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Sample records for adiabatic reformer processes

  1. Semi adiabatic theory of seasonal Markov processes

    Talkner, P. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    The dynamics of many natural and technical systems are essentially influenced by a periodic forcing. Analytic solutions of the equations of motion for periodically driven systems are generally not known. Simulations, numerical solutions or in some limiting cases approximate analytic solutions represent the known approaches to study the dynamics of such systems. Besides the regime of weak periodic forces where linear response theory works, the limit of a slow driving force can often be treated analytically using an adiabatic approximation. For this approximation to hold all intrinsic processes must be fast on the time-scale of a period of the external driving force. We developed a perturbation theory for periodically driven Markovian systems that covers the adiabatic regime but also works if the system has a single slow mode that may even be slower than the driving force. We call it the semi adiabatic approximation. Some results of this approximation for a system exhibiting stochastic resonance which usually takes place within the semi adiabatic regime are indicated. (author) 1 fig., 8 refs.

  2. LETTERS AND COMMENTS: Adiabatic process reversibility: microscopic and macroscopic views

    Anacleto, Joaquim; Pereira, Mário G.

    2009-05-01

    The reversibility of adiabatic processes was recently addressed by two publications. In the first (Miranda 2008 Eur. J. Phys. 29 937-43), an equation was derived relating the initial and final volumes and temperatures for adiabatic expansions of an ideal gas, using a microscopic approach. In that relation the parameter r accounts for the process reversibility, ranging between 0 and 1, which corresponds to the free and reversible expansion, respectively. In the second (Anacleto and Pereira 2009 Eur. J. Phys. 30 177-83), the authors have shown that thermodynamics can effectively and efficiently be used to obtain the general law for adiabatic processes carried out by an ideal gas, including compressions, for which r \\ge 1. The present work integrates and extends the aforementioned studies, providing thus further insights into the analysis of the adiabatic process. It is shown that Miranda's work is wholly valid for compressions. In addition, it is demonstrated that the adiabatic reversibility coefficient given in terms of the piston velocity and the root mean square velocity of the gas particles is equivalent to the macroscopic description, given just by the quotient between surroundings and system pressure values.

  3. Adiabatic Shear Mechanisms for the Hard Cutting Process

    YUE Caixu; WANG Bo; LIU Xianli; FENG Huize; CAI Chunbin

    2015-01-01

    The most important consequence of adiabatic shear phenomenon is formation of sawtooth chip. Lots of scholars focused on the formation mechanism of sawtooth, and the research often depended on experimental approach. For the present, the mechanism of sawtooth chip formation still remalns some ambiguous aspects. This study develops a combined numerical and experimental approach to get deeper understanding of sawtooth chip formation mechanism for Polycrystalline Cubic Boron Nitride (PCBN) tools orthogonal cutting hard steel GCr15. By adopting the Johnson-Cook material constitutive equations, the FEM simulation model established in this research effectively overcomes serious element distortions and cell singularity in high straln domaln caused by large material deformation, and the adiabatic shear phenomenon is simulated successfully. Both the formation mechanism and process of sawtooth are simulated. Also, the change features regarding the cutting force as well as its effects on temperature are studied. More specifically, the contact of sawtooth formation frequency with cutting force fluctuation frequency is established. The cutting force and effect of cutting temperature on mechanism of adiabatic shear are investigated. Furthermore, the effects of the cutting condition on sawtooth chip formation are researched. The researching results show that cutting feed has the most important effect on sawtooth chip formation compared with cutting depth and speed. This research contributes a better understanding of mechanism, feature of chip formation in hard turning process, and supplies theoretical basis for the optimization of hard cutting process parameters.

  4. Some characteristics of the atmosphere during an adiabatic process

    GAO Li; LI Jianping; REN Hongli

    2006-01-01

    Some important characteristics of the atmosphere during an adiabatic process are investigated, which include the invariability of atmospheric entropy range and local surface potential temperature, the conservation of the atmospheric mass intervened between any isentropic surface and the ground, and the isentropic surface intersecting with the ground. The analysis shows that the atmospheric reference state (ARS) for investigation on available potential energy (APE) should be defined objectively as the state which could be approached from the existing atmosphere by adiabatic adjustment, and be related to initial atmospheric state before adjustment. For the initial atmosphere state at any time, its corresponding ARS is different from the one at another time. Based on the above-mentioned conclusions,the reference state proposed by Lorenz cannot be obtained physically, so a new conception, the conditional minimum total potential energy, is put forward in order to objectively investigate atmospheric APE.

  5. Classical molecular dynamics simulation of electronically non-adiabatic processes.

    Miller, William H; Cotton, Stephen J

    2016-12-22

    Both classical and quantum mechanics (as well as hybrids thereof, i.e., semiclassical approaches) find widespread use in simulating dynamical processes in molecular systems. For large chemical systems, however, which involve potential energy surfaces (PES) of general/arbitrary form, it is usually the case that only classical molecular dynamics (MD) approaches are feasible, and their use is thus ubiquitous nowadays, at least for chemical processes involving dynamics on a single PES (i.e., within a single Born-Oppenheimer electronic state). This paper reviews recent developments in an approach which extends standard classical MD methods to the treatment of electronically non-adiabatic processes, i.e., those that involve transitions between different electronic states. The approach treats nuclear and electronic degrees of freedom (DOF) equivalently (i.e., by classical mechanics, thereby retaining the simplicity of standard MD), and provides "quantization" of the electronic states through a symmetrical quasi-classical (SQC) windowing model. The approach is seen to be capable of treating extreme regimes of strong and weak coupling between the electronic states, as well as accurately describing coherence effects in the electronic DOF (including the de-coherence of such effects caused by coupling to the nuclear DOF). A survey of recent applications is presented to illustrate the performance of the approach. Also described is a newly developed variation on the original SQC model (found universally superior to the original) and a general extension of the SQC model to obtain the full electronic density matrix (at no additional cost/complexity).

  6. Hypercomputability of quantum adiabatic processes: Fact versus Prejudices

    Kieu, T D

    2005-01-01

    We give an overview of a quantum adiabatic algorithm for Hilbert's tenth problem, including some discussions on its fundamental aspects and the emphasis on the probabilistic correctness of its findings. For the purpose of illustration, the numerical simulation results of some simple Diophantine equations are presented. We also discuss some prejudicial misunderstandings as well as some plausible difficulties faced by the algorithm in its physical implementation.

  7. Cosmological consequences of an adiabatic matter creation process

    Nunes, Rafael C

    2016-01-01

    In this paper we investigate the cosmological consequences of a continuous matter creation associated with the production of particles by the gravitational field acting on the quantum vacuum. To illustrate this, three phenomenological models are considered. An equivalent scalar field description is presented for each models. The effects on the cosmic microwave background power spectrum are analyzed for the first time in the context of adiabatic matter creation cosmology. Further, we introduce a model independent treatment, $Om$, which depends only on the Hubble expansion rate and the cosmological redshift to distinguish any cosmological model from $\\Lambda$CDM by providing a null test for the cosmological constant, meaning that, for any two redshifts $z_1$, $z_2$, $Om (z)$ is same, i.e. $Om (z_1)- Om (z_2)= 0$. Also, this diagnostic can differentiate between several cosmological models by indicating their quintessential/ phantom behavior without knowing the accurate value of the matter density, and the presen...

  8. Analytical calculation of adiabatic processes in real gases

    Amarskaja, I. B.; Belousov, V. S.; Filippov, P. S.

    2016-10-01

    The impact of gases nonideality in the compression and expansion processes on the specific heat ratio and the heat capacity is analyzed. The specific heat ratio variation leads to temperature variation during compression in the compressor and expansion in the turbine and, consequently, the gas turbine cycle efficiency factor variation. It is also essential to consider the gases nonideality in the compression and expansion processes in the compression processes in compressor. Generally it is assumed during calculations that the heat capacities depend only on temperature, in this case the reference data presented by various authors differs markedly. In the real processes the heat capacity and the specific heat ratio depend on temperature and within the particular temperatures and pressures range depend on pressure. Consequently, the operating fluid nonideality in the gas turbine cycle should be considered.

  9. Adiabatic reduction of a model of stochastic gene expression with jump Markov process.

    Yvinec, Romain; Zhuge, Changjing; Lei, Jinzhi; Mackey, Michael C

    2014-04-01

    This paper considers adiabatic reduction in a model of stochastic gene expression with bursting transcription considered as a jump Markov process. In this model, the process of gene expression with auto-regulation is described by fast/slow dynamics. The production of mRNA is assumed to follow a compound Poisson process occurring at a rate depending on protein levels (the phenomena called bursting in molecular biology) and the production of protein is a linear function of mRNA numbers. When the dynamics of mRNA is assumed to be a fast process (due to faster mRNA degradation than that of protein) we prove that, with appropriate scalings in the burst rate, jump size or translational rate, the bursting phenomena can be transmitted to the slow variable. We show that, depending on the scaling, the reduced equation is either a stochastic differential equation with a jump Poisson process or a deterministic ordinary differential equation. These results are significant because adiabatic reduction techniques seem to have not been rigorously justified for a stochastic differential system containing a jump Markov process. We expect that the results can be generalized to adiabatic methods in more general stochastic hybrid systems.

  10. Quasi-classical theory of electronic flux density in electronically adiabatic molecular processes.

    Diestler, D J

    2012-11-26

    The standard Born-Oppenheimer (BO) description of electronically adiabatic molecular processes predicts a vanishing electronic flux density (EFD). A previously proposed "coupled-channels" theory permits the extraction of the EFD from the BO wave function for one-electron diatomic systems, but attempts at generalization to many-electron polyatomic systems are frustrated by technical barriers. An alternative "quasi-classical" approach, which eliminates the explicit quantum dynamics of the electrons within a classical framework, yet retains the quantum character of the nuclear motion, appears capable of yielding EFDs for arbitrarily complex systems. Quasi-classical formulas for the EFD in simple systems agree with corresponding coupled-channels formulas. Results of the application of the new quasi-classical formula for the EFD to a model triatomic system indicate the potential of the quasi-classical scheme to elucidate the dynamical role of electrons in electronically adiabatic processes in more complex multiparticle systems.

  11. Coupled-channels quantum theory of electronic flux density in electronically adiabatic processes: fundamentals.

    Diestler, D J

    2012-03-22

    The Born-Oppenheimer (BO) description of electronically adiabatic molecular processes predicts a vanishing electronic flux density (j(e)), =1/2∫dR[Δ(b) (x;R) - Δ(a) (x;R)] even though the electrons certainly move in response to the movement of the nuclei. This article, the first of a pair, proposes a quantum-mechanical "coupled-channels" (CC) theory that allows the approximate extraction of j(e) from the electronically adiabatic BO wave function . The CC theory is detailed for H(2)(+), in which case j(e) can be resolved into components associated with two channels α (=a,b), each of which corresponds to the "collision" of an "internal" atom α (proton a or b plus electron) with the other nucleus β (proton b or a). The dynamical role of the electron, which accommodates itself instantaneously to the motion of the nuclei, is submerged in effective electronic probability (population) densities, Δ(α), associated with each channel (α). The Δ(α) densities are determined by the (time-independent) BO electronic energy eigenfunction, which depends parametrically on the configuration of the nuclei, the motion of which is governed by the usual BO nuclear Schrödinger equation. Intuitively appealing formal expressions for the electronic flux density are derived for H(2)(+).

  12. Non-Hermitian heat engine with all-quantum-adiabatic-process cycle

    Lin, S.; Song, Z.

    2016-11-01

    As a quantum device, a quantum heat engine (QHE) is described by a Hermitian Hamiltonian. However, since it is an open system, reservoirs must be imposed phenomenologically without any description in the context of quantum mechanics. A non-Hermitian system is expected to describe an open system that exchanges energy and particles with external reservoirs. Correspondingly, such an exchange can be adiabatic in the context of quantum mechanics. We first propose a non-Hermitian QHE by a concrete simple two-level system, which is an S=1/2 spin in a complex external magnetic field. The non-Hermitian { P }{ T }-symmetric Hamiltonian, as a self-contained one, describes both the working medium and reservoirs. A heat engine cycle is composed of completely quantum adiabatic processes. Surprisingly, the heat efficiency is obtained to be the same as that of the Hermitian quantum Otto cycle. A classical analog of this scheme is also presented. Our finding paves the way for revealing the role of a non-Hermitian Hamiltonian in physics.

  13. On Deepening Reform of Processing Trade Regulations

    2003-01-01

    The Processing trade has,since 1996,Taken half of the total import and export trade value for a consecutive six years.Despite the impact and influence of the Asian financial crisis,it has maintained a momentum of steady growth.In the five years from 1997 to 2001.import and export value through the processing trade grew at an annual average rate of 10.5 percent,with exports growing at an annual average rate of 11.8 percent.This good growth momentum continued into the first ten months of 2002,when the value of imports and exports grew 24.1 percent,with exports growing 20.6 percent and imports,29.7 percent.1 Rapid growth is expected for 2002 and in the first half of 2003,thanks to a rise in imports through the processing trade and the impact of the processing cycle.It has ,therefore,become an important subject of study in the further opeing up and accelerating of China's economic development to deepen reform of processing trade regulations to keep up with the new situation.

  14. A new symmetrical quasi-classical model for electronically non-adiabatic processes: Application to the case of weak non-adiabatic coupling

    Cotton, Stephen J.; Miller, William H.

    2016-10-01

    Previous work has shown how a symmetrical quasi-classical (SQC) windowing procedure can be used to quantize the initial and final electronic degrees of freedom in the Meyer-Miller (MM) classical vibronic (i.e, nuclear + electronic) Hamiltonian, and that the approach provides a very good description of electronically non-adiabatic processes within a standard classical molecular dynamics framework for a number of benchmark problems. This paper explores application of the SQC/MM approach to the case of very weak non-adiabatic coupling between the electronic states, showing (as anticipated) how the standard SQC/MM approach used to date fails in this limit, and then devises a new SQC windowing scheme to deal with it. Application of this new SQC model to a variety of realistic benchmark systems shows that the new model not only treats the weak coupling case extremely well, but it is also seen to describe the "normal" regime (of electronic transition probabilities ≳ 0.1) even more accurately than the previous "standard" model.

  15. Isothermal and Adiabatic Measurements.

    McNairy, William W.

    1996-01-01

    Describes the working of the Adiabatic Gas Law Apparatus, a useful tool for measuring the pressure, temperature, and volume of a variety of gases undergoing compressions and expansions. Describes the adaptation of this apparatus to perform isothermal measurements and discusses the theory behind the adiabatic and isothermal processes. (JRH)

  16. Application of the First Law of Thermodynamics to the Adiabatic Processes of an Ideal Gas: Physics Teacher Candidates' Opinions

    Gonen, S.

    2014-01-01

    The present study was carried out with 46 teacher candidates taking the course of "Thermodynamics" in the Department of Physics Teaching. The purpose of the study was to determine the difficulties that teacher candidates experienced in explaining the heat, work and internal energy relationships in the processes of adiabatic compression…

  17. Mechanisms controlling warm water volume interannual variations in the equatorial Pacific: diabatic versus adiabatic processes

    Lengaigne, M. [CNRS, UPMC, IRD, Laboratoire d' Oceanographie Experimentation et Approches Numeriques, Paris (France); Paris Cedex 05 (France); Hausmann, U. [Imperial College, Department of Physics, London (United Kingdom); Madec, G. [CNRS, UPMC, IRD, Laboratoire d' Oceanographie Experimentation et Approches Numeriques, Paris (France); National Oceanographic Centre, Southampton (United Kingdom); Menkes, C.; Vialard, J. [CNRS, UPMC, IRD, Laboratoire d' Oceanographie Experimentation et Approches Numeriques, Paris (France); Molines, J.M. [CNRS, UJF, INP, Laboratoire Ecoulements Geophysiques et Industriels, Grenoble (France)

    2012-03-15

    Variations of the volume of warm water above the thermocline in the equatorial Pacific are a good predictor of ENSO (El Nino/Southern Oscillation) and are thought to be critical for its preconditioning and development. In this study, the Warm Water Volume (WWV) interannual variability is analysed using forced general circulation model experiments and an original method for diagnosing processes responsible for WWV variations. The meridional recharge/discharge to higher latitudes drives 60% of the ENSO-related equatorial WWV variations, while diabatic processes in the eastern equatorial Pacific account for the remaining 40%. Interior meridional transport is partially compensated by western boundary transports, especially in the southern hemisphere. Diabatic equatorial WWV formation (depletions) during La Nina (El Nino) are explained by enhanced (reduced) diathermal transport through enhanced (reduced) vertical mixing and penetrating solar forcing at the 20 C isotherm depth. The respective contribution of diabatic and adiabatic processes during build-ups/depletions strongly varies from event-to-event. The WWV build-up during neutral ENSO phases (e.g. 1980-1982) is almost entirely controlled by meridional recharge, providing a text-book example for the recharge/discharge oscillator's theory. On the other hand, diabatic processes are particularly active during the strongest La Nina events (1984, 1988, 1999), contributing to more than 70% of the WWV build-up, with heating by penetrative solar fluxes explaining as much as 30% of the total build-up due to a very shallow thermocline in the eastern Pacific. This study does not invalidate the recharge/discharge oscillator theory but rather emphasizes the importance of equatorial diabatic processes and western boundary transports in controlling WWV changes. (orig.)

  18. Budgeting and Acquisition Business Process Reform

    2007-11-07

    Nichols Act reforms (1986) were intended to rectify this situation. Then, with the drawdown after the fall of the Soviet Union, budget offices were...significant constraint as a variable in analyses of the effectiveness and suitability of systems. CAIV is intended to reduce acquisition costs. After ...budget be separated from the overall defense budget. This separation would help prevent the kind of financial whiplash that causes cost overruns

  19. The European Union’s Reform Process: The Libson Treaty

    2010-02-22

    uncertainty that followed the rejection of the constitutional treaty. German Chancellor Angela Merkel made reviving the stalled reform process one of her...actor. The Convention began work in March 2002 under the leadership of former French President Valéry Giscard d’Estaing and finalized a 240-page...key priorities, seeking a new treaty deal that would institute crucial reforms. Analysts say that Merkel received a key assist with the May 2007

  20. The telecom reform process in Europe and the upcoming challenges

    Henten, Anders

    2013-01-01

    an introduction to the telecom reform process based on previous research and the papers in this issue of info. Findings – The introduction argues that the European telecommunication reform process with the telecommunications green paper of 1987 as an important point of departure has been a success in many ways......Purpose – The purpose of this paper is to provide a brief introduction to the telecommunication reform process in Europe, its status, and upcoming policy issues. Furthermore, it also aims to provide an overview of the papers in this special issue. Design/methodology/approach – The paper provides....... It has, for example, facilitated the development of mobile, of the internet and its many applications, and considerably lowered prices. However, there are important areas where a single European market has not developed. Moreover, new challenges are rising in terms of upcoming reconfigurations...

  1. Semiclassical analysis of the electron-nuclear coupling in electronic non-adiabatic processes

    Agostini, Federica; Gross, E K U

    2015-01-01

    In the context of the exact factorization of the electron-nuclear wave function, the coupling between electrons and nuclei beyond the adiabatic regime is encoded (i) in the time-dependent vector and scalar potentials and (ii) in the electron-nuclear coupling operator. The former appear in the Schroedinger-like equation that drives the evolution of the nuclear degrees of freedom, whereas the latter is responsible for inducing non-adiabatic effects in the electronic evolution equation. As we have devoted previous studies to the analysis of the vector and scalar potentials, in this paper we focus on the properties of the electron-nuclear coupling operator, with the aim of describing a numerical procedure to approximate it within a semiclassical treatment of the nuclear dynamics.

  2. Development and formative evaluation of an instructional simulation of adiabatic processes

    Hsu, Ying-Shao

    The purpose of this research was to develop a computer-based instructional simulation of adiabatic processes and to study the effects of selected characteristics of the simulation on students conceptual development, problem solving and transfer. To study these issues the related literature was reviewed, a simulation was developed and a two-pronged research study was employed. From the review of literature and constructivist theory, a simulation to facilitate active and situated learning was developed. It included the features of multiple representations, interaction, and authentic tasks. The subjects for the study were students enrolled in a beginning meteorology course at Iowa State University. An experimental study was conducted comparing achievement measures of two groups who used different versions of the simulation and a control group who did not use the simulation. In addition, selected students were interviewed to gain a deeper understanding of their use of the simulation. The performances of the groups were compared on scores from a posttest and weather forecasts. As expected, since the simulation was not integrated into classroom activities, there were no statistically significant differences between the groups. Interview data supported the design and future use of the simulation. Four of the five students saw the task as being authentic. The multiple representations were used by the students to construct knowledge across representations and to choose their own mode of representation for exploring the simulation. Of the five students interviewed, only one had used an effective problem solving strategy. This student also demonstrated a better understanding of how to transfer newly-gained knowledge to weather forecast exercises. Two other students were poised for improvement of their problem solving strategies, having the basic strategy but needing refinement, and the other two were in need of basic instruction and guidance. This study clearly revealed a

  3. Use of biofuels to produce hydrogen (reformation processes).

    Ramírez de la Piscina, Pilar; Homs, Narcís

    2008-11-01

    This tutorial review deals with the catalytic reformation of ethanol and glycerol to produce hydrogen that can be used as an energy carrier in a fuel cell. Both the worldwide production of ethanol in large amounts to be used as a biofuel and that of glycerol as a by-product in biodiesel manufacture are presented. The catalytic reformation processes of both ethanol and glycerol are contemplated, including thermodynamic and kinetic aspects. Catalysts are analyzed as a function of operation conditions, selectivity and stability.

  4. Reforming the Review Process: Right Problem, Wrong Solution.

    Meier, Kenneth J.

    1997-01-01

    Responds to recent scathing criticism of the peer review process of scholarly publishing. Identifies three main problems with reviewers and editors: unresponsiveness, inconsistency, and indecisiveness. Discusses the pros and cons of several proposed publishing reforms including multiple submissions, establishing clearer and more consistent…

  5. The Master Teacher: Role and Responsibilities in the Reform Process

    McClean, Wilma A.

    2009-01-01

    The primary purpose of the study is to determine the opinions of educators about the "master teacher" concept within the school system. The concept of the "master teacher" refers to the ideological approach used to implement a "master teacher" initiative or programme in the school reform process. The primary school…

  6. The public administration reform in post-war Bosnia and Herzegovina: a reform process embedded in a sovereignty paradox

    Milovich, L.; Ossewaarde, M.R.R.

    2013-01-01

    As the post-war Bosnia and Herzegovina has turned its interest towards a European Union membership, it has entered an accession process requiring it, among other things, to reform its public administration system. The European Union's involvement within the reform has been placed under critique, as

  7. Adiabatic quantum-flux-parametron cell library designed using a 10 kA cm-2 niobium fabrication process

    Takeuchi, Naoki; Nagasawa, Shuichi; China, Fumihiro; Ando, Takumi; Hidaka, Mutsuo; Yamanashi, Yuki; Yoshikawa, Nobuyuki

    2017-03-01

    Adiabatic quantum-flux-parametron (AQFP) logic is an energy-efficient superconductor logic with zero static power consumption and very small switching energy. In this paper, we report a new AQFP cell library designed using the AIST 10 kA cm-2 Nb high-speed standard process (HSTP), which is a high-critical-current-density version of the AIST 2.5 kA cm-2 Nb standard process (STP2). Since the intrinsic damping of the Josephson junction (JJ) of HSTP is relatively strong, shunt resistors for JJs were removed and the energy efficiency improved significantly. Also, excitation transformers in the new cells were redesigned so that the cells can operate in a four-phase excitation mode. We described the detail of HSTP and the AQFP cell library designed using HSTP, and showed experimental results of cell test circuits.

  8. Frequency Shift and Sub-band Effect in Pair-Production Process Under Adiabatic Closing the External Field

    Song, Xinfang; Wang, Wenyuan; Fu, Libin

    2016-09-01

    Oscillating electric field is chosen to investigate the electron-positron pair production process by using a quantum kinetic theory and the effective mass model [Phys. Rev. Lett. 112, 050402 (2014)]. The particle yield exhibits a characteristic oscillatory structure which is related to the multi-photon thresholds. The true peak positions are typically slightly above the naive threshold estimate, which is defined as frequency shift. During the numerical calculations, we find the frequency shift can be affected by the system parameters under adiabatic closing the external field, it is worthwhile to study in detail. In this paper, we investigate the frequency shift and the sub-band effect in electron-positron pair production with oscillating electric field. First, a quantum kinetic theory and the effective mass are presented to obtain the frequency shift, the results are fitted very well. And we find the frequency shift and the sub-band effect can be influenced by pulse duration, photon number, and strength of the external field. The frequency shift becomes evident as increases of photon number and the external field strength. The sub-band width is relatively lower at longer pulse duration, higher photon number region, and weaker external field. The results shown in the paper are helpful for understanding multi-photon pair production process in the strong field.

  9. The Amsterdam Process: A Structurationist Perspective on EU Treaty Reform

    Thomas Christiansen

    1999-01-01

    Full Text Available Intergovernmental Conferences are generally seen as key events in the design of the European Union. This paper challenges this traditional view. Arguing that treaty reform should be regarded as a continuous process rather than a series of events, the paper develops a procedural understanding of constitutional change based on structuration theory. In such a perspective, analytical attention is re-directed from the political limelight of largely ceremonial events to the more obscure 'valleys' the periods between the IGC summits in which the more momentous developments of European integration occur. The study of past instances of constitutional change as well as an analysis of the IGC leading to the Amsterdam Treaty demonstrate the significance of a wider set of actors and of the structural environment: the trajectory of past decisions, the multilateral generation of reform agendas, the institutionalised patterns of negotiation and decision-making and the constitutionalisation of the EU order. This severely limits the ability of national governments to negotiate on the basis of 'national interests' and thus dissolves one of the cornerstones of intergovernmentalism the over-arching significance of IGCs.

  10. Coupled-channels quantum theory of electronic flux density in electronically adiabatic processes: application to the hydrogen molecule ion.

    Diestler, D J; Kenfack, A; Manz, J; Paulus, B

    2012-03-22

    This article presents the results of the first quantum simulations of the electronic flux density (j(e)) by the "coupled-channels" (CC) theory, the fundamentals of which are presented in the previous article [Diestler, D. J. J. Phys. Chem. A 2012, DOI: 10.1021/jp207843z]. The principal advantage of the CC scheme is that it employs exclusively standard methods of quantum chemistry and quantum dynamics within the framework of the Born-Oppenheimer approximation (BOA). The CC theory goes beyond the BOA in that it yields a nonzero j(e) for electronically adiabatic processes, in contradistinction to the BOA itself, which always gives j(e) = 0. The CC is applied to oriented H(2)(+) vibrating in the electronic ground state ((2)Σ(g)(+)), for which the nuclear and electronic flux densities evolve on a common time scale of about 22 fs per vibrational period. The system is chosen as a touchstone for the CC theory, because it is the only one for which highly accurate flux densities have been calculated numerically without invoking the BOA [Barth et al, Chem. Phys. Lett. 2009, 481, 118]. Good agreement between CC and accurate results supports the CC approach, another advantage of which is that it allows a transparent interpretation of the temporal and spatial properties of j(e).

  11. THE MATHEMATICAL MODEL DEVELOPMENT OF THE ETHYLBENZENE DEHYDROGENATION PROCESS KINETICS IN A TWO-STAGE ADIABATIC CONTINUOUS REACTOR

    V. K. Bityukov

    2015-01-01

    Full Text Available The article is devoted to the mathematical modeling of the kinetics of ethyl benzene dehydrogenation in a two-stage adiabatic reactor with a catalytic bed functioning on continuous technology. The analysis of chemical reactions taking place parallel to the main reaction of styrene formation has been carried out on the basis of which a number of assumptions were made proceeding from which a kinetic scheme describing the mechanism of the chemical reactions during the dehydrogenation process was developed. A mathematical model of the dehydrogenation process, describing the dynamics of chemical reactions taking place in each of the two stages of the reactor block at a constant temperature is developed. The estimation of the rate constants of direct and reverse reactions of each component, formation and exhaustion of the reacted mixture was made. The dynamics of the starting material concentration variations (ethyl benzene batch was obtained as well as styrene formation dynamics and all byproducts of dehydrogenation (benzene, toluene, ethylene, carbon, hydrogen, ect.. The calculated the variations of the component composition of the reaction mixture during its passage through the first and second stages of the reactor showed that the proposed mathematical description adequately reproduces the kinetics of the process under investigation. This demonstrates the advantage of the developed model, as well as loyalty to the values found for the rate constants of reactions, which enable the use of models for calculating the kinetics of ethyl benzene dehydrogenation under nonisothermal mode in order to determine the optimal temperature trajectory of the reactor operation. In the future, it will reduce energy and resource consumption, increase the volume of produced styrene and improve the economic indexes of the process.

  12. On the topology of adiabatic passage

    Yatsenko, L P; Jauslin, H R

    2002-01-01

    We examine the topology of eigenenergy surfaces characterizing the population transfer processes based on adiabatic passage. We show that this topology is the essential feature for the analysis of the population transfers and the prediction of its final result. We reinterpret diverse known processes, such as stimulated Raman adiabatic passage (STIRAP), frequency-chirped adiabatic passage and Stark-chirped rapid adiabatic passage (SCRAP). Moreover, using this picture, we display new related possibilities of transfer. In particular, we show that we can selectively control the level which will be populated in STIRAP process in Lambda or V systems by the choice of the peak amplitudes or the pulse sequence.

  13. An Analysis of Biogas Reforming Process on Ni/YSZ and Ni/SDC Catalysts

    Janusz Szmyd

    2012-02-01

    Full Text Available The conversion of biogas to electricity presents an attractive niche application for fuel cells. Thus attempts have been made to use biogas as a fuel for high temperature fuel cell systems such as SOFC. Biogas can be converted to hydrogen-rich fuel in a reforming process. For hydrocarbon-based fuel, three types of fuel conversion can be considered in reforming reactions: an external reforming system, an indirect internal reforming system and a direct internal reforming system. High-temperature SOFC eliminates the need for an expensive external reforming system. The possibility of using internal reforming is one of the characteristics of high temperature fuel cells like SOFC. However, for high-temperature operation, thermal management of the SOFC system becomes an important issue. To properly carry out thermal management, both detailed modeling and numerical analyses of the phenomena occurring inside the SOFC system is required. In the present work, the process of reforming biogas on a Ni/YSZ and a Ni/SDC catalyst has been numerically and experimentally investigated. Measurements including different thermal boundary conditions, steam-to-carbon ratios and several different fuel compositions were taken. A numerical model containing methane/steam reforming reaction, dry reforming reaction and shift reaction has been proposed to predict the gas mixture composition at the outlet of the reformer. The results of the numerical computation were compared with experimental data and good agreement has been found. The results indicate the importance of combined, numerical and experimental studies in the design of SOFC reformers. The combined approach used leads to the successful prediction of the outlet gas composition for different modelling conditions.

  14. Policy process for health sector reforms: a case study of Punjab Province (Pakistan).

    Tarin, Ehsanullah; Green, Andrew; Omar, Maye; Shaw, Jane

    2009-01-01

    The health sector in the Punjab (Pakistan) faces many problems, and, the government introduced reforms during 1993-2000. This paper explores the policy process for the reforms. A case study method was used and, to assist this, a conceptual framework was developed. Analysis of four initiatives indicated that there were deviations from the government guidelines and that the policy processes used were weak. The progress of different reforms was affected by a variety of factors: the immaturity of the political process and civil society, which together with innate conservatism and resistance to change on the part of the bureaucracy resulted in weak strategic sectoral leadership and a lack of clear purpose underpinning the reforms. It also resulted in weaknesses in preparation of the detail of reforms leading to poor implementation. The study suggests a need for broadening the stakeholders' base, building the capacity of policy-makers in policy analysis and strengthening the institutional basis of policymaking bodies.

  15. Weather Types, temperature and relief relationship in the Iberian Peninsula: A regional adiabatic processes under directional weather types

    Peña Angulo, Dhais; Trigo, Ricardo; Cortesi, Nicola; Gonzalez-Hidalgo, Jose Carlos

    2016-04-01

    We have analyzed at monthly scale the spatial distribution of Pearson correlation between monthly mean of maximum (Tmax) and minimum (Tmin) temperatures with weather types (WTs) in the Iberian Peninsula (IP), represent them in a high spatial resolution grid (10km x 10km) from MOTEDAS dataset (Gonzalez-Hidalgo et al., 2015a). The WT classification was that developed by Jenkinson and Collison, adapted to the Iberian Peninsula by Trigo and DaCamara, using Sea Level Pressure data from NCAR/NCEP Reanalysis dataset (period 1951-2010). The spatial distribution of Pearson correlations shows a clear zonal gradient in Tmax under the zonal advection produced in westerly (W) and easterly (E) flows, with negative correlation in the coastland where the air mass come from but positive correlation to the inland areas. The same is true under North-West (NW), North-East (NE), South-West (SW) and South-East (SE) WTs. These spatial gradients are coherent with the spatial distribution of the main mountain chain and offer an example of regional adiabatic phenomena that affect the entire IP (Peña-Angulo et al., 2015b). These spatial gradients have not been observed in Tmin. We suggest that Tmin values are less sensitive to changes in Sea Level Pressure and more related to local factors. These directional WT present a monthly frequency over 10 days and could be a valuable tool for downscaling processes. González-Hidalgo J.C., Peña-Angulo D., Brunetti M., Cortesi, C. (2015a): MOTEDAS: a new monthly temperature database for mainland Spain and the trend in temperature (1951-2010). International Journal of Climatology 31, 715-731. DOI: 10.1002/joc.4298 Peña-Angulo, D., Trigo, R., Cortesi, C., González-Hidalgo, J.C. (2015b): The influence of weather types on the monthly average maximum and minimum temperatures in the Iberian Peninsula. Submitted to Hydrology and Earth System Sciences.

  16. Kinetic behaviour of commercial catalysts for methane reforming in ethanol steam reforming process

    Jorge Vicente; Javier Ere˜na; Martin Olazar; Pedro L. Benito; Javier Bilbao; Ana G. Gayubo

    2014-01-01

    Ethanol steam reforming has been studied in a fluidized bed (in order to ensure bed isothermicity) on commercial catalysts for methane reforming. The results allow analyzing the effect of temperature (in 300-700◦C range), and both metal and support nature on the reaction indices (ethanol conversion, yields and selectivities to H2 and byproducts (CO2, CO, CH4 and C2H4O)). Special attention has been paid to catalysts’ stability by comparing the evolution of the reaction indices with time on stream at 500◦C (minimum CO formation) and 700◦C (minimum deactivation by coke deposition). Although they provide a slightly lower H2 yield, the results evidence a good behaviour of Ni based catalysts, indicating that they are an interesting alternative of more expensive Rh based ones.

  17. 气体的绝热节流过程不是等焓过程%Adiabatic Throttling Process of Gas Is Not Isoenthalpic

    尹钊; 杭桂生

    2001-01-01

    说明气体的绝热节流过程不是等焓过程,指出用焦-汤系数μ=(T)/(p)H来说明焦耳-汤姆孙效应所存在的弊端,并给予正确的解释.%It is pointed out that the adiabatic throttling process of gas is not an isoenthalpic one and that there are some drawbacks for interpreting the Joule-Thomson effect with the Joule-Thomson coefficient μ=(T)/(p)H.A proper interpretation for the throttling process is given.

  18. Team-Based Professional Development: A Process for School Reform

    Witmer, Judith T.; Melnick, Steven A.

    2006-01-01

    In this book, the authors provide an overview of adult learning and its impact on professional development. The chapters provide a theoretical foundation along with practical advice on implementing team-based professional development among educators within school districts which will lead to true systemic reform. The following seven chapters are…

  19. THE BOLOGNA PROCESS: THE REFORM OF THE EUROPEAN HIGHER EDUCATION SYSTEMS

    Éva Szolár

    2011-03-01

    Full Text Available The structural reform becomes the most visible initiative of the Bologna process. However, today the reform serves as an umbrella for comprehensive reform processes in national systems of higher education. In Central and Eastern European countries the Bologna process is not only strongly connected to the overall political transformation, but provides for the higher education policy makers an opportunity for the Europeanization of the sector. The implementation of the three-cycle system (the reform of organizational dimensions creates a demand for other reforms, and under this agenda have been released a numerous fundamental questions and debates on higher education systems. In a narrow concept, the Bologna process at the present implies systemic (e.g. core functions and role of different higher education institutions, the future of university and non-university sector, programmatic (e.g. at different program levels different curricular emphasis, arrangements and functions; vocationalization of the academic curriculum, procedural (e.g. new modes and arrangements of teaching changes, and shift from accent on horizontal to vertical differences (e.g. the set up of stratified and hierarchical national systems based on reputation and prestige, especially in research quality, and from input to output oriented higher education. In a broad sense, and on the basis of national implementation experiences, we can also conceptualize the Bologna process as governance or recently finance reform. As the concepts behind these reform initiatives suggests, the original objectives of the Bologna process is reinterpreted and overwrote, by the Lisbon Strategy and several national higher educational policy objectives.

  20. Adiabatic turbocompound diesel engine

    Kamo, R.; Bryzik, W.

    1984-02-01

    The research and development of an adiabatic turbocompound engine have shown that the concept is feasible. The ability to meet the performance and sociability goals of the future power plants has been demonstrated. Low brake specific fuel consumption, low smoke and particulates, better NO /SUB x/ -BSFC trade-off, excellent multifuel capability, white smoke suppression, and potentially lower maintenance and greater reliability and durability are some of the attributes. The absence of the water cooling system adds to its attractiveness because of lower installed weight, cost, and reduction in parasitic losses. The operating environment of an adiabatic engine is shown as the basis for analysis and designing of adiabatic components. The types of material which can satisfy the needs of an adiabatic engine are presented. These materials include high temperature metals, high performance ceramics, and glass ceramics. The use of a turbocompound system to utilize the increased exhaust energy of an adiabatic engine is covered. A minimum fuel consumption of 0.285 lb/bhp-hr was achieved at 200 psi BMEP. Although the technical feasibility and viability of an adiabatic engine was demonstrated, the adiabatic diesel engine has problems which must be solved before it becomes a commercially viable product. These problem areas where more work is required are discussed.

  1. Comparative study of two theoretical models of methane and ethane steam reforming process

    Brus, Grzegorz; Kaczmarczyk Marcin Tomiczek, Robert; Mozdzierz, Marcin

    2016-09-01

    From the chemical point of view the reforming process of heavy hydrocarbons such as Associated Petroleum Gas (APG) is very complex. One of the main issue is a set of undesired chemical reactions that causes deposition of solid carbon and consequently block catalytic property of a reactor. The experimental investigation is crucial to design APG reforming reactors. However, the experiment needs to be preceded by careful thermodynamical analysis to design safe operation conditions. In case of small number of reactants and reactions such as in case of steam reforming of pure methane, the problem can be solved by treating each equilibrium reaction constant as an element of the system of non-linear equations. The system of equations can be solved by Newton-Raphson method. However in case of large number of reactants and reaction, such as in case of APG reforming this method is inefficient. A large number of strongly non-linear equations leads often to converge problem. In this paper the authors suggest to use different approach called Parametric Equation Method. In this method a system of non-linear equations is replaced by a set of single non-linear equations solved separately. The methods were used to simulate steam reforming of methane-ethane rich fuel. The results of computations from both methods were juxtaposed and comparative study were conducted. Finally safe operation conditions for steam reforming of methane-ethane fuel were calculated and presented.

  2. Quantum adiabatic machine learning

    Pudenz, Kristen L

    2011-01-01

    We develop an approach to machine learning and anomaly detection via quantum adiabatic evolution. In the training phase we identify an optimal set of weak classifiers, to form a single strong classifier. In the testing phase we adiabatically evolve one or more strong classifiers on a superposition of inputs in order to find certain anomalous elements in the classification space. Both the training and testing phases are executed via quantum adiabatic evolution. We apply and illustrate this approach in detail to the problem of software verification and validation.

  3. Health Reform in Ceará: the process of decentralisation in the 1990s.

    Medeiros, Regianne Leila Rolim; Atkinson, Sarah

    2009-06-30

    The objective of this article is to offer an overview of the health reform in Ceará focusing on the decentralisation process in the 1990s. The driving factor behind the Brazilian health reform movement was the necessity to reorganise the national health system and overcome inequalities. For the reformists, decentralisation, and together with it the idea of popular participation, is seen as essential to guarantee the fulfilment of the people's needs and to incorporate their voice in the decision-making processes of the health system. In the state of Ceará, after the 1986 elections, health reform movement members took control over the management of the state Health Secretariat. This is the main cause of the acceleration of the decentralisation process with the transference of responsibility over the management of health care delivery to municipalities.

  4. Health Reform in Ceará: the process of decentralisation in the 1990s

    Medeiros, Regianne Leila Rolim; Atkinson, Sarah

    2015-01-01

    The objective of this article is to offer an overview of the health reform in Ceará focusing on the decentralisation process in the 1990s. The driving factor behind the Brazilian health reform movement was the necessity to reorganise the national health system and overcome inequalities. For the reformists, decentralisation, and together with it the idea of popular participation, is seen as essential to guarantee the fulfilment of the people’s needs and to incorporate their voice in the decision-making processes of the health system. In the state of Ceará, after the 1986 elections, health reform movement members took control over the management of the state Health Secretariat. This is the main cause of the acceleration of the decentralisation process with the transference of responsibility over the management of health care delivery to municipalities. PMID:25729333

  5. Analysis of the National Modernizers Network for the Support of the Public Administration Reform Process from Romania

    Alina PROFIROIU

    2010-10-01

    Full Text Available The reform process of the state and implicitly of the public administration was a priority for the past governments of Romania. During 2004- 2009, within the reform process, the main actors involved in the coordination, implementation and monitoring of reform measures were: the Prime Minister, the Superior Council for Public Administration Reform, Public Policy Coordination and Structural Adjustment, the Ministry of Public Finance, the General Secretariat of Government, Ministry of Administration and Interior (renamed for a short time Ministry of Interior and Administrative Reform, the Central Unit for Public Administration Reform, National Institute of Administration, the National Agency of Civil Servants, and the National Modernizers Network. For evaluation of aspects related to the reform process it was designed a selective research within the members of the National Modernizers Network, for assessing their perception of the public administration reform undertaken by the institutions presented above. Evaluating their opinion can be an important point in the revitalization of the area of the administration reform process. Also, the research conducted aimed at assessing the degree of modernizers’ involvement in activities related to important aspects of the reform process: strategic planning, formulating and evaluating public policies, financial management, human resources management, decentralization, introduction of new information and communication technologies and administrative simplification.

  6. Adiabatic markovian dynamics.

    Oreshkov, Ognyan; Calsamiglia, John

    2010-07-30

    We propose a theory of adiabaticity in quantum markovian dynamics based on a decomposition of the Hilbert space induced by the asymptotic behavior of the Lindblad semigroup. A central idea of our approach is that the natural generalization of the concept of eigenspace of the Hamiltonian in the case of markovian dynamics is a noiseless subsystem with a minimal noisy cofactor. Unlike previous attempts to define adiabaticity for open systems, our approach deals exclusively with physical entities and provides a simple, intuitive picture at the Hilbert-space level, linking the notion of adiabaticity to the theory of noiseless subsystems. As two applications of our theory, we propose a general framework for decoherence-assisted computation in noiseless codes and a dissipation-driven approach to holonomic computation based on adiabatic dragging of subsystems that is generally not achievable by nondissipative means.

  7. Adiabatic quantum computing

    Lobe, Elisabeth; Stollenwerk, Tobias; Tröltzsch, Anke

    2015-01-01

    In the recent years, the field of adiabatic quantum computing has gained importance due to the advances in the realisation of such machines, especially by the company D-Wave Systems. These machines are suited to solve discrete optimisation problems which are typically very hard to solve on a classical computer. Due to the quantum nature of the device it is assumed that there is a substantial speedup compared to classical HPC facilities. We explain the basic principles of adiabatic ...

  8. Prediction of Reaction Kinetic of Al- Doura Heavy Naphtha Reforming Process Using Genetic Algorithm

    Ramzy H. Saihod

    2015-07-01

    Full Text Available In this study, genetic algorithm was used to predict the reaction kinetics of Iraqi heavy naphtha catalytic reforming process located in Al-Doura refinery in Baghdad. One-dimensional steady state model was derived to describe commercial catalytic reforming unit consisting of four catalytic reforming reactors in series process. The experimental information (Reformate composition and output temperature for each four reactors collected at different operating conditions was used to predict the parameters of the proposed kinetic model. The kinetic model involving 24 components, 1 to 11 carbon atoms for paraffins and 6 to 11 carbon atom for naphthenes and aromatics with 71 reactions. The pre-exponential Arrhenius constants and activation energies were determined after fine tuning of the model results with experimental data. The input to the optimization is the compositions for 21 components and the temperature for the effluent stream for each one of the four reactors within the reforming process while the output of optimization is 142 predicted kinetic parameters for 71 reactions within reforming process. The differential optimization technique using genetic algorithm to predict the parameters of the kinetic model. To validate the kinetic model, the simulation results of the model based on proposed kinetic model was compared with the experimental results. The comparison between the predicted and commercially results shows a good agreement, while the percentage of absolute error for aromatics compositions are (7.5, 2, 8.3, and 6.1% and the temperature absolute percentage error are (0.49, 0.5, 0.01, and 0.3% for four reactors respectively.

  9. Adiabatic quantum computation along quasienergies

    Tanaka, Atushi

    2009-01-01

    The parametric deformations of quasienergies and eigenvectors of unitary operators are applied to the design of quantum adiabatic algorithms. The conventional, standard adiabatic quantum computation proceeds along eigenenergies of parameter-dependent Hamiltonians. By contrast, discrete adiabatic computation utilizes adiabatic passage along the quasienergies of parameter-dependent unitary operators. For example, such computation can be realized by a concatenation of parameterized quantum circuits, with an adiabatic though inevitably discrete change of the parameter. A design principle of adiabatic passage along quasienergy is recently proposed: Cheon's quasienergy and eigenspace anholonomies on unitary operators is available to realize anholonomic adiabatic algorithms [Tanaka and Miyamoto, Phys. Rev. Lett. 98, 160407 (2007)], which compose a nontrivial family of discrete adiabatic algorithms. It is straightforward to port a standard adiabatic algorithm to an anholonomic adiabatic one, except an introduction of...

  10. Production of synthetic fuels using syngas from a steam hydrogasification and reforming process

    Raju, Arun Satheesh Kumar

    This thesis is aimed at the research, optimization and development of a thermo-chemical process aimed at the production of synthesis gas (mixture of H2 and CO) with a flexible H2 to CO ratio using coupled steam hydrogasification and steam reforming processes. The steam hydrogasification step generates a product gas containing significant amounts of methane by gasifying a carbonaceous feed material with steam and internally generated H2. This product gas is converted to synthesis gas with an excess H2 to CO using the steam reformer. Research involving experimental and simulation work has been conducted on steam hydrogasification, steam reforming and the Fischer-Tropsch reaction. The Aspen Plus simulation tool has been used to develop a process model that can perform heat and mass balance calculations of the whole process using built-in reactor modules and an empirical FT model available in the literature. This model has been used to estimate optimum feed ratios and process conditions for specific feedstocks and products. Steam hydrogasification of coal and wood mixtures of varying coal to wood ratios has been performed in a stirred batch reactor. The carbon conversion of the feedstocks to gaseous products is around 60% at 700°C and 80% at 800°C. The coal to wood ratio of the feedstock does not exert a significant influence on the carbon conversion. The rates of formation of CO, CO 2 and CH4 during gasification have been calculated based on the experimental results using a simple kinetic model. Experimental research on steam reforming has been performed. It has been shown that temperature and the feed CO2/CH4 ratio play a dominant role in determining the product gas H2/CO ratio. Reforming of typical steam hydrogasification product-gas stream has been investigated over a commercial steam reforming catalyst. The results demonstrate that the combined use of steam hydrogasification process with a reformer can generate a synthesis gas with a predetermined H2/CO ratio

  11. Adiabatic Quantum Search in Open Systems.

    Wild, Dominik S; Gopalakrishnan, Sarang; Knap, Michael; Yao, Norman Y; Lukin, Mikhail D

    2016-10-07

    Adiabatic quantum algorithms represent a promising approach to universal quantum computation. In isolated systems, a key limitation to such algorithms is the presence of avoided level crossings, where gaps become extremely small. In open quantum systems, the fundamental robustness of adiabatic algorithms remains unresolved. Here, we study the dynamics near an avoided level crossing associated with the adiabatic quantum search algorithm, when the system is coupled to a generic environment. At zero temperature, we find that the algorithm remains scalable provided the noise spectral density of the environment decays sufficiently fast at low frequencies. By contrast, higher order scattering processes render the algorithm inefficient at any finite temperature regardless of the spectral density, implying that no quantum speedup can be achieved. Extensions and implications for other adiabatic quantum algorithms will be discussed.

  12. Adiabatic Quantum Search in Open Systems

    Wild, Dominik S.; Gopalakrishnan, Sarang; Knap, Michael; Yao, Norman Y.; Lukin, Mikhail D.

    2016-10-01

    Adiabatic quantum algorithms represent a promising approach to universal quantum computation. In isolated systems, a key limitation to such algorithms is the presence of avoided level crossings, where gaps become extremely small. In open quantum systems, the fundamental robustness of adiabatic algorithms remains unresolved. Here, we study the dynamics near an avoided level crossing associated with the adiabatic quantum search algorithm, when the system is coupled to a generic environment. At zero temperature, we find that the algorithm remains scalable provided the noise spectral density of the environment decays sufficiently fast at low frequencies. By contrast, higher order scattering processes render the algorithm inefficient at any finite temperature regardless of the spectral density, implying that no quantum speedup can be achieved. Extensions and implications for other adiabatic quantum algorithms will be discussed.

  13. Characteristics of the Reforming Process in the Romanian Public Administration System

    Tudorel ANDREI

    2009-02-01

    Full Text Available This paper aims to analyze, starting fromthe case of Romania, the degree to which publicadministration reform contributes to the reductionof corruption. In this paper, which has its ownmethodology, the level of corruption is estimatedand a series of factors that can contributeto its reduction in a certain time interval aredetermined.The analysis of the public administrationreform process was realized by using arepresentative survey conducted in May 2007at the public administration level. A two-phasesampling technique was used to build the sample,which included 971 civil servants from central andlocal public administration.The reforming process of the centraland local public administration in Romania isanalyzed with regard to the civil service reform,the decentralization process and fight againstcorruption in the public administration. Eightstatistical variables were defined in order toanalyze these aspects. Most of the variablesused in this study reveal significant differences atthe level of the four types of public administrationinstitutions. Nevertheless, the analysis shows thatthe intensification of the reform process at civilservice level leads to the reduction of the levelof corruption.

  14. Policies lost in translation? Unravelling water reform processes in African waterscapes

    Kemerink-Seyoum, J.S.

    2015-01-01

    Since the 1980s a major change took place in public policies for water resources management. The role of governments shifted under this reform process from an emphasis on investment in the development, operation and maintenance of water infrastructure to a focus on managing water resources systems b

  15. The Reform Process of Portuguese Higher Education Institutions: From Collegial to Managerial Governance

    Bruckmann, Sofia; Carvalho, Teresa

    2014-01-01

    Portuguese public higher education institutions have been undergoing a major reform process since 2007. The most noticeable changes were introduced by Law 62/2007, which gave higher education institutions the option to choose between two different institutional models (foundational and public institute), and allowed the implementation of new…

  16. Efficient utilization of greenhouse gas in a gas-to-liquids process combined with carbon dioxide reforming of methane.

    Ha, Kyoung-Su; Bae, Jong Wook; Woo, Kwang-Jae; Jun, Ki-Won

    2010-02-15

    A process model for a gas-to-liquids (GTL) process mainly producing Fischer-Tropsch (FT) synthetic oils has been developed to assess the effects of reforming methods, recycle ratio of unreacted syngas mixture on the process efficiency and the greenhouse gas (GHG) emission. The reforming unit of our study is composed of both steam reforming of methane (SRM) and carbon dioxide reforming of methane (CDR) to form syngas, which gives composition flexibility, reduction in GHG emission, and higher cost-competitiveness. With recycling, it is found that zero emission of CO(2) from the process can be realized and the required amount of natural gas (NG) can be significantly reduced. This GTL process model has been built by using Aspen Plus software, and it is mainly composed of a feeding unit, a reforming unit, an FT synthesis unit, several separation units and a recycling unit. The composition flexibility of the syngas mixture due to the two different types of reforming reactions raises an issue that in order to attain the optimized feed composition of FT synthesis the amount of flow rate of each component in the fresh feed mixture should be determined considering the effects of the recycle and its split ratio. In the FT synthesis unit, the 15 representative reactions for the chain growth and water gas shift on the cobalt-based catalyst are considered. After FT synthesis, the unreacted syngas mixture is recycled to the reforming unit or the FT synthesis unit or both to enhance process efficiency. The effect of the split ratio, the recycle flow rate to the FT reactor over the recycle flow rate to the reforming unit, on the efficiency of the process was also investigated. This work shows that greater recycle to the reforming unit is less effective than that to the FT synthesis unit from the standpoint of the net heat efficiency of the process, since the reforming reactions are greatly endothermic and greater recycle to the reformer requires more energy.

  17. Dynamic Modeling and Simulation of a Commercial Naphtha Catalytic Reforming Process

    胡永有; 徐巍华; 侯卫锋; 苏宏业; 褚健

    2005-01-01

    A first principles-based dynamic model for a continuous catalyst regeneration (CCR) platforming process, the UOP commercial naphtha catalytic reforming process, is developed in this paper. The lumping details of the naphtha feed and reaction scheme of the reaction model are given. The process model is composed of the reforming reaction model with catalyst deactivation, the furnace model and the separator model, which is capable of capturing the major dynamics that occurs in this process system. Dynamic simulations are performed based on Gear numerical algorithm and method of lines (MOL), a numerical technique dealing with partial differential equations (PDEs). The results of simulation are also presented. Dynamic responses caused by disturbances in the process system can be correctly predicted through simulations.

  18. Optimum temperature policy for sorption enhanced steam methane reforming process for hydrogen production

    Retnamma, Rajasree [National Laboratory of energy and Geology (LNEG), Lisbon (PT). Energy Systems Modeling and Optimization Unit (UMOSE); Ravi Kumar, V.; Kulkarni, B.D. [National Chemical Laboratory, Pune (India). Chemical Engineering and Process Development

    2010-07-01

    Sorption enhanced steam methane reforming (SE-SMR) process offers high potential for producing H{sub 2} in fuel cell applications compared to conventional catalytic steam methane reforming (SMR) process. The reactor temperature can significantly affect the performance of the SE-SMR reaction and simultaneous adsorption behavior of CO{sub 2}. Determination of an optimal temperature policy in SE-SMR reactor is therefore an important optimization issue. Multi-stage operation is a possible way to implement optimum temperature policies. In the present work, simulation study has been carried out for multi-stage operation using a mathematical model incorporating basic mechanisms operating in a fixed bed reactor with nonlinear reaction kinetic features of an SE-SMR process. Three cases were considered for implementing the multi-stage concept and the results show that increase in temperature based on a policy leads to considerable improvement in the process performance. (orig.)

