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Sample records for activated carbon filter

  1. Ozone Removal by Filters Containing Activated Carbon: A Pilot Study

    Energy Technology Data Exchange (ETDEWEB)

    Fisk, William; Spears, Mike; Sullivan, Douglas; Mendell, Mark

    2009-09-01

    This study evaluated the ozone removal performance of moderate-cost particle filters containing activated carbon when installed in a commercial building heating, ventilating, and air conditioning (HVAC) system. Filters containing 300 g of activated carbon per 0.09 m2 of filter face area were installed in two 'experimental' filter banks within an office building located in Sacramento, CA. The ozone removal performance of the filters was assessed through periodic measurements of ozone concentrations in the air upstream and downstream of the filters. Ozone concentrations were also measured upstream and downstream of a 'reference' filter bank containing filters without any activated carbon. The filter banks with prefilters containing activated carbon were removing 60percent to 70percent of the ozone 67 and 81 days after filter installation. In contrast, there was negligible ozone removal by the reference filter bank without activated carbon.

  2. Sensory pollution from bag-type fiberglass ventilation filters: Conventional filter compared with filters containing various amounts of activated carbon

    DEFF Research Database (Denmark)

    Bekö, Gabriel; Fadeyi, M.O.; Clausen, Geo

    2009-01-01

    (100 g/m(2)). Each filter was weighed at the beginning of the soiling period and after 3 and 6 months of service. Additionally, up- and down-stream ozone concentrations and filter pressure drops were measured monthly. Following 6 months of service, the air downstream of each of the combination filters......As ventilation filters accumulate particles removed from the airstream, they become emitters of sensory pollutants that degrade indoor air quality. Previously we demonstrated that an F7 bag-type filter that incorporates activated carbon (a "combination filter") reduces this adverse effect compared...... to an equivalent filter without carbon. The aim of the present study was to examine how the amount of activated carbon (AC) used in combination filters affects their ability to remove both sensory offending pollutants and ozone. A panel evaluated the air downstream of four different filters after each had...

  3. Effect of a biological activated carbon filter on particle counts

    Institute of Scientific and Technical Information of China (English)

    Su-hua WU; Bing-zhi DONG; Tie-jun QIAO; Jin-song ZHANG

    2008-01-01

    Due to the importance of biological safety in drinking water quality and the disadvantages which exist in traditional methods of detecting typical microorganisms such as Cryptosporidium and Giardia,it is necessary to develop an alternative.Particle counts is a qualitative measurement of the amount of dissolved solids in water.The removal rate of particle counts was previously used as an indicator of the effectiveness of a biological activated carbon(BAC)filter in removing Cryptosporidium and Giardia.The particle counts in a BAC filter effluent over one operational period and the effects of BAC filter construction and operational parameters were investigated with a 10 m3/h pilot plant.The results indicated that the maximum particle count in backwash remnant water was as high as 1296 count/ml and it needed about 1.5 h to reduce from the maximum to less than 50 count/ml.During the standard filtration period,particle counts stay constant at less than 50 count/ml for 5 d except when influ-enced by sand filter backwash remnant water.The removal rates of particle counts in the BAC filter are related to characteristics of the carbon.For example,a columned carbon and a sand bed removed 33.3% and 8.5% of particles,respectively,while the particle counts in effluent from a cracked BAC filter was higher than that of the influent.There is no significant difference among particle removal rates with different filtration rates.High post-ozone dosage(>2 mg/L)plays an important role in particle count removal;when the dosage was 3 mg/L,the removal rates by carbon layers and sand beds decreased by 17.5% and increased by 9.5%,respectively,compared with a 2 mg/L dosage.

  4. Active carbon filter health condition detection with piezoelectric wafer active sensors

    Science.gov (United States)

    Bao, Jingjing; Giurgiutiu, Victor; Rubel, Glenn O.; Peterson, Gregory W.; Ball, Thomas M.

    2011-04-01

    The impregnated active carbon used in air purification systems degrades over time due to exposure to contamination and mechanical effects (packing, settling, flow channeling, etc.). A novel approach is proposed to detect contamination in active carbon filters by combining the electromechanical impedance spectroscopy (EMIS) and electrochemical impedance spectroscopy (ECIS). ECIS is currently being used to evaluate active carbon filtration material; however, it cannot differentiate the impedance changes due to chemical contamination from those due to mechanical changes. EMIS can detect impedance changes due to mechanical changes. For the research work presented in this paper, Piezoelectric wafer active sensor (PWAS) was used for the EMIS method. Some remarkable new phenomena were unveiled in the detection of carbon filter status. 1. PWAS EMIS can detect the presence of contaminants, such as water and kerosene in the carbon bed 2. PWAS EMIS can monitor changes in mechanical pressure that may be associated with carbon bed packing, settling and flow channeling 3. EMIS and ECIS measurements are consistent with each other and complimentary A tentative simplified impedance model was created to simulate the PWAS-carbon bed system under increasing pressure. Similar impedance change pattern was observed when comparing the simulation results with experimental data.

  5. Preparation of creating active carbon from cigarette filter waste using microwave-induced KOH activation

    Science.gov (United States)

    Hamzah, Yanuar; Umar, Lazuardi

    2017-05-01

    For the first time, cigarette filter waste, which is an environmental hazardous material, is used as basic material prepared for creating activated carbon (AC) via KOH chemical activation using a microwave input power of 630 W and irradiation time of 20 minutes. Active carbon was characterized by TGA, x-ray diffraction, scanning electron microscopy, energy dispersive x-ray, nitrogen adsorption-desorption, and absorption of methylene blue (MB). The results of x-ray diffraction showed that active carbon has a semi-crystalline structure with peaks of 2θ of 22.87° and 43.70°. Active carbon microstructure analysis showed that the layer height (Lc ) is inversely proportional to the width of the layer (La ), and the distance between the two layers is d002 and d100 , which depends significantly on the ratio of AC: KOH. It was found that the optimum BET surface area and adsorption capacity for MB were 328.13 m2 / g and 88.76 m2 / g, respectively. The results revealed the potential to prepare activated carbon from cigarette filter waste using microwave irradiation.

  6. Physicochemical and sensory changes in aged sugarcane spirit submitted to filtering with activated carbon filter

    Directory of Open Access Journals (Sweden)

    Felipe Cimino Duarte

    2012-09-01

    Full Text Available Sugarcane spirit is a drink considered as a national symbol of Brazil. It is produced by large producers and by about 30 thousand small and medium home-distilling producers dispersed throughout the country. The copper originating from the home-distillers can become a serious problem since at high concentrations in beverages it may cause serious human health problems. Therefore, the objective of this study was to investigate the influence of the activated carbon used in commercial filters on the physicochemical and sensory characteristics of aged sugarcane spirit. Analyses of copper, dry extract, alcoholic degree, higher alcohols, volatile acids, aldehydes, esters, furfural, and methanol were performed. The sensory evaluation was performed by seven selected trained judges, who analyzed the yellow color, woody aroma and flavor, and intensity of alcoholic aroma and flavor of the cane spirit before and after the filtration process. The sensory tests were carried out using a 9 cm non-structured intensity scale. A reduction was observed in all compounds analyzed physicochemically, except for the esters, which increased after filtration. This increase is probably due to the esterification of the alcohols and acids present. According to the sensory results obtained, a reduction was observed in the intensity of the yellow color, aroma, and wood flavor characteristics, the major characteristics of the aging process.

  7. Development and evaluation of antimicrobial activated carbon fiber filters using Sophora flavescens nanoparticles.

    Science.gov (United States)

    Sim, Kyoung Mi; Kim, Kyung Hwan; Hwang, Gi Byoung; Seo, SungChul; Bae, Gwi-Nam; Jung, Jae Hee

    2014-09-15

    Activated carbon fiber (ACF) filters have a wide range of applications, including air purification, dehumidification, and water purification, due to their large specific surface area, high adsorption capacity and rate, and specific surface reactivity. However, when airborne microorganisms such as bacteria and fungi adhere to the carbon substrate, ACF filters can become a source of microbial contamination, and their filter efficacy declines. Antimicrobial treatments are a promising means of preventing ACF bio-contamination. In this study, we demonstrate the use of Sophora flavescens in antimicrobial nanoparticles coated onto ACF filters. The particles were prepared using an aerosol process consisting of nebulization-thermal drying and particle deposition. The extract from S. flavescens is an effective, natural antimicrobial agent that exhibits antibacterial activity against various pathogens. The efficiency of Staphylococcus epidermidis inactivation increased with the concentration of S. flavescens nanoparticles in the ACF filter coating. The gas adsorption efficiency of the coated antimicrobial ACF filters was also evaluated using toluene. The toluene-removal capacity of the ACF filters remained unchanged while the antimicrobial activity was over 90% for some nanoparticle concentrations. Our results provide a scientific basis for controlling both bioaerosol and gaseous pollutants using antimicrobial ACF filters coated with S. flavescens nanoparticles.

  8. Removal of Toluene at Low Concentration with Activated Carbon Filter : Adsorption Analysis using Tenax Tube and TD-GCMSD

    OpenAIRE

    Shan, Chi-En

    2016-01-01

    Various studies have demonstrated the usefulness of adsorption of activated carbon on VOCs removal. Large porosity and high adsorption allows activated carbon to remove very small particles. This project was commissioned by the company name Genano Oy to test the activated carbon filter in their air purifier and hence to provide a database for the company. The purpose of this thesis was to study the effectiveness of impregnated activated carbon filter on toluene removal. Experiment was co...

  9. Effects of ozonation and temperature on the biodegradation of natural organic matter in biological granular activated carbon filters

    NARCIS (Netherlands)

    Van der Aa, L.T.J.; Rietveld, L.C.; Van Dijk, J.C.

    2011-01-01

    Four pilot (biological) granular activated carbon ((B)GAC) filters were operated to quantify the effects of ozonation and water temperature on the biodegradation of natural organic matter (NOM) in (B)GAC filters. The removal of dissolved organic carbon (DOC), assimilable organic carbon (AOC) and

  10. Effects of ozonation and temperature on biodegradation of natural organic matter in biological granular activated carbon filters

    NARCIS (Netherlands)

    Van der Aa, L.T.J.; Rietveld, L.C.; Van Dijk, J.C.

    2010-01-01

    Four pilot (biological) granular activated carbon ((B)GAC) filters were operated to quantify the effects of ozonation and water temperature on the biodegradation of natural organic matter (NOM) in (B)GAC filters. Removal of dissolved organic carbon (DOC), assimilable organic carbon (AOC) and oxygen

  11. Integrating powdered activated carbon into wastewater tertiary filter for micro-pollutant removal.

    Science.gov (United States)

    Hu, Jingyi; Aarts, Annelies; Shang, Ran; Heijman, Bas; Rietveld, Luuk

    2016-07-15

    Integrating powdered activated carbon (PAC) into wastewater tertiary treatment is a promising technology to reduce organic micro-pollutant (OMP) discharge into the receiving waters. To take advantage of the existing tertiary filter, PAC was pre-embedded inside the filter bed acting as a fixed-bed adsorber. The pre-embedding (i.e. immobilization) of PAC was realized by direct dosing a PAC solution on the filter top, which was then promoted to penetrate into the filter media by a down-flow of tap water. In order to examine the effectiveness of this PAC pre-embedded filter towards OMP removal, batch adsorption tests, representing PAC contact reactor (with the same PAC mass-to-treated water volume ratio as in the PAC pre-embedded filter) were performed as references. Moreover, as a conventional dosing option, PAC was dosed continuously with the filter influent (i.e. the wastewater secondary effluent with the investigated OMPs). Comparative results confirmed a higher OMP removal efficiency associated with the PAC pre-embedded filter, as compared to the batch system with a practical PAC residence time. Furthermore, over a filtration period of 10 h (approximating a realistic filtration cycle for tertiary filters), the continuous dosing approach resulted in less OMP removal. Therefore, it was concluded that the pre-embedding approach can be preferentially considered when integrating PAC into the wastewater tertiary treatment for OMP elimination. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Characterization of activated carbon fiber filters for pressure drop, submicrometer particulate collection, and mercury capture.

    Science.gov (United States)

    Hayashi, T; Lee, T G; Hazelwood, M; Hedrick, E; Biswas, P

    2000-06-01

    The use of activated carbon fiber (ACF) filters for the capture of particulate matter and elemental Hg is demonstrated. The pressure drop and particle collection efficiency characteristics of the ACF filters were established at two different face velocities and for two different aerosols: spherical NaCl and combustion-generated silica particles. The clean ACF filter specific resistance was 153 kg m-2 sec-1. The experimental specific resistance for cake filtration was 1.6 x 10(6) sec-1 and 2.4 x 10(5) sec-1 for 0.5- and 1.5-micron mass median diameter particles, respectively. The resistance factor R was approximately 2, similar to that for the high-efficiency particulate air filters. There was a discrepancy in the measured particle collection efficiencies and those predicted by theory. The use of the ACF filter for elemental Hg capture was illustrated, and the breakthrough characteristic was established. The capacity of the ACF filter for Hg capture was similar to other powdered activated carbons.

  13. Indoor Air Contaminant Adsorption By Palm Shell Activated Carbon Filter – A Proposed Study

    Directory of Open Access Journals (Sweden)

    Leman A.M

    2016-01-01

    Full Text Available Indoor air contaminant is a public issue. High Volatile Organic Compound (VOC, Carbon monoxide (CO, Carbon dioxide (CO2, and particulate matter is becoming main issue that needs to solve. Therefore, this study focus on improving indoor air quality by using activated carbon (AC for Ventilation and Air-Conditioning (VAC. It investigated because AC is widely explored but developing AC as a filter for VAC is not developed yet. The AC prepared by physical and chemical activation process and combination both of process and it was activated by H3PO4 and NaOH. Characterization and analysis process are consists of water content, ash content, bulk density, adsorption capacity, iodine number and indoor air filtering analysis. Treated activated carbon potential in achieving higher surface area of the structure to the range of 950 to 1150 m2/g for gas phase application. The higher surface area will adsorb more air pollution. Maintained properties of activated carbon such as hardness, density, pore, extractable ash, particle size (12 by 40 mesh and pH are becoming the main concern in achieving high quality of activated carbon.

  14. Impacts of backwashing on granular activated carbon filters for advanced wastewater treatment.

    Science.gov (United States)

    Frank, Joshua; Ruhl, Aki Sebastian; Jekel, Martin

    2015-12-15

    The use of granular activated carbon (GAC) in fixed bed filters is a promising option for the removal of organic micropollutants (OMP) from wastewater treatment plant effluents. Frequent backwashing of the filter bed is inevitable, but its effect on potential filter stratification is not well understood yet and thus has been evaluated in the present study for two commercial GAC products. Backwashing of GAC filters was simulated with 10 or 100 filter bed expansions of 20 or 100% at backwash velocities of 12 and 40 m/h, respectively. Five vertical fractions were extracted and revealed a vertical stratification according to grain sizes and material densities. Sieve analyses indicated increasing grain sizes towards the bottom for one GAC while grain sizes of the other GAC were more homogeneously distributed throughout the filter bed. The apparent densities of the top sections were significantly lower than that of the bottom sections of both products. Comparative long term fixed bed adsorption experiments with the top and bottom sections of the stratified GAC showed remarkable differences in breakthrough curves of dissolved organic carbon, UV light absorption at 254 nm wavelength (UVA254) and OMP. GAC from the upper section showed constantly better removal efficiencies than GAC from the bottom section, especially for weakly adsorbing OMP such as sulfamethoxazole. Furthermore correlations between UVA254 reductions and OMP removals were found.

  15. Seasonal changes in the invertebrate community of granular activated carbon filters and control technologies.

    Science.gov (United States)

    Wang, Qing; You, Wei; Li, Xiaowei; Yang, Yufeng; Liu, Lijun

    2014-03-15

    Invertebrate colonization of granular activated carbon (GAC) filters in the waterworks is one of the most frequently occurring and least studied biological problems of water processing in China. A survey of invertebrate colonization of GAC filters was carried out weekly from October 2010 to December 2011 at a reservoir water treatment works in South China. Twenty-six kinds of invertebrates were observed. The abundance was as high as 5600ind.m(-3) with a mean of 860ind.m(-3). Large variations in abundance were observed among different seasons and before and after GAC filtration. The dominant organisms were rotifers and copepods. The average invertebrate abundance in the filtrate was 12-18.7 times of that in the pre-filtered water. Results showed that the GAC filters were colonized by invertebrates which may lead to a higher output of organisms in the filtrate than in the pre-filtered water. The invertebrate abundance in the GAC filters was statistically correlated with the water temperature. Seasonal patterns were observed. The invertebrate abundance grew faster in the spring and summer. Copepods were dominant in the summer while rotifers dominated in all other seasons of the year. There was a transition of small invertebrates (rotifers) gradually being substituted by larger invertebrates (copepods) from spring to summer. Control measures such as backwashing with chloric water, drying filter beds and soaking with saliferous water were implemented in the waterworks to reduce invertebrate abundances in the GAC filters. The results showed that soaking with saliferous water (99%, reduction in percent) was best but drying the filter beds (84%) was more economical. Soaking filter beds with 20g/L saliferous water for one day can be implemented in case of emergency. In order to keep invertebrate abundance in the acceptable range, some of these measures should be adopted.

  16. Evaluation and Certification of Ambersorb 4652 for use in Activated Carbon Ion Exchange Filters for the International Space Station

    Science.gov (United States)

    Adam, Niklas; Cox, Trey; Larner, Katherine; Carter, Donald; Kouba, Coy

    2017-01-01

    In order to reduce the infiltration of dimethylsilanediol (DMSD) and other organosilicon containing species through the Multifiltration Beds (MF Beds), an alternate activated carbon was found to replace the obsolete Barnabey Cheney 580-26 activated carbon. The carbon that removed the most organosilicon compounds in testing1 was a synthetic activated carbon named Schunk 4652 which later became Ambersorb 4652. Since activated carbon has a large capacity for iodine (I2), and is used in the Activated Carbon Ion Exchange (ACTEX) filters on the International Space Station (ISS), testing was performed on the Ambersorb 4652 carbon to determine the effectiveness of the material for use in ACTEX filters to remove iodine. This work summarizes the testing and the certification of Ambersorb 4652 for use in the ACTEX filters for the ISS.

  17. Simulation of mercury capture by activated carbon injection in incinerator flue gas. 2. Fabric filter removal.

    Science.gov (United States)

    Scala, F

    2001-11-01

    Following a companion paper focused on the in-duct mercury capture in incinerator flue gas by powdered activated carbon injection, this paper is concerned with the additional mercury capture on the fabric filter cake, relevant to baghouse equipped facilities. A detailed model is presented for this process, based on material balances on mercury in both gaseous and adsorbed phases along the growing filter cake and inside the activated carbon particles,taking into account mass transfer resistances and adsorption kinetics. Several sorbents of practical interest have been considered, whose parameters have been evaluated from available literature data. The values and range of the operating variables have been chosen in order to simulate typical incinerators operating conditions. Results of simulations indicate that, contrary to the in-duct removal process, high mercury removal efficiencies can be obtained with moderate sorbent consumption, as a consequence of the effective gas/sorbent contacting on the filter. Satisfactory utilization of the sorbents is predicted, especially at long filtration times. The sorbent feed rate can be minimized by using a reactive sorbent and by lowering the filter temperature as much as possible. Minor benefits can be obtained also by decreasing the sorbent particle size and by increasing the cleaning cycle time of the baghouse compartments. Reverse-flow baghouses were more efficient than pulse-jet baghouses, while smoother operation can be obtained by increasing the number of baghouse compartments. Model results are compared with available relevant full scale data.

  18. Development of biomass in a drinking water granular active carbon (GAC) filter.

    Science.gov (United States)

    Velten, Silvana; Boller, Markus; Köster, Oliver; Helbing, Jakob; Weilenmann, Hans-Ulrich; Hammes, Frederik

    2011-12-01

    Indigenous bacteria are essential for the performance of drinking water biofilters, yet this biological component remains poorly characterized. In the present study we followed biofilm formation and development in a granular activated carbon (GAC) filter on pilot-scale during the first six months of operation. GAC particles were sampled from four different depths (10, 45, 80 and 115 cm) and attached biomass was measured with adenosine tri-phosphate (ATP) analysis. The attached biomass accumulated rapidly on the GAC particles throughout all levels in the filter during the first 90 days of operation and maintained a steady state afterward. Vertical gradients of biomass density and growth rates were observed during start-up and also in steady state. During steady state, biomass concentrations ranged between 0.8-1.83 x 10(-6) g ATP/g GAC in the filter, and 22% of the influent dissolved organic carbon (DOC) was removed. Concomitant biomass production was about 1.8 × 10(12) cells/m(2)h, which represents a yield of 1.26 × 10(6) cells/μg. The bacteria assimilated only about 3% of the removed carbon as biomass. At one point during the operational period, a natural 5-fold increase in the influent phytoplankton concentration occurred. As a result, influent assimilable organic carbon concentrations increased and suspended bacteria in the filter effluent increased 3-fold as the direct consequence of increased growth in the biofilter. This study shows that the combination of different analytical methods allows detailed quantification of the microbiological activity in drinking water biofilters.

  19. Anaerobic activated carbon filter for the treatment of phenol-bearing wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Khan, K.A. (Georgia Inst. of Technology, Atlanta, GA); Suidan, M.T.; Cross, W.H.

    1981-10-01

    An experiment using an activated carbon filter for the treatment of phenol-bearing wasterwater from coal gasification processes is discussed. Two granular-activated-carbon-packed anaerobic filter systems were constructed for use in the study. Both phenol and glucose of phenol-fed reactor systems were operated under continuous feeding for a period of 735 days. The glucose-fed reactor was very effective in reducing the organic content of the feed substrate. The performance of the phenol-fed reactor was tested at three different phenol concentration levels: (1) 200 mg/l; (2) 400 mg/l; and (3) 1000 mg/l. Using the 200 mg/l concentration of phenol an average 79% of the feed chemical oxygen demand (COD) was accounted for in the aqueous and gaseous phases of the final effluent. Using 400 mg/l the COD accounted for the aqueous and gaseous phases of the effluent rose to an average of 92%, and using 1000 mg/l, the COD removal efficiencies from the three columns fell to an average of 90%, respectively. Despite the differences in removal efficiencies between the different phases of the experiment, the granular-activated-carbon-packed anaerobic bioreactor proved to be an effective process in the reduction of phenol from a synthetically prepared wastewater. In addition to phenol reduction, there was also a consistent and effective reduction of the chemical oxygen demand and the total organic carbon content of the waste at a time when a methane-rich gaseous by-product was being produced simultaneously.

  20. Simplified greywater treatment systems: Slow filters of sand and slate waste followed by granular activated carbon.

    Science.gov (United States)

    Zipf, Mariah Siebert; Pinheiro, Ivone Gohr; Conegero, Mariana Garcia

    2016-07-01

    One of the main actions of sustainability that is applicable to residential, commercial, and public buildings is the rational use of water that contemplates the reuse of greywater as one of the main options for reducing the consumption of drinking water. Therefore, this research aimed to study the efficiencies of simplified treatments for greywater reuse using slow sand and slow slate waste filtration, both followed by granular activated carbon filters. The system monitoring was conducted over 28 weeks, using analyses of the following parameters: pH, turbidity, apparent color, biochemical oxygen demand (BOD), chemical oxygen demand (COD), surfactants, total coliforms, and thermotolerant coliforms. The system was run at two different filtration rates: 6 and 2 m(3)/m(2)/day. Statistical analyses showed no significant differences in the majority of the results when filtration rate changed from 6 to 2 m(3)/m(2)/day. The average removal efficiencies with regard to the turbidity, apparent color, COD and BOD were 61, 54, 56, and 56%, respectively, for the sand filter, and 66, 61, 60, and 51%, respectively, for the slate waste filter. Both systems showed good efficiencies in removing surfactants, around 70%, while the pH reached values of around 7.80. The average removal efficiencies of the total and thermotolerant coliforms were of 61 and 90%, respectively, for the sand filter, and 67 and 80%, respectively, for the slate waste filter. The statistical analysis found no significant differences between the responses of the two systems, which attest to the fact that the slate waste can be a substitute for sand. The maximum levels of efficiency were high, indicating the potential of the systems, and suggesting their optimization in order to achieve much higher average efficiencies.

  1. Benefit-cost analysis of commercially available activated carbon filters for indoor ozone removal in single-family homes.

    Science.gov (United States)

    Aldred, J R; Darling, E; Morrison, G; Siegel, J; Corsi, R L

    2016-06-01

    This study involved the development of a model for evaluating the potential costs and benefits of ozone control by activated carbon filtration in single-family homes. The modeling effort included the prediction of indoor ozone with and without activated carbon filtration in the HVAC system. As one application, the model was used to predict benefit-to-cost ratios for single-family homes in 12 American cities in five different climate zones. Health benefits were evaluated using disability-adjusted life-years and included city-specific age demographics for each simulation. Costs of commercially available activated carbon filters included capital cost differences when compared to conventional HVAC filters of similar particle removal efficiency, energy penalties due to additional pressure drop, and regional utility rates. The average indoor ozone removal effectiveness ranged from 4 to 20% across the 12 target cities and was largely limited by HVAC system operation time. For the parameters selected in this study, the mean predicted benefit-to-cost ratios for 1-inch filters were >1.0 in 10 of the 12 cities. The benefits of residential activated carbon filters were greatest in cities with high seasonal ozone and HVAC usage, suggesting the importance of targeting such conditions for activated carbon filter applications.

  2. Conversion of sand filters into activated carbon filters at the La Presa (Valencia) water works; Conversion de filtros de arena porcarbon activo en la ETAP de La Presa (Valencia)

    Energy Technology Data Exchange (ETDEWEB)

    Macian Cervera, V. J.; Monforte Monleon, L.; Ribera Orts, R.; Suris Jorda, J. I.; Klee, J. M.

    2007-07-01

    To improve the water quality at potable water treatment plant of La P esa (Valencia), the sand filters have been replaced for activated carbon filters. In the following review the results and conclusions of the direct sand filter conversion into activated carbon filters will be presented. The leads to a simple and fast solution to odour and taste removal, as well as dissolved organic matter, without investments in works at the water works. (Author)

  3. Carbon nanotube filters

    Science.gov (United States)

    Srivastava, A.; Srivastava, O. N.; Talapatra, S.; Vajtai, R.; Ajayan, P. M.

    2004-09-01

    Over the past decade of nanotube research, a variety of organized nanotube architectures have been fabricated using chemical vapour deposition. The idea of using nanotube structures in separation technology has been proposed, but building macroscopic structures that have controlled geometric shapes, density and dimensions for specific applications still remains a challenge. Here we report the fabrication of freestanding monolithic uniform macroscopic hollow cylinders having radially aligned carbon nanotube walls, with diameters and lengths up to several centimetres. These cylindrical membranes are used as filters to demonstrate their utility in two important settings: the elimination of multiple components of heavy hydrocarbons from petroleum-a crucial step in post-distillation of crude oil-with a single-step filtering process, and the filtration of bacterial contaminants such as Escherichia coli or the nanometre-sized poliovirus (~25 nm) from water. These macro filters can be cleaned for repeated filtration through ultrasonication and autoclaving. The exceptional thermal and mechanical stability of nanotubes, and the high surface area, ease and cost-effective fabrication of the nanotube membranes may allow them to compete with ceramic- and polymer-based separation membranes used commercially.

  4. Effect of biostimulation on biodegradation of dissolved organic carbon in biological granular activated carbon filters

    Directory of Open Access Journals (Sweden)

    K. Tihomirova

    2012-03-01

    Full Text Available The addition of labile organic carbon (LOC to enhance the biodegradation rate of dissolved organic carbon (DOC in biological columns was studied. Acetate standard solution (NaAc and LB (Luria Bertrani medium were used as LOC as biostimulants in glass column system used for measurements of biodegradable dissolved organic carbon (BDOC. The addition of LOC related with the increase of total DOC in sample. The concentration of BDOC increased up to 7 and 5 times and was utilized after 24 min. contact time. The biodegradation rate constant was increased at least 8 times during adaptation-biostimulation period. There was a strong positive correlation between the biodegradation rate constant and the concentration of BDOC. Biostimulation period ranged from 24 to 53 h for NaAc biostimulant and from 20 to 168 h for LB. The study has shown that LOC could be used as stimulator to enhance the biodegradation rate of DOC during biofiltration.

  5. Ammonium removal of drinking water at low temperature by activated carbon filter biologically enhanced with heterotrophic nitrifying bacteria.

    Science.gov (United States)

    Qin, Wen; Li, Wei-Guang; Zhang, Duo-Ying; Huang, Xiao-Fei; Song, Yang

    2016-03-01

    We sought to confirm whether use of Acinetobacter strains Y7 and Y16, both strains of heterotrophic nitrifying bacteria, was practical for removing ammonium (NH4 (+)-N) from drinking water at low temperatures. To test this, ammonium-containing drinking water was treated with strains Y7 and Y16 at 8 and 2 °C. Continuous ammonium treatment was conducted in order to evaluate the performance of three biologically enhanced activated carbon (BEAC) filters in removing ammonium. The three BEAC filters were inoculated with strain Y7, strain Y16, and a mixture of strains Y7 and Y16, respectively. A granular activated carbon (GAC) filter, without inoculation by any strains, was tested in parallel with the BEAC filters as control. The results indicated that NH4 (+)-N removal was significant when a BEAC filter was inoculated with the mixture of strains Y7 and Y16 (BEAC-III filter). Amounts of 0.44 ± 0.05 and 0.25 ± 0.05 mg L(-1) NH4 (+)-N were removed using the BEAC-III filter at 8 and 2 °C, respectively. These values were 2.8-4.0-fold higher than the values of ammonium removal acquired using the GAC filter. The synergistic effect of using strains Y7 and Y16 in concert was the cause of the high-ammonium removal efficiency achieved by using the BEAC-III filter at low temperatures. In addition, a high C/N ratio may promote NH4 (+)-N removal efficiency by improving biomass and microbial activity. This study provides new insight into the use of biofilters to achieve biological removal of ammonium at low temperature.

  6. Monte Carlo simulations of ripple filters designed for proton and carbon ion beams in hadrontherapy with active scanning technique

    Energy Technology Data Exchange (ETDEWEB)

    Bourhaleb, F; Givehchi, N; Iliescu, S; Rosa, A La; Pecka, A; Peroni, C [Dipartimento di Fisica Sperimentale, Universita' di Torino, Via P. Giuria 1, Torino 10125 (Italy); Attili, A; Cirio, R; Marchetto, F; Donetti, M; Garella, M A; Giordanengo, S; Pardo, J [INFN, Sezione di Torino, Via P. Giuria 1, Torino 10125 (Italy); Cirrone, P [INFN, Laboratori Nazionali del Sud, Via S.Sofia 62, Catania 95125 (Italy)], E-mail: bourhaleb@to.infn.it

    2008-02-01

    Proton and carbon ion beams have a very sharp Bragg peak. For proton beams of energies smaller than 100 MeV, fitting with a gaussian the region of the maximum of the Bragg peak, the sigma along the beam direction is smaller than 1 mm, while for carbon ion beams, the sigma derived with the same technique is smaller than 1 mm for energies up to 360 MeV. In order to use low energy proton and carbon ion beams in hadrontherapy and to achieve an acceptable homogeneity of the spread out Bragg peak (SOBP) either the peak positions along the beam have to be quite close to each other or the longitudinal peak shape needs to be broaden at least few millimeters by means of a properly designed ripple filter. With a synchrotron accelerator in conjunction with active scanning techniques the use of a ripple filter is necessary to reduce the numbers of energy switches necessary to obtain a smooth SOBP, leading also to shorter overall irradiation times. We studied the impact of the design of the ripple filter on the dose uniformity in the SOBP region by means of Monte Carlo simulations, implemented using the package Geant4. We simulated the beam delivery line supporting both proton and carbon ion beams using different energies of the beams. We compared the effect of different kind of ripple filters and their advantages.

  7. Reduction of Carbon Dioxide in Filtering Facepiece Respirators with an Active-Venting System: A Computational Study

    OpenAIRE

    2015-01-01

    During expiration, the carbon dioxide (CO2) levels inside the dead space of a filtering facepiece respirator (FFR) increase significantly above the ambient concentration. To reduce the CO2 concentration inside the dead space, we attach an active lightweight venting system (AVS) comprising a one-way valve, a blower and a battery in a housing to a FFR. The achieved reduction is quantified with a computational-fluid-dynamics model that considers conservation of mass, momentum and the dilute spec...

  8. Controlling of crustacean zooplankton reproduction in biological activated carbon (BAC) filters by strengthen operation and management of conventional process

    Institute of Scientific and Technical Information of China (English)

    LIU Li-jun; ZHANG Jin-song; LI Xiao-wei; HE Jun-guo

    2010-01-01

    To counter the mass reproduction and penetration of crustacean zooplankton in Biological Activated Carbon (BAC) filters which may result in the presence of organisms in potable water and water pollution,this paper analyzed the factors affecting organisms' reproduction in BAC filters.A comparative study was performed on the density and composition of crustacean zooplankton of the concerned water treatment units of two advanced water plants (Plant A and B) which with the same raw water and the same treatment technique in southern China.The results obtained show that the crustaceans' density and composition was very different between the sand filtered water of Plant A and Plant B.which Harpacticoida bred sharply in the sediment tanks and penetrated sand filter into BAC falters was the primary reason of crustaceans reproduce in BAC filters of Plant A.For prevention of the organisms reproduction in BAC,some strengthen measures was taken including pre-chlorination,cleaning coagulation tanks and sediment tanks completely,increasing sludge disposal frequency to stop organisms enter BAC filters,and the finished water quality was improved and enhanced.

  9. Retention of titanium dioxide nanoparticles in biological activated carbon filters for drinking water and the impact on ammonia reduction.

    Science.gov (United States)

    Liu, Zhiyuan; Yu, Shuili; Park, Heedeung; Liu, Guicai; Yuan, Qingbin

    2016-06-01

    Given the increasing discoveries related to the eco-toxicity of titanium dioxide (TiO2) nanoparticles (NPs) in different ecosystems and with respect to public health, it is important to understand their potential effects in drinking water treatment (DWT). The effects of TiO2 NPs on ammonia reduction, ammonia-oxidizing archaea (AOA) and ammonia-oxidizing bacteria (AOB) in biological activated carbon (BAC) filters for drinking water were investigated in static and dynamic states. In the static state, both the nitrification potential and AOB were significantly inhibited by 100 μg L(-1) TiO2 NPs after 12 h (p  0.05). In the dynamic state, different amounts of TiO2 NP pulses were injected into three pilot-scale BAC filters. The decay of TiO2 NPs in the BAC filters was very slow. Both titanium quantification and scanning electron microscope analysis confirmed the retention of TiO2 NPs in the BAC filters after 134 days of operation. Furthermore, the TiO2 NP pulses considerably reduced the performance of ammonia reduction. This study identified the retention of TiO2 NPs in BAC filters and the negative effect on the ammonia reduction, suggesting a potential threat to DWT by TiO2 NPs.

  10. Low powdered activated carbon concentrations to improve MBR sludge filterability at high salinity and low temperature

    NARCIS (Netherlands)

    Remy, M.J.J.; Temmink, B.G.; Brink, van den P.; Rulkens, W.H.

    2011-01-01

    Previous research has demonstrated that powdered activated carbon (PAC), when applied at very low dosages and long SRTs, reduces membrane fouling in membrane bioreactor (MBRs). This effect was related to stronger flocs which are less sensitive to shear. Low temperature and high salt concentration ar

  11. Enhancement of nuclease P1 production by Penicillium citrinum YL104 immobilized on activated carbon filter sponge.

    Science.gov (United States)

    Zhao, Nan; Ren, Hengfei; Li, Zhenjian; Zhao, Ting; Shi, Xinchi; Cheng, Hao; Zhuang, Wei; Chen, Yong; Ying, Hanjie

    2015-02-01

    The efficiency of current methods for industrial production of the enzyme nuclease P1 is limited. In this study, we sought to improve fermentation methods for the production of nuclease P1. An immobilized fermentation system using an activated carbon filter sponge as a carrier was used for the production of nuclease P1. In an airlift internal loop reactor (ALR), the fermentation performance of three different fermentation modes, including free-cell fermentation, repeated-batch fermentation, and semi-continuous immobilized fermentation, were compared. The fermentation kinetics in the fermentation broth of the three fermentation modes, including dissolved oxygen (DO), pH value, cell concentration, residual sugar concentration, and enzyme activity, were tested. The productivity of semi-continuous immobilized fermentation reached 8.76 U/mL/h, which was 33.3 and 80.2% higher than that of repeated-batch fermentation and free-cell fermentation, respectively. The sugar consumption of free-cell, repeated-batch, and semi-continuous immobilized fermentations was 41.2, 30.8, and 25.9 g/L, respectively. These results showed that immobilized-cell fermentation by using Penicillium citrinum with activated carbon filter sponge in an ALR was advantageous for nuclease P1 production, especially in the semi-continuous immobilized fermentation mode. In spite of the significant improvement in nuclease P1 production in semi-continuous immobilized fermentation mode, the specific activity of nuclease P1 was almost equal among the three fermentation modes.

  12. UV/TiO2 photocatalytic disinfection of carbon-bacteria complexes in activated carbon-filtered water: Laboratory and pilot-scale investigation.

    Science.gov (United States)

    Zhao, Jin Hui; Chen, Wei; Zhao, Yaqian; Liu, Cuiyun; Liu, Ranbin

    2015-01-01

    The occurrence of carbon-bacteria complexes in activated carbon filtered water has posed a public health problem regarding the biological safety of drinking water. The application of combined process of ultraviolet radiation and nanostructure titanium dioxide (UV/TiO2) photocatalysis for the disinfection of carbon-bacteria complexes were assessed in this study. Results showed that a 1.07 Lg disinfection rate can be achieved using a UV dose of 20 mJ cm(-2), while the optimal UV intensity was 0.01 mW cm(-2). Particle sizes ≥8 μm decreased the disinfection efficiency, whereas variation in particle number in activated carbon-filtered water did not significantly affect the disinfection efficiency. Photoreactivation ratio was reduced from 12.07% to 1.69% when the UV dose was increased from 5 mJ cm(-2) to 20 mJ cm(-2). Laboratory and on-site pilot-scale experiments have demonstrated that UV/TiO2 photocatalytic disinfection technology is capable of controlling the risk posed by carbon-bacteria complexes and securing drinking water safety.

  13. Impact of titanium dioxide nanoparticles on the bacterial communities of biological activated carbon filter intended for drinking water treatment.

    Science.gov (United States)

    Zhiyuan, Liu; Shuili, Yu; Heedeung, Park; Qingbin, Yuan; Guicai, Liu; Qi, Li

    2016-08-01

    Titanium dioxide nanoparticles (TiO2 NPs) are inevitably present in the aquatic environment owing to their increasing production and use. However, knowledge of the potential effects of TiO2 NPs on the treatment of drinking water is scarce. Herein, the effects of two types of anatase TiO2 NPs (TP1, 25 nm; TP2, 100 nm) on the bacterial community in a biological activated carbon (BAC) filter were investigated via quantitative polymerase chain reaction (Q-PCR) analysis, ATP quantification, and 454 pyrosequencing analysis. Both TP1 and TP2 significantly inhibited the bacterial ATP level (p < 0.01) and induced a decrease in the abundance of bacterial 16S rDNA gene copies at doses of 0.1 and 100 mg L(-1). Simultaneously, the diversity and evenness of the bacterial communities were considerably reduced. The relative abundances of bacteria annotated to OTUs from Nitrospira class and Betaproteobacteria class decreased upon TiO2 NP treatment, whereas those of Bacilli class and Gammaproteobacteria class increased. TiO2 NP size showed a greater effect on the bacterial composition than did the dose based on Bray-Curtis distances. These findings identified negative effects of TiO2 NPs on the bacterial community in the BAC filter. Given the fact that BAC filters are used widely in drinking water treatment plants, these results suggested a potential threat by TiO2 NP to drinking water treatment system.

  14. PWAS EMIS-ECIS Active Carbon Filter Residual Life Estimation Methodology

    Science.gov (United States)

    2013-09-23

    can detect the presence of contaminants, such as water and kerosene in the carbon bed 5. EMIS and ECIS measurements are consistent with each other...1. Flow rate F 2. Start time t0 Run carbon bed exhaust through H2O2 solution with methyl red indicator Record: The time when the indicator

  15. Combination of ozonation, activated carbon, and biological aerated filter for advanced treatment of dyeing wastewater for reuse.

    Science.gov (United States)

    Zou, Xiao-Ling

    2015-06-01

    Laboratorial scale experiments were performed to investigate and evaluate the performance and removal characteristics of organics, color, and genotoxicity by an integrated process including ozonation, activated carbon (AC), and biological aerated filter (BAF) for recycling biotreated dyeing wastewater (BTDW) collected from a cotton textile factory. Influent chemical oxygen demand (COD) in the range of 156 - 252 mg/L, 5-day biochemical oxygen demand (BOD5) of 13.5 - 21.7 mg/L, and color of 58 - 76° were observed during the 20-day continuous operation. Outflows with average COD of 43 mg/L, BOD5 of 6.6 mg/L, and color of 5.6° were obtained after being decontaminated by the hybrid system with ozone dosage of 0.25 mg O3applied/mg COD0, 40 min ozonation contact time, 30 min hydraulic retention time (HRT) for AC treatment, and 2.5 h HRT for BAF treatment. More than 82 % of the genotoxicity of BTDW was eliminated in the ozonation unit. The genotoxicity of the BAF effluent was less than 1.33 μg 4-nitroquinoline-N-oxide/L. Ozonation could change the organics molecular structures, destroy chromophores, increase the biodegradability, and obviously reduce the genotoxicity of BTDW. Results showed that the combined process could guarantee water reuse with high quality.

  16. Reduction of Carbon Dioxide in Filtering Facepiece Respirators with an Active-Venting System: A Computational Study.

    Directory of Open Access Journals (Sweden)

    Erik Birgersson

    Full Text Available During expiration, the carbon dioxide (CO2 levels inside the dead space of a filtering facepiece respirator (FFR increase significantly above the ambient concentration. To reduce the CO2 concentration inside the dead space, we attach an active lightweight venting system (AVS comprising a one-way valve, a blower and a battery in a housing to a FFR. The achieved reduction is quantified with a computational-fluid-dynamics model that considers conservation of mass, momentum and the dilute species, CO2, inside the FFR with and without the AVS. The results suggest that the AVS can reduce the CO2 levels inside the dead space at the end of expiration to around 0.4% as compared to a standard FFR, for which the CO2 levels during expiration reach the same concentration as that of the expired alveolar air at around 5%. In particular, during inspiration, the average CO2 volume fraction drops to near-to ambient levels of around 0.08% with the AVS. Overall, the time-averaged CO2 volume fractions inside the dead space for the standard FFR and the one with AVS are around 3% and 0.3% respectively. Further, the ability of the AVS to vent the dead-space air in the form of a jet into the ambient - similar to the jets arising from natural expiration without a FFR - ensures that the expired air is removed and diluted more efficiently than a standard FFR.

  17. Reduction of Carbon Dioxide in Filtering Facepiece Respirators with an Active-Venting System: A Computational Study.

    Science.gov (United States)

    Birgersson, Erik; Tang, Ee Ho; Lee, Wei Liang Jerome; Sak, Kwok Jiang

    2015-01-01

    During expiration, the carbon dioxide (CO2) levels inside the dead space of a filtering facepiece respirator (FFR) increase significantly above the ambient concentration. To reduce the CO2 concentration inside the dead space, we attach an active lightweight venting system (AVS) comprising a one-way valve, a blower and a battery in a housing to a FFR. The achieved reduction is quantified with a computational-fluid-dynamics model that considers conservation of mass, momentum and the dilute species, CO2, inside the FFR with and without the AVS. The results suggest that the AVS can reduce the CO2 levels inside the dead space at the end of expiration to around 0.4% as compared to a standard FFR, for which the CO2 levels during expiration reach the same concentration as that of the expired alveolar air at around 5%. In particular, during inspiration, the average CO2 volume fraction drops to near-to ambient levels of around 0.08% with the AVS. Overall, the time-averaged CO2 volume fractions inside the dead space for the standard FFR and the one with AVS are around 3% and 0.3% respectively. Further, the ability of the AVS to vent the dead-space air in the form of a jet into the ambient - similar to the jets arising from natural expiration without a FFR - ensures that the expired air is removed and diluted more efficiently than a standard FFR.

  18. Carbon nanofibers grown on metallic filters as novel catalytic materials

    OpenAIRE

    Tribolet, Pascal; Kiwi-Minsker, Lioubov

    2005-01-01

    Carbon nanofibers (CNF) were synthesized on sintered metal fibers (SMF) filters of nickel and Ni-containing alloys (Inconel, stainless steel (SS)) by thermal chemical vapor deposition of ethane in the presence of hydrogen at not, vert, similar660 °C. The CNFs were formed directly over the SMF filters without deposition of metal particles. The catalytic active sites leading to the CNF formation were attained by oxidation–reduction of the SMF filter. The CNFs present platelet morphology as dete...

  19. Pilot Study on Carbon-sand Filter for Sedimentation Effluent

    Directory of Open Access Journals (Sweden)

    Zhang Shuo

    2015-01-01

    Full Text Available The development of dual function of integrating with activated carbon adsorption and quartz sand filtration in the carbon-sand filter can collaboratively remove organic matters and turbidity and also protect the bio-security, and the pilot test is carried out to optimize the process parameters. The pilot test results show that the thickness of the filter materials is preferably 1,300mm of the activated carbon, 500mm of uniform quartz sand; filtration rate can be 8-12m/h; filter cycle is 24-48h; when the water temperature is 21°C to 29°C, the biofilm formation period in the carbon-sand filter is 15 to 20 days; removal of the organic matters and nitrogen runs through the entire filter bed, and the nitrite is mainly oxidized on the upper side; when the operation is mature, the layer of filter materials can form the biofilm and zoogloea, with the dual function of micro-biological degradation and activated carbon adsorption.

  20. Transformation of Activated Carbon Filters for Ethylene Glycol%乙二醇活性炭过滤器的改造

    Institute of Scientific and Technical Information of China (English)

    文四名; 温凌云; 范玉涛; 韩福泉; 何宇颉; 李英雪; 翁乙友; 瞿强; 左萌萌

    2012-01-01

    通过分析乙二醇加注泵停泵原因,改变了乙二醇过滤的思路.在该思路下停用活性炭过滤器并将其改造为机械过滤器后,乙二醇过滤效果良好,加注泵停机率减少,大幅降低了员工维护劳动强度,保证了产品稳定生产.改造成功实现设备废旧利用,节约了生产成本,实现了效益最大化.%Through analyzing reasons to cause glycol injection pumps stop,ideas about filtering ethylene glycol was changed,activated carbon filters were abandoned,and they were transformed into mechanical filters.The operation results show that the mechanical filter has good filtration efficiency for ethylene glycol,the outage rate of pumps has been decreased,which significantly reduce the labor intensity of the production staff and ensure stable production.The transformation saves the production cost to achieve maximum benefit.

  1. DSP Control of Line Hybrid Active Filter

    DEFF Research Database (Denmark)

    Dan, Stan George; Benjamin, Doniga Daniel; Magureanu, R.;

    2005-01-01

    Active Power Filters have been intensively explored in the past decade. Hybrid active filters inherit the efficiency of passive filters and the improved performance of active filters, and thus constitute a viable improved approach for harmonic compensation. In this paper a parallel hybrid filter ...

  2. Influence of geometry calibration in the determination of gamma emitters in active carbon filters; Influencia de la geometria de calibracion en la determinacion de emisores gamma en filtros de carbon activo

    Energy Technology Data Exchange (ETDEWEB)

    Laurado Tarrago, M.; Tent Petrus, J.

    2013-07-01

    Testing laboratories participate in external quality controls. For these controls are useful it is necessary to eliminate factors that can introduce sources of variability in the results. A factor to consider in this paper as a source of variability is the calibration geometry chosen for the correct quantification of the activity concentrations. This work contains the results of the intercomparison exercise and from them analysed the effect of the geometry of calibration used in the quantification of activity concentrations present in the activated carbon filter. (Author)

  3. Elimination of micropollutants and transformation products from a wastewater treatment plant effluent through pilot scale ozonation followed by various activated carbon and biological filters.

    Science.gov (United States)

    Knopp, Gregor; Prasse, Carsten; Ternes, Thomas A; Cornel, Peter

    2016-09-01

    Conventional wastewater treatment plants are ineffective in removing a broad range of micropollutants, resulting in the release of these compounds into the aquatic environment, including natural drinking water resources. Ozonation is a suitable treatment process for micropollutant removal, although, currently, little is known about the formation, behavior, and removal of transformation products (TP) formed during ozonation. We investigated the elimination of 30 selected micropollutants (pharmaceuticals, X-ray contrast media, industrial chemicals, and TP) by biological treatment coupled with ozonation and, subsequently, in parallel with two biological filters (BF) or granular activated carbon (GAC) filters. The selected micropollutants were removed to very different extents during the conventional biological wastewater treatment process. Ozonation (specific ozone consumption: 0.87 ± 0.29 gO3 gDOC(-1), hydraulic retention time: 17 ± 3 min) eliminated a large number of the investigated micropollutants. Although 11 micropollutants could still be detected after ozonation, most of these were eliminated in subsequent GAC filtration at bed volumes (BV) of approximately 25,000 m(3) m(-3). In contrast, no additional removal of micropollutants was achieved in the BF. Ozonation of the analgesic tramadol led to the formation of tramadol-N-oxide that is effectively eliminated by GAC filters, but not by BF. For the antiviral drug acyclovir, the formation of carboxy-acyclovir was observed during activated sludge treatment, with an average concentration of 3.4 ± 1.4 μg L(-1) detected in effluent samples. Subsequent ozonation resulted in the complete elimination of carboxy-acyclovir and led to the formation of N-(4-carbamoyl-2-imino-5-oxo imidazolidin)-formamido-N-methoxyacetetic acid (COFA; average concentration: 2.6 ± 1.0 μg L(-1)). Neither the BF nor the GAC filters were able to remove COFA. These results highlight the importance of considering TP in the

  4. Shunt Active Filter in Damping Harmonics Propagation

    Directory of Open Access Journals (Sweden)

    BERBAOUI, B.

    2010-08-01

    Full Text Available This paper deals with a hybrid shunt active power filter applied on 500 kV HVDC, after a description of the causes and effects harmonic pollution which may damage equipments and interrupt electric power customers service; in this paper we present the deferent solutions of this problem among one has to study the two most recent types of filtering: passive and hybrid filter. The hybrid filter consists of active filter connected in shunt with passive filter. The hybrid shunt active filter proposed is based on three levels PWM inverter and characterized by detecting the harmonic current flowing into the passive filter and controlled by notch algorithm. This structure has been applied on a test HVDC power system, is presented as a technical solution makes it possible to eliminate the disadvantages from passive filtering, and also economic price of active filtering part. The simulation results justified the effectiveness of this type of filter face of the classic passive filter.

  5. Generation of soluble microbial products by bio-activated carbon filter during drinking water advanced treatment and its influence on spectral characteristics.

    Science.gov (United States)

    Shen, Hong; Chen, Xin; Zhang, Dong; Chen, Hong-Bin

    2016-11-01

    In order to improve our understanding of bio-activated carbon (BAC) filter, the water quality of influent and effluent treated with BAC in a drinking water treatment plant (DWTP) of Shanghai during 2015 was valued. Combining the results from UV254, SUVA254, dissolved organic carbon (DOC) and scanning electron microscopic (SEM), it is found that performance of BAC treatment will be affected by characteristics of activated carbon (AC), which is relevant to the type of activated carbon (including shape and operating time) in this study. Fluorescence excitation-emission matrix (FEEM) shows that the humification index (HIX) and index of recent autochthonous contribution (BIX) is a reliable indicator to descript the variation of dissolved organic matter (DOM) during BAC process. The pattern of variation in BIX and HIX implies that soluble microbial products (SMPs) are formed and humic-like substances are removed during BAC treatment, which is also confirmed by the change of peaks of FEEM in BAC effluent. Large, positive correlations between SUVA254 and disinfection by-products formation potential yield (DBPFP yield) demonstrate that UV-absorbing DOM is directly related to the generation of DBPs. Poor correlations of HIX with DBPFP suggest that non-humic substances with UV-absorbing properties play an important role in the generation of DBPs in water with low SUVA254. Finally, strong but negative correlations between BIX and DBPFP suggest that vigorous microbial metabolism of BAC results in a decrease in DBPFP. However, the DBPFP yield will be enhanced for the generation of SMPs by BAC, especially in summer. Copyright © 2016 Elsevier B.V. All rights reserved.

  6. Anaerobic acidogenic digestion of olive mill wastewaters in biofilm reactors packed with ceramic filters or granular activated carbon.

    Science.gov (United States)

    Bertin, Lorenzo; Lampis, Silvia; Todaro, Daniela; Scoma, Alberto; Vallini, Giovanni; Marchetti, Leonardo; Majone, Mauro; Fava, Fabio

    2010-08-01

    Four identically configured anaerobic packed bed biofilm reactors were developed and employed in the continuous acidogenic digestion of olive mill wastewaters to produce volatile fatty acids (VFAs), which can be exploited in the biotechnological production of polyhydroxyalkanoates. Ceramic porous cubes or granular activated carbon were used as biofilm supports. Aside packing material, the role of temperature and organic loading rate (OLR) on VFA production yield and mixture composition were also studied. The process was monitored through a chemical, microbiological and molecular biology integrated procedure. The highest wastewater acidification yield was achieved with the ceramic-based technology at 25 degrees C, with an inlet COD and an OLR of about 17 g/L and 13 g/L/day, respectively. Under these conditions, about the 66% of the influent COD (not including its VFA content) was converted into VFAs, whose final amount represented more than 82% of the influent COD. In particular, acetic, propionic and butyric acids were the main VFAs by composing the 55.7, 21.5 and 14.4%, respectively, of the whole VFA mixture. Importantly, the relative concentrations of acetate and propionate were affected by the OLR parameter. The nature of the packing material remarkable influenced the process performances, by greatly affecting the biofilm bacterial community structure. In particular, ceramic cubes favoured the immobilization of Firmicutes of the genera Bacillus, Paenibacillus and Clostridium, which were probably involved in the VFA producing process.

  7. Actively Pumped Faraday Optical Filter

    Science.gov (United States)

    1996-04-30

    Richard I. Billmers Vincent M. Contarino David M. Allocca Martin F. Squicciarini William J. Scharpf 5d. PROJECT NUMBER 5e. TASK NUMBER 5f...States Patent [i9] Billmers et al. iiiiiiifflimi iilliiiiiii US005513032A [ii] Patent Number: [45] Date of Patent: 5,513,032 Apr. 30, 1996...54] ACTIVELY PUMPED FARADAY OPTICAL FILTER [75] Inventors: Richard I. Billmers , Bensalem; Vincent M. Contarino, Warrington; David M

  8. Radiochemical Analyses of the Filter Cake, Granular Activated Carbon, and Treated Ground Water from the DTSC Stringfellow Superfund Site Pretreatment Plant

    Energy Technology Data Exchange (ETDEWEB)

    Esser, B K; McConachie, W; Fischer, R; Sutton, M; Szechenyi, S

    2005-09-16

    The Department of Toxic Substance Control (DTSC) requested that Lawrence Livermore National Laboratory (LLNL) evaluate the treatment process currently employed at the Department's Stringfellow Superfund Site Pretreatment Plant (PTP) site to determine if wastes originating from the site were properly managed with regards to their radioactivity. In order to evaluate the current management strategy, LLNL suggested that DTSC characterize the effluents from the waste treatment system for radionuclide content. A sampling plan was developed; samples were collected and analyzed for radioactive constituents. Following is brief summary of those results and what implications for waste characterization may be made. (1) The sampling and analysis provides strong evidence that the radionuclides present are Naturally Occurring Radioactive Material (NORM). (2) The greatest source of radioactivity in the samples was naturally occurring uranium. The sample results indicate that the uranium concentration in the filter cake is higher than the Granular Activated Carbon (GAC) samples. (11 -14 and 2-6 ppm respectively). (3) No radiologic background for geologic materials has been established for the Stringfellow site, and comprehensive testing of the process stream has not been conducted. Without site-specific testing of geologic materials and waste process streams, it is not possible to conclude if filter cake and spent GAC samples contain radioactivity concentrated above natural background levels, or if radionuclides are being concentrated by the waste treatment process. Recommendation: The regulation of Technologically Enhanced, Naturally Occurring Radioactive Materials (T-NORM) is complex. Since the results of this study do not conclusively demonstrate that natural radioactive materials have not been concentrated by the treatment process it is recommended that the DTSC consult with the Department of Health Services (DHS) Radiological Health Branch to determine if any further

  9. Ultrathin diamond-like carbon films deposited by filtered carbon vacuum arcs

    Energy Technology Data Exchange (ETDEWEB)

    Anders, Andre; Fong, Walton; Kulkarni, Ashok; Ryan, Francis W.; Bhatia, C. Singh

    2001-07-13

    Ultrathin (< 5 nm) hard carbon films are of great interest to the magnetic storage industry as the areal density approaches 100 Gbit/in{sup 2}. These films are used as overcoats to protect the magnetic layers on disk media and the active elements of the read-write slider. Tetrahedral amorphous carbon films can be produced by filtered cathodic arc deposition, but the films will only be accepted by the storage industry only if the ''macroparticle'' issue has been solved. Better plasma filters have been developed over recent years. Emphasis is put on the promising twist filter system - a compact, open structure that operates with pulsed arcs and high magnetic field. Based on corrosion tests it is shown that the macroparticle reduction by the twist filter is satisfactory for this demanding application, while plasma throughput is very high. Ultrathin hard carbon films have been synthesized using S-filter and twist filter systems. Film properties such as hardness, elastic modulus, wear, and corrosion resistance have been tested.

  10. Ultrathin diamond-like carbon films deposited by filtered carbon vacuum arcs

    Energy Technology Data Exchange (ETDEWEB)

    Anders, Andre; Fong, Walton; Kulkarni, Ashok; Ryan, Francis W.; Bhatia, C. Singh

    2001-07-13

    Ultrathin (< 5 nm) hard carbon films are of great interest to the magnetic storage industry as the areal density approaches 100 Gbit/in{sup 2}. These films are used as overcoats to protect the magnetic layers on disk media and the active elements of the read-write slider. Tetrahedral amorphous carbon films can be produced by filtered cathodic arc deposition, but the films will only be accepted by the storage industry only if the ''macroparticle'' issue has been solved. Better plasma filters have been developed over recent years. Emphasis is put on the promising twist filter system - a compact, open structure that operates with pulsed arcs and high magnetic field. Based on corrosion tests it is shown that the macroparticle reduction by the twist filter is satisfactory for this demanding application, while plasma throughput is very high. Ultrathin hard carbon films have been synthesized using S-filter and twist filter systems. Film properties such as hardness, elastic modulus, wear, and corrosion resistance have been tested.

  11. 双层填料中置生物活性炭滤池中试优化研究%THE PILOT STUDY ON THE OPTIMIZATION OF MID-SET BIOLOGICAL ACTIVATED CARBON FILTER WITH TWO-STAGE FILTER

    Institute of Scientific and Technical Information of China (English)

    李少文; 杨永飞; 陆少鸣

    2012-01-01

    The mid-set biological activated carbon filter with double filler loading was used to remove the turbidity and organic matter from water whose turbidity was about 1 NTU effluent from sedimentation tank. The results were as following. Filling the thickness of 3 m cylindrical carbon whose diameter was φ3 mm, the cushion thickness of 0.7 m was filled with diameter φ3 ~ 5 mm and thickness of 1.2 m with diameter φ6 ~ 8 mm lightweight ceramic. The experiment was operated at 12 m · h-1 filter speed while the gas-water volume ratio was 0.2:1, the average pressure loss were 3.41 kPa and 2.81 kPa, CODMn average removal rates were 41.5% and 46.3%; the latter was operated at the 16 m·h-1 filtration rate while the gas-water volume ratio was 0.2:1, the average pressure loss was 4.08 kPa, CODMn, average removal rate was 41.4%.%采用中置生物活性炭滤池,装填双层填料,对进水浊度约1 NTU左右的沉淀池出水进行去除浊度和有机物中试.结果表明,装填厚3m粒径φ3 mm柱状炭、垫层分别采用厚0.7m粒径φ3~5 mm与厚1.2m粒径φ6~8 mm轻质陶粒,于12 m·h-1滤速、气水体积比为0.2∶1的工况下运行时,平均水压损失分别为3.41 kPa和2.81 kPa,CODMn平均去除率分别为41.5%和46.3%;后者在16m.h-1滤速,气水体积比0.2∶1的工况下运行时,平均水压损失为4.08kPa,CODMn平均去除率为41.4%.

  12. Sensory Pollution from Bag Filters, Carbon Filters and Combinations

    DEFF Research Database (Denmark)

    Bekö, Gabriel; Clausen, Geo; Weschler, Charles J.

    2008-01-01

    Used ventilation filters are a major source of sensory pollutants in air handling systems. The objective of the present study was to evaluate the net effect that different combinations of filters had on perceived air quality after 5 months of continuous filtration of outdoor suburban air. A panel....... Furthermore, its pressure drop changed very little during the 5 months of service, and it had the added benefit of removing a large fraction of ozone from the airstream. If similar results are obtained over a wider variety of soiling conditions, such filters may be a viable solution to a long recognized...

  13. Digital notch filter based active damping for LCL filters

    DEFF Research Database (Denmark)

    Yao, Wenli; Yang, Yongheng; Zhang, Xiaobin

    2015-01-01

    . In contrast, the active damping does not require any dissipation elements, and thus has become of increasing interest. As a result, a vast of active damping solutions have been reported, among which multi-loop control systems and additional sensors are necessary, leading to increased cost and complexity....... In this paper, a notch filter based active damping without the requirement of additional sensors is proposed, where the inverter current is employed as the feedback variable. Firstly, a design method of the notch filter for active damping is presented. The entire system stability has then been investigated...... in the z-domain. Simulations and experiments are carried out to verify the proposed active damping method. Both results have confirmed that the notch filter based active damping can ensure the entire system stability in the case of resonances with a good system performance....

  14. Activated, coal-based carbon foam

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, Darren Kenneth; Plucinski, Janusz Wladyslaw

    2004-12-21

    An ablation resistant, monolithic, activated, carbon foam produced by the activation of a coal-based carbon foam through the action of carbon dioxide, ozone or some similar oxidative agent that pits and/or partially oxidizes the carbon foam skeleton, thereby significantly increasing its overall surface area and concurrently increasing its filtering ability. Such activated carbon foams are suitable for application in virtually all areas where particulate or gel form activated carbon materials have been used. Such an activated carbon foam can be fabricated, i.e. sawed, machined and otherwise shaped to fit virtually any required filtering location by simple insertion and without the need for handling the "dirty" and friable particulate activated carbon foam materials of the prior art.

  15. Activated, coal-based carbon foam

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, Darren Kenneth [Wheeling, WV; Plucinski, Janusz Wladyslaw [Glen Dale, WV

    2009-06-09

    An ablation resistant, monolithic, activated, carbon foam produced by the activation of a coal-based carbon foam through the action of carbon dioxide, ozone or some similar oxidative agent that pits and/or partially oxidizes the carbon foam skeleton, thereby significantly increasing its overall surface area and concurrently increasing its filtering ability. Such activated carbon foams are suitable for application in virtually all areas where particulate or gel form activated carbon materials have been used. Such an activated carbon foam can be fabricated, i.e. sawed, machined and otherwise shaped to fit virtually any required filtering location by simple insertion and without the need for handling the "dirty" and friable particulate activated carbon foam materials of the prior art.

  16. An overview on hybrid active filters

    Energy Technology Data Exchange (ETDEWEB)

    Libano, Fausto B.; Uceda, Javier [Universidad Politecnica de Madrid (Spain). Division de Ingenieria Electronica; Simonetti, Domingos S.L. [Espirito Santo Univ., Vitoria, ES (Brazil). Dept. de Engenharia Eletrica

    1995-12-31

    This paper summarizes the main hybrid filter methods. A special attention is given to series active filter associations. Nowadays, an hybrid filtering is the preferred choice to improve line performance when feeding high-power non-linear loads. In addition, the use of an independent reference frame leads to a better response comparing to the initial proposition of p-q theory. A comparison of possible filter associations is given, presenting the expected function of each one. The work represents an interesting overview on the state-of-the-art of hybrid filters. (author) 16 refs., 8 figs., 2 tabs.

  17. Cast Steel Filtration Trials Using Ceramic-Carbon Filters

    Directory of Open Access Journals (Sweden)

    Lipowska B.

    2014-12-01

    Full Text Available Trials of cast steel filtration using two types of newly-developed foam filters in which carbon was the phase binding ceramic particles have been conducted. In one of the filters the source of carbon was flake graphite and coal-tar pitch, while in the other one graphite was replaced by a cheaper carbon precursor. The newly-developed filters are fired at 1000°C, i.e. at a much lower temperature than the currently applied ZrO2-based filters. During filtration trials the filters were subjected to the attack of a flowing metal stream having a temperature of 1650°C for 30 seconds.

