WorldWideScience

Sample records for adsorption heat

  1. Heats of adsorption for charcoal nitrogen systems

    Energy Technology Data Exchange (ETDEWEB)

    Prasad, M.; Akkimaradi, B.S.; Rastogi, S.C. [ISRO Satellite Centre, Bangalore (India). Thermal Systems Group; Rao, R.R. [Government College for Boys, Kolar, Karnataka (India); Srinivasan, K. [Indian Institute of Science, Bangalore (India). Dept. of Mechanical Engineering

    1999-07-01

    This paper develops an empirical equation for correlation of the loading dependence of the heat of adsorption for two samples of activated charcoal-nitrogen systems. Details are given of the use of isotherm data, the evaluation of the heat of adsorption using the Clausius-Clapeyron equation, the plotting of primary adsorption data, and the plotting of the heat of adsorption as a function of the loading of the two samples. The need to consider the heat of adsorption property when designing a system in which a gaseous medium is adsorbed by a solid sorbent is discussed. (UK)

  2. Solar heat utilization for adsorption cooling device

    OpenAIRE

    Malcho Milan; Patsch Marek; Pilát Peter

    2012-01-01

    This article deals with possibility of solar system connection with adsorption cooling system. Waste heat from solar collectors in summer is possible to utilize in adsorption cooling systems, which desorption temperatures have to be lower than temperature of heat transport medium operation temperature. For verification of work of this system was constructed on the Department of power engineering on University of Zilina solar adsorption cooling device.

  3. Solar heat utilization for adsorption cooling device

    Directory of Open Access Journals (Sweden)

    Malcho Milan

    2012-04-01

    Full Text Available This article deals with possibility of solar system connection with adsorption cooling system. Waste heat from solar collectors in summer is possible to utilize in adsorption cooling systems, which desorption temperatures have to be lower than temperature of heat transport medium operation temperature. For verification of work of this system was constructed on the Department of power engineering on University of Zilina solar adsorption cooling device.

  4. Efficient adsorption refrigerators integrated with heat pipes

    Energy Technology Data Exchange (ETDEWEB)

    Wang, R.Z. [Institute of Refrigeration and Cryogenics, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200030 (China)

    2008-03-15

    Several novel ideas to use heat pipes in adsorption water chiller or ice maker are presented in this paper. Experimental results have shown that the adsorption refrigerators are very efficient. The first example of such systems is a small scale silica gel-water adsorption water chiller with cooling power rated as 10 kW; the system could be powered by 60-100 C hot water, a cooling COP = 0.4 has been achieved when driven by 85 C hot water. This adsorption chiller has been used for solar powered air conditioner and also as the chiller for CCHP system. The second example is a silica gel-water adsorption room air conditioner powered by 80 C hot water. The system is very compact and is suggested for potential applications of micro CCHP system based on fuel cells. The system has a COP of over 0.3 and cooling power of about 1 kW. The third example is the use of split heat pipes to heat or cool the adsorber for making ice in fishing boats. The application of these technologies avoids the corrosion of adsorber at the heating phase by exhausted gases and at the cooling phase by seawater, and also has the advantage of high heat transfer performance. With such arrangement and careful considerations of the arrangement of wicks in heat pipes, and also the use of composite adsorbent (calcium chloride and activated carbon)-ammonia adsorption pair, the system test has shown the specific refrigeration power for more than 730 W/kg at -15 C. (author)

  5. Possibility of using adsorption refrigeration unit in district heating network

    OpenAIRE

    Grzebielec Andrzej; Rusowicz Artur; Jaworski Maciej; Laskowski Rafał

    2015-01-01

    Adsorption refrigeration systems are able to work with heat sources of temperature starting with 50 °C. The aim of the article is to determine whether in terms of technical and economic issues adsorption refrigeration equipment can work as elements that produce cold using hot water from the district heating network. For this purpose, examined was the work of the adsorption air conditioning equipment cooperating with drycooler, and the opportunities offered by the district heating network in W...

  6. Characterization of zeolite-based coatings for adsorption heat pumps

    CERN Document Server

    Freni, Angelo; Bonaccorsi, Lucio; Chmielewski, Stefanie; Frazzica, Andrea; Calabrese, Luigi; Restuccia, Giovanni

    2015-01-01

    This book proposes a radically new approach for characterizing thermophysical and mechanical properties of zeolite-based adsorbent coatings for Adsorptive Heat Transformers (AHT). It presents a developed standard protocol for the complete characterization of advanced coated adsorbers. Providing an in-depth analysis of the different procedures necessary for evaluating the performance of adsorbers, it also presents an analysis of their stability under the hydrothermal and mechanical stresses during their entire life cycle. Adsorptive Heat Transformers (AHT), especially adsorption chillers and

  7. Heat transfer to the adsorbent in solar adsorption cooling device

    Science.gov (United States)

    Pilat, Peter; Patsch, Marek; Papucik, Stefan; Vantuch, Martin

    2014-08-01

    The article deals with design and construction of solar adsorption cooling device and with heat transfer problem in adsorber. The most important part of adsorption cooling system is adsorber/desorber containing adsorbent. Zeolith (adsorbent) type was chosen for its high adsorption capacity, like a coolant was used water. In adsorber/desorber occur, at heating of adsorbent, to heat transfer from heat change medium to the adsorbent. The time required for heating of adsorber filling is very important, because on it depend flexibility of cooling system. Zeolith has a large thermal resistance, therefore it had to be adapted the design and construction of adsorber. As the best shows the tube type of adsorber with double coat construction. By this construction is ensured thin layer of adsorbent and heating is quick in all volume of adsorbent. The process of heat transfer was experimentally measured, but for comparison simulated in ANSYS, too.

  8. Possibility of using adsorption refrigeration unit in district heating network

    Science.gov (United States)

    Grzebielec, Andrzej; Rusowicz, Artur; Jaworski, Maciej; Laskowski, Rafał

    2015-09-01

    Adsorption refrigeration systems are able to work with heat sources of temperature starting with 50 °C. The aim of the article is to determine whether in terms of technical and economic issues adsorption refrigeration equipment can work as elements that produce cold using hot water from the district heating network. For this purpose, examined was the work of the adsorption air conditioning equipment cooperating with drycooler, and the opportunities offered by the district heating network in Warsaw during the summer. It turns out that the efficiency of the adsorption device from the economic perspective is not sufficient for production of cold even during the transitional period. The main problem is not the low temperature of the water supply, but the large difference between the coefficients of performance, COPs, of adsorption device and a traditional compressor air conditioning unit. When outside air temperature is 25 °C, the COP of the compressor type reaches a value of 4.49, whereas that of the adsorption device in the same conditions is 0.14. The ratio of the COPs is 32. At the same time ratio between the price of 1 kWh of electric power and 1 kWh of heat is only 2.85. Adsorption refrigeration equipment to be able to compete with compressor devices, should feature COPads efficiency to be greater than 1.52. At such a low driving temperature and even changing the drycooler into the evaporative cooler it is not currently possible to achieve.

  9. THERMODYNAMIC STUDY OF HIGH-PRESSURE ADSORPTION OF METHANE AND HEATS OF METHANE ADSORPTION ON MICROPOROUS CARBONS

    Institute of Scientific and Technical Information of China (English)

    杨晓东; 林文胜; 郑青榕; 顾安忠; 鲁雪生; 宋燕

    2002-01-01

    The study was done for high-pressure adsorption of methane on microporous carbons, which has an ANG vehicular application background. Adsorption isotherm of methane on super activated carbon up to 6 MPa was measured and isosteric heats of methane adsorption on a number of microporous carbons were determined from adsorption isosteres by the Clausius-Clapeyron equation. The variation of the isosteric heats of adsorption with the amount of methane adsorbed was discussed.

  10. Development of an adsorption chiller and heat pump for domestic heating and air-conditioning applications

    Energy Technology Data Exchange (ETDEWEB)

    Nunez, Tomas; Henning, Hans-Martin [Fraunhofer Institut for Solar Energy Systems ISE, Heidenhofstrasse 2, 79110 Freiburg (Germany); Mittelbach, Walter [SorTech AG, Weinbergweg 23, 06120 Halle a.d. Saale (Germany)

    2007-09-15

    The scope of this paper is to present the development of a prototype of a small adsorption heat pump working on the adsorption pair silica gel-water. The development of this prototype with remarkable high power densities has been carried out during the last year and is a result of continued joint work on adsorption heat transformation systems carried out at SorTech AG and the Fraunhofer Institute. (author)

  11. Performance Analysis of Waste Heat Driven Pressurized Adsorption Chiller

    KAUST Repository

    LOH, Wai Soong

    2010-01-01

    This article presents the transient modeling and performance of waste heat driven pressurized adsorption chillers for refrigeration at subzero applications. This innovative adsorption chiller employs pitch-based activated carbon of type Maxsorb III (adsorbent) with refrigerant R134a as the adsorbent-adsorbate pair. It consists of an evaporator, a condenser and two adsorber/desorber beds, and it utilizes a low-grade heat source to power the batch-operated cycle. The ranges of heat source temperatures are between 55 to 90°C whilst the cooling water temperature needed to reject heat is at 30°C. A parametric analysis is presented in the study where the effects of inlet temperature, adsorption/desorption cycle time and switching time on the system performance are reported in terms of cooling capacity and coefficient of performance. © 2010 by JSME.

  12. Experimental analysis of an adsorption refrigerator with mass and heat-pipe heat recovery process

    International Nuclear Information System (INIS)

    Highlights: ► We develop one heat pipe type adsorption refrigerator. ► New compound adsorbent of CaCl2/activated carbon–ammonia can work more effectively. ► Combined mass recovery-heat pipe heat recovery can improve adsorption performance. ► Combined mass recovery-heat pipe heat recovery can reduce cycle time. - Abstract: A heat pipe type adsorption refrigerator system is proposed and investigated, which can be powered by solar energy or waste heat of engine. The study assesses the performance of compound adsorbent (CaCl2 and activated carbon)–ammonia adsorption refrigeration cycle with different orifice sets and different mass and heat recovery processes by experimental prototype machine. Specific cooling power (SCP) and coefficient of performance (COP) were calculated with experimental data to analyze the influences of operating condition. The results show that the jaw opening of the hand needle nozzle can influence the adsorption performance obviously and the thermostatic expansion valve (TEV) is effective in the intermediate cycle time in the adsorption refrigeration system. The SCP of the cycle with the mass-heat recovery together (combined recovery process) is superior to that of the conventional cycles with mass recovery or heat recovery independently.

  13. Possibility of using adsorption refrigeration unit in district heating network

    Directory of Open Access Journals (Sweden)

    Grzebielec Andrzej

    2015-09-01

    Full Text Available Adsorption refrigeration systems are able to work with heat sources of temperature starting with 50 °C. The aim of the article is to determine whether in terms of technical and economic issues adsorption refrigeration equipment can work as elements that produce cold using hot water from the district heating network. For this purpose, examined was the work of the adsorption air conditioning equipment cooperating with drycooler, and the opportunities offered by the district heating network in Warsaw during the summer. It turns out that the efficiency of the adsorption device from the economic perspective is not sufficient for production of cold even during the transitional period. The main problem is not the low temperature of the water supply, but the large difference between the coefficients of performance, COPs, of adsorption device and a traditional compressor air conditioning unit. When outside air temperature is 25 °C, the COP of the compressor type reaches a value of 4.49, whereas that of the adsorption device in the same conditions is 0.14. The ratio of the COPs is 32. At the same time ratio between the price of 1 kWh of electric power and 1 kWh of heat is only 2.85. Adsorption refrigeration equipment to be able to compete with compressor devices, should feature COPads efficiency to be greater than 1.52. At such a low driving temperature and even changing the drycooler into the evaporative cooler it is not currently possible to achieve.

  14. SAPO-34 coated adsorbent heat exchanger for adsorption chillers

    International Nuclear Information System (INIS)

    In this work, adsorbent coatings on aluminum surfaces were prepared by dip-coating method starting from a water suspension of SAPO-34 zeolite and a silane-based binder. Silane-zeolite coatings morphology and surface coverage grade were evaluated by scanning electron microscopy. Adhesive and mechanical properties were evaluated by peel, pull-off, impact and micro-hardness tests, confirming the good interaction between metal substrate, binder and zeolite. Adsorption equilibrium and kinetics of water vapour adsorption on the adsorbent coating were studied in the range T = 30–150 °C and pH2O = 11 mbar using a CAHN 2000 thermo-balance. It was found that, in the investigated conditions, the organic binder doesn't affect the water adsorption capacity and adsorption kinetics of the original SAPO-34 zeolite. Subsequently, the zeolite coating was applied on a finned flat-tubes aluminum heat exchanger realizing a full-scale AdHEx with an uniform adsorbent coating 0.1 mm thick and a metal/adsorbent mass ratio = 6. The cooling capacity of the realized coated AdHEx was measured by a lab-scale adsorption chiller under realistic operating conditions for air conditioning applications. The coated AdHEx produced up to 675 W/kgads specific cooling power with a cycle time of 5 min. Adsorption stability of the coated adsorber subjected to 600 sorption cycles was successfully verified. - Highlights: • Adsorbent coatings on aluminum surfaces were prepared by dip-coating method. • Silane-zeolite coatings morphology, and mechanical properties were studied. • The zeolite coating was applied on a finned flat-tubes aluminum heat exchanger. • The coated AdHEx was tested in a lab scale adsorption chiller

  15. Comparison of Microwave and Conventional Driven Adsorption Heat Pump Cycle Duration

    OpenAIRE

    Demir, Hasan

    2015-01-01

    The present experimental study includes comparison of microwave regenerated and conventional heated adsorbent bed of adsorption heat pump. The novel adsorption heat pump driving with microwave heating system was designed and manufactured. Microwave oven was constructed for providing homogeneous temperature distribution in the adsorbent bed. Temperature and pressure variations in the adsorption heat pump for both microwave and conventional regenerated cycles were measured and investigated. Dur...

  16. Hydrothermal treatment of sorption materials. Implications on adsorption heat pumps

    Energy Technology Data Exchange (ETDEWEB)

    Henninger, S.K.; Mueller, S.; Ratzsch, K.F.; Schossig, P.; Henning, H.M. [Fraunhofer-Institut fuer Solare Energiesysteme (ISE), Freiburg im Breisgau (Germany). Dept. of Thermal Systems and Buildings; Munz, G. [PSE AG, Freiburg (Germany)

    2010-07-01

    Material stability of adsorbents for thermally driven systems like heat storage and heat transformation plays a key role. In particular high power-density applications like adsorption heat pumps and chillers in combination with recently developed adsorption materials lead to a significant increased number of cycles over the lifetime (<100'000) making cycle stability crucial. With regard to current developments on composite structures improving the heat and mass transfer, additional stability analysis like thermo-mechanical properties are now getting into focus. This contribution gives a broad overview on the stability of current available sorption materials like silica gels and zeolites, recently developed (silica-) aluminophosphates (AIPO/SAPO) and most novel synthesized metal organic framework (MOF) materials under hydrothermal treatment. The results give a first indication on the suitability of these materials for the use in heat storage, thermally driven sorption heat pumps and cooling machines. Pure powders as well as composites have been analysed under continuous cycling conditions. Whereas the stability of powders and granules have been analysed in-situ by thermogravimetric cycle measurements, a cycling-test rig has been developed in order to realise a lifetime stress of composites consisting of active sorption material and a support structure. The need for a first stage short-cycle analysis is demonstrated impressively by the dramatic loss of more than 50% in sorption capacity of a SAPO-34 sample within the first 10 cycles. Several composite samples have passed a treatment of 30'000 cycles or more and show continuous degradation effects leading to a reduction in sorption capacity of 20% compared to the initial value. (orig.)

  17. Influence of heat treatment of rayon-based activated carbon fibers on the adsorption of formaldehyde.

    Science.gov (United States)

    Rong, Haiqin; Ryu, Zhenyu; Zheng, Jingtang; Zhang, Yuanli

    2003-05-15

    The influence of heat treatment of rayon-based activated carbon fibers on the adsorption behavior of formaldehyde was studied. Heat treatment in an inert atmosphere of nitrogen for rayon-based activated carbon fibers (ACFs) resulted in a significant increase in the adsorption capacities and prolongation of breakthrough time on removing of formaldehyde. The effect of different heat-treatment conditions on the adsorption characteristics was investigated. The porous structure parameters of the samples under study were investigated using nitrogen adsorption at the low temperature 77.4 K. The pore size distributions of the samples under study were calculated by density functional theory. With the aid of these analyses, the relationship between structure and adsorption properties of rayon-based ACFs for removing formaldehyde was revealed. Improvement of their performance in terms of adsorption selectivity and adsorption rate for formaldehyde were achieved by heat post-treatment in an inert atmosphere of nitrogen.

  18. Metabolic Heat Regenerated Temperature Swing Adsorption for CO2, Thermal and Humidity Control Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Metabolic heat regenerated Temperature Swing Adsorption (MTSA) technology is proposed for a Portable Life Support System to remove and reject heat and carbon...

  19. Overall Heat and Mass Transfer Coefficient of Water Vapor Adsorption

    Science.gov (United States)

    Hamamoto, Yoshinori; Mori, Hideo; Godo, Masazumi; Miura, Kunio; Watanabe, Yutaka; Ishizawa, Toshihiko; Takatsuka, Takeshi

    A fundamental investigation was performed to develop a compact and simple desiccant ventilation unit which is one of the main components of a novel energy saving air-conditioning system. Water vapor in the air is adsorbed and/or desorbed to be controlled the humidity of supply air through a unit of an adsorbent packed bed. A numerical simulation helps to understand the phenomena of heat and mass transfer in the bed. Overall transfer coefficients of them as properties for the simulation were estimated by performing both experiment and calculation. It was clarified that the transient overall equivalent heat and mass transfer does not strongly depend on the air flow rate through the packed bed, the averaged equivalent mass transfer is governed by surface and pore diffusion in a particle of adsorbent at low flow rate. Moreover, the coefficient during the adsorption process is slightly larger than desorption. An equation of the overall mass transfer coefficient is derived. It shows five times as large as the value estimated by experiment. Therefore, the correlation and fitting parameters are presented for prediction of the overall heat and mass transfer coefficients. The estimation accuracy was improved.

  20. Particle size dependent heat of adsorption for CO on supported Pd nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Fischer-Wolfarth, Jan-Henrik; Flores-Camacho, Jose Manuel; Hartmann, Jens; Schauermann, Swetlana; Freund, Hans-Joachim [Fritz-Haber-Institute, Max-Planck-Society, Faradayweg 4-6, 14195 Berlin (Germany); Farmer, Jason; Campbell, Charles [Department of Chemistry, University of Washington, Seattle (United States)

    2010-07-01

    The particle size dependence of the heat of adsorption for carbon monoxide on supported Pd nanoparticles has been investigated at 300 K with a new single crystal microcalorimeter and compared to the heat of adsorption on Pd(111). The average Pd particle size was varied systematically in the range of 100 to 4900 Pd atoms, i.e. 2 to 8 nm diameter. All nanoparticles were supported on Fe{sub 3}O{sub 4}(111)/Pt(111). The initial heat of adsorption was found to decrease monotonically with decreasing particle size below 4 nm. The correlation of the heat of adsorption with a particle size dependent reduction of the particle lattice constant is discussed. Further, the microcalorimetry technique used to determine the adsorption energies and its performance is presented.

  1. Isosteric heats of adsorption for activated carbons made from corn cob

    Science.gov (United States)

    Beckner, M.; Olsen, R.; Romanos, J.; Burress, J.; Dohnke, E.; Carter, S.; Casteel, G.; Wexler, C.; Pfeifer, P.

    2010-03-01

    Activated carbons made from corn cob show promise as materials for high-capacity hydrogen storage. As part of our characterization of these materials, we are interested in learning how different production methods affect the adsorption energies. In this talk, we will present experimentally measured isosteric heats of adsorption for various activated carbons calculated using the Clausius-Clayperon equation and hydrogen isotherms at temperatures of 80 and 90K and pressures up to 100 bar measured on a volumetric instrument. We discuss differences observed between isosteric heats determined from Gibbs excess adsorption vs. absolute adsorption curves.

  2. Heat transfer design in adsorption refrigeration systems for efficient use of low-grade thermal energy

    International Nuclear Information System (INIS)

    Adsorption refrigeration and heat pump systems have been considered as important means for the efficient use of low-grade thermal energy of 60-150 oC. Sorption systems are merely thermodynamic systems based on heat exchangers, and therefore a good design to optimize heat and mass transfer with reaction or sorption processes is very important, for which the notable technique is the use of expanded graphite to improve both heat and mass transfer in the chemisorption beds. Studies have also shown the need to enhance the heat transfer in adsorption bed by matching with the efficient heat transfer of thermal fluids. Heat pipes and good thermal loop design coupled with adsorption beds could yield higher thermal performance of a sorption system. A novel design with passive evaporation, known as rising film evaporation coupled with a gravity heat pipe was introduced for high cooling output. It has also been shown that the performance of traditional heat and mass recovery in the sorption systems is limited, and novel arrangement of thermal fluid and refrigerant may improve the performance of sorption systems. Based upon the above researches, various sorption systems have been developed, and high performances have been reached. -- Highlights: →Heat transfer design in adsorption refrigeration systems is researched. →Solidified adsorbent is an effective way to improve the heat transfer. →Heat pipe and rising film evaporation could generate high cooling output. With efficient design two adsorption systems are developed. →Double way and double effect cycle is introduced.

  3. Simulated Lunar Testing of Metabolic Heat Regenerated Temperature Swing Adsorption

    Science.gov (United States)

    Padilla, Sebastian A.; Bower, Chad E.; Iacomini, Christie S.; Paul, Heather L.

    2012-01-01

    Metabolic heat regenerated Temperature Swing Adsorption (MTSA) technology is being developed for thermal and carbon dioxide (CO2) control for a Portable Life Support System (PLSS), as well as water recycling. An Engineering Development Unit (EDU) of the MTSA Subassembly (MTSAS) was designed and assembled for optimized Martian operations, but also meets system requirements for lunar operations. For lunar operations the MTSA sorption cycle is driven via a vacuum swing between suit ventilation loop pressure and lunar vacuum. The focus of this effort was testing in a simulated lunar environment. This environment was simulated in Paragon's EHF vacuum chamber. The objective of the testing was to evaluate the full cycle performance of the MTSA Subassembly EDU, and to assess CO2 loading and pressure drop of the wash coated aluminum reticulated foam sorbent bed. Lunar environment testing proved out the feasibility of pure vacuum swing operation, making MTSA a technology that can be tested and used on the Moon prior to going to Mars. Testing demonstrated better than expected CO2 Nomenclature loading on the sorbent and nearly replicates the equilibrium data from the sorbent manufacturer. This exceeded any of the previous sorbent loading tests performed by Paragon. Subsequently, the increased performance of the sorbent bed design indicates future designs will require less mass and volume than the current EDU rendering MTSA as very competitive for Martian PLSS applications.

  4. High Performance Cascading Adsorption Refrigeration Cycle with Internal Heat Recovery Driven by a Low Grade Heat Source Temperature

    OpenAIRE

    Yuki Ueda; Atsushi Akisawa; Aep Saepul Uyun; Takahiko Miyazaki

    2009-01-01

    This paper presents the performance of an advanced cascading adsorption cycle that utilizes a driven heat source temperature between 90–130 ºC. The cycle consists of four beds that contain silica gel as an adsorber fill. Two of the beds work in a single stage cycle that is driven by an external heat source, while the other two beds work in a mass recovery cycle that is driven by waste heat of sensible and adsorption heat of the high temperature cycle. The performances, in terms of the coef...

  5. Adsorption Behavior of Heat Modified Soybean Oil via Boundary Lubrication Coefficient of Friction Measurements

    Science.gov (United States)

    The frictional behaviors of soybean oil and heat modified soybean oils with different Gardner scale viscosities as additives in hexadecane have been examined in a boundary lubrication test regime (steel contacts) using Langmuir adsorption model. The free energy of adsorption (delta-Gads) of various...

  6. Improving Adsorption Dryer Energy Efficiency by Simultaneous Optimization and Heat Integration

    NARCIS (Netherlands)

    Atuonwu, J.C.; Straten, van G.; Deventer, van H.; Boxtel, van A.J.B.

    2011-01-01

    Conventionally, energy-saving techniques in drying technology are sequential in nature. First, the dryer is optimized without heat recovery and then, based on the obtained process conditions, heat recovery possibilities are explored. This work presents a methodology for energy-efficient adsorption d

  7. Flow adsorption calorimetry of coals before and after heat and oxidation treatment

    Energy Technology Data Exchange (ETDEWEB)

    Groszek, A.J.; Templer, C.E.

    1988-12-01

    Flow microcalorimetry has been used to determine the heats of preferential adsorption of n-butanol and ammonium hydroxide on a number of coals immersed in n-heptane and water respectively. The determinations have also been carried out on the coals subjected to heating in air to temperatures ranging from 100 degrees C to 200 degrees C, to illustrate how the calorimetric technique can detect changes in the surface properties of the coals subjected to various treatments. The heats of adsorption have provided information on the relative surface acidities and hydrophobicities of the coals. 6 refs., 5 figs., 4 tabs.

  8. Conceptual adsorption system of cooling and heating supplied by solar energy

    Directory of Open Access Journals (Sweden)

    Turski Michał

    2016-06-01

    Full Text Available This paper presents the possibility of reducing the demand for nonrenewable primary energy for buildings using a new conceptual adsorption system of cooling and heating supplied by solar energy. Moreover, the aim of this study is to shorten the payback time of investment in the standard adsorption cooling system through its integration with the heating system. Research has been carried out for an energy-efficient medium-sized single-family building with a floor area of 140 m2 and a heat load of 4.2 kW and cold load of 4.41 kW. It has been shown that the use of an adsorption system of cooling and heating supplied by solar energy decreased the demand for nonrenewable primary energy by about 66% compared to the standard building that meets the current requirements.

  9. Dynamics of CO 2 Adsorption on Amine Adsorbents. 1. Impact of Heat Effects

    KAUST Repository

    Bollini, Praveen

    2012-11-21

    The packed bed heat and mass transfer dynamics of CO2 adsorption onto a 3-aminopropylsilyl-functionalized SBA-15 silica material are reported. Concentration measurements at the outlet of the packed bed and temperature profiles inside the bed are measured simultaneously. Heat and mass transfer models in conjunction with the linear driving force rate model are used to simulate the concentration and temperature profiles in the bed. The heat and mass transfer processes in the amine adsorbent packed bed are successfully captured by the model, and comparison of isothermal and nonisothermal models reveals that isothermal models provide an accurate description of the dynamic mass transport behavior in the adsorption column under the experimental conditions used in this study. The results help establish that under certain experimental conditions, heat effects in amine adsorbent packed beds have a negligible effect on CO2 breakthrough, and simple isothermal models can be used to accurately assess adsorption kinetics. © 2012 American Chemical Society.

  10. Experimental Investigations of Adsorption Chiller Cycle Using Stratified Thermal Storage for Heat Recovery

    OpenAIRE

    Joshi, Chirag

    2016-01-01

    The thesis is aimed at the experimental investigations of a silica gel-water adsorption module used for a commercial adsorption chiller based on a novel heat recovery system (stratisorp) by the use of a stratified thermal storage tank. A stratification system is constructed which is aimed at introducing the water in the tank with minimal mixing in a rotationally symmetric fashion. The qualitative assessment of the stratification system is carried out using Background Oriented Schlieren method.

  11. Simulation of a vertical ground heat exchanger as low temperature heat source for a closed adsorption seasonal storage of solar heat

    OpenAIRE

    Hennaut, Samuel; Thomas, Sébastien; Davin, Elisabeth; Skrylnyk, Alexandre; Frère, Marc

    2014-01-01

    Get It @ ULg(opens in a new window)|View at Publisher| Export | Download | More... Energy Procedia Volume 48, 2014, Pages 370-379 2nd International Conference on Solar Heating and Cooling for Buildings and Industry, SHC 2013; Freiburg; Germany; 23 September 2013 through 25 September 2013; Code 104547 Simulation of a vertical ground heat exchanger as low temperature heat source for a closed adsorption seasonal storage of solar heat (Conference Paper) Hennaut, S....

  12. Optimization of steam methane reforming coupled with pressure swing adsorption hydrogen production process by heat integration

    International Nuclear Information System (INIS)

    Highlights: • A novel energy-saving H2 production process is exploited. • Heat integration technology is used to recover the wasted heat. • Heat coupling of heat exchangers is optimized in SMR and PSA sections. • Energy consumption is reduced to 39.5% that of the conventional process. - Abstract: Hydrogen has been widely researched as a promising alternative fuel. Steam methane reforming (SMR) coupled with pressure swing adsorption (PSA) is one of the most dominant processes for hydrogen production. In order to reduce the energy consumption, a novel energy saving SMR–PSA H2 production process by combining heat integration technology has been put forward. In SMR section, the waste heat of reformer and water–gas-shift (WGS) reactors is recovered to pre-heat feed gas and H2O. In the view of exergy, a compressor is used to achieve a well heat pairing of sensible and latent heat between hot and cold streams. In PSA section, the generated adsorption heat is recovered by heat pump and reused for regeneration of sorbent. In the total process, optimal heat coupling between hot and cold streams is realized. The simulation results indicated that the SMR and PSA sections in the optimized hydrogen production process can save 55.77 kJ/mol H2 and 6.01 kJ/mol H2, respectively. The total energy consumption of the novel SMR–PSA process can be reduced to 39.5% that of the conventional process

  13. Adsorption kinetics and isotherms of zeolite coatings directly crystallized on fibrous plates for heat pump applications

    International Nuclear Information System (INIS)

    Zeolite A coatings were grown on porous fibrous metal plates by using the substrate heating synthesis method. The coatings prepared were characterized by X-ray diffraction (XRD) and laser microscopy. Kinetic measurements were performed to determine the rates of adsorption of these materials while their adsorption isotherms were obtained by thermogravimetry (TG). The overall adsorption kinetics varied with the different samples investigated. The zeolite A coating grown on a copper fibrous support generally exhibited superior overall adsorption kinetics compared to a zeolite X coating with close mass, prepared previously on a stainless steel flat plate. The coating thickness as well as the support properties affected the performances of the samples. The inclusion of an additional polymer layer exhibited adverse impact on the kinetics especially after relatively high normalized loadings. The adsorption isotherms obtained for the zeolite coatings on fibrous supports were quite typical for zeolite A while the addition of polymer changed the isotherm type. -- Highlights: • Thick zeolite A coatings were grown on fibrous metal plates. • Use of fibrous supports improved heat transfer quality. • Coating thickness influenced adsorption kinetics notably. • Inclusion of an additional polymer layer changed kinetics and isotherm type

  14. Adsorption of SO2 onto oxidized and heat-treated activated carbon fibers (ACFS)

    Science.gov (United States)

    Daley, M.A.; Mangun, C.L.; DeBarr, J.A.; Riha, S.; Lizzio, A.A.; Donnals, G.L.; Economy, J.

    1997-01-01

    A series of activated carbon fibers (ACFs) and heat-treated oxidized ACFs prepared from phenolic fiber precursors have been studied to elucidate the role of pore size, pore surface chemistry and pore volume for the adsorption of SO2 and its catalytic conversion to H2SO4. For untreated ACFs, the initial rate of SO2 adsorption from flue gas was shown to be inversely related to pore size. At longer times, the amount of SO2 adsorbed from flue gas was dependent on both the pore size and pore volume. Oxidation of the ACFs, using an aqueous oxidant, decreased their adsorption capacity for SO2 from flue gas due to a decrease in pore volume and repulsion of the SO2 from acidic surface groups. If these samples were heat-treated to desorb the oxygen containing function groups, the amount of SO2 adsorption increased. This increase in adsorption capacity was directly correlated to the amount of CO2 evolved during heat-treatment of the oxidized ACFs. The amount of SO2 adsorbed for these samples was related to the pore size, pore surface chemistry and pore volume. This analysis is explained in more detail in this paper. ?? 1997 Elsevier Science Ltd. All rights reserved.

  15. Performance investigation of advanced adsorption desalination cycle with condenser-evaporator heat recovery scheme

    KAUST Repository

    Thu, Kyaw

    2013-01-01

    Energy or heat recovery schemes are keys for the performance improvement of any heat-activated cycles such as the absorption and adsorption cycles. We present two innovative heat recovery schemes between the condensing and evaporating units of an adsorption desalination (AD) cycle. By recovering the latent heat of condenser and dumping it into the evaporative process of the evaporator, it elevates the evaporating temperature and hence the adsorption pressure seen by the adsorbent. From isotherms, this has an effect of increasing the vapour uptake. In the proposed configurations, one approach is simply to have a run-about water circuit between the condenser and the evaporator and a pump is used to achieve the water circulation. This run-around circuit is a practical method for retrofitting purposes. The second method is targeted towards a new AD cycle where an encapsulated condenser-evaporator unit is employed. The heat transfer between the condensing and evaporative vapour is almost immediate and the processes occur in a fully integrated vessel, thereby minimizing the heat transfer resistances of heat exchangers. © 2013 Desalination Publications.

  16. Thermodynamic formalism of minimum heat source temperature for driving advanced adsorption cooling device

    Science.gov (United States)

    Saha, Bidyut Baran; Chakraborty, Anutosh; Koyama, Shigeru; Srinivasan, Kandadai; Ng, Kim Choon; Kashiwagi, Takao; Dutta, Pradip

    2007-09-01

    This letter presents a thermodynamic formulation to calculate the minimum driving heat source temperature of an advanced solid sorption cooling device, and it is validated with experimental data. This formalism has been developed from the rigor of the Boltzmann distribution function and the condensation approximation of adsorptive molecules. An interesting and useful finding has been established from this formalism that it is possible to construct a solid sorption refrigeration device that operates in a cycle transferring heat from a low temperature source to a heat sink with a driving heat source at a temperature close to but above ambient.

  17. Correlation of the isosteric heat of adsorption of organic molecules over zeolites with equalized electronegativity and chemical hardness

    Indian Academy of Sciences (India)

    N V K Dutt; S J Kulkarni; Y V L Ravikumar; B S N Murthy

    2006-07-01

    Considering the direct correlation between charge transfer and heat of adsorption, we have equated the isosteric heat of adsorption () with Nalewajski's charge transfer equation involving equalized electronegativities and chemical hardness given in the literature. The equation is then tested and compared with the experimental heat of adsorption values of organic molecules over zeolites given in the literature with the average percentage deviation of 15.9. Other similar types of equations of charge transfer affinity are also tested. Various semi-empirical equations based on Barrer's approach of the determination of and neural network method have been proposed, tested and compared for the first time.

  18. Preparation of modified semi-coke by microwave heating and adsorption kinetics of methylene blue.

    Science.gov (United States)

    Wang, Xin; Peng, Jin-Hui; Duan, Xin-Hui; Srinivasakannan, Chandrasekar

    2013-01-01

    Preparation of modified semi-coke has been achieved, using phosphoric acid as the modifying agent, by microwave heating from virgin semi-coke. Process optimization using a Central Composite Design (CCD) design of Response Surface Methodology (RSM) technique for the preparation of modifies semi-coke is presented in this paper. The optimum conditions for producing modified semi-coke were: concentration of phosphoric acid 2.04, heating time 20 minutes and temperature 587 degrees C, with the optimum iodine of 862 mg/g and yield of 47.48%. The textural characteristics of modified semi-coke were analyzed using scanning electron microscopy (SEM) and nitrogen adsorption isotherm. The BET surface area of modified semi-coke was estimated to be 989.60 m2/g, with the pore volume of 0.74 cm3/g and a pore diameter of 3.009 nm, with micro-pore volume contributing to 62.44%. The Methylene Blue monolayer adsorption capacity was found to be mg/g at K. The adsorption capacity of the modified semi-coke highlights its suitability for liquid phase adsorption application with a potential usage in waste water treatment. PMID:24779145

  19. High Performance Cascading Adsorption Refrigeration Cycle with Internal Heat Recovery Driven by a Low Grade Heat Source Temperature

    Directory of Open Access Journals (Sweden)

    Yuki Ueda

    2009-11-01

    Full Text Available This paper presents the performance of an advanced cascading adsorption cycle that utilizes a driven heat source temperature between 90–130 ºC. The cycle consists of four beds that contain silica gel as an adsorber fill. Two of the beds work in a single stage cycle that is driven by an external heat source, while the other two beds work in a mass recovery cycle that is driven by waste heat of sensible and adsorption heat of the high temperature cycle. The performances, in terms of the coefficient of performance (COP and the specific cooling power (SCP, are compared with conventional cascading-without-mass-recovery and single-stage cycles. The paper also presents the effect of the adsorbent mass on performance. The results show that the proposed cycle with mass recovery produces as high of a COP as the COP that is produced by the conventional cascading cycle. However, it produces a lower SCP than that of the single-stage cycle.

  20. Effect of drying method on the adsorption isotherms and isosteric heat of passion fruit pulp powder

    Directory of Open Access Journals (Sweden)

    Maria Angélica Marques Pedro

    2010-12-01

    Full Text Available The sorption behavior of dry products is generally affected by the drying method. The sorption isotherms are useful to determine and compare thermodynamic properties of passion fruit pulp powder processed by different drying methods. The objective of this study is to analyze the effects of different drying methods on the sorption properties of passion fruit pulp powder. Passion fruit pulp powder was dehydrated using different dryers: vacuum, spray dryer, vibro-fluidized, and freeze dryer. The moisture equilibrium data of Passion Fruit Pulp (PFP powders with 55% of maltodextrin (MD were determined at 20, 30, 40 and 50 ºC. The behavior of the curves was type III, according to Brunauer's classification, and the GAB model was fitted to the experimental equilibrium data. The equilibrium moisture contents of the samples were little affected by temperature variation. The spray dryer provides a dry product with higher adsorption capacity than that of the other methods. The vibro-fluidized bed drying showed higher adsorption capacity than that of vacuum and freeze drying. The vacuum and freeze drying presented the same adsorption capacity. The isosteric heats of sorption were found to decrease with increasing moisture content. Considering the effect of drying methods, the highest isosteric heat of sorption was observed for powders produced by spray drying, whereas powders obtained by vacuum and freeze drying showed the lowest isosteric heats of sorption.

  1. Simulation of a high efficiency multi-bed adsorption heat pump

    International Nuclear Information System (INIS)

    Attaining high energy efficiency with adsorption heat pumps is challenging due to thermodynamic losses that occur when the sorbent beds are thermally cycled without effective heat recuperation. The multi-bed concept described here enables high efficiency by effectively transferring heat from beds being cooled to beds being heated. A simplified lumped-parameter model and detailed finite element analysis are used to simulate a sorption compressor, which is used to project the overall heat pump coefficient of performance. Results are presented for ammonia refrigerant and a nano-structured monolithic carbon sorbent specifically modified for the application. The effects of bed geometry and number of beds on system performance are explored, and the majority of the performance benefit is obtained with four beds. Results indicate that a COP of 1.24 based on heat input is feasible at AHRI standard test conditions for residential HVAC equipment. When compared on a basis of primary energy input, performance equivalent to SEER 13 or 14 are theoretically attainable with this system. - Highlights: ► A multi-bed concept for adsorption heat pumps is capable of high efficiency. ► Modeling is used to simulate sorption compressor and overall heat pump performance. ► Results are presented for ammonia refrigerant and a nano-structured monolithic carbon sorbent. ► The majority of the efficiency benefit is obtained with four beds. ► Predicted COP as high as 1.24 for cooling is comparable to SEER 13 or 14 for electric heat pumps.

  2. Effects of heat treatment on the dye adsorption of ZnO nanorods for dye-sensitized solar cells

    Science.gov (United States)

    Yun, Won Suk; Choi, Seok Cheol; Sohn, Sang Ho; Oh, Sang Jin

    2012-11-01

    Well-aligned ZnO nanorods for the photoelectrode of dye-sensitized solar cells (DSSCs) were grown via a sonochemical method, and the heat-treatment effects on the dye adsorption in the DSSCs were studied. The heat treatment of well-aligned ZnO nanorods was performed at 200 ˜ 500 °C for 1 h, which was immediately followed by the dye adsorption. The dye amounts adsorbed in the ZnO nanorods were estimated from the UV-Vis absorbance by using Beer-Lambert's law. The efficiency of the DSSCs with ZnO nanorods was measured to investigate the heat-treatment effects of ZnO nanorods on the dye adsorption properties. The heat-treatment of ZnO nanorods was found to yield a change in their dye adsorption ability, resulting in a change in the efficiency of the DSSCs.

  3. Effects of heat treatment on the dye adsorption of ZnO nanorods for dye-sensitized solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Yun, Won Suk; Choi, Seok Cheol; Sohn, Sang Ho [Kyungpook National University, Daegu (Korea, Republic of); Oh, Sang Jin [Phoenix Materials, Gumi (Korea, Republic of)

    2012-11-15

    Well-aligned ZnO nanorods for the photoelectrode of dye-sensitized solar cells (DSSCs) were grown via a sonochemical method, and the heat-treatment effects on the dye adsorption in the DSSCs were studied. The heat treatment of well-aligned ZnO nanorods was performed at 200 ∼ 500 .deg. C for 1 h, which was immediately followed by the dye adsorption. The dye amounts adsorbed in the ZnO nanorods were estimated from the UV-Vis absorbance by using Beer-Lambert's law. The efficiency of the DSSCs with ZnO nanorods was measured to investigate the heat-treatment effects of ZnO nanorods on the dye adsorption properties. The heat-treatment of ZnO nanorods was found to yield a change in their dye adsorption ability, resulting in a change in the efficiency of the DSSCs.

  4. Augmentation of Cooling Output by Silica Gel-Water Adsorption Cycle Utilizing the Waste Heat of GHP

    Science.gov (United States)

    Homma, Hiroki; Araki, Nobuyuki

    The GHP (Gas engine Heat Pump) system is expected to have high energy-efficiency in utilizing the waste heat exhausted from a gas engine. In summer season, a silica gel-water adsorption cooling unit driven by the exhaust heat is considered as a cooling system for saving energy. In this work, an attempt was made to improve the COP of a silica gel-water adsorption cooling system by enhancing heat and mass transfer in the silica gel adsorption layer. A unit cell was introduced as a simplified model of adsorber for analyzing the phenomena of heat and mass transfer in the adsorbent. This cell was composed of a single tube with a silica gel layer bonded on its external surface. Optimization of heat and mass transfer characteristics for the unit cell was carried out by experimental and analytical approach.

  5. Performance analysis of a low-temperature waste heat-driven adsorption desalination prototype

    KAUST Repository

    Thu, Kyaw

    2013-10-01

    This paper discusses the performance analysis of an advanced adsorption desalination (AD) cycle with an internal heat recovery between the condenser and the evaporator. The AD cycle employs the adsorption-desorption principles to convert sea or brackish water into high-grade potable water with total dissolved solids (TDS) less than 10 ppm (mg/L) utilizing low-temperature heat source. The salient features of the AD cycle are the utilization of low temperature waste heat (typically 55 C to 85 C) with the employment of an environment-friendly silica gel/water pair and the low maintenance as it has no major moving parts other than the pumps and valves. For improved performance of the AD pilot plant, the internal heat recovery scheme between the condenser and evaporator has been implemented with a run-about water circuit between them. The efficacy of the scheme is analyzed in terms of key performance indicators such as the specific daily water production (SDWP) and the performance ratio (PR). Extensive experiments were performed for assorted heat source temperatures ranging from 70 C to 50 C. From the experiments, the SDWP of the AD cycle with the proposed heat recovery scheme is found to be 15 m3 of water per ton of silica gel that is almost twice that of the yield obtained by a conventional AD cycle for the same operation conditions. Another important finding of AD desalination plant is that the advanced AD cycle could still be operational with an inlet heat source temperature of 50 C and yet achieving a SDWP of 4.3 m3 - a feat that never seen by any heat-driven cycles. © 2013 Elsevier Ltd. All rights reserved.

  6. Conventional and Advanced Silicagel-water Adsorption Cycles Driven by Near - environmental Temperature Heat

    Science.gov (United States)

    Boelman, Elisa; B. Saha, Bidyut; Tanaka, Aiharu; Kashiwagi, Takao

    This work aims at clarifying the possible operating temperature ranges for silica gel-water adsorption refrigeration cycles driven by near-environmental temperature heat sources (between 50°C and 85°C), with relatively small regenerating temperature lifts (10 K to 65 K). A newly developed three stage advanced silica gel-water cycle, which is operational with 50°C driving heat source and 30°C cooling source is introduced and compared with a conventional single stage cycle. The cycles are evaluated in terms of cooling capacity, COP and the viability of operation with near-environmental temperature driving heat sources. The analysis is based on experimental and cycle simulation work. The results showed the advanced three stage cycle to be particularly suited for operation with low grade waste heat driving sources, since it worked with small regenerating temperature lifts (ΔTregen)of 10K to 30K. Another significant advantage of operation with small ΔTregen is the possibility to reduce irreversible heat losses from batched cycle operation. Experiments carried out on full-size machine suggested that, even with smallΔTregen, adsorber /desorber heat exchanger improvements such as higher thermal conductance and smaller heat capacitance can contribute to reduce heat losses while improving cycle performance in terms of cooling capacity and COP.

  7. CFD Simulation and Experimental Analyses of a Copper Wire Woven Heat Exchanger Design to Improve Heat Transfer and Reduce the Size of Adsorption Beds

    Directory of Open Access Journals (Sweden)

    John White

    2016-02-01

    Full Text Available The chief objective of this study is the proposal design and CFD simulation of a new compacted copper wire woven fin heat exchanger and silica gel adsorbent bed used as part of an adsorption refrigeration system. This type of heat exchanger design has a large surface area because of the wire woven fin design. It is estimated that this will help improve the coefficient of performance (COP of the adsorption phase and increase the heat transfer in this system arrangement. To study the heat transfer between the fins and porous adsorbent reactor bed, two experiments were carried out and matched to computational fluid dynamics (CFD results.

  8. Performance investigation of a waste heat driven pressurized adsorption refrigeration cycle

    Science.gov (United States)

    Habib, K.

    2015-12-01

    This article presents performance investigation of a waste heat driven two bed pressurised adsorption refrigeration system. In this study, highly porous activated carbon (AC) of type Maxsorb III has been selected as adsorbent while n-butane, R-134a, R410a, R507a and carbon dioxide (CO2) are chosen as refrigerants. All the five refrigerants work at above atmospheric pressure. Among the five pairs studied, the best pairs will be identified which will be used to provide sufficient cooling capacity for a driving heat source temperature above 60°C. Results indicate that for a driving source temperature above 60°C, AC-R410a pair provides highest cooling capacity while AC-CO2 pairs works better when the heat source temperature falls below 60°C.

  9. A study on multifunction heat pipe type high efficient adsorption refrigerator using compound adsorbent-ammonia

    Institute of Scientific and Technical Information of China (English)

    LU Zisheng; WANG Ruzhu; WANG Liwei; CHEN Chuanjuan

    2006-01-01

    A multifunction heat pipe adsorption refrigerator is designed, which uses solidified compound adsorbent of CaCl2 and activated carbon as adsorbent. Two work conditions, ice-maker driven by the exhaust heat from diesel engine and air-condi- tioning powered by solar energy, are studied. SCP (specific cooling power) and COP (coefficient of per- formance) for different conditions are analyzed. The optimum average SCP and COP for the refrigerator powered by waste heat of diesel engine are 770.4 W/kg and 0.39 at about -20℃ evaporating tem- perature. The optimum average SCP and COP for the refrigerator powered by solar energy are 524.2 W/kg and 0.27 at about 5.6℃ evaporating tempera- ture.

  10. Multi-Bed Multi-Stage Adsorption Refrigeration Cycle-Reducing Driving Heat Source Temperature

    Science.gov (United States)

    Alam, K. C. Amanul; Akahira, Akira; Hamamoto, Yoshinori; Akisawa, Atsushi; Kashiwagi, Takao; Saha, Bidyut Baran; Koyama, Shigeru; Ng, Kim Choon; Chua, Hui Tong

    The study aims at designing a multi-bed multi-stage adsorption chiller that can be driven by waste heat at near ambient temperature. The chiller is designed such a way that it can be switched into different modes depending on the driving heat source temperature. Stage regeneration techniques have been applied to operate the chiller by relatively low temperature heat source. Driving heat source temperature is validated by simulated data and the performances obtained from different modes are compared. In terms of COP (Coefficient of performance),the chiller shows best performance in conventional single-stage mode for driving heat source temperature greater than 60°C, two stage mode for driving source temperature between 42 and 60°C,in three-stage mode for driving source temperature less than 42°C. In terms of cooling capacity, it shows the best performance in single-stage mode for heat source temperature greater than 70°C. The mass recovery process in single-stage mode is also examined. It is seen that the mass recovery process improve cooling capacity significantly, specially for the low regenerating temperature region.

  11. Development of a thermal storage system based on the heat of adsorption of water in hygroscopic materials

    NARCIS (Netherlands)

    Wijsman, A.J.T.M.; Oosterhaven, R.; Ouden, C. den

    1979-01-01

    A thermal storage system based on the heat of adsorption of water in hygroscopic materials has been studied as a component of a solar space heating system. The aim of this project is to decrease the storage volume in comparison with a rock-bed storage system by increasing the stored energy density.

  12. Study on a waste heat-driven adsorption cooling cum desalination cycle

    KAUST Repository

    Ng, Kim Choon

    2012-05-01

    This article presents the performance analysis of a waste heat-driven adsorption cycle. With the implementation of adsorption-desorption phenomena, the cycle simultaneously produces cooling energy and high-grade potable water. A mathematical model is developed using isotherm characteristics of the adsorbent/adsorbate pair (silica gel and water), energy and mass balances for the each component of the cycle. The cycle is analyzed using key performance parameters namely (i) specific cooling power (SCP), (ii) specific daily water production (SDWP), (iii) the coefficient of performance (COP) and (iv) the overall conversion ratio (OCR). The numerical results of the adsorption cycle are validated using experimental data. The parametric analysis using different hot and chilled water temperatures are reported. At 85°C hot water inlet temperature, the cycle generates 3.6 m 3 of potable water and 23 Rton of cooling at the produced chilled water temperature of 10°C. © 2012 Elsevier Ltd and IIR. All rights reserved.

  13. Adsorption refrigeration-An efficient way to make good use of waste heat and solar energy

    Energy Technology Data Exchange (ETDEWEB)

    Wang, R.Z.; Oliveira, R.G. [Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, Huashan Rd., Shanghai 200030 (China)

    2006-07-01

    This paper presents the achievements gained in solid sorption refrigeration prototypes since the end of the l970s, when interest in sorption systems was renewed. The applications included are ice making and air conditioning. The latter includes not only cooling and heating, but also dehumidification by desiccant systems. The prototypes presented were designed to use waste heat or solar energy as the main heat source. The waste heat could be from diesel engines or from power plants, in combined cooling, heating and power systems (CCHP). The current technology of adsorption solar-powered icemakers allows a daily ice production of between 4 and 7kgm{sup -2} of solar collector, with a solar coefficient of performance (COP) between 0.10 and 0.16. The silica gel-water chillers studied can be powered by hot water warmer than 55{sup o}C. The COP is usually around 0.2-0.6, and in some commercially produced machines, it can be up to 0.7. The utilization of such chillers in CCHP systems, hospitals, buildings and grain depots are discussed. Despite their advantages, solid sorption systems still present some drawbacks such as low specific cooling power (SCP) and COP. Thus, some techniques to overcome these problems are also contemplated, together with the perspectives for their broad commercialisation. Among these techniques, a special attention was devoted to innovative adsorbent materials, to advanced cycles and to heat pipes, which are suitable devices not only to improve the heat transfer but also can help to avoid corrosion in the adsorbers. Recent experiments performed by the research group of the authors with machines that employ composite adsorbent material and heat pipes showed that it is possible to achieve a SCP of 770Wkg{sup -1} of salt and COP of 0.39 at evaporation temperatures of -20{sup o}C and generation temperature of 115{sup o}C. (author)

  14. Design of Heat Pipe Type Adsorption Ice Maker for Fishing Boats

    Institute of Scientific and Technical Information of China (English)

    王丽伟; 王如竹; 夏再忠; 吴静怡

    2005-01-01

    A heat pipe type adsorption ice maker with two adsorbers for fishing boats is designed by using ammonia as refrigerant and compound of activated carbon-GaG12 as adsorbent. This type of heat pipe adsorber can solve the problem of incompatibility between ammonia, copper, seawater and steel. The working process of the ice maker with 8.7kg adsorbent per bed is simulated. The results show that the optimal semi-cycle time is about 9min at the evaporating temperature of -15℃, where the corresponding cooling power, specific cooling power per kilogram adsorbent SCP and coefficient of refrigerant performance COP are respectively 3.6 kW, 217 W·kg-1 and 0.404.

  15. Performance Study of a Four-Bed Silica Gel-Water Adsorption Chiller with the Passive Heat Recovery Scheme

    OpenAIRE

    Zhilong He; Xiaolin Wang; Hui Tong Chua

    2015-01-01

    Adsorption chiller technology is one of the effective means to convert waste thermal energy into effective cooling, which substantially improves energy efficiency and lowers environmental pollution. This paper uses an improved lump-parameter design model to theoretically and experimentally evaluate the efficacy of the passive heat recovery scheme as applied to a four-bed adsorption chiller. Results show that the model can accurately track the experimental temporal system outlet temperatures. ...

  16. Modeling Of Metabolic Heat Regenerated Temperature Swing Adsorption (MTSA) Subassembly For Prototype Design

    Science.gov (United States)

    Bower, Chad E.; Padilla, Sebastian A.; Iacomini, Christie S.; Paul, Heather L.

    2010-01-01

    This paper describes modeling methods for the three core components of a Metabolic heat regenerated Temperature Swing Adsorption (MTSA) subassembly: a sorbent bed, a sublimation (cooling) heat exchanger (SHX), and a condensing icing (warming) heat exchanger (CIHX). The primary function of the MTSA, removing carbon dioxide from a space suit Portable Life Support System (PLSS) ventilation loop, is performed via the sorbent bed. The CIHX is used to heat the sorbent bed for desorption and to remove moisture from the ventilation loop while the SHX is alternately employed to cool the sorbent bed via sublimation of a spray of water at low pressure to prepare the reconditioned bed for the next cycle. This paper describes subsystem heat a mass transfer modeling methodologies relevant to the description of the MTSA subassembly in Thermal Desktop and SINDA/FLUINT. Several areas of particular modeling interest are discussed. In the sorbent bed, capture of the translating carbon dioxide (CO2) front and associated local energy and mass balance in both adsorbing and desorbing modes is covered. The CIHX poses particular challenges for modeling in SINDA/FLUINT as accounting for solids states in fluid submodels are not a native capability. Methods for capturing phase change and latent heat of ice as well as the transport properties across a layer of low density accreted frost are developed. This extended modeling capacity is applicable to temperatures greater than 258 K. To extend applicability to the minimum device temperature of 235 K, a method for a mapped transformation of temperatures from below the limit temperatures to some value above is given along with descriptions for associated material property transformations and the resulting impacts to total heat and mass transfer. Similar considerations are given for the SHX along with functional relationships for areal sublimation rates as limited by flow mechanics in t1he outlet duct.

  17. Metal-Organic Frameworks in Adsorption-Driven Heat Pumps: The Potential of Alcohols as Working Fluids.

    Science.gov (United States)

    de Lange, Martijn F; van Velzen, Benjamin L; Ottevanger, Coen P; Verouden, Karlijn J F M; Lin, Li-Chiang; Vlugt, Thijs J H; Gascon, Jorge; Kapteijn, Freek

    2015-11-24

    A large fraction of global energy is consumed for heating and cooling. Adsorption-driven heat pumps and chillers could be employed to reduce this consumption. MOFs are often considered to be ideal adsorbents for heat pumps and chillers. While most published works to date on this topic have focused on the use of water as a working fluid, the instability of many MOFs to water and the fact that water cannot be used at subzero temperatures pose certain drawbacks. The potential of using alcohol-MOF pairs in adsorption-driven heat pumps and chillers is investigated. To this end, 18 different selected MOF structures in combination with either methanol or ethanol as a working fluid are considered, and their potential is assessed on the basis of adsorption measurements and thermodynamic efficiencies. If alcohols are used instead of water, then (1) adsorption occurs at lower relative pressures for methanol and even lower pressure for ethanol, (2) larger pores can be utilized efficiently, as hysteresis is absent for pores smaller than 3.4 nm (2 nm for water), (3) larger pore sizes need to be employed to ensure the desired stepwise adsorption, (4) the effect of (polar/apolar) functional groups in the MOF is far less pronounced, (5) the energy released or taken up per cycle is lower, but heat and mass transfer may be enhanced, (6) stability of MOFs seems to be less of an issue, and (7) cryogenic applications (e.g., ice making) become feasible. From a thermodynamic perspective, UiO-67, CAU-3, and ZIF-8 seem to be the most promising MOFs for both methanol and ethanol as working fluids. Although UiO-67 might not be completely stable, both CAU-3 and ZIF-8 have the potential to be applied, especially in subzero-temperature adsorption chillers (AC).

  18. Heat Transfer Analysis of a Flat-plate Solar Collector Running a Solid Adsorption Refrigerator

    Directory of Open Access Journals (Sweden)

    S. Thiao

    2014-05-01

    Full Text Available Adsorption solar cooling appears to have prospect in the tropical countries. The present study is a theoretical investigation of the performance of a solar adsorption refrigerator using a flat-plate solar collector. The values of glass cover and absorber plate temperatures obtained from numerical solutions of heat balance equations are used to predict the solar coefficient of performance of the solar refrigerator. The simulation technique takes into account the variations of ambient temperature and solar radiation along the day. The effects of optical parameters of the glass cover such as absorption and transmission coefficients on glass cover and absorber plate temperatures and consequently on the coefficient of performance are analyzed. As a result, it is found that the absorber plate temperature is less to the absorption coefficient than the cover glass temperature. Also the thermal radiation exchange has more effect on the cover glass temperature. The higher values of COP are obtained between 11 and 13 h during the morning when the temperatures of the absorber plate and the ambient temperatures increase. Moreover the COP increases with the coefficient of transmission of the glass cover but the main parameter acting on the variations of the COP remains the temperature of the evaporator.

  19. The influence of adsorption coating on molecular heat transfer in the system `rarefied gas — metal'

    Science.gov (United States)

    Ukhov, A. I.; Borisov, S. F.; Porodnov, B. T.

    2010-03-01

    Based on the classical concept of atomic motion and the Goodman and Wachman lattice theory, we have developed a computer program to model the equilibrium and non-equilibrium scattering of helium atoms by 3D tungsten crystal lattice with allowance for adsorption surface coating. Within the concept of energy accommodation coefficient, we have calculated the rate of molecular heat transfer of helium to clean tungsten surface or to tungsten surface partially covered with an adsorbate. The calculations were performed for various surface temperatures. The calculated dependences were compared to test data obtained in experiments with surfaces controlled in terms of their chemical composition. Within the developed approach, the simulations proved capable of providing an adequate description to experimental data obtained for the equilibrium energy accommodation coefficient on the clean surface, and also for the non-equilibrium energy accommodation coefficient for the surface partially covered with adsorbate.

  20. Adsorption-desorption isotherms and heat of sorption of prickly pear fruit (Opuntia ficus indica)

    Energy Technology Data Exchange (ETDEWEB)

    Lahsasni, S.; Kouhila, M. E-mail: kouhila@hotmail.com; Mahrouz, M

    2004-01-01

    The equilibrium moisture contents were determined for prickly pear fruit using the gravimetric static method at t=30, 40 and 50 deg. C over a range of relative humidities from 0.05 to 0.9. The sorption curves of prickly pear fruit decreased with increase in temperature at constant relative humidity. The hysteresis effect was observed. The GAB, modified Halsey, modified Chung-Pfost, modified Oswin and modified Henderson models were tested to fit the experimental data. The GAB model was found to be the most suitable for describing the sorption curves. The monolayer moisture content values for the sorption at different temperatures are calculated using a modified BET equation. The isosteric heats of desorption and adsorption of water were determined from the equilibrium data at different temperatures.

  1. Study on an advanced adsorption desalination cycle with evaporator–condenser heat recovery circuit

    KAUST Repository

    Thu, Kyaw

    2011-01-01

    This paper presents the results of an investigation on the efficacy of a silica gel-water based advanced adsorption desalination (AD) cycle with internal heat recovery between the condenser and the evaporator. A mathematical model of the AD cycle was developed and the performance data were compared with the experimental results. The advanced AD cycle is able to produce the specific daily water production (SDWP) of 9.24 m3/tonne of silica gel per day at 70 °C hot water inlet temperature while the corresponding performance ratio (PR) is comparatively high at 0.77. It is found that the cycle can be operational at 50 °C hot water temperature with SDWP 4.3. The SDWP of the advanced cycle is almost twice that of the conventional AD cycle. © 2010 Elsevier Ltd. All rights reserved.

  2. Performance Study of a Four-Bed Silica Gel-Water Adsorption Chiller with the Passive Heat Recovery Scheme

    Directory of Open Access Journals (Sweden)

    Zhilong He

    2015-01-01

    Full Text Available Adsorption chiller technology is one of the effective means to convert waste thermal energy into effective cooling, which substantially improves energy efficiency and lowers environmental pollution. This paper uses an improved lump-parameter design model to theoretically and experimentally evaluate the efficacy of the passive heat recovery scheme as applied to a four-bed adsorption chiller. Results show that the model can accurately track the experimental temporal system outlet temperatures. The performance predictions from this model compare favourably with experimental results. At rated temperature conditions and over a wide range of cycle times, both the cooling capacity and COP can be predicted to within 12.5%. The analyses indicate that the model can be used confidently as a design tool for a four-bed adsorption chiller and the passive heat recovery scheme can effectively improve the system performance.

  3. New Carbon-Based Porous Materials with Increased Heats of Adsorption for Hydrogen Storage

    Energy Technology Data Exchange (ETDEWEB)

    Snurr, Randall Q.; Hupp, Joseph T.; Kanatzidis, Mercouri G.; Nguyen, SonBinh T.

    2014-11-03

    . Only after modeling suggested record-breaking hydrogen uptake at 77 K did we proceed to synthesize, characterize, and test the material, ultimately yielding experimental results that agreed closely with predictions that were made before the material was synthesized. We also synthesized, characterized, and computationally simulated the behavior of two new materials displaying the highest experimental Brunauer−Emmett−Teller (BET) surface areas of any porous materials reported to date (∼7000 m2/g). Key to evacuating the initially solvent-filled materials without pore collapse, and thereby accessing the ultrahigh areas, was the use of a supercritical CO2 activation technique developed by our team. In our efforts to increase the hydrogen binding energy, we developed the first examples of “zwitterionic” metal-organic frameworks (MOFs). The two structures feature zwitterionic characteristics arising from N-heterocyclic azolium groups in the linkers and negatively charged Zn2(CO2)5 nodes. These groups interact strongly with the H2 quadrupole. High initial isosteric heats of adsorption for hydrogen were measured at low H2 loading. Simulations were used to determine the H2 binding sites, and results were compared with inelastic neutron scattering. In addition to MOFs, the project produced a variety of related materials known as porous organic frameworks (POFs), including robust catechol-functionalized POFs with tunable porosities and degrees of functionalization. Post-synthesis metalation was readily carried out with a wide range of metal precursors (CuII, MgII, and MnII salts and complexes), resulting in metalated POFs with enhanced heats of hydrogen adsorption compared to the starting nonmetalated materials. Isosteric heats of adsorption as high as 9.6 kJ/mol were observed, compared to typical values around 5 kJ/mol in unfunctionalized MOFs and POFs. Modeling played an important role throughout the project. For example, we used molecular simulations to determine that

  4. Development of an adsorption reactor for domestic heating and solar cooling applications; Entwicklung und Nutzungspotential eines Sorptionsreaktors zur solaren Heizungsunterstuetzung und solaren Kuehlung

    Energy Technology Data Exchange (ETDEWEB)

    Nunez, T.; Henning, H.M. [Fraunhofer-Institut fuer Solare Energiesysteme (ISE), Freiburg im Breisgau (Germany); Mittelbach, W. [sorTech AG, Freiburg (Germany)

    2004-07-01

    With the aim to reduce the amount of primary energy used for domestic heating purposes the introduction of heat driven heat pumps can provide a significant improvement in fossil fuel utilisation. Furthermore, if the design of the heat pump allows the additional use of its cooling properties, year round operation becomes possible using waste or solar heat in summer in order to provide cooling for air conditioning applications. In this paper the development of a prototype of a small adsorption system working on the adsorption pair silica gel - water is presented. The development of this prototype has been carried out during the last year and is a result of continued joint work on adsorption heat transformation systems carried out at SorTech AG and the Fraunhofer Institute. First simulation results of the performance of an adsorption system for heating and air-conditioning applications are presented. The basis for the simulated system is a solar combi-system with a gas fired back-up furnace as it is commonly installed for solar assisted space heating purposes. This system was combined with the adsorption heat pump and a ground heat exchanger as low temperature energy source. The adsorption system is driven by the gas furnace in the heating season, in the summer season the excess energy from the solar system is used to drive the adsorption chiller. The simulations show up to which extent the year round utilisation of the solar collectors is improved due to the operation of the adsorption system as a chiller in the summer season and its contribution to cover the heating demand in the winter season reducing fossil fuel utilisation. (orig.)

