x} and SO{sub x} emissions that meet NSPS and New York State Envirommental Standards. TRW-CBU scope of work includes the engineering, design and supply of the slogging combustors, coal and limestone feed systems and a control system for these components. During this report period, the design activities for all systems progressed to permit the release of specifications and requests for proposals. Award of contracts for long-delivery items and major equipment are being placed to meet the revised program schedule.

  18. Compression properties of dust cake of fine fly ashes from a fluidized bed coal combustor on a ceramic filter

    Energy Technology Data Exchange (ETDEWEB)

    Choi, J.H.; Ha, S.J.; Jang, H.J. [Gyeongsang National University, Jinju (Republic of Korea). Dept. of Chemical Engineering & ERI

    2004-02-16

    Dust cake compressibility of fine fly ashes (from a coal power plant of fluidized bed combustor) on a ceramic filter was carefully investigated under well-controlled conditions and by measuring the cake thickness under filtration conditions using a laser displacement measuring system. Overall cake porosity and pressure drop of dust cake of three different particles of geometric mean diameters: 1.2, 2.2, and 3.6 {mu}m and the adjusted dynamic shape factors: 1.15, 1.28 and 1.64, respectively, were investigated, at face velocities of 0.02-0.08 m/s. Overall cake porosity was strongly dependent on face velocity and mass load but less dependent on particle sizes. It was understood that dust cake was compressed by reduction of previously formed cake layers with drag forces of lately formed dust layers. The expressions for overall cake porosity and pressure drop across the dust cake, and considering the compression effect, were developed with good agreement with experimental results.

  19. Effect of selective catalytic reduction (SCR) on fine particle emission from two coal-fired power plants in China

    Science.gov (United States)

    Li, Zhen; Jiang, Jingkun; Ma, Zizhen; Wang, Shuxiao; Duan, Lei

    2015-11-01

    Nitrogen oxides (NOx) emission abatement of coal-fired power plants (CFPPs) requires large-scaled installation of selective catalytic reduction (SCR), which would reduce secondary fine particulate matter (PM2.5) (by reducing nitrate aerosol) in the atmosphere. However, our field measurement of two CFPPs equipped with SCR indicates a significant increase of SO42- and NH4+ emission in primary PM2.5, due to catalytic enhancement of SO2 oxidation to SO3 and introducing of NH3 as reducing agent. The subsequent formation of (NH4)2SO4 or NH4HSO4 aerosol is commonly concentrated in sub-micrometer particulate matter (PM1) with a bimodal pattern. The measurement at the inlet of stack also showed doubled primary PM2.5 emission by SCR operation. This effect should therefore be considered when updating emission inventory of CFPPs. By rough estimation, the enhanced primary PM2.5 emission from CFPPs by SCR operation would offset 12% of the ambient PM2.5 concentration reduction in cities as the benefit of national NOx emission abatement, which should draw attention of policy-makers for air pollution control.

  20. The advanced super critical 700{sup o}C pulverized coal-fired power plant

    Energy Technology Data Exchange (ETDEWEB)

    Kjaer, S.; Klauke, F.; Vanstone, R.; Zeijseink, A.; Weissinger, G.; Kristensen, P.; Meier, J.; Blum, R.; Wieghardt, K. [Tech-Wise A/S, Fredericia (Denmark)

    2001-07-01

    This paper presents the efforts of a large European group of manufacturers, utilities and institutes co-operating in a phased long-term project named 'Advanced 700{sup o}C PF Power Plant'. The first phase started in 1998 based on a grant from the Commission's Thermie programme under the 4th Framework programme. The overall objective of the project is to ensure a role for coal in Europe also in future. The project's targets renewedpublic and political acceptance of coal by improving efficiency and economy of well-proven, super critical pulverised coal-fired technology. Net efficiencies of more than 50% will be reached through development of a super critical steam cycle operating at maximum steam temperatures in the range of 700{sup o}C. Principal efforts are based on development of creep resistant - and expensive - nickel-based materials named super-alloys for the hottest areas of the water/steam cycle. Three benchmarks for theinvestigations have been set up: (i) the net efficiency of the demonstration plant from the present state of the art performance of 44% will be boosted into the range of 50-51% for a plant located inland with a cooling tower and 53-54% for the best seawater-cooled versions. (ii) reductions of investment cost of PF power plant by revising the overall architecture of the plant. (iii) Co-firing of up to 20% biomass with coal. The Advanced 700{sup o}C PF power plant project (or AD700) will improve the competitiveness of coal-fired power generation and give a major reduction of CO{sub 2} from coal-fired power plants in the range of 15% from the best PF power plants presently and up to 40% from older plants. 11 figs., 2 tabs.

  1. Advanced coal-fueled gas turbine systems: Subscale combustion testing. Topical report, Task 3.1

    Energy Technology Data Exchange (ETDEWEB)

    1993-05-01

    This is the final report on the Subscale Combustor Testing performed at Textron Defense Systems` (TDS) Haverhill Combustion Laboratories for the Advanced Coal-Fueled Gas Turbine System Program of the Westinghouse Electric Corp. This program was initiated by the Department of Energy in 1986 as an R&D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular staged, rich-lean-quench, Toroidal Vortex Slogging Combustor (TVC) concept. Fuel-rich conditions in the first stage inhibit NO{sub x} formation from fuel-bound nitrogen; molten coal ash and sulfated sorbent are removed, tapped and quenched from the combustion gases by inertial separation in the second stage. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The primary objective of this work was to verify the feasibility of a direct coal-fueled combustion system for combustion turbine applications. This has been accomplished by the design, fabrication, testing and operation of a subscale development-type coal-fired combustor. Because this was a complete departure from present-day turbine combustors and fuels, it was considered necessary to make a thorough evaluation of this design, and its operation in subscale, before applying it in commercial combustion turbine power systems.

  2. Formation of CoAl2O4 Nanoparticles via Low-Temperature Solid-State Reaction of Fine Gibbsite and Cobalt Precursor

    Directory of Open Access Journals (Sweden)

    Natpakan Srisawad

    2012-01-01

    Full Text Available Nanocrystalline cobalt aluminate (CoAl2O4 was synthesized by the solid-state reaction method with cobalt chloride hexahydrate (CoCl2 · 6H2O as the source of Co and gibbsite (Al(OH3 as the source of Al, respectively. The effects of particle size of the starting fine gibbsite (0.6 and 13 μm and calcination temperatures (450, 550, and 650°C on the properties of CoAl2O4 were investigated by means of X-ray diffraction (XRD, thermogravimetry analysis and differential thermal analysis (TG/DTA, X-ray photoelectron spectroscopy (XPS, UV-visible absorption spectroscopy (UV-Vis, scanning electron microscopy (SEM, and transmission electron microscopy (TEM. Increasing of calcination temperature promoted the insertion amounts of Co2+ in alumina matrix in CoAl2O4 structure, which resulted in the brighter blue particles and increasing of UV spectra band. The lowest temperature for the formation of nanocrystalline CoAl2O4 particles was 550°C for the solid-state reaction of cobalt chloride and 0.6 μm fine gibbsite.

  3. Pure Air`s advanced flue gas desulfurization clean coal project

    Energy Technology Data Exchange (ETDEWEB)

    Brown, J.R. [Pure Air Bailly Station, Chesterton, IN (United States)

    1998-12-31

    Pure Air`s Advanced Flue Gas Desulfurization (AFGD) Clean Coal Project successfully completed four and a half years of operation in December 1996 at Northern Indiana Public Service Company`s (NIPSCO) Bailly Generating Station. This project received a $60 million grant from the DOE Clean Coal II program. Included in this was a three year DOE demonstration period. The facility was designed, built and is owned and operated by Pure Air of Allentown, Pennsylvania, through its project company, Pure Air on the Lake, Limited Partnership. The project met or exceeded all performance criteria. It has averaged 95.3% SO{sub 2} removal, 99.9% availability and produced high quality commercial gypsum during this four and a half year period. It demonstrated many advanced technology features including a single, large absorber module serving two boilers, a wastewater evaporation system, an air rotary sparger for oxidation, and a new technology for agglomerating gypsum.

  4. Carbon formation and metal dusting in advanced coal gasification processes

    Energy Technology Data Exchange (ETDEWEB)

    DeVan, J.H.; Tortorelli, P.F.; Judkins, R.R.; Wright, I.G.

    1997-02-01

    The product gases generated by coal gasification systems contain high concentrations of CO and, characteristically, have relatively high carbon activities. Accordingly, carbon deposition and metal dusting can potentially degrade the operation of such gasifier systems. Therefore, the product gas compositions of eight representative gasifier systems were examined with respect to the carbon activity of the gases at temperatures ranging from 480 to 1,090 C. Phase stability calculations indicated that Fe{sub 3}C is stable only under very limited thermodynamic conditions and with certain kinetic assumptions and that FeO and Fe{sub 0.877}S tend to form instead of the carbide. As formation of Fe{sub 3}C is a necessary step in the metal dusting of steels, there are numerous gasifier environments where this type of carbon-related degradation will not occur, particularly under conditions associated with higher oxygen and sulfur activities. These calculations also indicated that the removal of H{sub 2}S by a hot-gas cleanup system may have less effect on the formation of Fe{sub 3}C in air-blown gasifier environments, where the iron oxide phase can exist and is unaffected by the removal of sulfur, than in oxygen-blown systems, where iron sulfide provides the only potential barrier to Fe{sub 3}C formation. Use of carbon- and/or low-alloy steels dictates that the process gas composition be such that Fe{sub 3}C cannot form if the potential for metal dusting is to be eliminated. Alternatively, process modifications could include the reintroduction of hydrogen sulfide, cooling the gas to perhaps as low as 400 C and/or steam injection. If higher-alloy steels are used, a hydrogen sulfide-free gas may be processed without concern about carbon deposition and metal dusting.

  5. Trace component analysis of process hydrogen streams at the Wilsonville Advanced Coal Liquefaction Facility

    Energy Technology Data Exchange (ETDEWEB)

    Bronfenbrenner, J.C.

    1983-09-01

    This report summarizes subcontracted work done by the Radian Corporation to analyze trace components in process hydrogen streams at the Advanced Coal Liquefaction Facility in Wilsonville, Alabama. The data will be used to help define whether the gas streams to be treated in the hydrogen processing unit in the SRC-I Demonstration Plant will require further treatment to remove trace contaminants that could be explosive under certain conditions. 2 references.

  6. Fine mapping and replication of QTL in outbred chicken advanced intercross lines

    Directory of Open Access Journals (Sweden)

    Andersson Leif

    2011-01-01

    Full Text Available Abstract Background Linkage mapping is used to identify genomic regions affecting the expression of complex traits. However, when experimental crosses such as F2 populations or backcrosses are used to map regions containing a Quantitative Trait Locus (QTL, the size of the regions identified remains quite large, i.e. 10 or more Mb. Thus, other experimental strategies are needed to refine the QTL locations. Advanced Intercross Lines (AIL are produced by repeated intercrossing of F2 animals and successive generations, which decrease linkage disequilibrium in a controlled manner. Although this approach is seen as promising, both to replicate QTL analyses and fine-map QTL, only a few AIL datasets, all originating from inbred founders, have been reported in the literature. Methods We have produced a nine-generation AIL pedigree (n = 1529 from two outbred chicken lines divergently selected for body weight at eight weeks of age. All animals were weighed at eight weeks of age and genotyped for SNP located in nine genomic regions where significant or suggestive QTL had previously been detected in the F2 population. In parallel, we have developed a novel strategy to analyse the data that uses both genotype and pedigree information of all AIL individuals to replicate the detection of and fine-map QTL affecting juvenile body weight. Results Five of the nine QTL detected with the original F2 population were confirmed and fine-mapped with the AIL, while for the remaining four, only suggestive evidence of their existence was obtained. All original QTL were confirmed as a single locus, except for one, which split into two linked QTL. Conclusions Our results indicate that many of the QTL, which are genome-wide significant or suggestive in the analyses of large intercross populations, are true effects that can be replicated and fine-mapped using AIL. Key factors for success are the use of large populations and powerful statistical tools. Moreover, we believe that

  7. (Pittsburgh Energy Technology Center): Quarterly technical progress report for the period ending June 30, 1987. [Advanced Coal Research and Technology Development Programs

    Energy Technology Data Exchange (ETDEWEB)

    None

    1988-02-01

    Research programs on coal and coal liquefaction are presented. Topics discussed are: coal science, combustion, kinetics, surface science; advanced technology projects in liquefaction; two stage liquefaction and direct liquefaction; catalysts of liquefaction; Fischer-Tropsch synthesis and thermodynamics; alternative fuels utilization; coal preparation; biodegradation; advanced combustion technology; flue gas cleanup; environmental coordination, and technology transfer. Individual projects are processed separately for the data base. (CBS)

  8. Hydrocarbon-oil encapsulated bubble flotation of fine coal using 3-in. ID flotation column. Technical progress report for the eleventh quarter, April 1--June 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Peng, F.F.

    1996-05-01

    There are four modes of the collector dispersion techniques. They are (1) direct liquid additions and stirring, (2) ultrasonic energy collector dispersion, (3) atomized collector dispersion, and (4) gasified collector transported in air stream. Among those collector dispersion techniques, the technique using the gasified collector transported in air phase can be used to enhance the flotation performance with substantial reduction in collector usage and selectivity, compared to the flotation using direct liquid addition (and mechanical agitation) technique. In this phase of study, two modes of collector addition techniques including gasified collector transported in gas phase and direct collector addition techniques were applied in the column flotation to demonstrate the selectivity of utilizing the hydrocarbon-oil encapsulated air bubbles in the fine coal flotation process. The 1-in. ID flotation column was used to scale-up to 3-in. ID flotation column. The initial starting point to operate the 3-in ID flotation column were determined using both 1-in. and 3-in. flotation columns based on the three phases of work plans and experiment design. A 3-in. flotation column was used to evaluate two modes of collector dispersion and addition techniques on the recovery and grade of fine coals using various ranks of coal.

  9. Variations in coal maceral chemistry with rank advance in the German Creek and Moranbah Coal Measures of the Bowen Basin, Australia, using electron microprobe techniques

    Energy Technology Data Exchange (ETDEWEB)

    Ward, Colin R.; Li, Zhongsheng; Gurba, Lila W. [School of Biological, Earth and Environmental Sciences, University of New South Wales, Sydney, 2052 (Australia)

    2005-07-20

    Variations in the elemental composition of individual macerals in seams from the Permian German Creek and Moranbah Coal Measures in the Bowen Basin of Queensland have been studied over a wide range of coal ranks, using light-element electron microprobe techniques, to establish the coalification tracks of key macerals in a single coal-bearing interval from subbituminous through bituminous coal to anthracite. Vitrinite reflectance (Rv{sub max}) in the seams studied increases from 0.39% in the western part of the basin to over 3.5% in the east, apparently due to increases in burial depth. The study extends significantly the rank range covered by previous work on elemental analysis of individual macerals in the Gunnedah Basin, and provides a more useful basis than whole-coal analysis to evaluate the performance of coals in different utilisation processes. The microprobe results show that the carbon content of the telocollinite increases dramatically from 66% to 90% as the vitrinite reflectance of the coals (Rv{sub max}) increases from 0.39% to around 1.75%, but increases only slightly, from 90% to 91%, as Rv{sub max} increases from 1.75% to 3.52%. Oxygen decreases from around 26% to approximately 5% as Rv{sub max} increases from 0.39% to around 1.75%, and then decreases only very slightly into the anthracite range. The nitrogen content of the telocollinite in these coals also appears to decrease slightly with rank advance, and appears moreover to display a relatively abrupt drop at around 2% Rv{sub max}. This may be associated with the development of ammonium illite in the mineral matter. Organic sulphur in the telocollinite, on the other hand, seems to remain essentially constant with rank advance, at least in this particular succession. In contrast to vitrinite, fusinite and inertodetrinite have significantly higher but somewhat more constant carbon contents, varying only from around 81% to 93% C over the rank range studied. Oxygen in these macerals decreases from

  10. Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K. [eds.

    1994-06-01

    The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume I contains papers presented at the following sessions: opening commentaries; changes in the market and technology drivers; advanced IGCC systems; advanced PFBC systems; advanced filter systems; desulfurization system; turbine systems; and poster session. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  11. Computer Simulation Techniques for Molecular Structure of Coal for Advanced Coal Conversion Technology; Sekitan kodo henkan no tameno bunshikozo shimyureshon

    Energy Technology Data Exchange (ETDEWEB)

    Takanohashi, Toshimasa [Energy Resources Dept., Tokyo (Japan). Fundamental Research Div.; Nakamura, Kazuo [Osaka Gas Corp., Osaka (Japan). Fundamental Research Laboratories; Iino, Masashi [Tohoku University, Miyagi (Japan), Institute for Chemical Reaction Science

    1999-02-25

    Coal has complex chemical structure consisting of various bond types and the details are still not well understood. Recently, in addition to improvements of analytical techniques, molecular modeling and simulation techniques by using powerful computers and software have greatly developed and it has become possible to apply them to complex structure such as coal. Knowledge of coal's molecular structure is important for the understanding of various coal properties and reactivities under several conditions. In this paper, a new tool, i.e., molecular modeling technique of coal's macromolecular structure and dynamic simulation of coal properties, is introduced and the future applications of this technique will be outlined. (author)

  12. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-06-01

    This sixteenth quarterly report describes work done during the sixteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, giving a presentation, and making and responding to several outside contacts.

  13. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-05-10

    This fourteenth quarterly report describes work done during the fourteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing presentations, and making and responding to two outside contacts.

  14. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-05-11

    This fifteenth quarterly report describes work done during the fifteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing and giving presentations, and making and responding to several outside contacts.

  15. Treatment of metal-laden hazardous wastes with advanced Clean Coal Technology by-products

    Energy Technology Data Exchange (ETDEWEB)

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini; Wiles Elder

    1999-04-05

    This eleventh quarterly report describes work done during the eleventh three-month period of the University of Pittsburgh's project on the ``Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing and giving presentations, and making and responding to two outside contacts.

  16. Monolithic solid oxide fuel cell technology advancement for coal-based power generation

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-14

    The program is conducted by a team consisting of AiResearch Los Angeles Division of Allied-Signal Aerospace Company and Argonne National Laboratory (ANL). The objective of the program is to advance materials and fabrication methodologies to develop a monolithic solid oxide fuel cell (MSOFC) system capable of meeting performance, life, and cost goals for coal-based power generation. The program focuses on materials research and development, fabrication process development, cell/stack performance testing and characterization, cost and system analysis, and quality development.

  17. Measurement and modeling of advanced coal conversion processes, Volume I, Part 1. Final report, September 1986--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [and others

    1995-09-01

    The objective of this program was the development of a predictive capability for the design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. The foundation to describe coal specific conversion behavior was AFR`s Functional Group and Devolatilization, Vaporization and Crosslinking (DVC) models, which had been previously developed. The combined FG-DVC model was integrated with BYU`s comprehensive two-dimensional reactor model for combustion and coal gasification, PCGC-2, and a one-dimensional model for fixed-bed gasifiers, FBED-1. Progress utilizing these models is described.

  18. Dynamics of heterogeneous separation on fine clean coal dewatering by filter press%浮选细精煤压滤脱水非均相分离动力学特性

    Institute of Scientific and Technical Information of China (English)

    巩冠群; 谢广元; 张英杰; 沙杰; 刘均章; 张秀峰; 陈宣辰; 董玉蛟

    2011-01-01

    Based on the dewatering theory and analysis of heterogeneous separation of fine clean coal dewatering, the heterogeneous separation process on fine clean coal dewatering of Yongcheng anthracite was investigated. A theoretical model on fine coal dewatering and its heterogeneous separation dynamic equations were proposed. The results show that the pressure filtration of flotation fine clean coal has the characteristic of heterogeneous separation of fluid dynamics. Fine coal dewatering rate is the function of driving force of operation, filter media,filter cake properties, coal slurry property and effective area coefficient of compaction. Pressure filtration process is comprised of filtration and pressure dewatering. The dewatering dynamic equation of flotation fine clean coal of Yongcheng anthracite was proposed. The compressibility index of cake s is 0. 855 9, the material properties constant k is 0. 237 1.%基于脱水理论及非均相分离特点分析,研究了永城无烟煤浮选细精煤脱水非均相分离过程,提出了细精煤脱水理论模型和动力学简化方程.结果表明:浮选细精煤压滤脱水具备非均相分离流体动力学作用特点,脱水速度是操作推动力、过滤介质、滤饼特性、煤浆属性及有效压密面积系数的函数,压滤过程分为过滤及压榨脱水,给出了永城无烟煤浮选细精煤过滤方程,滤饼压缩性指数s值为0.855 9,物料特性常数k为0.237 1.

  19. Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

    Energy Technology Data Exchange (ETDEWEB)

    Rader, Jeff; Aguilar, Kelly; Aldred, Derek; Chadwick, Ronald; Conchieri, John; Dara, Satyadileep; Henson, Victor; Leininger, Tom; Liber, Pawel; Liber, Pawel; Lopez-Nakazono, Benito; Pan, Edward; Ramirez, Jennifer; Stevenson, John; Venkatraman, Vignesh

    2012-03-30

    The purpose of this project was to evaluate the ability of advanced low rank coal gasification technology to cause a significant reduction in the COE for IGCC power plants with 90% carbon capture and sequestration compared with the COE for similarly configured IGCC plants using conventional low rank coal gasification technology. GE’s advanced low rank coal gasification technology uses the Posimetric Feed System, a new dry coal feed system based on GE’s proprietary Posimetric Feeder. In order to demonstrate the performance and economic benefits of the Posimetric Feeder in lowering the cost of low rank coal-fired IGCC power with carbon capture, two case studies were completed. In the Base Case, the gasifier was fed a dilute slurry of Montana Rosebud PRB coal using GE’s conventional slurry feed system. In the Advanced Technology Case, the slurry feed system was replaced with the Posimetric Feed system. The process configurations of both cases were kept the same, to the extent possible, in order to highlight the benefit of substituting the Posimetric Feed System for the slurry feed system.

  20. The demonstration of an advanced cyclone coal combustor, with internal sulfur, nitrogen, and ash control for the conversion of a 23 MMBTU/hour oil fired boiler to pulverized coal

    Energy Technology Data Exchange (ETDEWEB)

    Zauderer, B.; Fleming, E.S.

    1991-08-30

    This work contains to the final report of the demonstration of an advanced cyclone coal combustor. Titles include: Chronological Description of the Clean Coal Project Tests,'' Statistical Analysis of Operating Data for the Coal Tech Combustor,'' Photographic History of the Project,'' Results of Slag Analysis by PA DER Module 1 Procedure,'' Properties of the Coals Limestone Used in the Test Effort,'' Results of the Solid Waste Sampling Performed on the Coal Tech Combustor by an Independent Contractor During the February 1990 Tests.'' (VC)

  1. Effects of polycyclic aromatic compounds in fine particulate matter generated from household coal combustion on response to EGFR mutations in vitro.

    Science.gov (United States)

    Ho, Kin-Fai; Chang, Chih-Cheng; Tian, Linwei; Chan, Chi-Sing; Musa Bandowe, Benjamin A; Lui, Ka-Hei; Lee, Kang-Yun; Chuang, Kai-Jen; Liu, Chien-Ying; Ning, Zhi; Chuang, Hsiao-Chi

    2016-11-01

    Induction of PM2.5-associated lung cancer in response to EGFR-tyrosine kinase inhibitors (EGFR-TKI) remains unclear. Polycyclic aromatic hydrocarbons (PAHs) and their polar derivatives (oxygenated PAHs: OPAHs and azaarenes: AZAs) were characterized in fine particulates (PM2.5) emitted from indoor coal combustion. Samples were collected in Xuanwei (Yunnan Province), a region in China with a high rate of lung cancer. Human lung adenocarcinoma cells A549 (with wild-type EGFR) and HCC827 (with EGFR mutation) were exposed to the PM2.5, followed by treatment with EGFR-TKI. Two samples showed significant and dose-dependent reduction in the cell viability in A549. EGFR-TKI further demonstrated significantly decreased in cell viability in A549 after exposure to the coal emissions. Chrysene and triphenylene, dibenzo[a,h]anthracene, benzo[ghi]perylene, azaarenes and oxygenated polycyclic aromatic hydrocarbons (carbonyl-OPAHs) were all associated with EGFR-TKI-dependent reduced cell viability after 72-h exposure to the PM2.5. The findings suggest the coal emissions could influence the response of EGFR-TKI in lung cancer cells in Xuanwei.

  2. Test of Advanced Fine Water Mist Nozzles in a Representative Spacecraft Atmosphere Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Fine water mist is being considered as a replacement technology for fire suppression on the next generation of manned spacecraft. It offers advantages in...

  3. Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 2

    Energy Technology Data Exchange (ETDEWEB)

    McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K. [eds.

    1994-06-01

    The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume II contains papers presented at the following sessions: filter technology issues; hazardous air pollutants; sorbents and solid wastes; and membranes. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  4. Update of progress for Phase II of B&W`s advanced coal-fired low-emission boiler system

    Energy Technology Data Exchange (ETDEWEB)

    McDonald, D.K. [Babcock & Wilcox, Barberton, OH (United States); Madden, D.A.; Rodgers, L.W. [Babcock & Wilcox, Alliance, OH (United States)] [and others

    1995-11-01

    Over the past five years, advances in emission control techniques at reduced costs and auxiliary power requirements coupled with significant improvements in steam turbine and cycle design have significantly altered the governing criteria by which advanced technologies have been compared. With these advances, it is clear that pulverized coal technology will continue to be competitive in both cost and performance with other advanced technologies such as Integrated Gasification Combined Cycle (IGCC) or first generation Pressurized Fluidized Bed Combustion (PFBC) technologies for at least the next decade. In the early 1990`s it appeared that if IGCC and PFBC could achieve costs comparable to conventional pulverized coal plants, their significantly reduced NO{sub x} and SO{sub 2} emissions would make them more attractive. A comparison of current emission control capabilities shows that all three technologies can already achieve similarly low emissions levels.

  5. Modeling Creep-Fatigue-Environment Interactions in Steam Turbine Rotor Materials for Advanced Ultra-supercritical Coal Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Chen [General Electric Global Research, Niskayuna, NY (United States)

    2014-04-01

    The goal of this project is to model creep-fatigue-environment interactions in steam turbine rotor materials for advanced ultra-supercritical (A-USC) coal power Alloy 282 plants, to develop and demonstrate computational algorithms for alloy property predictions, and to determine and model key mechanisms that contribute to the damages caused by creep-fatigue-environment interactions.

  6. AN ADVANCED COARSE-FINE SEARCH APPROACH FOR DIGITAL IMAGE CORRELATION APPLICATIONS

    Directory of Open Access Journals (Sweden)

    Samo Simončič

    2016-04-01

    Full Text Available The paper presents a newly developed fine search algorithm used in the application of digital correlation. In order to evaluate its performance a special purpose application was developed using C# programming language. The algorithm was then tested on a pre-prepared set of the computer generated speckled images. It turned out to be much faster than the conventional fine search algorithm. Consequently, it is a major step forward in a never ending quest for a fast digital correlation execution with sub pixel accuracy.

  7. In-plant testing of a novel coal cleaning circuit using advanced technologies. Technical report, September 1--November 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mining Engineering; Reed, S. [Kerr-McGee Coal Corp., Oklahoma City, OK (United States)

    1995-12-31

    A circuit utilizing hindered-bed classifiers, enhanced gravity concentrators and column flotation has been found to provide a highly efficient cleaning of fine coal in which both ash and total sulfur contents are significantly reduced while maximizing the recovery of coal. In this study, a circuit comprised of the three technologies will be tested in an operating preparation plant to evaluate circuit performance and to compare the performance with the current technologies used to treat fine coal. Prior to the in-plant testing, the effect of changing feed characteristics on the performance of the enhanced gravity concentrator was evaluated for process control purposes. During this reporting period, a {minus}16 mesh Illinois No. 6 coal sample containing about 30% ash and 8.0% total sulfur was collected from a refuse pond. The ash and total sulfur contents of the sample were depleted by withdrawing a controlled amount of tailings produced by the unit to determine the effect of changing feed compositions. It was found that higher combustible recovery values are achieved when the feed ash content is decreased and slightly lower product sulfur content values are obtained when the pyritic sulfur content in the feed is decreased. The lower total sulfur contents are most likely due to the natural by-pass to the product stream of 5--10% of the heavy particles. In other words, an increase in the feed sulfur content results in an incremental increase in the sulfur content of the product. The higher combustible recovery values obtained with decreasing feed ash contents are likely due to a reduction in the amount of entrapped coal particles within the bed of heavy-particles formed contiguous to the bowl wall in the Falcon unit. Higher bowl speeds and adjustment of the tailings rate have been found to counter the negative effects caused by the increase in feed ash and total sulfur contents.

  8. Valorization of bituminous coal pulps using column flotation; Valorisation de fines de charbon bitumineux par flottation en colonnes

    Energy Technology Data Exchange (ETDEWEB)

    Gursu, G.; Hicyilmaz, C. [Universite du Moyen-Orient, Ankara (Turkey); Bilgen, S. [Universite de Mersin (Turkey)

    2001-03-01

    Washing tests were performed with 5 x 5 x 200 cm{sup 3} laboratory flotation columns on bituminous coal pulps from Zonguldak (Turkey) containing 47.52% of ash. The final product contains 10% of ash with a 73.52% recovery. A re-washing of this concentrate allows to obtain a final product with 5.88% of ash and a 59.27% recovery. Abstract only. (J.S.)

  9. The Coal-Seq III Consortium. Advancing the Science of CO2 Sequestration in Coal Seam and Gas Shale Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Koperna, George [Advanced Resources International Inc., Arlington, VA (United States)

    2014-03-14

    The Coal-Seq consortium is a government-industry collaborative that was initially launched in 2000 as a U.S. Department of Energy sponsored investigation into CO2 sequestration in deep, unmineable coal seams. The consortium’s objective aimed to advancing industry’s understanding of complex coalbed methane and gas shale reservoir behavior in the presence of multi-component gases via laboratory experiments, theoretical model development and field validation studies. Research from this collaborative effort was utilized to produce modules to enhance reservoir simulation and modeling capabilities to assess the technical and economic potential for CO2 storage and enhanced coalbed methane recovery in coal basins. Coal-Seq Phase 3 expands upon the learnings garnered from Phase 1 & 2, which has led to further investigation into refined model development related to multicomponent equations-of-state, sorption and diffusion behavior, geomechanical and permeability studies, technical and economic feasibility studies for major international coal basins the extension of the work to gas shale reservoirs, and continued global technology exchange. The first research objective assesses changes in coal and shale properties with exposure to CO2 under field replicated conditions. Results indicate that no significant weakening occurs when coal and shale were exposed to CO2, therefore, there was no need to account for mechanical weakening of coal due to the injection of CO2 for modeling. The second major research objective evaluates cleat, Cp, and matrix, Cm, swelling/shrinkage compressibility under field replicated conditions. The experimental studies found that both Cp and Cm vary due to changes in reservoir pressure during injection and depletion under field replicated conditions. Using laboratory data from this study, a compressibility model was developed to predict the pore-volume compressibility, Cp, and the matrix compressibility, Cm, of coal and shale, which was applied to

  10. 四台选煤厂降低末精煤水分的措施%Measures of reducing moisture of fine clean coal in Sitai coal preparation plant

    Institute of Scientific and Technical Information of China (English)

    安尧

    2014-01-01

    针对四台选煤厂末精煤水分偏高问题,分析了末精煤产品组成和水分,发现粗煤泥和细煤泥水分较高是造成末精煤水分偏高的主要原因。通过将传统弧形筛改造为智能振动筛网式弧形筛,定期翻转弧形筛筛网,在筛面增设挡皮;将FC1200离心机筛篮孔径由0.375 mm增至0.500 mm,调整煤泥旋流器组运行参数;加大压滤机维护力度,根据压滤机入料浓度及时调整压滤机工艺参数;引进HVPF-120 m2立式压滤机;“以灰换水”增加筛分煤系统等措施,使末精煤水分由15.72%降至14.00%以内,减少产品运输系统中胶带机打滑现象,减轻员工劳动强度,外运精煤冻车皮现象得以杜绝,确保了选煤厂正常外运,仅运费一项就节约成本540万元。%To reduce the moisture of fine clean coal of Sitai coal preparation plant,analyse the product composition and moisture,find that high moisture of coarse slime and filter cake are the main reasons.To resolve this problem,take the following measures.First,replace the traditional sieve bend with the intelligent vibratory one,flip the screen surface regularly,add belt to screen surface in order to slow the speed of slurry.Second,increase the sieve seam of FC1200 centrifuge from 0.375 mm to 0.500 mm and adjust the operation parameters of hydrocyclone group. Third, improve maintenance of filter and adjust process parameters promptly according to the feed concentration. Fourth,introduce a vertical filter HVPF-120 m2,and increase ash to lower moisture by adding coal screening system.By these measures, the moisture of fine clean coal decrease from 15.72% to under 14. 00%,which reduce the belt slipping in product transportation system and decrease the labor intensity.Beyond that,the clean coal no longer freeze the railway cars.The measures ensure the normal outward transport of Sitai coal preparation plant and saves transport costs 5.4 ×106 yuan.

  11. Effect of pure oxygen fine bubbles on the organic matter removal and bacterial community evolution treating coal gasification wastewater by membrane bioreactor.

    Science.gov (United States)

    Zhuang, Haifeng; Hong, Xiaoting; Han, Hongjun; Shan, Shengdao

    2016-12-01

    A lab-scale study was investigated to evaluate the effect of pure oxygen fine bubbles on membrane bioreactor (O2-MBR) performance of treating coal gasification wastewater. Compared with conventional MBR using aeration source of air (CMBR), the removal efficiencies of COD and total phenols increased by 28% and 36%, and the organic compositions of treated effluent represented significant difference that was mainly attributed to the controlled the foam expansion and enhanced the enzymatic activities in O2-MBR. Moreover, membrane fouling mitigation was observed in O2-MBR, probably owing to the less EPS amount and larger PSD. It was notable that the pure oxygen with fine bubbles promoted marked evolution of bacterial community from CMBR to O2-MBR, particularly, the bacterial community richness and diversity in O2-MBR was lower than CMBR, and the genera Phycisphaera, Comamonas, Thauera and Ohtaekwangia composed the top four most relative abundance genera in O2-MBR, giving the total relative abundance of 26.7%.

  12. Monolithic solid oxide fuel cell technology advancement for coal-based power generation

    Science.gov (United States)

    1994-05-01

    This project has successfully advanced the technology for MSOFC's for coal-based power generation. Major advances include: tape-calendering processing technology, leading to 3X improved performance at 1000 C; stack materials formulations and designs with sufficiently close thermal expansion match for no stack damage after repeated thermal cycling in air; electrically conducting bonding with excellent structural robustness; and sealants that form good mechanical seals for forming manifold structures. A stack testing facility was built for high-spower MSOFC stacks. Comprehensive models were developed for fuel cell performance and for analyzing structural stresses in multicell stacks and electrical resistance of various stack configurations. Mechanical and chemical compatibility properties of fuel cell components were measured; they show that the baseline Ca-, Co-doped interconnect expands and weakens in hydrogen fuel. This and the failure to develop adequate sealants were the reason for performance shortfalls in large stacks. Small (1-in. footprint) two-cell stacks were fabricated which achieved good performance (average area-specific-resistance 1.0 ohm-sq cm per cell); however, larger stacks had stress-induced structural defects causing poor performance.

  13. ADVANCED MULTI-PRODUCT COAL UTILIZATION BY-PRODUCT PROCESSING PLANT

    Energy Technology Data Exchange (ETDEWEB)

    Robert Jewell; Thomas Robl; John Groppo

    2005-03-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. The ash produced by the plant was found to be highly variable as the plant consumes high and low sulfur bituminous coal, in Units 1 and 2 and a mixture of subbituminous and bituminous coal in Units 3 and 4. The ash produced reflected this consisting of an iron-rich ({approx}24%, Fe{sub 2}O{sub 3}), aluminum rich ({approx}29% Al{sub 2}O{sub 3}) and high calcium (6%-7%, CaO) ash, respectively. The LOI of the ash typically was in the range of 5.5% to 6.5%, but individual samples ranged from 1% to almost 9%. The lower pond at Ghent is a substantial body, covering more than 100 acres, with a volume that exceeds 200 million cubic feet. The sedimentation, stratigraphy and resource assessment of the in place ash was investigated with vibracoring and three-dimensional, computer-modeling techniques. Thirteen cores to depths reaching nearly 40 feet, were retrieved, logged in the field and transported to the lab for a series of analyses for particle size, loss on ignition, petrography, x-ray diffraction, and x-ray fluorescence. Collected data were processed using ArcViewGIS, Rockware, and Microsoft Excel to create three-dimensional, layered iso-grade maps, as well as stratigraphic columns and profiles, and reserve estimations. The ash in the pond was projected to exceed 7 million tons and contain over 1.5 million tons of coarse carbon, and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. The size, quality and consistency of the ponded material suggests that it is the better feedstock for the beneficiation plant.

  14. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Smith, V.E.

    1994-05-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  15. Study of Compressive Strength of Concrete with Coal Power Plant Fly Ash as Partial Replacement of Cement and Fine Aggregate

    Directory of Open Access Journals (Sweden)

    FAREED AHMED MEMON

    2010-10-01

    Full Text Available This research study comprises of concrete cubes made with Ordinary Portland Cement and with different configurations of fly ash by replacing cement and fine aggregate. To achieve the aim of this study, total 81 concrete cubes were cast. Among 81 cubes, 9 cubes were made with normal concrete, 36 cubes were made by replacing 25%, 50%, 75% and 100% of fine aggregate with fly ash and 36 cubes were made by replacing 10%, 25%, 50%, and 75% of cement with fly ash. The cubes were 6\\" x 6\\" in cross-section, and the mix design was aimed for 5000 psi. After proper curing of all 81 cubes, they were tested at 3, 7 and 28 days curing age. The cubes were tested in Forney Universal Testing Machine. By analyzing the test results of all the concrete cubes, the following main findings have been drawn. The compressive strength of concrete cubes made by replacing 100 % fine aggregate by fly ash was higher than the concrete cubes made with Ordinary Portland Cement at all 3, 7 and 28 days curing ages. On the other hand, the compressive strength of concrete cubes made by replacing 10 % and 25 % cement by fly ash was slightly lower than the concrete cubes made with Ordinary Portland Cement at all curing ages, whereas, the compressive strength of concrete cubes made by replacing 50 % and 75 % of cement by fly ash were quite lower than the concrete cubes made with Ordinary Portland Cement at all curing ages.