  19. IMPACT OF THE REFORM PROCESS OF THE PUBLIC ADMINISTRATION ECONOMIC AND SOCIAL DEVELOPMENT OF ROMANIA

    GEORGETA MODIGA

    2012-05-01

    Full Text Available Romanian society is in a continuous process of change in which all the economic, social, political, civic saw a new dynamic in trying to adapt to specific conditions of the phenomenon of Europeanization (full member of the European Union. The changing of Romanian society requires the public administration reform to be analyzed and disseminated on the following levels: strategic - by which to redefine the role of the state clearly, legally - using larger framework laws, organizational - administrative and fiscal decentralization, cultural - following a change of values and modes of action of public officials, non governmental organizations, the citizen / customer of public service. The term administrative reform is trivial, repetitive and recurrent nets into change, public administration reform is invited to constantly readjust the organization and the action and to clearly state objectives, called sometimes the brakes released, blockages to overcome obstacles of the past which is manifested by the upward trend of the society. Public administration is criticized especially by the public and less by governments in office. Almost general belief is that the administration functions poorly, fulfil its mission in an unsatisfactory manner, but nevertheless has an impact too on community life, economy and society. This paper aims to identify the type of problems that other countries have had to solve and the need hierarchy and management combined in a single system. Understanding the types of problems encountered and they do other countries in this process will shorten the learning cycle for Romania. The objectives of this approach is that the critical analysis of the relationship between public administration reform and administrative capacity based on the literature, outlining the operational model to assess the reform process in our country, the study of democratization (the stage of democratization of public administration modernization strategy

  20. Process Improvements to Reform Patient Flow in the Emergency Department.

    Whatley, Shawn D; Leung, Alexander K; Duic, Marko

    2016-01-01

    Emergency departments (ED) function to diagnose, stabilize, manage and dispose patients as efficiently as possible. Although problems may be suspected at triage, ED physician input is required at each step of the patient journey through the ED, from diagnosis to disposition. If we want timely diagnosis, appropriate treatment and great outcomes, then ED processes should connect patients and physicians as quickly as possible. This article discusses the key concepts of ED patient flow, value and efficiency. Based on these fundamentals, it describes the significant impact of ED process improvements implemented on measures of ED efficiency at a large community ED in Ontario, Canada.

  1. Combined Partial Oxidation and Carbon Dioxide Reforming Process: A Thermodynamic Study

    Sompop Jarungthammachote

    2011-01-01

    Full Text Available Problem statement: CO2 reforming is one of the methods to utilize a greenhouse gas to produce syngas, an important feed for methanol and Fischer-Tropsch synthesis. However, CO2 reforming is strong endothermic reaction requiring large amount of supplied energy. Partial oxidation, an exothermic reaction, is combined with CO2 reforming to serve the energy requirement. Thus, the optimum ranges of O2 and CO2 fed to the process corresponding to feedstock are needed to find. Moreover, one of the most important problems found in this process is solid carbon formation. Therefore, the operating range in which the carbon formation can be avoided is also required to study. Approach: In this study CH4 was used as feedstock. The optimum rage of O2 and CO2 fed to the process was found by using thermodynamic equilibrium method based on minimization of Gibbs free energy. The Lagrange multiplier method was conducted to form the equations and they were solved by the Newton-Raphson method. The solid carbon formation zone was also simulated. Results: The simulation showed that higher reaction temperature caused higher CH4 and CO2 conversions. Syngas production increased with increasing temperature. Operating the process with high temperature or high O2/CH4 and CO2/CH4 rations could eliminate solid carbon formation. Increase of O2/CH4 ration higher than 0.1 led decreasing syngas while increase of CO2/CH4 ration caused increasing H2 and CO. However, when CO2/CH4 ration was higher than 0.85, increasing CO2/CH4 ration showed insignificant change of syngas concentration. Conclusion: The combined partial oxidation and CO2 reforming of method should be operated with reaction temperature of 1050 K. The optimum range of CH4:CO2:O2 for this process is 1: 0.85-1.0:0.1-0.2.

  2. The Impact of the Health Care System Reform on the Romanian Nurses Professionalization Process

    Silvia POPOVICI

    2012-06-01

    Full Text Available The Romanian health sector went through a process of reform began in 2000 which entered into a final adjustment phase in 2010 when the economic crisis, the health professionals accelerated trend of labour migration, the precarious health of the population brought new challenges to the unsolved existing problems. Nurses are numerically the most important category of health professionals. Since 1994 they experienced a convergent movement of professionalization in the interior of the nurse profession. The aim of the study is to explore the nurses’ perceptions of the impact of the health care system reform on their own profession and on the internal process of professionalization. As a result a quantitative research was conducted on a sample including 411 nurses of different specialties working in Iasi county. The results of the research point out the significant impact of factors related to the reform of the health care system on the quality of the care process, on the nurses’ work conditions and professional satisfaction. The external disruptive factors produce negative effects on nurses’ group cohesion, despite the centripetal efforts of the professional organization and induce a slowdown movement of the nurses professionalization process.

  3. Analysis of reforming process of large distorted ring in final enlarging forging

    Miyazawa, Takeshi; Murai, Etsuo [Kushiro National College of Technology, Dept. of Mechanical Engineering, Kushiro, Hokkaido (Japan)

    2002-10-01

    In the construction of reactors or pressure vessels for oil chemical plants and nuclear power stations, mono block open-die forging rings are often utilized. Generally, a large forged ring is manufactured by means of enlarging forging with reductions of the wall thickness. During the enlarging process the circular ring is often distorted and becomes an ellipse in shape. However the shape control of the ring is a complicated work. This phenomenon makes the matter still worse in forging of larger rings. In order to make precision forging of large rings, we have developed the forging method using a v-shape anvil. The v-shape anvil is geometrically adjusted to fit the distorted ring in the final circle and reform automatically the shape of the ring during enlarging forging. This paper has analyzed the reforming process of distorted ring by computer program based on F.E.M. and examined the effect on the precision of ring forging. (author)

  4. Gas and liquid phase fuels desulphurization for hydrogen production via reforming processes

    Hoguet, Jean-Christophe; Karagiannakis, George P.; Valla, Julia A.; Agrafiotis, Christos C. [Aerosol and Particle Technology Laboratory, CERTH/CPERI, P.O. Box 361, 57001 Thermi, Thessaloniki (Greece); Konstandopoulos, Athanasios G. [Aerosol and Particle Technology Laboratory, CERTH/CPERI, P.O. Box 361, 57001 Thermi, Thessaloniki (Greece); Department of Chemical Engineering, Aristotle University, P.O. Box 1517, 54006 Thessaloniki (Greece)

    2009-06-15

    The present work focuses on the development of efficient desulphurization processes for multi-fuel reformers for hydrogen production. Two processes were studied: liquid hydrocarbon desulphurization and H{sub 2}S removal from reformate gases. For each process, materials with various chemical compositions and microporous structures were synthesized and characterized with respect to their physicochemical properties and desulphurization ability. In the case of liquid phase desulphurization, the adsorption of sulphur compounds contained in diesel fuel under ambient conditions was studied employing as sorbents, zeolite-based materials, i.e. NaY, HY and metal ion-exchanged NaY and HY, as well as a high-surface area activated carbon (AC), for three different diesel fuels with sulphur content varying between 5 and 180 ppmw. Among all sorbents studied, AC showed the best desulphurization performance followed by cerium ion-exchanged HY. The gas phase desulphurization experiments involved the evaluation of zinc-based mixed oxides, synthesized by non-conventional (combustion synthesis) techniques on high steam content reformate gas mixtures. (author)

  5. Assessment of total efficiency in adiabatic engines

    Mitianiec, W.

    2016-09-01

    The paper presents influence of ceramic coating in all surfaces of the combustion chamber of SI four-stroke engine on working parameters mainly on heat balance and total efficiency. Three cases of engine were considered: standard without ceramic coating, fully adiabatic combustion chamber and engine with different thickness of ceramic coating. Consideration of adiabatic or semi-adiabatic engine was connected with mathematical modelling of heat transfer from the cylinder gas to the cooling medium. This model takes into account changeable convection coefficient based on the experimental formulas of Woschni, heat conductivity of multi-layer walls and also small effect of radiation in SI engines. The simulation model was elaborated with full heat transfer to the cooling medium and unsteady gas flow in the engine intake and exhaust systems. The computer program taking into account 0D model of engine processes in the cylinder and 1D model of gas flow was elaborated for determination of many basic engine thermodynamic parameters for Suzuki DR-Z400S 400 cc SI engine. The paper presents calculation results of influence of the ceramic coating thickness on indicated pressure, specific fuel consumption, cooling and exhaust heat losses. Next it were presented comparisons of effective power, heat losses in the cooling and exhaust systems, total efficiency in function of engine rotational speed and also comparison of temperature inside the cylinder for standard, semi-adiabatic and full adiabatic engine. On the basis of the achieved results it was found higher total efficiency of adiabatic engines at 2500 rpm from 27% for standard engine to 37% for full adiabatic engine.

  6. Accelerating process and catalyst development in reforming reactions with high throughput technologies under industrially relevant conditions

    Schunk, S.A.; Bollmann, G.; Froescher, A.; Kaiser, H.; Lange de Oliveira, A.; Roussiere, T.; Wasserschaff, G. [hte Aktiengesellschaft, Heidelberg (Germany); Domke, I. [BASF SE, Ludwigshafen (Germany)

    2010-12-30

    The generation of hydrogen via reforming of a variety of carbon containing feed-stocks in the presence of water is up to date one of the most versatile technologies for the production of hydrogen and syngas. Although these reforming technologies are in principle well established, understood and commercialized, there are still a number of technological challenges that are not solved up to a satisfactorily degree and there is a constant demand for appropriate answers to the challenges posed. High throughput experimentation can be a valuable tool in helping accelerate the development of suitable solutions on the catalyst and process development side. In order to be able to generate test data that are close or identical to process relevant conditions, hte has developed a new technology portfolio of test technologies named Stage-IV technology. In contrast to earlier developments which address more small scale testing on the basis of catalyst volumes of 1ml up to 10 ml under isothermal conditions, our new technology portfolio offers the advantage of test volumes at sub-pilot scale also realizing reactor dimensions close to technical applications. This does not only ensure a good mimic of the hydrodynamic conditions of the technical scale, but also allows a fingerprinting of features like temperature gradients in the catalyst bed which play a large role for catalyst performance. Apart from catalyst tests with granulates when screening for optimized catalyst compositions, the units are designed to accommodate tests with shaped catalysts. In order to demonstrate how these technologies can accelerate catalyst and process development we have chosen technically challenging application examples: (I) Pre-reforming and reforming of methane based feeds which accelerate coking and catalyst deactivation. Higher reaction pressures, high CO{sub 2} contents in the feedgas (which occur typically in sources like bio-gas or certain types of natural gas), the presence of higher alkanes

  7. Adiabatic Quantum Simulators

    Biamonte, J D; Whitfield, J D; Fitzsimons, J; Aspuru-Guzik, A

    2010-01-01

    In his famous 1981 talk, Feynman proposed that unlike classical computers, which would presumably experience an exponential slowdown when simulating quantum phenomena, a universal quantum simulator would not. An ideal quantum simulator would be error resistant, easily controllable, and built using existing technology. Moving away from gate-model and projective measurement based implementations of quantum computing may offer a less resource-intensive, and consequently a more feasible solution. Here we consider an adiabatic quantum simulator which simulates the ground state properties of sparse Hamiltonians consisting of one- and two-body interaction terms, using sparse Hamiltonians with at most three-body interactions. Properties of such Hamiltonians can be well approximated with Hamiltonians containing only two-local terms. The register holding the simulated ground state is brought adiabatically into interaction with a probe qubit, followed by a single diabatic gate operation on the probe which then undergoes...

  8. Semiconductor adiabatic qubits

    Carroll, Malcolm S.; Witzel, Wayne; Jacobson, Noah Tobias; Ganti, Anand; Landahl, Andrew J.; Lilly, Michael; Nguyen, Khoi Thi; Bishop, Nathaniel; Carr, Stephen M.; Bussmann, Ezra; Nielsen, Erik; Levy, James Ewers; Blume-Kohout, Robin J.; Rahman, Rajib

    2016-12-27

    A quantum computing device that includes a plurality of semiconductor adiabatic qubits is described herein. The qubits are programmed with local biases and coupling terms between qubits that represent a problem of interest. The qubits are initialized by way of a tuneable parameter, a local tunnel coupling within each qubit, such that the qubits remain in a ground energy state, and that initial state is represented by the qubits being in a superposition of |0> and |1> states. The parameter is altered over time adiabatically or such that relaxation mechanisms maintain a large fraction of ground state occupation through decreasing the tunnel coupling barrier within each qubit with the appropriate schedule. The final state when tunnel coupling is effectively zero represents the solution state to the problem represented in the |0> and |1> basis, which can be accurately read at each qubit location.

  9. Adiabatic Quantum Computation: Coherent Control Back Action

    Goswami, Debabrata

    2013-01-01

    Though attractive from scalability aspects, optical approaches to quantum computing are highly prone to decoherence and rapid population loss due to nonradiative processes such as vibrational redistribution. We show that such effects can be reduced by adiabatic coherent control, in which quantum interference between multiple excitation pathways is used to cancel coupling to the unwanted, non-radiative channels. We focus on experimentally demonstrated adiabatic controlled population transfer experiments wherein the details on the coherence aspects are yet to be explored theoretically but are important for quantum computation. Such quantum computing schemes also form a back-action connection to coherent control developments. PMID:23788822

  10. [The reform process and social participation in health in Latin America].

    Vázquez, M L; Siqueira, E; Kruze, I; Da Silva, A; Leite, I C

    2002-01-01

    Currently, many countries throughout the world are reforming their health services. Even though these reforms differ according to the country's characteristics, they share many policies, one of which is the promotion of social participation in health-related matters. This policy, however, is not new in the field of health service organization. Throughout the last century, individual or collective collaboration between the population and health services has been promoted by several philosophies and concepts with different aims: from the search for collaboration with the general public to broaden public health system coverage to the promotion of the creation of mechanisms that would allow society to exercise control over these services' performance. Nevertheless, for the public to be involved with these services, several factors concerning both the services themselves and the population, need to converge. Although the theoretical frameworks that have encouraged social participation throughout the history of the development of health systems differ considerably, their practical implementation shares many common elements in all periods, from participation as a means of obtaining certain objectives to being an end in itself, as a democratic process. This can also be applied to the current promotion of social participation policies in the context of health care reforms, which are analyzed using Colombia and Brazil as examples.

  11. Reform of abortion law in Uruguay: context, process and lessons learned.

    Wood, Susan; Abracinskas, Lilián; Correa, Sonia; Pecheny, Mario

    2016-11-01

    In October 2012, a new law was approved in Uruguay that allows abortion on demand during the first 12 weeks of pregnancy, 14 weeks in the case of rape, and without a time limit when the woman's health is at risk or in the case of foetal anomalies. This paper analyses this legal reform. It is based on 27 individual and group interviews with key informants, and on review of primary documents and the literature. The factors explaining the reform include: secular values in society, favourable public opinion, a persistent feminist movement, effective coalition building, particular party politics, and a vocal public health sector. The content of the new law reflects the tensions between a feminist perspective of women's rights and public health arguments that stop short of fully recognizing women's autonomy. The Uruguayan reform shows that, even in Latin America, abortion can be addressed politically without electoral cost to the parties that promote it. On the other hand, the prevailing public health rationale and conditionalities built into the law during the negotiation process resulted in a law that cannot be interpreted as a full recognition of women's rights, but rather as a modified protectionist approach that circumscribes women's autonomy.

  12. Shortcuts to adiabaticity in cutting a spin chain

    Ren, Feng-Hua; Wang, Zhao-Ming; Gu, Yong-Jian

    2017-01-01

    "Shortcuts to adiabaticity" represents a strategy for accelerating a quantum adiabatic process, is useful for preparing or manipulating a quantum state. In this paper, we investigate the adiabaticity in the dynamics of an XY spin chain. During the process of cutting one long chain into two short chains, a "shortcut" can be obtained by applying a sequence of external pulses. The fidelity which measures the adiabaticity can be dramatically enhanced by increasing the pulse strength or pulse duration time. This reliability can be kept for different types of pulses, such as random pulse time interval or random strength. The free choice of the pulse can be explained by the adiabatic representation of the Hamiltonian, and it shows that the control effects are determined by the integral of the control function in the time domain.

  13. Plasma adiabatic lapse rate

    Amendt, Peter; Wilks, Scott

    2012-01-01

    The plasma analog of an adiabatic lapse rate (or temperature variation with height) in atmospheric physics is obtained. A new source of plasma temperature gradient in a binary ion species mixture is found that is proportional to the concentration gradient and difference in average ionization states . Application to inertial-confinement-fusion implosions indicates a potentially strong effect in plastic (CH) ablators that is not modeled with mainline (single-fluid) simulations. An associated plasma thermodiffusion coefficient is derived, and charge-state diffusion in a single-species plasma is also predicted.

  14. Nonresonance adiabatic photon trap

    Popov, S S; Burdakov, A V; Ushkova, M Yu

    2016-01-01

    Concept of high efficiency photon storage based on adiabatic confinement between concave mirrors is presented and experimentally investigated. The approach is insensitive to typical for Fabri-Perot cells requirements on quality of accumulated radiation, tolerance of resonator elements and their stability. Experiments have been carried out with the trap, which consists from opposed concave cylindrical mirrors and conjugated with them spherical mirrors. In result, high efficiency for accumulation of radiation with large angular spread and spectrum width has been confirmed. As radiation source a commercial fiber laser has been used.

  15. Experimental evaluation of methane dry reforming process on a membrane reactor to hydrogen production

    Silva, Fabiano S.A.; Benachour, Mohand; Abreu, Cesar A.M. [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Dept. of Chemical Engineering], Email: f.aruda@yahoo.com.br

    2010-07-01

    In a fixed bed membrane reactor evaluations of methane-carbon dioxide reforming over a Ni/{gamma}- Al{sub 2}O{sub 3} catalyst were performed at 773 K, 823 K and 873 K. A to convert natural gas into syngas a fixed-bed reactor associate with a selective membrane was employed, where the operating procedures allowed to shift the chemical equilibrium of the reaction in the direction of the products of the process. Operations under hydrogen permeation, at 873 K, promoted the increase of methane conversion, circa 83%, and doubled the yield of hydrogen production, when compared with operations where no hydrogen permeation occurred. (author)

  16. Adiabatic quantum simulators

    J. D. Biamonte

    2011-06-01

    Full Text Available In his famous 1981 talk, Feynman proposed that unlike classical computers, which would presumably experience an exponential slowdown when simulating quantum phenomena, a universal quantum simulator would not. An ideal quantum simulator would be controllable, and built using existing technology. In some cases, moving away from gate-model-based implementations of quantum computing may offer a more feasible solution for particular experimental implementations. Here we consider an adiabatic quantum simulator which simulates the ground state properties of sparse Hamiltonians consisting of one- and two-local interaction terms, using sparse Hamiltonians with at most three-local interactions. Properties of such Hamiltonians can be well approximated with Hamiltonians containing only two-local terms. The register holding the simulated ground state is brought adiabatically into interaction with a probe qubit, followed by a single diabatic gate operation on the probe which then undergoes free evolution until measured. This allows one to recover e.g. the ground state energy of the Hamiltonian being simulated. Given a ground state, this scheme can be used to verify the QMA-complete problem LOCAL HAMILTONIAN, and is therefore likely more powerful than classical computing.

  17. Sorption enhanced steam reforming of biomass-derived compounds: process and material

    He, Li

    2010-07-01

    An attempt has been made to develop a flexible system to produce very pure H{sub 2} with high efficiency from renewable bio-based recourses. First, such model compounds as ethanol, glycerol, sorbitol and glucose, have been tested for H{sub 2} production via sorption enhanced steam reforming (SESR) over Co-Ni/hydrotalcite-like (HTls) derived catalyst and CaO-based CO{sub 2} acceptor. The experimental results show that all of feedstocks, even heavy feedstocks, were able to offer high H{sub 2} purity (97.3approx99.1%) and yield at low steam to carbon (S/C = 1.3approx6) ratio in comparison to the corresponding steam reforming process. In addition, the studied system also presents encouraging potential for improvement of energy efficiency. Chemical looping combustion (CLC) was coupled to the cyclic multi-step SESR process to assist the acceptor regeneration by using multifunctional Pd/Co-Ni/HTls catalyst. With coupling of CLC to SESR, H{sub 2} concentration in the gas effluent of the SESR reactions was still higher than 95 mol% on a dry basis. The assembled CLC-SESR process has inherent high efficiency in H{sub 2} production. (Author)

  18. An Integrated Development Environment for Adiabatic Quantum Programming

    Humble, Travis S [ORNL; McCaskey, Alex [ORNL; Bennink, Ryan S [ORNL; Billings, Jay Jay [ORNL; D' Azevedo, Eduardo [ORNL; Sullivan, Blair D [ORNL; Klymko, Christine F [ORNL; Seddiqi, Hadayat [ORNL

    2014-01-01

    Adiabatic quantum computing is a promising route to the computational power afforded by quantum information processing. The recent availability of adiabatic hardware raises the question of how well quantum programs perform. Benchmarking behavior is challenging since the multiple steps to synthesize an adiabatic quantum program are highly tunable. We present an adiabatic quantum programming environment called JADE that provides control over all the steps taken during program development. JADE captures the workflow needed to rigorously benchmark performance while also allowing a variety of problem types, programming techniques, and processor configurations. We have also integrated JADE with a quantum simulation engine that enables program profiling using numerical calculation. The computational engine supports plug-ins for simulation methodologies tailored to various metrics and computing resources. We present the design, integration, and deployment of JADE and discuss its use for benchmarking adiabatic quantum programs.

  19. South African health financing reform 2000-2010: understanding the agenda-setting process.

    Pillay, Timesh D; Skordis-Worrall, Jolene

    2013-03-01

    Governments around the world are struggling to address persistent disparities in health care access. However, this priority competes with many others for support in moving onto and up the political agenda. In this paper, a novel method of agenda-setting analysis is developed by merging and modifying the Hall and Kingdon models. As a case study, this method is used to explore how health financing reform reached the policy agenda in South Africa between the years 2000 and 2010. Certain factors are identified that could have determined the agenda-setting process: a change in government, increase in the cost of private medical schemes, and increase in support for reform from various stakeholders. Further analysis, using a conceptual framework of interacting trends and shocks, identifies the growing middle class, the private sector, and workers unions as powerful actors and outlines further factors that may have contributed to the process: a broad political shift in the second half of the decade and the changing prioritisation of HIV/AIDS. Study findings have relevance to academics and policy makers in South Africa and beyond.

  20. Adiabatic paths and pseudoholomorphic curves

    Armen; G.; Sergeev

    2005-01-01

    We consider the (2+1)-dimensional Abelian Higgs model, governed by the Ginzburg-Landau action functional and describe the adiabatic limit construction for this model. Then we switch to the 4-dimensional case and Show that the Taubes correspondence may be considered as a (2+2)-dimensional analogue of the adiabatic limit construction.

  1. Geometry of the Adiabatic Theorem

    Lobo, Augusto Cesar; Ribeiro, Rafael Antunes; Ribeiro, Clyffe de Assis; Dieguez, Pedro Ruas

    2012-01-01

    We present a simple and pedagogical derivation of the quantum adiabatic theorem for two-level systems (a single qubit) based on geometrical structures of quantum mechanics developed by Anandan and Aharonov, among others. We have chosen to use only the minimum geometric structure needed for the understanding of the adiabatic theorem for this case.…

  2. Adiabatic Quantum Computing

    Pinski, Sebastian D

    2011-01-01

    Adiabatic Quantum Computing (AQC) is a relatively new subject in the world of quantum computing, let alone Physics. Inspiration for this project has come from recent controversy around D-Wave Systems in British Columbia, Canada, who claim to have built a working AQC which is now commercially available and hope to be distributing a 1024 qubit chip by the end of 2008. Their 16 qubit chip was demonstrated online for the Supercomputing 2007 conference within which a few small problems were solved; although the explanations that journalists and critics received were minimal and very little was divulged in the question and answer session. This 'unconvincing' demonstration has caused physicists and computer scientists to hit back at D-Wave. The aim of this project is to give an introduction to the historic advances in classical and quantum computing and to explore the methods of AQC. Through numerical simulations an algorithm for the Max Independent Set problem is empirically obtained.

  3. Improving the positive feedback adiabatic logic familiy

    J. Fischer

    2004-01-01

    Full Text Available Positive Feedback Adiabatic Logic (PFAL shows the lowest energy dissipation among adiabatic logic families based on cross-coupled transistors, due to the reduction of both adiabatic and non-adiabatic losses. The dissipation primarily depends on the resistance of the charging path, which consists of a single p-channel MOSFET during the recovery phase. In this paper, a new logic family called Improved PFAL (IPFAL is proposed, where all n- and pchannel devices are swapped so that the charge can be recovered through an n-channel MOSFET. This allows to decrease the resistance of the charging path up to a factor of 2, and it enables a significant reduction of the energy dissipation. Simulations based on a 0.13µm CMOS process confirm the improvements in terms of power consumption over a large frequency range. However, the same simple design rule, which enables in PFAL an additional reduction of the dissipation by optimal transistor sizing, does not apply to IPFAL. Therefore, the influence of several sources of dissipation for a generic IPFAL gate is illustrated and discussed, in order to lower the power consumption and achieve better performance.

  4. The role of the State in land reform processes: the case of Brazil

    Elisa Botella Rodríguez

    2009-12-01

    Full Text Available El propósito de este artículo es estudiar el proceso de reforma agrarian en Latinoamérica y caracterizar el caso de Brasil, por esta razón voy a exponer una visión general del proceso y el rol de los gobiernos durante el siglo XX acorde al punto de vista de organizaciones internacionales como el Banco Mundial o el Banco Interamericano de Desarrollo. Como punto a añadir al objetivo de mi investigación está el explicar en términos generales y únicamente con un análisis teórico el proceso de reforma agraria y, por esta razón, me gustaría mostrar las mejores normas a fin de poner en práctica esta clase de política de acuerdo a la difícil situación del punto de salida. Finalmente, la presencia de Brasil será tomada para demostrar las importantes implicaciones de los movimientos sociales para llevar a cabo los procesos de reforma agraria.____________________ABSTRACT:The purpose of my article is to study land reform processes in Latin America and characterise the case of Brazil, for this reason I am going to expound a general vision of the process and the role of Governments during the 20th century according to the point of view of International Organizations like The World Bank or The Inter-American Development Bank. In addition the objective of my research is explaining in general terms and only with a theoretical analysis land reform processes and, for this reason, I would like to show the best norms in order to put in practise this kind of policy according to the difficult situation of the starting point. Finally the instance of Brazil will be undertaken to demonstrate the main implications of social movements in order to make land reform processes.

  5. Why infrastructure still matters: unravelling water reform processes in an uneven waterscape in rural Kenya

    Jeltsje Sanne Kemerink

    2016-08-01

    Full Text Available Since the 1980s, a major change took place in public policies for water resources management. Whereas before governments primarily invested in the development, operation and maintenance of water infrastructure and were mainly concerned with the distribution of water, in the new approach they mainly focus on managing water resources systems by stipulating general frameworks for water allocation. This paper studies the rationales used to justify the water reform process in Kenya and discusses how and to what extent these rationales apply to different groups of water users within Likii catchment in the central part of the country. Adopting a critical institutionalist's perspective, this paper shows how the water resource configurations in the catchment are constituted by the interplay between a normative policy model introduced in a plural institutional context and the disparate infrastructural options available to water users as result of historically produced uneven social relations. We argue that, to progressively redress the colonial legacy, direct investments in infrastructure for marginalized water users and targeting the actual (redistribution of water to the users might be more effective than focusing exclusively on institutional reforms.

  6. Nanowire Plasmon Excitation by Adiabatic Mode Transformation

    Verhagen, Ewold; Spasenović, Marko; Polman, Albert; Kuipers, L. (Kobus)

    2009-05-01

    We show with both experiment and calculation that highly confined surface plasmon polaritons can be efficiently excited on metallic nanowires through the process of mode transformation. One specific mode in a metallic waveguide is identified that adiabatically transforms to the confined nanowire mode as the waveguide width is reduced. Phase- and polarization-sensitive near-field investigation reveals the characteristic antisymmetric polarization nature of the mode and explains the coupling mechanism.

  7. Performance analysis of adiabatic engine

    Sudhakar, V.

    1984-01-01

    As the development of the adiabatic diesel engine continues with a goal of 65% reduction in net in-cylinder heat transfer over a cooled engine, several uncooled engines with intermediate levels of reduced heat transfer were studied. Some aspects and results of the adiabatic diesel engine cycle simulation are discussed. Performance test data and simulation results are compared for a conventionally cooled and uncooled Cummins NH-450 turbocompound engines. Exhaust emissions were also measured and compared.

  8. The Bologna Process as a Reform Initiative in Higher Education in the Balkan Countries: The Case of Romania

    Damian, Radu Mircea

    2011-01-01

    This paper describes the development of the Bologna process in Romania. The historical context covers the last years of the communist regime through 1989. From 1990 free elections of university leadership, the foundation of private universities and new democratic legislation, and projects for reforming higher education funded by different sources…

  9. Bringing Women into Computer Engineering: Curriculum Reform Processes at Two Institutes of Technology. Linkoping Studies in Education and Psychology Dissertations, No. 60.

    Salminen-Karlsson, Minna

    This study examined curricular reform processes at two Swedish institutes of technology through a gender perspective, relating them to two social theories the reproduction theory of Bourdieu and Passeron and the gender contract theory of Yvonne Hirdman. The aim of the reform process was to make educational programs in computer engineering more…

  10. A Solved Model to Show Insufficiency of Quantitative Adiabatic Condition

    LIU Long-Jiang; LIU Yu-Zhen; TONG Dian-Min

    2009-01-01

    The adiabatic theorem is a useful tool in processing quantum systems slowly evolving,but its practical application depends on the quantitative condition expressed by Hamiltonian's eigenvalues and eigenstates,which is usually taken as a sufficient condition.Recently,the sumciency of the condition was questioned,and several counterex amples have been reported.Here we present a new solved model to show the insufficiency of the traditional quantitative adiabatic condition.

  11. Efficient point cloud data processing in shipbuilding: Reformative component extraction method and registration method

    Jingyu Sun

    2014-07-01

    Full Text Available To survive in the current shipbuilding industry, it is of vital importance for shipyards to have the ship components’ accuracy evaluated efficiently during most of the manufacturing steps. Evaluating components’ accuracy by comparing each component’s point cloud data scanned by laser scanners and the ship’s design data formatted in CAD cannot be processed efficiently when (1 extract components from point cloud data include irregular obstacles endogenously, or when (2 registration of the two data sets have no clear direction setting. This paper presents reformative point cloud data processing methods to solve these problems. K-d tree construction of the point cloud data fastens a neighbor searching of each point. Region growing method performed on the neighbor points of the seed point extracts the continuous part of the component, while curved surface fitting and B-spline curved line fitting at the edge of the continuous part recognize the neighbor domains of the same component divided by obstacles’ shadows. The ICP (Iterative Closest Point algorithm conducts a registration of the two sets of data after the proper registration’s direction is decided by principal component analysis. By experiments conducted at the shipyard, 200 curved shell plates are extracted from the scanned point cloud data, and registrations are conducted between them and the designed CAD data using the proposed methods for an accuracy evaluation. Results show that the methods proposed in this paper support the accuracy evaluation targeted point cloud data processing efficiently in practice.

  12. Developing a Steady-state Kinetic Model for Industrial Scale Semi-Regenerative Catalytic Naphtha Reforming Process

    Seif Mohaddecy, R.

    2014-05-01

    Full Text Available Due to the demand for high octane gasoline as a transportation fuel, the catalytic naphtha reformer has become one of the most important processes in petroleum refineries. In this research, the steady-state modelling of a catalytic fixed-bed naphtha reforming process to predict the momentous output variables was studied. These variables were octane number, yield, hydrogen purity, and temperature of all reforming reactors. To do such a task, an industrial scale semi-regenerative catalytic naphtha reforming unit was studied and modelled. In addition, to evaluate the developed model, the predicted variables i.e. outlet temperatures of reactors, research octane number, yield of gasoline and hydrogen purity were compared against actual data. The results showed that there is a close mapping between the actual and predicted variables, and the mean relative absolute deviation of the mentioned process variables were 0.38 %, 0.52 %, 0.54 %, 0.32 %, 4.8 % and 3.2 %, respectively.

  13. Adiabatic shear bands localization in materials undergoing deformations

    Ryabov, P. N.; Kudryashov, N. A.; Muratov, R. V.

    2017-01-01

    We consider the adiabatic shear banding phenomenon in composite materials undergoing the high speed shear deformations. The mathematical model of adiabatic shear banding in thermo-visco-plastic material is given. New two step numerical algorithm which is based on the Courant-Isaacson-Rees scheme that allows one to simulate fully localized plastic flow from initial stage of localization is proposed. To test this numerical algorithm we use three benchmark problems. The testing results show the accuracy and efficiency of proposed algorithm. The features of adiabatic shear bands formation in composites are studied. The existence of characteristic depth of localization in composites is shown. Influence of initial temperature distribution on the processes of adiabatic shear bands formation in composites is considered.

  14. A Novel Slurry-Based Biomass Reforming Process Final Technical Report

    Emerson, Sean C. [United Technologies Research Center, East Hartford, CT (United States); Davis, Timothy D. [United Technologies Research Center, East Hartford, CT (United States); Peles, A. [United Technologies Research Center, East Hartford, CT (United States); She, Ying [United Technologies Research Center, East Hartford, CT (United States); Sheffel, Joshua [United Technologies Research Center, East Hartford, CT (United States); Willigan, Rhonda R. [United Technologies Research Center, East Hartford, CT (United States); Vanderspurt, Thomas H. [United Technologies Research Center, East Hartford, CT (United States); Zhu, Tianli [United Technologies Research Center, East Hartford, CT (United States)

    2011-09-30

    This project was focused on developing a catalytic means of producing H2 from raw, ground biomass, such as fast growing poplar trees, willow trees, or switch grass. The use of a renewable, biomass feedstock with minimal processing can enable a carbon neutral means of producing H2 in that the carbon dioxide produced from the process can be used in the environment to produce additional biomass. For economically viable production of H2, the biomass is hydrolyzed and then reformed without any additional purification steps. Any unreacted biomass and other byproduct streams are burned to provide process energy. Thus, the development of a catalyst that can operate in the demanding corrosive environment and presence of potential poisons is vital to this approach. The concept for this project is shown in Figure 1. The initial feed is assumed to be a >5 wt% slurry of ground wood in dilute base, such as potassium carbonate (K2CO3). Base hydrolysis and reforming of the wood is carried out at high but sub-critical pressures and temperatures in the presence of a solid catalyst. A Pd alloy membrane allows the continuous removal of pure , while the retentate, including methane is used as fuel in the plant. The project showed that it is possible to economically produce H2 from woody biomass in a carbon neutral manner. Technoeconomic analyses using HYSYS and the DOE's H2A tool [1] were used to design a 2000 ton day-1 (dry basis) biomass to hydrogen plant with an efficiency of 46% to 56%, depending on the mode of operation and economic assumptions, exceeding the DOE 2012 target of 43%. The cost of producing the hydrogen from such a plant would be in the range of $1/kg H2 to $2/kg H2. By using raw biomass as a feedstock, the cost of producing hydrogen at large biomass consumption rates is more cost effective than steam reforming of hydrocarbons or biomass gasification and can achieve the overall cost goals of the DOE Fuel Cell Technologies Program. The complete conversion of wood

  15. A Novel Slurry-Based Biomass Reforming Process Final Technical Report

    Emerson, Sean C. [United Technologies Research Center, East Hartford, CT (United States); Davis, Timothy D. [United Technologies Research Center, East Hartford, CT (United States); Peles, A. [United Technologies Research Center, East Hartford, CT (United States); She, Ying [United Technologies Research Center, East Hartford, CT (United States); Sheffel, Joshua [United Technologies Research Center, East Hartford, CT (United States); Willigan, Rhonda R. [United Technologies Research Center, East Hartford, CT (United States); Vanderspurt, Thomas H. [United Technologies Research Center, East Hartford, CT (United States); Zhu, Tianli [United Technologies Research Center, East Hartford, CT (United States)

    2011-09-30

    This project was focused on developing a catalytic means of producing H2 from raw, ground biomass, such as fast growing poplar trees, willow trees, or switch grass. The use of a renewable, biomass feedstock with minimal processing can enable a carbon neutral means of producing H2 in that the carbon dioxide produced from the process can be used in the environment to produce additional biomass. For economically viable production of H2, the biomass is hydrolyzed and then reformed without any additional purification steps. Any unreacted biomass and other byproduct streams are burned to provide process energy. Thus, the development of a catalyst that can operate in the demanding corrosive environment and presence of potential poisons is vital to this approach. The concept for this project is shown in Figure 1. The initial feed is assumed to be a >5 wt% slurry of ground wood in dilute base, such as potassium carbonate (K2CO3). Base hydrolysis and reforming of the wood is carried out at high but sub-critical pressures and temperatures in the presence of a solid catalyst. A Pd alloy membrane allows the continuous removal of pure , while the retentate, including methane is used as fuel in the plant. The project showed that it is possible to economically produce H2 from woody biomass in a carbon neutral manner. Technoeconomic analyses using HYSYS and the DOE's H2A tool [1] were used to design a 2000 ton day-1 (dry basis) biomass to hydrogen plant with an efficiency of 46% to 56%, depending on the mode of operation and economic assumptions, exceeding the DOE 2012 target of 43%. The cost of producing the hydrogen from such a plant would be in the range of $1/kg H2 to $2/kg H2. By using raw biomass as a feedstock, the cost of producing hydrogen at large biomass consumption rates is more cost effective than steam reforming of hydrocarbons or biomass gasification and can achieve the overall cost goals of the DOE Fuel Cell Technologies Program. The complete conversion of wood

  16. Processing real-world waste plastics by pyrolysis-reforming for hydrogen and high-value carbon nanotubes.

    Wu, Chunfei; Nahil, Mohamad A; Miskolczi, Norbert; Huang, Jun; Williams, Paul T

    2014-01-01

    Producing both hydrogen and high-value carbon nanotubes (CNTs) derived from waste plastics is reported here using a pyrolysis-reforming technology comprising a two-stage reaction system, in the presence of steam and a Ni-Mn-Al catalyst. The waste plastics consisted of plastics from a motor oil container (MOC), commercial waste high density polyethylene (HDPE) and regranulated HDPE waste containing polyvinyl chloride (PVC). The results show that hydrogen can be produced from the pyrolysis-reforming process, but also carbon nanotubes are formed on the catalyst. However, the content of 0.3 wt.% polyvinyl chloride in the waste HDPE (HDPE/PVC) has been shown to poison the catalyst and significantly reduce the quantity and purity of CNTs. The presence of sulfur has shown less influence on the production of CNTs in terms of quantity and CNT morphologies. Around 94.4 mmol H2 g(-1) plastic was obtained for the pyrolysis-reforming of HDPE waste in the presence of the Ni-Mn-Al catalyst and steam at a reforming temperature of 800 °C. The addition of steam in the process results in an increase of hydrogen production and reduction of carbon yield; in addition, the defects of CNTs, for example, edge dislocations were found to be increased with the introduction of steam (from Raman analysis).

  17. Non-adiabatic primordial fluctuations

    Noller, Johannes; Magueijo, Joao, E-mail: johannes.noller08@imperial.ac.uk [Theoretical Physics Group, Imperial College, London SW7 2BZ (United Kingdom)

    2011-05-21

    We consider general mixtures of isocurvature and adiabatic cosmological perturbations. With a minimal assumption set consisting of the linearized Einstein equations and a primordial perfect fluid we derive the second-order action and its curvature variables. We also allow for varying equation of state and speed of sound profiles. The derivation is therefore carried out at the same level of generality that has been achieved for adiabatic modes before. As a result we find a new conserved super-horizon quantity and relate it to the adiabatically conserved curvature perturbation. Finally we demonstrate how the formalism can be applied by considering a Chaplygin gas-like primordial matter model, finding two scale-invariant solutions for structure formation.

  18. Telecom Reform

    and information infrastructure issues - for people in government, academia, industry and the consulting community. This book addresses the process of policy and regulatory reform in telecom that is now in its formative stage. It draws on detailed knowledge of industry development and regulatory experience...

  19. 氯苯连续绝热硝化合成硝基氯苯过程设计%Process design for production of nitrochlorobenzene by continuous adiabatic nitration of chlorobenzene

    许文林; 王雅琼; 张小兴

    2012-01-01

    依据氯苯绝热硝化反应合成硝基氯苯工艺过程的特点和中试试验结果,对5万t/a硝基氯苯生产过程中,氯苯连续绝热硝化反应合成硝基氯苯过程进行了设计.该过程主要由SV-5/100型18m长静态混合硝化反应器、耐腐高压泵、涡轮流量计、氯苯槽、混酸槽等组成.该工艺过程具有反应速率高、过程安全可靠、物料及能量的利用效率高、三废量少、操作费用低、产品质量稳定等优点.%A process design for the production of SO kt/a nitrochlorobenzene by continuous adiabatic nitration of chlorobenzene with mixed acid was presented according to the characteristics of the reaction and the pilot-scale experimental results. The production process is mainly consist of a SV-5/100 type static mixer with a length of 18 m as a continuous adiabatic nitration reactor, a corrosion resistance high-pressure pump, a turbine flow-meter, a chlorobenzene tank and a mixed acid tank, etc. The developed technology is featured by high reaction efficiency, safe and reliable nitrification process, high efficiency of the utilization of material and energy, less effluents produced, low operation cost, and high quality of the product.

  20. Adiabatic theory for the bipolaron

    Lakhno, V.D. (Institute of Mathematical Problems of Biology, Russian Academy of Sciences, Pushchino Moscow Region, 142292 (Russian Federation))

    1995-02-01

    A translation-invariant adiabatic theory is constructed for the bipolaron. It is shown that motions in the bipolaron are divided: the relative electron coordinates describe fast electron oscillations in the induced polarization well and the center of mass coordinates represent slow electron movement followed by polarization. Nonlinear differential bipolaron equations are derived which are asymptotically exact in the adiabatic limit. Particlelike solutions of these equations correspond to the bipolaron bound state. The exact solution yields the value of the ion critical parameter [eta]=0.31 for which the bipolaron state is stable, where [eta]=[epsilon][sub [infinity

  1. Analysis of Adiabatic Batch Reactor

    Erald Gjonaj

    2016-05-01

    Full Text Available A mixture of acetic anhydride is reacted with excess water in an adiabatic batch reactor to form an exothermic reaction. The concentration of acetic anhydride and the temperature inside the adiabatic batch reactor are calculated with an initial temperature of 20°C, an initial temperature of 30°C, and with a cooling jacket maintaining the temperature at a constant of 20°C. The graphs of the three different scenarios show that the highest temperatures will cause the reaction to occur faster.

  2. The Danish Regulatory Reform of Telecommunications

    Skouby, Knud Erik

    1998-01-01

    An overview of the liberalisation process and regulatory reform of telecommunications in Denmark......An overview of the liberalisation process and regulatory reform of telecommunications in Denmark...

  3. Elementary examples of adiabatic invariance

    Crawford, F.S. (Physics Department, University of California, Berkeley, CA (USA) Lawrence Berkeley Laboratory, University of California, Berkeley, CA 94720 (USA))

    1990-04-01

    Simple classical one-dimensional systems subject to adiabatic (gradual) perturbations are examined. The first examples are well known: the adiabatic invariance of the product {ital E}{tau} of energy {ital E} and period {tau} for the simple pendulum and for the simple harmonic oscillator. Next, the adiabatic invariants of the vertical bouncer are found---a ball bouncing elastically from the floor of a rising elevator having slowly varying velocity and acceleration. These examples lead to consideration of adiabatic invariance for one-dimensional systems with potentials of the form {ital V}={ital ax}{sup {ital n}}, with {ital a}={ital a}({ital t}) slowly varying in time. Then, the horizontal bouncer is considered---a mass sliding on a smooth floor, bouncing back and forth between two impenetrable walls, one of which is slowly moving. This example is generalized to a particle in a bound state of a general potential with one slowly moving turning point.'' Finally, circular motion of a charged particle in a magnetic field slowly varying in time under three different configurations is considered: (a) a free particle in a uniform field; (b) a free particle in a nonuniform betatron'' field; and (c) a particle constrained to a circular orbit in a uniform field.

  4. A Many Particle Adiabatic Invariant

    Hjorth, Poul G.

    1999-01-01

    For a system of N charged particles moving in a homogeneous, sufficiently strong magnetic field, a many-particle adiabatic invariant constrains the collisional exchange of energy between the degrees of freedom perpendicular to and parallel to the magnetic field. A description of the phenomenon...

  5. Digital Waveguide Adiabatic Passage Part 1: Theory

    Vaitkus, Jesse A; Greentree, Andrew D

    2016-01-01

    Spatial adiabatic passage represents a new way to design integrated photonic devices. In conventional adiabatic passage designs require smoothly varying waveguide separations. Here we show modelling of adiabatic passage devices where the waveguide separation is varied digitally. Despite digitisation, our designs show robustness against variations in the input wavelength and refractive index contrast of the waveguides relative to the cladding. This approach to spatial adiabatic passage opens new design strategies and hence the potential for new photonics devices.

  6. On adiabatic perturbations in the ekpyrotic scenario

    Linde, A.; Mukhanov, V.; Vikman, A.

    2010-02-01

    In a recent paper, Khoury and Steinhardt proposed a way to generate adiabatic cosmological perturbations with a nearly flat spectrum in a contracting Universe. To produce these perturbations they used a regime in which the equation of state exponentially rapidly changed during a short time interval. Leaving aside the singularity problem and the difficult question about the possibility to transmit these perturbations from a contracting Universe to the expanding phase, we will show that the methods used in Khoury are inapplicable for the description of the cosmological evolution and of the process of generation of perturbations in this scenario.

  7. On adiabatic perturbations in the ekpyrotic scenario

    Linde, A; Vikman, A

    2009-01-01

    In a recent paper arXiv:0910.2230, Khoury and Steinhardt proposed a way to generate adiabatic cosmological perturbations with a nearly flat spectrum in a contracting Universe. To produce these perturbations they used a regime in which the equation of state exponentially rapidly changed during a short time interval. Leaving aside the singularity problem and the difficult question about the possibility to transmit these perturbations from a contracting Universe to the expanding phase, we will show that the methods used in arXiv:0910.2230 are inapplicable for the description of the cosmological evolution and of the process of generation of perturbations in this scenario.

  8. Shortcuts to Adiabaticity by Counterdiabatic Driving in Trapped-ion Transport

    An, Shuoming; del Campo, Adolfo; Kim, Kihwan

    2016-01-01

    Adiabatic dynamics plays an essential role in quantum technologies. By driving a quantum system slowly, the quantum evolution can be engineered with suppressed excitation. Yet, environmentally-induced decoherence limits the implementation of adiabatic protocols. Shortcuts to adiabaticity (STA) have the potential to revolutionize quantum technologies by speeding up the time evolution while mimicking adiabatic dynamics. These nonadiabatic protocols can be engineered by means an auxiliary control field is used to tailor excitations. Here we present the first experimental realization of counterdiabatic driving in a continuous variable system, implementing a shortcut to the adiabatic transport of a trapped ion, in which nonadiabatic transitions are suppressed during all stages of the process. The resulting dynamics is equivalent to a "fast-motion video" of the adiabatic trajectory. We experimentally demonstrate the enhanced robustness of the protocol with respect to alternative approaches based on classical local ...

  9. Efficient utilization of greenhouse gases in a gas-to-liquids process combined with CO2/steam-mixed reforming and Fe-based Fischer-Tropsch synthesis.

    Zhang, Chundong; Jun, Ki-Won; Ha, Kyoung-Su; Lee, Yun-Jo; Kang, Seok Chang

    2014-07-15

    Two process models for carbon dioxide utilized gas-to-liquids (GTL) process (CUGP) mainly producing light olefins and Fischer-Tropsch (F-T) synthetic oils were developed by Aspen Plus software. Both models are mainly composed of a reforming unit, an F-T synthesis unit and a recycle unit, while the main difference is the feeding point of fresh CO2. In the reforming unit, CO2 reforming and steam reforming of methane are combined together to produce syngas in flexible composition. Meanwhile, CO2 hydrogenation is conducted via reverse water gas shift on the Fe-based catalysts in the F-T synthesis unit to produce hydrocarbons. After F-T synthesis, the unreacted syngas is recycled to F-T synthesis and reforming units to enhance process efficiency. From the simulation results, it was found that the carbon efficiencies of both CUGP options were successfully improved, and total CO2 emissions were significantly reduced, compared with the conventional GTL processes. The process efficiency was sensitive to recycle ratio and more recycle seemed to be beneficial for improving process efficiency and reducing CO2 emission. However, the process efficiency was rather insensitive to split ratio (recycle to reforming unit/total recycle), and the optimum split ratio was determined to be zero.

  10. Design Thinking: A Process for Developing and Implementing Lasting District Reform. Knowledge Brief

    Rice, Erik

    2011-01-01

    Traditionally, challenges such as how to sustain district reform, how to build a leadership pipeline, how to create an integrated project, or how to best intervene with struggling students would be resolved with a team of "experts" developing a solution in isolation of the stakeholders involved. By contrast, design thinking centers on the…

  11. Bond selective chemistry beyond the adiabatic approximation

    Butler, L.J. [Univ. of Chicago, IL (United States)

    1993-12-01

    One of the most important challenges in chemistry is to develop predictive ability for the branching between energetically allowed chemical reaction pathways. Such predictive capability, coupled with a fundamental understanding of the important molecular interactions, is essential to the development and utilization of new fuels and the design of efficient combustion processes. Existing transition state and exact quantum theories successfully predict the branching between available product channels for systems in which each reaction coordinate can be adequately described by different paths along a single adiabatic potential energy surface. In particular, unimolecular dissociation following thermal, infrared multiphoton, or overtone excitation in the ground state yields a branching between energetically allowed product channels which can be successfully predicted by the application of statistical theories, i.e. the weakest bond breaks. (The predictions are particularly good for competing reactions in which when there is no saddle point along the reaction coordinates, as in simple bond fission reactions.) The predicted lack of bond selectivity results from the assumption of rapid internal vibrational energy redistribution and the implicit use of a single adiabatic Born-Oppenheimer potential energy surface for the reaction. However, the adiabatic approximation is not valid for the reaction of a wide variety of energetic materials and organic fuels; coupling between the electronic states of the reacting species play a a key role in determining the selectivity of the chemical reactions induced. The work described below investigated the central role played by coupling between electronic states in polyatomic molecules in determining the selective branching between energetically allowed fragmentation pathways in two key systems.

  12. Efficient hydrogen production from ethanol and glycerol by vapour-phase reforming processes with new cobalt-based catalysts.

    Pereira, Evandro Brum; de la Piscina, Pilar Ramírez; Homs, Narcís

    2011-02-01

    The aim of this study was to investigate biohydrogen production from biofuel-reforming processes using new multi-component bulk-type cobalt-based catalysts. The addition of different components to improve the catalytic performance was studied. Monometallic cobalt catalyst and catalysts containing Ru (ca. 1%) and/or Na (ca. 0.5%) were characterized and tested in the 623-673 K temperature range in ethanol steam reforming (ESR) with a steam/carbon ratio (S/C) of 3. The catalysts showed a high performance for hydrogen production and, except for H(2) and CO(2), only small amounts of by-products were obtained, depending on the temperature and the catalyst used. The catalyst containing both Ru and Na (Co-Ru(Na)) showed the best catalytic behavior in ESR. It operated stably for at least 12 days under cycles of oxidative steam reforming of glycerol/ethanol mixtures (S/C=2) and activation under O(2).

  13. Non-catalytic recuperative reformer

    Khinkis, Mark J.; Kozlov, Aleksandr P.; Kurek, Harry

    2015-12-22

    A non-catalytic recuperative reformer has a flue gas flow path for conducting hot flue gas from a thermal process and a reforming mixture flow path for conducting a reforming mixture. At least a portion of the reforming mixture flow path is embedded in the flue gas flow path to permit heat transfer from the hot flue gas to the reforming mixture. The reforming mixture flow path contains substantially no material commonly used as a catalyst for reforming hydrocarbon fuel (e.g., nickel oxide, platinum group elements or rhenium), but instead the reforming mixture is reformed into a higher calorific fuel via reactions due to the heat transfer and residence time. In a preferred embodiment, extended surfaces of metal material such as stainless steel or metal alloy that are high in nickel content are included within at least a portion of the reforming mixture flow path.

  14. Invalidity of the quantitative adiabatic condition and general conditions for adiabatic approximations

    Li, Dafa

    2016-05-01

    The adiabatic theorem was proposed about 90 years ago and has played an important role in quantum physics. The quantitative adiabatic condition constructed from eigenstates and eigenvalues of a Hamiltonian is a traditional tool to estimate adiabaticity and has proven to be the necessary and sufficient condition for adiabaticity. However, recently the condition has become a controversial subject. In this paper, we list some expressions to estimate the validity of the adiabatic approximation. We show that the quantitative adiabatic condition is invalid for the adiabatic approximation via the Euclidean distance between the adiabatic state and the evolution state. Furthermore, we deduce general necessary and sufficient conditions for the validity of the adiabatic approximation by different definitions.

  15. The Transference of Gender-based Norms in the Law Reform Process: A Reflection on my Work in Thailand

    Y-Vonne Hutchinson

    2013-04-01

    Full Text Available In 2008, I spent a year as a Rule of Law specialist in Thailand with the International Rescue Committee (IRC, as part of a fellowship program for human rights lawyers. I was assigned the task of facilitating the development of a comprehensive legal code for the refugee camps along the border between Thailand and /Burma. As part of my work, I also sought to increase gender-based protection under the law through the incorporation of Thai and international human rights norms. This paper is a reflection on the processes that occurred during my time at IRC. The reform project approached the transference of contentious international norms for protection of women and girls in two ways: a through the inclusive design of the law reform process and b the establishment of a prohibition on rules that clearly violated international or national law. By forming a representative drafting committee and placing an emphasis on community consultation as a precursor to code finalisation, refugee perspectives, particularly female perspectives, were given scope to inform interpretations of national and international legal standards. By requiring international and national legal compliance and placing an emphasis on explanation and clarification of international and national standards in discussions, the project supported downward transference of international norms to a specific community context. We hoped that, as a product of these two normative flows, the resulting legal code would be a sustainable mechanism for gender-based protection and redress in cases of sexual and gender-based violence. During negotiations, it became evident that the inclusive design of the law reform process had a more positive impact on the success of norms transference than the actual substance of the norm. The norms that were most readily accepted were those introduced by law reform committee members themselves. Local norm translators played a pivotal role in the norms diffusion process

  16. Performance and economic assessments of a solid oxide fuel cell system with a two-step ethanol-steam-reforming process using CaO sorbent

    Tippawan, Phanicha; Arpornwichanop, Amornchai

    2016-02-01

    The hydrogen production process is known to be important to a fuel cell system. In this study, a carbon-free hydrogen production process is proposed by using a two-step ethanol-steam-reforming procedure, which consists of ethanol dehydrogenation and steam reforming, as a fuel processor in the solid oxide fuel cell (SOFC) system. An addition of CaO in the reformer for CO2 capture is also considered to enhance the hydrogen production. The performance of the SOFC system is analyzed under thermally self-sufficient conditions in terms of the technical and economic aspects. The simulation results show that the two-step reforming process can be run in the operating window without carbon formation. The addition of CaO in the steam reformer, which runs at a steam-to-ethanol ratio of 5, temperature of 900 K and atmospheric pressure, minimizes the presence of CO2; 93% CO2 is removed from the steam-reforming environment. This factor causes an increase in the SOFC power density of 6.62%. Although the economic analysis shows that the proposed fuel processor provides a higher capital cost, it offers a reducing active area of the SOFC stack and the most favorable process economics in term of net cost saving.