  5. Adsorption Characteristics of Cooling Tube with Exhausted Heat%余热冷管吸附特性研究

    Institute of Scientific and Technical Information of China (English)

    李玲超

    2015-01-01

    The solid adsorption refrigeration principle, introduces a waste heat as a heat source to heat absorption refrigeration tube. Design and introduces a new type of heat pipe cooling test device, using the device during opera-tion of the heat pipe cold experimental study. The results show that:in the adsorption of ambient temperature 12℃, set the desorption temperature of 180℃, heat the cold pipe cooling capacity alone 31kJ, cooling pipe lowest tem-perature reached 3℃, after the heat exchanger air temperature can reach 700 degrees Celsius.%根据固体吸附式制冷原理, 介绍了一种以余热为热源的余热吸附制冷管. 设计了一种新型的余热冷管测试装置, 采用该装置对余热冷管的运行过程进行实验研究. 实验结果表明: 在吸附环境温度为12℃, 设定脱附温度为180℃时, 余热冷管单只制冷量为31kJ, 制冷管最低温度达到3℃, 换热后空气温度可达到7℃.

  6. Modeling the heat and mass transfers in temperature-swing adsorption of volatile organic compounds onto activated carbons

    Energy Technology Data Exchange (ETDEWEB)

    Sylvain Giraudet; Pascaline Pre; Pierre Le Cloirec [Ecole des Mines de Nantes, Nantes (France)

    2009-02-15

    A theoretical model was built to simulate the adsorption of volatile organic compounds (VOCs) onto activated carbons in a fixed bed. This model was validated on a set of experimental data obtained for the adsorption of acetone, ethyl formate, and dichloromethane onto five commercial activated carbons. The influence of operating conditions was modeled with various VOC contents at the inlet of the adsorber and superficial velocities of the gas-phase from 0.14 to 0.28 m.s{sup -1}. Breakthrough times and maximum temperature rises were computed with a coefficient of determination of 0.988 and 0.901, respectively. The simulation was then extended to the adsorption of mixtures of VOCs. From the comparison of simulation and experimental results, the advantage of accounting for dispersions of heat and mass is shown and the importance in taking into account the temperature effect on the equilibrium data is demonstrated. 29 refs., 6 figs., 1 tab.

  7. Carbon-ammonia pairs for adsorption refrigeration applications: ice making, air conditioning and heat pumping

    Energy Technology Data Exchange (ETDEWEB)

    Tamainot-Telto, Z.; Metcalf, S.J.; Critoph, R.E.; Zhong, Y.; Thorpe, R. [School of Engineering, University of Warwick, Gibbet Hall Road, Coventry CV4 7AL (United Kingdom)

    2009-09-15

    A thermodynamic cycle model is used to select an optimum adsorbent-refrigerant pair in respect of a chosen figure of merit that could be the cooling production (MJ m{sup -3}), the heating production (MJ m{sup -3}) or the coefficient of performance (COP). This model is based mainly on the adsorption equilibrium equations of the adsorbent-refrigerant pair and heat flows. The simulation results of 26 various activated carbon-ammonia pairs for three cycles (single bed, two-bed and infinite number of beds) are presented at typical conditions for ice making, air conditioning and heat pumping applications. The driving temperature varies from 80 C to 200 C. The carbon absorbents investigated are mainly coconut shell and coal based types in multiple forms: monolithic, granular, compacted granular, fibre, compacted fibre, cloth, compacted cloth and powder. Considering a two-bed cycle, the best thermal performances based on power density are obtained with the monolithic carbon KOH-AC, with a driving temperature of 100 C; the cooling production is about 66 MJ m{sup -3} (COP = 0.45) and 151 MJ m{sup -3} (COP = 0.61) for ice making and air conditioning respectively; the heating production is about 236 MJ m{sup -3} (COP = 1.50). (author) [French] Un modele du cycle thermodynamique est utilise pour selectionner le meilleur couple adsorbant-ammoniac sur la base de la production frigorifique (MJ m{sup -3}), la production de chaleur (MJ m{sup -3}) ou bien le coefficient de performance (COP). Ce modele est essentiellement base sur les equations d'etat de l'adsorption (adsorbant-ammoniac). Les resultats de simulation de 26 differents couples charbon actif-ammoniac sont presentes pour des conditions typiques de fabrication de la glace, de climatisation et de pompe a chaleur. La temperature de generation varie de 80 C a 200 C. Les simulations sont effectuees pour trois types de cycle: lit unique, deux-lits et un nombre infini de lits. Les charbons actifs etudies sont

  8. Simulated Lunar Testing of Metabolic Heat Regenerated Temperature Swing Adsorption Technology

    Science.gov (United States)

    Padilla, Sebastian A.; Bower, Chad; Iacomini, Christie S.; Paul, H.

    2011-01-01

    Metabolic heat regenerated Temperature Swing Adsorption (MTSA) technology is being developed for thermal and carbon dioxide (CO2) control for a Portable Life Support System (PLSS), as well as water recycling. An Engineering Development Unit (EDU) of the MTSA subassembly was designed and assembled for optimized Martian operations, but also meets system requirements for lunar operations. For lunar operations the MTSA sorption cycle is driven via a vacuum swing between suit ventilation loop pressure and lunar vacuum. The focus of this effort is operations and testing in a simulated lunar environment. This environment was simulated in Paragon s EHF vacuum chamber. The objective of this testing was to evaluate the full cycle performance of the MTSA Subassembly EDU, and to assess CO2 loading and pressure drop of the wash coated aluminum reticulated foam sorbent bed. The lunar testing proved out the feasibility of pure vacuum swing operation, making MTSA a technology that can be tested and used on the Moon prior to going to Mars. Testing demonstrated better than expected CO2 loading on the sorbent and nearly replicates the equilibrium data from the sorbent manufacturer. This had not been achieved in any of the previous sorbent loading tests performed by Paragon. Subsequently, the increased performance of the sorbent bed design indicates future designs will require less mass and volume than the current EDU rendering MTSA as very competitive for Martian PLSS applications.

  9. Correlations and adsorption mechanisms of aromatic compounds on a high heat temperature treated bamboo biochar.

    Science.gov (United States)

    Yang, Kun; Yang, Jingjing; Jiang, Yuan; Wu, Wenhao; Lin, Daohui

    2016-03-01

    Adsorption of aromatic compounds, including polycyclic aromatic hydrocarbons, nitrobenzenes, phenols, and anilines, on a bamboo biochar produced at 700 °C (Ba700) was investigated with the mechanism discussion by isotherm fitting using the Polanyi-theory based Dubinin-Ashtakhov (DA) model. Correlations of adsorption capacity (Q(0)) of organic compounds with their molecular sizes and melting points, as well as correlations of adsorption affinity (E) with their solvatochromic parameters (i.e., π* and αm), on the biochar, were developed and indicating that adsorption is captured by the pore filling mechanism and derived from the hydrophobic effects of organic compounds and the forming of π-π electron donor-acceptor (EDA) interactions and hydrogen bonding interactions of organic molecules with surface sites of the biochar. The effects of organic molecular sizes and melting points on adsorption capacity are ascribed to the molecular sieving effect and the packing efficiency of the organic molecules in the biochar pores, respectively. These correlations can be used to quantitatively estimate the adsorption of organic compounds on biochars from their commonly physicochemical properties including solvatochromic parameters, melting points and molecular cross-sectional area. The prediction using these correlations is important for assessing the unknown adsorption behaviors of new organic compounds and also helpful to guide the surface modification of biochars and make targeted selection in the environmental applications of biochars as adsorbents.

  10. Nanomolar detection of rutin based on adsorptive stripping analysis at single-sided heated graphite cylindrical electrodes with direct current heating

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Shao-Hua; Sun, Jian-Jun; Zhang, De-Feng; Lin, Zhi-Bin; Nie, Fa-Hui; Qiu, He-Yuan; Chen, Guo-Nan [Key Laboratory of Analysis and Detection Technology for Food Safety, Ministry of Education, College of Chemistry and Chemical Engineering, Fuzhou University, 523 Gong Ye Road, Fuzhou 350002 (China)

    2008-09-20

    A single-sided heated graphite cylindrical electrode (ss-HGCE) was designed. Compared to previous alternative current (AC) heating, much simpler and cheaper direct current (DC) heating supplier was adopted for the first time to perform adsorptive accumulation of rutin at ss-HGCE at elevated electrode temperature. This offers great promise for low cost, miniaturization and high compatibility with portability. The square wave voltammetry (SWV) stripping peak current was enhanced with increasing the electrode temperature only during preconcentration step. This enhancement was contributed to the forced thermal convection induced by heating the electrode rather than the bulk solution, which is able to improve mass transfer and facilitate adsorption hence enhance stripping response. A detection limit of 1.0 x 10{sup -9} M (S/N = 3) could be obtained at an electrode temperature of 48 C during 5 min accumulation, one magnitude lower than that at 28 C (room temperature). This is the lowest value at carbon-based electrodes for rutin determination as we know. Such novel method was also successfully used to determine rutin in pharmaceutical tablets. (author)

  11. Thermal coated heat exchangers as a fundament for compact and dynamic evaporator in adsorption chillers and adsorption storages; Thermisch-beschichtete Waermeuebertrager als Basis fuer kompakte und dynamische Verdampfer in Adsorptionskaelteanlagen und -speichern

    Energy Technology Data Exchange (ETDEWEB)

    Lanzerath, Franz; Steinhilber, Matthias; Bardow, Andre [RWTH Aachen Univ. (Germany). Lehrstuhl fuer Technische Thermodynamik

    2012-07-01

    The advantage of adsorption chillers in the utilization of waste heat or solar heat often is underestimated by the low power density of the plants. This especially is true for mobile applications where size and weight of a component are crucial criteria, or for storage applications that require high dynamics and thus low thermal mass. In this connection, in many cases, the evaporator is the limiting component, since adsorption place special demands on the heat exchanger: The heat coupling must occur in order to maximize the vapor pressure at low temperature differences, so that the adsorption does not shift adversely. In addition, the physical properties of the widely used natural water as a refrigerant are unfavorable at low temperatures and complicate the process of evaporation. Nevertheless, in order to achieve sufficient heat transfer, large areas and correspondingly heavy evaporators are required. Thus, optimized heat exchangers are used in modern evaporators. In addition to the known positive properties of structured surfaces (for example rib structure), the authors were able to demonstrate the potential of thermal coatings, recently. The thermal coating of simple straight tubes resulted in an improvement of heat transfer by a factor of eight. The combination of macroscopic rib structure and thermal coating facilitates further improvements. The authors of the contribution under consideration report on the advantages of the new heat exchangers when operating an adsorption chiller. Thus, the impact of water level and cycle time on the evaporator capacity and adsorption per amount of cold produced is analyzed quantitatively. The impact of the k-value on the evaporation temperature is shown. The results show that the water level in the evaporator has a large impact on the cooling capacity of the adsorption system. Therefore, the optimal operating point must be determined in order to fully exploit the potential of the heat exchanger. The strong level dependence is

  12. Zeolite Y Adsorbents with High Vapor Uptake Capacity and Robust Cycling Stability for Potential Applications in Advanced Adsorption Heat Pumps.

    Science.gov (United States)

    Li, Xiansen; Narayanan, Shankar; Michaelis, Vladimir K; Ong, Ta-Chung; Keeler, Eric G; Kim, Hyunho; McKay, Ian S; Griffin, Robert G; Wang, Evelyn N

    2015-01-01

    Modular and compact adsorption heat pumps (AHPs) promise an energy-efficient alternative to conventional vapor compression based heating, ventilation and air conditioning systems. A key element in the advancement of AHPs is the development of adsorbents with high uptake capacity, fast intracrystalline diffusivity and durable hydrothermal stability. Herein, the ion exchange of NaY zeolites with ingoing Mg(2+) ions is systematically studied to maximize the ion exchange degree (IED) for improved sorption performance. It is found that beyond an ion exchange threshold of 64.1%, deeper ion exchange does not benefit water uptake capacity or characteristic adsorption energy, but does enhance the vapor diffusivity. In addition to using water as an adsorbate, the uptake properties of Mg,Na-Y zeolites were investigated using 20 wt.% MeOH aqueous solution as a novel anti-freeze adsorbate, revealing that the MeOH additive has an insignificant influence on the overall sorption performance. We also demonstrated that the labscale synthetic scalability is robust, and that the tailored zeolites scarcely suffer from hydrothermal stability even after successive 108-fold adsorption/desorption cycles. The samples were analyzed using N2 sorption, (27)Al/(29)Si MAS NMR spectroscopy, ICP-AES, dynamic vapor sorption, SEM, Fick's 2(nd) law and D-R equation regressions. Among these, close examination of sorption isotherms for H2O and N2 adsorbates allows us to decouple and extract some insightful information underlying the complex water uptake phenomena. This work shows the promising performance of our modified zeolites that can be integrated into various AHP designs for buildings, electronics, and transportation applications.

  13. Zeolite Y adsorbents with high vapor uptake capacity and robust cycling stability for potential applications in advanced adsorption heat pumps

    Energy Technology Data Exchange (ETDEWEB)

    Li, XS; Narayanan, S; Michaelis, VK; Ong, TC; Keeler, EG; Kim, H; Mckay, IS; Griffin, RG; Wang, EN

    2015-01-01

    Modular and compact adsorption heat pumps (AHPs) promise an energy-efficient alternative to conventional vapor compression based heating, ventilation and air conditioning systems. A key element in the advancement of AHPs is the development of adsorbents with high uptake capacity, fast intracrystalline diffusivity and durable hydrothermal stability. Herein, the ion exchange of NaY zeolites with ingoing Mg2+ ions is systematically studied to maximize the ion exchange degree (IED) for improved sorption performance. It is found that beyond an ion exchange threshold of 64.1%, deeper ion exchange does not benefit water uptake capacity or characteristic adsorption energy, but does enhance the vapor diffusivity. In addition to using water as an adsorbate, the uptake properties of Mg, Na-Y zeolites were investigated using 20 wt.% MeOH aqueous solution as a novel anti-freeze adsorbate, revealing that the MeOH additive has an insignificant influence on the overall sorption performance. We also demonstrated that the lab-scale synthetic scalability is robust, and that the tailored zeolites scarcely suffer from hydrothermal stability even after successive 108-fold adsorption/desorption cycles. The samples were analyzed using N-2 sorption, Al-27/Si-29 MAS NMR spectroscopy, ICP-AES, dynamic vapor sorption, SEM, Fick's 2nd law and D-R equation regressions. Among these, close examination of sorption isotherms for H2O and N-2 adsorbates allows us to decouple and extract some insightful information underlying the complex water uptake phenomena. This work shows the promising performance of our modified zeolites that can be integrated into various AHP designs for buildings, electronics, and transportation applications. (C) 2014 Elsevier Inc. All rights reserved.

  14. New composite sorbents of water and ammonia for chemical and adsorption heat pumps

    Science.gov (United States)

    Aristov, Yu. I.; Vasiliev, L. L.

    2006-11-01

    New sorbents of water and ammonia — “salt in porous matrix” composites and “salt on fiber” composites — have been reviewed. The possibility of “constructing” the sorption properties of the composites at the nanophase level by varying their composition, the size of the host-matrix pores, and synthesis conditions has been shown. The application of the new materials in adsorption refrigerating devices has been considered.

  15. Theoretical research of a silica gel-water adsorption chiller in a micro combined cooling, heating and power (CCHP) system

    Energy Technology Data Exchange (ETDEWEB)

    Li, S.; Wu, J.Y. [Shanghai Jiao Tong University, Institute of Refrigeration and Cryogenics, Dongchuan Road 800, Shanghai 200240 (China)

    2009-06-15

    A novel micro CCHP system, which is based on a two bed silica gel-water adsorption chiller, is constructed in this work. To reveal the chiller characteristic in this system, a transient model of the adsorption chiller is developed. According to the comparison of the simulated results and experimental data, the presented model shows a good performance in predicting the chiller performance, with both stable and variable heat source temperature. With the analysis of simulated results, it is found that the cooling capacity and the coefficient of performance (COP) of the chiller are influenced significantly by the average value and variation rate of electric load, as well as the average value of cooling load. The water tank also shows a great effect on the chiller performance. To get better performance of the chiller, the water tank should be adopted when the electric load is low or its variation rate is positive, and should not be utilized when the electric load is high or its variation rate is negative. A 500 L water tank is recommended in order to get better performance and acceptable start-up time. Furthermore, to get better performance as well as higher security, a cold accumulator should be adopted. (author)

  16. Performance investigation of a waste heat-driven 3-bed 2-evaporator adsorption cycle for cooling and desalination

    KAUST Repository

    Thu, Kyaw

    2016-06-13

    Environment-friendly adsorption (AD) cycles have gained much attention in cooling industry and its applicability has been extended to desalination recently. AD cycles are operational by low-temperature heat sources such as exhaust gas from processes or renewable energy with temperatures ranging from 55 °C to 85 °C. The cycle is capable of producing two useful effects, namely cooling power and high-grade potable water, simultaneously. This article discusses a low temperature, waste heat-powered adsorption (AD) cycle that produces cooling power at two temperature-levels for both dehumidification and sensible cooling while providing high-grade potable water. The cycle exploits faster kinetics for desorption process with one adsorber bed under regeneration mode while full utilization of the uptake capacity by adsorbent material is achieved employing two-stage adsorption via low-pressure and high-pressure evaporators. Type A++ silica gel with surface area of 863.6 m2/g and pore volume of 0.446 cm3/g is employed as adsorbent material. A comprehensive numerical model for such AD cycle is developed and the performance results are presented using assorted hot water and cooling water inlet temperatures for various cycle time arrangements. The cycle is analyzed in terms of key performance indicators i.e.; the specific cooling power (SCP), the coefficient of performance (COP) for both evaporators and the overall system, the specific daily water production (SDWP) and the performance ratio (PR). Further insights into the cycle performance are scrutinized using a Dühring diagram to depict the thermodynamic states of the processes as well as the vapor uptake behavior of adsorbent. In the proposed cycle, the adsorbent materials undergo near saturation conditions due to the pressurization effect from the high pressure evaporator while faster kinetics for desorption process is exploited, subsequently providing higher system COP, notably up to 0.82 at longer cycle time while the

  17. District heating operated adsorption heat pump with soil deposit for multistorey housing, office and institutional buildings - phase 1. Final report; Fjernvarmedrevne adsorptionsvarmepumper med jordlager til etageboliger, kontor- og institutionsbyggeri - fase 1. Slutrapport

    Energy Technology Data Exchange (ETDEWEB)

    2009-08-15

    The main idea of the concept was to show new ways to improve the use of district heating used as driving energy in an adsorption heat pump. This can take free heat from borehole storage to heat the building. By this the borehole stor-age is cooled and can be used for cooling the following summer, either directly or by using the adsorption machine as a cooling machine. This will heat the borehole storage (regenerate it) and it is ready to use as heat pump the follow-ing winter. It was shown that with this concept, compared with the traditional solution, a reduction of CO{sub 2} emission of 29% ca be realised with a payback time of approx. 14 years. It was assumed that the concept could only be used under special circumstances (limestone in the grounds, large plants), but analysis has shown that modifications of the original concept makes it more generally applicable. It is assumed however that there is a cooling demand of at least half of the heat demand and it is assumed that low-temperature heating at max 35 degrees C and preferably lower can be used. The report contains a thorough analysis of the importance of various parameters for performance of systems using the concept. The market for adsorption machines has evolved during the project, such that on completion of the project better and cheaper machines are available. The concept is presently (August 2009) being implemented in two buildings, Green Light House and Viborg New City Hall. In Viborg City Hall a combination of heat and electrical heating / cooling is used, so that the heating (with heat pump) and cooling can be made with electricity or with district heating. This fits well into the future flexible energy with varying heat and electricity prices and availability. (author)

  18. Effects of heat-treatment and hydrogen adsorption on Graphene grown on Cu foil

    Science.gov (United States)

    Cho, Jongweon; Gao, Li; Tian, Jifa; Cao, Helin; Yu, Qingkai; Guest, Jeffrey; Chen, Yong; Guisinger, Nathan

    2011-03-01

    Graphene has recently been a subject of intense research efforts due to its remarkable physical properties as an ideal two-dimensional material. While numerous different methods for graphene synthesis are being explored, CVD-grown graphene on Cu foil presents the possibility of a large-scale and high-quality synthesis of graphene.[1] To improve the quality of graphene films on Cu foil prepared by CVD and better understand its microscopic growth, atomic-scale characterization becomes of great importance. We have investigated the effects of thermal annealing and hydrogen adsorption/desorption on ex-situ CVD-grown monolayer graphene on polycrystalline Cu foil at the atomic-scale using ultrahigh vacuum scanning tunneling microscopy, and we will report on these studies.

  19. Experimental Setup for Determining Ammonia-Salt Adsorption and Desorption Behavior Under Typical Heat Pump Conditions. Experimental Results

    Energy Technology Data Exchange (ETDEWEB)

    Van der Pal, M.; De Boer, R.; Veldhuis, J.B.J. [ECN Biomass and Energy Efficiency, Petten (Netherlands)

    2013-09-15

    For the aim of obtaining a better understanding of the performance of a salt-ammonia sorption reactor/heat exchanger a new test-rig was developed. This test-rig enables the measurement of the performance in adsorption and desorption mode of different sorption reactor designs. It measures the speed of uptake and release of ammonia gas of various salt-ammonia reactions under well-controlled and well-monitored process conditions, similar to the heat pump conditions. The test-rig measures the ammonia uptake and release under controlled pressure and temperature conditions. Temperatures of the salt reactor can be varied from ambient temperature up to 200{sup o}C and the ammonia pressure can be varied between 0.02 to 2 MPa. These conditions can be set independently and repeated at regular time-intervals. Besides NH3-mass-flow meters, pressure and temperature sensors, the setup also contains an endoscope to observe any macroscopic structural changes in the material during uptake and release of ammonia. Measurements so far have shown a liquid phase of LiCl.3NH3 at pressures of 0.5 MPa and temperatures exceeding 90{sup o}C. Voilent foaming is observed at 120{sup o}C resulting in salt losses. A correlation was determined between the reaction rate of MgCl{sub 2}(2-6)NH3 and the relative pressure gradient yielding a reaction time of about 1500 seconds for a relative pressure difference of 1. Multiple sorption cycles of the CaCl{sub 2}(2-4)NH3 reaction, showed a reduced activity from 85% of the theoretical maximum sorbed mass at the first sorption cycle, to 15% after 300+ cycles.

  20. Theoretical study on adsorption heat of methane in coal%煤体对瓦斯吸附热的理论研究

    Institute of Scientific and Technical Information of China (English)

    刘志祥; 冯增朝

    2012-01-01

    Microscopic mechanism of adsorption heat's generation was expounded systematically.On the basis of the potential energy model,two-energy-state model was got and the computational formula of the corresponding adsorption heat was deduced.On the basis of the grand canonical ensemble theory,the Langmuir monolayer model of statistical mechanics was got,and the computational formula of the corresponding adsorption heat was deduced.This paper cited De Broglie thermal average wavelength,and got the approximate computational formula of adsorption heat based on the Langmuir monolayer model.To compare the two models,it shows that adsorption heat is much affected by the adsorption capacity,adsorption centers and the average distance between molecules,and that we should use different physical models for analysis towards the outer layer of methane(relative to the coal surface) and the inner methane.On the basis of the Langmuir monolayer model,from perspective of adsorption,the fractal features of pore structure and fracture structure was studied,the two-dimensional flat surface adsorption to the fractal surface adsorption was extended,and a fractal dimension based on De Broglie thermal average wavelength was got.%系统地阐述了吸附热产生的微观机理,根据势能模型,得到了基于玻尔兹曼分布的两能态模型,并推导出相应的吸附热计算公式。根据巨正则系综理论,得到了朗缪尔单分子层统计力学模型,并推导出相应的吸附热计算公式;引入德布罗意平均热波长后,得到了朗缪尔单分子层模型吸附热的近似计算公式。比较两种模型的结果可以看出:吸附热受吸附量、吸附中心和分子间平均距离的影响较大,对于外层瓦斯(相对于煤体表面)和内层瓦斯应该采用不同的物理模型进行分析。根据朗缪尔单分子层模型,从吸附的角度出发,研究了煤体表面结构的分形特征,并将二维平面吸附推广到分形表面吸附,

  1. Prediction of Pure Component Adsorption Equilibria Using an Adsorption Isotherm Equation Based on Vacancy Solution Theory

    DEFF Research Database (Denmark)

    Marcussen, Lis; Aasberg-Petersen, K.; Krøll, Annette Elisabeth

    2000-01-01

    An adsorption isotherm equation for nonideal pure component adsorption based on vacancy solution theory and the Non-Random-Two-Liquid (NRTL) equation is found to be useful for predicting pure component adsorption equilibria at a variety of conditions. The isotherm equation is evaluated successfully...... adsorption systems, spreading pressure and isosteric heat of adsorption are also calculated....

  2. Carbonaceous materials for adsorptive refrigerators

    Science.gov (United States)

    Buczek, B.; Wolak, E.

    2012-06-01

    Carbon monoliths prepared from hard coal precursors were obtained. The porous structure of the monoliths was evaluated on the basis of nitrogen adsorption — desorption equilibrium data. The investigated monoliths have a well-developed microporous structure with significant specific surface area (S BET ). Equilibrium studies of methanol vapour adsorption were used to characterize the methanol adsorptive capacity that was determined using a volumetric method. The heat of wetting by methanol was determined in order to estimate the energetic effects of the adsorption process. The results of the investigations show that all monoliths exhibit high adsorption capacity and high heat of wetting with methanol.

  3. Improving the Performance of an Adsorption Heat Converter in Condensation and Evaporation of the Adsorbate in Sorbent Pores

    Science.gov (United States)

    Lyakh, M. Yu.; Rabinovich, O. S.; Vasiliev, L. L.; Tsitovich, A. P.

    2013-11-01

    The possibilities of raising the specific refrigerating capacity and the cooling temperature of an adsorption refrigerator through the phase transition of the adsorbate in low-temperature-sorbent pores have been investigated by the computer-modeling method. Using an adsorption refrigerator with busofite-based MnCl2 and BaCl2 sorbents (in the high-temperature and low-temperature adsorbers respectively) as an example, it has been shown that the operating regime of the refrigerator with adsorbate condensation and evaporation enables one to raise the specific capacity of the apparatus by 20% and to double the average cooling temperature.

  4. Design of Heat Pipe Type Adsorption Ice Maker for Fishing Boats%热管型船用吸附制冰机的设计

    Institute of Scientific and Technical Information of China (English)

    王丽伟; 王如竹; 夏再忠; 吴静怡

    2005-01-01

    A heat pipe type adsorption ice maker with two adsorbers for fishing boats is designed by using ammonia as refrigerant and compound of activated carbon-CaCl2 as adsorbent. This type of heat pipe adsorber can solve the problem of incompatibility between ammonia, copper, seawater and steel. The working process of the ice maker with 8.7kg adsorbent per bed is simulated. The results show that the optimal semi-cycle time is about 9min at the evaporating temperature of -15℃, where the corresponding cooling power, specific cooling power per kilogram adsorbent SCP and coefficient of refrigerant performance COP are respectively 3.6 kW, 217W·kg-1 and 0.404.

  5. Effect of heat treatment on the properties of ZnO thin films prepared by successive ion layer adsorption and reaction (SILAR)

    Energy Technology Data Exchange (ETDEWEB)

    Jimenez-Gonzalez, A.; Suarez-Parra, R. [Photovoltaic Systems Group, Laboratorio de Energia Solar, IIM, Universidad Nacional Autonoma de Mexico, Temixco, Morelos (Mexico)

    1996-10-03

    ZnO thin films prepared by the chemical deposition technique, SILAR (successive ion layer adsorption and reaction), exhibit zincite (hexagonal) structure, are transparent in the visible and infrared region (90 % optical transmittance), and photoconductive. Heat treatments significantly modify the stoichiometry and crystal structure of as-prepared ZnO and therefore its optical and electrical properties. The dark conductivity of ZnO thin films changes according to the gas atmosphere employed during the treatment. As-prepared samples (of thickness 667 A) show a dark conductivity of 1.50x10{sup -6} [{Omega}{center_dot}cm]{sup -1}, while a maximum dark conductivity of 2.70x10{sup -2} [ {Omega}{center_dot}cm]{sup -1} was achieved after consecutive heat treatments in O{sub 2} and H{sub 2} at 350C. The optical bandgap, 3.38 eV, of the as-prepared ZnO decreases by 0.125 eV after annealing. The activation energy for the dark conductivity is much less, 0.65 eV (as prepared) to 0.11 eV (annealed in O{sub 2}) indicating that the defect structure in the film plays an important part in the charge carrier transport

  6. Adsorption of gaseous pollutants on activated carbon filters. Modelling of the coupled exchanges of heat and mass; Adsorption de polluants gazeux sur des filtres de charbon actif. Modelisation des echanges couples de matiere et de chaleur

    Energy Technology Data Exchange (ETDEWEB)

    Fiani, E.

    2000-01-27

    The aim of this work is to remove gasoline and odorous molecules vapors. Thermodynamics and kinetics studies have been carried out; they concern the fixation of representative gases on activated carbons. Hydrogen sulfide and n-butane are chosen to represent the odorous molecules. Different activated carbons are considered: only the adsorbent impregnated by KOH has satisfying performance. The adsorption of hydrocarbons on a granulated activated carbon is studied on four original devices specifically perfected for this work: gravimetry, calorimetry, thermal measurements and gaseous phase chromatography. The gravimetric measurements are coupled to thermal measurements inside the granulates. Strong temperature variations have then been observed inside a granulate during the adsorption. These experimental results have been taken into account to adapt the classical Langmuir kinetic model. This new model allows to predict all the curves: setting / internal temperature variation for the adsorption of the hydrocarbons alone. The competitive nature of the adsorption sites allows then to explain qualitatively the adsorption of binary mixtures of hydrocarbons. At last, the classical Langmuir model allows to explain correctly the thermodynamic results, for the hydrocarbons alone or in binary mixture. The proposed modelling allows then to treat both on a kinetic and thermodynamic way the case of a non isothermal adsorption at the scale of an activated carbon granulate and to predict the phenomena at the filter scale. (O.M.)

  7. Development of facile property calculation model for adsorption chillers based on equilibrium adsorption cycle

    Science.gov (United States)

    Yano, Masato; Hirose, Kenji; Yoshikawa, Minoru; Thermal management technology Team

    Facile property calculation model for adsorption chillers was developed based on equilibrium adsorption cycles. Adsorption chillers are one of promising systems that can use heat energy efficiently because adsorption chillers can generate cooling energy using relatively low temperature heat energy. Properties of adsorption chillers are determined by heat source temperatures, adsorption/desorption properties of adsorbent, and kinetics such as heat transfer rate and adsorption/desorption rate etc. In our model, dependence of adsorption chiller properties on heat source temperatures was represented using approximated equilibrium adsorption cycles instead of solving conventional time-dependent differential equations for temperature changes. In addition to equilibrium cycle calculations, we calculated time constants for temperature changes as functions of heat source temperatures, which represent differences between equilibrium cycles and real cycles that stemmed from kinetic adsorption processes. We found that the present approximated equilibrium model could calculate properties of adsorption chillers (driving energies, cooling energies, and COP etc.) under various driving conditions quickly and accurately within average errors of 6% compared to experimental data.

  8. 固体吸附式空调/热泵在火电厂中的应用研究%STUDY ON APPLYING SOLID-ADSORPTION AIR CONDITIONING / HEAT PUMP IN THERMAL POWER PLANT

    Institute of Scientific and Technical Information of China (English)

    李中华; 王如竹; 刘建军; 柳正军; 刘洪文

    2001-01-01

    采用新型固体吸附式制冷技术开发了电站锅炉排污热回收系统。该系统可直接回收排污热进行空调制冷,并对电厂热力系统进行热泵供热,不但节约大量空调用电,而且提高了机组热经济性,具有显著的节能效果。%A heat recovery system of discharged waste water from boilers in thermal power plant was developed. The recovered heat can be used to drive solid-adsorption refrigerator for air conditioning and supply heat to heat-pump for thermal system, reducing greatly the electricity consumption of air conditioning, improving thermal efficiency of generating units, resulting in obvious energy-saving effect.

  9. Study on the adsorption isosteres of the composite adsorbent CaCl2 and expanded graphite

    International Nuclear Information System (INIS)

    A test setup was built to study the adsorption performance of the composite adsorbent used in the adsorption system. The isovolume measurement method is adopted in the test setup to measure the adsorption isosteres of the composite adsorbent and ammonia working pair. The adsorption isosteres are the curves of the adsorption pressures variation with adsorption temperatures at constant adsorption quantity, which are convenient for the calculation of the adsorption heat and selection of the adsorption working pairs. The adsorption heats were calculated according to the adsorption isosteres, three clear crest values indicate that there were three types of reaction during the reaction processes of ammoniate calcium chloride and ammonia. The kinetic model of adsorption isosteres is obtained by the Temkin model, it is useful to estimate the adsorption performance of the working pairs and useful to guide the design of adsorption system.

  10. Experimental Investigation on a Zeolite-water Adsorption Chiller Driven by Low Heat Source%低温驱动沸石-水吸附式制冷机的性能研究

    Institute of Scientific and Technical Information of China (English)

    王南南; 刘再冲; 邓立生; 何兆红; 窪田光宏; 大坂侑吾; 黄宏宇; 陈颖

    2016-01-01

    A novel type of adsorption chiller with synthetic zeolite-water was proposed, in which the zeolite FAMZ01 was chosen as the ad-sorbent and coated adsorber with fin as adsorber. The effects of heat source temperature and chilled water inlet temperature on cooling power and coefficient of performance ( COP) were obtained experimentally. The results showed that the adsorption chiller can supply the chilled water steadily at driven heat source temperature of 55℃, and is with better performance at the driving heat source temperature about 65℃.%本文研究的合成沸石-水吸附式制冷机采用FAMZ01沸石作为吸附剂,吸附床选择翅片涂抹式吸附床,通过实验研究该制冷机的制冷功率、制冷性能系数( COP)随热源温度、冷冻水进口温度的变化规律。结果表明,该吸附式制冷机在55℃的热源下就可以稳定输出制冷量,并在驱动热源为65℃左右展现其较佳的性能。

  11. MOF compounds for the cry-adsorption of hydrogen. Improvement of the heat transfer and volumetric storage density; MOF-Materialien zur Kryoadsorption von Wasserstoff. Verbesserung von Waermetransfer und volumetrischer Speicherdichte

    Energy Technology Data Exchange (ETDEWEB)

    Jahn, Alexander [Technische Univ. Dresden (Germany). Inst. fuer Energietechnik; Fraunhofer-Institut fuer Fertigungstechnik und Angewandte Materialforschung IFAM, Dresden (Germany); Klaus, Marcel; Haberstroh, Christoph [Technische Univ. Dresden (Germany). Inst. fuer Energietechnik; Roentzsch, Lars [Fraunhofer-Institut fuer Fertigungstechnik und Angewandte Materialforschung IFAM, Dresden (Germany)

    2012-07-01

    The authors of the contribution under consideration report on new composite materials consisting of metal-organic framework compounds (MOF) and graphite for the cry-adsorption of hydrogen (H{sub 2}) at a temperature of 77 K. These composite materials are characterized by an enhanced volumetric and gravimetric storage density for H{sub 2}. Mixtures consisting of Cu-BTC (BTC = benzene-1.3.5-tricarboxylate) as a highly porous metal-organic framework compound and a highly thermally conductive natural graphite were mixed to a compact composite material by a powder-technological process route. Cylindrical pellets of this composite material were implemented in a tube reactor. This tube reactor was integrated in a specially developed test rig environment and used for experiments for adsorption and desorption of hydrogen. The main focus is thereby on the temperature progression within the reaction bed in order to draw conclusions on the extent and dynamics of the heating of the storage material due to the exothermal adsorption of hydrogen. As it could be shown, the enhancement of the effective thermal conductivity of the storage material due to the incorporate graphite affects the storage rate of the composite material. This is a significant advantage in comparison to bulk powder of MOF. In addition to the direct results, the authors also report on the test rig as well as application examples.

  12. Preparation of tamarind fruit seed activated carbon by microwave heating for the adsorptive treatment of landfill leachate: A laboratory column evaluation.

    Science.gov (United States)

    Foo, K Y; Lee, L K; Hameed, B H

    2013-04-01

    The preparation of tamarind fruit seed granular activated carbon (TSAC) by microwave induced chemical activation for the adsorptive treatment of semi-aerobic landfill leachate has been attempted. The chemical and physical properties of TSAC were examined. A series of column tests were performed to determine the breakthrough characteristics, by varying the operational parameters, hydraulic loading rate (5-20 mL/min) and adsorbent bed height (15-21 cm). Ammonical nitrogen and chemical oxygen demand (COD), which provide a prerequisite insight into the prediction of leachate quality was quantified. Results illustrated an encouraging performance for the adsorptive removal of ammonical nitrogen and COD, with the highest bed capacity of 84.69 and 55.09 mg/g respectively, at the hydraulic loading rate of 5 mL/min and adsorbent bed height of 21 cm. The dynamic adsorption behavior was satisfactory described by the Thomas and Yoon-Nelson models. The findings demonstrated the applicability of TSAC for the adsorptive treatment of landfill leachate.

  13. Study of Adsorption Cooling Tube Experiment with Marine Turbine Exhaust Waste Heat%船用轮机尾气余热吸附式冷管的实验研究

    Institute of Scientific and Technical Information of China (English)

    唐祥虎

    2016-01-01

    船用轮机尾气余热吸附式冷管实验以船舶轮机余热利用为背景,基于吸附制冷原理,在一支密闭管内通过吸、脱附循环获得冷量的吸附式制冷单元管;该冷管采用13X沸石分子筛-水工质对,在脱附温度为200℃,吸附温度为12℃工况下,蒸发温度达到了3℃,获得了198.8KJ制冷量,有效地实现了轮机尾气余热的再利用,是一种对环境友好、没有温室效应和臭氧破坏势的制冷方式,该研究具有潜在的应用价值,具有环保和节能的特点。%Adsorption cooling tube experiment of marine turbine exhaust waste heat is set in utilization of ship en -gine waste heat and based on the principle of adsorption refrigeration .It is a refrigeration unit that obtains cold quan-tity through the absorption and stripping cycle in a closed tube .The cooling tube uses 13X zeolite–water as adsorp-tion working pairs which can obtain 198.8KJ cold quantity as well as 3℃evaporating temperature in the condition of 200℃ stripping temperature and 12℃adsorption temperature.It is a way of refrigeration reusing the turbine exhaust gas waste heat , which is friendly to the environment with its GWP&ODP =0.The study has the characteristics of en-vironmental protection and energy saving with potential value of application .

  14. Adsorption Desalination: A Novel Method

    KAUST Repository

    Ng, Kim Choon

    2010-11-15

    The search for potable water for quenching global thirst remains a pressing concern throughout many regions of the world. The demand for new and sustainable sources and the associated technologies for producing fresh water are intrinsically linked to the solving of potable water availability and hitherto, innovative and energy efficient desalination methods seems to be the practical solutions. Quenching global thirst by adsorption desalination is a practical and inexpensive method of desalinating the saline and brackish water to produce fresh water for agriculture irrigation, industrial, and building applications. This chapter provides a general overview of the adsorption fundamentals in terms of adsorption isotherms, kinetics, and heat of adsorption. It is then being more focused on the principles of thermally driven adsorption desalination methods. The recent developments of adsorption desalination plants and the effect of operating conditions on the system performance in terms of specific daily water production and performance ratio are presented. Design of a large commercial adsorption desalination plant is also discussed herein.

  15. Adsorption of Carbon Dioxide on Activated Carbon

    Institute of Scientific and Technical Information of China (English)

    Bo Guo; Liping Chang; Kechang Xie

    2006-01-01

    The adsorption of CO2 on a raw activated carbon A and three modified activated carbon samples B, C, and D at temperatures ranging from 303 to 333 K and the thermodynamics of adsorption have been investigated using a vacuum adsorption apparatus in order to obtain more information about the effect of CO2 on removal of organic sulfur-containing compounds in industrial gases. The active ingredients impregnated in the carbon samples show significant influence on the adsorption for CO2 and its volumes adsorbed on modified carbon samples B, C, and D are all larger than that on the raw carbon sample A. On the other hand, the physical parameters such as surface area, pore volume, and micropore volume of carbon samples show no influence on the adsorbed amount of CO2. The Dubinin-Radushkevich (D-R) equation was the best model for fitting the adsorption data on carbon samples A and B, while the Freundlich equation was the best fit for the adsorption on carbon samples C and D. The isosteric heats of adsorption on carbon samples A, B, C, and D derived from the adsorption isotherms using the Clapeyron equation decreased slightly increasing surface loading. The heat of adsorption lay between 10.5 and 28.4 kJ/mol, with the carbon sample D having the highest value at all surface coverages that were studied. The observed entropy change associated with the adsorption for the carbon samples A, B, and C (above the surface coverage of 7 ml/g) was lower than the theoretical value for mobile adsorption. However, it was higher than the theoretical value for mobile adsorption but lower than the theoretical value for localized adsorption for carbon sample D.

  16. ANALYSIS ON REAL OPERATION AND ADSORBER PERFORMANCE OF A CONTINUOUS HEAT REGENERATIVE ADSORPTION AIR CONDITIONER%连续回热型吸附式空调实际运行与吸附床性能分析

    Institute of Scientific and Technical Information of China (English)

    吴静怡; 王如竹; 许煜雄

    2000-01-01

    近年来,我们研制了一台连续回热型吸附式空调/热泵,该空调/热泵在100热源驱动下,单位质量制冷功率SCP可达到150 W/kg,与此同时COP达到0.4。在系统的实际运行中,吸附床起到了重要的作用。本文介绍了该机组在实际运行中为稳定工况所采取的一系列措施,以及机组运行的实际Clapeyron图,着重讨论了系统运行参数对吸附床性能的影响%A continuous heat regenerative adsorption air conditionerhas been developed, which has specific cooling power of 150 W/kg andCOP of 0.5 in heating temperature of 100. In this systemtwo adsorbers are key devices, which are made of two shell and pipeexchangers. Adsorber performance depends on real operationparameter such as desorption temperature, adsorption temperature,condensing temperature, evaporating temperature, cycle time, massrecovery time and so on. In this paper, the methods controllingtemperature of heat source and evaporatingtemperature for stabilizing working condition are introduced.Clapeyron curves of real operation are showed. The factors effectingadsorber performance, such as cycle time of system and temperature ofheat source and so on, are chiefly discussed

  17. Determination of Differential Enthalpy and Isotherm by Adsorption Calorimetry

    Directory of Open Access Journals (Sweden)

    V. Garcia-Cuello

    2008-01-01

    Full Text Available An adsorption microcalorimeter for the simultaneous determination of the differential heat of adsorption and the adsorption isotherm for gas-solid systems are designed, built, and tested. For this purpose, a Calvet heat-conducting microcalorimeter is developed and is connected to a gas volumetric unit built in stainless steel to record adsorption isotherms. The microcalorimeter is electrically calibrated to establish its sensitivity and reproducibility, obtaining K=154.34±0.23 WV−1. The adsorption microcalorimeter is used to obtain adsorption isotherms and the corresponding differential heats for the adsorption of CO2 on a reference solid, such as a NaZSM-5 type zeolite. Results for the behavior of this system are compared with those obtained with commercial equipment and with other studies in the literature.

  18. Experimental Results and Model Calculations of a Hybrid Adsorption-Compression Heat Pump Based on a Roots Compressor and Silica Gel-Water Sorption

    Energy Technology Data Exchange (ETDEWEB)

    Van der Pal, M.; De Boer, R.; Wemmers, A.K.; Smeding, S.F.; Veldhuis, J.B.J.; Lycklama a Nijeholt, J.A.

    2013-10-15

    Thermally driven sorption systems can provide significant energy savings, especially in industrial applications. The driving temperature for operation of such systems limits the operating window and can be a barrier for market-introduction. By adding a compressor, the sorption cycle can be run using lower waste heat temperatures. ECN has recently started the development of such a hybrid heat pump. The final goal is to develop a hybrid heat pump for upgrading lower (<100C) temperature industrial waste heat to above pinch temperatures. The paper presents the first measurements and model calculations of a hybrid heat pump system using a water-silica gel system combined with a Roots type compressor. From the measurements can be seen that the effect of the compressor is dependent on where in the cycle it is placed. When placed between the evaporator and the sorption reactor, it has a considerable larger effect compared to the compressor placed between the sorption reactor and the condenser. The latter hardly improves the performance compared to purely heat-driven operation. This shows the importance of studying the interaction between all components of the system. The model, which shows reasonable correlation with the measurements, could proof to be a valuable tool to determine the optimal hybrid heat pump configuration.

  19. Adsorption Rate Models for Multicomponent Adsorption Systems

    Institute of Scientific and Technical Information of China (English)

    姚春才

    2004-01-01

    Three adsorption rate models are derived for multicomponent adsorption systems under either pore diffusion or surface diffusion control. The linear driving force (LDF) model is obtained by assuming a parabolic intraparticle concentration profile. Models I and Ⅱ are obtained from the parabolic concentration layer approximation. Examples are presented to demonstrate the usage and accuracy of these models. It is shown that Model I is suitable for batch adsorption calculations and Model Ⅱ provides a good approximation in fixed-bed adsorption processes while the LDF model should not be used in batch adsorption and may be considered acceptable in fixed-bed adsorption where the parameter Ti is relatively large.

  20. Adsorption and wetting.

    NARCIS (Netherlands)

    Schlangen, L.J.M.

    1995-01-01

    Adsorption and wetting are related phenomena. In order to improve knowledge of both and their relations, experiments, thermodynamics and a theoretical interpretation have been connected, starring n-alkanes.Starting from the Gibbs adsorption equation thermodynamic relations between vapour adsorption

  1. 回质回热吸附式制冷循环的热力学分析与方案优选%Thermodynamic analysis of mass and heat recovery adsorption refrigeration cycles and scheme selection

    Institute of Scientific and Technical Information of China (English)

    徐圣知; 王丽伟; 王如竹

    2016-01-01

    吸附式制冷是一种能利用低品位热能的节能环保的制冷方式。在空调工况下,硅胶-水回质回热系统应用最多。为了解在特定工况下选择何种循环能提升系统性能,应用热力学第一与第二定律评价指标分析了基本循环、回质循环、回质回热循环的COP、㶲效率、循环熵产。分析表明,回质循环存在推荐最高热源温度和最优热源温度,回质回热循环存在推荐最低热源温度和最优热源温度。例如对于典型夏季空调工况热源温度90℃、蒸发温度10℃、冷凝温度40℃,回质循环的推荐最高热源温度为93℃,高于实际热源温度90℃,选用回质循环更合适而非回质回热循环。最后,对制冷机组的分析表明给出的方法和推荐工作温度区间能针对实际系统给出方案优选和系统控制的指导性建议。%Adsorption refrigeration is an energy-saving and environmental-friendly refrigerating method, which can utilize low-grade thermal energy. Under air-conditioning working conditions, silica gel-water mass and heat recovery systems are most often used. In order to understand which kind of cycle can improve the performance of the system under specific working conditions, the evaluating indicators of the first and the second laws of thermodynamics were adopted to analyze the COP, the exergetic efficiency and the cycle entropy production of the basic cycle, mass recovery cycle and mass and heat recovery cycle. The analysis showed that only when the heating source temperature was relatively low, the COP of mass recovery cycle was remarkably higher than that of basic cycle. The COP of mass and heat recovery cycle was significantly higher than that of mass recovery cycle only when the heating source temperature was relatively high. Consequently, the mass recovery cycle had its recommended highest heating source temperature and optimum heating source temperature, while the mass and heat recovery

  2. Dynamic analysis of the CTAR (constant temperature adsorption refrigeration) cycle

    International Nuclear Information System (INIS)

    The basic SAR (solar-driven adsorption refrigeration) machine is an intermittent cold production system. Recently, the CO-SAR (continuous operation solar-powered adsorption refrigeration) system is developed. The CO-SAR machine is based on the theoretical CTAR (constant temperature adsorption refrigeration) cycle in which the adsorption process takes place at a constant temperature that equals the ambient temperature. Practically, there should be a temperature gradient between the adsorption bed and the surrounding atmosphere to provide a driving potential for heat transfer. In the present study, the dynamic analysis of the CTAR cycle is developed. This analysis provides a comparison between the theoretical and the dynamic operation of the CTAR cycle. The developed dynamic model is based on the D-A adsorption equilibrium equation and the energy and mass balances in the adsorption reactor. Results obtained from the present work demonstrate that, the idealization of the constant temperature adsorption process in the theoretical CTAR cycle is not far from the real situation and can be approached. Furthermore, enhancing the heat transfer between the adsorption bed and the ambient during the bed pre-cooling process helps accelerating the heat rejection process from the adsorption reactor and therefore approaching the isothermal process. - Highlights: • The dynamic analysis of the CTAR (constant temperature adsorption refrigeration) cycle is developed. • The CTAR theoretical and dynamic cycles are compared. • The dynamic cycle approaches the ideal one by enhancing the bed precooling

  3. Apparatus for thermal swing adsorption and thermally-enhanced pressure swing adsorption

    Science.gov (United States)

    Wegeng, Robert S.; Rassat, Scot D.; Stenkamp, Victoria S.; TeGrotenhuis, Ward E.; Matson, Dean W.; Drost, M. Kevin; Viswanathan, Vilayanur V.

    2005-12-13

    The present invention provides compact adsorption systems that are capable of rapid temperature swings and rapid cycling. Novel methods of thermal swing adsorption and thermally-enhanced pressure swing adsorption are also described. In some aspects of the invention, a gas is passed through the adsorbent thus allowing heat exchangers to be very close to all portions of the adsorbent and utilize less space. In another aspect, the adsorption media is selectively heated, thus reducing energy costs. Methods and systems for gas adsorption/desorption having improved energy efficiency with capability of short cycle times are also described. Advantages of the invention include the ability to use (typically) 30-100 times less adsorbent compared to conventional systems.

  4. Method for thermal swing adsorption and thermally-enhanced pressure swing adsorption

    Science.gov (United States)

    Wegeng, Robert S.; Rassat, Scot D.; Stenkamp, Victoria S.; TeGrotenhuis, Ward E.; Matson, Dean W.; Drost, M. Kevin; Viswanathan, Vilayanur V.

    2003-10-07

    The present invention provides compact adsorption systems that are capable of rapid temperature swings and rapid cycling. Novel methods of thermal swing adsorption and thermally-enhanced pressure swing adsorption are also described. In some aspects of the invention, a gas is passed through the adsorbent thus allowing heat exchangers to be very close to all portions of the adsorbent and utilize less space. In another aspect, the adsorption media is selectively heated, thus reducing energy costs. Methods and systems for gas adsorption/desorption having improved energy efficiency with capability of short cycle times are also described. Advantages of the invention include the ability to use (typically) 30-100 times less adsorbent compared to conventional systems.

  5. Adsorption and wetting.

    OpenAIRE

    Schlangen, L.J.M.

    1995-01-01

    Adsorption and wetting are related phenomena. In order to improve knowledge of both and their relations, experiments, thermodynamics and a theoretical interpretation have been connected, starring n-alkanes.Starting from the Gibbs adsorption equation thermodynamic relations between vapour adsorption and wetting are derived. The surface pressure of a film, formed by vapour adsorption on a solid surface, is calculated by integrating the vapour adsorption isotherm. The surface pressure at the sat...

  6. EFFECTS OF MASS AND HEAT RECOVERY ON PERFORMANCES OF ACTIVATED CARBON/AMMONIA ADSORPTION REFRIGERATION CYCLES%采用回质回热的活性炭-氨吸附制冷循环性能

    Institute of Scientific and Technical Information of China (English)

    曲天非; 王如竹; 王文

    2001-01-01

    回质是改善吸附循环性能的重要手段,回质过程大幅度提高了每循环单位质量吸附剂的制冷量;根据工况的不同,回质过程有可能在一定范围内提高或降低系统的性能系数;回质过程对循环的作用对金属及流体热容变化不敏感;回质回热复合循环具有较高的性能系数.%Mass recovery in activated carbon/ammonia adsorption cycle can play an important role to better the performance of refrigeration cycle. Coefficient of performance might increase or decrease with mass recovery process due to different working conditions. Cooling capacity per kg of adsorbent can be significantly increased with mass recovery process. And the effects of mass recovery do not vary much due to different operating conditions. The effect of mass recovery on cooling capacity does not vary with heat capacity of thermal fluid and bed metal. The higher the condensing temperature is, the more the cooling capacity of mass recovery cycle will be improved. The cycle with mass and heat recovery has a relatively higher COP. It can also be seen that the cycle time will be much shorter and it will certainly enhance the cycle with higher cooling/heating power.

  7. Adsorption refrigeration-green cooling driven by low grade thermal energy

    Institute of Scientific and Technical Information of China (English)

    WANG Ruzhu; WANG Liwei

    2005-01-01

    As a type of environmental benign refrigeration technology powered by low grade thermal energy, adsorption refrigeration have aroused more and more attention in recent years. In this paper, the research frontiers of adsorption refrigeration, including adsorbent, adsorption theory, heat recovery process, technology of adsorber, the research achievements, and the development achievements, are summarized. Typical systems for adsorption refrigeration research facing to applications in the recent years are presented. Future applications of adsorption refrigeration are analysed.

  8. Regenerative adsorbent heat pump

    Science.gov (United States)

    Jones, Jack A. (Inventor)

    1991-01-01

    A regenerative adsorbent heat pump process and system is provided which can regenerate a high percentage of the sensible heat of the system and at least a portion of the heat of adsorption. A series of at least four compressors containing an adsorbent is provided. A large amount of heat is transferred from compressor to compressor so that heat is regenerated. The process and system are useful for air conditioning rooms, providing room heat in the winter or for hot water heating throughout the year, and, in general, for pumping heat from a lower temperature to a higher temperature.

  9. Analysis of the use of adsorption processes in trigeneration systems

    Science.gov (United States)

    Grzebielec, Andrzej; Rusowicz, Artur

    2013-12-01

    The trigeneration systems for production of cold use sorption refrigeration machines: absorption and adsorption types. Absorption systems are characterized namely by better cooling coefficient of performance, while the adsorptive systems are characterized by the ability to operate at lower temperatures. The driving heat source temperature can be as low as 60-70 °C. Such temperature of the driving heat source allows to use them in district heating systems. The article focuses on the presentation of the research results on the adsorption devices designed to work in trigeneration systems.

  10. 船用余热吸附式空调系统性能的测试分析%Test Analysis of Performance of the Adsorption Air Conditioning System Powered by Marine Waste Heat

    Institute of Scientific and Technical Information of China (English)

    王海民; 郑青榕

    2012-01-01

    应用蒸汽驱动的五个由氨-复合吸附剂作制冷工质构成吸附床的制冷空调测试平台,分析循环冷却水进口温度、冷剂的循环量、蒸发温度、加热蒸汽的温度与体积流率变化影响系统供冷量的特点.结果表明,降低循环冷却水进口温度、合理地调控制冷剂流量和提供合适温度和体积流率的蒸汽可提高系统的制冷量和系统运行的稳定性.系统采用电加热锅炉产生蒸汽驱动时,制冷系数(COP)约为0.16,而采用船舶废气锅炉产生蒸汽驱动的COP将可达到1.02.%Applied of the refrigeration performance of a steam powered ammonia adsorption refrigeration unit, which consists of five adsorbers packed with composite adsorbent, the analysis is carried out by varying the inlet temperature, the flow rate of the refrigerant, evaporation temperature as well as the temperature and the volume flow rate of the heating medium. The results show that lowering the inlet temperature of the cooling water, reasonably setting the flow rate of the refrigerant and the steam for heating the adsorbent bed are crucial to stabilizing the refrigerating capacity. The coefficient of the performance (COP) of the unit is about 0.16 with inclusion of the electrical power consumption of the boiler. However, the COP would reach 1.02 on board ship if the steam from the exhaust gas boiler is used.

  11. Adsorption characteristics of siloxanes in landfill gas by the adsorption equilibrium test

    Energy Technology Data Exchange (ETDEWEB)

    Nam, Sangchul; Namkoong, Wan [Department of Environmental Engineering, Konkuk University, Hwayang-Dong, Gwangjin-Gu, Seoul 143-701 (Korea, Republic of); Kang, Jeong-Hee; Park, Jin-Kyu [Department of Environmental Engineering, Anyang University, Anyang 5-Dong, Manan-Gu, Anyang-Si, Gyeonggi-Do 430-714 (Korea, Republic of); Lee, Namhoon, E-mail: nhlee@anyang.ac.kr [Department of Environmental Engineering, Anyang University, Anyang 5-Dong, Manan-Gu, Anyang-Si, Gyeonggi-Do 430-714 (Korea, Republic of)

    2013-10-15

    Highlights: • Equilibrium test was attempted to evaluate adsorption characteristics of siloxane. • L2 had higher removal efficiency in carbon compared to noncarbon adsorbents. • Total adsorption capacity of siloxane was 300 mg/g by coal activated carbon. • Adsorption characteristics rely on size of siloxane molecule and adsorbent pore. • Conversion of siloxane was caused by adsorption of noncarbon adsorbents. - Abstract: Due to the increase in energy cost by constantly high oil prices and the obligation to reduce greenhouse effect gases, landfill gas is frequently used as an alternative energy source for producing heat and electricity. Most of landfill gas utility facilities, however, are experiencing problems controlling siloxanes from landfill gas as their catalytic oxidizers are becoming fouled by silicon dioxide dust. To evaluate adsorption characteristics of siloxanes, an adsorption equilibrium test was conducted and parameters in the Freundlich and Langmuir isotherms were analyzed. Coconut activated carbon (CA1), coal activated carbon (CA2), impregnated activated carbon (CA3), silicagel (NCA1), and activated alumina (NCA2) were used for the adsorption of the mixed siloxane which contained hexamethyldisiloxane (L2), octamethylcyclotetrasiloxane (D4), and decamethylcyclopentasiloxane (D5). L2 had higher removal efficiency in noncarbon adsorbents compared to carbon adsorbents. The application of Langmuir and Freundlich adsorption isotherm demonstrated that coconut based CA1 and CA3 provided higher adsorption capacity on L2. And CA2 and NCA1 provided higher adsorption capacity on D4 and D5. Based on the experimental results, L2, D4, and D5 were converted by adsorption and desorption in noncarbon adsorbents. Adsorption affinity of siloxane is considered to be affect by the pore size distribution of the adsorbents and by the molecular size of each siloxane.

  12. 热处理对木材吸湿特性及尺寸稳定性的影响%Effects of heat treatment on the moisture adsorption characteristic and dimensional stability of wood

    Institute of Scientific and Technical Information of China (English)

    丁涛; 顾炼百; 蔡家斌

    2015-01-01

    Heat treatment of Pinus sylvestris and Quercus mongolica boards were carried out in atmospheric stream or 0�45 MPa pressurized steam. Hygroscopicity and dimensional stability of the treated wood were compared with the con⁃trol. The results showed that heat treatments not only lowered the equilibrium moisture contents ( EMC) of the wood, but also altered the pattern of its moisture adsorption in high humidity environment. When the environmental relative humidity increased from 69% to 94%, the EMC change rates of the heat treated samples were just one third of those of the control samples. This might be attributed to the reconstruction of wood cell wall during the heat treatments. Dimen⁃sional stability of heat treated samples was significantly improved as a result. The radial and tangential swelling of pres⁃surized⁃steam treated Pinus sylvestris samples decreased by 34% and 47% compared to those of the control ones. For Quercus mongolica samples, the corresponding values were 46% and 51%. Most tangential anti⁃swelling efficiency ( ASE) values of the heat treated samples were higher than their radial ASE values. That means swelling difference be⁃tween radial direction and tangential direction was also reduced after heat treatments. It was also showed that pressurized steam induces more pronounced property modification than atmospheric steam.%分别在常压蒸汽与0.45 MPa加压蒸汽条件下,对樟子松和柞木进行热处理,比较了热处理材和未处理材的水分吸湿性及尺寸稳定性差异。结果表明:两种试材经过热处理后不仅吸湿量明显降低,在高湿条件下的吸湿特性也发生了显著变化,当环境相对湿度从69%增至94%时,热处理材的平衡含水率变化率仅为对照材的1/3,细胞壁微观构造在高温条件下的变化可能是造成这一现象的主要原因;吸湿性的降低使热处理材的尺寸稳定性获得了大幅度提高,樟子松试材加压蒸汽

  13. (Amino acid + silica) adsorption thermodynamics: Effects of temperature

    International Nuclear Information System (INIS)

    Highlights: • High resolution, low concentration Gly, Lys and Glu solution adsorption isotherms. • All isotherms fitted with Langmuir–Freundlich isotherm model. • Gly, Lys and Glu show exothermic adsorption processes. • Isosteric heat analyses reveal changes in interaction strength with surface coverage. - Abstract: A thorough understanding of amino acid adsorption by mineral and oxide surfaces has a major impact on a variety of industrial and biomedical applications. Little information currently exists regarding temperature effects on most of these adsorption processes. Deeper thermodynamic analyses of their multiple temperature adsorption isotherms would aid the interpretation of the interfacial interactions. Low solution concentration adsorption isotherms for glycine, lysine and glutamic acid on a silica adsorbent were generated for T = (291, 298 and 310) K. Data analysis via the Clausius–Clapeyron method yielded the isosteric heat of adsorption as a function of fractional monolayer coverage for each adsorptive. Each amino acid showed an exothermic adsorption response. Glycine and lysine experienced a greater negative effect of increased temperature compared with glutamic acid, indicating a greater number of adsorbed molecules than glutamic acid, with the former undergoing intermolecular clustering within the adsorbed phase. Isosteric heat analyses suggest ionic interactions for lysine and hydrogen bonding for glutamic acid, both weakening with increased coverage. In contrast, initial hydrogen bonding led to ionic bonding for glycine with increasing coverage

  14. Fluorocarbon Adsorption in Hierarchical Porous Frameworks

    Energy Technology Data Exchange (ETDEWEB)

    Motkuri, Radha K.; Annapureddy, Harsha V.; Vijayakumar, M.; Schaef, Herbert T.; Martin, P F.; McGrail, B. Peter; Dang, Liem X.; Krishna, Rajamani; Thallapally, Praveen K.

    2014-07-09

    The adsorption behavior of a series of fluorocarbon derivatives was examined on a set of microporous metal organic framework (MOF) sorbents and another set of hierarchical mesoporous MOFs. The microporous M-DOBDC (M = Ni, Co) showed a saturation uptake capacity for R12 of over 4 mmol/g at a very low relative saturation pressure (P/Po) of 0.02. In contrast, the mesoporous MOF MIL-101 showed an exceptionally high uptake capacity reaching over 14 mmol/g at P/Po of 0.4. Adsorption affinity in terms of mass loading and isosteric heats of adsorption were found to generally correlate with the polarizability of the refrigerant with R12 > R22 > R13 > R14 > methane. These results suggest the possibility of exploiting MOFs for separation of azeotropic mixtures of fluorocarbons and use in eco-friendly fluorocarbon-based adsorption cooling and refrigeration applications.