  18. Design of active N-path filters

    NARCIS (Netherlands)

    Darvishi, Milad; Zee, van der Ronan; Nauta, Bram

    2013-01-01

    A design methodology for synthesis of active N-path bandpass filters is introduced. Based on this methodology, a 0.1-to-1.2 GHz tunable 6th-order N-path channel-select filter in 65 nm LP CMOS is introduced. It is based on coupling N-path filters with gyrators, achieving a “flat” passband shape and h

  19. 生物活性炭老化对滤池过滤阻力和处理效果的影响%Effect of aged biological activated carbon on the filtration resistance and performance of biological activated carbon filter

    Institute of Scientific and Technical Information of China (English)

    刘璟言; 卢小燕; 尤作亮; 张金松; 郭建宁

    2016-01-01

    Biological activated carbon (BAC) used for about 10years was collected from drinking water treatment plant. The filtration resistance and performance of the aged BAC filter were investigated. The ageing of BAC produced a lot of small BAC particles. The small particles deposited on the surface of the BAC column after backwash and formed a dense filtration layer. The specific resistance of the dense filtration layer was 22 times higher than that of the deep layer of the aged BAC column. Enhanced backwash only decreased the initial filtration resistance and the removal of the dense filtration layer was the most effective method to reduce the filtration resistance. Enhanced backwash had no significant effect on the performance of the aged BAC column. The removal efficiency of the total organic carbon decreased from 24.71% to 7.04% after the removal of the dense filtration layer. However, the removal efficiencies of UV254 and particle count larger than 2µm did not change greatly and the values were nearly the same as those of the control group. There are several methods to increase the life cycle of the aged BAC, including decreasing the backwashing strength and prolonging the filtration cycle.%利用饮用水厂运行10年的生物活性炭(BAC)装填滤柱,研究活性炭老化对滤柱过滤阻力和处理效果的影响.结果表明,活性炭老化会产生大量小粒径颗粒炭,沉积于活性炭池表层的小粒径颗粒炭产生的过滤阻力是滤柱总阻力的主要来源,其比阻约为底层炭的22倍.强化反冲洗仅可降低初始过滤阻力,移除表层细炭是降低活性炭滤池阻力的有效方法.强化反冲洗对滤柱过滤性能无显著影响.移除表层细炭后,老化活性炭滤柱对总有机碳的去除率由24.71%下降至7.04%,而后恢复至移除前的水平.移除表层炭后老化活性炭对UV254和大于2µm颗粒数的去除率与对照组活性炭相似.降低活性炭滤池的反冲强度、延长过滤

  20. Active imaging system with Faraday filter

    Science.gov (United States)

    Snyder, James J.

    1993-01-01

    An active imaging system has a low to medium powered laser transmitter and receiver wherein the receiver includes a Faraday filter with an ultranarrow optical bandpass and a bare (nonintensified) CCD camera. The laser is locked in the vicinity of the passband of the Faraday filter. The system has high sensitivity to the laser illumination while eliminating solar background.

  1. Design and control of LCL-filter with active damping for Active Power Filter

    DEFF Research Database (Denmark)

    Zeng, Guohong; Rasmussen, Tonny Wederberg; Ma, L

    2010-01-01

    In the application of shunt Active Power Filter (APF) to compensate nonlinear load's harmonic, reactive and negative sequence current, it is more effective to use a LCL-filter than an L-filter as an interface between the Voltage Source Converter (VSC) and grid. In this paper, a designing procedure...... of LCL-filter for APF is introduced, which is aimed for simplified the implementation. To suppress the resonance that may be excited in the system, which brings in stability problems, an active damping control strategy using the current feed-back of the filter capacitor is adopted. By selecting two equal...

  2. Nanoporous Carbon Nitride: A High Efficient Filter for Seawater Desalination

    OpenAIRE

    Weifeng LI; Yang, Yanmei; Zhou, Hongcai; Zhang, Xiaoming; Zhao, Mingwen

    2015-01-01

    The low efficiency of commercially-used reverse osmosis (RO) membranes has been the main obstacle in seawater desalination application. Here, we report the auspicious performance, through molecular dynamics simulations, of a seawater desalination filter based on the recently-synthesized graphene-like carbon nitride (g-C2N) [Nat. Commun., 2015, 6, 6486]. Taking advantage of the inherent nanopores and excellent mechanical properties of g-C2N filter, highly efficient seawater desalination can be...

  3. Adsorption of gaseous pollutants on activated carbon filters. Modelling of the coupled exchanges of heat and mass; Adsorption de polluants gazeux sur des filtres de charbon actif. Modelisation des echanges couples de matiere et de chaleur

    Energy Technology Data Exchange (ETDEWEB)

    Fiani, E.

    2000-01-27

    The aim of this work is to remove gasoline and odorous molecules vapors. Thermodynamics and kinetics studies have been carried out; they concern the fixation of representative gases on activated carbons. Hydrogen sulfide and n-butane are chosen to represent the odorous molecules. Different activated carbons are considered: only the adsorbent impregnated by KOH has satisfying performance. The adsorption of hydrocarbons on a granulated activated carbon is studied on four original devices specifically perfected for this work: gravimetry, calorimetry, thermal measurements and gaseous phase chromatography. The gravimetric measurements are coupled to thermal measurements inside the granulates. Strong temperature variations have then been observed inside a granulate during the adsorption. These experimental results have been taken into account to adapt the classical Langmuir kinetic model. This new model allows to predict all the curves: setting / internal temperature variation for the adsorption of the hydrocarbons alone. The competitive nature of the adsorption sites allows then to explain qualitatively the adsorption of binary mixtures of hydrocarbons. At last, the classical Langmuir model allows to explain correctly the thermodynamic results, for the hydrocarbons alone or in binary mixture. The proposed modelling allows then to treat both on a kinetic and thermodynamic way the case of a non isothermal adsorption at the scale of an activated carbon granulate and to predict the phenomena at the filter scale. (O.M.)

  4. Active Comb Filter Using Operational Transconductance Amplifier

    OpenAIRE

    Rajeev Kumar Ranjan; Surya Prasanna Yalla; Shubham Sorya; Paul, Sajal K.

    2014-01-01

    A new approach for the design of an active comb filter is proposed to remove the selected frequencies of various signals. The proposed filter is based on only OTAs and capacitors, hence suitable for monolithic integrated circuit implementation. The workability of the circuit is tested using PSPICE for test signals of 60, 180, 300, and 420 Hz as in ECG signal. The results are given in the paper and found to agree well with theory.

  5. Active Comb Filter Using Operational Transconductance Amplifier

    Directory of Open Access Journals (Sweden)

    Rajeev Kumar Ranjan

    2014-01-01

    Full Text Available A new approach for the design of an active comb filter is proposed to remove the selected frequencies of various signals. The proposed filter is based on only OTAs and capacitors, hence suitable for monolithic integrated circuit implementation. The workability of the circuit is tested using PSPICE for test signals of 60, 180, 300, and 420 Hz as in ECG signal. The results are given in the paper and found to agree well with theory.

  6. Nanoporous Carbon Nitride: A High Efficient Filter for Seawater Desalination

    CERN Document Server

    Li, Weifeng; Zhou, Hongcai; Zhang, Xiaoming; Zhao, Mingwen

    2015-01-01

    The low efficiency of commercially-used reverse osmosis (RO) membranes has been the main obstacle in seawater desalination application. Here, we report the auspicious performance, through molecular dynamics simulations, of a seawater desalination filter based on the recently-synthesized graphene-like carbon nitride (g-C2N) [Nat. Commun., 2015, 6, 6486]. Taking advantage of the inherent nanopores and excellent mechanical properties of g-C2N filter, highly efficient seawater desalination can be achieved by modulating the nanopores under tensile strain. The water permeability can be improved by two orders of magnitude compared to RO membranes, which offers a promising approach to the global water shortage solution.

  7. Comparative research on removing mercury by powder activated carbon on bag filter%纯活性炭粉末布袋脱汞的比较研究

    Institute of Scientific and Technical Information of China (English)

    陈振松; 杨国华; 黄三; 于建伟; 盛伟鹏; 谭均军

    2011-01-01

    For improving mercury removal efficiency of activated carbon(AC) injection upstream a bag filter and the utilization ratio of powder activated carbon(PAC), mercury removal experiments were conducted in a small-scale bag filter with pure PAC as the sorbent. The results indicate that the average mercury removal efficiency(AMRE) was 99.1% within 85 minutes for the first adsorption, and the adsorption time was 1335 minutes with removal efficiency above 75%. For comparison, other experiments were conducted using PAC mixed with different pro- portion of fly ash. The results show that the AMRE within 85 minutes for the first adsorption was only 19.3% and the removal efficiency fell to 0 after 165 minutes with fly ash as the sot- bent. The AMRE within 85 minutes for the first adsorption were 99.1~,95%, 85.3%, 79.7%, and 59.6%, and the mercury adsorption capacity with removal efficiency above 75% were 196.1 172.5, 133.8, 123.6, and 21.7 μg Hg/g AC for the PAC based sorbents mixed with the fly ash of 0, 20%, 50%, 80%, and95%, respectively. Hence, the mercury removal new technology by pure PAC on bag filter has better mercury removal efficiency and utilization ratio of PAC.%为解决布袋除尘器活性炭(AC)喷射脱汞传统技术中活性炭粉末利用率低、脱汞效率低的问题,提出了纯活性炭粉末一布袋脱汞新技术,采用纯活性炭粉末为吸附剂,进行了布袋脱汞实验研究,结果表明:纯活性炭粉末初次吸附的前85min的平均脱汞效率为99.1%,脱汞效率大于75%的累计吸附时间为1335min.为便于比较,进行了活性炭粉末掺杂不同比例飞灰的脱汞实验,结果表明:纯飞灰在初次吸附的前85min脱汞效率仅为19.3%,165min时脱汞效率已经下降为0.活性炭粉末掺杂飞灰比例分别为0,20%,50%,80%,95%时,初次吸附的前85min的平均脱汞效率分别为99.1%,95%,85.3%,79.7%,59.6%,每

  8. 陶粒-沸石-活性炭组合填料生物滤池的研究%Research on Ceramic-zeolite-active Carbon Combined Medium Biological Aerated Filter

    Institute of Scientific and Technical Information of China (English)

    张尊举; 董春艳

    2013-01-01

    采用陶粒、沸石、活性炭填料合理组合作为曝气生物滤池的填料对高校生活污水进行处理。研究了组合填料生物滤池生物膜的培养,不同水力负荷、容积负荷和气水比对污水处理效率的影响,以及该生物滤池对生活污水的处理效果。结果表明,采用组合填料生物滤池,接种挂膜培养周期为25 d,在水力负荷为2.5 m3/(m2·h),气水比3.5:1,组合填料生物滤池出水COD、 BOD5、 SS、 NH3-N和色度平均值达到《城市污水再生利用城市杂用水水质》GB/T 18920-2002水质要求。%As a filter medium, Ceramic, zeolite, activated carbon were combined to use for biological aerated filter in the treatment of campus domestic wastewater. The study focused on the start rule of the combined medium biological aerated filter. Meanwhile, different hydraulic load, load capacity and water ratio on the sewage treatment effect, and the treatment effect of biological aerated filter for domestic wastewater were studied. The results show that, the time needed for the start-up and film formation of combined medium biological aerated filter about 25 d. When the hydraulic load was 2.5 m3/(m2·h) , the water ratio was 3.5:1, combined medium biological aerated filter becomes more reasonable and suitable, achieving good results in practical operation. the average values of COD、 BOD5、 SS、 NH3-N and Chrominance reached the Standards for The reuse of urban recycling water-water quality standard for urban miscellaneous water consumption GB/T 18920-2002.

  9. The use of nutshell carbons in drinking water filters for removal of trace metals.

    Science.gov (United States)

    Ahmedna, Mohamed; Marshall, Wayne E; Husseiny, Abdo A; Rao, Ramu M; Goktepe, Ipek

    2004-02-01

    Filtration of drinking water by point-of-use (POU) or point-of-entry (POE) systems is becoming increasingly popular in the United States. Drinking water is filtered to remove both organic and inorganic contaminants. The objective of this study was to evaluate the use of granular activated carbon from nutshells (almond, English walnut, pecan) in a POU water filtration system to determine its effectiveness in removing select, potentially toxic metal ions, namely, copper (Cu2+), lead (Pb2+) or zinc (Zn2+) found in drinking water. The nutshell-based carbon system was designated "Envirofilter" and was compared to four commercial POU systems with brand names of BRITA, Omni Filter, PUR and Teledyne Water Pik. Eight prototype "Envirofilters", consisting of individual or binary mixtures of carbons made from acid-activated almond or pecan shells and steam-activated pecan or walnut shells were constructed and evaluated for adsorption of the three metal ions. The results indicated that a binary mixture of carbons from acid-activated almond and either steam-activated pecan or walnut shells were the most effective in removing these metals from drinking water of all the POU systems evaluated. Binary mixtures of acid-activated almond shell-based carbon with either steam-activated pecan shell- or walnut shell-based carbon removed nearly 100% of lead ion, 90-95% of copper ion and 80-90% of zinc ion. Overall the performance data on the "Envirofilters" suggest that these prototypes require less carbon than commercial filters to achieve the same metal adsorption efficiency and may also be a less expensive product.

  10. Digitally Controlled ’Programmable’ Active Filters.

    Science.gov (United States)

    1985-12-01

    Mitra, S. K., Analysis and Synthesis of Linear Active .. Networks, Wiley, New York, 1969. * 6. Sedra , A. S. and Smith , K. C., "A Second-Generation...Current Conveyor and its Applications," IEEE Trans. Circuit Theory, Vol. CT-17, pp. 132-134, 1970. 7. Sedra , A. S., "A New Approach to Active Network...CT-18, pp. 358-361, May 1971. 27. Hamilton, T. A., and Sedra , A. S., "Some New IJ Configurations for Active Filters," IEEE Trans. Circuit Tehory, Vol

  11. Programmable Current-Mode Universal Active Filters Employing Current Conveyors

    OpenAIRE

    Muhammad Taher Abuelma'atti

    1998-01-01

    Novel current-mode active filter circuits using current-conveyors are presented. The proposed circuits can realize all standard second-order filter functions. The circuits enjoy high output impedances and can, therefore, be easily cascaded to produce higher order filters. Moreover, the realized filter function can be easily programmed using at most a 13-bit digital number without changing the circuit topology.

  12. Remoção de diclofenaco, ibuprofeno, naproxeno e paracetamol em filtro ecológico seguido por filtro de carvão granular biologicamente ativado Removal of diclofenac, ibuprofen, naproxen, and paracetamol in ecological filter followed by granular carbon filter biologically active

    Directory of Open Access Journals (Sweden)

    Caroline Moço Erba

    2012-06-01

    Full Text Available O filtro ecológico representa uma promissora tecnologia de tratamento, em razão desta não necessitar da aplicação de produtos químicos, além de sua constatada eficiência. Nele, estabelece-se entre os seres vivos a relação de cadeia alimentar. Inicialmente uma matriz aquosa foi acrescida de quatro fármacos (diclofenaco, naproxeno, ibuprofeno e paracetamol e posteriormente analisada por cromatografia líquida de alta eficiência para avaliar a remoção desses compostos pelo filtro ecológico seguido pelo filtro de carvão granular biologicamente ativado. Parâmetros, entre eles turbidez, coliformes totais e termotolerantes, cor aparente e cor verdadeira, foram mensurados para verificar a eficiência dos filtros. Houve remoção de 97,43% do diclofenaco, 85,03% do ibuprofeno: 94,11% do naproxeno e 84,07% do paracetamol.The ecological filter represents a promising treatment technology, because this doesn't require the application of chemicals and is efficient. In it, is between living beings the relationship of the food chain. Initially an aqueous matrix was added to four drugs (diclofenac, naproxen, ibuprofen and paracetamol, and subsequently analyzed by high performance liquid chromatography to evaluate the removal of these compounds by ecological filter followed by granular activated carbon filter biologically active. The pharmacological compounds and parameters such as turbity, total and fecal coliforms, apparent color and true color were measured to evaluate the effectiveness of filters. There was removal of the drugs applied and the parameters measured. The percentages of removal were 97,43% of diclofenaco,85,03% of ibuprofen, 94,11% of naproxen and 84,07% of paracetamol.

  13. Power System Harmonic Compensation Using Shunt Active Power Filter.

    Directory of Open Access Journals (Sweden)

    Shiuly Mukherjee

    2014-07-01

    Full Text Available This paper shows the method of improving the power quality using shunt active power filter. The proposedtopic comprises of PI controller, filter hysteresis current control loop, dc link capacitor. The switching signal generation for filter is fromhysteresis current controller techniques. With the all these element shunt active power filter reduce the total harmonic distortion. Thispaper represents the simulation and analysis of the using three phase three wire system active filter to compensate harmonics .Theproposed shunt active filter model uses balanced non-linear load. This paper successfully lowers the THD within IEEE norms and satisfactorily works to compensatecurrent harmonics.

  14. CONTROL OF DBPs IN THE MID-POSITIONING ACTIVATED CARBON FILTER PROCESS%中置活性炭滤池工艺消毒副产物的控制

    Institute of Scientific and Technical Information of China (English)

    郭键勇; 陆少鸣; 胡常浩; 刘金翠; 李少文

    2013-01-01

    中置活性炭滤池采用不同消毒工艺进行试验,考察其对出水消毒副产物的控制情况.结果表明,预臭氧投加量过大可能导致消毒副产物超标.在预臭氧投加量为0.3 mg/L时,后续处理采用中置曝气活性炭滤池,在砂滤池前加氯,可保证出水消毒副产物满足要求.当耐氯性微型水生动物难以控制时,可采用后臭氧消毒,臭氧投加量在1.0mg/L内,同时砂滤池后投加氯辅助消毒,既能控制消毒副产物,又可保证管网水质生物稳定性.%Different disinfection process was performed on mid-positioning activated carbon filter to investigate the removal of DBPs.The results show that the excessive preozone dosage may lead to exceed standard of DBPs.Under a preozone dosage of 0.3 mg/L and chlorination disinfection before sand filter, it can ensure that the effluent DBPs meet the requirement of standard.When the chlorine tolerance of aquatic micro-animals are hard to control, the post-ozonation disifection process could be adopted, with an ozone dosage within 1.0 mg/L and certain chlorine after the sand filter, which could both control DBPs and guarantee the network water safety.

  15. Power active filter control based on a resonant disturbance observer

    OpenAIRE

    Ramos Fuentes, German A.; Cortés Romero, John Alexander; Zou, Zhixiang; Costa Castelló, Ramon; Zhou, Keliang

    2015-01-01

    Active filters are power electronics devices used to eliminate harmonics from the distribution network. This article presents an active disturbance rejection control scheme for active filters. The controller is based on a linear disturbance observer combined with a disturbance rejection scheme. The parameter tuning is based on a combined pole placement and an optimal estimation based on Kalman-Bucy filter. Proposed scheme is validated through simulation and experimental work in an active filter.

  16. Prediction control of active power filters

    Institute of Scientific and Technical Information of China (English)

    王莉娜; 罗安

    2003-01-01

    A prediction method to obtain harmonic reference for active power filter is presented. It is a new use ofthe adaptive predictive filter based on FIR. The delay inherent in digital controller is successfully compensated by u-sing the proposed method, and the computing load is not very large compared with the conventional method. Moreo-ver, no additional hardware is needed. Its DSP-based realization is also presented, which is characterized by time-va-riant rate sampling, quasi synchronous sampling, and synchronous operation among the line frequency, PWM gener-ating and sampling in A/D unit. Synchronous operation releases the limitation on PWM modulation ratio and guar-antees that the electrical noises resulting from the switching operation of IGBTs do not interfere with the sampledcurrent. The simulation and experimental results verify the satisfactory performance of the proposed method.

  17. New control algorithm for shunt active filters, based on self-tuned vector filter

    OpenAIRE

    Perales Esteve, Manuel Ángel; Mora Jiménez, José Luis; Carrasco Solís, Juan Manuel; García Franquelo, Leopoldo

    2001-01-01

    A new, improved, method for calculating the reference of a shunt active filter is presented. This method lays on a filter, which is able to extract the main component of a vector signal. This filter acts as a Phase-Locked Loop, capturing a particular frequency. The output of this filter is in phase with the frequency isolated, and has its amplitude. Simulation and experimental results confirms the validity of the proposed algorithm.

  18. JPL Activated Carbon Treatment System (ACTS) for sewage

    Science.gov (United States)

    1976-01-01

    An Activated Carbon Treatment System (ACTS) was developed for sewage treatment and is being applied to a one-million gallon per day sewage treatment pilot plant in Orange County California. Activities reported include pyrolysis and activation of carbon-sewage sludge, and activated carbon treatment of sewage to meet ocean discharge standards. The ACTS Sewage treatment operations include carbon-sewage treatment, primary and secondary clarifiers, gravity (multi-media) filter, filter press dewatering, flash drying of carbon-sewage filter cake, and sludge pyrolysis and activation. Tests were conducted on a laboratory scale, 10,000 gallon per day demonstration plant and pilot test equipment. Preliminary economic studies are favorable to the ACTS process relative to activated sludge treatment for a 175,000,000 gallon per day sewage treatment plant.

  19. Rotating carbon nanotube membrane filter for water desalination

    Science.gov (United States)

    Tu, Qingsong; Yang, Qiang; Wang, Hualin; Li, Shaofan

    2016-05-01

    We have designed a porous nanofluidic desalination device, a rotating carbon nanotube membrane filter (RCNT-MF), for the reverse osmosis desalination that can turn salt water into fresh water. The concept as well as design strategy of RCNT-MF is modeled, and demonstrated by using molecular dynamics simulation. It has been shown that the RCNT-MF device may significantly improve desalination efficiency by combining the centrifugal force propelled reverse osmosis process and the porous CNT-based fine scale selective separation technology.

  20. Rotating carbon nanotube membrane filter for water desalination.

    Science.gov (United States)

    Tu, Qingsong; Yang, Qiang; Wang, Hualin; Li, Shaofan

    2016-05-18

    We have designed a porous nanofluidic desalination device, a rotating carbon nanotube membrane filter (RCNT-MF), for the reverse osmosis desalination that can turn salt water into fresh water. The concept as well as design strategy of RCNT-MF is modeled, and demonstrated by using molecular dynamics simulation. It has been shown that the RCNT-MF device may significantly improve desalination efficiency by combining the centrifugal force propelled reverse osmosis process and the porous CNT-based fine scale selective separation technology.

  1. Adaptive Notch filter based active damping for power converters using LCL filters

    DEFF Research Database (Denmark)

    Ciobotaru, M.; Rossé, A.; Bede, L.;

    2016-01-01

    This paper proposes an active damping technique for grid-connected converters using inductor-capacitor-inductor (LCL) filters. The technique relies on a discrete-time adaptive notch filter (NF) which is able to adapt its resonance frequency and bandwidth in real-time. The tuning function of this ......This paper proposes an active damping technique for grid-connected converters using inductor-capacitor-inductor (LCL) filters. The technique relies on a discrete-time adaptive notch filter (NF) which is able to adapt its resonance frequency and bandwidth in real-time. The tuning function...

  2. Generalized design of high performance shunt active power filter with output LCL filter

    DEFF Research Database (Denmark)

    Tang, Yi; Loh, Poh Chiang; Wang, Peng

    2012-01-01

    , the proposed SAPF offers superior switching harmonic suppression using much reduced passive filtering elements. Its output currents thus have high slew rate for tracking the targeted reference closely. Smaller inductance of the LCL filter also means smaller harmonic voltage drop across the passive output......This paper concentrates on the design, control, and implementation of an LCL-filter-based shunt active power filter (SAPF), which can effectively compensate for harmonic currents produced by nonlinear loads in a three-phase three-wire power system. With an LCL filter added at its output...... filter, which in turn minimizes the possibility of overmodulation, particularly for cases where high modulation index is desired. These advantages, together with overall system stability, are guaranteed only through proper consideration of critical design and control issues, like the selection of LCL...

  3. Assessment of exhaust emissions from carbon nanotube production and particle collection by sampling filters.

    Science.gov (United States)

    Tsai, Candace Su-Jung; Hofmann, Mario; Hallock, Marilyn; Ellenbecker, Michael; Kong, Jing

    2015-11-01

    This study performed a workplace evaluation of emission control using available air sampling filters and characterized the emitted particles captured in filters. Characterized particles were contained in the exhaust gas released from carbon nanotube (CNT) synthesis using chemical vapor deposition (CVD). Emitted nanoparticles were collected on grids to be analyzed using transmission electron microscopy (TEM). CNT clusters in the exhaust gas were collected on filters for investigation. Three types of filters, including Nalgene surfactant-free cellulose acetate (SFCA), Pall A/E glass fiber, and Whatman QMA quartz filters, were evaluated as emission control measures, and particles deposited in the filters were characterized using scanning transmission electron microscopy (STEM) to further understand the nature of particles emitted from this CNT production. STEM analysis for collected particles on filters found that particles deposited on filter fibers had a similar morphology on all three filters, that is, hydrophobic agglomerates forming circular beaded clusters on hydrophilic filter fibers on the collecting side of the filter. CNT agglomerates were found trapped underneath the filter surface. The particle agglomerates consisted mostly of elemental carbon regardless of the shapes. Most particles were trapped in filters and no particles were found in the exhaust downstream from A/E and quartz filters, while a few nanometer-sized and submicrometer-sized individual particles and filament agglomerates were found downstream from the SFCA filter. The number concentration of particles with diameters from 5 nm to 20 µm was measured while collecting particles on grids at the exhaust piping. Total number concentration was reduced from an average of 88,500 to 700 particle/cm(3) for the lowest found for all filters used. Overall, the quartz filter showed the most consistent and highest particle reduction control, and exhaust particles containing nanotubes were successfully

  4. Adsorption of Carbon Dioxide on Activated Carbon

    Institute of Scientific and Technical Information of China (English)

    Bo Guo; Liping Chang; Kechang Xie

    2006-01-01

    The adsorption of CO2 on a raw activated carbon A and three modified activated carbon samples B, C, and D at temperatures ranging from 303 to 333 K and the thermodynamics of adsorption have been investigated using a vacuum adsorption apparatus in order to obtain more information about the effect of CO2 on removal of organic sulfur-containing compounds in industrial gases. The active ingredients impregnated in the carbon samples show significant influence on the adsorption for CO2 and its volumes adsorbed on modified carbon samples B, C, and D are all larger than that on the raw carbon sample A. On the other hand, the physical parameters such as surface area, pore volume, and micropore volume of carbon samples show no influence on the adsorbed amount of CO2. The Dubinin-Radushkevich (D-R) equation was the best model for fitting the adsorption data on carbon samples A and B, while the Freundlich equation was the best fit for the adsorption on carbon samples C and D. The isosteric heats of adsorption on carbon samples A, B, C, and D derived from the adsorption isotherms using the Clapeyron equation decreased slightly increasing surface loading. The heat of adsorption lay between 10.5 and 28.4 kJ/mol, with the carbon sample D having the highest value at all surface coverages that were studied. The observed entropy change associated with the adsorption for the carbon samples A, B, and C (above the surface coverage of 7 ml/g) was lower than the theoretical value for mobile adsorption. However, it was higher than the theoretical value for mobile adsorption but lower than the theoretical value for localized adsorption for carbon sample D.

  5. Actively Pumped Optical Filters at 532 nm

    Science.gov (United States)

    Billmers, Richard I.; Gayen, S. K.; Contarino, Vincent M.; Scharpf, William J.; Squicciarini, Martin F.; Allocca, David A.

    1995-01-01

    The operation of two narrow-band optical filters at 532.33 nm is presented. Both of these filters operate on the 4P(sub 1/2) to 8S(sub 1/2) excited-state transition in potassium vapor. One of the filters is based on excited-state Faraday effect, and requires the application of an external axial magnetic field. The peak transmission of this filter is approximately 3.5% with a linewidth of less than 10 GHz. The second filter does not require a magnetic field for its operation, but readily attains peak transmissions of 25-30%. The 4P(sub 1/2) state is excited by a 769.9 nm light pulse which is linearly polarized for the first scheme and circularly polarized for the second.

  6. Fabrication of a multi-walled carbon nanotube-deposited glass fiber air filter for the enhancement of nano and submicron aerosol particle filtration and additional antibacterial efficacy.

    Science.gov (United States)

    Park, Jae Hong; Yoon, Ki Young; Na, Hyungjoo; Kim, Yang Seon; Hwang, Jungho; Kim, Jongbaeg; Yoon, Young Hun

    2011-09-01

    We grew multi-walled carbon nanotubes (MWCNTs) on a glass fiber air filter using thermal chemical vapor deposition (CVD) after the filter was catalytically activated with a spark discharge. After the CNT deposition, filtration and antibacterial tests were performed with the filters. Potassium chloride (KCl) particles (pressure drop across the filter. When a pristine glass fiber filter that had no CNTs was used, the particle filtration efficiencies at particle sizes under 30 nm and near 500 nm were 48.5% and 46.8%, respectively. However, the efficiencies increased to 64.3% and 60.2%, respectively, when the CNT-deposited filter was used. The reduction in the number of viable cells was determined by counting the colony forming units (CFU) of each test filter after contact with the cells. The pristine glass fiber filter was used as a control, and 83.7% of the E. coli were inactivated on the CNT-deposited filter.

  7. Design and Analysis of Robust Active Damping for LCL Filters using Digital Notch Filters

    DEFF Research Database (Denmark)

    Yao, Wenli; Yang, Yongheng; Zhang, Xiaobin;

    2017-01-01

    Resonant poles of LCL filters may challenge the entire system stability especially in digital-controlled Pulse Width Modulation (PWM) inverters. In order to tackle the resonance issues, many active damping solutions have been reported. For instance, a notch filter can be employed to damp the reso......Resonant poles of LCL filters may challenge the entire system stability especially in digital-controlled Pulse Width Modulation (PWM) inverters. In order to tackle the resonance issues, many active damping solutions have been reported. For instance, a notch filter can be employed to damp...... the resonance, where the notch frequency should be aligned exactly to the resonant frequency of the LCL filter. However, parameter variations of the LCL filter as well as the time delay appearing in digital control systems will induce resonance drifting, and thus break this alignment, possibly deteriorating...... the original damping. In this paper, the effectiveness of the notch filter based active damping is firstly explored, considering the drifts of the resonant frequency. It is revealed that, when the resonant frequency drifts away from its nominal value, the phase lead or lag introduced by the notch filter may...

  8. Harmonics Mitigation Using Active Power Filter

    Directory of Open Access Journals (Sweden)

    Sourabh Gupta

    2013-06-01

    Full Text Available This paper is proposed to reconsider the development of active power filter (APF technologies that are routinely utilized to mitigate harmonics in utility power lines. This reconsider can furthermore be considered as a “tutorial-type paper” as it provides a holistic coverage of the APF technologies by omitting the tedious details, but without losing the major essence of the subject matter. It is wanted that by this approach, it would be likely to lure more power engineering readers to be involved in this important and growing area. The discussion starts with a short overview of harmonic distortion difficulties and their impacts on electric power and powered value. The operation of common APF topologies, namely the shunt, sequence and hybrid APFs are recounted in minutia. This is followed by a reconsider on different types of reference pointer estimation extraction methods. In specific, the application of the p-q and elongation p-q theorems to extract the quotation pointers are elaborated, as they are the most commonly discovered in practical APF systems eventually, an overview of the APF command schemes is provided. A short consideration on the APF-solar photovoltaic scheme is furthermore granted. At the end of the paper, important references are cited to aid readers who are interested to discover the subject in larger detail.

  9. Novel Control Strategy for VSI and CSI Active Filters and Comparing These Two Types of Filters

    Directory of Open Access Journals (Sweden)

    Gholam Reza Arab

    2014-10-01

    Full Text Available Recently to eliminate the harmonics and improve the power factor of the power networks, much attention has been attracted to active filters. The advantages of these filters are lower volume and their better compensating characteristics than the passive filters. In conventional sliding mode controllers, the source current waveform is fluctuated in near to zero values. In this paper, using a new sliding technique, lower Total Harmonic Distortion (THD in source current is obtained and the current waveform is improved. As well as, two novel control strategies for two types of active filters, VSI and CSI is proposed and then these two types of filters are compared to reduce THD value of source current.The proposed controlled strategies are simulated by MATLAB/Simulink. The Simulation results confirm that the proposed strategies reduce the THD of source current more than other strategies, and active filter based on CSI has a better performance than active filter based on VSI with a dead time area (for avoiding short circuit of the source in high powers.

  10. DESIGN CONSIDERATIONS FOR SERIES HYBRID ACTIVE POWER FILTER

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Some important factors for designing a series hybrid active power filter (SHAPF) are presented in this paper for the case when the load is varied in a wide range and/or the source voltage is seriously distorted. Special design of passive filters, adaptive control of parameter and multi variant control are discussed in detail. The filter is stable, has good performance, and causes small capacitive reactive current. The simulation and experimental results accorded with the theoretical analysis results.

  11. Hybrid simulation: an active power filter case study

    Directory of Open Access Journals (Sweden)

    Y. A. Garcés

    2011-10-01

    Full Text Available The hybrid simulation concept consisting of a combination of computer simulation and laboratory tests. This approach is a cost effective alternative to physically testing the whole system and allows better understanding of complex coupled systems.This paper describes implementing an active power filter (APF hybrid prototype where the source system and load are implemented as a real-time simulation and the system of static power converter acting as an active power filter is implemented in physical hardware. It also confirmed the hybrid simulation results by implementing the simulation in MATLAB-Simulink regarding the same system implemented during the active power filter analysis and design stage.

  12. 活性炭滤池中微生物特征及其对溶解性有机碳的去除作用%Characteristics of biomass in biological activated carbon(BAC)filters and its contribution to DOC removal

    Institute of Scientific and Technical Information of China (English)

    张春雷; 王东升; 樊康平; 顾军农; 李涛

    2009-01-01

    采用异养菌总数计数(HPC)法检测了北京地区J水厂活性炭滤池中微生物量,并分析了活性炭滤池进出水中有机物的组成、活性炭的吸附作用及微生物作用对溶解性有机碳(DOC)去除的贡献率.结果表明,不同炭龄、不同运行周期活性炭滤池中的微生物量有显著的差异.由于溶解性可生物降解有机碳(BDOC)占溶解性有机碳(DOC)的比例较小,且受微生物数量、活性等因素的影响,微生物对DOC的去除效果极为有限,在1.5年和5年炭龄活性炭滤池中对DOC的去除率仅占总去除率的18.8%和26.4%.此外,微生物对较为敏感的嗅味物质2-MIB和geosmin去除作用也不显著,去除率在15%以下(初始浓度为100ng·L~(-1));在使用5年活性炭滤池中,微生物对2-MIB和geosmin去除率为12%和14%,分别占总去除率的32%和29%.因此,北京地区地表水净水厂活性炭滤池中微生物对有机物控制的贡献率较低,对DOC的去除主要以活性炭的吸附为主.%Heterotrophic plate count ( HPC ) determination is applied to measure the biomass on the carbon used in the biological activated carbon ( BAC ) filter in a water treatment plant in Beijing. The effect of the DOC component in the filtered water, the adsorption of active carbon, the biological activity, and their contribution to DOC removal is analyzed. The results indicate that the biomass fluctuates greatly with the service time of the carbon filter and the operation stage. The micro-biological degradation in BAC filters contributes little to the total DOC removal because of the low ratio of BDOC to DOC in the filtered water. The micro-biologically degraded DOC in the 1.5a-carbon filter comprises only 18.8% of total DOC removed, and 26.4% in the 5a-carbon filter. Furthermore, the micro-biological degradation process is not significant for odorous material removal and contributes 32% and 29% to the total removal of 2-MIB and geosmin, respectively, even in the 5a carbon

  13. Design and Development of a High Efficiency CarbonGranular Bed Filter in Industrial Scale

    Institute of Scientific and Technical Information of China (English)

    张济宇; 旷戈; 林诚

    2004-01-01

    The new dust removal technical route using the carbon-granular bed filter, packed of carbon particles with appropriate grade derive from an online-process vibration sieve, to replace the traditional baggy filter had been developed successfully for capturing the micro-carbon dusts produced from pulverization of petroleum coke,and the green close loop of carbon materials is thus completed in the combined pulverizing and classifying system and pulverized carbon dust removal process. The high dust removal efficiency greater than 99%, low outlet dust concentration less than 100 mg-m-S, low pressure drop through dust filtration chamber less than 980 Pa, simple and easy design, and flexible and stable operation were achieved also with the carbon-granular bed filter in both bench and industrial scale operations.

  14. Filtered-X Affine Projection Algorithms for Active Noise Control Using Volterra Filters

    Directory of Open Access Journals (Sweden)

    Sicuranza Giovanni L

    2004-01-01

    Full Text Available We consider the use of adaptive Volterra filters, implemented in the form of multichannel filter banks, as nonlinear active noise controllers. In particular, we discuss the derivation of filtered-X affine projection algorithms for homogeneous quadratic filters. According to the multichannel approach, it is then easy to pass from these algorithms to those of a generic Volterra filter. It is shown in the paper that the AP technique offers better convergence and tracking capabilities than the classical LMS and NLMS algorithms usually applied in nonlinear active noise controllers, with a limited complexity increase. This paper extends in two ways the content of a previous contribution published in Proc. IEEE-EURASIP Workshop on Nonlinear Signal and Image Processing (NSIP '03, Grado, Italy, June 2003. First of all, a general adaptation algorithm valid for any order of affine projections is presented. Secondly, a more complete set of experiments is reported. In particular, the effects of using multichannel filter banks with a reduced number of channels are investigated and relevant results are shown.

  15. Investigation on the Key Factors and the Solution for pH Value Decrease in Carbon Filter in O3-BAC Process

    Institute of Scientific and Technical Information of China (English)

    陆少鸣; 陈江玲; 李芳

    2013-01-01

    An investigation was carried out to eliminate the decrease of effluent pH value in carbon filter in O3-biological activated carbon process. The influence factors were examined in a pilot test, and pH was adjusted in the pilot and waterworks. Results show that the carbon filter is an acid-base buffer system and the activated carbon is the key factor. Chemical functional groups on activated carbon surface present acid-base properties to buffer the water but decrease with time, so that effluent pH value decreases. The effects of ozone dosage, CO2 in the carbon filter, and the filter influent quality are negligible. A new method to adjust pH is developed:the activated carbon is first modified by soaking in sodium hydroxide solution to make its pH reach the desired value, and then the pH value of inflow is controlled to certain value by dosing lime in sand filter influent. The method is economical and effective.

  16. Fractal analysis of granular activated carbons using isotherm data

    Energy Technology Data Exchange (ETDEWEB)

    Khalili, N.R.; Pan, M. [Illinois Institute of Technology, Chicago, IL (United States). Dept. of Chemical and Environmental Engineering; Sandi, G. [Argonne National Lab., IL (United States)

    1997-08-01

    Utilization of adsorption on solid surfaces was exercised for the first time in 1785. Practical application of unactivated carbon filters, and powdered carbon were first demonstrated in the American water treatment plant, and a municipal treatment plant in New Jersey, in 1883 and 1930, respectively. The use of activated carbon became widespread in the next few decades. At present, adsorption on carbons has a wide spread application in water treatment and removal of taste, odor, removal of synthetic organic chemicals, color-forming organics, and desinfection by-products and their naturally occurring precursors. This paper presents an analysis of the surface fractal dimension and adsorption capacity of a group of carbons.

  17. Load compensation for single phase system using series active filter

    African Journals Online (AJOL)

    user

    transmission system to low voltage distribution system, quite a good number of series ... Keywords: Active power filter (APF), current source type of harmonic load .... voltage source type harmonic loads are having diode rectifier with smoothing.

  18. Neuro-fuzzy based Controller for Solving Active Power Filter

    Directory of Open Access Journals (Sweden)

    Homayoun Ebrahimian

    2016-03-01

    Full Text Available In this paper, two soft computing techniques by fuzzy logic, neural network are used to design alternative control schemes for switching the APF active power filter (APF. The control of a shunt active power filter designed for harmonic and reactive current mitigation. Application of the mentioned model has been combined by an intelligent algorithm for improving the efficiency of proposed controller. Effectiveness of the proposed method has been applied over test case and shows the validity of proposed model.

  19. Peptide-modified optical filters for detecting protease activity.

    Science.gov (United States)

    Kilian, Kristopher A; Böcking, Till; Gaus, Katharina; Gal, Michael; Gooding, J Justin

    2007-11-01

    The organic derivatization of silicon-based nanoporous photonic crystals is presented as a method to immobilize peptides for the detection of protease enzymes in solution. A narrow-line-width rugate filter, a one-dimensional photonic crystal, is fabricated that exhibits a high-reflectivity optical resonance that is sensitive to small changes in the refractive index at the pore walls. To immobilize peptide in the pore of the photonic crystal, the hydrogen-terminated silicon surface was first modified with the alkene 10-succinimidyl undecenoate via hydrosilylation. The monolayer with the succinimide ester moiety at the distal end served the dual function of protecting the underlying silicon from oxidation as well as providing a surface suitable for subsequent derivatization with amines. The surface was further modified with 1-aminohexa(ethylene glycol) (EG(6)) to resist nonspecific adsorption of proteins common in complex biological samples. The distal hydroxyl of the EG(6) is activated using the solid-phase coupling reagent disuccinimidyl carbonate for selective immobilization of peptides as protease recognition elements. X-ray photoelectron spectroscopy analysis reveals high activation and coupling efficiency at each stage of the functionalization. Exposure of the peptide-modified crystals to the protease subtilisin in solution causes a change in the refractive index, resulting in a shift of the resonance to shorter wavelengths, indicating cleavage of organic material within the pores. The lowest detected concentration of enzyme was 37 nM (7.4 pmol in 200 microL).

  20. Use of dominant harmonic active filters in high power applications

    Science.gov (United States)

    Cheng, Po-Tai

    The application of power electronics equipment is increasing rapidly. It is estimated that 60% of electrical power will be processed by power electronics equipment by year 2000. These equipments typically require rectifiers for AC-DC power conversion. Due to their nonlinear nature, most rectifiers draw harmonic current from the utility grid. The harmonic current causes higher energy losses, and may excite resonance conditions in the utility grid. Harmonic standards such as IEEE 519 and IEC 1000-3-2 have been proposed to regulate the harmonic current and voltage levels. This work is to develop a dominant harmonic active filter (DHAF) to realize a cost-effective active filtering solution for nonlinear loads in the range of megawatt and above. The DHAF system achieves harmonic isolation at dominant harmonic frequencies, e.g. the 5th and 7th. This approach allows use of low switching frequency and small rating active filter inverters (1%--2% of the load MVA rating) for implementation. Review of conventional passive filters and various active filters based on high bandwidth PWM inverters is provided. The control theory of the DHAF system is presented. Comparison of the DHAF system and other dominant harmonic filtering approach is provided. Simulation results and laboratory prototype test results are presented to validate the effectiveness of the proposed DHAF system.

  1. Evaluation of harmonic detection methods for active power filter applications

    DEFF Research Database (Denmark)

    Asiminoaei, Lucian; Blaabjerg, Frede; Hansen, Steffan

    2005-01-01

    filter is to use a good method for current/voltage reference generation. There exist many implementations supported by different theories (either in time- or frequency-domain), which continuously debate their performances proposing ever better solutions. This paper gives a survey of the common used...... theories. Then, the work here proposes a simulation setup that decouples the harmonic reference generator from the active filter model and its controller. In this way the selected methods can be equally analyzed and compared with respect to their performance, which helps anticipating possible...... implementation issues. The conclusions are collected and a comparison is given at the end, which is useful in deciding the future hardware setup implementation. The comparison shows that the choice of numerical filtering is a key factor for obtaining good accuracies and dynamics for an active filter....

  2. Separating proteins with activated carbon.

    Science.gov (United States)

    Stone, Matthew T; Kozlov, Mikhail

    2014-07-15

    Activated carbon is applied to separate proteins based on differences in their size and effective charge. Three guidelines are suggested for the efficient separation of proteins with activated carbon. (1) Activated carbon can be used to efficiently remove smaller proteinaceous impurities from larger proteins. (2) Smaller proteinaceous impurities are most efficiently removed at a solution pH close to the impurity's isoelectric point, where they have a minimal effective charge. (3) The most efficient recovery of a small protein from activated carbon occurs at a solution pH further away from the protein's isoelectric point, where it is strongly charged. Studies measuring the binding capacities of individual polymers and proteins were used to develop these three guidelines, and they were then applied to the separation of several different protein mixtures. The ability of activated carbon to separate proteins was demonstrated to be broadly applicable with three different types of activated carbon by both static treatment and by flowing through a packed column of activated carbon.

  3. A Series-LC-Filtered Active Trap Filter for High Power Voltage Source Inverter

    DEFF Research Database (Denmark)

    Bai, Haofeng; Wang, Xiongfei; Loh, Poh Chiang

    2016-01-01

    current control of the auxiliary converter, which can be challenging considering that the switching harmonics have very high orders. In this paper, an Active Trap Filter (ATF) based on output impedance shaping is proposed. It is able to bypass the switching harmonics by providing nearly zero output...... impedance. A series-LC-filter is used to reduce the power rating and synthesize the desired output impedance of the ATF. Compared with the existing approaches, the compensated frequency range is greatly enlarged. Also, the current reference is simply set to zero, which reduces the complexity of the control...

  4. Sliding Mode Controller for Three-Phase Hybrid Active Power Filter with Photovoltaic Application

    OpenAIRE

    Blorfan, Ayman; Merckle, Jean; Flieller, Damien; Wira, Patrice; Sturtzer, Guy

    2012-01-01

    International audience; This paper presents a new three-phase hybrid active power filter configuration that interconnects a passive high-pass filter in parallel with an active power filter and a photovoltaic system. The proposed configuration can improves the filtering performance of the conventional active power filter, as well as simultaneously supply the power from the photovoltaic arrays to the load and utility. This paper will describe the proposed hybrid active power filter control usin...

  5. 75 FR 70208 - Certain Activated Carbon From the People's Republic of China: Final Results and Partial...

    Science.gov (United States)

    2010-11-17

    ... carbon cloth. Activated carbon cloth is a woven textile fabric made of or containing activated carbon fibers. It is used in masks and filters and clothing of various types where a woven format is required... preliminarily rescinded the review with respect to Lingzhou, the Department now finds that it would be unfair...

  6. In situ sorption of technetium using activated carbon

    Energy Technology Data Exchange (ETDEWEB)

    Holm, E. E-mail: elis.holm@radfys.lu.se; Gaefvert, T.; Lindahl, P.; Roos, P

    2000-07-15

    The sorption of technetium in pertechnetate form on carbon has been investigated. The sorption is pH dependent with maximal distribution coefficients, K{sub d}, in the order of 10{sup 6} at pH 2-4 for activated carbon with a grain size {<=}100 {mu}m. The equilibrium time to reach such distribution coefficient was about 5 h at room temperature. The exact mechanisms for the sorption are not fully understood but reduction of Tc by the carbon might be an important process. Technetium can effectively and rapidly (5 l min{sup -1}) be sorbed from very large volumes (several hundred liters) of environmental waters on commercial cartridge filters impregnated with activated carbon. After incineration, the filters can be analyzed for {sup 99}Tc by conventional methods.

  7. Active pre-filters for dc/dc Boost regulators

    Directory of Open Access Journals (Sweden)

    Carlos Andrés Ramos-Paja

    2014-07-01

    Full Text Available This paper proposes an active pre-filter to mitigate the current harmonics generated by classical dc/dc Boost regulators, which generate current ripples proportional to the duty cycle. Therefore, high output voltage conditions, i.e., high voltage conversion ratios, produce high current harmonics that must be filtered to avoid damage or source losses. Traditionally, these current components are filtered using electrolytic capacitors, which introduce reliability problems because of their high failure rate. The solution introduced in this paper instead uses a dc/dc converter based on the parallel connection of the Boost canonical cells to filter the current ripples generated by the Boost regulator, improving the system reliability. This solution provides the additional benefits of improving the overall efficiency and the voltage conversion ratio. Finally, the solution is validated with simulations and experimental results.

  8. Hybrid Active Filter with Variable Conductance for Harmonic Resonance Suppression in Industrial Power Systems

    DEFF Research Database (Denmark)

    Lee, Tzung-Lin; Wang, Yen-Ching; Li, Jian-Cheng

    2015-01-01

    -tuned passive filter and an active filter in series connection, both dc voltage and kVA rating of the active filter are dramatically decreased compared with the pure shunt active filter. In real application, this feature is very attractive since the active power filter with fully power electronics is very...... expensive. A reasonable trade-off between filtering performances and cost is to use the hybrid active filter. Design consideration are presented and experimental results are provided to validate effectiveness of the proposed method. Furthermore, this paper discusses filtering performances on line impedance...

  9. Flue-gas carbon capture on carbonaceous sorbents: Toward a low-cost multifunctional Carbon Filter for 'Green' energy producers

    Energy Technology Data Exchange (ETDEWEB)

    Radosz, M.; Hu, X.D.; Krutkramelis, K.; Shen, Y.Q. [University of Wyoming, Laramie, WY (United States)

    2008-05-15

    A low-pressure Carbon Filter Process (patent pending) is proposed to capture carbon dioxide (CO{sub 2}) from flue gas. This filter is filled with a low-cost carbonaceous sorbent, such as activated carbon or charcoal, which has a high affinity (and, hence, high capacity) to CO{sub 2} but not to nitrogen (N{sub 2}). This, in turn, leads to a high CO{sub 2}/N{sub 2} selectivity, especially at low pressures. The Carbon Filter Process proposed in this work can recover at least 90% of flue-gas CO{sub 2} of 90%+ purity at a fraction of the cost normally associated with the conventional amine absorption process. The Carbon Filter Process requires neither expensive materials nor flue-gas compression or refrigeration, and it is easy to heat integrate with an existing or grassroots power plant without affecting the cost of the produced electricity too much. An abundant supply of low-cost CO{sub 2} from electricity producers is good news for enhanced oil recovery (EOR) and enhanced coal-bed methane recovery (ECBMR) operators, because it will lead to higher oil and gas recovery rates in an environmentally sensitive manner. A CO{sub 2}-rich mixture that contains some nitrogen is much less expensive to separate from flue-gas than pure CO{sub 2}; therefore, mixed CO{sub 2}/N{sub 2}-EOR and CO{sub 2}/N{sub 2}-ECBMR methods are proposed to maximize the overall carbon capture and utilization efficiency.

  10. Design and control of hybrid active power filters

    CERN Document Server

    Lam, Chi-Seng

    2014-01-01

    Design and Control of Hybrid Active Power Filters presents an overview of the current quality problems and their compensators. To get a balance between the system cost and performance, hybrid active power filters (HAPFs) are valuable. The book presents the coverage of resonance phenomena prevention capability, filtering performance and system robustness analysis of HAPF; nonlinear inverter current slope characteristics and their linear operation region requirement analysis of the hysteresis PWM for the HAPF; minimum inverter capacity design procedure of HAPF, adaptive dc-link voltage controller for the HAPF and the real design example of a 220V 10kVA HAPF, in which the system performance analysis method, minimum dc voltage deduction concept and adaptive dc voltage idea can be further extended into the other active compensators, such as APF, static synchronous compensator STATCOM, etc. This book will benefit researchers, graduate students, and electrical power engineers in the field of power-quality compensati...

  11. Filtered pulsed cathodic arc deposition of fullerene-like carbon and carbon nitride films

    Energy Technology Data Exchange (ETDEWEB)

    Tucker, Mark D., E-mail: martu@ifm.liu.se; Broitman, Esteban; Näslund, Lars-Åke; Hultman, Lars; Rosen, Johanna [Thin Film Physics Division, Department of Physics, Chemistry and Biology (IFM), Linköping University, SE-58183 Linköping (Sweden); Czigány, Zsolt [Institute for Technical Physics and Materials Science, RCNS, Hungarian Academy of Sciences, P.O. Box 49, H-1525 Budapest (Hungary)

    2014-04-14

    Carbon and carbon nitride films (CN{sub x}, 0 ≤ x ≤ 0.26) were deposited by filtered pulsed cathodic arc and were investigated using transmission electron microscopy and X-ray photoelectron spectroscopy. A “fullerene-like” (FL) structure of ordered graphitic planes, similar to that of magnetron sputtered FL-CN{sub x} films, was observed in films deposited at 175 °C and above, with N{sub 2} pressures of 0 and 0.5 mTorr. Higher substrate temperatures and significant nitrogen incorporation are required to produce similar FL structure by sputtering, which may, at least in part, be explained by the high ion charge states and ion energies characteristic of arc deposition. A gradual transition from majority sp{sup 3}-hybridized films to sp{sup 2} films was observed with increasing substrate temperature. High elastic recovery, an attractive characteristic mechanical property of FL-CN{sub x} films, is evident in arc-deposited films both with and without nitrogen content, and both with and without FL structure.

  12. Filtered pulsed cathodic arc deposition of fullerene-like carbon and carbon nitride films

    Science.gov (United States)

    Tucker, Mark D.; Czigány, Zsolt; Broitman, Esteban; Näslund, Lars-Åke; Hultman, Lars; Rosen, Johanna

    2014-04-01

    Carbon and carbon nitride films (CNx, 0 ≤ x ≤ 0.26) were deposited by filtered pulsed cathodic arc and were investigated using transmission electron microscopy and X-ray photoelectron spectroscopy. A "fullerene-like" (FL) structure of ordered graphitic planes, similar to that of magnetron sputtered FL-CNx films, was observed in films deposited at 175 °C and above, with N2 pressures of 0 and 0.5 mTorr. Higher substrate temperatures and significant nitrogen incorporation are required to produce similar FL structure by sputtering, which may, at least in part, be explained by the high ion charge states and ion energies characteristic of arc deposition. A gradual transition from majority sp3-hybridized films to sp2 films was observed with increasing substrate temperature. High elastic recovery, an attractive characteristic mechanical property of FL-CNx films, is evident in arc-deposited films both with and without nitrogen content, and both with and without FL structure.

  13. Indirect control of a single-phase active power filter

    Directory of Open Access Journals (Sweden)

    Mihai CULEA

    2006-12-01

    Full Text Available The control of shunt active power filters using PWM inverters consists in generating a reference by separating, using different methods, the harmonics to be eliminated. The methods used are time-consuming and need dedicated control and signal processing equipments. To avoid these setbacks a new method is proposed in the paper. The active power filter is a current PWM rectifier with voltage output and with a capacitor on the DC side. The PWM rectifier is controlled so that the sum of its current and the load’s current is a sinusoid. The control block as well as simulation results are presented.

  14. Control strategies of active filters in the context of power conditioning

    DEFF Research Database (Denmark)

    Dan, Stan George; Benjamin, Doniga Daniel; Magureanu, R.;

    2005-01-01

    Active Power Filters have been intensively explored in the past decade. Various topologies and control schemes have been documented aiming at reducing the cost and improving the performance of the compensation system. Hybrid active filters inherit the efficiency of passive filters and the improved...... performance of active filters, and thus constitute a viable improved approach for harmonic compensation. In this paper a parallel hybrid filter is studied for current harmonic compensation. The hybrid filter is formed by a single tuned LC filter per phase and a small-rated power three-phase active filter...

  15. Adsorption characteristics of activated carbon hollow fibers

    OpenAIRE

    2009-01-01

    Carbon hollow fibers were prepared with regenerated cellulose or polysulfone hollow fibers by chemical activation using sodium phosphate dibasic followed by the carbonization process. The activation process increases the adsorption properties of fibers which is more prominent for active carbone fibers obtained from the cellulose precursor. Chemical activation with sodium phosphate dibasic produces an active carbon material with both mesopores and micropores.

  16. Improvement of spread-out Bragg peak flatness for a carbon-ion beam by the use of a ridge filter with a ripple filter.

    Science.gov (United States)

    Hara, Yousuke; Takada, Yoshihisa; Hotta, Kenji; Tansho, Ryohei; Nihei, Tetsuya; Suzuki, Yojiro; Nagafuchi, Kosuke; Kawai, Ryuichi; Tanabe, Masaki; Mizutani, Shohei; Himukai, Takeshi; Matsufuji, Naruhiro

    2012-03-21

    We have developed a novel design method of ridge filters for carbon-ion therapy using a broad-beam delivery system to improve the flatness of a biologically effective dose in the spread-out Bragg peak (SOBP). So far, the flatness of the SOBP is limited to about ±5% for carbon beams since the weight control of component Bragg curves composing the SOBP is difficult. This difficulty arises from using a large number of ridge-bar steps (e.g. about 100 for a SOBP width of 60 mm) required to form the SOBP for the pristine Bragg curve with an extremely sharp distal falloff. Instead of using a single ridge filter, we introduce a ripple filter to broaden the Bragg peak so that the number of ridge-bar steps can be reduced to about 30 for SOBP with of 60 mm for the ridge filter designed for the broadened Bragg peak. Thus we can manufacture the ridge filter more accurately and then attain a better flatness of the SOBP due to well-controlled weights of the component Bragg curves. We placed the ripple filter on the same frame of the ridge filter and arranged the direction of the ripple-filter-bar array perpendicular to that of the ridge-filter-bar array. We applied this method to a 290 MeV u(-1) carbon-ion beam in Heavy Ion Medical Accelerator in Chiba and verified the effectiveness by measurements.

  17. Development of active porous medium filters based on plasma textiles

    Science.gov (United States)

    Kuznetsov, Ivan A.; Saveliev, Alexei V.; Rasipuram, Srinivasan; Kuznetsov, Andrey V.; Brown, Alan; Jasper, Warren

    2012-05-01

    Inexpensive, flexible, washable, and durable materials that serve as antimicrobial filters and self-decontaminating fabrics are needed to provide active protection to people in areas regularly exposed to various biohazards, such as hospitals and bio research labs working with pathogens. Airlines and cruise lines need such material to combat the spread of infections. In households these materials can be used in HVAC filters to fight indoor pollution, which is especially dangerous to people suffering from asthma. Efficient filtering materials are also required in areas contaminated by other types of hazardous dust particulates, such as nuclear dust. The primary idea that guided the undertaken study is that a microplasma-generating structure can be embedded in a textile fabric to generate a plasma sheath ("plasma shield") that kills bacterial agents coming in contact with the fabric. The research resulted in the development of a plasma textile that can be used for producing new types of self-decontaminating garments, fabrics, and filter materials, capable of activating a plasma sheath that would filter, capture, and destroy any bacteriological agent deposited on its surface. This new material relies on the unique antimicrobial and catalytic properties of cold (room temperature) plasma that is benign to people and does not cause thermal damage to many polymer textiles, such as Nomex and polypropylene. The uniqueness of cold plasma as a disinfecting agent lies in the inability of bacteria to develop resistance to plasma exposure, as they can for antibiotics. Plasma textiles could thus be utilized for microbial destruction in active antimicrobial filters (for continuous decontamination and disinfection of large amounts of air) as well as in self-decontaminating surfaces and antibacterial barriers (for example, for creating local antiseptic or sterile environments around wounds and burns).

  18. Development of active porous medium filters based on plasma textiles

    Energy Technology Data Exchange (ETDEWEB)

    Kuznetsov, Ivan A.; Saveliev, Alexei V.; Rasipuram, Srinivasan; Kuznetsov, Andrey V.; Brown, Alan; Jasper, Warren [Mechanical and Aerospace Engineering, North Carolina State University, Raleigh, NC 27695 (United States); Textile Engineering Chemistry and Science, North Carolina State University, Raleigh, NC 27695 (United States)

    2012-05-15

    Inexpensive, flexible, washable, and durable materials that serve as antimicrobial filters and self-decontaminating fabrics are needed to provide active protection to people in areas regularly exposed to various biohazards, such as hospitals and bio research labs working with pathogens. Airlines and cruise lines need such material to combat the spread of infections. In households these materials can be used in HVAC filters to fight indoor pollution, which is especially dangerous to people suffering from asthma. Efficient filtering materials are also required in areas contaminated by other types of hazardous dust particulates, such as nuclear dust. The primary idea that guided the undertaken study is that a microplasma-generating structure can be embedded in a textile fabric to generate a plasma sheath (''plasma shield'') that kills bacterial agents coming in contact with the fabric. The research resulted in the development of a plasma textile that can be used for producing new types of self-decontaminating garments, fabrics, and filter materials, capable of activating a plasma sheath that would filter, capture, and destroy any bacteriological agent deposited on its surface. This new material relies on the unique antimicrobial and catalytic properties of cold (room temperature) plasma that is benign to people and does not cause thermal damage to many polymer textiles, such as Nomex and polypropylene. The uniqueness of cold plasma as a disinfecting agent lies in the inability of bacteria to develop resistance to plasma exposure, as they can for antibiotics. Plasma textiles could thus be utilized for microbial destruction in active antimicrobial filters (for continuous decontamination and disinfection of large amounts of air) as well as in self-decontaminating surfaces and antibacterial barriers (for example, for creating local antiseptic or sterile environments around wounds and burns).

  19. High Frequency State-Variable Biquadratic Active Filters

    Directory of Open Access Journals (Sweden)

    T. Dostal

    1998-04-01

    Full Text Available The state-variable (KHN active RC biquadratic filters with good performance in high frequency range , flexibility of outputs (LP, HP, BP, low sensitivities in novel current and hybrid modes, using current conveyors, transimpedance, trans-admittance and current operational amplifiers, are given in this paper.

  20. Adaptive Compensation of Reactive Power With Shunt Active Power Filters

    DEFF Research Database (Denmark)

    Blaabjerg, Frede; Asiminoaei, Lucian; Hansen, Steffan;

    2008-01-01

    This paper describes an adaptive method for compensating the reactive power with an active power filter (APF), which is initially rated for mitigation of only the harmonic currents given by a nonlinear industrial load. It is proven that, if the harmonic currents do not load the APF at the rated...

  1. Application of Discontinuous PWM Modulation in Active Power Filters

    DEFF Research Database (Denmark)

    Blaabjerg, Frede; Asiminoaei, Lucian; Rodriguez, Pedro

    2008-01-01

    Classical discontinuous pulsewidth modulations (DPWMs) may not be efficiently applied in active power filters (APFs), because it is hard to predict the peak values of the inverter current, and consequently it is difficult to calculate the position of the clamped interval, that minimizes the switc...

  2. Multi-channel Kalman filters for active noise control

    NARCIS (Netherlands)

    Ophem, S. van; Berkhoff, A.P.

    2013-01-01

    By formulating the feed-forward broadband active noise control problem as a state estimation problem it is possible to achieve a faster rate of convergence than the filtered reference least mean squares algorithm and possibly also a better tracking performance. A multiple input/multiple output

  3. Multi-channel Kalman filters for active noise control

    NARCIS (Netherlands)

    van Ophem, S.; Berkhoff, Arthur P.

    By formulating the feed-forward broadband active noise control problem as a state estimation problem it is possible to achieve a faster rate of convergence than the filtered reference least mean squares algorithm and possibly also a better tracking performance. A multiple input/multiple output

  4. Monitoring active filters under automotive aging scenarios with embedded instrument

    NARCIS (Netherlands)

    Wan, Jinbo; Kerkhoff, Hans G.

    2012-01-01

    In automotive mixed-signal SoCs, the analogue/mixed-signal front-ends are of particular interest with regard to dependability. Because of the many electrical disturbances at the front-end, often (active) filters are being used. Due to the harsh environments, in some cases, degradation of these filte

  5. An Evaluation of Mass Absorption Cross-Section for Optical Carbon Analysis on Teflon Filter Media.

    Science.gov (United States)

    Presler-Jur, Paige; Doraiswamy, Prakash; Hammond, Oki; Rice, Joann

    2017-04-05

    Black carbon (BC) or elemental carbon (EC) is a by-product of incomplete fuel combustion, and contributes adversely to human health, visibility, and climate impacts. Previous studies have examined non-destructive techniques for particle light attenuation measurements on Teflon(®) filters to estimate BC. The incorporation of an inline Magee Scientific OT21 Transmissometer into the MTL AH-225 robotic weighing system provides the opportunity to perform optical transmission measurements on Teflon(®) filters at the same time as the gravimetric mass measurement. In this study, we characterize the performance of the inline OT21, and apply it to determine the mass absorption cross-section (MAC) of PM2.5 BC across the U.S. We analyzed 5393 archived Teflon(®) filters from the Chemical Speciation Network (CSN) collected during 2010-2011 and determined MAC by comparing light attenuation on Teflon(®) filters to corresponding thermal EC on quartz-fiber filters. Results demonstrated the importance of the initial transmission (I0) value used in light attenuation calculations. While light transmission varied greatly within filter lots, the average I0 of filter blanks during from the sampling period provided an estimate for archived filters. For newly collected samples, it is recommended that filter-specific I0 measurements be made (i.e., same filter before sample collection). The estimated MAC ranged from 6.9 to 9.4 m(2)/g that varied by region and season across the U.S., indicating that using a default value may lead to under- or over-estimated BC concentrations. An analysis of the chemical composition of these samples indicated good correlation with EC for samples with higher EC content as a fraction of total PM2.5 mass, while the presence of light scattering species such as crustal elements impacted the correlation affecting the MAC estimate. Overall, the method is demonstrated to be a quick, cost-effective approach to estimate BC from archived and newly sampled Teflon

  6. Higher-order chaotic oscillator using active bessel filter

    DEFF Research Database (Denmark)

    Lindberg, Erik; Mykolaitis, Gytis; Bumelien, Skaidra;

    2010-01-01

    A higher-order oscillator, including a nonlinear unit and an 8th-order low-pass active Bessel filter is described. The Bessel unit plays the role of "three-in-one": a delay line, an amplifier and a filter. Results of hardware experiments and numerical simulation are presented. Depending on the pa...... on the parameters of the nonlinear unit the oscillator operates either in a one-scroll or two-scroll mode. Two positive Lyapunov exponents, found at larger values of the negative slopes of the nonlinear function, characterize the oscillations as hyperchaotic....