  16. Recent advances in the use of synchrotron radiation for the analysis of coal combustion products

    Energy Technology Data Exchange (ETDEWEB)

    Manowitz, B. [Brookhaven National Lab., Upton, NY (United States)

    1995-11-01

    Two major coal combustion problems are the formation and build-up of slag deposits on heat transfer surfaces and the production and control of toxic species in coal combustion emissions. The use of synchrotron radiation for the analysis of coal combustion products can play a role in the better understanding of both these phenomena. An understanding of the chemical composition of such slags under boiler operating conditions and as a function of the mineral composition of various coals is one ultimate goal of this program. The principal constituents in the ash of many coals are the oxides of Si, Al, Fe, Ca, K, S, and Na. The analytical method required must be able to determine the functional forms of all these elements both in coal and in coal ash at elevated temperatures. One unique way of conducting these analyses is by x-ray spectroscopy.

  17. Advanced characterization of pores and fractures in coals by nuclear magnetic resonance and X-ray computed tomography

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    This paper demonstrates capabilities of low-field nuclear magnetic resonance (NMR) and microfocus X-ray computed tomography (μCT) in advanced, nondestructive, and quantitative characterization of pore types, producible porosity, pore structure, and spatial disposition of pore-fractures in coals. Results show that the NMR transverse relaxation time (T2) at 0.5–2.5, 20–50, and >100 ms correspond to pores of <0.1 μm, >0.1 μm, and fractures, respectively. A much higher T2 spectrum peak reflects a much better development of pores (or fractures) corresponding to the T2, and vice versa. Three basic components in coals, i.e., the pores (or fractures), coal matrix, and minerals have their distinctive range of CT numbers. Among these, the CT number of pores is commonly less than 600 HU. The producible porosity, which is a determination of permeability, can be calculated by T2 cutoff value (T2C) of coal NMR. The coal pore structure can be efficiently estimated by the newly proposed "T2C based model". Finally, μCT scan was proven capable of modeling and spatial visualization of pores and fractures.

  18. Development of an Advanced Deshaling Technology to Improve the Energy Efficiency of Coal Handling, Processing, and Utilization Operations

    Energy Technology Data Exchange (ETDEWEB)

    Rick Honaker; Gerald Luttrell

    2007-09-30

    The concept of using a dry, density-based separator to achieve efficient, near-face rock removal, commonly referred to as deshaling, was evaluated in several applications across the U.S.. Varying amounts of high-density rock exist in most run-of-mine feed. In the central Appalachian coalfields, a rock content exceeding 50% in the feed to a preparation plant is commonplace due to high amounts of out-of-seam dilution made necessary by extracting coal from thin seams. In the western U.S, an increase in out-of-seam dilution and environmental regulations associated with combustion emissions have resulted in a need to clean low rank coals and dry cleaning may be the only option. A 5 ton/hr mobile deshaling unit incorporating a density-based, air-table technology commercially known as the FGX Separator has been evaluated at mine sites located within the states of Utah, Wyoming, Texas, West Virginia, Virginia, Pennsylvania and Kentucky. The FGX technology utilizes table riffling principles with air as the medium. Air enters through the table and creates a fluidized bed of particles comprised of mostly fine, high density particles. The high density particle bed lifts the low-density coal particles to the top of the bed. The low-density coal moves toward the front of the table due to mass action and the downward slope of the table. The high-density particles settle through the fluidized particle bed and, upon making contact with the table, moves toward the back of the table with the assistance of table vibration. As a result, the low-density coal particles exit the front of the table closest to the feed whereas the high-density, high-ash content particles leave on the side and front of the table located at the farthest from the feed entry. At each test site, the run-of-mine feed was either directly fed to the FGX unit or pre-screened to remove the majority of the -6mm material. The surface moisture of the feed must be maintained below 9%. Pre-screening is required when the

  19. Numerical simulation of fine blanking process using fully coupled advanced constitutive equations with ductile damage

    Science.gov (United States)

    Labergere, C.; Saanouni, K.; Benafia, S.; Galmiche, J.; Sulaiman, H.

    2013-05-01

    This paper presents the modelling and adaptive numerical simulation of the fine blanking process. Thermodynamically-consistent constitutive equations, strongly coupled with ductile damage, together with specific boundary conditions (particular command of forces on blank holder and counterpunch) are presented. This model is implemented into ABAQUS/EXPLICIT using the Vumat user subroutine and connected with an adaptive 2D remeshing procedure. The different material parameters are identified for the steel S600MC using experimental tensile tests conducted until the final fracture. A parametric study aiming to examine the sensitivity of the process parameters (die radius, clearance die/punch) to the punch force and fracture surfaces topology (convex zone, sheared zone, fracture zone and the burr).

  20. Optimising mechanical behaviour of new advanced steels based on fine non-equilibrium microstructures

    NARCIS (Netherlands)

    HajyAkbary, F.

    2015-01-01

    This Ph.D. thesis investigates the relation between microstructural and mechanical properties of Advanced High Strength Steels (AHSS), with the goal of developing a microstructure with optimised mechanical properties. Among different grades of AHSS, Quenching and Partitioning (Q&P) steel which is co

  1. Multiplexed Optical Fiber Sensors for Coal Fired Advanced Fossil Energy Systems

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Anbo [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Pickrell, Gary [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)

    2012-03-31

    This report summarizes technical progress on the program Multiplexed Optical Fiber Sensors for Coal Fired Advanced Fossil Energy Systems funded by the National Energy Technology Laboratory of the U.S. Department of Energy, and performed jointly by the Center for Photonics Technology of the Bradley Department of Electrical and Computer Engineering and the Department of Materials Science and Engineering at Virginia Tech. This three-year project started on October 1, 2008. In the project, a fiber optical sensing system based on intrinsic Fabry-Perot Interferometer (IFPI) was developed for strain and temperature measurements for Ultra Supercritical boiler condition assessment. Investigations were focused on sensor design, fabrication, attachment techniques and novel materials for high temperature and strain measurements. At the start of the project, the technical requirements for the sensing technology were determined together with our industrial partner Alstom Power. As is demonstrated in Chapter 4, all the technical requirements are successfully met. The success of the technology extended beyond laboratory test; its capability was further validated through the field test at DOE NETL, in which the sensors yielded distributed temperature mapping of a testing coupon installed in the turbine test rig. The measurement results agreed well with prior results generated with thermocouples. In this project, significant improvements were made to the IFPI sensor technology by splicing condition optimization, transmission loss reduction, sensor signal demodulation and sensor system design.

  2. Hydrogeologic investigation of the Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama

    Energy Technology Data Exchange (ETDEWEB)

    Gardner, F.G.; Kearl, P.M.; Mumby, M.E.; Rogers, S.

    1996-09-01

    This document describes the geology and hydrogeology at the former Advanced Coal Liquefaction Research and Development (ACLR&D) facility in Wilsonville, Alabama. The work was conducted by personnel from the Oak Ridge National Laboratory Grand Junction office (ORNL/GJ) for the U.S. Department of Energy (DOE) Pittsburgh Energy Technology Center (PETC). Characterization information was requested by PETC to provide baseline environmental information for use in evaluating needs and in subsequent decision-making for further actions associated with the closeout of facility operations. The hydrogeologic conceptual model presented in this report provides significant insight regarding the potential for contaminant migration from the ACLR&D facility and may be useful during other characterization work in the region. The ACLR&D facility is no longer operational and has been dismantled. The site was characterized in three phases: the first two phases were an environmental assessment study and a sod sampling study (APCO 1991) and the third phase the hydraulic assessment. Currently, a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) remedial investigation (RI) to address the presence of contaminants on the site is underway and will be documented in an RI report. This technical memorandum addresses the hydrogeologic model only.

  3. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    James T. Cobb, Jr.

    2003-09-12

    Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatment with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.

  4. Development of clean coal and clean soil technologies using advanced agglomeration techniques

    Energy Technology Data Exchange (ETDEWEB)

    Ignasiak, B.; Ignasiak, T.; Szymocha, K.

    1990-01-01

    Three major topics are discussed in this report: (1) Upgrading of Low Rank Coals by the Agflotherm Process. Test data, procedures, equipment, etc., are described for co-upgrading of subbituminous coals and heavy oil; (2) Upgrading of Bituminous Coals by the Agflotherm Process. Experimental procedures and data, bench and pilot scale equipments, etc., for beneficiating bituminous coals are described; (3) Soil Clean-up and Hydrocarbon Waste Treatment Process. Batch and pilot plant tests are described for soil contaminated by tar refuse from manufactured gas plant sites. (VC)

  5. Pure Air`s Advanced Flue Gas Desulfurization Clean Coal Project

    Energy Technology Data Exchange (ETDEWEB)

    Brown, J.R. [Pure Air Bailly Station, Chesterton, IN (United States)

    1997-12-31

    Pure Air`s Advanced Flue Gas Desulfurization (AFGD) Clean Coal Project successfully completed four and a half years of operation in December 1996 at Northern Indiana Public Service Company`s (NIPSCO) Bailly Generation Station. Included in this was a three year DOE demonstration period. The project was built by a joint venture company of Air Products and Chemicals, Inc. and Mitsubishi Heavy Industries America, Inc., utilizing Mitsubishi`s wet limestone flue gas desulfurization technology. The project met or exceeded all performance criteria. It has averaged 95.3% SO{sub 2} removal, 99.9% availability and produced 936,000 metric tons of high quality commercial gypsum during this four and a half year period. It demonstrated many advanced technology features including a single, large absorber module serving two boilers, a wastewater evaporation system, an air rotary sparger for oxidation, and a new technology for agglomerating gypsum. The AFGD system was designed, built, owned and operated by Pure Air and will continue to serve NIPSCO`s Bailly Station for at least another 15{1/2} years under an Own and Operate contract. The project enabled NIPSCO to cost effectively achieve full system wide compliance with the Phase 2 emission requirements for SO{sub 2} of the Clean Air Act Amendments (CAAA) of 1990 almost eight years before the target date. The project was the recipient of the Outstanding Engineering Achievement Award from the National Society of Professional Engineers in 1993 and the 1993 Powerplant Award from Power magazine. The data presented in this paper are based on performance during the first three years of operation.

  6. Advanced technology applications for second and third generation coal gasification systems. Appendix

    Science.gov (United States)

    Bradford, R.; Hyde, J. D.; Mead, C. W.

    1980-01-01

    Sixteen coal conversion processes are described and their projected goals listed. Tables show the reactants used, products derived, typical operating data, and properties of the feed coal. A history of the development of each process is included along with a drawing of the chemical reactor used.

  7. 78 FR 49061 - Valuation of Federal Coal for Advance Royalty Purposes and Information Collection Applicable to...

    Science.gov (United States)

    2013-08-12

    ... steam market and the stoker market. However, coal sold in the stoker market can demand and receive a higher price and should not be considered comparable to the same coal sold in the steam market. Another example is boilers in steam power plants that may have lower ash requirements than boilers used...

  8. FY 2000 Report on the results of international cooperative research scheme (power generation - No.3). Developmental research on high-performance plasma-assisted fine coal powder combustion mechanism for coal-fired power generation boilers to realize oilless ignition; 2000 nendo kokusai kyodo kenkyu teian kobo jigyo seika hokokusho (hatsuden No.3). Oilless chakka wo jitsugensuru sekitan karyoku hatsuden bifuntan nenshoroyo koseino plasma jonen kiko no kaihatsu kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Described herein are the results of the developmental research on the high-performance plasma-assisted fine coal powder combustion mechanism for coal-fired power generation boilers, a theme adopted by the international cooperative research scheme. The program for design/manufacture of the plasma torch manufactures laminar type torches for 100kW high power class and 10kW middle class. The high-performance plasma-assisted combustion mechanism is designed and manufactured using the torch. It has a structure which supplies secondary air and secondary coal flow to the primary coal flow. It is tested for starting up a commercial boiler firing finely pulverized coal, to confirm its functions. The tests for optimizing the oilless ignition and operation are conducted in Tashtagonal Iron Plant and Berdsk Chemical Plant. It is found that the cold start can be realized in the boiler, when the muffle burners are preheated for 30 to 40 minutes before the finely pulverized coal is supplied and the steady-state coal combustion is attained 3 to 5 minutes after the coal is supplied. The program for the combustion basics for the plasma-assisted mechanism collects the data related to its dependence on coal type. (NEDO)

  9. Optimising mechanical behaviour of new advanced steels based on fine non-equilibrium microstructures

    OpenAIRE

    HajyAkbary, F.

    2015-01-01

    This Ph.D. thesis investigates the relation between microstructural and mechanical properties of Advanced High Strength Steels (AHSS), with the goal of developing a microstructure with optimised mechanical properties. Among different grades of AHSS, Quenching and Partitioning (Q&P) steel which is composed of thin films of retained austenite between carbon depleted martensite laths, is selected. Different Q&P microstructures were developed in a 0.3C-1.6Si-3.5Mn (wt.%) steel with non-homogenous...

  10. Contribution of heavy metals to toxicity of coal combustion related fine particulate matter (PM2.5) in Caenorhabditis elegans with wild-type or susceptible genetic background.

    Science.gov (United States)

    Sun, Lingmei; Wu, Quli; Liao, Kai; Yu, Peihang; Cui, Qiuhong; Rui, Qi; Wang, Dayong

    2016-02-01

    Contribution of chemical components in coal combustion related fine particulate matter (PM2.5) to its toxicity is largely unclear. We focused on heavy metals in PM2.5 to investigate their contribution to toxicity formation in Caenorhabditis elegans. Among 8 heavy metals examined (Fe, Zn, Pb, As, Cd, Cr, Cu, and Ni), Pb, Cr, and Cu potentially contributed to PM2.5 toxicity in wild-type nematodes. Combinational exposure to any two of these three heavy metals caused higher toxicity than exposure to Pb, Cr, or Cu alone. Toxicity from the combinational exposure to Pb, Cr, and Cu at the examined concentrations was higher than exposure to PM2.5 (100 mg/L). Moreover, mutation of sod-2 or sod-3 gene encoding Mn-SOD increased susceptibility in nematodes exposed to Fe, Zn, or Ni, although Fe, Zn, or Ni at the examined concentration did not lead to toxicity in wild-type nematodes. Our results highlight the potential contribution of heavy metals to PM2.5 toxicity in environmental organisms.

  11. Study on Reduction Kinetics of Briquettes of Hematite Fines with Boiler Grade Coal and Coke Dust in Two Different Forms: Intermixing and Multilayered

    Science.gov (United States)

    Roy, Gopal Ghosh; Sarkar, Bitan Kumar; Chaudhuri, Mahua Ghosh; Mitra, Manoj Kumar; Dey, Rajib

    2016-11-01

    An attempt has been made to utilise hematite ore fines in the form of briquettes with two different form of mixing i.e. intermixing and multilayered by means of carbothermal reduction along with boiler grade coal and coke dust. The influence of reduction temperature (1323, 1373 and 1423 K) and reduction time (10, 20, 30, 45 and 60 min) has been investigated in detail and the reduced briquettes are characterised by XRD, SEM analyses. The reducibility of intermixing briquettes is found to be higher for multilayered briquettes. In addition, isothermal kinetic study has also been carried out for both intermixing and multilayered briquettes. The activation energy for intermixing briquettes are evaluated to be 125.88 kJ/mol for the initial stage of reaction (CG3 controlled mechanism) and 113.11 kJ/mol for the later part of reaction (D3 controlled mechanism), respectively. In case of multilayered briquettes, the corresponding activation energy is found to be 235.59 kJ/mol for reaction (CG3 controlled mechanism). These results corroborate the observed better reducibility of the intermixing briquettes over multilayered briquettes.

  12. Low-rank coal research. Final technical report, April 1, 1988--June 30, 1989, including quarterly report, April--June 1989

    Energy Technology Data Exchange (ETDEWEB)

    1989-12-31

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  13. 古叙矿区选煤厂细粒级分级入洗工艺的探讨和分析%Discussion and analysis on fine particle grading in washing process in Guxu coal preparation plant

    Institute of Scientific and Technical Information of China (English)

    杨泽伟; 王川

    2013-01-01

    针对选煤厂高度泥化煤质煤泥水处理的问题进行探讨,对古叙矿区原煤伴生矿及其夹矸高度泥化的特征进行了分析试验,同时对现有细粒级分级设备的优缺点进行了对比,并结合企业煤炭产品结构及对选煤厂生产成本进行了分析,从而选择在技术经济和经营结构上都较为合理的选煤工艺及设备选型。%In view of the problems of coal slurry water treatment of high argillization coal, the characters of raw ore in Guxu minging area and gangue with highly argillization have been tested and analyzed.Meanwhile,the advantages and disadvantages of existing fine particle gradG ing equipment have been compared,and after combined with the analyzation of coal product structure and production costs in coal preparation plant,the reasonable coal preparation process and equipment have been selection based on technical economic and business structures.

  14. Pilot Demonstration of Technology for the Production of High Value Materials from the Ultra-Fine (PM2.5) Fraction of Coal Combustion Ash

    Energy Technology Data Exchange (ETDEWEB)

    T. L. Robl; J. G. Groppo; R. Rathbone; B. Marrs; R. Jewell

    2008-07-18

    polyethylene terphthalate filled polymers were prepared and subjected to SEM analysis to verify that the UFA was well dispersed. The addition of fillers increased the modulus of the HDPE composite, but decreased both the offset yield stress and offset yield strain, showing that the fillers essentially made the composite stiffer but the transition to plastic deformation occurred earlier in filled HDPE as stress was applied. Similar results were obtained with TPE, however, the decrease in either stress or strain at offset yield were not as significant. Dynamic mechanical analyses (DMA) were also completed and showed that although there were some alterations in the properties of the HDPE and TPE, the alterations are small, and more importantly, transition temperatures are not altered. The UFA materials were also tested in expanded urethanes, were improvements were made in the composites strength and stiffness, particularly for lighter weight materials. The results of limited flammability and fire safety testing were encouraging. A flowsheet was developed to produce an Ultra-Fine Ash (UFA) product from reclaimed coal-fired utility pond ash. The flowsheet is for an entry level product development scenario and additional production can be accommodated by increasing operating hours and/or installing replicate circuits. Unit process design was based on experimental results obtained throughout the project and cost estimates were derived from single vendor quotes. The installation cost of this plant is estimated to be $2.1M.

  15. [Study on the Relationship between the Inhalable Fine Particulate Matter of Xuanwei Coal Combustion and Lung Cancer].

    Science.gov (United States)

    Yang, Jiapeng; Cao, Yu; Huang, Yunchao; Li, Guangjian; Ye, Lianhua; Zhao, Guangqiang; Lei, Yujie; Chen, Xiaobo; Tian, Linwei

    2015-07-01

    背景与目的 云南省宣威地区是中国乃至世界肺癌的高发区,肺癌已成为制约当地社会经济发展和影响社会民生的重要因素。煤炭是当地主要的生活燃料,燃煤是当地室内污染的主要来源。本研究探讨云南宣威不同肺癌发病率地区烟煤燃烧过程中可吸入细颗粒物(fine particulate matter, PM2.5)产出情况,以及不同地区PM2.5成分异同。探讨吸入细颗粒物与当地肺癌高发的关系。方法 收集宣威市来宾镇老林煤矿C1煤层、宝山镇虎场煤矿K7煤层、文兴镇太平煤矿M30煤层的煤矿进行燃烧试验。收集室内的空气中的PM2.5进行称重,元素分析,用电子显微镜观察其形态,对比三种PM2.5异同。对宣威地区的肺癌患者的术后标本进行电子显微镜观察。结果 室内空气中的PM2.5浓度分别为C1煤(8.244±1.460)mg/m³,K7煤(5.066±0.984)mg/m³,K7煤(5.071±1.460)mg/m³;三组空气中PM2.5浓度两两比较差异有统计学意义(Ρ=0.029)。C1煤层中滤膜上的杂质有(Silicon, Si)和氧(Oxygen, O)元素富集,三组滤膜上均发现了碳(Carbon, C),硫(Sulfur, S)的聚集,在部分的滤膜上可见游离的二氧化硅(SiO2),部分滤膜上有铝(Aluminium, Al)、钙(Calcium, Ca)元素的聚集。C1煤层与其他煤层相比所产生颗粒物形态不规则,成团块状,杂质较多。在部分的宣威来宾地区的肺癌患者术后标本中,发现纳米级细颗粒的杂质。结论 C1煤与K7和M30煤燃烧产生的PM2.5不同,PM2.5的成分可能与当地肺癌高发相关。.

  16. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    Energy Technology Data Exchange (ETDEWEB)

    Thomas Robl; John Groppo

    2009-06-30

    The overall objective of this project is to design, construct, and operate an ash beneficiation facility that will generate several products from coal combustion ash stored in a utility ash pond. The site selected is LG&E's Ghent Station located in Carroll County, Kentucky. The specific site under consideration is the lower ash pond at Ghent, a closed landfill encompassing over 100 acres. Coring activities revealed that the pond contains over 7 million tons of ash, including over 1.5 million tons of coarse carbon and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. These potential products are primarily concentrated in the lower end of the pond adjacent to the outlet. A representative bulk sample was excavated for conducting laboratory-scale process testing while a composite 150 ton sample was also excavated for demonstration-scale testing at the Ghent site. A mobile demonstration plant with a design feed rate of 2.5 tph was constructed and hauled to the Ghent site to evaluate unit processes (i.e. primary classification, froth flotation, spiral concentration, secondary classification, etc.) on a continuous basis to determine appropriate scale-up data. Unit processes were configured into four different flowsheets and operated at a feed rate of 2.5 tph to verify continuous operating performance and generate bulk (1 to 2 tons) products for product testing. Cementitious products were evaluated for performance in mortar and concrete as well as cement manufacture process addition. All relevant data from the four flowsheets was compiled to compare product yields and quality while preliminary flowsheet designs were generated to determine throughputs, equipment size specifications and capital cost summaries. A detailed market study was completed to evaluate the potential markets for cementitious products. Results of the study revealed that the Ghent local fly ash market is currently oversupplied by more than 500,000 tpy and distant markets (i

  17. World market: A survey of opportunities for advanced coal-fired systems

    Energy Technology Data Exchange (ETDEWEB)

    Holt, N.A.H.

    1995-06-01

    Although there is a wide range of forecasts for the future of World energy demand and consumption over the next 25 years, all forecasts show marked increases being required for all forms of fossil fuels even when optimistic projections are made for the future adoption of Nuclear and Renewable energy. It is also generally expected that coal usage will in this period experience its greatest growth (a doubling) in the Asia-Pacific region dominated demographically by China and India. In this paper, energy projections and the extent and nature of the coal reserves available worldwide are examined. While most coal technologies can handle a variety of feedstocks, there are often economic factors that will determine the preferred selection. The matching of technology to coal type and other factors is examined with particular reference to the Asia Pacific region. Oil usage is similarly forecast to experience a comparable growth in this region. Over 70% of the World`s oil reserves are heavy oils and refinery crudes are increasing in gravity and sulfur content. The clean coal technologies of gasification and fluid bed combustion can also use low value petroleum residuals as feedstocks. There is therefore a nearer term market opportunity to incorporate such technologies into cogeneration and coproduction schemes adjacent to refineries resulting in extremely efficient use of these resources.

  18. Flotation advances

    Energy Technology Data Exchange (ETDEWEB)

    Clifford, D.

    1998-11-01

    This paper describes recent advances in flotation cell and mechanism design. OutoKumpu have designed larger cells, suitable for the flotation of smaller particles, with differing mechanisms for particles of different types. Froth handling is also closely controlled. Flotation cells from BQR are also described. Flotation columns are also increasingly being adopted, complementing the use of conventional flotation cells. Designs by Wemco, Multotec, VERTI-MIX, Jameson, Suedala, Quinn and Cytec are detailed, giving improvements in fine coal separation coarse particle separation, and other innovations. 8 figs., 2 tabs.

  19. Advanced technology applications for second and third general coal gasification systems

    Science.gov (United States)

    Bradford, R.; Hyde, J. D.; Mead, C. W.

    1980-01-01

    The historical background of coal conversion is reviewed and the programmatic status (operational, construction, design, proposed) of coal gasification processes is tabulated for both commercial and demonstration projects as well as for large and small pilot plants. Both second and third generation processes typically operate at higher temperatures and pressures than first generation methods. Much of the equipment that has been tested has failed. The most difficult problems are in process control. The mechanics of three-phase flow are not fully understood. Companies participating in coal conversion projects are ordering duplicates of failure prone units. No real solutions to any of the significant problems in technology development have been developed in recent years.

  20. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    Energy Technology Data Exchange (ETDEWEB)

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  1. Recent advances in remote coal mining machine sensing, guidance, and teleoperation

    Energy Technology Data Exchange (ETDEWEB)

    Ralston, J.C.; Hainsworth, D.W.; Reid, D.C.; Anderson, D.L.; McPhee, R.J. [CSIRO Exploration & Minerals, Kenmore, Qld. (Australia)

    2001-10-01

    Some recent applications of sensing, guidance and telerobotic technology in the coal mining industry are presented. Of special interest is the development of semi or fully autonomous systems to provide remote guidance and communications for coal mining equipment. The use of radar and inertial based sensors are considered in an attempt to solve the horizontal and lateral guidance problems associated with mining equipment automation. Also described is a novel teleoperated robot vehicle with unique communications capabilities, called the Numbat, which is used in underground mine safety and reconnaissance missions.

  2. Advanced treatment of oil recovery wastewater from polymer flooding by UV/H2O2/O3 and fine filtration

    Institute of Scientific and Technical Information of China (English)

    REN Guang-meng; SUN De-zhi; Jong Shik CHUNK

    2006-01-01

    In order to purify oil recovery wastewater from polymer flooding (ORWPF) in tertiary oil recovery in oil fields, advanced treatment of UV/H2O2/O3 and fine filtration were investigated. The experimental results showed that polyacrylamide and oil remaining in ORWPF after the conventional treatment process could be effectively removed by UV/H2O2/O3 process. Fine filtration gave a high performance in eliminating suspended solids. The treated ORWPF can meet the quality requirement of the wastewater-bearing polymer injection in oilfield and be safely re-injected into oil reservoirs for oil recovery.

  3. Advanced treatment of biologically pretreated coal gasification wastewater by a novel integration of catalytic ultrasound oxidation and membrane bioreactor.

    Science.gov (United States)

    Jia, Shengyong; Han, Hongjun; Zhuang, Haifeng; Xu, Peng; Hou, Baolin

    2015-01-01

    Laboratorial scale experiments were conducted to investigate a novel system integrating catalytic ultrasound oxidation (CUO) with membrane bioreactor (CUO-MBR) on advanced treatment of biologically pretreated coal gasification wastewater. Results indicated that CUO with catalyst of FeOx/SBAC (sewage sludge based activated carbon (SBAC) which loaded Fe oxides) represented high efficiencies in eliminating TOC as well as improving the biodegradability. The integrated CUO-MBR system with low energy intensity and high frequency was more effective in eliminating COD, BOD5, TOC and reducing transmembrane pressure than either conventional MBR or ultrasound oxidation integrated MBR. The enhanced hydroxyl radical oxidation, facilitation of substrate diffusion and improvement of cell enzyme secretion were the mechanisms for CUO-MBR performance. Therefore, the integrated CUO-MBR was the promising technology for advanced treatment in engineering applications.

  4. Advanced treatment of biologically pretreated coal gasification wastewater by a novel integration of heterogeneous catalytic ozonation and biological process.

    Science.gov (United States)

    Zhuang, Haifeng; Han, Hongjun; Jia, Shengyong; Hou, Baolin; Zhao, Qian

    2014-08-01

    Advanced treatment of biologically pretreated coal gasification wastewater (CGW) was investigated employing heterogeneous catalytic ozonation integrated with anoxic moving bed biofilm reactor (ANMBBR) and biological aerated filter (BAF) process. The results indicated that catalytic ozonation with the prepared catalyst (i.e. MnOx/SBAC, sewage sludge was converted into sludge based activated carbon (SBAC) which loaded manganese oxides) significantly enhanced performance of pollutants removal by generated hydroxyl radicals. The effluent of catalytic ozonation process was more biodegradable and less toxic than that in ozonation alone. Meanwhile, ANMBBR-BAF showed efficient capacity of pollutants removal in treatment of the effluent of catalytic ozonation at a shorter reaction time, allowing the discharge limits to be met. Therefore, the integrated process with efficient, economical and sustainable advantages was suitable for advanced treatment of real biologically pretreated CGW.

  5. An evaluation of deeply-cleaned coals as industrial boiler fuels

    Energy Technology Data Exchange (ETDEWEB)

    Miller, B.G.; Wincek, R.T.; Scaroni, A.W.

    1999-07-01

    AMAX Research and Development Center (AMAX) recently conducted a program for the US Department of Energy (DOE) in which processes for preparing ultra-clean coal were developed (Jha et al., 1997). The coal cleaning methods targeted were advanced column flotation and selective agglomeration. The goal was to develop a coal-based fuel, preferably a coal-water slurry fuel (CWSF), that would be a viable alternative to fuel oil or natural gas in industrial and utility boilers, and would also be appropriate for advanced combustion systems that are under development. Additional objectives were to develop near-term applications of the advanced coal cleaning technologies in new or existing coal preparation plants in order to efficiently process minus 28 mesh fines and convert them into marketable products, and to determine the extent of removal of toxic trace elements from coal by the advanced cleaning technologies. AMAX cleaned three coals in an integrated advanced column flotation and selective agglomeration process development unit. The coals were from the Taggart (Virginia), Indiana VII (Indiana) and Hiawatha (Utah) seams. As a complement to the AMAX program, Penn State is evaluating the deeply-cleaned coals as industrial boiler fuels. Specifically, the handling characteristics, combustion performance, and trace element emissions of the coals are being determined. The coals are being tested in demonstration (20 million Btu/h) and research (2 million Btu/h) boilers as part of a Penn State/DOE project characterizing trace element emissions from coal-fired industrial boilers. This paper will discuss the atomization characteristics and combustion performance (in the demonstration boiler) in a 1 ton/h filter cake re-entrainment circuit. In addition, the combustion performance of the ultra-clean CWSFs is compared to that of other CWSFs prepared in Penn State's 1 ton/h single and double-stage grinding circuit.

  6. Development of advanced coal cleaning process; Kodo sekitan kaishitsu gijutsu no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Osaka, S. [Center for Coal Utilization, Japan, Tokyo (Japan); Akimoto, A.; Yamashita, T. [Idemitsu Kosan Co. Ltd., Tokyo (Japan)

    1996-09-01

    This paper aims to develop a clean coal production process which excellently removes environmental pollutant, is low-costed, and need no particular systems for distribution of products. The result of the development was described paying attention to column flotation which is a technology to high-efficiently select particulate regions, particulate heavy media cyclone, magnetic separation, and the basic design of the process into which those above were integrated. The two-stage selection process, which is an integration of column flotation and particulate heavy media cyclone into the conventional coal preparation equipment, can produce low-ash clean coal at high separation efficiency and also suppress the rise in processing cost. This process was also effective for removal of sulfur content and trace metal elements. The use of clean coal at power plant can be effective for not only the reduction in ash treatment amount, but the aspect of boiler operation characteristics such as heat transfer efficiency of boiler furnace wall, ash related troubles, loads of electrostatic precipitator, loads of flue gas desulfurization facilities. 17 figs., 5 tabs.

  7. Current and advanced NO/sub x/-control technology for coal-fired industrial boilers

    Energy Technology Data Exchange (ETDEWEB)

    1978-12-01

    A NOx-control-technology assessment study of coal-fired industrial boilers was conducted to examine the effectiveness of combustion-modification methods, including low excess air, staged combustion, and burner modifications. Boiler types considered included overfed and underfed stokers, spreader stokers, pulverized-coal and coal-fired cyclone units. Significant variations in NOx emissions occur with boiler type, firing method, and coal type; a relative comparison of emission-control performance, cost, and operational considerations is presented for each method. Baseline (as-found) emissions from grate-fired stokers were shown to be in the range of 200 to 300 ppM. Similarly, as-found emissions from suspension-fired units were quite low (350 to 600 ppM) as compared to comparably designed utility-sized units. Low excess air was shown to be the most effective method on existing units, reducing emissions by approximately 10%. Evaluation of staged combustion and burner modification, however, were limited due to current boiler designs. Major hardware modification/design and implementation are necessary before the potential of these techniques can be fully evaluated. The study emphasized the numerous operational factors that are of major importance to the user in selecting and implementing a combustion-modification program, including energy considerations, incremental capital and operating costs, corrosion, secondary pollutants, and retrofit potential.

  8. Anne Fine

    Directory of Open Access Journals (Sweden)

    Philip Gaydon

    2015-04-01

    Full Text Available An interview with Anne Fine with an introduction and aside on the role of children’s literature in our lives and development, and our adult perceptions of the suitability of childhood reading material.Since graduating from Warwick in 1968 with a BA in Politics and History, Anne Fine has written over fifty books for children and eight for adults, won the Carnegie Medal twice (for Goggle-Eyes in 1989 and Flour Babies in 1992, been a highly commended runner-up three times (for Bill’s New Frock in 1989, The Tulip Touch in 1996, and Up on Cloud Nine in 2002, been shortlisted for the Hans Christian Andersen Award (the highest recognition available to a writer or illustrator of children’s books, 1998, undertaken the positon of Children’s Laureate (2001-2003, and been awarded an OBE for her services to literature (2003. Warwick presented Fine with an Honorary Doctorate in 2005.Philip Gaydon’s interview with Anne Fine was recorded as part of the ‘Voices of the University’ oral history project, co-ordinated by Warwick’s Institute of Advanced Study.

  9. Fine coal particles separation by air-solid magnetic fluidization%气固磁场流态化分选细粒煤

    Institute of Scientific and Technical Information of China (English)

    宋树磊; 赵跃民; 骆振福; 唐利刚; 杨旭亮

    2012-01-01

    利用研制的横流式气固磁稳定流化床,以0.074~0.045 mm粒级磁铁矿粉和磁珠作为高密度和低密度分选介质,对6.0~0.5 mm细粒煤进行连续分选试验。结果表明:当处于稳定流化时,磁场气固流化床比普通气固流化床具有更宽的稳定操作气速范围;外加磁场使磁性颗粒沿磁力线形成平行磁链,增大了床层空隙率,形成了分布均匀的通道,气体通过时不会产生气泡,由此形成了稳定的散式气固磁场流化床;高密度分选和低密度分选的可能偏差分别为0.085,0.075 g/cm3。%Continuous separation tests of fine coal particles of 6. 0-0. 5 mm were done by a crossflow air-solid magneti- cally stabilized fluidized bed ( MSFB ), which used 0. 074-0. 045 mm magnetite powder and magnetite beads as medi- um of high and low density separation respectively. The results show that the range of steadily operational air velocity in air-solid magnetically fluidized beds is broader than that in standard air-solid fluidized beds when they are at stable fluidization. External magnetic field compels the magnetic grains to form parallel magnetic chains following the magnet- ic induction lines, which enlarge the bed voidage and form the uniform air channels. Air bubbles cannot be produced when the air flows through the channels, thus stable and particulate air-solid magnetically fluidized beds coming into being. The possible deviation of high and low density separation are 0. 085 and 0. 075 g/cm3 respectively.

  10. A fine art

    Energy Technology Data Exchange (ETDEWEB)

    Schnabel, G.; Raaff, T. [Andritz AG (Austria)

    2006-07-15

    The paper describes a new dewatering system for coal fines which challenges established processes by using screenbowl centrifuge and hyperbaric filter combinations. Company acquisitions over the past three to four years enabled Andritz AG to develop a new system combining two technologies. The article describes the benefits of the combination process and explains the basic operation of these machines. 4 figs.

  11. Engineering development of advanced coal-fired low-emissions boiler system. Phase II subsystem test design and plan - an addendum to the Phase II RD & T Plan

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-01

    Shortly after the year 2000 it is expected that new generating plants will be needed to meet the growing demand for electricity and to replace the aging plants that are nearing the end of their useful service life. The plants of the future will need to be extremely clean, highly efficient and economical. Continuing concerns over acid rain, air toxics, global climate changes, ozone depletion and solid waste disposal are expected to further then regulations. In the late 1980`s it was commonly believed that coal-fired power plants of the future would incorporate either some form of Integrated Gasification Combined Cycle (IGCC) or first generation Pressurized Fluidized Bed Combustion (PFBS) technologies. However, recent advances In emission control techniques at reduced costs and auxiliary power requirements coupled with significant improvements In steam turbine and cycle design have clearly indicated that pulverized coal technology can continue to be competitive In both cost and performance. In recognition of the competitive potential for advanced pulverized coal-fired systems with other emerging advanced coal-fired technologies, DOE`s Pittsburgh Energy Technology Center (PETC) began a research and development initiative In late 1990 named, Combustion 2000, with the intention of preserving and expanding coal as a principal fuel In the Generation of electrical power. The project was designed for two stages of commercialization, the nearer-term Low Emission Boiler System (LEBS) program, and for the future, the High Performance Power System (HIPPS) program. B&W is participating In the LEBS program.

  12. Energy and environmental research emphasizing low-rank coal. Semi-annual report, January--June 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-09-01

    Summaries of progress on the following tasks are presented: Mixed waste treatment; Hot water extraction of nonpolar organic pollutant from soils; Aqueous phase thermal oxidation wastewater treatment; Review of results from comprehensive characterization of air toxic emissions from coal-fired power plants; Air toxic fine particulate control; Effectiveness of sorbents for trace elements; Catalyst for utilization of methane in selective catalytic reduction of NOx; Fuel utilization properties; Hot gas cleaning; PFBC; catalytic tar cracking; sulfur forms in coal; resid and bitumen desulfurization; biodesulfurization; diesel fuel desulfurization; stability issues; Sorbent carbon development; Evaluation of carbon products; Stable and supercritical chars; Briquette binders; Carbon molecular sieves; Coal char fuel evaporation canister sorbent; Development of a coal by-product classification protocol for utilization; Use of coal ash in recycled plastics and composite materials; Corrosion of advanced structural materials; Joining of advanced structural materials; Resource data evaluation; and the Usti and Labem (Czech Republic) coal-upgrading program.