  15. Adsorption characteristics of siloxanes in landfill gas by the adsorption equilibrium test.

    Science.gov (United States)

    Nam, Sangchul; Namkoong, Wan; Kang, Jeong-Hee; Park, Jin-Kyu; Lee, Namhoon

    2013-10-01

    Due to the increase in energy cost by constantly high oil prices and the obligation to reduce greenhouse effect gases, landfill gas is frequently used as an alternative energy source for producing heat and electricity. Most of landfill gas utility facilities, however, are experiencing problems controlling siloxanes from landfill gas as their catalytic oxidizers are becoming fouled by silicon dioxide dust. To evaluate adsorption characteristics of siloxanes, an adsorption equilibrium test was conducted and parameters in the Freundlich and Langmuir isotherms were analyzed. Coconut activated carbon (CA1), coal activated carbon (CA2), impregnated activated carbon (CA3), silicagel (NCA1), and activated alumina (NCA2) were used for the adsorption of the mixed siloxane which contained hexamethyldisiloxane (L2), octamethylcyclotetrasiloxane (D4), and decamethylcyclopentasiloxane (D5). L2 had higher removal efficiency in noncarbon adsorbents compared to carbon adsorbents. The application of Langmuir and Freundlich adsorption isotherm demonstrated that coconut based CA1 and CA3 provided higher adsorption capacity on L2. And CA2 and NCA1 provided higher adsorption capacity on D4 and D5. Based on the experimental results, L2, D4, and D5 were converted by adsorption and desorption in noncarbon adsorbents. Adsorption affinity of siloxane is considered to be affect by the pore size distribution of the adsorbents and by the molecular size of each siloxane. PMID:23684695

  16. Adsorption kinetics,isotherm,and thermodynamic studies of adsorption of pollutant from aqueous solutions onto humic acid

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    In the present study,humic acid was used as an adsorbent for the investigation of the adsorption kinetics,isotherms,and thermo-dynamic parameters of hexavalent chromium from aqueous solution at varying pH,temperatures,and concentrations.Adsorption isotherms and equilibrium adsorption capacities were determined by the fittings of the experimental data to three well-known iso-therm models:Langmuir,Freundlich,and Redlich-Peterson.The results showed that the Langmuir and Redlich-Peterson models appear to fit the adsorption better than did the Freundlich adsorption model for the adsorption of chromium onto humic acid.The equilibrium constants were used to calculate thermodynamic parameters such as the change of free energy,enthalpy,and entropy.The derived adsorption constants (logaL) and their temperature dependencies from Langmuir isotherm have been used to calculate the corresponding thermodynamic quantities such as the free energy of adsorption,heat,and entropy of adsorption.The thermo-dynamic data indicate that Cr (VI) adsorption onto humic acid is entropically driven and characterized by physical adsorption.

  17. Influence of Si/Al ratio on hexane isomers adsorption equilibria

    NARCIS (Netherlands)

    A.F.P. Ferreira; M.C. Mittelmeijer-Hazeleger; A. Bliek; J.A. Moulijn

    2008-01-01

    In this work we aim to have a better knowledge of the influence of silica/alumina ratio (SAR) on the adsorption equilibrium of hexane isomers on MFI zeolites. With a manometric set-up coupled with a micro-calorimeter we did address adsorption properties and heats of adsorption of n-hexane, 2-methylp

  18. Adsorption of light alkanes on coconut nanoporous activated carbon

    Directory of Open Access Journals (Sweden)

    K. S. Walton

    2006-12-01

    Full Text Available This paper presents experimental results for adsorption equilibrium of methane, ethane, and butane on nanoporous activated carbon obtained from coconut shells. The adsorption data were obtained gravimetrically at temperatures between 260 and 300K and pressures up to 1 bar. The Toth isotherm was used to correlate the data, showing good agreement with measured values. Low-coverage equilibrium constants were estimated using virial plots. Heats of adsorption at different loadings were also estimated from the equilibrium data. Adsorption properties for this material are compared to the same properties for BPL activated carbon and BAX activated carbon.

  19. Microcalorimetry of oxygen adsorption on fcc Co{110}.

    Science.gov (United States)

    Liao, Kristine; Fiorin, Vittorio; Jenkins, Stephen J; King, David A

    2012-05-28

    The coverage dependent heats of adsorption and sticking probabilities for oxygen on fcc Co{110} have been measured at 300 K using single crystal adsorption calorimetry (SCAC). Initial adsorption is consistent with dissociative chemisorption at low coverage followed by oxide formation above 0.6 ML coverage. The initial heat of adsorption of 633 kJ mol(-1) is similar to heat values calorimetrically measured on other ferromagnetic metal surfaces, such as nickel and iron. As the coverage increases, the heat of adsorption and sticking probability drop very rapidly up to the onset of oxidation. As already observed for other oxygen-metal surface systems, strong lateral adatom repulsions are responsible for the transition from the chemisorption regime to oxide film formation at higher coverage. The heat of oxide formation at the onset is 475 kJ mol(-1), which is consistent with the formation of CoO crystallites. The oxide film formation is discussed in terms of nucleation and island growth, and the Mott-Cabrera mechanisms, the latter being evidenced by the relatively constant heat of adsorption and sticking probability in contrast to the nickel and iron oxidation cases.

  20. 壳聚糖金属离子印迹树脂的吸附模型%ADSORPTION MODEL OF METAL ION ON IMPRINTING CHITOSAN RESIN

    Institute of Scientific and Technical Information of China (English)

    谭天伟; 贺小进; 杜卫霞

    2001-01-01

    Adsorption model of metal ion on imprinting chitosan resin wasstudied. The chemical and the physical properties such as pore size distribution and heat stability were discussed and the imprinting chitosan resin can be used many times without losing adsorption capacity. The adsorption isotherms and adsorption mechanism were studied and a new model was suggested to correlate relation of adsorption with pH and metal ion concentration,which could explain mechanism of adsorption.

  1. Interfacial adsorption of insulin - Conformational changes and reversibility of adsorption

    NARCIS (Netherlands)

    Mollmann, SH; Jorgensen, L; Bukrinsky, JT; Elofsson, U; Norde, W; Frokjaer, S

    2006-01-01

    The adsorption of human insulin to Teflon particles was studied with respect to conformational changes and the reversibility of adsorption was examined by total internal reflection fluorescence (TIRF). Adsorption isotherms for the adsorption of human insulin indicated high affinity adsorption, even

  2. Interfacial adsorption of insulin. Conformational changes and reversibility of adsorption

    NARCIS (Netherlands)

    Mollmann, S.H.; Bukrinsky, J.T.; Elofsson, U.; Norde, W.; Frokjaer, S.

    2006-01-01

    The adsorption of human insulin to Teflon particles was studied with respect to conformational changes and the reversibility of adsorption was examined by total internal reflection fluorescence (TIRF). Adsorption isotherms for the adsorption of human insulin indicated high affinity adsorption, even

  3. Neon and CO2 adsorption on open carbon nanohorns.

    Science.gov (United States)

    Krungleviciute, Vaiva; Ziegler, Carl A; Banjara, Shree R; Yudasaka, Masako; Iijima, S; Migone, Aldo D

    2013-07-30

    We present the results of a thermodynamics and kinetics study of the adsorption of neon and carbon dioxide on aggregates of chemically opened carbon nanohorns. Both the equilibrium adsorption characteristics, as well as the dependence of the kinetic behavior on sorbent loading, are different for these two adsorbates. For neon the adsorption isotherms display two steps before reaching the saturated vapor pressure, corresponding to adsorption on strong and on weak binding sites; the isosteric heat of adsorption is a decreasing function of sorbent loading (this quantity varies by about a factor of 2 on the range of loadings studied), and the speed of the adsorption kinetics increases with increasing loading. By contrast, for carbon dioxide there are no substeps in the adsorption isotherms; the isosteric heat is a nonmonotonic function of loading, the value of the isosteric heat never differs from the bulk heat of sublimation by more than 15%, and the kinetic behavior is opposite to that of neon, with equilibration times increasing for higher sorbent loadings. We explain the difference in the equilibrium properties observed for neon and carbon dioxide in terms of differences in the relative strengths of adsorbate-adsorbate to adsorbate-sorbent interaction for these species.

  4. Adsorption of xenon and krypton on shales

    International Nuclear Information System (INIS)

    Parameters for the adsorption of Xe and Kr on shales and related samples have been measured by a method that uses a mass spectrometer as a manometer. The gas partial pressures used were 10-11 atm or less; the corresponding adsorption coverages are only small fractions of a monolayer, and Henry's Law behavior is expected and observed. Heats of adsorption in the range 2 to 7 kcal/mol were observed. Henry constants of the order of magnitude 1 cm3 STP g-1 atm-1 at 0 to 250C are obtained by extrapolation. Adsorption properties are variable by sample, but the general range suggests that shales might be sufficiently good adsorbents that equilibrium adsorption with modern air may account for a nontrivial fraction of the atmospheric inventory of Xe (perhaps even Kr). It seems doubtful, however, that this effect can account for the deficiency of atmospheric Xe in comparison with the planetary gas patterns observed in meteorites. If gas is adsorbed on interior surfaces in shale clays and can communicate with sample exteriors only through very narrow channels, and thus only very slowly, equilibrium adsorption may make substantial contributions to experimentally observed 'trapped' gases without the need for any further trapping mechanism. (author)

  5. [Treatment of organic waste gas by adsorption rotor].

    Science.gov (United States)

    Zhu, Run-Ye; Zheng, Liang-Wei; Mao, Yu-Bo; Wang, Jia-De

    2013-12-01

    The adsorption rotor is applicable to treating organic waste gases with low concentration and high air volume. The performance of adsorption rotor for purifying organic waste gases was investigated in this paper. Toluene was selected as the simulative gaseous pollutant and the adsorption rotor was packed with honeycomb modified 13X molecular sieves (M-13X). Experimental results of the fixed adsorption and the rotor adsorption were analyzed and compared. The results indicated that some information on the fixed adsorption was useful for the rotor adsorption. Integrating the characteristics of the adsorbents, waste gases and the structures of the rotor adsorption, the formulas on optimal rotor speed and cycle removal efficiency of the adsorption rotor were deduced, based on the mass and heat balances of the adsorbing process. The numerical results were in good agreement with the experimental data, which meant that the formulas on optimal rotor speed and cycle removal efficiency could be effectively applied in design and operation of the adsorption rotor.

  6. Structure sensitivity in adsorption

    DEFF Research Database (Denmark)

    Hammer, Bjørk; Nielsen, Ole Holm; Nørskov, Jens Kehlet

    1997-01-01

    The structure sensitivity of CO adsorption on different flat, stepped, kinked and reconstructed Pt surfaces is studied using large-scale density-functional calculations. We find an extremely strong structure sensitivity in the adsorption energy with variations up to 1 eV (or 100%) from one...

  7. A Simple Adsorption Experiment

    Science.gov (United States)

    Guirado, Gonzalo; Ayllon, Jose A.

    2011-01-01

    The study of adsorption phenomenon is one of the most relevant and traditional physical chemistry experiments performed by chemistry undergraduate students in laboratory courses. In this article, we describe an easy, inexpensive, and straightforward way to experimentally determine adsorption isotherms using pieces of filter paper as the adsorbent…

  8. Contribution of Ash Content Related to Methane Adsorption Behaviors of Bituminous Coals

    Directory of Open Access Journals (Sweden)

    Yanyan Feng

    2014-01-01

    Full Text Available Methane adsorption isotherms on coals with varying ash contents were investigated. The textural properties were characterized by N2 adsorption/desorption isotherm at 77 K, and methane adsorption characteristics were measured at pressures up to 4.0 MPa at 298 K, 313 K, and 328 K, respectively. The Dubinin-Astakhov model and the Polanyi potential theory were employed to fit the experimental data. As a result, ash content correlated strongly to methane adsorption capacity. Over the ash range studied, 9.35% to 21.24%, the average increase in methane adsorption capacity was 0.021 mmol/g for each 1.0% rise in ash content. With the increasing ash content range of 21.24%~43.47%, a reduction in the maximum adsorption capacities of coals was observed. In addition, there was a positive correlation between the saturated adsorption capacity and the specific surface area and micropore volume of samples. Further, this study presented the heat of adsorption, the isosteric heat of adsorption, and the adsorbed phase specific heat capacity for methane adsorption on various coals. Employing the proposed thermodynamic approaches, the thermodynamic maps of the adsorption processes of coalbed methane were conducive to the understanding of the coal and gas simultaneous extraction.

  9. Controlling the adsorption enthalpy of CO(2) in zeolites by framework topology and composition.

    Science.gov (United States)

    Grajciar, Lukáš; Čejka, Jiří; Zukal, Arnošt; Otero Areán, Carlos; Turnes Palomino, Gemma; Nachtigall, Petr

    2012-10-01

    Zeolites are often investigated as potential adsorbents for CO(2) adsorption and separation. Depending on the zeolite topology and composition (Si/Al ratio and extra-framework cations), the CO(2) adsorption heats at low coverages vary from -20 to -60 kJ mol(-1), and with increasing surface coverage adsorption heats either stay approximately constant or they quickly drop down. Experimental adsorption heats obtained for purely siliceous porous solids and for ion-exchanged zeolites of the structural type MFI, FER, FAU, LTA, TUN, IMF, and -SVR are discussed in light of results of periodic density functional theory calculations corrected for the description of dispersion interactions. Key factors influencing the stability of CO(2) adsorption complexes are identified and discussed at the molecular level. A general model for CO(2) adsorption in zeolites and related materials is proposed and data reported in literature are evaluated with regard to the proposed model. PMID:22887989

  10. Competitive Protein Adsorption - Multilayer Adsorption and Surface Induced Protein Aggregation

    DEFF Research Database (Denmark)

    Holmberg, Maria; Hou, Xiaolin

    2009-01-01

    In this study, competitive adsorption of albumin and IgG (immunoglobulin G) from human serum solutions and protein mixtures onto polymer surfaces is studied by means of radioactive labeling. By using two different radiolabels (125I and 131I), albumin and IgG adsorption to polymer surfaces...... is monitored simultaneously and the influence from the presence of other human serum proteins on albumin and IgG adsorption, as well as their mutual influence during adsorption processes, is investigated. Exploring protein adsorption by combining analysis of competitive adsorption from complex solutions...... of high concentration with investigation of single protein adsorption and interdependent adsorption between two specific proteins enables us to map protein adsorption sequences during competitive protein adsorption. Our study shows that proteins can adsorb in a multilayer fashion onto the polymer surfaces...

  11. Adsorption calorimetry of conjugated organic molecules on metal surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Lytken, Ole; Drescher, Hans-Joerg; Bebensee, Fabian; Steinrueck, Hans-Peter; Gottfried, J. Michael [Universitaet Erlangen-Nuernberg, Lehrstuhl fuer Physikalische Chemie II (Germany)

    2011-07-01

    Traditional experimental methods for determining adsorption energies, such as temperature programmed desorption (TPD) and equilibrium adsorption isotherms, rely on desorption. However, on many metal surfaces large conjugated organic molecules, such as PTCDA and pentacene, decompose at elevated temperatures before or simultaneously with desorption. Discussions about relative bond strengths are, therefore, typically based on indirect arguments, such as the height of the adsorbed species above the surface as measured with normal incidence X-ray standing waves (NIXSW) or chemical shifts in spectroscopic techniques such as X-ray photoelectron spectroscopy (XPS). Unlike the more traditional methods, nanojoule adsorption calorimetry does not require desorption of the molecules; instead, the heat of adsorption is measured directly as an adsorption-induced temperature change of the sample. We will describe the construction of such a calorimeter at the Universitaet Erlangen-Nuernberg.

  12. Hydrogen Adsorption on Pt, Rh and Pt-Rh Electrodes

    Institute of Scientific and Technical Information of China (English)

    贾梦秋; A.M.Meretskyi

    2005-01-01

    The hydrogen adsorption on Pt-Rh alloys in sulfuric acid aqueous solutions was studied by the method of cathode pulses. Hydrogen adsorption on the electrode with all ratio of alloy components (ωRh = 0-100%) is well described by the Temkin logarithmic isotherm. The surface coverage by adsorbed hydrogen at the same potential is decreased with increasing content of rhodium in the system. A linear dependence of adsorption peak potential on the alloy compositions in the case of weakly bonded adsorbed hydrogen is established. Hydrogen adsorption heat as a function of surface coverage for Pt-Rh-electrodes was obtained. The shape of the current-potential curve and position of the weakly bonded hydrogen adsorption on the potential scale are all related to alloy compositions, thus can serve as the basis for the determination surface composition of allovs.

  13. Experimental Microkinetic Approach of De-NO x by NH 3 on V 2 O 5 /WO 3 /TiO 2 Catalysts. 4. Individual Heats of Adsorption of Adsorbed H 2 O Species on Sulfate-Free and Sulfated TiO 2 Supports

    KAUST Repository

    Giraud, François

    2015-07-16

    © 2015 American Chemical Society. The present study is a part of an experimental microkinetic approach of the removal of NOx from coal-fired power plants by reduction with NH3 on V2O5/WO3/TiO2 catalysts (NH3-selective catalytic reduction, NH3-SCR). It is dedicated to the characterization of the heats of adsorption of molecularly adsorbed H2Oads species formed on sulfate-free and sulfated TiO2 supports. Water, which is always present during the NH3-SCR, may be in competition and/or react (formation of NH4+) with the adsorbed NH3 species controlling the coverage of the adsorbed intermediate species of the reaction. Mainly, an original experimental procedure named adsorption equilibrium infrared spectroscopy (AEIR) previously used for the adsorption of NH3 species on the same solids is adapted for the adsorption of H2O. At Ta = 300 K and for PH2 O ≤ 1 kPa, three main H2Oads species are formed (associated with a minor amount of dissociated H2O species) on the two TiO2 solids. The species are identified by the positions of their IR bands in the 3750-3000 cm-1 range. Considering the decreasing order of stability, they are (a) coordinated to strong (L2) and weak (L1) Lewis sites and denoted H2O ads-L2 and H2Oads-L1, respectively, and (b) hydrogen bonded to the H2Oads-L species and on O2-/OH sites of the solids (denoted H2Owads). The three species have a common well-defined δH2O IR band at a position in the range 1640-1610 cm-1 according to the total coverage of the surface. According to the AEIR method, the evolution of the intensity of this IR band during

  14. Heat pipes and solid sorption transformations fundamentals and practical applications

    CERN Document Server

    Vasiliev, LL

    2013-01-01

    Developing clean energy and utilizing waste energy has become increasingly vital. Research targeting the advancement of thermally powered adsorption cooling technologies has progressed in the past few decades, and the awareness of fuel cells and thermally activated (heat pipe heat exchangers) adsorption systems using natural refrigerants and/or alternatives to hydrofluorocarbon-based refrigerants is becoming ever more important. Heat Pipes and Solid Sorption Transformations: Fundamentals and Practical Applications concentrates on state-of-the-art adsorption research and technologies for releva

  15. Hybrid adsorptive membrane reactor

    Science.gov (United States)

    Tsotsis, Theodore T.; Sahimi, Muhammad; Fayyaz-Najafi, Babak; Harale, Aadesh; Park, Byoung-Gi; Liu, Paul K. T.

    2011-03-01

    A hybrid adsorbent-membrane reactor in which the chemical reaction, membrane separation, and product adsorption are coupled. Also disclosed are a dual-reactor apparatus and a process using the reactor or the apparatus.

  16. Hybrid adsorptive membrane reactor

    Science.gov (United States)

    Tsotsis, Theodore T. (Inventor); Sahimi, Muhammad (Inventor); Fayyaz-Najafi, Babak (Inventor); Harale, Aadesh (Inventor); Park, Byoung-Gi (Inventor); Liu, Paul K. T. (Inventor)

    2011-01-01

    A hybrid adsorbent-membrane reactor in which the chemical reaction, membrane separation, and product adsorption are coupled. Also disclosed are a dual-reactor apparatus and a process using the reactor or the apparatus.

  17. Adsorption behaviour of bulgur.

    Science.gov (United States)

    Erbaş, Mustafa; Aykın, Elif; Arslan, Sultan; Durak, Atike N

    2016-03-15

    The aim of this research was to determine the adsorption behaviour of bulgur. Three different particle sizes (2dry matter and 4.96-16.57, respectively. Constant k was between 0.85 and 0.93, and GAB equation was determined to fit very well for bulgur adsorption, because of %E values lower than 10%. Bulgur must be stored below 70% relative humidity and with less than 10 g water per 100 g of dry mater. PMID:26575716

  18. INVESTIGATION OF HEAT TRANSFER CHARACTER ON ADSORBENT BED WITH CONSIDERATION OF NON-EQUILIBRIUM ADSORPTION%具有非平衡吸附特征的吸附床传热特性研究

    Institute of Scientific and Technical Information of China (English)

    王文; 王如竹

    2001-01-01

    吸附床是固体吸附制冷系统的关键部件,对于连续回热等快速进行的吸附制冷循环,吸附床内温度的变化及其压力交变对吸附特性的影响不可忽视。本文对吸附床在吸附、解吸过程中的温度场和吸附率分布进行了模拟计算,并将其与采用平衡吸附模型的计算结果进行了比较,文中比较及结论有助于深入认识吸附床在制冷循环中工作特性,并为吸附床的设计提供参考依据。%The adsorbent bed is the key element of an adsorption refrigeration system.Its operation characteristics of temperature and pressure affect theadsorption characteristics and cycle performance greatly. The discussions about the temperature and adsorbed mass distribution in the adsorbent bedduring adsorption and desorption processes are shown with numerical method.Both models with equilibrium and non-equilibrium adsorption are compared with each other. It is concluded that non-equilibrium adsorption should beconsidered for solid adsorption refrigeration particularly for short cycletime. The discussion and comparison are helpful to reveal operating performance of adsorbent bed and also to provide reference to the design of adsorbent bed.

  19. Hydrogen adsorption on palladium and palladium hydride at 1 bar

    DEFF Research Database (Denmark)

    Johansson, Martin; Skulason, Egill; Nielsen, Gunver;

    2010-01-01

    strongly to Pd hydride than to Pd. The activation barrier for desorption at a H coverage of one mono layer is slightly lower on Pd hydride, whereas the activation energy for adsorption is similar on Pd and Pd hydride. It is concluded that the higher sticking probability on Pd hydride is most likely caused...... by a slightly lower equilibrium coverage of H, which is a consequence of the lower heat of adsorption for H on Pd hydride....

  20. Study of adsorption of Neon on open Carbon nanohorns aggregates

    Science.gov (United States)

    Ziegler, Carl Andrew

    Adsorption isotherms can be used to determine surface area of a substrate and the heat released when adsorption occurs. Our measurements are done determining the equilibrium pressures corresponding to a given amount of gas adsorbed on a substrate at constant temperature. The adsorption studies were done on aggregates of open dahlia-like carbon nanohorns. The nanohorns were oxidized for 9 hours at 550 °C to open them up and render their interior space accessible for adsorption. Volumetric adsorption measurements of Ne were performed at twelve different temperatures between 19 K and 48 K. The isotherms showed two substeps. The first substep corresponds to adsorption on the high energy binding sites in the interior of the nanohorns, near the tip. The second substep corresponds to low energy binding sites both on the outside of the nanotubes and inside the nanotube away from the tip. The isosteric heat measurements obtained from the isotherm data also shows these two distinct substeps. The effective surface area of the open nanotubes was determined from the isotherms using the point-B method. The isosteric heat and surface area data for neon on open nanohorns were compared to two similar experiments of neon adsorbed on aggregates of closed nanohorns.

  1. Operational strategy of adsorption desalination systems

    KAUST Repository

    Thu, Kyaw

    2009-03-01

    This paper presents the performances of an adsorption desalination (AD) system in two-bed and four-bed operational modes. The tested results are calculated in terms of key performance parameters namely, (i) specific daily water production (SDWP), (ii) cycle time, and (iii) performance ratio (PR) for various heat source temperatures, mass flow rates, cycle times along with a fixed heat sink temperature. The optimum input parameters such as driving heat source and cycle time of the AD cycle are also evaluated. It is found from the present experimental data that the maximum potable water production per tonne of adsorbent (silica gel) per day is about 10 m3 whilst the corresponding performance ratio is 0.61, and a longer cycle time is required to achieve maximum water production at lower heat source temperatures. This paper also provides a useful guideline for the operational strategy of the AD cycle. © 2008 Elsevier Ltd. All rights reserved.

  2. Surface Modification Effects on CNTs Adsorption of Methylene Blue and Phenol

    Directory of Open Access Journals (Sweden)

    A. H. Norzilah

    2011-01-01

    Full Text Available This study compares the adsorption capacity of modified CNTs using acid and heat treatment. The CNTs were synthesized from acetone and ethanol as carbon sources, using floating catalyst chemical vapor deposition (FC-CVD method. energy-dispersive X-ray spectroscopy (EDX and Boehm method revealed the existence of oxygen functional group on the surface of CNTs. Heat modification increases the adsorption capacity of as-synthesized CNTs for methylene blue (MB and phenol by approximately 76% and 50%, respectively. However, acid modification decreases the adsorption capacity. The equilibrium adsorption data fitted the Redlich-Peterson isotherm. For the adsorption kinetic study, the experimental data obeyed the pseudo-second-order model. Both modifications methods reduced the surface area and pore volume. The studies show that the adsorption of MB and phenol onto modified CNTs is much more influenced by their surface functional group than their surface area and pore volume.

  3. Experimental Investigation on a Novel Four-bed Adsorption Chiller

    Science.gov (United States)

    Ng, Kim Choon; Chua, Hui Tong; Wang, Jin Bao; Wang, Xiao Lin; Kashiwagi, Takao; Akisawa, Atsushi; Saha, Bidyut Baran

    A prototype multi-bed regenerative adsorption chiller with a novel four-bed operation mode has been designed, fabricated and tested. The rating tests are conducted under assorted ARI coolant, using a purpose-built rating. The 4.bed design exhibits superior heat extraction capability from the heat source as its "slave-first-then-master" arrangement permits individual bed to maximize energy utilization in a batch cycle. Overall system performance of chiller is evaluated for various adsorption-desorption cycle and switching time at assorted coolant inlet temperatures. For fair comparison, the 4-bed chiller is also compared with that of a two-bed mode at the same working conditions.

  4. Fluorocarbon adsorption in hierarchical porous frameworks

    Science.gov (United States)

    Motkuri, Radha Kishan; Annapureddy, Harsha V. R.; Vijaykumar, M.; Schaef, H. Todd; Martin, Paul F.; McGrail, B. Peter; Dang, Liem X.; Krishna, Rajamani; Thallapally, Praveen K.

    2014-07-01

    Metal-organic frameworks comprise an important class of solid-state materials and have potential for many emerging applications such as energy storage, separation, catalysis and bio-medical. Here we report the adsorption behaviour of a series of fluorocarbon derivatives on a set of microporous and hierarchical mesoporous frameworks. The microporous frameworks show a saturation uptake capacity for dichlorodifluoromethane of >4 mmol g-1 at a very low relative saturation pressure (P/Po) of 0.02. In contrast, the mesoporous framework shows an exceptionally high uptake capacity reaching >14 mmol g-1 at P/Po of 0.4. Adsorption affinity in terms of mass loading and isosteric heats of adsorption is found to generally correlate with the polarizability and boiling point of the refrigerant, with dichlorodifluoromethane >chlorodifluoromethane >chlorotrifluoromethane >tetrafluoromethane >methane. These results suggest the possibility of exploiting these sorbents for separation of azeotropic mixtures of fluorocarbons and use in eco-friendly fluorocarbon-based adsorption cooling.

  5. Regenerative adsorption distillation system

    KAUST Repository

    Ng, Kim Choon

    2013-12-26

    There is provided a regenerative adsorption distillation system comprising a train of distillation effects in fluid communication with each other. The train of distillation effects comprises at least one intermediate effect between the first and last distillation effects of the train, each effect comprising a vessel and a condensing tube for flow of a fluid therein. The system further comprises a pair of adsorption-desorption beds in vapour communication with the last effect and at least one intermediate effect, wherein the beds contain an adsorbent that adsorbs vapour from the last effect and transmits desorbed vapour into at least one of the intermediate effect.

  6. A pressure-amplifying framework material with negative gas adsorption transitions

    Science.gov (United States)

    Krause, Simon; Bon, Volodymyr; Senkovska, Irena; Stoeck, Ulrich; Wallacher, Dirk; Többens, Daniel M.; Zander, Stefan; Pillai, Renjith S.; Maurin, Guillaume; Coudert, François-Xavier; Kaskel, Stefan

    2016-04-01

    Adsorption-based phenomena are important in gas separations, such as the treatment of greenhouse-gas and toxic-gas pollutants, and in water-adsorption-based heat pumps for solar cooling systems. The ability to tune the pore size, shape and functionality of crystalline porous coordination polymers—or metal-organic frameworks (MOFs)—has made them attractive materials for such adsorption-based applications. The flexibility and guest-molecule-dependent response of MOFs give rise to unexpected and often desirable adsorption phenomena. Common to all isothermal gas adsorption phenomena, however, is increased gas uptake with increased pressure. Here we report adsorption transitions in the isotherms of a MOF (DUT-49) that exhibits a negative gas adsorption; that is, spontaneous desorption of gas (methane and n-butane) occurs during pressure increase in a defined temperature and pressure range. A combination of in situ powder X-ray diffraction, gas adsorption experiments and simulations shows that this adsorption behaviour is controlled by a sudden hysteretic structural deformation and pore contraction of the MOF, which releases guest molecules. These findings may enable technologies using frameworks capable of negative gas adsorption for pressure amplification in micro- and macroscopic system engineering. Negative gas adsorption extends the series of counterintuitive phenomena such as negative thermal expansion and negative refractive indices and may be interpreted as an adsorptive analogue of force-amplifying negative compressibility transitions proposed for metamaterials.

  7. A pressure-amplifying framework material with negative gas adsorption transitions

    Science.gov (United States)

    Krause, Simon; Bon, Volodymyr; Senkovska, Irena; Stoeck, Ulrich; Wallacher, Dirk; Többens, Daniel M.; Zander, Stefan; Pillai, Renjith S.; Maurin, Guillaume; Coudert, François-Xavier; Kaskel, Stefan

    2016-04-01

    Adsorption-based phenomena are important in gas separations, such as the treatment of greenhouse-gas and toxic-gas pollutants, and in water-adsorption-based heat pumps for solar cooling systems. The ability to tune the pore size, shape and functionality of crystalline porous coordination polymers—or metal–organic frameworks (MOFs)—has made them attractive materials for such adsorption-based applications. The flexibility and guest-molecule-dependent response of MOFs give rise to unexpected and often desirable adsorption phenomena. Common to all isothermal gas adsorption phenomena, however, is increased gas uptake with increased pressure. Here we report adsorption transitions in the isotherms of a MOF (DUT-49) that exhibits a negative gas adsorption; that is, spontaneous desorption of gas (methane and n-butane) occurs during pressure increase in a defined temperature and pressure range. A combination of in situ powder X-ray diffraction, gas adsorption experiments and simulations shows that this adsorption behaviour is controlled by a sudden hysteretic structural deformation and pore contraction of the MOF, which releases guest molecules. These findings may enable technologies using frameworks capable of negative gas adsorption for pressure amplification in micro- and macroscopic system engineering. Negative gas adsorption extends the series of counterintuitive phenomena such as negative thermal expansion and negative refractive indices and may be interpreted as an adsorptive analogue of force-amplifying negative compressibility transitions proposed for metamaterials.

  8. A pressure-amplifying framework material with negative gas adsorption transitions.

    Science.gov (United States)

    Krause, Simon; Bon, Volodymyr; Senkovska, Irena; Stoeck, Ulrich; Wallacher, Dirk; Többens, Daniel M; Zander, Stefan; Pillai, Renjith S; Maurin, Guillaume; Coudert, François-Xavier; Kaskel, Stefan

    2016-04-21

    Adsorption-based phenomena are important in gas separations, such as the treatment of greenhouse-gas and toxic-gas pollutants, and in water-adsorption-based heat pumps for solar cooling systems. The ability to tune the pore size, shape and functionality of crystalline porous coordination polymers--or metal-organic frameworks (MOFs)--has made them attractive materials for such adsorption-based applications. The flexibility and guest-molecule-dependent response of MOFs give rise to unexpected and often desirable adsorption phenomena. Common to all isothermal gas adsorption phenomena, however, is increased gas uptake with increased pressure. Here we report adsorption transitions in the isotherms of a MOF (DUT-49) that exhibits a negative gas adsorption; that is, spontaneous desorption of gas (methane and n-butane) occurs during pressure increase in a defined temperature and pressure range. A combination of in situ powder X-ray diffraction, gas adsorption experiments and simulations shows that this adsorption behaviour is controlled by a sudden hysteretic structural deformation and pore contraction of the MOF, which releases guest molecules. These findings may enable technologies using frameworks capable of negative gas adsorption for pressure amplification in micro- and macroscopic system engineering. Negative gas adsorption extends the series of counterintuitive phenomena such as negative thermal expansion and negative refractive indices and may be interpreted as an adsorptive analogue of force-amplifying negative compressibility transitions proposed for metamaterials. PMID:27049950

  9. Research of Porization and Adsorptions in High-Porous Adsorptive Layers of Vermiculite

    Directory of Open Access Journals (Sweden)

    K. Syrmanova

    2016-06-01

    Full Text Available Adsorption capacity of the adsorbent is dependent on the concentration of the substance in the liquid or vapor phase, its partial pressure, temperature, and the initial state of the adsorbent. At the swelling a cellular porous structure is formed, total porosity that connects with the entered number and the content of the gaseous component masses. The rheological characteristics of porous masses have the decisive effect on the porous structure. Common state for all versions of swelling is a plastic-viscous porous mass condition during their porization. The interlayer structure and inter-packet intervals may be considered as vermiculite plate micropores with dimensions of 0.3 – 1.2 nm. Vermiculite cation exchange capacity is in the range of 100-150 mEq / 100 g, i.e. from clay minerals it is one of the most interchangeable. The research results of the internal structure of adsorption layers by the adsorption isotherms means indicative of the internal surface of the porous layer is characterized by an extremely complex and developed form and can be described by means of fractal geometry. A model of the geometric structure of mica materials formed in the process of blistering during heat treatment is developed. The presented model has sufficiently general form and can be used both in the organization of systematic experimental studies of porization and adsorption in the adsorption layers of highly porous, and for the porization vermiculite optimization.

  10. Ethanol adsorption onto carbonaceous and composite adsorbents for adsorptive cooling system

    International Nuclear Information System (INIS)

    The aim of the present paper is the experimental characterization of adsorbent materials suitable for practical applications in adsorption refrigeration systems, employing ethanol as refrigerant. Different commercial activated carbons as well as a properly synthesized porous composite, composed of LiBr inside a silica gel host matrix, have been tested. A complete thermo-physical characterization, comprising nitrogen physi-sorption, specific heat and thermo-gravimetric equilibrium curves of ethanol adsorption over the sorbents, has been carried out. The equilibrium data have been fitted by means of the Dubinin – Astakhov equation. On the basis of the experimental data, a thermodynamic evaluation of the achievable performance of each adsorbent pair has been estimated by calculating the maximum COP (Coefficient of Performance) under typical working boundary conditions for refrigeration and air conditioning applications. The innovative composite material shows the highest thermodynamic performances of 0.64–0.72 for both tested working conditions. Nevertheless, the best carbonaceous material reaches COP value comparable with the synthesized composite. The results have demonstrated the potential of the chosen adsorbents for utilization in adsorption cooling systems. - Highlights: • We studied ethanol adsorption for adsorption cooling systems. • Commercial activated carbons and composite sorbent, LiBr/SiO2, are tested by complete thermo-physical characterization. • A thermodynamic evaluation has been carried out on each working pairs to estimate the performance of a refrigeration cycle

  11. Performance Study of Adsorption Cooling Cycle for Automotive Air-conditioning

    OpenAIRE

    Ali, Syed Muztuza; Chakraborty, Anutosh

    2015-01-01

    Exhaust gas from automobile can be used to drive adsorption cooling based air conditioning system for the vehicle cabin. This study describes the thermodynamic framework of a two stage indirect exhaust heat recovery system of automotive engine and an effective lumped parameter model to simulate the dynamic behaviors of an adsorption chiller that ranges from the transient to the cyclic steady states. Silica gel and water are used as adsorbent-adsorbate pair. The adsorption chiller model is dev...

  12. HYDROGEN SULFIDE ADSORPTION BY ALKALINE IMPREGNATED COCONUT SHELL ACTIVATED CARBON

    Directory of Open Access Journals (Sweden)

    HUI SUN CHOO

    2013-12-01

    Full Text Available Biogas is one type of renewable energy which can be burnt to produce heat and electricity. However, it cannot be burnt directly due to the presence of hydrogen sulfide (H2S which is highly corrosive to gas engine. In this study, coconut shell activated carbon (CSAC was applied as a porous adsorbent for H2S removal. The effect of amount of activated carbon and flow rate of gas stream toward adsorption capacity were investigated. Then, the activated carbons were impregnated by three types of alkaline (NaOH, KOH and K2CO3 with various ratios. The effects of various types of alkaline and their impregnation ratio towards adsorption capacity were analysed. In addition, H2S influent concentration and the reaction temperature on H2S adsorption were also investigated. The result indicated that adsorption capacity increases with the amount of activated carbon and decreases with flow rate of gas stream. Alkaline impregnated activated carbons had better performance than unimpregnated activated carbon. Among all impregnated activated carbons, activated carbon impregnated by K2CO3 with ratio 2.0 gave the highest adsorption capacity. Its adsorption capacity was 25 times higher than unimpregnated activated carbon. The result also indicated that the adsorption capacity of impregnated activated carbon decreased with the increment of H2S influent concentration. Optimum temperature for H2S adsorption was found to be 50˚C. In this study, the adsorption of H2S on K2CO3 impregnated activated carbon was fitted to the Langmuir isotherm. The fresh and spent K2CO3 impregnated activated carbon were characterized to study the adsorption process.

  13. K+ Adsorption Kinetics of Fluvo-Aquic and Cinnamon Soil Under DifferentTemperature

    Institute of Scientific and Technical Information of China (English)

    LONGHuai-yu; LIYun-zhu; ZHANGWei-li; JIANGYi-chao

    2004-01-01

    The K+ adsorption kinetics of fluvo-aquic soil and cinnamon soil under different temperatures were studied. The results showed: 1) The first order equations were the most suitable for fitting the adsorption under various temperature levels with constant K+ concentration in displacing fluid. With temperature increasing, the fitness of Elovich equation increased,while those of power equation and parabolic diffusion equation decreased; 2)the apparent adsorption rate constant ka and the product of ka multiplied by the apparent equilibrium adsorption q∞ increased when temperature increased, while the apparent equilibrium adsorption q∞reduced; 3)temperature influenced hardly the reaction order, the order of concentration and adsorpton site were always 1 under various temperatures, if they were taken into account simultaneously, the adsorption should be a two-order reaction process; 4)the Gibbs free energy change A G of potassium adsorption were negative, ranged from -4 444.56to -2 450.63 Jmol-1,and increased with temperature increasing, while enthalpy change A H,entropy change A S, apparent adsorption activation Ea, adsorption activation energy E2 and desorption activation energy E2 were temperature-independent; 5)the adsorption was spontaneous process with heat releasing and entropy dropping, fluvo-aquic soil released more heat than cinnamon soil.

  14. K+ Adsorption Kinetics of Fluvo-Aquic and Cinnamon Soil Under Different Temperature

    Institute of Scientific and Technical Information of China (English)

    LONG Huai-yu; LI Yun-zhu; ZHANG Wei-li; JIANG Yi-chao

    2004-01-01

    The K+ adsorption kinetics of fluvo-aquic soil and cinnamon soil under different temperatures were studied. The results showed: 1) The first order equations were the most suitable for fitting the adsorption under various temperature levels with constant K+ concentration in displacing fluid. With temperature increasing, the fitness of Elovich equation increased,while those of power equation and parabolic diffusion equation decreased; 2)the apparent adsorption rate constant ka and the product of ka multiplied by the apparent equilibrium adsorption q. increased when temperature increased, while the apparent equilibrium adsorption q∞ reduced; 3)temperature influenced hardly the reaction order, the order of concentration and adsorpton site were always 1 under various temperatures, if they were taken into account simultaneously, the adsorption should be a two-order reaction process; 4)the Gibbs free energy change AG of potassium adsorption were negative, ranged from -4 444.56to -2 450.63 Jmol-1,and increased with temperature increasing, while enthalpy change △H,entropy change △ S, apparent adsorption activation Ea, adsorption activation energy E1and desorption activation energy E2 were temperature-independent; 5)the adsorption was spontaneous process with heat releasing and entropy dropping, fluvo-aquic soil releasedmore heat than cinnamon soil.

  15. Removal of Volatile Organic Compounds by Adsorption and Photocatalytic Oxydation

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Based on the study of equilibrium adsorption on viscose rayon-based activated carbon fiber (ACF) by gravimetric method, mounting of TiO2 on PAN-based activated carbon cloth (ACC) and their photocatalytic activity as well as adsorption performance for benzene were investigated. The crystallinity of TiO2 and pore structure were characterized by XRD and N2 adsorption. The results show that crystallinity of TiO2 and pore structure could be postulated by heat treatment condition. Both crystallinity of TiO2 and pore structure of hybrid have effects on photocatalytic performance of TiO2-mounted ACC. It would be more attractive and prospective for the combination of TiO2 photocatalytic activity and adsorption ability of porous materials.

  16. Improved Isotherm Data for Adsorption of Methane on Activated Carbons

    KAUST Repository

    Loh, Wai Soong

    2010-08-12

    This article presents the adsorption isotherms of methane onto two different types of activated carbons, namely, Maxsorb III and ACF (A-20) at temperatures from (5 to 75) °C and pressures up to 2.5 MPa. The volumetric technique has been employed to measure the adsorption isotherms. The experimental results presented herein demonstrate the improved accuracy of the uptake values compared with previous measurement techniques for similar adsorbate-adsorbent combinations. The results are analyzed with various adsorption isotherm models. The heat of adsorption, which is concentration and temperature dependent, has been calculated from the measured isotherm data. Henry\\'s law coefficients for these adsorbent-methane pairs are also evaluated at various temperatures. © 2010 American Chemical Society.

  17. 换热器对化学吸附式制冷系统的影响%Study of the Effects of Heat Exchanger on the Chemical Adsorption Refrigeration System

    Institute of Scientific and Technical Information of China (English)

    彭庆龙; 齐朝晖

    2014-01-01

    The dynamic characteristics of the CaCl2-NH3 chemical adsorption refrigeration system driven by engine exhausted gas was studied. A thermal dynamic model is established to simulate the performanceofevaporation temperature, condensation temperature, evaporator and condenser outlet temperature in the running system and the article summarizes the varieties of system performance parameters in the different evaporation temperature and condensation temperature.Sothis result can provide a reference for the further research on the matching and optimization inthe chemical adsorption refrigeration system.%研究了内燃机尾气驱动的氯化钙-氨化学吸附式制冷系统的动态运行状况。通过建立热力学动态模型,仿真得到蒸发温度、冷凝温度、蒸发器与冷凝器出口温度在系统运行时的变化,并总结了在变蒸发温度或冷凝温度下系统性能参数的变化规律。结论可以为今后有关化学吸附式制冷系统各部件的匹配性和优化系统性能的进一步研究提供参考。

  18. Adsorption of ruthenium ions on activated charcoal: influence of temperature on the kinetics of the adsorption process

    Institute of Scientific and Technical Information of China (English)

    QADEER Riaz

    2005-01-01

    Influence of temperature on ruthenium adsorption on activated charcoal from 3 mol/L HNO3 solutions was investigated in the temperature range of 288 K to 308 K. It was observed that the rise in temperature increases the adsorption of ruthenium ions on activated charcoal and follows the kinetics of first order rate law with rate constant values 0.0564-0.0640 min-1 in the temperature range of 288 K to 308 K respectively. The activation energy for the adsorption process was found to be 1.3806kJ/mol. Various thermodynamics quantities namely △H, △S and △G were computed from the equilibrium constant KC values. The results indicated a positive heat of adsorption, a positive △S and a negative △G.

  19. On thermodynamics of methane+carbonaceous materials adsorption

    KAUST Repository

    Rahman, Kazi Afzalur

    2012-01-01

    This study presents the theoretical frameworks for the thermodynamic quantities namely the heat of adsorption, specific heat capacity, entropy, and enthalpy for the adsorption of methane onto various carbonaceous materials. The proposed theoretical frameworks are developed from the rigor of thermodynamic property surfaces of a single component adsorbate-adsorbent system and by incorporating the micropore filling theory approach, where the effect of adsorbed phase volume is considered. The abovementioned thermodynamic properties are quantitatively evaluated from the experimental uptake data for methane adsorption onto activated carbons such as Maxsorb III at temperatures ranging from 120 to 350 K and pressures up to 25 bar. Employing the proposed thermodynamic approaches, this paper shows the thermodynamic maps of the charge and discharge processes of adsorbed natural gas (ANG) storage system for understanding the behaviors of natural gas in ANG vessel. © 2011 Elsevier Ltd. All rights reserved.

  20. Surface Chemistry of Polymers Physical Adsorption of Nitrogen, Argon, Sulfur Dioxide and Neopentane on Polyvinylidene Fluoride

    OpenAIRE

    Houriet, Jean-Philippe; Ghiste, Patrick; Stoeckli, Fritz

    2007-01-01

    The adsorption of nitrogen, argon, sulfur dioxide and neopentane on polyvinylidene fluoride has been measured by static methods and by gas-solid chromatography. The polymer has a homogeneous surface of low energy, which is not significantly affected by heating.

  1. Pressure swing adsorption modeling of acetone and toluene on activated carbon

    Institute of Scientific and Technical Information of China (English)

    唐琳; 李立清; 邢俊东; 刘峥; 姚小龙

    2013-01-01

    A five steps pressure swing adsorption process was designed for acetone and toluene mixtures separation and recovery. Dynamic distributions of gas phase content and temperature were investigated. Based on the theory of Soret and Dufour, a non-isothermal mathematical model was developed to simulate the PSA process. Effects of heat and mass transfer coefficients were studied. The coupled Soret and Dufour effects were also evaluated. It is found that the heat transfer coefficient has little effect on mass transfer in adsorption stage. However, it has some impacts in desorption stage. The maximum value of C/C0 increases by about 25% as heat transfer coefficient decreases. The temperature variation is less than 0.05 K with the change of mass transfer coefficient, so that the effect of mass transfer coefficient on heat transfer can be ignored. It is also concluded that the Soret and Dufour coupled effects are not obvious in pressure swing adsorption compared with fixed-bed adsorption.

  2. Study of Adsorptive Ethylene/Ethane Separation with Ag+—Exchanged Resins via π—Complexation

    Institute of Scientific and Technical Information of China (English)

    WUZhongbiao; LIUYue

    2002-01-01

    Ag+-exchanged resins are prepared and studied for ethylene/ethane separation by adsorption.On Ag+-exchanged S9,at 25℃ and 0.1013MPa,the equilibrium adsorbed amount for C2H4 is 0.992mmol·g-1,and the adsorption ratio for C2H4/C2H6 is 3.56.The adsorption capacity can be restored almost completely at 25℃ and 75℃,and the desorption residual amount is less than 0.01mmol·g-1.For the adsorption consisting of physical adsorption and π-complexation with energy heterogeneity,the equilibrium data are correlated with Langmuir-Freundlich isotherm equation.Furthermore,the heat of adsorption and the overall diffusion time constants are calculated from the experimental datal.Considering all the adsorption characteristics,the application potential for industrial adsorption process is discussed.

  3. Development of equations for differential and integral enthalpy change of adsorption for simulation studies.

    Science.gov (United States)

    Do, D D; Nicholson, D; Fan, Chunyan

    2011-12-01

    We present equations to calculate the differential and integral enthalpy changes of adsorption for their use in Monte Carlo simulation. Adsorption of a system of N molecules, subject to an external potential energy, is viewed as one of transferring these molecules from a reference gas phase (state 1) to the adsorption system (state 2) at the same temperature and equilibrium pressure (same chemical potential). The excess amount adsorbed is the difference between N and the hypothetical amount of gas occupying the accessible volume of the system at the same density as the reference gas. The enthalpy change is a state function, which is defined as the difference between the enthalpies of state 2 and state 1, and the isosteric heat is defined as the negative of the derivative of this enthalpy change with respect to the excess amount of adsorption. It is suitable to determine how the system behaves for a differential increment in the excess phase adsorbed under subcritical conditions. For supercritical conditions, use of the integral enthalpy of adsorption per particle is recommended since the isosteric heat becomes infinite at the maximum excess concentration. With these unambiguous definitions we derive equations which are applicable for a general case of adsorption and demonstrate how they can be used in a Monte Carlo simulation. We apply the new equations to argon adsorption at various temperatures on a graphite surface to illustrate the need to use the correct equation to describe isosteric heat of adsorption.

  4. Computer simulation of argon adsorption on graphite surface from subcritical to supercritical conditions: the behavior of differential and integral molar enthalpies of adsorption.

    Science.gov (United States)

    Fan, Chunyan; Do, D D; Li, Zili; Nicholson, D

    2010-10-19

    We investigate in detail the computer simulation of argon adsorption on a graphite surface over a very wide range of temperature, from below the triple point to well above the critical point. Adsorption over such a wide temperature range has not been reported previously in the form of adsorption isotherms and enthalpy change during adsorption. The adsorption isotherms can be classified broadly into four categories: below the triple point, the isotherms show stepwise character (a strict layering mechanism) with 2D condensation; type II (according to the IUPAC classification) is followed by isotherms at temperatures above the triple point and below the critical point and a sharp spike is seen for isotherms in the neighborhood of the critical point; and finally the typical behavior of a maximum is observed for isotherms above the critical point. For the isosteric heat, the heat curve (plotted against loading) remains finite for subcritical conditions but is infinite (singularity) at the maximum in excess loading for supercritical adsorption. For the latter case, a better representation of the energy change is the use of the integral molecular enthalpy because this does not exhibit a singularity as in the case of isosteric heat. We compare the differential and integral molecular enthalpies for the subcritical and supercritical adsorptions.

  5. Experimental Investigation on Adsorption Capacity of a Variety of Activated Carbon/Refrigerant Pairs

    Directory of Open Access Journals (Sweden)

    Ahmed N. Shmroukh

    2015-04-01

    Full Text Available This study aims to develop a device with minimum heat and mass transfer limitations between adsorbent and adsorbate, and subsequently to obtain practically applicable adsorption capacity data. Also, 5 kW adsorption chillers (evaporators, condensers and adsorbers are designed based on the experimental output data of the whole tested pairs. A finned-tube heat exchanger was employed and installed at the center adsorber, and each employed adsorbent was immobilized on its surfaces by using an adhesive agent. A variety of pairs: are activated carbon powder (ACP/R-134a, ACP/R-407c, ACP/R-507A, activated carbon granules (ACG/R-507A, ACG /R-407c and ACG /R-134a, were examined at different adsorption temperatures of 25, 30, 35 and 50°C. It was found that, at the adsorption temperature of 25°C the maximum adsorption capacity was 0.8352 kg kg-1 for ACP/R-134a, while at the adsorption temperature of 50°C the maximum adsorption capacity was 0.3207 kg kg-1 for ACP/R- 134a. Therefore, the ACP/R-134a pair is highly recommended to be employed as adsorption refrigeration working pair because of its higher maximum adsorption capacity higher than the other examined pairs.

  6. Characterization of Adsorption Enthalpy of Novel Water-Stable Zeolites and Metal-Organic Frameworks.

    Science.gov (United States)

    Kim, Hyunho; Cho, H Jeremy; Narayanan, Shankar; Yang, Sungwoo; Furukawa, Hiroyasu; Schiffres, Scott; Li, Xiansen; Zhang, Yue-Biao; Jiang, Juncong; Yaghi, Omar M; Wang, Evelyn N

    2016-01-01

    Water adsorption is becoming increasingly important for many applications including thermal energy storage, desalination, and water harvesting. To develop such applications, it is essential to understand both adsorbent-adsorbate and adsorbate-adsorbate interactions, and also the energy required for adsorption/desorption processes of porous material-adsorbate systems, such as zeolites and metal-organic frameworks (MOFs). In this study, we present a technique to characterize the enthalpy of adsorption/desorption of zeolites and MOF-801 with water as an adsorbate by conducting desorption experiments with conventional differential scanning calorimetry (DSC) and thermogravimetric analyzer (TGA). With this method, the enthalpies of adsorption of previously uncharacterized adsorbents were estimated as a function of both uptake and temperature. Our characterizations indicate that the adsorption enthalpies of type I zeolites can increase to greater than twice the latent heat whereas adsorption enthalpies of MOF-801 are nearly constant for a wide range of vapor uptakes.

  7. Characterization of Adsorption Enthalpy of Novel Water-Stable Zeolites and Metal-Organic Frameworks

    Science.gov (United States)

    Kim, Hyunho; Cho, H. Jeremy; Narayanan, Shankar; Yang, Sungwoo; Furukawa, Hiroyasu; Schiffres, Scott; Li, Xiansen; Zhang, Yue-Biao; Jiang, Juncong; Yaghi, Omar M.; Wang, Evelyn N.

    2016-01-01

    Water adsorption is becoming increasingly important for many applications including thermal energy storage, desalination, and water harvesting. To develop such applications, it is essential to understand both adsorbent-adsorbate and adsorbate-adsorbate interactions, and also the energy required for adsorption/desorption processes of porous material-adsorbate systems, such as zeolites and metal-organic frameworks (MOFs). In this study, we present a technique to characterize the enthalpy of adsorption/desorption of zeolites and MOF-801 with water as an adsorbate by conducting desorption experiments with conventional differential scanning calorimetry (DSC) and thermogravimetric analyzer (TGA). With this method, the enthalpies of adsorption of previously uncharacterized adsorbents were estimated as a function of both uptake and temperature. Our characterizations indicate that the adsorption enthalpies of type I zeolites can increase to greater than twice the latent heat whereas adsorption enthalpies of MOF-801 are nearly constant for a wide range of vapor uptakes.

  8. Carbon dioxide and nitrogen adsorption on cation-exchanged SSZ-13 zeolites.

    Science.gov (United States)

    Pham, Trong D; Liu, Qingling; Lobo, Raul F

    2013-01-15

    Samples of high-silica SSZ-13, ion exchanged with protons and alkali-metal cations Li(+), Na(+), and K(+), were investigated using adsorption isotherms of CO(2) and N(2). The results show that Li-, Na-SSZ-13 have excellent CO(2) capacity at ambient temperature and pressure; in general, Li-SSZ-13 shows the highest capacity for N(2), CO(2) particularly in the low-pressure region. The effect of cation type and Si/Al ratio (6 and 12) on the adsorption properties was investigated through analysis of adsorption isotherms and heats of adsorption. The separation of CO(2) in a flue gas mixture was evaluated for these adsorbents in the pressure swing adsorption and vacuum pressure adsorption processes. PMID:23249267

  9. Copper adsorption in tropical oxisols

    Directory of Open Access Journals (Sweden)

    Silveira Maria Lucia Azevedo

    2003-01-01

    Full Text Available Cu adsorption, at concentrations between 0 to 800 mg L-1, was evaluated in surface and subsurface samples of three Brazilian soils: a heavy clayey-textured Rhodic Hapludalf (RH, a heavy clayey-textured Anionic ''Rhodic'' Acrudox (RA and a medium-textured Anionic ''Xanthic'' Acrudox (XA. After adsorption, two consecutive extractions were performed to the samples which received 100 mg L-1 copper. Surface samples adsorbed higher amounts of Cu than the subsurface, and exhibited lower Cu removed after the extractions, reinforcing the influence of the organic matter in the reactions. Cu adsorption was significant in the subsurface horizons of the Oxisols, despite the positive balance of charge, demonstrating the existence of mechanisms for specific adsorption, mainly related to the predominance of iron and aluminum oxides in the mineral fractions. In these samples, Cu was easily removed from the adsorption sites. RH demonstrated a higher capacity for the Cu adsorption in both horizons.

  10. CO2 adsorption on chemically modified activated carbon.

    Science.gov (United States)

    Caglayan, Burcu Selen; Aksoylu, A Erhan

    2013-05-15

    CO2 adsorption capacity of a commercial activated carbon was improved by using HNO3 oxidation, air oxidation, alkali impregnation and heat treatment under helium gas atmosphere. The surface functional groups produced were investigated by diffuse reflectance infrared Fourier transform spectrometer (DRIFTS). CO2 adsorption capacities of the samples were determined by gravimetric analyses for 25-200°C temperature range. DRIFTS studies revealed the formation of carboxylic acid groups on the HNO3 oxidized adsorbents. Increased aromatization and uniform distribution of the Na particles were observed on the samples prepared by Na2CO3 impregnation onto HNO3 oxidized AC support. The adsorption capacities of the nonimpregnated samples were increased by high temperature helium treatments or by increasing the adsorption temperature; both leading to decomposition of surface oxygen groups, forming sites that can easily adsorb CO2. The adsorption capacity loss due to cyclic adsorption/desorption procedures was overcome with further surface stabilization of Na2CO3 modified samples with high temperature He treatments. With Na2CO3 impregnation the mass uptakes of the adsorbents at 20 bars and 25 °C were improved by 8 and 7 folds and at 1 bar were increased 15 and 16 folds, on the average, compared to their air oxidized and nitric acid oxidized supports, respectively. PMID:23500788

  11. Adsorption design for wastewater treatment

    Energy Technology Data Exchange (ETDEWEB)

    Cooney, D.O.

    1998-12-31

    Understand the premier method for removing organic contaminants from water. Straight forward explanations and illustrations allow this overview to fill a dual purpose: study manual and design guide. The book discusses basic properties of activated carbons; explains the kinetics of adsorption processes; describes the design of both fixed-bed and batch process adsorption systems; contains useful knowledge that can be extended to other applications of adsorption, including drinking water treatment; and includes many illustrated examples and practice exercises.

  12. Adsorption of polyhydroxyl based surfactants

    OpenAIRE

    Matsson, Maria

    2005-01-01

    Adsorption on solid surfaces from solution is a fundamental property of a surfactant. It might even be the most important aspect of surfactant behavior, since it influences many applications, such as cleaning, detergency, dispersion, separation, flotation, and lubrication. Consequently, fundamental investigations of surfactant adsorption are relevant to many areas. The main aim of this thesis has been to elucidate the adsorption properties, primarily on the solid/water interface, of a particu...

  13. A Study of the Adsorption of Molecular Deposition Filming Flooding Agent MD-1 on Quartz Sand

    Institute of Scientific and Technical Information of China (English)

    GaoManglai; LiuYong; MengXiuxia; WangJianshe

    2004-01-01

    Molecular deposition filming flooding (MDFF) is a novel oil recovery technique based on the thermopositive monolayer electrostatic adsorption of the MDFF agent on different interfaces within reservoir systems. In this paper, the adsorption property of the MDFF agent, MD-I, on quartz sand has been studied through adsorption experiments at different pH and temperatures. Experimental data are also analyzed kinetically and thermodynamically. The results show that the adsorption of MD-I on quartz sand takes place mainly because of electrostatic interactions, which corresponds to adsorption that increases with pH. Kinetic analyses show that at a higher pH the activation energy for adsorption gets lower and, therefore, the adsorption becomes quicker for MD-1 on quartz sand. Thermodynamic analyses show that pH plays an important role in the adsorption of MD-1 on quartz sand. At a higher pH, more negative surface charges result in the increase of electrostatic interactions between MD-1 and quartz sand. Therefore, the saturated adsorption amount increases and more adsorption heat will be released.

  14. Adsorption and collective paramagnetism

    CERN Document Server

    Selwood, Pierce W

    1962-01-01

    Adsorption and Collective Paramagnetism describes a novel method for studying chemisorption. The method is based on the change in the number of unpaired electrons in the adsorbent as chemisorption occurs. The method is applicable to almost all adsorbates, but it is restricted to ferromagnetic adsorbents such as nickel, which may be obtained in the form of very small particles, that is to say, to ferromagnetic adsorbents with a high specific surface. While almost all the data used illustratively have been published elsewhere this is the first complete review of the subject. The book is addresse

  15. Studies on water treatment by adsorption. Kyuchaku ni yoru mizushori

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, M. (The University of Tokyo, Tokyo (Japan). Institute of Industrial Science)

    1994-06-05

    This paper summarizes studies on the water treatment by adsorption, as for the adsorption during water treatment, reactivation of activated charcoal, and clarification of heating process. Reactivation of activated charcoal for the water treatment is carried out through drying in the heating furnace. Basic problems are the recovery degree of adsorption performance of reactivated activated charcoal and the recovery yield. Behavior of the activated charcoal in the heating reactivation furnace is divided into three stages including drying process, heating process, and gasification process. Among these processes, behaviors of organic matters during heating process are described. Thermogravimetric analyses (TGA) were conducted for activated charcoals adsorbing various organic matters in aqueous solutions. Three types of organic matters were classified from the TGA pattern, i.e., organic matters with relatively low boiling point (type-I), organic matters with higher boiling point (type-II), and phenol and lignin (type-III). Organic matters belonging to type-I and type-II are desorbed or decomposed, to be disappeared. Effectiveness of alkali cleaning is suggested for the type-III organic matters. 3 refs., 5 figs.

  16. The influence of protein aggregation on adsorption kinetics

    Science.gov (United States)

    Rovner, Joel; Roberts, Christopher; Furst, Eric; Hudson, Steven

    2015-03-01

    When proteins adsorb to an air-water interface they lower the surface tension and may form an age-dependent viscoelastic film. Protein adsorption to surfaces is relevant to both commercial uses and biological function. The rate at which the surface tension decreases depends strongly on temperature, solution pH, and protein structure. These kinetics also depend on the degree to which the protein is aggregated in solution. Here we explore these differences using Chymotrypsinogen as a model protein whose degree of aggregation is adjusted through controlled heat treatment and measured by chromatography. To study these effects we have used a micropipette tensiometer to produce a spherical-cap bubble whose interfacial pressure was controlled - either steady or oscillating. Short heat treatment produced small soluble aggregates, and these adsorbed faster than the original protein monomer. Longer heat treatment produced somewhat larger soluble aggregates which adsorbed more slowly. These results point to complex interactions during protein adsorption.

  17. Entropy generation analysis of an adsorption cooling cycle

    KAUST Repository

    Thu, Kyaw

    2013-05-01

    This paper discusses the analysis of an adsorption (AD) chiller using system entropy generation as a thermodynamic framework for evaluating total dissipative losses that occurred in a batch-operated AD cycle. The study focuses on an adsorption cycle operating at heat source temperatures ranging from 60 to 85 °C, whilst the chilled water inlet temperature is fixed at 12.5 °C,-a temperature of chilled water deemed useful for dehumidification and cooling. The total entropy generation model examines the processes of key components of the AD chiller such as the heat and mass transfer, flushing and de-superheating of liquid refrigerant. The following key findings are observed: (i) The cycle entropy generation increases with the increase in the heat source temperature (10.8 to 46.2 W/K) and the largest share of entropy generation or rate of energy dissipation occurs at the adsorption process, (ii) the second highest energy rate dissipation is the desorption process, (iii) the remaining energy dissipation rates are the evaporation and condensation processes, respectively. Some of the noteworthy highlights from the study are the inevitable but significant dissipative losses found in switching processes of adsorption-desorption and vice versa, as well as the de-superheating of warm condensate that is refluxed at non-thermal equilibrium conditions from the condenser to the evaporator for the completion of the refrigeration cycle. © 2012 Elsevier Ltd. All rights reserved.