  7. Self-commissioning notch filter for active damping in three phase LCL-filter based grid converters

    DEFF Research Database (Denmark)

    Alzola, Rafael Pena; Liserre, Marco; Blaabjerg, Frede;

    2013-01-01

    challenge the LCL-filter stability. Active damping by using a notch filter on the reference voltage for the modulator is simple to implement and does not require additional sensors. With the notch frequency tuned for the resonant frequency the voltage reference does not contain any component susceptible...... of exciting the LCL-filter. However, the notch filter tuning requires considerable design effort and the variations in the resonance frequency limit the LCL-filter robustness. This paper proposes a simple tuning procedure for the notch filter that results in proper robustness. In order to cope with the grid...... inductance variations it is proposed to estimate the resonance frequency by means of Fourier analysis. The Goertzel algorithm, instead of the FFT, is used to reduce the calculation and memory requirements. Thus, the proposed self-commissioning notch filter results robust and consumes little computational...

  8. Shunt Active and Series Active Filters-Based Power Quality Conditioner for Matrix Converter

    Directory of Open Access Journals (Sweden)

    P. Jeno Paul

    2011-01-01

    Full Text Available This paper proposes a series active filter and shunt active filter to minimize the power quality impact present in matrix converters instead of passive filter. A matrix converter produces significant harmonics and nonstandard frequency components into load. The proposed system compensates the sag and swell problems efficiently in matrix converter. The proposed system has been tested and validated on the matrix converter using MATLAB/Simulink software. Simulated results confirm that the active power filters can maintain high performance for matrix converter.

  9. ACTIVATED CARBON (CHARCOAL OBTAINING . APPLICATION

    Directory of Open Access Journals (Sweden)

    Florin CIOFU

    2015-05-01

    Full Text Available The activated carbon is a microporous sorbent with a very large adsorption area that can reach in some cases even 1500sqm / gram. Activated carbon is produced from any organic material with high carbon content: coal, wood, peat or moor coal, coconut shells. The granular activated charcoal is most commonly produced by grinding the raw material, adding a suitable binder to provide the desired hardness and shape. Enabling coal is a complete process through which the raw material is fully exposed to temperatures between 600-900 degrees C, in the absence of oxygen, usually in a domestic atmosphere as gases such as nitrogen or argon; as material that results from this process is exposed in an atmosphere of oxygen and steam at a temperature in the interval from 600 - 1200 degrees C.

  10. A review of DOE HEPA filter component test activities

    Energy Technology Data Exchange (ETDEWEB)

    Slawski, J.W.; Bresson, J.F. [Informatics Corp., Inc., Albuquerque, NM (United States); Scripsick, R.C. [Los Alamos National Lab., NM (United States)

    1997-08-01

    All HEPA filters purchased for installation in DOE nuclear facilities are required to be tested at a Filter Test Facility (FTF) prior to installation. The number of HEPA filters purchased by DOE has been reduced so much that the Hanford FTF was closed. From Fiscal Year (FY) 1992 to 1994, funding was not provided to the FTF Technical Support Group (TSG) at the Los Alamos National Laboratory. As a consequence, Round Robin Tests (RRTs), performed twice each year by the FTFs to assess constituency of test results among the FTFs, were not performed in FY 1992 and FY 1993. The Annual Reports of FTF test activities were not prepared for FY 1992 - 1995. Technical support provided to the FTFs was minimal. There is talk of closing a second FTF, and ongoing discussions as to whether DOE will continue to fund operation of the FTFs. In FY 1994, DOE Defense Programs commenced funding the TSG. RRT data for FY 1994 and 1995 have been entered into the database; the FY 1994 RRT report has been issued; and the FY 1995 RRT report is in progress. Data from semiannual reports have been retrieved and entered into the database. Standards related to HEPA filter test and procurement activities are now scheduled for issuance by FY 1996. Continuation of these activities depends on whether DOE will continue to support the HEPA filter test program. The history and activities of the FTFs and the TSG at Los Alamos have been reported at previous Air Cleaning Conferences. Data from the FY 1991 Annual Report of FTF activities was presented at the 1992 Air Cleaning Conference. Preparation of the Annual Reports was temporarily suspended in 1992. However, all of the FTF Semiannual report data have been retrieved and entered into the data base. This paper focuses primarily on the results of HEPA filter tests conducted by FTFs during FY 1992 - FY 1995, and the possible effects of the DOE program uncertainties on the quality of HEPA filters for installation at the DOE sites. 15 refs., 13 tabs.

  11. An active trap filter for high-power voltage source converters

    DEFF Research Database (Denmark)

    Bai, Haofeng; Wang, Xiongfei; Loh, Poh Chiang;

    2015-01-01

    This paper proposes a power electronic based device to actively trap the switching current ripples for highpower converters. Control principle and system design of the active trap filter are discussed first. Comparisons of the active trap filter with LCL and LLCL filters are then carried out...... in time-domain simulations and experimental tests. The results demonstrate that the active trap filter not only provides more controllability and flexibility than the passive filters, but also mitigates the adverse effects of parameter shifts on harmonic filtering performance of passive filters....

  12. PROGRESS ON ACTIVATED CARBON FIBERS

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Activated carbon fiber is one kind of important adsorption materials. These novel fibrousadsorbents have high specific surface areas or abundant functional groups, which make them havegreater adsorption/desorption rates and larger adsorption capacities than other adsorbents. They canbe prepared as bundle, paper, cloth and felt to meet various technical requirement. They also showreduction property. In this paper the latest progress on the studies of the preparation and adsorptionproperties of activated carbon fibers is reviewed. The application of these materials in drinking waterpurification, environmental control, resource recovery, chemical industry, and in medicine and healthcare is also presented.

  13. A new shunt DC active filter of power supply in a steady high magnetic field facility

    Institute of Scientific and Technical Information of China (English)

    WANG Lei; LIU Xiao-Ning; WANG Can

    2011-01-01

    A DC active power filter is an indispensable part in a high power and high stability power supply system, especially in the power supply system of the Steady High Magnetic Field Facility, which requires that the current ripple should be limited to 50 parts per million. In view of the disadvantages of the series DC active power filter and shunt Pulse Width Modulation DC active filter, this paper puts forward a novel DC active filter by combining the advantages of the transistor regulator and the shunt type. The structure and principle of the new shunt linear active filter are introduced. Meanwhile, the design of several key components that construct the new shunt linear active filter is also analyzed. The simulation model and an experimental prototype of the shunt linear active filter are developed, and the results verify that the parameter design is reasonable and the shunt active filter has a good filter effect.

  14. Determination of ultraviolet filter activity on coconut oil cosmetic cream

    Science.gov (United States)

    Widiyati, Eni

    2017-08-01

    A research on determination of ultraviolet (UV) filter activity of cosmetic cream with coconut oil as raw material has been done. The cream was made by mixing the oil phase (coconut oil, stearic acid, lanolin and cetyl alcohol) at 70°C and the water phase (glycerin, aquadest and triethanolamine) at 70°C, while stirring until reached a temperature of 35°C. It was made also a cream with inorganic sunscreen TiO2 and organic sunscreen benzophenone-3 as a comparison. To study the UV filter activity, each cream was determined the UV absorption using UV spectrophotometer. The results show that cosmetic cream with coconut oil as raw material absorbs UV rays in the region of UV-C, whereas the cream with TiO2 absorbs the UV rays from UV-C to UV-A and cream with benzophenone-3 absorbs the UV rays from UV-B to UV-A region. This means that, the cosmetic cream with coconut oil as raw material has an activity as UV-C filter. If this cream is expected to have an activity as a sunscreen, it must be added an inorganic or organic sunscreen or a mixture of both as an active materials.

  15. Physicochemical and sensory changes in aged sugarcane spirit submitted to filtering with activated carbon filter Alterações físico-químicas e sensoriais de cachaças envelhecidas submetidas à filtragem com carvão ativado

    Directory of Open Access Journals (Sweden)

    Felipe Cimino Duarte

    2012-09-01

    Full Text Available Sugarcane spirit is a drink considered as a national symbol of Brazil. It is produced by large producers and by about 30 thousand small and medium home-distilling producers dispersed throughout the country. The copper originating from the home-distillers can become a serious problem since at high concentrations in beverages it may cause serious human health problems. Therefore, the objective of this study was to investigate the influence of the activated carbon used in commercial filters on the physicochemical and sensory characteristics of aged sugarcane spirit. Analyses of copper, dry extract, alcoholic degree, higher alcohols, volatile acids, aldehydes, esters, furfural, and methanol were performed. The sensory evaluation was performed by seven selected trained judges, who analyzed the yellow color, woody aroma and flavor, and intensity of alcoholic aroma and flavor of the cane spirit before and after the filtration process. The sensory tests were carried out using a 9 cm non-structured intensity scale. A reduction was observed in all compounds analyzed physicochemically, except for the esters, which increased after filtration. This increase is probably due to the esterification of the alcohols and acids present. According to the sensory results obtained, a reduction was observed in the intensity of the yellow color, aroma, and wood flavor characteristics, the major characteristics of the aging process.A cachaça é uma bebida considerada símbolo nacional, sendo produzida por grandes produtores e por cerca de 30 mil pequenos e médios produtores de alambiques artesanais espalhados por todo o País. O cobre oriundo dos destiladores dos alambiques artesanais pode tornar-se um grande problema, pois esse metal, em grandes concentrações na bebida, acarreta sérios problemas à saúde humana. Desta forma, objetivou-se estudar a influência da filtragem em carvão utilizado nos filtros comerciais sobre as características físico-químicas e

  16. ACTIVATION ENERGY OF DESORPTION OF DIBENZOFURAN ON ACTIVATED CARBONS

    Institute of Scientific and Technical Information of China (English)

    LI Xiang; LI Zhong; XI Hongxia; LUO Lingai

    2004-01-01

    Three kinds of commercial activated carbons, such as Norit RB1, Monolith and Chemviron activated carbons, were used as adsorbents for adsorption of dibenzofuran. The average pore size and specific surface area of these activated carbons were measured. Temperature Programmed Desorption (TPD) experiments were conducted to measure the TPD curves of dibenzofuran on the activated carbons, and then the activation energy for desorption of dibenzofuran on the activated carbons was estimated. The results showed that the Chemviron and the Norit RB1 activated carbon maintained higher specific surface area and larger micropore pore volume in comparison with the Monolith activated carbon, and the activation energy for the desorption of dibenzofuran on these two activated carbons was higher than that on the Monolith activated carbon. The smaller the pore of the activated carbon was, the higher the activated energy of dibenzofuran desorption was.

  17. Self-filtering oscillations in carbon nanotube hetero-junctions.

    Science.gov (United States)

    Scarpa, F; Narojczyk, J W; Wojciechowski, K W; Inman, D J

    2011-11-18

    We evaluate the vibrational properties of single-wall carbon nanotube (SWCNT) hetero-junction (HJ) oscillators using a hybrid atomistic-continuum approach validated by molecular mechanics/molecular dynamics simulations. The SWCNT-HJs show a broken symmetry topology of their mode shapes, with striction effects caused on the bending and radial modes by the combined effect of the HJ and the tube with the thinner radius. The single-wall nanotube HJs also show selective mass sensing properties based solely on the geometry and type of the boundary conditions of the specific nanostructure. This unusual behaviour has not been observed so far in classical SWCNT systems.

  18. Research on the filtering characteristic of single phase series hybrid active power filter based on fundamental magnetic flux compensation

    Science.gov (United States)

    Tian, Jun; Chen, Qiaofu; Zhang, Yuqi

    2012-12-01

    In this article, the PWM inverter works as a controlled fundamental current source in the single phase series hybrid active power filter (APF) based on fundamental magnetic flux compensation (FMFC). The series transformer can exhibit the self-impedance of primary winding to harmonic current, which forces harmonic current to flow into passive power filter. With the influence of harmonic current, the voltage of primary winding of transformer is a harmonic voltage, which makes the inverter output currents have a certain harmonic component, and it degrades the filtering characteristics. On the basis of PWM inverter, the mathematical model of series hybrid APF is established, and the filtering characteristics of single phase APF are analysed in detail. Three methods are gained to improve filtering characteristics: reasonably designing the inverter output filter inductance, increasing series transformer ratio and adopting voltage feed-forward control. Experimental results show that the proposed APF has greater validity.

  19. 'Active' filters for upgrading phosphorus removal from pond systems.

    Science.gov (United States)

    Shilton, A; Pratt, S; Drizo, A; Mahmood, B; Banker, S; Billings, L; Glenny, S; Luo, D

    2005-01-01

    This paper investigates limestone and iron slag filters as an upgrade option for phosphorus removal from wastewater treatment ponds. A review of 'active' filter technology and the results from laboratory and field research using packed columns of the different media is presented. It is shown that both limestone and iron slag can remove phosphorus but highlights that different types of limestone give markedly different performance. Filter performance appears to be improved by increasing temperature and by the presence of algae, presumably because of its tendency to elevate pH. Performance is related to hydraulic retention time (HRT), but this relationship is not linear, particularly at low HRTs. Importantly for future research, the results from field-testing with pond effluent show significant differences compared to those obtained when using a synthetic feed in the laboratory. For the iron slag filter, higher performance was observed in the field (72% in field vs. 27% in laboratory, at a 12 hour-HRT), while the opposite was observed for the limestone (64% in laboratory vs. 18% in field, at a 12-hour HRT).

  20. Active Finger Recognition from Surface EMG Signal Using Bayesian Filter

    Science.gov (United States)

    Araki, Nozomu; Hoashi, Yuki; Konishi, Yasuo; Mabuchi, Kunihiko; Ishigaki, Hiroyuki

    This paper proposed an active finger recognition method using Bayesian filter in order to control a myoelectric hand. We have previously proposed a finger joint angle estimation method based on measured surface electromyography (EMG) signals and a linear model. However, when we estimate 2 or more finger angles by this estimation method, the estimation angle of the inactive finger is not accurate. This is caused by interference of surface EMG signal. To solve this interference problem, we proposed active finger recognition method from the amplitude spectrum of surface EMG signal using Bayesian filter. To confirm the effectiveness of this recognition method, we developed a myoelectric hand simulator that implements proposed recognition algorithm and carried out real-time recognition experiment.

  1. A Technique for Shunt Active Filter meld micro grid System

    Directory of Open Access Journals (Sweden)

    A. Lumani

    2015-08-01

    Full Text Available The proposed system presents a control technique for a micro grid connected hybrid generation system ith case study interfaced with a three phase shunt active filter to suppress the current harmonics and reactive power present in the load using PQ Theory with ANN controller. This Hybrid Micro Grid is developed using freely renewable energy resources like Solar Photovoltaic (SPV and Wind Energy (WE. To extract the maximum available power from PV panels and wind turbines, Maximum power point Tracker (MPPT has been included. This MPPT uses the “Standard Perturbs and Observe” technique. By using PQ Theory with ANN Controller, the Reference currents are generated which are to be injected by Shunt active power filter (SAPFto compensate the current harmonics in the non linear load. Simulation studies shows that the proposed control technique performs non-linear load current harmonic compensation maintaining the load current in phase with the source voltage.\\

  2. Design and Simulation of a Shunt Active Filter in Application for Control of Harmonic Levels

    CERN Document Server

    Adrian, Gligor

    2010-01-01

    Nowadays, the active filters represent a viable alternative for controlling harmonic levels in industrial consumers electrical installations. It must be noted the availability of many different types of filter configurations that can be used but there is no standard method for rating the active filters. This paper focuses on describing the shunt active filter structure and design. The theoretical concepts underlying the design of shunt active filters are presented. To validate and highlight the performance of shunt active filters a Matlab-Simulink model was developed. Simulation results are also presented.

  3. Removal of virus and toxin using heatable multi-walled carbon nanotube web filters

    Directory of Open Access Journals (Sweden)

    Hoon-Sik Jang

    2016-02-01

    Full Text Available Many studies have used a carbon nanotube (CNT filter for pathogen removal and/or inactivation by means of electrochemical or electrochlorination. The large surface area, fine pore size and high electrical and thermal conductivity of CNTs make them suitable and distinct to use for the filtering and removal of pathogens. Here, we grew spin-capable multi-walled CNTs (MWCNTs and manufactured a web filter using the spun MWCNTs. Botulinum toxin type E light chain (BoT/E-LC and vaccinia virus (VV were filtered using the MWCNT web filters and were evaporated and removed by applying direct current (DC voltage to both sides of the MWCNT webs, excluding electrochemical or electrochlorination. The filtering and removal of BoT/E-LC and VV were performed after seven layers of the MWCNT sheets were coated onto a silicon oxide porous plate. The electrical resistance of the webs in the seven layer sheet was 293 Ω. The temperature of MWCNTs webs was linearly increased to ∼300 °C at 210 V of DC voltage. This temperature was enough to remove BoT/E-LC and VV. From the SEM and XPS results, we confirmed that BoT/E-LC and VV on the MWCNT webs were almost removed by applying a DC voltage and that some element (N, Na, Cl, etc. as residues on the MWCNT webs remained.

  4. Photoconductivity of Activated Carbon Fibers

    Science.gov (United States)

    Kuriyama, K.; Dresselhaus, M. S.

    1990-08-01

    The photoconductivity is measured on a high-surface-area disordered carbon material, namely activated carbon fibers, to investigate their electronic properties. Measurements of decay time, recombination kinetics and temperature dependence of the photoconductivity generally reflect the electronic properties of a material. The material studied in this paper is a highly disordered carbon derived from a phenolic precursor, having a huge specific surface area of 1000--2000m{sup 2}/g. Our preliminary thermopower measurements suggest that this carbon material is a p-type semiconductor with an amorphous-like microstructure. The intrinsic electrical conductivity, on the order of 20S/cm at room temperature, increases with increasing temperature in the range 30--290K. In contrast with the intrinsic conductivity, the photoconductivity in vacuum decreases with increasing temperature. The recombination kinetics changes from a monomolecular process at room temperature to a biomolecular process at low temperatures. The observed decay time of the photoconductivity is {approx equal}0.3sec. The magnitude of the photoconductive signal was reduced by a factor of ten when the sample was exposed to air. The intrinsic carrier density and the activation energy for conduction are estimated to be {approx equal}10{sup 21}/cm{sup 3} and {approx equal}20meV, respectively. The majority of the induced photocarriers and of the intrinsic carriers are trapped, resulting in the long decay time of the photoconductivity and the positive temperature dependence of the conductivity.

  5. Methane adsorption on activated carbon

    OpenAIRE

    Perl, Andras; Koopman, Folkert; Jansen, Peter; Rooij, Marietta de; Gemert, Wim van

    2014-01-01

    Methane storage in adsorbed form is a promising way to effectively and safely store fuel for vehicular transportation or for any other potential application. In a solid adsorbent, nanometer wide pores can trap methane by van der Waals forces as high density fluid at low pressure and room temperature. This provides the suitable technology to replace bulky and expensive cylindrical compressed natural gas tanks. Activated carbons with large surface area and high porosity are particularly suitabl...

  6. Minimizing activated carbons production cost

    Energy Technology Data Exchange (ETDEWEB)

    Stavropoulos, G.G.; Zabaniotou, A.A. [Department of Chemical Engineering, Aristotle University of Thessaloniki, Univ. P. O. Box 1520, 54006, Thessaloniki (Greece)

    2009-07-15

    A detailed economic evaluation of activated carbons production process from various raw materials is undertaken using the conventional economic indices (ROI, POT, and NPV). The fundamental factors that affect production cost were taken into account. It is concluded that for an attractive investment in activated carbons production one should select the raw material with the highest product yield, adopt a chemical activation production scheme and should base product price on product-surface area (or more generally on product adsorption capacity for the adsorbate in consideration). A raw material that well meets the above-mentioned criteria is petroleum coke but others are also promising (charcoals, and carbon black). Production cost then can be optimized by determining its minimum value of cost that results from the intercept between the curves of plant capacity and raw material cost - if any. Taking into account the complexity of such a techno-economic analysis, a useful suggestion could be to start the evaluations from a plant capacity corresponding to the break-even point, i. e. the capacity at which income equals production cost. (author)

  7. Catalytic NiO Filter Supported on Carbon Fiber for Oxidation of Volatile Organic Compounds

    Energy Technology Data Exchange (ETDEWEB)

    Sim, Jong Ki; Seo, Hyun Ook; Jeong, Myunggeun; Kim, Kwangdae; Kim, Young Dok [Sungkyunkwan Univ., Suwon (Korea, Republic of); Lim, Dong Chan [Korea Institute of Materials Science, Changwon (Korea, Republic of)

    2013-07-15

    Carbon-fiber-supported NiO catalytic filters for oxidation of volatile organic compounds were prepared by electroless Ni-P plating and subsequent annealing processes. Surface structure and crystallinity of NiO film on carbon fiber could be modified by post-annealing at different temperatures (500 and 650 .deg. C). Catalytic thermal decompositions of toluene over these catalytic filters were investigated. 500 .deg. C-annealed sample showed a higher catalytic reactivity toward toluene decomposition than 650 .deg. C-annealed one under same conditions, despite of its lower surface area and toluene adsorption capacity. X-ray diffraction and X-ray photoelectron spectroscopy studies suggest that amorphous structures of NiO on 500 .deg. C-annealed catalyst caused the higher reactivity for oxidation of toluene than that of 650 .deg. C-annealed sample with a higher crystallinity.

  8. PWM-Statcom system additionally having active filter function

    Energy Technology Data Exchange (ETDEWEB)

    Matsui, K.; Kojima, H.; Yamamoto, I.; Hasegawa, M. [Chubu Univ., Kasugai Aichi (Japan); Ando, K. [Nitto Kogyo Corp., Nagakute, Aichi (Japan)

    2006-07-01

    The harmonic characteristics of static synchronous compensators (Statcom) were discussed with particular reference to the difference between symmetrical and asymmetrical modulation strategies that influence a quality of output waveform. The asymmetrical modulation strategy is the better approach in higher power factor applications such as alternating current (AC) motor drives. It was noted that in cases requiring a passive filter with a very large scale Statcom, a symmetrical modulation strategy is superior. Therefore, in this study, a symmetrical modulation was preferred for a neutral point clamped (NPC) pulse width modulation (PWM) inverter. Due to switching in a limited narrow frequency band, such output harmonics can be eliminated using a simple passive filter and harmonics such as the fifth and the seventh, can be suppressed using the proposed Statcom scheme in which the feedback signals for the fifth and seventh harmonics are injected into the Statcom. Using these feedback signals, the harmonics in the power system were significantly reduced. This result was also confirmed by simulation. It was concluded that, in addition to the proper operation of the Statcom, it is possible to perform an active filtering function . 10 refs., 1 tab., 9 figs.

  9. Simulations of phenol adsorption on activated carbon and carbon black

    OpenAIRE

    Prosenjak, Claudia; Valente Nabais, Joao; Laginhas, Carlos; Carrott, Peter; Carrott, Manuela

    2010-01-01

    We use grand canonical Monte Carlo and molecular dynamics simulations to study the adsorption of phenol on carbon materials. Activated carbon is modelled by pore size distributions based on DFT methods; carbon black is represented by a single carbon slab with varying percentages of surface atoms removed. GCMC results for the adsorption from the corresponding gas phase gave reasonable agreement with experimental adsorption results. MD simulations, that studied the influence of the presence of ...

  10. T Source Inverter Based Shunt Active Filter with LCL Passive Filter for the 415V 50 Hz Distribution systems

    Directory of Open Access Journals (Sweden)

    S. Sellakumar

    2015-06-01

    Full Text Available The inverter topology is being used as an active filter to reduce the harmonics in the power system [1]. The traditional voltage source or current source inverters are having the disadvantages of limited output voltage range hence it may not be able to supply enough compensating currents during heavy switching surges, Vulnerable to EMI noise and the devices gets damaged in either open or short circuit conditions and the main switching device of VSI and CSI are not interchangeable. The active filters are the type of DC-AC system with wide range of voltage regulation and integration of energy storages is often required. This cannot be achieved with conventional inverters and hence the impedance source inverters have been suggested. The T source inverters are basically impedance source inverters which can be used as an active filter in the power system. The MATLAB simulation is done and the results are discussed in this paper for both the types. The proposed dampening system is fully characterized by LCL based passive filters [6] and T source inverter based shunt active filter. The disturbances in the supply voltage and load current due to the non linear loads are observed in the simulation. The same is studied after connecting the designed hybrid shunt active filter in the distribution system. The simulation results obtained from the proposed method proves that it gives comparatively better THD value.

  11. Effect of substrate bias in nitrogen incorporated amorphous carbon films with embedded nanoparticles deposited by filtered cathodic jet carbon arc technique

    Energy Technology Data Exchange (ETDEWEB)

    Panwar, O.S., E-mail: ospanwar@mail.nplindia.ernet.in [Amorphous and Microcrystalline Silicon Solar Cell Group, Physics of Energy Harvesting Division, National Physical Laboratory (C.S.I.R.), Dr. K.S. Krishnan Road, New Delhi-110012 (India); Kumar, Sushil; Ishpal,; Srivastava, A.K.; Chouksey, Abhilasha; Tripathi, R.K.; Basu, A. [Amorphous and Microcrystalline Silicon Solar Cell Group, Physics of Energy Harvesting Division, National Physical Laboratory (C.S.I.R.), Dr. K.S. Krishnan Road, New Delhi-110012 (India)

    2012-02-15

    Highlights: Black-Right-Pointing-Pointer a-C: N films having nanoparticles were deposited by filtered cathodic jet carbon arc (FCJCA) technique. Black-Right-Pointing-Pointer The effect of negative substrate bias on the properties of a-C: N films embedded with nanoparticles have been studied. Black-Right-Pointing-Pointer The properties of a-C: N films deposited by FCJCA technique have been compared with ta-C: N films deposited by FCVA process. - Abstract: The properties of nitrogen incorporated amorphous carbon (a-C: N) films with embedded nanoparticles, deposited using a filtered cathodic jet carbon arc technique, are reported. X-ray diffraction, high resolution transmission electron microscope and Raman spectroscopy measurements reveal an amorphous structure, but on closer examination the presence of clusters of nanocarbon single crystals with d-spacing close to diamond cubic-phase have also been identified. The effect of substrate bias on the microstructure, conductivity, activation energy, optical band gap, optical constants, residual stress, hardness, elastic modulus, plastic index parameter, percentage elastic recovery and density of states of a-C: N films have been studied and the properties obtained are found to depend on the substrate bias.

  12. Brillouin optical reflectometer with a Brillouin active filter

    Science.gov (United States)

    Budylin, G. S.; Gorshkov, B. G.; Gorshkov, G. B.; Zhukov, K. M.; Paramonov, V. M.; Simikin, D. E.

    2017-07-01

    A new scheme of a fibre-optic Brillouin reflectometer is experimentally studied, in which the spectral line of spontaneous Brillouin scattering is selected by an active Brillouin filter represented by the tested fibre itself. To improve the reflectometer characteristics, a cyclic code and Raman amplification of the scattering signal are applied. With an averaging time of 5 min, scanning of 25 km of fibre with a spatial resolution of 4 m and a sampling resolution of 1 m are provided. The root-mean-square deviation in determining the Brillouin frequency is less than 1.1 MHz. The reflectometer sensitivity is evaluated with respect to the temperature changes and mechanical deformation.

  13. Polanyi Evaluation of Adsorptive Capacities of Commercial Activated Carbons

    Science.gov (United States)

    Monje, Oscar; Surma, Jan M.

    2017-01-01

    Commercial activated carbons from Calgon (207C and OVC) and Cabot Norit (RB2 and GCA 48) were evaluated for use in spacecraft trace contaminant control filters. The Polanyi potential plots of the activated carbons were compared using to those of Barnebey-Cheney Type BD, an untreated activated carbon with similar properties as the acid-treated Barnebey-Sutcliffe Type 3032 utilized in the TCCS. Their adsorptive capacities under dry conditions were measured in a closed loop system and the sorbents were ranked for their ability to remove common VOCs found in spacecraft cabin air. This comparison suggests that these sorbents can be ranked as GCA 48 207C, OVC RB2 for the compounds evaluated.

  14. Design of activated carbon/activated carbon asymmetric capacitors

    Directory of Open Access Journals (Sweden)

    Isabel ePiñeiro-Prado

    2016-03-01

    Full Text Available Supercapacitors are energy storage devices that offer a high power density and a low energy density in comparison with batteries. Their limited energy density can be overcome by using asymmetric configuration in mass electrodes, where each electrode works within their maximum available potential window, rendering the maximum voltage output of the system. Such asymmetric capacitors must be optimized through careful electrochemical characterization of the electrodes for accurate determination of the capacitance and the potential stability limits. The results of the characterization are then used for optimizing mass ratio of the electrodes from the balance of stored charge. The reliability of the design largely depends on the approach taken for the electrochemical characterization. Therefore, the performance could be lower than expected and even the system could break down, if a well thought out procedure is not followed.In this work, a procedure for the development of asymmetric supercapacitors based on activated carbons is detailed. Three activated carbon materials with different textural properties and surface chemistry have been systematically characterized in neutral aqueous electrolyte. The asymmetric configuration of the masses of both electrodes in the supercapacitor has allowed to cover a higher potential window, resulting in an increase of the energy density of the three devices studied when compared with the symmetric systems, and an improved cycle life.

  15. Design of activated carbon/activated carbon asymmetric capacitors

    Science.gov (United States)

    Piñeiro-Prado, Isabel; Salinas-Torres, David; Ruiz Rosas, Ramiro; Morallon, Emilia; Cazorla-Amoros, Diego

    2016-03-01

    Supercapacitors are energy storage devices that offer a high power density and a low energy density in comparison with batteries. Their limited energy density can be overcome by using asymmetric configuration in mass electrodes, where each electrode works within their maximum available potential window, rendering the maximum voltage output of the system. Such asymmetric capacitors must be optimized through careful electrochemical characterization of the electrodes for accurate determination of the capacitance and the potential stability limits. The results of the characterization are then used for optimizing mass ratio of the electrodes from the balance of stored charge. The reliability of the design largely depends on the approach taken for the electrochemical characterization. Therefore, the performance could be lower than expected and even the system could break down, if a well thought out procedure is not followed. In this work, a procedure for the development of asymmetric supercapacitors based on activated carbons is detailed. Three activated carbon materials with different textural properties and surface chemistry have been systematically characterized in neutral aqueous electrolyte. The asymmetric configuration of the masses of both electrodes in the supercapacitor has allowed to cover a higher potential window, resulting in an increase of the energy density of the three devices studied when compared with the symmetric systems, and an improved cycle life.

  16. The Power Quality Compensation Strategy for Power Distribution System Based on Hybrid Parallel Active Power Filters

    Directory of Open Access Journals (Sweden)

    Rachid DEHINI

    2010-12-01

    Full Text Available In this paper, the main aim is to confront the performance of shunt active power filter (SAPF and the shunt hybrid active power filter (SHAPF to achieve flexibility and reliability of the filter devices. Both of the two devices used the classical proportional-integral controller for pulse generation to trigger the inventers MOSFET’s. In the adopted hybrid active filter there is a passive power filter with high power rating to filter the low order harmonies and one active filter with low power rating to filter the other high order harmonies. In order to investigate the effectiveness of (SHAPF, the studies have been accomplished using simulation with the MATLAB-SIMULINK. The results show That (SHAPF is more effective than (SAPF, and has lower cost.

  17. Biquadratic Filter Applications Using a Fully-Differential Active-Only Integrator

    Directory of Open Access Journals (Sweden)

    H. A. Yildiz

    2013-04-01

    Full Text Available A new class of active filters, real active-only filters is described and possible implementation issues of these filters are discussed. To remedy these issues, a fully-differential active-only integrator block built around current controlled current conveyors is presented. The integration frequency of the proposed circuit is adjustable over a wide frequency range. As an application, a real active-only filter based on the classical two-integrator loop topology is presented and designed. The feasibility of this filter in a 0.35µm CMOS process is verified through SPECTRE simulation program in the CADENCE design tool.

  18. Linear polymer separation using carbon-nanotube-modified centrifugal filter units.

    Science.gov (United States)

    Krawczyk, Tomasz; Marian, Karolina; Pawlyta, Mirosława

    2016-02-01

    The separation of linear polymers such as polysaccharides and polyethylene glycol was performed with modified commercial centrifugal filter units. The deposition of a 0.16-0.35 μm layer of modified carbon nanotubes prevented permeation of linear polymers of molecular weight higher than 20 000 Da through the membrane. It allowed facile purification of solution of 0.1 g of polymer samples from small molecules within 25 min by using a bench-top centrifuge. The structure of modified carbon nanotubes was optimized in order to achieve good adhesion to the low binding regenerated cellulose surface and low solubility in aqueous solutions after deposition. The best modification of carbon nanotubes was oxidation and subsequent amide formation of diethanolamine. Introduction of acetic acid groups using sodium chloroacetate worked equally well. The modified filter could be used multiple times without the decrease of the efficiency. The carbon nanotubes layer was stable in aqueous solutions in a pH range of 1-7. The proposed method provides a convenient way of purification of modified polymers in research areas such as drug delivery or macromolecular probes synthesis.

  19. Estimates of increased black carbon emissions from electrostatic precipitators during powdered activated carbon injection for mercury emissions control.

    Science.gov (United States)

    Clack, Herek L

    2012-07-03

    The behavior of mercury sorbents within electrostatic precipitators (ESPs) is not well-understood, despite a decade or more of full-scale testing. Recent laboratory results suggest that powdered activated carbon exhibits somewhat different collection behavior than fly ash in an ESP and particulate filters located at the outlet of ESPs have shown evidence of powdered activated carbon penetration during full-scale tests of sorbent injection for mercury emissions control. The present analysis considers a range of assumed differential ESP collection efficiencies for powdered activated carbon as compared to fly ash. Estimated emission rates of submicrometer powdered activated carbon are compared to estimated emission rates of particulate carbon on submicrometer fly ash, each corresponding to its respective collection efficiency. To the extent that any emitted powdered activated carbon exhibits size and optical characteristics similar to black carbon, such emissions could effectively constitute an increase in black carbon emissions from coal-based stationary power generation. The results reveal that even for the low injection rates associated with chemically impregnated carbons, submicrometer particulate carbon emissions can easily double if the submicrometer fraction of the native fly ash has a low carbon content. Increasing sorbent injection rates, larger collection efficiency differentials as compared to fly ash, and decreasing sorbent particle size all lead to increases in the estimated submicrometer particulate carbon emissions.

  20. Energy-filtered transmission electron microscopy of biological samples on highly transparent carbon nanomembranes

    CERN Document Server

    Rhinow, Daniel; Weber, Nils-Eike; Beyer, André; Gölzhäuser, Armin; Kühlbrandt, Werner; Hampp, Norbert; Turchanin, Andrey; 10.1016/j.ultramic.2011.01.028

    2011-01-01

    Ultrathin carbon nanomembranes (CNM) comprising crosslinked biphenyl precursors have been tested as support films for energy-filtered transmission electron microscopy (EFTEM) of biological specimens. Due to their high transparency CNM are ideal substrates for electron energy loss spectroscopy (EELS) and electron spectroscopic imaging (ESI) of stained and unstained biological samples. Virtually background-free elemental maps of tobacco mosaic virus (TMV) and ferritin have been obtained from samples supported by ~ 1 nm thin CNM. Furthermore, we have tested conductive carbon nanomembranes (cCNM) comprising nanocrystalline graphene, obtained by thermal treatment of CNM, as supports for cryoEM of ice-embedded biological samples. We imaged ice-embedded TMV on cCNM and compared the results with images of ice-embedded TMV on conventional carbon film (CC), thus analyzing the gain in contrast for TMV on cCNM in a quantitative manner. In addition we have developed a method for the preparation of vitrified specimens, sus...

  1. Preparation and investigation of diamond-like carbon stripper foils by filtered cathodic vacuum arc

    Energy Technology Data Exchange (ETDEWEB)

    Fan, Qiwen, E-mail: fanqiwen0926@163.com [Department of Nuclear Physics, China Institute of Atomic Energy, P.O. Box 275(62), Beijing 102413 (China); Du, Yinghui; Zhang, Rong; Xu, Guoji [Department of Nuclear Physics, China Institute of Atomic Energy, P.O. Box 275(62), Beijing 102413 (China)

    2013-04-21

    Thin diamond-like carbon (DLC) stripper foils ∼5μg/cm{sup 2} in thickness were produced and evaluated as heavy-ion strippers for the Beijing HI-13 Tandem Accelerator. The DLC layers ∼4μg/cm{sup 2} in thickness were produced by the filtered cathodic vacuum arc technology onto glass slides coated with betaine–saccharose as releasing agent, which were previously covered with evaporated carbon layers ∼1μg/cm{sup 2} in thickness by the controlled ac arc-discharge method. Irradiation lifetimes of the DLC stripper foils were tested using the heavy-ion beams at the terminal of the Beijing HI-13 Tandem Accelerator, and compared with those of the standard carbon stripper foils made by the combined dc and ac arc-discharge method. The measurements indicate that the DLC stripper foils outlast the standard combined dc and ac arc-discharge carbon stripper foils by a factor of at least 13 and 4 for the {sup 197}Au{sup −} (∼9MeV, ∼1μA) and {sup 63}Cu{sup −} (∼9MeV, ∼1μA) ion beams, respectively. The structure and properties of the DLC foils deposited onto silicon substrates by the filtered cathodic vacuum arc technology were also evaluated and analyzed by scanning electron microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy. The scanning electron microscopy images show that the DLC foils contain hardly droplets through the double 90° filters. The X-ray photoelectron spectrum indicates that sp{sup 3} bonds of the DLC foils exceed 70%. The integral intensity ratio of the D peak to the G peak (I{sub D}/I{sub G}) measured by the Raman spectroscopy is 0.78.

  2. Estimating particulate black carbon concentrations using two offline light absorption methods applied to four types of filter media

    Science.gov (United States)

    Davy, Pamela M.; Tremper, Anja H.; Nicolosi, Eleonora M. G.; Quincey, Paul; Fuller, Gary W.

    2017-03-01

    Atmospheric particulate black carbon has been linked to adverse health outcomes. Additional black carbon measurements would aid a better understanding of population exposure in epidemiological studies as well as the success, or otherwise, of relevant abatement technologies and policies. Two light absorption measurement methods of particles collected on filters have been applied to four different types of filters to provide estimations of particulate black carbon concentrations. The ratio of transmittance (lnI0/I) to reflectance (lnR0/R) varied by filter type and ranged from close to 0.5 (as expected from simple theory) to 1.35 between the four filter types tested. The relationship between light absorption and black carbon, measured by the thermal EC(TOT) method, was nonlinear and differed between filter type and measurement method. This is particularly relevant to epidemiological studies that use light absorption as an exposure metric. An extensive archive of filters was used to derive loading factors and mass extinction coefficients for each filter type. Particulate black carbon time series were then calculated at locations where such measurements were not previously available. When applied to two roads in London, black carbon concentrations were found to have increased between 2011 and 2013, by 0.3 (CI: -0.1, 0.5) and 0.4 (CI: 0.1, 0.9) μg m-3 year-1, in contrast to the expectation from exhaust abatement policies. New opportunities using archived or bespoke filter collections for studies on the health effects of black carbon and the efficacy of abatement strategies are created.

  3. Experimental Investigation of a Cryogenic Filter for Separating Solid Carbon Dioxide Particles from Liquid Nitrogen

    Institute of Scientific and Technical Information of China (English)

    LI Juan; SHI Yu-mei; WANG Rong-shun; LI Xiang-dong

    2009-01-01

    This paper presents an investigation of a new method of purifying cryogenic liquid using sintered metallic wire-mesh filter, which has the advantages of high purifying efficiency and preferred strength at absolutely low temperature. Experiments are conducted to purify solid CO2 particles from liquid nitrogen. Temperature and pressure in the upstream and downstream of the filter, and the flow rate of carbon dioxide (CO2) gas and liquid nitrogen are measured, with the gas content of filtrate analyzed using a CO2 concentration detector. It is illustrated that after filtration, the purity of liquid nitrogen (volume fraction) is higher than 99.99%, which means that the volume fraction of CO2 is less than 0.01%. Effects of operation parameters on the performance of the filter, such as pressure drop △p and filtration efficiency E are analyzed quantitatively. The present conclusions will provide a guideline to the optimumal design and operation of sintered metallic wire-mesh filter in cryogenic application.

  4. Cryogenic Adsorption of Nitrogen and Carbon Dioxide in Activated Carbon

    Science.gov (United States)

    Shen, Fuzhi; Liu, Huiming; Xu, Dong; Zhang, Hengcheng; Lu, Junfeng; Li, Laifeng

    2017-09-01

    Activated carbon have been used for a long time at low temperature for cryogenic applications. The knowledge of adsorption characteristics of activated carbon at cryogenic temperature is essential for some specific applications. However, such experimental data are very scare in the literature. In order to measure the adsorption characteristics of activated carbon under variable cryogenic temperatures, an adsorption measurement device was presented. The experiment system is based on the commercially available PCT-pro adsorption analyzer coupled to a two-stage Gifford McMahon refrigerator, which allows the sample to be cooled to 4.2K. Cryogenic environment can be maintained steadily without the cryogenic liquid through the cryocooler and temperature can be controlled precisely between 5K and 300K by the temperature controller. Adsorption measurements were performed in activated carbon for carbon dioxide and nitrogen and the adsorption isotherm were obtained.

  5. An active damping method based on biquad digital filter for parallel grid-interfacing inverters with LCL filters

    DEFF Research Database (Denmark)

    Lu, Xiaonan; Sun, Kai; Huang, Lipei

    2014-01-01

    to the conventional active damping approaches, the biquad filter based active damping method does not require additional sensors and control loops. Meanwhile, the multiple instable closed-loop poles of the parallel inverter system can be moved to the stable region simultaneously. Real-time simulations based on dSPACE...

  6. Effects of millimeter wave carbon fibers on filter-feeding freshwater invertebrates.

    Science.gov (United States)

    Soucek, David J; Dickinson, Amy; Cropek, Donald M

    2010-05-01

    The purpose of our study was to investigate the sub-lethal effects of millimeter wave carbon fibers (MWCF), a military obscurant, on filter-feeding freshwater invertebrates. We observed decreased survival, reproduction, and oxygen consumption in Daphnia magna at realistic loading rates. In experiments with the Asiatic clam (Corbicula fluminea), soft tissue dry weight and tissue condition index were not significantly different among control and MWCF exposed treatments; however, using a (15)N labeled alga as food, we observed decreased nitrogen turnover in tissues of clams exposed to MWCF, suggesting lower filtering or ingestion rates. Our findings combined with previous demonstrations of MWCF toxicity to green algae suggest that over a period of several months, bivalve growth may be inhibited, and cladoceran populations may be even more strongly affected by MWCF. Given that these fibers are persistent, further experiments should be conducted to determine the longer-term effects of contamination of water bodies with MWCF.

  7. Stratification of nitrification activity in rapid sand filters for drinking water treatment

    DEFF Research Database (Denmark)

    Tatari, Karolina; Smets, Barth F.; Musovic, Sanin

    2013-01-01

    Rapid sand filters used in groundwater treatment remove ammonium, iron and manganese from the water. Ammonium is removed biologically by nitrifying microorganisms attached on the sand surface. Nitrification kinetics and activity is strongly affected by filter design and operation, which are the key...... parameters in process optimization. Nitrification optimization needs a detailed insight of the process and the way it takes place in the filter. Filters are often considered in a “black box” approach, where data are only available for influent and effluent and the entire filter is assumed homogenous. The aim...... of this study is to investigate nitrification activity in a rapid sand filter, with focus on its homogeneity and how it relates to filter performance. Two groundwater treatment plants in Denmark were selected for the experimental investigations. Plant 1 operates a single line of pre and after filters and has...

  8. Adaptive Current Control Method for Hybrid Active Power Filter

    Science.gov (United States)

    Chau, Minh Thuyen

    2016-09-01

    This paper proposes an adaptive current control method for Hybrid Active Power Filter (HAPF). It consists of a fuzzy-neural controller, identification and prediction model and cost function. The fuzzy-neural controller parameters are adjusted according to the cost function minimum criteria. For this reason, the proposed control method has a capability on-line control clings to variation of the load harmonic currents. Compared to the single fuzzy logic control method, the proposed control method shows the advantages of better dynamic response, compensation error in steady-state is smaller, able to online control is better and harmonics cancelling is more effective. Simulation and experimental results have demonstrated the effectiveness of the proposed control method.

  9. Advanced nonlinear control of three phase series active power filter

    Directory of Open Access Journals (Sweden)

    Abouelmahjoub Y.

    2014-01-01

    Full Text Available The problem of controlling three-phase series active power filter (TPSAPF is addressed in this paper in presence of the perturbations in the voltages of the electrical supply network. The control objective of the TPSAPF is twofold: (i compensation of all voltage perturbations (voltage harmonics, voltage unbalance and voltage sags, (ii regulation of the DC bus voltage of the inverter. A controller formed by two nonlinear regulators is designed, using the Backstepping technique, to provide the above compensation. The regulation of the DC bus voltage of the inverter is ensured by the use of a diode bridge rectifier which its output is in parallel with the DC bus capacitor. The Analysis of controller performances is illustrated by numerical simulation in Matlab/Simulink environment.

  10. Studies of activated carbon and carbon black for supercapacitor applications

    Energy Technology Data Exchange (ETDEWEB)

    Richner, R.; Mueller, S.; Koetz, R.; Wokaun, A. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    Carbon Black and activated carbon materials providing high surface areas and a distinct pore distribution are prime materials for supercapacitor applications at frequencies < 0.5 Hz. A number of these materials were tested for their specific capacitance, surface and pore size distribution. High capacitance electrodes were manufactured on the laboratory scale with attention to ease of processability. (author) 1 fig., 1 ref.

  11. Energy-filtered transmission electron microscopy of biological samples on highly transparent carbon nanomembranes

    Energy Technology Data Exchange (ETDEWEB)

    Rhinow, Daniel, E-mail: daniel.rhinow@biophys.mpg.de [Max-Planck-Institute of Biophysics, Department of Structural Biology, Max-von-Laue-Strasse 3, D-60439 Frankfurt (Germany); Bueenfeld, Matthias; Weber, Nils-Eike; Beyer, Andre; Goelzhaeuser, Armin [University of Bielefeld, Department of Physics, Universitaetsstrasse 25, D-33615 Bielefeld (Germany); Kuehlbrandt, Werner [Max-Planck-Institute of Biophysics, Department of Structural Biology, Max-von-Laue-Strasse 3, D-60439 Frankfurt (Germany); Hampp, Norbert [University of Marburg, Department of Chemistry, Hans-Meerwein-Strasse, D-35032 Marburg (Germany); Turchanin, Andrey [University of Bielefeld, Department of Physics, Universitaetsstrasse 25, D-33615 Bielefeld (Germany)

    2011-04-15

    Ultrathin carbon nanomembranes (CNM) comprising crosslinked biphenyl precursors have been tested as support films for energy-filtered transmission electron microscopy (EFTEM) of biological specimens. Due to their high transparency CNM are ideal substrates for electron energy loss spectroscopy (EELS) and electron spectroscopic imaging (ESI) of stained and unstained biological samples. Virtually background-free elemental maps of tobacco mosaic virus (TMV) and ferritin have been obtained from samples supported by {approx}1 nm thin CNM. Furthermore, we have tested conductive carbon nanomembranes (cCNM) comprising nanocrystalline graphene, obtained by thermal treatment of CNM, as supports for cryoEM of ice-embedded biological samples. We imaged ice-embedded TMV on cCNM and compared the results with images of ice-embedded TMV on conventional carbon film (CC), thus analyzing the gain in contrast for TMV on cCNM in a quantitative manner. In addition we have developed a method for the preparation of vitrified specimens, suspended over the holes of a conventional holey carbon film, while backed by ultrathin cCNM. -- Research highlights: {yields} We examine ultrathin carbon nanomembranes (CNM) as supports for biological TEM. {yields} CNM comprise crosslinked biphenyl precursors. {yields} CNM supports enable background-free elemental mapping of heavy and light elements. {yields} We perform cryoEM of ice-embedded biological samples on graphene-like conductive CNM.

  12. Spin-Filter Effect Induced by Magnetic Edge States of Zigzag Carbon Nanotube

    Institute of Scientific and Technical Information of China (English)

    JIANG Zhan-Feng; LI Jian; SHEN Shun-Qing; LIU Wu-Ming

    2008-01-01

    @@ Spin-filter effect is predicted in a weak coupled junction composed of a nonmagnetic metal electrode and a zigzag carbon nanotube. This effect is induced by the magnetic edge states of the nanotube, and can produce spinpolarized current in the absence of an external magnetic field. We find that the spin polarization of the current changes its sign at the half-filling point of the nanotube, thus electric field control of spin transport can be realized. Furthermore, we find the coupling strength of the junction may cause a magnetic transition on the edge of the nanotube.

  13. Neural network controlled three-phase four-wire shunt active power filter

    Energy Technology Data Exchange (ETDEWEB)

    Elmitwally, A.; Abdelkader, S. [Mansura University (Egypt); El-Kateb, M. [Bath University (United Kingdom). Dept. of Electronic and Electrical Engineering

    2000-03-01

    A three-phase four-wire shunt active power filter for harmonic mitigation and reactive power compensation in power systems supplying nonlinear loads is presented. Three adaptive linear neurons are used to tackle the desired three-phase filter current templates. Another feedforward three layer neural network is adopted to control the output filter compensating currents online. This is accomplished by producing the appropriate switching patterns of the converter's legs IGBTs. Adequate tracking of the filter current references is obtained by this method. The active filter inject the current required to compensate for the harmonic and reactive components of the line currents. Simulation results of the proposed active filter indicate a remarkable improvement in the source current waveforms. This is reflected in the enhancement of the unified power quality index defined. Also, the filter has exhibited quite a high dynamic response for step variations in the load current assuring its potential for real-time applications. (author)

  14. A Series-LC-Filtered Active Damper for AC Power Electronics Based Power Systems

    DEFF Research Database (Denmark)

    Wang, Xiongfei; Blaabjerg, Frede; Loh, Poh Chiang

    2015-01-01

    This paper proposes an active damper with a series LC-filter for suppressing resonances in an ac power electronics based power system. The added filter capacitor helps to lower the voltage stress of the converter to be used for implementing the damper. Unlike active filters for the compensation...... is built, where the damper is integrated into a grid-connected converter. The results obtained from the experiments demonstrate the stability enhancement of ac power electronics based power systems by the active damper....

  15. Effects of filter choice in GT3X accelerometer assessments of free-living activity.

    Science.gov (United States)

    Wanner, Miriam; Martin, Brian W; Meier, Flurina; Probst-Hensch, Nicole; Kriemler, Susi

    2013-01-01

    ActiGraph accelerometers are widely used devices to objectively assess physical activity. The GT3X version has two filter options to be selected before data assessment (normal and low-frequency extension filter option). It is not clear whether the resulting physical activity levels differ depending on the choice of the filter. The aims were to compare GT3X data collected using the different filter options during free-living activities and to establish correction factors if the results were not comparable. Sixty-five participants of the population-based SAPALDIA-cohort (50.8% women, age range = 40-80 yr) wore two GT3X accelerometers with different filter selections simultaneously during 8 d. Spearman correlations, Wilcoxon rank sum tests, McNemar tests, scatter plots, and Bland-Altman plots were used to compare the data. Correction factors were established using linear regression models. Although Spearman correlations were high (r ≥ 0.93), there were significant differences in minutes per day between filter options for nonwearing time and time spent in sedentary, light, and moderate-to-vigorous physical activity (all P Mean counts per minute and steps per day were significantly higher using the low-frequency extension filter (P filter option and to specify the filter choice in publications. The correction factors can be used to make data assessed using the low-frequency extension filter comparable to data assessed using the normal filter option.

  16. Development of adaptive IIR filtered-e LMS algorithm for active noise control

    Institute of Scientific and Technical Information of China (English)

    SUN Xu; MENG Guang; TENG Pengxiao; CHEN Duanshi

    2003-01-01

    Compared to finite impulse response (FIR) filters, infinite impulse response (IIR)filters can match the system better with much fewer coefficients, and hence the computationload is saved and the performance improves. Therefore, it is attractive to use IIR filters insteadof FIR filters in active noise control (ANC). However, filtered-U LMS (FULMS) algorithm, theIIR filter-based algorithm commonly used so far cannot ensure global convergence. A new IIRfilter based adaptive algorithm, which can ensure global convergence with computation loadonly slightly increasing, is proposed in this paper. The new algorithm is called as filtered-eLMS algorithm since the error signal of which need to be filtered. Simulation results show thatthe FELMS algorithm presents better performance than the FULMS algorithm.

  17. BIOLOGICAL AERATED FILTERS (BAFs FOR CARBON AND NITROGEN REMOVAL: A REVIEW

    Directory of Open Access Journals (Sweden)

    ELSHAFIE AHMED

    2012-08-01

    Full Text Available Biological aerated filters (BAFs are an emerging wastewater treatment technology designed for a wide range of municipal and industrial applications. This review paper presents and discusses of the influence C/N ratio, nitrification and denitrification principle, effect of pH, DO and alkalinity on the nitrification and denitrification systems, organic and hydraulic loading of BAF reactor, etc. Results from upflow and downflow biofilter pilot at different condition, with nitrification and denitrification are reviewed. Under the optimal conditions, significant amount of COD, ammonia-nitrogen and total nitrogen were removed. Removal rates based on reactor volume for different carbon-aceous COD and ammonia loading rate are reported. The BAF system for the nitrification and denitrification processes for carbon and nitrogen removal from the wastewater need to be evaluated and applied properly to protect of our environment and resources.

  18. Flax shive as a sources of activated carbon for metals remediation

    Directory of Open Access Journals (Sweden)

    Akin, D. E.

    2007-02-01

    Full Text Available Flax shive constitutes about 70% of the flax stem and has limited use. Because shive is a lignocellulosic by-product, it can potentially be pyrolyzed and activated to produce an activated carbon. The objective of this study was to create an activated carbon from flax shive by chemical activation in order to achieve significant binding of selected divalent cations (cadmium, calcium, copper, magnesium, nickel, zinc. Shive carbons activated by exposure to phosphoric acid and com-pressed air showed greater binding of cadmium, copper, nickel or zinc than a sulfuric acid-activated flax shive carbon reported in the literature and a commercial, wood-based carbon. Uptake of calcium from a drinking water sample by the shive carbon was similar to commercial drinking water filters that contained cation exchange resins. Magnesium removal by the shive carbon was greater than a commercial drinking water filtration carbon but less than for filters containing cation exchange resins. The results indicate that chemically activated flax shive carbon shows considerable promise as a component in industrial and residential water filtration systems for removal of divalent cations.

  19. Petrographic evaluation of xylite activated carbon

    Energy Technology Data Exchange (ETDEWEB)

    Predeanu, G. [Metallurgical Research Institute, Department of Raw Materials, Mehadia St. 39, Sector 6, 060543 Bucharest (Romania); Panaitescu, C. [University POLITEHNICA Bucharest, Faculty of Industrial Chemistry, Fuel Laboratory, Polizu St. 1, Sector 1, 011061, Bucharest (Romania)

    2007-08-01

    Xylites are promising materials for activated carbon manufacturing due to their low rank, low inorganic content, and structural characteristics similar to the strong consistence of wood. These are similar to the classical adsorbents used for waste water purification, and available and profitable in the long term. This study has been undertaken to provide by means of petrographic data, new information on the porous structure development in chars during direct heating carbonization and physical activation. The xylite petrographic composition is very important, mainly due to the existence of structured wooden material - textinite with round and elongated cells - that influences the development of the structure and texture during carbonization and activation. The charcoal microstructure reveals some interesting aspects about the carbonization process with regard to evolution, efficiency and pore development. In the xylite activated carbon, the adsorption surface development by means of the highly porous system depends on the type of petrographical components, raw material grain size, and carbonization parameters. (author)

  20. A Self-commissioning Notch Filter for Active Damping in a Three-Phase LCL -Filter-Based Grid-Tie Converter

    DEFF Research Database (Denmark)

    Pena-Alzola, Rafael; Liserre, Marco; Blaabjerg, Frede

    2014-01-01

    LCL-filters are a cost-effective solution to mitigate harmonic current content in grid-tie converters. In order to avoid stability problems, the resonance frequency of LCL-filters can be damped with active techniques that remove dissipative elements but increase control complexity. A notch filter...... provides an effective solution, however tuning the filter requires considerable design effort and the variations in the grid impedance limit the LCL-filter robustness. This paper proposes a straightforward tuning procedure for a notch filter self-commissioning. In order to account for the grid inductance...

  1. Influence of thermal heating on diamond-like carbon film properties prepared by filtered cathodic arc

    Energy Technology Data Exchange (ETDEWEB)

    Khamnualthong, N., E-mail: nattapornkh@gmail.com [Department of Physics, Faculty of Science, King Mongkut' s University of Technology Thonburi, Bangkok, 10140 (Thailand); Western Digital Thailand Co. Ltd, Ayutthaya, 13160 (Thailand); Siangchaew, K. [Western Digital Thailand Co. Ltd, Ayutthaya, 13160 (Thailand); Limsuwan, P. [Department of Physics, Faculty of Science, King Mongkut' s University of Technology Thonburi, Bangkok, 10140 (Thailand); Thailand Center of Excellence in Physics, CHE, Ministry of Education, Bangkok 10400 (Thailand)

    2013-10-01

    Tetrahedral amorphous diamond-like carbon (ta-DLC) films were deposited on magnetic recording heads using the filtered cathodic arc method. The deposited film thickness was on the order of several nanometers. The DLC films were then annealed to 100 °C–300 °C for 30 and 60 min, and the structure of the ta-DLC films was investigated using Raman spectroscopy, where the gross changes were observed in the Raman D and G peaks. Detailed interpretation concluded that there was sp{sup 2} clustering as a function of temperature, and there was no sp{sup 3}-to-sp{sup 2} conversion after heating up to 300 °C. Furthermore, X-ray photoelectron spectroscopy suggested that oxidation of both the ta-DLC film and the adhesion layer occurs at 300 °C. Additionally, more film wear was observed with heating as measured by a nanoindenter. - Highlights: • Tetrahedral-amorphous diamond-like carbon (ta-DLC) by filtered cathodic arc • ta-DLC used in magnetic recording head as head overcoat • ta-DLC thickness range of less than 2 nm • ta-DLC property dependence on heating • Temperature effect range of up to 300 °C.

  2. LARGE AREA FILTERED ARC DEPOSITION OF CARBON AND BORON BASED HARD COATINGS

    Energy Technology Data Exchange (ETDEWEB)

    Bhattacharya, Rabi S.

    2003-12-05

    This document is a final report covering work performed under Contract No. DE-FG02-99ER82911 from the Department of Energy under a SBIR Phase II Program. Wear resistant, hard coatings can play a vital role in many engineering applications. The primary goal of this project was to develop coatings containing boron and carbon with hardness greater than 30 GPa and evaluate these coatings for machining applications. UES has developed a number of carbon and boron containing coatings with hardness in the range of 34 to 65 GPa using a combination of filtered cathodic arc and magnetron sputtering. The boron containing coatings were based on TiB2, TiBN, and TiBCN, while the carbon containing coatings ere TiC+C and hydrogen free diamond-like-carbon. Machining tests were performed with single and multilayer coated tools. The turning and milling tests were run at TechSolve Inc., under a subcontract at Ohio State University. Significant increases in tool lives were realized in end milling of H-13 die steel (8X) and titanium alloy (80%) using the TiBN coating. A multilayer TiBN/TiN performed the best in end-milling of highly abrasive Al-Si alloys. A 40% increase in life over the TiAlN benchmark coating was found. Further evaluations of these coatings with commercialization partners are currently in progress.

  3. The Analysis of Activated Carbon Regeneration Technologies

    Institute of Scientific and Technical Information of China (English)

    姚芳

    2014-01-01

    A series of methods for activated carbon regeneration were briefly introduced.Such as thermal regeneration,chemical regeneration,biochemical regeneration,and newly supercritical fluid regeneration, electrochemical regeneration,light-catalyzed regeneration,and microwave radiation method,and the developing trend of activated carbon regeneration was predicted.

  4. T Source Inverter Based Shunt Active Filter with LCL Passive Filter for the 415V 50 Hz Distribution systems

    OpenAIRE

    S. Sellakumar; Vijayakumar, M.

    2015-01-01

    The inverter topology is being used as an active filter to reduce the harmonics in the power system [1]. The traditional voltage source or current source inverters are having the disadvantages of limited output voltage range hence it may not be able to supply enough compensating currents during heavy switching surges, Vulnerable to EMI noise and the devices gets damaged in either open or short circuit conditions and the main switching device of VSI and CSI are not interchangeable. The active ...

  5. Making Activated Carbon by Wet Pressurized Pyrolysis

    Science.gov (United States)

    Fisher, John W.; Pisharody, Suresh; Wignarajah, K.; Moran, Mark

    2006-01-01

    A wet pressurized pyrolysis (wet carbonization) process has been invented as a means of producing activated carbon from a wide variety of inedible biomass consisting principally of plant wastes. The principal intended use of this activated carbon is room-temperature adsorption of pollutant gases from cooled incinerator exhaust streams. Activated carbon is highly porous and has a large surface area. The surface area depends strongly on the raw material and the production process. Coconut shells and bituminous coal are the primary raw materials that, until now, were converted into activated carbon of commercially acceptable quality by use of traditional production processes that involve activation by use of steam or carbon dioxide. In the wet pressurized pyrolysis process, the plant material is subjected to high pressure and temperature in an aqueous medium in the absence of oxygen for a specified amount of time to break carbon-oxygen bonds in the organic material and modify the structure of the material to obtain large surface area. Plant materials that have been used in demonstrations of the process include inedible parts of wheat, rice, potato, soybean, and tomato plants. The raw plant material is ground and mixed with a specified proportion of water. The mixture is placed in a stirred autoclave, wherein it is pyrolized at a temperature between 450 and 590 F (approximately between 230 and 310 C) and a pressure between 1 and 1.4 kpsi (approximately between 7 and 10 MPa) for a time between 5 minutes and 1 hour. The solid fraction remaining after wet carbonization is dried, then activated at a temperature of 500 F (260 C) in nitrogen gas. The activated carbon thus produced is comparable to commercial activated carbon. It can be used to adsorb oxides of sulfur, oxides of nitrogen, and trace amounts of hydrocarbons, any or all of which can be present in flue gas. Alternatively, the dried solid fraction can be used, even without the activation treatment, to absorb

  6. Hydrogen isotherms in palladium loaded carbon nanotubes and activated carbons

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, M. T.; Anson, A.; Lafuente, E.; Urriolabeitia, E.; Navarro, R.; Benito, A. M.; Maser, W. K.