  13. Advances in dust control technology on South African underground coal mines

    Energy Technology Data Exchange (ETDEWEB)

    Belle, B.K.; Du Plessis, J. [CSIR: Miningtek, Pretoria (South Africa)

    2001-07-01

    Despite the much-heralded arrival of the new millennium, improving mine health and safety remains an enormous challenge. Considerable progress with environmental (dust and methane) control in South African mines has indeed been made but it remains a matter of great concern to all parties, i.e. mine management, labor and the government. The introduction of the 1997 Directive on dust exposure and mine ventilation was a milestone for the South African coal mining industry in improving health and safety standards. These stricter guidelines and the latest dust control technologies are beneficial not only in the long-term health perspective, but also to in terms of controlling methane and coal dust explosions (high-risk) in the short term. Over the past two years, CSIR: Miningtek personnel developed new dust control systems through various Safety In Mines Research Advisory Committee (SIMRAC) funded projects and successfully implemented them in underground coal mines. Currently, it can be confidently claimed that the new and proven dust control systems are being effectively operated in more than 80% of the bord and pillar sections in South Africa. This paper highlights the critical components of the new dust control systems evaluated underground, viz., the half-curtain system, the retrofitted hood system, the double scrubber system and the integrated hood system for continuous miners, and the road header dust control system. The status of wet head dust control systems and the challenges facing high seam longwall mines are also presented in the paper. The relative effectiveness of various dust control systems are discussed and the relevant test results are given in the paper. It concludes with a discussion of the progress made and challenges facing the coal mining industry in reducing workers' exposure to respirable dust. 11 refs., 5 figs.

  14. 细度对瘦煤成焦性能的影响%The influence of fineness to the coking properties of lean coal

    Institute of Scientific and Technical Information of China (English)

    白永建

    2016-01-01

    Size grading was conducted to a lean coal sample with relatively high content of inertinite.Coking tests were carried out on the samples of raw coal and products of different size in size grading, followed by coal-blending coking tests with a fat coal sample.The results have showed that the coal qualities changed during the size grading and that higher coal qualities were found of the products of smaller size. Higher coking properties were found of cokes derived from lean coal of smaller size, especially coke strength after reaction (CSR), both in the coking tests of single coal and blending coal.%选择惰质组含量相对较高的瘦煤样品进行粒度分级,对原样及各粒级样品进行炼焦实验,并选择某肥煤样品与之进行配煤炼焦实验。结果表明:筛分会导致瘦煤的煤质出现变化,粒度小的样品其综合煤质特征较好;无论是单种煤成焦实验还是配煤成焦实验,以小粒度瘦煤为主的配煤方案所制备的焦炭质量较好,尤其焦炭反应后强度 CSR 有较大提升。

  15. Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals

    Energy Technology Data Exchange (ETDEWEB)

    Kloosterman, Jeff

    2012-12-31

    Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baseline CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.

  16. Fireside Corrosion Behavior of HVOF and Plasma-Sprayed Coatings in Advanced Coal/Biomass Co-Fired Power Plants

    Science.gov (United States)

    Hussain, T.; Dudziak, T.; Simms, N. J.; Nicholls, J. R.

    2013-06-01

    This article presents a systematic evaluation of coatings for advanced fossil fuel plants and addresses fireside corrosion in coal/biomass-derived flue gases. A selection of four candidate coatings: alloy 625, NiCr, FeCrAl and NiCrAlY were deposited onto superheaters/reheaters alloy (T91) using high-velocity oxy-fuel (HVOF) and plasma spraying. A series of laboratory-based fireside corrosion exposures were carried out on these coated samples in furnaces under controlled atmosphere for 1000 h at 650 °C. The tests were carried out using the "deposit-recoat" test method to simulate the environment that was anticipated from air-firing 20 wt.% cereal co-product mixed with a UK coal. The exposures were carried out using a deposit containing Na2SO4, K2SO4, and Fe2O3 to produce alkali-iron tri-sulfates, which had been identified as the principal cause of fireside corrosion on superheaters/reheaters in pulverized coal-fired power plants. The exposed samples were examined in an ESEM with EDX analysis to characterize the damage. Pre- and post-exposure dimensional metrologies were used to quantify the metal damage in terms of metal loss distributions. The thermally sprayed coatings suffered significant corrosion attack from a combination of aggressive combustion gases and deposit mixtures. In this study, all the four plasma-sprayed coatings studied performed better than the HVOF-sprayed coatings because of a lower level of porosity. NiCr was found to be the best performing coating material with a median metal loss of ~87 μm (HVOF sprayed) and ~13 μm (plasma sprayed). In general, the median metal damage for coatings had the following ranking (in the descending order: most to the least damage): NiCrAlY > alloy 625 > FeCrAl > NiCr.

  17. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide emissions from coal-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Sorge, J.N.; Larrimore, C.L.; Slatsky, M.D.; Menzies, W.R.; Smouse, S.M.; Stallings, J.W.

    1997-12-31

    This paper discusses the technical progress of a US Department of Energy Innovative Clean Coal Technology project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The primary objectives of the demonstration is to determine the long-term NOx reduction performance of advanced overfire air (AOFA), low NOx burners (LNB), and advanced digital control optimization methodologies applied in a stepwise fashion to a 500 MW boiler. The focus of this paper is to report (1) on the installation of three on-line carbon-in-ash monitors and (2) the design and results to date from the advanced digital control/optimization phase of the project.

  18. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide emissions from coal-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Sorge, J.N. [Southern Co. Services, Inc., Birmingham, AL (United States); Menzies, B. [Radian Corp., Austin, TX (United States); Smouse, S.M. [USDOE Pittsburgh Energy Technology Center, PA (United States); Stallings, J.W. [Electric Power Research Inst., Palo Alto, CA (United States)

    1995-09-01

    Technology project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide NOx emissions from coal-fired boilers. The primary objective of the demonstration is to determine the long-term NOx reduction performance of advanced overfire air (AOFA), low NOx burners (LNB), and advanced digital control/optimization methodologies applied in a stepwise fashion to a 500 MW boiler. The focus of this paper is to report (1) on the installation of three on-line carbon-in-ash monitors and (2) the design and results to date from the advanced digital control/optimization phase of the project.

  19. Proceedings of the joint contractors meeting: FE/EE Advanced Turbine Systems conference FE fuel cells and coal-fired heat engines conference

    Energy Technology Data Exchange (ETDEWEB)

    Geiling, D.W. [ed.

    1993-08-01

    The joint contractors meeting: FE/EE Advanced Turbine Systems conference FEE fuel cells and coal-fired heat engines conference; was sponsored by the US Department of Energy Office of Fossil Energy and held at the Morgantown Energy Technology Center, P.O. Box 880, Morgantown, West Virginia 26507-0880, August 3--5, 1993. Individual papers have been entered separately.

  20. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, January--March 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    Accomplishments for the past quarter are briefly described for the following areas of research: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale and tar sand researches cover processing studies. Coal research includes: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology covers: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin tight gas sands; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of naturally and artificially matured kerogens; and development of an effective method for the clean-up of natural gas.

  1. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, October--December 1992

    Energy Technology Data Exchange (ETDEWEB)

    Speight, J.G.

    1992-12-31

    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.

  2. Applicability of a dense-medium cyclone and Vorsyl separator for upgrading non-coking coal fines for use as a blast furnace injection fuel

    Energy Technology Data Exchange (ETDEWEB)

    A.K. Majumder; H. Shah; S. Choubey; J.P. Barnwal; A.K. Kundu; P.S. Dhillon [Advanced Materials and Processes Research Institute, Bhopal (India)

    2009-01-15

    Replacement of metallurgical coke by high injection rates of thermal coal into the blast furnace is an important technology as it reduces the cost of hot metals significantly. However, one of the main problems that prevents the use of thermal coals is their high mineral-matter contents. Although, the ash content of coals to be injected in a blast furnace should be as low as possible, a maximum of 16% ash is acceptable. A non-coking coal sample from Chhattisgarh area, India, having a feed ash content of around 27% was collected for beneficiation studies to a grade acceptable for the injection purposes. A series of experiments were conducted in a 76-mm diameter dense-medium cyclone (DMC) and a Vorsyl separator (VS). It is observed that a clean coal having around 16% ash can be produced using both the cyclones if the variables are properly optimized. Further, it is observed that at the same ash level the yield of clean coal was 5%-6% more in VS than in DMC. It has also been demonstrated that at the same ash level, the magnetite medium stability in a VS was better than a DMC. 4 refs.

  3. Advanced treatment of biologically pretreated coal gasification wastewater by a novel integration of heterogeneous Fenton oxidation and biological process.

    Science.gov (United States)

    Xu, Peng; Han, Hongjun; Zhuang, Haifeng; Hou, Baolin; Jia, Shengyong; Xu, Chunyan; Wang, Dexin

    2015-04-01

    Laboratorial scale experiments were conducted in order to investigate a novel system integrating heterogeneous Fenton oxidation (HFO) with anoxic moving bed biofilm reactor (ANMBBR) and biological aerated filter (BAF) process on advanced treatment of biologically pretreated coal gasification wastewater (CGW). The results indicated that HFO with the prepared catalyst (FeOx/SBAC, sewage sludge based activated carbon (SBAC) which loaded Fe oxides) played a key role in eliminating COD and COLOR as well as in improving the biodegradability of raw wastewater. The surface reaction and hydroxyl radicals (OH) oxidation were the mechanisms for FeOx/SBAC catalytic reaction. Compared with ANMBBR-BAF process, the integrated system was more effective in abating COD, BOD5, total phenols (TPs), total nitrogen (TN) and COLOR and could shorten the retention time. Therefore, the integrated system was a promising technology for engineering applications.

  4. [Engineering development of advanced coal-fired low-emission boiler systems]. Technical progress report, October--December 1995

    Energy Technology Data Exchange (ETDEWEB)

    Wesnor, J.D.; Bakke, E. [ABB Environmental Systems, Birmingham, AL (United States); Bender, D.J.; Kaminski, R.S. [Raytheon Engineers and Constructors, Inc., Philadelphia, PA (United States)

    1995-12-31

    The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emisssion boiler systems. The primary objectives are: NO{sub x} emissions, lb/million Btu; SO{sub 2} emissions, lb/million Btu; particulate emissions, lb/million Btu; and net plant efficiency, not less than 42%. The secondary objectives are: improved ash disposability; reduced waste generation; and reduced air toxics emissions. Accomplishments to date are summarized for the following tasks: task 1, project planning and management; task 7, component development and optimization; task 8, preliminary POC test facility design; task 9, subsystem test design and plan; task 10, subsystem test unit construction; and task 11, subsystem test operation and evaluation.

  5. THE SCALE-UP OF LARGE PRESSURIZED FLUIDIZED BEDS FOR ADVANCED COAL-FIRED POWER PROCESSES

    Energy Technology Data Exchange (ETDEWEB)

    Leon R. Glicksman; Michael Louge; Hesham F. Younis; Richard Tan; Mathew Hyre; Mark Torpey

    2003-11-24

    This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor an agency thereof, nor any of the their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, A combined-cycle High Performance Power System (HIPPS) capable of overall cycle efficiencies approaching 50% has been proposed and designed by Foster Wheeler Development Corporation (FWDC). A pyrolyzer in the first stage of the HIPPS process converts a coal feedstock into fuel gas and char at an elevated pressure of 1.4 Map. (206 psia) and elevated temperature of 930 C (1700 F). The generated char serves as the feedstock for a Pulverized Coal (PC) boiler operating at atmospheric pressure, and the fuel gas is directly fired in a gas turbine. The hydrodynamic behavior of the pyrolyzer strongly influences the quality of both the fuel gas and the generated char, the energy split between the gas turbine and the steam turbine, and hence the overall efficiency of the system. By utilizing a simplified set of scaling parameters (Glicksman et al.,1993), a 4/7th labscale cold model of the pyrolyzer operating at ambient temperature and pressure was constructed and tested. The scaling parameters matched include solid to gas density ratio, Froude number, length to diameter ratio; dimensionless superficial gas velocity and solid recycle rate, particle sphericity and particle size distribution (PSD).

  6. Ninth annual coal preparation, utilization, and environmental control contractors conference: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    Papers are grouped under the following sessions: compliance technology; high-efficiency preparation; characterization; advanced technologies; alternative fuels; coal utilization; industrial/commercial combustor development; combustion; superclean emission systems; carbon dioxide recovery and reuse; air toxics and fine particulates; air toxics sampling and analysis workshop; and combined poster session. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  7. Upgraded Coal Interest Group

    Energy Technology Data Exchange (ETDEWEB)

    Evan Hughes

    2009-01-08

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  8. Coal char fragmentation during pulverized coal combustion

    Energy Technology Data Exchange (ETDEWEB)

    Baxter, L.L.

    1995-07-01

    A series of investigations of coal and char fragmentation during pulverized coal combustion is reported for a suite of coals ranging in rank from lignite to low-volatile (lv) bituminous coal under combustion conditions similar to those found in commercial-scale boilers. Experimental measurements are described that utilize identical particle sizing characteristics to determine initial and final size distributions. Mechanistic interpretation of the data suggest that coal fragmentation is an insignificant event and that char fragmentation is controlled by char structure. Chars forming cenospheres fragment more extensively than solid chars. Among the chars that fragment, large particles produce more fine material than small particles. In all cases, coal and char fragmentation are seen to be sufficiently minor as to be relatively insignificant factors influencing fly ash size distribution, particle loading, and char burnout.

  9. 谱分解和C3相干联合识别煤层小断层研究%Joint technique of spectral decomposition and C3 coherence to detect fine faults of coal bed

    Institute of Scientific and Technical Information of China (English)

    曾凡盛; 王兴春; 陈同俊

    2013-01-01

    According to coal seismic data, C3 coherent technique has good detectability of coal bed's fine faults, but the results is easy affected by random noise. On the other hand, the Spectral Decomposition of S-Transform can improve the resolution of seismic data and suppress random noise. So we combined them together and formed a new technology to make a better interpretation of coal bed's faults. In order to validate the feasibility of this technology, we utilized both forward modeling sections and actual 3D seismic data. At first, we established a geological model containing a single coal bed, and obtained its forward modeling section. After that, 10% random noise was added into this section, and we achieved a new section containing white noise. Then, C3 coherences along coal bed's reflection of all sections, including seismic sections and their ISO frequency sections, were extracted along coal bed. By comparing the C3 coherences of forward modeling section and its ISO-frequency section, we found that the interpreted fine faults of coal bed from ISO-frequency section have higher reliability and precision than normal seismic section. Comparatively to seismic section containing white noise, the detected fine faults from its ISO-frequency section with middle-high frequency were not seriously affected by random noise, and basically avoided the false anomalies of C3 coherence. After applied above method to actual 3D seismic data on 15301 workface in Jilin-2 coalmine, we also found that the ISO-frequency section with middle-high frequency has better identifiable ability than normal seismic section in fine faults detecting. That is to say, in relatively simple condition of coal geological structure, fine faults which fault throws are less than 3m are detectable by middle-high ISO-frequency section. By underground validating, the precision and reliability of interpreted fine faults are acceptable and reasonable. On the contrary, when geological conditions of coal

  10. Influences of sodium hexametaphosphate on dispersion of fine montmorillonite in coal flotation%煤泥浮选过程中六偏磷酸钠对蒙脱石分散行为影响

    Institute of Scientific and Technical Information of China (English)

    徐东方; 朱书全; 曹国强; 崔浩然

    2016-01-01

    The influences of montmorillonite on coal flotation and the effects of sodium hexametaphosphate on the dispersion of fine clay mineral in coal flotation were investigated by wet contact angle and zeta potential measurement.Based on the theoretical calculation of EDLVO,the mechanism of montmorillonite and coal flotation in the presence of dispersant was analyzed.The results show that montmorillonite significantly inhibites coal flotation,and lower the combustible recovery of clean coal from 44.11% to 11.68%.Sodium hexametaphosphate can improve the performance of flotation by increasing 2 percentage of the combustible recovery.By adhering to the surface of coal particles and montmorillonite mineral particles,sodium hexametaphosphate increases the absolute value of zeta potential of the mineral to enhance the electrostatic repulsion,and it improves the hydrophilic polarization effect,strengthening the hydrophilic repulsion.Moreover,long-chain molecules formed from sodium hexametaphosphate hydrolysis adsorb on the particle surface,generating dimensional stabilization effect and increasing the steric hindrance when the particles approach to each other.%通过测定润湿接触角和Zeta电位分析了蒙脱石颗粒对煤泥浮选的作用,考察了六偏磷酸钠对煤和蒙脱石浮选行为的影响.依据扩展DLVO理论的计算,分析了分散剂影响煤和蒙脱石浮选行为的作用机理.结果表明:蒙脱石颗粒严重抑制了煤泥浮选,使精煤可燃体回收率从44.11%降至11.68%;六偏磷酸钠可改善浮选效果,使精煤可燃体回收率提高2个百分点;六偏磷酸钠增大煤和蒙脱石颗粒表面电位绝对值,从而提高颗粒间静电斥能,同时六偏磷酸钠附着在煤颗粒和蒙脱石颗粒表面,增强颗粒间的亲水作用能,并且六偏磷酸钠水解形成的长链分子吸附于颗粒表面后,使颗粒相互靠近时产生较强的空间稳定化作用,增大颗粒之间的空间斥力.

  11. Clean coal technologies market potential

    Energy Technology Data Exchange (ETDEWEB)

    Drazga, B. (ed.)

    2007-01-30

    Looking at the growing popularity of these technologies and of this industry, the report presents an in-depth analysis of all the various technologies involved in cleaning coal and protecting the environment. It analyzes upcoming and present day technologies such as gasification, combustion, and others. It looks at the various technological aspects, economic aspects, and the various programs involved in promoting these emerging green technologies. Contents: Industry background; What is coal?; Historical background of coal; Composition of coal; Types of coal; Environmental effects of coal; Managing wastes from coal; Introduction to clean coal; What is clean coal?; Byproducts of clean coal; Uses of clean coal; Support and opposition; Price of clean coal; Examining clean coal technologies; Coal washing; Advanced pollution control systems; Advanced power generating systems; Pulverized coal combustion (PCC); Carbon capture and storage; Capture and separation of carbon dioxide; Storage and sequestration of carbon dioxide; Economics and research and development; Industry initiatives; Clean Coal Power Initiative; Clean Coal Technology Program; Coal21; Outlook; Case Studies.

  12. Coal slurry - a problem of the brown coal industry

    Energy Technology Data Exchange (ETDEWEB)

    Guenther, H.; Hielscher, R.; Mohry, J.

    1983-01-01

    Technological and economic aspects are examined for processing coal-containing waste water from brown coal preparation plants in the German Democratic Republic. In 1979, 106.8 Mm/sup 3/ of coal slurry were produced by the GDR brown coal industry, with a coal fine content ranging between 7.8 g/l and 20.4 g/l. This amounts to 2.6 Mt/y of coal which is 1% of the annual brown coal production. Technological variants of processing and utilizing coal slurry are discussed. At a number of major coal preparation plants, coal slurry is flushed into sedimentation lakes. After a 2 to 3 year drying period, a 6 to 10 m thick layer of coal is recovered. Technologies of coal slurry processing with the aim of recovering coal fines are enumerated. Equipment for these processes include, filters, centrifuges, dryers, etc. Recovered coal can be used as fuel or processed into fertilizer in combination with fly ash and other waste products. 12 references.

  13. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 1, Final technical report, October 1, 1991--September 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., (United States); Gutterman, C. [Foster Wheeler Development Corp., Livingston, NJ (United States); Chander, S. [Pennsylvania State Univ., (United States)

    1994-12-31

    The overall objective of this project was to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrated coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. Heterofunctional solvents were the most effective in swelling coals. Also solvent blends such as isopropanol/water were more effective than pure solvents alone. Impregnating slurry catalysts simultaneously during coal swelling showed that better uptake was achieved with nonswelling solvent and higher impregnation temperature. Some enhancement in initial coal conversion was seen liquefying SO{sub 2}-treated Black Thunder coal with slurry catalysts, and also when hydrogen donor liquefaction solvents were used. Noncatalytic reactions showed no benefit from SO{sub 2} treatment. Coupling coal swelling and SO{sub 2} treatment with slurry catalysts was also not beneficial, although high conversion was seen with continuous operation and long residence time, however, similar high conversion was observed with untreated coal. SO{sub 2} treatment is not economically attractive unless it provides about 17% increase in coal reactivity. In most cases, the best results were obtained when the coal was untreated and the slurry catalyst was added directly into the reactor. Foster Wheeler`s ASCOT process had better average liquid yields than either Wilsonville`s vacuum tower/ROSE combination or delayed coking process. This liquid product also had good quality.

  14. Advanced CO{sub 2} Capture Technology for Low Rank Coal IGCC System

    Energy Technology Data Exchange (ETDEWEB)

    Alptekin, Gokhan

    2013-09-30

    The overall objective of the project is to demonstrate the technical and economic viability of a new Integrated Gasification Combined Cycle (IGCC) power plant designed to efficiently process low rank coals. The plant uses an integrated CO{sub 2} scrubber/Water Gas Shift (WGS) catalyst to capture over90 percent capture of the CO{sub 2} emissions, while providing a significantly lower cost of electricity (COE) than a similar plant with conventional cold gas cleanup system based on SelexolTM technology and 90 percent carbon capture. TDA’s system uses a high temperature physical adsorbent capable of removing CO{sub 2} above the dew point of the synthesis gas and a commercial WGS catalyst that can effectively convert CO in The overall objective of the project is to demonstrate the technical and economic viability of a new Integrated Gasification Combined Cycle (IGCC) power plant designed to efficiently process low rank coals. The plant uses an integrated CO{sub 2} scrubber/Water Gas Shift (WGS) catalyst to capture over90 percent capture of the CO{sub 2} emissions, while providing a significantly lower cost of electricity (COE) than a similar plant with conventional cold gas cleanup system based on SelexolTM technology and 90 percent carbon capture. TDA’s system uses a high temperature physical adsorbent capable of removing CO{sub 2} above the dew point of the synthesis gas and a commercial WGS catalyst that can effectively convert CO in bituminous coal the net plant efficiency is about 2.4 percentage points higher than an Integrated Gasification Combined Cycle (IGCC) plant equipped with SelexolTM to capture CO{sub 2}. We also previously completed two successful field demonstrations: one at the National Carbon Capture Center (Southern- Wilsonville, AL) in 2011, and a second demonstration in fall of 2012 at the Wabash River IGCC plant (Terra Haute, IN). In this project, we first optimized the sorbent to catalyst ratio used in the combined WGS and CO{sub 2} capture

  15. 基于EDS的煤中微细粒矿物相分布研究%Research on phase distribution of coal fine minerals based on energy disperse spectroscopy

    Institute of Scientific and Technical Information of China (English)

    于冰; 卢兆林; 王帅; 王震威; 于建勇

    2013-01-01

    Fine minerals mostly distribute in the organism of coal in the form of particulate,dissemination and irregular fine granular.The difficulty of mineral phase analysis,mineral formation time and the relation of organic matter are closely related to each other.The premise of selecting and establishing the analysis method is to divide the mineral phase boundaries.This paper presents a method which quantitatively combines low vaccum secondary electron image of scanning electron microscope (SEM),backscattered electron image technology and surface distribution and phase distribution of energy disperse spectroscopy (EDS) to assay the composition of the different micro fine granular minerals,phase distribution and the relationship of coal organic matter.The feasibility of distinguishing the type of clay minerals according to the relative content of major oxides in coal is analyzed.%煤中微细粒矿物大多数以微粒状、浸染状或不规则状细粒分布于有机基体中,矿物的相分析难度与矿物质形成时间以及与有机质的形成关系密切相关,能够准确划分矿物相的相界是选择和建立分析方法的前提.本文提出了一种采用扫描电镜(SEM)低真空二次电子像技术、背散射电子像技术结合能谱仪(EDS)面分布、相分布技术相结合的方法,来定量测定煤中不同微细粒矿物的组成、相分布以及与煤有机质的结构关系;分析了依据EDS获取粘土矿物主要氧化物相对含量数据来判别粘土矿物类型的可行性.

  16. Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems

    Energy Technology Data Exchange (ETDEWEB)

    1990-12-01

    The major objectives of the joint SCS/DOE study of air-blown gasification power plants with hot gas cleanup are to: (1) Evaluate various power plant configurations to determine if an air-blown gasification-based power plant with hot gas cleanup can compete against pulverized coal with flue gas desulfurization for baseload expansion at Georgia Power Company's Plant Wansley; (2) determine if air-blown gasification with hot gas cleanup is more cost effective than oxygen-blown IGCC with cold gas cleanup; (3) perform Second-Law/Thermoeconomic Analysis of air-blown IGCC with hot gas cleanup and oxygen-blown IGCC with cold gas cleanup; (4) compare cost, performance, and reliability of IGCC based on industrial gas turbines and ISTIG power island configurations based on aeroderivative gas turbines; (5) compare cost, performance, and reliability of large (400 MW) and small (100 to 200 MW) gasification power plants; and (6) compare cost, performance, and reliability of air-blown gasification power plants using fluidized-bed gasifiers to air-blown IGCC using transport gasification and pressurized combustion.

  17. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report, July--September 1992

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., AL (United States); Gutterman, C. [Foster Wheeler Development Corp., Livingston, NJ (United States); Chander, S. [Pennsylvania State Univ., University Park, PA (United States)

    1992-12-31

    The experimental study of coal swelling ratios have been determined with a wide variety of solvents. Only marginal levels of coal swelling were observed for the hydrocarbon solvents, but high levels were found with solvents having heteroatom functionality. Blends were superior to pure solvents. The activity of various catalyst precursors for pyrene hydrogenation and coal conversion was measured. Higher coal conversions were observed for the S0{sub 2}-treated coal than the raw coal, regardless of catalyst type. Coal conversions were highest for Molyvan-L, molybdenum naphthenate, and nickel octoate, respectively. Bottoms processing consists of a combination of the ASCOT process coupling solvent deasphalting with delayed coking. Initial results indicate that a blend of butane and pentane used near the critical temperature of butane is the best solvent blend for producing a yield/temperature relationship of proper sensitivity and yet retaining an asphalt phase of reasonable viscosity. The literature concerning coal swelling, both alone and in combination with coal liquefaction, and the use of dispersed or unsupported catalysts in coal liquefaction has been updated.

  18. Adding value to coal. Conference documentation and delegate information

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-11-01

    Papers discussed the economic and environmental benefits of coal preparation and the latest development of coal preparation technology. This included the recovery and processing of coal fines, and coal blending. All papers have been abstracted separately on the IEA Coal Research CD-ROM.

  19. The advanced supercritical 700 C pulverised coal-fired power plant

    Energy Technology Data Exchange (ETDEWEB)

    Kjaer, S.; Kristensen, P. [Tech-wise A/S, Fredericia (Denmark); Klauke, F. [Babcock Borsig Power Energy, Oberhausen (Germany); Vanstone, R. [ALSTOM Power UK Ltd., Rugby (United Kingdom); Zeijseink, A. [KEMA Nederland B.V., Arnhem (Netherlands); Weissinger, G. [ALSTOM Power Boilers GmbH, Stuttgart (Germany); Meier, J. [ALSTOM Power Ltd., Baden (Switzerland); Blum, R. [Elsam A/S, Fredericia (Denmark); Wieghardt, K. [Siemens, Muelheim (Germany)

    2002-07-01

    This paper presents the joint efforts of a large European group of manufacturers, utilities and institutes co-operating in a phased long-term project named 'Advanced 700 C PF Power Plant'. Net efficiencies of more than 50% will be reached through development of a super critical steam cycle operating at maximum steam temperatures in the range of 700 C. The principal efforts are based on development of creep resistant - and expensive - Nickel-based materials. (orig.) [German] Der Beitrag beschreibt die gemeinsamen Anstrengungen einer grossen Gruppe europaeischer Kraftwerksbauer, Kraftwerksbetreiber und Institute, die in einem gestuften langfristigen Projekt mit dem Titel 'Advanced 700 C PF Power Plant' zusammenarbeiten. Nettowirkungsgrade von mehr als 50% sollen durch die Entwicklung eines ueberkritischen Dampfkreislaufs erreicht werden, der mit maximalen Dampftemperaturen in der Groessenordnung von 700 C arbeitet. Die Hauptbemuehungen gelten der Entwicklung von kriechfesten und aufwaendigen Werkstoffen auf Nickelbasis, die als Superlegierungen bezeichnet werden. (orig.)

  20. Development of advanced NO sub x control concepts for coal-fired utility boilers

    Energy Technology Data Exchange (ETDEWEB)

    Newhall, J.; England, G.; Seeker, W.R.

    1991-12-23

    Energy and Environmental Research Corporation (EER) is currently conducting a test program to develop an advanced NO{sub x} control method utilizing reburning, promoted selective noncatalytic agent injection. The study will consist of fundamental and process testing over a large enough range of operating parameters to significantly reduce the risk of a full scale demonstration project. The test plan for the fundamental testing phase of the program is presented here.

  1. Intelligent Control via Wireless Sensor Networks for Advanced Coal Combustion Systems

    Energy Technology Data Exchange (ETDEWEB)

    Aman Behal; Sunil Kumar; Goodarz Ahmadi

    2007-08-05

    Numerical Modeling of Solid Gas Flow, System Identification for purposes of modeling and control, and Wireless Sensor and Actor Network design were pursued as part of this project. Time series input-output data was obtained from NETL's Morgantown CFB facility courtesy of Dr. Lawrence Shadle. It was run through a nonlinear kernel estimator and nonparametric models were obtained for the system. Linear and first-order nonlinear kernels were then utilized to obtain a state-space description of the system. Neural networks were trained that performed better at capturing the plant dynamics. It is possible to use these networks to find a plant model and the inversion of this model can be used to control the system. These models allow one to compare with physics based models whose parameters can then be determined by comparing them against the available data based model. On a parallel track, Dr. Kumar designed an energy-efficient and reliable transport protocol for wireless sensor and actor networks, where the sensors could be different types of wireless sensors used in CFB based coal combustion systems and actors are more powerful wireless nodes to set up a communication network while avoiding the data congestion. Dr. Ahmadi's group studied gas solid flow in a duct. It was seen that particle concentration clearly shows a preferential distribution. The particles strongly interact with the turbulence eddies and are concentrated in narrow bands that are evolving with time. It is believed that observed preferential concentration is due to the fact that these particles are flung out of eddies by centrifugal force.

  2. Advanced treatment of biologically pretreated coal gasification wastewater by a novel heterogeneous Fenton oxidation process.

    Science.gov (United States)

    Zhuang, Haifeng; Han, Hongjun; Ma, Wencheng; Hou, Baolin; Jia, Shengyong; Zhao, Qian

    2015-07-01

    Sewage sludge from a biological wastewater treatment plant was converted into sewage sludge based activated carbon (SBAC) with ZnCl2 as activation agent, which was used as a support for ferric oxides to form a catalyst (FeOx/SBAC) by a simple impregnation method. The new material was then used to improve the performance of Fenton oxidation of real biologically pretreated coal gasification wastewater (CGW). The results indicated that the prepared FeOx/SBAC significantly enhanced the pollutant removal performance in the Fenton process, so that the treated wastewater was more biodegradable and less toxic. The best performance was obtained over a wide pH range from 2 to 7, temperature 30°C, 15 mg/L of H2O2 and 1g/L of catalyst, and the treated effluent concentrations of COD, total phenols, BOD5 and TOC all met the discharge limits in China. Meanwhile, on the basis of significant inhibition by a radical scavenger in the heterogeneous Fenton process as well as the evolution of FT-IR spectra of pollutant-saturated FeOx/BAC with and without H2O2, it was deduced that the catalytic activity was responsible for generating hydroxyl radicals, and a possible reaction pathway and interface mechanism were proposed. Moreover, FeOx/SBAC showed superior stability over five successive oxidation runs. Thus, heterogeneous Fenton oxidation of biologically pretreated CGW by FeOx/SBAC, with the advantages of being economical, efficient and sustainable, holds promise for engineering application.

  3. Engineering development of advanced coal-fired low-emission boiler systems. Technical progress report No. 15, April 15 1996--June 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-08-19

    The Pittsburgh Energy Technology center of the US Department of Energy (DOE) has contracted with Combustion Engineering; Inc. (ABB CE) to perform work on the {open_quotes}Engineering Development of Advanced Coal-Fired Low-Emission Boiler Systems{close_quote} Project and has authorized ABB CE to complete Phase I on a cost-reimbursable basis and Phases II and III on a cost-share basis.

  4. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    Energy Technology Data Exchange (ETDEWEB)

    Andrew Jackura; John Groppo; Thomas Robl

    2006-12-31

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The market study for the products of the processing plant (Subtask 1.6), conducted by Cemex, is reported herein. The study incorporated simplifying assumptions and focused only on pozzolan and ultra fine fly ash (UFFA). It found that the market for pozzolan in the Ghent area was oversupplied, with resultant poor pricing structure. Reachable export markets for the Ghent pozzolan market were mostly locally served with the exception of Florida. It was concluded that a beneficiated material for that market may be at a long term disadvantage. The market for the UFFA was more complex as this material would compete with other beneficiated ash and potential metakaolin and silica fume as well. The study concluded that this market represented about 100,000 tons of sales per year and, although lucrative, represented a widely dispersed niche market.

  5. An analysis of markets for small-scale, advanced coal-combustion technology in Spain, Italy, and Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Placet, M.; Gerry, P.A.; Kenski, D.M.; Kern, D.M.; Nehring, J.L.; Szpunar, C.B.

    1989-09-01

    This report discusses the examination of potential overseas markets for using small-scale, US-developed, advanced coal-combustion technologies (ACTs). In previous work, member countries of the Organization for Economic Cooperation and Development (OECD) were rated on their potential for using ACTs through a comprehensive screening methodology. The three most promising OECD markets were found to be Spain, Italy, and Turkey. This report provides in-depth analyses of these three selected countries. First, it addresses changes in the European Community with particular reference to the 1992 restructuring and its potential effect on the energy situation in Europe, specifically in the three subject countries. It presents individual country studies that examine demographics, economics, building infrastructures, and energy-related factors. Potential niches for ACTs are explored for each country through regional analyses. Marketing channels, strategies, and the trading environments in each country are also discussed. The information gathered indicates that Turkey is a most promising market, Spain is a fairly promising market, and Italy appears to be a somewhat limited market for US ACTs. 76 refs., 16 figs., 14 tabs.

  6. An advanced anaerobic biofilter with effluent recirculation for phenol removal and methane production in treatment of coal gasification wastewater.

    Science.gov (United States)

    Li, Yajie; Tabassum, Salma; Zhang, Zhenjia

    2016-09-01

    An advanced anaerobic biofilter (AF) was introduced for the treatment of coal gasification wastewater (CGW), and effluent recirculation was adopted to enhance phenol removal and methane production. The results indicated that AF was reliable in treating diluted CGW, while its efficiency and stability were seriously reduced when directly treating raw CGW. However, its performance could be greatly enhanced by effluent recirculation. Under optimal effluent recirculation of 0.5 to the influent, concentrations of chemical oxygen demand (COD) and total phenol in the effluent could reach as low as 234.0 and 14.2mg/L, respectively. Also, the rate of methane production reached 169.0mLCH4/L/day. Though CGW seemed to restrain the growth of anaerobic microorganisms, especially methanogens, the inhibition was temporary and reversible, and anaerobic bacteria presented strong tolerance. The activities of methanogens cultivated in CGW could quickly recover on feeding with glucose wastewater (GW). However, the adaptability of anaerobic bacteria to the CGW was very poor and the activity of methanogens could not be improved by long-term domestication. By analysis using the Haldane model, it was further confirmed that high effluent recirculation could result in high activity for hydrolytic bacteria and substrate affinity for toxic matters, but only suitable effluent recirculation could result in high methanogenic activity.

  7. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, April--June 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    Progress made in five areas of research is described briefly. The subtask in oil shale research is on oil shale process studies. For tar sand the subtask reported is on process development. Coal research includes the following subtasks: Coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes the following: Advanced process concepts; advanced mitigation concepts; oil and gas technology. Jointly sponsored research includes: Organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sup 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; characterization of petroleum residua; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process;NMR analysis of samples from the ocean drilling program; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of Mowry formation shale from different sedimentary basins; solid-state NMR analysis of naturally and artificially matured kerogens; and development of effective method for the clean-up of natural gas.

  8. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report, April--June 1992

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., AL (United States); Gutterman, C. [Foster Wheeler Development Corp., Livingston, NJ (United States); Chander, S. [Pennsylvania State Univ., University Park, PA (United States)

    1992-08-26

    Research in this project centers upon developing a new approach to the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates all aspects of the coal liquefaction process including coal selection, pretreatment, coal swelling with catalyst impregnation, coal liquefaction experimentation, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. The project is being carried out under contract to the United States Department of Energy. On May 28, 1992, the Department of Energy authorized starting the experimental aspects of this projects; therefore, experimentation at Amoco started late in this quarterly report period. Research contracts with Auburn University, Pennsylvania State University, and Foster Wheeler Development Corporation were signed during June, 1992, so their work was just getting underway. Their work will be summarized in future quarterly reports. A set of coal samples were sent to Hazen Research for beneficiation. The samples were received and have been analyzed. The literature search covering coal swelling has been up-dated, and preliminary coal swelling experiments were carried out. Further swelling experimentation is underway. An up-date of the literature on the liquefaction of coal using dispersed catalysts is nearing completion; it will be included in the next quarterly report.

  9. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 2 -- Jointly sponsored research program. Final report, October 1986--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Smith, V.E.

    1994-09-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  10. Coal Combustion Science

    Energy Technology Data Exchange (ETDEWEB)

    Hardesty, D.R. (ed.); Fletcher, T.H.; Hurt, R.H.; Baxter, L.L. (Sandia National Labs., Livermore, CA (United States))

    1991-08-01

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. Specific tasks for this activity include: (1) coal devolatilization - the objective of this risk is to characterize the physical and chemical processes that constitute the early devolatilization phase of coal combustion as a function of coal type, heating rate, particle size and temperature, and gas phase temperature and oxidizer concentration; (2) coal char combustion -the objective of this task is to characterize the physical and chemical processes involved during coal char combustion as a function of coal type, particle size and temperature, and gas phase temperature and oxygen concentration; (3) fate of mineral matter during coal combustion - the objective of this task is to establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distribution of mineral species in the unreacted coal, and the local gas temperature and composition.