  18. Neon adsorption on oxidized single-walled carbon nanohorns

    Science.gov (United States)

    Krungleviciute, Vaiva; Migone, Aldo; Yudasaka, Masako; Iijima, Sumio

    2012-02-01

    We will present the results of a study of neon adsorption on oxidized single-walled carbon nanohorns. Our adsorption isotherm measurements were conducted at temperatures below 24.5 K, the triple point for Ne. Results for the effective specific surface area and for the effective pore volume of the nanohorn aggregates will be presented. We will also report on the sorbent-loading dependence of the isosteric heat of neon on the nanohorns, and on the binding energy. Our results for this system will be compared with those obtained for Ne on a sample of dahlia-like nanohorns annealed at 520 K.

  19. Capture of formaldehyde by adsorption on nanoporous materials.

    Science.gov (United States)

    Bellat, Jean-Pierre; Bezverkhyy, Igor; Weber, Guy; Royer, Sébastien; Averlant, Remy; Giraudon, Jean-Marc; Lamonier, Jean-François

    2015-12-30

    The aim of this work is to assess the capability of a series of nanoporous materials to capture gaseous formaldehyde by adsorption in order to develop air treatment process and gas detection in workspaces or housings. Adsorption-desorption isotherms have been accurately measured at room temperature by TGA under very low pressure (padsorption capacity and high affinity toward formaldehyde. In addition, these materials can be completely regenerated by heating at 200°C under vacuum. These cationic zeolites are therefore promising candidates as adsorbents for the design of air depollution process or gas sensing applications.

  20. A heat transfer correlation for transient vapor uptake of powdered adsorbent embedded onto the fins of heat exchangers

    KAUST Repository

    Li, Ang

    2015-10-23

    We present a detailed study on the transient heat transfer phenomena of powdered-adsorbent mixed with an organic binder for adherence to the fins of a heat exchangers. The transient performance of such an adsorbent-heat exchanger configuration has significant application potential in the adsorption desalination plants and chillers but seldom addressed in the literature. An experiment is designed to measure the heat transfer for several adsorption temperatures under a single vapor component environment. Analysis on the experimental data indicates that the adsorbent-adsorbate interactions contribute about 75% of the total thermal resistances throughout the uptake processes. It is found that the initial local adsorption heat transfer coefficients are significantly higher than the average values due primarily to the thermal mass effect of the adsorbent–adsorbate interaction layers. From these experiments, a correlation for the transient local adsorption heat transfer coefficients is presented at the sub-atmospheric pressures and assorted application temperatures.

  1. Effects of contact resistance and metal additives in finned-tube adsorbent beds on the performance of silica gel/water adsorption chiller

    OpenAIRE

    Rezk, Ahmed; Al-Dadah, R.K.; Mahmoud, S.; Elsayed, A.

    2013-01-01

    Recently interest in adsorption cooling systems has increased due to their capability to utilise low grade heat sources and environmentally friendly refrigerants. Currently, most of the commercially available adsorption cooling systems utilise granular packed adsorbent beds. Enhancing the heat transfer process inside the adsorbent bed will improve the overall efficiency of the adsorption system. Using recently developed empirical lumped analytical simulation model for a 450 kW two-bed silica ...

  2. A comparative adsorption study: 17β-estradiol onto aerobic granular sludge and activated sludge.

    Science.gov (United States)

    Zheng, Xiao-ying; He, Yu-jie; Chen, Wei; Wang, Ming-yang; Cao, Su-lan; Ni, Ming; Chen, Yu

    2016-01-01

    Adsorption plays a significant role in removing hydrophobic 17β-estradiol (E2) from wastewater. Batch experiments were conducted to compare the adsorption of E2 onto activated aerobic granular sludge (AGS) and activated sludge (AS), and features evaluated included the adsorption kinetics, thermodynamics, and influence of other environmental factors. By using a non-chemical wet-heat technique, both AGS and AS were treated to inactivated status. Then, after loading E2, the adsorption equilibrium capacity of the AGS was found to be greater than that of the AS at the same initial concentration of E2. Moreover, both the adsorption processes corresponded to a pseudo-second-order kinetic model; the adsorption rate constant of AGS was found to be higher and the half-adsorption time was shorter than that of AS. Next, evaluations of adsorption isotherms and thermodynamics indicated that the adsorption process was mainly a physical process. Lower temperatures facilitated a higher equilibrium adsorption capacity. However, the adsorption binding sites of AGS were distributed more uniformly at higher temperature, in contrast to the distribution found for AS. Finally, acidic conditions and an appropriate ionic strength (0.4 mol/L) were found to be particularly conducive to the adsorption process. Overall, the results showed that AGS has the potential to adsorb E2 with significant efficiency, thereby offering a new and more efficient means of treating E2 and trace oestrogens in wastewater.

  3. Liquid-Phase Adsorption Fundamentals.

    Science.gov (United States)

    Cooney, David O.

    1987-01-01

    Describes an experiment developed and used in the unit operations laboratory course at the University of Wyoming. Involves the liquid-phase adsorption of an organic compound from aqueous solution on activated carbon, and is relevant to adsorption processes in general. (TW)

  4. Adsorption of Hexavalent Chromium from Aqueous Solution Using Chemically Activated Carbon Prepared from Locally Available Waste of Bamboo (Oxytenanthera abyssinica)

    OpenAIRE

    Dula, Tamirat; Siraj, Khalid; Kitte, Shimeles Addisu

    2014-01-01

    This study reports on the adsorption of Hexavalent Chromium from aqueous solutions using activated carbon prepared from bamboo (Oxytenanthera abyssinica) waste by KOH activation heating in an electrical furnace at 1073 K for 3 hrs. Batch adsorption experiments were also carried out as a function of pH, contact time, initial concentration of the adsorbate, adsorbent dosage, and temperature of the solution. Kinetic studies of the data showed that the adsorption follows the pseudo-second-order k...

  5. A CFD Simulation on How the Different Sizes of Silica Gel Will Affect the Adsorption Performance of Silica Gel

    Directory of Open Access Journals (Sweden)

    John White

    2012-01-01

    Full Text Available The application of computational fluid dynamics (CFD in the area of porous media and adsorption cooling system is becoming more practical due to the significant improvement in computer power. The results from previous studies have shown that CFD can be useful tool for predicting the water vapour flow pattern, temperature, heat transfer, flow velocity, and adsorption rate. This paper investigates the effect of silica gel granular size on the water adsorption rate using computational fluid dynamics.

  6. Adsorption-electro-desorption treatment of air polluted by VOCs; Traitement de l'air charge en COV par adsorption-electrodesorption

    Energy Technology Data Exchange (ETDEWEB)

    Subrenat, A.; Le Cloirec, P. [Ecole des Mines de Nantes 44 (France)

    2004-10-01

    Volatile organic compounds (VOCs) are pollutants involved in the greenhouse effect. Their abatement is today seriously controlled when they are produced by industrial classified facilities. This paper presents a air treatment system based on the adsorption by activated carbon tissues. The filters are regenerated by electrical heating. The physico-chemical and electrical properties of activated carbon tissues are presented first with their adsorption properties with respect to VOCs. Then the design of a specific adsorber is described: adsorption filters, pressure drops and air flow, implementation and efficiency. Finally, the efficiency results obtained on a real-scale industrial plant are presented. (J.S.)

  7. Study on the adsorption performance of composite adsorbent of CaCl2 and expanded graphite with ammonia as adsorbate

    International Nuclear Information System (INIS)

    A novel constant volume test unit was built to study the adsorption performance of a new type composite adsorbent. This test unit can measure the adsorption isosteres of the working pairs. The adsorption isosteres are the curves of the adsorption pressure variation with the adsorption temperatures at constant adsorption quantities. Compared to the former test results of isothermals and isobars, the isosteres are better for the calculation of the adsorption heat, desorption heat and the selection the adsorption working pairs. Three experimental results were obtained: the first result was that the expanded graphite powders were superior to the expandable graphite powders to facilitate the transportation of working fluid in the composite adsorbent. The second one was that the composite adsorbent treated by solution is more homogeneous than the simple mixed composite adsorbent and the treated composite adsorbent has a better mass transfer performance. The last one was that the adsorption isosteres was the same one not only in the heating process but also in the cooling process and this performance was not relevant to the homogeneity of the composite adsorbent

  8. Adsorption removal of phosphate from aqueous solution by active red mud

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Red mud is the waste of alumina industry and has high TiO2 and Fe2O3 content which are active components for the adsorption of anion pollutants. In this study, the uptake of phosphate by red mud activated by heat treatment and acid-heat treatment was investigated.The factors influencing the adsorption were also investigated. The result showed that the red mud sample treated using acid-heat method at 80℃ with 0.25 mol/L HCl for 2 h achieved the highest phosphate removal. For the heat-activated red mud, the sample heated at 700℃ for 2 h preformed better than the other heat treatment. Phosphate removal by the activated red mud was significantly pH dependent, and pH 7 was the optimal pH for phosphate removal. The adsorption fits Langmuir isotherm model well and the maximum adsorption capacities of the acid-heat activated red mud and the heat activated samples were 202.9 mgP/g and 155.2 mgP/g, respectively.

  9. Visualization and Measurement of Adsorption/Desorption Process of Ethanol in Activated Carbon Adsorber

    Science.gov (United States)

    Asano, Hitoshi; Murata, Kenta; Takenaka, Nobuyuki; Saito, Yasushi

    Adsorption refrigerator is one of the efficient tools for waste heat recovery, because the system is driven by heat at relative low temperature. However, the coefficient of performance is low due to its batch operation and the heat capacity of the adsorber. In order to improve the performance, it is important to optimize the configuration to minimize the amount of driving heat, and to clarify adsorption/desorption phenomena in transient conditions. Neutron radiography was applied to visualize and measure the adsorption amount distribution in an adsorber. The visualization experiments had been performed at the neutron radiography facility of E-2 port of Kyoto University Research Reactor. Activated carbon and ethanol were used as the adsorbent and refrigerant. From the acquired radiographs, adsorption amount was quantitatively measured by applying the umbra method using a checkered neutron absorber with boron powder. Then, transient adsorption and desorption processes of a rectangular adsorber with 84 mm in width, 50 mm in height and 20 mm in depth were visualized. As the result, the effect of fins in the adsorbent layer on the adsorption amount distribution was clearly visualized.

  10. Experimental study on dynamic gas adsorption

    Institute of Scientific and Technical Information of China (English)

    Qin Yueping; Wang Yaru; Yang Xiaobin; Liu Wei; Luo Wei

    2012-01-01

    In order to predict the actual adsorption amount as gas adsorption reaches the equilibrium,this research designed a dynamic gas adsorption experiment under constant temperature and pressure,and also studied the isopiestic adsorption characteristics of coal samples with same quality but different sizes.Through the experiment,the study found the adsorption-time changing relationships under different pressures of four different size samples.After regression analysis,we obtained the functional relationship between adsorption and time.According to this,the research resulted in the actual adsorption amount when gas adsorption reaches the equilibrium.In addition,the current study obtained the relationship between adsorption and pressure as well as the effect of the coal size to the adsorption rate.These results have great theoretical and practical significance for the prediction of gas amount in coal seam and gas adsorption process.

  11. The adsorption of ethylene on Au/Pd(100) alloy surfaces

    Science.gov (United States)

    Li, Zhenjun; Thuening, Theodore; Tysoe, Wilfred T.

    2016-04-01

    The surface chemistry of ethylene is explored on model Au/Pd(100) alloy surfaces using a combination of temperature-programmed desorption and reflection-absorption infrared spectroscopy. The heat of adsorption of ethylene on the model alloy surface is found to increase monotonically with increasing palladium coverage in the alloy, from ~ 33 kJ/mol for a completely gold-covered surface to ~ 80 kJ/mol as the gold coverage decreases to zero. A large change in heat of adsorption is found for palladium coverages between 0 and ~ 0.35 monolayers, where previous studies have shown that the surface comprises exclusively isolated palladium sites. The heat of adsorption changes more slowly for higher palladium coverages, when palladium-palladium bridge sites appear. Vinyl species are identified for palladium coverages above ~ 0.8 ML from a vibrational mode at ~ 1120 cm- 1, which disappears when the sample is heated to ~ 250 K, due to vinyl decomposition.

  12. Adsorption of Atenolol on Kaolinite

    Directory of Open Access Journals (Sweden)

    Yingmo Hu

    2015-01-01

    Full Text Available In this study the adsorption of atenolol (AT, a β-blocker, on kaolinite, a clay mineral of low surface charge, was investigated under varying initial AT concentration, equilibrium time, solution pH, ionic strength, and temperature conditions. The results showed that the amounts of AT uptake by kaolinite were close to its cation exchange capacity value and the AT adsorption was almost instantaneous, suggesting a surface adsorption. The adsorption was exothermic and the free energy of adsorption was small negative, indicating physical adsorption. The increase in ionic strength of the solution drastically reduced AT uptake on kaolinite. A significant reduction in AT uptake was found at solution pH below 5 or above 10. The FTIR results showed band shifting and disappearance for NH bending vibration and benzene ring skeletal vibration at 3360 and 1515 cm−1 and band splitting at 1412 and 1240 cm−1 attributed to C–N valence vibration coupled with NH bending vibrations and alkyl aryl ether linkage, suggesting the participation of NH, –O–, and benzene ring for AT adsorption on kaolinite.

  13. Adsorption of ciprofloxacin on surface-modified carbon materials.

    Science.gov (United States)

    Carabineiro, S A C; Thavorn-Amornsri, T; Pereira, M F R; Figueiredo, J L

    2011-10-01

    The adsorption capacity of ciprofloxacin (CPX) was determined on three types of carbon-based materials: activated carbon (commercial sample), carbon nanotubes (commercial multi-walled carbon nanotubes) and carbon xerogel (prepared by the resorcinol/formaldehyde approach at pH 6.0). These materials were used as received/prepared and functionalised through oxidation with nitric acid. The oxidised materials were then heat treated under inert atmosphere (N2) at different temperatures (between 350 and 900°C). The obtained samples were characterised by adsorption of N2 at -196 °C, determination of the point of zero charge and by temperature programmed desorption. High adsorption capacities ranging from approximately 60 to 300 mgCPxgC(-1) were obtained (for oxidised carbon xerogel, and oxidised thermally treated activated carbon Norit ROX 8.0, respectively). In general, it was found that the nitric acid treatment of samples has a detrimental effect in adsorption capacity, whereas thermal treatments, especially at 900 °C after oxidation, enhance adsorption performance. This is due to the positive effect of the surface basicity. The kinetic curves obtained were fitted using 1st or 2nd order models, and the Langmuir and Freundlich models were used to describe the equilibrium isotherms obtained. The 2nd order and the Langmuir models, respectively, were shown to present the best fittings.

  14. Carbon nanomaterials for gas adsorption

    CERN Document Server

    Terranova, Maria Letizia

    2012-01-01

    Research in adsorption of gases by carbon nanomaterials has experienced considerable growth in recent years, with increasing interest for practical applications. Many research groups are now producing or using such materials for gas adsorption, storage, purification, and sensing. This book provides a selected overview of some of the most interesting scientific results regarding the outstanding properties of carbon nanomaterials for gas adsorption and of interest both for basic research and technological applications. Topics receiving special attention in this book include storage of H, purific

  15. The relationship between formate adsorption energy and electronic properties: A first principles density functional theory study

    Institute of Scientific and Technical Information of China (English)

    MORIKAWA; Yoshitada; NAKAMURA; Junji

    2009-01-01

    First principles density functional theory calculations have been performed for the chemisorption of formate adsorption on some metal surfaces. For the most stable adsorption site of short-bridge, the calculated formate adsorption energy follows the order of Au(110) < Ag(110) < Cu(110) < Pd(110) < Pt(110) < Ni(110) < Rh(110) < Fe(100) < Mo(100), and a clear linear correlation exists between the adsorption energy and the corresponding heat of formation of metal oxides. Moreover, it has been found that the formate adsorption energy for the transition metals can be correlated well with its d-band center (εd), and the IB Group metals can be described by the coupling matrix element square (Vad2).

  16. Thermodynamic formalism of water uptakes on solid porous adsorbents for adsorption cooling applications

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Baichuan; Chakraborty, Anutosh, E-mail: AChakraborty@ntu.edu.sg [School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)

    2014-05-19

    This Letter presents a thermodynamic formulation to calculate the amount of water vapor uptakes on various adsorbents such as zeolites, metal organic frameworks, and silica gel for the development of an advanced adsorption chiller. This formalism is developed from the rigor of the partition distribution function of each water vapor adsorptive site on adsorbents and the condensation approximation of adsorptive water molecules and is validated with experimental data. An interesting and useful finding has been established that the proposed model is thermodynamically connected with the pore structures of adsorbent materials, and the water vapor uptake highly depends on the isosteric heat of adsorption at zero surface coverage and the adsorptive sites of the adsorbent materials. Employing the proposed model, the thermodynamic trends of water vapor uptakes on various adsorbents can be estimated.

  17. Thermodynamic formalism of water uptakes on solid porous adsorbents for adsorption cooling applications

    Science.gov (United States)

    Sun, Baichuan; Chakraborty, Anutosh

    2014-05-01

    This Letter presents a thermodynamic formulation to calculate the amount of water vapor uptakes on various adsorbents such as zeolites, metal organic frameworks, and silica gel for the development of an advanced adsorption chiller. This formalism is developed from the rigor of the partition distribution function of each water vapor adsorptive site on adsorbents and the condensation approximation of adsorptive water molecules and is validated with experimental data. An interesting and useful finding has been established that the proposed model is thermodynamically connected with the pore structures of adsorbent materials, and the water vapor uptake highly depends on the isosteric heat of adsorption at zero surface coverage and the adsorptive sites of the adsorbent materials. Employing the proposed model, the thermodynamic trends of water vapor uptakes on various adsorbents can be estimated.

  18. Measurement and theoretical analysis of the adsorption of supercritical methane on superactivated carbon

    Institute of Scientific and Technical Information of China (English)

    周理; 李明; 周亚平

    2000-01-01

    Adsorption/desorption isotherms of supercritical methane on superactivated carbon have been measured in the range of 0-10 MPa and 233-333 K (20 K interval). The reversibility of the physical adsorption process is acknowledged. The heat of adsorption of 16.5 kJ/mol is determined from the isotherms, and a new modeling strategy for isotherms with maximum is presented. The model yields fits to the experimental isotherms with precision of ?%, maintaining the constancy of the characteristic energy of adsorption. The exponent of the model equation expresses the pore size distribution feature of the adsorbent. The density of the supercritical adsor-bate is evaluated as a parameter of the model. It is shown that the conventional isotherm theory works too at supercritical condition if the limit state of supercritical adsorption is introduced into isotherm modeling.

  19. Measurement and theoretical analysis of the adsorption of supercritical methane on superactivated carbon

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Adsorption/desorption isotherms of supercritical methane on superactivated carbon have been measured in the range of 0 10 MPa and 233 333 K (20 K interval). The reversibility of the physical adsorption process is acknowledged. The heat of adsorption of 16.5 kJ/mol is determined from the isotherms, and a new modeling strategy for isotherms with maximum is presented. The model yields fits to the experimental isotherms with precision of ±2%, maintaining the constancy of the characteristic energy of adsorption. The exponent of the model equation expresses the pore size distribution feature of the adsorbent. The density of the supercritical adsorbate is evaluated as a parameter of the model. It is shown that the conventional isotherm theory works too at supercritical condition if the limit state of supercritical adsorption is introduced into isotherm modeling.

  20. Evaluation of Optimal Pore Size of (3-Aminopropyltriethoxysilane Grafted MCM-41 for Improved CO2 Adsorption

    Directory of Open Access Journals (Sweden)

    Zhilin Liu

    2015-01-01

    Full Text Available An array of new MCM-41 with substantially larger average pore diameters was synthesized through adding 1,3,5-trimethylbenzene (TMB as the swelling agent to explore the effect of pore size on final adsorbent properties. The pore expanded MCM-41 was also grafted with (3-Aminopropyltriethoxysilane (APTES to determine the optimal pore size for CO2 adsorption. The pore-expanded mesoporous MCM-41s showed relatively less structural regularity but significant increments of pore diameter (4.64 to 7.50 nm; the fraction of mesopore volume also illustrated an increase. The adsorption heat values were correlated with the order of the adsorption capacities for pore expanded MCM-41s. After amine functionalization, the adsorption capacities and heat values showed a significant increase. APTES-grafted pore-expanded MCM-41s depicted a high potential for CO2 capture regardless of the major drawback of the high energy required for regeneration.

  1. Experimental research on dynamic operating characteristics of a novel silica gel-water adsorption chiller

    Institute of Scientific and Technical Information of China (English)

    WANG Dechang; WU Jingyi; WANG Ruzhu; DOU Weidong

    2007-01-01

    A novel silica gel-water adsorption chiller consisting of two adsorption/desorption chambers and an evaporator with one heat-pipe working chamber is experimentally studied.The dynamic operating characteristics of the chiller and the thermodynamic characteristics of the adsorber are obtained.The experimental results show that the dynamic operating characteristics of the chiller and the thermodynamic characteristics of the adsorber are satisfactory and that the cycle is a novel and effective adsorption cycle.A mass recovery process increases the cyclic adsorption capacity of the system and improves adaptability of the chiller to a lowgrade heat source.In addition,the experiment indicates that this novel chiller is highly suitable for an air conditioning system with a low dehumidification requirement or a system with a large cycle flowrate and an industrial cooling water system.

  2. Reversible alteration of CO2 adsorption upon photochemical or thermal treatment in a metal-organic framework.

    Science.gov (United States)

    Park, Jinhee; Yuan, Daqiang; Pham, Khanh T; Li, Jian-Rong; Yakovenko, Andrey; Zhou, Hong-Cai

    2012-01-11

    A metal-organic framework (MOF) for reversible alteration of guest molecule adsorption, here carbon dioxide, upon photochemical or thermal treatment has been discovered. An azobenzene functional group, which can switch its conformation upon light irradiation or heat treatment, has been introduced to the organic linker of a MOF. The resulting MOF adsorbs different amount of CO(2) after UV or heat treatment. This remarkable stimuli-responsive adsorption effect has been demonstrated through experiments.

  3. Reversible Alteration of CO2 Adsorption upon Photochemical or Thermal Treatment in a Metal-Organic Framework

    Energy Technology Data Exchange (ETDEWEB)

    Park, Jinhee; Yuan, Daqiang; Pham, Khanh T.; Li, Jian-Rong; Yakovenko, Andrey A; Zhou, Hong-Cai

    2012-01-11

    A metal–organic framework (MOF) for reversible alteration of guest molecule adsorption, here carbon dioxide, upon photochemical or thermal treatment has been discovered. An azobenzene functional group, which can switch its conformation upon light irradiation or heat treatment, has been introduced to the organic linker of a MOF. The resulting MOF adsorbs different amount of CO₂ after UV or heat treatment. This remarkable stimuli-responsive adsorption effect has been demonstrated through experiments.

  4. Experimental investigation on the optimal performance of Zeolite-water adsorption chiller

    KAUST Repository

    Myat, Aung

    2013-02-01

    This paper presents the performance testing of Zeolite adsorption cooling system driven by low grade waste heat source extracted from prime mover\\'s exhaust, power plant\\'s exhaust and the solar energy. The adsorbent FAM Z01 is used as an adsorbent in the adsorption chiller facility. Owing to its large equilibrium pore volume, it has the high affinity for the water vapor adsorbate. The key advantages of the Zeolite adsorption cooling system are: (i) it has no moving parts rendering less maintenance, (ii) the energy efficient means of cooling by the adsorption process with a low temperature heat source, (iii) the use of vapor pipes are replaced by self actuating vapor valves rendering smaller footprint area and (iv) it is environmental friendly with low carbon footprint. The experimental investigations were carried out for Zeolite adsorption chiller at different key operating conditions namely (i) heat source temperature, (ii) the cycle time and (iii) the heat recovery time. It is investigated that performance of coefficient (COP) of this system could be as high as 0.48 while the waste heat source temperature is applicable as low as 55 °C. © 2012.

  5. Potential Theory of Multicomponent Adsorption

    DEFF Research Database (Denmark)

    Shapiro, Alexander; Stenby, Erling Halfdan

    1998-01-01

    We developed a theory of multicomponent adsorption on the basis of the potential concept originally suggested by Polanyi. The mixture is considered as a heterogeneous substance segregated in the external field emitted by the adsorbent. The same standard equation of state, with no additional fitting...... parameters, is used for the segregated and for the bulk phases. With this approach, few parameters are needed to correlate pure component adsorption isotherms. These parameters may be used to predict adsorption equilibria of multicomponent mixtures without additional adjustment. A connection between...... the potential theory and the spreading pressure concept is established, and problems of the theory consistency are studied. Numerical algorithms are suggested for evaluation of the segregated state of the mixture in the potential field of adsorption forces. Comparison with experimental data shows good agreement...

  6. Adsorption of Benzoic Acid in Aqueous Solution by Bagasse Fly Ash

    Science.gov (United States)

    Suresh, S.

    2012-09-01

    This paper reports the studies on the benzoic acid (BA) onto bagasse fly ash (BFA) was studied in aqueous solution in a batch system. Physico-chemical properties including surface area, surface texture of the GAC before and after BA adsorption onto BFA were analysed using X-ray diffractometer (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). The optimum initial pH for the adsorption of BA was found to be 5.56. The adsorbent dose was 10 g/l for BFA and the equilibrium time 8 h of reaction. Pseudo first and second order models were used to find the adsorption kinetics. It was found that intraparticle diffusion played important role in the adsorption mechanisms of BA and the adsorption kinetics followed pseudo-second order kinetic model rather than the pseudo first order kinetic model. Isotherm data were generated for BA solution having initial concentrations of BA in the range of 10-200 mg/l for the BFA dosage of 10 g/l at temperatures of 288, 303, and 318 K. The adsorption of BA onto BFA was favorably influenced by an increase in temperature. Equilibrium data were well represented by the Redlich-Peterson isotherm model. Values of the change in entropy ( ΔS 0), heat of adsorption ( ΔH 0) for adsorption of BA on BFA was found to be 120.10 and 19.61 kJ/mol respectively. The adsorption of BA onto BFA was an endothermic reaction. Desorption of BA from BFA was studied by various solvents method. Acetic acid was found to be a better eluant for desorption of BA with a maximum desorption efficiency of 55.2 %. Owing to its heating value, spent BFA can be used as a co-fuel for the production of heat in boiler furnaces.

  7. Molecular adsorption on graphene

    Science.gov (United States)

    Kong, Lingmei; Enders, Axel; Rahman, Talat S.; Dowben, Peter A.

    2014-11-01

    Current studies addressing the engineering of charge carrier concentration and the electronic band gap in epitaxial graphene using molecular adsorbates are reviewed. The focus here is on interactions between the graphene surface and the adsorbed molecules, including small gas molecules (H2O, H2, O2, CO, NO2, NO, and NH3), aromatic, and non-aromatic molecules (F4-TCNQ, PTCDA, TPA, Na-NH2, An-CH3, An-Br, Poly (ethylene imine) (PEI), and diazonium salts), and various biomolecules such as peptides, DNA fragments, and other derivatives. This is followed by a discussion on graphene-based gas sensor concepts. In reviewing the studies of the effects of molecular adsorption on graphene, it is evident that the strong manipulation of graphene’s electronic structure, including p- and n-doping, is not only possible with molecular adsorbates, but that this approach appears to be superior compared to these exploiting edge effects, local defects, or strain. However, graphene-based gas sensors, albeit feasible because huge adsorbate-induced variations in the relative conductivity are possible, generally suffer from the lack of chemical selectivity.

  8. Protein Adsorption in Three Dimensions

    OpenAIRE

    Vogler, Erwin A.

    2011-01-01

    Recent experimental and theoretical work clarifying the physical chemistry of blood-protein adsorption from aqueous-buffer solution to various kinds of surfaces is reviewed and interpreted within the context of biomaterial applications, especially toward development of cardiovascular biomaterials. The importance of this subject in biomaterials surface science is emphasized by reducing the “protein-adsorption problem” to three core questions that require quantitative answer. An overview of the...

  9. Amphiphile Adsorption on Rigid Polyelectrolytes

    OpenAIRE

    Kuhn, Paulo S.; Levin, Yan; Barbosa, Marcia C.; Ravazzolo, Ana Paula

    2007-01-01

    A theory is presented which quantitatively accounts for the cooperative adsorption of cationic surfactants to anionic polyelectrolytes. For high salt concentration we find that the critical adsorption concentration (CAC) is a bilinear function of the polyion monomer and salt concentrations, with the coefficients dependent only on the type of surfactant used. The results presented in the paper might be useful for designing more efficient gene delivery systems.

  10. Equilibrium adsorption data from temperature-programmed desorption experiments

    OpenAIRE

    Foeth, Frank; Mugge, José; Vaart, van der, A.W.; Bosch, Hans; Reith, Tom

    1996-01-01

    This work describes a novel method that enables the calculation of a series of adsorption isotherms basically from a single Temperature-Programmed Desorption (TPD) experiment. The basic idea is to saturate an adsorbent packed in a fixed bed at a certain feed concentration and temperature and to subsequently increase its temperature linearly with time, while maintaining a constant feed concentration. We measured TPD response curves for carbon dioxide on activated carbon at different heating ra...

  11. Sorption Refrigeration / Heat Pump Cycles

    Science.gov (United States)

    Saha, Bidyut Baran; Alam, K. C. Amanul; Hamamoto, Yoshinori; Akisawa, Atsushi; Kashiwagi, Takao

    Over the past few decades there have been considerable efforts to use adsorption (solid/vapor) for cooling and heat pump applications, but intensified efforts were initiated only since the imposition of international restrictions on the production and use of CFCs (chlorofluorocarbons) and HCFCs (hydrochlorofluorocarbons). Up to now, only the desiccant evaporative cooling system of the open type has achieved commercial use, predominantly in the United States. Closed-type adsorption refrigeration and heat pump systems are rarely seen in the market, or are still in the laboratory testing stage. Promising recent development have been made in Japan for the use of porous metal hydrides and composite adsorbents. In this paper, a short description of adsorption theories along with an overview of present status and future development trends of thermally powered adsorption refrigeration cycles are outlined putting emphasis on experimental achievements. This paper also addressed some advanced absorption cycles having relatively higher COP, and also summarizes fundamental concepts of GAX cycles and various GAX cycles developed for heat pump applications.

  12. Surface chemistry of polymers. The adsorption of carbon dioxide and sulfur dioxide on polyvinylidene chloride

    OpenAIRE

    Stoeckli, Fritz

    2007-01-01

    Isotherms for the adsorption of nitrogen (77 K), carbon dioxide (195-247 K) and sulfur dioxide (254-293 K) on polyvinylidene chloride have been measured volumetrically. The B.E.T. cross-sectional areas of 18 Å2 (CO2) and 24 Å2 (SO2) are comparable to liquid density values. The isosteric heat of adsorption of CO2 is constant for 0.2

  13. ADSORPTION OF POLYCHLORINATED BIPHENYLS BY SOILS

    OpenAIRE

    Mihaela Preda; Radu Lăcătuşu; Dumitru Marian Motelică; Nicoleta Vrînceanu; Veronica Tănase

    2010-01-01

    The behavior of polychlorinated biphenyls (PCBs) in soil is determined by several factors including adsorption, mobility and degradation. Adsorption, directly or indirectly, influences the other factors. Adsorption process is generally evaluated by using adsorption isotherms representing the relationship between the quantity of substance adsorbed per unit weight and concentration of the substance in solution at equilibrium. They allow determination of the adsorption constant, which is directl...

  14. Adsorption refrigeration technology theory and application

    CERN Document Server

    Wang, Ruzhu; Wu, Jingyi

    2014-01-01

    Gives readers a detailed understanding of adsorption refrigeration technology, with a focus on practical applications and environmental concerns Systematically covering the technology of adsorption refrigeration, this book provides readers with a technical understanding of the topic as well as detailed information on the state-of-the-art from leading researchers in the field. Introducing readers to background on the development of adsorption refrigeration, the authors also cover the development of adsorbents, various thermodynamic theories, the design of adsorption systems and adsorption refri

  15. Modeling of Experimental Adsorption Isotherm Data

    OpenAIRE

    Xunjun Chen

    2015-01-01

    Adsorption is considered to be one of the most effective technologies widely used in global environmental protection areas. Modeling of experimental adsorption isotherm data is an essential way for predicting the mechanisms of adsorption, which will lead to an improvement in the area of adsorption science. In this paper, we employed three isotherm models, namely: Langmuir, Freundlich, and Dubinin-Radushkevich to correlate four sets of experimental adsorption isotherm data, which were obtained...

  16. Study of adsorption isotherms of green coconut pulp

    Directory of Open Access Journals (Sweden)

    Fábia Carolina Gonçalves Lavoyer

    2013-03-01

    Full Text Available Brazil is considered one of the largest producers and consumers of tropical fruits. Green coconut (Cocos nucifera L. stands out not only for its production and consumption, but also for the high amount of waste produced by coconut water industry and in natura consumption. Therefore, there is a need for utilization of this by-product. This study aims to study the adsorption isotherms of green coconut pulp and determine its isosteric heat of sorption. The adsorption isotherms at temperatures of 30, 40, 50, 60, and 70 °C were analyzed, and they exhibit type III behavior, typical of sugar rich foods. The experimental results of equilibrium moisture content were correlated by models present in the literature. The Guggenheim, Anderson and De Boer (GAB model proved particularly good overall agreement with the experimental data. The heat of sorption determined from the adsorption isotherms increased with the decrease in moisture content. The heat of sorption is considered as indicative of intermolecular attractive forces between the sorption sites and water vapor, which is an important factor to predict the shelf life of dried products.

  17. Effect of pyrolysis temperatures and times on the adsorption of cadmium onto orange peel derived biochar.

    Science.gov (United States)

    Tran, Hai Nguyen; You, Sheng-Jie; Chao, Huan-Ping

    2016-02-01

    The mechanism and capacity of adsorption of cadmium (Cd) on orange peel (OP)-derived biochar at various pyrolysis temperatures (400, 500, 600, 700 and 800°C) and heating times (2 and 6 h) were investigated. Biochar was characterized using proximate analysis, point of zero charge (PZC) analysis, Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray diffraction. Equilibrium and kinetic experiments of Cd adsorption on biochar were performed. The results indicated that the pH value at PZC of biochar approached 9.5. Equilibrium can be reached rapidly (within 1 min) in kinetic experiments and a removal rate of 80.6-96.9% can be generated. The results fitted the pseudo-second-order model closely. The adsorption capacity was estimated using the Langmuir model. The adsorption capacity of Cd on biochar was independent of the pyrolysis temperature and heating time (p>0.01). The maximum adsorption capacity of Cd was 114.69 (mg g(-1)). The adsorption of Cd on biochar was regarded as chemisorption. The primary adsorption mechanisms were regarded as Cπ-cation interactions and surface precipitation. Cadmium can react with calcite to form the precipitation of (Ca,Cd)CO3 on the surface of biochar. The OP-derived biochar can be considered a favourable alternative and a new green adsorbent for removing Cd(2+) ions from an aqueous solution. PMID:26608900

  18. Effect of pyrolysis temperatures and times on the adsorption of cadmium onto orange peel derived biochar.

    Science.gov (United States)

    Tran, Hai Nguyen; You, Sheng-Jie; Chao, Huan-Ping

    2016-02-01

    The mechanism and capacity of adsorption of cadmium (Cd) on orange peel (OP)-derived biochar at various pyrolysis temperatures (400, 500, 600, 700 and 800°C) and heating times (2 and 6 h) were investigated. Biochar was characterized using proximate analysis, point of zero charge (PZC) analysis, Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray diffraction. Equilibrium and kinetic experiments of Cd adsorption on biochar were performed. The results indicated that the pH value at PZC of biochar approached 9.5. Equilibrium can be reached rapidly (within 1 min) in kinetic experiments and a removal rate of 80.6-96.9% can be generated. The results fitted the pseudo-second-order model closely. The adsorption capacity was estimated using the Langmuir model. The adsorption capacity of Cd on biochar was independent of the pyrolysis temperature and heating time (p>0.01). The maximum adsorption capacity of Cd was 114.69 (mg g(-1)). The adsorption of Cd on biochar was regarded as chemisorption. The primary adsorption mechanisms were regarded as Cπ-cation interactions and surface precipitation. Cadmium can react with calcite to form the precipitation of (Ca,Cd)CO3 on the surface of biochar. The OP-derived biochar can be considered a favourable alternative and a new green adsorbent for removing Cd(2+) ions from an aqueous solution.

  19. Dynamic modeling of adsorption refrigerators for systm simulation; Dynamische Modellierung von Adsorptionskaelteanlagen fuer Systemsimulation

    Energy Technology Data Exchange (ETDEWEB)

    Dalibard, Antoine; Eicker, Ursula [Hochschule fuer Technik Stuttgart (Germany). Zentrum fuer nachhaltige Energietechnik; Ziegler, Felix [Technische Univ. Berlin (Germany). Inst. fuer Energietechnik, KT2

    2012-07-01

    The present paper deals with the dynamic modelling of two beds adsorption chillers with a special focus on the heat and mass recovery processes. A physical model able to calculate different heat recovery processes as well as mass recovery has been developed and implemented in the transient simulation environment TRNSYS. The main parameters required by the model and the modelling approach used are presented. Several concepts of heat recovery are presented and discussed. Also the concept of mass recovery is described. The model parameters have been adjusted to fit measurement data of an existing large capacity adsorption chiller (350 kW). This fitted model has been used to investigate the influence of the different heat recovery concepts on the chiller performance in steady state conditions. Depending on the concepts, the thermal COP can be increased by 10 to 30% in comparison with a cycle without heat recovery. Using mass recovery allows to increase the thermal COP by more than 10% and the cooling capacity by 2.5%. Combining both heat and mass recovery results in 35% COP improvement without reducing the cooling capacity. Comparing to other existing models, the model presents some advantages. It can simulate different heat recovery schemes and includes the possibility to calculate mass recovery between the two chambers. This model can be used for two beds adsorption chillers using different working pairs as silica-gel/water. Additionally, the model can be used for system simulation in order to investigate the influence of the transient behaviour of adsorption chillers on other components like cooling towers, solar collectors, buildings.. Further works will focus on the control optimization of adsorption chiller(s) at part load conditions. Also the primary energy savings potential of solar cooling systems equipped with adsorption chillers by using advanced controls will be investigated.

  20. Ammonia Process by Pressure Swing Adsorption

    Energy Technology Data Exchange (ETDEWEB)

    Dr Felix Jegede

    2010-12-27

    The overall objective of the project is to design, develop and demonstrate a technically feasible and commercially viable system to produce ammonia along with recovery of the products by adsorption separation methods and significantly decrease the energy requirement in ammonia production. This is achieved through a significantly more efficient ammonia psa recovery system. The new ammonia recovery system receives the reactor effluents and achieves complete ammonia recovery, (which completely eliminates the energy intensive refrigeration and condensation system currently used in ammonia production). It also recovers the unused reactants and recycles them back to the reactor, free of potential reactor contaminants, and without the need for re-compression and re-heat of recycle stream thereby further saving more energy. The result is a significantly lower energy consumption, along with capital cost savings.

  1. Adsorption Studies of Radish Leaf Powder

    Directory of Open Access Journals (Sweden)

    Ankita

    2016-01-01

    Full Text Available Radish leaves (Raphanus sativus powder fractions was subjected to moisture adsorption isotherms at different isothermal temperature conditions from 15-45°C with an equal interval of 10°C. The sorption data obtained in gravimetric static method under 0.11–0.90 water activity conditions were subjected for sorption isotherms and found to be typical sigmoid trend. Experimental data were assessed for the applicability in the prediction through sorption models fitting and found that Polynomial and GAB equations performed well over all fitted models in describing equilibrium moisture content – equilibrium relative humidity (EMC–ERH relationships for shelf stable dehydrated radish leaf powder, over the entire range of temperatures condition under study. The net isosteric heat of sorption, differential entropy and free energy were determined at different temperatures and their dependence was seen with respect to equilibrium moisture content.

  2. On the explanation of hysteresis in the adsorption of ammonia on graphitized thermal carbon black.

    Science.gov (United States)

    Zeng, Yonghong; Do, D D; Horikawa, Toshihide; Nicholson, D; Nakai, Kazuyuki

    2016-01-14

    We present a Monte Carlo simulation and experimental study of ammonia adsorption on graphitized thermal carbon black. Our new molecular model for the adsorbent is composed of basal plane graphene surfaces with ultrafine pores grafted with hydroxyl groups at the junctions between graphene layers. The simulated adsorption isotherms and isosteric heats are in good agreement with the experimental data of Holmes and Beebe, and the simulations reproduce the unusual experimental hysteresis of ammonia adsorption on an open graphite surface for the first time in the literature. The detailed mechanisms of adsorption and desorption, and the origin of hysteresis, are investigated by the microscopic analysis of the adsorbate structures to show that restructuring occurs during adsorption. The main results from this work are: (i) at the triple point, ammonia adsorbs preferentially around the functional groups to form clusters in the ultrafine pores and spills-over onto the basal plane as the loading is increased; followed by a 2D condensation on the graphite surface to form a bilayer adsorbate; (ii) at the boiling point, adsorption occurs on the basal plane due to the increasing importance of thermal fluctuations (an entropic effect); (iii) the isosteric heat is very high at zero loading due to the strong interaction between ammonia and the functional groups, decreases steeply when the functional group is saturated, and eventually reaches the heat of condensation as the fluid-fluid interaction increases. PMID:26661571

  3. Effect of the switching time on the performance of an adsorption chiller

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Sang Woo; Chung, Jae Dong [Sejong University, Seoul (Korea, Republic of); Kwon, Oh Kyung [Korea Institute of Industrial Technology, Chonan (Korea, Republic of)

    2016-05-15

    The switching time is an important operating condition that must be correctly anticipated for an effective adsorption cooling system. Before the adsorption (or desorption) process begins, time is required to cool down (or heat up) the bed temperature so that the bed pressure reaches the evaporator pressure (or condenser pressure). During the switching time, the supplied heat is reduced and pressure overload conditions can be avoided. The switching time cannot be estimated early on, and an improper switching time degrades the system performance. Thus, this study provides guideline with which to determine the required time to open this valve, i.e., the switching time, and carefully examines the thermo-physical behavior in the adsorption bed during this period. A two-dimensional numerical method with the composite sorbent of SWS-1L and a water pair is applied to a fin-tube type adsorption chiller. Three cases of no switching time, the optimal switching time and a double the optimal switching time are examined. The results show that no consideration of the switching time overestimates the performance of the adsorption cooling system in terms of the Coefficient of performance (COP) and the Specific cooling power (SCP). On the other hand, if the switching time exceeds the optimal value, the performance of the adsorption cooling system is also reduced compared to that when using the optimal switching time. The dependency of the optimal switching times on various design parameters, such as the fin pitch, fin height and heating temperature, is also examined.

  4. Comparative Study of Textural Characteristics on Methane Adsorption for Carbon Spheres Produced by CO2 Activation

    Directory of Open Access Journals (Sweden)

    Wen Yang

    2014-01-01

    Full Text Available Resorcinol-formaldehyde resin polymer was used as raw material for preparation of carbon spheres. Samples were treated with CO2 flow at 850°C by varying activation times. The CO2 activation granted better pore development of pore structure. The experimental data of CH4 adsorption as a function of equilibrium pressure was fitted by Langmuir and Dubinin-Astakhov (D-A models. It was concluded that the high surface area and micropore volume of carbon spheres did unequivocally determine methane capacities. In addition, a thermodynamic study of the heat of adsorption of CH4 on the carbon spheres was carried out. Adsorption of CH4 on carbon spheres showed a decrease in the adsorption heat with CH4 occupancy, and the heat of adsorption fell from 20.51 to 12.50 kJ/mol at 298 K and then increased to a little higher values at a very high loading (>0.70, indicating that CH4/CH4 interactions within the adsorption layer became significant.

  5. Measurement of dynamic adsorption coefficient of Xe on coconut charcoal in CO2 streams by gas-solid chromatography

    International Nuclear Information System (INIS)

    This paper presents a method for measuring the dynamic adsorption coefficients of Xe on coconut charcoal II-2 in CO2 carrier streams by SP-2305E gas chromatograph with the thermal conductivity cell. The adsorption column is made of stainless steel (diameter 4 x 240 mm) packed with 60-80 mesh coconut charcoal II-2. The CO2 content in carrier streams is about 87%. Three groups of data of Xe dynamic adsorption coefficient were obtained at temperature 15.5 deg C, 31.5 deg C and 50.5 deg C by pulse injection respectively. Another group was obtained at temperature approx. 16 deg C by continueous injection. In addition, adsorption isotherms and adsorption isometrics were determined. In this experimental system, the adsorption heat of Xe on coconut charcoal II-2 is 2820 cal/mole

  6. The Synergistic Effect of Anionic Surfactant on Adsorption Enhancement of the Carotenoids Extract using Mesoporous Hydroxyapatite Nanoparticles

    Directory of Open Access Journals (Sweden)

    Supalak Kongsri

    2015-09-01

    Full Text Available Fish hydroxyapatite (FHAp was prepared from fish scale waste by alkaline heat treatment. The obtained nanoparticles (21 nm of FHAp with high crystallinity (89.5% were used as biocompatible adsorbent for an adsorption of plant carotenoids extract. For optimum conditions of batch adsorption study, experimental parameters including pH of solution, adsorbent dosage, an initial concentration of carotenoids, amount of sodium dodecyl sulfate (SDS, contact time and temperature were investigated in details. From the results, the carotenoids adsorption of the FHAp was drastically enhanced in the presence of SDS through their hydrophobic interactions between the carotenoids and the cationic element FHAp via the anionic head of SDS by electrostatic and ion-exchange interactions and surface complexation. The adsorption behaviors fitted well by pseudo-second order kinetic model and Freundlich adsorption isotherm. Thermodynamic data demonstrated that the adsorption behaviors of the carotenoids on the hydroxyapatite nanoparticles were spontaneously endothermic and physisorption process.

  7. Isothermal Adsorption Measurement for the Development of High Performance Solid Sorption Cooling System

    Science.gov (United States)

    Saha, Bidyut Baran; Koyama, Shigeru; Alam, K. C. Amanul; Hamamoto, Yoshinori; Akisawa, Atsushi; Kashiwagi, Takao; Ng, Kim Choon; Chua, Hui Tong

    Interest in low-grade thermal heat powered solid sorption system using natural refrigerants has been increased. However, the drawbacks of these adsorption systems are their poor performance. The objective of this paper is to improve the performance of thermally powered adsorption cooling system by selecting new adsorbent-refrigerant pairs. Adsorption capacity of adsorbent-refrigerant pair depends on the thermophysical properties (pore size, pore volume and pore diameter) of adsorbent and isothermal characteristics of the adsorbent-refrigerant pair. In this paper, the thermophysical properties of three types of silica gels and three types of pitch based activated carbon fibers are determined from the nitrogen adsorption isotherms. The standard nitrogen gas adsorption/desorption measurements on various adsorbents at liquid nitrogen of temperature 77.4 K were performed. Surface area of each adsorbent was determined by the Brunauer, Emmett and Teller (BET) plot of nitrogen adsorption data. Pore size distribution was measured by the Horvath and Kawazoe (HK) method. Adsorption/desorption isotherm results showed that all three carbon fibers have no hysteresis and had better adsorption capacity in comparison with those of silica gels.

  8. Studies on the Physical Adsorption Equilibria of Gases on Porous Solids over a Wide Temperature Range Spanning the Critical Region——Adsorption on Microporous Activated Carbon

    Institute of Scientific and Technical Information of China (English)

    周亚平; 白书培; 周理; 杨斌

    2001-01-01

    Adsorption equilibria of nitrogen and methane on microporous (<2 nm) activated carbon were measured for a wide temperature range (103—298 K) spanning the critical region. Information relating to Henry constants, the isosteric heat of adsorption, and the amnount of limiting adsorption were evaluated. All isotherms show type-I features for both sub- and supercritical temperatures. A new isotherm equation and a consideration for the importance of the effect of the adsorbed phase volume allow this kind of isotherms to be modeled satisfactorily. The model parameter of the saturated amount of absolute adsorpaon (nt0) equals the limiting adsorption amount (nlim), leaving the physical meaning of the latter clarified, and the exponent parameter (q) proves to be an appropriate index of surface heterogeneity.

  9. An identification study of vermiculites and micas. Adsorption of metal ions in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Alexandre-Franco, Maria; Gomez-Serrano, Vicente [Extremadura Univ., Badajoz (Spain). Dept. doe Quimica Organica e Inorganica; Albarran-Liso, Angel [Extremadura Univ., Badajoz (Spain). Escuela de Ingenieros Agronomos

    2011-02-15

    This study deals with the identification of vermiculite in the presence of mica. Three natural silicates were first subjected to expansion by rapid heat treated at 400 C. Then, the starting silicates and their derived heat-treated products were analyzed by X-ray diffraction, FT-IR spectroscopy, N{sub 2} adsorption at - 196 C, and helium density measurement. The adsorption of cadmium, chromium, and lead was also carried out. Two of the silicates are composed of mainly biotite and the other of biotite and vermiculite. In general, the results of X-ray diffraction, FT-IR spectroscopy, and helium density measurements are well in agreement. The heat treatment at 400 C has little effect on the chemical composition, structure, and texture of the silicates. The development of microporosity is small in the silicates. Surprisingly, the adsorption capacity toward chromium and lead is larger for the biotite silicate than for the vermiculite containing silicate. (author)

  10. Heat Waves

    Science.gov (United States)

    Heat Waves Dangers we face during periods of very high temperatures include: Heat cramps: These are muscular pains and spasms due ... that the body is having trouble with the heat. If a heat wave is predicted or happening… - ...

  11. A biological oil adsorption filter

    Energy Technology Data Exchange (ETDEWEB)

    Pasila, A. [University of Helsinki (Finland). Dept. of Agricultural Engineering and Household Technology

    2005-12-01

    A new oil adsorption method called adsorption filtration (AF) has been developed. It is a technology where by oil residues can be cleaned from water by running it through a simple filter made from freeze treated, dried, milled and then fragmented plant material. By choosing suitable plants and fragmentation sizes it is possible to produce filters, which pass water but adsorb oil. The aim of this study was to investigate the possibilities of manufacturing oil adsorbing filter materials from reed canary grass (Phalaris arundinacea), flax (Linum usitatissimum L.) or hemp fibre (Cannabis sativa L.). The oil (80 ml) was mixed with de-ionised water (200 ml) and this mixture was filtered through 10 or 20 g adsorption filters. Fine spring harvested hemp fibre (diameter less than 1 mm) and reed canary grass fragments adsorb 2-4 g of oil per gram of adsorption material compared to 1-3 g of water. Adsorption filtration is thus a novel way of gathering spilled oil in shallow coastal waters before the oil reaches the shore. (author)

  12. A COMPUTATIONAL AND EXPERIMENTAL STUDY OF METAL AND COVALENT ORGANIC FRAMEWORKS USED IN ADSORPTION COOLING

    Energy Technology Data Exchange (ETDEWEB)

    Jenks, Jeromy WJ; TeGrotenhuis, Ward E.; Motkuri, Radha K.; Paul, Brian; McGrail, B. Peter

    2015-07-09

    Metal-organic frameworks (MOFs) have recently attracted enormous interest over the past few years due to their potential applications in energy storage and gas separation. However, there have been few reports on MOFs for adsorption cooling applications. Adsorption cooling technology is an established alternative to mechanical vapor compression refrigeration systems. Adsorption cooling is an excellent alternative in industrial environments where waste heat is available. Applications also include hybrid systems, refrigeration, power-plant dry cooling, cryogenics, vehicular systems and building HVAC. Adsorption based cooling and refrigeration systems have several advantages including few moving parts and negligible power consumption. Key disadvantages include large thermal mass, bulkiness, complex controls, and low COP (0.2-0.5). We explored the use of metal organic frameworks that have very high mass loading and relatively low heats of adsorption, with certain combinations of refrigerants to demonstrate a new type of highly efficient adsorption chiller. An adsorption chiller based on MOFs suggests that a thermally-driven COP>1 may be possible with these materials, which would represent a fundamental breakthrough in performance of adsorption chiller technology. Computational fluid dynamics combined with a system level lumped-parameter model have been used to project size and performance for chillers with a cooling capacity ranging from a few kW to several thousand kW. In addition, a cost model has been developed to project manufactured cost of entire systems. These systems rely on stacked micro/mini-scale architectures to enhance heat and mass transfer. Presented herein are computational and experimental results for hydrophyilic MOFs, fluorophilic MOFs and also flourophilic Covalent-organic frameworks (COFs).

  13. Research and Development of a Small-Scale Adsorption Cooling System

    Science.gov (United States)

    Gupta, Yeshpal

    The world is grappling with two serious issues related to energy and climate change. The use of solar energy is receiving much attention due to its potential as one of the solutions. Air conditioning is particularly attractive as a solar energy application because of the near coincidence of peak cooling loads with the available solar power. Recently, researchers have started serious discussions of using adsorptive processes for refrigeration and heat pumps. There is some success for the >100 ton adsorption systems but none exists in the adsorption system was developed and its performance was compared with similar thermal-powered systems. Results showed that both the adsorption and absorption systems provide equal cooling capacity for a driving temperature range of 70--120 ºC, but the adsorption system is the only system to deliver cooling at temperatures below 65 ºC. Additionally, the absorption and desiccant systems provide better COP at low temperatures, but the COP's of the three systems converge at higher regeneration temperatures. To further investigate the viability of solar-powered heat pump systems, an hourly building load simulation was developed for a single-family house in the Phoenix metropolitan area. Thermal as well as economic performance comparison was conducted for adsorption, absorption, and solar photovoltaic (PV) powered vapor compression systems for a range of solar collector area and storage capacity. The results showed that for a small collector area, solar PV is more cost-effective whereas adsorption is better than absorption for larger collector area. The optimum solar collector area and the storage size were determined for each type of solar system. As part of this dissertation work, a small-scale proof-of-concept prototype of the adsorption system was assembled using some novel heat transfer enhancement strategies. Activated carbon and butane was chosen as the adsorbent-refrigerant pair. It was found that a COP of 0.12 and a cooling

  14. Host receptors for bacteriophage adsorption.

    Science.gov (United States)

    Bertozzi Silva, Juliano; Storms, Zachary; Sauvageau, Dominic

    2016-02-01

    The adsorption of bacteriophages (phages) onto host cells is, in all but a few rare cases, a sine qua non condition for the onset of the infection process. Understanding the mechanisms involved and the factors affecting it is, thus, crucial for the investigation of host-phage interactions. This review provides a survey of the phage host receptors involved in recognition and adsorption and their interactions during attachment. Comprehension of the whole infection process, starting with the adsorption step, can enable and accelerate our understanding of phage ecology and the development of phage-based technologies. To assist in this effort, we have established an open-access resource--the Phage Receptor Database (PhReD)--to serve as a repository for information on known and newly identified phage receptors. PMID:26755501

  15. The Density Functional Study of Thiophene Adsorption on Zeolite Clusters

    Institute of Scientific and Technical Information of China (English)

    Lü Renqing; Cao Zuogang; Shen Guoping

    2007-01-01

    The density functional theory and the cluster model methods have been employed to investigate the interactions between thiophene and the HZSM-5 zeolites. The molecular complexes formed by the adsorption of thiophene on silanol H3SiOH with two coordination forms, and the model Br(o)nsted acid sites of zeolite cluster H3Si(OH)Al(OH)2SiH3 upon the interaction with thiophene have been comparatively studied.Full optimization and frequency analysis of all cluster models have been carried out using the B3LYP hybrid method at 6-31G basis level for hydrogen atoms and 6-31+G(d) basis set level for silicon, aluminum, oxygen,carbon, and sulfur atoms. The calculated results showed that the nature of interactions leading to the formation of the zeolite cluster-thiophene and silanol-thiophene complexes was associated with the van der Waals force confirmed by a slight change of geometric structures and properties. Thiophene is adsorbed on bridging hydroxyl group prior to silanol OH group judging from the magnitude of adsorption heat. The cluster model calculation reproducing the experimental prediction to form the experimental adsorption spectra of thiophene in HZSM-5 zeolite has illustrated the validity of the proposed adsorption models.

  16. Monomer Adsorption-Desorption Processes

    Institute of Scientific and Technical Information of China (English)

    KE Jian-Hong; LIN Zhen-Quan; CHEN Xiao-Shuang

    2009-01-01

    We propose an adsorption-desorption model for a deposit growth system, in which the adsorption and desorption of particles coexist. By means of the generalized rate equation we investigate the cluster (island) size distribution in the dynamic equilibrium state. The results show that the evolution behaviour of the system depends crucially on the details of the rate kernels. The cluster size distribution can take the ecale-frse power-law form in some cases, while it grows exponentially with size in other cases.

  17. Theoretical insight of adsorption cooling

    KAUST Repository

    Chakraborty, Anutosh

    2011-06-03

    This letter proposes and presents a thermodynamic formulation to calculate the energetic performances of an adsorption cooler as a function of pore widths and volumes of solid adsorbents. The simulated results in terms of the coefficient of performance are validated with experimental data. It is found from the present analysis that the performance of an adsorption cooling device is influenced mainly by the physical characteristics of solid adsorbents, and the characteristics energy between the adsorbent-adsorbate systems. The present study confirms that there exists a special type of silicagel having optimal physical characteristics that allows us to obtain the best performance.

  18. Performance Evaluation of a Continuous Operation Adsorption Chiller Powered by Solar Energy Using Silica Gel and Water as the Working Pair

    OpenAIRE

    Hassan Zohair Hassan

    2014-01-01

    In the present study, dynamic analysis and performance evaluation of a solar-powered continuous operation adsorption chiller are introduced. The adsorption chiller uses silica gel and water as the working pair. The developed mathematical model represents the heat and mass transfer within the reactor coupled with the energy balance of the collector plate and the glass cover. Moreover, a non-equilibrium adsorption kinetic model is taken into account by using the linear driving force equation. T...

  19. Evaluation and Treatment of Coal Fly Ash for Adsorption Application

    Directory of Open Access Journals (Sweden)

    Samson Oluwaseyi BADA

    Full Text Available Many researchers had investigated fly ash as an adsorbent for the uptake of organic compounds from petrochemical waste effluents. The availability, inexpensive and its adsorption characteristic had made it an alternative media for the removal of organic compounds from aqueous solution. The physical property of South African Coal Fly Ash (SACFA was investigated to determine its adsorption capability and how it can be improved. Chemical treatment using 1M HCl solution in the ratio of (1 g fly ash to (2 ml of acid was used and compared with untreated heat-treated samples. The chemically treated fly ash has a higher specific surface area of 5.4116 m2/g than the heat-treated fly ash with 2.9969 m2/g. More attention had to be given to the utilization of SACFA for the treatment of wastewaters containing organic compounds through the application of Liquid phase adsorption process that was considered as an inexpensive and environmentally friendly technology.

  20. Adsorption of Organics from Domestic Water Supplies.

    Science.gov (United States)

    McGuire, Michael J.; Suffet, Irwin H.

    1978-01-01

    This article discusses the current state of the art of organics removal by adsorption. Various theoretical explanations of the adsorption process are given, along with practical results from laboratory, pilot-scale, and full-scale applications. (CS)

  1. Microstructure-Dependent Gas Adsorption: Accurate Predictions of Methane Uptake in Nanoporous Carbons

    Energy Technology Data Exchange (ETDEWEB)

    Ihm, Yungok [University of Tennessee (UTK) and Oak Ridge National Laboratory (ORNL); Cooper, Valentino R [ORNL; Gallego, Nidia C [ORNL; Contescu, Cristian I [ORNL; Morris, James R [ORNL

    2014-01-01

    We demonstrate a successful, efficient framework for predicting gas adsorption properties in real materials based on first-principles calculations, with a specific comparison of experiment and theory for methane adsorption in activated carbons. These carbon materials have different pore size distributions, leading to a variety of uptake characteristics. Utilizing these distributions, we accurately predict experimental uptakes and heats of adsorption without empirical potentials or lengthy simulations. We demonstrate that materials with smaller pores have higher heats of adsorption, leading to a higher gas density in these pores. This pore-size dependence must be accounted for, in order to predict and understand the adsorption behavior. The theoretical approach combines: (1) ab initio calculations with a van der Waals density functional to determine adsorbent-adsorbate interactions, and (2) a thermodynamic method that predicts equilibrium adsorption densities by directly incorporating the calculated potential energy surface in a slit pore model. The predicted uptake at P=20 bar and T=298 K is in excellent agreement for all five activated carbon materials used. This approach uses only the pore-size distribution as an input, with no fitting parameters or empirical adsorbent-adsorbate interactions, and thus can be easily applied to other adsorbent-adsorbate combinations.

  2. Equilibrium and kinetic analysis of CO2-N2 adsorption separation by concentration pulse chromatography.

    Science.gov (United States)

    Li, Peiyuan; Tezel, F Handan

    2007-09-01

    CO2 and N(2) adsorption kinetics and equilibrium behaviours have been studied with silicalite, NaY and 13X by using concentration pulse chromatography for the separation of these gases in the present study. Adsorption Henry's Law constants, the heat of adsorption values, micropore diffusion coefficients and corresponding activation energies are determined experimentally and the three different mass transfer mechanisms are discussed. From the equilibrium data, the corresponding separation factors are obtained for the adsorption separation processes. The heat of adsorption values as well as the Henry's Law adsorption equilibrium constants of CO(2) are much higher than those of N(2) for all the adsorbents studied. 13X, NaY and silicalite all have good separation factors for CO(2)/N(2) system based on equilibrium processes. The order of the equilibrium separation factors is 13X (Ceca)>13X (Zeochem)>NaY (UOP)>silicalite (UOP). Equilibrium selectivity favours CO(2) over N(2). Micropore diffusion resistance is the definite dominant mass transfer mechanism for CO(2) with silicalite and NaY.

  3. Effect of an electrostatic field on gas adsorption and diffusion in tectonic coal

    Institute of Scientific and Technical Information of China (English)

    Jian Kuo; Lei Dongji; Fu Xuehai; Zhang Yugui; Li Hengle

    2015-01-01

    The characteristics of adsorption, desorption, and diffusion of gas in tectonic coal are important for the prediction of coal and gas outbursts. Three types of coal samples, of which both metamorphic grade and degree of damage is different, were selected from Tongchun, Qilin, and Pingdingshan mines. Using a series of experiments in an electrostatic field, we analyzed the characteristics of gas adsorption and diffusion in tectonic coal. We found that gas adsorption in coal conforms to the Langmuir equation in an electrostatic field. Both the depth of the adsorption potential well and the coal molecular electroneg-ativity increases under the action of an electrostatic field. A Joule heating effect was caused by changing the coal–gas system conductivity in an electrostatic field. The quantity of gas adsorbed and DP result from competition between the depth of the adsorption potential well, the coal molecular electronegativ-ity, and the Joule heating effect. DP peaks when the three factors control behavior equally. Compared with anthracite, the impact of the electrostatic field on the gas diffusion capacity of middle and high rank coals is greater. Compared with the original coal, the gas adsorption quantity, DP, and the gas diffusion capacity of tectonic coal are greater in an electrostatic field. In addition, the smaller the particle size of tectonic coal, the larger the DP.

  4. ADSORPTION MALACHITE GREEN ON NATURAL ZEOLITE

    Directory of Open Access Journals (Sweden)

    Eko Ariyanto

    2012-02-01

    Full Text Available A natural zeolite was employed as adsorbent for reducing of malachite green from aqueous solution. A batch system was applied to study the adsorption of malachite green in single system on natural zeolite. The adsorption studies indicate that malachite green in single component system follows the second-order kinetics and the adsorption is diffusion process with two stages for malachite green. Malachite green adsorption isotherm follows the Langmuir model.