    2005-07-01

    Session 5a In order to increase the hydrogen sorption capacity of carbon materials, a sample of single-wall carbon nanotubes (SWNTs) and the activated carbon MAXSORB have been loaded with palladium nanoparticles. While carbon materials adsorb hydrogen due to physical interactions, palladium can capture hydrogen into the bulk structure or chemically react to form hydrides. Experiental SWNTs have been synthesized in an electric arc reactor, using Ni and Y as catalysts in a 660 mbar He atmosphere. MAXSORB is a commercial activated carbon obtained from petroleum coke through a chemical treatment with KOH. Palladium has been deposited over the carbon support by means of a reflux method in a solution of an organometallic complex. Different samples have been prepared depending on the weight ratio (Carbon material / Pd) in the original reactants. The effectiveness of the deposition method has been examined by means of X-ray diffraction (XRD), induction coupled plasma spectrometry (ICPS) and transmission electron microscopy (TEM). The volumetric system Autosorb-1 from Quantachrome Instruments has been used to obtain the nitrogen adsorption isotherms at 77 K for all the materials. The hydrogen isotherms at 77 K and room temperature and up to 800 torr have also been obtained in the Autosorb-1. The BET specific surface area and the micropore volume have been calculated from the nitrogen adsorption data. High pressure hydrogen isotherms up to 90 bar have been carried out at room temperature in a VTI system provided with a Rubotherm microbalance. (Author)

  7. Application of wide band harmonic active filters; Aplicacao de filtros ativos de harmonicos de banda larga

    Energy Technology Data Exchange (ETDEWEB)

    Evans, Ian C. [Harmonics Solutions Co., Scotland (United Kingdom); Johnson, James R. [Schneider Electric (United States)

    2010-02-15

    Non linear charges causes problems such as flicker, harmonics, low displacement power factor and high inrush high currents. As the conventional technologies does not have capacity to face such problems, it is necessary specialized technologies such as the harmonic active filters with wide band logic. This paper presents four cases of difficult solution and analyses two types of active filter projects. (author)

  8. Comparison of continuous and filter-based carbon measurements at the Fresno supersite.

    Science.gov (United States)

    Park, Kihong; Chow, Judith C; Watson, John G; Trimble, Dana L; Doraiswamy, Prakash; Park, Kihong; Arnott, W Pat; Stroud, Kenneth R; Bowers, Kenneth; Bode, Richard; Petzold, Andre; Hansen, Anthony D A

    2006-04-01

    Results from six continuous and semicontinuous black carbon (BC) and elemental carbon (EC) measurement methods are compared for ambient samples collected from December 2003 through November 2004 at the Fresno Supersite in California. Instruments included a multi-angle absorption photometer (MAAP; lambda = 670 nm); a dual-wavelength (lambda = 370 and 880 nm) aethalometer; seven-color (lambda = 370, 470, 520, 590, 660, 880, and 950 nm) aethalometers; the Sunset Laboratory carbon aerosol analysis field instrument; a photoacoustic light absorption analyzer (lambda = 1047 nm); and the R&P 5400 ambient carbon particulate monitor. All of these acquired BC or EC measurements over periods of 1 min to 1 hr. Twenty-four-hour integrated filter samples were also acquired and analyzed by the Interagency Monitoring of Protected Visual Environments (IMPROVE) thermal/optical reflectance carbon analysis protocol. Site-specific mass absorption efficiencies estimated by comparing light absorption with IMPROVE EC concentrations were 5.5 m2/g for the MAAP, 10 m2/g for the aethalometer at a wavelength of 880 nm, and 2.3 m2/g for the photoacoustic analyzer; these differed from the default efficiencies of 6.5, 16.6, and 5 m2/g, respectively. Scaling absorption by inverse wavelength did not provide equivalent light absorption coefficients among the instruments for the Fresno aerosol measurements. Ratios of light absorption at 370 nm to those at 880 nm from the aethalometer were nearly twice as high in winter as in summer. This is consistent with wintertime contributions from vehicle exhaust and from residential wood combustion, which is believed to absorb more shorter-wavelength light. To reconcile BC and EC measurements obtained by different methods, a better understanding is needed of the wavelength dependence of light-absorption and mass-absorption efficiencies and how they vary with different aerosol composition.

  9. LOW ACTIVITY WASTE FEED SOLIDS CARACTERIZATION AND FILTERABILITY TESTS

    Energy Technology Data Exchange (ETDEWEB)

    McCabe, D.; Crawford, C.; Duignan, M.; Williams, M.; Burket, P.

    2014-04-03

    The primary treatment of the tank waste at the DOE Hanford site will be done in the Waste Treatment and Immobilization Plant (WTP) that is currently under construction. The baseline plan for the WTP Pretreatment facility is to treat the waste, splitting it into High Level Waste (HLW) feed and Low Activity Waste (LAW) feed. Both waste streams are then separately vitrified as glass and sealed in canisters. The LAW glass will be disposed onsite in the Integrated Disposal Facility (IDF). There are currently no plans to treat the waste to remove technetium in the WTP Pretreatment facility, so its disposition path is the LAW glass. Options are being explored to immobilize the LAW portion of the tank waste, i.e., the LAW feed from the WTP Pretreatment facility. Removal of {sup 99}Tc from the LAW Feed, followed by off-site disposal of the {sup 99}Tc, would eliminate a key risk contributor for the IDF Performance Assessment (PA) for supplemental waste forms, and has potential to reduce treatment and disposal costs. Washington River Protection Solutions (WRPS) is developing some conceptual flow sheets for LAW treatment and disposal that could benefit from technetium removal. One of these flowsheets will specifically examine removing {sup 99}Tc from the LAW feed stream to supplemental immobilization. The conceptual flow sheet of the {sup 99}Tc removal process includes a filter to remove insoluble solids prior to processing the stream in an ion exchange column, but the characteristics and behavior of the liquid and solid phases has not previously been investigated. This report contains results of testing of a simulant that represents the projected composition of the feed to the Supplemental LAW process. This feed composition is not identical to the aqueous tank waste fed to the Waste Treatment Plant because it has been processed through WTP Pretreatment facility and therefore contains internal changes and recycle streams that will be generated within the WTP process. Although

  10. Adaptive-Fuzzy Controller Based Shunt Active Filter for Power Line Conditioners

    Directory of Open Access Journals (Sweden)

    KamalaKanta Mahapatra

    2011-08-01

    Full Text Available This paper presents a novel Fuzzy Logic Controller (FLC in conjunction with Phase Locked Loop (PLL based shunt active filter for Power Line Conditioners (PLCs to improve the power quality in the distribution system. The active filter is implemented with current controlled Voltage Source Inverter (VSI for compensating current harmonics and reactive power at the point of common coupling. The VSI gate control switching pulses are derived from proposed Adaptive-Fuzzy-Hysteresis Current Controller (HCC and this method calculates the hysteresis bandwidth effectively using fuzzy logic. The bandwidth can be adjusted based on compensation current variation, which is used to optimize the required switching frequency and improves active filter substantially. These shunt active power filter system is investigated and verified under steady and transient-state with non-linear load conditions. This shunt active filter is in compliance with IEEE 519 and IEC 61000-3 recommended harmonic standards.

  11. Design and control of an LCL-filter-based three-phase active rectifier

    DEFF Research Database (Denmark)

    Liserre, Marco; Blaabjerg, Frede; Hansen, Steffan

    2005-01-01

    This paper proposes a step-by-step procedure for designing the LCL filter of a front-end three-phase active rectifier. The primary goal is to reduce the switching frequency ripple at a reasonable cost, while at the same time achieving a high-performance front-end rectifier (as characterized...... by a rapid dynamic response and good stability margin). An example LCL filter design is reported and a filter has been built and tested using the values obtained from this design. The experimental results demonstrate the performance of the design procedure both for the LCL filter and for the rectifier...... a powerful tool to design an LCL-filter-based active rectifier while avoiding trial-and-error procedures that can result in having to build several filter prototypes....

  12. Final Technical Report [Carbon Data Assimilation with a Coupled Ensemble Kalman Filter

    Energy Technology Data Exchange (ETDEWEB)

    Kalnay, Eugenia

    2013-08-30

    We proposed (and accomplished) the development of an Ensemble Kalman Filter (EnKF) approach for the estimation of surface carbon fluxes as if they were parameters, augmenting the model with them. Our system is quite different from previous approaches, such as carbon flux inversions, 4D-­Var, and EnKF with approximate background error covariance (Peters et al., 2008). We showed (using observing system simulation experiments, OSSEs) that these differences lead to a more accurate estimation of the evolving surface carbon fluxes at model grid-scale resolution. The main properties of the LETKF-­C are: a) The carbon cycle LETKF is coupled with the simultaneous assimilation of the standard atmospheric variables, so that the ensemble wind transport of the CO2 provides an estimation of the carbon transport uncertainty. b) The use of an assimilation window (6hr) much shorter than the months-long windows used in other methods. This avoids the inevitable “blurring” of the signal that takes place in long windows due to turbulent mixing since the CO2 does not have time to mix before the next window. In this development we introduced new, advanced techniques that have since been adopted by the EnKF community (Kang, 2009, Kang et al., 2011, Kang et al. 2012). These advances include “variable localization” that reduces sampling errors in the estimation of the forecast error covariance, more advanced adaptive multiplicative and additive inflations, and vertical localization based on the time scale of the processes. The main result has been obtained using the LETKF-­C with all these advances, and assimilating simulated atmospheric CO2 observations from different observing systems (surface flask observations of CO2 but no surface carbon fluxes observations, total column CO2 from GoSAT/OCO-­2, and upper troposphere AIRS retrievals). After a spin-­up of about one month, the LETKF-­C succeeded in reconstructing the true evolving surface fluxes of carbon at a model grid

  13. Final report on "Carbon Data Assimilation with a Coupled Ensemble Kalman Filter"

    Energy Technology Data Exchange (ETDEWEB)

    Kalnay, Eugenia; Kang, Ji-Sun; Fung, Inez

    2014-07-23

    We proposed (and accomplished) the development of an Ensemble Kalman Filter (EnKF) approach for the estimation of surface carbon fluxes as if they were parameters, augmenting the model with them. Our system is quite different from previous approaches, such as carbon flux inversions, 4D-Var, and EnKF with approximate background error covariance (Peters et al., 2008). We showed (using observing system simulation experiments, OSSEs) that these differences lead to a more accurate estimation of the evolving surface carbon fluxes at model grid-scale resolution. The main properties of the LETKF-C are: a) The carbon cycle LETKF is coupled with the simultaneous assimilation of the standard atmospheric variables, so that the ensemble wind transport of the CO2 provides an estimation of the carbon transport uncertainty. b) The use of an assimilation window (6hr) much shorter than the months-long windows used in other methods. This avoids the inevitable “blurring” of the signal that takes place in long windows due to turbulent mixing since the CO2 does not have time to mix before the next window. In this development we introduced new, advanced techniques that have since been adopted by the EnKF community (Kang, 2009, Kang et al., 2011, Kang et al. 2012). These advances include “variable localization” that reduces sampling errors in the estimation of the forecast error covariance, more advanced adaptive multiplicative and additive inflations, and vertical localization based on the time scale of the processes. The main result has been obtained using the LETKF-C with all these advances, and assimilating simulated atmospheric CO2 observations from different observing systems (surface flask observations of CO2 but no surface carbon fluxes observations, total column CO2 from GoSAT/OCO-2, and upper troposphere AIRS retrievals). After a spin-up of about one month, the LETKF-C succeeded in reconstructing the true evolving surface fluxes of carbon at a model grid resolution. When

  14. Adsorption of Hydantoins on Activated Carbon,

    Science.gov (United States)

    1985-05-01

    covery, Garten and Weiss (1965) proposed the existence of chromene (benzpyran) groups on the surface of H-carbons. The acid reaction with the chromene ...presence of the chromene groups on the surface of H-carbons is responsible for the acid-adsorbing characteristics. Activation temperatures and

  15. The Transport Properties of Activated Carbon Fibers

    Science.gov (United States)

    di Vittorio, S. L.; Dresselhaus, M. S.; Endo, M.; Issi, J-P.; Piraux, L.

    1990-07-01

    The transport properties of activated isotropic pitch-based carbon fibers with surface area 1000 m{sup 2}/g have been investigated. We report preliminary results on the electrical conductivity, the magnetoresistance, the thermal conductivity and the thermopower of these fibers as a function of temperature. Comparisons are made to transport properties of other disordered carbons.

  16. ACTIVATED CARBON FROM LIGNITE FOR WATER TREATMENT

    Energy Technology Data Exchange (ETDEWEB)

    Edwin S. Olson; Daniel J. Stepan

    2000-07-01

    High concentrations of humate in surface water result in the formation of excess amounts of chlorinated byproducts during disinfection treatment. These precursors can be removed in water treatment prior to disinfection using powdered activated carbon. In the interest of developing a more cost-effective method for removal of humates in surface water, a comparison of the activities of carbons prepared from North Dakota lignites with those of commercial carbons was conducted. Previous studies indicated that a commercial carbon prepared from Texas lignite (Darco HDB) was superior to those prepared from bituminous coals for water treatment. That the high alkali content of North Dakota lignites would result in favorable adsorptive properties for the very large humate molecules was hypothesized, owing to the formation of larger pores during activation. Since no standard humate test has been previously developed, initial adsorption testing was performed using smaller dye molecules with various types of ionic character. With the cationic dye, methylene blue, a carbon prepared from a high-sodium lignite (HSKRC) adsorbed more dye than the Darco HDB. The carbon from the low-sodium lignite was much inferior. With another cationic dye, malachite green, the Darco HDB was slightly better. With anionic dyes, methyl red and azocarmine-B, the results for the HSKRC and Darco HDB were comparable. A humate test was developed using Aldrich humic acid. The HSKRC and the Darco HDB gave equally high adsorption capacities for the humate (138 mg/g), consistent with the similarities observed in earlier tests. A carbon prepared from a high-sodium lignite from a different mine showed an outstanding improvement (201 mg/g). The carbons prepared from the low-sodium lignites from both mines showed poor adsorption capacities for humate. Adsorption isotherms were performed for the set of activated carbons in the humate system. These exhibited a complex behavior interpreted as resulting from two types

  17. Activation of Carbon Dioxide and Synthesis of Propylene Carbonate

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Cycloaddition of carbon dioxide and propylene oxide to propylene carbonate catalyzed by tetra-tert-butyl metal phthalocyanine in the presence of tributylamine (TBA) shows higher yield than catalyzed by unsubstituted metal phthalocyanine. Comparing different catalysts of diverse metals, (t-Bu)4PcMg is more active than (t-Bu)4PcFe. But (t-Bu)4PcCo and (t-Bu)4PcNi only have low catalytic activities towards the reaction. Moreover, the yield will increase as the temperature increases.

  18. Carbon dioxide adsorption in chemically activated carbon from sewage sludge.

    Science.gov (United States)

    de Andrés, Juan Manuel; Orjales, Luis; Narros, Adolfo; de la Fuente, María del Mar; Encarnación Rodríguez, María

    2013-05-01

    In this work, sewage sludge was used as precursor in the production of activated carbon by means of chemical activation with KOH and NaOH. The sludge-based activated carbons were investigated for their gaseous adsorption characteristics using CO2 as adsorbate. Although both chemicals were effective in the development of the adsorption capacity, the best results were obtained with solid NaOH (SBA(T16)). Adsorption results were modeled according to the Langmuir and Freundlich models, with resulting CO2 adsorption capacities about 56 mg/g. The SBA(T16) was characterized for its surface and pore characteristics using continuous volumetric nitrogen gas adsorption and mercury porosimetry. The results informed about the mesoporous character of the SBA(T16) (average pore diameter of 56.5 angstroms). The Brunauer-Emmett-Teller (BET) surface area of the SBA(T16) was low (179 m2/g) in comparison with a commercial activated carbon (Airpel 10; 1020 m2/g) and was mainly composed of mesopores and macropores. On the other hand, the SBA(T16) adsorption capacity was higher than that of Airpel 10, which can be explained by the formation of basic surface sites in the SBA(T16) where CO2 experienced chemisorption. According to these results, it can be concluded that the use of sewage-sludge-based activated carbons is a promising option for the capture of CO2. Adsorption methods are one of the current ways to reduce CO2 emissions. Taking this into account, sewage-sludge-based activated carbons were produced to study their CO2 adsorption capacity. Specifically, chemical activation with KOH and NaOH of previously pyrolyzed sewage sludge was carried out. The results obtained show that even with a low BET surface area, the adsorption capacity of these materials was comparable to that of a commercial activated carbon. As a consequence, the use of sewage-sludge-based activated carbons is a promising option for the capture of CO2 and an interesting application for this waste.

  19. ACTIVATED CARBON/REFRIGERANT COMBINATIONS FOR ...

    African Journals Online (AJOL)

    ES Obe

    2001-03-01

    Mar 1, 2001 ... Nigerian Journal of Technology Vol. 20. No. ... Federal university of Technology ... Activated carbon is the adsorbent while ammonia, ethanol and methanol are the adsorbate. The ... production is not a new phenomenon.

  20. PREPARATION OF MESOPOROUS CARBON BY CARBON DIOXIDE ACTIVATION WITH CATALYST

    Institute of Scientific and Technical Information of China (English)

    W.Z.Shen; A.H.Lu; J.T.Zheng

    2002-01-01

    A mesoporous activated carbon (AC) can be successfully prepared by catalytic activa-tion with carbon dioxide. For iron oxide as catalyst, there were two regions of mesoporesize distribution, i.e. 2-5nm and 30-70nm. When copper oxide or magnesium oxidecoexisted with iron oxide as composite catalyst, the content of pores with sizes of 2-5nm was decreased, while the pores with 30 70nm were increased significantly. Forcomparison, AC reactivated by carbon dioxide directly was also investigated. It wasshown that the size of mesopores of the resulting AC concentrated in 2-5nm with lessvolume. The adsorption of Congo red was tested to evaluate the property of the result-ing AC. Furthermore, the factors affecting pore size distribution and the possibility ofmesopore formation were discussed.

  1. A unified active damping control for single-phase differential buck inverter with LCL-filter

    DEFF Research Database (Denmark)

    Yao, Wenli; Wang, Xiongfei; Zhang, Xiaobin

    2015-01-01

    The single-phase differential mode buck inverter is recently introduced with a differential mode for power transfer and a common mode for actively decoupling the second-order power oscillation. However, it is limited to islanded applications with an LC filter. This paper addresses the stability...... and control of a grid-connected differential mode buck inverter with an LCL filter. A generalized small-signal model of the inverter is built first with the averaged switching model. It is shown that the LCL filter resonance merely occurs in the differential mode, while an LC filter resonance exists...

  2. Adsorptive performance of granular activated carbon in aquaculture and aquaria: a simplified method

    DEFF Research Database (Denmark)

    Taylor, Daniel; Kuhn, David D.; Smith, Stephen

    2017-01-01

    observed in one filter group throughout the indicator testing battery. Similar findings were observed between the two indicator tests, thereby confirming the method. This method can be adopted by commercial aquaculture operations or aquarists to assist in comparatively screening particular types, particle...... sizes, and sources of granular activated carbon for specific water quality and engineering requirements...

  3. Granular Activated Carbon Performance Capability and Availability.

    Science.gov (United States)

    1983-06-01

    Kinetics of Activated Carbon Adsorption Journal of Water Polution 47(4) Aoril 1975 Control Federation 4-t9 Wnitna) G Aoalied Polarography for...proposed models for kinetics of adsorption of pink water organics by activated carbon. Both models are basically similar in nature and propose that...include formulation of a complete model of the pink water system based upon existing data. This model would then serve to reduce the amount of

  4. Three-phase shunt active power filter connected to a photovoltaic array

    Energy Technology Data Exchange (ETDEWEB)

    Belaidi, R.; Chikouche, A.; Fathi, M.; Mghezzi, Larafi [Unite de Developpement des Equipements Solaires (Algeria); Haddouche, A. [Universite Badji Mokhtar (Algeria)], E-mail: rachidi3434@yahoo.fr

    2011-07-01

    In recent years, public awareness of power quality issues in distribution systems has arisen. The photovoltaic interactive shunt active power filter is a system which provides harmonic current damping and reactive power compensation during the hours of sunlight, while the distribution system provides power during the hours of darkness. The aim of this paper is to study the topology of a photovoltaic interactive shunt active power filter. Simulations were performed using Matlab and Simulink and were analyzed to determine the effectiveness of the system; an MPPT algorithm was used to maximize the power extracted from the photovoltaic array. Results showed that the use of the power filter achieves a reduction in the total harmonic distortion of the current from 33.54% to 3.47%. This study demonstrated that the photovoltaic interactive shunt active power filter helps improve power quality by filtering harmonic currents and compensating reactive power generated by non-linear loads.

  5. An Active Trap Filter for Switching Harmonics Attenuation of Low-Pulse-Ratio Inverters

    DEFF Research Database (Denmark)

    Bai, Haofeng; Wang, Xiongfei; Loh, Poh Chiang

    2017-01-01

    , but generally susceptible to filter parameter variations and harmonic resonances. This paper hence presents an alternative Active Trap Filter (ATF), based on a series-LC-filtered inverter, for attenuating switching harmonics in a flexible, while yet not cost burdensome, approach. A direct impedance synthesis...... method has also been proposed for the ATF to better enforce its active switching harmonic bypassing ability. Compared with conventional schemes for controlling active power filters, the proposed method is more readily implemented, since it requires neither current reference generation nor high......-bandwidth current control loop. Moreover, the use of a series LC-filter at its ac-side helps the ATF to reduce its inverter voltage and power ratings. Compensated frequency range of the ATF can hence be enlarged by using a comparably higher switching frequency and a proper step-by-step design procedure...

  6. Fast affine projections and the regularized modified filtered-error algorithm in multichannel active noise control

    NARCIS (Netherlands)

    Wesselink, J.M.; Berkhoff, A.P.

    2008-01-01

    In this paper, real-time results are given for broadband multichannel active noise control using the regularized modified filtered-error algorithm. As compared to the standard filtered-error algorithm, the improved convergence rate and stability of the algorithm are obtained by using an inner-outer

  7. 76 FR 42130 - Agency Information Collection Activities: BioWatch Filter Holder Log

    Science.gov (United States)

    2011-07-18

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF HOMELAND SECURITY Agency Information Collection Activities: BioWatch Filter Holder Log AGENCY: Department of... agent. ] Analysis Agency: Department of Homeland Security. Title: BioWatch Filter Holder Log. OMB...

  8. 76 FR 24504 - Agency Information Collection Activities: BioWatch Filter Holder Log

    Science.gov (United States)

    2011-05-02

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF HOMELAND SECURITY Agency Information Collection Activities: BioWatch Filter Holder Log AGENCY: Department of... submissions of responses. Analysis Agency: Department of Homeland Security, DHS. Title: BioWatch Filter...

  9. Enhanced mercuric chloride adsorption onto sulfur-modified activated carbons derived from waste tires.

    Science.gov (United States)

    Yuan, Chung-Shin; Wang, Guangzhi; Xue, Sheng-Han; Ie, Iau-Ren; Jen, Yi-Hsiu; Tsai, Hsieh-Hung; Chen, Wei-Jin

    2012-07-01

    A number of activated carbons derived from waste tires were further impregnated by gaseous elemental sulfur at temperatures of 400 and 650 degrees C, with a carbon and sulfur mass ratio of 1:3. The capabilities of sulfur diffusing into the micropores of the activated carbons were significantly different between 400 and 650 degrees C, resulting in obvious dissimilarities in the sulfur content of the activated carbons. The sulfur-impregnated activated carbons were examined for the adsorptive capacity of gas-phase mercuric chloride (HgC1) by thermogravimetric analysis (TGA). The analytical precision of TGA was up to 10(-6) g at the inlet HgCl2 concentrations of 100, 300, and 500 microg/m3, for an adsorption time of 3 hr and an adsorption temperature of 150 degrees C, simulating the flue gas emitted from municipal solid waste (MSW) incinerators. Experimental results showed that sulfur modification can slightly reduce the specific surface area of activated carbons. High-surface-area activated carbons after sulfur modification had abundant mesopores and micropores, whereas low-surface-area activated carbons had abundant macropores and mesopores. Sulfur molecules were evenly distributed on the surface of the inner pores after sulfur modification, and the sulfur content of the activated carbons increased from 2-2.5% to 5-11%. After sulfur modification, the adsorptive capacity of HgCl2 for high-surface-area sulfurized activated carbons reached 1.557 mg/g (22 times higher than the virgin activated carbons). The injection of activated carbons was followed by fabric filtration, which is commonly used to remove HgCl2 from MSW incinerators. The residence time of activated carbons collected in the fabric filter is commonly about 1 hr, but the time required to achieve equilibrium is less than 10 min. Consequently, it is worthwhile to compare the adsorption rates of HgCl2 in the time intervals of < 10 and 10-60 min.

  10. Nanospace engineering of KOH activated carbon.

    Science.gov (United States)

    Romanos, J; Beckner, M; Rash, T; Firlej, L; Kuchta, B; Yu, P; Suppes, G; Wexler, C; Pfeifer, P

    2012-01-13

    This paper demonstrates that nanospace engineering of KOH activated carbon is possible by controlling the degree of carbon consumption and metallic potassium intercalation into the carbon lattice during the activation process. High specific surface areas, porosities, sub-nanometer (activation temperature. The process typically leads to a bimodal pore size distribution, with a large, approximately constant number of sub-nanometer pores and a variable number of supra-nanometer pores. We show how to control the number of supra-nanometer pores in a manner not achieved previously by chemical activation. The chemical mechanism underlying this control is studied by following the evolution of elemental composition, specific surface area, porosity, and pore size distribution during KOH activation and preceding H(3)PO(4) activation. The oxygen, nitrogen, and hydrogen contents decrease during successive activation steps, creating a nanoporous carbon network with a porosity and surface area controllable for various applications, including gas storage. The formation of tunable sub-nanometer and supra-nanometer pores is validated by sub-critical nitrogen adsorption. Surface functional groups of KOH activated carbon are studied by microscopic infrared spectroscopy.

  11. ESTIMATION OF ACTIVATED ENERGY OF DESORPTION OF n—HEXANE ON ACTIVATED CARBONS BY PTD TECHNIQUE

    Institute of Scientific and Technical Information of China (English)

    LIZhong; WANGHongjuan; 等

    2001-01-01

    In this paper,six kinds of activated carbons such as Ag+-activated carbon,Cu2+activated carbon,Fe3+-activated carbon,activated carbon,Ba2+-activated carbon and Ca2+activated carbon were prepared.The model for estimating activated energy of desorption was established.Temperature-programmed desorption(TPD)experiments were conducted to measure the TPD curves of n-hexanol and then estimate the activation energy for desorption of n-hexanol on the activated carbons.Results showed that the activation energy for the desorption of n-hexanol on the Ag+-activated carbon,the Cu2+-activated carbon and the Fe3+-activated carbon were higher than those of n-hexanol on the activated carbon,the Ca2+-activated carbon and the Ba2+-activated carbon.

  12. ESTIMATION OF ACTIVATED ENERGY OF DESORPTION OF n-HEXANE ON ACTIVATED CARBONS BY TPD TECHNIQUE

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In this paper, six kinds of activated carbons such as Ag+-activated carbon, Cu2+-activated carbon, Fe3+- activated carbon, activated carbon, Ba2+- activated carbon and Ca2+-activated carbon were prepared. The model for estimating activated energy of desorption was established. Temperature-programmed desorption (TPD) experiments were conducted to measure the TPD curves of n-hexanol and then estimate the activation energy for desorption of n-hexanol on the activated carbons. Results showed that the activation energy for the desorption of n-hexanol on the Ag+- activated carbon, the Cu2+- activated carbon and the Fe3+- activated carbon were higher than those of n-hexanol on the activated carbon, the Ca2+- activated carbon and the Ba2+- activated carbon.

  13. Antimicrobial Activity of Carbon-Based Nanoparticles

    Directory of Open Access Journals (Sweden)

    Solmaz Maleki Dizaj

    2015-03-01

    Full Text Available Due to the vast and inappropriate use of the antibiotics, microorganisms have begun to develop resistance to the commonly used antimicrobial agents. So therefore, development of the new and effective antimicrobial agents seems to be necessary. According to some recent reports, carbon-based nanomaterials such as fullerenes, carbon nanotubes (CNTs (especially single-walled carbon nanotubes (SWCNTs and graphene oxide (GO nanoparticles show potent antimicrobial properties. In present review, we have briefly summarized the antimicrobial activity of carbon-based nanoparticles together with their mechanism of action. Reviewed literature show that the size of carbon nanoparticles plays an important role in the inactivation of the microorganisms. As major mechanism, direct contact of microorganisms with carbon nanostructures seriously affects their cellular membrane integrity, metabolic processes and morphology. The antimicrobial activity of carbon-based nanostructures may interestingly be investigated in the near future owing to their high surface/volume ratio, large inner volume and other unique chemical and physical properties. In addition, application of functionalized carbon nanomaterials as carriers for the ordinary antibiotics possibly will decrease the associated resistance, enhance their bioavailability and provide their targeted delivery.

  14. Simulation and reliability analysis of shunt active power filter based on instantaneous reactive power theory

    Institute of Scientific and Technical Information of China (English)

    CUI Yu-long; LIU Hong; WANG Jing-qin; SUN Shu-guang

    2007-01-01

    This paper first discusses the operating principle ofinstantaneous reactive power theory. Then, the theory is introduced into shunt active power filter and its control scheme is studied. Finally, Matlab/Simulink power system toolbox is used to simulate the system. In the simulation model, as the most common harmonic source, 3-phase thyfistor bridge rectifier circuit is constructed.The simulation results before and after the shunt active filter was switched to the system corresponding to different firing angles of the thyristors are presented and analyzed, which demonstrate the practicability and reliability of the proposed shunt active filter scheme.

  15. A NEW METHOD TO CALCULATE COMPENSATION CURRENT IN PARALLEL ACTIVE POWER FILTER

    Directory of Open Access Journals (Sweden)

    Ahmet ALTINTAŞ

    2004-03-01

    Full Text Available Nowadays, active power filter plays an important role in reducing harmonic current and reactive power in power lines. The reliability and effectiveness of an active power filter depends basically on three characteristics. These are the modulation method, the design characteristics of the PWM modulator and the method implemented to generate compensation current. For the last one, there are many proposed methods. Most of them complicated and hence difficult to implement and adjust. In this study, a new method to calculate compensation current is improved and tested in single-phase parallel active power filter controlled by microcontroller. Experimental and simulation results are presented in the paper.

  16. Operational characteristics of efficient co-removal of H2S and NH3 in a horizontal biotrickling filter using exhausted carbon.

    Science.gov (United States)

    Jiang, Xia; Tay, Joo Hwa

    2010-04-15

    Odorous H(2)S and NH(3) gases were effectively biodegraded in a horizontal biotrickling filter (HBTF) packed with H(2)S-exhausted carbon. During the process, the operational characteristics including the distribution of degradation products, biomass accumulation and biological activity, carbon surface characteristics and pressure drop were investigated. The results show that the content of biodegradation products on carbon was low, i.e. 0.9-2.8 wt% S and 0.3-1.0 wt% N. The low content benefited the stable operation of the HBTF, due to preventing a toxic concentration of degradation products on packing bed over a long-term operation. The biomass was distributed evenly along the HBTF . This avoided the problems of bed clogging and activity loss. On the other hand, the deteriorated performance was observed due to the biomass accumulation over a long-term operation. Carbon surface characteristics in the HBTF remained almost unchanged. pH values of carbon were neutral and micropore structure of carbon remained relatively stable. In addition, the pressure drop in the HBTF was very low. These operational characteristics of the HBTF system significantly contributed to efficient co-removal of H(2)S and NH(3) in the HBTF over a long-term operation.

  17. Decontamination System Development of Radioative Activated Carbon using Micro-bubbles

    Energy Technology Data Exchange (ETDEWEB)

    Jeon, Jong seon; Kim, Wi soo [NESS, Daejeon (Korea, Republic of); Han, Byoung sub. [Enesys Co., Daejeon (Korea, Republic of)

    2016-10-15

    This study was aimed to develop a decontamination system by applying such technical characteristics that minimizes a generation of secondary wastes while decontaminating radiation wastes. The radioactive activated carbon is removed from the end-of-life air cleaning filter in replacement or decommission of nuclear power plant or nuclear facility. By removing radioactive activated carbon, the filter would be classified as a low radioactive contaminant. And thus the amount of radioactive wastes and the treatment cost would be decreased. We are in development of the activated carbon cleaning technique by utilizing micro-bubbles, which improve efficiency and minimize damage of activated carbon. The purpose of using micro-bubbles is to decontamination carbon micropore, which is difficult to access, by principle of cavitation phenomenon generated in collapse of micro-bubbles. In this study, we introduced the micro-bubble decontamination system developed to decontaminate activated carbon. For further researches, we will determine carbon weight change and the decontamination rate under the experimental conditions such as temperature and pH.

  18. Stability Analysis and Active Damping for LLCL-filter-Based Grid-Connected Inverters

    DEFF Research Database (Denmark)

    Huang, Min; Wang, Xiongfei; Loh, Poh Chiang

    2015-01-01

    to use either passive or active damping methods. This paper analyzes the stability of the LLCL-filter based grid-connected inverter and identifies a critical resonant frequency for the LLCL-filter when sampling and transport delays are considered. In a high resonant frequency region the active damping...... is not required but in a low resonant frequency region the active damping is necessary. The basic LLCL resonance damping properties of different feedback states based on a notch filter concept are also studied. Then an active damping method which is using the capacitor current feedback for LLCL......-filter is introduced. Based on this active damping method, a design procedure for the controller is given. Last, both simulation and experimental results are provided to validate the theoretical analysis of this paper....

  19. Electrochemical efficacy of a carboxylated multiwalled carbon nanotube filter for the removal of ibuprofen from aqueous solutions under acidic conditions.

    Science.gov (United States)

    Bakr, Ahmed Refaat; Rahaman, Md Saifur

    2016-06-01

    This study provides insight into the efficiency of a functionalized multiwalled carbon nanotube filter for the removal of an anti-inflammatory drug, ibuprofen, through conventional filtration and electrochemical filtration processes. A comparison was made between carboxylated multiwalled carbon nanotubes (MWNTs-COOH) and pristine multiwalled carbon nanotubes (MWNTs) in order to emphasize the enhanced performance of MWNTs-COOH for the removal of ibuprofen using an electrochemical filtration process under acidic conditions. Ibuprofen-removal trials were evaluated based on absorbance values obtained using a UV/Vis spectrophotometer, and possible degradation products were identified using liquid chromatography mass spectrometry (LC-MS). The results exhibited near complete removal of ibuprofen by MWNTs-COOH at lower applied potentials (2 V), at lower flow rates, and under acidic conditions, which can be attributed to the generation of superoxides and their active participation in simultaneous degradation of ibuprofen, and its by-products, under these conditions. At higher applied potential (3 V), the possible participation of both bulk indirect oxidation reactions, and direct electron transfer were hypothesized for the removal behavior over time (breakthrough). At 3 V under acidic conditions, near 100% removal of the target molecule was achieved and was attributed to the enhanced generation of electroactive species toward bulk chemical reactions and a possible contribution from direct electron transfer under these conditions. The degradation by-products of ibuprofen were effectively removed by allowing longer residence time during the filtration process. Moreover, the effect of temperature was studied, yet showed a non-significant effect on the overall removal process.

  20. Robust Design of LCL-Filters for Active Damping in Grid Converters

    DEFF Research Database (Denmark)

    Alzola, Rafael Pena; Liserre, Marco; Blaabjerg, Frede

    2013-01-01

    elements. However, large variations in the grid inductance and resonances arising from parallel converters may still compromise the system stability. This calls for a robust design of LCL-filters with active damping. This paper proposes a design flow with little iteration for two well-known methods, namely......Grid converters require a simple inductor or an LCL-filter to limit the current ripples. The LCL-filter is nowadays the preferred solution as it allows lower inductance values. In order to solve the stability concerns, active damping is preferred to passive damping since it does not use dissipative...... lead-lag network and current capacitor feedback. The proposed formulas for the resonance frequency, grid and converter inductance ratio, and capacitance of the LCL-filter allow calculating all the LCL-filter parameters. An estimation for the achieved Total Harmonic Distortion (THD) of the grid current...

  1. Immobilization biological activated carbon used in advanced drinking water treatment

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Bacteria separated from a mature filter bed of groundwater treatment plants were incubated in a culture media containing iron and manganese. A consortium of 5 strains of bacteria removing iron and manganese were obtained by repeated enrichment culturing. It was shown from the experiments of effect factors that ironmanganese removal bacteria in the culture media containing both Fe and Mn grew better than in that containing only Fe, however, they were unable to grow in the culture media containing only Mn. When comparing the bacteria biomass in the case ofρ (DO) =2.8 mg/L andρ (DO) =9.0 mg/L, no significant difference was found.The engineering bacteria removing the organic and the bacteria removing iron and manganese were simultaneously inoculated into activated carbon reactor to treat the effluent of distribution network. The experimental results showed that by using IBAC ( Immobilization Biological Activated Carbon) treatment, the removal efficiency of iron, manganese and permanganate index was more than 98% , 96% and 55% , respectively. After the influent with turbidity of 1.5 NTU, color of 25 degree and offensive odor was treated, the turbidity and color of effluence were less than 0.5 NTU and 15 degree, respectively, and it was odorless. It is determined that the cooperation function of engineering bacteria and activated carbon achieved advanced drinking water treatment.

  2. Active Cancellation of Acoustical Resonances with an FPGA FIR Filter

    CERN Document Server

    Ryou, Albert

    2016-01-01

    We present a novel approach to enhancing the bandwidth of a feedback-controlled mechanical system by digitally canceling acoustical resonances (poles) and anti-resonances (zeros) in the open-loop response via an FPGA FIR filter. By performing a real-time convolution of the feedback error signal with an inverse filter, we can suppress arbitrarily many poles and zeros below 100 kHz, each with a linewidth down to 10 Hz. We demonstrate the efficacy of this technique by canceling the ten largest mechanical resonances and anti-resonances of a high-finesse optical resonator, thereby enhancing the unity gain frequency by more than an order of magnitude. This approach is applicable to a broad array of stabilization problems including optical resonators, external cavity diode lasers, and scanning tunneling microscopes, and points the way to applying modern optimal control techniques to intricate linear acoustical systems.es to intricate linear acoustical systems.

  3. Active cancellation of acoustical resonances with an FPGA FIR filter

    Science.gov (United States)

    Ryou, Albert; Simon, Jonathan

    2017-01-01

    We present a novel approach to enhancing the bandwidth of a feedback-controlled mechanical system by digitally canceling acoustical resonances (poles) and anti-resonances (zeros) in the open-loop response via an FPGA FIR filter. By performing a real-time convolution of the feedback error signal with an inverse filter, we can suppress arbitrarily many poles and zeros below 100 kHz, each with a linewidth down to 10 Hz. We demonstrate the efficacy of this technique by canceling the ten largest mechanical resonances and anti-resonances of a high-finesse optical resonator, thereby enhancing the unity gain frequency by more than an order of magnitude. This approach is applicable to a broad array of stabilization problems including optical resonators, external cavity diode lasers, and scanning tunneling microscopes and points the way to applying modern optimal control techniques to intricate linear acoustical systems.

  4. Active cancellation of acoustical resonances with an FPGA FIR filter.

    Science.gov (United States)

    Ryou, Albert; Simon, Jonathan

    2017-01-01

    We present a novel approach to enhancing the bandwidth of a feedback-controlled mechanical system by digitally canceling acoustical resonances (poles) and anti-resonances (zeros) in the open-loop response via an FPGA FIR filter. By performing a real-time convolution of the feedback error signal with an inverse filter, we can suppress arbitrarily many poles and zeros below 100 kHz, each with a linewidth down to 10 Hz. We demonstrate the efficacy of this technique by canceling the ten largest mechanical resonances and anti-resonances of a high-finesse optical resonator, thereby enhancing the unity gain frequency by more than an order of magnitude. This approach is applicable to a broad array of stabilization problems including optical resonators, external cavity diode lasers, and scanning tunneling microscopes and points the way to applying modern optimal control techniques to intricate linear acoustical systems.

  5. Production and characterization of granular activated carbon from activated sludge

    Directory of Open Access Journals (Sweden)

    Z. Al-Qodah

    2009-03-01

    Full Text Available In this study, activated sludge was used as a precursor to prepare activated carbon using sulfuric acid as a chemical activation agent. The effect of preparation conditions on the produced activated carbon characteristics as an adsorbent was investigated. The results indicate that the produced activated carbon has a highly porous structure and a specific surface area of 580 m²/g. The FT-IR analysis depicts the presence of a variety of functional groups which explain its improved adsorption behavior against pesticides. The XRD analysis reveals that the produced activated carbon has low content of inorganic constituents compared with the precursor. The adsorption isotherm data were fitted to three adsorption isotherm models and found to closely fit the BET model with R² equal 0.948 at pH 3, indicating a multilayer of pesticide adsorption. The maximum loading capacity of the produced activated carbon was 110 mg pesticides/g adsorbent and was obtained at this pH value. This maximum loading was found experimentally to steeply decrease as the solution pH increases. The obtained results show that activated sludge is a promising low cost precursor for the production of activated carbon.

  6. Activated coconut shell charcoal carbon using chemical-physical activation

    Science.gov (United States)

    Budi, Esmar; Umiatin, Nasbey, Hadi; Bintoro, Ridho Akbar; Wulandari, Futri; Erlina

    2016-02-01

    The use of activated carbon from natural material such as coconut shell charcoal as metal absorbance of the wastewater is a new trend. The activation of coconut shell charcoal carbon by using chemical-physical activation has been investigated. Coconut shell was pyrolized in kiln at temperature about 75 - 150 °C for about 6 hours in producing charcoal. The charcoal as the sample was shieved into milimeter sized granule particle and chemically activated by immersing in various concentration of HCl, H3PO4, KOH and NaOH solutions. The samples then was physically activated using horizontal furnace at 400°C for 1 hours in argon gas environment with flow rate of 200 kg/m3. The surface morphology and carbon content of activated carbon were characterized by using SEM/EDS. The result shows that the pores of activated carbon are openned wider as the chemical activator concentration is increased due to an excessive chemical attack. However, the pores tend to be closed as further increasing in chemical activator concentration due to carbon collapsing.

  7. Preparation and characterization of activated carbons from rice ...

    African Journals Online (AJOL)

    atmosphere followed by activation using CO2 gas at various temperatures and ... available carbons, such as coal and coconut shells (Anon 1992). The ash ... extraction of the chemical from the carbonized char an activated carbon is obtained.

  8. Bimodal micropore size distribution in active carbons

    Energy Technology Data Exchange (ETDEWEB)

    Vartapetyan, R.S.; Voloshchuk, A.M.; Limonov, N.A.; Romanov, Y.A. (Russian Academy of Sciences, Moscow (Russian Federation). Inst. of Physical Chemistry)

    1993-03-01

    The porous structure of active carbon was compared with that of the original mineral coal and its carbonization products. The parameters of the porous structure were calculated from the adsorption isotherms of CO[sub 2] (298 K) and H[sub 2]O (293 K). It was shown that carbonization of the original coal at 1120 K causes changes in the chemical composition, consolidation of the part which is amorphous to X-rays, generation of an ordered defect-containing structure on its basis, an increase in the volume of the micropores, and a decrease in the mean diameter. Activation of the carbonized coal affords a microporous structure with a bimodal size distribution.

  9. Genetic Algorithm-Based Design of the Active Damping for an LCL-Filter Three-Phase Active Rectifier

    DEFF Research Database (Denmark)

    Liserre, Marco; Aquila, Antonio Dell; Blaabjerg, Frede

    2004-01-01

    of this filter is easily done, for a wide range of sampling frequencies, with the use of genetic algorithms. This method is used only for the optimum choice of the parameters in the filter, and an on-line implementation is not needed. Thus the resulting active damping solution does not need new sensors...

  10. Commutation effect of Adjustable Speed Drives due to installation of active harmonic filters

    DEFF Research Database (Denmark)

    Asiminoaei, Lucian; Kalaschnikow, Sergej; Hansen, Steffan;

    2011-01-01

    The success of designing an industrial installation with Active Filters depends on how precise the load profile of the application is known, because this determines the amount of harmonic currents to be compensated. However, once the Active Filter is added to the installation, the harmonic curren...... and sizing industrial Active Filter applications together with Adjustable Speed Drives. Examples of using the developed toolbox are given in the paper, supported with practical measurements....... the commutation behavior of Adjustable Speed Drives when their harmonic currents are compensated by a Shunt Active Filter. The method is formulated as an analytical computation algorithm verified by simulations. Further on the method is implemented in a Harmonic Calculation Toolbox which facilitates calculation...

  11. Application of Wavelet-based Active Power Filter in Accelerator Magnet Power Supply

    CERN Document Server

    Xiaoling, Guo

    2013-01-01

    As modern accelerators demand excellent stability to magnet power supply (PS), it is necessary to decrease harmonic currents passing magnets. Aim at depressing rappel current from PS in Beijing electron-positron collider II, a wavelet-based active power filter (APF) is proposed in this paper. APF is an effective device to improve the quality of currents. As a countermeasure to these harmonic currents, the APF circuit generates a harmonic current, countervailing harmonic current from PS. An active power filter based on wavelet transform is proposed in this paper. Discrete wavelet transform is used to analyze the harmonic components in supply current, and active power filter circuit works according to the analysis results. At end of this paper, the simulation and experiment results are given to prove the effect of the mentioned Active power filter.

  12. Implementation of FFT Algorithm using DSP TMS320F28335 for Shunt Active Power Filter

    Science.gov (United States)

    Patel, Pinkal Jashvantbhai; Patel, Rajesh M.; Patel, Vinod

    2016-07-01

    This work presents simulation, analysis and experimental verification of Fast Fourier Transform (FFT) algorithm for shunt active power filter based on three-level inverter. Different types of filters can be used for elimination of harmonics in the power system. In this work, FFT algorithm for reference current generation is discussed. FFT control algorithm is verified using PSIM simulation results with DLL block and C-code. Simulation results are compared with experimental results for FFT algorithm using DSP TMS320F28335 for shunt active power filter application.

  13. Implementation of FFT Algorithm using DSP TMS320F28335 for Shunt Active Power Filter

    Science.gov (United States)

    Patel, Pinkal Jashvantbhai; Patel, Rajesh M.; Patel, Vinod

    2017-06-01

    This work presents simulation, analysis and experimental verification of Fast Fourier Transform (FFT) algorithm for shunt active power filter based on three-level inverter. Different types of filters can be used for elimination of harmonics in the power system. In this work, FFT algorithm for reference current generation is discussed. FFT control algorithm is verified using PSIM simulation results with DLL block and C-code. Simulation results are compared with experimental results for FFT algorithm using DSP TMS320F28335 for shunt active power filter application.

  14. Converting Poultry Litter into Activated Carbon

    Science.gov (United States)

    Disposal of animal manure is one of the biggest problems facing agriculture today. Now new technology has been designed to covert manure into environmentally friendly and highly valued activated carbon. When pelletized and activated under specific conditions, the litter becomes a highly porous mat...

  15. Analysis and Sliding Mode Control of Four-Wire Three-Leg Shunt Active Power Filter

    OpenAIRE

    Farid Hamoudi; Hocine Amimeur

    2015-01-01

    In this paper, the analysis and the sliding mode control application for a shunt active filter is presented. The active filter is based on a three-leg split-capacitor voltage source inverter which is used to compensate harmonics and unbalance in the phase currents, and therefore to cancel neutral current. The proposed sliding mode control is formulated from the multivariable state model established in dq0 frames. The selection of the sliding mode functions takes in account simultaneously, the...

  16. New controllability criteria for 3-phase 4-wire inverters applied to shunt active power filters

    OpenAIRE

    Perales Esteve, Manuel Ángel; Sánchez Segura, Juan Antonio; Torre, A. (Alberto) de la; Carrasco Solís, Juan Manuel; García Franquelo, Leopoldo; Terrón, L.

    2002-01-01

    In shunt active filter applications, the 3-phase 4-wire topology is frequently used when dealing with unbalanced loads containing zero sequence components. A new design criteria for this topology is presented, based on the well-known existing method for the 3-phase 3-wire system. Simulation and experimental results confirms the validity of this new criteria, providing an easy method for the design of the reactive elements involved in a shunt active filter.

  17. Carbon-cryogel hierarchical composites as effective and scalable filters for removal of trace organic pollutants from water.

    Science.gov (United States)

    Busquets, Rosa; Ivanov, Alexander E; Mbundi, Lubinda; Hörberg, Sofia; Kozynchenko, Oleksandr P; Cragg, Peter J; Savina, Irina N; Whitby, Raymond L D; Mikhalovsky, Sergey V; Tennison, Stephen R; Jungvid, Hans; Cundy, Andrew B

    2016-11-01

    Effective technologies are required to remove organic micropollutants from large fluid volumes to overcome present and future challenges in water and effluent treatment. A novel hierarchical composite filter material for rapid and effective removal of polar organic contaminants from water was developed. The composite is fabricated from phenolic resin-derived carbon microbeads with controllable porous structure and specific surface area embedded in a monolithic, flow permeable, poly(vinyl alcohol) cryogel. The bead-embedded monolithic composite filter retains the bulk of the high adsorptive capacity of the carbon microbeads while improving pore diffusion rates of organic pollutants. Water spiked with organic contaminants, both at environmentally relevant concentrations and at high levels of contamination, was used to determine the purification limits of the filter. Flow through tests using water spiked with the pesticides atrazine (32 mg/L) and malathion (16 mg/L) indicated maximum adsorptive capacities of 641 and 591 mg pollutant/g carbon, respectively. Over 400 bed volumes of water contaminated with 32 mg atrazine/L, and over 27,400 bed volumes of water contaminated with 2 μg atrazine/L, were treated before pesticide guideline values of 0.1 μg/L were exceeded. High adsorptive capacity was maintained when using water with high total organic carbon (TOC) levels and high salinity. The toxicity of water filtrates was tested in vitro with human epithelial cells with no evidence of cytotoxicity after initial washing.

  18. A novel modular approach to active power-line harmonic filtering in distribution systems

    Energy Technology Data Exchange (ETDEWEB)

    El Shatshat, R.A.

    2001-07-01

    An efficient and reliable modular active harmonic filter system was developed as a cost-effective solution to the problem of harmonics. The newly developed filter system include several CSC modules that are each dedicated to filter a specific harmonic. Overall switching losses are minimized because selective harmonics is eliminated. Two ADALINEs are proposed for the filter controller. One extracts the fundamental and harmonic components of the distorted current, and the other estimates the line voltage. The main features of the new filter system are high speed, accuracy of ADALINE, self synchronizing harmonic tracking, intelligence and robustness of the controller, optimum dc value, and minimal converter losses. Simulation results were also presented to demonstrate the effectiveness of the system.

  19. Active Damping Techniques for LCL-Filtered Inverters-Based Microgrids

    DEFF Research Database (Denmark)

    Lorzadeh, Iman; Firoozabadi, Mehdi Savaghebi; Askarian Abyaneh, Hossein

    2015-01-01

    LCL-type filters are widely used in gridconnected voltage source inverters, since it provides switching ripples reduction with lower cost and weight than the L-type counterpart. However, the inclusion of LCL-filters in voltage source inverters complicates the current control design regarding system...... the different active damping approaches for grid-connected inverters with LCL filters, which are based on high-order filters and additional feedbacks methods. These techniques are analyzed and discussed in detail....... stability issues; because an inherent resonance peak appears due to zero impedance at that resonance frequency. Moreover, in grid-interactive low-voltage microgrids, the interactions among the LCL-filtered-based parallel inverters may result in a more complex multiresonance issue which may compromise...

  20. Cathodoluminescence of Cr-doped diamond-like carbon film by filtered cathodic vacuum arc plasma

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Meng-Wen; Jao, Jui-Yun [Department of Materials Science and Engineering, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 402, Taiwan (China); Lin, Chun-Chun; Hsieh, Wei-Jen; Yang, Yu-Hsiang [Department of Materials Science and Engineering, National Tsing Hua University, 101, Sec. 2, Kuang-Fu Road, Hsinchu 300, Taiwan (China); Cheng, Li-Shin; Shieu, F.S. [Department of Materials Science and Engineering, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 402, Taiwan (China); Shih, Han C., E-mail: hcshih@mx.nthu.edu.tw [Department of Materials Science and Engineering, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 402, Taiwan (China); Department of Materials Science and Engineering, National Tsing Hua University, 101, Sec. 2, Kuang-Fu Road, Hsinchu 300, Taiwan (China); Institute of Materials Science and Nanotechnology, Chinese Culture University, 55 Hwa Kang Road, Yang Ming Shan, Taipei 111, Taiwan (China)

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer The formation of the DLC:Cr films dependent on the flow rates of C{sub 2}H{sub 2}/Ar have been achieved in our FCVA plasma. Black-Right-Pointing-Pointer The amorphous DLC:Cr have high sp{sup 2} content can be completely converted to nanocrystalline Cr{sub 3}C{sub 2}. Black-Right-Pointing-Pointer The effect of doping with Cr is apparently to change the band structure of the DLC and its consequent cathodoluminescence property. - Abstract: Cr doped diamond-like carbon (DLC:Cr) film was synthesized in various flow rates of C{sub 2}H{sub 2}/Ar under a substrate voltage of -50 V at 500 Degree-Sign C by a filtered cathodic vacuum arc plasma. This work has found that the structure of the films was correlated to the flow rate of C{sub 2}H{sub 2}/Ar but the luminescence properties are similar. The cathodoluminescence spectra of DLC:Cr films obtained at 1.9-2.4 eV verifies that the luminescence from the films is in the visible region. The incorporation of Cr into the carbon network results in red emission shifted to 1.99 eV and the orange emission (2.03 eV) also appeared due to the transitions between chromium-related electron levels and {sigma}* states. The peak at 2.10 eV may result from the defects of the structures in DLC:Cr films.

  1. Novel catalytic applications of carbon nanofibers on sintered metal fibers filters as structured supports

    OpenAIRE

    2009-01-01

    Supported metal catalysts are important from both an industrial and a scientific point of view. They are used, amongst others, in large-scale processes such as catalytic reforming, hydrotreating, polymerization reactions and hydrogenations. Often, these catalysts consist of nanosized metal particles deposited on a suitable support, which acts as an anchor for the active phase and, in several cases, contributes to improve the overall catalyst performances. The growth of carbon nanofibers on si...

  2. Novel catalytic applications of carbon nanofibers on sintered metal fibers filters as structured supports

    OpenAIRE

    2008-01-01

    Supported metal catalysts are important from both an industrial and a scientific point of view. They are used, amongst others, in large-scale processes such as catalytic reforming, hydrotreating, polymerization reactions and hydrogenations. Often, these catalysts consist of nanosized metal particles deposited on a suitable support, which acts as an anchor for the active phase and, in several cases, contributes to improve the overall catalyst performances. The growth of carbon nanofibers on si...

  3. A novel activated carbon for supercapacitors

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Haijie [Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Hunan 411105 (China); Liu, Enhui, E-mail: liuenhui99@sina.com.cn [Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Hunan 411105 (China); Xiang, Xiaoxia; Huang, Zhengzheng; Tian, Yingying; Wu, Yuhu; Wu, Zhilian; Xie, Hui [Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Hunan 411105 (China)

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer A novel activated carbon was prepared from phenol-melamine-formaldehyde resin. Black-Right-Pointing-Pointer The carbon has large surface area with microporous, and high heteroatom content. Black-Right-Pointing-Pointer Heteroatom-containing functional groups can improve the pseudo-capacitance. Black-Right-Pointing-Pointer Physical and chemical properties lead to the good electrochemical properties. -- Abstract: A novel activated carbon has been prepared by simple carbonization and activation of phenol-melamine-formaldehyde resin which is synthesized by the condensation polymerization method. The morphology, thermal stability, surface area, elemental composition and surface chemical composition of samples have been investigated by scanning electron microscope, thermogravimetry and differential thermal analysis, Brunauer-Emmett-Teller measurement, elemental analysis and X-ray photoelectron spectroscopy, respectively. Electrochemical properties have been studied by cyclic voltammograms, galvanostatic charge/discharge, and electrochemical impedance spectroscopy measurements in 6 mol L{sup -1} potassium hydroxide. The activated carbon shows good capacitive behavior and the specific capacitance is up to 210 F g{sup -1}, which indicates that it may be a promising candidate for supercapacitors.

  4. Activated charcoal filter effectively reduces p-benzosemiquinone from the mainstream cigarette smoke and prevents emphysema

    Indian Academy of Sciences (India)

    Neekkan Dey; Archita Das; Arunava Ghosh; Indu B Chatterjee

    2010-06-01

    In this paper, we have made a comparative evaluation of the cytotoxicity and pathophysiological effects of mainstream smoke from cellulose acetate (CA)-filtered cigarettes with that of charcoal-filtered cigarettes developed in our laboratory. Previously, we had demonstrated that the mainstream smoke from an Indian CA-filtered commercial cigarette contains p-benzosemiquinone (p-BSQ), a major, highly toxic, long-lived water-soluble radical. Here, we have examined 16 brands of different CA-filtered cigarettes including Kentucky research cigarettes, and observed that mainstream smoke from all the cigarettes contains substantial amounts of p-BSQ (100–200 g/cigarette). We also show that when the CA filter is replaced by a charcoal filter, the amount of p-BSQ in the mainstream smoke is reduced by 73–80%, which is accompanied by a reduction of carbonyl formation in bovine serum albumin to the extent of 70–90%. The charcoal filter also prevented cytotoxicity in A549 cells as evidenced by MTT assay, apoptosis as evidenced by FACS analysis, TUNEL assay, overexpression of Bax, activation of p53 and caspase 3, as well as emphysematous lung damage in a guinea pig model as seen by histology and morphometric analysis. The results indicate that the charcoal filter developed in our laboratory may protect smokers from cigarette smoke-induced cytotoxity, protein modification, apoptosis and emphysema.

  5. Endotoxin release from biologically active bench-scale drinking water anthracite/sand filters

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, W.B.; Mayfield, C.I.; Huck, P.M. [University of Waterloo, Waterloo, ON (Canada). Dept. of Civil and Environmental Engineering

    2008-12-15

    Endotoxin release from biologically active dual-media (anthracite/sand) bench-scale drinking water filters was investigated. The biological filters were typically net producers of endotoxin during normal operation with mean concentrations increasing from 6 endotoxin units (EU)/mL to 16 EU/mL in filter influent and effluent, respectively. The filter operating condition resulting in the greatest release of endotoxin occurred upon shutdown and subsequent restart, with the highest observed filter effluent endotoxin concentration being 745 EU/mL in the first pore volume following the return of flow through the filter. Effluent samples collected following filter shutdowns were chlorinated to determine the effect of bacterial cell death on endotoxin release. Chlorination did not induce immediate 'dumping' of endotoxin, nor did holding the chlorinated samples for 5 d result in an increase in aqueous endotoxin concentration. In addition to endotoxin, measurable quantities of potassium were detected in the interstitial water in the biofilter during shutdown periods. In order to reduce potential risk to dialysis patients and humidifier users, it is recommended that, following even short biofilter shutdowns, filters should be immediately backwashed or, failing this, the first five pore volumes of effluent water be discharged to waste to allow endotoxin levels to return to pre-shutdown values.

  6. The multilayered structure of ultrathin amorphous carbon films synthesized by filtered cathodic vacuum arc deposition

    KAUST Repository

    Wang, Na

    2013-08-01

    The structure of ultrathin amorphous carbon (a-C) films synthesized by filtered cathodic vacuum arc (FCVA) deposition was investigated by high-resolution transmission electron microscopy, electron energy loss spectroscopy, and x-ray photoelectron spectroscopy. Results of the plasmon excitation energy shift and through-thickness elemental concentration show a multilayered a-C film structure comprising an interface layer consisting of C, Si, and, possibly, SiC, a buffer layer with continuously increasing sp 3 fraction, a relatively thicker layer (bulk film) of constant sp 3 content, and an ultrathin surface layer rich in sp 2 hybridization. A detailed study of the C K-edge spectrum indicates that the buffer layer between the interface layer and the bulk film is due to the partial backscattering of C+ ions interacting with the heavy atoms of the silicon substrate. The results of this study provide insight into the minimum thickness of a-C films deposited by FCVA under optimum substrate bias conditions. Copyright © 2013 Materials Research Society.

  7. Interaction between fluorescein isothiocyanate and carbon dots: Inner filter effect and fluorescence resonance energy transfer

    Science.gov (United States)

    Liu, Huabing; Xu, Chaoyong; Bai, Yanli; Liu, Lin; Liao, Dongmei; Liang, Jiangong; Liu, Lingzhi; Han, Heyou

    2017-01-01

    Carbon dots (CDs) have been widely used for the preparation of multifunctional probes by conjugation with organic fluorescent dyes. However, the effect of organic fluorescent dyes on CDs still remains poorly understood. Herein, the effect of fluorescein isothiocyanate (FITC) on CDs was explored by spectroscopic techniques at pH 5.1, 7.0 and 9.0. The fluorescent intensity of CDs was found to be quenched gradually after mixing directly with different concentrations of FITC, but the fluorescent lifetime of CDs remained unchanged. According to the results of UV-vis absorption spectra and fluorescent lifetime measurements, a pH-dependent inner filter effect (IFE) between CDs and FITC was proposed. However, the fluorescent lifetime of CDs deceased after their conjugation with FITC, implying the fluorescence resonance energy transfer (FRET) between CDs and FITC. This study has revealed two different effects of FITC on CDs with varying pH values and provided useful theoretical guidelines for further research on the interaction between other nanoparticles and fluorophores.

  8. Robust Active Damping Control of LCL Filtered Grid Connected Converter Based Active Disturbance Rejection Control

    DEFF Research Database (Denmark)

    Abdeldjabar, Benrabah; Xu, Dianguo; Wang, Xiongfei;

    2016-01-01

    This paper deals with the problem of LCL filter resonance in grid connected inverter control. The system equations are reformulated to allow the application of the active disturbance rejection control (ADRC). The resonance, assumed unknown, is treated as a disturbance, then estimated and mitigated....... By using this new robust control, a high level of performance is achieved with a minimum complexity in the controller design, and without any adaptive algorithm. It is demonstrated that the true quality of the control system is obtained by the proposed solution. Furthermore, it is shown that this control...... is robust against parameter variations and disturbances....

  9. A novel modular approach to active power-line harmonic filtering in distribution systems

    Science.gov (United States)

    El Shatshat, Ramadan A.

    The objective of this research is to develop an efficient and reliable modular active harmonic filter system to realize a cost-effective solution to the harmonic problem. The proposed filter system consists of a number CSC modules, each dedicated to filter a specific harmonic of choice (Frequency-Splitting Approach). The power rating of the modules will decrease and their switching frequency will increase as the order of the harmonic to be filtered is increased. The overall switching losses are minimized due to the selected harmonic elimination and balanced a "power rating"-"switching frequency" product. Two ADALINEs are proposed as a part of the filter controller for processing the signals obtained from the power-line. One ADALINE (the Current ADALINE) extracts the fundamental and harmonic components of the distorted current. The other ADALINE (the Voltage ADALINE) estimates the line voltage. The outputs of both ADALINEs are used to construct the modulating signals of the filter modules. The proposed controller decides which CSC filter module(s) is connected to the electric grid. The automated connection of the corresponding filter module(s) is based on decision-making rules in such a way that the IEEE 519-1992 limits are not violated. The information available on the magnitude of each harmonic component allows us to select the active filter bandwidth (i.e., the highest harmonic to be suppressed). This will result in more efficiency and higher performance. The proposed controller adjusts the I dc in each CSC module according to the present magnitude of the corresponding harmonic current. This results in optimum dc-side current value and minimal converter losses. The comparison of the proposed modular active filter scheme and the conventional one converter scheme on practical use in industry is presented. This comparison shows that the proposed solution is more economical, reliable and flexible compared to conventional one. High speed and accuracy of ADALINE, self

  10. The Adsorption Mechanism of Modified Activated Carbon on Phenol

    OpenAIRE

    Lin J. Q.; Yang S. E.; Duan J. M.; Wu J.J.; Jin L. Y.; Lin J. M.; Deng Q. L.

    2016-01-01

    Modified activated carbon was prepared by thermal treatment at high temperature under nitrogen flow. The surface properties of the activated carbon were characterized by Boehm titration, BET and point of zero charge determination. The adsorption mechanism of phenol on modified activated carbon was explained and the adsorption capacity of modified activated carbon for phenol when compared to plain activated carbon was evaluated through the analysis of adsorption isotherms, thermodynamic and ki...

  11. Activated Carbon, Carbon Nanofiber and Carbon Nanotube Supported Molybdenum Carbide Catalysts for the Hydrodeoxygenation of Guaiacol

    Directory of Open Access Journals (Sweden)

    Eduardo Santillan-Jimenez

    2015-03-01

    Full Text Available Molybdenum carbide was supported on three types of carbon support—activated carbon; multi-walled carbon nanotubes; and carbon nanofibers—using ammonium molybdate and molybdic acid as Mo precursors. The use of activated carbon as support afforded an X-ray amorphous Mo phase, whereas crystalline molybdenum carbide phases were obtained on carbon nanofibers and, in some cases, on carbon nanotubes. When the resulting catalysts were tested in the hydrodeoxygenation (HDO of guaiacol in dodecane, catechol and phenol were obtained as the main products, although in some instances significant amounts of cyclohexane were produced. The observation of catechol in all reaction mixtures suggests that guaiacol was converted into phenol via sequential demethylation and HDO, although the simultaneous occurrence of a direct demethoxylation pathway cannot be discounted. Catalysts based on carbon nanofibers generally afforded the highest yields of phenol; notably, the only crystalline phase detected in these samples was Mo2C or Mo2C-ζ, suggesting that crystalline Mo2C is particularly selective to phenol. At 350 °C, carbon nanofiber supported Mo2C afforded near quantitative guaiacol conversion, the selectivity to phenol approaching 50%. When guaiacol HDO was performed in the presence of acetic acid and furfural, guaiacol conversion decreased, although the selectivity to both catechol and phenol was increased.

  12. Modeling & Analysis of Shunt Active Power Filter Using IRP Theory Fed to Induction Drive

    Directory of Open Access Journals (Sweden)

    PABBISETTY SAI SUJATHA

    2014-10-01

    Full Text Available Utility distribution networks have sensitive industrial loads and critical commercial operations suffer from various types of outages and service interruptions which can cost significant financial losses. Because of sensitivity of consumers on power quality and advancement in power electronics. Active power filter technology is the most efficient way to compensate reactive power and cancel out low order harmonics generated by nonlinear loads. The shunt active power filter was considered to be the most basic configuration for the APF. This paper reviews the basic principle of shunt active power filter, along with the current tracking circuit based on the instantaneous reactive power theory and the main circuit performing as an inverter with PWM hysteresis control. The instantaneous active and reactive current component (id-iq method and instantaneous active and reactive power (p-q method are two control strategies which are extensively used in active filters. A shunt active filter based on the instantaneous active and reactive current component (id-iq method is proposed. This method aims to compensate harmonic and first harmonic unbalance. A Comprehensive control method is analyzed and a harmonic Compensation simulation is conducted, the result of which verifies The harmonic detection algorithm is well-proposed and the power Quality of the grid is overall-enhanced. The results are obtained using MATLAB/SIMULINK software.