  11. Engineer exchanging project (coal mine technology field) in fiscal 1999. International information exchanging project (advance survey on Russia); 1999 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) kokusai koryu jigyo. Jizen chosa (Roshia)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This advance survey on Russia has performed visiting surveys and information collection at coal related organizations inside Japan and in overseas countries on production technology levels, trends and technology exchange needs in overseas coal producing countries. The project is intended to serve for improvement in the contents of and smooth execution of the engineer exchange project in the 'coal mine technology field. It was carried out by expertise people as the site surveys and the engineer reception and exchange surveys. Because of the economic crisis that has hit Russia in 1998, unprofitable coal mines were closed one after another under the coal mine scrap and build policy under the initiative of the World Bank. This situation is giving serious impacts on coal mines in the Far East Russia and the coastal areas. However, the importance of coal as the primary energy source has not been changed at all in the Far East Russia. Thus, the areas have fallen into a situation that they must rely on a great amount of introduced and imported coals as a result of weakening in coal mines in the Far Eastern area on the other hand. This paper reports mainly the situation in which the coal industries in the coastal areas are placed, and the possibilities of technology exchange. (NEDO)

  12. Trends in Global Demonstrations of Carbon Management Technologies to Advance Coal- Based Power Generation With Carbon Capture and Storage

    Science.gov (United States)

    Cohen, K. K.; Plasynski, S.; Feeley, T. J.

    2008-05-01

    conditions with geophysics. Borehole-based technologies include a novel geochemical two-phase reservoir sampler deployed at Otway, and thermal-based measurements at CO2SINK for coupled hydrologic-geochemical reservoir analyses. Seismic, geomechanical, hydrologic, geochemical, and core studies are used in a multidisciplinary approach to assess CO2 trapping and reservoir integrity at In Salah. With estimated lifetime storage of 17 MtCO2 at In Salah, this and other CCS demonstrations provide opportunities to gain commercial experience for advancing coal-based power generation-CCS for carbon management.

  13. Characterization of fine and carbonaceous particles emissions from pelletized biomass-coal blends combustion: Implications on residential crop residue utilization in China

    Science.gov (United States)

    Xu, Yue; Wang, Yan; Chen, Yingjun; Tian, Chongguo; Feng, Yanli; Li, Jun; Zhang, Gan

    2016-09-01

    Bulk biofuel, biomass pellets and pelletized biomass-coal blends were combusted in a typical rural conventional household stove and a high-efficiency stove. Reductions in PM2.5, organic carbon (OC) and elemental carbon (EC) emissions were evaluated by comparing emission factors (EFs) among 19 combinations of biofuel/residential stove types measured using a dilution sampling system. In the low-efficiency stove, the average EFs of PM2.5, OC, and EC of biomass pellets were 2.64 ± 1.56, 0.42 ± 0.36, and 0.30 ± 0.11 g/kg, respectively, significantly lower than those burned in bulk form. EFPM2.5 and EFOC of pelletized biomass combustion in the high-efficiency stove were lower than those of the same biofuel burned in the low-efficiency stove. Furthermore, pelletized corn residue and coal blends burned in the high-efficiency stove could significantly decrease emissions. Compared with the bulk material burned in the low-efficiency stove, the reduction rates of PM2.5, OC and EC from pelletized blends in the high-efficiency stove can reach 84%, 96% and 93%, respectively. If the annually produced corn residues in 2010 had been blended with 10% anthracite coal powder and burnt as pellets, it would have reduced about 82% of PM2.5, 90-96% of OC and 81-92% of EC emission in comparison with burning raw materials in conventional household stoves. Given the low cost, high health benefit and reduction effect on atmospheric pollutants, pelletized blends could be a promising alternative to fossil fuel resources or traditional bulk biofuel.

  14. RESIDUES FROM COAL CONVERSION AND UTILIZATION: ADVANCED MINERALOGICAL CHARACTERIZATION AND DISPOSED BYPRODUCT DIAGENESIS

    Energy Technology Data Exchange (ETDEWEB)

    Gregory J. McCarthy; Dean G. Grier

    2001-01-01

    Prior to the initiation of this study, understanding of the long-term behavior of environmentally-exposed Coal Combustion By-Products (CCBs) was lacking in (among others) two primary areas addressed in this work. First, no method had been successfully applied to achieve full quantitative analysis of the partitioning of chemical constituents into reactive or passive crystalline or noncrystalline compounds. Rather, only semi-quantitative methods were available, with large associated errors. Second, our understanding of the long-term behavior of various CCBs in contact with the natural environment was based on a relatively limited set of study materials. This study addressed these areas with two objectives, producing (1) a set of protocols for fully quantitative phase analysis using the Rietveld Quantitative X-ray Diffraction (RQXRD) method and (2) greater understanding of the hydrologic and geochemical nature of the long-term behavior of disposed and utilized CCBs. The RQXRD technique was initially tested using (1) mixtures of National Institute of Standards and Technology (NIST) crystalline standards, and (2) mixtures of synthetic reagents simulating various CCBs, to determine accuracy and precision of the method, and to determine the most favorable protocols to follow in order to efficiently quantify multi-phase mixtures. Four sets of borehole samples of disposed or utilized CCBs were retrieved and analyzed by RQXRD according to the protocols developed under the first objective. The first set of samples, from a Class F ash settling pond in Kentucky disposed for up to 20 years, showed little mineralogical alteration, as expected. The second set of samples, from an embankment in Indiana containing a mixture of chain-grate (stoker) furnace ash and fluidized bed combustion (FBC) residues, showed formation of the mineral thaumasite, as observed in previously studied exposed FBC materials. Two high-calcium CCBs studied, including a dry-process flue gas desulfurization

  15. Advanced Systems for Preprocessing and Characterizing Coal-Biomass Mixtures as Next-Generation Fuels and Feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Karmis, Michael [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Luttrell, Gerald [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Ripepi, Nino [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Bratton, Robert [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Dohm, Erich [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)

    2014-09-30

    The research activities presented in this report are intended to address the most critical technical challenges pertaining to coal-biomass briquette feedstocks. Several detailed investigations were conducted using a variety of coal and biomass feedstocks on the topics of (1) coal-biomass briquette production and characterization, (2) gasification of coal-biomass mixtures and briquettes, (3) combustion of coal-biomass mixtures and briquettes, and (4) conceptual engineering design and economic feasibility of briquette production. The briquette production studies indicate that strong and durable co-firing feedstocks can be produced by co-briquetting coal and biomass resources commonly available in the United States. It is demonstrated that binderless coal-biomass briquettes produced at optimized conditions exhibit very high strength and durability, which indicates that such briquettes would remain competent in the presence of forces encountered in handling, storage and transportation. The gasification studies conducted demonstrate that coal-biomass mixtures and briquettes are exceptional gasification feedstocks, particularly with regard to the synergistic effects realized during devolatilization of the blended materials. The mixture combustion studies indicate that coal-biomass mixtures are exceptional combustion feedstocks, while the briquette combustion study indicates that the use of blended briquettes reduces NOx, CO2, and CO emissions, and requires the least amount of changes in the operating conditions of an existing coal-fired power plant. Similar results were obtained for the physical durability of the pilot-scale briquettes compared to the bench-scale tests. Finally, the conceptual engineering and feasibility analysis study for a commercial-scale briquetting production facility provides preliminary flowsheet and cost simulations to evaluate the various feedstocks, equipment selection and operating parameters.

  16. Advanced Systems for Preprocessing and Characterizing Coal-Biomass Mixtures as Next-Generation Fuels and Feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Karmis, Michael; Luttrell, Gerald; Ripepi, Nino; Bratton, Robert; Dohm, Erich

    2014-06-30

    The research activities presented in this report are intended to address the most critical technical challenges pertaining to coal-biomass briquette feedstocks. Several detailed investigations were conducted using a variety of coal and biomass feedstocks on the topics of (1) coal-biomass briquette production and characterization, (2) gasification of coal-biomass mixtures and briquettes, (3) combustion of coal-biomass mixtures and briquettes, and (4) conceptual engineering design and economic feasibility of briquette production. The briquette production studies indicate that strong and durable co-firing feedstocks can be produced by co-briquetting coal and biomass resources commonly available in the United States. It is demonstrated that binderless coal-biomass briquettes produced at optimized conditions exhibit very high strength and durability, which indicates that such briquettes would remain competent in the presence of forces encountered in handling, storage and transportation. The gasification studies conducted demonstrate that coal-biomass mixtures and briquettes are exceptional gasification feedstocks, particularly with regard to the synergistic effects realized during devolatilization of the blended materials. The mixture combustion studies indicate that coal-biomass mixtures are exceptional combustion feedstocks, while the briquette combustion study indicates that the use of blended briquettes reduces NO{sub x}, CO{sub 2}, and CO emissions, and requires the least amount of changes in the operating conditions of an existing coal-fired power plant. Similar results were obtained for the physical durability of the pilot-scale briquettes compared to the bench-scale tests. Finally, the conceptual engineering and feasibility analysis study for a commercial-scale briquetting production facility provides preliminary flowsheet and cost simulations to evaluate the various feedstocks, equipment selection and operating parameters.

  17. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    Energy Technology Data Exchange (ETDEWEB)

    John Groppo; Thomas Robl; Robert Rathbone

    2006-06-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The secondary classification testing was concluded using a continuous demonstration-scale lamella classifier that was operated at a feed rate of 0.3 to 1.5 tons/hr. Feed to the secondary classifier was generated by operating the primary classifier at the conditions shown to be effective previously. Samples were taken while the secondary classifier was operated under a variety of conditions in order to determine the range of conditions where the unit could be efficiently operated. Secondary classification was effective for producing an ultra-fine ash (UFA) product. Inclined lamella plates provided an effective settling surface for coarser ash particles and plate spacing was shown to be an important variable. Results showed that the closer the plate spacing, the finer the size distribution of the UFA product. Flotation of the secondary classifier feed provided a lower LOI UFA product (2.5% LOI vs. 4.5% LOI) and a dispersant dosage of 2 to 2.5 g/kg was adequate to provide UFA grade (3.8 to 4.4 {micro}m) and recovery (53 to 68% 5{micro}m recovery). The UFA yield without flotation was {approx}33% and lower ({approx}20%) with flotation. Demonstration plant product evaluations showed that water requirements in mortar were reduced and 100% of control strength was achieved in 28 days for the coarser products followed by further strength gain of up to 130% in 56 days. The highest strengths of 110% of control in 7 days and 140% in 56 days were achieved with the finer products. Mortar air requirements for processed products were essentially the same as those for standard mortar, suggesting that the unburned carbon remaining does not have

  18. COAL OF THE FUTURE (Supply Prospects for Thermal Coal by 2030-2050)

    OpenAIRE

    2007-01-01

    The report, produced by Messrs. Energy Edge Ltd. (the U.K.) for the JRC Institute for Energy, aims at making a techno-economic analysis of novel extraction technologies for coal and their potential contribution to the global coal supply. These novel extraction technologies include: advanced coal mapping techniques, improved underground coal mining, underground coal gasification and utilisation of coalmine methane gas.

  19. New steels for advanced coal fired plant up to 620{degree}C

    Energy Technology Data Exchange (ETDEWEB)

    Metcalfe, E.; Bakker, W.T.; Blum, R.; Bygate, R.P.; Gibbons, T.B.; Hald, J.; Matsuyama, F.; Naoi, H.; Price, S.; Sawaragi, Y. [National Power, Leatherhead (United Kingdom)

    1997-09-01

    There are strong environmental and economic incentives to increase the thermal efficiency of fossil fired power stations, and this has led to a steady increase in steam temperatures and pressures. In addition, the economics of power generation are driving down the price of plant so that advanced technology must be available at reduced installed cost. The key to securing these conditions is the development of high temperature materials, available at an acceptable price, particularly for thick section components in the boiler and turbine. These considerations led to the establishment of a four year EPRI project with partners from Japan, UK, USA and Denmark whose objective was to establish strong 9Cr and 12Cr steels as practical, validated materials for thick section boiler components such as headers and main steam lines. This successful project has developed three strong steels for thick section components for plant operating in the temperature range 565-620{degree}C and two of them, P92 (NF616) and P122(HCM12A), have received ASME Code approval. This project has now entered its second phase with the fabrication of full sized headers which have been installed in the NJV power plant in Denmark. In addition, there is further work on the long term microstructural stability of the steels, and a full sized pressure vessel test under accelerated conditions is about to start. 6 refs., 7 figs., 2 tabs.

  20. Optical Thin Films for Gas Sensing in Advanced Coal Fired Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Ohodnicki, Paul; Brown, Thomas; Baltrus John; Chorpening, Benjamin

    2012-08-09

    Even for existing coal based plants, the opportunity for sensors and controls to improve efficiency is great. A wide range of gas species are of interest for relevant applications. Functional sensor layers for embedded sensing must be compatible with extreme conditions (temperature, pressure, corrosive). Au incorporated metal oxides have been looked at by a number of other authors previously for gas sensing, but have often focused on temperatures below 500{degree}C. Au nanoparticle incorporated metal oxide thin films have shown enhanced gas sensing response. In prior work, we have demonstrated that material systems such as Au nanoparticle incorporated TiO{sub 2} films exhibit a potentially useful optical response to changing gas atmospheres at temperatures up to ~800-850{degree}C. Current work is focused on sputter-deposited Au/TiO{sub 2} films. Au and Ti are multi-layered sputter deposited, followed by a 950{degree}C oxidation step. Increasing Au layer thickness yields larger particles. Interband electronic transitions significantly modify the optical constants of Au as compared to the damped free electron theory. A high temperature oxidation (20%O{sub 2}/N{sub 2}) treatment was performed at 700{degree}C followed by a reduction (4%H{sub 2}/N{sub 2}) treatment to illustrate the shift in both absorption and scattering with exposure to reducing gases. Shift of localized surface plasmon resonance (LSPR) absorption peak in changing gas atmospheres is well documented, but shift in the peak associated with diffuse scattering is a new observation. Increasing Au layer-thickness results in an increase in LSPR absorption and a shift to longer wavelengths. Diffuse scattering associated with the LSPR resonance of Au shows a similar trend with increasing Au thickness. To model the temperature dependence of LSPR, the modification to the plasmon frequency, the damping frequency, and the dielectric constant of the oxide matrix must be accounted for. Thermal expansion of Au causes

  1. 煤基草酸酯路线精细化学品分析%Analysis of fine chemicals based on coal to dimethyl oxalate

    Institute of Scientific and Technical Information of China (English)

    尚如静; 穆仕芳; 魏灵朝; 蒋元力

    2015-01-01

    Recent progress in industrialization of coal to ethylene glycol was outlined, and the diversified development direction of feedstocks and products for ethylene glycol production was discussed. Using indusrial vent gas and import methanol as feedstocks could reduce the costs of investment and product and the operational risk. Combination production of oxalic acid, methyl glycolate, glycolic acid, ethanol and/or oxamide in the coal-based ethylene glycol plants using the dimethyl oxalate hydrogenation technology offered a new way to product diversification, by which the market risk from overcapacity of ethylene glycol could be reduced effectively. Reasonable use of coal to ethylene glycol by-products could reduce the waste of resources and improve the economic effect. The diversified development could make better use of existing equipment, increase the variety of products and enhance the market risk tolerance capability.%对煤基草酸酯制乙二醇产业化现状进行概述,在此基础上分析煤基草酸酯路线制精细化学品发展方向。以工业尾气和进口甲醇为原料,可减少投资费用,降低产品成本和经营风险,增强项目的经济性;煤基草酸酯装置联产草酸、乙醇酸甲酯、乙醇酸、乙醇为产品多元化提供了新的途径,可有效降低乙二醇产能过剩带来的市场风险;合理利用煤基草酸酯制乙二醇副产物,可减小资源浪费,增加企业收益。煤基草酸酯路线精细化学品开发可以高效利用现有装置,丰富产品结构,增强市场抗风险能力。

  2. On the diffusion mechanisms of fine-scale γ′ in an advanced Ni-based superalloy

    Directory of Open Access Journals (Sweden)

    Chen Y.

    2014-01-01

    Full Text Available Size dependent compositional variations for the ordered L12-structure gamma prime (γ′ precipitates in the commercial Ni-based superalloy RR1000 have been investigated using scanning transmission electron microscope (STEM imaging combined with energy-dispersive X-ray (EDX spectroscopy. To address the problem of quantitative compositional determination for nanoscale particles within a metal matrix we have applied a novel electrochemical method to extract individual precipitates. The use of a high-efficiency EDX detector enabled compositional measurements to be obtained for particles with diameters as small as 20 nm with acquisition times of the order of a few minutes. We have studied compositional variations across the different size families of γ′ precipitates within a microstructure generated by slow cooling. Our results demonstrate the importance of kinetic factors for determining the precipitates compositions. In particular, we provide new evidence for the role of aluminium antisite atoms on the low-temperature growth kinetics of fine scale γ′ precipitates. Our findings provide valuable structural data towards improving the accuracy of predicting the microstructural evolution in Ni-based superalloys.

  3. Structural features of a bituminous coal and their changes during low-temperature oxidation and loss of volatiles investigated by advanced solid-state NMR spectroscopy

    Science.gov (United States)

    Mao, J.-D.; Schimmelmann, A.; Mastalerz, Maria; Hatcher, P.G.; Li, Y.

    2010-01-01

    Quantitative and advanced 13C solid-state NMR techniques were employed to investigate (i) the chemical structure of a high volatile bituminous coal, as well as (ii) chemical structural changes of this coal after evacuation of adsorbed gases, (iii) during oxidative air exposure at room temperature, and (iv) after oxidative heating in air at 75 ??C. The solid-state NMR techniques employed in this study included quantitative direct polarization/magic angle spinning (DP/MAS) at a high spinning speed of 14 kHz, cross polarization/total sideband suppression (CP/TOSS), dipolar dephasing, CH, CH2, and CHn selection, 13C chemical shift anisotropy (CSA) filtering, two-dimensional (2D) 1H-13C heteronuclear correlation NMR (HETCOR), and 2D HETCOR with 1H spin diffusion. With spectral editing techniques, we identified methyl CCH 3, rigid and mobile methylene CCH2C, methine CCH, quaternary Cq, aromatic CH, aromatic carbons bonded to alkyls, small-sized condensed aromatic moieties, and aromatic C-O groups. With direct polarization combined with spectral-editing techniques, we quantified 11 different types of functional groups. 1H-13C 2D HETCOR NMR experiments indicated spatial proximity of aromatic and alkyl moieties in cross-linked structures. The proton spin diffusion experiments indicated that the magnetization was not equilibrated at a 1H spin diffusion time of 5 ms. Therefore, the heterogeneity in spatial distribution of different functional groups should be above 2 nm. Recoupled C-H long-range dipolar dephasing showed that the fraction of large charcoal-like clusters of polycondensed aromatic rings was relatively small. The exposure of this coal to atmospheric oxygen at room temperature for 6 months did not result in obvious chemical structural changes of the coal, whereas heating at 75 ??C in air for 10 days led to oxidation of coal and generated some COO groups. Evacuation removed most volatiles and caused a significant reduction in aliphatic signals in its DP

  4. Coal conversion and biomass conversion: Volume 1: Final report on USAID (Agency for International Development)/GOI (Government of India) Alternate Energy Resources and Development Program

    Energy Technology Data Exchange (ETDEWEB)

    Kulkarni, A.; Saluja, J.

    1987-06-30

    The United States Agency for International Development (AID), in joint collaboration with the Government of India (GOI), supported a research and development program in Alternate Energy Resources during the period March 1983 to June 1987. The primary emphasis of this program was to develop new and advanced coal and biomass conversion technologies for the efficient utilization of coal and biomass feedstocks in India. This final ''summary'' report is divided into two volumes. This Report, Volume I, covers the program overview and coal projects and Volume II summarizes the accomplishments of the biomass projects. The six projects selected in the area of coal were: Evaluation of the Freeboard Performance in a Fluidized-Bed Combustor; Scale-up of AFBC boilers; Rheology, Stability and Combustion of Coal-Water Slurries; Beneficiation of Fine Coal in Dense Medium Cyclones; Hot Gas Cleanup and Separation; and Cold Gas Cleanup and Separation.

  5. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, First quarter 1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-31

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

  6. Study on conglutination model for fine moist material during screening

    Institute of Scientific and Technical Information of China (English)

    陈惜明; 邓凡政; 赵跃民; 朱红; 高庆宇

    2002-01-01

    All coal preparation in which fine coal is handled depends to some extent on the wettability of coal surface by water. The content of external water in fine moist material plays significant role on screening. This article probed into the causations why fine moist materials adhere to the screen deck on common vibrator in the process of screening. Although the wetting that results from interactions between the coal surface and water molecules that are determined by the composition of coal matrix (interrelated with coal rank) and heterogeneous constituents such as oxygen function groups, mineral impurities and pores have something to do with adhering, we found that the effect of wettability is not the key causation to agglomeration, in other words, water bridges among particles are the key causation to the fine moist materials adhesion. This paper also shows how the capillary adhesive forces forms and how to calculate and measure these forces.

  7. Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama. Topical report No. 14. Catalyst activity trends in two-stage coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    1984-02-01

    The Two Stage Coal Liquefaction process became operational at Wilsonville in May 1981, with the inclusion of an H-OIL ebullated-bed catalytic reactor. The two stage process was initially operated in a nonintegrated mode and has recently been reconfigurated to fully integrate the thermal and the catalytic stages. This report focuses on catalyst activity trends observed in both modes of operation. A literature review of relevant catalyst screening studies in bench-scale and PDU units is presented. Existing kinetic and deactivation models were used to analyze process data over an extensive data base. Based on the analysis, three separate, application studies have been conducted. The first study seeks to elucidate the dependence of catalyst deactivation rate on type of coal feedstock used. A second study focuses on the significance of catalyst type and integration mode on SRC hydrotreatment. The third study presents characteristic deactivation trends observed in integrated operation with different first-stage thermal severities. In-depth analytical work was conducted at different research laboratories on aged catalyst samples from Run 242. Model hydrogenation and denitrogenation activity trends are compared with process activity trends and with changes observed in catalyst porosimetric properties. The accumulation of metals and coke deposits with increasing catalyst age, as well as their distribution across a pellet cross-section, are discussed. The effect of catalyst age and reactor temperature on the chemical composition of flashed bottoms product is addressed. Results from regenerating spent catalysts are also presented. 35 references, 31 figures, 18 tables.

  8. Experiment and mechanism investigation on advanced reburning for NOx reduction: influence of CO and temperature

    Institute of Scientific and Technical Information of China (English)

    WANG Zhi-hua; ZHOU Jun-hu; ZHANG Yan-wei; LU Zhi-min; FAN Jian-ren; CEN Ke-fa

    2005-01-01

    Pulverized coal reburning, ammonia injection and advanced reburning in a pilot scale drop tube furnace were investigated. Premix of petroleum gas, air and NH3 were burned in a porous gas burner to generate the needed flue gas. Four kinds of pulverized coal were fed as reburning fuel at constant rate of 1g/min. The coal reburning process parameters including 15%~25% reburn heat input, temperature range from 1100 ℃ to 1400 ℃ and also the carbon in fly ash, coal fineness, reburn zone stoichiometric ratio, etc. were investigated. On the condition of 25% reburn heat input, maximum of 47% NO reduction with Yanzhou coal was obtained by pure coal reburning. Optimal temperature for reburning is about 1300 ℃ and fuel-rich stoichiometric ratio is essential; coal fineness can slightly enhance the reburning ability. The temperature window for ammonia injection is about 700 ℃~1100 ℃. CO can improve the NH3 ability at lower temperature. During advanced reburning, 72.9% NO reduction was measured. To achieve more than 70% NO reduction, Selective Non-catalytic NOx Reduction (SNCR) should need NH3/NO stoichiometric ratio larger than 5, while advanced reburning only uses common dose of ammonia as in conventional SNCR technology. Mechanism study shows the oxidization of CO can improve the decomposition of H2O, which will rich the radical pools igniting the whole reactions at lower temperatures.

  9. Monolithic solid oxide fuel cell technology advancement for coal-based power generation. Quarterly technical status report, January--March 1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-14

    The program is conducted by a team consisting of AiResearch Los Angeles Division of Allied-Signal Aerospace Company and Argonne National Laboratory (ANL). The objective of the program is to advance materials and fabrication methodologies to develop a monolithic solid oxide fuel cell (MSOFC) system capable of meeting performance, life, and cost goals for coal-based power generation. The program focuses on materials research and development, fabrication process development, cell/stack performance testing and characterization, cost and system analysis, and quality development.

  10. Impact property on fine particles from coal combustion in wet flue gas desulfurization process%湿法脱硫烟气中细颗粒物的变化特性

    Institute of Scientific and Technical Information of China (English)

    颜金培; 杨林军; 鲍静静

    2011-01-01

    Fine particles in flue gas before and after WFGD ( wet flue gas desulfurization) were sampled and measured by ELPI (electrical low pressure impactor). Fine particle concentrations and size distributions characteristics were obtained. And the microstructure and major element concentrations of particles were analyzed by SEM ( scanning electron microscopy) and EDS ( energy disperse spectroscopy), respectively. The results show that the removal efficiency of fine particles by WFGD is extremely low using NaOH and CaCO3 desulfurization, but particle number concentration has an obvious increase after ammonia desulfurization. Particles morphology structure and element contents have a great change after WFGD. The surfaces of fine particles from coal-fired may adsorb small particles to form roughness and aggregate structure. But it can be enwrapped by desulfurization reaction products to form a dense irregular block-like structure after CaCO3 desulfurization process. And fine particles are mostly of cube or prism crystal structure after ammonia desulfurization. The main elements of fine particles before WFGD are O, A1 and Si, however, the element content of S in particles is significantly increased after desulfurization, which increases from 1.33% to 10. 01%,19. 96% and 46. 64% after NaOH, CaCO3 and NH3 desulfurization respectively.%采用ELPI(电称低压冲击器)对WFGD(湿法烟气脱硫)前后烟气中的细颗粒进行采样分析,获得细颗粒浓度与粒径分布特性.对脱硫前后细颗粒形貌和主要元素进行SEM(扫描电镜)和EDS(能量色谱仪)分析.结果表明,NaOH和CaCO3脱硫后,WFGD系统对细颗粒脱除效率很低;氨法脱硫后WFGD出口颗粒数浓度明显增加;脱硫前后,细颗粒的形貌特征和元素组分会发生很大变化,洗涤前燃煤细颗粒表面容易吸附小颗粒而形成表面粗糙的团聚体结构;CaCO3脱硫后,细颗粒容易被脱硫反应产物连结或包裹而形成致密的不规则块状或

  11. Feasibility study for an advanced coal fired heat exchanger/gas turbine topping cycle for a high efficiency power plant. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Zhao, Y.; Pines, D.; Buggeln, R.C.; Shamroth, S.J.

    1993-11-01

    Significant improvements in efficiency for the conversion of coal into electricity can be achieved by cycles which employ a high temperature gas turbine topping cycle. The objective of this project is the development of an externally fired gas turbine system. The project computationally tested a new concept for a High Temperature Advanced Furnace (HITAF) and high temperature heat exchanger with a proprietary design to reduce the problems associated with the harsh coal environment. The program addressed two key technology issues: (1) the HITAF/heat exchanger heat transfer through a 2-D computer analysis of the HITAF configuration; (2) 3-D Computational Fluid Dynamics (CFD) model application to simulate the exclusion of particles and corrosive gases from the heat exchanger surface. The basic concept of this new combustor design was verified through the 2D and 3D modeling. It demonstrated that the corrosion and erosion of the exchanger material caused by coal and ash particles can be largely reduced by employing a specially designed firing scheme. It also suggested that a proper combustion geometry design is necessary to maximize the cleaning effect.

  12. Paste-like self-flowing transportation backfilling technology based on coal gangue

    Institute of Scientific and Technical Information of China (English)

    WANG Xin-min; ZHAO Bin; ZHANG Chuan-shu; ZHANG Qin-li

    2009-01-01

    A paste-like self-flowing pipeline transportation backfilling technology with coal gangue as aggregate is proposed to remove the potential damage caused by coal gangue piles. As well, the difficult problems of recovering high quality safety coal pillars and deep mining of the Suncun Coal Mine (SCM), Xinwen Coal Group, Shandong are resolved. The physical-chemical properties of coal gangue, optimized proportion of materials, backfilling system and craft in the SCM were studied in the laboratory and then an industrial test was carried out on high quality coal pillars under a town. The results show that finely crushed kaolinized and fresh gangue with granularity less than 5 mm can be used as aggregate with fly ash to replace part of the cement and a compos-ite water reducer as an additive, accounting for 1.0%-1.5% of the total amount of cement and fly ash. The recommended proportion is I(cement):4(fly ash): 15(coal gangue), with a mass fraction of 72%-75%, theological paste-like properties and a strength of more than 0.7 MPa at 7 d. The sequence of adding cement, fly ash, water reducer and then coal gangue ensures that the suspended state of the slurry, reducing the wear and jam of pipelines. The working face is advancing continuously by the alternating craft of building block walls with coal gangue and backfilling mined-out gobs with paste-like slurry. The recovery rate is as high as 90% with a backfilling cost of 36.9 Yuan/t, good utilization of coal gangue and no subsidence on the surface. This technology provides a good theoretical basis and application experience for coal mines, cement backfilling with paste-like slurry.

  13. Innovative clean coal technology: 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Final report, Phases 1 - 3B

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-01-01

    This report presents the results of a U.S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project was conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The technologies demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NOx burner. The primary objective of the demonstration at Hammond Unit 4 was to determine the long-term effects of commercially available wall-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology were also performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications was established for the project. Short-term and long-term baseline testing was conducted in an {open_quotes}as-found{close_quotes} condition from November 1989 through March 1990. Following retrofit of the AOFA system during a four-week outage in spring 1990, the AOFA configuration was tested from August 1990 through March 1991. The FWEC CF/SF low NOx burners were then installed during a seven-week outage starting on March 8, 1991 and continuing to May 5, 1991. Following optimization of the LNBs and ancillary combustion equipment by FWEC personnel, LNB testing commenced during July 1991 and continued until January 1992. Testing in the LNB+AOFA configuration was completed during August 1993. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NOx burners and advanced overfire systems.

  14. Effects of external atmosphere on the metallization phenomenology of composite pellets containing fines of iron ore and coal; Estudo do efeito da atmosfera gasosa na fenomenologia da metalizacao de pelotas auto-redutoras de minerio de ferro e carbono

    Energy Technology Data Exchange (ETDEWEB)

    D`Abreu, Jose C.; Oliveira, Luiz M.R. de [Pontificia Univ. Catolica do Rio de Janeiro, RJ (Brazil). Dept. de Ciencia dos Materiais e Metalurgia

    1996-12-31

    This work presents the effects of temperature, time and CO/CO{sub 2} ratio on metallization and morphology of metallic iron produced by reduction of composite pellets containing fines of iron and anthracite coal. The experiments were conducted in a temperature range of 950 - 1250 deg C, and maximum time of 60 minutes. On the other hand, mixtures of CO/CO{sub 2}, from 100% CO{sub 2} up to 100% CO, were used in the experiments, conducted in an appropriate electrically heated furnace apparatus. In order to fulfill the objectives, the reduced pellets were chemically analyzed before observed in optical and scanning electronic microscopes and the results presented in graphics of percentage metallization versus . The following main results may be drawn from this work: (a) the type of external atmosphere exert a major influence on the reduction rates and metallization of the composite pellets: (i) when CO is raised in the mixture, there is an increase in metallization and reaction rate and the metallization continue unchanged; (ii) and uniform internal reduction mechanism occurs. (b) when CO is decreased in CO-CO{sub 2} mixture, the reduction led to a superficial metallic layer, the metallization, initially high, drops and a topochemical mechanism of re-oxidation occurs. (c) the scanning electronic microscopy allowed to observe that calcium is always present in the root of whiskers. (author) 4 refs., 4 figs., 4 tabs.

  15. Advanced treatment of biologically pretreated coal gasification wastewater by a novel integration of three-dimensional catalytic electro-Fenton and membrane bioreactor.

    Science.gov (United States)

    Jia, Shengyong; Han, Hongjun; Hou, Baolin; Zhuang, Haifeng

    2015-12-01

    Laboratorial scale experiments were conducted to investigate a novel system three-dimensional catalytic electro-Fenton (3DCEF, catalyst of sewage sludge based activated carbon which loaded Fe3O4) integrating with membrane bioreactor (3DCEF-MBR) on advanced treatment of biologically pretreated coal gasification wastewater. The results indicated that 3DCEF-MBR represented high efficiencies in eliminating COD and total organic carbon, giving the maximum removal efficiencies of 80% and 75%, respectively. The integrated 3DCEF-MBR system significantly reduced the transmembrane pressure, giving 35% lower than conventional MBR after 30 days operation. The enhanced hydroxyl radical oxidation and bacteria self repair function were the mechanisms for 3DCEF-MBR performance. Therefore, the integrated 3DCEF-MBR was expected to be the promising technology for advanced treatment in engineering applications.

  16. Experimental research on influencing factors of wet removal of NO from coal-fired flue gas by UV/H2O2 advanced oxidation process

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Wet removal of NO from coal-fired flue gas by UV/H2O2 Advanced Oxidation Process (AOP) were investigated in a self-designed UV-bubble reactor. Several main influencing factors (UV intensity, H2O2 initial concentration, initial pH value, solution temperature, NO initial concentration, liquid-gas ratio and O2 percentage content) on the NO removal efficiency were studied. The results showed that UV intensity, H2O2 initial concentration, NO initial concentration and liquid-gas ratio are the main influencing factors. In the best conditions, the highest NO removal efficiency by UV/H2O2 advanced oxidation process could reach 82.9%. Based on the experimental study, the influencing mechanism of the relevant influencing factors were discussed in depth.

  17. Engineering development of advanced coal-fired low-emission boiler systems: Technical progress report No. 16, July-September 1996

    Energy Technology Data Exchange (ETDEWEB)

    Barcikowski, G.F.; Borio, R.W.; Bozzuto, C.R.; Burr, D.H.; Cellilli, L.; Fox, J.D.; Gibbons, T.B.; Hargrove, M.J.; Jukkola, G.D.; King, A.M.

    1996-11-27

    The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emission boiler systems. The Project is under budget and generally on schedule. The current status is shown in the Milestone Schedule Status Report included as Appendix A. Under Task 7--Component development and optimization, the CeraMem filter testing was completed. Due to an unacceptably high flue gas draft loss, which will not be resolved in the POCTF timeframe, a decision was made to change the design of the flue gas cleaning system from Hot SNO{sub x}{sup {trademark}} to an advanced dry scrubber called New Integrated Desulfurization (NID). However, it is recognized that the CeraMem filter still has the potential to be viable in pulverized coal systems. In Task 8-- Preliminary POCTF design, integrating and optimizing the performance and design of the boiler, turbine/generator and heat exchangers of the Kalina cycle as well as the balance of plant design were completed. Licensing activities continued. A NID system was substituted for the SNO{sub x} Hot Process.

  18. Recovery of clean coal from polymer flocculated raw coal slurry

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K.; Chen, Z. [Center for Applied Energy Research, Lexington, KY (US)

    2004-11-01

    The recovery of fine clean coal from waste streams using column flotation is recognized as an efficient and economical technique. However, due to the low percent solids (around 3% by weight) found in these fine waste slurries, the flotation columns have low capacities and are, thus, underutilized. In this study, a 3% (by weight) solids suspension of Upper Freeport coal was flocculated with polymers and concentrated to 10% (by weight) solids. The flocculated slurry was then floated using 250 g/t No. 2 fuel oil and 250 g/t MIBC, which provided a clean coal with 12% ash at an 80% yield. The results showed that flocculated coal could be floated effectively. Zeta potential and contact-angle data showed that the presence of polymer on the surface of the coal did not affect its hydrophobicity, and in some cases it improved the hydrophobicity as indicated by larger contact angles.

  19. Coal Beneficiation by Gas Agglomeration

    Energy Technology Data Exchange (ETDEWEB)

    Thomas D. Wheelock; Meiyu Shen

    2000-03-15

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  20. Measurement and modeling of advanced coal conversion processes, Volume I, Part 2. Final report, September 1986--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [and others

    1995-09-01

    This report describes work pertaining to the development of models for coal gasification and combustion processes. This volume, volume 1, part 2, contains research progress in the areas of large particle oxidation at high temperatures, large particle, thick-bed submodels, sulfur oxide/nitrogen oxides submodels, and comprehensive model development and evaluation.

  1. Development and testing of a high efficiency advanced coal combustor: Phase 3 industrial boiler retrofit. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Patel, R.L.; Thornock, D.E.; Miller, B.G.; Scaroni, A.W.; McGowan, J.G.

    1998-03-01

    Economics and/or political intervention may one day dictate the conversion from oil or natural gas to coal in boilers that were originally designed to burn oil or gas. In recognition of this future possibility the US Department of Energy, Federal Energy Technical Center (DOE-FETC) supported a program led by ABB Power Plant Laboratories with support from the Energy and Fuels Research Center of Penn State University with the goal of demonstrating the technical and economic feasibility of retrofitting a gas/oil designed boiler to burn micronized coal. In support of the overall goal the following specific objectives were targeted: develop a coal handling/preparation system that can meet the technical and operational requirements for retrofitting microfine coal on a boiler designed for burning oil or natural gas; maintain boiler thermal performance in accordance with specifications when burning oil or natural gas; maintain NOx emissions at or below 0.6 lb NO{sub 2} per million Btu; achieve combustion efficiencies of 98% or higher; and determine economic payback periods as a function of key variables.

  2. Commercially viable strategies for enhancing coal quality

    Energy Technology Data Exchange (ETDEWEB)

    A. Patwardhan; Y.P. Chugh [Southern Illinois University, Carbondale, IL (United States). Department of Mining and Mineral Resources Engineering

    2005-12-01

    The focus of this research is on coal quality enhancement, which includes reduction in the sulfur content and increase in heating value through simple, innovative, and commercially viable coal cleaning strategies. These strategies involve fine coal cleaning, plant optimization, partial coarse coal liberation, and multiple product generation. Evaluations on five mines in Illinois have indicated a potential to reduce the sulfur dioxide emission potential of these coals by up to 20%, while increasing the product heating value by up to 250 kcal/kg (450 BTU/lb). In addition, increases in coal yield by 2-6% are predicted depending on the specific conditions at the evaluated mine.