  17. Analysis and Simulation of Adiabatic Bend Transitions in Optical Fibers

    YAO Lei; LOU Shu-Qin; JIAN Shui-Sheng

    2009-01-01

    A low-loss criterion for bend transitions in optical fibers is proposed. An optical fiber can be tightly bent with low loss to be adiabatic for the fundamental mode, provided that an approximate upper bound on the rate of change of bend curvature for a given bend curvature is satisfied. Two typical adiabatic bend transition paths, the optimum profile and linear profile, are analyzed and studied numerically. A realizable adiabatic transition with an Archimedean spiral profile is introduced for low bend loss in tightly bent optical fibers. Design of the transitions is based on modeling of the propagation and coupling characteristics of the core and cladding modes,which clearly illustrate the physical processes involved.

  18. Pt-Re-Sn/Al{sub 2}O{sub 3} trimetallic catalysts for naphtha reforming processes without presulfiding step

    Mazzieri, V.A.; Grau, J.M.; Vera, C.R.; Yori, J.C.; Parera, J.M.; Pieck, C.L. [Instituto de Investigaciones en Catalisis y Petroquimica, INCAPE, FIQ-UNL, CONICET, Santiago del Estero 2654, 3000 Santa Fe (Argentina)

    2005-12-12

    The n-heptane reforming and the cyclopentane hydrogenolysis reactions over noble metal monometallic catalysts (0.3% Pt), bimetallic catalysts (0.3% Pt, x% Re, x=0.1, 0.3, 0.9 and 2.0, sulfided) and trimetallic catalysts (0.3% Pt, 0.3% Re, y% Sn, y=0.1, 0.3, 0.6 and 0.9, unsulfided) were studied. The metal function was supported over a chlorided {gamma}-alumina that provided the acid function. The reforming of n-heptane was performed at 450{sup o}C, molar ratio H{sub 2}/n-C{sub 7}=4 and WHSV=7.3 while the hydrogenolysis of cyclopentane was performed at 350{sup o}C, H{sub 2}/CP=20 and WHSV=2.4. The sulfided 0.3Pt-0.3Re catalyst (with 0.06% S) was found to be the best performing bimetallic one. It had a great stability, typical of this kind of catalysts, and also produced a reformate with a high iso-heptanes/toluene ratio. This is advantageous for fulfilling the current environmental regulations that limit the amount of aromatic hydrocarbons in reformulated gasolines. The best trimetallic catalyst was 0.3Pt-0.3Re-0.6Sn which had a similar activity and selectivity as sulfided 0.3Pt-0.3Re, though it displayed a higher stability and a lower hydrogenolysis activity, without the need of presulfidation. Tin affected the metal and acid functions of the catalyst simultaneously and inhibited them to such different degrees that a very convenient metal/acid activity ratio was obtained, resulting in an improvement of the activity, selectivity and stability of the catalysts. It can be concluded that it is possible to prepare trimetallic naphtha reforming catalysts of the Pt-Re-Sn kind with a better performance than conventional sulfided Pt-Re catalysts and with the additional advantage that they do not need complicated sulfiding pretreatments. This simplifies the commercial operation of the reformer unit and enables the application of this catalyst to continuously operated processes.

  19. A Kinetic Study of the Adiabatic Polymerization of Acrylamide.

    Thomson, R. A. M.

    1986-01-01

    Discusses theory, procedures, and results for an experiment which demonstrates the application of basic physics to chemical problems. The experiment involves the adiabatic process, in which polymerization carried out in a vacuum flask is compared to the theoretical prediction of the model with the temperature-time curve obtained in practice. (JN)

  20. Fast Quasi-Adiabatic Gas Cooling: An Experiment Revisited

    Oss, S.; Gratton, L. M.; Calza, G.; Lopez-Arias, T.

    2012-01-01

    The well-known experiment of the rapid expansion and cooling of the air contained in a bottle is performed with a rapidly responsive, yet very cheap thermometer. The adiabatic, low temperature limit is approached quite closely and measured with our apparatus. A straightforward theoretical model for this process is also presented and discussed.…

  1. Sliding seal materials for adiabatic engines

    Lankford, J.

    1985-01-01

    The sliding friction coefficients and wear rates of promising carbide, oxide, and nitride materials were measured under temperature, environmental, velocity, loading conditions that are representative of the adiabatic engine environment. In order to provide guidance needed to improve materials for this application, the program stressed fundamental understanding of the mechanisms involved in friction and wear. Microhardness tests were performed on the candidate materials at elevated temperatures, and in atmospheres relevant to the piston seal application, and optical and electron microscopy were used to elucidate the micromechanisms of wear following wear testing. X-ray spectroscopy was used to evaluate interface/environment interactions which seemed to be important in the friction and wear process. Electrical effects in the friction and wear processes were explored in order to evaluate the potential usefulness of such effects in modifying the friction and wear rates in service. However, this factor was found to be of negligible significance in controlling friction and wear.

  2. Adiabatic Wankel type rotary engine

    Kamo, R.; Badgley, P.; Doup, D.

    1988-01-01

    This SBIR Phase program accomplished the objective of advancing the technology of the Wankel type rotary engine for aircraft applications through the use of adiabatic engine technology. Based on the results of this program, technology is in place to provide a rotor and side and intermediate housings with thermal barrier coatings. A detailed cycle analysis of the NASA 1007R Direct Injection Stratified Charge (DISC) rotary engine was performed which concluded that applying thermal barrier coatings to the rotor should be successful and that it was unlikely that the rotor housing could be successfully run with thermal barrier coatings as the thermal stresses were extensive.

  3. Theory of Adiabatic Fountain Resonance

    Williams, Gary A.

    2017-01-01

    The theory of "Adiabatic Fountain Resonance" with superfluid ^4{He} is clarified. In this geometry a film region between two silicon wafers bonded at their outer edge opens up to a central region with a free surface. We find that the resonance in this system is not a Helmholtz resonance as claimed by Gasparini et al., but in fact is a fourth sound resonance. We postulate that it occurs at relatively low frequency because the thin silicon wafers flex appreciably from the pressure oscillations of the sound wave.

  4. Second Law Violation By Magneto-Caloric Effect Adiabatic Phase Transition of Type I Superconductive Particles

    Peter Keefe

    2004-03-01

    Full Text Available Abstract: The nature of the thermodynamic behavior of Type I superconductor particles, having a cross section less than the Ginzburg-Landau temperature dependent coherence length is discussed for magnetic field induced adiabatic phase transitions from the superconductive state to the normal state. Argument is advanced supporting the view that when the adiabatic magneto-caloric process is applied to particles, the phase transition is characterized by a decrease in entropy in violation of traditional formulations of the Second Law, evidenced by attainment of a final process temperature below that which would result from an adiabatic magneto-caloric process applied to bulk dimensioned specimens.

  5. Adiabatic scaling relations of galaxy clusters

    Ascasibar, Y; Yepes, G; Müller, V; Gottlöber, S

    2006-01-01

    The aim of the present work is to show that, contrary to popular belief, galaxy clusters are **not** expected to be self-similar, even when the only energy sources available are gravity and shock-wave heating. In particular, we investigate the scaling relations between mass, luminosity and temperature of galaxy groups and clusters in the absence of radiative processes. Theoretical expectations are derived from a polytropic model of the intracluster medium and compared with the results of high-resolution adiabatic gasdynamical simulations. It is shown that, in addition to the well-known relation between the mass and concentration of the dark matter halo, the effective polytropic index of the gas also varies systematically with cluster mass, and therefore neither the dark matter nor the gas profiles are exactly self-similar. It is remarkable, though, that the effects of concentration and polytropic index tend to cancel each other, leading to scaling relations whose logarithmic slopes roughly match the predictio...

  6. Property rights and water markets in Australia: An evolutionary process toward institutional reform

    Pigram, John J.

    1993-04-01

    In the past decade far-reaching reforms have taken place in the Australian water industry. Extensive restructuring of water administration has been accompanied by increased evidence of willingness by public agencies to consider alternative institutional arrangements to the traditional regulatory approach to water allocation and use. In irrigated agriculture, a market-based system linked to enforceable property rights to water is seen as preferable to rule-based management of water resources. However, significant social and economic considerations and political realities constrain the unfettered operation of water markets. The challenge facing the irrigation industry in Australia is to put in place institutional arrangements which reflect the most appropriate mix of incentive-based and regulatory mechanisms for water management.

  7. Modeling the kinetics of methane conversion in steam reforming process of coke-oven gas based on experimental data

    ZHANG Jia-yuan; ZHOU Jie-min

    2007-01-01

    Steam-reforming is an effective approach for upgrading methane and hydrocarbon of coke-oven gas into CO and H2, but the kinetic behavior needs more study. We investigated the conversion of methane in coke-oven gas by steam reforming process in an electric tubular flow at 14 kPa with temperature varying from 500℃ to 950℃, and developed a kenetic model for , ignoring the effects of adsorption and diffusion. The optimal dynamic conditions for methane conversion 14 kPa are as follows: the ratio of the amount of water to the amount of methane is from 1.1 to 1.3; the reaction temperature is from 1 223 K to 1 273 K. The methane conversion rate is larger than 95% when the ratio of the amount of water to the amount of methane is 1.2 at a temperature above 1 223 K with the residence time up to 0.75 s.

  8. Cummins/Tacom advanced adiabatic engine

    Kamo, R.; Bryzik, W.

    1984-01-01

    Cummins Engine Company, Inc. and the U.S. Army have been jointly developing an adiabatic turbocompound engine during the last nine years. Although progress in the early years was slow, recent developments in the field of advanced ceramics have made it possible to make steady progress. It is now possible to reconsider the temperature limitation imposed on current heat engines and its subsequent influence on higher engine efficiency when using an exhaust energy utilization system. This paper presents an adiabatic turbocompound diesel engine concept in which high-performance ceramics are used in its design. The adiabatic turbocompound engine will enable higher operating temperatures, reduced heat loss, and higher exhaust energy recovery, resulting in higher thermal engine efficiency. This paper indicates that the careful selection of ceramics in engine design is essential. Adiabatic engine materials requirements are defined and the possible ceramic materials which will satisfy these requirements are identified. Examples in design considerations of engine components are illustrated. In addition to these important points, the use of ceramic coatings in the design of engine components. The first generation adiabatic engine with ceramic coatings is described. The advanced adiabatic engine with minimum friction features utilizaing ceramics is also presented. The advanced ceramic turbocharger turbine rotor as well as the oilless ceramic bearing design is described. Finally, the current status of the advanced adiabatic engine program culminating in the AA750 V-8 adiabatic engine is presented.

  9. (Hybrid) Baryons Quantum Numbers and Adiabatic Potentials

    Page, P R

    1999-01-01

    We construct (hybrid) baryons in the flux-tube model of Isgur and Paton. In the limit of adiabatic quark motion, we build proper eigenstates of orbital angular momentum and indicate the flavour, spin, chirality and J^P of (hybrid) baryons. The adiabatic potential is calculated as a function of the quark positions.

  10. Quantum Computation by Adiabatic Evolution

    Farhi, E; Gutmann, S; Sipser, M; Farhi, Edward; Goldstone, Jeffrey; Gutmann, Sam; Sipser, Michael

    2000-01-01

    We give a quantum algorithm for solving instances of the satisfiability problem, based on adiabatic evolution. The evolution of the quantum state is governed by a time-dependent Hamiltonian that interpolates between an initial Hamiltonian, whose ground state is easy to construct, and a final Hamiltonian, whose ground state encodes the satisfying assignment. To ensure that the system evolves to the desired final ground state, the evolution time must be big enough. The time required depends on the minimum energy difference between the two lowest states of the interpolating Hamiltonian. We are unable to estimate this gap in general. We give some special symmetric cases of the satisfiability problem where the symmetry allows us to estimate the gap and we show that, in these cases, our algorithm runs in polynomial time.

  11. On a Nonlinear Model in Adiabatic Evolutions

    Sun, Jie; Lu, Song-Feng

    2016-08-01

    In this paper, we study a kind of nonlinear model of adiabatic evolution in quantum search problem. As will be seen here, for this problem, there always exists a possibility that this nonlinear model can successfully solve the problem, while the linear model can not. Also in the same setting, when the overlap between the initial state and the final stare is sufficiently large, a simple linear adiabatic evolution can achieve O(1) time efficiency, but infinite time complexity for the nonlinear model of adiabatic evolution is needed. This tells us, it is not always a wise choice to use nonlinear interpolations in adiabatic algorithms. Sometimes, simple linear adiabatic evolutions may be sufficient for using. Supported by the National Natural Science Foundation of China under Grant Nos. 61402188 and 61173050. The first author also gratefully acknowledges the support from the China Postdoctoral Science Foundation under Grant No. 2014M552041

  12. Time-resolved photoelectron spectroscopy of non-adiabatic dynamics in polyatomic molecules

    Stolow, Albert

    2015-01-01

    This review article discusses advances in the use of time-resolved photoelectron spectroscopy for the study of non-adiabatic processes in molecules. A theoretical treatment of the experiments is presented together with a number of experimental examples.

  13. Partial evolution based local adiabatic quantum search

    Sun Jie; Lu Song-Feng; Liu Fang; Yang Li-Ping

    2012-01-01

    Recently,Zhang and Lu provided a quantum search algorithm based on partial adiabatic evolution,which beats the time bound of local adiabatic search when the number of marked items in the unsorted database is larger than one.Later,they found that the above two adiabatic search algorithms had the same time complexity when there is only one marked item in the database.In the present paper,following the idea of Roland and Cerf [Roland J and Cerf N J 2002Phys.Rev.A 65 042308],if within the small symmetric evolution interval defined by Zhang et al.,a local adiabatic evolution is performed instead of the original “global” one,this “new” algorithm exhibits slightly better performance,although they are progressively equivalent with M increasing.In addition,the proof of the optimality for this partial evolution based local adiabatic search when M =1 is also presented.Two other special cases of the adiabatic algorithm obtained by appropriately tuning the evolution interval of partial adiabatic evolution based quantum search,which are found to have the same phenomenon above,are also discussed.

  14. Adiabatic theorems for generators of contracting evolutions

    Avron, J E; Graf, G M; Grech, P

    2011-01-01

    We develop an adiabatic theory for generators of contracting evolution on Banach spaces. This provides a uniform framework for a host of adiabatic theorems ranging from unitary quantum evolutions through quantum evolutions of open systems generated by Lindbladians all the way to classically driven stochastic systems. In all these cases the adiabatic evolution approximates, to lowest order, the natural notion of parallel transport in the manifold of instantaneous stationary states. The dynamics in the manifold of instantaneous stationary states and transversal to it have distinct characteristics: The former is irreversible and the latter is transient in a sense that we explain. Both the gapped and gapless cases are considered. Some applications are discussed.

  15. Digital Waveguide Adiabatic Passage Part 2: Experiment

    Ng, Vincent; Chaboyer, Zachary J; Nguyen, Thach; Dawes, Judith M; Withford, Michael J; Greentree, Andrew D; Steel, M J

    2016-01-01

    Using a femtosecond laser writing technique, we fabricate and characterise three-waveguide digital adiabatic passage devices, with the central waveguide digitised into five discrete waveguidelets. Strongly asymmetric behaviour was observed, devices operated with high fidelity in the counter-intuitive scheme while strongly suppressing transmission in the intuitive. The low differential loss of the digital adiabatic passage designs potentially offers additional functionality for adiabatic passage based devices. These devices operate with a high contrast ($>\\!90\\%$) over a 60~nm bandwidth, centered at $\\sim 823$~nm.

  16. Adiabatic pipelining: a key to ternary computing with quantum dots.

    Pečar, P; Ramšak, A; Zimic, N; Mraz, M; Lebar Bajec, I

    2008-12-10

    The quantum-dot cellular automaton (QCA), a processing platform based on interacting quantum dots, was introduced by Lent in the mid-1990s. What followed was an exhilarating period with the development of the line, the functionally complete set of logic functions, as well as more complex processing structures, however all in the realm of binary logic. Regardless of these achievements, it has to be acknowledged that the use of binary logic is in computing systems mainly the end result of the technological limitations, which the designers had to cope with in the early days of their design. The first advancement of QCAs to multi-valued (ternary) processing was performed by Lebar Bajec et al, with the argument that processing platforms of the future should not disregard the clear advantages of multi-valued logic. Some of the elementary ternary QCAs, necessary for the construction of more complex processing entities, however, lead to a remarkable increase in size when compared to their binary counterparts. This somewhat negates the advantages gained by entering the ternary computing domain. As it turned out, even the binary QCA had its initial hiccups, which have been solved by the introduction of adiabatic switching and the application of adiabatic pipeline approaches. We present here a study that introduces adiabatic switching into the ternary QCA and employs the adiabatic pipeline approach to successfully solve the issues of elementary ternary QCAs. What is more, the ternary QCAs presented here are sizewise comparable to binary QCAs. This in our view might serve towards their faster adoption.

  17. Structural evolutions and reforms of the French banking and financial system since the 1980s:Relationship with the legal process of European integration

    Christophe Blot; Jerome Creel; Anne-Laure Delatte; Fabien Labondance; Sandrine Levasseur

    2014-01-01

    Since the 1980s, structural and regulatory evolutions and reforms of the French banking and financial system have been manifold. They have been influenced not only by the European integration process, but also by the historical worldwide context of deregulation and, morerecently, by the crisis.The paper presents these three waves of regulation and their impact on the French banking and financial system

  18. The Ghosts of Higher Education Reform: On the Organisational Processes Surrounding Policy Borrowing

    Brøgger, Katja

    2014-01-01

    The Bologna Process is one of the most extensive examples of policy borrowing processes. Based on qualitative data, this article argues in favour of studying part of this process as "global smallness", centring on the organisational effects of the implementation of a globalised curriculum. Through Derrida's notion on hauntology,…

  19. Thermoelectric Effects under Adiabatic Conditions

    George Levy

    2013-10-01

    Full Text Available This paper investigates not fully explained voltage offsets observed by several researchers during the measurement of the Seebeck coefficient of high Z materials. These offsets, traditionally attributed to faulty laboratory procedures, have proven to have an irreducible component that cannot be fully eliminated in spite of careful laboratory procedures. In fact, these offsets are commonly observed and routinely subtracted out of commercially available Seebeck measurement systems. This paper offers a possible explanation based on the spontaneous formation of an adiabatic temperature gradient in the presence of a force field. The diffusion-diffusion heat transport mechanism is formulated and applied to predict two new thermoelectric effects. The first is the existence of a temperature gradient across a potential barrier in a semiconductor and the second is the Onsager reciprocal of the first, that is, the presence of a measureable voltage that arises across a junction when the temperature gradient is forced to zero by a thermal clamp. Suggested future research includes strategies for utilizing the new thermoelectric effects.

  20. 工业催化重整过程动态建模与仿真%Dynamic Modeling and Simulation of a Commercial Naphtha Catalytic Reforming Process

    胡永有; 徐巍华; 侯卫锋; 苏宏业; 褚健

    2005-01-01

    A first principles-based dynamic model for a continuous catalyst regeneration (CCR) platforming process, the UOP commercial naphtha catalytic reforming process, is developed in this paper. The lumping details of the naphtha feed and reaction scheme of the reaction model are given. The process model is composed of the reforming reaction model with catalyst deactivation, the furnace model and the separator model, which is capable of capturing the major dynamics that occurs in this process system. Dynamic simulations are performed based on Gear numerical algorithm and method of lines (MOL), a numerical technique dealing with partial differential equations (PDEs). The results of simulation are also presented. Dynamic responses caused by disturbances in the process system can be correctly predicted through simulations.

  1. Adiabatic hydrodynamics: The eightfold way to dissipation

    Haehl, Felix M; Rangamani, Mukund

    2015-01-01

    We provide a complete solution to hydrodynamic transport at all orders in the gradient expansion compatible with the second law constraint. The key new ingredient we introduce is the notion of adiabaticity, which allows us to take hydrodynamics off-shell. Adiabatic fluids are such that off-shell dynamics of the fluid compensates for entropy production. The space of adiabatic fluids is quite rich, and admits a decomposition into seven distinct classes. Together with the dissipative class this establishes the eightfold way of hydrodynamic transport. Furthermore, recent results guarantee that dissipative terms beyond leading order in the gradient expansion are agnostic of the second law. While this completes a transport taxonomy, we go on to argue for a new symmetry principle, an Abelian gauge invariance that guarantees adiabaticity in hydrodynamics. We suggest that this symmetry is the macroscopic manifestation of the microscopic KMS invariance. We demonstrate its utility by explicitly constructing effective ac...

  2. Adiabatic quantum gates and Boolean functions

    Andrecut, M; Ali, M K [Department of Physics, University of Lethbridge, Lethbridge, AB, T1K 3M4 (Canada)

    2004-06-25

    We discuss the logical implementation of quantum gates and Boolean functions in the framework of quantum adiabatic method, which uses the language of ground states, spectral gaps and Hamiltonians instead of the standard unitary transformation language. (letter to the editor)

  3. Fracture Criterion for Adiabatic Shear Localization during High Speed Cutting Process%高速切削过程绝热剪切局部化断裂判据

    王敏杰; 谷丽瑶

    2013-01-01

    随着切削速度进一步提高,带有绝热剪切带(Adiabatic shear band,ASB)的锯齿形切屑会不可避免地发生绝热剪切局部化断裂(Adiabatic shear localization fracture,ASLF),使锯齿彼此完全分离.以淬硬45钢(45 HRC)为例,采用前角-10°的PCBN刀具进行进给0.2~0.4 mm、切削速度高达1 400 m/min的高速正交车削试验,获得ASLF发生时的切屑形貌、切削条件以及剪切带内能量变化规律.结合梯度塑性理论,建立高速切削过程热塑性剪切波的传播模型,推导绝热剪切饱和极限(Adiabatic shear saturation limit,ASSL)及饱和度(Adiabatic shear saturation degree,ASSD)的表达式,提出ASLF判据,并与试验结果进行对比验证,分析讨论剪切带与材料属性、加载条件对ASSD的影响规律.由热塑性剪切波的传播理论推导的ASSL可有效描述剪切带中能量随切削条件的汇聚情况,为今后高速切削领域对锯齿形切屑发生ALSF的预报研究奠定了理论与试验基础.%As the cutting speed increases further, adiabatic shear localization fracture (ASLF) which is a fracture of adiabatic shear band (ASB) in serrated chip and makes segments separated completely inevitably. High speed machining experiment of hardened 45 steel (45 HRC) is carried out by using PCBN cutter with rake angle -10°at various speed up to 1 400 m/min and various feeds from 0.2 mm to 0.4 mm. The chip morphology, the cutting conditions and the corresponding changing regularity of energy in band are obtained. Combining gradient plasticity theory, the propagation model of thermo-plastic shear wave in serrated chip in high speed machining is established. Based on this theory, the expressions of adiabatic shear saturation limit (ASSL) and saturation degree (ASSD) are derived out, the fracture criterion of adiabatic shear localization is proposed and compare with the experimental results. The influences of shear band properties, material properties and loading conditions on

  4. Faster computation of adiabatic EMRIs using resonances

    Grossman, Rebecca; Perez-Giz, Gabe

    2011-01-01

    Motivated by the prohibitive computational cost of producing adiabatic extreme mass ratio inspirals, we explain how a judicious use of resonant orbits can dramatically expedite both that calculation and the generation of snapshot gravitational waves from geodesic sources. In the course of our argument, we clarify the resolution of a lingering debate on the appropriate adiabatic averaging prescription in favor of torus averaging over time averaging.

  5. Quantum Adiabatic Evolution Algorithms versus Simulated Annealing

    Farhi, E; Gutmann, S; Farhi, Edward; Goldstone, Jeffrey; Gutmann, Sam

    2002-01-01

    We explain why quantum adiabatic evolution and simulated annealing perform similarly in certain examples of searching for the minimum of a cost function of n bits. In these examples each bit is treated symmetrically so the cost function depends only on the Hamming weight of the n bits. We also give two examples, closely related to these, where the similarity breaks down in that the quantum adiabatic algorithm succeeds in polynomial time whereas simulated annealing requires exponential time.

  6. Thermodynamic equilibrium calculations of hydrogen production from the combined processes of dimethyl ether steam reforming and partial oxidation

    Semelsberger, Troy A.; Borup, Rodney L.

    Thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the combined processes of dimethyl ether (DME) partial oxidation and steam reforming were investigated as a function of oxygen-to-carbon ratio (0.00-2.80), steam-to-carbon ratio (0.00-4.00), temperature (100 °C-600 °C), pressure (1-5 atm) and product species. Thermodynamically, dimethyl ether processed with air and steam generates hydrogen-rich fuel-cell feeds; however, the hydrogen concentration is less than that for pure DME steam reforming. Results of the thermodynamic processing of dimethyl ether indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 °C, oxygen-to-carbon ratios greater than 0.00 and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure has negligible effects on the hydrogen content. Thermodynamically, dimethyl ether can produce concentrations of hydrogen and carbon monoxide of 52% and 2.2%, respectively, at a temperature of 300 °C, and oxygen-to-carbon ratio of 0.40, a pressure of 1 atm and a steam-to-carbon ratio of 1.50. The order of thermodynamically stable products (excluding H 2, CO, CO 2, DME, NH 3 and H 2O) in decreasing mole fraction is methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol and methyl-ethyl ether; trace amounts of formaldehyde, formic acid and methanol are observed. Ammonia and hydrogen cyanide are also thermodynamically favored products. Ammonia is favored at low temperatures in the range of oxygen-to-carbon ratios of 0.40-2.50 regardless of the steam-to-carbon ratio employed. The maximum ammonia content (i.e., 40%) occurs at an oxygen-to-carbon ratio of 0.40, a steam-to-carbon ratio of 1.00 and a temperature of 100 °C. Hydrogen cyanide is favored at high temperatures and low oxygen-to-carbon ratios with a maximum of 3.18% occurring at an oxygen-to-carbon ratio of 0.40 and a steam

  7. Analysis of adiabatic transfer in cavity quantum electrodynamics

    Joyee Ghosh; R Ghosh; Deepak Kumar

    2011-10-01

    A three-level atom in a configuration trapped in an optical cavity forms a basic unit in a number of proposed protocols for quantum information processing. This system allows for efficient storage of cavity photons into long-lived atomic excitations, and their retrieval with high fidelity, in an adiabatic transfer process through the ‘dark state’ by a slow variation of the control laser intensity. We study the full quantum mechanics of this transfer process with a view to examine the non-adiabatic effects arising from inevitable excitations of the system to states involving the upper level of , which is radiative. We find that the fidelity of storage is better, the stronger the control field and the slower the rate of its switching off. On the contrary, unlike the adiabatic notion, retrieval is better with faster rates of switching on of an optimal control field. Also, for retrieval, the behaviour with dissipation is non-monotonic. These results lend themselves to experimental tests. Our exact computations, when applied to slow variations of the control intensity for strong atom–photon couplings, are in very good agreement with Berry’s superadiabatic transfer results without dissipation.

  8. Regional Higher Education Reform Initiatives in Africa: A Comparative Analysis with the Bologna Process

    Woldegiorgis, Emnet Tadesse; Jonck, Petronella; Goujon, Anne

    2015-01-01

    Europe's Bologna Process has been identified as a pioneering approach in regional cooperation with respect to the area of higher education. To address the challenges of African higher education, policymakers are recommending regional cooperation that uses the Bologna Process as a model. Based on these recommendations, the African Union Commission…

  9. Hierarchical theory of quantum adiabatic evolution

    Zhang, Qi; Gong, Jiangbin; Wu, Biao

    2014-12-01

    Quantum adiabatic evolution is a dynamical evolution of a quantum system under slow external driving. According to the quantum adiabatic theorem, no transitions occur between nondegenerate instantaneous energy eigenstates in such a dynamical evolution. However, this is true only when the driving rate is infinitesimally small. For a small nonzero driving rate, there are generally small transition probabilities between the energy eigenstates. We develop a classical mechanics framework to address the small deviations from the quantum adiabatic theorem order by order. A hierarchy of Hamiltonians is constructed iteratively with the zeroth-order Hamiltonian being determined by the original system Hamiltonian. The kth-order deviations are governed by a kth-order Hamiltonian, which depends on the time derivatives of the adiabatic parameters up to the kth-order. Two simple examples, the Landau-Zener model and a spin-1/2 particle in a rotating magnetic field, are used to illustrate our hierarchical theory. Our analysis also exposes a deep, previously unknown connection between classical adiabatic theory and quantum adiabatic theory.

  10. Quantum state engineering in a cavity by Stark chirped rapid adiabatic passage

    Amniat-Talab, M; Guérin, S

    2006-01-01

    We propose a robust scheme to generate single-photon Fock states and atom-photon and atom-atom entanglement in atom-cavity systems. We also present a scheme for quantum networking between two cavity nodes using an atomic channel. The mechanism is based on Stark-chirped rapid adiabatic passage (SCRAP) and half-SCRAP processes in a microwave cavity. The engineering of these states depends on the design of the adiabatic dynamics through the static and dynamic Stark shifts.

  11. University Merger Reforms: Rational, political, institutional or incidental processes? The case of Denmark

    Aagaard, Kurt; Hansen, Hanne Foss; Rasmussen, Jørgen Gulddahl

    Mergers have for some years been popular within the public sector in many countries this includes mergers between higher education institutions. In the Danish university and Government Research Institutions sector a process of merger took place in 2006. ‘University merger reforms’ is an analysis ...... on an organizational level demands the use of more than one conceptual model for agenda-setting - decision making and institutional restructuring,......-sector and some of the conclusions made from other kinds of merger studies. Important conclusions of the study of the three universities are that mergers and especially post-mergers processes are much more than linear, straight forward rational processes and that understanding merger processes...

  12. On some issues of gravitationally induced adiabatic particle productions

    Pan, Supriya; Pramanik, Souvik

    2016-01-01

    In this work, we investigate the current accelerating universe driven by the gravitationally induced adiabatic matter creation process. To elaborate the underlying cognitive content, here we consider three models of adiabatic particle creation and constrain the model parameters by fitting the models with the Union 2.1 data set using $\\chi^2$ minimization technique. The models are analyzed by two geometrical and model independent tests, viz., cosmography and $Om$-diagnostic, which are widely used to distinguish the cosmological models from $\\Lambda$CDM. We also compared present values of those model independent parameters with that of the flat $\\Lambda$CDM model. Finally, the validity of the generalized second law of thermodynamics and the condition of thermodynamic equilibrium for the particle production models have been tested.

  13. Confinement loss in adiabatic photonic crystal fiber tapers

    Kuhlmey, Boris T.; Nguyen, Hong C.; Steel, M. J.; Eggleton, Benjamin J.

    2006-09-01

    We numerically study confinement loss in photonic crystal fiber (PCF) tapers and compare our results with previously published experimental data. Agreement between theory and experiment requires taking into account hole shrinkage during the tapering process, which we measure by using a noninvasive technique. We show that losses are fully explained within the adiabatic approximation and that they are closely linked to the existence of a fundamental core-mode cutoff. This cutoff is equivalent to the core-mode cutoff in depressed-cladding fibers, so that losses in PCF tapers can be obtained semiquantitatively from an equivalent depressed-cladding fiber model. Finally, we discuss the definition of adiabaticity in this open boundary problem.

  14. Reformer Fuel Injector

    Suder, Jennifer L.

    2004-01-01

    Today's form of jet engine power comes from what is called a gas turbine engine. This engine is on average 14% efficient and emits great quantities of green house gas carbon dioxide and air pollutants, Le. nitrogen oxides and sulfur oxides. The alternate method being researched involves a reformer and a solid oxide fuel cell (SOFC). Reformers are becoming a popular area of research within the industry scale. NASA Glenn Research Center's approach is based on modifying the large aspects of industry reforming processes into a smaller jet fuel reformer. This process must not only be scaled down in size, but also decrease in weight and increase in efficiency. In comparison to today's method, the Jet A fuel reformer will be more efficient as well as reduce the amount of air pollutants discharged. The intent is to develop a 10kW process that can be used to satisfy the needs of commercial jet engines. Presently, commercial jets use Jet-A fuel, which is a kerosene based hydrocarbon fuel. Hydrocarbon fuels cannot be directly fed into a SOFC for the reason that the high temperature causes it to decompose into solid carbon and Hz. A reforming process converts fuel into hydrogen and supplies it to a fuel cell for power, as well as eliminating sulfur compounds. The SOFC produces electricity by converting H2 and CO2. The reformer contains a catalyst which is used to speed up the reaction rate and overall conversion. An outside company will perform a catalyst screening with our baseline Jet-A fuel to determine the most durable catalyst for this application. Our project team is focusing on the overall research of the reforming process. Eventually we will do a component evaluation on the different reformer designs and catalysts. The current status of the project is the completion of buildup in the test rig and check outs on all equipment and electronic signals to our data system. The objective is to test various reformer designs and catalysts in our test rig to determine the most

  15. On criterion of modal adiabaticity

    WANG; Ning(

    2001-01-01

    [1]Pierce, A. D., Extension of the method of normal modes to sound propagation in an almost-stratified medium, J. Acoust.Soc. Am., 1965, 37: 19-27.[2]Wang, D. Z. , Shang, E. C., Underwater Acoustics (in Chinese), Beijing: Science Press, 1981.[3]Zhang Renhe, Li Fenghua, Beam-displacement rya-mode theory of sound propagation in shallow water, Science in China, Ser.A, 1999, 42(7): 739-749.[4]Zhou Jixun, Zhang Xuezhen, Rogers P., Resonance interaction of sound waves with internal solitons in coastal zone, J.Acoust. Soc. Am., 1991, 90: 2042-2054.[5]Shang, E. C., Wang, Y. Y., The impact of mesoscale oceanic structure on global-scale acoustic propagation, in Theoretical and Computational Acoustics (ed. Ding Lee et al. ), Singapore: World Scientific Publishing Co. , 1996, 409-431.[6]Milder, D. M., Ray and wave invariants for SOFAR channel propagation, J. Acoust. Soc. Am., 1969, 46: 1259-1263.[7]Nag l, A., Milder, D. M., Adiabatic mode theory of underwater sound propagation in a range-dependent environment, J.Acoust. Soc. Am., 1978, 63: 739-749.[8]Brekhovskikh, L. M., Waves in Layered Media, 2nd ed., New York: Academic Press Inc., 1973.[9]Brekhovskikh, L. M., Lysanov, Yu., Fundamental of Ocean Acoustics, Ch. 7, Sec. 7.2, Berlin: Springer-Verlag, 1982.[10]Evans, R. B., A coupled mode solution for acoustic propagation in a wave-guide with stepwise depth variations of a penerable bottom, J. Acoust. Soc. A.m., 1983, 74: 188-195.[11]Jensen, F. B., Kuperman, W. A., Porter, M. B. et al., Computational Ocean Acoustics, New York: Springer-Verlag,1992.[12]Wang Ning, Inverse scattering problem for the coupled second order ODE, Journal of The Physical Society of Japan, 1995, 64(12): 4907-4915.

  16. A Matter of Time: Enacting the Exclusion of Onshore Refugee Applicants through the Reform and Acceleration of Refugee Determination Processes

    Anthea Vogl

    2016-03-01

    Full Text Available State-based processes for determining refugee claims are crucial sites of inclusion or exclusion for onshore refugee applicants. This paper argues that cultures of disbelief and exclusion towards onshore refugee applicants are increasingly being enacted indirectly, via procedural reforms to Refugee Status Determination (RSD, which limit the ability of applicants to establish and articulate their claims. Focusing on Australia and Canada, this paper tracks the acceleration and truncation of RSD procedures, which first reflect and then frequently achieve the exclusion of onshore applicants. Two sets of reforms in particular have profoundly limited the terms on which applicants may present their claims. In Canada, this occurred as the result of a major overhaul of RSD that took place in December 2012. In Australia, the policy of ‘enhanced screening’ of applicants achieves the immediate screening-out of certain claims from the Australian determination system. Alongside analysing these reforms as a means of exclusion, this paper argues that the new procedures most disadvantage applicants making claims on the basis of gender-related persecution. Los procesos estatales para resolver las concesiones de asilo son situaciones cruciales para la inclusión o exclusión de los solicitantes de asilo una vez están en el territorio de acogida. Este artículo defiende que cada vez más, se está promulgando indirectamente la cultura de la desconfianza y exclusión hacia los solicitantes de asilo, a través de reformas procesuales de la Determinación del Estatus de Refugiado (DER, lo que limita la capacidad de los solicitantes para establecer y articular sus demandas de asilo. Centrándose en Australia y Canadá, este artículo realiza un seguimiento de la aceleración y el truncamiento de los procedimientos de DER que primero reflejan y después a menudo consiguen la exclusión de los solicitantes en el propio territorio de acogida. Dos grupos de reformas

  17. Thermal reservoir sizing for adiabatic compressed air energy storage

    Kere, Amelie; Goetz, Vincent; Py, Xavier; Olives, Regis; Sadiki, Najim [Perpignan Univ. (France). PROMES CNRS UPR 8521; Mercier-Allart, Eric [EDF R et D, Chatou (France)

    2012-07-01

    Despite the operation of the two existing industrial facilities to McIntosh (Alabama), and for more than thirty years, Huntorf (Germany), electricity storage in the form of compressed air in underground cavern (CAES) has not seen the development that was expected in the 80s. The efficiency of this form of storage was with the first generation CAES, less than 50%. The evolving context technique can significantly alter this situation. The new generation so-called Adiabatic CAES (A-CAES) is to retrieve the heat produced by the compression via thermal storage, thus eliminating the necessity of gas to burn and would allow consideration efficiency overall energy of the order of 70%. To date, there is no existing installation of A-CAES. Many studies describe the principal and the general working mode of storage systems by adiabatic compression of air. So, efficiencies of different configurations of adiabatic compression process were analyzed. The aim of this paper is to simulate and analyze the performances of a thermal storage reservoir integrated in the system and adapted to the working conditions of a CAES.

  18. 基于工作过程的Protel考核改革的研究%Research Based on Working Process of the Protel Assessment Reform

    宋冬萍

    2012-01-01

    The end of the assessment method has many shortcomings. According to the the Protel course assessment of the status quo, this paper puts forward reform measures and methods of assessment based on work process. Practice has proved that reforms of Protel assessment and the profession as a whole learning process integration, improved students' motivation to learn and comprehensive ability, teaching effcctive-ness.%终结性的考核方式存在诸多弊端.针对Protel课程的考核现状,提出了具体的基于工作过程考核的改革措施和方法.实践证明,通过改革使Protel考核与整个专业的学习过程相融合,切实提高了学生的学习主动性和综合能力,教学效果好.

  19. Nonadiabatic exchange dynamics during adiabatic frequency sweeps.

    Barbara, Thomas M

    2016-04-01

    A Bloch equation analysis that includes relaxation and exchange effects during an adiabatic frequency swept pulse is presented. For a large class of sweeps, relaxation can be incorporated using simple first order perturbation theory. For anisochronous exchange, new expressions are derived for exchange augmented rotating frame relaxation. For isochronous exchange between sites with distinct relaxation rate constants outside the extreme narrowing limit, simple criteria for adiabatic exchange are derived and demonstrate that frequency sweeps commonly in use may not be adiabatic with regard to exchange unless the exchange rates are much larger than the relaxation rates. Otherwise, accurate assessment of the sensitivity to exchange dynamics will require numerical integration of the rate equations. Examples of this situation are given for experimentally relevant parameters believed to hold for in-vivo tissue. These results are of significance in the study of exchange induced contrast in magnetic resonance imaging.

  20. Adiabatic optimization versus diffusion Monte Carlo methods

    Jarret, Michael; Jordan, Stephen P.; Lackey, Brad

    2016-10-01

    Most experimental and theoretical studies of adiabatic optimization use stoquastic Hamiltonians, whose ground states are expressible using only real nonnegative amplitudes. This raises a question as to whether classical Monte Carlo methods can simulate stoquastic adiabatic algorithms with polynomial overhead. Here we analyze diffusion Monte Carlo algorithms. We argue that, based on differences between L1 and L2 normalized states, these algorithms suffer from certain obstructions preventing them from efficiently simulating stoquastic adiabatic evolution in generality. In practice however, we obtain good performance by introducing a method that we call Substochastic Monte Carlo. In fact, our simulations are good classical optimization algorithms in their own right, competitive with the best previously known heuristic solvers for MAX-k -SAT at k =2 ,3 ,4 .

  1. Fast forward to the classical adiabatic invariant

    Jarzynski, Christopher; Patra, Ayoti; Subaşı, Yiğit

    2016-01-01

    We show how the classical action, an adiabatic invariant, can be preserved under non-adiabatic conditions. Specifically, for a time-dependent Hamiltonian $H = p^2/2m + U(q,t)$ in one degree of freedom, and for an arbitrary choice of action $I_0$, we construct a "fast-forward" potential energy function $V_{\\rm FF}(q,t)$ that, when added to $H$, guides all trajectories with initial action $I_0$ to end with the same value of action. We use this result to construct a local dynamical invariant $J(q,p,t)$ whose value remains constant along these trajectories. We illustrate our results with numerical simulations. Finally, we sketch how our classical results may be used to design approximate quantum shortcuts to adiabaticity.

  2. Rapid adiabatic passage without level crossing

    Rangelov, A A; Shore, B W

    2009-01-01

    We present a method for achieving complete population transfer in a two-state quantum system via adiabatic time evolution in which, contrary to conventional rapid adiabatic passage produced by chirped pulses, there occurs no crossing of diabatic energy curves: there is no sign change of the detuning. Instead, we use structured pulses, in which, in addition to satisfying conditions for adiabatic evolution, there occurs a sign change of the Rabi frequency when the detuning is zero. We present simulations that offer simple geometrical interpretation of the two-dimensional motion of the Bloch vector for this system, illustrating how both complete population inversion and complete population return occur for different choices of structured pulses.

  3. Energy efficiency of adiabatic superconductor logic

    Takeuchi, Naoki; Yamanashi, Yuki; Yoshikawa, Nobuyuki

    2015-01-01

    Adiabatic superconductor logic (ASL), including adiabatic quantum-flux-parametron (AQFP) logic, exhibits high energy efficiency because its bit energy can be decreased below the thermal energy through adiabatic switching operations. In the present paper, we present the general scaling laws of ASL and compare the energy efficiency of ASL with those of other energy-efficient logics. Also, we discuss the minimum energy-delay product (EDP) of ASL at finite temperature. Our study shows that there is a maximum temperature at which the EDP can reach the quantum limit given by ħ/2, which is dependent on the superconductor material and the Josephson junction quality, and that it is reasonable to operate ASL at cryogenic temperatures in order to achieve an EDP that approaches ħ/2.

  4. Complexity of the Quantum Adiabatic Algorithm

    Hen, Itay

    2013-01-01

    The Quantum Adiabatic Algorithm (QAA) has been proposed as a mechanism for efficiently solving optimization problems on a quantum computer. Since adiabatic computation is analog in nature and does not require the design and use of quantum gates, it can be thought of as a simpler and perhaps more profound method for performing quantum computations that might also be easier to implement experimentally. While these features have generated substantial research in QAA, to date there is still a lack of solid evidence that the algorithm can outperform classical optimization algorithms.

  5. On adiabatic invariant in generalized Galileon theories

    Ema, Yohei; Mukaida, Kyohei; Nakayama, Kazunori

    2015-01-01

    We consider background dynamics of generalized Galileon theories in the context of inflation, where gravity and inflaton are non-minimally coupled to each other. In the inflaton oscillation regime, the Hubble parameter and energy density oscillate violently in many cases, in contrast to the Einstein gravity with minimally coupled inflaton. However, we find that there is an adiabatic invariant in the inflaton oscillation regime in any generalized Galileon theory. This adiabatic invariant is useful in estimating the expansion law of the universe and also the particle production rate due to the oscillation of the Hubble parameter.

  6. Markovian quantum master equation beyond adiabatic regime

    Yamaguchi, Makoto; Yuge, Tatsuro; Ogawa, Tetsuo

    2017-01-01

    By introducing a temporal change time scale τA(t ) for the time-dependent system Hamiltonian, a general formulation of the Markovian quantum master equation is given to go well beyond the adiabatic regime. In appropriate situations, the framework is well justified even if τA(t ) is faster than the decay time scale of the bath correlation function. An application to the dissipative Landau-Zener model demonstrates this general result. The findings are applicable to a wide range of fields, providing a basis for quantum control beyond the adiabatic regime.

  7. Steam reforming of methane in equilibrium membrane reactors for integration in power cycles

    Bottino, A.; Comite, A.; Capannelli, G. [Department of Chemistry and Industrial Chemistry, Via Dodecaneso 31, 16146 Genoa (Italy); Di Felice, R. [Department of Process and Chemical Engineering ' G. Bonino, Via Opera Pia 15, Genoa (Italy); Pinacci, P. [CESI, Via Rubattino 54, 20134 Milano (Italy)

    2006-10-30

    Methane steam reforming is the most important industrial route to produce H{sub 2}. The process is governed by equilibrium reactions, the overall process is endothermic and high temperatures are required to reach satisfactory methane conversions. The possibility of using a membrane reactor, which separates H{sub 2} from the reaction zone with a subsequent improvement of the conversions, is a challenge of many academic and industrial researchers. A great effort of membrane reactor analysis applied to steam reforming is necessary in the light of the novel and potential process applications (fuel cells, CO{sub 2} capture). This paper presents the model of a non-adiabatic methane steam reformer membrane reactor (MSRMR) working in equilibrium conditions. The model was used to investigate the effects of some variables (e.g. temperature profile, separation efficiency, plant size) on the membrane area and the energy required by the process, which in turn affect fixed and operating costs. The simulations showed that the membrane area required sharp increases in the reactor size and that for large plants the development of thin and permeable membranes is a key issue. (author)

  8. Orthopaedic Surgery Under National Health Reform: An Analysis of Power, Process, Adaptation, and Leadership: AOA Critical Issues.

    Callahan, Charles D; Adair, Daniel; Bozic, Kevin J; Manning, Blaine T; Saleh, Jamal K; Saleh, Khaled J

    2014-07-01

    Morrison argued that demography, economy, and technology drive the evolution of industries from a formative first-generation state ("First Curve") to a radically different way of doing things ("Second Curve") that is marked by new skills, strategies, and partners. The current health-reform movement in the United States reflects these three key evolutionary trends: surging medical needs of an aging population, dramatic expansion of Medicare spending, and care delivery systems optimized through powerful information technology. Successful transition from a formative first-generation state (First Curve) to a radically different way of doing things (Second Curve) will require new skills, strategies, and partners. In a new world that is value-driven, community-centric (versus hospital-centric), and prevention-focused, orthopaedic surgeons and health-care administrators must form new alliances to reduce the cost of care and improve durable outcomes for musculoskeletal problems. The greatest barrier to success in the Second Curve stems not from lack of empirical support for integrated models of care, but rather from resistance by those who would execute them. Porter's five forces of competitive strategy and the behavioral analysis of change provide insights into the predictable forms of resistance that undermine clinical and economic success in the new environment of care. This paper analyzes the components that will differentiate orthopaedic care provision for the Second Curve. It also provides recommendations for future-focused orthopaedic surgery and health-care administrative leaders to consider as they design newly adaptive, mutually reinforcing, and economically viable musculoskeletal care processes that drive the level of orthopaedic care that our nation deserves-at a cost that it can afford.

  9. Integration of Methane Steam Reforming and Water Gas Shift Reaction in a Pd/Au/Pd-Based Catalytic Membrane Reactor for Process Intensification.

    Castro-Dominguez, Bernardo; Mardilovich, Ivan P; Ma, Liang-Chih; Ma, Rui; Dixon, Anthony G; Kazantzis, Nikolaos K; Ma, Yi Hua

    2016-09-19

    Palladium-based catalytic membrane reactors (CMRs) effectively remove H₂ to induce higher conversions in methane steam reforming (MSR) and water-gas-shift reactions (WGS). Within such a context, this work evaluates the technical performance of a novel CMR, which utilizes two catalysts in series, rather than one. In the process system under consideration, the first catalyst, confined within the shell side of the reactor, reforms methane with water yielding H₂, CO and CO₂. After reforming is completed, a second catalyst, positioned in series, reacts with CO and water through the WGS reaction yielding pure H₂O, CO₂ and H₂. A tubular composite asymmetric Pd/Au/Pd membrane is situated throughout the reactor to continuously remove the produced H₂ and induce higher methane and CO conversions while yielding ultrapure H₂ and compressed CO₂ ready for dehydration. Experimental results involving (i) a conventional packed bed reactor packed (PBR) for MSR, (ii) a PBR with five layers of two catalysts in series and (iii) a CMR with two layers of two catalysts in series are comparatively assessed and thoroughly characterized. Furthermore, a comprehensive 2D computational fluid dynamics (CFD) model was developed to explore further the features of the proposed configuration. The reaction was studied at different process intensification-relevant conditions, such as space velocities, temperatures, pressures and initial feed gas composition. Finally, it is demonstrated that the above CMR module, which was operated for 600 h, displays quite high H₂ permeance and purity, high CH₄ conversion levels and reduced CO yields.

  10. Reform of the NaCN dosing system in gold concentrate leaching process%氰化物添加系统的改造及效果

    王宝胜

    2011-01-01

    某矿山氰化厂对金精矿氰化浸出加氰化物系统进行自动化改造后,实现了浸出过程中氰化物的添加均衡稳定,氰化物浓度控制在要求值,优化了金氰化浸出指标,降低了氰化物消耗,实现了氰化物无泄露输送,安全环保.%After the automation reform of the dosing system in gold concentrate cyanidation process, the adding of cyanide is stable and its concentration can be controlled in the demanded level. The reform enhances the leaching rate of gold and reduces the consumption of cyanide. At the same time, the non-leakage transportation of cyanide is realized.

  11. Administrative Reform

    Plum, Maja

    Through the example of a Danish reform of educational plans in early childhood education, the paper critically addresses administrative educational reforms promoting accountability, visibility and documentation. Drawing on Foucaultian perspectives, the relation between knowledge and governing...... of administrative technology, tracing how the humanistic values of education embed and are embedded within ‘the professional nursery teacher' as an object and subject of administrative practice. Rather than undermining the humanistic potential of education, it is argued that the technology of accounting...

  12. Startup of an industrial adiabatic tubular reactor

    Verwijs, J.W.; Berg, van den H.; Westerterp, K.R.

    1992-01-01

    The dynamic behaviour of an adiabatic tubular plant reactor during the startup is demonstrated, together with the impact of a feed-pump failure of one of the reactants. A dynamic model of the reactor system is presented, and the system response is calculated as a function of experimentally-determine

  13. Quantum Pumping and Adiabatic Transport in Nanostructures

    Wakker, G.M.M.

    2011-01-01

    This thesis consists of a theoretical exploration of quantum transport phenomena and quantum dynamics in nanostructures. Specifically, we investigate adiabatic quantum pumping of charge in several novel types of nanostructures involving open quantum dots or graphene. For a bilayer of graphene we fin

  14. Adiabatic limits,vanishing theorems and the noncommutative residue

    2009-01-01

    In this paper,we compute the adiabatic limit of the scalar curvature and prove several vanishing theorems by taking adiabatic limits.As an application,we give a Kastler-Kalau-Walze type theorem for foliations.

  15. Adiabatic and Non-adiabatic quenches in a Spin-1 Bose Einstein Condensate

    Boguslawski, Matthew; Hebbe Madhusudhana, Bharath; Anquez, Martin; Robbins, Bryce; Barrios, Maryrose; Hoang, Thai; Chapman, Michael

    2016-05-01

    A quantum phase transition (QPT) is observed in a wide range of phenomena. We have studied the dynamics of a spin-1 ferromagnetic Bose-Einstein condensate for both adiabatic and non-adiabatic quenches through a QPT. At the quantum critical point (QCP), finite size effects lead to a non-zero gap, which makes an adiabatic quench possible through the QPT. We experimentally demonstrate such a quench, which is forbidden at the mean field level. For faster quenches through the QCP, the vanishing energy gap causes the reaction timescale of the system to diverge, preventing the system from adiabatically following the ground state. We measure the temporal evolution of the spin populations for different quench speeds and determine the exponents characterizing the scaling of the onset of excitations, which are in good agreement with the predictions of Kibble-Zurek mechanism.

  16. Computer modeling and prediction of multi-cylinder turbo-compound adiabatic diesel processes and performances; Une simulation mathematique des processus et prediction des performances du diesel multicylindrique turbocompound adiabatique

    Abdelhakem, B.; Aleksey, K. [Centre Universitaire de Bechar (Algeria); Serguevich, A. [Institut d`Automobiles et de Routes de Moscou (Russian Federation)

    1997-12-31

    Using a differential equation of the first law of thermodynamic, the volumetric balance equation and the equation of state a mathematical model is developed. It makes possible to calculate the performance parameters of turbo-compound adiabatic Diesel engine and the instantaneous parameters of working fluid in the cylinder, in the volumes ahead of the turbine and ahead the power turbine, in the volumes behind the compressor and the air cooler. The heat release to cycle and the heat transfer are calculated by the Wibe`s law and by Woschni`s equation. The computer program is used to evaluated the improving on the performance parameters of automotive Diesel engine by compounding and by heat loss restriction. It was found that the program is very useful both in teaching and research. (authors) 20 refs.

  17. Fixed-point adiabatic quantum search

    Dalzell, Alexander M.; Yoder, Theodore J.; Chuang, Isaac L.

    2017-01-01

    Fixed-point quantum search algorithms succeed at finding one of M target items among N total items even when the run time of the algorithm is longer than necessary. While the famous Grover's algorithm can search quadratically faster than a classical computer, it lacks the fixed-point property—the fraction of target items must be known precisely to know when to terminate the algorithm. Recently, Yoder, Low, and Chuang [Phys. Rev. Lett. 113, 210501 (2014), 10.1103/PhysRevLett.113.210501] gave an optimal gate-model search algorithm with the fixed-point property. Previously, it had been discovered by Roland and Cerf [Phys. Rev. A 65, 042308 (2002), 10.1103/PhysRevA.65.042308] that an adiabatic quantum algorithm, operating by continuously varying a Hamiltonian, can reproduce the quadratic speedup of gate-model Grover search. We ask, can an adiabatic algorithm also reproduce the fixed-point property? We show that the answer depends on what interpolation schedule is used, so as in the gate model, there are both fixed-point and non-fixed-point versions of adiabatic search, only some of which attain the quadratic quantum speedup. Guided by geometric intuition on the Bloch sphere, we rigorously justify our claims with an explicit upper bound on the error in the adiabatic approximation. We also show that the fixed-point adiabatic search algorithm can be simulated in the gate model with neither loss of the quadratic Grover speedup nor of the fixed-point property. Finally, we discuss natural uses of fixed-point algorithms such as preparation of a relatively prime state and oblivious amplitude amplification.

  18. Plasma heating via adiabatic magnetic compression-expansion cycle

    Avinash, K.; Sengupta, M.; Ganesh, R.

    2016-06-01

    Heating of collisionless plasmas in closed adiabatic magnetic cycle comprising of a quasi static compression followed by a non quasi static constrained expansion against a constant external pressure is proposed. Thermodynamic constraints are derived to show that the plasma always gains heat in cycles having at least one non quasi static process. The turbulent relaxation of the plasma to the equilibrium state at the end of the non quasi static expansion is discussed and verified via 1D Particle in Cell (PIC) simulations. Applications of this scheme to heating plasmas in open configurations (mirror machines) and closed configurations (tokamak, reverse field pinche) are discussed.