  13. Performance of Spent Mushroom Farming Waste (SMFW) Activated Carbon for Ni (II) Removal

    Science.gov (United States)

    Desa, N. S. Md; Ghani, Z. Ab; Talib, S. Abdul; Tay, C. C.

    2016-07-01

    The feasibility of a low cost agricultural waste of spent mushroom farming waste (SMFW) activated carbon for Ni(II) removal was investigated. The batch adsorption experiments of adsorbent dosage, pH, contact time, metal concentration, and temperature were determined. The samples were shaken at 125 rpm, filtered and analyzed using ICP-OES. The fifty percent of Ni(II) removal was obtained at 0.63 g of adsorbent dosage, pH 5-6 (unadjusted), 60 min contact time, 50 mg/L Ni(II) concentration and 25 °C temperature. The evaluated SMFW activated carbon showed the highest performance on Ni(II) removal compared to commercial Amberlite IRC86 resin and zeolite NK3. The result indicated that SMFW activated carbon is a high potential cation exchange adsorbent and suitable for adsorption process for metal removal. The obtained results contribute toward application of developed SMFW activated carbon in industrial pilot study.

  14. Active power filter for the reduction of the harmonic distortion and fundamental reactive power with improved dynamic response

    Energy Technology Data Exchange (ETDEWEB)

    Voncina, D.; Nastran, J.; Cajhen, R.; Nedeljkovic, D. [Ljubljana Univ. (Slovenia). Faculty of Electrical Engineering and Computer Science

    1995-12-31

    The parallel active power filter for nonlinear loads is described. First the method for extracting the fundamental active component from the load current, based on the combined analogue and digital signal processing is presented in detail. The load current is filtered by a precision analogue circuit. The phase and the amplitude of the load current fundamental component is passed to the microcontroller to calculate its active component. The implemented control principle provides fast response of the actual filter current. The results, obtained from the experimental circuit, illustrate the active filter`s performance in steady state and during load transients. 14 refs, 10 figs

  15. Indirect Control of a low power Single-Phase Active Power Filter

    Directory of Open Access Journals (Sweden)

    SILVIU EPURE

    2010-12-01

    Full Text Available This paper deals with a low power, single phase active filter used to compensate nonlinear loads. The filter uses the indirect control method and it is based on a particular connection between filter, polluting load and grid to avoid timeconsuming mathematic operations or signal processing computations and assures good rejection of harmonic currents injected by the nonlinear load into the grid. A scale model was first simulated in Simulink and then physically implemented. The paper presents simulation and experimental results, and highlight problems encountered during experiments.

  16. Properties of boron and phosphorous incorporated tetrahedral amorphous carbon films grown using filtered cathodic vacuum arc process

    Energy Technology Data Exchange (ETDEWEB)

    Panwar, O.S., E-mail: ospanwar@mail.nplindia.ernet.in [Plasma Processed Materials Group, National Physical Laboratory (CSIR), Dr. K.S. Krishnan Road, New Delhi 110012 (India); Khan, Mohd Alim [Plasma Processed Materials Group, National Physical Laboratory (CSIR), Dr. K.S. Krishnan Road, New Delhi 110012 (India); Satyanarayana, B.S. [40, Sreeniketan, NDSE 24, New Delhi 110096 (India); Kumar, Sushil; Ishpal [Plasma Processed Materials Group, National Physical Laboratory (CSIR), Dr. K.S. Krishnan Road, New Delhi 110012 (India)

    2010-04-15

    This paper reports the electrical, mechanical, structural and field emission properties of as grown and also boron and phosphorous incorporated tetrahedral amorphous carbon (ta-C) films, deposited using a filtered cathodic vacuum arc process. The effect of varying boron and phosphorous content (up to 2.0 at.% in to ta-C) on the conductivity ({sigma}{sub D}), activation energy ({Delta}E{sub 1}), hardness, microstructure, emission threshold (E{sub turn-ON}) and emission current density (J) at 12.5 V/{mu}m of ta-C: B and ta-C: P films deposited at a high negative substrate bias of -300 V are reported. It is observed that both boron and phosphorous incorporation leads to a nearly an order increase in {sigma}{sub D} and corresponding decrease in {Delta}E{sub 1} and a slight increase in hardness as compared to as grown ta-C films. In the case of field assisted electron emission, it is observed that E{sub turn-ON} increases and J decreases. The changes are attributed to the changes in the sp{sup 3}/sp{sup 2} ratio of the films due to boron and phosphorous incorporation. The effect of boron on ta-C is to give a p-type effect whereas the effect of phosphorous gives n-type doping effect.

  17. Activated carbon for the removal of pharmaceutical residues from treated wastewater.

    Science.gov (United States)

    Ek, Mats; Baresel, Christian; Magnér, Jörgen; Bergström, Rune; Harding, Mila

    2014-01-01

    Pharmaceutical residues, which pass naturally through the human body into sewage, are in many cases virtually unaffected by conventional wastewater treatment. Accumulated in the environment, however, they can significantly impact aquatic life. The present study indicates that many pharmaceutical residues found in wastewater can be removed with activated carbon in a cost-efficient system that delivers higher resource utilisation and security than other carbon systems. The experiment revealed a substantial separation of the analysed compounds, notwithstanding their relatively high solubility in water and dissimilar chemical structures. This implies that beds of activated carbon may be a competitive alternative to treatment with ozone. The effluent water used for the tests, performed over 20 months, originated from Stockholm's largest sewage treatment plant. Passing through a number of different filters with activated carbon removed 90-98% of the pharmaceutical residues from the water. This paper describes pilot-scale tests performed by IVL and the implications for an actual treatment plant that has to treat up to several thousand litres of wastewater per second. In addition, the advantages, disadvantages and costs of the method are discussed. This includes, for example, the clogging of carbon filters and the associated hydraulic capacity limits of the activated carbon.

  18. Shunt hybrid active power filter for harmonic mitigation: A practical design approach

    Indian Academy of Sciences (India)

    Unnikrishnan A K; Chandira Sekaran E; Subhash Joshi T G; Manju A S; Aby Joseph

    2015-06-01

    The increasing importance of Power Quality problems has been responsible for several improvements in Active Power Filter (APF) typologies in the last decade. The increased cost and switching losses make a pure shunt APF economically impractical for high power applications. In higher power levels shunt Hybrid Active Power Filter (HAPF) has been reported to be a useful approach to eliminate current harmonics caused by nonlinear loads. This paper presents a control strategy and design criteria for transformer-less shunt HAPF with special attention to the integration of series passive filter. The paper also compares the performance improvement of passive harmonic filter when modified as shunt HAPF. Experimental results obtained verify the viability and effectiveness of the proposed design criteria and control algorithm.

  19. Internal Porosity of Mineral Coating Supports Microbial Activity in Rapid Sand Filters for Groundwater Treatment

    DEFF Research Database (Denmark)

    Gülay, Arda; Tatari, Karolina; Musovic, Sanin

    2014-01-01

    A mineral coating develops on the filter grain surface when groundwater is treated via rapid sand filtration in drinking water production. The coating changes the physical and chemical properties of the filter material, but little is known about its effect on the activity, colonization, diversity...... prokaryotes in filter material with various degrees of mineral coating. We also examined the physical and chemical characteristics of the mineral coating. The amount of mineral coating correlated positively with the internal porosity, the packed bulk density, and the biologically available surface area......, and abundance of microbiota. This study reveals that a mineral coating can positively affect the colonization and activity of microbial communities in rapid sand filters. To understand this effect, we investigated the abundance, spatial distribution, colonization, and diversity of all and of nitrifying...

  20. Stability analysis and active damping for LLCL-filter based grid-connected inverters

    DEFF Research Database (Denmark)

    Huang, Min; Blaabjerg, Frede; Loh, Poh Chiang

    2014-01-01

    A higher order passive power filter (LLCL-filter) for the grid-tied inverter is becoming attractive for the industrial applications due to the possibility to reduce the cost of the copper and the magnetic material. To avoid the well-known stability problems of the LLCL-filter it is requested to use...... either passive or active damping methods. This paper analyzes the stability when damping is required and when damping is not necessary considering sampling and transport delay. Basic LLCL resonance damping properties of different feedback states are also studied. Then an active damping method which...... is using the capacitor current feedback for LLCL-filter is introduced. Based on this method, a design procedure for the control method is given. Last, both simulation and experimental results are provided to validate the theoretical analysis of this paper....

  1. Characteristics of Nonafluorobutyl Methyl Ether (NFE) Adsorption onto Activated Carbon Fibers and Different-Size-Activated Carbon Particles.

    Science.gov (United States)

    Tanada; Kawasaki; Nakamura; Araki; Tachibana

    2000-08-15

    The characteristics of adsorption of 1,1,1,2,2,3,3,4,4-nonafluorobutyl methyl ether (NFE), a chlorofluorocarbon (CFC) replacement, onto six different activated carbon; preparations (three activated carbon fibers and three different-sized activated carbon particles) were investigated to evaluate the interaction between activated carbon surfaces and NFE. The amount of NFE adsorbed onto the three activated carbon fibers increased with increasing specific surface area and pore volume. The amount of NFE adsorbed onto the three different-sized-activated carbon particles increased with an increase in the particle diameter of the granular activated carbon. The differential heat of the NFE adsorption onto three activated carbon fibers depended on the porosity structure of the activated carbon fibers. The adsorption rate of NFE was also investigated in order to evaluate the efficiency of NFE recovery by the activated carbon surface. The Sameshima equation was used to obtain the isotherms of NFE adsorption onto the activated carbon fibers and different-sized-activated carbon particles. The rate constant k for NFE adsorption onto activated carbon fibers was larger for increased specific surface area and pore volume. The rate of NFE adsorption on activated carbons of three different particle sizes decreased with increasing particle diameter at a low initial pressure. The adsorption isotherms of NFE for the six activated carbons conformed to the Dubinin-Radushkevich equation; the constants BE(0) (the affinity between adsorbate and adsorbent) and W(0) (the adsorption capacity) were calculated. These results indicated that the interaction between the activated carbon and NFE was larger with the smaller specific surface area of the activated carbon fibers and with the smaller particle diameter of the different-sized-activated carbon particles. The degree of packing of NFE in the pores of the activated carbon fibers was greater than that in the pores of the granular activated

  2. Cellulase activity and dissolved organic carbon release from lignocellulose macrophyte-derived in four trophic conditions.

    Science.gov (United States)

    Bottino, Flávia; Cunha-Santino, Marcela Bianchessi; Bianchini, Irineu

    2016-01-01

    Considering the importance of lignocellulose macrophyte-derived for the energy flux in aquatic ecosystems and the nutrient concentrations as a function of force which influences the decomposition process, this study aims to relate the enzymatic activity and lignocellulose hydrolysis in different trophic statuses. Water samples and two macrophyte species were collected from the littoral zone of a subtropical Brazilian Reservoir. A lignocellulosic matrix was obtained using aqueous extraction of dried plant material (≈40°C). Incubations for decomposition of the lignocellulosic matrix were prepared using lignocelluloses, inoculums and filtered water simulating different trophic statuses with the same N:P ratio. The particulate organic carbon and dissolved organic carbon (POC and DOC, respectively) were quantified, the cellulase enzymatic activity was measured by releasing reducing sugars and immobilized carbon was analyzed by filtration. During the cellulose degradation indicated by the cellulase activity, the dissolved organic carbon daily rate and enzyme activity increased. It was related to a fast hydrolysable fraction of cellulose that contributed to short-term carbon immobilization (ca. 10 days). After approximately 20 days, the dissolved organic carbon and enzyme activity were inversely correlated suggesting that the respiration of microorganisms was responsible for carbon mineralization. Cellulose was an important resource in low nutrient conditions (oligotrophic). However, the detritus quality played a major role in the lignocelluloses degradation (i.e., enzyme activity) and carbon release.

  3. Cellulase activity and dissolved organic carbon release from lignocellulose macrophyte-derived in four trophic conditions

    Directory of Open Access Journals (Sweden)

    Flávia Bottino

    2016-06-01

    Full Text Available Abstract Considering the importance of lignocellulose macrophyte-derived for the energy flux in aquatic ecosystems and the nutrient concentrations as a function of force which influences the decomposition process, this study aims to relate the enzymatic activity and lignocellulose hydrolysis in different trophic statuses. Water samples and two macrophyte species were collected from the littoral zone of a subtropical Brazilian Reservoir. A lignocellulosic matrix was obtained using aqueous extraction of dried plant material (≈40 °C. Incubations for decomposition of the lignocellulosic matrix were prepared using lignocelluloses, inoculums and filtered water simulating different trophic statuses with the same N:P ratio. The particulate organic carbon and dissolved organic carbon (POC and DOC, respectively were quantified, the cellulase enzymatic activity was measured by releasing reducing sugars and immobilized carbon was analyzed by filtration. During the cellulose degradation indicated by the cellulase activity, the dissolved organic carbon daily rate and enzyme activity increased. It was related to a fast hydrolysable fraction of cellulose that contributed to short-term carbon immobilization (ca. 10 days. After approximately 20 days, the dissolved organic carbon and enzyme activity were inversely correlated suggesting that the respiration of microorganisms was responsible for carbon mineralization. Cellulose was an important resource in low nutrient conditions (oligotrophic. However, the detritus quality played a major role in the lignocelluloses degradation (i.e., enzyme activity and carbon release.

  4. Catalytic activity of carbons for methane decomposition reaction

    Energy Technology Data Exchange (ETDEWEB)

    Muradov, Nazim; Smith, Franklyn; T-Raissi, Ali [Florida Solar Energy Center, University of Central Florida, 1679 Clearlake Road, Cocoa, FL 32922 (United States)

    2005-05-15

    Catalytic decomposition of methane is an environmentally attractive approach to CO{sub 2}-free production of hydrogen. The objective of this work is to evaluate catalytic activity of a wide range of carbon materials for methane decomposition reaction and determine major factors governing their activity. It was demonstrated that the catalytic activity of carbon materials for methane decomposition is mostly determined by their structural and surface properties. Kinetics of methane decomposition reaction over disordered (amorphous) carbons such as carbon black and activated carbon were determined. The mechanism of carbon-catalyzed methane decomposition reaction and the nature of active sites on the carbon surface are discussed in this paper.

  5. High activity carbon sorbents for mercury capture

    Energy Technology Data Exchange (ETDEWEB)

    George G. Stavropoulos; Irene S. Diamantopoulou; George E. Skodras; George P. Sakellaropoulos [Aristotle University of Thessaloniki, Thessaloniki (Greece). Chemical Process Engineering Laboratory

    2006-07-01

    High efficiency activated carbons have been prepared for removing mercury from gas streams. Starting materials used were petroleum coke, lignite, charcoal and olive seed waste, and were chemically activated with KOH. Produced adsorbents were primarily characterized for their porosity by N{sub 2} adsorption at 77K. Their mercury retention capacity was characterized based on the breakthrough curves. Compared with typical commercial carbons, they have exhibited considerably enhanced mercury adsorption capacity. An attempt has been made to correlate mercury entrapment and pore structure. It has been shown that physical surface area is increased during activation in contrast to the mercury adsorption capacity that initially increases and tends to decrease at latter stages. Desorption of active sites may be responsible for this behavior. 10 refs., 3 figs., 1 tab.

  6. Methane Adsorption Study Using Activated Carbon Fiber and Coal Based Activated Carbon

    Institute of Scientific and Technical Information of China (English)

    Guo Deyong; Li Fei; Liu Wenge

    2013-01-01

    Inlfuence of ammonium salt treatment and alkali treatment of the coal based activated carbon (AC) and activated carbon ifber (ACF) adsorbents on methane adsorption capacity was studied via high-pressure adsorption experiment. Sur-face functional groups and pore structure of two types of adsorbents were characterized by the application of infrared ab-sorption spectroscopy (IR) and low temperature liquid nitrogen adsorption method. The results show that both ammonium salt treatment and alkali treatment have obvious effect on changing BET, pore volume as well as pore size distribution of adsorbents; and methane adsorption capacity of the activated carbon ifber is the maximum after the ammonium salt treatment.

  7. How to dose powdered activated carbon in deep bed filtration for efficient micropollutant removal.

    Science.gov (United States)

    Altmann, Johannes; Ruhl, Aki S; Sauter, Daniel; Pohl, Julia; Jekel, Martin

    2015-07-01

    Direct addition of powdered activated carbon (PAC) to the inlet of a deep bed filter represents an energy- and space-saving option to remove organic micropollutants (OMPs) during advanced wastewater treatment or drinking water purification. In this lab-scale study, continuous dosing, preconditioning a filter with PAC and combinations thereof were investigated as possible dosing modes with respect to OMP adsorption efficiency. Continuous dosing resulted in decreasing effluent concentrations with increasing filter runtime due to adsorption onto accumulating PAC in the filter bed. Approximately constant removal levels were achieved at longer filter runtimes, which were mainly determined by the dose of fresh PAC, rather than the total PAC amount embedded. The highest effluent concentrations were observed during the initial filtration stage. Meanwhile, preconditioning led to complete OMP adsorption at the beginning of filtration and subsequent gradual OMP breakthrough. PAC distribution in the pumice filter was determined by the loss on ignition of PAC and pumice and was shown to be relevant for adsorption efficiency. Preconditioning with turbulent upflow led to a homogenous PAC distribution and improved OMP adsorption significantly. Combining partial preconditioning and continuous dosing led to low initial effluent concentrations, but ultimately achieved concentrations similar to filter runs without preconditioning. Furthermore, a dosing stop prior to the end of filtration was suitable to increase PAC efficiency without affecting overall OMP removals.

  8. Filterability of membrane bioreactor (MBR) sludge: impacts of polyelectrolytes and mixing with conventional activated sludge.

    Science.gov (United States)

    Yigit, Nevzat O; Civelekoglu, Gokhan; Cinar, Ozer; Kitis, Mehmet

    2010-01-01

    The main objective of this work was to investigate the filterability of MBR sludge and its mixture with conventional activated sludge (CAS). In addition, the impacts of type and dose of various polyelectrolytes, filter type and sludge properties on the filterability of both MBR and Mixed sludges were determined. Specific cake resistance (SCR) measured by the Buchner funnel filtration test apparatus and the solids content of the resulting sludge cake were used to assess the dewaterability of tested sludges. The type of filter paper used in Buchner tests affected the results of filterability for MBR, CAS and Mixed sludges. SCR values and optimum polyelectrolyte doses increased with increasing MLSS concentrations in the MBR, which suggested that increase in MLSS concentrations accompanied by increases in EPS and SMP concentrations and a shift toward smaller particles caused poorer dewaterability of the MBR sludge. The significant differences observed among the filterability of CAS and MBR sludges suggested that MLSS alone is not a good predictor of sludge dewaterability. Combining CAS and MBR sludges at different proportions generally improved their dewaterability. Combining MBR sludges having typically high MLSS and EPS concentrations with CAS having much lower MLSS concentrations may be an option for full-scale treatment plants experiencing sludge dewaterability problems. Better filterability and higher cake dry solids were achieved with cationic polyelectrolytes compared to anionic and non-ionic ones for all sludge types tested.

  9. Multiple Iteration of Weight Updates for Least Mean Square Adaptive Filter in Active Noise Control Application

    Directory of Open Access Journals (Sweden)

    Mustafa Rahimie

    2017-01-01

    Full Text Available The method of least mean square (LMS is the commonly used algorithm in Adaptive filter due to its simplicity and robustness in implementation. In Active Noise Control application, a filtered reference signal is used prior to LMS algorithm to overcome the constraint on stability and convergence performance of the system due to the existence of the auxiliary path. This is known as Filtered-X LMS algorithm. In conventional Filtered-X LMS algorithm, each filter weight is updated once on every audio sample. This paper proposes the improved version of Filtered-X LMS algorithm with the use of multiple iteration of filter weight on every sample of audio signal. The proposed work uses field programmable gate arrays to realize real-time simulation on hardware for the noise signal of 500 Hz. Results from the real-time hardware simulations have shown much faster error convergence and better adaptation performance for different selections of learning constant μ, as compared with the conventional method.

  10. Structural, nanomechanical and variable range hopping conduction behavior of nanocrystalline carbon thin films deposited by the ambient environment assisted filtered cathodic jet carbon arc technique

    Energy Technology Data Exchange (ETDEWEB)

    Panwar, O.S., E-mail: ospanwar@mail.nplindia.ernet.in [Polymorphic Carbon Thin Films Group, Physics of Energy Harvesting Division, CSIR-National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi - 110 012 (India); Rawal, Ishpal; Tripathi, R.K. [Polymorphic Carbon Thin Films Group, Physics of Energy Harvesting Division, CSIR-National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi - 110 012 (India); Srivastava, A.K. [Electron and Ion Microscopy, Sophisticated and Analytical Instruments, CSIR-National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi - 110 012 (India); Kumar, Mahesh [Ultrafast Opto-Electronics and Tetrahertz Photonics Group, CSIR-National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi - 110 012 (India)

    2015-04-15

    Highlights: • Nanocrystalline carbon thin films are grown by filtered cathodic jet carbon arc process. • Effect of gaseous environment on the properties of carbon films has been studied. • The structural and nanomechanical properties of carbon thin films have been studied. • The VRH conduction behavior in nanocrystalline carbon thin films has been studied. - Abstract: This paper reports the deposition and characterization of nanocrystalline carbon thin films by filtered cathodic jet carbon arc technique assisted with three different gaseous environments of helium, nitrogen and hydrogen. All the films are nanocrystalline in nature as observed from the high resolution transmission electron microscopic (HRTEM) measurements, which suggests that the nanocrystallites of size ∼10–50 nm are embedded though out the amorphous matrix. X-ray photoelectron spectroscopic studies suggest that the film deposited under the nitrogen gaseous environment has the highest sp{sup 3}/sp{sup 2} ratio accompanied with the highest hardness of ∼18.34 GPa observed from the nanoindentation technique. The film deposited under the helium gaseous environment has the highest ratio of the area under the Raman D peak to G peak (A{sub D}/A{sub G}) and the highest conductivity (∼2.23 S/cm) at room temperature, whereas, the film deposited under the hydrogen environment has the lowest conductivity value (2.27 × 10{sup −7} S/cm). The temperature dependent dc conduction behavior of all the nanocrystalline carbon thin films has been analyzed in the light of Mott’s variable range hopping (VRH) conduction mechanism and observed that all the films obey three dimension VRH conduction mechanism for the charge transport.

  11. Voltammetric Response of Epinephrine at Carbon Nanotube Modified Glassy Carbon Electrode and Activated Glassy Carbon Electrode

    Institute of Scientific and Technical Information of China (English)

    WANG Juan; TANG Ping; ZHAO Fa-qiong; ZENG Bai-zhao

    2005-01-01

    The electrochemical behavior of epinephrine at activated glassy carbon electrode and carbon nanotube-coated glassy carbon electrode was studied. Epinephrine could exhibit an anodic peak at about 0.2 V (vs. SCE) at bare glassy carbon electrode, but it was very small.However, when the electrode was activated at certain potential (i. e. 1.9V) or modified with carbon nanotube, the peak became more sensitive,resulting from the increase in electrode area in addition to the electrostatic attraction. Under the selected conditions, the anodic peak current was linear to epinephrine concentration in the range of 3.3 × 10-7-1.1 × 10-5mol/L at activated glassy carbon electrode and in the range of 1.0 × 10-6-5.0 × 10-5 mol/L at carbon nanotube-coated electrode. The correlation coefficients were 0. 998 and 0. 997, respectively. The determination limit was 1.0 × 10-7 mol/L. The two electrodes have been successfully applied for the determination of epinephrine in adrenaline hydrochloride injection with recovery of 95%-104%.

  12. Activated soil filters for removal of biocides from contaminated run-off and waste-waters

    DEFF Research Database (Denmark)

    Bester, Kai; Banzhaf, Stefan; Burkhardt, Michael

    2011-01-01

    Building facades can be equipped with biocides to prevent formation of algal, fungal and bacterial films. Thus run-off waters may contain these highly active compounds. In this study, the removal of several groups of biocides from contaminated waters by means of an activated soil filter was studied....... A technical scale activated vertical soil filter (biofilter) with different layers (peat, sand and gravel), was planted with reed (Phragmites australis) and used to study the removal rates and fate of hydrophilic to moderate hydrophobic (log Kow 1.8–4.4) biocides and biocide metabolites such as: Terbutryn...

  13. Removal of MIB and geosmin using granular activated carbon with and without MIEX pre-treatment.

    Science.gov (United States)

    Drikas, Mary; Dixon, Mike; Morran, Jim

    2009-12-01

    This study assessed the impact of MIEX pre-treatment, followed by either coagulation or microfiltration (MF), on the effectiveness of pilot granular activated carbon (GAC) filters for the removal of the taste and odour compounds, 2-methylisoborneol (MIB) and geosmin, from a surface drinking water source over a 2-year period. Complete removal of MIB and geosmin was achieved by all GAC filters for the first 10 months, suggesting that the available adsorption capacity was sufficient to compensate for differences in dissolved organic carbon (DOC) entering the GAC filters. Reduction of empty bed contact time (EBCT), in all but one GAC filter, resulted in breakthrough of spiked MIB and geosmin, with initial results inconclusive regarding the impact of MIEX pre-treatment. MIB and geosmin removal increased over the ensuing 12 months until complete removal of both MIB and geosmin was again achieved in all but one GAC filter, which had been pre-chlorinated. Autoclaving and washing the GAC filters had minimal impact on geosmin removal but reduced MIB removal by 30% in all but the pre-chlorinated filter, confirming that biodegradation impacted MIB removal. The impact of biodegradation was greater than any impact on GAC adsorption arising from DOC differences due to MIEX pre-treatment. It is not clear whether, at a lower initial EBCT, MIEX pre-treatment may have impacted on the adsorption capacity of the virgin GAC. The GAC filter maintained at the longer EBCT, which was also pre-chlorinated, completely removed MIB and geosmin for the period of the study, suggesting that the greater adsorption capacity was compensating for any decrease in biological degradation.

  14. Comparison of in vitro and in vivo estrogenic activity of UV filters in fish.

    Science.gov (United States)

    Kunz, Petra Y; Galicia, Hector F; Fent, Karl

    2006-04-01

    In this work, we evaluate whether in vitro systems are good predictors for in vivo estrogenic activity in fish. We focus on UV filters being used in sunscreens and in UV stabilization of materials. First, we determined the estrogenic activity of 23 UV filters and one UV filter metabolite employing a recombinant yeast carrying the estrogen receptor of rainbow trout (rtERalpha) and made comparisons with yeast carrying the human hERalpha for receptor specificity. Benzophenone-1 (BP1), benzophenone-2 (BP2), 4,4-dihydroxybenzophenone, 4-hydroxybenzophenone, 2,4,4-trihydroxy-benzophenone, and phenylsalicylate showed full dose-response curves with maximal responses of 81-115%, whereas 3-benzylidene camphor (3BC), octylsalicylate, benzylsalicylate, benzophenone-3, and benzophenone-4 displayed lower maximal responses of 15-74%. Whereas the activity of 17beta-estradiol was lower in the rtERalpha than the hERalpha assay, the activities of UV filters were similar or relatively higher in rtERalpha, indicating different relative binding activities of both ER. Subsequently, we analyzed whether the in vitro estrogenicity of eight UV filters is also displayed in vivo in fathead minnows by the induction potential of vitellogenin after 14 days of aqueous exposure. Of the three active compounds in vivo, 3BC induced vitellogenin at lower concentrations (435 microg/l) than BP1 (4919 microg/l) and BP2 (8783 microg/l). The study shows, for the first time, estrogenic activities of UV filters in fish both in vitro and in vivo. Thus we propose that receptor-based assays should be used for in vitro screening prior to in vivo testing, leading to environmental risk assessments based on combined, complementary, and appropriate species-related assays for hormonal activity.

  15. Carbon sink activity of managed grasslands

    Science.gov (United States)

    Klumpp, Katja; Chabbi, Abad; Gastal, Francois; Senapati, Nimai; Charrier, Xavier; Darsonville, Olivier; Creme, Alexandra

    2017-04-01

    In agriculture, a large proportion of GHG emission saving potential may be achieved by means of soil C sequestration. Recent demonstrations of carbon sink activities however, often questioned the existence of C storing grasslands, as uncertainty surrounding estimates are often larger than the sink itself. Besides climate, key components of the carbon sink activity in grasslands are type and intensity of management practices. Here, we analysed long term data on C flux and soil organic carbon stocks for two long term (>13yrs) national observation sites in France (SOERE-ACBB). These sites comprise a number of grassland fields and managements options (i.e. permanent, sowing, grazing, mowing, and fertilization) offering an opportunity to study carbon offsets (i.e. compensation of CH4 and N2O emissions), climatic-management interactions and trade-offs concerning ecosystem services (e.g. production). Furthermore, for some grassland fields, the carbon sink activity was compared using two methods; repeated soil inventory and estimation of the ecosystem C budget by continuous measurement of CO2 exchange (i.e. eddy covariance) in combination with quantification of other C imports and exports, necessary to estimate net C storage. In general grasslands, were a potential sink of C (i.e. net ecosystem exchange, NEE), where grazed sites had lower NEE compared the cut site. However, when it comes to net C storage (NCS), mowing reduced markedly potential sink leading to very low NCS compared to grazed sites. Including non-CO2 fluxes (CH4 and N2O emission) in the budget, revealed that GHG emissions were offset by C sink activity.

  16. IIR filtering based adaptive active vibration control methodology with online secondary path modeling using PZT actuators

    Science.gov (United States)

    Boz, Utku; Basdogan, Ipek

    2015-12-01

    Structural vibrations is a major cause for noise problems, discomfort and mechanical failures in aerospace, automotive and marine systems, which are mainly composed of plate-like structures. In order to reduce structural vibrations on these structures, active vibration control (AVC) is an effective approach. Adaptive filtering methodologies are preferred in AVC due to their ability to adjust themselves for varying dynamics of the structure during the operation. The filtered-X LMS (FXLMS) algorithm is a simple adaptive filtering algorithm widely implemented in active control applications. Proper implementation of FXLMS requires availability of a reference signal to mimic the disturbance and model of the dynamics between the control actuator and the error sensor, namely the secondary path. However, the controller output could interfere with the reference signal and the secondary path dynamics may change during the operation. This interference problem can be resolved by using an infinite impulse response (IIR) filter which considers feedback of the one or more previous control signals to the controller output and the changing secondary path dynamics can be updated using an online modeling technique. In this paper, IIR filtering based filtered-U LMS (FULMS) controller is combined with online secondary path modeling algorithm to suppress the vibrations of a plate-like structure. The results are validated through numerical and experimental studies. The results show that the FULMS with online secondary path modeling approach has more vibration rejection capabilities with higher convergence rate than the FXLMS counterpart.

  17. Cooperative redox activation for carbon dioxide conversion

    Science.gov (United States)

    Lian, Zhong; Nielsen, Dennis U.; Lindhardt, Anders T.; Daasbjerg, Kim; Skrydstrup, Troels

    2016-12-01

    A longstanding challenge in production chemistry is the development of catalytic methods for the transformation of carbon dioxide into useful chemicals. Silane and borane promoted reductions can be fined-tuned to provide a number of C1-building blocks under mild conditions, but these approaches are limited because of the production of stoichiometric waste compounds. Here we report on the conversion of CO2 with diaryldisilanes, which through cooperative redox activation generate carbon monoxide and a diaryldisiloxane that actively participate in a palladium-catalysed carbonylative Hiyama-Denmark coupling for the synthesis of an array of pharmaceutically relevant diarylketones. Thus the disilane reagent not only serves as the oxygen abstracting agent from CO2, but the silicon-containing `waste', produced through oxygen insertion into the Si-Si bond, participates as a reagent for the transmetalation step in the carbonylative coupling. Hence this concept of cooperative redox activation opens up for new avenues in the conversion of CO2.

  18. Genetic Algorithm-Based Design of the Active Damping for an LCL-Filter Three-Phase Active Rectifier

    DEFF Research Database (Denmark)

    Liserre, Marco; Aquila, Antonio Dell; Blaabjerg, Frede

    2004-01-01

    Active rectifiers/inverters are becoming used more and more often in regenerative systems and distributed power systems. Typically, the interface between the grid and rectifier is either an inductor or an LCL-filter. The use of an LCL-filter mitigates the switching ripple injected in the grid...... or complex calculations. Moreover, in the paper particular attention is devoted to the susceptibility of the systems in a high polluting environment....

  19. Carbon nanomaterials: Biologically active fullerene derivatives

    Directory of Open Access Journals (Sweden)

    Bogdanović Gordana

    2016-01-01

    Full Text Available Since their discovery, fullerenes, carbon nanotubes, and graphene attract significant attention of researches in various scientific fields including biomedicine. Nano-scale size and a possibility for diverse surface modifications allow carbon nanoallotropes to become an indispensable nanostructured material in nanotechnologies, including nanomedicine. Manipulation of surface chemistry has created diverse populations of water-soluble derivatives of fullerenes, which exhibit different behaviors. Both non-derivatized and derivatized fullerenes show various biological activities. Cellular processes that underline their toxicity are oxidative, genotoxic, and cytotoxic responses. The antioxidant/cytoprotective properties of fullerenes and derivatives have been considered in the prevention of organ oxidative damage and treatment. The same unique physiochemical properties of nanomaterials may also be associated with potential health hazards. Non-biodegradability and toxicity of carbon nanoparticles still remain a great concern in the area of biomedical application. In this review, we report on basic physical and chemical properties of carbon nano-clusters - fullerenes, nanotubes, and graphene - their specificities, activities, and potential application in biological systems. Special emphasis is given to our most important results obtained in vitro and in vivo using polyhydroxylated fullerene derivative C60(OH24. [Projekat Ministarstva nauke Republike Srbije, br. III45005

  20. Control of a Shunt Active Power Filter with Neural Networks—Theory and Practical Results

    Science.gov (United States)

    Villalva, Marcelo G.; Filho, Ernesto Ruppert

    This paper presents theoretical studies and practical results obtained with a four-wire shunt active power filter fully controlled with neural networks. The paper is focused on a current compensation method based on adaptive linear elements (adalines), which are powerful and easy-to-use neural networks. The reader will find here an introduction about these networks, an explanatory section about the achievement of Fourier series with adalines, and the full description of an adaline-based selective current compensator. The paper also brings a quick discussion about the use of a feedforward neural network in the current controller of the active filter, as well as simulation and experimental results obtained with the prototype of an active power filter.

  1. Partially resonant active filter using the digital PWM control circuit with the DSP

    Energy Technology Data Exchange (ETDEWEB)

    Matsuo, Hirofumi; Kurokawa, Fujio; Luo, Zongxin; Makino, Yutaka; Ishizuka, Yoichi [Nagasaki Univ. (Japan); Oshikata, Tetsuya [Shindengen Elect. Mfg. Co. Ltd. (Japan)

    2000-07-01

    The partially resonant active filter, as a pre-regulator, using the digital PWM control circuit with the DSP is proposed to improve the power factor and input current harmonic distortion factor. The steady-state and dynamic characteristics of this active filter are analysed and the relationship among the circuit parameters, variables and performance characteristics such as the pre-regulation of the output voltage, input power factor, input current harmonic distortion, boundaries of stability and so forth are defined. Using the partially resonant active filter, the high power efficiency over 91% is obtained and the high frequency switching noise is suppressed. Also, the digital control with the DSP is versatile and consequently, the power factor over 0.99 and total harmonic distortion factor less than 1% are easily realized. (orig.)

  2. Instantaneous Power Theory with Fourier and Optimal Predictive Controller Design for Shunt Active Power Filter

    Directory of Open Access Journals (Sweden)

    Suksan Tiyarachakun

    2014-01-01

    Full Text Available This paper presents a novel harmonic identification algorithm of shunt active power filter for balanced and unbalanced three-phase systems based on the instantaneous power theory called instantaneous power theory with Fourier. Moreover, the optimal design of predictive current controller using an artificial intelligence technique called adaptive Tabu search is also proposed in the paper. These enhancements of the identification and current control parts are the aim of the good performance for shunt active power filter. The good results for harmonic mitigation using the proposed ideas in the paper are confirmed by the intensive simulation using SPS in SIMULINK. The simulation results show that the enhanced shunt active power filter can provide the minimum %THD (Total Harmonic Distortion of source currents and unity power factor after compensation. In addition, the %THD also follows the IEEE Std.519-1992.

  3. Anaerobic filters for the treatment of coal gasification wastewater.

    Science.gov (United States)

    Suidan, M T; Siekerka, G L; Kao, S W; Pfeffer, J T

    1983-06-01

    A process train consisting of the following sequence of unit processes, a berl-saddle-packed anaerobic filter, an expanded bed, granular activated carbon anaerobic filter, and an activated sludge nitrification system was evaluated for the treatment of a synthetically prepared coal gasification wastewater. The first-stage anaerobic filter resulted in very little removal of organic matter and no methane production. Excellent reduction in organic matter occurred in the granular activated carbon anaerobic filter. The removal mechanism was initially adsorptive and near the end of the study, removal of organic matter was primarily through conversion to methane gas. It is felt that the success of the activated carbon anaerobic filter was due to the ability of the activated carbon to sequester some components of the wastewater that were toxic to the mixed culture of anaerobic microorganisms. The activated sludge nitrification system resulted in complete ammonia oxidation and was very efficient in final effluent polishing.

  4. Reducing uncertainties associated with filter-based optical measurements of light absorbing carbon particles with chemical information

    Directory of Open Access Journals (Sweden)

    J. E. Engström

    2011-08-01

    Full Text Available The presented filter-based optical method for determination of soot (light absorbing carbon or Black Carbon, BC can be implemented in the field under primitive conditions and at low cost. This enables researchers with small economical means to perform monitoring at remote locations, especially in the Asia where it is much needed.

    One concern when applying filter-based optical measurements of BC is that they suffer from systematic errors due to the light scattering of non-absorbing particles co-deposited on the filter, such as inorganic salts and mineral dust. In addition to an optical correction of the non-absorbing material this study provides a protocol for correction of light scattering based on the chemical quantification of the material, which is a novelty. A newly designed photometer was implemented to measure light transmission on particle accumulating filters, which includes an additional sensor recording backscattered light. The choice of polycarbonate membrane filters avoided high chemical blank values and reduced errors associated with length of the light path through the filter.

    Two protocols for corrections were applied to aerosol samples collected at the Maldives Climate Observatory Hanimaadhoo during episodes with either continentally influenced air from the Indian/Arabian subcontinents (winter season or pristine air from the Southern Indian Ocean (summer monsoon. The two ways of correction (optical and chemical lowered the particle light absorption of BC by 63 to 61 %, respectively, for data from the Arabian Sea sourced group, resulting in median BC absorption coefficients of 4.2 and 3.5 Mm−1. Corresponding values for the South Indian Ocean data were 69 and 97 % (0.38 and 0.02 Mm−1. A comparison with other studies in the area indicated an overestimation of their BC levels, by up to two orders of magnitude. This raises the necessity for chemical correction protocols on optical filter

  5. Enhanced capacitive properties of commercial activated carbon by re-activation in molten carbonates

    Science.gov (United States)

    Lu, Beihu; Xiao, Zuoan; Zhu, Hua; Xiao, Wei; Wu, Wenlong; Wang, Dihua

    2015-12-01

    Simple, affordable and green methods to improve capacitive properties of commercial activated carbon (AC) are intriguing since ACs possess a predominant role in the commercial supercapacitor market. Herein, we report a green reactivation of commercial ACs by soaking ACs in molten Na2CO3-K2CO3 (equal in mass ratios) at 850 °C combining the merits of both physical and chemical activation strategies. The mechanism of molten carbonate treatment and structure-capacitive activity correlations of the ACs are rationalized. Characterizations show that the molten carbonate treatment increases the electrical conductivity of AC without compromising its porosity and wettability of electrolytes. Electrochemical tests show the treated AC exhibited higher specific capacitance, enhanced high-rate capability and excellent cycle performance, promising its practical application in supercapacitors. The present study confirms that the molten carbonate reactivation is a green and effective method to enhance capacitive properties of ACs.

  6. Proximate analysis for determination of micropores in granulated activated carbon

    Energy Technology Data Exchange (ETDEWEB)

    Berman, Ya. G.; Nikolaev, V.B.; Shepelev, A.N.

    1987-02-01

    A method is discussed for determining the specific micropore volume of granulated activated carbon used for water treatment in Soviet coking plants. Toluene molecules with a diameter of 0.67 nm are sorbed by activated carbon with micropore diameter ranging from 0.7 to 1.4 nm. Therefore, sorptive properties of activated carbon in relation to toluene supply information on micropore volume in carbon. A formula which describes this relation is derived. The method for determining micropore volume on the basis of toluene adsorption was tested using 8 types of activated carbon produced from coal and petroleum. Types of activated carbon characterized by the highest adsorption were selected. 1 ref.

  7. Extraction of semivolatile organic compounds from high-efficiency particulate air (HEPA) filters by supercritical carbon dioxide

    Energy Technology Data Exchange (ETDEWEB)

    Schilling, J.B.

    1997-09-01

    Supercritical fluid extraction (SFE) using unmodified carbon dioxide has been explored as an alternative method for the extraction of semivolatile organic compounds from high-efficiency particulate air (HEPA) filters. HEPA filters provide the final stage of containment on many exhaust systems in US Department of Energy (DOE) facilities by preventing the escape of chemical and radioactive materials entrained in the exhausted air. The efficiency of the filters is tested by the manufacturer and DOE using dioctylphthalate (DOP), a substance regulated by the US Environmental Protection Agency under the Resource Conservation and Recovery Act. Therefore, the filters must be analyzed for semivolatile organics before disposal. Ninety-eight acid, base, and neutral semivolatile organics were spiked onto blank HEPA material and extracted using SFE, Soxhlet, automated Soxhlet, and sonication techniques. The SFE conditions were optimized using a Dionex SFE-703 instrument. Average recoveries for the 98 semivolatile compounds are 82.7% for Soxhlet, 74.0% for sonication, 70.2% for SFE, and 62.9% for Soxtec. Supercritical fluid extraction reduces the extraction solvent volume to 10--15 mL, a factor of 20--30 less than Soxhlet and more than 5 times less than Soxtec and sonication. Extraction times of 30--45 min are used compared to 16--18 h for Soxhlet extraction.

  8. Single-Phase LLCL-Filter-based Grid-Tied Inverter with Low-Pass Filter Based Capacitor Current Feedback Active damper

    DEFF Research Database (Denmark)

    Liu, Yuan; Wu, Weimin; Li, Yun

    2016-01-01

    The capacitor-current-feedback active damping method is attractive for high-order-filter-based high power grid-tied inverter when the grid impedance varies within a wide range. In order to improve the system control bandwidth and attenuate the high order grid background harmonics by using the quasi....... In this paper, a low pass filter is proposed to be inserted in the capacitor current feedback loop op LLCL-filter based grid-tied inverter together with a digital proportional and differential compensator. The detailed theoretical analysis is given. For verification, simulations on a 2kW/220V/10kHz LLCL...

  9. In vitro adsorption study of fluoxetine in activated carbons and activated carbon fibres

    Energy Technology Data Exchange (ETDEWEB)

    Nabais, J.M. Valente; Mouquinho, A.; Galacho, C.; Carrott, P.J.M.; Ribeiro Carrott, M.M.L. [Centro de Quimica de Evora e Departamento de Quimica da Universidade de Evora, Rua Romao Ramalho no. 59, 7000-671 Evora (Portugal)

    2008-05-15

    We study the in vitro adsorption of fluoxetine hydrochloride by different adsorbents in simulated gastric and intestinal fluid, pH 1.2 and 7.5, respectively. The tested materials were two commercial activated carbons, carbomix and maxsorb MSC30, one activated carbon fibre produced in our laboratory and also three MCM-41 samples, also produced by us. Selected samples were modified by liquid phase oxidation and thermal treatment in order to change the surface chemistry without significant modifications to the porous characteristics. The fluoxetine adsorption follows the Langmuir model. The calculated Q{sub 0} values range from 54 to 1112 mg/g. A different adsorption mechanism was found for the adsorption of fluoxetine in activated carbon fibres and activated carbons. In the first case the most relevant factors are the molecular sieving effect and the dispersive interactions whereas in the activated carbons the mechanism seams to be based on the electrostatic interactions between the fluoxetine molecules and the charged carbon surface. Despite the different behaviours most of the materials tested have potential for treating potential fluoxetine intoxications. (author)

  10. Fundamental Active Current Adaptive Linear Neural Networks for Photovoltaic Shunt Active Power Filters

    Directory of Open Access Journals (Sweden)

    Muhammad Ammirrul Atiqi Mohd Zainuri

    2016-05-01

    Full Text Available This paper presents improvement of a harmonics extraction algorithm, known as the fundamental active current (FAC adaptive linear element (ADALINE neural network with the integration of photovoltaic (PV to shunt active power filters (SAPFs as active current source. Active PV injection in SAPFs should reduce dependency on grid supply current to supply the system. In addition, with a better and faster harmonics extraction algorithm, the SAPF should perform well, especially under dynamic PV and load conditions. The role of the actual injection current from SAPF after connecting PVs will be evaluated, and the better effect of using FAC ADALINE will be confirmed. The proposed SAPF was simulated and evaluated in MATLAB/Simulink first. Then, an experimental laboratory prototype was also developed to be tested with a PV simulator (CHROMA 62100H-600S, and the algorithm was implemented using a TMS320F28335 Digital Signal Processor (DSP. From simulation and experimental results, significant improvements in terms of total harmonic distortion (THD, time response and reduction of source power from grid have successfully been verified and achieved.

  11. A New Generalized Discontinuous-PWM Strategy for Active Power Filters

    DEFF Research Database (Denmark)

    Asiminoaei, Lucian; Rodriguez, Pedro; Blaabjerg, Frede

    2007-01-01

    losses in any operating point. This paper proposes a new discontinuous pulse width modulation strategy applied to shunt active power filters. The proposed modulation strategy detects the current vector position relative to the inverter voltage reference and determines instantaneously the optimum clamped...... duration on each phase. It achieves a clamped voltage pattern, with variable lengths depending on the magnitude of the inverter current. This property adaptively reduces the current stress and minimizes the inverter switching losses, regardless of its application. The proposed modulation strategy...... is described, analyzed and validated on a three-phase voltage source inverter, rated at 7 kVA, 400 V, controlled as an active power filter....

  12. Preparation and characterization of activated carbon from waste biomass.

    Science.gov (United States)

    Tay, Turgay; Ucar, Suat; Karagöz, Selhan

    2009-06-15

    Lignocellulosic materials are good and cheap precursors for the production of activated carbon. In this study, activated carbons were prepared from the pyrolysis of soybean oil cake at 600 and 800 degrees C by chemical activation with K(2)CO(3) and KOH. The influence of temperature and type of chemical reagents on the porosity development was investigated and discussed. K(2)CO(3) was found more effective than KOH as a chemical reagent under identical conditions in terms of both porosity development and yields of the activated carbons. The maximum surface area (1352.86 m(2)g(-1)) was obtained at 800 degrees C with K(2)CO(3) activation which lies in the range of commercial activated carbons. Elemental analyses of the activated carbons indicate insignificant sulphur content for all activated carbons. The ash and sulphur contents of the activated carbons obtained with chemical activation by K(2)CO(3) were lower than those by chemical activation with KOH.

  13. Activated Carbon Adsorption Properties of the Residual Matters in Textile Dyeing and Printing Secondary Effluent

    Institute of Scientific and Technical Information of China (English)

    TIAN Qing; LI Fang; LIU Fang; YANG Bo; CHEN Ji-hua

    2008-01-01

    The research employed the adsorption isotherm measurement, the batch kinetic adsorption and the rapid small-scale carbon column test (RSSCT) to find out the characteristics and main impacting factors of granular activated carbon (GAC) adsorption, in treating the textile dyeing-printing/polyester alkali de-weighting secondary effluent (TSE). The adsorption affinities and capacities for the organics surrogated by CODCr, color and UV254 (UV absorbency at λ= 254 nm) predicted by isotherm, small-scale-fixed bed were discussed. Adsorption rates for CODCr, color and UV254 are much different and carbon particle size dependent. The color adsorption rate and capacity should be taken as the main consideration factors in designing bio-activated carbon filter(BACF). The breakthrough of GAC adsorption column is mainly influenced by the low MW readily adsorbable organics in TSE. UVm is a good adsorption breakthrough indicator. The study provides References for BACFs' design and operation control in textile secondary effluent (TSE) tertiary treatment.

  14. Preparation of activated carbon from a renewable agricultural ...

    African Journals Online (AJOL)

    STORAGESEVER

    2010-05-10

    May 10, 2010 ... Preparation of activated carbon from a renewable agricultural ... fuel-wood because household energy requirements are met with multiple ..... for activated carbon production - A review. Renewable & Sustainable. Energy ...

  15. Aqueous mercury adsorption by activated carbons.

    Science.gov (United States)

    Hadi, Pejman; To, Ming-Ho; Hui, Chi-Wai; Lin, Carol Sze Ki; McKay, Gordon

    2015-04-15

    Due to serious public health threats resulting from mercury pollution and its rapid distribution in our food chain through the contamination of water bodies, stringent regulations have been enacted on mercury-laden wastewater discharge. Activated carbons have been widely used in the removal of mercuric ions from aqueous effluents. The surface and textural characteristics of activated carbons are the two decisive factors in their efficiency in mercury removal from wastewater. Herein, the structural properties and binding affinity of mercuric ions from effluents have been presented. Also, specific attention has been directed to the effect of sulfur-containing functional moieties on enhancing the mercury adsorption. It has been demonstrated that surface area, pore size, pore size distribution and surface functional groups should collectively be taken into consideration in designing the optimal mercury removal process. Moreover, the mercury adsorption mechanism has been addressed using equilibrium adsorption isotherm, thermodynamic and kinetic studies. Further recommendations have been proposed with the aim of increasing the mercury removal efficiency using carbon activation processes with lower energy input, while achieving similar or even higher efficiencies.

  16. Microorganisms interacting in a bio filter

    Energy Technology Data Exchange (ETDEWEB)

    Barba-Avila, M. D.; Flores-Tene, F. J.; Moreno-Terrazas, R.; Ramirez-Lopez, E. M.

    2009-07-01

    Biofilm microorganisms developed on a bio filter support media allow the metabolism of volatile organic compounds (VOCs) to carbon dioxide and water. VOCs are present in polluted gaseous streams for varied industrial activities. The main objective of this study was to identify the microorganisms present in the biofilm developed on a bio filter support media using molecular biology techniques. (Author)

  17. Real-Time Control of Shunt Active Power Filter under Distorted Grid Voltage and Unbalanced Load Condition Using Self Tuning Filter

    OpenAIRE

    2014-01-01

    In this paper, an alternative control method is proposed to improve the harmonic suppression efficiency of the active power filter in a distorted and an unbalanced power system to compensate for the perturbations caused by the unbalanced non-linear loads. The proposed method uses a self-tuning filter (STF) to process the grid voltage in order to provide a uniform reference voltage to obtain the correct angular position of the phase locked loop. Moreover, the required compensation currents are...

  18. Black carbon emissions in gasoline exhaust and a reduction alternative with a gasoline particulate filter.

    Science.gov (United States)

    Chan, Tak W; Meloche, Eric; Kubsh, Joseph; Brezny, Rasto

    2014-05-20

    Black carbon (BC) mass and solid particle number emissions were obtained from two pairs of gasoline direct injection (GDI) vehicles and port fuel injection (PFI) vehicles over the U.S. Federal Test Procedure 75 (FTP-75) and US06 Supplemental Federal Test Procedure (US06) drive cycles on gasoline and 10% by volume blended ethanol (E10). BC solid particles were emitted mostly during cold-start from all GDI and PFI vehicles. The reduction in ambient temperature had significant impacts on BC mass and solid particle number emissions, but larger impacts were observed on the PFI vehicles than the GDI vehicles. Over the FTP-75 phase 1 (cold-start) drive cycle, the BC mass emissions from the two GDI vehicles at 0 °F (-18 °C) varied from 57 to 143 mg/mi, which was higher than the emissions at 72 °F (22 °C; 12-29 mg/mi) by a factor of 5. For the two PFI vehicles, the BC mass emissions over the FTP-75 phase 1 drive cycle at 0 °F varied from 111 to 162 mg/mi, higher by a factor of 44-72 when compared to the BC emissions of 2-4 mg/mi at 72 °F. The use of a gasoline particulate filter (GPF) reduced BC emissions from the selected GDI vehicle by 73-88% at various ambient temperatures over the FTP-75 phase 1 drive cycle. The ambient temperature had less of an impact on particle emissions for a warmed-up engine. Over the US06 drive cycle, the GPF reduced BC mass emissions from the GDI vehicle by 59-80% at various temperatures. E10 had limited impact on BC emissions from the selected GDI and PFI vehicles during hot-starts. E10 was found to reduce BC emissions from the GDI vehicle by 15% at standard temperature and by 75% at 19 °F (-7 °C).

  19. Design and control of an LCL-filter-based three-phase active rectifier

    DEFF Research Database (Denmark)

    Liserre, Marco; Blaabjerg, Frede; Hansen, Steffan

    2005-01-01

    This paper proposes a step-by-step procedure for designing the LCL filter of a front-end three-phase active rectifier. The primary goal is to reduce the switching frequency ripple at a reasonable cost, while at the same time achieving a high-performance front-end rectifier (as characterized...... a powerful tool to design an LCL-filter-based active rectifier while avoiding trial-and-error procedures that can result in having to build several filter prototypes....... controller. The system is stable and the grid current harmonic content is low both in the lowand high-frequency ranges. Moreover, the good agreement that was obtained between simulation and experimental results validates the proposed approach. Hence, the design procedure and the simulation model provide...

  20. Fuzzy logic controller based three-phase shunt active power filter under unbalanced network

    Energy Technology Data Exchange (ETDEWEB)

    Belaidi, R.; Chikouche, A.; Fathi, M. [Unite de Developpement des Equipements Solaires (Algeria); Haddouche, A.; Guendouz, A. [Universite Badji Mokhtar (Algeria)], E-mail: rachidi3434@yahoo.fr

    2011-07-01

    In recent years, public awareness of power quality issues in distribution systems has arisen. The photovoltaic interactive shunt active power filter is a system which provides harmonic current damping and reactive power compensation and a fuzzy logic controller was created to adjust the energy storage of the DC voltage; the aim of this paper is to study the performance of the fuzzy logic controller. Simulations were performed using Matlab and Simulink and were analyzed to determine the effectiveness of the system; the instantaneous reactive power theory was utilized. Results showed that the use of the fuzzy logic controller achieves a reduction of the total harmonic distortion of the current from 26.54% to 2.27%. This study demonstrated that the fuzzy logic controller combined with the photovoltaic interactive shunt active power filter helps improve power quality by filtering harmonic currents and compensating reactive power generated by non-linear loads.

  1. Neuro-Fuzzy based Controller for a Three- Phase Four-Wire Shunt Active Power Filter

    Directory of Open Access Journals (Sweden)

    Mridul Jha

    2011-10-01

    Full Text Available This paper describes the application of a novel neuro-fuzzy based control strategy which is used in order to improve the Active Power Filter (APF dynamics to minimize the harmonics for wide range of variations of load current under various conditions. To improve dynamic behavior of a three phase four-wire shunt active power filter and its robustness under range of load variations, adaptive hysteresis band with instantaneous p-q theory is used with the inclusion of neural network filter for reference current generation and fuzzy logic controller for DC voltage control. The proposed control scheme for “split-capacitor” converter topology is simple and also capable of maintaining the compensated line currents balanced, irrespective of unbalancing in the source voltages & deviation in the capacitor voltages. The results presented in MATLAB-SIMULINK software in this paper clearly reflect the effectiveness of the proposed APF to meet the IEEE-519 standard recommendations on harmonic levels.

  2. Activated Carbon Preparation and Modification for Adsorption

    Science.gov (United States)

    Cao, Yuhe

    Butanol is considered a promising, infrastructure-compatible biofuel. Butanol has a higher energy content than ethanol and can be used in conventional gas engines without modifications. Unfortunately, the fermentation pathway for butanol production is restricted by its toxicity to the microbial strains used in the process. Butanol is toxic to the microbes, and this can slow fermentation rates and reduce butanol yields. Gas stripping technology can efficiently remove butanol from the fermentation broth as it is produced, thereby decreasing its inhibitory effects. Traditional butanol separation heavily depends on the energy intensive distillation method. One of the main issues in acetone-butanol-ethanol fermentation is that butanol concentrations in the fermentation broth are low, ranging from 1 to 1.2 percent in weight, because of its toxicity to the microorganisms. Therefore distillation of butanol is even worse than distillation of corn ethanol. Even new separation methods, such as solid- extraction methods involve adding substances, such as polymer resin and zeolite or activated carbon, to biobutanol fermentatioon broth did not achieve energy efficient separation of butanol due to low adsorption selectivity and fouling in broth. Gas-stripping - condensation is another new butanol recovery method, however, the butanol in gas-stripping stream is too low to be condensed without using expensive and energy intensive liquid nitrogen. Adsorption can then be used to recover butanol from the vapor phase. Activated carbon (AC) samples and zeolite were investigated for their butanol vapor adsorption capacities. Commercial activated carbon was modified via hydrothermal H2O2 treatment, and the specific surface area and oxygen-containing functional groups of activated carbon were tested before and after treatment. Hydrothermal H2O 2 modification increased the surface oxygen content, Brunauer-Emmett-Teller surface area, micropore volume, and total pore volume of active carbon

  3. Composite supercapacitor electrodes made of activated carbon/PEDOT:PSS and activated carbon/doped PEDOT

    Indian Academy of Sciences (India)

    T S Sonia; P A Mini; R Nandhini; Kalluri Sujith; Balakrishnan Avinash; S V Nair; K R V Subramanian

    2013-08-01

    In this paper, we report on the high electrical storage capacity of composite electrodes made from nanoscale activated carbon combined with either poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) or PEDOT doped with multiple dopants such as ammonium persulfate (APS) and dimethyl sulfoxide (DMSO). The composites were fabricated by electropolymerization of the conducting polymers (PEDOT:PSS, doped PEDOT) onto the nanoscale activated carbon backbone, wherein the nanoscale activated carbon was produced by ball-milling followed by chemical and thermal treatments. Activated carbon/PEDOT:PSS yielded capacitance values of 640 F g-1 and 26mF cm-2, while activated carbon/doped PEDOT yielded capacitances of 1183 F g-1 and 42 mF cm-2 at 10 mV s-1. This is more than five times the storage capacity previously reported for activated carbon–PEDOT composites. Further, use of multiple dopants in PEDOT improved the storage performance of the composite electrode well over that of PEDOT:PSS. The composite electrodes were characterized for their electrochemical behaviour, structural and morphological details and electronic conductivity and showed promise as high-performance energy storage systems.

  4. Highly porous activated carbons prepared from carbon rich Mongolian anthracite by direct NaOH activation

    Energy Technology Data Exchange (ETDEWEB)

    Byamba-Ochir, Narandalai [School of Chemical Engineering, Chonnam National University, 77 Yongbong-Ro, Gwangju 61186 (Korea, Republic of); Shim, Wang Geun [Department of Polymer Science and Engineering, Sunchon National University, 255 Jungang-Ro, Suncheon, Jeollanam-Do 57922 (Korea, Republic of); Balathanigaimani, M.S., E-mail: msbala@rgipt.ac.in [Department of Chemical Engineering, Rajiv Gandhi Institute of Petroleum Technology, Ratapur Chowk, Rae Bareli, 229316 Uttar Pradesh (India); Moon, Hee, E-mail: hmoon@jnu.ac.kr [School of Chemical Engineering, Chonnam National University, 77 Yongbong-Ro, Gwangju 61186 (Korea, Republic of)

    2016-08-30

    Highlights: • Highly porous carbon materials from Mongolian anthracite by chemical activation. • Cheaper and eco-friendly activation process has been employed. • Activated carbons with graphitic structure and energetically heterogeneous surface. • Surface hydrophobicity and porosity of the activated carbons can be controlled. - Abstract: Highly porous activated carbons (ACs) were prepared from Mongolian raw anthracite (MRA) using sodium hydroxide as an activation agent by varying the mass ratio (powdered MRA/NaOH) as well as the mixing method of chemical agent and powdered MRA. The specific BET surface area and total pore volume of the prepared MRA-based activated carbons (MACs) are in the range of 816–2063 m{sup 2}/g and of 0.55–1.61 cm{sup 3}/g, respectively. The pore size distribution of MACs show that most of the pores are in the range from large micropores to small mesopores and their distribution can be controlled by the mass ratio and mixing method of the activating agent. As expected from the intrinsic property of the MRA, the highly graphitic surface morphology of prepared carbons was confirmed from Raman spectra and transmission electron microscopy (TEM) studies. Furthermore the FTIR and XPS results reveal that the preparation of MACs with hydrophobic in nature is highly possible by controlling the mixing conditions of activating agent and powdered MRA. Based on all the results, it is suggested that the prepared MACs could be used for many specific applications, requiring high surface area, optimal pore size distribution, proper surface hydrophobicity as well as strong physical strength.

  5. 78 FR 13894 - Certain Activated Carbon From China

    Science.gov (United States)

    2013-03-01

    ... COMMISSION Certain Activated Carbon From China Determination On the basis of the record \\1\\ developed in the... antidumping duty order on certain activated carbon from China would be likely to lead to continuation or... USITC Publication 4381 (February 2013), entitled Certain Activated Carbon from China: Investigation...

  6. SOGI-based capacitor voltage feedback active damping in LCL-filtered grid converters

    DEFF Research Database (Denmark)

    Xin, Zhen; Wang, Xiongfei; Loh, Poh Chiang

    2015-01-01

    The capacitor voltage feedback active damping control is an attractive way to suppress LCL-filter resonance especially for the systems where the capacitor voltage is used for grid synchronization, since no extra sensors are added. The derivative is the core of the capacitor voltage feedback active...... derivative is more suited for capacitor voltage feedback active damping control. Experimental results validate the effectiveness of the proposed method....

  7. Multi-Rate Fractional-Order Repetitive Control of Shunt Active Power Filter

    DEFF Research Database (Denmark)

    Xie, Chuan; Zhao, Xin; Savaghebi, Mehdi

    2017-01-01

    This paper presents a multi-rate fractional-order repetitive control (MRFORC) scheme for three-phase shunt active power filter (APF). The proposed APF control scheme includes an inner proportional-integral (PI) control loop with a sampling rate identical to switching frequency and an external plug-in...

  8. Passivity enhancement by series LC filtered active damper with zero current reference

    DEFF Research Database (Denmark)

    Bai, Haofeng; Wang, Xiongfei; Blaabjerg, Frede

    2016-01-01

    stability analysis of grid converters in the weak grid. Based on the impedance model of the series LC filtered active damper, the real part of its output admittance is investigated and shown to be able to enhance the passivity of the admittance of the converters seen by the grid. Finally, simulation...

  9. Active Damping of LLCL-Filter Resonance Based on LC-Trap Voltage or Current Feedback

    DEFF Research Database (Denmark)

    Huang, Min; Wang, Xiongfei; Loh, Poh Chiang;

    2016-01-01

    . Active damping is presently more efficient, and can easily be realized by feeding back a state variable. For the LCL-filter, the variable is usually its middle capacitor current. However, with computational delays considered, a simple proportional damper cannot be used with the capacitor current. Instead...

  10. Frequency Response Analysis of Current Controllers for Selective Harmonic Compensation in Active Power Filters

    DEFF Research Database (Denmark)

    Lascu, C.; Asiminoaei, L.; Boldea, I.;

    2009-01-01

    This paper compares four current control structures for selective harmonic compensation in active power filters. All controllers under scrutiny perform the harmonic compensation by using arrays of resonant controllers, one for the fundamental and one for each harmonic of interest, in order to ach...

  11. Passivity Enhancement of Grid-Tied Converters by Series LC-Filtered Active Damper

    DEFF Research Database (Denmark)

    Bai, Haofeng; Wang, Xiongfei; Loh, Poh Chiang;

    2017-01-01

    The series LC-filtered active damper can be used for stabilizing a grid converter tied to the non-ideal grid. Its operation principle is to mimic a damping resistance at the resonance frequencies appearing in the grid. However, the selection of the damping resistance has not been fully analyzed i...

  12. Tracking and convergence of multi-channel kalman filters for active noise control

    NARCIS (Netherlands)

    Berkhoff, A.; Ophem, S. van

    2013-01-01

    The feed-forward broadband active noise control problem can be formulated as a state estimation problem to achieve a faster rate of convergence than the filtered reference least mean squares algorithm and possibly also a better tracking performance. A multiple input/multiple output Kalman algorithm

  13. Tracking and convergence of multi-channel Kalman filters for active noise control

    NARCIS (Netherlands)

    Berkhoff, A.P.; Ophem, S. van

    2013-01-01

    The feed-forward broadband active noise control problem can be formulated as a state estimation problem to achieve a faster rate of convergence than the filtered reference least mean squares algorithm and possibly also a better tracking performance. A multiple input/multiple output Kalman algorithm

  14. A control architecture to coordinate distributed generators and active power filters coexisting in a microgrid

    DEFF Research Database (Denmark)

    Hashempour, Mohammad M.; Savaghebi, Mehdi; Quintero, Juan Carlos Vasquez

    2016-01-01

    This paper proposes a control architecture of distributed generators (DGs) inverters and shunt active power filters (APFs) in microgrids to compensate voltage harmonics in a coordinated way. For this, a hierarchical control structure is proposed that includes two control levels. The primary (local...