  5. Calorimetric measurements of the energetics of Pb adsorption and adhesion to Mo(100)

    International Nuclear Information System (INIS)

    The heat of adsorption of Pb on Mo(100) at 300 K has been measured calorimetrically using a single-crystal adsorption calorimeter and a pulsed atomic beam of Pb vapor. The heat of adsorption decreases with coverage in the first monolayer as (q0-q1θ-q2θ2), where q0=335.4kJ/mol, q1=65.0kJ/mol, and q2=69.8kJ/mol, indicating a heat of adsorption for an isolated Pb adatom of 335.4 kJ/mol, but with a repulsive interaction between two Pb adatoms centered in nearest-neighbor sites of 27.9 kJ/mol, and a relaxation of this repulsion of 11.6 kJ/mol by an isolated pair if unperturbed by third neighbors (that would otherwise prevent the adatoms from moving slightly off site-center to achieve this relaxation). In the second monolayer, the adsorption heat is nearly constant at ∼192.7kJ/mol, close to the enthalpy of sublimation of Pb. It decreases at ∼2ML by ∼7kJ/mol, which can be attributed to the conversion from layer-by-layer to three-dimensional island growth at ∼2ML. The initial islands are tiny and therefore adsorbing Pb atoms more weakly (bonding to fewer nearest neighbors). This is supported by Auger electron spectroscopy measurements. As the islands grow in size and their surfaces get flatter, the number of neighbors increases until the heat of adsorption above ∼6ML reaches a steady value of 191.5 kJ/mol, within 2% of the reported enthalpy of sublimation of Pb at 300 K (195.2 kJ/mol). copyright 1997 The American Physical Society

  6. Adsorption theory for polydisperse polymers.

    NARCIS (Netherlands)

    Roefs, S.P.F.M.; Scheutjens, J.M.H.M.; Leermakers, F.A.M.

    1994-01-01

    Most polymers are polydisperse. We extend the self-consistent field polymer adsorption theory due to Scheutjens and Fleer to account for an arbitrary polymer molecular weight distribution with a cutoff chain length Nmax. In this paper, the treatment is restricted to homopolymers. For this case a ver

  7. Adsorption of Levofloxacin to Goethite

    NARCIS (Netherlands)

    Qin, Xiaopeng; Liu, Fei; Zhao, Long; Hou, Hong; Wang, Guangcai; Li, Fasheng; Weng, Liping

    2016-01-01

    Batch experiments were conducted to investigate the adsorption of a widely used fluoroquinolone antibiotic levofloxacin (LEV) to goethite and effects of nitrate, sulfate, small organic acids, and humic acid (HA). The concentrations of LEV and small organic acids in single systems or mixtures were

  8. Scaling Laws of Polyelectrolyte Adsorption

    OpenAIRE

    Borukhov, I.; Andelman, D.; Orland, H.

    1997-01-01

    Adsorption of charged polymers (polyelectrolytes) from a semi-dilute solution to a charged surface is investigated theoretically. We obtain simple scaling laws for (i) the amount of polymer adsorbed to the surface, Gamma, and (ii) the width of the adsorbed layer D, as function of the fractional charge per monomer p and the salt concentration c_b. For strongly charged polyelectrolytes (p

  9. Modeling of a Novel Desorption Cycle by Dielectric Heating

    Science.gov (United States)

    Kumja, M.; Ng, K. C.; Yap, C.; Yanagi, H.; Koyama, S.; Saha, B. B.; Chakraborty, A.

    The paper presents an adsorption cycle for cooling using the dielectric heating method for the regeneration process. Conventional adsorption (AD) chillers employs thermally driven processes for desorption and adsorption where the thermal resistances are high, resulting in a relatively low chiller COP. In this paper, dielectric heating is used to irradiate where the microwave power vibrates the dipole structure of the molecules. Owing to the direct method of energy delivery, the heating process is thus efficient, contributing to an increase in the chiller performance and the COPs. We present the modeling and simulations of the adsorption-desorption cycle in an AD chiller, demonstrating a significant improvement in chiller performance by as much as three folds.

  10. Effect of Thermal Treatment on Fracture Properties and Adsorption Properties of Spruce Wood

    Directory of Open Access Journals (Sweden)

    Takato Nakano

    2013-09-01

    Full Text Available The effect of thermal treatment on spruce is examined by analyzing the fracture and hygroscopic properties. Specimens were heated at temperatures within the range 120–200 °C for 1 h. Fracture energy was measured using a single-edge notched bending test and the strain-softening index was estimated by dividing the fracture energy by the maximum load. Adsorption properties were estimated using adsorption isotherms. Fiber saturation points (FSPs were estimated by extrapolating the moisture adsorption isotherm curve. Langmuir’s adsorption coefficient and number of adsorption sites were obtained using Langmuir’s theory and the Hailwood-Horrobin theory, respectively. The fracture energy, FSPs, and specimen weights decreased at temperatures higher than 150 °C, but the critical point for the strain-softening index and the number of adsorption sites was shown to be 180 °C. We hypothesize that the fracture energy and FSP depend on the chemical structure of the cell wall, whereas the strain-softening behavior may be influenced by the number of adsorption sites, and in turn the number of hydrogen bonds in hemicellulose.

  11. Methane adsorption in nanoporous carbon: the numerical estimation of optimal storage conditions

    Science.gov (United States)

    Ortiz, L.; Kuchta, B.; Firlej, L.; Roth, M. W.; Wexler, C.

    2016-05-01

    The efficient storage and transportation of natural gas is one of the most important enabling technologies for use in energy applications. Adsorption in porous systems, which will allow the transportation of high-density fuel under low pressure, is one of the possible solutions. We present and discuss extensive grand canonical Monte Carlo (GCMC) simulation results of the adsorption of methane into slit-shaped graphitic pores of various widths (between 7 Å and 50 Å), and at pressures P between 0 bar and 360 bar. Our results shed light on the dependence of film structure on pore width and pressure. For large widths, we observe multi-layer adsorption at supercritical conditions, with excess amounts even at large distances from the pore walls originating from the attractive interaction exerted by a very high-density film in the first layer. We are also able to successfully model the experimental adsorption isotherms of heterogeneous activated carbon samples by means of an ensemble average of the pore widths, based exclusively on the pore-size distributions (PSD) calculated from subcritical nitrogen adsorption isotherms. Finally, we propose a new formula, based on the PSD ensemble averages, to calculate the isosteric heat of adsorption of heterogeneous systems from single-pore-width calculations. The methods proposed here will contribute to the rational design and optimization of future adsorption-based storage tanks.

  12. Study of a silica gel-water based dual mode adsorption chiller

    Directory of Open Access Journals (Sweden)

    Khairul Habib

    2016-04-01

    Full Text Available This article presents analytical investigation results on the performance of dual-mode multi-bed adsorption cooling systems using silica gel-water pair. This novel adsorption chiller utilizes effectively low-temperature solar or waste heat sources of temperature between 40 and 85°C. Two operation modes are possible for the advanced chiller. The first operation mode will be to work as a highly efficient conventional chiller where the driving source temperature is between 60 and 85°C. The second operation mode will be to work as an advanced two-stage adsorption chiller where the available driving source temperature is very low (below 60°C. In the present work, a simulation study of a dualmode, four-bed silica gel-water adsorption chiller is undertaken. For a driving source temperature above 60°C, the chiller functions as a single stage four-bed adsorption chiller. However, the chiller works as a two stage four-bed adsorption chiller when the driving source temperature falls within the range from 40°C to 60°C. With a cooling water temperature of 30°C. It has been found that this dual mode adsorption chiller is capable to provide cooling throughout the year via measuring the coefficient of performance and the cooling capacity of the system.

  13. ADSORPTION OF PITCH AND STICKIES ON MAGNESIUM ALUMINUM HYDROXIDES TREATED AT DIFFERENT TEMPERAURES

    Directory of Open Access Journals (Sweden)

    Guodong Li

    2011-04-01

    Full Text Available Magnesium aluminum hydroxides (MAH of nitrate and carbonate forms were prepared by co-precipitation, dried at different temperatures, and employed as an adsorbent for pitch and stickies in papermaking. Results indicated that MAH that had been heat-treated had higher adsorption capacity to model pitch and stickies at neutral pH. Low-temperature-dried magnesium aluminum hydroxides of nitrate form (MAH-NO3 had higher adsorption capacity to model pitch and model stickies than those of the carbonate form (MAH-CO3. Increasing the drying temperature of MAH reduced the difference of adsorption capacity between MAH-NO3 and MAH-CO3. Higher-temperature-dried magnesium aluminum hydroxides also showed higher adsorption capacity to model pitch and stickies when the drying temperature was lower than 550 oC. MAH displayed higher adsorption capacity while a lower initial adsorption rate of model stickies than of model pitch. The model pitch and stickies were adsorbed on MAH significantly by charge neutralization and distributed mainly on the surface of the platelets of magnesium aluminum hydroxides. The experimental isothermal adsorption data of model pitch and stickies on MAH dried at 500 oC fit well to the Freundlich and Dubinin–Radushkevich isotherm equations.

  14. Adsorption Models and Structural Characterization for Activated Carbon Fibers

    Institute of Scientific and Technical Information of China (English)

    CHEN Chuan-juan; WANG Ru-zhu; OLIVEIRA R.G.; HU Jin-qiang

    2009-01-01

    The nitrogen adsorption isotherms at 77.69 K were measured for two samples of activated carbon fibers and their microstructures were investigated. Among established isotherm equations, the Dubinin-Radushkevich equation showed the best agreement with the experimental data, while the Langmuir equation showed a large deviation when employed at low relative pressures. The MP method, t-method and αs-method were used to analyze the pore size distribution. The calculated average pore widths and BET (Brunauer-Emmett-Teller) surface areas for the sample A-13 were 0.86 nm and 1 286.60 m2/g, while for the sample A-16, they were 0.82 nm and 1 490.64 m2/g. The sample with larger pore width was more suitable to be used as additive in chemical heat pumps, while the other one could be used as adsorbent in adsorption refrigeration systems.

  15. WATER ADSORPTION AND DESORPTION ISOTHERMS ON MILK POWDER: II. WHOLE MILK

    Directory of Open Access Journals (Sweden)

    Edgar M. Soteras

    2014-03-01

    Full Text Available The aim of this research was the determination of adsorption and desorption isotherms of cow whole milk powder. The experiments have been carried out at 15, 25 and 40 ºC, in ranges of moisture and water activity characteristic of normal conditions in which the processes of drying, packaging and storage are developed. By studying the influence of the temperature on the experimental plots, the isosteric adsorption heat was determined. Experimental data were correlated to the referential model of Guggenheim, Anderson and Boer (GAB. For both, adsorption and desorption, a good model fit was observed. The isotherms showed very similar shapes between them and, by comparing adsorption and desorption isotherms, the phenomenon of hysteresis was confirmed.

  16. The Grand Ensemble of Subsystems: Applications to Fitting Single-Component Adsorption Data

    CERN Document Server

    Mosquera, Martin A

    2009-01-01

    In this work, it is reviewed the cell model of adsorption by using the small system grand ensemble method. Under the common assumption that the adsorbate phase is divided into identical and weakly-interacting subsystems, it is suggested that the general multiparametric isotherm that arise from the theory may be used to fit the experimental data of adsorption of gases and vapours on microporous adorbents (type I isotherm), even though these present heterogeneties like pore size distribution. A simplified isotherm that reduces the number of adjustable parameters with respect to the general isotherm is proposed. Both isotherms, due to their relative high accuracy, can be used to estimate thermodynamical properties like isosteric and differential heats of adsorption. Also, a simple method is presented for systems that show an apparent variation in the coverage limit as function of temperature; for several systems, this method reduces the fitting deviations. Finally, several applications to fitting data of adsorpt...

  17. Adsorption properties of aluminium oxide modified with palladium, gold, and cerium oxide nanoparticles

    Science.gov (United States)

    Lanin, S. N.; Bannykh, A. A.; Vinogradov, A. E.; Kovaleva, N. V.; Lanina, K. S.; Nikolaev, S. A.

    2016-07-01

    The adsorption properties of nanocomposites based on γ-Al2O3 modified with CeO x , Au/CeO x , and Pd/CeO x nanoparticles with contents of deposited metals ranging from 0.07 to 1.71 wt % are investigated by means of dynamic sorption method. n-Alkanes (C6-C8), acetonitrile, diethyl ether, tetrahydrofuran, and dioxane are used as test adsorbates. Adsorption isotherms are measured, and the isosteric heats of adsorption of a number of test adsorbates are calculated. Electron-donor and electron-acceptor characteristics of the surfaces of γ-Al2O3-based nanocomposites are estimated. It is shown that Au(0.1%)/CeO x (0.07%)/γ-Al2O3 nanocomposite, which has the lowest content of nanoparticles of the deposited metals, has the highest adsorption activity.

  18. Comparative Adsorption of Saturated and Unsaturated Fatty Acids at the Iron Oxide/Oil Interface.

    Science.gov (United States)

    Wood, Mary H; Casford, M T; Steitz, R; Zarbakhsh, A; Welbourn, R J L; Clarke, Stuart M

    2016-01-19

    A detailed comparison of the adsorption behavior of long straight chain saturated and unsaturated fatty acids at the iron oxide/oil interface has been considered using a combination of surface study techniques. Both depletion isotherms and polarized neutron reflectometry (PNR) show that the extent of adsorption decreases as the number of double bonds in the alkyl chains increases. Sum frequency generation spectroscopic measurements demonstrate that there is also an increase in chain disorder within the adsorbed layer as the unsaturation increases. However, for the unsaturated analogues, a decrease in peak intensity is seen for the double bond peak upon heating, which is thought to arise from isomerization in the surface-bound layer. The PNR study of oleic acid adsorption indicates chemisorbed monolayer adsorption, with a further diffuse reversible adsorbed layer formed at higher concentrations. PMID:26707597

  19. Absorption and adsorption chillers applied to air conditioning systems

    Science.gov (United States)

    Kuczyńska, Agnieszka; Szaflik, Władysław

    2010-07-01

    This work presents an application possibility of sorption refrigerators driven by low temperature fluid for air conditioning of buildings. Thermodynamic models were formulated and absorption LiBr-water chiller with 10 kW cooling power as well as adsorption chiller with silica gel bed were investigated. Both of them are using water for desorption process with temperature Tdes = 80 °C. Coefficient of performance (COP) for both cooling cycles was analyzed in the same conditions of the driving heat source, cooling water Tc = 25 °C and temperature in evaporator Tevap = 5 °C. In this study, the computer software EES was used to investigate the performance of absorption heat pump system and its behaviour in configuration with geothermal heat source.

  20. ADSORPTION OF TANNIN FROM AQUEOUS SOLUTION ONTO MACROPOROUS CROSSLINKED POLY(N—VINYL—ACETAMIDE)VIA HYDROGEN BONDING

    Institute of Scientific and Technical Information of China (English)

    XUMancai; XUMingcheng; 等

    2000-01-01

    A Strongly hydrophilic hydrogen-bonding adsorbent-macroporous crosslinked Poly(Nvinyl-acetamide),which contain both hydrogen bond acceptor and donator,was synthesized.Adsorption mechanism and dynamic adsorption of tannin from aqueous solution onto the adsorbent were investigated.Most of the differntial adsorption heats for various adsorption capacities calculated from the adsorption isotherms according to Clapeyron-Clausius equation lay in the range of hydrogen bond energy(8-50J/mol).Adsorption properties of the adsorbent were studied in detail.These results revealed a hydrogen bonding mechanism of the adsorption of tannin from aqueous solution onto the adsorbent.The result of the dynamic adsorption of tanning with the initial concentration under 600mg/L showed that the adsorption rate of tannin exceeded 90% when the flow rate was 3BV/h and the effluent volume reached 100BV.Therefore,the developed hydrogen-bonding adsorbent-macroporous crosslinked poly(N-vinyl-acetamide)-is an excellent adsorbent to remove tannin from extract of natural products,and has great value in application.

  1. Enthalpy contributions to adsorption of highly charged lysozyme onto a cation-exchanger under linear and overloaded conditions.

    Science.gov (United States)

    Silva, G L; Marques, F S; Thrash, M E; Dias-Cabral, A C

    2014-07-25

    An investigation of the adsorption mechanism of lysozyme onto carboxymethyl cellulose (CMC) was conducted using flow calorimetry and adsorption isotherm measurements. This study was undertaken to provide additional insight into the underlying mechanisms involved in protein adsorption that traditional approaches such isotherm measurements or van't Hoff analysis can't always provide, particularly when protein adsorption occurs under overloaded conditions. Lysozyme and CMC were selected for this study because the characteristics of the protein and the adsorbent are well known, hence, allowing the focus of this work to be on the driving forces influencing adsorption. Calorimetry results have showed that lysozyme adsorption onto CMC produced both exothermic and endothermic heats of adsorption. More specifically flow calorimetry data coupled with peak deconvolution methods illustrated a series of chronological events that included dilution, primary protein adsorption, rearrangement of surface proteins and a secondary adsorption of lysozyme molecules. The observations and conclusions derived from the experimental work presented in our figures and tables were developed within the mechanistic framework proposed by Lin et al., J. Chromatogr. A. 912 (2001) 281.

  2. Adsorption behavior of bisphenol-A and diethyl phthalate onto bubble surface in nonfoaming adsorptive bubble separation

    OpenAIRE

    Maruyama, Hideo; Seki, Hideshi; Matsukawa, Yasuhiro; Suzuki, Akira; INOUE, Norio

    2008-01-01

    To clarify adsorption equilibrium relationship at liquid-atmosphere interface, adsorption behavior of bisphenol-A (BPA) and diethyl phthalate (DEP) onto bubble surface was studied by using nonfoaming adsorptive bubble separation (NFBS) technique. The adsorption isotherm of BPA and DEP were obtained experimentally. The experimental results showed that adsorption equilibrium of BPA and DEP on bubble surface followed Langmuir's adsorption isotherm. Two adsorption parameters, the adsorption equil...

  3. Heat Stress

    Science.gov (United States)

    ... Publications and Products Programs Contact NIOSH NIOSH HEAT STRESS Recommend on Facebook Tweet Share Compartir NEW Criteria ... hot environments may be at risk of heat stress. Exposure to extreme heat can result in occupational ...

  4. Structure optimization and performance experiments of a solar-powered finned-tube adsorption refrigeration system

    International Nuclear Information System (INIS)

    Highlights: • New-structure finned-tube adsorption bed for enhancing heat and mass transfer. • Temperatures on different parts of the adsorption tubes differ little. • Maximum COP of 0.122 and maximum daily ice-making of 6.5 kg are achieved by experiments. • Cooling efficiency of system with valve control higher than that without valve control. - Abstract: A large-diameter aluminum-alloy finned-tube absorbent bed collector was designed and optimized by enhancing the heat and mass transfer in the collector. The collection efficiency of the adsorbent bed collector was between 31.64% and 42.7%, and the temperature distribution in the absorbent bed was relatively uniform, beneficial to adsorption/desorption of the adsorbate in the absorbent bed. A solar-powered solid adsorption refrigeration system with the finned-tube absorbent bed collector was built. Some experiments corresponding to the adsorption/desorption process with and without a valve control were conducted in four typical weather conditions: sunny with clear sky, sunny with partly cloudy sky, cloudy sky and overcast sky. Activated carbon–methanol was utilized as the working pair for adsorption refrigeration in the experiments. The experiments achieved the maximum COP of 0.122 and the maximum daily ice-making of 6.5 kg. Under the weather conditions of sunny with clear sky, sunny with partly cloudy sky, and cloudy sky, ice-making phenomenon were observed. Even in the overcast-sky weather condition, the cooling efficiency of the system still reached 0.039 when the total solar radiation was 11.51 MJ. The cooling efficiency of the solar-powered adsorption refrigeration system with a valve control in the adsorption/desorption process was significantly higher than that without a valve control

  5. Adsorption from solutions of non-electrolytes

    CERN Document Server

    Kipling, J J

    1965-01-01

    Adsorption from Solutions of Non-Electrolytes provides a general discussion of the subject, which has so far been given little or no attention in current textbooks of physical chemistry. A general view of the subject is particularly needed at a time when we wish to see how far it will be possible to use theories of solutions to explain the phenomena of adsorption. The book opens with an introductory chapter on the types of interface, aspects of adsorption from solution, types of adsorption, and classification of systems. This is followed by separate chapters on experimental methods, adsorption

  6. Study on the Irreversible Thermodynamics of a Marine Engine Exhaust-powered Adsorption Refrigerating System

    Institute of Scientific and Technical Information of China (English)

    XIE Yingchun; MEI Ning; XU Zhen

    2006-01-01

    This study investigates the heat and mass transfer mechanism of a marine engine exhaust-powered adsorption refrigerating system by using irreversible thermodynamics. The equations of entropy-production rate and the linear phenomenological equations of thermodynamic flux and force are established. The conventional experimental facilities of unit tube are developed and the phenomenological coefficients are obtained by fitting the experimental data. It is concluded that the thermodynamic process in the adsorbent bed is determined by the coupling effect of the heat and mass transfer; furthermore, the mass transfer is determined by the heat transfer. Taking some measures to increase heat transfer can improve the performance of the adsorption refrigerating system. The conclusions presented in this paper may be of value to the engineering applications of the system.

  7. Study on the irreversible thermodynamics of a marine engine exhaust-powered adsorption refrigerating system

    Science.gov (United States)

    Xie, Yingchun; Mei, Ning; Xu, Zhen

    2006-04-01

    This study investigates the heat and mass transfer mechanism of a marine engine exhaust-powered adsorption refrigerating system by using irreversible thermodynamics. The equations of entropy-production rate and the linear phenomenological equations of thermodynamic flux and force are established. The conventional experimental facilities of unit tube are developed and the phenomenological coefficients are obtained by fitting the experimental data. It is concluded that the thermodynamic process in the adsorbent bed is determined by the coupling effect of the heat and mass transfer; furthermore, the mass transfer is determined by the heat transfer. Taking some measures to increase heat transfer can improve the performance of the adsorption refrigerating system. The conclusions presented in this paper may be of value to the engineering applications of the system.

  8. CO2 adsorption on single-walled dahlia-like carbon nanohorns

    Science.gov (United States)

    Bohorquez, Jaime; Krungleviciute, Vaiva; Migone, Aldo; Yudasaka, Masako; Iijima, Sumio

    2010-03-01

    The adsorption of CO2 on spherical aggregates of as-produced (i.e., closed) dahlia-like single-walled carbon nanohorns was investigated. We conducted volumetric adsorption measurements at five temperatures between 147 and 180 K. The shape of the isotherms for CO2 is very different from those measured with neon and CF4. For CO2 there is a single, smeared step in the adsorption data between the lowest coverages and saturation. By contrast, Ne and CF4 show two distinct substeps on the same substrate. The isosteric heat was also obtained and its dependence on coverage also showed an usual behavior: it increased with increasing coverage. The isosteric heat decreases with coverage both for Ne and CF4. The stronger intermolecular interactions present for CO2 probably are responsible for this adsorbate's unusual behavior. Comparisons with the behavior reported in the literature for CO2 on SWNTs, which shows similar unusual characteristics, will also be made.

  9. Study of Solar Driven Silica gel-Water based Adsorption Chiller

    Science.gov (United States)

    Habib, K.; Assadi, M. K.; Zainudin, M. H. B.

    2015-09-01

    In this study, a dynamic behaviour of a solar powered single stage four bed adsorption chiller has been analysed designed for Malaysian climate. Silica gel and water have been used as adsorbent-refrigerant pair. A simulation program has been developed for modeling and performance evaluation of the chiller using the meteorological data of Kuala Lumpur. The optimum cooling capacity and coefficient of performance (COP) are calculated in terms of adsorption/desorption cycle time and regeneration temperature. Results indicate that the chiller is feasible even when low temperature heat source is available. Results also show that the adsorption cycle can achieve a cooling capacity of 14 kW when the heat source temperature is about 85°C.

  10. Experimental adsorption equilibrium study and comparison of zeolite with water and ethanol for cooling systems

    Institute of Scientific and Technical Information of China (English)

    MAIGA Abdoulaye Siddeye; CHEN Guang-ming; WANG Qin

    2007-01-01

    Two adsorption refrigeration working pairs of zeolite with water and ethanol were studied and the parameters of Dubinin-Astakhov model were regressed using the experimental data of equilibrium. The coefficient of heterogeneity varied from 1.305 to 1.52 for the zeolite-water pair and from 1.73 to 2.128 for zeolite-ethanol pair. The maximum adsorption capacity varied from 0.315 to 0.34 for zeolite-water and 0.23 to 0.28 for zeolite-ethanol, respectively. The results showed that the zeolite-water pair is suitable for solar energy cooling not only because of the high latent heat of vaporization of water but also because of the better equilibrium performance. On the other hand, zeolite-ethanol gives a high adsorption capacity at high regeneration temperature, which means it can be used in heat engine systems like buses and cars.

  11. ADSORPTION OF PHENOL FROM ITS AQUEOUS SOLUTIONS USING ACTIVATED LIGNITE COALS

    Directory of Open Access Journals (Sweden)

    Mehmet MAHRAMANLIOĞLU

    1998-01-01

    Full Text Available In this work the adsorption and recovery of phenol from its aqueous solutions has been the main purpose. The lignite coals obtained from Yeniköy, İstanbul, have been chosen as the adsorbent matter. The sample taken has first been activated. The activation of lignite samples were carried out by either heating with sulphuric acid or through destillation in an inert atmosphere. Aqueous solutions of phenol of various concentrations have been used in the adsorption process. It was seen that the adsorption results were in perfect correlation with the Langmuir isotherm. As a result, it has been proved that these lignite coals which have been used for heating purposes till today, can also be used as a good adsorbent agent. Furthermore, it has been observed that phenol can be removed some waste waters and its recovery process can even be possible under certain conditions.

  12. Adsorption of Phosphate on Variable Charge Soils

    Institute of Scientific and Technical Information of China (English)

    HUGUO-SONG; ZHUZU-XIANG; 等

    1992-01-01

    The study about the adsorption of phosphate on four variable charge soils and some minerals revealed that two stage adsorption appeared in the adsorption isothems of phosphate on 4 soils and there was a maximum adsorption on Al-oxide-typed surfaces between pH 3.5 to pH 5.5 as suspension pH changed from 2 to 9,but the adsorption amount of phosphate decreased continually as pH rose on Fe-oxide typed surfaces.The adsorption amount of phosphate and the maximum phosphate adsorption pH decreased in the order of yellow-red soil> lateritic red soil> red soil> paddy soil,which was coincided with the content order of amorphous Al oxide.The removement of organic matter and Fe oxide made the maximum phosphate adsorption pH rise from 4.0 to 5.0 and 4.5,respectively.The desorption curves with pH of four soils showed that phosphate desorbed least at pH 5.Generally the desorption was contrary to the adsorption with pH changing.There was a good accordance between adsorption or desorption and the concentration of Al in the suspension.The possible mechanisms of phosphate adsorption are discussed.

  13. Phosphate adsorption on lanthanum loaded biochar.

    Science.gov (United States)

    Wang, Zhanghong; Shen, Dekui; Shen, Fei; Li, Tianyu

    2016-05-01

    To attain a low-cost and high-efficient phosphate adsorbent, lanthanum (La) loaded biochar (La-BC) prepared by a chemical precipitation method was developed. La-BC and its pristine biochar (CK-BC) were comparatively characterized using zeta potential, BET surface area, scanning electron microscopy/energy dispersive spectrometer (SEM-EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FT-IR). The adsorption ability and the mechanisms during adsorption process for the La-BC samples were also investigated. La loaded on the surface of biochar can be termed as La-composites (such as LaOOH, LaONO3 and La(OH)3), leading to the decrease of negative charge and surface area of biochar. La-BC exhibited the high adsorption capacity to phosphate compared to CK-BC. Adsorption isotherm and adsorption kinetic studies showed that the Langmuir isotherm and second order model could well describe the adsorption process of La-BC, indicating that the adsorption was dominated by a homogeneous and chemical process. The calculated maximum adsorption capacity was as high as 46.37 mg g(-1) (computed in P). Thermodynamic analysis revealed that the adsorption was spontaneous and endothermic. SEM, XRD, XPS and FT-IR analysis suggested that the multi-adsorption mechanisms including precipitation, ligand exchange and complexation interactions can be evidenced during the phosphate adsorption process by La-composites in La-BC. PMID:26871732

  14. Adsorption of amitraz on the clay

    Directory of Open Access Journals (Sweden)

    Jale Gülen

    2013-01-01

    Full Text Available Amitraz (AZ that is used as acaridies was tried to extract with a clay. The experimental data were modelled as using Langmuir and Freundlich isotherms. The adsorption data fit well with Langmuir isotherm that indicated the AZ adsorption is homogeneous and monolayer. The monolayer adsorption capacity was found to be 35.02 mg/g at 20 ºC temperature. Effect of the phases contact time, the initial solution pH and the initial pesticide concentration were investigated from the point of adsorption equilibrium and yield. The adsorption kinetics were investigated by applying pseudo first order, pseudo second order and intra particle diffusion laws. Adsorption of AZ was found to be best fitted by the pseudo second order model. The intra particle diffusion also plays an important role in adsorption phenomenon.

  15. Adsorption modeling for macroscopic contaminant dispersal analysis

    Energy Technology Data Exchange (ETDEWEB)

    Axley, J.W.

    1990-05-01

    Two families of macroscopic adsorption models are formulated, based on fundamental principles of adsorption science and technology, that may be used for macroscopic (such as whole-building) contaminant dispersal analysis. The first family of adsorption models - the Equilibrium Adsorption (EA) Models - are based upon the simple requirement of equilibrium between adsorbent and room air. The second family - the Boundary Layer Diffusion Controlled Adsorption (BLDC) Models - add to the equilibrium requirement a boundary layer model for diffusion of the adsorbate from the room air to the adsorbent surface. Two members of each of these families are explicitly discussed, one based on the linear adsorption isotherm model and the other on the Langmuir model. The linear variants of each family are applied to model the adsorption dynamics of formaldehyde in gypsum wall board and compared to measured data.

  16. Fibrinogen adsorption on blocked surface of albumin

    DEFF Research Database (Denmark)

    Holmberg, Maria; Hou, Xiaolin

    2011-01-01

    We have investigated the adsorption of albumin and fibrinogen onto PET (polyethylene terephthalate) and glass surfaces and how pre-adsorption of albumin onto these surfaces can affect the adsorption of later added fibrinogen. For materials and devices being exposed to blood, adsorption...... of fibrinogen is often a non-wanted event, since fibrinogen is part of the clotting cascade and unspecific adsorption of fibrinogen can have an influence on the activation of platelets. Albumin is often used as blocking agent for avoiding unspecific protein adsorption onto surfaces in devices designed to handle...... energies, the adsorption of both albumin and fibrinogen has been monitored simultaneously on the same sample. Information about topography and coverage of adsorbed protein layers has been obtained using AFM (Atomic Force Microscopy) analysis in liquid. Our studies show that albumin adsorbs in a multilayer...

  17. The relationship between formate adsorption energy and electronic properties:A first principles density functional theory study

    Institute of Scientific and Technical Information of China (English)

    MA HongYan; WANG GuiChang; MORIKAWA Yoshitada; NAKAMURA Junji

    2009-01-01

    First principles density functional theory calculations have been performed for the chemisorption of formate adsorption on some metal surfaces.For the most stable adsorption site of short-bridge,the calculated formate adsorption energy follows the order of Au(110) < Ag(110) < Cu(110) < Pd(110) < Pt(110)< Ni(110)< Rh(110)< Fe(100)< Mo(100),and a clear linear correlation exists between the adsorption energy and the corresponding heat of formation of metal oxides.Moreover,it has been found that the formate adsorption energy for the transition metals can be correlated well with its d-band center (εd),and the IB Group metals can be described by the coupling matrix element square (Vad2).

  18. Adsorption of iron (III ion on activated carbons obtained from bagasse, pericarp of rubber fruit and coconut shell

    Directory of Open Access Journals (Sweden)

    Orawan Sirichote

    2002-04-01

    Full Text Available The adsorptions of iron (III from aqueous solution at room temperature on activated carbons obtaining from bagasse, pericarp of rubber fruit and coconut shell have been studied by atomic absorption spectrophotometry. The activated carbons were prepared by carbonization of these raw materials and followed by activation with ZnCl2 . The adsorption behavior of iron (III on these activated carbons could be interpreted by Langmuir adsorption isotherm as monolayer coverage. The maximum amounts of iron (III adsorbed per gram of these activated carbons were 0.66 mmol/g, 0.41 mmol/g and 0.18 mmol/g, respectively. Study of the temperature dependence on these adsorptions has revealed them to be exothermic processes with the heats of adsorption of about -8.9 kJ/mol , -9.7 kJ/mol and -5.7 kJ/mol for bagasse, pericarp of rubber fruit and coconut shell, respectively.

  19. Adsorption properties of biomass-based activated carbon prepared with spent coffee grounds and pomelo skin by phosphoric acid activation

    Science.gov (United States)

    Ma, Xiaodong; Ouyang, Feng

    2013-03-01

    Activated carbon prepared from spent coffee grounds and pomelo skin by phosphoric acid activation had been employed as the adsorbent for ethylene and n-butane at room temperature. Prepared activated carbon was characterized by means of nitrogen adsorption-desorption, X-ray powder diffraction, scanning electron microscope and Fourier transform infrared spectroscope. It was confirmed that pore structure played an important role during the adsorption testes. Adsorption isotherms of ethylene and n-butane fitted well with Langmuir equation. The prepared samples owned better adsorption capacity for n-butane than commercial activated carbon. Isosteric heats of adsorptions at different coverage were calculated through Clausius-Clapeyron equation. Micropore filling effect was explained in a thermodynamic way.

  20. Model-Based Energy Efficiency Optimization of a Low-Temperature Adsorption Dryer

    NARCIS (Netherlands)

    Atuonwu, J.C.; Straten, G. van; Deventer, H.C. van; Boxtel, A.J.B. van

    2011-01-01

    Low-temperature drying is important for heat-sensitive products, but at these temperatures conventional convective dryers have low energy efficiencies. To overcome this challenge, an energy efficiency optimization procedure is applied to a zeolite adsorption dryer subject to product quality. The pro

  1. The adsorption, reaction and decomposition of propylene on a clean Mo(100) surface

    Science.gov (United States)

    Wang, Luping; Tysoe, W. T.

    1991-04-01

    Propylene adsorbs onto Mo(100) at 110 K via precursor-state kinetics to saturate at a coverage, θ sat(C 3H 6) = 0.63 ± 0.05. Adsorption at lower temperatures results in multilayer adsorption. In contrast to ethylene, which rehybridizes to ~ sp 3 following adsorption at 80 K on Mo(100), propylene adsorbs molecularly at this temperature, rehybridizing only after heating to between 100 and 140 K. Further heating to between 180 and 200 K results in loss of hydrogen from the surface propylenic species and the formation of an aliene- or methylacetylene-like adsorbate which appears to be oriented so that the C-C-C axis is essentially parallel to the surface. Photoelectron spectroscopic data suggests significant carbon-carbon bond cleavage in the adsorbed C 3 species is underway by ~ 270 K. on Mo(100), resulting finally in the formation of adsorbed CH x species on heating the Mo(100) surface to room temperature. This chemistry is closely analogous to that observed following ethylene adsorption onto Mo(100) where a similar carbon-carbon bond cleavage was noted, and is in accord with the catalytic chemistry of molybdenum which catalyzes both olefin metathesis and hydrogenolysis. Further heating to above 400 K completely dehydrogenates the surface leaving chemisorbed, atomic carbon.

  2. Adsorption of Candida rugosa lipase at water-polymer interface: The case of poly( DL)lactide

    Science.gov (United States)

    Kamel, Gihan; Bordi, Federico; Chronopoulou, Laura; Lupi, Stefano; Palocci, Cleofe; Sennato, Simona; Verdes, Pedro V.

    2011-12-01

    Insights into the interactions between biological macromolecules and polymeric surfaces are of great interest because of potential uses in developing biotechnologies. In this study we focused on the adsorption of a model lipolytic enzyme, Candida rugosa lipase (CRL), on poly-(D,L)-lactic acid (PDLLA) polymer with the aim to gain deeper insights into the interactions between the enzyme and the carrier. Such studies are of particular relevance in order to establish the optimal conditions for enzyme immobilization and its applications. We employed two different approaches; by analyzing the influence of adsorbed CRL molecules on the thermodynamic behavior of Langmuir films of PDLLA deposited at air-water interface, we gained interesting information on the molecular interactions between the protein and the polymer. Successively, by a systematic analysis of the adsorption of CRL on PDLLA nanoparticles, we showed that the adsorption of a model lipase, CRL, on PDLLA is described in terms of a Langmuir-type adsorption behavior. In this model, only monomolecular adsorption takes place (i.e. only a single layer of the protein adsorbs on the support) and the interactions between adsorbed molecules and surface are short ranged. Moreover, both the adsorption and desorption are activated processes, and the heat of adsorption (the difference between the activation energy for adsorption and desorption) is independent from the surface coverage of the adsorbing species. Finally, we obtained an estimate of the number of molecules of the protein adsorbed per surface unit on the particles, a parameter of a practical relevance for applications in biocatalysis, and a semi-quantitative estimate of the energies (heat of adsorption) involved in the adsorption process.

  3. Heat pumps

    CERN Document Server

    Macmichael, DBA

    1988-01-01

    A fully revised and extended account of the design, manufacture and use of heat pumps in both industrial and domestic applications. Topics covered include a detailed description of the various heat pump cycles, the components of a heat pump system - drive, compressor, heat exchangers etc., and the more practical considerations to be taken into account in their selection.

  4. Effects of Igneous Intrusion on Microporosity and Gas Adsorption Capacity of Coals in the Haizi Mine, China

    OpenAIRE

    Jingyu Jiang; Yuanping Cheng

    2014-01-01

    This paper describes the effects of igneous intrusions on pore structure and adsorption capacity of the Permian coals in the Huaibei Coalfield, China. Twelve coal samples were obtained at different distances from a ~120 m extremely thick sill. Comparisons were made between unaltered and heat-affected coals using geochemical data, pore-fracture characteristics, and adsorption properties. Thermal alteration occurs down to ~1.3 × sill thickness. Approaching the sill, the vitrinite reflectance (R...

  5. Differential Adsorption of Ochratoxin A and Anthocyanins by Inactivated Yeasts and Yeast Cell Walls during Simulation of Wine Aging

    OpenAIRE

    Leonardo Petruzzi; Antonietta Baiano; Antonio De Gianni; Milena Sinigaglia; Maria Rosaria Corbo; Antonio Bevilacqua

    2015-01-01

    The adsorption of ochratoxin A (OTA) by yeasts is a promising approach for the decontamination of musts and wines, but some potential competitive or interactive phenomena between mycotoxin, yeast cells, and anthocyanins might modify the intensity of the phenomenon. The aim of this study was to examine OTA adsorption by two strains of Saccharomyces cerevisiae (the wild strain W13, and the commercial isolate BM45), previously inactivated by heat, and a yeast cell wall preparation. Experiments w...

  6. Low-pressure equilibrium binary argon-methane gas mixture adsorption on exfoliated graphite: Experiments and simulations

    Science.gov (United States)

    Albesa, Alberto; Russell, Brice; Vicente, José Luis; Rafti, Matías

    2016-04-01

    Adsorption equilibrium measurements of pure methane, pure argon, and binary mixtures over exfoliated graphite were carried for different initial compositions, temperatures, and total pressures in the range of 0.1-1.5 Torr using the volumetric static method. Diagrams for gas and adsorbed phase compositions were constructed for the conditions explored, and isosteric heats of adsorption were calculated. Experimental results were compared with predictions obtained with Monte Carlo simulations and using the Ideal Adsorbed Solution Theory (IAST).

  7. Adsorption in air treatment; Adsorption en traitement de l'air

    Energy Technology Data Exchange (ETDEWEB)

    Le Cloirec, P. [Ecole des Mines de Nantes, Dept. Systemes Energetiques et Environnement, 44 - Nantes (France)

    2003-01-01

    The aim of this article is to present the concepts and technologies of adsorption in air treatment. The following points are more particularly developed: 1 - approach of mechanisms: gas-solid transfer, equilibrium equations, multi-composed adsorption, adsorption influencing parameters, adsorption-desorption capacities and energies, specific case of hydrogen sulfide, the case of ketones; 2 - adsorbents implemented; 3 - adsorption and dynamical adsorber: flow and pressure drop in a porous medium, breakthrough curves, adsorption capacities, modeling of breakthrough curves; 4 - implementation of adsorber: models, dimensioning and practical operating data, process safety; 5 - regeneration of activated charcoals: reactivation, in-situ thermal regeneration. (J.S.)

  8. Adsorption separation of carbon dioxide, methane, and nitrogen on Hβ and Na-exchanged β-zeolite

    Institute of Scientific and Technical Information of China (English)

    Xiaoliang Xu; Xingxiang Zhao; Linbing Sun; Xiaoqin Liu

    2008-01-01

    Adsorption isotherms of carbon dioxide (CO2), methane (CH4), and nitrogen (N2) on Hβ and sodium exchanged β-zeolite (Naβ) were volumetrically measured at 273 and 303 K. The results show that all isotherms were of Brunauer type Ⅰ and well correlated with Langmuir-Freundlich model. After sodium ions exchange, the adsorption amounts of three adsorbates increased, while the increase magnitude of CO2 adsorption capacity was much higher than that of CH4 and N2. The selectivities of CO2 over CH4 and CO2 over N2 enhanced after sodium exchange. Also, the initial heat of adsorption data implied a stronger interaction of CO2 molecules with Na+ ions in Naβ. These results can be attributed to the larger electrostatic interaction of CO2 with extraframework cations in zeolites. However, Naβ showed a decrease in the selectivity of CH4 over N2, which can be ascribed to the moderate affinity of N2 with Naβ. The variation of isosteric heats of adsorption as a function of loading indicates that the adsorption of CO2 in Naβ presents an energetically heterogeneous profile. On the contrary, the adsorption of CH4 was found to be essentially homogeneous, which suggests the dispersion interaction between CH4 and lattice oxygen atoms, and such interaction does not depend on the exchangeable cations of zeolite.

  9. Development of adsorption cooling system. 3

    Energy Technology Data Exchange (ETDEWEB)

    Kim, J.N.; Cho, S.H.; Chue, K.T.; You, Y.J.; Lee, K.H.; Eun, T.H. [Korea Inst. of Energy Research, Taejon (Korea, Republic of)

    1995-12-01

    This report describes the third year study to develop adsorption chiller using silica gel/water pair for the recovery of low level waste heat. A pilot plant was fabricated and tested. In a typical run, the cooling capacity of 1.66 USRT and COP of 0.38 was obtained under the following operating conditions; chilled water temperature of 12{yields}8.9 degree C, hot water temperature of 72.7 degree C, cooling water temperature of 23.2 degree C, and half cycle time of 600(s). The COP of the pilot plant is comparable to 0.4 of Nishiyodo pilot plant having 3.68 USRT. In order to enhance the thermal conductivity of adsorbent layer, consolidated silica gel and graphite block was prepared and its characteristics was analyzed. A slurry method using water was appropriate of silica gel and graphite in the block, in which adsorbed amount of water is not much smaller than that on silica gel, was 6:1. The thermal conductivity of this block was 6.53 W/mk which was 37 times larger than that of silica gel. (author). 12 refs., 37 figs., 8 tabs.

  10. Theoretical Study of Ethanethiol Adsorption on HZSM-5 Zeolite

    Institute of Scientific and Technical Information of China (English)

    Renqing Lü; Guangmin Qiu; Chenguang Liu

    2005-01-01

    The density functional theory and the cluster model methods have been employed to investigate the interactions between ethanethiol and HZSM-5 zeolites. Molecular complexes formed by the adsorption of ethanethiol on silanol H3SiOH with two coordination forms, model Bronsted acid sites of zeolite cluster H3Si(OH)Al(OH)2SiH3 interaction with ethanethiol, aluminum species adsorbed ethanethiol have been comparatively studied. Full optimization and frequency analysis of all cluster models have been carried out using B3LYP hybrid method at 3-21G basis level for hydrogen atoms and 6-31G(d) basis set level for silicon, aluminum, oxygen, carbon, and sulfur atoms. The structures and energy changes of different coordination forms of H3Si(OH)Al(OH)2SiH3-ethanethiol, silanol-ethanethiol and Al(OH)3-ethanethiol have been studied. The calculated results showed the nature of interactions was van der Waals force as exhibited by not much change in geometric structures and properties. The preference order of ethanethiol adsorbed on HZSM-5 zeolite may be residual aluminum species, bridging hydroxyl groups and silanol OH groups from the adsorption heat. The adsorbed models of protonized ethanethiol on bridging hydroxyl OH groups and linear hydrogen bonded ethanethiol on bridging OH groups suggested in literature might not exist as revealed by this theoretical calculation. Possible adsorption models were obtained for the first time.

  11. Multi-bed Mass Recovery Adsorption Cycle -Improving Performance

    Science.gov (United States)

    Khan, Md. Zafar Iqbal; Saha, Bidyut Baran; Alam, K. C. Amanul; Miyazaki, Takahiko; Akisawa, Atsushi; Kashiwagi, Takao

    The study aims at clarifying the performance of a 3-bed, mass recovery silica gel-water adsorption refrigeration cycle. The cycle with mass recovery can be driven by waste heat at near ambient temperatures (between 50 and 90°C). All components of adsorption cycle are operated in different pressure levels. The 3-bed chiller with mass recovery process utilizes those pressure levels to enhance the refrigerant mass circulation. The innovative adsorption chiller comprises with three sorption elements (SEs), one evaporator and one condenser. The configuration of SE1 and SE2 are uniform but the configuration of SE3 is taken as half of SE1 or SE2. Two cycles (cycle-1, cycle-2) with mass recovery process are used and compare the performance with each other. In cycle-1, mass recovery process occurs between SE3 with either SE1 or SE2 and no mass recovery between SE1 and SE2 occurs. In cycle-2, mass recovery process occurs between SE1 and SE2, and no mass recovery process occurs between SE3 with either SE1 or SE2. The mathematical model shown herein is solved numerically. Simulated results are obtained from transient to cyclic steady state. Simulated results show that the COP and SCP of cycle-1 are better than those of cycle-2.

  12. Enhancing activated carbon adsorption of 2-methylisoborneol: methane and steam treatments

    Energy Technology Data Exchange (ETDEWEB)

    Kirk O. Nowack; Fred S. Cannon; David W. Mazyck [Pennsylvania State University, University Park, PA (United States). Department of Civil and Environmental Engineering

    2004-01-01

    This research investigated methods for tailoring a commercial, lignite-based granular activated carbon (GAC) to enhance its adsorption of 2-methylisoborneol (MIB) from natural water. Tailoring efforts focused on heat treatments in gas environments comprising steam and/or methane, since these gases can alter GAC pore structure and surface chemistry. Heat treatments that combined methane and steam enhanced MIB adsorption considerably, causing a 4-fold improvement (over untreated GAC) in fixed-bed adsorption performance relative to initial MIB breakthrough. These favorable effects, observed in rapid small-scale column tests, occurred following simultaneous and separate (sequential) applications of methane and steam. Moderately low temperature steam treatments also improved MIB uptake in fixed-bed adsorption tests but to a lesser extent (approximately 1.5-fold). In contrast, methane treatments alone, at various temperatures, led to significant carbon deposition within the GAC pore structure. As a result, total pore volume was reduced and MIB adsorption performance declined. 62 refs., 9 figs., 2 tabs.

  13. Study on cyclic characteristics of the solar-powered adsorption cooling system

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    According to the typical variable heat source of solar energy and the unsteady adsorption process of adsorption chiller,the research of cyclic transient characteristics of the solar-powered adsorption cooling system is presented in this work.A mathematic model of the whole system including the model of adsorption chiller,which reveals the transient operation process of the solar-powered adsorption cooling system,is developed and verified by experimental data.On the basis of the simulated results,the transient characteristics and the overall performance of the system,not only in the traditional open cycle mode but also in closed cycle mode,are both analyzed theoretically.Furthermore,the influence of parameters matching of components configuration and operation process on the cyclic characteristics of the system,such as the solar collector area,the water tank capacity and the chiller startup temperature,are discussed.The research in this work may play a very important role in optimizing the system cyclic process and improving the system adaptability especially under the condition of variable heat source.

  14. Study on cyclic characteristics of the solar-powered adsorption cooling system

    Institute of Scientific and Technical Information of China (English)

    WU JingYi; LI Sheng; HU YanFei

    2009-01-01

    According to the typical variable heat source of solar energy and the unsteady adsorption process of adsorption chiller, the research of cyclic transient characteristics of the solar-powered adsorption cooling system is presented in this work. A mathematic model of the whole system including the model of adsorption chiller, which reveals the transient operation process of the solar-powered adsorption cooling system, is developed and verified by experimental data. On the basis of the simulated results, the transient characteristics and the overall performance of the system, not only in the traditional open cycle mode but also in closed cycle mode, are both analyzed theoretically. Furthermore, the influence of pa-rameters matching of components configuration and operation process on the cyclic characteristics of the system, such as the solar collector area, the water tank capacity and the chiller startup temperature, are discussed. The research in this work may play a very important role in optimizing the system cyclic process and improving the system adaptability especially under the condition of variable heat source.

  15. Single-crystal adsorption calorimetry and density functional theory of CO chemisorption on fcc Co{110}.

    Science.gov (United States)

    Liao, Kristine; Fiorin, Vittorio; Gunn, David S D; Jenkins, Stephen J; King, David A

    2013-03-21

    Using single-crystal adsorption calorimetry (SCAC) and density functional theory (DFT), the interaction of carbon monoxide on fcc Co{110} is reported for the first time. The results indicate that adsorption is consistent with molecular chemisorption at all coverages. The initial heat of adsorption of 140 kJ mol(-1) is found in the range of heat values calorimetrically measured on other ferromagnetic metal surfaces, such as nickel and iron. DFT adsorption energies are in good agreement with the experimental results, and comparison between SCAC and DFT for CO on other ferromagnetic surfaces is made. The calculated dissociation barrier of 2.03 eV implies that dissociation at 300 K is unlikely even at the lowest coverage. At high coverages during the adsorption-desorption steady state regime, a pre-exponential factor for CO desorption of 1.2 × 10(17) s(-1) is found, implying a localised molecular adsorbed state prior to desorption in contrast to what we found with Ni surfaces. This result highlights the importance of the choice of the pre-exponential factor in evaluating the activation energy for desorption.

  16. Modeling studies: Adsorption of aniline blue by using Prosopis Juliflora carbon/Ca/alginate polymer composite beads.

    Science.gov (United States)

    Kumar, M; Tamilarasan, R

    2013-02-15

    The research article describes the experimental and modeling study for the adsorptive removal of aniline blue dye (AB dye) from aqueous matrices using a Prosopis Juliflora modified carbon/Ca/alginate polymer bead as a low cost and eco-friendly adsorbent. The rate of adsorption was investigated under various experimental parameters such as contact time, adsorbent dose, dye concentration, pH and temperature. The kinetics, equilibrium and thermodynamic studies were assessed to find out the efficiency of the adsorption process. The equilibrium uptake capacity of the adsorption process was found with Freundlich and Langmuir adsorption isotherm equations and it was evaluated by dimensionless separation factor (R(L)). The dynamics of adsorption was predicted by pseudo-first order, pseudo-second order Lagergren's equation and intra particle diffusion model. Adsorption feasibility was assessed with thermodynamic parameters such as isosteric heat of adsorption (ΔH°), standard entropy (ΔS°) and Gibbs free energy (ΔG°) using VantHoff plot. The alginate bead was characterized with FTIR spectroscopy and Scanning Electron Microscopy (SEM).

  17. Adsorption and Desorption of Methiopyrsulfuron in Soils

    Institute of Scientific and Technical Information of China (English)

    WU Chun-Xian; WANG Jin-Jun; ZHANG Su-Zhi; ZHANG Zhong-Ming

    2011-01-01

    Methiopyrsulfuron is a new low-rate sulfonylurea herbicide for weed control in wheat; however, there is a lack of published information on its behavior in soils. In this study, methiopyrsulfuron adsorption and desorption were measured in seven soils sampled from Heilongjiang, Shandong, Jiangxi, Sichuan, Anhui, and Chongqing provinces of China using a batch equilibrium method. The Freundlich equation was used to described its adsorption and desorption. Adsorption isotherms were nonlinear with the values of Kf-ads, the Freundlich empirical constant indicative of the adsorption capacity,ranging from 0.75 to 2.46, suggesting that little of this herbicide was adsorbed by any of the seven soils. Soil pH and organic matter content (OM) were the main factors influencing adsorption; adsorption was negatively correlated with pH and positively correlated with OM. Methiopyrsulfuron desorption was hysteretic on the soils with high OM content and low pH.

  18. Gibbs adsorption and the compressibility equation

    International Nuclear Information System (INIS)

    A new approach for deriving the equation of state is developed. It is shown that the integral in the compressibility equation is identical to the isotherm for Gibbs adsorption in radial coordinates. The Henry, Langmuir, and Frumkin adsorption isotherms are converted into equations of state. It is shown that using Henry's law gives an expression for the second virial coefficient that is identical to the result from statistical mechanics. Using the Langmuir isotherm leads to a new analytic expression for the hard-sphere equation of state which can be explicit in either pressure or density. The Frumkin isotherm results in a new equation of state for the square-well potential fluid. Conversely, new adsorption isotherms can be derived from equations of state using the compressibility equation. It is shown that the van der Waals equation gives an adsorption isotherm equation that describes both polymolecular adsorption and the unusual adsorption behavior observed for supercritical fluids. copyright 1995 American Institute of Physics

  19. ADSORPTION AND RELEASING PROPERTIES OF BEAD CELLULOSE

    Institute of Scientific and Technical Information of China (English)

    A. Morales; E. Bordallo; V. Leon; J. Rieumont

    2004-01-01

    The adsorption of some dyes on samples of bead cellulose obtained in the Unit of Research-Production "Cuba 9"was studied. Methylene blue, alizarin red and congo red fitted the adsorption isotherm of Langmuir. Adsorption kinetics at pH = 6 was linear with the square root of time indicating the diffusion is the controlling step. At pH = 12 a non-Fickian trend was observed and adsorption was higher for the first two dyes. Experiments carried out to release the methylene blue occluded in the cellulose beads gave a kinetic behavior of zero order. The study of cytochrome C adsorption was included to test a proteinic material. Crosslinking of bead cellulose was performed with epichlorohydrin decreasing its adsorption capacity in acidic or alkaline solution.

  20. Effect of piezoelectric material on hydrogen adsorption

    Energy Technology Data Exchange (ETDEWEB)

    Li, Xuan [Department of Materials Science and Engineering, Michigan Technological University, 1400 Townsend Drive, Houghton, MI, 49931 (United States); Civil and Environmental Engineering School, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing, 100083 (China); Hwang, Jiann-Yang; Shi, Shangzhao; Sun, Xiang; Zhang, Zheng [Department of Materials Science and Engineering, Michigan Technological University, 1400 Townsend Drive, Houghton, MI, 49931 (United States)

    2010-09-15

    In hydrogen storage applications, the primary issue for physisorption of hydrogen onto solid-state materials is the weak interaction force between hydrogen molecules and the adsorbents. It is found that enhanced adsorption can be obtained under an external electric field, because it appears the electric field increases the hydrogen adsorption energy. Experiments were carried out to determine hydrogen adsorption on activated carbon using the piezoelectric material PMN-PT as the charge supplier under hydrogen pressure. Results indicate that more than 20% hydrogen adsorption enhancement was obtained. Parameters related to hydrogen adsorption enhancement include the amount of the charge and temperature. Higher voltage and lower temperature promote the increase of adsorption capacity but room temperature results are very encouraging. (author)

  1. Adsorption of goethite onto quartz and kaolinite

    Science.gov (United States)

    Goldberg, M.C.; Weiner, Eugene R.; Boymel, P.M.

    1984-01-01

    The adsorption of colloidal goethite onto quartz and kaolinite substrates has been studied as a function of pH and NaCl concentration. Goethite adsorption was measured quantitatively by Fourier-transform infrared spectroscopy. The results indicate that adsorption onto both substrates is due primarily to coulombic forces; however, the pH dependence of adsorption is very different for the two substrates. This is explained by the fact that the surface charge on quartz is entirely pH-dependent, while kaolinite has surface faces which carry a permanent negative charge. Adsorption of goethite on to kaolinite increases markedly with increasing NaCl concentration, while adsorption onto quartz is relatively independent of NaCl concentration. This can be explained by the influence of NaCl concentration upon the development of surface charge on the substrates. A method is described for separating surface-bound goethite from free goethite.

  2. Adsorption of octylamine on titanium dioxide

    International Nuclear Information System (INIS)

    Processes of adsorption and desorption of a model active substance (octylamine) on the surface of unmodified titanium dioxide (E 171) have been performed. The effects of concentration of octylamine and time of the process on the character of adsorption have been studied and the efficiency of the adsorption/desorption has been determined. The samples obtained have been studied by X-ray diffraction. The nitrogen adsorption/desorption isotherms, particle size distribution and absorption capacities of water, dibutyl phthalate and paraffin oil have been determined. The efficiency of octylamine adsorption on the surface of the titanium dioxide has been found positively correlated with the concentration of octylamine in the initial solution. The desorption of octylamine has decreased with increasing concentration of this compound adsorbed. For octylamine in low concentrations the physical adsorption has been found to dominate, which is desirable when using TiO2 in the production of pharmaceuticals.

  3. Adsorption of I- ions on cinnabar for 129I waste management

    International Nuclear Information System (INIS)

    Adsorption of I- ions on natural cinnabars, whose localities are Spain, USA, and Mexico, have been studied by batch method. Only Spain cinnabar (S-cinnabar) was found to have relatively high adsorptivity to I- ions even in the presence of Cl- ions. The value of distribution ratio (Kd) is 103 ml/g under the conditions of initial [I-] = 1.0 x 10-6 M (1 M = 1 mol/dm3), pH 6.0, and solution/S-cinnabar = 100 ml/g. It was found that the adsorptivities of S-cinnabar to I- ions increase with an increase in the specific surface area and a decrease in pH, that the adsorption of I- ions on S-cinnabar is irreversible, and that S-cinnabars heated at temperatures higher than 100 C decrease the adsorptivities to I- ions. Furthermore, I- ions were found to be not adsorbed on HgS reagent which is the main component of cinnabar. From these results, the adsorption of I- ions on S-cinnabar is considered to be due to the reaction between I- ions and certain species in the surface, which are thermally unstable and minor component. (orig.)

  4. Experimental study on high-pressure adsorption of hydrogen on activated carbon

    Institute of Scientific and Technical Information of China (English)

    周亚平; 周理

    1996-01-01

    A systematic measurement of H2 adsorption on activated carbon over a wide scope of conditions was completed for the first time using a novel cryostat developed by the present authors. The equilibrium temperatures covered 77-298 K with the space of about 20 K, and the equilibrium pressures increased from 0 to about 7MPa. A set of adsorption/desorption isotherms was obtained by a standard volumetric method. This set of experimental data was fitted to all the well-known models of type-I isotherms, and Dubinin-Astakhov (D-A) equation was found to be the best-fit one On the basis of D-A model one can predict adsorption with relative error of ±4%. A 3-dimensional adsorption surface was also constructed, and the isosteric heat of adsorption was analytically determined. Except in the low pressure area, the calculated values agreed well with the experimental ones. Finally, the troubles encountered in applying D-A equation to supercritical adsorption is discussed.

  5. Decolorization of a textile vat dye by adsorption on waste ash

    Directory of Open Access Journals (Sweden)

    MIODRAG ŠMELCEROVIĆ

    2010-06-01

    Full Text Available An adsorption process using cheap adsorbents could be described as a simple, selective and low cost alternative for the treatment of colored waste water compared to conventional physical and chemical processes. In this study the use of a natural waste adsorbent–ash was investigated for the removal of a textile vat dye Ostanthren blue GCD remaining after the dyeing of cotton textile. The ash obtained as a waste material during the burning of brown coal in the heating station of Leskovac (Serbia was used for the treatment of waste waters from the textile industry, i.e., waste water after the dyeing process. The effect of ash quantity, initial dye concentration, pH and agitation time on adsorption was studied. The Langmuir model was used to describe the adsorption isotherm. Based on the analytical expression of the Langmuir model, the adsorption constants, such as adsorption capacity and adsorption energy, were found. Pseudo first and second order kinetic models were studied to evaluate the kinetic data.

  6. Dynamic modeling of fixed-bed adsorption of flue gas using a variable mass transfer model

    Energy Technology Data Exchange (ETDEWEB)

    Park, Jehun; Lee, Jae W. [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of)

    2016-02-15

    This study introduces a dynamic mass transfer model for the fixed-bed adsorption of a flue gas. The derivation of the variable mass transfer coefficient is based on pore diffusion theory and it is a function of effective porosity, temperature, and pressure as well as the adsorbate composition. Adsorption experiments were done at four different pressures (1.8, 5, 10 and 20 bars) and three different temperatures (30, 50 and 70 .deg. C) with zeolite 13X as the adsorbent. To explain the equilibrium adsorption capacity, the Langmuir-Freundlich isotherm model was adopted, and the parameters of the isotherm equation were fitted to the experimental data for a wide range of pressures and temperatures. Then, dynamic simulations were performed using the system equations for material and energy balance with the equilibrium adsorption isotherm data. The optimal mass transfer and heat transfer coefficients were determined after iterative calculations. As a result, the dynamic variable mass transfer model can estimate the adsorption rate for a wide range of concentrations and precisely simulate the fixed-bed adsorption process of a flue gas mixture of carbon dioxide and nitrogen.

  7. Enthalpy–entropy compensation for n-hexane adsorption on HZSM-5 containing transition metal ions

    International Nuclear Information System (INIS)

    Highlights: ► Enthalpy–entropy compensation for n-hexane adsorption on ion-exchanged ZSM-5 zeolites is shown. ► Linearity of −ΔH vs. −ΔS plots was found for all investigated ZSM-5 zeolites. ► This effect depends on the size, charge and electron configuration of the cations. ► Compensation temperature correlates to the number of zeolites’ strong acid centres. ► Compensation effect was not found for the adsorption of n-hexane on X and Y zeolites. - Abstract: In this work, the values of entropy changes related to n-hexane adsorption onto ion-exchanged ZSM-5 zeolites were calculated from differential heats, obtained from microcalorimetric experiments. The existence of enthalpy–entropy compensation effect, evidenced by the linearity of −ΔH vs. −ΔS plots and characteristic for all investigated ZSM-5 zeolites, was found. In the case of ZSM-5 structure, modifying the zeolite structure by ion-exchange gives rise to changes in the heats of adsorption and adsorption entropy in the same manner. The factors that can influence the appearance of entropy–enthalpy compensation were discussed. It was found that compensation effect is governed by ion-induced dipole interaction between highly polarising cationic centres in zeolite and nonopolar n-hexane molecules, and hence, depends on the size, charge and electron configuration of the cation. It was found also that the compensation temperature is in correlation with the number of zeolites’ strong acid centres. Contrary to the adsorption of n-hexane on ZSM-5 zeolites, compensation effect was not found for the adsorption of the same gas on faujasite-type zeolites.

  8. Selective adsorption for removal of nitrogen compounds from hydrocarbon streams over carbon-based adsorbents

    Science.gov (United States)

    Almarri, Masoud S.

    desulfurization of model diesel fuel, which contains equimolar concentrations of nitrogen (i.e., quinoline and indole), sulfur (i.e., dibenzothiophene and 4,6-dimethyldibenzothiophene), and aromatic compounds (naphthalene, 1-methylnaphthalene, and fluorene), was examined. The results revealed that when both nitrogen and sulfur compounds coexist in the fuel, the type and density of oxygen functional groups on the surface of the activated carbon are crucial for selective adsorption of nitrogen compounds but have negligible positive effects for sulfur removal. The adsorption of quinoline and indole is largely governed by specific interactions. There is enough evidence to support the importance of dipole--dipole and acid-base-specific interactions for the adsorption of both quinoline and indole. Modified carbon is a promising material for the efficient removal of the nitrogen compounds from light cycle oil (LCO). Adsorptive denitrogenation of LCO significantly improved the hydrodesulfurization (HDS) performance, especially for the removal of the refractory sulfur compounds such as 4-methyldibenzothiophene and 4,6-dimethyldibenzothiophene. An essential factor in applying activated carbon for adsorptive denitrogenation and desulfurization of liquid hydrocarbon streams is regeneration after saturation. The regeneration method of the saturated adsorbents consisted of toluene washing followed by heating to remove the remaining toluene. The results show that the spent activated carbon can be regenerated to completely recover the adsorption capacity. The high capacity and selectivity of activated carbon for nitrogen compounds, along with their ability to be regenerated, indicate that activated carbon is a promising adsorbent for the deep denitrogenation of liquid hydrocarbon streams.