  3. Use of CT-guided fine needle aspiration biopsy in epidermal growth factor receptor mutation analysis in patients with advanced lung cancer

    Energy Technology Data Exchange (ETDEWEB)

    Zhuang, Yi-Ping; Wang, Hai-Yan; Zhang, Jin; Feng, Yong (Dept. of Radiology, Jiangsu Cancer Inst. and Hospital, Nanjing, Jiangsu (China)), email: yipingzhuang2010@sina.com; Shi, Mei-Qi (Dept. of Chemotherapy, Jiangsu Cancer Inst. and Hospital, Nanjing, Jiangsu (China))

    2011-12-15

    Background. The safety of using a cutting needle when performing a core-needle biopsy is of major concern, in particular for small lung tumors or tumors near the hilum. Purpose. To investigate the usefulness of CT-guided fine needle aspiration biopsy (FNAB) of the lung in obtaining tumor tissue for epidermal growth factor receptor (EGFR) mutation analysis in advanced lung cancer patients. Material and Methods. Forty-three patients with stage IIIB-IV lung cancer were enrolled. In all patients, CT-guided FNAB was performed using an 18-gauge or 20-gauge Chiba aspiration needle for histology diagnosis and EGFR mutation analysis. Complications associated with CT-guided FNAB were observed, and the specimen mutational assessments were recorded. Results. The obtained tumor samples ranged from 0.5-1.5 cm in length and were adequate for histological and DNA analyses in all patients. No patient had a pneumothorax or hemoptysis. Minor needle tract bleeding appeared in eight patients. Mutation analysis was satisfactorily demonstrated in 23 mutations and 20 non-mutations. Ten and 13 mutations were identified by 18-gauge and 20-gauge needle biopsies, respectively. EFGR mutations, including 12 cases of EGFR exon 19 deletion and 11 cases of exon 21 point mutation, were present in 21 patients with adenocarcinomas, one with squamous cell carcinoma, and one with undifferentiated carcinoma. Conclusion. CT-guided FNAB is a feasible and safe technique for obtaining lung tumor tissues for EGFR gene mutation analysis

  4. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Third quarterly technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-31

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. Baseline, AOFA, LNB, and LNB plus AOFA test segments have been completed. Analysis of the 94 days of LNB long-term data collected show the full-load NO{sub x} emission levels to be approximately 0.65 lb/MBtu with fly ash LOI values of approximately 8 percent. Corresponding values for the AOFA configuration are 0.94 lb/MBtu and approximately 10 percent. For comparison, the long-term full-load, baseline NO{sub x} emission level was approximately 1.24 lb/MBtu at 5.2 percent LOI. Comprehensive testing in the LNB+AOFA configuration indicate that at full-load, NO{sub x} emissions and fly ash LOI are near 0.40 lb/MBtu and 8 percent, respectively. However, it is believed that a substantial portion of the incremental change in NO{sub x} emissions between the LNB and LNB+AOFA configurations is the result of additional burner tuning and other operational adjustments and is not the result of the AOFA system. During this quarter, LNB+AOFA testing was concluded. Testing performed during this quarter included long-term and verification testing in the LNB+AOFA configuration.

  5. Experimental research on surface modification of fine coal strengthening desulfurization and ash reduction through rotation friction electric separation%微粉煤表面改性强化旋转摩擦电选脱硫降灰试验研究∗

    Institute of Scientific and Technical Information of China (English)

    宋傲; 陶有俊; 羡宇帅; 张学彬; 丁晴晴

    2015-01-01

    为了提高微粉煤摩擦电选脱硫降灰的效果,采用表面改性的方法对微粉煤进行预处理,并使用旋转摩擦电选机对其分选。试验结果表明,当改性剂选用煤油、改性剂用量为10169 g/t以及改性时间为5 s时,微粉煤旋转摩擦电选效果最佳,可燃体回收率、脱灰率以及脱硫率分别为44.16%、80.96%和73.36%,表面改性后精煤产率提高了约5%、精煤灰分降低了约3%、精煤硫分降低了约0.4%。分析对比改性前后电选效果认为,表面改性能显著强化微粉煤旋转摩擦静电分选的脱硫降灰效果。%The authors preprocessed fine coal by using surface modification method and used rotation friction electricity separation in order to improve effects of fine coal friction electrostatic separation desulfurization and ash reduction.The test results showed that when the modifier was kerosene with 10169g/t dosage and 5s modification time,the effects of fine coal rotary friction e-lectric separation were best;combustible recovery,deashing and desulphurization values were 44.16%、80.96%、70.36%;after surface modification,the clean coal productivity increased 5%, clean ash decreased 3% and the sulphur content of clean coal decreased 0.4%.According to com-parative analyzing electrostatic separation before and after surface modification,surface modifica-tion performance can significantly enhance the desulfurization and deashing effects of fine coal with rotary friction electric separation.

  6. STUDY ON MAJOR FACTORS INFLUENCING SPONTANEOUS COMBUSTION OF COAL

    Institute of Scientific and Technical Information of China (English)

    Deng Jun; Xu Jingcai; Zhang Xinghai

    2000-01-01

    This paper theoretically analyzes major factors influencing spontaneous combustion of coal, such as molecule structure of coal, porosity, temperature, concentration of oxygen, coal thickness, velocity of face advance, and so on; and probes into how they affect the process of spontaneous combustion of coal, which is of momentous significance to predict or control self-ignition of coal.

  7. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., College Park, PA (United States); Gutterman, C.

    1995-04-01

    Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

  8. Clean coal - a national urgency

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, S.M.; Sahai, R. [Indian Bureau of Mines, Nagpur (India). Technical Consultancy Division

    2000-07-01

    India is the third largest producer and consumer of coal in the world. Coal generally has a high ash content, thereby requiring that it be cleaned for proper use. Technological advances now make it possible to reduce pollution considerably, even as energy use increases. However, to reduce environmental impacts, technologies for cleaning coal before combustion need to be developed. The paper focuses on the need for clean coal production and the benefits associated with it. Although the country is rich in coal reserves, the generally inferior quality of coal will lead to its depletion if it is not used cleanly. Increasing the proportion of prepared coal from the current level of less than 5% (i.e. 10-11 million tonnes per annum) of all coal consumed will lead to a massive saving. This can be achieved if new washeries are set up, preferably near the coalfields. 2 figs.

  9. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    Energy Technology Data Exchange (ETDEWEB)

    C. Jean Bustard; Kenneth E. Baldrey; Richard Schlager

    2000-04-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. Preliminary testing has identified a class of common deliquescent salts that effectively control flyash resistivity on a variety of coals. A method to evaluate cohesive properties of flyash in the laboratory has been selected and construction of an electrostatic tensiometer test fixture is underway. Preliminary selection of a variety of chemicals that will be screened for effect on flyash cohesion has been completed.

  10. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    Energy Technology Data Exchange (ETDEWEB)

    Kenneth E. Baldrey

    2003-01-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a liquid flue gas conditioning system was completed at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Two cohesivity-specific additive formulations, ADA-44C and ADA-51, will be evaluated. In addition, ammonia conditioning will also be compared.

  11. Third symposium on coal preparation. NCA/BCR coal conference and Expo IV

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-01-01

    The third Symposium on Coal preparation, sponsored by the National Coal Association and Bituminous Coal Research, Inc., was held at the Kentucky Fair and Exposition Center, Louisville, Kentucky, October 18-20, 1977. Fourteen papers from the proceedings have been entered individually into EDB and ERA; five additional papers had been entered previously from other sources. Topics covered involved chemical comminution and chemical desulfurization of coal (aimed at reducing sulfur sufficiently with some coals to meet air quality standards without flue gas desulfurization), coal cleaning concepts, removing coal fines and recycling wash water, comparative evaluation of coal preparation methods, coal refuse disposal without polluting the environment, spoil bank reprocessing, noise control in coal preparation plants, etc. (LTN)

  12. Chemical structures of coal lithotypes before and after CO2 adsorption as investigated by advanced solid-state 13C nuclear magnetic resonance spectroscopy

    Science.gov (United States)

    Cao, X.; Mastalerz, Maria; Chappell, M.A.; Miller, L.F.; Li, Y.; Mao, J.

    2011-01-01

    Four lithotypes (vitrain, bright clarain, clarain, and fusain) of a high volatile bituminous Springfield Coal from the Illinois Basin were characterized using advanced solid-state 13C nuclear magnetic resonance (NMR) spectroscopy. The NMR techniques included quantitative direct polarization/magic angle spinning (DP/MAS), cross polarization/total sideband suppression (CP/TOSS), dipolar dephasing, CHn selection, and recoupled C-H long-range dipolar dephasing techniques. The lithotypes that experienced high-pressure CO2 adsorption isotherm analysis were also analyzed to determine possible changes in coal structure as a result of CO2 saturation at high pressure and subsequent evacuation. The main carbon functionalities present in original vitrain, bright clarain, clarain and fusain were aromatic carbons (65.9%-86.1%), nonpolar alkyl groups (9.0%-28.9%), and aromatic C-O carbons (4.1%-9.5%). Among these lithotypes, aromaticity increased in the order of clarain, bright clarain, vitrain, and fusain, whereas the fraction of alkyl carbons decreased in the same order. Fusain was distinct from other three lithotypes in respect to its highest aromatic composition (86.1%) and remarkably small fraction of alkyl carbons (11.0%). The aromatic cluster size in fusain was larger than that in bright clarain. The lithotypes studied responded differently to high pressure CO2 saturation. After exposure to high pressure CO2, vitrain and fusain showed a decrease in aromaticity but an increase in the fraction of alkyl carbons, whereas bright clarain and clarain displayed an increase in aromaticity but a decrease in the fraction of alkyl carbons. Aromatic fused-rings were larger for bright clarain but smaller for fusain in the post-CO2 adsorption samples compared to the original lithotypes. These observations suggested chemical CO2-coal interactions at high pressure and the selectivity of lithotypes in response to CO2 adsorption. ?? 2011 Elsevier B.V.

  13. Fine mapping of QTL for prepulse inhibition in LG/J and SM/J mice using F(2) and advanced intercross lines.

    Science.gov (United States)

    Samocha, K E; Lim, J E; Cheng, R; Sokoloff, G; Palmer, A A

    2010-10-01

    Prepulse inhibition (PPI) of the startle response is a measure of sensorimotor gating, a process that filters out extraneous sensory, motor and cognitive information. Humans with neurological and psychiatric disorders, including schizophrenia, obsessive-compulsive disorder and Huntington's disease, exhibit a reduction in PPI. Habituation of the startle response is also disrupted in schizophrenic patients. In order to elucidate the genes involved in sensorimotor gating, we phenotyped 472 mice from an F(2) cross between LG/J × SM/J for PPI and genotyped these mice genome-wide using 162 single nucleotide polymorphism (SNP) markers. We used prepulse intensity levels that were 3, 6 and 12 dB above background (PPI3, PPI6 and PPI12, respectively). We identified a significant quantitative trait locus (QTL) on chromosome 12 for all three prepulse intensities as well as a significant QTL for both PPI6 and PPI12 on chromosome 11. We identified QTLs on chromosomes 7 and 17 for the startle response when sex was included as an interactive covariate and found a QTL for habituation of the startle response on chromosome 4. We also phenotyped 135 mice from an F(34) advanced intercross line (AIL) between LG/J × SM/J for PPI and genotyped them at more than 3000 SNP markers. Inclusions of data from the AIL mice reduced the size of several of these QTLs to less than 5 cM. These results will be useful for identifying genes that influence sensorimotor gaiting and show the power of AIL for fine mapping of QTLs.

  14. Bringing coal preheating in drum dryers to a commercial level

    Energy Technology Data Exchange (ETDEWEB)

    Babanin, B.I.; Proushin, Yu.E.; Dinel' t, V.M.; Nikolaeva, V.Z.; Shabarshova, Yu.V.; Patrushev, A.N.; Vodop' yanov, A.G.; Vlasov, V.S.; Sementin, V.P.

    1988-10-01

    Discusses operation of a system for coal charge preheating used in Western Siberia since 1965. It is the first coal preheating system constructed in the USSR. The following aspects of system operation are discussed: composition of combustion gases used for coal drying, drying temperature, consumption rate of combustion gases depending on coal moisture content, flue gas recirculation system, transport and storage of dried coal, methods for dust separation (wet and dry), air pollution from coal dryers, and efficiency of air pollution control. Operation of the coal preheating system shows that one-stage coal drying and preheating is economic but associated with increased investment (construction cost) and with increased coal comminution. Large one-stage dryers also cause irregular coal preheating depending on distribution of coal grain size (with overheating of coal fines). Recommendations for design modifications of one-stage dryers are made. 3 refs.

  15. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    1992-11-25

    This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO[sub x] combustion technologies on NO[sub x] emissions and boiler performance. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO[sub x] control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO[sub x] concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level I short-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

  16. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, second quarter 1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-11-25

    This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level I short-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

  17. Advances in LES of Two-phase Combustion (II) LES of Complex Gas-Particle Flows and Coal Combustion

    Institute of Scientific and Technical Information of China (English)

    周力行; 胡璨元

    2012-01-01

    Large-eddy simulation (LES) is under its rapid development and is recognized as a possible second gen- eration of CFD methods used in engineering. Large-eddy simulation of two-phase flows and combustion is particu- larly important for engineering applications. Some investigators, including the present authors, give their review on LES of spray combustion in gas-turbine combustors and internal combustion engines. However, up to now only a few papers are related to the state-of-the-art on LES of gas-particle flows and combustion. In this paper a review of the advances in LES of complex gas-particle flows and coal combustion is presented. Different sub-grid scale (SGS) stress models and combustion models are described, some of the main results are summarized, and some research needs are discussed.

  18. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    Energy Technology Data Exchange (ETDEWEB)

    Kenneth E. Baldrey

    2002-05-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was underway at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. This represents the first long-term full-scale testing of this class of products. Modifications to the flue gas conditioning system at Jim Bridger, including development of alternate injection lances, was also undertaken to improve chemical spray distribution and to avoid spray deposition to duct interior surfaces. Also in this quarter, a firm commitment was received for another long-term test of the cohesivity additives. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

  19. Advanced Emissions Control Development Program

    Energy Technology Data Exchange (ETDEWEB)

    A.P.Evans; K.E. Redinger; M.J. Holmes

    1998-04-01

    The objective of the Advanced Emissions Control Development Program (AECDP) is to develop practical, cost-effective strategies for reducing the emissions of air toxics from coal-fired boilers. Ideally, the project aim is to effectively control air toxic emissions through the use of conventional flue gas cleanup equipment such as electrostatic precipitators (ESPS), fabric filters (baghouse), and wet flue gas desulfurization. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate and hydrogen chloride. Following the construction and evaluation of a representative air toxics test facility in Phase I, Phase II focused on the evaluation of mercury and several other air toxics emissions. The AECDP is jointly funded by the United States Department of Energy's Federal Energy Technology Center (DOE), the Ohio Coal Development Office within the Ohio Department of Development (oCDO), and Babcock& Wilcox-a McDermott company (B&W).

  20. The development of coal-based technologies for Department of Defense facilities. Volume 1, Technical report. Semiannual technical progress report, September 28, 1994--March 27, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Miller, B.G.; Bartley, D.A.; Hatcher, P. [Pennsylvania State Univ., University Park, PA (United States). Energy and Fuels Research Center] [and others

    1996-10-15

    This program is being conducted as a cooperative agreement between the Consortium for Coal Water Mixture Technology and the U.S. Department of Energy. Activities this reporting period are summarized by phase. Phase I is nearly completed. During this reporting period, coal beneficiation/preparation studies, engineering designs and economics for retrofitting the Crane, Indiana boiler to fire coal-based fuels, and a 1,000-hour demonstration of dry, micronized coal were completed. In addition, a demonstration-scale micronized-coal water mixture (MCWM) preparation circuit was constructed and a 1,000-hour demonstration firing MCWM began. Work in Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analyses of coal use. Emissions reductions investigations involved literature surveys of NO{sub x}, SO{sub 2}, trace metals, volatile organic compounds, and fine particulate matter capture. In addition, vendors and engineering firms were contacted to identify the appropriate emissions technologies for the installation of commercial NO{sub x} and SO{sub 2} removal systems on the demonstration boiler. Information from the literature surveys and engineering firms will be used to identify, design, and install a control system(s). Work continued on the refinement and optimization of coal grinding and MCWM preparation procedures, and on the development of advanced processes for beneficiating high ash, high sulfur coals. Work also continued on determining the basic cost estimation of boiler retrofits, and evaluating environmental, regulatory, and regional economic impacts. In addition, the feasibility of technology adoption, and the public`s perception of the benefits and costs of coal usage was studied. A coal market analysis was completed. Work in Phase III focused on coal preparation studies, emissions reductions and economic analyses of coal use.

  1. Bioaccumulation and effects of metals and trace elements from aquatic disposal of coal combustion residues: recent advances and recommendations for further study.

    Science.gov (United States)

    Rowe, Christopher L

    2014-07-01

    Advances have been made recently in assessing accumulation and effects of coal combustion residues (CCR). I provide a brief review of recent advancements, provide a tabulated summary of results of recent work, and put forth recommendations for future studies. One advancement is that mercury accumulation has begun to receive (limited) attention, whereas it had rarely been considered in the past. Additionally, some constituents of CCR have been shown to be accumulated by adults and transferred to offspring, sometimes compromising offspring health. Studies have demonstrated that amphibians, possessing complex life cycles, may accumulate and transfer some contaminants to terrestrial systems. Some study has been given to molecular and cellular effects of CCR exposure, although these studies have been limited to invertebrates. Population models have also been applied to CCR affected systems and have shown that CCR may affect animal populations under some conditions. In light of these advancements, there are several topics that require further assessment. First, more attention to Hg and its dynamics in CCR affected systems is warranted. Hg can be highly accumulative and toxic under some conditions and may interact with other components of CCR (notably Se), perhaps altering accumulation and effects of the contaminant mixtures. Second, further investigation of maternal transfer and effects of CCR contaminants need to be conducted. These studies could benefit from incorporation of quantitative models to project impacts on populations. Finally, more attention to the organic constituents of CCR (PAHs) is required, as a focus on inorganic compounds only may restrict our knowledge of contaminant dynamics and effects as a whole. While further studies will shed light on some chemical and biological nuances of exposure and effect, information available to date from numerous study sites implicates CCR as a bulk effluent that presents risks of bioaccumulation and effects on organisms

  2. 火电厂脱汞技术综述%Mercury Removal Technology Advances of Coal-fired Power Plants

    Institute of Scientific and Technical Information of China (English)

    赵宝江

    2011-01-01

    Flue gas mercury pollution was attached great importance,and to research institutions it bacome one of the current focus of research.Combination of morphological characteristics of mercury,from coal before combustion,combustion and post-combustion synthesis,the latest developments of thermal power plants flue gas mercury removal technology was summerized.%火电厂烟气汞污染已受到高度重视,已成为科研机构当前重点研究内容之一。结合汞的形态特性,从煤燃烧前、燃烧中和燃烧后三方面综述了火电厂烟气脱汞技术最新进展。

  3. Technical and Energy Performance of an Advanced, Aqueous Ammonia-Based CO2 Capture Technology for a 500 MW Coal-Fired Power Station.

    Science.gov (United States)

    Li, Kangkang; Yu, Hai; Feron, Paul; Tade, Moses; Wardhaugh, Leigh

    2015-08-18

    Using a rate-based model, we assessed the technical feasibility and energy performance of an advanced aqueous-ammonia-based postcombustion capture process integrated with a coal-fired power station. The capture process consists of three identical process trains in parallel, each containing a CO2 capture unit, an NH3 recycling unit, a water separation unit, and a CO2 compressor. A sensitivity study of important parameters, such as NH3 concentration, lean CO2 loading, and stripper pressure, was performed to minimize the energy consumption involved in the CO2 capture process. Process modifications of the rich-split process and the interheating process were investigated to further reduce the solvent regeneration energy. The integrated capture system was then evaluated in terms of the mass balance and the energy consumption of each unit. The results show that our advanced ammonia process is technically feasible and energy-competitive, with a low net power-plant efficiency penalty of 7.7%.

  4. Mulled coal: A beneficiated coal form for use as a fuel or fuel intermediate. Phase 3, Final report

    Energy Technology Data Exchange (ETDEWEB)

    1993-08-01

    Energy International Corporation (El) was awarded a contract to evaluate a new concept for utilization of the fine coal wetcake produced by many of the physical beneficiation processes now under development. EI proposed development of a stabilized wetcake with properties that would facilitate storage, handling, transport, and subsequent conversion of the material into Coal-Water Fuel (CWF) at the point of use. The effort was performed in three phases. Phase I established the technical feasibility of stabilizing the fine coal ``wetcake`` in a form that can be readily handled and converted into a desired fuel form at the combustion site. The preferred form of stabilized ``wetcake`` was a granular free flowing material with the moisture encapsulated with the fine coal particles. The product was termed Mulled Coal. Phase I results indicated that the Mulled Coal was not only suitable as a CWF intermediate, but also had potential as a solid fuel. Phase II demonstrated the utilization of the Mulled Coal process to store and move fine coal products as a stable ``wetcake.`` Tasks in this phase tested components of the various systems required for storage, handling and combustion of the fine coals. Phase III expanded the technology by: 1. Evaluating Mulled Coal from representative coals from all producing regions in the US. 2. Development of bench-scale tests. 3. Design, construction, and operation of a 1 ton/hr continuous processing unit. 4. Evaluation of the effects of beneficiation. and 5. Developing an estimate of capital and operating costs for commercial units.

  5. Production of premium fuels from coal refuse pond material

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q.; Patil, D.P.; Sirkeci, A.; Patwardhan, A. [University of Kentucky, Lexington, KY (United States). Dept. of Mining Engineering

    2001-11-01

    Because of increasing production of fine coal during mining over the past century and because of inefficient fine-coal recovery technologies, a vast reserve of high-quality coal now exists in refuse ponds. A novel fine-coal circuit, consisting of a hindered-bed classifier, an enhanced gravity concentrator and a flotation column, was evaluated for the recovery of fine coal from refuse ponds. The treatment of a pond derived from Pittsburgh No. 8 seam coal resulted in the production of a premium fuel containing less than 5 % ash and a calorific value of about 30,170 kJ/kg with 60% mass yield. Results from the treatment of two refuse pond materials are presented.

  6. Bench-scale Development of an Advanced Solid Sorbent-based CO2 Capture Process for Coal-fired Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, Thomas [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Kataria, Atish [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Soukri, Mustapha [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Farmer, Justin [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Mobley, Paul [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Tanthana, Jak [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Wang, Dongxiang [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Wang, Xiaoxing [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Song, Chunshan [Research Triangle Institute (RTI), Research Triangle Park, NC (United States)

    2015-12-31

    It is increasingly clear that CO2 capture and sequestration (CCS) must play a critical role in curbing worldwide CO2 emissions to the atmosphere. Development of these technologies to cost-effectively remove CO2 from coal-fired power plants is very important to mitigating the impact these power plants have within the world’s power generation portfolio. Currently, conventional CO2 capture technologies, such as aqueous-monoethanolamine based solvent systems, are prohibitively expensive and if implemented could result in a 75 to 100% increase in the cost of electricity for consumers worldwide. Solid sorbent CO2 capture processes – such as RTI’s Advanced Solid Sorbent CO2, Capture Process – are promising alternatives to conventional, liquid solvents. Supported amine sorbents – of the nature RTI has developed – are particularly attractive due to their high CO2 loadings, low heat capacities, reduced corrosivity/volatility and the potential to reduce the regeneration energy needed to carry out CO2 capture. Previous work in this area has failed to adequately address various technology challenges such as sorbent stability and regenerability, sorbent scale-up, improved physical strength and attrition-resistance, proper heat management and temperature control, proper solids handling and circulation control, as well as the proper coupling of process engineering advancements that are tailored for a promising sorbent technology. The remaining challenges for these sorbent processes have provided the framework for the project team’s research and development and target for advancing the technology beyond lab- and bench-scale testing. Under a cooperative agreement with the US Department of Energy, and part of NETL’s CO2 Capture Program, RTI has led an effort to address and mitigate the challenges associated with solid sorbent CO2 capture. The overall objective

  7. Coal-water slurry fuel production: Its evolution and current status in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Morrison, J.L.; Miller, B.G.; Scaroni, A.W. [Pennsylvania State Univ., University Park, PA (United States)

    1997-12-31

    Interest in the US in utilizing bituminous coal in a slurry form has evolved substantially over the last two decades. In the mid-1970`s, technologies to utilize coal-oil mixtures (COMs) as potential fuel oil replacements for utility and industrial boilers were developed as a consequence of escalating world oil prices. To further reduce dependency on imported oil, interest shifted away from COMs to coal-water slurry fuels (CWSFs) because higher solids loadings were obtainable while eliminating the use of oil. Research which focused on the use of CWSF as a potential fuel oil replacement peaked in the mid to late-1980`s as a result of a decline in world oil prices. During the late 1980`s and early 1990`s, coal suppliers and coal-fired utilities began to evaluate the production of CWSF using bituminous coal fines from fine coal cleaning circuits in an effort to reduce dewatering/drying costs. This marked a philosophical change in the driving force behind the utilization of CWSF in the US. In an effort to broaden the supply of coal fines, The Pennsylvania State University (Penn State) and the Pennsylvania Electric Company (Penelec) surveyed a series of fine coal impoundments in western Pennsylvania to determine the quality, cleanability, and slurryability of the coal fines contained therein. The development and commercialization of recovery technologies, cleaning techniques, and CWSF reentrainment circuits, coupled with an interest by utilities to utilize low-cost fuels, has fostered the recovery of impounded coal fines. In addition to the fine coal impoundments, fine coal cleaning circuits which actively dispose of process water having suspended coal fines (e.g. centrifuge effluent) are being examined to determine if the fines can be recovered and thickened into a low solids CWSF. The paper describes required physical and chemical properties of a CWSF for boiler applications. There is a growing awareness that CWSF is a fuel form that can be cofired with coal. The

  8. Gaseous phase coal surface modification

    Energy Technology Data Exchange (ETDEWEB)

    Okoh, J.M.; Pinion, J.; Thiensatit, S.

    1992-05-07

    In this report, we present an improved, feasible and potentially cost effective method of cleaning and beneficiating ultrafine coal. Increased mechanization of mining methods and the need towards depyritization, and demineralization have led to an increase in the quantity of coal fines generated in recent times. For example, the amount of {minus}100 mesh coal occurring in coal preparation plant feeds now typically varies from 5 to 25% of the total feed. Environmental constraints coupled with the greatly increased cost of coal have made it increasingly important to recover more of these fines. Our method chemically modifies the surface of such coals by a series of gaseous phase treatments employing Friedel-Crafts reactions. By using olefins (ethene, propene and butene) and hydrogen chloride catalyst at elevated temperature, the surface hydrophobicity of coal is enhanced. This increased hydrophobicity is manifest in surface phenomena which reflect conditions at the solid/liquid interphase (zeta potential) and those which reflect conditions at the solid/liquid/gas interphases (contact angle, wettability and floatability).

  9. Enhancement of surface properties for coal beneficiation

    Energy Technology Data Exchange (ETDEWEB)

    Chander, S.; Aplan, F.F.

    1992-01-30

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  10. Advanced development of a pressurized ash agglomerating fluidized-bed coal gasification system: Topical report, Process analysis, FY 1983

    Energy Technology Data Exchange (ETDEWEB)

    None

    1987-07-31

    KRW Energy Systems, Inc., is engaged in the continuing development of a pressurized, fluidized-bed gasification process at its Waltz Mill Site in Madison, Pennsylvania. The overall objective of the program is to demonstrate the viability of the KRW process for the environmentally-acceptable production of low- and medium-Btu fuel gas from a variety of fossilized carbonaceous feedstocks and industrial fuels. This report presents process analysis of the 24 ton-per-day Process Development Unit (PDU) operations and is a continuation of the process analysis work performed in 1980 and 1981. Included is work performed on PDU process data; gasification; char-ash separation; ash agglomeration; fines carryover, recycle, and consumption; deposit formation; materials; and environmental, health, and safety issues. 63 figs., 43 tabs.

  11. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    Energy Technology Data Exchange (ETDEWEB)

    Kenneth E. Baldrey

    2001-09-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of fly ash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory fly ash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

  12. Desulfurization and oxidation behavior of ultra-fine CaO particles prepared from brown coal; Kattan wo mochiite choseishita CaO chobiryushi no datsuryu tokusei to sanka tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Benjamin, G.; Roman, M.; Yamazaki, Y.; Abe, H.; Harano, Y.; Takarada, Y. [Gunma University, Gunma (Japan). Faculty of Engineering

    1996-10-28

    The effect of reaction temperature and oxygen concentration on the desulfurization and oxidation behavior of ion-exchanged brown coal by Ca as new desulfurizing agent was studied. In experiment, Yallourn coal was used for ion- exchange, and limestone produced in Tochigi prefecture was also used for comparative study. Ca-exchanged brown coal was prepared by agitating coal in Ca(OH)2 slurry for 24 hours. The desulfurization behavior of a desulfurizing agent was obtained by measuring H2S and sulfur compounds in outlet gas of a reactor, and the oxidation behavior by measuring SO2 emission in outlet gas after oxidation reaction. As the experimental result, CaO produced from Ca-exchanged brown coal offered the extremely high activity to desulfurization reaction in a temperature range of 850-950{degree}C as compared with limestone. Although the oxidation behavior was dependent on oxidation temperature and oxygen concentration, CaS obtained from Ca-exchanged brown coal was more rapidly converted to CaSO4 than limestone. 3 refs., 8 figs., 2 tabs.

  13. Advanced Hybrid Particulate Collector Project Management Plan

    Energy Technology Data Exchange (ETDEWEB)

    Miller, S.J.

    1995-11-01

    As the consumption of energy increases, its impact on ambient air quality has become a significant concern. Recent studies indicate that fine particles from coal combustion cause health problems as well as atmospheric visibility impairment. These problems are further compounded by the concentration of hazardous trace elements such as mercury, cadmium, selenium, and arsenic in fine particles. Therefore, a current need exists to develop superior, but economical, methods to control emissions of fine particles. Since most of the toxic metals present in coal will be in particulate form, a high level of fine- particle collection appears to be the best method of overall air toxics control. However, over 50% of mercury and a portion of selenium emissions are in vapor form and cannot be collected in particulate control devices. Therefore, this project will focus on developing technology not only to provide ultrahigh collection efficiency of particulate air toxic emissions, but also to capture vapor- phase trace metals such as mercury and selenium. Currently, the primary state-of-the-art technologies for particulate control are fabric filters (baghouses) and electrostatic precipitators (ESPs). However, they both have limitations that prevent them from achieving ultrahigh collection of fine particulate matter and vapor-phase trace metals. The objective of this project is to develop a highly reliable advanced hybrid particulate collector (AHPC) that can provide > 99.99 % particulate collection efficiency for all particle sizes between 0.01 and 50 14m, is applicable for use with all U.S. coals, and is cost-0443competitive with existing technologies. Phase I of the project is organized into three tasks: Task I - Project Management, Reporting, and Subcontract Consulting Task 2 - Modeling, Design, and Construction of 200-acfm AHPC Model Task 3 - Experimental Testing and Subcontract Consulting

  14. Mode-I-crack compression modeling and numerical simulation for evaluation of in-situ stress around advancing coal workfaces

    Institute of Scientific and Technical Information of China (English)

    LIU Wei-qun; ZHU Li

    2009-01-01

    The relatively high stress probably leads to generation of a fractured or even instable area around a working coalface. Also, the generated weak area often evolves into an easy-infiltrating field of water/gas to greatly increase probability of accident occurrence. To reveal the distribution of high stress around working faces, we put forward the mode-I-crack compression model. In this model, the goaf following a working face is regarded as a mode-I crack in an infinite plate, and the self-gravity of overlaying strata is transformed into an uniform pressure applied normal to the upper edge of the model crack. Solving this problem is based on the Westergaard complex stress function. For comparison, the software RFPA-2D is also employed to simulate the same mining problem, and furthermore extendedly to calculate the stress interference induced by the simultaneous advances of two different working faces. The results show that, the area close to a working face or the goaf tail has the maximum stress, and the stress is distributed directly proportional to the square root of the advance and inversely proportional to the square root of the distance to the working face. The simultaneous advances of two neighboring working faces in different horizontals can lead to extremely high resultant stress in an interference area.

  15. Fiscal 1997 technological survey report. Engineer exchange project - coal mine technological field (Advanced coal producing country survey - U.S.A. survey); 1997 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) senshin santankoku chosa. Beikoku chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    While the introduction and adaptation of the Longwall excavation technology were carried forward for coal producing countries in the Pacific region, U.S.A. information was collected by making tours of coal mines in the West and Washington/Colorado/Utah States, with the intention of ascertaining technological trend so as to carry out efficient technological transfer, and for the purpose of replenishing the contents and contributing to the smooth implementation of the engineer exchange project in 'coal mine technological field'. The coal reserves are 400 billion tons, with 840 million tons produced and with 80 million tons exported; not less than 56% of the U.S. domestic electricity rests on coal. Production by open-pit mining is the majority while the output by underground mining is 38%; the Longwall method has increased as a digging method, taking 18% of all digging output. The productivity is 4.24 ton/person per day and ranks as the world highest. The coal mining technological trend in the U.S. can be summarized as follows. The coal mining output in the West is increasing, with the number of mines decreasing, so that the output per mine is increasing. With the output ratio by open-pit mining increasing, the digging method in the mine is being changed to the Longwall. (NEDO)

  16. 煤矿企业ERP系统分析与设计%ERP System Analysis and Design of Coal Mining Enterprises

    Institute of Scientific and Technical Information of China (English)

    胡霞; 周敏; 李爽; 慕龙蛟

    2013-01-01

      advanced ERP management ideas and methods for the status quo of China's coal mines, coal mines of information processing, to strengthen the overall management of the coal mine in China, so that the transition from extensive management to fine management. Focus on analysis of the coal mining enterprises to build ideas and ways of ERP, as well as specific constitution system.%  针对我国煤矿的现状,采用先进的ERP管理思想及方法,对煤矿进行信息化处理,加强我国煤矿的整体管理,使其由粗放式管理向精细化管理转变。重点分析了煤矿企业进行ERP构建的思路及方式,以及具体的构成体系等。

  17. Bench-scale Development of an Advanced Solid Sorbent-based CO2 Capture Process for Coal-fired Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, Thomas [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Kataria, Atish [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Soukri, Mustapha [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Farmer, Justin [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Mobley, Paul [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Tanthana, Jak [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Wang, Dongxiang [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Wang, Xiaoxing [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Song, Chunshan [Research Triangle Institute (RTI), Research Triangle Park, NC (United States)

    2015-12-31

    It is increasingly clear that CO2 capture and sequestration (CCS) must play a critical role in curbing worldwide CO2 emissions to the atmosphere. Development of these technologies to cost-effectively remove CO2 from coal-fired power plants is very important to mitigating the impact these power plants have within the world’s power generation portfolio. Currently, conventional CO2 capture technologies, such as aqueous-monoethanolamine based solvent systems, are prohibitively expensive and if implemented could result in a 75 to 100% increase in the cost of electricity for consumers worldwide. Solid sorbent CO2 capture processes – such as RTI’s Advanced Solid Sorbent CO2, Capture Process – are promising alternatives to conventional, liquid solvents. Supported amine sorbents – of the nature RTI has developed – are particularly attractive due to their high CO2 loadings, low heat capacities, reduced corrosivity/volatility and the potential to reduce the regeneration energy needed to carry out CO2 capture. Previous work in this area has failed to adequately address various technology challenges such as sorbent stability and regenerability, sorbent scale-up, improved physical strength and attrition-resistance, proper heat management and temperature control, proper solids handling and circulation control, as well as the proper coupling of process engineering advancements that are tailored for a promising sorbent technology. The remaining challenges for these sorbent processes have provided the framework for the project team’s research and development and target for advancing the technology beyond lab- and bench-scale testing. Under a cooperative agreement with the US Department of Energy, and part of NETL’s CO2 Capture Program, RTI has led an effort to address and mitigate the challenges associated with solid sorbent CO2 capture. The overall objective

  18. Fine Particles Formation During O2/CO2 Combustion of Low-rank Coal%低阶煤O2/CO2气氛下燃烧生成颗粒物的特性

    Institute of Scientific and Technical Information of China (English)

    汪应红; 王群英; 付晓恒

    2012-01-01

    选取了2种低阶煤在不同气氛下沉降炉中进行燃烧实验,产生的灰颗收集到粒旋风分离器和低压冲击器中,利用透射电子显微镜和扫描电镜分析亚微米颗粒和超微米颗粒的形态,利用扫描电镜能量色散谱仪联用,透射电子显微镜能量色散谱仪联用和计算机控制的扫描电镜分析灰颗粒的化学元素组成.研究结果表明:O2/CO2燃烧改变超细颗粒物的大小分布和灰中元素的浓度分布,但没有改变细颗粒的生成机制.对于含有更多有机结构矿物质的褐煤,O2/CO2燃烧提高了Fe、Na/K、A1和Si的气化程度,也因此增加了亚微颗粒的浓度,而且褐煤中的Fe元素的气化较为特殊,O2/CO2燃烧氧气浓度的增加提高了Fe气化后在其他粒子上的附着.%Two kinds of typical low-rank coal were burned in a drop tube furnace under different atmosphere. The produced particulate matters(PM) were collected by the cyclone and low pressure impactor(LPI). Transmission electron microscopy(TEM) and scanning electron microscope (SEM) were used to identify the morphology of the super-micron and submicron PM. SEM with an energy dispersive X-ray(SEM-EDX), TEM with an energy dispersive X-ray spectroscopy(TEM-EDS) and computer-controlled scanning electron microcopy(CCSEM) were applied to analyze the chemical composition in the ash. It has been confirmed that compared with air atmosphere, O2/CO2 atmosphere changes the generated fine ash particle size distribution and the concentration of the chemical composition, but the formation mechanisms are same for different atmosphere. For the case of the lignite with more amount of organic-associated minerals, O2/CO2 atmosphere increase the vaporization degree of Fe, Na/K sulfates, Al and Si, and thus increase the concentration of sub-micron particles. Also Fe is found to be a key element in the lignite. Oxy-fuel-combustion increases the attachment of vaporized Fe element to other particle.

  19. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quarterly report, November 1994--February 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    This second quarterly report describes work during the second three months of the University of Pittsburgh`s (Pitt`s) project on the {open_quotes}Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.{close_quotes} Participating with Pitt on this project are Dravo Lime Company (DLC), Mill Service, Inc. (MSI) and the Center for Hazardous Materials Research (CHMR). The report describes the activities of the project team during the reporting period. The principal work has focussed upon the acquisition of by-product samples and their initial analysis. Other efforts during the second quarter have been directed toward identifying the first hazardous waste samples and preparing for their treatment and analysis. Relatively little data has yet been collected. Major presentation of technical details and data will appear for the first time in the third quarterly report. The activity on the project during the second quarter of Phase One, as presented in the following sections, has fallen into seven areas: (1) Acquiring by-products, (2) Analyzing by-products, (3) Identifying, analyzing and treating suitable hazardous wastes, (4) Carrying out the quality assurance/quality control program, (5) Developing background, and (6) Initiating public relations

  20. Advanced treatment of biologically pretreated coal gasification wastewater using a novel anoxic moving bed biofilm reactor (ANMBBR)-biological aerated filter (BAF) system.