  15. A Control Architecture to Coordinate Distributed Generators and Active Power Filters Coexisting in a Microgrid

    DEFF Research Database (Denmark)

    Hashempour, Mohammad M.; Firoozabadi, Mehdi Savaghebi; Quintero, Juan Carlos Vasquez

    2016-01-01

    This paper proposes a control architecture of distributed generators (DGs) inverters and shunt active power filters (APFs) in microgrids to compensate voltage harmonics in a coordinated way. For this, a hierarchical control structure is proposed that includes two control levels. The primary (local...

  16. Drinking water biotic safety of particles and bacteria attached to fines in activated carbon process

    Institute of Scientific and Technical Information of China (English)

    CHEN Wei; LIN Tao; WANG Leilei

    2007-01-01

    In this paper,the drinking water biotic safety of particles and bacteria attached to fines in activated carbon process was investigated by actual treatment process and advanced treatment pilot trial with granular activated carbon.In the experiment,the particles were detected by IBR particle calculating instrument,the activated carbon fines were counted on the basis of the most probable number (MPN) with a microscope,the total number of bacteria was analyzed between the conventional agar culture medium and the one with R2A,and the bacteria attached to activated carbon fines was resolved by the homogenization technique.The experimental results showed that the average total number of particles was 205 CNT/mL in the activated carbon effluent during a filter cycle,of which the number of particles with sizes>2μm was 77 CNT/mL more than the present particle control criterion of the American drinking water product standard (50 CNT/mL).The backwash of low density and long duration lowered particle number in the effluent.The MPN of activated carbon frees in the effluent was between 400 and 600 CNT/L,which accounted for less than 5‰ of the total particles from activated carbon filtration for a poor relative level (R2= 0.34).The microorganisms in activated carbon effluent consisted mostly of heterotrophic bacillus and the total bacteria number was five times as high as that of the inflow,i.e.the effluent from sand filter.The actual bacteria number may be truly indicated by the detection technique with R2A culture medium compared with the traditional agar cultivation.The inactivation efficiency of bacteria attached to activated carbon fines was less than 40% under 1.1 mg/L of chlorine contacting for 40 min.Results showed that the particles and bacteria attached to activated carbon fines may influence drinking water biotic safety,and that the effective control measures need to be further investigated.

  17. Grid-Voltage-Feedforward Active Damping for Grid-Connected Inverter with LCL Filter

    DEFF Research Database (Denmark)

    Lu, Minghui; Wang, Xiongfei; Blaabjerg, Frede;

    2016-01-01

    For the grid-connected voltage source inverters, the feedforward scheme of grid voltage is commonly adopted to mitigate the current distortion caused by grid background voltages harmonics. This paper investigates the grid-voltage-feedforward active damping for grid connected inverter with LCL fil...... for Phase Locked Loop (PLL). Simulation and experiment results are provided for verifying the theoretical analyses....... filter. It reveals that proportional feedforward control can not only fulfill the mitigation of grid disturbance, but also offer damping effects on the LCL filter resonance. Digital delays are intrinsic to digital controlled inverters; with these delays, the feedforward control can be equivalent...

  18. A Series-LC-Filterd Active Trap Filter for High Power Voltage Source Inverter

    DEFF Research Database (Denmark)

    Bai, Haofeng; Wang, Xiongfei; Loh, Poh Chiang

    2016-01-01

    current control of the auxiliary converter, which can be challenging considering that the switching harmonics have very high orders. In this paper, an Active Trap Filter (ATF) based on output impedance shaping is proposed. It is able to bypass the switching harmonics by providing nearly zero output...... impedance. A series-LC-filter is used to reduce the power rating and synthesize the desired output impedance of the ATF. Compared with the existing approaches, the compensated frequency range is greatly enlarged. Also, the current reference is simply set to zero, which reduces the complexity of the control...

  19. Design of a multilevel Active Power Filter for More Electrical Airplane variable frequency systems

    Science.gov (United States)

    Guerreiro, Joel Filipe; Pomilio, Jose Antenor; Busarello, Tiago Davi Curi

    This paper presents the design and simulation of an Aeronautical Active Power Filter (AAPF) for a Variable Speed Variable Frequency (VSVF) advanced aircraft electric power system. The purposes of the AAPF are to mitigate current harmonics, to improve the source power factor and to mitigate the effects of unbalanced loads. Regarding the fact that the Aircraft Electrical Power System (AEPS) frequency may vary between 360 Hz and 900 Hz, and the load dynamics is often modified, an enhanced filtering technique is required. The designed AAPF topology is an asymmetrical multilevel inverter (AMI), which control strategy is based on the Conservative Power Theory (CPT) and synchronized by a Kalman Filter Phase-Locked Loop (KF-PLL). The above configuration renders the AAPF very robust and effective to its purpose. Accurate simulation results on Matlab/Simulink platform verify the feasibility of the proposed AAPF and the high performance of the control strategy during steady-state and dynamic operations.

  20. A numerical design approach for single amplifier, Active-RC Butterworth filter of order 5

    DEFF Research Database (Denmark)

    Gaunholt, Hans

    2007-01-01

    A design method is presented for the design of all pole lowpass active-RC filters applying operational amplifiers. The operational amplifier model used is the integrator model: omegat/s where omegat is the unity gain frequency. The design method is used for the design of a fifth order Butterworth...... filter applying just one operational amplifier coupled as a unity gain amplifier. It is shown that the influence from the real operational amplifier may be reduced by trimming just one resistor in the circuit. The unity gain amplifiers have the advantage of providing low power consumption, yielding...... a large dynamic range, sometimes simplifying the amplifier design and being usable over a larger frequency range than conventional constant gain amplifiers. The Schoeffler sensitivity index is used as a basis for a sensitivity comparison with other similar filters reported in the literature. © 2007 IEEE....

  1. A multi-standard active-RC filter with accurate tuning system

    Energy Technology Data Exchange (ETDEWEB)

    Ma Heping; Yuan Fang; Shi Yin [Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China); Dai, F F, E-mail: hpma@semi.ac.c [Department of Electrical and Computer Engineering, Auburn University, Auburn, AL 36849-5201 (United States)

    2009-09-15

    A low-power, highly linear, multi-standard, active-RC filter with an accurate and novel tuning architecture is presented. It exhibits IEEE 802.11 a/b/g (9.5 MHz) and DVB-H (3 MHz, 4 MHz) application. The filter exploits digitally-controlled polysilicon resistor banks and a phase lock loop type automatic tuning system. The novel and complex automatic frequency calibration scheme provides better than 4 corner frequency accuracy, and it can be powered down after calibration to save power and avoid digital signal interference. The filter achieves OIP3 of 26 dBm and the measured group delay variation of the receiver filter is 50 ns (WLAN mode). Its dissipation is 3.4 mA in RX mode and 2.3 mA (only for one path) in TX mode from a 2.85 V supply. The dissipation of calibration consumes 2 mA. The circuit has been fabricated in a 0.35 {mu}m 47 GHz SiGe BiCMOS technology; the receiver and transmitter filter occupy 0.21 mm{sup 2} and 0.11 mm{sup 2} (calibration circuit excluded), respectively.

  2. Simultaneous nutrients and carbon removal from low-strength domestic wastewater with an immobilised-microorganism biological aerated filter.

    Science.gov (United States)

    Chen, Q; Qu, L; Tong, G; Ni, J

    2011-01-01

    To improve the efficiency of low-strength domestic wastewater treatment, an immobilised-microorganism biological aerated filter (I-BAF) was established for simultaneous carbon, nitrogen and phosphorus removal. The I-BAF performance was systematically evaluated under continuous and intermittent aeration modes. At the optimal condition with an intermittent aeration control schedule of 2 h on/1 h off, the maximum removal rates of COD, NH(4)(+)-N, TN and P were 82.54%, 94.83%, 51.85% and 61.49%, respectively, and the corresponding averaged effluents could meet the first class standards of China. Further analysis of PCR-DGGE profile revealed that members of the gamma and alpha proteobacterium bacterial groups were probably responsible for the nitrogen and phosphorus removal. The I-BAF system showed excellent performance in carbon and nutrients removal, which provided a cost-effective solution for the treatment of low-strength domestic wastewater.

  3. The effect of substrate bias on titanium carbide/amorphous carbon nanocomposite films deposited by filtered cathodic vacuum arc

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xu, E-mail: zhangxu@bnu.edu.cn [Key Laboratory of Beam Technology and Material Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University (China); Liang, Hong [Key Laboratory of Beam Technology and Material Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University (China); Wu, Zhenglong [Analytical and Testing Center, Beijing Normal University (China); Wu, Xiangying; Zhang, Huixing [Key Laboratory of Beam Technology and Material Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University (China)

    2013-07-15

    The titanium carbide/amorphous carbon nanocomposite films have been deposited on silicon substrate by filtered cathodic vacuum arc (FCVA) technology, the effects of substrate bias on composition, structures and mechanical properties of the films are studied by scanning electron spectroscopy, X-ray diffraction and X-ray photoelectron spectroscopy and nano-indentation. The results show that the Ti content, deposition rate and hardness at first increase and then decrease with increasing the substrate bias. Maximum hardness of the titanium carbide/amorphous carbon nanocomposite film is 51 Gpa prepared at −400 V. The hardness enhancement may be attributed to the compressive stress and the fraction of crystalline TiC phase due to ion bombardment.

  4. New hybrid active power filter for harmonic current suppression and reactive power compensation

    Science.gov (United States)

    Biricik, Samet; Cemal Ozerdem, Ozgur; Redif, Soydan; Sezai Dincer, Mustafa

    2016-08-01

    In the case of undistorted and balanced grid voltages, low ratio shunt active power filters (APFs) can give unity power factors and achieve current harmonic cancellation. However, this is not possible when source voltages are distorted and unbalanced. In this study, the cost-effective hybrid active power filter (HAPF) topology for satisfying the requirements of harmonic current suppression and non-active power compensation for industry is presented. An effective strategy is developed to observe the effect of the placement of power capacitors and LC filters with the shunt APF. A new method for alleviating the negative effects of a nonideal grid voltage is proposed that uses a self-tuning filter algorithm with instantaneous reactive power theory. The real-time control of the studied system was achieved with a field-programmable gate array (FPGA) architecture, which was developed using the OPAL-RT system. The performance result of the proposed HAPF system is tested and presented under nonideal supply voltage conditions.

  5. Activated Carbon Fiber Monoliths as Supercapacitor Electrodes

    Directory of Open Access Journals (Sweden)

    Gelines Moreno-Fernandez

    2017-01-01

    Full Text Available Activated carbon fibers (ACF are interesting candidates for electrodes in electrochemical energy storage devices; however, one major drawback for practical application is their low density. In the present work, monoliths were synthesized from two different ACFs, reaching 3 times higher densities than the original ACFs’ apparent densities. The porosity of the monoliths was only slightly decreased with respect to the pristine ACFs, the employed PVDC binder developing additional porosity upon carbonization. The ACF monoliths are essentially microporous and reach BET surface areas of up to 1838 m2 g−1. SEM analysis reveals that the ACFs are well embedded into the monolith structure and that their length was significantly reduced due to the monolith preparation process. The carbonized monoliths were studied as supercapacitor electrodes in two- and three-electrode cells having 2 M H2SO4 as electrolyte. Maximum capacitances of around 200 F g−1 were reached. The results confirm that the capacitance of the bisulfate anions essentially originates from the double layer, while hydronium cations contribute with a mixture of both, double layer capacitance and pseudocapacitance.

  6. Charcoal and activated carbon at elevated pressure

    Energy Technology Data Exchange (ETDEWEB)

    Antal, M.J. Jr.; Dai, Xiangfeng; Norberg, N. [Univ. of Hawaii at Manoa, Honolulu, HI (United States)] [and others

    1995-12-01

    High quality charcoal has been produced with very high yields of 50% to 60% from macadamia nut and kukui nut shells and of 44% to 47% from Eucalyptus and Leucaena wood in a bench scale unit at elevated pressure on a 2 to 3 hour cycle, compared to commercial practice of 25% to 30% yield on a 7 to 12 day operating cycle. Neither air pollution nor tar is produced by the process. The effects of feedstock pretreatments with metal additives on charcoal yield are evaluated in this paper. Also, the influences of steam and air partial pressure and total pressure on yields of activated carbon from high yield charcoal are presented.

  7. Production of activated carbon from TCR char

    Science.gov (United States)

    Stenzel, Fabian; Heberlein, Markus; Klinner, Tobias; Hornung, Andreas

    2016-04-01

    The utilization of char for adsorptive purposes is known since the 18th century. At that time the char was made of wood or bones and used for decoloration of fluids. In the 20th century the production of activated carbon in an industrial scale was started. The today's raw materials for activated carbon production are hard coal, peat, wood or coconut shells. All these materials entail costs especially the latter. Thus, the utilization of carbon rich residues (biomass) is an interesting economic opportunity because it is available for no costs or even can create income. The char is produced by thermo-catalytic reforming (TCR®). This process is a combination of an intermediate pyrolysis and subsequently a reforming step. During the pyrolysis step the material is decomposed in a vapor and a solid carbon enriched phase. In the second step the vapor and the solid phase get in an intensive contact and the quality of both materials is improved via the reforming process. Subsequently, the condensables are precipitated from the vapor phase and a permanent gas as well as oil is obtained. Both are suitable for heat and power production which is a clear advantage of the TCR® process. The obtained biochar from the TCR® process has special properties. This material has a very low hydrogen and oxygen content. Its stability is comparable to hard coal or anthracite. Therefore it consists almost only of carbon and ash. The latter depends from input material. Furthermore the surface structure and area can be influenced during the reforming step. Depending from temperature and residence time the number of micro pores and the surface area can be increased. Preliminary investigations with methylene blue solution have shown that a TCR® char made of digestate from anaerobic digestion has adsorptive properties. The decoloration of the solution was achieved. A further influencing factor of the adsorption performance is the particle size. Based on the results of the preliminary tests a

  8. ENTRAINED-FLOW ADSORPTION OF MERCURY USING ACTIVATED CARBON

    Science.gov (United States)

    Bench-scale experiments were conducted in a flow reactor to simulate entrained-flow capture of elemental mercury (Hg) by activated carbon. Adsorption of Hg by several commercial activated carbons was examined at different carbon-to-mercury (C:Hg) ratios (by weight) (600:1 - 29000...

  9. Application of a Fused Carbon Nanomaterial Filter for Lunar Dust Abatement Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Seldon Laboratories, LLC, will apply its patented carbon nanotube filtration technology for air and nanoscale particulate engine exhaust filtration to NASA's Lunar...

  10. Application of a Fused Carbon Nanomaterial Filter for Lunar Dust Abatement Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Seldon Technologies will further test and develop its patented carbon nanotube filtration technology to NASA's Lunar Exploration challenges. This project focuses on...

  11. Improved method for the determination of nonpurgeable suspended organic carbon in natural water by silver filter filtration, wet chemical oxidation, and infrared spectrometry

    Science.gov (United States)

    Burkhardt, M.R.; Brenton, R.W.; Kammer, J.A.; Jha, V.K.; O'Mara-Lopez, P. G.; Woodworth, M.T.

    1999-01-01

    Precision and accuracy are reported for the first time for the analysis of nonpurgeable suspended organic carbon by silver membrane filtration followed by wet chemical oxidation. A water sample is pressure filtered through a 0.45-??m-pore-size, 47-mm-diameter silver membrane filter. The silver membrane filter then is cut into ribbons and placed in a flame-sealable glass ampule. The organic material trapped on the membrane filter strips is acidified, purged with oxygen to remove inorganic carbonates and volatile organic compounds, and oxidized to carbon dioxide (CO2) using phosphoric acid and potassium persulfate in the sealed glass ampule. The resulting CO2 is measured by a nondispersive infrared CO2 detector. The amount of CO2 is proportional to the concentration of chemically oxidizable nonpurgeable organic carbon in the environmental water sample. The quantitation and method detection limit for routine analysis is 0.2 mg/L. The average percent recovery in five representative matrices was 97 ?? 11%. The errors associated with sampling and sample preparation of nonpurgeable suspended organic carbon are also described.Precision and accuracy are reported for the first time for the analysis of nonpurgeable suspended organic carbon by silver membrane filtration followed by wet chemical oxidation. A water sample is pressure filtered through a 0.45-??m-pore-size, 47-mm-diameter silver membrane filter. The silver membrane filter then is cut into ribbons and placed in a flame-sealable glass ampule. The organic material trapped on the membrane filter strips is acidified, purged with oxygen to remove inorganic carbonates and volatile organic compounds, and oxidized to carbon dioxide (CO2) using phosphoric acid and potassium persulfate in the sealed glass ampule. The resulting CO2 is measured by a nondispersive infrared CO2 detector. The amount of CO2 is proportional to the concentration of chemically oxidizable nonpurgeable organic carbon in the environmental water sample

  12. Friction properties of amorphous carbon ultrathin films deposited by filtered cathodic vacuum arc and radio-frequency sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Matlak, J.; Komvopoulos, K., E-mail: kyriakos@me.berkeley.edu

    2015-03-31

    The friction properties of ultrathin films of amorphous carbon (a-C) deposited on Si(100) substrates by filtered cathodic vacuum arc and radio-frequency sputtering were investigated by surface force microscopy. Deposition parameters yielding a-C films with high sp{sup 3} content were used to deposit films of thickness between 5 and 35 nm. The coefficient of friction of both types of a-C films was measured with a 1-μm-radius conical diamond tip and normal loads in the range of 20–640 μN. The results show a strong dependence of the friction properties on the surface roughness, thickness, and structure of the a-C films, which are influenced by the intricacies of the deposition method. The dependence of the coefficient of friction on normal load and the dominance of adhesion and plowing friction mechanisms are interpreted in terms of the through-thickness variation of carbon atom hybridization of the a-C films. - Highlights: • Comparison of nanoscale friction properties of ultrathin amorphous carbon films. • Friction dependence on film roughness, thickness, and structure (hybridization). • Effect of through-thickness changes in carbon atom hybridization on film friction. • Explanation of film friction trends in terms of competing friction mechanisms.

  13. Stabilization of Mass Absorption Cross Section of Elemental Carbon for Filter-Based Absorption Photometer by Heated Inlet

    Science.gov (United States)

    Kondo, Y.; Sahu, L.; Takegawa, N.; Miyazaki, Y.; Han, S.; Moteki, N.; Hu, M.; Kim Oanh, N.; Kim, Y.

    2008-12-01

    Accurate measurements of elemental carbon (EC) or black carbon on a long-term basis are important for the studies of impacts of EC on climate and human health. In principle, mass concentrations of EC (MEC) can be estimated by the measurement of light absorption coefficient by EC. Filter-based methods, which quantify the absorption coefficient (kabs) from the change in transmission through a filter loaded with particles, have been widely used to measure MEC because of the ease of the operation. However, in practice, reliable determination of MEC has been very difficult because of the large variability in the mass absorption cross sections (Cabs), which is a conversion factor from kabs to MEC. Coating of EC by volatile compounds and co-existence of light-scattering particles greatly contributes to the variability of Cabs. In order to overcome this difficulty, volatile aerosol components were removed before collection of EC particles on filters by heating an inlet section to 400°C. The heated inlet vaporized almost completely sulfate, nitrate, ammonium, and organics without any detectable loss of EC. Simultaneous measurements of kabs by two types photometers (Particle Soot Absorption Photometer (PSAP) and Continuous Soot Monitoring System (COSMOS)) together with MEC by the EC-OC analyzer were made to determine Cabs at 6 different locations in Asia (Japan, Korea, China, and Thailand) in different seasons. The Cabs was stable to be 10.5±0.7 m2 g-1 at the wavelength of 565 nm for EC strongly impacted by emissions from vehicles and biomass burning. The stability of the Cabs for different EC sources and under the different physical and chemical conditions provides a firm basis for its use in estimating MEC in fine mode with an accuracy of about 10%.

  14. Hysteresis Current Control technique based on Space Vector Modulation for Active Power Filter

    Directory of Open Access Journals (Sweden)

    Wang Yun-liang

    2011-09-01

    Full Text Available In this paper, the hysteresis current control (HCC technique based on space vector modulation (SVM for shunt active power filter (APF is proposed. The switching control algorithms of the HCC based SVM manage to generate compensated current according to the reference current. Harmonics extraction is based on the instantaneous active and reactive power theorem in time domain by calculating the power compensation. A closed loop control system is carried out and the error current is the difference between the reference current which is obtained from the power compensation and the actual current needs to be injected back into the power grid. By implementing this control strategy, the APF manages to generate better compensated harmonics currents to the power grid. Keywords: active power filter, hysteresis current control, space vector modulation ,matlab/simulink

  15. Activated Carbon Fibers For Gas Storage

    Energy Technology Data Exchange (ETDEWEB)

    Burchell, Timothy D [ORNL; Contescu, Cristian I [ORNL; Gallego, Nidia C [ORNL

    2017-01-01

    The advantages of Activated Carbon Fibers (ACF) over Granular Activated Carbon (GAC) are reviewed and their relationship to ACF structure and texture are discussed. These advantages make ACF very attractive for gas storage applications. Both adsorbed natural gas (ANG) and hydrogen gas adsorption performance are discussed. The predicted and actual structure and performance of lignin-derived ACF is reviewed. The manufacture and performance of ACF derived monolith for potential automotive natural gas (NG) storage applications is reported Future trends for ACF for gas storage are considered to be positive. The recent improvements in NG extraction coupled with the widespread availability of NG wells means a relatively inexpensive and abundant NG supply in the foreseeable future. This has rekindled interest in NG powered vehicles. The advantages and benefit of ANG compared to compressed NG offer the promise of accelerated use of ANG as a commuter vehicle fuel. It is to be hoped the current cost hurdle of ACF can be overcome opening ANG applications that take advantage of the favorable properties of ACF versus GAC. Lastly, suggestions are made regarding the direction of future work.

  16. Incremental Activation Detection for Real-Time fMRI Series Using Robust Kalman Filter

    Directory of Open Access Journals (Sweden)

    Liang Li

    2014-01-01

    Full Text Available Real-time functional magnetic resonance imaging (rt-fMRI is a technique that enables us to observe human brain activations in real time. However, some unexpected noises that emerged in fMRI data collecting, such as acute swallowing, head moving and human manipulations, will cause much confusion and unrobustness for the activation analysis. In this paper, a new activation detection method for rt-fMRI data is proposed based on robust Kalman filter. The idea is to add a variation to the extended kalman filter to handle the additional sparse measurement noise and a sparse noise term to the measurement update step. Hence, the robust Kalman filter is designed to improve the robustness for the outliers and can be computed separately for each voxel. The algorithm can compute activation maps on each scan within a repetition time, which meets the requirement for real-time analysis. Experimental results show that this new algorithm can bring out high performance in robustness and in real-time activation detection.

  17. Incremental activation detection for real-time fMRI series using robust Kalman filter.

    Science.gov (United States)

    Li, Liang; Yan, Bin; Tong, Li; Wang, Linyuan; Li, Jianxin

    2014-01-01

    Real-time functional magnetic resonance imaging (rt-fMRI) is a technique that enables us to observe human brain activations in real time. However, some unexpected noises that emerged in fMRI data collecting, such as acute swallowing, head moving and human manipulations, will cause much confusion and unrobustness for the activation analysis. In this paper, a new activation detection method for rt-fMRI data is proposed based on robust Kalman filter. The idea is to add a variation to the extended kalman filter to handle the additional sparse measurement noise and a sparse noise term to the measurement update step. Hence, the robust Kalman filter is designed to improve the robustness for the outliers and can be computed separately for each voxel. The algorithm can compute activation maps on each scan within a repetition time, which meets the requirement for real-time analysis. Experimental results show that this new algorithm can bring out high performance in robustness and in real-time activation detection.

  18. Merging allylic carbon-hydrogen and selective carbon-carbon bond activation

    Science.gov (United States)

    Masarwa, Ahmad; Didier, Dorian; Zabrodski, Tamar; Schinkel, Marvin; Ackermann, Lutz; Marek, Ilan

    2014-01-01

    Since the nineteenth century, many synthetic organic chemists have focused on developing new strategies to regio-, diastereo- and enantioselectively build carbon-carbon and carbon-heteroatom bonds in a predictable and efficient manner. Ideal syntheses should use the least number of synthetic steps, with few or no functional group transformations and by-products, and maximum atom efficiency. One potentially attractive method for the synthesis of molecular skeletons that are difficult to prepare would be through the selective activation of C-H and C-C bonds, instead of the conventional construction of new C-C bonds. Here we present an approach that exploits the multifold reactivity of easily accessible substrates with a single organometallic species to furnish complex molecular scaffolds through the merging of otherwise difficult transformations: allylic C-H and selective C-C bond activations. The resulting bifunctional nucleophilic species, all of which have an all-carbon quaternary stereogenic centre, can then be selectively derivatized by the addition of two different electrophiles to obtain more complex molecular architecture from these easily available starting materials.

  19. Incidence Angle Effect of Energetic Carbon Ions on Deposition Rate, Topography, and Structure of Ultrathin Amorphous Carbon Films Deposited by Filtered Cathodic Vacuum Arc

    KAUST Repository

    Wang, N.

    2012-07-01

    The effect of the incidence angle of energetic carbon ions on the thickness, topography, and structure of ultrathin amorphous carbon (a-C) films synthesized by filtered cathodic vacuum arc (FCVA) was examined in the context of numerical and experimental results. The thickness of a-C films deposited at different incidence angles was investigated in the light of Monte Carlo simulations, and the calculated depth profiles were compared with those obtained from high-resolution transmission electron microscopy (TEM). The topography and structure of the a-C films were studied by atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS), respectively. The film thickness decreased with the increase of the incidence angle, while the surface roughness increased and the content of tetrahedral carbon hybridization (sp 3) decreased significantly with the increase of the incidence angle above 45° , measured from the surface normal. TEM, AFM, and XPS results indicate that the smoothest and thinnest a-C films with the highest content of sp 3 carbon bonding were produced for an incidence angle of 45°. The findings of this study have direct implications in ultrahigh-density magnetic recording, where ultrathin and smooth a-C films with high sp 3 contents are of critical importance. © 2012 IEEE.

  20. Volumetric and superficial characterization of carbon activated; Caracterizacion volumetrica y superficial de carbon activado

    Energy Technology Data Exchange (ETDEWEB)

    Carrera G, L.M.; Garcia S, I.; Jimenez B, J.; Solache R, M.; Lopez M, B.; Bulbulian G, S.; Olguin G, M.T. [Departamento de Quimica, Gerencia de Ciencias Basicas, Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    2000-07-01

    The activated carbon is the resultant material of the calcination process of natural carbonated materials as coconut shells or olive little bones. It is an excellent adsorbent of diluted substances, so much in colloidal form, as in particles form. Those substances are attracted and retained by the carbon surface. In this work is make the volumetric and superficial characterization of activated carbon treated thermically (300 Centigrade) in function of the grain size average. (Author)

  1. DEVELOPMENT OF ACTIVATED CARBONS FROM COAL COMBUSTION BY-PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    Harold H. Schobert; M. Mercedes Maroto-Valer; Zhe Lu

    2003-09-30

    The increasing role of coal as a source of energy in the 21st century will demand environmental and cost-effective strategies for the use of coal combustion by-products (CCBPs), mainly unburned carbon in fly ash. Unburned carbon is nowadays regarded as a waste product and its fate is mainly disposal, due to the present lack of efficient routes for its utilization. However, unburned carbon is a potential precursor for the production of adsorbent carbons, since it has gone through a devolatilization process while in the combustor, and therefore, only requires to be activated. Accordingly, the principal objective of this work was to characterize and utilize the unburned carbon in fly ash for the production of activated carbons. The unburned carbon samples were collected from different combustion systems, including pulverized utility boilers, a utility cyclone, a stoker, and a fluidized bed combustor. LOI (loss-on-ignition), proximate, ultimate, and petrographic analyses were conducted, and the surface areas of the samples were characterized by N2 adsorption isotherms at 77K. The LOIs of the unburned carbon samples varied between 21.79-84.52%. The proximate analyses showed that all the samples had very low moisture contents (0.17 to 3.39 wt %), while the volatile matter contents varied between 0.45 to 24.82 wt%. The elemental analyses show that all the unburned carbon samples consist mainly of carbon with very little hydrogen, nitrogen, sulfur and oxygen In addition, the potential use of unburned carbon as precursor for activated carbon (AC) was investigated. Activated carbons with specific surface area up to 1075m{sup 2}/g were produced from the unburned carbon. The porosity of the resultant activated carbons was related to the properties of the unburned carbon feedstock and the activation conditions used. It was found that not all the unburned carbon samples are equally suited for activation, and furthermore, their potential as activated carbons precursors could be

  2. Study of CO2 adsorption capacity of mesoporous carbon and activated carbon modified by triethylenetetramine (TETA)

    Science.gov (United States)

    Sulistianti, I.; Krisnandi, Y. K.; Moenandar, I.

    2017-04-01

    Mesoporous carbon was synthesized by soft template method using phloroglucinol and formaldehyde as a carbon source; and Pluronic F-127 as a mesoporous template. The synthesized mesoporous carbon and commercial activated carbon were modified with triethylenetetramine (TETA) to increase CO2 adsorption capacity. Based on FTIR characterization, the synthesized mesoporous carbon and the activated carbon without modification process has similarity pattern. After the modification, both of them showed absorption peaks in the area around 1580 to 1650 cm-1 which is known as N-H bending vibration and absorption peaks in the area around 3150 to 3380 cm-1 which is known as N-H stretching vibration. The XRD results showed two peaks at 2θ = 24.21° and 2θ = 43.85°, according to JCPDS index No. 75-1621 those peak are the typical peaks for hexagonal graphite carbon. In BET analysis, the synthesized mesoporous carbon and activated carbon modified TETA have surface area, pore volume and pore diameter lower than without modification process. In carbon dioxide adsorption testing, the synthesized mesoporous carbon showed better performance than the commercial activated carbon for CO2 adsorption both without modification and by modification. The synthesized mesoporous carbon obtained CO2 adsorption of 9.916 mmol/g and the activated carbon of 3.84 mmol/g for on 3.5 hours of adsorption. It is three times better than activated carbon for adsorption of carbon dioxide. The modified mesoporous carbon has the best performance for adsorption of gas CO2 if compared by unmodified.

  3. Superhydrophobic activated carbon-coated sponges for separation and absorption.

    Science.gov (United States)

    Sun, Hanxue; Li, An; Zhu, Zhaoqi; Liang, Weidong; Zhao, Xinhong; La, Peiqing; Deng, Weiqiao

    2013-06-01

    Highly porous activated carbon with a large surface area and pore volume was synthesized by KOH activation using commercially available activated carbon as a precursor. By modification with polydimethylsiloxane (PDMS), highly porous activated carbon showed superhydrophobicity with a water contact angle of 163.6°. The changes in wettability of PDMS- treated highly porous activated carbon were attributed to the deposition of a low-surface-energy silicon coating onto activated carbon (confirmed by X-ray photoelectron spectroscopy), which had microporous characteristics (confirmed by XRD, SEM, and TEM analyses). Using an easy dip-coating method, superhydrophobic activated carbon-coated sponges were also fabricated; those exhibited excellent absorption selectivity for the removal of a wide range of organics and oils from water, and also recyclability, thus showing great potential as efficient absorbents for the large-scale removal of organic contaminants or oil spills from water.

  4. Active slag filters-simple and sustainable phosphorus removal from wastewater using steel industry byproduct.

    Science.gov (United States)

    Pratt, C; Shilton, A

    2010-01-01

    Active filtration, where effluent is passed through a reactive substrate such as steel slag, offers a simple and cost-effective option for removing phosphorus (P) from effluent. This work summarises a series of studies that focused on the world's only full-scale active slag filter operated through to exhaustion. The filter achieved 75% P-removal during its first 5 years, reaching a retention capacity of 1.23 g P/kg slag but then its performance sharply declined. Scanning electron microscopy, X-ray diffraction, X-ray fluorescence, and chemical extractions revealed that P sequestration was primarily achieved via adsorption onto iron (Fe) oxyhydroxides on the slag's surface. It was concluded that batch equilibrium tests, whose use has been repeatedly proposed in the literature, cannot be used as an accurate predictor of filter adsorption capacity because Fe oxyhydroxides form via chemical weathering in the field, and laboratory tests don't account for this. Research into how chemical conditions affect slag's P retention capacity demonstrated that near-neutral pH and high redox are optimal for Fe oxyhydroxide stability and overall filter performance. However, as Fe oxyhydroxide sites fill up, removal capacity becomes exhausted. Attempts to regenerate P removal efficiency using physical techniques proved ineffective contrary to dogma in the literature. Based on the newly-developed understanding of the mechanisms of P removal, chemical regeneration techniques were investigated and were shown to strip large quantities of P from filter adsorption sites leading to a regenerated P removal efficiency. This raises the prospect of developing a breakthrough technology that can repeatedly remove and recover P from effluent.

  5. Metal-carbon nanocomposites based on activated IR pyrolized polyacrylonitrile

    Energy Technology Data Exchange (ETDEWEB)

    Efimov, Mikhail N.; Zhilyaeva, Natalya A.; Vasilyev, Andrey A.; Muratov, Dmitriy G.; Zemtsov, Lev M.; Karpacheva, Galina P. [A.V. Topchiev Institute of Petrochemical Synthesis RAS, Leninskiy Prospekt 29, 119991 Moscow Russia (Russian Federation)

    2016-05-18

    In this paper we report about new approach to preparation of metal-carbon nanocomposites based on activated carbon. Polyacrylonitrile is suggested as a precursor for Co, Pd and Ru nanoparticles carbon support which is prepared under IR pyrolysis conditions of a precursor. The first part of the paper is devoted to study activated carbon structural characteristics dependence on activation conditions. In the second part the effect of type of metal introduced in precursor on metal-carbon nanocomposite structural characteristics is shown. Prepared AC and nanocomposite samples are characterized by BET, TEM, SEM and X-ray diffraction.

  6. Control System Design of Shunt Active Power Filter Based on Active Disturbance Rejection and Repetitive Control Techniques

    OpenAIRE

    Le Ge; Xiaodong Yuan; Zhong Yang

    2014-01-01

    To rely on joint active disturbance rejection control (ADRC) and repetitive control (RC), in this paper, a compound control law for active power filter (APF) current control system is proposed. According to the theory of ADRC, the uncertainties in the model and from the circumstance outside are considered as the unknown disturbance to the system. The extended state observer can evaluate the unknown disturbance. Next, RC is introduced into current loop to improve the steady characteristics. Th...

  7. Ozonation of benzothiazole saturated-activated carbons: Influence of carbon chemical surface properties

    Energy Technology Data Exchange (ETDEWEB)

    Valdes, H. [Facultad de Ingenieria, Universidad Catolica de la Santisima Concepcion, Caupolican 491, Concepcion (Chile)]. E-mail: hvaldes@ucsc.cl; Zaror, C.A. [Departamento de Ingenieria Quimica (F. Ingenieria), Universidad de Concepcion, Correo 3, Casilla 160-C, Concepcion (Chile)

    2006-09-21

    The combined or sequential use of ozone and activated carbon to treat toxic effluents has increased in recent years. However, little is known about the influence of carbon surface active sites on ozonation of organic adsorbed pollutants. This paper presents experimental results on the effect of metal oxides and oxygenated surface groups on gaseous ozonation of spent activated carbons. Benzothiazole (BT) was selected as a target organic compound in this study due to its environmental concern. Activated carbons with different chemical surface composition were prepared from a Filtrasorb-400 activated carbon. Pre-treatment included: ozonation, demineralisation, and deoxygenation of activated carbon. Ozonation experiments of BT saturated-activated carbons were conducted in a fixed bed reactor loaded with 2 g of carbon samples. The reactor was fed with an O{sub 2}/O{sub 3} gas mixture (2 dm{sup 3}/min, 5 g O{sub 3}/h), for a given exposure time, in the range 10-120 min, at 298 K and 1 atm. Results show that extended gaseous ozonation of activated carbon saturated with BT led to the effective destruction of the adsorbate by oxidation reactions. Oxidation of BT adsorbed on activated carbon seemed to occur via both direct reaction with ozone molecules, and by oxygen radical species generated by catalytic ozone decomposition on metallic surface sites.

  8. Impact of Cylinder Deactivation on Active Diesel Particulate Filter Regeneration at Highway Cruise Conditions

    Directory of Open Access Journals (Sweden)

    Xueting eLu

    2015-08-01

    Full Text Available Abstract—Heavy-duty over-the-road trucks require periodic active diesel particulate filter regeneration to clean the filter of stored particulate matter. These events require sustained temperatures between 500 and 600□C to complete the regeneration process. Engine operation during typical 65 mile/hour highway cruise conditions (1200 rpm/7.6 bar results in temperatures of approximately 350□C, and can reach approximately 420□C with late fuel injection. This necessitates hydrocarbon fueling of a diesel oxidation catalyst or burner located upstream of the diesel particulate filter to reach the required regeneration temperatures. These strategies require increased fuel consumption, and the presence of a fuel-dosed oxidation catalyst (or burner between the engine and particulate filter. This paper experimentally demonstrates that, at the highway cruise condition, deactivation of valve motions and fuel injection for two or three (of six cylinders can instead be used to reach engine outlet temperatures of 520-570□C, a 170-220□C increase compared to normal operation. This is primarily a result of a reduction in the air-to-fuel ratio realized by reducing the displaced cylinder volume through cylinder deactivation.

  9. Design and real time implementation of fuzzy switched controller for single phase active power filter.

    Science.gov (United States)

    Afghoul, Hamza; Krim, Fateh; Chikouche, Djamel; Beddar, Antar

    2015-09-01

    This paper proposes a novel fuzzy switched controller (FSC) integrated in direct current control (DCC) algorithm for single phase active power filter (SPAPF). The controller under study consists of conventional PI controller, fractional order PI controller (FO-PI) and fuzzy decision maker (FDM) that switches between them using reduced fuzzy logic control. The proposed controller offers short response time with low damping and deals efficiently with the external disturbances while preserving the robustness properties. To fulfill the requirements of power quality, unity power factor and harmonics limitations in active power filtering an experimental test bench has been built using dSPACE 1104 to demonstrate the feasibility and effectiveness of the proposed controller. The obtained results present high performance in steady and transient states. Copyright © 2015 ISA. Published by Elsevier Ltd. All rights reserved.

  10. Adaptive Current Control with PI-Fuzzy Compound Controller for Shunt Active Power Filter

    Directory of Open Access Journals (Sweden)

    Juntao Fei

    2013-01-01

    Full Text Available An adaptive control technology and PI-fuzzy compound control technology are proposed to control an active power filter (APF. AC side current compensation and DC capacitor voltage tracking control strategy are discussed and analyzed. Model reference adaptive controller for the AC side current compensation is derived and established based on Lyapunov stability theory; proportional and integral (PI fuzzy compound controller is designed for the DC side capacitor voltage control. The adaptive current controller based on PI-fuzzy compound system is compared with the conventional PI controller for active power filter. Simulation results demonstrate the feasibility and satisfactory performance of the proposed control strategies. It is shown that the proposed control method has an excellent dynamic performance such as small current tracking error, reduced total harmonic distortion (THD, and strong robustness in the presence of parameters variation and nonlinear load.

  11. LCL-Filter Design for Robust Active Damping in Grid-Connected Converters

    DEFF Research Database (Denmark)

    Pena-Alzola, Rafael; Liserre, Marco; Blaabjerg, Frede;

    2014-01-01

    Grid-connected converters employ LCL-filters, instead of simple inductors, because they allow lower inductances while reducing cost and size. Active damping, without dissipative elements, is preferred to passive damping for solving the associated stability problems. However, large variations...... in the grid inductance may compromise system stability, and this problem is more severe for parallel converters. This situation, typical of rural areas with solar and wind resources, calls for robust LCL-filter design. This paper proposes a design procedure with remarkable results under severe grid inductance...... variation. The procedure considers active damping using lead-lag network and capacitor current feedback. Passive damping is also discussed. The design flow, with little iteration and no complex algorithms, selects the proper ratios between the switching and resonance frequency, the grid and converter...

  12. Active plasmonic band-stop filters based on graphene metamaterial at THz wavelengths.

    Science.gov (United States)

    Wei, Zhongchao; Li, Xianping; Yin, Jianjun; Huang, Rong; Liu, Yuebo; Wang, Wei; Liu, Hongzhan; Meng, Hongyun; Liang, Ruisheng

    2016-06-27

    Active plasmonic band-stop filters based on single- and double-layer doped graphene metamaterials at the THz wavelengths are proposed and investigated numerically by using the finite-difference time-domain (FDTD) method. The metamaterial unit cell structure is composed of two parallel graphene nanoscale ribbons. Simulated results exhibit that significant resonance wavelength shifts can be achieved with a slight variation of the doping concentration of the graphene ribbons. Besides, the asymmetry double-layer graphene metamaterial device has two apparent filter dips while the symmetry single-, double-layer and asymmetry single-layer graphene metamaterial devices just only one. The metamaterials with symmetry single-layer and asymmetry double-layer graphene can be used as a high-sensitivity refractive sensor with the sensitivity up to 5100 nm/RIU and a two-circuit switch, respectively. These prospects pave the way towards ultrafast active graphene-based plasmonic devices for THz applications.

  13. The steady-state performance of a controlled current active filter

    Energy Technology Data Exchange (ETDEWEB)

    Duke, R.M. (Univ. of Canterbury, Christchurch (New Zealand). Dept. of Electrical and Electronic Engineering); Round, S.D. (Univ. of Minnesota, Minneapolis, MN (United States). Dept. of Electrical Engineering)

    1993-04-01

    An active filter that uses a high-frequency D-class asynchronous switching inverter for power system current distortion compensation is described. The distortion compensation technique involves deriving a signal corresponding to the distortion component of load current, and inverting and amplifying this signal for addition back to the supply current to cancel the load current distortion. A synthetic sinusoid is used to determine the distortion component in the time domain. Extensive computed and experimental results, illustrating the system's steady-state performance and ability to reduce the current harmonic distortion components, are presented. An intelligent controller is proposed to maintain the active filter's performance at the optimal operating point under varying load conditions.

  14. Performance of a grid connected PV system used as active filter

    Energy Technology Data Exchange (ETDEWEB)

    Calleja, H. [Cenidet, Morelos (Mexico). Electronics Dept.; Jimenez, H. [IIE, Morelos (Mexico). Conventional Energy Sources Dept.

    2004-09-01

    In this paper, the performance of a grid connected photovoltaic (PV) system used as an active filter is presented. its main feature is the capability to compensate the reactive and harmonic currents drawn by nonlinear loads while simultaneously injecting into the grid the maximum power available from the cells. The system can also operate as a stand alone active filter. The system was connected to a 1 kW PV array and tested with the loads typically found in households: small motors, personal computers and electronic ballasts. The results show that the system can correct the power factor to values close to unity for all the cases tested, thereby improving the efficiency of the electric energy supply. (author)

  15. Enhanced adsorption of humic acids on ordered mesoporous carbon compared with microporous activated carbon.

    Science.gov (United States)

    Liu, Fengling; Xu, Zhaoyi; Wan, Haiqin; Wan, Yuqiu; Zheng, Shourong; Zhu, Dongqiang

    2011-04-01

    Humic acids are ubiquitous in surface and underground waters and may pose potential risk to human health when present in drinking water sources. In this study, ordered mesoporous carbon was synthesized by means of a hard template method and further characterized by X-ray diffraction, N2 adsorption, transition electron microscopy, elemental analysis, and zeta-potential measurement. Batch experiments were conducted to evaluate adsorption of two humic acids from coal and soil, respectively, on the synthesized carbon. For comparison, a commercial microporous activated carbon and nonporous graphite were included as additional adsorbents; moreover, phenol was adopted as a small probe adsorbate. Pore size distribution characterization showed that the synthesized carbon had ordered mesoporous structure, whereas the activated carbon was composed mainly of micropores with a much broader pore size distribution. Accordingly, adsorption of the two humic acids was substantially lower on the activated carbon than on the synthesized carbon, because of the size-exclusion effect. In contrast, the synthesized carbon and activated carbon showed comparable adsorption for phenol when the size-exclusion effect was not in operation. Additionally, we verified by size-exclusion chromatography studies that the synthesized carbon exhibited greater adsorption for the large humic acid fraction than the activated carbon. The pH dependence of adsorption on the three carbonaceous adsorbents was also compared between the two test humic acids. The findings highlight the potential of using ordered mesoporous carbon as a superior adsorbent for the removal of humic acids.

  16. Activated Carbon Composites for Air Separation

    Energy Technology Data Exchange (ETDEWEB)

    Baker, Frederick S [ORNL; Contescu, Cristian I [ORNL; Tsouris, Costas [ORNL; Burchell, Timothy D [ORNL

    2011-09-01

    Coal-derived synthesis gas is a potential major source of hydrogen for fuel cells. Oxygen-blown coal gasification is an efficient approach to achieving the goal of producing hydrogen from coal, but a cost-effective means of enriching O2 concentration in air is required. A key objective of this project is to assess the utility of a system that exploits porous carbon materials and electrical swing adsorption to produce an O2-enriched air stream for coal gasification. As a complement to O2 and N2 adsorption measurements, CO2 was used as a more sensitive probe molecule for the characterization of molecular sieving effects. To further enhance the potential of activated carbon composite materials for air separation, work was implemented on incorporating a novel twist into the system; namely the addition of a magnetic field to influence O2 adsorption, which is accompanied by a transition between the paramagnetic and diamagnetic states. The preliminary findings in this respect are discussed.

  17. Carrier phase shifted SPWM based on current sourced multi-modular converter for active power filter

    Institute of Scientific and Technical Information of China (English)

    王立乔; 李建林; 张仲超

    2004-01-01

    A novel current-source active power filter(APF)based on multi-modular converter with carrier phase-shifted SPWM(CPS-SPWM)technique is proposed.With this technique,the effect of equivalent high switching frequency converter is obtained with low switching frequency converter.It is very promising in current-source APF that adopt superconducting magnetic energy storage component.

  18. Thermal Filters for the ATHENA X-IFU: Ongoing Activities Toward the Conceptual Design

    Science.gov (United States)

    Barbera, Marco; Argan, A.; Bozzo, E.; Branduardi-Raymont, G.; Ciaravella, A.; Collura, A.; Cuttaia, F.; Gatti, F.; Jimenez Escobar, A.; Lo Cicero, U.; Lotti, S.; Macculi, C.; Mineo, T.; Nuzzo, F.; Paltani, S.; Parodi, G.; Piro, L.; Rauw, G.; Sciortino, L.; Sciortino, S.; Villa, F.

    2016-08-01

    ATHENA is the L2 mission selected by ESA to pursue the science theme "Hot and Energetic Universe." One of the two focal plane instruments is the X-ray Integral Field Unit, an array of TES microcalorimeters operated at T RF electromagnetic interferences on TES sensors and SQUID electronics, and to protect the detector from contamination. This paper reviews the ongoing activities driving the design of the X-IFU thermal filters.

  19. Digital Realization of Capacitor-Voltage Feedback Active Damping for LCL-Filtered Grid Converters

    DEFF Research Database (Denmark)

    Xin, Zhen; Wang, Xiongfei; Loh, Poh Chiang

    2015-01-01

    The capacitor voltage of an LCL-filter can also be used for active damping, if it is fed back for synchronization. By this way, an extra current sensor can be avoided. Compared with the existing active damping techniques designed with capacitor current feedback, the capacitor voltage feedback....... To overcome their drawbacks, a new derivative method is then proposed, based on the non-ideal generalized integrator. The performance of the proposed derivative has been found to match the ideal “s” function closely. Active damping based on capacitor voltage feedback can therefore be realized accurately...

  20. DPC controlled three-phase active filter for power quality improvement

    Energy Technology Data Exchange (ETDEWEB)

    Chaoui, Abdelmadjid; Krim, Fateh [Laboratoire d' Electronique de Puissance et Commande Industrielle (LEPCI), Universite de Setif (Algeria); Gaubert, Jean-Paul; Rambault, Laurent [Laboratoire d' Automatique et d' Informatique Industrielle (LAII-ESIP), Universite de Poitiers (France)

    2008-10-15

    This paper presents a new control method entitled direct power control (DPC) for shunt active power filtering (5th, 7th, 11th,..) (SAPF), which is applied to eliminate line current harmonics and compensate reactive power. Its main goal is to rebuild active and reactive powers to be compared to references values using hysteresis control. The outputs of hysteresis controllers associated with a switching table, control the instantaneous active and reactive power by selecting the optimum switching state of the voltage source inverter (VSI). A theoretical analysis with a complete simulation of the system and experimental results are presented to prove the excellent performance of the proposed control technique. (author)

  1. Reuse performance of granular-activated carbon and activated carbon fiber in catalyzed peroxymonosulfate oxidation.

    Science.gov (United States)

    Yang, Shiying; Li, Lei; Xiao, Tuo; Zhang, Jun; Shao, Xueting

    2017-03-01

    Recently, activated carbon was investigated as an efficient heterogeneous metal-free catalyst to directly activate peroxymonosulfate (PMS) for degradation of organic compounds. In this paper, the reuse performance and the possible deactivation reasons of granular-activated carbon (GAC) and activated carbon fiber (ACF) in PMS activation were investigated. As results indicated, the reusability of GAC, especially in the presence of high PMS dosage, was relatively superior to ACF in catalyzed PMS oxidation of Acid Orange 7 (AO7), which is much more easily adsorbed by ACF than by GAC. Pre-oxidation experiments were studied and it was demonstrated that PMS oxidation on ACF would retard ACF's deactivation to a big extent. After pre-adsorption with AO7, the catalytic ability of both GAC and ACF evidently diminished. However, when methanol was employed to extract the AO7-spent ACF, the catalytic ability could recover quite a bit. GAC and ACF could also effectively catalyze PMS to degrade Reactive Black 5 (RB5), which is very difficult to be adsorbed even by ACF, but both GAC and ACF have poor reuse performance for RB5 degradation. The original organic compounds or intermediate products adsorbed by GAC or ACF would be possibly responsible for the deactivation.

  2. Highly porous activated carbons prepared from carbon rich Mongolian anthracite by direct NaOH activation

    Science.gov (United States)

    Byamba-Ochir, Narandalai; Shim, Wang Geun; Balathanigaimani, M. S.; Moon, Hee

    2016-08-01

    Highly porous activated carbons (ACs) were prepared from Mongolian raw anthracite (MRA) using sodium hydroxide as an activation agent by varying the mass ratio (powdered MRA/NaOH) as well as the mixing method of chemical agent and powdered MRA. The specific BET surface area and total pore volume of the prepared MRA-based activated carbons (MACs) are in the range of 816-2063 m2/g and of 0.55-1.61 cm3/g, respectively. The pore size distribution of MACs show that most of the pores are in the range from large micropores to small mesopores and their distribution can be controlled by the mass ratio and mixing method of the activating agent. As expected from the intrinsic property of the MRA, the highly graphitic surface morphology of prepared carbons was confirmed from Raman spectra and transmission electron microscopy (TEM) studies. Furthermore the FTIR and XPS results reveal that the preparation of MACs with hydrophobic in nature is highly possible by controlling the mixing conditions of activating agent and powdered MRA. Based on all the results, it is suggested that the prepared MACs could be used for many specific applications, requiring high surface area, optimal pore size distribution, proper surface hydrophobicity as well as strong physical strength.

  3. A Novel Approach in Design of a Fuzzy Based Shunt Active Power Filter for the Enhancement of Power Quality

    Directory of Open Access Journals (Sweden)

    Soumya I C

    2014-03-01

    Full Text Available Active power filters most of the times are employed for elimination of the harmonics created by non-linear loads in power system and for reactive power compensation of linear and non-linear loads. Compensating current is sent by shunt active power filter (SAF at Point of Common Coupling (PCC to mitigate current harmonics in the line. Hence sinusoidal nature of current and voltage waveforms are reintroduced. Usually shunt active power filters are connected in parallel with non-linear and reactive loads. Fuzzy logic controller is used as it doesn’t require complex mathematical model. Filter inductor current is shaped by fuzzy controller so that line current is in phase with and of input voltage shape. Simulation of the proposed filter is carried out using MATLAB/SIMULINK.

  4. Characterization of Activated Carbons from Oil-Palm Shell by CO2 Activation with No Holding Carbonization Temperature

    Directory of Open Access Journals (Sweden)

    S. G. Herawan

    2013-01-01

    Full Text Available Activated carbons can be produced from different precursors, including coals of different ranks, and lignocellulosic materials, by physical or chemical activation processes. The objective of this paper is to characterize oil-palm shells, as a biomass byproduct from palm-oil mills which were converted into activated carbons by nitrogen pyrolysis followed by CO2 activation. The effects of no holding peak pyrolysis temperature on the physical characteristics of the activated carbons are studied. The BET surface area of the activated carbon is investigated using N2 adsorption at 77 K with selected temperatures of 500, 600, and 700°C. These pyrolysis conditions for preparing the activated carbons are found to yield higher BET surface area at a pyrolysis temperature of 700°C compared to selected commercial activated carbon. The activated carbons thus result in well-developed porosities and predominantly microporosities. By using this activation method, significant improvement can be obtained in the surface characteristics of the activated carbons. Thus this study shows that the preparation time can be shortened while better results of activated carbon can be produced.

  5. Active damping of LLCL-filter resonance based on LC-trap voltage and capacitor current feedback

    DEFF Research Database (Denmark)

    Huang, Min; Wang, Xiongfei; Loh, Poh Chiang

    2015-01-01

    . In this paper, different feedback coefficients like the proportional, derivative, integral, high pass and low pass feedback coefficients of the filter capacitor current and the LC-trap circuit voltage are investigated for damping the filter resonance. Active damping methods are analyzed by using the concept...

  6. Systematic Design of the Lead-Lag Network Method for Active Damping in LCL-Filter Based Three Phase Converters

    DEFF Research Database (Denmark)

    Alzola, Rafael Pena; Liserre, Marco; Blaabjerg, Frede

    2014-01-01

    Three-phase active rectifiers guarantee sinusoidal input currents and unity power factor at the price of a high switching frequency ripple. To adopt an LCL-filter, instead of an L-filter, allows using reduced values for the inductances and so preserving dynamics. However, stability problems can...

  7. Convergence analysis of the Filtered-U LMS algorithm for active noise control in case perfect cancellation is not possible

    NARCIS (Netherlands)

    Fraanje, P.R.; Verhaegen, M.; Doelman, N.J.

    2003-01-01

    The Filtered-U LMS algorithm, proposed by Eriksson for active noise control applications, adapts the coefficients of an infinite-impulse response controller. Conditions for global convergence of the Filtered-U LMS algorithm were presented by Wang and Ren (Signal Processing, 73 (1999) 3) and Mosquera

  8. THE ROLE OF ACTIVATED CARBON IN SOLVING ECOLOGICAL PROBLEMS

    Directory of Open Access Journals (Sweden)

    V. M. Mukhin

    2008-06-01

    Full Text Available The authors present a brief analysis of the current global situation concerning the utilization of activated carbon in various fields. The article presents data concerning the synthesis and adsorption and structure properties of new activated carbons, used for solving ecological problems. The authors investigated the newly obtained activated carbons in comparison with several AC marks known in the world. It has been shown that currently synthesized AC are competitive with foreign marks.

  9. HYDROGEN SULFIDE ADSORPTION BY ALKALINE IMPREGNATED COCONUT SHELL ACTIVATED CARBON

    Directory of Open Access Journals (Sweden)

    HUI SUN CHOO

    2013-12-01

    Full Text Available Biogas is one type of renewable energy which can be burnt to produce heat and electricity. However, it cannot be burnt directly due to the presence of hydrogen sulfide (H2S which is highly corrosive to gas engine. In this study, coconut shell activated carbon (CSAC was applied as a porous adsorbent for H2S removal. The effect of amount of activated carbon and flow rate of gas stream toward adsorption capacity were investigated. Then, the activated carbons were impregnated by three types of alkaline (NaOH, KOH and K2CO3 with various ratios. The effects of various types of alkaline and their impregnation ratio towards adsorption capacity were analysed. In addition, H2S influent concentration and the reaction temperature on H2S adsorption were also investigated. The result indicated that adsorption capacity increases with the amount of activated carbon and decreases with flow rate of gas stream. Alkaline impregnated activated carbons had better performance than unimpregnated activated carbon. Among all impregnated activated carbons, activated carbon impregnated by K2CO3 with ratio 2.0 gave the highest adsorption capacity. Its adsorption capacity was 25 times higher than unimpregnated activated carbon. The result also indicated that the adsorption capacity of impregnated activated carbon decreased with the increment of H2S influent concentration. Optimum temperature for H2S adsorption was found to be 50˚C. In this study, the adsorption of H2S on K2CO3 impregnated activated carbon was fitted to the Langmuir isotherm. The fresh and spent K2CO3 impregnated activated carbon were characterized to study the adsorption process.

  10. Preparation of a MFI zeolite coating on activated carbon

    NARCIS (Netherlands)

    Vaart, van der R.; Bosch, H.; Keizer, K.; Reith, T.

    1997-01-01

    A new and simple method for the preparation of MFI zeolite coated activated carbon is presented. Suitable nucleation sites for the growth of zeolites were introduced to the carbon by adding hydrophilic montmorillonite clay to the carbon substrate. A gas tight MFI zeolite coating was obtained on this

  11. Single and Mixed Gas Adsorption Equilibria of Carbon Dioxide/Methane on Activated Carbon

    NARCIS (Netherlands)

    van der Vaart, R.; van der Vaart, Rick; Huiskes, Cindy; Bosch, H.; Reith, T.

    2000-01-01

    Single gas adsorption isotherms of methane and carbon dioxide on micro-porous Norit RB1 activated carbon were determined in a gravimetric analyser in the temperature range of 292 to 349 K and pressures to 0.8 Mpa. Furthermore binary isotherms of carbon dioxide and methane mixtures were determined at

  12. Water treatment with exceptional virus inactivation using activated carbon modified with silver (Ag) and copper oxide (CuO) nanoparticles.

    Science.gov (United States)

    Shimabuku, Quelen Letícia; Arakawa, Flávia Sayuri; Fernandes Silva, Marcela; Ferri Coldebella, Priscila; Ueda-Nakamura, Tânia; Fagundes-Klen, Márcia Regina; Bergamasco, Rosangela

    2017-08-01

    Continuous flow experiments (450 mL min(-1)) were performed in household filter in order to investigate the removal and/or inactivation of T4 bacteriophage, using granular activated carbon (GAC) modified with silver and/or copper oxide nanoparticles at different concentrations. GAC and modified GAC were characterized by X-ray diffractometry, specific surface area, pore size and volume, pore average diameter, scanning electron microscopy, transmission electron microscopy, zeta potential and atomic absorption spectroscopy. The antiviral activity of the produced porous media was evaluated by passing suspensions of T4 bacteriophage (∼10(5) UFP/mL) through filters. The filtered water was analyzed for the presence of the bacteriophage and the release of silver and copper oxide. The porous media containing silver and copper oxide nanoparticles showed high inactivation capacity, even reaching reductions higher than 3 log. GAC6 (GAC/Ag0.5%Cu1.0%) was effective in the bacteriophage inactivation, reaching 5.53 log reduction. The levels of silver and copper released in filtered water were below the recommended limits (100 ppb for silver and 1000 ppb for copper) in drinking water. From this study, it is possible to conclude that activated carbon modified with silver and copper oxide nanoparticles can be used as a filter for virus removal in the treatment of drinking water.

  13. Production of activated carbon from a new precursor: Molasses

    Science.gov (United States)

    Legrouri, K.; Ezzine, M.; Ichcho, S.; Hannache, H.; Denoyel, R.; Pailler, R.; Naslain, R.

    2005-03-01

    Activated carbon has been prepared from molasses, a natural precursor of vegetable origin resulting from the sugar industry in Morocco. The preparation of the activated carbon from the molasses has been carried out by impregnation of the precursor with sulfuric acid, followed by carbonization. The adsorption capacity, the BET surface area, and the pore volume of the activated carbon were determined. The micropore volume was assessed by Dubinin- Radushkevich (DR) equation. The activated materials are mainly microporous and show the type I isotherm of the Brunauer classification for nitrogen adsorption. The activation in steam yielded a carbon that contains both micropores and supermicropores. Analysis of the nitrogen isotherm by BET and DR methods established that most of obtained carbons are highly microporous, with high surface areas (≥ 1200 m2/g) and very low mesoporosity.

  14. Effect of biostimulation on biodegradation of dissolved organic carbon in biological filters

    Directory of Open Access Journals (Sweden)

    K. Tihomirova

    2012-07-01

    Full Text Available The addition of labile organic carbon (LOC to enhance the biodegradation rate of dissolved organic carbon (DOC in biological columns was studied. Acetate standard solution (NaAc and Luria Bertrani (LB medium were used as LOC as biostimulants in glass column system used for measurements of biodegradable dissolved organic carbon (BDOC. The addition of LOC related with the increase of total DOC in sample. The concentration of BDOC increased up to 7 and 5 times and was utilized after 24 min. contact time. The biodegradation rate constant was increased at least 26 times during adaptation-biostimulation period. There was a strong positive correlation between the biodegradation rate constant and the concentration of BDOC. Biostimulation period ranged from 24 to 53 h for NaAc biostimulant and from 20 to 168 h for LB. The study has shown that LOC could be used as stimulator to enhance the biodegradation rate of DOC during biofiltration.

  15. Impact of exogenous organic carbon on the removal of chemicals of concern in the high rate nitrifying trickling filters.

    Science.gov (United States)

    Mai, Lei; van den Akker, Ben; Du, Jun; Kookana, Rai S; Fallowfield, Howard

    2016-06-01

    The application of fixed bed high rate nitrifying trickling filters (NTFs) for the removal of track organic chemicals of concern (CoC) is less well known than their application to nutrient removal in water treatment. Particularly, the effect of exogenous organic carbon substrate (sucrose) loading on the performance of NTFs is not well understood. A laboratory-scale NTF system was operated in recirculation mode, with the objective of removing ammonia and CoC simultaneously. The efficiency of a high rate NTF for removal both of low concentration of ammonia (5 mg NH4-N L(-1)) and different concentrations of CoC in the presence of an exogenous organic carbon substrate (30 mg total organic carbon (TOC) L(-1)) was investigated. In the presence of exogenous organic carbon, the results demonstrated that the high rate NTF was able to successfully remove most of the CoCs investigated, with the removal ranging from 20.2% to 87.54%. High removal efficiencies were observed for acetaminophen (87.54%), bisphenol A (86.60%), trimethoprim (86.24%) and 17α-ethynylestradiol (80.60%). It was followed by the medium removal efficiency for N, N-diethyl-m-toluamide (61.31%) and atrazine (56.90%). In contrast, the removal of caffeine (28.43%) and benzotriazole (20.20%) was poorer in the presence of exogenous organic carbon. The removal efficiency for CoC was also compared with the results obtained in our previous study in the absence of exogenous organic carbon. The results showed that the addition of exogenous organic carbon was able to improve the removal of some of the CoC. Significant TOC percentage removals (45.68%-84.43%) and ammonia removal rate (mean value of 0.44 mg NH4-N L(-1) h(-1)) were also achieved in this study. The findings from this study provide valuable information for optimising the efficiency of high rate NTF for the removal of ammonia, CoC and TOC.

  16. [Effects of different fertilizer application on soil active organic carbon].

    Science.gov (United States)

    Zhang, Rui; Zhang, Gui-Long; Ji, Yan-Yan; Li, Gang; Chang, Hong; Yang, Dian-Lin

    2013-01-01

    The variation characteristics of the content and components of soil active organic carbon under different fertilizer application were investigated in samples of calcareous fluvo-aquic soil from a field experiment growing winter wheat and summer maize in rotation in the North China Plain. The results showed that RF (recommended fertilization), CF (conventional fertilization) and NPK (mineral fertilizer alone) significantly increased the content of soil dissolved organic carbon and easily oxidized organic carbon by 24.92-38.63 mg x kg(-1) and 0.94-0.58 mg x kg(-1) respectively compared to CK (unfertilized control). The soil dissolved organic carbon content under OM (organic manure) increased greater than those under NPK and single fertilization, soil easily oxidized organic carbon content under OM and NPK increased greater than that under single chemical fertilization. OM and NPK showed no significant role in promoting the soil microbial biomass carbon, but combined application of OM and NPK significantly increased the soil microbial biomass carbon content by 36.06% and 20.69%, respectively. Soil easily oxidized organic carbon, dissolved organic carbon and microbial biomass carbon accounted for 8.41% - 14.83%, 0.47% - 0.70% and 0.89% - 1.20% of the total organic carbon (TOC), respectively. According to the results, the fertilizer application significantly increased the proportion of soil dissolved organic carbon and easily oxidized organic carbon, but there was no significant difference in the increasing extent of dissolved organic carbon. The RF and CF increased the proportion of soil easily oxidized organic carbon greater than OM or NPK, and significantly increased the proportion of microbial biomass carbon. OM or RF had no significant effect on the proportion of microbial biomass carbon. Therefore, in the field experiment, appropriate application of organic manure and chemical fertilizers played an important role for the increase of soil active organic carbon

  17. Tunable Q-switched thulium-doped Fiber Laser using multiwall carbon nanotube and Fabry-Perot Etalon filter

    Science.gov (United States)

    Ahmad, H.; Muhamad, A.; Sharbirin, A. S.; Samion, M. Z.; Ismail, M. F.