  9. Bentazone adsorption and desorption on agricultural soils

    OpenAIRE

    Boivin, A.; Cherrier, R.; Schiavon, M

    2005-01-01

    Herbicide fate and transport in soils greatly depend upon adsorption-desorption processes. Batch adsorption and desorption experiments were performed with the herbicide bentazone using 13 contrasted agricultural soil samples. Bentazone was found to be weakly sorbed by the different soils, showing average Freundlich adsorption coefficients (Kf) value of 1.4 ± 2.3 mg1 - nf Lnf kg-1. Soil organic matter content did not have a significant effect on bentazone sorption (r2 = 0.12), whereas natural ...

  10. High Pressure Multicomponent Adsorption in Porous Media

    DEFF Research Database (Denmark)

    Shapiro, Alexander; Stenby, Erling Halfdan

    1999-01-01

    We analyse adsorption of a multicomponent mixture at high pressure on the basis of the potential theory of adsorption. The adsorbate is considered as a segregated mixture in the external field produced by a solid adsorbent. we derive an analytical equation for the thickness of a multicomponent film...... close to a dew point. This equation (asymptotic adsorption equation, AAE) is a first order approximation with regard to the distance from a phase envelope....

  11. A detailed analysis of entropy production and improvement of the thermodynamic cycle of an adsorption refrigerating plant

    Science.gov (United States)

    Okunev, B. N.; Safonov, M. S.

    2006-07-01

    A thermodynamic analysis of an adsorption refrigerating plant with closed loops for a working substance and auxiliary liquid heat carrier has been carried out in application to the adsorption pair “water-CaCl2 impregnated into the pores of a silica gel.” Using the obtained periodic solutions of the system of energy-balance equations for the heat carrier and the sorbent layer, the most thermodynamically effective modes of operation of the refrigerating plant have been determined as functions of governing parameters. The entropy production in various modules of the plant is calculated, and the main sources of entropy generation are revealed. This made it possible to suggest an improved scheme of an adsorption refrigerating cycle with regenerative heat exchangers connected at the inlet and outlet from the adsorbers. The possibility of a considerable increase in the coefficient of thermodynamic efficiency in such a system has been justified.

  12. Heat pumps

    CERN Document Server

    Brodowicz, Kazimierz; Wyszynski, M L; Wyszynski

    2013-01-01

    Heat pumps and related technology are in widespread use in industrial processes and installations. This book presents a unified, comprehensive and systematic treatment of the design and operation of both compression and sorption heat pumps. Heat pump thermodynamics, the choice of working fluid and the characteristics of low temperature heat sources and their application to heat pumps are covered in detail.Economic aspects are discussed and the extensive use of the exergy concept in evaluating performance of heat pumps is a unique feature of the book. The thermodynamic and chemical properties o

  13. Adsorption of radioactive iodide by natural zeolites

    International Nuclear Information System (INIS)

    Two natural zeolites from Iranian deposits (clinoptilolite and natrolite) were characterized and their ability for adsorption of iodide from nuclear wastewaters was evaluated. The adsorption behavior was studied on natural and modified zeolites by γ-spectrometry using 131I as radiotracer. Adsorption isotherms and distribution coefficient (Kd) were measured. The results showed that clinoptilolite is a more promising zeolite for removal of iodide compared to natrolite. Furthermore, the adsorption was higher in silver, lead and thallium forms, whereas the lowest desorption was observed in lead modified zeolite. (author)

  14. Adsorption from Experimental Isotherms of Supercritical Gases

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A mathematical method was proposed for the determination of absolute adsorption from experimental isotherms. The method is based on the numerical equality of the absolute and the excess adsorption when either the gas phase density or the amount adsorbed is not quite considerable. The initial part of the experimental isotherms, which represents the absolute adsorption, became linear with some mathematical manipulations. The linear isotherms were reliably formulated. As consequence, either the volume or the density of the supercritical adsorbate could be determined by a non-empirical way. This method was illustrated by the adsorption data of supercritical hydrogen and methane on a superactivated carbon in large ranges of temperature and pressure.

  15. ADSORPTION OF POLYCHLORINATED BIPHENYLS BY SOILS

    Directory of Open Access Journals (Sweden)

    Mihaela Preda

    2010-01-01

    Full Text Available The behavior of polychlorinated biphenyls (PCBs in soil is determined by several factors including adsorption, mobility and degradation. Adsorption, directly or indirectly, influences the other factors. Adsorption process is generally evaluated by using adsorption isotherms representing the relationship between the quantity of substance adsorbed per unit weight and concentration of the substance in solution at equilibrium. They allow determination of the adsorption constant, which is directly proportional to the adsorption of PCBs in soil. PCBs are very insoluble in water, so they tend to accumulate in the lipids. This is the reason why polychlorinated biphenyls are more strongly adsorbed in soils with higher organic matter content. To obtain the adsorption isotherm were used standard solutions of PCB 101with initial concentrations: 0.05, 0.1, 0.5, 1 and 2 g/ml. The adsorption constants were in order: 3072 ml/g for chernozem, 2943 mg/l for chromic luvisol, 998 mg/l for aluviosol and 1443 mg/l for anthrosol. The values of adsorption constants depend on the organic matter and clay content.

  16. Adsorption-induced step formation

    DEFF Research Database (Denmark)

    Thostrup, P.; Christoffersen, Ebbe; Lorensen, Henrik Qvist;

    2001-01-01

    Through an interplay between density functional calculations, Monte Carlo simulations and scanning tunneling microscopy experiments, we show that an intermediate coverage of CO on the Pt(110) surface gives rise to a new rough equilibrium structure with more than 50% step atoms. CO is shown to bind...... so strongly to low-coordinated Pt atoms that it can break Pt-Pt bonds and spontaneously form steps on the surface. It is argued that adsorption-induced step formation may be a general effect, in particular at high gas pressures and temperatures....

  17. Adsorption analysis equilibria and kinetics

    CERN Document Server

    Do, Duong D

    1998-01-01

    This book covers topics of equilibria and kinetics of adsorption in porous media. Fundamental equilibria and kinetics are dealt with for homogeneous as well as heterogeneous particles. Five chapters of the book deal with equilibria and eight chapters deal with kinetics. Single component as well as multicomponent systems are discussed. In kinetics analysis, we deal with the various mass transport processes and their interactions inside a porous particle. Conventional approaches as well as the new approach using Maxwell-Stefan equations are presented. Various methods to measure diffusivity, such

  18. Effect of Adsorbent Diameter on the Performance of Adsorption Refrigeration

    Institute of Scientific and Technical Information of China (English)

    黄宏宇; 何兆红; 袁浩然; 小林敬幸; 赵丹丹; 窪田光宏; 郭华芳

    2014-01-01

    Adsorbents are important components in adsorption refrigeration. The diameter of an adsorbent can af-fect the heat and mass transfer of an adsorber. The effect of particle diameter on effective thermal conductivity was investigated. The heat transfer coefficient of the refrigerant and the void rate of the adsorbent layer can also affect the effective thermal conductivity of adsorbents. The performance of mass transfer in the adsorber is better when pressure drop decreases. Pressure drop decreases with increasing permeability. The permeability of the adsorbent layer can be improved with increasing adsorbent diameter. The effect of adsorbent diameter on refrigeration output power was experimentally studied. Output power initially increases and then decreases with increasing diameter under different cycle time conditions. Output power increases with decreasing cycle time under similar diameters.

  19. Investigation of Microgranular Adsorptive Filtration System

    Science.gov (United States)

    Cai, Zhenxiao

    Over the past few decades, enormous advances have been made in the application of low-pressure membrane filtration to both drinking water and wastewater treatment. Nevertheless, the full potential of this technology has not been reached, due primarily to limitations imposed by membrane fouling. In drinking water treatment, much of the fouling is caused by soluble and particulate natural organic matter (NOM). Efforts to overcome the problem have focused on removal of NOM from the feed solution, usually by addition of conventional coagulants like alum and ferric chloride (FeCl3) or adsorbents like powdered activated carbon (PAC). While coagulants and adsorbents can remove a portion of the NOM, their performance with respect to fouling control has been inconsistent, often reducing fouling but sometimes having no effect or even exacerbating fouling. This research investigated microgranular adsorptive filtration (muGAF), a process that combines three existing technologies---granular media filtration, packed bed adsorption, and membrane filtration---in a novel way to reduce membrane fouling while simultaneously removing NOM from water. In this technology, a thin layer of micron-sized adsorbent particles is deposited on the membrane prior to delivering the feed to the system. The research reported here represents the first systematic study of muGAF, and the results demonstrate the promising potential of this process. A new, aluminum-oxide-based adsorbent---heated aluminum oxide particles (HAOPs)---was synthesized and shown to be very effective for NOM removal as well as fouling reduction in muGAF systems. muGAF has also been demonstrated to work well with powdered activated carbon (PAC) as the adsorbent, but not as well as when HAOPs are used; the process has also been successful when used with several different membrane types and configurations. Experiments using a wide range of operational parameters and several analytical tools lead to the conclusion that the fouling

  20. Methanol adsorption studies of electrified ACF by MD simulations

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    [1]Wang, R. Z., Jia, J. P., Teng, Y. et al., A potential solid adsorption refrigeration pair-active carbon fiber- methanol, Acta Energ. Solar. Sinica (in Chinese), 1997, 18(2): 222-227.[2]Wang, R. Z., Wu, J. Y., Xu, Y. X. et al., Experiment on a continuous heat regenerative adsorption refrigerator using spiral plate heat exchanger as adsorbers, Applied Thermal Eng., 1998, 18(1-2): 13-23.[3]Vagner, C., Finqueneisel, G., Zimny, T. et al., Isotherms and kinetics of methanol vapor adsorption on carbon fibers and activated carbons, New Carbon Materials, 2003, 18(2): 133-136.[4]Wang, D. R., Development and application of activated carbon nanofiber, Carbon (in Chinese), 2003, 1: 35-41.[5]Su, J. C., Qiu, J. Sh., Preparation of activated carbon fiber-based composite adsorbent and its gas separation performance, Carbon Techniques (in Chinese), 2001, 3: 1-4.[6]Gasteiger, J., Marsili, M., Iterative partial equalization of orbital electronegativity-a rapid access to atomic charges, Tetrahedron, 1980, 36: 3219-3288.[7]Cornell, W. D., Cieplak, P., Bayly, C. I. et al., A second generation force field for the simulation of peoteins, nucleic acids, and organic molecules, J. Am. Chem. Soc., 1995, 117: 5179-5197.[8]Ewald, P. P., Die Berechnung optischer und elektrostatischer gitterpotentiale, Ann. Phys., 1921, 64: 253-287.[9]Allen, M. P., Tildesley, D. J., Computer Simulation of Liquids, Oxford: Oxford University Press, 1987, 157-162.[10]Leach, A. R., Molecular Modelling: Principles and Applications, London: Addison Wesley Longman Limited, 1996, 294-298.

  1. Transient Behavior of Activated Carbon Fiber-Ethanol Based Two-Stage Adsorption Chiller

    OpenAIRE

    El-Sharkawy, Ibrahim Ibrahim; Saha, Bidyut Baran; Hassan, Mahmoud; Koyama, Shigeru

    2008-01-01

    In this study, an analytical investigation on the performance of a low temperature solar or waste heat driven two-stage adsorption chiller is performed. Activated carbon fiber (ACF) of type (A-20) and ethanol are used as adsorbent-refrigerant pair. This innovative system can be driven by heat source of temperature between 50 and 70 degree C in combination with a heat sink of 30 degree C. A mathematical model is developed to analyze the dynamic behavior of the cycle as well as the influence of...

  2. Surfactant adsorption to soil components and soils.

    Science.gov (United States)

    Ishiguro, Munehide; Koopal, Luuk K

    2016-05-01

    Soils are complex and widely varying mixtures of organic matter and inorganic materials; adsorption of surfactants to soils is therefore related to the soil composition. We first discuss the properties of surfactants, including the critical micelle concentration (CMC) and surfactant adsorption on water/air interfaces, the latter gives an impression of surfactant adsorption to a hydrophobic surface and illustrates the importance of the CMC for the adsorption process. Then attention is paid to the most important types of soil particles: humic and fulvic acids, silica, metal oxides and layered aluminosilicates. Information is provided on their structure, surface properties and primary (proton) charge characteristics, which are all important for surfactant binding. Subsequently, the adsorption of different types of surfactants on these individual soil components is discussed in detail, based on mainly experimental results and considering the specific (chemical) and electrostatic interactions, with hydrophobic attraction as an important component of the specific interactions. Adsorption models that can describe the features semi-quantitatively are briefly discussed. In the last part of the paper some trends of surfactant adsorption on soils are briefly discussed together with some complications that may occur and finally the consequences of surfactant adsorption for soil colloidal stability and permeability are considered. When we seek to understand the fate of surfactants in soil and aqueous environments, the hydrophobicity and charge density of the soil or soil particles, must be considered together with the structure, hydrophobicity and charge of the surfactants, because these factors affect the adsorption. The pH and ionic strength are important parameters with respect to the charge density of the particles. As surfactant adsorption influences soil structure and permeability, insight in surfactant adsorption to soil particles is useful for good soil management. PMID

  3. Programming MOFs for water sorption: amino-functionalized MIL-125 and UiO-66 for heat transformation and heat storage applications.

    Science.gov (United States)

    Jeremias, Felix; Lozan, Vasile; Henninger, Stefan K; Janiak, Christoph

    2013-12-01

    Sorption-based heat transformation and storage appliances are very promising for utilizing solar heat and waste heat in cooling or heating applications. The economic and ecological efficiency of sorption-based heat transformation depends on the availability of suitable hydrophilic and hydrothermally stable sorption materials. We investigated the feasibility of using the metal-organic frameworks UiO-66(Zr), UiO-67(Zr), H2N-UiO-66(Zr) and H2N-MIL-125(Ti) as sorption materials in heat transformations by means of volumetric water adsorption measurements, determination of the heat of adsorption and a 40-cycle ad/desorption stress test. The amino-modified compounds H2N-UiO-66 and H2N-MIL-125 feature high heat of adsorption (89.5 and 56.0 kJ mol(-1), respectively) and a very promising H2O adsorption isotherm due to their enhanced hydrophilicity. For H2N-MIL-125 the very steep rise of the H2O adsorption isotherm in the 0.1 pump application. PMID:23864023

  4. HEAT RECUPERATION

    Directory of Open Access Journals (Sweden)

    S. L. Rovin

    2011-01-01

    Full Text Available Heat recovery is an effective method of shortening specific energy consumption. new constructions of recuperators for heating and cupola furnaces have been designed and successfully introduced. two-stage recuperator with computer control providing blast heating up to 600 °C and reducing fuel consumption by 30% is of special interest.

  5. Performance Analysis of a Double-effect Adsorption Refrigeration Cycle with a Silica Gel/Water Working Pair

    OpenAIRE

    Marlinda, Marlinda; Uyun, Aep Saepul; Miyazaki, Takahiko; Ueda, Yuki; Akisawa, Atsushi

    2010-01-01

    A numerical investigation of the double-effect adsorption refrigeration cycle is examined in this manuscript. The proposed cycle is based on the cascading adsorption cycle, where condensation heat that is produced in the top cycle is utilized as the driving heat source for the bottom cycle. The results show that the double-effect cycle produces a higher coefficient of performance (COP) as compared to that of the conventional single-stage cycle for driving temperatures between 100 °C and 150 °...

  6. Performance Analysis of a Double-effect Adsorption Refrigeration Cycle with a Silica Gel/Water Working Pair

    OpenAIRE

    Atsushi Akisawa; Takahiko Miyazaki; Yuki Ueda; Marlinda; Aep Saepul Uyun

    2010-01-01

    A numerical investigation of the double-effect adsorption refrigeration cycle is examined in this manuscript. The proposed cycle is based on the cascading adsorption cycle, where condensation heat that is produced in the top cycle is utilized as the driving heat source for the bottom cycle. The results show that the double-effect cycle produces a higher coefficient of performance (COP) as compared to that of the conventional single-stage cycle for driving temperatures between 100 °C and 150 ...

  7. Investigation on Adsorption State of Surface Adsorbate on Silicon Wafer

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    An adsorption kinetics model for adsorbate on the specularly polished silicon wafer was suggested. The mathematical model of preferential adsorption and the mechanism controlling the adsorption state of adsorbate were discussed.

  8. Adsorption of ferrous ions onto montmorillonites

    Energy Technology Data Exchange (ETDEWEB)

    Qin, Dawei, E-mail: qdw109@163.com [Qilu University of Technology, Jinan, 250353, Shandong (China); Niu, Xia [Qilu University of Technology, Jinan, 250353, Shandong (China); Qiao, Min; Liu, Gang; Li, Hongxin; Meng, Zhenxiao [Shandong SiBang pharmaceutical co., LTD, Jinan, Shandong, 250200 (China)

    2015-04-01

    Highlights: • Adsorption study of ferrous ions on montmorillonites. • Using ascorbic acid as antioxidants in adsorption process. • Fe (II)-MMT had good affinity for phosphate. - Abstract: The adsorption of Fe (II) onto montmorillonites was investigated through initial concentration, contact time, pH and temperature. During the whole adsorption process, the ascorbic acid (Vitamin C) was added as a kind of antioxidant, at the same time, deionized water (after boiling) and nitrogen protection were also used to avoid oxidation. The Fe{sup 2+}/Fe{sub total} ratio of the iron exists in the Fe-montmorillonites was found more than 95%. Two kinetic models, including pseudo-first-order and pseudo-second-order model, were used to analyze the adsorption process of Fe (II) on montmorillonites. The results of our study showed that adsorption process fitted with pseudo-second-order well. Adsorption isotherms showed that Langmuir model was better than Freundlich model. The thermodynamic parameters ΔG{sup 0} and ΔH{sup 0} were 3.696 kJ/mol and 6.689 kJ/mol (we just gave the values at 298 K), respectively. The positive values at different temperatures showed that the adsorption process was non-spontaneous and endothermic. The characteristics of materials were determined by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), Surface area and porosity analyzer, Thermogravimetric analysis (TGA), Differential scanning calorimeter (DSC) and Zeta potential distribution.

  9. Adsorption of Chlortetracycline from Water by Rectories

    Institute of Scientific and Technical Information of China (English)

    吕国诚; 吴丽梅; 王晓龙; 廖立兵; 王小雨

    2012-01-01

    The removal of antibiotics from water by clay minerals has become the focus of research due to their strong adsorptive ability. In this study, adsorption of chlortetracycline (CTC) onto rectories was conducted and the effects of time, concentration, temperature and pH were investigated. Experimental results showed that adsorption equilibrium was reached in 8 h. Based on the Langmuir model, the maximum adsorption capacity of CTC on rectories was 177.7 mg·g 1 at room temperature. By the study on adsorption dynamics, it is found that the kinetic date fit the pseudo-second-order model well. The adsorption of CTC by rectories is endothermic and the free energy is in the range of 10 to 30 kJ·mol 1 . The pH value of solution has significant effects on adsorption and the optimal pH is at acidity (pH 2-6). At concentration of 2500 mg·L 1 , the intercalated CTC produces an interlayer space with a height of 1.38 nm, which is 1.12 nm in raw rectories, suggesting that the adsorption occurs between layers of rectories.

  10. Kinetics of polymer adsorption, desorption and exchange.

    NARCIS (Netherlands)

    Dijt, J.C.

    1993-01-01

    The aim of the study in this thesis was to gain more insight in the kinetics of polymer adsorption. To this end some well-characterised polymers have been systematically investigated.In the process of polymer adsorption one may distinguish three kinetic contributions: transport to the surface, attac

  11. Adsorption of arsenic and boron by soil

    Energy Technology Data Exchange (ETDEWEB)

    Sakata, M.

    1986-01-01

    The author reports a study of the soil adsorption of As (trivalent) and B leached from coal ash. It has been found that the amount of adsorption is greatly affected by the pH of the solution. Maximum adsorption of As occurred from solutions with pH of about 8, while pH 8-9 resulted in maximum B adsorption. Furthermore, the As adsorption is related to the quantity of iron oxides and hydrated iron oxides in the soil, while the adsorption of B is related to the quantity of hydrated aluminium oxides and allophanes. Within the range of concentrations studied, the adsorption isotherm for As obeyed the Langmuir equation, and the B isotherm, that of Freundlich. At low concentrations, both elements conform to the Henry adsorption isotherm. The author also reports that the impact on ground water of elements such as As and B leached from coal ash can be conveniently predicted or evaluated by means of a diffusive flow model. 30 references, 14 figures, 3 tables.

  12. Adsorption Kinetic of 8-Hydroxyquinoline on Malachite

    OpenAIRE

    Oprea, Gabriela; Angela MICHNEA; Mihali, Cristina

    2007-01-01

    Influence of temperature and collector concentration on its adsorption rate on mineral surface was studied as regarding to the 8-hydroxyquinoline/malachite system. Theoretical equations as well as experimental data may be useful to estimate the adsorption rate and kinetics connected to the conditioning stage in mineral flotation in order to optimise the selectivity and the recovery of the desired mineral.

  13. Molecular Simulation of Adsorption in Microporous Materials

    OpenAIRE

    Yiannourakou M.; Ungerer P.; Leblanc B.; Rozanska X.; Saxe P.; Vidal-Gilbert S.; Gouth F.; Montel F.

    2013-01-01

    The development of industrial software, the decreasing cost of computing time, and the availability of well-tested forcefields make molecular simulation increasingly attractive for chemical engineers. We present here several applications of Monte-Carlo simulation techniques, applied to the adsorption of fluids in microporous solids such as zeolites and model carbons (pores < 2 nm). Adsorption was computed in the Grand Canonical ensemble ...

  14. Study on copper adsorption on olivine

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The copper adsorption on olivine supplied by A/S Olivine production plant at Aheim in western Norway has been studied. The factors which affect the uptake of copper have been evaluated. The results reveal that the equilibrium pH in aqueous solution has the greatest influence on the copper adsorption thanks to the competitive adsorption between proton and copper ions, and the adsorption of copper to olivine increases rapidly with the pH increasing from 4 to 6. The initial copper concentration and olivine dose also possess significant effect on copper adsorption. The adsorption efficieny of copper increases with the increase of olivine dose or the decrease of initial copper concentration at the same pH. The ionic strength effect on the adsorption has also been investigated, but it owns little effect on the adsorption process of copper due to the formation of inner sphere surface complexation of copper on olivine. The experimental data show that olivine has a high acid buffer capacity and is an effective adsorbent for copper.

  15. Adsorption Properties of the Cu(115) Surface

    DEFF Research Database (Denmark)

    Godowski, P. J.; Groso, A.; Hoffmann, S. V.;

    2010-01-01

    in context of substrate geometry and compared with the ones of other copper planes. There are no indications of dissociative adsorption of CO, only residual carbon and oxygen were found after adsorbate desorption around 220 K. CO molecules show a strong tendency to "on top" adsorption in sites far from...

  16. Surfactant adsorption to soil components and soils

    NARCIS (Netherlands)

    Ishiguro, Munehide; Koopal, Luuk K.

    2016-01-01

    Soils are complex and widely varying mixtures of organic matter and inorganic materials; adsorption of surfactants to soils is therefore related to the soil composition. We first discuss the properties of surfactants, including the critical micelle concentration (CMC) and surfactant adsorption on

  17. 银离子交换树脂π-络合吸附分离乙烯乙烷的研究%Study of Adsorptive Ethylene/Ethane Separation with Ag+-Exchanged Resins via π-Complexation

    Institute of Scientific and Technical Information of China (English)

    吴忠标; 刘越

    2002-01-01

    Ag+-exchanged resins are prepared and studied for ethylene/ethane separation by adsorption. OnAg+-exchanged S9, at 25℃ and 0.1013 MPa, the equilibrium adsorbed amount for C2H4 is 0.992 mmol.g-1, andthe adsorption ratio for C2H4/C2H6 is 3.56. The adsorption capacity can be restored almost completely at 25℃and 75℃, and the desorption residual amount is less than 0.01 mmol.g-1. For the adsorption consisting of physicaladsorption and π-complexation with energy heterogeneity, the equilibrium data are correlated with Langmuir-Freundlich isotherm equation. Furthermore, the heat of adsorption and the overall diffusion time constants arecalculated from the experimental data. Considering all the adsorption characteristics, the application potential forindustrial adsorption process is discussed.

  18. Heat exchanger

    Energy Technology Data Exchange (ETDEWEB)

    Craig, L.B.; Farma, A.J.

    1987-01-06

    This invention concerns a heat exchanger as used in a space heater, of the type in which hot exhaust gases transfer heat to water or the like flowing through a helical heat exchange coil. A significant improvement to the efficiency of the heat exchange occurring between the air and water is achieved by using a conduit for the water having external helical fluting such that the hot gases circulate along two paths, rather than only one. A preferred embodiment of such a heat exchanger includes a porous combustion element for producing radiant heat from a combustible gas, surrounded by a helical coil for effectively transferring the heat in the exhaust gas, flowing radially from the combustion element, to the water flowing through the coil. 4 figs.

  19. Effective adsorption of phosphate from wastewaters by big composite pellets made of reduced steel slag and iron ore concentrate.

    Science.gov (United States)

    Wang, Hongjuan; Shen, Shaobo; Liu, Longhui; Ji, Yilong; Wang, Fuming

    2015-01-01

    In order to remove phosphate from wastewater, a large plastic adsorption column filled with big phosphate-adsorbing pellets with diameters of 10 mm, heated by electromagnetic induction coils, was conceived. It was found that the prepared big pellets, which were made of reduced steel slag and iron ore concentrate, contain magnetic Fe and Fe3O4. The thermodynamics and kinetics of adsorption of phosphate from synthetic wastewaters on the pellets were studied in this work. The phosphate adsorption on the pellets followed three models of Freundlich, Langmuir and Dubinin-Kaganer-Radushkevick. The maximum phosphate adsorption capacity Qmax of the pellets were 2.46, 2.74 and 2.77 mg/g for the three temperatures of 20°C, 30°C and 40°C, respectively, based on the Langmuir model. The apparent adsorption energies were -12.9 kJ/mol for the three temperatures. It implied that ion exchange was the main mechanism involved in the adsorption processes. The adsorbed phosphate existed on the pellet surface mainly in the form of Fe3(PO4)2. A reduction pre-treatment of the pellet precursor with H2 greatly enhanced pellet adsorption for phosphate. The adsorption kinetics is better represented by a pseudo-first-order model. The adsorbed phosphate amounts were similar for both real and synthetic wastewaters under similar adsorption conditions. The percentage of adsorbed phosphate for a real wastewater increased with increasing pellet concentration and reached 99.2% at a pellet concentration of 64 (g/L). Some specific phosphate adsorption mechanisms for the pellets were revealed and the pellets showed the potential to efficiently adsorb phosphate from a huge amount of real wastewaters in an industrial scale.

  20. Adsorption kinetics of methyl violet onto perlite.

    Science.gov (United States)

    Doğan, Mehmet; Alkan, Mahir

    2003-01-01

    This study examines adsorption kinetics and activation parameters of methyl violet on perlite. The effect of process parameters like contact time, concentration of dye, temperature and pH on the extent of methyl violet adsorption from solution has been investigated. Results of the kinetic studies show that the adsorption reaction is first order with respect to dye solution concentration with activation energy of 13.2 kJ mol(-1). This low activation energy value indicates that the adsorption reaction is diffusion controlled. The activation parameters using Arrhenius and Eyring equations have been calculated. Adsorption increases with increase of variables such as contact time, initial dye concentration, temperature and pH.

  1. Theoretical study of adsorption of water vapor on surface of metallic uranium

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    According to the experimental data, there is an intermediate substance that formed in the initial stage of oxidation reaction when water vapor is absorbed onto the metallic uranium. The minimum energy of UOH2 wich C2v configuration is obtained in the state of 5A1 by B3LYP method of the density function theory (DFT), which is consistent with that by statics of atoms and molecules reaction (AMRS) and group theory. The results from calculations indicate that the adsorption of water vapor on the metallic uranium is an exothermic reaction and that the adsorbed amount decreases with the elevated temperatures. The adsorptive heat at 1 atm is -205.474 7 kJ.mol-1, which indicates a typical chemical adsorption.

  2. Effect of purity on adsorption capacities of a Mars-like clay mineral at different pressures

    Science.gov (United States)

    Jenkins, Traci; Mcdoniel, Bridgett; Bustin, Roberta; Allton, Judith H.

    1992-01-01

    There has been considerable interest in adsorption of carbon dioxide on Marslike clay minerals. Some estimates of the carbon dioxide reservoir capacity of the martian regolith were calculated from the amount of carbon dioxide adsorbed on the ironrich smectite nontronite under martian conditions. The adsorption capacity of pure nontronite could place upper limits on the regolith carbon dioxide reservoir, both at present martian atmospheric pressure and at the postulated higher pressures required to permit liquid water on the surface. Adsorption of carbon dioxide on a Clay Mineral Society standard containing nontronite was studied over a wide range of pressures in the absence of water. Similar experiments were conducted on the pure nontronite extracted from the natural sample. Heating curves were obtained to help characterize and determine the purity of the clay sample.

  3. Experimental Adsorption Isotherm of Methane onto Activated Carbon at Sub- and Supercritical Temperatures

    KAUST Repository

    Rahman, Kazi Afzalur

    2010-11-11

    This paper presents the experimentally measured adsorption isotherm data for methane onto the pitch-based activated carbon type Maxsorb III for temperatures ranging from (120 to 220) K and pressures up to 1.4 MPa. These data are useful to study adsorbed natural gas (ANG) storage systems when the low temperature natural gas regasified from the liquid phase is considered to charge in the storage chamber. Adsorption parameters were evaluated from the isotherm data using the Tóth and Dubinin-Astakhov models. The isosteric heat of adsorption, which is concentration- and temperature-dependent, is extracted from the data. The Henry\\'s law coefficients for the methane/Maxsorb III pairs are evaluated at various temperatures. © 2010 American Chemical Society.

  4. Insolubilization of Chestnut Shell Pigment for Cu(II Adsorption from Water

    Directory of Open Access Journals (Sweden)

    Zeng-Yu Yao

    2016-03-01

    Full Text Available Chestnut shell pigment (CSP is melanin from an agricultural waste. It has potential as an adsorbent for wastewater treatment but cannot be used in its original state because of its solubility in water. We developed a new method to convert CSP to insolubilized chestnut shell pigment (ICSP by heating, and the Cu(II adsorption performance of ICSP was evaluated. The conversion was characterized, and the thermal treatment caused dehydration and loss of carboxyl groups and aliphatic structures in CSP. The kinetic adsorption behavior obeyed the pseudo-second-order rate law, and the equilibrium adsorption data were well described with both the Langmuir and the Freundlich isotherms. ICSP can be used as a renewable, readily-available, easily-producible, environmentally-friendly, inexpensive and effective adsorbent to remove heavy-metal from aquatic environments.

  5. 3D hierarchical porous graphene aerogels for highly improved adsorption and recycled capacity

    Energy Technology Data Exchange (ETDEWEB)

    Chi, Caixia [School of Chemical Engineering and Technology, Harbin Institute of Technology, Xida Zhi street 92, Harbin 150001 (China); Food and Pharmaceutical Engineering College, Suihua University, Suihua 152061 (China); Xu, Hongbo [School of Chemical Engineering and Technology, Harbin Institute of Technology, Xida Zhi street 92, Harbin 150001 (China); Zhang, Ke, E-mail: zhangke@hit.edu.cn [School of Chemical Engineering and Technology, Harbin Institute of Technology, Xida Zhi street 92, Harbin 150001 (China); Wang, Yibo [School of Chemical Engineering and Technology, Harbin Institute of Technology, Xida Zhi street 92, Harbin 150001 (China); Zhang, Shuanghu [Food and Pharmaceutical Engineering College, Suihua University, Suihua 152061 (China); Liu, Xusong; Liu, Xin; Zhao, Jiupeng [School of Chemical Engineering and Technology, Harbin Institute of Technology, Xida Zhi street 92, Harbin 150001 (China); Li, Yao, E-mail: yaoli@hit.edu.cn [Center for Composite Materials, Harbin Institute of Technology, Harbin 150001 (China)

    2015-04-15

    Graphical abstract: - Highlights: • 3D HGAs were prepared by a “fishing” process. • Their porous morphologies were varied by changing of PS particles. • HGAs are used as adsorbents for removal of oils and organic solvents. • They exhibit highly improved adsorption and recycled capacity. - Abstract: This article demonstrates the fabrication of 3D hierarchical porous graphene aerogels (HGAs) with tunable porous architecture by a “fishing” process with polystyrene (PS) particles as sacrificial templates. Structure and morphology were characterized by X-ray diffraction (XRD), Raman spectroscopy, and scanning electron microscopy (SEM), respectively. The 3D HGAs exhibits low density, super hydrophobicity, high porosity and good thermal stability, which were used as adsorbents for removal of oils and organic solvents, showing highly efficient adsorption. In addition, they could be regenerated by heat treatment to release the adsorbates. After eight toluene-adsorbing and drying recycles, the adsorption capacity of HGAs reaches 93% of the initial uptake.

  6. Experimental investigation of a small-scale thermally driven pressurized adsorption chiller

    KAUST Repository

    Loh, Waisoong

    2015-01-01

    This paper describes the successful operation of an adsorption cycle in a miniaturized adsorption chiller (AD). The experiments show that the bench-scale pressurized adsorption chiller (PAC) has been successfully designed, commissioned, and tested. Experimental results at various heat fl uxes, half-cycle operation time intervals, and a cooling load of up to 24 W are also presented. A COP ranging from 0.05 to 0.15 is achieved depending on the parameters of the experimental conditions. Most importantly, the cooling performance of the PAC is achieved at a low encasement temperature that is below ambient. Besides having a high cooling density, the PAC has almost no major moving parts except for the fan of the condenser and it permits quiet operation as compared to other active coolers.

  7. ADSORPTION OF PROTEIN ON NANOPARTICLES

    Institute of Scientific and Technical Information of China (English)

    WU Qi

    1994-01-01

    The adsorption of protein on nanoparticles was studied by using dynamic light scattering to measure the hydrodynamic size of both pure protein and nanoparticles adsorbed with different amounts of protein. The thickness of the adsorbed protein layer increases as protein concentration, but decreases as the initial size of nanoparticles. After properly scaling the thickness with the initial diameter, we are able to fit all experimental data with a single master curve. Our experimental results suggest that the adsorbed proteins form a monolayeron the nanoparticle surface and the adsorbed protein molecules are attached to the particle surface at many points through a possible hydrogen-bonding. Our results also indicate that as protein concentration increases, the overall shape of the adsorbed protein molecule continuously changes from a flat layer on the particle surface to a stretched coil extended into water. During the change, the hydrodynamic volume of the adsorbed protein increases linearly with protein concentration.

  8. Adsorption on the carbon nanotubes

    Institute of Scientific and Technical Information of China (English)

    DING Yi; YANG Xiao-bao; NI Jun

    2006-01-01

    Adsorption on single walled carbon nanotubes (SWCNTs) is a subject of growing experimental and theoretical interest.The possible adsorbed patterns of atoms and molecules on the single-walled carbon nanotubes vary with the diameters and chirality of the tubes due to the confinement.The curvature of the carbon nanotube surface enlarges the distance of the adsorbate atoms and thus enhances the stability of high coverage structures of adsorbate.There exist two novel high-coverage stable structures of potassium adsorbed on SWCNTs,which are not stable on graphite.The electronic properties of SWCNTs can be modified by adsorbate atoms and metal-semiconductor and semiconductor-semi-conductor transitions can be achieved by the doping of alkali atoms.

  9. MATHEMATICAL MODELLING OF HEAT AND MASS TRANSFER DURING ADSORPTION-CONTACT DRYING OF CERAMIC MATERIALS (COMPUTING EXPERIMENT Математическое моделирование тепло- и массопереноса при адсорбционно-контактной сушке керамических материалов (вычислительный эксперимент

    Directory of Open Access Journals (Sweden)

    Dornyak O. R.

    2013-05-01

    Full Text Available One-temperature limited version of the general model of adsorption-contact drying for the ceramic brick is considered. Numerical modeling of heat and mass transfer in the donor and the acceptor samples for one-dimensional approach is carried out. It is shown, in particular, that the moisture diffusion coefficient of material in the contact zone can vary significantly due to changes in the conditions for liquid-phase transfer

  10. An entropy generation and genetic algorithm optimization of two-bed adsorption cooling cycle

    KAUST Repository

    Myat, Aung

    2011-09-28

    This article presents the performance analysis of adsorption cooling, shortly AD, system using a thermodynamic framework with an entropy generation analysis. The model captures the transient and the cyclic steady-state performances of the adsorption-desorption cycles operating under assorted heat source temperatures. Type-RD silica gel, with a pore surface area of 720 m2/g and diameters 0.4-0.7 mm, is used as an adsorbent and its high affinity for thewater vapour adsorbate gives a high equilibrium uptake. The key advantages of the AD are (a) it has no moving parts rendering less maintenance and (b) the energy efficient means of cooling by the adsorption process with a low-temperature heat source and (c) it is environmental friendly with low carbon footprint. By incorporating the genetic algorithm onto the entropy minimization technique, it is possible to locate the optimal system performance point or the global minima with respect to entropy generation using the system parameters such as coolant and heat source water temperatures, heat transfer areas, etc. The system analysis shows that the minimization of entropy generation in the AD cycle leads to the maximization of the coefficient of performance and this translates into a higher delivery of useful cooling effects at the particular input resource temperature. © Authors 2011.

  11. Silicagel-water adsorption cooling prototype system for mobile air conditioning

    Energy Technology Data Exchange (ETDEWEB)

    De Boer, R.; Smeding, S.F.; Mola, S. [ECN Efficiency and Infrastructure, Petten (Netherlands)

    2009-09-15

    A prototype adsorption cooling system was developed for the purpose of on-board test of mobile air conditioning driven by waste heat from the engine. The system was designed, constructed and first tested in the laboratory of ECN. The performance under various static operating conditions was determined in the laboratory. The system can produce 2 kW of chilling power with a COP of 0.4. The prototype was afterward installed in the Fiat Grande Punto demonstration car by CRF. The system was connected to the heating and cooling systems of the car and tested. The performance in the car was comparable to the performance in the lab, indicating that system integration was successful. A waste heat driven adsorption cooling system can be applied for comfort cooling purposes in a car. The amount of waste heat that is freely available in the engine coolant circuit as well as its temperature level is sufficient to drive the adsorption cooling system and to produce enough cold to keep comfortable interior temperatures.

  12. Kinetics, thermodynamics and surface heterogeneity assessment of uranium(VI) adsorption onto cation exchange resin derived from a lignocellulosic residue

    International Nuclear Information System (INIS)

    A new cation exchange resin (PGTFS-COOH) having a carboxylate functional group at the chain end was prepared by grafting poly(hydroxyethylmethacrylate) onto tamarind fruit shell, TFS (a lignocellulosic residue) using potassium peroxydisulphate-sodium thiosulphate redox initiator, and in the presence of N,N'-methylenebisacrylamide (MBA) as a crosslinking agent, followed by functionalisation. The adsorbent was characterized with the help of FTIR, XRD, scanning electron micrographs (SEM), and potentiometric titrations. The kinetic and isotherm data, obtained at optimum pH value 6.0 at different temperatures could be fitted with pseudo-second-order equation and Sips isotherm model, respectively. An increase in temperature induces positive effect on the adsorption process. The calculated activation energy of adsorption (Ea, 18.67 kJ/mol) indicates that U(VI) adsorption was largely due to diffusion-controlled process. The values of adsorption enthalpy, Gibbs free energy, and entropy were calculated using thermodynamic function relationships. The decrease in adsorption enthalpy with increasing U(VI) uploading on the adsorbent, reflects the surface energetic heterogeneity of the adsorbent. The isosteric heat of adsorption was quantitatively correlated with the fractional loading for the U(VI) ions adsorption onto PGTFS-COOH. The results showed that the PGTFS-COOH possessed heterogeneous surface with sorption sites having different activities.

  13. Modeling the adsorption of mixed gases based on pure gas adsorption properties

    Science.gov (United States)

    Tzabar, N.; Holland, H. J.; Vermeer, C. H.; ter Brake, H. J. M.

    2015-12-01

    Sorption-based Joule-Thomson (JT) cryocoolers usually operate with pure gases. A sorption-based compressor has many benefits; however, it is limited by the pressure ratios it can provide. Using a mixed-refrigerant (MR) instead of a pure refrigerant in JT cryocoolers allows working at much lower pressure ratios. Therefore, it is attractive using MRs in sorption- based cryocoolers in order to reduce one of its main limitations. The adsorption of mixed gases is usually investigated under steady-state conditions, mainly for storage and separation processes. However, the process in a sorption compressor goes through various temperatures, pressures and adsorption concentrations; therefore, it differs from the common mixed gases adsorption applications. In order to simulate the sorption process in a compressor a numerical analysis for mixed gases is developed, based on pure gas adsorption characteristics. The pure gas adsorption properties have been measured for four gases (nitrogen, methane, ethane, and propane) with Norit-RB2 activated carbon. A single adsorption model is desired to describe the adsorption of all four gases. This model is further developed to a mixed-gas adsorption model. In future work more adsorbents will be tested using these four gases and the adsorption model will be verified against experimental results of mixed-gas adsorption measurements.

  14. Arsenic Adsorption Equilibrium Concentration and Adsorption Rate of Activated Carbon Coated with Ferric-Aluminum Hydroxides

    Science.gov (United States)

    Zhang, M.; Sugita, H.; Oguma, T.; Hara, J.; Takahashi, S.

    2015-12-01

    In some areas of developing countries, ground or well water contaminated with arsenic has been reluctantly used as drinking water. It is highly desirable that effective and inexpensive arsenic removal agents should be developed and provided to reduce the potential health risk. Previous studies demonstrated that activated carbon coated with ferric-aluminum hydroxides (Fe-Al-C) has high adsorptive potential for removal of arsenic. In this study, a series of experiments using Fe-Al-C were carried to discuss adsorption equilibrium time, adsorption equilibrium concentration and adsorption rate of arsenic for Fe-Al-C. Fe-Al-C used in this study was provided by Astec Co., Ltd. Powder reagent of disodium hydrogen arsenate heptahydrate was dissolved into ion-exchanged water. The solution was then further diluted with ion-exchanged water to be 1 and 10 mg/L as arsenic concentration. The pH of the solution was adjusted to be around 7 by adding HCl and/or NaOH. The solution was used as artificial arsenic contaminated water in two types of experiments (arsenic adsorption equilibrium and arsenic adsorption rate tests). The results of the arsenic equilibrium tests were showed that a time period of about 3 days to reach apparent adsorption equilibrium for arsenic. The apparent adsorption equilibrium concentration and adsorbed amount of arsenic on Fe-Al-C adsorbent could be estimated by application of various adsorption isotherms, but the distribution coefficient of arsenic between solid and liquid varies with experimental conditions such as initial concentration of arsenic and addition concentration of adsorbent. An adsorption rate equation that takes into account the reduction in the number of effective adsorption sites on the adsorbent caused by the arsenic adsorption reaction was derived based on the data obtained from the arsenic adsorption rate tests.

  15. Adsorption of Iminodiacetic Acid Resin for Lutetium

    Institute of Scientific and Technical Information of China (English)

    熊春华; 姚彩萍; 王惠君

    2004-01-01

    The adsorption behavior and mechanism of a novel chelate resin,iminodiacetic acid resin(IDAAR) for Lu(Ⅲ) were investigated.The statically saturated adsorption capacity is 210.8 mg·g-1 at 298 K in HAc-NaAc medium.The Lu(Ⅲ) adsorbed on IDAAR can be eluted by 0.5 mol·L-1 HCl and the elution percentage reaches 96.5%.The resin can be regenerated and reused without obvious decrease in adsorption capacity.The apparent adsorption rate constant is k298=2.0×10-5 s-1.The adsorption behavior of IDAAR for Lu(Ⅲ) obeys the Freundlich isotherm.The thermodynamic adsorption parameters,enthalpy change ΔH,free energy change ΔG and entropy change ΔS of IDAAR for Lu(Ⅲ) are 13.1 kJ·mol-1,-1.37 kJ·mol-1 and 48.4 J·mol-1·K-1,respectively.The apparent activation energy is Ea=31.3 kJ·mol-1.The molar coordination ratio of the functional group of IDAAR to Lu(Ⅲ) is about 3∶1.The adsorption mechanism of IDAAR for Lu(Ⅲ) was examined by chemical method and IR spectrometry.

  16. Application of zeolitic materials prepared from fly ash to water vapor adsorption for solar cooling

    International Nuclear Information System (INIS)

    Highlights: ► Water vapor isotherms of lignite ash are of type III with low adsorption capacity. ► Mild fly ash hydrothermal treatment produces a hydrophilic zeolitic material. ► The zeolitic material exhibits a type IV water vapor adsorption isotherm. ► Under irradiation, its surface temperature is reduced due to water desorption. ► Potential application of the fly ash zeolitic material for solar cooling. -- Abstract: The water vapor adsorption properties of raw and hydrothermally treated fly ashes with NaOH and their application prospect as evaporative coolers of roof surfaces were studied. Initially, samples were characterized through techniques like elemental analysis, X-ray diffraction, thermogravimetry, reflectance measurements and water vapor adsorption isotherms. Moreover, the water adsorption properties and the associated temperature variations were determined in a specific wind tunnel with controllable environmental conditions. The adsorption isotherms for fly ash were of type III indicating hydrophobic material with low water vapor adsorption. The hydrothermal treatment in an alkaline solution transformed the fly ash in hydrophilic material of type IV. Moreover, the treated samples were capable of lowering their surface temperatures due to water evaporation and the release of the latent heat. The maximum difference of temperature increase under simulated solar irradiation was observed between the treated fly ash and the concrete with values of 5.0, 5.4 and 7.5 °C for the surface, middle and bottom position, respectively. The results indicate that the zeolitic materials prepared from the fly ash samples have a significant potential for solar cooling applications.

  17. Synthesis, structural elucidation and carbon dioxide adsorption on Zn (II) hexacyanoferrate (II) Prussian blue analogue

    Science.gov (United States)

    Roque-Malherbe, R.; Lugo, F.; Polanco, R.

    2016-11-01

    In the course of the last years hexacyanoferrates have been widely studied; even though, the adsorption properties of Zn (II) hexacyanoferrate(II) (labelled here Zn-HII) have not been thoroughly considered. In addition, soft porous crystals, i.e., adsorbents that display structural flexibility have been, as well, extensively studied, however this property has not been reported for Zn (II) hexacyanoferrate(II). In this regard, the key questions addressed here were the synthesis and structural characterization of Zn-HII together with the investigation of their low (up to 1 bar) and high pressure (up to 30 bar) adsorption properties, to found if these materials show structural flexibility. Then, to attain the anticipated goals, structural characterizations were made with: X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), diffuse reflectance infrared Fourier transform spectrometry (DRIFTS) and thermo-gravimetric analysis (TGA), simultaneously, with the investigation of the adsorption of carbon dioxide. As a result of the research process we concluded that the Zn-HII displayed Fm barm space group framework. Besides, the carbon dioxide adsorption investigation demonstrated the presence of the framework expansion effect together with an extremely high adsorption heat, properties that could be useful for the use of Zn(II) hexacyanoferrate(II) as an excellent adsorbent.

  18. Preparation, characterization and dye adsorption of Au nanoparticles/ZnAl layered double oxides nanocomposites

    Science.gov (United States)

    Zhang, Yu Xin; Hao, Xiao Dong; Kuang, Min; Zhao, Han; Wen, Zhong Quan

    2013-10-01

    In this work, Au/ZnAl-layer double oxides (LDO) nanocomposties were prepared through a facile calcination process of AuCl4- intercalated ZnAl-layered double hydroxides (LDHs) nanocomposites. The morphology and crystal structure of these nanocomposites were characterized by Scanning electron microscopy (SEM), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), and N2 sorption analysis. By tailoring the process parameter, such as calcination temperature, heating time and the component composition, the adsorption properties of methyl orange (MO) on the Au/ZnAl-LDO nanocomposites were investigated in this work. In a typical adsorption process, it was found that 0.985 mg of MO (0.01 g L-1, 100 mL, 1 mg of MO in total) can be removed in 60 min by utilizing only 2.5 mg of Au/ZnAl-LDO (Au content, 1%) as adsorbents. Our adsorption data obtained from the Langmuir model also gave good values of the determination coefficient, and the saturated adsorption capacity of Au/ZnAl-LDO nanocomposites for MO was found to be 627.51 mg/g under ambient condition (e.g., room temperature, 1 atm). In principle, these hybrid nanostructures with higher adsorption abilities could be very promising adsorbents for wastewater treatment.

  19. Preparation, characterization and dye adsorption of Au nanoparticles/ZnAl layered double oxides nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yu Xin, E-mail: zhangyuxin@cqu.edu.cn [College of Material Science and Engineering, Chongqing University, Chongqing 400044 (China); Key Laboratory of Fundamental Science of Micro/Nano-Devices and System Technology, Chongqing University, Chongqing 400044 (China); Hao, Xiao Dong; Kuang, Min [College of Material Science and Engineering, Chongqing University, Chongqing 400044 (China); Zhao, Han [School of Material Science and Engineering, Nanyang Technology University (NTU), 639875 Singapore (Singapore); Wen, Zhong Quan [Key Laboratory of Fundamental Science of Micro/Nano-Devices and System Technology, Chongqing University, Chongqing 400044 (China)

    2013-10-15

    In this work, Au/ZnAl-layer double oxides (LDO) nanocomposties were prepared through a facile calcination process of AuCl{sub 4}{sup −} intercalated ZnAl-layered double hydroxides (LDHs) nanocomposites. The morphology and crystal structure of these nanocomposites were characterized by Scanning electron microscopy (SEM), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), and N{sub 2} sorption analysis. By tailoring the process parameter, such as calcination temperature, heating time and the component composition, the adsorption properties of methyl orange (MO) on the Au/ZnAl-LDO nanocomposites were investigated in this work. In a typical adsorption process, it was found that 0.985 mg of MO (0.01 g L{sup −1}, 100 mL, 1 mg of MO in total) can be removed in 60 min by utilizing only 2.5 mg of Au/ZnAl-LDO (Au content, 1%) as adsorbents. Our adsorption data obtained from the Langmuir model also gave good values of the determination coefficient, and the saturated adsorption capacity of Au/ZnAl-LDO nanocomposites for MO was found to be 627.51 mg/g under ambient condition (e.g., room temperature, 1 atm). In principle, these hybrid nanostructures with higher adsorption abilities could be very promising adsorbents for wastewater treatment.

  20. Accurate fit and thermochemical analysis of the adsorption isotherms of methane in zeolite 13X

    Energy Technology Data Exchange (ETDEWEB)

    Llano-Restrepo, M. [University of Valle, Valle (Colombia). School of Chemical Engineering

    2010-07-01

    The recovery of methane from landfill gases and coal mines has become of the utmost importance because methane has a global-climate warming potential much higher than that of carbon dioxide. Zeolite 13X is widely used for the separation of methane and carbon dioxide from such sources. Accurate fits of the adsorption isotherms of methane in zeolite 13X are required for the rigorous simulation of that separation. In this work, a generalized statistical thermodynamic adsorption (GSTA) model has been used to obtain a very accurate correlation of a published set of adsorption isotherms of methane in zeolite 13X that were measured from 120 K to 273 K over the pressure range 0.07 Pa to 12.2 MPa. In contrast, none of five traditional adsorption models was capable of fitting these isotherms. A thermochemical interpretation of the correlation is provided and predictions for the isosteric heat of adsorption are made, which turn out to be in excellent agreement with the available experimental data.

  1. Experimental comparison of adsorption characteristics of silica gel and zeolite in moist air

    Science.gov (United States)

    Xin, F.; Yuan, Z. X.; Wang, W. C.; Du, C. X.

    2016-05-01

    In this work, the macro adsorption characteristic of water vapor by the allochroic silica gel and the zeolite 5A and ZSM-5 were investigated experimentally. BET analysis method presented the difference of the porosity, the micro pore volume, and the specific surface area of the material. The dynamic and the equilibrium characteristics of the sample were measured thermo-gravimetrically in the moist air. In general, the ZSM-5 zeolite showed an inferior feature of the adsorption speed and the equilibrium concentration to the others. By comparison to the result of SAPO-34 zeolite in the open literature, the 5A zeolite showed some superiorities of the adsorption. The equilibrium concentration of the ZSM-5 zeolite was higher than that of the SAPO-34 calcined in the nitrogen, whereas it was lower than that calcined in the air. The adsorption isotherm was correlated and the relation of the isotherm to the microstructure of the material was discussed. With more mesopore volume involved, the zeolite presented an S-shaped isotherm in contrast to the exponential isotherm of the silica gel. In addition, the significance of the S-shaped isotherm for the application in adsorption heat pump has also been addressed.

  2. Thermodynamics and kinetics of cadmium adsorption onto oxidized granular activated carbon

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Cadmium sorption behavior of granular activated carbon oxidized with nitric acid was systematically studied by sets of the equilibrium and time-based experiments under various conditions. The cadmium adsorption capacity of oxidized granular activated carbon enlarged with an increase in pH, and reduced with an increase in ionic strength. Experimental data were evaluated to find out kinetic characteristics. Adsorption processes were found to follow pseudo-second order rate equation. Adsorption isotherms correlate well with the Langmuir isotherm model and the maximum sorption capacity of cadmium evaluated is 51.02 μmol/g. Thermodynamic parameters were calculated based on Van't Hoff equation. Equilibrium constant Kd was evaluated from Freundlich isotherm model constants, Langmuir isotherm model constants and isotherms, respectively. The average change of standard adsorption heat ΔHo is -25.29 kJ/mol. Negative ΔHo and ΔGo values indicate the adsorption process for cadmium onto the studied activated carbon is exothermic and spontaneous. The standard entropy ΔSo is also negative, which suggests a decrease in the freedom of the system.

  3. Comparative study of carbon nanotubes and granular activated carbon: Physicochemical properties and adsorption capacities.

    Science.gov (United States)

    Gangupomu, Roja Haritha; Sattler, Melanie L; Ramirez, David

    2016-01-25

    The overall goal was to determine an optimum pre-treatment condition for carbon nanotubes (CNTs) to facilitate air pollutant adsorption. Various combinations of heat and chemical pre-treatment were explored, and toluene was tested as an example hazardous air pollutant adsorbate. Specific objectives were (1) to characterize raw and pre-treated single-wall (SW) and multi-wall (MW) CNTs and compare their physical/chemical properties to commercially available granular activated carbon (GAC), (2) to determine the adsorption capacities for toluene onto pre-treated CNTs vs. GAC. CNTs were purified via heat-treatment at 400 °C in steam, followed by nitric acid treatment (3N, 5N, 11N, 16N) for 3-12 h to create openings to facilitate adsorption onto interior CNT sites. For SWNT, Raman spectroscopy showed that acid treatment removed impurities up to a point, but amorphous carbon reformed with 10h-6N acid treatment. Surface area of SWNTs with 3 h-3N acid treatment (1347 m(2)/g) was higher than the raw sample (1136 m(2)/g), and their toluene maximum adsorption capacity was comparable to GAC. When bed effluent reached 10% of inlet concentration (breakthrough indicating time for bed cleaning), SWNTs had adsorbed 240 mg/g of toluene, compared to 150 mg/g for GAC. Physical/chemical analyses showed no substantial difference for pre-treated vs. raw MWNTs. PMID:26476807

  4. Adsorption of gases on heterogeneous surfaces

    CERN Document Server

    Rudzinski, W

    1991-01-01

    All real solid surfaces are heterogeneous to a greater or lesser extent and this book provides a broad yet detailed survey of the present state of gas adsorption. Coverage is comprehensive and extends from basic principles to computer simulation of adsorption. Underlying concepts are clarified and the strengths and weaknesses of the various methods described are discussed.Key Features* Adsorption isotherm equations for various types of heterogeneous solid surfaces* Methods of determining the nature of surface heterogeneity and porosity from experimental data* Studies of pha

  5. Adsorption of lead over graphite oxide.

    Science.gov (United States)

    Olanipekun, Opeyemi; Oyefusi, Adebola; Neelgund, Gururaj M; Oki, Aderemi

    2014-01-24

    The adsorption efficiency and kinetics of removal of lead in presence of graphite oxide (GO) was determined using the Atomic Absorption Spectrophotometer (AAS). The GO was prepared by the chemical oxidation of graphite and characterized using FTIR, SEM, TGA and XRD. The adsorption efficiency of GO for the solution containing 50, 100 and 150 ppm of Pb(2+) was found to be 98%, 91% and 71% respectively. The adsorption ability of GO was found to be higher than graphite. Therefore, the oxidation of activated carbon in removal of heavy metals may be a viable option to reduce pollution in portable water.

  6. Thermodynamics of binary gas adsorption in nanopores.

    Science.gov (United States)

    Dutta, Sujeet; Lefort, Ronan; Morineau, Denis; Mhanna, Ramona; Merdrignac-Conanec, Odile; Saint-Jalmes, Arnaud; Leclercq, Théo

    2016-09-21

    MCM-41 nanoporous silicas show a very high selectivity for monoalcohols over aprotic molecules during adsorption of a binary mixture in the gas phase. We present here an original use of gravimetric vapour sorption isotherms to characterize the role played by the alcohol hydrogen-bonding network in the adsorption process. Beyond simple selectivity, vapour sorption isotherms measured for various compositions help to completely unravel at the molecular level the step by step adsorption mechanism of the binary system in the nanoporous solid, from the first monolayers to the complete liquid condensation. PMID:27532892

  7. Adsorption of Cadmium By Silica Chitosan

    OpenAIRE

    Moftah Ali; Ani Mulyasuryani; Akhmad Sabarudin

    2013-01-01

    The adsorption process depends on initial concentration of Cd2+ and ratio of  chitosan in adsorbent. The present study deals with the competitive adsorption of Cd2+ ion onto silica graft with chitosan. Batch adsorption experiments were performed at five different initial Cd2+ concentrations (5, 10, 15, 20 and 25 ppm), on five different proportion from silica to chitosan (100%, 95%, 85%, 75% and 65%) as adsorbent at pH 5. In the recovery process, the high recovery at 0.5 mg and observed the re...

  8. Adsorption affinity of anions on metal oxyhydroxides

    Science.gov (United States)

    Pechenyuk, S. I.; Semushina, Yu. P.; Kuz'mich, L. F.

    2013-03-01

    The dependences of anion (phosphate, carbonate, sulfate, chromate, oxalate, tartrate, and citrate) adsorption affinity anions from geometric characteristics, acid-base properties, and complex forming ability are generalized. It is shown that adsorption depends on the nature of both the anions and the ionic medium and adsorbent. It is established that anions are generally grouped into the following series of adsorption affinity reduction: PO{4/3-}, CO{3/2-} > C2O{4/2-}, C(OH)(CH2)2(COO){3/3-}, (CHOH)2(COO){2/2-} > CrO{4/2-} ≫ SO{4/2-}.

  9. Adsorption-Induced Deformation of Mesoporous Solids

    CERN Document Server

    Gor, Gennady Yu

    2010-01-01

    The Derjaguin - Broekhoff - de Boer theory of capillary condensation is employed to describe deformation of mesoporous solids in the course of adsorption-desorption hysteretic cycles. We suggest a thermodynamic model, which relates the mechanical stress induced by adsorbed phase with the adsorption isotherm. Analytical expressions are derived for the dependence of the solvation pressure on the vapor pressure. The proposed method provides a semi-quantitative description of non-monotonic hysteretic deformation during capillary condensation without invoking any adjustable parameters. The method is showcased drawing on the examples of literature experimental data on adsorption deformation of porous glass and SBA-15 silica.

  10. Numerical simulation and performance investigation of an advanced adsorption desalination cycle

    KAUST Repository

    Thu, Kyaw

    2013-01-01

    Low temperature waste heat-driven adsorption desalination (AD) cycles offer high potential as one of the most economically viable and environmental-friendly desalination methods. This article presents the development of an advanced adsorption desalination cycle that employs internal heat recovery between the evaporator and the condenser, utilizing an encapsulated evaporator-condenser unit for effective heat transfer. A simulation model has been developed based on the actual sorption characteristics of the adsorbent-adsorbate pair, energy and mass balances applied to the components of the AD cycle. With an integrated design, the temperature in the evaporator and the vapor pressurization of the adsorber are raised due to the direct heat recovery from the condenser, resulting in the higher water production rates, typically improved by as much as three folds of the conventional AD cycle. In addition, the integrated design eliminates two pumps, namely, the condenser cooling water and the chilled water pumps, lowering the overall electricity consumption. The performance of the cycle is analyzed at assorted heat source and cooling water temperatures, and different cycle times as well as the transient heat transfer coefficients of the evaporation and condensation. © 2012 Elsevier B.V.

  11. Albumin (BSA) Adsorption over Graphene in Aqueous Environment: Influence of Orientation, Adsorption Protocol, and Solvent Treatment.

    Science.gov (United States)

    Vilhena, J G; Rubio-Pereda, Pamela; Vellosillo, Perceval; Serena, P A; Pérez, Rubén

    2016-02-23

    We report 150 ns explicit solvent MD simulations of the adsorption on graphene of albumin (BSA) in two orientations and using two different adsorption protocols, i.e., free and forced adsorption. Our results show that free adsorption occurs with little structural rearrangements. Even taking adsorption to an extreme, by forcing it with a 5 nN downward force applied during the initial 20 ns, we show that along a particular orientation BSA is able to preserve the structural properties of the majority of its binding sites. Furthermore, in all the cases considered in this work, the ibuprofen binding site has shown a strong resilience to structural changes. Finally, we compare these results with implicit solvent simulations and find that the latter predicts an extreme protein unfolding upon adsorption. The origin of this discrepancy is attributed to a poor description of the water entropic forces at interfaces in the implicit solvent methods.

  12. Pt、Rh及Pt-Rh合金电极上氢的吸附%Hydrogen Adsorption on Pt, Rh and Pt-Rh Electrodes

    Institute of Scientific and Technical Information of China (English)

    贾梦秋; A.M.Meretskyi

    2005-01-01

    The hydrogen adsorption on Pt-Rh alloys in sulfuric acid aqueous solutions was studied by the method of cathode pulses. Hydrogen adsorption on the electrode with all ratio of alloy components (wRh = 0-100%) is well described by the Temkin logarithmic isotherm. The surface coverage by adsorbed hydrogen at the same potential is decreased with increasing content of rhodium in the system. A linear dependence of adsorption peak potential on the alloy compositions in the case of weakly bonded adsorbed hydrogen is established. Hydrogen adsorption heat as a function of surface coverage for Pt-Rh-electrodes was obtained. The shape of the current-potential curve and position of the weakly bonded hydrogen adsorption on the potential scale are all related to alloy compositions, thus can serve as the basis for the determination surface composition of alloys.

  13. Adsorption of neon and tetrafluoromethane on carbon nanohorn aggregates: differences in specific surface area values

    Science.gov (United States)

    Krungleviciute, Vaiva; Yudasaka, Masako; Iijima, Sumio; Migone, Aldo

    2008-03-01

    We have measured adsorption isotherms for two different adsorbates, neon and tetrafluoromethane, on dahlia-like carbon nanohorn aggregates. The experiments were performed at similar relative temperatures for both gases. The measurements were conducted to explore the effect of adsorbate diameter on the behavior of the resulting adsorbed systems. We measured the effective specific surface area value of the nanohorn sample using both gases, and we found that this quantity was about 22% smaller when we determined this quantity using tetrafluoromethane, the larger molecule. Isosteric heat and binding energy values were also determined from our measurements. We will compare our experimental results with those from a computer simulation study performed by Prof. M. Calbi. The simulations help us understand the source of the observed differences in the measured specific surface values, as well as the coverage dependence of the isosteric heat of adsorption for both gases.