  19. Monte Carlo Simulation of Adiabatic Cooling and Nuclear Magnetism

    Lindgård, Per-Anker; Viertiö, H. E.; Mouritsen, Ole G.

    1988-01-01

    in experimental studies of nuclear magnetism using adiabatic demagnetization methods. It is found that, although fluctuations reduce the transition temperatures by 40%, the isentropes are reduced by less than 10% relative to those calculated by mean-field theory. The dynamics of the ordering process following...... constant-temperature or constant-magnetic-field quenches into the antiferromagnetic phase is found at late times to obey the classical Allen-Cahn growth law. The qualitative features of isentropic quenches and the nonequilibrium ordering phenomena during controlled heating treatments at constant rate...

  20. Analysis of interference in attosecond transient absorption in adiabatic condition

    Dong, Wenpu; Wang, Xiaowei; Zhao, Zengxiu

    2015-01-01

    We simulate the transient absorption of attosecond pulses of infrared laser-dressed atoms by considering a three-level system with the adiabatic approximation. We study the delay-dependent interference features in the transient absorption spectra of helium atoms from the perspective of the coherent interaction processes between the attosecond pulse and the quasi-harmonics, and find that many features of the interference fringes in the absorption spectra of the attosecond pulse can be attributed to the coherence phase difference. And the modulation signals of laser-induced sidebands of the dark state is found related to the dark state with population modulated by the dressing field.

  1. Hojman Exact Invariants and Adiabatic Invariants of Hamilton System

    2007-01-01

    The perturbation to Lie symmetry and adiabatic invariants are studied. Based on the concept of higherorder adiabatic invariants of mechanical systems with action of a small perturbation, the perturbation to Lie symmetry is studied, and Hojman adiabatic invariants of Hamilton system are obtained. An example is given to illustrate the application of the results.

  2. CO2 Reforming Characteristics under Visible Light Response of Cr- or Ag-Doped TiO2 Prepared by Sol-Gel and Dip-Coating Process

    Akira Nishimura

    2012-01-01

    Full Text Available A Cr- or Ag-doped TiO2 film was prepared by sol-gel and dip-coating process and used as the photocatalyst for CO2 reforming under the visible light. The ratio of amount of Cr or Ag added to amount of Ti in TiO2 sol solution (R varied from 0 to 100 wt% or 0 to 50 wt%, respectively. The total layer number of Cr- or Ag-doped TiO2 film (N coated was changed. The CO2 reforming performance with the Cr- or Ag-doped TiO2 film was tested under a Xe lamp with or without ultraviolet (UV light. As a result, when N equals to 1, the concentration of CO which was a product from CO2 reforming was maximized in Cr doping case for R = 70 wt% and in Ag doping case for R = 1 wt%, respectively. The best result of concentration of CO = 8306 ppmV, concentration of CH4 = 1367 ppmV, concentration of C2H6 = 1712 ppmV is obtained when top=7 with Cr doping in this study.

  3. Life cycle inventory analysis of hydrogen production by the steam-reforming process: comparison between vegetable oils and fossil fuels as feedstock

    Marquevich, M.; Sonnemann, G.W.; Castells, F.; Montane, D.

    2002-07-01

    A life cycle inventory analysis has been conducted to assess the environmental load, specifically CO{sub 2} (fossil) emissions and global warming potential (GWP), associated to the production of hydrogen by the steam reforming of hydrocarbon feedstocks (methane and naphtha) and vegetable oils (rapeseed oil, soybean oil and palm oil). Results show that the GWPs associated with the production of hydrogen by steam reforming in a 100 years time frame are 9.71 and 9.46 kg CO{sub 2}-equivalent/kg H{sub 2} for natural gas and naphtha, respectively. For vegetable oils, the GWP decreases to 6.42 kg CO{sub 2}-equivalent/kg H{sub 2} for rapeseed oil, 4.32 for palm oil and 3.30 for soybean oil. A dominance analysis determined that the part of the process that has the largest effect on the GWP is the steam reforming reaction itself for the fossil fuel-based systems, which accounts for 56.7% and 74% of the total GWP for natural gas and naphtha, respectively. This contribution is zero for vegetable oil-based systems, for which harvesting and oil production are the main sources of CO{sub 2}-eq emissions.(author)

  4. Chile's health sector reform: lessons from four reform periods.

    de la Jara, J J; Bossert, T

    1995-01-01

    This paper applies an interdisciplinary approach to analyze the process of health reform in four significant periods in Chilean history: (1) the consolidation of state responsibility for public health in the 1920s, (2) the creation of the state-run National Health Service in the 1950s, (3) the decentralization of primary care and privatization of health insurance in the 1980s, and (4) the strengthening of the mixed public-private market in the 1990s. Building on the authors' separate disciplines, the paper examines the epidemiological, political and economic contexts of these reforms to test simple hypotheses about how these factors shape reform adoption and implementation. The analysis underlines: (1) the importance of epidemiological data as an impetus to public policy; (2) the inhibiting role of economic recession in adoption and implementation of reforms: and (3) the importance of the congruence of reforms with underlying political ideology in civil society. The paper also tests several hypotheses about the reform processes themselves, exploring the role of antecedents, interest groups, and consensus-building in the policy process. It found that incremental processes building on antecedent trends characterize most reform efforts. However, interest group politics and consensus building were found to be complex processes that are not easily captured by the simple hypotheses that were tested. The interdisciplinary approach is found to be a promising form of analysis and suggests further theoretical and empirical issues to be explored.

  5. Efficient shortcuts to adiabatic passage for three-dimensional entanglement generation via transitionless quantum driving.

    He, Shuang; Su, Shi-Lei; Wang, Dong-Yang; Sun, Wen-Mei; Bai, Cheng-Hua; Zhu, Ai-Dong; Wang, Hong-Fu; Zhang, Shou

    2016-08-08

    We propose an effective scheme of shortcuts to adiabaticity for generating a three-dimensional entanglement of two atoms trapped in a cavity using the transitionless quantum driving (TQD) approach. The key point of this approach is to construct an effective Hamiltonian that drives the dynamics of a system along instantaneous eigenstates of a reference Hamiltonian to reproduce the same final state as that of an adiabatic process within a much shorter time. In this paper, the shortcuts to adiabatic passage are constructed by introducing two auxiliary excited levels in each atom and applying extra cavity modes and classical fields to drive the relevant transitions. Thereby, the three-dimensional entanglement is obtained with a faster rate than that in the adiabatic passage. Moreover, the influences of atomic spontaneous emission and photon loss on the fidelity are discussed by numerical simulation. The results show that the speed of entanglement implementation is greatly improved by the use of adiabatic shortcuts and that this entanglement implementation is robust against decoherence. This will be beneficial to the preparation of high-dimensional entanglement in experiment and provides the necessary conditions for the application of high-dimensional entangled states in quantum information processing.

  6. Efficient shortcuts to adiabatic passage for three-dimensional entanglement generation via transitionless quantum driving

    He, Shuang; Su, Shi-Lei; Wang, Dong-Yang; Sun, Wen-Mei; Bai, Cheng-Hua; Zhu, Ai-Dong; Wang, Hong-Fu; Zhang, Shou

    2016-08-01

    We propose an effective scheme of shortcuts to adiabaticity for generating a three-dimensional entanglement of two atoms trapped in a cavity using the transitionless quantum driving (TQD) approach. The key point of this approach is to construct an effective Hamiltonian that drives the dynamics of a system along instantaneous eigenstates of a reference Hamiltonian to reproduce the same final state as that of an adiabatic process within a much shorter time. In this paper, the shortcuts to adiabatic passage are constructed by introducing two auxiliary excited levels in each atom and applying extra cavity modes and classical fields to drive the relevant transitions. Thereby, the three-dimensional entanglement is obtained with a faster rate than that in the adiabatic passage. Moreover, the influences of atomic spontaneous emission and photon loss on the fidelity are discussed by numerical simulation. The results show that the speed of entanglement implementation is greatly improved by the use of adiabatic shortcuts and that this entanglement implementation is robust against decoherence. This will be beneficial to the preparation of high-dimensional entanglement in experiment and provides the necessary conditions for the application of high-dimensional entangled states in quantum information processing.

  7. Bang-Bang shortcut to adiabaticity in trapped ion quantum simulators

    Yoshimura, Bryce; Balasubramanian, Shankar; Han, Shuyang; Freericks, James

    2016-05-01

    An experimental simulation can prepare a nontrivial ground state via an adiabatic process, however due to experimental constraints this process becomes more and more difficult as the number of ions increase. Instead, we model the bang-bang optimization protocol as a shortcut to adiabaticity in the ground-state preparation of an ion-trap-based quantum simulator. This well known technique in the quantum control community is simple to implement and can be applied without prior knowledge of the Hamiltonian. We apply the bang-bang optimization protocol to the transverse-field Ising model as simulated in a linear Paul trap. We compare our results to a transverse magnetic field that exponential decays and the locally adiabatic approach. The bang-bang protocol produces a significantly higher ground-state probability than the exponential ramp. Although the bang-bang protocol produces a somewhat lower ground-state probability than the locally adiabatic approach, the implementation of the bang-bang protocol is far more simple than the locally adiabatic approach. NSF PHY-1314295.

  8. Transient Particle Energies in Shortcuts to Adiabatic Expansions of Harmonic Traps.

    Cui, Yang-Yang; Chen, Xi; Muga, J G

    2016-05-19

    The expansion of a harmonic potential that holds a quantum particle may be realized without any final particle excitation but much faster than adiabatically via "shortcuts to adiabaticity" (STA). While ideally the process time can be reduced to zero, practical limitations and constraints impose minimal finite times for the externally controlled time-dependent frequency protocols. We examine the role of different time-averaged energies (total, kinetic, potential, nonadiabatic) and of the instantaneous power in characterizing or selecting different protocols. Specifically, we prove a virial theorem for STA processes, set minimal energies (or times) for given times (or energies), and discuss their realizability by means of Dirac impulses or otherwise.

  9. Thermodynamic analysis of combined reforming process using Gibbs energy minimization method: In view of solid carbon formation

    Behzad Nematollahi; Mehran Rezaei; Ebrahim Nemati Lay; Majid Khajenoori

    2012-01-01

    Thermodynamic analysis was applied to study combined partial oxidation and carbon dioxide reforming of methane in view of carbon for-mation.The equilibrium calculations employing the Gibbs energy minimization were performed upon wide ranges of pressure (1-25 atm),temperature (600-1300 K),carbon dioxide to methane ratio (0-2) and oxygen to methane ratio (0-1).The thermodynamic results were compared with the results obtained over a Ru supported catalyst.The results revealed that by increasing the reaction pressure methane conversion decreased.Also it was found that the atmospheric pressure is the preferable pressure for both dry reforming and partial oxidation of methane and increasing the temperature caused increases in both activity of carbon and conversion of methane.The results clearly showed that the addition of O2 to the feed mixture could lead to a reduction of carbon deposition.

  10. Pumped shot noise in adiabatically modulated graphene-based double-barrier structures

    Zhu, Rui; Lai, Maoli

    2011-11-01

    Quantum pumping processes are accompanied by considerable quantum noise. Based on the scattering approach, we investigated the pumped shot noise properties in adiabatically modulated graphene-based double-barrier structures. It is found that compared with the Poisson processes, the pumped shot noise is dramatically enhanced where the dc pumped current changes flow direction, which demonstrates the effect of the Klein paradox.

  11. Quantum-Classical Correspondence of Shortcuts to Adiabaticity

    Okuyama, Manaka; Takahashi, Kazutaka

    2017-04-01

    We formulate the theory of shortcuts to adiabaticity in classical mechanics. For a reference Hamiltonian, the counterdiabatic term is constructed from the dispersionless Korteweg-de Vries (KdV) hierarchy. Then the adiabatic theorem holds exactly for an arbitrary choice of time-dependent parameters. We use the Hamilton-Jacobi theory to define the generalized action. The action is independent of the history of the parameters and is directly related to the adiabatic invariant. The dispersionless KdV hierarchy is obtained from the classical limit of the KdV hierarchy for the quantum shortcuts to adiabaticity. This correspondence suggests some relation between the quantum and classical adiabatic theorems.

  12. Non-adiabatic perturbations in multi-component perfect fluids

    Koshelev, N.A., E-mail: koshna71@inbox.ru [Ulyanovsk State University, Leo Tolstoy str 42, 432970 (Russian Federation)

    2011-04-01

    The evolution of non-adiabatic perturbations in models with multiple coupled perfect fluids with non-adiabatic sound speed is considered. Instead of splitting the entropy perturbation into relative and intrinsic parts, we introduce a set of symmetric quantities, which also govern the non-adiabatic pressure perturbation in models with energy transfer. We write the gauge invariant equations for the variables that determine on a large scale the non-adiabatic pressure perturbation and the rate of changes of the comoving curvature perturbation. The analysis of evolution of the non-adiabatic pressure perturbation has been made for several particular models.

  13. Solving the transport without transit quantum paradox of the spatial adiabatic passage technique

    Benseny, Albert; Oriols, Xavier; Mompart, Jordi

    2011-01-01

    We discuss and solve the transport without transit quantum paradox recently introduced in the context of the adiabatic transport of a single particle or a Bose--Einstein condensate between the two extreme traps of a triple-well potential. To this aim, we address the corresponding quantum dynamics in terms of Bohmian trajectories and show that transport always implies transit through the middle well, in full agreement with the quantum continuity equation. This adiabatic quantum transport presents a very counterintuitive effect: by slowing down the total time duration of the transport process, ultra-high Bohmian velocities are achieved such that, in the limit of perfect adiabaticity, relativistic corrections are needed to properly address the transfer process while avoiding superluminal matter wave propagation.

  14. PLACE OF REFORMS IN WESTERN STRUCTURING PROCESS OF OTTOMAN STATE AND THEIR EFFECT ON MODERNIZATION(1718-1789

    Zabit ACER

    2010-04-01

    Full Text Available When the crackle sounds started to be heard after the middle of the 17th century, that this wasn’t a temporary sound was understood. In order to understood the reason of these illnesses, old laws and sources were being examined and these were being told to the sultans and statesmen who could take the State to a traditional structure. The Ottoman State fell in luxury and dissipation in the pursuit of a tulip in the 18th century. In this peace term, the Ottomans knew Europeans very closely. The Ottoman State’s widening policy gave shape to its State structure and inner order. The Ottoman administrators sent ambassadors to Vienna and Paris after the Treaty of Passarowitz and wanted them to inform themselves not only about politics and diplomacy but also about social and cultural events and interesting things. Europe, which was examined by Ottoman Statesmen with a new eye, was living “Enlightenment Age”. It was understood that in reform studies made in the 18th century the Ottoman remained behind Europe. The effect of the West is clearly seen in these innovation studies. The effect of the West is clearly seen in these innovation studies. Although reforms studies were tried to be made in every area in this term, especially military area reforms were given importance. The Ottoman State stopped its widening policy across Europe and shaped its inner order and State structure.

  15. Liquid and Gaseous Fuel from Waste Plastics by Sequential Pyrolysis and Catalytic Reforming Processes over Indonesian Natural Zeolite Catalysts

    Mochamad Syamsiro

    2014-08-01

    Full Text Available In this study, the performance of several differently treated natural zeolites in a sequential pyrolysis and catalytic reforming of plastic materials i.e. polypropylene (PP and polystyrene (PS were investigated. The experiments were carried out on two stage reactor using semi-batch system. The samples were degraded at 500°C in the pyrolysis reactor and then reformed at 450°C in the catalytic reformer. The results show that the mordenite-type natural zeolites could be used as efficient catalysts for the conversion of PP and PS into liquid and gaseous fuel. The treatment of natural zeolites in HCl solution showed an increase of the surface area and the Si/Al ratio while nickel impregnation increased the activity of catalyst. As a result, liquid product was reduced while gaseous product was increased. For PP, the fraction of gasoline (C5-C12 increased in the presence of catalysts. Natural zeolite catalysts could also be used to decrease the heavy oil fraction (>C20. The gaseous products were found that propene was dominated in all conditions. For PS, propane and propene were the main components of gases in the presence of nickel impregnated natural zeolite catalyst. Propene was dominated in pyrolysis over natural zeolite catalyst. The high quality of gaseous product can be used as a fuel either for driving gas engines or for dual-fuel diesel engine.

  16. Tailor-made Reform

    2006-01-01

    Few people imagined how China would change when the country initiated its reform and opening-up policies almost 28 years ago. Without previous experience, the Chinese are following a trial-and-error approach in pressing ahead with the reform process, exploiting a method of development that seemed suitable to national conditions at the time. In an article published in the 21st Century Business Herald,Lou Jiwei, Vice Minister of Finance, looks back at China's path to revitalize its long-isolated economy. E...

  17. Comment on ``Adiabatic theory for the bipolaron''

    Smondyrev, M. A.; Devreese, J. T.

    1996-05-01

    Comments are given on the application of the Bogoliubov-Tyablikov approach to the bipolaron problem in a recent paper by Lakhno [Phys. Rev. B 51, 3512 (1995)]. This author believes that his model (1) is the translation-invariant adiabatic theory of bipolarons and (2) gives asymptotically exact solutions in the adiabatic limit while the other approaches are considered as either phenomenological or variational in nature. Numerical results by Lakhno are in contradiction with all other papers published on the subject because his model leads to much lower energies. Thus, the author concludes that bipolarons ``are more stable than was considered before.'' We prove that both the analytical and the numerical results presented by Lakhno are wrong.

  18. Ramsey numbers and adiabatic quantum computing.

    Gaitan, Frank; Clark, Lane

    2012-01-06

    The graph-theoretic Ramsey numbers are notoriously difficult to calculate. In fact, for the two-color Ramsey numbers R(m,n) with m, n≥3, only nine are currently known. We present a quantum algorithm for the computation of the Ramsey numbers R(m,n). We show how the computation of R(m,n) can be mapped to a combinatorial optimization problem whose solution can be found using adiabatic quantum evolution. We numerically simulate this adiabatic quantum algorithm and show that it correctly determines the Ramsey numbers R(3,3) and R(2,s) for 5≤s≤7. We then discuss the algorithm's experimental implementation, and close by showing that Ramsey number computation belongs to the quantum complexity class quantum Merlin Arthur.

  19. Ehrenfest's adiabatic hypothesis in Bohr's quantum theory

    Pérez, Enric

    2015-01-01

    It is widely known that Paul Ehrenfest formulated and applied his adiabatic hypothesis in the early 1910s. Niels Bohr, in his first attempt to construct a quantum theory in 1916, used it for fundamental purposes in a paper which eventually did not reach the press. He decided not to publish it after having received the new results by Sommerfeld in Munich. Two years later, Bohr published "On the quantum theory of line-spectra." There, the adiabatic hypothesis played an important role, although it appeared with another name: the principle of mechanical transformability. In the subsequent variations of his theory, Bohr never suppressed this principle completely. We discuss the role of Ehrenfest's principle in the works of Bohr, paying special attention to its relation to the correspondence principle. We will also consider how Ehrenfest faced Bohr's uses of his more celebrated contribution to quantum theory, as well as his own participation in the spreading of Bohr's ideas.

  20. Adiabatic quantum simulation of quantum chemistry.

    Babbush, Ryan; Love, Peter J; Aspuru-Guzik, Alán

    2014-10-13

    We show how to apply the quantum adiabatic algorithm directly to the quantum computation of molecular properties. We describe a procedure to map electronic structure Hamiltonians to 2-body qubit Hamiltonians with a small set of physically realizable couplings. By combining the Bravyi-Kitaev construction to map fermions to qubits with perturbative gadgets to reduce the Hamiltonian to 2-body, we obtain precision requirements on the coupling strengths and a number of ancilla qubits that scale polynomially in the problem size. Hence our mapping is efficient. The required set of controllable interactions includes only two types of interaction beyond the Ising interactions required to apply the quantum adiabatic algorithm to combinatorial optimization problems. Our mapping may also be of interest to chemists directly as it defines a dictionary from electronic structure to spin Hamiltonians with physical interactions.

  1. Adiabatic Quantum Optimization for Associative Memory Recall

    Hadayat eSeddiqi

    2014-12-01

    Full Text Available Hopfield networks are a variant of associative memory that recall patterns stored in the couplings of an Ising model. Stored memories are conventionally accessed as fixed points in the network dynamics that correspond to energetic minima of the spin state. We show that memories stored in a Hopfield network may also be recalled by energy minimization using adiabatic quantum optimization (AQO. Numerical simulations of the underlying quantum dynamics allow us to quantify AQO recall accuracy with respect to the number of stored memories and noise in the input key. We investigate AQO performance with respect to how memories are stored in the Ising model according to different learning rules. Our results demonstrate that AQO recall accuracy varies strongly with learning rule, a behavior that is attributed to differences in energy landscapes. Consequently, learning rules offer a family of methods for programming adiabatic quantum optimization that we expect to be useful for characterizing AQO performance.

  2. Limitations of some simple adiabatic quantum algorithms

    Ioannou, L M; Ioannou, Lawrence M.; Mosca, Michele

    2007-01-01

    Let $H(t)=(1-t/T)H_0 + (t/T)H_1$, $t\\in [0,T]$, be the Hamiltonian governing an adiabatic quantum algorithm, where $H_0$ is diagonal in the Hadamard basis and $H_1$ is diagonal in the computational basis. We prove that $H_0$ and $H_1$ must each have at least two large mutually-orthogonal eigenspaces if the algorithm's running time is to be subexponential in the number of qubits. We also reproduce the optimality proof of Farhi and Gutmann's search algorithm in the context of this adiabatic scheme; because we only consider initial Hamiltonians that are diagonal in the Hadamard basis, our result is slightly stronger than the original.

  3. Finding cliques by quantum adiabatic evolution

    Childs, A M; Goldstone, J; Gutmann, S; Childs, Andrew M.; Farhi, Edward; Goldstone, Jeffrey; Gutmann, Sam

    2002-01-01

    Quantum adiabatic evolution provides a general technique for the solution of combinatorial search problems on quantum computers. We present the results of a numerical study of a particular application of quantum adiabatic evolution, the problem of finding the largest clique in a random graph. An n-vertex random graph has each edge included with probability 1/2, and a clique is a completely connected subgraph. There is no known classical algorithm that finds the largest clique in a random graph with high probability and runs in a time polynomial in n. For the small graphs we are able to investigate (n <= 18), the quantum algorithm appears to require only a quadratic run time.

  4. Health care reforms

    Marušič Dorjan

    2016-09-01

    Full Text Available In large systems, such as health care, reforms are underway constantly. The article presents a definition of health care reform and factors that influence its success. The factors being discussed range from knowledgeable personnel, the role of involvement of international experts and all stakeholders in the country, the importance of electoral mandate and governmental support, leadership and clear and transparent communication. The goals set need to be clear, and it is helpful to have good data and analytical support in the process. Despite all debates and experiences, it is impossible to clearly define the best approach to tackle health care reform due to a different configuration of governance structure, political will and state of the economy in a country.

  5. Health care reforms.

    Marušič, Dorjan; Prevolnik Rupel, Valentina

    2016-09-01

    In large systems, such as health care, reforms are underway constantly. The article presents a definition of health care reform and factors that influence its success. The factors being discussed range from knowledgeable personnel, the role of involvement of international experts and all stakeholders in the country, the importance of electoral mandate and governmental support, leadership and clear and transparent communication. The goals set need to be clear, and it is helpful to have good data and analytical support in the process. Despite all debates and experiences, it is impossible to clearly define the best approach to tackle health care reform due to a different configuration of governance structure, political will and state of the economy in a country.

  6. The Danish Police Reform

    Degnegaard, Rex; Mark, Sofie

    2013-01-01

    Many cases highlight the need for responsible management in regards to transparency of organisations and involvement of stakeholders in decisions that will impact citizens, patients, customers and/or clients. Often these cases take an outside-in approach as they illustrate why it is essential...... for organisations to work with transparency and involvement with the aim of upholding and further developing a social responsibility to their environment. This case on the other hand takes an inside-out perspective on social responsibility by illustrating how social responsibility is necessary for public......, the reform process was problematic and the following years were challenging and filled with changes and turbulence. Media, politicians and the police itself directed heavy criticism towards the effects of the reform and reviews of the reform as well as of the work of the police were carried out resulting...

  7. Interpolation approach to Hamiltonian-varying quantum systems and the adiabatic theorem

    Pan, Yu; James, Matthew R. [Australian National University, Research School of Engineering, Canberra (Australia); Miao, Zibo [The University of Melbourne, Department of Electrical and Electronic Engineering, Melbourne (Australia); Amini, Nina H. [CNRS, Laboratoire des Signaux et Systemes (L2S) Supelec, Gif-Sur-Yvette (France); Ugrinovskii, Valery [University of New South Wales at ADFA, School of Engineering and Information Technology, Canberra (Australia)

    2015-12-15

    Quantum control could be implemented by varying the system Hamiltonian. According to adiabatic theorem, a slowly changing Hamiltonian can approximately keep the system at the ground state during the evolution if the initial state is a ground state. In this paper we consider this process as an interpolation between the initial and final Hamiltonians. We use the mean value of a single operator to measure the distance between the final state and the ideal ground state. This measure resembles the excitation energy or excess work performed in thermodynamics, which can be taken as the error of adiabatic approximation. We prove that under certain conditions, this error can be estimated for an arbitrarily given interpolating function. This error estimation could be used as guideline to induce adiabatic evolution. According to our calculation, the adiabatic approximation error is not linearly proportional to the average speed of the variation of the system Hamiltonian and the inverse of the energy gaps in many cases. In particular, we apply this analysis to an example in which the applicability of the adiabatic theorem is questionable. (orig.)

  8. Integration of Methane Steam Reforming and Water Gas Shift Reaction in a Pd/Au/Pd-Based Catalytic Membrane Reactor for Process Intensification

    Castro-Dominguez, Bernardo; Mardilovich, Ivan P.; Ma, Liang-Chih; Ma, Rui; Dixon, Anthony G.; Kazantzis, Nikolaos K.; Ma, Yi Hua

    2016-01-01

    Palladium-based catalytic membrane reactors (CMRs) effectively remove H2 to induce higher conversions in methane steam reforming (MSR) and water-gas-shift reactions (WGS). Within such a context, this work evaluates the technical performance of a novel CMR, which utilizes two catalysts in series, rather than one. In the process system under consideration, the first catalyst, confined within the shell side of the reactor, reforms methane with water yielding H2, CO and CO2. After reforming is completed, a second catalyst, positioned in series, reacts with CO and water through the WGS reaction yielding pure H2O, CO2 and H2. A tubular composite asymmetric Pd/Au/Pd membrane is situated throughout the reactor to continuously remove the produced H2 and induce higher methane and CO conversions while yielding ultrapure H2 and compressed CO2 ready for dehydration. Experimental results involving (i) a conventional packed bed reactor packed (PBR) for MSR, (ii) a PBR with five layers of two catalysts in series and (iii) a CMR with two layers of two catalysts in series are comparatively assessed and thoroughly characterized. Furthermore, a comprehensive 2D computational fluid dynamics (CFD) model was developed to explore further the features of the proposed configuration. The reaction was studied at different process intensification-relevant conditions, such as space velocities, temperatures, pressures and initial feed gas composition. Finally, it is demonstrated that the above CMR module, which was operated for 600 h, displays quite high H2 permeance and purity, high CH4 conversion levels and reduced CO yields. PMID:27657143

  9. Integration of Methane Steam Reforming and Water Gas Shift Reaction in a Pd/Au/Pd-Based Catalytic Membrane Reactor for Process Intensification

    Bernardo Castro-Dominguez

    2016-09-01

    Full Text Available Palladium-based catalytic membrane reactors (CMRs effectively remove H2 to induce higher conversions in methane steam reforming (MSR and water-gas-shift reactions (WGS. Within such a context, this work evaluates the technical performance of a novel CMR, which utilizes two catalysts in series, rather than one. In the process system under consideration, the first catalyst, confined within the shell side of the reactor, reforms methane with water yielding H2, CO and CO2. After reforming is completed, a second catalyst, positioned in series, reacts with CO and water through the WGS reaction yielding pure H2O, CO2 and H2. A tubular composite asymmetric Pd/Au/Pd membrane is situated throughout the reactor to continuously remove the produced H2 and induce higher methane and CO conversions while yielding ultrapure H2 and compressed CO2 ready for dehydration. Experimental results involving (i a conventional packed bed reactor packed (PBR for MSR, (ii a PBR with five layers of two catalysts in series and (iii a CMR with two layers of two catalysts in series are comparatively assessed and thoroughly characterized. Furthermore, a comprehensive 2D computational fluid dynamics (CFD model was developed to explore further the features of the proposed configuration. The reaction was studied at different process intensification-relevant conditions, such as space velocities, temperatures, pressures and initial feed gas composition. Finally, it is demonstrated that the above CMR module, which was operated for 600 h, displays quite high H2 permeance and purity, high CH4 conversion levels and reduced CO yields.

  10. Adiabatic asymmetric scattering of atoms in the field of a standing wave

    Hakobyan, M V; Ishkhanyan, A M

    2015-01-01

    A model of the asymmetric coherent scattering process (caused by initial atomic wave-packet splitting in the momentum space) taking place at the large detuning and adiabatic course of interaction for an effective two-state system interacting with a standing wave of laser radiation is discussed. We show that the same form of initial wave-packet splitting may lead to different, in general, diffraction patterns for opposite, adiabatic and resonant, regimes of the standing-wave scattering. We show that the scattering of the Gaussian wave packet in the adiabatic case presents refraction (a limiting form of the asymmetric scattering) in contrast to the bi-refringence (the limiting case of the high-order narrowed scattering) occurring in the resonant scattering.

  11. Demonstration of direct internal reforming for MCFC power plants

    Aasberg-Petersen, K.; Christensen, P.S.; Winther, S.K. [HALDOR TOPSOE A/S, Lynby (Denmark)] [and others

    1996-12-31

    The conversion of methane into hydrogen for an MCFC by steam reforming is accomplished either externally or internally in the stack. In the case of external reforming the plant electrical efficiency is 5% abs. lower mainly because more parasitic power is required for air compression for stack cooling. Furthermore, heat produced in the stack must be transferred to the external reformer to drive the endothermic steam reforming reaction giving a more complex plant lay-out. A more suitable and cost effective approach is to use internal steam reforming of methane. Internal reforming may be accomplished either by Indirect Internal Reforming (DIR) and Direct Internal Reforming (DIR) in series or by DIR-only as illustrated. To avoid carbon formation in the anode compartment higher hydrocarbons in the feedstock are converted into hydrogen, methane and carbon oxides by reaction with steam in ail adiabatic prereformer upstream the fuel cell stack. This paper discusses key elements of the desire of both types of internal reforming and presents data from pilot plants with a combined total of more than 10,000 operating hours. The project is being carried out as part of the activities of the European MCFC Consortium ARGE.

  12. Non-adiabatic effects in near-adiabatic mixed-field orientation and alignment

    Maan, Anjali; Ahlawat, Dharamvir Singh; Prasad, Vinod

    2016-11-01

    We present a theoretical study of the impact of a pair of moderate electric fields tilted an angle with respect to one another on a molecule. As a prototype, we consider a molecule with large rotational constant (with corresponding small rotational period) and moderate dipole moment. Within rigid-rotor approximation, the time-dependent Schrodinger equation is solved using fourth-order Runge-Kutta method. We have analysed that lower rotational states are significantly influenced by variation in pulse durations, the tilt angle between the fields and also on the electric field strengths. We also suggest a control scheme of how the rotational dynamics, orientation and alignment of a molecule can be enhanced by a combination of near-adiabatic pulses in comparision to non-adiabatic or adiabatic pulses.

  13. Shortcut to adiabaticity for an anisotropic unitary Fermi gas

    Deng, Shujin; Yu, Qianli; Wu, Haibin

    2016-01-01

    Coherent control of complex quantum systems is a fundamental requirement in quantum information processing and engineering. Recently developed notion of shortcut to adiabaticity (STA) has spawned intriguing prospects. So far, the most experimental investigations of STA are implemented in the ideal thermal gas or the weakly interacting ultracold Bose gases. Here we report the first demonstration of a many-body STA in a 3D anisotropically trapped unitary Fermi gas. A new dynamical scaling law is demonstrated on such a strongly interacting quantum gas. By simply engineering the frequency aspect ratio of a harmonic trap, the dynamics of the gas can be manipulated and the many-body state can be transferred adiabatically from one stationary state to another one in short time scale without the excitation. The universal scaling both for non-interacting and unitary Fermi gas is also verified. This could be very important for future many-body quantum engineering and the exploration of the fundamental law of the thermod...

  14. 博洛尼亚进程中的土耳其高等教育改革%Research on Turkey Higher Education Reform in Bologna Process

    李政云

    2012-01-01

    Since becoming a signatory country of Bologna Process, a series of reforms have been introduced in Turkey higher education. Firstly, deepening the reform of degree structures to realize its compatibility with other European countries; secondly, launching Erasmus Programme and signing bilateral collaboration agreements to strengthen personnel mobility and diploma recognition; thirdly, laying out the frame of Academic Assessment and Quality Development in Higher Education Institutions to establish a national quality assur- ance system; fourthly, reforming admission mechanisms and providing adequate student services to increase equity in higher education; fifthly, unveiling Lifelong Learning Strategy Document and Strategy Action Plan to advance the development of lifelong learning. During the reform process, Turkey continues the tradition of a hierarchical structure whose charac teristic is up-to-down; on the other hand, it begins to take attention to stakeholders" opinions through some organizational arrangement.%土耳其2001年成为博洛尼亚进程签署国之后,在高等教育领域进行了一系列改革,诸如深化学位结构改革,实现学位结构的进一步对等;启动伊拉斯莫项目及与其他国家签订高等教育双边合作协议,进一步加强人员流动与相关资格文凭的互认;制定"高等院校学术评估与质量发展"框架,建立全国性的高等教育质量保障机制;改革高校招生机制以及为学生提供更多服务,推进高等教育公平;出台《终身学习战略文件与行动计划》,推进终身教育发展等等。在改革进程中,土耳其一方面继续其等级制的管理传统,采用自上而下的决策路径,同时开始重视通过组织结构的设置以协调各方的利益表达。

  15. Reform and Backlash to Reform

    Hougaard Jensen, Svend E.; Hagen Jørgensen, Ole

    Using a stochastic general equilibrium model with overlapping generations, this paper studies (i) the effects on both extensive and intensive labor supply responses to changes in fertility rates, and (ii) the potential of a retirement reform to mitigate the effects of fertility changes on labor...

  16. La sociedad civil en el proceso de reformas a la Corte Suprema Argentina Civil Society in the Process of Reforms of the Argentinean Supreme Court

    Alba M. Ruibal

    2008-12-01

    Full Text Available Este artículo analiza la incidencia de la sociedad civil y su interacción con actores gubernamentales en el proceso de reformas a la Corte Suprema argentina iniciado en 2003. Se explica que la movilización social y la acción de organizaciones civiles a favor de un cambio en la Corte fueron factores determinantes en la cofiguración de los incentivos del Poder Ejecutivo para iniciar este proceso de reforma, así como en el contenido y la forma de los cambios realizados.This article analyzes the role of civil society and its interaction with government actors in the process of the reform of the Argentine Supreme Court initiated in 2003. It explains that social mobilization and the action of NGOs were determining factors in the configuration of incentives for the Executive Branch to initiate this process of reform, as well as in the content and form of the changes made.

  17. Reformation process of the neuronal template for nestmate-recognition cues in the carpenter ant Camponotus floridanus.

    Leonhardt, Sara Diana; Brandstaetter, Andreas Simon; Kleineidam, Christoph Johannes

    2007-09-01

    Ants use cuticular hydrocarbons (CHC-profiles) as multicomponent recognition cues to identify colony members (nestmates). Recognition cues (label) are thought to be perceived during ant-ant encounters and compared to a neuronal template that represents the colony label. Over time, the CHC-profile may change, and the template is adjusted accordingly. A phenotype mismatch between label and template, as happens with CHC-profiles of foreign workers (non-nestmates), frequently leads to aggressive behavior. We investigated the template reformation in workers of the carpenter ant Camponotus floridanus by masking their antennae with postpharyngeal gland (PPG) extracts from nestmates or non-nestmates. The behavioral response of manipulated workers encountering unmanipulated workers was measured independently after 2 and after 15 h. After 2 h of incubation, workers treated with either of the two PPG-extracts showed low aggression towards nestmates and high aggression towards non-nestmates. In contrast, after 15 h of incubation, workers treated with non-nestmate PPG-extract showed low aggression towards both nestmates and non-nestmates. The slow (>2 h) adjustment of the template indicates a reformation localized in the central nervous system rather than in chemosensory neurons. In addition, our data show that template adjustment to a new CHC-profile does not impair the assessment of the old CHC-profile as nestmate label.

  18. Applications of solar reforming technology

    Spiewak, I. [Weizmann Inst. of Science, Rehovoth (Israel); Tyner, C.E. [Sandia National Labs., Albuquerque, NM (United States); Langnickel, U. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Koeln (Germany)

    1993-11-01

    Research in recent years has demonstrated the efficient use of solar thermal energy for driving endothermic chemical reforming reactions in which hydrocarbons are reacted to form synthesis gas (syngas). Closed-loop reforming/methanation systems can be used for storage and transport of process heat and for short-term storage for peaking power generation. Open-loop systems can be used for direct fuel production; for production of syngas feedstock for further processing to specialty chemicals and plastics and bulk ammonia, hydrogen, and liquid fuels; and directly for industrial processes such as iron ore reduction. In addition, reforming of organic chemical wastes and hazardous materials can be accomplished using the high-efficiency destruction capabilities of steam reforming. To help identify the most promising areas for future development of this technology, we discuss in this paper the economics and market potential of these applications.

  19. 工业级催化重整装置的全流程模拟与优化%Modeling, Simulation and Optimization of a Whole Industrial Catalytic Naphtha Reforming Process on Aspen Plus Platform

    侯卫锋; 苏宏业; 胡永有; 褚健

    2006-01-01

    A new 18-lump kinetic model for naphtha catalytic reforming reactions is discussed. By developing this model as a user module, a whole industrial continuous catalytic reforming process is simulated on Aspen plus plat form. The technique utilizes the strong databases, complete sets of modules, and flexible simulation tools of the Aspen plus system and retains the characteristics of the proposed kinetic model. The calculated results are in fair agreement with the actual operating data. Based on the model of the whole reforming process, the process is optimized and the optimization results are tested in the actual industrial unit for about two months. The test shows that the process profit increases about 1000yuan·h-1 averagely, which is close to the calculated result.

  20. Adiabatic Regularization for Gauge Field and the Conformal Anomaly

    Chu, Chong-Sun

    2016-01-01

    We construct and provide the adiabatic regularization method for a $U(1)$ gauge field in a conformally flat spacetime by quantizing in the canonical formalism the gauge fixed $U(1)$ theory with mass terms for the gauge fields and the ghost fields. We show that the adiabatic expansion for the mode functions and the adiabatic vacuum can be defined in a similar way using WKB-type solutions as the scalar fields. As an application of the adiabatic method, we compute the trace of the energy momentum tensor and reproduces the known result for the conformal anomaly obtained by the other regularization methods. The availability of the adiabatic expansion scheme for gauge field allows one to study the renormalization of the de-Sitter space maximal superconformal Yang-Mills theory using the adiabatic regularization method.

  1. The Danish school reform

    Bager, Ann; Mølholm, Martin; Horsbøl, Anders

    (Latour), e.g. civil service and municipal practices and texts, into the organizational practices of two local schools. On the basis of these analyses, we will establish a participatory process in which local actors are involved in the co-creation of new plurivocal and egalitarian dialogue designs......The paper presents a methodological framework for the study of the discursive emergence of the recent Danish School reform (2014). The framework will enable discourse scholars to hold an actively involved position in changing and furthering plurivocal processes of translations, negotiations...... and implementation of the reform. The framework is operationalized through research-based participatory collaborative processes involving local actors in two Danish public schools. It interlinks diverse discourse strategies and perceptive distances that traditionally belong to separate branches within discourse...

  2. Adiabatic passage in the presence of noise

    Noel, T; Kurz, N; Shu, G; Wright, J; Blinov, B B

    2011-01-01

    We report on an experimental investigation of rapid adiabatic passage (RAP) in a trapped barium ion system. RAP is implemented on the transition from the $6S_{1/2}$ ground state to the metastable $5D_{5/2}$ level by applying a laser at 1.76 $\\mu$m. We focus on the interplay of laser frequency noise and laser power in shaping the effectiveness of RAP, which is commonly assumed to be a robust tool for high efficiency population transfer. However, we note that reaching high state transfer fidelity requires a combination of small laser linewidth and large Rabi frequency.

  3. Shortcuts to adiabaticity for quantum annealing

    Takahashi, Kazutaka

    2017-01-01

    We study the Ising Hamiltonian with a transverse field term to simulate the quantum annealing. Using shortcuts to adiabaticity, we design the time dependence of the Hamiltonian. The dynamical invariant is obtained by the mean-field ansatz, and the Hamiltonian is designed by the inverse engineering. We show that the time dependence of physical quantities such as the magnetization is independent of the speed of the Hamiltonian variation in the infinite-range model. We also show that rotating transverse magnetic fields are useful to achieve the ideal time evolution.

  4. Adiabatic Wave-Particle Interaction Revisited

    Dewar, R L; 10.1585/pfr.4.001

    2009-01-01

    In this paper we calculate and visualize the dynamics of an ensemble of electrons trapping in an electrostatic wave of slowly increasing amplitude, illustrating that, despite disordering of particles in angle during the trapping transition as they pass close to X-points, there is still an adiabatic invariant for the great majority of particles that allows the long-time distribution function to be predicted. Possible application of this approach to recent work on the nonlinear frequency shift of a driven wave is briefly discussed.

  5. Adiabatic quantum algorithm for search engine ranking

    Garnerone, Silvano; Lidar, Daniel A

    2011-01-01

    We propose an adiabatic quantum algorithm to evaluate the PageRank vector, the most widely used tool in ranking the relative importance of internet pages. We present extensive numerical simulations which provide evidence that this quantum algorithm outputs any component of the PageRank vector-and thus the ranking of the corresponding webpage-in a time which scales polylogarithmically in the number of webpages. This would constitute an exponential speed-up with respect to all known classical algorithms designed to evaluate the PageRank.

  6. Quantum Adiabatic Evolution Algorithms with Different Paths

    Farhi, E; Gutmann, S; Farhi, Edward; Goldstone, Jeffrey; Gutmann, Sam

    2002-01-01

    In quantum adiabatic evolution algorithms, the quantum computer follows the ground state of a slowly varying Hamiltonian. The ground state of the initial Hamiltonian is easy to construct; the ground state of the final Hamiltonian encodes the solution of the computational problem. These algorithms have generally been studied in the case where the "straight line" path from initial to final Hamiltonian is taken. But there is no reason not to try paths involving terms that are not linear combinations of the initial and final Hamiltonians. We give several proposals for randomly generating new paths. Using one of these proposals, we convert an algorithmic failure into a success.

  7. Generalized Ramsey numbers through adiabatic quantum optimization

    Ranjbar, Mani; Macready, William G.; Clark, Lane; Gaitan, Frank

    2016-09-01

    Ramsey theory is an active research area in combinatorics whose central theme is the emergence of order in large disordered structures, with Ramsey numbers marking the threshold at which this order first appears. For generalized Ramsey numbers r( G, H), the emergent order is characterized by graphs G and H. In this paper we: (i) present a quantum algorithm for computing generalized Ramsey numbers by reformulating the computation as a combinatorial optimization problem which is solved using adiabatic quantum optimization; and (ii) determine the Ramsey numbers r({{T}}m,{{T}}n) for trees of order m,n = 6,7,8, most of which were previously unknown.

  8. Adiabatic quantum computation and quantum phase transitions

    Latorre, J I; Latorre, Jose Ignacio; Orus, Roman

    2003-01-01

    We analyze the ground state entanglement in a quantum adiabatic evolution algorithm designed to solve the NP-complete Exact Cover problem. The entropy of entanglement seems to obey linear and universal scaling at the point where the mass gap becomes small, suggesting that the system passes near a quantum phase transition. Such a large scaling of entanglement suggests that the effective connectivity of the system diverges as the number of qubits goes to infinity and that this algorithm cannot be efficiently simulated by classical means. On the other hand, entanglement in Grover's algorithm is bounded by a constant.

  9. Exact invariants and adiabatic invariants of the singular Lagrange system

    陈向炜; 李彦敏

    2003-01-01

    Based on the theory of symmetries and conserved quantities of the singular Lagrange system,the perturbations to the symmetries and adiabatic invariants of the singular Lagrange systems are discussed.Firstly,the concept of higher-order adiabatic invariants of the singular Lagrange system is proposed.Then,the conditions for the existence of the exact invariants and adiabatic invariants are proved,and their forms are given.Finally,an example is presented to illustrate these results.

  10. Generating shortcuts to adiabaticity in quantum and classical dynamics

    Jarzynski, Christopher

    2013-01-01

    Transitionless quantum driving achieves adiabatic evolution in a hurry, using a counter-diabatic Hamiltonian to stifle non-adiabatic transitions. Here this strategy is cast in terms of a generator of adiabatic transport, leading to a classical analogue: dissipationless classical driving. For the single-particle piston, this approach yields simple and exact expressions for both the classical and quantal counter-diabatic terms. These results are further generalized to even-power-law potentials in one degree of freedom.

  11. Correlated mixtures of adiabatic and isocurvature cosmological perturbations

    Langlois, D; Langlois, David; Riazuelo, Alain

    2000-01-01

    We examine the consequences of the existence of correlated mixtures of adiabatic and isocurvature perturbations on the CMB and large scale structure. In particular, we consider the four types of ``elementary'' totally correlated hybrid initial conditions, where only one of the four matter species (photons, baryons, neutrinos, CDM) deviates from adiabaticity. We then study the height and position of the acoustic peaks with respect to the large angular scale plateau as a function of the isocurvature to adiabatic ratio.

  12. A Cornerstone of Health Reform

    2009-01-01

    In order to ensure fair and affordable health services for all Chinese citizens and to set up a healthcare system that covers both urban and rural residents, the Chinese Government put forward a strategic task of deepening the healthcare system reform. The major objective of this reform is to provide medical service as a public service. In an interview with Beijing-based Guangming Daily, Li Weiping, a fellow researcher at the Institute of Medicine and Economy under the Ministry of Health, says that public hospitals are key to making this reform work and medical workers will need to drive this process forward.

  13. Adiabatic Improved Efficient Charge Recovery Logic for Low Power CMOS Logic

    Prof. Mukesh Tiwar

    2012-08-01

    Full Text Available Power dissipation becoming a limiting factor in VLSI circuits and systems. Due to relatively high complexity of VLSI systems used in various applications, the power dissipation in CMOS inverter, arises from its switching activity, which is mainly influenced by the supply voltage and effective capacitance. The low-power requirements of present electronic systems have challenged the scientific research towards the study of technological, architectural and circuital solutions that allow a reduction of the energy dissipated by an electronic circuit. One of the main causes of energy dissipation in CMOS circuits is due to the charging and discharging of the node capacitances of the circuits, present both as a load and as parasitic. Such part of the total power dissipated by a circuit is called dynamic power. In order to reduce the dynamic power, an alternative approach to the traditional techniques of power consumption reduction, named adiabatic switching technique is use. Adiabatic switching is an approach to low-power digital circuits that differs fundamentally from other practical low-power techniques. The term adiabatic comes from thermodynamics, used to describe a process in which there is no exchange of heat with the environment. When adiabatic switching is used, the signal energies stored on circuit capacitances may be recycled instead of dissipated as heat. The adiabatic switching technique can achieve very low power dissipation, but at the expense of circuit complexity. Adiabatic logic offers a way to reuse the energy stored in the load capacitors rather than the traditional way of discharging the load capacitors to the ground and wasting this energy. Power reduction is achieved by recovering the energy in the recover phase of the supply clock.

  14. 催化重整过程的多目标优化%Multiobjective Optimization of the Industrial Naphtha Catalytic Reforming Process

    侯卫锋; 苏宏业; 牟盛静; 褚健

    2007-01-01

    In this article, a multiobjective optimization strategy for an industrial naphtha continuous catalytic reforming process that aims to obtain aromatic products is proposed. The process model is based on a 20-lumped kinetics reaction network and has been proved to be quite effective in terms of industrial application. The primary objectives include maximization of.yield of the aromatics and minimization of the yield of heavy aromatics. Four reactor inlet temperatures, reaction pressure, and hydrogen-to-oil molar ratio are selected as the decision variables. A genetic algorithm,which is proposed by the authors and named as the neighborhood and archived genetic algorithm (NAGA), is applied to solve this mulfiobjective optimization problem. The relations between each decision variable and the two objectives are also proposed and used for choosing a suitable solution from the obtained Pareto set.

  15. Teaching Reform and Practice of Manufacture Techniques of Process Equipment%过程装备制造工艺教学改革实践

    王中辉

    2012-01-01

    过程装备制造工艺是过程装备与控制工程专业的一门重要的专业课,针对过程装备制造工艺课程的地位和特点,从教材的选择、教学内容、教学方式和考核方式入手,对该课程进行了一系列的改革,在教学实践中获得了良好的教学效果。%Manufacture Techniques of Process Equipment was a key course of the specialty of the Process Equipment & Control Engineering. According to the characteristics and status of the course, the choice of teaching content and improvement of teaching methods and reform of the examination were probed and good effect was achieved in the teaching practice.

  16. A quantum search algorithm based on partial adiabatic evolution

    Zhang Ying-Yu; Hu He-Ping; Lu Song-Feng

    2011-01-01

    This paper presents and implements a specified partial adiabatic search algorithm on a quantum circuit. It studies the minimum energy gap between the first excited state and the ground state of the system Hamiltonian and it finds that, in the case of M=1, the algorithm has the same performance as the local adiabatic algorithm. However, the algorithm evolves globally only within a small interval, which implies that it keeps the advantages of global adiabatic algorithms without losing the speedup of the local adiabatic search algorithm.

  17. Magnesium Diboride Superconducting Coils for Adiabatic Demagnetization Refrigerators (ADR's) Project

    National Aeronautics and Space Administration — For Adiabatic Demagnetization Refrigerators (ADRs) in space applications, it is desirable to have very light weight, small diameter, high current density...

  18. Ways for the CCP to Promote the Construction of Anti-corrup-tion in the Process of Reform---Theoretical Research on the Relation Between Reform and Corruption-governance%中共如何在改革进程中推进反腐廉政建设--关于改革与腐败治理关系的理论思考

    李斌雄; 姜向红

    2015-01-01

    The gradual deepening of reform, the rapid economic growth and the spread of corruption co-exist in China during the 30 years since the implementation of the reform and opening-up policy. Academic circles at home and abroad have devel-oped various theories to explain the historical phenomenon.“Double paradox”is a typical one among them. As is shown in the historical process of reform in the new period, reforms is a process to break the inherent interest structure, and the difficulty of reform lies in the areas where corruption is most likely to occur. To fight against corruption, we must correctly handle the rela-tionship among reform, development and anti-corruption, which can guarantee the stability of reform and development. Mean-while, reform is a fundamental path for the prevention of corruption. The construction of anti-corruption and the comprehensive deepening of reform should be given synchronized consideration, deployment and implementation so as to safeguard the smooth promotion of reform. What’s more, we should be guided by important issues, unceasingly improve our ability to construct an-ti-corruption, strengthen the top-level design and overall scheme, and connect anti-corruption prevention with polices and reg-ulations of reform. Last, we should promote reform on the basis of the rule of law, prevent the possible conflicts of interest from changing into real corruptive behaviors and strengthen the supervision of reform. In this way, we can ensure the improvement and achievement of our reform.%改革开放30多年来,中国出现改革逐步深化、经济快速增长与腐败现象蔓延并存的历史现象。国内外学术界对这种改革、发展与腐败互动关系的现象存在多种理论解释,其中比较有代表性就是“双重悖论”。新时期的改革历史进程表明,改革是打破固有利益格局的过程,改革的重难点领域往往是腐败现象易发高发的区域。反腐廉政建设必须正确处

  19. Quantum Adiabatic Algorithms and Large Spin Tunnelling

    Boulatov, A.; Smelyanskiy, V. N.

    2003-01-01

    We provide a theoretical study of the quantum adiabatic evolution algorithm with different evolution paths proposed in this paper. The algorithm is applied to a random binary optimization problem (a version of the 3-Satisfiability problem) where the n-bit cost function is symmetric with respect to the permutation of individual bits. The evolution paths are produced, using the generic control Hamiltonians H (r) that preserve the bit symmetry of the underlying optimization problem. In the case where the ground state of H(0) coincides with the totally-symmetric state of an n-qubit system the algorithm dynamics is completely described in terms of the motion of a spin-n/2. We show that different control Hamiltonians can be parameterized by a set of independent parameters that are expansion coefficients of H (r) in a certain universal set of operators. Only one of these operators can be responsible for avoiding the tunnelling in the spin-n/2 system during the quantum adiabatic algorithm. We show that it is possible to select a coefficient for this operator that guarantees a polynomial complexity of the algorithm for all problem instances. We show that a successful evolution path of the algorithm always corresponds to the trajectory of a classical spin-n/2 and provide a complete characterization of such paths.

  20. The genesis of adiabatic shear bands

    Landau, P.; Osovski, S.; Venkert, A.; Gärtnerová, V.; Rittel, D.

    2016-11-01

    Adiabatic shear banding (ASB) is a unique dynamic failure mechanism that results in an unpredicted catastrophic failure due to a concentrated shear deformation mode. It is universally considered as a material or structural instability and as such, ASB is hardly controllable or predictable to some extent. ASB is modeled on the premise of stability analyses. The leading paradigm is that a competition between strain (rate) hardening and thermal softening determines the onset of the failure. It was recently shown that microstructural softening transformations, such as dynamic recrystallization, are responsible for adiabatic shear failure. These are dictated by the stored energy of cold work, so that energy considerations can be used to macroscopically model the failure mechanism. The initial mechanisms that lead to final failure are still unknown, as well as the ASB formation mechanism(s). Most of all - is ASB an abrupt instability or rather a gradual transition as would be dictated by microstructural evolutions? This paper reports thorough microstructural characterizations that clearly show the gradual character of the phenomenon, best described as a nucleation and growth failure mechanism, and not as an abrupt instability as previously thought. These observations are coupled to a simple numerical model that illustrates them.

  1. The Finish Municipal Reform

    Pekka Kettunen

    2015-06-01

    Full Text Available The article aims at evaluating the municipal amalgamation process as a way of reforming local government, by two criteria – efficiency in service provision and level of democracy. Those issues are applied onto a Finnish case study, as amalgamation is more common in Northern Europe. The author gives a review of amalgamation studies in the world and of the extensive evaluation reports of amalgamation reform in Finland. The paper examines amalgamation policy from two perspectives – from the instrumental or goal-oriented view and from the process aspect. The findings on the relatively high number of instances of amalgamation in Finland are the following: the main process-driving factors were political parties that mostly supported the reform and the underlying urge to construct larger entities which made municipalities take part in the process. The level of efficiency in the New, amalgamated municipalities is not necessarily higher, as efficient service provision can be found both in small and large municipalities. Efficiency is more determined by the dynamics of a municipal economy while the size of a municipality alone does not make a difference. As amalgamations change the nature of local political life they affect democracy both positively and negatively.