    2017-01-01

    In this paper, we demonstrate an electro-tunable Thulium-doped Fiber Laser (TDFL) using a voltage-controlled Fabry-Perot Etalon (FPE) filter with passive Q-switching capability, obtained by using a multi-walled carbon-nanotube (MWCNT) thin-film as a saturable absorber (SA). To the best of our knowledge, this is the first demonstration of a wavelength-tunable Q-switched TDFL using an FPE filter. The tunable TDFL has a wavelength-tuning range of 41.95 nm, from 1965.40 nm up to 2007.35 nm. Q-switching operation starts at a pump power of 94.72 mW and destabilizes at a maximum input pump power of 146.39 mW. By varying the pump power, the repetition rate and the pulse width can be tuned with a maximum tuning range of 15.5 kHz and 7.0 μs respectively. The laser also has a maximum pulse energy of 82.6 nJ and a peak power of 27.52 mW. The use of the MWCNT thin-film as an SA generates a stable Q-switching operation, which is verified by its relatively high signal-to-noise ratio at a value of 55.0 dB.

  18. Biomass derived graphene-like activated and non-activated porous carbon for advanced supercapacitors

    Indian Academy of Sciences (India)

    KASINATH OJHA; BHARAT KUMAR; ASHOK K GANGULI

    2017-03-01

    Graphene-like activated and non-activated carbon nanostructures were synthesized from various natural sources like sugar, rice husk and jute. These carbon nanostructures were characterized using SEM, FTIR and Raman spectroscopy, surface area and thermogravimetric analysis. The electrochemical studies of these carbon materials confirm their promising characteristics for supercapacitor applications. Activated carbon nanostructures exhibit higher specific capacitance compared to that of non-activated carbons (non-Ac sugar).The activated carbon (Ac-jute) exhibits maximum specific capacitance of 476 F/g at an applied current density of 0.2 A/g which is much higher than that of graphene oxide (GO).

  19. Rapid quantification of dimethyl methylphosphonate from activated carbon particles by static headspace gas chromatography mass spectrometry.

    Science.gov (United States)

    Mitchell, Brendan L; Billingsley, Brit G; Logue, Brian A

    2013-06-01

    Activated carbon (AC) particles are utilized as an adsorbent for binding hazardous vapors in protective equipment. The binding affinity and utilization of these AC particles should be known to ensure effective and efficient use. Therefore, a simple and effective method was developed for the quantification of the chemical warfare agent simulant, dimethyl methylphosphonate (DMMP), from AC particles. Static headspace gas chromatography mass-spectrometry with internal standard, DMMP-d6, was used to perform the analysis. The method produced a linear dynamic range of 2.48-620g DMMP/kg carbon and a detection limit of 1.24g DMMP/kg carbon. Furthermore, the method produced a coefficient of variation of less than 16% for all intra- and inter-assay analyses. The method provided a simple and effective procedure for quantifying DMMP from AC particles and was applied to the analysis of a DMMP-exposed AC protective respirator filter.

  20. The optical blocking filter for the ATHENA wide field imager: ongoing activities towards the conceptual design

    Science.gov (United States)

    Barbera, M.; Branduardi-Raymont, G.; Collura, A.; Comastri, A.; Eder, J.; Kamisiński, T.; Lo Cicero, U.; Meidinger, N.; Mineo, T.; Molendi, S.; Parodi, G.; Pilch, A.; Piro, L.; Rataj, M.; Rauw, G.; Sciortino, L.; Sciortino, S.; Wawer, P.

    2015-08-01

    ATHENA is the L2 mission selected by ESA to pursue the science theme "Hot and Energetic Universe" (launch scheduled in 2028). One of the key instruments of ATHENA is the Wide Field Imager (WFI) which will provide imaging in the 0.1-15 keV band over a 40'x40' large field of view, together with spectrally and time-resolved photon counting. The WFI camera, based on arrays of DEPFET active pixel sensors, is also sensitive to UV/Vis photons. Optically generated electron-hole pairs may degrade the spectral resolution as well as change the energy scale by introducing a signal offset. For this reason, the use of an X-ray transparent optical blocking filter is needed to allow the observation of all type of X-ray sources that present a UV/Visible bright counterpart. In this paper, we describe the main activities that we are carrying on for the conceptual design of the optical blocking filter, that will be mounted on the filter wheel, in order to satisfy the scientific requirements on optical load from bright UV/Vis astrophysical source, to maximize the X-ray transmission, and to withstand the severe acoustic and vibration loads foreseen during launch.

  1. Gradient Descent Learning for Utility Current Compensation using Active Regenerative PWM Filter

    Directory of Open Access Journals (Sweden)

    R. Balamurugan

    2011-01-01

    Full Text Available Problem statement: Harmonic analysis is a primary matter of power quality assessment. Its main intention is to check the utility whether it is delivering the loads without any deviations in voltages and currents. The problem is due to proliferation of Electronic converters and power electronics which gave birth to numerous new applications, offering unmatched comfort to the customers. Approach: Harmonics should be maintained within the limits said in standards like IEEE 519 and others such as IEEE 1159 for safeguarding the utility. This was provided by many mitigation technologies like passive, shunt and series filtering, active conditioners, but they were lack of some demerits like huge cost, many controllers and circuit components. So for controlling the harmonic loads the converter with four quadrant characteristics was implemented and this converter act as shunt active filter as well as rectifier simultaneously without any additional circuitry. For having better harmonic reduction in addition, many controllers like p-q Theorem based controller, Fuzzy and gradient descent based neural network is also used. Results: The simulation results gives the compared source current wave forms for various controllers with individual harmonic mitigations. Conclusion: The pure utility current is obtained by using this intelligent neural filter without any additional components and without any extra controllers than the conventional methods.

  2. The Adsorption Mechanism of Modified Activated Carbon on Phenol

    Directory of Open Access Journals (Sweden)

    Lin J. Q.

    2016-01-01

    Full Text Available Modified activated carbon was prepared by thermal treatment at high temperature under nitrogen flow. The surface properties of the activated carbon were characterized by Boehm titration, BET and point of zero charge determination. The adsorption mechanism of phenol on modified activated carbon was explained and the adsorption capacity of modified activated carbon for phenol when compared to plain activated carbon was evaluated through the analysis of adsorption isotherms, thermodynamic and kinetic properties. Results shows that after modification the surface alkaline property and pHpzc value of the activated carbon increase and the surface oxygen-containing functional groups decrease. The adsorption processes of the plain and modified carbon fit with Langmuir isotherm equation well, and the maximum adsorption capacity increase from 123.46, 111.11, 103.09mg/g to 192.31, 178.57, 163,93mg/g under 15, 25 and 35°C after modification, respectively. Thermodynamic parameters show that the adsorption of phenol on activated carbon is a spontaneously exothermic process of entropy reduction, implying that the adsorption is a physical adsorption. The adsorption of phenol on activated carbon follows the pseudo-second-order kinetics (R2>0.99. The optimum pH of adsorption is 6~8.

  3. Efficient L-lactic acid fermentation by the mold Rhizopus oryzae using activated carbon

    Energy Technology Data Exchange (ETDEWEB)

    Koide, M.; Hirata, M.; Gaw, M.; Takanashi, H.; Hano, T. [Oita Univ, Oita (Japan). Dept. of Applied Chemistry

    2004-11-01

    Batch fermentations of Rhizopus oryzae AHU 6537 in medium containing granular activated carbon from coal, powder activated carbon from coal or granular activated carbon from coconut were carried out in an airlift bioreactor. As a result, fermentation broths were decolorized by activated carbon, and clearer fermentation broths were obtained than in fermentation without activated carbon. With activated carbon from coal, the cells formed smaller pellets than in fermentation without activated carbon, and fermentation performance was improved. Productivity was further improved by increasing the amount of activated carbon from coal. Therefore, the productivity of lactic acid fermentation could be improved by selecting a suitable activated carbon and by controlling the amount of activated carbon.

  4. A Novel (DDCC-SFG-Based Systematic Design Technique of Active Filters

    Directory of Open Access Journals (Sweden)

    M. Fakhfakh

    2013-09-01

    Full Text Available This paper proposes a novel idea for the synthesis of active filters that is based on the use of signal-flow graph (SFG stamps of differential difference current conveyors (DDCCs. On the basis of an RLC passive network or a filter symbolic transfer function, an equivalent SFG is constructed. DDCCs’ SFGs are identified inside the constructed ‘active’ graph, and thus the equivalent circuit can be easily synthesized. We show that the DDCC and its ‘derivatives’, i.e. differential voltage current conveyors and the conventional current conveyors, are the main basic building blocks in such design. The practicability of the proposed technique is showcased via three application examples. Spice simulations are given to show the viability of the proposed technique.

  5. Current control for a shunt hybrid active power filter using recursive integral PI

    Institute of Scientific and Technical Information of China (English)

    Wei ZHAO; An LUO; Ke PENG; Xia DENG

    2009-01-01

    This paper presents a current control method for a shunt hybrid active power filter(HAPF) using recursive integral Pl algorithm.The method improves the performance of the HAPF system by reducing the influence of detection accuracy,time delay of instruction current calculation and phase displacement of output filter.Fuzzy logic based set-point weighing algorithm is combined in the control scheme to enhance its robustness and anti-interference ability.The proposed algorithm is easy to implement for engineering applications and easy to compute.Experiment results have verified the validity of the proposed controller.Furthermore,the proposed recursive integral PI algorithm can also be applied in the control of periodic current as in AC drivers.

  6. Active notch filter network with variable notch depth, width and frequency

    Science.gov (United States)

    Black, J. M. (Inventor)

    1980-01-01

    An active notch filter having independently adjustable notch frequency, width, and depth is provided by three equal capacitors connected in series with an operational amplifier (connected in a voltage follower configuration), a potentiometer across the series connected capacitors for notch depth adjustment, and a potentiometer (for notch frequency connected across the center capacitor); with its tap connected to receive a voltage feedback signal from a variable voltage divider comprised of another potentiometer for notch width. Adjusting the voltage dividing potentiometer will independently set the notch width, and adjusting the tap on the potentiometer across the center capacitor will independently adjust the notch frequency of the filter. A second operational amplifier connected in a voltage follower configuration may be used to connect the voltage divider output to the adjustable tap of the potentiometer across the center capacitor.

  7. Adsorption of aromatic compounds by carbonaceous adsorbents: a comparative study on granular activated carbon, activated carbon fiber, and carbon nanotubes.

    Science.gov (United States)

    Zhang, Shujuan; Shao, Ting; Kose, H Selcen; Karanfil, Tanju

    2010-08-15

    Adsorption of three aromatic organic compounds (AOCs) by four types of carbonaceous adsorbents [a granular activated carbon (HD4000), an activated carbon fiber (ACF10), two single-walled carbon nanotubes (SWNT, SWNT-HT), and a multiwalled carbon nanotube (MWNT)] with different structural characteristics but similar surface polarities was examined in aqueous solutions. Isotherm results demonstrated the importance of molecular sieving and micropore effects in the adsorption of AOCs by carbonaceous porous adsorbents. In the absence of the molecular sieving effect, a linear relationship was found between the adsorption capacities of AOCs and the surface areas of adsorbents, independent of the type of adsorbent. On the other hand, the pore volume occupancies of the adsorbents followed the order of ACF10 > HD4000 > SWNT > MWNT, indicating that the availability of adsorption site was related to the pore size distributions of the adsorbents. ACF10 and HD4000 with higher microporous volumes exhibited higher adsorption affinities to low molecular weight AOCs than SWNT and MWNT with higher mesopore and macropore volumes. Due to their larger pore sizes, SWNTs and MWNTs are expected to be more efficient in adsorption of large size molecules. Removal of surface oxygen-containing functional groups from the SWNT enhanced adsorption of AOCs.

  8. Highly Accurate Derivatives for LCL-Filtered Grid Converter with Capacitor Voltage Active Damping

    DEFF Research Database (Denmark)

    Xin, Zhen; Loh, Poh Chiang; Wang, Xiongfei

    2016-01-01

    The middle capacitor voltage of an LCL-filter, if fed back for synchronization, can be used for active damping. An extra sensor for measuring the capacitor current is then avoided. Relating the capacitor voltage to existing popular damping techniques designed with capacitor current feedback would...... are then proposed, based on either second-order or non-ideal generalized integrator. Performances of these derivatives have been found to match the ideal “s” function closely. Active damping based on capacitor voltage feedback can therefore be realized accurately. Experimental results presented have verified...

  9. Efficient organometallic spin filter between single-wall carbon nanotube or graphene electrodes

    DEFF Research Database (Denmark)

    Koleini, Mohammad; Paulsson, Magnus; Brandbyge, Mads

    2007-01-01

    We present a theoretical study of spin transport in a class of molecular systems consisting of an organometallic benzene-vanadium cluster placed in between graphene or single-wall carbon-nanotube-model contacts. Ab initio modeling is performed by combining spin density functional theory...

  10. ADSORPTION OF DYES ON ACTIVATED CARBON FIBERS

    Institute of Scientific and Technical Information of China (English)

    ChenShuixia; WuChangqing; 等

    1998-01-01

    The adsorption behavior of dyes on a variety of sisal based activated carbon fibers (SACF) has been studied in this paper. The results show that this kind of ACF has excellent adsorption capacities for some organic (dye) molecules.SACF can remove nearly all methylene blue,crystal violet,bromophenol blue and Eriochrome blue black R from water after static adsorption for 24h. at 30℃. The adsorption amounts can reach more than 400mg/g when adding 50 mg SACF into 50 ml dye solution.Under the same conditions,the adsorption amounts of xylenol orange fluorescein and Eriochrome black T wree lower.On the other hand,the adsorption amounts change along with the characteristics of adsorbents.The SACFs activated above 840℃,which have higher specific surface areas and wider pore radii,have higher adsorption amounts for the dyes.The researching results also show that the adsorption rates of dyes onto SACFs decrease by the order of methylene blue,Eriochrome blue black R and crystal violet.

  11. Fabrication of Activated Rice Husk Charcoal by Slip Casting as a Hybrid Material for Water Filter Aid

    Science.gov (United States)

    Tuaprakone, T.; Wongphaet, N.; Wasanapiarnpong, T.

    2011-04-01

    Activated charcoal has been widely used as an odor absorbent in household and water purification industry. Filtration equipment for drinking water generally consists of four parts, which are microporous membrane (porous alumina ceramic or diatomite, or porous polymer), odor absorbent (activated carbon), hard water treatment (ion exchange resin), and UV irradiation. Ceramic filter aid is usually prepared by slip casting of alumina or diatomite. The membrane offers high flux, high porosity and maximum pore size does not exceed 0.3 μm. This study investigated the fabrication of hybrid activated charcoal tube for water filtration and odor absorption by slip casting. The suitable rice husk charcoal and water ratio was 48 to 52 wt% by weight with 1.5wt% (by dry basis) of CMC binder. The green rice husk charcoal bodies were dried and fired between 700-900 °C in reduction atmosphere. The resulting prepared slip in high speed porcelain pot for 60 min and sintered at 700 °C for 1 h showed the highest specific surface area as 174.95 m2/g. The characterizations of microstructure and pore size distribution as a function of particle size were investigated.

  12. Catalytic diesel particulate filters reduce the in vitro estrogenic activity of diesel exhaust.

    Science.gov (United States)

    Wenger, Daniela; Gerecke, Andreas C; Heeb, Norbert V; Naegeli, Hanspeter; Zenobi, Renato

    2008-04-01

    An in vitro reporter gene assay based on human breast cancer T47D cells (ER-CALUX) was applied to examine the ability of diesel exhaust to induce or inhibit estrogen receptor (ER)-mediated gene expression. Exhaust from a heavy-duty diesel engine was either treated by iron- or copper/iron-catalyzed diesel particulate filters (DPFs) or studied as unfiltered exhaust. Collected samples included particle-bound and semivolatile constituents of diesel exhaust. Our findings show that all of the samples contained compounds that were able to induce ER-mediated gene expression as well as compounds that suppressed the activity of the endogenous hormone 17beta-estradiol (E2). Estrogenic activity prevailed over antiestrogenic activity. We found an overall ER-mediated activity of 1.63 +/- 0.31 ng E2 CALUX equivalents (E2-CEQs) per m(3) of unfiltered exhaust. In filtered exhaust, we measured 0.74 +/- 0.07 (iron-catalyzed DPF) and 0.55 +/- 0.09 ng E2-CEQ m(-3) (copper/iron-catalyzed DPF), corresponding to reductions in estrogenic activity of 55 and 66%, respectively. Our study demonstrates that both catalytic DPFs lowered the ER-mediated endocrine-disrupting potential of diesel exhaust.

  13. Catalytic diesel particulate filters reduce the in vitro estrogenic activity of diesel exhaust

    Energy Technology Data Exchange (ETDEWEB)

    Wenger, Daniela; Gerecke, Andreas C.; Heeb, Norbert V. [Laboratory for Analytical Chemistry, Empa, Swiss Federal Laboratories for Materials Testing and Research, Duebendorf (Switzerland); Naegeli, Hanspeter [University of Zurich-Vetsuisse, Institute of Pharmacology and Toxicology, Zurich (Switzerland); Zenobi, Renato [ETH Zurich, Department of Chemistry and Applied Biosciences, Zurich (Switzerland)

    2008-04-15

    An in vitro reporter gene assay based on human breast cancer T47D cells (ER-CALUX {sup registered}) was applied to examine the ability of diesel exhaust to induce or inhibit estrogen receptor (ER)-mediated gene expression. Exhaust from a heavy-duty diesel engine was either treated by iron- or copper/iron-catalyzed diesel particulate filters (DPFs) or studied as unfiltered exhaust. Collected samples included particle-bound and semivolatile constituents of diesel exhaust. Our findings show that all of the samples contained compounds that were able to induce ER-mediated gene expression as well as compounds that suppressed the activity of the endogenous hormone 17{beta}-estradiol (E2). Estrogenic activity prevailed over antiestrogenic activity. We found an overall ER-mediated activity of 1.63 {+-} 0.31 ng E2 CALUX equivalents (E2-CEQs) per m{sup 3} of unfiltered exhaust. In filtered exhaust, we measured 0.74 {+-} 0.07 (iron-catalyzed DPF) and 0.55 {+-} 0.09 ng E2-CEQ m{sup -3} (copper/iron-catalyzed DPF), corresponding to reductions in estrogenic activity of 55 and 66%, respectively. Our study demonstrates that both catalytic DPFs lowered the ER-mediated endocrine-disrupting potential of diesel exhaust. (orig.)

  14. Correction Methods for Organic Carbon Artifacts when Using Quartz-Fiber Filters in Large Particulate Matter Monitoring Networks: The Regression Method and Other Options

    Science.gov (United States)

    Sampling and handling artifacts can bias filter-based measurements of particulate organic carbon (OC). Several measurement-based methods for OC artifact reduction and/or estimation are currently used in research-grade field studies. OC frequently is not artifact-corrected in larg...

  15. Surface characteristics and antibacterial activity of a silver-doped carbon monolith

    Directory of Open Access Journals (Sweden)

    Marija Vukčević et al

    2008-01-01

    Full Text Available A carbon monolith with a silver coating was prepared and its antimicrobial behaviour in a flow system was examined. The functional groups on the surface of the carbon monolith were determined by temperature-programmed desorption and Boehm's method, and the point of zero charge was determined by mass titration. The specific surface area was examined by N2 adsorption using the Brunauer, Emmett and Teller (BET method. As a test for the surface activity, the deposition of silver from an aqueous solution of a silver salt was used. The morphology and structure of the silver coatings were characterized by scanning electron microscopy and x-ray diffraction. The resistance to the attrition of the silver deposited on the carbon monolith was tested. The antimicrobial activity of the carbon monolith with a silver coating was determined using standard microbiological methods. Carbon monolith samples with a silver coating showed good antimicrobial activity against Escherichia coli, Staphylococcus aureus and Candida albicans, and are therefore suitable for water purification, particularly as personal disposable water filters with a limited capacity.

  16. Preparation and application of active gangue's carbon black

    Institute of Scientific and Technical Information of China (English)

    ZHANG Xiang-lin; ZHANG Yi-dong

    2007-01-01

    After three-stage pulverization, dry-distillated activation and coupling agent surface modification, the kaolinite-typed gangue of Sichuan Hongni Coal Mine(SHCM) can be manufactured into activated gangue's carbon black. Its surface area is >25 m2/g, and possesses carbon black's carbon framework and structure. It can be used as strengthening agent of high polymer material such as rubber.

  17. What Carbon Sources Support Groundwater Microbial Activity in Riparian Forests?

    Science.gov (United States)

    Gurwick, N. P.; Groffman, P. M.; McCorkle, D. C.; Stolt, M. H.; Kellogg, D. Q.; Gold, A. J.

    2004-05-01

    A major question in riparian research is the source of energy to support subsurface microbial denitrification activity. The supply of microbially-available carbon frequently limits microbial activity in the subsurface. Therefore, identifying the relative importance of carbon sources in the riparian subsurface helps explain the sustainability and spatial heterogeneity of denitrification rates. We have investigated the importance of buried, carbon-rich soil horizons, deep roots and dissolved organic carbon as potential carbon sources to support groundwater denitrification in riparian forests in Rhode Island. We used field observations, laboratory incubations and in-situ experiments to evaluate these sources at four sites in different geomorphic settings. In particular, we measured the 14C-DIC signature and DIC concentration of ambient groundwater and groundwater that had been degassed, re-introduced into the well, and incubated in-situ. Buried horizons appear to be an important source of carbon in the subsurface, as shown by active respiration in laboratory incubations; greater microbial biomass in buried carbon-rich soils compared to surrounding carbon-poor soils; and the presence of very old carbon (>1,000 ybp) in DIC 225 cm beneath the surface. DIC collected from shallower wells showed no clear evidence of ancient carbon. Roots also appear to be important, creating hotspots of carbon availability and denitrification in the generally carbon poor subsurface matrix. Dissolved organic carbon did not stimulate denitrification in aquifer microcosms in the laboratory, suggesting that this was not an important carbon source for denitrification in our sites. Determining which carbon source is fueling denitrification has practical implications. Where buried horizons are the key source, surface management of the riparian zone will likely have little direct influence on groundwater denitrification. Where roots are the key source, changes in the plant community are likely to

  18. [Flue gas desulfurization by a novel biomass activated carbon].

    Science.gov (United States)

    Liu, Jie-Ling; Tang, Zheng-Guang; Chen, Jie; Jiang, Wen-Ju; Jiang, Xia

    2013-04-01

    A novel biomass columnar activated carbon was prepared from walnut shell and pyrolusite was added as a catalyst. The activated carbon prepared was used for flue gas desulphurization in a fixed-bed reactor with 16 g of activated carbon. The impact of operating parameters such as SO2 inlet concentration, space velocity, bed temperature, moisture content and O2 concentration on the desulfurization efficiency of activated carbon was investigated. The results showed that both the breakthrough sulfur capacity and breakthrough time of activated carbon decreased with the increase of SO2 inlet concentration within the range of 0.1% -0.3%. The breakthrough sulfur capacity deceased with the increase of space velocity, with optimal space velocity of 600 h(-1). The optimal bed temperature was 80 degrees C, and the desulfurization efficiency can be reduced if the temperature continue to increase. The presence of moisture and oxygen greatly promoted the adsorption of SO2 onto the activated carbon. The best moisture content was 10%. When the oxygen concentrations were between 10% and 13%, the desulfurization performance of activated carbon was the highest. Under the optimal operating conditions, the sulfur capacity of activated carbon was 252 mg x g(-1), and the breakthrough time was up to 26 h when the SO2 inlet concentration was 0.2%.

  19. Microbial Enzyme Activity and Carbon Cycling in Grassland Soil Fractions

    Science.gov (United States)

    Allison, S. D.; Jastrow, J. D.

    2004-12-01

    Extracellular enzymes are necessary to degrade complex organic compounds present in soils. Using physical fractionation procedures, we tested whether old soil carbon is spatially isolated from degradative enzymes across a prairie restoration chronosequence in Illinois, USA. We found that carbon-degrading enzymes were abundant in all soil fractions, including macroaggregates, microaggregates, and the clay fraction, which contains carbon with a mean residence time of ~200 years. The activities of two cellulose-degrading enzymes and a chitin-degrading enzyme were 2-10 times greater in organic matter fractions than in bulk soil, consistent with the rapid turnover of these fractions. Polyphenol oxidase activity was 3 times greater in the clay fraction than in the bulk soil, despite very slow carbon turnover in this fraction. Changes in enzyme activity across the restoration chronosequence were small once adjusted for increases in soil carbon concentration, although polyphenol oxidase activity per unit carbon declined by 50% in native prairie versus cultivated soil. These results are consistent with a `two-pool' model of enzyme and carbon turnover in grassland soils. In light organic matter fractions, enzyme production and carbon turnover both occur rapidly. However, in mineral-dominated fractions, both enzymes and their carbon substrates are immobilized on mineral surfaces, leading to slow turnover. Soil carbon accumulation in the clay fraction and across the prairie restoration chronosequence probably reflects increasing physical isolation of enzymes and substrates on the molecular scale, rather than the micron to millimeter scale.

  20. Filtered-X Radial Basis Function Neural Networks for Active Noise Control

    Directory of Open Access Journals (Sweden)

    Bambang Riyanto

    2004-05-01

    Full Text Available This paper presents active control of acoustic noise using radial basis function (RBF networks and its digital signal processor (DSP real-time implementation. The neural control system consists of two stages: first, identification (modeling of secondary path of the active noise control using RBF networks and its learning algorithm, and secondly neural control of primary path based on neural model obtained in the first stage. A tapped delay line is introduced in front of controller neural, and another tapped delay line is inserted between controller neural networks and model neural networks. A new algorithm referred to as Filtered X-RBF is proposed to account for secondary path effects of the control system arising in active noise control. The resulting algorithm turns out to be the filtered-X version of the standard RBF learning algorithm. We address centralized and decentralized controller configurations and their DSP implementation is carried out. Effectiveness of the neural controller is demonstrated by applying the algorithm to active noise control within a 3 dimension enclosure to generate quiet zones around error microphones. Results of the real-time experiments show that 10-23 dB noise attenuation is produced with moderate transient response.

  1. An implicit evolution scheme for active contours and surfaces based on IIR filtering.

    Science.gov (United States)

    Delibasis, Konstantinos K; Asvestas, Pantelis A; Kechriniotis, Aristides I; Matsopoulos, George K

    2014-05-01

    In this work, we present an approach for implementing an implicit scheme for the numerical solution of the partial differential equation of the evolution of an active contour/surface. The proposed scheme is applicable to any variant of the traditional active contour (AC), irrespectively of the calculation of the image-based force field and it is readily applicable to explicitly parameterized active surfaces (AS). The proposed approach is formulated as an infinite impulse response (IIR) filtering of the coordinates of the contour/surface points. The poles of the filter are determined by the parameters controlling the shape of the active contour/surface. We show that the proposed IIR-based implicit evolution scheme has very low complexity. Furthermore, the proposed scheme is numerically stable, thus it allows the convergence of the AC/AS with significantly fewer iterations than the explicit evolution scheme. It also possesses the separability property along the two parameters of the AS, thus it may be applied to deformable surfaces, without the need to store and invert large sparse matrices. We implemented the proposed IIR-based implicit evolution scheme in the Vector Field Convolution (VFC) AC/AS using synthetic and clinical volumetric data. We compared the segmentation results with those of the explicit AC/AS evolution, in terms of accuracy and efficiency. Results show that the VFC AC/AS with the proposed IIR-based implicit evolution scheme achieves the same segmentation results with the explicit scheme, with considerably less computation time.

  2. A Magnesium-Activated Carbon Hybrid Capacitor

    Energy Technology Data Exchange (ETDEWEB)

    Yoo, HD; Shterenberg, I; Gofer, Y; Doe, RE; Fischer, CC; Ceder, G; Aurbach, D

    2013-12-11

    Prototype cells of hybrid capacitor were developed, comprising activated carbon (AC) cloth and magnesium (Mg) foil as the positive and negative electrodes, respectively. The electrolyte solution included ether solvent (TBF) and a magnesium organo-halo-aluminate complex 0.25 M Mg2Cl3+-Ph2AlCl2-. In this solution Mg can be deposited/dissolved reversibly for thousands of cycles with high reversibility (100% cycling efficiency). The main barrier for integrating porous AC electrodes with this electrolyte solution was the saturation of the pores with the large ions in the AC prior to reaching the potential limit. This is due to the existence of bulky Mg and Al based ionic complexes consisting Cl, alkyl or aryl (R), and THF ligands. This problem was resolved by adding 0.5 M of lithium chloride (LiCl), thus introducing smaller ionic species to the solution. This Mg hybrid capacitor system demonstrated a stable cycle performance for many thousands of cycles with a specific capacitance of 90 Fg(-1) for the AC positive electrodes along a potential range of 2.4 V. (C) 2014 The Electrochemical Society. All rights reserved.

  3. Studies on adsorptive desulfurization by activated carbon

    Energy Technology Data Exchange (ETDEWEB)

    Rakesh Kumar, D.; Srivastava, Vimal Chandra [Department of Chemical Engineering, Indian Institute of Technology Roorkee, Roorkee, Uttarakhand (India)

    2012-05-15

    Sulfur removal using adsorption requires a proper process parametric study to determine its optimal performance characteristics. In this study, response surface methodology was employed for sulfur removal from model oil (dibenzothiophene; DBT dissolved in iso-octane) using commercial activated carbon (CAC) as an adsorbent. Experiments were carried out as per central composite design with four input parameters such as initial concentration (C{sub 0}: 100-900 mg/L), adsorbent dosage (m: 2-22 g/L), time of adsorption (t: 15-735 min), and temperature (T: 10-50 C). Regression analysis showed good fit of the experimental data to the second-order polynomial model with coefficient of determination R{sup 2}-value of 0.9390 and Fisher F-value of 16.5. The highest removal of sulfur by CAC was obtained with m = 20 g/L, t = 6 h, and T = 30 C. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  4. Adsorption of EDTA on activated carbon from aqueous solutions.

    Science.gov (United States)

    Zhu, Hai-song; Yang, Xiao-juan; Mao, Yan-peng; Chen, Yu; Long, Xiang-li; Yuan, Wei-kang

    2011-01-30

    In this study, the adsorption of EDTA on activated carbon from aqueous solutions has been investigated in a batch stirred cell. Experiments have been carried out to investigate the effects of temperature, EDTA concentration, pH, activated carbon mass and particle size on EDTA adsorption. The experimental results manifest that the EDTA adsorption rate increases with its concentration in the aqueous solutions. EDTA adsorption also increases with temperature. The EDTA removal from the solution increases as activated carbon mass increases. The Langmuir and Freundlich equilibrium isotherm models are found to provide a good fitting of the adsorption data, with R(2) = 0.9920 and 0.9982, respectively. The kinetic study shows that EDTA adsorption on the activated carbon is in good compliance with the pseudo-second-order kinetic model. The thermodynamic parameters (E(a), ΔG(0), ΔH(0), ΔS(0)) obtained indicate the endothermic nature of EDTA adsorption on activated carbon.

  5. [Study on adsorption properties of organic vapor on activated carbons].

    Science.gov (United States)

    Cai, Dao-Fei; Huang, Wei-Qiu; Wang, Dan-Li; Zhang, Lin; Yang, Guang

    2013-12-01

    Adsorption technology is widely used in oil vapor recovery, and adsorbents have decisive effect on separation. Three kinds of activated carbon (AC) were chosen to study their adsorption properties and adsorption energy, where n-hexane and n-heptane acted as adsorbate and adsorption experiments were conducted at 293.15 K. At the same time, regression formula of Logistic model was used to fit the throughout curves of active carbons. The results showed that: surface area and pore volume of activated carbon were the main factors affecting its adsorption properties; the adsorption behavior of n-hexane and n-heptane were corresponding to Langmuir adsorption isotherm model; adsorption energy of these three kinds of activated carbon became greater with increasing specific surface area. Fitting curve of Logistic model had high similarity with the experimental results, which could be used in the prediction of breakthrough curves of activated carbons.

  6. Real time control of an active power filter under distorted voltage condition

    Directory of Open Access Journals (Sweden)

    Ahmed Safa

    2012-10-01

    Full Text Available

    This paper, presents three phase shunt active filter under distorted voltage condition, the active power filter control is based on the use of self-tuning filter (STF for reference current generation and on space vector PWM for generation of pulses. The dc capacitor voltage is controlled by a classical PI controller.  The diode rectifier feed RL load is taken as a nonlinear load. The self-tuning filter allows extracting directly the voltage and current fundamental components in the axis without phase locked loop (PLL under distorted voltage condition. The experiment analysis is made based on working under distorted voltage condition, and the total harmonic distortion of source current after compensation .Self tuning filter based extraction technique is good under distorted voltage conditions. The total harmonic distortion (THD of source current is fully reduced. The effectiveness of the method is theoretically studied and verified by experimentation.

  7. Application of High Order X-LMS Filter for Active Noise Control

    Directory of Open Access Journals (Sweden)

    N.V.K.Mahalakshmi

    2014-06-01

    Full Text Available In this paper active noise is controlled by using higher order X-LMS (least mean square filter. This technique is based on X-NLMS (normalized least mean square, also known as traditional acoustic noise cancellation (ANC scheme. It cancels the wideband noise from the corrupted speech signal. The active noise reducing headphone is probably the most successful application of active control of sound – the technology of cancelling sound with sound i.e., by using anti-noise signal. This report presents an outlined technical review of noise cancellation in headphones. The principles of passive noise attenuation are presented after which active attenuation is introduced showing how the two complement the attenuation performance. In real-time environment, the number of different applications in which adaptive techniques are being successfully used that are echo cancellation, equalization of dispersive channels, system identification, signal enhancement, noise cancelling and control.

  8. Power quality improvement using DPC controlled three-phase shunt active filter

    Energy Technology Data Exchange (ETDEWEB)

    Chaoui, Abdelmadjid [Laboratoire d' Automatique et d' Informatique Industrielle (LAII-ESIP), Universite de Poitiers (France); Gaubert, Jean-Paul; Krim, Fateh [Laboratoire d' Electronique de Puissance et Commande Industrielle (LEPCI), Universite de Setif (Algeria)

    2010-06-15

    This paper presents a new control method entitled direct power control (DPC) for shunt active power filter (APF), which is applied to eliminate line current harmonics and compensate reactive power. Its main goal is to rebuild active and reactive source powers to be compared to references values using hysteresis control. The active power reference is issue of DC-side of inverter and reactive power reference is set to zero for unity power factor. The outputs of hysteresis controllers associated with a switching table, control the instantaneous active and reactive power by selecting the optimum switching state of the voltage source inverter (VSI). A theoretical analysis with a complete simulation of the system and experimental results are presented to prove the excellent performance of the proposed technique. (author)

  9. Decontamination of adsorbed chemical warfare agents on activated carbon using hydrogen peroxide solutions.

    Science.gov (United States)

    Osovsky, Ruth; Kaplan, Doron; Nir, Ido; Rotter, Hadar; Elisha, Shmuel; Columbus, Ishay

    2014-09-16

    Mild treatment with hydrogen peroxide solutions (3-30%) efficiently decomposes adsorbed chemical warfare agents (CWAs) on microporous activated carbons used in protective garments and air filters. Better than 95% decomposition of adsorbed sulfur mustard (HD), sarin, and VX was achieved at ambient temperatures within 1-24 h, depending on the H2O2 concentration. HD was oxidized to the nontoxic HD-sulfoxide. The nerve agents were perhydrolyzed to the respective nontoxic methylphosphonic acids. The relative rapidity of the oxidation and perhydrolysis under these conditions is attributed to the microenvironment of the micropores. Apparently, the reactions are favored due to basic sites on the carbon surface. Our findings suggest a potential environmentally friendly route for decontamination of adsorbed CWAs, using H2O2 without the need of cosolvents or activators.

  10. Effects on the efficiency of activated carbon on exposure to welding fumes

    Energy Technology Data Exchange (ETDEWEB)

    Ghosh, D. [Southern Company Services, Inc., Birmingham, AL (United States)

    1995-02-01

    It is the intention of this paper to document that certain types of welding fumes have little or no effect on the effectiveness of the carbon filter air filtration efficiency when directly exposed to a controlled amount of welding fumes for a short-term period. The welding processes studied were restricted to shielded metal arc welding (SMAW), flux cored arc welding (FCAW), gas tungsten arc welding (GTAW) and gas metal arc welding (GMAW) processes. Contrary to the SMAW and FCAW processes, the GTAW (or TIG) and the GMAW (or MIG) welding processes do not require the use of flux as part of the overall process. Credit was taken for these processes occurring in inert gas environments and producing minimal amount of smoke. It was concluded that a study involving the SMAW process would also envelop the effects of the TIG and MIG welding processes. The quantity of welding fumes generated during the arc welding process is a function of the particular process, the size and type of electrode, welding machine amperage, and operator proficiency. For this study, the amount of welding for specific testing was equated to the amount of welding normally conducted during plant unit outages. Different welding electrodes were also evaluated, and the subsequent testing was limited to an E7018 electrode which was judged to be representative of all carbon and stainless steel electrodes commonly used at the site. The effect of welding fumes on activated charcoal was tested using a filtration unit complete with prefilters, upstream and downstream high efficiency particulate air (HEPA) filters, and a carbon adsorber section. The complete system was field tested in accordance with ANSI N510 standards prior to exposing the filters and the adsorber bed to welding fumes. The carbon samples were tested at an established laboratory using ASTM D3803-1989 standards.

  11. DSP control of photovoltaic power generation system adding the function of shunt active power filter

    Energy Technology Data Exchange (ETDEWEB)

    Seo, H.-R.; Kim, K.-H.; Park, Y.-G.; Park, M.; Yu, I.-K. [Changwon National Univ., SarimDong (Korea, Republic of). Dept. of Electrical Engineering

    2007-07-01

    The growing number of power electronics-based equipment has created a problem on the quality of electric power supply since both high power industrial loads and domestic loads cause harmonics in the network voltage. Power quality problems can occur in the system or can be caused by the consumer. Active filter (AF) is widely used to compensate current harmonics and/or current imbalance of harmonic-producing loads. The power output of a photovoltaic (PV) system is directly affected by weather conditions. When alternating current (AC) power supply is required, power conversion by an inverter and an MPPT control is necessary. The proliferation of nonlinear loads such as inverter of PV power generation system can be treated as a harmonic source for the power distribution system. As such, the PV system combined with the function of the active filter system can be useful for the application in power distribution systems. This paper described a PV-AF system using DSP to prove that it is possible to combine AF theory to the three phase PV system connected to utility and verify it through experimental results. The paper described the control method of the PV-AF system, with reference to the photovoltaic power generation system, shunt active filter and PV-AF system. The experimental set-up was also presented. A laboratory system was designed and constructed to confirm the viability of the proposed PV-AF system. The test results revealed the stability and effectiveness of the proposed PV-AF system. 12 refs., 1 tabs., 12 figs.

  12. Activated soil filters for removal of biocides from contaminated run-off and waste-waters.

    Science.gov (United States)

    Bester, Kai; Banzhaf, Stefan; Burkhardt, Michael; Janzen, Niklas; Niederstrasser, Bernd; Scheytt, Traugott

    2011-11-01

    Building facades can be equipped with biocides to prevent formation of algal, fungal and bacterial films. Thus run-off waters may contain these highly active compounds. In this study, the removal of several groups of biocides from contaminated waters by means of an activated soil filter was studied. A technical scale activated vertical soil filter (biofilter) with different layers (peat, sand and gravel), was planted with reed (Phragmites australis) and used to study the removal rates and fate of hydrophilic to moderate hydrophobic (log K(ow) 1.8-4.4) biocides and biocide metabolites such as: Terbutryn, Cybutryn (Irgarol® 1051), Descyclopropyl-Cybutryn (Cybutryn and Terbutryn metabolite), Isoproturon, Diuron, and its metabolite Diuron-desmonomethyl, Benzo-isothiazolinone, n-Octyl-isothiazolinone, Dichloro-n-octylisothiazolinone and Iodocarbamate (Iodocarb). Three experiments were performed: the first one (36 d) under low flow conditions (61 L m(-2) d(-1)) reached removal rates between 82% and 100%. The second one was performed to study high flow conditions: During this experiment, water was added as a pulse to the filter system with a hydraulic load of 255 L m(-2) within 5 min (retention time waters or infiltration into soil without appropriate removal. In the last experiment the removal efficiencies of the different layers were studied. Though the peat layer was responsible for most of the removal, the sand and gravel layers also contributed significantly for some compounds. All compounds are rather removed by degradation than by sorption. Copyright © 2011 Elsevier Ltd. All rights reserved.

  13. Magnetic filtration process, magnetic filtering material, and methods of forming magnetic filtering material

    Science.gov (United States)

    Taboada-Serrano, Patricia; Tsouris, Constantino; Contescu, Cristian I; McFarlane, Joanna

    2013-10-08

    The present invention provides magnetically responsive activated carbon, and a method of forming magnetically responsive activated carbon. The method of forming magnetically responsive activated carbon typically includes providing activated carbon in a solution containing ions of ferrite forming elements, wherein at least one of the ferrite forming elements has an oxidation state of +3 and at least a second of the ferrite forming elements has an oxidation state of +2, and increasing pH of the solution to precipitate particles of ferrite that bond to the activated carbon, wherein the activated carbon having the ferrite particles bonded thereto have a positive magnetic susceptibility. The present invention also provides a method of filtering waste water using magnetic activated carbon.

  14. Tunable add-drop filter using an active whispering gallery mode microcavity

    CERN Document Server

    Monifi, Faraz; Yang, Lan

    2013-01-01

    An add-drop filter (ADF) fabricated using a whispering gallery mode resonator has different crosstalks for add and drop functions due to non-zero intrinsic losses of the resonator. Here, we show that introducing gain medium in the resonator and optically pumping it below the lasing threshold not only allows loss compensation to achieve similar and lower crosstalks but also tunability in bandwidth and add-drop efficiency. For an active ADF fabricated using an erbium-ytterbium co-doped microsphere, we achieved 24-fold enhancement in the intrinsic quality factor, 3.5-fold increase in drop efficiency, bandwidth tunability of 35 MHz and a crosstalk of only 2%.

  15. Shunt Active-Power-Filter Topology Based on Parallel Interleaved Inverters

    DEFF Research Database (Denmark)

    Blaabjerg, Frede; Asiminoaei, Lucian; Aeloiza, E.

    2008-01-01

    In this paper, an interleaved active-power-filter concept with reduced size of passive components is discussed. The topology is composed of two pulsewidth-modulation interleaved voltage-source inverters connected together on the ac line and sharing the same dc-link capacitor. The advantages......, because the power sharing allows one to use a higher switching frequency in each inverter. This paper analyzes the design of the passive components and gives a practical and low-cost solution for the minimization of the circulation currents between the inverters, by using common-mode coils. Several...

  16. Active power filter for medium voltage networks with predictive current control

    Energy Technology Data Exchange (ETDEWEB)

    Verne, Santiago A.; Valla, Maria I. [Laboratorio de Electronica Industrial, Control e Instrumentacion (LEICI), Facultad de Ingenieria, Universidad Nacional de La Plata and CONICET, La Plata (Argentina)

    2010-12-15

    A transformer less Shunt Active Power Filter (SAPF) for medium voltage distribution networks based on Multilevel Diode Clamped Inverter is presented in this paper. Converter current control is based on a Model Predictive strategy, which gives very fast current response. Also, the algorithm includes voltage balancing capability which is essential for proper converter operation. The presented current control algorithm is naturally applicable to converters with an arbitrary number of levels with reduced computational effort by virtue of the incorporation of switching restrictions which are necessary for reliable converter operation. The performance of the proposed algorithm is evaluated by means of computer simulations. (author)

  17. A New Synchronous Reference Frame-Based Method for Single-Phase Shunt Active Power Filters

    DEFF Research Database (Denmark)

    Monfared, Mohammad; Golestan, Saeed; Guerrero, Josep M.

    2013-01-01

    This paper deals with the design of a novel method in the synchronous reference frame (SRF) to extract the reference compensating current for single-phase shunt active power filters (APFs). Unlike previous works in the SRF, the proposed method has an innovative feature that it does not need...... the fictitious current signal. Frequency-independent operation, accurate reference current extraction and relatively fast transient response are other key features of the presented strategy. The effectiveness of the proposed method is investigated by means of detailed mathematical analysis. The results confirm...

  18. Reduced order generalized integrators with phase compensation for three-phase active power filter

    DEFF Research Database (Denmark)

    Xie, Chuan; Li, Kai; Zhao, Xin

    2017-01-01

    Current regulation is a critical issue for the stable operation of three-phase active power filters (APF). The challenge of the current controller lies in how to track the high slew rate reference with zero steady-state error in a fast and accurate way. Conventionally, multiple paralleled second-order...... generalized integrators (SOGIs) are utilized to achieve those objectives. However, it will increase the computational burden due to calculation of the multiple paralleled SOGIs. To overcome this issue, phase compensated reduced order generalized integrator (ROGI) is proposed in this paper. Compared...

  19. High-performance feedback-type active damping of LCL-filtered voltage source converters

    DEFF Research Database (Denmark)

    Wang, Xiongfei; Blaabjerg, Frede; Loh, Poh Chiang

    2015-01-01

    Active damping of LCL-filter resonance based on single-state feedback control is widely used with voltage source converters. Its robustness against grid impedance variation has always been a major concern with its controller design. To deal with this issue, this paper begins by developing......, but ensures also a robust stabilization against the grid parameters variations. For illustration, the approach is applied to design three single-state feedback-damping schemes, and their damping robustness are compared under both inductive and resonant grid impedances. Experimental results validate...

  1. Enhanced Stability of Capacitor-Current Feedback Active Damping for LCL-Filtered Grid Converters

    DEFF Research Database (Denmark)

    Xin, Zhen; Wang, Xiongfei; Loh, Poh Chiang;

    2015-01-01

    The proportional capacitor-current feedback active damping method has been widely used to suppress the LCL-filter resonance. However, the time delay in the damping control loop may lead to non-minimum phase or even unstable responses when the resonance frequency varies in a wide range. To improve...... the robustness of damping, this paper proposes an improved damping controller with the capacitor current feedback loop, which is based on the second-order generalized integrator, instead of a proportional gain, which can effectively mitigate the detrimental effect of the time delay. Robustness of the proposed...

  2. Active power filter for harmonic compensation using a digital dual-mode-structure repetitive control approach

    DEFF Research Database (Denmark)

    Zou, Zhixiang; Wang, Zheng; Cheng, Ming;

    2012-01-01

    This paper presents an digital dual-mode-structure repetitive control approach for the single-phase shunt active power filter (APF), which aims to enhance the tracking ability and eliminate arbitrary order harmonic. The proposed repetitive control scheme blends the characteristics of both odd......-harmonic repetitive control and even-harmonic repetitive control. Moreover, the convergence rate is faster than conventional repetitive controller. Additionally, the parameters have been designed and optimized for the dual-mode structure repetitive control to improve the performance of APF system. Experimental...... results on a laboratory setup are given to verify the proposed control scheme....

  3. Nanoscaled palladium catalysts on activated carbon support "Sibunit" for fine organic synthesis

    Science.gov (United States)

    Simakova, I.; Koskin, A.; Deliy, I.; Simakov, A.

    2005-08-01

    The application of nanosized palladium catalysts has gained growing importance over the last few years. Palladiumbased catalytic methods for fine organic synthesis permits the replacement of traditional labor-consuming techniques in multi-step organic syntheses and provides an improvement from the standpoint of cost and environmental impact. The use of activated carbon "Sibunit" as a substrate for catalysts has been fostered by the substrate's high surface area, chemical inertness both in acidic and basic media, and at the same time by the absence of very strong acidic centers on its surface which could promote undesirable side reactions during the catalytic run. A conversion of alpha-pinene derivatives to commercial biologically active compounds and fragrances as well as sun screens with ultra violet filtering properties, involves a catalytic hydrogenation as a key intermediate step. The aim of the present work is to clarify the factors favoring the dispersion of Pd metal on carbon. The effect of reduction temperature and pretreatment of the carbon surface on metal size during preparation of Pd on "Sibunit" catalysts for selective verbenol conversion was studied. The electron microscopy method (TEM) was used to show the influence on Pd metal dispersion of carbon surface oxidation by the oxidant H2O2, HNO3. The catalytic activity of Pd/C catalyst samples in verbenol hydrogenation reaction was determined. Kinetic peculiarities of verbenol hydrogenation over the most active catalyst sample were obtained.

  4. Cellulosic carbon fibers with branching carbon nanotubes for enhanced electrochemical activities for bioprocessing applications.

    Science.gov (United States)

    Zhao, Xueyan; Lu, Xin; Tze, William Tai Yin; Kim, Jungbae; Wang, Ping

    2013-09-25

    Renewable biobased carbon fibers are promising materials for large-scale electrochemical applications including chemical processing, energy storage, and biofuel cells. Their performance is, however, often limited by low activity. Herein we report that branching carbon nanotubes can enhance the activity of carbonized cellulosic fibers, such that the oxidation potential of NAD(H) was reduced to 0.55 V from 0.9 V when applied for bioprocessing. Coordinating with enzyme catalysts, such hierarchical carbon materials effectively facilitated the biotransformation of glycerol, with the total turnover number of NAD(H) over 3500 within 5 h of reaction.

  5. Adaptive Controller for Vehicle Active Suspension Generated Through LMS Filter Algorithms

    Institute of Scientific and Technical Information of China (English)

    SUN Jianmin; SHU Gequn

    2006-01-01

    The least means squares (LMS) adaptive filter algorithm was used in active suspension system.By adjusting the weight of adaptive filter, the minimum quadratic performance index was obtained.For two-degree-of-freedom vehicle suspension model, LMS adaptive controller was designed.The acceleration of the sprung mass,the dynamic tyre load between wheels and road,and the dynamic deflection between sprung mass and unsprung mass were determined as the evaluation targets of suspension performance.For LMS adaptive control suspension, compared with passive suspension, acceleration power spectral density of sprung mass acceleration under the road input model decreased 8-10 times in high frequency resonance band or low frequency resonance band.The simulation results show that LMS adaptive control is simple and remarkably effective.It further proves that the active control suspension system can improve both the riding comfort and handling safety in various operation conditions, and the method is fit for the active control of the suspension system.

  6. Enhanced Capacitive Characteristics of Activated Carbon by Secondary Activation

    Institute of Scientific and Technical Information of China (English)

    YANG Hui; LU Tian-hong; Yoshio Masaki

    2004-01-01

    The effect of the improvement of commercial activated carbon(AC) on its specific capacitance and high rate capability of double layer(dl) charging/discharging process has been studied. The improvement of AC was carried out via a secondary activation under steam in the presence of catalyst NiCl2, and the suitable condition was found to be a heat treatment at about 875 ℃ for 1 h. Under those conditions, the discharge specific capacitance of the improved AC increases up to 53.67 F/g, showing an increase of about 25% as compared with that of as-received AC. The good rectangular-shaped voltammograms and A.C. impedance spectra prove that the high rate capability of the capacitor made of the improved AC is enhanced significantly. The capacitance resistance(RC) time constant of the capacitor containing the improved AC is 1.74 s, which is much lower than that of the one containing as-received AC(an RC value of 4. 73 s). It is noted that both kinds of AC samples show a similar specific surface area and pore size distribution, but some changes have taken place in the carbon surface groups, especially a decrease in the concentration of surface carbonyl groups after the improvement, which have been verified by means of X-photoelectron spectroscopy. Accordingly, it is suggested that the decrease in the concentration of surface carbonyl groups for the improved AC is beneficial to the organic electrolyte ion penetrating into the pores, thus leading to the increase in both the specific capacitance and high rate capability of the supercapacitor.

  7. Studies relevant to the catalytic activation of carbon monoxide

    Energy Technology Data Exchange (ETDEWEB)

    Ford, P.C.

    1992-06-04

    Research activity during the 1991--1992 funding period has been concerned with the following topics relevant to carbon monoxide activation. (1) Exploratory studies of water gas shift catalysts heterogenized on polystyrene based polymers. (2) Mechanistic investigation of the nucleophilic activation of CO in metal carbonyl clusters. (3) Application of fast reaction techniques to prepare and to investigate reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and to the formation of carbon-carbon bonds via the migratory insertion of CO into metal alkyl bonds.

  8. Effects of Particle Filters and Accelerated Engine Replacement on Heavy-Duty Diesel Vehicle Emissions of Black Carbon, Nitrogen Oxides, and Ultrafine Particles

    Science.gov (United States)

    Kirchstetter, T.; Preble, C.; Dallmann, T. R.; DeMartini, S. J.; Tang, N. W.; Kreisberg, N. M.; Hering, S. V.; Harley, R. A.

    2013-12-01

    Diesel particle filters have become widely used in the United States since the introduction in 2007 of a more stringent exhaust particulate matter emission standard for new heavy-duty diesel vehicle engines. California has instituted additional regulations requiring retrofit or replacement of older in-use engines to accelerate emission reductions and air quality improvements. This presentation summarizes pollutant emission changes measured over several field campaigns at the Port of Oakland in the San Francisco Bay Area associated with diesel particulate filter use and accelerated modernization of the heavy-duty truck fleet. Pollutants in the exhaust plumes of hundreds of heavy-duty trucks en route to the Port were measured in 2009, 2010, 2011, and 2013. Ultrafine particle number, black carbon (BC), nitrogen oxides (NOx), and nitrogen dioxide (NO2) concentrations were measured at a frequency ≤ 1 Hz and normalized to measured carbon dioxide concentrations to quantify fuel-based emission factors (grams of pollutant emitted per kilogram of diesel consumed). The size distribution of particles in truck exhaust plumes was also measured at 1 Hz. In the two most recent campaigns, emissions were linked on a truck-by-truck basis to installed emission control equipment via the matching of transcribed license plates to a Port truck database. Accelerated replacement of older engines with newer engines and retrofit of trucks with diesel particle filters reduced fleet-average emissions of BC and NOx. Preliminary results from the two most recent field campaigns indicate that trucks without diesel particle filters emit 4 times more BC than filter-equipped trucks. Diesel particle filters increase emissions of NO2, however, and filter-equipped trucks have NO2/NOx ratios that are 4 to 7 times greater than trucks without filters. Preliminary findings related to particle size distribution indicate that (a) most trucks emitted particles characterized by a single mode of approximately

  9. Impact of sulfur oxides on mercury capture by activated carbon.

    Science.gov (United States)

    Presto, Albert A; Granite, Evan J

    2007-09-15

    Recent field tests of mercury removal with activated carbon injection (ACI) have revealed that mercury capture is limited in flue gases containing high concentrations of sulfur oxides (SOx). In order to gain a more complete understanding of the impact of SOx on ACl, mercury capture was tested under varying conditions of SO2 and SO3 concentrations using a packed bed reactor and simulated flue gas (SFG). The final mercury content of the activated carbons is independent of the SO2 concentration in the SFG, but the presence of SO3 inhibits mercury capture even at the lowest concentration tested (20 ppm). The mercury removal capacity decreases as the sulfur content of the used activated carbons increases from 1 to 10%. In one extreme case, an activated carbon with 10% sulfur, prepared by H2SO4 impregnation, shows almost no mercury capacity. The results suggest that mercury and sulfur oxides are in competition for the same binding sites on the carbon surface.

  10. Preparation and characterization of activated carbon produced from pomegranate seeds by ZnCl 2 activation

    Science.gov (United States)

    Uçar, Suat; Erdem, Murat; Tay, Turgay; Karagöz, Selhan

    2009-08-01

    In this study, pomegranate seeds, a by-product of fruit juice industry, were used as precursor for the preparation of activated carbon by chemical activation with ZnCl 2. The influence of process variables such as the carbonization temperature and the impregnation ratio on textural and chemical-surface properties of the activated carbons was studied. When using the 2.0 impregnation ratio at the carbonization temperature of 600 °C, the specific surface area of the resultant carbon is as high as 978.8 m 2 g -1. The results showed that the surface area and total pore volume of the activated carbons at the lowest impregnation ratio and the carbonization temperature were achieved as high as 709.4 m 2 g -1 and 0.329 cm 3 g -1. The surface area was strongly influenced by the impregnation ratio of activation reagent and the subsequent carbonization temperature.

  11. Dosimetric comparisons of carbon ion treatment plans for 1D and 2D ripple filters with variable thicknesses.

    Science.gov (United States)

    Ringbæk, Toke Printz; Weber, Uli; Santiago, Alina; Simeonov, Yuri; Fritz, Peter; Krämer, Michael; Wittig, Andrea; Bassler, Niels; Engenhart-Cabillic, Rita; Zink, Klemens

    2016-06-01

    A ripple filter (RiFi)-also called mini-ridge filter-is a passive energy modulator used in particle beam treatments that broadens the Bragg peak (BP) as a function of its maximum thickness. The number of different energies requested from the accelerator can thus be reduced, which significantly reduces the treatment time. A new second generation RiFi with 2D groove shapes was developed using rapid prototyping, which optimizes the beam-modulating material and enables RiFi thicknesses of up to 6 mm. Carbon ion treatment plans were calculated using the standard 1D 3 mm thick RiFi and the new 4 and 6 mm 2D RiFis for spherical planning target volumes (PTVs) in water, eight stage I non-small cell lung cancer cases, four skull base chordoma cases and three prostate cancer cases. TRiP98 was used for treatment planning with facility-specific base data calculated with the Monte Carlo code SHIELD-HIT12A. Dose-volume-histograms, spatial dose distributions and dosimetric indexes were used for plan evaluation. Plan homogeneity and conformity of thinner RiFis were slightly superior to thicker RiFis but satisfactory results were obtained for all RiFis investigated. For the 6 mm RiFi, fine structures in the dose distribution caused by the larger energy steps were observed at the PTV edges, in particular for superficial and/or very small PTVs but performances for all RiFis increased with penetration depth due to straggling and scattering effects. Plans with the new RiFi design yielded for the studied cases comparable dosimetric results to the standard RiFi while the 4 and 6 mm RiFis lowered the irradiation time by 25-30% and 45-49%, respectively.

  12. CCN activation of pure and coated carbon black particles.

    Science.gov (United States)

    Dusek, U; Reischl, G P; Hitzenberger, R

    2006-02-15

    The CCN (cloud condensation nucleus) activation of pure and coated carbon black particles was investigated using the University of Vienna cloud condensation nuclei counter (Giebl, H.; Berner, A.; Reischl, G.; Puxbaum, H.; Kasper-Giebl, A.; Hitzenberger, R. J. Aerosol Sci. 2002, 33, 1623-1634). The particles were produced by nebulizing an aqueous suspension of carbon black in a Collison atomizer. The activation of pure carbon black particles was found to require higher supersaturations than predicted by calculations representing the particles as insoluble, wettable spheres with mobility equivalent diameter. To test whether this effect is an artifact due to heating of the light-absorbing carbon black particles in the laser beam, experiments at different laser powers were conducted. No systematic dependence of the activation of pure carbon black particles on laser power was observed. The observations could be modeled using spherical particles and an effective contact angle of 4-6 degrees of water at their surface. The addition of a small amount of NaCl to the carbon black particles (by adding 5% by mass NaCl to the carbon black suspension) greatly enhanced their CCN efficiency. The measured CCN efficiencies were consistent with Kohler theory for particles consisting of insoluble and hygroscopic material. However, coating the carbon black particles with hexadecanol (a typical film-forming compound with one hydrophobic and one hydrophilic end) efficiently suppressed the CCN activation of the carbon black particles.

  13. Preparation of activated carbons from Chinese coal and hydrolysis lignin

    Energy Technology Data Exchange (ETDEWEB)

    Zou, Y.; Han, B.X. [Tuskegee University, Tuskegee, AL (USA). School of Engineering, Dept. of Chemical Engineering

    2001-07-01

    Activated carbons from Chinese coal and Chinese hydrolysis lignin have been prepared by chemical activation with potassium hydroxide. The following aspects of these activated materials have been analyzed: raw material; pre-treatment of raw material; activation agent, activation temperature and time, acid the activation agent/raw material ratio. Activated carbons with BET specific surface areas of the order of 2400-2600 m{sup 2}/g which exhibited substantial microporosity, a total pore volume of over 1.30 cm{sup 3}/g and a Methylene Blue adsorption capacity of over 440 mg/g were obtained.

  14. Characterization of activated carbon produced from urban organic waste

    Directory of Open Access Journals (Sweden)

    Abdul Gani Haji

    2013-10-01

    Full Text Available The difficulties to decompose organic waste can be handled naturally by pyrolisis so it can  decomposes quickly that produces charcoal as the product. This study aims to investigate the characteristics of activated carbon from urban organic waste. Charcoal results of pyrolysis of organic waste activated with KOH 1.0 M at a temperature of 700 and 800oC for 60 to 120 minutes. Characteristics of activated carbon were identified by Furrier Transform Infra Red (FTIR, Scanning Electron Microscopy (SEM, and X-Ray Diffraction (XRD. However, their quality is determined yield, moisture content, ash, fly substances, fixed carbon, and the power of adsorption of iodine and benzene. The identified functional groups on activated carbon, such as OH (3448,5-3436,9 cm-1, and C=O (1639,4 cm-1. In general, the degree and distance between the layers of active carbon crystallites produced activation in all treatments showed no significant difference. The pattern of activated carbon surface topography structure shows that the greater the pore formation in accordance with the temperature increase the more activation time needed. The yield of activated carbon obtained ranged from 72.04 to 82.75%. The results of characterization properties of activated carbon was obtained from 1.11 to 5.41% water, 13.68 to 17.27% substance fly, 20.36 to 26.59% ash, and 56.14 to 62.31% of fixed carbon . Absorption of activated carbon was good enough at 800oC and 120 minutes of activation time, that was equal to 409.52 mg/g of iodine and 14.03% of benzene. Activated carbon produced has less good quality, because only the water content and flying substances that meet the standards.Doi: 10.12777/ijse.5.2.89-94 [How to cite this article: Haji, A.G., Pari, G., Nazar, M., and Habibati.  (2013. Characterization of activated carbon produced from urban organic waste . International Journal of Science and Engineering, 5(2,89-94. Doi: 10.12777/ijse.5.2.89-94

  15. Reducing the chlorine dioxide demand in final disinfection of drinking water treatment plants using activated carbon.

    Science.gov (United States)

    Sorlini, Sabrina; Biasibetti, Michela; Collivignarelli, Maria Cristina; Crotti, Barbara Marianna

    2015-01-01

    Chlorine dioxide is one of the most widely employed chemicals in the disinfection process of a drinking water treatment plant (DWTP). The aim of this work was to evaluate the influence of the adsorption process with granular activated carbon (GAC) on the chlorine dioxide consumption in final oxidation/disinfection. A first series of tests was performed at the laboratory scale employing water samples collected at the outlet of the DWTP sand filter of Cremona (Italy). The adsorption process in batch conditions with seven different types of GAC was studied. A second series of tests was performed on water samples collected at the outlet of four GAC columns installed at the outlet of the DWTP sand filter. The results showed that the best chlorine dioxide demand (ClO2-D) reduction yields are equal to 60-80% and are achieved in the first 30 min after ClO2 addition, during the first 16 days of the column operation using a mineral, coal-based, mesoporous GAC. Therefore, this carbon removes organic compounds that are more rapidly reactive with ClO2. Moreover, a good correlation was found between the ClO2-D and UV absorbance at wavelength 254 nm using mineral carbons; therefore, the use of a mineral mesoporous GAC is an effective solution to control the high ClO2-D in the disinfection stage of a DWTP.

  16. Nanoporous separators for supercapacitor using activated carbon monolith electrode from oil palm empty fruit bunches

    Energy Technology Data Exchange (ETDEWEB)

    Nor, N. S. M., E-mail: madra@ukm.my; Deraman, M., E-mail: madra@ukm.my; Omar, R., E-mail: madra@ukm.my; Basri, N. H.; Dolah, B. N. M. [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Taer, E.; Awitdrus,; Farma, R. [Department of Physics, Faculty of Mathematics and Natural Sciences, University of Riau, 28293 Pekanbaru, Riau (Indonesia)

    2014-02-24

    Activated porous carbon electrode prepared from fibres of oil palm empty fruit bunches was used for preparing the carbon based supercapacitor cells. The symmetrical supercapacitor cells were fabricated using carbon electrodes, stainless steel current collector, H{sub 2}SO{sub 4} electrolyte, and three types of nanoporous separators. Cells A, B and C were fabricated using polypropylene, eggshell membrane, and filter paper, respectively. Electrochemical characterizations data from Electrochemical Impedance Spectroscopy, Cyclic Voltammetry, and Galvanic Charge Discharge techniques showed that specific capacitance, specific power and specific energy for cell A were 122 F g{sup −1}, 177 W kg{sup −1}, 3.42 Wh kg{sup −1}, cell B; 125 F g{sup −1}, 179 W kg{sup −1}, and 3.64 Wh kg{sup −1}, and cell C; 180 F g{sup −1}, 178 W kg{sup −1}, 4.27 Wh kg{sup −1}. All the micrographs from Field Emission Scanning Electron Microscope showed that the different in nanoporous structure of the separators lead to a significant different in influencing the values of specific capacitance, power and energy of supercapacitors, which is associated with the mobility of ion into the pore network. These results indicated that the filter paper was superior than the eggshell membrane and polypropylene nanoporous separators. However, we found that in terms of acidic resistance, polypropylene was the best nanoporous separator for acidic medium.