  14. Analysis of irrationality of coal susceptibility to spontaneous combustion determination method with fluid oxygen adsorption

    Institute of Scientific and Technical Information of China (English)

    HE Qi-lin

    2008-01-01

    Based on experiment results and theoretical analysis,pointed out that the method of coal susceptibility to spontaneous combustion determination with fluid oxygen adsorption can not present the essence of coal oxidation process and oxidation reaction.The method is incorrect,paying attention at one aspect and ignoring the rest.The method is not reasonable for coal susceptibility to spontaneous combustion determination.Susceptibility to spontaneous combustion of coal reflects chemical property of coal oxidation with oxygen absorption and heat release at low temperature.Coal's susceptibility to spontaneous combustion is mainly decided by the number of molecules with reaction activation energy and activation molecule production rate at certain temperature.Therefore,index of susceptibility to spontaneous combustion should adopt accumulative value or trend of heat release or oxygen adsorption during oxidation process.

  15. Analysis of irrationality of coal susceptibility to spontaneous combustion determination method with fluid oxygen adsorption

    Institute of Scientific and Technical Information of China (English)

    HE Qi-lin

    2008-01-01

    Based on experiment results and theoretical analysis, pointed out that the method of coal susceptibility to spontaneous combustion determination with fluid oxygen adsorption can not present the essence of coal oxidation process and oxidation reaction. The method is incorrect, paying attention at one aspect and ignoring the rest. The method is not reasonable for coal susceptibility to spontaneous combustion determination. Sus-ceptibility to spontaneous combustion of coal reflects chemical property of coal oxidation with oxygen absorption and heat release at low temperature. Coal's susceptibility to spon-taneous combustion is mainly decided by the number of molecules with reaction activation energy and activation molecule production rate at certain temperature. Therefore, index of susceptibility to spontaneous combustion should adopt accumulative value or trend of heat release or oxygen adsorption during oxidation process.

  16. Molecular Simulation of Hydrogen Adsorption Density in Single-Walled Carbon Nanotubes and Multilayer Adsorption Mechanism

    Institute of Scientific and Technical Information of China (English)

    Lianquan GUO; Changxiang MA; Shuai WANG; He MA; Xin LI

    2005-01-01

    The adsorption of hydrogen onto single-walled carbon nanotubes (SWCNTs) was studied by molecular dynamics (MD)sim.lation. It was found that the hydrogen molecules distribute regularly inside and outside of the tube. Density distribution was computed for H2 molecule. Theoretical analysis of the result showed the multilayer adsorption mechanism of SWCNTs. The storage of H2 in SWCNTs is computed, which provides essential theoretical reference for further study of hydrogen adsorption in SWCNTs.

  17. Analysis of Modified Starch Adsorption Kinetics on Cellulose Fibers via the Modified Langmuir Adsorption Theory

    OpenAIRE

    Zakrajšek, N.; Knez, S.; Ravnjak, D.; Golob, J.

    2009-01-01

    The kinetics of starch adsorption on cellulose fibers is one of the most important criteria regarding the efficient application of papermaking additives due to the continuous nature of paper production and the concomitant need to determine optimum residence times. This study presents an analysis of the kinetics of modified starch adsorption onto cellulose fibers via the application of the modified Langmuir adsorption theory (i.e. the collision theory). A model based on this theory was used to...

  18. Adsorption equilibrium and dynamics of lactase/CM-Sephadex system

    OpenAIRE

    Harsa, Hayriye Şebnem; Göksungur, Yekta; Güvenç, Ulgar

    1995-01-01

    Partitioning behaviour and adsorption isotherms of lactase/CM-Sephadex system at equilibrium were investigated together with the adsorption kinetics in this study. Maximum adsorption was obtained at the pH values between 5.5–6.0. Adsorption isotherm was a close fit to the Langmuir model.

  19. A hybrid multi-effect distillation and adsorption cycle

    KAUST Repository

    Thu, Kyaw

    2013-04-01

    This paper describes the development of a simple hybrid desalination system of a Multi-Effect Distillation (MED) and an adsorption (AD) cycle operating at sub-atmospheric pressures and temperatures. By hybridizing the conventional MED with an AD cycle, there is a symbiotic enhancement of performances of both cycles. The performance enhancement is attributed to (i) the cascade of adsorbent\\'s regeneration temperature and this extended the usage of thermal energy emanating from the brine heater and (ii) the vapor extraction from the last MED stage by AD cycle which provides the effect of lowering saturation temperatures of all MED stages to the extent of 5°C, resulting in scavenging of heat leaks into the MED stages from the ambient. The combined effects of the hybrid cycles increase the water production capacity of the desalination plant by nearly twofolds.In this paper, we demonstrate a hybrid cycle by simulating an 8-stage MED cycle which is coupled to an adsorption cycle for direct vapor extraction from the last MED stage. The sorption properties of silica gel is utilized (acting as a mechanical vapor compressor) to reduce the saturation temperatures of MED stages. The modeling utilizes the adsorption isotherms and kinetics of the adsorbent. +. adsorbate (silica-gel. +. water) pair along with the governing equations of mass, energy and concentration. For a 8-stage MED and AD cycles operating at assorted temperatures of 65-90°C, the results show that the water production rate increases from 60% to twofolds when compared to the MED alone. The performance ratio (PR) and gain output ratio (GOR) also improve significantly. © 2012 Elsevier Ltd.

  20. Adsorption of nisin and pediocin on nanoclays.

    Science.gov (United States)

    Meira, Stela Maris Meister; Jardim, Arthur Izé; Brandelli, Adriano

    2015-12-01

    Three different nanoclays (bentonite, octadecylamine-modified montmorillonite and halloysite) were studied as potential carriers for the antimicrobial peptides nisin and pediocin. Adsorption occurred from peptide solutions in contact with nanoclays at room temperature. Higher adsorption of nisin and pediocin was obtained on bentonite. The antimicrobial activity of the resultant bacteriocin-nanoclay systems was analyzed using skimmed milk agar as food simulant and the largest inhibition zones were observed against Gram-positive bacteria for halloysite samples. Bacteriocins were intercalated into the interlayer space of montmorillonites as deduced from the increase of the basal spacing measured by X-ray diffraction (XRD) assay. Infrared spectroscopy suggested non-electrostatic interactions, such as hydrogen bonding between siloxane groups from clays and peptide molecules. Transmission electron microscopy did not show any alteration in morphologies after adsorption of antimicrobial peptides on bentonite and halloysite. These results indicate that nanoclays, especially halloysite, are suitable nanocarriers for nisin and pediocin adsorption.

  1. Adsorption Isotherms and Surface Reaction Kinetics

    Science.gov (United States)

    Lobo, L. S.; Bernardo, C. A.

    1974-01-01

    Explains an error that occurs in calculating the conditions for a maximum value of a rate expression for a bimolecular reaction. The rate expression is derived using the Langmuir adsorption isotherm to relate gas pressures and corresponding surface coverages. (GS)

  2. PREPARATION OF ACTIVATED CARBON FIBER AND THEIR XENON ADSORPTION PROPERTIES (Ⅱ)-XENON ADSORPTION PROPERTIES

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The adsorption of xenon from air has an interest in the monitoring of nuclear explosion oraccident, or in the treatment of nuclear waste gas. In this paper, the pore structure of several series ofactivated carbon fibers has been characterized. The adsorption properties of xenon on theseactivated carbon fibers under different temperatures have been studied in details. The results showthat the xenon adsorption amount on activated carbon fibers do not increase with specific surfacearea of adsorbents, but are closely related to their pore size distribution. Pores whose radius equal toor narrow than 0.4nm would be more advantageous to the adsorption of xenon.

  3. Adsorption performances and refrigeration application of adsorption working pair of CaCl2-NH3

    Institute of Scientific and Technical Information of China (English)

    WANG; Liwei; WANG; Ruzhu; WU; Jingyi; WANG; Kai

    2004-01-01

    The adsorption performance of CaCl2-NH3 is studied under the condition of different expansion spaces for adsorbent, andthe relationships between adsorption performance of CaCl2-NH3 and the phenomena of swelling and agglomeration during adsorption are researched. It is found that the performance stability is related to the ratio of expansion space to the volume of adsorbent ras, and the performance attenuation is serious in the case of large ras. Severe adsorption hysteresis exists in the process of adsorption and desorption at the same evaporating and condensing temperatures, which is related to the stability constant of chemical reaction. This phenomenon cannot be explained by the theory of physical adsorption. Moderate agglomeration will be beneficial to the formation of ammoniate complex; the magnitude of expansion space will affect adsorption performance. Analysis shows that the activated energy needed in the process of adsorption for the sample with ras of 2:1 is less than that for the sample with ras of 3:1.The refrigeration performance of CaCl2-NH3 is predicted from experiments. The cooling capacity of one adsorption cycle is about 945.4 kJ/kg for the adsorbent with an ras of 2:1 at the evaporating temperature of 0℃.

  4. Selective adsorption of tannins onto hide collagen fibres

    Institute of Scientific and Technical Information of China (English)

    LIAO; Xuepin(廖学品); LU; Zhongbing(陆忠兵); SHI; Bi(石碧)

    2003-01-01

    Hide collagen of animals is used to prepare adsorbent material and its adsorption properties to tannins are investigated. It is indicated that the collagen fibres has excellent adsorption selectivity and high adsorption capacity to tannins. The adsorption rate of tannins is more than 90% whilst less than 10% of functional components are retained by the adsorbent. The adsorption mechanism of tannins onto hide collagen fibres is hydrogen-bonding association. Freundlich model can be used to describe the adsorption isotherms, and the pseudo-second-order rate model can be used to describe adsorption kinetics.

  5. Adsorption properties of nitrobenzene in wastewater with silica aerogels

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The adsorption properties of nitrobenzene from wastewater by hydrophobic silica aerogels were investigated.The effects of adsorption intensity by pH value,adsorption temperature,adsorption time and the amount of the silica aerogels were studied.The adsorption principle and mechanism of silica aerogels adsorbing nitrobenzene were discussed along with the Freundlich equation.The results showed that the adsorption intensity of the hydrophobic silica aerogels could reach 68.76% at better adsorption conditions of adsorption temperature 25°C,pH value 8.35,the amount of SiO2 aerogels dosage 3.33 g/L,and adsorption time of 30 min,and that the adsorption properties were related to the hydrophobility of aerogels,surface area of organic solution,structure of aerogels.

  6. Adsorption Characteristics of Remazol Black B on Anoxic Sludge

    Institute of Scientific and Technical Information of China (English)

    HUANG Man-hong; CHEN Liang; CHEN Dong-hui; CHEN Chao-peng

    2009-01-01

    The adsorption characteristics of Remazol Black B on anoxic sludge were investigated. The parameters, such as initial pH, sulphate concentration, and temperature,affecting the dye adsorption were studied. The adsorption data were analyzed with three adsorption isotherm models,namely Langmuir, Freudlich, and linear partition. The results showed that adsorption of Remazol Black B on the sterilized sludge reached equilibrium in 4 h. It also indicated that pH had significant effect on anoxic sludge adsorption behavior. The adsorption capacity of anoxic sludge decreased with the increase of pH value and the maximum adsorption capacity of dyes occurred at pH = 3. The adsorptive capacities increased with the decrease of temperature and increase of sulphate concentration. Results also indicated that the adsorption equilibrium of Remazol Black B on anoxic sludge could be well fitted by Freundlich model.

  7. ADSORPTION OF LDL ON THE MODIFIED CHITOSAN

    Institute of Scientific and Technical Information of China (English)

    LIUManying; ZHAOLirui; 等

    2000-01-01

    In this paper,the selective adsorption of LDL on chitosan modified with PEG and Asp.was studied.The adsorption rate of LDL and HDL on the double modified chitosan was 57% and 12% respoectively,The results shown that the double modified chitosan can be used a adsorbent for selective binding to LDL,this work may help to develop functional columns for hemoperfusion.

  8. Adsorption Kinetic of 8-Hydroxyquinoline on Malachite

    Directory of Open Access Journals (Sweden)

    Gabriela OPREA

    2007-01-01

    Full Text Available Influence of temperature and collector concentration on its adsorption rate on mineral surface was studied as regarding to the 8-hydroxyquinoline/malachite system. Theoretical equations as well as experimental data may be useful to estimate the adsorption rate and kinetics connected to the conditioning stage in mineral flotation in order to optimise the selectivity and the recovery of the desired mineral.

  9. Defluoridation of drinking water using adsorption processes

    International Nuclear Information System (INIS)

    Highlights: ► Comprehensive and critical literature review on various adsorbents used for defluoridation. ► pH, temperature, kinetics and co-existing anions effects on F adsorption. ► Choice of adsorbents for various circumstances. ► Adsorption thermodynamics and mechanisms. ► Future research on efficient, low cost adsorbents which are easily regenerated. -- Abstract: Excessive intake of fluoride (F), mainly through drinking water, is a serious health hazard affecting humans worldwide. There are several methods used for the defluoridation of drinking water, of which adsorption processes are generally considered attractive because of their effectiveness, convenience, ease of operation, simplicity of design, and for economic and environmental reasons. In this paper, we present a comprehensive and a critical literature review on various adsorbents used for defluoridation, their relative effectiveness, mechanisms and thermodynamics of adsorption, and suggestions are made on choice of adsorbents for various circumstances. Effects of pH, temperature, kinetics and co-existing anions on F adsorption are also reviewed. Because the adsorption is very weak in extremely low or high pHs, depending on the adsorbent, acids or alkalis are used to desorb F and regenerate the adsorbents. However, adsorption capacity generally decreases with repeated use of the regenerated adsorbent. Future research needs to explore highly efficient, low cost adsorbents that can be easily regenerated for reuse over several cycles of operations without significant loss of adsorptive capacity and which have good hydraulic conductivity to prevent filter clogging during the fixed-bed treatment process

  10. Influence of Pyrolysis Temperature on Rice Husk Char Characteristics and Its Tar Adsorption Capability

    OpenAIRE

    Anchan Paethanom; Kunio Yoshikawa

    2012-01-01

    A biomass waste, rice husk, was inspected by thermoanalytical investigation to evaluate its capability as an adsorbent medium for tar removal. The pyrolysis process has been applied to the rice husk material at different temperatures 600, 800 and 1000 °C with 20 °C/min heating rate, to investigate two topics: (1) influence of temperature on characterization of rice husk char and; (2) adsorption capability of rice husk char for tar removal. The results showed that subsequent ...

  11. Unconventional, highly selective CO2 adsorption in zeolite SSZ-13.

    Science.gov (United States)

    Hudson, Matthew R; Queen, Wendy L; Mason, Jarad A; Fickel, Dustin W; Lobo, Raul F; Brown, Craig M

    2012-02-01

    Low-pressure adsorption of carbon dioxide and nitrogen was studied in both acidic and copper-exchanged forms of SSZ-13, a zeolite containing an 8-ring window. Under ideal conditions for industrial separations of CO(2) from N(2), the ideal adsorbed solution theory selectivity is >70 in each compound. For low gas coverage, the isosteric heat of adsorption for CO(2) was found to be 33.1 and 34.0 kJ/mol for Cu- and H-SSZ-13, respectively. From in situ neutron powder diffraction measurements, we ascribe the CO(2) over N(2) selectivity to differences in binding sites for the two gases, where the primary CO(2) binding site is located in the center of the 8-membered-ring pore window. This CO(2) binding mode, which has important implications for use of zeolites in separations, has not been observed before and is rationalized and discussed relative to the high selectivity for CO(2) over N(2) in SSZ-13 and other zeolites containing 8-ring windows. PMID:22235866

  12. Nitrate Adsorption on Clay Kaolin: Batch Tests

    Directory of Open Access Journals (Sweden)

    Morteza Mohsenipour

    2015-01-01

    Full Text Available Soils possessing kaolin, gibbsite, goethite, and hematite particles have been found to have a natural capacity to attenuate pollution in aqueous phase. On the other hand, the hydroxyl group in soil increases anion exchange capacity under a low pH condition. The main objective of this paper was to evaluate effects of kaolin on nitrate reduction under acidic condition. In order to analyze the kaolin adsorption behaviour under various conditions, four different concentrations of nitrate, 45, 112.5, 225, and 450 mgNO3-/L, with a constant pH equal to 2, constant temperature equal to 25°C, and exposure period varying from 0 to 150 minutes were considered. The capacity of nitrate adsorption on kaolin has also been studied involving two well-known adsorption isotherm models, namely, Freundlich and Longmuir. The results revealed that approximately 25% of the nitrate present in the solution was adsorbed on clay kaolin. The laboratory experimental data revealed that Freundlich adsorption isotherm model was more accurate than Longmuir adsorption model in predicting of nitrate adsorption. Furthermore, the retardation factor of nitrate pollution in saturated zone has been found to be approximately 4 in presence of kaolin, which indicated that kaolin can be used for natural scavenger of pollution in the environment.

  13. Modeling of Experimental Adsorption Isotherm Data

    Directory of Open Access Journals (Sweden)

    Xunjun Chen

    2015-01-01

    Full Text Available Adsorption is considered to be one of the most effective technologies widely used in global environmental protection areas. Modeling of experimental adsorption isotherm data is an essential way for predicting the mechanisms of adsorption, which will lead to an improvement in the area of adsorption science. In this paper, we employed three isotherm models, namely: Langmuir, Freundlich, and Dubinin-Radushkevich to correlate four sets of experimental adsorption isotherm data, which were obtained by batch tests in lab. The linearized and non-linearized isotherm models were compared and discussed. In order to determine the best fit isotherm model, the correlation coefficient (r2 and standard errors (S.E. for each parameter were used to evaluate the data. The modeling results showed that non-linear Langmuir model could fit the data better than others, with relatively higher r2 values and smaller S.E. The linear Langmuir model had the highest value of r2, however, the maximum adsorption capacities estimated from linear Langmuir model were deviated from the experimental data.

  14. Investigation of the usability of activated carbon produced from sugar beet pulp for the adsorption of 2,4-D and Metribuzin pesticides in wastewaters

    OpenAIRE

    SEZER, Kazım; AKSU, Zümriye

    2013-01-01

    In this study the adsorption of 2,4-D and Metribuzin herbicides, present in wastewaters and used in Turkey intensively, on activated carbon produced from dried sugar beet pulp by heat activation and on commercial powdered activated carbon was comparatively investigated in a batch system. At studies, effect of initial herbicide concentration, temperature and pH parameters on adsorption rate and yield was investigated and optimum working conditions determined. Defining parameters of the system,...

  15. Vapor Jet Ejector Used To Generate Free Waste Heat Driven Cooling In Military Environmental Cooling Units

    OpenAIRE

    Elbel, Stefan; Bowers, Chad D.; Reichle, Manuel; Cristiani, Jonathan M.; Hrnjak, Predrag S.

    2012-01-01

    The waste heat driven vapor jet ejector cooling cycle is a very promising approach to produce ‘free’ cooling by utilizing low-grade energy sources. The mechanism behind ejector-based waste heat cooling is very different from absorption or adsorption cooling technologies that are also aimed at producing heat driven cooling. The ejector cooling system is actually more closely related to vapor compression technology, in which an ejector, a waste heat source, and a liquid pump are used to replace...

  16. Calcium adsorption on MgO(100): energetics, structure, and role of defects.

    Science.gov (United States)

    Zhu, Junfa; Farmer, Jason A; Ruzycki, Nancy; Xu, Lijun; Campbell, Charles T; Henkelman, Graeme

    2008-02-20

    The adsorption of Ca on the MgO(100) surface at 300 K has been studied using microcalorimetry, in combination with LEED, AES, ISS, work function, sticking probability measurements, and density functional theory (DFT) calculations. The MgO(100) thin films (approximately 4 nm thick) were grown epitaxially on a 1 microm thick Mo(100) single-crystal. The sticking probability of Ca on MgO(100) at 300 K is unity. On the basis of AES and ISS measurements, it was determined that Ca grows mainly as 3D particles on the MgO(100) surface with a density of approximately 1 x 10(12) islands/cm2. Ca adsorbs initially at defect sites with a very high heat of adsorption (approximately 410 kJ/mol). DFT calculations attribute this high initial heat to Ca binding to kink sites (376 kJ/mol), step sites (205 kJ/mol), and lower concentrations of stronger binding sites. The heat of adsorption decreases rapidly with coverage, reaching a minimum of 162 kJ/mol at approximately 0.3 ML, where Ca is mainly adding to small 3D Ca clusters. Afterward, it increases to the value of bulk Ca heat of sublimation (178 kJ/mol) at approximately 1.2 ML, attributed to the increase in stability with increasing Ca particle size. A 1.0 eV decrease of the work function with Ca coverage from 0 to 0.3 ML indicates that Ca adsorbed at defects is cationic, in agreement with calculations showing that Ca donates electron density to the MgO. Light ion sputtering of the MgO(100) surface generates point defects, but these do not change the heat of adsorption versus coverage, implying that they do not nucleate Ca particles. Oxygen vacancies are a likely candidate; DFT calculations show that F and F+ center vacancies bind Ca more weakly than terrace sites. More extensive sputtering creates extended defects (such as steps and kinks) that adsorb Ca with heats of adsorption up to approximately 400 kJ/mol, similar to that at the intrinsic defect sites.

  17. Calcium adsorption on MgO(100): energetics, structure, and role of defects.

    Science.gov (United States)

    Zhu, Junfa; Farmer, Jason A; Ruzycki, Nancy; Xu, Lijun; Campbell, Charles T; Henkelman, Graeme

    2008-02-20

    The adsorption of Ca on the MgO(100) surface at 300 K has been studied using microcalorimetry, in combination with LEED, AES, ISS, work function, sticking probability measurements, and density functional theory (DFT) calculations. The MgO(100) thin films (approximately 4 nm thick) were grown epitaxially on a 1 microm thick Mo(100) single-crystal. The sticking probability of Ca on MgO(100) at 300 K is unity. On the basis of AES and ISS measurements, it was determined that Ca grows mainly as 3D particles on the MgO(100) surface with a density of approximately 1 x 10(12) islands/cm2. Ca adsorbs initially at defect sites with a very high heat of adsorption (approximately 410 kJ/mol). DFT calculations attribute this high initial heat to Ca binding to kink sites (376 kJ/mol), step sites (205 kJ/mol), and lower concentrations of stronger binding sites. The heat of adsorption decreases rapidly with coverage, reaching a minimum of 162 kJ/mol at approximately 0.3 ML, where Ca is mainly adding to small 3D Ca clusters. Afterward, it increases to the value of bulk Ca heat of sublimation (178 kJ/mol) at approximately 1.2 ML, attributed to the increase in stability with increasing Ca particle size. A 1.0 eV decrease of the work function with Ca coverage from 0 to 0.3 ML indicates that Ca adsorbed at defects is cationic, in agreement with calculations showing that Ca donates electron density to the MgO. Light ion sputtering of the MgO(100) surface generates point defects, but these do not change the heat of adsorption versus coverage, implying that they do not nucleate Ca particles. Oxygen vacancies are a likely candidate; DFT calculations show that F and F+ center vacancies bind Ca more weakly than terrace sites. More extensive sputtering creates extended defects (such as steps and kinks) that adsorb Ca with heats of adsorption up to approximately 400 kJ/mol, similar to that at the intrinsic defect sites. PMID:18229925

  18. Cyclic steady state performance of adsorption chiller with low regeneration temperature zeolite

    Energy Technology Data Exchange (ETDEWEB)

    Qian, Mr. Suxin [University of Maryland, College Park; Gluesenkamp, Kyle R [ORNL; Hwang, Dr. Yunho [University of Maryland, College Park; Radermacher, Reinhard [University of Maryland, College Park; Chun, Mr. Ho-Hwan [University of Maryland, College Park

    2013-10-01

    Adsorption chillers are capable of utilizing inexpensive or free low grade thermal energy such as waste heat and concentrated solar thermal energy. Recently developed low regeneration temperature working pairs allow adsorption chillers to be driven by even lower temperature sources such as engine coolant and flat plate solar collectors. In this work, synthetic zeolite/water was implemented into a 3kW adsorption chiller test facility driven by hot water at 70 C. The zeolite was coated onto two fin-and-tube heat exchangers, with heat recovery employed between the two. Cyclic steady state parametric studies were experimentally conducted to evaluate the chiller's performance, resulting in a cooling coefficient of performance (COP) ranging from 0.1 to 0.6 at different operating conditions. Its performance was compared with published values for other low regeneration temperature working pairs. The physical limitations of the synthetic zeolite revealed by parametric study results were then discussed. A novel operating control strategy was proposed based on the unique characteristics of synthetic zeolite. In addition, a physics-based COP prediction model was derived to predict the performance of the chiller under equilibrium loading, and was validated by the experiment results. This analytical expression can be used to estimate the cyclic steady state performance for future studies.

  19. Numerical Analysis on Adsorption Characteristics of Activated Carbon/Ethanol Pair in Finned Tube Type Adsorber

    Science.gov (United States)

    Makimoto, Naoya; Kariya, Keishi; Koyama, Shigeru

    The cycle performance of adsorption cooling system depends on the thermophysical properties of the adsorbent/refrigerant pair and configuration of the adsorber/desorber heat exchanger. In this study, a twodimensional analysis is carried out in order to clarify the performance of the finned tube type adsorber/desorber heat exchanger using a highly porous activated carbon powder (ACP)/ethanol pair. The simulation results show that the average cooling capacity per unit volume of adsorber/desorber heat exchanger and coefficient of performance (COP) can be improved by optimizing fin thickness, fin height, fin pitch and tube diameter. The performance of a single stage adsorption cooling system using ACP/ethanol pair is also compared with that of activated carbon fiber (ACF)/ethanol pair. It is found that the cooling capacities of each adsorbent/refrigerant pair increase with the decrease of adsorption/desorption time and the cooling capacity of ACP/ethanol pair is approximately 2.5 times as much as that of ACF/ethanol pair. It is also shown that COP of ACP/ethanol pair is superior to that of ACF/ethanol pair.

  20. Heat pipes

    CERN Document Server

    Dunn, Peter D

    1994-01-01

    It is approximately 10 years since the Third Edition of Heat Pipes was published and the text is now established as the standard work on the subject. This new edition has been extensively updated, with revisions to most chapters. The introduction of new working fluids and extended life test data have been taken into account in chapter 3. A number of new types of heat pipes have become popular, and others have proved less effective. This is reflected in the contents of chapter 5. Heat pipes are employed in a wide range of applications, including electronics cooling, diecasting and injection mo

  1. MODELLING AND OPTIMIZATION OF AN ADSORPTION COOLING SYSTEM FOR AUTOMOTIVE APPLICATIONS

    OpenAIRE

    Verde Trindade, María

    2015-01-01

    [EN] This PhD study deals with the modelling of an adsorption system designed to provide air conditioning for vehicles, and is driven by the waste heat available from the water/glycol cooling circuit of the engine. The system is based on the sequential heating/cooling of two sorption beds containing a solid sorption material which desorbs or adsorbs water vapour. The condensation of the vapour is carried out by a cooling circuit while the subsequent evaporation of the condensed liquid is empl...

  2. The role of hydration in enzyme activity and stability: 1. Water adsorption by alcohol dehydrogenase in a continuous gas phase reactor.

    Science.gov (United States)

    Yang, F; Russell, A J

    1996-03-20

    The adsorption of water by alcohol dehydrogenase from baker's yeast (YADH) has been measured in a continuous-flow gas reactor at varying temperatures. Adsorption isotherms in the presence of gaseous organic substrates are compared to those from organic-free gas mixtures. Almost no effect of the hydrophobic molecule on total water adsorption was observed. A rarely mentioned multilayer isotherm model from the 1930s, the Huttig's isotherm, has been found to fit the experimental data with extremely good accuracy. The model enables the calculation of both the heat of adsorption of water to the enzyme and the total amount of water necessary for monolayer coverage. The heat of adsorption of water in the first layer is approximately -16 kcal/mol. This tight binding of water, which is much higher than the heat of condensation of pure water, helps to explain the kinetic properties of YADH-catalyzed reactions on vapor phase substrates. While the monolayer coverage is temperature independent, the enzyme demonstrates hysteresis when transitioning between adsorption and desorption. The hysteresis observed in water sorption studies may also explain previously reported properties of the enzyme. (c) 1996 John Wiley & Sons, Inc.

  3. Fluoride and lead adsorption on carbon nanotubes

    Institute of Scientific and Technical Information of China (English)

    WANG Shuguang; LI Yanhui

    2004-01-01

    The properties and applications of CNT have been studied extensively since Iijima discovered them in 1991[1,2]. They have exceptional mechanical properties and unique electrical property, highly chemical stability and large specific surface area. Thus far, they have widely potential applications in many fields. They can be used as reinforcing materials in composites[3], field emissions[4], hydrogen storage[5], nanoelectronic components[6], catalyst supports[7], adsorption material and so on. However, the study on the potential application of CNT, environmental protection field in particular, was hardly begun.Long[8] et al. reported that CNT had a significantly higher dioxin removal efficiency than that of activated carbon. The Langmuir adsorption constant is 2.7 × 1052, 1.3 × 1018 respectively. The results indicated that CNT is potential candidate for the removal of micro-organic pollutants. However, the reports on the CNT used as fluoride and heavy metal adsorbent are seldom.In this paper, A novel material, alumina supported on carbon nanotubes (Al2O3/CNT), was prepared from carbon nanotubes and Al(NO3)3. X-ray diffraction (XRD) spectra demonstrate that alumina is amorphous, and scanning electron microscope (SEM) images show that CNT and alumina are homogeneously mixed. Furthermore, the fluoride adsorption behavior on the surface of Al2O3/CNT has been investigated and compared with other adsorbents. The results indicate that Al2O3/CNT has a high adsorption capacity, with a saturation adsorption capacity of 39.4 mg/g. It is also found that the adsorption capacity of Al2O3/CNT is 3.0~4.5 times that of γ-Al2O3while almost equal to that of IRA-410 polymeric resin at 25 ℃. The adsorption isotherms of fluoride on Al2O3/CNT is fit the Freundlich equation well, optimal pH ranging from 5.0 to 9.0.Also in this paper, a novel material, modified carbon nanotubes (CNT), was prepared from carbon nanotubes and HNO3 under boiling condition. Infrared spectroscopy (IR

  4. Adsorption of aqueous copper on peanut hulls

    Science.gov (United States)

    Davis, Kanika Octavia

    A method was established for measuring the adsorption of Cu(II) from aqueous solution to unmodified and modified peanut hulls at constant temperature and pH. Modification of the hulls was performed by oxidation with alkaline hydrogen peroxide. During the modification process, the hydrogen peroxide solubilizes the lignin component, making the surface more porous which increases the availability of binding sites, while simultaneously oxidizing the cellulose. The oxidation of alcohol groups creates more binding sites by creating functional groups such as COO-, which increases chelation to metal ions. Fourier transform infrared spectroscopy confirms delignification of the peanut hulls by the disappearance of carboxyl peaks of the modified hulls, which were originally produced from the lignin content. Although, oxidation is not fully confirmed, it is not ruled out because the expected carboxylate peak (1680 cm-1) maybe overshadowed by a broad peak due to OH bending of water adsorbed to the hulls. Hulls adsorbed copper from solutions in the concentration range of 50-1000 ppm of CuCl2. Concentrations of pre- and post-adsorption solutions were determined using inductively coupled plasma optical emission spectroscopy. The adsorption isotherms were fit to known two and three-parameter models, evaluated and the binding mechanism was inferred. Maximum surface coverage was 3.5 +/- 0.6 mg Cu2+ /g hull for unmodified hulls and 11 +/- 1 mg Cu2+/g hull for modified hulls. The adsorption for the hulls is best described by the Langmuir model, suggesting monolayer, homogeneous adsorption. With a free energy of adsorption of 10.5 +/- 0.9 kJ/mol for unmodified hulls and 14.5 +/-0.4 kJ/mol for modified hulls, the process is categorized as chemisorption for both types of hulls. The adsorption for both hulls is also described by the Redlich-Peterson model, giving beta nearer to 1 than 0, which further suggests homogeneous adsorption described by the Langmuir model. After rinsing the hulls

  5. Molecular simulation of carbon dioxide adsorption for carbon capture and storage

    Science.gov (United States)

    Tenney, Craig M.

    Capture of CO2 from fossil fuel power plants and sequestration in unmineable coal seams are achievable methods for reducing atmospheric emissions of this greenhouse gas. To aid the development of effective CO2 capture and sequestration technologies, a series of molecular simulation studies were conducted to study the adsorption of CO2 and related species onto heterogeneous, solid adsorbents. To investigate the influence of surface heterogeneity upon adsorption behavior in activated carbons and coal, isotherms were generated via grand canonical Monte Carlo (GCMC) simulation for CO2 adsorption in slit-shaped pores with several variations of chemical and structural heterogeneity. Adsorption generally increased with increasing oxygen content and the presence of holes or furrows, which acted as preferred binding sites. To investigate the potential use of the flexible metal organic framework (MOF) Cu(BF4)2(bpy)2 (bpy=bipyridine) for CO2 capture, pure- and mixed-gas adsorption was simulated at conditions representative of power plant process streams. This MOF was chosen because it displays a novel behavior in which the crystal structure reversibly transitions from an empty, zero porosity state to a saturated, expanded state at the "gate pressure". Estimates of CO2 capacity above the gate pressure from GCMC simulations using a rigid MOF model showed good agreement with experiment. The CO2 adsorption capacity and estimated heats of adsorption are comparable to common physi-adsorbents under similar conditions. Mixed-gas simulations predicted CO2/N2 and CO2/H 2selectivities higher than typical microporous materials. To more closely investigate this gating effect, hybrid Monte-Carlo/molecular-dynamics (MCMD) was used to simulate adsorption using a flexible MOF model. Simulation cell volumes remained relatively constant at low gas pressures before increasing at higher pressure. Mixed-gas simulations predicted CO2/N 2 selectivities comparable to other microporous adsorbents. To

  6. Magnetar heating

    CERN Document Server

    Beloborodov, Andrei M

    2016-01-01

    We examine four candidate mechanisms that could explain the high surface temperatures of magnetars. (1) Heat flux from the liquid core heated by ambipolar diffusion. It could sustain the observed surface luminosity $L_s\\approx 10^{35}$ erg s$^{-1}$ if core heating offsets neutrino cooling at a temperature $T_{\\rm core}>6\\times 10^8$ K. This scenario is viable if the core magnetic field exceeds $10^{16}$ G, the magnetar has mass $M10^{16}$ G varying on a 100 meter scale could provide $L_s\\approx 10^{35}$ erg s$^{-1}$. (4) Bombardment of the stellar surface by particles accelerated in the magnetosphere. This mechanism produces hot spots on magnetars. Observations of transient magnetars show evidence for external heating.

  7. Static Analysis of Double Effect Adsorption Refrigeration Cycle Using Silica gel/Water Pair

    Science.gov (United States)

    Marlinda; Miyazaki, Takahiko; Ueda, Yuki; Akisawa, Atsushi

    In this paper,a static analysis of double effect adsorption refrigeration cycle utilizing condensation heat is discussed. Double effect adsorption refrigeration cycle consists of two cycles, High Temperature Cycle (HTC) which is driven from external heat sources, and Low Temperature Cycle (LTC) which is driven by condensation heat from HTC. Both of HTC and LTC are using silica gel and water as working pairs. The effect of heat source temperature on cycle performance was investigated in terms of coefficient of performance (COP) and specific cooling energy (SCE). Results showed that double effect cycle would produce higher COP than single effect cycle for driving temperature observed between 80-150°C with the same operating condition. However, the value of SCE is lower than single effect, despite that the SCE of double effect cycle is improved with heat source temperature higher than 100°C. Further, it was also observed that adsorbent mass ratio of HTC and LTC affected performance of chiller. When adsorbent mass ratio of HTC and LTC was unity, it was found that SCE and COP took the maximum.

  8. A review of the thermodynamics of protein association to ligands, protein adsorption, and adsorption isotherms

    DEFF Research Database (Denmark)

    Mollerup, Jørgen

    2008-01-01

    The application of thermodynamic models in the development of chromatographic separation processes is discussed. The paper analyses the thermodynamic principles of protein adsorption. It can be modeled either as a reversible association between the adsorbate and the ligands or as a steady...... of adsorption is discussed. Hydrophobic and reversed phase chromatography are useful techniques for measuring solute activity coefficients at infinite dilution....

  9. Heavy metal adsorption changes of EAF steel slag after phosphorus adsorption.

    Science.gov (United States)

    Song, Guanling; Cao, Lijing; Chen, Xiao; Hou, Wenhua; Wang, Qunhui

    2012-01-01

    A kind of electric arc furnace (EAF) steel slag was phosphated, and its isothermal and dynamic adsorptions of copper, cadmium, and lead ions were measured to determine if heavy metal adsorption changes after phosphorus adsorption. The surface area increased greatly after the slag was phosphated. Isothermal adsorption experiments showed that the theoretical Q(max) of the EAF steel slag on Cu(2+), Cd(2+), and Pb(2+) improved 59, 50, and 89% respectively after it was phosphated. Dynamic adsorption results showed that the greatest adsorption capacities of unit volume of Cu(2+), Cd(2+), and Pb(2+) were 2.2, 1.8, and 1.8 times that of the column packed with original EAF steel slag when the column was packed with phosphate EAF steel slag at the same heavy metal ion concentration. The breakthrough time, the exhaustion time and elution efficiency of the column also increased when the column was packed with phosphated EAF steel slag compared with that packed with original EAF steel slag. Phosphorus adsorption could further improve the heavy metal ion adsorption of the EAF steel slag.

  10. VOC emission control by circulating fluidized bed adsorption; Controle de l'emission de composes organiques volatils par adsorption en lit fluidise circulant

    Energy Technology Data Exchange (ETDEWEB)

    Song, W.

    2003-12-15

    This work deals with the circulating fluidized bed technology, applied to the elimination by adsorption of volatile organic compounds (VOCs), like toluene, in a gas flow. In the process, the adsorbent (millimetric spherical grains of micro-porous carbon) is moved by a strong flow rate of gas inside a vertical tube without lining. Mass and heat transfers are very important and important volumes of compounds can be processed. This work presents the determination of the adsorption equilibrium, the description of the experimental facility and of the results of experiments, the development of an original model of the process which combines a flow model and a mass transfer model, a parametric study of this model, and finally, some extensions of the process principle to staged operations with pressure variation or temperature variation cycles. (J.S.)

  11. Experimental study and exploration of adsorption working pair in adsorption refrigeration system%吸附式制冷系统中吸附工质对的探索和实验研究

    Institute of Scientific and Technical Information of China (English)

    安文卓; 刘泽勤; 裴凤

    2013-01-01

    This paper introduced the working principle of the adsorption refrigeration system, and analysed the progress of research about the adsorption working - medium pair in refrigeration and air conditioning academia, and pointed out that the study on improving the heat conduction property of the adsorbent was the weak link in the study field of adsorption working - medium pair at present. For the purpose to explore the optimum ratio of hybrid adsorbent, this topic is to carry out experimental study a-bout heat conduction property and adsorption property, and pointed out that it would have a significant role in promoting refrigeration system energy efficiency if the adsorption working - medium pair with both good heat conduction property and adsorption property could be found out.%介绍了吸附制冷工作原理,并对制冷空调学术界对吸附工质对的研究进展进行了分析,发现目前吸附工质对研究中相对薄弱的环节是吸附剂的导热性能.本课题以探索最佳比例混合式吸附剂为目的,开展吸附剂导热性能和吸附性能的实验研究,指出研究出兼具良好导热性能和吸附性能的吸附工质对,对提高制冷系统能效比将具有明显的促进作用.

  12. Accurate Treatment of Electrostatics during Molecular Adsorption in Nanoporous Crystals without Assigning Point Charges to Framework Atoms

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, T; Manz, TA; Sholl, DS

    2011-03-24

    Molecular simulations have become an important complement to experiments for studying gas adsorption and separation in crystalline nanoporous materials. Conventionally, these simulations use force fields that model adsorbate-pore interactions by assigning point charges to the atoms of the adsorbent. The assignment of framework charges always introduces ambiguity because there are many different choices for defining point charges, even when the true electron density of a material is known. We show how to completely avoid such ambiguity by using the electrostatic potential energy surface (EPES) calculated from plane wave density functional theory (DFT). We illustrate this approach by simulating CO(2) adsorption in four metal-organic frameworks (MOFs): IRMOF-1, ZIE-8, ZIE-90, and Zn(nicotinate)(2). The resulting CO(2) adsorption isotherms are insensitive to the exchange-correlation functional used in the DFT calculation of the EPES but are sensitive to changes in the crystal structure and lattice parameters. Isotherms computed from the DFT EPES are compared to those computed from several point charge models. This comparison makes possible, for the first time, an unbiased assessment of the accuracy of these point charge models for describing adsorption in MOFs. We find an unusually high Henry's constant (109 mmol/g.bar) and intermediate isosteric heat of adsorption (34.9 kJ/mol) for Zn(nicotinate)(2), which makes it a potentially attractive mateiial for CO(2) adsorption applications.

  13. Accurate Treatment of Electrostatics during Molecular Adsorption in Nanoporous Crystals without Assigning Point Charges to Framework Atoms

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, Taku [Georgia Inst. of Technology, Atlanta, GA (United States); Manz, Thomas A. [Georgia Inst. of Technology, Atlanta, GA (United States); Sholl, David S. [Georgia Inst. of Technology, Atlanta, GA (United States)

    2011-02-28

    Molecular simulations have become an important complement to experiments for studying gas adsorption and separation in crystalline nanoporous materials. Conventionally, these simulations use force fields that model adsorbate-pore interactions by assigning point charges to the atoms of the adsorbent. The assignment of framework charges always introduces ambiguity because there are many different choices for defining point charges, even when the true electron density of a material is known. We show how to completely avoid such ambiguity by using the electrostatic potential energy surface (EPES) calculated from plane wave density functional theory (DFT). We illustrate this approach by simulating CO2 adsorption in four metal-organic frameworks (MOFs): IRMOF-1, ZIF-8, ZIF-90, and Zn(nicotinate)2. The resulting CO2 adsorption isotherms are insensitive to the exchange-correlation functional used in the DFT calculation of the EPES but are sensitive to changes in the crystal structure and lattice parameters. Isotherms computed from the DFT EPES are compared to those computed from several point charge models. This comparison makes possible, for the first time, an unbiased assessment of the accuracy of these point charge models for describing adsorption in MOFs. We find an unusually high Henry’s constant (109 mmol/g·bar) and intermediate isosteric heat of adsorption (34.9 kJ/mol) for Zn(nicotinate)2, which makes it a potentially attractive material for CO2 adsorption applications.

  14. Development of adsorbents from used tire rubber. Their use in the adsorption of organic and inorganic solutes in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Troca-Torrado, Cesar; Alexandre-Franco, Maria; Fernandez-Gonzalez, Carmen; Gomez-Serrano, Vicente [Extremadura Univ., Badajoz (Spain). Dept. de Quimica Organica e Inorganica; Alfaro-Dominguez, Manuel [Extremadura Univ., Badajoz (Spain). Dept. de Ingenieria Mecanica, Energetica y de los Materiales

    2011-02-15

    Using used tire rubber (UTR), carbonaceous adsorbents (CAs) were prepared by chemical treatment of the material with HCl, HNO{sub 3} and NaOH aqueous solutions and by heat treatment at 900 C for 2 h in N{sub 2} atmosphere (H900). UTR and the UTR-derived products were first characterized in terms of texture by N{sub 2} adsorption at - 196 C and of oxygen surface groups by FT-IR spectroscopy and pH of the point of zero charge (pH{sub pzc}). Then, the products were tested as adsorbents of phenol, p-aminophenol, p-nitrophenol, and p-chlorophenol and of chromium, cadmium, mercury and lead in aqueous solution. The development of porosity is very poor in UTR and in the chemically treated products. H900 is the only CA with a better developed porosity, mainly in the regions of meso and macropores. pH{sub pzc} is close to 7.0 for most of the CAs. As an exception to the rule, pH{sub pzc} is 8.4 for H900. For this CA, the adsorption of all the adsorptives is greater. Usually, adsorption kinetics are fast. This is so in particular for p-nitrophenol and p-chlorophenol, on the one side, and for mercury and lead, on the other side. Adsorption is much higher for mercury and lead than for the remaining adsorptives. (author)

  15. Energies of the adsorption of functional groups to calcium carbonate polymorphs: the importance of -OH and -COOH groups.

    Science.gov (United States)

    Okhrimenko, D V; Nissenbaum, J; Andersson, M P; Olsson, M H M; Stipp, S L S

    2013-09-01

    The adsorption behavior of calcium carbonate is an important factor in many processes in nature, industry, and biological systems. We determined and compared the adsorption energies for a series of small molecules of different sizes and polarities (i.e., water, several alcohols, and acetic acid) on three synthetic CaCO3 polymorphs (calcite, aragonite, and vaterite). We measured isosteric heats of adsorption from vapor adsorption isotherms for 273 < T < 293 K, and we used XRD and SEM to confirm that samples did not change phase during the experiments. Density functional calculations and molecular dynamics simulations complemented the experimental results and aided interpretation. Alcohols with molecular mass greater than that of methanol bind more strongly to the calcium carbonate polymorphs than water and acetic acid. The adsorption energies for the alcohols are typical of chemisorption and indicate alcohol displacement of water from calcium carbonate surfaces. This explains why organisms favor biomolecules that contain alcohol functional groups (-OH) to control which polymorph they use, the crystal face and orientation, and the particle shape and size in biomineralization processes. This new insight is also very useful in understanding organic molecule adsorption mechanisms in soils, sediments, and rocks, which is important for predicting the behavior of mineral-fluid interactions when the challenge is to remediate contaminated groundwater aquifers or to produce oil and gas from reservoirs.

  16. N2 and CO2 Adsorption by Soils with High Kaolinite Content from San Juan Amecac, Puebla, México

    Directory of Open Access Journals (Sweden)

    Karla Quiroz-Estrada

    2016-07-01

    Full Text Available Carbon dioxide (CO2 is considered one of the most important greenhouse gases in the study of climate change. CO2 adsorption was studied using the gas chromatography technique, while the Freundlich and Langmuir adsorption models were employed for processing isotherm data in the temperature range of 473–573 K. The isosteric heat of adsorption was calculated from the Clausius–Clapeyron equation. Moreover, the thermodynamic properties ΔG, ΔU, and ΔS were evaluated from the adsorption isotherms of Langmuir using the Van’t Hoff Equation. The four soil samples were recollected from San Juan Amecac, Puebla, Mexico, and their morphologies were investigated through X-ray diffraction (XRD and N2 adsorption at 77 K. The SJA4 soil has a crystalline Kaolinite phase, which is one of its non-metallic raw materials, and N2 isotherms allowed for the determination of pore size distributions and specific surface areas of soil samples. The Barrett–Joyner–Halenda (BJH distribution of pore diameters was bimodal with peaks at 1.04 and 3.7 nm, respectively. CO2 adsorption showed that the SJA1 soil afforded a higher amount of adsorbed CO2 in the temperature range from 453 to 573 K followed by SJA4 and finally SJA2, classifying this process as exothermic physisorption.

  17. CO 2 adsorption in mono-, di- and trivalent cation-exchanged metal-organic frameworks: A molecular simulation study

    KAUST Repository

    Chen, Yifei

    2012-02-28

    A molecular simulation study is reported for CO 2 adsorption in rho zeolite-like metal-organic framework (rho-ZMOF) exchanged with a series of cations (Na +, K +, Rb +, Cs +, Mg 2+, Ca 2+, and Al 3+). The isosteric heat and Henry\\'s constant at infinite dilution increase monotonically with increasing charge-to-diameter ratio of cation (Cs + < Rb + < K + < Na + < Ca 2+ < Mg 2+ < Al 3+). At low pressures, cations act as preferential adsorption sites for CO 2 and the capacity follows the charge-to-diameter ratio. However, the free volume of framework becomes predominant with increasing pressure and Mg-rho-ZMOF appears to possess the highest saturation capacity. The equilibrium locations of cations are observed to shift slightly upon CO 2 adsorption. Furthermore, the adsorption selectivity of CO 2/H 2 mixture increases as Cs + < Rb + < K + < Na + < Ca 2+ < Mg 2+ ≈ Al 3+. At ambient conditions, the selectivity is in the range of 800-3000 and significantly higher than in other nanoporous materials. In the presence of 0.1% H 2O, the selectivity decreases drastically because of the competitive adsorption between H 2O and CO 2, and shows a similar value in all of the cation-exchanged rho-ZMOFs. This simulation study provides microscopic insight into the important role of cations in governing gas adsorption and separation, and suggests that the performance of ionic rho-ZMOF can be tailored by cations. © 2012 American Chemical Society.

  18. Adsorption of zinc on manganite (γ-MnOOH):particle concentration effect and adsorption reversibility

    Institute of Scientific and Technical Information of China (English)

    QIN Yan-wen; PAN Gang; ZHANG Ming-ming; LI Xian-liang

    2004-01-01

    The adsorption and desorption processes of Zn(Ⅱ) on γ-MnOOH as a function of particle concentrations (Cp) were studied. An obvious Cp effect was observed in this adsorption system. The degree of adsorption hysteresis increased greatly with the increasing of Cp, indicating that the extent of the real metastable-equilibrium states deviating from the ideal equilibrium state was enhanced with the increasing of Cp. The Cp-reversibility relationship confirmed the metastable-equilibrium adsorption (MEA) inequality (Pan, 1998a), which was the core formulation of the MEA theory. Because the MEA inequality was based on the basic hypothesis of MEA theory that adsorption density Г is not a state variable, the Cp-reversibility relationship gave indirect evidence to the basic hypothesis of MEA theory.

  19. Sorption phenomena of methanol on heat treated coal; Netsushori wo hodokoshita sekitan no methanol kyuchaku tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Yasuda, H.; Kaiho, M.; Yamada, O.; Soneda, Y.; Kobayashi, M.; Makino, M. [National Institute for Resources and Environment, Tsukuba (Japan)

    1996-10-28

    Experiments were carried out to learn methanol sorption characteristics of heat-treated coal. When Taiheiyo coal is heat-treated at 125{degree}C, performed with a first methanol adsorption at 25{degree}C, and then desorption at 25{degree}C, a site with strong interaction with methanol and a site with relatively weak interaction are generated in test samples. A small amount of methanol remains in both sites. Then, when the methanol is desorbed at as low temperature as 70{degree}C, the methanol in the site with strong interaction remains as it has existed therein, but the methanol in the site with relatively weak interaction desorbs partially, hence the adsorption amount in a second adsorption at 25{degree}C increases. However, when desorption is performed at as high temperature as 125{degree}C, the methanol in the site with strong interaction also desorbs, resulting in increased adsorption heat in the second adsorption. The adsorption velocity drops, however. Existence of methanol in a site with strong interaction affects the adsorption velocity, but no effect is given by methanol in a site with weak interaction. 3 refs., 4 figs.

  20. Conceptual adsorption models and open issues pertaining to performance assessment

    International Nuclear Information System (INIS)

    Recently several articles have been published that question the appropriateness of the distribution coefficient, Rd, concept to quantify radionuclide migration. Several distinct issues surrounding the modeling of nuclide retardation. The first section defines adsorption terminology and discusses various adsorption processes. The next section describes five commonly used adsorption conceptual models, specifically emphasizing what attributes that affect adsorption are explicitly accommodated in each model. I also review efforts to incorporate each adsorption model into performance assessment transport computer codes. The five adsorption conceptual models are (1) the constant Rd model, (2) the parametric Rd model, (3) isotherm adsorption models, (4) mass action adsorption models, and (5) surface-complexation with electrostatics models. The final section discusses the adequacy of the distribution ratio concept, the adequacy of transport calculations that rely on constant retardation factors and the status of incorporating sophisticated adsorption models into transport codes. 86 refs., 1 fig., 1 tab

  1. Competitive adsorption of heavy metal ions on peat

    Institute of Scientific and Technical Information of China (English)

    LIU Zhi-rong; ZHOU Li-min; WEI Peng; ZENG Kai; WEN Chuan-xi; LAN Hui-hua

    2008-01-01

    The uptake capacities, and the adsorption kinetics, of copper, Cu(Ⅱ), nickel, Ni(Ⅱ), and cadmium, Cd(Ⅱ), on peat have been studied under static conditions. The results show that the adsorption rates are rapid: equilibrium is reached in twenty minutes. The adsorption of copper, nickel and cadmium is pH dependent over the pH range from 2 to 6. The adsorption kinetics can be excellently described by the Elovich kinetic equation. The adsorption isotherm fits a Langmuir model very well. The adsorption capacifies follow the order Cu2+>Ni2+>Cd2+ in single-component systems and the competitive adsorption capacities fall in the decreasing order Cu2+> Ni2+>Cd2+ in multi-component systems. The adsorption capacities of these three heavy metal ions on peat are consistent with their observed competitive adsorption capacities.

  2. Adsorption behavior of molybdenum onto D314 ion exchange resin

    Institute of Scientific and Technical Information of China (English)

    王明玉; 蒋长俊; 王学文

    2014-01-01

    The adsorption behavior of molybdenum onto D314 was studied with the static adsorption method. The adsorption process was analyzed from thermodynamic and kinetic aspects. The experimental results show that the equilibrium adsorption data conform satisfactorily to the Langmuir equation. In the adsorption process of D314 for molybdenum, the enthalpy changeΔH is positive when temperature is in the range of 298−338 K, which indicates that the adsorption is an endothermic process, and the elevated temperature benefits to the adsorption. Kinetic analysis shows that the adsorption rate is controlled by intraparticle diffusion and chemical diffusion at the same time. The adsorption mechanism of molybdenum onto D314 was discussed based on IR spectra.

  3. Conceptual adsorption models and open issues pertaining to performance assessment

    International Nuclear Information System (INIS)

    Recently several articles have been published that question the appropriateness of the distribution coefficient, Rd, concept to quantify radionuclide migration. Several distinct issues are raised by various critics. In this paper I provide some perspective on issues surrounding the modeling of nuclide retardation. The first section defines adsorption terminology and discusses various adsorption processes. The next section describes five commonly used adsorption conceptual models, specifically emphasizing what attributes that affect adsorption are explicitly accommodated in each model. I also review efforts to incorporate each adsorption model into performance assessment transport computer codes. The five adsorption conceptual models are (1) the constant Rd model, (2) the parametric Rd model, (3) isotherm adsorption models, (4) mass-action adsorption models, and (5) surface-complexation with electrostatics models. The final section discusses the adequacy of the distribution ratio concept, the adequacy of transport calculations that rely on constant retardation factors and the status of incorporating sophisticated adsorption models into transport codes

  4. Heat Rash or Prickly Heat (Miliaria Rubra)

    Science.gov (United States)

    ... rash and rashes clinical tools newsletter | contact Share | Heat Rash or Prickly Heat (Miliaria Rubra) Information for adults A A A ... bumps can suddenly occur, as seen here. Overview Heat rash (miliaria rubra), also known as prickly heat, ...

  5. Adsorption of tellurium ions by nickel oxide

    Energy Technology Data Exchange (ETDEWEB)

    Edwards, W.J.; Bateman, J.M.

    1976-05-01

    This study was undertaken to investigate the mechanism of the adsorption process, and to provide chemistry data useful for the design of a Failed Fuel Detection and Location system for pressurized water power reactors. Such systems frequently operate by monitoring the level of a selected fission product in the coolant from each rod channel by means of its nuclear radiation. $sup 132$Te is a suitable nuclide for such monitoring and its adsorption on walls of a chamber offers a particularly simple and convenient preconcentration step. The method was to observe the depletion of tellurite ion from a solution of known initial concentration through adsorption by a NiO suspension. The activity of the samples and hence the tellurium concentration were measured with a Ge(Li) spectrometer, which permitted the 230 keV peak of $sup 132$Te to be isolated from the spectrum of the $sup 132$I daughter. The study shows that adsorption process proceeds by a dehydration reaction between -OH groups on the hydroxylated surface and similar groups on the adsorbing species. The equilibrium adsorption ratio is controlled by the solution pH by its effect on the relative distribution of the neutral, monobasic and dibasic tellurite species via the two acid ionization constants.

  6. Adsorption behavior of heavy metals on biomaterials.

    Science.gov (United States)

    Minamisawa, Mayumi; Minamisawa, Hiroaki; Yoshida, Shoichiro; Takai, Nobuharu

    2004-09-01

    We have investigated adsorption of Cd(II) and Pb(II) at pH 2-6.7 onto the biomaterials chitosan, coffee, green tea, tea, yuzu, aloe, and Japanese coarse tea, and onto the inorganic adsorbents, activated carbon and zeolite. High adsorptive capabilities were observed for all of the biomaterials at pH 4 and 6.7. In the adsorption of Cd(II), blend coffee, tea, green tea, and coarse tea have comparable loading capacities to activated carbon and zeolite. Although activated carbon, zeolite, and chitosan are utilized in a variety of fields such as wastewater treatment, chemical and metallurgical engineering, and analytical chemistry, these adsorbents are costly. On the other hand, processing of the test biomaterials was inexpensive, and all the biomaterials except for chitosan were able to adsorb large amounts of Pb(II) and Cd(II) ions after a convenient pretreatment of washing with water followed by drying. The high adsorption capability of the biomaterials prepared from plant materials is promising in the development of a novel, low-cost adsorbent. From these results, it is concluded that heavy metal removal using biomaterials would be an effective method for the economic treatment of wastewater. The proposed adsorption method was applied to the determination of amounts of Cd(II) and Pb(II) in water samples. PMID:15373400

  7. Adsorption of iodine on silver wire

    International Nuclear Information System (INIS)

    It is an important process in which iodine is adsorbed on silver wire during the preparation of 125I seed sources. In this paper, a technique of adsorption of iodine on silver wire was studied. The influence of several factors, such as the type of reagent for halogenation, the time for halogenation, the time for adsorption, pH value, ion concentration, carrier iodine and so on, on the utilization rate of 131I was investigated, and the effectiveness of our proposed technique for adsorption of iodine on silver wire was confirmed. The procedure is summarized as follows: silver wire acidification: using 4 mol/L HNO3 as halogenation agent, stirring acidified for 20 min; silver wire halogenation: used 2 mol/L NaClO3 as halogenated agent, halogenation for 3 h; adsorption of iodine on silver wire: room temperature, pH value for the reaction is about 3, the time for adsorption is 30 min, carrier iodine is 27.5 μg. Original radioactivity of reaction solution was determined based on radioactivity of source-core that user required. (authors)

  8. Adsorption of Cadmium By Silica Chitosan

    Directory of Open Access Journals (Sweden)

    Moftah Ali

    2013-03-01

    Full Text Available The adsorption process depends on initial concentration of Cd2+ and ratio of  chitosan in adsorbent. The present study deals with the competitive adsorption of Cd2+ ion onto silica graft with chitosan. Batch adsorption experiments were performed at five different initial Cd2+ concentrations (5, 10, 15, 20 and 25 ppm, on five different proportion from silica to chitosan (100%, 95%, 85%, 75% and 65% as adsorbent at pH 5. In the recovery process, the high recovery at 0.5 mg and observed the recovery decrease with increasing the initial concentration of Cd2+, and the low recovery at 0.25 mg from Cd2+. In this study, the adsorption capacity of Cd2+ in regard to the ratio of silica and chitosan hybrid adsorbents are examined in detail. The aim of this study to explore effects of initial concentrations of Cd2+, and the ratio of silica to chitosan on the adsorption and recovery of Cd2+.

  9. Modification of carbon-coated TiO2 by iron to increase adsorptivity and photoactivity for phenol.

    Science.gov (United States)

    Tryba, B; Toyoda, M; Morawski, A W; Inagaki, M

    2005-07-01

    Carbon-coated TiO(2) modified by iron, were prepared from TiO(2) of anatase structure and PET modified by FeC(2)O(4). Catalysts were prepared by mixing powders of TiO(2) and modified PET and heating at different temperatures, from 400 to 800 degrees C under flow of Ar gas. High adsorption of phenol was observed on the catalyst heated at 400 degrees C, confirmed by FT-IR analysis. On this catalyst, fast rate of phenol decomposition was achieved by addition of small amount of H(2)O(2) to the reaction mixture. Phenol decomposition proceeded mainly through the direct oxidation of phenol species adsorbed on the catalyst surface due to the photo-Fenton reaction. Iron-modified carbon-coated TiO(2) catalysts heated at 500-800 degrees C showed almost no phenol adsorption or oxidation. PMID:15950040

  10. PERFORMANCE STUDY OF A TWO STAGE SOLAR ADSORPTION REFRIGERATION SYSTEM

    Directory of Open Access Journals (Sweden)

    BAIJU. V

    2011-07-01

    Full Text Available The present study deals with the performance of a two stage solar adsorption refrigeration system with activated carbon-methanol pair investigated experimentally. Such a system was fabricated and tested under the conditions of National Institute of Technology Calicut, Kerala, India. The system consists of a parabolic solar concentrator,two water tanks, two adsorbent beds, condenser, expansion device, evaporator and accumulator. In this particular system the second water tank is act as a sensible heat storage device so that the system can be used during night time also. The system has been designed for heating 50 litres of water from 25oC to 90oC as well ascooling 10 litres of water from 30oC to 10oC within one hour. The performance parameters such as specific cooling power (SCP, coefficient of performance, solar COP and exergetic efficiency are studied. The dependency between the exergetic efficiency and cycle COP with the driving heat source temperature is also studied. The optimum heat source temperature for this system is determined as 72.4oC. The results show that the system has better performance during night time as compared to the day time. The system has a mean cycle COP of 0.196 during day time and 0.335 for night time. The mean SCP values during day time and night time are 47.83 and 68.2, respectively. The experimental results also demonstrate that the refrigerator has cooling capacity of 47 to 78 W during day time and 57.6 W to 104.4W during night time.

  11. ADSORPTION OF METHYLENE BLUE FROM AQUEOUS SOLUTION ON ATTAPULGITE

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Batch adsorption experiments were carried out for the removal of methylene blue (MB) from aqueous solution using attapulgite as adsorbent. The effects of various parameters such as temperature, contact time, the pH value, and attapulgite dosage on the adsorption performance were investigated. The standard curve and regression equation were established by spectrophotometry. The adsorption experimental results showed that the adsorption equilibrium data were well in accord with Langmuir adsorptive model. The optimal result was acquired under the experimental condition of attapulgite dosage 0.18g, MB concentration 50.0mg/L, pH 10, and adsorption time 20min at room temperature.

  12. Adsorption on Highly Ordered Porous Alumina

    Science.gov (United States)

    Mistura, Giampaolo; Bruschi, Lorenzo; Lee, Woo

    2016-10-01

    Porous anodic aluminum oxide (AAO) is characterized by a regular arrangement of the pores with a narrow pore size distribution over extended areas, uniform pore depth, and solid pore walls without micropores. Thanks to significant improvements in anodization techniques, structural engineering of AAO allows to accurately tailor the pore morphology. These features make porous AAO an excellent substrate to study adsorption phenomena. In this paper, we review recent experiments involving the adsorption in porous AAO. Particular attention will be devoted to adsorption in straight and structured pores with a closed end which shed new light on fundamental issues like the origin of hysteresis in closed end pores and the nature of evaporation from ink-bottle pores. The results will be compared to those obtained in other synthetic materials like porous silicon and silica.

  13. GENERAL: Cluster Growth Through Monomer Adsorption Processes

    Science.gov (United States)

    Ke, Jian-Hong; Lin, Zhen-Quan; Chen, Xiao-Shuang

    2010-02-01

    We propose a monomer adsorption model, in which only the monomers are allowed to diffuse and adsorb onto other clusters. By means of the generalized rate equation we investigate the kinetic behavior of the system with a special rate kernel. For the system without monomer input, the concentration aj(t) of the Aj clusters (j > 1) asymptotically retains a nonzero quantity, while for the system with monomer input, it decays with time and vanishes finally. We also investigate the kinetics of an interesting model with fixed-rate monomer adsorption. For the case without monomer source, the evolution of the system will halt at a finite time; while the system evolves infinitely in time in the case with monomer source. Finally, we also suggest a connection between the fixed-rate monomer adsorption systems and growing networks.