  2. Green tax reform and competitiveness

    Koskela, Erkki; Schöb, Ronnie; Sinn, Hans-Werner

    2000-01-01

    This paper develops a model of a small open economy that produces an export good with domestic labour and imported energy and is stuck in an unemployment situation resulting from an excessive fixed net-of-tax wage rate. We study a revenue-neutral green tax reform that substitutes energy for wage taxes. A moderate green tax reform will boost employment, improve welfare, and increase the economy's competitiveness. The driving force behind these results is the technological substitution process ...

  3. Adiabatic quantum pump in a zigzag graphene nanoribbon junction

    张林

    2015-01-01

    The adiabatic electron transport is theoretically studied in a zigzag graphene nanoribbon (ZGNR) junction with two time-dependent pumping electric fields. By modeling a ZGNR p–n junction and applying the Keldysh Green’s function method, we find that a pumped charge current is flowing in the device at a zero external bias, which mainly comes from the photon-assisted tunneling process and the valley selection rule in an even-chain ZGNR junction. The pumped charge current and its ON and OFF states can be efficiently modulated by changing the system parameters such as the pumping frequency, the pumping phase difference, and the Fermi level. A ferromagnetic ZGNR device is also studied to generate a pure spin current and a fully polarized spin current due to the combined spin pump effect and the valley valve effect. Our finding might pave the way to manipulate the degree of freedom of electrons in a graphene-based electronic device.

  4. Differential geometric treewidth estimation in adiabatic quantum computation

    Wang, Chi; Jonckheere, Edmond; Brun, Todd

    2016-10-01

    The D-Wave adiabatic quantum computing platform is designed to solve a particular class of problems—the Quadratic Unconstrained Binary Optimization (QUBO) problems. Due to the particular "Chimera" physical architecture of the D-Wave chip, the logical problem graph at hand needs an extra process called minor embedding in order to be solvable on the D-Wave architecture. The latter problem is itself NP-hard. In this paper, we propose a novel polynomial-time approximation to the closely related treewidth based on the differential geometric concept of Ollivier-Ricci curvature. The latter runs in polynomial time and thus could significantly reduce the overall complexity of determining whether a QUBO problem is minor embeddable, and thus solvable on the D-Wave architecture.

  5. 30 years of reform of China’s state-owned asset management system

    黄速建; 金书娟

    2009-01-01

    Reform of China’s state-owned asset management system is an important component of China’s economic system reform,but also a key factor in rejuvenating the national economy.In this article,the authors analyzed the background of the reform,summarized the reform process and discussed related question on how to deepen the reform.

  6. Adiabat-shaping in indirect drive inertial confinement fusion

    Baker, K. L.; Robey, H. F.; Milovich, J. L.; Jones, O. S.; Smalyuk, V. A.; Casey, D. T.; MacPhee, A. G.; Pak, A.; Celliers, P. M.; Clark, D. S.; Landen, O. L.; Peterson, J. L.; Berzak-Hopkins, L. F.; Weber, C. R.; Haan, S. W.; Döppner, T. D.; Dixit, S.; Hamza, A. V.; Jancaitis, K. S.; Kroll, J. J. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); and others

    2015-05-15

    Adiabat-shaping techniques were investigated in indirect drive inertial confinement fusion experiments on the National Ignition Facility as a means to improve implosion stability, while still maintaining a low adiabat in the fuel. Adiabat-shaping was accomplished in these indirect drive experiments by altering the ratio of the picket and trough energies in the laser pulse shape, thus driving a decaying first shock in the ablator. This decaying first shock is designed to place the ablation front on a high adiabat while keeping the fuel on a low adiabat. These experiments were conducted using the keyhole experimental platform for both three and four shock laser pulses. This platform enabled direct measurement of the shock velocities driven in the glow-discharge polymer capsule and in the liquid deuterium, the surrogate fuel for a DT ignition target. The measured shock velocities and radiation drive histories are compared to previous three and four shock laser pulses. This comparison indicates that in the case of adiabat shaping the ablation front initially drives a high shock velocity, and therefore, a high shock pressure and adiabat. The shock then decays as it travels through the ablator to pressures similar to the original low-adiabat pulses when it reaches the fuel. This approach takes advantage of initial high ablation velocity, which favors stability, and high-compression, which favors high stagnation pressures.

  7. Sufficient Condition for Validity of Quantum Adiabatic Theorem

    TAO Yong

    2012-01-01

    In this paper, we attempt to give a sufficient condition of guaranteeing the validity of the proof of the quantum adiabatic theorem. The new sufficient condition can clearly remove the inconsistency and the counterexample of the quantum adiabatic theorem pointed out by Marzlin and Sanders [Phys. Rev. Lett. 93 (2004) 160408].

  8. Constraints on the Adiabatic Temperature Change in Magnetocaloric Materials

    Nielsen, Kaspar Kirstein; Bahl, Christian Robert Haffenden; Smith, Anders

    2010-01-01

    The thermodynamics of the magnetocaloric effect implies constraints on the allowed variation in the adiabatic temperature change for a magnetocaloric material. An inequality for the derivative of the adiabatic temperature change with respect to temperature is derived for both first- and second...

  9. High Fidelity Adiabatic Quantum Computation via Dynamical Decoupling

    Quiroz, Gregory

    2012-01-01

    We introduce high-order dynamical decoupling strategies for open system adiabatic quantum computation. Our numerical results demonstrate that a judicious choice of high-order dynamical decoupling method, in conjunction with an encoding which allows computation to proceed alongside decoupling, can dramatically enhance the fidelity of adiabatic quantum computation in spite of decoherence.

  10. Quantum adiabatic algorithm for factorization and its experimental implementation.

    Peng, Xinhua; Liao, Zeyang; Xu, Nanyang; Qin, Gan; Zhou, Xianyi; Suter, Dieter; Du, Jiangfeng

    2008-11-28

    We propose an adiabatic quantum algorithm capable of factorizing numbers, using fewer qubits than Shor's algorithm. We implement the algorithm in a NMR quantum information processor and experimentally factorize the number 21. In the range that our classical computer could simulate, the quantum adiabatic algorithm works well, providing evidence that the running time of this algorithm scales polynomially with the problem size.

  11. Teleportation of an Unknown Atomic State via Adiabatic Passage

    2007-01-01

    We propose a scheme for teleporting an unknown atomic state via adiabatic passage. Taking advantage of adiabatic passage, the atom has no probability of being excited and thus the atomic spontaneous emission is suppressed.We also show that the fidelity can reach 1 under certain condition.

  12. Theoretical description of adiabatic laser alignment and mixed-field orientation: the need for a non-adiabatic model

    Omiste, J J; Schmelcher, P; González-Férez, R; Holmegaard, L; Nielsen, J H; Stapelfeldt, H; Küpper, J

    2011-01-01

    We present a theoretical study of recent laser-alignment and mixed-field-orientation experiments of asymmetric top molecules. In these experiments, pendular states were created using linearly polarized strong ac electric fields from pulsed lasers in combination with weak electrostatic fields. We compare the outcome of our calculations with experimental results obtained for the prototypical large molecule benzonitrile (C$_7$H$_5$N) [J.L. Hansen et al, Phys. Rev. A, 83, 023406 (2011)] and explore the directional properties of the molecular ensemble for several field configurations, i.e., for various field strengths and angles between ac and dc fields. For perpendicular fields one obtains pure alignment, which is well reproduced by the simulations. For tilted fields, we show that a fully adiabatic description of the process does not reproduce the experimentally observed orientation, and it is mandatory to use a diabatic model for population transfer between rotational states. We develop such a model and compare ...

  13. Entropy in adiabatic regions of convection simulations

    Tanner, Joel D; Demarque, Pierre

    2016-01-01

    One of the largest sources of uncertainty in stellar models is caused by the treatment of convection in stellar envelopes. One dimensional stellar models often make use of the mixing length or equivalent approximations to describe convection, all of which depend on various free parameters. There have been attempts to rectify this by using 3D radiative-hydrodynamic simulations of stellar convection, and in trying to extract an equivalent mixing length from the simulations. In this paper we show that the entropy of the deeper, adiabatic layers in these simulations can be expressed as a simple function of og g and log T_{eff} which holds potential for calibrating stellar models in a simple and more general manner.

  14. Parametric Erosion Investigation: Propellant Adiabatic Flame Temperature

    P. J. Conroy

    2002-01-01

    Full Text Available The influence of quasi-independent parameters and their potential influence on erosion in guns have been investigated. Specifically, the effects of flame temperature and the effect of assuming that the Lewis number (ratio of mass-to-heat transport to the surface, Le = 1, has been examined. The adiabatic flame temperature for a propellant was reduced by the addition of a diluent from a high temperature of 3843 K (similar to that of M9 down to 3004 K, which is near the value for M30A1 propellant. Mass fractions of critical species at the surface with and without the assumption of Le = 1 are presented, demonstrating that certain species preferentially reach the surface providing varied conditions for the surface reactions. The results for gun tube bore surface regression qualitatively agree with previous studies and with current experimental data.

  15. Multiplicity features of adiabatic autothermal reactors

    Lovo, M.; Balakotaiah, V. (Houston Univ., TX (United States). Dept. of Chemical Engineering)

    1992-01-01

    In this paper singularity theory, large activation energy asymptotic, and numerical methods are used to present a comprehensive study of the steady-state multiplicity features of three classical adiabatic autothermal reactor models: tubular reactor with internal heat exchange, tubular reactor with external heat exchange, and the CSTR with external heat exchange. Specifically, the authors derive the exact uniqueness-multiplicity boundary, determine typical cross-sections of the bifurcation set, and classify the different types of bifurcation diagrams of conversion vs. residence time. Asymptotic (limiting) models are used to determine analytical expressions for the uniqueness boundary and the ignition and extinction points. The analytical results are used to present simple, explicit and accurate expressions defining the boundary of the region of autothermal operation in the physical parameter space.

  16. Conformal Symmetries of Adiabatic Modes in Cosmology

    Hinterbichler, Kurt; Khoury, Justin

    2012-01-01

    We remark on the existence of non-linearly realized conformal symmetries for scalar adiabatic perturbations in cosmology. These conformal symmetries are present for any cosmological background, beyond any slow-roll or quasi-de Sitter approximation. The dilatation transformation shifts the curvature perturbation by a constant, and corresponds to the well-known symmetry under spatial rescaling. We argue that the scalar sector is also invariant under special conformal transformations, which shift the curvature perturbation by a term linear in the spatial coordinates. We discuss whether these conformal symmetries can be extended to include tensor perturbations. Tensor modes introduce their own set of non-linearly realized symmetries. We identify an infinite set of large gauge transformations which maintain the transverse, traceless gauge condition, while shifting the tensor mode non-trivially.

  17. Adiabatic perturbations in coupled scalar field cosmologies

    Beyer, Joschka

    2014-01-01

    We present a comprehensive and gauge invariant treatment of perturbations around cosmological scaling solutions for two canonical scalar fields coupled through a common potential in the early universe, in the presence of neutrinos, photons and baryons, but excluding cold dark matter. This setup is relevant for analyzing cosmic perturbations in scalar field models of dark matter with a coupling to a quintessence field. We put strong restrictions on the shape of the common potential and adopt a matrix-eigensystem approach to determine the dominant perturbations modes in such models. Similar to recent results in scenarios where standard cold dark matter couples to quintessence, we show that the stability of the adiabatic perturbation mode can be an issue for this class of scalar field dark matter models, but only for specific choices of the common potential. For an exponential coupling potential, a rather common shape arising naturally in many instances, this problem can be avoided. We explicitly calculate the d...

  18. Adiabatic density-functional perturbation theory

    Gonze, Xavier

    1995-08-01

    The treatment of adiabatic perturbations within density-functional theory is examined, at arbitrary order of the perturbation expansion. Due to the extremal property of the energy functional, standard variation-perturbation theorems can be used. The different methods (Sternheimer equation, extremal principle, Green's function, and sum over state) for obtaining the perturbation expansion of the wave functions are presented. The invariance of the Hilbert space of occupied wave functions with respect to a unitary transformation leads to the definition of a ``parallel-transport-gauge'' and a ``diagonal-gauge'' perturbation expansion. Then, the general expressions are specialized for the second, third, and fourth derivative of the energy, with an example of application of the method up to third order.

  19. Investigating the Performance of an Adiabatic Quantum Optimization Processor

    Rose, Geordie; Dickson, Neil G; Hamze, Firas; Amin, M H S; Drew-Brook, Marshall; Chudak, Fabian A; Bunyk, Paul I; Macready, William G

    2010-01-01

    We calculate median adiabatic times (in seconds) of a specific superconducting adiabatic quantum processor for an NP-hard Ising spin glass instance class with up to N=128 binary variables. To do so, we ran high performance Quantum Monte Carlo simulations on a large-scale Internet-based computing platform. We compare the median adiabatic times with the median running times of two classical solvers and find that, for problems with up to 128 variables, the adiabatic times for the simulated processor architecture are about 4 and 6 orders of magnitude shorter than the two classical solvers' times. This performance difference shows that, even in the potential absence of a scaling advantage, adiabatic quantum optimization may outperform classical solvers.

  20. Adiabatic logic future trend and system level perspective

    Teichmann, Philip

    2012-01-01

    Adiabatic logic is a potential successor for static CMOS circuit design when it comes to ultra-low-power energy consumption. Future development like the evolutionary shrinking of the minimum feature size as well as revolutionary novel transistor concepts will change the gate level savings gained by adiabatic logic. In addition, the impact of worsening degradation effects has to be considered in the design of adiabatic circuits. The impact of the technology trends on the figures of merit of adiabatic logic, energy saving potential and optimum operating frequency, are investigated, as well as degradation related issues. Adiabatic logic benefits from future devices, is not susceptible to Hot Carrier Injection, and shows less impact of Bias Temperature Instability than static CMOS circuits. Major interest also lies on the efficient generation of the applied power-clock signal. This oscillating power supply can be used to save energy in short idle times by disconnecting circuits. An efficient way to generate the p...

  1. How detrimental is decoherence in adiabatic quantum computation?

    Albash, Tameem

    2015-01-01

    Recent experiments with increasingly larger numbers of qubits have sparked renewed interest in adiabatic quantum computation, and in particular quantum annealing. A central question that is repeatedly asked is whether quantum features of the evolution can survive over the long time-scales used for quantum annealing relative to standard measures of the decoherence time. We reconsider the role of decoherence in adiabatic quantum computation and quantum annealing using the adiabatic quantum master equation formalism. We restrict ourselves to the weak-coupling and singular-coupling limits, which correspond to decoherence in the energy eigenbasis and in the computational basis, respectively. We demonstrate that decoherence in the instantaneous energy eigenbasis does not necessarily detrimentally affect adiabatic quantum computation, and in particular that a short single-qubit $T_2$ time need not imply adverse consequences for the success of the quantum adiabatic algorithm. We further demonstrate that boundary canc...

  2. Non-Hermitian shortcut to adiabaticity of two- and three-level systems with gain and loss

    Li, Guan-Qiang; Chen, Guang-De; Peng, Ping; Qi, Wei

    2017-01-01

    Achieving effectively adiabatic dynamics in finite time is a ubiquitous goal in virtually all fields of modern physics. So-called shortcuts to adiabaticity refer to a set of methods and techniques that allow us to obtain in a short time the same final state that would result from an adiabatic, infinitely slow process. In this paper we generalized the non-Hermitian shortcut method to the situation of the unbalanced gain and loss. We found that the ratio between the gain and loss can control the transfer time and may become a new freedom to speed up the adiabatic transfer process. By using two-level Landau-Zener model and Allen-Eberly model and three-level stimulated Raman adiabatic passage, we investigated the transfer processes and obtained the analytical results about the final transfer time, which are related with the parameters of the corresponding systems. It is pointed out that these processes can be implemented in many systems experimentally such as coupled optical waveguides.

  3. Adiabatic & non-adiabatic perturbation theory for coherence vector description of neutrino oscillations

    Hollenberg, Sebastian

    2011-01-01

    The standard wave function approach for the treatment of neutrino oscillations fails in situations where quantum ensembles at a finite temperature with or without an interacting background plasma are encountered. As a first step to treat such phenomena in a novel way, we propose a unified approach to both adiabatic and non-adiabatic two-flavor oscillations in neutrino ensembles with finite temperature and generic (e.g. matter) potentials. Neglecting effects of ensemble decoherence for now we study the evolution of a neutrino ensemble governed by the associated Quantum Kinetic Equations, which apply to systems with finite temperature. The Quantum Kinetic Equations are solved formally using the Magnus expansion and it is shown that a convenient choice of the quantum mechanical picture (e.g. the interaction picture) reveals suitable parameters to characterize the physics of the underlying system (e.g. an effective oscillation length). It is understood that this method also provides a promising starting point for...

  4. Adiabatic vs. non-adiabatic determination of specific absorption rate of ferrofluids

    Natividad, Eva [Instituto de Ciencia de Materiales de Aragon (CSIC-Universidad de Zaragoza), Sede Campus Rio Ebro, Maria de Luna, 3, 50018 Zaragoza (Spain); Castro, Miguel [Instituto de Ciencia de Materiales de Aragon (CSIC-Universidad de Zaragoza), Sede Campus Rio Ebro, Maria de Luna, 3, 50018 Zaragoza (Spain)], E-mail: mcastro@unizar.es; Mediano, Arturo [Grupo de Electronica de Potencia y Microelectronica (GEPM), Instituto de Investigacion en Ingenieria de Aragon (Universidad de Zaragoza), Maria de Luna, 3, 50018 Zaragoza (Spain)

    2009-05-15

    The measurement of temperature variations in adiabatic conditions allows the determination of the specific absorption rate of magnetic nanoparticles and ferrofluids from the correct incremental expression, SAR=(1/m{sub MNP})C({delta}T/{delta}t). However, when measurements take place in non-adiabatic conditions, one must approximate this expression by SAR{approx}C{beta}/m{sub MNP}, where {beta} is the initial slope of the temperature vs. time curve during alternating field application. The errors arising from the use of this approximation were estimated through several experiments with different isolating conditions, temperature sensors and sample-sensor contacts. It is concluded that small to appreciable errors can appear, which are difficult to infer or control.

  5. Adiabatic Rearrangement of Hollow PV Towers

    Eric A Hendricks

    2010-10-01

    Full Text Available Diabatic heating from deep moist convection in the hurricane eyewall produces a towering annular structure of elevated potential vorticity (PV. This structure has been referred to as a hollow PV tower. The sign reversal of the radial gradient of PV satisfies the Charney-Stern necessary condition for combined barotropic-baroclinic instability. For thin enough annular structures, small perturbations grow exponentially, extract energy from the mean flow, and lead to hollow tower breakdown, with significant vortex structural and intensity change. The three-dimensional adiabatic rearrangements of two prototypical hurricane-like hollow PV towers (one thick and one thin are examined in an idealized framework. For both hollow towers, dynamic instability causes air parcels with high PV to be mixed into the eye preferentially at lower levels, where unstable PV wave growth rates are the largest. Little or no mixing is found to occur at upper levels. The mixing at lower and middle levels is most rapid for the breakdown of the thin hollow tower, consistent with previous barotropic results. For both hollow towers, this advective rearrangement of PV affects the tropical cyclone structure and intensity in a number of ways. First, the minimum central pressure and maximum azimuthal mean velocity simultaneously decrease, consistent with previous barotropic results. Secondly, isosurfaces of absolute angular momentum preferentially shift inward at low levels, implying an adiabatic mechanism by which hurricane eyewall tilt can form. Thirdly, a PV bridge, similar to that previously found in full-physics hurricane simulations, develops as a result of mixing at the isentropic levels where unstable PV waves grow most rapidly. Finally, the balanced mass field resulting from the PV rearrangement is warmer in the eye between 900 and 700 hPa. The location of this warming is consistent with observed warm anomalies in the eye, indicating that in certain instances the hurricane

  6. Teachers' Sense of Self amid Adaptation to Educational Reform

    van den Berg, G.; Schulze, S.

    2014-01-01

    Education has been subject to a process of continuous educational reforms. The aim of this study was to explore teachers' abilities to adapt to these reforms and to find out how this process of continual reform related to their identities as teachers. The study used a narrative research approach. The data for this research were based on the…

  7. On the General Class of Models of Adiabatic Evolution

    Sun, Jie; Lu, Songfeng; Liu, Fang

    2016-10-01

    The general class of models of adiabatic evolution was proposed to speed up the usual adiabatic computation in the case of quantum search problem. It was shown [8] that, by temporarily increasing the ground state energy of a time-dependent Hamiltonian to a suitable quantity, the quantum computation can perform the calculation in time complexity O(1). But it is also known that if the overlap between the initial and final states of the system is zero, then the computation based on the generalized models of adiabatic evolution can break down completely. In this paper, we find another severe limitation for this class of adiabatic evolution-based algorithms, which should be taken into account in applications. That is, it is still possible that this kind of evolution designed to deal with the quantum search problem fails completely if the interpolating paths in the system Hamiltonian are chosen inappropriately, while the usual adiabatic evolutions can do the same job relatively effectively. This implies that it is not always recommendable to use nonlinear paths in adiabatic computation. On the contrary, the usual simple adiabatic evolution may be sufficient for effective use.

  8. Approximability of optimization problems through adiabatic quantum computation

    Cruz-Santos, William

    2014-01-01

    The adiabatic quantum computation (AQC) is based on the adiabatic theorem to approximate solutions of the Schrödinger equation. The design of an AQC algorithm involves the construction of a Hamiltonian that describes the behavior of the quantum system. This Hamiltonian is expressed as a linear interpolation of an initial Hamiltonian whose ground state is easy to compute, and a final Hamiltonian whose ground state corresponds to the solution of a given combinatorial optimization problem. The adiabatic theorem asserts that if the time evolution of a quantum system described by a Hamiltonian is l

  9. EXACT AND ADIABATIC INVARIANTS OF FIRST-ORDER LAGRANGE SYSTEMS

    陈向炜; 尚玫; 梅凤翔

    2001-01-01

    A system of first-order differential equations is expressed in the form of first-order Lagrange equations. Based on the theory of symmetries and conserved quantities of first-order Lagrange systems, the perturbation to the symmetries and adiabatic invariants of first-order Lagrange systems are discussed. Firstly, the concept of higher-order adiabatic invariants of the first-order Lagrange system is proposed. Then, conditions for the existence of the exact and adiabatic invariants are proved, and their forms are given. Finally, an example is presented to illustrate these results.

  10. Adiabatic control of atomic dressed states for transport and sensing

    Cooper, N. R.; Rey, A. M.

    2015-08-01

    We describe forms of adiabatic transport that arise for dressed-state atoms in optical lattices. Focusing on the limit of weak tunnel-coupling between nearest-neighbor lattice sites, we explain how adiabatic variation of optical dressing allows control of atomic motion between lattice sites: allowing adiabatic particle transport in a direction that depends on the internal state, and force measurements via spectroscopic preparation and readout. For uniformly filled bands these systems display topologically quantized particle transport. An implementation of the dressing scheme using optical transitions in alkaline-earth atoms is discussed as well as its favorable features for precise force sensing.

  11. Can ICT Reform Public Agencies?

    Jansen, Arild; Løvdal, Einar

    This study examines the reorganisation of the administration of admission to higher education in Norway, which has also included the development of a nationwide, ICT-based case handling system. This reform process was initiated out of the need to provide politicians with information for control and regulatory purposes, and the reform resulted in a centralised management information system. This system, however, has evolved into a coordinated but also partly locally delegated decision-making instrument which processes most of the applications for admission to higher education in Norway.

  12. Impact of Turbocharger Non-Adiabatic Operation on Engine Volumetric Efficiency and Turbo Lag

    S. Shaaban

    2012-01-01

    Full Text Available Turbocharger performance significantly affects the thermodynamic properties of the working fluid at engine boundaries and hence engine performance. Heat transfer takes place under all circumstances during turbocharger operation. This heat transfer affects the power produced by the turbine, the power consumed by the compressor, and the engine volumetric efficiency. Therefore, non-adiabatic turbocharger performance can restrict the engine charging process and hence engine performance. The present research work investigates the effect of turbocharger non-adiabatic performance on the engine charging process and turbo lag. Two passenger car turbochargers are experimentally and theoretically investigated. The effect of turbine casing insulation is also explored. The present investigation shows that thermal energy is transferred to the compressor under all circumstances. At high rotational speeds, thermal energy is first transferred to the compressor and latter from the compressor to the ambient. Therefore, the compressor appears to be “adiabatic” at high rotational speeds despite the complex heat transfer processes inside the compressor. A tangible effect of turbocharger non-adiabatic performance on the charging process is identified at turbocharger part load operation. The turbine power is the most affected operating parameter, followed by the engine volumetric efficiency. Insulating the turbine is recommended for reducing the turbine size and the turbo lag.

  13. Adiabatic Quantum Algorithm for Search Engine Ranking

    Garnerone, Silvano; Zanardi, Paolo; Lidar, Daniel A.

    2012-06-01

    We propose an adiabatic quantum algorithm for generating a quantum pure state encoding of the PageRank vector, the most widely used tool in ranking the relative importance of internet pages. We present extensive numerical simulations which provide evidence that this algorithm can prepare the quantum PageRank state in a time which, on average, scales polylogarithmically in the number of web pages. We argue that the main topological feature of the underlying web graph allowing for such a scaling is the out-degree distribution. The top-ranked log⁡(n) entries of the quantum PageRank state can then be estimated with a polynomial quantum speed-up. Moreover, the quantum PageRank state can be used in “q-sampling” protocols for testing properties of distributions, which require exponentially fewer measurements than all classical schemes designed for the same task. This can be used to decide whether to run a classical update of the PageRank.

  14. Design of the PIXIE Adiabatic Demagnetization Refrigerators

    Shirron, Peter J.; Kimball, Mark Oliver; Fixsen, Dale J.; Kogut, Alan J.; Li, Xiaoyi; DiPirro, Michael

    2012-01-01

    The Primordial Inflation Explorer (PIXIE) is a proposed mission to densely map the polarization of the cosmic microwave background. It will operate in a scanning mode from a sun-synchronous orbit, using low temperature detectors (at 0.1 K) and located inside a teslescope that is cooled to approximately 2.73 K - to match the background temperature. A mechanical cryocooler operating at 4.5 K establishes a low base temperature from which two adiabatic demagnetization refrigerator (ADR) assemblies will cool the telescope and detectors. To achieve continuous scanning capability, the ADRs must operate continuously. Complicating the design are two factors: 1) the need to systematically vary the temperature of various telescope components in order to separate the small polarization signal variations from those that may arise from temperature drifts and changing gradients within the telescope, and 2) the orbital and monthly variations in lunar irradiance into the telescope barrels. These factors require the telescope ADR to reject quasi-continuous heat loads of 2-3 millwatts, while maintaining a peak heat reject rate of less than 12 milliwatts. The detector heat load at 0.1 K is comparatively small at 1-2 microwatts. This paper will describe the 3-stage and 2-stage continuous ADRs that will be used to meet the cooling power and temperature stability requirements of the PIXIE detectors and telescope.

  15. Topological States and Adiabatic Pumping in Quasicrystals

    Kraus, Yaakov; Lahini, Yoav; Ringel, Zohar; Verbin, Mor; Zilberberg, Oded

    2012-02-01

    We find a connection between quasicrystals and topological matter, namely that quasicrystals exhibit non-trivial topological phases attributed to dimensions higher than their own [1]. Quasicrystals are materials which are neither ordered nor disordered, i.e. they exhibit only long-range order [2]. This long-range order is usually expressed as a projection from a higher dimensional ordered system. Recently, the unrelated discovery of Topological Insulators [3] defined a new type of materials classified by their topology. We show theoretically and experimentally using photonic lattices, that one-dimensional quasicrystals exhibit topologically-protected boundary states equivalent to the edge states of the two-dimensional Integer Quantum Hall Effect. We harness this property to adiabatically pump light across the quasicrystal, and generalize our results to higher dimensional systems. Hence, quasicrystals offer a new platform for the study of topological phases while their topology may better explain their surface properties.[4pt] [1] Y. E. Kraus, Y. Lahini, Z. Ringel, M. Verbin, and O. Zilberberg, arXiv:1109.5983 (2011).[0pt] [2] C. Janot, Quasicrystals (Clarendon, Oxford, 1994), 2nd ed.[0pt] [3] M. Z. Hasan and C. L. Kane, Rev. Mod. Phys. 82, 3045 (2010).

  16. Adiabatic quantum algorithm for search engine ranking.

    Garnerone, Silvano; Zanardi, Paolo; Lidar, Daniel A

    2012-06-08

    We propose an adiabatic quantum algorithm for generating a quantum pure state encoding of the PageRank vector, the most widely used tool in ranking the relative importance of internet pages. We present extensive numerical simulations which provide evidence that this algorithm can prepare the quantum PageRank state in a time which, on average, scales polylogarithmically in the number of web pages. We argue that the main topological feature of the underlying web graph allowing for such a scaling is the out-degree distribution. The top-ranked log(n) entries of the quantum PageRank state can then be estimated with a polynomial quantum speed-up. Moreover, the quantum PageRank state can be used in "q-sampling" protocols for testing properties of distributions, which require exponentially fewer measurements than all classical schemes designed for the same task. This can be used to decide whether to run a classical update of the PageRank.

  17. Adiabatic fission barriers in superheavy nuclei

    Jachimowicz, P; Skalski, J

    2016-01-01

    Using the microscopic-macroscopic model based on the deformed Woods-Saxon single-particle potential and the Yukawa-plus-exponential macroscopic energy we calculated static fission barriers $B_{f}$ for 1305 heavy and superheavy nuclei $98\\leq Z \\leq 126$, including even - even, odd - even, even - odd and odd - odd systems. For odd and odd-odd nuclei, adiabatic potential energy surfaces were calculated by a minimization over configurations with one blocked neutron or/and proton on a level from the 10-th below to the 10-th above the Fermi level. The parameters of the model that have been fixed previously by a fit to masses of even-even heavy nuclei were kept unchanged. A search for saddle points has been performed by the "Imaginary Water Flow" method on a basic five-dimensional deformation grid, including triaxiality. Two auxiliary grids were used for checking the effects of the mass asymmetry and hexadecapole non-axiallity. The ground states were found by energy minimization over configurations and deformations...

  18. Curriculum Reform: The Crisis in Teacher Education.

    Guyton, Edith

    1984-01-01

    Education currently faces a crisis in curriculum reform which presents a danger to pedagogical programs. Changes in teacher education programs should be based on research and should be accomplished by a reflective and rational process. Methods of reform are explored. (DF)

  19. Higher Education Reforms in the Slovak Republic.

    Pisut, Jan

    1993-01-01

    Early steps in the higher education reform process in the Slovak Republic since 1989 are outlined, difficulties are noted, and suggestions for possible forms of encouragement are listed. Suggestions focus on international cooperation, particularly within the European Community, interinstitutional collaboration, and internal reforms in governance,…

  20. 300 nm bandwidth adiabatic SOI polarization splitter-rotators exploiting continuous symmetry breaking.

    Socci, Luciano; Sorianello, Vito; Romagnoli, Marco

    2015-07-27

    Adiabatic polarization splitter-rotators are investigated exploiting continuous symmetry breaking thereby achieving significant device size and losses reduction in a single mask fabrication process for both SOI channel and ridge waveguides. A crosstalk lower than -25 dB is expected over 300nm bandwidth, making the device suitable for full grid CWDM and diplexer/triplexer FTTH applications at 1310, 1490 and 1550nm.

  1. Adiabatic rotation, quantum search, and preparation of superposition states

    Siu, M. Stewart

    2007-06-01

    We introduce the idea of using adiabatic rotation to generate superpositions of a large class of quantum states. For quantum computing this is an interesting alternative to the well-studied “straight line” adiabatic evolution. In ways that complement recent results, we show how to efficiently prepare three types of states: Kitaev’s toric code state, the cluster state of the measurement-based computation model, and the history state used in the adiabatic simulation of a quantum circuit. We also show that the method, when adapted for quantum search, provides quadratic speedup as other optimal methods do with the advantages that the problem Hamiltonian is time independent and that the energy gap above the ground state is strictly nondecreasing with time. Likewise the method can be used for optimization as an alternative to the standard adiabatic algorithm.

  2. Magnesium Diboride Superconducting Coils for Adiabatic Demagnetization Refrigerators (ADR's) Project

    National Aeronautics and Space Administration — For Adiabatic Demagnetization Refrigerators(ADR's) for space it is desirable to have very light weight, small diameter, high current density superconducting wires...

  3. Low-power adiabatic 9T static random access memory

    Yasuhiro Takahashi

    2014-06-01

    Full Text Available In this paper, the authors propose a novel static random access memory (SRAM that employs the adiabatic logic principle. To reduce energy dissipation, the proposed adiabatic SRAM is driven by two trapezoidal-wave pulses. The cell structure of the proposed SRAM has two high-value resistors based on a p-type metal-oxide semiconductor transistor, a cross-coupled n-type metal-oxide semiconductor (NMOS pair and an NMOS switch to reduce the short-circuit current. The inclusion of a transmission-gate controlled by a write word line signal allows the proposed circuit to operate as an adiabatic SRAM during data writing. Simulation results show that the energy dissipation of the proposed SRAM is lower than that of a conventional adiabatic SRAM.

  4. Adiabaticity and diabaticity in strong-field ionization

    Karamatskou, Antonia; Santra, Robin

    2013-01-01

    If the photon energy is much less than the electron binding energy, ionization of an atom by a strong optical field is often described in terms of electron tunneling through the potential barrier resulting from the superposition of the atomic potential and the potential associated with the instantaneous electric component of the optical field. In the strict tunneling regime, the electron response to the optical field is said to be adiabatic, and nonadiabatic effects are assumed to be negligible. Here, we investigate to what degree this terminology is consistent with a language based on the so-called adiabatic representation. This representation is commonly used in various fields of physics. For electronically bound states, the adiabatic representation yields discrete potential energy curves that are connected by nonadiabatic transitions. When applying the adiabatic representation to optical strong-field ionization, a conceptual challenge is that the eigenstates of the instantaneous Hamiltonian form a continuu...

  5. Adiabatic invariants of the extended KdV equation

    Karczewska, Anna; Infeld, Eryk; Rowlands, George

    2015-01-01

    When the Euler equations for shallow water are taken to the next order, beyond KdV, $\\eta^2$ is no longer an invariant. (It would seem that $\\eta$ is the only one.) However, two adiabatic invariants akin to $\\eta^2$ can be found. Here we present and test them. When the KdV expansion parameters are zero, $\\eta^2$ is recovered from both adiabatic invariants.

  6. Preparation of Entangled States of Three Particles by Adiabatic Passage

    郭建友

    2002-01-01

    We propose a novel technique for the creation of entangled states of three particles, based upon an adiabatic passage induced by a suitably crafted time-dependent external field. We derive the corresponding adiabatic and bare conditions for the preparation of entangled states. We obtain the time evolutions of the energy of the system and the populations involving the initial state and target entangled state.

  7. Adiabatic CMB perturbations in pre-big bang string cosmology

    Enqvist, Kari; Enqvist, Kari; Sloth, Martin S.

    2002-01-01

    We consider the pre-big bang scenario with a massive axion field which starts to dominate energy density when oscillating in an instanton-induced potential and subsequently reheats the universe as it decays into photons, thus creating adiabatic CMB perturbations. We find that the fluctuations in the axion field can give rise to a nearly flat spectrum of adiabatic perturbations with a spectral tilt $\\Delta n$ in the range $-0.1 \\lesssim \\Delta n \\lesssim 0.3$.

  8. Adiabatic CMB perturbations in pre-big bang string cosmology

    Enqvist, Kari; Sloth, Martin Snoager

    2001-01-01

    We consider the pre-big bang scenario with a massive axion field which starts to dominate energy density when oscillating in an instanton-induced potential and subsequently reheats the universe as it decays into photons, thus creating adiabatic CMB perturbations. We find that the fluctuations...... in the axion field can give rise to a nearly flat spectrum of adiabatic perturbations with a spectral tilt $\\Delta n$ in the range $-0.1 \\lesssim \\Delta n \\lesssim 1$....

  9. ENTROPY-VORTEX WAVES IN NON-ADIABATIC FLOWS

    Ibáñez S, Miguel H., E-mail: mhibanez@yahoo.com [Departamento de Ciencias Básicas, Facultad de Ingeniería, Universidad Autónoma del Caribe, Barranquilla (Colombia)

    2016-02-20

    The Ertel theorem on the vorticity along the flow of adiabatic fluids is generalized for non-adiabatic flows. Several limiting cases are analyzed and the results are applied to flows behind different hydrodynamics fronts, particularly to thermal fronts (heat and cooling fronts). An important conclusion of the present analysis is that vorticity is inherent in the condensation’s (or hot spots) formation by thermal instabilities in plasma flows. Implications for several astrophysical plasmas are outlined.

  10. Dependence of adiabatic population transfer on pulse profile

    S Dasgupta; T kushwaha; D Goswami

    2006-06-01

    Control of population transfer by rapid adiabatic passage has been an established technique wherein the exact amplitude profile of the shaped pulse is considered to be insignificant. We study the effect of ultrafast shaped pulses for two-level systems, by density-matrix approach. However, we find that adiabaticity depends simultaneously on pulse profile as well as the frequency modulation under non-resonant conditions.

  11. Adiabatic reduction of a piecewise deterministic markov model of stochastic gene expression with bursting transcription

    Lei, Jinzhi; Yvinec, Romain; Zhuge, Changjing

    2012-01-01

    This paper considers adiabatic reduction in a model of stochastic gene expression with bursting transcription. We prove that an adiabatic reduction can be performed in a stochastic slow/fast system with a jump Markov process. In the gene expression model, the production of mRNA (the fast variable) is assumed to follow a compound Poisson process (the phenomena called bursting in molecular biology) and the production of protein (the slow variable) is linear as a function of mRNA. When the dynamics of mRNA is assumed to be faster than the protein dynamics (due to a mRNA degradation rate larger than for the protein) we prove that, with the appropriate scaling, the bursting phenomena can be transmitted to the slow variable. We show that the reduced equation is either a stochastic differential equation with a jump Markov process or a deterministic ordinary differential equation depending on the scaling that is appropriate. These results are significant because adiabatic reduction techniques seem to have not been de...

  12. Nonequilibrium adiabatic molecular dynamics simulations of methane clathrate hydrate decomposition

    Alavi, Saman; Ripmeester, J. A.

    2010-04-01

    Nonequilibrium, constant energy, constant volume (NVE) molecular dynamics simulations are used to study the decomposition of methane clathrate hydrate in contact with water. Under adiabatic conditions, the rate of methane clathrate decomposition is affected by heat and mass transfer arising from the breakup of the clathrate hydrate framework and release of the methane gas at the solid-liquid interface and diffusion of methane through water. We observe that temperature gradients are established between the clathrate and solution phases as a result of the endothermic clathrate decomposition process and this factor must be considered when modeling the decomposition process. Additionally we observe that clathrate decomposition does not occur gradually with breakup of individual cages, but rather in a concerted fashion with rows of structure I cages parallel to the interface decomposing simultaneously. Due to the concerted breakup of layers of the hydrate, large amounts of methane gas are released near the surface which can form bubbles that will greatly affect the rate of mass transfer near the surface of the clathrate phase. The effects of these phenomena on the rate of methane hydrate decomposition are determined and implications on hydrate dissociation in natural methane hydrate reservoirs are discussed.

  13. Stimulated Raman adiabatic passage in physics, chemistry, and beyond

    Vitanov, Nikolay V.; Rangelov, Andon A.; Shore, Bruce W.; Bergmann, Klaas

    2017-01-01

    The technique of stimulated Raman adiabatic passage (STIRAP), which allows efficient and selective population transfer between quantum states without suffering loss due to spontaneous emission, was introduced in 1990 by Gaubatz et al.. Since then STIRAP has emerged as an enabling methodology with widespread successful applications in many fields of physics, chemistry, and beyond. This article reviews the many applications of STIRAP emphasizing the developments since 2001, the time when the last major review on the topic was written (Vitanov, Fleischhauer et al.). A brief introduction into the theory of STIRAP and the early applications for population transfer within three-level systems is followed by the discussion of several extensions to multilevel systems, including multistate chains and tripod systems. The main emphasis is on the wide range of applications in atomic and molecular physics (including atom optics, cavity quantum electrodynamics, formation of ultracold molecules, etc.), quantum information (including single- and two-qubit gates, entangled-state preparation, etc.), solid-state physics (including processes in doped crystals, nitrogen-vacancy centers, superconducting circuits, semiconductor quantum dots and wells), and even some applications in classical physics (including waveguide optics, polarization optics, frequency conversion, etc.). Promising new prospects for STIRAP are also presented (including processes in optomechanics, precision experiments, detection of parity violation in molecules, spectroscopy of core-nonpenetrating Rydberg states, population transfer with x-ray pulses, etc.).

  14. 从砂处理系统改造谈型砂性能控制%Control of Sand Properties by Sand Processing System Reform

    王易千

    2011-01-01

    The sand processing equipments were reformed to improve and stabilize the sand quality of product line, and the influencing factors of sand performance were analyzed. The sand quality is improved by the control of sand properties, and the ratio of effective bentonite content and moisture content, the ratio of compactability and moisture content are more reasonable. The rejection rate of crush and blowhole is reduced greatly.%为了提高和稳定生产线的型砂质量,对砂处理系统设备进行了整体改造,分析了型砂性能的影响因素。通过严格控制型砂性能指标,提高了型砂质量,使有效膨润土与水分比、紧实率与水分比趋于合理,铸件落砂、气孔废品率大幅下降。

  15. Reform and Practice of Process Control Engineering Based on MATLAB%基于MATLAB的过程控制工程教学改革与实践

    杨大勇; 杨俊清

    2011-01-01

    Process Control Engineering is one of the core courses with stronger practice,but experimental practice of the course is not enough.In order to solve the problem,the computer assisted instruction software based on MATLAB/Simulink is developed.Simulation experiments are brought before the real experiments in practice teaching,and the application of the teaching platform of multimedia network is combined.Reform and practice show that the method can enhance the experiment efficiency and effectiveness and improve the ability of student's analyzing and resolving problems.%过程控制工程是一门实践性很强的核心课程。针对该课程实验不足的问题,我们开发了基于MATLAB/Si mulink软件平台的计算机辅助教学软件,采用以仿真实验带动真实实验的方法,并结合网络教学平台的应用,进行了一系列的教学改革和实践。实践表明,该方法能有效提高实验效率,增强实验效果,提高学生分析问题、解决问题的能力。

  16. Broadband frequency conversion via adiabatically tapered $\\chi^{(2)}$ waveguide in photonic integrated circuits

    Xiong, Xiao; Guo, Xiang; Tang, Hong X; Ren, Xi-Feng; Guo, Guang-Can

    2016-01-01

    We propose to use the integrated aluminum nitride waveguide with engineered width variation to achieve optical frequency conversion based on $\\chi^{(2)}$ nonlinear effect on a photonic chip. We show that in an adiabatically tapered waveguide, the frequency conversion has a much broader bandwidth and the efficiency within the bandwidth is almost constant, which is favorable for short pulses. We demonstrate both analytically and numerically an "area law" for the frequency conversion, i.e. the product of bandwidth and efficiency is conserved as long as peak conversion efficiency does not saturate. The adiabatic structure shows higher saturation thresholds in pump power or interaction length, outperforming the conventional uniform waveguide design. With our approach, high-efficiency and wavefront-keeping conversion for short pulses is possible on a photonic chip, which will surely find applications for scalable on-chip information processing.

  17. Pulse-driven near-resonant quantum adiabatic dynamics: lifting of quasi-degeneracy

    Yatsenko, L P; Jauslin, H R

    2003-01-01

    We study the quantum dynamics of a two-level system driven by a pulse that starts near-resonant for small amplitudes, yielding nonadiabatic evolution, and induces an adiabatic evolution for larger amplitudes. This problem is analyzed in terms of lifting of degeneracy for rising amplitudes. It is solved exactly for the case of linear and exponential rising. Approximate solutions are given in the case of power law rising. This allows us to determine approximative formulas for the lineshape of resonant excitation by various forms of pulses such as truncated trig-pulses. We also analyze and explain the various superpositions of states that can be obtained by the Half Stark Chirped Rapid Adiabatic Passage (Half-SCRAP) process.

  18. Spectral-gap analysis for efficient tunneling in quantum adiabatic optimization

    Brady, Lucas T.; van Dam, Wim

    2016-09-01

    We investigate the efficiency of quantum adiabatic optimization when overcoming potential barriers to get from a local to a global minimum. Specifically we look at n qubit systems with symmetric cost functions f :{0,1 } n→R , where the ground state must tunnel through a potential barrier of width nα and height nβ. By the quantum adiabatic theorem the time delay sufficient to ensure tunneling grows quadratically with the inverse spectral gap during this tunneling process. We analyze barrier sizes with 1 /2 ≤α +β and α folklore result by Goldstone from 2002, which used large spin and instanton methods. Parts of our result also refine recent results by Kong and Crosson [arXiv:1511.06991] and Jiang et al. [arXiv:1603.01293] about the exponential gap scaling.

  19. Reformation for production process of acetone cyanohydrin%丙酮氰醇生产工艺改造

    赵永亮; 李晓光; 钱有程

    2013-01-01

    The production capacity of acetone cyanohydrin unit is 80 000 t/a,the consumption of raw acetone is 60 000 t/a,producing incineration wastewater 3 000 t/a. Because of acetone cyanohydrin production process backward, using inorganic alkali hydroxide as catalyst, the production process produced a large amount of sodium sulfate crystal impurity,device operation cycle was short,the crystallization cauldron cleaning for three days at a time, refining tower cleaning for five days at a time, causing high consumption of acetone and wastewater,so the production cost was high;highly toxic plant startup and shutdown for cleaning frequent operation, which cause safety problems. According to the existence problem, we put forward a new production process of acetone cyanohydrin using organic alkali as catalyst,which can bring numerous economic benefits.%丙酮氰醇装置生产能力为8万t/a,消耗原料丙酮6万t/a,产生焚烧废水3 000 t/a.因丙酮氰醇生产工艺落后,用无机碱氢氧化钠做催化剂,生产过程中产生大量硫酸钠晶体杂质,装置运行周期短,结晶釜3d清洗1次,精制塔5d清洗1次,造成原料丙酮、废水消耗偏高,产品生产成本高;剧毒装置开停车清洗操作频繁,安全隐患大.根据装置存在问题,提出生产丙酮氰醇生产用有机碱做催化剂,具有显著的经济效益和社会效益.

  20. Perturbation to Unified Symmetry and Adiabatic Invariants for Relativistic Hamilton Systems

    ZHANG Ming-Jiang; FANG Jian-Hui; LU Kai; PANG Ting; LIN Peng

    2009-01-01

    Based on the concept of adiabatic invariant, the perturbation to unified symmetry and adiabatic invariants for relativistic Hamilton systems are studied. The definition of the perturbation to unified symmetry for the system is presented, and the criterion of the perturbation to unified symmetry is given. Meanwhile, the Noether adiabatic invariants, the generalized Hojman adiabatic invariants, and the Mei adiabatic invariants for the perturbed system are obtained.

  1. Monte Carlo modeling of Lead-Cooled Fast Reactor in adiabatic equilibrium state

    Stanisz, Przemysław, E-mail: pstanisz@agh.edu.pl; Oettingen, Mikołaj, E-mail: moettin@agh.edu.pl; Cetnar, Jerzy, E-mail: cetnar@mail.ftj.agh.edu.pl

    2016-05-15

    Graphical abstract: - Highlights: • We present the Monte Carlo modeling of the LFR in the adiabatic equilibrium state. • We assess the adiabatic equilibrium fuel composition using the MCB code. • We define the self-adjusting process of breeding gain by the control rod operation. • The designed LFR can work in the adiabatic cycle with zero fuel breeding. - Abstract: Nuclear power would appear to be the only energy source able to satisfy the global energy demand while also achieving a significant reduction of greenhouse gas emissions. Moreover, it can provide a stable and secure source of electricity, and plays an important role in many European countries. However, nuclear power generation from its birth has been doomed by the legacy of radioactive nuclear waste. In addition, the looming decrease in the available resources of fissile U235 may influence the future sustainability of nuclear energy. The integrated solution to both problems is not trivial, and postulates the introduction of a closed-fuel cycle strategy based on breeder reactors. The perfect choice of a novel reactor system fulfilling both requirements is the Lead-Cooled Fast Reactor operating in the adiabatic equilibrium state. In such a state, the reactor converts depleted or natural uranium into plutonium while consuming any self-generated minor actinides and transferring only fission products as waste. We present the preliminary design of a Lead-Cooled Fast Reactor operating in the adiabatic equilibrium state with the Monte Carlo Continuous Energy Burnup Code – MCB. As a reference reactor model we apply the core design developed initially under the framework of the European Lead-cooled SYstem (ELSY) project and refined in the follow-up Lead-cooled European Advanced DEmonstration Reactor (LEADER) project. The major objective of the study is to show to what extent the constraints of the adiabatic cycle are maintained and to indicate the phase space for further improvements. The analysis

  2. When School Reform Goes Wrong

    Noddings, Nel

    2007-01-01

    In this much-needed volume, Nel Noddings uses her extensive experience at every level of schooling to challenge the No Child Left Behind Act (NCLB). Noddings invites readers to think critically about the ideas underlying NCLB, the reform movement that shaped it, and the processes it has put into play. She considers such questions as: Is money the…

  3. Energy Analysis in Combined Reforming of Propane

    K. Moon

    2013-01-01

    Full Text Available Combined (steam and CO2 reforming is one of the methods to produce syngas for different applications. An energy requirement analysis of steam reforming to dry reforming with intermediate steps of steam reduction and equivalent CO2 addition to the feed fuel for syngas generation has been done to identify condition for optimum process operation. Thermodynamic equilibrium data for combined reforming was generated for temperature range of 400–1000°C at 1 bar pressure and combined oxidant (CO2 + H2O stream to propane (fuel ratio of 3, 6, and 9 by employing the Gibbs free energy minimization algorithm of HSC Chemistry software 5.1. Total energy requirement including preheating and reaction enthalpy calculations were done using the equilibrium product composition. Carbon and methane formation was significantly reduced in combined reforming than pure dry reforming, while the energy requirements were lower than pure steam reforming. Temperatures of minimum energy requirement were found in the data analysis of combined reforming which were optimum for the process.

  4. Ecological tax reform

    NONE

    1996-12-31

    An environmental tax reform is seen by many as a possible solution to some crucial problems of modern society - pollution, excessive resource consumption and unemployment. Changes in the system of taxation are here seen as a long term process, one that must cheapen the costs of labour and make the costs of resource use more expensive - a process which can also create major changes in our society as to conceptions of quality, work, consumption etc. The conference presented proposals for an ecological tax and duty system that would contribute to: Changing technology so that it becomes more resource and energy effective. Changing the economic mechanisms so that resource consumption and pollution become more expensive while human resources become cheaper. Changing personal life styles and values so that material consumption becomes less decisive for our choices and priorities. An environmental tax reform is neither without problems nor painless. An economy and an industrial sector based on increasing consumption of energy and raw materials will, in the long run, lead to drawbacks that far outweigh those that are connected with an economic re-orientation whose driving force is another conception of nature. (EG)

  5. Development of a semi-adiabatic isoperibol solution calorimeter

    Venkata Krishnan, R.; Jogeswararao, G.; Parthasarathy, R.; Premalatha, S.; Prabhakar Rao, J.; Gunasekaran, G.; Ananthasivan, K., E-mail: asivan@igcar.gov.in [Chemistry Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102, Tamilnadu (India)

    2014-12-15

    A semi-adiabatic isoperibol solution calorimeter has been indigenously developed. The measurement system comprises modules for sensitive temperature measurement probe, signal processing, data collection, and joule calibration. The sensitivity of the temperature measurement module was enhanced by using a sensitive thermistor coupled with a lock-in amplifier based signal processor. A microcontroller coordinates the operation and control of these modules. The latter in turn is controlled through personal computer (PC) based custom made software developed with LabView. An innovative summing amplifier concept was used to cancel out the base resistance of the thermistor. The latter was placed in the dewar. The temperature calibration was carried out with a standard platinum resistance (PT100) sensor coupled with an 8½ digit multimeter. The water equivalent of this calorimeter was determined by using electrical calibration with the joule calibrator. The experimentally measured values of the quantum of heat were validated by measuring heats of dissolution of pure KCl (for endotherm) and tris (hydroxyl methyl) amino-methane (for exotherm). The uncertainity in the measurements was found to be within ±3%.

  6. Hot-electron nanoscopy using adiabatic compression of surface plasmons

    Giugni, Andrea

    2013-10-20

    Surface plasmon polaritons are a central concept in nanoplasmonics and have been exploited to develop ultrasensitive chemical detection platforms, as well as imaging and spectroscopic techniques at the nanoscale. Surface plasmons can decay to form highly energetic (or hot) electrons in a process that is usually thought to be parasitic for applications, because it limits the lifetime and propagation length of surface plasmons and therefore has an adverse influence on the functionality of nanoplasmonic devices. Recently, however, it has been shown that hot electrons produced by surface plasmon decay can be harnessed to produce useful work in photodetection, catalysis and solar energy conversion. Nevertheless, the surface-plasmon-to-hot-electron conversion efficiency has been below 1% in all cases. Here we show that adiabatic focusing of surface plasmons on a Schottky diode-terminated tapered tip of nanoscale dimensions allows for a plasmon-to-hot-electron conversion efficiency of ∼30%. We further demonstrate that, with such high efficiency, hot electrons can be used for a new nanoscopy technique based on an atomic force microscopy set-up. We show that this hot-electron nanoscopy preserves the chemical sensitivity of the scanned surface and has a spatial resolution below 50 nm, with margins for improvement.

  7. Adiabatic calorimetric decomposition studies of 50 wt.% hydroxylamine/water.

    Cisneros, L O; Rogers, W J; Mannan, M S

    2001-03-19

    Calorimetric data can provide a basis for determining potential hazards in reactions, storage, and transportation of process chemicals. This work provides calorimetric data for the thermal decomposition behavior in air of 50wt.% hydroxylamine/water (HA), both with and without added stabilizers, which was measured in closed cells with an automatic pressure tracking adiabatic calorimeter (APTAC). Among the data provided are onset temperatures, reaction order, activation energies, pressures of noncondensable products, thermal stability at 100 degrees C, and the effect of HA storage time. Discussed also are the catalytic effects of carbon steel, stainless steel, stainless steel with silica coating, inconel, titanium, and titanium with silica coating on the reaction self-heat rates and onset temperatures. In borosilicate glass cells, HA was relatively stable at temperatures up to 133 degrees C, where the HA decomposition self-heat rate reached 0.05 degrees C/min. The added stabilizers appeared to reduce HA decomposition rates in glass cells and at ambient temperatures. The tested metals and metal surfaces coated with silica acted as catalysts to lower the onset temperatures and increase the self-heat rates.