  17. Air filtration in the free molecular flow regime: a review of high-efficiency particulate air filters based on carbon nanotubes.

    Science.gov (United States)

    Li, Peng; Wang, Chunya; Zhang, Yingying; Wei, Fei

    2014-11-01

    Air filtration in the free molecular flow (FMF) regime is important and challenging because a higher filtration efficiency and lower pressure drop are obtained when the fiber diameter is smaller than the gas mean free path in the FMF regime. In previous studies, FMF conditions have been obtained by increasing the gas mean free path through reducing the pressure and increasing the temperature. In the case of carbon nanotubes (CNTs) with nanoscale diameters, it is possible to filtrate in the FMF regime under normal conditions. This paper reviews recent progress in theoretical and experimental studies of air filtration in the FMF regime. Typical structure models of high-efficiency particulate (HEPA) air filters based on CNTs are introduced. The pressure drop in air filters operated in the FMF regime is less than that predicted by the conventional air filtration theory. The thinnest HEPA filters fabricated from single-walled CNT films have an extremely low pressure drop. CNT air filters with a gradient nanostructure are shown to give a much better filtration performance in dynamic filtration. CNT air filters with a hierarchical structure and an agglomerated CNT fluidized bed air filter are also introduced. Finally, the challenges and opportunities for the application of CNTs in air filtration are discussed.

  18. A DSP-based active power filter for low voltage distribution systems

    Energy Technology Data Exchange (ETDEWEB)

    Shireen, Wajiha [University of Houston, Houston, TX 77204-4020 (United States); Tao, Li [Schlumberger Inc., Houston, TX (United States)

    2008-09-15

    The use of nonlinear loads, which inject undesired harmonic currents into low voltage distribution systems, is increasing rapidly. Active power filters are being considered as a potential candidate for solving harmonic problems in order to meet harmonic standards and guidelines. A new digital signal processor (DSP)-based control method for a single-phase active power filter (APF) is presented in this paper. Compared to conventional analog-based methods, the DSP-based solution provides a flexible and cheaper method to control the APF. The proposed scheme employs a carrier-based control that requires less feedback information compared to other reported solutions. Only one current sensor is used to sense the nonlinear load current and two voltage sensors to sense the input supply voltage and the dc bus voltage. The proposed method provides both harmonic elimination and power factor correction. The PSpice simulation and experiments using the DSP-based prototype are made to verify the feasibility of the method. (author)

  19. Simulation Research on a SVPWM Control Algorithm for a Four-Leg Active Power Filter

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    In this paper the topology of a four-leg shunt active-power filter (APF) is given.The APF compensates harmonic and reactive power in a three-phase four-wire system.The scheme adopted for control of the four-leg active power filter, a 3-Dimensional Pulse Width Modulation (PWM) technique, is presented.The theoretical deduction of a space vector PWM (SVPWM) algorithm is given in this paper.The paper also analyzes the distribution of the voltage-space vector of the four-leg converter in αβγ coordinates and describes methods to determine the location of the voltage-space vector and to calculate duration time.Finally, the algorithm is implemented in simulation; the results show that the total harmonic distortion (THD) of the three phase-current waveforms is reduced.The neutral wire current, after compensation, is about 0 A showing that the topology of the four-leg shunt APF is feasible and the proposed scheme is effective.

  20. Grafting of activated carbon cloths for selective adsorption

    Science.gov (United States)

    Gineys, M.; Benoit, R.; Cohaut, N.; Béguin, F.; Delpeux-Ouldriane, S.

    2016-05-01

    Chemical functionalization of an activated carbon cloth with 3-aminophthalic acid and 4-aminobenzoic acid groups by the in situ formation of the corresponding diazonium salt in aqueous acidic solution is reported. The nature and amount of selected functions on an activated carbon surface, in particular the grafted density, were determined by potentiometric titration, elemental analysis and X-ray photoelectron spectroscopy (XPS). The nanotextural properties of the modified carbon were explored by gas adsorption. Functionalized activated carbon cloth was obtained at a discrete grafting level while preserving interesting textural properties and a large porous volume. Finally, the grafting homogeneity of the carbon surface and the nature of the chemical bonding were investigated using Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS) technique.

  1. JV Task 90 - Activated Carbon Production from North Dakota Lignite

    Energy Technology Data Exchange (ETDEWEB)

    Steven Benson; Charlene Crocker; Rokan Zaman; Mark Musich; Edwin Olson

    2008-03-31

    The Energy & Environmental Research Center (EERC) has pursued a research program for producing activated carbon from North Dakota lignite that can be competitive with commercial-grade activated carbon. As part of this effort, small-scale production of activated carbon was produced from Fort Union lignite. A conceptual design of a commercial activated carbon production plant was drawn, and a market assessment was performed to determine likely revenue streams for the produced carbon. Activated carbon was produced from lignite coal in both laboratory-scale fixed-bed reactors and in a small pilot-scale rotary kiln. The EERC was successfully able to upgrade the laboratory-scale activated carbon production system to a pilot-scale rotary kiln system. The activated carbon produced from North Dakota lignite was superior to commercial grade DARCO{reg_sign} FGD and Rheinbraun's HOK activated coke product with respect to iodine number. The iodine number of North Dakota lignite-derived activated carbon was between 600 and 800 mg I{sub 2}/g, whereas the iodine number of DARCO FGD was between 500 and 600 mg I{sub 2}/g, and the iodine number of Rheinbraun's HOK activated coke product was around 275 mg I{sub 2}/g. The EERC performed both bench-scale and pilot-scale mercury capture tests using the activated carbon made under various optimization process conditions. For comparison, the mercury capture capability of commercial DARCO FGD was also tested. The lab-scale apparatus is a thin fixed-bed mercury-screening system, which has been used by the EERC for many mercury capture screen tests. The pilot-scale systems included two combustion units, both equipped with an electrostatic precipitator (ESP). Activated carbons were also tested in a slipstream baghouse at a Texas power plant. The results indicated that the activated carbon produced from North Dakota lignite coal is capable of removing mercury from flue gas. The tests showed that activated carbon with the greatest

  2. Tribological Characteristics of Chromium-active Carbon Electroplated Composite Coatings

    Institute of Scientific and Technical Information of China (English)

    GUKa-fi; HUAMeng; Yi-min

    2004-01-01

    A process of chromium electroplating using a standard bath with additives and active carbon particles was reported, and the tribological behaviors of the composite coatings using the pin-on-disk tester and the table wear tester were i nvestig(aed. Experimental results indicate that the electroplated chromium-active carbon composite coatings exhibited the low friction coefficient anti excellent anti-wear properties whets coffered with the normal chromium electroplated ones. The formation of active carbon particles within the chromium matrices can be explained by SEM analysis and the mechanis of wear resistance of the composite coatings were studied.

  3. ADSORPTION OF STRONTIUM IONS FROM WATER ON MODIFIED ACTIVATED CARBONS

    Directory of Open Access Journals (Sweden)

    Mihai Ciobanu

    2016-12-01

    Full Text Available Adsorption of strontium ions from aqueous solutions on active carbons CAN-7 and oxidized CAN-8 has been studied. It has been found that allure of the adsorption isotherms for both studied active carbons are practically identical. Studies have shown that the adsorption isotherms for strontium ions from aqueous solutions are well described by the Langmuir and Dubinin-Radushkevich equations, respectively. The surface heterogeneity of activated carbons CAN-7 and oxidized CAN-8 has been assessed by using Freundlich equation.

  4. Adsorption of chromium ion (VI) by acid activated carbon

    OpenAIRE

    A. A. Attia; Khedr,S. A.; Elkholy,S. A.

    2010-01-01

    The activated carbon produced from olive stones was chemically activated using sulfuric acid, (OS-S), and utilized as an adsorbent for the removal of Cr(VI) from aqueous solution in the concentration range 4-50 mg/L. Adsorption experiments were carried out in a batch process and various experimental parameters such as effect of contact time, initial chromium ion concentration, carbon dosage, and pH on percentage removal have been studied. Adsorption results obtained for activated carbon (OS-S...

  5. Sensitivity analysis of an LCL-filter-based three-phase active rectifier via a virtual circuit approach

    DEFF Research Database (Denmark)

    Blaabjerg, Frede; Chiarantoni, Ernesto; Aquila, Antonio Dell’;

    2004-01-01

    , to the grid side stiffness and to the parameters of the controller has never been detailed considered. In this paper the experimental results of an LCL-filter-based three-phase active rectifier are analysed with the circuit theory approach. A ?virtual circuit? is synthesized in role of the digital controller...... and of the feedback filters to have an homogenous model that allows a sensitivity analysis which is rigorous and straightforward for the industry....

  6. Study of Active Disturbance Rejection Controller on Filtering%ESO抑制扰动特性的研究

    Institute of Scientific and Technical Information of China (English)

    赵秀元

    2011-01-01

    Active disturbance rejection controlling technique on filtering is presented, and some examples given. The results show that it has fine filtering characters to high frequency noises.%给出了自抗扰控制技术用于滤波的研究结果,提供了一些仿真实例.结果表明,这种新型的控制技术对高频噪声具有较好的滤波特性.

  7. Physicochemical and porosity characteristics of thermally regenerated activated carbon polluted with biological activated carbon process.

    Science.gov (United States)

    Dong, Lihua; Liu, Wenjun; Jiang, Renfu; Wang, Zhansheng

    2014-11-01

    The characteristics of thermally regenerated activated carbon (AC) polluted with biological activated carbon (BAC) process were investigated. The results showed that the true micropore and sub-micropore volume, pH value, bulk density, and hardness of regenerated AC decreased compared to the virgin AC, but the total pore volume increased. XPS analysis displayed that the ash contents of Al, Si, and Ca in the regenerated AC respectively increased by 3.83%, 2.62% and 1.8%. FTIR spectrum showed that the surface functional groups of virgin and regenerated AC did not change significantly. Pore size distributions indicated that the AC regeneration process resulted in the decrease of micropore and macropore (D>10 μm) volume and the increase of mesopore and macropore (0.1 μm

  8. Multiple hormonal activities of UV filters and comparison of in vivo and in vitro estrogenic activity of ethyl-4-aminobenzoate in fish.

    Science.gov (United States)

    Kunz, Petra Y; Fent, Karl

    2006-10-12

    UV filters have been detected in surface water, wastewater and fish, and some of them are estrogenic in fish. At present, little is known about their additional hormonal activities in different hormonal receptor systems despite their increasing use and environmental persistence. Besides estrogenic activity, UV filters may have additional activities, both agonistic and antagonistic in aquatic organisms. In our study, we investigate a series of UV filters for multiple hormonal activities in vitro in human receptor systems and evaluate the predictive value of these findings for the activity in fish in vitro and in vivo. First we systematically analysed the estrogenic, antiestrogenic, androgenic, and antiandrogenic activity of 18 UV filters and one metabolite in vitro at non-cytotoxic concentrations with recombinant yeast systems carrying either a human estrogen (hERalpha) or androgen receptor (hAR). All 19 compounds elicited hormonal activities, surprisingly most of them multiple activities. We found 10 UV-filters having agonistic effects towards the hERalpha. Surprisingly, we identified for the first time six UV filters with androgenic activities and many of them having pronounced antiestrogenic and antiandrogenic activities. As much as 17 compounds inhibited 4,5-dihydrotestosterone activity in the hAR assay, while 14 compounds inhibited estradiol activity in the hERalpha assay, indicating antiandrogenic and antiestrogenic activity, respectively. In particular, the antiandrogenic activities of phenyl- and benzyl salicylate, benzophenone-1 and -2, and of 4-hydroxybenzophenone were higher than that of flutamide, a known hAR antagonist. In a second series of experiments, we investigated the predictive power of the hERalpha assay for aquatic organisms by further investigating the estrogenic UV filter ethyl 4-aminobenzoate (Et-PABA) in vitro and in vivo in fish. Et-PABA showed estrogenic activity in a recombinant yeast system carrying the rainbow trout estrogen receptor

  9. Adsorption onto activated carbons in environmental engineering: some trends in water and air treatment processes

    Energy Technology Data Exchange (ETDEWEB)

    Le Cloirec, P. [Ecole des Mines de Nantes, UMR CNRS 6144 GEPEA, 44 (France)

    2005-07-01

    Full text of publication follows: Adsorption is commonly used in environmental protection processes and particularly in water and air treatment systems. Organic pollutants in aqueous or gaseous phases are transferred and adsorbed onto porous materials. Activated carbon (powder, grains) treatment is usually carried out and filters are used to eliminate volatile organic compounds (VOC), odors or micropollutants. The main objectives of this paper are to present examples of classical or new activated carbon processes used in drinking water production, wastewater purification or in air treatment in terms of processes, performances and modeling. - Water treatment: Micropollutants such as pesticides, herbicides... are classically removed by activated carbon granular systems in drinking water treatment plants. In order to get a good water quality and to safe money, the breakthrough time has to be accurately determined. Models with mass balance and transfer equations are proposed. However, some difficulties are found especially for complex solutions to get good agreement between experimental data and calculated values. A statistical approach using neural networks is proposed to simulate breakthrough curves. Examples are presented and compared to deterministic models. In order to intensify processes, a combination of ultrafiltration and activated carbon fiber cloth (ACFC) is presented to remove the large spectra of particles and organic molecules present in water. Systems (UF/ACFC) for surface water and industrial colored wastewater are applied and performances are determined as a function of operating conditions. - Air treatment: Activated carbon grain filters are used to control VOC emissions. Due to an exothermic reaction, an increase of local temperature in the reactor is noted and some fire accidents have been reported. For safety technologies, this temperature has to be previously determined. A model is proposed to simulate the breakthrough curves and temperatures

  10. Effect of high substrate bias and hydrogen and nitrogen incorporation on filtered cathodic vacuum arc deposited tetrahedral amorphous carbon films

    Energy Technology Data Exchange (ETDEWEB)

    Panwar, O.S. [Plasma Processed Materials Group, National Physical Laboratory, Dr. K.S. Krishnan Road, New Delhi-110 012 (India)], E-mail: ospanwar@mail.nplindia.ernet.in; Khan, Mohd. Alim [Plasma Processed Materials Group, National Physical Laboratory, Dr. K.S. Krishnan Road, New Delhi-110 012 (India); Kumar, Mahesh; Shivaprasad, S.M. [Surface Physics and Nanostructures Group, National Physical Laboratory, Dr. K.S. Krishnan Road, New Delhi-110 012 (India); Satyanarayana, B.S. [MIT Innovation Centre and Electronics and Communication Department, Manipal Institute of Technology, Manipal-579104 (India); Dixit, P.N. [Plasma Processed Materials Group, National Physical Laboratory, Dr. K.S. Krishnan Road, New Delhi-110 012 (India); Bhattacharyya, R. [Emeritus Scientist, National Physical Laboratory, New Delhi-110012 (India); Khan, M.Y. [Department of Physics, Jamia Millia Islamia, Central University, New Delhi-110025 (India)

    2008-02-29

    The application of a sufficiently high negative substrate bias, during the growth of tetrahedral amorphous carbon (ta-C), is usually associated with low sp{sup 3} bonding configuration and stressed films. However, in an effort to understand and utilize the higher pseudo thermo dynamical conditions during the film growth, at high negative substrate bias (- 300 V), reported here is a study on ta-C films grown under different hydrogen and nitrogen concentration. As grown ta-C films were studied under different negative substrate bias conditions. The variation of the sp{sup 3} content and sp{sup 3}/sp{sup 2} ratio in the ta-C films exhibits a trend similar to those reported in literature, with a subtle variation in this report being the substrate bias voltage, which was observed to be around - 200 V, for obtaining the highest sp{sup 3} (80%) bonding and sp{sup 3}/sp{sup 2} (3.95) ratio. The hydrogen and nitrogen incorporated ta-C films studied, at a bias of - 300 V, show an increase in sp{sup 3} (87-91%) bonding and sp{sup 3}/sp{sup 2} (7-10) ratio in the range of studies reported. The inference is drawn on the basis of the set of data obtained from measurements carried out using X-ray photoelectron spectroscopy, X-ray induced Auger electron spectroscopy and Raman spectroscopy of as grown and hydrogen and nitrogen incorporated ta-C films deposited using an S bend filtered cathodic vacuum arc system. The study indicates the possibility of further tailoring ta-C film properties and also extending capabilities of the cathodic arc system for developing carbon based films for electronics and tribological applications.

  11. Carbon Dioxide (CO2) Adsorption by Activated Carbon Functionalized with Deep Eutectic Solvent (DES)

    Science.gov (United States)

    Zulkurnai, N. Z.; Ali, U. F. Md.; Ibrahim, N.; Manan, N. S. Abdul

    2017-06-01

    In recent years, carbon dioxide (CO2) emission has become a major concern as the amount of the emitted gas significantly increases annually. Consequently, this phenomenon contributes to global warming. Several CO2 capture methods, including chemical adsorption by activated carbon, have been proposed. In this study, activated carbon was prepared from sea mango (Cerbera odollam), which was functionalized with deep eutectic solvent (DES) composed of choline chloride and glycerol to increase the efficiency of CO2 capture. The samples underwent pre-carbonization and carbonization processes at 200 °C and 500 °C, respectively, with nitrogen gas and flowing several gases, namely, CO2 and steam, and then followed by impregnation with 50 phosphoric acid (H3PO4) at 1:2 precursor-to-activant ratio. The prepared activated carbon was impregnated with DES at 1:2 precursor-to-activant ratio. The optimum CO2 adsorption capacity of the activated carbon was obtained by using CO2 gas treatment method (9.851 mgCO2/gsol), followed by the absence of gases (9.685 mgCO2/gsol), steam (9.636 mgCO2/gsol), and N2 (9.536 mgCO2/gsol).

  12. Interaction forces between waterborne bacteria and activated carbon particles

    NARCIS (Netherlands)

    Busscher, Henk J.; Dijkstra, Rene J. B.; Langworthy, Don E.; Collias, Dimitris I.; Bjorkquist, David W.; Mitchell, Michael D.; Van der Mei, Henny C.

    2008-01-01

    Activated carbons remove waterborne bacteria from potable water systems through attractive Lifshitz-van der Waals forces despite electrostatic repulsion between negatively charged cells and carbon surfaces. In this paper we quantify the interaction forces between bacteria with negatively and positiv

  13. ELEMENTAL MERCURY CAPTURE BY ACTIVATED CARBON IN A FLOW REACTOR

    Science.gov (United States)

    The paper gives results of bench-scale experiments in a flow reactor to simulate the entrained-flow capture of elemental mercury (Hgo) using solid sorbents. Adsorption of Hgo by a lignite-based activated carbon (Calgon FGD) was examined at different carbon/mercury (C/Hg) rat...

  14. Collaborative filtering for brain-computer interaction using transfer learning and active class selection.

    Directory of Open Access Journals (Sweden)

    Dongrui Wu

    Full Text Available Brain-computer interaction (BCI and physiological computing are terms that refer to using processed neural or physiological signals to influence human interaction with computers, environment, and each other. A major challenge in developing these systems arises from the large individual differences typically seen in the neural/physiological responses. As a result, many researchers use individually-trained recognition algorithms to process this data. In order to minimize time, cost, and barriers to use, there is a need to minimize the amount of individual training data required, or equivalently, to increase the recognition accuracy without increasing the number of user-specific training samples. One promising method for achieving this is collaborative filtering, which combines training data from the individual subject with additional training data from other, similar subjects. This paper describes a successful application of a collaborative filtering approach intended for a BCI system. This approach is based on transfer learning (TL, active class selection (ACS, and a mean squared difference user-similarity heuristic. The resulting BCI system uses neural and physiological signals for automatic task difficulty recognition. TL improves the learning performance by combining a small number of user-specific training samples with a large number of auxiliary training samples from other similar subjects. ACS optimally selects the classes to generate user-specific training samples. Experimental results on 18 subjects, using both k nearest neighbors and support vector machine classifiers, demonstrate that the proposed approach can significantly reduce the number of user-specific training data samples. This collaborative filtering approach will also be generalizable to handling individual differences in many other applications that involve human neural or physiological data, such as affective computing.

  15. Collaborative filtering for brain-computer interaction using transfer learning and active class selection.

    Science.gov (United States)

    Wu, Dongrui; Lance, Brent J; Parsons, Thomas D

    2013-01-01

    Brain-computer interaction (BCI) and physiological computing are terms that refer to using processed neural or physiological signals to influence human interaction with computers, environment, and each other. A major challenge in developing these systems arises from the large individual differences typically seen in the neural/physiological responses. As a result, many researchers use individually-trained recognition algorithms to process this data. In order to minimize time, cost, and barriers to use, there is a need to minimize the amount of individual training data required, or equivalently, to increase the recognition accuracy without increasing the number of user-specific training samples. One promising method for achieving this is collaborative filtering, which combines training data from the individual subject with additional training data from other, similar subjects. This paper describes a successful application of a collaborative filtering approach intended for a BCI system. This approach is based on transfer learning (TL), active class selection (ACS), and a mean squared difference user-similarity heuristic. The resulting BCI system uses neural and physiological signals for automatic task difficulty recognition. TL improves the learning performance by combining a small number of user-specific training samples with a large number of auxiliary training samples from other similar subjects. ACS optimally selects the classes to generate user-specific training samples. Experimental results on 18 subjects, using both k nearest neighbors and support vector machine classifiers, demonstrate that the proposed approach can significantly reduce the number of user-specific training data samples. This collaborative filtering approach will also be generalizable to handling individual differences in many other applications that involve human neural or physiological data, such as affective computing.

  16. Shunt hybrid active power filter under nonideal voltage based on fuzzy logic controller

    Science.gov (United States)

    Dey, Papan; Mekhilef, Saad

    2016-09-01

    In this paper, a synchronous reference frame (SRF) method based on a modified phase lock loop (PLL) circuit is developed for a three-phase four-wire shunt hybrid active power filter (APF). Its performance is analysed under unbalanced grid conditions. The dominant lower order harmonics as well as reactive power can be compensated by the passive elements, whereas the active part mitigates the remaining distortions and improves the power quality. As different control methods show contradictory performance, fuzzy logic controller is considered here for DC-link voltage regulation of the inverter. Extensive simulations of the proposed technique are carried out in a MATLAB-SIMULINK environment. A laboratory prototype has been built on dSPACE1104 platform to verify the feasibility of the suggested SHAPF controller. The simulation and experimental results validate the effectiveness of the proposed technique.

  17. Mechanism of phenol adsorption onto electro-activated carbon granules.

    Science.gov (United States)

    Lounici, H; Aioueche, F; Belhocine, D; Drouiche, M; Pauss, A; Mameri, N

    2004-01-01

    The main purpose of this paper is to determine the mechanisms which govern the adsorption of the phenol onto electro-activated carbon granules. This new activation technique allowed an increase of the performance of the adsorbent. Two models were utilised to understand the improvement in the performance of electroactivated carbon granules. The first, a simple external resistance model based on film resistance, gave acceptable predictions, with an error of less than 15%, between the theoretical results and experimental data independent of the activation potential and phenol initial concentration. The second linear model, based on diffusion phenomena, was more representative in describing the experiment than the first model. It was observed that the electro-activation method did not change the mechanism which governs phenol adsorption onto granular carbon. Indeed, the same mathematical model based on diffusion phenomena made it possible to predict with a very low error (less than 5%) the experimental data obtained for the favourable activation potential, without activation potential and with an unfavourable activation potential. The electro-activation technique makes it possible to increase the number of active sites that improve the performance of the electro-activated granular carbon compared with conventional granular activated carbon.

  18. STUDIES ON THE PREPARATION OF ZINC-CONTAINING ACTIVATED CARBON FIBERS AND THEIR ANTIBACTERIAL ACTIVITY

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Several kinds of activated carbon fibers, using sisal fiber as precursors, were preparedwith steam activation or with ZnCl2 activation. Zinc or its compounds were dispersed in them. Theantibacterial activities of these activated carbon fibers were determined and compared. The researchresults showed that these sisal based activated carbon fibers supporting zinc have strongerantibacterial activity against Escherichia coli and S. aureus. The antibacterial activity is related tothe precursors, the pyrolysis temperature, and the zinc content. In addition, small quantity of silversupported on zinc-containing ACFs will greatly enhance the antibacterial activity of ACFs.

  19. Intact tropical forests, new evidence they uptake carbon actively

    Directory of Open Access Journals (Sweden)

    2009-03-01

    Full Text Available According to a paper recently published on Nature, tropical forests play as active carbon sink, absorbing 1.3·109 tons of carbon per year on a global scale. Functional interpretation is not clear yet, but a point is quite easy to realize: tropical forests accumulate and contain more carbon than any other vegetation cover and, if their disruption goes on at current rates, these ecosystems could revert to be a “carbon bomb”, releasing huge amount of CO2 to the atmosphere.

  20. Time-windows-based filtering method for near-surface detection of leakage from geologic carbon sequestration sites

    Energy Technology Data Exchange (ETDEWEB)

    Pan, L.; Lewicki, J.L.; Oldenburg, C.M.; Fischer, M.L.

    2010-02-28

    We use process-based modeling techniques to characterize the temporal features of natural biologically controlled surface CO{sub 2} fluxes and the relationships between the assimilation and respiration fluxes. Based on these analyses, we develop a signal-enhancing technique that combines a novel time-window splitting scheme, a simple median filtering, and an appropriate scaling method to detect potential signals of leakage of CO{sub 2} from geologic carbon sequestration sites from within datasets of net near-surface CO{sub 2} flux measurements. The technique can be directly applied to measured data and does not require subjective gap filling or data-smoothing preprocessing. Preliminary application of the new method to flux measurements from a CO{sub 2} shallow-release experiment appears promising for detecting a leakage signal relative to background variability. The leakage index of ?2 was found to span the range of biological variability for various ecosystems as determined by observing CO{sub 2} flux data at various control sites for a number of years.

  1. TESTING GUIDELINES FOR TECHNETIUM-99 ABSORPTION ON ACTIVATED CARBON

    Energy Technology Data Exchange (ETDEWEB)

    BYRNES ME

    2010-09-08

    CH2M HILL Plateau Remediation Company (CHPRC) is currently evaluating the potential use of activated carbon adsorption for removing technetium-99 from groundwater as a treatment method for the Hanford Site's 200 West Area groundwater pump-and-treat system. The current pump-and-treat system design will include an ion-exchange (IX) system for selective removal of technetium-99 from selected wells prior to subsequent treatment of the water in the central treatment system. The IX resin selected for technetium-99 removal is Purolite A530E. The resin service life is estimated to be approximately 66.85 days at the design technetium-99 loading rate, and the spent resin must be replaced because it cannot be regenerated. The resulting operating costs associated with resin replacement every 66.85 days are estimated at $0.98 million/year. Activated carbon pre-treatment is being evaluated as a potential cost-saving measure to offset the high operating costs associated with frequent IX resin replacement. This document is preceded by the Literature Survey of Technetium-99 Groundwater Pre-Treatment Option Using Granular Activated Carbon (SGW-43928), which identified and evaluated prior research related to technetium-99 adsorption on activated carbon. The survey also evaluated potential operating considerations for this treatment approach for the 200 West Area. The preliminary conclusions of the literature survey are as follows: (1) Activated carbon can be used to selectively remove technetium-99 from contaminated groundwater. (2) Technetium-99 adsorption onto activated carbon is expected to vary significantly based on carbon types and operating conditions. For the treatment approach to be viable at the Hanford Site, activated carbon must be capable of achieving a designated minimum technetium-99 uptake. (3) Certain radionuclides known to be present in 200 West Area groundwater are also likely to adsorb onto activated carbon. (4) Organic solvent contaminants of concern (COCs

  2. A novel spatiotemporal muscle activity imaging approach based on the Extended Kalman Filter.

    Science.gov (United States)

    Wang, Jing; Zhang, Yingchun; Zhu, Xiangjun; Zhou, Ping; Liu, Chenguang; Rymer, William Z

    2012-01-01

    A novel spatiotemporal muscle activity imaging (sMAI) approach has been developed using the Extended Kalman Filter (EKF) to reconstruct internal muscle activities from non-invasive multi-channel surface electromyogram (sEMG) recordings. A distributed bioelectric dipole source model is employed to describe the internal muscle activity space, and a linear relationship between the muscle activity space and the sEMG measurement space is then established. The EKF is employed to recursively solve the ill-posed inverse problem in the sMAI approach, in which the weighted minimum norm (WMN) method is utilized to calculate the initial state and a new nonlinear method is developed based on the propagating features of muscle activities to predict the recursive state. A series of computer simulations was conducted to test the performance of the proposed sMAI approach. Results show that the localization error rapidly decreases over 35% and the overlap ratio rapidly increases over 45% compared to the results achieved using the WMN method only. The present promising results demonstrate the feasibility of utilizing the proposed EKF-based sMAI approach to accurately reconstruct internal muscle activities from non-invasive sEMG recordings.

  3. Carbon-carbon bond cleavage in activation of the prodrug nabumetone.

    Science.gov (United States)

    Varfaj, Fatbardha; Zulkifli, Siti N A; Park, Hyoung-Goo; Challinor, Victoria L; De Voss, James J; Ortiz de Montellano, Paul R

    2014-05-01

    Carbon-carbon bond cleavage reactions are catalyzed by, among others, lanosterol 14-demethylase (CYP51), cholesterol side-chain cleavage enzyme (CYP11), sterol 17β-lyase (CYP17), and aromatase (CYP19). Because of the high substrate specificities of these enzymes and the complex nature of their substrates, these reactions have been difficult to characterize. A CYP1A2-catalyzed carbon-carbon bond cleavage reaction is required for conversion of the prodrug nabumetone to its active form, 6-methoxy-2-naphthylacetic acid (6-MNA). Despite worldwide use of nabumetone as an anti-inflammatory agent, the mechanism of its carbon-carbon bond cleavage reaction remains obscure. With the help of authentic synthetic standards, we report here that the reaction involves 3-hydroxylation, carbon-carbon cleavage to the aldehyde, and oxidation of the aldehyde to the acid, all catalyzed by CYP1A2 or, less effectively, by other P450 enzymes. The data indicate that the carbon-carbon bond cleavage is mediated by the ferric peroxo anion rather than the ferryl species in the P450 catalytic cycle. CYP1A2 also catalyzes O-demethylation and alcohol to ketone transformations of nabumetone and its analogs.

  4. Quality of poultry litter-derived granular activated carbon.

    Science.gov (United States)

    Qiu, Guannan; Guo, Mingxin

    2010-01-01

    Utilization of poultry litter as a source material for generating activated carbon is a value-added and environmentally beneficial approach to recycling organic waste. In this study, the overall quality of poultry litter-derived granular activated carbon was systematically evaluated based on its various physical and chemical properties. Granular activated carbon generated from pelletized poultry litter following a typical steam-activation procedure possessed numerous micropores in the matrix. The product exhibited a mean particle diameter of 2.59 mm, an apparent density of 0.45 g cm(-3), a ball-pan hardness of 91.0, an iodine number of 454 mg g(-1), and a BET surface area of 403 m(2) g(-1). It contained high ash, nitrogen, phosphorus contents and the trace elements Cu, Zn, and As. Most of the nutrients and toxic elements were solidified and solution-unextractable. In general, poultry litter-based activated carbon demonstrated overall quality comparable to that of low-grade commercial activated carbon derived from coconut shell and bituminous coal. It is promising to use poultry litter as a feedstock to manufacture activated carbon for wastewater treatment.

  5. Autonomous Navigation for Autonomous Underwater Vehicles Based on Information Filters and Active Sensing

    Directory of Open Access Journals (Sweden)

    Tianhong Yan

    2011-11-01

    Full Text Available This paper addresses an autonomous navigation method for the autonomous underwater vehicle (AUV C-Ranger applying information-filter-based simultaneous localization and mapping (SLAM, and its sea trial experiments in Tuandao Bay (Shangdong Province, P.R. China. Weak links in the information matrix in an extended information filter (EIF can be pruned to achieve an efficient approach-sparse EIF algorithm (SEIF-SLAM. All the basic update formulae can be implemented in constant time irrespective of the size of the map; hence the computational complexity is significantly reduced. The mechanical scanning imaging sonar is chosen as the active sensing device for the underwater vehicle, and a compensation method based on feedback of the AUV pose is presented to overcome distortion of the acoustic images due to the vehicle motion. In order to verify the feasibility of the navigation methods proposed for the C-Ranger, a sea trial was conducted in Tuandao Bay. Experimental results and analysis show that the proposed navigation approach based on SEIF-SLAM improves the accuracy of the navigation compared with conventional method; moreover the algorithm has a low computational cost when compared with EKF-SLAM.

  6. Autonomous navigation for autonomous underwater vehicles based on information filters and active sensing.

    Science.gov (United States)

    He, Bo; Zhang, Hongjin; Li, Chao; Zhang, Shujing; Liang, Yan; Yan, Tianhong

    2011-01-01

    This paper addresses an autonomous navigation method for the autonomous underwater vehicle (AUV) C-Ranger applying information-filter-based simultaneous localization and mapping (SLAM), and its sea trial experiments in Tuandao Bay (Shangdong Province, P.R. China). Weak links in the information matrix in an extended information filter (EIF) can be pruned to achieve an efficient approach-sparse EIF algorithm (SEIF-SLAM). All the basic update formulae can be implemented in constant time irrespective of the size of the map; hence the computational complexity is significantly reduced. The mechanical scanning imaging sonar is chosen as the active sensing device for the underwater vehicle, and a compensation method based on feedback of the AUV pose is presented to overcome distortion of the acoustic images due to the vehicle motion. In order to verify the feasibility of the navigation methods proposed for the C-Ranger, a sea trial was conducted in Tuandao Bay. Experimental results and analysis show that the proposed navigation approach based on SEIF-SLAM improves the accuracy of the navigation compared with conventional method; moreover the algorithm has a low computational cost when compared with EKF-SLAM.

  7. Active listening room compensation for massive multichannel sound reproduction systems using wave-domain adaptive filtering.

    Science.gov (United States)

    Spors, Sascha; Buchner, Herbert; Rabenstein, Rudolf; Herbordt, Wolfgang

    2007-07-01

    The acoustic theory for multichannel sound reproduction systems usually assumes free-field conditions for the listening environment. However, their performance in real-world listening environments may be impaired by reflections at the walls. This impairment can be reduced by suitable compensation measures. For systems with many channels, active compensation is an option, since the compensating waves can be created by the reproduction loudspeakers. Due to the time-varying nature of room acoustics, the compensation signals have to be determined by an adaptive system. The problems associated with the successful operation of multichannel adaptive systems are addressed in this contribution. First, a method for decoupling the adaptation problem is introduced. It is based on a generalized singular value decomposition and is called eigenspace adaptive filtering. Unfortunately, it cannot be implemented in its pure form, since the continuous adaptation of the generalized singular value decomposition matrices to the variable room acoustics is numerically very demanding. However, a combination of this mathematical technique with the physical description of wave propagation yields a realizable multichannel adaptation method with good decoupling properties. It is called wave domain adaptive filtering and is discussed here in the context of wave field synthesis.

  8. Filter Paper Inspired Zinc Oxide Nanomaterials with High Photocatalytic Activity for Degradation of Methylene Orange

    Directory of Open Access Journals (Sweden)

    Huang Liu

    2016-01-01

    Full Text Available Nanometer-sized zinc oxide (ZnO has been synthesized through sol-gel method with natural cellulose substance (commercial filter paper as template. The structure of zinc oxide nanomaterial was characterized by nitrogen adsorption-desorption and XRD. The morphology was observed by SEM and TEM. The results show that the hexagonal wurtzite phase is actually the only crystal phase in the sample and the product faithfully inherits the hierarchical morphology and the complex network structure of the original filter paper, which is composed of many randomly intersecting zinc oxide microfibers and nanosheets with lots of close stacked particles adsorbed on the surface. Moreover, these zinc oxide nanomaterials possess abundant mesoporous structure with an average pore diameter of ca. 21 nm and a wide pore size distribution (3–30 nm. Due to the strong absorption ability in the UV range, the zinc oxide nanomaterial prepared by this method displays significantly high photocatalytic activity for degrading methyl orange. In a short period of 20 minutes, the zinc oxide nanomaterial has degraded about 50% of the original MO, and the MO dye is fully degraded after UV irradiation for 80 minutes.

  9. An Improved Double Fuzzy PI Controller For Shunt Active Power Filter DC Bus Regulation

    Directory of Open Access Journals (Sweden)

    Nabil ELHAJ

    2015-06-01

    Full Text Available This paper targets to demonstrate the importance of the choice of the algorithm references detection to be applied with a double fuzzy PI corrector (DFPI for the control and the regulation of a shunt active power filter (SAPF DC bus voltage. In a previous work, the synchronous reference frame (SRF algorithm was applied and gave satisfactory results. In the present paper, the SRF is substituted by the positive sequence of the fundamental of the source voltage algorithm (PSF which offered better results regarding the power quality of the considered main utility feeding a variable DC RL load throughout a diode bridge. The results were carried out using computer simulation perfomed under MATLAB/Simulink environment. To make the obtained results more convenient, a comparison between the couples (SRF, PI, (PSF, PI, (SRF, DFPI, (PSF, DFPI is added to prove the effectiveness of the couple (PSF, DFPI in satisfying the compromise between a good regulation of the SAPF DC bus voltage and a good quality of filtering resulting in an improved quality of power.

  10. A Series-LC-Filtered Active Damper with Grid Disturbance Rejection for AC Power-Electronics-Based Power Systems

    DEFF Research Database (Denmark)

    Wang, Xiongfei; Pang, Ying; Loh, Poh Chiang;

    2015-01-01

    damper. Unlike an active power filter for mitigating low-frequency harmonics, the proposed damper dampens resonances at higher frequencies, whose values are dependent on interactions among multiple grid-connected converters and reactive elements of the system. Its control requirements are, therefore......-order resonant controller, in addition to the second-order resonant controller used for resonance damping. Experimental results obtained have confirmed the effectiveness of these controllers, and hence, the feasibility of the active damper.......This letter proposes an active damper with a series LC filter for suppressing resonances in an ac power-electronics-based power system. The added series filter capacitor helps to withstand most of the system voltage, hence, allowing a lower rated converter to be used for implementing the active...

  11. Functionalized Activated Carbon Derived from Biomass for Photocatalysis Applications Perspective

    Directory of Open Access Journals (Sweden)

    Samira Bagheri

    2015-01-01

    Full Text Available This review highlighted the developments of safe, effective, economic, and environmental friendly catalytic technologies to transform lignocellulosic biomass into the activated carbon (AC. In the photocatalysis applications, this AC can further be used as a support material. The limits of AC productions raised by energy assumption and product selectivity have been uplifted to develop sustainable carbon of the synthesis process, where catalytic conversion is accounted. The catalytic treatment corresponding to mild condition provided a bulk, mesoporous, and nanostructure AC materials. These characteristics of AC materials are necessary for the low energy and efficient photocatalytic system. Due to the excellent oxidizing characteristics, cheapness, and long-term stability, semiconductor materials have been used immensely in photocatalytic reactors. However, in practical, such conductors lead to problems with the separation steps and loss of photocatalytic activity. Therefore, proper attention has been given to develop supported semiconductor catalysts and certain matrixes of carbon materials such as carbon nanotubes, carbon microspheres, carbon nanofibers, carbon black, and activated carbons have been recently considered and reported. AC has been reported as a potential support in photocatalytic systems because it improves the transfer rate of the interface charge and lowers the recombination rate of holes and electrons.

  12. Activated Carbon Prepared in a Novel Gas Fired Static Bed ...

    African Journals Online (AJOL)

    Michael O. Mensah

    2015-12-02

    Dec 2, 2015 ... The reactor is fabricated using stainless steel plates of 4 mm ... is introduced into the reaction chamber. The ... reaction of carbon with the activating agent. A number ..... organic liquids, characterisation of the organic fraction of.

  13. OXIDATION AND CHARACTERIZATION OF ACTIVE CARBON AG-5

    Directory of Open Access Journals (Sweden)

    Tatiana Goreacioc

    2015-06-01

    Full Text Available The surface chemistry of the commercial active carbon AG-5 has been modified by oxidation with concentrated nitric acid. The structural changes caused by oxidative treatment were estimated on the basis of nitrogen adsorption-desorption isotherms and thermal analysis. Boehm titration method and infrared spectral analysis have been used in order to evaluate surface chemistry characteristics of active carbon samples. After oxidation process the amount of total acidic groups on oxidized active carbon surface (AG-5ox increases by about 6 times in comparison with unmodified sample (AG-5. The concentration of the acidic groups on the oxidized active carbon surface (AG-5ox was in the following order: strong acidic >>> weak acidic > phenolic.

  14. Application of Activated Carbon Mixed Matrix Membrane for Oxygen Purification

    Directory of Open Access Journals (Sweden)

    Tutuk Djoko Kusworo

    2010-07-01

    Full Text Available This study is performed primarily to investigate the effect of activated carbon on oxygen separation performance of polyethersulfone mixed matrix membrane. In this study, polyethersulfone (PES-activated carbon (AC mixed matrix membranes were fabricated using dry/wet technique. This study investigates the effect of polyethersulfone concentration and activated carbon loading on the performance of mixed matrix membrane in terms of permeability and selectivity of O2/N2 gas separation. The fabricated flat sheet mixed matrix membranes were characterized using permeation test, Field Emission Scanning Electron Microscopy (FESEM analysis and Differential Scanning Calorimetry (DSC. It was found that the activated carbon loading affected the gas separation performance of mixed matrix membrane. PES- 1wt% AC membrane yielded 3.75 of O2/N2 selectivity, however 5 wt% of AC can produced 5 O2/N2 selectivity

  15. [Influence of biological activated carbon dosage on landfill leachate treatment].

    Science.gov (United States)

    Cui, Yan-Rui; Guo, Yan; Wu, Qing

    2014-08-01

    Effects of biological activated carbon (BAC) dosage on COD removal in landfill leachate treatment were compared. The COD removal efficiency of reactors with 0, 100 and 300 g activated carbon dosage per litre activated sludge was 12.9%, 19.6% and 27.7%, respectively. The results indicated that BAC improved the refractory organic matter removal efficiency and there was a positive correlation between COD removal efficiency and BAC dosage. The output of carbon dioxide after 8h of aeration in reactors was 109, 193 and 306 mg corresponding to the activated carbon dosages mentioned above, which indicated the amount of biodegradation and BAC dosage also had a positive correlation. The combination of adsorption and bioregeneration of BAC resulted in the positive correlation betweem organic matter removal efficiency and BAC dosage, and bioregeneration was the root cause for the microbial decomposition of refractory organics.

  16. (Hevea brasiliensis) SEED PERICARP-ACTIVATED CARBON IN ...

    African Journals Online (AJOL)

    2012-11-03

    Nov 3, 2012 ... Biochemical Engineering and Biotechnology Laboratory, ... Keywords: abattoir waste water, activated carbon, adsorption isotherms, iron (III) chloride, lagergren equations, ... industrial wastes as well as natural agricultural bye-.

  17. Sustainable Regeneration of Nanoparticle Enhanced Activated Carbon in Water

    Science.gov (United States)

    The regeneration and reuse of exhausted granular activated carbon (GAC) is an appropriate method for lowering operational and environmental costs. Advanced oxidation is a promising environmental friendly technique for GAC regeneration. The main objective of this research was to ...

  18. Cooperative redox activation for carbon dioxide conversion

    DEFF Research Database (Denmark)

    Lian, Zhong; Nielsen, Dennis U.; Lindhardt, Anders T.

    2016-01-01

    A longstanding challenge in production chemistry is the development of catalytic methods for the transformation of carbon dioxide into useful chemicals. Silane and borane promoted reductions can be fined-tuned to provide a number of C1-building blocks under mild conditions, but these approaches...

  19. Carbon dioxide capture by activated methyl diethanol amine impregnated mesoporous carbon

    Science.gov (United States)

    Ardhyarini, N.; Krisnandi, Y. K.

    2017-07-01

    Activated Methyl Diethanol Amine (aMDEA) were impregnated onto the surface of the mesoporous carbon to increase carbon dioxide (CO2) adsorption capacity. The mesoporous carbon was synthesized through soft template method with phloroglucinol as carbon precursor and triblock copolymer (Pluronic F127) as structure directing agent. These activated MDEA impregnated mesoporous carbon (aMDEA-MC) were characterized using various solid characterization techniques. CO2 adsorption was investigated using autoclaved-reactor in the batch system. The FTIR spectrum of aMDEA-MC had absorption peaks at 3395 cm-1 and 1031 cm-1 which are characteristic for O-H stretch and amine C-N stretch in MDEA. The elemental analyzer showed that nitrogen content on the mesoporous carbon increased after impregnation by 23 wt.%. The BET surface area and total pore volume of mesoporous carbon decreased after impregnation, 43 wt.% and 50 wt.%, respectively. The maximum CO2 adsorption capacity of aMDEA43-MC was 2.63 mmol/g (298 K, 5 psi and pure CO2). This is 64 % and 35 % higher compared to the CO2 adsorption capacity of the starting MC and also commercially available activated carbon with higher surface area. All the results suggest that MDEA-MC is a promising adsorbent for CO2 capture.

  20. Waste polyvinylchloride derived pitch as a precursor to develop carbon fibers and activated carbon fibers.

    Science.gov (United States)

    Qiao, W M; Yoon, S H; Mochida, I; Yang, J H

    2007-01-01

    Polyvinylchloride (PVC) was successfully recycled through the solvent extraction from waste pipe with an extraction yield of ca. 86%. The extracted PVC was pyrolyzed by a two-stage process (260 and 410 degrees C) to obtain free-chlorine PVC based pitch through an effective removal of chlorine from PVC during the heat-treatment. As-prepared pitch (softening point: 220 degrees C) was spun, stabilized, carbonized into carbon fibers (CFs), and further activated into activated carbon fibers (ACFs) in a flow of CO2. As-prepared CFs show comparable mechanical properties to commercial CFs, whose maximum tensile strength and modulus are 862 MPa and 62 GPa, respectively. The resultant ACFs exhibit a high surface area of 1200 m2/g, narrow pore size distribution and a low oxygen content of 3%. The study provides an effective insight to recycle PVC from waste PVC and develop a carbon precursor for high performance carbon materials such as CFs and ACFs.

  1. Microstructure and surface properties of lignocellulosic-based activated carbons

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez-Garcia, P., E-mail: pegonzal@quim.ucm.es [Departamento de Quimica Inorganica, Facultad de Ciencias Quimicas, Universidad Complutense, E-28040, Madrid (Spain); Centeno, T.A. [Instituto Nacional del Carbon-CSIC, Apartado 73, E-33080 Oviedo (Spain); Urones-Garrote, E. [Centro Nacional de Microscopia Electronica, Universidad Complutense, E-28040, Madrid (Spain); Avila-Brande, D.; Otero-Diaz, L.C. [Departamento de Quimica Inorganica, Facultad de Ciencias Quimicas, Universidad Complutense, E-28040, Madrid (Spain)

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer Activated carbons were produced by KOH activation at 700 Degree-Sign C. Black-Right-Pointing-Pointer The observed nanostructure consists of highly disordered graphene-like layers with sp{sup 2} bond content Almost-Equal-To 95%. Black-Right-Pointing-Pointer Textural parameters show high surface area ( Almost-Equal-To 1000 m{sup 2}/g) and pore width of 1.3-1.8 nm. Black-Right-Pointing-Pointer Specific capacitance reaches values as high as 161 F/g. - Abstract: Low cost activated carbons have been produced via chemical activation, by using KOH at 700 Degree-Sign C, from the bamboo species Guadua Angustifolia and Bambusa Vulgaris Striata and the residues from shells of the fruits of Castanea Sativa and Juglans Regia as carbon precursors. The scanning electron microscopy micrographs show the conservation of the precursor shape in the case of the Guadua Angustifolia and Bambusa Vulgaris Striata activated carbons. Transmission electron microscopy analyses reveal that these materials consist of carbon platelet-like particles with variable length and thickness, formed by highly disordered graphene-like layers with sp{sup 2} content Almost-Equal-To 95% and average mass density of 1.65 g/cm{sup 3} (25% below standard graphite). Textural parameters indicate a high porosity development with surface areas ranging from 850 to 1100 m{sup 2}/g and average pore width centered in the supermicropores range (1.3-1.8 nm). The electrochemical performance of the activated carbons shows specific capacitance values at low current density (1 mA/cm{sup 2}) as high as 161 F/g in the Juglans Regia activated carbon, as a result of its textural parameters and the presence of pseudocapacitance derived from surface oxygenated acidic groups (mainly quinones and ethers) identified in this activated carbon.

  2. Ultrafine microporous and mesoporous activated carbon fibers from alkali lignin

    OpenAIRE

    2013-01-01

    A facile and sustainable approach has been successfully devised to fabricate ultrafine (100-500 nm) highly porous activated carbon fibers (ACFs) by electrospinning of aqueous solutions of predominantly alkali lignin (low sulfonate content) followed by simultaneous carbonization and activation at 850 °C under N2. Incorporating a polyethylene oxide (PEO) carrier with only up to one ninth of lignin not only enabled efficient electrospinning into fibers but also retained fibrous structures during...

  3. Microwave absorbing properties of activated carbon fibre polymer composites

    Indian Academy of Sciences (India)

    Tianchun Zou; Naiqin Zhao; Chunsheng Shi; Jiajun Li

    2011-02-01

    Microwave absorption of composites containing activated carbon fibres (ACFs) was investigated. The results show that the absorptivity greatly depends on increasing ACF content in the absorbing layer, first increasing and then decreasing. When the content is 0.76 wt.%, the bandwidth below −10dB is 12.2 GHz. Comparing the absorption characteristics of the ACF composite with one containing unactivated fibres, it is found that carbon fibre activation increases the absorption of the composite.

  4. Comparative ecophysiology of active zoobenthic filter feeding, essence of current knowledge

    Science.gov (United States)

    Riisgård, H. U.; Larsen, P. S.

    2000-12-01

    The present contribution gives an overview of current knowledge of a comprehensive and steadily growing research field. The first section deals with water pumping and particle retention mechanisms in ciliary and muscular filter feeders. The second section examines the biological filter pumps in order to assess adaptation to the environment. Filter-feeding benthic invertebrates have evolved filter pumps to solve common basic problems. This has led to a large degree of similarity between otherwise distant standing species, which makes comparative studies interesting and important. The present review of zoobenthic filter feeding aims at accentuating such recognition.

  5. Calculation of Binary Adsorption Equilibria: Hydrocarbons and Carbon Dioxide on Activated Carbon

    DEFF Research Database (Denmark)

    Marcussen, Lis; Krøll, A.

    1999-01-01

    Binary adsorption equilibria are calculated by means of a mathematical model for multicomponent mixtures combined with the SPD (Spreading Pressure Dependent) model for calculation of activity coefficients in the adsorbed phase. The model has been applied successfully for the adsorption of binary ...... mixtures of hydrocarbons and carbon dioxide on activated carbons. The model parameters have been determined, and the model has proven to be suited for prediction of adsorption equilibria in the investigated systems....

  6. Fast filtering false active subspaces for efficient high dimensional similarity processing

    Institute of Scientific and Technical Information of China (English)

    WANG GuoRen; YU Ge; XIN JunChang; ZHAO YuHai; ZHANG EnDe

    2009-01-01

    The query space of a similarity query is usually narrowed down by pruning inactive query subspaces which contain no query results and keeping active query subspaces which may contain objects corre-sponding to the request. However, some active query subspaces may contain no query results at all, those are called false active query subspaces. It is obvious that the performance of query processing degrades in the presence of false active query subspaces. Our experiments show that this problem becomes seriously when the data are high dimensional and the number of accesses to false active sub-spaces increases as the dimensionality increases. In order to solve this problem, this paper proposes a space mapping approach to reducing such unnecessary accesses. A given query space can be re-fined by filtering within its mapped space. To do so, a mapping strategy called maxgap is proposed to improve the efficiency of the refinement processing. Based on the mapping strategy, an index structure called MS-tree and algorithms of query processing are presented in this paper. Finally, the performance of MS-tree is compared with that of other competitors in terms of range queries on a real data set.

  7. Production of activated carbon from rice husk Vietnam

    Science.gov (United States)

    Korobochkin, V. V.; Tu, N. V.; Hieu, N. M.

    2016-09-01

    This work is dedicated to the production of activated carbon from rice husk from Delta of the Red River in Viet Nam. At the first stage, carbonization of a rice husk was carried out to obtain material containing 43.1% carbon and 25 % silica with a specific surface area of 51.5 m2/g. After separating of silica (the second stage), the specific surface area of the product increased to 204 m2/g and the silica content decreased to 1.23% by weight as well. The most important stage in the formation of the porous structure of the material is the activation. The products with the high specific surface area in the range of 800-1345 m2/g were obtained by activation of carbonized product with water vapour or carbon dioxide at temperatures of 700 °C and 850 °C, with varying the flow rate of the activating agent and activation time. The best results were achieved by activation of carbon material with water vapour at the flow rate of 0.08 dm3/min per 500 g of material and the temperature of 850 °C.

  8. Comparison of toluene adsorption among granular activated carbon and different types of activated carbon fibers (ACFs).

    Science.gov (United States)

    Balanay, Jo Anne G; Crawford, Shaun A; Lungu, Claudiu T

    2011-10-01

    Activated carbon fiber (ACF) has been demonstrated to be a good adsorbent for the removal of organic vapors in air. Some ACF has a comparable or larger surface area and higher adsorption capacity when compared with granular activated carbon (GAC) commonly used in respiratory protection devices. ACF is an attractive alternative adsorbent to GAC because of its ease of handling, light weight, and decreasing cost. ACF may offer the potential for short-term respiratory protection for first responders and emergency personnel. This study compares the critical bed depths and adsorption capacities for toluene among GAC and ACF of different forms and surface areas. GAC and ACF in cloth (ACFC) and felt (ACFF) forms were challenged in stainless steel chambers with a constant concentration of 500 ppm toluene via conditioned air at 25°C, 50% RH, and constant airflow (7 L/min). Breakthrough data were obtained for each adsorbent using gas chromatography with flame ionization detector. Surface areas of each adsorbent were determined using a physisorption analyzer. Results showed that the critical bed depth of GAC is 275% higher than the average of ACFC but is 55% lower than the average of ACFF. Adsorption capacity of GAC (with a nominal surface area of 1800 m(2)/g) at 50% breakthrough is 25% higher than the average of ACF with surface area of 1000 m(2)/g, while the rest of ACF with surface area of 1500 m(2)/g and higher have 40% higher adsorption capacities than GAC. ACFC with higher surface area has the smallest critical bed depth and highest adsorption capacity, which makes it a good adsorbent for thinner and lighter respirators. We concluded that ACF has great potential for application in respiratory protection considering its higher adsorption capacity and lower critical bed depth in addition to its advantages over GAC, particularly for ACF with higher surface area.

  9. SEVEN LEVEL CONTROL OF SHUNT ACTIVE POWER FILTER FOR POWER QUALITY ENHANCEMENT

    Directory of Open Access Journals (Sweden)

    G. JAYAKRISHNA

    2011-09-01

    Full Text Available Shunt Active Power Filter (SAPF is one of the controllers to enhance power quality (PQ. This paper presents Hybrid Cascaded Seven-Level Inverter (HCSLI used in SAPF to compensate reactive power, improve the power factor and to suppress the total harmonic distortion (THD in supply current due to linear load and Non- Linear Diode Rectifier Loads (NLDRLs.In this paper d-q reference frame theory for reference current computation, Constant Switching Frequency Multicarrier Sub-Harmonic Pulse Width Modulation (CSFMSHPWM technique for controlling the switches of HCSLI, Fuzzy logic controller (FLC for regulating dc side capacitor voltage are proposed. The results are validated through simulation using Mat Lab/simulink with and without SAPF for linear and nonlinear loads.

  10. Permanent Magnet Synchronous Generator Driven Wind Energy Conversion System Based on Parallel Active Power Filter

    Directory of Open Access Journals (Sweden)

    FERDI Brahim

    2014-05-01

    Full Text Available This paper proposes a novel application of the instantaneous P-Q theory in a wind energy conversion system (WECS. The proposed WECS is formed by permanent magnet synchronous generator (PMSG wind turbine system connected to the grid through parallel active power filter (PAPF. PAPF uses the generated wind energy to feed loads connected at the point of common coupling (PPC, compensates current harmonics and injects the excess of this energy into the grid using P-Q theory as control method. To demonstrate the feasibility and the performance of the proposed control scheme, simulation of this wind system has been realized using MATLAB/SIMULINK software. Simulation results show the accuracy and validity of the proposed control scheme for the PMSGPAPF system.

  11. Synthesis and evaluation of octocrylene-inspired compounds for UV-filter activity

    Directory of Open Access Journals (Sweden)

    Hudson C. Polonini

    2014-07-01

    Full Text Available Octocrylene (2-ethylhexyl 2-cyano-3,3-diphenyl-2-propenoate is present in several sunscreens and is known to work synergistically with UV filters. We prepared eight octocrylene-related compounds to test their photoprotective activities by measuring diffuse transmittance. The compounds had varied photoprotection profiles, with Sun Protection Factors (SPF ranging from 1 to 5 and UVA Protection Factors (UVAPF ranging from 1 to 8. Compounds 4, 5, and 7 showed the best protection against UVB sunrays, while compounds 5, 6, and 7 presented the best results for protection from UVA, so compound 7 had the most balanced protection overall. Results for compounds 4, 8, and 9 are reported for the first time in the literature.

  12. Evaluation of reference current extraction methods for DSP implementation in active power filters

    Energy Technology Data Exchange (ETDEWEB)

    Vardar, K.; Akpinar, E.; Suergevil, T. [Dokuz Eylul University, Department of Electrical and Electronics Engineering, Kaynaklar Kampusu, 35160 Buca, Izmir (Turkey)

    2009-10-15

    Generation of current references constitutes an important part in the control of active power filters (APFs) used in power system, since any inaccuracy in reference currents yields to incorrect compensation. In this paper, harmonic detection methods for generating reference currents have been evaluated on the basis of three-phase balanced and unbalanced load currents processed in the digital signal processor (DSP). The advantages and disadvantages of several methods found in the literature have been discussed on the basis of simulation results. Three of these methods have been programmed in the TMS320F2812 digital signal processor (DSP) unit and their performances are evaluated from the viewpoint of practical considerations. Finally, instantaneous reactive power method to estimate the APF reference currents is implemented and its practical results obtained under balanced and unbalanced loads are given. (author)

  13. Research on a new active power filter topology based on chopper circuit

    CERN Document Server

    Xiaoling, Guo; Bo, Zhang; Jing, Zhang

    2015-01-01

    The active power filter (APF) is attracting more and more attention for its outstanding performance in current and voltage ripple compensation. As modern high-energy accelerators are demanding much more stringent current ripple guideline, the APF is introduced to the magnet power supply (MPS) in accelerator system. However, the conventional APF has a lot of shortages and drawbacks due to its traditional topology, such as complex structure, nonadjustable working voltage, requirement of power supply, and so on. This paper proposes a new topology of APF, which is working as two types of chopper circuits. This APF need not extra electricity, but to use the power of the MPS current ripple to realize ripple depressing. At the end of this paper, the experiment result proves its feasibility and effect.

  14. Novel Algorithm for Active Noise Control Systems Based on Frequency Selective Filters

    Institute of Scientific and Technical Information of China (English)

    Hong-liang ZHAO

    2010-01-01

    A novel algorithm for active noise control systems based on frequency selective filters (FSFANC)is presented in the paper.The FSFANC aims at the m lti-tonal noise attenuation problem.One FSFANC system copes with one of the tonal components,and several FSFANC systems can nun independently in parallel to cancel the selected multiple tones.The proposed algorithm adopts a simple structrue with only two coefficients that can be explained as the real and imaginary parts of the structure to modelthesecondary path,and estimates the secondary path by injecting sinusoidal identification signals.Theoretical analysis and laboratory experiments show that the proposed algorithm possesses some advantages,such as simpler stricture,less computational burden,greater stability,and fast canverging speed.

  15. A Sliding Mode Control for Four-Wire Shunt Active Filter

    Science.gov (United States)

    Hamoudi, Farid; Chaghi, Aziz; Adli, Mouloud; Amimeur, Hocine

    2011-09-01

    The present paper deals with the sliding mode control of a three-phase four-wire shunt active filter SAF, to improve phase-current waveform, neutral current mitigation and reactive power compensation in electric power distribution system. The sliding mode is formulated using elementary differential geometry, then the control vector is deduced from the sliding surface accessibility using the Lyapunov stability. The algorithm used to establish the current references for the sliding mode controller is based on the instantaneous real and imaginary power theory for four-wire system. It will be seen that this method permits to synthesis the control vector with simple manner, and finally, the obtained simulation results confirm that the above objectives are satisfied.

  16. Hysteresis Current Control Based Shunt Active Power Filter for Six Pulse Ac/Dc Converter

    Directory of Open Access Journals (Sweden)

    Rakesh Kumar Pandey

    2017-02-01

    Full Text Available In this paper the simulation of Shunt Active power Filter using P-Q theory and PI controller has been presented. This SAPF compensates the harmonic currents drawn by three phase six pulse AC/DC converter. The process of compensation is done by calculating the instantaneous reactive power losses using p-q theory and the PI controller to reduce the ripple voltage of the dc capacitor of the PWM-VSI. This approach is different from conventional approach and provides very effective solution. In this simulation we use hysteresis band current controller (HCC for switching the VSI inverter. The simulation has been done for both steady state and transient conditions

  17. Nonlinear disturbance attenuation control for four-leg active power filter based on voltage source inverter

    Institute of Scientific and Technical Information of China (English)

    Juming CHEN; Feng LIU; Shengwei MEI

    2006-01-01

    Active power filter (APF) based on voltage source inverter (VSI) is one of the important measures for handling the power quality problem. Mathematically, the APF model in a power grid is a typical nonlinear one. The idea of passivity is a powerful tool to study the stabilization of such a nonlinear system. In this paper, a state-space model of the four-leg APF is derived, based on which a new H-infinity controller for current tracking is proposed from the passivity point of view. It can achieve not only asymptotic tracking, but also disturbance attenuation in the sense of L2-gain. Subsequently,a sufficient condition to guarantee the boundedness and desired mean of the DC voltage is also given. This straightforward condition is consistent with the power-balancing law of electrical circuits. Simulations performed on PSCAD platform verify the validity of the new approach.

  18. Adaptive RBF Neural Network Control for Three-Phase Active Power Filter

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    Juntao Fei

    2013-05-01

    Full Text Available Abstract An adaptive radial basis function (RBF neural network control system for three-phase active power filter (APF is proposed to eliminate harmonics. Compensation current is generated to track command current so as to eliminate the harmonic current of non-linear load and improve the quality of the power system. The asymptotical stability of the APF system can be guaranteed with the proposed adaptive neural network strategy. The parameters of the neural network can be adaptively updated to achieve the desired tracking task. The simulation results demonstrate good performance, for example showing small current tracking error, reduced total harmonic distortion (THD, improved accuracy and strong robustness in the presence of parameters variation and nonlinear load. It is shown that the adaptive RBF neural network control system for three-phase APF gives better control than hysteresis control.

  19. Different View on PQ Theory Used in the Control Algorithm of Active Power Filters

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    Rastislav Pavlanin

    2006-01-01

    Full Text Available The improvement of power quality is a frequently discussed issue, which still requires a considerable research effort to be devoted to the study of the problem. The aim of this paper is to describe some problems related to the control of switching compensators, commonly known as active power filters. It also includes some shortcomings of pq theory regarded as three phase instantaneous power theory. The term “shortcomings” means that the pq theory does not provide a proper description of power properties. Moreover the control algorithm based on this theory only achieves satisfactory results for sinusoidal balanced voltage system. Nevertheless it can still be considered a helpful approach to the problem under study. The simulation results presented in this paper illustrate the weaknesses of the pq theory.

  20. Voltage Quality Enhancement and Fault Current Limiting with Z-Source based Series Active Filter

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    F. Gharedaghi

    2011-11-01

    Full Text Available In this study, series active filter or dynamic voltage restorer application is proposed for reduction of downstream fault current in addition to voltage quality enhancement. Recently, the application of Z-source inverter is proposed in order to optimize DVR operation. This inverter makes DVR to operate appropriately when the energy storage device’s voltage level severely falls. Here, the Z-source inverter based DVR is proposed to compensate voltage disturbance at the PCC and to reduce the fault current in downstream of DVR. By calculating instantaneous current magnitude in synchronous frame, control system recognizes if the fault exists or not, and determines whether DVR should compensate voltage disturbance or try to reduce the fault current. The proposed system is simulated under voltage sag and swell and short circuit conditions. The simulation results show that the system operates correctly under voltage sag and short circuit conditions.