  14. Adsorption on smooth electrodes: A radiotracer study

    International Nuclear Information System (INIS)

    Adsorption on solids is a complicated process and in most cases, occurs as the early stage of other more complicated processes, i.e. chemical reactions, electrooxidation, electroreduction. The research reported here combines the electroanalytical method, cyclic voltammetry, and the use of radio-labeled isotopes, soft beta emitters, to study adsorption processes at smooth electrodes. The in-situ radiotracer method is highly anion (molecule) specific and provides information on the structure and composition of the electric double layer. The emphasis of this research was on studying adsorption processes at smooth electrodes of copper, gold, and platinum. The application of the radiotracer method to these smooth surfaces have led to direct in-situ measurements from which surface coverage was determined; anions and molecules were identified; and weak interactions of adsorbates with the surface of the electrodes were readily monitored. 179 refs

  15. Adsorption of aluminium by stream particulates.

    Science.gov (United States)

    Tipping, E; Ohnstad, M; Woof, C

    1989-01-01

    An experimental study was made of the adsorption of aluminium by fine particulates from Whitray Beck, a hill stream in NW England. Adsorption increased with Al(3) activity, pH and concentration of particles, and could be quantitatively described by the empirical equation: [Formula: see text] [particles] where square brackets indicate concentrations, curly brackets, activities, and alpha, beta and gamma are constants with values of 5.14x10(-10) (mol litre(-1))(2.015) (g particles litre(-1))(-1), 0.457, and 1.472, respectively. For the experimental data, the equation gave a correlation ratio of 0.99. The equation accounts reasonably well for the adsorption of Al by particulates from seven other streams. In applying the equation, it must be borne in mind that the desorption kinetics of Al depend on pH, and rapid reversibility (or=10%) of total monomeric Al. PMID:15092454

  16. Novel nano bearings constructed by physical adsorption

    Science.gov (United States)

    Zhang, Yongbin

    2015-09-01

    The paper proposes a novel nano bearing formed by the physical adsorption of the confined fluid to the solid wall. The bearing is formed between two parallel smooth solid plane walls sliding against one another, where conventional hydrodynamic lubrication theory predicted no lubricating effect. In this bearing, the stationary solid wall is divided into two subzones which respectively have different interaction strengths with the lubricating fluid. It leads to different physical adsorption and slip properties of the lubricating fluid at the stationary solid wall respectively in these two subzones. It was found that a significant load-carrying capacity of the bearing can be generated for low lubricating film thicknesses, because of the strong physical adsorption and non-continuum effects of the lubricating film.

  17. Hydrophobic nano-carrier for lysozyme adsorption

    Indian Academy of Sciences (India)

    CANAN ALTUNBAS; FULDEN ZEYNEP URAL; MURAT UYGUN; NESIBE AVCIBASI; UGUR AVCIBASI; DENIZ AKTAS UYGUN; SINAN AKGÖL

    2016-04-01

    In this work, poly(HEMA–APH) nanoparticles were synthesized by surfactant-free emulsion polymerization technique.Magnetic behaviour was introduced by simple addition of Fe$_3$O$_4$ into the polymerization medium.Characterization of the nanoparticle was carried out by FTIR, ESR, SEM, AFM and EDX analyses. These synthesized magnetic nanoparticles were used for adsorption of lysozyme. For this purpose, adsorption conditions wereoptimized and maximum lysozyme binding capacity was found to be 278.8 mg g$^{−1}$ polymer in pH 7.0 phosphate buffer at 25$^{\\circ}$C. Desorption and reusability properties of the nanoparticles were investigated and lysozyme adsorption efficiency did not change significantly at the end of the 10 successive reuses.

  18. Adsorption on Highly Ordered Porous Alumina

    Science.gov (United States)

    Mistura, Giampaolo; Bruschi, Lorenzo; Lee, Woo

    2016-04-01

    Porous anodic aluminum oxide (AAO) is characterized by a regular arrangement of the pores with a narrow pore size distribution over extended areas, uniform pore depth, and solid pore walls without micropores. Thanks to significant improvements in anodization techniques, structural engineering of AAO allows to accurately tailor the pore morphology. These features make porous AAO an excellent substrate to study adsorption phenomena. In this paper, we review recent experiments involving the adsorption in porous AAO. Particular attention will be devoted to adsorption in straight and structured pores with a closed end which shed new light on fundamental issues like the origin of hysteresis in closed end pores and the nature of evaporation from ink-bottle pores. The results will be compared to those obtained in other synthetic materials like porous silicon and silica.

  19. Heavy metal adsorption by sulphide mineral surfaces

    Science.gov (United States)

    Jean, Gilles E.; Bancroft, G. Michael

    1986-07-01

    The adsorption of aqueous Hg 2+, Pb 2+, Zn 2+ and Cd 2+ complexes on a variety of sulphide minerals has been studied as a function of the solution pH and also as a function of the nature of the ligands in solution. Sulphide minerals are excellent scavengers for these heavy metals. The adsorption is strongly pH dependent, i.e. there is a critical pH at which the adsorption increases dramatically. The pH dependence is related to the hydrolysis of the metal ions. Indirect evidence suggests that the hydrolyzed species are adsorbed directly on the sulphide groups, probably as a monolayer. The results also suggest the presence of MCI n2- n species physisorbed on the adsorbed monolayer. A positive identification of the adsorbed species was not possible using ESCA/XPS.

  20. Heat exchanger

    International Nuclear Information System (INIS)

    A heat exchanger having primary and secondary conduits in heat-exchanging relationship is described comprising: at least one serpentine tube having parallel sections connected by reverse bends, the serpentine tube constituting one of the conduits; a group of open-ended tubes disposed adjacent to the parallel sections, the open-ended tubes constituting the other of the conduits, and forming a continuous mass of contacting tubes extending between and surrounding the serpentine tube sections; and means securing the mass of tubes together to form a predetermined cross-section of the entirety of the mass of open-ended tubes and tube sections

  1. Heat transfer

    CERN Document Server

    Holman, J P

    2010-01-01

    As one of the most popular heat transfer texts, Jack Holman's "Heat Transfer" is noted for its clarity, accessible approach, and inclusion of many examples and problem sets. The new tenth edition retains the straight-forward, to-the-point writing style while covering both analytical and empirical approaches to the subject. Throughout the book, emphasis is placed on physical understanding while, at the same time, relying on meaningful experimental data in those situations that do not permit a simple analytical solution. New examples and templates provide students with updated resources for computer-numerical solutions.

  2. Rapid modification of montmorillonite with novel cationic Gemini surfactants and its adsorption for methyl orange

    Energy Technology Data Exchange (ETDEWEB)

    Liu Bo [State Key Laboratory of Pulp and Paper Engineering, School of Light Industry and Food, South China University of Technology, Guangzhou 510640, Guangdong (China); Wang Xiaoying, E-mail: xyw@scut.edu.cn [State Key Laboratory of Pulp and Paper Engineering, School of Light Industry and Food, South China University of Technology, Guangzhou 510640, Guangdong (China); Yang Bin [State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, Guangdong (China); Sun Runcang, E-mail: ynsun@scut.edu.cn [State Key Laboratory of Pulp and Paper Engineering, School of Light Industry and Food, South China University of Technology, Guangzhou 510640, Guangdong (China); Institute of Biomass Chemistry and Technology, Beijing Forestry University, Beijing 100083 (China)

    2011-11-01

    Graphical abstract: A rapid method was developed to prepare organic montmorillonite (organo-MMT) using three novel Gemini surfactant by microwave irradiation of 1 h, which was more effective than conventional heating method of 8-48 h. The results showed that as the dosage and chain length of Gemini surfactants increased, the amount of the intercalary or adsorbed surfactant on the organoclay gradually increased, and the amount of methyl orange adsorbed onto the organo-MMTs also enhanced. Highlights: {yields} Rapid modifications of montmorillonite with Gemini surfactants were performed for 1 h. {yields} The amount of the surfactant on organoclay was examined by thermogravimetric analysis. {yields} Surfactant amount on the organoclay increased with increasing chain length and dosage. {yields} All organoclays displayed more excellent adsorption capacities on dye than clay. {yields} The adsorption capacity was positive to the amount and chain length of the surfactant. - Abstract: A rapid method was developed to prepare organic montmorillonite (organo-MMT) using three novel Gemini surfactants by microwave irradiation of 1 h, which was more effective than conventional heating method of 8-48 h. The structure and morphology of organo-MMTs were characterized by XRD, FT-IR, TEM and SEM. The adsorption amount of Gemini surfactants on MMT and the thermal stability of organo-MMTs were investigated by thermogravimetric analysis (TGA). The results indicated that Gemini surfactants were more efficient than cetyltrimethyl ammonium bromide in the modification of MMT, the organoclays obtained by microwave irradiation method had larger layer spacing than those from traditional heating method. And with the increase of the dosage and chain length of Gemini surfactants, the amount of the intercalary or adsorbed surfactant on the organoclay gradually increased, whereas the thermal stability weakened appropriately. Besides, the adsorption results for methyl orange indicated that all organo

  3. Silver impregnated carbon for adsorption and desorption of elemental mercury vapors

    Institute of Scientific and Technical Information of China (English)

    Despina Karatza; Marina Prisciandaro; Amedeo Lancia; Dino Musmarra

    2011-01-01

    The Hg0 vapor adsorption experimental results on a novel sorbent obtained by impregnating a commercially available activated carbon (Darco G60 from BDH) with silver nitrate were reported.The study was performed by using a fundamental approach,in an apparatus at laboratory scale in which a synthetic flue gas,formed by Hg0 vapors in a nitrogen gas stream,at a given temperature and mercury concentration,was flowed through a fixed bed of adsorbent material.Breakthrough curves and adsorption isotherms were obtained for bed temperatures of 90,120 and 150°C and for Hg0 concentrations in the gas varying in the range of 0.8-5.0 mg/m3.The experimental gas-solid equilibrium data were used to evaluate the Langmuir parameters and the heat of adsorption.The experimental results showed that silver impregnated carbon was very effective to capture elemental mercury and the amount of mercury adsorbed by the carbon decreased as the bed temperature increased.In addition,to evaluate the possibility of adsorbent recovery,desorption was also studied.Desorption runs showed that both the adsorbing material and the mercury could be easily recovered,since at the end of desorption the residue on solid was almost negligible.The material balance on mercury and the constitutive equations of the adsorption phenomenon were integrated,leading to the evaluation of only one kinetic parameter which fits well both the experimentally determined breakthrough and desorption curves.

  4. Self-flocculated powdered activated carbon with different oxidation methods and their influence on adsorption behavior.

    Science.gov (United States)

    Gong, Zailin; Li, Shujin; Ma, Jun; Zhang, Xiangdong

    2016-03-01

    The commercial powdered activated carbon (PAC) has been selectively oxidized by two methods. The two oxidized methods are wet oxidation with ammonium persulfate and thermal treatment after acidification with hydrochloride acid, respectively. The two oxidized PAC were then functionalized with thermoresponsive poly (N-isopropylacrylamide) (PNIPAM) in aqueous solution at ambient temperature. Comparing the two oxidized PAC products and their grafted derivatives, the oxidized PAC modified with thermal treatment after acidification shows larger surface area of 1184 m(2)/g and better adsorption of bisphenol A. Its derivative also exhibits relatively large surface area and adsorption capacity after grafted with PNIPAM. The maximum surface adsorption capacity simulated under Langmuir Models reached 156 mg/g. In addition, the grafted PAC products show self-flocculation behaviors with rapid response to temperature because of the thermal phase transition and entanglement behaviors of PNIPAM. The present study provides a new way to obtain carboxyl-rich activated carbon with large surface area and better adsorption capacity. The retrievable grafted PAC with good self-flocculation effect responsive to temperature will have high potential application in water remediation which requires pre-heating and emergency water treatment in the wild. PMID:26551226

  5. Irreversible adsorption of atmospheric helium on olivine: A lobster pot analogy

    Science.gov (United States)

    Protin, Marie; Blard, Pierre-Henri; Marrocchi, Yves; Mathon, François

    2016-04-01

    This study reports new experimental results that demonstrate that large amounts of atmospheric helium may be adsorbed onto the surfaces of olivine grains. This behavior is surface-area-related in that this contamination preferentially affects grains that are smaller than 125 μm in size. One of the most striking results of our study is that in vacuo heating at 900 °C for 15 min is not sufficient to completely remove the atmospheric contamination. This suggests that the adsorption of helium may involve high-energy trapping of helium through irreversible anomalous adsorption. This trapping process of helium can thus be compared to a "lobster pot" adsorption: atmospheric helium easily gets in, but hardly gets out. While this type of behavior has previously been reported for heavy noble gases (Ar, Kr, Xe), this is the first time that it has been observed for helium. Adsorption of helium has, until now, generally been considered to be negligible on silicate surfaces. Our findings have significant implications for helium and noble gas analysis of natural silicate samples, such as for cosmic-ray exposure dating or noble gas characterization of extraterrestrial material. Analytical procedures in future studies should be adapted in order to avoid this contamination. The results of this study also allow us to propose an alternative explanation for previously described matrix loss of cosmogenic 3He.

  6. Electrothermal adsorption and desorption of volatile organic compounds on activated carbon fiber cloth.

    Science.gov (United States)

    Son, H K; Sivakumar, S; Rood, M J; Kim, B J

    2016-01-15

    Adsorption is an effective means to selectively remove volatile organic compounds (VOCs) from industrial gas streams and is particularly of use for gas streams that exhibit highly variable daily concentrations of VOCs. Adsorption of such gas streams by activated carbon fiber cloths (ACFCs) and subsequent controlled desorption can provide gas streams of well-defined concentration that can then be more efficiently treated by biofiltration than streams exhibiting large variability in concentration. In this study, we passed VOC-containing gas through an ACFC vessel for adsorption and then desorption in a concentration-controlled manner via electrothermal heating. Set-point concentrations (40-900 ppm(v)) and superficial gas velocity (6.3-9.9 m/s) were controlled by a data acquisition and control system. The results of the average VOC desorption, desorption factor and VOC in-and-out ratio were calculated and compared for various gas set-point concentrations and superficial gas velocities. Our results reveal that desorption is strongly dependent on the set-point concentration and that the VOC desorption rate can be successfully equalized and controlled via an electrothermal adsorption system.

  7. Examination of zinc adsorption capacity of soils treated with different pyrolysis products

    Directory of Open Access Journals (Sweden)

    Rétháti Gabriella

    2014-11-01

    Full Text Available Organic matter input into soils is essential regarding agricultural, environmental and soil science aspects as well. However, the application of the pyrolysed forms of biochars and materials with different organic matter content gained more attention in order to decrease the emission of the green house gases (CO2, N2O from the soil. During pyrolysis, the materials containing high organic matter (biomass-originated organic matter are heated in oxygen-free (or limited amount of oxygen environment. As a result, the solid phase, which remains after eliminating the gases and liquid phase, is more stable compared to the original product, it cannot be mineralized easily in the soil and its utilization is more beneficial in terms of climatic aspects. Furthermore, it can improve soil structure and it can retain soil moisture and cations in the topsoil for long periods of time, which is very important for plants. In our experiment, the effects of biochar and bone char were examined on soils by zinc adsorption experiments. Based on our experiments, we concluded that the pyrolysis products can have significant Zn adsorption capacity compared to the soil. Bone ash can adsorb more Zn than the charcoal product. The Zn adsorption capacity of soils treated by pyrolysis products can be described by Langmuir adsorption isotherms. However, based on the amount of pyrolysis products, one or two term Langmuir isotherm fits well on the experiment data, which depends on the time the pyrolysis product has spent in the soil.

  8. Multilayer adsorption mechanism of coal surface adsorption to three oxygen molecule

    Institute of Scientific and Technical Information of China (English)

    WANG Xue-feng; LI Zhi-gang; WANG Xin-yang; SUN Yan-qiu

    2008-01-01

    Compared chemical bonds change situation of coal surface and oxygen mole-cules before and after coal surface adsorption to three oxygen molecules,after adsorption each oxygen molecule's chemical bond got longer,but had not broken,the coal surface's chemical bonds changed a little.It proves that the coal surface adsorption to five oxygen molecules is the physical adsorption and is the multilayer adsorption according to the optimized geometry structure.The oxygen molecule's bond length that adsorbed by the side chain of coal surface changes most from 1.258 2×10 10 m to 1.316 8×10 10 m,which indicates this oxygen molecular to be the liveliest.The analysis of charge population reveals that how many electrons shift in the atom is directly proportional to the change of chemical bonds.The more electrons shift in the atom,the more molecule chemical bond changes.In the adsorption state,which is composed of coal surface and five oxygen molecules,the vibration frequency of oxygen molecules drops off,and the adsorption energy reached by calculation is 202.11 kJ/mol.

  9. Multilayer adsorption mechanism of coal surface adsorption to three oxygen molecule

    Institute of Scientific and Technical Information of China (English)

    WANG Xue-feng; LI Zhi-gang; WANG Xin-yang; SUN Yan-qiu

    2008-01-01

    Compared chemical bonds change situation of coal surface and oxygen mole-cules before and after coal surface adsorption to three oxygen molecules, after adsorption each oxygen molecule's chemical bond got longer, but had not broken, the coal surface's chemical bonds changed a little. It proves that the coal surface adsorption to five oxygen molecules is the physical adsorption and is the multilayer adsorption according to the op-timized geometry structure. The oxygen molecule's bond length that adsorbed by the side chain of coal surface changes most from 1.258 2×10-10 m to 1.316 8×10-10 m, which indi-cates this oxygen molecular to be the liveliest. The analysis of charge population reveals that how many electrons shift in the atom is directly proportional to the change of chemical bonds. The more electrons shift in the atom, the more molecule chemical bond changes. In the adsorption state, which is composed of coal surface and five oxygen molecules, the vibration frequency of oxygen molecules drops off, and the adsorption energy reached by calculation is 202.11 kJ/mol.

  10. Simultaneous metal adsorption on tannin resins

    International Nuclear Information System (INIS)

    Vegetable tannin sorbent is evaluated as ion exchange resin using a multitracer study on the adsorption behavior of various elements. Lisiloma latisiliqua L. tannins, polycondensated into spherical pellets were chosen as sorbent resin material. Sorption evaluation of Ce, Cu(II), U(VI), Eu, Fe(III), Th, Nd as representatives of different classes of metal ions were done at different pH values. The distribution ratio of the studied elements was calculated from laboratory experiments. Tannic ion exchange material shows excellent ability for actinides and rare earth elements adsorption from waters. Using radiotracers, the number of catechins subunits involve in each tannin-metal complex was determined. (author)

  11. Adsorption on mixtures of ion exchangers

    International Nuclear Information System (INIS)

    A theoretical study has been made of adsorption on mixtures of ion exchangers. The effect of variables such as the concentration of the ion being adsorbed, the concentration of the supporting electrolyte, loading, the values of the capacities and equilibrium constants for the various exchange processes, and the fraction of each adsorber in the mixture on the observed distribution coefficient has been investigated. A computer program has been written to facilitate the calculation of distribution coefficients for the adsorption of an ion on a given mixture of ion exchangers under a specified set of conditions

  12. Adsorption Behavior of Plutonium on Clay

    Institute of Scientific and Technical Information of China (English)

    LONG; Hao-qi; BAO; Liang-jin; SONG; Zhi-xin; WANG; Bo

    2013-01-01

    In this study,the adsorption distribution ratios of Pu in the Longdong clays were measured with batch method under hypoxic conditions,and the influence of the liquid-solid ratio and pH on the adsorption distribution ratio also was discussed.The initial concentration of Pu is about 1×10-10 mol/L,and the solution pH value was adjusted with NaOH or HClO4.The temperature of experiments was(30±

  13. Adsorption of amylase enzyme on ultrafiltration membranes

    DEFF Research Database (Denmark)

    Beier, Søren; Enevoldsen, Ann Dorrit; Kontogeorgis, Georgios;

    2007-01-01

    A method to measure the static adsorption on membrane surfaces has been developed and described. The static adsorption of an amylase-F has been measured on two different ultrafiltration membranes, both with a cut-off value of 10 kDa (a PES membrane and the ETNA10PP membrane, which is a surface-mo...... is independent of the membrane type. At higher concentrations of enzyme, concentration polarization effects can not be neglected. Therefore stagnant film theory and the osmotic pressure model can describe the dependency between flux and bulk concentration....

  14. Heat-Related Illnesses

    Medline Plus

    Full Text Available ... for signs of heat stroke or exhaustion. Heat Stroke and Exhaustion Symptoms of early heat exhaustion symptoms ... heavy sweating; nausea; and giddiness. Symptoms of heat stroke (late stage of heat illness) include flushed, hot, ...

  15. Modelling of CO2 Adsorption from Exhaust Gases

    Science.gov (United States)

    Panowski, Marcin; Klainy, Roman; Sztelder, Karol

    World tendencies in environmental protection points out necessity of reduction of CO2 emission to atmosphere. The one of the main sources of CO2 emission is placed in energy sector where electric energy and heat are produced based on fossil fuels combustion. Therefore, it seems to be necessary to perform research on CO2 emission reduction in this sector. The main aim of work presented in this paper was focused on the analysis and assessment of CO2 separation from flue gases on the total efficiency of conventional power station. The paper shows the numerical calculations performed with IPSEpro simulation software by SimTech.For the CO2 separation the PTSA (pressure-Temperature Swing Adsorption) process was chosen and the numerical as well as simulation model of such process was formulated. The calculations were made for few different adsorbents taking into account varying values of such thermodynamic parameters of separation process like temperature or pressure. Results obtained from calculations point out that mixed PTSA technology is not very energy consuming process. Owing to utilisation of waste heat for sorbent regeneration, it does not decrease the total efficiency for more than 0.6%. However, that is caused by separation only, while after that CO2 must be compressed for further treatment.

  16. Study on two stage activated carbon/HFC-134a based adsorption chiller

    Science.gov (United States)

    >K Habib,

    2013-06-01

    In this paper, a theoretical analysis on the performance of a thermally driven two-stage four-bed adsorption chiller utilizing low-grade waste heat of temperatures between 50°C and 70°C in combination with a heat sink (cooling water) of 30°C for air-conditioning applications has been described. Activated carbon (AC) of type Maxsorb III/HFC-134a pair has been examined as an adsorbent/refrigerant pair. FORTRAN simulation program is developed to analyze the influence of operating conditions (hot and cooling water temperatures and adsorption/desorption cycle times) on the cycle performance in terms of cooling capacity and COP. The main advantage of this two-stage chiller is that it can be operational with smaller regenerating temperature lifts than other heat-driven single-stage chillers. Simulation results shows that the two-stage chiller can be operated effectively with heat sources of 50°C and 70°C in combination with a coolant at 30°C.

  17. Adsorption desalination: An emerging low-cost thermal desalination method

    KAUST Repository

    Ng, K. C.

    2013-01-01

    Desalination, other than the natural water cycle, is hailed as the panacea to alleviate the problems of fresh water shortage in many water stressed countries. However, the main drawback of conventional desalination methods is that they are energy intensive. In many instances, they consumed electricity, chemicals for pre- and post-treatment of water. For each kWh of energy consumed, there is an unavoidable emission of Carbon Dioxide (CO2) at the power stations as well as the discharge of chemically-laden brine into the environment. Thus, there is a motivation to find new direction or methods of desalination that consumed less chemicals, thermal energy and electricity.This paper describes an emerging and yet low cost method of desalination that employs only low-temperature waste heat, which is available in abundance from either the renewable energy sources or exhaust of industrial processes. With only one heat input, the Adsorption Desalination (AD) cycle produces two useful effects, i.e., high grade potable water and cooling. In this article, a brief literature review, the theoretical framework for adsorption thermodynamics, a lumped-parameter model and the experimental tests for a wide range of operational conditions on the basic and the hybrid AD cycles are discussed. Predictions from the model are validated with measured performances from two pilot plants, i.e., a basic AD and the advanced AD cycles. The energetic efficiency of AD cycles has been compared against the conventional desalination methods. Owing to the unique features of AD cycle, i.e., the simultaneous production of dual useful effects, it is proposed that the life cycle cost (LCC) of AD is evaluated against the LCC of combined machines that are needed to deliver the same quantities of useful effects using a unified unit of $/MWh. In closing, an ideal desalination system with zero emission of CO2 is presented where geo-thermal heat is employed for powering a temperature-cascaded cogeneration plant.

  18. Assessing the adsorption properties of shales

    Science.gov (United States)

    Pini, Ronny

    2015-04-01

    Physical adsorption refers to the trapping of fluid molecules at near liquid-like densities in the pores of a given adsorbent material. Fine-grained rocks, such as shales, contain a significant amount of nanopores that can significantly contribute to their storage capacity. As a matter of fact, the current ability to extract natural gas that is adsorbed in the rock's matrix is limited, and current technology focuses primarily on the free gas in the fractures (either natural or stimulated), thus leading to recovery efficiencies that are very low. Shales constitute also a great portion of so-called cap-rocks above potential CO2 sequestration sites; hereby, the adsorption process may limit the CO2 mobility within the cap-rock, thus minimizing the impact of leakage on the whole operation. Whether it is an unconventional reservoir or a cap-rock, understanding and quantifying the mechanisms of adsorption in these natural materials is key to improve the engineering design of subsurface operations. Results will be presented from a laboratory study that combines conventional techniques for the measurement of adsorption isotherms with novel methods that allows for the imaging of adsorption using x-rays. Various nanoporous materials are considered, thus including rocks, such as shales and coals, pure clay minerals (a major component in mudrocks) and engineered adsorbents with well-defined nanopore structures, such as zeolites. Supercritical CO2 adsorption isotherms have been measured with a Rubotherm Magnetic Suspension balance by covering the pressure range 0.1-20~MPa. A medical x-ray CT scanner has been used to identify three-dimensional patterns of the adsorption properties of a packed-bed of adsorbent, thus enabling to assess the spatial variability of the adsorption isotherm in heterogeneous materials. The data are analyzed by using thermodynamically rigorous measures of adsorption, such as the net- and excess adsorbed amounts and a recently developed methodology is

  19. Thermal treatment of bentonite reduces aflatoxin b1 adsorption and affects stem cell death.

    Science.gov (United States)

    Nones, Janaína; Nones, Jader; Riella, Humberto Gracher; Poli, Anicleto; Trentin, Andrea Gonçalves; Kuhnen, Nivaldo Cabral

    2015-10-01

    Bentonites are clays that highly adsorb aflatoxin B1 (AFB1) and, therefore, protect human and animal cells from damage. We have recently demonstrated that bentonite protects the neural crest (NC) stem cells from the toxicity of AFB1. Its protective effects are due to the physico-chemical properties and chemical composition altered by heat treatment. The aim of this study is to prepare and characterize the natural and thermal treatments (125 to 1000 °C) of bentonite from Criciúma, Santa Catarina, Brazil and to investigate their effects in the AFB1 adsorption and in NC cell viability after challenging with AFB1. The displacement of water and mineralogical phases transformations were observed after the thermal treatments. Kaolinite disappeared at 500 °C and muscovite and montmorillonite at 1000 °C. Slight changes in morphology, chemical composition, and density of bentonite were observed. The adsorptive capacity of the bentonite particles progressively reduced with the increase in temperature. The observed alterations in the structure of bentonite suggest that the heat treatments influence its interlayer distance and also its adsorptive capacity. Therefore, bentonite, even after the thermal treatment (125 to 1000 °C), is able to increase the viability of NC stem cells previously treated with AFB1. Our results demonstrate the effectiveness of bentonite in preventing the toxic effects of AFB1.

  20. The role of beaded activated carbon's surface oxygen groups on irreversible adsorption of organic vapors.

    Science.gov (United States)

    Jahandar Lashaki, Masoud; Atkinson, John D; Hashisho, Zaher; Phillips, John H; Anderson, James E; Nichols, Mark

    2016-11-01

    The objective of this study is to determine the contribution of surface oxygen groups to irreversible adsorption (aka heel formation) during cyclic adsorption/regeneration of organic vapors commonly found in industrial systems, including vehicle-painting operations. For this purpose, three chemically modified activated carbon samples, including two oxygen-deficient (hydrogen-treated and heat-treated) and one oxygen-rich sample (nitric acid-treated) were prepared. The samples were tested for 5 adsorption/regeneration cycles using a mixture of nine organic compounds. For the different samples, mass balance cumulative heel was 14 and 20% higher for oxygen functionalized and hydrogen-treated samples, respectively, relative to heat-treated sample. Thermal analysis results showed heel formation due to physisorption for the oxygen-deficient samples, and weakened physisorption combined with chemisorption for the oxygen-rich sample. Chemisorption was attributed to consumption of surface oxygen groups by adsorbed species, resulting in formation of high boiling point oxidation byproducts or bonding between the adsorbates and the surface groups. Pore size distributions indicated that different pore sizes contributed to heel formation - narrow micropores (<7Å) in the oxygen-deficient samples and midsize micropores (7-12Å) in the oxygen-rich sample. The results from this study help explain the heel formation mechanism and how it relates to chemically tailored adsorbent materials. PMID:27295065

  1. Evaluation of minimum desorption temperatures of thermal compressors in adsorption refrigeration cycles

    Energy Technology Data Exchange (ETDEWEB)

    Saha, B.B.; El-Sharkawy, I.I.; Chakraborty, A.; Koyama, S.; Srinivasan, K. [Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, 6-1 Kasuga-koen Kasuga, Fukuoka 816-8580 (Japan); Banker, N.D.; Dutta, P. [Department of Mechanical Engineering, Indian Institute of Science, Bangalore (India); Prasad, M. [Thermal Systems Division, ISRO Satellite Centre, Bangalore (India)

    2006-11-15

    The purpose of this paper is to identify the minimum desorption temperatures required to operate thermally driven adsorption beds of a solid sorption refrigeration system. The method is based on the evaluation of uptake efficiency of the adsorption bed and estimating there from conditions under which the compressor ceases to provide any throughput. The difference in the densities of the refrigerant between the inlet and outlet, the adsorption characteristics of the adsorbate-refrigerant pair and the void volume in the thermal compressor are the contributors to the manifestation of the desorption state. Among them, the void volume is a controllable parameter whose role is analogous to the clearance volume in a positive displacement compressor. The methodology has been tested out with three systems, namely, silica gel+water, activated carbon fiber+ethanol and activated carbon+HFC 134a systems. It is shown that waste heat at as low as 60{sup o}C can operate these systems which make them good energy conservation devices through recovery of low grade process waste heat. (author)

  2. A Novel Parametric Analysis of a Conventional Silica-Gel Water Adsorption Chiller

    Science.gov (United States)

    Alam, K. C. A.; Saha, B. B.; Akisawa, Atsushi; Kashiwagi, Takao

    A conventional adsorption chiller with silica gel as adsorbent and water as adsorbate has been analyzed numerically. In the present study, a non-dimensional simulation model has been presented and a set of non-dimensional parameters for conventional adsorption chiller has been derived. The results obtained by simulation method are confirmed by the experimental results. Simulation results show that switching speed is most influential parameter and there is an optimum switching speed for cooling capacity and COP. Results also show that system performance (cooling capacity and COP) is strongly affected by the number of transfer unit of adsorber/desorber, NTUa due to severe sensible heating/cooling requirements. The model is somewhat sensitive to the number of transfer unit of evaporator, NTUe. The number of transfer unit of condenser, NTUc is the least sensitive parameter. Finally, an investigation is made parametrically to obtain the optimum value of switching speed and the number of transfer unit, NTU of different component. The present model can be employed to analyze and to optimize the adsorption cooling/heat pump system.

  3. Experimental study on activated carbon-nitrogen pair in a prototype pressure swing adsorption refrigeration system

    Science.gov (United States)

    Anupam, Kumar; Palodkar, Avinash V.; Halder, G. N.

    2016-04-01

    Pressure swing adsorption of nitrogen onto granular activated carbon in the single-bed adsorber-desorber chamber has been studied at six different pressures 6-18 kgf/cm2 to evaluate their performance as an alternative refrigeration technique. Refrigerating effect showed a linear rise with an increase in the operating pressure. However, the heat of adsorption and COP exhibited initial rise with the increasing operating pressure but decreased later after reaching a maximum value. The COP initially increases with operating pressures however, with the further rise of operating pressure it steadily decreased. The highest average refrigeration, maximum heat of adsorption and optimum coefficient of performance was evaluated to be 415.38 W at 18 kgf/cm2, 92756.35 J at 15 kgf/cm2 and 1.32 at 12 kgf/cm2, respectively. The system successfully produced chilled water at 1.7 °C from ambient water at 28.2 °C.

  4. Theoretical Insight of Physical Adsorption for a Single Component Adsorbent + Adsorbate System: II. The Henry Region

    KAUST Repository

    Chakraborty, Anutosh

    2009-07-07

    The Henry coefficients of a single component adsorbent + adsorbate system are calculated from experimentally measured adsorption isotherm data, from which the heat of adsorption at zero coverage is evaluated. The first part of the papers relates to the development of thermodynamic property surfaces for a single-component adsorbent + adsorbate system1 (Chakraborty, A.; Saha, B. B.; Ng, K. C.; Koyama, S.; Srinivasan, K. Langmuir 2009, 25, 2204). A thermodynamic framework is presented to capture the relationship between the specific surface area (Ai) and the energy factor, and the surface structural and the surface energy heterogeneity distribution factors are analyzed. Using the outlined approach, the maximum possible amount of adsorbate uptake has been evaluated and compared with experimental data. It is found that the adsorbents with higher specific surface areas tend to possess lower heat of adsorption (ΔH°) at the Henry regime. In this paper, we have established the definitive relation between Ai and ΔH° for (i) carbonaceous materials, metal organic frameworks (MOFs), carbon nanotubes, zeolites + hydrogen, and (ii) activated carbons + methane systems. The proposed theoretical framework of At and AH0 provides valuable guides for researchers in developing advanced porous adsorbents for methane and hydrogen uptake. © 2009 American Chemical Society.

  5. Adsorption properties of glyphosate onto 330 anion exchange resin%330阴离子交换树脂对草甘膦的吸附性能

    Institute of Scientific and Technical Information of China (English)

    肖谷清; 龙立平; 何露; 余婷; 钟桐生

    2011-01-01

    采用静态吸附法研究了330阴离子交换树脂对水中草甘膦的吸附性能,并研究了吸附动力学;测定了溶液的pH值、温度、NaCl含量等因素对330树脂吸附草甘膦的影响.结果表明:330树脂对水中草甘膦的吸附速率快;在pH=2.69时对草甘膦的吸附性能最好;330树脂对草甘膦的吸附是放热、自发的过程,吸附等温线符合Freundlich方程;NaCl含量对330树脂吸附草甘膦有显著影响.%The objective of this work was to study the adsorption properties of glyphosate onto 330 anion exchange resin by static adsorption.The adsorption kinetics of glyphosate onto 330 resin was measured.The study focused on the effects of the solution pH, temperature and NaCl on the adsorption of glyphosate onto 330 resin.The results showed that adsorption rate of glyphosate onto 330 resin was fast.The adsorption at the solution pH of 2.69 was the most efficient for 330 resin.Heat was discharged during the adsorption and the adsorption occurred automatically.It was found that the adsorption isotherms were ? tted to Freundlich models.NaCl is one of the most important factors influencing the adsorption of glyphosate onto 330 resin.

  6. Removal of Pyrethrin from Aqueous Effluents by Adsorptive Micellar Flocculation

    Directory of Open Access Journals (Sweden)

    Pardon K. Kuipa

    2015-01-01

    Full Text Available The equilibrium adsorption of pyrethrin onto aggregates formed by the flocculation of micelles of the surfactant sodium dodecyl sulphate (SDS with aluminium sulphate is reported. The experimental results were analysed using different adsorption isotherms (Langmuir, Freundlich, Redlich-Peterson, Sips, Radke-Prausnitz, Temkin, linear equilibrium, and the Dubin-Radushkevich isotherms. The Freundlich and linear equilibrium isotherms best describe the adsorption of pyrethrin onto SDS micellar flocs, with the Freundlich adsorption constant, KF, and the mass distribution coefficient, KD, of 64.266 ((mg/g(L/mg1/n and 119.65 L/g, respectively. Applicability of the Freundlich adsorption model suggests that heterogeneous surface adsorption affects the adsorption. The mean free energy value estimated using the Dubinin-Radushkevich isotherm was 0.136 kJ/mol indicating that physisorption may be predominant in the adsorption process.

  7. Adsorption of thorium from aqueous solutions by perlite.

    Science.gov (United States)

    Talip, Z; Eral, M; Hiçsönmez, U

    2009-02-01

    The use of expanded perlite for the adsorption of thorium from aqueous solution by batch technique is presented. The effects of particle size, pH of the solution, initial thorium concentration, shaking time, V/m ratio and temperature were determined. It was found that the adsorption capacity increases by the increase in the pH of the suspensions. The rate of thorium adsorption on expanded perlite was observed to be fast in the first hour of the reaction time. Adsorption isotherms were expressed by Langmuir and Freundlich adsorption models and the adsorption experiments conducted at 30 +/- 1 degrees C showed that the adsorption isotherms correlated well with the Langmuir model. From the adsorption data, thermodynamic parameters such as DeltaG(o), DeltaH(o) and DeltaS(o) were calculated as a function of temperature.

  8. Unexpected coupling between flow and adsorption in porous media.

    Science.gov (United States)

    Vanson, Jean-Mathieu; Coudert, François-Xavier; Rotenberg, Benjamin; Levesque, Maximilien; Tardivat, Caroline; Klotz, Michaela; Boutin, Anne

    2015-08-14

    We study the interplay between transport and adsorption in porous systems under a fluid flow, based on a lattice Boltzmann scheme extended to account for adsorption. We performed simulations on well-controlled geometries with slit and grooved pores, investigating the influence of adsorption and flow on dispersion coefficient and adsorbed density. In particular, we present a counterintuitive effect where fluid flow induces heterogeneity in the adsorbate, displacing the adsorption equilibrium towards downstream adsorption sites in grooves. We also present an improvement of the adsorption-extended lattice Boltzmann scheme by introducing the possibility for saturating Langmuir-like adsorption, while earlier work focused on linear adsorption phenomena. We then highlight the impact of this change in situations of high concentration of adsorbate. PMID:26139013

  9. The Calculation of Adsorption Isotherms from Chromatographic Peak Shapes

    Science.gov (United States)

    Neumann, M. G.

    1976-01-01

    Discusses the relationship between adsorption isotherms and elution peak shapes in gas chromatography, and describes a laboratory experiment which involves the adsorption of hexane, cyclohexane, and benzene on alumina at different temperatures. (MLH)

  10. Research on the chemical adsorption precursor state of CaCl2-NH3 for adsorption refrigeration

    Institute of Scientific and Technical Information of China (English)

    WANG Liwei; WANG Ruzhu; WU Jingyi; WANG Kai

    2005-01-01

    As a type of chemical adsorption working pair, the physical adsorption occurs first for CaCl2-NH3 because the effective reaction distance for van der Waals force is longer than that for chemical reaction force, and this physical adsorption state is named the precursor state of chemical adsorption. In order to get the different precursor states of CaCl2-NH3, the different distances between NH3 gas and Ca2+ are realized by the control of different phenomena of swelling and agglomeration in the process of adsorption. When the serious swelling exists while the agglomeration does not exist in the process of adsorption, experimental results show that the activated energy consumed by adsorption reaction increases for the reason of longer distance between Ca2+ and NH3, and at the same time the performance attenuation occurs in the repeated adsorption cycles. When the agglomeration occurs in the process of adsorption, the activated energy for the transition from precursor state to chemical adsorption decreases because the distance between NH3 gas and Ca2+ is shortened by the limited expansion space of adsorbent, and at the same time the performance attenuation does not occur. The adsorption refrigeration isobars are researched by the precursor state of chemical adsorption; results also show that the precursor state is a key factor for isobaric adsorption performance while the distribution of Ca2+ does not influence the permeation of NH3 gas in adsorbent.

  11. Adsorption of hydrogen in titanium

    International Nuclear Information System (INIS)

    In this work the absorption of hydrogen in titanium plates using a constant volume system has been realized. The changes of temperature and pressure were used to monitor the progress of the absorption. A stainless steel vacuum chamber with volume of 4,333 cm3 was used. A titanium sample of 45 x 5.4 x 0.3 cm was located in the center of the chamber. The sample was heated by an electrical source connected to the system. The sample was preconditioned with a vacuum-thermal treatment at 10-6 mbar and 800 Centigrade degrees for several days. Absorption was observed at room temperature and also at higher temperatures. The room temperature absorption was in the pressure range of 1.0 x 103 to 2.5 x 103 mbar, and other absorptions were from 180 to 630 Centigrade degrees at 3.5 x 10-1 to 1.3 x 103 mbar. It was found that the gas absorbed was function of the vacuum-thermal pre-conditioned treatment, pressure and temperature. When the first absorption was developed, additional absorptions were realized in short time. We measured the electrical resistivity of the sample in the experiments but we could not see important changes due to the absorption. (Author)

  12. Adsorption of copper ions from aqueous solutions on natural zeolite

    OpenAIRE

    Zendelska, Afrodita; Golomeova, Mirjana; Blažev, Krsto; Krstev, Boris; Golomeov, Blagoj; Krstev, Aleksandar

    2015-01-01

    The adsorption of copper ions from synthetic aqueous solutions on natural zeolite (clinoptilolite) was examined. In order to determine the rate of adsorption and the copper uptake at equilibrium, a series of experiments were performed under batch conditions from single ion solutions. Equilibrium data were evaluated based on adsorption (Langmuir and Freundlich) isotherms. The adsorption kinetics is reasonably fast. In the first 20 min of the experiment, approximately 80% of Cu2+ io...

  13. Adsorption of D113 Resin for Dysprosium(Ⅲ)

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The adsorption behavior and mechanism of D113 resin for Dy(Ⅲ) was investigated by using the method of resin adsorption. Experimental results show that the optimum medium pH of adsorption of D113 resin for Dy3+ is pH=6.00 in the HAc-NaAc medium. The static adsorption capacity of D113 resin for Dy3+chemical analysis and IR spectra.

  14. ADSORPTION OF PHENOL AND NITROPHENOLS ON A HYPERCROSSLINKED POLYMERIC ADSORBENT

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The adsorption of phenol and nitrophenols on hypercrosslinked polymeric adsorbent wasstudied as a function of the solution concentration and temperature. Adsorption isotherms of phenoland nitrophenols on hypercrosslinked resin were determined. These isotherms were modeledaccording to the Freundlich adsorption isotherm. The isotherms for phenol and nitrophenols onhypercrosslinked resin were assigned as L curves. Thermodynamic parameters were calculated for allphenol and nitrophenols. The kinetics experiment results showed that the adsorption rates were of thefirst-order kinetics. The rate constants at 303K were calculated.

  15. Adsorption of microcystins and anatoxin-a on nanofiltration membranes

    OpenAIRE

    Ribau Teixeira, Margarida; Rosa, Maria João

    2011-01-01

    This work pretends to study the adsorption of microcystin-LR (MC-LR) and anatoxin-a (ATX-a) on nanofiltration membranes and to understand the adsorption behaviour with the solution chemistry (background natural organic matter (NOM) and in the presence of ATX-a). Results demonstrate that MC-LR adsorption increases with water recovery due to the increase in MC-LR feed concentration. MC-LR adsorption is governed by hydrophobic interactions established between the membrane surface and...

  16. Theoretical study of adsorption of lithium atom on carbon nanotube

    OpenAIRE

    Senami, Masato; Ikeda, Yuji; Fukushima, Akinori; Tachibana, Akitomo

    2011-01-01

    We investigate the adsorption of lithium atoms on the surface of the (12,0) single wall carbon nanotube (SWCNT) by using ab initio quantum chemical calculations. The adsorption of one lithium atom on the inside of this SWCNT is favored compared to the outside. We check this feature by charge transfer and regional chemical potential density. The adsorption of multiple lithium atoms on the interior of the SWCNT is studied in terms of adsorption energy and charge transfer. We show that repulsive...

  17. Adsorption of Crystal Violet Dye onto Tamarind Seed Powder

    OpenAIRE

    Himanshu Patel; R. T. Vashi

    2010-01-01

    The present investigation describes adsorption of crystal violet dye from its aqueous solution onto tamarind (Tamarindus indica) fruit shell powder. Initial concentration, agitation speed and pH with various temperature have been studied, in which pH was found to be most effective. The adsorption data were mathematically analyzed using adsorption isotherm like Freundlich and Langmuir isotherm to study adsorption mechanism of crystal violet onto this seed powder. Freundlich isotherm was found ...

  18. RADICAL FLOW IN POROUS MEDIA WITH DISPERSION AND ADSORPTION

    Institute of Scientific and Technical Information of China (English)

    LIU Ci-qun; GUO Bai-qi; SONG Fu-quan; WANG Jin-ying

    2004-01-01

    The radical transport of chemical concentration in porous media with dispersion and adsorption was studied in this paper. Using Langmuir's adsorption model, the numerical equation of concentration transport was derived. The flows with and without adsorption were simulated and analyzed.Comparison of the obtained solution with the known analytical solution for flow without adsorption shows the presented numerical method is correct and effective, which can be used in reservoir engineering.

  19. Water adsorption in hydrophilic zeolites: experiment and simulation

    OpenAIRE

    Castillo, Juan Manuel; Silvestre Albero, Joaquín; Rodríguez Reinoso, Francisco; Vlugt, Thijs. J. H.; Calero, Sofía

    2013-01-01

    We have measured experimental adsorption isotherms of water in zeolite LTA4A, and studied the regeneration process by performing subsequent adsorption cycles after degassing at different temperatures. We observed incomplete desorption at low temperatures, and cation rearrangement at successive adsorption cycles. We also developed a new molecular simulation force field able to reproduce experimental adsorption isotherms in the range of temperatures between 273 K and 374 K. Small deviations obs...

  20. Adsorption component of the disjoining pressure in thin liquid films

    OpenAIRE

    Tsekov, R.

    2011-01-01

    The disjoining pressure isotherm in foam films is theoretically studied and an important contribution of adsorption is discovered. On the basis of the interfacial thermodynamics an adsorption disjoining pressure component is derived, which is repulsive and exponentially decaying by the film thickness. Expressions for its magnitude and decay length are derived in terms of well-known thermodynamic characteristics such as the partial Gibbs elasticity and adsorption length. Several adsorption iso...

  1. Preparation and characterization of nanosized P(NIPAM-MBA) hydrogel particles and adsorption of bovine serum albumin on their surface

    Science.gov (United States)

    Zhu, Xiaoli; Gu, Xiangling; Zhang, Lina; Kong, Xiang-Zheng

    2012-09-01

    Thermosensitive polymer hydrogel particles with size varying from 480 to 620 nm were prepared through precipitation copolymerization of N-isopropylacrylamide with N,N'-methylenebisacrylamide (MBA) in water with ammonium persulfate as the initiator. Only polymer hydrogels without any coagula were obtained when MBA concentration in the monomer mixture was kept between 2.5 and 10.0 wt%; with increased MBA concentration, the monomer conversion was enhanced, the size of the hydrogels was increased, and their shrinking was lessened when heated from 25°C to 40°C. Bovine serum albumin adsorption on the surface of the hydrogels of different MBA content was measured at different pH levels and under different temperatures. The results demonstrated that the adsorption of the protein on the hydrogels could be controlled by adjusting the pH, the temperature of adsorption, and the crosslinking in the hydrogels. The results were interpreted, and the mechanisms of the polymerization were proposed.

  2. Regeneration and efficiency characterization of hybrid adsorbent for thermal energy storage of excess and solar heat

    Energy Technology Data Exchange (ETDEWEB)

    Dicaire, Daniel; Tezel, F. Handan [University of Ottawa, Department of Chemical and Biological Engineering, 161 Louis Pasteur, Colonel By Hall, A402, Ottawa, ON, K1N 6N5 (Canada)

    2011-03-15

    Adsorption Thermal Energy Storage (TES) is a promising technology for long term thermal energy storage of excess and solar heat. By using the exothermic reversible adsorption process, excess heat from an incinerator or solar heat from the summer can be stored and then released for heating during the winter. The usefulness of the storage system relies heavily on the temperature and quality of the heat available for regeneration of the adsorbent as it affects the storage efficiency, the amount of water released from the adsorbent and in turn the performance or energy density of the storage system. In this study, a lab scale high throughput open loop forced air adsorption TES has been built. A series of adsorption experiments were performed to determine the effect of adsorption flow rate and cycling on the chosen best performing adsorbent, AA13X from Rio Tinto Alcan. Regeneration characterization experiments were performed to determine the effect of flow rate, temperature and feed air relative humidity on the regeneration and performance of the system. The results were compared with another adsorbent to verify the observed trend. Finally, the efficiency of the thermal storage system was calculated. (author)

  3. Adsorption modeling for off-gas treatment

    Energy Technology Data Exchange (ETDEWEB)

    Ladshaw, A.; Sharma, K.; Yiacoumi, S.; Tsouris, C. [Georgia Institute of Technology, Atlanta, GA 30332-0459 (United States); De Paoli, D.W. [Oak Ridge National Laboratory: Oak Ridge, TN 37831-6181 (United States)

    2013-07-01

    Off-gas generated from the reprocessing of used nuclear fuel contains a mixture of several radioactive gases including {sup 129}I{sub 2}, {sup 85}Kr, HTO, and {sup 14}CO{sub 2}. Over the past few decades, various separation and recovery processes have been studied for capturing these gases. Adsorption data for gaseous mixtures of species can be difficult to determine experimentally. Therefore, procedures capable of predicting the adsorption behavior of mixtures need to be developed from the individual isotherms of each of the pure species. A particular isotherm model of interest for the pure species is the Generalized Statistical Thermodynamic Adsorption isotherm. This model contains an adjustable number of parameters and will therefore describe a wide range of adsorption isotherms for a variety of components. A code has been developed in C++ to perform the non-linear regression analysis necessary for the determination of the isotherm parameters, as well as the least number of parameters needed to describe an entire set of data. (authors)

  4. BSA adsorption on bimodal PEO brushes

    NARCIS (Netherlands)

    Bosker, WTE; Iakovlev, PA; Norde, W; Stuart, Martien A. Cohen

    2005-01-01

    BSA adsorption onto bimodal PEO brushes at a solid surface was measured using optical reflectometry. Bimodal brushes consist of long (N = 770) and short (N = 48) PEO chains and were prepared on PS surfaces, applying mixtures of PS29-PEO48 and PS37-PEO770 block copolymers and using the Langmuir-Blodg

  5. BSA adsorption on bimodal PEO brushes

    NARCIS (Netherlands)

    Bosker, W.T.E.; Iakovlev, P.A.; Norde, W.; Cohen Stuart, M.A.

    2005-01-01

    BSA adsorption onto bimodal PEO brushes at a solid surface was measured using optical reflectometry. Bimodal brushes consist of long (N=770) and short (N=48) PEO chains and were prepared on PS surfaces, applying mixtures of PS 29-PEO48 and PS37-PEO770 block copolymers and using the Langmuir-Blodgett

  6. Optimization of Adsorptive Immobilization of Alcohol Dehydrogenases

    NARCIS (Netherlands)

    Trivedi, Archana; Heinemann, Matthias; Spiess, Antje C.; Daussmann, Thomas; Büchs, Jochen

    2005-01-01

    In this work, a systematic examination of various parameters of adsorptive immobilization of alcohol dehydrogenases (ADHs) on solid support is performed and the impact of these parameters on immobilization efficiency is studied. Depending on the source of the enzymes, these parameters differently in

  7. Adsorption Kinetics in Nanoscale Porous Coordination Polymers

    Energy Technology Data Exchange (ETDEWEB)

    Nune, Satish K.; Thallapally, Praveen K.; McGrail, Benard Peter; Annapureddy, Harsha V. R.; Dang, Liem X.; Mei, Donghai; Karri, Naveen; Alvine, Kyle J.; Olszta, Matthew J.; Arey, Bruce W.; Dohnalkova, Alice

    2015-10-07

    Nanoscale porous coordination polymers were synthesized using simple wet chemical method. The effect of various polymer surfactants on colloidal stability and shape selectivity was investigated. Our results suggest that the nanoparticles exhibited significantly improved adsorption kinetics compared to bulk crystals due to decreased diffusion path lengths and preferred crystal plane interaction.

  8. Theoretical study of cisplatin adsorption on silica

    Energy Technology Data Exchange (ETDEWEB)

    Simonetti, S., E-mail: ssimonet@uns.edu.ar [Departamento de Fisica and IFISUR, Universidad Nacional del Sur-CONICET, Av. Alem 1253, 8000 Bahia Blanca (Argentina); Departamentos de Ciencias Basicas e Ingenieria Mecanica, Universidad Tecnologica Nacional, 11 de Abril 461, 8000 Bahia Blanca (Argentina); Company, A. Diaz; Brizuela, G.; Juan, A. [Departamento de Fisica and IFISUR, Universidad Nacional del Sur-CONICET, Av. Alem 1253, 8000 Bahia Blanca (Argentina)

    2011-11-15

    The adsorption of cisplatin and its complexes, cis-[PtCl(NH{sub 3}){sub 2}]{sup +} and cis-[Pt(NH{sub 3}){sub 2}]{sup 2+}, on a SiO{sub 2}(1 1 1) hydrated surface has been studied by the Atom Superposition and Electron Delocalization method. The adiabatic energy curves for the adsorption of the drug and its products on the delivery system were considered. The electronic structure and bonding analysis were also performed. The molecule-surface interactions are formed at expenses of the OH surface bonds. The more important interactions are the Cl-H bond for cis-[PtCl{sub 2}(NH{sub 3}){sub 2}] and cis-[PtCl(NH{sub 3}){sub 2}]{sup +} adsorptions, and the Pt-O interaction for cis-[Pt(NH{sub 3}){sub 2}]{sup 2+} adsorption. The Cl p orbitals and Pt s, p y d orbitals of the molecule and its complexes, and the s H orbital and, the s and p orbitals of the O atoms of the hydrated surface are the main contribution to the surface bonds.

  9. Adsorption Properties of Chalk Reservoir Materials

    DEFF Research Database (Denmark)

    Okhrimenko, Denis

    Understanding adsorption energetics and wetting properties of calcium carbonate surfaces is essential for developing remediation strategies for aquifers, improving oil recovery, minimising risk in CO2 storage and optimising industrial processes. This PhD was focussed on comparing the vapour...

  10. Adsorption Phenomena at Organic-Inorganic Interfaces

    OpenAIRE

    Bachmann, M.; Janke, W.

    2007-01-01

    The qualitative solvent- and temperature-dependent conformational behavior of a peptide in the proximity of solid substrates with different adsorption properties is investigated by means of a simple lattice model. The resulting pseudophase diagrams exhibit a complex structure, which can be understood by analysing the minima of the free-energy landscape in dependence of appropriate system parameters.

  11. Adsorption of penicillin by decaffeinated tea waste

    Directory of Open Access Journals (Sweden)

    Gharbani Parvin

    2015-09-01

    Full Text Available Removal of penicillin has been investigated using decaffeinated tea waste (DCTW. Decaffeination of tea waste was investigated using different methods. Results indicate that ozonation was the most effective process for removal of penicillin. Batch adsorption experiments were completed at various temperatures (20, 30, and 40°C, DCTW dosages (2, 4, 6, 8, and 10 g per 250 mL, penicillin concentrations (4, 10, and 14 mg/L, and pH (3, 7, and 10 conditions. Studies showed that adsorption reaches equilibrium within 40 min. The main factor affecting adsorption of penicillin was the solution pH, with maximum adsorption occurring at pH 3. Higher adsorbent dosages and lower penicillin concentrations also resulted in higher percentages of penicillin removal. Results show that data obeyed the pseudo-first-order kinetic and Freundlich isotherm models. This process proves that low-cost DCTW could be used as a high performance adsorbent for removing penicillin from aqueous solutions.

  12. Modeling the Adsorption of Oxalate onto Montmorillonite.

    Science.gov (United States)

    Ramos, M Elena; Emiroglu, Caglayan; García, David; Sainz-Díaz, C Ignacio; Huertas, F Javier

    2015-11-01

    In this work, a multiscale modeling of the interaction of oxalate with clay mineral surfaces from macroscale thermodynamic equilibria simulations to atomistic calculations is presented. Previous results from macroscopic adsorption data of oxalate on montmorillonite in 0.01 M KNO3 media at 25 °C within the pH range from 2.5 to 9 have been used to develop a surface complexation model. The experimental adsorption edge data were fitted using the triple-layer model (TLM) with the aid of the FITEQL 4.0 computer program. Surface complexation of oxalate is described by two reactions: >AlOH + Ox(2-) + 2H(+) = >AlOxH + H2O (log K = 14.39) and >AlOH + Ox(2-) + H(+) = >AlOx(-) + H2O (log K = 10.39). The monodentate complex >AlOxH dominated adsorption below pH 4, and the bidentate complex >AlOx(-) was predominant at higher pH values. Both of the proposed inner-sphere oxalate species are qualitatively consistent with previously published diffuse reflectance FTIR spectroscopic results for oxalate on montmorillonite edge surface (Chem. Geol. 2014, 363, 283-292). Atomistic computational studies have been performed to understand the interactions at the molecular level between adsorbates and mineral surface, showing the atomic structures and IR frequency shifts of the adsorption complexes of oxalate with the edge surface of a periodic montmorillonite model. PMID:26444928

  13. Modeling adsorption with lattice Boltzmann equation.

    Science.gov (United States)

    Guo, Long; Xiao, Lizhi; Shan, Xiaowen; Zhang, Xiaoling

    2016-01-01

    The research of adsorption theory has recently gained renewed attention due to its critical relevance to a number of trending industrial applications, hydrogen storage and shale gas exploration for instance. The existing theoretical foundation, laid mostly in the early twentieth century, was largely based on simple heuristic molecular interaction models and static interaction potential which, although being insightful in illuminating the fundamental mechanisms, are insufficient for computations with realistic adsorbent structure and adsorbate hydrodynamics, both critical for real-life applications. Here we present and validate a novel lattice Boltzmann model incorporating both adsorbate-adsorbate and adsorbate-adsorbent interactions with hydrodynamics which, for the first time, allows adsorption to be computed with real-life details. Connection with the classic Ono-Kondo lattice theory is established and various adsorption isotherms, both within and beyond the IUPAC classification are observed as a pseudo-potential is varied. This new approach not only enables an important physical to be simulated for real-life applications, but also provides an enabling theoretical framework within which the fundamentals of adsorption can be studied. PMID:27256325

  14. Modeling adsorption with lattice Boltzmann equation

    Science.gov (United States)

    Guo, Long; Xiao, Lizhi; Shan, Xiaowen; Zhang, Xiaoling

    2016-01-01

    The research of adsorption theory has recently gained renewed attention due to its critical relevance to a number of trending industrial applications, hydrogen storage and shale gas exploration for instance. The existing theoretical foundation, laid mostly in the early twentieth century, was largely based on simple heuristic molecular interaction models and static interaction potential which, although being insightful in illuminating the fundamental mechanisms, are insufficient for computations with realistic adsorbent structure and adsorbate hydrodynamics, both critical for real-life applications. Here we present and validate a novel lattice Boltzmann model incorporating both adsorbate-adsorbate and adsorbate-adsorbent interactions with hydrodynamics which, for the first time, allows adsorption to be computed with real-life details. Connection with the classic Ono-Kondo lattice theory is established and various adsorption isotherms, both within and beyond the IUPAC classification are observed as a pseudo-potential is varied. This new approach not only enables an important physical to be simulated for real-life applications, but also provides an enabling theoretical framework within which the fundamentals of adsorption can be studied. PMID:27256325

  15. Adsorption and desorption of cellulose derivatives.

    NARCIS (Netherlands)

    Hoogendam, C.W.

    1998-01-01

    Cellulose derivatives, in particular carboxymethyl cellulose (CMC) are used in many (industrial) applications. The aim of this work is to obtain insight into the adsorption mechanism of cellulose derivatives on solid-liquid interfaces.In chapter 1 of this thesis we discuss some appl

  16. Adsorption of Ions at Uncharged Insoluble Monolayers

    Science.gov (United States)

    Peshkova, T. V.; Minkov, I. L.; Tsekov, R.; Slavchov, R. I.

    2016-08-01

    A method is proposed for the experimental determination of the adsorption of inorganic electrolytes at a surface covered with insoluble surfactant monolayer. This task is complicated by the fact that the change of the salt concentration alters both chemical potentials of the electrolyte and the surfactant. Our method resolves the question by combining data for the surface pressure versus area of the monolayer at several salt concentrations with data for the equilibrium spreading pressure of crystals of the surfactant (used to fix a standard state). We applied the method to alcohols spread at the surface of concentrated halide solutions. The measured salt adsorption is positive and has nonmonotonic dependence on the area per surfactant molecule. For the liquid expanded film, depending on the concentration, there is one couple of ions adsorbed per each 3–30 surfactant molecules. We analyzed which ion, the positive or the negative, stands closer to the surface, by measuring the effect of NaCl on the Volta potential of the monolayer. The potentiometric data suggest that Na+ is specifically adsorbed, while Cl– remains in the diffuse layer, i.e., the surface is positively charged. The observed reverse Hofmeister series of the adsorptions of NaF, NaCl, and NaBr suggests the same conclusion holds for all these salts. The force that causes the adsorption of Na+ seems to be the interaction of the ion with the dipole moment of the monolayer.

  17. Exhaustively sampling peptide adsorption with metadynamics.

    Science.gov (United States)

    Deighan, Michael; Pfaendtner, Jim

    2013-06-25

    Simulating the adsorption of a peptide or protein and obtaining quantitative estimates of thermodynamic observables remains challenging for many reasons. One reason is the dearth of molecular scale experimental data available for validating such computational models. We also lack simulation methodologies that effectively address the dual challenges of simulating protein adsorption: overcoming strong surface binding and sampling conformational changes. Unbiased classical simulations do not address either of these challenges. Previous attempts that apply enhanced sampling generally focus on only one of the two issues, leaving the other to chance or brute force computing. To improve our ability to accurately resolve adsorbed protein orientation and conformational states, we have applied the Parallel Tempering Metadynamics in the Well-Tempered Ensemble (PTMetaD-WTE) method to several explicitly solvated protein/surface systems. We simulated the adsorption behavior of two peptides, LKα14 and LKβ15, onto two self-assembled monolayer (SAM) surfaces with carboxyl and methyl terminal functionalities. PTMetaD-WTE proved effective at achieving rapid convergence of the simulations, whose results elucidated different aspects of peptide adsorption including: binding free energies, side chain orientations, and preferred conformations. We investigated how specific molecular features of the surface/protein interface change the shape of the multidimensional peptide binding free energy landscape. Additionally, we compared our enhanced sampling technique with umbrella sampling and also evaluated three commonly used molecular dynamics force fields. PMID:23706011

  18. Water adsorption on the Be(0001) surface:from monomer to trimer adsorption

    Institute of Scientific and Technical Information of China (English)

    Ning Hua; Tao Xiang-Ming; Tan Ming-Qiu

    2012-01-01

    In this paper,the density functional theory has been used to perform a comparative theoretical study of water monomer,dimer,trimer,and bilayer adsorptions on the Be(0001) surface. In our calculations,the adsorbed water molecules are energetically favoured adsorbed on the atop sites,and the dimer adsorption is found to be the most stable with a peak adsorption energy of ~ 437 meV.Further analyses have revealed that the essential bonding interaction between the water monomer and the metal substrate is the hybridization of the water 3a1-like molecular orbital with the (s,pz) orbitals of the surface beryllium atoms.While in the case of the water dimer adsorption,the lb1-like orbital of the H2O molecule plays a dominant role.

  19. Adsorption materials for the recovery and separation of biobased molecules

    NARCIS (Netherlands)

    IJzer, Anne Corine

    2016-01-01

    In this thesis we studied several strategies to improve adsorption technology for the adsorption of biobased molecules. These strategies are based on the adsorbent as well as the adsorption process. A systematic investigation of the chemical and physical structure of resin materials and their relati

  20. ADSORPTION OF GOLD ON TBP EXTRACTING RESIN FROM HCl SOLUTION

    Institute of Scientific and Technical Information of China (English)

    GaoHaoqi; CaoZhikai; 等

    1998-01-01

    Adsorption of gold on TBP extracting resin from HCl solution was researched.All the effects of factors,such as solution acidity,TBP content,temperature,etc.,on adsorption equilibrium were discussed and the equilibrium equation was formulated.The breakthough time of adsorption process with fixed bed was studied through experiment.