  8. Thermodynamics Analysis of Refinery Sludge Gasification in Adiabatic Updraft Gasifier

    Reem Ahmed

    2014-01-01

    Full Text Available Limited information is available about the thermodynamic evaluation for biomass gasification process using updraft gasifier. Therefore, to minimize errors, the gasification of dry refinery sludge (DRS is carried out in adiabatic system at atmospheric pressure under ambient air conditions. The objectives of this paper are to investigate the physical and chemical energy and exergy of product gas at different equivalent ratios (ER. It will also be used to determine whether the cold gas, exergy, and energy efficiencies of gases may be maximized by using secondary air injected to gasification zone under various ratios (0, 0.5, 1, and 1.5 at optimum ER of 0.195. From the results obtained, it is indicated that the chemical energy and exergy of producer gas are magnified by 5 and 10 times higher than their corresponding physical values, respectively. The cold gas, energy, and exergy efficiencies of DRS gasification are in the ranges of 22.9–55.5%, 43.7–72.4%, and 42.5–50.4%, respectively. Initially, all 3 efficiencies increase until they reach a maximum at the optimum ER of 0.195; thereafter, they decline with further increase in ER values. The injection of secondary air to gasification zone is also found to increase the cold gas, energy, and exergy efficiencies. A ratio of secondary air to primary air of 0.5 is found to be the optimum ratio for all 3 efficiencies to reach the maximum values.

  9. Development of a semi-adiabatic isoperibol solution calorimeter.

    Venkata Krishnan, R; Jogeswararao, G; Parthasarathy, R; Premalatha, S; Prabhakar Rao, J; Gunasekaran, G; Ananthasivan, K

    2014-12-01

    A semi-adiabatic isoperibol solution calorimeter has been indigenously developed. The measurement system comprises modules for sensitive temperature measurement probe, signal processing, data collection, and joule calibration. The sensitivity of the temperature measurement module was enhanced by using a sensitive thermistor coupled with a lock-in amplifier based signal processor. A microcontroller coordinates the operation and control of these modules. The latter in turn is controlled through personal computer (PC) based custom made software developed with LabView. An innovative summing amplifier concept was used to cancel out the base resistance of the thermistor. The latter was placed in the dewar. The temperature calibration was carried out with a standard platinum resistance (PT100) sensor coupled with an 8½ digit multimeter. The water equivalent of this calorimeter was determined by using electrical calibration with the joule calibrator. The experimentally measured values of the quantum of heat were validated by measuring heats of dissolution of pure KCl (for endotherm) and tris (hydroxyl methyl) amino-methane (for exotherm). The uncertainity in the measurements was found to be within ±3%.

  10. Thermodynamics analysis of refinery sludge gasification in adiabatic updraft gasifier.

    Ahmed, Reem; Sinnathambi, Chandra M; Eldmerdash, Usama; Subbarao, Duvvuri

    2014-01-01

    Limited information is available about the thermodynamic evaluation for biomass gasification process using updraft gasifier. Therefore, to minimize errors, the gasification of dry refinery sludge (DRS) is carried out in adiabatic system at atmospheric pressure under ambient air conditions. The objectives of this paper are to investigate the physical and chemical energy and exergy of product gas at different equivalent ratios (ER). It will also be used to determine whether the cold gas, exergy, and energy efficiencies of gases may be maximized by using secondary air injected to gasification zone under various ratios (0, 0.5, 1, and 1.5) at optimum ER of 0.195. From the results obtained, it is indicated that the chemical energy and exergy of producer gas are magnified by 5 and 10 times higher than their corresponding physical values, respectively. The cold gas, energy, and exergy efficiencies of DRS gasification are in the ranges of 22.9-55.5%, 43.7-72.4%, and 42.5-50.4%, respectively. Initially, all 3 efficiencies increase until they reach a maximum at the optimum ER of 0.195; thereafter, they decline with further increase in ER values. The injection of secondary air to gasification zone is also found to increase the cold gas, energy, and exergy efficiencies. A ratio of secondary air to primary air of 0.5 is found to be the optimum ratio for all 3 efficiencies to reach the maximum values.

  11. Land reform in Russia in 1990-2000-ies, or how land reform was "reformed" during the departmental reorganization

    Barsukova Svetlana, Yu.

    2015-06-01

    Full Text Available The paper provides an overview of the land reform in Russia's recent history. Analysis of land reform, which started in 1990, shows what actions and what logic led the land sector in the state in which it was at the finish line of the quarter-century reform marathon. The reform process was not linear, it highlighted the steps differing objectives and strategies to achieve them. Land reform is presented as a struggle of different political forces, which were reflected in the redistribution of functions between agencies in lobbying for appointment to senior positions promoted various commands. The authors conclude about the gradual displacement of state regulation of land relations, the deliberate destruction of the land management as a basis for the development of land resources.

  12. Phenomenon of transformed adiabatic shear band surrounded by deformed adiabatic shear band of ductile metal

    WANG Xue-bin

    2008-01-01

    The coexistent phenomenon of deformed and transformed adiabatic shear bands(ASBs) of ductile metal was analyzed using the JOHNSON-COOK model and gradient-dependent plasticity(GDP). The effects of melting point, density, heat capacity and work to heat conversion factor were investigated. Higher work to heat conversion factor, lower density, lower heat capacity and higher melting point lead to wider transformed ASB and higher local plastic shear deformation between deformed and transformed ASBs. Higher work to heat conversion factor, lower density, lower heat capacity and lower melting point cause higher local plastic shear deformation in the deformed ASB. Three reasons for the scatter in experimental data on the ASB width were pointed out and the advantages of the work were discussed. If the transformed ASB width is used to back-calculate the internal length parameter in the GDP, undoubtedly, the parameter will be extremely underestimated.

  13.  Railway Reforms

    Asmild, Mette; Holvad, Torben; Hougaard, Jens Leth;

    -directional Efficiency Analysis, which enables investigation of how railway reforms affect the inefficiencies of specific cost drivers. The main findings are that the reform initiatives generally improve operating efficiency but potentially differently for different cost drivers. Specifically, the paper provides clear......This paper considers railway operations in 23 European countries during 1995-2001, where a series of reform initiatives were launched by the European Commission, and analyses whether these reform initiatives improved the operating efficiency of the railways. Efficiency is measured using Multi...... empirical evidence that accounting separation is important for improving operating efficiency for both material and staff costs, whereas other reforms only influenced one of these factors...

  14. Constrained Adiabatic Trajectory Method (CATM): a global integrator for explicitly time-dependent Hamiltonians

    Leclerc, Arnaud; Viennot, David; Killingbeck, John P; 10.1063/1.3673320

    2012-01-01

    The Constrained Adiabatic Trajectory Method (CATM) is reexamined as an integrator for the Schr\\"odinger equation. An initial discussion places the CATM in the context of the different integrators used in the literature for time-independent or explicitly time-dependent Hamiltonians. The emphasis is put on adiabatic processes and within this adiabatic framework the interdependence between the CATM, the wave operator, the Floquet and the (t,t') theories is presented in detail. Two points are then more particularly analysed and illustrated by a numerical calculation describing the $H_2^+$ ion submitted to a laser pulse. The first point is the ability of the CATM to dilate the Hamiltonian spectrum and thus to make the perturbative treatment of the equations defining the wave function possible, possibly by using a Krylov subspace approach as a complement. The second point is the ability of the CATM to handle extremely complex time-dependencies, such as those which appear when interaction representations are used to...

  15. Constrained adiabatic trajectory method: A global integrator for explicitly time-dependent Hamiltonians

    Leclerc, A.; Jolicard, G.; Viennot, D.; Killingbeck, J. P.

    2012-01-01

    The constrained adiabatic trajectory method (CATM) is reexamined as an integrator for the Schrödinger equation. An initial discussion places the CATM in the context of the different integrators used in the literature for time-independent or explicitly time-dependent Hamiltonians. The emphasis is put on adiabatic processes and within this adiabatic framework the interdependence between the CATM, the wave operator, the Floquet, and the (t, t') theories is presented in detail. Two points are then more particularly analyzed and illustrated by a numerical calculation describing the H_2^+ ion submitted to a laser pulse. The first point is the ability of the CATM to dilate the Hamiltonian spectrum and thus to make the perturbative treatment of the equations defining the wave function possible, possibly by using a Krylov subspace approach as a complement. The second point is the ability of the CATM to handle extremely complex time-dependencies, such as those which appear when interaction representations are used to integrate the system.

  16. Global adiabaticity and non-Gaussianity consistency condition

    Romano, Antonio Enea; Sasaki, Misao

    2016-01-01

    In the context of single-field inflation, the conservation of the curvature perturbation on comoving slices, $R_c$, on super-horizon scales is one of the assumptions necessary to derive the consistency condition between the squeezed limit of the bispectrum and the spectrum of the primordial curvature perturbation. However, the conservation of $R_c$ holds only after the perturbation has reached the adiabatic limit where the constant mode of $R_c$ dominates over the other (usually decaying) mode. In this case, the non-adiabatic pressure perturbation defined in the thermodynamic sense, $\\delta P_{nad}\\equiv\\delta P-c_w^2\\delta\\rho$ where $c_w^2=\\dot P/\\dot\\rho$, usually becomes also negligible on superhorizon scales. Therefore one might think that the adiabatic limit is the same as thermodynamic adiabaticity. This is in fact not true. In other words, thermodynamic adiabaticity is not a sufficient condition for the conservation of $R_c$ on super-horizon scales. In this paper, we consider models that satisfies $\\d...

  17. Physics on the adiabatically changed Finslerian manifold and cosmology

    Lipovka, Anton A

    2016-01-01

    In present paper we confirm our previous result [4] that Planck constant is adiabatic invariant of electromagnetic field propagating on the adiabatically changed Finslerian manifold. Direct calculation from cosmological parameters gives value h=6x10(-27) (erg s). We also confirm that Planck constant (and hence other fundamental constants which depend on h) is varied on time due to changing of geometry. As an example the variation of the fine structure constant is calculated. Its relative variation ((da/dt)/a) consist 1.0x10(-18) (1/s). We show that on the Finsler manifold characterized by adiabatically changed geometry, classical free electromagnetic field is quantized geometrically, from the properties of the manifold in such manner that adiabatic invariant of field is ET=6x10(-27)=h. Electrodynamic equations on the Finslerian manifold are suggested. It is stressed that quantization naturally appears from these equations and is provoked by adiabatically changed geometry of manifold. We consider in details tw...

  18. Interplay between electric and magnetic effect in adiabatic polaritonic systems

    Alabastri, Alessandro

    2013-01-01

    We report on the possibility of realizing adiabatic compression of polaritonic wave on a metallic conical nano-structure through an oscillating electric potential (quasi dynamic regime). By comparing this result with an electromagnetic wave excitation, we were able to relate the classical lighting-rod effect to adiabatic compression. Furthermore, we show that while the magnetic contribution plays a marginal role in the formation of adiabatic compression, it provides a blue shift in the spectral region. In particular, magnetic permeability can be used as a free parameter for tuning the polaritonic resonances. The peculiar form of adiabatic compression is instead dictated by both the source and the metal permittivity. The analysis is performed by starting from a simple electrostatic system to end with the complete electromagnetic one through intermediate situations such as the quasi-electrostatic and quasi-dynamic regimes. Each configuration is defined by a particular set of equations which allows to clearly determine the individual role played by the electric and magnetic contribution in the generation of adiabatic compression. We notice that these findings can be applied for the realization of a THz nano-metric generator. © 2013 Optical Society of America.

  19. Adiabaticity and gravity theory independent conservation laws for cosmological perturbations

    Romano, Antonio Enea; Sasaki, Misao

    2015-01-01

    We carefully study the implications of adiabaticity for the behavior of cosmological perturbations. There are essentially three similar but different definitions of non-adiabaticity: one is appropriate for a thermodynamic fluid $\\delta P_{nad}$, another is for a general matter field $\\delta P_{c,nad}$, and the last one is valid only on superhorizon scales. The first two definitions coincide if $c_s^2=c_w^2$ where $c_s$ is the propagation speed of the perturbation, while $c_w^2=\\dot P/\\dot\\rho$. Assuming the adiabaticity in the general sense, $\\delta P_{c,nad}=0$, we derive a relation between the lapse function in the comoving slicing $A_c$ and $\\delta P_{nad}$ valid for arbitrary matter field in any theory of gravity, by using only momentum conservation. The relation implies that as long as $c_s\

  20. Adiabatic Quantum Computation is Equivalent to Standard Quantum Computation

    Aharonov, D; Kempe, J; Landau, Z; Lloyd, S; Regev, O; Aharonov, Dorit; Dam, Wim van; Kempe, Julia; Landau, Zeph; Lloyd, Seth; Regev, Oded

    2004-01-01

    Adiabatic quantum computation has recently attracted attention in the physics and computer science communities, but its computational power has been unknown. We settle this question and describe an efficient adiabatic simulation of any given quantum algorithm, which implies that the adiabatic computation model and the conventional quantum circuit model are polynomially equivalent. Our result can be extended to the physically realistic setting of particles arranged on a two-dimensional grid with nearest neighbor interactions. The equivalence between the models provides a new vantage point from which to tackle the central issues in quantum computation, namely designing new quantum algorithms and constructing fault tolerant quantum computers. In particular, by translating the main open questions in quantum algorithms to the language of spectral gaps of sparse matrices, the result makes quantum algorithmic questions accessible to a wider scientific audience, acquainted with mathematical physics, expander theory a...

  1. Semiclassical approximations for adiabatic slow-fast systems

    Teufel, Stefan

    2012-01-01

    In this letter we give a systematic derivation and justification of the semiclassical model for the slow degrees of freedom in adiabatic slow-fast systems first found by Littlejohn and Flynn [5]. The classical Hamiltonian obtains a correction due to the variation of the adiabatic subspaces and the symplectic form is modified by the curvature of the Berry connection. We show that this classical system can be used to approximate quantum mechanical expectations and the time-evolution of operators also in sub-leading order in the combined adiabatic and semiclassical limit. In solid state physics the corresponding semiclassical description of Bloch electrons has led to substantial progress during the recent years, see [1]. Here, as an illustration, we show how to compute the Piezo-current arising from a slow deformation of a crystal in the presence of a constant magnetic field.

  2. Teaching Reform and Practice of Circuit Course Based on the Process Assessment%基于过程考核的电路课程教学改革与实践

    吴卫兵; 高天星; 刘增良

    2015-01-01

    针对我国高校本科电气信息类专业必修的电路课程,介绍一种基于过程考核的学生成绩评价体系。讨论电路课程教学改革的动因,从考核内容与方法、教学方法与手段等方面详细介绍教学改革的实施路径和效果。从电路课程建设的角度出发,对相关问题进行探讨,并就过程考核如何促进课程改革提出了建设性的意见。%The article introduces a evaluation system of students' performance based on the process assessment which aims at cir-cuit course required of electrical and information professional for undergraduate college in our country.Discussing the motivation in teach-ing reform for circuit course,this essay presents the implementation paths and effectiveness of teaching reform from content and method of assessment to teaching methods in detail. This paper probes the relevant issues from the perspective of the circuit course construction, and makes constructive comments on how to promote the curriculum reform by the process assessment.

  3. 恩德粉煤气化装置空喷塔改造工艺计算%Process Calculation of Reformation for Empty Spray Tower in Ende Pulverized Coal Gasification Plant

    姜天夫

    2012-01-01

    Author has introduced the technical reformation scheme for the empty scrubber in Ende pulverized coal gasification plant and its process de- sign calculation principle ; the running effect indicates after reformation that the outlet temperature of water can be reduced from 60℃to 48℃, the con- tinuously running time of the empty scrubber is increased from less than 60 days to 100 days.%介绍了恩德粉煤气化装置空心洗涤塔的技术改造方案及其工艺设计计算过程;改造后的运行效果表明,出水温度由60℃降低到48℃,空心洗涤塔连续运行时间由不到60天增加到100天。

  4. Global adiabaticity and non-Gaussianity consistency condition

    Romano, Antonio Enea; Mooij, Sander; Sasaki, Misao

    2016-10-01

    In the context of single-field inflation, the conservation of the curvature perturbation on comoving slices, Rc, on super-horizon scales is one of the assumptions necessary to derive the consistency condition between the squeezed limit of the bispectrum and the spectrum of the primordial curvature perturbation. However, the conservation of Rc holds only after the perturbation has reached the adiabatic limit where the constant mode of Rc dominates over the other (usually decaying) mode. In this case, the non-adiabatic pressure perturbation defined in the thermodynamic sense, δPnad ≡ δP - cw2 δρ where cw2 = P ˙ / ρ ˙ , usually becomes also negligible on superhorizon scales. Therefore one might think that the adiabatic limit is the same as thermodynamic adiabaticity. This is in fact not true. In other words, thermodynamic adiabaticity is not a sufficient condition for the conservation of Rc on super-horizon scales. In this paper, we consider models that satisfy δPnad = 0 on all scales, which we call global adiabaticity (GA), which is guaranteed if cw2 = cs2 , where cs is the phase velocity of the propagation of the perturbation. A known example is the case of ultra-slow-roll (USR) inflation in which cw2 = cs2 = 1. In order to generalize USR we develop a method to find the Lagrangian of GA K-inflation models from the behavior of background quantities as functions of the scale factor. Applying this method we show that there indeed exists a wide class of GA models with cw2 = cs2, which allows Rc to grow on superhorizon scales, and hence violates the non-Gaussianity consistency condition.

  5. Global adiabaticity and non-Gaussianity consistency condition

    Antonio Enea Romano

    2016-10-01

    Full Text Available In the context of single-field inflation, the conservation of the curvature perturbation on comoving slices, Rc, on super-horizon scales is one of the assumptions necessary to derive the consistency condition between the squeezed limit of the bispectrum and the spectrum of the primordial curvature perturbation. However, the conservation of Rc holds only after the perturbation has reached the adiabatic limit where the constant mode of Rc dominates over the other (usually decaying mode. In this case, the non-adiabatic pressure perturbation defined in the thermodynamic sense, δPnad≡δP−cw2δρ where cw2=P˙/ρ˙, usually becomes also negligible on superhorizon scales. Therefore one might think that the adiabatic limit is the same as thermodynamic adiabaticity. This is in fact not true. In other words, thermodynamic adiabaticity is not a sufficient condition for the conservation of Rc on super-horizon scales. In this paper, we consider models that satisfy δPnad=0 on all scales, which we call global adiabaticity (GA, which is guaranteed if cw2=cs2, where cs is the phase velocity of the propagation of the perturbation. A known example is the case of ultra-slow-roll (USR inflation in which cw2=cs2=1. In order to generalize USR we develop a method to find the Lagrangian of GA K-inflation models from the behavior of background quantities as functions of the scale factor. Applying this method we show that there indeed exists a wide class of GA models with cw2=cs2, which allows Rc to grow on superhorizon scales, and hence violates the non-Gaussianity consistency condition.

  6. The adiabatic phase mixing and heating of electrons in Buneman turbulence

    Che, H.; Goldstein, M. L. [Goddard Space Flight Center, NASA, Greenbelt, Maryland 20771 (United States); Drake, J. F.; Swisdak, M. [IREAP, University of Maryland, College Park, Maryland 20742 (United States)

    2013-06-15

    The nonlinear development of the strong Buneman instability and the associated fast electron heating in thin current layers with Ω{sub e}/ω{sub pe}<1 is explored. Phase mixing of the electrons in wave potential troughs and a rapid increase in temperature are observed during the saturation of the instability. We show that the motion of trapped electrons can be described using a Hamiltonian formalism in the adiabatic approximation. The process of separatrix crossing as electrons are trapped and de-trapped is irreversible and guarantees that the resulting electron energy gain is a true heating process.

  7. Transient energy excitation in shortcuts to adiabaticity for the time dependent harmonic oscillator

    Chen, Xi

    2010-01-01

    There is recently a surge of interest to cut down the time it takes to change the state of a quantum system adiabatically. We study for the time-dependent harmonic oscillator the transient energy excitation in speed-up processes designed to reproduce the initial populations at some predetermined final frequency and time, providing lower bounds and examples. Implications for the limits imposed to the process times and for the principle of unattainability of the absolute zero, in a single expansion or in quantum refrigerator cycles, are drawn.

  8. Adiabatic hyperspherical approach to large-scale nuclear dynamics

    Suzuki, Yasuyuki

    2015-01-01

    We formulate a fully microscopic approach to large-scale nuclear dynamics using a hyperradius as a collective coordinate. An adiabatic potential is defined by taking account of all possible configurations at a fixed hyperradius, and its hyperradius dependence plays a key role in governing the global nuclear motion. In order to go to larger systems beyond few-body systems, we suggest basis functions of a microscopic multicluster model, propose a method for calculating matrix elements of an adiabatic Hamiltonian with use of Fourier transforms, and test its effectiveness.

  9. Nanoscale resolution for fluorescence microscopy via adiabatic passage

    Rubio, Juan Luis; Ahufinger, Verònica; Mompart, Jordi

    2015-01-01

    We propose the use of the subwavelength localization via adiabatic passage technique for fluorescence microscopy with nanoscale resolution in the far field. This technique uses a {\\Lambda}-type medium coherently coupled to two laser pulses: the pump, with a node in its spatial profile, and the Stokes. The population of the {\\Lambda} system is adiabatically transferred from one ground state to the other except at the node position, yielding a narrow population peak. This coherent localization allows fluorescence imaging with nanometer lateral resolution. We derive an analytical expression to asses the resolution and perform a comparison with the coherent population trapping and the stimulated-emission-depletion techniques.

  10. Microstructure evolution mechanism in adiabatic shear band in TA2

    杨扬; 熊俊; 杨续跃

    2004-01-01

    The micro structure evolution mechanism in adiabatic shear band in commercial pure titanium (TA2) at high strain rates(γ≈105 - 106/s) were studied. The nanosized recrystallized grains (about 50 nm in diameter) within the center of adiabatic shear band (ASB) were observed by means of transmission electronic microscope (TEM). A Rotational Dynamic Recrystallization (RDR) mechanism can explain the microstructure evolution (i. e. nanosized grains were formed within 5 - 10μs) in ASB. Kinetics calculations indicate that the recrystallized small grains are formed during the deformation and don't undergo significant growth by grain boundary migration after deformation.

  11. How to Make the Quantum Adiabatic Algorithm Fail

    Farhi, E; Gutmann, S; Nagaj, D; Farhi, Edward; Goldstone, Jeffrey; Gutmann, Sam; Nagaj, Daniel

    2005-01-01

    The quantum adiabatic algorithm is a Hamiltonian based quantum algorithm designed to find the minimum of a classical cost function whose domain has size N. We show that poor choices for the Hamiltonian can guarantee that the algorithm will not find the minimum if the run time grows more slowly than square root of N. These poor choices are nonlocal and wash out any structure in the cost function to be minimized and the best that can be hoped for is Grover speedup. These failures tell us what not to do when designing quantum adiabatic algorithms.

  12. Trace element mass balance in hydrous adiabatic mantle melting: The Hydrous Adiabatic Mantle Melting Simulator version 1 (HAMMS1)

    Kimura, Jun-Ichi; Kawabata, Hiroshi

    2014-06-01

    numerical mass balance calculation model for the adiabatic melting of a dry to hydrous peridotite has been programmed in order to simulate the trace element compositions of basalts from mid-ocean ridges, back-arc basins, ocean islands, and large igneous provinces. The Excel spreadsheet-based calculator, Hydrous Adiabatic Mantle Melting Simulator version 1 (HAMMS1) uses (1) a thermodynamic model of fractional adiabatic melting of mantle peridotite, with (2) the parameterized experimental melting relationships of primitive to depleted mantle sources in terms of pressure, temperature, water content, and degree of partial melting. The trace element composition of the model basalt is calculated from the accumulated incremental melts within the adiabatic melting regime, with consideration for source depletion. The mineralogic mode in the primitive to depleted source mantle in adiabat is calculated using parameterized experimental results. Partition coefficients of the trace elements of mantle minerals are parameterized to melt temperature mostly from a lattice strain model and are tested using the latest compilations of experimental results. The parameters that control the composition of trace elements in the model are as follows: (1) mantle potential temperature, (2) water content in the source mantle, (3) depth of termination of adiabatic melting, and (4) source mantle depletion. HAMMS1 enables us to obtain the above controlling parameters using Monte Carlo fitting calculations and by comparing the calculated basalt compositions to primary basalt compositions. Additionally, HAMMS1 compares melting parameters with a major element model, which uses petrogenetic grids formulated from experimental results, thus providing better constraints on the source conditions.

  13. Curriculum reform in China: Challenges and reflections

    Zhong Qi-quan

    2006-01-01

    With the implementation of the New Curriculum,conflicts between new and old ideas axe bound to arise.Voices supporting and protesting the reform will accompany the whole process.We have to expound our idea that quality education is an established policy that cannot be reverted,that curriculum reform must be carried out,and that any attempt to return to old curriculums may end in failure.The present paper explores the challenges to the basic curriculum reform and the relevant strategies through the analysis of educational phenomena of mainland China in recent years.

  14. [Reform of psychiatry in Spain].

    Pedrosa Gil, F; Luderer, H J

    2000-11-01

    Since the 1980's psychiatric care in Spain changed considerably (Reforma psiquiátrica española). In the course of this reform, many positive results were achieved. An extensive community network of mental health centres was build up which resulted in the majority of psychiatric patients being integrated in the Spanish general health care system and making a better organized mental health care structure possible. New legislation also improved the care and civil rights of patients. An analysis of the experiences of the Spanish psychiatric reform shows that the tendency to retain the old mental hospitals, alongside the other institutions still exists. The process of deinstitutionalization and the original aims of the psychiatric reform cannot only be satisfied by the closure of large psychiatric hospitals as during the reform new aspects and problems as well the great complexity of the task have become apparent. This article together with the details of the Spanish sources gives the German public a good overview of the developments in Spanish psychiatry.

  15. Catalytic reforming feed characterisation technique

    Larraz Mora, R.; Arvelo Alvarez, R. [Univ. of La Laguna, Chemical Engineering Dept., La Laguna (Spain)

    2002-09-01

    The catalytic reforming of naphtha is one of the major refinery processes, designed to increase the octane number of naphtha or to produce aromatics. The naphtha used as catalytic reformer feedstock usually contains a mixture of paraffins, naphthenes, and aromatics in the carbon number range C{sub 6} to C{sub 10}. The detailed chemical composition of the feed is necessary to predict the aromatics and hydrogen production as well as the operation severity. The analysis of feed naphtha is usually reported in terms of its ASTM distillation curve and API or specific gravity. Since reforming reactions are described in terms of lumped chemical species (paraffins, naphthenes and aromatics), a feed characterisation technique should be useful in order to predict reforming operating conditions and detect feed quality changes. Unfortunately online analyzer applications as cromatography or recently introduced naphtha NMR [1] are scarce in most of refineries. This work proposes an algorithmic characterisation method focusing on its main steps description. The method could help on the subjects previously described, finally a calculation example is shown. (orig.)

  16. Steepest Ascent Tariff Reforms

    Raimondos-Møller, Pascalis; Woodland, Alan D.

    2006-01-01

    a theoretical concept where the focus is upon the size of welfare gains accruing from tariff reforms rather than simply with the direction of welfare effects that has been the concern of theliterature.JEL code: F15.Keywords: Steepest ascent tariff reforms; piecemeal tariff policy; welfare; market access; small......This paper introduces the concept of a steepest ascent tariff reform for a small open economy. By construction, it is locally optimal in that it yields the highest gain in utility of any feasible tariff reform vector of the same length. Accordingly, it provides a convenient benchmark...... existing reforms are locally optimal, provide geometric illustrations and compare welfare effectiveness of reforms using numerical examples. Moreover, being a general concept, we apply it to the issue of market access and examine its implications. Overall, the paper's contribution lies in presenting...

  17. Towards robust dynamical decoupling and high fidelity adiabatic quantum computation

    Quiroz, Gregory

    Quantum computation (QC) relies on the ability to implement high-fidelity quantum gate operations and successfully preserve quantum state coherence. One of the most challenging obstacles for reliable QC is overcoming the inevitable interaction between a quantum system and its environment. Unwanted interactions result in decoherence processes that cause quantum states to deviate from a desired evolution, consequently leading to computational errors and loss of coherence. Dynamical decoupling (DD) is one such method, which seeks to attenuate the effects of decoherence by applying strong and expeditious control pulses solely to the system. Provided the pulses are applied over a time duration sufficiently shorter than the correlation time associated with the environment dynamics, DD effectively averages out undesirable interactions and preserves quantum states with a low probability of error, or fidelity loss. In this study various aspects of this approach are studied from sequence construction to applications of DD to protecting QC. First, a comprehensive examination of the error suppression properties of a near-optimal DD approach is given to understand the relationship between error suppression capabilities and the number of required DD control pulses in the case of ideal, instantaneous pulses. While such considerations are instructive for examining DD efficiency, i.e., performance vs the number of control pulses, high-fidelity DD in realizable systems is difficult to achieve due to intrinsic pulse imperfections which further contribute to decoherence. As a second consideration, it is shown how one can overcome this hurdle and achieve robustness and recover high-fidelity DD in the presence of faulty control pulses using Genetic Algorithm optimization and sequence symmetrization. Thirdly, to illustrate the implementation of DD in conjunction with QC, the utilization of DD and quantum error correction codes (QECCs) as a protection method for adiabatic quantum

  18. Kristeva's Reformation

    Kelly Oliver

    2014-12-01

    Full Text Available In my brief remarks, I consider what it means to return and rebind—that is to say, the significance of the re for Kristeva’s thought.  Kristeva does not just talk about binding or birth, or unbinding or death, but rather rebinding and rebirth, suggesting that it is a retrospective return rather than an original moment that is crucial.  The most significant moment, then, is not the moment of imaginary plenitude, nor the moment of originary loss, but rather the moment of rebirth that comes through rebinding after the loss of plenitude.  Indeed, Kristeva’s insistence on re-turning suggests that there is no originary moment of plenitude nor of castration or loss, but rather a constant movement of compensation for a recurrent loss.  By emphasizing rebinding and rebirth, she underscores not the loss as cutting wound but rather the healing power of signification, always already inherent within loss.  The flip-side of separation is reattachment.  And rather than just focus on the separation or cut, Kristeva looks to that which allows us to rebind and reattach in order to create relations that sustain us.  Both unbinding and binding are necessary for rebinding.  Thus, by focusing on rebinding, Kristeva insists on the process of unbinding and binding, and the oscillation between them.

  19. 《GNSS 测量与数据处理》讲座式授课改革与实践%Reform and Practice of the Teaching-Lecture Responsibility System on GNSS Surveying and Data-Processing

    刘智敏; 于胜文; 张凯华; 郝建录

    2013-01-01

    随着测绘就业市场对高校测绘毕业生的综合素质和创新能力要求的提高,进行测绘工程专业教学改革势在必行。GNSS测量与数据处理课程进行了讲座责任制的课程改革试点,讲座责任制是实现“以学生为主体,以工程项目为主线,以教师为主导,以能力培养为目标”的教学改革授课模式,通过教学改革方案实施、考试制度改革和学生问卷调查,得到了有益结论和改进措施。%When Geomatics university graduates were remanded to higher comprehensive quality and innovation ability by the employment market ,Geomatics engineering professional reform became imperative .The reform of teaching-lecture responsibility system was imple-mented on GNSS surveying and data processing ,The aims on"the university student as main body ,the teacher as led , project as main-line ,in order to increase capability"were realized by teaching-lecture responsibility system .Through teaching reform program ,the examina-tion system reform and student questionnaires , the useful conclusions and improvement measures were obtained .

  20. Reform and Discussion of Digital Image Processing Teaching Based on C-CDIO Mode%基于C-CDIO模式的“数字图像处理”课程教学改革与探讨

    刘伟; 郑扬冰; 刘红钊; 崔明月; 李根全; 黄荣杰

    2015-01-01

    CDIO体现了最新工程教育理念,是工程教育改革的最新成果。在此基础上,结合“数字图像处理”课程实践性和专业性强的特点,有针对性的进一步发展了以集成化课程链、应用化教学链、协作化实验链为特点的C-CDIO模式来探索“数字图像处理”课程教学改革。该教学改革打破了传统专业课教学模式,在提高学生工程意识,项目构思、设计、实施和操作的能力,以及团队合作精神等方面取得显著效果。%CDIO embodies the latest engineering education concept, and is the latest achievements in the reform of engineering education. On this basis, combing with the practical and professional characteristics of digital image processing teaching, we ex-plored its teaching reform with C-CDIO mode. This mode is mainly formed by three reform chains, including:integrated curricu-lum chain, application based teaching chain and cooperation featured experiment chain. The teaching reform broke the tradition-al courses teaching mode, and achieved remarkable results in improving students' engineering consciousness, project concep-tion, design, implementation and operation ability, as well as team spirit and so on.

  1. Adiabatic frequency conversion with a sign flip in the coupling

    Hristova, H. S.; Rangelov, A. A.; Montemezzani, G.; Vitanov, N. V.

    2016-09-01

    Adiabatic frequency conversion is a method recently developed in nonlinear optics [H. Suchowski, D. Oron, A. Arie, and Y. Silberberg, Phys. Rev. A 78, 063821 (2008), 10.1103/PhysRevA.78.063821], using ideas from the technique of rapid adiabatic passage (RAP) via a level crossing in quantum physics. In this method, the coupling coefficients are constant and the phase mismatch is chirped adiabatically. In this work, we propose another method for adiabatic frequency conversion, in which the phase mismatch is constant and the coupling is a pulse-shaped function with a sign flip (i.e., a phase step of π ) at its maximum. Compared to the RAP method, our technique has comparable efficiency but it is simpler to implement for it only needs two bulk crystals with opposite χ(2 ) nonlinearity. Moreover, because our technique requires constant nonzero frequency mismatch and has zero conversion efficiency on exact frequency matching, it can be used as a frequency filter.

  2. On Models of Nonlinear Evolution Paths in Adiabatic Quantum Algorithms

    SUN Jie; LU Song-Feng; Samuel L.Braunstein

    2013-01-01

    In this paper,we study two different nonlinear interpolating paths in adiabatic evolution algorithms for solving a particular class of quantum search problems where both the initial and final Hamiltonian are one-dimensional projector Hamiltonians on the corresponding ground state.If the overlap between the initial state and final state of the quantum system is not equal to zero,both of these models can provide a constant time speedup over the usual adiabatic algorithms by increasing some another corresponding "complexity".But when the initial state has a zero overlap with the solution state in the problem,the second model leads to an infinite time complexity of the algorithm for whatever interpolating functions being applied while the first one can still provide a constant running time.However,inspired by a related reference,a variant of the first model can be constructed which also fails for the problem when the overlap is exactly equal to zero if we want to make up the "intrinsic" fault of the second model — an increase in energy.Two concrete theorems are given to serve as explanations why neither of these two models can improve the usual adiabatic evolution algorithms for the phenomenon above.These just tell us what should be noted when using certain nonlinear evolution paths in adiabatic quantum algorithms for some special kind of problems.

  3. Flat FRW Cosmologies with Adiabatic Matter Creation Kinematic tests

    Lima, J A S

    1999-01-01

    Some observational consequences of a cosmological scenario driven by adiabatic matter creation are investigated. Exact expressions for the lookback time, age of the universe, luminosity distance, angular diameter, and galaxy number counts redshift relations are derived and their meaning discussed in detail. The expressions of the conventional FRW models are significantly modified and provide a powerful method to limit the parameters of the models.

  4. Digitized adiabatic quantum computing with a superconducting circuit

    Barends, R.; Shabani, A.; Lamata, L.; Kelly, J.; Mezzacapo, A.; Heras, U. Las; Babbush, R.; Fowler, A. G.; Campbell, B.; Chen, Yu; Chen, Z.; Chiaro, B.; Dunsworth, A.; Jeffrey, E.; Lucero, E.; Megrant, A.; Mutus, J. Y.; Neeley, M.; Neill, C.; O'Malley, P. J. J.; Quintana, C.; Roushan, P.; Sank, D.; Vainsencher, A.; Wenner, J.; White, T. C.; Solano, E.; Neven, H.; Martinis, John M.

    2016-06-01

    Quantum mechanics can help to solve complex problems in physics and chemistry, provided they can be programmed in a physical device. In adiabatic quantum computing, a system is slowly evolved from the ground state of a simple initial Hamiltonian to a final Hamiltonian that encodes a computational problem. The appeal of this approach lies in the combination of simplicity and generality; in principle, any problem can be encoded. In practice, applications are restricted by limited connectivity, available interactions and noise. A complementary approach is digital quantum computing, which enables the construction of arbitrary interactions and is compatible with error correction, but uses quantum circuit algorithms that are problem-specific. Here we combine the advantages of both approaches by implementing digitized adiabatic quantum computing in a superconducting system. We tomographically probe the system during the digitized evolution and explore the scaling of errors with system size. We then let the full system find the solution to random instances of the one-dimensional Ising problem as well as problem Hamiltonians that involve more complex interactions. This digital quantum simulation of the adiabatic algorithm consists of up to nine qubits and up to 1,000 quantum logic gates. The demonstration of digitized adiabatic quantum computing in the solid state opens a path to synthesizing long-range correlations and solving complex computational problems. When combined with fault-tolerance, our approach becomes a general-purpose algorithm that is scalable.

  5. Perturbation to Noether Symmetries and Adiabatic Invariants for Birkhoffian Systems

    Yi Zhang

    2015-01-01

    Full Text Available Based on El-Nabulsi dynamical model for a non-conservative system, the problem of perturbation to Noether symmetries and adiabatic invariants of a Birkhoffian system under the action of a small disturbance is proposed and studied. Firstly, the El-Nabulsi-Pfaff variational problem from extended exponentially fractional integral is presented and the El-Nabulsi-Birkhoff equations are established. Secondly, the definitions and the criterions criteria of the Noether symmetric transformations and quasisymmetric transformations of the Birkhoffian system are given, and the Noether theorems of the system are established, which reveal the inner relationship between the Noether symmetries and the conserved quantities. Thirdly, the perturbation of Noether symmetries under a small disturbance is studied, and corresponding adiabatic invariants are obtained. As special cases, the deductions in nonconservative Hamiltonian system and nonconservative Lagrangian system and standard Birkhoffian system are given. At the end of the paper, the case known as Hojman-Urrutia problem is discussed to investigate the Noether symmetries and the adiabatic invariants, the perturbation to Noether symmetries and the adiabatic invariants under El-Nabulsi dynamical model.

  6. High beta lasing in micropillar cavities with adiabatic layer design

    Lermer, M.; Gregersen, Niels; Lorke, M.;

    2013-01-01

    We report on lasing in optically pumped adiabatic micropillar cavities, based on the AlAs/GaAs material system. A detailed study of the threshold pump power and the spontaneous emission β factor in the lasing regime for different diameters dc is presented. We demonstrate a reduction of the thresh...

  7. Appearance of gauge fields and forces beyond the adiabatic approximation

    Gosselin, Pierre [Institut Fourier, UMR 5582 CNRS-UJF, UFR de Mathematiques, Universite Grenoble I, BP74, 38402 Saint Martin d' Heres, Cedex (France); Mohrbach, Herve, E-mail: mohrbach@univ-metz.f [Laboratoire de Physique Moleculaire et des Collisions, ICPMB-FR CNRS 2843, Universite Paul Verlaine-Metz, 57078 Metz Cedex 3 (France)

    2010-09-03

    We investigate the origin of quantum geometric phases, gauge fields and forces beyond the adiabatic regime. In particular, we extend the notions of geometric magnetic and electric forces discovered in studies of the Born-Oppenheimer approximation to arbitrary quantum systems described by matrix-valued quantum Hamiltonians. The results are illustrated by several physical relevant examples.

  8. Dark Energy and Dark Matter from an additional adiabatic fluid

    Dunsby, Peter K S; Reverberi, Lorenzo

    2016-01-01

    The Dark Sector is described by an additional barotropic fluid which evolves adiabatically during the universe's history and whose adiabatic exponent $\\gamma$ is derived from the standard definitions of specific heats. Although in general $\\gamma$ is a function of the redshift, the Hubble parameter and its derivatives, we find that our assumptions lead necessarily to solutions with $\\gamma = $ constant in a FLRW universe. The adiabatic fluid acts effectively as the sum of two distinct components, one evolving like non-relativistic matter and the other depending on the value of the adiabatic index. This makes the model particularly interesting as a way of simultaneously explaining the nature of both Dark Energy and Dark Matter, at least at the level of the background cosmology. The $\\Lambda$CDM model is included in this family of theories when $\\gamma = 0$. We fit our model to SNIa, $H(z)$ and BAO data, discussing the model selection criteria. The implications for the early-universe and the growth of small per...

  9. Dark energy and dark matter from an additional adiabatic fluid

    Dunsby, Peter K. S.; Luongo, Orlando; Reverberi, Lorenzo

    2016-10-01

    The dark sector is described by an additional barotropic fluid which evolves adiabatically during the Universe's history and whose adiabatic exponent γ is derived from the standard definitions of specific heats. Although in general γ is a function of the redshift, the Hubble parameter and its derivatives, we find that our assumptions lead necessarily to solutions with γ =constant in a Friedmann-Lemaître-Robertson-Walker universe. The adiabatic fluid acts effectively as the sum of two distinct components, one evolving like nonrelativistic matter and the other depending on the value of the adiabatic index. This makes the model particularly interesting as a way of simultaneously explaining the nature of both dark energy and dark matter, at least at the level of the background cosmology. The Λ CDM model is included in this family of theories when γ =0 . We fit our model to supernovae Ia, H (z ) and baryonic acoustic oscillation data, discussing the model selection criteria. The implications for the early Universe and the growth of small perturbations in this model are also discussed.

  10. Digitized adiabatic quantum computing with a superconducting circuit.

    Barends, R; Shabani, A; Lamata, L; Kelly, J; Mezzacapo, A; Las Heras, U; Babbush, R; Fowler, A G; Campbell, B; Chen, Yu; Chen, Z; Chiaro, B; Dunsworth, A; Jeffrey, E; Lucero, E; Megrant, A; Mutus, J Y; Neeley, M; Neill, C; O'Malley, P J J; Quintana, C; Roushan, P; Sank, D; Vainsencher, A; Wenner, J; White, T C; Solano, E; Neven, H; Martinis, John M

    2016-06-09

    Quantum mechanics can help to solve complex problems in physics and chemistry, provided they can be programmed in a physical device. In adiabatic quantum computing, a system is slowly evolved from the ground state of a simple initial Hamiltonian to a final Hamiltonian that encodes a computational problem. The appeal of this approach lies in the combination of simplicity and generality; in principle, any problem can be encoded. In practice, applications are restricted by limited connectivity, available interactions and noise. A complementary approach is digital quantum computing, which enables the construction of arbitrary interactions and is compatible with error correction, but uses quantum circuit algorithms that are problem-specific. Here we combine the advantages of both approaches by implementing digitized adiabatic quantum computing in a superconducting system. We tomographically probe the system during the digitized evolution and explore the scaling of errors with system size. We then let the full system find the solution to random instances of the one-dimensional Ising problem as well as problem Hamiltonians that involve more complex interactions. This digital quantum simulation of the adiabatic algorithm consists of up to nine qubits and up to 1,000 quantum logic gates. The demonstration of digitized adiabatic quantum computing in the solid state opens a path to synthesizing long-range correlations and solving complex computational problems. When combined with fault-tolerance, our approach becomes a general-purpose algorithm that is scalable.

  11. Adiabatic and diabatic aerosol transport to the Jungfraujoch

    Lugauer, M.; Baltensperger, U.; Furger, M.; Jost, D.T.; Schwikowski, M.; Gaeggeler, H.W. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-09-01

    Synoptic scale vertical motion, here detected by the geopotential height of the 500 hPa surface, mainly accounts for the aerosol transport to the Jungfraujoch in winter. In summer, diabatic convection provides the dominant vertical transport mechanism. Nevertheless, synoptic scale adiabatic motion still determines whether diabatic convection can develop. (author) 2 figs., 2 refs.

  12. Evolutions of Yang Phase Under Cyclic Condition and Adiabatic Condition

    QIAN Shang-Wu; GU Zhi-Yu

    2005-01-01

    There are three non-integrable phases in literatures: Berry phase, Aharonov-Anandan phase, and Yang phase. This article discusses the evolutions of Yang phase under the cyclic condition and the adiabatic condition for the generaltime-dependent harmonic oscillator, thus reveals the intimate relations between these three non-integrable phases.

  13. Perturbation to Noether-Mei Symmetry and Adiabatic Invariants for Nonholonomic Mechanical Systems in Phase Space

    ZHANG Ming-Jiang; FANG Jian-Hui; LU Kai

    2009-01-01

    Based on the concept of adiabatic invariant, the perturbation to Noether-Mei symmetry and adiabatic invariants for nonholonomic mechanical systems in phase space are studied. The definition of the perturbation to Noether-Mei symmetry for the system is presented, and the criterion of the perturbation to Noether-Mei symmetry is given. Meanwhile, the Noether adiabatic invariants and the Mei adiabatic invariants for the perturbed system are obtained.

  14. Electricity reform in developing and transition countries: A reappraisal

    Williams, J.H.; Ghanadan, R. [Energy and Resources Group, University of California at Berkeley, 310 Barrows Hall, Berkeley, CA 94720-3050 (United States)

    2006-05-15

    Since about 1990, many developing and transition countries have undertaken market-oriented reforms in their electric power sectors. Despite the widespread adoption of a standard policy model, reform processes and outcomes have often failed to meet expectations. Drawing on an extensive literature review and case studies in Asia, Africa, Latin America, and Eastern Europe, this paper describes common features of non-OECD electricity reform and reappraises reform policies and underlying assumptions. Comparison with the sector-focused policy goals of deregulation in OECD countries highlights the importance of national fiscal crises, macroeconomic reforms, and persuasion by multilateral lenders in shaping non-OECD reforms. It also makes clear reform's dependence on attracting foreign capital, and consequent vulnerability to volatile international financial conditions. Case studies of Bolivia, Ghana, India, Poland, and Thailand illustrate reform's diverse pathways and problems in different settings. A broad range of non-OECD reform experiences indicates that disappointing results have often resulted from a narrow focus on finance and cost recovery, inflexibly applied. The paper concludes that improving reform will require emphasizing a broader set of objectives, including service provision, public benefits, effective regulation, and social/political legitimacy. Above all, reforms must be based on realistic assessments of national needs and capabilities. (author)

  15. Perturbation and Adiabatic Invariants of Mei Symmetry for Nonholonomic Mechanical Systems

    DING Ning; FANG Jian-Hui; WANG Peng

    2007-01-01

    Based on the concept of adiabatic invariant,the perturbation and adiabatic invariants of the Mei symmetry for nonholonomic mechanical systems are studied.The exact invariants of the Mei symmetry for the system without perturbation are given,The perturbation to the Mei symmetry is discussed and the adiabatic invariants of the Mei symmetry for the perturbed system are obtained.

  16. Perturbation to Lie Symmetry and Lutzky Adiabatic Invariants for Lagrange Systems

    REN Ji-Rong; DING Ning; LI Ran; FANG Jian-Hui; DUAN Yi-Shi; WANG Peng; ZHANG Xiao-Ni

    2008-01-01

    Based on the concept of adiabatic invariant, perturbation to Lie symmetry and Lutzky adiabatic invariants for Lagrange systems are studied by using different methods from those of previous works. Exact invariants induced from Lie symmetry of the system without perturbation are given. Perturbation to Lie symmetry is discussed and Lutzky adiabatic invariants of the system subject to perturbation are obtained.

  17. Educational Reform in Mexico.

    Fuentes, Bertha Orozco; Elizando Y Carr, Sandra

    1993-01-01

    Since the 1970s, each presidential regime has presented an educational modernization reform program for Mexico. Although the various reforms have widened educational opportunities, the quality of education has continued to deteriorate because of student and teacher desertion, a low scholastic progress index, accessibility problems, lack of an…

  18. Comments on UN Reform

    YangHongxi; ZhangYaowu

    2004-01-01

    On October 9-13 2004, United Nations SecretaryGeneral Kofi Annan paid an official visit to China.During his stay, he had discussions with Chinese leaders on UN reform and changes in the international situation and etc. In recent 59th UN General Assembly Session, UN reform was also one of the hot topics.

  19. Steam Methane Reformation Testing for Air-Independent Solid Oxide Fuel Cell Systems

    Mwara, Kamwana N.

    2015-01-01

    Recently, NASA has been looking into utilizing landers that can be propelled by LOX-CH (sub 4), to be used for long duration missions. Using landers that utilize such propellants, also provides the opportunity to use solid oxide fuel cells as a power option, especially since they are able to process methane into a reactant through fuel reformation. One type of reformation, called steam methane reformation, is a process to reform methane into a hydrogen-rich product by reacting methane and steam (fuel cell exhaust) over a catalyst. A steam methane reformation system could potentially use the fuel cell's own exhaust to create a reactant stream that is hydrogen-rich, and requires less internal reforming of the incoming methane. Also, steam reformation may hold some advantages over other types of reforming, such as partial oxidation (PROX) reformation. Steam reformation does not require oxygen, while up to 25 percent can be lost in PROX reformation due to unusable CO (sub 2) reformation. NASA's Johnson Space Center has conducted various phases of steam methane reformation testing, as a viable solution for in-space reformation. This has included using two different types of catalysts, developing a custom reformer, and optimizing the test system to find the optimal performance parameters and operating conditions.

  20. Plasma catalytic reforming of methane

    Bromberg, L.; Cohn, D.R.; Rabinovich, A. [Massachusetts Inst. of Technology, Cambridge, MA (United States). Plasma Science and Fusion Center; Alexeev, N. [Russian Academy of Sciences, Moscow (Russian Federation). Baikov Inst. of Metallurgy

    1998-08-01

    Thermal plasma technology can be efficiently used in the production of hydrogen and hydrogen-rich gases from methane and a variety of fuels. This paper describes progress in plasma reforming experiments and calculations of high temperature conversion of methane using heterogeneous processes. The thermal plasma is a highly energetic state of matter that is characterized by extremely high temperatures (several thousand degrees Celsius) and high degree of dissociation and substantial degree of ionization. The high temperatures accelerate the reactions involved in the reforming process. Hydrogen-rich gas (50% H{sub 2}, 17% CO and 33% N{sub 2}, for partial oxidation/water shifting) can be efficiently made in compact plasma reformers. Experiments have been carried out in a small device (2--3 kW) and without the use of efficient heat regeneration. For partial oxidation/water shifting, it was determined that the specific energy consumption in the plasma reforming processes is 16 MJ/kg H{sub 2} with high conversion efficiencies. Larger plasmatrons, better reactor thermal insulation, efficient heat regeneration and improved plasma catalysis could also play a major role in specific energy consumption reduction and increasing the methane conversion. A system has been demonstrated for hydrogen production with low CO content ({approximately} 1.5%) with power densities of {approximately} 30 kW (H{sub 2} HHV)/liter of reactor, or {approximately} 10 m{sup 3}/hr H{sub 2} per liter of reactor. Power density should further increase with increased power and improved design.

  1. Adiabatic magnetocaloric temperature change in polycrystalline gadolinium – A new approach highlighting reversibility

    Mohammadreza Ghahremani

    2012-09-01

    Full Text Available The adiabatic temperature change (ΔT during the magnetization and demagnetization processes of bulk gadolinium is directly measured for several applied magnetic fields in the temperature range 285 K to 305 K. During the magnetization process, ΔT measurements display the same maximum for each applied field when plotted against the initial temperature (Ti. However, during the demagnetization process, the maximum ΔT varies for each applied field. This discrepancy between the magnetization and demagnetization measurements appears inconsistent with the reversibility of the magnetocaloric effect. A new approach is undertaken to highlight the reversibility of the magnetocaloric effect by plotting ΔT against the average temperature change (Tavg instead of Ti. The value of Tavg which corresponds to the maximum ΔT is found to increase linearly with the applied magnetic field, consistently for both the magnetization and demagnetization measurements. Solving the linear-fitting equations of these measurements gives a new, and more precise, Curie temperature measurement. This new approach confirmed that the relationship between the maximum adiabatic temperature change (ΔTpeak and the applied magnetic field is perfectly linear.

  2. RMB Interest Rate reform:Risk of International Monetary Environment

    Sun Xiaoqing

    2005-01-01

    @@ On July 21, 2005, the People's Bank of China announced a new reform plan, according to which, RMB would no longer be pegged to the U.S. dollar but would reform the exchange rate regime by moving into a managed floating exchange rate regime based on market supply and demand with reference to a basket of currencies. ① The reform is an important step in the process of China's reform and opening-up. Hence it has special significance for economic development of China. However,what merits attention is that the present international monetary regime is unstable, financial system is very fragile and big powers have shown an unwillingness to take financial cooperation.② This has posed great challenges to the process of RMB exchange rate reform. Now I would like to examine the possible risks of the reform and then try to make some suggestions through making some analysis of the status quo of international monetary and financial system.

  3. Methane reforming With CO2 to syngas over CeO2-promoted Ni/Al2O3-ZrO2 catalysts Prepared Via a direct sol-gel process

    Hansheng Li; Hang Xu; Jinfu Wang

    2011-01-01

    CeO2-promoted Ni/Al2O3-ZrO2 (Ni/Al2O3-ZrO2-CeO2) catalysts were prepared by a direct sol-gel process with citric acid as gelling agent.The catalysts used for the methane reforming with CO2 was studied by infrared spectroscopy (IR), thermal gravimetric analysis (TGA), microscopic analysis, X-ray diffraction (XRD) and temperature-programmed reduction (TPR).The catalytic performance for CO2 reforming of methane to synthesis gas was investigated in a continuous-flow micro-reactor under atmospheric pressure.TGA, IR, XRD and microscopic analysis show that the catalysts prepared by the direct sol-gel process consist of Ni particles with a nanostructure of around 5 nm and an amorphous-phase composite oxide support.There exists a chemical interaction between metallic Ni particles and supports, which makes metallic Ni well dispersed, highly active and stable.The addition of CeO2 effectively improves the dispersion and the stability of Ni particles of the prepared catalysts, and enhances the adsorption of CO2 on the surface of catalysts.The catalytic tests for methane reforming with CO2 to synthesis gas show that the Ni/Al2O3-ZrO2-CeO2 catalysts show excellent activity and stability compared with the Ni/Al2O3 catalyst.The excellent catalytic activity and stability of the Ni/Al2O3-ZrO2-CeO2 are attributed to the highly, uniformly and stably dispersed small metallic Ni particles, the high reducibility of the Ni oxides and the interaction between metallic Ni particles and the composite oxide supports.

  4. Work Process-oriented Practice Teaching Reform — FLASH Technology Courses, For Example%基于工作过程导向的实践教学改革研究——以FLASH技术课程为例

    蒋燕

    2013-01-01

    国家教育部在关于推进高等职业教育改革创新引领职业教育科学发展的若干意见中指出,高等职业教育人才培养中要改革培养模式,增强学生可持续发展能力,要把现代企业优秀文化理念融入人才培养全过程,强化学生职业道德和职业精神培养.该文主要以Flash技术课程为例,分析了以工作过程为导向从教学目标定位、重组教学内容、转变教学方式、调整考核评定、实践教学实施的保障等方面入手的教学改革研究.%National Ministry of Education, pointed out in a number of opinions on the promotion of vocational education re?form and innovation to lead the development of vocational education in science, to reform the personnel training in vocational education training mode to enhance students' capacity for sustainable development, it is necessary the outstanding cultural ideas of the modern enterprise financialthe whole process into personnel training, strengthening students' professional ethics and profes?sionalism training. In this paper, Flash technology courses, for example, the analysis of the work process-oriented teaching target?ing, recombinant teaching content, change teaching methods to adjust for the evaluation, and implementation of practice teach?ing security aspects of teaching reform research.

  5. Summary of Consultations on Child Care Reform = Sommaire des consultations sur la reforme des services de garde d'enfants.

    Ontario Ministry of Community and Social Services, Toronto.