    Science.gov (United States)

    Zhuang, Haifeng; Han, Hongjun; Jia, Shengyong; Zhao, Qian; Hou, Baolin

    2014-04-01

    A novel system integrating anoxic moving bed biofilm reactor (ANMBBR) and biological aerated filter (BAF) with short-cut biological nitrogen removal (SBNR) process was investigated as advanced treatment of real biologically pretreated coal gasification wastewater (CGW). The results showed the system had efficient capacity of degradation of pollutants especially nitrogen removal. The best performance was obtained at hydraulic residence times of 12h and nitrite recycling ratios of 200%. The removal efficiencies of COD, total organic carbon, NH4(+)-N, total phenols and total nitrogen (TN) were 74.6%, 70.0%, 85.0%, 92.7% and 72.3%, the corresponding effluent concentrations were 35.1, 18.0, 4.8, 2.2 and 13.6mg/L, respectively. Compared with traditional A(2)/O process, the system had high performance of NH4(+)-N and TN removal, especially under the high toxic loading. Moreover, ANMBBR played a key role in eliminating toxicity and degrading refractory compounds, which was beneficial to improve biodegradability of raw wastewater for SBNR process.

  1. The feasibility of using combined TiO2 photocatalysis oxidation and MBBR process for advanced treatment of biologically pretreated coal gasification wastewater.

    Science.gov (United States)

    Xu, Peng; Han, Hongjun; Hou, Baolin; Zhuang, Haifeng; Jia, Shengyong; Wang, Dexin; Li, Kun; Zhao, Qian

    2015-01-01

    The study examined the feasibility of using combined heterogeneous photocatalysis oxidation (HPO) and moving bed biofilm reactor (MBBR) process for advanced treatment of biologically pretreated coal gasification wastewater (CGW). The results indicated that the TOC removal efficiency was significantly improved in HPO. Gas chromatography-mass spectrometry (GC-MS) analysis indicated that the HPO could be employed to eliminate bio-refractory and toxic compounds. Meanwhile, the BOD5/COD of the raw wastewater was increased from 0.08 to 0.49. Furthermore, in the integration of TiO2 photocatalysis oxidation and MBBR process, the effluent of COD, BOD5, TOC, NH4(+)-N and TN were 22.1 mg/L, 1.1 mg/L, 11.8 mg/L, 4.1mg/L and 13.7 mg/L, respectively, which all met class-I criteria of the Integrated Wastewater Discharge Standard (GB18918-2002, China). The total operating cost was 2.8CNY/t. Therefore, there is great potential for the combined system in engineering applications as a final treatment for biologically pretreated CGW.

  2. A novel integration of three-dimensional electro-Fenton and biological activated carbon and its application in the advanced treatment of biologically pretreated Lurgi coal gasification wastewater.

    Science.gov (United States)

    Hou, Baolin; Han, Hongjun; Zhuang, Haifeng; Xu, Peng; Jia, Shengyong; Li, Kun

    2015-11-01

    A novel integrated process with three-dimensional electro-Fenton (3D EF) and biological activated carbon (BAC) was employed in advanced treatment of biologically pretreated Lurgi coal gasification wastewater. SAC-Fe (sludge deserved activated carbon from sewage and iron sludge) and SAC (sludge deserved activated carbon) were used in 3D EF as catalytic particle electrodes (CPEs) and in BAC as carriers respectively. Results indicated that 3D EF with SAC-Fe as CPEs represented excellent pollutants and COLOR removals as well as biodegradability improvement. The efficiency enhancement attributed to generating more H2O2 and OH. The integrated process exhibited efficient performance of COD, BOD5, total phenols, TOC, TN and COLOR removals at a much shorter retention time, with the corresponding concentrations in effluent of 31.18, 6.69, 4.29, 17.82, 13.88mg/L and <20 times, allowing discharge criteria to be met. The integrated system was efficient, cost-effective and ecological sustainable and could be a promising technology for engineering applications.

  3. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quarterly report, May 1995--August 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-11-01

    This fourth quarterly report describes work done during the fourth three-month period of the University of Pittsburgh`s project on the {open_quotes}Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.{close_quote} Participating with the university on this project are Dravo Lime Company, Mill Service, Inc., and the Center for Hazardous Materials Research. This report describes the activities of the project team during the reporting period. The principal work has focussed upon the production of six sets of samples with high water content for solidification testing and the mixing of five dry samples for solidification testing by the Proctor method. Twenty-eight day compressive strengths are reported for five of the six sets of samples with high water content. The report also discusses completion of the format of the database and the inclusion in it of all data collected to date. Special reports presented during the quarter include the Continuation Application, a News Release, and modification to the Test Plan. Work is progressing on the NEPA report and the Topical Report. The activity on the project during the fourth quarter of Phase one, as presented in the following sections, has fallen into six major areas: (1) Completion of by-product evaluations, (2) Completion of analyses of six wastes, (3) Initiation of eleven solidification tests, (4) Continued extraction and extract analysis of solidified samples, (5) Development of the database, and (6) Production of reports.

  4. Application of Pulsed Electrical Fields for Advanced Cooling and Water Recovery in Coal-Fired Power Plant

    Energy Technology Data Exchange (ETDEWEB)

    Young Cho; Alexander Fridman

    2009-04-02

    The overall objective of the present work was to develop technologies to reduce freshwater consumption in a cooling tower of coal-based power plant so that one could significantly reduce the need of make-up water. The specific goal was to develop a scale prevention technology based an integrated system of physical water treatment (PWT) and a novel filtration method so that one could reduce the need for the water blowdown, which accounts approximately 30% of water loss in a cooling tower. The present study investigated if a pulsed spark discharge in water could be used to remove deposits from the filter membrane. The test setup included a circulating water loop and a pulsed power system. The present experiments used artificially hardened water with hardness of 1,000 mg/L of CaCO{sub 3} made from a mixture of calcium chloride (CaCl{sub 2}) and sodium carbonate (Na{sub 2}CO{sub 3}) in order to produce calcium carbonate deposits on the filter membrane. Spark discharge in water was found to produce strong shockwaves in water, and the efficiency of the spark discharge in cleaning filter surface was evaluated by measuring the pressure drop across the filter over time. Results showed that the pressure drop could be reduced to the value corresponding to the initial clean state and after that the filter could be maintained at the initial state almost indefinitely, confirming the validity of the present concept of pulsed spark discharge in water to clean dirty filter. The present study also investigated the effect of a plasma-assisted self-cleaning filter on the performance of physical water treatment (PWT) solenoid coil for the mitigation of mineral fouling in a concentric counterflow heat exchanger. The self-cleaning filter utilized shockwaves produced by pulse-spark discharges in water to continuously remove scale deposits from the surface of the filter, thus keeping the pressure drop across the filter at a relatively low value. Artificial hard water was used in the

  5. Residues from coal conversion and utilization: Advanced mineralogical characterization and disposed byproduct diagenesis. [Semiannual report, 1 Mar 1999--31 Aug 1999

    Energy Technology Data Exchange (ETDEWEB)

    Gregory J. McCarthy; Dean G. Grier

    2000-01-01

    The goal of the project is to learn more about the phenomenon of coal conversion byproduct (CCB) diagenesis, first described by this group and co-workers at UND EERC seven years ago. CCB diagenesis is a change in the mineralogy that occurs after some CCBs are disposed in a landfill or utilized for a civil engineering application. Regulatory environmental tests and civil engineering tests are typically performed on as-generated CCBs, or on CCBs hydrated and cured for relatively short periods such as 7 or 28 days. One would like to know whether the results of these short-term tests will be valid years later. A change in mineralogy means a gain, loss or chemical redistribution of major, minor and trace elements, and alteration of physical properties. To attain this goal, two objectives were defined: (1) to develop improved methodology for quantitating mineralogy of these complex crystalline phase assemblages, and (2) to investigate the phenomenon of CCB diagenesis further by studying materials recovered from disposal landfills or civil engineering works. Objective 1--Hydrated CCBs are chemically and mineralogically complex, which makes quantitative mineralogy determination by conventional X-ray diffraction unusable or unreliable. The whole-pattern Rietveld quantitative X-ray diffraction (RQXRD) method, however, can overcome many of the problems and seems well suited to improve reliability. Two tasks were defined in the proposal: Task 1--Completion by October 1997. Prepare a reference set of CCBs for use in developing Rietveld QXRD. The reference materials will come primarily from in-house samples of advanced coal technology byproducts. The work will include SEM/EMPA characterization at UND EERC. Task 2--Completion by October 1997. Develop protocols for Rietveld QXRD analysis of CCBs. Make CCB structure data and protocols available on a Website. Determine levels of sensitivity, precision, and accuracy. Objective 2--Five types of CCBs disposed in landfills were studied

  6. Advanced Dewatering Systems Development

    Energy Technology Data Exchange (ETDEWEB)

    R.H. Yoon; G.H. Luttrell

    2008-07-31

    A new fine coal dewatering technology has been developed and tested in the present work. The work was funded by the Solid Fuels and Feedstocks Grand Challenge PRDA. The objective of this program was to 'develop innovative technical approaches to ensure a continued supply of environmentally sound solid fuels for existing and future combustion systems with minimal incremental fuel cost.' Specifically, this solicitation is aimed at developing technologies that can (i) improve the efficiency or economics of the recovery of carbon when beneficiating fine coal from both current production and existing coal slurry impoundments and (ii) assist in the greater utilization of coal fines by improving the handling characteristics of fine coal via dewatering and/or reconstitution. The results of the test work conducted during Phase I of the current project demonstrated that the new dewatering technologies can substantially reduce the moisture from fine coal, while the test work conducted during Phase II successfully demonstrated the commercial viability of this technology. It is believed that availability of such efficient and affordable dewatering technology is essential to meeting the DOE's objectives.

  7. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20141574 Chen Hao(Exploration and Development Research Institute,Daqing Oilfield Company,Daqing 163712,China)High-Resolution Sequences and Coal Accumulating Laws in Nantun Formation of Huhe Lake Sag(Petroleum Geology&Oilfield Development in Daqing,ISSN1000-3754,CN23-1286/TQ,32(4),2013,p.15-19,5 illus.,15 refs.)Key words:coal accumulation regularity,coal

  8. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091159 Gao Yan(No.3 Prospecting Team of Anhui Bureau of Coal Geology,Suzhou 234000,China) Effect of Depositional Environment of Coal-Bearing Stratum on Major Coal Seams in Suntan Coalmine,Anhui Province(Geology of Anhui,ISSN 1005- 6157,CN34-1111/P,18(2),2008,p.114 -117,5 illus.,1 ref.,with English abstract)

  9. 瞬变电磁法在玉泉煤业超前探测中的应用%Transient electromagnetic method in yuquan coal mine the application of advanced detection

    Institute of Scientific and Technical Information of China (English)

    李明山

    2016-01-01

    "Follow up" geophysical prospecting, drilling ahead of validation, geochemical exploration of comprehensive detection program has become a mine water prevention and control of an important system. The coal mine roadway of geophysical exploration of advanced detection methods is more, this paper introduces the working principle of the transient electromagnetic method in advanced detection of underground and methods, and its application in yuquan coal roadway drivage application of advanced detection results.%“物探先行、钻探验证、化探跟进”的综合探测程序已成为矿井防治水一项重要制度。煤矿井下巷道超前探测的物探方法较多,本文介绍了瞬变电磁法在井下超前探测中的工作原理和方法,及其在玉泉煤业巷道掘进超前探测的应用成果。

  10. Coal: Energy for the future

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-01

    This report was prepared in response to a request by the US Department of energy (DOE). The principal objectives of the study were to assess the current DOE coal program vis-a-vis the provisions of the Energy Policy Act of 1992 (EPACT), and to recommend the emphasis and priorities that DOE should consider in updating its strategic plan for coal. A strategic plan for research, development, demonstration, and commercialization (RDD and C) activities for coal should be based on assumptions regarding the future supply and price of competing energy sources, the demand for products manufactured from these sources, technological opportunities, and the need to control the environmental impact of waste streams. These factors change with time. Accordingly, the committee generated strategic planning scenarios for three time periods: near-term, 1995--2005; mid-term, 2006--2020; and, long-term, 2021--2040. The report is divided into the following chapters: executive summary; introduction and scope of the study; overview of US DOE programs and planning; trends and issues for future coal use; the strategic planning framework; coal preparation, coal liquid mixtures, and coal bed methane recovery; clean fuels and specialty products from coal; electric power generation; technology demonstration and commercialization; advanced research programs; conclusions and recommendations; appendices; and glossary. 174 refs.

  11. Ultra-fine dewatering

    Energy Technology Data Exchange (ETDEWEB)

    Patwardhan, A.; Chugh, Y.P.; Arnold, B.J.; Terblanche, A.N. [Southern Illinois University, IL (US)

    2004-12-01

    The paper assesses the results from a filter press study. They demonstrate the success of a low-cost, high-efficiency filter press for dewatering column flotation clean coal products from two coal mines. A Tecnicas Hidraulicas Filter Press and a PrepTech Inc. turbo column were used for in-plant testing at a mine extracting Illinois No. 6 seam coal and another extracting Illinois No. 5 seam coal. Based on the results, an increase in profitability of US $ 900,000 per year is projected from full-scale implementation of the technology at No. 5 seam coal mine. 6 figs.

  12. Possibilities of working thick brown coal seams in the Stara Jama mine of Zenica mines by sublevel working methods applying self-advancing Westfalia-Luenen powered supports, type B. S. 2. 1 and I. B. S. 2. 2

    Energy Technology Data Exchange (ETDEWEB)

    Bijelic, V.; Ivkovic, M.; Slijepcevic, S.; Krizan, D.

    1980-01-01

    This paper describes the properties of 9 exploitable coal seams of Zenica colliery. Two of them have been intensively exploited over many years. It outlines the development of working methods from room and pillar up to fully mechanized longwall mining. As final result of the efforts made in order to improve the productivity of longwall mining a modified type of Westfalia-Luenen self-advancing powered support is described. The results achieved with this support are shown in a table. (9 refs.) (In Serbo-Croatian).

  13. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20131668 Chang Huizhen(Key Laboratory of Coalbed Methane Resources and Reservoir Formation Process,CUMT,Ministry of Edu-cation,School of Resource and Earth Science,China University of Mining and Technology,Xuzhou 221008,China);Qin Yong Differences in of Pore Structure of Coals and Their Impact on the Permeability of Coals from the

  14. Advanced bioreactor concepts for gaseous substrates: Conversion of synthesis gas to liquid fuels and removal of SO{sub x} and NO{sub x} from coal combustion gases. CRADA final report

    Energy Technology Data Exchange (ETDEWEB)

    Kaufman, E.N.; Selvaraj, P.T.

    1997-10-01

    The purpose of the proposed research program was the development and demonstration of a new generation of gaseous substrate-based bioreactors for the production of liquid fuels from coal synthesis gas and the removal of NO{sub x} and SO{sub x} species from coal combustion flue gas. This study addressed the further investigation of optimal bacterial strains, growth media and kinetics for the biocatalytic conversion of coal synthesis gas to liquid fuel such as ethanol and the reduction of gaseous flue gas constituents. The primary emphasis was on the development of advanced bioreactor systems coupled with innovative biocatalytic systems that will provide increased productivity under controlled conditions. It was hoped that this would result in bioprocessing options that have both technical and economic feasibility, thus, ensuring early industrial use. Predictive mathematical models were formulated to accommodate hydrodynamics, mass transport, and conversion kinetics, and provide the data base for design and scale-up. The program was separated into four tasks: (1) Optimization of Biocatalytic Kinetics; (2) Development of Well-mixed and Columnar Reactors; (3) Development of Predictive Mathematical Models; and (4) Industrial Demonstration. Research activities addressing both synthesis gas conversion and flue gas removal were conducted in parallel by BRI and ORNL respectively.

  15. A Synergistic Combination of Advanced Separation and Chemical Scale Inhibitor Technologies for Efficient Use of Imparied Water As Cooling Water in Coal-based Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Jasbir Gill

    2010-08-30

    Nalco Company is partnering with Argonne National Laboratory (ANL) in this project to jointly develop advanced scale control technologies that will provide cost-effective solutions for coal-based power plants to operate recirculating cooling water systems at high cycles using impaired waters. The overall approach is to use combinations of novel membrane separations and scale inhibitor technologies that will work synergistically, with membrane separations reducing the scaling potential of the cooling water and scale inhibitors extending the safe operating range of the cooling water system. The project started on March 31, 2006 and ended in August 30, 2010. The project was a multiyear, multi-phase project with laboratory research and development as well as a small pilot-scale field demonstration. In Phase 1 (Technical Targets and Proof of Concept), the objectives were to establish quantitative technical targets and develop calcite and silica scale inhibitor chemistries for high stress conditions. Additional Phase I work included bench-scale testing to determine the feasibility of two membrane separation technologies (electrodialysis ED and electrode-ionization EDI) for scale minimization. In Phase 2 (Technology Development and Integration), the objectives were to develop additional novel scale inhibitor chemistries, develop selected separation processes, and optimize the integration of the technology components at the laboratory scale. Phase 3 (Technology Validation) validated the integrated system's performance with a pilot-scale demonstration. During Phase 1, Initial evaluations of impaired water characteristics focused on produced waters and reclaimed municipal wastewater effluents. Literature and new data were collected and evaluated. Characteristics of produced waters vary significantly from one site to another, whereas reclaimed municipal wastewater effluents have relatively more uniform characteristics. Assessment to date confirmed that calcite and silica

  16. Appalachian clean coal technology consortium

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, R.-H.; Basim, B.; Luttrell, G.H.; Phillips, D.I. [Virginia Polytechnic Inst., Blacksburg, VA (United States); Jiang, D.; Tao, D.; Parekh, B.K. [Kentucky Univ., Lexington, KY (United States); Meloy, T. [West Virginia Univ., Morgantown, WV (United States)

    1997-01-28

    Novel chemicals that can be used for increasing the efficiency of fine coal dewatering was developed at Virginia Tech. During the past quarter, Reagent A was tested on three different coal samples in laboratory vacuum filtration tests. these included flotation products from Middle Fork plant, Elkview Mining Company, and CONSOL, Inc. the tests conducted with the Middle Fork coal sample (100 mesh x 0) showed that cake moisture can be reduced by more than 10% beyond what can be achieved without using dewatering aid. This improvement was achieved at 1 lb/ton of Reagent A and 0.1 inch cake thickness. At 0. 5 inches of cake thickness, this improvement was limited to 8% at the same reagent dosage. the results obtained with the Elkview coal (28 mesh x 0) showed similar advantages in using the novel dewatering aid. Depending on the reagent dosage, cake thickness, drying cycle time and temperature, it was possible to reduce the cake moisture to 12 to 14% rage. In addition to achieving lower cake moisture, the use of Reagent A substantially decreased the cake formation time, indicating that the reagent improves the kinetics of dewatering, The test results obtained with CONSOL coal were not as good as with the other coals tested in the present work, which may be attributed to possible oxidation and/or contamination.

  17. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20111053 Chen Jian(School of Earth and Environment,Anhui University of Science and Technology,Huainan 232001,China);Liu Wenzhong Organic Affinity of Trace Elements in Coal from No.10 Coal-Bed at Western Huagou,Guoyang(Coal Geology & Exploration,ISSN1001-1986,CN61-1155/P,38(4),2010,p.16-20,24,3 illus.,3 tables,19 refs.)Key words:coal,minor elements,Anhui Province In order to study the organic affinity of trace elements in coal from No.10 coal-bed at western Huagou,Guoyang,10 borehole samples were collected at exploration area of Huaibei mining area.The contents of 12 kinds of trace elements were determined by the inductively coupled plasma mass spectrometry(ICP-MS),the total organic carbon(TOC)of coal was determined by LECO carbon and sulfur analyzer,and the organic affinity of trace elements were deduced from the correlations between contents and TOCs.The results showed that the contents of V,Cr,Co,Ni,Mo,Cd,Sb,Pb and Zn were lower than

  18. Flocculation, hydrophobic agglomeration and filtration of ultrafine coal

    Science.gov (United States)

    Yu, Zhimin

    In coal preparation plant circuits, fine coal particles are aggregated either by oil agglomeration or by flocculation. In a new hydrophobic agglomeration process, recently developed hydrophobic latices are utilized. While the selectivity of such aggregation processes determines the beneficiation results, the degree of aggregation has a strong effect on fine coal filtration. The aim of this research was to study the fundamentals and analyze the common grounds for these processes, including the potential effect of the coal surface properties. The selective flocculation tests, in which three types of coal, which differed widely in surface wettability, and three additives (hydrophobic latices, a semi-hydrophobic flocculant and a typical hydrophilic polyelectrolyte) were utilized, showed that coal wettability plays a very important role in selective flocculation. The abstraction of a hydrophobic latex on coal and silica revealed that the latex had a much higher affinity towards hydrophobic coal than to hydrophilic mineral matter. As a result, the UBC-1 hydrophobic latex flocculated only hydrophobic coal particles while the polyelectrolyte (PAM) flocculated all the tested coal samples and minerals, showing no selectivity in the fine coal beneficiation. The oil agglomeration was tested using kerosene emulsified with various surfactants (e.g. cationic, anionic and non-ionic). Surfactants enhance not only oil emulsification, hence reducing oil consumption (down to 0.25--0.5%), but also entirely change the electrokinetic properties of the droplets and affect the interaction energy between oil droplets and coal particles. Consequently, the results found in the course of the experimental work strongly indicate that even oxidized coals can be agglomerated if cationic surfactants are used to emulsify the oil. Oil agglomeration of the Ford-4 ultrafine coal showed that even at extremely low oil consumption (0.25 to 0.5%), a clean coal product with an ash content around 5% at over

  19. 巷道振波超前探测技术在煤矿巷道掘进中的应用%Application of Advance Detection Technology of Tunnel Vibration Wave Roadway Excavation in Coal Mine

    Institute of Scientific and Technical Information of China (English)

    罗鹏; 张恒; 常永峰

    2016-01-01

    本文主要介绍了巷道振波超前探测技术在煤矿巷道掘进的实践应用,主要是利用矿井震波超前探测法控制巷道前方的构造发育情况,减少巷道的报废,为巷道的设计修改和安全掘进提供地质资料。%This paper mainly introduces the application of the advanced detection technology of tunnel vibration wave roadway tunneling in coal mine, mainly uses mine seismic advanced sensor to development of the front structure of the roadway, to reduce roadway scrap and provide geological data for design modification and safety excavation of roadway.

  20. Coal Utilization in Schools: Issues and Answers.

    Science.gov (United States)

    Pusey, Robert H.

    Coal, at one-third the cost of natural gas and one-fifth the cost of oil, is our cheapest source of energy and is also in abundant supply. Because of significant technological advances, coal-fired equipment now approaches the clean and automatic operational characteristics of gas- and oil-fired boilers. For these reasons, and because schools are…

  1. Characterization and supply of coal based fuels

    Energy Technology Data Exchange (ETDEWEB)

    1992-06-01

    Studies and data applicable for fuel markets and coal resource assessments were reviewed and evaluated to provide both guidelines and specifications for premium quality coal-based fuels. The fuels supplied under this contract were provided for testing of advanced combustors being developed under Pittsburgh Energy Technology Center (PETC) sponsorship for use in the residential, commercial and light industrial (RCLI) market sectors. The requirements of the combustor development contractors were surveyed and periodically updated to satisfy the evolving needs based on design and test experience. Available coals were screened and candidate coals were selected for further detailed characterization and preparation for delivery. A team of participants was assembled to provide fuels in both coal-water fuel (CWF) and dry ultrafine coal (DUC) forms. Information about major US coal fields was correlated with market needs analysis. Coal fields with major reserves of low sulfur coal that could be potentially amenable to premium coal-based fuels specifications were identified. The fuels requirements were focused in terms of market, equipment and resource constraints. With this basis, the coals selected for developmental testing satisfy the most stringent fuel requirements and utilize available current deep-cleaning capabilities.

  2. Fine-mapping alleles for body weight in LG/J × SM/J F₂ and F(34) advanced intercross lines.

    Science.gov (United States)

    Parker, Clarissa C; Cheng, Riyan; Sokoloff, Greta; Lim, Jackie E; Skol, Andrew D; Abney, Mark; Palmer, Abraham A

    2011-10-01

    The present study measured variation in body weight using a combined analysis in an F(2) intercross and an F(34) advanced intercross line (AIL). Both crosses were derived from inbred LG/J and SM/J mice, which were selected for large and small body size prior to inbreeding. Body weight was measured at 62 (± 5) days of age. Using an integrated GWAS and forward model selection approach, we identified 11 significant QTLs that affected body weight on ten different chromosomes. With these results we developed a full model that explained over 18% of the phenotypic variance. The median 1.5-LOD support interval was 5.55 Mb, which is a significant improvement over most prior body weight QTLs. We identified nonsynonymous coding SNPs between LG/J and SM/J mice in order to further narrow the list of candidate genes. Three of the genes with nonsynonymous coding SNPs (Rad23b, Stk33, and Anks1b) have been associated with adiposity, waist circumference, and body mass index in human GWAS, thus providing evidence that these genes may underlie our QTLs. Our results demonstrate that a relatively small number of loci contribute significantly to the phenotypic variance in body weight, which is in marked contrast to the situation in humans. This difference is likely to be the result of strong selective pressure and the simplified genetic architecture, both of which are important advantages of our system.

  3. Fine-mapping quantitative trait loci affecting murine external ear tissue regeneration in the LG/J by SM/J advanced intercross line.

    Science.gov (United States)

    Cheverud, J M; Lawson, H A; Bouckaert, K; Kossenkov, A V; Showe, L C; Cort, L; Blankenhorn, E P; Bedelbaeva, K; Gourevitch, D; Zhang, Y; Heber-Katz, E

    2014-05-01

    External ear hole closure in LG/J mice represents a model of regenerative response. It is accompanied by the formation of a blastema-like structure and the re-growth of multiple tissues, including cartilage. The ability to regenerate tissue is heritable. An F34 advanced intercross line of mice (Wustl:LG,SM-G34) was generated to identify genomic loci involved in ear hole closure over a 30-day healing period. We mapped 19 quantitative trait loci (QTL) for ear hole closure. Individual gene effects are relatively small (0.08 mm), and most loci have co-dominant effects with phenotypically intermediate heterozygotes. QTL support regions were limited to a median size of 2 Mb containing a median of 19 genes. Positional candidate genes were evaluated using differential transcript expression between LG/J and SM/J healing tissue, function analysis and bioinformatic analysis of single-nucleotide polymorphisms in and around positional candidate genes of interest. Analysis of the set of 34 positional candidate genes and those displaying expression differences revealed over-representation of genes involved in cell cycle regulation/DNA damage, cell migration and adhesion, developmentally related genes and metabolism. This indicates that the healing phenotype in LG/J mice involves multiple physiological mechanisms.

  4. Meeting processing challenges in clean coal utilization

    Energy Technology Data Exchange (ETDEWEB)

    Chugh, Y.P.; Patwardhan, A.; Barnwal, J.P. [Southern Illinois University, Carbondale, IL (United States). Dept. of Mining and Mineral Resources Engineering

    2003-02-01

    The paper identifies some of the major challenges facing processing for clean coal utilization today. Some of the ongoing research at Southern Illinois University in the areas of plant optimization, fine coal cleaning and dewatering, fine coal-water slurry combustion, development of multiple products and mine-mouth utilization for lower grade products, and co-management of coal processing wastes and coal combustion byproducts underground, or as a cover material suitable for vegetation in surface mine reclamation is approaching commercialization. Additional research has been initiated recently in low cost desulfurization for SOx reduction, and/or reducing scrubbing costs. An integrated approach to evaluating processing unit operation for enhancing overall profitability of a mining complex is paying dividends. The approach is a good tool to assess role of processing for clean coal utilization in any setting. The authors have attempted to demonstrate its use for Indian coals. They plan to develop a computer program for making this integrated assessment approach more user friendly. 33 refs., 4 figs., 10 tabs.

  5. Feasibility study for an advanced coal fired heat exchanger/gas turbine topping cycle for a high efficiency power plant. Technical report, January 1, 1993--March 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Zhao, Y.; Buggeln, R.C.; Shamroth, S.J.

    1993-04-01

    The overall objective of this project is to prove the feasibility of AFR`s concepts for a high efficiency coal-fired generating plant using the REACH/Exchanger concept to power an externally fired gas turbine. The computational REACH reactor was modeled with PCGC-2. The reactor geometry, inlet flow rates and configurations were investigated via modeling in order to get an optimum operation condition, with which a thorough coal and gas mixture and a required coal particle dispersion can both be achieved. This is to ensure the efficiencies of both coal combustion and aerodynamic cleaning. The aerodynamic cleaning effect of the tertiary air injection was modeled with CELMINT. Various injection schemes investigated show the dramatic impact of the tertiary air and the injection positions on the overall air flow pattern in the reactor which is one of the major influencing factors on the particle dispersion. It is clearly demonstrated that an optimum tertiary injection scheme with a reasonable flow rate is able to keep the heat exchange tubes from particle fouling.

  6. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quarterly report, March 30, 1996--June 30, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Cobb, J.T. Jr.; Neufeld, R.D.; Blachere, J.R. [and others

    1998-04-01

    Progress is described on the use of by-products form clean coal technologies for the treatment of hazardous wastes. During the third quarter of Phase 2, work continued on evaluating Phase 1 samples (including evaluation of a seventh waste), conducting scholarly work, preparing for field work, preparing and delivering presentations, and making additional outside contacts.

  7. Enhancement of surface properties for coal beneficiation. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Chander, S.; Aplan, F.F.

    1992-01-30

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  8. CoalVal-A coal resource valuation program

    Science.gov (United States)

    Rohrbacher, Timothy J.; McIntosh, Gary E.

    2010-01-01

    CoalVal is a menu-driven Windows program that produces cost-of-mining analyses of mine-modeled coal resources. Geological modeling of the coal beds and some degree of mine planning, from basic prefeasibility to advanced, must already have been performed before this program can be used. United States Geological Survey mine planning is done from a very basic, prefeasibility standpoint, but the accuracy of CoalVal's output is a reflection of the accuracy of the data entered, both for mine costs and mine planning. The mining cost analysis is done by using mine cost models designed for the commonly employed, surface and underground mining methods utilized in the United States. CoalVal requires a Microsoft Windows? 98 or Windows? XP operating system and a minimum of 1 gigabyte of random access memory to perform operations. It will not operate on Microsoft Vista?, Windows? 7, or Macintosh? operating systems. The program will summarize the evaluation of an unlimited number of coal seams, haulage zones, tax entities, or other area delineations for a given coal property, coalfield, or basin. When the reader opens the CoalVal publication from the USGS website, options are provided to download the CoalVal publication manual and the CoalVal Program. The CoalVal report is divided into five specific areas relevant to the development and use of the CoalVal program: 1. Introduction to CoalVal Assumptions and Concepts. 2. Mine Model Assumption Details (appendix A). 3. CoalVal Project Tutorial (appendix B). 4. Program Description (appendix C). 5. Mine Model and Discounted Cash Flow Formulas (appendix D). The tutorial explains how to enter coal resource and quality data by mining method; program default values for production, operating, and cost variables; and ones own operating and cost variables into the program. Generated summary reports list the volume of resource in short tons available for mining, recoverable short tons by mining method; the seam or property being mined

  9. Recent trend in coal utilization technology. Coal utilization workshop

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Chon Ho; Son, Ja Ek; Lee, In Chul; Jin, Kyung Tae; Kim, Seong Soo [Korea Inst. of Energy Research, Taejon (Korea, Republic of)

    1995-12-01

    The 11th Korea-U.S.A. joint workshop on coal utilization technology was held in somerset, Pennsylvania, U.S.A. from october 2 to 3, 1995. In the opening ceremony, Dr.C. Low-el Miller, associate deputy assistant secretary of office of clean coal technology, U.S.DOE, gave congratulatory remarks and Dr. Young Mok Son, president of KIER, made a keynote address. In this workshop, 30 papers were presented in the fields of emission control technology, advanced power generation systems, and advanced coal cleaning and liquid fuels. Especially, from the Korean side, not only KIER but also other private research institutes and major engineering companies including KEPCO, Daewoo Institute of Construction Technology, Jindo Engineering and Construction Co. Daewoo Institute for Advanced Engineering and universities participated in this workshop, reflecting their great interests. Attendants actively discussed about various coal utilization technologies and exchanged scientific and technical information on the state-of-art clean coal technologies under development. (author)

  10. Fiscal 1996 survey of the base arrangement promotion for foreign coal import. Model survey for promotion of advanced coal utilization (survey of a model project to convert sludge into fuel by low grade coal); 1996 nendo kaigaitan yunyu kiban seibi sokushin chosa. Sekitan kodo riyo sokushin model chosa (teihin`itan ni yoru odei nenryoka model jigyo chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The paper made an investigation in the Tohoku district, mainly in Akita prefecture, into whether or not a technology of recycling sewage sludge using pulverized coal will be successful as business. Akita prefecture comparatively generates a little sewage sludge and secures reclaimed land for disposal, and is not in a situation where any immediate measures for disposal of sewage sludge should be taken. However, in Akita, there are clearly seen the attitude toward craving the effective use of sewage sludge and great interest in the pulverized coal law. Upon commercializing, the trially calculated yield was approximately 7%. The economical efficiency of the pulverized coal law is much dependent upon the coal price, but the coal having special specifications is not needed. Therefore, it is possible to select it from among overseas lignite, brown coal, etc. from viewpoints of the price and stable supply. The evaluation of the sludge fuel produced is an important factor for successful recycling. As to the quantity of chlorine contained in coal, particularly, strong measures for it should be taken since chlorine is related with the corrosion problem of incinerating facilities and finally with the quality control of cement to be recycled. 36 figs., 50 tabs.

  11. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2003-10-20

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  12. Coal mining: coal in Spain

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Arguelles Martinez, A.; Lugue Cabal, V.

    1984-01-01

    The Survey of Spanish Coal Resources published by the Centre for Energy Studies in 1979 is without doubt the most serious and full study on this subject. The coal boom of the last few years and the important role it will play in the future, as well as the wealth of new information which has come to light in the research carried out in Spanish coalfields by both the public and private sector, prompted the General Mine Management of the Ministry of Industry and Energy to commission IGME to review and update the previous Survey of Spanish Coal Resources of November 1981.

  13. Proceedings of the Third APEC Coal Flow Seminar

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-11-26

    This proceedings includes papers presented at the Third APEC Coal Flow Seminar held at Terrigal, Australia in November, 1996. Keynote addresses, three sessions for discussions, and presentations by members economies are included. `Future investment requirements for coal in the APEC region,` `Barriers to investment across the APEC region coal chain,` `International commercial financier`s perspective on coal,` `The role of advanced coal technologies in greenhouse gas abatement and financing its development and uptake,` `Investment issues affecting the uptake of clean coal technology (CCT),` `Role of multilateral development banks in financing CCT to reduce greenhouse gas emissions,` and `Strategies for addressing regional coal issues` were presented as keynote addresses. In the sessions, investment issues facing coal power development, financing coal and investment, and investment strategies for CCT were discussed. 58 refs., 42 figs., 40 tabs.

  14. Blended coals for improved coal water slurries

    Institute of Scientific and Technical Information of China (English)

    GU Tian-ye; WU Guo-guang; LI Qi-hui; SUN Zhi-qiang; ZENG Fang; WANG Guang-you; MENG Xian-liang

    2008-01-01

    Three coal samples of different ranks were used to study the effect of coal blending on the preparation of Coal Water Slurry (CWS). The results show that by taking advantage of two kinds of coal, the coal concentration in slurry made from hard-to-pulp coal can be effectively improved and increased by 3%-5% generally. DLT coal (DaLiuTa coal mine) is very poor in slurryability and the stability and rheology of the resulting slurry are not very good. When the amount of easily slurried coal is more than 30%, all properties of the CWS improve and the CWS meets the requirements for use as fuel. Coalification, porosity, surface oxygenic functional groups, zeta potential and grindability have a great effect on the performance of blended coal CWS. This leads to some differences in performance between the slurry made from a single coal and slurry made from blended coal.

  15. Coal in Asia-Pacific. Vol.9. No.1. Third APEC Coal Flow Seminar

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-02-01

    The Third APEC (Asia-Pacific Economic Cooperation) Coal Flow Seminar was held featuring regional investment strategies for coal, power infrastructure, and technology transfer in Terrigal, Australia in 26-28, November, 1996. This publication introduces the summary and the papers presented for the keynote speeches and the panels of this seminar. For the keynote speeches, `Investment requirements for steaming coal supplies in APEC member economies,` `Barriers to investment across the APEC regional coal chain,` `The role of advanced coal technologies in greenhouse gas abatement and financing its development and uptake,` `Investment in clean coal power plants,` and `Role of multilateral development banks in financing clean coal technologies to reduce greenhouse gas emission` were presented. In addition, summary and papers describing individual situations of APEC member economies are introduced. 59 refs., 42 figs., 37 tabs.

  16. Experimental study on promotion of coal combustion fine particles acoustic agglomeration removal by using wetting agents%润湿剂促进燃煤细颗粒声波团聚脱除的实验研究

    Institute of Scientific and Technical Information of China (English)

    颜金培; 陈立奇; 杨林军

    2014-01-01

    在声波团聚室中研究了润湿剂液滴与细颗粒碰撞团聚脱除特性,提出了一种利用润湿剂促进细颗粒在声波场中捕集的新方法。结果表明,不同润湿剂溶液对细颗粒在声波场中的团聚脱除效果存在较大差异,采用 JFC 和 FS-310润湿剂溶液时,细颗粒分级脱除效率与采用水时的分级脱除效率相近。而 SDS 和 Silanol w22溶液,则可有效提高细颗粒在各粒径段的分级脱除效率。细颗粒在声波场中的脱除效率与润湿剂润湿性能具有很好的相关性,随润湿剂对细颗粒相对接触角增大而降低,在声压级为150 dB 时,相对接触角由83°降低到0°,细颗粒脱除效率提高了18%,在无声场作用下,脱除效率仅提高了5%。细颗粒脱除效率随声压级的增大而提高,在低声压级条件下,添加润湿剂可有效提高细颗粒脱除效率,声压级在130 dB时,添加 SDS 溶液液滴后细颗粒脱除效率比声场单独作用时的脱除效率提高了25%。表明添加润湿剂可有效提高细颗粒在声波场中的团聚脱除效率,实现在低声压级条件下,获得高的细颗粒脱除效率。%The characteristics of agglomeration removal between wetting agent droplets and fine particles wereinvestigated in an acoustic agglomeration chamber. A novel technique using wetting agents to promote the fine particle capture by acoustic agglomeration was presented. The experimental results show that the type of wetting agent has a significant effect on the acoustic agglomeration of fine particles. The particle stage removal efficiencies using JFC and FS-310 are similar to that using plain water droplets, but the removal efficiencies bySDS and Silanol w 22 are much higher than that using water droplets. Fine particle removal efficiency in the acoustic field correlates well with the wettability of wetting agents, which decreases with increasing the relativecontact angle of wetting agents

  17. Quarry fines and waste

    OpenAIRE

    Mitchell, Clive

    2009-01-01

    Quarry fines and waste are an innevitable consequence of the extraction, processing and transportation of construction aggregate. This article summarises the production of quarry fines, detailing where and how much is produced and how the industry is tackling quarry fines minimisation.