    This document contains the English and French language versions of a report summarizing the results of a public consultation process on the subject of child care reform in Ontario, Canada. The process began with province-wide distribution of a public document called "Setting the Stage" which outlined a child care reform agenda as a focus for…

  6. Study and Analysis on Naphtha Catalytic Reforming Reactor Simulation

    Liang Ke min; Song Yongji; Pan Shiwei

    2004-01-01

    A naphtha catalytic reforming unit with four reactors connected in series is analyzed. A physical model is proposed to describe the catalytic reforming radial flow reactor. Kinetics and thermodynamics equations are selected to describe the naphtha catalytic reforming reaction characteristics based on idealizing the complex naphtha mixture to represent the paraffin, naphthene, and aromatic groups with individual compounds. The simulation results based on above models agree very well with actual operating data of process unit.

  7. Evaluation of Health Care System Reform in Hubei Province, China

    2014-01-01

    This study established a set of indicators for and evaluated the effects of health care system reform in Hubei Province (China) from 2009 to 2011 with the purpose of providing guidance to policy-makers regarding health care system reform. The resulting indicators are based on the “Result Chain” logic model and include the following four domains: Inputs and Processes, Outputs, Outcomes and Impact. Health care system reform was evaluated using the weighted TOPSIS and weighted Rank Sum Ratio met...

  8. Reforming Essential Oil%重整精油

    林翔云

    2013-01-01

    The necessity of reforming natural essential oil was introduced in this paper. By listing the example of reforming rose oil and lavender oil, the reforming method and process were studied.%讲述天然精油重整的必要性、重整方法和重整过程.列举了玫瑰与薰衣草2个重整精油实例以供参考.

  9. Experimental realization of non-adiabatic universal quantum gates using geometric Landau-Zener-Stückelberg interferometry.

    Wang, Li; Tu, Tao; Gong, Bo; Zhou, Cheng; Guo, Guang-Can

    2016-01-07

    High fidelity universal gates for quantum bits form an essential ingredient of quantum information processing. In particular, geometric gates have attracted attention because they have a higher intrinsic resistance to certain errors. However, their realization remains a challenge because of the need for complicated quantum control on a multi-level structure as well as meeting the adiabatic condition within a short decoherence time. Here, we demonstrate non-adiabatic quantum operations for a two-level system by applying a well-controlled geometric Landau-Zener-Stückelberg interferometry. By characterizing the gate quality, we also investigate the operation in the presence of realistic dephasing. Furthermore, the result provides an essential model suitable for understanding an interplay of geometric phase and Landau-Zener-Stückelberg process which are well explored separately.

  10. Adiabatic theory of solitons fed by dispersive waves

    Pickartz, Sabrina; Bandelow, Uwe; Amiranashvili, Shalva

    2016-09-01

    We consider scattering of low-amplitude dispersive waves at an intense optical soliton which constitutes a nonlinear perturbation of the refractive index. Specifically, we consider a single-mode optical fiber and a group velocity matched pair: an optical soliton and a nearly perfectly reflected dispersive wave, a fiber-optical analog of the event horizon. By combining (i) an adiabatic approach that is used in soliton perturbation theory and (ii) scattering theory from quantum mechanics, we give a quantitative account of the evolution of all soliton parameters. In particular, we quantify the increase in the soliton peak power that may result in the spontaneous appearance of an extremely large, so-called champion soliton. The presented adiabatic theory agrees well with the numerical solutions of the pulse propagation equation. Moreover, we predict the full frequency band of the scattered dispersive waves and explain an emerging caustic structure in the space-time domain.

  11. Stellar oscillations. II The non-adiabatic case

    Samadi, R; Sonoi, T

    2015-01-01

    A leap forward has been performed due to the space-borne missions, MOST, CoRoT and Kepler. They provided a wealth of observational data, and more precisely oscillation spectra, which have been (and are still) exploited to infer the internal structure of stars. While an adiabatic approach is often sufficient to get information on the stellar equilibrium structures it is not sufficient to get a full understanding of the physics of the oscillation. Indeed, it does not permit one to answer some fundamental questions about the oscillations, such as: What are the physical mechanisms responsible for the pulsations inside stars? What determines the amplitudes? To what extent the adiabatic approximation is valid? All these questions can only be addressed by considering the energy exchanges between the oscillations and the surrounding medium. This lecture therefore aims at considering the energetical aspects of stellar pulsations with particular emphasis on the driving and damping mechanisms. To this end, the full non-...

  12. Improved Refrigerant Characteristics Flow Predictions in Adiabatic Capillary Tube

    Shodiya Sulaimon

    2012-07-01

    Full Text Available This study presents improved refrigerant characteristics flow predictions using homogenous flow model in adiabatic capillary tube, used in small vapor compression refrigeration system. The model is based on fundamental equations of mass, momentum and energy. In order to improve the flow predictions, the inception of vaporization in the capillary tube is determined by evaluating initial vapor quality using enthalpy equation of refrigerant at saturation point and the inlet entrance effect of the capillary tube is also accounted for. Comparing this model with experimental data from open literature showed a reasonable agreement. Further comparison of this new model with earlier model of Bansal showed that the present model could be use to improve the performance predictions of refrigerant flow in adiabatic capillary tube.

  13. Multidimensional Study of High-Adiabat OMEGA Cryogenic Experiments

    Collins, T. J. B.; Betti, R.; Bose, A.; Christopherson, A. R.; Knauer, J. P.; Marozas, J. A.; Maximov, A. V.; Mora, A.; Radha, P. B.; Shang, W.; Shvydky, A.; Stoeckl, C.; Woo, K. M.; Varchas, G.

    2016-10-01

    Despite recent advances in modeling laser direct-drive inertial confinement fusion (ICF) experiments, there remains a predictability gap. This is particularly shown by the shortfall in hot-spot pressures inferred from OMEGA cryogenic implosions. To address this, a series of high-adiabat, cryogenic implosions were performed on OMEGA. These shots were performed with and without single-beam smoothing by spectral dispersion, at low and high drive intensities. These shots represent a regime where good agreement with simulation is expected because of the high adiabat. Multidimensional simulations of these shots will be presented with an emphasis on comparison with experimental indicators of departure from spherical symmetry (``1-D-ness''). The roles of short- and long-wavelength perturbations are considered. This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award Number DE-NA0001944.

  14. DESIGN OF TERNARY COUNTER BASED ON ADIABATIC DOMINO CIRCUIT

    Yang Qiankun; Wang Pengjun; Zheng Xuesong

    2013-01-01

    By researching the ternary counter and low power circuit design method,a novel design of low power ternary Domino counter on switch-level is proposed.Firstly,the switch-level structure expression of ternary loop operation circuit with enable pin is derived according to the switch-signal theory,and the one bit ternary counter is obtained combining the ternary adiabatic Domino literal operation circuit and buffer.Then the switch-level structure expression of enable signal circuit is derived,and the four bits ternary counter is obtained by cascade connection.Finally,the circuit is simulated by Spice tool and the output waveforms transform in proper order indicating that the logic function is correct.The energy consumption of the four bits ternary adiabatic Domino counter is 63% less than the conventional Domino counterpart.

  15. Crack propagation of Ti alloy via adiabatic shear bands

    Mendoza, I., E-mail: ivanmendozabravo@gmail.com [Instituto Tecnológico de Veracruz (Mexico); Villalobos, D. [Instituto Tecnológico de Veracruz (Mexico); Alexandrov, B.T. [The Ohio State University (United States)

    2015-10-01

    This study was focused on the characterization of the origin and mechanism of crack propagation as a result of hot induction bending of Ti alloy. Plates of Ti–6Al–4V alloy with 12.5 mm of thickness were submitted to hot induction bending below the beta transus temperature. Optical and scanning electron microscopy analysis showed crack formation in the tensile zone. Microstructural evidence showed that cracks propagate through the adiabatic shear bands by Dimple-Void mechanism. However, voids formation before shear banding also occurred. In both mechanisms adiabatic shear bands are formed via dynamic recrystallization where the alpha–beta interphase works as stress concentrator promoting the formation of dimples and voids.

  16. Particle creation and non-adiabatic transitions in quantum cosmology

    Massar, S

    1998-01-01

    The aim of this paper is to compute transitions amplitudes in quantum cosmology, and in particular pair creation amplitudes and radiative transitions. To this end, we apply a double adiabatic development to the solutions of the Wheeler-DeWitt equation restricted to mini-superspace wherein gravity is described by the scale factor $a$. The first development consists in working with instantaneous eigenstates, in $a$, of the matter Hamiltonian. The second development is applied to the gravitational part of the wave function and generalizes the usual WKB approximation. We then obtain an exact equation which replaces the Wheeler-DeWitt equation and determines the evolution, i.e. the dependence in $a$, of the coefficients of this double expansion. When working in the gravitational adiabatic approximation, the simplified equation delivers the unitary evolution of transition amplitudes occurring among instantaneous eigenstates. Upon abandoning this approximation, one finds that there is an additional coupling among ma...

  17. Adiabatic Tip-Plasmon Focusing for Nano-Raman Spectroscopy

    Berweger, Samuel; Atkin, Joanna M.; Olmon, Robert L.; Raschke, Markus Bernd

    2010-12-16

    True nanoscale optical spectroscopy requires the efficient delivery of light for a spatially nanoconfined excitation. We utilize adiabatic plasmon focusing to concentrate an optical field into the apex of a scanning probe tip of {approx}10 nm in radius. The conical tips with the ability for two-stage optical mode matching of the surface plasmon polariton (SPP) grating-coupling and the adiabatic propagating SPP conversion into a localized SPP at the tip apex represent a special optical antenna concept for far-field transduction into nanoscale excitation. The resulting high nanofocusing efficiency and the spatial separation of the plasmonic grating coupling element on the tip shaft from the near-field apex probe region allows for true background-free nanospectroscopy. As an application, we demonstrate tip-enhanced Raman spectroscopy (TERS) of surface molecules with enhanced contrast and its extension into the near-IR with 800 nm excitation.

  18. Linear response of galactic halos to adiabatic gravitational perturbations

    Murali, C; Murali, Chigurupati; Tremaine, Scott

    1997-01-01

    We determine the response of a self-similar isothermal stellar system to small adiabatic gravitational perturbations. For odd spherical harmonics, the response is identical to the response of the analogous isothermal fluid system. For even spherical harmonics, the response can be regarded as an infinite series of wavetrains in $\\log r$, implying alternating compression and rarefaction in equal logarithmic radius intervals. Partly because of the oscillatory nature of the solutions, tidal fields from external sources are not strongly amplified by an intervening isothermal stellar system, except at radii can even screen the external tidal field in a manner analogous to Debye screening. As Weinberg has pointed out, individual resonances in a stellar system can strongly amplify external tidal fields over a limited radial range, but we cannot address this possibility because we examine only adiabatic perturbations. We also discuss the application of our method to the halo response caused by the slow growth of an em...

  19. Robust quantum logic in neutral atoms via adiabatic Rydberg dressing

    Keating, Tyler; Cook, Robert L.; Hankin, Aaron M.; Jau, Yuan-Yu; Biedermann, Grant W.; Deutsch, Ivan H.

    2015-01-01

    We study a scheme for implementing a controlled-Z (cz) gate between two neutral-atom qubits based on the Rydberg blockade mechanism in a manner that is robust to errors caused by atomic motion. By employing adiabatic dressing of the ground electronic state, we can protect the gate from decoherence due to random phase errors that typically arise because of atomic thermal motion. In addition, the adiabatic protocol allows for a Doppler-free configuration that involves counterpropagating lasers in a σ+/σ- orthogonal polarization geometry that further reduces motional errors due to Doppler shifts. The residual motional error is dominated by dipole-dipole forces acting on doubly excited Rydberg atoms when the blockade is imperfect. For reasonable parameters, with qubits encoded into the clock states of 133Cs, we predict that our protocol could produce a cz gate in <10 μ s with error probability on the order of 10-3.

  20. Adiabatic Evolution in XXX Spin Chain is Fast

    Korepin, V

    2004-01-01

    Adiabatic theorem of quantum mechanics was used by E. Farhi, J. Goldstone, S. Gutmann and M. Sipser to design quantum algorithms of a new kind. A quantum computer evolves slowly enough, so that it remains in its instantaneous ground state, which tells the solution. We consider XXX Heisenberg spin chain. We rotate magnetic field and change its magnitude. The ground state evolves from a ferromagnetic one into a nontrivial ground state of XXX anti-ferromagnet. This adiabatic evolution goes very gently. Because of SU(2) symmetry and integrability only one mode get exited. We prove that the time of the evolution scales as a square root of number of qubits. This is faster then other known examples.

  1. Experimental Adiabatic Quantum Factorization under Ambient Conditions Based on a Solid-State Single Spin System.

    Xu, Kebiao; Xie, Tianyu; Li, Zhaokai; Xu, Xiangkun; Wang, Mengqi; Ye, Xiangyu; Kong, Fei; Geng, Jianpei; Duan, Changkui; Shi, Fazhan; Du, Jiangfeng

    2017-03-31

    The adiabatic quantum computation is a universal and robust method of quantum computing. In this architecture, the problem can be solved by adiabatically evolving the quantum processor from the ground state of a simple initial Hamiltonian to that of a final one, which encodes the solution of the problem. Adiabatic quantum computation has been proved to be a compatible candidate for scalable quantum computation. In this Letter, we report on the experimental realization of an adiabatic quantum algorithm on a single solid spin system under ambient conditions. All elements of adiabatic quantum computation, including initial state preparation, adiabatic evolution (simulated by optimal control), and final state read-out, are realized experimentally. As an example, we found the ground state of the problem Hamiltonian S_{z}I_{z} on our adiabatic quantum processor, which can be mapped to the factorization of 35 into its prime factors 5 and 7.

  2. Using the J1-J2 Quantum Spin Chain as an Adiabatic Quantum Data Bus

    Chancellor, Nicholas

    2012-01-01

    This paper investigates numerically a phenomenon which can be used to transport a single q-bit down a J1-J2 Heisenberg spin chain using a quantum adiabatic process. The motivation for investigating such processes comes from the idea that this method of transport could potentially be used as a means of sending data to various parts of a quantum computer made of artificial spins, and that this method could take advantage of the easily prepared ground state at the so called Majumdar-Ghosh point. We examine several annealing protocols for this process and find similar result for all of them. The annealing process works well up to a critical frustration threshold.

  3. Quantum state preparation in semiconductor dots by adiabatic rapid passage

    Wu, Yanwen; Piper, I.M.; Ediger, M.; Brereton, P.; Schmidgall, E. R.; Hugues, M.; Hopkinson, M.; Phillips, R.T.

    2010-01-01

    Preparation of a specific quantum state is a required step for a variety of proposed practical uses of quantum dynamics. We report an experimental demonstration of optical quantum state preparation in a semiconductor quantum dot with electrical readout, which contrasts with earlier work based on Rabi flopping in that the method is robust with respect to variation in the optical coupling. We use adiabatic rapid passage, which is capable of inverting single dots to a specified upper level. We d...

  4. Adiabatic Shear Bands in Simple and Dipolar Viscoplastic Materials

    1991-08-01

    shear banding, especially from a materials point oi *iew Experimental studies dealing with adiabatic .hear Danding mciude those of Zener and Hollomon...and especially in the region surrounding the center of the block, alters. The nonhomogeneity of the deformation near the corners is now evident...describe ehe work-hardening of the material and accounts approxi- mately for the history of ehe deformation. The rate of evolucion of 4> is assumed

  5. High-Fidelity Entangled Bell States via Shortcuts to Adiabaticity

    Paul, Koushik

    2016-01-01

    We present a couple of protocols based on shortcut to adiabaticity techniques for rapid generation of robust entangled Bell states in a system of two two-state systems. Our protocols rely on the so-called transitionless quantum driving (TQD) algorithm and Lewis-Riesenfeld invariant (LRI) method. Both TQD and LRI methods result in high fidelity in population transfer.Our study shows that it is possible to prepare an entangled state in infinitely short time without losing robustness and efficiency.

  6. Characterization of Adiabatic Noise in Charge-Based Coherent Nanodevices

    D'Arrigo, A.; Falci, G.; Mastellone, A.; Paladino, E.

    2008-10-01

    Low-frequency noise, often with 1/f spectrum, has been recognized as the main mechanism of decoherence in present-day solid state coherent nanodevices. The responsible degrees of freedom are almost static during the coherent time evolution of the device leading to effects analogous to inhomogeneous broadening in NMR. Here we present a characterization of the effects of adiabatic noise exploiting the tunability of nanodevices.

  7. Adiabatic trapping in coupled kinetic Alfven-acoustic waves

    Shah, H. A.; Ali, Z. [Department of Physics, G.C. University, 54000 Lahore (Pakistan); Masood, W. [COMSATS, Institute of Information Technology, Park Road, Chak Shahzad, Islamabad 44000 (Pakistan); National Centre for Physics (NCP), Shahdara Valley Road, 44000 Islamabad (Pakistan); Theoretical Plasma Physics Division, P. O. Nilore, Islamabad (Pakistan)

    2013-03-15

    In the present work, we have discussed the effects of adiabatic trapping of electrons on obliquely propagating Alfven waves in a low {beta} plasma. Using the two potential theory and employing the Sagdeev potential approach, we have investigated the existence of arbitrary amplitude coupled kinetic Alfven-acoustic solitary waves in both the sub and super Alfvenic cases. The results obtained have been analyzed and presented graphically and can be applied to regions of space where the low {beta} assumption holds true.

  8. Adiabatic Compression Sensitivity of AF-M315E

    2015-07-01

    is pressurized to specific driving pressures into an accumulator tank above a rapid-opening valve. This valve is placed directly above the burst disc...this mission. Of particular interest is the sensitivity of the propellant at elevated temperatures and the resulting system peak pressures and...dynamic response characteristics. For this study, an adiabatic compression U-tube apparatus was used to determine the driving pressure threshold levels

  9. Mapping the region of instability for adiabatic continuation method

    GUTIÉRREZHERNANDEZ, JUAN PABLO; Fontalvo Alzate, Javier; Gómez García, Miguel Ángel

    2011-01-01

    The pioneer schematic ideas of Kimura and Levenspiel (Ind. Eng. Chem. Proc. Des. Dev., 16 (1977) 145 – 148) have been developed to find numerically the region of instability for adiabatic packed bed reactors. Three different cases of special industrial interest and complexity are presented. The highly exothermic gas-phase reactions: ammonia synthesis, methanol production from syn-gas, and SO₂ oxidation. Equations were parameterized and solved according to a continuation homotopy numerical met...

  10. Excitation energies along a range-separated adiabatic connection

    Rebolini, Elisa, E-mail: rebolini@lct.jussieu.fr; Toulouse, Julien, E-mail: julien.toulouse@upmc.fr; Savin, Andreas, E-mail: savin@lct.jussieu.fr [Sorbonne Universités, UPMC Univ Paris 06, UMR 7616, Laboratoire de Chimie Théorique, F-75005 Paris (France); CNRS, UMR 7616, Laboratoire de Chimie Théorique, F-75005 Paris (France); Teale, Andrew M. [School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD (United Kingdom); Centre for Theoretical and Computational Chemistry, Department of Chemistry, University of Oslo, P.O. Box 1033 Blindern, N-0315 Oslo (Norway); Helgaker, Trygve [Centre for Theoretical and Computational Chemistry, Department of Chemistry, University of Oslo, P.O. Box 1033 Blindern, N-0315 Oslo (Norway)

    2014-07-28

    We present a study of the variation of total energies and excitation energies along a range-separated adiabatic connection. This connection links the non-interacting Kohn–Sham electronic system to the physical interacting system by progressively switching on the electron–electron interactions whilst simultaneously adjusting a one-electron effective potential so as to keep the ground-state density constant. The interactions are introduced in a range-dependent manner, first introducing predominantly long-range, and then all-range, interactions as the physical system is approached, as opposed to the conventional adiabatic connection where the interactions are introduced by globally scaling the standard Coulomb interaction. Reference data are reported for the He and Be atoms and the H{sub 2} molecule, obtained by calculating the short-range effective potential at the full configuration-interaction level using Lieb's Legendre-transform approach. As the strength of the electron–electron interactions increases, the excitation energies, calculated for the partially interacting systems along the adiabatic connection, offer increasingly accurate approximations to the exact excitation energies. Importantly, the excitation energies calculated at an intermediate point of the adiabatic connection are much better approximations to the exact excitation energies than are the corresponding Kohn–Sham excitation energies. This is particularly evident in situations involving strong static correlation effects and states with multiple excitation character, such as the dissociating H{sub 2} molecule. These results highlight the utility of long-range interacting reference systems as a starting point for the calculation of excitation energies and are of interest for developing and analyzing practical approximate range-separated density-functional methodologies.

  11. A field theory characterization of interacting adiabatic particles in cosmology

    Arteaga, Daniel

    2008-01-01

    We explore the adiabatic particle excitations of an interacting field in a cosmological background. By following the time-evolution of the quantum state corresponding to the particle excitation, we show how the basic properties characterizing the particle propagation can be recovered from the two-point propagators. As an application, we study the background-induced dissipative effects on the propagation of a two-level atom in an expanding universe.

  12. A field theory characterization of interacting adiabatic particles in cosmology

    Arteaga, Daniel [Departament de Fisica Fonamental and Institut de Ciencies del Cosmos, Facultat de Fisica, Universitat de Barcelona, Av. Diagonal 647, 08028 Barcelona (Spain)], E-mail: darteaga@ub.edu

    2008-08-07

    We explore the adiabatic particle excitations of an interacting field in a cosmological background. By following the time evolution of the quantum state corresponding to the particle excitation, we show how the basic properties characterizing the particle propagation can be recovered from the two-point propagators. As an application, we study the background-induced dissipative effects on the propagation of a two-level atom in an expanding universe.

  13. Adiabatic embedment of nanomechanical resonators in photonic microring cavities

    Xiong, Chi; Li, Mo; Rooks, Michael; Tang, Hong X

    2014-01-01

    We report a circuit cavity optomechanical system in which a nanomechanical resonator is adiabatically embedded inside an optical ring resonator with ultralow transition loss. The nanomechanical device forms part of the top layer of a horizontal silicon slot ring resonator, which enables dispersive coupling to the dielectric substrate via a tapered nanogap. Our measurements show nearly uncompromised optical quality factors (Q) after the release of the mechanical beam.

  14. Stimulated Raman adiabatic passage in physics, chemistry and beyond

    Nikolay V. Vitanov; Rangelov, Andon A.; Shore, Bruce W.; Bergmann, Klaas

    2016-01-01

    The technique of stimulated Raman adiabatic passage (STIRAP), which allows efficient and selective population transfer between quantum states without suffering loss due to spontaneous emission, was introduced in 1990 (Gaubatz \\emph{et al.}, J. Chem. Phys. \\textbf{92}, 5363, 1990). Since then STIRAP has emerged as an enabling methodology with widespread successful applications in many fields of physics, chemistry and beyond. This article reviews the many applications of STIRAP emphasizing the ...

  15. Dynamics of Quantum Adiabatic Evolution Algorithm for Number Partitioning

    Smelyanskiy, Vadius; vonToussaint, Udo V.; Timucin, Dogan A.; Clancy, Daniel (Technical Monitor)

    2002-01-01

    We have developed a general technique to study the dynamics of the quantum adiabatic evolution algorithm applied to random combinatorial optimization problems in the asymptotic limit of large problem size n. We use as an example the NP-complete Number Partitioning problem and map the algorithm dynamics to that of an auxiliary quantum spin glass system with the slowly varying Hamiltonian. We use a Green function method to obtain the adiabatic eigenstates and the minimum exitation gap, gmin = O(n2(sup -n/2)), corresponding to the exponential complexity of the algorithm for Number Partitioning. The key element of the analysis is the conditional energy distribution computed for the set of all spin configurations generated from a given (ancestor) configuration by simultaneous flipping of a fixed number of spins. For the problem in question this distribution is shown to depend on the ancestor spin configuration only via a certain parameter related to the energy of the configuration. As the result, the algorithm dynamics can be described in terms of one-dimensional quantum diffusion in the energy space. This effect provides a general limitation of a quantum adiabatic computation in random optimization problems. Analytical results are in agreement with the numerical simulation of the algorithm.

  16. Non-adiabatic oscillations of compact stars in general relativity

    Gualtieri, L; Miniutti, G

    2004-01-01

    We have developed a formalism to study non-adiabatic, non-radial oscillations of compact stars in the frequency domain including the effects of thermal diffusion in a general relativistic framework. When a general equation of state depending on temperature is used, the perturbations of the fluid result in heat flux which is coupled with the spacetime geometry through the Einstein field equations. Our results show that the frequency of the first pressure (p) and gravity (g) oscillation modes is significantly affected by thermal diffusion, while that of the fundamental (f) mode is basically unaltered due to the global nature of that oscillation. The damping time of the oscillations is generally much smaller than in the adiabatic case (more than two orders of magnitude for the p- and g-modes) reflecting the effect of thermal dissipation. Both the isothermal and adiabatic limits are recovered in our treatment and we study in more detail the intermediate regime. Our formalism finds its natural astrophysical applic...

  17. Steam bottoming cycle for an adiabatic diesel engine

    Poulin, E.; Demler, R.; Krepchin, I.; Walker, D.

    1984-03-01

    A study of steam bottoming cycles using adiabatic diesel engine exhaust heat projected substantial performance and economic benefits for long haul trucks. A parametric analysis of steam cycle and system component variables, system cost, size and performance was conducted. An 811 K/6.90 MPa state-of-the-art reciprocating expander steam system with a monotube boiler and radiator core condenser was selected for preliminary design. When applied to a NASA specified turbo-charged adiabatic diesel the bottoming system increased the diesel output by almost 18%. In a comparison of the costs of the diesel with bottoming system (TC/B) and a NASA specified turbocompound adiabatic diesel with after-cooling with the same total output, the annual fuel savings less the added maintenance cost was determined to cover the increased initial cost of the TC/B system in a payback period of 2.3 years. Also during this program steam bottoming system freeze protection strategies were developed, technological advances required for improved system reliability were considered and the cost and performance of advanced systems were evaluated.

  18. Adiabatic invariants for the regular region of the Dicke model

    Bastarrachea-Magnani, M. A.; Relaño, A.; Lerma-Hernández, S.; López-del-Carpio, B.; Chávez-Carlos, J.; Hirsch, J. G.

    2017-04-01

    Adiabatic invariants for the non-integrable Dicke model are introduced. They are shown to provide approximate second integrals of motion in the energy region where the system exhibits a regular dynamics. This low-energy region, present for any set of values of the Hamiltonian parameters is described both with a semiclassical and a full quantum analysis in a broad region of the parameter space. Peres lattices in this region exhibit that many observables vary smoothly with energy, along distinct lines which beg for a formal description. It is demonstrated how the adiabatic invariants provide a rationale to their presence in many cases. They are built employing the Born–Oppenheimer approximation, valid when a fast system is coupled to a much slower one. As the Dicke model has one bosonic and one fermionic degree of freedom, two versions of the approximation are used, depending on which one is the faster. In both cases a noticeably accord with exact numerical results is obtained. The employment of the adiabatic invariants provides a simple and clear theoretical framework to study the physical phenomenology associated to these regimes, far beyond the energies where a quadratic approximation around the minimal energy configuration can be used.

  19. Numerical study of polaron problem in the adiabatic limit

    Marsiglio, Frank; Li, Zhou; Blois, Cindy; Baillie, Devin

    2010-03-01

    We study the polaron problem in a one dimensional chain and on a two dimensional square lattice. The models we have used are the Holstein model and the Su-Schrieffer-Heeger (SSH) model. By a variational procedure based on the Lanczos method, we are able to examine the polaron problem in the limit when the mass of the ion is very large, i.e. close to the adiabatic limit. It is known that for the Holstein model there is no phase transition [1] for any nonzero phonon energy. It is also known that for the one dimensional Holstein or SSH model there will be long range order [2] (e.g. dimerization) in the adiabatic limit at half-filling. It is then interesting to study the long range order on a two dimensional square lattice in and away from the adiabatic limit. Moreover, recent progress for the single polaron near an impurity (disorder) [3] make it an interesting problem for studying bond length disorder which can change the hopping energy in a specific direction in the Holstein model. Reference: [1] H. Lowen, Phys.Rev.B 37, 8661 (1988) [2] J.E.Hirsch and E. Frandkin, Phys. Rev. Lett. 49, 402 (1982) [3]A.S.Mishchenko et.al Phys.Rev.B 79(2009) 180301(R)

  20. Quantum Adiabatic Algorithms, Small Gaps, and Different Paths

    Farhi, Edward; Gosset, David; Gutmann, Sam; Meyer, Harvey B; Shor, Peter

    2011-01-01

    We construct a set of instances of 3SAT which are not solved efficiently using the simplest quantum adiabatic algorithm. These instances are obtained by picking random clauses all consistent with two disparate planted solutions and then penalizing one of them with a single additional clause. We argue that by randomly modifying the beginning Hamiltonian, one obtains (with substantial probability) an adiabatic path that removes this difficulty. This suggests that the quantum adiabatic algorithm should in general be run on each instance with many different random paths leading to the problem Hamiltonian. We do not know whether this trick will help for a random instance of 3SAT (as opposed to an instance from the particular set we consider), especially if the instance has an exponential number of disparate assignments that violate few clauses. We use a continuous imaginary time Quantum Monte Carlo algorithm in a novel way to numerically investigate the ground state as well as the first excited state of our system...

  1. Atuarfitsialak: Greenland's Cultural Compatible Reform

    Wyatt, Tasha R.

    2012-01-01

    In 2002, Greenlandic reform leaders launched a comprehensive, nation-wide reform to create culturally compatible education. Greenland's reform work spans the entire educational system and includes preschool through higher education. To assist their efforts, reform leaders adopted the Standards for Effective Pedagogy developed at the Center for…

  2. ANeededReform

    2013-01-01

    In recent years, interest rate liberalization has become a hot topic amidst China’s ifnancial reforms. The People’s Bank of China (PBC) expanded the lfoating range of deposit and loan interest rates in 2012, and eliminated the lfoor on lending rates on July 20, 2013, a clear indication of the government’s intention to liberalize interest rates in future ifnancial reforms. Jia kang, Director of the Research Institute of Fiscal Science under the Ministry of Finance, and meng yan, an associate researcher at the Research Institute of Fiscal Science, believe that the interest rate liberalization is vital to China’s ifnancial reforms. Excerpts of their thoughts follow.

  3. Tax reform Ukraine: implementation mechanisms and consequences

    J.Lebedzevіch

    2015-06-01

    Full Text Available In the article the main shortcomings of the existing domestic tax systems, which were the main reasons for the need for its reform in the context of integration into the European Community. Determined the first stage of reforming tax systems Ukraine, which is associated with the adoption of the Law of Ukraine «On Amendments to the Tax Code of Ukraine and laws of Ukraine». The main provisions of this legal act, revealing the essence of the mechanism for implementing tax reform. Analyzed the mechanism of implementation of tax reform by analyzing the major innovations of the Tax Code of Ukraine and their comparison with the tax «standards» that operated the implementation of tax reform 2015. Thesis there is determined a number of tax loopholes and nedoopratsyuvan conducted tax reform and their implications for payers of taxes and duties, and the need for further research and improvement. The experience of European countries towards the introduction of electronic filing and processing of tax returns.

  4. Steam reforming of tars at low temperature and elevated pressure for model tar component naphthalene

    Speidel, Michael; Fischer, Holger

    2016-01-01

    A process of pressurized gasification and power generation in a hybrid system of Solid Oxide Fuel Cell (SOFC) and gas turbine enables an efficient use of biomass. This process requires tar reforming in order to protect the SOFC from plugging. Tars must be converted at 5 bar absolute pressure (bara) while avoiding secondary steam reforming of methane in order to reduce the required heat input for the tar reformer. This can be realized at low reforming temperatures (

  5. Adiabatic following in two-photon transition

    Nayfeh, M.H.; Nayfeh, A.H.

    1977-03-01

    The coherent interaction of two smoothly varying, near-resonant, two-photon pulses with a three-level system can be described by ''two-photon damped Bloch equations'' which are analogous to those for a one-photon transition in a two-level system except for the presence of a two-photon coupling and a frequency shift. These equations are solved for the cases ..gamma../sub 1/, ..gamma../sub 2/ very-much-less-than ..cap omega.., ..gamma../sub 1/ = ..gamma../sub 2/, and ..gamma../sub 2/k/sup 2/epsilon/sup 4//..cap omega../sup 2/, ..gamma../sub 1/ very-much-less-than ..cap omega.., where ..gamma../sub 1/ and ..gamma../sub 2/ are the atomic energy and phase relaxation widths, respectively, and ..cap omega.. is the Rabi frequency. The leading contribution to the refractive index is intensity dependent, caused by the level shifts inherent in multiphoton processes; it includes a relaxation dependent part which is important at times shorter than ..gamma../sup -1//sub 1/. The second-order contributions depend on the square of the intensity and the time-integrated square of the intensity. The latter contribution, which is relaxation dependent, causes line asymmetry at the long-wavelength wing; it consists of a term proportional to ..gamma../sub 2/-..gamma../sub 1/ and only important at early times and a term proportional to 2..gamma../sub 2/-..gamma../sub 1/.

  6. Power sector reforms in India

    Bajaj, Harbans L.; Sharma, Deepak

    2007-07-01

    India faces endemic electrical energy and peaking shortages. The Power Sector is plagued with mounting commercial losses due various inefficiencies, colossal commercial and technical losses and increasing subsidy burden on the states. These shortages have had a very detrimental effect on the overall economic growth of the country. In order to re-vitalise the sector and improve the techno-economic performance, the Government of India has initiated the reform process in 1991. This paper analyses the pre-reform era and identifies the key concerns which led to the initiation of the reforms. It also analyses the likely impact of the major policy and regulatory initiatives that have been undertaken since 1991 including the provisions of the new enactments which have come into force eventually in the form of The Electricity Act, 2003. This paper details out the key features of the Act and its likely impact on the Indian electricity industry in the emerging scenario. The paper also discusses major issues like power trading, role of regulator in the new regime, issue of open access, introduction of power markets and role of Appellate Tribunal for Electricity in harmonizing the orders of the various regulators.

  7. Reforming Schools: The Collective Doubting Perspective

    Schechter, Chen; Ganon-Shilon, Sherry

    2015-01-01

    Purpose: The ongoing challenge to sustain educational reforms requires a learning process through which doubt is induced as a means of fostering productive school change. The purpose of this paper is to explore the concept of doubt as well as the doubting process and its importance to the school community, particularly with regard to educational…

  8. Where Is China’s Medical Reform Heading?

    李明锋

    2008-01-01

    How to establish a perfect medical system has always been a global challenge. If there was one event that commanded most of our attention from start to finish in 2007, it was medical reform. In the past, China underwent two medical system periods: one during the planned economy and another during the reform-and-opening-up period characterized by market-oriented reform. In 2006, after ten years of reform efforts, China’s healthcare system found itself almost back where it started, a process that has brought with it its share of resentment and expectations from the public at large.

  9. Discussion on China's Power Sector Reforms and Where to Next?

    Li, Qingnan; Ma, Zheng; Jørgensen, Bo Nørregaard

    2016-01-01

    This paper reviews the reform history of China's Power sector, and evaluates its reform conversion process with a focus of deregulated electricity market based on the literatures and other European countries’ experience. Furthermore, the current China's electricity industry is investigated by using...... the SWOT analysis (strengths, weaknesses, opportunities, and threats). The research results show that, after a series of reform actions, China's Power sector has shifted from an absolute monopoly to a relative monopoly. This paper conducts four strategic recommendations for the acceleration of China......'s power sector reform and the stability of its electricity market in a deregulated environment....

  10. Non-adiabatic molecular dynamic simulations of opening reaction of molecular junctions

    Zobač, Vladmír; Lewis, James P.; Jelínek, Pavel

    2016-07-01

    We report non-adiabatic molecular dynamic simulations of the ring opening reaction of diarylethene (DAE) derivative molecules, both free standing and embedded between gold electrodes. Simulations are performed by the surface hopping method employing density functional theory. Typically, the free-standing molecules exhibit large quantum yields to open and close; however the process is quenched for the molecules embedded between electrodes. Our simulations reveal the importance of the DAE side chemical groups, which explain the efficiency of the quenching process. Namely, delocalization of the LUMO state contributes to electronic coupling between the molecule and electrodes, suppressing or enhancing the reaction process. The simulations indicate that a proper choice of the chemical side group, which provides the strong localization of the LUMO state, can substantially diminish the quenching mechanism. Additionally, we analyze a strong dependency of the quantum yield of the opening reaction coming from the mechanical strength of the molecules.

  11. The indonesia’s Police Reform Police in the Reform Era New Institutionalism Perspective

    ACHMAD NURMAND

    2016-05-01

    Full Text Available Since the reformation and democratization movement in 1998, Indonesians have faced a chronic corruption problem. At the beginning of reformation era in 1998 to fight against corruption, the Indonesian government reforms the organization structure of the Indonesia Police to be an independent body separated from the Military organization. The police reforms begun in 1999 and got legal foundation with Act No. 2/2002. However, since fourteen years, the level of police reform has not yet succeed because of low community satisfaction on police service and the intense conflicts always occur whenever ACA investigates the case of corruptions conducted by police leaders. Three conflicts between police institution and ACA have taken placed. By using institutionalism approach, this research focus on the reform in police themselves are major actors on how reforms are organized and managed. This study is interpretative in nature gained only through social constructions such as language, consciousness, shared meanings, documents, tools, and other artefacts’. This finding revealed that this unsuccessful institutionalization process took place in a context of the main task of police for communicty service. Second, the study has demonstrated that three concepts from institutional theory as aforementioned provided vocabularies and insights to explain the phenomenon under study.

  12. Railway Reform in China.

    1998-01-01

    The purpose of this working paper is to consider the current situation of Chinese Railways, the progress of reforms to date, and possible future developments. The first section describes the current problems of Chinese Railways, as a vast organisation subject to strong central control, facing enormous and rapidly growing demands which it is unable to satisfy. The progress of reform in Chinese Railways to date, and in particular the Economic Contract Responsibility System instituted in the lat...

  13. Steam reforming of ethanol

    Trane-Restrup, Rasmus; Dahl, Søren; Jensen, Anker Degn

    2013-01-01

    Steam reforming (SR) of oxygenated species like bio-oil or ethanol can be used to produce hydrogen or synthesis gas from renewable resources. However, deactivation due to carbon deposition is a major challenge for these processes. In this study, different strategies to minimize carbon deposition...... on Ni-based catalysts during SR of ethanol were investigated in a flow reactor. Four different supports for Ni were tested and Ce0.6Zr0.4O2 showed the highest activity, but also suffered from severe carbon deposition at 600 °C or below. Operation at 600 °C or above were needed for full conversion...... 400 ppm of the carbon in the feed at approx. 600 °C. The different promoters did not influence the product distribution to any significant extent. Selective poisoning with small amounts of K2SO4 on Ni–CeO2/MgAl2O4 at 600 °C decreased carbon deposition from 900 to 200 ppm of the carbon in the feed...

  14. O processo de Bolonha no espaço europeu e a reforma universitária brasileira/The Bologna process in the european space and the brazilian higher education reform

    Carmen Célia Barradas Correia Bastos

    2007-01-01

    Full Text Available Este artigo aborda questões que envolvem o movimento de reformas educacionais na educação superior, a partir do final do Século XX, como a Declaração de Bolonha assinada em 1999, por ministros da Educação europeus, e que promove, atualmente, a reforma chamada Processo de Bolonha. Outros documentos como a Declaração Mundial sobre Educação Superior, 1998, representam marco referencial das reformas a que se refere este texto. Em sua essência, os documentos europeus vinculam o movimento reformista da educação superior às necessidades contextualizadas pelo padrão de globalização da economia. São articulações que têm como base o incentivo à competitividade, mobilidade discente, adaptação ao mercado de trabalho. No Brasil, em que sentido é possível situar os reflexos desse movimento? Na busca desse entendimento, focalizamos o movimento empreendido pelo Ministério da Educação para discutir a reforma universitária para o país, em especial destacamos o Seminário Internacional Universidade XXI e a Declaração de Brasília. Resguardadas as especificidades de cada situação, vislumbramos refletir sobre possíveis intersecções dos movimentos reformistas na educação superior contemporânea. This article approaches questions that involve the movement of educational reforms in the higher education, from the end of Century XX, until the Declaration of Bologna signed in 1999, by European ministers of Education that promoted the reform called Bologna Process. Other documents as the World-wide Declaration on Higher Education, 1998, represent referential landmark of the reforms that this text is related to. In its essence, the European documents tie the reformist movement of the higher education to the necessities contextualized by the economy globalization standard. They are have as base the competitiveness encouragement, learning mobility, and adaptation to the work market. In Brazil, where is possible to point out the

  15. Tests of the CMB temperature-redshift relation, CMB spectral distortions and why adiabatic photon production is hard

    Chluba, Jens

    2014-01-01

    In the expanding Universe, the average temperature of the cosmic microwave background (CMB) is expected to depend like TCMB (1+z) on redshift z. Adiabatic photon production (or destruction) or deviations from isotropy and homogeneity could modify this scaling and several observational tests have been carried out in response. Here, we explain why `adiabatic' conditions are extremely difficult to establish in the redshift range targeted by these tests. Thus, instead of leading to a simple rescaling of the CMB temperature, a spectral distortion should be produced, which can be constrained using COBE/FIRAS. For scenarios with late photon production, tests of the temperature-redshift relation (TRR) should therefore be reinterpreted as weak spectral distortion limits, directly probing the energy dependence of the photon production process. For inhomogeneous cosmologies, a y-type distortion is produced, but this type of distortion can be created in several ways. Here, we briefly discuss possible effects that may hel...

  16. Non-adiabatic ab initio molecular dynamics of supersonic beam epitaxy of silicon carbide at room temperature.

    Taioli, Simone; Garberoglio, Giovanni; Simonucci, Stefano; a Beccara, Silvio; Aversa, Lucrezia; Nardi, Marco; Verucchi, Roberto; Iannotta, Salvatore; Dapor, Maurizio; Alfè, Dario

    2013-01-28

    In this work, we investigate the processes leading to the room-temperature growth of silicon carbide thin films by supersonic molecular beam epitaxy technique. We present experimental data showing that the collision of fullerene on a silicon surface induces strong chemical-physical perturbations and, for sufficient velocity, disruption of molecular bonds, and cage breaking with formation of nanostructures with different stoichiometric character. We show that in these out-of-equilibrium conditions, it is necessary to go beyond the standard implementations of density functional theory, as ab initio methods based on the Born-Oppenheimer approximation fail to capture the excited-state dynamics. In particular, we analyse the Si-C(60) collision within the non-adiabatic nuclear dynamics framework, where stochastic hops occur between adiabatic surfaces calculated with time-dependent density functional theory. This theoretical description of the C(60) impact on the Si surface is in good agreement with our experimental findings.

  17. Astrophysical fluid simulations of thermally ideal gases with non-constant adiabatic index: numerical implementation

    Vaidya, B; Bodo, G; Massaglia, S

    2015-01-01

    An Equation of State (\\textit{EoS}) closes the set of fluid equations. Although an ideal EoS with a constant \\textit{adiabatic index} $\\Gamma$ is the preferred choice due to its simplistic implementation, many astrophysical fluid simulations may benefit from a more sophisticated treatment that can account for diverse chemical processes. Here, we first review the basic thermodynamic principles of a gas mixture in terms of its thermal and caloric EoS by including effects like ionization, dissociation as well as temperature dependent degrees of freedom such as molecular vibrations and rotations. The formulation is revisited in the context of plasmas that are either in equilibrium conditions (local thermodynamic- or collisional excitation- equilibria) or described by non-equilibrium chemistry coupled to optically thin radiative cooling. We then present a numerical implementation of thermally ideal gases obeying a more general caloric EoS with non-constant adiabatic index in Godunov-type numerical schemes.We discu...

  18. Flapping current sheet motions in magnetotail excited by non-adiabatic ions: case study

    Wei, X., Jr.

    2015-12-01

    The current sheet is a crucial region of the magnetotail, where energy reserve and release take place. The origin of the up-down motions of the current sheet, referred to as flapping motions, is among the most fundamental issues of magnetotail dynamics. Observational evidences suggest that the flapping motion is a kind of internal excited kink-like waves, but its particular propagating features such as the low phase speeds and the propagating direction from the tail center toward flanks do not match any local generation mechanisms previously established so far. Here we report observations of the current sheet flapping motions induced by non-adiabatic ions in the magnetic field configurations with a finite guiding component, whose population present periodic hemispherical asymmetries. Three type of current sheet flapping event in this paper will be discussed. This current sheet flapping phenomenon implies that the excitation mechanism of the current sheet flapping motions is a self-circulation process between the non-adiabatic ion population and the current sheet equilibrium itself.

  19. The current sheet tiled and non-adiabatic ions effect on the flapping motion in magnetotail

    Wei, XinHua

    2016-04-01

    The current sheet is a crucial region of the magnetotail, where energy reserve and release take place. The origin of the up-down motions of the current sheet, referred to as flapping motions, is among the most fundamental issues of magnetotail dynamics. Observational evidences suggest that the flapping motion is a kind of internal excited kink-like waves, but its particular propagating features such as the low phase speeds and the propagating direction from the tail center toward flanks do not match any local generation mechanisms previously established so far. Here we report observations of the current sheet flapping motions induced by non-adiabatic ions in the magnetic field configurations with a finite guiding component, whose population present periodic hemispherical asymmetries. These flapping motion current sheet cases often observed tiled. The current sheet flapping phenomenon implies that the excitation mechanism of the current sheet flapping motions is a self-circulation process between the non-adiabatic ion population and the current sheet equilibrium itself.

  20. Risk evaluation on the basis of pressure rate measured by automatic pressure tracking adiabatic calorimeter.

    Iwata, Yusaku; Koseki, Hiroshi

    2008-11-15

    An automatic pressure tracking adiabatic calorimeter (APTAC) had been employed to obtain the thermokinetic and the vapor pressure data during runaway reactions. The APTAC is an adiabatic calorimeter with a large-scale sample mass and low thermal inertia, and is an extremely useful tool for assessing thermal hazards of reactive chemicals. The data obtained by the APTAC are important information for the design of the safe industrial process. The thermodynamics parameters and the gas production were discussed on the basis of the experimental data of various concentrations and weights of di-tert-butyl peroxide (DTBP)/toluene solution for the purpose of investigating the properties of the APTAC data. The thermal decomposition of DTBP was studied on the basis of the temperature data and the pressure data obtained by the APTAC. The activation energy and the frequency factor of DTBP are nearly constant and the same as the literature values in the concentrations between 20 and 60 wt.%. The pressure rise due to gas production is important data for designing the relief vent of a reactor. The time history of the gas production was investigated with various weights and concentrations. The total gas production index, which had the vapor pressure correction, was 1.0 in the decomposition of DTBP.

  1. Three-Body Coulomb Functions in the Hyperspherical Adiabatic Expansion Method

    Garrido, E.; Kievsky, A.; Viviani, M.

    2016-10-01

    In this work we describe a numerical method devised to compute continuum three-body wave functions. The method is implemented using the hyperspherical adiabatic expansion for the three-body wave function imposing a box boundary condition. The continuum energy spectrum results discretized and, for specific quantum number values, all the possible incoming and outgoing channels are simultaneously computed. For a given energy, the hyperradial continuum functions form a matrix whose ij-term refers to specific incoming and outgoing channels. When applied to three-body systems interacting only through the Coulomb potential, this method provides the adiabatic representation of the regular three-body Coulomb wave function. The computation of the irregular Coulomb wave function representation is also discussed. These regular and irregular Coulomb functions can be used to extract the {S} -matrix for those reactions where, together with some short-range potential, the Coulomb interaction is also present. The method is illustrated in the case of the 3→ 3 process of three alpha particles.

  2. Method for assessing modular concepts for reformate gas processing for PEM fuel cell systems for decentral power supply; Methodik zur Bewertung modularer Konzepte zur Reformatgasaufbereitung fuer PEM-Brennstoffzellenanlagen zur dezentralen Energieversorgung

    Gerber, J.

    2007-02-08

    The dissertation presents the fundamentals of hydrogen gas processing and CO gas purification methods and, on this basis, develops a method for energetic modularisation of the gas treatment process. All process stages are modelled and analyzed on the basis of mass and energy balances. The theoretical discussion of solution methods for the balance equations of the various process stages is limited to the steam reforming and CO gas purification system. Parameters are defined for energetic assessment of the process variants. The method leads to the identification of energetically optimized process variants. Its main goal is the optimum utilisation of process-internal energy and mass flows. The graphic pinch method is a key component of the method presented; it is adapted to the exemplary process. [German] In der Dissertation wird, ausgehend von der Darstellung der Grundlagen der Wasserstoffgasaufbereitungs- und CO-Gasreinigungsverfahren, eine Methodik zur energetischen Modularisierung des Gasaufbereitungsprozesses entwickelt. Die Modellierung und Analyse der einzelnen Prozessstufen erfolgt auf der Basis von Masse- und Energiebilanzen. Die theoretische Darstellung der Loesungsmethoden fuer die Bilanzgleichungen der einzelnen Prozessstufen ist dabei auf das System Dampfreformierung und CO-Gasreinigung eingegrenzt. Parameter zur energetischen Bewertung der Prozessvarianten werden definiert. Die Methodik fuehrt zur Eingrenzung energetisch optimierter Prozessvarianten. Ihr Hauptziel liegt in der optimalen Nutzung prozessinterner Energie- und Stoffstroeme. Ein zentraler Bestandteil der Methodik ist die graphische Pinch-Methode. Sie wird dem vorliegenden Prozess angepasst.

  3. Quantifying Waddington landscapes and paths of non-adiabatic cell fate decisions for differentiation, reprogramming and transdifferentiation

    Li, Chunhe; Wang, Jin

    2013-01-01

    Cellular differentiation, reprogramming and transdifferentiation are determined by underlying gene regulatory networks. Non-adiabatic regulation via slow binding/unbinding to the gene can be important in these cell fate decision-making processes. Based on a stem cell core gene network, we uncovered the stem cell developmental landscape. As the binding/unbinding speed decreases, the landscape topography changes from bistable attractors of stem and differentiated states to more attractors of stem and other different cell states as well as substates. Non-adiabaticity leads to more differentiated cell types and provides a natural explanation for the heterogeneity observed in the experiments. We quantified Waddington landscapes with two possible cell fate decision mechanisms by changing the regulation strength or regulation timescale (non-adiabaticity). Transition rates correlate with landscape topography through barrier heights between different states and quantitatively determine global stability. We found the optimal speeds of these cell fate decision-making processes. We quantified biological paths and predict that differentiation and reprogramming go through an intermediate state (IM1), whereas transdifferentiation goes through another intermediate state (IM2). Some predictions are confirmed by recent experimental studies. PMID:24132204

  4. Microstructural characteristics of adiabatic shear localization in a metastable beta titanium alloy deformed at high strain rate and elevated temperatures

    Zhan, Hongyi, E-mail: h.zhan@uq.edu.au [Centre for Advanced Materials Processing and Manufacture, School of Mechanical and Mining Engineering, The University of Queensland, St Lucia, Queensland 4072 (Australia); Zeng, Weidong [State Key Laboratory of Solidification Processing, School of Materials, Northwestern Polytechnical University, Xi' an 710072 (China); Wang, Gui [Centre for Advanced Materials Processing and Manufacture, School of Mechanical and Mining Engineering, The University of Queensland, St Lucia, Queensland 4072 (Australia); Defence Material Technology Centre, Level 2, 24 Wakefield St, Hawthorn, VIC 3122 (Australia); Kent, Damon [School of Science and Engineering, University of the Sunshine Coast, Sippy Downs, Queensland 4575 (Australia); Dargusch, Matthew [Centre for Advanced Materials Processing and Manufacture, School of Mechanical and Mining Engineering, The University of Queensland, St Lucia, Queensland 4072 (Australia); Defence Material Technology Centre, Level 2, 24 Wakefield St, Hawthorn, VIC 3122 (Australia)

    2015-04-15

    The microstructural evolution and grain refinement within adiabatic shear bands in the Ti6554 alloy deformed at high strain rates and elevated temperatures have been characterized using transmission electron microscopy. No stress drops were observed in the corresponding stress–strain curve, indicating that the initiation of adiabatic shear bands does not lead to the loss of load capacity for the Ti6554 alloy. The outer region of the shear bands mainly consists of cell structures bounded by dislocation clusters. Equiaxed subgrains in the core area of the shear band can be evolved from the subdivision of cell structures or reconstruction and transverse segmentation of dislocation clusters. It is proposed that dislocation activity dominates the grain refinement process. The rotational recrystallization mechanism may operate as the kinetic requirements for it are fulfilled. The coexistence of different substructures across the shear bands implies that the microstructural evolution inside the shear bands is not homogeneous and different grain refinement mechanisms may operate simultaneously to refine the structure. - Graphical abstract: Display Omitted - Highlights: • The microstructure within the adiabatic shear band was characterized by TEM. • No stress drops were observed in the corresponding stress–strain curve. • Dislocation activity dominated the grain refinement process. • The kinetic requirements for rotational recrystallization mechanism were fulfilled. • Different grain refinement mechanisms operated simultaneously to refine the structure.

  5. On the Function of the Trade Union in Process of Reforming an Enterprise%谈谈改制企业工会作用的发挥

    姜维顺

    2012-01-01

    改制后的工会组织,应着重围绕自身建设,发挥好凝聚作用;围绕安全生产,发挥好教育作用;围绕经济效益,发挥好引导作用;围绕和谐创建,发挥好渗透作用。%The reformed trade union should focus on when it should focus on playing the role of education, while omy. In the meanwhile, it should focus on playing the role the self - construction, playing the role of uniting it should focus on play the role of guarding for econ- of penetrating for the harmonious construction.

  6. Rethink of the Reform and Practice of Higher Vocational Curriculum Based on the Working Process%高职“基于工作过程”课程改革实践反思

    张郢峰

    2015-01-01

    当前经济形势下,高职院校的发展面临新的挑战,高职院校发展的基础是课程建设,利用校企双方优势互补、互相渗透,共同构建“基于工作过程”的课程体系、共同打造一流“双师型”教师队伍、共同进行教学质量监控与评价,才能确保课程改革走可持续发展道路,才能使职业教育改革具有生命力。%Under the current economic situation, the development of higher vocational colleges is facing new challenges. Curriculum construction is the foundation for the development of vocational colleges. By using the complementary advantages and mutual penetration of colleges and enterprises, the curriculum system based on the working process can be established, and the first-class dual-qualification teachers can also be built, and the teaching quality can be monitored and evaluated. It is ensured that the curriculum reform will be in the course of sustainable development, and the occupation education reform will be more vitality.

  7. 融合工艺知识的机械CAD/CAM课程教学改革%Teaching Reform of Integrating Process Knowledge on the Mechanical CAD/CAM Course

    郭利

    2015-01-01

    机械CAD/CAM课程是高职院校机械制造类专业的核心课程,目前机械CAD/CAM人才的综合应用能力相对薄弱,不能在企业发挥应有的作用。针对上述现状,提出了融合工艺知识的机械CAD/CAM课程教学改革模式,并实施了“小组讨论法”教学和教、学、做一体化教学,经实践证明,课程改革取得了很好的效果。%The mechanical CAD/CAM course is the core curriculum of the higher vocational colleges in the mechanical manufacturing specialized field. According to a large number of researches, the paper points out that the comprehensive capability of mechanical CAD/CAM talents is relatively weak and they can't play a proper role in the enterprise. According to current situation of the above, the teaching reform pattern of integrating process knowledge about the mechanical CAD/CAM course is put forward. At the same time, the teaching methods of group discussion and teach-Learn-Do integration are applied. The practice investigation indicates that the teaching reform has made remarkable progress.