  18. Kinetic comparison of biological and conventional flotation of coal

    Energy Technology Data Exchange (ETDEWEB)

    Amini, E.; Oliazadeh, M.; Kolahdoozan, M. [University of Queensland, Brisbane, Qld. (Australia)

    2009-03-15

    Froth flotation is commonly used in coal processing to selectively recover the organic material (coal) from inorganic waste material. Tabas coal, located in east Iran, contains fine disseminated pyrite which is floated with coal during flotation, and hence decreasing the quality of the final concentrate. Reagents, such as sodium cyanide, are typically added to depress pyrite. Due to the toxicity of cyanide, alternative strategies for depressing pyrite flotation are being investigated. In this paper the metallurgical performance of Tabas coal treated with sodium cyanide is compared to that of Tabas coal which has undergone bacterial treatment using Acidithiobacillus ferrooxidans. Results indicate that bacterial treatment decreases the flotation rate of pyrite and improves the selectivity between coal and gangue. The possibility of using bacteria in place of toxic chemicals such as cyanide has significant environmental benefit.

  19. Synfuels from coal - an environmentally sound approach

    Energy Technology Data Exchange (ETDEWEB)

    Marriott, J.N. (Sasol Technology Ltd (South Africa))

    1991-01-01

    The Sasol oil from coal process is a two stage process in which indirect liquefaction is used to convert coal to synthesis gas which is then reacted in a second stage to produce hydrocarbon liquids. The process has been used for over 35 years, and has been advanced and modernized to provide almost the same degree of environmental friendliness as some of the new clean coal technologies. A further advantage of the production of transport fuels from coal is that all sulphur is removed prior to processing and the product petrol and diesel fuels are fully sulphur free. Sasol has now diversified into added value products, and today's coal refineries co-produce power, steam, fuel and chemicals from coal. 2 tabs.

  20. Pneumatic pulse stratification in the gravimetric concentration of fines and its application to coal. La estratificacion neumatica-pulsante en la concentracion gravimetrica de finos y su aplicacion a los carbones

    Energy Technology Data Exchange (ETDEWEB)

    Alfaro Drets, J.; Lopez Santiago, F. (Instituto Geologico y Minero de Espana, Madrid (Spain))

    1988-01-01

    The problem concerning pneumatic concentration of coal slices has not been solved yet using conventional methods. The hydraulic systems in spiskasten, spirals, shaking tables and flotation create the need of clarifying the water for its reutilization or pouring. This problem get worse in the case of lignites due to their high content of clay, their low economic value and the presence of pyrites, a polluting element in thermal plants. The use of pneumatic tables is limited to sizes below 3 mm; however, the presence of links between carbon-slate and carbon-pyrites condition their grades of definition in larger sizes. To solve this problem Rodriguez Baltar designed a pneumatic pulsating cell which allows you to treat these slices using a simple and effective procedure. The IGME has tested this successfully, as the results presented in this study show. However, due to the fact that the process is new and it is still being developed, the first tests were made in a small laboratory cell. A larger, more versatile cell has been made, which improves the results obtained in the tests. 4 refs., 6 figs., 10 tabs.

  1. Comparative analysis for performance of brown coal combustion in a vortex furnace with improved design

    Science.gov (United States)

    Krasinsky, D. V.

    2016-09-01

    Comparative study of 3D numerical simulation of fluid flow and coal-firing processes was applied for flame combustion of Kansk-Achinsk brown coal in a vortex furnace of improved design with bottom injection of secondary air. The analysis of engineering performance of this furnace was carried out for several operational modes as a function of coal grinding fineness and coal input rate. The preferable operational regime for furnace was found.

  2. The strongest links : the Canadian coal chain

    Energy Technology Data Exchange (ETDEWEB)

    Moore, E.

    2008-09-15

    Issues related to the transportation of coal in Canada were discussed. Coal mines in Alberta and British Columbia are often required to transport their products over 1000 km for export at Pacific ports to countries in Asia or power plants in Ontario. The effectiveness of the supply chain is dependent on the inter-relationships between mine, rail, terminals, and ship transport. Coal customers are typically required to hire shipping companies and nominate vessels for terminals that have contracts with coal suppliers. Mines typically inform railway lines of the amounts of coal that will need to be transported each month. Many railways have increased the amounts of coal they are transporting by using lighter-weight aluminum train cars. Further efficiencies have been realized due to new braking and power distribution technologies in trains. Multiple locomotives are now also being used to provide improved control over the cars that carry the coal. Despite advances in rail technologies, coal deliveries are often delayed by harsh weather conditions and rain. It was concluded that the Canadian coal industry's success relies on its ability to transport large amounts of coal across long distances. 2 figs.

  3. COAL COMBUSTION EFFICIENCY IN CFB BOILER

    Institute of Scientific and Technical Information of China (English)

    Hairui Yang; Guangxi Yue

    2005-01-01

    The carbon content in the fly ash from most Chinese circulating fluidized bed (CFB) boilers is much higher than expected, thus directly influencing the combustion efficiency. In the present paper, carbon burnout was investigated both in field tests and laboratory experiments. The effect of coal property, operation condition, gas-solid mixing, char deactivation,residence time and cyclone performance are analyzed seriatim based on large amount of experimental results.A coal index is proposed to describe the coal rank, defined by the ratio of the volatile content to the coal heat value, is a useful parameter to analyze the char burnout. The carbon content in the fly ash depends on the coal rank strongly. CFB boilers burning anthracite, which has low coal index, usually have high carbon content in the fly ash. On the contrary, the CFB boilers burning brown coal, which has high coal index, normally have low carbon content.Poor gas-solid mixing in the furnace is another important reason of the higher carbon content in the fly ash. Increasing the velocity and rigidity of the secondary air could extend the penetration depth and induce more oxygen into the furnace center. Better gas solid mixing will decrease the lean oxygen core area and increase char combustion efficiency.The fine char particles could be divided into two groups according to their reactivity. One group is "fresh" char particles with high reactivity and certain amount of volatile content. The other group of char particles has experienced sufficient combustion time both in the furnace and in the cyclone, with nearly no volatile. These "old" chars in the fly ash will be deactivated during combustion of large coal particles and have very low carbon reactivity. The generated fine inert char particles by attrition of large coal particles could not easily burn out even with the fly ash recirculation. The fraction of large coal particles in coal feed should be reduced during fuel preparation process.The cyclone

  4. Conceptual flow sheets development for coal conversion plant coal handling-preparation and ash/slag removal operations

    Energy Technology Data Exchange (ETDEWEB)

    1979-07-01

    This report presents 14 conceptual flow sheets and major equipment lists for coal handling and preparation operations that could be required for future, commercial coal conversion plants. These flow sheets are based on converting 50,000 tons per day of clean coal representative of the Pittsburgh and Kentucky No. 9 coal seams. Flow sheets were used by Union Carbide Corporation, Oak Ridge National Laboratory, in a survey of coal handling/preparation equipment requirements for future coal conversion plants. Operations covered in this report include run-of-mine coal breaking, coarse coal cleaning, fine coal cleaning, live storage and blending, fine crushing (crushing to top sizes ranging from 1/4-inch to 20 mesh), drying, and grinding (70 percent minus 200 mesh). Two conceptual flow sheets and major equipment lists are also presented for handling ash or granulated slag and other solid wastes produced by nine leading coal conversion processes. These flow sheets provide for solid wastes transport to an environmentally acceptable disposal site as either dry solids or as a water slurry.

  5. Grinding analysis of Indian coal using response surface methodology

    Institute of Scientific and Technical Information of China (English)

    Twinkle Singh; Aishwarya Awasthi; Pranjal Tripathi; Shina Gautam; Alok Gautam

    2016-01-01

    The present work discusses a systematic approach to model grinding parameters of coal in a ball mill.A three level Box-Behnken design combined with response surface methodology using second order model was applied to the experiments done according to the model requirement.Three parameters ball charge (numbers 10-20),coal content (100-200 g) and the grinding time (4-8 min) were chosen for the experiments as well as for the modeling work.Coal fineness is defined as the d80 (80 % passing size).A quadratic model was developed to show the effect of parameters and their interaction with fineness of the product.Three different sizes (4,1 and 0.65 mm) of Indian coal were used.The model equations for each fraction were developed and different sets of experiments were performed.The predicted values of the fineness of coal were in good agreement with the experimental results (R2 values of d80 varies between 0.97 and 0.99).Fine size of three different coal sizes were obtained with larger ball charge with less grinding time and less solid content.This work represents the efficient use of response surface methodology and the Box-Behnken design use for grinding of Indian coal.

  6. Milliken Clean Coal Demonstration Project: A DOE Assessment

    Energy Technology Data Exchange (ETDEWEB)

    National Energy Technology Laboratory

    2001-08-15

    The goal of the U.S. Department of Energy's (DOE) Clean Coal Technology (CCT) program is to furnish the energy marketplace with a number of advanced, more efficient, and environmentally responsible coal-utilization technologies through demonstration projects. These projects seek to establish the commercial feasibility of the most promising advanced coal technologies that have developed beyond the proof-of-concept stage.

  7. Microfine coal firing results from a retrofit gas/oil-designed industrial boiler

    Energy Technology Data Exchange (ETDEWEB)

    Patel, R.; Borio, R.W.; Liljedahl, G. [Combustion Engineering, Inc., Windsor, CT (United States)] [and others

    1995-11-01

    Under US Department of Energy, Pittsburgh Energy Technology Center (PETC) support, the development of a High Efficiency Advanced Coal Combustor (HEACC) has been in progress since 1987 at the ABB Power Plant Laboratories. The initial work on this concept produced an advanced coal firing system that was capable of firing both water-based and dry pulverized coal in an industrial boiler environment.

  8. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091749 Cai Hou’an(College of Energy Geology,China University of Geosciences,Beijing 100083,China);Xu Debin SHRIMP U-Pb Isotope Age of Volcanic Rocks Distributed in the Badaohao Area,Liaoning Province and Its Significance(Coal Geology & Exploration,ISSN1001-1986,CN61-1155/P,36(4),2008,p.17-20,2 illus.,1 table,16 refs.)Key words:coal measures,volcanic rocks,U-Pb dating,LiaoningA set of andesite volcanic rocks distributes in the Badaohao area in Heishan County,Liaoning Province.It’s geological age and stratigraphy sequence relationship between the Lower Cretaceous Badaohao Formation and the volcanic rocks can not make sure till now and is influencing the further prospect for coals.Zircon

  9. Vibrated fluidized bed air classification of moist raw coal

    Institute of Scientific and Technical Information of China (English)

    杨国华; 赵跃民; 陈清如

    2002-01-01

    Vibrated fluidized bed air classification is completely different from traditional screening in principle. It extracts fine coal from moist raw coal by entrainment of an ascending airflow in a vibrated fluidized bed. Pilot tests showed that air classification efficiencies varied from 74.85% to 93.84% at cut-size 6, 4, 3, 2, 1, and 0.5 mm when free moisture of coal is in the range of 1.7% to 9.5%, and ash contents of fine coal products were 2%~3% lower than those of the same size fractions in feed, and 4%~10% lower than those of feeds for most cases because of the density differences between coal and waste, which is beneficial to producing lower ash fine coal from raw coal as fuel of blast furnaces or pulverized coal firing boilers. A commercial unit of 100 t/h has been in smooth operation, and several 300~400 t/h units are in plan or construction.

  10. Rosebud SynCoal Partnership, SynCoal{reg_sign} demonstration technology update

    Energy Technology Data Exchange (ETDEWEB)

    Sheldon, R.W. [Rosebud SynCoal Partnership, Billings, MT (United States)

    1997-12-31

    An Advanced Coal Conversion Process (ACCP) technology being demonstrated in eastern Montana (USA) at the heart of one of the world`s largest coal deposits is providing evidence that the molecular structure of low-rank coals can be altered successfully to produce a unique product for a variety of utility and industrial applications. The product is called SynCoal{reg_sign} and the process has been developed by the Rosebud SynCoal Partnership (RSCP) through the US Department of Energy`s multi-million dollar Clean Coal Technology Program. The ACCP demonstration process uses low-pressure, superheated gases to process coal in vibrating fluidized beds. Two vibratory fluidized processing stages are used to heat and convert the coal. This is followed by a water spray quench and a vibratory fluidized stage to cool the coal. Pneumatic separators remove the solid impurities from the dried coal. There are three major steps to the SynCoal{reg_sign} process: (1) thermal treatment of the coal in an inert atmosphere, (2) inert gas cooling of the hot coal, and (3) removal of ash minerals. When operated continuously, the demonstration plant produces over 1,000 tons per day (up to 300,000 tons per year) of SynCoal{reg_sign} with a 2% moisture content, approximately 11,800b Btu/lb and less than 1.0 pound of SO{sub 2} per million Btu. This product is obtained from Rosebud Mine sub-bituminous coal which starts with 25% moisture, 8,600 Btu/lb and approximately 1.6 pounds of SO{sub 2} per million Btu.

  11. Coal-derived carbon nanotubes by thermal plasma jet

    Energy Technology Data Exchange (ETDEWEB)

    Tian, Y.; Zhang, Y.L.; Wang, B.J.; Ji, W.J.; Zhang, Y.F.; Xie, K.C. [Nanjing University, Nanjing (China). Dept. of Physics

    2004-07-01

    A coal/arc-jet technique by directly and successively injecting coal fine particles into the arc plasma jet instead of arcing graphite or coal-based electrodes for producing carbon nanotubes (CNTs) from coal was developed. The derived carbon products by this technique were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), high-resolution TEM (HRTEM), X-ray energy dispersive spectrum (EDS), X-ray diffraction (XRD) and Raman spectrum. The experimental results clearly indicated that certain metal catalysts favored the growth of CNTs in the process, and the relevant growth mechanism was discussed in terms of the characterizations.

  12. A new approach to study fast pyrolysis of pulverized coal

    Energy Technology Data Exchange (ETDEWEB)

    Wang, J.; Yao, J.; Lin, W. [Chinese Academy of Sciences, Institute of Chemical Metallurgy Fast Reactions Laboratory, Beijing, BJ (China)

    2002-07-01

    An experimental study of the effects of varying bed temperature and coal particle size on the fast pyrolysis of pulverized coal in a downer reactor is described. A Datong bituminous coal (particle size 0.5 and 0.34 mm) was studied at temperatures ranging from 592{sup o} C to 720{sup o} C. The experiments were conducted in a batch apparatus. An on-line gas analyzer was used to measure carbon dioxide release curves. The experimental data were used to develop a pyrolysis model that quantifies the fast heating of fine coal particles. 14 refs., 4 figs., 2 tabs.

  13. 煤矿井下综合物探超前探测技术与应用%Technology and application of in-advance geophysical detection in coal mines

    Institute of Scientific and Technical Information of China (English)

    李萍

    2012-01-01

    对我国煤矿井下推广使用的地球物理探测技术进行了回顾,着重介绍了瑞利波和直流电法两种超前探测技术的新进展;结合七台河、平顶山等煤矿的应用实例,分析了煤矿井下超前地质预测的潜力,提出了煤矿井下超前探测技术的发展方向.%The paper introduces underground geophysical detection technology applied in coal mines, focusing on the improvement of in-advance geophysical detection techniques such as Rayleigh wave and direct current methods. In combination with the application in Qitaihe, Pingdingshan and other mines, the potential of in-advance geological prediction in underground mines was analyzed and the development orientation of in-advance underground geophysical detection technology was put forward.

  14. The Status Quo and Outlook of Chinese Coal Geology and Exploration Technologies

    Institute of Scientific and Technical Information of China (English)

    XU Shuishi; CHENG Aiguo; CAO Daiyong

    2008-01-01

    Coal is China's dominant energy resource. Coal geological exploration is the basis of sustainable development of coal industry. Since the late 1990s, the advances in Chinese coal geology and exploration techniques have been shown in the following aspects. (1) The basic research of coal geology has changed from traditional geological studies to earth system science; (2) Breakthroughs have been achieved in integrated exploration techniques for coal resources; (3) Evaluation of coal and coalbed methane resources provides important basis for macropolicy making for China's coal industry and construction of large coal bases; (4) Significant advances have been made in using information technology in coal geological exploration and 3S (GPS, GIS, RS) technology. For the present and a period of time in the future, major tasks of Chinese coal geological technology are as follows: (1) solving resources replacement problem in eastern China and geological problems of deep mining; (2) solving problem of integrated coal exploration of complex regions in energy bases of central China, and resources problems induced by coal exploitation; (3) making efforts to enhance the level of geological research and resources evaluation of coal-accumulation basins in western China; (4) strengthening geological research of clean coal technologies; (5) strengthening geological research of the problems in modern coal mining and safe production; (6) promoting information technology in coal resources and major geological investigations.

  15. Advances in Nanocarbon Metals: Fine Structure

    Science.gov (United States)

    2015-03-01

    necessary to improve the performance and stability of Cu covetic films grown by PLD. Slides 60–81 present our results on Cu covetic films. We have... improved properties over the base metal from which it is generated. After the conversion process, the C is highly stable, despite its form not being...from Third Millennium Materials, LLC. Pieces of the bulk material were used as targets for the film deposition. The attached PowerPoint presentation

  16. Field study for disposal of solid wastes from Advanced Coal Processes: Ohio LIMB Site Assessment. Final report, April 1986--November 1994

    Energy Technology Data Exchange (ETDEWEB)

    Weinberg, A.; Coel, B.J.; Butler, R.D.

    1994-10-01

    New air pollution regulations will require cleaner, more efficient processes for converting coal to electricity, producing solid byproducts or wastes that differ from conventional pulverized-coal combustion ash. Large scale landfill test cells containing byproducts were built at 3 sites and are to be monitored over at least 3 years. This report presents results of a 3-y field test at an ash disposal site in northern Ohio; the field test used ash from a combined lime injection-multistage burner (LIMB) retrofit at the Ohio Edison Edgewater plant. The landfill test cells used LIMB ash wetted only to control dusting in one cell, and LIMB ash wetted to optimize compaction density in the other cell. Both test cells had adequate load-bearing strength for landfill stability but had continuing dimensional instability. Heaving and expansion did not affect the landfill stability but probably contributed to greater permeability to infiltrating water. Leachate migration occurred from the base, but effects on downgradient groundwater were limited to increased chloride concentration in one well. Compressive strength of landfilled ash was adequate to support equipment, although permeability was higher and strength was lower than anticipated. Average moisture content has increased to about 90% (dry weight basis). Significant water infiltration has occurred; the model suggests that as much as 20% of the incident rainfall will pass through and exit as leachate. However, impacts on shallow ground water is minimal. Results of this field study suggest that LIMB ash from combustion of moderate to high sulfur coals will perform acceptably if engineering controls are used to condition and compact the materials, reduce water influx to the landfill, and minimize leachate production. Handling of the ash did not pose serious problems during cell construction; steaming and heat buildup were moderate.

  17. Coal gasification. Quarterly report, April--June 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1978-01-01

    The conversion of coal to high-Btu gas requires a chemical and physical transformation of solid coal. However, because coal has widely differing chemical and physical properties, depending on where it is mined, it is difficult to process. Therefore, to develop the most suitable techniques for gasifying coal, ERDA, together with the American Gas Association, is sponsoring the development of several advanced conversion processes. Although the basic coal-gasification chemical reactions are the same for each process, the processes under development have unique characteristics. A number of the processes for converting coal to high Btu and to low Btu gas have reached the pilot plant stage. The responsibility for designing, constructing and operating each of these pilot plants is defined and progress on each during the quarter is described briefly. The accumulation of data for a coal gasification manual and the development of mathematical models of coal gasification processes are reported briefly. (LTN)

  18. Coal industry annual 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-01

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  19. Coal industry annual 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-11-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  20. Coal Industry Annual 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  1. Royal Society, Discussion on New Coal Chemistry, London, England, May 21, 22, 1980, Proceedings

    Science.gov (United States)

    1981-03-01

    A discussion of new coal chemistry is presented. The chemical and physical structure of coal is examined in the first section, including structural studies of coal extracts, metal and metal complexes in coal and coal microporosity. The second section presents new advances in applied coal technology. The development of liquid fuels and chemicals from coal is given especial emphasis, with papers on the Sasol Synthol process, the Shell-Koppers gasification process, liquefaction and gasification in Germany, the Solvent Refined Coal process, the Exxon Donor Solvent liquefaction process and the Mobil Methanol-to-Gasoline process. Finally, some developments that will be part of the future of coal chemistry in the year 2000 are examined in the third section, including coal-based chemical complexes and the use of coal as an alternative source to oil for chemical feedstocks.

  2. An update on blast furnace granular coal injection

    Energy Technology Data Exchange (ETDEWEB)

    Hill, D.G. [Bethlehem Steel Corp., Burns Harbor, IN (United States); Strayer, T.J.; Bouman, R.W. [Bethlehem Steel Corp., PA (United States)

    1997-12-31

    A blast furnace coal injection system has been constructed and is being used on the furnace at the Burns Harbor Division of Bethlehem Steel. The injection system was designed to deliver both granular (coarse) and pulverized (fine) coal. Construction was completed on schedule in early 1995. Coal injection rates on the two Burns Harbor furnaces were increased throughout 1995 and was over 200 lbs/ton on C furnace in September. The injection rate on C furnace reached 270 lbs/ton by mid-1996. A comparison of high volatile and low volatile coals as injectants shows that low volatile coal replaces more coke and results in a better blast furnace operation. The replacement ratio with low volatile coal is 0.96 lbs coke per pound of coal. A major conclusion of the work to date is that granular coal injection performs very well in large blast furnaces. Future testing will include a processed sub-bituminous coal, a high ash coal and a direct comparison of granular versus pulverized coal injection.

  3. Coal industry of Russia in early 21st century

    Energy Technology Data Exchange (ETDEWEB)

    Malyshev, Y.N.; Trubetskoy, K.N. [Russian Union of Coal Producers, Moscow (Russia)

    2001-06-01

    The Russian coal industry enters 21st century as a completely revived and re-engineered profitable sector of the national economy, which is able to meet the national demand for coal and also to gradually expand the Russian annual exports of high quality coals to 40 MT. For the immediate future the improvement of coal sector efficiency on the basis of radical restructuring, introducing of the latest advanced technologies and product quality upgrading as well as the quantitative expansion of coal production, can be considered as the key direction for development. 4 refs., 4 annexs.

  4. Mechanism of the rib spalling and the controlling in the very soft coal seam

    Energy Technology Data Exchange (ETDEWEB)

    Wang Jia-chen [China University of Mining and Technology, Beijing (China). Laboratory of Coal Resources and Mine Safety Technology

    2007-08-15

    The mechanism of rib spalling was studied and a way of controlling it was proposed by decreasing coal wall pressure and increasing the shear strength of the coal wall. Using the top coal caving technique and increasing the resistance of the support can reduce the pressure on the coal wall. The cohesion and shear strength of the coal wall may be increased by means of water infusion through the coal wall. These are effective ways of preventing rib spalling. The quick advance of the coal wall and having the correct low wall height are also advantageous to wall stability. 2 refs., 11 figs.

  5. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman

    2002-10-15

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to

  6. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman

    2003-01-20

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to

  7. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan

    2002-04-15

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), and up to 5500 psi with emphasis upon 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced

  8. INTERACTIONS BETWEEN CATIONIC POLYELECTROLYTE AND PULP FINES

    Directory of Open Access Journals (Sweden)

    Elina Orblin

    2011-05-01

    Full Text Available Papermaking pulps are a mixture of fibres, fibre fragments, and small cells (parenchyma or ray cells, usually called pulp fines. The interactions between pulp fines and a cationic copolymer of acrylamide and acryloxyethyltrimethyl ammonium chloride were investigated based on solid-liquid isotherms prepared under different turbulence, and subsequent advanced surface characterization using X-ray photoelectron spectroscopy (XPS and time-of-flight secondary ion mass spectrometry (ToF-SIMS. The surface charge and surface area of pulp fine substrates were measured by methylene blue sorption-XPS analysis and nitrogen adsorption combined with mercury porosimetry, respectively. The driving force behind polyelectrolyte adsorption was the amount of the surface anionic charge, whereas surface area appeared to be of less importance. Based on a comparison of solid-liquid and XPS sorption isotherms, different polyelectrolyte conformations were suggested, depending on the types of fines: A flatter conformation and partial cell-wall penetration of polyelectrolytes on kraft fines from freshly prepared pulp, and a more free conformation with extended loops and tails on lignocellulosic fines from recycled pulp. Additionally, ToF-SIMS imaging proved that recycled pulp fines contained residual de-inking chemicals (primarily palmitic acid salts that possibly hinder the electrostatic interactions with polyelectrolytes.

  9. Coal - proximate analysis

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-06-14

    This Standard establishes a practice for the proximate analysis of coal, that is, the coal is analysed for the content of moisture, ash and volatile matter; fixed carbon is calculated. The standard provides a basis for the comparison of coals.

  10. Coal industry annual 1993

    Energy Technology Data Exchange (ETDEWEB)

    1994-12-06

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  11. Influence of Geological Structure on Coal and Gas Outburst Occurrences in Turkish Underground Coal Mines

    Science.gov (United States)

    Esen, Olgun; Özer, Samet Can; Fişne, Abdullah

    2015-04-01

    Coal and gas outbursts are sudden and violent releases of gas and in company with coal that result from a complex function of geology, stress regime with gas pressure and gas content of the coal seam. The phenomena is referred to as instantaneous outbursts and have occurred in virtually all the major coal producing countries and have been the cause of major disasters in the world mining industry. All structures from faults to joints and cleats may supply gas or lead to it draining away. Most geological structures influence the way in which gas can drain within coal seams. From among all the geological factors two groups can be distinguished: parameters characterising directly the occurrence and geometry of the coal seams; parameters characterising the tectonic disturbances of the coal seams and neighbouring rocks. Also dykes may act as gas barriers. When the production of the coal seam is advanced in mine working areas, these barriers are failed mostly in the weak and mylonitized zones. Geology also plays a very important role in the outburst process. Coal seams of complex geological structure including faults, folds, and fractured rocks are liable to outbursts if coal seams and neighbouring rocks have high gas content level. The purpose of the study is to enlighten the coal industry in Turkey to improving mine safety in underground coal production and decrease of coal and gas outburst events due to increasing depth of mining process. In Turkey; the years between 1969 and 2013, the number of 90 coal and gas outbursts took place in Zonguldak Hard Coal Basin in both Kozlu and Karadon Collieries. In this study the liability to coal and gas outburst of the coal seams are investigated by measuring the strength of coal and the rock pressure. The correlation between these measurements and the event locations shows that the geological structures resulted in 52 events out of 90 events; 19 events close to the fault zones, 25 events thorough the fault zones and 8 events in

  12. Health effects of coal technologies: research needs

    Energy Technology Data Exchange (ETDEWEB)

    1980-09-01

    In this 1977 Environmental Message, President Carter directed the establishment of a joint program to identify the health and environmental problems associated with advanced energy technologies and to review the adequacy of present research programs. In response to the President's directive, representatives of three agencies formed the Federal Interagency Committee on the Health and Environmental Effects of Energy Technologies. This report was prepared by the Health Effects Working Group on Coal Technologies for the Committee. In this report, the major health-related problems associated with conventional coal mining, storage, transportation, and combustion, and with chemical coal cleaning, in situ gasification, fluidized bed combustion, magnetohydrodynamic combustion, cocombustion of coal-oil mixtures, and cocombustion of coal with municipal solid waste are identified. The report also contains recommended research required to address the identified problems.

  13. Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, Howard

    2010-11-30

    This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energy's Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

  14. Engineering development of advanced coal-fired low-emission boiler systems. Technical progress report No. 10, January 1995--March 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-17

    The project is on schedule and under budget. The current status is shown in the Milestone Schedule Report included as Appendix A. All Project Plans were updated based on the revised finding level authorized for FY95 and anticipated for FY96. Technology Transfer activities included {open_quotes}supplying{close_quotes} three executives and several team members to the LEBS Workshop, delivering a technical paper at a conference, and working on a Combustion 2000 Session for another conference. ABBES and CeraMem reached agreement concerning Task 7 work, including ownership and disposition of project-purchased equipment to be used during Task 7 and also during Task 11. A test plan was prepared. Task 7 activities for the Low-NO{sub x} Firing System included computational modeling of the firing arrangement. Reasonable comparisons to experimental data previously obtained in the Boiler Simulation Facility were achieved. A kinetic evaluation for both baseline and low NO{sub x} firing arrangements was also performed, with results indicating that the final reducing zone within the main windbox has a dominant effect on NO{sub x} reduction, with higher temperatures being more favorable for lower NO{sub x}. A week of combustion testing was completed in the Fundamental Scale Burner Facility to examine the impact of integrated fuel staging (NO{sub x} reduction via the reburn mechanism), and to explore preliminary vertical staging concepts within the main windbox region. Preliminary results from this testing demonstrated the potential of vertical air staging within the main windbox to augment overfire air. Testing was performed to quantify the coal size distribution and power requirements for one (1) conventional static and four (4) dynamic classifier designs. Results from this testing show the dynamic classifier capable of producing finer grinds of coal at lower relative power requirements.

  15. 先进制造技术在煤机行业的信息化应用%Research on informatization application of advanced manufacturing technology in coal machine manufacturing industry

    Institute of Scientific and Technical Information of China (English)

    韩斌慧

    2015-01-01

    From manual process, machinery production, CNC machining, to current advanced manufacturing technology,manufacturing industry has changed from simple processing to diverse manufacturing methods considering low -carbon environmental protection,green manufacturing,and sustainable development. In this process,the penetration of information technology on the development of manufacturing technology has played a decisive role.This paper,taking product design,heat treatment control,micro -arc plasma welding remanufacturing,CAE simulation and other successful application of advanced manufacturing technology as examples,combined with coal machine manufacturing industry informatization status quo, elaborates the significance for enhancing coal industry technology level,reducing production costs,improving enterprise management that integrates effectively advanced manufacturing technology with information.%制造业由手工制造、机械化生产、数控加工,发展到现在的先进制造技术,实现了从单纯的产品加工到兼顾低碳环保、绿色制造、可持续发展等多元制造方式的转变。在此过程中,信息化的渗透对制造技术的发展起到了决定性作用。本文以先进制造技术在产品设计、热处理过程控制、微弧等离子焊接再制造、CAE 仿真分析等方面的成功应用为例,结合煤机制造行业的信息化现状,阐述了在煤机制造过程中将先进制造技术与信息化有效融合,对于提升煤机行业工艺技术水平,降低生产制造成本、全面提高企业管理方面的重要意义。

  16. Mitsubishi latest coal fired USC boiler technology (CFE Pacifico 700 MW)

    Energy Technology Data Exchange (ETDEWEB)

    Hashimoto, T.; Sakamoto, K. [Mitsubishi Heavy Industries, Ltd., Nagasaki (Japan). Power Systems; Fujitab, M. [Mitsubishi Heavy Industries, Ltd., Yokohama (Japan). Power Systems

    2013-07-01

    Mitsubishi Heavy Industries, Ltd. (MHI) has successfully completed commissioning work for CFE (Comision Federal de Electricidad) Pacifico 700 MW coal-fired unit in March 2010 which is the first supercritical unit in Latin America. This supercritical boiler was designed with state of the art technologies such as low NOx burners, high fineness pulverizers, advanced vertical furnace wall technology and so on. Especially the advanced vertical furnace wall technology with some improvements is a key technology to realize swift load changes such as 5% load per minute ramping rate with assuring dynamic characteristics. Recently the requirement of the high efficiency and the swift load changes for the power boilers has been increased so that even a coal-fired unit needs flexible operation characteristics for balancing variety of power sources. One of the challenges for the swift load change is to keep the furnace wall metal temperature low during the load change, which the advanced vertical furnace wall could realize. The report describes the features of the unit and commissioning result including load swing test results in details.

  17. Magnetic seeding sedimentation (MSS) of coal slimes

    Science.gov (United States)

    Wu, Xiqing; Yue, Tao; Dai, Liang

    2017-01-01

    Magnetic seeding sedimentation (MSS), i.e. adding magnetic seeds and pre-magnetization for sedimentation, is a technique especially for sedimentation of fine slimes, improving the sedimentation performance by introducing the magnetic interactions between particles in a suspension and enlarging the apparent size of the fine particles. The fine coal slimes with a size of 66.68%-38μm were investigated by the MSS. Sedimentation tests were conducted, and some measurements, such as laser size analysis, magnetic susceptibility by vibrating sample magnetometer (VSM), were also applied in order to probe the mechanism of the MSS. Based on the tests, measurements and calculations it was demonstrated that the sedimentation of coal slimes increased with the additions of the magnetic seeds, and in the presence of the polyacrylamide, and also there appeared a relatively large apparent size of slimes after additions of magnetic seeds and/or polyacrylamide. So, the reason for the influence of MSS lies in fact that the presence of the polyacrylamide intensified the adsorption of magnetic seeds on the coal particles and the coverage of the magnetic seeds on the coal surface from 0.2% wt. to1.3% wt., resulting in increased magnetic susceptibility of coal particles from 9.13×10-9m3/kg to 22.17×10-9m3/kg and thus a low magnetic field strength of pre-magnetization needed for the magnetic agglomeration to happen among the coal particles (the threshold of magnetic field strength for agglomeration) from 602mT to 24mT prior to proper sedimentation.

  18. 掘进巷道煤体瓦斯特征与震波频率特性研究%Study on Advancing Roadway Coal Mass Gas Features and Seismic Wave Frequency Characteristics

    Institute of Scientific and Technical Information of China (English)

    路拓; 刘盛东

    2012-01-01

    Through multiple seismic wave detective tests at the outburst coal seam heading face, and using spectrum and time-frequency analysis techniques obtain roadway single channel seismic signal frequency parameters. Contrastively analyze roadway corresponding checked parameters and establish relationship between coal mass gas absolute emission and seismic wave frequency parameters. Seismic wave energy is mainly concentrated in two independent frequency domains: high frequency and low frequency regions corresponding seismic wave basic frequency and secondary basic frequency respectively. Along with gas content in coal mass increasing, basic frequency and secondary basic frequency decreasing correspondingly and basic frequency will be more sensitive to gas content variation. Using seismic wave frequency to predict gas content near the advancing roadway heading face can provide a new parameter in gas outburst hazard prediction.%通过多次在突出煤层掘进巷道迎头进行震波探测试验,并使用频谱分析和时频分析技术得到各巷道的单道震波信号的频率参数,对比分析各条巷道对应的瓦斯检验参数,建立起煤体瓦斯绝对涌出量与震波频率参数的关系:震波能量主要集中在两个独立的频率域内,高频区和低频区分别对应了震波的主频和次主频;随着煤体瓦斯含量的增大,震波的主频和次主频相应降低,且次主频对瓦斯含量的变化更为灵敏.利用震波频率参数预测掘进巷道迎头附近瓦斯含量,可为瓦斯突出危险性预测提供一种新的参数.

  19. Prediction of oxygen concentration and temperature distribution in loose coal based on B P neural network

    Institute of Scientific and Technical Information of China (English)

    ZHANG Yong-jian; WU Guo-guang; XU Hong-feng; MENG Xian-liang; WANG Guang-you

    2009-01-01

    An effective method for preventing spontaneous combustion of coal stockpiles on the ground is to control the air-flow in loose coal. In order to determine and predict accurately oxygen concentrations and temperatures within coal stockpiles, it is vital to obtain information of self-heating conditions and tendencies of spontaneous coal combustion. For laboratory conditions, we de-signed our own experimental equipment composed of a control-heating system, a coal column and an oxygen concentration and temperature monitoring system, for simulation of spontaneous combustion of block coal (13-25 ram) covered with fine coal (0-3 mm). A BP artificial neural network (ANN) with 150 training samples was gradually established over the course of our experiment. Heating time, relative position of measuring points, the ratio of fine coal thickness, artificial density, voidage and activation energy were selected as input variables and oxygen concentration and temperature of coal column as output variables. Then our trained network was applied to predict the trend on the untried experimental data. The results show that the oxygen concentration in the coal column could be reduced below the minimum still able to induce spontaneous combustion of coal-6% by covering the coal pile with fine coal, which would meet the requirement to prevent spontaneous combustion of coal stockpiles. Based on the predic-tion of this ANN, the average errors of oxygen concentration and temperature were respectively 0.5% and 7 ~C, which meet actual tolerances. The implementation of the method would provide a practical guide in understanding the course of self-heating and spontaneous combustion of coal stockpiles.

  20. Effect of coal beneficiation process on rheology/atomization of coal water slurries. Final report, October 1, 1992--July 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Ohene, F.

    1997-05-01

    To examine the factors that govern fine spray production during atomization of coal water slurries, an experimental study of the effect of coal beneficiation and their rheological properties on atomization of clean slurries was proposed. The objective of this study was to understand the effect of low shear, high shear rheology, and viscoelastic behavior on the atomization of beneficiated slurries.

  1. Fundamental bioprocessing research for coal applications

    Energy Technology Data Exchange (ETDEWEB)

    Kaufman, E.N.

    1996-06-01

    The purpose of this program is to gain a fundamental understanding and sound scientific technical basis for evaluating the potential roles of innovative bioprocessing concepts for the utilization and conversion of coal. The aim is to explore the numerous ways in which advanced biological processes and techniques can open new opportunities for coal utilization or can replace more conventional techniques by use of milder conditions with less energy consumption or loss. There are several roles where biotechnology is likely to be important in coal utilization and conversion. These include potential bioprocessing systems such.

  2. Fine Arts Database (FAD)

    Data.gov (United States)

    General Services Administration — The Fine Arts Database records information on federally owned art in the control of the GSA; this includes the location, current condition and information on artists.

  3. Literature review and binder and coal selection for research studies on coal agglomeration

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, S.G.; Kuby, O.A.; Girimont, J.A.; peterson, C.A.; Saller, E.

    1982-02-26

    This report discusses the results of a literature survey on coal agglomeration and the approaches that were employed in selecting binders and coals to be studied in a process development program currently being performed for the Department of Energy. The survey is the first step toward the development of a useful process for the agglomeration of coal fines for use in a fixed-bed gasifier. Literature was found and reviewed on the effects of coal composition and physical properties, on agglomeration techniques and operating variables, on binders or additives to promote agglomeration, on pretreatment techniques on agglomerate feedstocks and post-treatment techniques on formed agglomerates, and on test results obtained by researchers in the past using various additives, treatments and agglomeration techniques. Much of this information did not deal directly with agglomerates for fixed-bed gasifiers, but the reported observations and results could be extrapolated to give useful guidelines for research plans. Conclusions and plans for further work are presented.

  4. Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semiannual technical report, January 14, 1997--August 14, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Schorr, B.S.; Levin, B.F.; DuPont, J.N.; Marder, A.R.

    1997-08-31

    Research is presently being conducted to determine the optimum ceramic/metal combination in thermally sprayed metal matrix composite coatings for erosion and corrosion resistance in new coal-fired boilers. The research will be accomplished by producing model cermet composites using powder metallurgy and electrodeposition methods in which the effect of ceramic/metal combination for the erosion and corrosion resistance will be determined. These results will provide the basis for determining the optimum hard phase constituent size and volume percent in thermal spray coatings. Thermal spray coatings will be applied by our industrial sponsor and tested in our erosion and corrosion laboratories. Bulk powder processed Ni-Al{sub 2}O{sub 3} composites were produced at Idaho National Engineering Laboratory. The composite samples contained 0, 21, 27, 37, and 45 volume percent Al{sub 2}O{sub 3} with an average particle size of 12 um. Also, to deposit model Ni-Al{sub 2}O{sub 3} coatings, an electrodeposition technique was developed and coatings with various volume fractions (0-35%) of Al{sub 2}O{sub 3} were produced. The powder and electrodeposition processing of Ni-Al{sub 2}O{sub 3} Composites provide the ability to produce two phase microstructure without changing the microstructure of the matrix material. Therefore, the effect of hard second phase particles size and volume fraction on erosion resistance could be analyzed.

  5. Engineering and Economic Analysis of an Advanced Ultra-Supercritical Pulverized Coal Power Plant with and without Post-Combustion Carbon Capture Task 7. Design and Economic Studies

    Energy Technology Data Exchange (ETDEWEB)

    Booras, George [Electric Power Research Inst. (EPRI), Palo Alto, CA (United States); Powers, J. [General Electric, Schenectady, NY (United States); Riley, C. [General Electric, Schenectady, NY (United States); Hendrix, H. [Hendrix Engineering Solutions, Inc., Calera, AL (United States)

    2015-09-01

    This report evaluates the economics and performance of two A-USC PC power plants; Case 1 is a conventionally configured A-USC PC power plant with superior emission controls, but without CO2 removal; and Case 2 adds a post-combustion carbon capture (PCC) system to the plant from Case 1, using the design and heat integration strategies from EPRI’s 2015 report, “Best Integrated Coal Plant.” The capture design basis for this case is “partial,” to meet EPA’s proposed New Source Performance Standard, which was initially proposed as 500 kg-CO2/MWh (gross) or 1100 lb-CO2/MWh (gross), but modified in August 2015 to 635 kg-CO2/MWh (gross) or 1400 lb-CO2/MWh (gross). This report draws upon the collective experience of consortium members, with EPRI and General Electric leading the study. General Electric provided the steam cycle analysis as well as v the steam turbine design and cost estimating. EPRI performed integrated plant performance analysis using EPRI’s PC Cost model.

  6. Analyses of fine paste ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Sabloff, J A [ed.

    1980-01-01

    Four chapters are included: history of Brookhaven fine paste ceramics project, chemical and mathematical procedures employed in Mayan fine paste ceramics project, and compositional and archaeological perspectives on the Mayan fine paste ceramics. (DLC)

  7. Transport of reservoir fines

    DEFF Research Database (Denmark)

    Yuan, Hao; Shapiro, Alexander; Stenby, Erling Halfdan

    Modeling transport of reservoir fines is of great importance for evaluating the damage of production wells and infectivity decline. The conventional methodology accounts for neither the formation heterogeneity around the wells nor the reservoir fines’ heterogeneity. We have developed an integral...... dispersion equation in modeling the transport and the deposition of reservoir fines. It successfully predicts the unsymmetrical concentration profiles and the hyperexponential deposition in experiments....

  8. Abstracts and research accomplishments of university coal research projects

    Energy Technology Data Exchange (ETDEWEB)

    1991-06-01

    The Principal Investigators of the grants supported by the University Coal Research Program were requested to submit abstracts and highlight accomplishments of their projects in time for distribution at a grantees conference. This book is a compilation of the material received in response to the request. Abstracts discuss the following area: coal science, coal surface science, reaction chemistry, advanced process concepts, engineering fundamentals and thermodynamics, environmental science.

  9. Applied coal petrology: the role of petrology in coal utilization

    Energy Technology Data Exchange (ETDEWEB)

    Isabel Suarez-Ruiz; John Crelling [Instituto Nacional del Carbon (INCAR-CSIC), Oviedo (Spain)

    2008-08-15

    This book is an integrated approach towards the applications of coal (organic) petrology and discusses the role of this science in the field of coal and coal-related topics. Contents are: Introduction 2. Basic factors controlling coal quality and technological behaviour of coal 3. Mining and benefication 4. Coal combustion 5. Coal gasification 6. Coal liquefaction 7. Coal carbonisation 8. Coal-derived carbons 9. Coal as a Petroleum source rock and reservoir rock 10. Environmental and health aspects 11. Other applications of coal petrology.

  10. Use of the GranuFlow Process in Coal Preparation Plants to Improve Energy Recovery and Reduce Coal Processing Wastes

    Energy Technology Data Exchange (ETDEWEB)

    Glenn A. Shirey; David J. Akers

    2005-12-31

    With the increasing use of screen-bowl centrifuges in today's fine coal cleaning circuits, a significant amount of low-ash, high-Btu coal can be lost during the dewatering step due to the difficulty in capturing coal of this size consist (< 100 mesh or 0.15mm). The GranuFlow{trademark} technology, developed and patented by an in-house research group at DOE-NETL, involves the addition of an emulsified mixture of high-molecular-weight hydrocarbons to a slurry of finesized coal before cleaning and/or mechanical dewatering. The binder selectively agglomerates the coal, but not the clays or other mineral matter. In practice, the binder is applied so as to contact the finest possible size fraction first (for example, froth flotation product) as agglomeration of this fraction produces the best result for a given concentration of binder. Increasing the size consist of the fine-sized coal stream reduces the loss of coal solids to the waste effluent streams from the screen bowl centrifuge circuit. In addition, the agglomerated coal dewaters better and is less dusty. The binder can also serve as a flotation conditioner and may provide freeze protection. The overall objective of the project is to generate all necessary information and data required to commercialize the GranuFlow{trademark} Technology. The technology was evaluated under full-scale operating conditions at three commercial coal preparation plants to determine operating performance and economics. The handling, storage, and combustion properties of the coal produced by this process were compared to untreated coal during a power plant combustion test.

  11. Development of advanced NO{sub x} control concepts for coal-fired utility boilers. Quarterly technical progress report No. 2, January 1--March 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Newhall, J.; England, G.; Seeker, W.R.

    1991-12-23

    Energy and Environmental Research Corporation (EER) is currently conducting a test program to develop an advanced NO{sub x} control method utilizing reburning, promoted selective noncatalytic agent injection. The study will consist of fundamental and process testing over a large enough range of operating parameters to significantly reduce the risk of a full scale demonstration project. The test plan for the fundamental testing phase of the program is presented here.

  12. Study on relationship between consolidation-compactness and size grade shortage of coal gangue

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, Z.; Sui, W.; Zhao, D.; Guo, Q. [College of Mineral Resource and Environment Sciences, Xuzhou, Jiangsu (China)

    1999-05-01

    Coal gangue which is being used as construction and filling material must have a fairly high degree of compactness. But the compactness of coal waste appears to have been affected by its complex lithologic composition and grain size distribution. This paper discusses the relationship between the granular composition and the compactness of coal waste. The results of compacting and permeability test using coal gangue with different grain size distribution show that the main factor which affects the consolidation-compactness of coal gangue is the low proportion of fine-grain, especially silt and clay. If its content of fine-grain is increased, not only the coal gangue can achieve a high degree of consolidation under a low compacting energy, its water-stability can also be improved significantly. 3 refs., 7 figs., 3 tabs.

  13. Behavior of South Yakutsk coals during prolonged stockpiling

    Energy Technology Data Exchange (ETDEWEB)

    Fatkulin, I.Ya.; Gebler, I.I.; Tager, A.N.; Panteleev, E.V.

    1981-01-01

    When brought to the surface, coal starts to react with atmospheric oxygen, leading to irreversible structural changes in the coal substance and a gradual change in every property. Above all, oxidation causes a deterioration in caking capacity and coking properties, which largely determine the technological value of coals as a raw material for the production of metallurgical coke. These problems are very acute for the South Yakutsk coalfield, which holds major reserves of high-grade coking coals and is starting to be developed in certain areas such as Neryungrinsk. Limiting stockpiling periods have been established on the basis of special research and practical experience for various types of coals from the well-known USSR coalfields (Donbas, Kuzbas, Karaganda), but no such information is available on South Yakutsk coals apart from some references to their unusually high oxidation resistance. Coals can oxidize at various rates after their extraction, depending on many factors including rank, petrographic constitution, degree of comminution during mining and conditions at the stockpile (temperature, humidity, etc.). During stockpiling, the smaller coal particles oxidize more rapidly than the larger, by reason of their greater specific surface area; hence, the caking capacity of the fines (<1 mm) from a homogeneous vitrinite coal is always below that of the lump coals.As the ambient temperature and humidity of the stockpile are raised, oxidation proceeds more rapidly. It is greatly inhibited at subzero temperatures. As a result of experiments, it was found that: (1) coals in the South Yakutsk coalfield are exceptionally resistant to oxidation; (2) it is possible to establish substantial reserves in the stockyards of coal cleaning and processing undertakings; and (3) samples of South Yakutsk coals remain representative (for normal standard analytical and testing purposes) over a storage period up to 1 year.

  14. Coal combustion products

    Science.gov (United States)

    Kalyoncu, R.S.; Olson, D.W.

    2001-01-01

    Coal-burning powerplants, which supply more than half of U.S. electricity, also generate coal combustion products, which can be both a resource and a disposal problem. The U.S. Geological Survey collaborates with the American Coal Ash Association in preparing its annual report on coal combustion products. This Fact Sheet answers questions about present and potential uses of coal combustion products.

  15. Coal markets in transition

    Energy Technology Data Exchange (ETDEWEB)

    Romer, R.

    1990-01-01

    Describes Colorado's coal industry, and the implementation of a nine point mining plan announced in 1988. This plan includes an environmental regulatory review, coal royalty reform, production and marketing incentives, clean coal and clean air issues, and promotion of the coal industry. Other issues to be addressed are abandoned mine reclamation, abandoned mine safety and land reclamation after surface mining. International markets for Colorado coal are also discussed.

  16. Assessing coal burnout

    Energy Technology Data Exchange (ETDEWEB)

    Lowe, A. [Pacific Power, Sydney, NSW (Australia)

    1999-11-01

    Recent research has allowed a quantitative description of the basic process of burnout for pulverized coals to be made. The Cooperative Research Centre for Black Coal Utilization has built on this work to develop a coal combustion model which will allow plant engineers and coal company representatives to assess their coals for combustion performance. The paper describes the model and its validation and outlines how it is run. 2 figs.

  17. Mobilization of iron from coal fly ash was dependent upon the particle size and the source of coal.

    Science.gov (United States)

    Smith, K R; Veranth, J M; Lighty, J S; Aust, A E

    1998-12-01

    Particulate air pollution, including coal fly ash, contains iron, and some of the pathological effects after inhalation may be due to reactive oxygen species produced by iron-catalyzed reactions. The objective of this study was to determine whether iron, present in coal fly ash, was mobilized, leading to ferritin induction in human airway epithelial cells, and whether the size of the particles affected the amount of iron mobilized. Three types of coal were used to generate the three size fractions of fly ash collected. The Utah coal fly ash was generated from a bituminous b coal, the Illinois coal fly ash from a bituminous c coal, and the North Dakota coal fly ash from a lignite a coal. Three size fractions were studied to compare the amount of iron mobilized in human airway epithelial (A549) cells and by citrate in cell-free suspensions. The size fractions selected were fine (airborne particulate matter fraction greater than 10 microm. Coal fly ash samples were incubated with 1 mM citrate to determine if iron associated with coal fly ash could be mobilized. Iron was mobilized by citrate from all three size fractions of all three coal types to levels as high as 56.7 nmol of Fe/mg of coal fly ash after 24 h. With all three coal types, more iron was mobilized by citrate from the fraction than from the >2.5 microm fractions. Further, the mobilized iron was in the Fe(III) form. To determine if iron associated with the coal fly ash could be mobilized by A549 cells, cells were treated with coal fly ash, and the amount of the iron storage protein ferritin was determined after 24 h. Ferritin levels were increased by as much as 11.9-fold in cells treated with coal fly ash. With two of the three types of coal studied, more ferritin was induced in cells treated with the fraction than with the >2.5 microm fractions. Further, inhibition of the endocytosis of the coal fly ash by the cells resulted in ferritin levels that were near that of the untreated cells, suggesting that

  18. Trace element emissions from coal

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-09-15

    Trace elements are emitted during coal combustion. The quantity, in general, depends on the physical and chemical properties of the element itself, the concentration of the element in the coal, the combustion conditions and the type of particulate control device used, and its collection efficiency as a function of particle size. Some trace elements become concentrated in certain particle streams following combustion such as bottom ash, fly ash, and flue gas particulate matter, while others do not. Various classification schemes have been developed to describe this partitioning behaviour. These classification schemes generally distinguish between: Class 1: elements that are approximately equally concentrated in the fly ash and bottom ash, or show little or no fine particle enrichment, examples include Mn, Be, Co and Cr; Class 2: elements that are enriched in the fly ash relative to bottom ash, or show increasing enrichment with decreasing particle size, examples include As, Cd, Pb and Sb; Class 3: elements which are emitted in the gas phase (primarily Hg (not discussed in this review), and in some cases, Se). Control of class 1 trace elements is directly related to control of total particulate matter emissions, while control of the class 2 elements depends on collection of fine particulates. Due to the variability in particulate control device efficiencies, emission rates of these elements can vary substantially. The volatility of class 3 elements means that particulate controls have only a limited impact on the emissions of these elements.

  19. Tandem fluidized bed elutriator-Pneumatic classification of coal particles in a fluidized conveyer

    Institute of Scientific and Technical Information of China (English)

    Zhouen Liu; Yimin Xie; Yin Wang; Jian Yu; Shiqiu Gao; Guangwen Xu

    2012-01-01

    Coal moisture control (CMC) in coking process,which reduces coal moisture before loading the coal into the coke oven,allows substantial reduction in coking energy consumption and increase in coke productivity.The technology is seeking to integrate the coal classification,thus calling it the coal classifying moisture control (CCMC),to separate the fine and coarse coal fractions in the CMC process so that the downstream coal crushing can only treat the coarse fraction.CCMC adopts a reactor that integrates a fiuidized bottom section and a pneumatic conveying top section.The present work investigates the pneumatic classification behavior in a laboratory CCMC reactor with such a configuration by removing the coal fraction below a given size (e.g.,3.0 mm) from a 0 to 20,0 mm coal feed.The results show that the coal classification were dominated by the gas velocity in the top conveying section,and the required gas velocity for ensuring the maximal degree of removing a fine coal fraction could be roughly predicted by the Richardson and Zaki equation.The effect of bottom fluidization on the performance of CCMC is also examined.

  20. Minimum secure speed of fully mechanized coal face based on critical temperature of coal spontaneous combustion

    Institute of Scientific and Technical Information of China (English)

    Wei LIU; Yue-Ping QIN; Yong-Jiang HAO; Tian-Zhu GUI; Jing-Yan JIA

    2013-01-01

    The critical temperature theory of spontaneous combustion of coal and the numerical simulation method are used to explore the minimum secure speed of fully mechanized coal face to prevent the spontaneous combustion in goaf.Combined with the actual situation of workface 31005 in a coal mine,the highest temperatures in goaf at different advancing speeds were obtained by the numerical simulation of spontaneous combustion in goaf,and then a power function equation between the highest temperature and the advancing speed was achieved by regression analysis.The advancing speed corresponding to the critical temperature value was taken as the minimum safe speed of workface based on the equation.Finally,the accuracy and reliability of the speed were verified by the actual advancing process of workface 31005.The results of this research show that the new judgment method of the minimum safety speed has a higher value to be applied in the field.

  1. Self-scrubbing coal{sup TM}: An integrated approach to clean air. A proposed Clean Coal Technology Demonstration Project

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-01

    This environmental assessment (EA) was prepared by the U.S.Department of Energy (DOE), with compliance with the National Environmental Policy Act (NEPA) of 1969, Council on Environmental Quality (CE) regulations for implementating NEPA (40 CFR 1500-1508) and DOE regulations for compliance with NEPA (10 CFR 1021), to evaluate the potential environmental impacts associated with a proposed demonstration project to be cost-shared by DOE and Custom Coals International (CCI) under the Clean Coal Technology (CCT) Demonstration Program of DOE`s Office of Fossil Energy. CCI is a Pennsylvania general partnership located in Pittsburgh, PA engaged in the commercialization of advanced coal cleaning technologies. The proposed federal action is for DOE to provide, through a cooperative agreement with CCI, cost-shared funding support for the land acquisition, design, construction and demonstration of an advanced coal cleaning technology project, {open_quotes}Self-Scrubbing Coal: An Integrated Approach to Clean Air.{close_quotes} The proposed demonstration project would take place on the site of the presently inactive Laurel Coal Preparation Plant in Shade Township, Somerset County, PA. A newly constructed, advanced design, coal preparation plant would replace the existing facility. The cleaned coal produced from this new facility would be fired in full-scale test burns at coal-fired electric utilities in Indiana, Ohio and PA as part of this project.

  2. Coal data: A reference

    Energy Technology Data Exchange (ETDEWEB)

    1995-02-01

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  3. Lance for injecting highly-loaded coal slurries into the blast furnace

    Energy Technology Data Exchange (ETDEWEB)

    Illuminati, D.

    1991-10-29

    A lance is used to inject fuel oil into a blast furnace. This simple design permits conversion of coal water and coal tar slurries to a fine mist at very low flow rates. This design prevents the build-up of deposits which increases service life and steadies the flow rate.

  4. Low-rank coal research: Volume 3, Combustion research: Final report. [Great Plains

    Energy Technology Data Exchange (ETDEWEB)

    Mann, M. D.; Hajicek, D. R.; Zobeck, B. J.; Kalmanovitch, D. P.; Potas, T. A.; Maas, D. J.; Malterer, T. J.; DeWall, R. A.; Miller, B. G.; Johnson, M. D.

    1987-04-01

    Volume III, Combustion Research, contains articles on fluidized bed combustion, advanced processes for low-rank coal slurry production, low-rank coal slurry combustion, heat engine utilization of low-rank coals, and Great Plains Gasification Plant. These articles have been entered individually into EDB and ERA. (LTN)

  5. Approach to reducing the effect of bone-coal power station on radiation environment

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The effect of two bone-coal power stations (6 MWe) on environment wasinvestigated within the scope of the dose contribution caused by various radionucildes in different ways. It is found that the best measures to reduce the effect of bone-coal power station on radiation environment include to select a fine boiler system and a comprehensive utilization of the bone-coal cinder (BCC), soot and ash in the catchers.

  6. Characterization of the impregnated iron based catalyst for direct coal liquefaction by EXAFS

    Institute of Scientific and Technical Information of China (English)

    JianliYang; JishengZhun; 等

    2001-01-01

    Catalyst plays an important role in direct cola liquefaction(DCL)[1],Due to relatively high activity,low cost and environmentally benign for disposal,iron catalysts are regarded as the most attractive catalysts for DCL.To maximize catalytic effect and minimize catalyst usage,ultra-fine size catalysts are preferred.The most effective catalysts are found to be those impregnated onto coal because of their high dispersion on coal surface and intimate contact with coal particles.

  7. Structural comparison of hazardous and non-hazardous coals based on gas sorption experiments

    Energy Technology Data Exchange (ETDEWEB)

    Lakatos, J.; Toth, J. [Research Lab. for Mining Chemistry, Hungarian Academy of Sciences, Miskolc-Egyetemvaros (Hungary); Radnai-Gyoengyoes, Z. [Geopard Ltd., Pecs (Hungary); Bokanyi, L. [Miskolc Univ., Miskolc-Egyetemvaros (Hungary). Dept. of Process Engineering

    1997-12-31

    Comparison of carbon-dioxide and propane sorption at ambient temperature was used for characterising the difference of the structure of hazardous and non hazardous coals. However, hazardous coals were found more microporous or contain more closed pores than non hazardous ones, this difference couldn`t have been enlarged and attributed to one petrographic component by producing the density fractions. Gas sorption isobars (nitrogen, methane, ethane) are proposed to make a distinction between fine pore structure of coals. (orig.)

  8. Approach to reducing the effect of bone—coal power station on radiation environment

    Institute of Scientific and Technical Information of China (English)

    NIShi-Ying; GUPei-Long; 等

    2002-01-01

    The effect of two bone-coal power stations(6MWe) on environment was investigated within the scope of the dose contribution caused by various radionucildes in different ways.It is found that the best measures to reduce the effect of bone-coal power station on radiation environment include to select a fine boiler system and a comprehensive utilization of the bone-coal cinder(BCC),soot and ash in the catchers.

  9. Pushing the pulverized coal envelope with LEBS

    Energy Technology Data Exchange (ETDEWEB)

    Regan, J.W.; Borio, R.W.; Palkes, M. [and others

    1995-11-01

    In response to challenges from technologies such as IGCC and PFBC, the ABB LEBS Team has proposed removing the barriers to very large advances in environmental and thermal performance of pulverized coal plants. Pulverized coal will continue to be the source of more than half of our electric generation well into the next century and we must develop low-risk low-cost advances that will compete with the claimed performance of other technologies. This paper describes near-term PC technologies for new and retrofit applications which will accomplish this.

  10. Suitable retention and recovery technology of floor coal at ends of fully mechanized face with great mining heights

    Institute of Scientific and Technical Information of China (English)

    Zhang Nenghu; WU Qi; Yuan Yong; Bai Qingsheng

    2011-01-01

    Gateways at faces of great mining heights are mostly driven along the roof of coal seams. For gateway height restrictions, a 1-3 m floor coal is retained, leaving a triangular floor coal at the face ends, causing a loss of coal. In order to improve coal recovery rates and to ensure efficiency of equipment at coal mining faces, we investigated suitable retention methods and recovery technology of floor coal at face ends. The upper floor coal can directly be recovered by a shearer with floor dinting. The lower floor coal is recovered by shearer with floor dinting after advanced floor dinting and retaining a step for protecting coal sides in a haulage gateway. Field practice shows that this method can improve the coal recovery rates at fully mechanized working faces with great mining heights.

  11. Experimental study on pollution emission from combustion of blended coals

    Energy Technology Data Exchange (ETDEWEB)

    Li Yonghua; Chen Hongwei; Zhen Zhi; Liu Jizhen; Feng Zhaoxing; Dong Jianxun [North China Electric Power University, Baoding (China)

    2003-07-01

    The pollution brought by NOx and SOx produced by coal combustion is getting recognition by each country in the world. This paper adopts an experimental method, selects four kinds of lignite and three kinds of soft coal that are mainly used by some power plant and reports a study of the pollution emission characteristics of component and blended coals. The test rig is introduced from Canada with a capacity of 640 MJ/h with a complete milling system and flue gas online analysis system. The study focuses on the influence of oxygen concentration, pulverized coal fineness and pulverized coal nitrogen content on the pollution emission. The study is useful for achieving clean combustion in large power plants. 5 refs., 4 figs., 7 tabs.

  12. Gaseous phase coal surface modification. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Okoh, J.M.; Pinion, J.; Thiensatit, S.

    1992-05-07

    In this report, we present an improved, feasible and potentially cost effective method of cleaning and beneficiating ultrafine coal. Increased mechanization of mining methods and the need towards depyritization, and demineralization have led to an increase in the quantity of coal fines generated in recent times. For example, the amount of {minus}100 mesh coal occurring in coal preparation plant feeds now typically varies from 5 to 25% of the total feed. Environmental constraints coupled with the greatly increased cost of coal have made it increasingly important to recover more of these fines. Our method chemically modifies the surface of such coals by a series of gaseous phase treatments employing Friedel-Crafts reactions. By using olefins (ethene, propene and butene) and hydrogen chloride catalyst at elevated temperature, the surface hydrophobicity of coal is enhanced. This increased hydrophobicity is manifest in surface phenomena which reflect conditions at the solid/liquid interphase (zeta potential) and those which reflect conditions at the solid/liquid/gas interphases (contact angle, wettability and floatability).

  13. Which fine-tuning arguments are fine?

    CERN Document Server

    Grinbaum, Alexei

    2009-01-01

    The argument from naturalness is widely employed in contemporary quantum field theory. Essentially a formalized aesthetic criterion, it received a meaning in the debate on the Higgs mechanism, which goes beyond aesthetics. We follow the history of technical definitions of fine tuning at the scale of electroweak symmetry breaking. It is argued that they give rise to a special interpretation of probability, which we call Gedankenfrequency. By extension of its original meaning, the argument from naturalness is used to compare different models beyond the Standard Model. We show that in this case naturalness cannot be defined objectively. Rather, it functions as socio-historical heuristics in particle physics and it contributes to the advent of a probabilistic version of Popper's falsificationism.

  14. COMPARATIVE RESEARCH ON THE CHARACTERISTICS OF THE FLYASH FROM COAL REFUSE-FIRED AND COAL-FIRED POWER PLANTS

    Institute of Scientific and Technical Information of China (English)

    Yu Jifeng; Han Zuozhen; Wang Xiuying

    2000-01-01

    The physical,chemical and mineral facies properties of the flyash from Xiezhuang Coal Refuse-Fired Power Plant have been studied by means of naked eyes,microscope,chemical composition analysis and XRD analysis,and compared with that of the flyash from Tai'an Coal-Fired Power Plant.The result shows that the flyash from coal refuse-fired power plant is of better quality in making construction items,for being brighter in color,fine and high activity.Some ways of comprehensive utilization of the ash have been suggested in this paper.

  15. Pulverized coal burnout in blast furnace simulated by a drop tube furnace

    Energy Technology Data Exchange (ETDEWEB)

    Du, Shan-Wen [Steel and Aluminum Research and Development Department, China Steel Corporation, Kaohsiung 812 (China); Chen, Wei-Hsin [Department of Greenergy, National University of Tainan, Tainan 700 (China); Lucas, John A. [School of Engineering of the University of Newcastle, Callaghan, NSW 2308 (Australia)

    2010-02-15

    Reactions of pulverized coal injection (PCI) in a blast furnace were simulated using a drop tube furnace (DTF) to investigate the burnout behavior of a number of coals and coal blends. For the coals with the fuel ratio ranging from 1.36 to 6.22, the experimental results indicated that the burnout increased with decreasing the fuel ratio, except for certain coals departing from the general trend. One of the coals with the fuel ratio of 6.22 has shown its merit in combustion, implying that the blending ratio of the coal in PCI operation can be raised for a higher coke replacement ratio. The experiments also suggested that increasing blast temperature was an efficient countermeasure for promoting the combustibility of the injected coals. Higher fuel burnout could be achieved when the particle size of coal was reduced from 60-100 to 100-200 mesh. However, once the size of the tested coals was in the range of 200 and 325 mesh, the burnout could not be improved further, resulting from the agglomeration of fine particles. Considering coal blend reactions, the blending ratio of coals in PCI may be adjusted by the individual coal burnout rather than by the fuel ratio. (author)

  16. Survey of technological advancement of coal exploitation in Asia and Pacific for fiscal 1997. Formulation of production plans for model coal mines in China; 1997 nendo Asia Taiheiyo sekitan kaihatsu kodoka chosa. Chugoku ni okeru model tanko no seisan keikaku no sakutei

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In view of the prospective demand for coal in China and of the current state of transportation, a development plan is formulated for Tangkou Mining Area (of model mines) for the purpose of realizing efficient exploitation of coal. The infrastructures for coal transportation are complete in this area, and delivery of coal is easy from this area to the coal demanding regions. Although coal seams are quite deep in the ground, the important ones contain rich reserves. Exploitation is carried out under a vertical shaft scheme, in which pits extend horizontally at the level of 950m below the sea surface. As for production, an annual yield of 3-million ton is predicted thanks to two compositely mechanized coal faces. Coal is won by the monolayer side hole method in the case of seams not thicker than 4.0m, and by the caved stope method in the case not thinner than 4.0m. Employed for the mines are 1077 people. Operation days are 300, efficiency 15t/man/shift. The annual sale in total is expected to be worth 759-million 534.6-thousand yuan. To be required for the construction will be 1.2-billion yuan for mines and 0.2-billion yuan for coal dressing facilities, or 1.4-billion yuan in all, and the figures indicate that the plan is economically promising. 43 figs., 119 tabs.

  17. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization

    Science.gov (United States)

    Jha, Mahesh C.; Blandon, Antonio E.; Hepworth, Malcolm T.

    1988-01-01

    Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

  18. Coal technology program. Progress report, May 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-07-01

    Two successful operability tests with sustained operation of the bench-scale hydrocarbonizer were achieved with Illinois No. 6 coal diluted with char. Several activities in the area of nondestructive testing of coatings are reviewed. Failure analysis activities included examination of several components from the solvent refined coal plants at Wilsonville, Alabama, and Tacoma, Washington. In the gas-fired potassium boiler project, all of the design work were completed except for several of the instrument and control drawings. In the design studies of a coal-fired alkali metal vapor topping cycle, the first phase of a cycle analysis and the design and analysis of a metal vapor turbine were completed. A report entitled ''Critical Component Test Facility--Advance Planning for Test Modules'' presents the planning study for the conceptual design of component test modules on a nonsite-specific basis. Engineering studies, project evaluation and process and program analysis of coal conversion processes were continued. A report on the landfill storage of solid wastes from coal conversion is being finalized. In the coal-fueled MIUS project, a series of successful tests of the coal feeding system and a report on the analysis of 500-hr fire-side corrosion tests in a fluidized bed combustor were completed.

  19. Coal combustion science. Quarterly progress report, April 1993--June 1993

    Energy Technology Data Exchange (ETDEWEB)

    Hardesty, D.R. [ed.

    1994-05-01

    This document is a quarterly status report of the Coal Combustion Science Project that is being conducted at the Combustion Research Facility, Sandia National Laboratories. The information reported is for Apr-Jun 1993. The objective of this work is to support the Office of Fossil Energy in executing research on coal combustion science. This project consists of basic research on coal combustion that supports both the PETC Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. The objective of the kinetics and mechanisms of pulverized coal char combustion task is to characterize the combustion behavior of selected US coals under conditions relevant to industrial pulverized coal-fired furnaces. Work is being done in four areas: kinetics of heterogeneous fuel particle populations; char combustion kinetics at high carbon conversion; the role of particle structure and the char formation process in combustion and; unification of the Sandia char combustion data base. This data base on the high temperature reactivities of chars from strategic US coals will permit identification of important fuel-specific trends and development of predictive capabilities for advanced coal combustion systems. The objective of the fate of inorganic material during coal combustion task is the establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of inorganic material during coal combustion as a function of coal type, particle size and temperature, the initial forms and distribution of inorganic species in the unreacted coal, and the local gas temperature and composition. In addition, optical diagnostic capabilities are being developed for in situ, real-time detection of inorganic vapor species and surface species during ash deposition. Selected papers have been indexed separately for inclusion in the Energy Science and Technology Database.

  20. Coal combustion science. Quarterly progress report, July--September 1994

    Energy Technology Data Exchange (ETDEWEB)

    Hardesty, D.R. [ed.; Baxter, L.L.; Davis, K.A.; Hurt, R.H.; Yang, N.Y.C.

    1995-09-01

    This document is a quarterly status report of the Coal Combustion Science Project that is being conducted at the Combustion Research Facility, Sandia National Laboratories, Livermore, California. The information reported is for the period July-September 1994. The objective of this work is to support the Office of Fossil Energy in executing research on coal combustion science. This project consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project.

  1. ENEL's strategy for clean coal utilisation

    Energy Technology Data Exchange (ETDEWEB)

    Arrighi, Leonardo [ENEL Generation and Energy Management Division, Rome (Italy). Thermal Plant Development and Assistance Technical Area; Pasini, Sauro [ENEL Engineering and Innovation Division, Pisa (Italy). Research Technical Area

    2009-07-01

    Enel is targeting an increase of coal-fired capacity in order to balance the mix of fuel for electricity production. Replacement of old coal- and oil-fired units by new coal-fired ones, more efficient and environmentally friendlier, is the main approach. The launch of several prototype projects in the field of CO{sub 2} separation, oxy-combustion, hydrogen electricity production and the partnership in advanced projects (VGB COMTES700 and EPRI IGCC P66) complete the strategy to reduce greenhouse gases emissions associated with coal combustion. (orig.)

  2. Engineer exchanging project on coal mine technology field in fiscal 1999. International information exchanging project (advance survey on North America); 1999 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) kokusai koryu jigyo. Jizen chosa (Hokubei)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This project has been performed with an intention of making visiting surveys and information collection at coal related organizations in overseas coal producing countries on production technology levels and trends. The project is intended to serve for improvement in the contents of and smooth execution of the engineer exchange project in the 'coal mine technology field. It was carried out by the site surveys. The surveys revealed that the situation of the American coal industry is expected of stable increase in the demand and supply in the future, but the coal price is on the falling trend, and therefore, the industry is compelled to further increase the intensity and enhance the productivity. The industry is strongly influenced by the amended air pollution prevention act and nature destruction problems, hence further coal mine curtailment is estimated. Under such a background, it was found that the long-wall mining process progressing toward larger scale and higher productivity, and the high-wall mining process that provides higher productivity at lower cost and has less impact on the environmental problems can continue development in mountainous areas, particularly in the Appalachian area. The high-wall mining process mines coal at exposed facings on the side of a mountain by using a continuous miner, and transports the coal using machines. (NEDO)

  3. MERCURY CONTROL WITH ADVANCED HYBRID PARTICULATE COLLECTOR

    Energy Technology Data Exchange (ETDEWEB)

    Ye Zhuang; Stanley J. Miller

    2005-05-01

    This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-00NT40769 and specifically addressed Technical Topical Area 4-Testing Novel and Less Mature Control Technologies on Actual Flue Gas at the Pilot Scale. The project team included the Energy & Environmental Research Center (EERC) as the main contractor; W.L. Gore & Associates, Inc., as a technical and financial partner; and the Big Stone Power Plant operated by Otter Tail Power Company, host for the field-testing portion of the research. Since 1995, DOE has supported development of a new concept in particulate control called the advanced hybrid particulate collector (AHPC). The AHPC has been licensed to W.L. Gore & Associates, Inc., and has been marketed as the Advanced Hybrid{trademark} filter by Gore. The Advanced Hybrid{trademark} filter combines the best features of electrostatic precipitators (ESPs) and baghouses in a unique configuration, providing major synergism between the two collection methods, both in the particulate collection step and in the transfer of dust to the hopper. The Advanced Hybrid{trademark} filter provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and it solves the problem of reentrainment and re-collection of dust in conventional baghouses. The Advanced Hybrid{trademark} filter also appears to have unique advantages for mercury control over baghouses or ESPs as an excellent gas--solid contactor. The objective of the project was to demonstrate 90% total mercury control in the Advanced Hybrid{trademark} filter at a lower cost than current mercury control estimates. The approach included bench-scale batch tests, larger-scale pilot testing with real flue gas on a coal-fired combustion system, and field demonstration at the 2.5-MW (9000-acfm) scale at a utility power plant to prove scale-up and demonstrate longer-term mercury control

  4. TOXIC SUBSTANCES FROM COAL COMBUSTION

    Energy Technology Data Exchange (ETDEWEB)

    A KOLKER; AF SAROFIM; CL SENIOR; FE HUGGINS; GP HUFFMAN; I OLMEZ; J LIGHTY; JOL WENDT; JOSEPH J HELBLE; MR AMES; N YAP; R FINKELMAN; T PANAGIOTOU; W SEAMES

    1998-12-08

    carried out during August at the Advanced Photon Source (APS), the new synchrotron facility at Argonne National Laboratory, Chicago, IL. Further analysis of small-scale combustion experiments conducted at PSI in Phase I was completed this quarter. The results of these experiments for the first time suggest almost complete vaporization of certain trace elements (Se, Zn) from coal combustion in the flame zone, in accordance with theoretical equilibrium predictions. Other elements (As, Sb, Cr) appeared considerably less volatile and may react with constituents in the bulk ash at combustion temperatures. The combustion section of the University of Arizona's Downflow Combustor was completely rebuilt. The University of Utah worked on setting up EPA Method 26A to give the capability to measure chlorine in flue gas. The chlorine kinetic calculations performed as part of the Phase I program were found to have an error in the initial conditions. Therefore, the calculations were re-done this quarter with the correct starting conditions. Development of a quasi-empirical emissions model based on reported emissions of particulate matter from field measurements was continued this quarter. As a first step in developing the ToPEM, we developed a sub-model that calculates the evaporation of major elements (Na, K, Fe, Si, Al, Ca and Mg) from both inherent and extraneous minerals of coal. During this quarter, this sub-model was included into EMAF, which formed the ToPEM. Experimental data from the Phase I program were used to test and modify the sub-model and the ToPEM.

  5. Evaluation of technology modifications required to apply clean coal technologies in Russian utilities. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-01

    The report describes the following: overview of the Russian power industry; electric power equipment of Russia; power industry development forecast for Russia; clean coal technology demonstration program of the US Department of Energy; reduction of coal TPS (thermal power station) environmental impacts in Russia; and base options of advanced coal thermal power plants. Terms of the application of clean coal technology at Russian TPS are discussed in the Conclusions.

  6. Low-rank coal research. Quarterly report, January--March 1990