  8. 基于工作过程导向的《审计》课程改革研究与实践%Research and Practice of Audit Curriculum Reform Based on Working Process Orientation

    吴万盛; 童莉莉

    2013-01-01

    Now working process oriented teaching mode has become the mainstream of teaching reform in higher vocational colleges. The teaching mode integrated the content and ability needed in work into teaching, and resolve the problems of disconnection between theory and practice. This article makes reform on the A udit course of financial management specialty in higher vocational colleges, designs five tasks, and has carried on the practice.%以工作过程为导向的教学模式已成为现今高职院校进行教学改革的主流,该教学模式将工作过程中所需的知识、能力融入到教学内容中,解决了理论与实践的脱节问题,本文通过对高职院校财务管理专业《审计》课程进行改革,设计了五项工作任务,并进行了实践。

  9. 应用型本科农药加工技术课程教学改革构想%Conception of the Course Reform of Pesticide Formulation Processing in Application-oriented Universities

    李凌绪; 李平亮; 邢小霞

    2016-01-01

    农药加工技术是植物保护专业的重要选修课,是紧密联系农药制剂生产的综合性、实践性课程,在以往的教学中比较重视理论教学,对实践能力的培养重视度不够。本文针对这一问题进行了分析,提出优化教学内容,改革教学方法,校企合作强化实践教学,建立以实践能力为主的评价体系,以提高学生的实践能力,适应用人单位的需求。%Pesticide formulation processing, an important selective course of plant protection major, is a comprehensive and practical course closely linked with pesticide preparation manufacture. The theory was emphasized more than the practical ability in the past teaching. Base on this problem, a series of effective teaching reform ideas such as optimizing the teaching content, reforming the teaching method, strengthening the practical teaching through the university-enterprise cooperation, building a new evaluating system based on the practical ability were introduced to improve the practical ability of students and fit the requirement of enterprises.

  10. Skill and application of accounting adjustment of housing sold in process of housing reform%房改房已售面积账务处理的技巧与应用

    杜亚辉; 王红; 马思潇; 王晓华

    2015-01-01

    Aiming at the requirements of accounting adjustment of units of housing sold in the process of housing reform ,the problems arising from the adjustment of building area in housing reform are analyzed and the general idea and measures of adjusting building area are put forward with the aid of the computer modeling to complete the adjustment ,thereby strengthening the management of fixed assets and safeguarding the rights and interests of state‐ow ned assets .%针对单位对房改房已售房产账务调整的要求,对房改房建筑面积调整过程中出现的问题进行分析,通过计算机建模辅助完成面积调整,提出面积调整的思路与处理方式,加强固定资产管理,保障国有资产权益。

  11. Environmental Reform in Asia: Comparions, Challenges, Next Steps

    Sonnenfeld, D.A.; Mol, A.P.J.

    2006-01-01

    Most comparative studies of environmental reform have focused on the experiences of advanced, industrialized societies in Europe and the Americas. But can these research traditions be applied when studying processes of environmental reform in Asia, a continent of crucial importance for the global en

  12. Bringing Home the Bacon: The Politics of Rural School Reform.

    Sher, Jonathan P.

    1983-01-01

    Self-interested political, corporate, and education leaders have undermined recent West Virginia court decisions mandating educational reform. Three implications are: (1) principals, teachers, parents, and students must be equal partners in the educaiton reform process; (2) a constituency for rural children is needed; and (3) rural educators must…

  13. Adiabatic demagnetization of a pyrochlore antiferromagnet Gd 2Ti 2O 7

    Sosin, S. S.; Prozorova, L. A.; Smirnov, A. I.; Golov, A. I.; Berkutov, I. B.; Petrenko, O. A.; Balakrishnan, G.; Zhitomirsky, M. E.

    2005-04-01

    An adiabatic demagnetization process is studied in the pyrochlore antiferromagnet Gd2Ti2O7. A strong cooling of the sample is observed by decreasing magnetic field in the range 120-60 kOe corresponding to a crossover between saturated and spin-liquid phases. This phenomenon indicates that a considerable part of the magnetic entropy associated with a macroscopic number of local soft modes survives in the strongly correlated paramagnetic state. Monte Carlo simulations demonstrate good agreement with the experiment. The cooling power of the process is experimentally estimated with a view to possible technical applications. The results on Gd2Ti2O7 are compared to those for Gd3Ga5O12, a related material for low-temperature magnetic cooling.

  14. Applications of Adiabatic Approximation to One- and Two-electron Phenomena in Strong Laser Fields

    Bondar, Denys

    2010-01-01

    The adiabatic approximation is a natural approach for the description of phenomena induced by low frequency laser radiation because the ratio of the laser frequency to the characteristic frequency of an atom or a molecule is a small parameter. Since the main aim of this work is the study of ionization phenomena, the version of the adiabatic approximation that can account for the transition from a bound state to the continuum must be employed. Despite much work in this topic, a universally accepted adiabatic approach of bound-free transitions is lacking. Hence, based on Savichev's modified adiabatic approximation [Sov. Phys. JETP 73, 803 (1991)], we first of all derive the most convenient form of the adiabatic approximation for the problems at hand. Connections of the obtained result with the quasiclassical approximation and other previous investigations are discussed. Then, such an adiabatic approximation is applied to single-electron ionization and non-sequential double ionization of atoms in a strong low fr...

  15. Shortcuts to adiabaticity by counterdiabatic driving for trapped-ion displacement in phase space

    An, Shuoming; Lv, Dingshun; Del Campo, Adolfo; Kim, Kihwan

    2016-09-01

    The application of adiabatic protocols in quantum technologies is severely limited by environmental sources of noise and decoherence. Shortcuts to adiabaticity by counterdiabatic driving constitute a powerful alternative that speed up time-evolution while mimicking adiabatic dynamics. Here we report the experimental implementation of counterdiabatic driving in a continuous variable system, a shortcut to the adiabatic transport of a trapped ion in phase space. The resulting dynamics is equivalent to a `fast-motion video' of the adiabatic trajectory. The robustness of this protocol is shown to surpass that of competing schemes based on classical local controls and Fourier optimization methods. Our results demonstrate that shortcuts to adiabaticity provide a robust speedup of quantum protocols of wide applicability in quantum technologies.

  16. Adiabatic quantum computing with spin qubits hosted by molecules.

    Yamamoto, Satoru; Nakazawa, Shigeaki; Sugisaki, Kenji; Sato, Kazunobu; Toyota, Kazuo; Shiomi, Daisuke; Takui, Takeji

    2015-01-28

    A molecular spin quantum computer (MSQC) requires electron spin qubits, which pulse-based electron spin/magnetic resonance (ESR/MR) techniques can afford to manipulate for implementing quantum gate operations in open shell molecular entities. Importantly, nuclear spins, which are topologically connected, particularly in organic molecular spin systems, are client qubits, while electron spins play a role of bus qubits. Here, we introduce the implementation for an adiabatic quantum algorithm, suggesting the possible utilization of molecular spins with optimized spin structures for MSQCs. We exemplify the utilization of an adiabatic factorization problem of 21, compared with the corresponding nuclear magnetic resonance (NMR) case. Two molecular spins are selected: one is a molecular spin composed of three exchange-coupled electrons as electron-only qubits and the other an electron-bus qubit with two client nuclear spin qubits. Their electronic spin structures are well characterized in terms of the quantum mechanical behaviour in the spin Hamiltonian. The implementation of adiabatic quantum computing/computation (AQC) has, for the first time, been achieved by establishing ESR/MR pulse sequences for effective spin Hamiltonians in a fully controlled manner of spin manipulation. The conquered pulse sequences have been compared with the NMR experiments and shown much faster CPU times corresponding to the interaction strength between the spins. Significant differences are shown in rotational operations and pulse intervals for ESR/MR operations. As a result, we suggest the advantages and possible utilization of the time-evolution based AQC approach for molecular spin quantum computers and molecular spin quantum simulators underlain by sophisticated ESR/MR pulsed spin technology.

  17. Non-adiabatic effects in thermochemistry, spectroscopy and kinetics: the general importance of all three Born-Oppenheimer breakdown corrections.

    Reimers, Jeffrey R; McKemmish, Laura K; McKenzie, Ross H; Hush, Noel S

    2015-10-14

    Using a simple model Hamiltonian, the three correction terms for Born-Oppenheimer (BO) breakdown, the adiabatic diagonal correction (DC), the first-derivative momentum non-adiabatic correction (FD), and the second-derivative kinetic-energy non-adiabatic correction (SD), are shown to all contribute to thermodynamic and spectroscopic properties as well as to thermal non-diabatic chemical reaction rates. While DC often accounts for >80% of thermodynamic and spectroscopic property changes, the commonly used practice of including only the FD correction in kinetics calculations is rarely found to be adequate. For electron-transfer reactions not in the inverted region, the common physical picture that diabatic processes occur because of surface hopping at the transition state is proven inadequate as the DC acts first to block access, increasing the transition state energy by (ℏω)(2)λ/16J(2) (where λ is the reorganization energy, J the electronic coupling and ω the vibration frequency). However, the rate constant in the weakly-coupled Golden-Rule limit is identified as being only inversely proportional to this change rather than exponentially damped, owing to the effects of tunneling and surface hopping. Such weakly-coupled long-range electron-transfer processes should therefore not be described as "non-adiabatic" processes as they are easily described by Born-Huang ground-state adiabatic surfaces made by adding the DC to the BO surfaces; instead, they should be called just "non-Born-Oppenheimer" processes. The model system studied consists of two diabatic harmonic potential-energy surfaces coupled linearly through a single vibration, the "two-site Holstein model". Analytical expressions are derived for the BO breakdown terms, and the model is solved over a large parameter space focusing on both the lowest-energy spectroscopic transitions and the quantum dynamics of coherent-state wavepackets. BO breakdown is investigated pertinent to: ammonia inversion, aromaticity

  18. 利用超低温冷冻技术改造真空溅镀产线%Reforming a vacuum sputtering line by ultralow-temperature freezing process

    刘辛; 徐斌; 邹寅峰

    2011-01-01

    Due to the high atmospheric humidity in sumer and autumn and the water vapor accompanied by workpieces to be coated and their holders, the time required for high vacuum in vacuum chamber is long in the continuous vacuum sputtering process. Thus, the whole production process becomes slow with the reduced utilization rate of productive capacity and increased energy consumption. For this reason, the original vacuum sputtering line was reformed via the ultralow-temperature freezing process with no change of the original layout in the line. As a result, the water vapor in vacuum chamber can be captured and collected quickly so as to acquire the high vacuum required in vacuum chamber, thus attaining the goal for reform.%在连续化真李溅镀生产实践中,由于夏秋两个季节的环境湿度大,加之待镀工件和夹具携带的水蒸气,使得真窄腔体达到要求的高真空时间较长.这样既延缓了生产节拍,降低了设备产能,又加大了能源消耗.在不改变原生产线设备布局的情况下,利用超低温冷冻技术对原生产线进行改造,以实现快速捕集真空腔体内的水气,使真空腔体迅速达到要求的高真空,并取得了良好效果.

  19. Reforming Science and Mathematics Education

    Lagowski, J. J.

    1995-09-01

    Since 1991, the National Science Foundation has signed cooperative agreements with 26 states to undertake ambitious and comprehensive initiatives to reform science, mathematics, and technology education. Collectively, those agreements are known as the State Systemic Initiatives (SSI's). Two complimentary programs, The Urban and Rural Systemic Initiatives (USI's and RSI's), address similar reforms in the nation's largest cities and poorest rural areas. The SSI Program departs significantly from past NSF practice in several ways. The funding is for a longer term and is larger in amount, and the NSF is taking a more activist role, seeking to leverage state and private funds and promote the coordination of programs within states. The Initiatives also have a stronger policy orientation than previous NSF programs have had. The NSF strategy is a reflection of the growing and widely held view that meaningful reforms in schools are most likely to be achieved through state initiatives that set clear and ambitious learning goals and standards; align all of the available policy levers in support of reform; stimulate school-level initiatives; and mobilize human and financial resources to support these changes. Two premises underlie systemic reform: (1) all children can meet significantly higher standards if they are asked to do so and given adequate opportunities to master the content, and (2) state and local policy changes can create opportunities by giving schools strong and consistent signals about the changes in practice and performance that are expected. Because this is an enormous investment of Federal resources that is intended to bring about deep, systemic improvement in the nation's ability to teach science and mathematics effectively, the NSF has contracted with a consortium of independent evaluators to conduct a review of the program. The first of the SSI's were funded in 1991, sufficiently long ago to begin to formulate some initial impressions of their impact. Take

  20. Adiabatic quantum computation and quantum annealing theory and practice

    McGeoch, Catherine C

    2014-01-01

    Adiabatic quantum computation (AQC) is an alternative to the better-known gate model of quantum computation. The two models are polynomially equivalent, but otherwise quite dissimilar: one property that distinguishes AQC from the gate model is its analog nature. Quantum annealing (QA) describes a type of heuristic search algorithm that can be implemented to run in the ``native instruction set'''' of an AQC platform. D-Wave Systems Inc. manufactures {quantum annealing processor chips} that exploit quantum properties to realize QA computations in hardware. The chips form the centerpiece of a nov

  1. Non-adiabatic study of the Kepler subgiant KIC 6442183

    Grosjean M.

    2015-01-01

    Full Text Available Thanks to the precision of Kepler observations, [3] were able to measure the linewidth and amplitude of individual modes (including mixed modes in several subgiant power spectra. We perform a forward modelling of a Kepler subgiant based on surface properties and observed frequencies. Non-adiabatic computations including a time- dependent treatment of convection give the lifetimes of radial and non-radial modes. Next, combining the lifetimes and inertias with a stochastic excitation model gives the amplitudes of the modes. We can now directly compare theoretical and observed linewidths and amplitudes of mixed-modes to obtain new constraints on our theoretical models.

  2. Adiabatic Passage of Collective Excitations in Atomic Ensembles

    LIYong; MIAOYuan-Xiu; SUNChang-Pu

    2004-01-01

    We describe a theoretical scheme that allows for transfer of quantum states of atomic collective excitation between two macroscopic atomic ensembles localized in two spatially-separated domains. The conception is based on the occurrence of double-exciton dark states due to the collective destructive quantum interference of the emissions from the two atomic ensembles. With an adiabatically coherence manipulation for the atom-field couplings by stimulated Rmann scattering, the dark states will extrapolate from an exciton state of an ensemble to that of another. This realizes the transport of quantum information among atomic ensembles.

  3. Adiabatic Passage of Collective Excitations in Atomic Ensembles

    LI Yong; MIAO Yuan-Xiu; SUN Chang-Pu

    2004-01-01

    We describe a theoretical scheme that allows for transfer of quantum states of atomic collective excitation between two macroscopic atomic ensembles localized in two spatially-separated domains. The conception is based on the occurrence of double-exciton dark states due to the collective destructive quantum interference of the emissions from the two atomic ensembles. With an adiabatically coherence manipulation for the atom-field couplings by stimulated Ramann scattering, the dark states will extrapolate from an exciton state of an ensemble to that of another. This realizes the transport of quantum information among atomic ensembles.

  4. Fast CNOT gate via shortcuts to adiabatic passage

    Wang, Zhe; Xia, Yan; Chen, Ye-Hong; Song, Jie

    2016-10-01

    Based on the shortcuts to adiabatic passage, we propose a scheme for directly implementing a controlled-not (CNOT) gate in a cavity quantum electrodynamics system. Moreover, we generalize the scheme to realize a CNOT gate in two separate cavities connected by an optical fiber. The strictly numerical simulation shows that the schemes are fast and insensitive to the decoherence caused by atomic spontaneous emission and photon leakage. In addition, the schemes can provide a theoretical basis for the manipulation of the multiqubit quantum gates in distant nodes of a quantum network.

  5. Adiabatic transport of qubits around a black hole

    Viennot, David

    2016-01-01

    We consider localized qubits evolving around a black hole following a quantum adiabatic dynamics. We develop a geometric structure (based on fibre bundles) permitting to describe the quantum states of a qubit and the spacetime geometry in a single framework. The quantum decoherence induced by the black hole on the qubit is analysed in this framework (the role of the dynamical and geometric phases in this decoherence is treated), especially for the quantum teleportation protocol when one qubit falls to the event horizon. A simple formula to compute the fidelity of the teleportation is derived. The case of a Schwarzschild black hole is analysed.

  6. Power comparison of CMOS and adiabatic full adder circuit

    Reddy, Sunil Gavaskar; 10.5121/vlsic.2011.2306

    2011-01-01

    Full adders are important components in applications such as digital signal processors (DSP) architectures and microprocessors. Apart from the basic addition adders also used in performing useful operations such as subtraction, multiplication, division, address calculation, etc. In most of these systems the adder lies in the critical path that determines the overall performance of the system. In this paper conventional complementary metal oxide semiconductor (CMOS) and adiabatic adder circuits are analyzed in terms of power and transistor count using 0.18UM technology.

  7. Diabatic Versus Adiabatic Calculation of Torsion-Vibration Interactions

    Hougen, Jon T.

    2013-06-01

    The introductory part of this talk will deal briefly with two historical topics: (i) use of the words adiabatic, nonadiabatic, and diabatic in thermodynamics and quantum mechanics, and (ii) application of diabatic and adiabatic ideas to vibrational energy level calculations for a pair of diatomic-molecule potential energy curves exhibiting an avoided crossing. The main part of the talk will be devoted to recent work with Li-Hong Xu and Ron Lees on how ab initio projected frequency calculations for small-amplitude vibrations along the large-amplitude internal rotation path in methanol can best be used to help guide experimental assignments and fits in the IR vibrational spectrum. The three CH stretching vibrations for CH_{3}OH can conveniently be represented as coefficients multiplying three different types of basis vibrations, i.e., as coefficients of: (i) the local mode C-H_i bond displacements δr_{i} for hydrogens H_{1}, H_{2} and H_{3} of the methyl top, (ii) symmetrized linear combinations of the three δr_{i} of species A_{1} oplus E in the permutation-inversion group G_{6} = C_{3v} appropriate for methanol, or (iii) symmetrized linear combinations of the three δr_{i} of species 2A_{1} oplus A_{2} in the permutation-inversion group G_{6}. In this talk, we will focus on diabatic and adiabatic computations for the A_{1} oplus E basis vibrations of case (ii) above. We will briefly explain how Jahn-Teller-like and Renner-Teller-like torsion-vibration interaction terms occurring in the potential energy expression in the diabatic calculation become torsion-vibration Coriolis interaction terms occurring in the kinetic energy expression of the adiabatic calculations, and also show how, for algebraically solvable parameter choices, the same energy levels are obtained from either calculation. A final conclusion as to which approach is computationally superior for the numerical data given in a quantum chemistry output file has not yet been arrived at.

  8. Adiabatic regularization of power spectra in nonminimally coupled chaotic inflation

    Alinea, Allan L.

    2016-10-01

    We investigate the effect of adiabatic regularization on both the tensor- and scalar-perturbation power spectra in nonminimally coupled chaotic inflation. Similar to that of the minimally coupled general single-field inflation, we find that the subtraction term is suppressed by an exponentially decaying factor involving the number of e -folds. By following the subtraction term long enough beyond horizon crossing, the regularized power spectrum tends to the ``bare'' power spectrum. This study justifies the use of the unregularized (``bare'') power spectrum in standard calculations.

  9. Nonlinear effects generation in non-adiabatically tapered fibres

    Palací, Jesús; Mas, Sara; Monzón-Hernández, David; Martí, Javier

    2015-12-01

    Nonlinear effects are observed in a non-adiabatically tapered optical fibre. The designed structure allows for the introduction of self-phase modulation, which is observed through pulse breaking and spectral broadening, in approximately a centimetre of propagation using a commercial telecom laser. These devices are simple to fabricate and suitable to generate and control a variety of nonlinear effects in practical applications because they do not experience short-term degradation as previously reported approaches. Experimental and theoretical results are obtained, showing a good agreement.

  10. ADELE adiabatic compressed air energy storage. Status and perspectives

    Freund, Sebastian [General Electric Deutschland Holding GmbH, Garching (Germany). GE Global Research Renewable Energy Systems Lab.; Marquardt, Roland; Moser, Peter [RWE Power AG, Essen (Germany). Research and Development Innovative Power Plant Technology

    2013-06-01

    This paper gives an overview about compressed air energy storage (CAES) technology and a summary of the ADELE programme, a multi-year R and D programme undertaken by a consortium led by RWE Power to develop adiabatic (A) CAES technology and commercialise the first plant. The ACAES technology is to utilise waste heat developing upon compression in order to increase the entire efficiency. The ADELE-ING project is to provide the basis for making the decision on the construction of a 85 MW prototype. (orig.)

  11. Adiabatic regularisation of power spectra in nonminimally coupled chaotic inflation

    Alinea, Allan L

    2016-01-01

    We investigate the effect of adiabatic regularisation on both the tensor- and scalar-perturbation power spectra in \\textit{nonminimally} coupled chaotic inflation. Similar to that of the \\textit{minimally} coupled general single-field inflation, we find that the subtraction term is suppressed by an exponentially decaying factor involving the number of $ e $-folds. By following the subtraction term long enough beyond horizon crossing, the regularised power spectrum tends to the "bare" power spectrum. This study justifies the use of the unregularised ("bare") power spectrum in standard calculations.

  12. Metallization of Nanofilms in Strong Adiabatic Electric Fields

    Durach, Maxim; Rusina, Anastasia; Kling, Matthias F.; Stockman, Mark I.

    2010-08-01

    We introduce an effect of metallization of dielectric nanofilms by strong, adiabatically varying electric fields. The metallization causes optical properties of a dielectric film to become similar to those of a plasmonic metal (strong absorption and negative permittivity at low optical frequencies). This is a quantum effect, which is exponentially size-dependent, occurring at fields on the order of 0.1V/Å and pulse durations ranging from ˜1fs to ˜10ns for a film thickness of 3-10 nm.

  13. From Classical Nonlinear Integrable Systems to Quantum Shortcuts to Adiabaticity

    Okuyama, Manaka; Takahashi, Kazutaka

    2016-08-01

    Using shortcuts to adiabaticity, we solve the time-dependent Schrödinger equation that is reduced to a classical nonlinear integrable equation. For a given time-dependent Hamiltonian, the counterdiabatic term is introduced to prevent nonadiabatic transitions. Using the fact that the equation for the dynamical invariant is equivalent to the Lax equation in nonlinear integrable systems, we obtain the counterdiabatic term exactly. The counterdiabatic term is available when the corresponding Lax pair exists and the solvable systems are classified in a unified and systematic way. Multisoliton potentials obtained from the Korteweg-de Vries equation and isotropic X Y spin chains from the Toda equations are studied in detail.

  14. Stimulated Raman adiabatic passage analogues in classical physics

    Rangelov, A A [University of Kassel, Heinrich-Plett-Str. 40, D-34132 Kassel (Germany); Vitanov, N V [Department of Physics, Sofia University, James Bourchier 5 blvd., 1164 Sofia (Bulgaria); Shore, B W [618 Escondido Cir., Livermore, CA (United States)

    2009-03-14

    Stimulated Raman adiabatic passage (STIRAP) is a well-established technique for producing coherent population transfer in a three-state quantum system. We here exploit the resemblance between the Schroedinger equation for such a quantum system and the Newton equation of motion for a classical system undergoing torque to discuss several classical analogues of STIRAP, notably the motion of a moving charged particle subject to the Lorentz force of a quasistatic magnetic field, the orientation of a magnetic moment in a slowly varying magnetic field and the Coriolis effect. Like STIRAP, these phenomena occur for counterintuitive motion of the torque and are robustly insensitive to small changes in the interaction properties.

  15. Understanding University Reform in Japan through the Prism of the Social Sciences

    Goodman, Roger

    2008-01-01

    This article looks at current university reforms in Japan through two slightly different social science prisms: how social science methodologies and theories can help us understand those reforms better and how social science teaching in universities will be affected by the current reform processes. (Contains 3 tables and 7 notes.)

  16. Learning dynamics and support for economic reforms: why good news can be bad

    S.J.G. van Wijnbergen; T. Willems

    2014-01-01

    Support for economic reforms has often shown puzzling dynamics: many reforms that began successfully lost public support. We show that learning dynamics can rationalize this paradox because the process of revealing reform outcomes is an example of sampling without replacement. We show that this conc

  17. Pharmacological Curriculum Reform of Vocational Clinical Major Based on the Working Process%基于工作过程的高职临床医学专业药理课程改革

    楚丽雅; 田维忠; 邵红英; 莫莉

    2013-01-01

    Objective: To investigate the pharmacology curriculum reform effect of vocational clinical major based on the work process and improve the quality of teaching. Methods:To conduct comparison study of two classes with the same teacher. To use traditional teaching methods in control classes; conduct work process-based curriculum reform in experimental class, and design course content in accordance with the patient's diagnosis and treatment process and the drug process, and build five learning contexts, 13 learning units, 56 project tasks, and integrate the teaching content of each unit with a comprehensive training project. After class to investigate the students in experimental class and the teachers about clinical training and internship with education and compare the summative assessment results of two classes. Results:The theoretical results and training assessment scores of experimental class is significantly higher than the control class (P<0.01);98.00%of the students in experimental class think that their self-learning ability is improved, 100%of the teachers think that they create a student-centered learning atmosphere. Conclusion: The pharmacology curriculum reform of vocational clinical major based on the working process adapts to the requirements of higher vocational education reform, and it pays more attention to high-end skilled expertise, and can improve the comprehensive professional abilities of the students.%  目的:探讨基于工作过程的高职临床医学专业药理课程改革效果,提高教学质量。方法:选择同一教师授课的两个班级进行对照研究。对照班采用传统授课方式;实验班实施基于工作过程的课程改革,按照病人的诊疗流程和用药过程设计课程内容,构建5个学习情境、13个学习单元、56个项目任务,每个单元用一个综合实训项目将教学内容串联在一起。授课后用自制调查问卷对实验班学生、临床见习和实习带教教

  18. Adiabatic heavy-ion fusion potentials for fusion at deep sub-barrier energies

    S V S Sastry; S Kailas; A K Mohanty; A Saxena

    2005-01-01

    The recently reported unusual behaviour of fusion cross-sections at extreme sub-barrier energies has been examined. The adiabatic limit of fusion barriers has been determined from experimental data using the barrier penetration model. These adiabatic barriers are consistent with the adiabatic fusion barriers derived from the modified Wilzynska–Wilzynski prescription. The fusion barrier systematics has been obtained for a wide range of heavy-ion systems.

  19. Perturbation to Symmetries and Adiabatic Invariants of Nonholonomic System in Terms of Quasi-coordinates

    2005-01-01

    Based on the theory of Lie symmetries and conserved quantities, the exact invariants and adiabatic invariants of nonholonomic system in terms of quasi-coordinates are studied. The perturbation to symmetries for the nonholonomic system in terms of quasi-coordinates under small excitation is discussed. The concept of high-order adiabatic invariant is presented, and the forms of exact invariants and adiabatic invariants as well as the conditions for their existence are given. Then the corresponding inverse problem is studied.

  20. Perturbation to Symmetries and Adiabatic Invariants of Nonholonomic Dynamical System of Relative Motion

    CHEN Xiang-Wei; WANG Ming-Quan; WANG Xin-Min

    2005-01-01

    Based on the theory of symmetries and conserved quantities, the exact invariants and adiabatic invariants of nonholonomic dynamical system of relative motion are studied. The perturbation to symmetries for the nonholonomic dynamical system of relative motion under small excitation is discussed. The concept of high-order adiabatic invariant is presented, and the form of exact invariants and adiabatic invariants as well as the conditions for their existence are given. Then the corresponding inverse problem is studied.

  1. Perturbation to Lie Symmetry and Generalized Hojman Adiabatic Invariants for Relativistic Hamilton System

    WANG Yu-Sheng; ZHANG Xiao-Ni; YUAN Bao-He; FANG Jian-Hui; YANG Guo-Hong; LIN Peng; PANG Ting

    2008-01-01

    Based on the concept of higher-order adiabatic invariants of mechanical system with action of a small perturbation, the perturbation to Lie symmetry and generalized Hojman adiabatic invariants for the relativistic Hamilton system are studied. Perturbation to Lie symmetry is discussed under general infinitesimal transformation of groups in which time is variable. The form and the criterion of generalized Hojman adiabatic invariants for this system are obtained. Finally, an example is given to illustrate the results.

  2. Lie symmetries, perturbation to symmetries and adiabatic invariants of Poincaré equation

    Chen Xiang-Wei; Liu Cui-Mei; Li Yan-Min

    2006-01-01

    Based on the invariance of differential equations under infinitesimal transformations,Lie symmetry,laws of conservations,perturbation to the symmetries and adiabatic invariants of Poincaré equations are presented.The concepts of Lie symmetry and higher order adiabatic invariants of Poincaré equations are proposed.The conditions for existence of the exact invariants and adiabatic invariants are proved,and their forms are also given.In addition,an example is presented to illustrate these results.

  3. Perturbation to Lie Symmetry and Adiabatic Invariants for General Holonomic Mechanical Systems

    DING Ning; FANG Jian-Hui; WANG Peng; ZHANG Xiao-Ni

    2007-01-01

    Based on the concept of adiabatic invariant, the perturbation to the Lie symmetry and adiabatic invariants for general holonomic mechanical systems are studied. The exact invariants induced directly from the Lie symmetry of the system without perturbation are given. The perturbation to the Lie symmetry is discussed and the adiabatic invariants that have the different form from that in [Act. Phys. Sin. 55 (2006) 3236 (in Chinese)] of the perturbed system, are obtained.

  4. Exact invariants and adiabatic invariants of dynamical system of relative motion

    Chen Xiang-Wei; Wang Xin-Min; Wang Ming-Quan

    2004-01-01

    Based on the theory of symmetries and conserved quantities, the exact inwriants and adiabatic inwriants of a dynamical system of relative motion are studied. The perturbation to symmetries for the dynamical system of relative motion under small excitation is discussed. The concept of high-order adiabatic invariant is presented, and the form of exact invariants and adiabatic invariants as well as the conditions for their existence are given. Then the corresponding inverse problem is studied.

  5. Indications of the Implementation in the Process of Educational Reform in Uruguay Indicadores de la implementación en procesos de reforma educativa en Uruguay

    Marcos R. Sarasola

    2000-01-01

    Full Text Available In this paper the author investigates, from a qualitative perspective, the problems associated with implementing educational innovations. He studies the recent case of the Basic Cycle reform in Uruguay. Based on the concepts of van der Vegt and Vandenberghe (1992, he analyzes the "functions guides" exercised by the director in order to be able to regulate the internal flow of the implementation. The first of these is "conceptual clarity", which has to do with providing the professors with a clear vision of what will take place within the implementation, and with specifying that vision in terms of the professional knowledge and abilities of the faculty as well. The second of these is "directional pressure," which refers to an operational level of the implementation; that is to say, how daily activities mesh with the objectives of the reform. Next, "function of support" refers to the support offered by the director for the management of resources (material, emotional, technical, and administrative resources, so that the resources may then effectively support the work in the center. Finally is "definition of latitude," that is, the degree of educational autonomy that the faculty have with respect to the external objectives of the reform. En este trabajo el autor estudia, desde una perspectiva cualitativa, la problemática de la implementación de innovaciones educativas. Toma por caso la reciente reforma del Ciclo Básico en Uruguay. Con base en los conceptos de van der Vegt y Vandenberghe (1992, analiza las "funciones guía" ejercidas por el director para poder regular el flujo interno de la implementación. La primera de ellas es la "claridad conceptual", que tiene que ver con las posibilidades de proveer a los profesores de una clara visión de lo que ha de lograrse con la implementación y con concretar esa visión en términos de saber profesional y habilidades de los docentes. La segunda es la "presión direccional" que refiere a un nivel

  6. Fast adiabatic quantum state transfer and entanglement generation between two atoms via dressed states

    Wu, Jin-Lei; Ji, Xin; Zhang, Shou

    2017-01-01

    We propose a dressed-state scheme to achieve shortcuts to adiabaticity in atom-cavity quantum electrodynamics for speeding up adiabatic two-atom quantum state transfer and maximum entanglement generation. Compared with stimulated Raman adiabatic passage, the dressed-state scheme greatly shortens the operation time in a non-adiabatic way. By means of some numerical simulations, we determine the parameters which can guarantee the feasibility and efficiency both in theory and experiment. Besides, numerical simulations also show the scheme is robust against the variations in the parameters, atomic spontaneous emissions and the photon leakages from the cavity.

  7. Adiabatic invariants of generalized Lutzky type for disturbed holonomic nonconservative systems

    Luo Shao-Kai; Cai Jian-Le; Jia Li-Qun

    2008-01-01

    Based on the definition of higher-order adiabatic invariants of a mechanical system,a new type of adiabatic invariants,i.e.generalized Lutzky adiabatic invariants,of a disturbed holonomic nonconservative mechanical system are obtained by investigating the perturbation of Lie symmetries for a holonomic nonconservative mechanical system with the action of small disturbance.The adiabatic invaxiants and the exact invariants of the Lutzky type of some special cases,for example,the Lie point symmetrical transformations,the special Lie symmetrical transformations,and the Lagrange system,are given.And an example is given to illustrate the application of the method and results.

  8. A new type of adiabatic invariants for nonconservative systems of generalized classical mechanics

    Zhang Yi

    2006-01-01

    The perturbations to symmetries and adiabatic invariants for nonconservative systems of generalized classical mechanics are studied. The exact invariant in the form of Hojman from a particular Lie symmetry for an undisturbed system of generalized mechanics is given. Based on the concept of high-order adiabatic invariant in generalized mechanics, the perturbation to Lie symmetry for the system under the action of small disturbance is investigated, and a new adiabatic invariant for the nonconservative system of generalized classical mechanics is obtained, which can be called the Hojman adiabatic invariant. An example is also given to illustrate the application of the results.

  9. Rorty the Reformer?

    Harvey Cormier

    2008-12-01

    Full Text Available Rorty should be read as a reformer, rather than a revolutionary transformer. While the reformer aims to improve what is already good, the revolutionary transformer seeks to dispense with the merely good in a quest for the absolutely best. For Rorty this choice was a bad choice. In order to make the case that Rorty was a reformer,we explicate Rorty’s views on truth. These views argue that we can obtain consensus about what is worth preserving and improving without reference to either rightness, truth, or objectivity. For after all, there is no way for philosophers to get outside the circle of language within which we debate about what we take to be authoritative and aceptable.

  10. First Exploration on Curriculum Reform of Informatization Teaching Process of Health Jurisprudence%《卫生法学》课程信息化教学过程改革初探

    李艳霞

    2013-01-01

    There are many defects in traditional teaching process of Health Jurisprudence, and information-ization is the inevitable result of reforming traditional health law study with the social development. Curriculum reform of informatization teaching process of Health Jurisprudence should embody the following aspects: making teaching preparations by course preparation, configuration and training of teachers, students entrance education, etc.; organizing and implementing teaching by students' autonomous learning, teachers' guidance to students' learning, simulative court teaching, intensive practice teaching, etc.;and evaluating by teaching assessment and e-valuation in the end.%传统《卫生法学》课程教学过程存在诸多缺陷,信息化是卫生改革顺应时代发展对传统卫生法律研究进行变革的必然结果,《卫生法学》课程信息化教学过程改革应从课程授课准备、教师的配置与培训、学生入学教育等方面予以教学准备,从学生自主学习和教师、学生的导学、助学以及模拟法庭教学、集中实践教学等方面组织教学实施,最后以教学考核与评价予以考量。

  11. The 0.1K bolometers cooled by adiabatic demagnetization

    Roellig, T.; Lesyna, L.; Kittel, P.; Werner, M.

    1983-01-01

    The most straightforward way of reducing the noise equivalent power of bolometers is to lower their operating temperature. We have been exploring the possibility of using conventionally constructed bolometers at ultra-low temperatures to achieve NEP's suitable to the background environment of cooled space telescopes. We have chosen the technique of adiabatic demagnetization of a paramagnetic salt as a gravity independent, compact, and low power way to achieve temperatures below pumped He-3 (0.3 K). The demagnetization cryostat we used was capable of reaching temperatures below 0.08 K using Chromium Potassium Alum as a salt from a starting temperature of 1.5 K and a starting magnetic field of 30,000 gauss. Computer control of the magnetic field decay allowed a temperature of 0.2 K to be maintained to within 0.5 mK over a time period exceeding 14 hours. The refrigerator duty cycle was over 90 percent at this temperature. The success of these tests has motivated us to construct a more compact portable adiabatic demagnetization cryostat capable of bolometer optical tests and use at the 5m Hale telescope at 1mm wavelengths.

  12. General background conditions for K-bounce and adiabaticity

    Romano, Antonio Enea

    2016-01-01

    We study the background conditions for a bounce in a single scalar field model with a generalized kinetic term $K(X)$. At the background level we impose the existence of two turning points where the derivative of the Hubble parameter $H$ changes sign and of a bounce point where the Hubble parameter vanishes. We find the conditions for $K(X)$ and the potential which ensure the above requirements. We then give the examples of two models constructed according to these conditions. One is based on a quadratic $K$, and the other on a $K$ which is avoiding divergences of the second time derivative of the scalar field, which may otherwise occur. An appropriate choice of the initial conditions can lead to a sequence of consecutive bounces. In models where the bounce occurs when the potential is not constant, large non adiabatic perturbations are produced, which can in turn source the growth of anisotropies. In the region where these models have a constant potential they became adiabatic on any scale and because of thi...

  13. Breakdown of the adiabatic Born-Oppenheimer approximation in graphene

    Pisana, Simone; Lazzeri, Michele; Casiraghi, Cinzia; Novoselov, Kostya S.; Geim, A. K.; Ferrari, Andrea C.; Mauri, Francesco

    2007-03-01

    The adiabatic Born-Oppenheimer approximation (ABO) has been the standard ansatz to describe the interaction between electrons and nuclei since the early days of quantum mechanics. ABO assumes that the lighter electrons adjust adiabatically to the motion of the heavier nuclei, remaining at any time in their instantaneous ground state. ABO is well justified when the energy gap between ground and excited electronic states is larger than the energy scale of the nuclear motion. In metals, the gap is zero and phenomena beyond ABO (such as phonon-mediated superconductivity or phonon-induced renormalization of the electronic properties) occur. The use of ABO to describe lattice motion in metals is, therefore, questionable. In spite of this, ABO has proved effective for the accurate determination of chemical reactions, molecular dynamics and phonon frequencies in a wide range of metallic systems. Here, we show that ABO fails in graphene. Graphene, recently discovered in the free state, is a zero-bandgap semiconductor that becomes a metal if the Fermi energy is tuned applying a gate voltage, Vg. This induces a stiffening of the Raman G peak that cannot be described within ABO.

  14. Adiabatic Compression of Compact Tori for Current Drive and Heating

    Woodruff, Simon; McNab, Angus; Miller, Kenneth; Ziemba, Tim

    2008-11-01

    Several critical issues stand in the development path for compact tori. An important one is the production of strong magnetic fields, (or large flux amplifications) by use of a low current source. The Pulsed Build-up Experiment is a Phase II SBIR project in which we aim to show a new means for generating strong magnetic fields from a low current source, namely, the repetitive injection of helicity-bearing plasma that also undergoes an acceleration and compression. In the Phase I SBIR, advanced computations were benchmarked against analytic theory and run to determine the best means for the acceleration and compression of a compact torus plasma. The study included detailed simulations of magnetic reconnection. In Phase II, an experiment has been designed and is being built to produce strong magnetic fields in a spheromak by the repetitive injection of magnetic helicity from a low current coaxial plasma source. The plasma will be accelerated and compressed in a similar manner to a traveling wave adiabatic compression scheme that was previously applied to a mirror plasma [1]. [1] P. M. Bellan Scalings for a Traveling Mirror Adiabatic Magnetic Compressor Rev. Sci. Instrum. 53(8) 1214 (1982) Work supported by DOE Grant No. DE-FG02-06ER84449.

  15. Romanian Public Servants on Public Administration Reforms

    Sorin Dan ȘANDOR

    2008-06-01

    Full Text Available The present paper tries to assess the public administration reforms based on the opinions of public servants – the ones in charge with the actual implementation of the reforms. In November 2007 a mail survey was done in Romanian PA institutions. The opinions showed the necessity of the administrative reforms is accepted mainly as a request of the European Union. The way in which reforms were done is seen as a strenuous process, characterized by low coherence, with many changes of focus and done mainly through enacting new legislation over and over, which led to over-regulation. De-centralization (financial and managerial has still a long way to go, legislative improvement also (especially streamlining rules and procedures, citizens/community is not seen as a real partnership. More optimistic answers are regarding the functioning of local institutions (especially along the organizational culture dimension, which are seen as functioning very well in the context of reforms (a cautionary note should be made – loyalty or subjectivity may have lead to such answers.

  16. The agrarian reform, between memory and forgetfulness

    Ingrid Hall

    2013-12-01

    Full Text Available Although the Peruvian Agrarian Reform has been a mayor event for the peasant communities of Peru, especially in the Andes, it is barely evoked. It is the case of the community of Llanchu, located in the region of Cusco y in the Province of Calca, even if it has born thanks to the reform. In this paper we will analyse the way people refers to the agrarian reform. We will show that discourses about the past are socially controlled as any other kind of speech in that society. We will also discuss the way this past is engraved in the society and its territory. The ancient categories former to the reform are then still in use today even if they are expressed in new words. We will finally discuss the fact that the forgetfulness of the reform makes this community appear like a long-date one. The main question raised here is “what is supposed to be a peasant community today in the Peruvian Andes?” Is that so important to show a social unity and a historical continuity? This point is especially crucial today, as those populations entered in a process of ethnicization.

  17. Lunar Organic Waste Reformer Project

    National Aeronautics and Space Administration — The Lunar Organic Waste Reformer (LOWR) utilizes high temperature steam reformation to convert all plastic, paper, and human waste materials into useful gases. In...

  18. On the Reform of Russian Education

    Mironov, V. V.

    2013-01-01

    The "modernization" of Russian education is linked to the functioning of the entire social system of Russia, and reforms are proving difficult and contradictory. The use of the Unified State Examination in Russia, plus participation in the Bologna process, is causing concern about the ability of education to meet the needs of the…

  19. Reforming the Paradigm of American Education.

    Leonard, B. Charles; Messner, Phillip E.

    1991-01-01

    The current crisis of U.S. public education cannot be addressed through reforms to the existing paradigm. In fact, the current paradigm is being challenged and shifted bringing in a new perception of the educational process. Because of resistance in the education profession, that change may be variously applied. (JB)

  20. Reforming Systems: Realizing the Fourth Way

    Harris, Alma

    2011-01-01

    This article outlines how the work of Andy Hargreaves has significantly and substantially informed our understanding of educational change, particularly systemwide change, by drawing upon his most recent research and writing to consider what is known about the process of successful, large-scale reform. It focuses on some of the "fallacies of…

  1. Political Transformations and Higher Education Reforms

    Kozma, Tamas

    2008-01-01

    The Bologna process is a comprehensive concept for European higher education reforms of the 20th and 21st centuries. However, it means something else in Central European countries than it does in the rest of Europe. It has been combined in Central Europe with a major social change referred to as the "political transformation" (Johnson…

  2. GLOBALIZATION, NEOLIBERALISM, EDUCATIONAL REFORMS AND CREATIVITY

    Octavio González-Vázquez

    2015-07-01

    Full Text Available Globalization and neoliberalism strongly affect education reforms in our country. Changes involving the three processes have conditions that can promote or inhibit the development of creativity. We can use one or the other with the development of our own creativity.

  3. Policy and Workforce Reform in England

    Gunter, Helen M.

    2008-01-01

    Current workforce reform, known as Remodelling the School Workforce, is part of an enduring policy process where there have been tensions between public and private sector structures and cultures. I show that the New Right and New Labour governments who have built and configured site based performance management over the past quarter of a century…

  4. Stepping Forward In Political Reform

    2011-01-01

    It seems that the bulk of foreign media reports about China’s reforms have limited their focus to changes in China’s economic setup with little mention paid to its political reform.Actually,since China carried out the reform and opening-up policy in 1978,it has not only made fundamental changes to its economic system but also implemented a series of important reforms to its political institutions

  5. Stepping Forward In Political Reform

    LAI HAIRONG

    2011-01-01

    It seems that the bulk of foreign media reports about China's reforms have limited their focus to changes in China's economic setup with little mention paid to its political reform.Actually,since China carried out the reform and opening-up policy in 1978,it has not only made fundamental changes to its economic system but also implemented a series of important reforms to its political institutions.

  6. Globalization, Citizenship and Educational Reform

    Qi, Jie

    2009-01-01

    This paper explores the notions of globalization as embodied in Japanese educational reforms during the 1980s and 1990s. Modern institutional discourses of educational reform in Japan have shifted over time and all of these reform movements have been constructed by particular social and historical trajectories. Generally speaking, it has been…

  7. The road half traveled: agricultural market reform in Sub-Saharan Africa

    Kherallah Mylène

    2002-11-01

    Full Text Available This article reviews the extensive evidence on agricultural market reforms in Sub-Saharan Africa and summarises the impact reforms have had on market performance, agricultural production, use of modern inputs, and poverty. It offers eight recommendations for completing the reform process and developing a new agenda for agricultural markets in Sub-Saharan Africa. The reform experience in Sub-Saharan Africa has varied widely across countries and crop subsectors. The available evidence shows clear progress in some areas and mixed results in others. Most reforms were only partially implemented and policy reversal was common. Once implemented, however, reforms have increased competition and reduced marketing margins, benefiting both producers and consumers. Reforms have also boosted export crop production. On the other hand, food crop production has stagnated and yields have not improved. Further expansion of private trade is constrained by lack of access to credit, uncertainty about the government’s commitment to reform, and high transaction costs.

  8. Quantum state specific reactant preparation in a molecular beam by rapid adiabatic passage

    Chadwick, Helen, E-mail: helen.chadwick@epfl.ch; Hundt, P. Morten; Reijzen, Maarten E. van; Yoder, Bruce L.; Beck, Rainer D. [Laboratoire de Chimie Physique Moléculaire, Ecole Polytechnique Fédérale de Lausanne, Lausanne (Switzerland)

    2014-01-21

    Highly efficient preparation of molecules in a specific rovibrationally excited state for gas/surface reactivity measurements is achieved in a molecular beam using tunable infrared (IR) radiation from a single mode continuous wave optical parametric oscillator (cw-OPO). We demonstrate that with appropriate focusing of the IR radiation, molecules in the molecular beam crossing the fixed frequency IR field experience a Doppler tuning that can be adjusted to achieve complete population inversion of a two-level system by rapid adiabatic passage (RAP). A room temperature pyroelectric detector is used to monitor the excited fraction in the molecular beam and the population inversion is detected and quantified using IR bleaching by a second IR-OPO. The second OPO is also used for complete population transfer to an overtone or combination vibration via double resonance excitation using two spatially separated RAP processes.

  9. Simulation of Quasi-Adiabatic Beam Capture into Acceleration at the Nuclotron

    Volkov, V I; Issinsky, I B; Kovalenko, A D

    2003-01-01

    The routine RF system being used at the Nuclotron allows one to inject the beam at ramping magnetic field with following acceleration at constant amplitude of accelerating voltage. At these conditions at least a half of the particles circulating in the vacuum chamber after injection is not captured in longitudinal acceptance. At the same time vacuum chamber sizes permit to extend the momentum spread of the beam enough to make gymnastic with it inside the stable zone of longitudinal phase space on the flat magnetic field at injection. A quasi-adiabatic capture was considered for increasing the Nuclotron beam intensity. Simulation of such a kind of process with subsequent acceleration was performed. It was shown that in this case it is possible to capture and accelerate up to 100 % of the injected beam.

  10. Energy conservation by means of adiabatic cooling and humidification; Energiebesparing door adiabatisch koelen en bevochtigen

    Leffers, B. [Stulz Groep, Amstelveen (Netherlands)

    2012-10-01

    Water (R718) as refrigerant is a natural alternative to cooling processes that work with the so-called classic refrigerants. It offers an environment-friendly cooling method with a strikingly low energy use, thus significantly reducing the direct and indirect CO2 emission. Cooling systems that use adiabatic refrigerants may constitute an appealing alternative under certain circumstances [Dutch] Water (R718) als koudemiddel is een natuurlijk alternatief voor koelprocessen die werken met de zogenaamde klassieke koudemiddelen. De toepassing hiervan is een milieuvriendelijke manier van koelen met een opvallend laag energiegebruik waardoor de directe en ook de indirecte CO2-emissie aanzienlijk wordt gereduceerd. Koelsystemen die gebruik maken van adiabatische koelers zijn onder bepaalde omstandigheden een aantrekkelijk alternatief.

  11. A maximum-entropy approach to the adiabatic freezing of a supercooled liquid.

    Prestipino, Santi

    2013-04-28

    I employ the van der Waals theory of Baus and co-workers to analyze the fast, adiabatic decay of a supercooled liquid in a closed vessel with which the solidification process usually starts. By imposing a further constraint on either the system volume or pressure, I use the maximum-entropy method to quantify the fraction of liquid that is transformed into solid as a function of undercooling and of the amount of a foreign gas that could possibly be also present in the test tube. Upon looking at the implications of thermal and mechanical insulation for the energy cost of forming a solid droplet within the liquid, I identify one situation where the onset of solidification inevitably occurs near the wall in contact with the bath.

  12. Adiabatic Ekpyrosis: Scale-Invariant Curvature Perturbations from a Single Scalar Field in a Contracting Universe

    Khoury, Justin

    2009-01-01

    The universe can be made flat and smooth by undergoing a phase of ultra-slow (ekpyrotic) contraction with equation of state w >> 1, a condition that is achievable with a single, canonical scalar field and conventional general relativity. It has been argued, though, that another goal, generating scale-invariant density perturbations, requires at least two scalar fields and a two-step process that first produces entropy fluctuations and then converts them to curvature perturbations. In this paper, we exploit a loophole in the argument and introduce an ekpyrotic model based on a single, canonical scalar field that utilizes a purely "adiabatic mechanism" to generate nearly scale-invariant curvature fluctuations. The curvature perturbation tends to a constant at long wavelengths, indicating that the background evolution is a dynamical attractor. The resulting spectrum is slightly red with distinctive non-gaussian fluctuations.

  13. 死刑变革中的生命尊严考量%Reflections on Life Dignity in the Process of Death Penalty Reformation

    韩跃红; 杨勇

    2015-01-01

    基于生命尊严所蕴含的绝对性和神圣不可侵犯性,死刑废除论的思想得以兴起和发展。世界上死刑趋于减少和执行方式趋于人道,折射出生命价值地位的上升和生命尊严观念与现代文明之间的契合。本世纪初兴起于中国大地的死刑存废之争是一次现代化的思想洗礼,尽管争论的结果是我国尚不具备废除死刑的条件,但争论本身以及此后采取的限制死刑、改革死刑执行方式的做法,使我国民众受到一次生命尊严理念的深刻教育。%Based on the absoluteness and sanctity of life dignity,the dispute over the existence and abolish-ment of death penalty has sprung up.The death penalty around the world tends to decrease and its executive way turned humane,reflecting the nobler position of life value and the integration of human dignity and modern civilization.The dispute over the existence and the abolishment of death penalty in China was a thought baptism in the 21st century.Though it is unlikely to abolish death penalty completely in China at the present time,this dispute will finally become a useful education experience about life dignity for the people in the restriction and reformation of death penalty.

  14. Second Law Analysis of Adiabatic and Non-Adiabatic Pipeline Flows of Unstable and Surfactant-Stabilized Emulsions

    Rajinder Pal

    2016-03-01

    Full Text Available Entropy generation, and hence exergy destruction, in adiabatic flow of unstable and surfactant-stabilized emulsions was investigated experimentally in different diameter pipes. Four types of emulsion systems are investigated covering a broad range of the dispersed-phase concentration: (a unstable oil-in-water (O/W emulsions without surfactant; (b surfactant-stabilized O/W emulsions; (c unstable water-in-oil (W/O emulsions without surfactant; and (d surfactant-stabilized W/O emulsions. The entropy generation rate per unit pipe length is affected by the type of the emulsion as well as its stability. Unstable emulsions without any surfactant present at the interface generate less entropy in the turbulent regime as compared with the surfactant-stabilized emulsions of the same viscosity and density. The effect of surfactant is particularly severe in the case of W/O emulsions. In the turbulent regime, the rate of entropy generation in unstable W/O emulsions is much lower in comparison with that observed in the stable W/O emulsions. A significant delay in the transition from laminar to turbulent regime is also observed in the case of unstable W/O emulsion. Finally, the analysis and simulation results are presented on non-adiabatic pipeline flow of emulsions.

  15. Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles

    Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

    1992-08-01

    The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R&D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

  16. Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles

    Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

    1992-08-01

    The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

  17. Non-adiabatic Excited State Molecule Dynamics Modeling of Photochemistry and Photophysics of Materials

    Nelson, Tammie Renee [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Tretiak, Sergei [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-01-06

    Understanding and controlling excited state dynamics lies at the heart of all our efforts to design photoactive materials with desired functionality. This tailor-design approach has become the standard for many technological applications (e.g., solar energy harvesting) including the design of organic conjugated electronic materials with applications in photovoltaic and light-emitting devices. Over the years, our team has developed efficient LANL-based codes to model the relevant photophysical processes following photoexcitation (spatial energy transfer, excitation localization/delocalization, and/or charge separation). The developed approach allows the non-radiative relaxation to be followed on up to ~10 ps timescales for large realistic molecules (hundreds of atoms in size) in the realistic solvent dielectric environment. The Collective Electronic Oscillator (CEO) code is used to compute electronic excited states, and the Non-adiabatic Excited State Molecular Dynamics (NA-ESMD) code is used to follow the non-adiabatic dynamics on multiple coupled Born-Oppenheimer potential energy surfaces. Our preliminary NA-ESMD simulations have revealed key photoinduced mechanisms controlling competing interactions and relaxation pathways in complex materials, including organic conjugated polymer materials, and have provided a detailed understanding of photochemical products and intermediates and the internal conversion process during the initiation of energetic materials. This project will be using LANL-based CEO and NA-ESMD codes to model nonradiative relaxation in organic and energetic materials. The NA-ESMD and CEO codes belong to a class of electronic structure/quantum chemistry codes that require large memory, “long-queue-few-core” distribution of resources in order to make useful progress. The NA-ESMD simulations are trivially parallelizable requiring ~300 processors for up to one week runtime to reach a meaningful restart point.

  18. The buzz on reform.

    Bouchard, E A

    1994-01-01

    Mr. Bouchard bravely travels through the maze of lingo and anagrams spawned by recent attempts at healthcare reform. This comprehensive list of terminology and definitions, which provides considerable detail and analysis, will be invaluable to anyone trying to understand current trends.

  19. China Launched VAT Reform

    Li Zhen

    2009-01-01

    @@ In order to boost domestic demand,reduce the tax burden on companies,encourage technological upgrades and push for industrial restructuring,China decided to extend its value-added tax(VAT) reform to all industries nationwide beginning January 1,2009.

  20. Educational Reforms in Yugoslavia

    Kintzer, Frederick C.

    1978-01-01

    Yugoslavia's educational system had to be completely rebuilt after World War II to ensure the nation's full and rapid competition in the postwar world. The reforms are discussed in light of the political, social, and economic structure of Yugoslavia. (Author/LBH)